Sample records for filtrate csh caustic

  1. Caustics in turbulent aerosols

    E-Print Network [OSTI]

    M. Wilkinson; B. Mehlig

    2004-11-03T23:59:59.000Z

    Networks of caustics can occur in the distribution of particles suspended in a randomly moving gas. These can facilitate coagulation of particles by bringing them into close proximity, even in cases where the trajectories do not coalesce. We show that the long-time morphology of these caustic patterns is determined by the Lyapunov exponents lambda_1, lambda_2 of the suspended particles, as well as the rate J at which particles encounter caustics. We develop a theory determining the quantities J, lambda_1, lambda_2 from the statistical properties of the gas flow, in the limit of short correlation times.

  2. Electron caustic lithography

    SciTech Connect (OSTI)

    Kennedy, S. M.; Zheng, C. X.; Tang, W. X.; Paganin, D. M.; Jesson, D. E. [School of Physics, Monash University, Victoria, 3800 (Australia); Fu, J. [Department of Mechanical and Aerospace Engineering, Monash University, Victoria, 3800 (Australia)

    2012-06-15T23:59:59.000Z

    A maskless method of electron beam lithography is described which uses the reflection of an electron beam from an electrostatic mirror to produce caustics in the demagnified image projected onto a resist-coated wafer. By varying the electron optics, e.g. via objective lens defocus, both the morphology and dimensions of the caustic features may be controlled, producing a range of bright and tightly focused projected features. The method is illustrated for line and fold caustics and is complementary to other methods of reflective electron beam lithography.

  3. Summary - Caustic Recovery Technology

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2Uranium Transferon the Passing of AdmiraltheOil and Less CO2Caustic Recovery

  4. Moist caustic leaching of coal

    DOE Patents [OSTI]

    Nowak, Michael A. (Elizabeth, PA)

    1994-01-01T23:59:59.000Z

    A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

  5. Causticizing for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07T23:59:59.000Z

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  6. Caustics in special multiple lenses

    E-Print Network [OSTI]

    V. Bozza

    2000-01-13T23:59:59.000Z

    Despite its mathematical complexity, the multiple gravitational lens can be studied in detail in every situation where a perturbative approach is possible. In this paper, we examine the caustics of a system with a lens very far from the others with respect to their Einstein radii, and a system where mutual distances between lenses are small compared to the Einstein radius of the total mass. Finally we review the case of a planetary system adding some new information (area of caustics, duality and higher order terms).

  7. Effect of temperature on the microstructure of calcium silicate hydrate (C-S-H)

    SciTech Connect (OSTI)

    Gallucci, E., E-mail: gallucci.emmanuel@ch.sika.com; Zhang, X.; Scrivener, K.L.

    2013-11-15T23:59:59.000Z

    Temperature affects the properties of concrete through its effect on the hydration of cement and its associated microstructural development. This paper focuses on the modifications to C-S-H induced by isothermal curing between 5 and 60 °C. The results show that as the temperature increases (within the range studied) the C/S ratio of C-S-H changes only slightly, with a higher degree of polymerisation of silicate chains, but there is a significant decrease in its bound water content and an increase of apparent density of 25%. This increase seems to come from a different packing of C-S-H at the nanoscale. As a consequence of these changes, the microstructure of the cement paste is much coarser and porous, which explains the lower final strengths obtained by curing at elevated temperatures. -- Highlights: •C-S-H structure studied at the atomic level •Multiple analytical techniques used •Studies conducted at temperatures above and below normal temperatures.

  8. Role of interatomic bonding in the mechanical anisotropy and interlayer cohesion of CSH crystals

    SciTech Connect (OSTI)

    Dharmawardhana, C.C. [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States); Misra, A. [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States)] [Department of Civil, Environmental, and Architectural Engineering, University of Kansas, Lawrence, KS 66045 (United States); Aryal, S.; Rulis, P. [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)] [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States); Ching, W.Y., E-mail: ccdxz8@mail.umkc.edu [Department of Physics and Astronomy, University of Missouri—Kansas City, Kansas City, MO 64110 (United States)

    2013-10-15T23:59:59.000Z

    Atomic scale properties of calcium silicate hydrate (CSH), the main binding phase of hardened Portland cement, are not well understood. Over a century of intense research has identified almost 50 different crystalline CSH minerals which are mainly categorized by their Ca/Si ratio. The electronic structure and interatomic bonding in four major CSH crystalline phases with structures close to those found in hardened cement are investigated via ab initio methods. Our result reveals the critical role of hydrogen bonding and importance of specifying precise locations for water molecules. Quantitative analysis of contributions from different bond types to the overall cohesion shows that while the Si-O covalent bonds dominate, the hydrogen bonding and Ca-O bonding are also very significant. Calculated results reveal the correlation between bond topology and interlayer cohesion. The overall bond order density (BOD) is found to be a more critical measure than the Ca/Si ratio in classifying different CSH crystals.

  9. Dark matter axions and caustic rings

    SciTech Connect (OSTI)

    Sikivie, P.

    1997-11-01T23:59:59.000Z

    This report contains discussions on the following topics: the strong CP problem; dark matter axions; the cavity detector of galactic halo axions; and caustic rings in the density distribution of cold dark matter halos.

  10. Caustic graphene plasmons with Kelvin angle

    E-Print Network [OSTI]

    Shi, Xihang; Gao, Fei; Xu, Hongyi; Yang, Zhaoju; Zhang, Baile

    2015-01-01T23:59:59.000Z

    A century-long argument made by Lord Kelvin that all swimming objects have an effective Mach number of 3, corresponding to the Kelvin angle of 19.5 degree for ship waves, has been recently challenged with the conclusion that the Kelvin angle should gradually transit to the Mach angle as the ship velocity increases. Here we show that a similar phenomenon can happen for graphene plasmons. By analyzing the caustic wave pattern of graphene plasmons stimulated by a swift charged particle moving uniformly above graphene, we show that at low velocities of the charged particle, the caustics of graphene plasmons form the Kelvin angle. At large velocities of the particle, the caustics disappear and the effective semi-angle of the wave pattern approaches the Mach angle. Our study introduces caustic wave theory to the field of graphene plasmonics, and reveals a novel physical picture of graphene plasmon excitation during electron energy-loss spectroscopy measurement.

  11. Characterization, Washing, Leaching, and Filtration of C-104 Sludge

    SciTech Connect (OSTI)

    KP Brooks; PR Bredt; GR Golcar; SA Hartley; LK Jagoda; KG Rappe; MW Urie

    2000-06-09T23:59:59.000Z

    Approximately 1,400 g of wet Hanford Tank C-104 Sludge was evaluated by Battelle for the high-level waste (HLW) pretreatment processes of ultrafiltration, dilute caustic washing, and elevated-temperature caustic leaching. The filterability of diluted C-104 sludge was measured with a 0.1-{micro}m sintered metal Mott filter using a 24-inch-long, single-element, crossflow filtration system (cells unit filter [CUF]). While the filtrate was being recirculated prior to washing and leaching, a 6.9 wt% solids slurry was evaluated with a matrix of seven 1-hour conditions of varying trans-membrane pressure (30 to 70 psid) and axial velocity (9 to 15 ft/s). The filtrate flux and backpulse efficiency were determined for each condition. The slurry was concentrated to 23 wt% solids, a second matrix of six 1-hour conditions was performed, and data analogous to that recorded in the first matrix were obtained. The low-solids-concentration matrix produced filtrate flux rates that ranged from 0.038 to 0.083 gpm/ft{sup 2}. The high-solids-concentration matrix produced filtrate flux rates that ranged from 0.0095 to 0.0172 gpm/ft{sup 2}. In both cases, the optimum filtrate flux was at the highest axial velocity (15 ft/s) and transmembrane pressure had little effect. Nearly all of the measured filtrate fluxes were more than an order of magnitude greater than the required plant flux for C-104 of 0.00126 gpm/ft{sup 2}. In both matrices, the filtrate flux appeared to be proportional to axial velocity, and the permeability appeared to be inversely proportional to the trans-membrane pressure. The first test condition was repeated as the last test condition for each matrix. In both cases, there was a significant decrease in filtrate flux, indicating some filter fouling during the test matrix that could not be removed by backpulsing alone, although the backpulse number and duration were not optimized. Following testing of these two matrices, the material was washed within the CUF by continuously adding approximately 5 L of 0.01-M NaOH and then removing it through the filter as permeate. The purpose of this washing step with 0.01-MNaOH was to remove water-soluble components that might inhibit dissolution of salts during caustic leaching, while avoiding peptization of the solids that occurs at a pH below 12. After washing the sludge with dilute caustic, it was combined with 3-M caustic, and the slurry was leached in a stainless steel vessel at 85 C for 8 hours. This leaching was followed by two 0.01-M caustic washes, each conducted in a stainless steel vessel to dilute remaining analytes from the interstitial liquids. Each rinse was performed at 85 C for 8 hours. Permeate from each of these process steps was removed using the crossflow filter system. Samples of the permeate from each slurry-washing activity and all intermediate process steps were taken and analyzed for chemical and radiochemical constituents. The fraction of each component removed was calculated. Key results are presented in Table S.1.

  12. Rotary filtration system

    DOE Patents [OSTI]

    Herman, David T. (Aiken, SC); Maxwell, David N. (Aiken, SC)

    2011-04-19T23:59:59.000Z

    A rotary filtration apparatus for filtering a feed fluid into permeate is provided. The rotary filtration apparatus includes a container that has a feed fluid inlet. A shaft is at least partially disposed in the container and has a passageway for the transport of permeate. A disk stack made of a plurality of filtration disks is mounted onto the shaft so that rotation of the shaft causes rotation of the filtration disks. The filtration disks may be made of steel components and may be welded together. The shaft may penetrate a filtering section of the container at a single location. The rotary filtration apparatus may also incorporate a bellows seal to prevent leakage along the shaft, and an around the shaft union rotary joint to allow for removal of permeate. Various components of the rotary filtration apparatus may be removed as a single assembly.

  13. Laboratory Demonstration of the Pretreatment Process with Caustic and Oxidative Leaching Using Actual Hanford Tank Waste

    SciTech Connect (OSTI)

    Fiskum, Sandra K.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Snow, Lanee A.

    2009-01-01T23:59:59.000Z

    This report describes the bench-scale pretreatment processing of actual tank waste materials through the entire baseline WTP pretreatment flowsheet in an effort to demonstrate the efficacy of the defined leaching processes on actual Hanford tank waste sludge and the potential impacts on downstream pretreatment processing. The test material was a combination of reduction oxidation (REDOX) tank waste composited materials containing aluminum primarily in the form of boehmite and dissolved S saltcake containing Cr(III)-rich entrained solids. The pretreatment processing steps tested included • caustic leaching for Al removal • solids crossflow filtration through the cell unit filter (CUF) • stepwise solids washing using decreasing concentrations of sodium hydroxide with filtration through the CUF • oxidative leaching using sodium permanganate for removing Cr • solids filtration with the CUF • follow-on solids washing and filtration through the CUF • ion exchange processing for Cs removal • evaporation processing of waste stream recycle for volume reduction • combination of the evaporated product with dissolved saltcake. The effectiveness of each process step was evaluated by following the mass balance of key components (such as Al, B, Cd, Cr, Pu, Ni, Mn, and Fe), demonstrating component (Al, Cr, Cs) removal, demonstrating filterability by evaluating filter flux rates under various processing conditions (transmembrane pressure, crossflow velocities, wt% undissolved solids, and PSD) and filter fouling, and identifying potential issues for WTP. The filterability was reported separately (Shimskey et al. 2008) and is not repeated herein.

  14. In Situ Causticizing for Black Liquor Gasification

    SciTech Connect (OSTI)

    Scott Alan Sinquefield

    2005-10-01T23:59:59.000Z

    Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

  15. Caustic Recovery Technology | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments EnergyFebruary3CarolinaAdministration-Sierra NevadaNationalCaustic

  16. Progress in caustic dezincing of galvanized scrap

    SciTech Connect (OSTI)

    Dudek, F.J.; Daniels, E.J. [Argonne National Lab., IL (United States); Morgan, W.A. [Metal Recovery Technologies, Inc., East Chicago, IN (United States)

    1997-08-01T23:59:59.000Z

    In response to the worldwide increase in consumption of galvanized steel for automobiles in the last fifteen years, and the cost of environmental compliance associated with remelting larger quantities of galvanized steel scrap, processes are being developed to separate and recover the steel and zinc from galvanized ferrous scrap. In the process discussed here, zinc is dissolved from the scrap in hot caustic and is recovered electrolytically as dendritic powder. The dezinced ferrous scrap is rinsed and used directly. The process is effective for zinc, lead, and aluminum removal on loose and baled scrap and on all types of galvanized steel. Pilot testing has been conducted in Hamilton, Ontario for batch treatment of 900 tonnes of mostly baled scrap. A pilot plant in East Chicago, Indiana, now in its second generation, has dezinced in a continuous process mode about 1,800 tonnes of loose clips and shredded stamping plant scrap; this scrap typically has residual zinc below 0.05% and sodium dragout below 0.001%. This paper reviews caustic dezincing pilot plant performance and economics.

  17. ACTINIDE REMOVAL PROCESS SAMPLE ANALYSIS, CHEMICAL MODELING, AND FILTRATION EVALUATION

    SciTech Connect (OSTI)

    Martino, C.; Herman, D.; Pike, J.; Peters, T.

    2014-06-05T23:59:59.000Z

    Filtration within the Actinide Removal Process (ARP) currently limits the throughput in interim salt processing at the Savannah River Site. In this process, batches of salt solution with Monosodium Titanate (MST) sorbent are concentrated by crossflow filtration. The filtrate is subsequently processed to remove cesium in the Modular Caustic Side Solvent Extraction Unit (MCU) followed by disposal in saltstone grout. The concentrated MST slurry is washed and sent to the Defense Waste Processing Facility (DWPF) for vitrification. During recent ARP processing, there has been a degradation of filter performance manifested as the inability to maintain high filtrate flux throughout a multi-batch cycle. The objectives of this effort were to characterize the feed streams, to determine if solids (in addition to MST) are precipitating and causing the degraded performance of the filters, and to assess the particle size and rheological data to address potential filtration impacts. Equilibrium modelling with OLI Analyzer{sup TM} and OLI ESP{sup TM} was performed to determine chemical components at risk of precipitation and to simulate the ARP process. The performance of ARP filtration was evaluated to review potential causes of the observed filter behavior. Task activities for this study included extensive physical and chemical analysis of samples from the Late Wash Pump Tank (LWPT) and the Late Wash Hold Tank (LWHT) within ARP as well as samples of the tank farm feed from Tank 49H. The samples from the LWPT and LWHT were obtained from several stages of processing of Salt Batch 6D, Cycle 6, Batch 16.

  18. Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

    2009-03-02T23:59:59.000Z

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan. • Characterizing the homogenized sample groups. • Performing parametric leaching testing on each group for compounds of interest. • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form of gibbsite, and its impact on filtration. The initial sample was diluted with a liquid simulant to simulate the receiving concentration of retrieved tank waste into the UFP2 vessel (< 10 wt% undissolved solids). Filtration testing was performed on the dilute waste sample and dewatered to a higher solids concentration. Filtration testing was then performed on the concentrated slurry. Afterwards, the slurry was caustic leached to remove aluminum present in the undissolved solid present in the waste. The leach was planned to simulate leaching conditions in the UFP2 vessel. During the leach, slurry supernate samples were collected to measure the dissolution rate of aluminum in the waste. After the slurry cooled down from the elevated leach temperature, the leach liquor was dewatered from the solids. The remaining slurry was rinsed and dewatered with caustic solutions to remove a majority of the dissolved aluminum from the leached slurry. The concentration of sodium hydroxide in the rinse solutions was high enough to maintain the solubility of the aluminum in the dewatered rinse solutions after dilution of the slurry supernate. Filtration tests were performed on the final slurry to compare to filtration performance before and after caustic leaching.

  19. Caustic Leaching of Sludges from Selected Hanford Tanks

    SciTech Connect (OSTI)

    Chase, C.W.; Egan, B.Z.; Spencer, B.B.

    1998-08-01T23:59:59.000Z

    The objective of this project was to measure the caustic dissolution behavior of sludge components from selected Hanford waste tank sludge samples under different conditions. The dissolution of aluminum, chromium, and other constituents of actual sludge samples in aqueous sodium hydroxide solution was evaluated using various values of temperature, sodium hydroxide concentration, volume of caustic solution per unit mass of sludge (liquid:solids ratio), and leaching time.

  20. A mathematical and experimental study of caustic flooding

    E-Print Network [OSTI]

    Shen, Tsu-Cheng

    1985-01-01T23:59:59.000Z

    : Dr. Ching Buang Wu A simple non-equilibrium chemical displacement model for continuous, linear, caustic flooding of crude oil is presented. The laboratory experiments were conducted to support the numerical simulation and to verify the results...-water fractional flow curves depending on its local concentration and water saturation. The numerical study was supported by caustic displacement testing of Sacroc crude oil. Quantitative agreements were found between the results from mathematical and experimen...

  1. Liquid filtration simulation

    SciTech Connect (OSTI)

    Corey, I.; Bergman, W.

    1996-06-01T23:59:59.000Z

    We have a developed a computer code that simulates 3-D filtration of suspended particles in fluids in realistic filter structures. This code, being the most advanced filtration simulation package developed to date, provides LLNL and DOE with new capabilities to address problems in cleaning liquid wastes, medical fluid cleaning, and recycling liquids. The code is an integrated system of commercially available and LLNL-developed software; the most critical are the computational fluid dynamics (CFD) solver and the particle transport program. For the CFD solver, we used a commercial package based on Navier-Stokes equations and a LLNL-developed package based on Boltzman-lattice gas equations. For the particle transport program, we developed a cod based on the 3-D Langevin equation of motion and the DLVO theory of electrical interactions. A number of additional supporting packages were purchased or developed to integrate the simulation tasks and to provide visualization output.

  2. Physics of Caustics and Protein Folding: Mathematical Parallels

    E-Print Network [OSTI]

    Walter Simmons; Joel L. Weiner

    2011-08-13T23:59:59.000Z

    The energy for protein folding arises from multiple sources and is not large in total. In spite of the many specific successes of energy landscape and other approaches, there still seems to be some missing guiding factor that explains how energy from diverse small sources can drive a complex molecule to a unique state. We explore the possibility that the missing factor is in the geometry. A comparison of folding with other physical phenomena, together with analytic modeling of a molecule, led us to analyze the physics of optical caustic formation and of folding behavior side-by-side. The physics of folding and caustics is ostensibly very different but there are several strong parallels. This comparison emphasizes the mathematical similarity and also identifies differences. Since the 1970's, the physics of optical caustics has been developed to a very high degree of mathematical sophistication using catastrophe theory. That kind of quantitative application of catastrophe theory has not previously been applied to folding nor have the points of similarity with optics been identified or exploited. A putative underlying physical link between caustics and folding is a torsion wave of non-constant wave speed, propagating on the dihedral angles and $\\Psi$ found in an analytical model of the molecule. Regardless of whether we have correctly identified an underlying link, the analogy between caustic formation and folding is strong and the parallels (and differences) in the physics are useful.

  3. Physics of Caustics and Protein Folding: Mathematical Parallels

    E-Print Network [OSTI]

    Simmons, Walter

    2011-01-01T23:59:59.000Z

    The energy for protein folding arises from multiple sources and is not large in total. In spite of the many specific successes of energy landscape and other approaches, there still seems to be some missing guiding factor that explains how energy from diverse small sources can drive a complex molecule to a unique state. We explore the possibility that the missing factor is in the geometry. A comparison of folding with other physical phenomena, together with analytic modeling of a molecule, led us to analyze the physics of optical caustic formation and of folding behavior side-by-side. The physics of folding and caustics is ostensibly very different but there are several strong parallels. This comparison emphasizes the mathematical similarity and also identifies differences. Since the 1970's, the physics of optical caustics has been developed to a very high degree of mathematical sophistication using catastrophe theory. That kind of quantitative application of catastrophe theory has not previously been applied ...

  4. Synthesis and nano-mechanical characterization of calcium-silicate-hydrate (C-S-H) made with 1.5 CaO/SiO{sub 2} mixture

    SciTech Connect (OSTI)

    Foley, Emmy M. [Arizona Public Service, Wintersburg, AZ 85354 (United States)] [Arizona Public Service, Wintersburg, AZ 85354 (United States); Kim, Jung J. [Department of Civil and Environmental Engineering, Sejong University, Seoul 143-747 (Korea, Republic of)] [Department of Civil and Environmental Engineering, Sejong University, Seoul 143-747 (Korea, Republic of); Reda Taha, M.M., E-mail: mrtaha@unm.edu [Department of Civil Engineering, MSC01 1070, 1 University of New Mexico, Albuquerque, NM 87131-0001 (United States)

    2012-09-15T23:59:59.000Z

    In this study, calcium silicate hydrate (C-S-H) is synthesized and characterized. C-S-H slurry was made with calcium oxide (CaO) to micro-silica (SiO{sub 2}) mixture ratio of 1.5 and enough deionized water. The slurry was continuously mixed for 7 days, then the excess water was removed. Two methods of drying were implemented: one method used the standard d-dry technique and the other was equilibrated to 11% relative humidity (RH). The dried powders were characterized using thermo gravimetric analysis (TGA), X-ray diffraction analysis (XRDA), and {sup 29}Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. The stoichiometric formulas of synthetic C-S-H powders dried to d-dry and 11% RH in this study were approximated as C{sub 1.2}SH{sub 0.7} and C{sub 1.2}SH{sub 2.4} respectively. The powders were then compacted to create specimens with porosities similar to C-S-H in hydrated cement. The specimens underwent nanoindentation to mechanically characterize C-S-H. The experiments provide insight on the nanoscale mechanical characteristics of C-S-H.

  5. CENTRIFUGAL MEMBRANE FILTRATION

    SciTech Connect (OSTI)

    William A. Greene; Patricia A. Kirk; Richard Hayes; Joshua Riley

    2005-10-28T23:59:59.000Z

    SpinTek Membrane Systems, Inc., the developer of a centrifugal membrane filtration technology, has engineered and developed a system for use within the U.S. Department of Energy (DOE) Environmental Management (EM) Program. The technology uses supported microporous membranes rotating at high rpm, under pressure, to separate suspended and colloidal solids from liquid streams, yielding a solids-free permeate stream and a highly concentrated solids stream. This is a crosscutting technology that falls under the Efficient Separations and Processing Crosscutting Program, with potential application to tank wastes, contaminated groundwater, landfill leachate, and secondary liquid waste streams from other remediation processes, including decontamination and decommissioning systems. SpinTek II High Shear Rotary Membrane Filtration System is a unique compact crossflow membrane system that has large, demonstrable advantages in performance and cost compared to currently available systems: (1) High fluid shear prevents membrane fouling even with very high solids content; hazardous and radioactive components can be concentrated to the consistency of a pasty slurry without fouling. (2) Induced turbulence and shear across the membrane increases membrane flux by a factor of ten over existing systems and allows operation on fluids not otherwise treatable. (3) Innovative ceramic membrane and mechanical sealing technology eliminates compatibility problems with aggressive DOE waste streams. (4) System design allows rapid, simple disassembly for inspection or complete decontamination. (5) Produces colloidal- and suspended-solids-free filtrate without the addition of chemicals. The first phase of this project (PRDA maturity stage 5) completed the physical scale-up of the SpinTek unit and verified successful scale-up with surrogate materials. Given successful scale-up and DOE concurrence, the second phase of this project (PRDA maturity stage 6) will provide for the installation and operation of the full-scale two-stage SpinTek unit for treatment of a DOE waste-stream at the Los Alamos National Laboratory. This technology has very broad application across the DOE system. Nineteen DOE technical needs areas (Appendix C) have been identified. Following successful full-scale demonstration for treatment of DOE wastes, this innovative technology will be rapidly deployed on a wide range of waste and process streams throughout the DOE system.

  6. General calculations using graphics hardware, with application to interactive caustics

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    General calculations using graphics hardware, with application to interactive caustics Chris Trendall and A. James Stewart iMAGIS­GRAVIR/IMAG and University of Toronto Abstract. Graphics hardware has general computation. This paper shows that graphics hardware can perform general calculations, which

  7. Experimental investigation of caustic steam injection for heavy oils 

    E-Print Network [OSTI]

    Madhavan, Rajiv

    2010-01-16T23:59:59.000Z

    An experimental study has been conducted to compare the effect of steam injection and caustic steam injection in improving the recovery of San Ardo and Duri heavy oils. A 67 cm long x 7.4 cm O.D (outer diameter), steel ...

  8. Economic Feasibility of Electrochemical Caustic Recycling at the Hanford Site

    SciTech Connect (OSTI)

    Poloski, Adam P.; Kurath, Dean E.; Holton, Langdon K.; Sevigny, Gary J.; Fountain, Matthew S.

    2009-03-01T23:59:59.000Z

    This report contains a review of potential cost benefits of NaSICON Ceramic membranes for the separation of sodium from Hanford tank waste. The primary application is for caustic recycle to the Waste Treatment and Immobilization Plant (WTP) pretreatment leaching operation. The report includes a description of the waste, the benefits and costs for a caustic-recycle facility, and Monte Carlo results obtained from a model of these costs and benefits. The use of existing cost information has been limited to publicly available sources. This study is intended to be an initial evaluation of the economic feasibility of a caustic recycle facility based on NaSICON technology. The current pretreatment flowsheet indicates that approximately 6,500 metric tons (MT) of Na will be added to the tank waste, primarily for removing Al from the high-level waste (HLW) sludge (Kirkbride et al. 2007). An assessment (Alexander et al. 2004) of the pretreatment flowsheet, equilibrium chemistry, and laboratory results indicates that the quantity of Na required for sludge leaching will increase by 6,000 to 12,000 MT in order to dissolve sufficient Al from the tank-waste sludge material to maintain the number of HLW canisters produced at 9,400 canisters as defined in the Office of River Protection (ORP) System Plan (Certa 2003). This additional Na will significantly increase the volume of LAW glass and extend the processing time of the Waste Treatment and Immobilization Plant (WTP). Future estimates on sodium requirements for caustic leaching are expected to significantly exceed the 12,000-MT value and approach 40,000-MT of total sodium addition for leaching (Gilbert, 2007). The cost benefit for caustic recycling is assumed to consist of four major contributions: 1) the cost savings realized by not producing additional immobilized low-activity waste (ILAW) glass, 2) caustic recycle capital investment, 3) caustic recycle operating and maintenance costs, and 4) research and technology costs needed to deploy the technology. In estimating costs for each of these components, several parameters are used as inputs. Due to uncertainty in assuming a singular value for each of these parameters, a range of possible values is assumed. A Monte Carlo simulation is then performed where the range of these parameters is exercised, and the resulting range of cost benefits is determined.

  9. Health Benefits of Particle Filtration

    SciTech Connect (OSTI)

    Fisk, William J.

    2013-10-01T23:59:59.000Z

    The evidence of health benefits of particle filtration in homes and commercial buildings is reviewed. Prior reviews of papers published before 2000 are summarized. The results of 16 more recent intervention studies are compiled and analyzed. Also, reviewed are four studies that modeled health benefits of using filtration to reduce indoor exposures to particles from outdoors. Prior reviews generally concluded that particle filtration is, at best, a source of small improvements in allergy and asthma health effects; however, many early studies had weak designs. A majority of recent intervention studies employed strong designs and more of these studies report statistically significant improvements in health symptoms or objective health outcomes, particularly for subjects with allergies or asthma. The percent age improvement in health outcomes is typically modest, for example, 7percent to 25percent. Delivery of filtered air to the breathing zone of sleeping allergic or asthmatic persons may be more consistently effective in improving health than room air filtration. Notable are two studies that report statistically significant improvements, with filtration, in markers that predict future adverse coronary events. From modeling, the largest potential benefits of indoor particle filtration may be reductions in morbidity and mortality from reducing indoor exposures to particles from outdoor air.

  10. Health Benefits of Particle Filtration

    SciTech Connect (OSTI)

    Fisk, William J.

    2013-10-01T23:59:59.000Z

    The evidence of health benefits of particle filtration in homes and commercial buildings is reviewed. Prior reviews of papers published before 2000 are summarized. The results of 16 more recent intervention studies are compiled and analyzed. Also reviewed are four studies that modeled health benefits of using filtration to reduce indoor exposures to particles from outdoors. Prior reviews generally concluded that particle filtration is, at best, a source of small improvements in allergy and asthma health effects; however, many early studies had weak designs. A majority of recent intervention studies employed strong designs and more of these studies report statistically significant improvements in health symptoms or objective health outcomes, particularly for subjects with allergies or asthma. The percentage improvement in health outcomes is typically modest, e.g., 7percent to 25percent. Delivery of filtered air to the breathing zone of sleeping allergic or asthmatic persons may be more consistently effective in improving health than room air filtration. Notable are two studies that report statistically significant improvements, with filtration, in markers that predict future adverse coronary events. From modeling, the largest potential benefits of indoor particle filtration may be reductions in morbidity and mortality from reducing indoor exposures to particles from outdoor air.

  11. Analysis of ray stability and caustic formation in a layered moving fluid medium

    E-Print Network [OSTI]

    Bergman, David R

    2015-01-01T23:59:59.000Z

    Caustic formation occurs within a ray skeleton as optical or acoustic fields propagate in a medium with variable refractive properties and are unphysical, their presence being an artifact of the ray approximation of the field, and methods of correcting the field near a caustic are well known. Differential geometry provides a novel approach to calculating acoustic intensity, assessing ray stability and locating caustics in acoustic ray traces when the properties of medium are completely arbitrary by identifying points on the caustic with conjugate points along various rays. The method of geodesic deviation is applied to the problem of determining ray stability and locating caustics in 2-dimensional acoustic ray traces in a layered moving medium. Specifically, a general treatment of caustic formation in sound ducts and in piecewise continuous media is presented and applied to various idealized and realistic scenarios.

  12. Integrated pore blockage-cake filtration model for crossflow filtration

    SciTech Connect (OSTI)

    Daniel, Richard C.; Billing, Justin M.; Russell, Renee L.; Shimskey, Rick W.; Smith, Harry D.; Peterson, Reid A.

    2011-07-01T23:59:59.000Z

    Crossflow filtration is to be a key process in the treatment and disposal of approximately 60,000 metric tons of high-level radioactive waste stored at the Hanford Site in Richland, Washington. Pacific Northwest National Laboratory is assessing filter performance with waste simulant materials that mimic the chemical and physical properties of Hanford tank waste. Prior simulant studies indicated that waste filtration performance may be limited by pore and cake fouling. To limit the shutdown of waste treatment operations, the pre-treatment facility plans to recover filter flux losses from cake formation and filter fouling by frequently backpulsing the filter elements. The objective of the current paper is to develop a simple model of flux decline resulting from cake and pore fouling and potential flux recovery through backpulsing of the filters for Hanford waste filtration operations. To this end, a model capable of characterizing the decline in waste-simulant filter flux as a function of both irreversible pore blockage and reversible cake formation is proposed. This model is used to characterize the filtration behavior of Hanford waste simulants in both continuous and backpulsed operations. The model is then used to infer the optimal backpulse frequency under specific operating conditions.

  13. Cross flow filtration of aqueous radioactive tank wastes

    SciTech Connect (OSTI)

    McCabe, D.J. [Westinghouse Savannah River Co., Aiken, SC (United States); Reynolds, B.A. [Battelle Pacific Northwest Lab., Richland, WA (United States); Todd, T.A. [Idaho National Engineering and Environmental Lab., Idaho Falls, ID (United States); Wilson, J.H. [Oak Ridge National Lab., TN (United States)

    1997-02-01T23:59:59.000Z

    The Tank Focus Area (TFA) of the Department of Energy (DOE) Office of Science and Technology addresses remediation of radioactive waste currently stored in underground tanks. Baseline technologies for treatment of tank waste can be categorized into three types of solid liquid separation: (a) removal of radioactive species that have been absorbed or precipitated, (b) pretreatment, and (c) volume reduction of sludge and wash water. Solids formed from precipitation or absorption of radioactive ions require separation from the liquid phase to permit treatment of the liquid as Low Level Waste. This basic process is used for decontamination of tank waste at the Savannah River Site (SRS). Ion exchange of radioactive ions has been proposed for other tank wastes, requiring removal of insoluble solids to prevent bed fouling and downstream contamination. Additionally, volume reduction of washed sludge solids would reduce the tank space required for interim storage of High Level Wastes. The scope of this multi-site task is to evaluate the solid/liquid separations needed to permit treatment of tank wastes to accomplish these goals. Testing has emphasized cross now filtration with metal filters to pretreat tank wastes, due to tolerance of radiation and caustic.

  14. Filtration Understanding: FY10 Testing Results and Filtration Model Update

    SciTech Connect (OSTI)

    Daniel, Richard C.; Billing, Justin M.; Burns, Carolyn A.; Peterson, Reid A.; Russell, Renee L.; Schonewill, Philip P.; Shimskey, Rick W.

    2011-04-04T23:59:59.000Z

    This document completes the requirements of Milestone 2-4, Final Report of FY10 Testing, discussed in the scope of work outlined in the EM31 task plan WP-2.3.6-2010-1. The focus of task WP 2.3.6 is to improve the U.S. Department of Energy’s (DOE’s) understanding of filtration operations for high-level waste (HLW) to improve filtration and cleaning efficiencies, thereby increasing process throughput and reducing the Na demand (through acid neutralization). Developing the cleaning/backpulsing requirements will produce much more efficient operations for both the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and the Savannah River Site (SRS), thereby significantly increasing throughput by limiting cleaning cycles. The scope of this work is to develop the understanding of filter fouling to allow developing this cleaning/backpulsing strategy.

  15. Caustic Crossing Microlensing Event by Binary MACHOs and Time Scale Bias

    E-Print Network [OSTI]

    Mareki Honma

    1998-11-25T23:59:59.000Z

    Caustic crossing microlensing events provide us a unique opportunity to measure the relative proper motion of the lens to the source, and so those caused by binary MACHOs are of great importance for understanding the structure of the Galactic halo and the nature of MACHOs. The microlensing event 98-SMC-01, occurred in June 1998, is the first event for which the proper motion is ever measured through the caustic crossing, and this event may be caused by binary MACHOs as we argue in this Letter. Motivated by the possible existence of binary MACHOs, we have performed the Monte Carlo simulations of caustic crossing events by binary MACHOs and investigated the properties and detectability of the events. Our calculation shows that typical caustic crossing events have the interval between two caustic crossings ($t_{\\rm cc}$) of about 5 days. We argue that with the current strategy of binary event search the proper motions of these typical events are not measurable because of the short time scale. Therefore the proper motion distribution measured from caustic crossing events suffers significantly from {`}time scale bias{'}, which is a bias toward finding long time scale events and hence slowly moving lenses. We predict there are two times more short time scale events ($t_{\\rm cc}\\le 10$ days) than long time scale events ($t_{\\rm cc}\\ge 10$ days), and propose an hourly monitoring observation instead of the nightly monitoring currently undertaken to detect caustic crossing events by binary MACHOs more efficiently.

  16. Caustic Crossing in the Gravitational Lens Q2237+0305

    E-Print Network [OSTI]

    V. N. Shalyapin

    2001-02-22T23:59:59.000Z

    The monitoring of the gravitational lens Q2237+0305 carried out by the OGLE group during 1997--1999 is analyzed. The significant light amplifications in the C and A quasar components with maxima in mid- and late 1999, respectively, are interpreted as the crossing of microlens caustics by the source. A constraint on the emitting-region size R < 10^(15) cm has been obtained from the light-curve shape by assuming a power-law quasar brightness distribution (r^2+R^2)^(-p). To estimate the exponent p ~ 1.2 requires refining the standard model for the quasar continuum formation in an optically thick accretion disk with p = 1.5

  17. On calculation of microlensing light curve by gravitational lens caustic

    E-Print Network [OSTI]

    M. B. Bogdanov

    2001-02-02T23:59:59.000Z

    For an analysis of microlensing observational data in case of binary gravitational lenses as well as for an interpretation of observations of high magnification events in multiple images of a lensed quasar it is necessary to calculate for a given source the microlensing light curve by a fold caustic. This problem comes to the numerical calculation of a singular integral. We formulated the sufficient condition of a convergence of the integral sum for this singular integral. The strictly approach to the problem of a comparison of model results with the unequally sampled observational data consists in calculation of the model light curve in equidistant points of the canonical dissection of the integration segment and a following interpolation of its values at the moments of observations.

  18. Design and Economic Evaluation of Thermionic Cogeneration in a Chlorine-Caustic Plant 

    E-Print Network [OSTI]

    Miskolezy, G.; Morgan, D.; Turner, R.

    1985-01-01T23:59:59.000Z

    The study shows that it is feasible to equip a chlorine-caustic plant with thermionic cogeneration. Thermionic combustors replace the existing burners of the boilers used to raise steam for the evaporators, and are capable of generating...

  19. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Broader source: Energy.gov (indexed) [DOE]

    Diesel Particulate Filtration (DPF) Technology: Success stories at the High Temperature Materials Laboratory (HTML) User Program Dr. Amit Shyam, ORNL Sponsored by U.S. Department...

  20. Diesel Particulate Filtration (DPF) Technology: Success stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Success stories at the High Temperature Materials Laboratory (HTML) User Program Diesel Particulate Filtration (DPF) Technology: Success stories at the High Temperature...

  1. Particulate Emissions Control by Advanced Filtration Systems...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Filtration Systems for GDI Engines (ANLCorningHyundai CRADA) June 19, 2014 DOE Annual Merit Review & Peer Evaluation Meeting PI: Kyeong Lee Co-investigators: Seung Choi,...

  2. Particulate Emissions Control by Advanced Filtration Systems...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Filtration Systems for GDI Engines (ANLCorningHyundai CRADA) May 15, 2013 DOE Annual Merit Review & Peer Evaluation Meeting PI: Kyeong Lee Postdocs: Seung Choi, Heeje...

  3. CFD Analysis of Particle Deposition During DPF Filtration Processes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deposition During DPF Filtration Processes A 3-D DPF model is developed to predict thermo-physical properties during filtration processes and to quantitatively investigate...

  4. Evaluation of Side Stream Filtration Technology at Oak Ridge...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ssfevaluation.pdf More Documents & Publications Side Stream Filtration for Cooling Towers Technical Evaluation of Side Stream Filtration for Cooling Towers Cooling Towers:...

  5. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Broader source: Energy.gov (indexed) [DOE]

    Filtration (DPF) Systems Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) February 26, 2008 DOE Merit Review PI: Kyeong Lee (Postdoc: Joe Song) Transportation...

  6. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA)...

  7. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of...

  8. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Broader source: Energy.gov (indexed) [DOE]

    Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) Development of Advanced Particulate Filters...

  9. Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency Studies Using Laboratory Generated Particles. Single Wall Diesel Particulate Filter (DPF) Filtration Efficiency...

  10. Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, Caustic Wash Tank And Caustic Storage Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 6 Operations

    SciTech Connect (OSTI)

    Peters, T. B.

    2014-01-02T23:59:59.000Z

    Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Caustic Storage Tank (CST) samples from the Interim Salt Disposition Project (ISDP) Salt Batch (“Macrobatch”) 6 have been analyzed for 238Pu, 90Sr, 137Cs, and by Inductively Coupled Plasma Emission Spectroscopy (ICPES). The Pu, Sr, and Cs results from the current Macrobatch 6 samples are similar to those from comparable samples in previous Macrobatch 5. In addition the SEHT and DSSHT heel samples (i.e. ‘preliminary’) have been analyzed and reported to meet NGS Demonstration Plan requirements. From a bulk chemical point of view, the ICPES results do not vary considerably between this and the previous samples. The titanium results in the DSSHT samples continue to indicate the presence of Ti, when the feed material does not have detectable levels. This most likely indicates that leaching of Ti from MST has increased in ARP at the higher free hydroxide concentrations in the current feed.

  11. Linear Thermodynamics of Rodlike DNA Filtration

    E-Print Network [OSTI]

    Li, Zirui

    Linear thermodynamics transportation theory is employed to study filtration of rodlike DNA molecules. Using the repeated nanoarray consisting of alternate deep and shallow regions, it is demonstrated that the complex ...

  12. PERFORMANCE IMPROVEMENT OF CROSS-FLOW FILTRATION FOR HIGH LEVEL WASTE TREATMENT

    SciTech Connect (OSTI)

    Duignan, M.; Nash, C.; Poirier, M.

    2011-01-12T23:59:59.000Z

    In the interest of accelerating waste treatment processing, the DOE has funded studies to better understand filtration with the goal of improving filter fluxes in existing cross-flow equipment. The Savannah River National Laboratory (SRNL) was included in those studies, with a focus on start-up techniques, filter cake development, the application of filter aids (cake forming solid precoats), and body feeds (flux enhancing polymers). This paper discusses the progress of those filter studies. Cross-flow filtration is a key process step in many operating and planned waste treatment facilities to separate undissolved solids from supernate slurries. This separation technology generally has the advantage of self-cleaning through the action of wall shear stress created by the flow of waste slurry through the filter tubes. However, the ability of filter wall self-cleaning depends on the slurry being filtered. Many of the alkaline radioactive wastes are extremely challenging to filtration, e.g., those containing compounds of aluminum and iron, which have particles whose size and morphology reduce permeability. Unfortunately, low filter flux can be a bottleneck in waste processing facilities such as the Savannah River Modular Caustic Side Solvent Extraction Unit and the Hanford Waste Treatment Plant. Any improvement to the filtration rate would lead directly to increased throughput of the entire process. To date increased rates are generally realized by either increasing the cross-flow filter axial flowrate, limited by pump capacity, or by increasing filter surface area, limited by space and increasing the required pump load. SRNL set up both dead-end and cross-flow filter tests to better understand filter performance based on filter media structure, flow conditions, filter cleaning, and several different types of filter aids and body feeds. Using non-radioactive simulated wastes, both chemically and physically similar to the actual radioactive wastes, the authors performed several tests to demonstrate increases in filter performance. With the proper use of filter flow conditions and filter enhancers, filter flow rates can be increased over rates currently realized today.

  13. ORNL/TM-2008/073 CAUSTIC-SIDE SOLVENT-EXTRACTION

    E-Print Network [OSTI]

    Pennycook, Steve

    .S. Department of Energy (DOE) Information Bridge: Web site: http://www.osti.gov/bridge Reports produced before) representatives, and International Nuclear Information System (INIS) representatives from the following sourceORNL/TM-2008/073 CAUSTIC-SIDE SOLVENT-EXTRACTION MODELING FOR HANFORD INTERIM PRETREATMENT SYSTEM

  14. Structural evaluation of mixer pump installed in Tank 241-AN-107 for caustic addition project

    SciTech Connect (OSTI)

    Leshikar, G.A.

    1995-06-16T23:59:59.000Z

    This report documents the structural analysis and evaluation of a mixer pump and caustic addition system to be used in Tank 107-AN. This pump will be installed in the central pump pit of this double- shell tank for the purpose of bringing the hydroxide ion concentration into compliance with Tank Farm operating specifications.

  15. Safety basis for the 241-AN-107 mixer pump installation and caustic addition

    SciTech Connect (OSTI)

    Van Vleet, R.J. [Westinghouse Hanford Co., Richland, WA (United States)

    1994-10-05T23:59:59.000Z

    This safety Basis was prepared to determine whether or not the proposed activities of installing a 76 HP jet mixer pump and the addition of approximately 50,000 gallons of 19 M (50:50 wt %) aqueous caustic are within the safety envelope as described by Tank Farms (chapter six of WHC-SD-WM-ISB-001, Rev. 0). The safety basis covers the components, structures and systems for the caustic addition and mixer pump installation. These include: installation of the mixer pump and monitoring equipment; operation of the mixer pump, process monitoring equipment and caustic addition; the pump stand, caustic addition skid, the electrical skid, the video camera system and the two densitometers. Also covered is the removal and decontamination of the mixer pump and process monitoring system. Authority for this safety basis is WHC-IP-0842 (Waste Tank Administration). Section 15.9, Rev. 2 (Unreviewed Safety Questions) of WHC-IP-0842 requires that an evaluation be performed for all physical modifications.

  16. Chemical cleaning of coal by molten caustic leaching after pretreatment by low-temperature devolatilization

    DOE Patents [OSTI]

    Chriswell, Colin D. (Slater, IA); Kaushik, Surender M. (Socorro, NM); Shah, Navin D. (Houston, TX); Markuszewski, Richard (Ames, IA)

    1989-08-22T23:59:59.000Z

    Pretreatment of coal by devolatization at temperatures ranging from about 420.degree. C. to about 450.degree. C. for from about 10 minutes to about 30 minutes before leaching with molten caustic leads to a significant reduction in carbonate formation, greatly reducing the cost of cleaning coal on a per ton basis.

  17. A GEOCHEMICAL MODULE FOR "AMDTreat" TO COMPUTE CAUSTIC QUANTITY, EFFLUENT QUALITY, AND SLUDGE VOLUME1

    E-Print Network [OSTI]

    of sludge produced by the treatment, a titration simulation is being developed using the geochemical program The AMDTreat computer program ( . Treatment with caustic chemicals typically is used to increase pH (6 to 8), whereas active manganese removal requires treatment to alkaline pH (~10). The treatment

  18. An alternative parameterisation for binary-lens caustic-crossing events

    E-Print Network [OSTI]

    A. Cassan

    2008-10-15T23:59:59.000Z

    Microlensing events are being discovered and alerted by the two survey teams OGLE and MOA at an increasing rate. Around ten percent of these events involve binary lenses. Such events potentially contain much information on the physical properties of the observed binary systems, which can then be used for e.g. statistical studies on binary objects in the Galactic disk or bulge. However, such events are usually not straightforward to study, because the model equations are strongly non-linear and there are many local minima that can fool the search for the best solution if the parameter space is not inspected with great care. In this work an alternative parameterisation for the binary lens fitting problem is proposed, in which the parameters involved are defined to represent as closely as possible the caustic-crossing features observed in most binary lens light curves. Furthermore, we work out an extension of the method in order to make use of the straight line fold caustic approximation, when the latter applies for both the caustic entry and exit. We introduce an alternative parameterisation in order to confine the exploration of the parameter space to regions where the models only involve caustic crossing at the dates seen in the light curve. We find that the proposed parameterisation provides more robustness to the light curve fitting process, in particular in avoiding a code to get stuck in false minima.

  19. Formation of zeolite during caustic dissolution of fiberglass; Implications for studies of the kaolinite-to-mullite transformation

    SciTech Connect (OSTI)

    Jantzen, C.M. (Westinghouse Savannah River Co., Aiken, SC (United States))

    1990-12-01T23:59:59.000Z

    This paper reports on insoluble zeolitic reaction products formed during the caustic dissolution of fiberglass filters. The zeolite that forms in Linde B{sub 1}, the higher temperature form of the zeolite identified during caustic dissolution of free SiO{sub 2} in kaolinite-to-mullite transformations. The Linde B{sub 1} is a sodium aluminosilicate hydrate that preferentially incorporates Ca{sup 2+} and Mg{sup 2+}. Formation of the Linde B{sub 1} zeolite from fiberglass dissolution in NaOH indicates that caustic dissolution of kaolinite does not preferentially dissolve free amorphous SiO{sub 2}, but dissolves any multicomponent amorphous phase present.

  20. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02T23:59:59.000Z

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

  1. Caustic Recycling Pilot Unit to Separate Sodium from LLW at Hanford Site - 12279

    SciTech Connect (OSTI)

    Pendleton, Justin; Bhavaraju, Sai; Priday, George; Desai, Aditya; Duffey, Kean; Balagopal, Shekar [Ceramatec Inc., Salt Lake City, UT 84119 (United States)

    2012-07-01T23:59:59.000Z

    As part of the Department of Energy (DOE) sponsored Advanced Remediation Technologies initiative, a scheme was developed to combine Continuous Sludge Leaching (CSL), Near-Tank Cesium Removal (NTCR), and Caustic Recycling Unit (CRU) using Ceramatec technology, into a single system known as the Pilot Near-Tank Treatment System (PNTTS). The Cesium (Cs) decontaminated effluent from the NTCR process will be sent to the caustic recycle process for recovery of the caustic which will be reused in another cycle of caustic leaching in the CSL process. Such an integrated mobile technology demonstration will give DOE the option to insert this process for sodium management at various sites in Hanford, and will minimize the addition of further sodium into the waste tanks. This allows for recycling of the caustic used to remove aluminum during sludge washing as a pretreatment step in the vitrification of radioactive waste which will decrease the Low Level Waste (LLW) volume by as much as 39%. The CRU pilot process was designed to recycle sodium in the form of pure sodium hydroxide. The basis for the design of the 1/4 scale pilot caustic recycling unit was to demonstrate the efficient operation of a larger scale system to recycle caustic from the NTCR effluent stream from the Parsons process. The CRU was designed to process 0.28 liter/minute of NTCR effluent, and generate 10 M concentration of 'usable' sodium hydroxide. The proposed process operates at 40 deg. C to provide additional aluminum solubility and then recover the sodium hydroxide to the point where the aluminum is saturated at 40 deg. C. A system was developed to safely separate and vent the gases generated during operation of the CRU with the production of 10 M sodium hydroxide. Caustic was produced at a rate between 1.9 to 9.3 kg/hr. The CRU was located inside an ISO container to allow for moving of the unit close to tank locations to process the LLW stream. Actual tests were conducted with the NTCR effluent simulant from the Parsons process in the CRU. The modular CRU is easily scalable as a standalone system for caustic recycling, or for NTTS integration or for use as an In-Tank Treatment System to process sodium bearing waste to meet LLW processing needs at the Hanford site. The standalone pilot operation of the CRU to recycle sodium from NTCR effluent places the technology demonstration at TRL level 6. Multiple operations were performed with the CRU to process up to 500 gallons of the NTCR effluent and demonstrate an efficient separation of up to 70 % of the sodium without solids precipitation while producing 10 M caustic. Batch mode operation was conducted to study the effects of chemistry variation, establish the processing rate, and optimize the process operating conditions to recycle caustic from the NTCR effluent. The performance of the CRU was monitored by tracking the density parameter to control the concentration of caustic produced. Different levels of sodium were separated in tests from the effluent at a fixed operating current density and temperature. The voltage of the modules remained stable during the unit operation which demonstrated steady operation to separate sodium from the NTCR effluent. The sodium transfer current efficiency was measured in testing based on the concentration of caustic produced. Measurements showed a current efficiency of 99.8% for sodium transfer from the NTCR effluent to make sodium hydroxide. The sodium and hydroxide contents of the anolyte (NTCR feed) and catholyte (caustic product) were measured before and after each batch test. In two separate batch tests, samples were taken at different levels of sodium separation and analyzed to determine the stability of the NTCR effluent after sodium separation. The stability characteristics and changes in physical and chemical properties of the NTCR effluent chemistry after separation of sodium hydroxide as a function of storage time were evaluated. Parameters such as level of precipitated alumina, total alkalinity, analysis of Al, Na, K, Cs, Fe, OH, nitrate, nitrite, total dissolved and

  2. Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, Caustic Wash Tank And Caustic Storage Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 6 Operations

    SciTech Connect (OSTI)

    Peters, T. B.

    2013-10-01T23:59:59.000Z

    Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Caustic Storage Tank (CST) samples from several of the ''microbatches'' of Integrated Salt Disposition Project (ISDP) Salt Batch (''Macrobatch'') 6 have been analyzed for {sup 238}Pu, {sup 90}Sr, {sup 137}Cs, and by Inductively Coupled Plasma Emission Spectroscopy (ICPES). The results from the current microbatch samples are similar to those from comparable samples in Macrobatch 5. From a bulk chemical point of view, the ICPES results do not vary considerably between this and the previous macrobatch. The titanium results in the DSSHT samples continue to indicate the presence of Ti, when the feed material does not have detectable levels. This most likely indicates that leaching of Ti from MST in ARP continues to occur. Both the CST and CWT samples indicate that the target Free OH value of 0.03 has been surpassed. While at this time there is no indication that this has caused an operational problem, the CST should be adjusted into specification. The {sup 137}Cs results from the SRNL as well as F/H lab data indicate a potential decline in cesium decontamination factor. Further samples will be carefully monitored to investigate this.

  3. Plasma discharge self-cleaning filtration system

    DOE Patents [OSTI]

    Cho, Young I.; Fridman, Alexander; Gutsol, Alexander F.; Yang, Yong

    2014-07-22T23:59:59.000Z

    The present invention is directed to a novel method for cleaning a filter surface using a plasma discharge self-cleaning filtration system. The method involves utilizing plasma discharges to induce short electric pulses of nanoseconds duration at high voltages. These electrical pulses generate strong Shockwaves that disintegrate and dislodge particulate matter located on the surface of the filter.

  4. Washing and caustic leaching of Hanford tank sludge: Results of FY 1997 studies

    SciTech Connect (OSTI)

    Lumetta, G.J.; Burgeson, I.E.; Wagner, M.J.; Liu, J.; Chen, Y.L.

    1997-08-01T23:59:59.000Z

    The current plan for remediating the Hanford tank farms consists of waste retrieval, pretreatment, treatment (immobilization), and disposal. The tank wastes will be partitioned into high-level and low-level fractions. The HLW will be immobilized in a borosilicate glass matrix; the resulting glass canisters will then be disposed of in a geologic repository. Because of the expected high cost of HLW vitrification and geologic disposal, pretreatment processes will be implemented to reduce the volume of immobilized high-level waste (IHLW). Caustic leaching (sometimes referred to as enhanced sludge washing or ESW) represents the baseline method for pretreating Hanford tank sludges. Caustic leaching is expected to remove a large fraction of the Al, which is present in large quantities in Hanford tank sludges. A significant portion of the P is also expected to be removed from the sludge by metathesis of water-insoluble metal phosphates to insoluble hydroxides and soluble Na{sub 3}PO{sub 4}. Similar metathesis reactions can occur for insoluble sulfate salts, allowing the removal of sulfate from the HLW stream. This report describes the sludge washing and caustic leaching tests performed at the Pacific Northwest National Laboratory in FY 1996. The sludges used in this study were taken from Hanford tanks AN-104, BY-108, S-101, and S-111.

  5. Water filtration optimization by geometric programming

    E-Print Network [OSTI]

    Wray, Duane Jimmy

    1970-01-01T23:59:59.000Z

    important as a means of removing suspended and colloidal matter. Sand is the most commonly used filter media but is rapidly being replaced by a combination of anthracite, sand, and garnet for faster filtration rates. Due to the complexity... of the filtering process, the design of these filters has remained an art without ever progressing to a science. Filters are in general designed from experience and rules of thumb without any assurance that maximum efficiency is attained at minimum cost. A...

  6. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    SciTech Connect (OSTI)

    Adriaan van Heiningen

    2007-06-30T23:59:59.000Z

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

  7. Demand Controlled Filtration in an Industrial Cleanroom

    SciTech Connect (OSTI)

    Faulkner, David; DiBartolomeo, Dennis; Wang, Duo

    2007-09-01T23:59:59.000Z

    In an industrial cleanroom, significant energy savings were realized by implementing two types of demand controlled filtration (DCF) strategies, one based on particle counts and one on occupancy. With each strategy the speed of the recirculation fan filter units was reduced to save energy. When the control was based on particle counts, the energy use was 60% of the baseline configuration of continuous fan operation. With simple occupancy sensors, the energy usage was 63% of the baseline configuration. During the testing of DCF, no complaints were registered by the operator of the cleanroom concerning processes and products being affected by the DCF implementation.

  8. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ANLCorningCaterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANLCorningCaterpillar CRADA) ace22lee.pdf More Documents & Publications...

  9. Development of Model Filtration Media for Investigating Size...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency A novel method for fabricating custom porous filtration media for emission control has been developed. Controlled pore sizes could be used to optimize...

  10. P-Area Acid/Caustic Basin groundwater monitoring report. First quarter 1993

    SciTech Connect (OSTI)

    Not Available

    1993-06-01T23:59:59.000Z

    During first quarter 1993, samples from the six PAC monitoring wells at the P-Area Acid/Caustic Basin were analyzed for indicator parameters, groundwater quality parameters, and parameters characterizing suitability as a drinking water supply. Monitoring results that exceeded the final Primary Drinking Water Standards (PDWS) or the Savannah River Site (SRS) flagging criteria or turbidity standard during the quarter are discussed in this report. During first quarter 1993, no constituents exceeded the final PDWS. Aluminum exceeded the SRS Flag 2 criterion in four of the wells. Iron and manganese each exceeded its Flag 2 criterion in wells PAC 2, 5, and 6.

  11. CAUSTIC SIDE SOLVENT EXTRACTION AT THE SAVANNAH RIVER SITE OPERATING EXPERIENCE AND LESSONS LEARNED

    SciTech Connect (OSTI)

    Brown, S.

    2010-01-06T23:59:59.000Z

    The Modular Caustic-Side Solvent Extraction Unit (MCU) is the first, production-scale Caustic-Side Solvent Extraction process for cesium separation to be constructed. The process utilizes an engineered solvent to remove cesium from waste alkaline salt solution resulting from nuclear processes. While the application of this solvent extraction process is unique, the process uses commercially available centrifugal contactors for the primary unit operation as well as other common methods of physical separation of immiscible liquids. The fission product, cesium-137, is the primary focus of the process due to the hazards associated with its decay. The cesium is extracted from the waste, concentrated, and stripped out of the solvent resulting in a low-level waste salt solution and a concentrated cesium nitrate stream. The concentrated cesium stream can be vitrified into borosilicate glass with almost no increase in glass volume, and the salt solution can be dispositioned as a low-level grout. The unit is deployed as an interim process to disposition waste prior to start-up of the Salt Waste Processing Facility. The Salt Waste Processing Facility utilizes the same cesium removal technology, but will treat more contaminated waste. The MCU is not only fulfilling a critical need, it is the first demonstration of the process at production-scale.

  12. F-Area Acid/Caustic Basin groundwater monitoring report. Second quarter 1995

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    During second quarter 1995, samples from the FAC monitoring wells at the F-Area Acid/Caustic Basin were collected and analyzed for herbicides/pesticides, indicator parameters, metals, nitrate, radionuclide indicators, volatile organic compounds, and other constituents. Piezometer FAC 5P and monitoring well FAC 6 were dry and could not be sampled. New monitoring wells FAC 9C, 10C, 11C, and 12C were completed in the Barnwell/McBean aquifer and were sampled for the first time during third quarter 1994 (second quarter 1995 is the fourth of four quarters of data required to support the closure of the basin). Analytical results that exceeded final Primary Drinking Water Standards (PDWS) or Savannah River Site (SRS) Flag 2 criteria such as the SRS turbidity standard of 50 NTU during the quarter were as follows: gross alpha exceeded the final PDWS and aluminum, iron, manganese, and radium-226 exceeded the SRS Flag 2 criteria in one or more of the FAC wells. Turbidity exceeded the SRS standard (50 NTU) in well FAC 3. Groundwater flow direction in the water table beneath the F-Area Acid/Caustic Basin was to the west at a rate of 1300 feet per year. Groundwater flow in the Barnwell/McBean was to the northeast at a rate of 50 feet per year.

  13. MODELING AND CONTROL OF A CONTINUOUS BIOREACTOR WITH CROSSFLOW FILTRATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MODELING AND CONTROL OF A CONTINUOUS BIOREACTOR WITH CROSS­FLOW FILTRATION Ying Zhao and Sigurd on an industrial application of a continuous bioreactor with cross­flow filtration. In this paper the general study the possibility of partial control of this bioreactor. keywords: Continuous bioreactor

  14. Water Modeling of Steel Flow, Air Entrainment and Filtration

    E-Print Network [OSTI]

    Beckermann, Christoph

    Water Modeling of Steel Flow, Air Entrainment and Filtration Christoph Beckermann Associate Beckermann, C., "Water Modeling of Steel Flow, Air Entrainment and Filtration," in Proceedings of the 46th, 1992. #12;Abstract This paper presents an analysis of water modeling of steel pouring to study (1) air

  15. Flexographic Newspaper Deinking: Treatment of Wash Filtrate Effluent

    E-Print Network [OSTI]

    Abubakr, Said

    Flexographic Newspaper Deinking: Treatment of Wash Filtrate Effluent by Membrane Technology B une meilleure qualité d'eau comparativementaux essaisdefloculation Jar-Test. INTRODUCTION Water of filtrate are produced by wash- JOURNAL OF PULP AND PAPER SCIENCE: VOL. 25 NO. 10OCTOBER 1999 ing which

  16. Household scale slow sand filtration in the Dominican Republic

    E-Print Network [OSTI]

    Donison, Kori S. (Kori Shay), 1981-

    2004-01-01T23:59:59.000Z

    Slow sand filtration is a method of water treatment that has been used for hundreds of years. In the past two decades, there has been resurgence in interest in slow sand filtration, particularly as a low-cost, household-scale ...

  17. Hierarchical analysis of filtration. Progress report

    SciTech Connect (OSTI)

    Quintard, M. [Ecole Nationale Superieure des Arts et Metiers, 33 - Talence (France). Lab. Energetique et Phenomenes de Transfert; Whitaker, S. [California Univ., Davis, CA (United States). Dept. of Chemical Engineering

    1993-07-01T23:59:59.000Z

    The original proposal for this work suggested two lines Of analysis that could be used to develop an hierarchical analysis of filtration. The first of these was semi-empirical and required the use of an angle-dependent rate coefficient to model the effect of particle inertia, while the second made use of a particle velocity decomposition that separated the velocity into an inertial part and a diffusive part. We have concluded that the semiempirical approach cannot lead to an efficient treatment of the filtration problem, and in this study we have dirrcted most of our effort toward the development of the velocity decomposition approach. Problems arise with the velocity decomposition method because the panicle tracking equation is hyperbolic in nature, and there are regions in the flow field where it is difficult to calculate the deterministic particle velocity. These problems can be avoided with an asymptotic analysis, and we have used this approach to determine single fiber efficiencies for small Stokes numbers. These efficiencies illustrate a minimum as a function of the particle diameter; however, the range of validity (in terms of the Stokes number) of the asymptotic method is uncertain. If the range of validity of the asymptotic expansion is suitable for the solution of practical problems, the current work on homogeneous filters should be expanded to included a broader range of values of the key parameters and then extended to include the case of heterogeneous filters. If the range of validity of the asymptotic method is not suitable for the solution of practical problems, the particle tracking problem must be resolved or we must move on to the use of Brownian dynamics. This approach is outlined, where we have indicated how Brownian dynamics may be incorporated into the method of volume averaging.

  18. Characterization of the Dynamics in the Protonic Conductor CsH2PO4 by 17O Solid-State NMR Spectroscopy and First-Principles Calculations: Correlating Phosphate and Protonic Motion

    E-Print Network [OSTI]

    Kim, Gunwoo; Griffin, John M.; Blanc, Frédéric; Haile, Sossina M.; Grey, Claire P.

    2015-03-03T23:59:59.000Z

    promising class of proton-conducting solid electrolytes for use in fuel cells that operate in an intermediate-temperature range (200 - 600 ºC).1-4 In particular, CsH2PO4, has been intensively studied because of its desirable operating temperature (230 – 260... of the adjacent O3 oxygen atoms (see Figure 1). This O-H separation was based upon the O1-H1 covalent bond length in the X-ray structure.15 Prior to calculation of the NMR parameters, all structures were fully geometry-optimized, with the unit cell parameters...

  19. THE CHEMICAL AND RADIATION RESISTANCE OF POLYPHENYLENE SULFIIDE AS ENCOUNTERED IN THE MODULAR CAUSTIC SIDE SOLVENT EXTRACTION PROCESSES

    SciTech Connect (OSTI)

    Fondeur, F.; Herman, D.; Poirier, M.; Fink, S.

    2011-06-30T23:59:59.000Z

    Polyphenylene sulfide (PPS) is a semicrystalline polymer with excellent engineering plastic properties and suitable processing temperatures. PPS can also be made containing branches (using a trifunctional monomer) and with crosslinked microstructure (when curing the monomer at high temperature in the presence of oxygen). PPS is made from the condensation reaction between para-dichlorobenzene and sodium sulfide with the assistance of a catalyst (to lower the activation barrier). The synthesis conditions for making PPS has evolved since its invention in the 1960's to the optimal conditions developed by the Philips Corporation in the 1970's. The resulting polymer consists of chemically stable molecular moieties such as benzene rings and ether like sulfur linkages between the aromatic rings. Polyphenylene sulfide (PPS) is extremely resistant to gamma irradiation, caustic solution, and dilute nitric acid. PPS is the material of construction for the coalescers used in the Modular Caustic-Side Solvent Extraction Unit (MCU). After applying the equivalent of 3.3 E8 rad (330 Mrad), or the equivalent of 11 years of gamma irradiation (assuming a stripping solution concentration of 7.5 Ci/gal), and several months of exposures to 3M caustic solution and caustic salt simulant, no dimensional changes nor chemical changes were detected in PPS whether the PPS was in fiber form or in a composite with E-glass fibers. However, PPS acts as a media for heterogeneous nucleation. In particular, PPS appears to favor aluminosilicate formation in saturated solutions of aluminum and silicon in caustic environments. Parallel testing, in progress, is examining the stability of PPS when exposed to the new solvent formulation under development for MCU. Preliminary data, after two months of exposure, demonstrates PPS is stable to the new solvent.

  20. Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System - 1997 Notice of Violation Consent Order

    SciTech Connect (OSTI)

    Evans, S.K.

    2002-01-31T23:59:59.000Z

    This Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System is one of two documents that comprise the Sampling and Analysis Plan for the HWMA/RCRA closure certification of the TRA-731 caustic and acid storage tank system at the Idaho National Engineering and Environmental Laboratory. This plan, which provides information about sampling design, required analyses, and sample collection and handling procedures, is to be used in conjunction with the Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System.

  1. Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System - 1997 Notice of Violation Consent Order

    SciTech Connect (OSTI)

    Evans, Susan Kay; Orchard, B. J.

    2002-01-01T23:59:59.000Z

    This Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System is one of two documents that comprise the Sampling and Analysis Plan for the HWMA/RCRA closure certification of the TRA-731 caustic and acid storage tank system at the Idaho National Engineering and Environmental Laboratory. This plan, which provides information about sampling design, required analyses, and sample collection and handling procedures, is to be used in conjunction with the Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System.

  2. Schwarz, T. and Wells, S. (1999) "Storm Water Particle Removal using Cross-Flow Filtration and Sedimentation," in Advances in Filtration and Separation Technology, Volume 12, ed. by W. Leung, American Filtrations and Separations Society, pp.219-226.

    E-Print Network [OSTI]

    Wells, Scott A.

    and Sedimentation," in Advances in Filtration and Separation Technology, Volume 12, ed. by W. Leung, American Filtrations and Separations Society, pp.219-226. CONTINUOUS DEFLECTION SEPARATION OF STORMWATER PARTICULATES

  3. Simulation of filtration for suspension transport in porous media

    E-Print Network [OSTI]

    Kim, Yun Sung, 1974-

    2005-01-01T23:59:59.000Z

    This thesis describes the development and application of a novel method for analyzing the filtration of particles transported through a granular porous medium. The proposed analysis considers the deposition of particles ...

  4. Improved filtration membranes through self-organizing amphiphilic comb copolymers

    E-Print Network [OSTI]

    Asatekin Alexiou, Ayse

    2009-01-01T23:59:59.000Z

    The operating cost of a membrane filtration system is generally determined by two major factors: the permeability of the membrane to water, and the lifetime of the membrane. Both of these are strongly affected by the ...

  5. Size-Dependent Filtration of Non-Loaded Particulate Traps

    E-Print Network [OSTI]

    White, Jessica

    2014-12-12T23:59:59.000Z

    This work investigates the filtration efficiency of uncoated, commercial Diesel Particulate Filter (DPF) substrates of three porosities (55.8%, 61.1%, 65.0%) for particulate sizes representative of Gasoline Direct Injection (GDI) exhaust, and also...

  6. Experiments concerning the dynamic filtration of drilling mud

    E-Print Network [OSTI]

    Eller, John Gary

    1989-01-01T23:59:59.000Z

    EXPERIMENTS CONCERNING THE DYNAMIC FILTRATION OF DRILLING MUD A Thesis by JOHN GARY ELLER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May... 1989 Major Subject: Petroleum Engineering EXPERIMENTS CONCERNING THE DYNAMIC FILTRATION OF DRILLING MUD A Thesis by JOHN GARY ELLER Approved as to style and content by: Hans C. Ju am-Wold (Chair of Committee) tephen A. Holditch (Member) Ted...

  7. Water Clarity Simulant for K East Basin Filtration Testing

    SciTech Connect (OSTI)

    Schmidt, Andrew J.

    2006-01-20T23:59:59.000Z

    This document provides a simulant formulation intended to mimic the behavior of the suspended solids in the K East (KE) Basin fuel storage pool. The simulant will be used to evaluate alternative filtration apparatus to improve Basin water clarity and to possibly replace the existing sandfilter. The simulant was formulated based on the simulant objectives, the key identified parameters important to filtration, the composition and character of the KE Basin suspended sludge particles, and consideration of properties of surrogate materials.

  8. PEP Integrated Test D Run Report Caustic and Oxidative Leaching in UFP-VSL-T02A

    SciTech Connect (OSTI)

    Sevigny, Gary J.; Bredt, Ofelia P.; Burns, Carolyn A.; Kurath, Dean E.; Geeting, John GH; Golovich, Elizabeth C.; Guzman-Leong, Consuelo E.; Josephson, Gary B.

    2009-12-11T23:59:59.000Z

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes" of the External Flowsheet Review Team (EFRT) issue response plan. The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario (Test B and D) has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario (Test A) has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP and vessels UFP VSL-00001A and B in the WTP PTF). In Test D, 19M sodium hydroxide (NaOH, caustic) was added to the waste slurry in the UFP VSL T02 vessel after the solids were concentrated to ~20% undissolved solids. The NaOH was added to leach solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by heating to 85°C using direct injection of steam to accelerate the leach process. The main difference of Test D compared to Test B is that the leach temperature is 85°C for 24 hrs as compared to 100°C for 12 hours. The other difference is the Test D simulant had Cr in the simulant from the start of processing and Test B had Cr added to adjust the simulant composition after aluminum leaching. Following the caustic leach, the UFP-VSL-T02A vessel contents are cooled using the vessel cooling jacket. The slurry was then concentrated to 17 wt% undissolved solids and washed with inhibited water to remove NaOH and other soluble salts. Next, the slurry was oxidatively leached using sodium permanganate to solubilize chrome. The slurry was then washed to remove the dissolved chrome and concentrated.

  9. everage manufacturers use a clever process known as crossflow filtration1

    E-Print Network [OSTI]

    Brainerd, Elizabeth

    B everage manufacturers use a clever process known as crossflow filtration1 to produce sparkling. Onpage439ofthisissue,Sandersonandcol- leagues2 reportthatsomefishspeciesalsouse crossflow filtration of precisely how cross- flow filtration in fishes works. In fact, although crossflow filtration has been

  10. Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System - 1997 Notice of Violation Consent Order

    SciTech Connect (OSTI)

    Evans, S.K.

    2002-01-31T23:59:59.000Z

    This Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA- 731 Caustic and Acid Storage Tank System is one of two documents that comprise the Sampling and Analysis Plan for the HWMA/RCRA closure certification of the TRA-731 caustic and acid storage tank system at the Idaho National Engineering and Environmental Laboratory. This plan, which provides information about the project description, project organization, and quality assurance and quality control procedures, is to be used in conjunction with the Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System. This Quality Assurance Project Plan specifies the procedures for obtaining the data of known quality required by the closure activities for the TRA-731 caustic and acid storage tank system.

  11. Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System - 1997 Notice of Violation Consent Order

    SciTech Connect (OSTI)

    Evans, Susan Kay; Orchard, B. J.

    2002-01-01T23:59:59.000Z

    This Quality Assurance Project Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System is one of two documents that comprise the Sampling and Analysis Plan for the HWMA/RCRA closure certification of the TRA-731 caustic and acid storage tank system at the Idaho National Engineering and Environmental Laboratory. This plan, which provides information about the project description, project organization, and quality assurance and quality control procedures, is to be used in conjunction with the Field Sampling Plan for the HWMA/RCRA Closure Certification of the TRA-731 Caustic and Acid Storage Tank System. This Quality Assurance Project Plan specifies the procedures for obtaining the data of known quality required by the closure activities for the TRA-731 caustic and acid storage tank system.

  12. Characterization and modification of particulate properties to enhance filtration performance

    SciTech Connect (OSTI)

    Snyder, T.R.; Vann Bush, P.; Robinson, M.S.

    1990-06-01T23:59:59.000Z

    The specific objectives of this project are to characterize the particulate properties that determine the filtration performance of fabric filters, and to investigate methods for modifying these particulate properties to enhance filtration performance. Inherent in these objectives is the development of an experimental approach that will lead to full-scale implementation of beneficial conditioning processes identified during the project. The general approach has included a large number of laboratory evaluations to be followed by optional field tests of a new successful conditioning processes performed on a sidestream device. This project was divided into five tasks. The schedule followed for these tasks is shown in Figure 4. Tasks 2 and 3 each focus on one of the two complementary parts of the project. Task 2 Parametric Tests of Ashes and Fabrics, evaluates the degree to which ash properties and fabric design determine filtration performance. Task 3 Survey of Methods to Modify the Particle Filtration Properties, provides a literature review and laboratory study of techniques to modify ash properties. The results of these two tasks were used in Task 4 Proof-of-Concept Tests of Methods to Modify Particle Filtration Properties to demonstrate the effects on filtration performance of modifying ash properties. The findings of all the tasks are summarized in this Final Report. 13 refs.

  13. The effect of concentration on the structure and crystallinity of a cementitious waste form for caustic wastes

    SciTech Connect (OSTI)

    Chung, Chul-Woo; Turo, Laura A.; Ryan, Joseph V.; Johnson, Bradley R.; McCloy, John S.

    2013-06-01T23:59:59.000Z

    Cement-based waste forms have long been considered economical technologies for disposal of various types of waste. A solidified cementitious waste form, Cast Stone, was developed to immobilize the radioactive secondary waste from vitrification processes. In this work, Cast Stone was considered for a Na-based caustic liquid waste, and its physical properties were analyzed as a function of liquid waste loading up to 2 M Na. Differences in crystallinity (phase composition), microstructure, mesostructure (pore size distribution, surface area), and macrostructure (density, compressive strength) were investigated using various analytical techniques, in order to assess the suitability of Cast Stone as a chemically durable waste. It was found that the concentration of secondary waste simulant (caustic waste) had little effect on the relevant engineering properties of Cast Stone, showing that Cast Stone could be an effective and tolerant waste form for a wide range of concentrations of high sodium waste.

  14. Recommended Guanidine Suppressor for the Next-Generation Caustic-Side Solvent Extraction Process

    SciTech Connect (OSTI)

    Moyer, Bruce A [ORNL; Delmau, Laetitia Helene [ORNL; Duncan, Nathan C [ORNL; Ensor, Dale [Tennessee Technological University; Hill, Talon G [ORNL; Lee, Denise L [ORNL; Roach, Benjamin D [ORNL; Sloop Jr, Frederick {Fred} V [ORNL; Williams, Neil J [ORNL

    2013-01-01T23:59:59.000Z

    The guanidine recommended for the Next-Generation Caustic-Side is N,N ,N -tris(3,7-dimethyloctyl)guanidine (TiDG). Systematic testing has shown that it is significantly more lipophilic than the previously recommended guanidine DCiTG, the active extractant in the commercial guanidine product LIX -79, while not otherwise changing the solvent performance. Previous testing indicated that the extent of partitioning of the DCiTG suppressor to the aqueous strip solution is significantly greater than expected, potentially leading to rapid depletion of the suppressor from the solvent and unwanted organic concentrations in process effluents. Five candidate guanidines were tested as potential replacements for DCiTG. The tests included batch extraction with simulated waste and flowsheet solutions, third-phase formation, emulsion formation, and partition ratios of the guanidine between the solvent and aqueous strip solution. Preliminary results of a thermal stability test of the TiDG solvent at one month duration indicated performance approximately equivalent to DCiTG. Two of the guanidines proved adequate in all respects, and the choice of TiDG was deemed slightly preferable vs the next best guanidine BiTABG.

  15. CHEMICAL STABILITY OF POLYPHENYLENE SULFIDE IN THE NEXT GENERATION SOLVENT FOR CAUSTIC-SIDE SOLVENT EXTRACTION

    SciTech Connect (OSTI)

    Fondeur, F.; Fink, S.

    2011-12-08T23:59:59.000Z

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. For simplicity, this solvent is referred to as the Next Generation Solvent (NGS). The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The initial deployment target envisioned for the technology was within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with polyphenylene sulfide (PPS), the polymer used in the coalescers within MCU. This report provides the data from exposing PPS polymer to NGS. The test was conducted over a three month period. PPS is remarkably stable in the presence of the next generation solvent. Testing showed no indication of swelling or significant leaching. Preferential sorption of the Modifier on PPS was observed but the same behavior occurs with the baseline solvent. Therefore, PPS coalescers exposed to the NGS are expected to perform comparably to those in contact with the baseline solvent.

  16. Caustic Precipitation of Plutonium and Uranium with Gadolinium as a Neutron Poison

    SciTech Connect (OSTI)

    VISSER, ANN E.; BRONIKOWSKI, MICHAEL G.; RUDISILL, TRACY S.

    2005-10-18T23:59:59.000Z

    The caustic precipitation of plutonium (Pu) and uranium (U) from Pu and U-containing waste solutions has been investigated to determine whether gadolinium (Gd) could be used as a neutron poison for precipitation with greater than a fissile mass containing both Pu and enriched U. Precipitation experiments were performed using both process solution samples and simulant solutions with a range of 2.6-5.16 g/L U and 0-4.3:1 U:Pu. Analyses were performed on solutions at intermediate pH to determine the partitioning of elements for accident scenarios. When both Pu and U were present in the solution, precipitation began at pH 4.5 and by pH 7, 99% of Pu and U had precipitated. When complete neutralization was achieved at pH > 14 with 1.2 M excess OH{sup -}, greater than 99% of Pu, U, and Gd had precipitated. At pH > 14, the particles sizes were larger and the distribution was a single mode. The ratio of hydrogen:fissile atoms in the precipitate was determined after both settling and centrifuging and indicates that sufficient water was associated with the precipitates to provide the needed neutron moderation for Gd to prevent a criticality in solutions containing up to 4.3:1 U:Pu and up to 5.16 g/L U.

  17. Life Extension Program for the Modular Caustic Side Solvent Extraction Unit at Savannah River Site - 13179

    SciTech Connect (OSTI)

    Samadi, Azadeh [Savannah River Remediation, Aiken, SC 29808 (United States)] [Savannah River Remediation, Aiken, SC 29808 (United States)

    2013-07-01T23:59:59.000Z

    Caustic Side Solvent Extraction (CSSX) is currently used at the U.S. Department of Energy (DOE) Savannah River Site (SRS) for removal of cesium from the high-level salt-wastes stored in underground tanks. Currently, the Actinide Removal Process (ARP) and the CSSX process are deployed in the (ARP)/Modular CSSX Unit (MCU), to process salt waste for permanent disposition. The CSSX technology utilizes a multi-component organic solvent and annular centrifugal contactors to extract cesium from alkaline salt waste. The original plant was permitted for a three year design life; however, given the successful operation of the plant, a life extension program was completed to continue operations. The program included detailed engineering analyses of the life-expectancy of passive and active components, resulting in component replacement and/or maintenance and monitoring program improvements. The program also included a review of the operations and resulted in a series of operational improvements. Since the improvements have been made, an accelerated processing rate has been demonstrated. In addition, plans for instituting a next-generation solvent are in place and will enhance the decontamination factors. (author)

  18. C-018H LERF filtration test plan. Revision 1

    SciTech Connect (OSTI)

    Moberg, T.P.; King, C.V.

    1994-08-26T23:59:59.000Z

    The following outlines the plan to test the polymeric backwash filtration system at the LERF. These tests will determine if the ETF filter design is adequate. If the tests show that the design is adequate, the task will be complete. If the tests show that the technology is inadequate, it may be necessary to perform further tests to qualify other candidate filtration technologies (e.g., polymeric tubular ultrafiltration, centrifugal ultrafiltration). The criteria to determine the success or failure of the backwash filter will be based on the system`s ability to remove the bacteria and inorganic contaminants from the evaporator process condensate. The tests are designed to qualify the design basis of the filtration technology that will be used in the ETF.

  19. Technetium separation from aqueous solutions using polymer filtration

    SciTech Connect (OSTI)

    Schroeder, N.C.; Ball, J.R.; Robison, T.W.; Gibson, R.R.; Smith, B.F. [Los Alamos National Lab., NM (United States)

    1997-12-31T23:59:59.000Z

    Water-soluble, metal-binding, polymers that possess functional groups with high selectivity for technetium have been developed for ground and waste waters remediation. When combined with ultrafiltration, a new homogeneous all aqueous-based technology for metals removal/recovery, called Polymer Filtration, becomes available. Technetium distribution coefficients experiments were obtained with the polymers from simple solutions, high nitrate simulants, and DSSF simulant. We have completed a preliminary proof-of-principal evaluation of Polymer Filtration technology for removal of technetium-99 from Paducah Gaseous Diffusion Plant contaminated groundwater simulant.

  20. Waste and Solvent Composition Limits for Modular Caustic-Side Solvent Extraction Unit (MCU)

    SciTech Connect (OSTI)

    Adu-Wusu, Kofi; Waler, Douglas D.; Edwards, Thomas B

    2005-05-26T23:59:59.000Z

    This study examined waste feed and solvent limits for the Modular Caustic-Side Solvent Extraction Unit (MCU) currently being designed and built at the Savannah River Site (SRS) to remove cesium from highly alkaline radioactive waste. The study involved proposing ranges for 12 waste feed components (i.e., Na{sup +}, K{sup +}, Cs{sup +}, OH{sup -}, NO{sub 3}{sup -}, NO{sub 2}{sup -}, Cl{sup -}, F{sup -}, SO{sub 4}{sup 2-}, PO{sub 4}{sup 3-}, and CO{sub 3}{sup 2-}, and AlO{sub 2}{sup -}) through a compilation of SRS waste data. Statistical design methods were used to generate numerous wastes with varying compositions from the proposed ranges. An Oak Ridge National Laboratory (ORNL) model called SXFIT was used to predict the cesium extraction distribution coefficients (D-values) between the organic (solvent) phase and the aqueous waste phase using the waste component concentrations as inputs. The D-values from the SXFIT model were used as input along with MCU base case process parameters to a SASSE (Spreadsheet Algorithm for Stagewise Solvent Extraction) model to calculate final cesium concentrations for the MCU. The SASSE model was developed at Argonne National Laboratory (ANL). The SXFIT D-value and the waste component concentration data were used to develop a handier alternative model (neural network model) to the SXFIT model that predicts D-values within 15% of the SXFIT D-values. Both the SXFIT and the neural network model revealed the following. The solvent extractant concentration ratios are approximately equal to the corresponding D-value ratios; a useful feature that could be used to predict extraction D-values when the extractant concentration in the solvent changes in the MCU operation. Also, potassium is the only waste component out of the 12 that shows a distinct relationship with the cesium extraction D-values; an indication of potassium's competition with cesium in the Caustic-Side Solvent Extraction (CSSX) process. A waste feed acceptance model suitable for assessing wastes within relatively wide ranges of D-values (0.6-40) and initial cesium-137 concentrations (0.2-12.8 Ci/gal) has been developed from the SASSE outputs. The waste feed acceptance model is an equation involving initial cesium-137 concentration and D-value that results in a final cesium-137 concentration of 0.1 Ci/gal, the target concentration for the MCU. For example, the waste feed acceptance model shows the minimum acceptable extraction D-value based on MCU base conditions is 5.73. The waste feed acceptance model is defined by a simple linear relationship for extraction D-values {ge} 7. This facilitates quicker calculations. For a given extraction D-value, final cesium-137 concentration (C{sub f}) and initial cesium-137 concentration (C{sub 0}) are linearly related; while for a given C{sub 0}, log (C{sub f}) and log (extraction D-value) are linear with a slope of -1.43. These two relationships allow one to quickly calculate C{sub f} at other MCU conditions without resorting to the SASSE model. The SASSE runs indicate that broad changes in the MCU process parameters for the extraction, scrub and strip stages (i.e., flow rate, temperature, fraction of interstage carryover, total liquid volume per contactor stage, and efficiency per contactor stage) will not result in C{sub f} exceeding target, at least for the MCU base conditions.

  1. Caustic-Side Solvent Extraction: Chemical and Physical Properties of the Optimized Solvent

    SciTech Connect (OSTI)

    Delmau, L.H.

    2002-10-08T23:59:59.000Z

    This work was undertaken to optimize the solvent used in the Caustic Side Solvent Extraction (CSSX) process and to measure key chemical and physical properties related to its performance in the removal of cesium from the alkaline high-level salt waste stored in tanks at the Savannah River Site. The need to adjust the solvent composition arose from the prior discovery that the previous baseline solvent was supersaturated with respect to the calixarene extractant. The following solvent-component concentrations in Isopar{reg_sign} L diluent are recommended: 0.007 M calix[4]arene-bis(tert-octylbenzo-crown-6) (BOBCalixC6) extractant, 0.75 M 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (Cs-7SB) phase modifier, and 0.003 M tri-n-octylamine (TOA) stripping aid. Criteria for this selection included BOBCalixC6 solubility, batch cesium distribution ratios (D{sub Cs}), calculated flowsheet robustness, third-phase formation, coalescence rate (dispersion numbers), and solvent density. Although minor compromises within acceptable limits were made in flowsheet robustness and solvent density, significant benefits were gained in lower risk of third-phase formation and lower solvent cost. Data are also reported for the optimized solvent regarding the temperature dependence of D{sub Cs} in extraction, scrubbing, and stripping (ESS); ESS performance on recycle; partitioning of BOBCalixC6, Cs-7SB, and TOA to aqueous process solutions; partitioning of organic anions; distribution of metals; solvent phase separation at low temperatures; solvent stability to elevated temperatures; and solvent density and viscosity. Overall, the technical risk of the CSSX process has been reduced by resolving previously identified issues and raising no new issues.

  2. FILTRATION DYNAMIQUE DE SUSPENSIONS DE CaCO3 ET DE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    FILTRATION DYNAMIQUE DE SUSPENSIONS DE CaCO3 ET DE SOLUTIONS DE SURFACTANTS Soutenue le 26 Juin. tel-00413890,version1-7Sep2009 #12;Résumé Filtration dynamique de suspensions de CaCO3 et de solutions

  3. Reducing Mortality from Terrorist Releases of Chemical and Biological Agents: I. Filtration for Ventilation Systems in Commercial Building

    E-Print Network [OSTI]

    Thatcher, Tracy L.

    2011-01-01T23:59:59.000Z

    Filtration for Ventilation Systems in Commercial BuildingsFiltration for Ventilation Systems in Commercial Buildingsbuilding's mechanical ventilation system and by infiltration

  4. Caustic stress corrosion cracking of E-Brite and Carpenter 7-MO stainless steels welded to Nickel 200 and Inconel 600

    E-Print Network [OSTI]

    Stockman, Steven Miles

    1982-01-01T23:59:59.000Z

    steel, each welded separatelv to Nickel 200 and Inconel 600, were teated for stress corrosion cracking in caus- tic supplied by Dow Chemical of Freeport, Texas, The V-bend type of specimen was tested in the caustic at room temperature, 60C and 800... ' The oh/ective of the test was to determine whether either of the stainless steels could be used in re- pairing nickel and nickel alloy equipment at the Dow Chemical caustic plant. Both stainless steels passed the initial test- ing and are recommended...

  5. Life extension program for the modular caustic side solvent extraction unit at Savannah River Site

    SciTech Connect (OSTI)

    Samadi-Dezfouli, Azadeh

    2012-11-14T23:59:59.000Z

    Caustic Side Solvent Extraction (CSSX) is currently used at the U.S. Department of Energy (DOE) Savannah River Site (SRS) for removal of cesium from the high-level salt-wastes stored in underground tanks. At SRS, the CSSX process is deployed in the Modular CSSX Unit (MCU). The CSSX technology utilizes a multi-component organic solvent and annular centrifugal contactors to extract cesium from alkaline salt waste. Coalescers and decanters process the Decontaminated Salt Solution (DSS) and Strip Effluent (SE) streams to allow recovery and reuse of the organic solvent and to limit the quantity of solvent transferred to the downstream facilities. MCU is operated in series with the Actinide Removal Process (ARP) which removes strontium and actinides from salt waste utilizing monosodium titanate. ARP and MCU were developed and implemented as interim salt processing until future processing technology, the CSSX-based Salt Waste Processing Facility (SWPF), is operational. SWPF is slated to come on-line in October 2014. The three year design life of the ARP/MCU process, however, was reached in April 2011. Nevertheless, most of the individual process components are capable of operating longer. An evaluation determined ARP/MCU can operate until 2015 before major equipment failure is expected. The three year design life of the ARP/MCU Life Extension (ARP/MCU LE) program will bridge the gap between current ARP/MCU operations and the start of SWPF operation. The ARP/MCU LE program introduces no new technologies. As a portion of this program, a Next Generation Solvent (NGS) and corresponding flowsheet are being developed to provide a major performance enhancement at MCU. This paper discusses all the modifications performed in the facility to support the ARP/MCU Life Extension. It will also discuss the next generation chemistry, including NGS and new stripping chemistry, which will increase cesium removal efficiency in MCU. Possible implementation of the NGS chemistry in MCU accomplishes two objectives. MCU serves as a demonstration facility for improved flowsheet deployment at SWPF; operating with NGS and boric acid validates improved cesium removal performance and increased throughput as well as confirms Defense Waste Processing Facility (DWPF) ability to vitrify waste streams containing boron. NGS implementation at MCU also aids the ARP/MCU LE operation, mitigating the impacts of delays and sustaining operations until other technology is able to come on-line.

  6. NEXT GENERATION SOLVENT MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT

    SciTech Connect (OSTI)

    Fondeur, F.; Peters, T.; Fink, S.

    2011-09-29T23:59:59.000Z

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil{reg_sign}, Tefzel{reg_sign} and Isolast{reg_sign}) in the modified NGS (where the concentration of the guanidine suppressor and MaxCalix was varied systematically) showed that guanidine (LIX{reg_sign}79) selectively affected Tefzel{reg_sign} (by an increase in size and lowering its density). The copolymer structure of Tefzel{reg_sign} and possibly its porosity allows for the easier diffusion of guanidine. Tefzel{reg_sign} is used as the seat material in some of the valves at MCU. Long term exposure to guanidine, may make the valves hard to operate over time due to the seat material (Tefzel{reg_sign}) increasing in size. However, since the physical changes of Tefzel{reg_sign} in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel{reg_sign} seating material. PEEK, Grafoil{reg_sign} and Isolast{reg_sign} were not affected by guanidine and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and no leachate was observed in the NGS from any of the polymers studied.

  7. MODULAR CAUSTIC SIDE SOLVENT EXTRACTION UNIT (MCU) GAMMA MONITORS SYSTEM FINAL REPORT

    SciTech Connect (OSTI)

    Casella, V

    2005-12-15T23:59:59.000Z

    The Department of Energy (DOE) selected Caustic-Side Solvent Extraction (CSSX) as the preferred technology for the removal of radioactive cesium from High-Level Waste (HLW) at the Savannah River Site (SRS). Before the full-scale Salt Waste Processing Facility (SWPF) becomes operational, the Closure Business Unit (CBU) plans to process a portion of dissolved saltcake waste through a Modular CSSX Unit (MCU). This work was derived from Technical Task Request SP-TTR-2004-00013, ''Gamma Monitor for MCU''. The deliverables for this task are the hardware and software for the gamma monitors and a report summarizing the testing and acceptance of this equipment for use in the MCU. Gamma-ray monitors are required to: (1) Measure the Cs-137 concentration in the decontaminated salt solution before entering the DSS (Decontaminated Salt Solution) Hold Tank, (2) Measure the Cs-137 concentration in the strip effluent before entering the Strip Effluent Hold Tank, (3) Verify proper operation of the solvent extraction system by verifying material balance within the process (The DSS Hold Tank Cs-137 concentration will be very low and the Cs-137 concentration in the Strip Effluent Hold Tank will be fifteen times higher than the Cs-137 concentration in the Feed Tank.) Sodium iodide monitors are used to measure the Cs-137 concentration in the piping before the DSS Hold tank, while GM monitors are used for Cs-137 measurements before the Strip Effluent Hold Tank. Tungsten shields were designed using Monte Carlo calculations and fabricated to reduce the process background radiation at the detector positions. These monitors were calibrated with NIST traceable standards that were specially made to be the same as the piping being monitored. Since this gamma ray monitoring system is unique, specially designed software was written and acceptance tested by Savannah River National Laboratory personnel. The software is a LabView-based application that serves as a unified interface for controlling the monitor hardware and communicating with the host Distributed Control System (DCS). In order to provide user friendly software for the process personnel, the software was broken down into just a few software modules. These software modules are the Application Window, Detector Selection, Detector Configuration Settings, Background Counting, and Routine Data Acquisition. Instructions for using the software have been included in a user's manual that is appended to this report. The work presented in this report meets all of the requirements set forth in the project task plan to design and implement gamma ray monitors for the MCU. Additional setup and testing of the system will be required when it implemented in the process.

  8. CHARACTERIZATION AND EVALUATION OF CAUSTIC WASH TANK AND SOLVENT HOLD TANK SAMPLES FROM MCU FROM AUGUST TO SEPTEMBER 2011

    SciTech Connect (OSTI)

    Fondeur, F.; Fink, S.

    2012-08-01T23:59:59.000Z

    During processing of Salt Batches 3 and 4 in the Modular Caustic-Side Solvent Extraction Unit (MCU), the decontamination efficiency for cesium declined from historical values and from expectations based on laboratory testing. This report documents efforts to analyze samples of solvent and process solutions from MCU in an attempt to understand the cause of the reduced performance and to recommend mitigations. CWT Solutions from MCU from the time period of variable decontamination factor (DF) performance which covers from April 2011 to September 2011 (during processing of Salt Batch 4) were examined for impurities using chromatography and spectroscopy. The results indicate that impurities were found to be of two types: aromatic containing impurities most likely from Modifier degradation and aliphatic type impurities most likely from Isopar{reg_sign} L and tri-n-octylamine (TOA) degradation. Caustic washing the Solvent Hold Tank (SHT) solution with 1M NaOH improved its extraction ability as determined from {sup 22}Na uptake tests. Evidence from this work showed that pH variance in the aqueous solutions within the range of 1M nitric acid to 1.91M NaOH that contacted the solvent samples does not influence the analytical determination of the TOA concentration by GC-MS.

  9. RESULTS OF CAUSTIC DISSOLUTION OF ALUMINOSILICATE SCALE AND CHARACTERIZATION DATA FOR SAMPLES FROM THE EVAPORATOR POT AND GRAVITY DRAIN LINE

    SciTech Connect (OSTI)

    Wilmarth, B; Rita Sullivan, R; Chris Martino, C

    2006-08-21T23:59:59.000Z

    The build-up of sodium aluminosilicate scale in the 2H Evaporator system continues to cause operational difficulties. The use of a nitric acid cleaning operation proved successful in 2001. However, the operation required additional facilities to support spent cleaning solution neutralization and was quite costly. A proposed caustic cleaning flowsheet has many advantages over the acid flowsheet. Therefore, samples were retrieved from the evaporator system (gravity drain line and pot) for both chemical and radiological characterization and dissolution testing. The characterization of these scale samples showed the presence of nitrated cancrinite along with a dehydrated zeolite. Small amounts of depleted uranium were also found in these samples as expected and the amount of uranium ranged from 0.5 wt% to 2 wt%. Dissolution in sodium hydroxide solutions of various caustic concentrations showed that the scale slowly dissolves at elevated temperature (90 C). Data from similar testing indicate that the scale removed from the GDL in 2005 dissolves slower than that removed in 1997. Differences in the particle size of these samples of scale may well explain the measured dissolution rate differences.

  10. Energy conservation in electrostatic fabric filtration of industrial dust

    SciTech Connect (OSTI)

    Ariman, T.

    1981-12-01T23:59:59.000Z

    Conservation in energy consumption in industrial fabric filtration systems has become very important due to the substantial increase in energy costs. Recently, an external electric field was utilized in the industrial dust control by fabric filters with very promising initial results. A substantial decrease in the pressure drop and an increase in collection efficiency were observed. The detailed outcome of the experimental research program in electrostatic fabric filtration was presented. The results show that pressure drop decreases substantially with the increased electrostatic field strength for all relevant parameters. Furthermore, the data of the experimental program was utilized to develop a semi-empirical model for the determination of the pressure drop and to establish an Energy-Optimized Design Criteria.

  11. Modified approaches for high pressure filtration of fine clean coal

    SciTech Connect (OSTI)

    Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

    1995-12-31T23:59:59.000Z

    Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

  12. Evaluation of hyperbaric filtration for fine coal dewatering. Final report

    SciTech Connect (OSTI)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc. (United States)

    1996-08-15T23:59:59.000Z

    The main objectives of the project were to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20% moisture. The program consisted of three phases, namely Phase 1 -- Model Development, Phase 2 -- Laboratory Studies, Phase 3 -- Pilot Plant Testing. The Pennsylvania State University led efforts in Phase 1, the University of Kentucky in Phase 2, and CONSOL Inc. in Phase 3 of the program. All three organizations were involved in all the three phases of the program. The Pennsylvania State University developed a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky conducted experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in Phase 1 and 2 were tested in two of the CONSOL Inc. coal preparation plants using an Andritz Ruthner portable hyperbaric filtration unit.

  13. CROSSFLOW FILTRATION: EM-31, WP-2.3.6

    SciTech Connect (OSTI)

    Duignan, M.; Nash, C.; Poirier, M.

    2011-02-01T23:59:59.000Z

    In the interest of accelerating waste treatment processing, the DOE has funded studies to better understand filtration with the goal of improving filter fluxes in existing crossflow equipment. The Savannah River National Laboratory (SRNL) performed some of those studies, with a focus on start-up techniques, filter cake development, the application of filter aids (cake forming solid precoats), and body feeds (flux enhancing polymers). This paper discusses the progress of those filter studies. Crossflow filtration is a key process step in many operating and planned waste treatment facilities to separate undissolved solids from supernate solutions. This separation technology generally has the advantage of self-cleaning through the action of wall shear stress created by the flow of waste slurry through the filter tubes. However, the ability of filter wall self-cleaning depends on the slurry being filtered. Many of the alkaline radioactive wastes are extremely challenging to filtration, e.g., those containing compounds of aluminum and iron, which have particles whose size and morphology reduce permeability. Unfortunately, low filter flux can be a bottleneck in waste processing facilities such as the Savannah River Integrated Salt Disposition Process and the Hanford Waste Treatment Plant. Any improvement to the filtration rate would lead directly to increased throughput of the entire process. To date increased rates are generally realized by either increasing the crossflow filter feed flow rate, limited by pump capacity, or by increasing filter surface area, limited by space and increasing the required pump load. SRNL set up both dead-end and crossflow filter tests to better understand filter performance based on filter media structure, flow conditions, filter cleaning, and several different types of filter aids and body feeds. Using non-radioactive simulated wastes, both chemically and physically similar to the actual radioactive wastes, the authors performed several tests to evaluate methods to improve filter performance. With the proper use of filter flow conditions and filter enhancers, filter flow rates can be increased over rates currently realized today. Experiments that use non-radioactive simulants for actual waste always carry the inherent risk of not eliciting prototypic results; however, they will assist in focusing the scope needed to minimize radioactive testing and thus maximize safety. To that end this investigation has determined: (1) Waste simulant SB6 was found to be more challenging to filtration than a SRS Tank 8F simulant; (2) Higher solids concentration presents a greater challenge to filtration; (3) Filter cake is something that should be properly developed in initial filter operation; (4) Backpulsing is not necessary to maintain a good filter flux with salt wastes; (5) Scouring a filter without cleaning will lead to improved filter performance; (6) The presence of a filter cake can improve the solids separation by an order of magnitude as determined by turbidity; (7) A well developed cake with periodic scouring may allow a good filter flux to be maintained for long periods of time; and (8) Filtrate flux decline is reversible when the concentration of the filtering slurry drops and the filter is scoured.

  14. FULL-SCALE TESTING OF A CAUSTIC SIDE SOLVENT EXTRACTION SYSTEM TO REMOVE CESIUM FROM SAVANNAH RIVER SITE RADIOACTIVE WASTE

    SciTech Connect (OSTI)

    Poirier, M; Thomas Peters, T; Earl Brass, E; Stanley Brown, S; Mark Geeting, M; Lcurtis Johnson, L; Charles02 Coleman, C; S Crump, S; Mark Barnes, M; Samuel Fink, S

    2007-10-15T23:59:59.000Z

    Savannah River Site (SRS) personnel have completed construction and assembly of the Modular Caustic Side Solvent Extraction Unit (MCU) facility. Following assembly, they conducted testing to evaluate the ability of the process to remove non-radioactive cesium and to separate the aqueous and organic phases. They conducted tests at salt solution flow rates of 3.5, 6.0, and 8.5 gpm. During testing, the MCU Facility collected samples and submitted them to Savannah River National Laboratory (SRNL) personnel for analysis of cesium, Isopar{reg_sign} L, and Modifier [1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol]. SRNL personnel analyzed the aqueous samples for cesium by Inductively-Coupled Plasma Mass Spectroscopy (ICP-MS) and the solvent samples for cesium using a Parr Bomb Digestion followed by ICP-MS. They analyzed aqueous samples for Isopar{reg_sign} L and Modifier by gas chromatography (GC).

  15. INVESTIGATION OF THE POTENTIAL FOR CAUSTIC STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS

    SciTech Connect (OSTI)

    Lam, P.

    2009-10-15T23:59:59.000Z

    The evaporator recycle streams contain waste in a chemistry and temperature regime that may be outside of the current waste tank corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history (1998-2008) of Tanks 30 and 32 showed that these tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved F-Area tanks. Therefore, for the Type III/IIIA waste tanks the efficacy of the stress relief of welding residual stress is the only corrosion-limiting mechanism. The objective of this experimental program is to test carbon steel small scale welded U-bend specimens and large welded plates (12 x 12 x 1 in.) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 C). These conditions simulate worst-case situations in Tanks 30 and 32. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test is currently in progress, but no cracking has been observed after 9 weeks of immersion. Based on the preliminary results, it appears that the environmental conditions of the tests are unable to develop stress corrosion cracking within the duration of these tests.

  16. Determination of glomerular filtration rate by external counting methods

    E-Print Network [OSTI]

    Sartor, Tammy Lee

    1981-01-01T23:59:59.000Z

    comparing the DTPA to other accepted methods; the results were very favorable for the use of ggmTC-DTPA. Klopper et al. , sa1d mTc-DTPA ". . . rapidly prepared by a kit method, is a useful addition to the list of radiopharmaceuticals that can be used... points. First, the external counting method is suitable as a true means of determining the glomerular filtration rate (GFR). Second, the method is applicable to cats. To do this, five dogs were injected with ggmTc(Sn)-DTPA. Plasma samples were drawn...

  17. Development of Model Filtration Media for Investigating Size-Dependent

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * S H IMaterialsDepartmentFiltration Efficiency |

  18. Caustic Leaching of SRS Tank 12H Sludge With and Without Chelating Agents

    SciTech Connect (OSTI)

    Spencer, B.B.

    2003-04-30T23:59:59.000Z

    The primary objective of this study was to measure the effect of adding triethanolamine (TEA) to caustic leaching solutions to improve the solubility of aluminum in actual tank-waste sludge. High-level radioactive waste sludge that had a high aluminum assay was used for the tests. This waste, which originated with the processing of aluminum-clad/aluminum-alloy fuels, generates high levels of heat because of the high {sup 90}Sr concentration and contains hard-to-dissolve boehmite phases. In concept, a chelating agent, such as TEA, can both improve the dissolution rate and increase the concentration in the liquid phase. For this reason, TEA could also increase the solubility of other sludge components that are potentially problematic to downstream processing. Tests were conducted to determine if this were the case. Because of its relatively high vapor pressure, process design should include methods to minimize losses of the TEA. Sludge was retrieved from tank 12H at the Savannah River Site by on-site personnel, and then shipped to Oak Ridge National Laboratory for the study. The sludge contained a small quantity of rocky debris. One slate-like flat piece, which had approximate dimensions of 1 1/4 x 1/2 x 1/8 in., was recovered. Additional gravel-like fragments with approximate diameters ranging from 1/8 to 1/4 in. were also recovered by sieving the sludge slurry through a 1.4-mm square-pitch stainless steel mesh. These particles ranged from a yellow quartz-like material to grey-colored gravel. Of the 32.50 g of sludge received, the mass of the debris was only 0.89 g, and the finely divided sludge comprised {approx}97% of the mass. The sludge was successfully subdivided into uniform aliquots during hot-cell operations. Analytical measurements confirmed the uniformity of the samples. The smaller sludge samples were then used as needed for leaching experiments conducted in a glove box. Six tests were performed with leachate concentrations ranging from 0.1 to 3.0 m NaOH, 0 to 3.0 m TEA and 0 to 2.9 m NaNO{sub 3}. Figure ES.1 illustrates the leaching of aluminum in all six tests. One test was performed at an operating temperature of 80 C to obtain baseline data, and the remaining five tests were all performed at 60 C. A leaching solution of 3.0 m NaOH was used for the test performed at 80 C and for one of the tests performed at 60 C. These results indicated that more aluminum entered the solution at the higher temperature, though equilibrium was achieved at both temperatures within {approx}10 days. The addition of TEA significantly increased the concentration of aluminum in the leachate, and the concentration continued to increase even after 11 days of processing. The fraction of aluminum dissolved at 60EC increased from {approx}35% using 3.0 m NaOH alone to {approx}87% using a combination of 3.0 m NaOH and 3.0 m TEA. The high-nitrate, low-hydroxide solutions did not significantly dissolve the aluminum, because aluminate ion could not be produced. A small addition of TEA had no effect on this process. The use of TEA also increased the solubility of some other sludge components. The fractions of copper, nickel, and iron that were dissolved increased to 72, 13, and 52%, respectively. However, the original fractions of these metals were only 0.055, 0.72, and 3.1%, respectively, of the dry mass of the sludge and therefore represent minor constituents. The presence of nickel in the leachate did have a dramatic effect on its color, which changed from light yellow to deep green as the nickel concentration increased. By comparison, the baseline leaching with 3.0 m NaOH at 60 C removed {approx}14% of the copper; iron and nickel were below the detectable limit.

  19. Does filtration efficiency affect measurements of particle chemical composition?

    SciTech Connect (OSTI)

    Romo-Kroeger, C.M. [Univ. of Tarapaca, Arica (Chile)

    1998-07-01T23:59:59.000Z

    Most experimentalists accept an uncertainty of 4--6% in the determination of aerosol mass concentration. However, in some combustion processes sulfur and other elements are present in significant amounts as particles of very small size. A direct method to measure filtration efficiency was developed and used for the determination of the efficiency of a Nuclepore filter. This needs two equivalent filtration systems operated in sequence. The amount of particulate matter collected on each system is measured and introduced in a simple formula. The particulate masses deposited on the filters in each system were measured as total mass, by balance gravimetry, and as individual elemental masses, by PIXE (particle induced X-ray emission). With this very general method it was possible to determine the efficiencies of a 0.4 {micro}m Nuclepore filter operated with a stacked filter unit for particles less than 2.5 {micro}m in total mass and elemental masses. The experiment showed that the efficiency of this filter is very poor for some specific elements, like sulfur, that are concentrated in very small particles.

  20. Water washes and caustic leaches of sludge from Hanford Tank S-101 and water washes of sludge from Hanford Tank C-103

    SciTech Connect (OSTI)

    Hunt, R.D.; Collins, J.L.; Chase, C.W.

    1998-07-01T23:59:59.000Z

    In 1993, the Department of Energy (DOE) selected the enhanced sludge washing (ESW) process as the baseline for pretreatment of Hanford tank sludges. The ESW process uses a series of water washes and caustic leaches to separate nonradioactive components such as aluminum, chromium, and phosphate from the high-level waste sludges. If the ESW process is successful, the volume of immobilized high-level waste will be significantly reduced. The tests on the sludge from Hanford Tank S-101 focused on the effects of process variables such as sodium hydroxide concentration (1 and 3 M), temperature (70 and 95 C), and leaching time (5, 24, 72, and 168 h) on the efficacy of the ESW process with realistic liquid-to-solid ratios. Another goal of this study was to evaluate the effectiveness of water washes on a sludge sample from hanford Tank C-103. The final objective of this study was to test potential process control monitors during the water washes and caustic leaches with actual sludge. Both {sup 137}Cs activity and conductance were measured for each of the water washes and caustic leaches. Experimental procedures, a discussion of results, conclusions and recommendations are included in this report.

  1. Prediction of additive filtration rate from slurry properties

    SciTech Connect (OSTI)

    Rudenko, L.I.; Urusova, N.P.

    1987-01-01T23:59:59.000Z

    The authors study the porosity, specific surface area, and certain other characteristics of solid contaminants and suspensions of commercial lube oil additives, and also the possibility of using the results from these studies to determine the rate of additive filtration through a layer of the solid contaminants. For investigation, the authors took the solid contaminants in the additive VNII NP-360 (a mixture of zinc dialkylphenyldithiophosphate and barium alkylphenolate), AFK (calcium trialkylphenolate), EFO (solvent extract from residual lube stocks successively treated with P/sub 2/S/sub 5/, an alcohol, ZnO, and Ba(OH)/sub 2/), MASK (overbased calcium alkylsalicylate), PMS (overbased calcium sulfonate), VNII NP-370 (calcium salt of product obtained by condensation of alkylphenols with formaldehyde), and the boron component of the additive A-9250 (boron-containing Mannich base).

  2. Results Of Routine Strip Effluent Hold Tank, Decontaminated Salt Solution Hold Tank, And Caustic Wash Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 4 Operations

    SciTech Connect (OSTI)

    Peters, T. B.; Fink, S. D.

    2012-10-25T23:59:59.000Z

    Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), and Caustic Wash Tank (CWT) samples from several of the ?microbatches? of Integrated Salt Disposition Project (ISDP) Salt Batch (?Macrobatch?) 4 have been analyzed for {sup 238}Pu, {sup 90}Sr, {sup 137}Cs, and by inductively-coupled plasma emission spectroscopy (ICPES). Furthermore, samples from the CWT have been analyzed by a variety of methods to investigate a decline in the decontamination factor (DF) of the cesium observed at MCU. The results indicate good decontamination performance within process design expectations. While the data set is sparse, the results of this set and the previous set of results for Macrobatch 3 samples indicate generally consistent operations. There is no indication of a disruption in plutonium and strontium removal. The average cesium DF and concentration factor (CF) for samples obtained from Macrobatch 4 are slightly lower than for Macrobatch 3, but still well within operating parameters. The DSSHT samples show continued presence of titanium, likely from leaching of the monosodium titanate in Actinide Removal Process (ARP).

  3. Experimental study of head loss and filtration for LOCA debris

    SciTech Connect (OSTI)

    Rao, D.V.; Souto, F.J. [Science and Engineering Associates, Inc., Albuquerque, NM (United States)

    1996-02-01T23:59:59.000Z

    A series of controlled experiments were conducted to obtain head loss and filtration characteristics of debris beds formed of NUKON{trademark} fibrous fragments, and obtain data to validate the semi-theoretical head loss model developed in NUREG/CR-6224. A thermally insulated closed-loop test set-up was used to conduct experiments using beds formed of fibers only and fibers intermixed with particulate debris. A total of three particulate mixes were used to simulate the particulate debris. The head loss data were obtained for theoretical fiber bed thicknesses of 0.125 inches to 4.0 inches; approach velocities of 0.15 to 1.5 ft/s; temperatures of 75 F and 125 F; and sludge-to-fiber nominal concentration ratios of 0 to 60. Concentration measurements obtained during the first flushing cycle were used to estimate the filtration efficiencies of the debris beds. For test conditions where the beds are fairly uniform, the head loss data were predictable within an acceptable accuracy range by the semi-theoretical model. The model was equally applicable for both pure fiber beds and the mixed beds. Typically the model over-predicted the head losses for very thin beds and for thin beds at high sludge-to-fiber mass ratios. This is attributable to the non-uniformity of such debris beds. In this range the correlation can be interpreted to provide upper bound estimates of head loss. This is pertinent for loss of coolant accidents in boiling water reactors.

  4. The Role of Filtration in Maintaining Clean Heat Exchanger Coils

    SciTech Connect (OSTI)

    Li Yang; James E. Braun; Eckhard A. Groll

    2004-06-30T23:59:59.000Z

    The main purpose of the study was to investigate the role of filtration in maintaining clean heat exchanger coils and overall performance. Combinations of 6 different levels of filtration (MERV 14, 11, 8, 6, 4, and no filter) and 4 different coils (an eight-row lanced-fin coil, HX8L), (an eight-row wavy-fin coil, HX8W), (a four-row lanced-fin coil, HX4L) and (a two-row lanced-fin coil, HX2L) were tested at 4 different air velocities (1.52, 2.03, 2.54,3.05 m/s (300, 400, 500, 600 ft/min)). The fouled conditions were obtained after injection of 600 grams of ASHRAE standard dust upstream of the filter/coil combination. This magnitude of dust is representative of a year of normal operation for an air conditioning system. The air-side pressure drops of the coils and filters and air-side heat transfer coefficients of the coils were determined from the measurements under the clean and fouled conditions. Depending upon the filter and coil test, the coil pressure drops increased in the range of 6%-30% for an air velocity at 2.54 m/s (500 ft/min). The impact was significantly greater for tests performed without a filter. The largest relative effect of fouling on pressure drop occurs for coils with fewer rows and having lanced fins. Coils with a greater number of rows can hold more dust so that a fixed amount of dust has a relatively smaller impact. The impact of fouling on air-side heat transfer coefficients was found to be relatively small. In some cases, heat transfer was actually enhanced due to additional turbulence caused by the presence of dust. The experimental results for pressure drops and heat transfer coefficients were correlated and the correlations were implemented within computer models of prototypical rooftop air conditioners and used to evaluate the impact of fouling on cooling capacity and EER. The equipment cooling capacity is reduced with fouling primarily because of a decrease in air flow due to the increase pressure drop rather than due to changes in h eat transfer coefficient. In most cases, the EER was reduced with fouling primarily due to increased fan power. However, the changes in EER were relatively small, in the range of 1%-9% (10%). For most cases, equipment having low efficiency filters had higher EER after fouling than equipment with high efficiency filters, because the high efficiency filter caused significantly higher pressure drops than the low efficiency filters. The extra filter pressure drop outweighed the reduced coil pressure drop after fouling. The impact of fan efficiency curves was also investigated in the study. The energy penalty associated with high efficiency filters was reduced considerably with higher efficiency fans. There is an energy penalty associated with the use of high efficiency filtration. However, the primary reason for selecting high efficiency filters for a particular application would be improved air quality. For HX8L, the quantity of dust passing through the coil with a MERV4 filter was approximately 30 times the dust passing the coil with a MERV14 filter. Without an upstream filter, the quantity of dust passing through the coil was approximately 60 times the value for a MERV14 filter.

  5. Evaluation of Side Stream Filtration Technology at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Boyd, Brian K.

    2014-08-01T23:59:59.000Z

    This technology evaluation was performed by Pacific Northwest National Laboratory and Oak Ridge National Laboratory on behalf of the Federal Energy Management Program. The objective was to quantify the benefits side stream filtration provides to a cooling tower system. The evaluation assessed the performance of an existing side stream filtration system at a cooling tower system at Oak Ridge National Laboratory’s Spallation Neutron Source research facility. This location was selected because it offered the opportunity for a side-by-side comparison of a system featuring side stream filtration and an unfiltered system.

  6. Membrane filtration studies of inversely soluble model metalworking fluids

    SciTech Connect (OSTI)

    Misra, S.K.; Skoeld, R.O. [Chalmers Univ. of Technology, Gothenburg (Sweden)] [Chalmers Univ. of Technology, Gothenburg (Sweden)

    1999-01-01T23:59:59.000Z

    Model metalworking fluids, characterized by phase separation of functional components at elevated temperatures, were studied. Results of membrane filtration experiments with three oils of differing chemical nature confirm the feasibility of specific removal of finely dispersed contaminant oils without the simultaneous loss of active components from adequately formulated fluids. Prerequisites are that membrane materials and pore sizes be suitably chosen and that operating temperatures be kept below the cloud point of the least soluble component. The most suitable filter in the present study was a hydrophilic regenerated cellulose membrane with a NMWL of 100,000 dalton. Complete oil removal was attained if membrane pore sizes did not exceed 0.1 {micro}m. It was also found that intrinsically water-soluble boundary lubricants of the polyglycol ether type are retained by membranes in the presence of PPG-1800, which serves as a precipitation promoter above the cloud point. This is of considerable practical importance since it offers the possibility of designing water-soluble boundary lubrication and extreme pressure additives which are activated by the presence of an inversely soluble component above its cloud point. The latter compound also acts as the principal hydrodynamic lubricant of the present model formulations. The usefulness of a new analytical tool for the rapid acquisition and imaging of data pertinent to changes in molecular aggregation and phase conditions was demonstrated.

  7. Characterization and modification of particulate properties to enhance filtration performance

    SciTech Connect (OSTI)

    Snyder, T.R.; Robinson, M.S.; Vann Bush, P.

    1989-06-22T23:59:59.000Z

    This report describes the results of project activities that occurred during the period from March 1 through May 31, 1989. The organization of this report generally follows the outline of work presented in the Project Work Plan. Work performed during this period included tests under Task 2 -- Parametric Tests of Ashes and Fabrics, and Task 3 -- Survey of Methods to Modify Particle Filtration Properties. Discussion of the Task 2 work has been organized topically, rather than adhering to the activities specified in the Work Plan. Cohesive ash from the Tennessee Valley Authority's 160 MW Atmospheric Fluidized-Bed Combustor at the Shawnee Plant in Paducah, Kentucky was obtained during this quarter and has been analyzed in the laboratory. The second phase of the abstract search and review of pertinent articles included in activity 3.1 is nearly complete. A summary of this phase of the literature search is included in this report. A variety of potential conditioning agents have been evaluated during this reporting period. These agents include sodium bicarbonate, hydrated lime, various grades of fine silica powder, gasifier char, glass beads and glass fibers. The three source ashes have been mixed with these agents in different concentrations and using various mixing techniques. These tests are continuing, and this report contains a summary of the combinations evaluated during this past quarter. 17 figs., 7 tabs.

  8. Portable water filtration system for oil well fractionation

    SciTech Connect (OSTI)

    Seibert, D. L.

    1985-08-13T23:59:59.000Z

    The invention comprises a portable, multi-stage filtration system utilized in filtering water for an oil and gas stimulation process commonly known as fracking. Three stages are used, the first being a straining operation reducing the size of particulate matter in the water to about three-eighths of an inch. The second stage is a centrifugal separator, reducing the particle size to about 50 microns. The final stage utilizes a cartridge-type filter giving a final particle size in the water of about 5 microns. In this manner, water which is injected into the well head during the fracking process and which is obtained from readily available sources such as ponds, streams and the like is relatively free of particulate matter which can foul the fracking process. The invention, by virtue of being mounted on a trailer, is portable and thus can be easily moved from site to site. Water flow rates obtained using the invention are between 250 and 300 gallons per minute, sufficient for processing a small to medium sized well.

  9. ALTERNATE HIGH EFFICIENCY PARTICULATE AIR (HEPA) FILTRATION SYSTEM

    SciTech Connect (OSTI)

    Bruce Bishop; Robert Goldsmith; Karsten Nielsen; Phillip Paquette

    2002-08-16T23:59:59.000Z

    In Phase IIA of this project, CeraMem has further developed and scaled up ceramic HEPA filters that are appropriate for use on filtration of vent gas from HLW tanks at DOE sites around the country. This work included procuring recrystallized SiC monoliths, developing membrane and cement materials, and defining a manufacturing process for the production of prototype full sizes HEPA filters. CeraMem has demonstrated that prototype full size filters can be manufactured by producing 9 full size filters that passed DOP aerosol testing at the Oak Ridge Filter Test Facility. One of these filters was supplied to the Savannah River Technical Center (SRTC) for process tests using simulated HLW tank waste. SRTC has reported that the filter was regenerable (with some increase in pressure drop) and that the filter retained its HEPA retention capability. CeraMem has also developed a Regenerable HEPA Filter System (RHFS) design and acceptance test plan that was reviewed by DOE personnel. The design and acceptance test plan form the basis of the system proposal for follow-on work in Phase IIB of this project.

  10. Evaluation of Collector Well Configurations to Model Hydrodynamics in Riverbank Filtration and Groundwater Remediation

    E-Print Network [OSTI]

    De Leon, Tiffany Lucinda

    2011-10-21T23:59:59.000Z

    Collector well designs are necessary to maximize groundwater uptake and riverbank filtration without negatively impacting an aquifer. Unfortunately, there is a lack of information and research regarding the implementation of collector well design...

  11. Vit Plant receives and sets key air filtration equipment for Low Activity Waste Facility

    Broader source: Energy.gov [DOE]

    WTP lifted a nearly 100-ton carbon bed absorber into the Low-Activity Waste Facility. This key piece of air-filtration equipment will remove mercury and acidic gases before air is channeled through...

  12. Self-healing properties of water filtration membranes containing amphiphilic comb polymer

    E-Print Network [OSTI]

    Devereaux, Caitlin Albright, 1980-

    2004-01-01T23:59:59.000Z

    (cont.) and filtration experiments, as well as other characterization techniques. Surface analysis is accomplished via x-ray photoelectron spectroscopy (XPS). Membrane samples are cleaned (in hydrogen peroxide or ...

  13. Design of a small-scale continuous linear motion pharmaceutical filtration module

    E-Print Network [OSTI]

    Wong, Katherine Wing-Shan

    2010-01-01T23:59:59.000Z

    A new small-scale continuous linear motion pharmaceutical filtration prototype was designed, fabricated, and tested. The goal of this unit is to filter an Active Pharmaceutical Ingredient (API) from a mixture of API ...

  14. Form, function and flow in the plankton : jet propulsion and filtration by pelagic tunicates

    E-Print Network [OSTI]

    Sutherland, Kelly Rakow

    2010-01-01T23:59:59.000Z

    Trade-offs between filtration rate and swimming performance among several salp species with distinct morphologies and swimming styles were compared. Small-scale particle encounter at the salp filtering apparatus was also ...

  15. Radioactive Testing Results in Support of the In-Tank Precipitation Facility - Filtrate Test

    SciTech Connect (OSTI)

    Hobbs, D.T.

    1998-10-21T23:59:59.000Z

    This report documents results investigating the decomposition of excess NaTPB in presence of filtrate from one of the Cycle I Demonstration tests, fulfilling a request by CST Engineering and the ITP Flow Sheet Team.

  16. A Brief Review of Filtration Studies for Waste Treatment at the Hanford Site

    SciTech Connect (OSTI)

    Daniel, Richard C.; Schonewill, Philip P.; Shimskey, Rick W.; Peterson, Reid A.

    2010-12-01T23:59:59.000Z

    This document completes the requirements of Milestone 1-2, PNNL Draft Literature Review, discussed in the scope of work outlined in the EM-31 Support Project task plan WP-2.3.6-2010-1. The focus of task WP 2.3.6 is to improve the U.S. Department of Energy’s (DOE’s) understanding of filtration operations for high-level waste (HLW) to enhance filtration and cleaning efficiencies, thereby increasing process throughput and reducing the sodium demand (through acid neutralization). Developing the processes for fulfilling the cleaning/backpulsing requirements will result in more efficient operations for both the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and the Savannah River Site (SRS), thereby increasing throughput by limiting cleaning cycles. The purpose of this document is to summarize Pacific Northwest National Laboratory’s (PNNL’s) literature review of historical filtration testing at the laboratory and of testing found in peer-reviewed journals. Eventually, the contents of this document will be merged with a literature review by SRS to produce a summary report for DOE of the results of previous filtration testing at the laboratories and the types of testing that still need to be completed to address the questions about improved filtration performance at WTP and SRS. To this end, this report presents 1) a review of the current state of crossflow filtration knowledge available in the peer-reviewed literature, 2) a detailed review of PNNL-related filtration studies specific to the Hanford site, and 3) an overview of current waste filtration models developed by PNNL and suggested avenues for future model development.

  17. Factors influencing the precoat filtration of boiling water reactor water streams

    SciTech Connect (OSTI)

    Hermansson, H.P. (Studsvik Material AB, Nykoeping (Sweden)); Persson, G. (Forsmark Nuclear Power Plant, Oesthammar (Sweden)); Reinvall, A. (Industrial Power Co. Ltd., Olkiluoto (Finland))

    1994-10-01T23:59:59.000Z

    A series of studies on precoat filtration were carried out on condensate and preheater drains in the Swedish and Finnish boiling water reactors (BWRs). The goal was to increase knowledge about the precoat filtration process and to find physical and chemical means to improve the performance of the precoat filters in the condensate polishing plants. To achieve this goal a number of parameters, such as type of resin, bed depth, pH, oxygen and organic contaminant concentrations (measured total organic carbon), and corrosion product particle characteristics, were selected for the study. The work was mainly carried out in the power plants using an experimental facility fed with on-line sampled condensates and drains taken from the plant sampling lines. The main results are that there is a varying influence on precoat filtration from all the aforementioned parameters. The oxygen concentration, the concentration of organic contaminants, and the type of corrosion products are, however, the factors that have the strongest influence within the parameter ranges that are representative for BWR operation. The results are rather similar when the different units are compared. There are, however, some differences that could be mainly attributed to deviations in operation parameters and the subsequent differences in the corrosion product spectra. The mechanism for precoat filtration of corrosion products in BWR condensate is complex. The filtration behavior is to a large extent governed by competition between depth filtration and electrostatic interactions. During the early stages of the filtration cycle, electrostatic interaction is of great importance, whereas depth filtration becomes more important with increasing operating time. Rapid pressure drop buildup rates have been demonstrated to be caused by the presence of amorphous corrosion products. An effect from the presence of organic contaminants has been found, although this should be of little significance.

  18. EFFICACY OF FILTRATION PROCESSES TO OBTAIN WATER CLARITY AT K EAST SPENT NUCLEAR FUEL (SNF) BASIN

    SciTech Connect (OSTI)

    DUNCAN JB

    2006-09-28T23:59:59.000Z

    The objective is to provide water clarity to the K East Basin via filtration processes. Several activities are planned that will challenge not only the capacity of the existing ion exchange modules to perform as needed but also the current filtration system to maintain water clarity. Among the planned activities are containerization of sludge, removal of debris, and hydrolasing the basin walls to remove contamination.

  19. Can combining economizers with improved filtration save energy and protect equipment in data centers?

    SciTech Connect (OSTI)

    Shehabi, Arman; Ganguly, Srirupa; Gundel, Lara A.; Horvath, Arpad; Kirchstetter, Thomas W.; Lunden, Melissa M.; Tschudi, William; Gadgil, Ashok J.; Nazaroff, William W

    2009-06-05T23:59:59.000Z

    Economizer use in data centers is an energy efficiency strategy that could significantly limit electricity demand in this rapidly growing economic sector. Widespread economizer implementation, however, has been hindered by potential equipment reliability concerns associated with exposing information technology equipment to particulate matter of outdoor origin. This study explores the feasibility of using economizers in data centers to save energy while controlling particle concentrations with high-quality air filtration. Physical and chemical properties of indoor and outdoor particles were analyzed at an operating northern California data center equipped with an economizer under varying levels of air filtration efficiency. Results show that when improved filtration is used in combination with an economizer, the indoor/outdoor concentration ratios for most measured particle types were similar to levels when using conventional filtration without economizers. An energy analysis of the data center reveals that, even during the summer months, chiller savings from economizer use greatly outweigh any increase in fan power associated with improved filtration. These findings indicate that economizer use combined with improved filtration could reduce data center energy demand while providing a level of protection from particles of outdoor origin similar to that observed with conventional design.

  20. Caustic stress corrosion cracking of E-Brite and Carpenter 7-MO stainless steels welded to Nickel 200 and Inconel 600 

    E-Print Network [OSTI]

    Stockman, Steven Miles

    1982-01-01T23:59:59.000Z

    -Brite and Carpenter 7-MO Stainless Steels Welded to Nickel 200 and Znconel 600~ (December 1982) Steven Miles Stockman, B. S ~ , Texas AgM University Chairman of Advisory Committee: Dr, R. B. Griffin Samples of E-Brite stainless steel and Carpenter 7-MO stainless... steel, each welded separatelv to Nickel 200 and Inconel 600, were teated for stress corrosion cracking in caus- tic supplied by Dow Chemical of Freeport, Texas, The V-bend type of specimen was tested in the caustic at room temperature, 60C and 800...

  1. DEMONSTRATION OF THE NEXT-GENERATION CAUSTIC-SIDE SOLVENT EXTRACTION SOLVENT WITH 2-CM CENTRIGUGAL CONTRACTORS USING TANK 49H WASTE AND WASTE SIMULANT

    SciTech Connect (OSTI)

    Pierce, R.; Peters, T.; Crowder, M.; Pak, D.; Fink, S.; Blessing, R.; Washington, A.; Caldwell, T.

    2011-11-29T23:59:59.000Z

    Researchers successfully demonstrated the chemistry and process equipment of the Caustic-Side Solvent Extraction (CSSX) flowsheet using MaxCalix for the decontamination of high level waste (HLW). The demonstration was completed using a 12-stage, 2-cm centrifugal contactor apparatus at the Savannah River National Laboratory (SRNL). This represents the first CSSX process demonstration of the MaxCalix solvent system with Savannah River Site (SRS) HLW. Two tests lasting 24 and 27 hours processed non-radioactive simulated Tank 49H waste and actual Tank 49H HLW, respectively. A solvent extraction system for removal of cesium from alkaline solutions was developed utilizing a novel solvent invented at the Oak Ridge National Laboratory (ORNL). This solvent consists of a calix[4]arene-crown-6 extractant dissolved in an inert hydrocarbon matrix. A modifier is added to the solvent to enhance the extraction power of the calixarene and to prevent the formation of a third phase. An additional additive is used to improve stripping performance and to mitigate the effects of any surfactants present in the feed stream. The process that deploys this solvent system is known as Caustic Side Solvent Extraction (CSSX). The solvent system has been deployed at the Savannah River Site (SRS) in the Modular CSSX Unit (MCU) since 2008.

  2. Caustic Recovery Technology

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613PortsmouthBartlesville EnergyDepartment ofSystems AreStorageof Energy

  3. Characterization, Leaching, and Filtrations Testing of Ferrocyanide Tank sludge (Group 8) Actual Waste Composite

    SciTech Connect (OSTI)

    Fiskum, Sandra K.; Billing, Justin M.; Crum, J. V.; Daniel, Richard C.; Edwards, Matthew K.; Shimskey, Rick W.; Peterson, Reid A.; MacFarlan, Paul J.; Buck, Edgar C.; Draper, Kathryn E.; Kozelisky, Anne E.

    2009-02-28T23:59:59.000Z

    This is the final report in a series of eight reports defining characterization, leach, and filtration testing of a wide variety of Hanford tank waste sludges. The information generated from this series is intended to supplement the Waste Treatment and Immobilization Plant (WTP) project understanding of actual waste behaviors associated with tank waste sludge processing through the pretreatment portion of the WTP. The work described in this report presents information on a high-iron waste form, specifically the ferrocyanide tank waste sludge. Iron hydroxide has been shown to pose technical challenges during filtration processing; the ferrocyanide tank waste sludge represented a good source of the high-iron matrix to test the filtration processing.

  4. NEXT GENERATION SOLVENT-MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT (FINAL REPORT)

    SciTech Connect (OSTI)

    Fondeur, F.; Peters, T.; Fink, S.

    2012-01-17T23:59:59.000Z

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil, Tefzel and Isolast) in the modified NGS (where the concentration of LIX{reg_sign}79 and MaxCalix was varied systematically) showed that LIX{reg_sign}79 selectively affected Tefzel and its different grades (by an increase in size and lowering its density). The copolymer structure of Tefzel and possibly its porosity allows for the easier diffusion of LIX{reg_sign}79. Tefzel is used as the seat material in some of the valves at MCU. Long term exposure to LIX{reg_sign}79, may make the valves hard to operate over time due to the seat material (Tefzel) increasing in size. However, since the physical changes of Tefzel in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel seating material. PEEK, Grafoil and Isolast were not affected by LIX{reg_sign}79 and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and with the exception of CPVC, no leachate was observed in the NGS from any of the polymers studied. The testing shows no major concerns for compatibility over the short duration of these tests but does indicate that longer duration exposure studies are warranted, especially for Tefzel. However, the physical changes experienced by Tefzel in the improved solvent were comparable to the physical changes obtained when Tefzel is placed in CSSX baseline solvent. Therefore, there is no effect of the improved solvent beyond those observed in CSSX baseline solvent.

  5. Pretreatment Engineering Platform (PEP) Integrated Test B Run Report--Caustic and Oxidative Leaching in UFP-VSL-T02A

    SciTech Connect (OSTI)

    Geeting, John GH; Bredt, Ofelia P.; Burns, Carolyn A.; Golovich, Elizabeth C.; Guzman-Leong, Consuelo E.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Aaberg, Rosanne L.

    2009-12-10T23:59:59.000Z

    Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed, constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes” of the External Flowsheet Review Team (EFRT) issue response plan.( ) The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  6. PEP Run Report for Integrated Test A, Caustic Leaching in UFP-VSL-T01A, Oxidative Leaching in UFP-VSL-T02A

    SciTech Connect (OSTI)

    Guzman-Leong, Consuelo E.; Bredt, Ofelia P.; Burns, Carolyn A.; Daniel, Richard C.; Su, Yin-Fong; Geeting, John GH; Golovich, Elizabeth C.; Josephson, Gary B.; Kurath, Dean E.; Sevigny, Gary J.; Smith, Dennese M.; Valdez, Patrick LJ; Yokuda, Satoru T.; Young, Joan K.

    2009-12-04T23:59:59.000Z

    Pacific Northwest National Laboratory (PNNL) was tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and operated as part of a plan to respond to issue M12, “Undemonstrated Leaching Processes.”(a) The PEP, located in the Process Engineering Laboratory-West (PDLW) located in Richland, Washington, is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing.

  7. Agglomeration and filtration of colloidal suspensions with DVLO interactions in simulation and experiment

    E-Print Network [OSTI]

    Harting, Jens

    ]. Eisfeld et al. propose a pseudo-continuous model for statistically described domain geometries, where 2010 Elsevier Inc. All rights reserved. 1. Introduction Cake filtration is an energy efficient or membrane and build up a filter cake with increasing thick- ness. The high flow resistance of nanoporous

  8. On the data dependent filtration techniques in the single-photon emission computed tomography

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    On the data dependent filtration techniques in the single-photon emission computed tomography J computed tomography (SPECT) data modeled as the 2D attenuated ray transform with Poisson noise.G.Novikov, A noise property analysis of single-photon emission computed tomography data, Inverse Problems 20, pp.175

  9. VOLUME 16, NUMBER 3 HVAC&R RESEARCH MAY 2010 The Effects of Filtration on

    E-Print Network [OSTI]

    Siegel, Jeffrey

    VOLUME 16, NUMBER 3 HVAC&R RESEARCH MAY 2010 273 The Effects of Filtration on Pressure Drop and Energy Consumption in Residential HVAC Systems (RP-1299) Brent Stephens Atila Novoselac, PhD Jeffrey A of high-efficiency HVAC filters is a common strategy to control exposure to airborne particulate matter

  10. Evaluation of a Combined Cyclone and Gas Filtration System for Particulate Removal in the Gasification Process

    SciTech Connect (OSTI)

    Rizzo, Jeffrey J. [Phillips66 Company, West Terre Haute, IN (United States)

    2010-04-30T23:59:59.000Z

    The Wabash gasification facility, owned and operated by sgSolutions LLC, is one of the largest single train solid fuel gasification facilities in the world capable of transforming 2,000 tons per day of petroleum coke or 2,600 tons per day of bituminous coal into synthetic gas for electrical power generation. The Wabash plant utilizes Phillips66 proprietary E-Gas (TM) Gasification Process to convert solid fuels such as petroleum coke or coal into synthetic gas that is fed to a combined cycle combustion turbine power generation facility. During plant startup in 1995, reliability issues were realized in the gas filtration portion of the gasification process. To address these issues, a slipstream test unit was constructed at the Wabash facility to test various filter designs, materials and process conditions for potential reliability improvement. The char filtration slipstream unit provided a way of testing new materials, maintenance procedures, and process changes without the risk of stopping commercial production in the facility. It also greatly reduced maintenance expenditures associated with full scale testing in the commercial plant. This char filtration slipstream unit was installed with assistance from the United States Department of Energy (built under DOE Contract No. DE-FC26-97FT34158) and began initial testing in November of 1997. It has proven to be extremely beneficial in the advancement of the E-Gas (TM) char removal technology by accurately predicting filter behavior and potential failure mechanisms that would occur in the commercial process. After completing four (4) years of testing various filter types and configurations on numerous gasification feed stocks, a decision was made to investigate the economic and reliability effects of using a particulate removal gas cyclone upstream of the current gas filtration unit. A paper study had indicated that there was a real potential to lower both installed capital and operating costs by implementing a char cyclonefiltration hybrid unit in the E-Gas (TM) gasification process. These reductions would help to keep the E-Gas (TM) technology competitive among other coal-fired power generation technologies. The Wabash combined cyclone and gas filtration slipstream test program was developed to provide design information, equipment specification and process control parameters of a hybrid cyclone and candle filter particulate removal system in the E-Gas (TM) gasification process that would provide the optimum performance and reliability for future commercial use. The test program objectives were as follows: 1. Evaluate the use of various cyclone materials of construction; 2. Establish the optimal cyclone efficiency that provides stable long term gas filter operation; 3. Determine the particle size distribution of the char separated by both the cyclone and candle filters. This will provide insight into cyclone efficiency and potential future plant design; 4. Determine the optimum filter media size requirements for the cyclone-filtration hybrid unit; 5. Determine the appropriate char transfer rates for both the cyclone and filtration portions of the hybrid unit; 6. Develop operating procedures for the cyclone-filtration hybrid unit; and, 7. Compare the installed capital cost of a scaled-up commercial cyclone-filtration hybrid unit to the current gas filtration design without a cyclone unit, such as currently exists at the Wabash facility.

  11. Effect of Oxalate on the Recycle of Neptunium Filtrate Solution by Anion Exchange

    SciTech Connect (OSTI)

    Kyser, E

    2004-11-18T23:59:59.000Z

    A series of laboratory column runs has been performed that demonstrates the recovery of neptunium (Np) containing up to 0.05 M oxalate. Np losses were generally less than one percent to the raffinate for feed solutions that contained 2 to 10 g Np/L. Up to 16 percent Np losses were observed with lower Np feed concentrations, but those losses were attributed to the shortened residence times rather than the higher oxalate to Np ratios. Losses in the plant are expected to be significantly less due to the lower cross-section flowrate possible with existing plant pumps. Elimination of the permanganate treatment of filtrates appears to be reasonable since the amount of Np in those filtrates does not appear to be practical to recover. Combination of untreated filtrates with other actinide rich solutions is not advisable as precipitation problems are likely. If untreated filtrates are kept segregated from other actinide rich streams, the recovery of the remaining Np is probably still possible, but could be limited due to the excessively high oxalate to Np ratio. The persistence of hydrazine/hydrazoic acid in filtrate solutions dictates that the nitrite treatment be retained to eliminate those species from the filtrates prior to transfer to the canyon. Elimination of the permanganate treatment of precipitator flushes and recovery by anion exchange does not appear to be limited by the oxalate effect on anion exchange. Np from solutions with higher oxalate to Np molar ratios than expected in precipitator flushes was recovered with low to modest losses. Solubility problems appear to be unlikely when the moles of oxalate involved are less than the total number of moles of Np due to complexation effects. The presence of significant concentrations of iron (Fe) in the solutions will further decrease the probability of Np oxalate precipitation due the formation of Fe oxalate complexes. Np oxalate solubility data in 8 M HNO{sub 3} with from one to six times as much oxalate as Np have been obtained. These data supplement literature data in the high HNO{sub 3} low oxalate region, but provide additional data for solutions with relatively large amounts of Np present. Enhanced solubility of Np oxalate over that reported in the literature was observed.

  12. Recycling of cleach plant filtrates by electrodialysis removal of inorganic non-process elements.

    SciTech Connect (OSTI)

    Tsai, S. P.; Pfromm, P.; Henry, M. P.; Fracaro, A. T.; Swanstrom, C. P.; Moon, P.; Energy Systems; Inst. of Paper Science and Tech.

    2000-11-01T23:59:59.000Z

    Water use in the pulp and paper industry is very significant, and the U.S. pulp and paper industries as well as other processing industries are actively pursuing water conservation and pollution prevention by in-process recycling of water. Bleach plant effluent is a large portion of the water discharged from a typical bleached kraft pulp mill. The recycling of bleach plant effluents to the kraft recovery cycle is widely regarded as an approach to low effluent bleached kraft pulp production. The focus of this work has been on developing an electrodialysis process for recycling the acidic bleach plant effluent of bleached Kraft pulp mills. Electrodialysis is uniquely suited as a selective kidney to remove non-process elements (NPEs) from bleach plant effluent before they reach the chemical recovery cycle. Using electrodialysis for selective NPE removal can prevent the problems caused by accumulation of inorganic NPEs in the pulping cycle and recovery boiler. In this work, acidic bleach plant filtrates from three mills using different bleaching sequences based on chlorine dioxide were characterized. The analyses showed no fundamental differences in the inorganic NPE composition or other characteristics among these filtrates. The majority of total dissolved solids in the effluents were found to be inorganic NPEs. Chloride and nitrate were present at significant levels in all effluent samples. Sodium was the predominant metal ion, while calcium and magnesium were also present at considerable levels. The feasibility of using electrodialysis to selectively remove inorganic NPEs from the acidic bleach effluent was successfully demonstrated in laboratory experiments with effluents from all these three mills. Although there were some variations in these effluents, chloride and potentially harmful cations, such as potassium, calcium, and magnesium, were removed efficiently from the bleach effluents into a small-volume, concentrated purge stream. This effective removal of inorganic NPEs can enable the mills to recycle bleach effluents to reduce water consumption. The electrodialysis process also effectively retained up to 98% of the organics and can reduce the organic discharge in the mill wastewater. By using suitable commercially available electrodialysis membranes, there were no indications of rapid or irreversible membrane fouling or scale formation, even in extended laboratory scale operations up to 100 hours. Results of laboratory experiments also showed that commercially available membranes properly selected for this process would have good stability to withstand the potentially oxidative conditions of the filtrate. A pilot-scale field demonstration was also conducted at a southern mill, using the D0 filtrate from the bleach plant. During the field demonstration we found serious membrane 2 stack clogging problems, which apparently were caused by fine fibers that escaped through the 5-micron pre-filters, although such a pre-filtration method had been satisfactory in the laboratory tests. Additional R&D is recommended to address this pre-filtration or clogging issue with systems approaches integrating pre-filtration, other separation methods, and stack design. After the pre-filtration/clogging issue is overcome, laboratory development and pilot demonstration are recommended to optimize the process parameters and to evaluate the long-term process parameters. The key technical issues here include membrane lives, control and mitigation of fouling and scaling, and cleaning-in-place protocols. From the data collected in this work, a preliminary process design and economic evaluations were performed for a model mill with 1,000-ton/day pulp production that uses a bleaching sequence based on chlorine dioxide. Assuming 3 m{sup 3} acidic effluents to be treated per ton of pulp produced, the electrodialysis process would require a membrane area of about 361 m{sup 2} for this model mill. The energy consumption of the electrodialytic stack for separation is estimated to be about $160/day, and the estimated capital cost of the electrodia

  13. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Final report

    SciTech Connect (OSTI)

    Weber, G.F.; Dunham, G.E.; Laudal, D.L.; Ness, S.R.; Schelkoph, G.L.

    1994-08-01T23:59:59.000Z

    The overall objective of the project proposed was to evaluate the catalyst-coated fabric filter concept for effective control of NO{sub 2} and particulate emissions simultaneously. General goals included demonstrating high removal efficiency of NO{sub x} and particulate matter, acceptable bag and catalyst life, and that process economics show a significant cost savings in comparison to a commercial SCR process and conventional particulate control. Specific goals included the following: reduce NO{sub x} emissions to 60 ppM or less; demonstrate particulate removal efficiency of >99.5%; demonstrate a bag/catalyst life of >1 year; Control ammonia slip to <25 ppM; show that catalytic fabric filtration can achieve a 50% cost savings over conventional fabric filtration and SCR control technology; determine compatibility with S0{sub 2} removal systems; and show that the concept results in a nonhazardous waste product.

  14. DECONTAMINATION OF PLUTONIUM FOR FLUORIDE AND CHLORIDE DURING OXALATE PRECIPITATION, FILTRATION AND CALCINATION PROCESSES

    SciTech Connect (OSTI)

    Kyser, E.

    2012-07-25T23:59:59.000Z

    Due to analytical limitations for the determination of fluoride (F) and chloride (Cl) in a previous anion exchange study, an additional study of the decontamination of Pu from F and Cl by oxalate precipitation, filtration and calcination was performed. Anion product solution from the previous impurity study was precipitated as an oxalate, filtered, and calcined to produce an oxide for analysis by pyrohydrolysis for total Cl and F. Analysis of samples from this experiment achieved the purity specification for Cl and F for the proposed AFS-2 process. Decontamination factors (DF's) for the overall process (including anion exchange) achieved a DF of {approx}5000 for F and a DF of {approx}100 for Cl. Similar experiments where both HF and HCl were spiked into the anion product solution to a {approx}5000 {micro}g /g Pu concentration showed a DF of 5 for F and a DF of 35 for Cl across the combined precipitation-filtration-calcination process steps.

  15. EXPERIMENTS ON CAKE DEVELOPMENT IN CROSSFLOW FILTRATION FOR HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Duignan, M.; Nash, C.

    2011-04-14T23:59:59.000Z

    Crossflow filtration is a key process step in many operating and planned waste treatment facilities to separate undissolved solids from supernate slurries. This separation technology generally has the advantage of self cleaning through the action of wall shear stress, which is created by the flow of waste slurry through the filter tubes. However, the ability of filter wall self cleaning depends on the slurry being filtered. Many of the alkaline radioactive wastes are extremely challenging to filtration, e.g., those containing compounds of aluminum and iron, which have particles whose size and morphology reduces permeability. Low filter flux can be a bottleneck in waste processing facilities such as the Salt Waste Processing Facility at the Savannah River Site and the Waste Treatment Plant at the Hanford Site. Any improvement to the filtration rate would lead directly to increased throughput of the entire process. To date, increased rates are generally realized by either increasing the crossflow filter axial flowrate, which is limited by pump capacity, or by increasing filter surface area, which is limited by space and increases the required pump load. In the interest of accelerating waste treatment processing, DOE has funded studies to better understand filtration with the goal of improving filter fluxes in existing crossflow equipment. The Savannah River National Laboratory (SRNL) was included in those studies, with a focus on startup techniques and filter cake development. This paper discusses those filter studies. SRNL set up both dead-end and crossflow filter tests to better understand filter performance based on filter media structure, flow conditions, and filter cleaning. Using non-radioactive simulated wastes, which were both chemically and physically similar to the actual radioactive wastes, the authors performed several tests to demonstrate increases in filter performance. With the proper use of filter flow conditions filter flow rates can be increased over rates currently realized today. This paper describes the selection of a challenging simulated waste and crossflow filter tests to demonstrate how performance can be improved over current operation.

  16. On the splitting of the Bloch-Beilinson filtration Arnaud BEAUVILLE

    E-Print Network [OSTI]

    Beauville, Arnaud

    (X) , with CHp (X) = F0 CHp (X) . . . Fp+1 (X) = 0 and F1 CH(X) = Ker cX . We refer to [J] for a discussion graduation given by CHp (A) = s CHp s(A) , where CHp s(A) is the subspace of elements CHp (A) with k A = k2 not define the required filtration because the vanishing of the terms CHp s(A) for s

  17. The effect of various mud filtrates on the permeability of sandstone cores

    E-Print Network [OSTI]

    Pfile, Robert Ambrose

    1954-01-01T23:59:59.000Z

    ' or the Degree of MASTER OF SCIENCE August, 1954 MAJOR SUBJECT: PETROLEUM ENGINEERING THE EFFECT OF VARIOUS MUD FILTRATES ON THE PERMEABILITY OF SANDSTONE CORES A Thesis By Robert A. Pfile Appr ved as to styIe and content by: (Chairman of mmittee... kind and amount of clay contained in the different cores. INTRODUCTION There is general agreement among members of the petroleum industry that the productive capacity of a well penetrating a clay- containing oil sand may be seriously impaired due...

  18. Effects of drilling fluid properties and shear rate on dynamic filtration

    E-Print Network [OSTI]

    McCarty, Robert Andrew

    1990-01-01T23:59:59.000Z

    be used to eliminate the residual fines left behind from the previous mud run. 2. Synthetic cores should be used to increase reproducibility and homogeneity. This will further separate core properties from mud filter cake properties allowing a more... are subjected to a differential pressure across porous and permeable formations. Differential pressure causes solids in drilling fluids to be filtered out and deposited as a cake on the wellbore wall as the liquid phase (mud filtrate) invades the formation...

  19. Filtration and Leach Testing for REDOX Sludge and S-Saltcake Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Geeting, John GH; Hallen, Richard T.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Snow, Lanee A.; Swoboda, Robert G.

    2009-02-20T23:59:59.000Z

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.( ) The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP-RPP-WTP-467, eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste-testing program was implemented that included: • Homogenizing the archive samples by group as defined in the test plan • Characterizing the homogenized sample groups • Performing parametric leaching testing on each group for compounds of interest • Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on filtration/leaching tests performed on two of the eight waste composite samples and follow-on parametric tests to support aluminum leaching results from those tests.

  20. Modeling Mud-Filtrate Invasion Effects on Resistivity Logs to Estimate Permeability of Vuggy and Fractured Carbonate Formations

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    measurements with conventional and non- conventional well logs to calculate static and dynamic petrophysical/or fractures in the displacement of hydrocarbons by mud filtrate. Introduction Permeability estimation is one

  1. Hazardous Materials Verification and Limited Characterization Report on Sodium and Caustic Residuals in Materials and Fuel Complex Facilities MFC-799/799A

    SciTech Connect (OSTI)

    Gary Mecham

    2010-08-01T23:59:59.000Z

    This report is a companion to the Facilities Condition and Hazard Assessment for Materials and Fuel Complex Sodium Processing Facilities MFC-799/799A and Nuclear Calibration Laboratory MFC-770C (referred to as the Facilities Condition and Hazards Assessment). This report specifically responds to the requirement of Section 9.2, Item 6, of the Facilities Condition and Hazards Assessment to provide an updated assessment and verification of the residual hazardous materials remaining in the Sodium Processing Facilities processing system. The hazardous materials of concern are sodium and sodium hydroxide (caustic). The information supplied in this report supports the end-point objectives identified in the Transition Plan for Multiple Facilities at the Materials and Fuels Complex, Advanced Test Reactor, Central Facilities Area, and Power Burst Facility, as well as the deactivation and decommissioning critical decision milestone 1, as specified in U.S. Department of Energy Guide 413.3-8, “Environmental Management Cleanup Projects.” Using a tailored approach and based on information obtained through a combination of process knowledge, emergency management hazardous assessment documentation, and visual inspection, this report provides sufficient detail regarding the quantity of hazardous materials for the purposes of facility transfer; it also provides that further characterization/verification of these materials is unnecessary.

  2. Characterization, Leaching, and Filtration Testing for Tributyl Phosphate (TBP, Group 7) Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Edwards, Matthew K.; Billing, Justin M.; Blanchard, David L.; Buck, Edgar C.; Casella, Amanda J.; Casella, Andrew M.; Crum, J. V.; Daniel, Richard C.; Draper, Kathryn E.; Fiskum, Sandra K.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Snow, Lanee A.; Swoboda, Robert G.

    2009-03-09T23:59:59.000Z

    .A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual waste-testing program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. The tributyl phosphate sludge (TBP, Group 7) is the subject of this report. The Group 7 waste was anticipated to be high in phosphorus as well as aluminum in the form of gibbsite. Both are believed to exist in sufficient quantities in the Group 7 waste to address leaching behavior. Thus, the focus of the Group 7 testing was on the removal of both P and Al. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

  3. Measurement-Based Evaluation of Installed Filtration System Performance in Single-Family Homes

    SciTech Connect (OSTI)

    Chan, Wanyu Rengie; Singer, Brett C.

    2014-04-03T23:59:59.000Z

    This guide discusses important study design issues to consider when conducting an on-site evaluation of filtration system performance. The two most important dichotomies to consider in developing a study protocol are (1) whether systems are being evaluated in occupied or unoccupied homes and (2) whether different systems are being compared in the same homes or if the comparison is between systems installed in different homes. This document provides perspective and recommendations about a suite of implementation issues including the choice of particle measurement devices, selection of sampling locations, ways to control and/or monitor factors and processes that can impact particle concentrations, and data analysis approaches.

  4. Use of tangential filtration unit for processing liquid waste from nuclear laundries

    SciTech Connect (OSTI)

    Augustin, X.; Buzonniere, A. de [Technicatome, Gif-sur-Yvette (France); Barnier, H. [CEA Cadarache, St. Paul-lez-Durance (France)

    1993-12-31T23:59:59.000Z

    Nuclear facilities produce large quantities of weakly contaminated effluents charged with insoluble and soluble products. In collaboration with CEA, TECHNICATOME has developed an ultrafiltration process for liquid waste from nuclear facilities associated with prior insolubilization of radiochemical activity. This process, seeded ultrafiltration, is based on the use of a decloggable mineral filter media and combines very high separation efficiency with long membrane life. The efficiency of the tangential filtration unit which has been processing effluents from the Cadarache Nuclear Research Center (CEA-France) nuclear facility since mid-1988, has been confirmed on several sites.

  5. Multifunctional nanocomposites of carbon nanotubes and nanoparticles formed via vacuum filtration

    DOE Patents [OSTI]

    Hersam, Mark C; Ostojic, Gordana; Liang, Yu Teng

    2013-10-22T23:59:59.000Z

    In one aspect, the present invention provides a method of forming a film of nanocomposites of carbon nanotubes (CNTs) and platinum (Pt) nanoparticles. In one embodiment, the method includes the steps of (a) providing a first solution that contains a plurality of CNTs, (b) providing a second solution that contains a plurality of Pt nanoparticles, (c) combining the first solution and the second solution to form a third solution, and (d) filtering the third solution through a nanoporous membrane using vacuum filtration to obtain a film of nanocomposites of CNTs and Pt nanoparticles.

  6. Evaluation of dust cake filtration at high temperature with effluence from an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Dennis, R.A.

    1990-08-01T23:59:59.000Z

    In the spring of 1989, two separate test series were simultaneously conducted at the US Department of Energy's (DOE's) Morgantown Energy Technology Center (METC) to examine applied and fundamental behavior of dust cake filtration under high temperature and high pressure (HTHP) conditions. The purpose was to provide information on dust-cake filtration properties to gas stream cleanup researchers associated with the Tidd 70 megawatt (MW) pressurized fluidized-bed combustor (PFBC). The two test facilities included (1) a high-pressure natural-gas combustor with injected particulate, which was fed to two full-size candle filters; and (2) an atmospheric fluidized-bed combustor (AFBC) with coal and limestone sorbent to generate a particulate-laden combustion exhaust gas, which was sent to a single full-size candle filter and a small-scale disc filter. Several major conclusions from these studies are noted below. On average reducing the mean particulate size by 33% and the associated loading carried in the filtrate will increase the dust cake specific flow resistance (K{sub 2}) by 498%. High-temperature and high-pressure filtration can be successfully performed with ceramic candle filters at moderate filtration face velocities and reasonable system pressure drops. Off-line filter cleaning can produce a filter system with a higher apparent permeability than that produced from on-line filter cleaning at the same face velocity. 19 refs., 89 figs., 13 tabs.

  7. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect (OSTI)

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W. (Center for Nanoscale Materials); ( ES)

    2012-05-15T23:59:59.000Z

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  8. Dust Filtration by Planet-Induced Gap Edges: Implications for Transitional Disks

    E-Print Network [OSTI]

    Zhu, Zhaohuan; Dong, Ruobing; Espaillat, Catherine; Hartmann, Lee

    2012-01-01T23:59:59.000Z

    By carrying out two-dimensional two-fluid global simulations, we have studied the response of dust to gap formation by a single planet in the gaseous component of a protoplanetary disk - the so-called "dust filtration" mechanism. We have found that a gap opened by a giant planet at 20 AU in a \\alpha=0.01, \\dot{M}=10^{-8} Msun/yr disk can effectively stop dust particles larger than 0.1 mm drifting inwards, leaving a sub-millimeter dust cavity/hole. However, smaller particles are difficult to filter by a planet-induced gap due to 1) dust diffusion, and 2) a high gas accretion velocity at the gap edge. An analytic model is also derived to understand what size particles can be filtered by the gap edge. Finally, with our updated understanding of dust filtration, we have computed Monte-Carlo radiative transfer models with variable dust size distributions to generate the spectral energy distributions (SEDs) of disks with gaps. By comparing with transitional disk observations (e.g. GM Aur), we have found that dust fi...

  9. Monte Carlo Modeling of Nuclear Measurements in Vertical and Horizontal Wells in the Presence of Mud-Filtrate Invasion and Salt Mixing1

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    of Mud-Filtrate Invasion and Salt Mixing1 Alberto Mendoza2 , William E. Preeg3 , Carlos Torres-Verdín2 the influence of the spatial distributions of fluid saturation and salt concentration on generic compensated-bearing formation. The simulations also consider the mixing of salt between mud-filtrate and connate water. Subse

  10. Mathematical modeling of mass transfer during centrifugal filtration of polydisperse suspensions

    SciTech Connect (OSTI)

    V.F. Pozhidaev; Y.B. Rubinshtein; G.Y. Golberg; S.A. Osadchii [Dahl East Ukraine National University, Lugansk (Ukraine)

    2009-07-15T23:59:59.000Z

    A mass-transfer equation, the solution of which for given boundary conditions makes it possible to derive in analytical form a relationship between the extraction of the solid phase of a suspension into the centrifuge effluent and the fineness of the particles, is suggested on the basis of a model; this is of particular importance in connection with the development of a new trend in the utilization of filtering centrifuges - concentration of coal slurries by extraction into the centrifuge effluent of the finest particles, the ash content of which is substantially higher than that of particles of the coarser classes. Results are presented for production studies under conditions at an active establishment (the Neryungrinskaya Enrichment Factory); these results confirmed the adequacy of the mathematical model proposed: convergence of computed and experimental data was within the limits of the experimental error (no more than 3%). The model in question can be used to predict results of suspension separation by centrifugal filtration.

  11. Simulated Waste for Leaching and Filtration Studies--Laboratory Preparation Procedure

    SciTech Connect (OSTI)

    Smith, Harry D.; Russell, Renee L.; Peterson, Reid A.

    2009-10-27T23:59:59.000Z

    This report discusses the simulant preparation procedure for producing multi-component simulants for leaching and filtration studies, including development and comparison activities in accordance with the test plan( ) prepared and approved in response to the Test Specification 24590-WTP-TSP-RT-06-006, Rev 0 (Smith 2006). A fundamental premise is that this approach would allow blending of the different components to simulate a wide variety of feeds to be treated in the Hanford Tank Waste Treatment and Immobilization Plant (WTP). For example, a given feed from the planned feed vector could be selected, and the appropriate components would then be blended to achieve a representation of that particular feed. Using the blending of component simulants allows the representation of a much broader spectrum of potential feeds to the Pretreatment Engineering Platform (PEP).

  12. Selective Filtration of Gadolinium Trichloride for Use in Neutron Detection in Large Water Cherenkov Detectors

    SciTech Connect (OSTI)

    Vagins, Mark R.

    2013-04-10T23:59:59.000Z

    Water Cherenkov detectors have been used for many years as inexpensive, effective detectors for neutrino interactions and nucleon decay searches. While many important measurements have been made with these detectors a major drawback has been their inability to detect the absorption of thermal neutrons. We believe an inexpensive, effective technique could be developed to overcome this situation via the addition to water of a solute with a large neutron cross section and energetic gamma daughters which would make neutrons detectable. Gadolinium seems an excellent candidate especially since in recent years it has become very inexpensive, now less than $8 per kilogram in the form of commercially-available gadolinium trichloride, GdCl{sub 3}. This non-toxic, non-reactive substance is highly soluble in water. Neutron capture on gadolinium yields a gamma cascade which would be easily seen in detectors like Super-Kamiokande. We have been investigating the use of GdCl{sub 3} as a possible upgrade for the Super-Kamiokande detector with a view toward improving its performance as a detector for atmospheric neutrinos, supernova neutrinos, wrong-sign solar neutrinos, reactor neutrinos, proton decay, and also as a target for the coming T2K long-baseline neutrino experiment. This focused study of selective water filtration and GdCl{sub 3} extraction techniques, conducted at UC Irvine, followed up on highly promising benchtop-scale and kiloton-scale work previously carried out with the assistance of 2003 and 2005 Advanced Detector Research Program grants.

  13. Dust filtration at gap edges: Implications for the spectral energy distributions of discs with embedded planets

    E-Print Network [OSTI]

    W. K. M. Rice; Philip J. Armitage; Kenneth Wood; Giuseppe Lodato

    2006-09-29T23:59:59.000Z

    The spectral energy distributions (SEDs) of some T Tauri stars display a deficit of near-IR flux that could be a consequence of an embedded Jupiter-mass planet partially clearing an inner hole in the circumstellar disc. Here, we use two-dimensional numerical simulations of the planet-disc interaction, in concert with simple models for the dust dynamics, to quantify how a planet influences the dust at different radii within the disc. We show that pressure gradients at the outer edge of the gap cleared by the planet act as a filter - letting particles smaller than a critical size through to the inner disc while holding back larger particles in the outer disc. The critical particle size depends upon the disc properties, but is typically of the order of 10 microns. This filtration process will lead to discontinuous grain populations across the planet's orbital radius, with small grains in the inner disc and an outer population of larger grains. We show that this type of dust population is qualitatively consistent with SED modelling of systems that have optically thin inner holes in their circumstellar discs. This process can also produce a very large gas-to-dust ratio in the inner disc, potentially explaining those systems with optically thin inner cavities that still have relatively high accretion rates.

  14. Morphology of Nano and Micro Fiber Structures in Ultrafine Particles Filtration

    SciTech Connect (OSTI)

    Kimmer, Dusan; Vincent, Ivo; Fenyk, Jan; Petras, David [SPUR a.s., T. Bati 299, 764 22 Zlin (Czech Republic); Zatloukal, Martin; Sambaer, Wannes [Centre of Polymer Systems, Polymer Centre, Tomas Bata University in Zlin, nam. T. G. Masaryka 5555, 760 01 Zlin (Czech Republic); Zdimal, Vladimir [Institute of Chemical Process Fundamentals of the AS CR, v.v.i., Rozvojova 135, 165 02 Praha 6 (Czech Republic)

    2011-07-15T23:59:59.000Z

    Selected procedures permitting to prepare homogeneous nanofibre structures of the desired morphology by employing a suitable combination of variables during the electrospinning process are presented. A comparison (at the same pressure drop) was made of filtration capabilities of planar polyurethane nanostructures formed exclusively by nanofibres, space polycarbonate nanostructures having bead spacers, structures formed by a combination of polymethyl methacrylate micro- and nanofibres and polypropylene meltblown microstructures, through which ultrafine particles of ammonium sulphate 20-400 nm in size were filtered. The structures studied were described using a new digital image analysis technique based on black and white images obtained by scanning electron microscopy. More voluminous structures modified with distance microspheres and having a greater thickness and mass per square area of the material, i.e. structures possessing better mechanical properties, demanded so much in nanostructures, enable preparation of filters having approximately the same free volume fraction as flat nanofibre filters but an increased effective fibre surface area, changed pore size morphology and, consequently, a higher filter quality.

  15. DECONTAMINATION FACTORS AND FILTRATION FLUX IMPACT TO ARP AT REDUCED MST CONCENTRATION

    SciTech Connect (OSTI)

    Hobbs, D.

    2012-06-27T23:59:59.000Z

    Tank Farm and Closure Engineering is evaluating changes to the Actinide Removal Process facility operations to decrease the MST concentration from 0.4 g/L to 0.2 g/L and the contact time from 12 hours to between 6 and 8 hours. For this evaluation, SRNL reviewed previous datasets investigating the performance of MST at 0.2 g/L in salt solutions ranging from 4.5 to 7.5 M in sodium concentration. In general, reducing the MST concentration from 0.4 to 0.2 g/L and increasing the ionic strength from 4.5 to 7.5 M in sodium concentration will decrease the measured decontamination factors for plutonium, neptunium, uranium and strontium. The decontamination factors as well as single standard deviation values for each sorbate are reported. These values are applicable within the sorbate and sodium concentrations used in the experimental measurements. Decreasing the MST concentration in the ARP from 0.4 g/L to 0.2 g/L will produce an increase in the filter flux, and could lead to longer operating times between filter cleaning. The increase in flux is a function of a number of operating parameters, and is difficult to quantify. However, it is estimated that the reduction in MST could result in a reduction of filtration time of up to 20%.

  16. The influence of zeta potential and yield stress on the filtration characteristics of a magnesium hydroxide simulant

    SciTech Connect (OSTI)

    Biggs, Simon; Nabi, Rafiq; Poole, Colin [Leeds University/Nexia Solutions URA in Particle Science and Technology, Institute of Particle Science and Engineering, School of Process, Environmental and Materials Engineering, The University of Leeds, Leeds LS2 9JT (United Kingdom); Patel, Ashok [British Nuclear Group, Reactor Sites, Berkeley Centre, Berkeley, Gloucestershire, GL13 9PB (United Kingdom)

    2007-07-01T23:59:59.000Z

    In the UK, irradiated fuels from Magnox reactors are often stored in water-filled ponds under alkaline conditions, so as to minimise corrosion of fuel cladding. This is important to prevent or reduce leakage of soluble fission products and actinides to the pond water. A variety of intermediate level wastes derived from Magnox materials are stored at power stations. Under these alkaline conditions, various species of magnesium are formed, of which magnesium hydroxide is the dominant material. The particle-fluid interactions are significant for the design and operation of facilities for hydraulic retrieval, filtration, dewatering and ion exchange treatment of fuel storage pond water and stored wet Magnox wastes. Here we describe a study of particulate properties and filtration characteristics of oxide particle simulants under laboratory conditions. Cake and medium resistance data were correlated across a range of pH conditions with electro-acoustic zeta potential and shear yield stress measurements, as a function of particle volume fractions. The influence of zeta potential on filtration properties arises directly from the interaction of particles within the sediment cake. (authors)

  17. The effects of selected environmental variables on filtration rate of Mytilopsis leucophaeata and evaluation of its potential role in the purification of mariculture effluent

    E-Print Network [OSTI]

    Rice, Patrick Hays

    2000-01-01T23:59:59.000Z

    Laivlotte 2020 turbidity meter (Table I). Cuttlefish ink, colloidal carbon suspensions, microalgae cultures and mariculture eIHuent were used to provide measurable suspended particles which could be removed by the mussel filtration apparatus in order... concentration versus filtration rate, including Aquadag?, Sepia ink and cultured Nannoch/orops/s (microalgae). A specific amount of each colloid was suspended in filtered seawater Concentrations were estimated by relative turbidity measurements. Wang (1990...

  18. DEMONSTRATION OF THE NEXT-GENERATION CAUSTIC-SIDE SOLVENT EXTRACTION SOLVENT WITH 2-CM CENTRIFUGAL CONTRACTORS USING TANK 49H WASTE AND WASTE SIMULANT

    SciTech Connect (OSTI)

    Pierce, R.; Peters, T.; Crowder, M.; Caldwell, T.; Pak, D; Fink, S.; Blessing, R.; Washington, A.

    2011-09-27T23:59:59.000Z

    Researchers successfully demonstrated the chemistry and process equipment of the Caustic-Side Solvent Extraction (CSSX) flowsheet using MaxCalix for the decontamination of high level waste (HLW). The demonstration was completed using a 12-stage, 2-cm centrifugal contactor apparatus at the Savannah River National Laboratory (SRNL). This represents the first CSSX process demonstration of the MaxCalix solvent system with Savannah River Site (SRS) HLW. Two tests lasting 24 and 27 hours processed non-radioactive simulated Tank 49H waste and actual Tank 49H HLW, respectively. Conclusions from this work include the following. The CSSX process is capable of reducing {sup 137}Cs in high level radioactive waste by a factor of more than 40,000 using five extraction, two scrub, and five strip stages. Tests demonstrated extraction and strip section stage efficiencies of greater than 93% for the Tank 49H waste test and greater than 88% for the simulant waste test. During a test with HLW, researchers processed 39 liters of Tank 49H solution and the waste raffinate had an average decontamination factor (DF) of 6.78E+04, with a maximum of 1.08E+05. A simulant waste solution ({approx}34.5 liters) with an initial Cs concentration of 83.1 mg/L was processed and had an average DF greater than 5.9E+03, with a maximum DF of greater than 6.6E+03. The difference may be attributable to differences in contactor stage efficiencies. Test results showed the solvent can be stripped of cesium and recycled for {approx}25 solvent turnovers without the occurrence of any measurable solvent degradation or negative effects from minor components. Based on the performance of the 12-stage 2-cm apparatus with the Tank 49H HLW, the projected DF for MCU with seven extraction, two scrub, and seven strip stages operating at a nominal efficiency of 90% is {approx}388,000. At 95% stage efficiency, the DF in MCU would be {approx}3.2 million. Carryover of organic solvent in aqueous streams (and aqueous in organic streams) was less than 0.1% when processing Tank 49H HLW. The entrained solvent concentration measured in the decontaminated salt solution (DSS) was as much as {approx}140 mg/L, although that value may be overstated by as much as 50% due to modifier solubility in the DSS. The entrained solvent concentration was measured in the strip effluent (SE) and the results are pending. A steady-state concentration factor (CF) of 15.9 was achieved with Tank 49H HLW. Cesium distribution ratios [D(Cs)] were measured with non-radioactive Tank 49H waste simulant and actual Tank 49H waste. Below is a comparison of D(Cs) values of ESS and 2-cm tests. Batch Extraction-Strip-Scrub (ESS) tests yielded D(Cs) values for extraction of {approx}81-88 for tests with Tank 49H waste and waste simulant. The results from the 2-cm contactor tests were in agreement with values of 58-92 for the Tank 49H HLW test and 54-83 for the simulant waste test. These values are consistent with the reference D(Cs) for extraction of {approx}60. In tests with Tank 49H waste and waste simulant, batch ESS tests measured D(Cs) values for the two scrub stages as {approx}3.5-5.0 for the first scrub stage and {approx}1.0-3.0 for the second scrub stage. In the Tank 49H test, the D(Cs) values for the 2-cm test were far from the ESS values. A D(Cs) value of 161 was measured for the first scrub stage and 10.8 for the second scrub stage. The data suggest that the scrub stage is not operating as effectively as intended. For the simulant test, a D(Cs) value of 1.9 was measured for the first scrub stage; the sample from the second scrub stage was compromised. Measurements of the pH of all stage samples for the Tank 49H test showed that the pH for extraction and scrub stages was 14 and the pH for the strip stages was {approx}7. It is expected that the pH of the second scrub stage would be {approx}12-13. Batch ESS tests measured D(Cs) values for the strip stages to be {approx}0.002-0.010. A high value in Strip No.3 of a test with simulant solution has been attributed to issues associated with the limits of detection for the

  19. Filtrations in Dyson-Schwinger equations: next-to^{j} -leading log expansions systematically

    E-Print Network [OSTI]

    Olaf Krueger; Dirk Kreimer

    2015-02-11T23:59:59.000Z

    Dyson-Schwinger equations determine the Green functions $G^r(\\alpha,L)$ in quantum field theory. Their solutions are triangular series in a coupling constant $\\alpha$ and an external scale parameter $L$ for a chosen amplitude $r$, with the order in $L$ bounded by the order in the coupling. Perturbation theory calculates the first few orders in $\\alpha$. On the other hand, Dyson--Schwinger equations determine next-to$^{\\{\\mathrm{j}\\}}$-leading log expansions, $G^r(\\alpha,L) = 1 + \\sum_{j=0}^\\infty \\sum_{\\mathcal{M}} p_j^{\\mathcal{M}}\\alpha^j \\mathcal{M}(u)$. $\\sum_{\\mathcal{M}}$ sums a finite number of functions $\\mathcal{M}$ in $u = \\alpha L/2$. The leading logs come from the trivial representation $\\mathcal{M}(u) = \\begin{bsmallmatrix}\\bullet\\end{bsmallmatrix}(u)$ at $j=0$ with $p_0^{\\begin{bsmallmatrix}\\bullet\\end{bsmallmatrix}} = 1$. All non-leading logs are organized by the suppression in powers $\\alpha^j$. We describe an algebraic method to derive all next-to$^{\\{\\mathrm{j}\\}}$-leading log terms from the knowledge of the first $(j+1)$ terms in perturbation theory and their filtrations. This implies the calculation of the functions $\\mathcal{M}(u)$ and periods $p_j^\\mathcal{M}$. In the first part of our paper, we investigate the structure of Dyson-Schwinger equations and develop a method to filter their solutions. Applying renormalized Feynman rules maps each filtered term to a certain power of $\\alpha$ and $L$ in the log-expansion. Based on this, the second part derives the next-to$^{\\{\\mathrm{j}\\}}$-leading log expansions. Our method is general. Here, we exemplify it using the examples of the propagator in Yukawa theory and the photon self-energy in quantum electrodynamics. The reader may apply our method to any (set of) Dyson-Schwinger equation(s) appearing in renormalizable quantum field theories.

  20. Final Report: Pilot-Scale X-Flow Filtration Test - Env C Plus Entrained Solids Plus Sr/TRU

    SciTech Connect (OSTI)

    Duignan, M.R.

    2000-07-27T23:59:59.000Z

    This report discusses the results of the operation of a cross-flow filter in a pilot-scale experimental facility that was designed, built, and run by the Experimental Thermal Fluids Laboratory of the Savannah River Technology Center of the Westinghouse Savannah River Company. This filtration technology was evaluated for its inclusion in the pretreatment section of the nuclear waste stabilization plant being designed by BNFL, Inc. The plant will be built at the U.S. Department of Energy's Hanford Site as part of the River Protection Project.

  1. Characterization, Leaching, and Filtration Testing for Bismuth Phosphate Sludge (Group 1) and Bismuth Phosphate Saltcake (Group 2) Actual Waste Sample Composites

    SciTech Connect (OSTI)

    Lumetta, Gregg J.; Buck, Edgar C.; Daniel, Richard C.; Draper, Kathryn; Edwards, Matthew K.; Fiskum, Sandra K.; Hallen, Richard T.; Jagoda, Lynette K.; Jenson, Evan D.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Shimskey, Rick W.; Sinkov, Sergey I.; Snow, Lanee A.

    2009-02-19T23:59:59.000Z

    A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan.() The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. The actual waste-testing program included homogenizing the samples by group, characterizing the solids and aqueous phases, and performing parametric leaching tests. Two of the eight defined groups—bismuth phosphate sludge (Group 1) and bismuth phosphate saltcake (Group 2)—are the subjects of this report. The Group 1 waste was anticipated to be high in phosphorus and was implicitly assumed to be present as BiPO4 (however, results presented here indicate that the phosphate in Group 1 is actually present as amorphous iron(III) phosphate). The Group 2 waste was also anticipated to be high in phosphorus, but because of the relatively low bismuth content and higher aluminum content, it was anticipated that the Group 2 waste would contain a mixture of gibbsite, sodium phosphate, and aluminum phosphate. Thus, the focus of the Group 1 testing was on determining the behavior of P removal during caustic leaching, and the focus of the Group 2 testing was on the removal of both P and Al. The waste-type definition, archived sample conditions, homogenization activities, characterization (physical, chemical, radioisotope, and crystal habit), and caustic leaching behavior as functions of time, temperature, and hydroxide concentration are discussed in this report. Testing was conducted according to TP-RPP-WTP-467.

  2. Pyrolysis Oil Stabilization: Hot-Gas Filtration; Cooperative Research and Development Final Report, CRADA Number CRD-09-333

    SciTech Connect (OSTI)

    Baldwin, R.

    2012-07-01T23:59:59.000Z

    The hypothesis that was tested in this task was that separation of char, with its associated mineral matter from pyrolysis vapors before condensation, will lead to improved oil quality and stability with respect to storage and transportation. The metric used to evaluate stability in this case was a 10-fold reduction in the rate of increase of viscosity as determined by ASTM D445 (the accelerated aging test). The primary unit operation that was investigated for this purpose was hot-gas filtration. A custom-built heated candle filter system was fabricated by the Pall Corporation and furnished to NREL for this test campaign. This system consisted of a candle filter element in a containment vessel surrounded by heating elements on the external surface of the vessel. The filter element and housing were interfaced to NREL?s existing 0.5 MTD pyrolysis Process Development Unit (PDU). For these tests the pyrolysis reactor of the PDU was operated in the entrained-flow mode. The HGF test stand was installed on a slipstream from the PDU so that both hot-gas filtered oil and bio-oil that was not hot-gas filtered could be collected for purposes of comparison. Two filter elements from Pall were tested: (1) porous stainless steel (PSS) sintered metal powder; (2) sintered ceramic powder. An extremely sophisticated bio-oil condensation and collection system was designed and fabricated at NREL and interfaced to the filter unit.

  3. A Ceramic membrane to Recycle Caustic

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613Portsmouth SitePresentations | Department ofCouncil OfficialsA Banner Year forA Ceramic

  4. Emulsions for interfacial filtration.

    SciTech Connect (OSTI)

    Grillet, Anne Mary; Bourdon, Christopher Jay; Souza, Caroline Ann; Welk, Margaret Ellen; Hartenberger, Joel David; Brooks, Carlton, F.

    2006-11-01T23:59:59.000Z

    We have investigated a novel emulsion interfacial filter that is applicable for a wide range of materials, from nano-particles to cells and bacteria. This technology uses the interface between the two immiscible phases as the active surface area for adsorption of targeted materials. We showed that emulsion interfaces can effectively collect and trap materials from aqueous solution. We tested two aqueous systems, a bovine serum albumin (BSA) solution and coal bed methane produced water (CBMPW). Using a pendant drop technique to monitor the interfacial tension, we demonstrated that materials in both samples were adsorbed to the liquid-liquid interface, and did not readily desorb. A prototype system was built to test the emulsion interfacial filter concept. For the BSA system, a protein assay showed a progressive decrease in the residual BSA concentration as the sample was processed. Based on the initial prototype operation, we propose an improved system design.

  5. Evaluation of the 183-D Water Filtration Facility for Bat Roosts and Development of a Mitigation Strategy, 100-D Area, Hanford Site

    SciTech Connect (OSTI)

    Lindsey, C. T.; Gano, K. A.; Lucas, J. G.

    2011-03-07T23:59:59.000Z

    The 183-D Water Filtration Facility is located in the 100-D Area of the Hanford Site, north of Richland, Washington. It was used to provide filtered water for cooling the 105-D Reactor and supplying fire-protection and drinking water for all facilities in the 100-D Area. The facility has been inactive since the 1980s and is now scheduled for demolition. Therefore, an evaluation was conducted to determine if any part of the facility was being used as roosting habitat by bats.

  6. Laplacian Growth II: Saffman - Taylor Problem Without Surface Tension in Filtration Combustion: Formation of One Finger with Half of the Channel Width

    E-Print Network [OSTI]

    Oleg Kupervasser

    2014-05-22T23:59:59.000Z

    Filtration combustion is described by Laplacian growth without surface tension. These equations have elegant analytical solutions that replace the complex integro-differential motion equations by simple differential equations of pole motion in a complex plane. The main problem with such a solution is the existence of finite time singularities. To prevent such singularities, nonzero surface tension is usually used.However, nonzero surface tension does not exist in filtration combustion, and this destroys the analytical solutions. However, a more elegant approach exists for solving the problem. First, we can introduce a small amount of pole noise to the system. Second, for regularisation of the problem, we throw out all new poles that can produce a finite time singularity. It can be strictly proved that the asymptotic solution for such a system is a single finger. Moreover, the qualitative consideration demonstrates that a finger with 1/2 of the channel width is statistically stable. Therefore, all properties of such a solution are exactly the same as those of the solution with nonzero surface tension under numerical noise. The solution of the ST problem without surface tension is similar to the solution for the equation of cellular flames in the case of the combustion of gas mixtures.

  7. Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report, October--December 1996

    SciTech Connect (OSTI)

    Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

    1996-12-31T23:59:59.000Z

    A portion of each filtrate sample was freeze-dried and the resulting solids were analyzed for ash content. Adsorption experiments with calcium and barium were carried at 70{degrees}C in a temperature controlled incubator under continuous mixing in order to simulate the environment experienced by brownstock as it moves through the Q stage. In the calcium experiments, it was difficult to accurately determine the calcium adsorbed on the pulp by measuring the depletion of calcium in the aqueous phase. Consequently, the technique was modified. In the modified technique, the calcium-adsorbed pulp is acid washed again to release the calcium. The calcium concentration in the washings is measured, and the calcium adsorbed on the pulp is estimated by material balance. Measurement of calcium adsorption on the brownstock pulp fibers from the L-P/Samoa mill have been obtained.

  8. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Quarterly technical progress report, October 1--December 31, 1993

    SciTech Connect (OSTI)

    Weber, G.F.; Ness, S.R.; Schelkoph, G.L.

    1994-01-01T23:59:59.000Z

    The EERC approach to meeting the program objective involves the development of a CFF for simultaneous NO. and particulate control. The idea of applying either a permanent or throwaway catalyst to a high-temperature fabric filter for NO. control is not new (1--4). However, advances at OCF have shown that a high-activity catalyst can be applied to a high-temperature woven glass cloth, resulting in a fabric filter material that can operate at temperatures higher than commercially available, coated glass fabric. The NO. is removed by catalytic reduction with ammonia to form nitrogen and water. The catalyst employed at this time is vanadium-titanium, but the exact catalyst composition and the unique method of applying the catalyst to high-temperature glass fabric are the property of OCF (5). Other catalyst options are being evaluated by OCF in order to improve catalyst performance and minimize catalyst cost. Bench-scale experimental results have shown that over 90% NO. removal can be achieved, that the catalyst-coated fabric has promising self-abrasion characteristics, and that the potential exists for substantially reduced cost compared to conventional SCR and fabric filtration technologies (6,7). However, development of the technology required further evaluation of air-to-cloth ratio effects, ammonia slip, SO{sub 2} oxidation to SO{sub 3}, temperature cycling, catalyst-coated fabric preparation, fuel impacts, fabric cleaning (reverse-gas versus pulse-jet), catalyst life (poisoning and resistance to erosion), and filter performance/life (particulate control, differential pressure, and durability).

  9. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Quarterly technical progress report, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Weber, G.F.; Ness, S.R.; Laudal, D.L.; Dunham, G.E.

    1993-08-01T23:59:59.000Z

    The University of North Dakota Energy & Environmental Research Center (EERC), Owens-Corning Fiberglas Corporation (OCF), and Raytheon Engineers & Constructors (RE&C), are conducting research to develop a catalytic fabric filter (CFF) for simultaneous NO{sub x} and particulate control. Advances at OCF have shown that a high-activity catalyst can be applied to a high-temperature woven glass cloth resulting in a fabric filter material that can operate at temperatures higher than commercially available, coated glass fabric. The NO{sub x} is removed by catalytic reduction with ammonia to form nitrogen and water. The catalyst employed at this time is vanadium/titanium, but the exact catalyst composition and the unique method of applying the catalyst to high-temperature glass fabric are the property of OCF. Other catalyst options are being evaluated by OCF in order to improve catalyst performance and minimize catalyst cost. Bench-scale experimental results have shown that over 90% NO{sub x} removal can be achieved, that the catalyst/fabric has promising self-abrasion characteristics, and that the potential exists for substantially reduced cost compared to conventional SCR/fabric filtration technology. However, development of the technology requires further evaluation of air-to-cloth ratio effects, ammonia slip, SO{sub 2} oxidation to SO{sub 3}, temperature cycling, catalyst-coated fabric preparation, fuel impacts, fabric cleaning (reverse-gas versus pulse-jet), catalyst life (poisoning and resistance to erosion), and filter performance/life (particulate control, differential pressure, and durability).

  10. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Quarterly technical progress report, July 1--September 30, 1993

    SciTech Connect (OSTI)

    Weber, G.F.; Ness, S.R.; Schelkoph, G.L.

    1993-11-01T23:59:59.000Z

    The EERC approach to meeting the program objective involves the development of a CFF for simultaneous NO{sub x} and particulate control. The idea of applying either a permanent or throwaway catalyst to a high-temperature fabric filter for NO{sub x} control is not new. However, advances at OCF have shown that a high-activity catalyst can be applied to a high-temperature woven glass cloth, resulting in a fabric filter material that can operate at temperatures higher than commercially available, coated glass fabric. The NO{sub x} is removed by catalytic reduction with ammonia to form nitrogen and water. The catalyst employed at this time is vanadium-titanium, but the exact catalyst composition and the unique method of applying the catalyst to high-temperature glass fabric are the property of OCF. Other catalyst options are being evaluated by OCF in order to improve catalyst performance and minimize catalyst cost. Bench-scale experimental results have shown that over 90% NO{sub x} removal can be achieved, that the catalyst-fabric has promising self-abrasion characteristics, and that the potential exists for substantially reduced cost compared to conventional SCR and fabric filtration technologies. However, development of the technology required further evaluation of air-to-cloth ratio effects, ammonia slip, SO{sub 2} oxidation to SO{sub 3}, temperature cycling, catalyst-coated fabric preparation, fuel impacts, fabric cleaning (reverse-gas versus pulse-jet), catalyst life (poisoning and resistance to erosion), and filter performance/life (particulate control, differential pressure, and durability).

  11. Water nano-filtration device

    DOE Patents [OSTI]

    Judkins, Roddie R. (Knoxville, TN) [Knoxville, TN

    2009-02-03T23:59:59.000Z

    A water filter includes a porous support characterized by a mean porosity in the range of 20 to 50% and a mean pore size of 2 to 5 .mu.m; and a carbon filter membrane disposed thereon which is characterized by a mean particle size of no more than 50 .mu.m and a mean pore size of no more than 7.2 .mu.m.

  12. Water Filtration Using Plant Xylem

    E-Print Network [OSTI]

    Boutilier, Michael Stephen Ha

    Effective point-of-use devices for providing safe drinking water are urgently needed to reduce the global burden of waterborne disease. Here we show that plant xylem from the sapwood of coniferous trees – a readily available, ...

  13. Chemical filtration for steam purity

    SciTech Connect (OSTI)

    Kovalcik, F.

    1985-03-01T23:59:59.000Z

    Few industrial process systems are as vulnerable to corrosion as the steam generating loop of an electric power plant. Impurities inevitably migrate into the steam cycle, and must be removed to prevent turbine blade corrosion. It is critical to understand the behavior of the condensate polishing resins used to remove the impurities. The Electric Power Research Institute (EPRI) participated in investigations involving ion chromatography which identified chloride as a problem in studies of regeneration and polishing procedures. A modified regeneration procedure consists of ammonium sulfate treatment of the resin before and after ammonia recirculation, followed by a dilute ammonia rinse. A joint study with Southern California Edison also simulated condenser leaks to find the effect of cooling water intrusion.

  14. THE GEODESIC X-RAY TRANSFORM WITH FOLD CAUSTICS The ...

    E-Print Network [OSTI]

    2012-08-28T23:59:59.000Z

    Aug 28, 2012 ... D d expq0 .w0/ PJ.1/ because. ?k @w. @vk .p0;v0/ D ?k @. @vk d dt. ?. ?. ?tD1 ..... flow-out of .x0;?0/ as the Hs norm in those coordinates w.r.t. the measure d. We can ... 0 follows by interpolation, see, e.g., [27, Sec 4.2]. To finish ...

  15. Experimental investigation of caustic steam injection for heavy oils

    E-Print Network [OSTI]

    Madhavan, Rajiv

    2010-01-16T23:59:59.000Z

    CHAPTER I INTRODUCTION 1.1 Overview Heavy oil is a part of the unconventional petroleum reserve. Heavy oil does not flow very easily and is classified as heavy because of its high specific gravity. With increasing demand for oil and with depleting... and success of the sodium carbonate and sodium silicate floods respectively. (5) Attainment of very low interfacial tension does not ensure improved oil recovery but a minimum value is necessary for a successful steam alkaline flood. Tiab, Okoye...

  16. Physical process first law and caustic avoidance for Rindler horizon

    E-Print Network [OSTI]

    Srijit Bhattacharjee; Sudipta Sarkar

    2014-12-03T23:59:59.000Z

    We study the perturbation induced by a slowly rotating massive object as it passes through a Rindler horizon. It is shown that the passage of this object can be approximately modeled as Delta\\,function type tidal distortions hitting the horizon. Further, following the analysis presented by Amsel, Marolf and Virmani related to the issue of the validity of physical process first law, we establish a condition on the size of the object so that this law holds for the Rindler horizon.

  17. A Ceramic membrane to Recycle Caustic | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China 2015ofDepartmentDepartment of Energy This documentFormer WorkerTheA Ceramic

  18. Jiangxi Ganzhong Chlorine Caustic Company aka China Jiangxi Chlor Alkali

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunanInformationJamesManufacturing | Open Energy

  19. Growth of sheets in 3D confinements - a model for the C-S-H meso 2 structure

    E-Print Network [OSTI]

    Etzold, Merlin A.; McDonald, Peter J.; Routh, Alexander F.

    2014-06-21T23:59:59.000Z

    - and dicalcium silicate surfaces on particle aggre-41 gation [8]. Particle based models have also been used by the group of Ulm to successfully interpret nano42 indentation results [9]. Small-angle neutron scattering data of cement paste has been interpreted... -vectors, both curves show a q?4 dependence which corresponds to203 the experimental Porod regime. The simulated data is compared to experimental small-angle neutron204 scattering data for cement from Allen et al. (dashed) [30]. For large and intermediate...

  20. Associations of blood lead, cadmium, and mercury with estimated glomerular filtration rate in the Korean general population: Analysis of 2008-2010 Korean National Health and Nutrition Examination Survey data

    SciTech Connect (OSTI)

    Kim, Yangho [Department of Occupational and Environmental Medicine, Ulsan University Hospital, University of Ulsan College of Medicine, Ulsan (Korea, Republic of)] [Department of Occupational and Environmental Medicine, Ulsan University Hospital, University of Ulsan College of Medicine, Ulsan (Korea, Republic of); Lee, Byung-Kook, E-mail: bklee@sch.ac.kr [Institute of Environmental and Occupational Medicine, Soonchunhyang University 646 Eupnae-ri, Shinchang-myun, Asan-si, Choongnam 336-745 (Korea, Republic of)] [Institute of Environmental and Occupational Medicine, Soonchunhyang University 646 Eupnae-ri, Shinchang-myun, Asan-si, Choongnam 336-745 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Introduction: The objective of this study was to evaluate associations between blood lead, cadmium, and mercury levels with estimated glomerular filtration rate in a general population of South Korean adults. Methods: This was a cross-sectional study based on data obtained in the Korean National Health and Nutrition Examination Survey (KNHANES) (2008-2010). The final analytical sample consisted of 5924 participants. Estimated glomerular filtration rate (eGFR) was calculated using the MDRD Study equation as an indicator of glomerular function. Results: In multiple linear regression analysis of log2-transformed blood lead as a continuous variable on eGFR, after adjusting for covariates including cadmium and mercury, the difference in eGFR levels associated with doubling of blood lead were -2.624 mL/min per 1.73 m Superscript-Two (95% CI: -3.803 to -1.445). In multiple linear regression analysis using quartiles of blood lead as the independent variable, the difference in eGFR levels comparing participants in the highest versus the lowest quartiles of blood lead was -3.835 mL/min per 1.73 m Superscript-Two (95% CI: -5.730 to -1.939). In a multiple linear regression analysis using blood cadmium and mercury, as continuous or categorical variables, as independent variables, neither metal was a significant predictor of eGFR. Odds ratios (ORs) and 95% CI values for reduced eGFR calculated for log2-transformed blood metals and quartiles of the three metals showed similar trends after adjustment for covariates. Discussion: In this large, representative sample of South Korean adults, elevated blood lead level was consistently associated with lower eGFR levels and with the prevalence of reduced eGFR even in blood lead levels below 10 {mu}g/dL. In conclusion, elevated blood lead level was associated with lower eGFR in a Korean general population, supporting the role of lead as a risk factor for chronic kidney disease.

  1. FILTRATION EFFICIENCIES OF BOOTHBAY DEPRESSOR TRAWLS

    E-Print Network [OSTI]

    opening of 4 mm was determined in a flume (circulating water chan- nel) at the U.S. Navy's David Taylor Model Basin under experimental conditions as de- scribed by Mahnken and Jossi (1967). Veloci- ties

  2. CONDITIONING AND INITIAL ENLARGEMENT OF FILTRATION ON ...

    E-Print Network [OSTI]

    2004-09-03T23:59:59.000Z

    CSDES ON A MANIFOLD. 2303. [14] FITZSIMMONS, P., PITMAN, J. W. and YOR, M. (1993). Markovian bridges, construction, Palm interpretation and splicing.

  3. FILTRATION ASSOCIATED TO TORSION SEMI-STABLE ...

    E-Print Network [OSTI]

    2014-09-12T23:59:59.000Z

    sociated torsion semi-stable representations of G. In particular, we prove that ... Let k be a perfect field of characteristic p ? 3, W(k) its ring of Witt vectors,.

  4. Filtration for Metals Removal from Stormwater Runoff

    E-Print Network [OSTI]

    Clark, Shirley E.

    Waste ­ Peat-Sand Mix ­ Kudzu ­ Peanut Hull Pellets MetalsMetals Copper,Cadmium, Chromium, Zinc, Lead CAPACITIES FOR COPPER #12;2 Capacity of Media for Zn 0 10 20 30 40 50 60 70 80 90 100 TP 207*Com post Kudzu-Sand M ix Cotton W aste Sand gZn/kgmedia 14 16 0 2 4 6 8 10 12 14 Compost Kudzu PeanutHulls St

  5. Thermophilic Biotrickling Filtration of Ethanol Vapors

    E-Print Network [OSTI]

    .g., from the tobacco, (4) the pulp and paper, (5) and food industry (6). One option is cooling these gases containing organic packing materials: treatment of NOx at 55 °C, (7) co-treatment of methanol and R temperatures. High operating temperatures accelerate the degradation of the organic packing material, (4, 9)

  6. Methods for microbial filtration of fluids

    DOE Patents [OSTI]

    Carman, Margaret L. (San Ramon, CA); Jackson, Kenneth J. (San Leandro, CA); Knapp, Richard B. (Danville, CA); Knezovich, John P. (Stockton, CA); Shah, Nilesh N. (Livermore, CA); Taylor, Robert T. (Livermore, CA)

    1996-01-01T23:59:59.000Z

    Novel methods for purifying contaminated subsurface groundwater are disclosed. The method is involves contacting the contaminated subsurface groundwater with methanotrophic or heterotrophic microorganisms which produce contaminant-degrading enzymes. The microorganisms are derived from surface cultures and are injected into the ground so as to act as a biofilter. The contaminants which may be treated include organic or metallic materials and radionuclides.

  7. Methods for microbial filtration of fluids

    DOE Patents [OSTI]

    Carman, M.L.; Jackson, K.J.; Knapp, R.B.; Knezovich, J.P.; Shah, N.N.; Taylor, R.T.

    1996-01-30T23:59:59.000Z

    Novel methods for purifying contaminated subsurface groundwater are disclosed. The method is involves contacting the contaminated subsurface groundwater with methanotrophic or heterotrophic microorganisms which produce contaminant-degrading enzymes. The microorganisms are derived from surface cultures and are injected into the ground so as to act as a biofilter. The contaminants which may be treated include organic or metallic materials and radionuclides. 8 figs.

  8. Side Stream Filtration for Cooling Towers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretary of EnergyFocus GroupSherrell R. Greene AboutSide Stream

  9. Sandusky Water Filtration | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ |Rippey Jump to:WY)Project JumpSanMiguel,WastewaterWater

  10. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  11. Bench-Scale Cross Flow Filtration of

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0 ACRF8

  12. Bench-Scale Cross Flow Filtration of

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  13. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0 ACRF892

  14. Bench-Scale Cross Flow Filtration of

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  15. Bench-Scale Cross Flow Filtration of

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  16. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0 ACRF

  17. Bench-Scale Cross Flow Filtration of

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  18. Bench-Scale Cross Flow Filtration of

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  19. Bench-Scale Cross Flow Filtration of

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  20. Bench-Scale Cross Flow Filtration of

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  1. Bench-Scale Cross Flow Filtration of

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  2. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  3. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  4. Bench-Scale Cross Flow Filtration of

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  5. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT04 ACRF567

  6. Bench-Scale Cross Flow Filtration of

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  7. Bench-Scale Cross Flow Filtration of

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  8. Bench-Scale Cross Flow Filtration of

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  9. Bench-Scale Cross Flow Filtration of

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  10. Bench-Scale Cross Flow Filtration of

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  11. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0498

  12. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT04981

  13. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT049811

  14. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0498110 A

  15. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0498110 A7

  16. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT0498110

  17. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT04981104

  18. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced Materials Find More Like3.3 PrintVultureBehavior ofDESERT04981104

  19. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC5 Science

  20. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC5

  1. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC51 ISDAC

  2. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC51 ISDAC2

  3. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC51 ISDAC24

  4. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC51 ISDAC246

  5. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC51 ISDAC2462

  6. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC51

  7. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC512 Cloud

  8. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC512 Cloud2

  9. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC512 Cloud23

  10. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC512 Cloud234

  11. Bench-Scale Cross Flow Filtration of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BESFor41BeforeAllen HPC512

  12. Hazard Analysis for the Pretreatment Engineering Platform (PEP)

    SciTech Connect (OSTI)

    Sullivan, Robin S.; Geeting, John GH; Lawrence, Wesley E.; Young, Jonathan

    2008-07-10T23:59:59.000Z

    The Pretreatment Engineering Platform (PEP) is designed to perform a demonstration on an engineering scale to confirm the Hanford Waste Treatment Plant Pretreatment Facility (PTF) leaching and filtration process equipment design and sludge treatment process. The system will use scaled prototypic equipment to demonstrate sludge water wash, caustic leaching, oxidative leaching, and filtration. Unit operations to be tested include pumping, solids washing, chemical reagent addition and blending, heating, cooling, leaching, filtration, and filter cleaning. In addition, the PEP will evaluate potential design changes to the ultrafiltration process system equipment to potentially enhance leaching and filtration performance as well as overall pretreatment throughput. The skid-mounted system will be installed and operated in the Processing Development Laboratory-West at Pacific Northwest National Laboratory (PNNL) in Richland, Washington.

  13. Resonant character of laser-induced formation of particles in a Cs-H2 vapour J. L. Picqu, J. Vergs and R. Vetter

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . This resonant character confirms the feasibility, which was also pointed out in the case of UF6 mole- cules [4

  14. EXAFS study of Nd(III) uptake by amorphous calcium silicate hydrates (CSH) P. Mandaliev a,b,*, R. Dhn a

    E-Print Network [OSTI]

    Wehrli, Bernhard

    EXAFS study of Nd(III) uptake by amorphous calcium silicate hydrates (C­S­H) P. Mandaliev a,b,*, R Accepted 3 June 2009 Available online 7 June 2009 Keywords: Amorphous calcium silicate hydrate (C Binding mechanisms Molecular level a b s t r a c t Calcium silicate hydrate (C­S­H) phases control

  15. Biosand filtration of high turbidity water : modified filter design and safe filtrate storage

    E-Print Network [OSTI]

    Collin, Clair

    2009-01-01T23:59:59.000Z

    Unsafe drinking water is a major cause of water-related diseases that predominantly affect people living in developing countries. The most prevalent water-related disease is diarrhea, estimated to kill 1.8 million children ...

  16. Caustic Recycle from Hanford Tank Waste Using Large Area NaSICON Structures (LANS)

    SciTech Connect (OSTI)

    Fountain, Matthew S.; Sevigny, Gary J.; Balagopal, S.; Bhavaraju, S.

    2009-03-31T23:59:59.000Z

    This report presents the results of a 5-day test of an electrochemical bench-scale apparatus using a proprietary (NAS-GY) material formulation of a (Na) Super Ion Conductor (NaSICON) membrane in a Large Area NaSICON Structures (LANS) configuration. The primary objectives of this work were to assess system performance, membrane seal integrity, and material degradation while removing Na from Group 5 and 6 tank waste from the Hanford Site.

  17. Extraction of long-lived radionuclides from caustic Hanford tank waste supernatants

    SciTech Connect (OSTI)

    Chaiko, D.J.; Mertz, C.J.; Vojta, Y. [and others

    1995-07-01T23:59:59.000Z

    A series of polymer-based extraction systems, based on the use of polyethylene glycols (PEGs) or polypropylene glycols (PPGs), was demonstrated to be capable of selective extraction and recovery of long-lived radionuclides, such as {sup 99}Tc and {sup 129}I, from Hanford SY-101 tank waste, neutralized current acid waste, and single-shell tank waste simulants. During the extraction process, anionic species like TcO{sub 4}{sup {minus}} and I{sup {minus}} are selectively transferred to the less dense PEG-rich aqueous phase. The partition coefficients for a wide range of inorganic cations and anions, such as sodium, potassium, aluminum, nitrate, nitrite, and carbonate, are all less than one. The partition coefficients for pertechnetate ranged from 12 to 50, depending on the choice of waste simulant and temperature. The partition coefficient for iodide was about 5, while that of iodate was about 0.25. Irradiation of the PEG phase with gamma-ray doses up to 20 Mrad had no detectable effect on the partition coefficients. The most selective extraction systems examined were those based on PPGs, which exhibited separation factors in excess of 3000 between TcO{sub 4}{sup {minus}} and NO{sub 3}{sup {minus}}/NO{sub 2}{sub {minus}}. An advantage of the PPG-based system is minimization of secondary waste production. These studies also highlighted the need for exercising great care in extrapolating the partitioning behavior with tank waste simulants to actual tank waste.

  18. In the Soup: Caustic Ingestion from the Improper Consumption of a Self-Heating Soup

    E-Print Network [OSTI]

    Hanson, Matthew; Hafner, John William

    2012-01-01T23:59:59.000Z

    Consumption of a Self-Heating Soup Matthew Hanson, MD John® Hillside made several self-heating food product canisters,with no readily available heating source to have hot soups

  19. Point source in a phononic grating: stop bands give rise to phonon-focusing caustics

    E-Print Network [OSTI]

    Maznev, Alex

    We use locally-excited gigahertz surface phonon wavepackets in microscopic line structures of different pitches to reveal profound anisotropy in the radiation pattern of a point source in a grating. Time-domain data obtained ...

  20. Design and Economic Evaluation of Thermionic Cogeneration in a Chlorine-Caustic Plant

    E-Print Network [OSTI]

    Miskolezy, G.; Morgan, D.; Turner, R.

    consists of four cell rooms. Each cell room has one cell circuit of 50 cells requiring 185 V and Work performed under DOE Contract DE-AC02-83CE40635 Roger Turner Crawford & Russell Incorporated Stamford, eN 70,000 A de. The power for the four... combust'ors allows factory assembly with signi ficant savings due to the lower cost of shop labor and the greater efficiency of factory operations. Examination of the other system costs (i.e., burner, burner support, boiler modi fications busbar...

  1. RESULTS OF PHYSICOCHEMICAL CHARACTERIZATION AND CAUSTIC DISSOLUTION TESTS ON TANK 241-C-108 HEEL SOLIDS

    SciTech Connect (OSTI)

    CALLAWAY WS; HUBER HJ

    2010-07-01T23:59:59.000Z

    Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

  2. The multiple quasar Q2237+0305 under a microlensing caustic

    E-Print Network [OSTI]

    T. Anguita; R. W. Schmidt; E. L. Turner; J. Wambsganss; R. L. Webster; K. A. Loomis; D. Long; R. McMillan

    2008-01-15T23:59:59.000Z

    We use the high magnification event seen in the 1999 OGLE campaign light curve of image C of the quadruply imaged gravitational lens Q2237+0305 to study the structure of the quasar engine. We have obtained g'- and r'-band photometry at the Apache Point Observatory 3.5m telescope where we find that the event has a smaller amplitude in the r'-band than in the g'- and OGLE V-bands. By comparing the light curves with microlensing simulations we obtain constraints on the sizes of the quasar regions contributing to the g'- and r'-band flux. Assuming that most of the surface mass density in the central kiloparsec of the lensing galaxy is due to stars and by modeling the source with a Gaussian profile, we obtain for the Gaussian width 1.20 x 10^15 sqrt(M/0.1M_sun)cm 72 percent confidence.

  3. Analytical Modeling of Cake Filtration Scott A. Wells

    E-Print Network [OSTI]

    Wells, Scott A.

    properties of kaolin suspensions in distilled water. Constitutive properties were determined by experiments to the analytical model predictions assuming that porosity and pressure were functions only of fractional cake that whenever the distribution of porosity was only a function of fractional cake position, #12;2 z/L, where z

  4. Hydraulic pump with in-ground filtration and monitoring capability

    DOE Patents [OSTI]

    Hopkins, C.D.; Livingston, R.R.; Toole, W.R. Jr.

    1995-01-01T23:59:59.000Z

    A hydraulically operated pump is described for in-ground filtering and monitoring of wells or other fluid sources, including a hollow cylindrical pump housing with an inlet and an outlet, filtering devices positioned in the inlet and the outlet, a piston that fits slidably within the pump housing, and an optical cell in fluid communication with the pump housing. A conduit within the piston allows fluid communication between the exterior and one end of the piston. A pair of O-rings form a seal between the inside of the pump housing and the exterior of the piston. A flow valve positioned within the piston inside the conduit allows fluid to flow in a single direction. In operation, fluid enters the pump housing through the inlet, flows through the conduit and towards an end of the pump housing. The piston then makes a downward stroke closing the valve, thus forcing the fluid out from the pump housing into the optical cell, which then takes spectrophotometric measurements of the fluid. A spring helps return the piston back to its starting position, so that a new supply of fluid may enter the pump housing and the downward stroke can begin again. The pump may be used independently of the optical cell, as a sample pump to transport a sample fluid from a source to a container for later analysis.

  5. Application of CFCC technology to hot gas filtration applications

    SciTech Connect (OSTI)

    Richlen, S.

    1995-06-01T23:59:59.000Z

    Discussion will feature high temperature filter development under the DOE`s Office of Industrial Technologies Continuous Fiber Ceramic Composite (CFCC) Program. Within the CFCC Program there are four industry projects and a national laboratory technology support project. Atlantic Research, Babcock & Wilcox, DuPont Lanxide Composites, and Textron are developing processing methods to produce CFCC Components with various types of matrices and composites, along with the manufacturing methods to produce industrial components, including high temperature gas filters. The Oak Ridge National Laboratory is leading a National Laboratory/University effort to increase knowledge of such generic and supportive technology areas as environmental degradation, measurement of mechanical properties, long-term performance, thermal shock and thermal cycling, creep and fatigue, and non-destructive characterization. Tasks include composite design, materials characterization, test methods, and performance-related phenomena, that will support the high temperature filter activities of industry and government.

  6. Cost Analysis Procedures for Use in Promoting Fine Filtration Media

    E-Print Network [OSTI]

    Renfert, David A.

    2006-05-19T23:59:59.000Z

    to run a compressor in standby mode (unloaded) or in reserve. (2) Many plants are limited in compressed air capacity and any reduction in compressed air demand will have benefits around the plant. ii) Controlling the cleaning cycle based... to estimate the percentage of time a compressor runs unloaded, so the calculation determines the theoretical costs to produce the volume of compressed air used for cleaning media. Motor efficiency (? motor ) = 0.9. {Company name} 27 Cost Analysis...

  7. Hydraulic pump with in-ground filtration and monitoring capability

    DOE Patents [OSTI]

    Hopkins, Charles D. (Augusta, GA); Livingston, Ronald R. (Aiken, SC); Toole, Jr., William R. (Aiken, SC)

    1996-01-01T23:59:59.000Z

    A hydraulically operated pump for in-ground filtering and monitoring of ws or other fluid sources, including a hollow cylindrical pump housing with an inlet and an outlet, filtering devices positioned in the inlet and the outlet, a piston that fits slidably within the pump housing, and an optical cell in fluid communication with the pump housing. A conduit within the piston allows fluid communication between the exterior and one end of the piston. A pair of o-rings form a seal between the inside of the pump housing and the exterior of the piston. A flow valve positioned within the piston inside the conduit allows fluid to flow in a single direction. In operation, fluid enters the pump housing through the inlet, flows through the conduit and towards an end of the pump housing. The piston then makes a downward stroke closing the valve, thus forcing the fluid out from the pump housing into the optical cell, which then takes spectrophotometric measurements of the fluid. A spring helps return the piston back to its starting position, so that a new supply of fluid may enter the pump housing and the downward stroke can begin again. The pump may be used independently of the optical cell, as a sample pump to transport a sample fluid from a source to a container for later analysis.

  8. Oxidation of sewage supernatant liquor by trickling filtration

    E-Print Network [OSTI]

    Styner, Pete

    1956-01-01T23:59:59.000Z

    ', '': . . 195~9 ":, ' '59 9- ", 19. , -: '; '; 15'F9-;: . :: 418 ?: 499'' ', , : P "-. 8'~5, . : ?. ;. 159 9 . -', ::". , $9-. -:. . . : P P$3I8. :;. "-, . -. , :s8138: '439, ": . ::"::14i:, 9', . ::-', , '-- 4N ' -", ';, '. , :" XL' ". . -:, ' 14..., -. ;;. , ';. ;. . . XiqnM, :or es. crest. sn4-;~ss od As jskNsi' ':5xo, nsg4j~s's1'nips ?', :; . , "::, ' ', : digssegos emik mme-, el@, -er&kling-;Blear srs -eaiu nnies=smpg+sk'in ehs bra semsne. ok' ehs 'soles~, shd erssemiame nf ehs 1@n$4, 'rsspsnei'vole A eriohlkng...

  9. air filtration technologies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Infrastructure Technologies FY 2002 Progress Report IV.E Air Management Subsystems Renewable Energy Websites Summary: . Approach Use automotive and aerospace...

  10. Energy Implications of In-line filtration in California Homes

    E-Print Network [OSTI]

    Walker, Iain S.

    2014-01-01T23:59:59.000Z

    Air Flow in Residential Air Conditioning Systems. ASHRAErefrigerating and Air-conditioning Engineers, Atlanta, GA.Refrigerating and Air- conditioning Engineers, Atlanta, GA.

  11. Energy Implications of In-Line Filtration in California

    E-Print Network [OSTI]

    Walker, Iain S.

    2014-01-01T23:59:59.000Z

    Air Flow in Residential Air Conditioning Systems. ASHRAERefrigeration and Air- conditioning Engineers, Atlanta, GA.Heat Exchanger Coils. Air Conditioning and Refrigeration

  12. DOE Zero Energy Ready Home: Ventilation and Filtration Strategies...

    Broader source: Energy.gov (indexed) [DOE]

    immediate comfort complaints, and it'll also drive up the electric consumption, as the heat pump won't be able to carry the load. It changes the physics that's happening inside of...

  13. Structural Oil Pan With Integrated Oil Filtration And Cooling System

    DOE Patents [OSTI]

    Freese, V, Charles Edwin (Westland, MI)

    2000-05-09T23:59:59.000Z

    An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

  14. The Benefits of Better Ventilation and Filtration Practices in Schools

    E-Print Network [OSTI]

    Lamping, G.

    2013-01-01T23:59:59.000Z

    Conference, San Antonio, Texas Dec. 16-18 The 3 I’s of IEQ can affect health and attendance 1. Invisible Particles Aerosols Levels in the classroom Airborne particles have the potential to cause allergic reactions, skin irritation, coughing, sneezing... Pollutants • Toxic Gases • Airborne Microbes • Occupants • Particles • Ammonia/Acetone • Hydrogen Sulfide • Infectious Microbes • Building Materials & Processes • Formaldehyde • Total Volatile Organic Compounds • Asbestos and Lead Dust • Infiltration from...

  15. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Broader source: Energy.gov (indexed) [DOE]

    heat release in DPF regeneration. - Derive equations for the oxidation rate of diesel particulates - Measure the amount of heat release from the oxidation Characterize...

  16. Can combining economizers with improved filtration save energy and

    E-Print Network [OSTI]

    electricity demand in this rapidly growing economic sector. Widespread economizer implementation, however, has electricity demand. For example, in 2005, US data center operations required about 45 billion k center energy demand while providing a level of protection from particles of outdoor origin similar

  17. PHENOMENOLOGICAL MODEL OF FILTRATION PROCESSES: 1. CAKE FORMATION AND EXPRESSION

    E-Print Network [OSTI]

    ;cation makes use, and abuse, of the famous Darcy equation (Darcy, 1856). The scienti#12;c foundation equation for the local solids fraction, which together with initial and boundary conditions determines is approximated by interpreting appropriately the same equations. Date: September 24, 2000. Key words and phrases

  18. Iterative methods for solving the pressure problem at multiphase filtration

    E-Print Network [OSTI]

    Vabishchevich, P

    2011-01-01T23:59:59.000Z

    Applied problems of oil and gas recovery are studied numerically using the mathematical models of multiphase fluid flows in porous media. The basic model includes the continuity equations and the Darcy laws for each phase, as well as the algebraic expression for the sum of saturations. Primary computational algorithms are implemented for such problems using the pressure equation. In this paper, we highlight the basic properties of the pressure problem and discuss the necessity of their fulfillment at the discrete level. The resulting elliptic problem for the pressure equation is characterized by a non-selfadjoint operator. Possibilities of approximate solving the elliptic problem are considered using the iterative methods. Special attention is given to the numerical algorithms for calculating the pressure on parallel computers.

  19. Particulate Emissions Control by Advanced Filtration Systems or GDI Engines

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  20. advanced membrane filtration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    available reverse osmosis (RO) and nanofiltration (NF) membranes are based on the thin film composite (TFC) aromatic polyamide membranes. However, they have several disadvantages...

  1. Energy Implications of In-Line Filtration in California

    E-Print Network [OSTI]

    information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name Occupant concern about indoor air quality (IAQ) issues has led to the increased use of more effective air

  2. WEIGHT FILTRATIONS VIA COMMUTING AUTOMORPHISMS Daniel R. Grayson

    E-Print Network [OSTI]

    Subject Classification. Primary 19E20. Supported by NSF grant DMS 90-02715. I thank Tom Goodwillie, Stephen Lichten* *baum, Friedhelm Waldhausen, Steven Landsburg, and Stephen Ullom for useful discussions

  3. WEIGHT FILTRATIONS VIA COMMUTING AUTOMORPHISMS Daniel R. Grayson

    E-Print Network [OSTI]

    . Primary 19E20. Supported by NSF grant DMS 90­02715. I thank Tom Goodwillie, Stephen Lichtenbaum, Friedhelm Waldhausen, Steven Landsburg, and Stephen Ullom for useful discussions and ideas. 1 #12; 2 DANIEL R. GRAYSON

  4. WEIGHT FILTRATIONS VIA COMMUTING AUTOMORPHISMS Daniel R. Grayson

    E-Print Network [OSTI]

    90-02715. I thank Tom Goodwillie, Stephen Lichtenbaum, Friedhelm Waldhausen, Steven Landsburg, and Stephen Ullom for useful discussions and ideas. 1 #12;2 DANIEL R. GRAYSON nonvanishing homotopy group

  5. Engineering Optimisation of cryptosporidium filtration under simulated swimming

    E-Print Network [OSTI]

    Martin, Ralph R.

    conditions / Tanya Leibrick. M.Res. 2012 Eng.D. The development of a lifing methodology for ceramic matrix composites / Danilo T. Di Salvo. Eng.D. 2012 Ph.D. Humic acid removal and fouling using tubular ceramic-scale modelling of ceramic composite layers and reinforced concrete slabs subjected to blast loading / Zainorizuan

  6. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Broader source: Energy.gov (indexed) [DOE]

    of small micro pores was reduced (blocked by catalyst materials), while the number of mediumlarge pores relatively increased. 8 Heavily catalyzed membrane increased back...

  7. Development of Advanced Diesel Particulate Filtration (DPF) Systems...

    Broader source: Energy.gov (indexed) [DOE]

    May 20, 2009 DOE Annual Merit Review & Peer Evaluation Meeting PI: Kyeong Lee (Postdoc: Seung Yang) Argonne National Laboratory DOE Project Managers: Kenneth Howden & Gurpreet...

  8. Air cooled turbine component having an internal filtration system

    DOE Patents [OSTI]

    Beeck, Alexander R. (Orlando, FL)

    2012-05-15T23:59:59.000Z

    A centrifugal particle separator is provided for removing particles such as microscopic dirt or dust particles from the compressed cooling air prior to reaching and cooling the turbine blades or turbine vanes of a turbine engine. The centrifugal particle separator structure has a substantially cylindrical body with an inlet arranged on a periphery of the substantially cylindrical body. Cooling air enters centrifugal particle separator through the separator inlet port having a linear velocity. When the cooling air impinges the substantially cylindrical body, the linear velocity is transformed into a rotational velocity, separating microscopic particles from the cooling air. Microscopic dust particles exit the centrifugal particle separator through a conical outlet and returned to a working medium.

  9. activated carbon filtration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Blackhawk Road, APG, MD USA 21010 ABSTRACT The impregnated active carbon in active carbon filters by combining the electromechanical impedance spectroscopy (EMIS Giurgiutiu, Victor...

  10. Evaluation of Side Stream Filtration Technology at Oak Ridge National

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd of Year 2010Salt | Department ofEvaluation

  11. Side Stream Filtration for Cooling Towers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreakingMay 2015ParentsMiddle|SecurityDepartmentShawn Wang About UsShirley

  12. Technical Evaluation of Side Stream Filtration for Cooling Towers |

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssuesEnergy Solar Decathlon | Department of

  13. DOE Zero Energy Ready Home: Ventilation and Filtration Strategies with

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube| Department ofDepartment of EnergyCustomIndoor airPLUS Webinar (Text

  14. Side Stream Filtration for Cooling Towers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretary of EnergyFocus GroupSherrell R. Greene AboutSide StreamSide

  15. CMI Unique Facility: Filtration Test Facility | Critical Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C l a r k CCLEAN ENERGY JOBSCritical

  16. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * S H I ETechnology |

  17. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * S H I ETechnology |Department of Energy 2011

  18. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * S H I ETechnology |Department of Energy

  19. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * S H I ETechnology |Department of

  20. Diesel Particulate Filtration (DPF) Technology: Success stories at the High

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E T A * SEnergyTemperature Materials Laboratory

  1. CFD Analysis of Particle Deposition During DPF Filtration Processes |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy FutureDepartmentCAIRSPlanning Timeline

  2. Magnetic Filtration Process, Magnetic Filtering Material, and Method of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9November 6, InaprilU . SMagellanForming Magnetic

  3. Indestructible Ultra-filtration: Ceramic HEPA Filters - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other News CommunityPortal Building Energy Efficiency

  4. Technical Evaluation of Side Stream Filtration for Cooling Towers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic| Department ofGeneralWind »Assistance:Technical

  5. N,N'-DICYCLOHEXYL-N"-ISOTRIDECYLGUANIDINE AS SUPPRESSOR FOR THE NEXT GENERATION CAUSTIC SIDE SOLVENT EXTRACTION (NG-CSSX) PROCESS

    SciTech Connect (OSTI)

    Duncan, Nathan C [ORNL; Roach, Benjamin D [ORNL; Williams, Neil J [ORNL; Bonnesen, Peter V [ORNL; Rajbanshi, Arbin [ORNL; Moyer, Bruce A [ORNL

    2012-01-01T23:59:59.000Z

    ABSTRACT The purity, concentration, and source of the N,N'-dicyclohexyl-N"-isotridecylguanidine (DCiTG) suppressor (guanidine) used in the NG-CSSX process were found to influence solvent performance. As the starting isotridecanol used in the preparation of DCiTG is comprised of a mixture of branched-chain aliphatic alcohols, varying in composition with manufacturer, the resulting DCiTG itself is a mixture. Thus, it is necessary to address how the solvent performance will be affected by the different preparations of the DCiTG solvent component. In this study, four preparations of DCiTG from three sources were analyzed and evaluated for purity and performance, both in the absence and presence of an anionic surfactant impurity.

  6. SALTSTONE VAULT CLASSIFICATION SAMPLES MODULAR CAUSTIC SIDE SOLVENT EXTRACTION UNIT/ACTINIDE REMOVAL PROCESS WASTE STREAM APRIL 2011

    SciTech Connect (OSTI)

    Eibling, R.

    2011-09-28T23:59:59.000Z

    Savannah River National Laboratory (SRNL) was asked to prepare saltstone from samples of Tank 50H obtained by SRNL on April 5, 2011 (Tank 50H sampling occurred on April 4, 2011) during 2QCY11 to determine the non-hazardous nature of the grout and for additional vault classification analyses. The samples were cured and shipped to Babcock & Wilcox Technical Services Group-Radioisotope and Analytical Chemistry Laboratory (B&W TSG-RACL) to perform the Toxic Characteristic Leaching Procedure (TCLP) and subsequent extract analysis on saltstone samples for the analytes required for the quarterly analysis saltstone sample. In addition to the eight toxic metals - arsenic, barium, cadmium, chromium, mercury, lead, selenium and silver - analytes included the underlying hazardous constituents (UHC) antimony, beryllium, nickel, and thallium which could not be eliminated from analysis by process knowledge. Additional inorganic species determined by B&W TSG-RACL include aluminum, boron, chloride, cobalt, copper, fluoride, iron, lithium, manganese, molybdenum, nitrate/nitrite as Nitrogen, strontium, sulfate, uranium, and zinc and the following radionuclides: gross alpha, gross beta/gamma, 3H, 60Co, 90Sr, 99Tc, 106Ru, 106Rh, 125Sb, 137Cs, 137mBa, 154Eu, 238Pu, 239/240Pu, 241Pu, 241Am, 242Cm, and 243/244Cm. B&W TSG-RACL provided subsamples to GEL Laboratories, LLC for analysis for the VOCs benzene, toluene, and 1-butanol. GEL also determines phenol (total) and the following radionuclides: 147Pm, 226Ra and 228Ra. Preparation of the 2QCY11 saltstone samples for the quarterly analysis and for vault classification purposes and the subsequent TCLP analyses of these samples showed that: (1) The saltstone waste form disposed of in the Saltstone Disposal Facility in 2QCY11 was not characteristically hazardous for toxicity. (2) The concentrations of the eight RCRA metals and UHCs identified as possible in the saltstone waste form were present at levels below the UTS. (3) Most of the inorganic species measured in the leachate do not exceed the MCL, SMCL or TW limits. (4) The inorganic waste species that exceeded the MCL by more than a factor of 10 were nitrate, nitrite and the sum of nitrate and nitrite. (5) Analyses met all quality assurance specifications of US EPA SW-846. (6) The organic species (benzene, toluene, 1-butanol, phenol) were either not detected or were less than reportable for the vault classification samples. (7) The gross alpha and radium isotopes could not be determined to the MCL because of the elevated background which raised the detection limits. (8) Most of the beta/gamma activity was from 137Cs and its daughter 137mBa. (9) The concentration of 137Cs and 90Sr were present in the leachate at concentrations 1/40th and 1/8th respectively than in the 2003 vault classification samples. The saltstone waste form placed in the Saltstone Disposal Facility in 2QCY11 met the SCHWMR R.61-79.261.24(b) RCRA metals requirements for a nonhazardous waste form. The TCLP leachate concentrations for nitrate, nitrite and the sum of nitrate and nitrite were greater than 10x the MCLs in SCDHEC Regulations R.61-107.19, Part I A, which confirms the Saltstone Disposal Facility classification as a Class 3 Landfill. The saltstone waste form placed in the Saltstone Disposal Facility in 2QCY11 met the R.61-79.268.48(a) non wastewater treatment standards.

  7. Chemomechanics of calcium leaching of cement-based materials at different scales : the role of CH-dissolution and C-S-H degradation on strength and durability performance of materials and structures

    E-Print Network [OSTI]

    Heukamp, Franz H. (Franz Hoyte), 1973-

    2003-01-01T23:59:59.000Z

    Calcium leaching is a durability threat for cement-based materials employed in critical infrastructures, such as Nuclear Waste Storage Systems. This thesis presents a comprehensive study of the material and structural ...

  8. Quantum Mechanical Metric for Internal Cohesion in Cement Crystals

    E-Print Network [OSTI]

    Dharmawardhana, C. C.; Misra, Anil; Ching, Wai-Yim

    2014-12-05T23:59:59.000Z

    Calcium silicate hydrate (CSH) is the main binding phase of Portland cement, the single most important structural material in use worldwide. Due to the complex structure and chemistry of CSH at various length scales, the focus has progressively...

  9. Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and Limited Reoxidation

    E-Print Network [OSTI]

    Um, Wooyong

    2013-01-01T23:59:59.000Z

    R. L. Vitrification offgas caustic scrubber secondary wastetrapped by melter off gas scrubber solutions, and plans areSSS-2 (moles/L) Caustic Scrubber Solution; Median Values

  10. PROJECT W-551 DETERMINATION DATA FOR EARLY LAW INTERIM PRETREATMENT SYSTEM SELECTION

    SciTech Connect (OSTI)

    TEDESCHI AR

    2008-08-11T23:59:59.000Z

    This report provides the detailed assessment forms and data for selection of the solids separation and cesium separation technology for project W-551, Interim Pretreatment System. This project will provide early pretreated low activity waste feed to the Waste Treatment Plant to allow Waste Treatment Plan Low Activity Waste facility operation prior to construction completion of the Pretreatment and High Level Waste facilities. The candidate solids separations technologies are rotary microfiltration and crossflow filtration, and the candidate cesium separation technologies are fractional crystallization, caustic-side solvent extraction, and ion-exchange using spherical resorcinol-formaldehyde resin. This data was used to prepare a cross-cutting technology summary, reported in RPP-RPT-37740.

  11. PROJECT W-551 SUMMARY INFORMATION FOR EARLY LAW INTERIM PRETREATMENT SYSTEM SELECTION

    SciTech Connect (OSTI)

    TEDESCHI AR

    2008-08-11T23:59:59.000Z

    This report provides summary data for use by the decision board to assess and select the final technology for project W-551, Interim Pretreatment System. This project will provide early pretreated low activity waste feed to the Waste Treatment Plant to allow Waste Treatment Plan Low Activity Waste facility operation prior to construction completion of the Pretreatment and High Level Waste facilities. The candidate solids separations technologies are rotary microfiltration and crossflow filtration, and the candidate cesium separation technologies are fractional crystallization, caustic-side solvent extraction, and ion-exchange using spherical resorcinol-fonnaldebyde resin. This document provides a summary of comparative data against prior weighted criteria to support technology selection. Supporting details and background for this summary are documented in the separate report, RPP-RPT-37741.

  12. Results Of Routine Strip Effluent Hold Tank And Decontaminated Salt Solution Hold Tank Samples From Modular Caustic-Side Solvent Extraction Unit During Macrobatch 5 Operations

    SciTech Connect (OSTI)

    Peters, T. B.; Fondeur, F. F.

    2013-04-30T23:59:59.000Z

    Strip Effluent Hold Tank (SEHT) and Decontaminated Salt Solution Hold Tank (DSSHT) samples from several of the ''microbatches'' of Integrated Salt Disposition Project (ISDP) Salt Batch (''Macrobatch'') 5 have been analyzed for {sup 238}Pu, {sup 90}Sr, {sup 137}Cs, and by Inductively Coupled Plasma Emission Spectroscopy (ICPES). The results indicate good decontamination performance within process design expectations. While the data set is sparse, the results of this set and the previous set of results for Macrobatch 4 samples indicate generally consistent operations. The DSSHT samples show continued presence of titanium, likely from leaching of the monosodium titanate in the Actinide Removal process (ARP).

  13. For More Information: http://www.Rowan.edu/engineering

    E-Print Network [OSTI]

    Rusu, Adrian

    , as additional sources of funding are secured. Recent Funded Projects Recycling scrubber caustic, Bio

  14. Characterization and preservation techniques of plant xylem as low cost membrane filtration devices

    E-Print Network [OSTI]

    Potash, Benjamin R

    2014-01-01T23:59:59.000Z

    Safe drinking water remains inaccessible for roughly 1.1 billion people in the world.³? As a result, 400 children under the age of 5 die every hour from biological contamination of drinking water.³? Studies have been done ...

  15. DOE ZERH Webinar: Ventilation and Filtration Strategies with Indoor airPLUS

    Broader source: Energy.gov [DOE]

    The Indoor airPLUS qualification, a prerequisite for Zero Energy Ready Homes, offers an important platform to improve the indoor air quality (IAQ) in high-performance homes.  A critical aspect of...

  16. Drilling mud filtration and its effect on the electrical resistivity of porous media 

    E-Print Network [OSTI]

    Flock, Donald Louis

    1957-01-01T23:59:59.000Z

    at the saturation S^.,, The ratio of equations 5 and 6 define a new factor called the resistivity index (I) as follows: ? ? V - ( f f U ) Numerous experiments have been performed to establish the value of the empirical constants n and m c Dunlap, Bilhartz... F I G U v o lu m e R E 2 C G O G - c c INVAS ION OF BENTONITE MUD A ( C O R E S I N I T I A L L Y S A T U R A T E D W I T H B R l M E C O N T A I N I N G I O O O O P P M N A C L ) * FIGURE 4 I OOOO VARIATION OF DEPTH...

  17. Hybrid Filtration Membranes incorporating Nanoporous Silica within a Nanoscale Alumina Fibre Scaffold

    E-Print Network [OSTI]

    Su, Veronica Mei Tiing; Clyne, Trevor William

    2015-06-11T23:59:59.000Z

    Characterisation Experimental permeation studies were conducted with the set-up shown schematically in Fig.1. The membranes were supported in a polycarbonate filter holder, using previously-developed procedures [8]. A cross-flow condition was generated with a... increased. This is difficult to avoid, since, in the absence of a conductive coating, the fibres have a strong tendency to become charged in the SEM. In order to study individual fibres in detail, transmission electron microscope (TEM) studies were...

  18. Vehicle Technologies Office Merit Review 2014: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  19. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2004-09-29T23:59:59.000Z

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  20. Aging and Gas Filtration Studies in the ATLAS Transition Radiation Tracker

    E-Print Network [OSTI]

    Sprachmann, Gerald; Störi, Herbert

    2006-01-01T23:59:59.000Z

    The Transition Radiation Tracker (TRT) is one of three particle tracking detectors of the ATLAS Inner Detector whose goal is to exploit the highly exciting new physics potential at CERN's next accelerator, the so-called Large Hadron Collider (LHC). The TRT consists of 370000 straw proportional tubes of 4 mm diameter with a 30 micron anode wire, which will be operated with a Xe/CO2/O2 gas mixture at a high voltage of approximately 1.5 kV. This detector enters a new area that requires it to operate at unprecedented high rates and integrated particle fluxes. Full functionality of the detector over the lifetime (10 years) of the experiment is demanded. Aging of gaseous detectors is a term for the degradation of detector performance during exposure to ionizing radiation. This phenomenon involves very complex physical and chemical processes that are induced by pollution originating from very small amounts of silicon-based substances in some components of the gas system. This work presents a review of previous aging...

  1. Pressure Drop and Filtration through Fibrous Porous Media on the Sump Strainer of Light Water Reactors

    E-Print Network [OSTI]

    Lee, Saya

    2014-12-15T23:59:59.000Z

    materials during a Loss of Coolant Accident (LOCA) might accumulate on the containment sump strainer causing loss of Net Positive Suction Head (NPSH), called the upstream effect, or it might penetrate through the strainer becoming a source of clogging...

  2. Vehicle Technologies Office Merit Review 2015: Particulate Emissions Control by Advanced Filtration Systems for GDI Engines

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about particulate...

  3. Webinar: Ventilation and Filtration Strategies with Indoor airPLUS and Zero Energy Ready Homes

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy Zero Energy Ready Home (ZERH) Program represents a whole new level of home performance, with rigorous requirements that ensure outstanding levels of energy savings,...

  4. Next generation of electrospun textiles for chemical and biological protection and air filtration

    E-Print Network [OSTI]

    Chen, Liang, Ph. D. Massachusetts Institute of Technology

    2009-01-01T23:59:59.000Z

    (cont.) only in the presence of water, which serves as a medium promoting the nucleophilic action of the amidoximes in the fibers. Bactericidal fiber mats were produced from electrospinning of blends containing a biocide ...

  5. Comparison of soy protein concentrates produced by membrane filtration and acid precipitation

    E-Print Network [OSTI]

    Kim, Hyun Jung

    2003-01-01T23:59:59.000Z

    The recovery of proteins using ultrafiltration (UF) process is an attractive alternative compared to conventional acid precipitation method. The mild processing condition, which leads to less protein denaturation, may be one of major virtues...

  6. Can combining economizers with improved filtration save energy and protect equipment in data centers?

    E-Print Network [OSTI]

    Shehabi, Arman

    2010-01-01T23:59:59.000Z

    USA Abstract Economizer use in data centers is an energy efficiency strategy that could significantly limit electricity demand

  7. Can combining economizers with improved filtration save energy and protect equipment in data centers?

    E-Print Network [OSTI]

    Shehabi, Arman

    2009-01-01T23:59:59.000Z

    USA Abstract Economizer use in data centers is an energy efficiency strategy that could significantly limit electricity demand

  8. E-Print Network 3.0 - adsorption filtration photo-catalysis Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technische Hochschule Zrich (ETHZ) Collection: Environmental Sciences and Ecology 13 Effects of Phosphate on Uranium(VI) Adsorption to Goethite-Coated Sand Summary: Effects of...

  9. Hot Gas Filtration of Fine and Ultra fine Particles with Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Particulate Filter Technology for Commercial Vehicles: Sintered Metal Particulate Filter Opens a New Dimension of Performance A New SiC-based DPF for the Automotive Industry...

  10. Pilot study of horizontal roughing filtration in northern Ghana as pretreatment for highly turbid dugout water

    E-Print Network [OSTI]

    Losleben, Tamar

    2008-01-01T23:59:59.000Z

    In Northern Region Ghana (NRG), highly turbid rainwater runoff and intermittent streams are collected in earthen dams called dugouts. These dams serve as many communities' main source of drinking and domestic water despite ...

  11. Catalytic fabric filtration for simultaneous NO sub x and particulate control

    SciTech Connect (OSTI)

    Weber, G.F.; Ness, S.R.; Laudal, D.L.; Dunham, G.

    1992-05-01T23:59:59.000Z

    The objective of this program is to develop advanced concepts for removal of NO{sub x} from flue gas emitted by coalfired utility boilers, or for the control of NO{sub x} formation by advanced combustion modification techniques. Funded projects are required to focus on the development of technology that significantly advances the state of the art using a process or a combination of processes capable of reducing NO{sub x}. emissions to 60 ppM or less. The concept must have successfully undergone sufficient laboratory-scale development to justify scaleup for further evaluation at the pilot scale (not to exceed 5 MWe in size). Other requirements include production of a nonhazardous waste or a salable byproduct. The concept should have application to both new and retrofit coal-fired systems. The concept should also show the potential for a 50% cost savings when compared to a commercial selective catalytic reduction (SCR) process capable of meeting the 60-ppM NO{sub x} emission limit.

  12. Drilling mud filtration and its effect on the electrical resistivity of porous media

    E-Print Network [OSTI]

    Flock, Donald Louis

    1957-01-01T23:59:59.000Z

    as a cementing material,, To obtain this reaction* a water-saturated sand was reduced to a low residual water content by flushing it with kerosene,, This was followed by a solu? tion containing five percent silicon tetrachloride in kerosene, until... the system was saturated with brine containing 10P000 ppma of NaCl0 The core was then flushed with kerosene at a pressure differential of 30 psio The resistivity of the core was measured during the flood and the produced water was collected in a 17...

  13. Particle concentrations in air-conditioned office building with normal and high efficiency filtration

    E-Print Network [OSTI]

    Fisk, W.J.

    2011-01-01T23:59:59.000Z

    particle generation or resuspension, for particles largerLayton DW 1995. Deposition, resuspension, and penetration ofindoor generation or resuspension of particles larger than

  14. Impact of Feedwater Salinity on Energy Requirements of a Small-Scale Membrane Filtration System 

    E-Print Network [OSTI]

    Richards, B.S.; Masson, L.; Schäfer, Andrea

    2009-01-01T23:59:59.000Z

    Many remote communities in both developed and developing countries lack electricity and clean drinking water. One solution, for such communities that rely on brackish groundwater, is a photovoltaic (PV) powered hybrid ...

  15. Magnetic filtration process, magnetic filtering material, and methods of forming magnetic filtering material

    DOE Patents [OSTI]

    Taboada-Serrano, Patricia; Tsouris, Constantino; Contescu, Cristian I; McFarlane, Joanna

    2013-10-08T23:59:59.000Z

    The present invention provides magnetically responsive activated carbon, and a method of forming magnetically responsive activated carbon. The method of forming magnetically responsive activated carbon typically includes providing activated carbon in a solution containing ions of ferrite forming elements, wherein at least one of the ferrite forming elements has an oxidation state of +3 and at least a second of the ferrite forming elements has an oxidation state of +2, and increasing pH of the solution to precipitate particles of ferrite that bond to the activated carbon, wherein the activated carbon having the ferrite particles bonded thereto have a positive magnetic susceptibility. The present invention also provides a method of filtering waste water using magnetic activated carbon.

  16. Can combining economizers with improved filtration save energy and protect equipment in data centers?

    E-Print Network [OSTI]

    Shehabi, Arman

    2009-01-01T23:59:59.000Z

    by potential equipment reliability concerns associated withblack carbon; equipment reliability; energy efficiency 1.potential equipment reliability concerns associated with

  17. Can combining economizers with improved filtration save energy and protect equipment in data centers?

    E-Print Network [OSTI]

    Shehabi, Arman

    2010-01-01T23:59:59.000Z

    by potential equipment reliability concerns associated withblack carbon; equipment reliability; energy efficiency 1.potential equipment reliability concerns associated with

  18. Final Report: Pilot-scale Cross-flow Filtration Test - Envelope A + Entrained Solids

    SciTech Connect (OSTI)

    Duignan, M.R.

    2000-06-27T23:59:59.000Z

    This report discusses the results of the operation of a cross-flow filter in a pilot-scale experimental facility that was designed, built, and run by the Experimental Thermal Fluids Laboratory of the Savannah River Technology Center of the Westinghouse Savannah River Company.This filter technology was evaluated for its inclusion in the pretreatment section of the nuclear waste stabilization plant being designed by BNFL, Inc. This plant will be built at the U.S. Department of Energy's Hanford Site as part of the River Protection Project.

  19. air filtration-based intervention: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nearly all Chinas rural residents and a shrinking fraction of urban residents use solid fuels (biomass and coal) for household cooking andor heating. Consequently, global...

  20. Evaluation of Side Stream Filtration Technology at Oak Ridge National Laboratory

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:RevisedAdvisoryStandardGeneration |10 DOEGoalsEvaluation11 DOEEmissionsMeet

  1. Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p pofHon. Daniel B.Honoring MaySintered

  2. First Draft Performance Assessment for the H-Area Tank Farm at...

    Office of Environmental Management (EM)

    of Concern COPC Constituent of Potential Concern CPT Cone Penetration Test CRC Cesium Removal Column CSH Calcium Silicate Hydrate CSRA Central Savannah River Area CTS...

  3. Natural Abundance 43Ca NMR Spectroscopy of Tobermorite and Jennite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which has limited our ability to understand the structure of, for example, Ca–silicate hydrate (C–S–H). 43Ca nuclear magnetic resonance (NMR) spectroscopy has...

  4. Microsoft Word - NRAP-TRS-III-004-2014_Acid Gas Interactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    involves dissolution of key cementitious phases (portlandite and amorphous calcium-silicate-hydrate (C-S-H)), precipitation and dissolution of carbonate species (calcite),...

  5. BACKPRESSURE TESTING OF ROTARY MICROFILTER DISKS

    SciTech Connect (OSTI)

    Fowley, M.; Herman, D.

    2011-04-14T23:59:59.000Z

    The Savannah River National Laboratory (SRNL), under the Department of Energy (DOE) Office of Environmental Management (EM), is modifying and testing the SpinTek{trademark} rotary microfilter (RMF) for radioactive filtration service in the Department of Energy (DOE) complex. The RMF has been shown to improve filtration throughput when compared to other conventional methods such as cross-flow filtration. A concern with the RMF was that backpressure, or reverse flow through the disk, would damage the filter membranes. Reverse flow might happen as a result of an inadvertent valve alignment during flushing. Testing was completed in the Engineering Development Laboratory (EDL) located in SRNL to study the physical effects of backpressure as well as to determine the maximum allowable back-pressure for RMF disks. The RMF disks tested at the EDL were manufactured by SpinTek{trademark} Filtration and used a Pall Corporation PMM050 filter membrane (0.5 micron nominal pore size) made from 316L stainless steel. Early versions of the RMF disks were made from synthetic materials that were incompatible with caustic solutions and radioactive service as well as being susceptible to delaminating when subjected to backpressure. Figure 1-1 shows the essential components of the RMF; 3 rotating disks and 3 stationary turbulence promoters (or shear elements) are shown. Figure 1-2 show the assembly view of a 25 disk RMF proposed for use at the Savannah River Site (SRS) and at the Hanford Facility. The purpose of the testing discussed in this report was to determine the allowable backpressure for RMF disks as well as study the physical effects of backpressure on RMF disks made with the Pall PMM050 membrane. This was accomplished by pressurizing the disks in the reverse flow direction (backpressure) until the test limit was reached or until membrane failure occurred. Backpressure was applied to the disks with air while submerged in deionized (DI) water. This method provided a visual representation of membrane integrity via bubble flow patterns. Membrane failure was defined as the inability to filter effectively at the nominal filter pore size. Effective filtration was determined by turbidity measurements of filtrate that was produced by applying forward-pressure to the disks while submerged in a representative simulant. The representative simulant was Tank 8F simulated sludge produced for SRNL by Optima Chemical. Two disks were tested. Disk 1 was tested primarily to determine approximate levels of backpressure where membrane failure occurred. These levels were then used to define the strategy for testing the Disk 2; a strategy that would better define and quantify the mode of failure.

  6. Deteriorated hardened cement paste structure analyzed by XPS and {sup 29}Si NMR techniques

    SciTech Connect (OSTI)

    Kurumisawa, Kiyofumi, E-mail: kurumi@eng.hokudai.ac.jp [Faculty of Engineering, Hokkaido University, Japan, Kita 13, Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628 (Japan)] [Faculty of Engineering, Hokkaido University, Japan, Kita 13, Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628 (Japan); Nawa, Toyoharu [Faculty of Engineering, Hokkaido University, Japan, Kita 13, Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628 (Japan)] [Faculty of Engineering, Hokkaido University, Japan, Kita 13, Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628 (Japan); Owada, Hitoshi [Radioactive Waste Management Funding and Research Center, 1-15-7 Tsukishima, Chuo-ku, Tokyo (Japan)] [Radioactive Waste Management Funding and Research Center, 1-15-7 Tsukishima, Chuo-ku, Tokyo (Japan); Shibata, Masahito [Taiheiyo Consultant Co., Ltd., 2-4-2, Ohsaku, Sakura-City, Chiba (Japan)] [Taiheiyo Consultant Co., Ltd., 2-4-2, Ohsaku, Sakura-City, Chiba (Japan)

    2013-10-15T23:59:59.000Z

    In this report, X-ray photoelectron spectroscopy (XPS) and {sup 29}Si-MAS-NMR was used for the evaluation of deteriorated hardened cement pastes. The deterioration by ammonium nitrate solution was accompanied by changes in the pore structure as well as by structural changes in the C–S–H in the hardened cement paste. The CaO/SiO{sub 2} ratio of the C–S–H decreased with the progress of deterioration, there was also polymerization of the silicate in the C–S–H. It was confirmed that the degree of polymerization of silicate of the C–S–H in hardened cement paste can be determined by XPS. It was also shown that the polymerization depends on the structure of the C–S–H. -- Highlights: •The polymerization of silicate of the C–S–H in the HCP can be observed by XPS. •The structure of C–S–H changed with the degree of calcium leaching. •The NMR result about silicate in C–S–H was in good agreement with the XPS result.

  7. Contact Mechanics Based Mechanical Characterization of Portland Cement Paste

    E-Print Network [OSTI]

    Jones, Christopher

    2012-02-14T23:59:59.000Z

    that the calcium silicate hydrate (C-S-H) phase of hydrated portland cement has different properties on the nanometric scale than on the micron scale. Packing density of C-S-H particles is proposed as an explanation for the disparity in the measured results...

  8. Appendix C: Air Permits Annual Site Environmental Report

    E-Print Network [OSTI]

    Pennycook, Steve

    Caustic scrubber stack exhaust 314 Caustic scrubber exhaust 317 Lithium metal wash station 318 Lithium Exhaust from machine shop 48 Chip washing and drying Y-9212-C 01-0020-05 025984P 113 Dissolver trays/scrubber

  9. Appendix C: Air Permits Annual Site Environmental Report

    E-Print Network [OSTI]

    Pennycook, Steve

    description Y-9204-2-B 01-0020-71 025954P 313 Caustic scrubber stack exhaust 314 Caustic scrubber exhaust 317 trays/scrubber 114 Shear and hacksaw hood 128 Precipitation process 26 Drum receiving/sampling hood

  10. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01T23:59:59.000Z

    and Alloys (kt) Paper Pulp (kt) Caustic Soda (kt) Paper and Paperboard (Mt) Soda Ash (kt) Motor Vehicles and Chasis [

  11. Application of Pulse Spark Discharges for Scale Prevention and Continuous Filtration Methods in Coal-Fired Power Plant

    SciTech Connect (OSTI)

    Cho, Young; Fridman, Alexander

    2012-06-30T23:59:59.000Z

    The overall objective of the present work was to develop a new scale-prevention technology by continuously precipitating and removing dissolved mineral ions (such as calcium and magnesium) in cooling water while the COC could be doubled from the present standard value of 3.5. The hypothesis of the present study was that if we could successfully precipitate and remove the excess calcium ions in cooling water, we could prevent condenser-tube fouling and at the same time double the COC. The approach in the study was to utilize pulse spark discharges directly in water to precipitate dissolved mineral ions in recirculating cooling water into relatively large suspended particles, which could be removed by a self-cleaning filter. The present study began with a basic scientific research to better understand the mechanism of pulse spark discharges in water and conducted a series of validation experiments using hard water in a laboratory cooling tower. Task 1 of the present work was to demonstrate if the spark discharge could precipitate the mineral ions in water. Task 2 was to demonstrate if the selfcleaning filter could continuously remove these precipitated calcium particles such that the blowdown could be eliminated or significantly reduced. Task 3 was to demonstrate if the scale could be prevented or minimized at condenser tubes with a COC of 8 or (almost) zero blowdown. In Task 1, we successfully completed the validation study that confirmed the precipitation of dissolved calcium ions in cooling water with the supporting data of calcium hardness over time as measured by a calcium ion probe. In Task 2, we confirmed through experimental tests that the self-cleaning filter could continuously remove precipitated calcium particles in a simulated laboratory cooling tower such that the blowdown could be eliminated or significantly reduced. In addition, chemical water analysis data were obtained which were used to confirm the COC calculation. In Task 3, we conducted a series of heat transfer fouling tests using a condenser heat exchanger in the laboratory cooling tower, from which we confirmed that the plasma water treatment technology could prevent or significantly mitigate mineral foulings in condenser tubes when compared with the no-treatment case. With the completion of the present work, a cooling water treatment technology using pulse spark discharges is currently ready for field-validation tests. The plasma water treatment technology is a true mechanical water softener with almost no maintenance, which continuously converts hard water to soft water spending a relatively small amount of energy. Such a mechanical water softener could find wide-spread applications to solve hard water problems both in industry and at home.

  12. Adsorption/Membrane Filtration as a Contaminant Concentration and Separation Process for Mixed Wastes and Tank Wastes - Final Report

    SciTech Connect (OSTI)

    Benjamin, M.M.

    1999-10-01T23:59:59.000Z

    This project was conducted to evaluate novel approaches for removing radioactive strontium (Sr) and cesium (Cs) from the tank wastes. The bulk of the Sr removal research conducted as part of this project investigated adsorption of Sr onto a novel adsorbent known as iron-oxide-coated sand. The second major focus of the work was on the removal of cesium. Since the chemistries of strontium and cesium have little commonality, different materials (namely, cesium scavengers known as hexacyanoferrates, HCFs) were employed in these tests. This study bridged several scientific areas and yielded valuable knowledge for implementing new technological processes. The applicability of the results extends beyond the highly specialized application niches investigated experimentally to other issues of potential interest for EMSP programs (e.g., separation of chromium from a variety of wastes using IOCS, separation of Cs from neutral and acidic wastes with EC-controlled HCFs).

  13. Performance of a silicon photovoltaic module under enhanced illumination and selective filtration of incoming radiation with simultaneous cooling

    SciTech Connect (OSTI)

    Maiti, Subarna; Vyas, Kairavi; Ghosh, Pushpito K. [Process Design and Engineering Cell, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G.B. Marg, Bhavnagar 364002, Gujarat (India)

    2010-08-15T23:59:59.000Z

    A promising option to reduce the cost of silicon photovoltaic systems is to concentrate the sunlight incident on the solar cells to increase the output power. However, this leads to higher module temperatures which affects performance adversely and may also cause long term damage. Proper cooling is therefore necessary to operate the system under concentrated radiation. The present work was undertaken to circumvent the problem in practical manner. A suitable liquid, connected to a heat exchanger, was placed in the housing of the photovoltaic module and unwanted wavelengths of solar radiation were filtered out to minimise overheating of the cells. The selection of the liquid was based on factors such as boiling point, transparency towards visible radiation, absorption of infrared and ultraviolet radiation, stability, flow characteristics, heat transfer properties, and electrical nonconductivity. Using a square parabolic type reflector, more than two fold increase in output power was realised on a clear sunny day employing a 0.13 m{sup 2} silicon solar module. Without the cooling arrangement the panel temperature rose uncontrollably. (author)

  14. From Emergency to Fix: Point-of-Use Water Filtration Technology in Colonias Along the United States-Mexico Border

    E-Print Network [OSTI]

    Vandewalle, Emily Lauren

    2014-04-30T23:59:59.000Z

    Small-scale decentralized facilities and technologies are rapidly becoming a dominant technological fix to deliver water to underserved populations in developing nations. This project examines the case of a university partnership with government...

  15. The effects of cerium doping on the size, morphology, and optical properties of ?-hematite nanoparticles for ultraviolet filtration

    SciTech Connect (OSTI)

    Cardillo, Dean [Institute for Superconducting and Electronic Materials, AIIM Facility, University of Wollongong Innovation Campus, Squires Way, North Wollongong, NSW 2500 (Australia); Konstantinov, Konstantin, E-mail: konstan@uow.edu.au [Institute for Superconducting and Electronic Materials, AIIM Facility, University of Wollongong Innovation Campus, Squires Way, North Wollongong, NSW 2500 (Australia); Devers, Thierry [Centre de Recherche sur la Matière Divisée, Institut de Physique, site de Chartres, Université d’Orléans (France)

    2013-11-15T23:59:59.000Z

    Highlights: • Possible application of cerium-doped ?-hematite as ultraviolet filter. • Nanoparticles obtained through co-precipitation technique using various cerium doping levels followed by annealing. • Comprehensive materials characterisation utilizing XRD, DSC/TGA, STEM, UV–vis spectroscopy. • Increasing cerium content reduces particle sizing and alters morphology. • Solubility of cerium in hematite seen between 5 and 10% doping, 10% cerium doping greatly enhances attenuation in ultraviolet region and increases optical bandgap. - Abstract: Metal oxide nanoparticles have potential use in energy storage, electrode materials, as catalysts and in the emerging field of nanomedicine. Being able to accurately tailor the desirable properties of these nanoceramic materials, such as particle size, morphology and optical bandgap (E{sub g}) is integral in the feasibility of their use. In this study we investigate the altering of both the structure and physical properties through the doping of hematite (?-Fe{sub 2}O{sub 3}) nanocrystals with cerium at a range of concentrations, synthesised using a one-pot co-precipitation method. This extremely simple synthesis followed by thermal treatment results in stable Fe{sub 2?x}Ce{sub x}O{sub y} nanoceramics resulting from the burning of any unreacted precursors and transformation of goethite-cerium doped nanoparticle intermediate. The inclusion of Ce into the crystal lattice of these ?-Fe{sub 2}O{sub 3} nanoparticles causes a significantly large reduction in mean crystalline size and alteration in particle morphology with increasing cerium content. Finally we report an increase optical semiconductor bandgap, along with a substantial increase in the ultraviolet attenuation found for a 10% Ce-doping concentration which shows the potential application of cerium-doped hematite nanocrystals to be used as a pigmented ultraviolet filter for cosmetic products.

  16. Proceedings of Healthy Buildings 2009 Paper 474 Impacts of HVAC Filtration on Air-Conditioner Energy Consumption in

    E-Print Network [OSTI]

    Siegel, Jeffrey

    -Conditioner Energy Consumption in Residences Brent Stephens1,* , Atila Novoselac1 and Jeffrey A. Siegel1 1, a greater pressure drop will generally lead to increased energy consumption (e.g., Fisk et al., 2002 The University of Texas at Austin, USA * Corresponding email: stephens.brent@mail.utexas.edu SUMMARY The use

  17. A study of the effects of mud filtrate invasion on the response of standard resistivity logging tools

    E-Print Network [OSTI]

    Semmelbeck, Mark Edward

    1985-01-01T23:59:59.000Z

    not accurately rep- resent the water saturation profile in the reservoir resulting from invasion. ACKNOWLEDGEMENTS The author wishes to express his sincere appreciation to the following individuals. Dr. S. A. Holditch, professor of Petroleum Engineering... Relative Permeability Data Capillary Pressure Data Base Case Water Saturation Profile Idealized Invasion Process Page 13 21 26 27 29 Water Saturation Profile Base Case 35 Water Salinity Profile Base Case 36 Water Resistivity Profile Base...

  18. Vibration Analysis for Damage Detection in Ultra filtration Fibers J. Roussel*, P. Ravier*, C. Capdessus**, M. Jabloun*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , due to the high water pressure, fibers may be damaged, causing the dirty water to reach the module of modules [GUO10], which requires time and money. Moreover water analysis methods do not allow determine detection errors and improper estimation of damages. Time and money could be saved with an on-line based

  19. We develop a procedure to simulate and detect the spatial distribution of mud-filtrate invasion in the

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    of reservoirs. Accurate determination of in-situ formation resistivity as a direct measure of initial oil to a waterflood. Consequently, the invaded zone resistivity, xoR remains a direct indicator of residual oil

  20. Numerical Simulation of Mud-Filtrate Invasion in Horizontal Wells and Sensitivity Analysis of Array Induction Tools1

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    assess- ment of reservoirs. Accurate determination of in-situ forma- tion resistivity as a direct measure be regarded as analogous to a waterflood. Consequently, the invaded zone resistivity, Rxo remains a direct

  1. Mechanism of action of cysteamine in depleting prolactin immunoreactivity

    SciTech Connect (OSTI)

    Sagar, S.M.; Millard, W.J.; Martin, J.B.; Murchison, S.C.

    1985-08-01T23:59:59.000Z

    The thiol reagent cysteamine (CSH) depletes anterior pituitary cells of immunoreactive PRL both in vivo and in vitro. The authors examined the hypothesis that CSH affects either the solubility or immunoreactivity of PRL through a mechanism involving thiol-disulfide exchange. Adult female rats were treated with either CSH (300 mg/kg, sc) or an equimolar dose of ethanolamine as a control. Anterior pituitary glands were extracted in 0.1 M sodium borate buffer, pH 9.0. Treatment of pituitary extracts with beta-mercaptoethanol (BME) destroys the immunoreactivity of PRL. However, extraction in the presence of reduced glutathione or CSH of pituitaries of rats treated with CSH restores immunoreactive PRL to control levels. Extracts were also subjected to polyacrylamide gel electrophoresis (PAGE). On gels of pituitary extracts of CSH-treated rats, the band that comigrates with purified PRL is diminished compared to that in ethanolamine-treated controls. However, extraction of the pituitaries in sodium dodecyl sulfate-containing buffer followed by chemical reduction with BME restores the PRL band. Therefore, CSH acts on PRL through a thiol-related mechanism to yield a product that is poorly soluble in aqueous buffer at pH 9 and is poorly immunoreactive. Dispersed anterior pituitary cells in tissue culture were incubated with L-(TVS)methionine to radiolabel newly synthesized peptides. PAGE followed by autoradiography confirmed the above results obtained in vivo.

  2. Efficient ray tracing algorithms based on wavefront construction and model based interpolation method

    E-Print Network [OSTI]

    Lee, Kyoung-Jin

    2006-08-16T23:59:59.000Z

    at the surface and reveal the caustic shadow. . . . . 53 3.13 Some ray paths showing caustics in the gradient low velocity blob sphere model. Rays from the source are bending and crossing near the caustic point where the velocity gradient is high...

  3. Recaustization of kraft black liquor via bipolar electrodialysis

    SciTech Connect (OSTI)

    Koumoundouros, J.A.; Oshen, S.; Lynch, J.D.

    1990-05-01T23:59:59.000Z

    The US Department of Energy in conjunction with HPD Inc. supported a research program to perform a laboratory feasibility study with various black liquor samples for the recaustization of these samples via bipolar electrodialysis. The research was conducted at the HPD pilot plant facility in Plainfield, Illinois, beginning in April 1989. This report is a summary of the work completed thru November 1989. The program was designed to operate the electrodialyzer in order to obtain performance and engineering data such as current efficiency, power consumption per gram of NaOH produced, and assess fouling and/or membrane durability. Prior to the electrodialysis laboratory runs, the black liquor samples were pretreated in order to remove as much lignin as possible. The black liquor samples were air oxidized, acidified to pH = 9.0 and pH = 2.0 and later filtered via a Buchner funnel under vacuum. The filtrate was then utilized to become the feed to the electrodialysis stack. Initial test runs were performed with synthetic solutions of either sodium sulfate or sodium bicarbonate in order to determine acceptable operating current, power, current efficiencies, and fouling behavior. A second set of test were conducted with a series of four Southern Kraft black liquor samples. Based on the results of this study, it was determined that the use of bipolar electrodialysis for producing a caustic stream and an acidified black liquor stream is feasible and was demonstrated. 9 refs., 27 figs., 32 tabs.

  4. Computer News, Volume 29

    E-Print Network [OSTI]

    MATH DEPT Computer News, Volume 29. How to update your login shell from csh to tcsh. If you, like me, have had an account on the Math network of SUNs ...

  5. A realistic molecular model of cement hydrates

    E-Print Network [OSTI]

    Ulm, Franz-Josef

    Despite decades of studies of calcium-silicate-hydrate (C-S-H), the structurally complex binder phase of concrete, the interplay between chemical composition and density remains essentially unexplored. Together these ...

  6. Multi-Scale Studies of Transport and Adsorption Phenomena of Cement-based Materials in Aqueous and Saline Environment

    E-Print Network [OSTI]

    Yoon, Se Yoon

    2012-01-01T23:59:59.000Z

    and (d) 7days, and (e) Cl XRF map with microscopic image,by X-ray fluorescence (XRF). NaCl-reacted C-S-H samples werean X-ray fluorescence (XRF) map. Using XRD, this chapter

  7. Dynamic behavior of hydration water in calcium-silicate-hydrate gel: A quasielastic neutron scattering spectroscopy investigation

    E-Print Network [OSTI]

    Li, Hua

    The translational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel was studied by quasielastic neutron scattering spectroscopy in the temperature range from 280 to 230 K. The stretch exponent ...

  8. American Mineralogist, Volume 97, pages 10601069, 2012 0003-004X/12/00071060$05.00/DOI: http://dx.doi.org/10.2138/am.2012.4058 1060

    E-Print Network [OSTI]

    Jacobsen, Steven D.

    -coordination with hydroxyl, VI Si-OH. Thaumasite and ettringite also form in the porous matrix of aging concrete, especially and of carbonation. Because C-S-H in concrete prov

  9. Effects of cysteamine on pituitary, MTTW15 tumor, and serum prolactin levels measured by rat lymphoma cell bioassay and radioimmunoassay

    SciTech Connect (OSTI)

    Parsons, J.A.; Peterson, E.K.; Hartfel, M.A.

    1984-05-01T23:59:59.000Z

    Cysteamine (CSH), a sulfhydryl compound, reduces both serum and anterior pituitary (AP) PRL measured by RIA. We have used the Nb2 lymphoma cell bioassay (BIO) for PRL to evaluate possible CSH-related changes in PRL levels in sera and tissues of male and MtTW15 mammosomatotropic tumor-bearing female rats. Experimental animals received a single sc injection of CSH (300 mg/kg), and samples were collected 0.5-24 h later. Since CSH and serum from CSH rats were toxic in BIO, samples were dialyzed before assay. All samples were evaluated for PRL and GH by RIA as well. A significant decrease (P less than 0.05) in BIO serum PRL was evident in male rats 0.5 h after CSH; levels remained low for 24 h. Serum PRL by RIA was significantly depressed at 4 h but not at 0.5 h or 24 h. PRL in AP extracts was decreased (60-90%) at all times by BIO and RIA. Significant decreases of BIO- and RIA-detectable PRL were recorded in serum and tissues (AP and tumors) at 4 h in tumor rats. Sequentially bled (0.5-4 h) CSH-treated tumor-bearing rats showed 50% and 80% reductions in serum PRL at 1 and 4 h by both BIO and RIA. CSH had no effect on GH levels in sera and tissues of any animal studied at any time interval. Our results substantiate earlier reports on CSH-induced decreases in RIA-detectable PRL. They show that such changes cannot be attributed to assay effects alone, as significant decreases in circulating and stored PRL (both AP and tumor) were evident by BIO. Results with tissue extracts were the most dramatic. They suggest an action of CSH or a metabolic intermediate with stored PRL which reduces both extractable PRL and hormone release. Such an effect of CSH on PRL extraction has been suggested by others. Whatever the mechanism, it appears to be relatively specific, since GH cells were not affected.

  10. Order and disorder in calcium–silicate–hydrate

    SciTech Connect (OSTI)

    Bauchy, M., E-mail: bauchy@mit.edu [Concrete Sustainability Hub, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); MIT-CNRS Joint Laboratory at Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); Qomi, M. J. Abdolhosseini; Ulm, F.-J. [Concrete Sustainability Hub, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); Pellenq, R. J.-M. [Concrete Sustainability Hub, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); MIT-CNRS Joint Laboratory at Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); Centre Interdisciplinaire des Nanosciences de Marseille, CNRS and Aix-Marseille University, Campus de Luminy, 13288 Marseille Cedex 09 (France)

    2014-06-07T23:59:59.000Z

    Despite advances in the characterization and modeling of cement hydrates, the atomic order in Calcium–Silicate–Hydrate (C–S–H), the binding phase of cement, remains an open question. Indeed, in contrast to the former crystalline model, recent molecular models suggest that the nanoscale structure of C–S–H is amorphous. To elucidate this issue, we analyzed the structure of a realistic simulated model of C–S–H, and compared the latter to crystalline tobermorite, a natural analogue of C–S–H, and to an artificial ideal glass. The results clearly indicate that C–S–H appears as amorphous, when averaged on all atoms. However, an analysis of the order around each atomic species reveals that its structure shows an intermediate degree of order, retaining some characteristics of the crystal while acquiring an overall glass-like disorder. Thanks to a detailed quantification of order and disorder, we show that, while C–S–H retains some signatures of a tobermorite-like layered structure, hydrated species are completely amorphous.

  11. Cysteamine-induced depletion of somatostatin and prolactin

    SciTech Connect (OSTI)

    Millard, W.J.; Sagar, S.M.; Martin, J.B.

    1985-06-01T23:59:59.000Z

    Cysteamine (2-aminoethanethiol (CSH), given in vivo or in vitro, rapidly but reversibly depletes immunoreactive somatostatin (irSS) in the central nervous system and gut as well as biological and immunological prolactin (PRL) activity in both the anterior pituitary and blood of the rat. This depletion of irSS and PRL is dose dependent and cannot be accounted for by release of either compound. Basal and potassium-stimulated SS release is reduced from hypothalamic tissue in vitro in CSH-treated animals. PRL secretion induced both pharmacologically and physiologically is abolished after CSH administration. Furthermore, CSH reduces cellular PRL content in a number of hyperprolactinemic states. The mechanism by which CSH reduces PRL levels is not clear, but it does not appear to act through the dopamine receptor nor does it alter the morphological structure of the lactotrope in normal animals. Most likely, CSH acts by interacting with the disulfide bonds of PRL, thus rendering the molecule both immunologically and biologically inactive.

  12. The Milky Way's Dark Matter Distribution and Consequences for Axion Detection

    SciTech Connect (OSTI)

    Duffy, Leanne D. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM, 87545 (United States)

    2010-08-30T23:59:59.000Z

    Signals for both direct and indirect dark matter detection depend on the phase-space distribution of dark matter. The possibility of structures with high physical density, known as caustics, has provided an opportunity to increase the discovery potential of the Axion Dark Matter eXperiment (ADMX). I discuss the formation of dark matter caustics and consequences of the caustic ring model for ADMX.

  13. The Milky Way's dark matter distribution and consequences for axion detection

    SciTech Connect (OSTI)

    Duffy, Leanne D [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    Signals for both direct and indirect dark matter detection depend on the phase-space distribution of dark matter. The possibility of structures with high physical density, known as caustics, has provided an opportunity to increase the discovery potential of the Axion Dark Matter eXperiment (ADMX). I discuss the formation of dark matter caustics and consequences of the caustic ring model for ADMX.

  14. U.S. Department of Energy Categorical Exclusion ...

    Broader source: Energy.gov (indexed) [DOE]

    Caustic Side Solvent Extraction Unit (MCU) Life Extension Support Testing Savannah River Site AikenAikenSouth Carolina SRNL, and Engineering Developmental Laboratory (EDL) in...

  15. NETL F 451.1-1/1 Categorical Exclusion (CX) Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    DOENETL FE 0561 ORD 2010 Erik Saab 2010 NETL Morgantown GPDUSyngas Generator Decommissioning Prepatory work for the demolition of the GPDU and SGG Structures, Caustic Soda Tank...

  16. Pastoral at the Boundaries: The Hybridization of Genre in the Fourteenth-Century Italian Eclogue Revival

    E-Print Network [OSTI]

    Combs-Schilling, Jonathan David

    2012-01-01T23:59:59.000Z

    world (or, in Samuel Johnson’s more caustic formulation,di Bretschneider. 69-82. Johnson, Samuel. 2006. The Lives of

  17. ITP Chemicals: Final Report: Evaluation of Alternative Technologies...

    Office of Environmental Management (EM)

    Ammonia, and Terephthalic Acid, December 2007 ITP Chemicals: Final Report: Evaluation of Alternative Technologies for Ethylene, Caustic-Chlorine, Ethylene Oxide, Ammonia, and...

  18. METC/Shell Cooperative Agreement CRADA 93-011 high temperature high pressure filtration and sorbent test program. Volume 2, Final report

    SciTech Connect (OSTI)

    NONE

    1995-06-01T23:59:59.000Z

    This report is a summary of the results of activities of the particulate monitoring group in support of the METC/Shell CRADA 93-011. Online particulate monitoring began in August 1993 and ended in October 1994. The particulate monitoring group participated in six MGCR runs (No. 5 through No. 10). The instrument used in measuring the particle loadings (particle counts and size distribution) is the Particle Measuring Systems Classical Scattering Aerosol Spectrometer Probe High Temperature and High Pressure (PMS Model CSASP-100-HTHP). This PMS unit is rated to operate at temperatures up to 540{degree}C and gage pressures up to 2.07 MPa. Gas stream conditions, temperature at 540{degree}C, gage pressure at 2.93 MPa, and gas flowrate at 0.0157 SCM per second, precluded the direct measurement of particulate loadings in the gas stream with the PMS unit. A side stream was extracted from the gas stream after it came over to the MGCR, (Modular Gas Cleanup Rig), from the FBG, pressurized fluidized-bed gasifier, but before it entered the filter testing vessel. A sampling probe of 0.635 cm O.D. thin wall stainless steel tubing was used for extracting the sample gas isokinetically based on the expected flowrate. The sample gas stream was further split into two streams; one was directed to the PMS unit and the other to the alkali monitor unit.

  19. Rate of Decline in Serum PFOA Concentrations after Granular Activated Carbon Filtration at Two Public Water Systems in Ohio and West Virginia

    E-Print Network [OSTI]

    Bartell, Scott M; Calafat, Antonia M; Lyu, Christopher; Kato, Kayoko; Ryan, P. Barry; Steenland, Kyle

    2009-01-01T23:59:59.000Z

    Court of Wood County, West Virginia, 10 April 2002. LittleSystems in Ohio and West Virginia Scott M. Bartell, 1,2plant in Washington, West Virginia, is owned and operated by

  20. Rate of decline in serum PFOA concentrations after granular activated carbon filtration at two public water systems in Ohio and West Virginia.

    E-Print Network [OSTI]

    Bartell, Scott M; Calafat, Antonia M; Lyu, Christopher; Kato, Kayoko; Ryan, P Barry; Steenland, Kyle

    2010-01-01T23:59:59.000Z

    Court of Wood County, West Virginia, 10 April 2002. LittleSystems in Ohio and West Virginia Scott M. Bartell, 1,2plant in Washington, West Virginia, is owned and operated by

  1. Novel Cleanup Agents Designed Exclusively for Oil Field Membrane Filtration Systems Low Cost Field Demonstrations of Cleanup Agents in Controlled Experimental Environments

    SciTech Connect (OSTI)

    David Burnett; Harold Vance

    2007-08-31T23:59:59.000Z

    The goal of our project is to develop innovative processes and novel cleaning agents for water treatment facilities designed to remove fouling materials and restore micro-filter and reverse osmosis (RO) membrane performance. This project is part of Texas A&M University's comprehensive study of the treatment and reuse of oilfield brine for beneficial purposes. Before waste water can be used for any beneficial purpose, it must be processed to remove contaminants, including oily wastes such as residual petroleum hydrocarbons. An effective way of removing petroleum from brines is the use of membrane filters to separate oily waste from the brine. Texas A&M and its partners have developed highly efficient membrane treatment and RO desalination for waste water including oil field produced water. We have also developed novel and new cleaning agents for membrane filters utilizing environmentally friendly materials so that the water from the treatment process will meet U.S. EPA drinking water standards. Prototype micellar cleaning agents perform better and use less clean water than alternate systems. While not yet optimized, the new system restores essentially complete membrane flux and separation efficiency after cleaning. Significantly the amount of desalinated water that is required to clean the membranes is reduced by more than 75%.

  2. Method of producing a colloidal fuel from coal and a heavy petroleum fraction. [partial liquefaction of coal in slurry, filtration and gasification of residue

    DOE Patents [OSTI]

    Longanbach, J.R.

    1981-11-13T23:59:59.000Z

    A method is provided for combining coal as a colloidal suspension within a heavy petroleum fraction. The coal is broken to a medium particle size and is formed into a slurry with a heavy petroleum fraction such as a decanted oil having a boiling point of about 300 to 550/sup 0/C. The slurry is heated to a temperature of 400 to 500/sup 0/C for a limited time of only about 1 to 5 minutes before cooling to a temperature of less than 300/sup 0/C. During this limited contact time at elevated temperature the slurry can be contacted with hydrogen gas to promote conversion. The liquid phase containing dispersed coal solids is filtered from the residual solids and recovered for use as a fuel or feed stock for other processes. The residual solids containing some carbonaceous material are further processed to provide hydrogen gas and heat for use as required in this process.

  3. Effects on Occupants of Enhanced Particle Filtration in a non-problem office environment: A Double-Blind Crossover Intervention Study

    E-Print Network [OSTI]

    Mendell, M.J.

    2011-01-01T23:59:59.000Z

    environmental comfort, performance indicators, and symptom0.27 - 0.81). A l l performance indicators (confusion scale,itchy, or irritated Performance indicators (7-not at all, to

  4. Estimation of Dry-Rock Elastic Moduli Based on the Simulation of Mud-Filtrate Invasion Effects on Borehole Acoustic Logs

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    of Petroleum Engineers This paper was prepared for presentation at the 2007 SPE Annual Technical Conference(s). Contents of the paper, as presented, have not been reviewed by the Society of Petroleum Engineers position of the Society of Petroleum Engineers, its officers, or members. Papers presented at SPE meetings

  5. Quantitative comparison of processes of oil-and water-based mud-filtrate invasion and corresponding effects on borehole resistivity measurements

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    resistivity from the simulated radial distri- butions of water saturation and salt concentration and compare of OBM invasion compared with those of WBM invasion. INTRODUCTION During the process of drilling wells for hydrocarbon exploration and production, drilling fluids sustain a pressure higher than that of formation

  6. Household ceramic water filter evaluation using three simple low-cost methods : membrane filtration, 3M Petrifilm and hydrogen sulfide bacteria in northern region, Ghana

    E-Print Network [OSTI]

    Mattelet, Claire (Claire Eliane H. Y.)

    2006-01-01T23:59:59.000Z

    Drinking water continues to be a major source of waterborne diseases and death in the world because many points of water collection remain unsafe. This thesis reports high level of fecal contamination found in rivers and ...

  7. Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report 3, January--March, 1997

    SciTech Connect (OSTI)

    Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

    1997-05-01T23:59:59.000Z

    Progress during this quarter is described on four tasks. The first task involves the recovery of organic matter from bleach effluents and black liquors, separation of carbohydrates and lignin degradation products, analysis of functional groups, and characterization of carbohydrate polymers. Progress in the second task was made in the selection of model compounds. Several subtasks are complete in Task 3, but the paper summarizes progress made in the determination of the residual hemicellulose content in the pulp samples. Finally, results are given for the measurement of metal adsorption isotherms on wood pulp. Goals for the next quarter are listed.

  8. Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Quarterly technical progress report, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Weber, G.F.; Ness, S.R.; Laudal, D.L.; Dunham, G.

    1992-05-01T23:59:59.000Z

    The objective of this program is to develop advanced concepts for removal of NO{sub x} from flue gas emitted by coalfired utility boilers, or for the control of NO{sub x} formation by advanced combustion modification techniques. Funded projects are required to focus on the development of technology that significantly advances the state of the art using a process or a combination of processes capable of reducing NO{sub x}. emissions to 60 ppM or less. The concept must have successfully undergone sufficient laboratory-scale development to justify scaleup for further evaluation at the pilot scale (not to exceed 5 MWe in size). Other requirements include production of a nonhazardous waste or a salable byproduct. The concept should have application to both new and retrofit coal-fired systems. The concept should also show the potential for a 50% cost savings when compared to a commercial selective catalytic reduction (SCR) process capable of meeting the 60-ppM NO{sub x} emission limit.

  9. A Genome-Wide Search for Linkage of Estimated Glomerular Filtration Rate (eGFR) in the Family Investigation of Nephropathy and Diabetes (FIND)

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    of Nephropathy and Diabetes (FIND) Farook Thameem 1 , RobertInvestigation of Nephropathy and Diabetes Research Group " 1National Institute of Diabetes and Digestive and Kidney

  10. OPERATIONS REVIEW OF THE SAVANNAH RIVER SITE INTEGRATED SALT DISPOSITION PROCESS - 11327

    SciTech Connect (OSTI)

    Peters, T.; Poirier, M.; Fondeur, F.; Fink, S.; Brown, S.; Geeting, M.

    2011-02-07T23:59:59.000Z

    The Savannah River Site (SRS) is removing liquid radioactive waste from its Tank Farm. To treat waste streams that are low in Cs-137, Sr-90, and actinides, SRS developed the Actinide Removal Process and implemented the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU). The Actinide Removal Process contacts salt solution with monosodium titanate to sorb strontium and select actinides. After monosodium titanate contact, the resulting slurry is filtered to remove the monosodium titanate (and sorbed strontium and actinides) and entrained sludge. The filtrate is transferred to the MCU for further treatment to remove cesium. The solid particulates removed by the filter are concentrated to {approx} 5 wt %, washed to reduce the sodium concentration, and transferred to the Defense Waste Processing Facility for vitrification. The CSSX process extracts the cesium from the radioactive waste using a customized solvent to produce a Decontaminated Salt Solution (DSS), and strips and concentrates the cesium from the solvent with dilute nitric acid. The DSS is incorporated in grout while the strip acid solution is transferred to the Defense Waste Processing Facility for vitrification. The facilities began radiological processing in April 2008 and started processing of the third campaign ('MarcoBatch 3') of waste in June 2010. Campaigns to date have processed {approx}1.2 million gallons of dissolved saltcake. Savannah River National Laboratory (SRNL) personnel performed tests using actual radioactive samples for each waste batch prior to processing. Testing included monosodium titanate sorption of strontium and actinides followed by CSSX batch contact tests to verify expected cesium mass transfer. This paper describes the tests conducted and compares results from facility operations. The results include strontium, plutonium, and cesium removal, cesium concentration, and organic entrainment and recovery data. Additionally, the poster describes lessons learned during operation of the facility.

  11. TESTING OF A ROTARY MICROFILTER TO SUPPORT HANFORD APPLICATIONS

    SciTech Connect (OSTI)

    Poirier, M; David Herman, D; David Stefanko, D; Samuel Fink, S

    2008-06-26T23:59:59.000Z

    Savannah River National Laboratory (SRNL) researchers are investigating and developing a rotary microfilter for solid-liquid separation applications at the Savannah River Site (SRS). Because of the success of that work, the Hanford Site is evaluating the use of the rotary microfilter for its Supplemental Pretreatment process. The authors performed rotary filter testing with a full-scale, 25-disk unit with 0.5 {micro} filter media manufactured by Pall Corporation using a Hanford AN-105 simulant at solids loadings of 0.06, 0.29, and 1.29 wt%. The conclusions from this testing are: (1) The filter flux at 0.06 wt% solids reached a near constant value at an average of 0.26 gpm/ft{sup 2} (6.25 gpm total). (2) The filter flux at 0.29 wt% solids reached a near constant value at an average of 0.17 gpm/ft{sup 2} (4 gpm total). (3) The filter flux at 1.29 wt% solids reached a near constant value at an average of 0.10 gpm/ft{sup 2} (2.4 gpm total). (4) Because of differences in solids loadings, a direct comparison between crossflow filter flux and rotary filter flux is not possible. The data show the rotary filter produces a higher flux than the crossflow filter, but the improvement is not as large as seen in previous testing. (5) Filtrate turbidity measured < 4 NTU in all samples collected. (6) During production, the filter should be rinsed with filtrate or dilute caustic and drained prior to an extended shutdown to prevent the formation of a layer of settled solids on top of the filter disks. (7) Inspection of the seal faces after {approx} 140 hours of operation showed an expected amount of initial wear, no passing of process fluid through the seal faces, and very little change in the air channeling grooves on the stationary face. (8) Some polishing was observed at the bottom of the shaft bushing. The authors recommend improving the shaft bushing by holding it in place with a locking ring and incorporated grooves to provide additional cooling. (9) The authors recommend that CH2MHill Hanford test other pore size media to determine the optimum pore size for Hanford waste.

  12. SOLIDS PRECIPITATION EVENT IN MCU CAUSAL ANALYSIS AND RECOMMENDATIONS FROM SOLIDS RECOVERY TEAM

    SciTech Connect (OSTI)

    Garrison, A.; Aponte, C.

    2014-08-15T23:59:59.000Z

    A process upset occurred in the Modular Caustic-Side Solvent Extraction Unit (MCU) facility on April 6th, 2014. During recovery efforts, a significant amount of solids were found in the Salt Solution Feed Tank (SSFT), Salt Solution Receipt Tanks (SSRTs), two extraction contactors, and scrub contactors. The solids were identified by Savannah River National Laboratory (SRNL) as primarily sodium oxalate and sodium alumina silicate (NAS) with the presence of some aluminum hydroxide. NAS solids have been present in the SSFT since simulant runs during cold chemical startup of MCU in 2007, and have not hindered operations since that time. During the process upset in April 2014, the oxalate solids partially blocked the aqueous outlet of the extraction contactors, causing salt solution to exit through the contactor organic outlet to the scrub contactors with the organic phase. This salt solution overwhelmed the scrub contactors and passed with the organic phase to the strip section of MCU. The partially reversed flow of salt solution resulted in a Strip Effluent (SE) stream that was high in Isopar™ L, pH and sodium. The primary cause of the excessive solids accumulation in the SSRTs and SSFT at MCU is attributed to an increase in the frequency of oxalic acid cleaning of the 512-S primary filter. Agitation in the SSRTs at MCU in response to cold weather likely provided the primary mechanism to transfer the solids to the contactors. Sources of the sodium oxalate solids are attributed to the oxalic acid cleaning solution used to clean the primary filter at the Actinide Removal Process (ARP) filtration at 512-S, as well as precipitation from the salt batch feed, which is at or near oxalate saturation. The Solids Recovery Team was formed to determine the cause of the solids formation and develop recommendations to prevent or mitigate this event in the future. A total of 53 recommendations were generated. These recommendations were organized into 4 focus areas: • Improve understanding of oxalate equilibrium and kinetics in salt solutions • Reduction/elimination of oxalic acid cleaning in 512-S • Flowsheet optimization • Improving diagnostic capability The recommendations implemented prior to resumption of MCU operations provide a risk mitigation or detection function through additional sampling and observation. The longer term recommendations provide a framework to increase the basic process knowledge of both oxalate chemistry and filtration behavior and then facilitate decisions that improve the salt flowsheet as a system.

  13. Appendix F: Air Permits Annual Site Environmental Report

    E-Print Network [OSTI]

    Pennycook, Steve

    Laboratory beryllium 161 Laboratory beryllium Y-9204-2-B 01-0020-71 025954P 313 Caustic scrubber stack exhaust 314 Caustic scrubber exhaust 317 Lithium metal wash station 318 Lithium cell pan wash station Y washing and drying Y-9212-C 01-0020-05 025984P 113 Dissolver trays/scrubber 114 Shear and hacksaw hood 128

  14. In situ X-ray pair distribution function analysis of accelerated carbonation of a synthetic calcium-?silicate?-hydrate gel

    SciTech Connect (OSTI)

    Morandeau, Antoine E.; White, Claire E. (Princeton)

    2015-01-01T23:59:59.000Z

    Calcium–silicate–hydrate (C–S–H) gel is the main binder component in hydrated ordinary Portland cement (OPC) paste, and is known to play a crucial role in the carbonation of cementitious materials, especially for more sustainable alternatives containing supplementary cementitious materials. However, the exact atomic structural changes that occur during carbonation of C–S–H gel remain unknown. Here, we investigate the local atomic structural changes that occur during carbonation of a synthetic calcium–silicate–hydrate gel exposed to pure CO? vapour, using in situ X-ray total scattering measurements and subsequent pair distribution function (PDF) analysis. By analysing both the reciprocal and real-space scattering data as the C–S–H carbonation reaction progresses, all phases present during the reaction (crystalline and non-crystalline) have been identified and quantified, with the results revealing the emergence of several polymorphs of crystalline calcium carbonate (vaterite and calcite) in addition to the decalcified C–S–H gel. Furthermore, the results point toward residual calcium being present in the amorphous decalcified gel, potentially in the form of an amorphous calcium carbonate phase. As a result of the quantification process, the reaction kinetics for the evolution of the individual phases have been obtained, revealing new information on the rate of growth/dissolution for each phase associated with C–S–H gel carbonation. Moreover, the investigation reveals that the use of real space diffraction data in the form of PDFs enables more accurate determination of the phases that develop during complex reaction processes such as C–S–H gel carbonation in comparison to the conventional reciprocal space Rietveld analysis approach.

  15. The Big Flow

    E-Print Network [OSTI]

    P. Sikivie

    2001-12-04T23:59:59.000Z

    The late infall of cold dark matter onto an isolated galaxy, such as our own, produces streams and caustics in its halo. The outer caustics are topological spheres whereas the inner caustics are rings. The self-similar model of galactic halo formation predicts that the caustic ring radii $a_n$ follow the approximate law $a_n \\sim 1/n$. In a study of 32 extended and well-measured external galactic rotation curves evidence was found for this law. In the case of the Milky Way, the locations of eight sharp rises in the rotation curve fit the prediction of the self-similar model at the 3% level. Moreover, a triangular feature in the IRAS map of the galactic plane is consistent with the imprint of a ring caustic upon the baryonic matter. These observations imply that the dark matter in our neighborhood is dominated by a single flow. Estimates of that flow's density and velocity vector are given.

  16. The application of a chemical equilibrium model, SOLTEQ, to predict the chemical speciations in stabilized/solidified waste forms

    E-Print Network [OSTI]

    Park, Joo-Yang

    1994-01-01T23:59:59.000Z

    19 22 23 28 28 31 33 36 37 37 39 39 45 69 84 APPENDIX 1 APPENDIX 2 VITA Page 93 105 126 vln LIST OF TABLES TABLE Page I Typical Chemical Composition of Ordinary Portland Cement (10) . . . . . . . . . . 7 2 Values of Empirical... activity coefficients in the high ionic strength solution occurring in the S/S waste forms and can describe the variable stoichiometry of calcium silicate hydrate (CSH). CSH is the primary hydration product of binder such as Portland cement. For SOLTEQ...

  17. Surface Nanostructuring of Polysulfone Membranes by Atmospheric Pressure Plasma-Induced Graft Polymerization (APPIGP)

    E-Print Network [OSTI]

    Kim, Soo Min

    2013-01-01T23:59:59.000Z

    irradiation. Membrane performance b,d Riboflavin filtration:L p (riboflavin) ? at pH (3-7) Dextran filtration: L p ?; J

  18. 194 PART 2 LANDSCAPE DESIGN GUIDELINES AND PRECINCT PLANS View of McGowan looking northwest

    E-Print Network [OSTI]

    Chen, Tsuhan

    GUTERMAN BIOCLIMATIC LAB PALMROAD POMOLOGY COLD STORAGE AND SALES WATER FILTRATION PLANT PLANTATIONS GUTERMAN BIOCLIMATIC LAB PALMROAD POMOLOGY COLD STORAGE AND SALES WATER FILTRATION PLANT PLANTATIONS

  19. Non-thermal plasma based technologies for the aftertreatment...

    Broader source: Energy.gov (indexed) [DOE]

    DPF Dielectric barrier discharge Copyright Accentus 2003 Improved Filtration Pellets 50-60% filtration Cordierite Monoliths Ceramic Fibres and Foams Meshes & Sintered...

  20. TBP recruitment to the U1 snRNA gene promoter is disrupted by substituting a U6 proximal sequence element A (PSEA) for the U1 PSEA

    E-Print Network [OSTI]

    Barakat, Nermeen H.

    2008-01-01T23:59:59.000Z

    filtrate vial into an SS-34 centrifuge rotor: counterbalancefilter assembly from centrifuge; then separate filtrate vialrecover the retentate. Centrifuge at 300-1000 Xg (1600-3000

  1. Reduction of radiation dose to radiosensitive organs and its tradeoff with image quality in Computed Tomography

    E-Print Network [OSTI]

    Zhang, Di

    2012-01-01T23:59:59.000Z

    of CT scanners such as spectra, bowtie filtration, and beamaccount, including spectra, bowtie filtration, and so on.In addition, the „moving? bowtie shaped filter cannot be

  2. Cement & Concrete Science Conference: Leeds, 2009 Hydration of alite containing aluminium

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Cement & Concrete Science Conference: Leeds, 2009 Hydration of alite containing aluminium Begarin in cement is tricalcium silicate which leads during its hydration to the nucleation and growth of calcium silicate hydrate (referred to C-S-H (CaO)x-SiO2-(H2O)y). The development of this hydrate around the cement

  3. Sr radionuclide in cement: An atomistic modeling study Mostafa Youssef a

    E-Print Network [OSTI]

    Yildiz, Bilge

    Docking 90 Sr radionuclide in cement: An atomistic modeling study Mostafa Youssef a , Roland J: Available online xxxx Keywords: Molecular simulation Cement Nuclear waste storage Mechanical properties a b crystalline analog, the 9 Å-tobermorite. C­S­H is the major binding phase of cement. Strontium was shown

  4. Concrete is the most prevalent man-made substance on Earth. This strong, durable building material has been in use for at

    E-Print Network [OSTI]

    Entekhabi, Dara

    -high-density concrete, a containment vessel for nuclear waste might last up to 16,000 years in- stead of 100. Changes that model to perform six tests that validated its accuracy. FINDINGS The team found that C-S-H isn't really

  5. Effect of temperature on the hydration of Portland cement blended with siliceous fly ash

    SciTech Connect (OSTI)

    Deschner, Florian, E-mail: florian.deschner@gmail.com [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland)] [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Lothenbach, Barbara; Winnefeld, Frank [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland)] [Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Neubauer, Jürgen [GeoZentrum Nordbayern, Mineralogy, University of Erlangen-Nuremberg, 91054 Erlangen (Germany)] [GeoZentrum Nordbayern, Mineralogy, University of Erlangen-Nuremberg, 91054 Erlangen (Germany)

    2013-10-15T23:59:59.000Z

    The effect of temperature on the hydration of Portland cement pastes blended with 50 wt.% of siliceous fly ash is investigated within a temperature range of 7 to 80 °C. The elevation of temperature accelerates both the hydration of OPC and fly ash. Due to the enhanced pozzolanic reaction of the fly ash, the change of the composition of the C–S–H and the pore solution towards lower Ca and higher Al and Si concentrations is shifted towards earlier hydration times. Above 50 °C, the reaction of fly ash also contributes to the formation of siliceous hydrogarnet. At 80 °C, ettringite and AFm are destabilised and the released sulphate is partially incorporated into the C–S–H. The observed changes of the phase assemblage in dependence of the temperature are confirmed by thermodynamic modelling. The increasingly heterogeneous microstructure at elevated temperatures shows an increased density of the C–S–H and a higher coarse porosity. -- Highlights: •The reaction of quartz powder at 80 °C strongly enhances the compressive strength. •Almost no strength increase of fly ash blended OPC at 80 °C was found after 2 days. •Siliceous hydrogarnet is formed upon the reaction of fly ash at high temperatures. •Temperature dependent change of the system was simulated by thermodynamic modelling. •Destabilisation of ettringite above 50 °C correlates with sulphate content of C–S–H.

  6. Synthesis and characterization of hafnium and molybdenum bifunctional initiators for the preparation of triblock copolymers

    E-Print Network [OSTI]

    Gabert, Andrea Jennifer

    2007-01-01T23:59:59.000Z

    Chapter 1. Three monofunctional mixed alkyl hafnium complexes containing the (MesNpy)2 ligand ([(MesitylNCH2)2CMe(2-CsH4N)]2) were synthesized. (MesNpy)Hf(Neo)R ((2b), R = Me; Neo = CH2CMe2Ph) and (MesNpy)Hf(CH2TMS)(R), ...

  7. Two-dimensional protonic diffusion in a hydrogen-bonded compound CsOH . H2O, studied by solid state NMR

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    949 Two-dimensional protonic diffusion in a hydrogen-bonded compound CsOH . H2O, studied by solid césium hydroxide monohydrate CsH3O2 polycristallin révèle une diffusion protonique rapide dans ses phases hautes températures. Par mesure directe, la constante de diffusion est trouvée D = 1.2 10-5 exp(-1700/T

  8. 1 Copyright ## by ASME Proceedings of ICEM `03

    E-Print Network [OSTI]

    Sheffield, University of

    ) as these offer several advantages over Portland cement, notably a lower heat of hydration. The use. Where physical adsorption is a significant factor for immobilisation, the calcium silicate hydrate gel (C-S-H) formed on hydration of a Portland cement is advantageous as it has a high surface area

  9. Contact Mechanics Based Mechanical Characterization of Portland Cement Paste 

    E-Print Network [OSTI]

    Jones, Christopher

    2012-02-14T23:59:59.000Z

    are derived to characterize creep indentation tests performed on hardened cement paste and to extract the time-dependent properties. The effect of approximating C-S-H viscoelastic properties with a time-independent Poisson's ratio is discussed, and arguments...

  10. Comparison study of solid/liquid separation techniques for oilfield pit closures

    SciTech Connect (OSTI)

    Wojtanowicz, A.K.; Field, S.D.; Osterman, M.C.

    1987-07-01T23:59:59.000Z

    Vacuum filtration, belt-press filtration, screw-press filtration, and centrifuging techniques were evaluated in full-scale experiments for use in oilfield waste volume reduction. Centrifuging and belt-press filtration proved applicable to oilfield pit cleanups. Also, an effective chemical conditioning (coagulation and flocculation) was found for deliquoring seven types of oilfield waste slurries before separation.

  11. Provisional Patent Application Electrostatic Fluid Deionization, particularly Seawater Desalination

    E-Print Network [OSTI]

    McEliece, Robert J.

    foregoing the secondary. [P 6] Filtration uses particulate beds as a large strainer, physically removing

  12. Reducing Indoor Residential Exposures to Outdoor Pollutants

    E-Print Network [OSTI]

    include ventilation systems, filtration and other measures. These strategies can be used for several types

  13. CHARACTERIZATION OF A PRECIPITATE REACTOR FEED TANK (PRFT) SAMPLE FROM THE DEFENSE WASTE PROCESSING FACILITY (DWPF)

    SciTech Connect (OSTI)

    Crawford, C.; Bannochie, C.

    2014-05-12T23:59:59.000Z

    A sample of from the Defense Waste Processing Facility (DWPF) Precipitate Reactor Feed Tank (PRFT) was pulled and sent to the Savannah River National Laboratory (SRNL) in June of 2013. The PRFT in DWPF receives Actinide Removal Process (ARP)/ Monosodium Titanate (MST) material from the 512-S Facility via the 511-S Facility. This 2.2 L sample was to be used in small-scale DWPF chemical process cell testing in the Shielded Cells Facility of SRNL. A 1L sub-sample portion was characterized to determine the physical properties such as weight percent solids, density, particle size distribution and crystalline phase identification. Further chemical analysis of the PRFT filtrate and dissolved slurry included metals and anions as well as carbon and base analysis. This technical report describes the characterization and analysis of the PRFT sample from DWPF. At SRNL, the 2.2 L PRFT sample was composited from eleven separate samples received from DWPF. The visible solids were observed to be relatively quick settling which allowed for the rinsing of the original shipping vials with PRFT supernate on the same day as compositing. Most analyses were performed in triplicate except for particle size distribution (PSD), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and thermogravimetric analysis (TGA). PRFT slurry samples were dissolved using a mixed HNO3/HF acid for subsequent Inductively Coupled Plasma Atomic Emission Spectroscopy (ICPAES) and Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) analyses performed by SRNL Analytical Development (AD). Per the task request for this work, analysis of the PRFT slurry and filtrate for metals, anions, carbon and base were primarily performed to support the planned chemical process cell testing and to provide additional component concentrations in addition to the limited data available from DWPF. Analysis of the insoluble solids portion of the PRFT slurry was aimed at detailed characterization of these solids (TGA, PSD, XRD and SEM) in support of the Salt IPT chemistry team. The overall conclusions from analyses performed in this study are that the PRFT slurry consists of 0.61 Wt.% insoluble MST solids suspended in a 0.77 M [Na+] caustic solution containing various anions such as nitrate, nitrite, sulfate, carbonate and oxalate. The corresponding measured sulfur level in the PRFT slurry, a critical element for determining how much of the PRFT slurry gets blended into the SRAT, is 0.437 Wt.% TS. The PRFT slurry does not contain insoluble oxalates nor significant quantities of high activity sludge solids. The lack of sludge solids has been alluded to by the Salt IPT chemistry team in citing that the mixing pump has been removed from Tank 49H, the feed tank to ARP-MCU, thus allowing the sludge solids to settle out. ? The PRFT aqueous slurry from DWPF was found to contain 5.96 Wt.% total dried solids. Of these total dried solids, relatively low levels of insoluble solids (0.61 Wt.%) were measured. The densities of both the filtrate and slurry were 1.05 g/mL. ? Particle size distribution of the PRFT solids in filtered caustic simulant and XRD analysis of washed/dried PRFT solids indicate that the PRFT slurry contains a bimodal distribution of particles in the range of 1 and 6 ?m and that the particles contain sodium titanium oxide hydroxide Na2Ti2O4(OH)2 crystalline material as determined by XRD. These data are in excellent agreement with similar data obtained from laboratory sampling of vendor supplied MST. Scanning Electron Microscopy (SEM) combined with Energy Dispersive X-ray Spectroscopy (EDS) analysis of washed/dried PRFT solids shows the particles to be like previous MST analyses consisting of irregular shaped micron-sized solids consisting primarily of Na and Ti. ? Thermogravimetric analysis of the washed and unwashed PRFT solids shows that the washed solids are very similar to MST solids. The TGA mass loss signal for the unwashed solids shows similar features to TGA performed on cellulose nitrate filter paper indicating significant presence of the deteriorated filter

  14. MACHO Mass Determination Based on Space Telescope Observation

    E-Print Network [OSTI]

    Mareki Honma

    1999-03-24T23:59:59.000Z

    We investigate the possibility of lens mass determination for a caustic crossing microlensing event based on a space telescope observation. We demonstrate that the parallax due to the orbital motion of a space telescope causes a periodic fluctuation of the light curve, from which the lens distance can be derived. Since the proper motion of the lens relative to the source is also measurable for a caustic crossing event, one can find a full solution for microlensing properties of the event, including the lens mass. To determine the lens mass with sufficient accuracy, the light curve near the caustic crossing should be observed within uncertainty of $\\sim$ 1%. We argue that the Hubble Space Telescope observation of the caustic crossing supplied with ground-based observations of the full light curve will enable us to determine the mass of MACHOs, which is crucial for understanding the nature of MACHOs.

  15. Appendix F: Air Permits Annual Site Environmental Report

    E-Print Network [OSTI]

    Pennycook, Steve

    scrubber stack exhaust 314 Caustic scrubber exhaust 317 Lithium metal wash station 318 Lithium cell pan washing and drying Y-9212-C 01-0020-05 025984P 113 Dissolver trays/scrubber 114 Shear and hacksaw hood 128

  16. Canned Air in China

    E-Print Network [OSTI]

    Hacker, Randi

    2013-10-23T23:59:59.000Z

    Broadcast Transcript: Not that long ago, coal smoke made the air here in Beijing so caustic that your nasal passages were seared with each breath. Those were the good old days: Car ownership was limited to government ...

  17. The Effect of Simulated Barium Carbonate Waste Stream on the Hydration of Composite Cement Systems

    E-Print Network [OSTI]

    Sheffield, University of

    Claire Utton*, Dr N B Milestone, Dr J Hill Immobilisation Science Laboratory, Department of Engineering of spent uranium oxide fuel and passed through a caustic scrubber producing a sodium carbonate waste form

  18. CX-007078: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Nuclear Magnetic Resonance analysis of spent Caustic Side Solvent Extraction (CSSX) SolventCX(s) Applied: B3.6Date: 08/18/2011Location(s): Aiken, South CarolinaOffice(s): Environmental Management, Savannah River Operations Office

  19. CX-010025: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Actinide Removal Process /Modular Caustic Side Solvent Extraction Unit Life Extension Support Testing CX(s) Applied: B3.6 Date: 01/24/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  20. --No Title--

    Broader source: Energy.gov (indexed) [DOE]

    This work (Module A) involves performing the fluidized bed steam reforming (FBSR) process on caustic DWPF Offgas Condensate Tank (OGCT) in SRNL HLC, A-block. The DWPF OGCT...

  1. Control of the Accumulation of Non-Process Elements in Pulp Mills with Bleach Filtrate Reuse: A Chemical Equilibrium Approach to Predicting the Partitioning of Metals in Pulp Mill and Bleach Plant Streams

    SciTech Connect (OSTI)

    Frederick, W.J. Jr.; Rudie, A.W.; Schmidl, G.W.; Sinquefield, S.A.; Rorrer, G.L.; Laver, M.L.; Yantasee, W.; Ming, D.

    2000-08-01T23:59:59.000Z

    The overall goal of this project was to develop fundamental, experimentally based methods for predicting the solubility or organic and inorganic matter and their interactions in recycled effluent from kraft pulp mills and bleach plants. This included: characterizing the capacity of wood pulp and dissolved organic matter to bind metal ions, developing a thermodynamic database of properties needed to describe the solubility of inorganic matter in pulp mill streams, incorporation of the database into equilibrium calculation software for predicting the solubility of the metals of interest, and evaluating its capability to predict the distribution of the metals between pulp fibers, inorganic precipitates, and solution.

  2. Runoff Polishing by Natural Media Filtration: Upflow vs. Downflow Mukesh R. Pratap1, Shirley E. Clark2, Robert Pitt3, Christopher D. Roenning2, Daniel P. Treese2, and Christina Y.S. Siu2

    E-Print Network [OSTI]

    Clark, Shirley E.

    . Turbidity removal seen in both modes (data not shown). Some washout of media likely in both modes, but washout of media lasted longer in the upflow mode. Phosphate removal (data not shown) was possible) Maintenance: remove upper media layer Disadvantages: Clogging Pretreatment (i.e., sedimentation to reduce

  3. Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Milestones and progress, Quarter 9 (July 1--September 30, 1998)

    SciTech Connect (OSTI)

    Frederick, W.J.; Laver, M.L.; Rorrer, G.L.; Rudie, A.W.; Schmidl, W.

    1998-12-31T23:59:59.000Z

    The two approach changes that were discussed and recommended in the Quarter 8 (April 1--June 30, 1998) progress report have been implemented in the current project plan. The OLI software has been used to develop a preliminary process model for predicting the distribution of NPE`s in a two stage brownstock washer, and the OLI database has been upgraded to include improved chemical equilibrium data for metal-organic interactions. This exercise served as a tool to evaluate the data and methods developed in this study, and to demonstrate its utility to industry. The Weyerhaeuser-NAELS software has also been applied to predicting inorganic solubility behavior. Task C-1.2, Estimation of unavailable thermodynamic parameters (scheduled completion date: 12/97), has been combined with Task D-2.1, Evaluation of the estimation procedure (scheduled completion date: 3/99) with a new scheduled completion date of 8/99. A model for the adsorption of metal ions on wood pulp fibers will include transport effects as well as adsorption equilibrium, and will be combined with a brownstock washer model to evaluate its predictive capability in comparison with mill data, and to demonstrate the applicability of the results obtained in this project. Three tasks are behind schedule: Task A-2.3, Measurement of stability constants for wood organics with metal ions (scheduled completion date: 6/98), Task B-2.1, Measure metal adsorption isotherms on wood pulp (scheduled completion date: 9/97), and Task B-2.3, Measure metal ion adsorption kinetics for strongly adsorbing metal species (scheduled completion date: 3/98). The reasons and expected completion dates are discussed in the Performance Variances and Open Items section. All other tasks are either completed, on, or ahead of schedule.

  4. Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Milestones and progress, Quarter 8 (April 1--June 30, 1998)

    SciTech Connect (OSTI)

    Frederick, W.J.; Laver, M.L.; Rorrer, G.L.; Rudie, A.W.; Schmidl, W.

    1998-08-01T23:59:59.000Z

    Overall, this project is on schedule and proceeding as planned. Two approach changes are recommended. One is to rely on commercially developed software, in particular that developed by OLI Systems, Inc., and now being expanded in a collaborative effort between OLI Systems, Inc. and IPST to provide a simulation package for the pulp and paper industry and to integrate it with existing process simulation tools used by that industry. The second is the development of a detailed brownstock/bleached fiber washer model as a tool to evaluate the data and methods developed in this study, and to demonstrate its utility to industry. Both of these are discussed in more detail in the Approach Changes section of this report. Two tasks are behind schedule. They are Task A-2.3, Measurement of stability constants for wood organics with metal ions (scheduled completion date: 6/98), and Task C-1.2, Estimation of unavailable thermodynamic parameters (scheduled completion date: 12/97). The reasons and expected completion dates for these tasks are discussed in the Performance Variances and Open Items section of this report. All other tasks are either completed, or on or ahead of schedule.

  5. Influence of amorphous silica on the hydration in ultra-high performance concrete

    SciTech Connect (OSTI)

    Oertel, Tina, E-mail: tina.oertel@isc.fraunhofer.de [Fraunhofer–Institute for Silicate Research ISC, Neunerplatz 2, 97082 Würzburg (Germany); Inorganic Chemistry I, Universität Bayreuth, Universitätsstr. 30, 95440 Bayreuth (Germany); Helbig, Uta, E-mail: uta.helbig@th-nuernberg.de [Crystallography and X-ray Methods, Technische Hochschule Nürnberg Georg Simon Ohm, Wassertorstraße 10, 90489 Nürnberg (Germany); Hutter, Frank [Fraunhofer–Institute for Silicate Research ISC, Neunerplatz 2, 97082 Würzburg (Germany); Kletti, Holger [Building Materials, Bauhaus–Universität Weimar, Coudraystr. 11, 99423 Weimar (Germany); Sextl, Gerhard [Fraunhofer–Institute for Silicate Research ISC, Neunerplatz 2, 97082 Würzburg (Germany); Chemical Technology of Advanced Materials, Julius Maximilian Universität, Röntgenring 11, 97070 Würzburg (Germany)

    2014-04-01T23:59:59.000Z

    Amorphous silica particles (silica) are used in ultra-high performance concretes to densify the microstructure and accelerate the clinker hydration. It is still unclear whether silica predominantly increases the surface for the nucleation of C–S–H phases or dissolves and reacts pozzolanically. Furthermore, varying types of silica may have different and time dependent effects on the clinker hydration. The effects of different silica types were compared in this study by calorimetric analysis, scanning and transmission electron microscopy, in situ X-ray diffraction and compressive strength measurements. The silica component was silica fume, pyrogenic silica or silica synthesized by a wet-chemical route (Stoeber particles). Water-to-cement ratios were 0.23. Differences are observed between the silica for short reaction times (up to 3 days). Results indicate that silica fume and pyrogenic silica accelerate alite hydration by increasing the surface for nucleation of C–S–H phases whereas Stoeber particles show no accelerating effect.

  6. Thermodynamics and cement science

    SciTech Connect (OSTI)

    Damidot, D., E-mail: damidot@ensm-douai.fr [Universite Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France); Lothenbach, B. [Empa, Lab. Concrete and Construction Chemistry, Duebendorf (Switzerland); Herfort, D. [Cementir Holding (Denmark); Glasser, F.P. [Chemistry Department, University of Aberdeen, Aberdeen (United Kingdom)

    2011-07-15T23:59:59.000Z

    Thermodynamics applied to cement science has proved to be very valuable. One of the most striking findings has been the extent to which the hydrate phases, with one conspicuous exception, achieve equilibrium. The important exception is the persistence of amorphous C-S-H which is metastable with respect to crystalline calcium silicate hydrates. Nevertheless C-S-H can be included in the scope of calculations. As a consequence, from comparison of calculation and experiment, it appears that kinetics is not necessarily an insuperable barrier to engineering the phase composition of a hydrated Portland cement. Also the sensitivity of the mineralogy of the AFm and AFt phase compositions to the presence of calcite and to temperature has been reported. This knowledge gives a powerful incentive to develop links between the mineralogy and engineering properties of hydrated cement paste and, of course, anticipates improvements in its performance leading to decreasing the environmental impacts of cement production.

  7. New insights into water bonding during early tricalcium silicate hydration with quasielastic neutron scattering

    SciTech Connect (OSTI)

    Gutberlet, T., E-mail: gutberlet@cbm.bv.tum.de [Centre for Building Materials (CBM), Technische Universität München, Baumbachstraße 7, 81245 Munich (Germany); Hilbig, H.; Beddoe, R.E. [Centre for Building Materials (CBM), Technische Universität München, Baumbachstraße 7, 81245 Munich (Germany)] [Centre for Building Materials (CBM), Technische Universität München, Baumbachstraße 7, 81245 Munich (Germany); Lohstroh, W. [Forschungs-Neutronenquelle Heinz Maier-Leibnitz (FRM II), Technische Universität München, Lichtenbergstraße 1, 85748 Garching (Germany)] [Forschungs-Neutronenquelle Heinz Maier-Leibnitz (FRM II), Technische Universität München, Lichtenbergstraße 1, 85748 Garching (Germany)

    2013-09-15T23:59:59.000Z

    New information on the water bonding during the first 36 h of hydration of tricalcium silicate was obtained using the high neutron flux at the sample position of the time-of-flight spectrometer (TOFTOF), FRM II in Garching, Germany, together with {sup 29}Si NMR and X-ray diffraction measurements. A rapid increase in the amount of constrained water was observed at the beginning of the induction period. This is attributed to the formation of an early C-S-H with a large specific surface area (around 800 m{sup 2}/g). During subsequent hydration, the amount of constrained water, as given by the total surface area of the hydration products, is controlled by (a) the formation of new metastable early C-S-H which increases total surface area and (b) polymerisation processes which reduce total surface area. The relative contribution of these processes varies during hydration.

  8. Pushing schedule derivation method

    SciTech Connect (OSTI)

    Henriquez, B. [Compania Siderurgica Huachipato S.A., Talcahuano (Chile)

    1996-12-31T23:59:59.000Z

    The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.

  9. Copyright 2004, Society of Petroleum Engineers Inc. This paper was prepared for presentation at the SPE Annual Technical Conference and

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    of the process of mud-filtrate invasion yield 2D cross-sections of water saturation, salt concentration drilling causes invasion of mud-filtrate into porous rock formations. Of particular interest are thinly

  10. -OGP 04 (1) -Predicting Injectivity Decline

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    the Arabian Gulf is treated by filtration and deaeration before distribution through a long, complex, network further south. Water from the Arabian Gulf is treated by filtration and deaeration before distribution

  11. The effect of adjacent layers like biofilms on mass transport through nanofiltration membranes

    E-Print Network [OSTI]

    Bothe, Dieter

    , which is always present on the membrane surface in crossflow filtration processes, as well as a feed to high tangential flow velocities in crossflow filtrations, the size of this biofilm is limited to values

  12. Use of CaO as an activator for producing a price-competitive non-cement structural binder using ground granulated blast furnace slag

    SciTech Connect (OSTI)

    Kim, Min Sik; Jun, Yubin; Lee, Changha, E-mail: clee@unist.ac.kr; Oh, Jae Eun, E-mail: ohjaeeun@unist.ac.kr

    2013-12-15T23:59:59.000Z

    The use of calcium oxide (CaO) demonstrates a superior potential for the activation of ground granulated blast furnace slag (GGBFS), and it produces a higher mechanical strength than calcium hydroxide [Ca(OH){sub 2}]. The mechanical strength differences between CaO- and Ca(OH){sub 2}-activated GGBFS binders are explored using isothermal calorimetry, powder X-ray diffraction, thermogravimetric and differential thermal analysis (TGA and DTA) as well as compressive strength testing. Calcium silicate hydrate (C–S–H), Ca(OH){sub 2} and a hydrotalcite-like phase are found as reaction products in all samples. The TGA and DTA results indicate that the use of CaO produces more C–S–H, although this is not likely to be the primary cause of higher strength development in the CaO-activated GGBFS. Rather, other factors such as porosity may govern the strength at a higher order of magnitude. Significant reduction of Ca(OH){sub 2} occurs only with the use of Ca(OH){sub 2}, followed by the formation of carbonate (CaCO{sub 3}), indicating carbonation. -- Highlights: •CaO showed a better potential for the activation of GGBFS than Ca(OH){sub 2}. •Strength test, XRD, TGA/DTA and isothermal calorimetry are used. •C-S-H, Ca(OH){sub 2}, and a hydrotalcite-like phase are found in all samples. •The use of Ca(OH){sub 2} causes some degree of carbonation.

  13. The Role of Bone Morphogenetic Protein 10 (BMP10) and Crossveinless 2 (CV2) in Cardiomyogenesis

    E-Print Network [OSTI]

    Cubberly, Mark Raymond

    2013-01-01T23:59:59.000Z

    After filtration through a mesh strainer, the cells werewell dishes, 70 µm cell strainers are placed into each well.

  14. 656 Florida Entomologist 85(4) December 2002 A NOVEL AERIAL-INTERCEPTION TRAP FOR ARTHROPOD SAMPLING

    E-Print Network [OSTI]

    Carrel, James E.

    with a conventional meat baster and rapidly filtering it through a tea strainer, allowing the filtrate to re- turn

  15. Results from tests of DuPont crossflow filter

    SciTech Connect (OSTI)

    Steimke, J.L.

    2000-05-05T23:59:59.000Z

    Crossflow filtration will be used to filter radioactive waste slurry as part of the Late Wash Process.

  16. Conditioned stochastic differential equations: theory, examples and ...

    E-Print Network [OSTI]

    2002-07-03T23:59:59.000Z

    Keywords: Brownian bridge; Conditioning; Initial enlargement of filtration; Exponential generalization of. Pitman's 2M-X theorem; Filtering; Portfolio optimization.

  17. Rheology and Convective Heat Transfer of Colloidal Gas Aphrons in Horizontal Minichannels

    E-Print Network [OSTI]

    Tseng, H.; Pilon, L.; Warrier, G.

    2006-01-01T23:59:59.000Z

    processes including centrifugation, filtration, extraction and chromatography, (iv) cell flotation [16] such as yeast-cells [17], (iv) mineral

  18. Cummins SuperTruck Program - Technology and System Level Demonstration...

    Broader source: Energy.gov (indexed) [DOE]

    On Program Participants - Collaborations Cummins Inc. - Cummins Fuel Systems - Cummins Turbo Technologies - Cummins Emissions Solutions - Cummins Electronics - Cummins Filtration...

  19. Cummins SuperTruck Program - Technology Demonstration of Highly...

    Broader source: Energy.gov (indexed) [DOE]

    On Program Participants - Collaborations Cummins Inc. - Cummins Fuel Systems - Cummins Turbo Technologies - Cummins Emissions Solutions - Cummins Electronics - Cummins Filtration...

  20. The Dissolution and Characterization of Aluminum Clad Oxide Fuel

    SciTech Connect (OSTI)

    Gray, J.H.

    1998-10-26T23:59:59.000Z

    Laboratory dissolution studies of aluminum clad mixed oxide fuel rods have been conducted using two different F-Canyon decladding and dissolving flowsheets. During the first phase of the experimental program, materials from three different color coded fuel rods were dissolved in caustic and nitric acid solutions. The final phase of the laboratory program involved the dissolution and characterization of materials from three cracked pellet fuel rods using a selected caustic/ nitric acid flowsheet.Laboratory results obtained from the initial dissolution studies identified several inconsistencies and potential problem issues with the behavior of materials from the color coded fuel rods. Based on these findings and influenced by the difficulties introduced by using the RCRA listed mercury during processing, the flowsheet selected for dissolving these aluminum clad fuel rods in F-Canyon dissolvers was the two- step caustic decladding/ nitric acid dissolution flowsheet.The final phase of the experimental program involved testing materials from three cracked pellet fuel rods using the selected flowsheet. Again all aluminum fuel rod components dissolved during the decladding step. However, some uranium and plutonium bearing solids remained with the caustic decladding solution which could be sent to waste. The quantities of uranium and plutonium expected to remain with the caustic solutions are small.Fluoride ions will need to be present in the nitric acid dissolver solution to dissolve all solids. At 0.05 molar fluoride concentration, no plutonium bearing solids remained in the product solutions.

  1. MEASURING THE MASS DISTRIBUTION IN GALAXY CLUSTERS

    SciTech Connect (OSTI)

    Geller, Margaret J. [Smithsonian Astrophysical Observatory, 60 Garden St., Cambridge, MA 02138 (United States)] [Smithsonian Astrophysical Observatory, 60 Garden St., Cambridge, MA 02138 (United States); Diaferio, Antonaldo [Dipartimento di Fisica, Universita degli Studi di Torino, via P. Giuria 1, I-10125 Torino (Italy)] [Dipartimento di Fisica, Universita degli Studi di Torino, via P. Giuria 1, I-10125 Torino (Italy); Rines, Kenneth J. [Department of Physics and Astronomy, Western Washington University, Bellingham, WA 98225 (United States)] [Department of Physics and Astronomy, Western Washington University, Bellingham, WA 98225 (United States); Serra, Ana Laura, E-mail: mgeller@cfa.harvard.edu, E-mail: diaferio@ph.unito.it, E-mail: kenneth.rines@wwu.edu, E-mail: serra@to.infn.it [INAF, Osservatorio Astronomico di Torino, via Osservatorio 20, I-10025 Pino Torinese (Italy)

    2013-02-10T23:59:59.000Z

    Cluster mass profiles are tests of models of structure formation. Only two current observational methods of determining the mass profile, gravitational lensing, and the caustic technique are independent of the assumption of dynamical equilibrium. Both techniques enable the determination of the extended mass profile at radii beyond the virial radius. For 19 clusters, we compare the mass profile based on the caustic technique with weak lensing measurements taken from the literature. This comparison offers a test of systematic issues in both techniques. Around the virial radius, the two methods of mass estimation agree to within {approx}30%, consistent with the expected errors in the individual techniques. At small radii, the caustic technique overestimates the mass as expected from numerical simulations. The ratio between the lensing profile and the caustic mass profile at these radii suggests that the weak lensing profiles are a good representation of the true mass profile. At radii larger than the virial radius, the extrapolated Navarro, Frenk and White fit to the lensing mass profile exceeds the caustic mass profile. Contamination of the lensing profile by unrelated structures within the lensing kernel may be an issue in some cases; we highlight the clusters MS0906+11 and A750, superposed along the line of sight, to illustrate the potential seriousness of contamination of the weak lensing signal by these unrelated structures.

  2. MODELING OF PARTICULATE REMOVAL IN MIXED MEDIA

    E-Print Network [OSTI]

    Clark, Shirley E.

    versus Downflow Modes DATA COLLECTION #12;4 UPFLOW CONTRUCTION #12;5 UPFLOW FILTRATION RESULTS · Drawback to downflow filtration is the need for pretreatment. Upflow filtration may remove need for pretreatment-specific, and transfer of data from lab-scale to field is not applicable. ACKNOWLEDGMENTS Anitha Balakrishnan, UAB Renee

  3. Copyright 2004, Society of Petroleum Engineers Inc. This paper was prepared for presentation at the SPE Annual Technical Conference and

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    standard methods often remain influenced by formation damage and mud-filtrate invasion. Proper quantitative understanding of the process of mud-filtrate invasion is necessary to identity and assess biases in the standard to quantity the effects of mud-filtrate invasion on borehole acoustic logs and introduce a novel algorithm

  4. Annual Logging Symposium, May 25-28, 2008 PREDICTION OF FORMATION-TESTER FLUID-SAMPLE QUALITY IN

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    with formation testers are often contaminated with mud filtrate. In some cases, it may take hours or even days to achieve acceptable levels of mud-filtrate contamination, thereby rendering the fluid- sampling operation the high spatial asymmetry of the mud-filtrate invaded zone (especially for the case of point probes

  5. Invasion Correction of Acoustic Logs in a Gas Reservoir Shihong Chi*, Jianghui Wu, and Carlos Torres-Verdin, The University of Texas at Austin

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    Torres-Verdin, The University of Texas at Austin Summary Mud-filtrate invasion modifies the connate fluid saturation distribution of mud filtrate and connate formation fluids is first obtained by simulating the mud, the near-wellbore formation is often altered by stress, mud-filtrate invasion, chemical reactions, and many

  6. Survey of electrochemical production of inorganic compounds. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

  7. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    SciTech Connect (OSTI)

    HARRINGTON SJ

    2011-01-06T23:59:59.000Z

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  8. Conformal chemically resistant coatings for microflow devices

    DOE Patents [OSTI]

    Folta, James A.; Zdeblick, Mark

    2003-05-13T23:59:59.000Z

    A process for coating the inside surfaces of silicon microflow devices, such as electrophoresis microchannels, with a low-stress, conformal (uniform) silicon nitride film which has the ability to uniformly coat deeply-recessed cavities with, for example, aspect ratios of up to 40:1 or higher. The silicon nitride coating allows extended exposure to caustic solutions. The coating enables a microflow device fabricated in silicon to be resistant to all classes of chemicals: acids, bases, and solvents. The process involves low-pressure (vacuum) chemical vapor deposition. The ultra-low-stress silicon nitride deposition process allows 1-2 .mu.m thick films without cracks, and so enables extended chemical protection of a silicon microflow device against caustics for up to 1 year. Tests have demonstrated the resistance of the films to caustic solutions at both ambient and elevated temperatures to 65.degree. C.

  9. Dezincing galvanized scrap

    SciTech Connect (OSTI)

    Dudek, F.J.; Daniels, E.J. [Argonne National Lab., IL (United States); Braun, C. [Metal Recovery Technologies, Inc., East Chicago, IN (United States)

    1998-07-01T23:59:59.000Z

    A caustic leach dezincing process is being developed for upgrading galvanized stamping plant scrap into clean scrap with recovery of the zinc. With further development the technology could also process galvanized scrap from obsolete automobiles. This paper will review: (1) the status of recent pilot plant operations in East Chicago, Indiana and plans for a commercial demonstration facility with a dezincing capacity of up to 250,000 tonnes/year, (2) the economics of caustic dezincing, and (3) benefits of decreased cost of environmental compliance, raw material savings, and improved operations with use of dezinced scrap.

  10. The 4th Symposium on Analysis & PDEs - Purdue University

    E-Print Network [OSTI]

    All talks are in MATH 175. Registration and coffee breaks are in Math Library Lounge (3rd floor in MATH building). TUESDAY ... Sub-Riemannian geometry in models of the visual cortex [Slides]. 3:00-4:00. Giorgio Talenti Università di Firenze. On complex-valued 2D eikonals: continuation past a caustic [Slides]. 4:

  11. CAIRNS: The Cluster And Infall Region Nearby Survey I. Redshifts and Mass Profiles

    E-Print Network [OSTI]

    K. Rines; M. J. Geller; M. J. Kurtz; A. Diaferio

    2003-06-25T23:59:59.000Z

    The CAIRNS (Cluster And Infall Region Nearby Survey) project is a spectroscopic survey of the infall regions surrounding eight nearby, rich, X-ray luminous clusters of galaxies. We collect 15665 redshifts (3471 new or remeasured) within \\sim 5-10 Mpc of the centers of the clusters, making it the largest study of the infall regions of clusters. We determine cluster membership and the mass profiles of the clusters based on the phase space distribution of the galaxies. All of the clusters display decreasing velocity dispersion profiles. The mass profiles are fit well by functional forms based on numerical simulations but exclude an isothermal sphere. Specifically, NFW and Hernquist models provide good descriptions of cluster mass profiles to their turnaround radii. Our sample shows that the predicted infall pattern is ubiquitous in rich, X-ray luminous clusters over a large mass range. The caustic mass estimates are in excellent agreement with independent X-ray estimates at small radii and with virial estimates at intermediate radii. The mean ratio of the caustic mass to the X-ray mass is 1.03\\pm0.11 and the mean ratio of the caustic mass to the virial mass (when corrected for the surface pressure term) is 0.93\\pm0.07. We further demonstrate that the caustic technique provides reasonable mass estimates even in merging clusters.

  12. Phase I Focused Corrective Measures Study/Feasibility Study for the L-Area Oil and Chemical Basin (904-83G)

    SciTech Connect (OSTI)

    Palmer, E. [Westinghouse Savannah River Company, AIKEN, SC (United States)

    1997-02-01T23:59:59.000Z

    This report presents the completed Resource Conservation and Recovery Act (RCRA) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Focused Corrective Measures Study/Feasibility Study (CMS/FS) for the L-Area Oil and Chemical Basin (LAOCB)/L-Area Acid Caustic Basin (9LAACB) Solid Waste Management Unit/Operable Unit (SWMU/OU) at the Savannah River Site (SRS).

  13. Process for tertiary oil recovery using tall oil pitch

    DOE Patents [OSTI]

    Radke, C.J.

    1983-07-25T23:59:59.000Z

    A process and compositions for enhancing the recovery of acid crudes are disclosed. The process involves injecting caustic solutions into the reservoir to maintain a pH of 11 to 13. The fluid contains an effective amount of multivalent cation for inhibiting alkaline silica dissolution with the reservoir. A tall oil pitch soap is added as a polymeric mobility control agent. (DMC)

  14. Safe Operating Procedure (Revised 6/10)

    E-Print Network [OSTI]

    Farritor, Shane

    welding or other forms of welding processes. · Repair or servicing of any vehicle. · Caustic or explosive -- Furnace operations, pouring, casting, hot dipping, and welding Hot sparks Faceshields, goggles, spectacles Environmental Health and Safety · (402) 472-4925 · http://ehs.unl.edu High temperature exposure Screen face

  15. CX-012578: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Actinide Removal and Extraction-Scrub-Strip (ESS) Testing for Modular Caustic-side Solvent Extraction (MCU) Support (SB8) CX(s) Applied: B3.6Date: 41850 Location(s): South CarolinaOffices(s): Savannah River Operations Office

  16. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan K.

    2002-01-02T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  17. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan Keith

    2002-01-01T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  18. A predictive model for particle size distribution and yield for Bayer precipitation and classification

    E-Print Network [OSTI]

    Kapraun, Christopher Michael

    1996-01-01T23:59:59.000Z

    SOg= NaC1 Org-C = Temp Liquor density Total caustic Dissolved alumina Total alkali Sodium sulfate Sodium chloride Organic carbon Temperature (gtL) (g/L) (gtL) (gti ) (gtL) (gtL) (gtl-) ('C) 22 In this same study, Langa also supplied...

  19. Washing of the AW-101 entrained solids

    SciTech Connect (OSTI)

    GJ Lumetta

    2000-03-31T23:59:59.000Z

    BNFL Inc. (BNFL) is under contract with the US Department of Energy, River Protection Project (DOE-RPP) to design, construct, and operate facilities for treating wastes stored in the single-shell and double-shell tanks at the Hanford Site, Richland, Washington. The DOE-BNFL RPP contract identifies two feeds to the waste treatment plant: (1) primarily liquid low-activity waste (LAW) consisting of less than 2 wt% entrained solids and (2) high-level waste (HLW) consisting of 10 to 200 g/L solids slurry. This report describes the results of a test conducted by Battelle to assess the effects of inhibited water washing on the composition of the entrained solids in the diluted AW-101 low-activity waste (LAW) sample. The objective of this work was to gather data on the solubility of the AW-101 entrained solids in 0.01 M NaOH, so that BNFL can evaluate whether these solids require caustic leaching. The work was conducted according to test plan BNFL-TP-29953-9, Rev. 0, LAW Entrained Solids Water Wash and Caustic Leach Testing. The test went according to plan, with no deviations from the test plan. Based on the results of the 0.01 M NaOH washing, a decision was made by BNFL to not proceed with the caustic leaching test. The composition of the washed solids was such that caustic leaching would not result in significant reduction in the immobilized HLW volume.

  20. Perturbative analysis in planetary gravitational lensing

    E-Print Network [OSTI]

    V. Bozza

    1999-04-22T23:59:59.000Z

    The traditional perturbative method is applied to the case of gravitational lensing of planetary systems. A complete and detailed description of the structure of caustics for a system with an arbitrary number of planets can be obtained. I have also found precise analytical expressions for microlensing light curves perturbed by the presence of planets.

  1. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Robert Dilmore, Peng Lu, Douglas Allen, Yee Soong,*, Sheila Hedges, Jaw K. Fu,4

    E-Print Network [OSTI]

    Zhu, Chen

    sources (such as fossil fuel-fired power plants) and the long-term storage of CO2 in underground, brine-b utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester

  2. Harvard Department of Chemistry and Chemical Biology

    E-Print Network [OSTI]

    Heller, Eric

    Guide Glove Material Applications Butyl A synthetic rubber material that offers the highest permeation resistance to gas and water vapors. Esp. suited for use with esters and ketones. Neoprene A synthetic rubber and caustics. Moderate abrasion resistance. Nitrile A synthetic rubber material that offers chemical

  3. * Corresponding author: Tel: +33 2 23 23 81 57 / Fax: + 33 2 23 23 81 20 Email address : pierre-francois.biard@ensc-rennes.fr

    E-Print Network [OSTI]

    Boyer, Edmond

    at semi-industrial scale17 in a compact wet scrubber has been investigated. The gas residence time in the scrubber was18 reduced to 30 ms using a NaOCl caustic scrubbing solution. The contactor is composed of a19: Absorption, chemical scrubbing, compact scrubber, hydrogen sulphide,37 odour control.38 39 hal-00904248

  4. Savannah River Site Salt Processing Project: FY2002 Research and Development Program Plan

    SciTech Connect (OSTI)

    Harmon, Harry D.; Leugemors, Robert K.; Schlahta, Stephan N.; Fink, Samuel D.; Thompson, Major C.; Walker, Darrell D.

    2001-10-31T23:59:59.000Z

    This Plan describes the technology development program for alpha/strontium removal and Caustic Side Solvent Extraction cesium removal in FY2002. Crystalline Silicotitanate and Small Tank Tetratphenylborate Precipitation are discussed as possible backup technologies. Previous results are summarized in the Savannah River Site Salt Processing Project Research and Development Summary Report

  5. Explosive growth of inhomogeneities in the distribution of droplets in a turbulent air

    E-Print Network [OSTI]

    S. A. Derevyanko; G. Falkovich; K. Turitsyn; S. Turitsyn

    2006-04-23T23:59:59.000Z

    We study how the spatial distribution of inertial particles evolves with time in a random flow. We describe an explosive appearance of caustics and show how they influence an exponential growth of clusters due to smooth parts of the flow, leading in particular to an exponential growth of the average distance between particles.

  6. Time Capsule

    E-Print Network [OSTI]

    Barta, Timothy

    2012-04-01T23:59:59.000Z

    or even contagious, even contagious through a television or computer screen. And there's a hostile, caustic recoil Some insist a "man" can't be raped Or that "women" don't abuse Or that a "woman" who acts "girly" is wrong 258 for not being...

  7. Material characterization of the clay bonded silicon carbide candle filters and ash formations in the W-APF system after 500 hours of hot gas filtration at AEP. Appendix to Advanced Particle Filter: Technical progress report No. 11, January--March 1993

    SciTech Connect (OSTI)

    Alvin, M.A.

    1993-04-05T23:59:59.000Z

    (1) After 500 hours of operation in the pressurized fluidized-bed combustion gas environment, the fibrous outer membrane along the clay bonded silicon carbide Schumacher Dia Schumalith candles remained intact. The fibrous outer membrane did not permit penetration of fines through the filter wall. (2) An approximate 10-15% loss of material strength occurred within the intact candle clay bonded silicon carbide matrix after 500 hours of exposure to the PFBC gas environment. A relatively uniform strength change resulted within the intact candles throughout the vessel (i.e., top to bottom plenums), as well as within the various cluster ring positions (i.e., outer versus inner ring candle filters). A somewhat higher loss of material strength, i.e., 25% was detected in fractured candle segments removed from the W-APF ash hopper. (3) Sulfur which is present in the pressurized fluidized-bed combustion gas system induced phase changes along the surface of the binder which coats the silicon carbide grains in the Schumacher Dia Schumalith candle filter matrix.

  8. The effect of sodium chloride on the dissolution of calcium silicate hydrate gels

    SciTech Connect (OSTI)

    Hill, J. [UK Nirex Limited, Curie Avenue, Harwell, Didcot Oxfordshire, OX11 0RH (United Kingdom)]. E-mail: joanne.hill@nirex.co.uk; Harris, A.W. [UK Nirex Limited, Curie Avenue, Harwell, Didcot Oxfordshire, OX11 0RH (United Kingdom); Manning, M. [Formerly AEA Technology, Building 220, Harwell, Didcot Oxfordshire, OX11 0RA (United Kingdom); Chambers, A. [Serco Assurance, Building 150, Harwell International Business Centre, Didcot, Oxfordshire, OX11 0RA (United Kingdom); Swanton, S.W. [Serco Assurance, Building 150, Harwell International Business Centre, Didcot, Oxfordshire, OX11 0RA (United Kingdom)

    2006-07-01T23:59:59.000Z

    The use of cement based materials will be widespread in the long-term management of radioactive materials in the United Kingdom. One of the applications could be the Nirex reference vault backfill (NRVB) as an engineered barrier within a deep geological repository. NRVB confers alkaline conditions, which would provide a robust chemical barrier through the control of the solubility of some key radionuclides, enhanced sorption and minimised corrosion of steel containers. An understanding of the dissolution of C-S-H gels in cement under the appropriate conditions (e.g., saline groundwaters) is necessary to demonstrate the expected evolution of the chemistry over time and to provide sufficient cement to buffer the porewater conditions for the required time. A programme of experimental work has been undertaken to investigate C-S-H gel dissolution behaviour in sodium chloride solutions and the effect of calcium/silicon ratio (C/S), temperature and cation type on this behaviour. Reductions in calcium concentration and pH values were observed with samples equilibrated at 45 deg. C compared to those prepared at 25 deg. C. The effect of salt cation type on salt-concentration dependence of the dissolution of C-S-H gels was investigated by the addition of lithium or potassium chloride in place of sodium chloride for gels with a C/S of 1.0 and 1.8. With a C/S of 1.0, similar increases in dissolved calcium concentration with increasing ionic strength were recorded for the different salts. However, at a C/S of 1.8, anomalously high calcium concentrations were observed in the presence of lithium.

  9. Improved evidence for the existence of an intermediate phase during hydration of tricalcium silicate

    SciTech Connect (OSTI)

    Bellmann, Frank, E-mail: frank.bellmann@uni-weimar.d [Institute for Building Materials Science, Bauhaus University Weimar, 99423 Weimar (Germany); Damidot, Denis [Ecole des Mines de Douai, Civil and Environmental Engineering Department, 941 rue Charles Bourseul, BP 10838, 59508 Doua cedexi (France); Moeser, Bernd [Institute for Building Materials Science, Bauhaus University Weimar, 99423 Weimar (Germany); Skibsted, Jorgen [Instrument Center for Solid-State NMR Spectroscopy and Interdisciplinary Nanoscience Center (iNANO), Department of Chemistry, Aarhus University DK-8000 Aarhus C (Denmark)

    2010-06-15T23:59:59.000Z

    Tricalcium silicate (Ca{sub 3}SiO{sub 5}) with a very small particle size of approximately 50 nm has been prepared and hydrated for a very short time (5 min) by two different modes in a paste experiment, using a water/solid-ratio of 1.20, and by hydration as a suspension employing a water/solid-ratio of 4000. A phase containing uncondensed silicate monomers close to hydrogen atoms (either hydroxyl groups or water molecules) was formed in both experiments. This phase is distinct from anhydrous tricalcium silicate and from the calcium-silicate-hydrate (C-S-H) phase, commonly identified as the hydration product of tricalcium silicate. In the paste experiment, approximately 79% of silicon atoms were present in the hydrated phase containing silicate monomers as determined from {sup 29}Sileft brace{sup 1}Hright brace CP/MAS NMR. This result is used to show that the hydrated silicate monomers are part of a separate phase and that they cannot be attributed to a hydroxylated surface of tricalcium silicate after contact with water. The phase containing hydrated silicate monomers is metastable with respect to the C-S-H phase since it transforms into the latter in a half saturated calcium hydroxide solution. These data is used to emphasize that the hydration of tricalcium silicate proceeds in two consecutive steps. In the first reaction, an intermediate phase containing hydrated silicate monomers is formed which is subsequently transformed into C-S-H as the final hydration product in the second step. The introduction of an intermediate phase in calculations of the early hydration of tricalcium silicate can explain the presence of the induction period. It is shown that heterogeneous nucleation on appropriate crystal surfaces is able to reduce the length of the induction period and thus to accelerate the reaction of tricalcium silicate with water.

  10. Course 28123 Chemical/Biochemical Engineering Laboratory

    E-Print Network [OSTI]

    Simaan, Nabil

    and solid extraction, organic synthesis, fixed bed enzyme reactor, solids handling, combustion/ high, filtration, drying in a tunnel, spray drying, fluidization and fluidized bed drying, distillation, absorption

  11. fe0014066-battelle | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treatment technologies such as chemical treatment, filtration, reverse osmosis, distillation, etc., must be adapted to treat a range of flowback water chemistries and have...

  12. Microsoft PowerPoint - 3 - Marcinowski Waste Presentation.pptx

    Energy Savers [EERE]

    a principal requirement for safe underground operations, as it supports worker safety, mining and waste emplacement. * Current Status * Ventilation in Filtration Mode * 60,000...

  13. Enterprise Assessments Targeted Review, Lawrence Livermore National...

    Broader source: Energy.gov (indexed) [DOE]

    February 2015 Targeted Review of the Safety-Class Room Ventilation Systems and Associated Final Filtration Stages, and Review of Federal Assurance Capability at the Lawrence...

  14. Robust Waste-to-Value Solution Using Advanced Monitoring and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    water to desired purity for reuse, moving through filtration, an aerobic membrane bioreactor (MBR), and reverse osmosis (RO). Predictive monitoring and supervisory controls are...

  15. Mr. John E. Kieling, Bureau Chief Hazardous Waste Bureau

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that time underground exhaust air has continued to be routed through HEPA filtration. The radiological release contaminated portions of the underground facility. In addition, the...

  16. Carlsbad Field Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HEPA filtration. On April 11, 2014, in anticipation of investigation of the source of a radiological release from the facility, the Permittees implemented the Resource...

  17. Universit d'Ottawa Facult de gnie

    E-Print Network [OSTI]

    Petriu, Emil M.

    , microelectronics, bioethanol fuel, biodiesel fuel, thermodynamics and mechanical separations (filtration * Production of bioethanol from agricultural waste as an additive to gasoline * Removal of CO2 from flue gases

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    clean fuel vehicles; The cost of retrofitting diesel vehicles with U.S. Environmental Protection Agency verified closed crankcase filtration devices, diesel oxidation...

  19. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    north of S-1950 drift, is complete. b. Ventilation * Air Flow-The underground ventilation system is operating in filtration mode using one 860 fan that supplies a...

  20. U.S. DEPARTMENT OF ENERGY EERE PROJECT MANAG EMENT CENTER NEPA...

    Broader source: Energy.gov (indexed) [DOE]

    valves, in-core monitoring devices, facility air filtration systems, or substation transformers or capacitors; addition of structural bracing to meet earthquake standards andor...

  1. U.S. DEPARTMENT OF ENERGY EERE PROJECT MANAG EMENT CEN T ER

    Broader source: Energy.gov (indexed) [DOE]

    valves, in-core monitoring devices, facility air filtration systems, or substation transformers or capacitors; addition of structural bracing to meet earthquake standards andor...

  2. RL-721 REV? I. Project Title: NEPA REVIEW SCREENING FORM Document...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    valves, in-core monitoring devices, facility air filtration systems, or substation transformers or capacitors; addition of structural bracing to meet earthquake standards andor...

  3. RL-721 REV4 I. Project Title: NEPA REVIEW SCREENING FORM Document...

    Broader source: Energy.gov (indexed) [DOE]

    valves, in-core monitoring devices, facility air filtration systems, or substation transformers or capacitors; addition of structural bracing to meet earthquake standards andor...

  4. RI-:ClPIl<:NT:King County U.S. DEPARTlIIENT OF ENERGY EERE PROJECT...

    Broader source: Energy.gov (indexed) [DOE]

    valves, in-core monitoring devices, facility air filtration systems, Of" substation transformers or capacitors; addition of structural bracing to meet earthquake standards andOf"...

  5. u.s. DEPARTlIlENT OF ENERGY EERE PROJECT M ANAGE MENT CEN T

    Broader source: Energy.gov (indexed) [DOE]

    valves, in-core monitoring devices. facility air filtration systems, or substation transformers or capacitors; addition of structural bracing to meet earthquake standards andor...

  6. Call for Papers 2008/2009 Special Issue for the IEEE Technology and Society Magazine entitled

    E-Print Network [OSTI]

    Drinking water filtration, waste treatment (low cost, effective yet without adverse environmental impact) o Electricity generation, wind and solar power, solar cooker, lighting (renewable energy sources, low

  7. Identification and Localization of the CupB Protein Involved...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fraction containing two protein complexes of about 450 and 550 kDa, obtained after nickel column and gel filtration chromatography of the membranes solubilized with...

  8. Building America Technology Solutions for New and Existing Homes...

    Broader source: Energy.gov (indexed) [DOE]

    the garage-to-house air leakage. Air Leakage and Air Transfer Between Garage and Living Space More Documents & Publications DOE ZERH Webinar: Ventilation and Filtration Strategies...

  9. Recovery of Iron/Iron Oxide Nanoparticles from Solution: Comparison...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simple washing of the nanoparticles during vacuum filtration (i.e., “flash drying”) can leave up to 17 weight percent residual moisture. Modeling calculations...

  10. Department of Energy's Energy Savings Performance Contracts Stretch...

    Broader source: Energy.gov (indexed) [DOE]

    unoccupied periods. Pool pump control. An adjustable speed drive was installed with a flow meter to control the pool filtration system and reduce flow during unoccupied...

  11. Control of size and charge selectivity in amphiphilic graft copolymer nanofiltration membranes

    E-Print Network [OSTI]

    Lovell, Nathan Gary

    2010-01-01T23:59:59.000Z

    The throughput and efficiency of membrane separations make polymer filtration membranes an important resource for the pharmaceutical, food and wastewater treatment industries. Nanofiltration (NF) membranes fill an important ...

  12. Determination and distribution of left ventricular size as measured by noncontrast CT in the Multi-Ethnic Study of Atherosclerosis.

    E-Print Network [OSTI]

    2015-01-01T23:59:59.000Z

    of Cardiovascular Computed Tomography. Bild DE, Bluemke DA,filtration rate and computed tomography based leftof 4 th quartile of computed tomography derived left

  13. Information Relaxations, Duality, and Convex Stochastic Dynamic ...

    E-Print Network [OSTI]

    2014-07-14T23:59:59.000Z

    heuristics for managing natural gas storage assets; see also Nadarajah, Margot, and ... at the beginning of period t; we will refer to F as the natural filtration.

  14. Supertruck technologies for 55% thermal efficiency and 68% freight...

    Broader source: Energy.gov (indexed) [DOE]

    On Program Partners Cummins Inc. - Cummins Fuel Systems - Cummins Electronics - Cummins Turbo Technologies - Cummins Emissions Solutions - Cummins Filtration - Modine - VanDyne...

  15. The role of calcium hydroxide in the formation of thaumasite

    SciTech Connect (OSTI)

    Bellmann, F. [Institute for Building Materials Science, Department of Civil Engineering, Bauhaus-University Weimar (Germany)], E-mail: frank.bellmann@bauing.uni-weimar.de; Stark, J. [Institute for Building Materials Science, Department of Civil Engineering, Bauhaus-University Weimar (Germany)

    2008-10-15T23:59:59.000Z

    It has recently been derived by thermodynamic calculation that the presence or absence of calcium hydroxide plays a vital role in the resistance of cement paste or concrete against the formation of thaumasite. To obtain experimental data on this matter, special binders have been mixed and used for the preparation of mortar bars. These specimens were exposed to moderate sulphate attack for a period of 18 months at a temperature of 8 deg. C. Mortar bars containing calcium hydroxide showed visual signs of attack a few months after exposure, leading to expansion, mass loss and complete failure. In contrast to this, no signs of attack were observed when no calcium hydroxide was present in the microstructure. These results confirm the conclusions of earlier thermodynamic calculations that the presence of calcium hydroxide has an important impact on the formation of thaumasite. Calcium-rich C-S-H formed in the presence of calcium hydroxide is vulnerable against sulphate attack and the formation of thaumasite. In the absence of calcium hydroxide, C-S-H has a much lower calcium/silicon ratio and a higher resistance against the formation of thaumasite.

  16. The di- and tricalcium silicate dissolutions

    SciTech Connect (OSTI)

    Nicoleau, L., E-mail: luc.nicoleau@basf.com [BASF Research Construction Materials and Systems, BASF Construction Chemicals GmbH, 83308 Trostberg (Germany); Nonat, A.; Perrey, D. [Institut Carnot de Bourgogne UMR5209 CNRS, 9 avenue Alain Savary, BP 47870, 21078 Dijon Cedex (France)] [Institut Carnot de Bourgogne UMR5209 CNRS, 9 avenue Alain Savary, BP 47870, 21078 Dijon Cedex (France)

    2013-05-15T23:59:59.000Z

    In this study, a specially designed reactor connected to an ICP spectrometer enabled the careful determination of the dissolution rates of C{sub 3}S, C{sub 2}S and CaO, respectively, over a broad range of concentration of calcium and silicates under conditions devoid of C–S–H. The kinetic laws, bridging the dissolution rates and the undersaturations, were obtained after extrapolation of rate zero allowing the estimation of the true experimental solubility products of C{sub 3}S (K{sub sp} = 9.6 · 10{sup ?23}), C{sub 2}S (K{sub sp} = 4.3 · 10{sup ?18}) and CaO (K{sub sp} = 9.17 · 10{sup ?6}). The latter are then compared to the solubilities calculated from the enthalpies of formation. We propose that the observed deviations result from the protonation of the unsaturated oxygen atoms present at the surface of these minerals. Hydration rates measured in cement pastes or in C{sub 3}S pastes are in excellent agreement with the kinetic law found in this study for C{sub 3}S under conditions undersaturated with respect to C–S–H.

  17. On the nature of structural disorder in calcium silicate hydrates with a calcium/silicon ratio similar to tobermorite

    SciTech Connect (OSTI)

    Grangeon, Sylvain, E-mail: S.Grangeon@brgm.fr [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France)] [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Claret, Francis; Lerouge, Catherine [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France)] [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Warmont, Fabienne [CRMD, UMR 6619 – CNRS, 1b rue de la férollerie, 45071 Orléans Cedex 2 (France)] [CRMD, UMR 6619 – CNRS, 1b rue de la férollerie, 45071 Orléans Cedex 2 (France); Sato, Tsutomu; Anraku, Sohtaro [Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste, Resources and Geoenvironmental/Engineering Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo 060-8628 (Japan)] [Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste, Resources and Geoenvironmental/Engineering Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo 060-8628 (Japan); Numako, Chiya [Faculty of Integrated Arts and Sciences, The University of Tokushima, 1-1, Minami-Josanjima, Tokushima, 770-8502 (Japan)] [Faculty of Integrated Arts and Sciences, The University of Tokushima, 1-1, Minami-Josanjima, Tokushima, 770-8502 (Japan); Linard, Yannick [ANDRA, Centre de Meuse/Haute Marne, 55290 Bure (France)] [ANDRA, Centre de Meuse/Haute Marne, 55290 Bure (France); Lanson, Bruno [ISTerre, Grenoble University, CNRS, F-38041 Grenoble (France)] [ISTerre, Grenoble University, CNRS, F-38041 Grenoble (France)

    2013-10-15T23:59:59.000Z

    Four calcium silicate hydrates (C-S-H) with structural calcium/silicon (Ca/Si) ratios ranging from 0.82 ± 0.02 to 0.87 ± 0.02 were synthesized at room temperature, 50, 80, and 110 °C. Their structure was elucidated by collating information from electron probe micro-analysis, transmission electron microscopy, extended X-ray absorption fine structure spectroscopy, and powder X-ray diffraction (XRD). A modeling approach specific to defective minerals was used because sample turbostratism prevented analysis using usual XRD refinement techniques (e.g. Rietveld analysis). It is shown that C-S-H with Ca/Si ratio of ? 0.8 are structurally similar to nano-crystalline turbostratic tobermorite, a naturally occurring mineral. Their structure thus consists of sheets of calcium atoms in 7-fold coordination, covered by ribbons of silicon tetrahedra with a dreierketten (wollastonite-like) organization. In these silicate ribbons, 0.42 Si per bridging tetrahedron are missing. Random stacking faults occur systematically between successive layers (turbostratic stacking). Layer-to-layer distance is equal to 11.34 Å. Crystallites have a mean size of 10 nm in the a–b plane, and a mean number of 2.6–2.9 layers stacked coherently along the c* axis.

  18. Effect of blast furnace slag on self-healing of microcracks in cementitious materials

    SciTech Connect (OSTI)

    Huang, Haoliang, E-mail: haoliang.huang@tudelft.nl [Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology (Netherlands); Ye, Guang [Microlab, Faculty of Civil Engineering and Geosciences, Delft University of Technology (Netherlands); Magnel Laboratory for Concrete Research, Department of Structural Engineering, Ghent University (Belgium); Damidot, Denis [Université Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France)

    2014-06-01T23:59:59.000Z

    The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH){sub 2} solution as activator, it was found that the reaction products formed in cracks are composed of C-S-H, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of C-S-H in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO{sub 4}{sup 2?} ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50 h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high. - Highlights: • Self-healing reaction products in slag cement paste were characterized. • Self-healing reaction products formed in time were quantified with image analysis. • Self-healing in slag cement paste was simulated with a reactive transport model. • Effect of carbonation on self-healing was investigated by thermodynamic modeling. • Effect of slag on self-healing was discussed based on experiments and simulation.

  19. UNITED STATES DEPAR.TMENT OF THE INTERIOR FISH AND WILDLIFE SERVICE

    E-Print Network [OSTI]

    to a clear oil. At this stage the #12;oil is ready for market as crude marine oil. Marine oils have been by filtration, and the filtrate is marketed as light cold- pressed marine oil. Thus, light cold FISHERIES WASHINGTON, D.C. FISHERY LEAFLET 528 #12;MARINE OILS - ') NEW AVENUES FOR VENTURE Marine oils

  20. Presented at the Engineering Foundation and the American Society of Civil Engineers Conference on Information & Monitoring Needs for Evaluating the

    E-Print Network [OSTI]

    Pitt, Robert E.

    of experiments conducted to determine if four potential filter media (sand, activated carbon, peat moss's exhaustion of the chemical capacity. Upflow filtration using a siphon control may improve the life of the filters. However, for upflow filtration with siphon control for entering water, it would be expected