National Library of Energy BETA

Sample records for fine particulate emissions

  1. Advanced Fine Particulate Characterization Methods

    SciTech Connect (OSTI)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and sunflower hulls for the biomass material to be carbonized. The ability to remove mercury from a bituminous coal's derived flue gas was low. Removals of only 15% were attained while injecting 6 lb/Macf of activated carbon upstream of an electrostatic precipitator. Poisoning of sites on the activated carbon by SO{sub 2} and SO{sub 3} contributed to the poor mercury capture performance.

  2. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Glenn C. England

    2004-10-20

    In 1997, the United States Environmental Protection Agency (EPA) promulgated new National Ambient Air Quality Standards (NAAQS) for particulate matter, including for the first time particles with aerodynamic diameter smaller than 2.5 micrometers ({micro}m) referred to as PM2.5. PM2.5 in the atmosphere also contributes to reduced atmospheric visibility, which is the subject of existing rules for siting emission sources near Class 1 areas and new Regional Haze rules. There are few existing data regarding emissions and characteristics of fine aerosols from oil, gas and power generation industry combustion sources, and the information that is available is generally outdated and incomplete. Traditional stationary source air emission sampling methods tend to underestimate or overestimate the contribution of the source to ambient aerosols because they do not properly account for primary aerosol formation, which occurs after the gases leave the stack. Primary aerosol includes both filterable particles that are solid or liquid aerosols at stack temperature plus those that form as the stack gases cool through mixing and dilution processes in the plume downwind of the source. These deficiencies in the current methods can have significant impacts on regulatory decision-making. PM2.5 measurement issues were extensively reviewed by the American Petroleum Institute (API) (England et al., 1998), and it was concluded that dilution sampling techniques are more appropriate for obtaining a representative particulate matter sample from combustion systems for determining PM2.5 emission rate and chemical speciation. Dilution sampling is intended to collect aerosols including those that condense and/or react to form solid or liquid aerosols as the exhaust plume mixes and cools to near-ambient temperature immediately after the stack discharge. These techniques have been widely used in recent research studies. For example, Hildemann et al. (1994) and McDonald et al. (1998) used filtered ambient air to dilute the stack gas sample followed by 80-90 seconds residence time to allow aerosol formation and growth to stabilize prior to sample collection and analysis. More accurate and complete emissions data generated using the methods developed in this program will enable more accurate source-receptor and source apportionment analysis for PM2.5 National Ambient Air Quality Standards (NAAQS) implementation and streamline the environmental assessment of oil, gas and power production facilities. The overall goals of this program were to: (1) Develop improved dilution sampling technology and test methods for PM2.5 mass emissions and speciation measurements, and compare results obtained with dilution and traditional stationary source sampling methods. (2) Develop emission factors and speciation profiles for emissions of fine particulate matter, especially organic aerosols, for use in source-receptor and source apportionment analyses. (3) Identify and characterize PM2.5 precursor compound emissions that can be used in source-receptor and source apportionment analyses.

  3. Response of fine particulate matter to emission changes of oxides of nitrogen and anthropogenic volatile organic compounds in the eastern United States

    SciTech Connect (OSTI)

    Alexandra P. Tsimpidi; Vlassis A. Karydis; Spyros N. Pandis

    2008-11-15

    A three-dimensional chemical transport model (Particulate Matter Comprehensive Air Quality Model with Extensions) is used to investigate changes in fine particle (PM2.5) concentrations in response to 50% emissions changes of oxides of nitrogen (NOx) and anthropogenic volatile organic compounds (VOCs) during July 2001 and January 2002 in the eastern United States. The reduction of NOx emissions by 50% during the summer results in lower average oxidant levels and lowers PM2.5 (8% on average), mainly because of reductions of sulfate (9-11%), nitrate (45-58%), and ammonium (7-11%). The organic particulate matter (PM) slightly decreases in rural areas, whereas it increases in cities by a few percent when NOx is reduced. Reduction of NOx during winter causes an increase of the oxidant levels and a rather complicated response of the PM components, leading to small net changes. Sulfate increases (8-17%), nitrate decreases (18-42%), organic PM slightly increases, and ammonium either increases or decreases a little. The reduction of VOC emissions during the summer causes on average a small increase of the oxidant levels and a marginal increase in PM2.5. This small net change is due to increases in the inorganic components and decreases of the organic ones. Reduction of VOC emissions during winter results in a decrease of the oxidant levels and a 5-10% reduction of PM2.5 because of reductions in nitrate (4-19%), ammonium (4-10%), organic PM (12-14%), and small reductions in sulfate. Although sulfur dioxide (SO{sub 2}) reduction is the single most effective approach for sulfate control, the coupled decrease of SO{sub 2} and NOx emissions in both seasons is more effective in reducing total PM2.5 mass than the SO{sub 2} reduction alone. 34 refs., 7 figs., 1 tab.

  4. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  5. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1988-01-01

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

  6. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  7. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-10-02

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  8. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2008-12-31

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This is accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results were compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratorys monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions provides critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  9. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Glenn C. England; Stephanie Wien; Mingchih O. Chang

    2002-08-01

    This report provides results from the first year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operations. Detailed emission rate and chemical speciation test results for a refinery gas-fired process heater and plans for cogeneration gas turbine tests and pilot-scale tests are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods to compare PM2.5 mass and chemical speciation. Test plans are presented for a gas turbine facility that will be tested in the fourth quarter of 2002. A preliminary approach for pilot-scale tests is presented that will help define design constraints for a new dilution sampler design that is smaller, lighter, and less costly to use.

  10. Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Gaseous Emissions - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  11. Characterization of Particulate Emissions from GDI Engine Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis ...

  12. Particle Number & Particulate Mass Emissions Measurements on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP ...

  13. Fine Structure Studies in Proton Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure Studies in Proton Emission In order to understand the evolution of single particle wave functions and deformations beyond the proton drip line, a program has been initiated to study fine structure decay in proton emission. Fine structure in the proton emission spectrum allows one not only to define low energy states in the daughter, but from a comparison of the proton energies and partial half-lives, enables determination of the composition of the single-particle proton states in the

  14. Effects of Advanced Combustion Technologies on Particulate Matter Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characteristics | Department of Energy Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Effects of Advanced Combustion Technologies on Particulate Matter Emissions Characteristics Findings of important implications for aftertreatment devices such as EGR coolers and diesel particulate filters, of physico-chemical changes observed in particulate matter during advanced combustion. PDF icon deer08_storey.pdf More Documents & Publications Measurement and

  15. Investigation of Direct Injection Vehicle Particulate Matter Emissions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Direct Injection Vehicle Particulate Matter Emissions Investigation of Direct Injection Vehicle Particulate Matter Emissions This study focuses primarily on particulate matter mass analysis of a gasoline direct injection engine in a test cell with a chassis dynamometer. PDF icon p-10_gibbs.pdf More Documents & Publications On-Road PM Mass Emission Measured with OBS-TRPM Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Reducing the

  16. Final Report: Particulate Emissions Testing, Unit 1, Potomac River

    Energy Savers [EERE]

    Generating Station, Alexandria, Virginia | Department of Energy Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria, Virginia Docket No. EO-05-01: TRC Environmental Corporation (TRC) of Lowell, Massachusetts was retained by Mirant Potomac River, LLC (Mirant) to provide sampling and analytical support in completing a Particulate Emission

  17. Final Report: Particulate Emissions Testing, Unit 1, Potomac...

    Broader source: Energy.gov (indexed) [DOE]

    analytical support in completing a Particulate Emission Test of Unit 1 of the Potomac River generating facility. The Test Program at the Potomac facility involved the completion ...

  18. Characterization of Particulate Emissions from GDI Engine Combustion with

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alcohol-blended Fuels | Department of Energy Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Characterization of Particulate Emissions from GDI Engine Combustion with Alcohol-blended Fuels Analysis showed that gasoline direct injection engine particulates from alcohol-blended fuels are significantly different in morphology and nanostructures PDF icon p-19_seong.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Fuel and Lubricant

  19. Reducing the Particulate Emission Numbers in DI Gasoline Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy the Particulate Emission Numbers in DI Gasoline Engines Reducing the Particulate Emission Numbers in DI Gasoline Engines Formation of droplets was minimized through optimization of fuel vaporization and distribution avoiding air/fuel zones richer than stoichiometric and temperatures that promote particle formation PDF icon deer10_klindt.pdf More Documents & Publications Bosch Powertrain Technologies Vehicle Emissions Review - 2012 Ethanol Effects on Lean-Burn and

  20. Emissions and Durability of Underground Mining Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Durability of Underground Mining Diesel Particulate Filter Applications Emissions and Durability of Underground Mining Diesel Particulate Filter Applications Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_rubeli.pdf More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine

  1. Concentrations and Size Distributions of Particulate Matter Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel | Department of Energy Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel 2002 DEER Conference Presentation: West Virginia

  2. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    DOE R&D Accomplishments [OSTI]

    Molina, Luisa T.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavala, Miguel; Velasco, Erik; Molina; Mario J.

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation.

  3. Emission abatement system utilizing particulate traps

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2004-04-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  4. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace056_stewart_2011_o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions

  5. The use of a receptor model for fine particulate in Mexico City

    SciTech Connect (OSTI)

    Vega, E.; Garcia, I.; Ruiz, M.E.

    1997-12-31

    Mexico City Metropolitan Area (MCMA) faces severe pollution problems typical of large urban areas all over the world. The city is in an elevated basin (2,240 m) at a subtropical latitude (19.5N), with a high mountain chain at the West and South. This basin setting inhibits dispersion of pollution and contributes to the frequent wintertime thermal inversions which further trap pollutants near the surface. The study of atmospheric pollution and its control have been carried out using physico-chemical dispersion models, and the type known as receptor models often finds favor. The main objective of this paper is to present the results of a chemical mass balance receptor model applied to two different data sets of particulate matter. The twelve-hour samples were collected during day and night periods in the winter of 1989, previous to the introduction of catalytic converters in automobiles, and the other after 1991, since the catalytic converters are compulsory in all the new model vehicles. Samples of particulate matter were collected using a denuder and a Hi-Vol systems for the fine fraction (aerosols with diameter less than 2.5 {micro}m) and total suspended particles respectively. The results show that the major source contributions to the inhalable particulate matter for the first period are: automobiles (44%); secondary aerosols (19%); dust (10%).

  6. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Molina, Luisa T.; Molina, Mario J.; Volkamer, Rainer; de Foy, Benjamin; Lei, Wenfang; Zavaka, Miguel; Velasco, Erik

    2008-10-31

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a com

  7. Requirements from Particulate Filter Technology for Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions ...

  8. Emissions and Durability of Underground Mining Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Ceramic Particulate Filters Development of an Accelerated Ash-Loading Protocol ...

  9. SOURCE SIGNATURES OF FINE PARTICULATE MATTER FROM PETROLEUM REFINING AND FUEL USE

    SciTech Connect (OSTI)

    Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Artur Braun; Yuanzhi Chen; J. David Robertson; Joseph Kyger; Adel F. Sarofim; Ronald J. Pugmire; Henk L.C. Meuzelaar; JoAnn Lighty

    2003-07-31

    The molecular structure and microstructure of a suite of fine particulate matter (PM) samples produced by the combustion of residual fuel oil and diesel fuel were investigated by an array of analytical techniques. Some of the more important results are summarized below. Diesel PM (DPM): A small diesel engine test facility was used to generate a suite of diesel PM samples from different fuels under engine load and idle conditions. C XANES, {sup 13}C NMR, XRD, and TGA were in accord that the samples produced under engine load conditions contained more graphitic material than those produced under idle conditions, which contained a larger amount of unburned diesel fuel and lubricating oil. The difference was enhanced by the addition of 5% of oxygenated compounds to the reference fuel. Scanning transmission x-ray micro-spectroscopy (STXM) was able to distinguish particulate regions rich in C=C bonds from regions rich in C-H bonds with a resolution of {approx}50 nm. The former are representative of more graphitic regions and the latter of regions rich in unburned fuel and oil. The dominant microstructure observed by SEM and TEM consisted of complex chain-like structures of PM globules {approx}20-100 nm in mean diameter, with a high fractal dimension. High resolution TEM revealed that the graphitic part of the diesel soot consisted of onion-like structures made up of graphene layers. Typically 3-10 graphene layers make up the ''onion rings'', with the layer spacing decreasing as the number of layers increases. ROFA PM: Residual oil fly ash (ROFA) PM has been analyzed by a new approach that combines XAFS spectroscopy with selective leaching procedures. ROFA PM{sub 2.5} and PM{sub 2.5+} produced in combustion facilities at the U.S. EPA National Risk Management Research Laboratory (NRML) were analyzed by XAFS before and after leaching with water, acid (1N HCl), and pentane. Both water and acid leaching removed most of the metal sulfates, which were the dominant phase present for most metals (V, Ni, Zn, etc.). This allowed conclusive identification in the leaching residue of important secondary sulfide and oxide phases, including Ni sulfide, a toxic and carcinogenic phase observed in the leached PM{sub 2.5+} samples. Other significant secondary phases identified included V{sub 2}O{sub 4}, V sulfide, and NiFe{sub 2}O{sub 4}.

  10. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace056stewart2011o.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter ...

  11. Diesel Particulate Filters and NO2 Emission Limits | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters and NO2 Emission Limits Diesel Particulate Filters and NO2 Emission Limits EPAs New air quality standards for NO2 will impact future DPF designs PDF icon deer09_ibrahim.pdf More Documents & Publications RYPOS - An Actively Regenerated DPF that Demonstrates Significant NO2 Reduction Emission Controls for Heavy-Duty Trucks RYPOS Trap Field Demonstrations Part 1

  12. Fuel-Neutral Studies of Particulate Matter Transport Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace056_stewart_2012_o.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods

  13. Concentrations and Size Distributions of Particulate Matter Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigation of the Effects of Fuels and Aftertreatment Devices on the Emission Profiles of Trucks and Buses ARB's Study of Emissions from Diesel and CNG Heavy-duty Transit Buses ...

  14. Advances in controlling particulate emissions from fossil-fired power plants

    SciTech Connect (OSTI)

    Chang, R.

    1995-12-31

    Present and possible future Federal, state, and local air pollutant emission regulations coupled with an increasingly competitive business environment and the aging of existing particulate control equipment are motivating utilities to improve particulate control system effectiveness and reduce control cost. To these ends, several cost-effective means of improving particulate control are being developed and tested. Three fossil plant retrofit technologies of note include two flue gas conditioning systems--one ``agentless`` arrangement that uses the SO{sub 2} in the flue gas as the raw material for an SO{sub 3} conditioning system, and a promising new additive that has performed well in laboratory and pilot-scale tests. A second retrofit technology supplements all or most of the existing electrostatic precipitator with a pulse-jet baghouse. A third approach described in this paper is one example of a new class of advanced filtration systems, some of which can remove NO{sub x} and particulate in the same vessel. Technologies like these will enable utilities to boost particulate removal effectiveness after switching to lower-sulfur coal for Clean Air Act compliance, minimize compliance costs, and optimally position themselves for possible further emission regulations.

  15. Spectral Emissions and Dosimetry of Metal Tritide Particulates

    SciTech Connect (OSTI)

    Strom, Daniel J.; Stewart, Robert D.; McDonald, Joseph C.

    2002-01-01

    Inference of intakes and doses from inhalation of metal tritide particles has come under scrutiny because of decommissioning and decontamination of U.S. Department of Energy facilities. Since self-absorption of radiation is very significant for larger particles, interpretation of counting results of metal tritide particles by liquid scintillation requires information about emission spectra. Similarly, inference of dose requires knowledge of charged particle and photon spectra. Using the PENELOPE Monte Carlo radiation transport computer code, we calculated various dosimetric, microdosimetric and spectral emissions from tritides of Sc, Ti, Zr, Er, and Hf. For metal tritide particles with physical diameters in the range from about 0.01 mm to 25 mm, we present energy emission fractions, distributions of microdosimetric quantities, and the emitted spectra of electrons and bremsstrahlung photons. Results characterizing the effects of uncertainties associated with the composition and density of the tritides are also presented. Emission spectra are used to illustrate trends in the relationship between "apparent" and "observed" activity as a function of particle type and size. Emissions from metal tritide particles are weakly penetrating, and the emission spectra tend to "harden" as the particle size increases. Microdosimetric considerations suggest that the radiation emitted by metal tritides can be classified as a low Linear Energy Transfer (LET) radiation source. For cells less than about 7 mm away from the surface of a metal tritide, the primary dose component is due to electrons. However, bremsstrahlung radiation may deposit some energy tens, hundreds or even thousands of micrometers away from the surface of a tritide particle.

  16. Implications of Low Particulate Matter Emissions on System Fuel Efficiency for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Parks, II, James E; Prikhodko, Vitaly Y

    2009-01-01

    Advanced diesel combustion regimes such as High Efficiency Clean Combustion (HECC) offer the benefits of reduced engine out NOX and particulate matter (PM) emissions. Lower PM emissions during advanced combustion reduce the demand on diesel particulate filters (DPFs) and can, thereby, reduce the fuel penalty associated with DPF regeneration. In this study, a SiC DPF was loaded and regenerated on a 1.7-liter 4-cylinder diesel engine operated in conventional and advanced combustion modes at different speed and load conditions. A diesel oxidation catalyst (DOC) and a lean NOX trap (LNT) were also installed in the exhaust stream. Five steady-state speed and load conditions were weighted to estimate Federal Test Procedure (FTP) fuel efficiency. The DPF was loaded using lean-rich cycling with frequencies that resulted in similar levels of NOX emissions downstream of the LNT. The pressure drop across the DPF was measured at a standard point (1500 rpm, 5.0 bar) before and after loading, and a P rise rate was determined for comparison between conventional and advanced combustion modes. Higher PM emissions in conventional combustion resulted in a higher rate of backpressure rise across the DPF at all of the load points leading to more frequent DPF regenerations and higher fuel penalty. The fuel penalty during conventional combustion was 4.2% compared with 3.1% for a mixture of conventional and advanced modes.

  17. Investigation of Direct Injection Vehicle Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Direct Injection Vehicle Particulate Matter Emissions Investigation of Direct Injection Vehicle Particulate Matter Emissions This study focuses primarily on particulate matter mass ...

  18. Particulate emissions from residential wood combustion: Final report: Norteast regional Biomass Program

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The objective of this study was to provide a resource document for the Northeastern states when pursuing the analysis of localized problems resulting from residential wood combustion. Specific tasks performed include assigning emission rates for total suspended particulates (TSP) and benzo(a)pyrene (BaP) from wood burning stoves, estimating the impact on ambient air quality from residential wood combustion and elucidating the policy options available to Northeastern states in their effort to limit any detrimental effects resulting from residential wood combustion. Ancillary tasks included providing a comprehensive review on the relevant health effects, indoor air pollution and toxic air pollutant studies. 77 refs., 11 figs., 25 tabs.

  19. UTILIZING WATER EMULSIFICATION TO REDUCE NOX AND PARTICULATE EMISSIONS ASSOCIATED WITH BIODIESEL

    SciTech Connect (OSTI)

    Kass, Michael D; Lewis Sr, Samuel Arthur; Lee, Doh-Won; Huff, Shean P; Storey, John Morse; Swartz, Matthew M; Wagner, Robert M

    2009-01-01

    A key barrier limiting extended utilization of biodiesel is higher NOx emissions compared to petrodiesel fuels. The reason for this effect is unclear, but various researchers have attributed this phenomena to the higher liquid bulk modulus associated with biodiesel and the additional heat released during the breaking of C-C double bonds in the methyl ester groups. In this study water was incorporated into neat biodiesel (B100) as an emulsion in an attempt to lower NOx and particulate matter (PM) emissions. A biodiesel emulsion containing 10wt% water was formulated and evaluated against an ultra-low sulfur petroleum diesel (ULSD) and neat biodiesel (B100) in a light-duty diesel engine operated at 1500RPM and at loads of 68Nm (50ft-lbs) and 102Nm (75ft-lbs). The influence of exhaust gas recirculation (EGR) was also examined. The incorporation of water was found to significantly lower the NOx emissions of B100, while maintaining fuel efficiency when operating at 0 and 27% EGR. The soot fraction of the particulates (as determined using an opacity meter) was much lower for the B100 and B100-water emulsion compared ULSD. In contrast, total PM mass (for the three fuel types) was unchanged for the 0% EGR condition but was significantly lower for the B100 and B100-emulsion during the 27% EGR condition compared to the ULSD fuel. Analysis of the emissions and heat release data indicate that water enhances air-fuel premixing to maintain fuel economy and lower soot formation. The exhaust chemistry of the biodiesel base fuels (B100 and water-emulsified B100) was found to be unique in that they contained measurable levels of methyl alkenoates, which were not found for the ULSD. These compounds were formed by the partial cracking of the methyl ester groups during combustion.

  20. FINE PARTICAL AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Wayne S. Seames; Art Fernandez

    2003-09-21

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and pulverized coal. The objective was to determine potential tradeoffs between CO{sub 2} mitigation through using a CO{sub 2} neutral fuel, such as municipal sewage sludge, and the emergence of other potential problems such as the emission of toxic fly ash particles. The work led to new insight into mechanisms governing the partitioning of major and trace metals from the combustion of sewage sludge, and mixtures of coal and sewage sludge. The research also showed that the co-combustion of coal and sewage sludge emitted fine particulate matter that might potentially cause greater lung injury than that from the combustion of either coal alone or municipal sewage sludge alone. The reason appeared to be that the toxicity measured required the presence of large amounts of both zinc and sulfur in particles that were inhaled. MSS provided the zinc while coal provided the sulfur. Additional research showed that the toxic effects could most likely be engineered out of the process, through the introduction of kaolinite sorbent downstream of the combustion zone, or removing the sulfur from the fuel. These results are consequences of applying ''Health Effects Engineering'' to this issue. Health Effects Engineering is a new discipline arising out of this work, and is derived from using a collaboration of combustion engineers and toxicologists to mitigate the potentially bad health effects from combustion of this biomass fuel.

  1. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  2. Advanced Hybrid Particulate Collector Project Management Plan

    SciTech Connect (OSTI)

    Miller, S.J.

    1995-11-01

    As the consumption of energy increases, its impact on ambient air quality has become a significant concern. Recent studies indicate that fine particles from coal combustion cause health problems as well as atmospheric visibility impairment. These problems are further compounded by the concentration of hazardous trace elements such as mercury, cadmium, selenium, and arsenic in fine particles. Therefore, a current need exists to develop superior, but economical, methods to control emissions of fine particles. Since most of the toxic metals present in coal will be in particulate form, a high level of fine- particle collection appears to be the best method of overall air toxics control. However, over 50% of mercury and a portion of selenium emissions are in vapor form and cannot be collected in particulate control devices. Therefore, this project will focus on developing technology not only to provide ultrahigh collection efficiency of particulate air toxic emissions, but also to capture vapor- phase trace metals such as mercury and selenium. Currently, the primary state-of-the-art technologies for particulate control are fabric filters (baghouses) and electrostatic precipitators (ESPs). However, they both have limitations that prevent them from achieving ultrahigh collection of fine particulate matter and vapor-phase trace metals. The objective of this project is to develop a highly reliable advanced hybrid particulate collector (AHPC) that can provide > 99.99 % particulate collection efficiency for all particle sizes between 0.01 and 50 14m, is applicable for use with all U.S. coals, and is cost-0443competitive with existing technologies. Phase I of the project is organized into three tasks: Task I - Project Management, Reporting, and Subcontract Consulting Task 2 - Modeling, Design, and Construction of 200-acfm AHPC Model Task 3 - Experimental Testing and Subcontract Consulting

  3. Emissions of Volatile Particulate Components from Turboshaft Engines running JP-8 and Fischer-Tropsch Fuels

    SciTech Connect (OSTI)

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Landgraf, Bradley J

    2009-01-01

    Rotating-wing aircraft or helicopters are heavily used by the US military and also a wide range of commercial applications around the world, but emissions data for this class of engines are limited. In this study, we focus on emissions from T700-GE-700 and T700-GE-701C engines; T700 engine was run with military JP-8 and T701C run with both JP-8 and Fischer-Tropsch (FT) fuels. Each engine was run at three engine power settings from the idle to maximum power in sequence. Exhaust particles measured at the engine exhaust plane (EEP) have a peak mobility diameter less than 50nm in all engine power settings. At a 4-m downstream location, sulfate/sulfur measurements indicate all particulate sulfur exists practically as sulfate, and the particulate sulfur and sulfate contents increased as the engine power increased. The conversion of sulfur to sulfate was found not to be dependent on engine power setting. Analysis also showed that conversion of sulfur to sulfate was not by the adsorption of sulfur dioxide gas on the soot particles and then subsequently oxidized to form sulfate, but by gas-phase conversion of SO2 via OH or O then subsequently forming H2SO4 and condensing on soot particles. Without the sulfur and aromatic components, use of the FT fuel led to significant reduction of soot emissions as compared to that of the JP-8 fuel producing less number of particles than that of the JP-8 fuel; however, the FT fuel produced much higher number concentrations of particles smaller than 7nm than that of JP-8 in all engine power settings. This indicates non-aromatics components in the FT fuel could have contributed to the enhancement of emissions of particles smaller than 7nm. These small particles are volatile, not observed at the EEP, and may be important in playing a role for the formation of secondary particles in the atmosphere or serving as a site for effective cloud nuclei condensation to occur.

  4. Effects of fine particulate matter and its constituents on low birth weight among full-term infants in California

    SciTech Connect (OSTI)

    Basu, Rupa; Harris, Maria; Sie, Lillian; Malig, Brian; Broadwin, Rachel; Green, Rochelle

    2014-01-15

    Relationships between prenatal exposure to fine particles (PM{sub 2.5}) and birth weight have been observed previously. Few studies have investigated specific constituents of PM{sub 2.5}, which may identify sources and major contributors of risk. We examined the effects of trimester and full gestational prenatal exposures to PM{sub 2.5} mass and 23 PM{sub 2.5} constituents on birth weight among 646,296 term births in California between 2000 and 2006. We used linear and logistic regression models to assess associations between exposures and birth weight and risk of low birth weight (LBW; <2500 g), respectively. Models were adjusted for individual demographic characteristics, apparent temperature, month and year of birth, region, and socioeconomic indicators. Higher full gestational exposures to PM{sub 2.5} mass and several PM{sub 2.5} constituents were significantly associated with reductions in term birth weight. The largest reductions in birth weight were associated with exposure to vanadium, sulfur, sulfate, iron, elemental carbon, titanium, manganese, bromine, ammonium, zinc, and copper. Several of these PM{sub 2.5} constituents were associated with increased risk of term LBW. Reductions in birth weight were generally larger among younger mothers and varied by race/ethnicity. Exposure to specific constituents of PM{sub 2.5}, especially traffic-related particles, sulfur constituents, and metals, were associated with decreased birth weight in California. -- Highlights: Examine full gestational and trimester fine particle and its constituents on term birth weight. Fine particles and several of its constituents associated with birth weight reductions. Largest reductions for traffic-related particles, sulfur constituents, and metals. Greater birth weight reductions for younger mothers, and varied by race/ethnicity.

  5. Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  6. Vehicle Technologies Office Merit Review 2014: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  7. Ethanol Blend Effects On Direct Injection Spark-Ignition Gasoline Vehicle Particulate Matter Emissions

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Barone, Teresa L

    2010-01-01

    Direct injection spark-ignition (DISI) gasoline engines can offer better fuel economy and higher performance over their port fuel-injected counterparts, and are now appearing increasingly in more U.S. vehicles. Small displacement, turbocharged DISI engines are likely to be used in lieu of large displacement engines, particularly in light-duty trucks and sport utility vehicles, to meet fuel economy standards for 2016. In addition to changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the 10% allowed by current law due to the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA). In this study, we present the results of an emissions analysis of a U.S.-legal stoichiometric, turbocharged DISI vehicle, operating on ethanol blends, with an emphasis on detailed particulate matter (PM) characterization. Gaseous species, particle mass, and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. For the gaseous species and particle mass measurements, dilution was carried out using a full flow constant volume sampling system (CVS). For the particle number concentration and size distribution measurements, a micro-tunnel dilution system was employed. The vehicles were fueled by a standard test gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. During steady-state operation, the geometric mean diameter of the particle-number size distribution remained approximately the same (50 nm) but the particle number concentration decreased with increasing ethanol content in the fuel. In addition, increasing ethanol content significantly reduced the number concentration of 50 and 100 nm particles during gradual and WOT accelerations.

  8. A Study of Emissions from a Light Duty Diesel Engine with the European Particulate Measurement Programme

    Broader source: Energy.gov [DOE]

    A comparison of regulated emissions measured by the California Air Resources Board (CARB) and particle number emissions with the Joint Research Committee participating international laboratories was a success, and the CARB measurements and standard deviations compared well with the other laboratories

  9. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul M.; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition.

  10. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nicholas; Farron, Carrie; Foster, David E.; Andrie, Michael; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun S.; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented in an engine test cell with a spark ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion. SIDI is of particular interest for improved fuel efficiency compared to other SI engines, however, the efficiency benefit comes with greater PM emissions and may therefore be subject to the proposed number based PM regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition

  11. Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-Out and Tailpipe Particulate Matter Emissions: Preprint

    SciTech Connect (OSTI)

    He, X.; Ireland, J. C.; Zigler, B. T.; Ratcliff, M. A.; Knoll, K. E.; Alleman, T. L.; Tester, J. T.

    2011-02-01

    The influences of ethanol and iso-butanol blended with gasoline on engine-out and post Three-Way Catalyst (TWC) particle size distribution and number concentration were studied using a GM 2.0L turbocharged Spark Ignition Direct Injection (SIDI) engine. The engine was operated using the production ECU with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. US federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at ten selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm. Idle and low speed / low load conditions emitted higher total particle numbers than other operating conditions. At idle, the engine-out Particulate Matter (PM) emissions were dominated by nucleation mode particles, and the production TWC reduced these nucleation mode particles by more than 50%, while leaving the accumulation mode particle distribution unchanged. At engine load higher than 6 bar NMEP, accumulation mode particles dominated the engine-out particle emissions and the TWC had little effect. Compared to the baseline gasoline (E0), E10 does not significantly change PM emissions, while E20 and BU12 both reduce PM emissions under the conditions studied. Iso-butanol was observed to impact PM emissions more than ethanol, with up to 50% reductions at some conditions. In this paper, the issues related to PM measurement using FMPS are also discussed. While some uncertainties are due to engine variation, the FMPS must be operated under careful maintenance procedures in order to achieve repeatable measurement results.

  12. Evaluation of a Partial Flow Dilution System for Transient Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Partial Flow Dilution System for Transient Particulate Matter Emissions Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions A commercially...

  13. Fine particle (2.5 microns) emissions: regulations, measurement, and control

    SciTech Connect (OSTI)

    John D. McKenna; James H. Turner; James P. McKenna, Jr.

    2008-09-15

    Contents: Introduction; Health effects; Air monitoring; Emission control methods - fabric filter/baghouses, electrostatic precipitators, wet scrubbers; Environmental technology verification and baghouse filtration products; Cost considerations; and Nanoparticulates.

  14. The use of CETANER{trademark} for the reduction of particulate matter emissions in a turbocharged direct injection (TDI) diesel engine

    SciTech Connect (OSTI)

    Hess, H.S.; Chiodo, J.A.; Boehman, A.L.; Tijim, P.J.A.; Waller, F.J.

    1999-07-01

    In this experimental study, the effects of the addition of CETANER{trademark} to a premium diesel fuel at various blend levels (5%, 10% and 15% by weight) were evaluated using a 1.9 liter turbocharged direct injection diesel engine. CETANER{trademark}, a product developed by Air Products and Chemicals, Inc., can be manufactured from coal-derived syngas through a two-stage process: (i) Liquid Phase DiMethyl Ether synthesis (LPDME); and (ii) oxidative coupling of DiMethyl Ether (DME) to form long chain linear ethers. When compared to other oxygenated components currently being researched, CETANER has several key advantages: (1) it is derived from a non-petroleum feedstock; (2) it has a cetane number greater than 100; and (3) it will have a cost comparable to diesel fuel. Particulate matter emissions and exhaust gas composition (NOx and CO), were determined at six steady-state engine operating conditions. In addition, fuel properties (viscosity, cloud point, pour point, density, flash point and calorific value) of the various blends were also determined. Engine test results indicate that CETANER is effective in reducing particulate matter emissions at all blend levels tested, without any modifications to engine operating parameters. At the highest blend level (15% CETANER by weight), particulate matter emissions were reduced by greater than 20% when compared to premium diesel fuel.

  15. Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

    SciTech Connect (OSTI)

    Matthias, Nick; Farron, Carrie; Foster, David E.; Andrie, Mike; Krieger, Roger; Najt, Paul; Narayanaswamy, Kushal; Solomon, Arun; Zelenyuk, Alla

    2012-01-01

    More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs) from an aerosol sample. One method is a Dekati Thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample handling methods have been implemented for this project in an engine test cell built around a direct injection spark ignited (DISI) engine. The engine was designed for stoichiometric, homogeneous combustion. Direct injection is of particular interest for improved fuel efficiency but this comes with the production of a significant amount of (PM) and may therefore be subject to the proposed number based regulation. Another aspect of this project is to characterize PM from this engine in terms of particle number and composition. The first interesting observation is that PM number distributions, acquired using a TSI SMPS, have a large accumulation mode (30-294 nm) but a very small nuclei mode (8-30 nm). This is understood to represent a lack of condensation particles meaning that neither the exhaust conditions nor the sample handling conditions are conducive to condensation. This lack of nuclei mode does not, however, represent a lack of VOCs in the sample. It has been observed, using mass spectral analysis (limited to PM>50 nm), that PM from the DISI engine has approximately 40% organic content through varying operating conditions. This begs the question of how effective different sample handling methods are at removing these VOCs. For one specific operating condition, called Cold Start, the un-treated PM was 40% organic. The TD reduced this by 7% while the EvCh reduced it by 13%. For other operating conditions, PM treated for volatile removal actually exhibited an increase in organic fraction on the order of 5%. This addition appears to be sensitive to the gaseous hydrocarbon concentrations in the exhaust although a precise correlation has not yet been derived. It has been concluded that VOCs are tightly bound to the PM carbon core and thus are not effectively removed by either treatment method.

  16. 2007 Diesel Particulate Measurement Research (E-66 Project) ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Particulate Measurement Research (E-66 Project) 2007 Diesel Particulate Measurement Research (E-66 Project) 2004 Diesel Engine Emissions Reduction (DEER) Conference:...

  17. Predicting Thermal Stress in Diesel Particulate Filters | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Stress in Diesel Particulate Filters Predicting Thermal Stress in Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Corning...

  18. Volatile organic compound and particulate emission studies of AF (Air Force) paint-booth facilities. Phase 1. Final report, February-December 1987

    SciTech Connect (OSTI)

    Ayer, J.; Wolbach, D.

    1988-07-01

    This study presents the results of volatile organic compound (VOC) and particulate emission surveys performed at three Air Force painting facilities. The three facilities -- one in McClellan AFB buildings 655 and two at Travis AFB in buildings 550 and 1014 -- did not meet local VOC emission standards. The possibility of reducing these emissions with recirculation modifications and various VOC reduction and control strategies is discussed. Although VOC emissions from paint spray booths can be controlled by add-on control systems, control is expensive for present air flow rates. The use of air recirculation within the spray booth can reduce the cost of VOC emission controls by reducing the quantity of air that requires processing. Recirculation systems were designed for two of the painting facilities included in this study. In designing the systems, various criteria such as paint booth VOC concentrations and health and safety standards were considered. Add-on VOC emission-control systems that can be used in conjunction with the recirculation system are evaluated. The devices of interest are a solvent incineration system and an activated-carbon adsorption bed. The VOC removal efficiency, initial capital investment and operating costs for both of these technologies are discussed.

  19. Pleated Ceramic Fiber Diesel Particulate Filter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pleated Ceramic Fiber Diesel Particulate Filter Pleated Ceramic Fiber Diesel Particulate Filter 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_nixdorf.pdf More Documents & Publications Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Expanded Capacity Microwave-Cleaned Diesel Particulate Filter

  20. ADVANCED HYBRID PARTICULATE COLLECTOR

    SciTech Connect (OSTI)

    Ye Zhuang; Stanley J. Miller; Michelle R. Olderbak; Rich Gebert

    2001-12-01

    A new concept in particulate control, called an advanced hybrid particulate collector (AHPC), is being developed under funding from the U.S. Department of Energy. The AHPC combines the best features of electrostatic precipitators (ESPs) and baghouses in an entirely novel manner. The AHPC concept combines fabric filtration and electrostatic precipitation in the same housing, providing major synergism between the two methods, both in the particulate collection step and in transfer of dust to the hopper. The AHPC provides ultrahigh collection efficiency, overcoming the problem of excessive fine-particle emissions with conventional ESPs, and solves the problem of reentrainment and re-collection of dust in conventional baghouses. Phase I of the development effort consisted of design, construction, and testing of a 5.7-m{sup 3}/min (200-acfm) working AHPC model. Results from both 8-hr parametric tests and 100-hr proof-of-concept tests with two different coals demonstrated excellent operability and greater than 99.99% fine-particle collection efficiency. Since all of the developmental goals of Phase I were met, the approach was scaled up in Phase II to a size of 255 m{sup 3}/min (9000 acfm) (equivalent in size to 2.5 MW) and was installed on a slipstream at the Big Stone Power Plant. For Phase II, the AHPC at Big Stone Power Plant was operated continuously from late July 1999 until mid-December 1999. The Phase II results were highly successful in that ultrahigh particle collection efficiency was achieved, pressure drop was well controlled, and system operability was excellent. For Phase III, the AHPC was modified into a more compact configuration, and components were installed that were closer to what would be used in a full-scale commercial design. The modified AHPC was operated from April to July 2000. While operational results were acceptable during this time, inspection of bags in the summer of 2000 revealed some membrane damage to the fabric that appeared to be caused by electrical effects. Subsequently, extensive theoretical, bench-scale, and pilot-scale investigations were completed to find an approach to prevent bag damage without compromising AHPC performance. Results showed that the best bag protection and AHPC performance were achieved by using a perforated plate installed between the discharge electrodes and bags. This perforated-plate design was then installed in the 2.5-MW AHPC at Big Stone Power Plant in Big Stone City, South Dakota, and the AHPC was operated from March to June 2001. Results showed that the perforated-plate design solved the bag damage problem and offered even better AHPC performance than the previous design. All of the AHPC performance goals were met, including ultrahigh collection efficiency, high air-to-cloth ratio, reasonable pressure drop, and long bag-cleaning interval.

  1. Users guide for the conversion of Navy paint-spray-booth particulate emission-control systems from wet to dry operation. Final report, January-September 1989

    SciTech Connect (OSTI)

    Ayer, J.; Tate, D.

    1990-03-01

    The report is a guide for converting U.S. Navy paint-spray-booth particulate emission control systems from wet to dry operation. The use of water curtains for air-pollution-control of paint-spray booths is considered a major source of water and solid-waste pollution from industrial painting operations. It is possible, however, to eliminate this water-pollution problem and significantly reduce the solid-waste load by converting the booth to utilize a dry-filter pollution-control system. The conversion, however, requires extensive planning prior to actual facility modification. The report describes requirements to facilitate the planning and preparation for conversion of typical spray booths. Although the report addresses modifications of Navy spray booths, the basic engineering requirements discussed apply also to other Department of Defense installations and to commercial industrial facilities.

  2. Advanced particulate matter control apparatus and methods

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND); Zhuang, Ye (Grand Forks, ND); Almlie, Jay C. (East Grand Forks, MN)

    2012-01-10

    Apparatus and methods for collection and removal of particulate matter, including fine particulate matter, from a gas stream, comprising a unique combination of high collection efficiency and ultralow pressure drop across the filter. The apparatus and method utilize simultaneous electrostatic precipitation and membrane filtration of a particular pore size, wherein electrostatic collection and filtration occur on the same surface.

  3. Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure in Genotoxicity Studies to Support Engineering Development of Emission Controls

    Broader source: Energy.gov [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  4. Particle Number & Particulate Mass Emissions Measurements on a 'Euro VI' Heavy-duty Engine using the PMP Methodologies

    Broader source: Energy.gov [DOE]

    Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  5. Ceramic Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramic Particulate Filters Ceramic Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_yonushonis.pdf More Documents & Publications Durability of Diesel Engine Particulate Filters Durability of Diesel Engine Particulate Filters Durability of Diesel Engine

  6. Full phosphorescent white-light organic light-emitting diodes with improved color stability and efficiency by fine tuning primary emission contributions

    SciTech Connect (OSTI)

    Hua, Wang, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Du, Xiaogang [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China) [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Su, Wenming, E-mail: wmsu2008@sinano.ac.cn, E-mail: wanghua001@tyut.edu.cn; Zhang, Dongyu [Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China)] [Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China); Lin, Wenjing [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China) [Key Laboratory of Interface Science and Engineering in Advanced Materials, Taiyuan University of Technology, Ministry of Education, Taiyuan 030024 (China); Research Center of Advanced Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024 (China); Printable Electronics Research Centre, Suzhou Institute of Nano-Tech and Nano-Bionics, CAS, suzhou 215123 (China)

    2014-02-15

    In this paper, a novel type of white-light organic light emitting diode (OLED) with high color stability was reported, in which the yellow-light emission layer of (4,4{sup ?}-N,N{sup ?}-dicarbazole)biphenyl (CBP) : tris(2-phenylquinoline-C2,N{sup ?})iridium(III) (Ir(2-phq){sub 3}) was sandwiched by double blue-light emission layers of 1,1-bis-[(di-4-tolylamino)pheny1]cyclohexane (TAPC) : bis[4,6-(di-fluorophenyl)-pyridinato-N,C2{sup ?}]picolinate (FIrpic) and tris[3-(3-pyridyl)mesityl]borane (3TPYMB):FIrpic. And, it exhibited the maximum current efficiency of 33.1 cd/A, the turn-on voltage at about 3 V and the maximum luminance in excess of 20000 cd/m{sup 2}. More important, it realized very stable white-light emission, and its CIE(x, y) coordinates only shift from (0.34, 0.37) to (0.33, 0.37) as applied voltage increased from 5 V to 12 V. It is believed that the new scheme in emission layer of white-light OLED can fine tune the contribution of primary emission with applied voltage changed, resulting in high quality white-light OLED.

  7. Assessing the nonlinear response of fine particles to precursor emissions: Development and application of an extended response surface modeling technique v1.0

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, B.; Wang, S. X.; Xing, J.; Fu, K.; Fu, J. S.; Jang, C.; Zhu, Y.; Dong, X. Y.; Gao, Y.; Wu, W. J.; et al

    2015-01-30

    An innovative extended response surface modeling technique (ERSM v1.0) is developed to characterize the nonlinear response of fine particles (PM₂̣₅) to large and simultaneous changes of multiple precursor emissions from multiple regions and sectors. The ERSM technique is developed based on the conventional response surface modeling (RSM) technique; it first quantifies the relationship between PM₂̣₅ concentrations and the emissions of gaseous precursors from each single region using the conventional RSM technique, and then assesses the effects of inter-regional transport of PM₂̣₅ and its gaseous precursors on PM₂̣₅ concentrations in the target region. We apply this novel technique with a widelymore » used regional chemical transport model (CTM) over the Yangtze River delta (YRD) region of China, and evaluate the response of PM₂̣₅ and its inorganic components to the emissions of 36 pollutant–region–sector combinations. The predicted PM₂̣₅ concentrations agree well with independent CTM simulations; the correlation coefficients are larger than 0.98 and 0.99, and the mean normalized errors (MNEs) are less than 1 and 2% for January and August, respectively. It is also demonstrated that the ERSM technique could reproduce fairly well the response of PM₂̣₅ to continuous changes of precursor emission levels between zero and 150%. Employing this new technique, we identify the major sources contributing to PM₂̣₅ and its inorganic components in the YRD region. The nonlinearity in the response of PM₂̣₅ to emission changes is characterized and the underlying chemical processes are illustrated.« less

  8. Assessing the nonlinear response of fine particles to precursor emissions: Development and application of an extended response surface modeling technique v1.0

    SciTech Connect (OSTI)

    Zhao, B.; Wang, S. X.; Xing, J.; Fu, K.; Fu, J. S.; Jang, C.; Zhu, Y.; Dong, X. Y.; Gao, Y.; Wu, W. J.; Wang, J. D.; Hao, J. M.

    2015-01-30

    An innovative extended response surface modeling technique (ERSM v1.0) is developed to characterize the nonlinear response of fine particles (PM₂̣₅) to large and simultaneous changes of multiple precursor emissions from multiple regions and sectors. The ERSM technique is developed based on the conventional response surface modeling (RSM) technique; it first quantifies the relationship between PM₂̣₅ concentrations and the emissions of gaseous precursors from each single region using the conventional RSM technique, and then assesses the effects of inter-regional transport of PM₂̣₅ and its gaseous precursors on PM₂̣₅ concentrations in the target region. We apply this novel technique with a widely used regional chemical transport model (CTM) over the Yangtze River delta (YRD) region of China, and evaluate the response of PM₂̣₅ and its inorganic components to the emissions of 36 pollutant–region–sector combinations. The predicted PM₂̣₅ concentrations agree well with independent CTM simulations; the correlation coefficients are larger than 0.98 and 0.99, and the mean normalized errors (MNEs) are less than 1 and 2% for January and August, respectively. It is also demonstrated that the ERSM technique could reproduce fairly well the response of PM₂̣₅ to continuous changes of precursor emission levels between zero and 150%. Employing this new technique, we identify the major sources contributing to PM₂̣₅ and its inorganic components in the YRD region. The nonlinearity in the response of PM₂̣₅ to emission changes is characterized and the underlying chemical processes are illustrated.

  9. Alternatives to Diesel Fuel in California - Fuel Cycle Energy and Emission Effects of Possible Replacements Due to the TAC Diesel Particulate Decision

    SciTech Connect (OSTI)

    Christopher L. Saraicks; Donald M. Rote; Frank Stodolsky; James J. Eberhardt

    2000-05-01

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression ignition by spark ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7 percent above projected (total) consumption level. In the second case, ressionignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOx emissions, though all scenarios bring about PM10 reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  10. Alternatives to diesel fuel in California - fuel cycle energy and emission effects of possible replacements due to the TAC diesel particulate decision.

    SciTech Connect (OSTI)

    Saricks, C. L.; Rote, D. M.; Stodolsky, F.; Eberhardt, J. J.

    1999-12-03

    Limitations on petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible mid-course strategies, each of which results in some degree of (conventional) diesel displacement. In the first case, with substantial displacement of compression-ignition by spark-ignition engines, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles. Gasoline demand in California increases by 32.2 million liters (8.5 million gallons) per day overall, about 21% above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter (3.6 million gallon) equivalents per day, about 7% above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case the authors estimated localized air emission plus generalized greenhouse gas and energy changes. Fuel replacement by di-methyl ether yields the greatest overall reduction in NOX emissions, though all scenarios bring about PM{sub 10} reductions relative to the 2010 baseline, with greatest reductions from the first case described above and the least from fuel replacement by Fischer-Tropsch synthetic diesel. Economic implications of vehicle and engine replacement were not formally evaluated.

  11. Requirements from Particulate Filter Technology for Commercial Vehicles:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sintered Metal Particulate Filter Opens a New Dimension of Performance | Department of Energy from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance Requirements from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_biddinger.pdf More

  12. Update on 2007 Diesel Particulate Measurement Research | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2007 Diesel Particulate Measurement Research Update on 2007 Diesel Particulate Measurement Research 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_shimpi.pdf More Documents & Publications Real-Time Measurement of Diesel Trap Efficiency Mass Correlation of Engine Emissions with Spectral Instruments Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles

  13. Real-time measurements of particulate matter and polycyclic aromatic hydrocarbon emissions from stationary combustion sources used in oil and gas production

    SciTech Connect (OSTI)

    D. w. Hahn; K. r. Hencken; H. A. Johnsen; J. R. Ross; P. M. Walsh

    1998-12-10

    Particulate matter emissions and some components of the particles were measured in the exhaust from combustion equipment used in oil and gas production operations near Bakersfield, California. The combustion sources included a 22.5 MW (electric) turbine generator, a 342-Bhp rich-burn spark ignition engine, and a 50 million Btu/h steam generator, all fired using natural gas. The particle components and measurement techniques were as follows: (1) Calcium, magnesium, sodium, silicon, and iron were measured using laser-induced breakdown spectroscopy (LIBS), (2) particle-bound polycyclic aromatic hydrocarbons (PAH) were detected using the charge produced by photoionization, (3) particles having sizes between 0.1 and 7.5 {micro}m were counted using an instrument based on light scattering, and (4) total particulate matter was measured according to US EPA Method 5. Not all of the methods were applied to all of the sources. Measurements were also made in the ambient air near the combustion air inlets to the units, for comparison with the concentrations in the exhaust, but the inlet and outlet measurements were not done simultaneously. Calcium, sodium, and silicon were found in the exhaust from the steam generator at concentrations similar to those in the ambient air near the inlet to the burner. Sodium and silicon were observed in the engine exhaust at levels a factor of four higher than their concentrations in the air. The principal metal observed in the engine exhaust was calcium, a component of the lubricating oil, at a concentration of 11.6 {micro}g/m{sup 3}. The air entering the gas turbine is filtered, so the average concentrations of metals in the turbine exhaust under steady operating conditions were even lower than in the air. During start-up following a shut-down to wash the turbine, silicon and iron were the major species in the stack, at concentrations of 6.4 and 16.2 {micro}g/m{sup 3}, respectively. A possible source of silicon is the water injected into the turbine for NO{sub x} control. Iron-containing particles are expected to be scale from ferrous metals. A commercial photoelectric aerosol sensor was used to measure PAH adsorbed on particles in the exhaust from the steam generator and the rich-burn engine. The conversion of the instrument readings to PAH concentrations is dependent upon the specific distribution of PAH species present. Using the typical calibration factor recommended by the instrument manufacturer, the estimated average concentration of particle-bound PAH was below the instrument detection limit (3--10 ng/m{sup 3}) in the stack gas from the steam generator, and was estimated to be 0.045--0.15 {micro}g/m{sup 3} in the exhaust from the rich-burn engine. Particle mass concentrations estimated from number concentrations determined using the particle counting and sizing instrument were only small fractions of the concentrations measured using Method 5. This is thought to be due primarily to the limited range over which size was quantified (0.1 to 7.5 {micro}m) and the poor efficiency with which the sampling system transferred large particles.

  14. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A.P.Evans; K.E. Redinger; M.J. Holmes

    1998-04-01

    The objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESPS), fabric filters (baghouse), and wet flue gas desulfurization. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate and hydrogen chloride. Following the construction and evaluation of a representative air toxics test facility in Phase I, Phase II focused on the evaluation of mercury and several other air toxics emissions. The AECDP is jointly funded by the United States Department of Energy's Federal Energy Technology Center (DOE), the Ohio Coal Development Office within the Ohio Department of Development (oCDO), and Babcock& Wilcox-a McDermott company (B&W).

  15. Advanced Particulate Filter Technologies for Direct Injection Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Applications | Department of Energy Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Specific designs and material properties have to be developed for gasoline particulate filters based on the different engine and exhaust gas characteristic of gasoline engines compared to diesel engines, e.g., generally lower levels of engine-out particulate emissions or higher

  16. Characterization of Pre-Commercial Gasoline Engine Particulates Through

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Aerosol Methods | Department of Energy Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Advanced aerosol analysis methods were used to examine particulates from single cylinder test engines running on gasoline and ethanol blends. PDF icon deer12_zelenyuk.pdf More Documents & Publications Fuel-Neutral Studies of Particulate Matter Transport Emissions

  17. Development of Advanced Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters Development of Advanced Particulate Filters 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace024_lee_2012_o.pdf More Documents & Publications Particulate Emissions Control by Advanced Filtration Systems or GDI Engines Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF

  18. Integrated emissions control system for residential CWS furnace

    SciTech Connect (OSTI)

    Balsavich, J.C. Jr.

    1991-11-01

    To meet the emission goals set by the Pittsburgh Energy Technology Center (PETC), Tecogen Inc. is developing a novel, integrated emission control system to control NO{sub x}, SO{sub 2}, and particulate emissions. At the heart of this system is a unique emissions control reactor for the control of SO{sub 2}. This reactor provides high sorbent particle residence time within the reactor while doing so in a very compact geometry. In addition to controlling SO{sub 2} emissions, the reactor provides a means of extracting a substantial amount of the particulates present in the combustion gases. Final cleanup of any fine particulates exiting the reactor, including respirable-sized particulates, is completed with the use of high efficiency bag filters. With SO{sub 2} and particulate emissions being dealt with by an emissions control reactor and bag filters, the control of NO{sub x} emissions needs to be addressed. Under a previous contract with PETC (contract No. AC22-87PC79650), Tecogen developed a residential-scale Coal Water Slurry (CWS) combustor. This combustor makes use of centrifugal forces, set up by a predominantly tangential flow field, to separate and confine larger unburned coal particles in the furnace upper chamber. Various partitions are used to retard the axial, downward flow of these particles, and thus maximize their residence time in the hottest section of the combustor. By operating this combustor under staged conditions, the local stoichiometry in the primary zone can be controlled in such a manner as to minimize NO{sub x} emissions.

  19. Requirements-Driven Diesel Catalyzed Particulate Trap Design and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_harris.pdf More Documents & Publications Diesel Emission Control Technology Review Investigation of Aging Mechanisms in Lean NOx Traps Diesel Particulate Filters: Market Introducution

  20. Evaluation of a Partial Flow Dilution System for Transient Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Matter Emissions | Department of Energy a Partial Flow Dilution System for Transient Particulate Matter Emissions Evaluation of a Partial Flow Dilution System for Transient Particulate Matter Emissions A commercially available partial flow dilution system was evaluated against a constant volume sampling system over a suite of transient engine dynamometer tests. PDF icon deer08_shade.pdf More Documents & Publications Evaluation of the European PMP Methodologies Using Chassis Dynamometer

  1. Optimization of an Advanced Passive/Active Diesel Emission Control...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Diesel Particulate Filters and NO2 Emission Limits Active Diesel Emission Control Technology for Transport Refrigeration Units Active Diesel Emission ...

  2. Reliability and Design Strength Limit Calculations on Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy and Design Strength Limit Calculations on Diesel Particulate Filters Reliability and Design Strength Limit Calculations on Diesel Particulate Filters 2004 Diesel Engine Emissions Reduction (DEER) Confererence Presentation: Corning PDF icon 2004_deer_webb.pdf More Documents & Publications Predicting Thermal Stress in Diesel Particulate Filters Environmental Effects on Power Electronic Devices Effect of Machining Procedures on the Strength of Ceramics for

  3. Development and Applications of Catalyzed Diesel Particulate Filter |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Applications of Catalyzed Diesel Particulate Filter Development and Applications of Catalyzed Diesel Particulate Filter 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Sud Chemie Prototech Inc. PDF icon 2004_deer_huang.pdf More Documents & Publications CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets A Revealing Look Inside Passive and Active DPF Regeneration: In-Situ Optical Analysis of Ash Formation and

  4. Development of Acicular Mullite Materials for Diesel Particulate Filters

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application | Department of Energy Acicular Mullite Materials for Diesel Particulate Filters Application Development of Acicular Mullite Materials for Diesel Particulate Filters Application 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_pyzik.pdf More Documents & Publications Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Future Trends for DPFƒSCR On-Filter (SCRF) fundamental Modeling and

  5. CARB Verification of Catalyzed Diesel Particulate Filters for Emergency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Sets | Department of Energy CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets CARB Verification of Catalyzed Diesel Particulate Filters for Emergency Generator Sets 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_huang.pdf More Documents & Publications Development and Applications of Catalyzed Diesel Particulate Filter California ARB Verification Testing of the CBSTM Soot Filter for

  6. Method for dispersing catalyst onto particulate material

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  7. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  8. Diesel Particulate Filters: Market Introducution in Europe | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Filters: Market Introducution in Europe Diesel Particulate Filters: Market Introducution in Europe 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Aaqius and Aaqius PDF icon 2004_deer_seguelong2.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles French perspective on diesel engines & emissions Diesel Particulate Filter: A Success for Faurecia Exhaust Systems

  9. Pitch based foam with particulate

    DOE Patents [OSTI]

    Klett, James W. (Knoxville, TN)

    2001-01-01

    A thermally conductive, pitch based foam composite having a particulate content. The particulate alters the mechanical characteristics of the foam without severely degrading the foam thermal conductivity. The composite is formed by mixing the particulate with pitch prior to foaming.

  10. Airborne particulate discriminator

    DOE Patents [OSTI]

    Creek, Kathryn Louise; Castro, Alonso; Gray, Perry Clayton

    2009-08-11

    A method and apparatus for rapid and accurate detection and discrimination of biological, radiological, and chemical particles in air. A suspect aerosol of the target particulates is treated with a taggant aerosol of ultrafine particulates. Coagulation of the taggant and target particles causes a change in fluorescent properties of the cloud, providing an indication of the presence of the target.

  11. Integrated emissions control system for residential CWS furnace. Annual status report No. 2, October 1, 1990--September 30, 1991

    SciTech Connect (OSTI)

    Balsavich, J.C. Jr.

    1991-11-01

    To meet the emission goals set by the Pittsburgh Energy Technology Center (PETC), Tecogen Inc. is developing a novel, integrated emission control system to control NO{sub x}, SO{sub 2}, and particulate emissions. At the heart of this system is a unique emissions control reactor for the control of SO{sub 2}. This reactor provides high sorbent particle residence time within the reactor while doing so in a very compact geometry. In addition to controlling SO{sub 2} emissions, the reactor provides a means of extracting a substantial amount of the particulates present in the combustion gases. Final cleanup of any fine particulates exiting the reactor, including respirable-sized particulates, is completed with the use of high efficiency bag filters. With SO{sub 2} and particulate emissions being dealt with by an emissions control reactor and bag filters, the control of NO{sub x} emissions needs to be addressed. Under a previous contract with PETC (contract No. AC22-87PC79650), Tecogen developed a residential-scale Coal Water Slurry (CWS) combustor. This combustor makes use of centrifugal forces, set up by a predominantly tangential flow field, to separate and confine larger unburned coal particles in the furnace upper chamber. Various partitions are used to retard the axial, downward flow of these particles, and thus maximize their residence time in the hottest section of the combustor. By operating this combustor under staged conditions, the local stoichiometry in the primary zone can be controlled in such a manner as to minimize NO{sub x} emissions.

  12. The State of the Science in Diesel Particulate Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy The State of the Science in Diesel Particulate Control The State of the Science in Diesel Particulate Control 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_muntean.pdf More Documents & Publications Method Development: Identification of the Soluble Organic Fraction of Particulate Matter on DPF Soot Aftertreatment Research Prioritization: A CLEERS Industrial Survey Development of a Sub-Grid Model of a Diesel Particulate Filter:

  13. Molecular marker analysis as a guide to the sources of fine organic aerosols

    SciTech Connect (OSTI)

    Rogge, W.F.; Cass, G.R.; Hildemann, L.M.; Mazurek, M.A.; Simoneit, B.R.T.

    1992-07-01

    The molecular composition of fine particulate (D{sub p} {ge} 2 {mu}m) organic aerosol emissions from the most important sources in the Los Angeles area has been determined. Likewise, ambient concentration patterns for more than 80 single organic compounds have been measured at four urban sites (West Los Angeles, Downtown Los Angeles, Pasadena, and Rubidoux) and at one remote offshore site (San Nicolas Island). It has been found that cholesterol serves as a marker compound for emissions from charbroilers and other meat cooking operations. Vehicular exhaust being emitted from diesel and gasoline powered engines can be traced in the Los Angeles atmosphere using fossil petroleum marker compounds such as steranes and pentacyclic triterpanes (e.g., hopanes). Biogenic fine particle emission sources such as plant fragments abraded from leaf surfaces by wind and weather can be traced in the urban atmosphere. Using distinct and specific source organic tracers or assemblages of organic compounds characteristic for the sources considered it is possible to estimate the influence of different source types at any urban site where atmospheric data are available.

  14. Molecular marker analysis as a guide to the sources of fine organic aerosols

    SciTech Connect (OSTI)

    Rogge, W.F.; Cass, G.R. ); Hildemann, L.M. . Dept. of Civil Engineering); Mazurek, M.A. ); Simoneit, B.R.T. Environmental Geochemistry Group)

    1992-07-01

    The molecular composition of fine particulate (D[sub p] [ge] 2 [mu]m) organic aerosol emissions from the most important sources in the Los Angeles area has been determined. Likewise, ambient concentration patterns for more than 80 single organic compounds have been measured at four urban sites (West Los Angeles, Downtown Los Angeles, Pasadena, and Rubidoux) and at one remote offshore site (San Nicolas Island). It has been found that cholesterol serves as a marker compound for emissions from charbroilers and other meat cooking operations. Vehicular exhaust being emitted from diesel and gasoline powered engines can be traced in the Los Angeles atmosphere using fossil petroleum marker compounds such as steranes and pentacyclic triterpanes (e.g., hopanes). Biogenic fine particle emission sources such as plant fragments abraded from leaf surfaces by wind and weather can be traced in the urban atmosphere. Using distinct and specific source organic tracers or assemblages of organic compounds characteristic for the sources considered it is possible to estimate the influence of different source types at any urban site where atmospheric data are available.

  15. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A. P. Evans

    1998-12-03

    McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using the Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species, hydrogen chloride and hydrogen fluoride.

  16. Advanced Emission Control Development Program.

    SciTech Connect (OSTI)

    Evans, A.P.

    1997-12-31

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  17. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    M. J. Holmes

    1998-12-03

    McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using the Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and hydrogen chloride and hydrogen fluoride.

  18. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A. P. Evans

    1998-12-03

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W?s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  19. Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emission intensities and line ratios from a fast neutral helium beam J-W. Ahn a͒ Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA D. Craig, b͒ G. Fiksel, and D. J. Den Hartog Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA and Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, Madison, Wisconsin 53706, USA J. K. Anderson Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA M. G.

  20. Update on State Air Emission Regulations That Affect Electric Power Producers (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    Several states have recently enacted air emission regulations that will affect the electricity generation sector. The regulations are intended to improve air quality in the states and assist them in complying with the revised 1997 National Ambient Air Quality Standards (NAAQS) for ground-level ozone and fine particulates. The affected states include Connecticut, Massachusetts, Maine, Missouri, New Hampshire, New Jersey, New York, North Carolina, Oregon, Texas, and Washington. The regulations govern emissions of NOx, SO2, CO2, and mercury from power plants.

  1. Emissions

    Office of Scientific and Technical Information (OSTI)

    Emissions of Greenhouse Gases from the Use of Transportation Fuels and Electricity Volume 1: Main Text ::_:_ii_i!!._i_!!!i_!!_!_!i!ii_!).._i!iiii!!_i!i_!!_iii!i!_ii_iii!!_i!i!ii_!i!!_!!!_ii!!_)i!i_i_i!!ii!i!_!!ii!!i_!i_!iii_!!i!i_i!i!!_!ii_i!i._!ii_i!i!_i!_!!!i!!_!_!!_!_!!!!i_!_!!!i_:``.!ii!!_i_i_i!!!_!_!_ii_i_!_i_i_!!i!i!i!!!ii:!i_i!_ii!_!!ii_! ,qh_...dllri" :._m..41W..- ,,mm,m_ - Centerfor TransportationResearch Argonne NationalLaboratory Operated by lhe University of Chicago, under

  2. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-05_lu.pdf More Documents & Publications Advanced Metal Fiber Wall-Flow DPF For Diesel Emission Control Requirements from Particulate Filter Technology for Commercial Vehicles:

  3. Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction | Department of Energy the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-15_wei.pdf More Documents & Publications On-Road PM Mass Emission Measured with OBS-TRPM Investigation of Direct Injection Vehicle Particulate Matter

  4. New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER Conference Presentation: Corning Incorporated PDF icon 2003_deer_merkel.pdf More Documents & Publications 12TH DIESEL ENGINE-EFFICIENCY AND EMISSIONS RESEARCH CONFERENCE (DEER 2006) PRESENTATIONS Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by

  5. Optical backscatter probe for sensing particulate in a combustion gas stream

    DOE Patents [OSTI]

    Parks, James E; Partridge, William P

    2013-05-28

    A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

  6. Integrated emissions control system for residential CWS furnace. Final report, September 20, 1989--March 20, 1993

    SciTech Connect (OSTI)

    Breault, R.W.; McLarnon, C.

    1993-03-01

    One of the major obstacles to the successful development and commercialization of a coal-fired residential furnace is the need for a reliable, cost-effective emission control system. Tecogen is developing a novel, integrated control system to control NO{sub x}SO{sub 2}, and particulate emissions. At the heart of this system is a unique emissions control reactor for the control of SO{sub 2}. This reactor provides high sorbent particle residence time within the reactor while doing so in a very compact geometry. Final cleanup of any fine particulates exiting the reactor including respirable-sized particulates, is completed with the use of high efficiency bag filters. Under a previous contract with PETC (Contract No. DE-AC22-87PC79650), Tecogen developed a residential-scale Coal Water Slurry (CWS) combustor to control NO{sub x}emission. This combustor makes use of centrifugal forces, set up by a predominantly tangential flow field, to separate and confine larger unburned coal particles in the furnace upper chamber. Various partitions are used to retard the axial, downward flow of these particles, and thus maximize their residence time in the hottest section of the combustor. By operating this combustor under staged conditions, the local stoichiometry in the primary zone can be controlled in such a manner as to minimize NO{sub x} emission.

  7. A Standard Soot Generator for Diesel Particulate Filter Testing |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A Standard Soot Generator for Diesel Particulate Filter Testing A Standard Soot Generator for Diesel Particulate Filter Testing Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_nickolaus.pdf More Documents & Publications XP-SiC: An Innovative Substrate

  8. Improvement and Simplification of Diesel Particulate Filter System using a

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceria-Based Fuel-Borne Catalyst in Serial Applications | Department of Energy Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications Improvement and Simplification of Diesel Particulate Filter System using a Ceria-Based Fuel-Borne Catalyst in Serial Applications 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Rhodia Electronics and Catalysis PDF icon 2004_deer_macaudiere.pdf More Documents &

  9. Accelerated Extraction of Diesel Particulate Matter SOF | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Extraction of Diesel Particulate Matter SOF Accelerated Extraction of Diesel Particulate Matter SOF Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_lewis.pdf More Documents & Publications Chemical Analysis of Soot Using Thermal Desorption/Pyrolysis Gas

  10. Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Loading and Regeneration | Department of Energy Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon deer10_sappok.pdf More Documents & Publications Vehicle Technologies Office Merit

  11. Sandia Energy - Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of solid fuels such as coal and biomass. Recent research in the MFC has focused on char-NOx formation and reburn (Figure 2), NOx formation during oxy-fuel combustion of pulverized...

  12. Liquid additives for particulate emissions control

    DOE Patents [OSTI]

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Hyatt, David E.; Bustard, Cynthia Jean; Sjostrom, Sharon

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  13. Liquid additives for particulate emissions control

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1999-01-05

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  14. Evaluation of Gas, Oil and Wood Pellet Fueled Residential Heating System Emissions Characteristics

    SciTech Connect (OSTI)

    McDonald, R.

    2009-12-01

    This study has measured the emissions from a wide range of heating equipment burning different fuels including several liquid fuel options, utility supplied natural gas and wood pellet resources. The major effort was placed on generating a database for the mass emission rate of fine particulates (PM 2.5) for the various fuel types studied. The fine particulates or PM 2.5 (less than 2.5 microns in size) were measured using a dilution tunnel technique following the method described in US EPA CTM-039. The PM 2.5 emission results are expressed in several units for the benefit of scientists, engineers and administrators. The measurements of gaseous emissions of O{sub 2}, CO{sub 2}, CO, NO{sub x} and SO{sub 2} were made using a combustion analyzer based on electrochemical cells These measurements are presented for each of the residential heating systems tested. This analyzer also provides a steady state efficiency based on stack gas and temperature measurements and these values are included in the report. The gaseous results are within the ranges expected from prior emission studies with the enhancement of expanding these measurements to fuels not available to earlier researchers. Based on measured excess air levels and ultimate analysis of the fuel's chemical composition the gaseous emission results are as expected and fall within the range provided for emission factors contained in the US-EPA AP 42, Emission Factors Volume I, Fifth Edition. Since there were no unexpected findings in these gaseous measurements, the bulk of the report is centered on the emissions of fine particulates, or PM 2.5. The fine particulate (PM 2.5) results for the liquid fuel fired heating systems indicate a very strong linear relationship between the fine particulate emissions and the sulfur content of the liquid fuels being studied. This is illustrated by the plot contained in the first figure on the next page which clearly illustrates the linear relationship between the measured mass of fine particulate per unit of energy, expressed as milligrams per Mega-Joule (mg/MJ) versus the different sulfur contents of four different heating fuels. These were tested in a conventional cast iron boiler equipped with a flame retention head burner. The fuels included a typical ASTM No. 2 fuel oil with sulfur below 0.5 percent (1520 average ppm S), an ASTM No. 2 fuel oil with very high sulfur content (5780 ppm S), low sulfur heating oil (322 ppm S) and an ultra low sulfur diesel fuel (11 ppm S). Three additional oil-fired heating system types were also tested with normal heating fuel, low sulfur and ultralow sulfur fuel. They included an oil-fired warm air furnace of conventional design, a high efficiency condensing warm air furnace, a condensing hydronic boiler and the conventional hydronic boiler as discussed above. The linearity in the results was observed with all of the different oil-fired equipment types (as shown in the second figure on the next page). A linear regression of the data resulted in an Rsquared value of 0.99 indicating that a very good linear relationship exits. This means that as sulfur decreases the PM 2.5 emissions are reduced in a linear manner within the sulfur content range tested. At the ultra low sulfur level (15 ppm S) the amount of PM 2.5 had been reduced dramatically to an average of 0.043 mg/MJ. Three different gas-fired heating systems were tested. These included a conventional in-shot induced draft warm air furnace, an atmospheric fired hydronic boiler and a high efficiency hydronic boiler. The particulate (PM 2.5) measured ranged from 0.011 to 0.036 mg/MJ. depending on the raw material source used in their manufacture. All three stoves tested were fueled with premium (low ash) wood pellets obtained in a single batch to provide for uniformity in the test fuel. Unlike the oil and gas fired systems, the wood pellet stoves had measurable amounts of particulates sized above the 2.5-micron size that defines fine particulates (less than 2.5 microns). The fine particulate emissions rates ranged from 22 to 30 mg/ MJ with an average value

  15. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Scahill, John W. (Golden, CO)

    1986-01-01

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  16. Fluidizing device for solid particulates

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.

    1984-06-27

    A flexible whip or a system of whips with novel attachments is suspended in a hopper and is caused to impact against fibrous and irregularly shaped particulates in the hopper to fluidize the particulates and facilitate the flow of the particulates through the hopper. The invention provides for the flow of particulates at a substantially constant mass flow rate and uses a minimum of energy.

  17. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration...

  18. Advanced Particulate Filter Technologies for Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Advanced Particulate Filter Technologies for Direct Injection Gasoline Engine Applications Specific ...

  19. Evaluation of Passive and Active Soot Filters for Removal of Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from Diesel Engines | Department of Energy Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines 2002 DEER Conference Presentation: Cummins, Inc. PDF icon 2002_deer_bunting.pdf More Documents & Publications Exhaust Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Active Soot Filter Regeneration Development and Field

  20. Investigations of release phenomenon of volatile organic compounds and particulates from residual storage chip piles

    SciTech Connect (OSTI)

    Mohan, S.; Nagarkatti, M.

    1996-12-31

    This paper outlines the method for estimating Particulate Matter and Volatile Organic Compounds (VOCs) emissions from wood handling and storage operations at a pulp mill. Fugitive particulate matter emissions from wood handling and storage operations are due to material load/dropout operations, wind erosion from storage piles and vehicular traffic on paved roads. The particulate matter emissions are a function of a number of variables like windspeed, surface moisture content, material silt content, and number of days of precipitation. Literature review attributes VOC emissions to biological, microbiological, chemical, and physical processes occurring in wood material storage pile. The VOC emissions are from the surface of these piles and the VOC released during retrieval of chips from the pile. VOC emissions are based on the chip throughput, number of turnovers, moisture content and surface area of the pile. The emission factors with the requisite calculation methodology to be utilized for quantifying VOC emissions from chip piles has been discussed in this paper.

  1. Method for dispersing catalyst onto particulate material and product thereof

    DOE Patents [OSTI]

    Utz, Bruce R. (Pittsburgh, PA); Cugini, Anthony V. (Pittsburgh, PA)

    1992-01-01

    A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

  2. Void/particulate detector

    DOE Patents [OSTI]

    Claytor, T.N.; Karplus, H.B.

    1983-09-26

    Apparatus for detecting voids and particulates in a flowing stream of fluid contained in a pipe may comprise: (a) a transducer for transmitting an ultrasonic signal into the stream, coupled to the pipe at a first location; (b) a second transducer for detecting the through-transmission of said signal, coupled to the pipe at a second location; (c) a third transducer for detecting the back-scattering of said signal, coupled to the pipe at a third location, said third location being upstream from said first location; (d) circuit means for normalizing the back-scattered signal from said third transducer to the through-transmitted signal from said second transducer; which normalized signal provides a measure of the voids and particulates flowing past said first location.

  3. Rigid particulate matter sensor

    DOE Patents [OSTI]

    Hall, Matthew (Austin, TX)

    2011-02-22

    A sensor to detect particulate matter. The sensor includes a first rigid tube, a second rigid tube, a detection surface electrode, and a bias surface electrode. The second rigid tube is mounted substantially parallel to the first rigid tube. The detection surface electrode is disposed on an outer surface of the first rigid tube. The detection surface electrode is disposed to face the second rigid tube. The bias surface electrode is disposed on an outer surface of the second rigid tube. The bias surface electrode is disposed to face the detection surface electrode on the first rigid tube. An air gap exists between the detection surface electrode and the bias surface electrode to allow particulate matter within an exhaust stream to flow between the detection and bias surface electrodes.

  4. Regenerable particulate filter

    DOE Patents [OSTI]

    Stuecker, John N. (Albuquerque, NM); Cesarano, III, Joseph (Albuquerque, NM); Miller, James E. (Albuquerque, NM)

    2009-05-05

    A method of making a three-dimensional lattice structure, such as a filter used to remove particulates from a gas stream, where the physical lattice structure is designed utilizing software simulation from pre-defined mass transfer and flow characteristics and the designed lattice structure is fabricated using a free-form fabrication manufacturing technique, where the periodic lattice structure is comprised of individual geometric elements.

  5. Vehicle Emissions Review - 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Vehicle Emissions Review - 2011 Reviews regulatory requirements and general technology approaches for heavy- and light-duty vehicle emissions control - filter technology, new catalysts, NOx control, diesel oxidation catalysts, gasoline particulate filters PDF icon deer11_johnson.pdf More Documents & Publications Vehicle Emissions Review - 2012 Diesel Emission Control Review Review of Emerging Diesel Emissions and Control

  6. Active DPF for Off-Road Particulate Matter (PM) Control | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy DPF for Off-Road Particulate Matter (PM) Control Active DPF for Off-Road Particulate Matter (PM) Control This presentation details how a possibly catalyzed active diesel particulate filter can be used to control off-road particulate matter. PDF icon deer08_servati.pdf More Documents & Publications DPF for a Tractor Auxiliary Power Unit A Low-Cost Continuous Emissions Monitoring System for Mobile and Stationary Engine SCR/DPF Applications/Data-Logger for Vehicle Data Acquisition

  7. Monitoring and Control of Alkali Volatilization and Batch Carryover for Minimization of Particulates and Crown Corrosion

    SciTech Connect (OSTI)

    2001-01-01

    New Technology will Allow Glass Manufacturers to Optimize Furnace Conditions. Laser-induced breakdown spectroscopy is a continuous monitoring technique that glass manufacturers can use to reduce particulate matter emissions and extend furnace life.

  8. Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon | Department of Energy Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-14_strzelec.pdf More Documents & Publications Non-Petroleum-Based Fuels: Effects on Emissions Control Technologies Vehicle Technologies Office: 2010 Fuel

  9. Controlling formation fines at their sources to maintain well productivity

    SciTech Connect (OSTI)

    Nguyen, P.D.; Weaver, J.D.; Rickman, R.D.; Dusterhoft, R.G.; Parker, M.A.

    2007-05-15

    Migration of formation fines has been shown to cause production decline in many wells. Despite the availability of new downhole tools for use in well stimulation and completion, the ability to sustain desired production levels is often plagued with fines migration problems. The solution to this problem is appropriate treatment to mitigate fines migration at its source. This paper describes the use of an ultra-thin tackifying agent (UTTA) for stabilizing fines in high-rate producing or injection wells. This UTTA is applied as part of an initial prepad in fracturing or gravel-packing operations, as a remedial treatment, or as a post-treatment following acid fracturing or matrix acidizing treatments. The primary purpose of UTTA application is to immobilize formation fines so that they will not detach, migrate with flowing fluids, plug the pore channels, and reduce the flow path permeability. Results of laboratory testing indicate that the UTTA system is applicable to most types of formation fines, including coals, sandstones, and carbonates. Once injected into the formation matrix or proppant pack, the UTTA forms a thin film on formation surfaces, encapsulating the fines. Capillary action helps pull the tackifier into the contact points, fixing the particulate in place without plugging the pore throat. The UTTA does not require a shut-in time after its application. The thin film tackifier does not harden, but remains flexible, enhancing the ability of a formation to withstand stress cycling and allowing the formation to handle high shear stress during high flow rates.

  10. Advanced Ceramic Filter For Diesel Emission Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramic Filter For Diesel Emission Control Advanced Ceramic Filter For Diesel Emission Control 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Dow Automotive PDF icon 2004_deer_mao.pdf More Documents & Publications Vehicle Evaluation of Downsized Dow ACM DPF fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate Filters Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters

  11. Apparatus for particulate matter analysis

    DOE Patents [OSTI]

    Gundel, Lara A.; Apte, Michael G.; Hansen, Anthony D.; Black, Douglas R.

    2007-01-30

    The apparatus described herein is a miniaturized system for particle exposure assessment (MSPEA) for the quantitative measurement and qualitative identification of particulate content in gases. The present invention utilizes a quartz crystal microbalance (QCM) or other mass-sensitive temperature compensated acoustic wave resonator for mass measurement. Detectors and probes and light sources are used in combination for the qualitative determination of particulate matter.

  12. Enhanced control of fine particles following Title IV coal switching and NOx control

    SciTech Connect (OSTI)

    Durham, M.D.; Baldrey, K.E.; Bustard, C.J.; Martin, C.

    1997-12-31

    Electrostatic precipitators (ESPs) serve as the primary particle control devices for a majority of coal-fired power generating units in the United States. ESPs are used to collect particulate matter that range in size from less than one micrometer in diameter to several hundred micrometers. Many of the options that utilities will use to respond to Title IV of the 1990 Clean Air Act Amendments will result in changes to the ash that will be detrimental to the performance of the ESP causing increased emissions of fine particles and higher opacity. For example, a switch to low-sulfur coal significantly increases particle resistivity while low-NO{sub x} burners increase the carbon content of ashes. Both of these changes could result in derating of the boiler to comply with emissions standards. ADA has developed a chemical additive that is designed to improve the operation of ESI`s to bring these systems into compliance operation without the need for expensive capital modifications. The additives provide advantages over competing technologies in terms of low capital cost, easy to handle chemicals, and relatively non-toxic chemicals. In addition, the new additive is insensitive to ash chemistry which will allow the utility complete flexibility to select the most economical coal. Results from full-scale and pilot plant demonstrations are reported.

  13. Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and O2 emissions found from the thermogravimetric analyzer soot oxidation. PDF icon p-18lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration...

  14. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  15. Electrically heated particulate filter restart strategy

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-07-12

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a propagation module that estimates a propagation status of combustion of particulate matter in the particulate filter. A regeneration module controls current to the particulate filter to re-initiate regeneration based on the propagation status.

  16. Electrical diesel particulate filter (DPF) regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-12-31

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is disposed upstream of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  17. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  18. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Final report

    SciTech Connect (OSTI)

    Weber, G.F.; Dunham, G.E.; Laudal, D.L.; Ness, S.R.; Schelkoph, G.L.

    1994-08-01

    The overall objective of the project proposed was to evaluate the catalyst-coated fabric filter concept for effective control of NO{sub 2} and particulate emissions simultaneously. General goals included demonstrating high removal efficiency of NO{sub x} and particulate matter, acceptable bag and catalyst life, and that process economics show a significant cost savings in comparison to a commercial SCR process and conventional particulate control. Specific goals included the following: reduce NO{sub x} emissions to 60 ppM or less; demonstrate particulate removal efficiency of >99.5%; demonstrate a bag/catalyst life of >1 year; Control ammonia slip to <25 ppM; show that catalytic fabric filtration can achieve a 50% cost savings over conventional fabric filtration and SCR control technology; determine compatibility with S0{sub 2} removal systems; and show that the concept results in a nonhazardous waste product.

  19. Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Operations | Department of Energy Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations Particulate Matter Characteristics for Highly Dilute Stoichiometric GDI Engine Operations The overall goal of this study is to help identify which conditions and potential mechanisms impede soot formation in GDI operations. PDF icon p-24_storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion

  20. Development of an Accelerated Ash-Loading Protocol for Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_bunting_2.pdf More Documents & Publications

  1. Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Traps | Department of Energy Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate Traps Burning Modes and Oxidation Rates of Soot: Relevance to Diesel Particulate Traps Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_vanderwal.pdf More Documents &

  2. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect (OSTI)

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  3. Pelletization of fine coals

    SciTech Connect (OSTI)

    Sastry, K.V.S.

    1991-09-01

    The present research project attempts to provide a basis to determine the pelletizability of fine coals, to ascertain the role of additives and binders and to establish a basis for binder selection. Currently, there are no established techniques for determining the quality of coal pellets. Our research is intended to develop a series of tests on coal pellets to measure their storage characteristics, transportability, ease of gasification and rate of combustion. Information developed from this research should be valuable for making knowledgeable decisions for on-time plant design, occasional binder selection and frequent process control during the pelletization of coal fines. During the last quarter, we continued the batch pelletization studies on Upper Freeport coal. The results as presented in that last quarterly report (April 1991) indicated that the surface conditions on the coal particle influenced the pelletizing growth rates. For example, a fresh (run of mine) sample of coal will display different pelletizing growth kinetics than a weathered sample of the same coal. Since coal is a heterogeneous material, the oxidized product of coal is equally variable. We found it to be logistically difficult to consistently produce large quantities of artificially oxidized coal for experimental purposes and as such we have used a naturally weathered coal. We have plans to oxidize coals under controlled oxidizing conditions and be able to establish their pelletizing behavior. The next phase of experiments were directed to study the effect of surface modification, introduced during the coal cleaning steps, on pelletizing kinetics. Accordingly, we initiated studies with two additives commonly used during the flotation of coal: dextrin (coal depressant) and dodecane (coal collector).

  4. Method for the Removal of Ultrafine Particulates from an Aqueous Suspension

    SciTech Connect (OSTI)

    Chaiko, David J.; Kopasz, John P.; Ellison, Adam J.G.

    1999-03-05

    A method of separating ultra-fine particulate from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel-containing the particulate, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

  5. Method for the removal of ultrafine particulates from an aqueous suspension

    DOE Patents [OSTI]

    Chaiko, David J. (Naperville, IL); Kopasz, John P. (Bolingbrook, IL); Ellison, Adam J. G. (Corning, NY)

    2000-01-01

    A method of separating ultra-fine particulates from an aqueous suspension such as a process stream or a waste stream. The method involves the addition of alkali silicate and an organic gelling agent to a volume of liquid, from the respective process or waste stream, to form a gel. The gel then undergoes syneresis to remove water and soluble salts from the gel containing the particulates, thus, forming a silica monolith. The silica monolith is then sintered to form a hard, nonporous waste form.

  6. Continuous fine ash depressurization system

    DOE Patents [OSTI]

    Liu, Guohai (Birmingham, AL); Peng, Wan Wang (Birmingham, AL); Vimalchand, Pannalal (Birmingham, AL)

    2011-11-29

    A system for depressurizing and cooling a high pressure, high temperature fine solid particles stream having entrained gas therein. In one aspect, the system has an apparatus for cooling the high pressure, high temperature fine solid particles stream having entrained gas therein and a pressure letdown device for depressurization by separating the cooled fine solid particles from a portion of the fine solid particles stream having entrained gas therein, resulting in a lower temperature, lower pressure outlet of solid particles for disposal or handling by downstream equipment.

  7. Comparison of Particulate Collection in Probes and on Filters

    SciTech Connect (OSTI)

    Eaton, J.M.; Humphreys, M.P.

    2001-06-14

    Major radionuclide emissions from the Department of Energy's Y-12 National Security Complex are nuclides of uranium which are emitted as a particulate. The radionuclide NESHAP regulation requires stack sampling to be conducted in accordance with ANST Standard N13.1, 1969. Appendix B of this standard requires in every case where sampling delivery lines are used that an evaluation should be made of deposition in these lines. A number of Y-12 Complex stacks are fitted with continuous samplers which draw particulate laden air through a probe and across a sample filter. One approach to evaluate line loss as required by the ANSI standard is to establish a representative factor that is used for all subsequent sampling efforts. Another approach is to conduct a routine probe wash procedure on an ongoing basis to account for line losses. In 1991, Y-12 National Security Complex personnel began routine probe washes as part of their sample collection procedure. Since then, 50-80 stacks have been sampled on a near continuous basis and probe washes have been conducted quarterly. Particulate collection in probes versus particulate collection on filters is recorded as a probe factor and probe factor trends for a 10-year period are available.

  8. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for LIght-Duty Diesel Vehicles | Department of Energy Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles PDF icon 2005_deer_anderson.pdf More Documents & Publications Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency

  9. Particulate Generation in Tritium Systems

    Office of Environmental Management (EM)

    Particulate Generation in a Tritium System Paul Cloessner, PhD Laboratory Fellow Tritium Focus Group February 22, 2014 Outline * Description of Events * Analysis of Material * Sources of material contamination * System Restoration/Modifications * Contaminant Minimization and Control * Lessons Learned 2 An Unpleasant Surprise * Let down filter on compressor became plugged after 10 years of operation. * Tritium processing interrupted when other filters (flow orifices) became plugged approximately

  10. Hot Gas Filtration of Fine and Ultra fine Particles with Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic ...

  11. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of internal combustion engine vehicles. These vehicles can run on gasoline, diesel, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs) particulate matter (PM) A

  12. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    SciTech Connect (OSTI)

    McMeeking, Gavin R.; Kreidenweis, Sonia M.; Baker, Stephen; Carrico, Christian M.; Chow, Judith C.; Collett, Jr., Jeffrey L.; Hao, Wei Min; Holden, Amanda S.; Kirchstetter, Thomas W.; Malm, William C.; Moosmuller, Hans; Sullivan, Amy P.; Wold, Cyle E.

    2009-05-15

    We characterized the gas- and speciated aerosol-phase emissions from the open combustion of 33 different plant species during a series of 255 controlled laboratory burns during the Fire Laboratory at Missoula Experiments (FLAME). The plant species we tested were chosen to improve the existing database for U.S. domestic fuels: laboratory-based emission factors have not previously been reported for many commonly-burned species that are frequently consumed by fires near populated regions and protected scenic areas. The plants we tested included the chaparral species chamise, manzanita, and ceanothus, and species common to the southeastern US (common reed, hickory, kudzu, needlegrass rush, rhododendron, cord grass, sawgrass, titi, and wax myrtle). Fire-integrated emission factors for gas-phase CO{sub 2}, CO, CH{sub 4}, C{sub 2-4} hydrocarbons, NH{sub 3}, SO{sub 2}, NO, NO{sub 2}, HNO{sub 3} and particle-phase organic carbon (OC), elemental carbon (EC), SO{sub 4}{sup 2-}, NO{sub 3}{sup -}, Cl{sup -}, Na{sup +}, K{sup +}, and NH{sub 4}{sup +} generally varied with both fuel type and with the fire-integrated modified combustion efficiency (MCE), a measure of the relative importance of flaming- and smoldering-phase combustion to the total emissions during the burn. Chaparral fuels tended to emit less particulate OC per unit mass of dry fuel than did other fuel types, whereas southeastern species had some of the largest observed EF for total fine particulate matter. Our measurements often spanned a larger range of MCE than prior studies, and thus help to improve estimates for individual fuels of the variation of emissions with combustion conditions.

  13. Advanced emissions control development program. Quarterly technical progress report No. 9, October 1--December 31, 1996

    SciTech Connect (OSTI)

    Evans, A.P.

    1996-12-31

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U.S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emission compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emission control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  14. Diesel particulate filter with zoned resistive heater

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-03-08

    A diesel particulate filter assembly comprises a diesel particulate filter (DPF) and a heater assembly. The DPF filters a particulate from exhaust produced by an engine. The heater assembly has a first metallic layer that is applied to the DPF, a resistive layer that is applied to the first metallic layer, and a second metallic layer that is applied to the resistive layer. The second metallic layer is etched to form a plurality of zones.

  15. Zone heated diesel particulate filter electrical connection

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-03-30

    An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

  16. Trends in Particulate Nanostructure | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Nanostructure Trends in Particulate Nanostructure This work attempts to explain the differences in the physical characteristics (nanostructure) of the soot across platforms, heavy-duty and light-duty, and biodiesel blend level. PDF icon p-10_strzelec.pdf More Documents & Publications Investigation of NO2 Oxidation Kinetics and Burning Mode for Medium Duty Diesel Particulate: Contrasting O2 and NO2 Oxidation Load Expansion with Diesel/Gasoline RCCI for Improved Engine Efficiency

  17. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Durability of Diesel Engine Particulate Filters High Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the...

  18. Electrically-Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon pm041lance2011p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel...

  19. Electrically heated particulate filter embedded heater design

    DOE Patents [OSTI]

    Gonze, Eugene V.; Chapman, Mark R.

    2014-07-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine and wherein an upstream surface of the particulate filter includes machined grooves. A grid of electrically resistive material is inserted into the machined grooves of the exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  20. Electrically heated particulate filter using catalyst striping

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J; Ament, Frank

    2013-07-16

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating is applied to the PF that increases a temperature of the combustion of the particulates within the PF.

  1. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  2. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  3. Preserving Diesel Exhaust Ultrafine (Nano-) Particulate Structure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Dispersion in a Phospholipid Lung Surfactant In Vitro Genotoxicity of Gasoline and Diesel Engine Vehicle Exhaust Particulate and Semi-Volatile Organic Compound Materials

  4. Advanced Metal Fiber Wall-Flow DPF For Diesel Emission Control | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Metal Fiber Wall-Flow DPF For Diesel Emission Control Advanced Metal Fiber Wall-Flow DPF For Diesel Emission Control A new metal fiber wall-flow DPF with up to 99% efficiency and lower back pressure PDF icon deer09_lu.pdf More Documents & Publications Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Pleated Ceramic Fiber Diesel Particulate Filter Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece

  5. Engine gaseous, aerosol precursor and particulate at simulated flight altitude conditions. Technical memo

    SciTech Connect (OSTI)

    Wey, C.C.

    1998-10-01

    The overall objective of the NASA Atmospheric Effects of Aviation Project (AEAP) is to develop scientific bases for assessing atmospheric impacts of the exhaust emissions by both current and future fleets of subsonic and supersonic aircraft. Among the six primary elements of the AEAP is Emissions Characterization. The objective of the Emission Characterization effort is to determine the exhaust emission constituents and concentrations at the engine exit plane. The specific objective of this engine test is to obtain a database of gaseous and particulate emissions as a function of fuel sulfur and engine operating conditions. The database of the particulate emission properties is to be used as a comparative baseline with subsequent flight measurement. The engine used in this test was a Pratt and Whitney F100-200E turbofan engine. Aviation fuel (Jet A) with a range of fuel sulfur was used. Low and high sulfur values are limited by commercially available fuels and by fuel specification limits of 0.3% by weight. Test matrix was set by parametrically varying the combustor inlet temperature (T3) between idle and maximum power setting at simulated SLS and up to five other altitudes for each fuel. Four diagnostic systems, extractive and non-intrusive, were assembled for the gaseous and particulate emissions characterization measurements study. NASA extractive system includes smoke meter and analyzers for measurement of CO, CO{sub 2}, NO, NOx, O{sub 2}, total unburnt hydrocarbons (THC), and SO{sub 2}. Particulate emissions were characterized by University of Missouri-Rolla Mobile Aerosol Sampling System.

  6. Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Filter Technology for Low-Temperature and Low-NOx/PM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM Applications 2004 DEER Conference Presentation: Johnson-Matthey Catalysts PDF icon 2004_deer_chatterjee.pdf More Documents & Publications Performance of Johnson Matthey EGRT’ Emission Control System for NOx and PM Emission Reduction in Retrofit Applications Part 1 Aftertreatment Modeling Status, Futur Potential, and

  7. A Study of Emissions from a Light Duty Diesel Engine with the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Study of Emissions from a Light Duty Diesel Engine with the European Particulate Measurement Programme A Study of Emissions from a Light Duty Diesel Engine with the European ...

  8. On-Road PM Mass Emission Measured with OBS-TRPM | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PM Mass Emission Measured with OBS-TRPM On-Road PM Mass Emission Measured with OBS-TRPM Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-14_wei.pdf More Documents & Publications Performance of the Low-Efficiency Diesel Particulate Filter for Diesel PM Reduction Investigation of Direct Injection Vehicle Particulate Matter Emissions A High Temperature Direct Vehicle Exhaust Flowmeter for

  9. Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Particulate Emissions Control by Advanced Filtration Systems or GDI Engines

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  11. Fuel-Neutral Studies of Particulate Matter Transport Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace056stewart2012o.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline ...

  12. Electrically heated particulate filter propagation support methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-06-07

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate combustion of particulate matter in the particulate filter. A propagation module estimates a propagation status of the combustion of the particulate matter based on a combustion temperature. A temperature adjustment module controls the combustion temperature by selectively increasing a temperature of exhaust that passes through the particulate filter.

  13. Active Diesel Emission Control Technology for Sub-50 HP Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon deer08depetrillo.pdf More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine 2005deerdePetrillo.pdf Active Diesel Emission ...

  14. Radiant zone heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-12-27

    A system includes a particulate matter (PM) filter including an upstream end for receiving exhaust gas and a downstream end. A radiant zoned heater includes N zones, where N is an integer greater than one, wherein each of the N zones includes M sub-zones, where M is an integer greater than or equal to one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones, restricts exhaust gas flow in a portion of the PM filter that corresponds to the selected one of the N zones, and deactivates non-selected ones of the N zones.

  15. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) PDF icon ace22lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration...

  16. Mesoscale Simulations of Particulate Flows with Parallel Distributed...

    Office of Scientific and Technical Information (OSTI)

    Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. ...

  17. A New CFD Model for understanding and Managing Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon...

  18. New Cordierite Diesel Particulate Filters for Catalyzed and Non...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications 2003 DEER...

  19. Durability of Diesel Particulate Filters - Bench Studies on Cordierite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August...

  20. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine...

  1. Reduction of Transient Particulate Matter Spikes with Decision...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric ...

  2. Failure Stress and Apparent Elastic Modulus of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Three...

  3. Characterization of Pre-Commercial Gasoline Engine Particulates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol Methods...

  4. Local Soot Loading Distribution in Cordierite Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by...

  5. Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_depetrillo.pdf More Documents & Publications Active Diesel Emission Control Technology for Sub-50 HP Engines with Low Exhaust Temperature Profiles

  6. Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Emission Control | Department of Energy Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control Fuel Formulation Effects on Diesel Fuel Injection, Combustion, Emissions and Emission Control 2003 DEER Conference Presentation: The Pennsylvania State University PDF icon 2003_deer_boehman.pdf More Documents & Publications Fuel Impacts on Soot Nanostructure and Reactivity Effect of Alternative Fuels on Soot Properties and Regeneration of Diesel Particulate

  7. Electrically heated particulate filter enhanced ignition strategy

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2012-10-23

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating applied to at least one of the PF and the grid. A control module estimates a temperature of the grid and controls the engine to produce a desired exhaust product to increase the temperature of the grid.

  8. Compressive behavior of fine sand.

    SciTech Connect (OSTI)

    Martin, Bradley E.; Kabir, Md. E.; Song, Bo; Chen, Wayne

    2010-04-01

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  9. Considerations for modeling small-particulate impacts from surface coal-mining operations based on wind-tunnel simulations

    SciTech Connect (OSTI)

    Perry, S.G.; Petersen, W.B.; Thompson, R.S.

    1994-12-31

    The Clean Air Act Amendments of 1990 provide for a reexamination of the current Environmental Protection Agency`s (USEPA) methods for modeling fugitive particulate (PM10) from open-pit, surface coal mines. The Industrial Source Complex Model (ISCST2) is specifically named as the method that needs further study. Title II, Part B, Section 234 of the Amendments states that {open_quotes}...the Administrator shall analyze the accuracy of such model and emission factors and make revisions as may be necessary to eliminate any significant over-predictions of air quality effect of fugitive particulate emissions from such sources.{close_quotes}

  10. Dense, finely, grained composite materials

    DOE Patents [OSTI]

    Dunmead, Stephen D. (Davis, CA); Holt, Joseph B. (San Jose, CA); Kingman, Donald D. (Danville, CA); Munir, Zuhair A. (Davis, CA)

    1990-01-01

    Dense, finely grained composite materials comprising one or more ceramic phase or phase and one or more metallic and/or intermetallic phase or phases are produced by combustion synthesis. Spherical ceramic grains are homogeneously dispersed within the matrix. Methods are provided, which include the step of applying mechanical pressure during or immediately after ignition, by which the microstructures in the resulting composites can be controllably selected.

  11. Aqueour biphase extraction for processing of fine coal

    SciTech Connect (OSTI)

    Osseo-Asare, K.

    1997-07-23

    Ever-stringent environmental constraints dictate that future coal cleaning technologies be compatible with micron-size particles. For super-clean coal production, the degree of liberation needed to separate coal from mineral matter, including pyrite, requires grinding to 10 mm or below. In addition, large amounts of fine coal are discharged to refuse ponds because current coal cleaning technology cannot adequately treat such finely divided materials. This research program seeks to develop an advanced coal cleaning technology uniquely suited to micron-size particles, i.e., aqueous biphase extraction. This technique relies on the ability of an aqueous system consisting of a water-soluble organic polymer and an inorganic metal salt to separate into two immiscible aqueous phases. Differences in the hydrophobic/hydrophilic properties of particulates can then be exploited to effect selective transfers to either the upper polymer-rich phase, or the lower salt-rich phase. An experimental program is proposed involving phase diagram determination, phase separation rate measurements, partition measurements, and washing experiments.

  12. Neutron Imaging of Diesel Particulate Filters | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Particulate Filters Neutron Imaging of Diesel Particulate Filters Neutron computed tomography shows soot and ash loading in a cordierite diesel particulate filter PDF icon deer09_bilheux.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters

  13. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  14. Method of producing particulate-reinforced composites and composties produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2013-12-24

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intenisty acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaciton products comprise a solide particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particles-reinforced composite materials produced by such a process.

  15. Method of producing particulate-reinforced composites and composites produced thereby

    DOE Patents [OSTI]

    Han, Qingyou; Liu, Zhiwei

    2015-12-29

    A process for producing particle-reinforced composite materials through utilization of an in situ reaction to produce a uniform dispersion of a fine particulate reinforcement phase. The process includes forming a melt of a first material, and then introducing particles of a second material into the melt and subjecting the melt to high-intensity acoustic vibration. A chemical reaction initiates between the first and second materials to produce reaction products in the melt. The reaction products comprise a solid particulate phase, and the high-intensity acoustic vibration fragments and/or separates the reaction products into solid particles that are dispersed in the melt and are smaller than the particles of the second material. Also encompassed are particle-reinforced composite materials produced by such a process.

  16. Expanded Capacity Microwave-Cleaned Diesel Particulate Filter | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Expanded Capacity Microwave-Cleaned Diesel Particulate Filter Expanded Capacity Microwave-Cleaned Diesel Particulate Filter 2002 DEER Conference Presentation: Industrial Ceramic Solutions, LLC PDF icon 2002_deer_nixdorf.pdf More Documents & Publications Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Pleated Ceramic Fiber Diesel Particulate Filter Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape

  17. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  18. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  19. Electric power plant emissions and public health

    SciTech Connect (OSTI)

    O'Connor, A.B.; Roy, C.

    2008-02-15

    The generation of electric power is one important source of pollutants such as mercury, sulfur dioxide, nitrogen oxides, and fine particulate matter that can affect the respiratory, cardiovascular, and central nervous systems and cause pregnancy complications. But protecting people from environmental health hazards has become increasingly complex. Air pollutants are often invisible and travel many miles virtually undetected. Nurses can play a critical role in preventive strategies, as well as in the national debate on energy production and dependence on fossil fuels.

  20. Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration Effects of Diesel Exhaust Emissions on Soot Oxidation and DPF Regeneration DPF regeneration experiments verified the effects of NO2 and O2 emissions found from the thermogravimetric analyzer soot oxidation. PDF icon p-18_lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) Development of Advanced Particulate Filters

  1. Particulate matter pollution in Mexico City

    SciTech Connect (OSTI)

    Vega R, E.; Mora P, V.; Mugica A, V.

    1998-12-31

    The levels of particulate matter are of concern since they may induce severe effects on public health and is the second atmospheric pollution problem in Mexico City. Another noticeable effect in large cities attributable to particulate matter, is the deterioration of visibility. In this paper the analysis of the data of TSP and PM10 during 1988 to 1996 is presented. The seasonal variation of particulate matter, the typical ratios of PM10/TSP and relationships of the two variables were determined. It was found that PM10 concentrations show an important tendency to decrease during this period, due to some control strategies, although this is not the case for TSP. The monthly trend exhibits a clear relationship with the dry (October through April) and wet (May through September) seasons. The particulate matter concentrations are lower during the wet season. The hourly behavior shows that the highest concentrations are correlated with the traffic rush hours. The most TSP polluted area was the northeast, meanwhile the southeast is the most PM10 polluted area. There is a clear evidence of the particulate matter transportation from these areas to other sites of the City.

  2. Advanced Emissions Control Development Program. Quarterly Technical Progress Report {number_sign}7 for the period: April 1 to June 30, 1996

    SciTech Connect (OSTI)

    Evans, A.P.

    1996-12-31

    Babcock {ampersand} Wilcox (B{ampersand}W) is conducting a five-year project aimed at the development of practical, cost- effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B{ampersand}W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  3. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  4. ROTARY FILTER FINES TESTING FOR SMALL COLUMN ION EXCHANGE

    SciTech Connect (OSTI)

    Herman, D.

    2011-08-03

    SRNL was requested to quantify the amount of 'fines passage' through the 0.5 micron membranes currently used for the rotary microfilter (RMF). Testing was also completed to determine if there is any additional benefit to utilizing a 0.1 micron filter to reduce the amount of fines that could pass through the filter. Quantifying of the amount of fines that passed through the two sets of membranes that were tested was accomplished by analyzing the filtrate by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) for titanium. Even with preparations to isolate the titanium, all samples returned results of less than the instrument's detection limit of 0.184 mg/L. Test results show that the 0.5 micron filters produced a significantly higher flux while showing a negligible difference in filtrate clarity measured by turbidity. The first targeted deployment of the RMF is with the Small Column Ion Exchange (SCIX) at the Savannah River Site (SRS). SCIX uses crystalline silicotitanate (CST) to sorb cesium to decontaminate a clarified salt solution. The passage of fine particles through the filter membranes in sufficient quantities has the potential to impact the downstream facilities. To determine the amount of fines passage, a contract was established with SpinTek Filtration to operate a 3-disk pilot scale unit with prototypic filter disk and various feeds and two different filter disk membranes. SpinTek evaluated a set of the baseline 0.5 micron filter disks as well as a set of 0.1 micron filter disks to determine the amount of fine particles that would pass the membrane and to determine the flux each set produced. The membrane on both disk sets is manufactured by the Pall Corporation (PMM 050). Each set of disks was run with three feed combinations: prototypically ground CST, CST plus monosodium titanate (MST), and CST, MST, plus Sludge Batch 6 (SB6) simulant. Throughout the testing, samples of the filtrate were collected, measured for turbidity, and sent back to SRNL for analysis to quantify the amount of fines that passed through the membrane. It should be noted that even though ground CST was tested, it will be transferred to the Defense Waste Processing Facility (DWPF) feed tank and is not expected to require filtration.

  5. Method of dispersing particulate aerosol tracer

    DOE Patents [OSTI]

    O'Holleran, Thomas P. (Belleville, MI)

    1988-01-01

    A particulate aerosol tracer which comprises a particulate carrier of sheet silicate composition having a particle size up to one micron, and a cationic dopant chemically absorbed in solid solution in the carrier. The carrier is preferably selected from the group consisting of natural mineral clays such as bentonite, and the dopant is selected from the group consisting of rare earth elements and transition elements. The tracers are dispersed by forming an aqueous salt solution with the dopant present as cations, dispersing the carriers in the solution, and then atomizing the solution under heat sufficient to superheat the solution droplets at a level sufficient to prevent reagglomeration of the carrier particles.

  6. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  7. Particulate matter sensor with a heater

    DOE Patents [OSTI]

    Hall, Matthew (Austin, TX)

    2011-08-16

    An apparatus to detect particulate matter. The apparatus includes a sensor electrode, a shroud, and a heater. The electrode measures a chemical composition within an exhaust stream. The shroud surrounds at least a portion of the sensor electrode, exclusive of a distal end of the sensor electrode exposed to the exhaust stream. The shroud defines an air gap between the sensor electrode and the shroud and an opening toward the distal end of the sensor electrode. The heater is mounted relative to the sensor electrode. The heater burns off particulate matter in the air gap between the sensor electrode and the shroud.

  8. Fine structure on the green band in ZnO

    SciTech Connect (OSTI)

    Reynolds, D. C.; Look, D. C.; Jogai, B.

    2001-06-01

    An emission band at 2.4 eV, called the green band, is observed in most ZnO samples, no matter what growth technique is used. Sometimes this band includes fine structure, which consists mainly of doublets, repeated with a longitudinal-optical-phonon-energy spacing (72 meV). We have developed a vibronic model for the green band, based on transitions from two separate shallow donors to a deep acceptor. The donors, at energies 30 and 60 meV from the conduction-band edge, respectively, are also found from Hall-effect measurements. {copyright} 2001 American Institute of Physics.

  9. Advanced emissions control development program. Quarterly technical progress report {number_sign}4, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Farthing, G.A.

    1995-12-31

    Babcock and Wilcox (B and W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls will likely arise as the US Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendments of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B and W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF will provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. The specific objectives of the project are to: (1) measure and understand the production and partitioning of air toxics species for a variety of steam coals, (2) optimize the air toxics removal performance of conventional flue gas cleanup systems (ESPs, baghouses, scrubbers), (3) develop advanced air toxics emissions control concepts, (4) develop and validate air toxics emissions measurement and monitoring techniques, and (5) establish a comprehensive, self-consistent air toxics data library. Development work is currently concentrated on the capture of mercury, fine particulate, and a variety of inorganic species such as the acid gases (hydrogen chloride, hydrogen fluoride, etc.).

  10. Reducing the negative human-health impacts of bioenergy crop emissions through region-specific crop selection

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Porter, William C.; Rosenstiel, Todd N.; Guenther, Alex; Lamarque, Jean-Francois; Barsanti, Kelley

    2015-05-06

    An expected global increase in bioenergy-crop cultivation as an alternative to fossil fuels will have consequences on both global climate and local air quality through changes in biogenic emissions of volatile organic compounds (VOCs). While greenhouse gas emissions may be reduced through the substitution of next-generation bioenergy crops such as eucalyptus, giant reed, and switchgrass for fossil fuels, the choice of species has important ramifications for human health, potentially reducing the benefits of conversion due to increases in ozone (O₃) and fine particulate matter (PM₂̣₅) levels as a result of large changes in biogenic emissions. Using the Community Earth Systemmore » Model we simulate the conversion of marginal and underutilized croplands worldwide to bioenergy crops under varying future anthropogenic emissions scenarios. A conservative global replacement using high VOC-emitting crop profiles leads to modeled population-weighted O₃ increases of 5–27 ppb in India, 1–9 ppb in China, and 1–6 ppb in the United States, with peak PM₂̣₅ increases of up to 2 μgm⁻³. We present a metric for the regional evaluation of candidate bioenergy crops, as well as results for the application of this metric to four representative emissions profiles using four replacement scales (10–100% maximum estimated available land). Finally, we assess the total health and climate impacts of biogenic emissions, finding that the negative consequences of using high-emitting crops could exceed 50% of the positive benefits of reduced fossil fuel emissions in value.« less

  11. Systems and methods for controlling diesel engine emissions

    DOE Patents [OSTI]

    Webb, Cynthia Chaffin; Weber, Phillip Anthony; Khair, Magdi K.

    2004-06-01

    Systems and methods for controlling diesel engine emissions, including, for example, oxides of nitrogen emissions, particulate matter emissions, and the like. The emission control system according to this invention is provided in the exhaust passageway of a diesel engine and includes a catalyst-based particulate filter; and first and second lean NO.sub.x trap systems coupled to the catalyst-based particulate filter. The first and second lean NO.sub.x trap systems are arranged in a parallel flow configuration with each other. Each of the first and second lean NO.sub.x trap systems include a carbon monoxide generating catalyst device, a sulfur trap device, a lean NO.sub.x device, a supplemental fuel injector device, and a plurality of flow diverter devices.

  12. Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Partial-Flow Diesel Particulate Filter of Sintered Metal Fiber Fleece Poster presented at the 16th Directions ...

  13. Expanded Capacity Microwave-Cleaned Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEER Conference Presentation: Industrial Ceramic Solutions, LLC PDF icon ... Time and Fuel Consumption Pleated Ceramic Fiber Diesel Particulate Filter Versatile ...

  14. Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Ultra-Lite Diesel Particulate Filter Cartridge for Reduced

  15. Particulate Generation in a Tritium System | Department of Energy

    Office of Environmental Management (EM)

    Particulate Generation in a Tritium System Particulate Generation in a Tritium System Presentation from the 33rd Tritium Focus Group Meeting held in Aiken, South Carolina on April 22-24, 2014. PDF icon Particulate Generation in a Tritium System More Documents & Publications Fuel Injector Holes Fuel Injector Holes Fuel injector Holes (Fabrication of Micro-Orifices for Fuel Injectors)

  16. Electrically heated particulate filter preparation methods and systems

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31

    A control system that controls regeneration of a particulate filter is provided. The system generally includes a fuel control module that controls injection of fuel into exhaust that passes through the particulate filter. A regeneration module controls current to the particulate filter to initiate regeneration after the fuel has been injected into the exhaust.

  17. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ANL/Corning/Caterpillar CRADA) | Department of Energy (ANL/Corning/Caterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) PDF icon ace_22_lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems

  18. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024_lee_2011_o.pdf More Documents & Publications Development of Advanced Particulate Filters Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA)

  19. Electrically-Assisted Diesel Particulate Filter Regeneration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon pm041_lance_2012_o.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Electrically-Assisted Diesel Particulate Filter Regeneration Durability of Diesel Engine Particulate Filters (Agreement ID:10461)

  20. Transportable Emissions Testing Laboratory for Alternative Vehicles Emissions Testing

    SciTech Connect (OSTI)

    Clark, Nigel

    2012-01-31

    The overall objective of this project was to perform research to quantify and improve the energy efficiency and the exhaust emissions reduction from advanced technology vehicles using clean, renewable and alternative fuels. Advanced vehicle and alternative fuel fleets were to be identified, and selected vehicles characterized for emissions and efficiency. Target vehicles were to include transit buses, school buses, vocational trucks, delivery trucks, and tractor-trailers. Gaseous species measured were to include carbon monoxide, carbon dioxide, oxides of nitrogen, hydrocarbons, and particulate matter. An objective was to characterize particulate matter more deeply than by mass. Accurate characterization of efficiency and emissions was to be accomplished using a state-of-the-art portable emissions measurement system and an accompanying chassis dynamometer available at West Virginia University. These two units, combined, are termed the Transportable Laboratory. An objective was to load the vehicles in a real-world fashion, using coast down data to establish rolling resistance and wind drag, and to apply the coast down data to the dynamometer control. Test schedules created from actual vehicle operation were to be employed, and a specific objective of the research was to assess the effect of choosing a test schedule which the subject vehicle either cannot follow or can substantially outperform. In addition the vehicle loading objective was to be met better with an improved flywheel system.

  1. Measurements of particulate matter concentrations at a landfill site (Crete, Greece)

    SciTech Connect (OSTI)

    Chalvatzaki, E.; Kopanakis, I.; Kontaksakis, M.; Glytsos, T.; Kalogerakis, N.; Lazaridis, M.

    2010-11-15

    Large amounts of solid waste are disposed in landfills and the potential of particulate matter (PM) emissions into the atmosphere is significant. Particulate matter emissions in landfills are the result of resuspension from the disposed waste and other activities such as mechanical recycling and composting, waste unloading and sorting, the process of coating residues and waste transport by trucks. Measurements of ambient levels of inhalable particulate matter (PM{sub 10}) were performed in a landfill site located at Chania (Crete, Greece). Elevated PM{sub 10} concentrations were measured in the landfill site during several landfill operations. It was observed that the meteorological conditions (mainly wind velocity and temperature) influence considerably the PM{sub 10} concentrations. Comparison between the PM{sub 10} concentrations at the landfill and at a PM{sub 10} background site indicates the influence of the landfill activities on local concentrations at the landfill. No correlation was observed between the measurements at the landfill and the background sites. Finally, specific preventing measures are proposed to control the PM concentrations in landfills.

  2. Source apportionment of particulate matter in the US and associations with lung inflammatory markers

    SciTech Connect (OSTI)

    Duvall, R.M.; Norris, G.A.; Dailey, L.A.; Burke, J.M.; McGee, J.K.; Gilmour, M.I.; Gordon, T.; Devlin, R.B.

    2008-07-01

    Size-fractionated particulate matter (PM) samples were collected from six U.S. cities and chemically analyzed as part of the Multiple Air Pollutant Study. Particles were administered to cultured lung cells and the production of three different proinflammatory markers was measured to explore the association between the health effect markers and PM. Ultrafine, fine, and coarse PM samples were collected between December 2003 and May 2004 over a 4-wk period in each city. Filters were pooled for each city and the PM samples were extracted then analyzed for trace metals, ions, and elemental carbon. Particle extracts were applied to cultured human primary airway epithelial cells, and the secreted levels of interleukin-8 (IL-8), heme oxygenase-1, and cyclooxygenase-2 were measured 1 and 24 h following exposure. Fine PM sources were quantified by the chemical mass balance (CMB) model. The relationship between toxicological measures, PM sources, and individual species were evaluated using linear regression. Ultrafine and fine PM mass were associated with increases in IL-8 (r{sup 2} = .80 for ultrafine and r{sup 2} = .52 for fine). Sources of fine PM and their relative contributions varied across the sampling sites and a strong linear association was observed between IL-8 and secondary sulfate from coal combustion (r{sup 2} = .79). Ultrafine vanadium, lead, copper, and sulfate were also associated with increases in IL-8. Increases in inflammatory markers were not observed for coarse PM mass and source markers. These findings suggest that certain PM size fractions and sources are associated with markers of lung injury or inflammation.

  3. Optimization of an Advanced Passive/Active Diesel Emission Control System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Advanced Passive/Active Diesel Emission Control System Optimization of an Advanced Passive/Active Diesel Emission Control System Evaluation of PM exhaust aftertreatment technologies of a non-road engine over a steady-state cycle PDF icon deer08_shade.pdf More Documents & Publications Diesel Particulate Filters and NO2 Emission Limits Active Diesel Emission Control Technology for Transport Refrigeration Units Active Diesel Emission Control Systems

  4. Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Characterized particulate emissions from U.S.-legal stoichiometric GDI and European certified lean-burn GDI vehicles operating on ethanol blends PDF icon deer11_storey.pdf More Documents & Publications Measurement and Characterization of Unregulated Emissions from Advanced Technologies Measurement and Characterization of Unregulated Emissions from Advanced

  5. Diesel engine emissions reduction by multiple injections having increasing pressure

    DOE Patents [OSTI]

    Reitz, Rolf D. (Madison, WI); Thiel, Matthew P. (Madison, WI)

    2003-01-01

    Multiple fuel charges are injected into a diesel engine combustion chamber during a combustion cycle, and each charge after the first has successively greater injection pressure (a higher injection rate) than the prior charge. This injection scheme results in reduced emissions, particularly particulate emissions, and can be implemented by modifying existing injection system hardware. Further enhancements in emissions reduction and engine performance can be obtained by using known measures in conjunction with the invention, such as Exhaust Gas Recirculation (EGR).

  6. French perspective on diesel engines & emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    French perspective on diesel engines & emissions French perspective on diesel engines & emissions 2002 DEER Conference Presentation: Aaqius & Aaqius PDF icon 2002_deer_nino.pdf More Documents & Publications Diesel Particulate Filters: Market Introducution in Europe Review of SCR Technologies for Diesel Emission Control: Euruopean Experience and Worldwide Perspectives Performance and durability of PSA Peugeot Citroen's DPF System on a Taxi Fleet in the Paris Area

  7. DEMONSTRATION OF POTENTIAL FOR SELECTIVE CATALYTIC REDUCTION AND DIESEL PARTICULATE FILTERS

    SciTech Connect (OSTI)

    McGILL,R; KHAIR, M; SHARP, C

    2003-08-24

    This project addresses the potential for Selective Catalytic Reduction (SCR) devices (using urea as reductant) together with Diesel Particulate Filters (DPF) and low-pressure loop exhaust gas recirculation (EGR) to achieve future stringent emissions standards for heavy-duty engines powering Class 8 vehicles. Two emission control systems consisting of the three technologies (EGR, SCR, and DPF) were calibrated on a Caterpillar C-12 heavy-duty diesel engine. Results of these calibrations showed good promise in meeting the 2010 heavy-duty emission standards as set forth by the Environmental Protection Agency (EPA). These two emission control systems were developed to evaluate a series of fuels that have similar formulations except for their sulfur content. Additionally, one fuel, code-named BP15, was also evaluated. This fuel was prepared by processing straight-run distillate stocks through a commercial, single stage hydrotreater employing high activity catalyst at maximum severity. An additional goal of this program is to provide data for an on-going EPA technology review that evaluates progress toward meeting 2007/2010 emission standards. These emissions levels were to be achieved not only on the transient test cycles but in other modes of operation such as the steady-state Euro-III style emission test known as the OICA (Organisation Internationale des Compagnies d'Automobiles) or the ESC (European Stationary Cycle). Additionally, hydrocarbon and carbon monoxide emissions standards are to be met.

  8. Apparatus for measuring surface particulate contamination

    DOE Patents [OSTI]

    Woodmansee, Donald E. (Simpsonville, SC)

    2002-01-01

    An apparatus for measuring surface particulate contamination includes a tool for collecting a contamination sample from a target surface, a mask having an opening of known area formed therein for defining the target surface, and a flexible connector connecting the tool to the mask. The tool includes a body portion having a large diameter section defining a surface and a small diameter section extending from the large diameter section. A particulate collector is removably mounted on the surface of the large diameter section for collecting the contaminants. The tool further includes a spindle extending from the small diameter section and a spool slidingly mounted on the spindle. A spring is disposed between the small diameter section and the spool for biasing the spool away from the small diameter section. An indicator is provided on the spindle so as to be revealed when the spool is pressed downward to compress the spring.

  9. Face crack reduction strategy for particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-01-31

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion. A control module initiates combustion of PM in the PM filter using a heater and selectively adjusts oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter. A method comprises providing a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and at least one portion; initiating combustion of PM in the PM filter using a heater; selectively adjusting oxygen levels of the exhaust gas to adjust a temperature of combustion adjacent to the at least one portion of the PM filter.

  10. Generator powered electrically heated diesel particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2014-03-18

    A control circuit for a vehicle powertrain includes a switch that selectivity interrupts current flow between a first terminal and a second terminal. A first power source provides power to the first terminal and a second power source provides power to the second terminal and to a heater of a heated diesel particulate filter (DPF). The switch is opened during a DPF regeneration cycle to prevent the first power source from being loaded by the heater while the heater is energized.

  11. Immobilization of Rocky Flats Graphite Fines Residue

    SciTech Connect (OSTI)

    Rudisill, T.S.

    1999-04-06

    The development of the immobilization process for graphite fines has proceeded through a series of experimental programs. The experimental procedures and results from each series of experiments are discussed in this report.

  12. Advanced Emissions Control Development Program. Quarterly Technical Progress Report {number_sign}5 for the period October 1 to December 31, 1995

    SciTech Connect (OSTI)

    Farthing, George A.

    1996-12-31

    Babcock {ampersand} Wilcox (B{ampersand}W) is conducting a five year project aimed at the development of practical, cost- effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls will likely arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendments of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF will provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. The specific objectives of the project are to: (1) measure and understand the production and partitioning of air toxics species for a variety of steam coals, (2) optimize the air toxics removal performance of conventional flue gas cleanup systems (ESPs, baghouses, scrubbers), (3) develop advanced air toxics emissions control concepts, (4) develop and validate air toxics emissions measurement and monitoring techniques, and (5) establish a comprehensive, self-consistent air toxics data library. Development work is currently concentrated on the capture of mercury, fine particulate, and a variety of inorganic species such as the acid gases (hydrogen chloride, hydrogen fluoride, etc.).

  13. Advanced Emissions Control Development Program. Quarterly Technical Progress Report {number_sign}6 for the period: January 1 to March 31, 1996

    SciTech Connect (OSTI)

    Farthing, George A.

    1996-12-31

    Babcock {ampersand} Wilcox (B{ampersand}W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls will likely arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the clean Air Act Amendments of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B{ampersand}W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF will provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. The specific objectives of the project are to: (1) measure and understand the production and partitioning of air toxics species for a variety of steam coals, (2) optimize the air toxics removal performance of conventional flue gas cleanup systems (ESPs, baghouses, scrubbers), (3) develop advanced air toxics emissions control concepts, (4) develop and validate air toxics emissions measurement and monitoring techniques, and (5) establish a comprehensive, self- consistent air toxics data library. Development work is currently concentrated on the capture of mercury, fine particulate, and a variety of inorganic species such as the acid gases (hydrogen chloride, hydrogen fluoride, etc.).

  14. Pelletization of fine coals. Final report

    SciTech Connect (OSTI)

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  15. Development of the DDA 8. 2L diesel engine for 1988 emission standards

    SciTech Connect (OSTI)

    Winsor, R.E.; Wheeler, C.L.

    1988-01-01

    The emission development performed to meet 1988 Federal and California emission standards with a four-stroke direct-injection V-8 diesel engine of 8.2L displacement is described. On the naturally aspirated engine the major concern was meeting particulate and lug smoke standards at low NO/sub x/ levels. Acceleration smoke and particulate emission reduction was necessary on the turbocharged engine. The performance and emission goals were met by modifying the unit injectors and pistons of both naturally aspirated and turbocharged engines.

  16. Hydrophobic Dewatering of Fine Coal. Topical report, March 1, 1995-March 31, 1997

    SciTech Connect (OSTI)

    Yoon, R.; Sohn, S.; Luttrell, J.; Phillips, D.

    1997-12-31

    Many advanced fine coal cleaning technologies have been developed in recent years under the auspices of the U.S. Department of Energy. However, they are not as widely deployed in industry as originally anticipated. An important reason for this problem is that the cleaned coal product is difficult to dewater because of the large surface area associated with fine particles. Typically, mechanical dewatering, such as vacuum filtration and centrifugation, can reduce the moisture to 20-35% level, while thermal drying is costly. To address this important industrial problem, Virginia Tech has developed a novel dewatering process, in which water is displaced from the surface of fine particulate materials by liquid butane. Since the process is driven by the hydrophobic interaction between coal and liquid butane, it was referred to as hydrophobic dewatering (HD). A fine coal sample with 21.4 pm median size was subjected to a series of bench-scale HD tests. It was a mid-vol bituminous coal obtained from the Microcel flotation columns operating at the Middle Fork coal preparation plant, Virginia. All of the test results showed that the HD process can reduce the moisture to substantially less than 10%. The process is sensitive to the amount of liquid butane used in the process relative to the solids concentration in the feed stream. Neither the intensity nor the time of agitation is critical for the process. Also, the process does not require long time for phase separation. Under optimal operating conditions, the moisture of the fine coal can be reduced to 1% by weight of coal.

  17. Advanced Collaborative Emissions Study (ACES)

    SciTech Connect (OSTI)

    Greenbaum, Daniel; Costantini, Maria; Van Erp, Annemoon; Shaikh, Rashid; Bailey, Brent; Tennant, Chris; Khalek, Imad; Mauderly, Joe; McDonald, Jacob; Zielinska, Barbara; Bemis, Jeffrey; Storey, John; Hallberg, Lance; Clark, Nigel

    2013-12-31

    The objective of the Advanced Collaborative Emissions Study (ACES) was to determine before widespread commercial deployment whether or not the new, energy-efficient, heavy duty diesel engines (2007 and 2010 EPA Emissions Standards Compliant) may generate anticipated toxic emissions that could adversely affect the environment and human health. ACES was planned to take place in three phases. In Phase 1, extensive emissions characterization of four production-intent prototype engine and control systems designed to meet 2007 standards for nitrogen oxides (NOx) and particulate matter (PM) was conducted at an existing emissions characterization facility: Southwest Research Institute (SwRI). One of the tested engines was selected (at random, after careful comparison of results) for health testing in Phase 3. In Phase 2, extensive emission characterization of three production-intent prototype engine and control systems meeting the 2010 standards (including more advanced NOx controls to meet the more stringent 2010 NOx standards) was conducted at the same test facility. In Phase 3, one engine/aftertreatment system selected from Phase 1 was further characterized during health effects studies (at an existing inhalation toxicology laboratory: Lovelace Respiratory Research Institute, [LRRI]) to form the basis of the ACES safety assessment. The Department of Energy (DOE) award provided funding for emissions characterization in Phases 1 and 2 as well as exposure characterization in Phase 3. The main health analyses in Phase 3 were funded separately and are not reported here.

  18. PARTICULATE CHARACTERIZATION AND ULTRA LOW-NOx BURNER FOR THE CONTROL OF NO{sub x} AND PM{sub 2.5} FOR COAL FIRED BOILERS

    SciTech Connect (OSTI)

    Ralph Bailey; Hamid Sarv; Jim Warchol; Debi Yurchison

    2001-09-30

    In response to the serious challenge facing coal-fired electric utilities with regards to curbing their NO{sub x} and fine particulate emissions, Babcock and Wilcox and McDermott Technology, Inc. conducted a project entitled, ''Particulate Characterization and Ultra Low-NO{sub x} Burner for the Control of NO{sub x} and PM{sub 2.5} for Coal Fired Boilers.'' The project included pilot-scale demonstration and characterization of technologies for removal of NO{sub x} and primary PM{sub 2.5} emissions. Burner development and PM{sub 2.5} characterization efforts were based on utilizing innovative concepts in combination with sound scientific and fundamental engineering principles and a state-of-the-art test facility. Approximately 1540 metric tonnes (1700 tons) of high-volatile Ohio bituminous coal were fired. Particulate sampling for PM{sub 2.5} emissions characterization was conducted in conjunction with burner testing. Based on modeling recommendations, a prototype ultra low-NO{sub x} burner was fabricated and tested at 100 million Btu/hr in the Babcock and Wilcox Clean Environment Development Facility. Firing the unstaged burner with a high-volatile bituminous Pittsburgh 8 coal at 100 million Btu/hr and 17% excess air achieved a NO{sub x} goal of 0.20 lb NO{sub 2}/million Btu with a fly ash loss on ignition (LOI) of 3.19% and burner pressure drop of 4.7 in H{sub 2}O for staged combustion. With the burner stoichiometry set at 0.88 and the overall combustion stoichiometry at 1.17, average NO{sub x} and LOI values were 0.14 lb NO{sub 2}/million Btu and 4.64% respectively. The burner was also tested with a high-volatile Mahoning 7 coal. Based on the results of this work, commercial demonstration is being pursued. Size classified fly ash samples representative of commercial low-NO{sub x} and ultra low-NO{sub x} combustion of Pittsburgh 8 coal were collected at the inlet and outlet of an ESP. The mass of size classified fly ash at the ESP outlet was sufficient to evaluate the particle size distribution, but was of insufficient size to permit reliable chemical analysis. The size classified fly ash from the inlet of the ESP was used for detailed chemical analyses. Chemical analyses of the fly ash samples from the ESP outlet using a high volume sampler were performed for comparison to the size classified results at the inlet. For all test conditions the particulate removal efficiency of the ESP exceeded 99.3% and emissions were less than the NSPS limits of {approx}48 mg/dscm. With constant combustion conditions, the removal efficiency of the ESP increased as the ESP voltage and Specific Collection Area (SCA) increased. The associated decrease in particle emissions occurred in size fractions both larger and smaller than 2.5 microns. For constant ESP voltage and SCA, the removal efficiency for the ultra low-NO{sub x} combustion ash (99.4-99.6%) was only slightly less than for the low-NO{sub x} combustion ash (99.7%). The decrease in removal efficiency was accompanied by a decrease in ESP current. The emission of PM{sub 2.5} from the ESP did not change significantly as a result of the change in combustion conditions. Most of the increase in emissions was in the size fraction greater than 2.5 microns, indicating particle re-entrainment. These results may be specific to the coal tested in this program. In general, the concentration of inorganic elements and trace species in the fly ash at the ESP inlet was dependent on the particle size fraction. The smallest particles tended to have higher concentrations of inorganic elements/trace species than larger particles. The concentration of most elements by particle size range was independent of combustion condition and the concentration of soluble ions in the fly ash showed little change with combustion condition when evaluated on a carbon free basis.

  19. Exhaust system with emissions storage device and plasma reactor

    DOE Patents [OSTI]

    Hoard, John W. (Livonia, MI)

    1998-01-01

    An exhaust system for a combustion system, comprising a storage device for collecting NO.sub.x, hydrocarbon, or particulate emissions, or mixture of these emissions, and a plasma reactor for destroying the collected emissions is described. After the emission is collected in by the storage device for a period of time, the emission is then destroyed in a non-thermal plasma generated by the plasma reactor. With respect to the direction of flow of the exhaust stream, the storage device must be located before the terminus of the plasma reactor, and it may be located wholly before, overlap with, or be contained within the plasma reactor.

  20. Leatec Fine Ceramics Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Place: Tao-Yuan Hsien, Taiwan Product: Taiwan-based manufacturer of chip alumina fine ceramic substrates. The firm also produces PV junction boxes. References: Leatec Fine...

  1. Estimates of Particulate Mass in Multi Canister Overpacks (MCO)

    SciTech Connect (OSTI)

    SLOUGHTER, J.P.

    2000-02-16

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulates that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  2. Estimates of particulate mass in multi-canister overpacks

    SciTech Connect (OSTI)

    SLOUGHTER, J.P.

    1999-02-25

    High, best estimate, and low values are developed for particulate inventories within MCO baskets that have been loaded with freshly cleaned fuel assemblies and scrap. These per-basket estimates are then applied to all anticipated MCO payload configurations to identify which configurations are bounding for each type of particulate. Finally the resulting bounding and nominal values for residual particulates are combined with corresponding values [from other documents] for particulate that may be generated by corrosion of exposed uranium after the fuel has been cleaned. The resulting rounded nominal estimate for a typical MCO after 40 years of storage is 8 kg. The estimate for a bounding total particulate case MCO is that it may contain up to 64 kg of particulate after 40 years of storage.

  3. Shielded regeneration heating element for a particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-01-04

    An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

  4. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. Modeling of such flows at micro and macro levels as well establishing relationships between these approaches are needed to

  5. Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dynamic Neutron Radiography | Department of Energy Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Local Soot Loading Distribution in Cordierite Diesel Particulate Filters by Dynamic Neutron Radiography Quantitative analysis of the soot loading and soot distribution for Cordierite type DPFs are studied under controlled conditions. PDF icon deer10_harvel.pdf More Documents & Publications Neutron Imaging of Diesel Particulate Filters

  6. High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) |

    Energy Savers [EERE]

    Department of Energy High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) High Efficiency Particulate Air (HEPA) Filter Test Facility (FTF) DOE-STD-3020-2015 Specification for HEPA Filters Used by DOE Contractors The purpose of this standard is to establish specifications and quality assurance (QA) requirements for the procurement, packaging, shipping and storage of high efficiency particulate air (HEPA) filters. DOE-STD-3025-2007 Quality Assurance Inspection and Testing of HEPA

  7. Non-Destructive Neutron Imaging to Analyze Particulate Filters | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Neutron Imaging to Analyze Particulate Filters Non-Destructive Neutron Imaging to Analyze Particulate Filters Non-destructive, non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter. PDF icon p-27_toops.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Vehicle Technologies Office Merit Review 2014:

  8. Detailed Assessment of Particulate Characteristics from Low-Temperature

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Engines | Department of Energy Assessment of Particulate Characteristics from Low-Temperature Combustion Engines Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace083_lee_2012_p.pdf More Documents & Publications Characterization of Pre-Commercial Gasoline Engine Particulates Through Advanced Aerosol

  9. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024_lee_2010_o.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) Development of Advanced Particulate Filters

  10. Development of an Active Regeneration Diesel Particulate Filter System |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy an Active Regeneration Diesel Particulate Filter System Development of an Active Regeneration Diesel Particulate Filter System PDF icon 2004_deer_anderson.pdf More Documents & Publications A New Active DPF System for "Stop and Go" Duty-Cycle Vehicles Donaldson Active Regeneration PM System A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration

  11. Diesel Particulate Filter: A Success for Faurecia Exhaust Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Filter: A Success for Faurecia Exhaust Systems Diesel Particulate Filter: A Success for Faurecia Exhaust Systems 2003 DEER Conference Presentation: Faurecia Exhaust Systems PDF icon 2003_deer_parmann.pdf More Documents & Publications Combination of Diesel fuel system architectures and Ceria-based fuel-borne catalysts for improvement and simplification of the Diesel Particulate Filter System in serial applications Improvement and Simplification of Diesel Particulate

  12. Durability of Diesel Particulate Filters - Bench Studies on Cordierite

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy Particulate Filters - Bench Studies on Cordierite Filters Durability of Diesel Particulate Filters - Bench Studies on Cordierite Filters Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_dacosta.pdf More Documents & Publications Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Development of

  13. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Fluid particulate flows are common phenomena in nature and industry. Modeling of such flows at micro and macro levels as well establishing relationships between these approaches are needed to

  14. Blowers for Air Assisted Diesel Particulate Filter Regeneration |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Blowers for Air Assisted Diesel Particulate Filter Regeneration Blowers for Air Assisted Diesel Particulate Filter Regeneration Prototypes of a new series of high-pressure, brushless DC motor-drive blowers have completed field testing, and DFM and manufacturing cost studies are well advanced. PDF icon p-14_milburn.pdf More Documents & Publications Development of a Non Air-assisted Thermal Regenerator Development of an Active Regeneration Diesel Particulate Filter

  15. Substrate Studies of an Electrically-Assisted Diesel Particulate Filter |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Transient distributed DPF wall and gas temperature were simultaneously measured using the optical and thermocouple systems, on both electrically assisted and conventional fuel-only DPF regeneration cycles PDF icon deer12_parks.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration

  16. Diesel particulate filter regeneration via resistive surface heating

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-10-08

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine; and a grid of electrically resistive material that is applied to an exterior upstream surface of the PF and that selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  17. Characterization of emissions from advanced automotive power plant concepts

    SciTech Connect (OSTI)

    Montalvo, D.A.; Hare, C.T.

    1984-11-01

    Emissions from three diesel cars using two fuel formulations were assessed. The three diesel cars included a prototype naturally-aspirated Fiat 131, a prototype turbocharged Fiat 131, and a 1981 Oldsmobile Cutlass Supreme. Each Fiat was tested with and without a prototype catalytic trap. Vehicle operating procedures used for test purposes included the 1981 Federal Test Procedures as well as the Highway Fuel Economy Test, the New York City Cycle, and an 85 km/hr steady-state cruise. Both regulated and unregulated gaseous and particulate emissions were measured. Organic solubles in particulate were analyzed for various constituents and characteristics including fractionation by relative polarity, benzo(a)pyrene (BaP), and mutagenic activity by Ames bioassay. Application of the catalytic trap oxidizer system to the Fiat prototypes resulted in significant reductions of organic and carbon monoxide emissions under all transient driving conditions examined. Total particulate emissions were reduced an average of 55 percent with the turbocharged engine and 65 percent with the naturally-aspirated engine. The Ames assay mutagenic response (revertants/microgram) of the particulate-phase organics was elevated by the catalytic exhaust aftertreatment device, however the emission rates (revertants/km) were reduced an average of 66 percent with the turbocharged and 73 percent with the naturally-aspirated engines.

  18. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024lee2011o.pdf More Documents & Publications Development of Advanced Particulate Filters...

  19. Development of an Active Regeneration Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DPF System for "Stop and Go" Duty-Cycle Vehicles Donaldson Active Regeneration PM System A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration...

  20. Effect of Biodiesel Blends on Diesel Particulate Filter Performance

    SciTech Connect (OSTI)

    Williams, A.; McCormick, R. L.; Hayes, R. R.; Ireland, J.; Fang, H. L.

    2006-11-01

    Presents results of tests of ultra-low sulfur diesel blended with soy-biodiesel at 5 percent using a Cummins ISB engine with a diesel particulate filter.

  1. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneratio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Self-cleaning ceramic filter cartridges offer the advantage of better fuel economy, faster ... More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Expanded ...

  2. Non-Destructive Neutron Imaging to Analyze Particulate Filters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    non-invasive imaging is being employed in the laboratory to understand how soot, ash, and catalytic washcoat are deposited within a diesel particulate filter. PDF icon...

  3. Detailed Assessment of Particulate Characteristics from Low-Temperatur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detailed Assessment of Particulate Characteristics from Low-Temperature Combustion Engines ... Program Annual Merit Review and Peer Evaluation Meeting PDF icon ...

  4. Development of Acicular Mullite Materials for Diesel Particulate...

    Broader source: Energy.gov (indexed) [DOE]

    Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Future Trends for DPFSCR On-Filter (SCRF) fundamental Modeling and Experimental Studies of ...

  5. Substrate Studies of an Electrically-Assisted Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of an Electrically-Assisted Diesel Particulate Filter Transient distributed DPF wall and gas temperature were simultaneously measured using the optical and thermocouple systems, on...

  6. Value Analysis of Alternative Diesel Particulate Filter (DPF...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel ... Provide higher soot mass limits and durability than other materials at the same porosity. ...

  7. Diesel Particulate Oxidation Model: Combined Effects of Fixed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions ...

  8. Mesoscale simulations of particulate flows with parallel distributed...

    Office of Scientific and Technical Information (OSTI)

    distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier ...

  9. Electrically heated particulate filter regeneration using hydrocarbon adsorbents

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-02-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

  10. Development and Demonstration of an Electronic Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and...

  11. Neutron Imaging of Diesel Particulate Filters

    SciTech Connect (OSTI)

    Strzelec, Andrea; Bilheux, Hassina Z; FINNEY, Charles E A; Daw, C Stuart; Foster, Prof. Dave; Rutland, Prof. Christopher J.; Schillinger, Burkhard; Schulz, Michael

    2009-01-01

    This article presents nondestructive neutron computed tomography (nCT) measurements of Diesel Particulate Filters (DPFs) as a method to measure ash and soot loading in the filters. Uncatalyzed and unwashcoated 200cpsi cordierite DPFs exposed to 100% biodiesel (B100) exhaust and conventional ultra low sulfur 2007 certification diesel (ULSD) exhaust at one speed-load point (1500rpm, 2.6bar BMEP) are compared to a brand new (never exposed) filter. Precise structural information about the substrate as well as an attempt to quantify soot and ash loading in the channel of the DPF illustrates the potential strength of the neutron imaging technique.

  12. Electrically heated particulate filter with reduced stress

    DOE Patents [OSTI]

    Gonze, Eugene V.

    2013-03-05

    A system comprises a particulate matter (PM) filter comprising an inlet for receiving exhaust gas. A zoned heater is arranged in the inlet and comprises a resistive heater comprising N zones, where N is an integer greater than one. Each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates others of the N zones.

  13. Particulate Matter Characteristics for Highly Dilute Stoichiometric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon p-24storey.pdf More Documents & Publications Ethanol Effects on Lean-Burn and Stoichiometric GDI Emissions Effects of Advanced Combustion Technologies on...

  14. Method of forming particulate materials for thin-film solar cells

    DOE Patents [OSTI]

    Eberspacher, Chris; Pauls, Karen Lea

    2004-11-23

    A method for preparing particulate materials useful in fabricating thin-film solar cells is disclosed. Particulate materials is prepared by the method include for example materials comprising copper and indium and/or gallium in the form of single-phase, mixed-metal oxide particulates; multi-phase, mixed-metal particulates comprising a metal oxide; and multinary metal particulates.

  15. Final report for "Characterization of Fine Particulate Matter (PM) and secondary PM Precursor Gases in the Mexico City Metropolitan Area"

    SciTech Connect (OSTI)

    Prof. Jose-Luis Jimenez

    2009-05-18

    The objectives of this funded project were (a) to further analyze the data collected by our group and collaborators in Mexico City during the MCMA-2003 field campaign, with the goal of further our understanding of aerosol sources and processes; and (b) to deploy several advanced instruments, including the newly developed high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and thermal-denuder (TD), during the MILAGRO/MAX-Mex/MCMA-2006 field campaign, and to analyze those data (together with the 2003 data) to provide additional insights on the formation and transformation of aerosols in the Mexico City area. These goals were addressed in collaboration with our project partners, MIT/Molina Center, and Aerodyne Research. Overall this project was very successful, resulting on 22+ journal papers including six highly cited papers and three papers that are the most cited in their respective journals (out of several thousand papers) since the year in which they were published. Multiple discoveries, such as the the underestimation of SOA in urban areas even for short photochemical ages, the demonstration that urban POA is of similar or higher volatility than urban SOA, and the first analysis of organic aerosol elemental composition in real-time have been recently published. Several dozen presentations at major US and international conferences and seminars also acknowledged this grant.

  16. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  17. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, W.R. Jr.; Guthrie, S.E.; Raber, T.N.; Wally, K.; Whinnery, L.L.; Zifer, T.

    1999-02-02

    The present invention pertains generally to immobilizing particulate matter contained in a packed bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that (a) the particulate retains its essential chemical nature, (b) the local movement of the particulate particles is not unduly restricted, (c) bulk powder migration and is prevented, (d) physical and chemical access to the particulate is unchanged over time, and (e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of an individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport. 4 figs.

  18. Method for immobilizing particulate materials in a packed bed

    DOE Patents [OSTI]

    Even, Jr., William R.; Guthrie, Stephen E.; Raber, Thomas N.; Wally, Karl; Whinnery, LeRoy L.; Zifer, Thomas

    1999-01-01

    The present invention pertains generally to immobilizing particulate matter contained in a "packed" bed reactor so as to prevent powder migration, compaction, coalescence, or the like. More specifically, this invention relates to a technique for immobilizing particulate materials using a microporous foam-like polymer such that a) the particulate retains its essential chemical nature, b) the local movement of the particulate particles is not unduly restricted, c) bulk powder migration and is prevented, d) physical and chemical access to the particulate is unchanged over time, and e) very high particulate densities are achieved. The immobilized bed of the present invention comprises a vessel for holding particulate matter, inlet and an outlet ports or fittings, a loosely packed bed of particulate material contained within the vessel, and a three dimensional porous matrix for surrounding and confining the particles thereby fixing the movement of individual particle to a limited local position. The established matrix is composed of a series of cells or chambers comprising walls surrounding void space, each wall forming the wall of an adjacent cell; each wall containing many holes penetrating through the wall yielding an overall porous structure and allowing useful levels of gas transport.

  19. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, D.E.

    1997-10-21

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

  20. Electrically-Assisted Diesel Particulate Filter Regeneration | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon pm041_lance_2011_p.pdf More Documents & Publications Electrically-Assisted Diesel Particulate Filter Regeneration Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Biofuels Impact on DPF Durability

  1. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, Daniel E. (Orchard Park, NY)

    1997-01-01

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

  2. Method for removing particulate matter from a gas stream

    DOE Patents [OSTI]

    Postma, Arlin K. (Benton City, WA)

    1984-01-01

    Particulate matter is removed from a stream of pressurized gas by directing the stream of gas upwardly through a bed of porous material, the porous bed being held in an open ended container and at least partially submerged in liquid. The passage of the gas through the porous bed sets up a circulation in the liquid which cleans the particulate matter from the bed.

  3. System for utilizing oil shale fines

    DOE Patents [OSTI]

    Harak, Arnold E.

    1982-01-01

    A system is provided for utilizing fines of carbonaceous materials such as particles or pieces of oil shale of about one-half inch or less diameter which are rejected for use in some conventional or prior surface retorting process, which obtains maximum utilization of the energy content of the fines and which produces a waste which is relatively inert and of a size to facilitate disposal. The system includes a cyclone retort (20) which pyrolyzes the fines in the presence of heated gaseous combustion products, the cyclone retort having a first outlet (30) through which vapors can exit that can be cooled to provide oil, and having a second outlet (32) through which spent shale fines are removed. A burner (36) connected to the spent shale outlet of the cyclone retort, burns the spent shale with air, to provide hot combustion products (24) that are carried back to the cyclone retort to supply gaseous combustion products utilized therein. The burner heats the spent shale to a temperature which forms a molten slag, and the molten slag is removed from the burner into a quencher (48) that suddenly cools the molten slag to form granules that are relatively inert and of a size that is convenient to handle for disposal in the ground or in industrial processes.

  4. Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health

    SciTech Connect (OSTI)

    West, Jason; Smith, Steven J.; Silva, Raquel; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zacariah; Fry, Meridith M.; Anenberg, Susan C.; Horowitz, L.; Lamarque, Jean-Francois

    2013-10-01

    Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. Relative to a reference scenario, global GHG mitigation in the RCP4.5 scenario avoids 0.50.2, 1.30.6, and 2.21.6 million premature deaths in 2030, 2050, and 2100, from changes in fine particulate matter and ozone. Global average marginal co-benefits of avoided mortality are $40-400 (ton CO2)-1, exceeding marginal abatement costs in 2030 and 2050, and within the low range of costs in 2100. East Asian co-benefits are 10-80 times the marginal cost in 2030. These results indicate that transitioning to a low-carbon future might be justified by air quality and health co-benefits.

  5. Process for producing dispersed particulate composite materials

    DOE Patents [OSTI]

    Henager, Jr., Charles H. (Richland, WA); Hirth, John P. (Viola, ID)

    1995-01-01

    This invention is directed to a process for forming noninterwoven dispersed particulate composite products. In one case a composite multi-layer film product comprises a substantially noninterwoven multi-layer film having a plurality of discrete layers. This noninterwoven film comprises at least one discrete layer of a first material and at least one discrete layer of a second material. In another case the first and second materials are blended together with each other. In either case, the first material comprises a metalloid and the second material a metal compound. At least one component of a first material in one discrete layer undergoes a solid state displacement reaction with at least one component of a second material thereby producing the requisite noninterwoven composite film product. Preferably, the first material comprises silicon, the second material comprises Mo.sub.2 C, the third material comprises SiC and the fourth material comprises MoSi.sub.2.

  6. Overlap zoned electrically heated particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Chapman, Mark R [Brighton, MI

    2011-07-19

    A system includes a particulate matter (PM) filter that includes an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than or equal to one, and wherein the N zones and the M sub-zones are arranged in P layers, where P is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  7. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for ... Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency ...

  8. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines 2009...

  9. Active Diesel Emission Control Technology for Transport Refrigeration Units

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Transport Refrigeration Units Active Diesel Emission Control Technology for Transport Refrigeration Units This project discusses a CARB Level 2+ verified active regeneration technology for smal diesel engines PDF icon deer09_guzman.pdf More Documents & Publications Diesel Particulate Filters and NO2 Emission Limits RYPOS - An Actively Regenerated DPF that Demonstrates Significant NO2 Reduction 2005_deer_dePetrillo.pdf

  10. Emissions from the European Light Duty Diesel Vehicle During DPF

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration Events | Department of Energy the European Light Duty Diesel Vehicle During DPF Regeneration Events Emissions from the European Light Duty Diesel Vehicle During DPF Regeneration Events Repeated partial regenerations may cause changes in the mechanical and chemical properties of the PM in the DPF. PDF icon deer09_dwyer.pdf More Documents & Publications A Study of Emissions from a Light Duty Diesel Engine with the European Particulate Measurement Programme Measurement of

  11. Strategies for Integrated Emission Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Emission Control Strategies for Integrated Emission Control A new filter system technology significantly reduces harmful pollutants, uses less precious metals, and offers long-term durability. PDF icon deer08_copan.pdf More Documents & Publications Selective Catalytic Reduction and Exhaust Gas Recirculation Systems Optimization A Bimetmallic Fuel-Borne Catalyst for Reduce Precious Metal Use in Medium-Duty Diesel Engines Diesel Particulate Filters: Market Introducution in Europe

  12. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, G.S.

    1998-12-15

    Particulate contamination removal from wafers is disclosed using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer`s position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates. 4 figs.

  13. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1998-01-01

    Particulate contamination removal from wafers using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer's position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates.

  14. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  15. Synthesis of fine-grained TATB

    DOE Patents [OSTI]

    Lee, Kien-Yin (Santa Fe, NM); Kennedy, James E. (Santa Fe, NM)

    2003-04-15

    A method for producing fine-grained triamino-trinitrobenzene (TATB) powders having improved detonation-spreading performance and hence increased shock sensitivity when compared with that for ultrafine TATB is described. A single-step, sonochemical amination of trichloro-trinitrobenzene using ammonium hydroxide solution in a sealed vessel yields TATB having approximately 6 .mu.m median particle diameter and increased shock sensitivity.

  16. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  17. Optimization of Engine-out Emissions from a Diesel Engine to Meet Tier 2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bin 5 Emission Limits | Department of Energy Engine-out Emissions from a Diesel Engine to Meet Tier 2 Bin 5 Emission Limits Optimization of Engine-out Emissions from a Diesel Engine to Meet Tier 2 Bin 5 Emission Limits Drastic reduction of engine-out emissions and complicated aftertreatment system comprising of oxidation catalyst, particulate filter, and DeNOx catalyst are implemented to meet Tier 2 Bin 5 limits for U.S. market diesel engines. PDF icon deer08_yoon.pdf More Documents &

  18. Biodiesel Emissions Testing with a Modern Diesel Engine - Equipment Only: Cooperative Research and Development Final Report, CRADA Number CRD-10-399

    SciTech Connect (OSTI)

    Williams, A.

    2013-06-01

    To evaluate the emissions and performance impact of biodiesel in a modern diesel engine equipped with a diesel particulate filter. This testing is in support of the Non-Petroleum Based Fuels (NPBF) 2010 Annual Operating Plan (AOP).

  19. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024lee2010o.pdf More Documents & Publications Development of Advanced Diesel Particulate...

  20. Diesel Particulate Filter Technology for Low-Temperature and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filter Technology for Low-Temperature and Low-NOxPM Applications Diesel Particulate Filter Technology for Low-Temperature and Low-NOxPM Applications 2004 DEER Conference...

  1. Blowers for Air Assisted Diesel Particulate Filter Regeneration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blowers for Air Assisted Diesel Particulate Filter Regeneration Prototypes of a new series of high-pressure, brushless DC motor-drive blowers have completed field testing, and DFM ...

  2. Mechanical Properties of Particulate Reinforced Aluminium Alloy Matrix Composite

    SciTech Connect (OSTI)

    Sayuti, M. [Faculty of Engineering, Malikussaleh University of Lhokseumawe, 24300 Aceh (Indonesia); Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Sulaiman, S.; Baharudin, B. T. H. T.; Arifin, M. K. A. [Department of Mechanical and Manufacturing Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia); Suraya, S.; Vijayaram, T. R.

    2011-01-17

    This paper discusses the mechanical properties of Titanium Carbide (TiC) particulate reinforced aluminium-silicon alloy matrix composite. TiC particulate reinforced LM6 alloy matrix composites were fabricated by carbon dioxide sand molding process with different particulate weight fraction. Tensile strength, hardness and microstructure studies were conducted to determine the maximum load, tensile strength, modulus of elasticity and fracture surface analysis have been performed to characterize the morphological aspects of the test samples after tensile testing. Hardness values are measured for the TiC reinforced LM6 alloy composites and it has been found that it gradually increases with increased addition of the reinforcement phase. The tensile strength of the composites increased with the increase percentage of TiC particulate.

  3. ARM - Field Campaign - Semi-Continuous OCEC Particulate Measurement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send Campaign : Semi-Continuous OCEC Particulate Measurement 2013.06.01 - 2013.11.27 Lead Scientist : Robert Cary For data sets, see below. Abstract The Sunset Laboratory...

  4. ARM - Field Campaign - 1999 Northeast Corridor Ozone & Particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : 1999 Northeast Corridor Ozone & Particulate Study 1999.07.23 - 1999.08.11 Lead...

  5. Zone heated inlet ignited diesel particulate filter regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2012-06-26

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

  6. Mesoscale simulations of particulate flows with parallel distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange multiplier technique (Journal Article) | SciTech Connect Journal Article: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Authors: Kanarska, Y ; Lomov, I ; Antoun, T Publication Date: 2010-09-10 OSTI Identifier: 1120915 Report Number(s): LLNL-JRNL-455392 DOE Contract Number: W-7405-ENG-48

  7. Mesoscale Simulations of Particulate Flows with Parallel Distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange Multiplier Technique (Conference) | SciTech Connect Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique Citation Details In-Document Search Title: Mesoscale Simulations of Particulate Flows with Parallel Distributed Lagrange Multiplier Technique × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a

  8. Mesoscale simulations of particulate flows with parallel distributed

    Office of Scientific and Technical Information (OSTI)

    Lagrange multiplier technique (Journal Article) | SciTech Connect Journal Article: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique Citation Details In-Document Search Title: Mesoscale simulations of particulate flows with parallel distributed Lagrange multiplier technique × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI)

  9. Reduction of Transient Particulate Matter Spikes with Decision Tree Based

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control | Department of Energy Transient Particulate Matter Spikes with Decision Tree Based Control Reduction of Transient Particulate Matter Spikes with Decision Tree Based Control Using a non-parametric decision tree to measure transient PM could correctly identify 94% of high opacity spikes and used to take targeted action to reduce PM without affecting NOx. PDF icon deer12_brahma.pdf More Documents & Publications New Demands on Heavy Duty Engine Management Systems An Enabling Study

  10. Experimental Diesel Particulate Filter Capabilities at PNNL | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Diesel Particulate Filter Capabilities at PNNL Experimental Diesel Particulate Filter Capabilities at PNNL Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_gallant.pdf More Documents & Publications Diesel Soot Filter Characterization and Modeling for Advanced Substrates fundamental Modeling and Experimental Studies of Acicular Mullite Diesel

  11. Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramics | Department of Energy Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Failure Stress and Apparent Elastic Modulus of Diesel Particulate Filter Ceramics Three established mechanical test specimen geometries and test methods for brittle materials are adapted to DPF architecture to evaluate failure initiation stress and apparent elastic modulus of the ceramics. PDF icon p-15_wereszczak.pdf More Documents & Publications Durability of Diesel Engine

  12. Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Time and Fuel Consumption | Department of Energy Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Ultra-Lite Diesel Particulate Filter Cartridge for Reduced Regeneration Time and Fuel Consumption Self-cleaning ceramic filter cartridges offer the advantage of better fuel economy, faster regeneration time, improved heat transfer, and reduction in manufacturing steps PDF icon deer09_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber

  13. Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Future Diesel Aftertreatment Systems | Department of Energy Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems Value Analysis of Alternative Diesel Particulate Filter (DPF) Substrates for Future Diesel Aftertreatment Systems DPF products like Acicular Mullite meet multiple needs Provide higher soot mass limits and durability than other materials at the same porosity. PDF icon deer09_majkowski.pdf More Documents &

  14. Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters | Department of Energy Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters SEM analysis showed that ACM DPF can be coated with relatively high catalyst washcoat without significantly affecting the porosity or pore size Therefore, it maintains a low back pressure performance at very high catalyst PDF icon deer09_malanga.pdf More Documents & Publications Future Trends for

  15. Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wins R&D 100 Award | Department of Energy Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award October 15, 2014 - 4:51pm Addthis Developed jointly by Corning, the FEV Group, Maguffin Microwave, Detroit Diesel, and Oak Ridge National Laboratory (ORNL) in cooperation with the New York City Department of Sanitation, the Radio Frequency Diesel

  16. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    McInnis, E.L.; Scharff, R.P.; Bauman, B.D.; Williams, M.A.

    1995-01-17

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figures.

  17. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    Bauman, Bernard D.; Williams, Mark A.; Bagheri, Reza

    1997-12-02

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

  18. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    Bauman, B.D.; Williams, M.A.; Bagheri, R.

    1997-12-02

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figs.

  19. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    McInnis, E.L.; Bauman, B.D.; Williams, M.A.

    1996-04-09

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles. 2 figs.

  20. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    McInnis, Edwin L.; Scharff, Robert P.; Bauman, Bernard D.; Williams, Mark A.

    1995-01-01

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

  1. Higher modulus compositions incorporating particulate rubber

    DOE Patents [OSTI]

    McInnis, Edwin L.; Bauman, Bernard D.; Williams, Mark A.

    1996-04-09

    Rubber particles, to be used as fillers or extenders for various composite polymer systems, are chlorinated by a gas-solid phase reaction with a chlorine-containing gas. A composite polymer containing the chlorinated rubber fillers or extenders exhibits a higher flexural modulus than if prepared using an unchlorinated rubber filler or extender. Chlorination of the rubber particles is carried out by contacting the finely divided rubber particles with a chlorine-containing gas comprising at least about 5 volume percent chlorine. Advantageously, the chlorine can be diluted with air, nitrogen or other essentially inert gases and may contain minor amounts of fluorine. Improved performance is obtained with nitrogen dilution of the chlorine gas over air dilution. Improved polymer composite systems having higher flexural modulus result from the use of the chlorinated rubber particles as fillers instead of unchlorinated rubber particles.

  2. Reducing VOC Press Emission from OSB Manufacturing

    SciTech Connect (OSTI)

    Dr. Gary D. McGinnis; Laura S. WIlliams; Amy E. Monte; Jagdish Rughani: Brett A. Niemi; Thomas M. Flicker

    2001-12-31

    Current regulations require industry to meet air emission standards with regard to particulates, volatile organic compounds (VOCs), hazardous air pollutants (HAPs) and other gases. One of many industries that will be affected by the new regulations is the wood composites industry. This industry generates VOCs, HAPs, and particulates mainly during the drying and pressing of wood. Current air treatment technologies for the industry are expensive to install and operate. As regulations become more stringent, treatment technologies will need to become more efficient and cost effective. The overall objective of this study is to evaluate the use of process conditions and chemical additives to reduce VOC/HAPs in air emitted from presses and dryers during the production of oriented strand board.

  3. Operability and Emissions from a Medium-Duty Fleet Operating with GTL Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Catalyzed DPFs | Department of Energy Operability and Emissions from a Medium-Duty Fleet Operating with GTL Fuel and Catalyzed DPFs Operability and Emissions from a Medium-Duty Fleet Operating with GTL Fuel and Catalyzed DPFs 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Shell Global Solutions (US) Inc. PDF icon 2004_deer_cherrillo.pdf More Documents & Publications Diesel Particulate Filter Technology for Low-Temperature and Low-NOx/PM Applications

  4. Active Diesel Emission Control Technology for Sub-50 HP Engines with Low

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Temperature Profiles | Department of Energy Sub-50 HP Engines with Low Exhaust Temperature Profiles Active Diesel Emission Control Technology for Sub-50 HP Engines with Low Exhaust Temperature Profiles A new type of emission control technology was presented for the small engines used in APU's and TRU's. PDF icon deer08_depetrillo.pdf More Documents & Publications Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine 2005_deer_dePetrillo.pdf Active Diesel Emission

  5. Diesel particulate filter (DPF) regeneration by electrical heating of resistive coatings

    DOE Patents [OSTI]

    Williamson, Weldon S. (Malibu, CA); Gonze, Eugene V. (Pinckney, MI)

    2008-12-30

    An exhaust system that processes exhaust generated by an engine includes a diesel particulate filter (DPF) that is disposed downstream of the engine and that filters particulates from the exhaust. An electrical heater is integrally formed in an upstream end of the DPF and selectively heats the exhaust to initiate combustion of the particulates within the exhaust as it passes therethrough. Heat generated by combustion of the particulates induces combustion of particulates within the DPF.

  6. Results of Self-Absorption Study on the Versapor 3000 Filters for Radioactive Particulate Air Sampling

    SciTech Connect (OSTI)

    Barnett, J. M.; Cullinan, Valerie I.; Barnett, Debra S.; Trang-Le, Truc LT; Bliss, Mary; Greenwood, Lawrence R.; Ballinger, Marcel Y.

    2009-02-17

    Since the mid-1980s, Pacific Northwest National Laboratory (PNNL) has used a value of 0.85 as the correction factor for self absorption of activity for particulate radioactive air samples collected from building exhaust for environmental monitoring. This value accounts for activity that cannot be detected by direct counting of alpha and beta particles. Emissions can be degraded or blocked by filter fibers for particles buried in the filter material or by inactive dust particles collected with the radioactive particles. These filters are used for monitoring air emissions from PNNL stacks for radioactive particles. This paper describes an effort to re-evaluate self-absorption effects in particulate radioactive air sample filters (Versapor 3000, 47 mm diameter) used at PNNL. There were two methods used to characterize the samples. Sixty samples were selected from the archive for acid digestion to compare the radioactivity measured by direct gas-flow proportional counting of filters to the results obtained after acid digestion of the filter and counting again by gas-flow proportional detection. Thirty different sample filters were selected for visible light microscopy to evaluate filter loading and particulate characteristics. Mass-loading effects were also considered. Filter ratios were calculated by dividing the initial counts by the post-digestion counts with the expectation that post-digestion counts would be higher because digestion would expose radioactivity embedded in the filter in addition to that on top of the filter. Contrary to expectations, the post digestion readings were almost always lower than initial readings and averaged approximately half the initial readings for both alpha and beta activity. Before and after digestion readings appeared to be related to each other, but with a low coefficient of determination (R^2) value. The ratios had a wide range of values indicating that this method did not provide sufficient precision to quantify self-absorption effects. The microscopy analysis compares different filter loadings and shows that smaller particle sizes (under 10 micron) can readily be seen on the more lightly loaded filters. At higher loadings, however, the particle size is harder to differentiate. This study provides data on actual stack emission samples showing a range of mass loading conditions and visual evidence of particle size and distribution and also presents the difficulties in quantifying self-absorption effects using actual samples.

  7. Method for producing dustless graphite spheres from waste graphite fines

    DOE Patents [OSTI]

    Pappano, Peter J (Oak Ridge, TN); Rogers, Michael R (Clinton, TN)

    2012-05-08

    A method for producing graphite spheres from graphite fines by charging a quantity of spherical media into a rotatable cylindrical overcoater, charging a quantity of graphite fines into the overcoater thereby forming a first mixture of spherical media and graphite fines, rotating the overcoater at a speed such that the first mixture climbs the wall of the overcoater before rolling back down to the bottom thereby forming a second mixture of spherical media, graphite fines, and graphite spheres, removing the second mixture from the overcoater, sieving the second mixture to separate graphite spheres, charging the first mixture back into the overcoater, charging an additional quantity of graphite fines into the overcoater, adjusting processing parameters like overcoater dimensions, graphite fines charge, overcoater rotation speed, overcoater angle of rotation, and overcoater time of rotation, before repeating the steps until graphite fines are converted to graphite spheres.

  8. Immobilization of Rocky Flats Graphite Fines Residues

    SciTech Connect (OSTI)

    Rudisill, T. S.

    1998-11-06

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt percent graphite, 15 wt percent calcium fluoride (CaF2), and 12 wt percent plutonium oxide (PuO2). Approximately 950 kilograms of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 degrees C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO2 concentration in the residue averages 12 wt percent, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF2 dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO2) as a surrogate for PuO2 and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF2 and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.In general, the recovery of cerium from the full-scale waste forms was higher than for smaller scale experiments. The presence of CaF2 also caused a dramatic increase in cerium recovery not seen in the small-scale experiments. However, the results from experiments with actual graphite fines were encouraging. A 4:1 frit to residue ratio, a temperature of 700 degrees C, and a 2 hr heating time produced waste forms with plutonium recoveries of 4 plus/minus 1 g/kg. With an increase in the frit to residue ratio, waste forms fabricated at this scale should meet the Rocky Flats product specification. The scale-up of the waste form fabrication process to nominally 3 kg is expected to require a 5:1 to 6:1 frit to residue ratio and maintaining the waste form centerline temperature at 700 degrees C for 2 hr.

  9. Loading and Regeneration Analysis of a Diesel Particulate Filter with a Radio Frequency-Based Sensor

    SciTech Connect (OSTI)

    Sappok, Alex; Prikhodko, Vitaly Y; Parks, II, James E

    2010-01-01

    Accurate knowledge of diesel particulate filter (DPF) loading is critical for robust and efficient operation of the combined engine-exhaust aftertreatment system. Furthermore, upcoming on-board diagnostics regulations require on-board technologies to evaluate the status of the DPF. This work describes the application of radio frequency (RF) based sensing techniques to accurately measure DPF soot levels and the spatial distribution of the accumulated material. A 1.9L GM turbo diesel engine and a DPF with an RF-sensor were studied. Direct comparisons between the RF measurement and conventional pressure-based methods were made. Further analysis of the particulate matter loading rates was obtained with a mass-based soot emission measurement instrument (TEOM). Comparison with pressure drop measurements show the RF technique is unaffected by exhaust flow variations and exhibits a high degree of sensitivity to DPF soot loading and good dynamic response. Additional computational and experimental work further illustrates the spatial resolution of the RF measurements. Based on the experimental results, the RF technique shows significant promise for improving DPF control enabling optimization of the combined engine-aftertreatment system for improved fuel economy and extended DPF service life.

  10. TOXICOLOGICAL EVALUATION OF REALISTIC EMISSIONS OF SOURCE AEROSOLS (TERESA): APPLICATION TO POWER PLANT-DERIVED PM2.5

    SciTech Connect (OSTI)

    Annette C. Rohr; Petros Koutrakis; John Godleski

    2011-03-31

    Determining the health impacts of different sources and components of fine particulate matter (PM2.5) is an important scientific goal, because PM is a complex mixture of both inorganic and organic constituents that likely differ in their potential to cause adverse health outcomes. The TERESA (Toxicological Evaluation of Realistic Emissions of Source Aerosols) study focused on two PM sources - coal-fired power plants and mobile sources - and sought to investigate the toxicological effects of exposure to realistic emissions from these sources. The DOE-EPRI Cooperative Agreement covered the performance and analysis of field experiments at three power plants. The mobile source component consisted of experiments conducted at a traffic tunnel in Boston; these activities were funded through the Harvard-EPA Particulate Matter Research Center and will be reported separately in the peer-reviewed literature. TERESA attempted to delineate health effects of primary particles, secondary (aged) particles, and mixtures of these with common atmospheric constituents. The study involved withdrawal of emissions directly from power plant stacks, followed by aging and atmospheric transformation of emissions in a mobile laboratory in a manner that simulated downwind power plant plume processing. Secondary organic aerosol (SOA) derived from the biogenic volatile organic compound {alpha}-pinene was added in some experiments, and in others ammonia was added to neutralize strong acidity. Specifically, four scenarios were studied at each plant: primary particles (P); secondary (oxidized) particles (PO); oxidized particles + secondary organic aerosol (SOA) (POS); and oxidized and neutralized particles + SOA (PONS). Extensive exposure characterization was carried out, including gas-phase and particulate species. Male Sprague Dawley rats were exposed for 6 hours to filtered air or different atmospheric mixtures. Toxicological endpoints included (1) breathing pattern; (2) bronchoalveolar lavage (BAL) fluid cytology and biochemistry; (3) blood cytology; (4) in vivo oxidative stress in heart and lung tissue; and (5) heart and lung histopathology. In addition, at one plant, cardiac arrhythmias and heart rate variability (HRV) were evaluated in a rat model of myocardial infarction. Statistical analyses included analyses of variance (ANOVA) to determine differences between exposed and control animals in response to different scenario/plant combinations; univariate analyses to link individual scenario components to responses; and multivariate analyses (Random Forest analyses) to evaluate component effects in a multipollutant setting. Results from the power plant studies indicated some biological responses to some plant/scenario combinations. A number of significant breathing pattern changes were observed; however, significant clinical changes such as specific irritant effects were not readily apparent, and effects tended to be isolated changes in certain respiratory parameters. Some individual exposure scenario components appeared to be more strongly and consistently related to respiratory parameter changes; however, the specific scenario investigated remained a better predictor of response than individual components of that scenario. Bronchoalveolar lavage indicated some changes in cellularity of BAL fluid in response to the POS and PONS scenarios; these responses were considered toxicologically mild in magnitude. No changes in blood cytology were observed at any plant or scenario. Lung oxidative stress was increased with the POS scenario at one plant, and cardiac oxidative stress was increased with the PONS scenario also at one plant, suggesting limited oxidative stress in response to power plant emissions with added atmospheric constituents. There were some mild histological findings in lung tissue in response to the P and PONS scenarios. Finally, the MI model experiments indicated that premature ventricular beat frequency was increased at the plant studied, while no changes in heart rate, HRV, or electrocardiographic intervals were observed. Overall, the

  11. Mechanisms of particulate matter formation in spark-ignition engines. 2: Effect of fuel, oil, and catalyst parameters

    SciTech Connect (OSTI)

    Kayes, D.; Hochgreb, S.

    1999-11-15

    A combined experimental and modeling effort was performed in order to understand how particulate matter (PM) is formed in spark-ignition (SI) internal combustion engines. Fuel type and fuel/air ratio strongly affect particle concentrations. PM emissions vary by up to 6 orders of magnitude between fuels at the same fuel/air ratio. Minimum PM concentrations are emitted at a global fuel/air ratio within 10% of stoichiometric, with the exact value depending on the particular fuel. Concentrations can increase by more than 3 orders of magnitude when the fuel/air ratio is either increased or decreased 30% from stoichiometric. Particles derived from oil consumption were found to be between 0 and 40% of the PM concentration for the oils used in the present experiments. Differences in PM emissions with and without the catalytic converter are not statistically significant. Particulate number and mass concentrations plus particle sizes are addressed in this paper, as is the correlation between PM and hydrocarbon (HC) emissions.

  12. Fuel-Neutral Studies of PM Transportation Emissions

    SciTech Connect (OSTI)

    Stewart, Mark L.; Zelenyuk, Alla; Howden, Ken

    2012-11-15

    New gasoline engine technologies such as Spark Ignition Direct Injection (SIDI), Gasoline Direct Injection Compression Ignition (GDICI), and Reaction Controlled Compression Ignition (RCCI) offer the possibility of dramatically increasing the fuel efficiency of future vehicles. One drawback to these advanced engines is that they have the potential to produce higher levels of exhaust particulates than current Port Fuel Injection (PFI) engines. Regulation of engine particulate emissions in Europe is moving from mass-based standards toward number-based standards. Due to growing health concerns surrounding nano-aerosols, it is likely that similar standards will eventually be applied in the United States. This would place more emphasis on the reliable removal of smaller particles, which make up the vast majority of the particulates generated on a number basis. While Diesel Particulate Filters (DPF) have become standard, different filter systems would likely be required for advanced gasoline vehicles, due to factors such as differing particulate properties and higher exhaust temperatures. High exhaust temperatures can limit the accumulation of a soot cake, which performs most of the actual filtration in a typical DPF system.

  13. Particulate and gaseous organic receptor modeling for the southern California Air Quality Study. Final report

    SciTech Connect (OSTI)

    Watson, J.G.; Chow, J.G.; Lu, Z.; Gertler, A.W.

    1993-11-01

    The Chemical Mass Balance (CMB) receptor model was applied to the chemically-speciated diurnal particulate matter samples and volatile organic compound (VOC) acquired during the summer and fall campaigns of the Southern California Air Quality Study (SCAQS). Source profiles applicable to the Los Angeles area were used to apportion PM[sub (2.5)] and PM[sub (10)] to primary paved road dust, primary construction dust, primary motor vehicle exhaust, primary marine aerosol, secondary ammonium nitrate, and secondary ammonium sulfate. Nonmethane hydrocarbon was apportioned to motor vehicle exhaust, liquid fuel, gasoline vapor, gas leaks, architectural and industrial coatings, and biogenic emissions. Suspended dust was the major contributor to PM(10) during the summer, while secondary ammonium nitrate and primary motor vehicle exhaust contributions were high in the fall. Motor vehicle exhaust was the major contributor to nonmethane hydrocarbons, ranging from 30% to 70% of the total.

  14. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    SciTech Connect (OSTI)

    Greenblatt, Jeffery B.

    2013-10-10

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants, targets were less well-defined, but while all three scenarios were able to make significant reductions in ROG, NOx and PM2.5 both statewide and in the two regional air basins, they may nonetheless fall short of what will be required by future federal standards. Specifically, in Scenario 1, regional NOx emissions are approximately three times the estimated targets for both 2023 and 2032, and in Scenarios 2 and 3, NOx emissions are approximately twice the estimated targets. Further work is required in this area, including detailed regional air quality modeling, in order to determine likely pathways for attaining these stringent targets.

  15. Oil shale fines process developments in Brazil

    SciTech Connect (OSTI)

    Lisboa, A.C.; Nowicki, R.E. ); Piper, E.M. )

    1989-01-01

    The Petrobras oil shale retorting process, utilizes the particle range of +1/4 inch - 3 1/2 inches. The UPI plant in Sao Mateus do Sul has over 106,000 hours of operation, has processed over 6,200,000 metric tons of shale and has produced almost 3,000,000 barrels of shale oil. However, the nature of the raw oil shale is such that the amount of shale less than 1/4 inch that is mined and crushed and returned to the mine site is about 20 percent, thereby, increasing the cost of oil produced by a substantial number. Petrobras has investigated several systems to process the fines that are not handled by the 65 MTPH UPI plant and the 260 MTPH commercial plant. This paper provides an updated status of each of these processes in regard to the tests performed, potential contributions to an integrated use of the oil shale mine, and future considerations.

  16. Method of making fine-grained triaminotrinitrobenzene

    DOE Patents [OSTI]

    Benziger, Theodore M. (Santa Fe, NM)

    1984-01-01

    A method of forming a fine-grained species of the insensitive high explosive sym-triaminotrinitrobenzene (TATB) without grinding. In accordance with the method, 1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) is aminated by reaction with gaseous ammonia in an emulsion of toluene in water. The ratio of water to toluene in the emulsion is selected so that toluene is the dispersed phase in the emulsion. The size of the dispersed TCTNB-containing toluene droplets determines the particle size of the resulting TATB. The emulsion is preferably formed with an emulsifier such as ammonium oleate, which may be generated in situ from oleic acid, and stabilized with a protective colloid such as polyvinyl alcohol.

  17. Method of making fine-grained triaminotrinitrobenzene

    DOE Patents [OSTI]

    Benziger, T.M.

    1983-07-26

    A method is given for forming a fine-grained species of the insensitive high explosive sym-triaminotrinitrobenzene (TATB) without grinding. In accordance with the method, 1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) is aminated by reaction with gaseous ammonia in an emulsion of toluene in water. The ratio of water to toluene in the emulsion is selected so that toluene is the dispersed phase in the emulsion. The size of the dispersed TCTNB-containing toluene droplets determines the particle size of the resulting TATB. The emulsion is preferably formed with an emulsifier such as ammonium oleate, which may be generated in situ from oleic acid, and stabilized with a protective colloid such as polyvinyl alcohol.

  18. Source Contribution Analysis of Surface Particulate Polycyclic Aromatic Hydrocarbon Concentrations in Northeastern Asia by Source-receptor Relationships

    SciTech Connect (OSTI)

    Inomata, Yayoi; Kajino, Mizuo; Sato, Keiichi; Ohara, Toshimasa; Kurokawa, Jun-Ichi; Ueda, Hiromasa; Tang, Ning; Hayakawa, Kazuichi; Ohizumi, Tsuyoshi; Akimoto, Hajime

    2013-11-01

    We analyzed the sourceereceptor relationships for particulate polycyclic aromatic hydrocarbon (PAH) concentrations in northeastern Asia using an aerosol chemical transport model. The model successfully simulated the observed concentrations. In Beijing (China) benzo[a]pyren (BaP) concentrations are due to emissions from its own domain. In Noto, Oki and Tsushima (Japan), transboundary transport from northern China (>40N, 40-60%) and central China (30-40N, 10-40%) largely influences BaP concentrations from winter to spring, whereas the relative contribution from central China is dominant (90%) in Hedo. In the summer, the contribution from Japanese domestic sources increases (40-80%) at the 4 sites. Contributions from Japan and Russia are additional source of BaP over the northwestern Pacific Ocean in summer. The contribution rates for the concentrations from each domain are different among PAH species depending on their particulate phase oxidation rates. Reaction with O3 on particulate surfaces may be an important component of the PAH oxidation processes.

  19. Progression of soot cake layer properties during the systematic regeneration of diesel particulate filters measured with neutron tomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Toops, Todd J.; Pihl, Josh A.; Finney, Charles E. A.; Gregor, Jens; Bilheux, Hassina

    2015-01-16

    Although particulate filters (PFs) have been a key component of the emission control system for modern diesel engines, there remain significant questions about the basic regeneration behavior of the filters and how it changes with accumulation of increasing soot layers. This effort describes a systematic deposition and regeneration of particulate matter in 25-mm diameter 76-mm long wall-flow PFs composed of silicon carbide (SiC) material. The initial soot distributions were analyzed for soot cake thickness using a nondestructive neutron imaging technique. With the PFs intact, it was then possible to sequentially regenerate the samples and reanalyze them, which was performedmoreafter nominal 20, 50, and 70 % regenerations. The loaded samples show a relatively uniform distribution of particulate with an increasing soot cake thickness and nearly identical initial density of 70 mg/cm3. Throughout regeneration, the soot cake thickness initially decreases significantly while the density increases to 8090 mg/cm3. After ~50 % regeneration, the soot cake thickness stays relatively constant, but instead, the density decreases as pores open up in the layer (~35 mg/cm3 at 70 % regeneration). Complete regeneration initially occurs at the rear of the PF channels. With this information, a conceptual model of the regeneration is proposed.less

  20. Assessing the potential visibility benefits of Clean Air Act Title IV emission reductions

    SciTech Connect (OSTI)

    Trexler, E.C. Jr.; Shannon, J.D.

    1995-06-01

    Assessments are made of the benefits of the 1990 Clean Air Act Title IV (COVE), Phase 2, SO2 and NOX reduction provisions, to the visibility in typical eastern and western Class 1 areas. Probable bands of visibility impairment distribution curves are developed for Shenandoah National Park, Smoky Mountain National Park and the Grand Canyon National Park, based on the existing emissions, ``Base Case``, and for the COVE emission reductions, ``CAAA Case``. Emission projections for 2010 are developed with improved versions of the National Acid Precipitation Assessment Program emission projection models. Source-receptor transfer matrices created with the Advanced Statistical Trajectory Regional Air Pollution (ASTRAP) model are used with existing emission inventories and with the emission projections to calculate atmospheric concentrations of sulfate and nitrate at the receptors of interest for existing and projected emission scenarios. The Visibility Assessment Scoping Model (VASM) is then used to develop distributions of visibility impairment. VASM combines statistics of observed concentrations of particulate species and relative humidity with ASTRAP calculations of the relative changes in atmospheric sulfate and nitrate particulate concentrations in a Monte Carlo approach to produce expected distributions of hourly particulate concentrations and RH. Light extinction relationships developed in theoretical and field studies are then used to calculate the resulting distribution of visibility impairment. Successive Monte Carlo studies are carried out to develop sets of visibility impairment distributions with and without the COVE emission reductions to gain insight into the detectability of expected visibility improvements.

  1. Method and apparatus for injecting particulate media into the ground

    DOE Patents [OSTI]

    Dwyer, Brian P.; Dwyer, Stephen F.; Vigil, Francine S.; Stewart, Willis E.

    2004-12-28

    An improved method and apparatus for injecting particulate media into the ground for constructing underground permeable reactive barriers, which are used for environmental remediation of subsurface contaminated soil and water. A media injector sub-assembly attached to a triple wall drill string pipe sprays a mixture of active particulate media suspended in a carrier fluid radially outwards from the sub-assembly, at the same time that a mixing fluid is sprayed radially outwards. The media spray intersects the mixing spray at a relatively close distance from the point of injection, which entrains the particulate media into the mixing spray and ensures a uniform and deep dispersion of the active media in the surrounding soil. The media injector sub-assembly can optionally include channels for supplying compressed air to an attached down-the-hole hammer drive assembly for use during drilling.

  2. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  3. For Cape Wind, Summer Breeze Makes Offshore Wind Feel Fine |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    For Cape Wind, Summer Breeze Makes Offshore Wind Feel Fine For Cape Wind, Summer Breeze Makes ... one of the world's largest wind farms, the Department's Loan Programs Office ...

  4. EERE Success Story-Radio Frequency Diesel Particulate Filter Sensor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduces Fuel Consumption, Wins R&D 100 Award | Department of Energy Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award EERE Success Story-Radio Frequency Diesel Particulate Filter Sensor Reduces Fuel Consumption, Wins R&D 100 Award October 15, 2014 - 4:51pm Addthis Developed jointly by Corning, the FEV Group, Maguffin Microwave, Detroit Diesel, and Oak Ridge National Laboratory (ORNL) in cooperation with the New York City Department of

  5. Effects of Advanced Combustion Technologies on Particulate Matter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from Advanced Technologies Efficient Emissions Control for Multi-Mode Lean DI Engines Measurement and Characterization of Lean NOx Adsorber Regeneration and...

  6. Field Emission Measurements from Niobium Electrodes

    SciTech Connect (OSTI)

    M. BastaniNejad, P.A. Adderley, J. Clark, S. Covert, J. Hansknecht, C. Hernandez-Garcia, R. Mammei, M. Poelker

    2011-03-01

    Increasing the operating voltage of a DC high voltage photogun serves to minimize space charge induced emittance growth and thereby preserve electron beam brightness, however, field emission from the photogun cathode electrode can pose significant problems: constant low level field emission degrades vacuum via electron stimulated desorption which in turn reduces photocathode yield through chemical poisoning and/or ion bombardment and high levels of field emission can damage the ceramic insulator. Niobium electrodes (single crystal, large grain and fine grain) were characterized using a DC high voltage field emission test stand at maximum voltage -225kV and electric field gradient > 10MV/m. Niobium electrodes appear to be superior to diamond-paste polished stainless steel electrodes.

  7. Imaging of Diesel Particulate Filters using a High-Flux Neutron...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified...

  8. Testing an Active Diesel Particulate Filter on a 2-Cycle Marine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Testing an Active Diesel Particulate Filter on a 2-Cycle Marine Engine Presentation given at DEER 2006, August 20-24, ...

  9. Residence times of fine tropospheric aerosols as determined by {sup 210}Pb progeny.

    SciTech Connect (OSTI)

    Marley, N. A.; Gaffney, J. S.; Drayton, P. J.; Cunningham, M. M.; Mielcarek, C.; Ravelo, R.; Wagner, C.

    1999-10-05

    Fine tropospheric aerosols can play important roles in the radiative balance of the atmosphere. The fine aerosols can act directly to cool the atmosphere by scattering incoming solar radiation, as well as indirectly by serving as cloud condensation nuclei. Fine aerosols, particularly carbonaceous soots, can also warm the atmosphere by absorbing incoming solar radiation. In addition, aerosols smaller than 2.5 {micro}m have recently been implicated in the health effects of air pollution. Aerosol-active radioisotopes are ideal tracers for the study of atmospheric transport processes. The source terms of these radioisotopes are relatively well known, and they are removed from the atmosphere only by radioactive decay or by wet or dry deposition of the host aerosol. The progeny of the primordial radionuclide {sup 238}U are of particular importance to atmospheric studies. Uranium-238 is common throughout Earth's crust and decays to the inert gas {sup 222}Rn, which escapes into the atmosphere. Radon-222 decays by the series of alpha and beta emissions shown in Figure 1 to the long-lived {sup 210}Pb. Once formed, {sup 210}Pb becomes attached to aerosol particles with average attachment times of 40 s to 3 min.

  10. Emissions characteristics of Military Helicopter Engines Fueled with JP-8 and a Fischer-Tropsch Fuel

    SciTech Connect (OSTI)

    Corporan, E.; DeWitt, M.; Klingshirn, Christopher D; Striebich, Richard; Cheng, Mengdawn

    2010-01-01

    The rapid growth in aviation activities and more stringent U.S. Environmental Protection Agency regulations have increased concerns regarding aircraft emissions, due to their harmful health and environmental impacts, especially in the vicinity of airports and military bases. In this study, the gaseous and particulate-matter emissions of two General Electric T701C engines and one T700 engine were evaluated. The T700 series engines power the U.S. Army's Black Hawk and Apache helicopters. The engines were fueled with standard military JP-8 fuel and were tested at three power settings. In addition, one of the T701C engines was operated on a natural-gas-derived Fischer-Tropsch synthetic paraffinic kerosene jet fuel. Test results show that the T701C engine emits significantly lower particulate-matter emissions than the T700 for all conditions tested. Particulate-matter mass emission indices ranged from 0.2-1.4 g/kg fuel for the T700 and 0.2-0.6 g/kg fuel for the T701C. Slightly higher NOx and lower CO emissions were observed for the T701C compared with the T700. Operation of the T701C with the Fischer-Tropsch fuel rendered dramatic reductions in soot emissions relative to operation on JP-8, due primarily to the lack of aromatic compounds in the alternative fuel. The Fischer-Tropsch fuel also produced smaller particles and slight reductions in CO emissions.

  11. A New CFD Model for understanding and Managing Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration | Department of Energy CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon 2004_deer_hou.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Vehicle Evaluation of Downsized Dow ACM DPF

  12. Electrically heated particulate matter filter with recessed inlet end plugs

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Ament, Frank (Troy, MI)

    2012-02-21

    A particulate matter (PM) filter includes filter walls having inlet ends and outlet ends. First adjacent pairs of the filter walls define inlet channels. Second adjacent pairs of the filter walls define outlet channels. Outlet end plugs are arranged in the inlet channels adjacent to the output ends. Inlet end plugs arranged in the outlet channels spaced from the inlet ends.

  13. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  14. Electrically heated particulate filter diagnostic systems and methods

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2009-09-29

    A system that diagnoses regeneration of an electrically heated particulate filter is provided. The system generally includes a grid module that diagnoses a fault of the grid based on at least one of a current signal and a voltage signal. A diagnostic module at least one of sets a fault status and generates a warning signal based on the fault of the grid.

  15. Inductively heated particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore Jr., Michael J; Kirby, Kevin W; Phelps, Amanda; Gregoire, Daniel J

    2012-10-23

    A system includes a particulate matter (PM) filter with an upstream end for receiving exhaust gas, a downstream end and zones. The system also includes a heating element. A control module selectively activates the heating element to inductively heat one of the zones.

  16. Stratification of particulate and VOC pollutants in horizontal-flow-paint spray booths. Report for September 1988-October 1989

    SciTech Connect (OSTI)

    Darvin, C.H.

    1990-01-01

    The paper discusses stratification of particulate and volatile organic compound (VOC) pollutants in horizontal flow paint spray booths, as part of a joint U.S. Air Force/EPA research and development program on emissions from paint spray booths. The test program discussed in the paper was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control strategies are being developed. The results of one series of tests indicate that the pollutants, both particulate and VOC, fall to the lower level of the booth or stratify at the level at which they were generated. This might be expected since the densities of typical pollutants found in spray booths are greater than air. The results showed, however, that the concentration of pollutants in the lower level prior to exiting the booth was significantly greater than expected. Data indicated that, for the 16 ft (4.9 m) high booth tested, the concentration at the exit of the booth below the 8 ft (2.4 m) level was 5-25 times greater than the concentration above that level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The concentrated zone could be directed to a proportionally smaller VOC control system of significantly less capital and operating cost.

  17. Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol-Diesel Blends

    SciTech Connect (OSTI)

    Merritt, P. M.; Ulmet, V.; McCormick, R. L.; Mitchell, W. E.; Baumgard, K. J.

    2005-11-01

    Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent). Benzene emissions were reduced by up to 50 percent with the ethanol-blended fuels. Emissions of 1,3-butadiene were also substantially decreased, with reductions ranging from 24 to 82 percent. Isolated trends were noted for certain PAHs. There was a decrease in 1-nitropyrene with use of ethanol in all cases. Particulate phase 1-nitropyrene was reduced from 18 to 62 percent. There was also a general increase in the proportion of heavy PAHs in the particulate phase with ethanol use, and although less pronounced, a general decrease in light PAHs in the particulate phase.

  18. Electrically heated particulate filter regeneration methods and systems for hybrid vehicles

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-10-12

    A control system for controlling regeneration of a particulate filter for a hybrid vehicle is provided. The system generally includes a regeneration module that controls current to the particulate filter to initiate regeneration. An engine control module controls operation of an engine of the hybrid vehicle based on the control of the current to the particulate filter.

  19. Coal-fueled diesel technology development Emissions Control

    SciTech Connect (OSTI)

    Van Kleunen, W.; Kaldor, S.; Gal, E.; Mengel, M.; Arnold, M.

    1994-01-01

    GEESI Emissions Control program activity ranged from control concept testing of 10 CFM slipstream from a CWS fuel single cylinder research diesel engine to the design, installation, and operation of a full-size Emissions Control system for a full-size CWS fuel diesel engine designed for locomotive operation.Early 10 CFM slipstream testing program activity was performed to determine Emissions Characteristics and to evaluate Emissions Control concepts such a Barrier filtration, Granular bed filtration, and Cyclone particulate collection for reduction of particulate and gaseous emissions. Use of sorbent injection into the engine exhaust gas upstream of the barrier filter or use of sorbent media in the granular bed filter were found to provide reduction of exhaust gas SO{sub 2} and NO{sub x} in addition to collection of ash particulate. Emergence of the use of barrier filtration as a most practical Emissions Control concept disclosed a need to improve cleanability of the filter media in order to avoid reduction of turbocharger performance by excessive barrier filter pressure drop. The next progression of program activity, after the slipstream feasibility state, was 500 CFM cold flow testing of control system concepts. The successful completion of 500 CFM cold flow testing of the Envelope Filter led to a subsequent progression to a similar configuration Envelope Filter designed to operate at 500 CFM hot gas flow from the CWS fuel research diesel engine in the GETS engine test laboratory. This Envelope Filter included the design aspect proven by cold flow testing as well as optimization of the selection of the installed filter media.

  20. Vehicle Technologies Office Merit Review 2014: Fuel-Neutral Studies of Particulate Matter Transport Emissions

    Broader source: Energy.gov [DOE]

    Presentation given by Pacific Northwest National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fuel...

  1. A Comprehensive Program for Measurement of Military Aircraft Emissions

    SciTech Connect (OSTI)

    Cheng, Mengdawn

    2009-11-01

    Emissions of gases and particulate matter by military aircraft were characterized inplume by 'extractive' and 'optical remote-sensing (ORS)' technologies. Non-volatile particle size distribution, number and mass concentrations were measured with good precision and reproducibly. Time-integrated particulate filter samples were collected and analyzed for smoke number, elemental composition, carbon contents, and sulfate. Observed at EEP the geometric mean diameter (as measured by the mobility diameter) generally increased as the engine power setting increased, which is consistent with downstream observations. The modal diameters at the downstream locations are larger than that at EEP at the same engine power level. The results indicate that engine particles were processed by condensation, for example, leading to particle growth in-plume. Elemental analysis indicated little metals were present in the exhaust, while most of the exhaust materials in the particulate phase were carbon and sulfate (in the JP-8 fuel). CO, CO{sub 2}, NO, NO{sub 2}, SO{sub 2}, HCHO, ethylene, acetylene, propylene, and alkanes were measured. The last five species were most noticeable under engine idle condition. The levels of hydrocarbons emitted at high engine power level were generally below the detection limits. ORS techniques yielded real-time gaseous measurement, but the same techniques could not be extended directly to ultrafine particles found in all engine exhausts. The results validated sampling methodology and measurement techniques used for non-volatile particulate aircraft emissions, which also highlighted the needs for further research on sampling and measurement for volatile particulate matter and semi-volatile species in the engine exhaust especially at the low engine power setting.

  2. Production of a pellet fuel from Illinois coal fines. Technical report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.

    1995-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. For this effort, we will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. Previously it has been decided that corn starch would be used as binder and a roller-and-die mill would be used for pellet manufacture. A quality starch binder has been identified and tested. To potentially lower binder costs, a starch that costs about 50% of the high quality starch was tested. Results indicate that the lower cost starch will not lower binder cost because more is required to produce a comparable quality pellet. Also, a petroleum in water emulsion was evaluated as a potential binder. The compound seemed to have adhesive properties but was found to be a poor binder. Arrangements have been made to collect a waste slurry from the mine previously described.

  3. Cardiopulmonary Toxicity Induced by Ambient Particulate Matter (BI City Concentrated Ambient Particle Study)

    SciTech Connect (OSTI)

    Annette Rohr; James Wagner Masako Morishita; Gerald Keeler; Jack Harkema

    2010-06-30

    Alterations in heart rate variability (HRV) have been reported in rodents exposed to concentrated ambient particles (CAPs) from different regions of the United States. The goal of this study was to compare alterations in cardiac function induced by CAPs in two distinct regional atmospheres. AirCARE 1, a mobile laboratory with an EPA/Harvard fine particle (particulate matter <2.5 {micro}m; PM{sub 2.5}) concentrator was located in urban Detroit, MI, where the PM mixture is heavily influenced by motor vehicles, and in Steubenville, OH, where PM is derived primarily from long-range transport and transformation of power plant emissions, as well as from local industrial operations. Each city was studied during both winter and summer months, for a total of four sampling periods. Spontaneously hypertensive rats instrumented for electrocardiogram (ECG) telemetry were exposed to CAPs 8 h/day for 13 consecutive days during each sampling period. Heart rate (HR), and indices of HRV (standard deviation of the average normal-to-normal intervals [SDNN]; square root of the mean squared difference of successive normal-to-normal intervals [rMSSD]), were calculated for 30-minute intervals during exposures. A large suite of PM components, including nitrate, sulfate, elemental and organic carbon, and trace elements, were monitored in CAPs and ambient air. In addition, a unique sampler, the Semi-Continuous Elements in Air Sampler (SEAS) was employed to obtain every-30-minute measurements of trace elements. Positive matrix factorization (PMF) methods were applied to estimate source contributions to PM{sub 2.5}. Mixed modeling techniques were employed to determine associations between pollutants/CAPs components and HR and HRV metrics. Mean CAPs concentrations in Detroit were 518 and 357 {micro}g/m{sup 3} (summer and winter, respectively) and 487 and 252 {micro}g/m{sup 3} in Steubenville. In Detroit, significant reductions in SDNN were observed in the summer in association with cement/lime, iron/steel, and gasoline/diesel factors, while associations with the sludge incineration factor and components were less consistent. In winter, increases in HR were associated with a refinery factor and its components. CAPs-associated HR decreases in winter were linked to sludge incineration, cement/lime, and coal/secondary factors and the majority of their associated components. Specific relationships for increased rMSSD in winter were difficult to determine due to lack of consistency between factors and associated constituents. In Steubenville, we observed significant changes in HR (both increases and decreases), SDNN, and rMSSD in the summer, but not in the winter. We examined associations between individual source factors/PM components and HRV metrics segregated by predominant wind direction (NE or SW). Changes in HR (both increases and decreases) were linked with metal processing, waste incineration, and iron/steel factors along with most of their associated elemental constituents. Reductions in SDNN were associated with metal processing, waste incineration, and mobile source factors and the majority of elements loading onto these factors. There were no consistent associations between changes in rMSSD and source factors/components. Despite the large number of coal-fired power plants in the region, and therefore the large contribution of secondary sulfate to overall PM mass, we did not observe any associations with the coal/secondary factor or with the majority of its associated components. There were several inconsistencies in our results which make definitive conclusions difficult. For example, we observed opposing signs of effect estimates with some components depending on season, and with others depending on wind direction. In addition, our extensive dataset clearly would be subject to issues of multiple comparisons, and the 'true' significant results are unknown. Overall, however, our results suggest that acute changes in cardiac function were most strongly associated with local industrial sources. Results for coal-fired power plant-derived PM were

  4. Emission Controls for Heavy-Duty Trucks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controls for Heavy-Duty Trucks Emission Controls for Heavy-Duty Trucks Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_clerc.pdf More Documents & Publications SCRT Technology for Retrofit of Heavy-Duty Diesel Applications Effects of Biomass Fuels on Engine & System Out Emissions for Short Term Endurance Development of SCR on Diesel Particulate

  5. A Comparison of Two Gasoline and Two Diesel Cars with Varying Emission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Technologies | Department of Energy A Comparison of Two Gasoline and Two Diesel Cars with Varying Emission Control Technologies A Comparison of Two Gasoline and Two Diesel Cars with Varying Emission Control Technologies 2002 DEER Conference Presentation: Ecotraffic Environmental Consultants PDF icon 2002_deer_ahlvik.pdf More Documents & Publications Summary of Swedish Experiences on CNG and "Clean" Diesel Buses Diesel Particulate Filters: Market Introducution in Europe

  6. Photocatalytic hydrogen production using visible-light-responsive Ta{sub 3}N{sub 5} photocatalyst supported on monodisperse spherical SiO{sub 2} particulates

    SciTech Connect (OSTI)

    Liu, Xiaoming; Zhao, Lan; Domen, Kazunari; Takanabe, Kazuhiro

    2014-01-01

    Graphical abstract: A simple and effective solgel process followed by nitridation in an NH{sub 3} flow has been developed to deposit Ta{sub 3}N{sub 5} semiconductor photocatalyst layers onto monodisperse spherical SiO{sub 2} particles. The obtained Ta{sub 3}N{sub 5}/SiO{sub 2} particles maintain an original spherical morphology of SiO{sub 2} and a sub-micrometer size with a narrow size distribution and without aggregation. The presence of SiO{sub 2} support shows at least no detrimental effects on photocatalytic activity, but tunes the secondary particle size to control dispersibility of the photocatalyst in the solution. - Highlights: Fine nanoparticles of Ta{sub 3}N{sub 5} were immobilized on the surfaces of SiO{sub 2} giving SiO{sub 2}@Ta{sub 3}N{sub 5} coreshell spheres successfully produced H{sub 2} from methanol solution under visible light. The presence of support (SiO{sub 2}) ensures the dispersion of the particulate in solution maintaining high photocatalytic activity of Ta{sub 3}N{sub 5}. The obtained supported photocatalyst gives uniform size distribution and control the degree of dispersibility in the solution, which may control nature of light absorption and reflection of the photoreactor. - Abstract: Fine nanoparticles of Ta{sub 3}N{sub 5} (1020 nm) were synthesized on the surfaces of SiO{sub 2} spheres with a diameter of ?550 nm. A solgel method was used to modify the surface of SiO{sub 2} with Ta{sub 2}O{sub 5} from TaCl{sub 5} dissolved in ethanol in the presence of citric acid and polyethylene glycol. The resulting oxide composites were treated in an NH{sub 3} flow at 1123 K to form coreshell structured Ta{sub 3}N{sub 5}/SiO{sub 2} sub-microspheres. The obtained samples were characterized using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDX), transmission electron microscopy (TEM), and photocatalytic activity measurements for H{sub 2} evolution from an aqueous methanol solution. The XRD results demonstrate the expected sequential formation of Ta{sub 2}O{sub 5} layers, followed by Ta{sub 3}N{sub 5} after nitridation on the Ta{sub 2}O{sub 5}/SiO{sub 2} composite. SEM and TEM observations indicate that the obtained Ta{sub 3}N{sub 5}/SiO{sub 2} sub-microspheres have a uniform size distribution with high crystallinity and an obvious coreshell structure. The presence of support maintained the intrinsic photocatalytic activity of Ta{sub 3}N{sub 5} nanoparticles, but it did drastically improve the dispersion of the photocatalysts in the solution. This study proposes the use of an inert support in photocatalytic reactors to improve ease of handling the powder photocatalyst for gas-phase photocatalysis and the suspension of the solution, controlling nature of light harvesting and degree of scattering of the photoreactor.

  7. Fluidizable particulate materials and methods of making same

    DOE Patents [OSTI]

    Gupta, Raghubir P. (Durham, NC)

    1999-01-01

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  8. Design characteristics for facilities which process hazardous particulate

    SciTech Connect (OSTI)

    Abeln, S.P.; Creek, K.; Salisbury, S.

    1998-12-01

    Los Alamos National Laboratory is establishing a research and processing capability for beryllium. The unique properties of beryllium, including light weight, rigidity, thermal conductivity, heat capacity, and nuclear properties make it critical to a number of US defense and aerospace programs. Concomitant with the unique engineering properties are the health hazards associated with processing beryllium in a particulate form and the potential for worker inhalation of aerosolized beryllium. Beryllium has the lowest airborne standard for worker protection compared to all other nonradioactive metals by more than an order of magnitude. This paper describes the design characteristics of the new beryllium facility at Los Alamos as they relate to protection of the workforce. Design characteristics to be reviewed include; facility layout, support systems to minimize aerosol exposure and spread, and detailed review of the ventilation system design for general room air cleanliness and extraction of particulate at the source.

  9. Fluidizable particulate materials and methods of making same

    SciTech Connect (OSTI)

    Gupta, R.P.

    1999-10-26

    The invention provides fluidizable, substantially spherical particulate material of improved attrition resistance having an average particle size from about 100 to about 400 microns useful as sorbents, catalysts, catalytic supports, specialty ceramics or the like. The particles are prepared by spray drying a slurry comprising inorganic starting materials and an organic binder. Exemplary inorganic starting materials include mixtures of zinc oxide with titanium dioxide, or with iron oxide, alumina or the like. Exemplary organic binders include polyvinyl alcohol, hydroxypropylemethyl cellulose, polyvinyl acetate and the like. The spray dried particles are heat treated at a first temperature wherein organic binder material is removed to thereby provide a porous structure to the particles, and thereafter the particles are calcined at a higher temperature to cause reaction of the inorganic starting materials and to thereby form the final inorganic particulate material.

  10. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update (EIA)

    3. Methane Emissions 3.1. Total emissions The major sources of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9 percent higher than the 2008 total of 724 MMTCO2e (Table 17). Methane emissions declined steadily from 1990 to 2001, as emissions from coal mining and landfills fell, then rose from 2002 to 2009 as a result of moderate increases in emissions related to energy,

  11. Stabilization void-fill encapsulation high-efficiency particulate filters

    SciTech Connect (OSTI)

    Alexander, R.G.; Stewart, W.E.; Phillips, S.J.; Serkowski, M.M.; England, J.L.; Boynton, H.C.

    1994-05-01

    This report discusses high-efficiency particulate air (HEPA) filter systems that which are contaminated with radionuclides are part of the nuclear fuel processing systems conducted by the US Department of Energy (DOE) and require replacement and safe and efficient disposal for plant safety. Two K-3 HEPA filters were removed from service, placed burial boxes, buried, and safely and efficiently stabilized remotely which reduced radiation exposure to personnel and the environment.

  12. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND)

    2003-04-08

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between the rows of filter elements are rows of high voltage discharge electrodes. Between the rows of discharge electrodes and the rows of filter elements are grounded perforated plates for creating electrostatic precipitation zones.

  13. Microwave mode shifting antenna system for regenerating particulate filters

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA; Gregoire, Daniel J [Thousand Oaks, CA

    2011-04-26

    A regeneration system comprises a particulate matter (PM) filter including a microwave energy absorbing surface, and an antenna system comprising N antennas and an antenna driver module that sequentially drives the antenna system in a plurality of transverse modes of the antenna system to heat selected portions of the microwave absorbing surface to regenerate the PM filter, where N is an integer greater than one. The transverse modes may include transverse electric (TE) and/or transverse magnetic (TM) modes.

  14. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    SciTech Connect (OSTI)

    K. Osseo-Asare; X. Zeng

    2002-01-01

    The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

  15. Modified approaches for high pressure filtration of fine clean coal

    SciTech Connect (OSTI)

    Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

    1995-12-31

    Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

  16. Topological Quantization in Units of the Fine Structure Constant (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect SciTech Connect Search Results Journal Article: Topological Quantization in Units of the Fine Structure Constant Citation Details In-Document Search Title: Topological Quantization in Units of the Fine Structure Constant Fundamental topological phenomena in condensed matter physics are associated with a quantized electromagnetic response in units of fundamental constants. Recently, it has been predicted theoretically that the time-reversal invariant topological

  17. Emissions of Transport Refrigeration Units with CARB Diesel, Gas-to-Liquid Diesel, and Emissions Control Devices

    SciTech Connect (OSTI)

    Barnitt, R. A.; Chernich, D.; Burnitzki, M.; Oshinuga, A.; Miyasato, M.; Lucht, E.; van der Merwe, D.; Schaberg, P.

    2010-05-01

    A novel in situ method was used to measure emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. Test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. Exhaust configurations were a stock muffler and a Thermo King pDPF diesel particulate filter. The TRU engine operating speeds were high and low, controlled by the TRU user interface. Results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine speeds. Application of a Thermo King pDPF reduced regulated emissions, sometimes almost entirely. The application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine speed, but showed an increase in oxides of nitrogen at low engine speed.

  18. Processing and Protection of Rare Earth Permanent Magnet Particulate for Bonded Magnet Applications

    SciTech Connect (OSTI)

    Peter Kelly Sokolowski

    2007-12-01

    Rapid solidification of novel mixed rare earth-iron-boron, MRE{sub 2}Fe{sub 14}B (MRE = Nd, Y, Dy; currently), magnet alloys via high pressure gas atomization (HPGA) have produced similar properties and structures as closely related alloys produced by melt spinning (MS) at low wheel speeds. Recent additions of titanium carbide and zirconium to the permanent magnet (PM) alloy design in HPGA powder (using He atomization gas) have made it possible to achieve highly refined microstructures with magnetic properties approaching melt spun particulate at cooling rates of 10{sup 5}-10{sup 6}K/s. By producing HPGA powders with the desirable qualities of melt spun ribbon, the need for crushing ribbon was eliminated in bonded magnet fabrication. The spherical geometry of HPGA powders is more ideal for processing of bonded permanent magnets since higher loading fractions can be obtained during compression and injection molding. This increased volume loading of spherical PM powder can be predicted to yield a higher maximum energy product (BH){sub max} for bonded magnets in high performance applications. Passivation of RE-containing powder is warranted for the large-scale manufacturing of bonded magnets in applications with increased temperature and exposure to humidity. Irreversible magnetic losses due to oxidation and corrosion of particulates is a known drawback of RE-Fe-B based alloys during further processing, e.g. injection molding, as well as during use as a bonded magnet. To counteract these effects, a modified gas atomization chamber allowed for a novel approach to in situ passivation of solidified particle surfaces through injection of a reactive gas, nitrogen trifluoride (NF{sub 3}). The ability to control surface chemistry during atomization processing of fine spherical RE-Fe-B powders produced advantages over current processing methodologies. In particular, the capability to coat particles while 'in flight' may eliminate the need for post atomization treatment, otherwise a necessary step for oxidation and corrosion resistance. Stability of these thin films was attributed to the reduction of each RE's respective oxide during processing; recognizing that fluoride compounds exhibit a slightly higher (negative) free energy driving force for formation. Formation of RE-type fluorides on the surface was evidenced through x-ray photoelectron spectroscopy (XPS). Concurrent research with auger electron spectroscopy has been attempted to accurately quantify the depth of fluoride formation in order to grasp the extent of fluorination reactions with spherical and flake particulate. Gas fusion analysis on coated powders (dia. <45 {micro}m) from an optimized experiment indicated an as-atomized oxygen concentration of 343ppm, where typical, nonpassivated RE atomized alloys exhibit an average of 1800ppm oxygen. Thermogravimetric analysis (TGA) on the same powder revealed a decreased rate of oxidation at elevated temperatures up to 300 C, compared to similar uncoated powder.

  19. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  20. The innate and adaptive immune response induced by alveolar macrophages exposed to ambient particulate matter

    SciTech Connect (OSTI)

    Miyata, Ryohei; Eeden, Stephan F. van

    2011-12-15

    Emerging epidemiological evidence suggests that exposure to particulate matter (PM) air pollution increases the risk of cardiovascular events but the exact mechanism by which PM has adverse effects is still unclear. Alveolar macrophages (AM) play a major role in clearing and processing inhaled PM. This comprehensive review of research findings on immunological interactions between AM and PM provides potential pathophysiological pathways that interconnect PM exposure with adverse cardiovascular effects. Coarse particles (10 {mu}m or less, PM{sub 10}) induce innate immune responses via endotoxin-toll-like receptor (TLR) 4 pathway while fine (2.5 {mu}m or less, PM{sub 2.5}) and ultrafine particles (0.1 {mu}m or less, UFP) induce via reactive oxygen species generation by transition metals and/or polyaromatic hydrocarbons. The innate immune responses are characterized by activation of transcription factors [nuclear factor (NF)-{kappa}B and activator protein-1] and the downstream proinflammatory cytokine [interleukin (IL)-1{beta}, IL-6, and tumor necrosis factor-{alpha}] production. In addition to the conventional opsonin-dependent phagocytosis by AM, PM can also be endocytosed by an opsonin-independent pathway via scavenger receptors. Activation of scavenger receptors negatively regulates the TLR4-NF-{kappa}B pathway. Internalized particles are subsequently subjected to adaptive immunity involving major histocompatibility complex class II (MHC II) expression, recruitment of costimulatory molecules, and the modulation of the T helper (Th) responses. AM show atypical antigen presenting cell maturation in which phagocytic activity decreases while both MHC II and costimulatory molecules remain unaltered. PM drives AM towards a Th1 profile but secondary responses in a Th1- or Th-2 up-regulated milieu drive the response in favor of a Th2 profile.

  1. Fine coal cleaning via the micro-mag process

    DOE Patents [OSTI]

    Klima, Mark S.; Maronde, Carl P.; Killmeyer, Richard P.

    1991-01-01

    A method of cleaning particulate coal which is fed with a dense medium slurry as an inlet feed to a cyclone separator. The coal particle size distribution is in the range of from about 37 microns to about 600 microns. The dense medium comprises water and ferromagnetic particles that have a relative density in the range of from about 4.0 to about 7.0. The ferromagnetic particles of the dense medium have particle sizes of less than about 15 microns and at least a majority of the particle sizes are less than about 5 microns. In the cyclone, the particulate coal and dense-medium slurry is separated into a low gravity product stream and a high gravity produce stream wherein the differential in relative density between the two streams is not greater than about 0.2. The low gravity and high gravity streams are treated to recover the ferromagnetic particles therefrom.

  2. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Engines | Department of Energy Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_44_hall.pdf More Documents & Publications Development and Demonstration of an Electronic Particulate Matter Sensor for Both

  3. Development of a Sub-Grid Model of a Diesel Particulate Filter: application

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the lattice-Boltzmann technique | Department of Energy a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique 2002 DEER Conference Presentation: Pacific Northwest National Laboratory PDF icon 2002_deer_muntean.pdf More Documents & Publications The State of the Science in Diesel Particulate Control fundamental Modeling and Experimental

  4. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    SciTech Connect (OSTI)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was found that the ground pellets could be used as an effective NOx control agent for pulverized-coal-fired systems. NOx emissions reductions up to 63% were recorded, when using AFP as a NOx control agent. In addition to performance benefits, economic analyses showed the good economic benefits of AFP fuel. Using equipment manufacturer inputs, and reasonable values for biomass, biosolids and coal fines costs, it was determined that an AFP plant would have good profitability. For cases where biosolids contents were in the range of 50%, the after tax Internal Rates of Return were in the range of 40% to 50%. These are very attractive returns. Besides the baseline analysis for the various AFP formulations tested at pilot scale, sensitivity analysis showed the impact of important parameters on return. From results, it was clear that returns are excellent for a range of parameters that could be expected in practice. Importantly, these good returns are achieved even without incentives related to the emissions control benefits of biomass.

  5. Development of a Sub-Grid Model of a Diesel Particulate Filter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the lattice-Boltzmann technique Development of a Sub-Grid Model of a Diesel Particulate Filter: application of the lattice-Boltzmann technique 2002 DEER Conference ...

  6. Measuring PM Distribution in a Catalyzed Particulate Filter using a Terahertz Wave Scanner

    Broader source: Energy.gov [DOE]

    Terahertz scanning system produced 3-dimensional image of local PM density in catatalyzed particulate filters tested under loading and oxidizing conditions

  7. Apparatus for removal of particulate matter from gas streams

    DOE Patents [OSTI]

    Smith, Peyton L. (Baton Rouge, LA); Morse, John C. (Baton Rouge, LA)

    2000-01-01

    An apparatus for the removal of particulate matter from the gaseous product stream of an entrained flow coal gasifier which apparatus includes an initial screen, an intermediate screen which is aligned with the direction of flow of the gaseous product stream and a final screen transversely disposed to the flow of gaseous product and which apparatus is capable of withstanding at least a pressure differential of about 10 psi (68.95 kPa) or greater at the temperatures of the gaseous product stream.

  8. Ash reduction system using electrically heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  9. Low exhaust temperature electrically heated particulate matter filter system

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI); Bhatia, Garima (Bangalore, IN)

    2012-02-14

    A system includes a particulate matter (PM) filter, a sensor, a heating element, and a control module. The PM filter includes with an upstream end that receives exhaust gas, a downstream end and multiple zones. The sensor detects a temperature of the exhaust gas. The control module controls current to the heating element to convection heat one of the zones and initiate a regeneration process. The control module selectively increases current to the heating element relative to a reference regeneration current level when the temperature is less than a predetermined temperature.

  10. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, S.J.

    1999-08-17

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between each row of filter elements is a grounded plate. Between the grounded plates and the filter elements are electrode grids for creating electrostatic precipitation zones between each row of filter elements. In this way, when the filter elements are cleaned by pulsing air in a reverse direction, the dust removed from the bags will collect in the electrostatic precipitation zones rather than on adjacent filter elements. 12 figs.

  11. Controlled laser production of elongated articles from particulates

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Lewis, Gary K. (Los Alamos, NM); Milewski, John O. (Santa Fe, NM)

    2002-01-01

    It has been discovered that wires and small diameter rods can be produced using laser deposition technology in a novel way. An elongated article such as a wire or rod is constructed by melting and depositing particulate material into a deposition zone which has been designed to yield the desired article shape and dimensions. The article is withdrawn from the deposition zone as it is formed, thus enabling formation of the article in a continuous process. Alternatively, the deposition zone is moved along any of numerous deposition paths away from the article being formed.

  12. Electrically heated particulate filter with zoned exhaust flow control

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2012-06-26

    A system includes a particulate matter (PM) filter that includes X zones. An electrical heater includes Y heater segments that are associated with respective ones of the X zones. The electrical heater is arranged upstream from and proximate with the PM filter. A valve assembly includes Z sections that are associated with respective ones of the X zones. A control module adjusts flow through each of the Z sections during regeneration of the PM filter via control of the valve assembly. X, Y and Z are integers.

  13. Elevated exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Bhatia, Garima [Bangalore, IN

    2012-04-17

    A system includes an electrical heater and a particulate matter (PM) filter that is arranged one of adjacent to and in contact with the electrical heater. A control module selectively increases an exhaust gas temperature of an engine to a first temperature and that initiates regeneration of the PM filter using the electrical heater while the exhaust gas temperature is above the first temperature. The first temperature is greater than a maximum exhaust gas temperature at the PM filter during non-regeneration operation and is less than an oxidation temperature of the PM.

  14. Advanced hybrid particulate collector and method of operation

    DOE Patents [OSTI]

    Miller, Stanley J. (Grand Forks, ND)

    1999-01-01

    A device and method for controlling particulate air pollutants of the present invention combines filtration and electrostatic collection devices. The invention includes a chamber housing a plurality of rows of filter elements. Between each row of filter elements is a grounded plate. Between the grounded plates and the filter elements are electrode grids for creating electrostatic precipitation zones between each row of filter elements. In this way, when the filter elements are cleaned by pulsing air in a reverse direction, the dust removed from the bags will collect in the electrostatic precipitation zones rather than on adjacent filter elements.

  15. Wireless zoned particulate matter filter regeneration control system

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Kirby, Kevin W [Calabasas Hills, CA; Phelps, Amanda [Malibu, CA

    2011-10-04

    An assembly includes a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas, a downstream end and multiple zones. An absorbing layer absorbs microwave energy in one of N frequency ranges and is arranged with the upstream end. N is an integer. A frequency selective filter has M frequency selective segments and receives microwave energy in the N frequency ranges. M is an integer. One of the M frequency selective segments permits passage of the microwave energy in one of the N frequency ranges and does not permit passage of microwave energy in the other of the N frequency ranges.

  16. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  17. Zoned electrical heater arranged in spaced relationship from particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-11-15

    A system comprises a particulate matter (PM) filter that comprises an upstream end for receiving exhaust gas and a downstream end. A zoned heater is arranged spaced from the upstream end and comprises N zones, where N is an integer greater than one, wherein each of the N zones comprises M sub-zones, where M is an integer greater than one. A control module selectively activates at least a selected one of the N zones to initiate regeneration in downstream portions of the PM filter from the one of the N zones and deactivates non-selected ones of the N zones.

  18. Detailed Characterization of Particulates Emitted by Pre-Commercial Single-Cylinder Gasoline Compression Ignition Engine

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Reitz, Paul; Stewart, Mark L.; Imre, D.; Loeper, Paul; Adams, Cory; Andrie, Michael; Rothamer, David; Foster, David E.; Narayanaswamy, Kushal; Najt, Paul M.; Solomon, Arun S.

    2014-08-01

    Gasoline Compression Ignition (GCI) engines have the potential to achieve high fuel efficiency and to significantly reduce both NOx and particulate matter (PM) emissions by operating under dilute partially-premixed conditions. This low temperature combustion strategy is dependent upon direct-injection of gasoline during the compression stroke and potentially near top dead center (TDC). The timing and duration of the in-cylinder injections can be tailored based on speed and load to create optimized conditions that result in a stable combustion. We present the results of advanced aerosol analysis methods that have been used for detailed real-time characterization of PM emitted from a single-cylinder GCI engine operated at different speed, load, timing, and number and duration of near-TDC fuel injections. PM characterization included 28 measurements of size and composition of individual particles sampled directly from the exhaust and after mass and/or mobility classification. We use these data to calculate particle effective density, fractal dimension, dynamic shape factors in free-molecular and transition flow regimes, average diameter of primary spherules, number of spherules, and void fraction of soot agglomerates.

  19. Improvement and Simplification of Diesel Particulate Filter System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Rhodia Electronics and Catalysis PDF icon 2004deermacaudiere.pdf More Documents & Publications ...

  20. Particulate Produced from Advanced Combustion Operation in a...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Carbon Monoxide Emissions Hydrogen Assisted Diesel Combustion in a Common Rail Turbodiesel Engine Effects of Ignition Quality and Fuel Composition on Critical Equivalence Ratio

  1. Optical Backscatter Probe for Sensing Particulate Matter - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This Technology Technology Marketing SummaryTo provide emissions information for automotive engines, ORNL researchers developed a technology that enables very rapid measurement...

  2. Stratification of particulate and VOC pollutants in paint spray booths, June 1990. Report for April 1988-April 1989

    SciTech Connect (OSTI)

    Darvin, C.H.; Ayer, J.

    1990-01-01

    The paper discusses flow management as part of a joint EPA/U.S. Air Force program on emissions from paint spray booths. The goal of the program is to identify and develop efficient and economical emissions control concepts for this source. Flow management is one potential solution that reduces the volume of gases that must be processed in a control system. Although it will not itself control pollution, it can influence the economic and technical viability of subsequent control systems. The test program discussed here was designed to characterize the pollutants both within and exiting a typical back-draw booth for which emissions control and flow management strategies are being developed. Study results indicate that both particulate and volatile organic compounds (VOCs) fall to the lower level of the booth or, at most, stratify at the level at which they were generated. Results indicate that the concentration at the lower level of the booth near the exhaust was from 5 to 25 times greater than that at the upper level. The importance of these findings is that it might be possible to partition a booth's air flow into two zones, one lean and the other concentrated. The enriched lower zone could then be directed to a proportionately smaller VOC control system, of lower capital and operating costs.

  3. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors

  4. Fossil and Contemporary Fine Carbon Fractions at 12 Rural and Urban Sites in the United States

    SciTech Connect (OSTI)

    Schichtel, B; Malm, W; Bench, G; Fallon, S; McDade, C; Chow, J

    2007-03-01

    Fine particulate matter collected at two urban, four near-urban, and six remote sites throughout the United States were analyzed for total carbon (TC) and radiocarbon ({sup 14}C). Samples were collected at most sites for both a summer and winter season. The radiocarbon was used to partition the TC into fossil and contemporary fractions. On average, contemporary carbon composed about half of the carbon at the urban, {approx}70-97% at near-urban, and 82-100% at remote sites. At Phoenix, Arizona, and Seattle, Washington, one monitor was located within the urban center and one outside to assess the urban excess over background concentrations. During the summer the urban and rural sites had similar contemporary carbon concentrations. However, during the winter the urban sites had more than twice the contemporary carbon measured at the neighboring sites, indicating anthropogenic contributions to the contemporary carbon. The urban fossil carbon was 4-20 times larger than the neighboring rural sites for both seasons. Organic (OC) and elemental carbon (EC) from TOR analysis were available. These and the radiocarbon data were used to estimate characteristic fossil and contemporary EC/TC ratios for the winter and summer seasons. These ratios were applied to carbon data from the Interagency Monitoring of Protected Visual Environments network to estimate the fraction of contemporary carbon at mostly rural sites throughout the United States. In addition, the ratios were used to develop a semiquantitative, lower bound estimate of secondary organic carbon (SOC) contribution to fossil and contemporary carbon. SOC accounted for more than one-third of the fossil and contemporary carbon.

  5. Use of micro-XANES to speciate chromium in airborne fine particles in the Sacramento Valley

    SciTech Connect (OSTI)

    Michelle L. Werner; Peter S. Nico; Matthew A. Marcus; Cort Anastasio

    2007-07-15

    While particulate matter (PM) in the atmosphere can lead to a wide array of negative health effects, the cause of toxicity is largely unknown. One aspect of PM that likely affects health is the chemical composition, in particular the transition metals within the particles. Chromium is one transition metal of interest due to its two major oxidation states, with Cr(III) being much less toxic compared to Cr(VI). Using microfocused X-ray absorption near edge structure (micro-XANES), we analyzed the Cr speciation in fine particles (diameters {le} 2.5 {mu}m) collected at three sites in the Sacramento Valley of northern California: Sacramento, a large urban area, Davis, a small city, and Placerville, a rural area. These are several major stationary sources of Cr within 24 km of the site including chrome-plating plants, power plants and incinerators. The microfocused X-ray beam enables us to look at very small areas on the filter with a resolution of typically 5-7 micrometers. With XANES we are able to not only distinguish between Cr(VI) and Cr(III), but also to identify different types of Cr(III) and more reduced Cr species. At all of our sampling sites the main Cr species were Cr(III), with Cr(OH){sub 3} or a Cr-Fe, chromite-like, phase being the dominant species. Cr(VI)-containing particles were found only in the most urban site. All three sites contained some reduced Cr species, either Cr(0) or Cr{sub 3}C{sub 2}, although these were minor components. This work demonstrates that micro-XANES can be used as a minimally invasive analytical tool to investigate the composition of ambient PM. 32 refs., 6 figs.

  6. Near-zero emissions combustor system for syngas and biofuels

    SciTech Connect (OSTI)

    Yongho, Kim; Rosocha, Louis

    2010-01-01

    A multi-institutional plasma combustion team was awarded a research project from the DOE/NNSA GIPP (Global Initiative for Prolifereation Prevention) office. The Institute of High Current Electronics (Tomsk, Russia); Leonardo Technologies, Inc. (an American-based industrial partner), in conjunction with the Los Alamos National Laboratory are participating in the project to develop novel plasma assisted combustion technologies. The purpose of this project is to develop prototypes of marketable systems for more stable and cleaner combustion of syngas/biofuels and to demonstrate that this technology can be used for a variety of combustion applications - with a major focus on contemporary gas turbines. In this paper, an overview of the project, along with descriptions of the plasma-based combustors and associated power supplies will be presented. Worldwide, it is recognized that a variety of combustion fuels will be required to meet the needs for supplying gas-turbine engines (electricity generation, propulsion), internal combustion engines (propulsion, transportation), and burners (heat and electricity generation) in the 21st Century. Biofuels and biofuel blends have already been applied to these needs, but experience difficulties in modifications to combustion processes and combustor design and the need for flame stabilization techniques to address current and future environmental and energy-efficiency challenges. In addition, municipal solid waste (MSW) has shown promise as a feedstock for heat and/or electricity-generating plants. However, current combustion techniques that use such fuels have problems with achieving environmentally-acceptable air/exhaust emissions and can also benefit from increased combustion efficiency. This project involves a novel technology (a form of plasma-assisted combustion) that can address the above issues. Plasma-assisted combustion (PAC) is a growing field that is receiving worldwide attention at present. The project is focused on research necessary to develop a novel, high-efficiency, low-emissions (near-zero, or as low as reasonably achievable), advanced combustion technology for electricity and heat production from biofuels and fuels derived from MSW. For any type of combustion technology, including the advanced technology of this project, two problems of special interest must be addressed: developing and optimizing the combustion chambers and the systems for igniting and sustaining the fuel-burning process. For MSW in particular, there are new challenges over gaseous or liquid fuels because solid fuels must be ground into fine particulates ({approx} 10 {micro}m diameter), fed into the advanced combustor, and combusted under plasma-assisted conditions that are quite different than gaseous or liquid fuels. The principal idea of the combustion chamber design is to use so-called reverse vortex gas flow, which allows efficient cooling of the chamber wall and flame stabilization in the central area of the combustor (Tornado chamber). Considerable progress has been made in design ing an advanced, reverse vortex flow combustion chamber for biofuels, although it was not tested on biofuels and a system that could be fully commercialized has never been completed.

  7. Method and apparatus for calibrating a particle emissions monitor

    SciTech Connect (OSTI)

    Flower, W.L.; Renzi, R.F.

    1998-07-07

    The invention discloses a method and apparatus for calibrating particulate emissions monitors, in particular, sampling probes, and in general, without removing the instrument from the system being monitored. A source of one or more specific metals in aerosol (either solid or liquid) or vapor form is housed in the instrument. The calibration operation is initiated by moving a focusing lens, used to focus a light beam onto an analysis location and collect the output light response, from an operating position to a calibration position such that the focal point of the focusing lens is now within a calibration stream issuing from a calibration source. The output light response from the calibration stream can be compared to that derived from an analysis location in the operating position to more accurately monitor emissions within the emissions flow stream. 6 figs.

  8. Method and apparatus for calibrating a particle emissions monitor

    SciTech Connect (OSTI)

    Flower, William L.; Renzi, Ronald F.

    1998-07-07

    The instant invention discloses method and apparatus for calibrating particulate emissions monitors, in particular, and sampling probes, in general, without removing the instrument from the system being monitored. A source of one or more specific metals in aerosol (either solid or liquid) or vapor form is housed in the instrument. The calibration operation is initiated by moving a focusing lens, used to focus a light beam onto an analysis location and collect the output light response, from an operating position to a calibration position such that the focal point of the focusing lens is now within a calibration stream issuing from a calibration source. The output light response from the calibration stream can be compared to that derived from an analysis location in the operating position to more accurately monitor emissions within the emissions flow stream.

  9. Cooler and particulate separator for an off-gas stack

    DOE Patents [OSTI]

    Wright, George T. (15 Cherry Hills Dr., Aiken, SC 29803)

    1992-01-01

    An off-gas stack for a melter comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes pervents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

  10. Cooler and particulate separator for an off-gas stack

    DOE Patents [OSTI]

    Wright, G.T.

    1991-04-08

    This report describes an off-gas stack for a melter, furnace or reaction vessel comprising an air conduit leading to two sets of holes, one set injecting air into the off-gas stack near the melter plenum and the second set injecting air downstream of the first set. The first set injects air at a compound angle, having both downward and tangential components, to create a reverse vortex flow, counter to the direction of flow of gas through the stack and also along the periphery of the stack interior surface. Air from the first set of holes prevents recirculation zones from forming and the attendant accumulation of particulate deposits on the wall of the stack and will also return to the plenum any particulate swept up in the gas entering the stack. The second set of holes injects air in the same direction as the gas in the stack to compensate for the pressure drop and to prevent the concentration of condensate in the stack. A set of sprayers, receiving water from a second conduit, is located downstream of the second set of holes and sprays water into the gas to further cool it.

  11. DATABASE AND ANALYTICAL TOOL DEVELOPMENT FOR THE MANAGEMENT OF DATA DERIVED FROM US DOE (NETL) FUNDED FINE PARTICULATE (PM2.5) RESEARCH

    SciTech Connect (OSTI)

    Robinson P. Khosah; Charles G. Crawford

    2003-03-13

    Advanced Technology Systems, Inc. (ATS) was contracted by the U. S. Department of Energy's National Energy Technology Laboratory (DOE-NETL) to develop a state-of-the-art, scalable and robust web-accessible database application to manage the extensive data sets resulting from the DOE-NETL-sponsored ambient air monitoring programs in the upper Ohio River valley region. The data management system was designed to include a web-based user interface that will allow easy access to the data by the scientific community, policy- and decision-makers, and other interested stakeholders, while providing detailed information on sampling, analytical and quality control parameters. In addition, the system will provide graphical analytical tools for displaying, analyzing and interpreting the air quality data. The system will also provide multiple report generation capabilities and easy-to-understand visualization formats that can be utilized by the media and public outreach/educational institutions. The project is being conducted in two phases. Phase 1, which is currently in progress and will take twelve months to complete, will include the following tasks: (1) data inventory/benchmarking, including the establishment of an external stakeholder group; (2) development of a data management system; (3) population of the database; (4) development of a web-based data retrieval system, and (5) establishment of an internal quality assurance/quality control system on data management. In Phase 2, which will be completed in the second year of the project, a platform for on-line data analysis will be developed. Phase 2 will include the following tasks: (1) development of a sponsor and stakeholder/user website with extensive online analytical tools; (2) development of a public website; (3) incorporation of an extensive online help system into each website; and (4) incorporation of a graphical representation (mapping) system into each website. The project is now into its sixth month of Phase 1 development activities.

  12. Database and Analytical Tool Development for the Management of Data Derived from US DOE (NETL) Funded Fine Particulate (PM2.5) Research

    SciTech Connect (OSTI)

    Robinson Khosah

    2007-07-31

    Advanced Technology Systems, Inc. (ATS) was contracted by the U. S. Department of Energy's National Energy Technology Laboratory (DOE-NETL) to develop a state-of-the-art, scalable and robust web-accessible database application to manage the extensive data sets resulting from the DOE-NETL-sponsored ambient air monitoring programs in the upper Ohio River valley region. The data management system was designed to include a web-based user interface that will allow easy access to the data by the scientific community, policy- and decision-makers, and other interested stakeholders, while providing detailed information on sampling, analytical and quality control parameters. In addition, the system will provide graphical analytical tools for displaying, analyzing and interpreting the air quality data. The system will also provide multiple report generation capabilities and easy-to-understand visualization formats that can be utilized by the media and public outreach/educational institutions. The project was conducted in two phases. Phase One included the following tasks: (1) data inventory/benchmarking, including the establishment of an external stakeholder group; (2) development of a data management system; (3) population of the database; (4) development of a web-based data retrieval system, and (5) establishment of an internal quality assurance/quality control system on data management. Phase Two involved the development of a platform for on-line data analysis. Phase Two included the following tasks: (1) development of a sponsor and stakeholder/user website with extensive online analytical tools; (2) development of a public website; (3) incorporation of an extensive online help system into each website; and (4) incorporation of a graphical representation (mapping) system into each website. The project is now technically completed.

  13. Database and Analytical Tool Development for the Management of Data Derived from US DOE (NETL) Funded Fine Particulate (PM2.5) Research

    SciTech Connect (OSTI)

    Robinson P. Khosah; Frank T. Alex

    2007-02-11

    Advanced Technology Systems, Inc. (ATS) was contracted by the U. S. Department of Energy's National Energy Technology Laboratory (DOE-NETL) to develop a state-of-the-art, scalable and robust web-accessible database application to manage the extensive data sets resulting from the DOE-NETL-sponsored ambient air monitoring programs in the upper Ohio River valley region. The data management system was designed to include a web-based user interface that will allow easy access to the data by the scientific community, policy- and decision-makers, and other interested stakeholders, while providing detailed information on sampling, analytical and quality control parameters. In addition, the system will provide graphical analytical tools for displaying, analyzing and interpreting the air quality data. The system will also provide multiple report generation capabilities and easy-to-understand visualization formats that can be utilized by the media and public outreach/educational institutions. The project is being conducted in two phases. Phase One includes the following tasks: (1) data inventory/benchmarking, including the establishment of an external stakeholder group; (2) development of a data management system; (3) population of the database; (4) development of a web-based data retrieval system, and (5) establishment of an internal quality assurance/quality control system on data management. Phase Two, which is currently underway, involves the development of a platform for on-line data analysis. Phase Two includes the following tasks: (1) development of a sponsor and stakeholder/user website with extensive online analytical tools; (2) development of a public website; (3) incorporation of an extensive online help system into each website; and (4) incorporation of a graphical representation (mapping) system into each website. The project is now into its forty-eighth month of development activities.

  14. Excitonic fine-structure splitting in telecom-wavelength InAs/GaAs quantum dots: Statistical distribution and height-dependence

    SciTech Connect (OSTI)

    Goldmann, Elias Barthel, Stefan; Florian, Matthias; Jahnke, Frank; Schuh, Kolja

    2013-12-09

    The variation of the excitonic fine-structure splitting is studied for semiconductor quantum dots under the influence of a strain-reducing layer, utilized to shift the emission wavelength of the excitonic transition into the telecom-wavelength regime of 1.31.5 ?m. By means of a sp{sup 3}s{sup *}-tight-binding model and configuration interaction, we calculate wavelength shifts and fine-structure splittings for various quantum dot geometries. We find the splittings remaining small and even decreasing with strain-reducing layer composition for quantum dots with large height. Combined with an observed increased emission efficiency, the applicability for generation of entanglement photons is persistent.

  15. Resistive heater geometry and regeneration method for a diesel particulate filter

    DOE Patents [OSTI]

    Phelps, Amanda; Kirby, Kevin W.; Gregoir, Daniel J.

    2011-10-25

    One embodiment of the invention includes a diesel particulate filter comprising a first face and a second face; a bottom electrode layer formed over the first face of the diesel particulate filter; a middle resistive layer formed over a portion of the bottom electrode layer; and a top electrode layer formed over a portion of the middle resistive layer.

  16. Friction stir weld tools having fine grain structure

    DOE Patents [OSTI]

    Grant, Glenn J.; Frye, John G.; Kim, Jin Yong; Lavender, Curt A.; Weil, Kenneth Scott

    2016-03-15

    Tools for friction stir welding can be made with fewer process steps, lower cost techniques, and/or lower cost ingredients than other state-of-the-art processes by utilizing improved compositions and processes of fabrication. Furthermore, the tools resulting from the improved compositions and processes of fabrication can exhibit better distribution and homogeneity of chemical constituents, greater strength, and/or increased durability. In one example, a friction stir weld tool includes tungsten and rhenium and is characterized by carbide and oxide dispersoids, by carbide particulates, and by grains that comprise a solid solution of the tungsten and rhenium. The grains do not exceed 10 micrometers in diameter.

  17. NWCF Evaporator Tank System 2001 Offgas Emissions Inventory

    SciTech Connect (OSTI)

    Boardman, R.D.; Lamb, K.M.; Matejka, L.A.; Nenni, J.A.

    2002-02-27

    An offgas emissions inventory and liquid stream characterization of the Idaho New Waste Calcining Facility (NWCF) Evaporator Tank System (ETS), formerly known as the High Level Liquid Waste Evaporator (HLLWE), has been completed. The emissions rates of volatile and semi-volatile organic compounds, multiple metals, particulate, and hydrochloric acid were measured in accordance with an approved Quality Assurance Project Plan (QAPjP) and Test Plan that invoked U.S. Environmental Protection Agency (EPA) standard sample collection and analysis procedures. Offgas samples were collected during the start up and at the end of evaporator batches when it was hypothesized the emissions would be at peak rates. Corresponding collection of samples from the evaporator feed overhead condensate, and bottoms was made at approximately the same time as the emissions inventory to support material balance determinations for the evaporator process. The data indicate that organic compound emissions are slightly higher at the beginning of the batch while metals emissions, including mercury, are slightly higher at the end of the evaporator batch. The maximum emissions concentrations are low for all constituents of primary concern. Mercury emissions were less than 5 ppbv, while the sum of HCl and Cl2 emissions was less than 1 ppmv. The sum of all organic emissions also was less than 1 ppmv. The estimated hazardous quotient (HQ) for the evaporator was 6.2e-6 as compared to 0.25 for the EPA target criteria. The cancer risk was 1.3e-10 compared to an EPA target of le-5.

  18. NWCF Evaporator Tank System 2001 Offgas Emissions Inventory

    SciTech Connect (OSTI)

    Boardman, Richard Doin; Lamb, Kenneth Mitchel; Matejka, Leon Anthony; Nenni, Joseph A

    2002-02-01

    An offgas emissions inventory and liquid stream characterization of the Idaho New Waste Calcining Facility (NWCF) Evaporator Tank System (ETS), formerly known as the High Level Liquid Waste Evaporator (HLLWE), has been completed. The emissions rates of volatile and semi-volatile organic compounds, multiple metals, particulate, and hydrochloric acid were measured in accordance with an approved Quality Assurance Project Plan (QAPjP) and Test Plan that invoked U.S. Environmental Protection Agency (EPA) standard sample collection and analysis procedures. Offgas samples were collected during the start up and at the end of evaporator batches when it was hypothesized the emissions would be at peak rates. Corresponding collection of samples from the evaporator feed overhead condensate, and bottoms was made at approximately the same time as the emissions inventory to support material balance determinations for the evaporator process. The data indicate that organic compound emissions are slightly higher at the beginning of the batch while metals emissions, including mercury, are slightly higher at the end of the evaporator batch. The maximum emissions concentrations are low for all constituents of primary concern. Mercury emissions were less than 5 ppbv, while the sum of HCl and Cl2 emissions was less than 1 ppmv. The sum of all organic emissions also was less than 1 ppmv. The estimated hazardous quotient (HQ) for the evaporator was 6.2e-6 as compared to 0.25 for the EPA target criteria. The cancer risk was 1.3e-10 compared to an EPA target of le-5.

  19. Russian Policy on Methane Emissions in the Oil and Gas Sector: A Case Study in Opportunities and Challenges in Reducing Short-Lived Forcers

    SciTech Connect (OSTI)

    Evans, Meredydd; Roshchanka, Volha

    2014-08-04

    This paper uses Russian policy in the oil and gas sector as a case study in assessing options and challenges for scaling-up emission reductions. We examine the challenges to achieving large-scale emission reductions, successes that companies have achieved to date, how Russia has sought to influence methane emissions through its environmental fine system, and options for helping companies achieve large-scale emission reductions in the future through simpler and clearer incentives.

  20. High exhaust temperature, zoned, electrically-heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  1. Integrated exhaust and electrically heated particulate filter regeneration systems

    DOE Patents [OSTI]

    Gonze, Eugene V.; Paratore, Jr., Michael J.

    2013-01-08

    A system includes a particulate matter (PM) filter that includes multiple zones. An electrical heater includes heater segments that are associated with respective ones of the zones. The electrical heater is arranged upstream from and proximate with the PM filter. A post-fuel injection system injects fuel into at least one of a cylinder of an engine and an exhaust system. A control module is configured to operate in a first mode that includes activating the electrical heater to heat exhaust of the engine. The control module is also configured to operate in a second mode that includes activating the post-injection system to heat the exhaust. The control module selectively operates in at least one of the first mode and the second mode.

  2. Dry scrubbing oxides and particulate contaminants from hot gases

    SciTech Connect (OSTI)

    Quee, J. A.; Haak, M. P.

    1985-03-12

    Sulfur dioxides are dry scrubbed from a flue gas by introducing minute droplets containing a liquid, such as water, and an alkali or alkaline reactant, such as lime, into the spray zone in the primary spray drying chamber of a spray dryer and concurrently contacting these droplets with the hot flue gas. The droplets are partially dried to a tacky condition before reaching a foraminous collecting member extending through the primary spray drying chamber and collect on the collecting member as a moist, porous mat. As the flue gas continues to flow through the mat, the mat serves as a filter for removing fly ash and other particulate matter and remaining sulfur oxides react with unreacted particles of the reactant and reactive ingredients of the fly ash particles in the mat.

  3. Cashew nut roasting: Chemical characterization of particulate matter and genotocixity analysis

    SciTech Connect (OSTI)

    Oliveira Galvo, Marcos Felipe de; Melo Cabral, Thiago de; Andr, Paulo Afonso de; Ftima Andrade, Maria de; Miranda, Regina Maura de; Saldiva, Paulo Hilrio Nascimento; Castro Vasconcellos, Prola de; Batistuzzo de Medeiros, Silvia Regina

    2014-05-01

    Background: Particulate matter (PM) is potentially harmful to health and related to genotoxic events, an increase in the number of hospitalizations and mortality from respiratory and cardiovascular diseases. The present study conducted the first characterization of elemental composition and polycyclic aromatic hydrocarbon (PAH) analysis of PM, as well as the biomonitoring of genotoxic activity associated to artisanal cashew nut roasting, an important economic and social activity worldwide. Methods: The levels of PM{sub 2.5} and black carbon were also measured by gravimetric analysis and light reflectance. The elemental composition was determined using X-ray fluorescence spectrometry and PAH analysis was carried out by gas chromatographymass spectrometry. Genotoxic activity was measured by the Tradescantia pallida micronucleus bioassay (Trad-MCN). Other biomarkers of DNA damage, such as nucleoplasmic bridges and nuclear fragments, were also quantified. Results: The mean amount of PM{sub 2.5} accumulated in the filters (January 2124.2 g/m{sup 3}; May 1022.2 g/m{sup 3}; September 1291.9 g/m{sup 3}), black carbon (January 363.6 g/m{sup 3}; May 70 g/m{sup 3}; September 69.4 g/m{sup 3}) and concentrations of Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Se, Br and Pb were significantly higher than the non-exposed area. Biomass burning tracers K, Cl, and S were the major inorganic compounds found. Benzo[k]fluoranthene, indene[1,2,3-c,d]pyrene, benzo[ghi]perylene, phenanthrene and benzo[b]fluoranthene were the most abundant PAHs. Mean benzo[a]pyrene-equivalent carcinogenic power values showed a significant cancer risk. The Trad-MCN bioassay revealed an increase in micronucleus frequency, 27 times higher than the negative control and significantly higher in all the months analyzed, possibly related to the mutagenic PAHs found. Conclusions: This study demonstrated that artisanal cashew nut roasting is a serious occupational problem, with harmful effects on workers' health. Those involved in this activity are exposed to higher PM{sub 2.5} concentrations and to 12 PAHs considered potentially mutagenic and/or carcinogenic. The Trad-MCN with T. pallida was sensitive and efficient in evaluating the genotoxicity of the components and other nuclear alterations may be used as effective biomarkers of DNA damage. - Highlights: The cashew nut roasting generated high concentrations of particulate matter fine. The biomass burning tracers K, Cl, S were the major inorganic compounds found. It was identified 12 PAHs considered to be potentially mutagenic and/or carcinogenic. The genotoxic potential of this activity was confirmed by the Trad MCN assay. This activity is a serious occupational problem with harmful effects to health workers.

  4. Performance of the Low-Efficiency Diesel Particulate Filter for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-15wei.pdf More Documents & ...

  5. Results of emissions testing while burning densified refuse derived fuel, Dordt College, Sioux Center, Iowa

    SciTech Connect (OSTI)

    Not Available

    1989-10-01

    Pacific Environmental Services, Inc. provided engineering and source testing services to the Council of Great Lake Governors to support their efforts in promoting the development and utilization of densified refuse derived fuels (d-RDF) and pelletized wastepaper fuels in small steam generating facilities. The emissions monitoring program was designed to provide a complete air emissions profile while burning various refuse derived fuels. The specific goal of this test program was to conduct air emissions tests at Dordt College located in Sioux Center, Iowa and to identify a relationship between fuel types and emission characteristics. The sampling protocol was carried out June 12 through June 20, 1989 on boiler {number sign}4. This unit had been previously modified to burn d-RDF. The boiler was not equipped with any type of air pollution control device so the emissions samples were collected from the boiler exhaust stack on the roof of the boilerhouse. The emissions that were sampled included: particulates; PM{sub 10} particulates; hydrochloric acid; dioxins; furans; polychlorinated biphenyls (PCB); metals and continuous monitors for CO, CO{sub 2}O{sub 2}SO{sub x}NO{sub x} and total hydrocarbons. Grab samples of the fuels were collected, composited and analyzed for heating value, moisture content, proximate and ultimate analysis, ash fusion temperature, bulk density and elemental ash analysis. Grab samples of the boiler ash were also collected and analyzed for total hydrocarbons total dioxins, total furans, total PCBs and heavy metals. 77 figs., 20 tabs.

  6. Analysis of fine structure in the nuclear continuum

    SciTech Connect (OSTI)

    Shevchenko, A.; Kalmykov, Y.; Neumann-Cosel, P. von; Ponomarev, V. Yu.; Richter, A.; Wambach, J.; Carter, J.; Usman, I.; Cooper, G. R. J.; Fearick, R. W.

    2008-02-15

    Fine structure has been shown to be a general phenomenon of nuclear giant resonances of different multipolarities over a wide mass range. In this article we assess various techniques that have been proposed to extract quantitative information from the fine structure in terms of characteristic scales. These include the so-called local scaling dimension, the entropy index method, Fourier analysis, and continuous and discrete wavelet transforms. As an example, results on the isoscalar giant quadrupole resonance in {sup 208}Pb from high-energy-resolution inelastic proton scattering and calculations with the quasiparticle-phonon model are analyzed. Wavelet analysis, both continuous and discrete, of the spectra is shown to be a powerful tool to extract the magnitude and localization of characteristic scales.

  7. Fine Structure of Dark Energy and New Physics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jejjala, Vishnu; Kavic, Michael; Minic, Djordje

    2007-01-01

    Following our recent work on the cosmological constant problem, in this letter we make a specific proposal regarding the fine structure (i.e., the spectrum) of dark energy. The proposal is motivated by a deep analogy between the blackbody radiation problem, which led to the development of quantum theory, and the cosmological constant problem, for which we have recently argued calls for a conceptual extension of the quantum theory. We argue that the fine structure of dark energy is governed by a Wien distribution, indicating its dual quantum and classical nature. We discuss observational consequences of such a picture of darkmore »energy and constrain the distribution function.« less

  8. Maintenance is the cheapest way to improve fine coal dewatering

    SciTech Connect (OSTI)

    Burger, J.

    1986-01-01

    There are a great many things that a preparation plant operator can do right now to increase fine coal dewatering effectiveness and maintenance is one of them, says Donald A. Dahlstrom, at the University of Utah. Dewatering of fine coal is increasingly important, because electricity generation, the largest coal consumer, is so strongly affected by the moisture content. Every pound of water put into a boiler raises costs about 2 1/2 cents. The heat it takes to turn water to steam and get it out the stack is heat that could have been used to generate power. In addition, there is the cost of shipping the water. You can add the freight costs to that. In contrast it costs about 1/2-cent/lb to remove the water at the preparation plant.

  9. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect (OSTI)

    B. K. Parekh; D. P. Patil

    2008-04-30

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake is subjected to pressure for a short time, the free water present is released from the filter cake. Laboratory studies have shown that depending on the coal type a filter cake containing about 15% moisture could be obtained using the two-stage filtration technique. It was also noted that applying intermittent breaks in vacuum force during cake formation, which disturbed the cake structure, helped in removing moisture from the filter cakes. In this project a novel approach of cleaning coal using column flotation was also developed. With this approach the feed capacity of the column is increased significantly, and the column was also able to recover coarser size coal which usually gets lost in the process. The outcome of the research benefits the coal industry, utility industry, and indirectly the general public. The benefits can be counted in terms of clean energy, cleaner environment, and lower cost power.

  10. Computational Challenges and Opportunities for Fine Scale Mapping of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complete Brains | Argonne Leadership Computing Facility Computational Challenges and Opportunities for Fine Scale Mapping of Complete Brains Event Sponsor: Computation Institute Presentation Start Date: Feb 11 2016 - 12:00pm Building/Room: Searle 240A, 5735 S. Ellis Ave., via Blue Jeans (See Webcast below) Location: The University of Chicago Speaker(s): Narayanan "Bobby" Kasthuri Speaker(s) Title: University of Chicago Host: Ian Foster The Kasthuri lab is pioneering new techniques

  11. Transportable Heavy Duty Emissions Testing Laboratory and Research Program

    SciTech Connect (OSTI)

    David Lyons

    2008-03-31

    The objective of this program was to quantify the emissions from heavy-duty vehicles operating on alternative fuels or advanced fuel blends, often with novel engine technology or aftertreatment. In the first year of the program West Virginia University (WVU) researchers determined that a transportable chassis dynamometer emissions measurement approach was required so that fleets of trucks and buses did not need to be ferried across the nation to a fixed facility. A Transportable Heavy-Duty Vehicle Emissions Testing Laboratory (Translab) was designed, constructed and verified. This laboratory consisted of a chassis dynamometer semi-trailer and an analytic trailer housing a full scale exhaust dilution tunnel and sampling system which mimicked closely the system described in the Code of Federal Regulations for engine certification. The Translab was first used to quantify emissions from natural gas and methanol fueled transit buses, and a second Translab unit was constructed to satisfy research demand. Subsequent emissions measurement was performed on trucks and buses using ethanol, Fischer-Tropsch fuel, and biodiesel. A medium-duty chassis dynamometer was also designed and constructed to facilitate research on delivery vehicles in the 10,000 to 20,000lb range. The Translab participated in major programs to evaluate low-sulfur diesel in conjunction with passively regenerating exhaust particulate filtration technology, and substantial reductions in particulate matter were recorded. The researchers also participated in programs to evaluate emissions from advanced natural gas engines with closed loop feedback control. These natural gas engines showed substantially reduced levels of oxides of nitrogen. For all of the trucks and buses characterized, the levels of carbon monoxide, oxides of nitrogen, hydrocarbons, carbon dioxide and particulate matter were quantified, and in many cases non-regulated species such as aldehydes were also sampled. Particle size was also quantified during selected studies. A laboratory was established at WVU to provide for studies which supported and augmented the Translab research, and to provide for development of superior emissions measurement systems. This laboratory research focused on engine control and fuel sulfur issues. In recent years, as engine and aftertreatment technologies advanced, emissions levels were reduced such that they were at or below the Translab detectable limits, and in the same time frame the US Environmental Protection Agency required improved measurement methodologies for engine emissions certification. To remain current and relevant, the researchers designed a new Translab analytic system, housed in a container which can be transported on a semi-trailer. The new system's dilution tunnel flow was designed to use a subsonic venturi with closed loop control of blower speed, and the secondary dilution and particulate matter filter capture were designed to follow new EPA engine certification procedures. A further contribution of the program has been the development of techniques for creating heavy-duty vehicle test schedules, and the creation of schedules to mimic a variety of truck and bus vocations.

  12. Carbon Emissions: Food Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  13. Alternatives to conventional diesel fuel-some potential implications of California's TAC decision on diesel particulate.

    SciTech Connect (OSTI)

    Eberhardt, J. J.; Rote, D. M.; Saricks, C. L.; Stodolsky, F.

    1999-08-10

    Limitations on the use of petroleum-based diesel fuel in California could occur pursuant to the 1998 declaration by California's Air Resources Board (CARB) that the particulate matter component of diesel exhaust is a carcinogen, therefore a toxic air contaminant (TAC) subject to provisions of the state's Proposition 65. It is the declared intention of CARB not to ban or restrict diesel fuel, per se, at this time. Assuming no total ban, Argonne National Laboratory (ANL) explored two feasible ''mid-course'' strategies. (1) Increased penetration of natural gas and greater gasoline use in the transportation fuels market, to the extent that some compression-ignition (CI) applications revert to spark-ignition (SI) engines. (2) New specifications requiring diesel fuel reformulation based on exhaust products of individual diesel fuel constituents. Each of these alternatives results in some degree of (conventional) diesel displacement. In the first case, diesel fuel is assumed admissible for ignition assistance as a pilot fuel in natural gas (NG)-powered heavy-duty vehicles, and gasoline demand in California increases by 32.2 million liters per day overall, about 21 percent above projected 2010 baseline demand. Natural gas demand increases by 13.6 million diesel liter equivalents per day, about 7 percent above projected (total) consumption level. In the second case, compression-ignition engines utilize substitutes for petroleum-based diesel having similar ignition and performance properties. For each case we estimated localized air emission plus generalized greenhouse gas and energy changes. Economic implications of vehicle and engine replacement were not evaluated.

  14. Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Heavy Duty and NRMM According to Annex XXVII StVZO | Department of Energy Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO This presentation discusses how a diesel particulate filter can be integrated in the exhaust piping of a heavy-duty engine. PDF icon deer08_rembor.pdf More

  15. MODELING OF LONG-TERM FATE OF MOBILIZED FINES DUE TO DAM-EMBANKMENT...

    Office of Scientific and Technical Information (OSTI)

    FINES DUE TO DAM-EMBANKMENT INTERFACIAL DISLOCATIONS Citation Details In-Document Search Title: MODELING OF LONG-TERM FATE OF MOBILIZED FINES DUE TO DAM-EMBANKMENT ...

  16. Cyber Power Group Ltd aka Fine Silicon Co Ltd | Open Energy Informatio...

    Open Energy Info (EERE)

    Cyber Power Group Ltd aka Fine Silicon Co Ltd Jump to: navigation, search Name: Cyber Power Group Ltd (aka Fine Silicon Co Ltd) Place: Baoding, Hebei Province, China Product:...

  17. Monitoring Fine Sediment; Grande Ronde and John Day Rivers, 1999 Annual Report.

    SciTech Connect (OSTI)

    Rhodes, Jonathan J.; Greene, M. Jonas; Purser, Michael D.

    2000-01-01

    This project was initiated to monitor surface fine sediment levels and overwinter intrusion of fine sediment in spring chinook salmon spawning habitat in the North Folk John Day and Grande Ronde Rivers, for five years.

  18. Study Pinpoints Sources of Polluting Vehicle Emissions (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01

    Unburned lubricant produces 60%-90% of organic carbon emissions. While diesel fuel is often viewed as the most polluting of conventional petroleum-based fuels, emissions from gasoline engines can more significantly degrade air quality. Gasoline exhaust is at least as toxic on a per-unit-mass basis as diesel exhaust, and contributes up to 10 times more particulate matter (PM) to the emission inventory. Because emissions from both fuels can gravely impact health and the environment, researchers at the National Renewable Energy Laboratory (NREL) launched a study to understand how these pollutants relate to fuels, lubricants, and engine operating conditions. NREL's Collaborative Lubricating Oil Study on Emissions (CLOSE) project tested a variety of vehicles over different drive cycles at moderate (72 F) and cold (20 F) temperatures. Testing included: (1) Normal and high-emitting light-, medium-, and heavy-duty vehicles; (2) Gasoline, diesel, and compressed natural gas (CNG)-powered vehicles; (3) New and aged lubricants representative of those currently on the market; and (4) Gasoline containing no ethanol, E10, Texas-mandated low-emission diesel fuel, biodiesel, and CNG. The study confirmed that normally functioning emission control systems for gasoline light-duty vehicles are very effective at controlling organic carbon (OC) emissions. Diesel vehicles without aftertreatment emission control systems exhibited OC emissions approximately one order of magnitude higher than gasoline vehicles. High-emitter gasoline vehicles produced OC emissions similar to diesel vehicles without exhaust aftertreatment emission control. Exhaust catalysts combusted or converted more than 75% of lubricating oil components in the exhaust gases. Unburned crankcase lubricant made up 60%-90% of OC emissions. This OC represented 20%-50% of emitted PM in all but two of the vehicles. Three-way catalysts proved effective at reducing most of the OC. With high PM emitters or vehicles with deteriorated aftertreatment, high-molecular-weight fuel components and unburned lubricant were emitted at higher rates than in vehicles in good repair, with functioning emissions systems. Light-duty gasoline, medium-duty diesel, and heavy-duty natural gas vehicles produced more particles with fresh oil than with aged oil. The opposite trend was observed in light- and medium-duty high PM emitters. This effect was not readily apparent with heavy-duty diesel vehicles, perhaps because the lubricant represented a much smaller fraction of the total PM in those trucks.

  19. Mercury Emission Measurement at a CFB Plant

    SciTech Connect (OSTI)

    John Pavlish; Jeffrey Thompson; Lucinda Hamre

    2009-02-28

    In response to pending regulation to control mercury emissions in the United States and Canada, several projects have been conducted to perform accurate mass balances at pulverized coal (pc)-fired utilities. Part of the mercury mass balance always includes total gaseous mercury as well as a determination of the speciation of the mercury emissions and a concentration bound to the particulate matter. This information then becomes useful in applying mercury control strategies, since the elemental mercury has traditionally been difficult to control by most technologies. In this instance, oxidation technologies have proven most beneficial for increased capture. Despite many years of mercury measurement and control projects at pc-fired units, far less work has been done on circulating fluidized-bed (CFB) units, which are able to combust a variety of feedstocks, including cofiring coal with biomass. Indeed, these units have proven to be more problematic because it is very difficult to obtain a reliable mercury mass balance. These units tend to have very different temperature profiles than pc-fired utility boilers. The flexibility of CFB units also tends to be an issue when a mercury balance is determined, since the mercury inputs to the system come from the bed material and a variety of fuels, which can have quite variable chemistry, especially for mercury. In addition, as an integral part of the CFB operation, the system employs a feedback loop to circulate the bed material through the combustor and the solids collection system (the primary cyclone), thereby subjecting particulate-bound metals to higher temperatures again. Despite these issues, CFB boilers generally emit very little mercury and show good native capture. The Energy & Environmental Research Center is carrying out this project for Metso Power in order to characterize the fate of mercury across the unit at Rosebud Plant, an industrial user of CFB technology from Metso. Appropriate solids were collected, and flue gas samples were obtained using the Ontario Hydro method, mercury continuous emission monitors, and sorbent trap methods. In addition, chlorine and fluorine were determined for solids and in the flue gas stream. Results of this project have indicated a very good mercury mass balance for Rosebud Plant, indicating 105 {+-} 19%, which is well within acceptable limits. The mercury flow through the system was shown to be primarily in with the coal and out with the flue gas, which falls outside of the norm for CFB boilers.

  20. Condensing economizers for thermal efficiency improvements and emissions control

    SciTech Connect (OSTI)

    Heaphy, J.P.; Carbonara, J.; Litzke, W.; Butcher, T.A.

    1993-12-31

    Flue gas condensing economizers improve the thermal efficiency of boilers by recovering sensible heat and water vapor latent heat from flue gas exhaust. In addition to improving thermal efficiency, condensing economizers also have the potential to act as control devices for emissions of particulates, SO{sub x}, and air toxics. Both Consolidated Edison of New York and Brookhaven National LaborAtory are currently working on condensing economizer technology with an emphasis on developing their potential for emissions control. Con Edison is currently conducting a condensing economizer demonstration at their oil-fired 74th Street Station in New York. Since installing this equipment in February of 1992 a heat rate improvement of 800 Btu/kWh has been seen. At another location, Ravenswood Station, a two stage condensing economizer has been installed in a pilot test. In this advanced configuration -the ``Integrated Flue Gas Treatment or IFGT system- two heat exchanger sections are installed and sprays of water with and without SO{sub 2} sorbents are included. Detailed studies of the removal of particulates, SO{sub 2}, SO{sub 3}, and selected air toxics have been done for a variety of operating conditions. Removal efficiencies for SO{sub 2} have been over 98% and for SO{sub 3} over 65%. Brookhaven National Laboratory`s studies involve predicting and enhancing particulate capture in condensing economizers with an emphasis on small, coal-fired applications. This work is funded by the Pittsburgh Energy Technology Center of the Department of Energy. Flyash capture efficiencies as high as 97% have been achieved to date with a single stage economizer.

  1. Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering

    SciTech Connect (OSTI)

    M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov

    2007-07-01

    Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

  2. On-Board Engine Exhaust Particulate Matter Sensor for HCCI and Conventional Diesel Engines

    SciTech Connect (OSTI)

    Hall, Matt; Matthews, Ron

    2011-09-30

    The goal of the research was to refine and complete development of an on-board particulate matter (PM) sensor for diesel, DISI, and HCCI engines, bringing it to a point where it could be commercialized and marketed.

  3. Engine-External HC-Dosing for Regeneration of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to ...

  4. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  5. Imaging of Diesel Particulate Filters using a High-Flux Neutron Source |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Imaging of Diesel Particulate Filters using a High-Flux Neutron Source Detailed images of deposits identified inside automotive DPFs using neutrons show how the deposits of soot, ash, and washcoat occurs within the filter. PDF icon p-14_toops.pdf More Documents & Publications Neutron Imaging of Advanced Engine Technologies Neutron Imaging of Advanced Engine Technologies Non-Destructive Neutron

  6. Development of SCR on Diesel Particulate Filter System for Heavy Duty

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy SCR on Diesel Particulate Filter System for Heavy Duty Applications Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications Evaluation of a system consisting of SCRDPF in comparison to a commercial 2010 CDPF system on an engine under high and low engine-out NOx conditions PDF icon deer12_naseri.pdf More Documents & Publications Investigation on continuous soot oxidation and NOx reduction by SCR coated DPF SCR-DPF Integrations

  7. New Measurement Explores Fine Details of Proton Structure | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement Explores Fine Details of Proton Structure BigCal, contained 1,744 lead glass bars The new calorimeter, called BigCal, contained 1,744 lead glass bars, such as the one shown, for detecting the scattered electrons. A collaboration of scientists is probing deep inside the proton at Jefferson Lab by measuring quantities that relate to the proton's shape and size. These so-called form factors give scientists a tool for studying the proton's inner structure. "In principle, we would

  8. Process for preparing fine grain titanium carbide powder

    DOE Patents [OSTI]

    Janney, M.A.

    1985-03-12

    A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

  9. Process for making ultra-fine ceramic particles

    DOE Patents [OSTI]

    Stangle, Gregory C. (Alfred, NY); Venkatachari, Koththavasal R. (Hornell, NY); Ostrander, Steven P. (Scotia, NY); Schulze, Walter A. (Alfred Station, NY)

    1995-01-01

    A process for producing ultra-fine ceramic particles in which droplets are formed from a ceramic precursor mixture containing a metal cation, a nitrogen-containing fuel, a solvent, and an anion capable of participating in an anionic oxidation-reduction reaction with the nitrogen containing fuel. The nitrogen-containing fuel contains at least three nitrogen atoms, at least one oxygen atom, and at least one carbon atom. The ceramic precursor mixture is dried to remove at least 85 weight percent of the solvent, and the dried mixture is then ignited to form a combusted powder.

  10. Process for preparing fine grain titanium carbide powder

    DOE Patents [OSTI]

    Janey, Mark A. (Concord, TN)

    1986-01-01

    A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular-level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

  11. Optical and Physical Properties from Primary On-Road Vehicle ParticleEmissions And Their Implications for Climate Change

    SciTech Connect (OSTI)

    Strawa, A.W.; Kirchstetter, T.W.; Hallar, A.G.; Ban-Weiss, G.A.; McLaughlin, J.P.; Harley, R.A.; Lunden, M.M.

    2009-01-23

    During the summers of 2004 and 2006, extinction and scattering coefficients of particle emissions inside a San Francisco Bay Area roadway tunnel were measured using a combined cavity ring-down and nephelometer instrument. Particle size distributions and humidification were also measured, as well as several gas phase species. Vehicles in the tunnel traveled up a 4% grade at a speed of approximately 60 km h{sup -1}. The traffic situation in the tunnel allows the apportionment of emission factors between light duty gasoline vehicles and diesel trucks. Cross-section emission factors for optical properties were determined for the apportioned vehicles to be consistent with gas phase and particulate matter emission factors. The absorption emission factor (the absorption cross-section per mass of fuel burned) for diesel trucks (4.4 {+-} 0.79 m{sup 2} kg{sup -1}) was 22 times larger than for light-duty gasoline vehicles (0.20 {+-} 0.05 m{sup 2} kg{sup -1}). The single scattering albedo of particles - which represents the fraction of incident light that is scattered as opposed to absorbed - was 0.2 for diesel trucks and 0.3 for light duty gasoline vehicles. These facts indicate that particulate matter from motor vehicles exerts a positive (i.e., warming) radiative climate forcing. Average particulate mass absorption efficiencies for diesel trucks and light duty gasoline vehicles were 3.14 {+-} 0.88 m{sup 2} g{sub PM}{sup -1} and 2.9 {+-} 1.07 m{sup 2} g{sub PM}{sup -1}, respectively. Particle size distributions and optical properties were insensitive to increases in relative humidity to values in excess of 90%, reinforcing previous findings that freshly emitted motor vehicle particulate matter is hydrophobic.

  12. Simulations of the Fuel Economy and Emissions of Hybrid Transit Buses over Planned Local Routes

    SciTech Connect (OSTI)

    Gao, Zhiming; LaClair, Tim J; Daw, C Stuart; Smith, David E; Franzese, Oscar

    2014-01-01

    We present simulated fuel economy and emissions city transit buses powered by conventional diesel engines and diesel-hybrid electric powertrains of varying size. Six representative city drive cycles were included in the study. In addition, we included previously published aftertreatment device models for control of CO, HC, NOx, and particulate matter (PM) emissions. Our results reveal that bus hybridization can significantly enhance fuel economy by reducing engine idling time, reducing demands for accessory loads, exploiting regenerative braking, and shifting engine operation to speeds and loads with higher fuel efficiency. Increased hybridization also tends to monotonically reduce engine-out emissions, but trends in the tailpipe (post-aftertreatment) emissions involve more complex interactions that significantly depend on motor size and drive cycle details.

  13. Supercritical fluid molecular spray thin films and fine powders

    DOE Patents [OSTI]

    Smith, Richard D.

    1988-01-01

    Solid films are deposited, or fine powders formed, by dissolving a solid material into a supercritical fluid solution at an elevated pressure and then rapidly expanding the solution through a short orifice into a region of relatively low pressure. This produces a molecular spray which is directed against a substrate to deposit a solid thin film thereon, or discharged into a collection chamber to collect a fine powder. The solvent is vaporized and pumped away. Solution pressure is varied to determine, together with flow rate, the rate of deposition and to control in part whether a film or powder is produced and the granularity of each. Solution temperature is varied in relation to formation of a two-phase system during expansion to control porosity of the film or powder. A wide variety of film textures and powder shapes are produced of both organic and inorganic compounds. Films are produced with regular textural feature dimensions of 1.0-2.0 .mu.m down to a range of 0.01 to 0.1 .mu.m. Powders are formed in very narrow size distributions, with average sizes in the range of 0.02 to 5 .mu.m.

  14. Implementing Strategies for Drying and Pressing Wood Without Emissions Controls

    SciTech Connect (OSTI)

    Sujit Banerjee; Terrance Conners

    2007-09-07

    Drying and pressing wood for the manufacture of lumber, particleboard, oriented strand board (OSB), veneer and medium density fiberboard (MDF) release volatile organic compounds (VOCs) into the atmosphere. These emissions require control equipment that are capital-intensive and consume significant quantities of natural gas and electricity. The objective of our work was to understand the mechanisms through which volatile organic compounds are generated and released and to develop simple control strategies. Of the several strategies developed, two have been implemented for OSB manufacture over the course of this study. First, it was found that increasing final wood moisture by about 2-4 percentage points reduced the dryer emissions of hazardous air pollutants by over 70%. As wood dries, the escaping water evaporatively cools the wood. This cooling tapers off wood when the wood is nearly dry and the wood temperature rises. Thermal breakdown of the wood tissue occurs and VOCs are released. Raising the final wood moisture by only a few percentage points minimizes the temperature rise and reduces emissions. Evaporative cooling also impacts has implications for VOC release from wood fines. Flaking wood for OSB manufacture inevitable generates fines. Fines dry out rapidly because of their high surface area and evaporative cooling is lost more rapidly than for flakes. As a result, fines emit a disproportionate quantity of VOCs. Fines can be reduced in two ways: through screening of the green furnish and through reducing their generation during flaking. The second approach is preferable because it also increased wood yield. A procedure to do this by matching the sharpness angle of the flaker knife to the ambient temperature was also developed. Other findings of practical interests are as follows: Dielectric heating of wood under low-headspace conditions removes terpenes and other extractives from softwood; The monoterpene content in trees depend upon temperature and seasonal effects; Method 25A emissions from lumber drying can be modeled from a knowledge of the airflow through the kiln; A heat transfer model shows that VOCs released during hot-pressing mainly originate from the surface of the board; and Boiler ash can be used to adsorb formaldehyde from air streams.

  15. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Kang, T.W.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.; AMAX Research and Development Center, Golden, CO )

    1989-10-01

    The main objective of this research is to develop a thermal process for drying fine coal that (1) reduces explosion potential, (2) uses a fluidized bed with minimum elutriation, (3) produces a stable dry coal by preventing moisture reabsorption and autogeneous heating, (4) reduces fugitive dust emissions, and (5) is technically and economically feasible. The project scope of work requires completion of five tasks: (1) project planning, (2) characterization of the two feed coals, (3) bench-scale IFB drying studies, (4) product characterization and testing, and (5) technical and economic process evaluation. The project technical achievements are primarily related to understanding of the behavior of the two coals in the IFB reactor. Solids residence time and solids entrainment can be correlated using the Reynolds number. Gas produced from the coal during drying and the product composition can be correlated to the average dryer temperature. A dry product with minimal proximate moisture and substantially increased heating value can be produced from either of these coals under a wide variety of fluidizing gas-to-solids ratios and IFB operating temperatures. Product characterization indicates that moisture reabsorption can be significantly reduced and that fugitive dust contents can be almost completely reduced. 4 refs., 19 figs., 24 tabs.

  16. Secondary Emission Calorimetry

    SciTech Connect (OSTI)

    Winn, David Roberts

    2015-03-24

    This report describes R&D on a new type of calorimeter using secondary emission to measure the energy of radiation, particularly high energy particles.

  17. Carbon Emissions: Paper Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994...

  18. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.

  19. COMPILATION OF REGIONAL TO GLOBAL INVENTORIES OF ANTHROPOGENIC EMISSIONS

    SciTech Connect (OSTI)

    BENKOVITZ,C.M.

    2002-11-01

    The mathematical modeling of the transport and transformation of trace species in the atmosphere is one of the scientific tools currently used to assess atmospheric chemistry, air quality, and climatic conditions. From the scientific but also from the management perspectives accurate inventories of emissions of the trace species at the appropriate spatial, temporal, and species resolution are required. There are two general methodologies used to estimate regional to global emissions: bottom-up and top-down (also known as inverse modeling). Bottom-up methodologies to estimate industrial emissions are based on activity data, emission factors (amount of emissions per unit activity), and for some inventories additional parameters (such as sulfur content of fuels). Generally these emissions estimates must be given finer sectoral, spatial (usually gridded), temporal, and for some inventories species resolution. Temporal and spatial resolution are obtained via the use of surrogate information, such as population, land use, traffic counts, etc. which already exists in or can directly be converted to gridded form. Speciation factors have been and are being developed to speciate inventories of NO{sub x}, particulate matter, and hydrocarbons. Top-down (inverse modeling) methodologies directly invert air quality measurements in terms of poorly known but critical parameters to constrain the emissions needed to explain these measurements; values of these parameters are usually computed using atmospheric transport models. Currently there are several strong limitations of inverse modeling, but the continued evolution of top-down estimates will be facilitated by the development of denser monitoring networks and by the massive amounts of data from satellite observations.

  20. Sizes, graphitic structures and fractal geometry of light-duty diesel engine particulates.

    SciTech Connect (OSTI)

    Lee, K. O.; Zhu, J.; Ciatti, S.; Choi, M. Y.; Energy Systems; Drexel Univ.

    2003-01-01

    The particulate matter of a light-duty diesel engine was characterized in its morphology, sizes, internal microstructures, and fractal geometry. A thermophoretic sampling system was employed to collect particulates directly from the exhaust manifold of a 1.7-liter turbocharged common-rail direct-injection diesel engine. The particulate samples collected at various engine-operating conditions were then analyzed by using a high-resolution transmission electron microscope (TEM) and an image processing/data acquisition system. Results showed that mean primary particle diameters (dp), and radii of gyration (Rg), ranged from 19.4 nm to 32.5 nm and 77.4 nm to 134.1 nm, respectively, through the entire engine-operating conditions of 675 rpm (idling) to 4000 rpm and 0% to 100% loads. It was also revealed that the other important parameters sensitive to the particulate formation, such as exhaust-gas recirculation (EGR) rate, equivalence ratio, and temperature, affected particle sizes significantly. Bigger primary particles were measured at higher EGR rates, higher equivalence ratios (fuel-rich), and lower exhaust temperatures. Fractal dimensions (D{sup f}) were measured at a range of 1.5 - 1.7, which are smaller than those measured for heavy-duty direct-injection diesel engine particulates in our previous study. This finding implies that the light-duty diesel engine used in this study produces more stretched chain-like shape particles, while the heavy-duty diesel engine emits more spherical particles. The microstructures of diesel particulates were observed at high TEM magnifications and further analyzed by a Raman spectroscope. Raman spectra revealed an atomic structure of the particulates produced at high engine loads, which is similar to that of typical graphite.

  1. Air Emission Inventory for the INEEL -- 1999 Emission Report

    SciTech Connect (OSTI)

    Zohner, Steven K

    2000-05-01

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  2. Characterization and modification of particulate properties to enhance filtration performance

    SciTech Connect (OSTI)

    Snyder, T.R.; Robinson, M.S.; Vann Bush, P.

    1989-06-22

    This report describes the results of project activities that occurred during the period from March 1 through May 31, 1989. The organization of this report generally follows the outline of work presented in the Project Work Plan. Work performed during this period included tests under Task 2 -- Parametric Tests of Ashes and Fabrics, and Task 3 -- Survey of Methods to Modify Particle Filtration Properties. Discussion of the Task 2 work has been organized topically, rather than adhering to the activities specified in the Work Plan. Cohesive ash from the Tennessee Valley Authority's 160 MW Atmospheric Fluidized-Bed Combustor at the Shawnee Plant in Paducah, Kentucky was obtained during this quarter and has been analyzed in the laboratory. The second phase of the abstract search and review of pertinent articles included in activity 3.1 is nearly complete. A summary of this phase of the literature search is included in this report. A variety of potential conditioning agents have been evaluated during this reporting period. These agents include sodium bicarbonate, hydrated lime, various grades of fine silica powder, gasifier char, glass beads and glass fibers. The three source ashes have been mixed with these agents in different concentrations and using various mixing techniques. These tests are continuing, and this report contains a summary of the combinations evaluated during this past quarter. 17 figs., 7 tabs.

  3. CNG and Diesel Transit Bus Emissions in Review

    SciTech Connect (OSTI)

    Ayala, A.; Kado, N.; Okamoto, R.; Gebel, M. Rieger, P.; Kobayashi, R.; Kuzmicky, P.

    2003-08-24

    Over the past three years, the California Air Resources Board (CARB), in collaboration with the University of California and other entities, has investigated the tailpipe emissions from three different latemodel, in-use heavy-duty transit buses in five different configurations. The study has focused on the measurement of regulated emissions (NOX, HC, CO, total PM), other gaseous emissions (CO2, NO2, CH4, NMHC), a number of pollutants of toxic risk significance (aromatics, carbonyls, PAHs, elements), composition (elemental and organic carbon), and the physical characterization (size-segregated number count and mass) of the particles in the exhaust aerosol. Emission samples are also tested in a modified Ames assay. The impact of oxidation catalyst control for both diesel and compressed natural gas (CNG) buses and a passive diesel particulate filter (DPF) were evaluated over multiple driving cycles (idle, 55 mph cruise, CBD, UDDS, NYBC) using a chassis dynamometer. For brevity, only CBD results are discussed in this paper and particle sizing results are omitted. The database of results is large and some findings have been reported already at various forums including last year's DEER conference. The goal of this paper is to offer an overview of the lessons learned and attempt to draw overall conclusions and interpretations based on key findings to date.

  4. Programmable Differential Delay Circuit With Fine Delay Adjustment

    DOE Patents [OSTI]

    DeRyckere, John F. (Eau Claire, WI); Jenkins, Philip Nord (Eau Claire, WI); Cornett, Frank Nolan (Chippewa Falls, WI)

    2002-07-09

    Circuitry that provides additional delay to early arriving signals such that all data signals arrive at a receiving latch with same path delay. The delay of a forwarded clock reference is also controlled such that the capturing clock edge will be optimally positioned near quadrature (depending on latch setup/hold requirements). The circuitry continuously adapts to data and clock path delay changes and digital filtering of phase measurements reduce errors brought on by jittering data edges. The circuitry utilizes only the minimum amount of delay necessary to achieve objective thereby limiting any unintended jitter. Particularly, this programmable differential delay circuit with fine delay adjustment is designed to allow the skew between ASICS to be minimized. This includes skew between data bits, between data bits and clocks as well as minimizing the overall skew in a channel between ASICS.

  5. Stabilizing soft fine-grained soils with fly ash

    SciTech Connect (OSTI)

    Edil, T.B.; Acosta, H.A.; Benson, C.H.

    2006-03-15

    The objective of this study was to evaluate the effectiveness of self-cementing fly ashes derived from combustion of subbituminous coal at electric power plants for stabilization of soft fine-grained soils. California bearing ratio (CBR) and resilient modulus (M{sub r}) tests were conducted on mixtures prepared with seven soft fine-grained soils (six inorganic soils and one organic soil) and four fly ashes. The soils were selected to represent a relatively broad range of plasticity, with plasticity indices ranging between 15 and 38. Two of the fly ashes are high quality Class C ashes (per ASTM C 618) that are normally used in Portland cement concrete. The other ashes are off-specification ashes, meaning they do not meet the Class C or Class F criteria in ASTM C 618. Tests were conducted on soils and soil-fly ash mixtures prepared at optimum water content (a standardized condition), 7% wet of optimum water content (representative of the typical in situ condition in Wisconsin), and 9-18% wet of optimum water content (representative of a very wet in situ condition). Addition of fly ash resulted in appreciable increases in the CBR and M{sub r} of the inorganic soils. For water contents 7% wet of optimum, CBRs of the soils alone ranged between 1 and 5. Addition of 10% fly ash resulted in CBRs ranging between 8 and 17, and 18% fly ash resulted in CBRs between 15 and 31. Similarly, M{sub r} of the soil alone ranged between 3 and 15 MPa at 7% wet of optimum, whereas addition of 10% fly ash resulted in M{sub r} between 12 and 60 MPa and 18% fly ash resulted in M{sub r} between 51 and 106 MPa. In contrast, except for one fly ash, addition of fly ash generally had little effect on CBR or M{sub r} of the organic soil.

  6. DEVELOPMENT OF A NOVEL FINE COAL CLEANING SYSTEM

    SciTech Connect (OSTI)

    Manoj K. Mohanty

    2005-06-01

    The goal of the proposed project was to develop a novel fine coal separator having the ability to clean 1 mm x 0 size coal in a single processing unit. The novel fine coal separator, named as EG(Enhanced Gravity) Float Cell, utilizes a centrifugal field to clean 1 mm x 250 micron size coal, whereas a flotation environment to clean minus 250 micron coal size fraction. Unlike a conventional enhanced gravity concentrator, which rotates to produce a centrifugal field requiring more energy, the EG Float Cell is fed with a tangential feed slurry to generate an enhanced gravity field without any rotating part. A prototype EG Float Cell unit having a maximum diameter of 60 cm (24 inch) was fabricated during the first-half of the project period followed by a series of exploratory tests to make suitable design modification. Test data indicated that there was a significant concentration of coarse heavy materials in the coarse tailings discharge of the EG Float Cell. The increase in weight (%) of 1 mm x 250 micron (16 x 60 mesh) size fraction from 48.9% in the feed to 72.2% in the coarse tailings discharge and the corresponding increase in the ash content from 56.9% to 87.0% is indicative of the effectiveness of the enhanced gravity section of the EG Float Cell. However, the performance of the flotation section needs to be improved. Some of the possible design modifications may include more effective air sparging system for the flotation section to produce finer bubbles and a better wash water distributor.

  7. Evaluation of static pressure drops and PM10 and TSP emissions for modified 1D-3D cyclones

    SciTech Connect (OSTI)

    Holt, G.A.; Baker, R.V.; Hughs, S.E.

    1999-12-01

    Five modifications of a standard 1D3D cyclone were tested and compared against the standard 1D3D design in the areas of particulate emissions and static pressure drop across the cyclone. The modifications to the 1D3D design included a 2D2D inlet, a 2D2D air outlet, a D/3 trash exit, an expansion chamber with a D/3 trash exit, and a tapered air outlet duct. The 1D3D modifications that exhibited a significant improvement in reducing both PM10 and total suspended particulate (TSP) emissions were the designs with the 2D2D inlet and air exhaust combined with either the conical D/3 tail cone or the expansion chamber. In reference to the standard 1D3D cyclone, the average reduction in PM10 emissions was 24 to 29% with a 29 to 35% reduction observed in TSP emissions. The modifications with the tapered air outlets did not show any significant improvements in controlling PM10 emissions. However, the modification with the tapered air outlet/expansion chamber combination exhibited statistical significance in reducing TSP emissions by 18% compared to the 1D3D cyclone. All modifications tested exhibited lower static pressure drops than the standard 1D3D.

  8. Heavy-Duty Stoichiometric Compression Ignition Engine with Improved Fuel Economy over Alternative Technologies for Meeting 2010 On-Highway Emission

    SciTech Connect (OSTI)

    Kirby J. Baumgard; Richard E. Winsor

    2009-12-31

    The objectives of the reported work were: to apply the stoichiometric compression ignition (SCI) concept to a 9.0 liter diesel engine; to obtain engine-out NO{sub x} and PM exhaust emissions so that the engine can meet 2010 on-highway emission standards by applying a three-way catalyst for NO{sub x} control and a particulate filter for PM control; and to simulate an optimize the engine and air system to approach 50% thermal efficiency using variable valve actuation and electric turbo compounding. The work demonstrated that an advanced diesel engine can be operated at stoichiometric conditions with reasonable particulate and NOx emissions at full power and peak torque conditions; calculated that the SCI engine will operate at 42% brake thermal efficiency without advanced hardware, turbocompounding, or waste heat recovery; and determined that EGR is not necessary for this advanced concept engine, and this greatly simplifies the concept.

  9. Development of a Low-Cost Particulate Matter Monitor

    SciTech Connect (OSTI)

    White, Richard M.; Apte, Michael G.; Gundel, Lara A.; Black, Justin

    2008-08-01

    We describe a small, inexpensive portable monitor for airborne particulates, composed of the following elements: a. A simple size-selective inlet (vertical elutriator) that permits only particles below a pre-set diameter to pass and enter the measurement section; b. A measurement section in which passing particles are deposited thermophoretically on a micro-fabricated resonant piezoelectric mass sensor; c. An optical characterization module co-located with the mass sensor module that directs infrared and ultraviolet beams through the deposit. The emergent optical beams are detected by a photodiode. The optical absorption of the deposit can be measured in order to characterize the deposit, and determine how much is due to diesel exhaust and/or environmental tobacco smoke; and d. A small pump that moves air through the device, which may also be operated in a passive mode. The component modules were designed by the project team, and fabricated at UCB andLBNL. Testing and validation were performed in a room-sized environmental chamber at LBNL in to which was added either environmental tobacco smoke (ETS, produced by a cigarette smoking machine) or diesel exhaust (from a conventional diesel engine). Two pilot field tests in a dwelling compared the monitor with existing aerosol instruments during exposure to infiltrated ambient air to which cigarette smoke, diesel exhaust, wood smoke and cooking fumes were added. The limit of detection (LOD) derived from statistical analysis of field data is 18 mu g m-3, at the 99percent confidence level. The monitor weighs less than 120 g and has a volume of roughly 250 cm3. Power consumption is approximately 100 milliwatts. During this study, the optical component of the device was not fully implemented and has been left for future efforts. Suggested improvements in the current prototype include use of integrated thermal correction, reconfiguration of the resonator for increased particle collection area, increased thermophoretic collection efficiency using an increased temperature gradient, and shielding the resonator electronics from deposition of ultrafine particles.

  10. Plasma regenerated particulate trap and NO.sub.x reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2000-01-01

    A non-catalytic two-stage process for removal of NO.sub.x and particulates from engine exhaust comprises a first stage that plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, and a second stage, which preferably occurs simultaneously with the first stage, that converts NO.sub.2 and carbon soot particles to respective environmentally benign gases that include N.sub.2 and CO.sub.2. By preconverting NO to NO.sub.2 in the first stage, the efficiency of the second stage for NO.sub.x reduction is enhanced while carbon soot from trapped particulates is simultaneously converted to CO.sub.2 when reacting with the NO.sub.2 (that converts to N.sub.2). For example, an internal combustion engine exhaust is connected by a pipe to a chamber where carbon-containing particulates are electrostatically trapped or filtered and a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. Volatile hydrocarbons (C.sub.x H.sub.y) from the trapped particulates are oxidized in the plasma and the remaining soot from the particulates reacts with the NO.sub.2 to convert NO.sub.2 to N.sub.2, and the soot to CO.sub.2. The nitrogen exhaust components remain in the gas phase throughout the process, with no accompanying adsorption.

  11. Emissions inventory report summary for Los Alamos National Laboratory for calendar year 2008

    SciTech Connect (OSTI)

    Ecology and Air Quality Group

    2009-10-01

    Los Alamos National Laboratory (LANL) is subject to annual emissions reporting requirements for regulated air pollutants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), Notice of Intent and Emissions Inventory Requirements. The applicability of the requirements is based on the Laboratory’s potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. Additionally, on April 30, 2004, LANL was issued a Title V Operating Permit from the New Mexico Environment Department/Air Quality Bureau, under 20.2.70 NMAC. This permit was modified and reissued on July 16, 2007. This Title V Operating Permit (Permit No. P-100M2) includes emission limits and operating limits for all regulated sources of air pollution at LANL. The Title V Operating Permit also requires semiannual emissions reporting for all sources included in the permit. This report summarizes both the annual emissions inventory reporting and the semiannual emissions reporting for LANL for calendar year 2008. LANL’s 2008 emissions are well below the emission limits in the Title V Operating Permit.

  12. Emissions Inventory Report Summary for Los Alamos National Laboratory for Calendar Year 2004

    SciTech Connect (OSTI)

    M. Stockton

    2005-10-01

    Los Alamos National Laboratory (LANL) is subject to annual emissions reporting requirements for regulated air pollutants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), ''Notice of Intent and Emissions Inventory Requirements''. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. Additionally, on April 30, 2004, LANL was issued a Title V Operating Permit from the New Mexico Environment Department, Air Quality Bureau, under 20.2.70 NMAC. This Title V Operating Permit (Permit No. P-100) includes emission limits and operating limits for all regulated sources of air pollution at LANL. The Title V Operating Permit also requires semi-annual emissions reporting for all sources included in the permit. This report summarizes both the annual emissions inventory reporting and the semi-annual emissions reporting for LANL for calendar year 2004. LANL's 2004 emissions are well below the emission limits in the Title V Operating Permit.

  13. Emissions Inventory Report Summary for Los Alamos National Laboratory for Calendar Year 2009

    SciTech Connect (OSTI)

    Environmental Stewardship Group

    2010-10-01

    Los Alamos National Laboratory (LANL) is subject to annual emissions reporting requirements for regulated air pollutants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), Notice of Intent and Emissions Inventory Requirements. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. Additionally, on April 30, 2004, LANL was issued a Title V Operating Permit from the New Mexico Environment Department/Air Quality Bureau, under 20.2.70 NMAC. This permit was modified and reissued on July 16, 2007. This Title V Operating Permit (Permit No. P-100M2) includes emission limits and operating limits for all regulated sources of air pollution at LANL. The Title V Operating Permit also requires semiannual emissions reporting for all sources included in the permit. This report summarizes both the annual emissions inventory reporting and the semiannual emissions reporting for LANL for calendar year 2009. LANL's 2009 emissions are well below the emission limits in the Title V Operating Permit.

  14. Effectiveness of Diesel Oxidation Catalyst in Reducing HC and CO Emissions from Reactivity Controlled Compression Ignition

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Curran, Scott; Parks, II, James E; Wagner, Robert M

    2013-01-01

    Reactivity Controlled Compression Ignition (RCCI) has been shown to allow for diesel-like or better brake thermal efficiency with significant reductions in nitrogen oxide (NOX) particulate matter (PM) emissions. Hydrocarbon (HC) and carbon monoxide (CO) emission levels, on the other hand, are similar to those of port fuel injected gasoline engines. The higher HC and CO emissions combined with the lower exhaust temperatures with RCCI operation present a challenge for current exhaust aftertreatments. The reduction of HC and CO emissions in a lean environment is typically achieved with an oxidation catalyst. In this work, several diesel oxidation catalysts (DOC) with different precious metal loadings were evaluated for effectiveness to control HC and CO emissions from RCCI combustion in a light-duty multi-cylinder engine operating on gasoline and diesel fuels. Each catalyst was evaluated in a steady-state engine operation with temperatures ranging from 160 to 260 C. A shift to a higher light-off temperature was observed during the RCCI operation. In addition to the steady-state experiments, the performances of the DOCs were evaluated during multi-mode engine operation by switching from diesel-like combustion at higher exhaust temperature and low HC/CO emissions to RCCI combustion at lower temperature and higher HC/CO emissions. High CO and HC emissions from RCCI generated an exotherm keeping the catalyst above the light-off temperature.

  15. Emissions Inventory Report Summary for Los Alamos National Laboratory for Calendar Year 2006

    SciTech Connect (OSTI)

    Ecology and Air Quality Group

    2007-09-28

    Los Alamos National Laboratory (LANL) is subject to annual emissions reporting requirements for regulated air pollutants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), Notice of Intent and Emissions Inventory Requirements. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. Additionally, on April 30, 2004, LANL was issued a Title V Operating Permit from the New Mexico Environment Department, Air Quality Bureau, under 20.2.70 NMAC. Modification Number 1 to this Title V Operating Permit was issued on June 15, 2006 (Permit No P-100M1) and includes emission limits and operating limits for all regulated sources of air pollution at LANL. The Title V Operating Permit also requires semi-annual emissions reporting for all sources included in the permit. This report summarizes both the annual emissions inventory reporting and the semi-annual emissions reporting for LANL for calendar year 2006. LANL's 2006 emissions are well below the emission limits in the Title V Operating Permit.

  16. Simulated fuel economy and emissions performance during city and interstate driving for a heavy-duty hybrid truck

    SciTech Connect (OSTI)

    Daw, C Stuart; Gao, Zhiming; Smith, David E; LaClair, Tim J; Pihl, Josh A; Edwards, Kevin Dean

    2013-01-01

    We compare simulated fuel economy and emissions for both conventional and hybrid class 8 heavy-duty diesel trucks operating over multiple urban and highway driving cycles. Both light and heavy freight loads were considered, and all simulations included full aftertreatment for NOx and particulate emissions controls. The aftertreatment components included a diesel oxidation catalyst (DOC), urea-selective catalytic NOx reduction (SCR), and a catalyzed diesel particulate filter (DPF). Our simulated hybrid powertrain was configured with a pre-transmission parallel drive, with a single electric motor between the clutch and gearbox. A conventional HD truck with equivalent diesel engine and aftertreatment was also simulated for comparison. Our results indicate that hybridization can significantly increase HD fuel economy and improve emissions control in city driving. However, there is less potential hybridization benefit for HD highway driving. A major factor behind the reduced hybridization benefit for highway driving is that there are fewer opportunities to utilize regenerative breaking. Our aftertreatment simulations indicate that opportunities for passive DPF regeneration are much greater for both hybrid and conventional trucks during highway driving due to higher sustained exhaust temperatures. When passive DPF regeneration is extensively utilized, the fuel penalty for particulate control is virtually eliminated, except for the 0.4%-0.9% fuel penalty associated with the slightly higher exhaust backpressure.

  17. Impact of Biodiesel on the Oxidation Kinetics and Morphology of Diesel Particulate

    SciTech Connect (OSTI)

    Strzelec, Andrea; Toops, Todd J; Daw, C Stuart

    2011-01-01

    We compare the oxidation characteristics of four different diesel particulates generated with a modern light-duty engine. The four particulates represent engine fueling with conventional ultra-low sulfur diesel (ULSD), biodiesel, and two intermediate blends of these fuels. The comparisons discussed here are based on complementary measurements implemented in a laboratory micro-reactor, including temperature programmed desorption and oxidation, pulsed isothermal oxidation, and BET surface area. From these measurements we have derived models that are consistent with the observed oxidation reactivity differences. When accessible surface area effects are properly accounted for, the oxidation kinetics of the fixed carbon components were found to consistently exhibit an Arrhenius activation energy of 113 6 kJ/mol. Release of volatile carbon from the as-collected particulate appears to follow a temperaturedependent rate law.

  18. Apparatus for real-time airborne particulate radionuclide collection and analysis

    DOE Patents [OSTI]

    Smart, John E. (West Richland, WA); Perkins, Richard W. (Richland, WA)

    2001-01-01

    An improved apparatus for collecting and analyzing an airborne particulate radionuclide having a filter mounted in a housing, the housing having an air inlet upstream of the filter and an air outlet downstream of the filter, wherein an air stream flows therethrough. The air inlet receives the air stream, the filter collects the airborne particulate radionuclide and permits a filtered air stream to pass through the air outlet. The improvement which permits real time counting is a gamma detecting germanium diode mounted downstream of the filter in the filtered air stream. The gamma detecting germanium diode is spaced apart from a downstream side of the filter a minimum distance for a substantially maximum counting detection while permitting substantially free air flow through the filter and uniform particulate radionuclide deposition on the filter.

  19. Emission Abatement System

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2003-05-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  20. Evaluating Radionuclide Air Emission Stack Sampling Systems

    SciTech Connect (OSTI)

    Ballinger, Marcel Y.

    2002-12-16

    The Pacific Northwest National Laboratory (PNNL) operates a number of research and development (R&D) facilities for the U.S. Department of Energy at the Hanford Site, Washington. These facilities are subject to Clean Air Act regulations that require sampling of radionuclide air emissions from some of these facilities. A revision to an American National Standards Institute (ANSI) standard on sampling radioactive air emissions has recently been incorporated into federal and state regulations and a re-evaluation of affected facilities is being performed to determine the impact. The revised standard requires a well-mixed sampling location that must be demonstrated through tests specified in the standard. It also carries a number of maintenance requirements, including inspections and cleaning of the sampling system. Evaluations were performed in 2000 2002 on two PNNL facilities to determine the operational and design impacts of the new requirements. The evaluation included inspection and cleaning maintenance activities plus testing to determine if the current sampling locations meet criteria in the revised standard. Results show a wide range of complexity in inspection and cleaning activities depending on accessibility of the system, ease of removal, and potential impact on building operations (need for outages). As expected, these High Efficiency Particulate Air (HEPA)-filtered systems did not show deposition significant enough to cause concerns with blocking of the nozzle or other parts of the system. The tests for sampling system location in the revised standard also varied in complexity depending on accessibility of the sample site and use of a scale model can alleviate many issues. Previous criteria to locate sampling systems at eight duct diameters downstream and two duct diameters upstream of the nearest disturbances is no guarantee of meeting criteria in the revised standard. A computational fluid dynamics model was helpful in understanding flow and contaminant mixing in an exhaust system and may be useful to identify potential sampling locations in an exhaust system that are likely to meet criteria in the revised standard.

  1. In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F | Department of Energy Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F In Vitro Genotoxicity of Particulate and Semi-Volatile Organic Compound Exhaust Materails from a Set of Gasoline and a Set of Diesel Engine Vehicles Operated at 30°F 2003 DEER Conference Presentation: Centers for Disease Control and

  2. MOL.19980331.0174 PARTICULATE MATTEX AMBIENT A I R QUALITY

    National Nuclear Security Administration (NNSA)

    MOL.19980331.0174 PARTICULATE MATTEX AMBIENT A I R QUALITY DATA REPORT FOR 1989 AND 1990 WBS No. 1.2.5.4.2 Contract No. DE-AC08-87NVl0576 March 1992 Prepared by: Radiological/Environmental Field Programs Department Science Applications International Corporation Technical & Management Support Services Las Vegas, Nevada 1.0 MECUTIVE SUMMARY Routine particulate matter ambient air quality monitoring has been performed at two stations in the Yucca Mountain air monitoring network since the spring

  3. NNA.921218.0092 PARTICULATE MATIER AMEIENT AIR QUALITY DATA REPORT FOR 1991

    National Nuclear Security Administration (NNSA)

    NNA.921218.0092 PARTICULATE MATIER AMEIENT AIR QUALITY DATA REPORT FOR 1991 WBS No. 1.2.13.4.2 Contract No. DE-ACO8-87NV10576 Oc tobe r 199 2 Prepared by: Radiological/Environmental Field Programs Department Science Applications International Corporation Technical & Management Support Services L a s Vegas, Nevada TABLE OF CONTENTS m Section 1. Executive Summary 2. 3. Results Particulate Matter Ambient Air Quality Monitoring Methods List of Tables 1-1 3-1 3-2 3-3 3-4 3-5 3-6 Page 1-1 2-1 3-1

  4. Photon enhanced thermionic emission

    DOE Patents [OSTI]

    Schwede, Jared; Melosh, Nicholas; Shen, Zhixun

    2014-10-07

    Photon Enhanced Thermionic Emission (PETE) is exploited to provide improved efficiency for radiant energy conversion. A hot (greater than 200.degree. C.) semiconductor cathode is illuminated such that it emits electrons. Because the cathode is hot, significantly more electrons are emitted than would be emitted from a room temperature (or colder) cathode under the same illumination conditions. As a result of this increased electron emission, the energy conversion efficiency can be significantly increased relative to a conventional photovoltaic device. In PETE, the cathode electrons can be (and typically are) thermalized with respect to the cathode. As a result, PETE does not rely on emission of non-thermalized electrons, and is significantly easier to implement than hot-carrier emission approaches.

  5. Field emission electron source

    DOE Patents [OSTI]

    Zettl, Alexander Karlwalter (Kensington, CA); Cohen, Marvin Lou (Berkeley, CA)

    2000-01-01

    A novel field emitter material, field emission electron source, and commercially feasible fabrication method is described. The inventive field emission electron source produces reliable electron currents of up to 400 mA/cm.sup.2 at 200 volts. The emitter is robust and the current it produces is not sensitive to variability of vacuum or the distance between the emitter tip and the cathode. The novel emitter has a sharp turn-on near 100 volts.

  6. Combustion and Emissions Modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combustion and Emissions Modeling This email address is being protected from spambots. You need JavaScript enabled to view it. - Computational Fluid Dynamics Project Leader Background Modern transportation engines are designed to use the available fuel resources efficiently and minimize harmful emissions. Optimization of these designs is based on a wealth of practical design, construction and operating experiences, and use of modern testing facilities and sophisticated analyses of the combustion

  7. Regulation of Emissions from Stationary Diesel Engines (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    On July 11, 2006, the Environmental Protection Agency (EPA) issued regulations covering emissions from stationary diesel engines New Source Performance Standards that limit emissions of NOx, particulate matter, SO2, carbon monoxide, and hydrocarbons to the same levels required for nonroad diesel engines. The regulation affects new, modified, and reconstructed diesel engines. Beginning with model year 2007, engine manufacturers must specify that new engines less than 3,000 horsepower meet the same emissions standard as nonroad diesel engines. For engines greater than 3,000 horsepower, the standard will be fully effective in 2011. Stationary diesel engine fuel will also be subject to the same standard as nonroad diesel engine fuel, which reduces the sulfur content of the fuel to 500 parts per million by mid-2007 and 15 parts per million by mid-2010.

  8. Fuel-cycle energy and emissions impacts of tripled fuel economy vehicles

    SciTech Connect (OSTI)

    Mintz, M.M.; Wang, M.Q.; Vyas, A.D.

    1998-12-31

    This paper presents estimates of the full cycle energy and emissions impacts of light-duty vehicles with tripled fuel economy (3X vehicles) as currently being developed by the Partnership for a New Generation of Vehicles (PNGV). Seven engine and fuel combinations were analyzed: reformulated gasoline, methanol, and ethanol in spark-ignition, direct-injection engines; low sulfur diesel and dimethyl ether in compression-ignition, direct-injection engines; and hydrogen and methanol in fuel-cell vehicles. The fuel efficiency gain by 3X vehicles translated directly into reductions in total energy demand, petroleum demand, and carbon dioxide emissions. The combination of fuel substitution and fuel efficiency resulted in substantial reductions in emissions of nitrogen oxide, carbon monoxide, volatile organic compounds, sulfur oxide, and particulate matter smaller than 10 microns, particularly under the High Market Share Scenario.

  9. Varying fine structure 'constant' and charged black holes

    SciTech Connect (OSTI)

    Bekenstein, Jacob D.; Schiffer, Marcelo

    2009-12-15

    Speculation that the fine-structure constant {alpha} varies in spacetime has a long history. We derive, in 4-D general relativity and in isotropic coordinates, the solution for a charged spherical black hole according to the framework for dynamical {alpha} J. D. Bekenstein, Phys. Rev. D 25, 1527 (1982).. This solution coincides with a previously known one-parameter extension of the dilatonic black hole family. Among the notable properties of varying-{alpha} charged black holes are adherence to a 'no hair' principle, the absence of the inner (Cauchy) horizon of the Reissner-Nordstroem black holes, the nonexistence of precisely extremal black holes, and the appearance of naked singularities in an analytic extension of the relevant metric. The exteriors of almost extremal electrically (magnetically) charged black holes have simple structures which makes their influence on applied magnetic (electric) fields transparent. We rederive the thermodynamic functions of the modified black holes; the otherwise difficult calculation of the electric potential is done by a shortcut. We confirm that variability of {alpha} in the wake of expansion of the universe does not threaten the generalized second law.

  10. Integrated emissions control system for residential CWS furnace. Annual status report number 1, 20 September 1989--30 September 1990

    SciTech Connect (OSTI)

    Balsavich, J.C.; Breault, R.W.

    1990-10-01

    One of the major obstacles to the successful development and commercialization of a coal-fired residential furnace is the need for a reliable, cost-effective emission control system. Tecogen Inc. is developing a novel, integrated emission control system to control NO{sub x}, SO{sub 2}, and particulate emissions. A reactor provides high sorbent particle residence time within the reactor to control SO{sub 2} emissions, while providing a means of extracting a substantial amount of the particulates present in the combustion gases. Final cleanup of any flyash exiting the reactor is completed with the use of high-efficiency bag filters. Tecogen Inc. developed a residential-scale Coal Water Slurry (CWS) combustor which makes use of centrifugal forces to separate and confine larger unburned coal particles in the furnace upper chamber. Various partitions are used to retard the axial, downward flow of these particles, and thus maximize their residence time in the hottest section of the combustor. By operating this combustor under staged conditions, the local stoichiometry in the primary zone can be controlled to minimize NO{sub x} emissions. During the first year of the program, work encompassed a literature search, developing an analytical model of the SO{sub 2} reactor, fabricating and assembling the initial prototype components, testing the prototype component, and estimating the operating and manufacturing costs.

  11. A Community Emissions Data System (CEDS) for Historical Emissions

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect SciTech Connect Search Results Conference: A Community Emissions Data System (CEDS) for Historical Emissions Citation Details In-Document Search Title: A Community Emissions Data System (CEDS) for Historical Emissions Historical emission estimates for anthropogenic aerosol and precursor compounds are key data needed for Earth system models, climate models, and atmospheric chemistry and transport models; both for general analysis and assessment and also for

  12. Enhanced control of mercury emissions through modified speciation

    SciTech Connect (OSTI)

    Livengood, C.D.; Mendelsohn, M.H.

    1997-07-01

    In anticipation of possible regulations regarding mercury emissions, research efforts sponsored by DOE, EPRI, and others are investigating the risks posed by mercury emissions, improved techniques for measuring those emissions, and possible control measures. The focus in the control research is on techniques that can be used in conjunction with existing flue-gas-cleanup (FGC) systems in order to minimize additional capital costs and operational complexity. Argonne National Laboratory has supported the DOE Fossil Energy Program for over 15 years with research on advanced environmental control technologies. The emphasis in Argonne`s work has been on integrated systems that combine control of several pollutants. Specific topics have included spray drying for sulfur dioxide and particulate-matter control with high-sulfur coal, combined sulfur dioxide and nitrogen oxides control technologies, and techniques to enhance mercury control in existing FGC systems. The latter area has focused on low-cost dry sorbents for use with fabric filters or electrostatic precipitators and techniques for improving the capture of mercury in wet flue-gas desulfurization (FGD) systems. This paper presents results from recent work that has studied the effects of several oxidizing agents in combination with typical flue-gas species (e.g., nitrogen oxides and sulfur dioxide) on the oxidation of Hg{sup 0}.

  13. Controlling particulates, temperature, and tritium in an inert glovebox for a weapons program

    SciTech Connect (OSTI)

    Purson, J.D.; Powers, D.; Walthers, C.; Navarro, C.; Newman, E.; Romero, J.; Jenkins, R.

    1996-07-01

    A glovebox is described in which several environmental parameters are controlled and monitored. Included in these are particulate, tritium, water vapor, oxygen and temperature. The paper details the design rationale and process and describes the glovebox, presently in use for neutron generator production.

  14. Methods of hydrolyzing pretreated densified biomass particulates and systems related thereto

    DOE Patents [OSTI]

    Bals, Bryan; Teymouri, Farzaneh; Campbell, Tim; Dale, Bruce

    2015-02-03

    A method is provided in which pretreated and densified cellulosic biomass particulates can be hydrolyzed at a high solids loading rate as compared with the solids loading rate of loose hydrolysable cellulosic biomass fibers. The resulting high concentration sugar-containing stream can be easily converted to biofuels or an entire suite of other useful bioproducts.

  15. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) Greenhouse Gas Emissions Overview Diagram Notes [a] CO2 emissions related to petroleum consumption (includes 64 MMTCO2 of non-fuel-related emissions). [b] CO2 emissions related to coal consumption (includes 0.3 MMTCO2 of non-fuel-related emissions). [c] CO2 emissions related to natural gas consumption (includes 13 MMTCO2 of

  16. Fugitive Emissions | Department of Energy

    Energy Savers [EERE]

    Fugitive Emissions Fugitive Emissions Fugitive emissions refers to the release of greenhouse gases (GHGs) from pressurized systems. The Fugitive Emissions Working Group (FEWG) is a network of scientists, engineers, technicians, and environmental professionals representing more than 20 U.S. Department of Energy (DOE) laboratories, power marketing administrations, program offices, and National Nuclear Security Administration facilities that are working to reduce emissions of high-impact fugitive

  17. Diesel and CNG Transit Bus Emissions Characterization By Two Chassis Dynamometer Laboratories: Results and Issues

    SciTech Connect (OSTI)

    Nigel N. Clark, Mridul Gautam; Byron L. Rapp; Donald W. Lyons; Michael S. Graboski; Robert L. McCormick; Teresa L. Alleman; Paul Norton

    1999-05-03

    Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFHAER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more. The driving styles may be characterized as aggressive and non-aggressive, but both styles followed the CBD speed command acceptably. PM emissions were far higher for the aggressive driving style. For the NG fueled vehicles driving style had a similar, although smaller, effect on NO{sub x}. It is evident that driver habits may cause substantial deviation in emissions for the CBD cycle. When the CO emissions are used as a surrogate for driver aggression, a regression analysis shows that NO{sub x} and PM emissions from the two laboratories agree closely for equivalent driving style. Implications of driver habit for emissions inventories and regulations are briefly considered.

  18. Monitoring Fine Sediment; Grande Ronde and John Day Rivers, 2000 Annual Report.

    SciTech Connect (OSTI)

    Rhodes, Jonathan J.; Greene, M. Jonas; Purser, Michael D.

    2001-01-01

    Fine sediment in spawning substrate has a major effect on salmon survival from egg to smolt. Basin-wide restoration plans have established targets for fine sediment levels in spawning habitat. The project was initiated to monitor surface fine sediment levels and overwinter intrusion of fine sediment in spring chinook salmon spawning habitat in the North Fork John Day (NFJDR) and Grande Ronde Rivers, for five years. The project is also investigating the potential relationship between surface fine levels and overwinter sedimentation. It will provide data to assess trends in substrate conditions in monitored reaches and whether trends are consistent with efforts to improve salmon habitat conditions. The data on the magnitude of overwinter sedimentation will also be used to estimate salmon survival from egg to emergence. In Sept. 1998, 1999, and Aug. 2000, sites for monitoring overwinter sedimentation were established in salmon spawning habitat in the upper Grande Ronde River, Catherine Creek (a Grande Ronde tributary), the North Fork John Day River (NFJDR), and Granite Creek (a NFJDR tributary). Surface fine sediment levels were measured in these reaches via the grid method and visually estimated to test the relative accuracy of these two methods. In 1999 and 2000, surface fine sediment was also estimated via pebble counts at selected reaches to allow comparison of results among the methods. Overwintering substrate samples were collected in April 1999 and April-May 2000 to estimate the amount of overwinter sedimentation in clean gravels in spawning habitat. Monitoring methods and locations are described.

  19. Towards a Fine-Resolution Global Coupled Climate System for Prediction on

    Office of Scientific and Technical Information (OSTI)

    Decadal/Centennial Scales (Technical Report) | SciTech Connect Towards a Fine-Resolution Global Coupled Climate System for Prediction on Decadal/Centennial Scales Citation Details In-Document Search Title: Towards a Fine-Resolution Global Coupled Climate System for Prediction on Decadal/Centennial Scales The over-arching goal of this project was to contribute to the realization of a fully coupled fine resolution Earth System Model simulation in which a weather-scale atmosphere is coupled to

  20. FUEL FORMULATION EFFECTS ON DIESEL FUEL INJECTION, COMBUSTION, EMISSIONS AND EMISSION CONTROL

    SciTech Connect (OSTI)

    Boehman, A; Alam, M; Song, J; Acharya, R; Szybist, J; Zello, V; Miller, K

    2003-08-24

    This paper describes work under a U.S. DOE sponsored Ultra Clean Fuels project entitled ''Ultra Clean Fuels from Natural Gas,'' Cooperative Agreement No. DE-FC26-01NT41098. In this study we have examined the incremental benefits of moving from low sulfur diesel fuel and ultra low sulfur diesel fuel to an ultra clean fuel, Fischer-Tropsch diesel fuel produced from natural gas. Blending with biodiesel, B100, was also considered. The impact of fuel formulation on fuel injection timing, bulk modulus of compressibility, in-cylinder combustion processes, gaseous and particulate emissions, DPF regeneration temperature and urea-SCR NOx control has been examined. The primary test engine is a 5.9L Cummins ISB, which has been instrumented for in-cylinder combustion analysis and in-cylinder visualization with an engine videoscope. A single-cylinder engine has also been used to examine in detail the impacts of fuel formulation on injection timing in a pump-line-nozzle fueling system, to assist in the interpretation of results from the ISB engine.