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  1. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Giant Protease TPP II's Structure, Mechanism Uncovered Print Wednesday, 23 February 2011 00:00 Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of

  2. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Print Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and proteolysis, researchers from Berkeley Lab, the University of California,

  3. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Print Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and proteolysis, researchers from Berkeley Lab, the University of California,

  4. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Print Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and proteolysis, researchers from Berkeley Lab, the University of California,

  5. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Print Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and proteolysis, researchers from Berkeley Lab, the University of California,

  6. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Print Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and proteolysis, researchers from Berkeley Lab, the University of California,

  7. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Giant Protease TPP II's Structure, Mechanism Uncovered Print Tripeptidyl peptidase II (TPP II), the largest known eukaryotic enzyme that breaks down proteins (a protease), is implicated in numerous cellular processes including the degradation of the endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and proteolysis, researchers from Berkeley Lab, the University of California,

  8. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked...

  9. Lead Hexacyanoferrate(II) Tetrahydrate: Crystal Structure, FTIR...

    Office of Scientific and Technical Information (OSTI)

    Lead Hexacyanoferrate(II) Tetrahydrate: Crystal Structure, FTIR Spectroscopy and Thermal Decomposition Studies Citation Details In-Document Search Title: Lead Hexacyanoferrate(II) ...

  10. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stimulate the digestion of fat and protein and acts as a satiety agent, suppressing hunger and inhibiting food intake. Tripeptidyl peptidase II (TPP II) is known to partly...

  11. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Wednesday, 26 January 2011 00:00 Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked

  12. Finding

    Office of Legacy Management (LM)

    Finding of No Significant Impact Ground Water Compliance at the Grand Junction UMTRA Project Site (Climax Uranium Millsite) September 1999 U.S. Department of Energy Grand Junction ...

  13. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of fat and protein and acts as a satiety agent, suppressing hunger and inhibiting food intake. Tripeptidyl peptidase II (TPP II) is known to partly regulate CCK-8 (a CCK with...

  14. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    endogenous satiety agent cholecystokinin-8, making TPP II a target in the treatment of obesity. To gain insight into this molecular machine's mechanisms of activation and...

  15. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked to a DNA's nucleic acid segment through its active site tyrosine, cleaving the DNA. Details of this

  16. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked to a DNA's nucleic acid segment through its active site tyrosine, cleaving the DNA. Details of this

  17. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked to a DNA's nucleic acid segment through its active site tyrosine, cleaving the DNA. Details of this

  18. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked to a DNA's nucleic acid segment through its active site tyrosine, cleaving the DNA. Details of this

  19. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked to a DNA's nucleic acid segment through its active site tyrosine, cleaving the DNA. Details of this

  20. Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topoisomerase II Structure Suggests Novel DNA Cleavage Mechanism Print Type II topoisomerases are molecular machines that regulate DNA supercoiling and separate interlocked chromosomes. These enzymes are also exploited clinically as targets of antibiotics and anticancer therapeutics. Researchers at ALS Beamline 8.3.1 imaged type II topoisomerase's ordinarily short-lived state in which it is linked to a DNA's nucleic acid segment through its active site tyrosine, cleaving the DNA. Details of this

  1. First Structural Steel Erected at NSLS-II

    ScienceCinema (OSTI)

    None

    2010-01-08

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  2. First Structural Steel Erected at NSLS-II

    SciTech Connect (OSTI)

    2009-09-14

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  3. Proofreading RNA: Structure of RNA Polymerase II's Backtracked State

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proofreading RNA: Structure of RNA Polymerase II's Backtracked State Proofreading RNA: Structure of RNA Polymerase II's Backtracked State Print Wednesday, 25 November 2009 00:00 Proofreading Ensures Functional Proteins Genes encoded in DNA are made up of nucleotides wound into a double helix of complementary nucleotide, or base, pairs. Converting these "instructions" into complementary strands of RNA is termed transcription, and is the first of two steps in expressing genes, or turning

  4. STRUCTURE AND FEEDBACK IN 30 DORADUS. II. STRUCTURE AND CHEMICAL ABUNDANCES

    SciTech Connect (OSTI)

    Pellegrini, E. W.; Baldwin, J. A.; Ferland, G. J.

    2011-09-01

    We use our new optical-imaging and spectrophotometric survey of key diagnostic emission lines in 30 Doradus, together with CLOUDY photoionization models, to study the physical conditions and ionization mechanisms along over 4000 individual lines of sight at points spread across the face of the extended nebula, out to a projected radius 75 pc from R136 at the center of the ionizing cluster NGC 2070. We focus on the physical conditions, geometry, and importance of radiation pressure on a point-by-point basis, with the aim of setting observational constraints on important feedback processes. We find that the dynamics and large-scale structure of 30 Dor are set by a confined system of X-ray bubbles in rough pressure equilibrium with each other and with the confining molecular gas. Although the warm (10,000 K) gas is photoionized by the massive young stars in NGC 2070, the radiation pressure does not currently play a major role in shaping the overall structure. The completeness of our survey also allows us to create a composite spectrum of 30 Doradus, simulating the observable spectrum of a spatially unresolved, distant giant extragalactic H II region. We find that the highly simplified models used in the 'strong line' abundance technique do in fact reproduce our observed line strengths and deduced chemical abundances, in spite of the more than one order of magnitude range in the ionization parameter and density of the actual gas in 30 Dor.

  5. Proofreading RNA: Structure of RNA Polymerase II's Backtracked State

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proofreading RNA: Structure of RNA Polymerase II's Backtracked State Print Proofreading Ensures Functional Proteins Genes encoded in DNA are made up of nucleotides wound into a double helix of complementary nucleotide, or base, pairs. Converting these "instructions" into complementary strands of RNA is termed transcription, and is the first of two steps in expressing genes, or turning them into proteins. Accurate transcription is crucial, because if even 1 in 100,000 bases is

  6. Proofreading RNA: Structure of RNA Polymerase II's Backtracked State

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proofreading RNA: Structure of RNA Polymerase II's Backtracked State Print Proofreading Ensures Functional Proteins Genes encoded in DNA are made up of nucleotides wound into a double helix of complementary nucleotide, or base, pairs. Converting these "instructions" into complementary strands of RNA is termed transcription, and is the first of two steps in expressing genes, or turning them into proteins. Accurate transcription is crucial, because if even 1 in 100,000 bases is

  7. Proofreading RNA: Structure of RNA Polymerase II's Backtracked State

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proofreading RNA: Structure of RNA Polymerase II's Backtracked State Print Proofreading Ensures Functional Proteins Genes encoded in DNA are made up of nucleotides wound into a double helix of complementary nucleotide, or base, pairs. Converting these "instructions" into complementary strands of RNA is termed transcription, and is the first of two steps in expressing genes, or turning them into proteins. Accurate transcription is crucial, because if even 1 in 100,000 bases is

  8. Structure Learning and Statistical Estimation in Distribution Networks - Part II

    SciTech Connect (OSTI)

    Deka, Deepjyoti; Backhaus, Scott N.; Chertkov, Michael

    2015-02-13

    Limited placement of real-time monitoring devices in the distribution grid, recent trends notwithstanding, has prevented the easy implementation of demand-response and other smart grid applications. Part I of this paper discusses the problem of learning the operational structure of the grid from nodal voltage measurements. In this work (Part II), the learning of the operational radial structure is coupled with the problem of estimating nodal consumption statistics and inferring the line parameters in the grid. Based on a Linear-Coupled(LC) approximation of AC power flows equations, polynomial time algorithms are designed to identify the structure and estimate nodal load characteristics and/or line parameters in the grid using the available nodal voltage measurements. Then the structure learning algorithm is extended to cases with missing data, where available observations are limited to a fraction of the grid nodes. The efficacy of the presented algorithms are demonstrated through simulations on several distribution test cases.

  9. IBEX satellite finds ribbon-like structure at edge of heliosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IBEX satellite finds ribbon-like structure at edge of heliosphere The NASA IBEX mission ... Using the High Energy Neutral Atom Imager, led by Los Alamos National Laboratory, the NASA ...

  10. Local-global alignment for finding 3D similarities in protein structures

    DOE Patents [OSTI]

    Zemla, Adam T.

    2011-09-20

    A method of finding 3D similarities in protein structures of a first molecule and a second molecule. The method comprises providing preselected information regarding the first molecule and the second molecule. Comparing the first molecule and the second molecule using Longest Continuous Segments (LCS) analysis. Comparing the first molecule and the second molecule using Global Distance Test (GDT) analysis. Comparing the first molecule and the second molecule using Local Global Alignment Scoring function (LGA_S) analysis. Verifying constructed alignment and repeating the steps to find the regions of 3D similarities in protein structures.

  11. Proofreading RNA: Structure of RNA Polymerase II's Backtracked...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of RNA Polymerase II's Backtracked State Print Proofreading Ensures Functional Proteins Genes encoded in DNA are made up of nucleotides wound into a double helix of complementary...

  12. Microbial Lithotrophic Oxidation of Structural Fe(II) in Biotite...

    Office of Scientific and Technical Information (OSTI)

    of the growth yield of lithoautotrophic circumneutral-pH Fe(II)-oxidizing bacteria. ... Subject: 54 ENVIRONMENTAL SCIENCES; AQUIFERS; BACTERIA; BIOTITE; IRON; MICA; ...

  13. Synthesis and structural characterisation of iron(II) and copper(II) diphosphates containing flattened metal oxotetrahedra

    SciTech Connect (OSTI)

    Keates, Adam C.; Wang, Qianlong; Weller, Mark T.

    2014-02-15

    Single crystal and bulk polycrystalline forms of K{sub 2}MP{sub 2}O{sub 7} (M=Fe(II), Cu(II)) have been synthesised and their structures determined from single crystal X-ray diffraction data. Both compounds crystallize in the tetragonal system, space group P-42{sub 1}m. Their structures are formed from infinite sheets of linked oxopolyhedra of the stoichiometry [MP{sub 2}O{sub 7}]{sup 2?} with potassium cations situated between the layers. The MO{sub 4} tetrahedra share oxygen atoms with [P{sub 2}O{sub 7}]{sup 4?} diphosphate groups and the potassium ions have KO{sub 8} square prismatic geometry. In both compounds the M(II) centre has an unusual strongly flattened, tetrahedral coordination to oxygen, as a result of the JahnTeller (JT) effect for the high spin d{sup 6} Fe(II) and p-orbital mixing or a second order JT effect for d{sup 9} Cu(II) centres in four fold coordination. The uncommon transition metal ion environments found in these materials are reflected in their optical absorption spectra and magnetism data. - Graphical abstract: The structures of the tetragonal polymorphs of K{sub 2}MP{sub 2}O{sub 7}, M=Cu(II), Fe(II), consist of infinite sheets of stoichiometry [MP{sub 2}O{sub 7}]{sup 2?}, formed from linked pyrophosphate groups and MO{sub 4} tetrahedra, separated by potassium ions. In both compounds the unusual tetrahedral coordination of the M(II) centre is strongly flattened as a result of JahnTeller (JT) effects for high spin, d{sup 6} Fe(II) and p-orbital mixing and second-order JT effects for d{sup 9} Cu(II). Display Omitted - Highlights: Tetrahedral copper and iron(II) coordinated by oxygen. New layered phosphate structure. JahnTeller and d{sup 10} distorted coordinations.

  14. Why Basin And Range Systems Are Hard To Find Ii- Structural Model...

    Open Energy Info (EERE)

    geothermal reservoir definition and development. Authors David D. Blackwell, Richard P. Smith, Al Waibel, Maria C. Richards and Patrick Stepp Published GRC, 2009 DOI Not Provided...

  15. Why Basin and Range Systems are Hard to Find II- Structural Model...

    Open Energy Info (EERE)

    geothermal reservoir definition and development. Authors David D. Blackwell, Richard P. Smith, Al Waibel, Maria C. Richards and Patrick Stepp Conference GRC Annual Meeting; Reno,...

  16. Synthesis and Structural Flexibility of a Series of Copper(II...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis and Structural Flexibility of a Series of Copper(II) Azolate-Based Metal-Organic ... solvent molecules in the expanded framework 2 induced no change in the pore size, ...

  17. Crystal structure of the sweet-tasting protein thaumatin II at 1.27 A

    SciTech Connect (OSTI)

    Masuda, Tetsuya; Ohta, Keisuke; Tani, Fumito; Mikami, Bunzo; Kitabatake, Naofumi

    2011-07-08

    Highlights: {yields} X-ray crystallographic structure of sweet-tasting protein, thaumatin II, was determined at a resolution of 1.27 A. {yields} The overall structure of thaumatin II is similar to that of thaumatin I, but a slight shift of the C{alpha} atom of G96 in thaumatin II was observed. {yields} The side chain of two critical residues, 67 and 82, for sweetness was modeled in two alternative conformations. {yields} The flexibility and fluctuation of side chains at 67 and 82 seems to be suitable for interaction of thaumatin molecules with sweet receptors. -- Abstract: Thaumatin, an intensely sweet-tasting protein, elicits a sweet taste sensation at 50 nM. Here the X-ray crystallographic structure of one of its variants, thaumatin II, was determined at a resolution of 1.27 A. Overall structure of thaumatin II is similar to thaumatin I, but a slight shift of the C{alpha} atom of G96 in thaumatin II was observed. Furthermore, the side chain of residue 67 in thaumatin II is highly disordered. Since residue 67 is one of two residues critical to the sweetness of thaumatin, the present results suggested that the critical positive charges at positions 67 and 82 are disordered and the flexibility and fluctuation of these side chains would be suitable for interaction of thaumatin molecules with sweet receptors.

  18. The Three-Dimensional Structural Basis of Type II Hyperprolinemia...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: OTHERNIH Country of Publication: United States Language: ENGLISH Subject: 08 HYDROGEN; ALDEHYDES; CHAINS; CONFORMATIONAL CHANGES; CRYSTAL STRUCTURE; DEFECTS; ENZYMES; ...

  19. Substrate Specificity and Structure of Human Aminoadipate Aminotransferase/kynurenine Aminotransferase II

    SciTech Connect (OSTI)

    Han,Q.; Cai, T.; Tagle, D.; Robinson, H.; Li, J.

    2008-01-01

    KAT (kynurenine aminotransferase) II is a primary enzyme in the brain for catalysing the transamination of kynurenine to KYNA (kynurenic acid). KYNA is the only known endogenous antagonist of the N-methyl-D-aspartate receptor. The enzyme also catalyses the transamination of aminoadipate to a-oxoadipate; therefore it was initially named AADAT (aminoadipate aminotransferase). As an endotoxin, aminoadipate influences various elements of glutamatergic neurotransmission and kills primary astrocytes in the brain. A number of studies dealing with the biochemical and functional characteristics of this enzyme exist in the literature, but a systematic assessment of KAT II addressing its substrate profile and kinetic properties has not been performed. The present study examines the biochemical and structural characterization of a human KAT II/AADAT. Substrate screening of human KAT II revealed that the enzyme has a very broad substrate specificity, is capable of catalysing the transamination of 16 out of 24 tested amino acids and could utilize all 16 tested a-oxo acids as amino-group acceptors. Kinetic analysis of human KAT II demonstrated its catalytic efficiency for individual amino-group donors and acceptors, providing information as to its preferred substrate affinity. Structural analysis of the human KAT II complex with a-oxoglutaric acid revealed a conformational change of an N-terminal fraction, residues 15-33, that is able to adapt to different substrate sizes, which provides a structural basis for its broad substrate specificity.

  20. Modeling direct interband tunneling. II. Lower-dimensional structures

    SciTech Connect (OSTI)

    Pan, Andrew; Chui, Chi On

    2014-08-07

    We investigate the applicability of the two-band Hamiltonian and the widely used Kane analytical formula to interband tunneling along unconfined directions in nanostructures. Through comparisons with kp and tight-binding calculations and quantum transport simulations, we find that the primary correction is the change in effective band gap. For both constant fields and realistic tunnel field-effect transistors, dimensionally consistent band gap scaling of the Kane formula allows analytical and numerical device simulations to approximate non-equilibrium Green's function current characteristics without arbitrary fitting. This allows efficient first-order calibration of semiclassical models for interband tunneling in nanodevices.

  1. Development of structure in shearing, viscous media. II

    SciTech Connect (OSTI)

    Hunter, J.H. Jr.; Horak, T.

    1983-02-01

    In this paper we present an approximate, algebraic method for determining when local, self-gravitating structures can develop in viscous, shearing media, such as disks that may be generated by computer simulation. The great advantage of the technique is that it does not require the numerical solution of the linear differential equation. This is particularly important in the present context, since the general local problem considered here is characterized by five independent parameters. We show that the vorticity modes can grow spectacularly in viscous disks. Indeed, in the presence of significant shear viscosity, the familiar density waves damp strongly and only vortices survive. Thus, the growth of structure in circumstellar disks and in the solar nebula may have proceeded along fundamentally different lines from those of the density enhancements in the disks of galaxies.

  2. Engineering characterization of ground motion. Task II. Effects of ground motion characteristics on structural response considering localized structural nonlinearities and soil-structure interaction effects. Volume 2

    SciTech Connect (OSTI)

    Kennedy, R.P.; Kincaid, R.H.; Short, S.A.

    1985-03-01

    This report presents the results of part of a two-task study on the engineering characterization of earthquake ground motion for nuclear power plant design. Task I of the study, which is presented in NUREG/CR-3805, Vol. 1, developed a basis for selecting design response spectra taking into account the characteristics of free-field ground motion found to be significant in causing structural damage. Task II incorporates additional considerations of effects of spatial variations of ground motions and soil-structure interaction on foundation motions and structural response. The results of Task II are presented in four parts: (1) effects of ground motion characteristics on structural response of a typical PWR reactor building with localized nonlinearities and soil-structure interaction effects; (2) empirical data on spatial variations of earthquake ground motion; (3) soil-structure interaction effects on structural response; and (4) summary of conclusions and recommendations based on Tasks I and II studies. This report presents the results of the first part of Task II. The results of the other parts will be presented in NUREG/CR-3805, Vols. 3 to 5.

  3. Excitonic transitions in highly efficient (GaIn)As/Ga(AsSb) type-II quantum-well structures

    SciTech Connect (OSTI)

    Gies, S.; Kruska, C.; Berger, C.; Hens, P.; Fuchs, C.; Rosemann, N. W.; Veletas, J.; Stolz, W.; Koch, S. W.; Heimbrodt, W.; Ruiz Perez, A.; Hader, J.; Moloney, J. V.

    2015-11-02

    The excitonic transitions of the type-II (GaIn)As/Ga(AsSb) gain medium of a “W”-laser structure are characterized experimentally by modulation spectroscopy and analyzed using microscopic quantum theory. On the basis of the very good agreement between the measured and calculated photoreflectivity, the type-I or type-II character of the observable excitonic transitions is identified. Whereas the energetically lowest three transitions exhibit type-II character, the subsequent energetically higher transitions possess type-I character with much stronger dipole moments. Despite the type-II character, the quantum-well structure exhibits a bright luminescence.

  4. Two coordination polymers of manganese(II) isophthalate and their preparation, structures, and magnetic properties

    SciTech Connect (OSTI)

    Chen Jinxi; Wang Jingjing; Ohba, Masaaki

    2012-01-15

    Two manganese coordination polymers, [Mn{sub 2}(ip){sub 2}(dmf)]{center_dot}dmf (1) and [Mn{sub 4}(ip){sub 4}(dmf){sub 6}]{center_dot}2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) A, b=12.193(3) A, c=12.576(3) A, {alpha}=62.19(2) Degree-Sign , {beta}=66.423(17) Degree-Sign , {gamma}=72.72(2) Degree-Sign , Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) A, b=20.20(2) A, c=18.01(3) A, {beta}=108.40(4) Degree-Sign , Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions. - Graphical abstract: Three-dimensional porous and two-dimensional layered manganese isophthalates have been prepared. Magnetic susceptibility measurements exhibit overall weak antiferromagnetic interactions between the Mn(II) ions in both compounds. Highlights: Black-Right-Pointing-Pointer Two manganese isophthalates have been prepared. Black-Right-Pointing-Pointer Compound 1 adopts a three-dimensional porous structure. Black-Right-Pointing-Pointer Compound 2 adopts a two-dimensional layered structure. Black-Right-Pointing-Pointer Magnetic properties of both compounds are investigated.

  5. Structure of the minor pseudopilin XcpW from the Pseudomonas aeruginosa type II secretion system

    SciTech Connect (OSTI)

    Franz, Laura P.; Douzi, Badreddine; Durand, Eric; Dyer, David H.; Voulhouxd, Rom; Forest, Katrina T.

    2012-01-13

    Pseudomonas aeruginosa utilizes the type II secretion machinery to transport virulence factors through the outer membrane into the extracellular space. Five proteins in the type II secretion system share sequence homology with pilin subunits of type IV pili and are called the pseudopilins. The major pseudopilin X{sub cp}T{sub G} assembles into an intraperiplasmic pilus and is thought to act in a piston-like manner to push substrates through an outer membrane secretin. The other four minor pseudopilins, X{sub cp}U{sub H}, X{sub cp}V{sub I}, X{sub cp}W{sub J} and X{sub cp}X{sub K}, play less well defined roles in pseudopilus formation. It was recently discovered that these four minor pseudopilins form a quaternary complex that is presumed to initiate the formation of the pseudopilus and to localize to its tip. Here, the structure of X{sub cp}W{sub J} was refined to 1.85 {angstrom} resolution. The structure revealed the type IVa pilin fold with an embellished variable antiparallel {beta}-sheet as also found in the X{sub cp}W{sub J} homologue enterotoxigenic Escherichia coli G{sub sp}J{sub W} and the X{sub cp}U{sub H} homologue Vibrio cholerae E{sub ps}U{sub H}. It is proposed that the exposed surface of this sheet may cradle the long N-terminal 1 helix of another pseudopilin. The final 31 amino acids of the X{sub cp}W{sub J} structure are instrinsically disordered. Deletion of this unstructured region of X{sub cp}W{sub J} did not prevent type II secretion in vivo.

  6. Crystal structure and magnetic properties of NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl

    SciTech Connect (OSTI)

    Jin Tengteng; Liu Wei; Chen Shuang; Prots, Yurii; Schnelle, Walter; Zhao Jingtai; Kniep, Ruediger; Hoffmann, Stefan

    2012-08-15

    A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Single-crystal X-ray diffraction data show that the title compound crystallizes in the monoclinic system, space group P2{sub 1}/c (No. 14), with lattice parameters a=8.392(2) A, b=6.3960(10) A, c=16.670(2) A, {beta}=109.470(10) Degree-Sign , V=843.6(3) A{sup 3}, Z=4. The crystal structure is characterized by a complex chain of copper-centered polyhedra running along [0 1 0] which are connected by phosphate tetrahedra. The resulting three-dimensional polyhedra framework exhibits channels filled by additional copper and sodium atoms. Field and temperature dependent measurements of the specific heat and the magnetic susceptibility reveal low-dimensional magnetic behavior. The compound starts to decompose at 700 K under release of oxygen and evaporation of Cu{sup I}Cl as shown by simultaneous thermogravimetry and mass spectrometry. - Graphical abstract: The crystal structure of the new copper(II) phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], exhibits linear chains of copper tetrahedra which show low-dimensional magnetic behavior proven by specific heat and magnetic susceptibility measurements. Highlights: Black-Right-Pointing-Pointer A new copper(II) oxide phosphate chloride, NaCu{sup II}[(Cu{sup II}{sub 3}O)(PO{sub 4}){sub 2}Cl], has been synthesized by flux synthesis. Black-Right-Pointing-Pointer The crystal structure comprises chains of Cu{sub 4}O tetrahedra. Black-Right-Pointing-Pointer Low-dimensional behavior has been proven by magnetic and specific heat measurements. Black-Right-Pointing-Pointer On heating, Cu{sup I}Cl and oxygen are released shown by simultaneous thermogravimetry and mass spectrometry.

  7. Nuclear Shell Structure and Beta Decay I. Odd A Nuclei II. Even A Nuclei

    DOE R&D Accomplishments [OSTI]

    Mayer, M.G.; Moszkowski, S.A.; Nordheim, L.W.

    1951-05-01

    In Part I a systematics is given of all transitions for odd A nuclei for which sufficiently reliable data are available. The allowed or forbidden characters of the transitions are correlated with the positions of the initial and final odd nucleon groups in the nuclear shell scheme. The nuclear shells show definite characteristics with respect to parity of the ground states. The latter is the same as the one obtained from known spins and magnetic moments in a one-particle interpretation. In Part II a systematics of the beta transitions of even-A nuclei is given. An interpretation of the character of the transitions in terms of nuclear shell structure is achieved on the hypothesis that the odd nucleon groups have the same structure as in odd-A nuclei, together with a simple coupling rule between the neutron and proton groups in odd-odd nuclei.

  8. FINDING η CAR ANALOGS IN NEARBY GALAXIES USING Spitzer. II. IDENTIFICATION OF AN EMERGING CLASS OF EXTRAGALACTIC SELF-OBSCURED STARS

    SciTech Connect (OSTI)

    Khan, Rubab; Kochanek, C. S.; Stanek, K. Z.; Gerke, Jill

    2015-02-01

    Understanding the late-stage evolution of the most massive stars such as η Carinae is challenging because no true analogs of η Car have been clearly identified in the Milky Way or other galaxies. In Khan et al., we utilized Spitzer IRAC images of 7 nearby (≲ 4 Mpc) galaxies to search for such analogs, and found 34 candidates with flat or red mid-IR spectral energy distributions. Here, in Paper II, we present our characterization of these candidates using multi-wavelength data from the optical through the far-IR. Our search detected no true analogs of η Car, which implies an eruption rate that is a fraction 0.01 ≲ F ≲ 0.19 of the core-collapse supernova (ccSN) rate. This is roughly consistent with each M {sub ZAMS} ≳ 70 M {sub ☉} star undergoing one or two outbursts in its lifetime. However, we do identify a significant population of 18 lower luminosity (log (L/L {sub ☉}) ≅ 5.5-6.0) dusty stars. Stars enter this phase at a rate that is a fraction 0.09 ≲ F ≲ 0.55 of the ccSN rate, and this is consistent with all 25 < M {sub ZAMS} < 60 M {sub ☉} stars undergoing an obscured phase at most lasting a few thousand years once or twice. These phases constitute a negligible fraction of post-main-sequence lifetimes of massive stars, which implies that these events are likely to be associated with special periods in the evolution of the stars. The mass of the obscuring material is of order ∼M {sub ☉}, and we simply do not find enough heavily obscured stars for theses phases to represent more than a modest fraction (∼10% not ∼50%) of the total mass lost by these stars. In the long term, the sources that we identified will be prime candidates for detailed physical analysis with the James Webb Space Telescope.

  9. Synthesis, structures, and properties of three Zn(II), Mn(II), and Cd(II) compounds based on tetrazole-1-acetic ligand

    SciTech Connect (OSTI)

    Liu, Dong-Sheng Chen, Wen-Tong; Xu, Ya-Ping; Shen, Ping; Hu, Shao-Jun; Sui, Yan

    2015-03-15

    Three new compounds, ([Zn(tza){sub 2}(H{sub 2}O)]·H{sub 2}O){sub n} (1), ([Mn(tza){sub 2}(Htza){sub 2}]·2H{sub 2}O){sub n} (2) and [Cd(tza){sub 2}]{sub n} (3), were obtained by reactions of 1H-Tetrazole-1-acetic (Htza) with corresponding metal salts, and characterized by elemental analysis, infrared spectroscopy, and single crystal X-ray diffraction, respectively. The X-ray diffraction analysis reveals that compound 1 is three-dimensional (3D) supramolecular structure with line chains. Compound 2 is three-dimensional (3D) supramolecular structure with Mn-carboxylate chains. Compound 3 is a 3D framework with (3,6)-connected ‘ant’ topological network. Furthermore, the photoluminescence of 1 and 3 and the magnetic properties of 2 have also been investigated. - Graphical abstract: Three new Zn/Mn/Cd compounds were obtained by reactions of Htza with corresponding metal salts, and characterized by chemical methods. Different linear chains result in different final structures. Compounds 1 and 2 are 3D supramolecular structures. Compound 3 is a 3D framework with (3,6)-connected ‘ant’ topological network. - Highlights: • Three new Zn/Mn/Cd compounds based on Htza ligand has been synthesized. • Different linear chains result in different final structures. • The fluorescence or magnetic properties have been investigated.

  10. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

    SciTech Connect (OSTI)

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

    2012-08-17

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  11. Cu{sup II} coordination polymers based on 5-methoxyisophthalate and flexible N-donor ligands: Structures and magnetic properties

    SciTech Connect (OSTI)

    Chang, Xin-Hong; Qin, Jian-Hua; Ma, Lu-Fang; Wang, Li-Ya

    2014-04-01

    Three Cu{sup II} coordination polymers, ([Cu{sub 2}(CH{sub 3}O-ip){sub 2}(bmib)]){sub n} (1), ([Cu{sub 2}(CH{sub 3}O-ip){sub 2}(bmib){sub 2}]){sub n} (2) and ([Cu(CH{sub 3}O-ip)(bbip)]∙2H{sub 2}O){sub n} (3) (CH{sub 3}O-H{sub 2}ip is 5-methoxyisophthalic acid, bmib is 1,4-bis(2-methylimidazol-1-yl)butane and bbip is 1,3-bis(1H-benzimidazolyl)propane), have been synthesized by hydrothermal methods. Complexes 1–3 were structurally characterized by elemental analysis, infrared (IR) spectra and X-ray single-crystal diffraction. Complex 1 shows a 3D six-connected self-penetrating network based on paddlewheel secondary building units. Complex 2 has a 3-fold interpenetrating 3D diamond framework. Complex 3 possesses a 1D tube-like chain. Thermo-gravimetric and magnetic properties of 1–3 were also investigated. - Graphical abstract: Structures and magnetic properties of copper(II) coordination polymers constructed from 5-methoxyisophthalate linker and two flexible N-donor ancillary ligands. Three copper(II) coordination polymers with 5-methoxyisophthalate and two related flexible N-donor ancillary ligands have been synthesized and structurally characterized. Moreover, thermal behaviors and magnetic properties of these complexes have also been investigated. - Highlights: • Three Cu(II) coordination polymers were synthesized. • The conformations of N-donor ligands and pH value have an effect on the final structures. • The magnetic properties of 1–3 have been investigated.

  12. Photosystem II

    ScienceCinema (OSTI)

    James Barber

    2010-09-01

    James Barber, Ernst Chain Professor of Biochemistry at Imperial College, London, gives a BSA Distinguished Lecture titled, "The Structure and Function of Photosystem II: The Water-Splitting Enzyme of Photosynthesis."

  13. Now on display: a gallery of group II intron structures at different...

    Office of Scientific and Technical Information (OSTI)

    DOI: 10.11861759-8753-4-14 Select the DOI to obtain a copy of this journal article from the publisher. Find in Google Scholar Find in Google Scholar Search WorldCat Search ...

  14. High resolution structures of the bone morphogenetic protein type II receptor in two crystal forms: Implications for ligand binding

    SciTech Connect (OSTI)

    Mace, Peter D.; Cutfield, John F.; Cutfield, Sue M. . E-mail: sue.cutfield@otago.ac.nz

    2006-12-29

    BMPRII is a type II TGF-{beta} serine threonine kinase receptor which is integral to the bone morphogenetic protein (BMP) signalling pathway. It is known to bind BMP and growth differentiation factor (GDF) ligands, and has overlapping ligand specificity with the activin type II receptor, ActRII. In contrast to activin and TGF-{beta} type ligands, BMPs bind to type II receptors with lower affinity than type I receptors. Crystals of the BMPRII ectodomain were grown in two different forms, both of which diffracted to high resolution. The tetragonal form exhibited some disorder, whereas the entire polypeptide was seen in the orthorhombic form. The two structures retain the basic three-finger toxin fold of other TGF-{beta} receptor ectodomains, and share the main hydrophobic patch used by ActRII to bind various ligands. However, they present different conformations of the A-loop at the periphery of the proposed ligand-binding interface, in conjunction with rearrangement of a disulfide bridge within the loop. This particular disulfide (Cys94-Cys117) is only present in BMPRII and activin receptors, suggesting that it is important for their likely shared mode of binding. Evidence is presented that the two crystal forms represent ligand-bound and free conformations of BMPRII. Comparison with the solved structure of ActRII bound to BMP2 suggests that His87, unique amongst TGF-{beta} receptors, may play a key role in ligand recognition.

  15. Mechanism of Bacterial Cell-Surface Attachment Revealed by the Structure of Cellulosomal Type II Cohesin-dockerin Complex

    SciTech Connect (OSTI)

    Adams,J.; Pal, G.; Jia, Z.; Smith, S.

    2006-01-01

    Bacterial cell-surface attachment of macromolecular complexes maintains the microorganism in close proximity to extracellular substrates and allows for optimal uptake of hydrolytic byproducts. The cellulosome is a large multienzyme complex used by many anaerobic bacteria for the efficient degradation of plant cell-wall polysaccharides. The mechanism of cellulosome retention to the bacterial cell surface involves a calcium-mediated protein-protein interaction between the dockerin (Doc) module from the cellulosomal scaffold and a cohesin (Coh) module of cell-surface proteins located within the proteoglycan layer. Here, we report the structure of an ultra-high-affinity (K{sub a} = 1.44 x 10{sup 10} M{sup 1-}) complex between type II Doc, together with its neighboring X module from the cellulosome scaffold of Clostridium thermocellum, and a type II Coh module associated with the bacterial cell surface. Identification of X module-Doc and X module-Coh contacts reveal roles for the X module in Doc stability and enhanced Coh recognition. This extremely tight interaction involves one face of the Coh and both helices of the Doc and comprises significant hydrophobic character and a complementary extensive hydrogen-bond network. This structure represents a unique mechanism for cell-surface attachment in anaerobic bacteria and provides a rationale for discriminating between type I and type II Coh modules.

  16. Cross-Linking and Mass Spectrometry Methodologies to Facilitate Structural Biology: Finding a Path through the Maze

    SciTech Connect (OSTI)

    Merkley, Eric D.; Cort, John R.; Adkins, Joshua N.

    2013-09-01

    Multiprotein complexes, rather than individual proteins, make up a large part of the biological macromolecular machinery of a cell. Understanding the structure and organization of these complexes is critical to understanding cellular function. Chemical cross-linking coupled with mass spectrometry is emerging as a complementary technique to traditional structural biology methods and can provide low-resolution structural information for a multitude of purposes, such as distance constraints in computational modeling of protein complexes. In this review, we discuss the experimental considerations for successful application of chemical cross-linking-mass spectrometry in biological studies and highlight three examples of such studies from the recent literature. These examples (as well as many others) illustrate the utility of a chemical cross-linking-mass spectrometry approach in facilitating structural analysis of large and challenging complexes.

  17. Synthesis and structural characterization of two half-sandwich nickel(II) complexes with the scorpionate ligands

    SciTech Connect (OSTI)

    Wang, G.-F. E-mail: s-shuwen@163.com; Zhang, X.; Sun, S.-W.; Sun, H.; Ma, H.-X.

    2015-12-15

    The synthesis and characterization of two new halfsandwich mononuclear nickel(II) complexes with the scorpionate ligands, [k{sup 3}-N, N',N''-Tp{sup t-Bu}, {sup Me}NiI] (1) and [k{sup 3}-N,N',N''-Tp{sup t-Bu}, {sup Me}NiNO{sub 3}] (2), are reported. These complexes have been fully characterized by elemental analyses and infrared spectra. Their molecular structures were determined by single crystal X-ray diffraction. The nickel(II) ion of complex 1 is in a four-coordinate environment, in which the donor atoms are provided by three nitrogen atoms of a hydrotris(pyrazolyl) borate ligand and one iodide atom, while that of complex 2 is in a five-coordinate environment with three nitrogen atoms from a hydrotris(pyrazolyl)borate ligand and two oxygen atoms from a nitrate ion.

  18. Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties

    SciTech Connect (OSTI)

    Zhang, Ju-Wen; Gong, Chun-Hua; Hou, Li-Li; Tian, Ai-Xiang; Wang, Xiu-Li

    2013-09-15

    Three new metal-organic coordination polymers [Co(4-bbc){sub 2}(bbbm)] (1), [Co(3,5-pdc)(bbbm)]·2H{sub 2}O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H{sub 2}pdc=3,5-pyridinedicarboxylic acid, 1,4-H{sub 2}ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co{sup II} ions. Polymer 2 exhibits a 2D network with a (3·4·5)(3{sup 2}·4·5·6{sup 2}·7{sup 4}) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1–3. Moreover, the thermal stability, electrochemical and luminescent properties of 1–3 were investigated. - graphical abstract: Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were hydrothermally synthesized and structurally characterized. The aromatic carboxylates play a key role in the dimensionality of three polymers. The electrochemical and luminescent properties of three polymers were investigated. Display Omitted - Highlights: • Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were obtained. • The aromatic carboxylates have an important influence on the dimensionality of three polymers. • The electrochemical and luminescent properties of three polymers were investigated.

  19. Find Journals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Find Energy Incentives Quicker and Easier with DSIRE Open Data and Website Find Energy Incentives Quicker and Easier with DSIRE Open Data and Website March 3, 2015 - 4:16pm Addthis The updated Database of State Incentives for Renewables & Efficiency helps homeowners and businesses find incentive programs that can reduce or defray installation or purchase costs of technologies like photovoltaic systems. | Photo by Dennis Schroeder, National Renewable Energy

  20. Molecular, crystal, and electronic structure of the cobalt(II) complex with 10-(2-benzothiazolylazo)-9-phenanthrol

    SciTech Connect (OSTI)

    Linko, R. V.; Sokol, V. I.; Polyanskaya, N. A.; Ryabov, M. A.; Strashnov, P. V.; Davydov, V. V.; Sergienko, V. S.

    2013-05-15

    The reaction of 10-(2-benzothiazolylazo)-9-phenanthrol (HL) with cobalt(II) acetate gives the coordination compound [CoL{sub 2}] {center_dot} CHCl{sub 3} (I). The molecular and crystal structure of I is determined by X-ray diffraction. The coordination polyhedron of the Co atom in complex I is an octahedron. The anion L acts as a tridentate chelating ligand and is coordinated to the Co atom through the phenanthrenequinone O1 atom and the benzothiazole N1 atom of the moieties L and the N3 atom of the azo group to form two five-membered metallocycles. The molecular and electronic structures of the compounds HL, L, and CoL{sub 2} are studied at the density functional theory level. The results of the quantum-chemical calculations are in good agreement with the values determined by X-ray diffraction.

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  3. Find Books

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Books Find Books The Library Catalog is available to the public, though many eBooks are limited to LANL researchers. Question? 667-5809 Email Library Catalog: Search here for all...

  4. Find Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reports Find Reports Most of the reports sources below are publicly accessible. Question? 667-5809 Email Unclassified Los Alamos Reports Library Catalog - Print and electronic (1943-present) Los Alamos Authors (LANL-only access) - LA-, LA-CP, and LA-UR reports (1973-present) Los Alamos Research Online - Find published versions of Los Alamos research (2006-present) Classified reports - contact the SI-RMS Technical Report Collection for an appointment: phone icon 5-4168 / email icon

  5. STRUCTURE IN THE 3D GALAXY DISTRIBUTION. II. VOIDS AND WATERSHEDS OF LOCAL MAXIMA AND MINIMA

    SciTech Connect (OSTI)

    Way, M. J.; Gazis, P. R.; Scargle, Jeffrey D. E-mail: PGazis@sbcglobal.net

    2015-01-20

    The major uncertainties in studies of the multi-scale structure of the universe arise not from observational errors but from the variety of legitimate definitions and detection methods for individual structures. To facilitate the study of these methodological dependencies, we have carried out 12 different analyses defining structures in various ways. This has been done in a purely geometrical way by utilizing the HOP algorithm as a unique parameter-free method of assigning groups of galaxies to local density maxima or minima. From three density estimation techniques (smoothing kernels, Bayesian blocks, and self-organizing maps) applied to three data sets (the Sloan Digital Sky Survey Data Release 7, the Millennium simulation, and randomly distributed points) we tabulate information that can be used to construct catalogs of structures connected to local density maxima and minima. We also introduce a void finder that utilizes a method to assemble Delaunay tetrahedra into connected structures and characterizes regions empty of galaxies in the source catalog.

  6. Structure And Dynamics of the Hydrated Palladium(II) Ion in Aqueous Solution a QMCF MD Simulation And EXAFS Spectroscopic Study

    SciTech Connect (OSTI)

    Hofer, T.S.; Randolf, B.R.; Shah, S.Adnan Ali; Rode, B.M.; Persson, I.

    2009-06-01

    The pharmacologically and industrially important palladium(II) ion is usually characterised as square-planar structure in aqueous solution, similar to the platinum(II) ion. Our investigations by means of the most modern experimental and theoretical methods give clear indications, however, that the hydrated palladium(II) ion is hexa-coordinated, with four ligands arranged in a plane at 2.0 {angstrom} plus two additional ligands in axial positions showing an elongated bond distance of 2.7-2.8 A. The second shell consists in average of 8.0 ligands at a mean distance of 4.4 {angstrom}. This structure provides a new basis for the interpretation of the kinetic properties of palladium(II) complexes.

  7. Swift heavy ion irradiation of Pt nanocrystals: II. Structural changes and H desorption

    SciTech Connect (OSTI)

    Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C.

    2014-09-24

    The structural properties and H desorption from embedded Pt nanocrystals (NCs) following irradiation with swift heavy ions were investigated as a function of energy and fluence. From x-ray absorption near-edge spectroscopy analysis, Pt-H bonding was identified in NCs annealed in a forming gas (95% N{sub 2} + 5% H{sub 2}) ambient. The H content decreased upon irradiation and the desorption process was NC-size dependent such that larger NCs required a higher fluence to achieve a H-free state. Pt-H bonding and NC dissolution both perturbed the NC structural parameters (coordination number, bond-length and mean-square relative displacement) as determined with extended x-ray absorption fine structure measurements.

  8. Structural Dimensions, Fabrication, Materials, and Operational History for Types I and II Waste Tanks

    SciTech Connect (OSTI)

    Wiersma, B.J.

    2000-08-16

    Radioactive waste is confined in 48 underground storage tanks at the Savannah River Site. The waste will eventually be processed and transferred to other site facilities for stabilization. Based on waste removal and processing schedules, many of the tanks, including those with flaws and/or defects, will be required to be in service for another 15 to 20 years. Until the waste is removed from storage, transferred, and processed, the materials and structures of the tanks must maintain a confinement function by providing a leak-tight barrier to the environment and by maintaining acceptable structural stability during design basis event which include loading from both normal service and abnormal conditions.

  9. The crystal and molecular structure of bis[1,3-bis(diphenylphosphino)propane] dichlororuthenium(II)

    SciTech Connect (OSTI)

    Fontes, M.R.M.; Oliva, G.; Cordeiro, L.A.C.; Batista, A.A.

    1993-12-31

    The title compound, trans-[Ru(dpp){sub 2}Cl{sub 2}], crystallizes in the triclinic space group P1, with a = 9.529(1), b = 11.071(1), c = 11.936(1) {angstrom}, {alpha} = 71.967(9), {beta} = 72.879(6), {gamma} = 88.703(9){degrees}, V = 1141.1(2) {angstrom}{sup 3} and Z = 1. The structure was solved and refined to a final R = 0.039, for 3126 independently observed reflections with I > 3{sigma} (I). The ruthenium(II) ion is located on a crystallographic centre of symmetry and shows a distorted octahedral coordination with the chloride atoms in an exactly trans configuration. 19 refs., 1 fig., 3 tabs.

  10. Find Patents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Patents Find Patents Some of these resources are Lab-only and will require Remote Access. Questions? 667-5809 Email US Patents Google Patents - search USPTO patents in a Google interface USPTO Database (United States Patent and Trademark Office) DOE Patents - only patents resulting from DOE-sponsored research Worldwide Patents Espacenet Patent Search (European Patent Office) Free Patents Online SciFinder information (from Chemical Abstracts Service) Ordering Patents Thomson Innovation - contact

  11. Find Preprints

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preprints Find Preprints Journal preprints may only be available via subscription and thus require Remote Access. Questions? 667-5809 Email Databases arXiv.org - open access eprints in Physics, Mathematics, Computer Science, Quantitative Biology, and Statistics bioRxiv.org - preprint server for Biology operated by Cold Spring Harbor Laboratory INSPIRE - High Energy Physics (HEP) papers updated daily (a collaboration of CERN, DESY, Fermilab, and SLAC) Journals Online journals often offer

  12. Physics with gamma-beams and charged particle detectors: I) Nuclear structure II) Nuclear astrophysics

    SciTech Connect (OSTI)

    Gai, Moshe

    2015-02-24

    The Charged Particle Working Group (CPWG) is proposing to construct large area Silicon Strip Detector (SSD), a gas Time Projection Chamber detector read by an electronic readout system (eTPC) and a Bubble Chamber (BC) containing superheated high purity water to be used in measurements utilizing intense gamma-ray beams from the newly constructed ELI-NP facility at Magurele, Bucharest in Romania. We intend to use the SSD and eTPC detectors to address essential problems in nuclear structure physics, such as clustering and the many alpha-decay of light nuclei such as {sup 12}C and {sup 16}O. All three detectors (SSD, eTPC and BC) will be used to address central problems in nuclear astrophysics such as the astrophysical cross section factor of the {sup 12}C(α,γ) reaction and other processes central to stellar evolution. The CPWG intends to submit to the ELI-NP facility a Technical Design Report (TDR) for the proposed detectors.

  13. Structural properties and band offset determination of p-channel mixed As/Sb type-II staggered gap tunnel field-effect transistor structure

    SciTech Connect (OSTI)

    Zhu, Y.; Jain, N.; Hudait, M. K.; Mohata, D. K.; Datta, S.; Lubyshev, D.; Fastenau, J. M.; Liu, A. K.

    2012-09-10

    The structural properties and band offset determination of p-channel staggered gap In{sub 0.7}Ga{sub 0.3}As/GaAs{sub 0.35}Sb{sub 0.65} heterostructure tunnel field-effect transistor (TFET) grown by molecular beam epitaxy (MBE) were investigated. High resolution x-ray diffraction revealed that the active layers are strained with respect to 'virtual substrate.' Dynamic secondary ion mass spectrometry confirmed an abrupt junction profile at the In{sub 0.7}Ga{sub 0.3}As/GaAs{sub 0.35}Sb{sub 0.65} heterointerface and minimal level of intermixing between As and Sb atoms. The valence band offset of 0.37 {+-} 0.05 eV was extracted from x-ray photoelectron spectroscopy. A staggered band lineup was confirmed at the heterointerface with an effective tunneling barrier height of 0.13 eV. Thus, MBE-grown staggered gap In{sub 0.7}Ga{sub 0.3}As/GaAs{sub 0.35}Sb{sub 0.65} TFET structures are a promising p-channel option to provide critical guidance for the future design of mixed As/Sb type-II based complementary logic and low power devices.

  14. Three tetranuclear copper(II) cluster-based complexes constructed from 4-amino-1,2,4-triazole and different aromatic carboxylates: Assembly, structures, electrochemical and magnetic properties

    SciTech Connect (OSTI)

    Wang, Xiu-Li; Zhao, Wei; Zhang, Ju-Wen; Lu, Qi-Lin

    2013-02-15

    Three new tetranuclear copper(II) cluster-based complexes constructed from 4-amino-1,2,4-triazole (atrz) and three types of aromatic carboxylates, [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(DNBA){sub 6}] (1), [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(1,3-BDC){sub 3}]{center_dot}2H{sub 2}O (2) and [Cu{sub 4}({mu}{sub 3}-OH){sub 2}(atrz){sub 2}(SIP){sub 2}]{center_dot}4H{sub 2}O (3) (HDNBA=3,5-dinitrobenzoic acid, 1,3-H{sub 2}BDC=1,3-benzenedicarboxylic acid and NaH{sub 2}SIP=sodium 5-sulfoisophthalate), have been hydrothermally synthesized and structurally characterized. Complex 1 displays a single-molecular Cu{sup II}{sub 4} cluster structure, which is further connected by the intermolecular hydrogen-bonding interactions to form a 2D supramolecular layer. In 2, there also exist tetranuclear Cu{sup II}{sub 4} clusters, which are linked by the 1,3-BDC anions to give a 3D NaCl-type framework. In 3, the Cu{sup II}{sub 4} clusters are connected by the carboxyl and sulfo groups of SIP anions to generate 3D (4,8)-connected framework with a (4{sup 10}{center_dot}6{sup 14}{center_dot}8{sup 4})(4{sup 5}{center_dot}6){sub 2} topology. The atrz ligand conduces to the construction of tetranuclear copper(II) clusters and the carboxylates with different non-carboxyl substituent show important effects on the final structures of the title complexes. The electrochemical and magnetic properties of 1-3 have been investigated. - Graphical abstract: Three tetranuclear copper(II) cluster-based complexes based on different carboxylates have been synthesized under hydrothermal conditions. The carboxylate anions play a key role in the formation of three different structures. Highlights: Black-Right-Pointing-Pointer Three new tetranuclear copper(II) cluster-based complexes have been obtained. Black-Right-Pointing-Pointer The atrz conduces to the construction of tetranuclear copper(II) clusters. Black-Right-Pointing-Pointer Carboxylates show important effect on the structures of

  15. In situ ligand generation for novel Mn(II) and Ni(II) coordination polymers with disulfide ligand: Solvothermal syntheses, structures and magnetic properties

    SciTech Connect (OSTI)

    Han, Yinfeng Wang, Chang'an; Zheng, Zebao; Sun, Jiafeng; Nie, Kun; Zuo, Jian; Zhang, Jianping

    2015-07-15

    Two coordination polymers, ([Mn{sub 2}(L1){sub 2}(μ{sub 2}-H{sub 2}O)(H{sub 2}O){sub 4}]·5H{sub 2}O){sub n}1 and ([Ni(L1)(H{sub 2}O){sub 2}]·2H{sub 2}O){sub n}2 (H{sub 2}L1=2,2′-dithiobisnicotinic acid), were prepared by the solvothermal reactions of the Mn(II) or Ni(II) ions with 2-mercaptonanicotinic acid. In 1, the [Mn{sub 2}(COO){sub 4}] units are connected by the 2,2′-dithiobisnicotinic dianion to form a two-dimensional (4,4)-connected network. In 2, the adjacent Ni(II) ions are connected by the carboxyl groups of the 2,2′-dithiobisnicotinic dianion to form an one-dimensional inorganic rod-shaped chain [Ni(COO){sub 2}]{sub n}, which are further interconnected by the 2,2′-dithiobisnicotinic ligand, giving rise to a two-dimensional framework. Variable-temperature magnetic susceptibilities of 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent metal ions. - Graphical abstract: Two 2D coordination polymers were synthesized by transition-metal/in-situ oxidation of 2-mercaptonicotinic acid. The compounds pack into 2D frameworks by the carboxyl groups of 2,2′-dithiobisnicotinic dianion and exhibit overall weak antiferromagnetic coupling. - Highlights: • Two 2D coordination polymers containing 2,2′-dithiobisnicotinic dianion. • In situ oxidation and dehydro coupling reaction of 2-mercaptonbenzoic acid. • Two compounds display weak antiferromagnetic exchanges.

  16. THE POSSIBLE ROLE OF CORONAL STREAMERS AS MAGNETICALLY CLOSED STRUCTURES IN SHOCK-INDUCED ENERGETIC ELECTRONS AND METRIC TYPE II RADIO BURSTS

    SciTech Connect (OSTI)

    Kong, Xiangliang; Chen, Yao; Feng, Shiwei; Wang, Bing; Du, Guohui; Guo, Fan; Li, Gang

    2015-01-10

    Two solar typeII radio bursts, separated by ?24 hr in time, are examined together. Both events are associated with coronal mass ejections (CMEs) erupting from the same active region (NOAA 11176) beneath a well-observed helmet streamer. We find that the typeII emissions in both events ended once the CME/shock fronts passed the white-light streamer tip, which is presumably the magnetic cusp of the streamer. This leads us to conjecture that the closed magnetic arcades of the streamer may play a role in electron acceleration and typeII excitation at coronal shocks. To examine such a conjecture, we conduct a test-particle simulation for electron dynamics within a large-scale partially closed streamer magnetic configuration swept by a coronal shock. We find that the closed field lines play the role of an electron trap via which the electrons are sent back to the shock front multiple times and therefore accelerated to high energies by the shock. Electrons with an initial energy of 300 eV can be accelerated to tens of keV concentrating at the loop apex close to the shock front with a counter-streaming distribution at most locations. These electrons are energetic enough to excite Langmuir waves and radio bursts. Considering the fact that most solar eruptions originate from closed field regions, we suggest that the scenario may be important for the generation of more metric typeIIs. This study also provides an explanation of the general ending frequencies of metric typeIIs at or above 20-30 MHz and the disconnection issue between metric and interplanetary typeIIs.

  17. Hybrid type-I InAs/GaAs and type-II GaSb/GaAs quantum dot structure with enhanced photoluminescence

    SciTech Connect (OSTI)

    Ji, Hai-Ming; Liang, Baolai Simmonds, Paul J.; Juang, Bor-Chau; Yang, Tao; Young, Robert J.; Huffaker, Diana L.

    2015-03-09

    We investigate the photoluminescence (PL) properties of a hybrid type-I InAs/GaAs and type-II GaSb/GaAs quantum dot (QD) structure grown in a GaAs matrix by molecular beam epitaxy. This hybrid QD structure exhibits more intense PL with a broader spectral range, compared with control samples that contain only InAs or GaSb QDs. This enhanced PL performance is attributed to additional electron and hole injection from the type-I InAs QDs into the adjacent type-II GaSb QDs. We confirm this mechanism using time-resolved and power-dependent PL. These hybrid QD structures show potential for high efficiency QD solar cell applications.

  18. Sputtered II-VI Alloys and Structures forTandem PV: Final Subcontract Report, 9 December 2003 - 30 July 2007

    SciTech Connect (OSTI)

    Compaan, A. D.; Collins, R.; Karpov, V. G.; Giolando, D.

    2008-09-01

    This report elaborates on Phase 3 and provides summaries of the first two Phases. Phase 3 research work was divided into five task areas covering different aspects of the II-VI tandem cell.

  19. Synthesis, structure, and magnetic properties of a novel mixed-valence copper(I/II) phosphate, Cu{sub 2}PO{sub 4}

    SciTech Connect (OSTI)

    Etheredge, K.M.S.; Hwu, S.J.

    1995-09-27

    Via phase compatibility studies, a novel mixed-valence copper(I/II) phosphate, Cu{sub 2}PO{sub 4}, has been isolated from a direct reaction of Cu{sub 2}{sup I}O, Cu{sup II}O, and P{sub 2}O{sub 5} in fused silica. The single-crystal X-ray diffraction shows that the title compound crystallizes in a triclinic (P1) unit cell, with lattice dimensions a = 6.145(2) {angstrom}, b = 9.348(2) {angstrom}, c = 6.009(1) {angstrom}, {alpha} = 96.46(2){degrees}, {beta} = 100.16(2){degrees}, {gamma} = 73.97(2){degrees}, V = 325.8(1) {angstrom}{sup 3}; Z =4. The structure has been refined by the least-squares method to R = 0.019, R{sub w} = 0.030, and GOF = 1.43 for 128 variables. The four copper atoms in each asymmetric unit adopt three distorted coordination geometries that are consistent with the corresponding electronic states, e.g., square pyramidal Cu(1){sup II}O{sub 5}, octahedral Cu(2){sup II}O{sub 6}, and linear Cu(3,4){sup I}O{sub 2}. A low-dimensional framework exists consisting of arrays of nearly parallel CuO{sub 2} units which are separated by the nonmagnetic, closed-shell P{sup 5+} cation in PO{sub 4} tetrahedra. Closely spaced CuO{sub 2} chains and a relatively short Cu{sup I}-Cu{sup I} distance, e.g., 2.737 {angstrom} for Cu(3)-Cu(3), are attributed to the bond strength of the cross-linked PO{sub 4} tetrahedra. In the extended Cu(I/II)-O framework, short linkages of Cu{sup I}-O-Cu{sup II}-O-Cu{sup I} and Cu{sup II}-O-Cu{sup II}, composed of regular Cu-O bonds (1.86-1.99 {angstrom}), are interconnected through long Cu{sup II}-O bonds (2.36-2.74 {angstrom}). The magnetic measurements indicate that the Cu-O framework exhibits a spin 1/2 ground state and an antiferromagnetic ordering with a broad susceptibility maximum between 95 and 105 K. The results of stoichiometric synthesis, thermal analysis, and bond valence sum calculations of the title compound are also discussed.

  20. Copper(II) complexes with 4-(1H-1, 2, 4-trizol-1-ylmethyl) benzoic acid: Syntheses, crystal structures and antifungal activities

    SciTech Connect (OSTI)

    Xiong, Pingping; Li, Jie; Bu, Huaiyu; Wei, Qing; Zhang, Ruolin; Chen, Sanping

    2014-07-01

    Reaction of Cu(II) with an asymmetric semi-rigid organic ligand 4-(1H-1, 2, 4-trizol-1-ylmethyl) benzoic acid (HL), yielded five compounds, [Cu{sub 0.5}L]{sub n} (1), [Cu(HL){sub 2}Cl{sub 2}]{sub n} (2), [Cu(HL){sub 2}Cl{sub 2}(H{sub 2}O)] (3), [Cu(L){sub 2}(H{sub 2}O)]{sub n} (4) and [Cu(L)(phen)(HCO{sub 2})]{sub n} (5), which have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. As for compounds 1, 2 and 5, Cu(II) is bridged through HL, Cl{sup -}, and formic acid, respectively, featuring 1D chain-structure. In compound 3, Cu(II) with hexahedral coordination sphere is assembled through hydrogen-bonding into 3D supramolecular framework. In compound 4, 1D chain units –Cu–O–Cu–O– are ligand-bridged into a 3D network. All compounds were tested on fungi (Fusarium graminearum, Altemaria solani, Macrophoma kawatsukai, Alternaria alternata and Colletotrichum gloeosporioides). Compound 1 exhibits a better antifungal effect compared to other compounds. An effect of structure on the antifungal activity has also been correlated. - Graphical abstract: Copper(II) compounds with 4-(1H-1, 2, 4-trizol-1-ylmethyl) benzoic acid, were prepared, structurally characterized and investigated for antifungal activity. - Highlights: • The title compounds formed by thermodynamics and thermokinetics. • The five compounds show higher inhibition percentage than reactants. • The structure effect on the antifungal activity.

  1. The H I chronicles of little things BCDs II: The origin of IC 10's H I structure

    SciTech Connect (OSTI)

    Ashley, Trisha; Simpson, Caroline E.; Pokhrel, Nau Raj; Elmegreen, Bruce G.; Johnson, Megan; Nidever, David L. E-mail: simpsonc@fiu.edu E-mail: bge@us.ibm.com E-mail: dnidever@umich.edu

    2014-12-01

    In this paper we analyze Very Large Array (VLA) telescope and Green Bank Telescope (GBT) atomic hydrogen (H I) data for the LITTLE THINGS (Local Irregulars That Trace Luminosity Extremes, The H I Nearby Galaxy Survey; https://science.nrao.edu/science/surveys/littlethings) blue compact dwarf galaxy IC 10. The VLA data allow us to study the detailed H I kinematics and morphology of IC 10 at high resolution while the GBT data allow us to search the surrounding area at high sensitivity for tenuous H I. IC 10's H I appears highly disturbed in both the VLA and GBT H I maps with a kinematically distinct northern H I extension, a kinematically distinct southern plume, and several spurs in the VLA data that do not follow the general kinematics of the main disk. We discuss three possible origins of its H I structure and kinematics in detail: a current interaction with a nearby companion, an advanced merger, and accretion of intergalactic medium. We find that IC 10 is most likely an advanced merger or a galaxy undergoing accretion.

  2. IMPROVED V II log(gf) VALUES, HYPERFINE STRUCTURE CONSTANTS, AND ABUNDANCE DETERMINATIONS IN THE PHOTOSPHERES OF THE SUN AND METAL-POOR STAR HD 84937

    SciTech Connect (OSTI)

    Wood, M. P.; Lawler, J. E.; Den Hartog, E. A.; Sneden, C.; Cowan, J. J. E-mail: jelawler@wisc.edu E-mail: chris@verdi.as.utexas.edu

    2014-10-01

    New experimental absolute atomic transition probabilities are reported for 203 lines of V II. Branching fractions are measured from spectra recorded using a Fourier transform spectrometer and an echelle spectrometer. The branching fractions are normalized with radiative lifetime measurements to determine the new transition probabilities. Generally good agreement is found between this work and previously reported V II transition probabilities. Two spectrometers, independent radiometric calibration methods, and independent data analysis routines enable a reduction in systematic uncertainties, in particular those due to optical depth errors. In addition, new hyperfine structure constants are measured for selected levels by least squares fitting line profiles in the FTS spectra. The new V II data are applied to high resolution visible and UV spectra of the Sun and metal-poor star HD 84937 to determine new, more accurate V abundances. Lines covering a range of wavelength and excitation potential are used to search for non-LTE effects. Very good agreement is found between our new solar photospheric V abundance, log ε(V) = 3.95 from 15 V II lines, and the solar-system meteoritic value. In HD 84937, we derive [V/H] = –2.08 from 68 lines, leading to a value of [V/Fe] = 0.24.

  3. NMR studies of chiral P,S-chelate platinum, rhodium, and iridium complexes and the X-ray structure of a palladium(II) allyl derivative

    SciTech Connect (OSTI)

    Albinati, A. [Univ. of Milan (Italy)] [Univ. of Milan (Italy); Eckert, J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States); Pregosin, P.; Ruegger, H.; Salzmann, R.; Stoessel, C. [ETH-Zentrum, Zuerich (Switzerland)] [ETH-Zentrum, Zuerich (Switzerland)

    1997-02-18

    Several Rh(I), Ir(III), and Pt(II) complexes of the chiral P,S-bidentate ligand 2 have been prepared and characterized. Detailed two-dimensional NMR studies show that (i) the boat-type chelate ring and the stereogenic sulfur center can invert rapidly at ambient temperature and (ii) the sulfur donor may dissociate, essentially destroying the chiral pocket. The solid-state structure of [Pt({eta}{sup 3}-C{sub 3}H{sub 5})(2)]PF{sub 6} (3) has been determined and the sulfur substituent shown to have an axial orientation. The six-membered chelate ring takes up a boat-like conformation. As shown by an X-ray diffraction study for 3, and via incoherent inelastic neutron scattering (IINS) measurements for the Pd analog, 4, the OH group is remote from the metal atom. 42 refs., 11 figs., 6 tabs.

  4. Aerobic C-H Acetoxylation of 8-Methylquinoline in PdII-Pyridinecarboxylic Acid Systems: Some Structure-Reactivity Relationships

    SciTech Connect (OSTI)

    Wang, Daoyong; Zavalij, Peter Y.; Vedernikov, Andrei N.

    2013-09-09

    Catalytic oxidative CH acetoxylation of 8-methylquinoline as a model substrate with O2 as oxidant was performed using palladium(II) carboxylate catalysts derived from four different pyridinecarboxylic acids able to form palladium(II) chelates of different size. A comparison of the rates of the substrate CH activation and the O2 activation steps shows that the CH activation step is rate-limiting, whereas the O2 activation occurs at a much faster rate already at 20 C. The chelate ring size and the chelate ring strain of the catalytically active species are proposed to be the key factors affecting the rate of the CH activation.

  5. Two new Co(II)-MOFs based on polymeric chain building units: Crystal structures, and magnetic properties

    SciTech Connect (OSTI)

    Han, Min-Le; Wu, Ya-Pan; Zhao, Jun; Li, Dong-Sheng; Wang, Yao-Yu

    2015-10-15

    Two new Co(II) metal-organic frameworks, namely [Co{sub 2}(bpm)(H{sub 2}O){sub 3}(L)]{sub n} (1) and ([Co(bpe)(H{sub 2}O)(H{sub 2}L)]·(bpe){sub 0.5}·(H{sub 2}O)){sub n} (2), (H{sub 4}L=1,1′:2′,1″-terphenyl-3,3″,4′,5′-tetracarboxylic acid, bpm=bis(4-pyridyl)amine, bpe=1,2-bis(4-pyridyl)ethene), have been obtained under hydrothermal conditions. Both complexes 1 and 2 have been characterized by elemental analysis, IR spectra, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). Complexes 1 and 2 consist of 1D Co(II) chains bridging by carboxylate groups in syn-anti fashion. 1 shows a novel 3D tri-nodal (4,6,10)-connected net with a (3.4{sup 3}.5{sup 2}){sub 2}(3{sup 2}.4{sup 14}.5{sup 12}.6{sup 12}.7{sup 4}.8)(3{sup 2}.4{sup 2}.5{sup 5}.6{sup 4}.7{sup 2}) topology. While 2 exhibits a 2D sql layer. Magnetic susceptibility measurements indicate that both 1 and 2 show weak antiferromagnetic interactions between the adjacent Co(II) ions in 300–8 K for 1 and 300–16 K for 2, respectively, and then 2 also displays ferromagnetic coupling at lower temperatures. - Graphical abstract: Two Co(II) coordination polymers with similar metal chain bridging by carboxylates in syn-anti fashion have been synthesized. Both 1 and 2 show weak antiferromagnetic interactions in high temperature, and then 2 also displays ferromagnetic coupling at lower temperatures. - Highlights: • Two Co(II) coordination polymers with similar metal chain bridging by carboxylates. • A novel 3D (4,6,10)-connected net and a 2D sql layers. • A antiferromagnetic coupling at high temperature for 1 and 2. • A ferromagnetic coupling at lower temperature for 2.

  6. Five new Zn(II) and Cd(II) coordination polymers constructed by 3,5-bis-oxyacetate-benzoic acid: Syntheses, crystal structures, network topologies and luminescent properties

    SciTech Connect (OSTI)

    Jiang Xianrong; Yuan Hongyan; Feng Yunlong

    2012-07-15

    Five Zn(II) and Cd(II) coordination polymers, [Zn{sub 2}(BOABA)(bpp)(OH)]{center_dot}0.5H{sub 2}O (1), [Cd{sub 3}(BOABA){sub 2}(bpp){sub 2}(H{sub 2}O){sub 6}]{center_dot}2H{sub 2}O (2), [Cd{sub 3}(BOABA){sub 2}(2,2 Prime -bipy){sub 3}(H{sub 2}O){sub 4}]{center_dot}5.5H{sub 2}O (3), [CdNa(BOABA)(H{sub 2}O)]{sub 2}{center_dot}H{sub 2}O (4) and [Cd{sub 2}(BOABA)(bimb)Cl(H{sub 2}O){sub 2}]{center_dot}H{sub 2}O (5) (H{sub 3}BOABA=3,5-bis-oxyacetate-benzoic acid, bpp=1,3-bi(4-pyridyl)propane, 2,2 Prime -bipy=2,2 Prime -bipyridine, bimb=1,4-bis(imidazol-1 Prime -yl)butane), have been solvothermally synthesized and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra and TG analyses. 1 is an uninodal 4-connected 2D square grid network based on binuclear zinc clusters. 2 is 2D wavelike layer structure and further linked by hydrogen bonds into the final 3D (5,6,6)-connected topology network. 3 is 3-connected 2D topology network and the 2,2 Prime -bipy ligands decorate in two different types. 4 is a (4,8)-connected 2D topology network with heterocaryotic {l_brace}Cd{sub 2}Na{sub 2}{r_brace} clusters and BOABA{sup 3-} ligands. 5 can be rationalized as a (3,10)-connected 3D topology network with tetranuclear {l_brace}Cd{sub 4}Cl{sub 2}{r_brace} clusters and BOABA{sup 3-} ligands. Meanwhile, photoluminescence studies revealed that these five coordination polymers display strong fluorescent emission bands in the solid state at room temperature. - Graphical abstract: Five new d{sup 10} metal(II) coordination polymers based on H{sub 3}BOABA ligand were obtained and characterized. They display different topological structures and luminescent properties. Highlights: Black-Right-Pointing-Pointer Five d{sup 10} metal(II) polymers based on 3,5-bis-oxyacetate-benzoic acid were obtained. Black-Right-Pointing-Pointer The polymers were structurally characterized by single-crystal X-ray diffraction. Black-Right-Pointing-Pointer Polymers 1-5 display different

  7. Effect of three bis-pyridyl-bis-amide ligands with various spacers on the structural diversity of new multifunctional cobalt(II) coordination polymers

    SciTech Connect (OSTI)

    Lin, Hong-Yan; Lu, Huizhe; Le, Mao; Luan, Jian; Wang, Xiu-Li; Liu, Guocheng; Zhang, Juwen

    2015-03-15

    Three new cobalt(II) coordination polymers [Co{sub 2}(1,4-NDC){sub 2}(3-bpye)(H{sub 2}O)] (1), [Co(1,4-NDC)(3-bpfp)(H{sub 2}O)] (2) and [Co(1,4-NDC)(3-bpcb)] (3) [3-bpye=N,N′-bis(3-pyridinecarboxamide)-1,2-ethane, 3-bpfp=bis(3-pyridylformyl)piperazine, 3-bpcb=N,N′-bis(3-pyridinecarboxamide)-1,4-benzene, and 1,4-H{sub 2}NDC=1,4-naphthalenedicarboxylic acid] have been hydrothermally synthesized. The structures of complexes 1–3 have been determined by X-ray single crystal diffraction analyses and further characterized by infrared spectroscopy (IR), powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Complex 1 is a 3D coordination structure with 8-connected (4{sup 20}.6{sup 8}) topology constructed from 3D [Co{sub 2}(1,4-NDC){sub 2}(H{sub 2}O)]{sub n} framework and bidentate 3-bpye ligands. Complex 2 shows 1D “cage+cage”-like chain formed by 1D [Co{sub 2}(1,4-NDC){sub 2}]{sub n} ribbon chains and [Co{sub 2}(3-bpfp){sub 2}] loops, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. Complex 3 displays a 3D coordination network with a 6-connected (4{sup 12}.6{sup 3}) topology based on 2D [Co{sub 2}(1,4-NDC){sub 2}]{sub n} layers and bidentate 3-bpcb bridging ligands. The influences of different bis-pyridyl-bis-amide ligands with various spacers on the structures of title complexes are studied. Moreover, the fluorescent properties, electrochemical behaviors and magnetic properties of complexes 1–3 have been investigated. - Graphical abstract: Three multifunctional cobalt(II) complexes constructed from three bis-pyridyl-bis-amide and 1,4-naphthalenedicarboxylic acid have been hydrothermally synthesized and characterized. The fluorescent, electrochemical and magnetic properties of 1–3 have been investigated. - Highlights: • Three multifunctional cobalt(II) complexes based on various bis-pyridyl-bis-amide ligands. • Complex 1 is a 3D coordination structure with 8-connected (4{sup 20}.6{sup 8

  8. Inter-cage dynamics in structure I, II, and H fluoromethane hydrates as studied by NMR and molecular dynamics simulations

    SciTech Connect (OSTI)

    Trueba, Alondra Torres; Kroon, Maaike C.; Peters, Cor J.; Moudrakovski, Igor L.; Ratcliffe, Christopher I.; Ripmeester, John A.; Alavi, Saman

    2014-06-07

    Prospective industrial applications of clathrate hydrates as materials for gas separation require further knowledge of cavity distortion, cavity selectivity, and defects induction by guest-host interactions. The results presented in this contribution show that under certain temperature conditions the guest combination of CH{sub 3}F and a large polar molecule induces defects on the clathrate hydrate framework that allow intercage guest dynamics. {sup 13}C NMR chemical shifts of a CH{sub 3}F/CH{sub 4}/TBME sH hydrate and a temperature analysis of the {sup 2}H NMR powder lineshapes of a CD{sub 3}F/THF sII and CD{sub 3}F/TBME sH hydrate, displayed evidence that the populations of CH{sub 4} and CH{sub 3}F in the D and D{sup ?} cages were in a state of rapid exchange. A hydrogen bonding analysis using molecular dynamics simulations on the TBME/CH{sub 3}F and TBME/CH{sub 4} sH hydrates showed that the presence of CH{sub 3}F enhances the hydrogen bonding probability of the TBME molecule with the water molecules of the cavity. Similar results were obtained for THF/CH{sub 3}F and THF/CH{sub 4} sII hydrates. The enhanced hydrogen bond formation leads to the formation of defects in the water hydrogen bonding lattice and this can enhance the migration of CH{sub 3}F molecules between adjacent small cages.

  9. A series of Cd(II) complexes with {pi}-{pi} stacking and hydrogen bonding interactions: Structural diversities by varying the ligands

    SciTech Connect (OSTI)

    Wang Xiuli; Zhang Jinxia; Liu Guocheng; Lin Hongyan

    2011-02-15

    Seven new Cd(II) complexes consisting of different phenanthroline derivatives and organic acid ligands, formulated as [Cd(PIP){sub 2}(dnba){sub 2}] (1), [Cd(PIP)(ox)].H{sub 2}O (2), [Cd(PIP)(1,4-bdc)(H{sub 2}O)].4H{sub 2}O (3), [Cd(3-PIP){sub 2}(H{sub 2}O){sub 2}].4H{sub 2}O (4), [Cd{sub 2}(3-PIP){sub 4}(4,4'-bpdc)(H{sub 2}O){sub 2}].5H{sub 2}O (5), [Cd(3-PIP)(nip)(H{sub 2}O)].H{sub 2}O (6), [Cd{sub 2}(TIP){sub 4}(4,4'-bpdc)(H{sub 2}O){sub 2}].3H{sub 2}O (7) (PIP=2-phenylimidazo[4,5-f]1,10-phenanthroline, 3-PIP=2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline, TIP=2-(2-thienyl)imidazo[4,5-f]1,10-phenanthroline, Hdnba=3,5-dinitrobenzoic acid, H{sub 2}ox=oxalic acid, 1,4-H{sub 2}bdc=benzene-1,4-dicarboxylic acid, 4,4'-H{sub 2}bpdc=biphenyl-4,4'-dicarboxylic acid, H{sub 2}nip=5-nitroisophthalic acid) have been synthesized under hydrothermal conditions. Complexes 1 and 4 possess mononuclear structures; complexes 5 and 7 are isostructural and have dinuclear structures; complexes 2 and 3 feature 1D chain structures; complex 6 contains 1D double chain, which are further extended to a 3D supramolecular structure by {pi}-{pi} stacking and hydrogen bonding interactions. The N-donor ligands with extended {pi}-system and organic acid ligands play a crucial role in the formation of the final supramolecular frameworks. Moreover, thermal properties and fluorescence of 1-7 are also investigated. -- Graphical abstract: Seven new supramolecular architectures have been successfully isolated under hydrothermal conditions by reactions of different phen derivatives and Cd(II) salts together with organic carboxylate anions auxiliary ligands. Display Omitted Research highlights: {yields} Complexes 1-7 are 0D or 1D polymeric structure, the {pi}-{pi} stacking and H-bonding interactions extend the complexes into 3D supramolecular network. To our knowledge, systematic study on {pi}-{pi} stacking and H-bonding interactions in cadmium(II) complexes are still limited. {yields} The structural

  10. Finding Large Aperture Fractures in Geothermal Resource Areas Using a Three-Component Long-Offset Surface Seismic Survey, PSInSAR and Kinematic Structural Analysis

    SciTech Connect (OSTI)

    Teplow, William J.; Warren, Ian

    2015-08-12

    The DOE cost-share program applied innovative and cutting edge seismic surveying and processing, permanent scatter interferometry-synthetic aperture radar (PSInSAR) and structural kinematics to the exploration problem of locating and mapping largeaperture fractures (LAFs) for the purpose of targeting geothermal production wells. The San Emidio geothermal resource area, which is under lease to USG, contains production wells that have encountered and currently produce from LAFs in the southern half of the resource area (Figure 2). The USG lease block, incorporating the northern extension of the San Emidio geothermal resource, extends 3 miles north of the operating wellfield. The northern lease block was known to contain shallow thermal waters but was previously unexplored by deep drilling. Results of the Phase 1 exploration program are described in detail in the Phase 1 Final Report (Teplow et al., 2011). The DOE cost shared program was completed as planned on September 30, 2014. This report summarizes results from all of Phase 1 and 2 activities.

  11. Galaxy evolution and large-scale structure in the far-infrared. II. The IRAS faint source survey

    SciTech Connect (OSTI)

    Lonsdale, C.J.; Hacking, P.B.; Conrow, T.P.; Rowan-Robinson, M. Queen Mary College, London )

    1990-07-01

    The new IRAS Faint Source Survey data base is used to confirm the conclusion of Hacking et al. (1987) that the 60 micron source counts fainter than about 0.5 Jy lie in excess of predictions based on nonevolving model populations. The existence of an anisotropy between the northern and southern Galactic caps discovered by Rowan-Robinson et al. (1986) and Needham and Rowan-Robinson (1988) is confirmed, and it is found to extend below their sensitivity limit to about 0.3 Jy in 60 micron flux density. The count anisotropy at f(60) greater than 0.3 can be interpreted reasonably as due to the Local Supercluster; however, no one structure accounting for the fainter anisotropy can be easily identified in either optical or far-IR two-dimensional sky distributions. The far-IR galaxy sky distributions are considerably smoother than distributions from the published optical galaxy catalogs. It is likely that structure of the large size discussed here have been discriminated against in earlier studies due to insufficient volume sampling. 105 refs.

  12. EA-1809: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Finding of No Significant Impact EA-1809: Finding of No Significant Impact White Earth Nation Wind Energy Project II, Becker and Mahnomen Counties, MN DOE's Golden Field Office has...

  13. EA-1904: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA-1904: Finding of No Significant Impact Linac Coherent Light Source II at Stanford Linear Accelerator Laboratory, San Mateo, CA Based on the findings in the EA, DOE has...

  14. Synthesis and X-ray structure analysis of a new binuclear Schiff base Co(II) complex with the ligand N,N'-bis(3-methoxysalicylidene)-1,4-butanediamine

    SciTech Connect (OSTI)

    Nasr-Esfahani, M.

    2009-12-15

    The title binuclear complex, tris[N,N-bis(3-methoxysalicylidene)-1,4-diaminobutane] dicobalt(II), C{sub 60}H{sub 70}Co{sub 2}N{sub 6}O{sub 15}, was prepared by the reaction of the tetradentate Schiff base ligand bis(3-methoxysalicylidene)-1,4-diaminobutane and Co(CH{sub 3}COO){sub 2} . 4H{sub 2}O in a ethanol solution and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two Co(II) ions are bridged by one N{sup 0},N'-bis(3-methoxysalicylidene)-1,4-diaminobutane. The two Co(II) ions, have two distorted octahedral coordination involving two O and two N atoms.

  15. PARS II Training Materials | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    attachments, and running standard, pre-built reports. PARS 102 Presentation PARS 102 Workbook PARS 103 - Updating Projects and Reporting Introduction to PARS II, finding and...

  16. Synthesis, crystal structure and magnetic characterization of metal(II) coordination polymers based on 2-carboxyethylphosphonic acid and 1,10-phenanthroline (metal=Cu, Co, Cd)

    SciTech Connect (OSTI)

    Fernandez-Zapico, Eva; Montejo-Bernardo, Jose Manuel; D'Vries, Richard; Garcia, Jose R.; Garcia-Granda, Santiago; Rodriguez Fernandez, Jesus; Pedro, Imanol de; Blanco, Jesus A.

    2011-12-15

    Three non-isostructural metal(II) coordination polymers (metal=copper, cobalt, cadmium) were synthesized under the same mild hydrothermal conditions (T=408 K) by mixture of the corresponding metal acetate with 2-carboxyethylphosphonic acid and 1,10-phenanthroline (1:1:1 M ratio) and their structures were determined by single-crystal X-ray diffraction. Cu{sub 2}(HO{sub 3}PCH{sub 2}CH{sub 2}COO){sub 2}(C{sub 12}H{sub 8}N{sub 2}){sub 2}(H{sub 2}O){sub 2} and Cd{sub 2}(HO{sub 3}PCH{sub 2}CH{sub 2}COO){sub 2}(C{sub 12}H{sub 8}N{sub 2}){sub 2} are triclinic (space group P-1) with a=7.908(5) A, b=10.373(5) A, c=11.515(5) A, {alpha}=111.683(5) Degree-Sign , {beta}=95.801(5) Degree-Sign , {gamma}=110.212(5) Degree-Sign (T=120 K), and a=8.162(5) A, b=9.500(5) A, c=11.148(5) A, {alpha}=102.623(5) Degree-Sign , {beta}=98.607(5) Degree-Sign , {gamma}=113.004(5) Degree-Sign (T=293 K), respectively. In contrast, [Co{sub 2}(HO{sub 3}PCH{sub 2}CH{sub 2}COO){sub 2}(C{sub 12}H{sub 8}N{sub 2}){sub 2}({mu}-OH{sub 2})](H{sub 2}O) is orthorhombic (space group Pbcn) with a=21.1057(2) A, b=9.8231(1) A, c=15.4251(1) A (T=120 K). For these three compounds, structural features, including H-bond network and the {pi}-{pi} stacking interactions, and thermal stability are reported and discussed. None of the materials present a long-range magnetic order in the range of temperatures investigated from 300 K down to 1.8 K. - Graphical abstract: In same synthetic conditions, both the chemical and structural features of three transition metal(II) coordination polymers based on 2-carboxyethylphosphonate and 1-10 Prime -phenanthroline are influenced by the metal cation characteristics, leading to non-homologous materials with different properties, which show the high chemical versatility of this interesting system. Highlights: Black-Right-Pointing-Pointer Non-isostructural metal coordination polymers were synthesized under mild hydrothermal conditions. Black-Right-Pointing-Pointer Ligand's flexibility

  17. Analysis of the structural parameters that influence gas production from the Devonian shale. Annual progress report, 1979-1980. Volume II. Data repository and reports published during fiscal year 1979-1980: regional structure, surface structure, surface fractures, hydrology

    SciTech Connect (OSTI)

    Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.; Lee, K. D.; Ruotsala, J. E.; Wilson, T. H.; Williams, R. T.

    1980-10-01

    This volume comprises appendices giving regional structure data, surface structure data, surface fracture data, and hydrology data. The fracture data covers oriented Devonian shale cores from West Virginia, Ohio, Virginia, Pennsylvania, and Kentucky. The subsurface structure of the Eastern Kentucky gas field is also covered. (DLC)

  18. Weatherization Works II - Summary of Findings from the ARRA Period...

    Broader source: Energy.gov (indexed) [DOE]

    ... For example, the income eligibility requirements were adjusted from being 150% of the federal poverty level to 200% and the average amount of DOE funds that could be invested in a ...

  19. PARS II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... September 9, 2010 (V1.1) PARS II 103 Project Updating and Reporting Page 49 4. Click to begin entering funding values. 5. Click + sign to expand detail for OPC, TEC, and UND, if ...

  20. H I ABSORPTION TOWARD H II REGIONS AT SMALL GALACTIC LONGITUDES

    SciTech Connect (OSTI)

    Jones, C.; Dickey, J. M.; Dawson, J. R.; McClure-Griffiths, N. M.; Anderson, L. D.; Bania, T. M.

    2013-09-10

    We make a comprehensive study of H I absorption toward H II regions located within |l| < 10 Degree-Sign . Structures in the extreme inner Galaxy are traced using the longitude-velocity space distribution of this absorption. We find significant H I absorption associated with the Near and Far 3 kpc Arms, the Connecting Arm, Bania's Clump 1, and the H I Tilted Disk. We also constrain the line-of-sight distances to H II regions, by using H I absorption spectra together with the H II region velocities measured by radio recombination lines.

  1. National Synchrotron Light Source II (NSLS-II) Project | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Synchrotron Light Source II (NSLS-II) Project National Synchrotron Light Source II (NSLS-II) Project National Synchrotron Light Source II (NSLS-II) Project Frank ...

  2. Thermodynamical and structural insights of orange II adsorption by Mg{sub R}AlNO{sub 3} layered double hydroxides

    SciTech Connect (OSTI)

    Mustapha Bouhent, Mohamed; Derriche, Zoubir; Denoyel, Renaud; Prevot, Vanessa; Forano, Claude

    2011-05-15

    [Mg{sub 1-x} Al{sub x}(OH){sub 2}][(NO{sub 3}){sub x}, nH{sub 2}O] Layered Double Hydroxide (LDH) sorbents with variable Mg/Al molar (R=(1-x)/x) ratios were investigated for adsorption of azo dye, orange II (OII) at various pH and temperature conditions. Mg{sub 2}AlNO{sub 3} displays the highest adsorption capacity with 3.611 mmol of OII per gram of Mg{sub 2}AlNO{sub 3} at 40 {sup o}C. Adsorption isotherms have been fitted using the Langmuir model and free energy of adsorption ({Delta}G{sup o}), enthalpy ({Delta}H{sup o}) and entropy ({Delta}S{sup o}) were calculated. The experimental values for {Delta}G{sup o} in temperature range between 10 and 40 {sup o}C were found to be negative indicating that a spontaneous process occurred. Positive calculated enthalpy values, characteristic of an endothermic process were found. Characterization of solids (PXRD, FTIR, UV-vis, TGA/DTA, adsorption isotherm BET analysis, SEM and Zetametry) before and after adsorption showed that adsorption proceeds in two steps. First, adsorption occurs at the LDH surface, followed by intercalation via anion exchange. -- Graphical Abstract: Structural and thermodynamical insight of adsorption/Intercalation of OII in Mg{sub R}Al LDH Display Omitted Highlights: {yields} The nitrate containing hydrotalcite-like compounds (Mg{sub R}AlNO{sub 3} LDH) were prepared by the coprecipitation method. {yields} Adsorption of anionic orange dye(OII) is studied on LDHs at different temperatures. {yields} The adsorption process is well described by the Langmuir isotherm model. {yields} Mg{sub 2}AlNO{sub 3} displays the highest adsorption capacity with 3.611 mmol of OII per gram of Mg{sub 2}AlNO{sub 3} at 40 {sup o}C. {yields} Adsorption process does not occur on the surface of the LDH only but an intercalation process is also occurring concomitantly according to the thermodynamical values.

  3. EA-1744: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Finding of No Significant Impact EA-1744: Finding of No Significant Impact Brea Power II, LLC's Olinda Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas, Brea, California Based in the analyses in the Environmental Assessment, DOE determined that its proposed action - awarding a grant to Brea Power II, LLC to facilitate modifcation and expansion of an existing landfill gas collection system and construction and operation of a combined cycle power facility at the Olinda Alpha

  4. A novel inorganic-organic compound: Synthesis and structural characterization of tin(II) phenylbis(phosphonate), Sn{sub 2}(PO{sub 3}C{sub 6}H{sub 4}PO{sub 3})

    SciTech Connect (OSTI)

    Subbiah, Ayyappan; Bhuvanesh, Nattamai; Clearfield, Abraham . E-mail: clearfield@mail.chem.tamu.edu

    2005-04-15

    A novel tin(II) phenylbis(phosphonate) compound has been synthesized hydrothermally and its structure has been determined by single crystal X-ray diffraction. The structure is monoclinic, space group P2{sub 1}/c (no. 14), a=4.8094(4), b=16.2871(13), c=6.9107(6)A; {beta}=106.292(6){sup o}, V=519.59(7)A{sup 3}, Z=2. The three-dimensional structure consists of 3-coordinated tin and 4-coordinated phosphorus double layers separated (pillared) by phenyl rings. These phenyl rings are placed 4.8A apart along the a-axis in the structure resulting in lower surface area ({approx}14m{sup 2}/g). The porosity has been increased by replacing phenyl groups by methyl groups ({approx}31m{sup 2}/g)

  5. BORE II

    SciTech Connect (OSTI)

    2015-08-01

    Bore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and for improving remediation of contaminated sites. Termed "hydrophysical logging," this technology is based on the concept of measuring repeated depth profiles of fluid electric conductivity in a borehole that is pumping. As fluid enters the wellbore, its distinct electric conductivity causes peaks in the conductivity log that grow and migrate upward with time. Analysis of the evolution of the peaks enables characterization of groundwater flow distribution more quickly, more cost effectively, and with higher resolution than ever before. Combining the unique interpretation software Bore II with advanced downhole instrumentation (the hydrophysical logging tool), the method quantifies inflow and outflow locations, their associated flow rates, and the basic water quality parameters of the associated formation waters (e.g., pH, oxidation-reduction potential, temperature). In addition, when applied in conjunction with downhole fluid sampling, Bore II makes possible a complete assessment of contaminant concentration within groundwater.

  6. BORE II

    Energy Science and Technology Software Center (OSTI)

    2015-08-01

    Bore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and for improving remediation of contaminated sites. Termed "hydrophysical logging," this technology is based on the concept of measuring repeated depth profiles of fluid electric conductivity in a borehole that is pumping. As fluid enters the wellbore, its distinct electric conductivity causes peaks in the conductivity log that grow and migratemore » upward with time. Analysis of the evolution of the peaks enables characterization of groundwater flow distribution more quickly, more cost effectively, and with higher resolution than ever before. Combining the unique interpretation software Bore II with advanced downhole instrumentation (the hydrophysical logging tool), the method quantifies inflow and outflow locations, their associated flow rates, and the basic water quality parameters of the associated formation waters (e.g., pH, oxidation-reduction potential, temperature). In addition, when applied in conjunction with downhole fluid sampling, Bore II makes possible a complete assessment of contaminant concentration within groundwater.« less

  7. Find Theses and Dissertations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theses and Dissertations Find Theses and Dissertations Most of the theses sources below are publicly accessible. Questions? 667-5809 Email Electronic Databases Open Access Theses and Dissertations - Results limited to freely accessible, full-text ETDs Center for Research Libraries - Foreign Dissertations Collection Theses Canada - Canadian theses from Library and Archives Canada EThOS (Electronic Theses Online Service) - UK theses from the British Library Networked Digital Library of Theses and

  8. Computational insights on crystal structures of the oxygen-evolving complex of photosystem II with either Ca²⁺ or Ca²⁺ substituted by Sr²⁺

    SciTech Connect (OSTI)

    Vogt, Leslie; Ertem, Mehmed Z.; Pal, Rhitankar; Brudvig, Gary W.; Batista, Victor S.

    2015-01-15

    The oxygen-evolving complex of photosystem II can function with either Ca²⁺ or Sr²⁺ as the heterocation, but the reason for differing turnover rates remains unresolved despite reported X-ray crystal structures for both forms. Using quantum mechanics/molecular mechanics (QM/MM) calculations, we optimize structures with each cation in both the resting state (S₁) and in a series of reduced states (S₀, S₋₁, and S-₂). Through comparison with experimental data, we determine that X-ray crystal structures with either Ca²⁺ or Sr²⁺ are most consistent with the S-₂ state, Mn₄[III,III,III,II] with O4 and O5 protonated. As expected, the QM/MM models show that Ca²⁺/Sr²⁺ substitution results in elongation of the heterocation bonds and displaces terminal waters W3 and W4. The optimized structures also show that hydrogen-bonded W5 is displaced in all S states with Sr²⁺ as the heterocation, suggesting that this water may play a critical role during water oxidation.

  9. Computational insights on crystal structures of the oxygen-evolving complex of photosystem II with either Ca²⁺ or Ca²⁺ substituted by Sr²⁺

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vogt, Leslie; Ertem, Mehmed Z.; Pal, Rhitankar; Brudvig, Gary W.; Batista, Victor S.

    2015-01-15

    The oxygen-evolving complex of photosystem II can function with either Ca²⁺ or Sr²⁺ as the heterocation, but the reason for differing turnover rates remains unresolved despite reported X-ray crystal structures for both forms. Using quantum mechanics/molecular mechanics (QM/MM) calculations, we optimize structures with each cation in both the resting state (S₁) and in a series of reduced states (S₀, S₋₁, and S-₂). Through comparison with experimental data, we determine that X-ray crystal structures with either Ca²⁺ or Sr²⁺ are most consistent with the S-₂ state, Mn₄[III,III,III,II] with O4 and O5 protonated. As expected, the QM/MM models show that Ca²⁺/Sr²⁺ substitutionmore » results in elongation of the heterocation bonds and displaces terminal waters W3 and W4. The optimized structures also show that hydrogen-bonded W5 is displaced in all S states with Sr²⁺ as the heterocation, suggesting that this water may play a critical role during water oxidation.« less

  10. Raman spectra of Cu{sub 2}B{sup II}C{sup IV}X{sub 4}{sup VI} magnetic quaternary semiconductor compounds with tetragonal stannite type structure

    SciTech Connect (OSTI)

    Rincón, C. Quintero, M.; Power, Ch.; Moreno, E.; Quintero, E.; Morocoima, M.; Henao, J. A.; Macías, M. A.

    2015-05-28

    A comparative study of the Raman spectra of Cu{sub 2}B{sup II}C{sup IV}S{sub 4}{sup VI} and Cu{sub 2}B{sup II}C{sup IV}Se{sub 4}{sup VI}(where B = Mn or Fe) magnetic quaternary semiconductor compounds with stannite-type structure (I4{sup ¯}2m) has been done. Most of the fourteen Raman lines expected for these materials were observed in the spectra. The two strongest lines observed have been assigned to the IR inactive A{sub 1}{sup 1} and A{sub 1}{sup 2} stannite modes that originated from the motion of the S or Se anion around the Cu and C{sup IV} cations remaining at rest. The shift in the frequency of these two lines of about 150 cm{sup −1} to lower energies observed in Cu{sub 2}B{sup II}C{sup IV}Se{sub 4}{sup VI} compounds as compared to those in Cu{sub 2}B{sup II}C{sup IV}S{sub 4}{sup VI} ones, can then be explained as due to the anion mass effect. Based on the fact that values of these frequencies depend mainly on anion mass and bond-stretching forces between nearest-neighbor atoms, the vibrational frequencies v{sup ¯}(A{sub 1}{sup 2}) and v{sup ¯}(A{sub 1}{sup 2}) of both modes for several Cu{sub 2}B{sup II}C{sup IV}X{sub 4}{sup VI} stannite compounds (where X = S, Se, or Te) very close to the experimental data reported for these materials were calculated from a simple model that relates these stretching forces to the anion-cation bond-distances.

  11. Removal of Ca2+ from the Oxygen-Evolving Complex in Photosystem II Has Minimal Effect on the Mn4O5 Core Structure: A Polarized Mn X-ray Absorption Spectroscopy Study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lohmiller, Thomas; Shelby, Megan L.; Long, Xi; Yachandra, Vittal K.; Yano, Junko

    2015-05-19

    We studied Ca2+ -depleted and Ca2+ -reconstituted spinach photosystem II using polarized X-ray absorption spectroscopy of oriented PS II preparations to investigate the structural and functional role of the Ca2+ ion in the Mn4O5Ca cluster of the oxygen-evolving complex (OEC). Samples were prepared by low pH/citrate treatment as one-dimensionally ordered membrane layers and poised in the Ca2+ -depleted S1 (S1') and S2 (S2') states, the S2'YZ• state, at which point the catalytic cycle of water oxidation is inhibited, and the Ca2+ -reconstituted S1 state. Polarized Mn K-edge XANES and EXAFS spectra exhibit pronounced dichroism. Polarized EXAFS data of all statesmore » of Ca2+ -depleted PS II investigated show only minor changes in distances and orientations of the Mn-Mn vectors compared to the Ca2+ -containing OEC, which may be attributed to some loss of rigidity of the core structure. Thus, removal of the Ca2+ ion does not lead to fundamental distortion or rearrangement of the tetranuclear Mn cluster, which indicates that the Ca2+ ion in the OEC is not critical for structural maintenance of the cluster, at least in the S1 and S2 states, but fulfills a crucial catalytic function in the mechanism of the water oxidation reaction. On the basis of this structural information, reasons for the inhibitory effect of Ca2+ removal are discussed, attributing to the Ca2+ ion a fundamental role in organizing the surrounding (substrate) water framework and in proton-coupled electron transfer to YZ• (D1-Tyr161).« less

  12. Ii1

    Office of Legacy Management (LM)

    -r Ii1 5uitc 79% 955 L%fan~Plu,S.W.. Worhingm. D.C.200242134, 7117-03.87.cdy.43 23 September 1987 Mr. Andrew Wallo, III, NE-23 Division of Facility & Site Decommissioning Projects U.S. Department of Energy Germantown, Maryland 20545 Dear Mr. Wallo: ELIMINATION RECOMMENDATION -- COLLEGES AND UNIVtRSITIES The attached elimination recommendation was prepared in accordance.)l- flL.o* with your suggestion during our meeting on 22 September, The recommendat:on y0.0-02 includes 26 colleges and

  13. Part II

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    80 Thursday, No. 251 December 31, 2015 Part II Department of Defense General Services Administration National Aeronautics and Space Administration 48 CFR Chapter 1 Federal Acquisition Regulations; Final Rules VerDate Sep<11>2014 17:22 Dec 30, 2015 Jkt 238001 PO 00000 Frm 00001 Fmt 4717 Sfmt 4717 E:\FR\FM\31DER2.SGM 31DER2 tkelley on DSK3SPTVN1PROD with RULES2 81886 Federal Register / Vol. 80, No. 251 / Thursday, December 31, 2015 / Rules and Regulations DEPARTMENT OF DEFENSE GENERAL

  14. PARS II TRAINING

    Broader source: Energy.gov [DOE]

    PARS II 102 Monthly Updating and Reporting Training Workbook (PARS II Release 1.1), September 13, 2010.

  15. Atomic structure of the sweet-tasting protein thaumatin I at pH 8.0 reveals the large disulfide-rich region in domain II to be sensitive to a pH change

    SciTech Connect (OSTI)

    Masuda, Tetsuya; Ohta, Keisuke; Mikami, Bunzo; Kitabatake, Naofumi; Tani, Fumito

    2012-03-02

    Highlights: Black-Right-Pointing-Pointer Structure of a recombinant thaumatin at pH 8.0 determined at a resolution of 1.0 A. Black-Right-Pointing-Pointer Substantial fluctuations of a loop in domain II was found in the structure at pH 8.0. Black-Right-Pointing-Pointer B-factors for Lys137, Lys163, and Lys187 were significantly affected by pH change. Black-Right-Pointing-Pointer An increase in mobility might play an important role in the heat-induced aggregation. -- Abstract: Thaumatin, an intensely sweet-tasting plant protein, elicits a sweet taste at 50 nM. Although the sweetness remains when thaumatin is heated at 80 Degree-Sign C for 4 h under acid conditions, it rapidly declines when heating at a pH above 6.5. To clarify the structural difference at high pH, the atomic structure of a recombinant thaumatin I at pH 8.0 was determined at a resolution of 1.0 A. Comparison to the crystal structure of thaumatin at pH 7.3 and 7.0 revealed the root-mean square deviation value of a C{alpha} atom to be substantially greater in the large disulfide-rich region of domain II, especially residues 154-164, suggesting that a loop region in domain II to be affected by solvent conditions. Furthermore, B-factors of Lys137, Lys163, and Lys187 were significantly affected by pH change, suggesting that a striking increase in the mobility of these lysine residues, which could facilitate a reaction with a free sulfhydryl residue produced via the {beta}-elimination of disulfide bonds by heating at a pH above 7.0. The increase in mobility of lysine residues as well as a loop region in domain II might play an important role in the heat-induced aggregation of thaumatin above pH 7.0.

  16. PARS II TRAINING

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    13, 2010 (V1.1) PARS II 102 Monthly Updating and Reporting i Project Assessment and Reporting System PARS II 102 Monthly Updating and Reporting Training Workbook (PARS II Release ...

  17. ARM - RHUBC II Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Instruments Related Links RHUBC-II Home RHUBC Home ARM Field Campaigns Home ARM Data Discovery Browse Data Deployment Instruments Science Team RHUBC-II Wiki Site Tour News RHUBC-II Backgrounder (PDF, 300K) News & Press Images Experiment Planning RHUBC-II Proposal Abstract Science Plan (PDF, 267KB) Science Objectives Contacts Eli Mlawer, Principal Investigator Dave Turner, Principal Investigator RHUBC II Instruments RHUBC-II Instruments - Cerro Toco, Chile Guest Instruments Instrument

  18. Synthesis and Structural Features of [4,4'-Diisopropoxyester-2,2'-bipyridine], [Dichloro(4,4'-diisopropoxyester-2,2'-bi-pyridine)-platinum(ii)] and Its Dichloromethane Solvated Pseudo-Polymorph: Versatile Supramolecular Interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Browning, Charles; Nesterov, Vladimir N.; Wang, Xiaoping; Omary, Mohammad A.

    2015-06-03

    We report that the organic ligand 4,4'-diisopropoxyester-2,2'-bipyridine, C18H20N2O4 (1), crystallizes in the triclinic crystal system P-1 and the molecule occupies a special position in the unit cell. In the crystal, molecules form stacks with partial overlapping of the pyridine rings. The Pt(II) dichloro complex of 1 crystallizes from a mixture of ethanol/hexane and from dichloromethane to form orange and yellow crystals, respectively. The orange non-solvated crystals of the (bipyridine)(dichloro)platinum(II) complex C18H20N2O4PtCl2 (2) crystallize in the triclinic crystal system P-1 as well with two independent molecules in the unit cell. In the crystal packing, molecules form two types of dimers withmore » Pt1 ··· Pt1A and Pt2···Pt2A distances of 3.478 and 5.186 angstrom respectively. The yellow crystals, as a solvated pseudo-polymorph C18H20N2O4PtCl2·1.5 CH2Cl2 (3) also crystallize in the triclinic crystal system P-1 with two independent molecules in the unit cell. In the crystal packing, molecules form Pt2 ···Pt1 ···Pt1A ···Pt2A intermolecular contacts with alternating distances 3.501 and 3.431 angstrom, respectively, forming infinite chains. Graphical Abstract The dichloro(bipyridine)platinum complex, dichloro(4,4'-diisopropoxyester-2,2'-bipyridine)platinum(II), forms single crystals as a stable non-solvated form and a solvated polymorph with dramatically different supramolecular structure and short contacts.« less

  19. Development of improved processing and evaluation methods for high reliability structural ceramics for advanced heat engine applications Phase II. Final report

    SciTech Connect (OSTI)

    Pujari, V.J.; Tracey, D.M.; Foley, M.R.

    1996-02-01

    The research program had as goals the development and demonstration of significant improvements in processing methods, process controls, and nondestructive evaluation (NDE) which can be commercially implemented to produce high reliability silicon nitride components for advanced heat engine applications at temperatures to 1370{degrees}C. In Phase I of the program a process was developed that resulted in a silicon nitride - 4 w% yttria HIP`ed material (NCX 5102) that displayed unprecedented strength and reliability. An average tensile strength of 1 GPa and a strength distribution following a 3-parameter Weibull distribution were demonstrated by testing several hundred buttonhead tensile specimens. The Phase II program focused on the development of methodology for colloidal consolidation producing green microstructure which minimizes downstream process problems such as drying, shrinkage, cracking, and part distortion during densification. Furthermore, the program focused on the extension of the process to gas pressure sinterable (GPS) compositions. Excellent results were obtained for the HIP composition processed for minimal density gradients, both with respect to room-temperature strength and high-temperature creep resistance. Complex component fabricability of this material was demonstrated by producing engine-vane prototypes. Strength data for the GPS material (NCX-5400) suggest that it ranks very high relative to other silicon nitride materials in terms of tensile/flexure strength ratio, a measure of volume quality. This high quality was derived from the closed-loop colloidal process employed in the program.

  20. Biofoam II

    DOE Patents [OSTI]

    Morrison, Robert L.

    1994-01-01

    Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties.

  1. Biofoam II

    DOE Patents [OSTI]

    Morrison, R.L.

    1994-11-01

    Biofoam is a rigid, microcellular organic foam made from organic materials derived from natural products and biological organisms. Starting materials include agar, agarose, gelatin, algin, alginates, gellan gum, and microcrystalline cellulose. The organic material is dissolved in a polar solvent, typically water, and the mixture is gelled. The water in the gel pores is replaced at least once with another solvent to reduce the pore size of the final biofoam. The solvent in the gel pores may be replaced several times. After the final replacement of solvent, the gel is frozen and freeze-dried to form a biofoam. Translucent biofoams are formed by selecting a final solvent that forms very small crystals. A variety of crystalline, fibrous, amorphous, or metallic additives may be incorporated into the foam structure to produce lightweight composite materials with enhanced strength and insulating properties. 1 fig.

  2. THE ZURICH ENVIRONMENTAL STUDY (ZENS) OF GALAXIES IN GROUPS ALONG THE COSMIC WEB. II. GALAXY STRUCTURAL MEASUREMENTS AND THE CONCENTRATION OF MORPHOLOGICALLY CLASSIFIED SATELLITES IN DIVERSE ENVIRONMENTS

    SciTech Connect (OSTI)

    Cibinel, A.; Carollo, C. M.; Lilly, S. J.; Miniati, F.; Cameron, E.; Peng, Y.; Pipino, A.; Rudick, C. S.; Silverman, J. D.; Van Gorkom, J. H.; Finoguenov, A.; Norberg, P. E-mail: marcella@phys.ethz.ch

    2013-10-20

    We present structural measurements for the galaxies in the 0.05 < z < 0.0585 groups of the Zurich Environmental Study, aimed at establishing how galaxy properties depend on four environmental parameters: group halo mass (M{sub GROUP}), group-centric distance (R/R{sub 200}), ranking into central or satellite, and large-scale structure density (?{sub LSS}). Global galaxy structure is quantified both parametrically and non-parametrically. We correct all these measurements for observational biases due to point-spread function blurring and surface brightness effects as a function of galaxy size, magnitude, steepness of light profile, and ellipticity. Structural parameters are derived also for bulges, disks, and bars. We use the galaxy bulge-to-total ratios (B/T) together with the calibrated non-parametric structural estimators to implement a quantitative morphological classification that maximizes purity in the resulting morphological samples. We investigate how the concentration C of satellite galaxies depends on galaxy mass for each Hubble type and on M{sub GROUP}, R/R{sub 200}, and ?{sub LSS}. At galaxy masses M ? 10{sup 10} M{sub ?}, the concentration of disk satellites increases with increasing stellar mass separately within each morphological bin of B/T. The known increase in concentration with stellar mass for disk satellites is thus due, at least in part, to an increase in galaxy central stellar density at constant B/T. The correlation between concentration and galaxy stellar mass becomes progressively steeper for later morphological types. The concentration of disk satellites shows a barely significant dependence on ?{sub LSS} or R/R{sub 200}. The strongest environmental effect is found with group mass for >10{sup 10} M{sub ?} disk-dominated satellites, which are ?10% more concentrated in high mass groups than in lower mass groups.

  3. Spectroscopic study on deuterated benzenes. II. High-resolution laser spectroscopy and rotational structure in the S{sub 1} state

    SciTech Connect (OSTI)

    Kunishige, Sachi; Katori, Toshiharu; Baba, Masaaki; Hayashi, Masato; Hasegawa, Hirokazu; Ohshima, Yasuhiro

    2015-12-28

    High-resolution spectra of the S{sub 1}←S{sub 0} transition in jet-cooled deuterated benzenes were observed using pulse dye amplification of single-mode laser light and mass-selective resonance enhanced multiphoton ionization (REMPI) detection. The vibrational and rotational structures were accurately analyzed for the vibronic levels in the S{sub 1} state. The degenerate 6{sup 1} levels of C{sub 6}H{sub 6} or C{sub 6}D{sub 6} are split into 6a{sup 1} and 6b{sup 1} in many of deuterated benzenes. The rigid-rotor rotational constants were assessed and found to be slightly different between 6a and 6b because of different mean molecular structures. Their rotational levels are significantly shifted by Coriolis interactions. It was found that the Coriolis parameter proportionally changed with the number of substituted D atoms.

  4. Synergetic effects of II-VI sensitization upon TiO{sub 2} for photoelectrochemical water splitting; a tri-layered structured scheme

    SciTech Connect (OSTI)

    Mumtaz, Asad; Mohamed, Norani Muti

    2014-10-24

    World's energy demands are growing on a higher scale increasing the need of more reliable and long term renewable energy resources. Efficient photo-electrochemical (PEC) devices based on novel nano-structured designs for solar-hydrogen generation need to be developed. This study provides an insight of the tri-layered-TiO2 based nanostructures. Observing the mechanism of hydrogen production, the comparison of the structural order during the synthesis is pronounced. The sequence in the tri-layered structure affects the photogenerated electron (e{sup −}) and hole (h{sup +}) pair transfer and separation. It is also discussed that not only the semiconductors band gaps alignment is important with respect to the water redox potential but also the interfacial regions. Quasi-Fermi-level adjustment at the interfacial regions plays a key role in deciding the solar to hydrogen efficiency. More efficient multicomponent semiconductor nano-design (MCSN) could be developed with the approach given in this study.

  5. Finding of No Significant Impact

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. Department of Energy Finding of No Significant Impact 2 June 2001 This page intentionally left blank. U.S. Department of Energy Finding of No Significant Impact 12 June 2001 This page intentionally left blank.

  6. ARM - Research Highlights: Notable Findings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HighlightsNotable Research Findings Form Submit a New Research Highlight Sort Highlights Submitter Title Research Area Working Group Submission Date DOE Progress Reports Notable Research Findings for 2001-2006 Office of Science Abstracts Database Research Highlights Summaries Notable Research Findings for the Past Five Years Aerosols Cloud Parameterization and Modeling (Currently Cloud Modeling) Cloud Properties Instantaneous Radiative Flux (Currently Radiative Processes)

  7. Final Report: Design & Evaluation of Energy Efficient Modular Classroom Structures Phase II / Volume I-VII, January 17, 1995 - October 30, 1999

    SciTech Connect (OSTI)

    1999-10-30

    We are developing innovations to enable modular builders to improve the energy performance of their classrooms with no increase in first cost. The Modern Building Systems' (MBS) classroom building conforms to the stringent Oregon energy code, and at $18/ft{sup 2} ($1.67/m{sup 2}) (FOB the factory) it is at the low end of the cost range for modular classrooms. We have investigated daylighting, cross-ventilation, solar preheat of ventilation air, air-to-air heat exchanger, electric lighting controls, and down-sizing HVAC systems as strategies to improve energy performance. We were able to improve energy performance with no increase in first cost in all climates examined. Two papers and a full report on Phase I of this study are available. The work described in this report is from the second phase of the project. In the first phase we redesigned the basic modular classroom to incorporate energy strategies including daylighting, cross-ventilation, solar preheating of ventilation air, and insulation. We also explored thermal mass but determined that it was not a cost-effective strategy in the five climates we examined. Energy savings ranged from 6% to 49% with an average of 23%. Paybacks ranged from 1.3 years to 23.8 years, an average of 12.1 years. In Phase II the number of baseline buildings was expanded by simulating buildings that would be typical of those produced by Modern Building Systems, Inc. (MBS) for each of the seven locations/climates. A number of parametric simulations were performed for each energy strategy. Additionally we refined our previous algorithm for a solar ventilation air wall preheater and developed an algorithm for a roof preheater configuration. These algorithms were coded as functions in DOE 2.1E. We were striving for occupant comfort as well as energy savings. We performed computer analyses to verify adequate illumination on vertical surfaces and acceptable glare levels when using daylighting. We also used computational fluid dynamics

  8. Neutron and X-ray structural characterization of the hexaaquavanadium(II) compound VSO{sub 4}{center_dot}7H{sub 2}O

    SciTech Connect (OSTI)

    Cotton, F.A.; Falvello, L.R.; Pascual, I.; Tomas, M.; Murillo, C.A. |; Schultz, A.J.

    1994-11-23

    The title compound, for which crystals are more reactive toward oxygen than the chemically similar compound VSO{sub 4}{center_dot}6H{sub 2}O, has been prepared as large single crystals and characterized by both X-ray diffraction at room temperature and neutron diffraction at 11-16 K. VSO{sub 4}{center_dot}7H{sub 2}O crystallizes in the monoclinic space group P2{sub 1}/c, Z = 4, with the following cell dimensions, where in each case the room temperature X-ray value is given first followed by the 11-16 K neutron value: a = 14.130(3), 14.013(2) {angstrom}; b = 6.501(1), 6.481(1) {angstrom}; c = 11.017(2), 10.981(2) {angstrom}; {beta} = 105.64(2), 105.39(1){degrees}; V = 974.5(3), 961.5(3) {angstrom}{sup 3}. The structure was refined to residuals of R = 0.0289 and 0.0766 and quality of fit = 1.047 and 1.427 for X-ray and neutron data, respectively. It consists of two independent centrosymmetric V(H{sub 2}O){sub 6}{sup 2+} ions connected to a sulfate ion and an interstitial water molecule by an extensive network of hydrogen bonds. The room temperature and low-temperature structures are qualitatively identical. Each hydrogen atom is involved in a hydrogen bond. The network of hydrogen bonds is implicated in the stability of VSO{sub 4}{center_dot}7H{sub 2}O in the solid state in dry surroundings.

  9. Find R&D Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find technical reports, journal articles, accepted manuscripts, conference papers, patents, theses, books, multimedia, and data information. Use the basic or advanced search to get ...

  10. Aegir II | Open Energy Information

    Open Energy Info (EERE)

    Aegir II Jump to: navigation, search Name Aegir II Facility Aegir II Sector Wind energy Facility Type Offshore Wind Facility Status Proposed Location Lake Michigan MI Coordinates...

  11. Penascal II | Open Energy Information

    Open Energy Info (EERE)

    Penascal II Jump to: navigation, search Name Penascal II Facility Penascal II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Developer Iberdrola...

  12. Glacier II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Glacier II Facility Glacier II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NaturEner Developer...

  13. Wilton Wind Energy Center II II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Wilton Wind Energy Center II II Facility Wilton Wind Energy Center II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  14. Find a Job | Careers | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find a Job We're looking for scientists, research technicians, engineers, analysts, managers and project leaders, administrators, and communicators, along with information technology, security, facilities, and clerical/administrative support specialists. Interested in joining our team? Find your opportunity We're passionate about our mission-to develop clean energy and energy efficiency technologies and practices, advance related science and engineering, and provide knowledge and innovations to

  15. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ......II-1 S. ...

  16. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at ALS Beamline 8.2.2. Treating Obesity with Satiety Cholecystokinin (CCK) is a hormone in the brain and gastrointestinal system that helps stimulate the digestion of fat...

  17. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of California, Berkeley, and the Max Planck Institute of Biochemistry combined ... J. Peters, and W. Baumeister (Max Planck Institute of Biochemistry); P.J. Walian ...

  18. Giant Protease TPP II's Structure, Mechanism Uncovered

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The protein "skeleton" of this giant protease is depicted in magenta ribbon. The grey enclosure represents a lower-resolution surface and is included to aid visualization of...

  19. Peak finding using biorthogonal wavelets

    SciTech Connect (OSTI)

    Tan, C.Y.

    2000-02-01

    The authors show in this paper how they can find the peaks in the input data if the underlying signal is a sum of Lorentzians. In order to project the data into a space of Lorentzian like functions, they show explicitly the construction of scaling functions which look like Lorentzians. From this construction, they can calculate the biorthogonal filter coefficients for both the analysis and synthesis functions. They then compare their biorthogonal wavelets to the FBI (Federal Bureau of Investigations) wavelets when used for peak finding in noisy data. They will show that in this instance, their filters perform much better than the FBI wavelets.

  20. Nanocrystal structures

    DOE Patents [OSTI]

    Eisler, Hans J.; Sundar, Vikram C.; Walsh, Michael E.; Klimov, Victor I.; Bawendi, Moungi G.; Smith, Henry I.

    2008-12-30

    A structure including a grating and a semiconductor nanocrystal layer on the grating, can be a laser. The semiconductor nanocrystal layer can include a plurality of semiconductor nanocrystals including a Group II-VI compound, the nanocrystals being distributed in a metal oxide matrix. The grating can have a periodicity from 200 nm to 500 nm.

  1. Nanocrystal structures

    DOE Patents [OSTI]

    Eisler, Hans J.; Sundar, Vikram C.; Walsh, Michael E.; Klimov, Victor I.; Bawendi, Moungi G.; Smith, Henry I.

    2006-12-19

    A structure including a grating and a semiconductor nanocrystal layer on the grating, can be a laser. The semiconductor nanocrystal layer can include a plurality of semiconductor nanocrystals including a Group IIVI compound, the nanocrystals being distributed in a metal oxide matrix. The grating can have a periodicity from 200 nm to 500 nm.

  2. EA-1828: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Carbon Dioxide Capture from Biofuels Production and Sequestration into the Mount Simon Sandstone Phase II Project in Decatur, Illinois

  3. Find Internships | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Internships Find Internships Internships in energy efficiency and renewable energy-related fields, such as solar and fuel cells, energy efficiency, atmospheric sciences, ecology, global carbon cycles, climatology, and more, include EERE's own student internship program. Featured Internships Clean Cities University Workforce Development Program Clean Cities logo Science Undergraduate Laboratory Internships (SULI) Fall 2013 Picture of tow people in a labratory working Minority Educational

  4. Writing audit findings: Be reasonable!

    SciTech Connect (OSTI)

    Girvin, N.W.

    1992-05-01

    A customary approach to auditing and reporting deficiencies is to keep a running list of those that are found, evaluate the severity of each, and based on the evidence, document findings or observations or concerns in an audit report. The report is issued and the auditee is normally requested to address ``root cause`` as part of their corrective action. This paper describes a ``root problems`` approach to documenting audit findings that is designed not only to put the QA auditor in a more favorable light, but to more effectively enable the auditee to identify root cause and meaningful corrective action. The positive results of this approach are considerable. You will have fewer findings but those you do have will be substantial. You will cite requirements that sound reasonable and make arguments difficult. If some of the supporting deficiencies (examples) prove to be incorrect, you will still have ample support for the original finding. You will be seen as reasonable individual who can help lead the auditee towards identification of root cause without taking away part of the responsibility. You even have a fair chance of fostering a sense of commitment to quality improvement on the auditee`s part. This in itself, is its own reward.

  5. Writing audit findings: Be reasonable

    SciTech Connect (OSTI)

    Girvin, N.W.

    1992-05-01

    A customary approach to auditing and reporting deficiencies is to keep a running list of those that are found, evaluate the severity of each, and based on the evidence, document findings or observations or concerns in an audit report. The report is issued and the auditee is normally requested to address root cause'' as part of their corrective action. This paper describes a root problems'' approach to documenting audit findings that is designed not only to put the QA auditor in a more favorable light, but to more effectively enable the auditee to identify root cause and meaningful corrective action. The positive results of this approach are considerable. You will have fewer findings but those you do have will be substantial. You will cite requirements that sound reasonable and make arguments difficult. If some of the supporting deficiencies (examples) prove to be incorrect, you will still have ample support for the original finding. You will be seen as reasonable individual who can help lead the auditee towards identification of root cause without taking away part of the responsibility. You even have a fair chance of fostering a sense of commitment to quality improvement on the auditee's part. This in itself, is its own reward.

  6. ACRA-II

    Energy Science and Technology Software Center (OSTI)

    003089IBMPC00 ACRA-II: Kernel Integration Code System for Estimation of Radiation Doses Caused by a Hypothetical Reactor Accident

  7. Cori Phase II Preparations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Announcements » Cori Phase II Preparations Cori Phase II Preparations May 9, 2016 by Rebecca Hartman-Baker We expect the first cabinets of Cori Phase II to arrive in CRT/Wang Hall on the LBL campus in July. NERSC personnel will immediately get to work on bringing the machine into production. Before the machine can be released to the NERSC user community, a number of tasks must be completed, some of which will have a direct impact on NERSC users. We've created the Cori Phase II Schedule page to

  8. Project Final Report: HPC-Colony II

    SciTech Connect (OSTI)

    Jones, Terry R; Kale, Laxmikant V; Moreira, Jose

    2013-11-01

    This report recounts the HPC Colony II Project which was a computer science effort funded by DOE's Advanced Scientific Computing Research office. The project included researchers from ORNL, IBM, and the University of Illinois at Urbana-Champaign. The topic of the effort was adaptive system software for extreme scale parallel machines. A description of findings is included.

  9. Phase II Accident Investigation Board Briefing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase II Accident Investigation Board Briefing Phase II Accident Investigation Board Briefing Topic: Ted Wyka DOE, Provided a Brief on the Findings in the WIPP Accident Investigation. Information Provided included the Judgments of NEED and Causes That Contributed to the Incident. AIB Brief - May 20, 2015 (1.98

  10. Find Jobs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Jobs Find Jobs Clean energy jobs can be found in the public, private, and nonprofit sectors and can range from entry-level to professional positions in a wide range of fields. This section can help you familiarize yourself with different types of green energy jobs as you begin your search for a job that meets your interests and skills. EERE Career Opportunities EERE Career Opportunities Energy Efficency and Renewable Energy, the DOE office leading the nation's effort to enhance energy efficiency

  11. FINDING OF NO SIGNIFICANT IMPACT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    COMMERCIAL DEMONSTRATION OF THE MANUFACTURED AGGREGATE PROCESSING TECHNOLOGY UTILIZING SPRAY DRYER ASH 1 AGENCY: U.S. Department of Energy (DOE) ACTION: Finding of No Significant Impact (FONSI) SUMMARY: The DOE has prepared an Environmental Assessment (EA), DOE/EA-1449, to analyze the potential environmental consequences of participating in a cooperative agreement with Universal Aggregates, LLC, for the design, construction, and operation of a plant to manufacture lightweight aggregates. The

  12. Algorithm for Finding Similar Shapes in Large Molecular Structures Libraries

    Energy Science and Technology Software Center (OSTI)

    1994-10-19

    The SHAPES software consists of methods and algorithms for representing and rapidly comparing molecular shapes. Molecular shapes algorithms are a class of algorithm derived and applied for recognizing when two three-dimensional shapes share common features. They proceed from the notion that the shapes to be compared are regions in three-dimensional space. The algorithms allow recognition of when localized subregions from two or more different shapes could never be superimposed by any rigid-body motion. Rigid-body motionsmore » are arbitrary combinations of translations and rotations.« less

  13. Eu{sub 3}F{sub 4}S{sub 2}: Synthesis, crystal structure, and magnetic properties of the mixed-valent europium(II,III) fluoride sulfide EuF{sub 2}.(EuFS){sub 2}

    SciTech Connect (OSTI)

    Grossholz, Hagen; Hartenbach, Ingo; Kotzyba, Gunter; Poettgen, Rainer; Trill, Henning; Mosel, Bernd D.; Schleid, Thomas

    2009-11-15

    Using the method to synthesize rare-earth metal(III) fluoride sulfides MFS (M=Y, La, Ce-Lu), in some cases we were able to obtain mixed-valent compounds such as Yb{sub 3}F{sub 4}S{sub 2} instead. With Eu{sub 3}F{sub 4}S{sub 2} another isotypic representative has now been synthesized. Eu{sub 3}F{sub 4}S{sub 2} (tetragonal, I4/mmm, a=400.34(2), c=1928.17(9) pm, Z=2) is obtained from the reaction of metallic europium, elemental sulfur, and europium trifluoride in a molar ratio of 5:6:4 within seven days at 850 deg. C in silica-jacketed gas-tightly sealed platinum ampoules. The single-phase product consists of black plate-shaped single crystals with a square cross section, which can be obtained from a flux using equimolar amounts of NaCl as fluxing agent. The crystal structure is best described as an intergrowth structure, in which one layer of CaF{sub 2}-type EuF{sub 2} is followed by two layers of PbFCl-type EuFS when sheeted parallel to the (001) plane. Accordingly there are two chemically and crystallographically different europium cations present. One of them (Eu{sup 2+}) is coordinated by eight fluoride anions in a cubic fashion, the other one (Eu{sup 3+}) exhibits a monocapped square antiprismatic coordination sphere with four F{sup -} and five S{sup 2-} anions. Although the structural ordering of the different charged europium cations is plausible, a certain amount of charge delocalization with some polaron activity has to take place, which is suggested by the black color of the title compound. Temperature dependent magnetic susceptibility measurements of Eu{sub 3}F{sub 4}S{sub 2} show Curie-Weiss behavior with an experimental magnetic moment of 8.19(5) mu{sub B} per formula unit and a paramagnetic Curie temperature of 0.3(2) K. No magnetic ordering is observed down to 4.2 K. In accordance with an ionic formula splitting like (Eu{sup II})(Eu{sup III}){sub 2}F{sub 4}S{sub 2} only one third of the europium centers in Eu{sub 3}F{sub 4}S{sub 2} carry permanent

  14. Topo II: An Enzyme Target for Antibacterial and Cancer Drugs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topo II: An Enzyme Target for Antibacterial and Cancer Drugs Print The veil has finally been lifted on an enzyme that is critical to the process of DNA transcription and replication and is a prime target of antibacterial and anticancer drugs. Researchers at Berkeley Lab and the University of California, Berkeley, have produced the first three-dimensional structural images of a DNA-bound type II topoisomerase (topo II) that is responsible for untangling coiled strands of the chromosome during

  15. Topo II: An Enzyme Target for Antibacterial and Cancer Drugs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topo II: An Enzyme Target for Antibacterial and Cancer Drugs Print The veil has finally been lifted on an enzyme that is critical to the process of DNA transcription and replication and is a prime target of antibacterial and anticancer drugs. Researchers at Berkeley Lab and the University of California, Berkeley, have produced the first three-dimensional structural images of a DNA-bound type II topoisomerase (topo II) that is responsible for untangling coiled strands of the chromosome during

  16. Topo II: An Enzyme Target for Antibacterial and Cancer Drugs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topo II: An Enzyme Target for Antibacterial and Cancer Drugs Print The veil has finally been lifted on an enzyme that is critical to the process of DNA transcription and replication and is a prime target of antibacterial and anticancer drugs. Researchers at Berkeley Lab and the University of California, Berkeley, have produced the first three-dimensional structural images of a DNA-bound type II topoisomerase (topo II) that is responsible for untangling coiled strands of the chromosome during

  17. Topo II: An Enzyme Target for Antibacterial and Cancer Drugs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topo II: An Enzyme Target for Antibacterial and Cancer Drugs Print The veil has finally been lifted on an enzyme that is critical to the process of DNA transcription and replication and is a prime target of antibacterial and anticancer drugs. Researchers at Berkeley Lab and the University of California, Berkeley, have produced the first three-dimensional structural images of a DNA-bound type II topoisomerase (topo II) that is responsible for untangling coiled strands of the chromosome during

  18. Limon II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Limon II Facility Limon II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NextEra Energy Resources...

  19. Preliminary PBFA II design

    SciTech Connect (OSTI)

    Johnson, D. L.; VanDevender, J. P.; Martin, T. H.

    1980-01-01

    The upgrade of Sandia National Laboratories particle beam fusion accelerator, PBFA I, to PBFA II presents several interesting and challenging pulsed power design problems. PBFA II requires increasing the PBFA I output parameters from 2 MV, 30 TW, 1 MJ to 4 MV, 100 TW, 3.5 MJ with the constraint of using much of the same PBFA I hardware. The increased PBFA II output will be obtained by doubling the number of modules (from 36 to 72), increasing the primary energy storage (from 4 MJ to 15 MJ), lowering the pulse forming line (PFL) output impedance, and adding a voltage doubling network.

  20. Luz II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name: Luz II Place: Jerusalem, Israel Zip: 91450 Sector: Solar Product: Jerusalem-based utility-scale solar power plant developer. Coordinates:...

  1. _Part II - Contract Clauses

    National Nuclear Security Administration (NNSA)

    M0572 dated 3215 Contract DE-AC04-94AL85000 Modification No. M202 Page I - 1 Part II - Contract Clauses Section I TABLE OF CONTENTS 1. FAR 52.202-1 DEFINITIONS (JAN 2012)...

  2. PARS II Training Materials

    Broader source: Energy.gov [DOE]

    PARS II presentation hand-outs and step-by-step "how to" exercises for each course are available for download. Users who are attending Web classes should download these documents prior to attending...

  3. Network II Database

    Energy Science and Technology Software Center (OSTI)

    1994-11-07

    The Oak Ridge National Laboratory (ORNL) Rail and Barge Network II Database is a representation of the rail and barge system of the United States. The network is derived from the Federal Rail Administration (FRA) rail database.

  4. A Study of Resonant Excitation of Longitudinal HOMs in the Cryomodules of LCLS-II

    SciTech Connect (OSTI)

    Bane, Karl

    2015-09-23

    The Linac Coherent Light Source (LCLS) at SLAC, the world’s first hard X-ray FEL, is being upgraded to the LCLS-II. The major new feature will be the installation of 35 cryomodules (CMs) of TESLA-type, superconducting accelerating structures, to allow for high rep-rate operation. It is envisioned that eventually the LCLS-II will be able to deliver 300 pC, 1 kA pulses of beam at a rate of 1 MHz. At a cavity temperature of 2 K, any heat generated (even on the level of a few watts) is expensive to remove. In the last linac of LCLS-II, L3—where the peak current is highest—the power radiated by the bunches in the CMs is estimated at 13.8 W (charge 300 pC option, rep rate 1 MHz). But this calculation ignores resonances that can be excited between the bunch frequency and higher order mode (HOM) frequencies in the CMs, which in principle can greatly increase this number. In the present work we calculate the multi-bunch wakefields excited in a CM of LCLS-II, in order to estimate the probability of the beam losing a given amount of power. Along theway, we find some interesting properties of the resonant interaction. In detail, we begin this report by finding the wakes experienced by bunches far back in the bunch train. Then we present a complementary approach that calculates the field amplitude excited in steady-state by a train of bunches, and show that the two approaches agree. Next we obtain the properties of the 450 longitudinal HOMs that cover the range 3–5 GHz in the CMs of LCLS-II, where we include the effects of the inter-CM ceramic dampers. At the end we apply our method using these modes.

  5. Regional Transmission Projects: Finding Solutions

    SciTech Connect (OSTI)

    The Keystone Center

    2005-06-15

    The Keystone Center convened and facilitated a year-long Dialogue on "Regional Transmission Projects: Finding Solutions" to develop recommendations that will help address the difficult and contentious issues related to expansions of regional electric transmission systems that are needed for reliable and economic transmission of power within and across regions. This effort brought together a cross-section of affected stakeholders and thought leaders to address the problem with the collective wisdom of their experience and interests. Transmission owners sat at the table with consumer advocates and environmental organizations. Representatives from regional transmission organizations exchanged ideas with state and federal regulators. Generation developers explored common interests with public power suppliers. Together, the Dialogue participants developed consensus solutions about how to begin unraveling some of the more intractable issues surrounding identification of need, allocation of costs, and reaching consensus on siting issues that can frustrate the development of regional transmission infrastructure. The recommendations fall into three broad categories: 1. Recommendations on appropriate institutional arrangements and processes for achieving regional consensus on the need for new or expanded transmission infrastructure 2. Recommendations on the process for siting of transmission lines 3. Recommendations on the tools needed to support regional planning, cost allocation, and siting efforts. List of Dialogue participants: List of Dialogue Participants: American Electric Power American Transmission Company American Wind Energy Association California ISO Calpine Corporation Cinergy Edison Electric Institute Environmental Defense Federal Energy Regulatory Commission Great River Energy International Transmission Company ISO-New England Iowa Public Utility Board Kanner & Associates Midwest ISO National Association of Regulatory Utility Commissioners National Association

  6. ARM - RHUBC II Science Objectives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Objectives Related Links RHUBC-II Home RHUBC Home ARM Field Campaigns Home ARM Data Discovery Browse Data Deployment Instruments Science Team RHUBC-II Wiki Site Tour News RHUBC-II Backgrounder (PDF, 300K) News & Press Images Experiment Planning RHUBC-II Proposal Abstract Science Plan (PDF, 267KB) Science Objectives Contacts Eli Mlawer, Principal Investigator Dave Turner, Principal Investigator RHUBC II Science Objectives To conduct clear-sky radiative closure studies in order to reduce the

  7. ARM - RHUBC II Science Team

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Team Related Links RHUBC-II Home RHUBC Home ARM Field Campaigns Home ARM Data Discovery Browse Data Deployment Instruments Science Team RHUBC-II Wiki Site Tour News RHUBC-II Backgrounder (PDF, 300K) News & Press Images Experiment Planning RHUBC-II Proposal Abstract Science Plan (PDF, 267KB) Science Objectives Contacts Eli Mlawer, Principal Investigator Dave Turner, Principal Investigator RHUBC II Science Team Principal Investigators Eli Mlawer, Atmospheric & Environmental Research, Inc.

  8. About APPLE II Operation

    SciTech Connect (OSTI)

    Schmidt, T.; Zimoch, D.

    2007-01-19

    The operation of an APPLE II based undulator beamline with all its polarization states (linear horizontal and vertical, circular and elliptical, and continous variation of the linear vector) requires an effective description allowing an automated calculation of gap and shift parameter as function of energy and operation mode. The extension of the linear polarization range from 0 to 180 deg. requires 4 shiftable magnet arrrays, permitting use of the APU (adjustable phase undulator) concept. Studies for a pure fixed gap APPLE II for the SLS revealed surprising symmetries between circular and linear polarization modes allowing for simplified operation. A semi-analytical model covering all types of APPLE II and its implementation will be presented.

  9. Finding Hidden Oil and Gas Reserves

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Finding Hidden Oil and Gas Reserves Finding Hidden Oil and Gas Reserves Key Challenges: Seismic imaging methods, vital in our continuing search for deep offshore oil and gas...

  10. Canfield's Couplet Clues for Finding Superconductors

    ScienceCinema (OSTI)

    Canfield, Paul

    2015-06-30

    Ames Laboratory scientist, Paul Canfield, summarizes his thoughts about finding new superconducting materials.

  11. Canfield's Couplet Clues for Finding Superconductors

    SciTech Connect (OSTI)

    Canfield, Paul

    2015-04-28

    Ames Laboratory scientist, Paul Canfield, summarizes his thoughts about finding new superconducting materials.

  12. Bore II - Advanced Wellbore Technology Characterizes Groundwater Flow and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contamination - Energy Innovation Portal Geothermal Geothermal Energy Analysis Energy Analysis Find More Like This Return to Search Bore II - Advanced Wellbore Technology Characterizes Groundwater Flow and Contamination Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryBore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and

  13. Finding nonoverlapping substructures of a sparse matrix

    SciTech Connect (OSTI)

    Pinar, Ali; Vassilevska, Virginia

    2004-08-09

    Many applications of scientific computing rely on computations on sparse matrices, thus the design of efficient implementations of sparse matrix kernels is crucial for the overall efficiency of these applications. Due to the high compute-to-memory ratio and irregular memory access patterns, the performance of sparse matrix kernels is often far away from the peak performance on a modern processor. Alternative data structures have been proposed, which split the original matrix A into A{sub d} and A{sub s}, so that A{sub d} contains all dense blocks of a specified size in the matrix, and A{sub s} contains the remaining entries. This enables the use of dense matrix kernels on the entries of A{sub d} producing better memory performance. In this work, we study the problem of finding a maximum number of non overlapping rectangular dense blocks in a sparse matrix, which has not been studied in the sparse matrix community. We show that the maximum non overlapping dense blocks problem is NP-complete by using a reduction from the maximum independent set problem on cubic planar graphs. We also propose a 2/3-approximation algorithm for 2 times 2 blocks that runs in linear time in the number of nonzeros in the matrix. We discuss alternatives to rectangular blocks such as diagonal blocks and cross blocks and present complexity analysis and approximation algorithms.

  14. Finding Nonoverlapping Substructures of a Sparse Matrix

    SciTech Connect (OSTI)

    Pinar, Ali; Vassilevska, Virginia

    2005-08-11

    Many applications of scientific computing rely on computations on sparse matrices. The design of efficient implementations of sparse matrix kernels is crucial for the overall efficiency of these applications. Due to the high compute-to-memory ratio and irregular memory access patterns, the performance of sparse matrix kernels is often far away from the peak performance on a modern processor. Alternative data structures have been proposed, which split the original matrix A into A{sub d} and A{sub s}, so that A{sub d} contains all dense blocks of a specified size in the matrix, and A{sub s} contains the remaining entries. This enables the use of dense matrix kernels on the entries of A{sub d} producing better memory performance. In this work, we study the problem of finding a maximum number of nonoverlapping dense blocks in a sparse matrix, which is previously not studied in the sparse matrix community. We show that the maximum nonoverlapping dense blocks problem is NP-complete by using a reduction from the maximum independent set problem on cubic planar graphs. We also propose a 2/3-approximation algorithm that runs in linear time in the number of nonzeros in the matrix. This extended abstract focuses on our results for 2x2 dense blocks. However we show that our results can be generalized to arbitrary sized dense blocks, and many other oriented substructures, which can be exploited to improve the memory performance of sparse matrix operations.

  15. Ribosomal Database Project II

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Ribosomal Database Project (RDP) provides ribosome related data and services to the scientific community, including online data analysis and aligned and annotated Bacterial small-subunit 16S rRNA sequences. As of March 2008, RDP Release 10 is available and currently (August 2009) contains 1,074,075 aligned 16S rRNA sequences. Data that can be downloaded include zipped GenBank and FASTA alignment files, a histogram (in Excel) of the number of RDP sequences spanning each base position, data in the Functional Gene Pipeline Repository, and various user submitted data. The RDP-II website also provides numerous analysis tools.[From the RDP-II home page at http://rdp.cme.msu.edu/index.jsp

  16. _Part II - Contract Clauses

    National Nuclear Security Administration (NNSA)

    09/30/2015 to Mod 0588 Contract DE-AC04-94AL85000 Modification No. M202 Page I - 1 Part II - Contract Clauses Section I TABLE OF CONTENTS 1. FAR 52.202-1 DEFINITIONS (JAN 2012) (REPLACED M473) ............................................................. 8 2. FAR 52.203-3 GRATUITIES (APR 1984) ................................................................................................. 8 3. FAR 52.203-5 COVENANT AGAINST CONTINGENT FEES (APR 1984) ........................................... 9

  17. MS, II-J

    Office of Legacy Management (LM)

    I' ; ,' Departm&th of Energy 1 MS, II-J Washington. DC 20585 ' . I I The Honorable John Gallagher ,)fl', /',' ' 103 E. Michigan Avenue .i., ,.' Battle Creek, Michigan 49016 _. Dear Mayor Gallagheri d,---, " '/ approachto openness i.n: with the: public. In (FUSRAP)i.is responsible agencies, determining ~author~ity, performing remedial action to cleanup sites to meet current radiological protection requirements.. A conservative set of technical evaluation guidelines is used in these

  18. Section II INT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6/14/11 Page 1 of 9 Printed copies of this document are uncontrolled. Retrieve latest version electronically. SANDIA CORPORATION SF 6432-IN (06/14/11) SECTION II GENERAL PROVISIONS FOR INTERNATIONAL COMMERCIAL TRANSACTIONS THE FOLLOWING CLAUSES APPLY TO THIS CONTRACT AS INDICATED UNLESS SPECIFICALLY DELETED, OR EXCEPT TO THE EXTENT THEY ARE SPECIFICALLY SUPPLEMENTED OR AMENDED IN WRITING IN THE SIGNATURE PAGE OR SECTION I OF THIS CONTRACT. IN01 ACCEPTANCE OF TERMS AND CONDITIONS This Contract

  19. Enclosure II June

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enclosure II June 10,2010 Hanford Radiological Health and Safety Document 1 Forward The Richland Operations Office and the Office of River Protection have established a supplemental set of contractual requirements and an expectation that the contractor organizations establish the mechanisms necessary to maintain site consistency, optimize site-wide radiological programs to provide an overall benefit to the government, and support DOE in the management oflong-term risks relative to radiological

  20. Ashtabula II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    II Wind Farm Jump to: navigation, search Name Ashtabula II Wind Farm Facility Ashtabula II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  1. Heber II Geothermal Facility | Open Energy Information

    Open Energy Info (EERE)

    Heber II Geothermal Facility Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Heber II Geothermal Facility General Information Name Heber II Geothermal Facility...

  2. Kibby Mountain II | Open Energy Information

    Open Energy Info (EERE)

    Kibby Mountain II Jump to: navigation, search Name Kibby Mountain II Facility Kibby Mountain II Sector Wind energy Facility Type Commercial Scale Wind Facility Status Under...

  3. Papalote Creek II | Open Energy Information

    Open Energy Info (EERE)

    Papalote Creek II Jump to: navigation, search Name Papalote Creek II Facility Papalote Creek II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  4. Marengo II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    II Wind Farm Jump to: navigation, search Name Marengo II Wind Farm Facility Marengo II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  5. Springview II Wind Project | Open Energy Information

    Open Energy Info (EERE)

    Springview II Wind Project Jump to: navigation, search Name Springview II Wind Project Facility Springview II Wind Project Sector Wind energy Facility Type Commercial Scale Wind...

  6. Meadow Lake II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Meadow Lake II Facility Meadow Lake II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Horizon Wind...

  7. Klondike II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Klondike II Wind Farm Jump to: navigation, search Name Klondike II Wind Farm Facility Klondike II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  8. Vansycle Ridge II | Open Energy Information

    Open Energy Info (EERE)

    Vansycle Ridge II Jump to: navigation, search Name Vansycle Ridge II Facility Vansycle Ridge II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  9. Carleton College II | Open Energy Information

    Open Energy Info (EERE)

    Carleton College II Jump to: navigation, search Name Carleton College II Facility Carleton College II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  10. Little Pringle II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Little Pringle II Facility Little Pringle II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner SWI Wind...

  11. Annex II Technical Specifications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mechanical - opto-mechanical design development and structural assessment for Diagnostics .........7 14 CAD DESIGN REQUIREMENTS (IF APPLICABLE) ...

  12. TE Connectivity Finds Answers in Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TE Connectivity Finds Answers in Tomography TE Connectivity Finds Answers in Tomography Print Thursday, 22 August 2013 10:50 TE Connectivity is a world leader in connectivity-the...

  13. Structures of Pseudomonas aeruginosa β-ketoacyl-(acyl-carrier-protein) synthase II (FabF) and a C164Q mutant provide templates for antibacterial drug discovery and identify a buried potassium ion and a ligand-binding site that is an artefact of the crystal form

    SciTech Connect (OSTI)

    Baum, Bernhard; Lecker, Laura S. M.; Zoltner, Martin; Jaenicke, Elmar; Schnell, Robert; Hunter, William N.; Brenk, Ruth

    2015-07-28

    Three crystal structures of recombinant P. aeruginosa FabF are reported: the apoenzyme, an active-site mutant and a complex with a fragment of a natural product inhibitor. The characterization provides reagents and new information to support antibacterial drug discovery. Bacterial infections remain a serious health concern, in particular causing life-threatening infections of hospitalized and immunocompromised patients. The situation is exacerbated by the rise in antibacterial drug resistance, and new treatments are urgently sought. In this endeavour, accurate structures of molecular targets can support early-stage drug discovery. Here, crystal structures, in three distinct forms, of recombinant Pseudomonas aeruginosa β-ketoacyl-(acyl-carrier-protein) synthase II (FabF) are presented. This enzyme, which is involved in fatty-acid biosynthesis, has been validated by genetic and chemical means as an antibiotic target in Gram-positive bacteria and represents a potential target in Gram-negative bacteria. The structures of apo FabF, of a C164Q mutant in which the binding site is altered to resemble the substrate-bound state and of a complex with 3-(benzoylamino)-2-hydroxybenzoic acid are reported. This compound mimics aspects of a known natural product inhibitor, platensimycin, and surprisingly was observed binding outside the active site, interacting with a symmetry-related molecule. An unusual feature is a completely buried potassium-binding site that was identified in all three structures. Comparisons suggest that this may represent a conserved structural feature of FabF relevant to fold stability. The new structures provide templates for structure-based ligand design and, together with the protocols and reagents, may underpin a target-based drug-discovery project for urgently needed antibacterials.

  14. Inert doublet model and LEP II limits

    SciTech Connect (OSTI)

    Lundstroem, Erik; Gustafsson, Michael; Edsjoe, Joakim

    2009-02-01

    The inert doublet model is a minimal extension of the standard model introducing an additional SU(2) doublet with new scalar particles that could be produced at accelerators. While there exists no LEP II analysis dedicated for these inert scalars, the absence of a signal within searches for supersymmetric neutralinos can be used to constrain the inert doublet model. This translation however requires some care because of the different properties of the inert scalars and the neutralinos. We investigate what restrictions an existing DELPHI Collaboration study of neutralino pair production can put on the inert scalars and discuss the result in connection with dark matter. We find that although an important part of the inert doublet model parameter space can be excluded by the LEP II data, the lightest inert particle still constitutes a valid dark matter candidate.

  15. EA-1523: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Modifications at the Strategic Petroleum Reserve's West Hackberry Raw Water Intake Structure Site, Calcasieu Parish, Louisiana

  16. Breezy Bucks II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Breezy Bucks II Facility Breezy Bucks II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Breezy Bucks II...

  17. Salty Dog II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Salty Dog II Facility Salty Dog II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Salty Dog II LLC...

  18. Impact of substrate temperature on the structural and optical properties of strain-balanced InAs/InAsSb type-II superlattices grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Liu, Shi; Li, Hua; Cellek, Oray O.; Ding, Ding; Lin, Zhi-Yuan; Steenbergen, Elizabeth H.; He, Zhao-Yu; Johnson, Shane R.; Zhang, Yong-Hang; Center for Photonics Innovation, Arizona State University, Tempe, Arizona 85287 ; Shen, Xiao-Meng; School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287 ; Fan, Jin; Smith, David J.; Department of Physics, Arizona State University, Tempe, Arizona 85287 ; Lu, Jing

    2013-02-18

    Molecular beam epitaxial growth of strain-balanced InAs/InAs{sub 1-x}Sb{sub x} type-II superlattices on GaSb substrates has been investigated for substrate temperatures from 400 Degree-Sign C to 450 Degree-Sign C. The Sb composition is found to vary linearly with substrate temperature at constant V/III ratios. For samples grown at the optimized substrate temperature (410 Degree-Sign C), superlattice zero-order peak full-width at half-maximums are routinely less than 25 arc sec using high-resolution X-ray diffraction. Cross-sectional transmission electron microscopy images show the absence of any visible defects. Strong photoluminescence covers a wavelength range from 5.5 to 13 {mu}m at 12 K. Photoluminescence linewidth simulations show satisfactory agreement with experiments.

  19. Cu(II) promotes amyloid pore formation

    SciTech Connect (OSTI)

    Zhang, Hangyu; Rochet, Jean-Christophe; Stanciu, Lia A.

    2015-08-14

    The aggregation of α-synuclein is associated with dopamine neuron death in Parkinson's disease. There is controversy in the field over the question of which species of the aggregates, fibrils or protofibrils, are toxic. Moreover, compelling evidence suggested the exposure to heavy metals to be a risk of PD. Nevertheless, the mechanism of metal ions in promoting PD remains unclear. In this research, we investigated the structural basis of Cu(II) induced aggregation of α-synuclein. Using transmission electron microscopy experiments, Cu(II) was found to promote in vitro aggregation of α-synuclein by facilitating annular protofibril formation rather than fibril formation. Furthermore, neuroprotective baicalein disaggregated annular protofibrils accompanied by considerable decrease of β-sheet content. These results strongly support the hypothesis that annular protofibrils are the toxic species, rather than fibrils, thereby inspiring us to search novel therapeutic strategies for the suppression of the toxic annular protofibril formation. - Highlights: • Cu(II) promoted the annular protofibril formation of α-synuclein in vitro. • Cu(II) postponed the in vitro fibrillization of α-synuclein. • Neuroprotective baicalein disaggregated annular protofibrils.

  20. THE SURVEY OF LINES IN M31 (SLIM): INVESTIGATING THE ORIGINS OF [C II] EMISSION

    SciTech Connect (OSTI)

    Kapala, M. J.; Sandstrom, K.; Groves, B.; Kreckel, K.; Schinnerer, E.; Walter, F.; Fouesneau, M. [Max Planck Institut fr Astronomie, Knigstuhl 17, D-69117 Heidelberg (Germany); Croxall, K. [Department of Astronomy, The Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Dalcanton, J. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Leroy, A., E-mail: kapala@mpia.de [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903 (United States)

    2015-01-01

    The [C II] 158 ?m line is one of the strongest emission lines observed in star-forming galaxies and has been empirically measured to correlate with the star-formation rate (SFR) globally and on kiloparsec scales. However, because of the multiphase origins of [C II], one might expect this relation to break down at small scales. We investigate the origins of [C II] emission by examining high spatial resolution observations of [C II] in M31 with the Survey of Lines in M31. We present five ?700 700 pc (3' 3') fields mapping the [C II] emission, H? emission, and the ancillary infrared (IR) data. We spatially separate star-forming regions from diffuse gas and dust emission on ?50 pc scales. We find that the [C II]-SFR correlation holds even at these scales, although the relation typically has a flatter slope than found at larger (kiloparsec) scales. While the H? emission in M31 is concentrated in the SFR regions, we find that a significant amount (?20%-90%) of the [C II] emission comes from outside star-forming regions and that the total IR emission (TIR) has the highest diffuse fraction of all SFR tracers. We find a weak correlation of the [C II]/TIR to dust color in each field and find a large-scale trend of increasing [C II]/TIR with galactocentric radius. The differences in the relative diffuse fractions of [C II], H?, and IR tracers are likely caused by a combination of energetic photon leakage from H II regions and heating by the diffuse radiation field arising from older (B-star) stellar populations. However, we find that by averaging our measurements over kiloparsec scales, these effects are minimized, and the relation between [C II] and SFR found in other nearby galaxy studies is retrieved.

  1. PART II - CONTRACT CLAUSES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I Contract No. DE-AC06-09RL14728 Modification 479 I-1 PART II - CONTRACT CLAUSES SECTION I CONTRACT CLAUSES I.1 FAR 52.252-2 CLAUSES INCORPORATED BY REFERENCE (FEB 1998) This Contract incorporates one or more clauses by reference, with the same force and effect as if they were given in full text. Upon request, the Contracting Officer will make their full text available. Also, the full text of a clause may be accessed electronically at these addresses: https://www.acquisition.gov/far/index.html

  2. PART II - CONTRACT CLAUSES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I Contract No. DE-AC27-08RV14800 Modification No. 330 I-1 PART II - CONTRACT CLAUSES SECTION I CONTRACT CLAUSES I.1 FAR 52.252-2 CLAUSES INCORPORATED BY REFERENCE (FEB 1998) This Contract incorporates one or more clauses by reference, with the same force and effect as if they were given in full text. Upon request, the Contracting Officer will make their full text available. Also, the full text of a clause may be accessed electronically at these addresses: http://www.arnet.gov/far/

  3. Section II INT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (11-03-2010) Title: Standard Terms & Conditions for International Commercial Transactions Owner: Procurement Policy & Quality Dept Initial Release Date: 11/3/10 Page 1 of 8 PPQD-TMPLT-008R01 Template Release Date: 12/01/09 Printed copies of this document are uncontrolled. Before using a printed copy to perform work, verify the version against the electronic document to ensure you are using the correct version. SANDIA CORPORATION SF 6432-IN (11-03-2010) SECTION II GENERAL PROVISIONS FOR

  4. Section II INT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IN (01-12-2010) Title: Standard Terms & Conditions for International Commercial Transactions Owner: Procurement Policy & Quality Dept Initial Release Date: 01/12/10 Page 1 of 6 PPQD-TMPLT-008R01 Template Release Date: 12/01/09 Printed copies of this document are uncontrolled. Before using a printed copy to perform work, verify the version against the electronic document to ensure you are using the correct version. SANDIA CORPORATION SF 6432-IN (01-12-2010) SECTION II GENERAL PROVISIONS

  5. II.1 Itic

    Office of Legacy Management (LM)

    i! il II.1 Itic ihl j' ieil - Department of Emrgy \ Washington, DC20585 1 ' . The Honorable Bill. Johnson 30 Church Street Rochester, New York, 14614, Dear Mayor Johnion: I. ,Se$retary of EnergL Hazel.O'Leary has annouqced a .new appro the Department of Energy (DOE) and its communications with' .,support of this initiative, we are pleased to forward ttie e related to the, former Eastman Kodak Research Laboratoryisit jurisdiction that performed work for DOE or its predecesior information is

  6. PARS II Training Workbook (Course 103)

    Broader source: Energy.gov [DOE]

    PARS II 103 Updating Projects and Reporting Training Workbook (PARS II Release 1.1), September, 2010.

  7. Topo II: An Enzyme Target for Antibacterial and Cancer Drugs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topo II: An Enzyme Target for Antibacterial and Cancer Drugs Topo II: An Enzyme Target for Antibacterial and Cancer Drugs Print Wednesday, 27 February 2008 00:00 The veil has finally been lifted on an enzyme that is critical to the process of DNA transcription and replication and is a prime target of antibacterial and anticancer drugs. Researchers at Berkeley Lab and the University of California, Berkeley, have produced the first three-dimensional structural images of a DNA-bound type II

  8. Nemesis I: Parallel Enhancements to ExodusII

    Energy Science and Technology Software Center (OSTI)

    2006-03-28

    NEMESIS I is an enhancement to the EXODUS II finite element database model used to store and retrieve data for unstructured parallel finite element analyses. NEMESIS I adds data structures which facilitate the partitioning of a scalar (standard serial) EXODUS II file onto parallel disk systems found on many parallel computers. Since the NEMESIS I application programming interface (APl)can be used to append information to an existing EXODUS II files can be used on filesmore » which contain NEMESIS I information. The NEMESIS I information is written and read via C or C++ callable functions which compromise the NEMESIS I API.« less

  9. ORISE: Forensic scientist finds truth in fingerprints

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forensic scientist finds truth in fingerprints For more than 30 years, Imogene Van Buren has searched for truth in the friction ridges of fingerprints. She has identified victims...

  10. Right rock: Finding/refining customer expectations

    SciTech Connect (OSTI)

    Ashby, R.

    1997-11-01

    This report contains viewgraphs on methods of finding customer expectations of software and then refining the documentation and software to fit these expectations.

  11. A THOUSAND SHADOWS OF ANDROMEDA: ROTATING PLANES OF SATELLITES IN THE MILLENNIUM-II COSMOLOGICAL SIMULATION

    SciTech Connect (OSTI)

    Ibata, Rodrigo A.; Martin, Nicolas F.; Ibata, Neil G.; Lewis, Geraint F.; Conn, Anthony; Elahi, Pascal; Arias, Veronica; Fernando, Nuwanthika

    2014-03-20

    In a recent contribution, Bahl and Baumgardt investigated the incidence of planar alignments of satellite galaxies in the Millennium-II simulation and concluded that vast, thin planes of dwarf galaxies, similar to that observed in the Andromeda galaxy (M31), occur frequently by chance in ?-cold dark matter cosmology. However, their analysis did not capture the essential fact that the observed alignment is simultaneously radially extended, yet thin, and kinematically unusual. With the caveat that the Millennium-II simulation may not have sufficient mass resolution to identify confidently simulacra of low-luminosity dwarf galaxies, we re-examine that simulation for planar structures, using the same method as employed by Ibata etal. on the real M31 satellites. We find that 0.04% of host galaxies display satellite alignments that are at least as extreme as the observations, when we consider their extent, thickness, and number of members rotating in the same sense. We further investigate the angular momentum properties of the co-planar satellites, and find that the median of the specific angular momentum derived from the line-of-sight velocities in the real M31 structure (1.3 10{sup 4} km s{sup 1} kpc) is very high compared to systems drawn from the simulations. This analysis confirms that it is highly unlikely that the observed structure around the Andromeda galaxy is due to a chance occurrence. Interestingly, the few extreme systems that are similar to M31 arise from the accretion of a massive sub-halo with its own spatially concentrated entourage of orphan satellites.

  12. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for heavy element production...II-1 P. K.Sahu, J. B. Natowitz, R. Wada, K. Hagel, T. Materna, Z. Chen, L. Qin, M. Barbui,...

  13. Project Home Again Phase II

    SciTech Connect (OSTI)

    2010-01-30

    Phase II is a continuation of a charitable residential community project in New Orleans that builds affordable and energy efficient single detached residences that are storm resistant.

  14. Phase II Final Report

    SciTech Connect (OSTI)

    Schuknecht, Nate; White, David; Hoste, Graeme

    2014-09-11

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  15. National Synchrotron Light Source II

    ScienceCinema (OSTI)

    Steve Dierker

    2010-01-08

    The National Synchrotron Light Source II (NSLS-II) at the U.S. Department of Energy's Brookhaven National Laboratory is a proposed new state-of-the-art medium energy storage ring designed to deliver world-leading brightness and flux with top-off operation

  16. Missourian Finds New Opportunity in Energy Industry

    Broader source: Energy.gov [DOE]

    How one Missouri man decided to take matters into his own hands - creating a company that improves energy efficiency in homes and buildings - after not being able to find work during the recession.

  17. National Electric Transmission Congestion Study: Preliminary Findings

    Broader source: Energy.gov [DOE]

    The Department hosted three webinars in August 2012 to receive input and suggestions concerning the preliminary findings of the National Electric Transmission Congestion Study. The updated presentation used in the webinars is now available.

  18. TE Connectivity Finds Answers in Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TE Connectivity Finds Answers in Tomography TE Connectivity Finds Answers in Tomography Print Thursday, 22 August 2013 10:50 TE Connectivity is a world leader in connectivity-the $13 billion global company designs and manufactures more than 500,000 different electronic connectivity products for the automotive, energy, industrial, broadband communications, consumer device, healthcare, aerospace, and defense industries. TE Connectivity has a long-standing commitment to innovation and engineering

  19. Floodplain Assessment and Statement of Findings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Statement of Findings for Installation of a Renewable Energy Anaerobic Digester Facility at the University of California, Davis in Yolo County, California January 28, 2013 1.0 Introduction This Floodplain Assessment and Statement of Findings has been prepared in accordance with 10 Code of Federal Regulations (CFR) 1022, "Compliance with Floodplain and Wetland Environmental Review Requirements" which were promulgated to implement the requirements of the U.S. Department of Energy's

  20. Floodplain Statement of Findings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Floodplain Statement of Findings Floodplain Statement of Findings Loan Guarantee to AES Energy Storage, LLC Project Dyno Electric Grid Stability Advanced Battery Systems Project Dyno would provide ancillary services within the New York power market. The Project is composed of advanced lithium ion battery cells and power control technologies to store power to help maintain the stability of the electric power grid. The Project would be composed of ten fifty-three foot metal containers each housing

  1. Distributed PV Interconnection Recent Analysis Findings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recent Analysis Findings Page 1 of 18 Kristen Ardani, Miriam Makhyoun Page 1 of 18 [Speaker: Kristen Ardani] Cover Slide: Good afternoon, everyone. Thank you for joining the Distributed Generation Interconnection Collaborative informational webinar. Today, we are kicking off 2015 with a joint presentation from SEPA and NREL, in which each will discuss recent research and analysis findings related to interconnection. Slide 2: So really, the purpose of today's meeting is to hear recent research

  2. Distributed PV Interconnection: Recent Analysis Findings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 21, 2015 "NREL and SEPA Recent Analysis Findings" Miriam Makhyoun, Solar Electric Power Association (SEPA) Kristen Ardani, National Renewable Energy Laboratory (NREL) 2 Purpose of Today's Meeting * Hear results from SEPA's recent survey of utility interconnection practices. o SEPA finds that utilities confront common challenges as they move towards more streamlined interconnection application processing. * Hear NREL results of forthcoming DGIC data collection and analysis,

  3. NREL Publishes Gearbox Reliability Collaborative Findings Report |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Publishes Gearbox Reliability Collaborative Findings Report NREL Publishes Gearbox Reliability Collaborative Findings Report October 3, 2011 - 12:56pm Addthis This is an excerpt from the Third Quarter 2011 edition of the Wind Program R&D Newsletter. In June, DOE's National Renewable Energy Laboratory (NREL) published the first formal report on the efforts of the Gearbox Reliability Collaborative (GRC) to address a major challenge for the wind energy industry-gearbox

  4. Mars Rover finds changing rocks, surprising scientists

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mars Rover finds changing rocks, surprising scientists Mars Rover finds changing rocks, surprising scientists As NASA's Curiosity rover treks up a three-mile-high mountain on Mars, the rocks are changing. Back on Earth, scientists analyzing the data realized this was something different: It turned out to be the first of the high-silica rocks. December 24, 2015 Mars landscape This color-adjusted composite of images taken by NASA's Curiosity rover in September shows the lower portion of Mount

  5. TE Connectivity Finds Answers in Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TE Connectivity Finds Answers in Tomography TE Connectivity Finds Answers in Tomography Print Thursday, 22 August 2013 10:50 TE Connectivity is a world leader in connectivity-the $13 billion global company designs and manufactures more than 500,000 different electronic connectivity products for the automotive, energy, industrial, broadband communications, consumer device, healthcare, aerospace, and defense industries. TE Connectivity has a long-standing commitment to innovation and engineering

  6. Jefferson Laboratory Findings Excite Theoreticians, Experimentatlists |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jefferson Lab Laboratory Findings Excite Theoreticians, Experimentatlists Jefferson Laboratory Findings Excite Theoreticians, Experimentatlists March 1999 Seemingly reasonable assumptions define the human view of the world. But ruled of thumb can mislead - or be altogether incorrect. Fortunately, in physics, most assumptions can be tested. Those that don't measure up are amended. An experiment at the Department of Energy's Thomas Jefferson National Accelerator Facility (Jefferson Lab) has

  7. Cloud structure of the nearest brown dwarfs. II: High-amplitude variability for Luhman 16 A and B in and out of the 0.99 μm FeH feature

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buenzli, Esther; Marley, Mark S.; Apai, Daniel; Saumon, Didier; Biller, Beth A.; Crossfield, Ian J. M.; Radigan, Jacqueline

    2015-10-20

    The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm.more » We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. Here, we re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.« less

  8. Cloud structure of the nearest brown dwarfs. II: High-amplitude variability for Luhman 16 A and B in and out of the 0.99 μm FeH feature

    SciTech Connect (OSTI)

    Buenzli, Esther; Marley, Mark S.; Apai, Daniel; Saumon, Didier; Biller, Beth A.; Crossfield, Ian J. M.; Radigan, Jacqueline

    2015-10-20

    The re-emergence of the 0.99 μm FeH feature in brown dwarfs of early- to mid-T spectral type has been suggested as evidence for cloud disruption where flux from deep, hot regions below the Fe cloud deck can emerge. The same mechanism could account for color changes at the L/T transition and photometric variability. We present the first observations of spectroscopic variability of brown dwarfs covering the 0.99 μm FeH feature. We observed the spatially resolved very nearby brown dwarf binary WISE J104915.57–531906.1 (Luhman 16AB), a late-L and early-T dwarf, with Hubble Space Telescope/WFC3 in the G102 grism at 0.8–1.15 μm. We find significant variability at all wavelengths for both brown dwarfs, with peak-to-valley amplitudes of 9.3% for Luhman 16B and 4.5% for Luhman 16A. This represents the first unambiguous detection of variability in Luhman 16A. We estimate a rotational period between 4.5 and 5.5 hr, very similar to Luhman 16B. Variability in both components complicates the interpretation of spatially unresolved observations. The probability for finding large amplitude variability in any two brown dwarfs is less than 10%. Our finding may suggest that a common but yet unknown feature of the binary is important for the occurrence of variability. For both objects, the amplitude is nearly constant at all wavelengths except in the deep K i feature below 0.84 μm. No variations are seen across the 0.99 μm FeH feature. The observations lend strong further support to cloud height variations rather than holes in the silicate clouds, but cannot fully rule out holes in the iron clouds. Here, we re-evaluate the diagnostic potential of the FeH feature as a tracer of cloud patchiness.

  9. EA-1375: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Construction and Operation of a New Office Building and Related Structures Within TA-3 at Los Alamos National Laboratory, Los Alamos, New Mexico

  10. Competing retention pathways of uranium upon reaction with Fe(II)

    SciTech Connect (OSTI)

    Massey, Michael S.; Lezama Pacheco, Juan S.; Jones, Morris; Ilton, Eugene S.; Cerrato, Jose M.; Bargar, John R.; Fendorf, Scott

    2014-10-01

    Biogeochemical retention processes, including adsorption, reductive precipitation, and incorporation into host minerals, are important in contaminant transport, remediation, and geologic deposition of uranium. Recent work has shown that U can become incorporated into iron (hydr)oxide minerals, with a key pathway arising from Fe(II)-induced transformation of ferrihydrite, (Fe(OH)3nH2O) to goethite (?-FeO(OH)); this is a possible U retention mechanism in soils and sediments. Several key questions, however, remain unanswered regarding U incorporation into iron (hydr)oxides and this pathways contribution to U retention, including: (i) the competitiveness of U incorporation versus reduction to U(IV) and subsequent precipitation of UO2; (ii) the oxidation state of incorporated U; (iii) the effects of uranyl aqueous speciation on U incorporation; and, (iv) the mechanism of U incorporation. Here we use a series of batch reactions conducted at pH ~7, [U(VI)] from 1 to 170 ?M, [Fe(II)] from 0 to 3 mM, and [Ca] at 0 or 4 mM) coupled with spectroscopic examination of reaction products of Fe(II)-induced ferrihydrite transformation to address these outstanding questions. Uranium retention pathways were identified and quantified using extended x-ray absorption fine structure (EXAFS) spectroscopy, x-ray powder diffraction, x-ray photoelectron spectroscopy, and transmission electron microscopy. Analysis of EXAFS spectra showed that 14 to 89% of total U was incorporated into goethite, upon reaction with Fe(II) and ferrihydrite. Uranium incorporation was a particularly dominant retention pathway at U concentrations ? 50 ?M when either uranyl-carbonato or calcium-uranyl-carbonato complexes were dominant, accounting for 64 to 89% of total U. With increasing U(VI) and Fe(II) concentrations, U(VI) reduction to U(IV) became more prevalent, but U incorporation remained a functioning retention pathway. These findings highlight the potential importance of U(V) incorporation within iron

  11. Methods for preparation of cyclopentadienyliron (II) arenes

    DOE Patents [OSTI]

    Keipert, Steven J.

    1991-01-01

    Two improved methods for preparation of compounds with the structure shown in equation X [(Cp)--Fe--(Ar)].sup.+.sub.b X.sup.b- (X) where Cp is an eta.sup.5 complexed, substituted or unsubstituted, cyclopentadienyl or indenyl anion, Ar is an eta.sup.6 complexed substituted or unsubstituted, pi-arene ligand anad X is a b-valent anion where b is an integer between 1 and 3. The two methods, which differ in the source of the cyclopentadienyl anion - Lewis acid complex, utilize a Lewis acid assisted ligand transfer reaction. The cyclopentadienyl anion ligand, assisted by a Lewis acid is transferred to ferrous ion in the presence of an arene. In the first method, the cyclopentadienyl anion is derived from ferrocene and ferrous chloride. In this reaction, the cyclopentadienyliron (II) arene product is derived partially from ferrocene and partially from the ferrous salt. In the second method, the cyclopentadienyl anion - Lewis acid complex is formed by direct reaction of the Lewis acid with an inorganic cyclopentadienide salt. The cyclopentadienyliron (II) arene product of this reaction is derived entirely from the ferrous salt. Cyclopentadienyliron (II) arene cations are of great interest due to their utility as photoactivatable catalysts for a variety of polymerization reactions.

  12. Dimorphism in iron(II) methylphosphonate: Low-temperature crystal structure and temperature-dependent Mossbauer studies of a new form of the layered weak ferromagnet Fe[(CH{sub 3}PO{sub 3})(H{sub 2}O)

    SciTech Connect (OSTI)

    Leone, Philippe . E-mail: philippe.leone@cnrs-imn.fr; Palvadeau, Pierre; Boubekeur, Kamal; Meerschaut, Alain; Bellitto, Carlo; Bauer, Elvira M.; Righini, Guido; Fabritchnyi, Pavel

    2005-04-15

    A second form of the literature-known layered weak ferromagnet Fe[(CH{sub 3}PO{sub 3})(H{sub 2}O)] has been isolated. The crystal structure determination of this new form (2) has been carried out at T=300, 200 and 130K. It crystallizes in the orthorhombic space group Pmn2{sub 1}: a=5.7177(11), b=8.8093(18), c=4.8154(10)A, while form (1) crystallizes in the space group Pna2{sub 1}: a=17.58(2), b=4.814(1), c=5.719(1)A. Moessbauer spectroscopy on form (2) has been performed in the temperature range 4-300K; and, at T{approx}160K, a drastic change in the quadrupole splitting ({delta}E) and a broadening of the doublet components is noticed. But surprisingly, on cooling the crystal, no structural change is observed, which could account for the increase in {delta}E. Below T=25K, {sup 57}Fe spectra transform into hyperfine splitting patterns which reveal a magnetically ordered state in agreement with the results of earlier magnetic susceptibility studies.

  13. Current-wave spectra coupling project. Volume IV. Part A. Formulation of the three-dimensional structure of storm-generated currents. Part B. Summaries of Volumes I, II and III

    SciTech Connect (OSTI)

    Venezian, G.; Bretschneider, C.L.

    1980-09-01

    An attempt is made to formulate the technical approach to the problem of three dimensional wind driven currents under hurricane conditions. Reference is given to the splendid piece of research on the subject by Forristall (1974) Three-dimensional structure of storm-generated currents, J. Geophys. Res. 79, 2721-2727. The present approach, although not entirely satisfactory, seems to be an improvement on the work by Forristall, but this remains to be verified with future work, including the use of measured data. An improvement could be made if there were some better way of representing the shear stress as a function of the wind velocity (wind speed and direction). It seems that the wind velocity relative to the water motion is what matters, but in turbulent flow the surface value is not well defined. This difficulty leaves one with an unbalanced vortex stretching which accounts for the spin-up of the fluid, but the details of that are lacking. Essentially, it appears that it is feasible to modify Forristall's approach to obtain a more realistic representation of the structure of the boundary layer to take into account the turbulent nature of the flow.

  14. Timber Road II | Open Energy Information

    Open Energy Info (EERE)

    Road II Jump to: navigation, search Name Timber Road II Facility Timber Road II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Horizon Wind...

  15. Nobles Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    Farm II Jump to: navigation, search Name Nobles Wind Farm II Facility Nobles Wind Farm II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  16. Shiloh II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Shiloh II Wind Farm Jump to: navigation, search Name Shiloh II Wind Farm Facility Shiloh II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  17. Oliver II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    II Wind Farm Jump to: navigation, search Name Oliver II Wind Farm Facility Oliver II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NextEra...

  18. CWES II Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    II Wind Farm Jump to: navigation, search Name CWES II Wind Farm Facility CWES II Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner SeaWest...

  19. Investigators find hundreds of intentional nuclear releases

    SciTech Connect (OSTI)

    Lobsenz, G.

    1994-10-24

    Investigators with the federal Advisory Committee on Human Radiation Experiments have said that the category of intentional releases is now known to be larger, in variety and quantity, than the 13 releases identified prior to the committee`s formation in January 1994 by President Clinton. The committee is now aware of hundreds of additional intentional releases. In addition to the intentional releases, the committee said it had compiled documents on 400 biomedical experiments involving radiation prior to 1975, and had at least fragmentary evidence of more than 1,000 more. The committee also discovered a top secret 1953 Defense Department policy statement on human experimentation that was based on the World War II-era Nuremberg Code. The committee said it was looking into how or whether the policy was implemented. The committee is expected to issue a final report, including recommendations on possible compensation for victims by April 1995.

  20. PARS II 104 Contractor Monthly Upload | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    104 Contractor Monthly Upload PARS II 104 Contractor Monthly Upload PDF icon PARS II 104 Contractor Monthly Upload More Documents & Publications PARS II TRAINING PARS II Training ...

  1. Finding a Career in Energy Efficiency

    Broader source: Energy.gov [DOE]

    Kendra went to a county agency hoping they could help her find work, but what she really wanted was a career. That’s when she was referred to an upcoming weatherization training program hosted by the Laborers’ International Union of North America, a half-million strong labor union for construction workers, including weatherization workers.

  2. An interesting finding in sup 229 Th

    SciTech Connect (OSTI)

    Reich, C.W.

    1990-01-01

    Work at INEL has recently established that the first excited states of {sup 229}Th forms a closely spaced doublet with the ground state, the separation being 1 {plus minus} 4 electron volts. A discussion of the data and the reasoning supporting this unprecedented finding is given. Some potential applications are briefly mentioned. 27 refs., 3 figs., 2 tabs.

  3. DOE issues Finding of No Significant Impact on the Disposition of Five Signature Properties at Idaho National Laboratory

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy (DOE) has determined that tearing down four World War II-era historic structures and part of another structure at Idaho National Laboratory’s Central Facilities Area that remain from when the area served as the U.S. Naval Proving Ground will not have a significant impact on the environment.

  4. Endicott Biofuels II LLC | Open Energy Information

    Open Energy Info (EERE)

    Endicott Biofuels II LLC Jump to: navigation, search Name: Endicott Biofuels II, LLC Place: Houston, Texas Zip: 77060-3235 Sector: Biofuels Product: Houston-based biofuels producer...

  5. Cabazon Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Cabazon Wind Farm II Facility Cabazon Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Goldman Sachs...

  6. Cinergy Ventures II LLC | Open Energy Information

    Open Energy Info (EERE)

    Cinergy Ventures II LLC Jump to: navigation, search Name: Cinergy Ventures II, LLC Place: Cincinnati, Ohio Zip: OH 45202 Product: The venture capital arm of Cinergy Corp....

  7. Harvest Wind Farm II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Harvest Wind Farm II Facility Harvest Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner John...

  8. Kotzebue Wind Project II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Kotzebue Wind Project II Facility Kotzebue Wind Project Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  9. Tatanka Wind Project II | Open Energy Information

    Open Energy Info (EERE)

    II Jump to: navigation, search Name Tatanka Wind Project II Facility Tatanka Wind Project Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  10. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... L. W. May, S. Wuenschel, B. Stein, and S. J. Yennello Analysis of 86,78Kr + 64,58Ni data taken on the upgraded NIMROD-ISiS...... II-28 S. Wuenschel, S. ...