National Library of Energy BETA

Sample records for file transfer electronic

  1. Electron Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansas Nuclear ProfileMultiferroicAward |ElectronFluctuations3 Pierre

  2. GNU Radio & USRPGNU Radio & USRP File transfer through WirelessFile transfer through Wireless

    E-Print Network [OSTI]

    Yu, Chansu

    1 GNU Radio & USRPGNU Radio & USRP File transfer through WirelessFile transfer through WirelessSachin Hirve April 30, 2008April 30, 2008 Contents:Contents: What is Software Radio?What is Software Radio? USRPUSRP ­­ MultiMulti--functional hardwarefunctional hardware GNU RadioGNU Radio Previous Work

  3. Drinking Water and Groundwater Protection Division File Transfer...

    Open Energy Info (EERE)

    Drinking Water and Groundwater Protection Division File Transfer Protocol (FTP) Site Instructions Jump to: navigation, search OpenEI Reference LibraryAdd to library Permitting...

  4. Engineering nanocarbon interfaces for electron transfer

    E-Print Network [OSTI]

    Hilmer, Andrew J. (Andrew Joseph)

    2013-01-01

    Electron-transfer reactions at nanometer-scale interfaces, such as those presented by single-walled carbon nanotubes (SWCNTs), are important for emerging optoelectronic and photovoltaic technologies. Electron transfer also ...

  5. Photo-induced electron transfer method

    DOE Patents [OSTI]

    Wohlgemuth, Roland (2823 Hillegass Ave., Berkeley, CA 94705); Calvin, Melvin (2683 Buena Vista Way, Berkeley, CA 94708)

    1984-01-01

    The efficiency of photo-induced electron transfer reactions is increased and the back transfer of electrons in such reactions is greatly reduced when a photo-sensitizer zinc porphyrin-surfactant and an electron donor manganese porphyrin-surfactant are admixed into phospho-lipid membranes. The phospholipids comprising said membranes are selected from phospholipids whose head portions are negatively charged. Said membranes are contacted with an aqueous medium in which an essentially neutral viologen electron acceptor is admixed. Catalysts capable of transfering electrons from reduced viologen electron acceptor to hydrogen to produce elemental hydrogen are also included in the aqueous medium. An oxidizable olefin is also admixed in the phospholipid for the purpose of combining with oxygen that coordinates with oxidized electron donor manganese porphyrin-surfactant.

  6. Electron Transfer Dynamics in Photocatalytic CO2 Conversion ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Transfer Dynamics in Photocatalytic CO2 Conversion Electron Transfer Dynamics in Photocatalytic CO2 Conversion Coal is the workhorse of our power industry, responsible for...

  7. Electron Attachment Step in Electron Capture Dissociation (ECD) and Electron Transfer Dissociation (ETD)

    E-Print Network [OSTI]

    Simons, Jack

    (ETD) Iwona Anusiewicz, Joanna Berdys-Kochanska, and Jack Simons* Chemistry Department and Henry Eyring (in electron capture dissociation (ECD)) or transferred (in electron transfer dissociation (ETD used a Landau-Zener-Stueckelberg curve-crossing approximation to estimate the ETD rates for electron

  8. Reaction coordinates for electron transfer reactions

    SciTech Connect (OSTI)

    Rasaiah, Jayendran C.; Zhu Jianjun

    2008-12-07

    The polarization fluctuation and energy gap formulations of the reaction coordinate for outer sphere electron transfer are linearly related to the constant energy constraint Lagrangian multiplier m in Marcus' theory of electron transfer. The quadratic dependence of the free energies of the reactant and product intermediates on m and m+1, respectively, leads to similar dependence of the free energies on the reaction coordinates and to the same dependence of the activation energy on the reorganization energy and the standard reaction free energy. Within the approximations of a continuum model of the solvent and linear response of the longitudinal polarization to the electric field in Marcus' theory, both formulations of the reaction coordinate are expected to lead to the same results.

  9. Custody transfer enhanced by electronic billing system

    SciTech Connect (OSTI)

    Knox, R.M.

    1986-10-20

    Transcontinental Gas Pipe Line (TGPL) Corp. engineers have developed an electronic billing system for custody transfer that can reduce the cost of doing business and improve the accuracy of transfer measurements. The system accurately measures gas flow and quality, transmits gas data to a central facility, provides a capability to review the collected data, prepares bills based upon these data, and reduces staffing associated with the data collection and billing process. On-line flow computers are keys to this electronic billing system. These computers, referred to as remote terminal units (RTU's), are currently in service at TGPL at more than 30 locations with 30 more locations due to be on-line within 6 months and an additional 40 locations due within 15 months. These RTU's will be obtaining gas data from metering stations located in New York, New Jersey, Pennsylvania, Maryland, Virginia, North Carolina, Georgia, Louisiana, and Texas.

  10. Quantum tunneling resonant electron transfer process in Lorentzian plasmas

    SciTech Connect (OSTI)

    Hong, Woo-Pyo; Jung, Young-Dae

    2014-08-15

    The quantum tunneling resonant electron transfer process between a positive ion and a neutral atom collision is investigated in nonthermal generalized Lorentzian plasmas. The result shows that the nonthermal effect enhances the resonant electron transfer cross section in Lorentzian plasmas. It is found that the nonthermal effect on the classical resonant electron transfer cross section is more significant than that on the quantum tunneling resonant charge transfer cross section. It is shown that the nonthermal effect on the resonant electron transfer cross section decreases with an increase of the Debye length. In addition, the nonthermal effect on the quantum tunneling resonant electron transfer cross section decreases with increasing collision energy. The variation of nonthermal and plasma shielding effects on the quantum tunneling resonant electron transfer process is also discussed.

  11. Metal ion modulated electron transfer in photosynthetic proteins.

    SciTech Connect (OSTI)

    Utschig, L. M.; Thurnauer, M. C.; Chemistry

    2004-07-01

    Photosynthetic purple bacterial reaction center (RC) proteins are ideal native systems for addressing basic questions regarding the nature of biological electron transfer because both the protein structure and the electron-transfer reactions are well-characterized. Metal ion binding to the RC can affect primary photochemistry and provides a probe for understanding the involvement of local protein environments in electron transfer. The RC has two distinct transition metal ion binding sites, the well-known non-heme Fe{sup 2+} site buried in the protein interior and a recently discovered Zn{sup 2+} site located on the surface of the protein. Fe{sup 2+} removal and Zn{sup 2+} binding systematically affect different electron-transfer steps in the RC. Factors involved in the metal ion alteration of RC electron transfer may provide a paradigm for other biological systems involved in electron transfer.

  12. Analytical Model for Rates of Electron Attachment and Intramolecular Electron Transfer in Electron Transfer

    E-Print Network [OSTI]

    Simons, Jack

    . As a result, in ECD the primary source of excess energy is the recombination energy released when the electron) where free low-energy electrons rather than anion collision partners are used to effect the initial) experiments, one subjects a mass-to-charge-selected parent ion to very low-energy electrons (often boiled off

  13. Electron transfer and protein engineering studies of the soluble methane monooxygenase from Methylococcus capsulatus (Bath)

    E-Print Network [OSTI]

    Blazyk, Jessica L. (Jessica Lee), 1974-

    2003-01-01

    Chapter 1. Introduction: Electron Transfer in Biological Systems In many biological processes, including oxidative phosphorylation and photosynthesis, electron transfer reactions play vital roles. Electrons must be transported ...

  14. File Transfer Protocol (FTP) Site Instructions | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbHFarinello GeothermalFideris IncFile FTP Document Upload Website

  15. Global electronic funds transfer between small and medium sized companies

    E-Print Network [OSTI]

    Stovall, Shawn Eric

    2006-01-01

    Cross-border electronic funds transfer is a rapidly expanding field for business and consumer payments. Large multi-national corporations have been able to invest the capital necessary to create infrastructures or work ...

  16. Solvent structure and hydrodynamic effects in photoinduced electron transfer

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent structure and hydrodynamic effects in photoinduced electron transfer S. F. Swallen, Kristin to account for realistic finite-volume solvent effects. This work introduces physically important effects caused by the solvent which fundamentally affect the rates and spatial distribution of charge transfer

  17. Kinetic Monte Carlo Simulation of Electron Transfer

    E-Print Network [OSTI]

    Southern California, University of

    hold up to one electron: occ(i) = 1 (occupied) or 0 (unoccupied) Reduction: If molecule i;Algorithm occ[i] 0 (i = 0 to N-1) nred 0 // number of injected electrons nox 0 // number of ejected(rand()/RAND_MAX)/r rth r*rand()/RAND_MAX racc 0 for i 0 to N-1 if (rth reduction

  18. Microsoft PowerPoint - File Transfer-Turner

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on darkMicroorganisms toPalladium wavyfamilyOuachitaEnergyTransfer

  19. This is a review text file submitted electronically to MR. Reviewer: Thomas Schick

    E-Print Network [OSTI]

    Schick, Thomas

    This is a review text file submitted electronically to MR. Reviewer: Thomas Schick Reviewer"ottingen Germany schick@uni-math.gwdg.de Author: Loya, P. and Park, J. Short title: Boundary problems

  20. This is a review text file submitted electronically to MR. Reviewer: Thomas Schick

    E-Print Network [OSTI]

    Schick, Thomas

    This is a review text file submitted electronically to MR. Reviewer: Thomas Schick Reviewer"ottingen Germany schick@uni-math.gwdg.de Author: Loya, P., McDonald, P., Park, J. Short title: Zeta

  1. Modification of quinone electrochemistry by the proteins in the biological electron transfer chains: examples

    E-Print Network [OSTI]

    Gunner, Marilyn

    Modification of quinone electrochemistry by the proteins in the biological electron transfer chains . Electrochemistry Quinones are the primary intramembrane, mobile, electron carriers in the energy-coupling electron

  2. Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansas Nuclear ProfileMultiferroicAwardElectronElectronic &on

  3. CORRELATING ELECTRONIC AND VIBRATIONAL MOTIONS IN CHARGE TRANSFER SYSTEMS

    SciTech Connect (OSTI)

    Khalil, Munira

    2014-06-27

    The goal of this research program was to measure coupled electronic and nuclear motions during photoinduced charge transfer processes in transition metal complexes by developing and using novel femtosecond spectroscopies. The scientific highlights and the resulting scientific publications from the DOE supported work are outlined in the technical report.

  4. Mechanistic studies of photo-induced proton-coupled electron transfer and oxygen atom transfer reactions in model systems

    E-Print Network [OSTI]

    Hodgkiss, Justin M. (Justin Mark), 1978-

    2007-01-01

    Time-resolved optical spectroscopy has been employed for mechanistic studies in model systems designed to undergo photo-induced proton-coupled electron transfer (PCET) and oxygen atom transfer (OAT) reactions, both of which ...

  5. Spectroscopic investigation of photo-induced proton-coupled electron transfer and Dexter energy transfer in model systems

    E-Print Network [OSTI]

    Young, Elizabeth R. (Elizabeth Renee), 1980-

    2009-01-01

    Spectroscopic investigations of systems designed to advance the mechanistic interrogation of photo-induced proton coupled electron transfer (PCET) and proton-coupled (through-bond) energy transfer (PCEnT) are presented. ...

  6. Electronic energy transfer: vibrational control and nonlinear wavepacket interferometry

    E-Print Network [OSTI]

    Dmitri S. Kilin; Jeffrey A. Cina; Oleg V. Prezhdo

    2004-12-31

    The time-development of photoexcitations in molecular aggregates exhibits specific dynamics of electronic states and vibrational wavefunction. We discuss the dynamical formation of entanglement between electronic and vibrational degrees of freedom in molecular aggregates with theory of electronic energy transfer and the method of vibronic 2D wavepackets [Cina, Kilin, Humble, J. Chem. Phys. 118, 46 (2003)]. The vibronic dynamics is also described by applying Jaynes-Cummings model to the electronic energy transfer [Kilin, Pereverzev, Prezhdo, J. Chem. Phys. 120, 11209 (2004);math-ph/0403023]. Following the ultrafast excitation of donor[chem-ph/9411004] the population of acceptor rises by small portions per each vibrational period, oscillates force and back between donor and acceptor with later damping and partial revivals of this oscillation. The transfer rate gets larger as donor wavepacket approaches the acceptor equilibrium configuration, which is possible at specific energy differences of donor and acceptor and at maximal amount of the vibrational motion along the line that links donor and acceptor equilibria positions. The four-pulse phase-locked nonlinear wavepacket 2D interferograms reflect the shape of the relevant 2D vibronic wavepackets and have maxima at longer delay between excitation pulses for dimers with equal donor-acceptor energy difference compare to dimers with activationless energy configuration [Cina, Fleming, J. Phys. Chem. A. 108, 11196 (2004)].

  7. DNA Damage Induced by Low-Energy Electrons: Electron Transfer and Diffraction

    SciTech Connect (OSTI)

    Zheng Yi; Wagner, J. Richard; Sanche, Leon [Groupe de Recherche en Sciences des Radiations, Faculte de Medecine, Universite de Sherbrooke, Sherbrooke, QC J1H 5N4 (Canada)

    2006-05-26

    Thin films of the short single strand of DNA, GCAT, in which guanine (G) or adenine (A) have been removed, were bombarded under vacuum by 4 to 15 eV electrons. The fragments corresponding to base release and strand breaks (SB) were analyzed by high performance liquid chromatography and their yields compared with those obtained from unmodified GCAT. From such a comparison, it is shown that, using GCAT as a model system (1) most SB result from electron capture by DNA bases followed by electron transfer to the phosphate group and (2) the initial capture probability depends on the coherence of the electron wave within the tetramer.

  8. Photoinduced electron transfer in perylene-TiO2 nanoassemblies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/OPerformance andAreaPhotoinduced electron transfer in

  9. The influence of diffusion on photoinduced electron transfer and geminate recombination

    E-Print Network [OSTI]

    Fayer, Michael D.

    in some electron transfer reactions).' Many bio- chemical charge-transfer reactions take place in fluid media whose properties govern life processes.' Before current can flow in a fuel cell, the fuel has to diffuse to an electrode for electron transfer to occur and the spent fuel must diffuse away

  10. Proton-coupled electron transfer reactions in solution: Molecular dynamics with quantum transitions for model systems

    E-Print Network [OSTI]

    Hammes-Schiffer, Sharon

    Proton-coupled electron transfer reactions in solution: Molecular dynamics with quantum transitions A general minimal model for proton-coupled electron transfer PCET reactions in solution is presented. This model consists of three coupled degrees of freedom that represent an electron, a proton, and a solvent

  11. Exploring the Energy Landscape for QA to QB Electron Transfer in Bacterial

    E-Print Network [OSTI]

    Gunner, Marilyn

    ) is rate-limited by conformational changes rather than electron tunneling. QB movement from a distal trapped in a different conformation. Now electron transfer from QA - to QB occurs even below 40 KExploring the Energy Landscape for QA - to QB Electron Transfer in Bacterial Photosynthetic

  12. Bridge mediated two-electron transfer reactions: On the influence of intersite Coulomb interactions

    E-Print Network [OSTI]

    Rder, Beate

    Bridge mediated two-electron transfer reactions: On the influence of intersite Coulomb interactions 17 June 2004 Donor-acceptor two-electron transfer TET mediated by a linear molecular bridge of a strong electronic intersite coupling within the bridge and against the background of fast vibrational

  13. Time-optimal polarization transfer from an electron spin to a nuclear spin

    E-Print Network [OSTI]

    Haidong Yuan; Robert Zeier; Nikolas Pomplun; Steffen J. Glaser; Navin Khaneja

    2015-09-07

    Polarization transfers from an electron spin to a nuclear spin are essential for various physical tasks, such as dynamic nuclear polarization in nuclear magnetic resonance and quantum state transformations on hybrid electron-nuclear spin systems. We present time-optimal schemes for electron-nuclear polarization transfers which improve on conventional approaches and will have wide applications.

  14. The Role of Excited Rydberg States in Electron Transfer Dissociation Monika Sobczyk and Jack Simons*

    E-Print Network [OSTI]

    Simons, Jack

    and Background In electron capture dissociation1 (ECD) or electron transfer dissociation2 (ETD) mass spectroscopy oxygen or a disulfide sulfur atom to eventually generate N-CR or S-S bond cleavage, as illustrated-lying antibonding orbitals, we considered in refs 3 and 4 the possibility of electron transfer (or capture) directly

  15. Aqueous systems from first-principles : structure, dynamics and electron-transfer reactions

    E-Print Network [OSTI]

    Sit, Patrick Hoi Land

    2006-01-01

    In this thesis, we show for the first time how it is possible to calculated fully from first-principles the diabatic free-energy surfaces of electron-transfer reactions. The excitation energy corresponding to the transfer ...

  16. A stochastic reorganizational bath model for electronic energy transfer

    SciTech Connect (OSTI)

    Fujita, Takatoshi E-mail: aspuru@chemistry.harvard.edu; Huh, Joonsuk; Aspuru-Guzik, Aln E-mail: aspuru@chemistry.harvard.edu

    2014-06-28

    Environmentally induced fluctuations of the optical gap play a crucial role in electronic energy transfer dynamics. One of the simplest approaches to incorporate such fluctuations in energy transfer dynamics is the well known Haken-Strobl-Reineker (HSR) model, in which the energy-gap fluctuation is approximated as white noise. Recently, several groups have employed molecular dynamics simulations and excited-state calculations in conjunction to account for excitation energies thermal fluctuations. On the other hand, since the original work of HSR, many groups have employed stochastic models to simulate the same transfer dynamics. Here, we discuss a rigorous connection between the stochastic and the atomistic bath models. If the phonon bath is treated classically, time evolution of the exciton-phonon system can be described by Ehrenfest dynamics. To establish the relationship between the stochastic and atomistic bath models, we employ a projection operator technique to derive the generalized Langevin equations for the energy-gap fluctuations. The stochastic bath model can be obtained as an approximation of the atomistic Ehrenfest equations via the generalized Langevin approach. Based on this connection, we propose a novel scheme to take account of reorganization effects within the framework of stochastic models. The proposed scheme provides a better description of the population dynamics especially in the regime of strong exciton-phonon coupling. Finally, we discuss the effect of the bath reorganization in the absorption and fluorescence spectra of ideal J-aggregates in terms of the Stokes shifts. We find a simple expression that relates the reorganization contribution to the Stokes shifts the reorganization shift to the ideal or non-ideal exciton delocalization in a J-aggregate. The reorganization shift can be described by three parameters: the monomer reorganization energy, the relaxation time of the optical gap, and the exciton delocalization length. This simple relationship allows one to understand the physical origin of the Stokes shifts in molecular aggregates.

  17. Photoinitiated proton-coupled electron transfer and radical transport kinetics in class la ribonucleotide reductase

    E-Print Network [OSTI]

    Pizano, Arturo A. (Arturo Alejandro)

    2013-01-01

    Proton-coupled electron transfer (PCET) is a critical mechanism in biology, underpinning key processes such as radical transport, energy transduction, and enzymatic substrate activation. Ribonucleotide reductases (RNRs) ...

  18. Thermal transfer structures coupling electronics card(s) to coolant-cooled structure(s)

    DOE Patents [OSTI]

    David, Milnes P; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Parida, Pritish R; Schmidt, Roger R

    2014-12-16

    Cooling apparatuses and coolant-cooled electronic systems are provided which include thermal transfer structures configured to engage with a spring force one or more electronics cards with docking of the electronics card(s) within a respective socket(s) of the electronic system. A thermal transfer structure of the cooling apparatus includes a thermal spreader having a first thermal conduction surface, and a thermally conductive spring assembly coupled to the conduction surface of the thermal spreader and positioned and configured to reside between and physically couple a first surface of an electronics card to the first surface of the thermal spreader with docking of the electronics card within a socket of the electronic system. The thermal transfer structure is, in one embodiment, metallurgically bonded to a coolant-cooled structure and facilitates transfer of heat from the electronics card to coolant flowing through the coolant-cooled structure.

  19. Structural Fluctuations, Spin, Reorganization Energy, and Tunneling Energy Control of Intramolecular Electron Transfer

    E-Print Network [OSTI]

    Kurnikova, Maria

    calculations of electronic couplings, molecular dynamics simulations of molecular geometries, and Poisson exists to interpret electron-transfer (ET) reactions and their dependence upon molecular structure.1Structural Fluctuations, Spin, Reorganization Energy, and Tunneling Energy Control

  20. Pattern transfer of electron beam modified self-assembled monolayers for high-resolution lithography

    E-Print Network [OSTI]

    Parikh, Atul N.

    Pattern transfer of electron beam modified self-assembled monolayers for high-resolution electron beam lithography. Focused electron beams from 1 to 50 keV and scanning tunneling microscopy at 10 of electron beam damage on the monolayers and the subsequent etching reactions has been explored through x

  1. Chemical Bonding: The Classical Description sharing or transferring electrons between atoms

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Chemical Bonding: The Classical Description sharing or transferring electrons between atoms LEWIS electron dot diagram -> formula (SF6) VSEPR (valence-shell electron-pair repulsion) theory Molecular Structure (w/o quantum mechanics) Chapter. 3 Two or more atoms approach -> their electrons interact and form

  2. Bridge mediated two-electron transfer reactions: Analysis of stepwise and concerted pathways

    E-Print Network [OSTI]

    Rder, Beate

    Bridge mediated two-electron transfer reactions: Analysis of stepwise and concerted pathways E. G-electron transfer TET mediated by a single regular bridge (B) is developed. The presence of different intermediate-exponential kinetics becomes possible. For the latter case the rate KTET is calculated, which describes the bridge

  3. Dynamical Arrest of Electron Transfer in Liquid Crystalline Solvents Vitaliy Kapko and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Dynamical Arrest of Electron Transfer in Liquid Crystalline Solvents Vitaliy Kapko and Dmitry V Form: May 3, 2006 We argue that electron transfer reactions in slowly relaxing solvents proceed in the nonergodic regime, making the reaction activation barrier strongly dependent on the solvent dynamics

  4. Reorganization energy of intermolecular electron transfer in solvents near isotropicnematic transition

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Reorganization energy of intermolecular electron transfer in solvents near isotropic of orientational isotropic/ nematic phase transition. These data are used to calculate the solvent reorganization.1063/1.1580107 I. INTRODUCTION The effect of a condensed-phase solvent on the kinetics of electron transfer ET

  5. Electron Transfer Catalyzed [2 + 2] Cycloreversion of Benzene G. Devi Reddy and Olaf Wiest*

    E-Print Network [OSTI]

    Hudlicky, Tomas

    Electron Transfer Catalyzed [2 + 2] Cycloreversion of Benzene Dimers G. Devi Reddy and Olaf Wiest, Florida 32611-7200 Received December 8, 1998 The catalysis of the [2 + 2] cycloreversion of the anti-o,o-benzene dimer 1 and the syn-o,o- naphthalene-benzene dimer 2 through thermal and photoinduced electron transfer

  6. Exploring Electron Transfer in Organic Semiconductors | MIT-Harvard...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    more than one electronic state. These processes are at the heart of several technological applications, including organic LEDs, artificial photosynthesis and molecular electronics...

  7. COST TRANSFER INSTRUCTIONS If you are using the electronic version of the Cost Transfer form, you must ensure that each form has a new CTXXXXXXXX number. When you

    E-Print Network [OSTI]

    Tipple, Brett

    COST TRANSFER INSTRUCTIONS If you are using the electronic version of the Cost Transfer form, you and send it in with the same number. A Cost Transfer is an adjustment made sometime after an event has occurred which transfers costs from University projects or activities where the charges had been originally

  8. Model Proton-Coupled Electron Transfer Reactions in Solution: Predictions of Rates, Mechanisms, and Kinetic Isotope Effects

    E-Print Network [OSTI]

    Hammes-Schiffer, Sharon

    Model Proton-Coupled Electron Transfer Reactions in Solution: Predictions of Rates, Mechanisms isotope effects for proton-coupled electron transfer (PCET) reactions. These studies are based, the solvent is represented as a dielectric continuum, and the active electrons and transferring protons

  9. Gene expression and deletion analysis of mechanisms for electron transfer from electrodes to Geobacter sulfurreducens

    E-Print Network [OSTI]

    Lovley, Derek

    transfer to electrodes. Keywords: microbial fuel cell, Geobacter sulfurreducens, cathode, electron donor. Surprisingly, genes for putative cell-electrode connections, such as outer-surface cytochromes and pili, which emerging area in microbe-electrode interactio

  10. Photochemical ribonucleotide reductase for the study of proton-coupled electron transfer

    E-Print Network [OSTI]

    Reece, Steven Y., 1980-

    2007-01-01

    Charge transport and catalysis in enzymes often rely on amino acid radicals as intermediates. The generation and transport of these radicals are synonymous with proton-coupled electron transfer (PCET), which intrinsically ...

  11. Nonadiabatic electron transfer in the condensed phase, via semiclassical and Langevin equation approach

    E-Print Network [OSTI]

    Song, XiaoGeng, Ph. D. Massachusetts Institute of Technology

    2009-01-01

    In this dissertation, we discuss two methods developed during my PhD study to simulate electron transfer systems. The first method, the semi-classical approximation, is derived from the stationary phase approximation to ...

  12. Proton-coupled electron transfer : from basic principles to small molecule activation

    E-Print Network [OSTI]

    Rosenthal, Joel, 1979-

    2007-01-01

    Proton-coupled electron transfer (PCET) is the basic mechanism for bioenergetic conversion. Hallmark examples of such reactivities include water oxidation which is coupled to photosynthesis and oxygen reduction which is ...

  13. Hot Electron Transfer from Semiconductor Nanocrystals | MIT-Harvard...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have been touted as promising materials for photovoltaics because discretization of their electronic energy levels can slow down this cooling process, which might enable the...

  14. Building model systems to understand Proton-Coupled Electron Transfer in heme : spectroscopic investigation of charge transfer to axially bound diimide acceptors

    E-Print Network [OSTI]

    Hanson, Christina J

    2013-01-01

    Proton-Coupled Electron Transfer (PCET) is an important mechanistic motif in chemistry, which allows for efficient charge transport in many biological systems. We seek to understand how the proton and electron motions are ...

  15. Transferred metal electrode films for large-area electronic devices...

    Office of Scientific and Technical Information (OSTI)

    metal electrode films for large-area electronic devices The evaporation of metal-film gate electrodes for top-gate organic field-effect transistors (OFETs) limits the...

  16. Current Theoretical Challenges in Proton-Coupled Electron Transfer: Electron Proton Nonadiabaticity, Proton Relays, and Ultrafast Dynamics

    SciTech Connect (OSTI)

    Hammes-Schiffer, Sharon

    2011-06-16

    Proton-coupled electron transfer (PCET) reactions play an important role in a wide range of biological and chemical processes. The motions of the electrons, transferring protons, solute nuclei, and solvent nuclei occur on a wide range of time scales and are often strongly coupled. As a result, the theoretical description of these processes requires a combination of quantum and classical methods. This Perspective discusses three of the current theoretical challenges in the field of PCET. The first challenge is the calculation of electron proton nonadiabatic effects, which are significant for these reactions because the hydrogen tunneling is often faster than the electronic transition. The second challenge is the modeling of electron transfer coupled to proton transport along hydrogen-bonded networks. The third challenge is the simulation of the ultrafast dynamics of nonequilibrium photoinduced PCET reactions in solution. Insights provided by theoretical studies may assist in the design of more effective catalysts for energy conversion processes. The proton relay portion of this review is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  17. Powering microbes with electricity: direct electron transfer from electrodes to microbes

    SciTech Connect (OSTI)

    Lovley, DR

    2010-09-16

    P>The discovery of electrotrophs, microorganisms that can directly accept electrons from electrodes for the reduction of terminal electron acceptors, has spurred the investigation of a wide range of potential applications. To date, only a handful of pure cultures have been shown to be capable of electrotrophy, but this process has also been inferred in many studies with undefined consortia. Potential electron acceptors include: carbon dioxide, nitrate, metals, chlorinated compounds, organic acids, protons and oxygen. Direct electron transfer from electrodes to cells has many advantages over indirect electrical stimulation of microbial metabolism via electron shuttles or hydrogen production. Supplying electrons with electrodes for the bioremediation of chlorinated compounds, nitrate or toxic metals may be preferable to adding organic electron donors or hydrogen to the subsurface or bioreactors. The most transformative application of electrotrophy may be microbial electrosynthesis in which carbon dioxide and water are converted to multi-carbon organic compounds that are released extracellularly. Coupling photovoltaic technology with microbial electrosynthesis represents a novel photosynthesis strategy that avoids many of the drawbacks of biomass-based strategies for the production of transportation fuels and other organic chemicals. The mechanisms for direct electron transfer from electrodes to microorganisms warrant further investigation in order to optimize envisioned applications.

  18. Solvent reorganization energy of electron-transfer reactions in polar solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Solvent reorganization energy of electron-transfer reactions in polar solvents Dmitry V. Matyushova theory of solvent reorganization energy in polar molecular solvents is developed. The theory represents the solvent response as a combination of the density and polarization fluctuations of the solvent given

  19. Solvent Reorganization Entropy of Electron Transfer in Polar Solvents Pradip K. Ghorai and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Solvent Reorganization Entropy of Electron Transfer in Polar Solvents Pradip K. Ghorai and Dmitry V Form: February 2, 2006 We report the results of molecular dynamics simulations of the solvent of a positive reorganization entropy in polar solvents. The results of simulations are analyzed in terms

  20. Solvent relaxation effects on the kinetics of photoinduced electron transfer reactions

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent relaxation effects on the kinetics of photoinduced electron transfer reactions J. Najbar formation and recombination of radical- ion pairs limited by solvent dielectric relaxation. The problem). Solvent relaxation moves the system to lower energy on the radical-ion pair surface where crossing

  1. Modeling the free energy surfaces of electron transfer in condensed phases

    E-Print Network [OSTI]

    Matyushov, Dmitry

    PROOF COPY 509037JCP Modeling the free energy surfaces of electron transfer in condensed phases analytical solution for the ET free energy surfaces demonstrates the following features: i the range of ET reaction coordinates is limited by a one-sided fluctuation band, ii the ET free energies are infinite

  2. Distance Dependence of Electron Transfer in DNA: The Role of the Reorganization Energy and Free Energy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Distance Dependence of Electron Transfer in DNA: The Role of the Reorganization Energy and Free of the solvent reorganization energy and free energy in the heterogeneous DNA environment. DNA is modeled represents water. Model calculations show the importance of including the reorganization energy and the free

  3. Constraint-Based Modeling of Carbon Fixation and the Energetics of Electron Transfer in Geobacter metallireducens

    SciTech Connect (OSTI)

    Feist, AM; Nagarajan, H; Rotaru, AE; Tremblay, PL; Zhang, T; Nevin, KP; Lovley, DR; Zengler, K

    2014-04-24

    Geobacter species are of great interest for environmental and biotechnology applications as they can carry out direct electron transfer to insoluble metals or other microorganisms and have the ability to assimilate inorganic carbon. Here, we report on the capability and key enabling metabolic machinery of Geobacter metallireducens GS-15 to carry out CO2 fixation and direct electron transfer to iron. An updated metabolic reconstruction was generated, growth screens on targeted conditions of interest were performed, and constraint-based analysis was utilized to characterize and evaluate critical pathways and reactions in G. metallireducens. The novel capability of G. metallireducens to grow autotrophically with formate and Fe(III) was predicted and subsequently validated in vivo. Additionally, the energetic cost of transferring electrons to an external electron acceptor was determined through analysis of growth experiments carried out using three different electron acceptors (Fe(III), nitrate, and fumarate) by systematically isolating and examining different parts of the electron transport chain. The updated reconstruction will serve as a knowledgebase for understanding and engineering Geobacter and similar species. Author Summary The ability of microorganisms to exchange electrons directly with their environment has large implications for our knowledge of industrial and environmental processes. For decades, it has been known that microbes can use electrodes as electron acceptors in microbial fuel cell settings. Geobacter metallireducens has been one of the model organisms for characterizing microbe-electrode interactions as well as environmental processes such as bioremediation. Here, we significantly expand the knowledge of metabolism and energetics of this model organism by employing constraint-based metabolic modeling. Through this analysis, we build the metabolic pathways necessary for carbon fixation, a desirable property for industrial chemical production. We further discover a novel growth condition which enables the characterization of autotrophic (i.e., carbon-fixing) metabolism in Geobacter. Importantly, our systems-level modeling approach helped elucidate the key metabolic pathways and the energetic cost associated with extracellular electron transfer. This model can be applied to characterize and engineer the metabolism and electron transfer capabilities of Geobacter for biotechnological applications.

  4. Laser-Energy Transfer and Enhancement of Plasma Waves and Electron Beams by Interfering High-Intensity Laser Pulses

    E-Print Network [OSTI]

    Umstadter, Donald

    Laser-Energy Transfer and Enhancement of Plasma Waves and Electron Beams by Interfering High%) and a decreased electron-beam divergence angle (by 45%), as compared with single-pulse illumination. Simulations reveal that increased stochastic heating of electrons may have also contributed to the electron-beam

  5. Bridge-Mediated Two-Electron Transfer via Delocalized Bridge Orbitals E. G. Petrov, Ya. R. Zelinskyy, and V. May*,

    E-Print Network [OSTI]

    Rder, Beate

    Bridge-Mediated Two-Electron Transfer via Delocalized Bridge Orbitals E. G. Petrov, Ya. R, 2004 Bridge mediated two-electron transfer (TET) in a donor-acceptor (D-A) complex is studied theoretically. A type of bridge is considered where the intersite coupling in the bridge becomes so large

  6. Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

    SciTech Connect (OSTI)

    Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M.

    2010-12-08

    Many, if not most, redox reactions are coupled to proton transfers. This includes most common sources of chemical potential energy, from the bioenergetic processes that power cells to the fossil fuel combustion that powers cars. These proton-coupled electron transfer or PCET processes may involve multiple electrons and multiple protons, as in the 4 e, 4 H+ reduction of dioxygen (O2) to water (eq 1), or can involve one electron and one proton such as the formation of tyrosyl radicals from tyrosine residues (TyrOH) in enzymatic catalytic cycles (eq 2). In addition, many multi-electron, multi-proton processes proceed in one-electron and one-proton steps. Organic reactions that proceed in one-electron steps involve radical intermediates, which play critical roles in a wide range of chemical, biological, and industrial processes. This broad and diverse class of PCET reactions are central to a great many chemical and biochemical processes, from biological catalysis and energy transduction, to bulk industrial chemical processes, to new approaches to solar energy conversion. PCET is therefore of broad and increasing interest, as illustrated by this issue and a number of other recent reviews.

  7. Ultrafast Photo-Induced Charge Transfer Unveiled by Two-Dimensional Electronic Spectroscopy

    E-Print Network [OSTI]

    Bixner, Oliver; Mancal, Tomas; Hauer, Juergen; Milota, Franz; Fischer, Michael; Pugliesi, Igor; Bradler, Maximilian; Schmid, Walther; Riedle, Eberhard; Kauffmann, Harald F; Christensson, Niklas

    2012-01-01

    The interaction of exciton and charge transfer (CT) states plays a central role in photo-induced CT processes in chemistry, biology and physics. In this work, we use a combination of two-dimensional electronic spectroscopy (2D-ES), pump-probe measurements and quantum chemistry to investigate the ultrafast CT dynamics in a lutetium bisphthalocyanine dimer in different oxidation states. It is found that in the anionic form, the combination of strong CT-exciton interaction and electronic asymmetry induced by a counter-ion enables CT between the two macrocycles of the complex on a 30 fs timescale. Following optical excitation, a chain of electron and hole transfer steps gives rise to characteristic cross-peak dynamics in the electronic 2D spectra, and we monitor how the excited state charge density ultimately localizes on the macrocycle closest to the counter-ion within 100 fs. A comparison with the dynamics in the radical species further elucidates how CT states modulate the electronic structure and tune fs-reac...

  8. Manipulation of the distance of light-induced electron transfer within a semi-rigid donor(amine)/acceptor(terpyridine) assembly via

    E-Print Network [OSTI]

    structure calculations qualitatively reproduce the experimental observations. From the calculations interest in the kinetics and dynamics of electron transfer (ET) reac- tions, including reactions kinetics and dynamics studies: `how far is the electron transferred?' At first glance, this would appear

  9. Simulating Electron Transfer Attachment to a Positively Charged Model Peptide Iwona Anusiewicz, Joanna Berdys-Kochanska, Piotr Skurski,, and Jack Simons*,

    E-Print Network [OSTI]

    Simons, Jack

    's findings. I. Introduction In electron capture dissociation1 (ECD) or electron-transfer dissociation2 (ETD subsequently transfer an H atom to either the carbonyl oxygen or a sulfur atom to produce the radical species

  10. Quantum DotBridgeFullerene Heterodimers with Controlled Photoinduced Electron Transfer

    SciTech Connect (OSTI)

    Cotlet, M.; Xu, Z.

    2011-06-27

    A series of donor-bridge-acceptor systems in the form of core/shell CdSe/ZnS quantum dot-bridge-fullerene heterodimers (see picture) with varying bridge length and varying quantum dot size were self-assembled by a surface-based stepwise method to demonstrate control of the rate and of the magnitude of fluctuations of photoinduced electron transfer at the single-molecule level.

  11. Metal complex-based electron-transfer mediators in dye-sensitized solar cells

    DOE Patents [OSTI]

    Elliott, C. Michael (Fort Collins, CO); Sapp, Shawn A. (Broomfield, CO); Bignozzi, Carlo Alberto (Ferrara, IT); Contado, Cristiano (Legnago, IT); Caramori, Stefano (Viconovo, IT)

    2006-03-28

    This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.

  12. Electrostatic models of electron-driven proton transfer across a lipid membrane

    E-Print Network [OSTI]

    Anatoly Yu. Smirnov; Lev G. Mourokh; Franco Nori

    2010-11-29

    We present two models for electron-driven uphill proton transport across lipid membranes, with the electron energy converted to the proton gradient via the electrostatic interaction. In the first model, associated with the cytochrome c oxidase complex in the inner mitochondria membranes, the electrostatic coupling to the site occupied by an electron lowers the energy level of the proton-binding site, making the proton transfer possible. In the second model, roughly describing the redox loop in a nitrate respiration of E. coli bacteria, an electron displaces a proton from the negative side of the membrane to a shuttle, which subsequently diffuses across the membrane and unloads the proton to its positive side. We show that both models can be described by the same approach, which can be significantly simplified if the system is separated into several clusters, with strong Coulomb interaction inside each cluster and weak transfer couplings between them. We derive and solve the equations of motion for the electron and proton creation/annihilation operators, taking into account the appropriate Coulomb terms, tunnel couplings, and the interaction with the environment. For the second model, these equations of motion are solved jointly with a Langevin-type equation for the shuttle position. We obtain expressions for the electron and proton currents and determine their dependence on the electron and proton voltage build-ups, on-site charging energies, reorganization energies, temperature, and other system parameters. We show that the quantum yield in our models can be up to 100% and the power-conversion efficiency can reach 35%.

  13. Interfacial electron transfer dynamics of ru(II)-polypy6ridine sensitized TiO2

    SciTech Connect (OSTI)

    Jakubikova, Elena [Los Alamos National Laboratory; Martin, Richard L [Los Alamos National Laboratory; Batista, Enrique R [Los Alamos National Laboratory; Snoeberger, Robert C [YALE UNIV.; Batista, Victor S [YALE UNIV.

    2009-01-01

    Quantum dynamics simulations combined with density functional theory calculations are applied to study interfacial electron transfer (IET) from pyridine-4-phosphonic acid, [Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 2+} and [Ru(tpy)(bpy)(H{sub 2}O)-Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 4+} into the (101) surface of anatase TiO{sub 2}. IET rate from pyridine-4-phosphonic acid attached to the nanoparticle in bidentate mode ({tau} {approx} 100 fs) is an order of magnitude faster than the IET rate of the adsorbate attached in the monodentate mode ({tau} {approx} 1 ps). Upon excitation with visible light, [Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 2+} attached to TiO{sub 2} in bidentate binding mode will undergo IET with the rate of {approx} 1-10 ps, which is competitive with the excited state decay into the ground state. The probability of electron injection from [Ru(tpy)(bpy)(H{sub 2}O)-Ru(tpy)(tpy(PO{sub 3}H{sub 2}))]{sup 4+} is rather low, as the excitation with visible light localizes the excited electron in the tpy-tpy bridge, which does not have favorable coupling with the TiO{sub 2} nanoparticle. The results are relevant to better understanding of the adsorbate features important for promoting efficient interfacial electron transfer into the semiconductor.

  14. Room Temperature, Hybrid Sodium-Based Flow Batteries with Multi-Electron Transfer Redox Reactions

    SciTech Connect (OSTI)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volume of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. The critical barriers to mature this new HNFBs have also been explored.

  15. Electronic and vibronic properties of a discotic liquid-crystal and its charge transfer complex

    SciTech Connect (OSTI)

    Haverkate, Lucas A.; Mulder, Fokko M.; Zbiri, Mohamed Johnson, Mark R.; Carter, Elizabeth; Kotlewski, Arek; Picken, S.

    2014-01-07

    Discotic liquid crystalline (DLC) charge transfer (CT) complexes combine visible light absorption and rapid charge transfer characteristics, being favorable properties for photovoltaic (PV) applications. We present a detailed study of the electronic and vibrational properties of the prototypic 1:1 mixture of discotic 2,3,6,7,10,11-hexakishexyloxytriphenylene (HAT6) and 2,4,7-trinitro-9-fluorenone (TNF). It is shown that intermolecular charge transfer occurs in the ground state of the complex: a charge delocalization of about 10{sup ?2} electron from the HAT6 core to TNF is deduced from both Raman and our previous NMR measurements [L. A. Haverkate, M. Zbiri, M. R. Johnson, B. Deme, H. J. M. de Groot, F. Lefeber, A. Kotlewski, S. J. Picken, F. M. Mulder, and G. J. Kearley, J. Phys. Chem. B 116, 13098 (2012)], implying the presence of permanent dipoles at the donor-acceptor interface. A combined analysis of density functional theory calculations, resonant Raman and UV-VIS absorption measurements indicate that fast relaxation occurs in the UV region due to intramolecular vibronic coupling of HAT6 quinoidal modes with lower lying electronic states. Relatively slower relaxation in the visible region the excited CT-band of the complex is also indicated, which likely involves motions of the TNF nitro groups. The fast quinoidal relaxation process in the hot UV band of HAT6 relates to pseudo-Jahn-Teller interactions in a single benzene unit, suggesting that the underlying vibronic coupling mechanism can be generic for polyaromatic hydrocarbons. Both the presence of ground state CT dipoles and relatively slow relaxation processes in the excited CT band can be relevant concerning the design of DLC based organic PV systems.

  16. Ultrafast electron transfer at organic semiconductor interfaces: Importance of molecular orientation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ayzner, Alexander L.; Nordlund, Dennis; Kim, Do -Hwan; Bao, Zhenan; Toney, Michael F.

    2014-12-04

    Much is known about the rate of photoexcited charge generation in at organic donor/acceptor (D/A) heterojunctions overaged over all relative arrangements. However, there has been very little experimental work investigating how the photoexcited electron transfer (ET) rate depends on the precise relative molecular orientation between D and A in thin solid films. This is the question that we address in this work. We find that the ET rate depends strongly on the relative molecular arrangement: The interface where the model donor compound copper phthalocyanine is oriented face-on with respect to the fullerene C60 acceptor yields a rate that is approximatelymore4 times faster than that of the edge-on oriented interface. Our results suggest that the D/A electronic coupling is significantly enhanced in the face-on case, which agrees well with theoretical predictions, underscoring the importance of controlling the relative interfacial molecular orientation.less

  17. Ultrafast electron transfer at organic semiconductor interfaces: Importance of molecular orientation

    SciTech Connect (OSTI)

    Ayzner, Alexander L.; Nordlund, Dennis; Kim, Do -Hwan; Bao, Zhenan; Toney, Michael F.

    2014-12-04

    Much is known about the rate of photoexcited charge generation in at organic donor/acceptor (D/A) heterojunctions overaged over all relative arrangements. However, there has been very little experimental work investigating how the photoexcited electron transfer (ET) rate depends on the precise relative molecular orientation between D and A in thin solid films. This is the question that we address in this work. We find that the ET rate depends strongly on the relative molecular arrangement: The interface where the model donor compound copper phthalocyanine is oriented face-on with respect to the fullerene C60 acceptor yields a rate that is approximately 4 times faster than that of the edge-on oriented interface. Our results suggest that the D/A electronic coupling is significantly enhanced in the face-on case, which agrees well with theoretical predictions, underscoring the importance of controlling the relative interfacial molecular orientation.

  18. Coupled electron-nuclear dynamics: Charge migration and charge transfer initiated near a conical intersection

    SciTech Connect (OSTI)

    Mendive-Tapia, David; Vacher, Morgane; Bearpark, Michael J.; Robb, Michael A.

    2013-07-28

    Coupled electron-nuclear dynamics, implemented using the Ehrenfest method, has been used to study charge migration with fixed nuclei, together with charge transfer when nuclei are allowed to move. Simulations were initiated at reference geometries of neutral benzene and 2-phenylethylamine (PEA), and at geometries close to potential energy surface crossings in the cations. Cationic eigenstates, and the so-called sudden approximation, involving removal of an electron from a correlated ground-state wavefunction for the neutral species, were used as initial conditions. Charge migration without coupled nuclear motion could be observed if the Ehrenfest simulation, using the sudden approximation, was started near a conical intersection where the states were both strongly coupled and quasi-degenerate. Further, the main features associated with charge migration were still recognizable when the nuclear motion was allowed to couple. In the benzene radical cation, starting from the reference neutral geometry with the sudden approximation, one could observe sub-femtosecond charge migration with a small amplitude, which results from weak interaction with higher electronic states. However, we were able to engineer large amplitude charge migration, with a period between 10 and 100 fs, corresponding to oscillation of the electronic structure between the quinoid and anti-quinoid cationic electronic configurations, by distorting the geometry along the derivative coupling vector from the D{sub 6h} Jahn-Teller crossing to lower symmetry where the states are not degenerate. When the nuclear motion becomes coupled, the period changes only slightly. In PEA, in an Ehrenfest trajectory starting from the D{sub 2} eigenstate and reference geometry, a partial charge transfer occurs after about 12 fs near the first crossing between D{sub 1}, D{sub 2} (N{sup +}-Phenyl, N-Phenyl{sup +}). If the Ehrenfest propagation is started near this point, using the sudden approximation without coupled nuclear motion, one observes an oscillation of the spin density charge migration between the N atom and the phenyl ring with a period of 4 fs. When the nuclear motion becomes coupled, this oscillation persists in a damped form, followed by an effective charge transfer after 30 fs.

  19. Fundamental studies of energy-and hole/electron- transfer in hydroporphyrin architectures

    SciTech Connect (OSTI)

    Bocian, David F.

    2014-08-20

    The long-term objective of the Bocian/Holten/Lindsey research program is to design, synthesize, and characterize tetrapyrrole-based molecular architectures that absorb sunlight, funnel energy, and separate charge with high efficiency and in a manner compatible with current and future solar-energy conversion schemes. The synthetic tetrapyrroles include porphyrins and hydroporphyrins; the latter classes of molecules encompass analogues of the naturally occurring chlorophylls and bacteriochlorophylls (e.g., chlorins, bacteriochlorins, and their derivatives). The attainment of the goals of the research program requires the close interplay of molecular design and synthesis (Lindsey group), static and time-resolved optical spectroscopic measurements (Holten group), and electrochemical, electron paramagnetic resonance, and resonance Raman studies, as well as density functional theory calculations (Bocian Group). The proposed research encompasses four interrelated themes: (1) Determination of the rates of ground-state hole/electron transfer between (hydro)porphyrins in multipigment arrays as a function of array size, distance between components, linker type, site of linker connection, and frontier molecular orbital composition. (2) Examination of excited-state energy transfer among hydroporphyrins in multipigment arrrays, including both pairwise and non-adjacent transfer, with a chief aim to identify the relative contributions of through-space (Frster) and through-bond (Dexter) mechanisms of energy transfer, including the roles of site of linker connection and frontier molecular orbital composition. (3) Elucidation of the role of substituents in tuning the spectral and electronic properties of bacteriochlorins, with a primary aim of learning how to shift the long-wavelength absorption band deeper into the near-infrared region. (4) Continued development of the software package PhotochemCAD for spectral manipulations and calculations through the compilation of a database of spectra for naturally occurring and synthetic hydroporphyrins. The availability of such data should augment efforts in the design of light-harvesting systems where spectral coverage in the red and near-infrared regions is desired. Collectively, the proposed studies will provide fundamental insights into molecular properties, interactions, and processes relevant to the design of molecular architectures for solar-energy conversion. The accomplishment of these goals is only possible through a highly synergistic program that encompasses molecular design, synthesis, and characterization.

  20. Impact of environmentally induced fluctuations on quantum mechanically mixed electronic and vibrational pigment states in photosynthetic energy transfer and 2D electronic spectra

    E-Print Network [OSTI]

    Fujihashi, Yuta; Ishizaki, Akihito

    2015-01-01

    Recently, nuclear vibrational contribution signatures in 2D electronic spectroscopy have attracted considerable interest, in particular as regards interpretation of the oscillatory transients observed in light-harvesting complexes. These transients have dephasing times that persist for much longer than theoretically predicted electronic coherence lifetime. As a plausible explanation for this long-lived spectral beating in 2D electronic spectra, quantum-mechanically mixed electronic and vibrational states (vibronic excitons) were proposed by Christensson et al. [J. Phys. Chem. B 116, 7449 (2012)] and have since been explored. In this work, we address a dimer which produces little beating of electronic origin in the absence of vibronic contributions, and examine the impact of protein-induced fluctuations upon electronic-vibrational quantum mixtures by calculating the electronic energy transfer dynamics and 2D electronic spectra in a numerically accurate manner. It is found that, at cryogenic temperatures, the e...

  1. 03.110 Electronic Funds Transfer (EFT) of Salary. 1. Purpose. To provide a service to University of North Texas System

    E-Print Network [OSTI]

    03.110 Electronic Funds Transfer (EFT) of Salary. 1. Purpose. To provide a service to University to participate must complete and sign an Authorization Agreement for Electronic Funds Transfer of Salary Form Controller to electronically deposit an employee's salary directly to their account and to initiate

  2. 2+/TiO2-Codoped Zeolites: Synthesis, Characterization, and the Role of TiO2 in Electron Transfer Photocatalysis

    E-Print Network [OSTI]

    Turro, Claudia

    Transfer Photocatalysis Stefan H. Bossmann,*, Claudia Turro, Claudia Schnabel, Megh Raj Pokhrel, Leon M, such an effective electron-transfer relay was missing in zeolite photocatalysis, and therefore, the possible

  3. Watching Electrons Transfer from Metals to Insulators using Two Photon Photoemission

    E-Print Network [OSTI]

    Johns, James E.

    2010-01-01

    principles calculations of hot-electron lifetimes in metals.Harris, Femtosecond studies of electron tunneling at metal-M. , Electronic structure and electron dynamics at Si(100).

  4. Ultrafast single-electron transfer in coupled quantum dots driven by a few-cycle chirped pulse

    SciTech Connect (OSTI)

    Yang, Wen-Xing, E-mail: wenxingyang2@126.com [Department of Physics, Southeast University, Nanjing 210096 (China); Institute of Photonics Technologies, National Tsing-Hua University, Hsinchu 300, Taiwan (China); Chen, Ai-Xi [Department of Applied Physics, School of Basic Science, East China Jiaotong University, Nanchang 330013 (China); Bai, Yanfeng [Department of Physics, Southeast University, Nanjing 210096 (China); Lee, Ray-Kuang [Institute of Photonics Technologies, National Tsing-Hua University, Hsinchu 300, Taiwan (China)

    2014-04-14

    We theoretically study the ultrafast transfer of a single electron between the ground states of a coupled double quantum dot (QD) structure driven by a nonlinear chirped few-cycle laser pulse. A time-dependent Schrdinger equation without the rotating wave approximation is solved numerically. We demonstrate numerically the possibility to have a complete transfer of a single electron by choosing appropriate values of chirped rate parameters and the intensity of the pulse. Even in the presence of the spontaneous emission and dephasing processes of the QD system, high-efficiency coherent transfer of a single electron can be obtained in a wide range of the pulse parameters. Our results illustrate the potential to utilize few-cycle pulses for the excitation in coupled quantum dot systems through the nonlinear chirp parameter control, as well as a guidance in the design of experimental implementation.

  5. Desulfurization of organic sulfur from lignite by an electron transfer process

    SciTech Connect (OSTI)

    Demirbas, A. [Selcuk University, Konya (Turkey). Dept. for Chemical Engineering

    2006-10-15

    This study is an attempt to desulfurize organic sulfur from lignite samples with ferrocyanide ion as the electron transferring agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the lignite samples has been investigated. The desulfurization process has been found to be continuous and gradually increases with increase of temperature from 298 to 368 K. The particle size has no significant impact on sulfur removal from the lignite samples. Particle size has no profound impact on the amount of sulfur removal. The desulfurization reaction has been found to be dependent on the concentration of potassium ferrocyanide. Gradual increase in the concentration of potassium ferrocyanide raised the magnitude of desulfurization, but at a higher concentration, the variation is not significant.

  6. Electronic-excitation energy transfer in heterogeneous dye solutions under laser excitation

    SciTech Connect (OSTI)

    Levshin, L.V.; Mukushev, B.T.; Saletskii, A.M.

    1995-10-01

    An experimental study has been made of electronic-excitation energy transfer (EEET) among dye molecules of different types for different exciting-fight wavelengths and temperatures. Upon selective laser excitation of the donor, the inhomogeneous broadening of molecular levels increases the probability of EEET from the donor to acceptor molecules. The efficiency of this process is directly proportional to the acceptor molecule concentration and is temperature dependent. The EEET is accompanied by the spectral migration of energy among donor molecules, which reduces the fluorescence quantum efficiency of the donor. Increasing the frequency of the exciting light decreases in the donor fluorescence quantum efficiency. An increase in the acceptor molecule concentration results in a decrease of the spectral migration of excitation in the donor molecule system. 5 refs., 5 figs.

  7. Charge Transfer Fluorescence and 34 nm Exciton Diffusion Length in Polymers with Electron Acceptor End Traps

    SciTech Connect (OSTI)

    Zaikowski, L.; Mauro, G.; Bird, M.; Karten, B.; Asaoka, S.; Wu, Q.; Cook, A. R.; Miller, J.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are as large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. The efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.

  8. Charge transfer fluorescence and 34 nm exciton diffusion length in polymers with electron acceptor end traps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zaikowski, Lori; Mauro, Gina; Bird, Matthew; Karten, Brianne; Asaoka, Sadayuki; Wu, Qin; Cook, Andrew R.; Miller, John R.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are asmorelarge as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. As a result, the efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.less

  9. Room Temperature, Hybrid Sodium-Based Flow Batteries with Multi-Electron Transfer Redox Reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volumemoreof the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. The critical barriers to mature this new HNFBs have also been explored.less

  10. Excitonic splitting and coherent electronic energy transfer in the gas-phase benzoic acid dimer

    SciTech Connect (OSTI)

    Ottiger, Philipp; Leutwyler, Samuel

    2012-11-28

    The benzoic acid dimer, (BZA){sub 2}, is a paradigmatic symmetric hydrogen bonded dimer with two strong antiparallel hydrogen bonds. The excitonic S{sub 1}/S{sub 2} state splitting and coherent electronic energy transfer within supersonically cooled (BZA){sub 2} and its {sup 13}C-, d{sub 1}-, d{sub 2}-, and {sup 13}C/d{sub 1}- isotopomers have been investigated by mass-resolved two-color resonant two-photon ionization spectroscopy. The (BZA){sub 2}-(h-h) and (BZA){sub 2}-(d-d) dimers are C{sub 2h} symmetric, hence only the S{sub 2} Leftwards-Arrow S{sub 0} transition can be observed, the S{sub 1} Leftwards-Arrow S{sub 0} transition being strictly electric-dipole forbidden. A single {sup 12}C/{sup 13}C or H/D isotopic substitution reduces the symmetry of the dimer to C{sub s}, so that the isotopic heterodimers (BZA){sub 2}-{sup 13}C, (BZA){sub 2}-(h-d), (BZA){sub 2}-(h{sup 13}C-d), and (BZA){sub 2}-(h-d{sup 13}C) show both S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} bands. The S{sub 1}/S{sub 2} exciton splitting inferred is {Delta}{sub exc}= 0.94 {+-} 0.1 cm{sup -1}. This is the smallest splitting observed so far for any H-bonded gas-phase dimer. Additional isotope-dependent contributions to the splittings, {Delta}{sub iso}, arise from the change of the zero-point vibrational energy upon electronic excitation and range from {Delta}{sub iso}= 3.3 cm{sup -1} upon {sup 12}C/{sup 13}C substitution to 14.8 cm{sup -1} for carboxy H/D substitution. The degree of excitonic localization/delocalization can be sensitively measured via the relative intensities of the S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} origin bands; near-complete localization is observed even for a single {sup 12}C/{sup 13}C substitution. The S{sub 1}/ S{sub 2} energy gap of (BZA){sub 2} is {Delta}{sub calc}{sup exc}=11 cm{sup -1} when calculated by the approximate second-order perturbation theory (CC2) method. Upon correction for vibronic quenching, this decreases to {Delta}{sub vibron}{sup exc}=2.1 cm{sup -1} [P. Ottiger et al., J. Chem. Phys. 136, 174308 (2012)], in good agreement with the observed {Delta}{sub exc}= 0.94 cm{sup -1}. The observed excitonic splittings can be converted to exciton hopping times {tau}{sub exc}. For the (BZA){sub 2}-(h-h) homodimer {tau}{sub exc}= 18 ps, which is nearly 40 times shorter than the double proton transfer time of (BZA){sub 2} in its excited state [Kalkman et al., ChemPhysChem 9, 1788 (2008)]. Thus, the electronic energy transfer is much faster than the proton-transfer in (BZA){sub 2}{sup *}.

  11. Redox linked flavin sites in extracellular decaheme proteins involved in microbe-mineral electron transfer.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Edwards, Marcus J.; White, Gaye F.; Norman, Michael; Tome-Fernandez, Alice; Ainsworth, Emma; Shi, Liang; Fredrickson, Jim K.; Zachara, John M.; Butt, Julea N.; Richardson, David J.; et al

    2015-07-01

    Extracellular microbe-mineral electron transfer is a major driving force for the oxidation of organic carbon in many subsurface environments. Extracellular multi-heme cytochromes of the Shewenella genus play a major role in this process but the mechanism of electron exchange at the interface between cytochrome and acceptor is widely debated. The 1.8 x-ray crystal structure of the decaheme MtrC revealed a highly conserved CX?C disulfide that, when substituted for AX?A, severely compromised the ability of S. oneidensis to grow under aerobic conditions. Reductive cleavage of the disulfide in the presence of flavin mononucleotide (FMN) resulted in the reversible formation ofmorea stable flavocytochrome. Similar results were also observed with other decaheme cytochromes, OmcA, MtrF and UndA. The data suggest that these decaheme cytochromes can transition between highly reactive flavocytochromes or less reactive cytochromes, and that this transition is controlled by a redox active disulfide that responds to the presence of oxygen.less

  12. chsm.Rev. 1992. 92.463-480 463 Dynamical Solvent Effects on Activated Electron-Transfer Reactions

    E-Print Network [OSTI]

    Turro, Nicholas J.

    influencesexerted by the solvating environment upon the kinetics of electron- transfer (ET)proteases, either solvent influences upon AG' attributed to the reactionfree energy, AGO, whereas the former describesthe only mildly by the "slow" nuclear solvent modes. In addition to such energetic factors, however, one

  13. A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents Peter Vath and Matthew B. Zimmt* Department of Chemistry, Brown ReceiVed: February 9, 1999; In Final Form: April 26, 1999 The temperature dependence of the solvent

  14. Reorganization Energy of Electron Transfer in Viscous Solvents above the Glass Transition Pradip K. Ghorai and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Reorganization Energy of Electron Transfer in Viscous Solvents above the Glass Transition Pradip KVed: September 15, 2005; In Final Form: NoVember 6, 2005 We present a molecular-dynamics study of the solvent arrest of the slow, collective relaxation of the solvent related to Debye relaxation of the solvent

  15. Solvent Reorganization Energy and Free Energy Change for Donor/Acceptor Electron Transfer at Micelle Surfaces: Theory and Experiment

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent Reorganization Energy and Free Energy Change for Donor/Acceptor Electron TransferVed: April 7, 1998 Theories are presented for calculating the solvent reorganization energy and the free and acceptor. The form of this dependence has been of considerable interest for many years.2-6 Solvents

  16. Electron-Transfer from H-2 and Ar to Stored Multiply Charged Argon Ions Produced by Synchrotron Radiation

    E-Print Network [OSTI]

    Kravis, S. D.; Church, David A.; Johnson, B. M.; Meron, M.; Jones, K. W.; Levin, J. C.; Sellin, I. A.; Azuma, Y.; Berrahmansour, N.; Berry, H. G.; Druetta, M.

    1992-01-01

    The rate coefficients for electron transfer from Ar and H-2 to Ar(q+) ions (3 less-than-or-equal-to q less-than-or-equal-to 6) have been measured using an ion-storage technique in a Penning ion trap. The ions were produced in the trap by K...

  17. Resolving the Electron Transfer Kinetics in the Bacterial Reaction Center by Pulse Polarized 2-D Photon Echo Spectroscopy

    E-Print Network [OSTI]

    Mukamel, Shaul

    of photosynthesis is excitation energy transfer toward and charge separation within highly conserved reaction modeling of the nonlinear optical response of the bacterial RC B. viridis incorporating electron and energy of artificial photochemical devices. While the RCs of higher plants operate at high band gaps (680-700 nm

  18. Modeling the Effects of Mutations on the Free Energy of the First Electron Transfer to QB in Photosynthetic Reaction Centers

    E-Print Network [OSTI]

    Gunner, Marilyn

    Modeling the Effects of Mutations on the Free Energy of the First Electron Transfer from QA - to QB, 1999; ReVised Manuscript ReceiVed February 14, 2000 ABSTRACT: Numerical calculations of the free energy changes in nearby residues. This reduces the effect of mutation and makes the changes in state free energy

  19. Proton-coupled electron transfer at the Qo-site of the bc1 complex controls the rate of ubihydroquinone oxidation.

    E-Print Network [OSTI]

    Crofts, Antony R.

    1 Proton-coupled electron transfer at the Qo-site of the bc1 complex controls the rate transfer; proton transfer; bc1 complex; Qo-site; Marcus theory; ES-complex Abbreviations: bc1 complex of the transmembrane proton gradient is positive or negative, respectively; PDB#, Protein Data Bank identifier; Q

  20. Visualizing the non-equilibrium dynamics of photoinduced intramolecular electron transfer with femtosecond X-ray pulses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Canton, Sophie E.; Kjr, Kasper S.; Vank, Gyrgy; van Driel, Tim B.; Adachi, Shin -ichi; Bordage, Amlie; Bressler, Christian; Chabera, Pavel; Christensen, Morten; Dohn, Asmus O.; et al

    2015-03-02

    Ultrafast photoinduced electron transfer preceding energy equilibration still poses many experimental and conceptual challenges to the optimization of photoconversion since an atomic-scale description has so far been beyond reach. Here we combine femtosecond transient optical absorption spectroscopy with ultrafast X-ray emission spectroscopy and diffuse X-ray scattering at the SACLA facility to track the non-equilibrated electronic and structural dynamics within a bimetallic donoracceptor complex that contains an optically dark centre. Exploiting the 100-fold increase in temporal resolution as compared with storage ring facilities, these measurements constitute the first X-ray-based visualization of a non-equilibrated intramolecular electron transfer process over large interatomic distances.moreThus experimental and theoretical results establish that mediation through electronically excited molecular states is a key mechanistic feature. The present study demonstrates the extensive potential of femtosecond X-ray techniques as diagnostics of non-adiabatic electron transfer processes in synthetic and biological systems, and some directions for future studies, are outlined.less

  1. Experimental evidence for the role of the CO orbital in electron transfer to gas phase acetic acid CH3CO2H: Effects of molecular orientation

    E-Print Network [OSTI]

    Brooks, Philip R.

    Experimental evidence for the role of the CO orbital in electron transfer to gas phase acetic acid; published online 20 April 2009 Electron transfer from K atoms to oriented acetic acid molecules produces acids and their sim- pler constituents, formic and acetic acid, this damage results from resonant

  2. Transparent Conductors from Carbon Nanotubes LBL-Assembled with Polymer Dopant with ?-? Electron Transfer

    SciTech Connect (OSTI)

    Zhu, Jian; Shim, Bong Sup; Di Prima, Matthew; Kotov, Nicholas A.

    2011-01-01

    Single-walled carbon nanotube (SWNT) and other carbon-based coatings are being considered as replacements for indium tin oxide (ITO). The problems of transparent conductors (TCs) coatings from SWNT and similar materials include poor mechanical properties, high roughness, low temperature resilience, and fast loss of conductivity. The simultaneous realization of these desirable characteristics can be achieved using high structural control of layer-by-layer (LBL) deposition, which is demonstrated by the assembly of hydroethyl cellulose (HOCS) and sulfonated polyetheretherketone (SPEEK)-SWNTs. A new type of SWNT doping based on electron transfer from valence bands of nanotubes to unoccupied levels of SPEEK through ?-? interactions was identified for this system. It leads to a conductivity of 1.1 10? S/m at 66 wt % loadings of SWNT. This is better than other polymer/SWNT composites and translates into surface conductivity of 920 ?/? and transmittance of 86.7% at 550 nm. The prepared LBL films also revealed unusually high temperature resilience up to 500 C, and low roughness of 3.5 nm (ITO glass -2.4 nm). Tensile modulus, ultimate strength, and toughness of such coatings are 13 2 GPa, 366 35 MPa, and 8 3 kJ/m, respectively, and exceed corresponding parameters of all similar TCs. The cumulative figure of merit, ?TC, which included the critical failure strain relevant for flexible electronics, was ?TC = 0.022 and should be compared to ?TC = 0.006 for commercial ITO. Further optimization is possible using stratified nanoscale coatings and improved doping from the macromolecular LBL components.

  3. Rational engineering of Geobacter sulfurreducens electron transfer components: A foundation for building improved Geobacter-based bioelectrochemical technologies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dantas, Joana M.; Morgado, Leonor; Aklujkar, Muktak; Bruix, Marta; Londer, Yuri Y.; Schiffer, Marianne; Pokkuluri, P. Raj; Salgueiro, Carlos A.

    2015-07-30

    Multiheme cytochromes have been implicated in Geobacter sulfurreducens extracellular electron transfer (EET). These proteins are potential targets to improve EET and enhance bioremediation and electrical current production by G. sulfurreducens. However, the functional characterization of multiheme cytochromes is particularly complex due to the co-existence of several microstates in solution, connecting the fully reduced and fully oxidized states. Throughout the last decade, new strategies have been developed to characterize multiheme redox proteins functionally and structurally. These strategies were used to reveal the functional mechanism of G. sulfurreducens multiheme cytochromes and also to identify key residues in these proteins for EET. Inmoreprevious studies, we set the foundations for enhancement of the EET abilities of G. sulfurreducens by characterizing a family of five triheme cytochromes (PpcA-E). These periplasmic cytochromes are implicated in electron transfer between the oxidative reactions of metabolism in the cytoplasm and the reduction of extracellular terminal electron acceptors at the cell's outer surface. The results obtained suggested that PpcA can couple e-/H+ transfer, a property that might contribute to the proton electrochemical gradient across the cytoplasmic membrane for metabolic energy production. The structural and functional properties of PpcA were characterized in detail and used for rational design of a family of 23 single site PpcA mutants. In this review, we summarize the functional characterization of the native and mutant proteins. Mutants that retain the mechanistic features of PpcA and adopt preferential e-/H+ transfer pathways at lower reduction potential values compared to the wild-type protein were selected for in vivo studies as the best candidates to increase the electron transfer rate of G. sulfurreducens. For the first time G. sulfurreducens strains have been manipulated by the introduction of mutant forms of essential proteins with the aim to develop and improve bioelectrochemical technologies.less

  4. Electron-Transfer Collisions of Low-Energy Multicharged Nitrogen-Ions with H-2 and N-2

    E-Print Network [OSTI]

    Wang, H. Y.; Church, David A.

    1987-01-01

    VOLUME 36, NUMBER 9 NOVEMBER 1, 1987 Electron-transfer collisions of low-energy multicharged nitrogen ions with H2 and N2 Hua-Ying Wang and D. A. Church Department of Physics, Texas A&M University, College Station, Texas 77843-4242 (Received 27 April... 1987) A stored-ion collision technique has been used to study the charge-changing collisions of mul- ticharged nitrogen ions with H2 and N2 target gases. The ions were produced inside a Penning trap with use of electron-impact ionization. The time...

  5. Solid State Electron Transfer via Bacterial Nanowires: Contributions Toward a Mechanistic Understanding of Geophysical Response of Biostimulated Subsurface

    SciTech Connect (OSTI)

    Estella Atekwana

    2012-05-08

    The degradation of organic matter by microorganisms provides a source of electrical potential or so-called 'self potential' (SP) that can be measured by using a voltmeter. During this process electrons are being produced as a waste-product and bacterial cells have to dispose of these to allow for the complete biodegradation of organic matter. Especially in anaerobic microbial communities, exo-cellular electron transfer is the most important driving force behind this process and organisms have developed different, but also similar, ways to transfer electrons to other microorganisms. Recently, it has been postulated that direct electron transfer from cell-to-cell is actually done by 'hard-wired' microorganisms. This shuttling of electrons is most likely done by certain c-type cytochromes that form the functional part of electrically conductive nanowires. In this study we investigated if nanowires can explain the geoelectrical (self potential and spectral induced polarization) signals observed at some biostimulated environments such as DOE sites. The objectives of our project are to: (1) investigate any temporal changes in the geophysical signatures (Self Potential (SP) and Induced Polarization (IP)) associated with nanowires of the bacterium Shewanella oneidensis MR-1, wild type and mtrc/omcA deletion mutant, (2) demonstrate that mutant strains of bacteria that produce nonconductive nanowires do not contribute to geoelectrical responses. We accomplished the following: (1) Provided training to students and a postdoctoral fellow that worked on the project, (2) Conducted several SP & IP measurements correlating the distribution of nanowires and SIP/SP signals in partial fulfillment of object No. 1 and 2. On the following we will report and discuss the results of our last experiment with some emphasis on the source mechanisms of both SP and IP associated with Shewanella oneidensis MR-1, wild type in sand columns.

  6. Electron Transport and Scattering in Graphene Devices Transferred to SrTiO3 Substrates

    E-Print Network [OSTI]

    Sachs, Raymond

    2013-01-01

    graphene device on SiO 2 (left) and STO (right). 5.6 PreparationGraphene Field-Effect Transistor Devices . 67 5.4 Measurement Setup . 68 5.5 Device Transfer Technique .. 70 5.6 Preparation

  7. United States-Mexico electricity transfers: Of alien electrons and the migration of undocumented environmental burdens

    SciTech Connect (OSTI)

    Gandara, A. [Univ. of California, Davis, CA (United States)

    1995-08-01

    This article intends to set forth the necessity for reform in the United States policy and procedures regarding approval of power transfers between the United States and Mexico. In order to do this, the article will review the history of electrical power transfers between the United States and Mexico (Part II), analyze recent regulatory changes in the United States and Mexico which may result in increased power exports to Mexico (Part III), evaluate the extent to which the present permit and authorization system in the United States considers the increased environmental burden of such power transfers (Part IV), and, where appropriate, propose some procedural and policy reforms that could take into account the environmental burdens generated by the production of power destined for transfer across the United States-Mexico border (Part V).

  8. Contribution of charge-transfer processes to ion-induced electron emission

    SciTech Connect (OSTI)

    Roesler, M.

    1996-12-01

    Charge changing events of ions moving inside metals are shown to contribute significantly to electron emission in the intermediate velocity regime via electrons coming from projectile ionization. Inclusion of equilibrium charge state fractions, together with two-electron Auger processes and resonant-coherent electron loss from the projectile, results in reasonable agreement with previous calculations for frozen protons, though a significant part of the emission is now interpreted in terms of charge exchange. The quantal character of the surface barrier transmission is shown to play an important role. The theory compares well with experimental observations for {ital H} projectiles. {copyright} {ital 1996 The American Physical Society.}

  9. Kinetics and thermodynamics of electron transfer in Debye solvents: An analytical and nonperturbative reduced density matrix theory

    E-Print Network [OSTI]

    Ping Han; Rui-Xue Xu; Baiqing Li; Jian Xu; Ping Cui; Yan Mo; YiJing Yan

    2006-04-11

    A nonperturbative electron transfer rate theory is developed based on the reduced density matrix dynamics, which can be evaluated readily for the Debye solvent model without further approximation. Not only does it recover for reaction rates the celebrated Marcus' inversion and Kramers' turnover behaviors, the present theory also predicts for reaction thermodynamics, such as equilibrium Gibbs free-energy and entropy, some interesting solvent-dependent features that are calling for experimental verification. Moreover, a continued fraction Green's function formalism is also constructed, which can be used together with Dyson equation technique, for efficient evaluation of nonperturbative reduced density matrix dynamics.

  10. Blinking suppression of CdTe quantum dots on epitaxial graphene and the analysis with Marcus electron transfer

    SciTech Connect (OSTI)

    Hirose, Takuya; Tamai, Naoto, E-mail: tamai@kwansei.ac.jp [Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337 (Japan); Kutsuma, Yasunori; Kurita, Atsusi; Kaneko, Tadaaki [Department of Physics, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337 (Japan)

    2014-08-25

    We have prepared epitaxial graphene by a Si sublimation method from 4H-SiC. Single-particle spectroscopy of CdTe quantum dots (QDs) on epitaxial graphene covered with polyvinylpyrrolidone (PVP) or polyethylene glycol (PEG) showed the suppression of luminescence blinking and ?10 times decreased luminescence intensity as compared with those on a glass. The electronic coupling constant, H{sub 01}, between CdTe QDs and graphene was calculated to be (3.3??0.4)??10{sup 2?}cm{sup ?1} in PVP and (3.7??0.8)??10{sup 2?}cm{sup ?1} in PEG based on Marcus theory of electron transfer and Tang-Marcus model of blinking with statistical distribution.

  11. Water-Stable, Hydroxamate Anchors for Functionalization of TiO{sub 2} Surfaces with Ultrafast Interfacial Electron Transfer

    SciTech Connect (OSTI)

    McNamara, W. R.; Milot, R. L.; Song, H.; Snoeberger III, R. C.; Batista, Victor S.; Schmuttenmaer, C. A.; Brudvig, Gary W.; Crabtree, Robert H.

    2010-01-01

    A novel class of derivatized hydroxamic acid linkages for robust sensitization of TiO{sub 2} nanoparticles (NPs) under various aqueous conditions is described. The stability of linkages bound to metal oxides under various conditions is important in developing photocatalytic cells which incorporate transition metal complexes for solar energy conversion. In order to compare the standard carboxylate anchor to hydroxamates, two organic dyes differing only in anchoring groups were synthesized and attached to TiO{sub 2} NPs. At acidic, basic, and close to neutral pH, hydroxamic acid linkages resist detachment compared to the labile carboxylic acids. THz spectroscopy was used to compare ultrafast interfacial electron transfer (IET) into the conduction band of TiO{sub 2} for both linkages and found similar IET characteristics. Observable electron injection and stronger binding suggest that hydroxamates are a suitable class of anchors for designing water stable molecules for functionalizing TiO{sub 2}.

  12. Electron Transfer from Plastocyanin to the Photosystem I Reaction Center in Mutants with Increased Potential of the Primary Donor in Chlamydomonas

    E-Print Network [OSTI]

    in Photosynthesis, P.O. Box 871601, Arizona State UniVersity, Tempe, Arizona 85287-1601, and Institut de Biologie-mediated electron transfer from the artificial electron donor DCPIP to methyl viologen in thylakoid membranes and other model s

  13. Sulfur oxidation to sulfate coupled with electron transfer to electrodes by Desulfuromonas strain TZ1

    SciTech Connect (OSTI)

    Zhang, T; Bain, TS; Barlett, MA; Dar, SA; Snoeyenbos-West, OL; Nevin, KP; Lovley, DR

    2014-01-02

    Microbial oxidation of elemental sulfur with an electrode serving as the electron acceptor is of interest because this may play an important role in the recovery of electrons from sulfidic wastes and for current production in marine benthic microbial fuel cells. Enrichments initiated with a marine sediment inoculum, with elemental sulfur as the electron donor and a positively poised (+300 mV versus Ag/AgCl) anode as the electron acceptor, yielded an anode biofilm with a diversity of micro-organisms, including Thiobacillus, Sulfurimonas, Pseudomonas, Clostridium and Desulfuromonas species. Further enrichment of the anode biofilm inoculum in medium with elemental sulfur as the electron donor and Fe(III) oxide as the electron acceptor, followed by isolation in solidified sulfur/Fe(III) medium yielded a strain of Desulfuromonas, designated strain TZ1. Strain TZ1 effectively oxidized elemental sulfur to sulfate with an anode serving as the sole electron acceptor, at rates faster than Desulfobulbus propionicus, the only other organism in pure culture previously shown to oxidize S with current production. The abundance of Desulfuromonas species enriched on the anodes of marine benthic fuel cells has previously been interpreted as acetate oxidation driving current production, but the results presented here suggest that sulfur-driven current production is a likely alternative.

  14. Excited states and electron transfer in solution : models based on density functional theory

    E-Print Network [OSTI]

    Kowalczyk, Timothy Daniel

    2012-01-01

    Our understanding of organic materials for solar energy conversion stands to benefit greatly from accurate, computationally tractable electronic structure methods for excited states. Here we apply two approaches based on ...

  15. Theoretical and simulation tools for electron transfer and chain reactions in single walled carbon nanotubes

    E-Print Network [OSTI]

    Nair, Nitish

    2009-01-01

    Single walled carbon nanotubes (SWNT) are cylindrical sheets of graphene whose electronic structures and diameters are determined by their chiralities. Current synthetic methods produce batches of nanotubes containing a ...

  16. Engineering Escherichia coli for molecularly defined electron transfer to metal oxides and electrodes

    E-Print Network [OSTI]

    Jensen, Heather Marie

    2013-01-01

    E. J. P. Novel Mode of Microbial Energy Metabolism: OrganicEnergy level diagram of the electronic transitions in ferricytochromes c.Pg 179 Figure F-1: A schematic of a microbial

  17. Role of quinones in electron transfer of PQQglucose dehydrogenase anodesmediation or orientation effect

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Babanova, Sofia; Matanovic, Ivana; Chavez, Madelaine Seow; Atanassov, Plamen

    2015-06-16

    In this study, the influence of two quinones (1,2- and 1,4-benzoquinone) on the operation and mechanism of electron transfer in PQQ-sGDH anodes has been determined. Benzoquinones were experimentally explored as mediators present in the electrolyte. The electrochemical performance of the PQQsGDH anodes with and without the mediators was examined and for the first time molecular docking simulations were used to gain a fundamental understanding to explain the role of the mediator molecules in the design and operation of the enzymatic electrodes. It was proposed that the higher performance of the PQQsGDH anodes in the presence of 1,2- and 1,4-benzoquinones introducedmorein the solution is due to the shorter distance between these molecules and PQQ in the enzymatic molecule. It was also hypothesized that when 1,4-benzoquinone is adsorbed on a carbon support, it would play the dual role of a mediator and an orienting agent. At the same time, when 1,2-benzoquinone and ubiquinone are adsorbed on the electrode surface, the enzyme would transfer the electrons directly to the support, and these molecules would primarily play the role of an orienting agent.less

  18. Final Report: The Impact of Carbonate on Surface Protonation, Electron Transfer and Crystallization Reactions in Iron Oxide Nanoparticles and Colloids

    SciTech Connect (OSTI)

    Dixon, David Adams [The University of Alabama

    2013-07-02

    This project addresses key issues of importance in the geochemical behavior of iron oxides and in the geochemical cycling of carbon and iron. For Fe, we are specifically studying the influence of carbonate on electron transfer reactions, solid phase transformations, and the binding of carbonate to reactive sites on the edges of particles. The emphasis on carbonate arises because it is widely present in the natural environment, is known to bind strongly to oxide surfaces, is reactive on the time scales of interest, and has a speciation driven by acid-base reactions. The geochemical behavior of carbonate strongly influences global climate change and CO{sub 2} sequestration technologies. Our goal is to answer key questions with regards to specific site binding, electron transfer reactions, and crystallization reactions of iron oxides that impact both the geochemical cycling of iron and CO{sub 2} species. Our work is focused on the molecular level description of carbonate chemistry in solution including the prediction of isotope fractionation factors. We have also done work on critical atmospheric species.

  19. Electronic Coupling Dependence of Ultrafast Interfacial Electron...

    Office of Scientific and Technical Information (OSTI)

    Electron Transfer on Nanocrystalline Thin Films and Single Crystal Lian, Tianquan 14 SOLAR ENERGY The long-term goal of the proposed research is to understand electron transfer...

  20. Nonadiabatic Molecular Dynamics Study of Electron Transfer from Alizarin to the Hydrated Ti4+ Ion

    E-Print Network [OSTI]

    to the more costly traditional solar cell.1-5 It employs organic or transition-metal- based chromophores that forms the basis of the Gratzel type solar cell. The experimental data and electronic structure The dye-sensitized nanocrystalline solar cell, also known as the Gratzel cell, is a promising alternative

  1. Laser pulse control of ultrafast heterogeneous electron transfer: A computational study

    E-Print Network [OSTI]

    Rder, Beate

    this control task is more suited to an experimental test than the direct control of the charge injection injection from perylene into the conduction band of TiO2 is studied theoretically. The approach accounts for the electronic-ground state of the dye, the first excited state, the ionized state formed after charge injection

  2. Electron Transfer Reactivity Patterns at Chemically Modified Electrodes: Fundamentals and Application to the Optimization of Redox Recycling Amplification Systems

    SciTech Connect (OSTI)

    Adam Johan Bergren

    2006-05-01

    Electroanalytical chemistry is often utilized in chemical analysis and Fundamental studies. Important advances have been made in these areas since the advent of chemically modified electrodes: the coating of an electrode with a chemical film in order to impart desirable, and ideally, predictable properties. These procedures enable the exploitation of unique reactivity patterns. This dissertation presents studies that investigate novel reaction mechanisms at self-assembled monolayers on gold. In particular, a unique electrochemical current amplification scheme is detailed that relies on a selective electrode to enable a reactivity pattern that results in regeneration of the analyte (redox recycling). This regenerating reaction can occur up to 250 times for each analyte molecule, leading to a notable enhancement in the observed current. The requirements of electrode selectivity and the resulting amplification and detection limit improvements are described with respect to the heterogeneous and homogeneous electron transfer rates that characterize the system. These studies revealed that the heterogeneous electrolysis of the analyte should ideally be electrochemically reversible, while that for the regenerating agent should be held to a low level. Moreover, the homogeneous reaction that recycles the analyte should occur at a rapid rate. The physical selectivity mechanism is also detailed with respect to the properties of the electrode and redox probes utilized. It is shown that partitioning of the analyte into/onto the adlayer leads to the extraordinary selectivity of the alkanethiolate monolayer modified electrode. Collectively, these studies enable a thorough understanding of the complex electrode mechanism required for successful redox recycling amplification systems, Finally, in a separate (but related) study, the effect of the akyl chain length on the heterogeneous electron transfer behavior of solution-based redox probes is reported, where an odd-even oscillation (with respect to the number of methylene units in the alkyl chain) was observed. Characterization of the adlayers by infrared reflection spectroscopy, ellipsometry, and wetting revealed odd-even effects in the orientation of the terminal methyl group and hydrophobic character of the adlayers. Using these structural characterizations as a basis, several possible mechanisms that can account for the odd-even effect in the heterogeneous electron transfer rates of solution-based redox couples are discussed.

  3. Reorganization asymmetry of electron transfer in ferroelectric media and principles of artificial photosynthesis

    E-Print Network [OSTI]

    Dmitry V. Matyushov

    2006-03-24

    This study considers electronic transitions within donor-acceptor complexes dissolved in media with macroscopic polarization. The change of the polarizability of the donor-acceptor complex in the course of electronic transition couples to the reaction field of the polar environment and the electric field created by the macroscopic polarization. An analytical theory developed to describe this situation predicts a significant asymmetry of the reorganization energy between charge separation and charge recombination transitions. This result is proved by Monte Carlo simulations of a model polarizable diatomic dissolved in a ferroelectric fluid of soft dipolar spheres. The ratio of the reorganization energies for the forward and backward reactions up to a factor of 25 is obtained in the simulations. This result, as well as the effect of the macroscopic electric field, is discussed in application to the design of efficient photosynthetic devices.

  4. Electron Transfer within Self-Assembling Cyclic Tetramers Using Chlorophyll-Based Donor?Acceptor Building Blocks

    SciTech Connect (OSTI)

    Gunderson, Victoria L.; Smeigh, Amanda L.; Kim, Chul Hoon; Co, Dick T.; Wasielewski, Michael R. (NWU)

    2012-05-09

    The synthesis and photoinduced charge transfer properties of a series of Chl-based donor-acceptor triad building blocks that self-assemble into cyclic tetramers are reported. Chlorophyll a was converted into zinc methyl 3-ethylpyrochlorophyllide a (Chl) and then further modified at its 20-position to covalently attach a pyromellitimide (PI) acceptor bearing a pyridine ligand and one or two naphthalene-1,8:4,5-bis(dicarboximide) (NDI) secondary electron acceptors to give Chl-PI-NDI and Chl-PI-NDI2. The pyridine ligand within each ambident triad enables intermolecular Chl metal-ligand coordination in dry toluene, which results in the formation of cyclic tetramers in solution, as determined using small- and wide-angle X-ray scattering at a synchrotron source. Femtosecond and nanosecond transient absorption spectroscopy of the monomers in toluene-1% pyridine and the cyclic tetramers in toluene shows that the selective photoexcitation of Chl results in intramolecular electron transfer from 1*Chl to PI to form Chl+{lg_bullet}-PI-{lg_bullet}-NDI and Chl+{lg_bullet}-PI-{lg_bullet}-NDI2. This initial charge separation is followed by a rapid charge shift from PI-{lg_bullet} to NDI and subsequent charge recombination of Chl+{lg_bullet}-PI-NDI-{lg_bullet} and Chl+{lg_bullet}-PI-(NDI)NDI-{lg_bullet} on a 5-30 ns time scale. Charge recombination in the Chl-PI-NDI2 cyclic tetramer ({tau}CR = 30 {+-} 1 ns in toluene) is slower by a factor of 3 relative to the monomeric building blocks ({tau}CR = 10 {+-} 1 ns in toluene-1% pyridine). This indicates that the self-assembly of these building blocks into the cyclic tetramers alters their structures in a way that lengthens their charge separation lifetimes, which is an advantageous strategy for artificial photosynthetic systems.

  5. Characterization of alternate reductant binding and electron transfer in the dopamine. beta. -monooxygenase reaction

    SciTech Connect (OSTI)

    Stewart, L.C.; Klinman, J.P.

    1987-08-25

    The steady-state limiting kinetic parameters V/sub max/, V/K/sub DA/, and V/K/sub O/sub 2//, together with deuterium isotope effects on these parameters, have been determined for the dopamine ..beta..-monooxygenase (D..beta..M) reaction in the presence of structurally distinct reductants. The results show the one-electron reductant ferrocyanide to be nearly as kinetically competent as the presumed in vivo reductant ascrobate. Further, a reductant system of ferricyanide plus substrate dopamine yields steady-state kinetic parameters and isotope effects very similar to those measured solely in the presence of ferrocyanide, indicating a role for catecholamine in the rapid recycling of oxidized ferrocyanide. Use of substrate dopamine as the sole reductant is found to lead to a highly unusual kinetic independence of oxygen concentration, as well as significantly reduced values of V/sub max/ and V/K/sub DA/, and the authors conclude that dopamine reduces enzymic copper in a rate-limiting step that is 40-fold slower than with ascorbate. The near-identical kinetic parameters measured in the presence of either ascorbate or ferrocyanide, together with markedly reduced rates with dopamine, are interpreted in terms of a binding site for reductant that is physically distinct from the substrate binding site. This view is supported by molecular modeling, which reveals ascorbate and ferrocyanide to possess an unexpected similarity in potential sites for interaction with enzymic residues. With regard to electron flux, identical values of V/K/sub O/sub 2// have been measured with (2,2-/sup 2/H/sub 2/)dopamine as substrate both in the presence and in the absence of added ascorbate. This key result unambiguously rules out an entry of electrons to enzyme forms leading from the enzyme-dopamine complex to enzyme-bound product and, hence, reaction mechanisms involving a reductive activation of the putative Cu(II)-OOH prior to substrate hydroxylation.

  6. Engineering high charge transfer n-doping of graphene electrodes and its application to organic electronics

    E-Print Network [OSTI]

    Sanders, Simon; Cabrero-Vilatela, Andrea; Kidambi, Piran R.; Alexander-Webber, Jack A.; Weijtens, Christ; Braeuninger, Philipp; Aria, Adrianus I.; Qasim, Malik M.; Wilkinson, Timothy D.; Robertson, John; Hofmann, Stephan; Meyer, Jens

    2015-07-06

    including organic photovoltaic cells and organic light emitting diodes (OLEDs).18 Most of these applications require low sheet resistances and detailed band engineering to optimize charge injection/extraction.18 Hence effective doping and the controlled... to applications but also as a model system to develop a detailed understanding of the n-doping mechanisms for organic electronics in general. Here, we focus on the n-type doping of monolayer graphene with an alkali metal compound i.e. cesium carbonate (Cs2CO3...

  7. Transition Metal Donor-Peptide-Acceptor Complexes: From Intramolecular Electron Transfer Reactions to the Study of Reactive Intermediates

    SciTech Connect (OSTI)

    Isied, Stephan S.

    2003-03-11

    The trans-polyproline (PII) oligomers (Figure 1) are unusually rigid peptide structures which have been extensively studied by our group for peptide mediated intramolecular electron transfer (ET) at long distances. We have previously studied ET across a series of metal ion donor (D) acceptor (A) oligoproline peptides with different distances, driving forces and reorganizational energies. The majority of these experiments involve generating the ET intermediate using pulse radiolysis methods, although more recently photochemical methods are also used. Results of these studies showed that ET across peptides can vary by more than twelve orders of magnitude. Using ruthenium bipyridine donors, ET reaction rate constants across several proline residues (n = 4 - 9) occurred in the millisecond (ms) to {micro}s timescale, thus limiting the proline peptide conformational motions to only minor changes (far smaller than the large changes that occur on the ms to sec timescale, such as trans to cis proline isomerization). The present report describes our large data base of experimental results for D-peptide-A complexes in terms of a model where the involvement of both superexchange and hopping (hole and electron) mechanisms account for the long range ET rate constants observed. Our data shows that the change from superexchange to hopping mechanisms occurs at different distances depending on the type of D and A and their interactions with the peptides. Our model is also consistent with generalized models for superexchange and hopping which have been put forward by a number of theoretical groups to account for long range ET phenomena.

  8. Carver File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    File Storage File Storage Disk Quota Change Request Form Carver File Systems Carver has 3 kinds of file systems available to users: home directories, scratch directories and...

  9. Euclid File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    File storage File storage Disk Quota Change Request Form Euclid File Systems Euclid has 3 kinds of file systems available to users: home directories, scratch directories and...

  10. J. Phys. Chem. 1994,98, 4899-4905 4899 Electrostatic Field Measurements and Band Flattening during Electron-Transfer Processes at

    E-Print Network [OSTI]

    . The interfacial SHG at a fundamental wavelength of 584 nm is dominated by the electric field-induced second Electron-Transfer Processes at Single-CrystalTi02 Electrodes by Electric Field-Induced Optical Second Harmonic Generation Juliette M. Lantz and Robert M. Corn' Department of Chemistry, University of Wisconsin

  11. Testing time-dependent density functional theory with depopulated molecular orbitals for predicting electronic excitation energies of valence, Rydberg, and charge-transfer

    E-Print Network [OSTI]

    Truhlar, Donald G

    transition energies J. Chem. Phys. 137, 244104 (2012); 10.1063/1.4769078 A long-range-corrected densityTesting time-dependent density functional theory with depopulated molecular orbitals for predicting electronic excitation energies of valence, Rydberg, and charge-transfer states and potential energies near

  12. Large Electron Transfer Rate Effects from the Duschinsky Mixing of Vibrations Gerald M. Sando, Kenneth G. Spears,* and Joseph T. Hupp

    E-Print Network [OSTI]

    Road, EVanston, Illinois 60208 Peder Thusgaard Ruhoff Maersk Mc-Kinney Moller Institute for Production Technology, UniVersity of Southern Denmark, Odense UniVersity, CampusVej 55, DK-5230 Odense M, Denmark Recei of magnitude for inverted electron transfer reactions and modest mixing. The peak location in a rate vs energy

  13. Nonadiabatic dynamics of electron transfer in solution: Explicit and implicit solvent treatments that include multiple relaxation time scales

    SciTech Connect (OSTI)

    Schwerdtfeger, Christine A.; Soudackov, Alexander V.; Hammes-Schiffer, Sharon, E-mail: shs3@illinois.edu [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States)] [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States)

    2014-01-21

    The development of efficient theoretical methods for describing electron transfer (ET) reactions in condensed phases is important for a variety of chemical and biological applications. Previously, dynamical dielectric continuum theory was used to derive Langevin equations for a single collective solvent coordinate describing ET in a polar solvent. In this theory, the parameters are directly related to the physical properties of the system and can be determined from experimental data or explicit molecular dynamics simulations. Herein, we combine these Langevin equations with surface hopping nonadiabatic dynamics methods to calculate the rate constants for thermal ET reactions in polar solvents for a wide range of electronic couplings and reaction free energies. Comparison of explicit and implicit solvent calculations illustrates that the mapping from explicit to implicit solvent models is valid even for solvents exhibiting complex relaxation behavior with multiple relaxation time scales and a short-time inertial response. The rate constants calculated for implicit solvent models with a single solvent relaxation time scale corresponding to water, acetonitrile, and methanol agree well with analytical theories in the Golden rule and solvent-controlled regimes, as well as in the intermediate regime. The implicit solvent models with two relaxation time scales are in qualitative agreement with the analytical theories but quantitatively overestimate the rate constants compared to these theories. Analysis of these simulations elucidates the importance of multiple relaxation time scales and the inertial component of the solvent response, as well as potential shortcomings of the analytical theories based on single time scale solvent relaxation models. This implicit solvent approach will enable the simulation of a wide range of ET reactions via the stochastic dynamics of a single collective solvent coordinate with parameters that are relevant to experimentally accessible systems.

  14. Ultra-stable Molecule-Surface Architectures at Metal Oxides: Structure, Bonding, and Electron-transfer Processes

    SciTech Connect (OSTI)

    Hamers, Robert John

    2013-12-07

    Research funded by this project focused on the development of improved strategies for functionalization of metal oxides to enhance charge?transfer processes relevant to solar energy conversion. Initial studies included Fe2O3, WO3, TiO2, SnO2, and ZnO as model oxide systems; these systems were chosen due to differences in metal oxidation state and chemical bonding types in these oxides. Later studies focused largely on SnO2 and ZnO, as these materials show particularly promising surface chemistry, have high electron mobility, and can be readily grown in both spherical nanoparticles and as elongated nanorods. New molecules were synthesized that allowed the direct chemical assembly of novel nanoparticle ?dyadic? structures in which two different oxide materials are chemically joined, leading to an interface that enhances the separation of of charge upon illumination. We demonstrated that such junctions enhance photocatalytic efficiency using model organic compounds. A separate effort focused on novel approaches to linking dye molecules to SnO2 and ZnO as a way to enhance solar conversion efficiency. A novel type of surface binding through

  15. Photo-induced water oxidation at the aqueous GaN (101?0) interface: Deprotonation kinetics of the first proton-coupled electron-transfer step

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ertem, Mehmed Z. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yale Univ., New Haven, CT (United States); Kharche, Neerav [Brookhaven National Lab. (BNL), Upton, NY (United States); Batista, Victor S. [Yale Univ., New Haven, CT (United States); Hybertsen, Mark S. [Brookhaven National Lab. (BNL), Upton, NY (United States); Tully, John C. [Yale Univ., New Haven, CT (United States); Muckerman, James T. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-04-03

    Photoeclectrochemical water splitting plays a key role in a promising path to the carbon-neutral generation of solar fuels. Wurzite GaN and its alloys (e.g., GaN/ZnO and InGaN) are demonstrated photocatalysts for water oxidation, and they can drive the overall water splitting reaction when coupled with co-catalysts for proton reduction. In the present work, we investigate the water oxidation mechanism on the prototypical GaN (101?0) surface using a combined ab initio molecular dynamics and molecular cluster model approach taking into account the role of water dissociation and hydrogen bonding within the first solvation shell of the hydroxylated surface. The investigation of free-energy changes for the four proton-coupled electron-transfer (PCET) steps of the water oxidation mechanism shows that the first PCET step for the conversion of Ga-OH to Ga-O?? requires the highest energy input. We further examine the sequential PCETs, with the proton transfer (PT) following the electron transfer (ET), and find that photo-generated holes localize on surface NH sites is thermodynamically more favorable than OH sites. However, proton transfer from OH sites with subsequent localization of holes on oxygen atoms is kinetically favored owing to hydrogen bonding interactions at the GaN (101?0)water interface. We find that the deprotonation of surface OH sites is the limiting factor for the generation of reactive oxyl radical ion intermediates and consequently for water oxidation.

  16. Interfacial Engineering of Nanoparticle Systems: Assesment of Electron Transfer in Inter and Intrananoparticle Photosystems as well as Sensing Applications

    E-Print Network [OSTI]

    Phebus, Bruce Drury

    2015-01-01

    carbonate functionalized graphene quantum dots as stable electron-selective layer for improvement of inverted polymer

  17. Franklin File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Files systems Files systems NERSC's global home and project file systems are available on Franklin. Additionally, Franklin has over 400 TB of locally attached high-performance...

  18. A parametric study of shock jump chemistry, electron temperature, and radiative heat transfer models in hypersonic flows

    E-Print Network [OSTI]

    Greendyke, Robert Brian

    1988-01-01

    will examine the radiance model and various step models in order to determine their appropriateness to the flight regime of the AOTV. The final area to be investigated will be the effect of nonequilibrium corrections on the radiative heat transfer models... of T and e T will be valid as long as there is a reasonable amount vNs of nitrogen molecules in the flow. Radiative Heat Transfer Models For this study, four radiative heat transfer models were examined. One of these models is an optically thin radiance...

  19. File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji Fiji IsFileFileFile

  20. Tuning near-gap electronic structure, interface charge transfer and visible light response of hybrid doped graphene and Ag3PO4 composite: Dopant effects

    E-Print Network [OSTI]

    He, Chao-Ni; Xu, Liang; Yang, Yin-Cai; Zhou, Bing-Xin; Huang, Gui-Fang; Peng, P; Liu, Wu-Ming

    2015-01-01

    The enhanced photocatalytic performance of doped graphene(GR)/semiconductor nanocomposites have recently been widely observed, but an understanding of the underlying mechanisms behind it is still out of reach. As a model system to study the effect of dopants, we investigate the electronic structures and optical properites of doped GR/Ag3PO4 nanocomposites using the first-principles calculations, demonstrating that the band gap, near-gap electronic structure and interface charge transfer of the doped GR/Ag3PO4(100) composite can be tuned by the dopants. Interestingly, the doping atom and C atoms bonded to dopant become active sites for photocatalysis because they are positively or negatively charged due to the charge redistribution caused by interaction. The dopants can enhance the visible light absorption and photoinduced electrons transfer. We propose that the N atom may be most appropriate doping for the GR/Ag3PO4 photocatalyst. This work can rationalize the available experimental results about N-doped GR-s...

  1. Photo-induced water oxidation at the aqueous GaN (1010) interface: Deprotonation kinetics of the first proton-coupled electron-transfer step

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ertem, Mehmed Z.; Kharche, Neerav; Batista, Victor S.; Hybertsen, Mark S.; Tully, John C.; Muckerman, James T.

    2015-03-12

    Photoeclectrochemical water splitting plays a key role in a promising path to the carbon-neutral generation of solar fuels. Wurzite GaN and its alloys (e.g., GaN/ZnO and InGaN) are demonstrated photocatalysts for water oxidation, and they can drive the overall water splitting reaction when coupled with co-catalysts for proton reduction. In the present work, we investigate the water oxidation mechanism on the prototypical GaN (1010) surface using a combined ab initio molecular dynamics and molecular cluster model approach taking into account the role of water dissociation and hydrogen bonding within the first solvation shell of the hydroxylated surface. The investigation ofmorefree-energy changes for the four proton-coupled electron-transfer (PCET) steps of the water oxidation mechanism shows that the first PCET step for the conversion of Ga-OH to Ga-O?? requires the highest energy input. We further examine the sequential PCETs, with the proton transfer (PT) following the electron transfer (ET), and find that photo-generated holes localize on surface NH sites is thermodynamically more favorable than OH sites. However, proton transfer from OH sites with subsequent localization of holes on oxygen atoms is kinetically favored owing to hydrogen bonding interactions at the GaN (1010)water interface. We find that the deprotonation of surface OH sites is the limiting factor for the generation of reactive oxyl radical ion intermediates and consequently for water oxidation.less

  2. Excitonic couplings and interband energy transfer in a double-wall molecular aggregate imaged by coherent two-dimensional electronic

    E-Print Network [OSTI]

    Mukamel, Shaul

    transfer efficiency are relevant to many applications such as artificial photosynthesis, polariton science making recourse to an a priori model. Theory and simulations, based on an effective multilevel scheme and a quantum-dissipative model with experimental pulse envelopes, explain the origin of the cross peaks, reveal

  3. File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji Fiji IsFileFile

  4. Files systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji FijiO FileFiles

  5. Thorium and uranium redox-active ligand complexes; reversible intramolecular electron transfer in U(dpp-BIAN)2/ U(dpp-BIAN)2(THE)

    SciTech Connect (OSTI)

    Schelter, Eric John [Los Alamos National Laboratory; Wu, Ruilian [Los Alamos National Laboratory; Scott, Brian L [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory; Batista, Enrique R [Los Alamos National Laboratory; Morris, David E [Los Alamos National Laboratory; Kiplinger, Jaqueline L [Los Alamos National Laboratory

    2008-01-01

    Actinide complexes of the redox-active ligand dpp-BIAN{sup 2-} (dpp-BIAN = bis(2,6-diisopropylphenyl)acenaphthylene), An(dpp-BIAN){sub 2}(THF){sub n} (An = Th, n = 1; An = U, n = 0, 1) have been prepared. Solid-state magnetic and single-crystal X-ray data for U(dpp-BIAN){sub 2}(THF){sub n} show when n = 0, the complex exists in an f{sup 2}-{pi}*{sup 4} configuration; whereas an intramolecular electron transfer occurs for n = 1, resulting in an f{sup 3}-{pi}*{sup 3} ground configuration. The magnetic data also indicate that interconversion between the two forms of the complex is possible, limited only by the ability of THF vapor to penetrate the solid on cooling of the sample. Spectroscopic data indicate the complex exists solely in the f{sup 2}-{pi}*{sup 4} form in solution, evidenced by the appearance of only small changes in the electronic absorption spectra of the U(dpp-BIAN){sub 2} complex on titration with THF and by measurement of the solution magnetic moment m d{sub 8}-tetrahydrofuran using Evans method. Electrochemistry of the complexes is reported, with small differences observed in wave potentials between metals and in the presence of THF. These data represent the first example of a well-defined, reversible intramolecular electron transfer in an f-element complex and the second example of oxidation state change through dative interaction with a metal ion.

  6. Photoreactivity of ZnO nanoparticles in visible light: Effect of surface states on electron transfer reaction

    SciTech Connect (OSTI)

    Baruah, Sunandan; Dutta, Joydeep; Sinha, Sudarson Sekhar; Ghosh, Barnali; Pal, Samir Kumar; Raychaudhuri, A. K.

    2009-04-01

    Wide band gap metal oxide semiconductors such as zinc oxide (ZnO) show visible band photolysis that has been employed, among others, to degrade harmful organic contaminants into harmless mineral acids. Metal oxides show enhanced photocatalytic activity with the increase in electronic defects in the crystallites. By introducing defects into the crystal lattice of ZnO nanoparticles, we observe a redshift in the optical absorption shifting from the ultraviolet region to the visible region (400-700 nm), which is due to the creation of intermediate defect states that inhibit the electron hole recombination process. The defects were introduced by fast nucleation and growth of the nanoparticles by rapid heating using microwave irradiation and subsequent quenching during the precipitation reaction. To elucidate the nature of the photodegradation process, picosecond resolved time correlated single photon count (TCSPC) spectroscopy was carried out to record the electronic transitions resulting from the de-excitation of the electrons to their stable states. Photodegradation and TCSPC studies showed that defect engineered ZnO nanoparticles obtained through fast crystallization during growth lead to a faster initial degradation rate of methylene blue as compared to the conventionally synthesized nanoparticles.

  7. A mixed quantum-classical Liouville study of the population dynamics in a model photo-induced condensed phase electron transfer reaction

    SciTech Connect (OSTI)

    Rekik, Najeh; Freedman, Holly; Hanna, Gabriel [Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2G2 (Canada); Hsieh, Chang-Yu [Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6 (Canada)

    2013-04-14

    We apply two approximate solutions of the quantum-classical Liouville equation (QCLE) in the mapping representation to the simulation of the laser-induced response of a quantum subsystem coupled to a classical environment. These solutions, known as the Poisson Bracket Mapping Equation (PBME) and the Forward-Backward (FB) trajectory solutions, involve simple algorithms in which the dynamics of both the quantum and classical degrees of freedom are described in terms of continuous variables, as opposed to standard surface-hopping solutions in which the classical degrees of freedom hop between potential energy surfaces dictated by the discrete adiabatic state of the quantum subsystem. The validity of these QCLE-based solutions is tested on a non-trivial electron transfer model involving more than two quantum states, a time-dependent Hamiltonian, strong subsystem-bath coupling, and an initial energy shift between the donor and acceptor states that depends on the strength of the subsystem-bath coupling. In particular, we calculate the time-dependent population of the photoexcited donor state in response to an ultrafast, on-resonance pump pulse in a three-state model of an electron transfer complex that is coupled asymmetrically to a bath of harmonic oscillators through the optically dark acceptor state. Within this approach, the three-state electron transfer complex is treated quantum mechanically, while the bath oscillators are treated classically. When compared to the more accurate QCLE-based surface-hopping solution and to the numerically exact quantum results, we find that the PBME solution is not capable of qualitatively capturing the population dynamics, whereas the FB solution is. However, when the subsystem-bath coupling is decreased (which also decreases the initial energy shift between the donor and acceptor states) or the initial shift is removed altogether, both the PBME and FB results agree better with the QCLE-based surface-hopping results. These findings highlight the challenges posed by various conditions such as a time-dependent external field, the strength of the subsystem-bath coupling, and the degree of asymmetry on the accuracy of the PBME and FB algorithms.

  8. Eliza File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES ScienceInformation Company Name orElectronicElenaEliza File

  9. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansas Nuclear ProfileMultiferroicAward | DepartmentElectron thermal

  10. Near Infrared (NIR) Imaging Techniques Using Lasers and Nonlinear Crystal Optical Parametric Oscillator/Amplifier (OPO/OPA) Imaging and Transferred Electron (TE) Photocathode Image Intensifiers

    SciTech Connect (OSTI)

    YATES,GEORGE J.; MCDONALD,THOMAS E. JR.; BLISS,DAVID E.; CAMERON,STEWART M.; GREIVES,KENNETH H.; ZUTAVERN,FRED J.

    2000-12-20

    Laboratory experiments utilizing different near-infrared (NIR) sensitive imaging techniques for LADAR range gated imaging at eye-safe wavelengths are presented. An OPO/OPA configuration incorporating a nonlinear crystal for wavelength conversion of 1.56 micron probe or broadcast laser light to 807 nm light by utilizing a second pump laser at 532 nm for gating and gain, was evaluated for sensitivity, resolution, and general image quality. These data are presented with similar test results obtained from an image intensifier based upon a transferred electron (TE) photocathode with high quantum efficiency (QE) in the 1-2 micron range, with a P-20 phosphor output screen. Data presented include range-gated imaging performance in a cloud chamber with varying optical attenuation of laser reflectance images.

  11. Desulfurization of organic sulfur from a subbituminous coal by electron-transfer process with K{sub 4}(Fe(CN){sub 6})

    SciTech Connect (OSTI)

    Dipu Borah [Pragjyotika J College, Titabar (India). Department of Chemistry

    2006-02-01

    The desulfurization reaction involving direct electron transfer from potassium ferrocyanide, K{sub 4}(Fe(CN){sub 6}), successfully removed organic sulfur from a subbituminous coal. The temperature variation of desulfurization revealed that increase of temperature enhanced the level of sulfur removal. Moreover, the desulfurization reaction was found to be dependent on the concentration of K{sub 4}(Fe(CN){sub 6}). Gradual increase in the concentration of K{sub 4}(Fe(CN){sub 6}) raised the magnitude of desulfurization, but at higher concentration the variation was not significant. The removal of organic sulfur from unoxidized coal slightly increased with reduced particle size. Desulfurization from oxidized coals (prepared by aerial oxidation) revealed a higher level of sulfur removal in comparison to unoxidized coal. Highest desulfurization of 36.4 wt % was obtained at 90{sup o}C and 0.1 M concentration of K{sub 4}(Fe(CN){sub 6}) in the 100-mesh size oxidized coal prepared at 200{sup o}C. Model sulfur compound study revealed that aliphatic types of sulfur compounds are primarily responsible for desulfurization. Because of higher stability, thiophene and condensed thiophene-type of compounds perhaps remained unaffected by the electron-transfer agent. Infrared study revealed the formation of oxidized sulfur compounds (sulfoxide, sulfone, sulfonic acid, etc.) in the oxidized coals. The desulfurization reaction in different systems is well-represented by the pseudo-first-order kinetic model. Application of the transition state theory indicated that the desulfurization reaction proceeds with the absorption of heat (endothermic reaction) and is nonspontaneous in nature. 53 refs., 6 figs., 3 tabs.

  12. Optical characterization of free electron concentration in heteroepitaxial InN layers using Fourier transform infrared spectroscopy and a 2 Multiplication-Sign 2 transfer-matrix algebra

    SciTech Connect (OSTI)

    Katsidis, C. C.; Ajagunna, A. O.; Georgakilas, A.

    2013-02-21

    Fourier Transform Infrared (FTIR) reflectance spectroscopy has been implemented as a non-destructive, non-invasive, tool for the optical characterization of a set of c-plane InN single heteroepitaxial layers spanning a wide range of thicknesses (30-2000 nm). The c-plane (0001) InN epilayers were grown by plasma-assisted molecular beam epitaxy (PAMBE) on GaN(0001) buffer layers which had been grown on Al{sub 2}O{sub 3}(0001) substrates. It is shown that for arbitrary multilayers with homogeneous anisotropic layers having their principal axes coincident with the laboratory coordinates, a 2 Multiplication-Sign 2 matrix algebra based on a general transfer-matrix method (GTMM) is adequate to interpret their optical response. Analysis of optical reflectance in the far and mid infrared spectral range has been found capable to discriminate between the bulk, the surface and interface contributions of free carriers in the InN epilayers revealing the existence of electron accumulation layers with carrier concentrations in mid 10{sup 19} cm{sup -3} at both the InN surface and the InN/GaN interface. The spectra could be fitted with a three-layer model, determining the different electron concentration and mobility values of the bulk and of the surface and the interface electron accumulation layers in the InN films. The variation of these values with increasing InN thickness could be also sensitively detected by the optical measurements. The comparison between the optically determined drift mobility and the Hall mobility of the thickest sample reveals a value of r{sub H} = 1.49 for the Hall factor of InN at a carrier concentration of 1.11 Multiplication-Sign 10{sup 19} cm{sup -3} at 300 Degree-Sign {Kappa}.

  13. TO: FILE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1; -.ll 1q4207---TO: FILE

  14. TO: FILE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1; -.ll, TO: FILE

  15. TO: FILE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1; -.ll, TO: FILE3

  16. TO: FILE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1; -.ll, TO: FILE3F&i

  17. File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji Fiji IsFile Systems

  18. File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji Fiji IsFile

  19. FERC Filing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunitiesofExtrans - PermeationGovernment | Department ofFerc Filing

  20. Introducing fast file transfer from space

    E-Print Network [OSTI]

    Wood, Lloyd

    anywhere on EarthDMC can image anywhere on Earth Palm Island Resort, Dubai, 14 Dec 2003 (UK-DMC) Three

  1. Electron transfer networks Murad Banaji

    E-Print Network [OSTI]

    Banaji,. Murad

    energy AMS subject classifications. 37A60, 52A41, 80A30, 90C25 DOI. 10.1137/120866919 1. Introduction. 1

  2. Standard interface file handbook

    SciTech Connect (OSTI)

    Shapiro, A.; Huria, H.C. )

    1992-10-01

    This handbook documents many of the standard interface file formats that have been adopted by the US Department of Energy to facilitate communications between and portability of, various large reactor physics and radiation transport software packages. The emphasis is on those files needed for use of the VENTURE/PC diffusion-depletion code system. File structures, contents and some practical advice on use of the various files are provided.

  3. Page 1 of 1 Internal Billing and Non-Salary Cost Transfers Using Journal Entry Tool (JET)

    E-Print Network [OSTI]

    Bohnhoff, David

    Page 1 of 1 Internal Billing and Non-Salary Cost Transfers Using Journal Entry Tool (JET) JET loading the file to JET. Cell Format: Please use upper case for alpha letters used in the funding codes file named "JET Excel File Layout". #12;

  4. UNIX file permissions

    E-Print Network [OSTI]

    ... out sensitive information (like promotion documents and qualifier exams). ... about security, you will want to change your "umask" line in your .cshrc file.

  5. Office of Technology Transfer Material Transfer Agreements

    E-Print Network [OSTI]

    Tullos, Desiree

    Office of Technology Transfer Material Transfer Agreements Confidentiality Agreements Copyright / Patent Licensing The Office of Technology Transfer facilitates the transfer of innovations out of the university for public benefit TOOLS #12;Office of Technology Transfer Facilitating transfer of innovations

  6. Register file soft error recovery

    DOE Patents [OSTI]

    Fleischer, Bruce M.; Fox, Thomas W.; Wait, Charles D.; Muff, Adam J.; Watson, III, Alfred T.

    2013-10-15

    Register file soft error recovery including a system that includes a first register file and a second register file that mirrors the first register file. The system also includes an arithmetic pipeline for receiving data read from the first register file, and error detection circuitry to detect whether the data read from the first register file includes corrupted data. The system further includes error recovery circuitry to insert an error recovery instruction into the arithmetic pipeline in response to detecting the corrupted data. The inserted error recovery instruction replaces the corrupted data in the first register file with a copy of the data from the second register file.

  7. Direct probe of Mott-Hubbard to charge-transfer insulator transition and electronic structure evolution in transition-metal systems

    SciTech Connect (OSTI)

    Olalde-Velasco, P; Jimenez-Mier, J; Denlinger, JD; Hussain, Z; Yang, WL

    2011-07-11

    We report the most direct experimental verification of Mott-Hubbard and charge-transfer insulators through x-ray emission spectroscopy in transition-metal (TM) fluorides. The p-d hybridization features in the spectra allow a straightforward energy alignment of the anion-2p and metal-3d valence states, which visually shows the difference between the two types of insulators. Furthermore, in parallel with the theoretical Zaanen-Sawatzky-Allen diagram, a complete experimental systematics of the 3d Coulomb interaction and the 2p-3d charge-transfer energy is reported and could serve as a universal experimental trend for other TM systems including oxides.

  8. The Nature of the Intramolecular Charge Transfer Excited State in p-Pyrrolocyanobenzene (PBN) and Other Derivatives of Benzene Substituted by Electron Donor and Acceptor

    E-Print Network [OSTI]

    Haas, Yehuda

    -Pyrrolocyanobenzene (PBN) and Other Derivatives of Benzene Substituted by Electron Donor and Acceptor Groups Shmuel Zilberg analysis of these compounds, in which benzene is substituted by an electron withdrawing group of benzene and is of a covalent nature. Light emission from this state is due to local excitation

  9. The Effect of the Initial Window Size and Limited Transmit Algorithm on the Transient Behavior of TCP Transfers

    E-Print Network [OSTI]

    Avrachenkov, Konstantin

    . This harmful scenario happens when the very last pack ets of the file transfer are lost. Therefore to avoid on the network load we suggest to implement the new modification only for short file transfers. Key words. TCP for the TCP performance since based on conservative approach its value is normally set to sev eral times

  10. The Effect of the Initial Window Size and Limited Transmit Algorithm on the Transient Behavior of TCP Transfers

    E-Print Network [OSTI]

    Ayesta, Urtzi

    . This harmful scenario happens when the very last pack- ets of the file transfer are lost. Therefore to avoid on the network load we suggest to implement the new modification only for short file transfers. Key words. TCP for the TCP performance since based on conservative approach its value is normally set to sev- eral times

  11. Construction of file database management

    SciTech Connect (OSTI)

    MERRILL,KYLE J.

    2000-03-01

    This work created a database for tracking data analysis files from multiple lab techniques and equipment stored on a central file server. Experimental details appropriate for each file type are pulled from the file header and stored in a searchable database. The database also stores specific location and self-directory structure for each data file. Queries can be run on the database according to file type, sample type or other experimental parameters. The database was constructed in Microsoft Access and Visual Basic was used for extraction of information from the file header.

  12. Renewal-anomalous-heterogeneous files

    E-Print Network [OSTI]

    Ophir Flomenbom

    2010-08-13

    Renewal-anomalous-heterogeneous files are solved. A simple file is made of Brownian hard spheres that diffuse stochastically in an effective 1D channel. Generally, Brownian files are heterogeneous: the spheres' diffusion coefficients are distributed and the initial spheres' density is non-uniform. In renewal-anomalous files, the distribution of waiting times for individual jumps is exponential as in Brownian files, yet obeys: {\\psi}_{\\alpha} (t)~t^(-1-{\\alpha}), 0renewal as all the particles attempt to jump at the same time. It is shown that the mean square displacement (MSD) in a renewal-anomalous-heterogeneous file, , obeys, ~[_{nrml}]^{\\alpha}, where _{nrml} is the MSD in the corresponding Brownian file. This scaling is an outcome of an exact relation (derived here) connecting probability density functions of Brownian files and renewal-anomalous files. It is also shown that non-renewal-anomalous files are slower than the corresponding renewal ones.

  13. EIA-176 Electronic Filing System (EFS)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural GasNatural GasEIA lowers forecast for summer

  14. BPA files reciprocity tariff

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 12 BONNEVILLE POWER ADMINISTRATION FOR IMMEDIATE RELEASE Friday, March 30, 2012 CONTACT: Doug Johnson, 503-230-5840 or 503-230-5131 BPA files reciprocity tariff Portland, Ore. -...

  15. Frontiers in Biosciences 9, 309-337, January 1, 2004 PROTON AND ELECTRON TRANSFER IN THE ACCEPTOR QUINONE COMPLEX OF PHOTOSYNTHETIC REACTION

    E-Print Network [OSTI]

    Wraight, Colin A.

    , and to export these in a mobile form for subsequent utilization in "energy coupled" electron transport chains summarizes progress to date, which suggests that the RC can serve as a paradigm, not only for many energy is to convert light energy into metastable oxidizing and reducing equivalents, by charge separation

  16. Hopper File Storage and I/O

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    File Storage and IO File Storage and IO Disk Quota Change Request Form Hopper File Systems Hopper has 5 user file systems which provide different degrees of storage, performance...

  17. Energy transfer dynamics in trimers and aggregates of light-harvesting...

    Office of Scientific and Technical Information (OSTI)

    Energy transfer dynamics in trimers and aggregates of light-harvesting complex II probed by 2D electronic spectroscopy Citation Details In-Document Search Title: Energy transfer...

  18. 1999 CBECS Public Use Files

    Gasoline and Diesel Fuel Update (EIA)

    oil, propane, district steam or district hot water were used in the building. HOW ARE THE PUBLIC USE FILES USED? For each group of variables, there are two items: a layout file and...

  19. Spring 2014 Heat Transfer -2

    E-Print Network [OSTI]

    Virginia Tech

    Spring 2014 Heat Transfer - 2 A thin electronic chip is in the shape of a square wafer, b = 1 cm surface of the chip with a heat transfer coefficient of h = 100 W/m2 -K. Assume the chip has a uniform per side with a mass of m = 0.3 grams and specific heat of C = 103 J/kg-K. The chip is mounted

  20. EPA -- Amended Environmental Impact Statement Filing System Guidance...

    Office of Environmental Management (EM)

    Amended Environmental Impact Statement Filing System Guidance EPA -- Amended Environmental Impact Statement Filing System Guidance Amended Environmental Impact Statement Filing...

  1. TO: FILE MEMORANDUM

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1;TO: FILE FROM:FILE

  2. Electrochemical charge transfer at a metallic electrode: a simulation study

    E-Print Network [OSTI]

    Pounds, Michael A.

    2010-01-01

    Part I Electrochemical charge transfer at a metallic electrode: a simulation study The factors which affect the rate of heterogeneous electron transfer at a metallic electrode in the context of Marcus theory are ...

  3. High-precision transfer-printing and integration of vertically oriented semiconductor arrays for flexible

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    transfer printing, nanowires, flexible electronics, printable electronics, nanoscale devices ABSTRACT Flexible electronics utilizing single crystalline semiconductors typically require post-growth processes devices. High performance electronics on flexible substrates have been gaining attention from research

  4. Extending DIRAC File Management with Erasure-Coding for efficient storage

    E-Print Network [OSTI]

    Samuel Cadellin Skipsey; Paulin Todev; David Britton; David Crooks; Gareth Roy

    2015-10-30

    The state of the art in Grid style data management is to achieve increased resilience of data via multiple complete replicas of data files across multiple storage endpoints. While this is effective, it is not the most space-efficient approach to resilience, especially when the reliability of individual storage endpoints is sufficiently high that only a few will be inactive at any point in time. We report on work performed as part of GridPP\\cite{GridPP}, extending the Dirac File Catalogue and file management interface to allow the placement of erasure-coded files: each file distributed as N identically-sized chunks of data striped across a vector of storage endpoints, encoded such that any M chunks can be lost and the original file can be reconstructed. The tools developed are transparent to the user, and, as well as allowing up and downloading of data to Grid storage, also provide the possibility of parallelising access across all of the distributed chunks at once, improving data transfer and IO performance. We expect this approach to be of most interest to smaller VOs, who have tighter bounds on the storage available to them, but larger (WLCG) VOs may be interested as their total data increases during Run 2. We provide an analysis of the costs and benefits of the approach, along with future development and implementation plans in this area. In general, overheads for multiple file transfers provide the largest issue for competitiveness of this approach at present.

  5. Technology Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Booth Myers, Hao-Lin Chen, Glenn Meyer, Dino Ciarlo 1997 Sealed-Tube Electron Beam Guns for Material Processing Luis Zapata, Lloyd Hackel, Damon Matteo 1997 High Power, High...

  6. Characterization and Development of Advanced Heat Transfer Technologie...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Development of Advanced Heat Transfer Technologies Advanced Power Electronics and Electric Machines Compact, Light-Weight, Single-Phase, Liquid-Cooled Cold Plate...

  7. Cover photo credits: Clockwise from top left Dave Marci, file photo, file photo, Blair E. Witherington. Background file photo.

    E-Print Network [OSTI]

    #12;Cover photo credits: Clockwise from top left Dave Marci, file photo, file photo, Blair E. Witherington. Background file photo. #12;Deepwater Horizon Oil Spill Phase II Early Restoration Plan

  8. Cover photo credits: Clockwise from top left Dave Marci, file photo, file photo, Blair E. Witherington. Background file photo.

    E-Print Network [OSTI]

    #12;#12;Cover photo credits: Clockwise from top left Dave Marci, file photo, file photo, Blair E. Witherington. Background file photo. #12;Deepwater Horizon Oil Spill Phase II Early Restoration Plan

  9. Excitation energy transfer in the photosystem I

    SciTech Connect (OSTI)

    Webber, Andrew N

    2012-09-25

    Photosystem I is a multimeric pigment protein complex in plants, green alage and cyanobacteria that functions in series with Photosystem II to use light energy to oxidize water and reduce carbon dioxide. The Photosystem I core complex contains 96 chlorophyll a molecules and 22 carotenoids that are involved in light harvesting and electron transfer. In eucaryotes, PSI also has a peripheral light harvesting complex I (LHCI). The role of specific chlorophylls in excitation and electron transfer are still unresolved. In particular, the role of so-called bridging chlorophylls, located between the bulk antenna and the core electron transfer chain, in the transfer of excitation energy to the reaction center are unknown. During the past funding period, site directed mutagenesis has been used to create mutants that effect the physical properties of these key chlorophylls, and to explore how this alters the function of the photosystem. Studying these mutants using ultrafast absorption spectroscopy has led to a better understanding of the process by which excitation energy is transferred from the antenna chlorophylls to the electron transfer chain chlorophylls, and what the role of connecting chlorophylls and A_0 chlorophylls is in this process. We have also used these mutants to investigate whch of the central group of six chlorophylls are involved in the primary steps of charge separation and electron transfer.

  10. LONG TERM FILE MIGRATION - PART I: FILE REFERENCE PATTERNS

    E-Print Network [OSTI]

    Smith, A.J.

    2011-01-01

    death). or even and a renewal model two state Semi-MarkovThus model for those files displaying no trend, a renewal

  11. File:20121127144736519.pdf | Open Energy Information

    Open Energy Info (EERE)

    pixels, file size: 116 KB, MIME type: applicationpdf) File history Click on a datetime to view the file as it appeared at that time. DateTime Thumbnail Dimensions User...

  12. 1999 CBECS Public Use Files

    U.S. Energy Information Administration (EIA) Indexed Site

    only. Geographic identifiers and National Oceanic and Atmospheric Administration Weather Division identifiers are not included on any data files delivered to EIA. Geographic...

  13. Instructions to CBECS 1995 Microdata Files

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Files WHAT IS CBECS? Please Note: These microdata files, which contain building characteristics, energy consumption and expenditures, and energy end-use estimates replace the...

  14. Drinking Water and Groundwater Protection Division File Transfer Protocol

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstrumentsAreafor Geothermal Resources Rules - Idaho Jump

  15. Globus Online File Transfer - NERSC Tutorial - March 8, 2011

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUseful LinksGlassRegistration Welcome to

  16. "Covalent functionalization and electron-transfer properties...

    Office of Scientific and Technical Information (OSTI)

    to combine the outstanding stability and electrochemical properties of carbon-based structures with the unique properties of molecular structures for applications such as...

  17. ELECTRON TRANSFER AT SENSITIZED SEMICONDUCTOR ELECTRODES

    E-Print Network [OSTI]

    Spitler, Mark T.

    2010-01-01

    Pleskov. , Y. , Electrochemistry of SemiconductorsjPlenum54 Semiconductor electrochemistry Experimental apparatus forSemiconductor electrochemistry is a complex intersec'tion of

  18. Microsoft Word - Electron transfer.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OF PAGESpersonal MarchBoardJune 1, 2015 1Simulations

  19. MEMORANDUfl J: FILE DATE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V. Andolina:I.)p' : ,J: FILE

  20. TO: FILE FROM: SUBJECT:

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1;TO: FILE FROM: I .-

  1. MICROCOMP output file

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPA PublicLED1,400 Jobs |Inc.MEETINGO:\END\EPAC300.lc (file 1 of

  2. Other File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/O Streams forOrhan Kizilkaya, Ph.D. Title:Other File Systems

  3. Localized radio frequency communication using asynchronous transfer mode protocol

    DOE Patents [OSTI]

    Witzke, Edward L. (Edgewood, NM); Robertson, Perry J. (Albuquerque, NM); Pierson, Lyndon G. (Albuquerque, NM)

    2007-08-14

    A localized wireless communication system for communication between a plurality of circuit boards, and between electronic components on the circuit boards. Transceivers are located on each circuit board and electronic component. The transceivers communicate with one another over spread spectrum radio frequencies. An asynchronous transfer mode protocol controls communication flow with asynchronous transfer mode switches located on the circuit boards.

  4. Electronic Coupling Dependence of Ultrafast Interfacial Electron Transfer

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) | SciTech(Journal Article)at the Linac CoherentArticle) |

  5. Bioheat Transfer Valvano, page 1 Bioheat Transfer

    E-Print Network [OSTI]

    a technically challenging task. First, tissue heat transfer includes conduction, convection, radiation and by heat transfer due to blood flow near the probe. In vivo, the instrument measures effective thermal properties that are the combination of conductive and convective heat transfer. Thermal properties

  6. Reading File Bonneville Power Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reading File Bonneville Power Administration P.O. Box 3621 Portland, Oregon 97208-3621 POWER SERVICES In reply refer to: PG-5 Ms. Renata Kurschner Director, Generation Resource...

  7. Hopper /scratch file system slow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    count has been set back to 2 on Aug 5. The file stripe count of 1 triggered a bug with "cp -p" in a loop calling sytem function ioctl(). The bug has been fixed in new Lustre...

  8. Using pico to edit files

    E-Print Network [OSTI]

    Using pico to edit files. Someday you might want to learn emacs or vi. They are much more powerful editors than pico, but much more complicated, too. I have...

  9. Wireless Power Transfer

    ScienceCinema (OSTI)

    None

    2013-11-19

    Wireless Power Transfer is an innovative approach using magnetic resonance coupling of air core transformers designed for today's growing plug-in electric vehicle market. This technology can provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions. Plug-in Electric Vehicles (PEV) are burdened by the need for cable and plug charger, galvanic isolation of the on-board electronics, bulk and cost of this charger and the large energy storage system (ESS) packs needed. With a system where you have to physically plug in there are a number of occasions where the owner could very well forget to charge the vehicle. For stationary applications (like charging of a PHEV at home), ORNL's innovative wireless power transfer technology adds a convenience factor compared to actually plugging in which will mean that the vehicle will have a full charge every morning. Electric vehicle charging must be safe, compact and efficient in order to be convenient for customers. By reconfiguring the transformer and altering the resonance frequency, energy is transferred to the battery with lower energy losses and with fewer demands on the primary circuit by the rest of the transformer system. The ORNL discovery shows that sufficient power for the battery can be transferred from the primary to secondary circuits without significant energy losses if the operating frequency is set at 50% to 95% of the resonance frequency of the circuit. The electrical power is then transmitted to the chargeable battery, which is electrically coupled to the secondary circuit through the air core transformer. Some advantages include: Reduced energy losses during transfer of energy to the battery; A charge potential that is relatively unaffected by up to 25% misalignment of vehicle; and Other receiving components draw less power from the primary circuit. These advantages allow wireless power technology applications to expand at the workplace and beyond as the demand for EV rises. For vehicles that operate over a fixed route such as busses and shuttle vehicles, Wireless Power Transfer (WPT) means that a smaller battery pack can be used. In the traditional system, the battery pack is designed to accommodate the needs of the entire route or shift. With WPT the battery can be downsized because it can be charged when the vehicle stops on its route (a rental car shuttle bus, for example, can charge when it waits in the terminal and again when it waits at the rental car place. Thus the battery only needs enough charge to get to the next stop. This decrease in battery size means significant cost savings to electrify the vehicle. This technology enables efficient "opportunity charging stations" for predefined routes and planned stops reducing down time. Charging can occur in minutes. This improvement also eliminates the harmful emissions that occur in garages while buses are at idle during charging. In larger cities, dynamic charging offers an even greater impact utilizing existing infrastructure. As vehicles travel along busy freeways and interstate systems, wireless charging can occur while the vehicle is in motion. With this technology a vehicle essentially has unlimited electric range while using a relatively small battery pack. In-motion charging stations use vehicle sensors to alert the driver. Traveling at normal speeds, sensors establish in-motion charging. WPT transmit pads sequentially energize to the negotiated power level based on vehicle speed and its requested charging energy. Lower power when vehicle speed is slow and much higher power for faster moving vehicles. Vehicle to Infrastructure communications (V2I) coordinates WPT charging level according to on-board battery pack state-of-charge. V2I activates the roadway transmit pads placing them in standby mode and negotiates charging fee based on prevailing grid rate and vehicle energy demand. Dynamic charging would allow electricity to supply a very large fraction of the energy for the transportation sector and reduce greatly petroleum consump

  10. Wireless Power Transfer

    SciTech Connect (OSTI)

    2013-07-22

    Wireless Power Transfer is an innovative approach using magnetic resonance coupling of air core transformers designed for today's growing plug-in electric vehicle market. This technology can provide a convenient, safe and flexible means to charge electric vehicles under stationary and dynamic conditions. Plug-in Electric Vehicles (PEV) are burdened by the need for cable and plug charger, galvanic isolation of the on-board electronics, bulk and cost of this charger and the large energy storage system (ESS) packs needed. With a system where you have to physically plug in there are a number of occasions where the owner could very well forget to charge the vehicle. For stationary applications (like charging of a PHEV at home), ORNL's innovative wireless power transfer technology adds a convenience factor compared to actually plugging in which will mean that the vehicle will have a full charge every morning. Electric vehicle charging must be safe, compact and efficient in order to be convenient for customers. By reconfiguring the transformer and altering the resonance frequency, energy is transferred to the battery with lower energy losses and with fewer demands on the primary circuit by the rest of the transformer system. The ORNL discovery shows that sufficient power for the battery can be transferred from the primary to secondary circuits without significant energy losses if the operating frequency is set at 50% to 95% of the resonance frequency of the circuit. The electrical power is then transmitted to the chargeable battery, which is electrically coupled to the secondary circuit through the air core transformer. Some advantages include: Reduced energy losses during transfer of energy to the battery; A charge potential that is relatively unaffected by up to 25% misalignment of vehicle; and Other receiving components draw less power from the primary circuit. These advantages allow wireless power technology applications to expand at the workplace and beyond as the demand for EV rises. For vehicles that operate over a fixed route such as busses and shuttle vehicles, Wireless Power Transfer (WPT) means that a smaller battery pack can be used. In the traditional system, the battery pack is designed to accommodate the needs of the entire route or shift. With WPT the battery can be downsized because it can be charged when the vehicle stops on its route (a rental car shuttle bus, for example, can charge when it waits in the terminal and again when it waits at the rental car place. Thus the battery only needs enough charge to get to the next stop. This decrease in battery size means significant cost savings to electrify the vehicle. This technology enables efficient "opportunity charging stations" for predefined routes and planned stops reducing down time. Charging can occur in minutes. This improvement also eliminates the harmful emissions that occur in garages while buses are at idle during charging. In larger cities, dynamic charging offers an even greater impact utilizing existing infrastructure. As vehicles travel along busy freeways and interstate systems, wireless charging can occur while the vehicle is in motion. With this technology a vehicle essentially has unlimited electric range while using a relatively small battery pack. In-motion charging stations use vehicle sensors to alert the driver. Traveling at normal speeds, sensors establish in-motion charging. WPT transmit pads sequentially energize to the negotiated power level based on vehicle speed and its requested charging energy. Lower power when vehicle speed is slow and much higher power for faster moving vehicles. Vehicle to Infrastructure communications (V2I) coordinates WPT charging level according to on-board battery pack state-of-charge. V2I activates the roadway transmit pads placing them in standby mode and negotiates charging fee based on prevailing grid rate and vehicle energy demand. Dynamic charging would allow electricity to supply a very large fraction of the energy for the transportation sector and reduce greatly petroleum consump

  11. Inorganic semiconductor nanomaterials for flexible and stretchable bio-integrated electronics

    E-Print Network [OSTI]

    Rogers, John A.

    -integrated electronics; flexible electronics; semiconductor nanomaterials; stretchable electronics; transfer printing flexible/stretchable electronics, in which semiconductor nanomaterials serve as the active componentsREVIEW Inorganic semiconductor nanomaterials for flexible and stretchable bio

  12. Technology transfer at Lawrence Berkeley Laboratory

    SciTech Connect (OSTI)

    Johnson, D. (ed.)

    1992-09-01

    Lawrence Berkeley Laboratory (LBL) is dedicated to commercializing new technology in such fields as advanced materials, biotechnology, and electronics. Technology transfer between national laboratories and the industrial community is important in maintaining America's competitive edge. This document examines opportunities to establish working relationships with LBL. Streamlined methods for technology transfer are available with the aid of the Technology Transfer Department and the Patent Department at LBL. Research activities at LBL are concentrated in three major program areas: Energy Sciences, General Sciences, and Biosciences. Each program area consists of three research divisions. LBL welcomes both requests for information and proposals to conduct research.

  13. Technology transfer at Lawrence Berkeley Laboratory

    SciTech Connect (OSTI)

    Johnson, D. [ed.

    1992-09-01

    Lawrence Berkeley Laboratory (LBL) is dedicated to commercializing new technology in such fields as advanced materials, biotechnology, and electronics. Technology transfer between national laboratories and the industrial community is important in maintaining America`s competitive edge. This document examines opportunities to establish working relationships with LBL. Streamlined methods for technology transfer are available with the aid of the Technology Transfer Department and the Patent Department at LBL. Research activities at LBL are concentrated in three major program areas: Energy Sciences, General Sciences, and Biosciences. Each program area consists of three research divisions. LBL welcomes both requests for information and proposals to conduct research.

  14. Thermal Assessment of Naturally Cooled Electronic Enclosures With

    E-Print Network [OSTI]

    Bahrami, Majid

    and heat generation rates. Existing relationships for natural convection and radiation heat transfer of the radiation heat transfer is on the order of 50% of the total heat transfer for the tested enclosures. As such and radiation. [DOI: 10.1115/1.4007077] Keywords: electronic enclosures, conjugate heat transfer, fin spacing

  15. Extending DIRAC File Management with Erasure-Coding for efficient storage

    E-Print Network [OSTI]

    Skipsey, Samuel Cadellin; Britton, David; Crooks, David; Roy, Gareth

    2015-01-01

    The state of the art in Grid style data management is to achieve increased resilience of data via multiple complete replicas of data files across multiple storage endpoints. While this is effective, it is not the most space-efficient approach to resilience, especially when the reliability of individual storage endpoints is sufficiently high that only a few will be inactive at any point in time. We report on work performed as part of GridPP\\cite{GridPP}, extending the Dirac File Catalogue and file management interface to allow the placement of erasure-coded files: each file distributed as N identically-sized chunks of data striped across a vector of storage endpoints, encoded such that any M chunks can be lost and the original file can be reconstructed. The tools developed are transparent to the user, and, as well as allowing up and downloading of data to Grid storage, also provide the possibility of parallelising access across all of the distributed chunks at once, improving data transfer and IO performance. ...

  16. following an electron bunch for free electron laser

    SciTech Connect (OSTI)

    2012-01-01

    A video artist's ultra-slow-motion impression of an APEX-style electron gun firing a continuous train of electron bunches into a superconducting linear accelerator (in reality this would happen a million times a second). As they approach the speed of light the bunches contract, maintaining beam quality. After acceleration, the electron bunches are diverted into one or more undulators, the key components of free electron lasers. Oscillating back and forth in the changing magnetic field, they create beams of structured x-ray pulses. Before entering the experimental areas the electron bunches are diverted to a beam dump. (Animation created by Illumina Visual, http://www.illuminavisual.com/, for Lawrence Berkeley National Laboratory. Music for this excerpt, "Feeling Dark (Behind The Mask)" is by 7OOP3D http://ccmixter.org/files/7OOP3D/29126 and is licensed under a Creative Commons license: http://creativecommons.org/licenses/by-nc/3.0/)

  17. CMSC 412 Project #5 File System

    E-Print Network [OSTI]

    Hollingsworth, Jeffrey K.

    will be emailed to you). CFS - Chameleon FileSystem The main part of this project is to develop a new filesystem. The second IDE disk's image is called diskd.img. CFS will provide a filesystem that includes multiple. Then you can mount the CFS file system on drive 1 onto /d, for instance. VFS and file operations Since

  18. Wireless adiabatic power transfer

    SciTech Connect (OSTI)

    Rangelov, A.A., E-mail: rangelov@phys.uni-sofia.bg [Department of Physics, Sofia University, James Bourchier 5 blvd., 1164 Sofia (Bulgaria); Suchowski, H.; Silberberg, Y. [Department of Physics of Complex System, Weizmann Institute of Science, Rehovot 76100 (Israel); Vitanov, N.V. [Department of Physics, Sofia University, James Bourchier 5 blvd., 1164 Sofia (Bulgaria)

    2011-03-15

    Research Highlights: > Efficient and robust mid-range wireless energy transfer between two coils. > The adiabatic energy transfer is analogous to adiabatic passage in quantum optics. > Wireless energy transfer is insensitive to any resonant constraints. > Wireless energy transfer is insensitive to noise in the neighborhood of the coils. - Abstract: We propose a technique for efficient mid-range wireless power transfer between two coils, by adapting the process of adiabatic passage for a coherently driven two-state quantum system to the realm of wireless energy transfer. The proposed technique is shown to be robust to noise, resonant constraints, and other interferences that exist in the neighborhood of the coils.

  19. HEAT TRANSFER FLUIDS

    E-Print Network [OSTI]

    Lenert, Andrej

    2012-01-01

    The choice of heat transfer fluids has significant effects on the performance, cost, and reliability of solar thermal systems. In this chapter, we evaluate existing heat transfer fluids such as oils and molten salts based ...

  20. Transfer and characterization of silicon nanomembrane based photonic devices on flexible polyimide substrate

    E-Print Network [OSTI]

    Texas at Austin, University of

    Transfer and characterization of silicon nanomembrane based photonic devices on flexible polyimide nanomembrane based photonic devices on a Kapton polyimide flexible substrate. Compared with electronic devices

  1. Accessing Your EM Data Through the File Server A major problem of putting flash drives directly into the microscope

    E-Print Network [OSTI]

    Baker, Timothy S.

    into the microscope computer is the threat of viruses. A particularly malevolent virus could shut the microscope down including your home computer. Here are the steps for transferring and accessing your files. 1. On the microscope computer go to the Desktop and then to: My Computer/Tools/M ap Network Drive. 2. In the Drive: box

  2. Heat Transfer Guest Editorial

    E-Print Network [OSTI]

    Kandlikar, Satish

    Journal of Heat Transfer Guest Editorial We are indeed delighted in bringing out this special issue was showcased in diverse areas such as traditional heat and mass transfer, lab-on-chip, sensors, biomedical applica- tions, micromixers, fuel cells, and microdevices. Selected papers in the field of heat transfer

  3. A Metadata-Rich File System

    SciTech Connect (OSTI)

    Ames, S; Gokhale, M B; Maltzahn, C

    2009-01-07

    Despite continual improvements in the performance and reliability of large scale file systems, the management of file system metadata has changed little in the past decade. The mismatch between the size and complexity of large scale data stores and their ability to organize and query their metadata has led to a de facto standard in which raw data is stored in traditional file systems, while related, application-specific metadata is stored in relational databases. This separation of data and metadata requires considerable effort to maintain consistency and can result in complex, slow, and inflexible system operation. To address these problems, we have developed the Quasar File System (QFS), a metadata-rich file system in which files, metadata, and file relationships are all first class objects. In contrast to hierarchical file systems and relational databases, QFS defines a graph data model composed of files and their relationships. QFS includes Quasar, an XPATH-extended query language for searching the file system. Results from our QFS prototype show the effectiveness of this approach. Compared to the defacto standard, the QFS prototype shows superior ingest performance and comparable query performance on user metadata-intensive operations and superior performance on normal file metadata operations.

  4. Electron Paramagnetic Resonance Studies of Pi-Cation Radical Tetrapyrroles

    E-Print Network [OSTI]

    Hondros, Christopher John

    2014-01-01

    arise because the thermal-activation behavior of the processIn this respect, the thermal-activation behavior exhibiteddiminish the thermal activation of hole/electron-transfer.

  5. Heat transfer system

    DOE Patents [OSTI]

    Not Available

    1980-03-07

    A heat transfer system for a nuclear reactor is described. Heat transfer is accomplished within a sealed vapor chamber which is substantially evacuated prior to use. A heat transfer medium, which is liquid at the design operating temperatures, transfers heat from tubes interposed in the reactor primary loop to spaced tubes connected to a steam line for power generation purposes. Heat transfer is accomplished by a two-phase liquid-vapor-liquid process as used in heat pipes. Condensible gases are removed from the vapor chamber through a vertical extension in open communication with the chamber interior.

  6. Heat transfer system

    DOE Patents [OSTI]

    McGuire, Joseph C. (Richland, WA)

    1982-01-01

    A heat transfer system for a nuclear reactor. Heat transfer is accomplished within a sealed vapor chamber which is substantially evacuated prior to use. A heat transfer medium, which is liquid at the design operating temperatures, transfers heat from tubes interposed in the reactor primary loop to spaced tubes connected to a steam line for power generation purposes. Heat transfer is accomplished by a two-phase liquid-vapor-liquid process as used in heat pipes. Condensible gases are removed from the vapor chamber through a vertical extension in open communication with the chamber interior.

  7. Small file aggregation in a parallel computing system

    DOE Patents [OSTI]

    Faibish, Sorin; Bent, John M.; Tzelnic, Percy; Grider, Gary; Zhang, Jingwang

    2014-09-02

    Techniques are provided for small file aggregation in a parallel computing system. An exemplary method for storing a plurality of files generated by a plurality of processes in a parallel computing system comprises aggregating the plurality of files into a single aggregated file; and generating metadata for the single aggregated file. The metadata comprises an offset and a length of each of the plurality of files in the single aggregated file. The metadata can be used to unpack one or more of the files from the single aggregated file.

  8. GDCT Initialization File [gdct.ini] Format Specification Guide

    E-Print Network [OSTI]

    Rosebrugh, Robert

    GDCT Initialization File [gdct.ini] Format Specification Guide Written By: Jeremy Bradbury June 22, 2000 Below is the layout of the gdct.ini file. It is important to note the following: If the gdct.ini to represent that a file does not exist under the "Recent Files" section of the gdct.ini file. [Internal

  9. Electron radiography

    DOE Patents [OSTI]

    Merrill, Frank E.; Morris, Christopher

    2005-05-17

    A system capable of performing radiography using a beam of electrons. Diffuser means receive a beam of electrons and diffuse the electrons before they enter first matching quadrupoles where the diffused electrons are focused prior to the diffused electrons entering an object. First imaging quadrupoles receive the focused diffused electrons after the focused diffused electrons have been scattered by the object for focusing the scattered electrons. Collimator means receive the scattered electrons and remove scattered electrons that have scattered to large angles. Second imaging quadrupoles receive the collimated scattered electrons and refocus the collimated scattered electrons and map the focused collimated scattered electrons to transverse locations on an image plane representative of the electrons' positions in the object.

  10. Saving Output to a File (Using Codeblocks or Dev-C++) Saving Your Output to a File

    E-Print Network [OSTI]

    Sokol, Dina

    Saving Output to a File (Using Codeblocks or Dev-C++) Saving Your Output to a File To save | New | Source File. d. In the new window, right-click and select Paste. e. Then select "File | Save as" to save and name the file. i. In the window that pops up, the bottom fill-in box is labelled "Save as type

  11. 01-06-2000 - Use of Non-approved Electronic Equipment in a Class...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6-2000 - Use of Non-approved Electronic Equipment in a Class I, Division 2 Hazardous Location Document Number: NA Effective Date: 012000 File (public): 01-06-2000yellow...

  12. Fuel transfer system

    DOE Patents [OSTI]

    Townsend, H.E.; Barbanti, G.

    1994-03-01

    A nuclear fuel bundle fuel transfer system includes a transfer pool containing water at a level above a reactor core. A fuel transfer machine therein includes a carriage disposed in the transfer pool and under the water for transporting fuel bundles. The carriage is selectively movable through the water in the transfer pool and individual fuel bundles are carried vertically in the carriage. In a preferred embodiment, a first movable bridge is disposed over an upper pool containing the reactor core, and a second movable bridge is disposed over a fuel storage pool, with the transfer pool being disposed therebetween. A fuel bundle may be moved by the first bridge from the reactor core and loaded into the carriage which transports the fuel bundle to the second bridge which picks up the fuel bundle and carries it to the fuel storage pool. 6 figures.

  13. Fuel transfer system

    DOE Patents [OSTI]

    Townsend, Harold E. (Campbell, CA); Barbanti, Giancarlo (Cupertino, CA)

    1994-01-01

    A nuclear fuel bundle fuel transfer system includes a transfer pool containing water at a level above a reactor core. A fuel transfer machine therein includes a carriage disposed in the transfer pool and under the water for transporting fuel bundles. The carriage is selectively movable through the water in the transfer pool and individual fuel bundles are carried vertically in the carriage. In a preferred embodiment, a first movable bridge is disposed over an upper pool containing the reactor core, and a second movable bridge is disposed over a fuel storage pool, with the transfer pool being disposed therebetween. A fuel bundle may be moved by the first bridge from the reactor core and loaded into the carriage which transports the fuel bundle to the second bridge which picks up the fuel bundle and carries it to the fuel storage pool.

  14. EPA to Require Electronic Filing of EISs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatementof EnergyQuality'Lean'1401of Energy EPA andto

  15. Proton transfer in nucleobases is mediated by water

    SciTech Connect (OSTI)

    Khistyaev, Kirill; Golan, Amir; Bravaya, Ksenia B.; Orms, Natalie; Krylov, Anna I.; Ahmed, Musahid

    2013-04-29

    Water plays a central role in chemistry and biology by mediating the interactions between molecules, altering energy levels of solvated species, modifying potential energy proles along reaction coordinates, and facilitating ecient proton transport through ion channels and interfaces. This study investigates proton transfer in a model system comprising dry and microhydrated clusters of nucleobases. With mass spectrometry and tunable vacuum ultraviolet synchrotron radiation, we show that water shuts down ionization-induced proton transfer between nucleobases, which is very ecient in dry clusters. Instead, a new pathway opens up in which protonated nucleo bases are generated by proton transfer from the ionized water molecule and elimination of a hydroxyl radical. Electronic structure calculations reveal that the shape of the potential energy prole along the proton transfer coordinate depends strongly on the character of the molecular orbital from which the electron is removed, i.e., the proton transfer from water to nucleobases is barrierless when an ionized state localized on water is accessed. The computed energetics of proton transfer is in excellent agreement with the experimental appearance energies. Possible adiabatic passage on the ground electronic state of the ionized system, while energetically accessible at lower energies, is not ecient. Thus, proton transfer is controlled electronically, by the character of the ionized state, rather than statistically, by simple energy considerations.

  16. Facility Survey & Transfer

    Broader source: Energy.gov [DOE]

    As DOE facilities become excess, many that are radioactively and/or chemically contaminated will become candidate for transfer to DOE-EM for deactivation and decommissioning.

  17. Electron Irradiation Induced Changes of the Electrical Transport Properties of Graphene

    E-Print Network [OSTI]

    Woo, Sung Oh

    2014-08-06

    This research investigates the effect of electron irradiation on transport properties in graphene Field Effect Transistor (FET) devices. Upon irradiation, graphene is doped with electrons and adsorbs molecules by transfer of accumulated electrons...

  18. Proton transfer from the bulk to the bound ubiquinone QB of the reaction center in

    E-Print Network [OSTI]

    Steinhoff, Heinz-Jrgen

    Proton transfer from the bulk to the bound ubiquinone QB of the reaction center in chromatophores, 1999) The mechanism of proton transfer from the bulk into the mem- brane protein interior was studied is accompanied by proton trapping. We used kinetic spec- troscopy to measure (i) the electron transfer to QB (at

  19. File:CDPHE Industrial Individual Wastewater Discharge Permit...

    Open Energy Info (EERE)

    Help Apps Datasets Community Login | Sign Up Search File Edit History File:CDPHE Industrial Individual Wastewater Discharge Permit Application.pdf Jump to: navigation, search...

  20. Department of Energy Files Motion to Withdraw Yucca Mountain...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Files Motion to Withdraw Yucca Mountain License Application Department of Energy Files Motion to Withdraw Yucca Mountain License Application March 3, 2010 -...

  1. NERSC Online Training May 3: Navigating NERSC File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Online Training May 3: Navigating NERSC File Systems NERSC Online Training May 3: Navigating NERSC File Systems April 26, 2011 by Richard Gerber A NERSC training event, "Navigating...

  2. Wireless adiabatic power transfer

    E-Print Network [OSTI]

    A. A. Rangelov; H. Suchowski; Y. Silberberg; N. V. Vitanov

    2010-10-30

    We propose a technique for efficient mid-range wireless power transfer between two coils, by adapting the process of adiabatic passage for a coherently driven two-state quantum system to the realm of wireless energy transfer. The proposed technique is shown to be robust to noise, resonant constraints, and other interferences that exist in the neighborhood of the coils.

  3. Reprint of: Regulation of photosynthetic electron transport , Jean-David Rochaix

    E-Print Network [OSTI]

    Halazonetis, Thanos

    , the two light reactions operate in series whereby electrons extracted from water by PSII are transferred Keywords: Electron transport Linear electron ow Cyclic electron ow Photosystem II Photosystem I Light-harvesting with the oxidation of water followed by electron ow along the electron transport chain and concomitant pumping

  4. 1 Files and Databases mass storage

    E-Print Network [OSTI]

    Verschelde, Jan

    Outline 1 Files and Databases mass storage hash functions 2 Dictionaries logical key values nested Jan Verschelde, 28 January 2015 Intro to Computer Science (MCS 260) mass storage and dictionaries L-7 28 January 2015 1 / 32 #12;mass storage dictionaries in Python 1 Files and Databases mass storage

  5. Electroweak nuclear response at moderate momentum transfer

    SciTech Connect (OSTI)

    Ankowski, Artur M.; Benhar, Omar

    2011-05-15

    We discuss the convergence of the expansion of the nuclear electroweak current in powers of |k|/M, where M is the nucleon mass and k denotes either the momentum transfer or the momentum of the struck nucleon. We have computed the electron and neutrino scattering cross sections off uniform nuclear matter at equilibrium density using correlated wave functions and the cluster expansion formalism. The results of our work suggest that the proposed approach provides accurate estimates of the measured electron scattering cross sections. On the other hand, the description of the current based on the widely used leading-order approximation does not appear to be adequate, even at momentum transfer as low as 300 MeV.

  6. Technology transfer 1994

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    This document, Technology Transfer 94, is intended to communicate that there are many opportunities available to US industry and academic institutions to work with DOE and its laboratories and facilities in the vital activity of improving technology transfer to meet national needs. It has seven major sections: Introduction, Technology Transfer Activities, Access to Laboratories and Facilities, Laboratories and Facilities, DOE Office, Technologies, and an Index. Technology Transfer Activities highlights DOE`s recent developments in technology transfer and describes plans for the future. Access to Laboratories and Facilities describes the many avenues for cooperative interaction between DOE laboratories or facilities and industry, academia, and other government agencies. Laboratories and Facilities profiles the DOE laboratories and facilities involved in technology transfer and presents information on their missions, programs, expertise, facilities, and equipment, along with data on whom to contact for additional information on technology transfer. DOE Offices summarizes the major research and development programs within DOE. It also contains information on how to access DOE scientific and technical information. Technologies provides descriptions of some of the new technologies developed at DOE laboratories and facilities.

  7. Advanced Heat Transfer Technologies Increase Vehicle Performance and Reliability; The Spectrum of Clean Energy Innovation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-06-01

    Fact sheet describes NREL's work with heat transfer technologies to keep hybrid electric and all-electric vehicle power electronic components cool.

  8. TO: FILE FROM: I SUBJECT:

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1;TO: FILE FROM: I .-

  9. TO: FILE MEMORANDUM ALTERNATE NAME:

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1;TO: FILE

  10. Index of /radsafe/files

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACT EVALUATION PLAN FOR THE SITE-218in aradsafe/files [ICO] Name Last

  11. Anomalous electron-ion energy coupling in electron drift wave turbulence

    E-Print Network [OSTI]

    Zhao, Lei

    and thermal diffusivity will be determined by the colli- sionless energy transfer processesthermal energy will not be lost only via electron transport processes.thermal energy will not only be lost via turbu- lent transport processes[

  12. HEAT AND MOISTURE TRANSFER THROUGH CLOTHING

    E-Print Network [OSTI]

    Voelker, Conrad; Hoffmann, Sabine; Kornadt, Oliver; Arens, Edward; Zhang, Hui; Huizenga, Charlie

    2009-01-01

    R. C. Eberhart (ed), Heat transfer in medicine and biology.between convective heat transfer and mass transferConvective and radiative heat transfer coefficients for

  13. Heat and moisture transfer through clothing

    E-Print Network [OSTI]

    Voelker, Conrad; Hoffmann, Sabine; Kornadt, Oliver; Arens, Edward; Zhang, Hui; Huizenga, Charlie

    2009-01-01

    R. C. Eberhart (ed), Heat transfer in medicine and biology.Convective and radiative heat transfer coefficients forbetween convective heat transfer and mass transfer

  14. Ames Lab 101: Technology Transfer

    ScienceCinema (OSTI)

    Covey, Debra

    2012-08-29

    Ames Laboratory Associate Laboratory Director, Sponsored Research Administration, Debra Covey discusses technology transfer. Covey also discusses Ames Laboratory's most successful transfer, lead-free solder.

  15. Repairable File and Storage Systems A Dissertation Presented

    E-Print Network [OSTI]

    Chiueh, Tzi-cker

    Repairable File and Storage Systems A Dissertation Presented by Ningning Zhu to The Graduate School of the Dissertation Repairable File and Storage System by Ningning Zhu Doctor of Philosophy in Computer Science Stony stream file/storage system. Repairable file/storage system needs to perform two tasks. First it has

  16. Investigation of electrons interaction in a superconductor

    E-Print Network [OSTI]

    Iogann Tolbatov

    2009-10-21

    Investigating the interaction of electrons in a superconductor by means of a method of solitary waves of Korteweg - de Vries, we refute the claim of absence of "Cooper pairs" in a superconductor. We also indicate that the nondissipative transfer of energy in the superconductor is possible only with the help of a pair of electrons.

  17. Multiscale photosynthetic exciton transfer

    E-Print Network [OSTI]

    A. K. Ringsmuth; G. J. Milburn; T. M. Stace

    2012-06-14

    Photosynthetic light harvesting provides a natural blueprint for bioengineered and biomimetic solar energy and light detection technologies. Recent evidence suggests some individual light harvesting protein complexes (LHCs) and LHC subunits efficiently transfer excitons towards chemical reaction centers (RCs) via an interplay between excitonic quantum coherence, resonant protein vibrations, and thermal decoherence. The role of coherence in vivo is unclear however, where excitons are transferred through multi-LHC/RC aggregates over distances typically large compared with intra-LHC scales. Here we assess the possibility of long-range coherent transfer in a simple chromophore network with disordered site and transfer coupling energies. Through renormalization we find that, surprisingly, decoherence is diminished at larger scales, and long-range coherence is facilitated by chromophoric clustering. Conversely, static disorder in the site energies grows with length scale, forcing localization. Our results suggest sustained coherent exciton transfer may be possible over distances large compared with nearest-neighbour (n-n) chromophore separations, at physiological temperatures, in a clustered network with small static disorder. This may support findings suggesting long-range coherence in algal chloroplasts, and provides a framework for engineering large chromophore or quantum dot high-temperature exciton transfer networks.

  18. Electronic Coupling Dependence of Ultrafast Interfacial Electron...

    Office of Scientific and Technical Information (OSTI)

    (BES) (SC-22) Country of Publication: United States Language: English Subject: 14 SOLAR ENERGY Word Cloud More Like This Full Text preview image File size NAView Full Text...

  19. Pattern transfer printing by kinetic control of adhesion to an elastomeric stamp

    DOE Patents [OSTI]

    Nuzzo, Ralph G. (Champaign, IL); Rogers, John A. (Champaign, IL); Menard, Etienne (Urbana, IL); Lee, Keon Jae (Tokyo, JP); Khang, Dahl-Young (Urbana, IL); Sun, Yugang (Champaign, IL); Meitl, Matthew (Champaign, IL); Zhu, Zhengtao (Urbana, IL)

    2011-05-17

    The present invention provides methods, systems and system components for transferring, assembling and integrating features and arrays of features having selected nanosized and/or microsized physical dimensions, shapes and spatial orientations. Methods of the present invention utilize principles of `soft adhesion` to guide the transfer, assembly and/or integration of features, such as printable semiconductor elements or other components of electronic devices. Methods of the present invention are useful for transferring features from a donor substrate to the transfer surface of an elastomeric transfer device and, optionally, from the transfer surface of an elastomeric transfer device to the receiving surface of a receiving substrate. The present methods and systems provide highly efficient, registered transfer of features and arrays of features, such as printable semiconductor element, in a concerted manner that maintains the relative spatial orientations of transferred features.

  20. Ponderomotive phase plate for transmission electron microscopes

    DOE Patents [OSTI]

    Reed, Bryan W. (Livermore, CA)

    2012-07-10

    A ponderomotive phase plate system and method for controllably producing highly tunable phase contrast transfer functions in a transmission electron microscope (TEM) for high resolution and biological phase contrast imaging. The system and method includes a laser source and a beam transport system to produce a focused laser crossover as a phase plate, so that a ponderomotive potential of the focused laser crossover produces a scattering-angle-dependent phase shift in the electrons of the post-sample electron beam corresponding to a desired phase contrast transfer function.

  1. Policy on Cost Transfer Policy on Cost Transfer

    E-Print Network [OSTI]

    Sridhar, Srinivas

    Policy on Cost Transfer 12/22/2014 Policy on Cost Transfer I. Purpose and Scope The University has posting of a cost to the general ledger, initiated by payroll charges, purchase orders or check requests (and the purchasing card). Cost Transfer means any subsequent transfer of the original charge

  2. Proceedings of Heat Transfer 2003: ASME Summer Heat Transfer Conference

    E-Print Network [OSTI]

    Kandlikar, Satish

    Proceedings of Heat Transfer 2003: ASME Summer Heat Transfer Conference Las Vegas, Nevada, USA July 21-23, 2003 HT2003-47449 HEAT TRANSFER FROM A MOVING AND EVAPORATING MENISCUS ON A HEATED SURFACE meniscus with complete evaporation of water without any meniscus break-up. The experimental heat transfer

  3. Interoperability format translation and transformation between IFC architectural design file and simulation file formats

    DOE Patents [OSTI]

    Chao, Tian-Jy; Kim, Younghun

    2015-01-06

    Automatically translating a building architecture file format (Industry Foundation Class) to a simulation file, in one aspect, may extract data and metadata used by a target simulation tool from a building architecture file. Interoperability data objects may be created and the extracted data is stored in the interoperability data objects. A model translation procedure may be prepared to identify a mapping from a Model View Definition to a translation and transformation function. The extracted data may be transformed using the data stored in the interoperability data objects, an input Model View Definition template, and the translation and transformation function to convert the extracted data to correct geometric values needed for a target simulation file format used by the target simulation tool. The simulation file in the target simulation file format may be generated.

  4. Interoperability format translation and transformation between IFC architectural design file and simulation file formats

    DOE Patents [OSTI]

    Chao, Tian-Jy; Kim, Younghun

    2015-02-03

    Automatically translating a building architecture file format (Industry Foundation Class) to a simulation file, in one aspect, may extract data and metadata used by a target simulation tool from a building architecture file. Interoperability data objects may be created and the extracted data is stored in the interoperability data objects. A model translation procedure may be prepared to identify a mapping from a Model View Definition to a translation and transformation function. The extracted data may be transformed using the data stored in the interoperability data objects, an input Model View Definition template, and the translation and transformation function to convert the extracted data to correct geometric values needed for a target simulation file format used by the target simulation tool. The simulation file in the target simulation file format may be generated.

  5. 2012 ELECTRON DONOR-ACCEPTOR INTERACTIONS GORDON RESEARCH CONFERENCE, AUGUST 5-10, 2012

    SciTech Connect (OSTI)

    McCusker, James

    2012-08-10

    The upcoming incarnation of the Gordon Research Conference on Electron Donor Acceptor Interactions will feature sessions on classic topics including proton-coupled electron transfer, dye-sensitized solar cells, and biological electron transfer, as well as emerging areas such as quantum coherence effects in donor-acceptor interactions, spintronics, and the application of donor-acceptor interactions in chemical synthesis.

  6. Accelerating the transfer in Technology Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation DataStreamsTotalproposalsAboutAccelerating the transfer in

  7. File:Apschem.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New Pages Recent Changes AllApschem.pdf Jump to: navigation, search File File history File

  8. Thermalisation of electrons in a stellar atmosphere

    E-Print Network [OSTI]

    L. Chevallier

    2006-01-23

    We are interested in electrons kinetics in a stellar atmosphere to validate or invalidate the usually accepted hypothesis of thermalisation of electrons. For this purpose, we calculate the velocity distribution function of electrons by solving the kinetic equation of these particles together with the equations of radiative transfer and statistical equilibrium. We note that this distribution can deviate strongly from a Maxwell-Boltzmann distribution if non-LTE effects are important. Some results and astrophysical consequences are examined.

  9. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall toUranium4,(Million CubicErin Boedecker,

  10. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall toUranium4,(Million CubicErin Boedecker,Coke

  11. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall toUranium4,(Million CubicErin

  12. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall toUranium4,(Million

  13. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall

  14. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall3,"Alabama","Alabama","Electric Power

  15. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall3,"Alabama","Alabama","Electric

  16. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to

  17. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall to $3.43 by September1 7 6DEPARTMENTMonthlyMay-15

  18. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall to $3.43 by September1 7 6DEPARTMENTMonthlyMay-15Electric Power

  19. FILE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers CoMadison -T:..) ".. _,;

  20. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 RelativeSoutheast RegionFuture Production1002 2.

  1. File

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 RelativeSoutheast RegionFuture Production1002

  2. TECHNOLOGY TRANSFER: PROBLEMS AND PROSPECTS

    E-Print Network [OSTI]

    TECHNOLOGY TRANSFER: PROBLEMS AND PROSPECTS Jesse w. Fussell Department of Defense 9800 Savage Road of technology transfer in this technical area in the past, to forecast prospects for technology transfer in the future, and to suggest some ideas for stimulating the process. 2. TECHNOLOGY TRANSFER PROBLEMS Many

  3. Instructions to CBECS 1992 Microdata Files

    U.S. Energy Information Administration (EIA) Indexed Site

    and dBASE (CE92F01D.DBF) formats. These files contain the 1992 CBECS basic data including building characteristics, energy consumption and expenditures, and temperature data. The...

  4. Optimizing Native Files in Energy.gov

    Broader source: Energy.gov [DOE]

    For native files in Energy.gov, following these best practices will result in better search results in commercial search engines. To learn how to optimize PDFs, see the PDF requirements.

  5. Technology transfer issue

    SciTech Connect (OSTI)

    Jacobson, C.

    1982-05-31

    Testimony by Lawrence J. Brady, Commerce Assistant Secretary for Trade Administration, at Congressional hearings on the national security issues of technology transfers to the Soviet Union identified steps the US needs to take to deal effectively with the problem. These steps include an understanding of how the Soviet Union has and will benefit militarily by acquiring Western technology and efforts to work with other countries, counterintelligence agencies, and industries to stem the flow of technological information. Brady outlined changes in technology development that complicate the enforcement of transfer rules, and emphasized the importance of a close relationship between the business community and the Commerce Department. (DCK)

  6. Collective operations in a file system based execution model

    DOE Patents [OSTI]

    Shinde, Pravin; Van Hensbergen, Eric

    2013-02-12

    A mechanism is provided for group communications using a MULTI-PIPE synthetic file system. A master application creates a multi-pipe synthetic file in the MULTI-PIPE synthetic file system, the master application indicating a multi-pipe operation to be performed. The master application then writes a header-control block of the multi-pipe synthetic file specifying at least one of a multi-pipe synthetic file system name, a message type, a message size, a specific destination, or a specification of the multi-pipe operation. Any other application participating in the group communications then opens the same multi-pipe synthetic file. A MULTI-PIPE file system module then implements the multi-pipe operation as identified by the master application. The master application and the other applications then either read or write operation messages to the multi-pipe synthetic file and the MULTI-PIPE synthetic file system module performs appropriate actions.

  7. Collective operations in a file system based execution model

    DOE Patents [OSTI]

    Shinde, Pravin; Van Hensbergen, Eric

    2013-02-19

    A mechanism is provided for group communications using a MULTI-PIPE synthetic file system. A master application creates a multi-pipe synthetic file in the MULTI-PIPE synthetic file system, the master application indicating a multi-pipe operation to be performed. The master application then writes a header-control block of the multi-pipe synthetic file specifying at least one of a multi-pipe synthetic file system name, a message type, a message size, a specific destination, or a specification of the multi-pipe operation. Any other application participating in the group communications then opens the same multi-pipe synthetic file. A MULTI-PIPE file system module then implements the multi-pipe operation as identified by the master application. The master application and the other applications then either read or write operation messages to the multi-pipe synthetic file and the MULTI-PIPE synthetic file system module performs appropriate actions.

  8. Ultrafast Electron Dynamics at Alkali/Ice Structures

    E-Print Network [OSTI]

    Wolf, Martin

    trapping sites, i.e. at local potential minima, are formed. Photoinjection of excess electrons into these alkali-ion covered amorphous ice layers, results in the trapping of a solvated electron at an alkali, i.e. pump-probe time delay, the electron transfer is mediated by tunneling through a potential

  9. File:06COAExtraLegalVehiclePermittingProcess.pdf | Open Energy...

    Open Energy Info (EERE)

    traLegalVehiclePermittingProcess.pdf Jump to: navigation, search File File history File usage Metadata File:06COAExtraLegalVehiclePermittingProcess.pdf Size of this preview: 463 ...

  10. Electronic structure and transition energies in polymer-fullerene bulk heterojunctions

    E-Print Network [OSTI]

    2014-01-01

    Electronic Structure and Transition Energies in Polymer?the HOMO and LUMO energy levels and transition energies haveand charge-transfer transition energies. The interface band

  11. Three Dimensional Radiative Transfer

    E-Print Network [OSTI]

    Tom Abel

    2000-05-09

    Radiative Transfer (RT) effects play a crucial role in the thermal history of the intergalactic medium. Here I discuss recent advances in the development of numerical methods that introduce RT to cosmological hydrodynamics. These methods can also readily be applied to time dependent problems on interstellar and galactic scales.

  12. DATABASE DESIGN, Gio Wiederhold CHAPTER 8, file CHAP8.tex This file is c

    E-Print Network [OSTI]

    Wiederhold, Gio

    To a Mouse, 1787 The previous chapter described models of databases. The structure of the database the database model, but do not make it directly available to a database management system. In this chapter we404 !le DATABASE DESIGN, Gio Wiederhold CHAPTER 8, file CHAP8.tex This file is c fl1977 by Mc

  13. Introduction Container Library Container Tools FUSE Container File System Evaluation Container Library and FUSE Container File

    E-Print Network [OSTI]

    The library was completely overhauled It now provides consistently named functions and data types The commentsIntroduction Container Library Container Tools FUSE Container File System Evaluation Container Library and FUSE Container File System Softwarepraktikum fur Fortgeschrittene Michael Kuhn Parallele und

  14. Charge Transfer Properties Through Graphene Layers in Gas Detectors

    E-Print Network [OSTI]

    Thuiner, P; Jackman, R B; Mller, H; Nguyen, T T; Oliveri, E; Pfeiffer, D; Resnati, F; Ropelewski, L; Smith, J A; van Stenis, M; Veenhof, R

    2015-01-01

    Graphene is a single layer of carbon atoms arranged in a honeycomb lattice with remarkable mechanical, electrical and optical properties. For the first time graphene layers suspended on copper meshes were installed into a gas detector equipped with a gaseous electron multiplier. Measurements of low energy electron and ion transfer through graphene were conducted. In this paper we describe the sample preparation for suspended graphene layers, the testing procedures and we discuss the preliminary results followed by a prospect of further applications.

  15. Charge Transfer Properties Through Graphene Layers in Gas Detectors

    E-Print Network [OSTI]

    P. Thuiner; R. Hall-Wilton; R. B. Jackman; H. Mller; T. T. Nguyen; E. Oliveri; D. Pfeiffer; F. Resnati; L. Ropelewski; J. A. Smith; M. van Stenis; R. Veenhof

    2015-03-23

    Graphene is a single layer of carbon atoms arranged in a honeycomb lattice with remarkable mechanical, electrical and optical properties. For the first time graphene layers suspended on copper meshes were installed into a gas detector equipped with a gaseous electron multiplier. Measurements of low energy electron and ion transfer through graphene were conducted. In this paper we describe the sample preparation for suspended graphene layers, the testing procedures and we discuss the preliminary results followed by a prospect of further applications.

  16. Generation of anomalously energetic suprathermal electrons by an electron beam interacting with a nonuniform plasma

    E-Print Network [OSTI]

    Sydorenko, D; Chen, L; Ventzek, P L G

    2015-01-01

    Generation of anomalously energetic suprathermal electrons was observed in simulation of a high- voltage dc discharge with electron emission from the cathode. An electron beam produced by the emission interacts with the nonuniform plasma in the discharge via a two-stream instability. Efficient energy transfer from the beam to the plasma electrons is ensured by the plasma nonuniformity. The electron beam excites plasma waves whose wavelength and phase speed gradually decrease towards anode. The short waves near the anode accelerate plasma bulk electrons to suprathermal energies. The sheath near the anode reflects some of the accelerated electrons back into the plasma. These electrons travel through the plasma, reflect near the cathode, and enter the accelerating area again but with a higher energy than before. Such particles are accelerated to energies much higher than after the first acceleration. This mechanism plays a role in explaining earlier experimental observations of energetic suprathermal electrons i...

  17. Cost Transfer Procedures How And When To Make Cost Transfers

    E-Print Network [OSTI]

    Hammack, Richard

    Cost Transfer Procedures How And When To Make Cost Transfers Effective February 9, 2003, cost elsewhere. Federal regulations require additional documentation to support cost transfers to sponsored program indexes. Costs may not be shifted to other research projects or from one budget period to the next

  18. Comparison of the One-electron Oxidations of CO-Bridged vs Unbridged Bimetallic Complexes: Electron-transfer Chemistry of Os2Cp2(CO)4 and Os2Cp*2(?-CO)2(CO)2 (Cp = ?5-C5H5, Cp* = ?5-C5Me5)

    SciTech Connect (OSTI)

    Laws, Derek R.; Bullock, R. Morris; Lee, Richmond; Huang, Kuo-Wei; Geiger, William J.

    2014-09-22

    The one-electron oxidations of two dimers of half-sandwich osmium carbonyl complexes have been examined by electrochemistry, spectro-electrochemistry, and computational methods. The all-terminal carbonyl complex Os2Cp2(CO)4 (1, Cp = ?5-C5H5) undergoes a reversible one-electron anodic reaction at E1/2 = 0.41 V vs ferrocene in CH2Cl2/0.05 M [NBu4][B(C6F5)4], giving a rare example of a metal-metal bonded radical cation unsupported by bridging ligands. The IR spectrum of 1+ is consistent with an approximately 1:1 mixture of anti and gauche structures for the 33 e- radical cation in which it has retained all-terminal bonding of the CO ligands. DFT calculations, including orbital-occupancy-perturbed Mayer bond-order analyses, show that the HOMOs of anti-1 and gauche-1 are metal-ligand delocalized. Removal of an electron from 1 has very little effect on the Os-Os bond order, accounting for the resistance of 1+ to heterolytic cleavage. The Os-Os bond distance is calculated to decrease by 0.10 and 0.06 as a consequence of one-electron oxidation of anti-1 and gauche-1, respectively. The CO-bridged complex Os2Cp*2(?-CO)2(CO)2 (Cp* = ?5-C5Me5), trans-2, undergoes a more facile oxidation, E1/2 = - 0.11 V, giving a persistent radical cation shown by solution IR analysis to preserve its bridged-carbonyl structure. However, ESR analysis of frozen solutions of 2+ is interpreted in terms of the presence of two isomers, most likely anti-2+ and trans-2+, at low temperature. Calculations show that the HOMO of trans-2 is highly delocalized over the metal-ligand framework, with the bridging carbonyls accounting for about half of the orbital makeup. The Os-Os bond order again changes very little with removal of an electron, and the Os-Os bond length actually undergoes minor shortening. Calculations suggest that the second isomer of 2+ has both the trans CO-bridged and the anti all-terminal CO structures. DRL and WEG acknowledge the support of the National Science Foundation under grant CHE-0808909. K-WH acknowledges financial support from KAUST. RMB thanks the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences for support. Pacific Northwest National Laboratory is a multiprogram national laboratory operated by Battelle for the U.S. Department of Energy. We thank Dr. S. I. Gorelsky for the discussion on the OOP analysis.

  19. Faculty Positions Heat Transfer and

    E-Print Network [OSTI]

    Faculty Positions Heat Transfer and Thermal/Energy Sciences Naval Postgraduate School Monterey-track faculty position at the assistant professor level in the areas of Heat Transfer and Thermal/Fluid Sciences

  20. Ultra-short channel GaN high electron mobility transistor-like...

    Office of Scientific and Technical Information (OSTI)

    based on the velocity-field dependence of two-dimensional electron gas (2-DEG) channel accounting for the ballistic electron acceleration and the inter-valley transfer. In...

  1. Call Description cread highspeed, synchronous read from a CFS file

    E-Print Network [OSTI]

    Torczon, Virginia

    Call Description cread highspeed, synchronous read from a CFS file cwrite highspeed, synchronous write to a CFS file gilow global MIN operation used for integer scalars gopf make a global operation

  2. The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 1

    E-Print Network [OSTI]

    Fernandez, Eduardo

    The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 1 PGM = SPAR1 2010 FLORIDA ATLANTIC UNIVERSITY SPACE FILE PAGE: 2 PGM = SPAR1 2010 FLORIDA ATLANTIC UNIVERSITY REPORT: SPA130 ROOM INVENTORY REPORT RUN

  3. The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 1

    E-Print Network [OSTI]

    Fernandez, Eduardo

    The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 1 PGM = SPAR1 2010 FLORIDA ATLANTIC UNIVERSITY:515:10105671124552::::P515_REPORTS_I... #12;The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 2 PGM = SPAR1 2010 FLORIDA

  4. Swipe transfer assembly

    DOE Patents [OSTI]

    Christiansen, Robert M. (Blackfoot, ID); Mills, William C. (McKeesport, PA)

    1992-01-01

    The swipe transfer assembly is a mechanical assembly which is used in conjunction with glove boxes and other sealed containments. It is used to pass small samples into or out of glove boxes without an open breach of the containment, and includes a rotational cylinder inside a fixed cylinder, the inside cylinder being rotatable through an arc of approximately 240.degree. relative to the outer cylinder. An offset of 120.degree. from end to end allows only one port to be opened at a time. The assembly is made of stainless steel or aluminum and clear acrylic plastic to enable visual observation. The assembly allows transfer of swipes and smears from radiological and other specially controlled environments.

  5. QER- Comment of Energy Transfer

    Broader source: Energy.gov [DOE]

    From: Lee Hanse Executive Vice President Interstate Energy Transfer Mobile - 210 464 2929 Office - 210 403 6455

  6. HIGEE Mass Transfer

    E-Print Network [OSTI]

    Mohr, R. J.; Fowler, R.

    1986-01-01

    compared with other more conventional mass transfer equipment, will show up to advantage at reasonably large capacity but compare poorly for low capacity duties. (3) Capacity and separation capability (i.e. number of stages) in a HIGEE... are not independent variables, because diameter features in both. If the casing dimensions, OD and axial length, are arbitrarily fixed; then for a duty requiring a large number of stages the packing thickness will be greater and the ID correspondingly smaller...

  7. Plastic container bagless transfer

    DOE Patents [OSTI]

    Tibrea, Steven L.; D'Amelio, Joseph A.; Daugherty, Brent A.

    2003-11-18

    A process and apparatus are provided for transferring material from an isolated environment into a storage carrier through a conduit that can be sealed with a plug. The plug and conduit can then be severed to provide a hermetically sealed storage carrier containing the material which may be transported for storage or disposal and to maintain a seal between the isolated environment and the ambient environment.

  8. Ionization of Water Clusters is Mediated by Exciton Energy Transfer from Argon Clusters

    E-Print Network [OSTI]

    Golan, Amir

    2013-01-01

    VUV) Photoionization of Small Water Clusters. J. Phys. Chem.Energy Transfer between Water Molecules. Nat. Phys. 2010, 6,of Low-Energy Electrons in Water. Nat. Phys. 2010, 6, 78-81.

  9. Computing the energetic component of the charge-transfer symmetry factor

    E-Print Network [OSTI]

    Drechsel-Grau, Christof

    The oxidation half-reaction of the aqueous ferrous ion serves as a model to investigate electron-transfer dynamics. The present classical model consists of two empirical valence bond states and a control parameter that effectively determines...

  10. Effects of PMMA-transfer residues on the growth of organic semiconductor molecules on CVD graphene

    E-Print Network [OSTI]

    Kratzer, Markus; Bayer, Bernhard C.; Kidambi, Piran R.; Matkovi?, Aleksandar; Gaji?, Rado; Cabrero-Vilatela, Andrea; Weatherup, Robert S.; Hofmann, Stephan; Teichert, Christian

    2015-03-09

    Scalably grown and transferred graphene is a highly promising material for organic electronic applications, but controlled interfacing of graphene thereby remains a key challenge. Here, we study the growth characteristics of the important organic...

  11. Formal Methods Technology Transfer: A View from NASA

    E-Print Network [OSTI]

    Caldwell, James

    Formal Methods Technology Transfer: A View from NASA James L. Caldwell Flight Electronics Technology Division NASA Langley Research Center Hampton, Virginia 23681 26 February 1996 Abstract Since 1988 NASA Langley Research Center has supported a formal methods research group. From its inception

  12. Technology Transfer, Entrepreneurship and Innovation

    E-Print Network [OSTI]

    Reed, Nancy E.

    Technology Transfer, Entrepreneurship and Innovation The College of Engineering at UH Manoa has a strong tradition of technology transfer and entrepreneurship that supports the University of Hawai`i's innovation and technology transfer initiative. Principal units are mechanical engineering, electrical

  13. 5. Heat transfer Ron Zevenhoven

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Three heat transfer mechanisms Conduction Convection Radiation 2/120 Pic: B88 bo Akademi University1/120 5. Heat transfer Ron Zevenhoven bo Akademi University Thermal and Flow Engineering / Vrme | Thermal and Flow Engineering | 20500 Turku | Finland #12;3/120 5.1 Conductive heat transfer bo Akademi

  14. Technology Transfer Ombudsman Program | Department of Energy

    Office of Environmental Management (EM)

    Technology Transfer Ombudsman Program Technology Transfer Ombudsman Program The Technology Transfer Commercialization Act of 2000, Public Law 106-404 (PDF) was enacted in November...

  15. Duplicate File Names-A Novel Steganographic Data Hiding Technique

    E-Print Network [OSTI]

    Wu, Jie

    or a terrorist plot. None-the-less, these files can also be potentially dangerous viruses, malware, child porn

  16. Switched Control of Electron Nuclear Spin Systems

    E-Print Network [OSTI]

    Navin Khaneja

    2007-07-11

    In this article, we study control of electron-nuclear spin dynamics at magnetic field strengths where the Larmor frequency of the nucleus is comparable to the hyperfine coupling strength. The quantization axis for the nuclear spin differs from the static B_0 field direction and depends on the state of the electron spin. The quantization axis can be switched by flipping the state of electron spin, allowing for universal control on nuclear spin states. We show that by performing a sequence of flips (each followed by a suitable delay), we can perform any desired rotation on the nuclear spins, which can also be conditioned on the state of the electron spin. These operations, combined with electron spin rotations can be used to synthesize any unitary transformation on the coupled electron-nuclear spin system. We discuss how these methods can be used for design of experiments for transfer of polarization from the electron to the nuclear spins.

  17. CHANDRA OBSERVATIONS OF THE ``DARK'' MOON AND GEOCORONAL SOLAR WIND CHARGE TRANSFER

    E-Print Network [OSTI]

    Wargelin, Bradford J.

    CHANDRA OBSERVATIONS OF THE ``DARK'' MOON AND GEOCORONAL SOLAR WIND CHARGE TRANSFER B. J. Wargelin, which were tentatively ascribed to continuum emission from energetic solar wind electrons impacting with contemporaneous measurements of solar wind parameters, strongly favor charge transfer between highly charged solar

  18. Graphene Transistors Fabricated via Transfer-Printing In Device Active-Areas

    E-Print Network [OSTI]

    Graphene Transistors Fabricated via Transfer-Printing In Device Active-Areas on Large Wafer Xiaogan graphene islands from a graphite and then uses transfer printing to place the islands from the stamp from the printed graphene. The transistors show a hole and electron mobility of 3735 and 795 cm2/V

  19. Local heat transfer measurement and thermo-fluid characterization of a pulsating heat pipe

    E-Print Network [OSTI]

    Khandekar, Sameer

    and possibly future specific requirements from electronics cooling [6,7], heat recovery [8,9] and passiveLocal heat transfer measurement and thermo-fluid characterization of a pulsating heat pipe Mauro 2013 Accepted 29 July 2013 Available online Keywords: Pulsating Heat Pipes Local heat transfer Pressure

  20. Patent subsidy and patent filing in China By Zhen Lei

    E-Print Network [OSTI]

    Sekhon, Jasjeet S.

    Patent subsidy and patent filing in China By Zhen Lei , Zhen Sun, and Brian Wright Department of patent subsidy policies on patent filings in Chi- na. China had rapid growth in patenting in recent years and became the number one in patent filings in 2011. We study five neighboring cities in Jiangsu province

  1. The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 1

    E-Print Network [OSTI]

    Fernandez, Eduardo

    The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 1 PGM = SPAR1 2010 FLORIDA ATLANTIC UNIVERSITY:515:10105671124552::::P515_REPORTS_I... #12;The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 2 PGM = SPAR1 2010 FLORIDA:515:10105671124552::::P515_REPORTS_I... #12;The SAS System PHYSICAL FACILITIES SPACE FILE PAGE: 3 PGM = SPAR1 2010 FLORIDA

  2. 3.0 Exporting Models Save model as OBJ file

    E-Print Network [OSTI]

    Gordon, Scott

    3.0 Exporting Models Save model as OBJ file: o Make sure that the model, and the UV are saved. Save model as an OgreXML file: o Install the blender2ogre exporter Visit https directory (remember that single-click selects a folder) o Type a name for the saved file in the box just

  3. Tuning HDF5 for Lustre File Systems

    SciTech Connect (OSTI)

    Howison, Mark; Koziol, Quincey; Knaak, David; Mainzer, John; Shalf, John

    2010-09-24

    HDF5 is a cross-platform parallel I/O library that is used by a wide variety of HPC applications for the flexibility of its hierarchical object-database representation of scientific data. We describe our recent work to optimize the performance of the HDF5 and MPI-IO libraries for the Lustre parallel file system. We selected three different HPC applications to represent the diverse range of I/O requirements, and measured their performance on three different systems to demonstrate the robustness of our optimizations across different file system configurations and to validate our optimization strategy. We demonstrate that the combined optimizations improve HDF5 parallel I/O performance by up to 33 times in some cases running close to the achievable peak performance of the underlying file system and demonstrate scalable performance up to 40,960-way concurrency.

  4. Transfer of polarized 3He ions in the AtR beam transfer line

    SciTech Connect (OSTI)

    Tsoupas N.; MacKay, W.W.; Meot, F.; Roser, T.; Trbojevic, D.

    2012-05-20

    In addition to collisions of electrons with various unpolarized ion species as well as polarized protons, the proposed electron-hadron collider (eRHIC) will facilitate the collisions of electrons with polarized {sup 3}He ions. The AGS is the last acceleration stage, before injection into one of the RHIC's collider ring for final acceleration. The AtR (AGS to RHIC) transfer line will be utilized to transport the polarized {sup 3}He ions from AGS into one of the RHIC's collider rings. Some of the peculiarities of the AtR line's layout (simultaneous horizontal and vertical bends) may degrade the matching of the stable spin direction of the AtR line with that of RHIC's. In this paper we discuss possible simple modifications of the AtR line to accomplish a perfect matching of the stable spin direction of the injected {sup 3}He beam with the stable spin direction at the injection point of RHIC.

  5. Wireless power transfer for scaled electronic biomedical implants

    E-Print Network [OSTI]

    Theilmann, Paul Thomas

    2012-01-01

    Power Rectifier Driving LED ..b)current through the LED, (c)power delivered to the LED5.4.2 Higher Power Rectifier Driving LED Modeled Measured I

  6. Wireless power transfer for scaled electronic biomedical implants

    E-Print Network [OSTI]

    Theilmann, Paul Thomas

    2012-01-01

    System Model .. 105 3.3.1 Model Verification . 108 Summary . 112 References .. 113 Chapter 4 Low Power

  7. Length-Dependence of Electron Transfer Coupling Matrix in Polyene

    E-Print Network [OSTI]

    Pandey, Ravi

    matrix element, VDA, for 1,3-trans- butadiene molecule calculated with the KT approach shows excellent

  8. Subcooled Boiling Heat Transfer for Cooling of Power Electronics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    radiator and associated pumping system are still required in HEVs. This additional cooling system adds weight and cost while decreasing the efficiency of HEVs. With the...

  9. Theoretical Study of Electron Transfer in Organic Solar Cells

    E-Print Network [OSTI]

    Reslan, Randa

    2015-01-01

    rate in symmetric organic solar cells exp where ! !" is theN. S. Sariciftci, Organic solar cells: An overview, JournalW. Warta, and E. D. Dunlop, Solar cell efficiency tables (

  10. Theoretical Study of Electron Transfer in Organic Solar Cells

    E-Print Network [OSTI]

    Reslan, Randa

    2015-01-01

    rate in symmetric organic solar cells exp where ! !" is theN. S. Sariciftci, Organic solar cells: An overview, Journalfor the use of organic solar cells. First, the methano-

  11. Electron Transfer Dynamics in Efficient Molecular Solar Cells

    SciTech Connect (OSTI)

    Meyer, Gerald John

    2014-10-01

    This research provided new mechanistic insights into surface mediated photochemical processes relevant to solar energy conversion. In this past three years our research has focused on oxidation photo-redox chemistry and on the role surface electric fields play on basic spectroscopic properties of molecular-semiconductor interfaces. Although this research as purely fundamental science, the results and their interpretation have relevance to applications in dye sensitized and photogalvanic solar cells as well as in the storage of solar energy in the form of chemical bonds.

  12. Measurement of Electromagnetic Radiation Emitted during Rapid Intramolecular Electron Transfer

    E-Print Network [OSTI]

    , photosynthesis, artificial photosynthesis, redox chemistry, photography, xerog- raphy, and other processes all

  13. Photoinduced Excited State Electron Transfer at Liquid/Liquid Interfaces

    E-Print Network [OSTI]

    Cooper, Jason K; Benjamin, Ilan

    2014-01-01

    of Coumarin- 314 at the Water/Air Interface. J. Phys. Chem.Solvation of Coumarin 314 at Water/Air Interfaces AontainingSolvation Dynamics at the Air/Water Interface with Time-

  14. Wireless power transfer for scaled electronic biomedical implants

    E-Print Network [OSTI]

    Theilmann, Paul Thomas

    2012-01-01

    power generators for biomedical applications, MicrosystSubretinal Neurostimulator," Biomedical Engineering, IEEEIntegration, and Evaluation," Biomedical Engineering, IEEE

  15. Interfacial electron transfer dynamics of photosensitized zinc oxide nanoclusters

    SciTech Connect (OSTI)

    Murakoshi, Kei; Yanagida, Shozo; Capel, M.

    1997-06-01

    The authors have prepared and characterized photosensitized zinc oxide (ZnO) nanoclusters, dispersed in methanol, using carboxylated coumarin dyes for surface adsorption. Femtosecond time-resolved emission spectroscopy allows the authors to measure the photo-induced charge carrier injection rate constant from the adsorbed photosensitizer to the n-type semiconductor nanocluster. These results are compared with other photosensitized semiconductors.

  16. Comparing the Primary Electron Transfer Process in Organic Photovoltai...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Organic Photovoltaic Heterojunctions with Photosynthetic Reaction Centers October 4, 2011 at 3pm36-428 Garry Rumbles National Renewable Energy Laboratory (NREL), Univeristy...

  17. Theoretical Study of Electron Transfer in Organic Solar Cells

    E-Print Network [OSTI]

    Reslan, Randa

    2015-01-01

    as part of the Molecularly Engineered Energy Materials (MEEM), an Energy Frontier Research Center funded by the U.S.Department of Energy, Office of Science, Office of Basic

  18. Electronic Funds Transfer Authorization Form 4/2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES ScienceInformation Company Name or DBA: Address: City/State/Zip:

  19. Transferred metal electrode films for large-area electronic devices

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of rare Kaon and PionExperiments (Journallithium(Journal Article) | SciTech

  20. Light-harvesting, Excitation Energy/Electron Transfer, and Photoregulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCenter (LMI-EFRC) ProximityCenter (LMI-EFRC) - Xiangin

  1. Rudolph A. Marcus and His Theory of Electron Transfer Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumni > The Energy MaterialsRooftop SolarRoy PrimusRudolph

  2. SF 9424-EFT;Electronic Funds Transfer Agreement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumni > The EnergyRyanPhysics6/14/11 Page9424-EFT (03-2015)

  3. The Future of the Andrew File System

    ScienceCinema (OSTI)

    None

    2011-04-25

    The talk will discuss the ten operational capabilities that have made AFS unique in the distributed file system space and how these capabilities are being expanded upon to meet the needs of the 21st century. Derrick Brashear and Jeffrey Altman will present a technical road map of new features and technical innovations that are under development by the OpenAFS community and Your File System, Inc. funded by a U.S. Department of Energy Small Business Innovative Research grant. The talk will end with a comparison of AFS to its modern days competitors.

  4. Transportation and Energy Use Data Files

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData Files Transportation and Energy Use Data Files

  5. Optimizing File Availability in a Secure Serverless Distributed File System John R. Douceur and Roger P. Wattenhofer

    E-Print Network [OSTI]

    Optimizing File Availability in a Secure Serverless Distributed File System John R. Douceur, and availability by storing replicas of each file on multiple machines. It continuously monitors machine availability and relocates replicas as necessary to maximize the effective availability of the system. We

  6. Method of fabricating a cooled electronic system

    DOE Patents [OSTI]

    Chainer, Timothy J; Gaynes, Michael A; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Schmidt, Roger R; Schultz, Mark D; Simco, Daniel P; Steinke, Mark E

    2014-02-11

    A method of fabricating a liquid-cooled electronic system is provided which includes an electronic assembly having an electronics card and a socket with a latch at one end. The latch facilitates securing of the card within the socket. The method includes providing a liquid-cooled cold rail at the one end of the socket, and a thermal spreader to couple the electronics card to the cold rail. The thermal spreader includes first and second thermal transfer plates coupled to first and second surfaces on opposite sides of the card, and thermally conductive extensions extending from end edges of the plates, which couple the respective transfer plates to the liquid-cooled cold rail. The extensions are disposed to the sides of the latch, and the card is securable within or removable from the socket using the latch without removing the cold rail or the thermal spreader.

  7. Modelling charge transfer reactions with the frozen density embedding formalism

    SciTech Connect (OSTI)

    Pavanello, Michele [Gorlaeus Laboratories, Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden (Netherlands); Neugebauer, Johannes [Institute for Physical and Theoretical Chemistry, Technische Universitaet Braunschweig, Hans-Sommer-Strasse 10, 38106 Braunschweig (Germany)

    2011-12-21

    The frozen density embedding (FDE) subsystem formulation of density-functional theory is a useful tool for studying charge transfer reactions. In this work charge-localized, diabatic states are generated directly with FDE and used to calculate electronic couplings of hole transfer reactions in two {pi}-stacked nucleobase dimers of B-DNA: 5{sup '}-GG-3{sup '} and 5{sup '}-GT-3{sup '}. The calculations rely on two assumptions: the two-state model, and a small differential overlap between donor and acceptor subsystem densities. The resulting electronic couplings agree well with benchmark values for those exchange-correlation functionals that contain a high percentage of exact exchange. Instead, when semilocal GGA functionals are used the electronic couplings are grossly overestimated.

  8. NREL: Technology Transfer - Ombuds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines lightGeospatial ToolkitSMARTS -BeingFuture for SolarTechnology Transfer

  9. DATA META FILE 2004 This file describes the instrumentation, field setup, and quality control procedures

    E-Print Network [OSTI]

    Minnesota, University of

    to revision. See dates above for recent updates concerning the data file and metadata. The following data) was measured in 2004. A calibration drift was discovered and the sensor was replaced for 2005. PAR can

  10. Seer: An analysis package for LHCO files

    E-Print Network [OSTI]

    Travis A. W. Martin

    2015-03-10

    Seer is a multipurpose package for performing trigger, signal determination and cuts of an arbitrary number of collider processes stored in the LHCO file format. This article details the use of Seer, including the necessary details for users to customize the code for investigating new kinematic variables.

  11. DEEP SEA DRILLING PROJECT DATA FILE DOCUMENTS

    E-Print Network [OSTI]

    DEEP SEA DRILLING PROJECT DATA FILE DOCUMENTS Ocean Drilling Program Texas A&M University Technical; however, republication of any portion requires the written consent of the Director, Ocean Drilling Program, Texas A&M University Research Park, 1000 Discovery Drive, College Station, Texas 77840, as well

  12. Title: Ontario Greenbelt Boundary File Data Creator /

    E-Print Network [OSTI]

    Title: Ontario Greenbelt Boundary File Data Creator / Copyright Owner: Ontario Ministry of Municipal Affairs and Housing Publisher: Ontario Ministry of Municipal Affairs and Housing Edition: N/A Versions: N/A Publication Date: N/A Coverage Date(s): N/A Updates: N/A Abstract: The Ontario Greenbelt

  13. Electron tube

    DOE Patents [OSTI]

    Suyama, Motohiro (Hamamatsu, JP); Fukasawa, Atsuhito (Hamamatsu, JP); Arisaka, Katsushi (Los Angeles, CA); Wang, Hanguo (North Hills, CA)

    2011-12-20

    An electron tube of the present invention includes: a vacuum vessel including a face plate portion made of synthetic silica and having a surface on which a photoelectric surface is provided, a stem portion arranged facing the photoelectric surface and made of synthetic silica, and a side tube portion having one end connected to the face plate portion and the other end connected to the stem portion and made of synthetic silica; a projection portion arranged in the vacuum vessel, extending from the stem portion toward the photoelectric surface, and made of synthetic silica; and an electron detector arranged on the projection portion, for detecting electrons from the photoelectric surface, and made of silicon.

  14. Electron uptake by iron-oxidizing phototrophic bacteria

    SciTech Connect (OSTI)

    Bose, A; Gardel, EJ; Vidoudez, C; Parra, EA; Girguis, PR

    2014-02-26

    Oxidation-reduction reactions underlie energy generation in nearly all life forms. Although most organisms use soluble oxidants and reductants, some microbes can access solid-phase materials as electron-acceptors or -donors via extracellular electron transfer. Many studies have focused on the reduction of solid-phase oxidants. Far less is known about electron uptake via microbial extracellular electron transfer, and almost nothing is known about the associated mechanisms. Here we show that the iron-oxidizing photoautotroph Rhodopseudomonas palustris TIE-1 accepts electrons from a poised electrode, with carbon dioxide as the sole carbon source/electron acceptor. Both electron uptake and ruBisCo form I expression are stimulated by light. Electron uptake also occurs in the dark, uncoupled from photosynthesis. Notably, the pioABC operon, which encodes a protein system essential for photoautotrophic growth by ferrous iron oxidation, influences electron uptake. These data reveal a previously unknown metabolic versatility of photoferrotrophs to use extracellular electron transfer for electron uptake.

  15. Recoil Polarization Measurements of the Proton Electromagnetic Form Factor Ratio to High Momentum Transfer

    E-Print Network [OSTI]

    Puckett, Andrew J R

    2015-01-01

    The electromagnetic form factors of the nucleon characterize the effect of its internal structure on its response to an electromagnetic probe as studied in elastic electron-nucleon scattering. These form factors are functions of the squared four-momentum transfer $Q^2$ between the electron and the proton. The two main classes of observables of this reaction are the scattering cross section and polarization asymmetries, both of which are sensitive to the form factors in different ways. When considering large momentum transfers, double-polarization observables offer superior sensitivity to the electric form factor. This thesis reports the results of a new measurement of the ratio of the electric and magnetic form factors of the proton at high momentum transfer using the recoil polarization technique. A polarized electron beam was scattered from a liquid hydrogen target, transferring polarization to the recoiling protons. These protons were detected in a magnetic spectrometer which was used to reconstruct their ...

  16. Electronic Fireflies

    E-Print Network [OSTI]

    Hacker, Randi; Greene, Megan

    2009-01-28

    . The Japanese: firefly connection goes back to the 8th Century when poets used them to represent human passions. But pollution and development have depleted the number of fireflies. So what's a New Year's reveler to do? Buy Denshi Hotaru, life-sized, electronic...

  17. Technology transfer 1995

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    Technology Transfer 1995 is intended to inform the US industrial and academic sectors about the many opportunities they have to form partnerships with the US Department of Energy (DOE) for the mutual advantage of the individual institutions, DOE, and the nation as a whole. It also describes some of the growing number of remarkable achievements resulting from such partnerships. These partnership success stories offer ample evidence that Americans are learning how to work together to secure major benefits for the nation--by combining the technological, scientific, and human resources resident in national laboratories with those in industry and academia. The benefits include more and better jobs for Americans, improved productivity and global competitiveness for technology-based industries, and a more efficient government laboratory system.

  18. General Relativistic Radiative Transfer

    E-Print Network [OSTI]

    S. Knop; P. H. Hauschildt; E. Baron

    2006-11-30

    We present a general method to calculate radiative transfer including scattering in the continuum as well as in lines in spherically symmetric systems that are influenced by the effects of general relativity (GR). We utilize a comoving wavelength ansatz that allows to resolve spectral lines throughout the atmosphere. The used numerical solution is an operator splitting (OS) technique that uses a characteristic formal solution. The bending of photon paths and the wavelength shifts due to the effects of GR are fully taken into account, as is the treatment of image generation in a curved spacetime. We describe the algorithm we use and demonstrate the effects of GR on the radiative transport of a two level atom line in a neutron star like atmosphere for various combinations of continuous and line scattering coefficients. In addition, we present grey continuum models and discuss the effects of different scattering albedos on the emergent spectra and the determination of effective temperatures and radii of neutron star atmospheres.

  19. Heat transfer probe

    DOE Patents [OSTI]

    Frank, Jeffrey I.; Rosengart, Axel J.; Kasza, Ken; Yu, Wenhua; Chien, Tai-Hsin; Franklin, Jeff

    2006-10-10

    Apparatuses, systems, methods, and computer code for, among other things, monitoring the health of samples such as the brain while providing local cooling or heating. A representative device is a heat transfer probe, which includes an inner channel, a tip, a concentric outer channel, a first temperature sensor, and a second temperature sensor. The inner channel is configured to transport working fluid from an inner inlet to an inner outlet. The tip is configured to receive at least a portion of the working fluid from the inner outlet. The concentric outer channel is configured to transport the working fluid from the inner outlet to an outer outlet. The first temperature sensor is coupled to the tip, and the second temperature sensor spaced apart from the first temperature sensor.

  20. 1 Copyright 2013 by ASME Proceedings of the ASME 2013 Summer Heat Transfer Conference

    E-Print Network [OSTI]

    Bahrami, Majid

    Storage (TES) systems; ii) power electronics of solar/wind/tidal energy conversion systems; iii) power in the characteristics of heat transfer equipment. Generally, processes such as start-up, shut- down, power surge subjected to daily variation, seasonal variation, and weather conditions. As such, the power electronics

  1. Short-pulse chirped adiabatic population transfer in diatomic molecules S. Kallush and Y. B. Band

    E-Print Network [OSTI]

    Band, Yehuda B.

    Short-pulse chirped adiabatic population transfer in diatomic molecules S. Kallush and Y. B. Band electronic states to a second electronic state. Our chirped-pulse rapid adiabatic passage scheme is implemented with short-duration optical pulses, and can be understood in terms of ``road design engineering

  2. The File Mover: An Efficient Data Transfer System for Grid Applications Cosimo Anglano, Massimo Canonico

    E-Print Network [OSTI]

    Anglano, Cosimo

    resources, seems a promising solution. In or- der to enable the achievement of satisfactory performance High Energy Physics, Climate Modeling, and Life Sciences, re- quires the processing of massive data], For these applications, the creation of Data Grids[8], that pool geographically distributed storage and computing

  3. The effect of molecular aggregates over the interfacial charge transfer processes on dye sensitized solar cells

    SciTech Connect (OSTI)

    Planells, Miquel; Forneli, Amparo; Martinez-Ferrero, Eugenia; Sanchez-Diaz, Antonio; Sarmentero, Maria Angeles [Institute of Chemical Research of Catalonia (ICIQ). Avda. Paiesos Catalans, 16 Tarragona 43007 (Spain); Ballester, Pablo; Palomares, Emilio [Institute of Chemical Research of Catalonia (ICIQ). Avda. Paiesos Catalans, 16 Tarragona 43007 (Spain); Institucio Catalana de Recerca i Estudis Avancats (ICREA), Passeig Lluis Companys, 23 08010 Barcelona (Spain); O'Regan, Brian C. [Centre for Electronic Materials and Devices, Imperial College of London, Exhibition Road, SW7 2AZ London (United Kingdom)

    2008-04-14

    The electron transfer reaction between the photoinjected electrons in the nanocrystalline TiO{sub 2} mesoporous sensitized films and the oxidized electrolyte in dye sensitized solar cells (DSSC) plays a major role on the device efficiency. In this communication we show that, although the presence of molecular aggregates on the free base porphyrin DSSC limits the device photocurrent response under illumination, they form an effective hydrophobic barrier against the oxidized electrolyte impeding fast back-electron transfer kinetics. Therefore, their drawback can be overcome by designing dyes with peripheral moieties that prevent the formation of the aggregates and are able to achieve efficiencies as high as 3.2% under full sun.

  4. Working Data File Sets from the Comprehensive Epidemiologic Data Resource (CEDR)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The more-than-100 working data file sets available from CEDR mainly include the data collected and updated by the three epidemiologic research centers. A researcher selects or generates variables from these more dynamic data files in order to form analytic data files. CEDR is a DOE electronic database comprised of health studies of DOE contract workers and environmental studies of areas surrounding DOE facilities. CEDR provides independent researchers and the public with access to de-identified data collected since the Department's early production years. Current holdings include studies of over 1 million workers at 31 DOE sites. Most of CEDR's holdings are derived from epidemiologic studies of DOE workers at many large nuclear weapons plants, such as Hanford, Los Alamos, the Oak Ridge reservation, Savannah River Site, and Rocky Flats. These studies primarily use death certificate information to identify excess deaths and patterns of disease among workers to determine what factors contribute to the risk of developing cancer and other illnesses. In addition, many of these studies have radiation exposure measurements on individual workers.

  5. on technology transfer, industry research +

    E-Print Network [OSTI]

    Cafarella, Michael J.

    on technology transfer, industry research + economic development annual report U N I V E R S I T Y and resources available at the University of Michigan as showcased in this year's Annual Report on Technology Transfer, Industry Research, and Economic Development. At the heart of the University's contributions

  6. 4065 (RP-664) Heat Transfer

    E-Print Network [OSTI]

    of roomsurface-to-air heat transmission is dependentonan accurateestimateof the filmcoefficient. Forty- eight4065 (RP-664) Convective Energy and Heat Transfer Thermal Load in Building Calculations Daniel E convection film coefficients significantly underpredict the rate of surface convective heat 'transfer

  7. Single photoelectron spin detection and angular momentum transfer in a gate defined quantum dot

    E-Print Network [OSTI]

    Takafumi Fujita; Kazuhiro Morimoto; Haruki Kiyama; Giles Allison; Marcus Larsson; Arne Ludwig; Sascha R. Valentin; Andreas D. Wieck; Akira Oiwa; Seigo Tarucha

    2015-04-14

    Recent innovations in fabricating nanoscale confined spin systems have enabled investigation of fundamental quantum correlations between single quanta of photons and matter states. Realization of quantum state transfer from photon polarization to electron spin using gate defined quantum dots (QDs) may give evidence of preserved coherence of angular momentum basis states at the photon-spin interface. The interface would enlarge the concept of quantum information technology, in which single photogenerated electron spins are manipulated with the dots, but this remains a serious challenge. Here, we report the detection of single electron spins generated by polarized single photons via a double QD (DQD) to verify the angular momentum transfer from single photons to single electrons. Pauli spin blockade (PSB) is used to project the photoelectron spin state onto the up or down spin state. Our result promises the realization of coherent quantum state transfer and development of hybrid photon and spin quantum technology.

  8. Cooled electronic system with thermal spreaders coupling electronics cards to cold rails

    DOE Patents [OSTI]

    Chainer, Timothy J; Gaynes, Michael A; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Schmidt, Roger R; Schultz, Mark D; Simco, Daniel P; Steinke, Mark E

    2013-07-23

    Liquid-cooled electronic systems are provided which include an electronic assembly having an electronics card and a socket with a latch at one end. The latch facilitates securing of the card within the socket or removal of the card from the socket. A liquid-cooled cold rail is disposed at the one end of the socket, and a thermal spreader couples the electronics card to the cold rail. The thermal spreader includes first and second thermal transfer plates coupled to first and second surfaces on opposite sides of the card, and thermally conductive extensions extending from end edges of the plates, which couple the respective transfer plates to the liquid-cooled cold rail. The thermally conductive extensions are disposed to the sides of the latch, and the card is securable within or removable from the socket using the latch without removing the cold rail or the thermal spreader.

  9. Uploading Files to Your University Writing Portfolio: ENGL 1100 & Note: If your file is over 250mb, please see the section in troubleshooting about uploading files

    E-Print Network [OSTI]

    Gopalakrishnan, K.

    a saved document from your computer into your University Writing Portfolio. 8. Select the document you forgot to save your document with the course prefix and course number. BE SURE to save or change finished, click "save file(s)." Always SAVE after uploading new content! *Tip: You may upload and rename

  10. A Theoretical Investigation Into Energy Transfer In Photosynthetic Open Quantum Systems

    E-Print Network [OSTI]

    Wilkins, David M

    2015-01-01

    This thesis looks at the electronic energy transfer in the Fenna-Matthews-Olson complex, in which evidence of long-lived coherence has been observed in 2-dimensional infrared experiments. I use three techniques: the numerically exact Hierarchical Equations of Motion, and the perturbative Redfield and Foerster theories, the latter of which ignores quantum coherence in the transfer. Both of the approximate methods perform very well - and while oscillations in site populations (a hallmark of coherence) are present in the exact transfer dynamics and absent in the dynamics of Foerster theory, the latter gives a reasonable prediction of transfer rates and steady-state populations, despite being incoherent - suggesting that coherence is not vital for the dynamics of transfer. Since Foerster theory is very inexpensive to run and performs so well, I then apply it to calculate the effects of static disorder in bacteriochlorophyll site energies and of a more structured spectral density. Ultimately, the energy transfer i...

  11. INSPIRE and SPIRES Log File Analysis

    SciTech Connect (OSTI)

    Adams, Cole; /Wheaton Coll. /SLAC

    2012-08-31

    SPIRES, an aging high-energy physics publication data base, is in the process of being replaced by INSPIRE. In order to ease the transition from SPIRES to INSPIRE it is important to understand user behavior and the drivers for adoption. The goal of this project was to address some questions in regards to the presumed two-thirds of the users still using SPIRES. These questions are answered through analysis of the log files from both websites. A series of scripts were developed to collect and interpret the data contained in the log files. The common search patterns and usage comparisons are made between INSPIRE and SPIRES, and a method for detecting user frustration is presented. The analysis reveals a more even split than originally thought as well as the expected trend of user transition to INSPIRE.

  12. File:5 CCR 1001-5 Colorado Stationary Source Permitting and Air...

    Open Energy Info (EERE)

    Up Search File Edit History File:5 CCR 1001-5 Colorado Stationary Source Permitting and Air Pollution Control Emission Notice Requirements.pdf Jump to: navigation, search File...

  13. Urban Sewage Delivery Heat Transfer System (2): Heat Transfer

    E-Print Network [OSTI]

    Zhang, C.; Wu, R.; Li, X.; Li, G.; Zhuang, Z.; Sun, D.

    2006-01-01

    analysis of above flow resistance and energy cost, we know that the economy flux ratio of transfer heat-transfer means is between 0.54 and 0.85, namely sewage flux is smaller, and minC Cr min wwCVc?= . It is necessary to point out that though depending... efficiency of contranatant two pass thimble: ()213 1 11 21wwNn wz tt Cr tt 1n? ?? ?==?+ ? (1) Fig.1 Reverse-flow heat efficiency of TDHTS Contranatant single pass heat-transfer efficiency: ( ) ()1 1exp (1 ) 1exp (1)n Cr NTU Cr? = ?? ? ? Put...

  14. Dramatic changes in electronic structure revealed by fractionally charged nuclei

    SciTech Connect (OSTI)

    Cohen, Aron J.; Mori-Snchez, Paula

    2014-01-28

    Discontinuous changes in the electronic structure upon infinitesimal changes to the Hamiltonian are demonstrated. These are revealed in one and two electron molecular systems by full configuration interaction (FCI) calculations when the realm of the nuclear charge is extended to be fractional. FCI electron densities in these systems show dramatic changes in real space and illustrate the transfer, hopping, and removal of electrons. This is due to the particle nature of electrons seen in stretched systems and is a manifestation of an energy derivative discontinuity at constant number of electrons. Dramatic errors of density functional theory densities are seen in real space as this physics is missing from currently used approximations. The movements of electrons in these simple systems encapsulate those in real physical processes, from chemical reactions to electron transport and pose a great challenge for the development of new electronic structure methods.

  15. Electronic fingerprinting of RNA

    E-Print Network [OSTI]

    Gegenheimer, Peter Albert

    1988-01-01

    Software has been developed to assist RNA fingerprinting analysis. One program generates, from a DNA sequence data file, the oligonucleotides resulting from digestion of an RNA transcript labeled with any specified ...

  16. Web-enabled project management and collaboration using Microsoft Groove system

    E-Print Network [OSTI]

    Yuksel, Kamer

    2008-10-10

    Application Service Provider CFMA Construction Financial Management Association EDA Electronic Data Interchange FTP File Transfer Protocols IT Information Technology NSPE National Society of Professional Engineers PMCS Project Management... ............................................................................................................56 5.3 Files Tool..................................................................................................................57 5.4 Forms Tool...

  17. Electron energy loss spectroscopy of gold nanoparticles on graphene

    SciTech Connect (OSTI)

    DeJarnette, Drew [Microelectronics and Photonics Graduate Program, University of Arkansas, Fayetteville, Arkansas 72701 (United States); Roper, D. Keith, E-mail: dkroper@uark.edu [Microelectronics and Photonics Graduate Program, University of Arkansas, Fayetteville, Arkansas 72701 (United States); Department of Chemical Engineering, University of Arkansas, Fayetteville, Arkansas 72701 (United States)

    2014-08-07

    Plasmon excitation decay by absorption, scattering, and hot electron transfer has been distinguished from effects induced by incident photons for gold nanoparticles on graphene monolayer using electron energy loss spectroscopy (EELS). Gold nano-ellipses were evaporated onto lithographed graphene, which was transferred onto a silicon nitride transmission electron microscopy grid. Plasmon decay from lithographed nanoparticles measured with EELS was compared in the absence and presence of the graphene monolayer. Measured decay values compared favorably with estimated radiative and non-radiative contributions to decay in the absence of graphene. Graphene significantly enhanced low-energy plasmon decay, increasing mode width 38%, but did not affect higher energy plasmon or dark mode decay. This decay beyond expected radiative and non-radiative mechanisms was attributed to hot electron transfer, and had quantum efficiency of 20%, consistent with previous reports.

  18. Electron-electron interaction, weak localization and spin valve effect in vertical-transport graphene devices

    SciTech Connect (OSTI)

    Long, Mingsheng; Gong, Youpin; Wei, Xiangfei; Zhu, Chao; Xu, Jianbao; Liu, Ping; Guo, Yufen; Li, Weiwei; Liu, Liwei, E-mail: lwliu2007@sinano.ac.cn [Key Laboratory of Nanodevices and Applications-CAS and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences (CAS), Suzhou 215123 (China); Liu, Guangtong [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2014-04-14

    We fabricated a vertical structure device, in which graphene is sandwiched between two asymmetric ferromagnetic electrodes. The measurements of electron and spin transport were performed across the combined channels containing the vertical and horizontal components. The presence of electron-electron interaction (EEI) was found not only at low temperatures but also at moderate temperatures up to ?120?K, and EEI dominates over weak localization (WL) with and without applying magnetic fields perpendicular to the sample plane. Moreover, spin valve effect was observed when magnetic filed is swept at the direction parallel to the sample surface. We attribute the EEI and WL surviving at a relatively high temperature to the effective suppress of phonon scattering in the vertical device structure. The findings open a way for studying quantum correlation at relatively high temperature.

  19. EPA -- Amended Environmental Impact Statement Filing System Guidance...

    Office of Environmental Management (EM)

    1506.10 of the Council on Environmental Quality's Regulations Implementing the National Environmental Policy Act The purpose of the EPA Filing System Guidelines is to provide...

  20. Building Life Cycle Cost Programs File Saving Troubleshooting...

    Energy Savers [EERE]

    Cycle Cost Programs File Saving Troubleshooting Some users have experienced difficulties saving BLCC projects. The primary issue causing the issue is that the user is not an...

  1. Public Financial Disclosure Reports Filed by the Secretary and...

    Office of Environmental Management (EM)

    Public Financial Disclosure Reports Filed by the Secretary and Deputy Secretary The Stop Trading on Congressional Knowledge (STOCK) Act requires online posting of the Public...

  2. Motion for Leave to File Consolidated Answer and Consolidated...

    Broader source: Energy.gov (indexed) [DOE]

    of Robert G. Burnley, Director ofthe Commonwealth of Virginia Department of Environmental Quality, filed in Federal Energy Regulatory Commission ("FERC") Docket No. ELOS-14S. The...

  3. FERC Hydroelectric Project Handbook for Filings other than Licenses...

    Open Energy Info (EERE)

    FERC Hydroelectric Project Handbook for Filings other than Licenses and Exemptions Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance...

  4. File:01MTALandUseConsiderations.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbHFarinello GeothermalFideris IncFile FTP DocumentFD-bFile EditFileFile

  5. Consumer Electronics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit the followingConcentrating SolarConstruction Review BasicConsumer-Electronics

  6. Microwave-cut silicon layer transfer

    SciTech Connect (OSTI)

    Thompson, D.C.; Alford, T.L.; Mayer, J.W.; Hochbauer, T.; Nastasi, M.; Lau, S.S.; Theodore, N. David; Henttinen, K.; Suni, Ilkka; Chu, Paul K. [Department of Chemical and Materials Engineering, Arizona State University, Tempe, Arizona 85287-6006 (United States); Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87544 (United States); Department of Electrical and Computer Engineering, University of California at San Diego, San Diego, California 92093 (United States); Advanced Products Research and Development Laboratory, Freescale Semiconductor Incorporated, 2100 East Elliot Road, Tempe, Arizona 85284 (United States); VTT Centre for Microelectronics, P.O. Box 1208, 02044 VTT (Finland); Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)

    2005-11-28

    Microwave heating is used to initiate exfoliation of silicon layers in conjunction with the ion-cut process for transfer of silicon layers onto insulator or heterogeneous layered substrates. Samples were processed inside a 2.45 GHz, 1300 W cavity applicator microwave system for time durations as low as 12 s. This is a significant decrease in exfoliation incubation times. Sample temperatures measured by pyrometry were within previous published ranges. Rutherford backscattering spectrometry and cross-sectional transmission electron microscopy were used to determine layer thickness and crystallinity. Surface quality was measured by using atomic force microscopy. Hall measurements were used to characterize electrical properties as a function of postcut anneal time and temperature.

  7. Geothermal Electricity Technology Evaluation Model (GETEM) Individual Case Files and Summary Spreadsheet (GETEM version Spring 2013)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hanson, Steven CJ

    This group of files-- 10 GETEM individual case files and 1 summary spreadsheet-- contain final data from the revisions between summer 2011 and spring 2013.

  8. Geothermal Electricity Technology Evaluation Model (GETEM) Individual Case Files and Summary Spreadsheet (GETEM version Spring 2013)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hanson, Steven CJ

    2013-03-07

    This group of files-- 10 GETEM individual case files and 1 summary spreadsheet-- contain final data from the revisions between summer 2011 and spring 2013.

  9. Spontaneous hot-electron light emission from electron-fed optical antennas

    E-Print Network [OSTI]

    Buret, Mickael; Dellinger, Jean; Cazier, Nicolas; Mennemanteuil, Marie-Maxime; Berthelot, Johann; Smetanin, Igor V; Protsenko, Igor E; Colas-des-Francs, Grard; Bouhelier, Alexandre

    2015-01-01

    Nanoscale electronics and photonics are among the most promising research areas providing functional nano-components for data transfer and signal processing. By adopting metal-based optical antennas as a disruptive technological vehicle, we demonstrate that these two device-generating technologies can be interfaced to create an electronically-driven self-emitting unit. This nanoscale plasmonic transmitter operates by injecting electrons in a contacted tunneling antenna feedgap. Under certain operating conditions, we show that the antenna enters a highly nonlinear regime in which the energy of the emitted photons exceeds the quantum limit imposed by the applied bias. We propose a model based upon the spontaneous emission of hot electrons that correctly reproduces the experimental findings. The electron-fed optical antennas described here are critical devices for interfacing electrons and photons, enabling thus the development of optical transceivers for on-chip wireless broadcasting of information at the nanos...

  10. Vrije Universiteit Brussel Technology Transfer Interface

    E-Print Network [OSTI]

    Goelzer, Heiko

    Vrije Universiteit Brussel Technology Transfer Interface -connecting science and society- [for Prof. Hugo Thienpont More Information Technology Transfer Interface (TTI) Vrije Universiteit Brussel.interface@vub.ac.be - www.vubtechtransfer.be Vrije Universiteit Brussel Technology Transfer Interface -connecting science

  11. Second Line of Defense Help Desk: Electronic Maintenance Reports - Local Maintenance Provider User Guide Rev. 1

    SciTech Connect (OSTI)

    Leigh, Richard J.

    2011-12-14

    The Electronic Maintenance Report forms present a uniform dataset for analysis of Sustainability metrics. These forms collect readily minable data while allowing the attachment of site-specific checklists or other supporting files for review by the Sustainability Manager and Program Management.

  12. Multiple-charge transfer and trapping in DNA dimers

    E-Print Network [OSTI]

    Tornow, Sabine; Anders, Frithjof B; Zwicknagl, Gertrud

    2010-01-01

    We investigate the charge transfer characteristics of one and two excess charges in a DNA base-pair dimer using a model Hamiltonian approach. The electron part comprises diagonal and off-diagonal Coulomb matrix elements such a correlated hopping and the bond-bond interaction, which were recently calculated by Starikov [E. B. Starikov, Phil. Mag. Lett. {\\bf 83}, 699 (2003)] for different DNA dimers. The electronic degrees of freedom are coupled to an ohmic or a super-ohmic bath serving as dissipative environment. We employ the numerical renormalization group method in the nuclear tunneling regime and compare the results to Marcus theory for the thermal activation regime. For realistic parameters, the rate that at least one charge is transferred from the donor to the acceptor in the subspace of two excess electrons significantly exceeds the rate in the single charge sector. Moreover, the dynamics is strongly influenced by the Coulomb matrix elements. We find sequential and pair transfer as well as a regime wher...

  13. Effects of partial charge-transfer solute -- solvent interactions in absorption spectra of aromatic hydrocarbons in aqueous and alcoholic solutions

    E-Print Network [OSTI]

    I. A. Ar'ev; N. I. Lebovka; E. A. Solovieva

    2013-03-03

    A method for study of charge-transfer interactions between solute molecules and solvent based on the comparison of the ratios of spectral shifts of different electronic transitions in solute molecules in chemically inert solvent is proposed. The method is applicable to molecules that do not change their dipole moment on excitation. As an example, a presence of charge transfer interactions in higher electronic states of aromatic hydrocarbons (benzene, phenanthrene, and naphthalene) dissolved in water and alcohols was demonstrated.

  14. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    with thermophilic anaerobic digester were constructed andand mesophilic anaerobic digesters, these same comparativewith a thermophilic anaerobic digester sludge and amended

  15. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    was monitored by cessation of biogas production as well as awas monitored by cessation of biogas production as well as a

  16. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    Microbial ecology meets electrochemistry: Electricity-drivenMicrobial ecology meets electrochemistry: Electricity-drivenMicrobial ecology meets electrochemistry: Electricity-driven

  17. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    energy generation. Trends Biotech 23(6):291-298. Rozendalwastewater treatment. Trends Biotech Bigham R (2007) 10 topbusiness models. Nat Biotech Kleijntjens RHdB, P.A. ;

  18. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    celebrations anymore. Breweries are taking their wastewater,technology is not limited to brewery wastes, bacteria haveBusch Inc. and Foster?s breweries, of the United States and

  19. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    1988) Novel mode of microbial energy metabolism: Organic1988) Novel mode of microbial energy metabolism: Organicadvances microbial research Beyond energy generation, MFCs

  20. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    catalyses electricity generation at microbial fuel cellElectricity generation from cellulose by rumen microorganisms in microbial fuelElectricity generation from cellulose by rumen microorganisms in microbial fuel

  1. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    annually to treat food processing waste (3, 4). Moreover,waste alone contains 34 billion kWh of energy (3), while food

  2. Following electron flow: From a Gram-positive community to mechanisms of electron transfer

    E-Print Network [OSTI]

    Wrighton, Kelly Catherine

    2010-01-01

    that harvest energy from marine sediments. Science 295:483-DR (2006) Harvesting energy from the marine sediment-water

  3. Technology Transfer Overview | Department of Energy

    Office of Environmental Management (EM)

    Technology Transfer Overview Technology Transfer Overview Through strategic investments in science and technology, the U.S. Department of Energy (DOE) helps power and secure...

  4. MODERN DEVELOPMENTS IN MULTIPHASE FLOW & HEAT TRANSFER

    E-Print Network [OSTI]

    Lahey, Richard T.

    MODERN DEVELOPMENTS IN MULTIPHASE FLOW & HEAT TRANSFER "ENGINEERING APPLICATIONS OF FRACTAL and multiphase flow & heat transfer will be stressed. This paper will begin by reviewing some important concepts

  5. Preparing for Transfer Biological Engineering

    E-Print Network [OSTI]

    Walter, M.Todd

    Preparing for Transfer Majors: Biological Engineering Chemical Engineering Civil Engineering Computer Science Electrical & Computer Engineering Engineering Physics Environmental Engineering Information Science, Systems, & Technology Materials Science & Engineering Mechanical Engineering Operations

  6. Preparing for Transfer Biological Engineering

    E-Print Network [OSTI]

    Walter, M.Todd

    Preparing for Transfer Majors: Biological Engineering Biomedical Engineering* Chemical Engineering Civil Engineering Computer Science Electrical & Computer Engineering Engineering Physics Environmental Engineering Information Science, Systems, & Technology Materials Science & Engineering Mechanical Engineering

  7. Knowledge Capture and Transfer Program

    Broader source: Energy.gov [DOE]

    The Office of Learning and Workforce Development is working with Heads of Departmental Elements, DOE senior leaders and subject-matter-experts to capture and transfer the knowledge and experiences...

  8. Electrohydrodynamically enhanced condensation heat transfer

    E-Print Network [OSTI]

    Wawzyniak, Markus

    1993-01-01

    In a condenser the thickness of the liquid condensate film covering the cooled surface constitutes a resistance to the heat transfer. By establishing a non uniform electric field in the vicinity of the condensation surface the extraction of liquid...

  9. Wireless transfer of electric power

    E-Print Network [OSTI]

    Moffatt, Robert Alexander

    2009-01-01

    In this dissertation, I describe the design and construction of a system which can transfer electric power wirelessly. This is accomplished using inductive, near-field, non-radiative coupling between self-resonant copper ...

  10. Automatic computation of transfer functions

    DOE Patents [OSTI]

    Atcitty, Stanley; Watson, Luke Dale

    2015-04-14

    Technologies pertaining to the automatic computation of transfer functions for a physical system are described herein. The physical system is one of an electrical system, a mechanical system, an electromechanical system, an electrochemical system, or an electromagnetic system. A netlist in the form of a matrix comprises data that is indicative of elements in the physical system, values for the elements in the physical system, and structure of the physical system. Transfer functions for the physical system are computed based upon the netlist.

  11. Effects of Solvent and Solute Polarizability on the Reorganization Energy of Electron Shikha Gupta and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Effects of Solvent and Solute Polarizability on the Reorganization Energy of Electron Transfer of the effect of solute and solvent polarizability on the solvent reorganization energy of intramolecular electron transfer. In the first set of simulations, the polarizability of the solvent is varied at constant

  12. Storing files in a parallel computing system based on user-specified parser function

    DOE Patents [OSTI]

    Faibish, Sorin; Bent, John M; Tzelnic, Percy; Grider, Gary; Manzanares, Adam; Torres, Aaron

    2014-10-21

    Techniques are provided for storing files in a parallel computing system based on a user-specified parser function. A plurality of files generated by a distributed application in a parallel computing system are stored by obtaining a parser from the distributed application for processing the plurality of files prior to storage; and storing one or more of the plurality of files in one or more storage nodes of the parallel computing system based on the processing by the parser. The plurality of files comprise one or more of a plurality of complete files and a plurality of sub-files. The parser can optionally store only those files that satisfy one or more semantic requirements of the parser. The parser can also extract metadata from one or more of the files and the extracted metadata can be stored with one or more of the plurality of files and used for searching for files.

  13. LLaannggeerrhhaannss LLaabb PPrroottooccoollss Importing DRILL Data via .txt file

    E-Print Network [OSTI]

    Langerhans, Brian

    LLaannggeerrhhaannss LLaabb PPrroottooccoollss Importing DRILL Data via .txt file To import data into the DRILL or to modify existing entries or to delete entries, using a modified DRILL data xlsx./ .txt file instead of using the DRILL Admin functions. 1. Back up the DRILL using the weekly backup protocol. 2

  14. TIGER:Thermal-Aware File Assignment in Storage Clusters

    E-Print Network [OSTI]

    Qin, Xiao

    TIGER:Thermal-Aware File Assignment in Storage Clusters Ajit Chavan, Xunfei Jiang, Mohemmad I/O performance. I. INTRODUCTION Thermal management for power-dense storage clusters can address cooling problems. The following three factors make thermal-aware file assign- ment desirabe and practical for storage clusters

  15. Energy Efficient Prefetching with Buffer Disks for Cluster File Systems

    E-Print Network [OSTI]

    Qin, Xiao

    Energy Efficient Prefetching with Buffer Disks for Cluster File Systems Adam Manzanares, Xiaojun the energy- efficiency of large scale parallel storage systems. To address these issues we introduce EEVFS (Energy Efficient Virtual File System), which is able to manage data placement and disk states to help

  16. Replication in the Harp File System Barbara Liskov

    E-Print Network [OSTI]

    Liskov, Barbara

    many failures the file server with a small uninterruptible power supply (UPS) that is intended) after provide a strong semantics for file operations: each opera a power failure; the server uses, monitored by the Office of Naval Research under volatile memory at several nodes. It survives a power

  17. Access Your Files | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden Documentation DataStreamsTotalproposalsAboutAcceleratingthYour Files Access

  18. Core File Settings | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit the followingConcentratingPortalCool MagneticCopper Palladium-Core File

  19. TO: FILE MEHClRANDUM ALTERNATE

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1. .&. ' , c 1 1;TO: FILE FROM:

  20. Form:MapFile | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainable Urban Transport JumpFlowood,PevafersaMapFile Jump to: navigation, search

  1. Detailed Drawings of NERSC File Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet HanfordDOEDanielDeSmall Business ForumDesignerFile System

  2. File Storage and I/O

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji Fiji Is JustFile

  3. File Storage and I/O

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji Fiji Is JustFile

  4. File storage and I/O

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji FijiO File storage

  5. File storage and I/O

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah861MayArtQuestionsFieldFiji FijiO File

  6. Parallel File Systems at HPC Centers: Usage,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access| Department ofStephen PSeptember|March Study Could Lead toFile

  7. Help:Managing files | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam: Energyarea, California | OpenHeliotronicsManaging files Jump

  8. Category:Map Files | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County,Camilla, Georgia:Geothermal Regulatory RoadmapISGANLEDSMap Files Jump

  9. Help:Uploading Files | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy ElectricalsFTLTechnology Srl JumpSubObjects JumpUploading Files

  10. FY 16-17 ASC Utility Filings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunitiesofExtrans -ORGANIZATION FY 2013 FY6-17-ASC-Utility-Filings

  11. Nanoscale heat transfer - from computation to experiment

    E-Print Network [OSTI]

    Luo, Tengfei

    2013-04-09

    Heat transfer can differ distinctly at the nanoscale from that at the macroscale. Recent advancement in

  12. CANISTER TRANSFER SYSTEM DESCRIPTION DOCUMENT

    SciTech Connect (OSTI)

    B. Gorpani

    2000-06-23

    The Canister Transfer System receives transportation casks containing large and small disposable canisters, unloads the canisters from the casks, stores the canisters as required, loads them into disposal containers (DCs), and prepares the empty casks for re-shipment. Cask unloading begins with cask inspection, sampling, and lid bolt removal operations. The cask lids are removed and the canisters are unloaded. Small canisters are loaded directly into a DC, or are stored until enough canisters are available to fill a DC. Large canisters are loaded directly into a DC. Transportation casks and related components are decontaminated as required, and empty casks are prepared for re-shipment. One independent, remotely operated canister transfer line is provided in the Waste Handling Building System. The canister transfer line consists of a Cask Transport System, Cask Preparation System, Canister Handling System, Disposal Container Transport System, an off-normal canister handling cell with a transfer tunnel connecting the two cells, and Control and Tracking System. The Canister Transfer System operating sequence begins with moving transportation casks to the cask preparation area with the Cask Transport System. The Cask Preparation System prepares the cask for unloading and consists of cask preparation manipulator, cask inspection and sampling equipment, and decontamination equipment. The Canister Handling System unloads the canister(s) and places them into a DC. Handling equipment consists of a bridge crane hoist, DC loading manipulator, lifting fixtures, and small canister staging racks. Once the cask has been unloaded, the Cask Preparation System decontaminates the cask exterior and returns it to the Carrier/Cask Handling System via the Cask Transport System. After the DC is fully loaded, the Disposal Container Transport System moves the DC to the Disposal Container Handling System for welding. To handle off-normal canisters, a separate off-normal canister handling cell is located adjacent to the canister transfer cell and is interconnected to the transfer cell by means of the off-normal canister transfer tunnel. All canister transfer operations are controlled by the Control and Tracking System. The system interfaces with the Carrier/Cask Handling System for incoming and outgoing transportation casks. The system also interfaces with the Disposal Container Handling System, which prepares the DC for loading and subsequently seals the loaded DC. The system support interfaces are the Waste Handling Building System and other internal Waste Handling Building (WHB) support systems.

  13. Polarisation Transfer in Proton Compton Scattering at High Momentum Transfer

    SciTech Connect (OSTI)

    David Hamilton

    2004-12-31

    The Jefferson Lab Hall A experiment E99-114 comprised a series of measurements to explore proton Compton scattering at high momentum transfer. For the first time, the polarisation transfer observables in the p (~ 0 ~ p) reaction were measured in the GeV energy range, where it is believed that quark-gluon degrees of freedom begin to dominate. The experiment utilised a circularly polarised photon beam incident on a liquid hydrogen target, with the scattered photon and recoil proton detected in a lead-glass calorimeter and a magnetic spectrometer, respectively.

  14. Exciton coherence lifetimes from electronic structure

    E-Print Network [OSTI]

    Parkhill, John; Aspuru-Guzik, Alan

    2011-01-01

    We model the coherent energy transfer of an electronic excitation within covalently linked aromatic homodimers from first-principles, to answer whether the usual models of the bath calculated via detailed electronic structure calculations can reproduce the key dynamics. For these systems the timescales of coherent transport are experimentally known from time-dependent polarization anisotropy measurements, and so we can directly assess the whether current techniques might be predictive for this phenomenon. Two choices of electronic basis states are investigated, and their relative merits discussed regarding the predictions of the perturbative model. The coupling of the electronic degrees of freedom to the nuclear degrees of freedom is calculated rather than assumed, and the fluorescence anisotropy decay is directly reproduced. Surprisingly we find that although TDDFT absolute energies are routinely in error by orders of magnitude more than the coupling energy, the coherent transport properties of these dimers ...

  15. Scrap uranium recycling via electron beam melting

    SciTech Connect (OSTI)

    McKoon, R.

    1993-11-01

    A program is underway at the Lawrence Livermore National Laboratory (LLNL) to recycle scrap uranium metal. Currently, much of the material from forging and machining processes is considered radioactive waste and is disposed of by oxidation and encapsulation at significant cost. In the recycling process, uranium and uranium alloys in various forms will be processed by electron beam melting and continuously cast into ingots meeting applicable specifications for virgin material. Existing vacuum processing facilities at LLNL are in compliance with all current federal and state environmental, safety and health regulations for the electron beam melting and vaporization of uranium metal. One of these facilities has been retrofitted with an auxiliary electron beam gun system, water-cooled hearth, crucible and ingot puller to create an electron beam melt furnace. In this furnace, basic process R&D on uranium recycling will be performed with the goal of eventual transfer of this technology to a production facility.

  16. ARCHITECTURE OF A CHARGE-TRANSFER STATE REGULATING LIGHT HARVESTING IN A PLANT ANTENNA PROTEIN

    SciTech Connect (OSTI)

    Fleming, Graham; Ahn, Tae Kyu; Avenson, Thomas J.; Ballottari, Matteo; Cheng, Yuan-Chung; Niyogi, Krishna K.; Bassi, Roberto; Fleming, Graham R.

    2008-04-02

    Energy-dependent quenching of excess absorbed light energy (qE) is a vital mechanism for regulating photosynthetic light harvesting in higher plants. All of the physiological characteristics of qE have been positively correlated with charge-transfer between coupled chlorophyll and zeaxanthin molecules in the light-harvesting antenna of photosystem II (PSII). In this work, we present evidence for charge-transfer quenching in all three of the individual minor antenna complexes of PSII (CP29, CP26, and CP24), and we conclude that charge-transfer quenching in CP29 involves a de-localized state of an excitonically coupled chlorophyll dimer. We propose that reversible conformational changes in CP29 can `tune? the electronic coupling between the chlorophylls in this dimer, thereby modulating the energy of the chlorophylls-zeaxanthin charge-transfer state and switching on and off the charge-transfer quenching during qE.

  17. A Five-Year Study of File-System Metadata Nitin Agrawal

    E-Print Network [OSTI]

    Swift, Michael

    in file size, file age, file-type frequency, directory size, namespace structure, file-system population that explains the namespace structure and the distribution of directory sizes. We find significant temporal by mass-emailing a scanning pro- gram to Microsoft's employees, and we had a 22% par- ticipation rate

  18. A FiveYear Study of FileSystem Metadata Nitin Agrawal

    E-Print Network [OSTI]

    Swift, Michael

    in file size, file age, filetype frequency, directory size, namespace structure, filesystem population that explains the namespace structure and the distribution of directory sizes. We find significant temporal by massemailing a scanning pro gram to Microsoft's employees, and we had a 22% par ticipation rate

  19. T-607: Update: Adobe Acrobat, Reader, and Flash Player SWF File Processing Arbitrary Code Execution Vulnerability

    Broader source: Energy.gov [DOE]

    Update: Adobe Acrobat, Reader, and Flash Player SWF File Processing Arbitrary Code Execution Vulnerability.

  20. Release strategies for making transferable semiconductor structures, devices and device components

    DOE Patents [OSTI]

    Rogers, John A. (Champaign, IL); Nuzzo, Ralph G. (Champaign, IL); Meitl, Matthew (Raleigh, NC); Ko, Heung Cho (Urbana, IL); Yoon, Jongseung (Urbana, IL); Menard, Etienne (Durham, NC); Baca, Alfred J. (Urbana, IL)

    2011-04-26

    Provided are methods for making a device or device component by providing a multilayer structure having a plurality of functional layers and a plurality of release layers and releasing the functional layers from the multilayer structure by separating one or more of the release layers to generate a plurality of transferable structures. The transferable structures are printed onto a device substrate or device component supported by a device substrate. The methods and systems provide means for making high-quality and low-cost photovoltaic devices, transferable semiconductor structures, (opto-)electronic devices and device components.

  1. Release strategies for making transferable semiconductor structures, devices and device components

    DOE Patents [OSTI]

    Rogers, John A; Nuzzo, Ralph G; Meitl, Matthew; Ko, Heung Cho; Yoon, Jongseung; Menard, Etienne; Baca, Alfred J

    2014-11-25

    Provided are methods for making a device or device component by providing a multilayer structure having a plurality of functional layers and a plurality of release layers and releasing the functional layers from the multilayer structure by separating one or more of the release layers to generate a plurality of transferable structures. The transferable structures are printed onto a device substrate or device component supported by a device substrate. The methods and systems provide means for making high-quality and low-cost photovoltaic devices, transferable semiconductor structures, (opto-)electronic devices and device components.

  2. Doping suppression and mobility enhancement of graphene transistors fabricated using an adhesion promoting dry transfer process

    SciTech Connect (OSTI)

    Cheol Shin, Woo; Hun Mun, Jeong; Yong Kim, Taek; Choi, Sung-Yool; Jin Cho, Byung, E-mail: bjcho@kaist.edu, E-mail: tskim1@kaist.ac.kr [Department of Electrical Engineering, Graphene Research Center, KAIST, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Yoon, Taeshik; Kim, Taek-Soo, E-mail: bjcho@kaist.edu, E-mail: tskim1@kaist.ac.kr [Department of Mechanical Engineering, Graphene Research Center, KAIST, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)] [Department of Mechanical Engineering, Graphene Research Center, KAIST, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2013-12-09

    We present the facile dry transfer of graphene synthesized via chemical vapor deposition on copper film to a functional device substrate. High quality uniform dry transfer of graphene to oxidized silicon substrate was achieved by exploiting the beneficial features of a poly(4-vinylphenol) adhesive layer involving a strong adhesion energy to graphene and negligible influence on the electronic and structural properties of graphene. The graphene field effect transistors (FETs) fabricated using the dry transfer process exhibit excellent electrical performance in terms of high FET mobility and low intrinsic doping level, which proves the feasibility of our approach in graphene-based nanoelectronics.

  3. Optically pulsed electron accelerator

    DOE Patents [OSTI]

    Fraser, J.S.; Sheffield, R.L.

    1985-05-20

    An optically pulsed electron accelerator can be used as an injector for a free electron laser and comprises a pulsed light source, such as a laser, for providing discrete incident light pulses. A photoemissive electron source emits electron bursts having the same duration as the incident light pulses when impinged upon by same. The photoemissive electron source is located on an inside wall of a radiofrequency-powered accelerator cell which accelerates the electron burst emitted by the photoemissive electron source.

  4. Optically pulsed electron accelerator

    DOE Patents [OSTI]

    Fraser, John S. (Los Alamos, NM); Sheffield, Richard L. (Los Alamos, NM)

    1987-01-01

    An optically pulsed electron accelerator can be used as an injector for a free electron laser and comprises a pulsed light source, such as a laser, for providing discrete incident light pulses. A photoemissive electron source emits electron bursts having the same duration as the incident light pulses when impinged upon by same. The photoemissive electron source is located on an inside wall of a radio frequency powered accelerator cell which accelerates the electron burst emitted by the photoemissive electron source.

  5. Inelastic electron-vortex-beam scattering

    E-Print Network [OSTI]

    Ruben Van Boxem; Bart Partoens; Jo Verbeeck

    2015-03-16

    Recent theoretical and experimental developments in the field of electron vortex beam physics have raised questions on what exactly this novelty in the field of electron microscopy (and other fields, such as particle physics) really provides. An important part in the answer to those questions lies in scattering theory. The present investigation explores various aspects of inelastic quantum scattering theory for cylindrically symmetric beams with orbital angular momentum. The model system of Coulomb scattering on a hydrogen atom provides the setting to address various open questions: How is momentum transferred? Do vortex beams selectively excite atoms, and how can one employ vortex beams to detect magnetic transitions? The analytical approach presented here provides answers to these questions. OAM transfer is possible, but not through selective excitation; rather, by pre- and post-selection one can filter out the relevant contributions to a specific signal.

  6. Susceptor heating device for electron beam brazing

    DOE Patents [OSTI]

    Antieau, Susan M. (Pittsburgh, PA); Johnson, Robert G. R. (Trafford, PA)

    1999-01-01

    A brazing device and method are provided which locally apply a controlled amount of heat to a selected area, within a vacuum. The device brazes two components together with a brazing metal. A susceptor plate is placed in thermal contact with one of the components. A serrated pedestal supports the susceptor plate. When the pedestal and susceptor plate are in place, an electron gun irradiates an electron beam at the susceptor plate such that the susceptor plate is sufficiently heated to transfer heat through the one component and melt the brazing metal.

  7. Electron beam generation in Tevatron electron lenses

    SciTech Connect (OSTI)

    Kamerdzhiev, V.; Kuznetsov, G.; Shiltsev, V.; Solyak, N.; Tiunov, M.; /Novosibirsk, IYF

    2006-08-01

    New type of high perveance electron guns with convex cathode has been developed. Three guns described in this article are built to provide transverse electron current density distributions needed for Electron Lenses for beam-beam compensation in the Tevatron collider. The current distribution can be controlled either by the gun geometry or by voltage on a special control electrode located near cathode. We present the designs of the guns and report results of beam measurements on the test bench. Because of their high current density and low transverse temperature of electrons, electron guns of this type can be used in electron cooling and beam-beam compensation devices.

  8. Journal of Heat Transfer1999 JHT Heat Transfer Gallery Department of Mechanical 8. Aerospace Engineering

    E-Print Network [OSTI]

    Kihm, IconKenneth David

    Journal of Heat Transfer1999 JHT Heat Transfer Gallery S. M. You Department of Mechanical 8 Transfer Visualization Committee organized two photo gallery sessions in 1998. The International Heat Transfer Photo Gallery was held at the l la' International Heat Transfer Conference (IHTC) in Kyongju

  9. Vibronic coupling explains the ultrafast carotenoid-to-bacteriochlorophyll energy transfer in natural and artificial light harvesters

    E-Print Network [OSTI]

    Perlk, Vclav; Cranston, Laura J; Cogdell, Richard J; Lincoln, Craig N; Savolainen, Janne; anda, Frantiek; Man?al, Tom; Hauer, Jrgen

    2015-01-01

    The initial energy transfer in photosynthesis occurs between the light-harvesting pigments and on ultrafast timescales. We analyze the carotenoid to bacteriochlorophyll energy transfer in LH2 Marichromatium purpuratum as well as in an artificial light-harvesting dyad system by using transient grating and two-dimensional electronic spectroscopy with 10 fs time resolution. We find that F\\"orster-type models reproduce the experimentally observed 60 fs transfer times, but overestimate coupling constants, which leads to a disagreement with both linear absorption and electronic 2D-spectra. We show that a vibronic model, which treats carotenoid vibrations on both electronic ground and excited state as part of the system's Hamiltonian, reproduces all measured quantities. Importantly, the vibronic model presented here can explain the fast energy transfer rates with only moderate coupling constants, which are in agreement with structure based calculations. Counterintuitively, the vibrational levels on the carotenoid el...

  10. Radiative transfer in decomposed domains

    E-Print Network [OSTI]

    T. Heinemann; W. Dobler; A. Nordlund; A. Brandenburg

    2005-11-09

    An efficient algorithm for calculating radiative transfer on massively parallel computers using domain decomposition is presented. The integral formulation of the transfer equation is used to divide the problem into a local but compute-intensive part for calculating the intensity and optical depth integrals, and a nonlocal part for communicating the intensity between adjacent processors. The waiting time of idle processors during the nonlocal communication part does not have a severe impact on the scaling. The wall clock time thus scales nearly linearly with the inverse number of processors.

  11. PUBLISHED ONLINE: 10 JANUARY 2010 | DOI: 10.1038/NPHYS1498 Ultrafast energy transfer between water molecules

    E-Print Network [OSTI]

    Loss, Daniel

    -called water dimer). This intermolecular coulombic decay leads to an ejection of a low-energy electron from and leads to dissociation of the water dimer into two H2O+ ions. As electrons of low energy (0.7-20 eV) haveLETTERS PUBLISHED ONLINE: 10 JANUARY 2010 | DOI: 10.1038/NPHYS1498 Ultrafast energy transfer

  12. Novel Aspects of Direct Laser Acceleration of Relativistic Electrons

    E-Print Network [OSTI]

    Arefiev, A V; Khudik, V N

    2015-01-01

    We examine the impact of several factors on electron acceleration by a laser pulse and the resulting electron energy gain. Specifically, we consider the role played by: 1) static longitudinal electric field; 2) static transverse electric field; 3) electron injection into the laser pulse; and 4) static longitudinal magnetic field. It is shown that all of these factors lead, under certain conditions, to a considerable electron energy gain from the laser pulse. In contrast with other mechanisms such as wakefield acceleration, the static electric fields in this case do not directly transfer substantial energy to the electron. Instead, they reduce the longitudinal dephasing between the electron and the laser beam, which then allows the electron to gain extra energy from the beam. The mechanisms discussed here are relevant to experiments with under-dense gas jets, as well as to experiments with solid-density targets involving an extended pre-plasma.

  13. Comparison of leading parallel NAS file systems on commodity hardware

    SciTech Connect (OSTI)

    Hedges, R; Fitzgerald, K; Gary, M; Stearman, D M

    2010-11-08

    High performance computing has experienced tremendous gains in system performance over the past 20 years. Unfortunately other system capabilities, such as file I/O, have not grown commensurately. In this activity, we present the results of our tests of two leading file systems (GPFS and Lustre) on the same physical hardware. This hardware is the standard commodity storage solution in use at LLNL and, while much smaller in size, is intended to enable us to learn about differences between the two systems in terms of performance, ease of use and resilience. This work represents the first hardware consistent study of the two leading file systems that the authors are aware of.

  14. File:03IDGTermEasement.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale,3IDGTermEasement.pdf Jump to: navigation, search File File history File usage Metadata

  15. File:04TXAStateExplorationProcess.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1ORDExplorationInjectionPermit (1).pdf Jump to: navigation, search File File history File usage

  16. File:04UTAStateExplorationProcess.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1ORDExplorationInjectionPermit (1).pdf Jump to: navigation, search File File history File

  17. File:05AKADrillingWellDevelopment.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1ORDExplorationInjectionPermit (1).pdf Jump to: navigation, search File File history File-FD-a -5-FD-b

  18. File:01IDALandUseConsiderations.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbHFarinello GeothermalFideris IncFile FTP DocumentFD-bFile EditFile Edit

  19. File:01LandUseOverview.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbHFarinello GeothermalFideris IncFile FTP DocumentFD-bFile EditFile

  20. RandFile package for Mathematica for accessing file-based sources of randomness

    E-Print Network [OSTI]

    J. A. Miszczak; M. Wahl

    2015-03-15

    We present a package for Mathematica computer algebra system which allows the exploitation of local files as sources of random data. We provide the description of the package and illustrate its usage by showing some examples. We also compare the provided functionality with alternative sources of randomness, namely a built-in pseudo-random generator and the package for accessing hardware true random number generators.

  1. Photoexcited energy transfer in a weakly coupled dimer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hernandez, Laura Alfonso; Nelson, Tammie; Tretiak, Sergei; Fernandez-Alberti, Sebastian

    2015-01-08

    Nonadiabatic excited-state molecular dynamics (NA-ESMD) simulations have been performed in order to study the time-dependent exciton localization during energy transfer between two chromophore units of the weakly coupled anthracene dimer dithia-anthracenophane (DTA). Simulations are done at both low temperature (10 K) and room temperature (300 K). The initial photoexcitation creates an exciton which is primarily localized on a single monomer unit. Subsequently, the exciton experiences an ultrafast energy transfer becoming localized on either one monomer unit or the other, whereas delocalization between both monomers never occurs. In half of the trajectories, the electronic transition density becomes completely localized on themoresame monomer as the initial excitation, while in the other half, it becomes completely localized on the opposite monomer. In this article, we present an analysis of the energy transfer dynamics and the effect of thermally induced geometry distortions on the exciton localization. Finally, simulated fluorescence anisotropy decay curves for both DTA and the monomer unit dimethyl anthracene (DMA) are compared. As a result, our analysis reveals that changes in the transition density localization caused by energy transfer between two monomers in DTA is not the only source of depolarization and exciton relaxation within a single DTA monomer unit can also cause reorientation of the transition dipole.less

  2. Saving Your Data (Data Transfer) Transfer Raw Data to Another Computer

    E-Print Network [OSTI]

    California at San Diego, University of

    Saving Your Data (Data Transfer) Transfer Raw Data to Another Computer 1. Open a terminal 2 the Data Manager window 2. Right click the scan you want to save or the whole study and select "Transfer

  3. Transfer Factors for Contaminant Uptake

    E-Print Network [OSTI]

    of supply, upon written request as follows: Address: U.S. Nuclear Regulatory Commission OfficeTransfer Factors for Contaminant Uptake by Fruit and Nut Trees Office of Nuclear Regulatory; licensee event reports; and Commission papers and their attachments. NRC publications in the NUREG series

  4. Spring 2014 Heat Transfer -1

    E-Print Network [OSTI]

    Virginia Tech

    Spring 2014 1 Heat Transfer - 1 Consider a cylindrical nuclear fuel rod of length L and diameter df and the tube at a rate m , and the outer surface of the tube is well insulated. Heat generation occurs within. The specific heat of water pc , and the thermal conductivity of the fuel rod fk are constants. The system

  5. Experimental determination of the elastic cotunneling rate in a hybrid single-electron box

    SciTech Connect (OSTI)

    Sun, Chia-Heng; Tai, Po-Chen; Chen, Yung-Fu, E-mail: yfuchen@ncu.edu.tw [Department of Physics, National Central University, Jhongli 32001, Taiwan (China); Jiang, Jheng-An; Wu, Cen-Shawn [Department of Physics, National Changhua University of Education, Changhua 500, Taiwan (China); Chen, Jeng-Chung [Department of Physics, National Tsing-Hua University, Hsinchu 30013, Taiwan (China)

    2014-06-09

    We report measurements of charge configurations and charge transfer dynamics in a hybrid single-electron box composed of aluminum and copper. We used two single-electron transistors (SETs) to simultaneously read out different parts of the box, enabling us to map out stability diagrams of the box and identify various charge transfer processes in the box. We further characterized the elastic cotunneling in the box, which is an important source of error in electron turnstiles consisting of hybrid SETs, and found that the rate was as low as 1?Hz at degeneracy and compatible with theoretical estimates for electron tunneling via virtual states in the central superconducting island of the box.

  6. AB Electronic Tubes and Quasi-Superconductivity at Room Temperature

    E-Print Network [OSTI]

    Alexander Bolonkin

    2008-05-02

    Author offers and researches a new idea - filling tubes by electronic gases. He shows: If the insulating envelope (cover) of the tube is charged positively, the electrons within the tube are not attracted to covering. Tube (as a whole) remains a neutral (uncharged) body. The electron gas in the tube has very low density and very high conductivity, close to superconductivity. If we take the density (pressure) of electron gas as equal to atmospheric pressure, the thickness of insulator film may be very small and the resulting tube is very light. Author shows the offered tubes can be applied to many technical fields. For example: (1) Transfer of energy over very long distance with very small electric losses. (2) Design of cheap high altitude electric lines without masts. (3) Transfer of energy from one continent to another continent through the ionosphere. (4) Transfer of a plasma beam (which can convey thrust and energy) from Earth surface to a space ship. (5) Observation of the sky by telescope without atmospheric hindrances. (6) Dirigibles (air balloons) of the highest lift force. (7) Increasing of gun range severalfold. (8) Transfer of matter. And so on. Key words: AB tubes, electronic tubes, superconductivity, transmission energy.

  7. Chapter 9: Electronics

    E-Print Network [OSTI]

    Spieler, Helmuth G

    2008-01-01

    R. Armstrong Contents Electronics 9.1 Introduction 9.2measurements 9.11 Digital electronics 9.11.1 Logic elementsProblems page 1 vii Electronics This chapter was contributed

  8. Linear, third- and fifth-order nonlinear spectroscopy of a charge transfer system coupled to an underdamped vibration

    E-Print Network [OSTI]

    Dijkstra, Arend G

    2015-01-01

    We study hole, electron and exciton transport in a charge transfer system in the presence of underdamped vibrational motion. We analyze the signature of these processes in the linear and third-, and fifth-order nonlinear electronic spectra. Calculations are performed with a numerically exact hierarchical equations of motion method for an underdamped Brownian oscillator spectral density. We find that combining electron, hole and exciton transfer can lead to non-trivial spectra with more structure than with excitonic coupling alone. Traces taken during the waiting time of a two-dimensional spectrum are dominated by vibrational motion and do not reflect the electron, hole, and exciton dynamics directly. We find that the fifth-order nonlinear response is particularly sensitive to the charge transfer process. While third-order 2D spectroscopy detects the correlation between two coherences, fifth-order 2D spectroscopy (2D population spectroscopy) is here designed to detect correlations between the excited states du...

  9. Pseudopotential for the electron-electron interaction

    E-Print Network [OSTI]

    Lloyd-Williams, J H; Conduit, G J

    2015-01-01

    We propose a pseudopotential for the electron-electron Coulomb interaction to improve the efficiency of many-body electronic structure calculations. The pseudopotential accurately replicates the scattering properties of the Coulomb interaction, and recovers the analytical solution for two electrons in a parabolic trap. A case study for the homogeneous electron gas using the diffusion Monte Carlo and configuration interaction methods recovers highly accurate values for the ground state energy, and the smoother potential reduces the computational cost by a factor of ~30. Finally, we demonstrate the use of the pseudopotential to study isolated lithium and beryllium atoms.

  10. Controlling Graphene's Electronic Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlling Graphene's Electronic Structure Print Wednesday, 25 April 2007 00:00 Graphene, because of its unusual electron properties, reduced dimensionality, and scale, has...

  11. Millisecond newly born pulsars as efficient accelerators of electrons

    E-Print Network [OSTI]

    Osmanov, Z; Machabeli, G; Chkheidze, N

    2015-01-01

    The newly born millisecond pulsars are investigated as possible energy sources for creating ultra-high energy electrons. The transfer of energy from the star rotation to high energy electrons takes place through the Landau damping of centrifugally driven (via a two stream instability) electrostatic Langmuir waves. Generated in the bulk magnetosphere plasma, such waves grow to high amplitudes, and then damp, very effectively, on relativistic electrons driving them to even higher energies. We show that the rate of transfer of energy is so efficient that no energy losses might affect the mechanism of particle acceleration; the electrons might achieve energies of the order of 10^{18}eV for parameters characteristic of a young star.

  12. C++11 header files appear missing on Edison

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aborted for test.cxx (code 4) edison03: > This is because the installed Intel compilers rely upon the GNU header files for C++11 support, while the default SLES version of...

  13. A Multilevel File System for High Assurancey Cynthia E. Irvine

    E-Print Network [OSTI]

    A Multilevel File System for High Assurancey Cynthia E. Irvine Computer Science Department Naval to provide an interface which is both \\friendly" and exible, and relies entirely upon the high assur- ance

  14. "Annual Electric Power Industry Report (EIA-861 data file)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In 2013, demand-side management data started being collected as energy efficiency and demand response data. Retail Sales, Customer Sited is a new file; this data was previously...

  15. The Umbrella File System: Storage Management Across Heterogeneous Devices

    E-Print Network [OSTI]

    Garrison, John Allen

    2011-08-08

    With the advent of Flash based solid state devices (SSDs), the differences in physical devices used to store data in computers are becoming more and more pronounced. Effectively mapping the differences in storage devices to the files...

  16. Annual Electric Generator data - EIA-860 data file

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    in the file are wholly-owned by their operator). 61EnviroAssocYyyyy Contains boiler association data for the environmental equipment data collected on the Form EIA-860....

  17. ASSEMBLY TRANSFER SYSTEM DESCRIPTION DOCUMENT

    SciTech Connect (OSTI)

    B. Gorpani

    2000-06-26

    The Assembly Transfer System (ATS) receives, cools, and opens rail and truck transportation casks from the Carrier/Cask Handling System (CCHS). The system unloads transportation casks consisting of bare Spent Nuclear Fuel (SNF) assemblies, single element canisters, and Dual Purpose Canisters (DPCs). For casks containing DPCs, the system opens the DPCs and unloads the SNF. The system stages the assemblies, transfer assemblies to and from fuel-blending inventory pools, loads them into Disposal Containers (DCs), temporarily seals and inerts the DC, decontaminates the DC and transfers it to the Disposal Container Handling System. The system also prepares empty casks and DPCs for off-site shipment. Two identical Assembly Transfer System lines are provided in the Waste Handling Building (WHB). Each line operates independently to handle the waste transfer throughput and to support maintenance operations. Each system line primarily consists of wet and dry handling areas. The wet handling area includes a cask transport system, cask and DPC preparation system, and a wet assembly handling system. The basket transport system forms the transition between the wet and dry handling areas. The dry handling area includes the dry assembly handling system, assembly drying system, DC preparation system, and DC transport system. Both the wet and dry handling areas are controlled by the control and tracking system. The system operating sequence begins with moving transportation casks to the cask preparation area. The cask preparation operations consist of cask cavity gas sampling, cask venting, cask cool-down, outer lid removal, and inner shield plug lifting fixture attachment. Casks containing bare SNF (no DPC) are filled with water and placed in the cask unloading pool. The inner shield plugs are removed underwater. For casks containing a DPC, the cask lid(s) is removed, and the DPC is penetrated, sampled, vented, and cooled. A DPC lifting fixture is attached and the cask is placed into the cask unloading pool. In the cask unloading pool the DPC is removed from the cask and placed in an overpack and the DPC lid is severed and removed. Assemblies are removed from either an open cask or DPC and loaded into assembly baskets positioned in the basket staging rack in the assembly unloading pool. A method called ''blending'' is utilized to load DCs with a heat output of less than 11.8 kW. This involves combining hotter and cooler assemblies from different baskets. Blending requires storing some of the hotter fuel assemblies in fuel-blending inventory pools until cooler assemblies are available. The assembly baskets are then transferred from the basket staging rack to the assembly handling cell and loaded into the assembly drying vessels. After drying, the assemblies are removed from the assembly drying vessels and loaded into a DC positioned below the DC load port. After installation of a DC inner lid and temporary sealing device, the DC is transferred to the DC decontamination cell where the top area of the DC, the DC lifting collar, and the DC inner lid and temporary sealing device are decontaminated, and the DC is evacuated and backfilled with inert gas to prevent prolonged clad exposure to air. The DC is then transferred to the Disposal Container Handling System for lid welding. In another cask preparation and decontamination area, lids are replaced on the empty transportation casks and DPC overpacks, the casks and DPC overpacks are decontaminated, inspected, and transferred to the Carrier/Cask Handling System for shipment off-site. All system equipment is designed to facilitate manual or remote operation, decontamination, and maintenance. The system interfaces with the Carrier/Cask Handling System for incoming and outgoing transportation casks and DPCs. The system also interfaces with the Disposal Container Handling System, which prepares the DC for loading and subsequently seals the loaded DC. The system support interfaces are the Waste Handling Building System and other internal WHB support systems.

  18. Determination of equilibrium electron temperature and times using an electron swarm model with BOLSIG+ calculated collision frequencies and rate coefficients

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pusateri, Elise N.; Morris, Heidi E.; Nelson, Eric M.; Ji, Wei

    2015-08-04

    Electromagnetic pulse (EMP) events produce low-energy conduction electrons from Compton electron or photoelectron ionizations with air. It is important to understand how conduction electrons interact with air in order to accurately predict EMP evolution and propagation. An electron swarm model can be used to monitor the time evolution of conduction electrons in an environment characterized by electric field and pressure. Here a swarm model is developed that is based on the coupled ordinary differential equations (ODEs) described by Higgins et al. (1973), hereinafter HLO. The ODEs characterize the swarm electric field, electron temperature, electron number density, and drift velocity. Importantmoreswarm parameters, the momentum transfer collision frequency, energy transfer collision frequency, and ionization rate, are calculated and compared to the previously reported fitted functions given in HLO. These swarm parameters are found using BOLSIG+, a two term Boltzmann solver developed by Hagelaar and Pitchford (2005), which utilizes updated cross sections from the LXcat website created by Pancheshnyi et al. (2012). We validate the swarm model by comparing to experimental effective ionization coefficient data in Dutton (1975) and drift velocity data in Ruiz-Vargas et al. (2010). In addition, we report on electron equilibrium temperatures and times for a uniform electric field of 1 StatV/cm for atmospheric heights from 0 to 40 km. We show that the equilibrium temperature and time are sensitive to the modifications in the collision frequencies and ionization rate based on the updated electron interaction cross sections.less

  19. ReadMe file: A user's guide for the vitality model parameter fitting routine and the S-Plus functions contained in file VitalityModelFitting.ssc.

    E-Print Network [OSTI]

    Washington at Seattle, University of

    ReadMe file: A user's guide for the vitality model parameter fitting routine and the S-Plus functions contained in file VitalityModelFitting.ssc. The VitalityModelFitting.ssc file contains all functions necessary to run the MLE parameter fitting routine for the vitality-based survival model

  20. Analytic Data File Sets from the Comprehensive Epidemiologic Data Resource (CEDR)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The 261 files from more than 60 studies in CEDR's Analytic Data File Sets contain the data that a researcher directly used in conducting the analyses and result in reported findings or publication in a peer-reviewed journal. CEDR is a DOE electronic database comprised of health studies of DOE contract workers and environmental studies of areas surrounding DOE facilities. CEDR provides independent researchers and the public with access to de-identified data collected since the Department's early production years. Current holdings include studies of over 1 million workers at 31 DOE sites. Most of CEDR's holdings are derived from epidemiologic studies of DOE workers at many large nuclear weapons plants, such as Hanford, Los Alamos, the Oak Ridge reservation, Savannah River Site, and Rocky Flats. These studies primarily use death certificate information to identify excess deaths and patterns of disease among workers to determine what factors contribute to the risk of developing cancer and other illnesses. In addition, many of these studies have radiation exposure measurements on individual workers.

  1. File:03MTCEncroachmentOverview.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale,3IDGTermEasement.pdf Jump to: navigation, search File File

  2. File:05DrillingPermittingOverview.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1ORDExplorationInjectionPermit (1).pdf Jump to: navigation, search File File

  3. File:Archaeological Consultants.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New Pages Recent Changes AllApschem.pdf Jump to: navigation, search File File history

  4. File:Archaeology excavation permit.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New Pages Recent Changes AllApschem.pdf Jump to: navigation, search File File

  5. Chemistry Transfer Evaluations Before requesting a transfer evaluation, please look up your courses on the UO Transfer Credit

    E-Print Network [OSTI]

    Cina, Jeff

    Chemistry Transfer Evaluations Before requesting a transfer evaluation, please look up your courses://registrar.uoregon.edu/current_students/transfer-articulation If your Chemistry courses have not been evaluated, or if you feel the evaluation is not correct, then fill out this form and bring it and the associated documents to a Chemistry advisor. Name

  6. Federating LHCb datasets using the DIRAC File catalog

    E-Print Network [OSTI]

    Haen, Christophe; Frank, Markus; Tsaregorodtsev, Andrei

    2015-01-01

    In the distributed computing model of LHCb the File Catalog (FC) is a central component that keeps track of each file and replica stored on the Grid. It is federating the LHCb data files in a logical namespace used by all LHCb applications. As a replica catalog, it is used for brokering jobs to sites where their input data is meant to be present, but also by jobs for finding alternative replicas if necessary. The LCG File Catalog (LFC) used originally by LHCb and other experiments is now being retired and needs to be replaced. The DIRAC File Catalog (DFC) was developed within the framework of the DIRAC Project and presented during CHEP 2012. From the technical point of view, the code powering the DFC follows an Aspect oriented programming (AOP): each type of entity that is manipulated by the DFC (Users, Files, Replicas, etc) is treated as a separate 'concern' in the AOP terminology. Hence, the database schema can also be adapted to the needs of a Virtual Organization. LHCb opted for a highly tuned MySQL datab...

  7. Design and Implementation of Ceph: A Scalable Distributed File System

    SciTech Connect (OSTI)

    Weil, S A; Brandt, S A; Miller, E L; Long, D E; Maltzahn, C

    2006-04-19

    File system designers continue to look to new architectures to improve scalability. Object-based storage diverges from server-based (e.g. NFS) and SAN-based storage systems by coupling processors and memory with disk drives, delegating low-level allocation to object storage devices (OSDs) and decoupling I/O (read/write) from metadata (file open/close) operations. Even recent object-based systems inherit decades-old architectural choices going back to early UNIX file systems, however, limiting their ability to effectively scale to hundreds of petabytes. We present Ceph, a distributed file system that provides excellent performance and reliability with unprecedented scalability. Ceph maximizes the separation between data and metadata management by replacing allocation tables with a pseudo-random data distribution function (CRUSH) designed for heterogeneous and dynamic clusters of unreliable OSDs. We leverage OSD intelligence to distribute data replication, failure detection and recovery with semi-autonomous OSDs running a specialized local object storage file system (EBOFS). Finally, Ceph is built around a dynamic distributed metadata management cluster that provides extremely efficient metadata management that seamlessly adapts to a wide range of general purpose and scientific computing file system workloads. We present performance measurements under a variety of workloads that show superior I/O performance and scalable metadata management (more than a quarter million metadata ops/sec).

  8. WeatherMaker: Weather file conversion and evaluation

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1999-07-01

    WeatherMaker is a weather-data utility for use with the ENERGY-10 design-tool computer program. The three main features are: Convert--Weather files can be converted from one format to another. For example, a TMY2 format file can be converted to an ENERGY-10 binary file that can be used in a simulation. This binary file can then be converted to a text format that allows it to be read and/or manipulated in WordPad or Excel. Evaluate--ENERGY-10 weather files can be studied in great detail. There are 8 graphical displays of the data that provide insight into the data, and a summary tables that presents results calculated from the hourly data. Adjust--Hourly temperature data can be adjusted starting with hourly data from a nearby TMY2 site. Dry-bulb and wet-bulb temperatures are adjusted up or down as required to match given monthly statistics. This feature can be used to generate weather files for any of 3,958 sites in the US where such monthly statistics are tabulated. The paper shows a variety of results, explains the methods used, and discusses the rationale for making the adjustments. It is anticipated that WeatherMaker will be released by the time of the ASES Solar 99 conference.

  9. Direct transfer of graphene onto flexible substrates

    E-Print Network [OSTI]

    Araujo, Paulo Antonio Trinidade

    In this paper we explore the direct transfer via lamination of chemical vapor deposition graphene onto different flexible substrates. The transfer method investigated here is fast, simple, and does not require an intermediate ...

  10. NERSC HPSS Bandwidth and Transfer Activity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aggregate Transfer Bandwidth This graph shows the aggregate transfer rate to the storage systems as a function of time of day. The red line is the peak bandwidth observed within...

  11. Power transfer through strongly coupled resonances

    E-Print Network [OSTI]

    Kurs, Andr

    2007-01-01

    Using self-resonant coils in a strongly coupled regime, we experimentally demonstrate efficient non-radiative power transfer over distances of up to eight times the radius of the coils. We use this system to transfer 60W ...

  12. Via Electronic Submission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Re: Excess Uranium Management: Effects of DOE Transfers of Excess Uranium on Domestic Uranium Mining, Conversion and Enrichment Industries: Request for Information Dear Mr....

  13. Academic Knowledge Transfer in Social Networks

    E-Print Network [OSTI]

    Slater, Mark David

    2013-01-01

    4.3 Digital Library Requirements . . . . . . . . . . . 4.43.1.1 Digital Libraries . . . . . . . . . . . .A Prototype Personal Digital Library Knowledge Transfer

  14. Waste Feed Delivery Transfer System Analysis

    SciTech Connect (OSTI)

    JULYK, L.J.

    2000-05-05

    This document provides a documented basis for the required design pressure rating and pump pressure capacity of the Hanford Site waste-transfer system in support of the waste feed delivery to the privatization contractor for vitrification. The scope of the analysis includes the 200 East Area double-shell tank waste transfer pipeline system and the associated transfer system pumps for a11 Phase 1B and Phase 2 waste transfers from AN, AP, AW, AY, and A2 Tank Farms.

  15. Submersible canned motor transfer pump

    DOE Patents [OSTI]

    Guardiani, R.F.; Pollick, R.D.; Nyilas, C.P.; Denmeade, T.J.

    1997-08-19

    A transfer pump is described which is used in a waste tank for transferring high-level radioactive liquid waste from a waste tank and having a column assembly, a canned electric motor means, and an impeller assembly with an upper impeller and a lower impeller connected to a shaft of a rotor assembly. The column assembly locates a motor housing with the electric motor means adjacent to the impeller assembly which creates an hydraulic head, and which forces the liquid waste, into the motor housing to cool the electric motor means and to cool and/or lubricate the radial and thrust bearing assemblies. Hard-on-hard bearing surfaces of the bearing assemblies and a ring assembly between the upper impeller and electric motor means grind large particles in the liquid waste flow. Slots in the static bearing member of the radial bearing assemblies further grind down the solid waste particles so that only particles smaller than the clearances in the system can pass there through, thereby resisting damage to and the interruption of the operation of the transfer pump. The column assembly is modular so that sections can be easily assembled, disassembled and/or removed. A second embodiment employs a stator jacket which provides an alternate means for cooling the electric motor means and lubricating and/or cooling the bearing assemblies, and a third embodiment employs a variable level suction device which allows liquid waste to be drawn into the transfer pump from varying and discrete levels in the waste tank. 17 figs.

  16. Enhanced heat transfer using nanofluids

    DOE Patents [OSTI]

    Choi, Stephen U. S. (Lisle, IL); Eastman, Jeffrey A. (Naperville, IL)

    2001-01-01

    This invention is directed to a method of and apparatus for enhancing heat transfer in fluids such as deionized water. ethylene glycol, or oil by dispersing nanocrystalline particles of substances such as copper, copper oxide, aluminum oxide, or the like in the fluids. Nanocrystalline particles are produced and dispersed in the fluid by heating the substance to be dispersed in a vacuum while passing a thin film of the fluid near the heated substance. The fluid is cooled to control its vapor pressure.

  17. 13TechTransfer Success Stories 2012 Everyone has experienced it: The batteries

    E-Print Network [OSTI]

    13TechTransfer Success Stories 2012 Problem Everyone has experienced it: The batteries on your electronic device running out at the most inopportune moment. But what if the batteries had the ability recharging the battery in the process. Sandia, working with Pacific Northwest National Laboratory (PNNL

  18. preprintof25August2009preprintof25August2009 Forster Transfer Outside the Weak-Excitation Limit

    E-Print Network [OSTI]

    Fygenson, Deborah Kuchnir

    used in molecular biophysics to deter- mine structures and dynamics of proteins, DNA, RNA approximation, Forster [15] calculated the rate constant for energy transfer between the donor-excited (D A lifetime observed in the absence of an acceptor, R is the separation of the dyes, and R0 Electronic

  19. Photoinduced Vibrational Coherence Transfer in Molecular Dimers Dmitri S. Kilin, Oleg V. Prezhdo,*, and Michael Schreiber

    E-Print Network [OSTI]

    the extremely efficient use of solar energy seen in nature and formulation of the basic principles of energy the sequence of energy- and electron-transfer events that determine collection and storage of solar energy for novel energy sources drives the design of artificial light-harvesting systems. Understanding

  20. SU-E-T-585: Commissioning of Electron Monte Carlo in Eclipse Treatment Planning System for TrueBeam

    SciTech Connect (OSTI)

    Yang, X; Lasio, G; Zhou, J; Lin, M; Yi, B; Guerrero, M

    2014-06-01

    Purpose: To commission electron Monte Carlo (eMC) algorithm in Eclipse Treatment Planning System (TPS) for TrueBeam Linacs, including the evaluation of dose calculation accuracy for small fields and oblique beams and comparison with the existing eMC model for Clinacs. Methods: Electron beam percent-depth-dose (PDDs) and profiles with and without applicators, as well as output factors, were measured from two Varian TrueBeam machines. Measured data were compared against the Varian TrueBeam Representative Beam Data (VTBRBD). The selected data set was transferred into Eclipse for beam configuration. Dose calculation accuracy from eMC was evaluated for open fields, small cut-out fields, and oblique beams at different incident angles. The TrueBeam data was compared to the existing Clinac data and eMC model to evaluate the differences among Linac types. Results: Our measured data indicated that electron beam PDDs from our TrueBeam machines are well matched to those from our Varian Clinac machines, but in-air profiles, cone factors and open-filed output factors are significantly different. The data from our two TrueBeam machines were well represented by the VTBRBD. Variations of TrueBeam PDDs and profiles were within the 2% /2mm criteria for all energies, and the output factors for fields with and without applicators all agree within 2%. Obliquity factor for two clinically relevant applicator sizes (1010 and 1515 cm{sup 2}) and three oblique angles (15, 30, and 45 degree) were measured for nominal R100, R90, and R80 of each electron beam energy. Comparisons of calculations using eMC of obliquity factors and cut-out factors versus measurements will be presented. Conclusion: eMC algorithm in Eclipse TPS can be configured using the VTBRBD. Significant differences between TrueBeam and Clinacs were found in in-air profiles and open field output factors. The accuracy of the eMC algorithm was evaluated for a wide range of cut-out factors and oblique incidence.