National Library of Energy BETA

Sample records for fine coal particles

  1. Pelletization of fine coals

    SciTech Connect (OSTI)

    Sastry, K.V.S.

    1991-09-01

    The present research project attempts to provide a basis to determine the pelletizability of fine coals, to ascertain the role of additives and binders and to establish a basis for binder selection. Currently, there are no established techniques for determining the quality of coal pellets. Our research is intended to develop a series of tests on coal pellets to measure their storage characteristics, transportability, ease of gasification and rate of combustion. Information developed from this research should be valuable for making knowledgeable decisions for on-time plant design, occasional binder selection and frequent process control during the pelletization of coal fines. During the last quarter, we continued the batch pelletization studies on Upper Freeport coal. The results as presented in that last quarterly report (April 1991) indicated that the surface conditions on the coal particle influenced the pelletizing growth rates. For example, a fresh (run of mine) sample of coal will display different pelletizing growth kinetics than a weathered sample of the same coal. Since coal is a heterogeneous material, the oxidized product of coal is equally variable. We found it to be logistically difficult to consistently produce large quantities of artificially oxidized coal for experimental purposes and as such we have used a naturally weathered coal. We have plans to oxidize coals under controlled oxidizing conditions and be able to establish their pelletizing behavior. The next phase of experiments were directed to study the effect of surface modification, introduced during the coal cleaning steps, on pelletizing kinetics. Accordingly, we initiated studies with two additives commonly used during the flotation of coal: dextrin (coal depressant) and dodecane (coal collector).

  2. Enhanced control of fine particles following Title IV coal switching and NOx control

    SciTech Connect (OSTI)

    Durham, M.D.; Baldrey, K.E.; Bustard, C.J.; Martin, C.

    1997-12-31

    Electrostatic precipitators (ESPs) serve as the primary particle control devices for a majority of coal-fired power generating units in the United States. ESPs are used to collect particulate matter that range in size from less than one micrometer in diameter to several hundred micrometers. Many of the options that utilities will use to respond to Title IV of the 1990 Clean Air Act Amendments will result in changes to the ash that will be detrimental to the performance of the ESP causing increased emissions of fine particles and higher opacity. For example, a switch to low-sulfur coal significantly increases particle resistivity while low-NO{sub x} burners increase the carbon content of ashes. Both of these changes could result in derating of the boiler to comply with emissions standards. ADA has developed a chemical additive that is designed to improve the operation of ESI`s to bring these systems into compliance operation without the need for expensive capital modifications. The additives provide advantages over competing technologies in terms of low capital cost, easy to handle chemicals, and relatively non-toxic chemicals. In addition, the new additive is insensitive to ash chemistry which will allow the utility complete flexibility to select the most economical coal. Results from full-scale and pilot plant demonstrations are reported.

  3. Design, synthesis, and characterization of novel fine-particle, unsupported catalysts for coal liquefaction

    SciTech Connect (OSTI)

    Klein, M.T.

    1992-05-22

    An investigation aimed at devising a procedure for preparing alkyl-or aryl-capped iron sulfide particles continues. An initial attempt to prepare fine-particle, aryl-capped iron sulfides (S-31) involved the competitive reaction of thiophenol (PhSH) and sodium sulfide (Na{sub 2}S) with Fe(II). However, SEM examination of the particles formed by this procedure indicated that no size control had been attained. It was thought that the phenyl group of thiophenol was not bulky enough to prevent thiolate bridging and consequent particle size growth of the metal sulfide. So the bulkier thiol 1-adamantanethiol was synthesized and used in synthesis S-33 in the next attempt to prepare fine-particle, capped iron sulfides.

  4. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  5. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    SciTech Connect (OSTI)

    K. Osseo-Asare; X. Zeng

    2002-01-01

    The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

  6. Pelletization of fine coals. Final report

    SciTech Connect (OSTI)

    Sastry, K.V.S.

    1995-12-31

    Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

  7. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect (OSTI)

    B. K. Parekh; D. P. Patil

    2008-04-30

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake is subjected to pressure for a short time, the free water present is released from the filter cake. Laboratory studies have shown that depending on the coal type a filter cake containing about 15% moisture could be obtained using the two-stage filtration technique. It was also noted that applying intermittent breaks in vacuum force during cake formation, which disturbed the cake structure, helped in removing moisture from the filter cakes. In this project a novel approach of cleaning coal using column flotation was also developed. With this approach the feed capacity of the column is increased significantly, and the column was also able to recover coarser size coal which usually gets lost in the process. The outcome of the research benefits the coal industry, utility industry, and indirectly the general public. The benefits can be counted in terms of clean energy, cleaner environment, and lower cost power.

  8. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  9. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1988-01-01

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

  10. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  11. Aqueour biphase extraction for processing of fine coal

    SciTech Connect (OSTI)

    Osseo-Asare, K.

    1997-07-23

    Ever-stringent environmental constraints dictate that future coal cleaning technologies be compatible with micron-size particles. For super-clean coal production, the degree of liberation needed to separate coal from mineral matter, including pyrite, requires grinding to 10 mm or below. In addition, large amounts of fine coal are discharged to refuse ponds because current coal cleaning technology cannot adequately treat such finely divided materials. This research program seeks to develop an advanced coal cleaning technology uniquely suited to micron-size particles, i.e., aqueous biphase extraction. This technique relies on the ability of an aqueous system consisting of a water-soluble organic polymer and an inorganic metal salt to separate into two immiscible aqueous phases. Differences in the hydrophobic/hydrophilic properties of particulates can then be exploited to effect selective transfers to either the upper polymer-rich phase, or the lower salt-rich phase. An experimental program is proposed involving phase diagram determination, phase separation rate measurements, partition measurements, and washing experiments.

  12. Design, synthesis, and characterization of novel fine-particle, unsupported catalysts for coal liquefaction. Technical progress report, January 26, 1992--April 25, 1992

    SciTech Connect (OSTI)

    Klein, M.T.

    1992-05-22

    An investigation aimed at devising a procedure for preparing alkyl-or aryl-capped iron sulfide particles continues. An initial attempt to prepare fine-particle, aryl-capped iron sulfides (S-31) involved the competitive reaction of thiophenol (PhSH) and sodium sulfide (Na{sub 2}S) with Fe(II). However, SEM examination of the particles formed by this procedure indicated that no size control had been attained. It was thought that the phenyl group of thiophenol was not bulky enough to prevent thiolate bridging and consequent particle size growth of the metal sulfide. So the bulkier thiol 1-adamantanethiol was synthesized and used in synthesis S-33 in the next attempt to prepare fine-particle, capped iron sulfides.

  13. Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

    SciTech Connect (OSTI)

    Mohanty, M.K.; Samal, A.R.; Palit, A.

    2008-02-15

    One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.

  14. Modified approaches for high pressure filtration of fine clean coal

    SciTech Connect (OSTI)

    Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

    1995-12-31

    Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

  15. Hot Gas Filtration of Fine and Ultra fine Particles with Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic ...

  16. ULTRASONICALLY-ENHANCED DENSE-MEDIUM CYCLONING FOR FINE COAL AND COAL REFUSE IMPOUNDMENT MATERIALS

    SciTech Connect (OSTI)

    Dr. Mark S. Klima; Dr. Barbara J. Arnold

    2001-08-01

    The Pennsylvania State University, its project team (Typlex, Inc., DAGER, Inc., and PrepTech, Inc.), and advisory committee members have demonstrated the application of ultrasonic energy during dense-medium cyclining and subsequent recovery of fine coal and coal refuse impoundment materials. The results will help to extend the range of conventional dense-medium cyclining to sizes now typically cleaned in relatively inefficient water-only cyclone and spiral concentrators circuits. This technology also provides a potential approach to produce ultra-clean material as would be used for feedstocks for premium carbon products. This report describes Phase I of the project, which involved laboratory testing of dense-medium cyclining and subsequent medium recovery, with and without ultrasonic treatment, along with fundamental dispersion testing. Dense-medium cycloning was conducted with a 76.2-mm (3-in.) diameter cyclone under various conditions including magnetite grade, medium relative density, inlet pressure, cyclone geometry, and feed coal. Dense-medium recovery testing was carried out with a 305-mm (12-in.) diameter x 152-mm (6-in.) wide wet-drum magnetic separator using the cyclone clean coal and refuse products as the feed material. Fundamental testing of dispersion/reagglomeration phenomena was conducted with coal/clay mixtures. In almost all cases, the dense-medium cyclone was capable of achieving separations down to approximately 0.037 mm. Ultrasonic treatment had a slight effect on reducing the ash content of the clean coal. It was also found that ultrasonic treatment improved the purity of the magnetic fraction during wet-drum magnetic separation. The treatment was particularly beneficial for the cyclone overflow material. The fundamental testing indicated that agitation after ultrasonic treatment is necessary to disperse fine particles and to prevent agglomeration.

  17. ELECTROKINETIC DENSIFICATION OF COAL FINES IN WASTE PONDS

    SciTech Connect (OSTI)

    E. James Davis

    1999-12-18

    The objective of this research was to demonstrate that electrokinetics can be used to remove colloidal coal and mineral particles from coal-washing ponds and lakes without the addition of chemical additives such as salts and polymeric flocculants. The specific objectives were: Design and develop a scaleable electrophoresis apparatus to clarify suspensions of colloidal coal and clay particles; Demonstrate the separation process using polluted waste water from the coal-washing facilities at the coal-fired power plants in Centralia, WA; Develop a mathematical model of the process to predict the rate of clarification and the suspension electrical properties needed for scale up.

  18. Fine Anthracite Coal Washing Using Spirals

    SciTech Connect (OSTI)

    R.P. Killmeyer; P.H. Zandhuis; M.V. Ciocco; W. Weldon; T. West; D. Petrunak

    2001-05-31

    The spiral performed well in cleaning the coarse 8 x 16 mesh size fraction, as demonstrated by the Ep ranging from 0.091 to 0.177. This is in line with typical spiral performance. In addition, the presence of the coarser size fraction did not significantly affect spiral performance on the typical 16 x 100 mesh fraction, in which the Ep ranged from 0.144 to 0.250. Changes in solids concentration and flow rate did not show a clear correlation with spiral performance. However, for difficult-to-clean coals with high near-gravity material, such as this anthracite, a single-stage spiral cleaning such a wide size fraction may not be able to achieve the clean coal ash and yield specifications required. In the first place, while the performance of the spiral on the coarse 8 x 16 mesh fraction is good with regard to Ep, the cutpoints (SG50s) are high (1.87 to 1.92), which may result in a clean coal with a higher-than-desired ash content. And second, the combination of the spiral's higher overall cutpoint (1.80) with the high near-gravity anthracite results in significant misplaced material that increases the clean coal ash error. In a case such as this, one solution may be to reclean the clean coal and middlings from the first-stage spiral in a second stage spiral.

  19. Hydrophobic Dewatering of Fine Coal. Topical report, March 1, 1995-March 31, 1997

    SciTech Connect (OSTI)

    Yoon, R.; Sohn, S.; Luttrell, J.; Phillips, D.

    1997-12-31

    Many advanced fine coal cleaning technologies have been developed in recent years under the auspices of the U.S. Department of Energy. However, they are not as widely deployed in industry as originally anticipated. An important reason for this problem is that the cleaned coal product is difficult to dewater because of the large surface area associated with fine particles. Typically, mechanical dewatering, such as vacuum filtration and centrifugation, can reduce the moisture to 20-35% level, while thermal drying is costly. To address this important industrial problem, Virginia Tech has developed a novel dewatering process, in which water is displaced from the surface of fine particulate materials by liquid butane. Since the process is driven by the hydrophobic interaction between coal and liquid butane, it was referred to as hydrophobic dewatering (HD). A fine coal sample with 21.4 pm median size was subjected to a series of bench-scale HD tests. It was a mid-vol bituminous coal obtained from the Microcel flotation columns operating at the Middle Fork coal preparation plant, Virginia. All of the test results showed that the HD process can reduce the moisture to substantially less than 10%. The process is sensitive to the amount of liquid butane used in the process relative to the solids concentration in the feed stream. Neither the intensity nor the time of agitation is critical for the process. Also, the process does not require long time for phase separation. Under optimal operating conditions, the moisture of the fine coal can be reduced to 1% by weight of coal.

  20. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the second quarter, January 19--March 31, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-05-01

    This research project is for the development of a technically and economically feasible process for drying and stabilizing of fine particles of high-moisture subbituminous coal. Research activities were initiated with efforts concentrating on characterization of the two feed coals: Eagle Butte coal from AMAX Coal Company's mine located in the Powder River Basin of Wyoming; and coal from Usibelli Coal Mine, Inc.'s mine located in central Alaska. Both of the feed coals are high-moisture subbituminous coals with ''as received'' moisture contents of 29% and 22% for the Eagle Butte and Usibelli coals, respectively. However, physical analyses of the crushed coal samples (--28-mesh particle size range) indicate many differences. The minimum fluidization velocity (MFV) of the feed coals were experimentally determined. The MFV for --28-mesh Eagle Butte coal is approximately 1 ft/min, and the MFV for --28-mesh Usibelli coal is approximately 3 ft/min. 2 refs., 16 figs., 3 tabs.

  1. An efficient process for recovery of fine coal from tailings of coal washing plants

    SciTech Connect (OSTI)

    Cicek, T.; Cocen, I.; Engin, V.T.; Cengizler, H.

    2008-07-01

    Gravity concentration of hard lignites using conventional jigs and heavy media separation equipment is prone to produce coal-rich fine tailings. This study aims to establish a fine coal recovery process of very high efficiency at reasonable capital investment and operational costs. The technical feasibility to upgrade the properties of the predeslimed fine refuse of a lignite washing plant with 35.9% ash content was investigated by employing gravity separation methods. The laboratory tests carried out with the combination of shaking table and Mozley multi-gravity separator (MGS) revealed that the clean coal with 18% ash content on dry basis could be obtained with 58.9% clean coal recovery by the shaking table stage and 4.1% clean coal recovery by MGS stage, totaling to the sum of 63.0% clean coal recovery from a predeslimed feed. The combustible recovery and the organic efficiency of the shaking table + MGS combination were 79.5% and 95.5%, respectively. Based on the results of the study, a flow sheet of a high-efficiency fine coal recovery process was proposed, which is also applicable to the coal refuse pond slurry of a lignite washing plant.

  2. Fine coal cleaning via the micro-mag process

    DOE Patents [OSTI]

    Klima, Mark S.; Maronde, Carl P.; Killmeyer, Richard P.

    1991-01-01

    A method of cleaning particulate coal which is fed with a dense medium slurry as an inlet feed to a cyclone separator. The coal particle size distribution is in the range of from about 37 microns to about 600 microns. The dense medium comprises water and ferromagnetic particles that have a relative density in the range of from about 4.0 to about 7.0. The ferromagnetic particles of the dense medium have particle sizes of less than about 15 microns and at least a majority of the particle sizes are less than about 5 microns. In the cyclone, the particulate coal and dense-medium slurry is separated into a low gravity product stream and a high gravity produce stream wherein the differential in relative density between the two streams is not greater than about 0.2. The low gravity and high gravity streams are treated to recover the ferromagnetic particles therefrom.

  3. Maintenance is the cheapest way to improve fine coal dewatering

    SciTech Connect (OSTI)

    Burger, J.

    1986-01-01

    There are a great many things that a preparation plant operator can do right now to increase fine coal dewatering effectiveness and maintenance is one of them, says Donald A. Dahlstrom, at the University of Utah. Dewatering of fine coal is increasingly important, because electricity generation, the largest coal consumer, is so strongly affected by the moisture content. Every pound of water put into a boiler raises costs about 2 1/2 cents. The heat it takes to turn water to steam and get it out the stack is heat that could have been used to generate power. In addition, there is the cost of shipping the water. You can add the freight costs to that. In contrast it costs about 1/2-cent/lb to remove the water at the preparation plant.

  4. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would suffer from low throughput capacities and high maintenance requirements. In general, surface area-based separators (e.g., shaking tables, magnetic drum separator, electrodynamic separator, etc.) have lower throughput capacities than volume-based separators (e.g., flotation cell, dense-medium bath, cyclones, etc.) by an order of magnitude. Furthermore, the electrodes of the laboratory unit need to be cleaned frequently, creating a high maintenance requirement if it is scaled-up to a commercial unit. The bench-scale continuous TES unit developed at NETL, on the other hand, separates positively and negatively charged particles by splitting the gaseous stream containing these particles in an electric field by means of a flow splitter, so that the oppositely charged particles can be directed into different compartments. This device is fundamentally different from the laboratory unit in that the former is a surface area-based separator, while the latter is a volume-based separator. The bench-scale unit is referred to as an entrained flow separator by the in-house researchers at NETL. Thus, the entrained flow TES unit is a significant improvement over the laboratory unit with regard to throughput capacity. In the present work, the entrained flow separator concept will be utilized for developing a proof-of concept (POC) separator that can be scaled-up to commercial size units. To accomplish this, it is necessary to develop a bench-scale separator that can achieve high Btu recoveries while maintaining the high degree of separation efficiencies. It is the objective of the present investigation to develop an efficient separator by studying the mechanisms of triboelectrification and investigating better ways of separating the charged particles. An important criterion for developing efficient separators is that they not only provide high separation efficiencies but also have high throughput capacities, which are essential ingredients for successful commercialization.

  5. DEVELOPMENT OF A NOVEL FINE COAL CLEANING SYSTEM

    SciTech Connect (OSTI)

    Manoj K. Mohanty

    2005-06-01

    The goal of the proposed project was to develop a novel fine coal separator having the ability to clean 1 mm x 0 size coal in a single processing unit. The novel fine coal separator, named as EG(Enhanced Gravity) Float Cell, utilizes a centrifugal field to clean 1 mm x 250 micron size coal, whereas a flotation environment to clean minus 250 micron coal size fraction. Unlike a conventional enhanced gravity concentrator, which rotates to produce a centrifugal field requiring more energy, the EG Float Cell is fed with a tangential feed slurry to generate an enhanced gravity field without any rotating part. A prototype EG Float Cell unit having a maximum diameter of 60 cm (24 inch) was fabricated during the first-half of the project period followed by a series of exploratory tests to make suitable design modification. Test data indicated that there was a significant concentration of coarse heavy materials in the coarse tailings discharge of the EG Float Cell. The increase in weight (%) of 1 mm x 250 micron (16 x 60 mesh) size fraction from 48.9% in the feed to 72.2% in the coarse tailings discharge and the corresponding increase in the ash content from 56.9% to 87.0% is indicative of the effectiveness of the enhanced gravity section of the EG Float Cell. However, the performance of the flotation section needs to be improved. Some of the possible design modifications may include more effective air sparging system for the flotation section to produce finer bubbles and a better wash water distributor.

  6. Apparatus for centrifugal separation of coal particles

    DOE Patents [OSTI]

    Dickie, William (New Eagle, PA); Cavallaro, Joseph A. (Mt. Keesport, PA); Killmeyer, Richard P. (Pleasant Hills, PA)

    1991-01-01

    A gravimetric cell for centrifugal separation of fine coal by density has a cylindrical body and a butterfly valve or other apparatus for selectively sealing the body radially across the approximate center of the cylinder. A removable top is provided which seals the cylinder in the centrifuge and in unvented areas.

  7. POC-scale testing of an advanced fine coal dewatering equipment/technique

    SciTech Connect (OSTI)

    Groppo, J.G.; Parekh, B.K.; Rawls, P.

    1995-11-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

  8. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1991-04-23

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up millions of tons of coal fines in refuse piles and ponds. It is anticipated that the new centrifuge can become an important ancillary to the advanced deep cleaning processes for coal. Because of these convictions, CTC has been engaged in a pioneering research effort into the new art of drying fine clean coal in high gravity, high production, batch type of centrifuge, since 1981. This work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. It promises to provide needed fine coal drying capability at somewhat lower capital costs and at substantially lower operating costs than competitive systems. It also promises to do so with no detrimental effects on either the coal quality or the environment. The primary objective of this project is to prove the concept of a high gravity batch centrifuge for drying coal fines in a commercial coal processing plant environment. The proof of concept tests also include testing with a variety of coals from different regions. A further objective is to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology. 2 figs., 3 tabs.

  9. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  10. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1990-07-24

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up the millions of tons of coal fines in refuse piles and ponds. It is anticipated that the new centrifuge can become an important ancillary to the advanced deep cleaning processes for coal. Because of these convictions, CTC has been engaged in a pioneering research effort into the new art of drying fine clean coal in high gravity, high production, batch type centrifuges, since 1981. This work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. It promises to provide needed fine coal drying capability at somewhat lower capital costs and at substantially lower operating costs than competitive systems. It also promises to do so with no detrimental effects on either the coal quality or the evironment. The primary objective of this project is to prove the concept in a commercial coal processing plant environment. The proof of concept tests will also include testing with a variety of coals from different regions. A further objective will be to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology.

  11. POC-Scale Testing of an Advanced Fine Coal Dewatering Equipment/Technique

    SciTech Connect (OSTI)

    B. K. Karekh; D. Tao; J. G. Groppo

    1998-08-28

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 mm) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy's program to show that ultra-clean coal could be effectively dewatered to 20% or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 45 months beginning September 30, 1994. This report discusses technical progress made during the quarter from January 1 ? March 31, 1998.

  12. DOE Receives First Repayment from Successful DryFining™ Clean Coal Power

    Office of Environmental Management (EM)

    Initiative Project | Department of Energy First Repayment from Successful DryFining™ Clean Coal Power Initiative Project DOE Receives First Repayment from Successful DryFining™ Clean Coal Power Initiative Project July 6, 2011 - 1:00pm Addthis Washington, DC - The success of a U.S. Department of Energy (DOE) Clean Coal Power Initiative (CCPI) project has led to a repayment of $580,000 to U.S. taxpayers, with much more - potentially exceeding $13 million - possible in the future. Great River

  13. POC-SCALE TESTING OF OIL AGGLOMERATION TECHNIQUES AND EQUIPMENT FOR FINE COAL PROCESSING

    SciTech Connect (OSTI)

    1998-01-01

    This report covers the technical progress achieved from October 1, 1997 to December 31, 1997 on the POC-Scale Testing of Oil Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental test procedures and the results related to the processing of coal fines originating from process streams generated at the Shoal Creek Mine preparation plant, owned and operated by the Drummond Company Inc. of Alabama, are described. Two samples of coal fines, namely Cyclone Overflow and Pond Fines were investigated. The batch test results showed that by applying the Aglofloat technology a significant ash removal might be achieved at a very high combustible matter recovery: · for the Cyclone Overflow sample the ash reduction was in the range 50 to 55% at combustible matter recovery about 98% · for the Pond Fines sample the ash reduction was up to 48% at combustible matter recovery up to 85%. Additional tests were carried out with the Alberta origin Luscar Mine coal, which will be used for the parametric studies of agglomeration equipment at the 250 kg/h pilot plant. The Luscar coal is very similar to the Mary Lee Coal Group (processed at Shoal Creek Mine preparation plant) in terms of rank and chemical composition.

  14. FINE PARTICAL AND TOXIC METAL EMISSIONS FROM THE COMBUSTION OF SEWAGE SLUDGE/COAL MIXTURES: A SYSTEMATIC ASSESSMENT

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Wayne S. Seames; Art Fernandez

    2003-09-21

    This research project focuses on pollutants from the combustion of mixtures of dried municipal sewage sludge (MSS) and pulverized coal. The objective was to determine potential tradeoffs between CO{sub 2} mitigation through using a CO{sub 2} neutral fuel, such as municipal sewage sludge, and the emergence of other potential problems such as the emission of toxic fly ash particles. The work led to new insight into mechanisms governing the partitioning of major and trace metals from the combustion of sewage sludge, and mixtures of coal and sewage sludge. The research also showed that the co-combustion of coal and sewage sludge emitted fine particulate matter that might potentially cause greater lung injury than that from the combustion of either coal alone or municipal sewage sludge alone. The reason appeared to be that the toxicity measured required the presence of large amounts of both zinc and sulfur in particles that were inhaled. MSS provided the zinc while coal provided the sulfur. Additional research showed that the toxic effects could most likely be engineered out of the process, through the introduction of kaolinite sorbent downstream of the combustion zone, or removing the sulfur from the fuel. These results are consequences of applying ''Health Effects Engineering'' to this issue. Health Effects Engineering is a new discipline arising out of this work, and is derived from using a collaboration of combustion engineers and toxicologists to mitigate the potentially bad health effects from combustion of this biomass fuel.

  15. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1990-10-24

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up the millions of tons of coal fines in refuse piles and ponds. Work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. The primary objective of this project is to prove the concept in a commercial coal processing plant environment. The proof of concept tests will include testing with a variety of coals from different regions. A further objective will be to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology. To supply some perspective on the ability of the new centrifuges to successfully dry a variety of coals from various coal fields, it was decided that coals ranging from very fine to course size consists and with both low and high inherent moistures would be tested. Coals tested include: Pittsburgh no. 8 seam (Pennsylvania), Pittsburgh no. 8 seam (West Virginia), and Blue Creek Seam (Alabama). 6 figs.

  16. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Barbour, F.A.; Turner, T.F.; Kang, T.W.; Berggren, M.H.; Hogsett, R.F.; Jha, M.C.

    1990-02-01

    The objective of this research project was to demonstrate a technically feasible and economically viable process for drying and stabilizing high-moisture subbituminous coal. Controlled thermal drying of coal fines was achieved using the inclined fluidized-bed drying and stabilization process developed by the Western Research Institute. The project scope of work required completion of five tasks: (1) project planning, (2) characterization of two feed coals, (3) bench-scale inclined fluidized-bed drying studies, (4) product characterization and testing, and (5) technical and economic evaluation of the process. High moisture subbituminous coals from AMAX Eagle Butte mine located in the Powder River Basin of Wyoming and from Usibelli Coal Mine, Inc. in Healy, Alaska were tested in a 10-lb/hr bench-scale inclined fluidized-bed. Experimental results show that the dried coal contains less than 1.5% moisture and has a heating value over 11,500 Btu/lb. The coal fines entrainment can be kept below 15 wt % of the feed. The equilibrium moisture of dried coal was less than 50% of feed coal equilibrium moisture. 7 refs., 60 figs., 47 tabs.

  17. Multi-gravity separator: an alternate gravity concentrator to process coal fines

    SciTech Connect (OSTI)

    Majumder, A.K.; Bhoi, K.S.; Barnwal, J.P.

    2007-08-15

    The multi-gravity separator (MGS) is a novel piece of equipment for the separation of fine and ultra-fine minerals. However, the published literature does not demonstrate its use in the separation of coal fines. Therefore, an attempt was made to study the effects of different process variables on the performance of an MGS for the beneficiation of coal fines. The results obtained from this study revealed that among the parameters studied, drum rotation and feed solids concentration play dominating roles in controlling the yield and ash content of the clean coal. Mathematical modeling equations that correlate the variables studied and the yield and ash contents of the clean coal were developed to predict the performance of an MGS under different operating and design conditions. The entire exercise revealed that the MGS could produce a clean coal with an ash content of 14.67% and a yield of 71.23% from a feed coal having an ash content of 24.61 %.

  18. The effect of oxygen-to-fuel stoichiometry on coal ash fine-fragmentation mode formation mechanisms.

    SciTech Connect (OSTI)

    Fix, G.; Seames, W. S.; Mann, M. D.; Benson, S. A.; Miller, D. J.

    2011-04-01

    Ash particles smaller than 2.5 {micro}m in diameter generated during pulverized coal combustion are difficult to capture and may pose greater harm to the environment and human health than the discharge of larger particles. Recent research efforts on coal ash formation have revealed a middle fine-fragment mode centered around 2 {micro}m. Formation of this middle or fine-fragment mode (FFM) is less well understood compared to larger coarse and smaller ultrafine ash. This study is part of an overall effort aimed at determining the key factors that impact the formation of FFM. This work examined the effects of oxygen-to-fuel stoichiometry (OFS). Pulverized Illinois No.6 bituminous coal was combusted and the ash generated was size segregated in a Dekati low pressure inertial impactor. The mass of each fraction was measured and the ash was analyzed using scanning electron microscopy (SEM) and X-ray microanalysis. The FFM ash types were classified based on the SEM images to evaluate the significant fine-fragment ash formation mechanisms and determine any possible link between stoichiometry and formation mechanism. From the particle size distributions (PSDs), the coarse mode appears unaffected by the change in OFS, however, the OFS 1.05 lowered the fraction of ultrafine ash in relation to the higher OFS settings, and appears to increase the portion of the FFM. An intermediate minimum was found in the FFM at 1.3 {micro}m for the 1.20 and 1.35 OFS tests but was not observed in the 1.05 OFS. SEM analysis also suggests that OFS may contribute to changing formation mechanisms.

  19. Production and gasification tests of coal fines/coal tar extrudate. Final report June 1982-December 1983

    SciTech Connect (OSTI)

    Furman, A.; Rib, D.; Smith, D.; Waslo, D.

    1984-01-01

    Gasification is a fuels conversion technology that permits the production of clean synthetic gas from coal and other carbonaceous fuels. Of the various gasifier types, however, the fixed bed is the only system currently being offered on a commercial basis. While this reactor type offers proven performance in terms of reliability and thermal efficiency, it requires a sized feedstock. This means that up to 30% of the incoming run-of-mine coal could be rejected as fines. Direct extrusion of this - 1/8-inch coal fines fraction with a tar binder offers a potentially attractive solution to this problem by consolidating the fines and, at the same time, providing a feed mechanism to the pressurized reactor. Work is described on a recently completed extrudate evaluation program conducted at the General Electric Research and Development Center in Schenectady under GRI and NYSERDA sponsorship. A 6-inch, single screw extruder was used to produce 88 tons of Illinois No. 6 coal extrudate with tar binder, which was then successfully gasified in General Electric's 1-ton/hr, Process Evaluation Facility (PEF) scale, fixed-bed reactor. Performance data on the extrusion process and on gasification testing are presented. The test results indicate that the extrudate makes a satisfactory gasifier feedstock in terms of both thermal and mechanical performance.

  20. Fine and ultrafine particles generated during fluidized bed combustion of different solid fuels

    SciTech Connect (OSTI)

    Urciuolo, M.; Barone, A.; D'Alessio, A.; Chirone, R.

    2008-12-15

    The paper reports an experimental study carried out with a 110-mm ID fluidized bed combustor focused on the characterization of particulates formation/emission during combustion of coal and non-fossil solid fuels. Fuels included: a bituminous coal, a commercial predried and granulated sludge (GS), a refuse-derived fuel (RDF), and a biomass waste (pine seed shells). Stationary combustion experiments were carried out analyzing the fate of fuel ashes. Fly ashes collected at the combustor exhaust were characterized both in terms of particle size distribution and chemical composition, with respect to both trace and major elements. Tapping-Mode Atomic Force Microscopy (TM-AFM) technique and high-efficiency cyclone-type collector devices were used to characterize the size and morphology of the nanometric-and micronic-size fractions of fly ash emitted at the exhaust respectively. Results showed that during the combustion process: I) the size of the nanometric fraction ranges between 2 and 65 nm; ii) depending on the fuel tested, combustion-assisted attrition or the production of the primary ash particles originally present in the fuel particles, are responsible of fine particle generation. The amount in the fly ash of inorganic compounds is larger for the waste-derived fuels, reflecting the large inherent content of these compounds in the parent fuels.

  1. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  2. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F.; Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C.; Hu, W.; Zou, Y.; Chen, W.; Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R.

    1992-03-01

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  3. Process for making ultra-fine ceramic particles

    DOE Patents [OSTI]

    Stangle, Gregory C. (Alfred, NY); Venkatachari, Koththavasal R. (Hornell, NY); Ostrander, Steven P. (Scotia, NY); Schulze, Walter A. (Alfred Station, NY)

    1995-01-01

    A process for producing ultra-fine ceramic particles in which droplets are formed from a ceramic precursor mixture containing a metal cation, a nitrogen-containing fuel, a solvent, and an anion capable of participating in an anionic oxidation-reduction reaction with the nitrogen containing fuel. The nitrogen-containing fuel contains at least three nitrogen atoms, at least one oxygen atom, and at least one carbon atom. The ceramic precursor mixture is dried to remove at least 85 weight percent of the solvent, and the dried mixture is then ignited to form a combusted powder.

  4. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Kang, T.W.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.; AMAX Research and Development Center, Golden, CO )

    1989-10-01

    The main objective of this research is to develop a thermal process for drying fine coal that (1) reduces explosion potential, (2) uses a fluidized bed with minimum elutriation, (3) produces a stable dry coal by preventing moisture reabsorption and autogeneous heating, (4) reduces fugitive dust emissions, and (5) is technically and economically feasible. The project scope of work requires completion of five tasks: (1) project planning, (2) characterization of the two feed coals, (3) bench-scale IFB drying studies, (4) product characterization and testing, and (5) technical and economic process evaluation. The project technical achievements are primarily related to understanding of the behavior of the two coals in the IFB reactor. Solids residence time and solids entrainment can be correlated using the Reynolds number. Gas produced from the coal during drying and the product composition can be correlated to the average dryer temperature. A dry product with minimal proximate moisture and substantially increased heating value can be produced from either of these coals under a wide variety of fluidizing gas-to-solids ratios and IFB operating temperatures. Product characterization indicates that moisture reabsorption can be significantly reduced and that fugitive dust contents can be almost completely reduced. 4 refs., 19 figs., 24 tabs.

  5. Synergistic Utilization of Coal Fines and Municipal Solid Waste in Coal-Fired Boilers. Phase I Final Report

    SciTech Connect (OSTI)

    V. Zamansky; P. Maly; M. Klosky

    1998-06-12

    A feasibility study was performed on a novel concept: to synergistically utilize a blend of waste coal fines with so-called E-fuel for cofiring and reburning in utility and industrial boilers. The E-fuel is produced from MSW by the patented EnerTech's slurry carbonization process. The slurry carbonization technology economically converts MSW to a uniform, low-ash, low-sulfur, and essentially chlorine-free fuel with energy content of about 14,800 Btu/lb.

  6. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the third quarter, April 1, 1989-June 30, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Barbour, F.A.; Turner, T.F.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-07-01

    This research project is for the development of a technical and economical feasible process for drying and stability fine particles of high-moisture subbituminous coal. Research conducted in this quarter focused upon thermogravimetric analysis (TGA) of both feed coals; continuation of the bench-scale IFB drying experiments; and initiation of the characterization of the products from the bench-scale drying experiments to determine their moisture reabsorption, dustiness, and spontaneous ignition properties. Thirty 4-hr and six 12-hr bench-scale IFB drying tests were conducted this quarter making a total of forty-one 4-hr (19 using Eagle Butte feed coal and 22 using Usibelli feed coal) and six 12-hr (3 using each feed coal) tests conducted thus far. IFB reactor slopes of 3, 6, 9, 12, and 15 degrees were investigated for each feed coal. During the tests using Eagle Butte coal, gas-to-solids ratios ranging from approximately 0.7 to 9.7 lb/lb (kg/kg) and average IFB reactor temperatures ranging from approximately 370 to 700/degree/F (188 to 371/degree/C) were tested. 5 refs., 41 figs., 7 tabs.

  7. Coal Particle Flow Patterns for O2 Enriched, Low NOx Burners

    SciTech Connect (OSTI)

    Jennifer Sinclair Curtis

    2005-08-01

    This project involved a systematic investigation examining the effect of near-flame burner aerodynamics on standoff distance and stability of turbulent diffusion flames and the resultant NO{sub x} emissions from actual pulverized coal diffusion flames. Specifically, the scope of the project was to understand how changes in near-flame aerodynamics and transport air oxygen partial pressure can influence flame attachment and coal ignition, two properties essential to proper operation of low NO{sub x} burners. Results from this investigation utilized a new 2M tall, 0.5m in diameter combustor designed to evaluate near-flame combustion aerodynamics in terms of transport air oxygen partial pressure (Po{sub 2}), coal fines content, primary fuel and secondary air velocities, and furnace wall temperature furnish insight into fundamental processes that occur during combustion of pulverized coal in practical systems. Complementary cold flow studies were conducted in a geometrically similar chamber to analyze the detailed motion of the gas and particles using laser Doppler velocimetry. This final technical report summarizes the key findings from our investigation into coal particle flow patterns in burners. Specifically, we focused on the effects of oxygen enrichment, the effect of fines, and the effect of the nozzle velocity ratio on the resulting flow patterns. In the cold flow studies, detailed measurements using laser Doppler velocimetry (LDV) were made to determine the details of the flow. In the hot flow studies, observations of flame stability and measurements of NO{sub x} were made to determine the effects of the flow patterns on burner operation.

  8. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.-H. Yoon; G.H. Luttrell; B. Luvsansambuu; A.D. Walters

    2000-10-01

    Work continued during the past quarter to improve the performance of the POC-scale unit. For the charging system, a more robust ''turbocharger'' has been fabricated and installed. All of the internal components of the charger have been constructed from the same material (i.e., Plexiglas) to prevent particles from contacting surfaces with different work functions. For the electrode system, a new set of vinyl-coated electrodes have been constructed and tested. The coated electrodes (i) allow higher field strengths to be tested without of risk of arcing and (ii) minimize the likelihood of charge reversal caused by particles colliding with the conducting surfaces of the uncoated electrodes. Tests are underway to evaluate these modifications. Several different coal samples were collected for testing during this reporting period. These samples included (i) a ''reject'' material that was collected from the pyrite trap of a pulverizer at a coal-fired power plant, (ii) an ''intermediate'' product that was selectively withdrawn from the grinding chamber of a pulverizer at a power plant, and (iii) a run-of-mine feed coal from an operating coal preparation plant. Tests were conducted with these samples to investigate the effects of several key parameters (e.g., particle size, charger type, sample history, electrode coatings, etc.) on the performance of the bench-scale separator.

  9. Process and apparatus for separating fine particles by microbubble flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1991-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine particles, especially coal, so as to produce a high purity and large recovery efficiently. This is accomplished through the use of a high aspect ratio flotation column, microbubbles, and a countercurrent use of wash water to gently wash the froth. Also, disclosed are unique processes and apparatus for generating microbubbles for flotation in a high efficient and inexpensive manner using either a porous tube or an in-line static generator. 23 figures.

  10. Process and apparatus for separating fine particles by microbubble flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, Roe-Hoan (Blacksburg, VA); Adel, Gregory T. (Blacksburg, VA); Luttrell, Gerald H. (Blacksburg, VA)

    1991-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine particles, especially coal, so as to produce a high purity and large recovery efficiently. This is accomplished through the use of a high aspect ratio flotation column, microbubbles, and a countercurrent use of wash water to gently wash the froth. Also, disclosed are unique processes and apparatus for generating microbubbles for flotation in a high efficient and inexpensive manner using either a porous tube or an in-line static generator.

  11. OPTIMIZATION OF COAL PARTICLE FLOW PATTERNS IN LOW NOX BURNERS

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Gregory E. Ogden; Jennifer Sinclair; Caner Yurteri

    2001-08-20

    The proposed research is directed at evaluating the effect of flame aerodynamics on NO{sub x} emissions from coal fired burners in a systematic manner. This fundamental research includes both experimental and modeling efforts being performed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NO{sub x} burners to the kinetic emissions limit (below 0.2 lb./MMBTU). Experimental studies include both cold and hot flow evaluations of the following parameters: flame holder geometry, secondary air swirl, primary and secondary inlet air velocity, coal concentration in the primary air and coal particle size distribution. Hot flow experiments will also evaluate the effect of wall temperature on burner performance. Cold flow studies will be conducted with surrogate particles as well as pulverized coal. The cold flow furnace will be similar in size and geometry to the hot-flow furnace but will be designed to use a laser Doppler velocimeter/phase Doppler particle size analyzer. The results of these studies will be used to predict particle trajectories in the hot-flow furnace as well as to estimate the effect of flame holder geometry on furnace flow field. The hot-flow experiments will be conducted in a novel near-flame down-flow pulverized coal furnace. The furnace will be equipped with externally heated walls. Both reactors will be sized to minimize wall effects on particle flow fields. The cold-flow results will be compared with Fluent computation fluid dynamics model predictions and correlated with the hot-flow results with the overall goal of providing insight for novel low NO{sub x} burner geometry's.

  12. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  13. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    SciTech Connect (OSTI)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was found that the ground pellets could be used as an effective NOx control agent for pulverized-coal-fired systems. NOx emissions reductions up to 63% were recorded, when using AFP as a NOx control agent. In addition to performance benefits, economic analyses showed the good economic benefits of AFP fuel. Using equipment manufacturer inputs, and reasonable values for biomass, biosolids and coal fines costs, it was determined that an AFP plant would have good profitability. For cases where biosolids contents were in the range of 50%, the after tax Internal Rates of Return were in the range of 40% to 50%. These are very attractive returns. Besides the baseline analysis for the various AFP formulations tested at pilot scale, sensitivity analysis showed the impact of important parameters on return. From results, it was clear that returns are excellent for a range of parameters that could be expected in practice. Importantly, these good returns are achieved even without incentives related to the emissions control benefits of biomass.

  14. Production of a pellet fuel from Illinois coal fines. Technical report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.

    1995-12-31

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. For this effort, we will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. Previously it has been decided that corn starch would be used as binder and a roller-and-die mill would be used for pellet manufacture. A quality starch binder has been identified and tested. To potentially lower binder costs, a starch that costs about 50% of the high quality starch was tested. Results indicate that the lower cost starch will not lower binder cost because more is required to produce a comparable quality pellet. Also, a petroleum in water emulsion was evaluated as a potential binder. The compound seemed to have adhesive properties but was found to be a poor binder. Arrangements have been made to collect a waste slurry from the mine previously described.

  15. Study of deactivation and regeneration of catalysts used in the LC-fining of solvent refined coal

    SciTech Connect (OSTI)

    Curtis, C.W. (Auburn Univ., AL); Guin, J.A.; Nalitham, R.; mohsin, A.; Tarrer, A.R.; Potts, J.D.; Hastings, K.E.

    1981-03-29

    Batch experiments as well as results from LC-Fining catalytic upgrading of coal extracts indicate deactivation of the Shell 324 Ni/Mo catalyst in the presence of solvent refined coal (SRC). At increased levels of SRC loading, deactivation increases. The chief cause of catalyst deactivation appears to be coking. The Shell 324 catalyst can be substantially regenerated after the upgrading reaction by medium temperature ashing followed by presulfiding.

  16. Improvement of storage, handling and transportability of fine coal. Quarterly technical progress report No. 3, July 1, 1994--September 30, 1994

    SciTech Connect (OSTI)

    1996-08-16

    The Mulled Coal process was developed as a means of overcoming the adverse handling characteristics of wet fine coal without thermal drying. The process involves the addition of a low cost, harmless reagent to wet fine coal using off-the-shelf mixing equipment. The objectives of this project are to demonstrate that: The Mulled Coal process, which has been proven to work on a wide range of wet fine coals at bench scale, will work equally well on a continuous basis, producing consistent quality at a convincing rate of production in a commercial coal preparation plant. The wet product from a fine coal cleaning circuit can be converted to a solid fuel form for ease of handling and cost savings in storage and rail car transportation. A wet fine coal product thus converted to a solid fuel form, can be stored, shipped, and burned with conventional fuel handling, transportation, and combustion systems. During this third quarter of the contract period, activities were underway under Tasks 2 and 3. Sufficient characterization of the feedstock coal options at the Chetopa Plant was conducted and mulling characteristics determined to enable a decision to be made regarding the feedstock selection. It was decided that the froth concentrate will be the feedstock wet fine coal used for the project. On that basis, activities in the areas of design and procurement were initiated.

  17. Engineering development of advanced physical fine coal cleaning for premium fuel applications: Subtask 3.3 - dewatering studies

    SciTech Connect (OSTI)

    Yoon, R. H.; Phillips, D. I.; Sohn, S. M.; Luttrell, G. H.

    1996-10-01

    If successful, the novel Hydrophobic Dewatering (HD) process being developed in this project will be capable of efficiently removing moisture from fine coal without the expense and other related drawbacks associated with mechanical dewatering or thermal drying. In the HD process, a hydrophobic substance is added to a coal-water slurry to displace water from the surface of coal, while the spent hydrophobic substance is recovered for recycling. For this process to have commercialization potential, the amount of butane lost during the process must be small. Earlier testing revealed the ability of the hydrophobic dewatering process to reduce the moisture content of fine coal to a very low amount as well as the determination of potential butane losses by the adsorption of butane onto the coal surface. Work performed in this quarter showed that the state of oxidation affects the amount of butane adsorbed onto the surface of the coal and also affects the final moisture content. the remaining work will involve a preliminary flowsheet of a continuous bench-scale unit and a review of the economics of the system. 1 tab.

  18. Improvement of storage, handling, and transportability of fine coal. Quarterly technical progress report No. 5, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    1996-08-21

    The Mulled Coal process was developed as a means of overcoming the adverse handling characteristics of wet fine coal without thermal drying. The process involves the addition of a low cost, harmless reagent to wet fine coal using off-the-shelf mixing equipment. Based on laboratory- and bench-scale testing, Mulled Coal can be stored, shipped, and burned without causing any of the plugging, pasting, carryback and freezing problems normally associated with wet coal. The objectives of this project are to demonstrate that: the Mulled Coal process, which has been proven to work on a wide range of wet fine coals at bench scale, will work equally well on a continuous basis, producing consistent quality at a convincing rate of production in a commercial coal preparation plant; the wet product from a fine coal cleaning circuit can be converted to a solid fuel form for ease of handling and cost savings in storage and rail car transportation; and a wet fine coal product thus converted to a solid fuel form, can be stored, shipped, and burned with conventional fuel handling, transportation, and combustion systems. During this reporting period, virtually all of the technical activities and progress was made in the areas of circuit installation and startup operations. Work in these activity areas are described.

  19. OPTIMIZATION OF COAL PARTICLE FLOW PATTERNS IN LOW NOX BURNERS

    SciTech Connect (OSTI)

    Jost O.L. Wendt; Gregory E. Ogden; Jennifer Sinclair; Stephanus Budilarto

    2001-09-04

    It is well understood that the stability of axial diffusion flames is dependent on the mixing behavior of the fuel and combustion air streams. Combustion aerodynamic texts typically describe flame stability and transitions from laminar diffusion flames to fully developed turbulent flames as a function of increasing jet velocity. Turbulent diffusion flame stability is greatly influenced by recirculation eddies that transport hot combustion gases back to the burner nozzle. This recirculation enhances mixing and heats the incoming gas streams. Models describing these recirculation eddies utilize conservation of momentum and mass assumptions. Increasing the mass flow rate of either fuel or combustion air increases both the jet velocity and momentum for a fixed burner configuration. Thus, differentiating between gas velocity and momentum is important when evaluating flame stability under various operating conditions. The research efforts described herein are part of an ongoing project directed at evaluating the effect of flame aerodynamics on NO{sub x} emissions from coal fired burners in a systematic manner. This research includes both experimental and modeling efforts being performed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NO{sub x} burners. Experimental studies include both cold-and hot-flow evaluations of the following parameters: primary and secondary inlet air velocity, coal concentration in the primary air, coal particle size distribution and flame holder geometry. Hot-flow experiments will also evaluate the effect of wall temperature on burner performance.

  20. Electron density modification in ionospheric E layer by inserting fine dust particles

    SciTech Connect (OSTI)

    Misra, Shikha; Mishra, S. K.

    2015-02-15

    In this paper, we have developed the kinetics of E-region ionospheric plasma comprising of fine dust grains and shown that the electron density in E-layer can purposely be reduced/enhanced up to desired level by inserting fine dust particles of appropriate physical/material properties; this may certainly be promising for preferred rf-signal processing through these layers. The analytical formulation is based on average charge theory and includes the number and energy balance of the plasma constituents along with charge balance over dust particles. The effect of varying number density, work function, and photo-efficiency of dust particles on ionospheric plasma density at different altitude in E-layer has been critically examined and presented graphically.

  1. Determining the radiative properties of pulverized-coal particles from experiments. Final report

    SciTech Connect (OSTI)

    Menguec, M.P.

    1992-02-01

    A comprehensive coupled experimental-theoretical study has been performed to determine the effective radiative properties of pulverized-coal/char particles. The results obtained show that the ``effective`` scattering phase function of coal particles are highly forward scattering and show less sensitivity to the size than predicted from the Lorenz-Mie theory. The main reason for this is the presence of smaller size particles associated with each larger particle. Also, the coal/char particle clouds display more side scattering than predicted for the same size range spheres, indicating the irregular shape of the particles and fragmentation. In addition to these, it was observed that in the visible wavelength range the coal absorption is not gray, and slightly vary with the wavelength. These two experimental approaches followed in this study are unique in a sense that the physics of the problem are not approximated. The properties determined include all uncertainties related to the particle shape, size distribution, inhomogeneity and spectral complex index of refraction data. In order to obtain radiative property data over a wider wavelength spectrum, additional ex-situ experiments have been carried out using a Fourier Transform Infrared (FT-IR) Spectrometer. The spectral measurements were performed over the wavelength range of 2 to 22 {mu}m. These results were interpreted to obtain the ``effective`` efficiency factors of coal particles and the corresponding refractive index values. The results clearly show that the coal/char radiative properties display significant wavelength dependency in the infrared spectrum.

  2. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect (OSTI)

    Wang, Xiang-Huai; Leonard, J.W.; Parekh, B.K.; Raichur, A.M.; Jiang, Chengliang.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof will lead to identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  3. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect (OSTI)

    Wang, Xiang-Huai.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof, are directed at identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  4. Pyrite surface characterization and control for advanced fine coal desulfurization technologies

    SciTech Connect (OSTI)

    Wang, Xiang-Huai.

    1991-01-01

    The objective of this project is to conduct extensive studies on the surfaces reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of the pyrite rejection in coal flotation. The product as well as their structure, the mechanism and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc., are directed at identifying the cause and possible solutions of the pyrite rejection problems in coal cleaning.

  5. Integrating flotation to improve the performance of an HMC circuit treating a low-rank fine coal

    SciTech Connect (OSTI)

    Celik, H.; Polat, M.

    2005-11-01

    One reason that heavy media cyclone (HMC) circuits suffer from the inadvertent loss of magnetite and fine coal is the presence of nonmagnetic material in the magnetic separator feed. In this study, flotation was applied to the undersize fractions of the HMC drain-and-rinse screens to minimize these problems. These fractions, which contain 17.9% nonmagnetic material, are currently sent to magnetic separators and the nonmagnetic portion from the separators contains 39.1% ash. Applying flotation resulted in a clean coal product with an ash content of 8.7% and a calorific value of 6,300 kcal/kg. The refuse from flotation, which will be sent to the magnetic separators, contains 7.7% nonmagnetics.

  6. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995

    SciTech Connect (OSTI)

    Groppo, J.G.; Parekh, B.K.

    1996-02-01

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

  7. Dependence of liquefaction behavior on coal characteristics. Part V. Penetration of solvent vapor into coal particles. Final technical report, March 1981-February 1984

    SciTech Connect (OSTI)

    Hsieh, S. T.; Duda, J. L.

    1984-04-01

    The investigation of the sorption of solvent vapor into high volatile bituminous coal at temperatures up to 175/sup 0/C indicates that the solvent weight gain involves a complex coupling of several phenomena including adsorption, sorption into the coal matrix, capillary condensation and extraction into the condensed vapor phase. It appears that the sorption in untreated coal is dominated by capillary condensation induced by solvent extraction. As a result, an equilibrium state is not attainable. This extraction mechanism can be eliminated by the preextraction of the coal particles with pyridine. Vapor sorption experiments conducted on pyridine-extracted coal can be used to obtain information concerning the adsorption process and the process associated with the diffusion of the solvent molecules into the coal matrix. Vapor sorption studies conducted on pyridine-extracted coal particles indicate that the sorption process involves a coupling of adsorption, molecular diffusion and a relaxation of the coal structure to a new state. The results have been compared with models derived to describe the coupling of molecular diffusion and polymer chain relaxation in glassy polymers. The thermodynamics of solvent sorption into coal particles is complicated by the presence of severe hysteresis effects. The amount of solvent sorbed by a coal particle is not only a function of solvent activity but depends upon the past history of the sorption process which influences the structure of coal. As a result, fits all the data to various models were obtained but the resulting parameters had doubtful physical significance. (LTN)

  8. Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF

    Broader source: Energy.gov [DOE]

    Basics of particle collection and desogn of filters for diesel soot particles are discussed. Parameters which influence back pressure and filter loading are described.

  9. Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same

    DOE Patents [OSTI]

    Burnet, George (Ames, IA); Gokhale, Ashok J. (College Station, TX)

    1990-07-10

    A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste, and method for producing the same, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces.

  10. Hardened, environmentally disposable composite granules of coal cleaning refuse, coal combustion waste, and other wastes, and method preparing the same

    DOE Patents [OSTI]

    Burnet, G.; Gokhale, A.J.

    1990-07-10

    A hardened, environmentally inert and disposable composite granule of coal cleaning refuse and coal combustion waste and method for producing the same are disclosed, wherein the coal combustion waste is first granulated. The coal cleaning refuse is pulverized into fine particles and is then bound, as an outer layer, to the granulated coal combustion waste granules. This combination is then combusted and sintered. After cooling, the combination results in hardened, environmentally inert and disposable composite granules having cores of coal combustion waste, and outer shells of coal cleaning refuse. The composite particles are durable and extremely resistant to environmental and chemical forces. 3 figs.

  11. Simulation of Coal Ash Particle Deposition Experiments (Copyright 2011, American Chemical Society)

    SciTech Connect (OSTI)

    Ai, Weiguo; Kuhlman, John M

    2011-01-20

    Existing experimental ash particle deposition measurements from the literature have been simulated using the computational fluid dynamics (CFD) discrete phase model (DPM) Lagrangian particle tracking method and an existing ash particle deposition model based on the Johnson−Kendall−Roberts (JKR) theory, in the Fluent commercial CFD code. The experimental heating tube was developed to simulate ash temperature histories in a gasifier; ash-heating temperatures ranged from 1873 to 1573 K, spanning the ash-melting temperature. The present simulations used the realizable k−ε turbulence model to compute the gas flow field and the heat transfer to a cooled steel particle impact probe and DPM particle tracking for the particle trajectories and temperatures. A user-defined function (UDF) was developed to describe particle sticking/rebounding and particle detachment on the impinged wall surface. Expressions for the ash particle Young’s modulus in the model, E, versus the particle temperature and diameter were developed by fitting to the E values that were required to match the experimental ash sticking efficiencies from several particle size cuts and ash-heating temperatures for a Japanese bituminous coal. A UDF that implemented the developed stiffness parameter equations was then used to predict the particle sticking efficiency, impact efficiency, and capture efficiency for the entire ash-heating temperature range. Frequency histogram comparisons of adhesion and rebound behavior by particle size between model and experiments showed good agreement for each of the four ash-heating temperatures. However, to apply the present particle deposition model to other coals, a similar validation process would be necessary to develop the effective Young’s modulus versus the particle diameter and temperature correlation for each new coal.

  12. Combustion of dense streams of coal particles. Final report, August 29, 1990--February 28, 1994

    SciTech Connect (OSTI)

    Annamalai, K.; Gopalakrishnan, C.; Du, X.

    1994-05-01

    The USA consumes almost 94 quads of energy (1 quad = 10{sup 15} BTU or 1.05 {times} 10{sup 15} KJ). The utilities account for about 30 quads of fossil energy where coal is predominantly used as energy source. The coal is ground to finer size and fired into the boiler as dense suspension. Under dense conditions, the particles burn at slower rate due to deficient oxygen within the interparticle spacing. Thus interactions exist amongst the particles for dense clouds. While the earlier literature dealt with combustion processes of isolated particles, the recent research focusses upon the interactive combustion. The interactive combustion studies include arrays consisting of a finite number of particles, and streams and clouds of a large number of particles. Particularly stream combustion models assume cylindrical geometry and predict the ignition and combustion characteristics. The models show that the ignition starts homogeneously for dense streams of coal particles and the ignition time show a minimum as the stream denseness is increased, and during combustion, there appears to be an inner flame within the stream and an outer flame outside the stream for a short period of time. The present experimental investigation is an attempt to verify the model predictions. The set-up consists of a flat flame burner for producing hot vitiated gases, a locally fluidizing feeder system for feeding coal particles, a particle collection probe for collecting particles and an image processing system for analyzing the flame structure. The particles are introduced as a stream into the hot gases and subsequently they ignite and burn. The ash % of fired and collected particles are determined and used to estimate the gasification efficiency or burnt fraction. The parametric studies include gas temperature, oxygen % in gases, residence time, and A:F ratio of the stream.

  13. Relationship between Particle Size Distribution of Low-Rank Pulverized Coal and Power Plant Performance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ganguli, Rajive; Bandopadhyay, Sukumar

    2012-01-01

    Tmore » he impact of particle size distribution (PSD) of pulverized, low rank high volatile content Alaska coal on combustion related power plant performance was studied in a series of field scale tests. Performance was gauged through efficiency (ratio of megawatt generated to energy consumed as coal), emissions (SO 2 , NO x , CO), and carbon content of ash (fly ash and bottom ash). The study revealed that the tested coal could be burned at a grind as coarse as 50% passing 76 microns, with no deleterious impact on power generation and emissions. The PSD’s tested in this study were in the range of 41 to 81 percent passing 76 microns. There was negligible correlation between PSD and the followings factors: efficiency, SO 2 , NO x , and CO. Additionally, two tests where stack mercury (Hg) data was collected, did not demonstrate any real difference in Hg emissions with PSD. The results from the field tests positively impacts pulverized coal power plants that burn low rank high volatile content coals (such as Powder River Basin coal). These plants can potentially reduce in-plant load by grinding the coal less (without impacting plant performance on emissions and efficiency) and thereby, increasing their marketability.« less

  14. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    A.D. Walters; G.H. Luttrell; G.T. Adel; R.-H. Yoon

    1999-01-01

    It is the objective of the current project to further refine the TES process developed at FETC through bench-scale and proof-of-concept (POC) test programs. The bench-scale test program is aimed at studying the charging mechanisms associated with coal and mineral matter and improving the triboelectrification process, while the POC test program is aimed at obtaining scale-up information. The POC tests will be conducted at a throughput of 200-250 kg/hr. It is also the objective of the project to conduct a cost analysis based on the scale-up information obtained in the present work. Specific objectives of the work conducted during the current reporting period can be summarized as follows: to complete the engineering design of the TES tribocharging system and electrostatic separator, and to continue work related to the procurement and fabrication of the key components required to construct and install the proposed POC test circuit.

  15. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 13, October--December, 1995

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-01-31

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit. During Quarter 13 (October--December 1995), testing of the GranuFlow dewatering process indicated a 3--4% reduction in cake moisture for screen-bowl and solid-bowl centrifuge products. The Orimulsion additions were also found to reduce the potential dustiness of the fine coal, as well as improve solids recovery in the screen-bowl centrifuge. Based on these results, Lady Dunn management now plans to use a screen bowl centrifuge to dewater their Microcel{trademark} column froth product. Subtask 3.3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter. Continuing Subtask 6.4 work, investigating coal-water-slurry formulation, indicated that selective agglomeration products can be formulated into slurries with lower viscosities than advanced flotation products. Subtask 6.5 agglomeration bench-scale testing results indicate that a very fine grind is required to meet the 2 lb ash/MBtu product specification for the Winifrede coal, while the Hiawatha coal requires a grind in the 100- to 150-mesh topsize range. Detailed design work remaining involves the preparation and issuing of the final task report. Utilizing this detailed design, a construction bid package was prepared and submitted to three Colorado based contractors for quotes as part of Task 9.

  16. Optimization of Coal Particle Flow Patterns in Low N0x Burners

    SciTech Connect (OSTI)

    Caner Yurteri; Gregory E. Ogden; Jennifer Sinclair; Jost O.L. Wendt

    1998-03-06

    The proposed research is directed at evaluating the effect of flame aerodynamics on NOX emissions tlom coal fired burners in a systematic manner. This fimdamental research includes both experimental and modeling efforts being petiormed at the University of Arizona in collaboration with Purdue University. The objective of this effort is to develop rational design tools for optimizing low NOX burners to the kinetic emissions limit (below 0.2 lb./MMBTU). Experimental studies include both cold and hot flow evaluations of the following parameters: flame holder geometry, secondary air swirl, primary and secondary inlet air velocity, coal concentration in the primary air and coal particle size distribution. Hot flow experiments will also evaluate the effect of wall temperature on burner performance. Cold flow studies will be conducted with surrogate particles as well as pulverized coal. The cold flow furnace will be similar in size and geometry to the hot-flow furnace but will be designed to use a laser Doppler velocimeter/phase Doppler particle size analyzer. The results of these studies will be used to predict particle trajectories in the hot-flow fhrnace as well as to estimate the effect of flame holder geometry on furnace flow field. The hot-flow experiments will be conducted in a novel near-flame down-flow pulverized coal furnace. The fhrnace will be equipped with externally heated walls. Both reactors will be sized to minimize wall effects on particle flow fields. The cold-flow results will be compared with Fluent computation fluid dynamics model predictions and correlated with the hot-flow results with the overall goal of providing insight for novel low NOX burner geometry's.

  17. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect (OSTI)

    R.-H. Yoon; G.H. Luttrell; A.D. Walters

    1999-10-01

    During the past quarter, the installation, testing and shakedown phases of commissioning the TES unit were completed (Tasks 4, 5.1 and 5.2). A representative from Carpco Inc. was on site to provide training in the operation of the test unit and assist with the initial test runs. Problems have been encountered with the recycle conveyor generating dust that neutralizes the particle charge. Testing has continued by batch feeding the unit while the recycle conveying problem is being solved. Good separations have been achieved while operating in this mode. Comparison tests have also been carried out using a bench-scale triboelectrostatic separator in parallel with the POC Carpco unit.

  18. Use of micro-XANES to speciate chromium in airborne fine particles in the Sacramento Valley

    SciTech Connect (OSTI)

    Michelle L. Werner; Peter S. Nico; Matthew A. Marcus; Cort Anastasio

    2007-07-15

    While particulate matter (PM) in the atmosphere can lead to a wide array of negative health effects, the cause of toxicity is largely unknown. One aspect of PM that likely affects health is the chemical composition, in particular the transition metals within the particles. Chromium is one transition metal of interest due to its two major oxidation states, with Cr(III) being much less toxic compared to Cr(VI). Using microfocused X-ray absorption near edge structure (micro-XANES), we analyzed the Cr speciation in fine particles (diameters {le} 2.5 {mu}m) collected at three sites in the Sacramento Valley of northern California: Sacramento, a large urban area, Davis, a small city, and Placerville, a rural area. These are several major stationary sources of Cr within 24 km of the site including chrome-plating plants, power plants and incinerators. The microfocused X-ray beam enables us to look at very small areas on the filter with a resolution of typically 5-7 micrometers. With XANES we are able to not only distinguish between Cr(VI) and Cr(III), but also to identify different types of Cr(III) and more reduced Cr species. At all of our sampling sites the main Cr species were Cr(III), with Cr(OH){sub 3} or a Cr-Fe, chromite-like, phase being the dominant species. Cr(VI)-containing particles were found only in the most urban site. All three sites contained some reduced Cr species, either Cr(0) or Cr{sub 3}C{sub 2}, although these were minor components. This work demonstrates that micro-XANES can be used as a minimally invasive analytical tool to investigate the composition of ambient PM. 32 refs., 6 figs.

  19. Pilot Demonstration of Technology for the Production of High Value Materials from the Ultra-Fine (PM2.5) Fraction of Coal Combustion Ash

    SciTech Connect (OSTI)

    T. L. Robl; J. G. Groppo; R. Rathbone; B. Marrs; R. Jewell

    2008-07-18

    The overall objective of this research was to determine the feasibility of recovering a very fine fraction of fly ash, that is 5 microns in diameter or less and examining the characteristics of these materials in new or at least less traditional applications. These applications included as a polymer filler or as a 'super' pozzolanic concrete additive. As part of the effort the ash from 6 power plants was investigated and characterized. This work included collection from ESP Hoppers and ponds. The ash was thoroughly characterized chemically and physically. Froth flotation was used to reduce the carbon and testing showed that flotation could effectively reduce carbon to acceptable levels (i.e. 0.5% LOI) for most of the substrates tested. in order to enable eventual use as fillers. Hydraulic classification was used in the separation of the fine ash from the coarse ash. Hydraulic classification requires the ash to be dispersed to be effective and a range of dispersants were tested for adsorption as well as sedimentation rate. A wide range of dosages were required (0.3 to 10 g/kg). In general the ponded ash required less dispersant. A model was developed for hydraulic classification. A pilot-scale hydraulic classifier was also designed and operated for the project. Product yields of up to 21% of feed solids were achieved with recoveries of <5 {micro}m particles as high as 64%. Mean particle sizes (D{sub 50}) of the ultra fine ash (UFA) products varied from 3.7 to 10 {micro}m. A patent was filed on the classifier design. A conceptual design of a Process Demonstration Unit (PDU) with a feed rate of 2 tons of raw ash feed per hour was also completed. Pozzolanic activity was determined for the UFA ashes in mortars. In general the overall strength index was excellent with values of 90% achieved in 3 days and {approx}100% in 7 days. Three types of thermoplastic polymers were evaluated with the UFA as a filler: high density polyethylene, thermoplastic elastomer and polyethylene terphthalate filled polymers were prepared and subjected to SEM analysis to verify that the UFA was well dispersed. The addition of fillers increased the modulus of the HDPE composite, but decreased both the offset yield stress and offset yield strain, showing that the fillers essentially made the composite stiffer but the transition to plastic deformation occurred earlier in filled HDPE as stress was applied. Similar results were obtained with TPE, however, the decrease in either stress or strain at offset yield were not as significant. Dynamic mechanical analyses (DMA) were also completed and showed that although there were some alterations in the properties of the HDPE and TPE, the alterations are small, and more importantly, transition temperatures are not altered. The UFA materials were also tested in expanded urethanes, were improvements were made in the composites strength and stiffness, particularly for lighter weight materials. The results of limited flammability and fire safety testing were encouraging. A flowsheet was developed to produce an Ultra-Fine Ash (UFA) product from reclaimed coal-fired utility pond ash. The flowsheet is for an entry level product development scenario and additional production can be accommodated by increasing operating hours and/or installing replicate circuits. Unit process design was based on experimental results obtained throughout the project and cost estimates were derived from single vendor quotes. The installation cost of this plant is estimated to be $2.1M.

  20. Analysis of mass loss of a coal particle during the course of burning in a flow of inert material

    SciTech Connect (OSTI)

    Pelka, Piotr

    2009-08-15

    This paper is an attempt to explain the role of erosion during the process of coal combustion in a circulating fluidized bed. Different kinds of carbon deposits found in Poland, both bituminous as well as lignite with the particle of 10 mm in diameter were the subject of the research. According to many publications it is well known that erosion plays a significant role in coal combustion, by changing its mechanism as well as generating an additional mass loss of the mother particle. The purpose of this research was to determine the influence of an inert material on an erosive mass loss of a single coal particle burning in a two-phase flow. The determination of the influence of a coal type, the rate of flow of inert material and the temperature inside the furnace on the erosive mass loss of burning coal particle was also taken into consideration. The results obtained indicate that the velocity of the erosive mass loss depends on the chemical composition and petrographic structure of burning coal. The mechanical interaction of inert and burning coal particles leads to the shortening of the period of overall mass loss of the coal particle by even two times. The increase in the rate of flow of the inert material intensifies the generation of mass loss by up to 100%. The drop in temperature which slows down the combustion process, decreases the mass loss of the coal particle as the result of mechanical interaction of the inert material. As was observed, the process of percolation plays a significant role by weakening the surface of the burning coal. (author)

  1. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.-H. Yoon; G.H. Luttrell; A.D. Walters

    2000-01-01

    During the past quarter, several modifications were made to the TES unit and the materials handling system. The cylindrical electrodes were replaced by a set of screen electrodes to provide a more uniform electrostatic field. The problem with the recycle conveyor neutralizing the particle charge was also corrected by replacing it with a bucket elevator. In addition, problems with the turbocharger were corrected by increasing the number of charging stages from one to two. These modifications have significantly improved the separation performance and have permitted the POC-scale unit to achieve results in line with those obtained by the bench-scale separator. The testing phase of the project was continued at a rapid pace during this quarter. The test work showed that the modifications to the TES unit and the reduction in feed size from 28 mesh to 35 mesh resulted in significant overall improvement in yield and combustible recovery compared to the data reported in the last quarter. At that time, there was a significant discrepancy between the bench-scale and the pilot-scale results. The pilot-scale test work is now approaching the bench scale test results. However, further pilot-scale test work is required to further improve the results and duplicate the bench-scale test work.

  2. Proof of concept and performance optimization of high gravity batch type centrifuge for dewatering fine coal. Quarterly technical progress report No. 3, March 20, 1990--June 20, 1990, Revision

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.E. Jr.

    1990-07-24

    Coal Technology Corporation (CTC) believes that the new CTC high gravity, high production, batch type centrifugal dryer technology can play a significant role in improving the product quality as well as costs of operation in coal processing plants. It is further believed that the new centrifugal dryer technology can form an important part in systems used to clean up the millions of tons of coal fines in refuse piles and ponds. It is anticipated that the new centrifuge can become an important ancillary to the advanced deep cleaning processes for coal. Because of these convictions, CTC has been engaged in a pioneering research effort into the new art of drying fine clean coal in high gravity, high production, batch type centrifuges, since 1981. This work has progressed to the point where the new centrifugal dryer technology is nearly ready for commercialization. It promises to provide needed fine coal drying capability at somewhat lower capital costs and at substantially lower operating costs than competitive systems. It also promises to do so with no detrimental effects on either the coal quality or the evironment. The primary objective of this project is to prove the concept in a commercial coal processing plant environment. The proof of concept tests will also include testing with a variety of coals from different regions. A further objective will be to optimize the efficiency and the cost effectiveness of the new centrifugal dryer technology.

  3. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  4. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. First annual report, September 1, 1990--August 30, 1991

    SciTech Connect (OSTI)

    Wang, Xiang-Huai

    1991-12-31

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof, are directed at identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  5. Levitation and collection of diamond fine particles in the rf plasma chamber equipped with a hot filament

    SciTech Connect (OSTI)

    Shimizu, S.; Shimizu, T.; Thomas, H. M.; Morfill, G. E.; Jacob, W.

    2011-11-15

    We demonstrate the levitation of diamond fine particles in a H{sub 2} rf plasma chamber equipped with a hot filament and heated electrodes. The levitation conditions should be carefully chosen to compensate the strong thermophoretic forces caused by the filament and the electrodes. This levitation technique with the existence of a hot filament can be applied, e.g., for the efficient growth of diamond layers on seed particles injected and levitated in an rf plasma with reactive gases, e.g., CH{sub 4}/H{sub 2}. Additionally, the method for direct capture of levitated particles on a planar substrate was established, which is useful if it is necessary to analyze the particles after the levitation.

  6. DOE Award Results in Several Patents, Potential Increased Coal Recovery

    Broader source: Energy.gov [DOE]

    A $13 million cooperative effort with the Office of Fossil Energy's National Energy Technology Laboratory (NETL) over the past seven years has resulted in the successful demonstration of a novel technology that addresses a problem plaguing coal operators and environmentalists alike: separating fine coal particles from water and their ultimate use as a significant energy resource.

  7. Proof of concept and performance optimization of high gravity batch-type centrifugal dryer for dewatering fine coal

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.

    1991-01-01

    The primary objective of the project was to assemble, analyze and make use of those data that could help to clearly identify, optimize and confirm the technical and economic advantages that the new high gravity centrifugal dryer technology can provide to the coal industry and to end users. Other objectives were: to confirm the feasibility of the dryer for drying coals from a number of different seams; to use the data base for optimizing the dryer's systems, and: to produce projected technical and economic comparisons with thermal dryers as applied to an existing coal processing plant flow sheet. (JL)

  8. Image analysis measurements of particle coefficient of restitution for coal gasification applications

    SciTech Connect (OSTI)

    Gibson, LaTosha M.; Gopalan, Balaji; Pisupati, Sarma V.; Shadle, Lawrence J.

    2013-10-01

    New robust Lagrangian computational fluid dynamic (CFD) models are powerful tools that can be used to study the behavior of a diverse population of coal particle sizes, densities, and mineral compositions in entrained gasifiers. By using this approach, the responses of the particles impacting the wall were characterized over a range of velocities (1 to 8 m/s) and incident angles (90 to 20). Within CFD models, the kinematic coefficient of restitution is the boundary condition defining the particle wall behavior. Four surfaces were studied to simulate the physical conditions of different entrained-flow gasification particlesurface collision scenarios: 1) a flat metal plate 2) a low viscosity silicon adhesive, 3) a high viscosity silicon adhesive, and 4) adhered particles on a flat metal plate with Young's modulus of elasticity ranging from 0.9 to 190 GPa. Entrained flow and drop experiments were conducted with granular coke particles, polyethylene beads and polystyrene pellets. The particle normal and tangential coefficients of restitution were measured using high speed imaging and particle tracking. The measured coefficients of restitution were observed to have a strong dependence on the rebound angles for most of the data. Suitable algebraic expressions for the normal and the tangential component of the coefficient of restitution were developed based upon ANOVA analysis. These expressions quantify the effect of normalized Young's modulus, particle equancy, and relative velocity on the coefficient of restitution. The coefficient of restitution did not have a strong dependence on the particle velocity over the range considered as long as the velocity was above the critical velocity. However, strong correlations were found between the degree of equancy of the particles and the mean coefficient of restitution such that the coefficient of restitution decreased for smaller particle equancies. It was concluded that the degree of equancy and the normalized Young's modulus should be considered in applications such as gasification and other cases involving the impact of non-spherical particles and complex surfaces. Sliding was observed when particles impacted on oblique surfaces; however, the resulting effects were within the range of measurement uncertainties.

  9. Method for making fine and ultrafine spherical particles of zirconium titanate and other mixed metal oxide systems

    DOE Patents [OSTI]

    Hu, Michael Z.

    2006-05-23

    Disclosed is a method for making amorphous spherical particles of zirconium titanate and crystalline spherical particles of zirconium titanate comprising the steps of mixing an aqueous solution of zirconium salt and an aqueous solution of titanium salt into a mixed solution having equal moles of zirconium and titanium and having a total salt concentration in the range from 0.01 M to about 0.5 M. A stearic dispersant and an organic solvent is added to the mixed salt solution, subjecting the zirconium salt and the titanium salt in the mixed solution to a coprecipitation reaction forming a solution containing amorphous spherical particles of zirconium titanate wherein the volume ratio of the organic solvent to aqueous part is in the range from 1 to 5. The solution of amorphous spherical particles is incubated in an oven at a temperature .ltoreq.100.degree. C. for a period of time .ltoreq.24 hours converting the amorphous particles to fine or ultrafine crystalline spherical particles of zirconium titanate.

  10. STUDY OF SOLVENT AND CATALYST INTERACTIONS IN DIRECT COAL LIQUEFACTION

    SciTech Connect (OSTI)

    Michael T. Klein

    1998-10-01

    Major objectives of the present project are to develop a better understanding of the roles of the catalyst and the liquefaction solvent in the coal liquefaction process. An open question concerning the role of the catalyst is whether intimate contact between the catalyst and the coal particles is important or required. To answer this question, it had been planned to coat an active catalyst with a porous silica coating which was found to retain catalyst activity while preventing actual contact between catalyst and coal. Consultation with people in DuPont who coat catalysts for increasing abrasion resistance have indicated that only portions of the catalyst are coated by their process (spray drying) and that sections of uncoated catalyst remain. For that reason, it was decided to suspend the catalyst in a basket separated from the coal in the reactor. The basket walls were to be permeable to the liquefaction solvent but not to the coal particles. Several such baskets were constructed of stainless steel with holes which would not permit passage of coal particles larger than 30 mesh. Liquefactions run with the coal of greater than 30 mesh size gave normal conversion of coal to liquid in the absence of catalyst in the basket, but substantially increased conversion when Ni/Mo on alumina catalyst was in the basket. While this result is interesting and suggestive of some kind of mass transfer of soluble material occurring between the catalyst and the coal, it does not eliminate the possibility of breakdown of the coal particle into particle sizes permeable to the basket. Indeed, a small amount of fine coal has been found inside the basket. To determine whether fine coal from breakdown of the coal particles is responsible for the conversion, a new basket is being prepared with 0.5{micro}m pore size.

  11. Capture Efficiency of Cooking-Related Fine and Ultrafine Particles by Residential Exhaust Hoods

    SciTech Connect (OSTI)

    Lunden, Melissa M.; Delp, William W.

    2014-06-05

    Effective exhaust hoods can mitigate the indoor air quality impacts of pollutant emissions from residential cooking. This study reports capture efficiencies (CE) measured for cooking generated particles for scripted cooking procedures in a 121-m3 chamber with kitchenette. CEs also were measured for burner produced CO2 during cooking and separately for pots and pans containing water. The study used four exhaust hoods previously tested by Delp and Singer (Environ. Sci. Technol., 2012, 46, 6167-6173). For pan-frying a hamburger over medium heat on the back burner, CEs for particles were similar to those for burner produced CO2 and mostly above 80percent. For stir-frying green beans in a wok (high heat, front burner), CEs for burner CO2 during cooking varied by hood and airflow: CEs were 34-38percent for low (51?68 L s-1) and 54?72percent for high (109?138 L s-1) settings. CEs for 0.3?2.0 ?m particles during front burner stir-frying were 3?11percent on low and 16?70percent on high settings. Results indicate that CEs measured for burner CO2 are not predictive of CEs of cooking-generated particles under all conditions, but they may be suitable to identify devices with CEs above 80percent both for burner combustion products and for cooking-related particles.

  12. Surface preparation of substances for continuous convective assembly of fine particles

    DOE Patents [OSTI]

    Rossi, Robert (Rochester, MN)

    2003-01-01

    A method for producing periodic nanometer-scale arrays of metal or semiconductor junctions on a clean semiconductor substrate surface is provided comprising the steps of: etching the substrate surface to make it hydrophilic, forming, under an inert atmosphere, a crystalline colloid layer on the substrate surface, depositing a metal or semiconductor material through the colloid layer onto the surface of the substrate, and removing the colloid from the substrate surface. The colloid layer is grown on the clean semiconductor surface by withdrawing the semiconductor substrate from a sol of colloid particles.

  13. Production of Illinois base compliance coal using enhanced gravity separation. [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect (OSTI)

    Paul, B.C.; Honaker, R.Q.; Ho, K.

    1993-12-31

    Illinois Basin coal often contains a significant portion of finely dispersed pyrite. Most of the free pyrite particles exist in the fine size fractions, which are generally treated using froth flotation. An inherent problem of the froth flotation process is the inefficient treatment of middling particles containing a small amount of coal on their surface. On the other hand, gravity-based processes can effectively remove middling particles containing only a small amount of coal. Falcon Concentrators Inc. and Knelson Gold Concentrators Inc. have developed full-scale, enhanced gravity separators for the treatment of heavy minerals. This project will evaluate the potential of using these concentrators to de-ash and de-sulfurize Illinois coal fines, thus, producing coal products that meet the requirements for Phase I of the Clean Air Act. Since both continuous separators are commercially available, the results obtained in this investigation should be applicable to industrial operations.

  14. EVALUATION OF THE EMISSION, TRANSPORT, AND DEPOSITION OF MERCURY, FINE PARTICULATE MATTER, AND ARSENIC FROM COAL-BASED POWER PLANTS IN THE OHIO RIVER VALLEY REGION

    SciTech Connect (OSTI)

    Kevin Crist

    2004-10-02

    Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, is evaluating the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury, arsenic, and associated fine particulate matter. This evaluation will involve two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring will include the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station will contain sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), arsenic, particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO{sub 2}, O{sub 3}, etc.). Laboratory analysis of time-integrated samples will be used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Near-real-time measurements will be used to measure the ambient concentrations of PM mass and all gaseous species including Hg{sup 0} and RGM. Approximately of 18 months of field data will be collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data will also provide mercury, arsenic, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis will include (1) development of updated inventories of mercury and arsenic emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg{sup 0}, RGM, arsenic, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This will be accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results will also be compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratory's monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by U.S. EPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions will provide critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  15. Evaluation of the Emission, Transport, and Deposition of Mercury and Fine Particulate Matter from Coal-Based Power Plants in the Ohio River Valley Region

    SciTech Connect (OSTI)

    Kevin Crist

    2008-12-31

    As stated in the proposal: Ohio University, in collaboration with CONSOL Energy, Advanced Technology Systems, Inc (ATS) and Atmospheric and Environmental Research, Inc. (AER) as subcontractors, evaluated the impact of emissions from coal-fired power plants in the Ohio River Valley region as they relate to the transport and deposition of mercury and associated fine particulate matter. This evaluation involved two interrelated areas of effort: ambient air monitoring and regional-scale modeling analysis. The scope of work for the ambient air monitoring included the deployment of a surface air monitoring (SAM) station in southeastern Ohio. The SAM station contains sampling equipment to collect and measure mercury (including speciated forms of mercury and wet and dry deposited mercury), particulate matter (PM) mass, PM composition, and gaseous criteria pollutants (CO, NOx, SO2, O3, etc.). Laboratory analyses of time-integrated samples were used to obtain chemical speciation of ambient PM composition and mercury in precipitation. Nearreal- time measurements were used to measure the ambient concentrations of PM mass and all gaseous species including Hg0 and RGM. Approximately 30 months of field data were collected at the SAM site to validate the proposed regional model simulations for episodic and seasonal model runs. The ambient air quality data provides mercury, and fine particulate matter data that can be used by Ohio Valley industries to assess performance on multi-pollutant control systems. The scope of work for the modeling analysis includes (1) development of updated inventories of mercury emissions from coal plants and other important sources in the modeled domain; (2) adapting an existing 3-D atmospheric chemical transport model to incorporate recent advancements in the understanding of mercury transformations in the atmosphere; (3) analyses of the flux of Hg0, RGM, and fine particulate matter in the different sectors of the study region to identify key transport mechanisms; (4) comparison of cross correlations between species from the model results to observations in order to evaluate characteristics of specific air masses associated with long-range transport from a specified source region; and (5) evaluation of the sensitivity of these correlations to emissions from regions along the transport path. This is accomplished by multiple model runs with emissions simulations switched on and off from the various source regions. To the greatest extent possible, model results were compared to field data collected at other air monitoring sites in the Ohio Valley region, operated independently of this project. These sites may include (1) the DOE National Energy Technologies Laboratorys monitoring site at its suburban Pittsburgh, PA facility; (2) sites in Pittsburgh (Lawrenceville) PA and Holbrook, PA operated by ATS; (3) sites in Steubenville, OH and Pittsburgh, PA operated by the USEPA and/or its contractors; and (4) sites operated by State or local air regulatory agencies. Field verification of model results and predictions provides critical information for the development of cost effective air pollution control strategies by the coal-fired power plants in the Ohio River Valley region.

  16. Assessment of reduction behavior of hematite iron ore pellets in coal fines for application in sponge ironmaking

    SciTech Connect (OSTI)

    Kumar, M.; Patel, S.K.

    2009-07-01

    Studies on isothermal reduction kinetics (with F grade coal) in fired pellets of hematite iron ores, procured from four different mines of Orissa, were carried out in the temperature range of 850-1000C to provide information for the Indian sponge iron plants. The rate of reduction in all the fired iron ore pellets increased markedly with a rise of temperature up to 950C, and thereafter it decreased at 1000C. The rate was more intense in the first 30 minutes. All iron ores exhibited almost complete reduction in their pellets at temperatures of 900 and 950C in 2 hours' heating time duration, and the final product morphologies consisted of prominent cracks. The kinetic model equation 1-(1-a){sup 1/3}=kt was found to fit best to the experimental data, and the values of apparent activation energy were evaluated. Reductions of D. R. Pattnaik and M. G. Mohanty iron ore pellets were characterized by higher activation energies (183 and 150 kJ mol{sup -1}), indicating carbon gasification reaction to be the rate-controlling step. The results established lower values of activation energy (83 and 84 kJ mol{sup -1}) for the reduction of G. M. OMC Ltd. and Sakaruddin iron ore pellets, proposing their overall rates to be controlled by indirect reduction reactions.

  17. PASSIVE CONTROL OF PARTICLE DISPERSION IN A PARTICLE-LADEN CIRCULAR JET USING ELLIPTIC CO-ANNULAR FLOW: A MEANS FOR IMPROVING UTILIZATION AND EMISSION REDUCTIONS IN PULVERIZED COAL BURNER

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2003-06-01

    A passive control technology utilizing elliptic co-flow to control the particle flinging and particle dispersion in a particle (coal)-laden flow was investigated using experimental and numerical techniques. Preferential concentration of particles occurs in particle-laden jets used in pulverized coal burner and causes uncontrollable NO{sub x} formation due to inhomogeneous local stoichiometry. This particular project was aimed at characterizing the near-field flow behavior of elliptic coaxial jets. The knowledge gained from the project will serve as the basis of further investigation on fluid-particle interactions in an asymmetric coaxial jet flow-field and thus is important to improve the design of pulverized coal burners where non-homogeneity of particle concentration causes increased NO{sub x} formation.

  18. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    T.D. Wheelock

    1999-03-01

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  19. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  20. Coal combustion aerothermochemistry research. Final report

    SciTech Connect (OSTI)

    Witte, A.B.; Gat, N.; Denison, M.R.; Cohen, L.M.

    1980-12-15

    On the basis of extensive aerothermochemistry analyses, laboratory investigations, and combustor tests, significant headway has been made toward improving the understanding of combustion phenomena and scaling of high swirl pulverized coal combustors. A special attempt has been made to address the gap between scientific data available on combustion and hardware design and scaling needs. Both experimental and theoretical investigations were conducted to improve the predictive capability of combustor scaling laws. The scaling laws derived apply to volume and wall burning of pulverized coal in a slagging high-swirl combustor. They incorporate the findings of this investigation as follows: laser pyrolysis of coal at 10/sup 6/ K/sec and 2500K; effect of coal particle shape on aerodynamic drag and combustion; effect of swirl on heat transfer; coal burnout and slag capture for 20 MW/sub T/ combustor tests for fine and coarse coals; burning particle trajectories and slag capture; particle size and aerodynamic size; volatilization extent and burnout fraction; and preheat level. As a result of this work, the following has been gained: an increased understanding of basic burning mechanisms in high-swirl combustors and an improved model for predicting combustor performance which is intended to impact hardware design and scaling in the near term.

  1. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. Fourth quarterly technical progress report, June 1, 1991--August 31, 1991

    SciTech Connect (OSTI)

    Wang, Xiang-Huai

    1991-12-31

    The objective of this project is to conduct extensive studies on the surfaces reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of the pyrite rejection in coal flotation. The product as well as their structure, the mechanism and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc., are directed at identifying the cause and possible solutions of the pyrite rejection problems in coal cleaning.

  2. Pyrite surface characterization and control for advanced fine coal desulfurization technologies. Third quarterly technical progress report, March 1, 1991--May 30, 1991

    SciTech Connect (OSTI)

    Wang, Xiang-Huai; Leonard, J.W.; Parekh, B.K.; Raichur, A.M.; Jiang, Chengliang

    1991-12-31

    The objective of this project is to conduct extensive studies on the surface reactivity of pyrite by using electrochemical, surface analysis, potentiometric and calorimetric titration, and surface hydrophobicity characterization techniques and to correlate the alteration of the coal-pyrite surface with the efficiency of pyrite rejection in coal flotation. The products as well as their structure, the mechanisms and the kinetics of the oxidation of coal-pyrite surfaces and their interaction with various chemical reagents will be systematically studied and compared with that of mineral-pyrite and synthetic pyrite to determine the correlation between the surface reactivity of pyrite and the bulk chemical properties of pyrite and impurities. The surface chemical studies and the studies of floatability of coal-pyrite and the effect of various parameters such as grinding media and environment, aging under different atmospheres, etc. on thereof will lead to identifying the causes and possible solutions of the pyrite rejection problems in coal cleaning.

  3. Proof of concept and performance optimization of high gravity batch-type centrifugal dryer for dewatering fine coal. Final report, September 20, 1989--September 21, 1991

    SciTech Connect (OSTI)

    Smith, L.B.; Durney, T.

    1991-12-31

    The primary objective of the project was to assemble, analyze and make use of those data that could help to clearly identify, optimize and confirm the technical and economic advantages that the new high gravity centrifugal dryer technology can provide to the coal industry and to end users. Other objectives were: to confirm the feasibility of the dryer for drying coals from a number of different seams; to use the data base for optimizing the dryer`s systems, and: to produce projected technical and economic comparisons with thermal dryers as applied to an existing coal processing plant flow sheet. (JL)

  4. Continuous fine ash depressurization system

    DOE Patents [OSTI]

    Liu, Guohai (Birmingham, AL); Peng, Wan Wang (Birmingham, AL); Vimalchand, Pannalal (Birmingham, AL)

    2011-11-29

    A system for depressurizing and cooling a high pressure, high temperature fine solid particles stream having entrained gas therein. In one aspect, the system has an apparatus for cooling the high pressure, high temperature fine solid particles stream having entrained gas therein and a pressure letdown device for depressurization by separating the cooled fine solid particles from a portion of the fine solid particles stream having entrained gas therein, resulting in a lower temperature, lower pressure outlet of solid particles for disposal or handling by downstream equipment.

  5. Novel microorganism for selective separation of coal from pyrite and ash. Final report

    SciTech Connect (OSTI)

    Misra, M.; Smith, R.W.

    1995-09-01

    The separation of fine coal from ash and pyrite was evaluated using a microorganism Mycobacterium phlei.

  6. COAL PARTICLE FLOW PATTERNS FOR O2 ENRICHED, LOW NOx BURNERS

    SciTech Connect (OSTI)

    Jennifer L. Sinclair

    2001-09-30

    Over the past year, the hot flow studies have focused on the validation of a novel 2M near-flame combustion furnace. The 2M furnace was specifically designed to investigate burner aerodynamics and flame stability phenomena. Key accomplishments include completion of coal & oxygen mass balance calculations and derivation of emission conversion equations, upgrade of furnace equipment and flame safety systems, shakedown testing and partial completion of a parametric flame stability study. These activities are described in detail below along with a description of the 2M furnace and support systems.

  7. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    SciTech Connect (OSTI)

    Smith, V.E.; Merriam, N.W.

    1994-10-01

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  8. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  9. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  10. A facile gel-combustion route for fine particle synthesis of spinel ferrichromite: X-ray and Mssbauer study on effect of Mg and Ni content

    SciTech Connect (OSTI)

    Vader, V.T.; Achary, S.N.; Meena, S.S.

    2014-02-01

    Highlights: A novel and facile synthesis route. Transformation of system from random to inverse spinel. Appearance of superparamagnetism phase. - Abstract: A novel nitratecitrate gel combustion route was used to prepare fine particle of a series Mg{sub 1?x}Ni{sub x}FeCrO{sub 4} (0.0 ? x ? 1.0) and its structural properties were investigated. The in situ oxidizing environment provided by the nitrate ions in the gel increases the rate of oxidation and lowers the decomposition temperature of component. All the samples after sintering were characterized at room temperature by X-ray diffraction (XRD) method and Mssbauer spectroscopy techniques. The X-ray and Mssbauer studies confirmed the single phase cubic spinel structure with all Fe ions in 3+ charge state. XRD and Mssbauer studies revealed that the samples of x = 0.0, and 0.2 are random spinel and show rather broad lines, while x = 0.41.0 are inverse spinel.

  11. Coal-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  12. Effects of preoxidation on the swelling and softening of bituminous coals

    SciTech Connect (OSTI)

    Maloney, D. J.; Jenkins, R. G.; Walker, Jr., P. L.

    1980-04-01

    A study was conducted to evaluate the applicability of a DuPont 942-TMA (Thermomechanical Analyzer) dilatometer system for the characterization of the swelling and softening properties of caking coals. The results of this investigation demonstrate the utility of this dilatometer system. Several parameters clearly defined with this unit are characteristic of the plastic transitions occurring upon carbonization. These include softening, dilation and resolidification temperature and volume contraction, expansion and total dilation values. The transition parameters measured with the 942-TMA unit are influenced significantly by coal particle size, dilatometer load, and heating rate. All transition temperatures exhibit marked increases with increasing heating rate. Softening temperatures decrease with increasing load and particle size. Dilation temperatures are essentially independent of dilatometer load effects and resolidification temperatures are independent of load and particle size over the range of conditions used in this study. Volume contraction and expansion values show an increase with decreasing coal particle size. Volume expansion values also exhibit strong heating rate and load dependencies. The results point up the great difficulty involved in obtaining truly fresh unoxidized coal samples. Storage of fine coal particles for extended periods of time in atmospheres with even slight oxygen concentrations show signs of weathering. Exposure of an HVA coal to dry air at ambient temperature has much less effect on subsequent swelling and softening properties than does exposure to moist air.

  13. Assessing the nonlinear response of fine particles to precursor emissions: Development and application of an extended response surface modeling technique v1.0

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, B.; Wang, S. X.; Xing, J.; Fu, K.; Fu, J. S.; Jang, C.; Zhu, Y.; Dong, X. Y.; Gao, Y.; Wu, W. J.; et al

    2015-01-30

    An innovative extended response surface modeling technique (ERSM v1.0) is developed to characterize the nonlinear response of fine particles (PM₂̣₅) to large and simultaneous changes of multiple precursor emissions from multiple regions and sectors. The ERSM technique is developed based on the conventional response surface modeling (RSM) technique; it first quantifies the relationship between PM₂̣₅ concentrations and the emissions of gaseous precursors from each single region using the conventional RSM technique, and then assesses the effects of inter-regional transport of PM₂̣₅ and its gaseous precursors on PM₂̣₅ concentrations in the target region. We apply this novel technique with a widelymore » used regional chemical transport model (CTM) over the Yangtze River delta (YRD) region of China, and evaluate the response of PM₂̣₅ and its inorganic components to the emissions of 36 pollutant–region–sector combinations. The predicted PM₂̣₅ concentrations agree well with independent CTM simulations; the correlation coefficients are larger than 0.98 and 0.99, and the mean normalized errors (MNEs) are less than 1 and 2% for January and August, respectively. It is also demonstrated that the ERSM technique could reproduce fairly well the response of PM₂̣₅ to continuous changes of precursor emission levels between zero and 150%. Employing this new technique, we identify the major sources contributing to PM₂̣₅ and its inorganic components in the YRD region. The nonlinearity in the response of PM₂̣₅ to emission changes is characterized and the underlying chemical processes are illustrated.« less

  14. Assessing the nonlinear response of fine particles to precursor emissions: Development and application of an extended response surface modeling technique v1.0

    SciTech Connect (OSTI)

    Zhao, B.; Wang, S. X.; Xing, J.; Fu, K.; Fu, J. S.; Jang, C.; Zhu, Y.; Dong, X. Y.; Gao, Y.; Wu, W. J.; Wang, J. D.; Hao, J. M.

    2015-01-30

    An innovative extended response surface modeling technique (ERSM v1.0) is developed to characterize the nonlinear response of fine particles (PM₂̣₅) to large and simultaneous changes of multiple precursor emissions from multiple regions and sectors. The ERSM technique is developed based on the conventional response surface modeling (RSM) technique; it first quantifies the relationship between PM₂̣₅ concentrations and the emissions of gaseous precursors from each single region using the conventional RSM technique, and then assesses the effects of inter-regional transport of PM₂̣₅ and its gaseous precursors on PM₂̣₅ concentrations in the target region. We apply this novel technique with a widely used regional chemical transport model (CTM) over the Yangtze River delta (YRD) region of China, and evaluate the response of PM₂̣₅ and its inorganic components to the emissions of 36 pollutant–region–sector combinations. The predicted PM₂̣₅ concentrations agree well with independent CTM simulations; the correlation coefficients are larger than 0.98 and 0.99, and the mean normalized errors (MNEs) are less than 1 and 2% for January and August, respectively. It is also demonstrated that the ERSM technique could reproduce fairly well the response of PM₂̣₅ to continuous changes of precursor emission levels between zero and 150%. Employing this new technique, we identify the major sources contributing to PM₂̣₅ and its inorganic components in the YRD region. The nonlinearity in the response of PM₂̣₅ to emission changes is characterized and the underlying chemical processes are illustrated.

  15. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  16. Process for preparing a stabilized coal-water slurry

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Doohee (Macungie, PA)

    1987-01-01

    A process for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases.

  17. Process for preparing a stabilized coal-water slurry

    DOE Patents [OSTI]

    Givens, E.N.; Kang, D.

    1987-06-23

    A process is described for preparing a stabilized coal particle suspension which includes the steps of providing an aqueous media substantially free of coal oxidizing constituents, reducing, in a nonoxidizing atmosphere, the particle size of the coal to be suspended to a size sufficiently small to permit suspension thereof in the aqueous media and admixing the coal of reduced particle size with the aqueous media to release into the aqueous media coal stabilizing constituents indigenous to and carried by the reduced coal particles in order to form a stabilized coal particle suspension. The coal stabilizing constituents are effective in a nonoxidizing atmosphere to maintain the coal particle suspension at essentially a neutral or alkaline pH. The coal is ground in a nonoxidizing atmosphere such as an inert gaseous atmosphere to reduce the coal to a sufficient particle size and is admixed with an aqueous media that has been purged of oxygen and acid-forming gases. 2 figs.

  18. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, Wendell H. (Kaysville, UT); Oblad, Alex G. (Salt Lake City, UT); Shabtai, Joseph S. (Salt Lake City, UT)

    1994-01-01

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

  19. Process for selective grinding of coal

    DOE Patents [OSTI]

    Venkatachari, Mukund K. (San Francisco, CA); Benz, August D. (Hillsborough, CA); Huettenhain, Horst (Benicia, CA)

    1991-01-01

    A process for preparing coal for use as a fuel. Forming a coal-water slurry having solid coal particles with a particle size not exceeding about 80 microns, transferring the coal-water slurry to a solid bowl centrifuge, and operating same to classify the ground coal-water slurry to provide a centrate containing solid particles with a particle size distribution of from about 5 microns to about 20 microns and a centrifuge cake of solids having a particle size distribution of from about 10 microns to about 80 microns. The classifer cake is reground and mixed with fresh feed to the solid bowl centrifuge for additional classification.

  20. Coal beneficiation by gas agglomeration

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  1. Coal Beneficiation by Gas Agglomeration

    SciTech Connect (OSTI)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  2. Production of Illinois base compliance coal using enhanced gravity separation. Technical report, March 1, 1994--May 31, 1994

    SciTech Connect (OSTI)

    Paul, B.C.; Honaker, R.Q.

    1994-09-01

    It is well known that froth flotation is inefficient for treating fine coal fractions containing a significant portion of middling particles. On the other hand, gravity-based processes can effectively remove middling particles containing only a small amount of coal. Falcon Concentrators Inc. and Knelson Gold Concentrators Inc. have developed full-scale, enhanced gravity separators for the treatment of heavy minerals. This project is evaluating the potential of using these concentrators to treat Illinois Basin coal fines. During this reporting period, -28 mesh run-of-mine Illinois No. 5 and No. 6 coal samples were processed using a continuous Falcon concentrator having a 10-inch bowl diameter. For the Illinois No. 5 coal sample, the ash content was reduced in the 100 {times} 325 mesh size fraction from about 18% to 8% while achieving a high combustible recovery value of nearly 97%. In addition, the total sulfur content was substantially decreased from 2.6% to 1.7%. Similar results were obtained from the treatment of the Illinois No. 6 coal sample where ash rejections ranged from 40%-70% for a 28 {times} 325 mesh feed having 7% ash. Combustible recovery values from these tests were greater than 87% while treating mass feed rates between 1 to 2 tons/hour. A parametric study found that lower feed solids contents provided marginally lower product ash and total sulfur contents while feed rate and bowl speed appeared to have no significant effect over the range of values tested.

  3. New coal dewatering technology turns sludge to powder

    SciTech Connect (OSTI)

    2009-03-15

    Virginian Tech's College of Engineering's Roe-Hoan Yoon and his group have developed a hyperbaric centrifuge that can dewater coal as fine as talcum powder. Such coal fines presently must be discarded by even the most advanced coal cleaning plants because of their high moisture content. The new technology can be used with the Microcel technology to remove ash, to re-mine the fine coal discarded to impoundments and to help minimize waste generation. Virginia Tech has received $1 million in funding from the US Department of State to also help the Indian coal industry produce a cleaner product. 1 photo.

  4. SPLAT II: An Aircraft Compatible, Ultra-Sensitive, High Precision Instrument for In-Situ Characterization of the Size and Composition of Fine and Ultrafine Particles

    SciTech Connect (OSTI)

    Zelenyuk, Alla; Yang, Juan; Choi, Eric Y.; Imre, Dan G.

    2009-05-01

    The properties of aerosols depend on the size and internal compositions of the individual particles. The vast majority of atmospheric aerosols are smaller than 200 nm, yet the single particle mass spectrometers, the only instruments that can characterize the size and internal compositions of individual particles, typically detect these small particles with extremely low efficiencies. In this paper we describe a new instrument called SPLAT II that provides unparalleled sensitivity to small particles, detecting 100% of particles that are larger than 125 nm and 40% of 100 nm particles. This instrument also brings an increase by a factor of 10 in temporal resolution, sizing up to 500 particles per second and characterizing the composition of up to 100 of them. SPLAT II uses a two-laser, two-step process to evaporate the particles and generate ions, producing high quality, reproducible mass spectra of the refractive and non-refractive aerosol fractions to yield the complete compositions of individual particles. The instrument control board provides for size dependent delays for lasers triggers to eliminate a size dependent hit rate. The mass spectra are recorded with 14-bit vertical resolution and analyzed using custom software packages. The instruments high sizing resolution and sensitivity makes it possible to combine it with the differential mobility analyzer(s) and measure particle size, composition, density, dynamic shape factor, hygroscopicity, and fractal dimension.

  5. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-12-01

    A real-time laser light-reflectivity technique is being used to study simultaneous thermophoretic and inertial influences on the deposition behavior of MgO particles produced via ultrasonic nebulization (submicrometer range). The deposition surface (a concave platinum ribbon) is exposed to a high velocity/temperature jet of alkali sulfate-free combustion products exiting from a seeded (C3[sub 3]H[sub 8]/air) microcombustor (110 cm[sup 3]). The reflectivity data were calibrated against deposition rates obtained from SEM pictures of the target, and were normalized with the nominal particle feed rate, in order to obtain the mass transfer Stanton number, St[sub m], trends depicted in Figure 1. For the submicron (ca. 0.7[mu]m) particles inertial effects appear to set in at Stokes (Stk) numbers of O(10[sup [minus]2]) (an order of magnitude lower than the ones needed for pure'' inertial impaction), affecting significantly the dominant thermophoretic deposition mechanism. A first order (in Stk) theoretical analysis of the problem in which particle inertia is treated as equivalent to pressure diffusion,'' cannot explain the observed dependence of the deposition rate on Stk. We are presently formulating a Lagrangian approach, valid for all values of Stk, in order to interpret these data. In addition, a Single Particle Counter (SPC) and Transit Time Velocimeter (TTV), are being developed, to allow more precise measurements of particle feed rates and velocities.

  6. Coal slurry pipelines: Blach Mesa and future projects

    SciTech Connect (OSTI)

    Brolick, H.J.

    1998-12-31

    Most people in the mining industry have some familiarity with pipelining of minerals in slurry form, however, many may not realize the extent that mineral slurry pipeline transport is used throughout the world. The author is referring to the shipment of the minerals in the raw or concentrate form, not tailings pipelines which are also commonplace in the minerals industry. There are over forty mineral pipelines around the world. The list covers a wide range of minerals, including copper ore concentrate, iron ore concentrate, limestone, phosphate concentrate, kaolin, Gilsonite and gold ore, with only eleven of the mineral pipelines located in the USA. It should be noted that one of the earliest slurry pipelines was a 108 mile coal slurry pipeline in Ohio, which started up in 1957. The pipeline only operated until 1963 when a railroad company literally bought out the transportation contract. This really was the beginning of the unit train concept. Each mineral has specific physical and chemical characteristics to be considered when evaluating transport by pipeline. The processing required at the pipeline origin, as well as at the pipeline termination, are also important factors in determining slurry pipeline feasibility. Transport distance, annual volume, and continuity of shipments are other important factors. One of the most difficult minerals to transport as a slurry is coal because the specific gravity is closer to water than most other minerals. Thus, the fine balance of creating enough fine particles to serve as a carrier for the coarser material, while at the same time having a material that can be economically dewatered is very sensitive and technical designs will vary with types of coal. Additionally, since coal is purchased for its thermal value, excess surface moisture can lower the value of the coal to the customer. One of the most successful slurry pipeline operations, and the only current operating long-distance coal slurry pipeline is the Black Mesa Pipeline System. The Black Mesa Pipeline is a 273 mile (439 km) long, 18-inch (457 mm) coal/water slurry pipeline, originating on the Black Mesa in the Northeastern part of Arizona, USA. The system delivers coal from the Peabody Coal Company`s Black Mesa open pit mine to the Mohave Generating Station which is a 1580 MW steam powered electric generating plant located in Laughlin, Nevada. Black Mesa Pipeline began commercial operation in November, 1970 and has transported in excess of 110,000,000 tons (99,800,000 metric tons) of coal with an availability factor of 99%.

  7. Fluid/particle separation and coal cleaning: Progress, potential advances, and their effects on FGD (flue-gas desulfurization)

    SciTech Connect (OSTI)

    Livengood, C.D.; Doctor, R.D.

    1989-01-01

    Argonne National Laboratory (ANL) has been investigating several approaches to SO{sub 2} and NO{sub x} control that could play significant roles in future emission-control strategies. These techniques include greater application of an existing technology, physical coal cleaning (PCC), as a precombustion complement to FGD, and the combined removal of NO{sub x} and SO{sub 2} in flue-gas cleanup (FGC) systems based on spray drying (a wet/dry process) or in-duct injection of dry sorbents. This paper discusses the results of some of that research with particular attention to the beneficial role of fabric filtration in the dry and wet/dry FGC processes. 7 refs., 5 figs.

  8. Coal Markets

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal Markets Release date: February 8, 2016 | Next release date: February 16, 2016 | Archive Coal Markets Weekly production Dollars per short ton Dollars per mmbtu Average weekly...

  9. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, W.H.; Oblad, A.G.; Shabtai, J.S.

    1994-05-03

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400 C at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1. 1 figures.

  10. Hydrogen production with coal using a pulverization device

    DOE Patents [OSTI]

    Paulson, Leland E. (Morgantown, WV)

    1989-01-01

    A method for producing hydrogen from coal is described wherein high temperature steam is brought into contact with coal in a pulverizer or fluid energy mill for effecting a steam-carbon reaction to provide for the generation of gaseous hydrogen. The high temperature steam is utilized to drive the coal particles into violent particle-to-particle contact for comminuting the particulates and thereby increasing the surface area of the coal particles for enhancing the productivity of the hydrogen.

  11. RESEARCH & DEVELOPMENT TO PREPARE AND CHARACTERIZE ROBUST COAL/BIOMASS MIXTURES FOR DIRECT CO-FEEDING INTO GASIFICATION SYSTEMS

    SciTech Connect (OSTI)

    Felix, Larry; Farthing, William; Hoekman, S. Kent

    2014-12-31

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes. The specific objectives of the project include: • Demonstration of the continuous production of a uniform densified and formed feedstock from loblolly pine (a lignocellulosic, short rotation woody crop) in a hydrothermal carbonization (HTC) process development unit (PDU). • Demonstration that finely divided bituminous coal and HTC loblolly pine can be blended to form 90/10 and 70/30 weight-percent mixtures of coal and HTC biomass for further processing by pelletization and briquetting equipment to form robust weather resistant pellets and/or briquettes suitable for transportation and long term storage. • Characterization of the coal-biomass pellets and briquettes to quantify their physical properties (e.g. flow properties, homogeneity, moisture content, particle size and shape), bulk physical properties (e.g. compressibility, heat transfer and friability) and assess their suitability for use as fuels for commercially-available coal gasifiers. • Perform economic analyses using Aspen-based process simulations to determine the costs for deploying and operating HTC processing facilities for the production of robust coal/biomass fuels suitable for fueling commercially-available coal-fired gasifiers. This Final Project Scientific/Technical Report discusses and documents the project work required to meet each of these objectives.

  12. Influence of viscous deformation at the contact point of primary particles on compaction of alkoxide-derived fine SiO{sub 2} granules under ultrahigh isostatic pressure

    SciTech Connect (OSTI)

    Kamiya, Hidehiro; Suzuki, Hisao; Kato, Daisuke; Jimbo, Genji

    1996-09-01

    Viscous deformation and the adhesion force at the contact point between amorphous silica particles under ultrahigh isostatic pressure (up to 1 GPa) are important in the densification of powder compacts. The amount of viscous deformation and the strength of adhesion force have been changed in the present study by altering the calcination temperature and particle diameter, and the new values have been determined successfully using a diametral compression test. The diameter of spherical and monosized alkoxide-derived silica powders has been controlled within the range of 10--400 nm. Close-packed granules of these powders have been produced by spray drying. Because of viscous deformation, as-spray-died ultrafine silica powders without calcination could be consolidated into highly dense compacts (>74% of theoretical density) by applying ultra-high isostatic pressure (1 GPa). Relatively high temperature in the calcined particles (>400 C) causes viscous deformation at the contact point to disappear almost completely and clearly increases the adhesion force, because of neck growth that has resulted from viscous sintering. At temperatures >200 C, the green density of the calcined powders decreases to 65% of theoretical density, even under 1 GPa pressure. The relationship between green density and viscous deformation in silica particles at the point of contact has been analyzed quantitatively by the Hertz and Rumpf model. The relationship between granule strength and neck growth at the contact point with calcination has been estimated Quantitatively.

  13. Fine Structure Studies in Proton Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure Studies in Proton Emission In order to understand the evolution of single particle wave functions and deformations beyond the proton drip line, a program has been initiated to study fine structure decay in proton emission. Fine structure in the proton emission spectrum allows one not only to define low energy states in the daughter, but from a comparison of the proton energies and partial half-lives, enables determination of the composition of the single-particle proton states in the

  14. Capacity mapping for optimum utilization of pulverizers for coal fired boilers - article no. 032201

    SciTech Connect (OSTI)

    Bhattacharya, C.

    2008-09-15

    Capacity mapping is a process of comparison of standard inputs with actual fired inputs to assess the available standard output capacity of a pulverizer. The base capacity is a function of grindability; fineness requirement may vary depending on the volatile matter (VM) content of the coal and the input coal size. The quantity and the inlet will change depending on the quality of raw coal and output requirement. It should be sufficient to dry pulverized coal (PC). Drying capacity is also limited by utmost PA fan power to supply air. The PA temperature is limited by air preheater (APH) inlet flue gas temperature; an increase in this will result in efficiency loss of the boiler. The higher PA inlet temperature can be attained through the economizer gas bypass, the steam coiled APH, and the partial flue gas recirculation. The PS/coal ratioincreases with a decrease in grindability or pulverizer output and decreases with a decrease in VM. The flammability of mixture has to be monitored on explosion limit. Through calibration, the PA flow and efficiency of conveyance can be verified. The velocities of coal/air mixture to prevent fallout or to avoid erosion in the coal carrier pipe are dependent on the PC particle size distribution. Metal loss of grinding elements inversely depends on the YGP index of coal. Variations of dynamic loading and wearing of grinding elements affect the available milling capacity and percentage rejects. Therefore, capacity mapping in necessary to ensure the available pulverizer capacity to avoid overcapacity or undercapacity running of the pulverizing system, optimizing auxiliary power consumption. This will provide a guideline on the distribution of raw coal feeding in different pulverizers of a boiler to maximize system efficiency and control, resulting in a more cost effective heat rate.

  15. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  16. ATMOSPHERIC AEROSOL SOURCE-RECEPTOR RELATIONSHIPS: THE ROLE OF COAL-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Allen L. Robinson; Spyros N. Pandis; Cliff I. Davidson

    2004-12-01

    This report describes the technical progress made on the Pittsburgh Air Quality Study (PAQS) during the period of March 2004 through August 2004. Significant progress was made this project period on the analysis of ambient data, source apportionment, and deterministic modeling activities. Results highlighted in this report include evaluation of the performance of PMCAMx+ for an air pollution episode in the Eastern US, an emission profile for a coke production facility, ultrafine particle composition during a nucleation event, and a new hybrid approach for source apportionment. An agreement was reached with a utility to characterize fine particle and mercury emissions from a commercial coal fired power. Research in the next project period will include source testing of a coal fired power plant, source apportionment analysis, emission scenario modeling with PMCAMx+, and writing up results for submission as journal articles.

  17. Studies on the reduction kinetics of hematite iron ore pellets with noncoking coals for sponge iron plants

    SciTech Connect (OSTI)

    Kumar, M.; Mohapatra, P.; Patel, S.K.

    2009-07-01

    In the present investigation, fired pellets were made by mixing hematite iron ore fines of -100, -16+18, and -8+10 mesh size in different ratios and studies on their reduction kinetics in Lakhanpur, Orient OC-2 and Belpahar coals were carried out at temperatures ranging from 850{sup o}C to 1000{sup o}C with a view toward promoting the massive utilization of fines in ironmaking. The rate of reduction in all the fired iron ore pellets increased markedly with an increase in temperature up to 1000{sup o}C, and it was more intense in the first 30min. The values of activation energy, calculated from integral and differential approaches, for the reduction of fired pellets (prepared from iron ore fines of -100 mesh size) in coals were found to be in the range 131-148 and 130-181 kJ mol{sup -1} (for =0.2 to 0.8), indicating the process is controlled by a carbon gasification reaction. The addition of selected larger size particles in the matrix of -100 mesh size fines up to the extent studied decreased the activation energy and slightly increased the reduction rates of resultant fired pellets. In comparison to coal, the reduction of fired pellets in char was characterized by significantly lower reduction rates and higher activation energy.

  18. Vacuum pyrolyzed tire oil as a coal solvent

    SciTech Connect (OSTI)

    Orr, E.C.; Shi, Y.; Ji, Q.

    1995-12-31

    Coal liquefaction is highly dependent upon the type of coal liquefaction solvent used. The solvent must readily solubilize the coal and must act as an effective hydrogen donor or shuttler. Oil derived from the vacuum pyrolysis of used rubber tires has recently been used as a coal solvent with good conversion of coal to liquids in a hydrogen atmosphere. All experiments were completed in shaken tubing reactors at 450{degrees}C utilizing a bituminous coal. Results show the effectiveness of the pyrolyzed tire oil as a coal liquefaction solvent depends upon hydrogen pressure. Electron probe microanalysis data reveal good dispersion of the molybdenum catalyst in coal particles taken from liquefaction experiments.

  19. Advanced Fine Particulate Characterization Methods

    SciTech Connect (OSTI)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and sunflower hulls for the biomass material to be carbonized. The ability to remove mercury from a bituminous coal's derived flue gas was low. Removals of only 15% were attained while injecting 6 lb/Macf of activated carbon upstream of an electrostatic precipitator. Poisoning of sites on the activated carbon by SO{sub 2} and SO{sub 3} contributed to the poor mercury capture performance.

  20. Screen bowl centrifuge: a high-efficiency particle size separator

    SciTech Connect (OSTI)

    Mohanty, M.K.; Zhang, B.; Khanna, N.; Palit, A.; Dube, B.

    2008-05-15

    Over the years, screen bowl centrifuges have been widely used for dewatering fine coal in coal preparation plants in the United States and elsewhere. It is generally recognized in the engineering and scientific communities that screen bowl centrifuges provide some degree of particle size separation while dewatering fine coal in a common application. However, the extent of differential partitioning of coarse and fine particles achievable by a screen bowl centrifuge has not been systematically studied in the past. The present investigation was aimed at conducting a parametric study using a statistically designed experimental program to better understand and optimize the size classification performance of a screen bowl centrifuge. A continuously operating screen bowl centrifuge having a bowl diameter of 0.5 m was used for this study at the Illinois Coal Development Park. Three key operating parameters, i.e., feed flow rate, feed solid content and pool depth, were varied to conduct a total of 17 experiments using a three-level factorial test matrix. Some of the best size separation performances achieved in this study may be described as having an imperfection value of 0.13 at an effective separation size (d(50c)) of 38 mu m and an imperfection value of 0.27 at an effective separation size (d(50c)) of 2.8 mu m. Due to an effective separation of ultrafine high ash materials, the ash content of the screen bowl feed was reduced from 22.3% to a minimum of 8.84% with a combustible recovery of 84.1% and an ash rejection of 71.6%. A higher combustible recovery of 92.1% was achieved at a product ash content of 12.5% with a d(50c) of 2.8 mu m and imperfection of 0.27.

  1. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal In response to concerns of climate change, the United States is contemplating a complete and rapid transformation of the way it both produces and consumes energy to significantly reduce its carbon emissions. The integrated Coal Program focuses on retaining the benefits of continuing to use coal to produce electric power. This strategy can help us depend less on foreign sources of energy, respond to the world's growing climate concerns, and compete economically. It also will ensure that our

  2. Coal Markets

    Gasoline and Diesel Fuel Update (EIA)

    Coal Markets Release date: March 14, 2016 | Next release date: March 21, 2016 | Archive Coal Markets Weekly production Dollars per short ton Dollars per mmbtu Average weekly coal commodity spot prices dollars per short ton Week ending Week ago change Central Appalachia 12,500 Btu, 1.2 SO2 Northern Appalachia 13,000 Btu, < 3.0 SO2 Illinois Basin 11,800 Btu, 5.0 SO2 Powder River Basin 8,800 Btu, 0.8 SO2 Uinta Basin 11,700 Btu, 0.8 SO2 Source: With permission, SNL Energy Note: Coal prices shown

  3. Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report

    SciTech Connect (OSTI)

    Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S.

    1989-04-28

    This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

  4. Kinetics of coal pyrolysis

    SciTech Connect (OSTI)

    Seery, D.J.; Freihaut, J.D.; Proscia, W.M. ); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. ); Jenkins, R.; Mallin, J.; Espindola-Merin, B. ); Essenhigh, R.; Misra, M.K. )

    1989-07-01

    This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

  5. Compressive behavior of fine sand.

    SciTech Connect (OSTI)

    Martin, Bradley E.; Kabir, Md. E.; Song, Bo; Chen, Wayne

    2010-04-01

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  6. Influence of combustion conditions and coal properties on physical properties of fly ash generated from pulverized coal combustion

    SciTech Connect (OSTI)

    Hiromi Shirai; Hirofumi Tsuji; Michitaka Ikeda; Toshinobu Kotsuji

    2009-07-15

    To develop combustion technology for upgrading the quality of fly ash, the influences of the coal properties, such as the size of pulverized coal particles and the two-stage combustion ratio during the combustion, on the fly ash properties were investigated using our test furnace. The particle size, density, specific surface area (obtained by the Blaine method), and shape of fly ash particles of seven types of coal were measured. It was confirmed that the size of pulverized coal particles affects the size of the ash particles. Regarding the coal properties, the fuel ratio affected the ash particle size distribution. The density and shape of the ash particles strongly depended on their ash size. Our results indicated that the shape of the ash particles and the concentration of unburned carbon affected the specific surface area. The influence of the two-stage combustion ratio was limited. 8 refs., 13 figs., 3 tabs.

  7. EIA -Quarterly Coal Distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Coal Distribution Home > Coal> Quarterly Coal Distribution Back Issues Quarterly Coal Distribution Archives Release Date: March 9, 2016 Next Release Date: May 2016 The Quarterly Coal Distribution Report (QCDR) provides detailed quarterly data on U.S. domestic coal distribution by coal origin, coal destination, mode of transportation and consuming sector. All data are preliminary and superseded by the final Coal Distribution - Annual Report. Year/Quarters By origin State By destination

  8. Primary coal crushers grow to meet demand

    SciTech Connect (OSTI)

    Fiscor, S.

    2009-09-15

    Mine operators look for more throughput with less fines generation in primary crushers (defined here as single role crushers and two stage crushers). The article gives advice on crusher selection and application. Some factors dictating selection include the desired product size, capacity, Hard Grove grindability index, percentage of rock to be freed and hardness of that rock. The hardness of coal probably has greatest impact on product fineness. 2 refs., 1 fig., 1 tab.

  9. Coal Distribution Database, 2008

    U.S. Energy Information Administration (EIA) Indexed Site

    Processing Coal Plants and Commercial and Institutional Coal Users" and Form EIA-7A, "Coal Production and Preparation Report." Appendix A Assigning Missing Data to EIA-923...

  10. Coal industry annual 1994

    SciTech Connect (OSTI)

    1995-10-01

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  11. Coal Market Module

    Gasoline and Diesel Fuel Update (EIA)

    power generation, industrial steam generation, coal-to-liquids production, coal coke manufacturing, residentialcommercial consumption, and coal exports) within the CMM. By...

  12. Mechanical properties of reconstituted Australian black coal

    SciTech Connect (OSTI)

    Jasinge, D.; Ranjith, P.G.; Choi, S.K.; Kodikara, J.; Arthur, M.; Li, H.

    2009-07-15

    Coal is usually highly heterogeneous. Great variation in properties can exist among samples obtained even at close proximity within the same seam or within the same core sample. This makes it difficult to establish a correlation between uniaxial compressive strength (UCS) and point load index for coal. To overcome this problem, a method for making reconstituted samples for laboratory tests was developed. Samples were made by compacting particles of crushed coal mixed with cement and water. These samples were allowed to cure for four days. UCS and point load tests were performed to measure the geomechanical properties of the reconstituted coal. After four days curing, the average UCS was found to be approximately 4 MPa. This technical note outlines some experimental results and correlations that were developed to predict the mechanical properties of the reconstituted black coal samples. By reconstituting the samples from crushed coal, it is hoped that the samples will retain the important mechanical and physicochemical properties of coal, including the swelling, fluid transport, and gas sorption properties of coal. The aim is to be able to produce samples that are homogeneous with properties that are highly reproducible, and the reconstituted coal samples can be used for a number of research areas related to coal, including the long-term safe storage of CO{sub 2} in coal seams.

  13. Keystone coal industry manual

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The 1994 Keystone Coal Industry Manual is presented. Keystone has served as the one industry reference authority for the many diverse organizations concerned with the supply and utilization of coal in the USA and Canada. Through the continuing efforts of coal producers, buyers, users, sellers, and equipment designers and manufacturers, the coal industry supplies an abundant and economical fuel that is indispensable in meeting the expanding energy needs of North America. The manual is divided into the following sections: coal sales companies, coal export, transportation of coal, consumer directories, coal associations and groups, consulting and financial firms, buyers guide, industry statistics and ownership, coal preparation, coal mine directory, and coal seams.

  14. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    Annual Coal Distribution Report 2010 U.S. Energy Information Administration | Annual Coal Distribution Report 2010 Alabama ...

  15. EIA - Coal Distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Annual Coal Distribution Report > Annual Coal Distribution Archives Annual Coal Distribution Archive Release Date: February 17, 2011 Next Release Date: December 2011 Domestic coal distribution by origin State, destination State, consumer category, method of transportation; foreign coal distribution by major coal-exporting state and method of transportation; and domestic and foreign coal distribution by origin state. Year Domestic and foreign distribution of U.S. coal by State of origin

  16. Preparation of Clay Brick Using Coal Waste

    SciTech Connect (OSTI)

    Yoo, Jung W.; Jung, Jin H.; Kim, Jae M.; Lee, Sung M.; Kim, Hyung T.

    2004-03-31

    A great deal of coal waste produced during the development of a mine was accumulated around the mine, which caused many problems such as traffic, acid mine drainage and damage of forest and scenery. Carbon in the coal waste helps calcination of the brick even at low temperature. Considering the reuse of natural waste and energy saving, clay brick was prepared using coal waste under various conditions, including particle size, amount of coal waste mixed, calcination temperature and pressing pressure. The specimens were characterized by XRD, SEM and TG-DTA and interpreted in terms of water absorption and compressive strength.

  17. Research on fundamental aspects of inorganic particle deposition on coal-fired equipment. Final technical report, 6 September 1990--31 October 1994

    SciTech Connect (OSTI)

    Rosner, D.E.

    1995-01-01

    We review results of our recent DOE-PETC research program on the deposition dynamics of combustion-generated particles in power production technologies. We outline and illustrate the results of recently developed methods to predict total surface deposition rates and associated convective heat transfer reductions for targets exposed to a distribution of particles suspended in a mainstream. Our methods combine the essential features of recently developed single particle sticking probability laws with correlations of the inertial impaction of particles on targets in high Reynolds number cross-flow, to develop formulae and ``universal`` graphs which provide the dependence of particle deposition rates, and associated reductions in convective heat transfer, on such system parameters as mainstream velocity, mean suspended particle size and target size. The deposition rate/deposit microstructue/properties prediction and correlation procedures illustrated be incorporated into improved ``fouling propensity indices,`` to motivate, evaluate and implement ``ruggedization`` and/or fouling reduction strategies, and/or incorporated (as subroutines) into more ``comprehensive`` CFD models of an entire power plant.

  18. Effects of pulverized coal fly-ash addition as a wet-end filler in papermaking

    SciTech Connect (OSTI)

    Sinha, A.S.K.

    2008-09-15

    This experimental study is based on the innovative idea of using pulverized coal fly ash as a wet-end filler in papermaking. This is the first evaluation of the possible use of fly ash in the paper industry. Coal-based thermal power plants throughout the world are generating fly ash as a solid waste product. The constituents of fly ash can be used effectively in papermaking. Fly ash has a wide variation in particle size, which ranges from a few micrometers to one hundred micrometers. Fly ash acts as an inert material in acidic, neutral, and alkaline papermaking processes. Its physical properties such as bulk density (800-980 kg/m{sup 3}), porosity (45%-57%), and surface area (0.138-2.3076 m{sup 2}/g) make it suitable for use as a paper filler. Fly ash obtained from thermal power plants using pulverized coal was fractionated by a vibratory-sieve stack. The fine fraction with a particle size below 38 micrometers was used to study its effect on the important mechanical-strength and optical properties of paper. The effects of fly-ash addition on these properties were compared with those of kaolin clay. Paper opacity was found to be much higher with fly ash as a filler, whereas brightness decreased as the filler percentage increased Mechanical strength properties of the paper samples with fly ash as filler were superior to those with kaolin clay.

  19. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  20. Black Bear Prep plant replaces high-frequency screens with fine wire sieves

    SciTech Connect (OSTI)

    Barbee, C.J.; Nottingham, J.

    2007-12-15

    At the Black Bear prep plant (near Wharncliffe, WV, USA) the clean coal from the spirals traditionally reported to high-frequency screens, which removed high-ash clay fines. Screens have inherent inefficiencies that allow clean coal to report to the screen underflow. The goal of this project was to capture the maximum amount of spiral clean coal while still removing the high-ash clay material found in the spiral product. The reduction of the circulating load and plant downtime for unscheduled maintenance were projected as additional benefits. After the plant upgrade, the maintenance related to the high frequency screens was eliminated and an additional 2.27 tons per hour (tph) of fine coal was recovered, which resulted in a payback period of less than one year. The article was adapted from a paper presented at Coal Prep 2007 in April 2007, Lexington, KY, USA. 1 ref., 1 fig., 1 tab.

  1. Development of dense-phase pneumatic transport of coal

    SciTech Connect (OSTI)

    Horisaka, S.; Ikemiya, H.; Kajiwara, T.

    1996-12-31

    Dense phase pneumatic transport system has been developed to reduce entrained particles as is seen in the belt conveyor system. High mass flow rate and dense phase (Loading ratio = 50--100kg-coal/kg-N{sub 2}) transport has been achieved by applying this plug flow system to pneumatic conveying of coal (Average particle diameter = 2.5 mm).

  2. The fate of alkali species in advanced coal conversion systems

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  3. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    SciTech Connect (OSTI)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles. It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.

  4. Coal industry annual 1997

    SciTech Connect (OSTI)

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  5. Coal industry annual 1996

    SciTech Connect (OSTI)

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  6. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  7. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  8. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li

    2006-07-15

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  9. Vacuum pyrolyzed tire oil as a coal solvent

    SciTech Connect (OSTI)

    Orr, E.C.; Shi, Yanlong; Ji, Qin; Anderson, L.L.; Eyring, E.M.

    1995-12-31

    Recent interest in coprocessing coal with hydrogen rich waste materials in order to produce liquid transportation fuels has given rise to interesting twists on standard coal liquefaction. In general, coprocessing coal with a waste material has been approached with the idea that the waste material would be mixed with the coal under liquefaction conditions with little or no preliminary processing of the waste material other than shredding into smaller size particles. Mixing the waste material with the coal would occur in the primary stage of liquefaction. The primary stage would accomplish the dissolution of the coal and breakdown of the waste material. The products would then be introduced into the secondary stage where upgrading of product would occur. This paper describes the usefulness of oil derived from pyrolysis of waste rubber tires as a reactant in coal coprocessing or coal liquefaction.

  10. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  11. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  12. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    Destination State ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 Alabama _____________________________________________________________________________________________________________________________________ Table DS-1. Domestic coal

  13. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    Origin State ~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 U.S. Energy Information Administration | Quarterly Coal Distribution Report 1st Quarter 2012 Alabama ___________________________________________________________________________________________________________________________________ Table OS-1. Domestic coal

  14. Controlling formation fines at their sources to maintain well productivity

    SciTech Connect (OSTI)

    Nguyen, P.D.; Weaver, J.D.; Rickman, R.D.; Dusterhoft, R.G.; Parker, M.A.

    2007-05-15

    Migration of formation fines has been shown to cause production decline in many wells. Despite the availability of new downhole tools for use in well stimulation and completion, the ability to sustain desired production levels is often plagued with fines migration problems. The solution to this problem is appropriate treatment to mitigate fines migration at its source. This paper describes the use of an ultra-thin tackifying agent (UTTA) for stabilizing fines in high-rate producing or injection wells. This UTTA is applied as part of an initial prepad in fracturing or gravel-packing operations, as a remedial treatment, or as a post-treatment following acid fracturing or matrix acidizing treatments. The primary purpose of UTTA application is to immobilize formation fines so that they will not detach, migrate with flowing fluids, plug the pore channels, and reduce the flow path permeability. Results of laboratory testing indicate that the UTTA system is applicable to most types of formation fines, including coals, sandstones, and carbonates. Once injected into the formation matrix or proppant pack, the UTTA forms a thin film on formation surfaces, encapsulating the fines. Capillary action helps pull the tackifier into the contact points, fixing the particulate in place without plugging the pore throat. The UTTA does not require a shut-in time after its application. The thin film tackifier does not harden, but remains flexible, enhancing the ability of a formation to withstand stress cycling and allowing the formation to handle high shear stress during high flow rates.

  15. Coal and Coal-Biomass to Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Coal-Biomass to Liquids Turning coal into liquid fuels like gasoline, diesel and jet fuel, with biomass to reduce carbon dioxide emissions, is the main goal of the Coal and Coal-Biomass to Liquids program. The program also aims to reduce the cost of these low-emission fuels, and will take advantage of carbon capture and sequestration technologies to further reduce greenhouse gas emissions. Other Coal and Coal-Biomass to Liquids (C&CBTL) Program Activities: The C&CBTL Program

  16. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  17. Method for reducing NOx during combustion of coal in a burner

    DOE Patents [OSTI]

    Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

    2008-04-15

    An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

  18. Coal Research FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Research FAQs faq-header-big.jpg COAL RESEARCH Q: Why is coal research needed? A: The energy resources that currently fuel the Nation's economy are approximately 82 percent fossil-based, with coal playing a significant role. All segments of U.S. society rely on America's existing multibillion-dollar investment in its highly reliable and affordable coal-based energy infrastructure. In the power-generation industry, coal is affordably producing approximately 40 percent of U.S. electricity.

  19. Synthesis of fine-grained TATB

    DOE Patents [OSTI]

    Lee, Kien-Yin (Santa Fe, NM); Kennedy, James E. (Santa Fe, NM)

    2003-04-15

    A method for producing fine-grained triamino-trinitrobenzene (TATB) powders having improved detonation-spreading performance and hence increased shock sensitivity when compared with that for ultrafine TATB is described. A single-step, sonochemical amination of trichloro-trinitrobenzene using ammonium hydroxide solution in a sealed vessel yields TATB having approximately 6 .mu.m median particle diameter and increased shock sensitivity.

  20. Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (S. Somerville, NJ)

    1989-01-01

    A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

  1. NETL: Coal Gasification Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasification Systems Coal Gasification is a process that can turn coal into clean power, chemicals, hydrogen and transportation fuels, and can be used to capture the carbon from ...

  2. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 1st Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  3. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 4th Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  4. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 3rd Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  5. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 3rd Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  6. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 4th Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  7. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 3rd Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  8. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 4th Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  9. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 2nd Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  10. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 3rd Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  11. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 4th Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  12. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 1st Quarter 2011 Origin: Alabama (thousand short tons) Coal Destination State...

  13. Coal Distribution Database, 2006

    U.S. Energy Information Administration (EIA) Indexed Site

    Domestic Distribution of U.S. Coal by Origin State, Consumer, Destination and Method of Transportation, 2009 Final February 2011 2 Overview of 2009 Coal Distribution Tables...

  14. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 1st Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  15. By Coal Origin State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table OS-1. Domestic coal distribution, by origin State, 2nd Quarter 2010 Origin: Alabama (thousand short tons) Coal Destination State...

  16. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 1st Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  17. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 2nd Quarter 2010 Destination: Alabama (thousand short tons) Coal Origin State...

  18. By Coal Destination State

    U.S. Energy Information Administration (EIA) Indexed Site

    Table DS-1. Domestic coal distribution, by destination State, 2nd Quarter 2011 Destination: Alabama (thousand short tons) Coal Origin State...

  19. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

    1995-01-01

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  20. Pneumatic solids feeder for coal gasification reactor

    SciTech Connect (OSTI)

    Notestein, J.E.; Halow, J.S.

    1991-12-31

    This invention is comprised of a pneumatic feeder system for a coal gasification reactor which includes one or more feeder tubes entering the reactor above the level of the particle bed inside the reactor. The tubes are inclined downward at their outer ends so that coal particles introduced into the tubes through an aperture at the top of the tubes slides downward away from the reactor and does not fall directly into the reactor. Pressurized gas introduced into, or resulting from ignition of recycled combustible gas in a chamber adjacent to the tube ends, propels the coal from the tube into the reactor volume and onto the particle bed. Leveling of the top of the bed is carried out by a bladed rotor mounted on the reactor stirring shaft. Coal is introduced into the tubes from containers above the tubes by means of rotary valves placed across supply conduits. This system avoids placement of feeder hardware in the plenum above the particle bed and keeps the coal from being excessively heated prior to reaching the particle bed.

  1. Coal liquefaction

    DOE Patents [OSTI]

    Schindler, Harvey D.

    1985-01-01

    In a two-stage liquefaction wherein coal, hydrogen and liquefaction solvent are contacted in a first thermal liquefaction zone, followed by recovery of an essentially ash free liquid and a pumpable stream of insoluble material, which includes 850.degree. F.+ liquid, with the essentially ash free liquid then being further upgraded in a second liquefaction zone, the liquefaction solvent for the first stage includes the pumpable stream of insoluble material from the first liquefaction stage, and 850.degree. F.+ liquid from the second liquefaction stage.

  2. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  3. ATMOSPHERIC AEROSOL SOURCE-RECEPTOR RELATIONSHIPS: THE ROLE OF COAL-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Allen L. Robinson; Spyros N. Pandis; Cliff I. Davidson

    2004-04-01

    This report describes the technical progress made on the Pittsburgh Air Quality Study (PAQS) during the period of September 2003 through February 2004. Significant progress was made this project period on the analysis of ambient data, source apportionment, and deterministic modeling activities. Results highlighted in this report include chemical fractionation of the organic fraction to quantify the ratio of organic mass to organic carbon (OM/OC). The average OM/OC ratio for the 31 samples analyzed so far is 1.89, ranging between 1.62 and 2.53, which is consistent with expectations for an atmospherically processed regional aerosol. Analysis of the single particle data reveals that a on a particles in Pittsburgh consist of complex mixture of primary and secondary components. Approximately 79% of all particles measured with the instrument containing some form of carbon, with Carbonaceous Ammonium Nitrate (54.43%) being the dominant particle class. PMCAMx predictions were compared with data from more than 50 sites of the STN network located throughout the Eastern United States for the July 2001 period. OC and sulfate concentrations predicted by PMCAMx are within {+-}30% of the observed concentration at most of these sites. Spherical Aluminum Silicate particle concentrations (SAS) were used to estimate the contribution of primary coal emissions to fine particle levels at the central monitoring site. Primary emissions from coal combustion contribute on average 0.44 {+-} 0.3 {micro}g/m{sup 3} to PM{sub 2.5} at the site or 1.4 {+-} 1.3% of the total PM{sub 2.5} mass. Chemical mass balance analysis was performed to apportion the primary organic aerosol. About 70% of the primary OC emissions are from vehicular sources, with the gasoline contribution being on average three times greater than the diesel emissions in the summer.

  4. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, Walter A. (Spring, TX); Gorski, Alan (Lovington, NM); Jaehnig, Leo J. (New Orleans, LA); Moskal, Clifford J. (Oklahoma City, OK); Naylor, Joseph D. (Houston, TX); Parimi, Krishnia (Allison Park, PA); Ward, John V. (Arvada, CO)

    1984-01-03

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

  5. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

    1984-01-03

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

  6. Preparation for upgrading western subbituminous coal

    SciTech Connect (OSTI)

    Grimes, R.W.; Cha, C.Y.; Sheesley, D.C.

    1990-11-01

    The objective of this project was to establish the physical and chemical characteristics of western coal and determine the best preparation technologies for upgrading this resource. Western coal was characterized as an abundant, easily mineable, clean, low-sulfur coal with low heating value, high moisture, susceptibility to spontaneous ignition, and considerable transit distances from major markets. Project support was provided by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The research was conducted by the Western Research Institute, (WRI) in Laramie, Wyoming. The project scope of work required the completion of four tasks: (1) project planning, (2) literature searches and verbal contacts with consumers and producers of western coal, (3) selection of the best technologies to upgrade western coal, and (4) identification of research needed to develop the best technologies for upgrading western coals. The results of this research suggest that thermal drying is the best technology for upgrading western coals. There is a significant need for further research in areas involving physical and chemical stabilization of the dried coal product. Excessive particle-size degradation and resulting dustiness, moisture reabsorption, and high susceptibility to spontaneous combustion are key areas requiring further research. Improved testing methods for the determination of equilibrium moisture and susceptibility to spontaneous ignition under various ambient conditions are recommended.

  7. System for utilizing oil shale fines

    DOE Patents [OSTI]

    Harak, Arnold E.

    1982-01-01

    A system is provided for utilizing fines of carbonaceous materials such as particles or pieces of oil shale of about one-half inch or less diameter which are rejected for use in some conventional or prior surface retorting process, which obtains maximum utilization of the energy content of the fines and which produces a waste which is relatively inert and of a size to facilitate disposal. The system includes a cyclone retort (20) which pyrolyzes the fines in the presence of heated gaseous combustion products, the cyclone retort having a first outlet (30) through which vapors can exit that can be cooled to provide oil, and having a second outlet (32) through which spent shale fines are removed. A burner (36) connected to the spent shale outlet of the cyclone retort, burns the spent shale with air, to provide hot combustion products (24) that are carried back to the cyclone retort to supply gaseous combustion products utilized therein. The burner heats the spent shale to a temperature which forms a molten slag, and the molten slag is removed from the burner into a quencher (48) that suddenly cools the molten slag to form granules that are relatively inert and of a size that is convenient to handle for disposal in the ground or in industrial processes.

  8. Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal Coal Coal Coal is the largest domestically produced source of energy in America and is used to generate a significant chunk of our nation's electricity. The Energy Department is working to develop technologies that make coal cleaner, so we can ensure it plays a part in our clean energy future. The Department is also investing in development of carbon capture, utilization and storage (CCUS) technologies, also referred to as carbon capture, utilization and sequestration. Featured Energy

  9. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  10. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  11. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    SciTech Connect (OSTI)

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  12. Process for removal of hazardous air pollutants from coal

    DOE Patents [OSTI]

    Akers, David J. (Indiana, PA); Ekechukwu, Kenneth N. (Silver Spring, MD); Aluko, Mobolaji E. (Burtonsville, MD); Lebowitz, Howard E. (Mountain View, CA)

    2000-01-01

    An improved process for removing mercury and other trace elements from coal containing pyrite by forming a slurry of finely divided coal in a liquid solvent capable of forming ions or radicals having a tendency to react with constituents of pyrite or to attack the bond between pyrite and coal and/or to react with mercury to form mercury vapors, and heating the slurry in a closed container to a temperature of at least about 50.degree. C. to produce vapors of the solvent and withdrawing vapors including solvent and mercury-containing vapors from the closed container, then separating mercury from the vapors withdrawn.

  13. Prestigious Coal-Fired Project of the Year Award Goes to Plant

    Energy Savers [EERE]

    Demonstrating Innovative DOE-Funded Technology | Department of Energy Prestigious Coal-Fired Project of the Year Award Goes to Plant Demonstrating Innovative DOE-Funded Technology Prestigious Coal-Fired Project of the Year Award Goes to Plant Demonstrating Innovative DOE-Funded Technology December 16, 2010 - 12:00pm Addthis Washington, DC - An innovative project demonstrating DryFining™ technology, a more cost-effective way to control coal-based power plant emissions while improving fuel

  14. Evaluation of coal-mineral association and coal cleanability by using SEM-based automated image analysis

    SciTech Connect (OSTI)

    Straszheim, W.E.; Younkin, K.A.; Markuszewski, R. ); Smith, F.J. )

    1988-06-01

    A technique employing SEM-based automated image analysis (AIA) has been developed for assessing the association of mineral particles with coal, and thus the cleanability of that coal, when the characteristics of the separation process are known. Data resulting from AIA include the mineral distribution by particle size, mineral phase, and extent of association with coal. This AIA technique was applied to samples of -325 mesh (-44 ..mu..m) coal from the Indiana No. 3, Upper Freeport, and Sunnyside (UT) seams. The coals were subjected to cleaning by float-sink separations at 1.3, 1.4, 1.6, and 1.9 specific gravity and by froth flotation. For the three coals, the float-sink procedure at a given specific gravity produced different amounts of clean coal, but with similar ash content. Froth flotation removed much less ash, yielding a product ash content of --8% for the Upper Freeport coal, regardless of recovery, while reducing the ash content to less than 5% for the other two coals. The AIA results documented significantly more association of minerals with the Upper Freeport coal, which thus led to the poor ash reduction.

  15. Interpretation of Wild 2 Dust Fine Structure: Comparison of Stardust Aluminium Foil Craters to the Three-Dimensional Shape of Experimental Impacts by Artificial Aggregate Particles and Meteorite Powders

    SciTech Connect (OSTI)

    Kearsley, A T; Burchell, M J; Price, M C; Graham, G A; Wozniakiewicz, P J; Cole, M J; Foster, N J; Teslich, N

    2009-12-10

    New experimental results show that Stardust crater morphology is consistent with interpretation of many larger Wild 2 dust grains being aggregates, albeit most of low porosity and therefore relatively high density. The majority of large Stardust grains (i.e. those carrying most of the cometary dust mass) probably had density of 2.4 g cm{sup -3} (similar to soda-lime glass used in earlier calibration experiments) or greater, and porosity of 25% or less, akin to consolidated carbonaceous chondrite meteorites, and much lower than the 80% suggested for fractal dust aggregates. Although better size calibration is required for interpretation of the very smallest impacting grains, we suggest that aggregates could have dense components dominated by {micro}m-scale and smaller sub-grains. If porosity of the Wild 2 nucleus is high, with similar bulk density to other comets, much of the pore-space may be at a scale of tens of micrometers, between coarser, denser grains. Successful demonstration of aggregate projectile impacts in the laboratory now opens the possibility of experiments to further constrain the conditions for creation of bulbous (Type C) tracks in aerogel, which we have observed in recent shots. We are also using mixed mineral aggregates to document differential survival of pristine composition and crystalline structure in diverse fine-grained components of aggregate cometary dust analogues, impacted onto both foil and aerogel under Stardust encounter conditions.

  16. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  17. Coal feed lock

    DOE Patents [OSTI]

    Pinkel, I. Irving (Fairview Park, OH)

    1978-01-01

    A coal feed lock is provided for dispensing coal to a high pressure gas producer with nominal loss of high pressure gas. The coal feed lock comprises a rotor member with a diametral bore therethrough. A hydraulically activated piston is slidably mounted in the bore. With the feed lock in a charging position, coal is delivered to the bore and then the rotor member is rotated to a discharging position so as to communicate with the gas producer. The piston pushes the coal into the gas producer. The rotor member is then rotated to the charging position to receive the next load of coal.

  18. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  19. International perspectives on coal preparation

    SciTech Connect (OSTI)

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  20. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  1. Indonesian coal mining

    SciTech Connect (OSTI)

    2008-11-15

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  2. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  3. Hydrogen Production: Coal Gasification

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically through the process of coal gasification with carbon capture, utilization, and storage.

  4. Annual Coal Report

    Reports and Publications (EIA)

    2016-01-01

    Provides information about U.S. coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience, including Congress, federal and state agencies, the coal industry, and the general public.

  5. Coal Distribution Database, 2008

    U.S. Energy Information Administration (EIA) Indexed Site

    4Q 2009 April 2010 Quarterly Coal Distribution Table Format and Data Sources 4Q 2009 In keeping with EIA's efforts to increase the timeliness of its reports, this Quarterly Coal...

  6. Coal Distribution Database, 2008

    U.S. Energy Information Administration (EIA) Indexed Site

    3Q 2009 February 2010 Quarterly Coal Distribution Table Format and Data Sources 3Q 2009 In keeping with EIA's efforts to increase the timeliness of its reports, this Quarterly Coal...

  7. Coal gasification apparatus

    DOE Patents [OSTI]

    Nagy, Charles K. (Monaca, PA)

    1982-01-01

    Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

  8. Method for fluorinating coal

    DOE Patents [OSTI]

    Huston, John L. (Skokie, IL); Scott, Robert G. (Westmont, IL); Studier, Martin H. (Downers Grove, IL)

    1978-01-01

    Coal is fluorinated by contact with fluorine gas at low pressure. After pial fluorination, when the reaction rate has slowed, the pressure is slowly increased until fluorination is complete, forming a solid fluorinated coal of approximate composition CF.sub.1.55 H.sub.0.15. The fluorinated coal and a solid distillate resulting from vacuum pyrolysis of the fluorinated coal are useful as an internal standard for mass spectrometric unit mass assignments from about 100 to over 1500.

  9. Coal production 1989

    SciTech Connect (OSTI)

    Not Available

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  10. Annual Coal Distribution Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Annual Coal Distribution Report Release Date: April 16, 2015 | Next Release Date: March 2016 | full report | Revision/Correction Revision to the Annual Coal Distribution Report 2013 data The 2013 Annual Coal Distribution Report has been republished to include final 2013 electric power sector data as well as domestic and foreign distribution data. Contact:

  11. Coal Combustion Products

    Broader source: Energy.gov [DOE]

    Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the largest segment of U.S. electricity generation (45 percent in 2010), finding a sustainable solution for CCPs is an important environmental challenge.

  12. Rate of coal devolatilization in iron and steelmaking processes

    SciTech Connect (OSTI)

    Sampaio, R.S.; Rio Doce, C.V. do; Fruehan, R.J.; Ozturk, B. . Center for Iron and Steel Making Research)

    1991-01-01

    The devolatilization of coal particles under ironmaking and steelmaking conditions was studied. A new experimental technique was developed to measure the rates of devolatilization. A unique method was used to prepare coal particles based on thick coal bands rich in a given maceral group. Experiments with these single particles gave good reproducibility. The rates of devolatilization for all coal types from low to high rank coals were measured in the gaseous atmosphere and within the slag phase. Real time x-ray images were taken for high volatile, low volatile and anthracite coals devolatilizing in a molten smelting slag. The rate in terms of percentage devolatilization were relatively independent of coal type and a small function of furnace temperature at high heating rates and temperatures studied. The rates depended on particle size and heating rates. The results were consistent with internal transport controlled processes primarily heat transfer. Furthermore the rates were the same in the gas and slag phase which is consistent with heat transfer control.

  13. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    SciTech Connect (OSTI)

    Adams, Bradley; Davis, Kevin; Senior, Constance; Shim, Hong Shim; Otten, Brydger; Fry, Andrew; Wendt, Jost; Eddings, Eric; Paschedag, Alan; Shaddix, Christopher; Cox, William; Tree, Dale

    2013-09-30

    Reaction Engineering International (REI) managed a team of experts from University of Utah, Siemens Energy, Praxair, Vattenfall AB, Sandia National Laboratories, Brigham Young University (BYU) and Corrosion Management Ltd. to perform multi-scale experiments, coupled with mechanism development, process modeling and CFD modeling, for both applied and fundamental investigations. The primary objective of this program was to acquire data and develop tools to characterize and predict impacts of CO{sub 2} flue gas recycle and burner feed design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) inherent in the retrofit of existing coal-fired boilers for oxy-coal combustion. Experimental work was conducted at Sandia National Laboratories’ Entrained Flow Reactor, the University of Utah Industrial Combustion Research Facility, and Brigham Young University. Process modeling and computational fluid dynamics (CFD) modeling was performed at REI. Successful completion of the project objectives resulted in the following key deliverables: 1) Multi-scale test data from 0.1 kW bench-scale, 100 kW and 200 kW laboratory-scale, and 1 MW semi-industrial scale combustors that describe differences in flame characteristics, fouling, slagging and corrosion for coal combustion under air-firing and oxygen-firing conditions, including sensitivity to oxy-burner design and flue gas recycle composition. 2) Validated mechanisms developed from test data that describe fouling, slagging, waterwall corrosion, heat transfer, char burnout and sooting under coal oxy-combustion conditions. The mechanisms were presented in a form suitable for inclusion in CFD models or process models. 3) Principles to guide design of pilot-scale and full-scale coal oxy-firing systems and flue gas recycle configurations, such that boiler operational impacts from oxy-combustion retrofits are minimized. 4) Assessment of oxy-combustion impacts in two full-scale coal-fired utility boiler retrofits based on computational fluid dynamics (CFD) modeling of air-fired and oxygen-fired operation. This research determined that it is technically feasible to retrofit the combustion system in an air-fired boiler for oxy-fired operation. The impacts of CO{sub 2} flue gas recycle and burner design on flame characteristics (burnout, NO{sub x}, SO{sub x}, mercury and fine particle emissions, heat transfer) and operational concerns (fouling, slagging and corrosion) were minimal, with the exception of high sulfur levels resulting from untreated flue gas recycle with medium and high-sulfur coals. This work focused on combustion in the radiant and convective sections of the boiler and did not address boiler system integration issues, plant efficiencies, impacts on downstream air pollution control devices, or CO{sub 2} capture and compression. The experimental data, oxy-firing system principles and oxy-combustion process mechanisms provided by this work can be used by electric utilities, boiler OEMs, equipment suppliers, design firms, software vendors, consultants and government agencies to assess retrofit applications of oxy-combustion technologies to existing boilers and to guide development of new designs.

  14. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1992-12-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators. 14 figs.

  15. Apparatus for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1995-03-14

    An apparatus is disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal, and minerals so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators. 14 figs.

  16. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, R.H.; Adel, G.T.; Luttrell, G.H.

    1998-09-29

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators. 14 figs.

  17. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, Roe-Hoan (Blacksburg, VA); Adel, Gregory T. (Blacksburg, VA); Luttrell, Gerald H. (Blacksburg, VA)

    1998-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators.

  18. Apparatus for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, Roe-Hoan (Blacksburg, VA); Adel, Gregory T. (Blacksburg, VA); Luttrell, Gerald H. (Blacksburg, VA)

    1995-01-01

    An apparatus is disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal, and minerals so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators.

  19. Apparatus and process for the separation of hydrophobic and hydrophilic particles using microbubble column flotation together with a process and apparatus for generation of microbubbles

    DOE Patents [OSTI]

    Yoon, Roe-Hoan (Blacksburg, VA); Adel, Gregory T. (Blacksburg, VA); Luttrell, Gerald H. (Blacksburg, VA)

    1992-01-01

    A method and apparatus are disclosed for the microbubble flotation separation of very fine and coarse particles, especially coal and minerals, so as to produce high purity and high recovery efficiency. This is accomplished through the use of a flotation column, microbubbles, recycling of the flotation pulp, and countercurrent wash water to gently wash the froth. Also disclosed are unique processes and apparatus for generating microbubbles for flotation in a highly efficient and inexpensive manner using either a porous tube or in-line static generators.

  20. Low-rank coal research under the UND/DOE cooperative agreement. Quarterly technical progress report, April 1983-June 1983

    SciTech Connect (OSTI)

    Wiltsee, Jr., G. A.

    1983-01-01

    Progress reports are presented for the following tasks: (1) gasification wastewater treatment and reuse; (2) fine coal cleaning; (3) coal-water slurry preparation; (4) low-rank coal liquefaction; (5) combined flue gas cleanup/simultaneous SO/sub x/-NO/sub x/ control; (6) particulate control and hydrocarbons and trace element emissions from low-rank coals; (7) waste characterization; (8) combustion research and ash fowling; (9) fluidized-bed combustion of low-rank coals; (10) ash and slag characterization; (11) organic structure of coal; (12) distribution of inorganics in low-rank coals; (13) physical properties and moisture of low-rank coals; (14) supercritical solvent extraction; and (15) pyrolysis and devolatilization.

  1. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  2. Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer

    SciTech Connect (OSTI)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk

    2010-04-15

    In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

  3. Enzymantic Conversion of Coal to Liquid Fuels

    SciTech Connect (OSTI)

    Richard Troiano

    2011-01-31

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

  4. Development of an Advanced Deshaling Technology to Improve the Energy Efficiency of Coal Handling, Processing, and Utilization Operations

    SciTech Connect (OSTI)

    Rick Honaker; Gerald Luttrell

    2007-09-30

    The concept of using a dry, density-based separator to achieve efficient, near-face rock removal, commonly referred to as deshaling, was evaluated in several applications across the U.S.. Varying amounts of high-density rock exist in most run-of-mine feed. In the central Appalachian coalfields, a rock content exceeding 50% in the feed to a preparation plant is commonplace due to high amounts of out-of-seam dilution made necessary by extracting coal from thin seams. In the western U.S, an increase in out-of-seam dilution and environmental regulations associated with combustion emissions have resulted in a need to clean low rank coals and dry cleaning may be the only option. A 5 ton/hr mobile deshaling unit incorporating a density-based, air-table technology commercially known as the FGX Separator has been evaluated at mine sites located within the states of Utah, Wyoming, Texas, West Virginia, Virginia, Pennsylvania and Kentucky. The FGX technology utilizes table riffling principles with air as the medium. Air enters through the table and creates a fluidized bed of particles comprised of mostly fine, high density particles. The high density particle bed lifts the low-density coal particles to the top of the bed. The low-density coal moves toward the front of the table due to mass action and the downward slope of the table. The high-density particles settle through the fluidized particle bed and, upon making contact with the table, moves toward the back of the table with the assistance of table vibration. As a result, the low-density coal particles exit the front of the table closest to the feed whereas the high-density, high-ash content particles leave on the side and front of the table located at the farthest from the feed entry. At each test site, the run-of-mine feed was either directly fed to the FGX unit or pre-screened to remove the majority of the -6mm material. The surface moisture of the feed must be maintained below 9%. Pre-screening is required when the surface moisture of the feed coal exceeds the maximum limit. However, the content of -6mm in the feed to the FGX separator should be maintained between 10% and 20% to ensure an adequate fluidized bed. A parametric evaluation was conducted using a 3-level experimental design at each test site to identify the optimum separation performance and parameter values. The test data was used to develop empirical expressions that describe the response variables (i.e., mass yield and product ash content) as a function of the operating parameter values. From this process, it was established that table frequency and longitudinal slope are the most critical factors in controlling both mass yield and clean coal ash while the cross table slope was the least significant. Fan blower frequency is a critical parameter that controls mass yield. Although the splitter positions between product and middling streams and the middling and tailing streams were held constant during the tests, a separate evaluation indicated that performance is sensitive to splitter position within certain lengths of the table and insensitive in others. For a Utah bituminous coal, the FGX separator provided clean coal ash contents that ranged from a low of 8.57% to a high of 12.48% from a feed coal containing around 17% ash. From the 29 tests involved in the statistically designed test program, the average clean coal ash content was 10.76% while the tailings ash content averaged around 72%. One of the best separation performances achieved an ash reduction from 17.36% to 10.67% while recovering 85.9% of the total feed mass, which equated to an ash rejection value of around 47%. The total sulfur content was typically decreased from 1.61% to 1.49%. These performances were quantified by blending the middlings stream with the clean coal product. At a second Utah site, coal sources from three different bituminous coal seams were treated by the FGX deshaling unit. Three parameter values were varied based on the results obtained from Site No. 1 to obtain the optimum results shown in Table E-1. Approximately 9 tests w

  5. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  6. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  7. Resinous binders for coal and chars

    SciTech Connect (OSTI)

    Olson, E.S.; Sharma, R.K.; Young, B.C.

    1995-12-31

    Binder development and application to the briquetting or pelleting of coal fines has been extensive. The search for low-cost, effective binders for making strong and durable briquettes or pellets continues unabated. Strong, durable compacts are required, not only for handling, transport, and storage of the product but also to withstand the rigors of application such as flue gas treatment sorbents and catalytic supports. Many kinds of binders, organic and inorganic, have been used to gain the desired strength. Synthetic polymers have been investigated because they promote good strength and water insolubility, but these features are generally outweighed by the polymer cost. Promising earlier developments of biomass-derived binders have received slow market acceptance, mainly because of the cost resulting from the high concentrations required. However, recent advances in processing lignocellulosic materials have generated potentially low-cost polymeric binding agents for making coal briquettes. Phenol novolaks were previously used with lignites to make activated carbons. Recently, binders were prepared from mixtures of phenol, lignin, and formaldehyde and used for wood flour molding and friction materials. The goal of our work was to investigate the characteristics of resinous binders from lignocellulosic as well as coal-derived materials when used with dried or beneficiated coals and chars.

  8. Catalyst for coal liquefaction process

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Kang, Chia-Chen C. (Princeton, NJ)

    1984-01-01

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  9. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  10. Coal combustion products (CCPs

    Office of Environmental Management (EM)

    Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the largest segment of U.S. electricity generation (45 percent in 2010), finding a sustainable solution for CCPs is an important environmental challenge. When properly managed, CCPs offer society environmental and economic benefits without harm to public health and safety. Research supported by the U.S. Department of Energy's (DOE) Office of Fossil Energy (FE) has made an

  11. Coal Distribution Database, 2006

    U.S. Energy Information Administration (EIA) Indexed Site

    TF RailroadVesselShip Fuel It is also noted that Destination State code of "X Export" indicates movements to foreign destinations. 1 68 Domestic Coal Distribution...

  12. Coal | Open Energy Information

    Open Energy Info (EERE)

    Assuming no additional constraints on CO2 emissions, coal remains the largest source of electricity generation in the AEO2011 Reference case because of continued reliance on...

  13. Coal Market Module

    Gasoline and Diesel Fuel Update (EIA)

    The use of coals with sub- optimal characteristics carries with it penalties in operating efficiency, maintenance cost, and system reliability. Such penalties range from the...

  14. British coal privatization procedures

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    The form in which British Coal is to be privatized has finally been announced. Offers are to be invited for the operating underground and opencast mines which will be grouped into five regionally based companies. Additionally, offers will be invited for a number of collieries which are currently under care and maintenance. The five Regional Coal Companies to be formed are Central North, which will comprise the assets in the Yorkshire and Durham coalfields, including the five collieries in the Selby Complex; Central South, which will contain the assets located in the Nottinghamshire, Leicestershire, Derbyshire, and Warwickshire coalfields; North East, which has four opencast sites, Scotland, which has nine operating open-cast sites and a single underground mine, Longannet; and South Wales with its nine operating opencast sites. Tower colliery, the last underground mine in South Wales, was finally put on care and maintenance on April 20, 1994. Details of the five Regional Coal Companies are given. A new public sector body, the Coal Authority will be set up to which all British Coal's title to unworked coal and coal mines will be transferred. All the relevant property rights and liabilities of British Coal will be transferred into the Regional Coal Companies prior to their sun.

  15. Balancing coal pipes

    SciTech Connect (OSTI)

    Earley, D.; Kirkenir, B.

    2009-11-15

    Balancing coal flow to the burners to optimise combustion by using real-time measurement systems (such as microwave mass measurement) is discussed. 3 figs.

  16. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M. (Macungie, PA); Yeh, Chung-Liang (Bethlehem, PA); Donath, Ernest E. (St. Croix, VI)

    1983-01-01

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  17. By Coal Destination State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    California (thousand short tons) Coal Origin State Transportation Mode Electric Power Sector Coke Plants Industrial Plants (excluding Coke) Commercial & Institutional Total...

  18. Annual Coal Distribution Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    Domestic Distribution of U.S. Coal by Destination State, Consumer, Destination and Method of Transportation, 2001 (Thousand Short Tons) DESTINATION: Alabama State of Origin by...

  19. Coal Distribution Database, 2006

    U.S. Energy Information Administration (EIA) Indexed Site

    Report - Annual provides detailed information on domestic coal distribution by origin state, destination state, consumer category, and method of transportation. Also provided is...

  20. Rail Coal Transportation Rates

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Recurring Reserves Stocks All reports Browse by Tag Alphabetical Frequency Tag Cloud Data For: 2001 Next Release Date: October 2003 U. S. Coal-Producing Districts...

  1. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    SciTech Connect (OSTI)

    Bradley Adams; Andrew Fry; Constance Senior; Hong Shim; Huafeng Wang; Jost Wendt; Christopher Shaddix

    2009-06-30

    This report summarizes Year 1 results of a research program designed to use multi-scale experimental studies and fundamental theoretical models to characterize and predict the impacts of retrofit of existing coal-fired utility boilers for oxy-combustion. Through the course of Year 1 activities, great progress was made toward understanding the issues associated with oxy-combustion retrofit of coal-fired boilers. All four Year 1 milestones and objectives have been, or will be, completed on schedule and within budget. Progress in the four milestone areas may be summarized as follows: • University of Utah has performed size segregated ash composition measurements in the Oxy-Fuel Combustor (OFC). These experiments indicate that oxy-combustion retrofit may impact ash aerosol mineral matter composition. Both flame temperature and flue gas composition have been observed to influence the concentration of calcium, magnesium and iron in the fine particulate. This could in turn impact boiler fouling and slagging. • Sandia National Labs has shown that char oxidation rate is dependent on particle size (for sizes between 60 and 100 microns) by performing fundamental simulations of reacting char particles. These predictions will be verified by making time-resolved optical measurements of char particle temperature, velocity and size in bench-scale experiments before the end of Year 1. • REI and Siemens have completed the design of an oxy-research burner that will be mounted on University of Utah’s pilot-scale furnace, the L1500. This burner will accommodate a wide range of O2, FGR and mixing strategies under conditions relevant for utility boiler operation. Through CFD modeling of the different burner designs, it was determined that the key factor influencing flame stabilization location is particle heat-up rate. The new oxy-research burner and associated equipment is scheduled for delivery before the end of Year 1. • REI has completed a literature survey of slagging and fouling mechanisms in coal-fired power plants to understand key issues influencing these deposition regimes and infer their behavior under oxy-fired conditions. Based on the results of this survey, an algorithm for integrating slagging predictions into CFD models was outlined. This method accounts for ash formation, particle impaction and sticking, deposit growth and physical properties and impact of the deposit on system flow and heat transfer. A model for fouling in the back pass has also been identified which includes vaporization of sodium, deposition of sodium sulfate on fly ash particles and tube surfaces, and deposit growth rate on tubes. In Year 1, REI has also performed a review of the literature describing corrosion in order to understand the behavior of oxidation, sulfidation, chloridation, and carburization mechanisms in air-fired and oxy-combustion systems. REI and Vattenfall have met and exchanged information concerning oxy-coal combustion mechanisms for CFD simulations currently used by Vattenfall. In preparation for Year 2 of this program, two coals (North Antelope PRB, Western bituminous) have been ordered, pulverized and delivered to the University of Utah and Sandia National Labs. Materials for the corrosion experiments have been identified, suppliers located, and a schedule for equipment fabrication and shakedown has been established. Finally, a flue gas recycle system has been designed and is being constructed for the OFC.

  2. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect (OSTI)

    Stefano Orsino

    2005-03-30

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

  3. U.S. Coal Reserves

    Gasoline and Diesel Fuel Update (EIA)

    Coal Glossary › FAQS › Overview Data Coal Data Browser new! Summary Prices Reserves Consumption Production Stocks Imports, exports & distribution Coal transportation rates International All coal data reports Analysis & Projections Major Topics Most popular Consumption Environment Imports & exports Industry characteristics Prices Production Projections Recurring Reserves Stocks All reports Browse by Tag Alphabetical Frequency Tag Cloud ‹ See all Coal Reports U.S. Coal Reserves

  4. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  5. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B.

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  6. Method of burning lightly loaded coal-water slurries

    DOE Patents [OSTI]

    Krishna, C.R.

    1984-07-27

    In a preferred arrangement of the method of the invention, a lightly loaded coal-water slurry, containing in the range of approximately 40% to 52% + 2% by weight coal, is atomized to strip water from coal particles in the mixture. Primary combustor air is forced around the atomized spray in a combustion chamber of a combustor to swirl the air in a helical path through the combustion chamber. A flame is established within the combustion chamber to ignite the stripped coal particles, and flame temperature regulating means are provided for maintaining the flame temperature within a desired predetermined range of temperatures that is effective to produce dry, essentially slag-free ash from the combustion process.

  7. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  8. Oil shale fines process developments in Brazil

    SciTech Connect (OSTI)

    Lisboa, A.C.; Nowicki, R.E. ); Piper, E.M. )

    1989-01-01

    The Petrobras oil shale retorting process, utilizes the particle range of +1/4 inch - 3 1/2 inches. The UPI plant in Sao Mateus do Sul has over 106,000 hours of operation, has processed over 6,200,000 metric tons of shale and has produced almost 3,000,000 barrels of shale oil. However, the nature of the raw oil shale is such that the amount of shale less than 1/4 inch that is mined and crushed and returned to the mine site is about 20 percent, thereby, increasing the cost of oil produced by a substantial number. Petrobras has investigated several systems to process the fines that are not handled by the 65 MTPH UPI plant and the 260 MTPH commercial plant. This paper provides an updated status of each of these processes in regard to the tests performed, potential contributions to an integrated use of the oil shale mine, and future considerations.

  9. Method of making fine-grained triaminotrinitrobenzene

    DOE Patents [OSTI]

    Benziger, Theodore M. (Santa Fe, NM)

    1984-01-01

    A method of forming a fine-grained species of the insensitive high explosive sym-triaminotrinitrobenzene (TATB) without grinding. In accordance with the method, 1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) is aminated by reaction with gaseous ammonia in an emulsion of toluene in water. The ratio of water to toluene in the emulsion is selected so that toluene is the dispersed phase in the emulsion. The size of the dispersed TCTNB-containing toluene droplets determines the particle size of the resulting TATB. The emulsion is preferably formed with an emulsifier such as ammonium oleate, which may be generated in situ from oleic acid, and stabilized with a protective colloid such as polyvinyl alcohol.

  10. Method of making fine-grained triaminotrinitrobenzene

    DOE Patents [OSTI]

    Benziger, T.M.

    1983-07-26

    A method is given for forming a fine-grained species of the insensitive high explosive sym-triaminotrinitrobenzene (TATB) without grinding. In accordance with the method, 1,3,5-trichloro-2,4,6-trinitrobenzene (TCTNB) is aminated by reaction with gaseous ammonia in an emulsion of toluene in water. The ratio of water to toluene in the emulsion is selected so that toluene is the dispersed phase in the emulsion. The size of the dispersed TCTNB-containing toluene droplets determines the particle size of the resulting TATB. The emulsion is preferably formed with an emulsifier such as ammonium oleate, which may be generated in situ from oleic acid, and stabilized with a protective colloid such as polyvinyl alcohol.

  11. Coal liquefaction process

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Moon, William G. (Cheswick, PA); Prudich, Michael E. (Pittsburgh, PA)

    1983-01-01

    A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

  12. Mechanochemical hydrogenation of coal

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Smol, Robert (East Patchogue, NY); Farber, Gerald (Elmont, NY); Naphtali, Leonard M. (Washington, DC)

    1981-01-01

    Hydrogenation of coal is improved through the use of a mechanical force to reduce the size of the particulate coal simultaneously with the introduction of gaseous hydrogen, or other hydrogen donor composition. Such hydrogen in the presence of elemental tin during this one-step size reduction-hydrogenation further improves the yield of the liquid hydrocarbon product.

  13. Coal. [Great Plains Project

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    The status of various research projects related to coal is considered: gasification (approximately 30 processes) and in-situ gasification. Methanol production, retrofitting internal combustion engines to stratified charge engines, methanation (Conoco), direct reduction of iron ores, water resources, etc. Approximately 200 specific projects related to coal are considered with respect to present status. (LTN)

  14. Cross flow cyclonic flotation column for coal and minerals beneficiation

    DOE Patents [OSTI]

    Lai, Ralph W. (Upper St. Clair, PA); Patton, Robert A. (Pittsburgh, PA)

    2000-01-01

    An apparatus and process for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophillic tailings.

  15. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    Smith, P.; Deo, M.; Eddings, E.; Sarofim, A.; Gueishen, K.; Hradisky, M.; Kelly, K.; Mandalaparty, P.; Zhang, H.

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  16. Enzymatic desulfurization of coal

    SciTech Connect (OSTI)

    Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P.; Nochur, S.V.

    1991-05-16

    The overall objective of this program was to investigate the feasibility of an enzymatic desulfurization process specifically intended for organic sulfur removal from coal. Toward that end, a series of specific objectives were defined: (1) establish the feasibility of (bio)oxidative pretreatment followed by biochemical sulfate cleavage for representative sulfur-containing model compounds and coals using commercially-available enzymes; (2) investigate the potential for the isolation and selective use of enzyme preparations from coal-utilizing microbial systems for desulfurization of sulfur-containing model compounds and coals; and (3) develop a conceptual design and economic analysis of a process for enzymatic removal of organic sulfur from coal. Within the scope of this program, it was proposed to carry out a portion of each of these efforts concurrently. (VC)

  17. Coal in China

    SciTech Connect (OSTI)

    Minchener, A.J.

    2005-07-01

    The article gives an overview of the production and use of coal in China, for power generation and in other sectors. Coal use for power generation was 850 million tonnes in 2003 and 800 million tonnes in the non-power sector. The majority of power will continue to be produced from coal, with a trend towards new larger pulverised coal fired units and introduction of circulating fluidised bed combustors. Stricter regulations are forcing introduction of improved pollution control technologies. It seems likely that China will need international finance to supplement private and state investment to carry out a programme to develop and apply clean coal technologies. The author concludes that there is evidence of a market economy being established but there is a need to resolve inconsistencies with the planned aspects of the economy and that additional policies are needed in certain sectors to achieve sustainable development. 1 ref., 2 figs., 2 tabs.

  18. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  19. Advanced solids NMR studies of coal structure and chemistry. Progress report, March 1 - September 1, 1996

    SciTech Connect (OSTI)

    Zilm, K.W.

    1996-12-31

    This report covers the progress made on the title project for the project period. The study of coal chemical structure is a vital component of research efforts to develop better chemical utili- zation of coals, and for furthering our basic understanding of coal geochemistry. In this grant we are addressing several structural questions pertaining to coals with advances in state of the art solids NMR methods. Our goals are twofold. First, we are interested in developing new methods that will enable us to measure important structural parameters in whole coals not directly accessible by other techniques. In parallel with these efforts we will apply these NNM methods in a study of the chemical differences between gas-sourcing and oil-sourcing coals. The NMR methods work will specifically focus on determination of the number and types of methylene groups, determination of the number and types of methine groups, identification of carbons adjacent to nitrogen and sites with exchangeable protons, and methods to more finely characterize the distribution of hydrogen in coals. We will also develop NMR methods for probing coal macropore structure using hyperpolarized {sup 29}Xe as a probe, and study the molecular dynamics of what appear to be mobile, CH{sub 2} rich, long chain hydrocarbons. The motivation for investigating these specific structural features of coals arises from their relevance to the chemical reactivity of coals, and their suitability for possible correlations with the oil sourcing potential of some types of coals. The coals to be studied and contrasted include oil-prone coals from Australia and Indonesia, those comprising the Argonne Premium Coal Sample bank, and other relevant samples.

  20. Modeling coal combustion behavior in an ironmaking blast furnace raceway: model development and applications

    SciTech Connect (OSTI)

    Maldonado, D.; Austin, P.R.; Zulli, P.; Guo B.

    2009-03-15

    A numerical model has been developed and validated for the investigation of coal combustion phenomena under blast furnace operating conditions. The model is fully three-dimensional, with a broad capacity to analyze significant operational and equipment design changes. The model was used in a number of studies, including: Effect of cooling gas type in coaxial lance arrangements. It was found that oxygen cooling improves coal burnout by 7% compared with natural gas cooling under conditions that have the same amount of oxygen enrichment in the hot blast. Effect of coal particle size distribution. It was found that during two similar periods of operation at Port Kembla's BF6, a difference in PCI capability could be attributed to the difference in coal size distribution. Effect of longer tuyeres. Longer tuyeres were installed at Port Kembla's BF5, leading to its reline scheduled for March 2009. The model predicted an increase in blast velocity at the tuyere nose due to the combustion of volatiles within the tuyere, with implications for tuyere pressure drop and PCI capability. Effect of lance tip geometry. A number of alternate designs were studied, with the best-performing designs promoting the dispersion of the coal particles. It was also found that the base case design promoted size segregation of the coal particles, forcing smaller coal particles to one side of the plume, leaving larger coal particles on the other side. 11 refs., 15 figs., 4 tabs.

  1. Coal in a changing climate

    SciTech Connect (OSTI)

    Lashof, D.A.; Delano, D.; Devine, J.

    2007-02-15

    The NRDC analysis examines the changing climate for coal production and use in the United States and China, the world's two largest producers and consumers of coal. The authors say that the current coal fuel cycle is among the most destructive activities on earth, placing an unacceptable burden on public health and the environment. There is no such thing as 'clean coal.' Our highest priorities must be to avoid increased reliance on coal and to accelerate the transition to an energy future based on efficient use of renewable resources. Energy efficiency and renewable energy resources are technically capable of meeting the demands for energy services in countries that rely on coal. However, more than 500 conventional coal-fired power plants are expected in China in the next eight years alone, and more than 100 are under development in the United States. Because it is very likely that significant coal use will continue during the transition to renewables, it is important that we also take the necessary steps to minimize the destructive effects of coal use. That requires the U.S. and China to take steps now to end destructive mining practices and to apply state of the art pollution controls, including CO{sub 2} control systems, to sources that use coal. Contents of the report are: Introduction; Background (Coal Production; Coal Use); The Toll from Coal (Environmental Effects of Coal Production; Environmental Effects of Coal Transportation); Environmental Effects of Coal Use (Air Pollutants; Other Pollutants; Environmental Effects of Coal Use in China); What Is the Future for Coal? (Reducing Fossil Fuel Dependence; Reducing the Impacts of Coal Production; Reducing Damage From Coal Use; Global Warming and Coal); and Conclusion. 2 tabs.

  2. COAL CLEANING VIA LIQUID-FLUIDIZED CLASSIFICAITON (LFBC) WITH SELECTIVE SOLVENT SWELLING

    SciTech Connect (OSTI)

    J. M. Calo

    2000-12-01

    The concept of coal beneficiation due to particle segregation in water-fluidized beds, and its improvement via selective solvent-swelling of organic material-rich coal particles, was investigated in this study. Particle size distributions and their behavior were determined using image analysis techniques, and beneficiation effects were explored via measurements of the ash content of segregated particle samples collected from different height locations in a 5 cm diameter liquid-fluidized bed column (LFBC). Both acetone and phenol were found to be effective swelling agents for both Kentucky No.9 and Illinois No.6 coals, considerably increasing mean particle diameters, and shifting particle size distributions to larger sizes. Acetone was a somewhat more effective swelling solvent than phenol. The use of phenol was investigated, however, to demonstrate that low cost, waste solvents can be effective as well. For unswollen coal particles, the trend of increasing particle size from top to bottom in the LFBC was observed in all cases. Since the organic matter in the coal tends to concentrate in the smaller particles, the larger particles are typically denser. Consequently, the LFBC naturally tends to separate coal particles according to mineral matter content, both due to density and size. The data for small (40-100 {micro}m), solvent-swollen particles clearly showed improved beneficiation with respect to segregation in the water-fluidized bed than was achieved with the corresponding unswollen particles. This size range is quite similar to that used in pulverized coal combustion. The original process concept was amply demonstrated in this project. Additional work remains to be done, however, in order to develop this concept into a full-scale process.

  3. Coal market momentum converts skeptics

    SciTech Connect (OSTI)

    Fiscor, S.

    2006-01-15

    Tight supplies, soaring natural gas prices and an improving economy bode well for coal. Coal Age presents it 'Forecast 2006' a survey of 200 US coal industry executives. Questions asked included predicted production levels, attitudes, expenditure on coal mining, and rating of factors of importance. 7 figs.

  4. Environmentally conscious coal combustion

    SciTech Connect (OSTI)

    Hickmott, D.D.; Brown, L.F.; Currier, R.P.

    1997-08-01

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The objective of this project was to evaluate the environmental impacts of home-scale coal combustion on the Navajo Reservation and develop strategies to reduce adverse health effects associated with home-scale coal combustion. Principal accomplishments of this project were: (1) determination of the metal and gaseous emissions of a representative stove on the Navajo Reservation; (2) recognition of cyclic gaseous emissions in combustion in home-scale combustors; (3) `back of the envelope` calculation that home-scale coal combustion may impact Navajo health; and (4) identification that improved coal stoves require the ability to burn diverse feedstocks (coal, wood, biomass). Ultimately the results of Navajo home-scale coal combustion studies will be extended to the Developing World, particularly China, where a significant number (> 150 million) of households continue to heat their homes with low-grade coal.

  5. Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  6. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  7. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  8. Aqueous coal slurry

    SciTech Connect (OSTI)

    Berggren, M.H.; Smit, F.J.; Swanson, W.W.

    1989-10-30

    A principal object of the invention is the provision of an aqueous coal slurry containing a dispersant, which is of low-cost and which contains very low or no levels of sodium, potassium, sulfur and other contaminants. In connection with the foregoing object, it is an object of the invention to provide an aqueous slurry containing coal and dextrin as a dispersant and to provide a method of preparing an aqueous coal slurry which includes the step of adding an effective amount of dextrin as a dispersant. The invention consists of certain novel features and a combination of parts hereinafter fully described, and particularly pointed out in the appended claims. 6 tabs.

  9. Coal-fueled diesel locomotive test

    SciTech Connect (OSTI)

    Hsu, B.D.; McDowell, R.E.; Confer, G.L.; Basic, S.L.

    1993-01-01

    The biggest challenges to the development of a commercially-acceptable coal-fueled diesel-electric locomotive are integrating all systems into a working unit that can be operated in railroad service. This involves mainly the following three systems: (1) the multi-cylinder coal-fueled diesel engine, (2) the locomotive and engine controls, and (3) the CWS fuel supply system. Consequently, a workable 12-cylinder coal-fueled diesel engine was considered necessary at this stage to evolve the required locomotive support systems, in addition to gaining valuable multi-cylinder engine operating experience. The CWS fuel used during this project was obtained from Otisca, Inc. (Syracuse, NY). It was prepared from micronized and deashed Kentucky Blue Gem coal to 49.0% coal loading by weight, with less than 1% ash and 5 micron mean diameter particle size. Its higher heating value was analyzed at approximately 34630 kJ/k. Anti-agglomerating additive Triton X-114 was added to the CWS at GE Transportation Systems at 2% of coal weight. The nature of the Otisca CWS fuel makes it inherently more difficult to store, pump, and inject than diesel fuel, since concepts which govern Newtonian or normally viscous liquids do not apply entirely to CWS. Otisca CWS tends to be unstable and to settle in tanks and lines after a period of time, making it necessary to provide a means of agitation during storage. To avoid long term settling problems and to minimize losses, piping velocities were designed to be in the 60-90 m/min range.

  10. Ash reduction in clean coal spiral product circuits

    SciTech Connect (OSTI)

    Brodzik, P.

    2007-04-15

    The article describes the Derrick Corporation's Stack Sizer{trademark} technology for high capacity fine wet cleaning with long-lasting high open-area urethane screen panels. After field trials, a Stack Sizer fitted with a 100-micron urethane panel is currently processing approximately 40 stph of clean coal spiral product having about 20% ash at McCoy-Elkhorn's Bevin Branch coal preparation plant in Kentucky, USA. Product yield is about 32.5 short tons per hour with 10% ash. The material is then fed to screen bowl centrifuges for further processing. At Blue Diamond Coal's Leatherwood preparation plant similar Stacker Sizers are achieving the same results. 2 figs., 3 tabs., 2 photo.

  11. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 2 (Jan 2016) Archived Editions: Coal ...

  12. Clean Coal Power Initiative | Department of Energy

    Office of Environmental Management (EM)

    Clean Coal Power Initiative Clean Coal Power Initiative "Clean coal technology" describes a new generation of energy processes that sharply reduce air emissions and other ...

  13. Puda Coal Inc | Open Energy Information

    Open Energy Info (EERE)

    Puda Coal Inc Jump to: navigation, search Name: Puda Coal, Inc Place: Taiyuan, Shaanxi Province, China Product: Specializes in coal preparation by applying a water jig washing...

  14. Dense, finely, grained composite materials

    DOE Patents [OSTI]

    Dunmead, Stephen D. (Davis, CA); Holt, Joseph B. (San Jose, CA); Kingman, Donald D. (Danville, CA); Munir, Zuhair A. (Davis, CA)

    1990-01-01

    Dense, finely grained composite materials comprising one or more ceramic phase or phase and one or more metallic and/or intermetallic phase or phases are produced by combustion synthesis. Spherical ceramic grains are homogeneously dispersed within the matrix. Methods are provided, which include the step of applying mechanical pressure during or immediately after ignition, by which the microstructures in the resulting composites can be controllably selected.

  15. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H. (Golden, CO); Smit, Francis J. (Arvada, CO); Swanson, Wilbur W. (Golden, CO)

    1993-01-01

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  16. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  17. Clean Coal Research

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE's clean coal R&D is focused on developing and demonstrating advanced power generation and carbon capture, utilization and storage technologies for existing facilities and new fossil-fueled...

  18. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H.; Smit, Francis J.; Swanson, Wilbur W.

    1993-04-06

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  19. Coal markets squeeze producers

    SciTech Connect (OSTI)

    Ryan, M.

    2005-12-01

    Supply/demand fundamentals seem poised to keep prices of competing fossil fuels high, which could cushion coal prices, but increased mining and transportation costs may squeeze producer profits. Are markets ready for more volatility?

  20. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  1. Coal Liquefaction desulfurization process

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  2. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment. Quarterly report No. 9, September 1, 1988--November 30, 1988

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-12-01

    A real-time laser light-reflectivity technique is being used to study simultaneous thermophoretic and inertial influences on the deposition behavior of MgO particles produced via ultrasonic nebulization (submicrometer range). The deposition surface (a concave platinum ribbon) is exposed to a high velocity/temperature jet of alkali sulfate-free combustion products exiting from a seeded (C3{sub 3}H{sub 8}/air) microcombustor (110 cm{sup 3}). The reflectivity data were calibrated against deposition rates obtained from SEM pictures of the target, and were normalized with the nominal particle feed rate, in order to obtain the mass transfer Stanton number, St{sub m}, trends depicted in Figure 1. For the submicron (ca. 0.7{mu}m) particles inertial effects appear to set in at Stokes (Stk) numbers of O(10{sup {minus}2}) (an order of magnitude lower than the ones needed for ``pure`` inertial impaction), affecting significantly the dominant thermophoretic deposition mechanism. A first order (in Stk) theoretical analysis of the problem in which particle inertia is treated as equivalent to ``pressure diffusion,`` cannot explain the observed dependence of the deposition rate on Stk. We are presently formulating a Lagrangian approach, valid for all values of Stk, in order to interpret these data. In addition, a Single Particle Counter (SPC) and Transit Time Velocimeter (TTV), are being developed, to allow more precise measurements of particle feed rates and velocities.

  3. Coal repository. Final report

    SciTech Connect (OSTI)

    Not Available

    1983-11-01

    The Coal Repository Project was initiated in 1980 by the Department of Energy/Pittsburgh Energy Technology Center to provide a centralized system for the collection of well characterized coal samples, and distribution to organizations involved in the chemical beneficiation of coal and related research. TRW Energy Development Group, together with its subcontractor Commercial Testing and Engineering Company, established the Coal Repository at the TRW Capistrano Chemical Facility, which is the location of the DOE-owned Multi-Use Fuel and Energy Processes Test Plant (MEP). Twenty tons each of three coals (Illinois No. 6, Kentucky No. 11 (West), and Pittsburgh No. 8 (from an Ohio mine)) were collected, characterized, and stored under a nitrogen atmosphere. Ten tons of each coal are 3/8-inch x 0, five tons of each are 14-mesh x 0, and five tons of each are 100-mesh x 0. Although TRW was within budget and on schedule, Department of Energy funding priorities in this area were altered such that the project was terminated prior to completion of the original scope of work. 9 figures, 3 tables.

  4. Process for forming coal compacts and product thereof

    DOE Patents [OSTI]

    Gunnink, Brett (Columbia, MO); Kanunar, Jayanth (Arlington, MA); Liang, Zhuoxiong (San Francisco, CA)

    2002-01-01

    A process for forming durable, mechanically strong compacts from coal particulates without use of a binder is disclosed. The process involves applying a compressive stress to a particulate feed comprising substantially water-saturated coal particles while the feed is heated to a final compaction temperature in excess of about 100.degree. C. The water present in the feed remains substantially in the liquid phase throughout the compact forming process. This is achieved by heating and compressing the particulate feed and cooling the formed compact at a pressure sufficient to prevent water present in the feed from boiling. The compacts produced by the process have a moisture content near their water saturation point. As a result, these compacts absorb little water and retain exceptional mechanical strength when immersed in high pressure water. The process can be used to form large, cylindrically-shaped compacts from coal particles (i.e., "coal logs") so that the coal can be transported in a hydraulic coal log pipeline.

  5. Eastman, AP start on coal unit

    SciTech Connect (OSTI)

    1995-10-25

    Eastman Chemical and Air Products and Chemicals (AP) have started construction of a $214-million, coal-to-methanol demonstration unit at Eastmans site in Kingsport, TN. The project is part of the Department of Energy`s clean coal technology program and is receiving $93 million in federal support. The demonstration unit-which will have a methanol capacity of 260 tons/day-will use novel catalyst technology for converting coal-derived synthesis gas (syngas) to methanol. Unlike conventional technology that processes syngas through a fixed bed of dry catalyst particles, the liquid-phase methanol process converts the syngas in a single vessel containing catalysts suspended in mineral oil. The companies say the innovation allows the process to better able handle the gases from coal gasifiers and is more stable and reliable than existing processes. Eastman says it will use the methanol produced by the plant as a chemical feedstock. It currently uses methanol as an intermediate in making acetic anhydride and dimethyl terephthalate. In addition, the companies say the methanol will be evaluated as a feedstock in making methyl tert-butyl ether for reformulated fuels. Eastman also says it will evaluate coproducing dimethyl ether (DME) with the methanol. DME can be used as a fuel additive or blended with methanol for a chemical feedstock, according to Eastman.

  6. Transformations of inorganic coal constituents in combustion systems

    SciTech Connect (OSTI)

    Helble, J.J.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. ); Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. ); Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L. ); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. (Kentucky Univ., Lexingt

    1992-11-01

    The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles What determines their composition Whether or not particles deposit How combustion conditions, including reactor size, affect these processes remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

  7. Synthetic Coal Slag Infiltration into Varying Refractory Materials

    SciTech Connect (OSTI)

    Kaneko, Tetsuya K.; Thomas, Hugh; Bennett, James P.; Sridhar, Seetharaman

    2012-10-01

    The infiltrations of synthetic coal slag into 99%Al{sub 2}O{sub 3}, 85%Al{sub 2}O{sub 3}15%SiO{sub 2}, and 90%Cr{sub 2}O{sub 3}10%Al{sub 2}O{sub 3} refractories with a temperature gradient induced along the penetration direction were compared to one another. The infiltrating slag was synthesized with a composition that is representative of an average of the ash contents from U S coal feedstock. Experiments were conducted with a hot-face temperature of 1450C in a CO/CO{sub 2} atmosphere. Minimal penetration was observed in the 90%Cr{sub 2}O{sub 3}10%Al{sub 2}O{sub 3} material because interactions between the refractory and the slag produced a protective layer of FeCr{sub 2}O{sub 4}, which impeded slag flow into the bulk of the refractory. After 5 h, the 99%Al{sub 2}O{sub 3} sample exhibited an average penetration of 12.7 mm whereas the 85%Al{sub 2}O{sub 3}15%SiO{sub 2} sample showed 3.8 mm. Slag infiltrated into the 99%Al{sub 2}O{sub 3} and 85%Al{sub 2}O{sub 3}15%SiO{sub 2} refractory systems by dissolving the respective refractories' matrix materials, which consist of fine Al{sub 2}O{sub 3} particles and an amorphous alumino-silicate phase. Due to enrichment in SiO{sub 2}, a network-former, infiltration into the 85%Al{sub 2}O{sub 3}15%SiO{sub 2} system yielded a higher viscosity slag and hence, a shallower penetration depth. The results suggest that slag infiltration can be limited by interactions with the refractory through the formation of either a solid layer that physically impedes fluid flow or a more viscous slag that retards infiltration.

  8. Chemical leaching of coal to remove ash, alkali and vanadium

    SciTech Connect (OSTI)

    Smit, F.J.; Huggins, D.K.; Berggren, M.; Anast, K.R.

    1986-04-15

    A process is described for upgrading powdered coal to improve the usefulness thereof as a fuel for internal combustion engines which consists of: (a) pressure-leaching powdered coal having a particle size ranging from about 28 mesh to about 200 mesh in an aqueous caustic solution at a temperature ranging from about 175/sup 0/C, to about 350/sup 0/C., the amount of caustic in the solution ranging from about 5% to about 30% by weight, the amount of coal being sufficient to form a slurry comprising about 10% to 30% by weight of solids, (b) hydrochloric acid leaching the caustic leached coal to dissolve acid-soluble constituents resulting from the caustic leach, (c) pressure leaching the acid-leached coal with a liquid from the group consisting of water and dilute aqueous ammonia to remove sodium and chlorine, and thereafter (d) filtering and washing the pressure leached coal, whereby the coal is characterized by up to about 0.85% by weight of ash, up to about 150 ppm of alkali metals and up to about 4 ppm vanadium.

  9. STEO November 2012 - coal supplies

    Gasoline and Diesel Fuel Update (EIA)

    Despite drop in domestic coal production, U.S. coal exports to reach record high in 2012. While U.S. coal production is down 7 percent this year due in part to utilities switching to low-priced natural gas to generate electricity, American coal is still finding plenty of buyers in overseas markets. U.S. coal exports are expected to hit a record 125 million tons in 2012, the U.S. Energy Information Administration says in its new monthly short-term energy outlook. Coal exports are expected to

  10. Energy and environmental research emphasizing low-rank coal. Semi-annual report, January--June 1994

    SciTech Connect (OSTI)

    1994-09-01

    Summaries of progress on the following tasks are presented: Mixed waste treatment; Hot water extraction of nonpolar organic pollutant from soils; Aqueous phase thermal oxidation wastewater treatment; Review of results from comprehensive characterization of air toxic emissions from coal-fired power plants; Air toxic fine particulate control; Effectiveness of sorbents for trace elements; Catalyst for utilization of methane in selective catalytic reduction of NOx; Fuel utilization properties; Hot gas cleaning; PFBC; catalytic tar cracking; sulfur forms in coal; resid and bitumen desulfurization; biodesulfurization; diesel fuel desulfurization; stability issues; Sorbent carbon development; Evaluation of carbon products; Stable and supercritical chars; Briquette binders; Carbon molecular sieves; Coal char fuel evaporation canister sorbent; Development of a coal by-product classification protocol for utilization; Use of coal ash in recycled plastics and composite materials; Corrosion of advanced structural materials; Joining of advanced structural materials; Resource data evaluation; and the Usti and Labem (Czech Republic) coal-upgrading program.

  11. Spin-mapping of coal structures with ESE and ENDOR

    SciTech Connect (OSTI)

    Belford, R.L.; Clarkson, R.B.

    1991-12-01

    The goals of this program include developing a system for the analysis of the chemical forms of organic sulfur in coal and for study of coal particle surfaces by multifrequency EPR spectroscopy, ENDOR, and ESE spectroscopy and Applying it to coals, to the effects of treatment upon their sulfur-containing organic components, and to related carbonaceous materials (chars and the like). The approach is to utilize the naturally-occurring unpaired electrons in the organic structures of coals as spies to provide molecular structure information, reading out the information with Electron Paramagnetic Resonance (EPR) spectroscopy. Several forms of EPR are employed: Multifrequency continuous-wave (CW) EPR, from 1 GHz to 240 GHz source frequency; electron-nuclear double resonance (ENDOR), in which NMR spectra at paramagnetic centers are obtained by EPR detection; and pulsed EPR, including ESE (Electron Spin Echo) spectroscopy.

  12. Coal hydrogenation and deashing in ebullated bed catalytic reactor

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Johanson, Edwin S. (Princeton, NJ)

    1983-01-01

    An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

  13. EIA projections of coal supply and demand

    SciTech Connect (OSTI)

    Klein, D.E.

    1989-10-23

    Contents of this report include: EIA projections of coal supply and demand which covers forecasted coal supply and transportation, forecasted coal demand by consuming sector, and forecasted coal demand by the electric utility sector; and policy discussion.

  14. Assessment of Drag Models for Geldart A Particles in Bubbling Fluidized Beds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Estejab, Bahareh; Battaglia, Francine

    2015-10-08

    In order to accurately predict the hydrodynamic behavior of gas and solid phases using an Eulerian–Eulerian approach, it is crucial to use appropriate drag models to capture the correct physics. In this study, the performance of seven drag models for fluidization of Geldart A particles of coal, poplar wood, and their mixtures was assessed. In spite of the previous findings that bode badly for using predominately Geldart B drag models for fine particles, the results of our study revealed that if static regions of mass in the fluidized beds are considered, these drag models work well with Geldart A particles.more » It was found that drag models derived from empirical relationships adopt better with Geldart A particles compared to drag models that were numerically developed. Overall, the Huilin–Gidaspow drag model showed the best performance for both single solid phases and binary mixtures, however, for binary mixtures, Wen–Yu model predictions were also accurate.« less

  15. Underground Coal Gasification Program

    Energy Science and Technology Software Center (OSTI)

    1994-12-01

    CAVSIM is a three-dimensional, axisymmetric model for resource recovery and cavity growth during underground coal gasification (UCG). CAVSIM is capable of following the evolution of the cavity from near startup to exhaustion, and couples explicitly wall and roof surface growth to material and energy balances in the underlying rubble zones. Growth mechanisms are allowed to change smoothly as the system evolves from a small, relatively empty cavity low in the coal seam to a large,more » almost completely rubble-filled cavity extending high into the overburden rock. The model is applicable to nonswelling coals of arbitrary seam thickness and can handle a variety of gas injection flow schedules or compositions. Water influx from the coal aquifer is calculated by a gravity drainage-permeation submodel which is integrated into the general solution. The cavity is considered to consist of up to three distinct rubble zones and a void space at the top. Resistance to gas flow injected from a stationary source at the cavity floor is assumed to be concentrated in the ash pile, which builds up around the source, and also the overburden rubble which accumulates on top of this ash once overburden rock is exposed at the cavity top. Char rubble zones at the cavity side and edges are assumed to be highly permeable. Flow of injected gas through the ash to char rubble piles and the void space is coupled by material and energy balances to cavity growth at the rubble/coal, void/coal and void/rock interfaces. One preprocessor and two postprocessor programs are included - SPALL calculates one-dimensional mean spalling rates of coal or rock surfaces exposed to high temperatures and generates CAVSIM input: TAB reads CAVSIM binary output files and generates ASCII tables of selected data for display; and PLOT produces dot matrix printer or HP printer plots from TAB output.« less

  16. Gasification Characteristics of Coal/Biomass Mixed Fuels

    SciTech Connect (OSTI)

    Mitchell, Reginald

    2013-09-30

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO{sub 2} was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO{sub 2}. In contrast, mixed char reactivity to H{sub 2}O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H{sub 2}O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times and off-gas compositions in gasification conditions established in a variety of commercial gasifiers. The model has the potential to provide insight on certain implications of co-firing coal and biomass in gasification and combustion application when kinetic parameters for the mixed chars are employed.

  17. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M. (Monongahela, PA)

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  18. ROTARY FILTER FINES TESTING FOR SMALL COLUMN ION EXCHANGE

    SciTech Connect (OSTI)

    Herman, D.

    2011-08-03

    SRNL was requested to quantify the amount of 'fines passage' through the 0.5 micron membranes currently used for the rotary microfilter (RMF). Testing was also completed to determine if there is any additional benefit to utilizing a 0.1 micron filter to reduce the amount of fines that could pass through the filter. Quantifying of the amount of fines that passed through the two sets of membranes that were tested was accomplished by analyzing the filtrate by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) for titanium. Even with preparations to isolate the titanium, all samples returned results of less than the instrument's detection limit of 0.184 mg/L. Test results show that the 0.5 micron filters produced a significantly higher flux while showing a negligible difference in filtrate clarity measured by turbidity. The first targeted deployment of the RMF is with the Small Column Ion Exchange (SCIX) at the Savannah River Site (SRS). SCIX uses crystalline silicotitanate (CST) to sorb cesium to decontaminate a clarified salt solution. The passage of fine particles through the filter membranes in sufficient quantities has the potential to impact the downstream facilities. To determine the amount of fines passage, a contract was established with SpinTek Filtration to operate a 3-disk pilot scale unit with prototypic filter disk and various feeds and two different filter disk membranes. SpinTek evaluated a set of the baseline 0.5 micron filter disks as well as a set of 0.1 micron filter disks to determine the amount of fine particles that would pass the membrane and to determine the flux each set produced. The membrane on both disk sets is manufactured by the Pall Corporation (PMM 050). Each set of disks was run with three feed combinations: prototypically ground CST, CST plus monosodium titanate (MST), and CST, MST, plus Sludge Batch 6 (SB6) simulant. Throughout the testing, samples of the filtrate were collected, measured for turbidity, and sent back to SRNL for analysis to quantify the amount of fines that passed through the membrane. It should be noted that even though ground CST was tested, it will be transferred to the Defense Waste Processing Facility (DWPF) feed tank and is not expected to require filtration.

  19. Entrained-flow dry-bottom gasification of high-ash coals in coal-water slurries

    SciTech Connect (OSTI)

    E.G. Gorlov; V.G. Andrienko; K.B. Nefedov; S.V. Lutsenko; B.K. Nefedov

    2009-04-15

    It was shown that the effective use of dry ash removal during entrained-flow gasification of coal-water slurries consists in simplification of the ash storage system and utilization of coal ash, a decrease in the coal demand, a reduction in the atmospheric emissions of noxious substances and particulate matter, and abandonment of the discharge of water used for ash slurry. According to the results of gasification of coal-water slurries (5-10 {mu}m) in a pilot oxygen-blow unit at a carbon conversion of >91%, synthesis gas containing 28.5% CO, 32.5% H{sub 2}, 8.2% CO{sub 2}, 1.5% CH{sub 4}, the rest being nitrogen, was obtained. The fly ash in its chemical composition, particle size, and density meets the requirements of the European standard EN 450 as a cement additive for concrete manufacture.

  20. Vibration mills in the manufacturing technology of slurry fuel from unbeneficiated coal sludge

    SciTech Connect (OSTI)

    E.G. Gorlov; A.I. Seregin; G.S. Khodakov [Institute for Fossil Fuels, Moscow (Russia)

    2008-08-15

    Coal-water slurry fuel (CWSF) is economically viable provided that its ash content does not exceed 30% and the amount water in the fuel is at most 45%. Two impoundments were revealed that have considerable reserves of waste coal useful for commercial manufacture of CWSF without the beneficiation step. One of the CWSF manufacture steps is the comminution of coal sludge to have a particle size required by the combustion conditions. Vibration mills, which are more compact and energy-intensive that drum mills, can be used in the CWSG manufacture process. The rheological characteristics of CWSF obtained from unbeneficiated waste coal were determined.

  1. Coal production, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    Coal production in the United States in 1991 declined to a total of 996 million short tons, ending the 6-year upward trend in coal production that began in 1985. The 1991 figure is 33 million short tons below the record level of 1.029 billion short tons produced in 1990 (Table 1). Tables 2 through 33 in this report include data from mining operations that produced, prepared, and processed 10,000 or more short tons during the year. These mines yielded 993 million short tons, or 99.7 percent of the total coal production in 1991, and their summary statistics are discussed below. The majority of US coal (587 million short tons) was produced by surface mining (Table 2). Over half of all US surface mine production occurred in the Western Region, though the 60 surface mines in this area accounted for only 5 percent of the total US surface mines. The high share of production was due to the very large surface mines in Wyoming, Texas and Montana. Nearly three quarters of underground production was in the Appalachian Region, which accounted for 92 percent of underground mines. Continuous mining methods produced the most coal among those underground operations that responded. Of the 406 million short tons, 59 percent (239 million short tons) was produced by continuous mining methods, followed by longwall (29 percent, or 119 million short tons), and conventional methods (11 percent, or 46 million short tons).

  2. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

    1988-01-01

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  3. Ninth annual coal preparation, utilization, and environmental control contractors conference: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    Papers are grouped under the following sessions: compliance technology; high-efficiency preparation; characterization; advanced technologies; alternative fuels; coal utilization; industrial/commercial combustor development; combustion; superclean emission systems; carbon dioxide recovery and reuse; air toxics and fine particulates; air toxics sampling and analysis workshop; and combined poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  4. 2009 Coal Age Buyers Guide

    SciTech Connect (OSTI)

    2009-07-15

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  5. 2008 Coal Age buyers guide

    SciTech Connect (OSTI)

    2008-07-15

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  6. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P.; Bair, Wilford G.

    1992-01-01

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  7. Hydroliquefaction of coal

    DOE Patents [OSTI]

    Sze, Morgan C. (Upper Montclair, NJ); Schindler, Harvey D. (Fairlawn, NJ)

    1982-01-01

    Coal is catalytically hydroliquefied by passing coal dispersed in a liquefaction solvent and hydrogen upwardly through a plurality of parallel expanded catalyst beds, in a single reactor, in separate streams, each having a cross-sectional flow area of no greater than 255 inches square, with each of the streams through each of the catalyst beds having a length and a liquid and gas superficial velocity to maintain an expanded catalyst bed and provide a Peclet Number of at least 3. If recycle is employed, the ratio of recycle to total feed (coal and liquefaction solvent) is no greater than 2:1, based on volume. Such conditions provide for improved selectivity to liquid product to thereby reduce hydrogen consumption. The plurality of beds are formed by partitions in the reactor.

  8. Healy Clean Coal Project

    SciTech Connect (OSTI)

    1997-12-31

    The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

  9. Sustainable development with clean coal

    SciTech Connect (OSTI)

    1997-08-01

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  10. Coal Market Module - NEMS Documentation

    Reports and Publications (EIA)

    2014-01-01

    Documents the objectives and the conceptual and methodological approach used in the development of the National Energy Modeling System's (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 2014 (AEO2014). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM's two submodules. These are the Coal Production Submodule (CPS) and the Coal Distribution Submodule (CDS).

  11. Method for simultaneous use of a single additive for coal flotation, dewatering, and reconstitution

    DOE Patents [OSTI]

    Wen, Wu-Wey (Murrysville, PA); Gray, McMahan L. (Pittsburgh, PA); Champagne, Kenneth J. (Finleyville, PA)

    1995-01-01

    A single dose of additive contributes to three consecutive fine coal unit operations, i.e., flotation, dewatering and reconstitution, whereby the fine coal is first combined with water in a predetermined proportion so as to formulate a slurry. The slurry is then mixed with a heavy hydrocarbon-based emulsion in a second predetermined proportion and at a first predetermined mixing speed and for a predetermined period of time. The conditioned slurry is then cleaned by a froth flotation method to form a clean coal froth and then the froth is dewatered by vacuum filtration or a centrifugation process to form reconstituted products that are dried to dust-less clumps prior to combustion.

  12. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  13. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    reports Coal Transportation Rates to the Electric Power Sector With Data through 2014 | Release Date: February 23, 2016 | Next Release Date: January 2017 | Previous Data Years Year: 2013 2011 2010 2008 2002 Go Background and Methodology The data in the tables are based on primary data collected by EIA from plant owners and operators on the Form EIA-923, "Power Plant Operations Report" (EIA-923 Data) and supplement data and analysis of coal transportation costs released by EIA in June

  14. Clean Coal Power Initiative

    SciTech Connect (OSTI)

    Doug Bartlett; Rob James; John McDermott; Neel Parikh; Sanjay Patnaik; Camilla Podowski

    2006-03-31

    This report is the fifth quarterly Technical Progress Report submitted by NeuCo, Incorporated, under Award Identification Number, DE-FC26-04NT41768. This award is part of the Clean Coal Power Initiative (''CCPI''), the ten-year, $2B initiative to demonstrate new clean coal technologies in the field. This report is one of the required reports listed in Attachment B Federal Assistance Reporting Checklist, part of the Cooperative Agreement. The report covers the award period January 1, 2006 - March 31, 2006 and NeuCo's efforts within design, development, and deployment of on-line optimization systems during that period.

  15. Coal and Coal-Biomass to Liquids FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal and Coal-Biomass to Liquids FAQs faq-header-big.jpg BASICS Q: How are gasoline and diesel fuel made from coal? A: Gasoline and diesel fuels can be produced from coal in two distinct processes: Indirect Liquefaction and Direct Liquefaction. In Indirect Liquefaction, coal is first gasified to produce synthesis gas (syngas for short), which is a mixture containing primarily hydrogen (H2) and carbon monoxide (CO) gases. The Fischer-Tropsch (FT) synthesis is a commercial process that can be used

  16. Process for coal liquefaction employing selective coal feed

    DOE Patents [OSTI]

    Hoover, David S. (New Tripoli, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

  17. Focusing particle concentrator with application to ultrafine particles

    DOE Patents [OSTI]

    Hering, Susanne; Lewis, Gregory; Spielman, Steven R.

    2013-06-11

    Technology is presented for the high efficiency concentration of fine and ultrafine airborne particles into a small fraction of the sampled airflow by condensational enlargement, aerodynamic focusing and flow separation. A nozzle concentrator structure including an acceleration nozzle with a flow extraction structure may be coupled to a containment vessel. The containment vessel may include a water condensation growth tube to facilitate the concentration of ultrafine particles. The containment vessel may further include a separate carrier flow introduced at the center of the sampled flow, upstream of the acceleration nozzle of the nozzle concentrator to facilitate the separation of particle and vapor constituents.

  18. Biochemical transformation of coals

    DOE Patents [OSTI]

    Lin, Mow S. (Rocky Point, NY); Premuzic, Eugene T. (East Moriches, NY)

    1999-03-23

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed.

  19. Biochemical transformation of coals

    DOE Patents [OSTI]

    Lin, M.S.; Premuzic, E.T.

    1999-03-23

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed. 7 figs.

  20. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  1. Catalytic coal hydroliquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA)

    1984-01-01

    A process is described for the liquefaction of coal in a hydrogen donor solvent in the presence of hydrogen and a co-catalyst combination of iron and a Group VI or Group VIII non-ferrous metal or compounds of the catalysts.

  2. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

    1986-01-01

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  3. Coal Preparation Plant Simulation

    Energy Science and Technology Software Center (OSTI)

    1992-02-25

    COALPREP assesses the degree of cleaning obtained with different coal feeds for a given plant configuration and mode of operation. It allows the user to simulate coal preparation plants to determine an optimum plant configuration for a given degree of cleaning. The user can compare the performance of alternative plant configurations as well as determine the impact of various modes of operation for a proposed configuration. The devices that can be modelled include froth flotationmore » devices, washers, dewatering equipment, thermal dryers, rotary breakers, roll crushers, classifiers, screens, blenders and splitters, and gravity thickeners. The user must specify the plant configuration and operating conditions and a description of the coal feed. COALPREP then determines the flowrates within the plant and a description of each flow stream (i.e. the weight distribution, percent ash, pyritic sulfur and total sulfur, moisture, BTU content, recoveries, and specific gravity of separation). COALPREP also includes a capability for calculating the cleaning cost per ton of coal. The IBM PC version contains two auxiliary programs, DATAPREP and FORLIST. DATAPREP is an interactive preprocessor for creating and editing COALPREP input data. FORLIST converts carriage-control characters in FORTRAN output data to ASCII line-feed (X''0A'') characters.« less

  4. Coal Preparation Plant Simulation

    Energy Science and Technology Software Center (OSTI)

    1992-02-25

    COALPREP assesses the degree of cleaning obtained with different coal feeds for a given plant configuration and mode of operation. It allows the user to simulate coal preparation plants to determine an optimum plant configuration for a given degree of cleaning. The user can compare the performance of alternative plant configurations as well as determine the impact of various modes of operation for a proposed configuration. The devices that can be modelled include froth flotationmore » devices, washers, dewatering equipment, thermal dryers, rotary breakers, roll crushers, classifiers, screens, blenders and splitters, and gravity thickeners. The user must specify the plant configuration and operating conditions and a description of the coal feed. COALPREP then determines the flowrates within the plant and a description of each flow stream (i.e. the weight distribution, percent ash, pyritic sulfur and total sulfur, moisture, BTU content, recoveries, and specific gravity of separation). COALPREP also includes a capability for calculating the cleaning cost per ton of coal.« less

  5. Annual Coal Distribution Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    and Foreign Distribution of U.S. Coal by State of Origin, 2001 State Region Domestic Foreign Total Alabama 14,828 4,508 19,336 Alaska 825 698 1,524 Arizona 13,143 - 13,143...

  6. Coal liquefaction process

    DOE Patents [OSTI]

    Maa, Peter S.

    1978-01-01

    A process for liquefying a particulate coal feed to produce useful petroleum-like liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone, or stage to the next succeeding higher temperature zone, or stage, of the series. The temperature within the initial zone, or stage, of the series is maintained about 70.degree. F and 750.degree. F and the temperature within the final zone, or stage, is maintained between about 750.degree. F and 950.degree. F. The residence time within the first zone, or stage, ranges, generally, from about 20 to about 150 minutes and residence time within each of the remaining zones, or stages, of the series ranges, generally, from about 10 minutes to about 70 minutes. Further steps of the process include: separating the product from the liquefaction zone into fractions inclusive of a liquid solvent fraction; hydrotreating said liquid solvent fraction in a hydrogenation zone; and recycling the hydrogenated liquid solvent mixture to said coal liquefaction zones.

  7. Lignin-assisted coal depolymerization

    SciTech Connect (OSTI)

    Lalvani, S.B.

    1991-01-01

    Previous research has shown that addition of lignin-derived liquids to coal stirred in tetralin under mild reaction conditions (375{degree}C and 300--500 psig) results in a marked enhancement in the rate of coal depolymerization. A mathematical model was developed to study the kinetics of coal depolymerization in the presence of liquid-derived liquids. In the present study, a reaction pathway was formulated to explain the enhancement in coal depolymerization due to lignin (solid) addition. The model postulated assumes that the products of lignin obtained during thermolysis interact with the reactive moieties present in coal while simultaneous depolymerization of coal occurs. A good fit between the experimental data and the kinetic model was found. The results show that in addition to the enhancement in the rate of coal depolymerization, lignin also reacts (and enhances the extent of depolymerization of coal) with those reaction sites in coal that are not susceptible to depolymerization when coal alone is reacted in tetralin under identical reaction conditions. Additional work is being carried out to determine a thorough materials balance on the lignin-assisted coal depolymerization process. A number of liquid samples have been obtained which are being studied for their stability in various environments. 5 refs., 4 figs., 1 tab.

  8. National Coal Quality Inventory (NACQI)

    SciTech Connect (OSTI)

    Robert Finkelman

    2005-09-30

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  9. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  10. Coal mine methane global review

    SciTech Connect (OSTI)

    2008-07-01

    This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

  11. Annual Coal Distribution Report - Energy Information Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    current Coal Distribution Report Annual Coal Distribution Report Release Date: April 16, 2015 | Next Release Date: January 2016 | full report | Revision/Correction Archive Domestic coal distribution by origin State, destination State, consumer category, method of transportation; foreign coal distribution by major coal-exporting state and method of transportation; and domestic and foreign coal distribution by origin state. Year Domestic and foreign distribution of U.S. coal by State of origin

  12. Appalachian recapitalization: United Coal comes full circle

    SciTech Connect (OSTI)

    Fiscor, S.

    2006-05-15

    The article recounts the recent history of the United Coal Co. which exited from the coal business between 1992 and 1997 and has recently returned. More coal reserves have been added by its four companies Sapphire Coal, Carter Roag Coal, Pocahontas Coal and Wellmore, bringing the grand total to 222.6 Mtons. United Coal's developments and investment strategy are discussed. The company headquarters are in Bristol, Va., USA. 1 tab., 7 photos.

  13. Are surface coal mine sediment ponds working

    SciTech Connect (OSTI)

    Poe, M.L.; Betson, R.P.

    1985-12-09

    Flowrates and storm generated water quality data were collected at sedimentation ponds on four surface mines in the states of Pennsylvania, Maryland, and West Virginia. The water quality data were analyzed for suspended solids and settleable solids content, and particle size distribution. The results were compared to the effluent limitations guidelines for total suspended solids as promulgated under the Clean Water Act for Coal Mining Point Source Category and adopted under the Surface Mine Control and Reclamation Act of 1977 and the resulting state regulatory programs. 3 references, 1 figure, 2 tables.

  14. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  15. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  16. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  17. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  18. Flotation machine and process for removing impurities from coals

    DOE Patents [OSTI]

    Szymocha, K.; Ignasiak, B.; Pawlak, W.; Kulik, C.; Lebowitz, H.E.

    1997-02-11

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal. 4 figs.

  19. Flotation machine and process for removing impurities from coals

    DOE Patents [OSTI]

    Szymocha, Kazimierz (Edmonton, CA); Ignasiak, Boleslaw (Edmonton, CA); Pawlak, Wanda (Edmonton, CA); Kulik, Conrad (Newark, CA); Lebowitz, Howard E. (Mountain View, CA)

    1995-01-01

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  20. Flotation machine and process for removing impurities from coals

    DOE Patents [OSTI]

    Szymocha, Kazimierz (Edmonton, CA); Ignasiak, Boleslaw (Edmonton, CA); Pawlak, Wanda (Edmonton, CA); Kulik, Conrad (Newark, CA); Lebowitz, Howard E. (Mountain View, CA)

    1997-01-01

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  1. Flotation machine and process for removing impurities from coals

    DOE Patents [OSTI]

    Szymocha, K.; Ignasiak, B.; Pawlak, W.; Kulik, C.; Lebowitz, H.E.

    1995-12-05

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other mineral particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal. 4 figs.

  2. Moist caustic leaching of coal

    DOE Patents [OSTI]

    Nowak, Michael A. (Elizabeth, PA)

    1994-01-01

    A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

  3. Summary of coal export project

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    Through the international coal project and related activities, SSEB has called attention to the problems and potential of the US coal industry. The program has provided an excellent format for frank discussions on the problems facing US coal exports. Every effort must be made to promote coal and its role in the southern economy. Coal is enjoying its best years in the domestic market. While the export market is holding its own, there is increased competition in the world market from Australia, Columbia, China and, to a lesser extent, Russia. This is coming at a time when the US has enacted legislation and plans are underway to deepen ports. In addition there is concern that increased US coal and electricity imports are having a negative impact on coal production. These limiting factors suggest the US will remain the swing supplier of coal on the world market in the near future. This presents a challenge to the US coal and related industry to maintain the present market and seek new markets as well as devote research to new ways to use coal more cleanly and efficiently.

  4. TOXIC SUBSTANCES FROM COAL COMBUSTION-A COMPREHENSIVE ASSESSMENT

    SciTech Connect (OSTI)

    C.L. Senior; F. Huggins; G.P. Huffman; N. Shah; N. Yap; J.O.L. Wendt; W. Seames; M.R. Ames; A.F. Sarofim; S. Swenson; J.S. Lighty; A. Kolker; R. Finkelman; C.A. Palmer; S.J. Mroczkowski; J.J. Helble; R. Mamani-Paco; R. Sterling; G. Dunham; S. Miller

    2001-06-30

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the National Energy Technology Laboratory (NETL), the Electric Power Research Institute, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NOx combustion systems, and new power generation plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). The work discussed in this report covers the Phase II program. Five coals were studied (three in Phase I and two new ones in Phase II). In this work UK has used XAFS and Moessbauer spectroscopies to characterize elements in project coals. For coals, the principal use was to supply direct information about certain hazardous and other key elements (iron) to complement the more complete indirect investigation of elemental modes of occurrence being carried out by colleagues at USGS. Iterative selective leaching using ammonium acetate, HCl, HF, and HNO3, used in conjunction with mineral identification/quantification, and microanalysis of individual mineral grains, has allowed USGS to delineate modes of occurrence for 44 elements. The Phase II coals show rank-dependent systematic differences in trace-element modes of occurrence. The work at UU focused on the behavior of trace metals in the combustion zone by studying vaporization from single coal particles. The coals were burned at 1700 K under a series of fuel-rich and oxygen-rich conditions. The data collected in this study will be applied to a model that accounts for the full equilibrium between carbon monoxide and carbon dioxide. The model also considers many other reactions taking place in the combustion zone, and involves the diffusion of gases into the particle and combustion products away from the particle. A comprehensive study has been conducted at UA to investigate the post-combustion partitioning of trace elements during large-scale combustion of pulverized coal combustion. For many coals, there are three distinct particle regions developed by three separate mechanisms: (1) a submicron fume, (2) a micron-sized fragmentation region, and (3) a bulk (>3 {micro}m) fly ash region. The controlling partitioning mechanisms for trace elements may be different in each of the three particle regions. A substantial majority of semi-volatile trace elements (e.g., As, Se, Sb, Cd, Zn, Pb) volatilize during combustion. The most common partitioning mechanism for semi-volatile elements is reaction with active fly ash surface sites. Experiments conducted under this program at UC focused on measuring mercury oxidation under cooling rates representative of the convective section of a coal-fired boiler to determine the extent of homogeneous mercury oxidation under these conditions. In fixed bed studies at EERC, five different test series were planned to evaluate the effects of temperature, mercury concentration, mercury species, stoichiometric ratio of combustion air, and ash source. Ash samples generated at UA and collected from full-scale power plants were evaluated. Extensive work was carried out at UK during this program to develop new methods for identification of mercury species in fly ash and sorbents. We demonstrated the usefulness of XAFS spectroscopy for the speciation of mercury captured on low-temperature sorbents from combustion flue gases and dev

  5. Process for changing caking coals to noncaking coals

    DOE Patents [OSTI]

    Beeson, Justin L. (Woodridge, IL)

    1980-01-01

    Caking coals are treated in a slurry including alkaline earth metal hydroxides at moderate pressures and temperatures in air to form noncaking carbonaceous material. Hydroxides such as calcium hydroxide, magnesium hydroxide or barium hydroxide are contemplated for slurrying with the coal to interact with the agglomerating constituents. The slurry is subsequently dewatered and dried in air at atmospheric pressure to produce a nonagglomerating carbonaceous material that can be conveniently handled in various coal conversion and combustion processes.

  6. Low severity coal liquefaction promoted by cyclic olefins

    SciTech Connect (OSTI)

    Curtis, C.W.

    1992-07-27

    Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

  7. Navajo Coal Combustion and Respiratory Health Near Shiprock, New Mexico

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bunnell, Joseph E.; Garcia, Linda V.; Furst, Jill M.; Lerch, Harry; Olea, Ricardo A.; Suitt, Stephen E.; Kolker, Allan

    2010-01-01

    Indoormore » air pollution has been identified as a major risk factor for acute and chronic respiratory diseases throughout the world. In the sovereign Navajo Nation, an American Indian reservation located in the Four Corners area of the USA, people burn coal in their homes for heat. To explore whether/how indoor coal combustion might contribute to poor respiratory health of residents, this study examined respiratory health data, identified household risk factors such as fuel and stove type and use, analyzed samples of locally used coal, and measured and characterized fine particulate airborne matter inside selected homes. In twenty-five percent of homes surveyed coal was burned in stoves not designed for that fuel, and indoor air quality was frequently found to be of a level to raise concerns. The average winter 24-hour PM 2.5 concentration in 20 homes was 36.0  μ g/ m 3 . This is the first time that PM 2.5 has been quantified and characterized inside Navajo reservation residents' homes.« less

  8. Coal-Producing Region

    Gasoline and Diesel Fuel Update (EIA)

    . Coal Production by State (thousand short tons) Year to Date Coal-Producing Region and State July - September 2015 April - June 2015 July - September 2014 2015 2014 Percent Change Alabama 3,192 3,504 4,331 10,718 12,345 -13.2 Alaska 255 345 372 866 1,178 -26.5 Arizona 1,762 1,912 2,165 5,429 5,979 -9.2 Arkansas 26 27 18 74 58 27.4 Colorado 5,123 5,078 6,574 15,464 18,367 -15.8 Illinois 13,967 13,360 14,816 44,105 42,575 3.6 Indiana 9,124 8,577 9,805 27,164 29,328 -7.4 Kansas 42 49 5 144 16 NM

  9. Exploration for deep coal

    SciTech Connect (OSTI)

    2008-12-15

    The most important factor in safe mining is the quality of the roof. The article explains how the Rosebud Mining Co. conducts drilling and exploration in 11 deep coal mine throughout Pennsylvania and Ohio. Rosebud uses two Atlas Copco CS10 core drilling rigs mounted on 4-wheel drive trucks. The article first appeared in Atlas Copco's in-house magazine, Deep Hole Driller. 3 photos.

  10. COAL & POWER SYSTEMS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    COAL & POWER SYSTEMS STRATEGIC & MULTI-YEAR PROGRAM PLANS U.S. DEPARTMENT OF ENERGY * OFFICE OF FOSSIL ENERGY GREENER, SOONER... THROUGH TECHNOLOGY INTRODUCTION .......... i-1 STRATEGIC PLAN ........ 1-1 PROGRAM PLANS Vision 21 .......................... 2-1 Central Power Systems ...... 3-1 Distributed Generation ..... 4-1 Fuels ................................ 5-1 Carbon Sequestration ....... 6-1 Advanced Research ........... 7-1 TABLE OF CONTENTS STRATEGIC & MULTI-YEAR PROGRAM

  11. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  12. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D.

    1985-01-01

    The coal liquefaction process disclosed uses three stages. The first stage is a liquefaction. The second and third stages are hydrogenation stages at different temperatures and in parallel or in series. One stage is within 650.degree.-795.degree. F. and optimizes solvent production. The other stage is within 800.degree.-840.degree. F. and optimizes the C.sub.5 -850.degree. F. product.

  13. Assessment of underground coal gasification in bituminous coals: catalog of bituminous coals and site selection. Appendix A. National coal resource data system: Ecoal, Wcoal, and Bmalyt. Final report, Phase I. [Bituminous coal; by state; coal seam depth and thickness; identification

    SciTech Connect (OSTI)

    1982-01-31

    Appendix A is a catalog of the bituminous coal in 29 states of the contiguous United States which contain identified bituminous coal resources.

  14. Appalachian Clean Coal Technology Consortium. Final report, October 10, 1994--March 31, 1997

    SciTech Connect (OSTI)

    Yoon, R.H.; Parekh, B.K.; Meloy, T.

    1997-12-31

    The Appalachian Clean Coal Technology Consortium is a group comprised of representatives from the Virginia Polytechnic Institute and State University, West Virginia University, and the University of Kentucky Center for Applied Energy Research, that was formed to pursue research in areas related to the treatment and processing of fine coal. Each member performed research in their respective areas of expertise and the report contained herein encompasses the results that were obtained for the three major tasks that the Consortium undertook from October, 1994 through March, 1997. In the first task, conducted by Virginia Polytechnic Institute, novel methods (both mechanical and chemical) for dewatering fine coal were examined. In the second task, the Center for Applied Energy Research examined novel approaches for destabilization of [highly stable] flotation froths. And in the third task, West Virginia University developed physical and mathematical models for fine coal spirals. The Final Report is written in three distinctive chapters, each reflecting the individual member`s task report. Recommendations for further research in those areas investigated, as well as new lines of pursuit, are suggested.

  15. Zero emission coal

    SciTech Connect (OSTI)

    Ziock, H.; Lackner, K.

    2000-08-01

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  16. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  17. Environmental development plan: coal liquefaction

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    This Environmental Development plan (EDP) examines environmental concerns that are being evaluated for the technologies in DOE's Coal Liquefaction Program. It identifies the actions that are planned or underway to resolve these concerns while the technologies are being developed. Research is scheduled on the evaluation and mitigation of potential environmental impacts. This EDP updates the FY 1977 Coal Liquefaction Program EDP. Chapter II describes the DOE Coal Liquefaction Program and focuses on the Solvent Refined Coal (SRC), H-Coal, and Exxon donor solvent (EDS) processes because of their relatively advanced R and D stages. The major unresolved environmental concerns associated with the coal liquefaction subactivities and projects are summarized. The concerns were identified in the 1977 EDP's and research was scheduled to lead to the resolution of the concerns. Much of this research is currently underway. The status of ongoing and planned research is shown in Table 4-1.

  18. Particle Astrophysics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Particle Astrophysics Particle Astrophysics Understanding discoveries at the Energy, Intensity, and Cosmic Frontiers Get Expertise Rajan Gupta (505) 667-7664 Email Bruce Carlsten (505) 667-5657 Email Particle Astrophysics Stars offer unique laboratories for particle physics. They can be sensitive to minute interactions of neutrinos, as well as to other, hypothetical weakly interacting particles. The origin of this sensitivity lies in the mechanism of stellar evolution: it can be sped up, or even

  19. "Annual Coal Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Annual Coal Report Data Released: January 20, 2015 Data for: 2013 Re-Release Date: April 23, 2015 (CORRECTION) Annual Coal Report 2013 Correction/Update April 23, 2015 The Annual Coal Report (ACR) 2013 has been republished in order to update electric power sector data with finalized data. Contact: JenAlyse Arena Phone: 202-586-4866 Email: JenAlyse Arena Fax: 202-287-1944

  20. Coal Data Publication Revision Policy

    Gasoline and Diesel Fuel Update (EIA)

    Publication Revision Policy IF this occurs: THEN Survey Manager determines impact: WHAT happens next to the database and in our coal reports: Respondent provides data that are clearly incorrect or revised data for any period in the current reporting year. If National level percentage is > 1%, or If Regional level percentage is > 5%, or If State level percentage is > 10%. Quarterly Coal Report (QCR) and Quarterly Coal Distribution Report (QCDR) will be reposted no further back than the

  1. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  2. Gasification Studies Task 4 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Whitty, Kevin; Fletcher, Thomas; Pugmire, Ronald; Smith, Philip; Sutherland, James; Thornock, Jeremy; Hunsacker, Isaac; Li, Suhui; Kelly, Kerry; Puntai, Naveen; Reid, Charles; Schurtz, Randy

    2011-10-01

    A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical (Subtask 4.4) and physical (Subtask 4.5) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation.

  3. Low-rank coal oil agglomeration

    DOE Patents [OSTI]

    Knudson, Curtis L.; Timpe, Ronald C.

    1991-01-01

    A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

  4. Carbon Dioxide Emission Factors for Coal

    Reports and Publications (EIA)

    1994-01-01

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  5. Clean Coal Technologies | Open Energy Information

    Open Energy Info (EERE)

    of harmful pollutants from coal, including mercury, sulfur and coal tars. References: Clean Coal Technologies1 This article is a stub. You can help OpenEI by expanding it....

  6. Particle separation

    DOE Patents [OSTI]

    Moosmuller, Hans (Reno, NV); Chakrabarty, Rajan K. (Reno, NV); Arnott, W. Patrick (Reno, NV)

    2011-04-26

    Embodiments of a method for selecting particles, such as based on their morphology, is disclosed. In a particular example, the particles are charged and acquire different amounts of charge, or have different charge distributions, based on their morphology. The particles are then sorted based on their flow properties. In a specific example, the particles are sorted using a differential mobility analyzer, which sorts particles, at least in part, based on their electrical mobility. Given a population of particles with similar electrical mobilities, the disclosed process can be used to sort particles based on the net charge carried by the particle, and thus, given the relationship between charge and morphology, separate the particles based on their morphology.

  7. FE Clean Coal News | Department of Energy

    Energy Savers [EERE]

    Clean Coal News FE Clean Coal News RSS December 2, 2015 DOE Selects Projects To Enhance Its Research into Recovery of Rare Earth Elements from Coal and Coal Byproducts The U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) has selected 10 projects to receive funding for research in support of the lab's program on Recovery of Rare Earth Elements from Coal and Coal Byproducts. The selected research projects will further program goals by focusing on the development of

  8. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 2 (Jan 2016) Archived Editions: Coal Gasification and Transportation Fuels Quarterly News, Vol. 2, Issue 1 (Oct 2015) Coal Gasification and Transportation Fuels Quarterly News, Vol. 1, Issue 4 (July 2015) Coal Gasification and Transportation Fuels Quarterly News, Vol. 1, Issue 3 (Apr 2015) Coal Gasification and Transportation Fuels Quarterly News, Vol. 1,

  9. Quarterly Coal Distribution Report - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    Quarterly Coal Distribution Report Release Date: March 9, 2016 | Next Release Date: May 2016 | full report The Quarterly Coal Distribution Report (QCDR) provides detailed U.S. domestic coal distribution data by coal origin state, coal destination state, mode of transportation, and consuming sector. Quarterly data for all years are preliminary and will be superseded by the release of the corresponding "Annual Coal Distribution Report." Highlights for the fourth quarter 2014: Total

  10. Quarterly Coal Report - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    Coal Glossary › FAQS › Overview Data Coal Data Browser new! Summary Prices Reserves Consumption Production Stocks Imports, exports & distribution Coal transportation rates International All coal data reports Analysis & Projections Major Topics Most popular Consumption Environment Imports & exports Industry characteristics Prices Production Projections Recurring Reserves Stocks All reports Browse by Tag Alphabetical Frequency Tag Cloud ‹ See all Coal Reports Quarterly Coal

  11. EIA - Weekly U.S. Coal Production

    Gasoline and Diesel Fuel Update (EIA)

    Coal Glossary › FAQS › Overview Data Coal Data Browser new! Summary Prices Reserves Consumption Production Stocks Imports, exports & distribution Coal transportation rates International All coal data reports Analysis & Projections Major Topics Most popular Consumption Environment Imports & exports Industry characteristics Prices Production Projections Recurring Reserves Stocks All reports Browse by Tag Alphabetical Frequency Tag Cloud Weekly U.S. Coal Production Coal producing

  12. Stabilizing soft fine-grained soils with fly ash

    SciTech Connect (OSTI)

    Edil, T.B.; Acosta, H.A.; Benson, C.H.

    2006-03-15

    The objective of this study was to evaluate the effectiveness of self-cementing fly ashes derived from combustion of subbituminous coal at electric power plants for stabilization of soft fine-grained soils. California bearing ratio (CBR) and resilient modulus (M{sub r}) tests were conducted on mixtures prepared with seven soft fine-grained soils (six inorganic soils and one organic soil) and four fly ashes. The soils were selected to represent a relatively broad range of plasticity, with plasticity indices ranging between 15 and 38. Two of the fly ashes are high quality Class C ashes (per ASTM C 618) that are normally used in Portland cement concrete. The other ashes are off-specification ashes, meaning they do not meet the Class C or Class F criteria in ASTM C 618. Tests were conducted on soils and soil-fly ash mixtures prepared at optimum water content (a standardized condition), 7% wet of optimum water content (representative of the typical in situ condition in Wisconsin), and 9-18% wet of optimum water content (representative of a very wet in situ condition). Addition of fly ash resulted in appreciable increases in the CBR and M{sub r} of the inorganic soils. For water contents 7% wet of optimum, CBRs of the soils alone ranged between 1 and 5. Addition of 10% fly ash resulted in CBRs ranging between 8 and 17, and 18% fly ash resulted in CBRs between 15 and 31. Similarly, M{sub r} of the soil alone ranged between 3 and 15 MPa at 7% wet of optimum, whereas addition of 10% fly ash resulted in M{sub r} between 12 and 60 MPa and 18% fly ash resulted in M{sub r} between 51 and 106 MPa. In contrast, except for one fly ash, addition of fly ash generally had little effect on CBR or M{sub r} of the organic soil.

  13. coal contacts | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal contacts Strategic Center for Coal Director: Sean Plasynski 412-386-4867 Senior Management & Technical Advisor: Gregory Kawalkin 412-386-6135 Senior Management & Technical ...

  14. FE Clean Coal News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity from Innovative DOE-Supported Clean Coal Project An innovative clean coal technology project in Texas will supply electricity to the largest municipally owned...

  15. FMI NewCoal | Open Energy Information

    Open Energy Info (EERE)

    developer focused on upgrading low rank coals to improve combustion efficiency and reduce production of greenhouse emissions for coal fired utility and industrial power generation...

  16. American Clean Coal Fuels | Open Energy Information

    Open Energy Info (EERE)

    American Clean Coal Fuels Retrieved from "http:en.openei.orgwindex.php?titleAmericanCleanCoalFuels&oldid768408" Categories: Organizations Energy Generation Organizations...

  17. Jamestown Oxy Coal Alliance | Open Energy Information

    Open Energy Info (EERE)

    Oxy Coal Alliance Jump to: navigation, search Name: Jamestown Oxy-Coal Alliance Place: New York Product: The Jamestown Alliance has been formed to develop a CCS demonstration...

  18. EIA - Weekly U.S. Coal Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rounding. Bituminous and Lignite Total includes bituminous coal, subbituminous coal, and lignite, and Anthracite Total includes Pennsylvania anthracite. The States in...

  19. SciTech Connect: "clean coal"

    Office of Scientific and Technical Information (OSTI)

    clean coal" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "clean coal" Semantic Semantic Term Title: Full Text: Bibliographic Data: Creator ...

  20. Immobilization of Rocky Flats Graphite Fines Residue

    SciTech Connect (OSTI)

    Rudisill, T.S.

    1999-04-06

    The development of the immobilization process for graphite fines has proceeded through a series of experimental programs. The experimental procedures and results from each series of experiments are discussed in this report.

  1. Measurement and modeling of advanced coal conversion processes

    SciTech Connect (OSTI)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G. ); Smoot, L.D.; Brewster, B.S. )

    1992-01-01

    The objectives of this proposed study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. This report describes progress during twenty second quarter of the program. Specifically, the paper discusses progress in three task areas: (1) Submodel development and evaluation: coal to char chemistry submodel; fundamental high-pressure reaction rate data; secondary reaction of pyrolysis product and burnout submodels; ash physics and chemistry submodel; large particle submodels; large char particle oxidation at high pressures; and SO[sub x]-NO[sub x] submodel development and evaluation; (2) Comprehensive model development and evaluation: integration of advanced submodels into entrained-flow code, with evaluation and documentation; comprehensive fixed-bed modeling review, development evaluation and implementation; and generalized fuels feedstock submodel; and (3) Application of integrated codes: application of generalized pulverized coal comprehensive code and application of fixed-bed code.

  2. Coal: Energy for the future

    SciTech Connect (OSTI)

    1995-05-01

    This report was prepared in response to a request by the US Department of energy (DOE). The principal objectives of the study were to assess the current DOE coal program vis-a-vis the provisions of the Energy Policy Act of 1992 (EPACT), and to recommend the emphasis and priorities that DOE should consider in updating its strategic plan for coal. A strategic plan for research, development, demonstration, and commercialization (RDD and C) activities for coal should be based on assumptions regarding the future supply and price of competing energy sources, the demand for products manufactured from these sources, technological opportunities, and the need to control the environmental impact of waste streams. These factors change with time. Accordingly, the committee generated strategic planning scenarios for three time periods: near-term, 1995--2005; mid-term, 2006--2020; and, long-term, 2021--2040. The report is divided into the following chapters: executive summary; introduction and scope of the study; overview of US DOE programs and planning; trends and issues for future coal use; the strategic planning framework; coal preparation, coal liquid mixtures, and coal bed methane recovery; clean fuels and specialty products from coal; electric power generation; technology demonstration and commercialization; advanced research programs; conclusions and recommendations; appendices; and glossary. 174 refs.

  3. Coal Age buyers guide 2007

    SciTech Connect (OSTI)

    2007-07-15

    The buyers guide provides a comprehensive list of more than 1,200 suppliers that provide equipment and services to US coal mine and coal preparation plants, mainly based in the USA. Telephone numbers of companies are provided for each product category.

  4. Coal Age buyers guide 2005

    SciTech Connect (OSTI)

    2005-07-01

    The Buyers Guide provides a comprehensive list of more than 1,200 suppliers that provide equipment and services to US coal mine and coal preparation plants, mainly based in the USA. Telephone numbers of companies are provided for each product category.

  5. Coal Age buyers guide 2006

    SciTech Connect (OSTI)

    2006-07-15

    The Buyers Guide provides a comprehensive list of more than 1,200 suppliers that provide equipment and services to US coal mine and coal preparation plants, mainly based in the USA. Telephone numbers of companies are provided for each product category.

  6. Land reclamation beautifies coal mines

    SciTech Connect (OSTI)

    Coblentz, B.

    2009-07-15

    The article explains how the Mississippi Agricultural and Forestry Experiments station, MAFES, has helped prepare land exploited by strip mining at North American Coal Corporation's Red Hills Mine. The 5,800 acre lignite mine is over 200 ft deep and uncovers six layers of coal. About 100 acres of land a year is mined and reclaimed, mostly as pine plantations. 5 photos.

  7. Commercialization of clean coal technologies

    SciTech Connect (OSTI)

    Bharucha, N.

    1994-12-31

    The steps to commercialization are reviewed in respect of their relative costs, the roles of the government and business sectors, and the need for scientific, technological, and economic viability. The status of commercialization of selected clean coal technologies is discussed. Case studies related to a clean coal technology are reviewed and conclusions are drawn on the factors that determine commercialization.

  8. Centrifuge treatment of coal tar

    SciTech Connect (OSTI)

    L.A. Kazak; V.Z. Kaidalov; L.F. Syrova; O.S. Miroshnichenko; A.S. Minakov

    2009-07-15

    New technology is required for the removal of water and heavy fractions from regular coal tar. Centrifuges offer the best option. Purification of coal tar by means of centrifuges at OAO NLMK permits the production of pitch coke or electrode pitch that complies with current standards.

  9. Particle generator

    DOE Patents [OSTI]

    Hess, Wayne P.; Joly, Alan G.; Gerrity, Daniel P.; Beck, Kenneth M.; Sushko, Peter V.; Shlyuger, Alexander L.

    2005-06-28

    Energy tunable solid state sources of neutral particles are described. In a disclosed embodiment, a halogen particle source includes a solid halide sample, a photon source positioned to deliver photons to a surface of the halide, and a collimating means positioned to accept a spatially defined plume of hyperthermal halogen particles emitted from the sample surface.

  10. Liquid CO{sub 2}/Coal Slurry for Feeding Low Rank Coal to Gasifiers

    SciTech Connect (OSTI)

    Marasigan, Jose; Goldstein, Harvey; Dooher, John

    2013-09-30

    This study investigates the practicality of using a liquid CO{sub 2}/coal slurry preparation and feed system for the E-Gas™ gasifier in an integrated gasification combined cycle (IGCC) electric power generation plant configuration. Liquid CO{sub 2} has several property differences from water that make it attractive for the coal slurries used in coal gasification-based power plants. First, the viscosity of liquid CO{sub 2} is much lower than water. This means it should take less energy to pump liquid CO{sub 2} through a pipe compared to water. This also means that a higher solids concentration can be fed to the gasifier, which should decrease the heat requirement needed to vaporize the slurry. Second, the heat of vaporization of liquid CO{sub 2} is about 80% lower than water. This means that less heat from the gasification reactions is needed to vaporize the slurry. This should result in less oxygen needed to achieve a given gasifier temperature. And third, the surface tension of liquid CO{sub 2} is about 2 orders of magnitude lower than water, which should result in finer atomization of the liquid CO{sub 2} slurry, faster reaction times between the oxygen and coal particles, and better carbon conversion at the same gasifier temperature. EPRI and others have recognized the potential that liquid CO{sub 2} has in improving the performance of an IGCC plant and have previously conducted systemslevel analyses to evaluate this concept. These past studies have shown that a significant increase in IGCC performance can be achieved with liquid CO{sub 2} over water with certain gasifiers. Although these previous analyses had produced some positive results, they were still based on various assumptions for liquid CO{sub 2}/coal slurry properties. This low-rank coal study extends the existing knowledge base to evaluate the liquid CO{sub 2}/coal slurry concept on an E-Gas™-based IGCC plant with full 90% CO{sub 2} capture. The overall objective is to determine if this technology could be used to reduce the cost and improve the efficiency of IGCC plants. The study goes beyond the systems-level analyses and initial lab work that formed the bases of previous studies and includes the following tasks: performing laboratory tests to quantify slurry properties; developing an engineering design of a liquid CO{sub 2} slurry preparation and feed system; conducting a full IGCC plant techno-economic analysis for Powder River Basin (PRB) coal and North Dakota lignite in both water and liquid CO{sub 2} slurries; and identifying a technology development plan to continue the due diligence to conduct a comprehensive evaluation of this technology. The initial task included rheology tests and slurry data analyses that would increase the knowledge and understanding of maximum solids loading capability for both PRB and lignite. Higher coal concentrations have been verified in liquid CO{sub 2} over water slurries, and a coal concentration of 75% by weight in liquid CO{sub 2} has been estimated to be achievable in a commercial application. In addition, lower slurry viscosities have been verified in liquid CO{sub 2} at the same solids loading, where the liquid CO{sub 2}/coal slurry viscosity has been measured to be about a factor of 10 lower than the comparable water slurry and estimated to be less than 100 centipoise in a commercial application. In the following task, an engineering design of a liquid CO{sub 2}/coal slurry preparation and mixing system has been developed for both a batch and continuous system. The capital cost of the design has also been estimated so that it could be used in the economic analysis. An industry search and survey has been conducted to determine if essential components required to construct the feed system are available from commercial sources or if targeted R&D efforts are required. The search and survey concluded that commercial sources are available for selected components that comprise both the batch and continuous type systems. During normal operation, the fuel exits the bottom of the coal silo and is fed to a rod mill for grinding to the desired particle size. From the rod mill, the coal is transported in a dense phase pneumatic transport system to the top of a solids heat exchanger, wherein the ground coal is chilled to a low temperature (in the range of -23.3°C (-10°F)) prior to mixing with liquid CO{sub 2}. This temperature was selected based on evaluating trade-offs between refrigeration work and the cost of the system pressure boundary at various combinations of pressure and temperature that correspond to the gas/liquid phase boundary for CO{sub 2}. Electrical loads to drive the equipment comprising the liquid CO{sub 2} feed system are significantly greater than those for a water slurry system, and this effect has been captured in the technical performance analysis. In the next task, a plant-wide techno-economic analysis has been conducted for PRB coal and lignite in both liquid CO{sub 2} and water slurry feed. The IGCC cases using a liquid CO{sub 2} slurry system show reduced plant output and higher heat rate for PRB coal and for ND lignite at 90% CO{sub 2} capture. Some of these performance differences can be attributed to the higher requirement for steam for the liquid CO{sub 2} slurry cases to drive the water-gas shift reaction, thereby reducing steam turbine power generation. Other factors contributing to the calculated performance differences are the increase in parasitic loads attributable to refrigeration to produce liquid CO{sub 2} and chilled coal and the reduction in enthalpy of the inlet streams to the gasifier associated with the low temperature liquid CO{sub 2} slurry feed. The capital costs for the complete plant are slightly higher for the liquid CO{sub 2} slurry cases for PRB coal but somewhat reduced for ND lignite relative to the corresponding water slurry cases. Differences in dollar/kWe costs are higher for both coals due to the reduction in net output. The cost of electricity computed for the liquid CO{sub 2}/coal slurry cases is greater for both PRB and ND Lignite coals. It does not appear that there is any benefit to using liquid CO{sub 2}/coal slurries for feeding low rank coals to the E-Gas™ gasifier. Any incidental benefits in improved cold gas efficiency are more than compensated for in higher overall plant costs, increased complexity, and reduced power output and efficiency. The results of the study are compared with previous published analyses, and the differences in model assumptions, approach and basis are summarized. It has been concluded that the use of liquid CO{sub 2} may still prove to have a significant advantage in a different type of gasifier, i.e., single-stage entrained flow with radiant quench section, but some key questions remain unanswered that can validate the potential improvement of gasifier performance using liquid CO{sub 2} slurries. In order to provide a path to answering these questions, a technology development roadmap has been developed to resolve fundamental issues and to better define the operation aspects of using liquid CO{sub 2}/coal slurries. The fundamental issues could be resolved by conducting additional laboratory analyses consisting of: • A rheological test program to quantitatively evaluate slurry preparation and handling for liquid CO{sub 2} including experiments to evaluate preparation systems. • An experimental program on CO{sub 2}-assisted gasification in order to obtain the most relevant experimental data from drop tube furnace studies to aid in verifying the potential advantages of direct feed of liquid CO{sub 2}/coal as gasifier feedstocks. Quantifying the operational aspects of liquid CO{sub 2} slurries can best be achieved with: • An experimental program using a flow test loop to evaluate equipment performance and handling properties of liquid CO{sub 2}/coal slurries for gasifier feedstocks on a scale sufficient to predict full scale operating parameters. • Spray atomization studies necessary to evaluate the effect of atomization properties of liquid CO{sub 2}/coal slurries that could be significantly different than those of water/coal slurries.

  11. MECHANISMS AND OPTIMIZATION OF COAL COMBUSTION

    SciTech Connect (OSTI)

    Kyriacos Zygourakis

    2000-10-31

    The completed research project has made some significant contributions that will help us meet the challenges outlined in the previous section. One of the major novelties of our experimental approach involves the application of video microscopy and digital image analysis to study important transient phenomena (like particle swelling and ignitions) occurring during coal pyrolysis and combustion. Image analysis was also used to analyze the macropore structure of chars, a dominant factor in determining char reactivity and ignition behavior at high temperatures where all the commercial processes operate. By combining advanced experimental techniques with mathematical modeling, we were able to achieve the main objectives of our project. More specifically: (1) We accurately quantified the effect of several important process conditions (like pyrolysis heating rate, particle size, heat treatment temperature and soak time) on the combustion behavior of chars. These measurements shed new light into the fundamental mechanisms of important transient processes like particle swelling and ignitions. (2) We developed and tested theoretical models that can predict the ignition behavior of char particles and their burn-off times at high temperatures where intraparticle diffusional limitations are very important.

  12. Coal Reserves Data Base report

    SciTech Connect (OSTI)

    Jones, R.W.; Glass, G.B.

    1991-12-05

    The Coal Reserves Data Base (CRDB) Program is a cooperative data base development program sponsored by the Energy Information Administration (EIA). The objective of the CRDB Program is to involve knowledgeable coal resource authorities from the major coal-bearing regions in EIA's effort to update the Nation's coal reserves data. This report describes one of two prototype studies to update State-level reserve estimates. The CRDB data are intended for use in coal supply analyses and to support analyses of policy and legislative issues. They will be available to both Government and non-Government analysts. The data also will be part of the information used to supply United States energy data for international data bases and for inquiries from private industry and the public. (VC)

  13. Coals and coal requirements for the COREX process

    SciTech Connect (OSTI)

    Heckmann, H.

    1996-12-31

    The utilization of non met coals for production of liquid hot metal was the motivation for the development of the COREX Process by VAI/DVAI during the 70`s. Like the conventional ironmaking route (coke oven/blast furnace) it is based on coal as source of energy and reduction medium. However, in difference to blast furnace, coal can be used directly without the necessary prestep of cokemaking. Coking ability of coals therefore is no prerequisite of suitability. Meanwhile the COREX Process is on its way to become established in ironmaking industry. COREX Plants at ISCOR, Pretoria/South Africa and POSCO Pohang/Korea, being in operation and those which will be started up during the next years comprise already an annual coal consumption capacity of approx. 5 Mio. tonnes mtr., which is a magnitude attracting the interest of industrial coal suppliers. The increasing importance of COREX as a comparable new technology forms also a demand for information regarding process requirements for raw material, especially coal, which is intended to be met here.

  14. Determination of filter-cake thicknesses from on-line flow measurements and gas/particle transport modeling

    SciTech Connect (OSTI)

    Smith, D.H.; Powell, V.; Ibrahim, E.; Ferer, M.; Ahmadi, G.

    1996-12-31

    The use of cylindrical candle filters to remove fine ({approx}0.005 mm) particles from hot ({approx}500- 900{degrees}C) gas streams currently is being developed for applications in advanced pressurized fluidized bed combustion (PFBC) and integrated gasification combined cycle (IGCC) technologies. Successfully deployed with hot-gas filtration, PFBC and IGCC technologies will allow the conversion of coal to electrical energy by direct passage of the filtered gases into non-ruggedized turbines and thus provide substantially greater conversion efficiencies with reduced environmental impacts. In the usual approach, one or more clusters of candle filters are suspended from a tubesheet in a pressurized (P {approx_lt}1 MPa) vessel into which hot gases and suspended particles enter, the gases pass through the walls of the cylindrical filters, and the filtered particles form a cake on the outside of each filter. The cake is then removed periodically by a backpulse of compressed air from inside the filter, which passes through the filter wall and filter cake. In various development or demonstration systems the thickness of the filter cake has proved to be an important, but unknown, process parameter. This paper describes a physical model for cake and pressure buildups between cleaning backpulses, and for longer term buildups of the ``baseline`` pressure drop, as caused by incomplete filter cleaning and/or re-entrainment. When combined with operating data and laboratory measurements of the cake porosity, the model may be used to calculate the (average) filter permeability, the filter-cake thickness and permeability, and the fraction of filter-cake left on the filter by the cleaning backpulse or re-entrained after the backpulse. When used for a variety of operating conditions (e.g., different coals, sorbents, temperatures, etc.), the model eventually may provide useful information on how the filter-cake properties depend on the various operating parameters.

  15. Leatec Fine Ceramics Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Place: Tao-Yuan Hsien, Taiwan Product: Taiwan-based manufacturer of chip alumina fine ceramic substrates. The firm also produces PV junction boxes. References: Leatec Fine...

  16. Additive development for ultra-clean coal slurry fuel: Final report

    SciTech Connect (OSTI)

    Berggren, M.H.; Swanson, W.W.

    1988-05-24

    AMAX performed research to develop improved quality, cost-effective dispersing additives for coal-water slurry fuels intended for high-intensity combustion systems. Dispersants were identified on the basis of coal surface characteristics and coal-dispersant interactions. Micronized samples of physically and chemically cleaned coal feedstocks from the Eastern and Midwestern regions of the United States were examined using bulk and surface analysis techniques. Utilization of coal surface and dispersant functionality was optimized through multicomponent application of additives, pH control, and control of surface oxidation. A low-cost, low-alkali, sulfur-free dextrin compound was found to be effective in enhancing dispersion when applied to the coal surfaces as a pretreatment or with conventional dispersants as a co-additive. The cleaning method and ash content had minimal direct impact on coal surface functionality. Parameters such as internal moisture, particle size, surface area, surface oxidation, and soluble ions were the primary considerations which influenced slurry loading and additive consumption. The dispersing additive packages functioned over the range of coal types and cleaning levels investigated. The preferred additives were compatible with each other, allowing for blending to optimize performance, cost, and alkali contamination. Each additive was found to be suitable for use in applications which utilize elevated-temperature fuel delivery systems. 17 refs., 8 figs., 27 tabs.

  17. Coal Technology '80. Volume 5. Synthetic fuels from coal. Volume 6. Industrial/utility applications for coal

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The 3rd international coal utilization exhibition and conference Coal Technology '80 was held at the Astrohall, Houston, Texas, November 18-20, 1980. Volume 5 deals with coal gasification and coal liquefaction. Volume 6 deals with fluidized-bed combustion of coal, cogeneration and combined-cycle power plants, coal-fuel oil mixtures (COM), chemical feedstocks via coal gasification and Fischer-Tropsch synthesis. Thirty-six papers have been entered individually into EDB and seven also into ERA; three had been entered previously from other sources. (LTN)

  18. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. [Coal pyrite electrodes

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-01-01

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eighth quarter, wet chemical and dry oxidation tests were done on Upper Freeport coal from the Troutville [number sign]2 Mine, Clearfield County, Pennsylvania. In addition electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania.

  19. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, W.A.; Healy, F.E.; Sapienza, R.S.

    1985-04-18

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  20. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  1. Development of coal-based technologies for Department of Defense Facilities. Semiannual technical progress report, March 28, 1997--September 27, 1997

    SciTech Connect (OSTI)

    Miller, B.G.; Miller, S.F.; Morrison, J.L.

    1998-01-06

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of developing technologies which can potentially decrease DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Phase I was completed on November 1, 1995. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations included performing pilot-scale air toxics (i.e., trace elements and volatile organic compounds) testing and evaluating a ceramic filtering device on the demonstration boiler. Also, a sodium bicarbonate duct injection system was installed on the demonstration boiler. An economic analysis was conducted which investigated the benefits of decreased dependence on imported oil by using new coal combustion technologies. Work related to coal preparation and utilization was primarily focused on preparing the final report. Work in Phase III focused on coal preparation studies, pilot-scale NO{sub x} reduction studies, economic analyses of coal use, and evaluation of deeply-cleaned coal as boiler fuel. Coal preparation studies were focused on continuing activities on particle size control, physical separations, and surface-based separation processes. The evaluation of deeply-cleaned coal as boiler fuel included receiving three cleaned coals from Cyprus-Amax.

  2. Mechanism of instantaneous coal outbursts

    SciTech Connect (OSTI)

    Guan, P.; Wang, H.Y.; Zhang, Y.X.

    2009-10-15

    Thousands of mine workers die every year from mining accidents, and instantaneous coal outbursts in underground coal mines are one of the major killers. Various models for these outbursts have been proposed, but the precise mechanism is still unknown. We hypothesize that the mechanism of coal outbursts is similar to magma fragmentation during explosive volcanic eruptions; i.e., it is caused by high gas pressure inside coal but low ambient pressure on it, breaking coal into pieces and releasing the high-pressure gas in a shock wave. Hence, coal outbursts may be regarded as another type of gas-driven eruption, in addition to explosive volcanic, lake, and possible ocean eruptions. We verify the hypothesis by experiments using a shock-tube apparatus. Knowing the mechanism of coal outbursts is the first step in developing prediction and mitigation measures. The new concept of gas-driven solid eruption is also important to a better understanding of salt-gas outbursts, rock-gas outbursts, and mud volcano eruptions.

  3. POC-scale testing of a dry triboelectrostatic separator for fine coal cleaning

    SciTech Connect (OSTI)

    R.-H. Yoon; G.H. Luttrell; G.T. Adel; A.D. Walters

    1999-07-01

    The Proof-of-Concept (POC) triboelectrostatic separator (TES) has now been successfully installed at the Virginia Tech pilot-plant. As a result, most of the personnel assigned to this project during the past quarter have been performing work elements associated with the installation and shakedown testing of the electrostatic separator, tribocharger system, product conveying systems and nitrogen purge system (Tasks 4, 5.1 and 5.2). A representative from Carpco also carried out training in the operating features of the unit during the past month. Most of the shakedown test work has now been successfully completed. However, several minor operational problems associated with the pilot-scale equipment are currently in the process of being resolved.

  4. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.-H. Yoon; G.H. Luttrell; G.T. Adel; A.D. Walters

    1999-04-01

    The project has reached the point where the Proof of Concept (POC) electrostatic separator is in the design stage. During the quarter, the design concepts of the TES unit have been finalized with Carpco. During the past quarter, most of the personnel assigned to this project have been performing work elements associated with process/engineering design (Task 3) of the process including the TES unit, the Turbo charger and the product conveying system.

  5. DOE - Fossil Energy: Introduction to Coal Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduction An Energy Lesson Cleaning Up Coal COAL is our most abundant fossil fuel. The United States has more coal than the rest of the world has oil. There is still enough coal underground in this country to provide energy for the next 200 to 300 years. But coal is not a perfect fuel. Trapped inside coal are traces of impurities like sulfur and nitrogen. When coal burns, these impurities are released into the air. While floating in the air, these substances can combine with water vapor (for

  6. Clean coal technologies: A business report

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The book contains four sections as follows: (1) Industry trends: US energy supply and demand; The clean coal industry; Opportunities in clean coal technologies; International market for clean coal technologies; and Clean Coal Technology Program, US Energy Department; (2) Environmental policy: Clean Air Act; Midwestern states' coal policy; European Community policy; and R D in the United Kingdom; (3) Clean coal technologies: Pre-combustion technologies; Combustion technologies; and Post-combustion technologies; (4) Clean coal companies. Separate abstracts have been prepared for several sections or subsections for inclusion on the data base.

  7. Bioprocessing of lignite coals using reductive microorganisms

    SciTech Connect (OSTI)

    Crawford, D.L.

    1992-03-29

    In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

  8. Coal Study Guide for Elementary School | Department of Energy

    Office of Environmental Management (EM)

    for Elementary School Coal Study Guide for Elementary School Focuses on the basics of coal, history of coal use, conversion of coal into electricity, and climate change concerns. PDF icon Fossil Energy Study Guide: Coal (for Elementary School) More Documents & Publications Coal Study Guide - Middle School Coal Study Guide - High School Secondary Energy Infobook and Secondary Infobook Activities (19 Activities)

  9. Particle separator

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA)

    1990-01-01

    Method and apparatus (10) are provided for separating and classifying particles (48,50,56) by dispersing the particles within a fluid (52) that is upwardly flowing within a cone-shaped pipe (12) that has its large end (20) above its small end (18). Particles of similar size and shape (48,50) migrate to individual levels (A,B) within the flowing fluid. As the fluid is deflected by a plate (42) at the top end of the pipe (12), the smallest particles are collected on a shelf-like flange (40). Ever larger particles are collected as the flow rate of the fluid is increased. To prevent particle sticking on the walls (14) of the pipe (12), additional fluid is caused to flow into the pipe (12) through holes (68) that are specifically provided for that purpose. Sticking is further prevented by high frequency vibrators (70) that are positioned on the apparatus (10).

  10. Interest in coal chemistry intensifies

    SciTech Connect (OSTI)

    Haggin, J.

    1982-08-09

    Research on coal structure has increased greatly in recent years as the future role of coal as a source of gaseous and liquid fuels, as well as chemicals, becomes more apparent. This paper reviews in some detail work being carried out in the US, particularly in the laboratories of Mobil and Exxon, and in the universities. New ideas on the chemical and physical structure of coal are put forward, and a proposal for a new classification system based on the fundamental properties of the vitrinite macerals is introduced.

  11. STEO December 2012 - coal demand

    Gasoline and Diesel Fuel Update (EIA)

    coal demand seen below 1 billion tons in 2012 for fourth year in a row Coal consumption by U.S. power plants to generate electricity is expected to fall below 1 billion tons in 2012 for the fourth year in a row. Domestic coal consumption is on track to total 829 million tons this year. That's the lowest level since 1992, according to the U.S. Energy Information Administration's new monthly energy forecast. Utilities and power plant operators are choosing to burn more lower-priced natural gas

  12. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    2006-08-15

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  13. Coal gasification vessel

    DOE Patents [OSTI]

    Loo, Billy W. (Oakland, CA)

    1982-01-01

    A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

  14. Coal competition: prospects for the 1980s

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    This report consists of 10 chapters which present an historical overview of coal and the part it has played as an energy source in the economic growth of the United States from prior to World War II through 1978. Chapter titles are: definition of coals, coal mining; types of coal mines; mining methods; mining work force; development of coal; mine ownership; production; consumption; prices; exports; and imports. (DMC)

  15. Clean Coal Technology Programs: Program Update 2007

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FE-0514 Clean Coal Technology Programs: Program Update 2007 Includes Clean Coal Technology Demonstration Program (CCTDP), Power Plant Improvement Initiative (PPII), and Clean Coal Power Initiative (CCPI) Projects As of September 2007 U.S. Department of Energy Assistant Secretary for Fossil Energy Washington, DC 20585 January 2008 T E C H N O L O G Y DOE/FE-0514 Clean Coal Technology Programs: Program Update 2007 Includes Clean Coal Technology Demonstration Program (CCTDP), Power Plant

  16. Annual Coal Distribution Report - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    Distribution Report Release Date: April 16, 2015 | Next Release Date: March 2016 | full report | Revision/Correction The Annual Coal Distribution Report (ACDR) provides detailed information on domestic coal distribution by origin state, destination state, consumer category, and method of transportation. Also provided is a summary of foreign coal distribution by coal-producing state. All data for 2013 are final and this report supersedes the 2013 quarterly coal distribution reports. Highlights

  17. Sustainable Coal Use | Department of Energy

    Energy Savers [EERE]

    Sustainable Coal Use Sustainable Coal Use Coal is a vital energy resource, not only for the United States, but also for many developed and developing economies around the world. Finding ways to use coal cleanly and more efficiently at lower costs is a major R&D challenge, and an ongoing focus of activities by the DOE's Office of Fossil Energy. PDF icon Fossil Energy Research Benefits - Sustainable Coal Use More Documents & Publications Heating Ventilation and Air Conditioning Efficiency

  18. Trillion Particles,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trillion Particles, 120,000 cores, and 350 TBs: Lessons Learned from a Hero IO Run on Hopper Surendra Byna , Andrew Uselton , Prabhat , David Knaak , and Yun...

  19. Combustion characteristics of pulverized coal and air/gas premixed flame in a double swirl combustor

    SciTech Connect (OSTI)

    Kamal, M.M.

    2009-07-01

    An experimental work was performed to investigate the co-firing of pulverized coal and premixed gas/air streams in a double swirl combustor. The results showed that the NOx emissions are affected by the relative rates of thermal NOx formation and destruction via the pyrolysis of the fuel-N species in high temperature fuel-rich zones. Various burner designs were tested in order to vary the temperature history and the residence time across both coal and gas flames inside the furnace. It was found that by injecting the coal with a gas/air mixture as a combined central jet surrounded by a swirled air stream, a double flame envelope develops with high temperature fuel-rich conditions in between the two reaction zones such that the pyrolysis reactions to N{sub 2} are accelerated. A further reduction in the minimum NOx emissions, as well as in the minimum CO concentrations, was reported for the case where the coal particles are fed with the gas/air mixture in the region between the two swirled air streams. On the other hand, allocating the gas/air mixture around the swirled air-coal combustion zone provides an earlier contact with air and retards the NOx reduction mechanism in such a way that the elevated temperatures around the coal particles allow higher overall NOx emissions. The downstream impingement of opposing air jets was found more efficient than the impinging of particle non-laden premixed flames for effective NOx reduction. In both cases, there is an upstream flow from the stagnation region to the coal primary combustion region, but with the case of air impingement, the hot fuel-rich zone develops earlier. The optimum configuration was found by impinging all jets of air and coal-gas/air mixtures that pronounced minimum NOx and CO concentrations of 310 and 480ppm, respectively.

  20. U.S. coal outlook in Asia

    SciTech Connect (OSTI)

    Johnson, C.J.

    1997-02-01

    Coal exports from the US to Asia are declining over time as a result of (1) increased competition from coal suppliers within the Asia-Pacific region, (2) changing steel making technologies, (3) decreased emphasis on security of coal supplies, and (4) deregulation of the energy industry--particularly electric utilities. There are no major changes on the horizon that are likely to alter the role of the US as a modest coal supplier to the Asia-Pacific region. The downward trend in US coal exports to Asia is expected to continue over the 1997--2010 period. But economic and policy changes underway in Asia are likely to result in periodic coal shortages, lasting a few months to a year, and short term increased export opportunities for US coal. US coal exports to Asia are projected to fluctuate within the following ranges over the 2000--2010 period: 10--17 million tons in total exports, 6--12 million tons in thermal coal exports, and 4--9 million tons in coking coal exports. The most important role for US coal, from the perspective of Asian coal importing countries, is to ensure a major alternative source of coal supplies that can be turned to in the event of unforeseen disruptions in coal supplies from the Asia-Pacific region or South Africa. However, the willingness of consumers to pay a premium to ensure US export capacity is declining, with increased emphasis on obtaining the lowest cost coal supplies.

  1. Integrated Waste Treatment Unit (IWTU) Input Coal Analyses and Off-Gass Filter (OGF) Content Analyses

    SciTech Connect (OSTI)

    Jantzen, Carol M.; Missimer, David M.; Guenther, Chris P.; Shekhawat, Dushyant; VanEssendelft, Dirk T.; Means, Nicholas C.

    2015-04-23

    A full engineering scale Fluidized Bed Steam Reformer (FBSR) system is being used at the Idaho Nuclear Technology and Engineering Center (INTEC) to stabilize acidic Low Activity Waste (LAW) known as Sodium Bearing Waste (SBW). The INTEC facility, known as the Integrated Waste Treatment Unit (IWTU), underwent an Operational Readiness Review (ORR) and a Technology Readiness Assessment (TRA) in March 2014. The IWTU began non-radioactive simulant processing in late 2014 and by January, 2015 ; the IWTU had processed 62,000 gallons of simulant. The facility is currently in a planned outage for inspection of the equipment and will resume processing simulated waste feed before commencing to process 900,000 gallons of radioactive SBW. The SBW acidic waste will be made into a granular FBSR product (carbonate based) for disposal in the Waste Isolation Pilot Plant (WIPP). In the FBSR process calcined coal is used to create a CO2 fugacity to force the waste species to convert to carbonate species. The quality of the coal, which is a feed input, is important because the reactivity, moisture, and volatiles (C,H,N,O, and S) in the coal impact the reactions and control of the mineralizing process in the primary steam reforming vessel, the Denitration and Mineralizing Reformer (DMR). Too much moisture in the coal can require that additional coal be used. However since moisture in the coal is only a small fraction of the moisture from the fluidizing steam this can be self-correcting. If the coal reactivity or heating value is too low then the coal feedrate needs to be adjusted to achieve the desired heat generation. Too little coal and autothermal heat generation in the DMR cannot be sustained and/or the carbon dioxide fugacity will be too low to create the desired carbonate mineral species. Too much coal and excess S and hydroxide species can form. Excess sulfur from coal that (1) is too rich in sulfur or (2) from overfeeding coal can promote wall scale and contribute to corrosion in process piping and materials, in excessive off-gas absorbent loading, and in undesired process emissions. The ash content of the coal is important as the ash adds to the DMR and other vessel products which affect the final waste product mass and composition. The amount and composition of the ash also affects the reaction kinetics. Thus ash content and composition contributes to the mass balance. In addition, sodium, potassium, calcium, sulfur, and maybe silica and alumina in the ash may contribute to wall-scale formation. Sodium, potassium, and alumina in the ash will be overwhelmed by the sodium, potassium, and alumina from the feed but the impact from the other ash components needs to be quantified. A maximum coal particle size is specified so the feed system does not plug and a minimum particle size is specified to prevent excess elutriation from the DMR to the Process Gas Filter (PGF). A vendor specification was used to procure the calcined coal for IWTU processing. While the vendor supplied a composite analysis for the 22 tons of coal (Appendix A), this study compares independent analyses of the coal performed at the Savannah River National Laboratory (SRNL) and at the National Energy Technology Laboratory (NETL). Three supersacks a were sampled at three different heights within the sack in order to determine within bag variability and between bag variability of the coal. These analyses were also compared to the vendor’s composite analyses and to the coal specification. These analyses were also compared to historic data on Bestac coal analyses that had been performed at Hazen Research Inc. (HRI) between 2004-2011.

  2. Southern Coal finds value in the met market

    SciTech Connect (OSTI)

    Fiscor, S.

    2009-11-15

    The Justice family launches a new coal company (Southern Coal Corp.) to serve metallurgical and steam coal markets. 1 tab., 3 photos.

  3. Domestic Distribution of U.S. Coal by Origin State,

    U.S. Energy Information Administration (EIA) Indexed Site

    of transportation. Also provided is a summary of foreign coal distribution by coal-exporting State. This Final 2008 Coal Distribution Report - Annual, supersedes the Preliminary...

  4. Domestic Distribution of U.S. Coal by Destination State,

    U.S. Energy Information Administration (EIA) Indexed Site

    of transportation. Also provided is a summary of foreign coal distribution by coal-exporting State. This Final 2008 Coal Distribution Report - Annual, supersedes the Preliminary...

  5. U.S. Energy Information Administration | Annual Coal Distribution...

    Gasoline and Diesel Fuel Update (EIA)

    and Institutional: Form EIA-3, "Quarterly Coal Consumption and Quality Report, Manufacturing and TransformationProcessing Coal Plants and Commercial and Institutional Coal...

  6. DOE/EIA-M060(2007) Coal Market Module

    Gasoline and Diesel Fuel Update (EIA)

    power generation, industrial steam generation, coal-to-liquids production, coal coke manufacturing, residentialcommercial consumption, and coal exports) within the CMM. By...

  7. Coal Market Module of the Energy Modeling System Model Documentation...

    Gasoline and Diesel Fuel Update (EIA)

    power generation, industrial steam generation, coal-to-liquids production, coal coke manufacturing, residentialcommercial consumption, and coal exports) within the CMM. By...

  8. Coal Market Module of the National Energy Modeling System Model...

    Gasoline and Diesel Fuel Update (EIA)

    power generation, industrial steam generation, coal-to-liquids production, coal coke manufacturing, residentialcommercial consumption, and coal exports) within the CMM. By...

  9. Coal - U.S. Energy Information Administration (EIA)

    U.S. Energy Information Administration (EIA) Indexed Site

    Coal made up more than 80% of retired electricity generating capacity in 2015 electricitystatesgenerationcapacityretirements U.S. coal exports declined 23% in 2015, as coal imports ...

  10. The development of coal-based technologies for Department of Defense facilities. Volume 1, Technical report. Semiannual technical progress report, September 28, 1994--March 27, 1995

    SciTech Connect (OSTI)

    Miller, B.G.; Bartley, D.A.; Hatcher, P. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1996-10-15

    This program is being conducted as a cooperative agreement between the Consortium for Coal Water Mixture Technology and the U.S. Department of Energy. Activities this reporting period are summarized by phase. Phase I is nearly completed. During this reporting period, coal beneficiation/preparation studies, engineering designs and economics for retrofitting the Crane, Indiana boiler to fire coal-based fuels, and a 1,000-hour demonstration of dry, micronized coal were completed. In addition, a demonstration-scale micronized-coal water mixture (MCWM) preparation circuit was constructed and a 1,000-hour demonstration firing MCWM began. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations involved literature surveys of NO{sub x}, SO{sub 2}, trace metals, volatile organic compounds, and fine particulate matter capture. In addition, vendors and engineering firms were contacted to identify the appropriate emissions technologies for the installation of commercial NO{sub x} and SO{sub 2} removal systems on the demonstration boiler. Information from the literature surveys and engineering firms will be used to identify, design, and install a control system(s). Work continued on the refinement and optimization of coal grinding and MCWM preparation procedures, and on the development of advanced processes for beneficiating high ash, high sulfur coals. Work also continued on determining the basic cost estimation of boiler retrofits, and evaluating environmental, regulatory, and regional economic impacts. In addition, the feasibility of technology adoption, and the public`s perception of the benefits and costs of coal usage was studied. A coal market analysis was completed. Work in Phase III focused on coal preparation studies, emissions reductions and economic analyses of coal use.

  11. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Grimes, R. William (Laramie, WY); Tweed, Robert E. (Laramie, WY)

    1995-01-01

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  12. Coal Transportation Rate Sensitivity Analysis

    Reports and Publications (EIA)

    2005-01-01

    On December 21, 2004, the Surface Transportation Board (STB) requested that the Energy Information Administration (EIA) analyze the impact of changes in coal transportation rates on projected levels of electric power sector energy use and emissions. Specifically, the STB requested an analysis of changes in national and regional coal consumption and emissions resulting from adjustments in railroad transportation rates for Wyoming's Powder River Basin (PRB) coal using the National Energy Modeling System (NEMS). However, because NEMS operates at a relatively aggregate regional level and does not represent the costs of transporting coal over specific rail lines, this analysis reports on the impacts of interregional changes in transportation rates from those used in the Annual Energy Outlook 2005 (AEO2005) reference case.

  13. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

    1995-04-04

    A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

  14. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    Wendt, J.; Eddings, E.; Lighty, J.; Ring, T.; Smith, P.; Thornock, J.; Y Jia, W. Morris; Pedel, J.; Rezeai, D.; Wang, L.; Zhang, J.; Kelly, K.

    2012-01-06

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol.

  15. Clean Coal Diesel Demonstration Project

    SciTech Connect (OSTI)

    Robert Wilson

    2006-10-31

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  16. Two stage liquefaction of coal

    DOE Patents [OSTI]

    Neuworth, Martin B. (Chevy Chase, MD)

    1981-01-01

    A two stage coal liquefaction process and apparatus comprising hydrogen donor solvent extracting, solvent deashing, and catalytic hydrocracking. Preferrably, the catalytic hydrocracking is performed in an ebullating bed hydrocracker.

  17. Which route to coal liquefaction

    SciTech Connect (OSTI)

    Nene, R.G.

    1981-11-01

    Two main methods for producing liquid fuels from coal are currently undergoing intensive evaluation. One, direct liquefaction (e.g., SRC-II, Exxon Donor Solvent (EDS), and H-Coal) produces liquid fuels directly from coal; the other, indirect liquefaction (e.g., Lurgi gasifier followed by Fischer-Tropsch, and Shell-Koppers gasifier followed by methanol synthesis and Mobil's MTG process) first gasifies coal and then converts the gaseous material into liquid products. This paper compares both routes basing its assessment on yields, thermal efficiencies, elemental balances, investment, complexity, and state of development. It is shown that direct liquefaction is more efficient and produces more product per investment dollar. Higher efficiency for direct liquefaction is verified bY stoichiometric and thermodynamic analysis. All approaches require about the same capital investment per unit of feed. Indirect liquefaction can be either more or less complex than direct liquefaction, depending upon the process. Direct liquefaction is least developed. 8 refs.

  18. Upgrading coal plant damper drives

    SciTech Connect (OSTI)

    Hood, N.R.; Simmons, K. [Alamaba Power (United States)

    2009-11-15

    The replacement of damper drives on two coal-fired units at the James H. Miller Jr. electric generating plant by Intelligent Contrac electric rotary actuators is discussed. 2 figs.

  19. Coal and Biomass to Liquids

    Broader source: Energy.gov [DOE]

    Over the last several decades, the Office of Fossil Energy performed RD&D activities that made significant advancements in the areas of coal conversion to liquid fuels and chemicals. Technology...

  20. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-01-01

    During the ninth quarter, electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania. Scanning electron microscopy and energy dispersive X-ray analysis were done to characterize the morphology and composition of the surface of as-received coal, oxidized coal and coal pyrite. In addition, electrokinetic tests were done on Upper Freeport coal pyrite.

  1. Particle preconcentrator

    DOE Patents [OSTI]

    Linker, K.L.; Conrad, F.J.; Custer, C.A.; Rhykerd, C.L. Jr.

    1998-12-29

    An apparatus and method are disclosed for preconcentrating particles and vapors. The preconcentrator apparatus permits detection of highly diluted amounts of particles in a main gas stream, such as a stream of ambient air. A main gas stream having airborne particles entrained therein is passed through a pervious screen. The particles accumulate upon the screen, as the screen acts as a sort of selective particle filter. The flow of the main gas stream is then interrupted by diaphragm shutter valves, whereupon a cross-flow of carrier gas stream is blown parallel past the faces of the screen to dislodge the accumulated particles and carry them to a particle or vapor detector, such as an ion mobility spectrometer. The screen may be heated, such as by passing an electrical current there through, to promote desorption of particles therefrom during the flow of the carrier gas. Various types of screens are disclosed. The apparatus and method of the invention may find particular utility in the fields of narcotics, explosives detection and chemical agents. 3 figs.

  2. Particle preconcentrator

    DOE Patents [OSTI]

    Linker, Kevin L.; Conrad, Frank J.; Custer, Chad A.; Rhykerd, Jr., Charles L.

    2005-09-20

    An apparatus and method for preconcentrating particles and vapors. The preconcentrator apparatus permits detection of highly diluted amounts of particles in a main gas stream, such as a stream of ambient air. A main gas stream having airborne particles entrained therein is passed through a pervious screen. The particles accumulate upon the screen, as the screen acts as a sort of selective particle filter. The flow of the main gas stream is then interrupted by diaphragm shutter valves, whereupon a cross-flow of carrier gas stream is blown parallel past the faces of the screen to dislodge the accumulated particles and carry them to a particle or vapor detector, such as an ion mobility spectrometer. The screen may be heated, such as by passing an electrical current there through, to promote desorption of particles therefrom during the flow of the carrier gas. Various types of screens are disclosed. The apparatus and method of the invention may find particular utility in the fields of narcotics, explosives detection and chemical agents.

  3. Particle preconcentrator

    DOE Patents [OSTI]

    Linker, Kevin L. (Albuquerque, NM); Conrad, Frank J. (Russellville, NM); Custer, Chad A. (Albuquerque, NM); Rhykerd, Jr., Charles L. (Albuquerque, NM)

    1998-01-01

    An apparatus and method for preconcentrating particles and vapors. The preconcentrator apparatus permits detection of highly diluted amounts of particles in a main gas stream, such as a stream of ambient air. A main gas stream having airborne particles entrained therein is passed through a pervious screen. The particles accumulate upon the screen, as the screen acts as a sort of selective particle filter. The flow of the main gas stream is then interrupted by diaphragm shutter valves, whereupon a cross-flow of carrier gas stream is blown parallel past the faces of the screen to dislodge the accumulated particles and carry them to a particle or vapor detector, such as an ion mobility spectrometer. The screen may be heated, such as by passing an electrical current there through, to promote desorption of particles therefrom during the flow of the carrier gas. Various types of screens are disclosed. The apparatus and method of the invention may find particular utility in the fields of narcotics, explosives detection and chemical agents.

  4. Particle preconcentrator

    DOE Patents [OSTI]

    Linker, Kevin L. (Albuquerque, NM); Conrad, Frank J. (Russellville, SC); Custer, Chad A. (Albuquerque, NM); Rhykerd, Jr., Charles L. (Albuquerque, NM)

    2000-01-01

    An apparatus and method for preconcentrating particles and vapors. The preconcentrator apparatus permits detection of highly diluted amounts of particles in a main gas stream, such as a stream of ambient air. A main gas stream having airborne particles entrained therein is passed through a pervious screen. The particles accumulate upon the screen, as the screen acts as a sort of selective particle filter. The flow of the main gas stream is then interrupted by diaphragm shutter valves, whereupon a cross-flow of carrier gas stream is blown parallel past the faces of the screen to dislodge the accumulated particles and carry them to a particle or vapor detector, such as an ion mobility spectrometer. The screen may be heated, such as by passing an electrical current there through, to promote desorption of particles therefrom during the flow of the carrier gas. Various types of screens are disclosed. The apparatus and method of the invention may find particular utility in the fields of narcotics, explosives detection and chemical agents.

  5. Apparatus for entrained coal pyrolysis

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-11-16

    This invention discloses a process and apparatus for pyrolyzing particulate coal by heating with a particulate solid heating media in a transport reactor. The invention tends to dampen fluctuations in the flow of heating media upstream of the pyrolysis zone, and by so doing forms a substantially continuous and substantially uniform annular column of heating media flowing downwardly along the inside diameter of the reactor. The invention is particularly useful for bituminous or agglomerative type coals.

  6. Streamline coal slurry letdown valve

    DOE Patents [OSTI]

    Platt, R.J.; Shadbolt, E.A.

    1983-11-08

    A streamlined coal slurry letdown valve is featured which has a two-piece throat comprised of a seat and seat retainer. The two-piece design allows for easy assembly and disassembly of the valve. A novel cage holds the two-piece throat together during the high pressure letdown. The coal slurry letdown valve has long operating life as a result of its streamlined and erosion-resistance surfaces. 5 figs.

  7. Streamline coal slurry letdown valve

    DOE Patents [OSTI]

    Platt, Robert J. (Dover, NJ); Shadbolt, Edward A. (Basking Ridge, NJ)

    1983-01-01

    A streamlined coal slurry letdown valve is featured which has a two-piece throat comprised of a seat and seat retainer. The two-piece design allows for easy assembly and disassembly of the valve. A novel cage holds the two-piece throat together during the high pressure letdown. The coal slurry letdown valve has long operating life as a result of its streamlined and erosion-resistance surfaces.

  8. Coal liquefaction and gasification technologies

    SciTech Connect (OSTI)

    Mangold, E.C.; Muradaz, M.A.; Ouellette, R.P.; Farah, O.G.; Cheremisinoff, P.N.

    1982-01-01

    The state-of-the-art of selected coal liquefaction and gasification processes developed with support from the United States are reviewed. The Exxon Donor Solvent, H-Coal, SRC-I, SRC-II, Mobile Gasoline Synthesis, Fischer-Tropsch Synthesis, and Zinc Halide Hydrocracking liquefaction processes and the Slagging Lurgi, Texaco, Combustion Engineering, COGAS, and Shell-Koppers gasification processes are covered. Separate abstracts were prepared for 5 chapters.

  9. Formation of NOx precursors during Chinese pulverized coal pyrolysis in an arc plasma jet

    SciTech Connect (OSTI)

    Wei-ren Bao; Jin-cao Zhang; Fan Li; Li-ping Chang

    2007-08-15

    The formation of NOx precursors (HCN and NH{sub 3}) from the pyrolysis of several Chinese pulverized coals in an arc plasma jet was investigated through both thermodynamic analysis of the C-H-O-N system and experiments. Results of thermodynamic analysis show that the dominant N-containing gaseous species is HCN together with a small amount of ammonia above the temperature of 2000 K. The increase of H content advances the formation of HCN and NH{sub 3}, but the yields of HCN and NH{sub 3} are decreased with a high concentration of O in the system. These results are accordant with the experimental data. The increasing of input power promotes the formation of HCN and NH{sub 3} from coal pyrolysis in an arc plasma jet. Tar-N is not formed during the process. The yield of HCN changes insignificantly with the changing of the residence time of coal particles in the reactor, but that of NH{sub 3} decreases as residence times increase because of the relative instability at high temperature. Adsorption and gasification of CO{sub 2} on the coal surface also can restrain the formation of HCN and NH{sub 3} compare to the results in an Ar plasma jet. Yields of HCN and NH{sub 3} are sensitive to the coal feeding rate, indicating that NOx precursors could interact with the nascent char to form other N-containing species. The formation of HCN and NH{sub 3} during coal pyrolysis in a H{sub 2}/Ar plasma jet are not dependent on coal rank. The N-containing gaseous species is released faster than others in the volatiles during coal pyrolysis in an arc plasma jet, and the final nitrogen content in the char is lower than that in the parent coal, which it is independent of coal type. 16 refs., 9 figs., 1 tab.

  10. 2015 Gasification Systems and Coal and Coal-Biomass to Liquids...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015 Gasification Systems and Coal & Coal-Biomass to Liquids Workshop Workshop Summary Additional materials will be added when they are received from the author. Presentations ...

  11. Coal desulfurization by chlorinolysis: production and combustion-test evaluation of product coals. Final report

    SciTech Connect (OSTI)

    Kalvinskas, J.; Daly, D.

    1982-04-30

    Laboratory-scale screening tests were carried out on PSOC 276, Pittsburgh Coal from Harrison County, Ohio to establish chlorination and hydrodesulfurization conditions for the batch reactor production of chlorinolysis and chlorinolysis-hydrodesulfurized coals. In addition, three bituminous coals, Pittsburgh No. 8 from Greene County, PA, Illinois No. 6 from Jackson County, Illinois and Eagle No. 5 from Moffat County, Colorado were treated on the lab scale by the chlorinolysis process to provide 39 to 62% desulfurization. Two bituminous coals (PSOC 276, Pittsburgh Coal from Harrison County, Ohio and 282, Illinois No. 6 Coal from Jefferson County, Illinois) and one subbituminous coal (PSOC 230, Rosebud Coal fom Rosebud County, Montana) were then produced in 11 to 15 pound lots as chlorinolysis and hydrodesulfurized coals. The chlorinolysis coals had a desulfurization of 29 to 69%, reductions in volatiles (12 to 37%) and hydrogen (6 to 31%). Hydrodesulfurization provided a much greater desulfurization (56 to 86%), reductions in volatiles (77 to 84%) and hydrogen (56 to 64%). The three coals were combustion tested in the Penn State plane flame furance to determine ignition and burning characteristics. All three coals burned well to completion as: raw coals, chlorinolysis processed coals and hydrodesulfurized coals. The hydrodesulfurized coals experienced greater ignition delays and reduced burning rates than the other coals because of the reduced volatile content. It is thought that the increased open pore volume in the desulfurized-devolatilized coals compensates in part for the decreased volatiles effect on ignition and burning. 4 figures, 2 tables.

  12. Direct coal liquefaction process

    DOE Patents [OSTI]

    Rindt, J.R.; Hetland, M.D.

    1993-10-26

    An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300 C to 400 C for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.

  13. Direct coal liquefaction process

    DOE Patents [OSTI]

    Rindt, John R. (Grand Forks, ND); Hetland, Melanie D. (Grand Forks, ND)

    1993-01-01

    An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300.degree. C. to 400.degree. C. for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.

  14. Production of a pellet fuel from Illinois coal mines. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.; Ho, Ken

    1995-12-31

    The goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, we will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach.

  15. Transformations of inorganic coal constituents in combustion systems. Volume 1, sections 1--5: Final report

    SciTech Connect (OSTI)

    Helble, J.J.; Srinivasachar, S.; Wilemski, G.; Boni, A.A.; Kang, Shin-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M.; Peterson, T.W.; Wendt, J.O.L.; Gallagher, N.B.; Bool, L.; Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A.

    1992-11-01

    The inorganic constituents or ash contained in pulverized coal significantly increase the environmental and economic costs of coal utilization. For example, ash particles produced during combustion may deposit on heat transfer surfaces, decreasing heat transfer rates and increasing maintenance costs. The minimization of particulate emissions often requires the installation of cleanup devices such as electrostatic precipitators, also adding to the expense of coal utilization. Despite these costly problems, a comprehensive assessment of the ash formation and had never been attempted. At the start of this program, it was hypothesized that ash deposition and ash particle emissions both depended upon the size and chemical composition of individual ash particles. Questions such as: What determines the size of individual ash particles? What determines their composition? Whether or not particles deposit? How combustion conditions, including reactor size, affect these processes? remained to be answered. In this 6-year multidisciplinary study, these issues were addressed in detail. The ambitious overall goal was the development of a comprehensive model to predict the size and chemical composition distributions of ash produced during pulverized coal combustion. Results are described.

  16. Energy recycling by co-combustion of coal and recovered paint solids from automobile paint operations

    SciTech Connect (OSTI)

    Achariya Suriyawong; Rogan Magee; Ken Peebles; Pratim Biswas

    2009-05-15

    This paper presents the results of an experimental study of particulate emission and the fate of 13 trace elements (arsenic (As), barium (Ba), cadmium (Cd), chromium (Cr), copper (Cu), cobalt (Co), manganese (Mn), molybdenum (Mo), nickel (Ni), lead (Pb), mercury (Hg), vanadium (V), and zinc (Zn)) during combustion tests of recovered paint solids (RPS) and coal. The emissions from combustions of coal or RPS alone were compared with those of co-combustion of RPS with subbituminous coal. The distribution/partitioning of these toxic elements between a coarse-mode ash (particle diameter (d{sub p}) > 0.5 {mu}m), a submicrometer-mode ash (d{sub p} < 0.5 {mu}m), and flue gases was also evaluated. Submicrometer particles generated by combustion of RPS alone were lower in concentration and smaller in size than that from combustion of coal. However, co-combustion of RPS and coal increased the formation of submicrometer-sized particles because of the higher reducing environment in the vicinity of burning particles and the higher volatile chlorine species. Hg was completely volatilized in all cases; however, the fraction in the oxidized state increased with co-combustion. Most trace elements, except Zn, were retained in ash during combustion of RPS alone. Mo was mostly retained in all samples. The behavior of elements, except Mn and Mo, varied depending on the fuel samples. As, Ba, Cr, Co, Cu, and Pb were vaporized to a greater extent from cocombustion of RPS and coal than from combustion of either fuel. Evidence of the enrichment of certain toxic elements in submicrometer particles has also been observed for As, Cd, Cr, Cu, and Ni during co-combustion. 27 refs., 6 figs., 5 tabs.

  17. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  18. Modeling the behavior of selenium in Pulverized-Coal Combustion systems

    SciTech Connect (OSTI)

    Senior, Constance; Otten, Brydger Van; Wendt, Jost O.L.; Sarofim, Adel

    2010-11-15

    The behavior of Se during coal combustion is different from other trace metals because of the high degree of vaporization and high vapor pressures of the oxide (SeO{sub 2}) in coal flue gas. In a coal-fired boiler, these gaseous oxides are absorbed on the fly ash surface in the convective section by a chemical reaction. The composition of the fly ash (and of the parent coal) as well as the time-temperature history in the boiler therefore influences the formation of selenium compounds on the surface of the fly ash. A model was created for interactions between selenium and fly ash post-combustion. The reaction mechanism assumed that iron reacts with selenium at temperatures above 1200 C and that calcium reacts with selenium at temperatures less than 800 C. The model also included competing reactions of SO{sub 2} with calcium and iron in the ash. Predicted selenium distributions in fly ash (concentration versus particle size) were compared against measurements from pilot-scale experiments for combustion of six coals, four bituminous and two low-rank coals. The model predicted the selenium distribution in the fly ash from the pilot-scale experiments reasonably well for six coals of different compositions. (author)

  19. Development of catalyst free carbon nanotubes from coal and waste plastics

    SciTech Connect (OSTI)

    Dosodia, A.; Lal, C.; Singh, B.P.; Mathur, R.B.; Sharma, D.K.

    2009-07-01

    DC-Arc technique has been used to synthesize carbon nanotubes from super clean coal, chemically cleaned coal, original coal and waste plastics instead of using high purity graphite in the presence of metal catalysts. The results obtained are compared in terms of yield, purity and type of carbon nanotubes produced from different types of raw material used. In the present study different types of raw materials have been prepared i.e. chemically cleaned coal and super clean coal, and the carbon nanotubes have been synthesized by DC Arc discharge method. Taking in account the present need of utilizing coal as a cheaper raw material for bulk production of carbon nanotubes and utilization of waste plastics (which itself is a potential environmental threat) for production of such an advance material the present work was undertaken. Since the process does not involve presence of any kind of metal catalyst, it avoids the cost intensive process of removal of these metal particles. The residual coal obtained after refining has major fuel potential and can be utilized for various purposes.

  20. Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993

    SciTech Connect (OSTI)

    Solomon, P.R.; Serio, M.A.; Hamblen, D.G.

    1995-09-01

    This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

  1. Enhancement of surface properties for coal beneficiation

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  2. Coal Transportation Issues (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    Most of the coal delivered to U.S. consumers is transported by railroads, which accounted for 64% of total domestic coal shipments in 2004. Trucks transported approximately 12% of the coal consumed in the United States in 2004, mainly in short hauls from mines in the East to nearby coal-fired electricity and industrial plants. A number of minemouth power plants in the West also use trucks to haul coal from adjacent mining operations. Other significant modes of coal transportation in 2004 included conveyor belt and slurry pipeline (12%) and water transport on inland waterways, the Great Lakes, and tidewater areas (9%).

  3. Beluga Coal Gasification - ISER

    SciTech Connect (OSTI)

    Steve Colt

    2008-12-31

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  4. Spin-mapping of coal structures with ESE and ENDOR. Thirteenth quarterly report

    SciTech Connect (OSTI)

    Belford, R.L.; Clarkson, R.B.

    1991-12-01

    The goals of this program include developing a system for the analysis of the chemical forms of organic sulfur in coal and for study of coal particle surfaces by multifrequency EPR spectroscopy, ENDOR, and ESE spectroscopy and Applying it to coals, to the effects of treatment upon their sulfur-containing organic components, and to related carbonaceous materials (chars and the like). The approach is to utilize the naturally-occurring unpaired electrons in the organic structures of coals as spies to provide molecular structure information, reading out the information with Electron Paramagnetic Resonance (EPR) spectroscopy. Several forms of EPR are employed: Multifrequency continuous-wave (CW) EPR, from 1 GHz to 240 GHz source frequency; electron-nuclear double resonance (ENDOR), in which NMR spectra at paramagnetic centers are obtained by EPR detection; and pulsed EPR, including ESE (Electron Spin Echo) spectroscopy.

  5. Coal Study Guide - High School | Department of Energy

    Office of Environmental Management (EM)

    High School Coal Study Guide - High School PDF icon Coal Study Guide - High School More Documents & Publications Coal Study Guide - Middle School Coal Study Guide for Elementary School Fossil Energy Today - First Quarter, 2011

  6. Coal Study Guide - Middle School | Department of Energy

    Office of Environmental Management (EM)

    Middle School Coal Study Guide - Middle School PDF icon Coal Study Guide - Middle School More Documents & Publications Coal Study Guide for Elementary School Coal Study Guide - High School Guide to Low-Emission Boiler and Combustion Equipment Selection

  7. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  8. Eight Advanced Coal Projects Chosen for Further Development by DOE's

    Office of Environmental Management (EM)

    University Coal Research Program | Department of Energy Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program July 5, 2011 - 1:00pm Addthis Washington, DC - The Department of Energy has selected eight new projects to further advanced coal research under the University Coal Research Program. The selected projects will improve coal conversion and

  9. Clean Coal Program Research Activities

    SciTech Connect (OSTI)

    Larry Baxter; Eric Eddings; Thomas Fletcher; Kerry Kelly; JoAnn Lighty; Ronald Pugmire; Adel Sarofim; Geoffrey Silcox; Phillip Smith; Jeremy Thornock; Jost Wendt; Kevin Whitty

    2009-03-31

    Although remarkable progress has been made in developing technologies for the clean and efficient utilization of coal, the biggest challenge in the utilization of coal is still the protection of the environment. Specifically, electric utilities face increasingly stringent restriction on the emissions of NO{sub x} and SO{sub x}, new mercury emission standards, and mounting pressure for the mitigation of CO{sub 2} emissions, an environmental challenge that is greater than any they have previously faced. The Utah Clean Coal Program addressed issues related to innovations for existing power plants including retrofit technologies for carbon capture and sequestration (CCS) or green field plants with CCS. The Program focused on the following areas: simulation, mercury control, oxycoal combustion, gasification, sequestration, chemical looping combustion, materials investigations and student research experiences. The goal of this program was to begin to integrate the experimental and simulation activities and to partner with NETL researchers to integrate the Program's results with those at NETL, using simulation as the vehicle for integration and innovation. The investigators also committed to training students in coal utilization technology tuned to the environmental constraints that we face in the future; to this end the Program supported approximately 12 graduate students toward the completion of their graduate degree in addition to numerous undergraduate students. With the increased importance of coal for energy independence, training of graduate and undergraduate students in the development of new technologies is critical.

  10. Blast Furnace Granulated Coal Injection

    SciTech Connect (OSTI)

    1998-09-30

    Production levels on each furnace exceeded 7000 NTHM/day during July. The combined production of 14,326 was a result of lower coke rates and below average delay rates on both furnaces, The combined production was at its highest level since September 1997. In August, the combined productivity declined to less than 13,500 NTHM/day. Although D furnace maintained a production rate in excess of 7000 NTHM/day, C furnace was lower because of a castfloor breakout and subsequent five day repair from August 26-30. Despite the lower productivity in August, injected coal and furnace coke rates were very good during the month. During September, the operation was difficult as a result of higher delays on both furnaces. The combined average monthly delay rate was considerably above the twenty-month average of 113 minutes per day and the combined average monthly production was less than 14,000 NTHM/day. Higher furnace coke rates at lower coal injection levels also contributed to the decrease. Additionally, the coke rate on both furnaces was increased substantially and the injected coal rate was decreased in preparation for the high volatile Colorado coal trial that started on September 28. The furnace process results for this quarter are shown in Tables 1A and 1B. In addition, the last twelve months of injected coal and coke rates for each furnace are shown in Figures 1 and 2.

  11. Proceedings, twenty-fourth annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    2007-07-01

    Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

  12. Heat exchanger for coal gasification process

    DOE Patents [OSTI]

    Blasiole, George A.

    1984-06-19

    This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

  13. Metallic species derived from fluidized bed coal combustion. [59 references

    SciTech Connect (OSTI)

    Natusch, D.F.S.; Taylor, D.R.

    1980-01-01

    Samples of fly ash generated by the combustion of Montana Rosebud coal in an experimental 18 inch fluidized bed combustor were collected. The use of a heated cascade impactor permitted collection of size fractionated material that avoided condensation of volatile gases on the particles. Elemental concentration trends were determined as a function of size and temperature and the results compared to published reports for conventional power plants. The behavior of trace metals appears to be substantially different in the two systems due to lower operating temperatures and the addition of limestone to the fluidized bed. Corrosion of the impactor plates was observed at the highest temperature and lowest limestone feed rate sampled during the study. Data from the elemental concentration and leaching studies suggest that corrosion is most likely due to reactions involving sodium sulfate. However, it is concluded that corrosion is less of a potential problem in fluidized-bed systems than in conventional coal-fired systems.

  14. Tracking New Coal-Fired Power Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tracking New Coal-Fired Power Plants (data update 12132010) January 14, 2011 b National ... Office of Strategic Energy Analysis & Planning Erik Shuster 2 Tracking New Coal-Fired ...

  15. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect (OSTI)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  16. Clean Coal Ltd | Open Energy Information

    Open Energy Info (EERE)

    Clean Coal Ltd Place: London, England, United Kingdom Zip: W1F 8QE Product: London-based company which specialises in underground coal gasification project management and project...

  17. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's penumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  18. Respiratory disease in Utah coal miners

    SciTech Connect (OSTI)

    Rom, W.N.; Kanner, R.E.; Renzetti, A.D. Jr.; Shigeoka, J.W.; Barkman, H.W.; Nichols, M.; Turner, W.A.; Coleman, M.; Wright, W.E.

    1981-04-01

    Two hundred forty-two Utah underground coal miners volunteered to participate in a respiratory disease study. They were an older group (mean, 56 years of age) and had spent a mean of 29 years in the coal-mining industry. The prevalence of chronic bronchitis was 57%, and that of coal worker's pneumoconiosis, 25%; only one worker had progressive massive fibrosis. Significant impairment of pulmonary function was found among those with a history of cigarette smoking. Chronic bronchitis or coal worker's pneumoconiosis among nonsmokers did not impair pulmonary function. There was a significant association among the nonsmokers between increasing exposure to coal dust and coal worker's pneumoconiosis, but not for changes in pulmonary function. Coal mine dust had a significant influence in causing the symptom complex of chronic cough and sputum production, and coal worker's pneumoconiosis.

  19. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  20. Weekly Coal Production Estimation Methodology

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Coal Production Estimation Methodology Step 1 (Estimate total amount of weekly U.S. coal production) U.S. coal production for the current week is estimated using a ratio estimation from the given equation below; ̂ () = () × × { + ( - )} (1) ℎ ̂ () =