Sample records for field measurements alkalinity

  1. Surfactant-enhanced alkaline flooding field project. Annual report

    SciTech Connect (OSTI)

    French, T.R.; Josephson, C.B.

    1993-12-01T23:59:59.000Z

    The Tucker sand from Hepler field, Crawford County, Kansas, was characterized using routine and advanced analytical methods. The characterization is part of a chemical flooding pilot test to be conducted in the field, which is classified as a DOE Class I (fluvial-dominated delta) reservoir. Routine and advanced methods of characterization were compared. Traditional wireline logs indicate that the reservoir is vertically compartmentalized on the foot scale. Routine core analysis, X-ray computed tomography (CT), minipermeameter measurement, and petrographic analysis indicate that compartmentalization and lamination extend to the microscale. An idealized model of how the reservoir is probably structured (complex layering with small compartments) is presented. There was good agreement among the several methods used for characterization, and advanced characterization methods adequately explained the coreflood and tracer tests conducted with short core plugs. Tracer and chemical flooding tests were conducted in short core plugs while monitoring with CT to establish flow patterns and to monitor oil saturations in different zones of the core plugs. Channeling of injected fluids occurred in laboratory experiments because, on core plug scale, permeability streaks extended the full length of the core plugs. A graphic example of how channeling in field core plugs can affect oil recovery during chemical injection is presented. The small scale of compartmentalization indicated by plugs of the Tucker sand may actually help improve sweep between wells. The success of field-scale waterflooding and the fluid flow patterns observed in highly heterogeneous outcrop samples are reasons to expect that reservoir flow patterns are different from those observed with short core plugs, and better sweep efficiency may be obtained in the field than has been observed in laboratory floods conducted with short core plugs.

  2. Magnetic Field Measurement System

    SciTech Connect (OSTI)

    Kulesza, Joe; Johnson, Eric; Lyndaker, Aaron; Deyhim, Alex; Waterman, Dave; Blomqvist, K. Ingvar [Advanced Design Consulting USA, 126 Ridge Road, P.O. Box 187, Lansing, NY 14882 (United States); Dunn, Jonathan Hunter [MAX-lab, SE-221 00 Lund (Sweden)

    2007-01-19T23:59:59.000Z

    A magnetic field measurement system was designed, built and installed at MAX Lab, Sweden for the purpose of characterizing the magnetic field produced by Insertion Devices (see Figure 1). The measurement system consists of a large granite beam roughly 2 feet square and 14 feet long that has been polished beyond laboratory grade for flatness and straightness. The granite precision coupled with the design of the carriage yielded minimum position deviations as measured at the probe tip. The Hall probe data collection and compensation technique allows exceptional resolution and range while taking data on the fly to programmable sample spacing. Additional flip coil provides field integral data.

  3. Detailed evaluation of the West Kiehl alkaline-surfactant-polymer field project and its application to mature Minnelusa waterfloods. Annual report for the period January 1993--December 1993

    SciTech Connect (OSTI)

    Pitts, M.J.; Surkalo, H.; Mundorf, W.R.

    1994-11-01T23:59:59.000Z

    The combination of an interfacial tension agent and a mobility control agent has the potential to produce additional oil beyond a waterflood. The West Kiehl alkaline-surfactant-polymer project is the most advanced application of this chemical enhanced oil recovery technique. The West Kiehl alkaline-surfactant-polymer flood was initiated in September 1987 as a secondary application after primary recovery. A preliminary analysis of the West Kiehl alkaline-surfactant-polymer flood indicates that incremental oil of 20% of the original stock tank oil in place will be produced above waterflooding. The cost of the incremental oil will be less than $2.50 per incremental barrel. A statistical analysis of approximately 120 Minnelusa oil fields in the Powder River Basin indicates that the original stock tank oil in place exceeds one billion barrels. If the enhanced oil recovery technology implemented at West Kiehl field could be successfully applied to these fields, the potential incremental oil recovery would approach 200 million barrels. {open_quotes}Detailed Evaluation of the West Kiehl Alkaline-Surfactant-Polymer Field Project and Its Application to Mature Minnelusa Waterfloods{close_quotes} objective is to evaluate both the field performance of the alkaline-surfactant-polymer enhanced oil recovery technology as well as its potential application to other Minnelusa oil fields.

  4. Fermion measure and axion fields

    E-Print Network [OSTI]

    Mitra, P

    2015-01-01T23:59:59.000Z

    It is known from path integral studies of the chiral anomaly that the fermion measure has to depend on gauge fields interacting with the fermion. It is argued here that in the presence of axion fields interacting with the fermion, they too may be involved in the measure, with unexpected consequences.

  5. Measurements of magnetic field alignment

    SciTech Connect (OSTI)

    Kuchnir, M.; Schmidt, E.E.

    1987-11-06T23:59:59.000Z

    The procedure for installing Superconducting Super Collider (SSC) dipoles in their respective cryostats involves aligning the average direction of their field with the vertical to an accuracy of 0.5 mrad. The equipment developed for carrying on these measurements is described and the measurements performed on the first few prototypes SSC magnets are presented. The field angle as a function of position in these 16.6 m long magnets is a characteristic of the individual magnet with possible feedback information to its manufacturing procedure. A comparison of this vertical alignment characteristic with a magnetic field intensity (by NMR) characteristic for one of the prototypes is also presented. 5 refs., 7 figs.

  6. A new magnetic field integral measurement system

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements. b. Second field integral (horizontal and vertical) measurements. c. Multipole components of first field integral measurements. 2. Translation Coil a. Multipole...

  7. Alkaline flooding injection strategy

    SciTech Connect (OSTI)

    French, T.R.; Josephson, C.B.

    1992-03-01T23:59:59.000Z

    The objective of this project is to improved alkali-surfactant flooding methods, and this includes determining the proper design of injection strategy. Several different injection strategies have been used or suggested for recovering heavy oils with surfactant-enhanced alkaline flooding methods. Oil recovery was compared for four different injection strategies: (1) surfactant followed by polymer, (2) surfactant followed by alkaline polymer, (3) alkaline surfactant followed by polymer, and (4) alkali, surfactant, and polymer mixed in a single formulation. The effect of alkaline preflush was also studied under two different conditions. All of the oil recovery experiments were conducted under optimal conditions with a viscous, non-acidic oil from Hepler (KS) oil field. The coreflood experiments were conducted with Berea sandstone cores since field core was not available in sufficient quantity for coreflood tests. The Tucker sand of Hepler field is a Class I fluvial dominated deltaic reservoir, as classified by the Department of Energy, which has been selected as the site of a DOE-sponsored field pilot test.

  8. Field Calibration Facilities for Environmental Measurement of...

    Broader source: Energy.gov (indexed) [DOE]

    the facilities. Field Calibration Facilities for Environmental Measurement of Radium, Thorium, and Potassium (October 2013) More Documents & Publications Calibration Model...

  9. CORONAL MAGNETIC FIELD MEASUREMENTS THROUGH GYRORESONANCE EMISSION

    E-Print Network [OSTI]

    White, Stephen

    Chapter 5 CORONAL MAGNETIC FIELD MEASUREMENTS THROUGH GYRORESONANCE EMISSION Stephen M. White This article reviews the use of gyroresonance emission at radio wavelengths to measure coronal magnetic fields. Keywords: Sun, solar corona, solar magnetic fields, solar radio emission Introduction Since the realization

  10. Lunar magnetic field measurements with a cubesat

    E-Print Network [OSTI]

    Garrick-Bethell, Ian

    We have developed a mission concept that uses 3-unit cubesats to perform new measurements of lunar magnetic fields, less than 100 meters above the Moon’s surface. The mission calls for sending the cubesats on impact ...

  11. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    alkaline province of West Texas, near the northern terminusthe Diablo Plateau, West Texas • the lujavritic-tinguaitic

  12. Measurement of Magnetic Field Using Collaborative AUVs

    E-Print Network [OSTI]

    Idaho, University of

    Measurement of Magnetic Field Using Collaborative AUVs Jesse Pentzer, Brendan Crosbie, Thomas Bean, tests using multiple types of AUVs to individually sample bathymetric data and water mass properties, salinity, and temperature data was reported [2]. In 2007, an AUV was equipped to measure water properties

  13. Reservoir Characterization of Bridgeport and Cypress Sandstones in Lawrence Field Illinois to Improve Petroleum Recovery by Alkaline-Surfactant-Polymer Flood

    SciTech Connect (OSTI)

    Seyler, Beverly; Grube, John; Huff, Bryan; Webb, Nathan; Damico, James; Blakley, Curt; Madhavan, Vineeth; Johanek, Philip; Frailey, Scott

    2012-12-21T23:59:59.000Z

    Within the Illinois Basin, most of the oilfields are mature and have been extensively waterflooded with water cuts that range up to 99% in many of the larger fields. In order to maximize production of significant remaining mobile oil from these fields, new recovery techniques need to be researched and applied. The purpose of this project was to conduct reservoir characterization studies supporting Alkaline-Surfactant-Polymer Floods in two distinct sandstone reservoirs in Lawrence Field, Lawrence County, Illinois. A project using alkaline-surfactantpolymer (ASP) has been established in the century old Lawrence Field in southeastern Illinois where original oil in place (OOIP) is estimated at over a billion barrels and 400 million barrels have been recovered leaving more than 600 million barrels as an EOR target. Radial core flood analysis using core from the field demonstrated recoveries greater than 20% of OOIP. While the lab results are likely optimistic to actual field performance, the ASP tests indicate that substantial reserves could be recovered even if the field results are 5 to 10% of OOIP. Reservoir characterization is a key factor in the success of any EOR application. Reservoirs within the Illinois Basin are frequently characterized as being highly compartmentalized resulting in multiple flow unit configurations. The research conducted on Lawrence Field focused on characteristics that define reservoir compartmentalization in order to delineate preferred target areas so that the chemical flood can be designed and implemented for the greatest recovery potential. Along with traditional facies mapping, core analyses and petrographic analyses, conceptual geological models were constructed and used to develop 3D geocellular models, a valuable tool for visualizing reservoir architecture and also a prerequisite for reservoir simulation modeling. Cores were described and potential permeability barriers were correlated using geophysical logs. Petrographic analyses were used to better understand porosity and permeability trends in the region and to characterize barriers and define flow units. Diagenetic alterations that impact porosity and permeability include development of quartz overgrowths, sutured quartz grains, dissolution of feldspar grains, formation of clay mineral coatings on grains, and calcite cementation. Many of these alterations are controlled by facies. Mapping efforts identified distinct flow units in the northern part of the field showing that the Pennsylvanian Bridgeport consists of a series of thick incised channel fill sequences. The sandstones are about 75-150 feet thick and typically consist of medium grained and poorly sorted fluvial to distributary channel fill deposits at the base. The sandstones become indistinctly bedded distributary channel deposits in the main part of the reservoir before fining upwards and becoming more tidally influenced near their top. These channel deposits have core permeabilities ranging from 20 md to well over 1000 md. The tidally influenced deposits are more compartmentalized compared to the thicker and more continuous basal fluvial deposits. Fine grained sandstones that are laterally equivalent to the thicker channel type deposits have permeabilities rarely reaching above 250 md. Most of the unrecovered oil in Lawrence Field is contained in Pennsylvanian Age Bridgeport sandstones and Mississippian Age Cypress sandstones. These reservoirs are highly complex and compartmentalized. Detailed reservoir characterization including the development of 3-D geologic and geocellular models of target areas in the field were completed to identify areas with the best potential to recover remaining reserves including unswept and by-passed oil. This project consisted of tasks designed to compile, interpret, and analyze the data required to conduct reservoir characterization for the Bridgeport and Cypress sandstones in pilot areas in anticipation of expanded implementation of ASP flooding in Lawrence Field. Geologic and geocellular modeling needed for reservoir characterization and res

  14. Anodes for alkaline electrolysis

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev (Latham, NY)

    2011-02-01T23:59:59.000Z

    A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

  15. Oceanic CO{sub 2} measurements for the WOCE hydrological survey in the Pacific Ocean; Shipboard alkalinity analyses during 1991 and 1992. Final technical report, February 1, 1992--July 31, 1994

    SciTech Connect (OSTI)

    Keeling, C.D.

    1998-07-01T23:59:59.000Z

    This research group contributed titration alkalinity analyses to transects of the WOCE Hydrological Survey during 1991 and 1992. The results have been transmitted to the Carbon Dioxide Information and Analysis Center (CDIAC) of the Department of Energy in a technical data report having two parts: Oceanic CO{sub 2} Measurements for the WOCE Hydrographic Survey of the Pacific Ocean, 1990--1991: Shipboard Analyses During 1991 and 1992, Part 1. Alkalinity Measurements on TUNES, Leg 3, 1991. Oceanic CO{sub 2} Measurements for the WOCE Hydrographic Survey of the Pacific Ocean, 1990--1991: Shipboard Analyses During 1991 and 1992, Part 2. Alkalinity Measurements on CGC92, Legs 1 and 2, 1992. This report contains a paper entitled, ``Total dissolved inorganic carbon measurements made on WOCE leg P13`` by Andrew G. Dickson. A brief description of how these measurements were made and calibrated has been provided along with a statement of the quality of the measurements. The data themselves have been sent to ORNL CDIAC for archival and distribution.

  16. Alkalinity tolerance of peach rootstocks 

    E-Print Network [OSTI]

    Shi, Yan

    1992-01-01T23:59:59.000Z

    be substituted for chlorophyll analyses in the alkalinity tolerance evaluation in sorghum, soybeans and citrus (DeCianzio et al. , 1979; Mckenzie et al. , 1984; Sudahono, 1991). Active Fe, a form of Fe effective in chlorophyll formation, is proportional... 1992 ABSTRACT Alkalinity Tolerance of Peach Rootstocks. (May 1992) Yan Shi, B. S. , Fujian Agricultural College Chair of Advisory Committee: Dr. David H. Byrne Peaches suffer from Fe chlorosis when grown in alkaline soils. A range of alkalinity...

  17. Field Emission Measurements from Niobium Electrodes

    SciTech Connect (OSTI)

    M. BastaniNejad, P.A. Adderley, J. Clark, S. Covert, J. Hansknecht, C. Hernandez-Garcia, R. Mammei, M. Poelker

    2011-03-01T23:59:59.000Z

    Increasing the operating voltage of a DC high voltage photogun serves to minimize space charge induced emittance growth and thereby preserve electron beam brightness, however, field emission from the photogun cathode electrode can pose significant problems: constant low level field emission degrades vacuum via electron stimulated desorption which in turn reduces photocathode yield through chemical poisoning and/or ion bombardment and high levels of field emission can damage the ceramic insulator. Niobium electrodes (single crystal, large grain and fine grain) were characterized using a DC high voltage field emission test stand at maximum voltage -225kV and electric field gradient > 10MV/m. Niobium electrodes appear to be superior to diamond-paste polished stainless steel electrodes.

  18. Quantitative, directional measurement of electric field heterogeneity in the

    E-Print Network [OSTI]

    Boxer, Steven G.

    Quantitative, directional measurement of electric field heterogeneity in the active site SUMMARY Extensive structural studies of enzymes have revealed that biological catalysis occurs within substantial electrostatic field heterogeneity, widely differing sensitivities of discrete probes to a set

  19. Earth's Magnetic Field Measurements for the LCLS Undulators

    SciTech Connect (OSTI)

    Hacker, Kirsten

    2010-12-13T23:59:59.000Z

    Measurements of the earth's magnetic field at several locations at SLAC were conducted to determine the possible field error contribution from tuning the undulators in a location with a different magnetic field than that which will be found in the undulator hall. An average difference of 0.08 {+-} 0.04 Gauss has been measured between the downward earth's field components in the test facility and SLAC tunnel locations.

  20. Role of Photoexcitation and Field Ionization in the Measurement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Field Ionization in the Measurement of Accurate Oxide Stoichiometry by Laser-Assisted Atom Probe Abstract: Pulsed lasers extend the high spatial and mass...

  1. Measuring Residential Ventilation System Airflows: Part 2 -Field

    E-Print Network [OSTI]

    1 Measuring Residential Ventilation System Airflows: Part 2 - Field Evaluation of Airflow Meter Residential Ventilation System Airflows: Part 2 - Field Evaluation of Airflow Meter Devices and System Flow, mechanical ventilation, measurement, ASHRAE 62.2, flow hood ABSTRACT The 2008 California State Energy Code

  2. Molecular-scale measurements of electric fields at electrochemical interfaces.

    SciTech Connect (OSTI)

    Hayden, Carl C.; Farrow, Roger L.

    2011-01-01T23:59:59.000Z

    Spatially resolved measurements of electric fields at electrochemical interfaces would be a critical step toward further understanding and modeling the detailed structure of electric double layers. The goal of this project was to perform proof-of-principle experiments to demonstrate the use of field-sensitive dyes for optical measurements of fields in electrochemical systems. A confocal microscope was developed that provides sensitive detection of the lifetime and high resolution spectra of excited fluorescence for dyes tethered to electrically conductive surfaces. Excited state lifetimes for the dyes were measured and found to be relatively unquenched when linked to indium tin oxide, but strongly quenched on gold surfaces. However, our fluorescence detection is sufficiently sensitive to measure spectra of submonolayer dye coatings even when the fluorescence was strongly quenched. Further work to create dye labeled interfaces on flat, uniform and durable substrates is necessary to make electric field measurements at interfaces using field sensitive dyes.

  3. Alkalinity tolerance of peach rootstocks

    E-Print Network [OSTI]

    Shi, Yan

    1992-01-01T23:59:59.000Z

    1992 ABSTRACT Alkalinity Tolerance of Peach Rootstocks. (May 1992) Yan Shi, B. S. , Fujian Agricultural College Chair of Advisory Committee: Dr. David H. Byrne Peaches suffer from Fe chlorosis when grown in alkaline soils. A range of alkalinity... could be assessed by leaf visual-chlorosis rating and Sped-502 reading instead of extractable leaf-chlorophyll concentration or leaf Fe concentration. Some modifications were suggested for the future evaluation. Bicarbonate was a major factor which...

  4. Measuring Oscillatory Velocity Fields Due to Swimming Algae

    E-Print Network [OSTI]

    Guasto, Jeffrey S; Gollub, J P

    2010-01-01T23:59:59.000Z

    In this fluid dynamics video, we present the first time-resolved measurements of the oscillatory velocity field induced by swimming unicellular microorganisms. Confinement of the green alga C. reinhardtii in stabilized thin liquid films allows simultaneous tracking of cells and tracer particles. The measured velocity field reveals complex time-dependent flow structures, and scales inversely with distance. The instantaneous mechanical power generated by the cells is measured from the velocity fields and peaks at 15 fW. The dissipation per cycle is more than four times what steady swimming would require.

  5. Field measurements in the Fermilab electron cooling solenoid prototype

    SciTech Connect (OSTI)

    A. C. Crawford et al.

    2003-10-02T23:59:59.000Z

    To increase the Tevatron luminosity, Fermilab is developing a high-energy electron cooling system [1] to cool 8.9-GeV/c antiprotons in the Recycler ring. The schematic layout of the Recycler Electron Cooling (REC) system is shown in Figure 1. Cooling of antiprotons requires a round electron beam with a small angular spread propagating through a cooling section with a kinetic energy of 4.3 MeV. To confine the electron beam tightly and to keep its transverse angles below 10{sup -4} rad, the cooling section will be immersed into a solenoidal field of 50-150G. As part of the R&D effort, a cooling section prototype consisting of 9 modules (90% of the total length of a future section) was assembled and measured. This paper describes the technique of measuring and adjusting the magnetic field quality in the cooling section and presents preliminary results of solenoid prototype field measurements. The design of the cooling section solenoid is discussed in Chapter 2. Chapter 3 describes details of a dedicated measurement system, capable of measuring small transverse field components, while the system's measurement errors are analyzed in Chapter 4. Chapter 5 contains measured field distributions of individual elements of the cooling section as well as an evaluation of the magnetic shielding efficiency. An algorithm of field adjustments for providing lowest possible electron trajectory perturbations is proposed in Chapter 6; also, this chapter shows the results of our first attempts of implementing the algorithm.

  6. Measuring Helical FCG Voltage with an Electric Field Antenna

    SciTech Connect (OSTI)

    White, A D; Anderson, R A; Javedani, J B; Reisman, D B; Goerz, D A; Ferriera, A J; Speer, R D

    2011-08-01T23:59:59.000Z

    A method of measuring the voltage produced by a helical explosive flux compression generator using a remote electric field antenna is described in detail. The diagnostic has been successfully implemented on several experiments. Measured data from the diagnostic compare favorably with voltages predicted using the code CAGEN, validating our predictive modeling tools. The measured data is important to understanding generator performance, and is measured with a low-risk, minimally intrusive approach.

  7. Sub-wavelength position measurements with running wave driving fields

    E-Print Network [OSTI]

    J. Evers; S. Qamar

    2009-01-29T23:59:59.000Z

    A scheme for sub-wavelength position measurements of quantum particles is discussed, which operates with running-wave laser fields as opposed to standing wave fields proposed in previous setups. The position is encoded in the phase of the applied fields rather than in the spatially modulated intensity of a standing wave. Therefore, disadvantages of standing wave schemes such as cases where the atom remains undetected since it is at a node of the standing wave field are avoided. Reversing the directions of parts of the driving laser fields allows to switch between different magnification levels, and thus to optimize the localization.

  8. New limits on extragalactic magnetic fields from rotation measures

    E-Print Network [OSTI]

    Pshirkov, Maxim S; Urban, Federico R

    2015-01-01T23:59:59.000Z

    We take advantage of the wealth of rotation measures data contained in the NVSS catalogue to derive new, statistically robust, upper limits on the strength of extragalactic magnetic fields. We simulate the extragalactic contribution to the rotation measures for a given field strength and correlation length, by assuming that the electron density follows the distribution of Lyman-$\\alpha$ clouds. Based on the observation that rotation measures from low-luminosity distant radio sources do not exhibit any trend with redshift, while the extragalactic contribution instead grows with distance, we constrain fields with Mpc coherence length to be below 1.2 nG at the $2\\sigma$ level, and fields coherent across the entire observable Universe below 0.5 nG. These limits do not depend on the particular origin of these cosmological fields.

  9. Magnetic field measurements on the sun and implications for stellar magnetic field observations

    SciTech Connect (OSTI)

    Sun, W.H.; Giampapa, M.S.; Worden, S.P.

    1987-01-01T23:59:59.000Z

    Results of solar magnetic field measurements in plages, sunspot umbrae, and sunspot penumbrae using high spectral resolution, unpolarized infrared H band spectral data are presented. A Fourier deconvolution analysis scheme similar to that utilized for stellar magnetic field measurements is adopted. As an example, a field strength of 3240 + or - 450 G is determined in a sunspot umbra combined with a value of 2000 + or - 180 G in the associated penumbra. These values are compared with a direct measurement of the spot umbra and penumbra field strengths based on the observed separation of the Zeeman components of the magnetically sensitive lines. Possible origins for the discrepancy between the results inferred by these two different techniques are discussed. The Fourier analysis results confirm the widespread occurrence of kilogauss level fields in the solar photosphere. The implications of the solar results for stellar magnetic field measurements are considered. 45 references.

  10. VEHICLE EMISSIONS AND TRAFFIC MEASURES: EXPLORATORY ANALYSIS OF FIELD

    E-Print Network [OSTI]

    Frey, H. Christopher

    VEHICLE EMISSIONS AND TRAFFIC MEASURES: EXPLORATORY ANALYSIS OF FIELD OBSERVATIONS AT SIGNALIZED between vehicle emissions and traffic control measures is an important step toward reducing the potential roadway design and traffic control, have the ability to reduce vehicle emissions. However, current vehicle

  11. Field quality measurements of a 2-Tesla transmission line magnet

    SciTech Connect (OSTI)

    Velev, G.V.; Foster, W.; Kashikhin, V.; Mazur, P.; Oleck, A.; Piekarz, H.; Schlabach, P.; Sylvester, C.; /Fermilab; Wake, M.; /KEK, Tsukuba

    2005-09-01T23:59:59.000Z

    A prototype 2-Tesla superconducting transmission line magnet for future hadron colliders was designed, built and tested at Fermilab. The 1.5 m long, combined-function gradient-dipole magnet has a vertical pole aperture of 20 mm. To measure the magnetic field quality in such a small magnet aperture, a specialized rotating coil of 15.2 mm diameter, 0.69 m long was fabricated. Using this probe, a program of magnetic field quality measurements was successfully performed. Results of the measurements are presented and discussed.

  12. High-frequency electric field measurement using a toroidal antenna

    DOE Patents [OSTI]

    Lee, Ki Ha (Lafayette, CA)

    2002-01-01T23:59:59.000Z

    A simple and compact method and apparatus for detecting high frequency electric fields, particularly in the frequency range of 1 MHz to 100 MHz, uses a compact toroidal antenna. For typical geophysical applications the sensor will be used to detect electric fields for a wide range of spectrum starting from about 1 MHz, in particular in the frequency range between 1 to 100 MHz, to detect small objects in the upper few meters of the ground. Time-varying magnetic fields associated with time-varying electric fields induce an emf (voltage) in a toroidal coil. The electric field at the center of (and perpendicular to the plane of) the toroid is shown to be linearly related to this induced voltage. By measuring the voltage across a toroidal coil one can easily and accurately determine the electric field.

  13. NEAR-FIELD SCANNING MICROWAVE MICROSCOPY: MEASURING LOCAL MICROWAVE PROPERTIES AND ELECTRIC FIELD DISTRIBUTIONS

    E-Print Network [OSTI]

    Anlage, Steven

    WEIF-49 NEAR-FIELD SCANNING MICROWAVE MICROSCOPY: MEASURING LOCAL MICROWAVE PROPERTIES AND ELECTRIC>;ics, University of Maryland, College Park, MD 2OY@-4lll, USA Abstract We describe the near-field scanning methods of scanning probe microscopy have been developed. Generally spea- king one can divide

  14. Near field optical probe for critical dimension measurements

    DOE Patents [OSTI]

    Stallard, B.R.; Kaushik, S.

    1999-05-18T23:59:59.000Z

    A resonant planar optical waveguide probe for measuring critical dimensions on an object in the range of 100 nm and below is disclosed. The optical waveguide includes a central resonant cavity flanked by Bragg reflector layers with input and output means at either end. Light is supplied by a narrow bandwidth laser source. Light resonating in the cavity creates an evanescent electrical field. The object with the structures to be measured is translated past the resonant cavity. The refractive index contrasts presented by the structures perturb the field and cause variations in the intensity of the light in the cavity. The topography of the structures is determined from these variations. 8 figs.

  15. Estimating of pulsed electric fields using optical measurements.

    SciTech Connect (OSTI)

    Flanagan, Timothy McGuire; Chantler, Gary R.

    2013-09-01T23:59:59.000Z

    We performed optical electric field measurements ion nanosecond time scales using the electrooptic crystal beta barium borate (BBO). Tests were based on a preliminary bench top design intended to be a proofofprinciple stepping stone towards a modulardesign optical Efield diagnostic that has no metal in the interrogated environment. The long term goal is to field a modular version of the diagnostic in experiments on large scale xray source facilities, or similarly harsh environments.

  16. LIDAR Wind Speed Measurements of Evolving Wind Fields

    SciTech Connect (OSTI)

    Simley, E.; Pao, L. Y.

    2012-07-01T23:59:59.000Z

    Light Detection and Ranging (LIDAR) systems are able to measure the speed of incoming wind before it interacts with a wind turbine rotor. These preview wind measurements can be used in feedforward control systems designed to reduce turbine loads. However, the degree to which such preview-based control techniques can reduce loads by reacting to turbulence depends on how accurately the incoming wind field can be measured. Past studies have assumed Taylor's frozen turbulence hypothesis, which implies that turbulence remains unchanged as it advects downwind at the mean wind speed. With Taylor's hypothesis applied, the only source of wind speed measurement error is distortion caused by the LIDAR. This study introduces wind evolution, characterized by the longitudinal coherence of the wind, to LIDAR measurement simulations to create a more realistic measurement model. A simple model of wind evolution is applied to a frozen wind field used in previous studies to investigate the effects of varying the intensity of wind evolution. LIDAR measurements are also evaluated with a large eddy simulation of a stable boundary layer provided by the National Center for Atmospheric Research. Simulation results show the combined effects of LIDAR errors and wind evolution for realistic turbine-mounted LIDAR measurement scenarios.

  17. Net alkalinity and net acidity 2: Practical considerations Carl S. Kirby a,*, Charles A. Cravotta III b,1

    E-Print Network [OSTI]

    Kirby, Carl S.

    Net alkalinity and net acidity 2: Practical considerations Carl S. Kirby a,*, Charles A. Cravotta of the sample. The Hot Acidity directly measures net acidity (=Ã?net alkalinity). Samples that had near-neutral p in their alkalinities and dissolved Fe, Mn, and Al concentrations. Hot Acidity was approximately equal to net acidity

  18. Triggering for Magnetic Field Measurements of the LCLS Undulators

    SciTech Connect (OSTI)

    Hacker, Kirsten

    2010-12-13T23:59:59.000Z

    A triggering system for magnetic field measurements of the LCLS undulators has been built with a National Instruments PXI-1002 and a Xylinx FPGA board. The system generates single triggers at specified positions, regardless of encoder sensor jitter about a linear scale.

  19. Constraining Cosmic Magnetic Fields by a Measurement of

    E-Print Network [OSTI]

    Erdmann, Martin

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 7 Energy-Energy-Correlations 51 7.1 Definition of Energy-EnergyConstraining Cosmic Magnetic Fields by a Measurement of Energy-Energy-Correlations with the Pierre Ultra High Energy Cosmic Rays 3 2.1 Cosmic Rays with Energies below 4 Ee

  20. Measurement of Gravitomagnetic and Acceleration Fields Around Rotating Superconductors

    E-Print Network [OSTI]

    M. Tajmar; F. Plesescu; B. Seifert; K. Marhold

    2006-10-17T23:59:59.000Z

    It is well known that a rotating superconductor produces a magnetic field proportional to its angular velocity. The authors conjectured earlier, that in addition to this so-called London moment, also a large gravitomagnetic field should appear to explain an apparent mass increase of Niobium Cooper-pairs. A similar field is predicted from Einstein's general relativity theory and the presently observed amount of dark energy in the universe. An experimental facility was designed and built to measure small acceleration fields as well as gravitomagnetic fields in the vicinity of a fast rotating and accelerating superconductor in order to detect this so-called gravitomagnetic London moment. This paper summarizes the efforts and results that have been obtained so far. Measurements with Niobium superconductors indeed show first signs which appear to be within a factor of 2 of our theoretical prediction. Possible error sources as well as the experimental difficulties are reviewed and discussed. If the gravitomagnetic London moment indeed exists, acceleration fields could be produced in a laboratory environment.

  1. Alkaline solution absorption of carbon dioxide method and apparatus

    DOE Patents [OSTI]

    Hobbs, D.T.

    1991-01-01T23:59:59.000Z

    Disclosed is a method for measuring the concentration of hydroxides (or pH) in alkaline solutions, using the tendency of hydroxides to adsorb CO{sub 2}. The method comprises passing CO{sub 2} over the surface of an alkaline solution in a remote tank before and after measurements of the CO{sub 2} concentration. Comparison of the measurements yields the adsorption fraction from which the hydroxide concentration can be calculated using a correlation of hydroxide or pH to adsorption fraction. A schematic is given of a process system according to a preferred embodiment of the invention. 2 figs.

  2. Measuring the Earth's gravity field with cold atom interferometers

    E-Print Network [OSTI]

    Carraz, Olivier; Massotti, Luca; Haagmans, Roger; Silvestrin, Pierluigi

    2015-01-01T23:59:59.000Z

    The scope of the paper is to propose different concepts for future space gravity missions using Cold Atom Interferometers (CAI) for measuring the diagonal elements of the gravity gradient tensor, the spacecraft angular velocity and the spacecraft acceleration. The aim is to achieve better performance than previous space gravity missions due to a very low white noise spectral behaviour of the CAI instrument and a very high common mode rejection, with the ultimate goals of determining the fine structures of the gravity field with higher accuracy than GOCE and detecting time-variable signals in the gravity field.

  3. Verifying a Simplified Fuel Oil Flow Field Measurement Protocol

    SciTech Connect (OSTI)

    Henderson, H.; Dentz, J.; Doty, C.

    2013-07-01T23:59:59.000Z

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  4. ANGULAR MEASUREMENTS OF HTS CRITICAL CURRENT FOR HIGH FIELD SOLENOIDS

    SciTech Connect (OSTI)

    Turrioni, D.; Barzi, E.; Lamm, M.; Lombardo, V.; Zlobin, A. V. [Fermi National Accelerator Laboratory Batavia, Illinois, 60510 (United States); Thieme, C. [American Superconductor (AMSC) Westborough, MA, 01581 (United States)

    2008-03-03T23:59:59.000Z

    An experiment is in the works at Fermilab to confirm that ionization cooling is an efficient way to shrink the size of a muon beam. This would pave the way for Muon Collider machines, which however require in their last stages of acceleration very high field solenoids. The use of high temperature superconducting materials (HTS) is being considered for these magnets using Helium or higher temperature refrigeration. A sample holder was designed to perform critical current (I{sub c}) measurements of HTS conductors under externally applied magnetic fields varying from zero to 90 degree with respect to the c-axis. This was performed in an ample range of temperatures and magnetic field values. A description of the test setup and results for (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub x} (BSCCO-2223) tapes, and Second Generation HTS in the form of 348 superconductor are presented.

  5. The IMCA: A field instrument for uranium enrichment measurements

    SciTech Connect (OSTI)

    Gardner, G.H.; Koskelo, M.; Moeslinger, M. [Canberra Industries, Meriden, CT (United States); Mayer, R.L. II; McGinnis, B.R. [Lockheed Martin Utility Services, Piketon, OH (United States). Portsmouth Gaseous Diffusion Plant; Wishard, B. [International Atomic Energy Agency, Vienna (Austria)

    1996-12-31T23:59:59.000Z

    The IMCA (Inspection Multi-Channel Analyzer) is a portable gamma-ray spectrometer designed to measure the enrichment of uranium either in a laboratory or in the field. The IMCA consists of a Canberra InSpector Multi-Channel Analyzer, sodium iodide or a planar germanium detector, and special application software. The system possesses a high degree of automation. The IMCA uses the uranium enrichment meter principle, and is designed to meet the International Atomic Energy Agency (IAEA) requirements for the verification of enriched uranium materials. The IMCA is available with MGA plutonium isotopic analysis software or MGAU uranium analysis software as well. In this paper, the authors present a detailed description of the hardware and software of the IMCA system, as well as results from preliminary measurements testing compliance of IMCA with IAEA requirements using uranium standards and UF6 cylinders. Measurements performed on UF6 cylinders in the field under variable environmental conditions (temperatures ranging from 0 to 35 C) have shown that good results can be achieved. The enrichment of UF6 contained in the cylinder is determined by using calibration constants generated from an instrument calibration, using traceable uranium oxide standards, performed in the laboratory under controlled environmental conditions. The IMCA software is designed to make the necessary matrix and container corrections to ensure that accurate results are achieved in the field.

  6. Nucleotide sequences encoding a thermostable alkaline protease

    DOE Patents [OSTI]

    Wilson, David B. (Ithaca, NY); Lao, Guifang (Bethesda, MD)

    1998-01-01T23:59:59.000Z

    Nucleotide sequences, derived from a thermophilic actinomycete microorganism, which encode a thermostable alkaline protease are disclosed. Also disclosed are variants of the nucleotide sequences which encode a polypeptide having thermostable alkaline proteolytic activity. Recombinant thermostable alkaline protease or recombinant polypeptide may be obtained by culturing in a medium a host cell genetically engineered to contain and express a nucleotide sequence according to the present invention, and recovering the recombinant thermostable alkaline protease or recombinant polypeptide from the culture medium.

  7. Field Test of Measurement-Device-Independent Quantum Key Distribution

    E-Print Network [OSTI]

    Yan-Lin Tang; Hua-Lei Yin; Si-Jing Chen; Yang Liu; Wei-Jun Zhang; Xiao Jiang; Lu Zhang; Jian Wang; Li-Xing You; Jian-Yu Guan; Dong-Xu Yang; Zhen Wang; Hao Liang; Zhen Zhang; Nan Zhou; Xiongfeng Ma; Teng-Yun Chen; Qiang Zhang; Jian-Wei Pan

    2014-08-11T23:59:59.000Z

    A main type of obstacles of practical applications of quantum key distribution (QKD) network is various attacks on detection. Measurement-device-independent QKD (MDIQKD) protocol is immune to all these attacks and thus a strong candidate for network security. Recently, several proof-of-principle demonstrations of MDIQKD have been performed. Although novel, those experiments are implemented in the laboratory with secure key rates less than 0.1 bps. Besides, they need manual calibration frequently to maintain the system performance. These aspects render these demonstrations far from practicability. Thus, justification is extremely crucial for practical deployment into the field environment. Here, by developing an automatic feedback MDIQKD system operated at a high clock rate, we perform a field test via deployed fiber network of 30 km total length, achieving a 16.9 bps secure key rate. The result lays the foundation for a global quantum network which can shield from all the detection-side attacks.

  8. Laboratory measurements on reservoir rocks from The Geysers geothermal field

    SciTech Connect (OSTI)

    Boitnott, G.N.

    1995-01-26T23:59:59.000Z

    A suite of laboratory measurements have been conducted on Geysers metagraywacke and metashale recovered from a drilled depth of 2599 to 2602 meters in NEGU-17. The tests have been designed to constrain the mechanical and water-storage properties of the matrix material. Various measurements have been made at a variety of pressures and at varying degrees of saturation. Both compressional and shear velocities exhibit relatively little change with effective confining pressure. In all of the samples, water saturation causes an increase in the compressional velocity. In some samples, saturation results in a moderate decrease in shear velocity greater in magnitude than would be expected based on the slight increase in bulk density. It is found that the effect of saturation on the velocities can be quantitatively modeled through a modification of Biot-Gassmann theory to include weakening of the shear modulus with saturation. The decrease is attributed to chemo-mechanical weakening caused by the presence of water. The degree of frame weakening of the shear modulus is variable between samples, and appears correlated with petrographic features of the cores. Two related models are presented through which we can study the importance of saturation effects on field-scale velocity variations. The model results indicate that the saturation effects within the matrix are significant and may contribute to previously observed field anomalies. The results help to define ways in which we may be able to separate the effects of variations in rock properties, caused by phenomena such as degree of fracturing, from similar effects caused by variations in matrix saturation. The need for both compressional and shear velocity data in order to interpret field anomalies is illustrated through comparisons of model results with the field observations.

  9. System having unmodulated flux locked loop for measuring magnetic fields

    DOE Patents [OSTI]

    Ganther, Jr., Kenneth R. (Olathe, KS); Snapp, Lowell D. (Blue Springs, MO)

    2006-08-15T23:59:59.000Z

    A system (10) for measuring magnetic fields, wherein the system (10) comprises an unmodulated or direct-feedback flux locked loop (12) connected by first and second unbalanced RF coaxial transmission lines (16a, 16b) to a superconducting quantum interference device (14). The FLL (12) operates for the most part in a room-temperature or non-cryogenic environment, while the SQUID (14) operates in a cryogenic environment, with the first and second lines (16a, 16b) extending between these two operating environments.

  10. Development of alkaline fuel cells.

    SciTech Connect (OSTI)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari [Colorado School of Mines, Golden, CO; Horan, James L. [Colorado School of Mines, Golden, CO; Caire, Benjamin R. [Colorado School of Mines, Golden, CO; Ziegler, Zachary C. [Colorado School of Mines, Golden, CO; Herring, Andrew M. [Colorado School of Mines, Golden, CO; Yang, Yuan [Colorado School of Mines, Golden, CO; Zuo, Xiaobing [Argonne National Laboratory, Argonne, IL; Robson, Michael H. [University of New Mexico, Albuquerque, NM; Artyushkova, Kateryna [University of New Mexico, Albuquerque, NM; Patterson, Wendy [University of New Mexico, Albuquerque, NM; Atanassov, Plamen Borissov [University of New Mexico, Albuquerque, NM

    2013-09-01T23:59:59.000Z

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  11. Debye size microprobes for electric field measurements in laboratory plasmas

    SciTech Connect (OSTI)

    Pribyl, P.; Gekelman, W.; Nakamoto, M.; Lawrence, E.; Chiang, F.; Stillman, J.; Judy, J.; Katz, N.; Kintner, P.; Niknejadi, P. [Department of Physics Astronomy, University of California, Los Angeles, California 90095 (United States); Department of Electrical Engineering, University of California, Los Angeles, California 90095 (United States); Department of Physics, MIT, Cambridge, Massachussetts (United States); Department of Electrical Engineering, Cornell University, Ithaca, New York 14850 (United States); Cal Poly, Pomona, California 91768 (United States)

    2006-07-15T23:59:59.000Z

    Microelectromechanical systems (MEMS) have led to the development of a host of tiny machines and sensors over the past decade. Plasma physics is in great need of small detectors for several reasons. First of all, very small detectors do not disturb a plasma, and secondly some detectors can only work because they are very small. We report on the first of a series of small (sub-Debye length) probes for laboratory plasmas undertaken at the basic Plasma Science Facility at UCLA. The goal of the work is to develop robust and sensitive diagnostic probes that can survive in a plasma. The probes must have electronics packages in close proximity. We report on the construction and testing of probes that measure the electric field.

  12. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01T23:59:59.000Z

    Performance and produced polymer evaluation of four alkaline-surfactant-polymer projects concluded that only one of the projects could have benefited from combining the alkaline-surfactant-polymer and gelation technologies. Cambridge, the 1993 Daqing, Mellott Ranch, and the Wardlaw alkaline-surfacant-polymer floods were studied. An initial gel treatment followed by an alkaline-surfactant-polymer flood in the Wardlaw field would have been a benefit due to reduction of fracture flow. Numerical simulation demonstrated that reducing the permeability of a high permeability zone of a reservoir with gel improved both waterflood and alkaline-surfactant-polymer flood oil recovery. A Minnelusa reservoir with both A and B sand production was simulated. A and B sands are separated by a shale layer. A sand and B sand waterflood oil recovery was improved by 196,000 bbls or 3.3% OOIP when a gel was placed in the B sand. Alkaline-surfactant-polymer flood oil recovery improvement over a waterflood was 392,000 bbls or 6.5% OOIP. Placing a gel into the B sand prior to an alkaline-surfactant-polymer flood resulted in 989,000 bbl or 16.4% OOIP more oil than only water injection. A sand and B sand alkaline-surfactant-polymer flood oil recovery was improved by 596,000 bbls or 9.9% OOIP when a gel was placed in the B sand.

  13. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; David Stewart; Bill Jones

    2005-10-01T23:59:59.000Z

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Chromium acetate-xanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of the gels tested appeared to alter alkaline-surfactant-polymer solution oil recovery. Total waterflood plus chemical flood oil recovery sequence recoveries were all similar. Chromium acetate-polyacrylamide gel used to seal fractured core maintain fracture closure if followed by an alkaline-surfactant-polymer solution. Chromium acetate gels that were stable to injection of alkaline-surfactant-polymer solutions at 72 F were stable to injection of alkaline-surfactant-polymer solutions at 125 F and 175 F in linear corefloods. Chromium acetate-polyacrylamide gels maintained diversion capability after injection of an alkaline-surfactant-polymer solution in stacked; radial coreflood with a common well bore. Xanthan gum-chromium acetate gels maintained gel integrity in linear corefloods after injection of an alkaline-surfactant-polymer solution at 125 F. At 175 F, Xanthan gum-chromium acetate gels were not stable either with or without subsequent alkaline-surfactant-polymer solution injection. Numerical simulation demonstrated that reducing the permeability of a high permeability zone of a reservoir with gel improved both waterflood and alkaline-surfactant-polymer flood oil recovery. A Minnelusa reservoir with both A and B sand production was simulated. A and B sands are separated by a shale layer. A sand and B sand waterflood oil recovery was improved by 196,000 bbls when a gel was placed in the B sand. A sand and B sand alkaline-surfactant-polymer flood oil recovery was improved by 596,000 bbls when a gel was placed in the B sand. Alkaline-surfactant-pol

  14. Alkaline and alkaline earth metal phosphate halides and phosphors

    DOE Patents [OSTI]

    Lyons, Robert Joseph; Setlur, Anant Achyut; Cleaver, Robert John

    2012-11-13T23:59:59.000Z

    Compounds, phosphor materials and apparatus related to nacaphite family of materials are presented. Potassium and rubidium based nacaphite family compounds and phosphors designed by doping divalent rare earth elements in the sites of alkaline earth metals in the nacaphite material families are descried. An apparatus comprising the phosphors based on the nacaphite family materials are presented herein. The compounds presented is of formula A.sub.2B.sub.1-yR.sub.yPO.sub.4X where the elements A, B, R, X and suffix y are defined such that A is potassium, rubidium, or a combination of potassium and rubidium and B is calcium, strontium, barium, or a combination of any of calcium, strontium and barium. X is fluorine, chlorine, or a combination of fluorine and chlorine, R is europium, samarium, ytterbium, or a combination of any of europium, samarium, and ytterbium, and y ranges from 0 to about 0.1.

  15. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qui; Dan Wilson; Phil Dowling

    2004-05-01T23:59:59.000Z

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding in the swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to the naturally fractured reservoirs or those with thief zones because much of the injected solution bypasses the target pore space containing oil. The objective of this work is to investigate whether combining these two technologies could broaden the applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium--polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values of 9.2 to 12.9.

  16. Parity violating radiative emission of neutrino pair in heavy alkaline earth atoms of even isotopes

    E-Print Network [OSTI]

    M. Yoshimura; N. Sasao; S. Uetake

    2014-03-26T23:59:59.000Z

    Metastable excited states ${}^3P_2, {}^3P_0$ of heavy alkaline earth atoms of even isotopes are studied for parity violating (PV) effects in radiative emission of neutrino pair (RENP). PV terms arise from interference between two diagrams containing neutrino pair emission of valence spin current and nuclear electroweak charge density proportional to the number of neutrons in nucleus. This mechanism gives large PV effects, since it does not suffer from the suppression of 1/(electron mass) usually present for non-relativistic atomic electrons. A controllable magnetic field is crucial to identify RENP process by measuring PV observables. Results of PV asymmetries under the magnetic field reversal and the photon circular polarization reversal are presented for an example of Yb atom.

  17. Effect of the terrestrial magnetic field on direct-current measurements in underground pipelines

    SciTech Connect (OSTI)

    Dzhala, R.M.; Dikmarova, L.P.; Kornienko, V.Yu.

    1995-12-01T23:59:59.000Z

    The effect of the secondary field of an underground pipeline, magnetized by the terrestrial magnetic field, on noncontacting measurements of direct current flowing in it is discussed. The systematic errors of three known measurement methods are compared. A method based on the measurement of the difference between the field components parallel to the terrestrial field component orthogonal to the pipline is identified as the most accurate. 5 refs., 3 figs.

  18. Magnetic-field sensing coil embedded in ceramic for measuring ambient magnetic field

    DOE Patents [OSTI]

    Takahashi, Hironori

    2004-02-10T23:59:59.000Z

    A magnetic pick-up coil for measuring magnetic field with high specific sensitivity, optionally with an electrostatic shield (24), having coupling elements (22) with high winding packing ratio, oriented in multiple directions, and embedded in ceramic material for structural support and electrical insulation. Elements of the coil are constructed from green ceramic sheets (200) and metallic ink deposited on surfaces and in via holes of the ceramic sheets. The ceramic sheets and the metallic ink are co-fired to create a monolithic hard ceramic body (20) with metallized traces embedded in, and placed on exterior surfaces of, the hard ceramic body. The compact and rugged coil can be used in a variety of environments, including hostile conditions involving ultra-high vacuum, high temperatures, nuclear and optical radiation, chemical reactions, and physically demanding surroundings, occurring either individually or in combinations.

  19. Measuring bi-directional current through a field-effect transistor by virtue of drain-to-source voltage measurement

    DOE Patents [OSTI]

    Turner, Steven Richard

    2006-12-26T23:59:59.000Z

    A method and apparatus for measuring current, and particularly bi-directional current, in a field-effect transistor (FET) using drain-to-source voltage measurements. The drain-to-source voltage of the FET is measured and amplified. This signal is then compensated for variations in the temperature of the FET, which affects the impedance of the FET when it is switched on. The output is a signal representative of the direction of the flow of current through the field-effect transistor and the level of the current through the field-effect transistor. Preferably, the measurement only occurs when the FET is switched on.

  20. Subtleties of the fermion measure in the presence of axion fields

    E-Print Network [OSTI]

    P. Mitra

    2015-05-01T23:59:59.000Z

    It is known from path integral studies of the chiral anomaly that the fermion measure has to depend on gauge fields interacting with the fermion. It is pointed out here that in the presence of an axion field interacting with the fermion, it too is involved in the measure, with unexpected consequences for the utility of the field.

  1. LiveLab: Measuring Wireless Networks and Smartphone Users in the Field

    E-Print Network [OSTI]

    Zhong, Lin

    1 LiveLab: Measuring Wireless Networks and Smartphone Users in the Field Clayton Shepard*, Ahmad and wireless networks with a reprogrammable in- device logger designed for long-term user studies. We discuss to measure smartphone users in the field and to measure wireless networks with smartphone users. The key

  2. 2011 Alkaline Membrane Fuel Cell Workshop Final Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2011 Alkaline Membrane Fuel Cell Workshop Final Report B. Pivovar National Renewable Energy Laboratory Proceedings from the Alkaline Membrane Fuel Cell Workshop Arlington, Virginia...

  3. Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Properties of Alkaline-Earth Oxide Nanoparticles. Photoluminescence Properties of Alkaline-Earth Oxide Nanoparticles. Abstract: Previous experiments have demonstrated that...

  4. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson

    2004-10-01T23:59:59.000Z

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Neither aluminum citrate-polyacrylamide nor silicate-polyacrylamide gel systems produced significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of the gels tested appeared to alter alkaline-surfactant-polymer solution oil recovery. Total waterflood plus chemical flood oil recovery sequence recoveries were all similar.

  5. SciTech Connect: Field Test Results from Lidar Measured Yaw Control...

    Office of Scientific and Technical Information (OSTI)

    Conference: Field Test Results from Lidar Measured Yaw Control for Improved Yaw Alignment with the NREL Controls Advanced Research Turbine: Preprint Citation Details In-Document...

  6. Measurements of electric and magnetic fields in the Waianae, Hawaii area

    SciTech Connect (OSTI)

    Mantiply, E.D.

    1992-07-01T23:59:59.000Z

    During November 27--30, 1990, the US Environmental Protection Agency (EPA) conducted a measurement survey of electric and magnetic field levels along the southwest coast of Oahu, Hawaii. These measurements were requested by the State of Hawaii to determine the levels of radiofrequency (RF) electric and magnetic fields near Naval radio transmitters at Lualualei. The objective was to determine maximum fields in residential areas. This report documents the measurement results. Also, a few measurements were made of extremely-low-frequency (ELF) electric and magnetic fields at 60 hertz, the frequency used for electrical power.

  7. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2003-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  8. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2002-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  9. Field measurement of lateral earth pressures on retaining walls

    E-Print Network [OSTI]

    Riggins, Michael

    1974-01-01T23:59:59.000Z

    . The measured pressures are compared with the computed Coulomb and Rankine pressures for the active case. The measured pressures on the cantilever wall are in close agreement with the theoretical pressures on the upper half of the wall, but the measured... Pressure Variance with Time and Temperature. INTRODUCTION Present Status of the Question -- The latera1 earth pressure theories developed by Coulomb in 1776 and Rankine in 1S57 are known as the classical earth pressure theories (5)*. The basic equation...

  10. Uncertainties in Achieving Energy Savings from HVAC Maintenance Measures in the Field

    E-Print Network [OSTI]

    California at Davis, University of

    Uncertainties in Achieving Energy Savings from HVAC Maintenance Measures in the Field Kristin Group, Davis, CA, USA 4 Southern California Edison, Irwindale, CA, USA ABSTRACT HVAC maintenance utilities across the nation to include HVAC maintenance measures in energy efficiency programs

  11. COUPLING THE ALKALINE-SURFACTANT-POLYMER TECHNOLOGY AND THE GELATION TECHNOLOGY TO MAXIMIZE OIL PRODUCTION

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; David Stewart; Bill Jones

    2005-04-01T23:59:59.000Z

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or more efficient areal sweep efficiency for those with high permeability contrast ''thief zones''. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or those with thief zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. A prior fluid-fluid report discussed interaction of different gel chemical compositions and alkaline-surfactant-polymer solutions. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses. Aluminum-polyacrylamide, flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9. Chromium acetate-polyacrylamide flowing and rigid flowing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid flowing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Chromium acetate-xanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid flowing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid flowing gel producing the greatest amount. Higher oil recovery could have been due to higher differential pressures across cores. None of the gels tested appeared to alter alkaline-surfactant-polymer solution oil recovery. Total waterflood plus chemical flood oil recovery sequence recoveries were all similar.

  12. Screening citrus rootstocks for alkalinity tolerance

    E-Print Network [OSTI]

    Sudahono

    1991-01-01T23:59:59.000Z

    SCREENING CITRUS ROOTSTOCKS FOR ALKALINITY TOLERANCE A Thesis by SUDAHONO Submitted to the Office of Graduate Studies of Texas ALM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1991 Major... Subject: Horticulture SCREENING CITRUS ROOTSTOCKS FOR ALKALINITY TOLERANCE A Thesis by SUDAHONO Approved as to style and content by: David H. yr (Chair of Com ttee) Robert E. Rouse (Member) ~. Err. tg~i ~PI. ~~ Frank M. Hone (Member) Calvin G...

  13. Measurement of advective soil gas flux: Results of field and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at a high chamber-flushing rate, are likely to yield flux measurements closer to the true values. Citation: Amonette JE, JL Barr, RL Erikson, LM Dobeck, JL Barr, and JA...

  14. Meteorological field measurements at potential and actual wind turbine sites

    SciTech Connect (OSTI)

    Renne, D.S.; Sandusky, W.F.; Hadley, D.L.

    1982-09-01T23:59:59.000Z

    An overview of experiences gained in a meteorological measurement program conducted at a number of locations around the United States for the purpose of site evaluation for wind energy utilization is provided. The evolution of the measurement program from its inception in 1976 to the present day is discussed. Some of the major accomplishments and areas for improvement are outlined. Some conclusions on research using data from this program are presented.

  15. Field measurements of earth pressure on a cantilever retaining wall

    E-Print Network [OSTI]

    Schulze, Larry Wayne

    1980-01-01T23:59:59.000Z

    Cells Configuration of Conduit for Pressure Cell Loads Profile of Backfill Material Location of Borings Boring - Sl Boring - S2 . Boring - 53 . Measured Pressure Versus Time Cross Section of a Terra Tec Pressure Cell Movement Measuring System... and key were instrumented with seven Terra Tec pneumatic pressure cells. Due to extreme construction delays, the stem of the above mentioned retaining walI was not instrumented until the third year of the pro- ject. The stem was instrumented with five...

  16. The measurement and analysis of the magnetic field of a synchrotron light source magnet 

    E-Print Network [OSTI]

    Graf, Udo Werner

    1994-01-01T23:59:59.000Z

    In this thesis a unique system is used to measure the magnetic field of a superconducting synchrotron light source magnet. The magnet measured is a superferric dipole C-magnet designed to produce a magnetic field up to 3 Tesla in magnitude. Its...

  17. Kinetic Simulations of Retarding-Field Analyzer Measurements in Tokamak Edge Plasmas

    E-Print Network [OSTI]

    Kinetic Simulations of Retarding-Field Analyzer Measurements in Tokamak Edge Plasmas Fabrice of probe measurements in tokamaks, particularly those obtained from Retarding-Field-Analyzers (RFAs) [1]. This type of probe provides an integral of the ion velocity distribution in tokamak edge plasmas, which

  18. LiveLab: Measuring Wireless Networks and Smartphone Users in the Field

    E-Print Network [OSTI]

    Zhong, Lin

    LiveLab: Measuring Wireless Networks and Smartphone Users in the Field Clayton Shepard*, Ahmad and wireless networks with a reprogrammable in- device logger designed for long-term user studies. We discuss of smartphone usage and measurement of wireless networks x In-field programmability of the logger so

  19. Suppressing Multi-Channel Ultra-Low-Field MRI Measurement Noise Using Data Consistency and Image

    E-Print Network [OSTI]

    Suppressing Multi-Channel Ultra-Low-Field MRI Measurement Noise Using Data Consistency and Image of Mathematics, National Taiwan University, Taipei, Taiwan, 4 Elekta Oy, Helsinki, Finland Abstract Ultra-low. (2013) Suppressing Multi-Channel Ultra-Low-Field MRI Measurement Noise Using Data Consistency and Image

  20. Field measurements of interactions between furnaces and forced air distribution systems

    E-Print Network [OSTI]

    of equipment that provides the heating energy (the furnace, boiler or heat pump) and the method usedLBNL 40587 Field measurements of interactions between furnaces and forced air distribution systems Vol. 104 Part 1 Field measurements of interactions between furnaces and forced air distribution

  1. Electric field and temperature measurement using ultra wide bandwidth pigtailed electro-optic probes

    E-Print Network [OSTI]

    Boyer, Edmond

    .1364/AO.47.002470 #12;2 Introduction In the field of high power microwave (HPM) measurements, ultra wideHz-GHz frequency range) and allowing getting simultaneously one specific component of the HPM E field and the probe determining the energy of a single shot HPM signal by measuring the temperature increase of an EO probe

  2. Field Profile and Loading Measurements on Higher Order Modes in a Two Cell 500 MHz Superconducting Structure

    E-Print Network [OSTI]

    Barry, W.

    2011-01-01T23:59:59.000Z

    in the Proceedings Field Profile and Loading Measurements onNo. N00014-91-4152. Field Profile and Loading Measurementspart of this study, field profile and loading measurements

  3. Field measurements of lateral earth pressures on a pre-cast panel retaining wall

    E-Print Network [OSTI]

    Prescott, David Monroe

    1973-01-01T23:59:59.000Z

    t Member August 1973 ABSTRACT FIELD MEASUREMENTS OF LATERAL EARTH PRESSURES ON A PRE-CAST PANEL RETAINING WALL. (AUGUST 1973) David Monroe Prescott, B. S. , Texas A&M University; Directed by: Dr. Harry M. Coyle Terra Tec pneumatic earth pressure... Typical Calibration Curve for Terra Tec Cell 10 15 6 Typical Field Relationsihp Between Zero Gage Reading and Temperature-Pressure Cell 7 Measured Pressure Versus Time, Upper Row of Cells . . . . . . , , . . . . . . . . . . . 16 19 8 Measured...

  4. Near- and far-field measurements of phase-ramped frequency selective surfaces at infrared wavelengths

    SciTech Connect (OSTI)

    Tucker, Eric; Boreman, Glenn, E-mail: gboreman@uncc.edu [Department of Physics and Optical Science, University of North Carolina at Charlotte, 9201 University City Blvd., Charlotte, North Carolina 28223 (United States); D'Archangel, Jeffrey [CREOL, The College of Optics and Photonics, University of Central Florida, 4304 Scorpius St., Orlando, Florida 32816 (United States); Raschke, Markus B. [Department of Physics, Department of Chemistry, and JILA, University of Colorado, 390 UCB, Boulder, Colorado 80309 (United States)

    2014-07-28T23:59:59.000Z

    Near- and far-field measurements of phase-ramped loop and patch structures are presented and compared to simulations. The far-field deflection measurements show that the phase-ramped structures can deflect a beam away from specular reflection, consistent with simulations. Scattering scanning near-field optical microscopy of the elements comprising the phase ramped structures reveals part of the underlying near-field phase contribution that dictates the far-field deflection, which correlates with the far-field phase behavior that was expected. These measurements provide insight into the resonances, coupling, and spatial phase variation among phase-ramped frequency selective surface (FSS) elements, which are important for the performance of FSS reflectarrays.

  5. Field calculation of D0 toroids and comparison with measurement

    SciTech Connect (OSTI)

    Yamada, R.; Ostiguy, F.; Brzezniak, J.

    1992-06-01T23:59:59.000Z

    The magnetic structure of the D0 detector is described in an earlier report. The two-dimensional code POISSON was used for the initial design of the magnetic structures and the magnetic properties of the D0 toroids. During the construction, the two-dimensional code ANSYS was used to perform more detailed calculations. Full three-dimensional analysis was also performed using the code TOSCA. These new results are reported here and compared with measurements. In this study the magnetic flux in all toroids, CF, EF, and SAMUS is set in the same direction.

  6. Idaho field experiment 1981. Volume 2: measurement data

    SciTech Connect (OSTI)

    Start, G E; Sagendorf, J F; Ackermann, G R; Cate, J H; Hukari, N F; Dickson, C R

    1984-04-01T23:59:59.000Z

    The 1981 Idaho Field Experiment was conducted in southeastern Idaho over the upper Snake River Plain. Nine test-day case studies were conducted between July 15 and 30, 1981. Releases of SF/sub 6/ gaseous tracer were made for 8-hour periods from 46m above ground. Tracer was sampled hourly, for 12 sequential hours, at about 100 locations within an area 24km square. Also, a single total integrated sample of about 30 hours duration was collected at approximately 100 sites within an area 48 by 72km square (using 6km spacings). Extensive tower profiles of meteorology at the release point were collected. RAWINSONDES, RABALS and PIBALS were collected at 3 to 5 sites. Horizontal, low-altitude winds were monitored using the INEL MESONET. SF/sub 6/ tracer plume releases were marked with co-located oil fog releases and bi-hourly sequential launches of tetroon pairs. Aerial LIDAR observations of the oil fog plume and airborne samples of SF/sub 6/ were collected. High altitude aerial photographs of daytime plumes were collected. Volume II lists the data in tabular form or cites the special supplemental reports by other participating contractors. While the primary user file and the data archive are maintained on 9 track/1600 cpi magnetic tapes, listings of the individual values are provided for the user who either cannot utilize the tapes or wishes to preview the data. The accuracies and quality of these data are described.

  7. Alkaline earth filled nickel skutterudite antimonide thermoelectrics

    DOE Patents [OSTI]

    Singh, David Joseph

    2013-07-16T23:59:59.000Z

    A thermoelectric material including a body centered cubic filled skutterudite having the formula A.sub.xFe.sub.yNi.sub.zSb.sub.12, where A is an alkaline earth element, x is no more than approximately 1.0, and the sum of y and z is approximately equal to 4.0. The alkaline earth element includes guest atoms selected from the group consisting of Be, Mb, Ca, Sr, Ba, Ra and combinations thereof. The filled skutterudite is shown to have properties suitable for a wide variety of thermoelectric applications.

  8. Experimental Measurement of the Flow Field of Heavy Trucks

    SciTech Connect (OSTI)

    Fred Browand; Charles Radovich

    2005-05-31T23:59:59.000Z

    Flat flaps that enclose the trailer base on the sides and top are known to reduce truck drag and reduce fuel consumption. Such flapped-truck geometries have been studied in laboratory wind tunnels and in field tests. A recent review of wind tunnel data for a variety of truck geometries and flow Reynolds numbers show roughly similar values of peak drag reduction, but differ in the determination of the optimum flap angle. Optimum angles lie in the range 12 degrees-20 degrees, and may be sensitive to Reynolds number and truck geometry. The present field test is undertaken to provide additional estimates of the magnitude of the savings to be expected on a typical truck for five flap angles 10, 13, 16, 19, and 22 degrees. The flaps are constructed from a fiberglass-epoxy-matrix material and are one-quarter of the base width in length (about 61 cm, or 2 feet). They are attached along the rear door hinge lines on either side of the trailer, so that no gap appears at the joint between the flap and the side of the trailer The flap angle is adjusted by means of two aluminum supports. The present test is performed on the NASA Crows Landing Flight Facility at the northern end of the San Joaquin valley in California. The main runway is approximately 2400 meters in length, and is aligned approximately in a north-south direction The test procedure is to make a series of runs starting at either end of the runway. All runs are initiated under computer control to accelerate the truck to a target speed of 60 mph (96 6 km/hr), to proceed at the target speed for a fixed distance, and to decelerate at the far end of the runway. During a run, the broadcast fuel rate, the engine rpm, forward speed, elapsed time--as well as several other parameters (10 in all)--are digitized at a rate of 100 digitizations per second. Various flapped-conditions are interspersed with the ''no flaps'' control, and are sequenced in a different order on different days. Approximately 310 runs are accumulated over the 5-day test period, May 17-21, 2004. The runway slopes rather uniformly upward from north-to-south. Over the distance of 2424 meters between our two ''start'' markers at either end of the runway, the net change in elevation is a little over ten meters. Test results clearly show the greater fuel consumption required to lift the truck against gravity in the southbound direction For this reason, it is important that the tests be averaged over a round trip circuit--that is, a run in both directions over the identical portion of the roadway. Northbound-southbound averages require an overlap segment of the runway (near the middle of the runway) where the truck--starting from either end--has achieved its target speed. For the target truck speed of 60 mph, this overlap region is approximately 700 meters in length. Typically a run and the return run are accomplished within a time interval of 6 minutes. Analysis of the data show fuel consumption savings at all flap angle settings tested, when compared to the ''no flaps'' condition. The most beneficial flap angle appears to be 13 degrees, for which the fuel consumption is 0.3778 {+-} 0.0025 liters/km compared to the ''no flaps'' control of 0.3941 {+-} 0.0034 liters/km. The error bounds expressed above mark the 99% confidence interval in the mean values given. That is, additional estimates of the mean fuel consumption would be expected to lie within the bounds given, approximately 99% of the time. The fuel consumption saving is--to reasonable accuracy--about 1.63 liters/100 kilometers. These savings represent the increment associated only with the change in drag due to the presence or absence of flaps. The result will hold for any truck of similar size and shape and engine performance regardless of the loading of the truck or the rolling resistance. The economy achieved by use of base flaps can be compared to the economy resulting from driving two trucks in a tandem configuration. In December 2003, such fuel consumption tests were performed at the same Crows Landing testsite. In the tests, two identical trucks are ope

  9. A small unperturbing probe for the measurement and mapping of electric fields at extremely low frequencies

    E-Print Network [OSTI]

    Shrekenhamer, Abraham

    1975-01-01T23:59:59.000Z

    by means of optical fibers to eliminate perturbation of the measured electric field. The instrument utilizes the phenomenon of charge induction in con- ductors in the presence of an electric field. The charge induced on the exterior of the probe... conceptual circuit for electric field to analog voltage conversion. . 29 15 Induced-charge to analog-voltage converter. . . 35 16 Probe component layout . 36 17 Axis selector, optoelectronic converter and battery switching circuits. 18 Receiver...

  10. Measurement of the drift field in the ARGONTUBE LAr TPC with 266~nm pulsed laser beams

    E-Print Network [OSTI]

    A. Ereditato; D. Goeldi; S. Janos; I. Kreslo; M. Luethi; C. Rudolf von Rohr; M. Schenk; T. Strauss; M. S. Weber; M. Zeller

    2014-10-30T23:59:59.000Z

    ARGONTUBE is a liquid argon time projection chamber (LAr TPC) with a drift field generated in-situ by a Greinacher voltage multiplier circuit. We present results on the measurement of the drift-field distribution inside ARGONTUBE using straight ionization tracks generated by an intense UV laser beam. Our analysis is based on a simplified model of the charging of a multi-stage Greinacher circuit to describe the voltages on the field cage rings.

  11. Measuring Magnetic Fields Near and Far with the SKA via the Zeeman Effect

    E-Print Network [OSTI]

    Robishaw, Timothy; Surcis, Gabriele; Vlemmings, Wouter; Richards, A M S; Etoka, Sandra; Bourke, Tyler; Fish, Vincent; Gray, Malcolm; Imai, Hiroshi; Kramer, Busaba; McBride, James; Momjian, Emmanuel; Sarma, Anuj; Zijlstra, Albert

    2015-01-01T23:59:59.000Z

    The measurement of Zeeman splitting in spectral lines---both in emission and absorption---can provide direct estimates of the magnetic field strength and direction in atomic and molecular clouds, both in our own Milky Way and in external galaxies. This method will probe the magnetic field in the warm and cold neutral components of the interstellar medium, providing a complement to the extensive SKA Faraday studies planning to probe the field in the ionized components.

  12. Lightning strikes to tall objects: Currents inferred from far electromagnetic fields versus directly measured currents

    E-Print Network [OSTI]

    Florida, University of

    -field-to-current conversion factor for lightning strikes to flat ground based on the transmission line model and (b currents on tall towers are used for testing the validity of field-to-current conversion equations [e on current measurement location (e.g., near the top or bottom of the tower) and on whether initial or largest

  13. MEASUREMENT AND ANALYSIS OF ELECTROMAGNETIC FIELDS FROM TRAMS, TRAINS AND HYBRID CARS

    E-Print Network [OSTI]

    Halgamuge, Malka N.

    of electric and magnetic fields emitted from Australian trams, trains and hybrid cars were investigated cars are now electrically operated, therefore emitting less CO2 and less pollution into the environmentMEASUREMENT AND ANALYSIS OF ELECTROMAGNETIC FIELDS FROM TRAMS, TRAINS AND HYBRID CARS Malka N

  14. A COMPARISON OF LABORATORY AND FIELD-TEST MEASUREMENTS OF HEAT PUMP WATER HEATERS

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    #12;A COMPARISON OF LABORATORY AND FIELD-TEST MEASUREMENTS OF HEAT PUMP WATER HEATERS William P a heat pump water heater (HPWH). After developing the HPWH, a field-test plan was implemented whereby 20 evaluate this effect. #12;INTRODUCTION Domestic water heaters account for approximately 2.5 EJ (2.4 x 1015

  15. Electric field measurement in microwave discharge ion thruster with electro-optic probe

    SciTech Connect (OSTI)

    Ise, Toshiyuki; Tsukizaki, Ryudo; Koizumi, Hiroyuki [The University of Tokyo, Bunkyo-ku, Tokyo 113-8656 (Japan); Togo, Hiroyoshi [Microsystem Integration Laboratories, Nippon Telegraph and Telephone, Morinosato, Atsugi-shi, Kanagawa 243-0198 (Japan); Kuninaka, Hitoshi [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, Chuo-ku, Sagamihara, Kanagawa 229-8510 (Japan)

    2012-12-15T23:59:59.000Z

    In order to understand the internal phenomena in a microwave discharge ion thruster, it is important to measure the distribution of the microwave electric field inside the discharge chamber, which is directly related to the plasma production. In this study, we proposed a novel method of measuring a microwave electric field with an electro-optic (EO) probe based on the Pockels effect. The probe, including a cooling system, contains no metal and can be accessed in the discharge chamber with less disruption to the microwave distribution. This method enables measurement of the electric field profile under ion beam acceleration. We first verified the measurement with the EO probe by a comparison with a finite-difference time domain numerical simulation of the microwave electric field in atmosphere. Second, we showed that the deviations of the reflected microwave power and the beam current were less than 8% due to inserting the EO probe into the ion thruster under ion beam acceleration. Finally, we successfully demonstrated the measurement of the electric-field profile in the ion thruster under ion beam acceleration. These measurements show that the electric field distribution in the thruster dramatically changes in the ion thruster under ion beam acceleration as the propellant mass flow rate increases. These results indicate that this new method using an EO probe can provide a useful guide for improving the propulsion of microwave discharge ion thrusters.

  16. Complex-optical-field lidar system for range and vector velocity measurement

    E-Print Network [OSTI]

    Gao, Shuang; Sullivan, Maurice O.; Hui, Rongqing

    2012-11-01T23:59:59.000Z

    Complex-optical-field lidar system for range and vector velocity measurement Shuang Gao,1,2 Maurice O’Sullivan,3 and Rongqing Hui2,* 1Department of Electronic Engineering and Information Science, University of Science and Technology of China... lidar system based on the measurement of complex optical field is demonstrated for the first time. An electro-optic in- phase/quadrature (I/Q) modulator is used in the lidar transmitter to realize carrier-suppressed complex optical field modulation...

  17. Magnetometer suitable for Earth field measurement based on transient atomic response

    E-Print Network [OSTI]

    Lenci, L; Valente, P; Failache, H; Lezama, A

    2015-01-01T23:59:59.000Z

    We describe the development of a simple atomic magnetometer using $^{87}$Rb vapor suitable for Earth magnetic field monitoring. The magnetometer is based on time-domain determination of the transient precession frequency of the atomic alignment around the measured field. A sensitivity of 1.5 nT/$\\sqrt{Hz}$ is demonstrated on the measurement of the Earth magnetic field in the laboratory. We discuss the different parameters determining the magnetometer precision and accuracy and predict a sensitivity of 30 pT/$\\sqrt{Hz}$

  18. Distribution of Carbon Impurity Sources Between Low and High Field Side Measured via Zeeman-Spectroscopy in JET

    E-Print Network [OSTI]

    Distribution of Carbon Impurity Sources Between Low and High Field Side Measured via Zeeman-Spectroscopy in JET

  19. Measurement of Untruncated Nuclear Spin Interactions via Zero- to Ultra-Low-Field Nuclear Magnetic Resonance

    E-Print Network [OSTI]

    John W. Blanchard; Tobias F. Sjolander; Jonathan P. King; Micah P. Ledbetter; Emma H. Levine; Vikram S. Bajaj; Dmitry Budker; Alexander Pines

    2015-07-09T23:59:59.000Z

    Zero- to ultra-low-field nuclear magnetic resonance (ZULF NMR) provides a new regime for the measurement of nuclear spin-spin interactions free from effects of large magnetic fields, such as truncation of terms that do not commute with the Zeeman Hamiltonian. One such interaction, the magnetic dipole-dipole coupling, is a valuable source of spatial information in NMR, though many terms are unobservable in high-field NMR, and the coupling averages to zero under isotropic molecular tumbling. Under partial alignment, this information is retained in the form of so-called residual dipolar couplings. We report zero- to ultra-low-field NMR measurements of residual dipolar couplings in acetonitrile-2-$^{13}$C aligned in stretched polyvinyl acetate gels. This represents the first investigation of dipolar couplings as a perturbation on the indirect spin-spin $J$-coupling in the absence of an applied magnetic field. As a consequence of working at zero magnetic field, we observe terms of the dipole-dipole coupling Hamiltonian that are invisible in conventional high-field NMR. This technique expands the capabilities of zero- to ultra-low-field NMR and may have applications in precision measurement of subtle physical interactions, chemical analysis, and characterization of local mesoscale structure in materials.

  20. New measurements of magnetic fields of roAp stars with FORS1 at the VLT

    E-Print Network [OSTI]

    S. Hubrig; T. Szeifert; M. Schoeller; G. Mathys; D. W. Kurtz

    2003-09-21T23:59:59.000Z

    Magnetic fields play a key role in the pulsations of rapidly oscillating Ap (roAp) stars since they are a necessary ingredient of all pulsation excitation mechanisms proposed so far. This implies that the proper understanding of the seismological behaviour of the roAp stars requires knowledge of their magnetic fields. However, the magnetic fields of the roAp stars are not well studied. Here we present new results of measurements of the mean longitudinal field of 14 roAp stars obtained from low resolution spectropolarimetry with FORS1 at the VLT.

  1. Network Maps of Technology Fields: How Measures of Relatedness Influence Network Structures

    E-Print Network [OSTI]

    Yan, Bowen

    2015-01-01T23:59:59.000Z

    The structure of the total technology space, together with the specialized knowledge positions of the inventors, companies and countries, conditions the prospect of their next innovations. Prior studies have proposed representing the technology space as a network of patent technology classes connected by links weighted according to their relatedness. Although the choice of relatedness measures affects the structure of the resulting networks, such measures have not been assessed in terms of their influences on network structures. In this paper, we first present six measures based on the similarity of knowledge bases of different technology fields and, alternatively, on the likelihood for inventors, organizations or countries to diversify across technology fields. Then, we compare the resulting networks in terms of network structures, vertex and edge properties and their predictability on the importance of the represented technology fields. Based on USPTO patent data from 1976 to 2010 and International Patent C...

  2. High Field Magnetization measurements of uranium dioxide single crystals (P08358- E003-PF)

    SciTech Connect (OSTI)

    K. Gofryk; N. Harrison; M. Jaime

    2014-12-01T23:59:59.000Z

    Conclusions: Our preliminary high field magnetic measurements of UO2 are consistent with a complex nature of the magnetic ordering in this material, compatible with the previously proposed non-collinear 3-k magnetic structure. Further extensive magnetic studies on well-oriented (<100 > and <111>) UO2 crystals are planned to address the puzzling behavior of UO2 in both antiferromagnetic and paramagnetic states at high fields.

  3. Mean field limit for bosons with compact kernels interactions by Wigner measures transportation

    SciTech Connect (OSTI)

    Liard, Quentin, E-mail: quentin.liard@univ-rennes1.fr; Pawilowski, Boris, E-mail: boris.pawilowski@univ-rennes1.fr [IRMAR, Université de Rennes I, Campus de Beaulieu, 35042 Rennes Cedex (France)

    2014-09-15T23:59:59.000Z

    We consider a class of many-body Hamiltonians composed of a free (kinetic) part and a multi-particle (potential) interaction with a compactness assumption on the latter part. We investigate the mean field limit of such quantum systems following the Wigner measures approach. We prove in particular the propagation of these measures along the flow of a nonlinear (Hartree) field equation. This enhances and complements some previous results of the same type shown in Z. Ammari and F. Nier and Fröhlich et al. [“Mean field limit for bosons and propagation of Wigner measures,” J. Math. Phys. 50(4), 042107 (2009); Z. Ammari and F. Nier and Fröhlich et al., “Mean field propagation of Wigner measures and BBGKY hierarchies for general bosonic states,” J. Math. Pures Appl. 95(6), 585–626 (2011); Z. Ammari and F. Nier and Fröhlich et al., “Mean-field- and classical limit of many-body Schrödinger dynamics for bosons,” Commun. Math. Phys. 271(3), 681–697 (2007)].

  4. Alkaline earth cation extraction from acid solution

    DOE Patents [OSTI]

    Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

    2003-01-01T23:59:59.000Z

    An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

  5. The separatrix radius measurement of field-reversed configuration plasma in FRX-L

    SciTech Connect (OSTI)

    Zhang, S. (Shouyin); Tejero, E. M. (Erik M.); Taccetti, J. M. (Jose Martin); Wurden, G. A. (Glen A.); Intrator, Thomas; Waganaar, W. J. (William J.)

    2004-01-01T23:59:59.000Z

    Magnetic pick-up coils and single turn flux loops are installed on the FRX-L device. The combination of the two measurements provides the excluded flux radius that approximates the separatrix radius of the field-reversed configuration plasma. Arrays of similar probes are used to map out local magnetic field dynamics beyond both ends of the theta-coil confinement region to help understand the effects of cusp locations on flux trapping during the FRC formation process. Details on the probe design and system calibrations are presented. The overall system calibration of excluded flux radius measurement is examined by replacing FRC plasma with a known radius aluminum conductor cylinder.

  6. Geosynthetic clay liners in alkaline environments

    SciTech Connect (OSTI)

    McKelvey, J.A. III [Roy F. Weston, Inc., West Chester, PA (United States)

    1997-11-01T23:59:59.000Z

    The use of geosynthetic clay liners (GCLs) as secondary barrier layers in environmental applications such as landfills and other impoundment facilities is becoming increasingly more popular among the engineering community, particularly at project sites where earthen materials suitable for barrier layers may not be locally available. Design engineers for these environmental applications are becoming well versed at performing equivalency calculations comparing the performance of geosynthetic materials to their earthen counterparts. For barrier layers, these equivalency calculations would normally compare the mechanical and hydraulic properties of the GCL to a compacted clay liner. Of these properties, the ability of the hydraulic properties to withstand degradation due to permeation of contained leachates is of prominent concern. Such is the case in alkaline environments. The leachate may adversely affect the GCL by minimizing swelling, decreasing adsorption capacity and increasing the permeability of the material. If the effect on the material is significant, the usefulness of this product is diminished, possibly voiding any equivalency comparison to compacted clay liner performance. The design engineer must fully understand what effect, if any, specific leachates will have on the GCL being considered. Accordingly, appropriate performance testing with the leachate in question must be performed during the design phase and confirmed during construction through quality assurance testing. This paper will present the design considerations, required laboratory testing and conformance tests for a recent project that contained an alkaline leachate. Through appropriate testing, a contaminant resistant GCL was shown to possess desired hydraulic properties in the presence of the alkaline leachate.

  7. Full-field velocity measurements of single and two phase flows using digital pulsed laser velocimetry

    E-Print Network [OSTI]

    Canaan, Robert Ernst

    1990-01-01T23:59:59.000Z

    particles. The use of a cylindrical constant heat flux emitting conductor enabled full-field velocity measurement of unsteady natural convective flows over a wide range of single phase flow regimes. The method was additionally extended to the measurement... and will utilize a constant heat flux emitting electrical conductor in order to represent a simple model of a nuclear reactor fuel element vertically positioned within a rectangular coolant channel. Natural convective cooling is of particularly recent concern...

  8. Identification of an elasticity-tensor random field at mesoscopic scale using experimental measurements at mesoscopic and macroscopic scales for

    E-Print Network [OSTI]

    Boyer, Edmond

    of the random field at meso-scale (1) using image field measurements at macro- and meso-scales, (2) introducing- and meso-scales for a given sample submitted to a given load. The experimental displacement (strain) field is measured on the whole domain (1x1 cm) at the macro-scale while, at the meso-scale, the displacement (strain

  9. Coupling the Alkaline-Surfactant-Polymer Technology and The Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01T23:59:59.000Z

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or reservoirs with different sand lenses with high permeability contrast. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more crude oil than waterflooding from swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or reservoirs with high permeability contrast zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium-polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses with the exception of the xanthan gum-chromium acetate gels. Aluminum-polyacrylamide flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9, either in linear corefloods or in dual separate radial core, common manifold corefloods. Chromium acetate-polyacrylamide flowing and rigid tonguing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid tonguing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Chromium acetate gels were stable to injection of alkaline-surfactant-polymer solutions at 72 F, 125 F and 175 F in linear corefloods. Chromium acetate-polyacrylamide gels maintained diversion capability after injection of an alkaline-surfactant-polymer solution in stacked; radial coreflood with a common well bore. Chromium acetate-polyacrylamide gel used to seal fractured core maintain fracture closure if followed by an alkaline-surfactant-polymer solution. Chromium acetatexanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection at 72, 125, and 175 F. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid tonguing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid tonguing gel producing the greatest amount. Higher oil recovery could have been due to higher differential

  10. Coupling the Alkaline-Surfactant-Polymer Technology and the Gelation Technology to Maximize Oil Production

    SciTech Connect (OSTI)

    Malcolm Pitts; Jie Qi; Dan Wilson; Phil Dowling; David Stewart; Bill Jones

    2005-12-01T23:59:59.000Z

    Gelation technologies have been developed to provide more efficient vertical sweep efficiencies for flooding naturally fractured oil reservoirs or reservoirs with different sand lenses with high permeability contrast. The field proven alkaline-surfactant-polymer technology economically recovers 15% to 25% OOIP more crude oil than waterflooding froin swept pore space of an oil reservoir. However, alkaline-surfactant-polymer technology is not amenable to naturally fractured reservoirs or reservoirs with high permeability contrast zones because much of injected solution bypasses target pore space containing oil. This work investigates whether combining these two technologies could broaden applicability of alkaline-surfactant-polymer flooding into these reservoirs. Fluid-fluid interaction with different gel chemical compositions and alkaline-surfactant-polymer solution with pH values ranging from 9.2 to 12.9 have been tested. Aluminum-polyacrylamide gels are not stable to alkaline-surfactant-polymer solutions at any pH. Chromium-polyacrylamide gels with polymer to chromium ion ratios of 25 or greater were stable to alkaline-surfactant-polymer solutions if solution pH was 10.6 or less. When the polymer to chromium ion was 15 or less, chromium-polyacrylamide gels were stable to alkaline-surfactant-polymer solutions with pH values up to 12.9. Chromium-xanthan gum gels were stable to alkaline-surfactant-polymer solutions with pH values of 12.9 at the polymer to chromium ion ratios tested. Silicate-polyacrylamide, resorcinol-formaldehyde, and sulfomethylated resorcinol-formaldehyde gels were also stable to alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Iron-polyacrylamide gels were immediately destroyed when contacted with any of the alkaline-surfactant-polymer solutions with pH values ranging from 9.2 to 12.9. Gel solutions under dynamic conditions of linear corefloods showed similar stability to alkaline-surfactant-polymer solutions as in the fluid-fluid analyses with the exception of the xanthan gum-chromium acetate gels. Aluminum-polyacrylamide flowing gels are not stable to alkaline-surfactant-polymer solutions of either pH 10.5 or 12.9, either in linear corefloods or in dual separate radial core, common manifold corefloods. Chromium acetate-polyacrylamide flowing and rigid tonguing gels are stable to subsequent alkaline-surfactant-polymer solution injection. Rigid tonguing chromium acetate-polyacrylamide gels maintained permeability reduction better than flowing chromium acetate-polyacrylamide gels. Chromium acetate gels were stable to injection of alkaline-surfactant-polymer solutions at 72 F, 125 F and 175 F in linear corefloods. Chromium acetate-polyacrylamide gels maintained diversion capability after injection of an alkaline-surfactant-polymer solution in stacked; radial coreflood with a common well bore. Chromium acetate-polyacrylamide gel used to seal fractured core maintain fracture closure if followed by an alkaline-surfactant-polymer solution. Chromium acetate-xanthan gum rigid gels are not stable to subsequent alkaline-surfactant-polymer solution injection at 72, 125, and 175 F. Silicate-polyacrylamide gels are not stable with subsequent injection of either a pH 10.5 or a 12.9 alkaline-surfactant-polymer solution. Resorcinol-formaldehyde gels were stable to subsequent alkaline-surfactant-polymer solution injection. When evaluated in a dual core configuration, injected fluid flows into the core with the greatest effective permeability to the injected fluid. The same gel stability trends to subsequent alkaline-surfactant-polymer injected solution were observed. Aluminum citrate-polyacrylamide, resorcinol-formaldehyde, and the silicate-polyacrylamide gel systems did not produce significant incremental oil in linear corefloods. Both flowing and rigid tonguing chromium acetate-polyacrylamide gels and the xanthan gum-chromium acetate gel system produced incremental oil with the rigid tonguing gel producing the greatest amount. Higher oil recovery could have been due to higher differentia

  11. Aurora Australis Marine Science Cruise AU9404 -Oceanographic Field Measurements and Analysis

    E-Print Network [OSTI]

    Aurora Australis Marine Science Cruise AU9404 - Oceanographic Field Measurements and Analysis MARK RSV Aurora Australis from December 1994 to February 1995. The major constituent of the cruise Institute ship R.V. Knorr (M. McCartney, pers. comm.) several days prior to occupation by the Aurora

  12. Instrumentation for Measurement of Strain Dependence of Nb3Sn Conductors National High Magnetic Field Laboratory

    E-Print Network [OSTI]

    Weston, Ken

    Instrumentation for Measurement of Strain Dependence of Nb3Sn Conductors National High Magnetic Field Laboratory Magnet Science and Technology, Florida State University An NHMFL User Collaboration Grants Program (UCGP) award is supporting students from the FAMU-FSU College of Engineering as part

  13. FULL FIELD STRESS MEASUREMENT FOR IN SITU STRUCTURAL HEALTH MONITORING OF AIRFRAME COMPONENTS AND REPAIRS

    E-Print Network [OSTI]

    Boyer, Edmond

    FULL FIELD STRESS MEASUREMENT FOR IN SITU STRUCTURAL HEALTH MONITORING OF AIRFRAME COMPONENTS to structural health monitoring however is problematic. The reasons are manifold but a key one is that strain detector to furnish a basis for in situ structural health monitoring. It first covers some preliminaries

  14. Maneuverability of ships in ice: numerical simulation and comparison with field measurements

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Maneuverability of ships in ice: numerical simulation and comparison with field measurements Biao Su Department of Marine Technology, NTNU May 28, 2013 #12;Motivation Local ice load Global ice load Ship's performance · Ice-hull interaction · Local ice load · Global ice load · Ship's performance #12

  15. Numerical simulation of ice-induced loads on ships and comparison with field measurements

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Numerical simulation of ice-induced loads on ships and comparison with field measurements Biao Su Department of Marine Technology, NTNU May 28, 2013 #12;Motivation Local ice load Global ice load Ship's performance · Ice-hull interaction · Local ice load · Global ice load · Ship's performance #12;Outline

  16. Atmospheric Environment 40 (2006) 38813897 Field measurements of desert dust deposition in Libya

    E-Print Network [OSTI]

    Clarke, Michèle

    Atmospheric Environment 40 (2006) 3881­3897 Field measurements of desert dust deposition in Libya-based dust monitoring study of three zones across Libya, ranging from the Mediterranean coast to the Sahara studies in North Africa shows that areas of Libya have the highest dust deposition rates on record. r 2006

  17. Field representation of a watt balance magnet by partial profile measurements

    E-Print Network [OSTI]

    Li, Shisong; Zhao, Wei; Huang, Songling

    2015-01-01T23:59:59.000Z

    Permanent magnets with high-permeability yokes have been widely used in watt balances for supplying a robust and strong magnetic field at the coil position. Subjected to the mechanical realization, only several $B_r(z)$ (radial magnetic field along the vertical direction) profiles can be measured by coils for field characterization. In this article, we present an algorithm that can construct the global magnetic field of the air gap based on $N(N\\geq1)$ additional measurements of $B_r(z)$ profiles. The proposed algorithm is realized by polynomially estimating the $B_z(r)$ function with analysis of basic relations between two magnetic components in air gap, i.e., $B_r(r,z)$ and $B_z(r,z)$, following the Maxwell's equations. The algorithm, verified by FEM simulations, can characterize the three-dimensional contribution of the magnetic field for a watt balance magnet with acceptable accuracy, which would supply basic field parameters for alignment and misalignment corrections.

  18. Surfactant-enhanced alkaline flooding with weak alkalis

    SciTech Connect (OSTI)

    French, T.R.; Josephson, C.B.

    1991-02-01T23:59:59.000Z

    The objective of Project BE4B in FY90 was to develop cost-effective and efficient chemical flooding formulations using surfactant-enhanced, lower pH (weak) alkaline chemical systems. Chemical systems were studied that mitigate the deleterious effects of divalent ions. The experiments were conducted with carbonate mixtures and carbonate/phosphate mixtures of pH 10.5, where most of the phosphate ions exist as the monohydrogen phosphate species. Orthophosphate did not further reduce the deleterious effect of divalent ions on interfacial tension behavior in carbonate solutions, where the deleterious effect of the divalent ions is already very low. When added to a carbonate mixture, orthophosphate did substantially reduce the adsorption of an atomic surfactant, which was an expected result; however, there was no correlation between the amount of reduction and the divalent ion levels. For acidic oils, a variety of surfactants are available commercially that have potential for use between pH 8.3 and pH 9.5. Several of these surfactants were tested with oil from Wilmington (CA) field and found to be suitable for use in that field. Two low-acid crude oils, with acid numbers of 0.01 and 0.27 mg KOH/g of oil, were studied. It was shown that surfactant-enhanced alkaline flooding does have merit for use with these low-acid crude oils. However, each low-acid oil tested was found to behave differently, and it was concluded that the applicability of the method must be experimentally determined for any given low-acid crude oil. 19 refs., 10 figs. 4 tabs.

  19. Quiet Sun internetwork magnetic fields from the inversion of Hinode measurements

    E-Print Network [OSTI]

    D. Orozco Suarez; L. R. Bellot Rubio; J. C. del Toro Iniesta; S. Tsuneta; B. W. Lites; K. Ichimoto; Y. Katsukawa; S. Nagata; T. Shimizu; R. A. Shine; Y. Suematsu; T. D. Tarbell; A. M. Title

    2007-10-07T23:59:59.000Z

    We analyze Fe I 630 nm observations of the quiet Sun at disk center taken with the spectropolarimeter of the Solar Optical Telescope aboard the Hinode satellite. A significant fraction of the scanned area, including granules, turns out to be covered by magnetic fields. We derive field strength and inclination probability density functions from a Milne-Eddington inversion of the observed Stokes profiles. They show that the internetwork consists of very inclined, hG fields. As expected, network areas exhibit a predominance of kG field concentrations. The high spatial resolution of Hinode's spectropolarimetric measurements brings to an agreement the results obtained from the analysis of visible and near-infrared lines.

  20. Lyman-{alpha} radiation of a metastable hydrogen beam to measure electric fields

    SciTech Connect (OSTI)

    Lejeune, A.; Cherigier-Kovacic, L.; Doveil, F.

    2011-10-31T23:59:59.000Z

    The interaction between a metastable H(2s) atomic hydrogen beam and an external electric field leads to the emission of the Lyman-{alpha} line. It originates in the Stark mixing of the near-degenerate 2s{sub 1/2} and 2p{sub 1/2} levels separated by the Lamb shift. The quenched radiation proportional to the square of the electric field amplitude is recovered in vacuum by using such an atomic probe beam. We observe the strong enhancement of the signal when the field is oscillating at the Lamb shift frequency. This technique is applied in a plasma, offering an alternative way to measure weak electric fields by direct and non-intrusive means.

  1. Electric and magnetic fields and field derivatives from lightning stepped leaders and first return strokes measured at distances

    E-Print Network [OSTI]

    Florida, University of

    Electric and magnetic fields and field derivatives from lightning stepped leaders and first return; published 5 September 2008. [1] Using electric and magnetic field and field derivative sensors arrayed over-peak width of the stepped-leader/return-stroke electric field waveform; the stepped-leader electric field

  2. Field testing of a probe to measure fouling in an industrial flue gas stream

    SciTech Connect (OSTI)

    Sohal, M.S.

    1990-11-01T23:59:59.000Z

    The US Department of Energy, Office of Industrial Technology sponsors work in the area of measuring and mitigating fouling in heat exchangers. This report describes the design and fabrication of a gas-side fouling measuring device, and its testing in an industrial environment. The report gives details of the probe fabrication, material used, controllers, other instrumentation required for various measurements, and computer system needed for recording the data. The calibration constants for measuring the heat flux with the heat fluxmeter were determined. The report also describes the field test location, the tests performed, the data collected, and the data analysis. The conclusions of the tests performed were summarized. Although fouling deposits on the probe were minimal, the tests proved that the probe is capable of measuring the fouling in a harsh industrial environment. 17 refs., 19 figs., 5 tabs.

  3. Steel characteristics measurement system using Barkhausen jump sum rate and magnetic field intensity and method of using same

    DOE Patents [OSTI]

    Kohn, Gabriel (Omer, IL); Hicho, George (Derwood, MD); Swartzendruber, Lydon (New Carrollton, MD)

    1997-01-01T23:59:59.000Z

    A steel hardness measurement system and method of using same are provided for measuring at least one mechanical or magnetic characteristic of a ferromagnetic sample as a function of at least one magnetic characteristic of the sample. A magnetic field generator subjects the sample to a variable external magnetic field. The magnetic field intensity of the magnetic field generated by the magnetic field generating means is measured and a signal sensor is provided for measuring Barkhausen signals from the sample when the sample is subjected to the external magnetic field. A signal processing unit calculates a jump sum rate first moment as a function of the Barkhausen signals measured by the signal sensor and the magnetic field intensity, and for determining the at least one mechanical or magnetic characteristic as a function of the jump sum rate first moment.

  4. Steel characteristics measurement system using Barkhausen jump sum rate and magnetic field intensity and method of using same

    DOE Patents [OSTI]

    Kohn, G.; Hicho, G.; Swartzendruber, L.

    1997-04-08T23:59:59.000Z

    A steel hardness measurement system and method of using same are provided for measuring at least one mechanical or magnetic characteristic of a ferromagnetic sample as a function of at least one magnetic characteristic of the sample. A magnetic field generator subjects the sample to a variable external magnetic field. The magnetic field intensity of the magnetic field generated by the magnetic field generating means is measured and a signal sensor is provided for measuring Barkhausen signals from the sample when the sample is subjected to the external magnetic field. A signal processing unit calculates a jump sum rate first moment as a function of the Barkhausen signals measured by the signal sensor and the magnetic field intensity, and for determining the at least one mechanical or magnetic characteristic as a function of the jump sum rate first moment. 7 figs.

  5. Ion-trap measurements of electric-field noise near surfaces

    E-Print Network [OSTI]

    M. Brownnutt; M. Kumph; P. Rabl; R. Blatt

    2014-09-23T23:59:59.000Z

    Electric-field noise near surfaces is a common problem in diverse areas of physics, and a limiting factor for many precision measurements. There are multiple mechanisms by which such noise is generated, many of which are poorly understood. Laser-cooled, trapped ions provide one of the most sensitive systems to probe electric-field noise at MHz frequencies and over a distance range 30 - 3000 $\\mu$m from the surface. Over recent years numerous experiments have reported spectral densities of electric-field noise inferred from ion heating-rate measurements and several different theoretical explanations for the observed noise characteristics have been proposed. This paper provides an extensive summary and critical review of electric-field noise measurements in ion traps, and compares these experimental findings with known and conjectured mechanisms for the origin of this noise. This reveals that the presence of multiple noise sources, as well as the different scalings added by geometrical considerations, complicate the interpretation of these results. It is thus the purpose of this review to assess which conclusions can be reasonably drawn from the existing data, and which important questions are still open. In so doing it provides a framework for future investigations of surface-noise processes.

  6. Summary of Field Measurement on UF6 Cylinders Using Electro-Mechanically Cooled Systems

    SciTech Connect (OSTI)

    McGinnis, Brent R [ORNL; Smith, Steven E [ORNL; Solodov, Alexander A [ORNL; Whitaker, J Michael [ORNL; Morgan, James B [ORNL; MayerII, Richard L. [USEC, Inc.; Montgomery, J. Brent [U.S. Enrichment Corporation Paducah Gaseous Diffusion Plant

    2009-01-01T23:59:59.000Z

    Measurement of the enrichment of solid state UF6 stored within large metal cylinders is a task commonly performed by plant operators and inspectors. The measurement technologies typically used range from low-resolution, high-efficiency sodium iodide detectors to high-resolution, moderate-efficiency high-purity germanium (HPGe) detectors. The technology used and methods deployed are dependent upon the material being measured, environmental conditions, time constraints, and measurement-precision requirements. Operators and inspectors typically use specially designed, HPGe detectors that are cooled with liquid nitrogen in situations where high-resolution measurements are required. However, the requirement for periodically refilling the system with liquid nitrogen makes remote usage cumbersome and slow. The task of cooling the detector reduces the available time for the inspector to perform other safeguards activities while on site. If the inspector has to reduce the count time for each selected cylinder to ensure that all preselected cylinders are measured during the inspection, the resulting measurement uncertainties may be increased, making it more difficult to detect and verify potential discrepancies in the operator's declarations. However, recent advances in electromechanically cooled HPGe detectors may provide the inspector with an improved verification tool by eliminating the need for liquid nitrogen. This report provides a summary of test results for field measurements performed using electromechanically cooled HPGe detectors on depleted, natural, and low-enriched uranium cylinders. The results of the study provide valuable information to inspectors and operators regarding the capabilities and limitations of electromechanically cooled systems based on true field-measurement conditions.

  7. Text-Alternative Version of Building America Webinar: Field Test Best Practices, BEopt, and the National Residential Efficiency Measures Database

    Broader source: Energy.gov [DOE]

    This is the transcript of the Building America webinar, Field Test Best Practices, BEopt, and the National Residential Efficiency Measures Database, held on March 18, 2015.

  8. Measurement of Asymmetric Optical Pumping of Ions Accelerating in a Magnetic-field Gradient

    SciTech Connect (OSTI)

    Xuan Sun; Earl Scime; Mahmood Miah; Samuel Cohen; Frederick Skiff

    2004-10-28T23:59:59.000Z

    We report observations of asymmetric optical pumping of argon ions accelerating in a magnetic field gradient. The signature is a difference in the laser-induced-fluorescence (LIF) emission amplitude from a pair of Zeeman-split states. A model that reproduces the dependence of the asymmetry on magnetic-field and ion-velocity gradients is described. With the model, the fluorescence intensity ratio provides a new method of measuring ion collisionality. This phenomenon has implications for interpreting stellar plasma spectroscopy data which often exhibit unequal Zeeman state intensities.

  9. Prospects for x-ray polarimetry measurements of magnetic fields in magnetized liner inertial fusion plasmas

    SciTech Connect (OSTI)

    Lynn, Alan G., E-mail: lynn@ece.unm.edu; Gilmore, Mark [Department of Electrical and Computer Engineering, University of New Mexico, Albuquerque, New Mexico 87131 (United States)

    2014-11-15T23:59:59.000Z

    Magnetized Liner Inertial Fusion (MagLIF) experiments, where a metal liner is imploded to compress a magnetized seed plasma may generate peak magnetic fields ?10{sup 4} T (100 Megagauss) over small volumes (?10{sup ?10}m{sup 3}) at high plasma densities (?10{sup 28}m{sup ?3}) on 100 ns time scales. Such conditions are extremely challenging to diagnose. We discuss the possibility of, and issues involved in, using polarimetry techniques at x-ray wavelengths to measure magnetic fields under these extreme conditions.

  10. Alkaline chemistry of transuranium elements and technetium and the treatment of alkaline radioactive wastes

    SciTech Connect (OSTI)

    Delegard, C.H. [Westinghouse Hanford Co., Richland, WA (United States); Peretrukhin, V.F.; Shilov, V.P.; Pikaev, A.K. [Russian Academy of Sciences (Russian Federation). Inst. of Physical Chemistry

    1995-05-01T23:59:59.000Z

    Goal of this survey is to generalize the known data on fundamental physical-chemical properties of TRUs and Tc, methods for their isolation, and to provide recommendations that will be useful for partitioning them from alkaline high-level wastes.

  11. alkaline ph alter: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in magnitude and are often opposite in direction. It was also found that during Clyde Marshall; Leslie; F. Nims 37 Subcellular localization of marine bacterial alkaline...

  12. alkali metal alkaline: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for hydrogen, the alkali-metal atoms, the alkaline earth atoms, and the inert gases are tabulated along with the resulting values of the atomic static polarizabilities,...

  13. alkaline phosphatase production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    any soluble alkaline phospha rase activity remaining, and the supernatant solution and pellet separated. The pellet was suspended in 110 ml of the above buffer and homogenized. To...

  14. alkaline water electrolysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Solid-State Water Electrolysis with an Alkaline Membrane Yongjun Leng,, Energy Storage, Conversion and Utilization Websites Summary: Supporting Information ABSTRACT:...

  15. alkaline single cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    through both new materials and membrane electrode processing 10 Liquid metal batteries : ambipolar electrolysis and alkaline earth electroalloying cells MIT - DSpace...

  16. alkaline earth metal compounds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Berkeley. FOM Institute for Plasma Physics Cohen, Ronald C. 2 Liquid metal batteries : ambipolar electrolysis and alkaline earth electroalloying cells MIT - DSpace...

  17. alkaline secondary cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    through both new materials and membrane electrode processing 8 Liquid metal batteries : ambipolar electrolysis and alkaline earth electroalloying cells MIT - DSpace...

  18. Alkaline Membrane Fuel Cell Workshop Welcome and OverviewInnovation

    Broader source: Energy.gov (indexed) [DOE]

    Alkaline Membrane Fuel Cell Workshop Welcome and Overview Innovation for Our Energy Future Bryan Pivovar National Renewable Energy Laboratory AMFC Workshop May 8, 2011 Innovation...

  19. alkaline phosphate wastes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  20. alkaline emissions produced: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  1. alkaline tank waste: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  2. alkaline waste solutions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  3. alkaline nuclear wastes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  4. alkaline nuclear waste: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences Websites Summary: -solid waste for CO2 mitigation and reduction of greenhouse effect gases into the atmosphere. ? 2008 ElsevierCarbonation of alkaline paper mill...

  5. LDV measurements of the velocity field within a ribbed internal duct flow

    SciTech Connect (OSTI)

    Huckle, E.; Pantelic, D.; Hu, K.; Jones, S.; Travkin, V.; Catton, I.

    1999-07-01T23:59:59.000Z

    Laser Doppler velocimetry (LDV) has been used to measure the velocity field in an internal duct flow of air with regular rib roughness. The experiments were conducted to study the effect regular wall obstacles have on the flow velocity field. The instantaneous u and v velocities were measured in both a smooth and rough rectangular duct. For the smooth channel the wind tunnel Reynolds number capability was first investigated and was shown to be linear with blower shaft frequency, having a range of 13,000--42,000. Next, the turbulent velocity profiles were measured in the smooth channel for 6 different blower speeds (Reynolds numbers), and the results greatly resembled those found in previous literature. Twenty sets of rectangular, 6.35 mm x 6.35 mm ribs were then mounted to the top and bottom of the channel with a spacing of 75 mm (P/H = 11.8). A grid of nodes were selected and the turbulent velocities were measured for a given Reynolds number, and are presented and discussed. Valuable insight was gained which will aid in future studies intended to measure the Reynolds stress and other closure terms.

  6. Field measurements of ammonia volatilization from surface applications of nitrogen fertilizers to a calcareous soil

    E-Print Network [OSTI]

    Hargrove, W. L

    1977-01-01T23:59:59.000Z

    to measure volatilized NH3 in the labora- tory. A) Vacuum pump, B) Boric acid trap to collect volatilized NH ~ C) NH3 volatilization chamber, D) Trkp to re- move NH3 from incoming air . . . . . . . . . . . 21 A schematic of the apparatus used to make... direct measurements of NH losses in the field. A) Vacuum pum), B) Boric acid trap, C) NH volatilization chamber, consisting of metal cylinder and plexi- glass top The cumulative NH losses over time for four rates of' a)plication of urea...

  7. Field evaluation of methodology for measurement of cadmium in stationary-source stack gases. Final report

    SciTech Connect (OSTI)

    Moseman, R.F.; Bath, D.B.; McReynolds, J.R.; Holder, D.J.; Sykes, A.L.

    1986-12-01T23:59:59.000Z

    A laboratory and field-evaluation study was done to develop methodology for the measurement of cadmium in stationary-source stack emissions. Field evaluations were performed at a municipal solid-waste incinerator and a sewage-sludge incinerator. The methodology was tested through the laboratory and field-sampling validation phases to evaluate precision and accuracy of the proposed method. Colocated, quadruplicate flue-gas samples of nominally 30 and 60 dscf in 1 and 2 hours sampling time were collected to assure an adequate cadmium content, a representative sample, and the production of data to validate the method in terms of between-train precision. The overall accuracy and precision of the analysis procedure were 89.2% and 1.7%, respectively. The detection limit of the atomic absorption instrument was 0.03 ug/mL. The methodology proved to be a reliable sampling approach to determine cadmium emissions from the stationary sources tested.

  8. A fast continuous magnetic field measurement system based on digital signal processors

    SciTech Connect (OSTI)

    Velev, G.V.; Carcagno, R.; DiMarco, J.; Kotelnikov, S.; Lamm, M.; Makulski, A.; /Fermilab; Maroussov, V.; /Purdue U.; Nehring, R.; Nogiec, J.; Orris, D.; /Fermilab; Poukhov,; Prakoshyn, F.; /Dubna, JINR; Schlabach, P.; Tompkins, J.C.; /Fermilab

    2005-09-01T23:59:59.000Z

    In order to study dynamic effects in accelerator magnets, such as the decay of the magnetic field during the dwell at injection and the rapid so-called ''snapback'' during the first few seconds of the resumption of the energy ramp, a fast continuous harmonics measurement system was required. A new magnetic field measurement system, based on the use of digital signal processors (DSP) and Analog to Digital (A/D) converters, was developed and prototyped at Fermilab. This system uses Pentek 6102 16 bit A/D converters and the Pentek 4288 DSP board with the SHARC ADSP-2106 family digital signal processor. It was designed to acquire multiple channels of data with a wide dynamic range of input signals, which are typically generated by a rotating coil probe. Data acquisition is performed under a RTOS, whereas processing and visualization are performed under a host computer. Firmware code was developed for the DSP to perform fast continuous readout of the A/D FIFO memory and integration over specified intervals, synchronized to the probe's rotation in the magnetic field. C, C++ and Java code was written to control the data acquisition devices and to process a continuous stream of data. The paper summarizes the characteristics of the system and presents the results of initial tests and measurements.

  9. MAGNETIC FIELD STRUCTURE OF THE LARGE MAGELLANIC CLOUD FROM FARADAY ROTATION MEASURES OF DIFFUSE POLARIZED EMISSION

    SciTech Connect (OSTI)

    Mao, S. A. [National Radio Astronomy Observatory, P.O. Box O, Socorro, NM 87801 (United States); McClure-Griffiths, N. M.; McConnell, D. [Australia Telescope National Facility, CSIRO Astronomy and Space Science, Epping, NSW 1710 (Australia); Gaensler, B. M. [Sydney Institute for Astronomy, School of Physics, University of Sydney, Sydney, NSW 2006 (Australia); Haverkorn, M. [Department of Astrophysics, Radboud University, P.O. Box 9010, 6500-GL Nijmegen (Netherlands); Beck, R. [Max-Planck-Institut fuer Radioastronomie, D-53121 Bonn (Germany); Wolleben, M. [Square Kilometre Array South Africa, The Park, Pinelands 7405 (South Africa); Stanimirovic, S. [Department of Astronomy, University of Wisconsin, Madison, WI 53706 (United States); Dickey, J. M. [Physics Department, University of Tasmania, Hobart, TAS 7001 (Australia); Staveley-Smith, L., E-mail: mao@astro.wisc.edu [International Centre for Radio Astronomy Research (ICRAR), The University of Western Australia, Crawley, WA 6009 (Australia)

    2012-11-01T23:59:59.000Z

    We present a study of the magnetic field of the Large Magellanic Cloud (LMC), carried out using diffuse polarized synchrotron emission data at 1.4 GHz acquired at the Parkes Radio Telescope and the Australia Telescope Compact Array. The observed diffuse polarized emission is likely to originate above the LMC disk on the near side of the galaxy. Consistent negative rotation measures (RMs) derived from the diffuse emission indicate that the line-of-sight magnetic field in the LMC's near-side halo is directed coherently away from us. In combination with RMs of extragalactic sources that lie behind the galaxy, we show that the LMC's large-scale magnetic field is likely to be of quadrupolar geometry, consistent with the prediction of dynamo theory. On smaller scales, we identify two brightly polarized filaments southeast of the LMC, associated with neutral hydrogen arms. The filaments' magnetic field potentially aligns with the direction toward the Small Magellanic Cloud (SMC). We suggest that tidal interactions between the SMC and the LMC in the past 10{sup 9} years are likely to have shaped the magnetic field in these filaments.

  10. Effects of non-radial magnetic field on measuring magnetic helicity transport across solar photosphere

    E-Print Network [OSTI]

    Song, Yongliang

    2015-01-01T23:59:59.000Z

    It is generally believed that the evolution of magnetic helicity has a close relationship with solar activity. Before the launch of SDO, earlier studies have mostly used MDI/SOHO line of sight magnetograms and assumed that magnetic fields are radial when calculating magnetic helicity injection rate from photospheric magnetograms. However, this assumption is not necessarily true. Here we use the vector magnetograms and line of sight magnetograms, both taken by HMI/SDO, to estimate the effects of non-radial magnetic field on measuring magnetic helicity injection rate. We find that: 1) The effect of non-radial magnetic field on estimating tangential velocity is relatively small; 2) On estimating magnetic helicity injection rate, the effect of non-radial magnetic field is strong when active regions are observed near the limb and is relatively small when active regions are close to disk center; 3) The effect of non-radial magnetic field becomes minor if the amount of accumulated magnetic helicity is the only conce...

  11. Magnetic field measurements at milliarcsecond resolution around massive young stellar objects

    E-Print Network [OSTI]

    Surcis, G; van Langevelde, H J; Kramer, B Hutawarakorn; Bartkiewicz, A; Engelkamp, H

    2015-01-01T23:59:59.000Z

    Magnetic fields have only recently been included in theoretical simulations of high-mass star formation. The simulations show that magnetic fields can play a crucial role not only in the formation and dynamics of molecular outflows, but also in the evolution of circumstellar disks. Therefore, new measurements of magnetic fields at milliarcsecond resolution close to massive young stellar objects (YSOs) are fundamental for providing new input for numerical simulations and for understanding the formation process of massive stars. The polarized emission of 6.7 GHz CH3OH masers allows us to investigate the magnetic field close to the massive YSO where the outflows and disks are formed. Recently, we have detected with the EVN CH3OH maser polarized emission towards 10 massive YSOs. From a first statistical analysis we have found evidence that magnetic fields are primarily oriented along the molecular outflows. To improve our statistics we are carrying on a large observational EVN campaign for a total of 19 sources, ...

  12. Volume 152, number 4,s CHEMICAL PHYSICS LETTERS 18 November 1988 NON-INTRUSIVE MEASUREMENT OF AXIAL ELECTRIC FIELDS

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Volume 152, number 4,s CHEMICAL PHYSICS LETTERS 18 November 1988 NON-INTRUSIVE MEASUREMENT OF AXIAL pertur- bations by sheath accumulation. Non-intrusive mea- surements of the electric fields through for the non- perturbative measurement of the axial electric fields in glow discharges. The A `n, + X I&+ (4

  13. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01T23:59:59.000Z

    A test program is being sponsored by the US Department of Energy (DOE), EPRI, FirstEnergy, and TVA to investigate furnace injection of alkaline sorbents as a means of reducing sulfuric acid concentrations in the flue gas from coal-fired boilers. This test program is being conducted at the FirstEnergy Bruce Mansfield Plant (BMP), although later testing will be conducted at a TVA plant. A sorbent injection test was conducted the week of April 18, 2000. The test was the first of several short-term (one- to two-week duration) tests to investigate the effectiveness of various alkaline sorbents for sulfuric acid control and the effects of these sorbents on boiler equipment performance. This first short-term test investigated the effect of injecting dry dolomite powder (CaCO{sub 3} {center_dot} MgCO{sub 3}), a mineral similar to limestone, into the furnace of Unit 2. During the test program, various analytical techniques were used to assess the effects of sorbent injection. These primarily included sampling with the controlled condensation system (CCS) for determining flue gas SO{sub 3} content and an acid dew-point (ADP) meter for determining the sulfuric acid dew point (and, indirectly, the concentration of sulfuric acid) of the flue gas. EPA Reference Method 26a was used for determining hydrochloric acid (HCl) and hydrofluoric acid (HF), as well and chlorine (Cl{sub 2}) and fluorine (F{sub 2}) concentrations in the flue gas. Fly ash resistivity was measured using a Southern Research Institute (SRI) point-to-plane resistivity probe, and unburned carbon in fly ash was determined by loss on ignition (LOI). Coal samples were also collected and analyzed for a variety of parameters. Finally, visual observations were made of boiler furnace and convective pass surfaces prior to and during sorbent injection.

  14. ORIGINAL PAPER Recognition of early Carboniferous alkaline granite

    E-Print Network [OSTI]

    Siebel, Wolfgang

    ORIGINAL PAPER Recognition of early Carboniferous alkaline granite in the southern Altai orogen for the Bulgen alkaline granite yield crystallization ages of 358 ± 4 Ma (SHRIMP) and 354 ± 4 Ma (LA-orogenic granitoids (460­375 Ma) in this region. The Bulgen granite has high SiO2, total alkalis, rare earth elements

  15. alkaline earth silicate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth silicate First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline...

  16. alkaline earth ions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth ions First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effects of Alkaline Earth Metal Ion...

  17. alkaline earth cax: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth cax First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline...

  18. alkaline earth oxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth oxides First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline...

  19. alkaline earth metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth metals First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effects of Alkaline Earth Metal...

  20. alkaline earth atoms: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth atoms First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline...

  1. alkaline earth codoped: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth codoped First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline...

  2. alkaline earth compound: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth compound First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline...

  3. alkaline earth metallic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth metallic First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effects of Alkaline Earth Metal...

  4. Field-resolved measurement of reaction-induced spectral densities by polarizability response spectroscopy

    SciTech Connect (OSTI)

    Moran, Andrew M.; Nome, Rene A.; Scherer, Norbert F. [Department of Chemistry and the James Franck Institute, University of Chicago, 929 East 57th St., Chicago, Illinois 60637 (United States)

    2007-11-14T23:59:59.000Z

    The experimental design and theoretical description of a novel five-pulse laser spectroscopy is presented with an application to a pyridinium charge transfer complex in acetonitrile and methanol. In field-resolved polarizability response spectroscopy (PORS), an electronically resonant laser pulse first excites a solvated chromophore (reactant) and off-resonant Raman spectra of the resulting nuclear motions are measured as a function of the reaction time. The present apparatus differs from our earlier design by performing the Raman probe measurement (with fixed pulse delays) in the frequency domain. In addition, the full electric fields of the signals are measured by spectral interferometry to separate nonresonant and Raman responses. Our theoretical model shows how the PORS signal arises from nuclear motions that are displaced/driven by the photoinduced reaction. The field-resolved off-resonant (of the solute's electronic transitions) probing favors detection of solvent (as opposed to solute) dynamics coupled to the reaction. The sign of the signal represents the relative strengths of polarization responses associated with the ground and photoexcited solutions. Signatures of nonresonant and PORS signal contributions to the experimental results are analyzed with numerical calculations based on a theoretical model we have developed for reaction-induced PORS. Our model identifies two mechanisms of PORS signal generation: (i) structural relaxation induced resonance; (ii) dephasing induced resonance. In the charge transfer reaction investigated, the solvent-dependent and time-evolving (solvent) polarizability spectral density (PSD) is readily obtained. The general trend of an initial broadband inertial nuclear response followed by a decrease in the linewidth of the PSD establishes that the measured PSD is inconsistent with the approximation of a linear response. Furthermore, the explicit time evolution of the PSD is important for properly describing solvent control of reactions that do not satisfy the time-scale separability inherent to nonadiabatic kinetic models.

  5. Multi-channel Doppler backscattering measurements in the C-2 field reversed configuration

    SciTech Connect (OSTI)

    Schmitz, L., E-mail: lschmitz@ucla.edu; Peebles, W. A. [Department of Physics and Astronomy, University of California Los Angeles, Los Angeles, California 90095 (United States); Ruskov, E. [Department of Physics and Astronomy, University of California, Irvine, Irvine, California 92697 (United States); Deng, B. H.; Gota, H.; Gupta, D.; Tuszewski, M.; Douglass, J.; Binderbauer, M.; Tajima, T. [Tri Alpha Energy, Inc., P.O. Box 7010, Rancho Santa Margarita, California 92688 (United States)

    2014-11-15T23:59:59.000Z

    A versatile heterodyne Doppler Backscattering (DBS) system is used to measure density fluctuation levels (in the wavenumber range k?{sub s} ? 50), and the toroidal E × B flow velocity in the C-2 Field-Reversed Configuration (FRC). Six tunable frequencies in three waveguide bands (26 GHz ? f ? 90 GHz) are launched using monostatic beam optics, via a quasi-optical beam combiner/polarizer and an adjustable parabolic focusing mirror (inside the vacuum enclosure) achieving Gaussian beam spot sizes of 3–5.5 cm at the X/O-mode cutoff. The DBS system covers plasma densities of 0.8 × 10{sup 13} ? n{sub e} ? 1 × 10{sup 14} cm{sup ?3}, and provides access to the FRC core (up to the field null) and across the FRC separatrix into the scrape-off layer plasma.

  6. On the consistency of magnetic field measurements of Ap stars: lessons learned from the FORS1 archive

    E-Print Network [OSTI]

    Landstreet, J D; Fossati, L

    2014-01-01T23:59:59.000Z

    CONTEXT. The ESO archive of FORS1 spectropolarimetric observations may be used to create a homogeneous database of magnetic field measurements. However, no systematic comparison of FORS field measurements to those obtained with other instruments has been undertaken so far. AIMS. We exploit the FORS archive of circular spectropolarimetric data to examine in a general way how reliable and accurate field detections obtained with FORS are. METHODS. We examine the observations of Ap and Bp stars, on the grounds that almost all of the unambiguous detections of magnetic fields in the FORS1 archive are in these kinds of stars. We assess the overall quality of the FORS1 magnetic data by examining the consistency of field detections with what is known from previous measurements obtained with other instruments, and we look at patterns of internal consistency. RESULTS. FORS1 magnetic measurements are fully consistent with those made with other instruments, and the internal consistency of the data is excellent. However, i...

  7. Single-shot spatiotemporal measurements of ultrashort THz waveforms using temporal electric-field cross correlation

    SciTech Connect (OSTI)

    Matlis, Nicholas; Plateau, Guillaume; van Tilborg, Jeroen; Leemans, Wim

    2011-06-17T23:59:59.000Z

    A new single-shot technique based on linear spectral interferometry between a temporally short reader pulse and a temporally long probe pulse is demonstrated for measuring the spatiotemporal phase and amplitude of an optical probe for use as an ultrafast diagnostic. The probe spatiotemporal field information is recovered, with a resolution set by the duration of the reader pulse, by applying a single Fourier transform operation to the interferogram image, without need of any reference data. The technique was used in conjunction with electro-optic sampling to measure waveforms of coherent, ultrashort THz pulses emitted by electron bunches from a laser-plasma accelerator with sub-50fs resolution. The presence of strong spatiotemporal coupling in the THz waveforms and of complex temporal electron-bunch structure was determined.

  8. Dynamic density field measurements of an explosively driven ????? phase transition in iron

    SciTech Connect (OSTI)

    Hull, L. M.; Gray, G. T.; Warthen, B. J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87544 (United States)

    2014-07-28T23:59:59.000Z

    We provide a unique set of observations of the behavior of the ??? phase transition under a complex axially symmetric loading path created by sweeping a detonation wave along the end surface of a cylindrical sample. The primary data sets are the measured mass density distributions acquired at 5 independent times during the sweep of the detonation along the surface. Shocked regions and boundaries are measured, as well as regions and boundaries of elevated density (presumed to be the ??phase iron). The formation and dynamics of these regions were captured and are available for comparisons to material descriptions. We also applied 16 Photon Doppler Velocimetry probes to capture the free surface velocity along a discrete set of radially distributed points in order to compare and correlate the density measurements with previous shock wave studies. The velocimetry data are in nearly exact agreement with previous shock wave studies of the ??? phase transition, the density distributions, while generally in agreement with expectations evolved from the shock wave studies, show that the epsilon phase is generated in regions of high shear stress but at hydrostatic stresses below the typically quoted 13?GPa value. The density field measurements are particularly useful for observing the effects of the forward and reverse transformation kinetics, as well as the reverse transformation hysteresis.

  9. Method of increasing the sulfation capacity of alkaline earth sorbents

    DOE Patents [OSTI]

    Shearer, J.A.; Turner, C.B.; Johnson, I.

    1980-03-13T23:59:59.000Z

    A system and method for increasing the sulfation capacity of alkaline earth carbonates to scrub sulfur dioxide produced during the fluidized bed combustion of coal in which partially sulfated alkaline earth carbonates are hydrated in a fluidized bed to crack the sulfate coating and convert the alkaline earth oxide to the hydroxide. Subsequent dehydration of the sulfate-hydroxide to a sulfate-oxide particle produces particles having larger pore size, increased porosity, decreased grain size and additional sulfation capacity. A continuous process is disclosed.

  10. Nonperturbative measurement of the local magnetic field using pulsed polarimetry for fusion reactor conditions (invited)

    SciTech Connect (OSTI)

    Smith, Roger J. [University of Washington, Seattle, Washington 98195-2250 (United States)

    2008-10-15T23:59:59.000Z

    A novel diagnostic technique for the remote and nonperturbative sensing of the local magnetic field in reactor relevant plasmas is presented. Pulsed polarimetry [Patent No. 12/150,169 (pending)] combines optical scattering with the Faraday effect. The polarimetric light detection and ranging (LIDAR)-like diagnostic has the potential to be a local B{sub pol} diagnostic on ITER and can achieve spatial resolutions of millimeters on high energy density (HED) plasmas using existing lasers. The pulsed polarimetry method is based on nonlocal measurements and subtle effects are introduced that are not present in either cw polarimetry or Thomson scattering LIDAR. Important features include the capability of simultaneously measuring local T{sub e}, n{sub e}, and B{sub ||} along the line of sight, a resiliency to refractive effects, a short measurement duration providing near instantaneous data in time, and location for real-time feedback and control of magnetohydrodynamic (MHD) instabilities and the realization of a widely applicable internal magnetic field diagnostic for the magnetic fusion energy program. The technique improves for higher n{sub e}B{sub ||} product and higher n{sub e} and is well suited for diagnosing the transient plasmas in the HED program. Larger devices such as ITER and DEMO are also better suited to the technique, allowing longer pulse lengths and thereby relaxing key technology constraints making pulsed polarimetry a valuable asset for next step devices. The pulsed polarimetry technique is clarified by way of illustration on the ITER tokamak and plasmas within the magnetized target fusion program within present technological means.

  11. Lithium ion diffusion in Li ?-alumina single crystals measured by pulsed field gradient NMR spectroscopy

    SciTech Connect (OSTI)

    Chowdhury, Mohammed Tareque, E-mail: mtareque@mail.tagen.tohoku.ac.jp; Takekawa, Reiji; Iwai, Yoshiki; Kuwata, Naoaki; Kawamura, Junichi [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai 980-8577 (Japan)] [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai 980-8577 (Japan)

    2014-03-28T23:59:59.000Z

    The lithium ion diffusion coefficient of a 93% Li ?-alumina single crystal was measured for the first time using pulsed field gradient (PFG) NMR spectroscopy with two different crystal orientations. The diffusion coefficient was found to be 1.2 × 10{sup ?11} m{sup 2}/s in the direction perpendicular to the c axis at room temperature. The Li ion diffusion coefficient along the c axis direction was found to be very small (6.4 × 10{sup ?13} m{sup 2}/s at 333 K), which suggests that the macroscopic diffusion of the Li ion in the ?-alumina crystal is mainly two-dimensional. The diffusion coefficient for the same sample was also estimated using NMR line narrowing data and impedance measurements. The impedance data show reasonable agreement with PFG-NMR data, while the line narrowing measurements provided a lower value for the diffusion coefficient. Line narrowing measurements also provided a relatively low value for the activation energy and pre-exponential factor. The temperature dependent diffusion coefficient was obtained in the temperature range 297–333 K by PFG-NMR, from which the activation energy for diffusion of the Li ion was estimated. The activation energy obtained by PFG-NMR was smaller than that obtained by impedance measurements, which suggests that thermally activated defect formation energy exists for 93% Li ?-alumina single crystals. The diffusion time dependence of the diffusion coefficient was observed for the Li ion in the 93% Li ?-alumina single crystal by means of PFG-NMR experiments. Motion of Li ion in fractal dimension might be a possible explanation for the observed diffusion time dependence of the diffusion coefficient in the 93% Li ?–alumina system.

  12. Process for treating alkaline wastes for vitrification

    DOE Patents [OSTI]

    Hsu, C.L.W.

    1995-07-25T23:59:59.000Z

    A process is described for treating alkaline wastes for vitrification. The process involves acidifying the wastes with an oxidizing agent such as nitric acid, then adding formic acid as a reducing agent, and then mixing with glass formers to produce a melter feed. The nitric acid contributes nitrates that act as an oxidant to balance the redox of the melter feed, prevent reduction of certain species to produce conducting metals, and lower the pH of the wastes to a suitable level for melter operation. The formic acid reduces mercury compounds to elemental mercury for removal by steam stripping, and MnO{sub 2} to the Mn(II) ion to prevent foaming of the glass melt. The optimum amounts of nitric acid and formic acid are determined in relation to the composition of the wastes, including the concentrations of mercury (II) and MnO{sub 2}, noble metal compounds, nitrates, formates and so forth. The process minimizes the amount of hydrogen generated during treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. 4 figs.

  13. Process for treating alkaline wastes for vitrification

    DOE Patents [OSTI]

    Hsu, Chia-lin W. (Augusta, GA)

    1995-01-01T23:59:59.000Z

    A process for treating alkaline wastes for vitrification. The process involves acidifying the wastes with an oxidizing agent such as nitric acid, then adding formic acid as a reducing agent, and then mixing with glass formers to produce a melter feed. The nitric acid contributes nitrates that act as an oxidant to balance the redox of the melter feed, prevent reduction of certain species to produce conducting metals, and lower the pH of the wastes to a suitable level for melter operation. The formic acid reduces mercury compounds to elemental mercury for removal by steam stripping, and MnO.sub.2 to the Mn(II) ion to prevent foaming of the glass melt. The optimum amounts of nitric acid and formic acid are determined in relation to the composition of the wastes, including the concentrations of mercury (II) and MnO.sub.2, noble metal compounds, nitrates, formates and so forth. The process minimizes the amount of hydrogen generated during treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product.

  14. Response of Desulfovibrio vulgaris to Alkaline Stress

    SciTech Connect (OSTI)

    Stolyar, S.; He, Q.; He, Z.; Yang, Z.; Borglin, S.E.; Joyner, D.; Huang, K.; Alm, E.; Hazen, T.C.; Zhou, J.; Wall, J.D.; Arkin, A.P.; Stahl, D.A.

    2007-11-30T23:59:59.000Z

    The response of exponentially growing Desulfovibrio vulgarisHildenborough to pH 10 stress was studied using oligonucleotidemicroarrays and a study set of mutants with genes suggested by microarraydata to be involved in the alkaline stress response deleted. The datashowed that the response of D. vulgaris to increased pH is generallysimilar to that of Escherichia coli but is apparently controlled byunique regulatory circuits since the alternative sigma factors (sigma Sand sigma E) contributing to this stress response in E. coli appear to beabsent in D. vulgaris. Genes previously reported to be up-regulated in E.coli were up-regulated in D. vulgaris; these genes included three ATPasegenes and a tryptophan synthase gene. Transcription of chaperone andprotease genes (encoding ATP-dependent Clp and La proteases and DnaK) wasalso elevated in D. vulgaris. As in E. coli, genes involved in flagellumsynthesis were down-regulated. The transcriptional data also identifiedregulators, distinct from sigma S and sigma E, that are likely part of aD. vulgaris Hildenborough-specific stress response system.Characterization of a study set of mutants with genes implicated inalkaline stress response deleted confirmed that there was protectiveinvolvement of the sodium/proton antiporter NhaC-2, tryptophanase A, andtwo putative regulators/histidine kinases (DVU0331 andDVU2580).

  15. Process for treating alkaline wastes for vitrification

    DOE Patents [OSTI]

    Hsu, Chia-lin W.

    1994-01-01T23:59:59.000Z

    According to its major aspects and broadly stated, the present invention is a process for treating alkaline waste materials, including high level radioactive wastes, for vitrification. The process involves adjusting the pH of the wastes with nitric acid, adding formic acid (or a process stream containing formic acid) to reduce mercury compounds to elemental mercury and MnO{sub 2} to the Mn(II) ion, and mixing with class formers to produce a melter feed. The process minimizes production of hydrogen due to noble metal-catalyzed formic acid decomposition during, treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. An important feature of the present invention is the use of different acidifying and reducing, agents to treat the wastes. The nitric acid acidifies the wastes to improve yield stress and supplies acid for various reactions; then the formic acid reduces mercury compounds to elemental mercury and MnO{sub 2}) to the Mn(II) ion. When the pH of the waste is lower, reduction of mercury compounds and MnO{sub 2}) is faster and less formic acid is needed, and the production of hydrogen caused by catalytically-active noble metals is decreased.

  16. Statistics of Met-Ocean Conditions Between West and Central Gulf of Mexico Based on Field Measurements

    E-Print Network [OSTI]

    Su, Lin

    2012-07-16T23:59:59.000Z

    Statistics of met-ocean conditions including wind, current and wave at the location between west and central Gulf of Mexico (GOM) are derived based on about three year of field measurements. Two-parameter Weibull distribution has been employed...

  17. Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign – Part 2: Model comparison and radical budget

    E-Print Network [OSTI]

    Dusanter, S.

    Measurements of hydroxyl (OH) and hydroperoxy (HO2) radicals were made during the Mexico City Metropolitan Area (MCMA) field campaign as part of the MILAGRO (Megacity Initiative: Local and Global Research Observations) ...

  18. Density fluctuation measurements by far-forward collective scattering in the MST reversed-field pinch

    SciTech Connect (OSTI)

    Ding, W. X.; Lin, L.; Brower, D. L. [Department of Physics and Astronomy, University of California Los Angeles, Los Angeles, California 90095 (United States); Duff, J. R.; Sarff, J. S. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

    2012-10-15T23:59:59.000Z

    The multichannel polarimeter-interferometer system on the MST reversed-field pinch can be utilized to measure far-forward collective scattering from electron density fluctuations. The collective scattering system has 11 viewing chords with {approx}8 cm spacing. The source is a 432 {mu}m (694 GHz) far infrared laser and the scattered power is measured using a heterodyne detection scheme. Collective scattering provides a line-integrated measurement of fluctuations within the divergence of the probe beam covering wavenumber range: k{sub Up-Tack} < 1.3 cm{sup -1}, corresponding k{sub Up-Tack }{rho}{sub s} < 1.3 ({rho}{sub s} is the ion-sound Larmor radius), the region of primary interest for turbulent fluctuation-induced transport. The perpendicular wavenumber consists of toroidal, poloidal, and radial contributions, which vary with chord position. Coherent modes associated with tearing instabilities and neutral-beam driven fast particles are observed along with broadband turbulence at frequencies up to 500 kHz. Changes in frequency are consistent with a Doppler shift due to parallel plasma flow.

  19. Self-heating in a GaN based heterostructure field effect transistor: Ultraviolet and visible Raman measurements and simulations

    E-Print Network [OSTI]

    Holtz, Mark

    Self-heating in a GaN based heterostructure field effect transistor: Ultraviolet and visible Raman online 8 December 2006 We report direct self-heating measurements for AlGaN/GaN heterostructure field density can be commensurately high, collisional energy loss from electrons to the crystal leads to self-heating

  20. Enhanced Oil Recovery Using the Alkaline-Surfactant-Polymer (ASP) 

    E-Print Network [OSTI]

    Musharova, Darya

    2010-07-14T23:59:59.000Z

    Alkaline Surfactant Polymer (ASP) process is a tertiary method of oil recovery that has promising results for future development. It has already been implemented in different areas of the United States such as Wyoming, west Texas, also in Canada...

  1. alkaline membrane cell: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fuelAnalysis of PtC electrode performance in a flowing- electrolyte alkaline fuel cell Fikile R 17 October 2011 Accepted 18 October 2011 Available online 12 November 2011...

  2. advanced alkaline water: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How does the use of advanced waterHow does the use of advanced water treatment affect energy Keller, Arturo A. 4 Development of conductometric biosensors based on alkaline...

  3. alkaline massif se: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  4. alkaline hydrothermal reaction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  5. alkaline hydrothermal vent: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  6. alkaline phosphatase activities: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  7. african alkaline fermentedfood: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  8. alkaline phosphatase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  9. alkaline phosphatase-conjugated oligonucleotide: Topics by E...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  10. alkaline complex south: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  11. alkaline membrane fuel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  12. alkaline anaerobic respiration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  13. alkaline province located: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  14. alkaline massif kola: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  15. A particulate non-specific alkaline phosphatase in Saccharomyces cerevisiae

    E-Print Network [OSTI]

    Mitchell, James Kent

    1980-01-01T23:59:59.000Z

    utant Strain DO4-AP2 24 24 24 30 31 36 39 41 43 43 43 46 46 51 51 TABLE OF CONTENTS (Continued) Isoelectric Focussing Page 53 IV. Discussion and Conclusions 56 V. References 65 VI, Vita 68 LIST OF TABLES Tables Page 1.... Fluorescent Readings of 4-methylumbelliferone 25 2. Fluorescent Readings of a-naphthol 25 3. Substrate Specificity of Particulate Alkaline Phosohatase 40 Intracellular Localization of Particulate Alkaline Phos- phatase 45 5. Specific Activity of a...

  16. Urban Dispersion Program MSG05 Field Study: Summary of Tracer and Meteorological Measurements

    SciTech Connect (OSTI)

    Allwine, K Jerry; Flaherty, Julia E.

    2006-08-09T23:59:59.000Z

    The Urban Dispersion Program is a multi-year project, funded by the U.S. Department of Homeland Security, to better understand the flow and dispersion of airborne contaminants through and around the deep street canyons of New York City. The first tracer and meteorological field study was a limited study conducted during March 2005 near the Madison Square Garden in midtown Manhattan. Six safe, inert, gaseous perfluorocarbon tracers were released simultaneously at five street-level locations during two experimental days. In addition to collecting tracer data, meteorological data were also collected. Brookhaven National Laboratory conducted the bulk of the tracer and meteorological field efforts with Pacific Northwest National Laboratory and Stevens Institute of Technology assisting by measuring the vertical profile of winds. The Environmental Protection Agency worked with Brookhaven National Laboratory in accomplishing the personal exposure component of the study. This report presents some results from this analysis. In general, different release locations showed vastly different plume footprints for tracer materials, and the situation was made very complex with upwind and/or crosswind transport of tracer near street-level for the different release locations. Overall wind speeds and directions upwind and over the city were generally constant throughout each of the two experimental periods.

  17. Tomographic imaging system for measuring impurity line emission in a field-reversed configuration

    SciTech Connect (OSTI)

    Roche, T.; Heidbrink, W. W.; McWilliams, R. [University of California, Irvine, California 92697 (United States); Bolte, N.; Garate, E.; Wessel, F. [University of California, Irvine, California 92697 (United States); Tri Alpha Energy, Inc., Rancho Santa Margarita, California 92688 (United States)

    2012-10-15T23:59:59.000Z

    A 16 chord optical tomography system has been developed and implemented in the flux coil generated-field reversed configuration (FRC). The chords are arranged in two fans of eight, which cover {approx}35% of the vessel area at the midplane. Each illuminate separate photomultiplier tubes (PMTs) which are fitted with narrow band-pass filters. In this case, filters are centered at 434.8 nm to measure emission from singly ionized argon. PMT crosstalk is negligible. Background noise due to electron radiation and H{sub {gamma}} line radiation is <10% of argon emission. The spatial resolution of the reconstruction is 1.5 cm. Argon is introduced using a puff valve and tube designed to impart the gas into the system as the FRC is forming. Reconstruction of experimental data results in time-dependent, 2D emissivity profiles of the impurity ions. Analysis of these data show radial, cross-field diffusion to be in the range of 10-10{sup 3} m{sup 2}/s during FRC equilibrium.

  18. Non Intrusive Measures for Determining the Minimum Field of View for User Search Task in 3D Virtual Environments

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Non Intrusive Measures for Determining the Minimum Field of View for User Search Task in 3D Virtual on the use of several novel non- intrusive temporal and quantitative measures of visual attention, such as engines. The use of this virtual camera can show interesting results for non-invasive study

  19. Accurate correction of magnetic field instabilities for high-resolution isochronous mass measurements in storage rings

    E-Print Network [OSTI]

    P. Shuai; H. S. Xu; Y. H. Zhang; Yu. A. Litvinov; M. Wang; X. L. Tu; K. Blaum; X. H. Zhou; Y. J. Yuan; G. Audi; X. L. Yan; X. C. Chen; X. Xu; W. Zhang; B. H. Sun; T. Yamaguchi; R. J. Chen; C. Y. Fu; Z. Ge; W. J. Huang; D. W. Liu; Y. M. Xing; Q. Zeng

    2014-07-13T23:59:59.000Z

    Isochronous mass spectrometry (IMS) in storage rings is a successful technique for accurate mass measurements of short-lived nuclides with relative precision of about $10^{-5}-10^{-7}$. Instabilities of the magnetic fields in storage rings are one of the major contributions limiting the achievable mass resolving power, which is directly related to the precision of the obtained mass values. A new data analysis method is proposed allowing one to minimise the effect of such instabilities. The masses of the previously measured at the CSRe $^{41}$Ti, $^{43}$V, $^{47}$Mn, $^{49}$Fe, $^{53}$Ni and $^{55}$Cu nuclides were re-determined with this method. An improvement of the mass precision by a factor of $\\sim 1.7$ has been achieved for $^{41}$Ti and $^{43}$V. The method can be applied to any isochronous mass experiment irrespective of the accelerator facility. Furthermore, the method can be used as an on-line tool for checking the isochronous conditions of the storage ring.

  20. On the Collective Magnetic Field Strength and Vector Structure of Dark Umbral Cores Measured by the Hinode Spectropolarimeter

    E-Print Network [OSTI]

    Schad, T A

    2015-01-01T23:59:59.000Z

    We study 7530 sunspot umbrae and pores measured by the Hinode Spectropolarimeter (SP) between November 2006 and November 2012. We primarily seek confirmation of the long term secular decrease in the mean magnetic field strength of sunspot umbrae found by Penn and Livingston (2011, IAU Symp. 273,126) between 1998 and 2011. The excellent SP photometric properties and full vector magnetic field determinations from full-Stokes Milne-Eddington inversions are used to address the interrelated properties of the magnetic field strength and brightness temperature for all umbral cores. We find non-linear relationships between magnetic field strength and umbral temperature (and continuum contrast), as well as between umbral radius and magnetic field strength. Using disambiguated vector data, we find that the azimuths measured in the umbral cores reflect an organization weakly influenced by Joy's law. The large selection of umbrae displays a log-normal size spectrum similar to earlier solar cycles. Influenced by the ampli...

  1. Laser measurement of H{sup -} ions in a field-effect-transistor based radio frequency ion source

    SciTech Connect (OSTI)

    Tanaka, N.; Matsuno, T.; Funaoi, T.; Ando, A. [Tohoku University, Aramaki 6-6-05, Aoba, Sendai, Miyagi 980-8579 (Japan); Tauchi, Y. [Yamaguchi University, Tokiwadai 2-16-1, Ube, Yamaguchi 755-8611 (Japan); Nakano, H.; Tsumori, K.; Takeiri, Y. [National Institute for Fusion Science, Oroshi-Cho 322-6, Toki, Gifu 509-5292 (Japan)

    2012-02-15T23:59:59.000Z

    Hydrogen negative ion density measurements are required to clarify the characteristics of negative ion production and ion source performance. Both of laser photodetachment and cavity ring down (CRD) measurements have been implemented to a field-effect-transistor based radio-frequency ion source. The density ratio of negative hydrogen ions to electrons was successfully measured by laser photodetachment and effect of magnetic filter field on negative ion density was confirmed. The calculated CRD signal showed that CRD mirrors with >99.990% reflectivity are required and loss of reflectivity due to cesium contamination should be minimized.

  2. Proximity detector circuits: an attractive alternative to tunnel diode oscillators for contactless measurements in pulsed magnetic fields

    SciTech Connect (OSTI)

    Altarawneh, Moaz M [Los Alamos National Laboratory; Mielke, Charles H [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    A new radio frequency oscillator circuit based on a proximity detector integrated circuit is described as an alternative for the traditional tunnel diode oscillator used for pulsed magnetic field measurements at low temperatures. The new circuit has been successfully applied to measure the superconducting upper critical field in Ba{sub 0.55}K{sub 0.45}Fe{sub 2}As{sub 2} single crystfl.ls up to 60 T. The new circuit design avoids many of the problems associated with tunnel diode circuits while keeping the advantages of contact less measurements in pulsed magnets.

  3. Atmospheric Radiation Measurement (ARM) Data from Manacapuru, Brazil for the Green Ocean Amazon (GOAMAZON) Field Campaign

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Amazon rain forest in Brazil is the largest broadleaf forest in the world, covering 7 million square kilometers of the Amazon Basin in South America. It represents over half of the planet’s remaining rain forests, and comprises the most biodiverse tract of tropical rain forest on the planet. Due to the sheer size of the Amazon rain forest, the area has a strong impact on the climate in the Southern Hemisphere. To understand the intricacies of the natural state of the Amazon rain forest, the Green Ocean Amazon, or GOAMAZON, field campaign is a two-year scientific collaboration among U.S. and Brazilian research organizations. They are conducting a variety of different experiments with dozens of measurement tools, using both ground and aerial instrumentation, including the ARM Aerial Facility's G-1 aircraft. For more information on the holistic view of the campaign, see the Department of Energy’s GOAMAZON website. As a critical component of GOAMAZON, the ARM Mobile Facility (AMF) will obtain measurements near Manacapuru, south of Manaus, Brazil, from January to December 2014. The city of Manaus, with a population of 3 million, uses high-sulfur oil as their primary source of electricity. The AMF site is situated to measure the atmospheric extremes of a pristine atmosphere and the nearby cities’ pollution plume, as it regularly intersects with the site. Along with other instrument systems located at the Manacapuru site, this deployment will enable scientists to study how aerosol and cloud life cycles are influenced by pollutant outflow from a tropical megacity.

  4. Method and apparatus for steady-state magnetic measurement of poloidal magnetic field near a tokamak plasma

    DOE Patents [OSTI]

    Woolley, Robert D. (Hillsborough, NJ)

    1998-01-01T23:59:59.000Z

    A method and apparatus for the steady-state measurement of poloidal magnetic field near a tokamak plasma, where the tokamak is configured with respect to a cylindrical coordinate system having z, phi (toroidal), and r axes. The method is based on combining the two magnetic field principles of induction and torque. The apparatus includes a rotor assembly having a pair of inductive magnetic field pickup coils which are concentrically mounted, orthogonally oriented in the r and z directions, and coupled to remotely located electronics which include electronic integrators for determining magnetic field changes. The rotor assembly includes an axle oriented in the toroidal direction, with the axle mounted on pivot support brackets which in turn are mounted on a baseplate. First and second springs are located between the baseplate and the rotor assembly restricting rotation of the rotor assembly about its axle, the second spring providing a constant tensile preload in the first spring. A strain gauge is mounted on the first spring, and electronic means to continually monitor strain gauge resistance variations is provided. Electronic means for providing a known current pulse waveform to be periodically injected into each coil to create a time-varying torque on the rotor assembly in the toroidal direction causes mechanical strain variations proportional to the torque in the mounting means and springs so that strain gauge measurement of the variation provides periodic magnetic field measurements independent of the magnetic field measured by the electronic integrators.

  5. Method and apparatus for steady-state magnetic measurement of poloidal magnetic field near a tokamak plasma

    DOE Patents [OSTI]

    Woolley, R.D.

    1998-09-08T23:59:59.000Z

    A method and apparatus are disclosed for the steady-state measurement of poloidal magnetic field near a tokamak plasma, where the tokamak is configured with respect to a cylindrical coordinate system having z, phi (toroidal), and r axes. The method is based on combining the two magnetic field principles of induction and torque. The apparatus includes a rotor assembly having a pair of inductive magnetic field pickup coils which are concentrically mounted, orthogonally oriented in the r and z directions, and coupled to remotely located electronics which include electronic integrators for determining magnetic field changes. The rotor assembly includes an axle oriented in the toroidal direction, with the axle mounted on pivot support brackets which in turn are mounted on a baseplate. First and second springs are located between the baseplate and the rotor assembly restricting rotation of the rotor assembly about its axle, the second spring providing a constant tensile preload in the first spring. A strain gauge is mounted on the first spring, and electronic means to continually monitor strain gauge resistance variations is provided. Electronic means for providing a known current pulse waveform to be periodically injected into each coil to create a time-varying torque on the rotor assembly in the toroidal direction causes mechanical strain variations proportional to the torque in the mounting means and springs so that strain gauge measurement of the variation provides periodic magnetic field measurements independent of the magnetic field measured by the electronic integrators. 6 figs.

  6. Environmental Measurement While Drilling System for Real-Time Field Screening of Contaminants

    SciTech Connect (OSTI)

    Lockwood, G.J.; Normann, R.A.; Williams, C.V.

    1999-02-22T23:59:59.000Z

    Sampling during environmental drilling is essential to fully characterize the spatial distribution and migration of subsurface contaminants. However, analysis of the samples is expensive and time-consuming: off-site laboratory analysis can take weeks or months. Real-time information on environmental conditions, drill bit location and temperature during drilling is valuable in many environmental restoration operations. This type of information can be used to provide field screening data and improved efficiency of site characterization activities. The Environmental Measurement-While-Drilling (EMWD) System represents an innovative blending of new and existing technology in order to obtain real-time data during drilling. The system consists of two subsystems. The down-hole subsystem (at the drill bit) consists of sensors, a power supply, a signal conditioning and transmitter board, and a radio-frequency (RF) coaxial cable. The up-hole subsystem consists of a battery pack/coil, pickup coil, receiver, and personal computer. The system is compatible with fluid miser drill pipe, a directional drilling technique that uses minimal drilling fluids and generates little to no secondary waste. In EMWD, downhole sensors are located behind the drill bit and linked by a high-speed data transmission system to a computer at the surface. Sandia-developed Windows{trademark}-based software is used for data display and storage. As drilling is conducted, data is collected on the nature and extent of contamination, enabling on-the-spot decisions regarding drilling and sampling strategies. Initially, the downhole sensor consisted of a simple gamma radiation detector, a Geiger-Mueller tube (GMT). The design includes data assurance techniques to increase safety by reducing the probability of giving a safe indication when an unsafe condition exists. The EMWD system has been improved by the integration of a Gamma Ray Spectrometer (GRS) in place of the GMT. The GRS consists of a sodium iodide-thallium activated crystal coupled to a photomultiplier tube (PMT). The output of the PMT goes to a multichannel analyzer (MCA).The MCA data is transmitted to the surface via a signal conditioning and transmitter board similar to that used with the GMT. The EMWD system is described and the results of the GRS field tests and field demonstration are presented.

  7. Measurement of fracture aperture fields using transmitted light: An evaluation of measurement errors and their influence on

    E-Print Network [OSTI]

    Detwiler, Russell

    Scott E. Pringle and Robert J. Glass Flow Visualization and Processes Laboratory, Sandia National Laboratories, Albuquerque, New Mexico Abstract. Understanding of single-phase and multiphase flow and transport light transmission techniques yield quantitative measurements of aperture, solute concentration

  8. Ionospheric currents correlated with geomagnetic induced currents; Freja magnetic field measurements and the sunburst monitor system

    SciTech Connect (OSTI)

    Zanetti, L.J.; Potemra, T.A.; Anderson, B.J.; Erlandson, R.E.; Holland, D.B. [Johns Hopkins Univ., Laurel, MD (United States)] [Johns Hopkins Univ., Laurel, MD (United States); Acuna, M.H. [NASA/Goddard Space Flight Center, Greenbelt, MD (United States)] [NASA/Goddard Space Flight Center, Greenbelt, MD (United States); Kappenman, J. [Minnesota Power, Duluth, MN (United States)] [Minnesota Power, Duluth, MN (United States); Lesher, R.; Feero, B. [Electric Research and Management, Inc., State College, PA (United States)] [Electric Research and Management, Inc., State College, PA (United States)

    1994-08-15T23:59:59.000Z

    Temporal and spatial fluctuations of large-scale electric currents totaling millions of amperes in the ionosphere have long been known to induce current and voltage in the Earth`s surface and on large manmade conductive structures. A strong, persistent solar wind can interact with the geomagnetic environment and produce auroral zone currents at mid latitudes. Presented here is a specific correlation of ionospheric auroral currents inferred from magnetic field measurements from the Swedish Freja satellite and induced current in the electric power distribution system on the east coast of the United States, in particular the Chalk Point, Maryland, transformer station. The event discussed here registered a Kp level of 6 to 8 and occurred on April 4-5, 1993. An important aspect is that information from both of these space- and ground-based monitoring systems is available automatically and in real time. In addition, satellite data from earlier local times, e.g., data monitored from European ground stations, can give precursor information of later North American geomagnetic activity. 24 refs., 2 figs.

  9. Field Measurements at River and Tidal Current Sites for Hydrokinetic Energy Development: Best Practices Manual

    SciTech Connect (OSTI)

    Neary, Vincent S [ORNL; Gunawan, Budi [Oak Ridge National Laboratory (ORNL)

    2011-09-01T23:59:59.000Z

    In this report, existing data collection techniques and protocols for characterizing open channel flows are reviewed and refined to further address the needs of the MHK industry. The report provides an overview of the hydrodynamics of river and tidal channels, and the working principles of modern acoustic instrumentation, including best practices in remote sensing methods that can be applied to hydrokinetic energy site characterization. Emphasis is placed upon acoustic Doppler velocimeter (ADV) and acoustic-Doppler current profiler (ADCP) instruments, as these represent the most practical and economical tools for use in the MHK industry. Incorporating the best practices as found in the literature, including the parameters to be measured, the instruments to be deployed, the instrument deployment strategy, and data post-processing techniques. The data collected from this procedure aims to inform the hydro-mechanical design of MHK systems with respect to energy generation and structural loading, as well as provide reference hydrodynamics for environmental impact studies. The standard metrics and protocols defined herein can be utilized to guide field experiments with MHK systems.

  10. SEM technique for imaging and measuring electronic transport in nanocomposites based on electric field induced contrast

    DOE Patents [OSTI]

    Jesse, Stephen (Knoxville, TN) [Knoxville, TN; Geohegan, David B. (Knoxville, TN) [Knoxville, TN; Guillorn, Michael (Brooktondale, NY) [Brooktondale, NY

    2009-02-17T23:59:59.000Z

    Methods and apparatus are described for SEM imaging and measuring electronic transport in nanocomposites based on electric field induced contrast. A method includes mounting a sample onto a sample holder, the sample including a sample material; wire bonding leads from the sample holder onto the sample; placing the sample holder in a vacuum chamber of a scanning electron microscope; connecting leads from the sample holder to a power source located outside the vacuum chamber; controlling secondary electron emission from the sample by applying a predetermined voltage to the sample through the leads; and generating an image of the secondary electron emission from the sample. An apparatus includes a sample holder for a scanning electron microscope having an electrical interconnect and leads on top of the sample holder electrically connected to the electrical interconnect; a power source and a controller connected to the electrical interconnect for applying voltage to the sample holder to control the secondary electron emission from a sample mounted on the sample holder; and a computer coupled to a secondary electron detector to generate images of the secondary electron emission from the sample.

  11. Measuring the rotation period distribution of field M-dwarfs with Kepler

    E-Print Network [OSTI]

    McQuillan, Amy; Mazeh, Tsevi

    2013-01-01T23:59:59.000Z

    We have analysed 10 months of public data from the Kepler space mission to measure rotation periods of main-sequence stars with masses between 0.3 and 0.55 M_sun. To derive the rotational period we introduce the autocorrelation function and show that it is robust against phase and amplitude modulation and residual instrumental systematics. Of the 2483 stars examined, we detected rotation periods in 1570 (63.2%), representing an increase of a factor ~ 30 in the number of rotation period determination for field M-dwarfs. The periods range from 0.37-69.7 days, with amplitudes ranging from 1.0-140.8 mmags. The rotation period distribution is clearly bimodal, with peaks at ~ 19 and ~ 33 days, hinting at two distinct waves of star formation, a hypothesis that is supported by the fact that slower rotators tend to have larger proper motions. The two peaks of the rotation period distribution form two distinct sequences in period-temperature space, with the period decreasing with increasing temperature, reminiscent of ...

  12. Lyman-? radiation of a probing metastable hydrogen beam to measure electric fields in diluted fluids and plasmas

    SciTech Connect (OSTI)

    Doveil, F.; Lejeune, A.; Chérigier-Kovacic, L. [Aix Marseille Université, CNRS, PIIM UMR 7345, FR-13397 Marseilles Cedex 20 (France)] [Aix Marseille Université, CNRS, PIIM UMR 7345, FR-13397 Marseilles Cedex 20 (France)

    2013-05-15T23:59:59.000Z

    The interaction between a metastable H(2s) atomic hydrogen beam and an external electric field leads to the emission of the Lyman-? line. It originates in the Stark mixing of the near-degenerate 2s{sub 1/2} and 2p{sub 1/2} levels separated by the Lamb shift. The quenched radiation proportional to the square of the electric field amplitude is recovered in vacuum by using such an atomic probe beam. For larger electric field, saturation is observed and related to the beam finite transit time. We also observe the strong enhancement of the signal when the field is oscillating at the Lamb shift frequency. This technique is applied in a plasma, offering an alternative way to measure weak electric fields by direct and non-intrusive means.

  13. Arrangement for measuring the field angle of a magnetic field as a function of axial position within a magnet bore tube

    DOE Patents [OSTI]

    Pidcoe, Stephen V. (Bonita, CA); Zink, Roger A. (Desoto, TX); Boroski, William N. (Aurora, IL); McCaw, William R. (Burr Ridge, IL)

    1993-01-01T23:59:59.000Z

    An arrangement for measuring the field angle of a magnetic field as a function of axial position within a magnet bore tube of a magnet such as is used with the Superconducting Super Collider (SSC). The arrangement includes a magnetic field alignment gauge that is carried through the magnet bore tube by a positioning shuttle in predetermined increments. The positioning shuttle includes an extensible body assembly which is actuated by an internal piston arrangement. A pair of spaced inflatable cuffs are carried by the body assembly and are selectively actuated in cooperation with pressurizing of the piston to selectively drive the positioning shuttle in an axial direction. Control of the shuttle is provided by programmed electronic computer means located exteriorly of the bore tube and which controls valves provided pressurized fluid to the inflatable cuss and the piston arrangement.

  14. Heat inactivation of alkaline phosphatase in human milk 

    E-Print Network [OSTI]

    Odumodu, Chinyelu Uzoamaka

    1979-01-01T23:59:59.000Z

    of bovine mii. k than in similar portions of human milk. The activity of the enzyme was, in general, three times more in colostrum than in normal human milk. A definite alkaline phosphatase acti. vity with stages of lactation wa- indeterminate because.... LIST OF FIGURES. I NTR ODD'CTI ON. vill 1X The Study and Its Purposes. The Objectives. . LITERATURE REVIEW 1 3 Distribution of the Enzyme in Various Milk Portions. Variation of Alkaline Phosphatase in Relation to 'the Progress of Lactation...

  15. Non-invasive field measurements of soil water content using a pulsed 14 MeV neutron generator

    E-Print Network [OSTI]

    Johnson, Peter D.

    Non-invasive field measurements of soil water content using a pulsed 14 MeV neutron generator S-3120, United States 1. Introduction Knowledge of soil water content is critical to agricultural, hydrological from H will be a function of the soils' water-content. To the best of our knowledge

  16. Wind Fields over the Great Lakes Measured by the SeaWinds Scatterometer on the QuikSCAT Satellite

    E-Print Network [OSTI]

    Wind Fields over the Great Lakes Measured by the SeaWinds Scatterometer on the QuikSCAT Satellite for wind retrieval over the Great Lakes on a daily basis. We use data acquired by the SeaWinds Scatterometer on the QuikSCAT (QSCAT) satellite launched in June 1999 to derive wind speeds and directions over

  17. A model of the AGS based on stepwise ray-tracing through the measured field maps of the main magnets

    SciTech Connect (OSTI)

    Dutheil Y.; Meot, F.; Tsoupas, N.

    2012-05-20T23:59:59.000Z

    Two-dimensional mid-plane magnetic field maps of two of the main AGS magnets were produced, from Hall probe measurements, for a series of different current settings. The analysis of these data yielded the excitation functions [1] and the harmonic coefficients [2] of the main magnets which have been used so far in all the models of the AGS. The constant increase of the computation power makes it possible today to directly use a stepwise raytracing through these measured field maps with a reasonable computation time. We describe in detail how these field maps have allowed the generation of models of the 6 different types of AGS main magnets, and how they are being handled with the Zgoubi ray-tracing code [3]. We give and discuss a number of results obtained regarding both beam and spin dynamics in the AGS, and we provide comparisons with other numerical and analytical modelling methods.

  18. Field Test Results from Lidar Measured Yaw Control for Improved Yaw Alignment with the NREL Controls Advanced Research Turbine: Preprint

    SciTech Connect (OSTI)

    Scholbrock, A.; Fleming, P.; Wright, A.; Slinger, C.; Medley, J.; Harris, M.

    2014-12-01T23:59:59.000Z

    This paper describes field tests of a light detection and ranging (lidar) device placed forward looking on the nacelle of a wind turbine and used as a wind direction measurement to directly control the yaw position of a wind turbine. Conventionally, a wind turbine controls its yaw direction using a nacelle-mounted wind vane. If there is a bias in the measurement from the nacelle-mounted wind vane, a reduction in power production will be observed. This bias could be caused by a number of issues such as: poor calibration, electromagnetic interference, rotor wake, or other effects. With a lidar mounted on the nacelle, a measurement of the wind could be made upstream of the wind turbine where the wind is not being influenced by the rotor's wake or induction zone. Field tests were conducted with the lidar measured yaw system and the nacelle wind vane measured yaw system. Results show that a lidar can be used to effectively measure the yaw error of the wind turbine, and for this experiment, they also showed an improvement in power capture because of reduced yaw misalignment when compared to the nacelle wind vane measured yaw system.

  19. SU-E-T-17: A Mathematical Model for PinPoint Chamber Correction in Measuring Small Fields

    SciTech Connect (OSTI)

    Li, T; Zhang, Y; Li, X; Heron, D.E.; Huq, M.Saiful [University of Pittsburgh Medical Center, Pittsburgh, PA (United States)

    2014-06-01T23:59:59.000Z

    Purpose: For small field dosimetry, such as measuring the cone output factor for stereotactic radiosurgery, ion chambers often result in underestimation of the dose, due to both the volume averaging effect and the lack of electron equilibrium. The purpose of this work is to develop a mathematical model, specifically for the pinpoint chamber, to calculate the correction factors corresponding to different type of small fields, including single cone-based circular field and non-standard composite fields. Methods: A PTW 0.015cc PinPoint chamber was used in the study. Its response in a certain field was modeled as the total contribution of many small beamlets, each with different response factor depending on the relative strength, radial distance to the chamber axis, and the beam angle. To get these factors, 12 cone-shaped circular fields (5mm,7.5mm, 10mm, 12.5mm, 15mm, 20mm, 25mm, 30mm, 35mm, 40mm, 50mm, 60mm) were irradiated and measured with the PinPoint chamber. For each field size, hundreds of readings were recorded for every 2mm chamber shift in the horizontal plane. These readings were then compared with the theoretical doses as obtained with Monte Carlo calculation. A penalized-least-square optimization algorithm was developed to find out the beamlet response factors. After the parameter fitting, the established mathematical model was validated with the same MC code for other non-circular fields. Results: The optimization algorithm used for parameter fitting was stable and the resulted response factors were smooth in spatial domain. After correction with the mathematical model, the chamber reading matched with the Monte Carlo calculation for all the tested fields to within 2%. Conclusion: A novel mathematical model has been developed for the PinPoint chamber for dosimetric measurement of small fields. The current model is applicable only when the beam axis is perpendicular to the chamber axis. It can be applied to non-standard composite fields. Further validation with other type of detectors is being conducted.

  20. alkaline direct ethanol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline direct ethanol First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Author's personal copy...

  1. alkaline cementitious materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline cementitious materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Discrete element...

  2. ORIGINAL PAPER Calcium Carbonate Nucleation in an Alkaline Lake

    E-Print Network [OSTI]

    ORIGINAL PAPER Calcium Carbonate Nucleation in an Alkaline Lake Surface Water, Pyramid Lake, Nevada (X) needed for calcium carbonate nucleation and crystal growth in Pyramid Lake (PL) surface water­16. Notwithstanding high X, calcium carbonate growth did not occur on aragonite single crystals suspended PL surface

  3. Variation in serum alkaline phosphatase activity in cattle

    E-Print Network [OSTI]

    Fletcher, Jesse Lane

    1956-01-01T23:59:59.000Z

    the serum was stored, the analysis was completed within ten days of the date of collection of the blood sample. The serum alkaline phosphatase activity was determined 17 by the method of Bessy, Lowry, and Brock (194-6), in which 0.1 ml. of serum is used...

  4. Increase in the Export of Alkalinity from North America's

    E-Print Network [OSTI]

    Berkowitz, Alan R.

    be fluvially exported. The fluvial export of terrestrial alkalinity is also the major source of oceanic bicarbonate or car- bonate through the weathering of the parent rock material, and the hydrologic cycle trans delivery can alter the export rates of elements with a weathering source (4). It has recently been shown

  5. alkaline earth elements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    earth elements First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Bose-Einstein condensation of alkaline...

  6. alkaline earth lanthanide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth lanthanide First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with...

  7. alkaline earth ruthenates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth ruthenates First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with...

  8. alkaline earth cations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth cations First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Noncovalent interaction or...

  9. alkaline earth compounds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth compounds First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with...

  10. alkaline earth transition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth transition First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 SU(N) magnetism in chains of...

  11. alkaline earth chalcogenides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth chalcogenides First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with...

  12. alkaline earth halogenides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    earth halogenides First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with alkaline earth...

  13. alkaline earth metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    earth metal First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effects of Alkaline Earth Metal Ion...

  14. alkali alkaline earth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali alkaline earth First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Long range interactions between...

  15. alkaline earth plasmas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth plasmas First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Static and Dynamic Structure...

  16. alkaline earth chlorides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline earth chlorides First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quantum computing with...

  17. alkaline air pollution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline air pollution First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Environmental Pollution Air...

  18. Exposure assessment of Electromagnetic Fields from Wireless Computer Networks (Wi-Fi); Phase 1 Laboratory Measurements

    E-Print Network [OSTI]

    Haddadi, Hamed

    Exposure assessment of Electromagnetic Fields from Wireless Computer Networks (Wi-Fi); Phase 1 networks, the most popular Wi-Fi devices used in the schools were identified. The regulatory standards bisecting the screen and keyboard. The maximum electric field strength recorded at 1 m varied from 719 mVm-1

  19. Uncertainty in the reactive transport model response to an alkaline perturbation in a clay formation

    E-Print Network [OSTI]

    Burnol, A.; Blanc, P.; Xu, T.; Spycher, N.; Gaucher, E.C.

    2006-01-01T23:59:59.000Z

    degradation of a concrete/clay interface, in Migration'05 -an alkaline plume in a clay barrier, Applied Geochemistry,AN ALKALINE PERTURBATION IN A CLAY FORMATION A. Burnol*, P.

  20. alkaline-earth hafnates bahfo3: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline-earth hafnates bahfo3 First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 Next Page Last Page Topic Index 1 Quantum computing with alkaline earth atoms CERN Preprints...

  1. Computer Modeling Illuminates Degradation Pathways of Cations in Alkaline Membrane Fuel Cells (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-08-01T23:59:59.000Z

    Cation degradation insights obtained by computational modeling could result in better performance and longer lifetime for alkaline membrane fuel cells.

  2. Behaviour model identification based on inverse modeling and using Optical Full Field Measurements (OFFM): application on rubber and steel

    SciTech Connect (OSTI)

    Velay, V.; Robert, L.; Schmidt, F.; Hmida, S.; Vallet, T. [Research Centre on Tools Materials and Processes (CROMeP), Ecole des mines d'Albi-Carmaux, 81013 ALBI Cedex 9 (France)

    2007-04-07T23:59:59.000Z

    Biaxial properties of materials (polymer or steel) used in many industrial processes are often difficult to measure. However, these properties are useful for the numerical simulations of plastic-processing operations like blow moulding or thermoforming for polymers and superplastic forming or single point incremental forming for steels. Today, Optical Full Field Measurements (OFFM) are promising tools for experimental analysis of materials. Indeed, they are able to provide a very large amount of data (displacement or strain) spatially distributed. In this paper, a mixed numerical and experimental investigation is proposed in order to identify multi-axial constitutive behaviour models. The procedure is applied on two different materials commonly used in forming processes: polymer (rubber in this first approach) and steel. Experimental tests are performed on various rubber and steel structural specimens (notched and open-hole plate samples) in order to generate heterogeneous displacement field. Two different behaviour models are considered. On the one hand, a Money-Rivlin hyperelastic law is investigated to describe the high levels of strain induced in tensile test performed on a rubber open-hole specimen. On the other hand, Ramberg-Osgood law allows to reproduce elasto-plastic behaviour of steel on a specimen that induces heterogeneous strain fields. Each parameter identification is based on a same Finite Element Model Updated (FEMU) procedure which consists in comparing results provided by the numerical simulation (ABAQUS) with full field measurements obtained by the DISC (Digital Image Stereo-Correlation) technique (Vic-3D)

  3. Temperature measurement of axisymmetric flames under the influence of magnetic field using Talbot interferometry

    SciTech Connect (OSTI)

    Agarwal, Shilpi, E-mail: sipi.agarwal@gmail.com, E-mail: manojklakra@gmail.com, E-mail: cshakher@iddc.iitd.ac.in; Kumar, Manoj, E-mail: sipi.agarwal@gmail.com, E-mail: manojklakra@gmail.com, E-mail: cshakher@iddc.iitd.ac.in; Shakher, Chandra, E-mail: sipi.agarwal@gmail.com, E-mail: manojklakra@gmail.com, E-mail: cshakher@iddc.iitd.ac.in [Instrument Design Development Centre, Indian Institute of Technology Delhi, HauzKhas, New Delhi - 110016 (India)

    2014-10-15T23:59:59.000Z

    Combustion process control is related with ecological improvement and the problem of energy efficiency; hence it has a wide interest at both economical and scientific levels. Application of a magnetic field is one of the most promising methods of combustion control. The presence of magnetic field induces the changes in flame behavior. The effect of uniform magnetic field developed by permanent magnet is studied by Talbot interferometry using circular gratings. Experimental results show a small decrease in flame temperature and increase in flame dimensions.

  4. EMF in your environment. Magnetic field measurements of everyday electrical devices

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    The publication compares the strength of 60 hertz magnetic fields produced by common electrical items and shows you how their strength diminishes as you move farther away from them. The information presented here has to do with the strength of the magnetic field; however, the authors aren't certain that the strength of the field is the only important consideration. It may turn out that other factors are also important. Future research is likely to reveal that the information given in the publication is only part of the story.

  5. Measurements on Subscale Y-Ba-Cu-O Racetrack Coils at 77 K and Self-Field

    SciTech Connect (OSTI)

    Wang, X.; Caspi, S.; Cheng, D. W.; Dietderich, D. R.; Felice, H.; Ferracin, P.; Godeke, A.; Joseph, J. M.; Lizarazo, J.; Prestemon, S. O.; Sabbi, G.

    2009-10-19T23:59:59.000Z

    YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) tapes carry significant amount of current at fields beyond the limit of Nb-based conductors. This makes the YBCO tapes a possible conductor candidate for insert magnets to increase the bore field of Nb{sub 3}Sn high-field dipoles. As an initial step of the YBCO insert technology development, two subscale racetrack coils were wound using Kapton-insulated commercial YBCO tapes. Both coils had two layers; one had 3 turns in each layer and the other 10 turns. The coils were supported by G10 side rails and waxed strips and not impregnated. The critical current of the coils was measured at 77 K and self-field. A 2D model considering the magnetic-field dependence of the critical current was used to estimate the expected critical current. The measured results show that both coils reached 80%-95% of the expected values, indicating the feasibility of the design concept and fabrication process.

  6. Author's personal copy Performance of an alkaline-acid direct ethanol fuel cell

    E-Print Network [OSTI]

    Zhao, Tianshou

    Author's personal copy Performance of an alkaline-acid direct ethanol fuel cell L. An, T.S. Zhao ethanol fuel cell Alkaline-acid Species concentrations Membrane thickness Power density a b s t r a c t This paper reports on the performance of an alkaline-acid direct ethanol fuel cell (AA-DEFC) that is composed

  7. Irradiators for measuring the biological effects of low dose-rate ionizing radiation fields

    E-Print Network [OSTI]

    Davidson, Matthew Allen

    2011-01-01T23:59:59.000Z

    Biological response to ionizing radiation differs with radiation field. Particle type, energy spectrum, and dose-rate all affect biological response per unit dose. This thesis describes methods of spectral analysis, ...

  8. Measuring Instantaneous Frequency of Local Field Potential Oscillations using the Kalman Smoother

    E-Print Network [OSTI]

    Nguyen, David P.

    Rhythmic local field potentials (LFPs) arise from coordinated neural activity. Inference of neural function based on the properties of brain rhythms remains a challenging data analysis problem. Algorithms that characterize ...

  9. Measuring and shimming the magnetic field of a 4 Tesla MRI magnet

    E-Print Network [OSTI]

    Kyriazis, Georgios

    1993-01-01T23:59:59.000Z

    The Biomedical Magnetic Resonance Laboratory (BMRL) of the University of Illinois at Urbana-Champaign (UIUC) has ordered from the Texas Accelerator Center (TAC) a superconducting, self-shielded, solenoidal magnet with a maximum field of 4 Tesla...

  10. Equilibrium and stability studies of plasmas confined in a dipole magnetic field using magnetic measurements

    E-Print Network [OSTI]

    Karim, Ishtak

    2007-01-01T23:59:59.000Z

    The Levitated Dipole Experiment (LDX) is the first experiment of its kind to use a levitated current ring to confine a plasma in a dipole magnetic field. Unlike most other confinement devices, plasma compressibility ...

  11. Calculation methods and detection techniques for electric and magnetic fields from power lines with measurement verification

    E-Print Network [OSTI]

    Mamishev, Alexander V

    1994-01-01T23:59:59.000Z

    of extremely low frequency magnetic fields in the direct proximity of the conductors of power lines, situated well above the ground level. Conventional approximation of a sagged wire as a straight horizontal conductor of infinite length has been substituted...

  12. Permeability Change of Crystalline Silicate Mineral-Packed Bed Column by Highly Alkaline Plume

    SciTech Connect (OSTI)

    Hideo Usui; Yuichi Niibori; Hitoshi Mimura [Department of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University, Aramaki Aza Aoba 6-6-01-2, Aoba-ku, Sendai, 980-8579 (Japan); Osamu Tochiyama [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577 (Japan)

    2007-07-01T23:59:59.000Z

    For the construction of the geological disposal system, the use of the cementitious material may change the permeability of the natural barrier around the repository. Cementitious materials may alter the pH of ground water to highly alkaline. Also, the potential permeability change of the natural barrier is one of the notable factors for performance assessments of geological disposal systems. In the high pH region, the solubility of silica is very high compared to that in the natural pH (around 8). Therefore, highly alkaline groundwater would dissolve and alter a part of rock surface. Usui et al. (2005) reported that the change of mineral pore structure due to chemical reaction is the key factor to consider the change of the permeability [5-6]. Moreover, such a change of the pore structure was considered to be the result of the spatial heterogeneity of chemical composition. Since such spatial heterogeneity exists also in the sedimentary rocks consisting of crystalline minerals such as quartz and feldspar, we need to examine natural rock, in order to obtain more reliable understanding about the change of permeability induced by highly alkaline groundwater (plume). In this study, silica sand as crystalline mineral was packed in the column, and the effect of dissolution induced by the highly alkaline plume on the permeability-change was examined. The silica sand particles mainly consist of SiO{sub 2} and include Al{sub 2}O{sub 3}, FeO, and K{sub 2}O. The volumetric flow rate and the pressure difference between the inlet and outlet of the column were measured, and the permeability was calculated. At the same time, the concentrations of elements in the fluid were measured by ICP-AES. The experimental result showed that permeability decreased gradually, although the silica sand was continuously dissolved in the column. The behavior of the permeability is considered to be the result from the rearrangement of the particles, or precipitation of secondary mineral. In the column test using the silica sand as packed mineral, the flow-path seems to be clogged by the rearrangement of the particles rather than the increase of the pore space between the particles. (authors)

  13. Laboratory measured characteristics of hot-mix asphaltic concrete as related to field performance

    E-Print Network [OSTI]

    TenBrook, James Joseph

    1966-01-01T23:59:59.000Z

    Laboratory Army Corps of Engineers Study o THD 1';otorized Press Gyratory Testing 1'~machine ~'marshall Device California Ilachine 1G Field Test Sites Test Section Layout 12 Maco Section Layout 13 Paving A Test Section 14 Coring One Meek Samples 15... molded in their laboratories at the standard $0 blow compactive effort. These marshall specimens were used to provide density and stability data; and to provide a means of comparison between field and laboratory specimens. The significant conclusions...

  14. Method of measuring the dc electric field and other tokamak parameters

    DOE Patents [OSTI]

    Fisch, Nathaniel J. (Princeton, NJ); Kirtz, Arnold H. (Princeton Junction, NJ)

    1992-01-01T23:59:59.000Z

    A method including externally imposing an impulsive momentum-space flux to perturb hot tokamak electrons thereby producing a transient synchrotron radiation signal, in frequency-time space, and the inference, using very fast algorithms, of plasma parameters including the effective ion charge state Z.sub.eff, the direction of the magnetic field, and the position and width in velocity space of the impulsive momentum-space flux, and, in particular, the dc toroidal electric field.

  15. Measuring stellar magnetic fields with the low resolution spectropolarimeter of the William Herschel Telescope

    E-Print Network [OSTI]

    F. Leone

    2007-09-13T23:59:59.000Z

    Despite the influence of magnetic fields on the structure and evolution of stars is largely demonstrated from the theoretical point of view, their observational evidence in non-degenerated stars is still rather scanty and mainly circumscribed to bright objects (V 600, show an internal error of <50 G selecting the whole interval and <200 G within a Balmer line. Ripples in the Stokes V spectra of HD3360 result in an instrumental positive magnetic field certainly not larger than 80 G.

  16. Measurement and simulation of a droplet population in a turbulent flow field Rbert Bords a,1

    E-Print Network [OSTI]

    John, Volker

    online 30 May 2012 Keywords: Two-phase turbulent flow Disperse droplet population Non-intrusive are determined by non-intrusive measurements. A direct discretization of the 4D equation for the droplet size deter- mined by means of non-intrusive measurement techniques. In this way, suitable time

  17. Possibilities for Measurement and Compensation of Stray DC Electric Fields Acting on Drag-Free Test Masses

    E-Print Network [OSTI]

    W. J. Weber; L. Carbone; A. Cavalleri; R. Dolesi; C. D. Hoyle; M. Hueller; S. Vitale

    2003-09-13T23:59:59.000Z

    DC electric fields can combine with test mass charging and thermal dielectric voltage noise to create significant force noise acting on the drag-free test masses in the LISA (Laser Interferometer Space Antenna) gravitational wave mission. This paper proposes a simple technique to measure and compensate average stray DC potentials at the mV level, yielding substantial reduction in this source of force noise. We discuss the attainable resolution for both flight and ground based experiments.

  18. Reversing the weak measurement of an arbitrary field with finite photon number 

    E-Print Network [OSTI]

    Sun, Qingqing; Al-Amri, M.; Zubairy, M. Suhail.

    2009-01-01T23:59:59.000Z

    phase qubit was performed. A general procedure for N-dimensional sys- tem was also proposed in #3;12#4;, which requires 2N steps. An important question remains: can we reverse a multidi- mensional state in a simpler way? In Sec. II, we address... is the conclusion. II. SCHEMES The state of interest is an arbitrary cavity field with finite photon number #5;n,m=0nmax #1;nm#6;n#7;#8;m#6;, which is continuously monitored by an ideal photon detector outside. If there is no click, the field evolves into #5;n...

  19. Design of A Conduction-cooled 4T Superconducting Racetrack for Multi-field Coupling Measurement System

    E-Print Network [OSTI]

    Chen, Yuquan; Wu, Wei; Guan, Mingzhi; Wu, Beimin; Mei, Enming; Xin, Canjie

    2015-01-01T23:59:59.000Z

    A conduction-cooled superconducting magnet producing a transverse field of 4 Tesla has been designed for the new generation multi-field coupling measurement system, which was used to study the mechanical behavior of superconducting samples at cryogenic temperature and intense magnetic fields. Considering experimental costs and coordinating with system of strain measurements by contactless signals (nonlinear CCD optics system), the racetrack type for the coil winding was chosen in our design, and a compact cryostat with a two-stage GM cryocooler was designed and manufactured for the superconducting magnet. The magnet was composed of a pair of flat racetrack coils wound by NbTi/Cu superconducting composite wires, a copper and stainless steel combinational form and two Bi2Sr2CaCu2Oy superconducting current leads. All the coils were connected in series and can be powered with a single power supply. The maximum central magnetic field is 4 T. In order to support the high stress and uniform thermal distribution in t...

  20. Reversing the weak measurement of an arbitrary field with finite photon number

    E-Print Network [OSTI]

    Sun, Qingqing; Al-Amri, M.; Zubairy, M. Suhail.

    2009-01-01T23:59:59.000Z

    this weak measurement does not totally collapse the system, the infor- mation of the initial state is passed over to the final state. If such retained information is complete, it would be possible to recover the initial state with some operations... between the unsharpness of the measurement and the best efficiency of the reversing operation #3;10#4;. In a recent experiment #3;11#4;, based on a proposal by Korotkov and Jordan #3;12#4;, the rever- sal of a weak measurement on a superconducting...

  1. Use of Remote Technology in the Surface Water Environmental Monitoring Program at SRS Reducing Measurements in the Field - 13336

    SciTech Connect (OSTI)

    Eddy, T.; Terry, B.; Meyer, A.; Hall, J.; Allen, P.; Hughey, D.; Hartley, T. [Savannah River Nuclear Solutions, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River Nuclear Solutions, Savannah River Site, Aiken, SC 29808 (United States)

    2013-07-01T23:59:59.000Z

    There are a wide range of sensor and remote technology applications available for use in environmental monitoring programs. Each application has its own set of limitations and can be challenging when attempting to utilize it under diverse environmental field conditions. The Savannah River Site Environmental Monitoring Program has implemented several remote sensing and surface water flow technologies that have increased the quality of the data while reducing the number of field measurements. Implementation of this technology reduced the field time for personnel that commute across the Savannah River Site (SRS) over a span of 310 square miles. The wireless surface water flow technology allows for immediate notification of changing field conditions or equipment failure thus reducing data-loss or erroneous field data and improving data-quality. This wireless flow technology uses the stage-to-flow methodology coupled with implementation of a robust highly accurate Acoustic Doppler Profiler system for measuring discharge under various field conditions. Savings for implementation of the wireless flow application and Flowlink{sup R} technology equates to approximately 1175 hours annually for the radiological liquid effluent and surveillance programs. The SonTek River Suveyor and Flowtracker technologies are utilized for calibration of the wireless flow monitoring devices in the site streams and validation of effluent flows at the SRS. Implementation of similar wireless devices is also planned in the National Pollutant Discharge Elimination System (NPDES) Storm-water Monitoring Program. SRS personnel have been developing a unique flow actuator device. This device activates an ISCO{sup TM} automated sampler under flowing conditions at storm-water outfall locations across the site. This technology is unique in that it was designed to be used under field conditions with rapid changes in flow and sedimentation where traditional actuators have been unsuccessful in tripping the automated sampler. In addition, automated rain gauges will be tied into this technology for immediate notification of rain at storm-water locations further enhancing the automation of environmental data collection. These technological improvements at SRS have led to data-quality improvements while reducing the field technician time in the field and costs for maintaining the traditional environmental monitoring applications. (authors)

  2. Particle Image Velocimetry measurement of indoor airflow field: A review of the technologies and applications

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    quantitative information of indoor air distribution and local air velocity around occupants or passengers, which has strong relationship with the ventilation effectiveness, the pollutant transportation Velocimetry (PIV); Measurement Technology 1. Introduction Ventilation concepts, including natural ventilation

  3. Lift, drag and flow-field measurements around a small ornithopter

    SciTech Connect (OSTI)

    Balakumar, B J [Los Alamos National Laboratory; Chavez - Alarcon, Ramiro [NMSU; Shu, Fangjun [NMSU

    2011-01-12T23:59:59.000Z

    The aerodynamics of a flight-worthy, radio controlled ornithopter is investigated using a combination of Particle-Image Velocimetry (PIV), load cell measurements, and high-speed photography of smoke visualizations. The lift and thrust forces of the ornithopter are measured at various flow speeds, flapping frequencies and angles of attack to characterize the flight performance. These direct force measurements are then compared with forces estimated using control volume analysis on PIV data. High-speed photography of smoke streaks is used to visualize the evolution of leading edge vortices, and to qualitatively infer the effect of wing deformation on the net downwash. Vortical structures in the wake are compared to previous studies on root flapping, and direct measurements of flapping efficiency are used to argue that the current ornithopter operates sub-optimally in converting the input energy into propulsive work.

  4. Field Instruments for Real Time In-Situ Crude Oil Concentration Measurements

    E-Print Network [OSTI]

    Fuller, C. B.; Bonner, J. S.; Page, C. A.; Arrambide, G.; Sterling Jr., M. C.; Ojo, T.

    The Texas Water Resources Institute awarded a Mill Scholarship to M.C. Sterling, Jr in 2002. This project describes five sensors for rapid monitoring of crude oil concentrations in an aquatic system. These measurements are critical for monitoring...

  5. mConverse: Inferring Conversation Episodes from Respiratory Measurements Collected in the Field

    E-Print Network [OSTI]

    Kumar, Santosh

    , Experimentation, Measurement, Human Factors Permission to make digital or hard copies of all or part of this work Electrical & Comp. Engg. Behavioral Medicine University of Memphis The Ohio State University University

  6. POISON SPIDER FIELD CHEMICAL FLOOD PROJECT, WYOMING

    SciTech Connect (OSTI)

    Douglas Arnell; Malcolm Pitts; Jie Qi

    2004-11-01T23:59:59.000Z

    A reservoir engineering and geologic study concluded that approximate 7,852,000 bbls of target oil exits in Poison Spider. Field pore volume, OOIP, and initial oil saturation are defined. Potential injection water has a total dissolved solids content of 1,275 mg/L with no measurable divalent cations. If the Lakota water consistently has no measurable cations, the injection water does not require softening to dissolve alkali. Produced water total dissolved solids were 2,835 mg/L and less than 20 mg/L hardness as the sum of divalent cations. Produced water requires softening to dissolve chemicals. Softened produced water was used to dissolve chemicals in these evaluations. Crude oil API gravity varies across the field from 19.7 to 22.2 degrees with a dead oil viscosity of 95 to 280 cp at 75 F. Interfacial tension reductions of up to 21,025 fold (0.001 dyne/cm) were developed with fifteen alkaline-surfactant combinations at some alkali concentration. An additional three alkaline-surfactant combinations reduced the interfacial tension greater than 5,000 fold. NaOH generally produced the lowest interfacial tension values. Interfacial tension values of less than 0.021 dyne/cm were maintained when the solutions were diluted with produced water to about 60%. Na{sub 2}CO{sub 3} when mixed with surfactants did not reduce interfacial tension values to levels at which incremental oil can be expected. NaOH without surfactant interfacial tension reduction is at a level where some additional oil might be recovered. Most of the alkaline-surfactant-polymer solutions producing ultra low interfacial tension gave type II- phase behavior. Only two solutions produced type III phase behavior. Produced water dilution resulted in maintenance of phase type for a number of solutions at produced water dilutions exceeding 80% dilution. The average loss of phase type occurred at 80% dilution. Linear corefloods were performed to determine relative permeability end points, chemical-rock compatibility, polymer injectivity, dynamic chemical retention by rock, and recommended injected polymer concentration. Average initial oil saturation was 0.796 Vp. Produced water injection recovered 53% OOIP leaving an average residual oil saturation of 0.375 Vp. Poison Spider rock was strongly water-wet with a mobility ratio for produced water displacing the 280 cp crude oil of 8.6. Core was not sensitive to either alkali or surfactant injection. Injectivity increased 60 to 80% with alkali plus surfactant injection. Low and medium molecular weight polyacrylamide polymers (Flopaam 3330S and Flopaam 3430S) dissolved in either an alkaline-surfactant solution or softened produced water injected and flowed through Poison Spider rock. Recommended injected polyacrylamide concentration is 2,100 mg/L for both polymers for a unit mobility ratio. Radial corefloods were performed to evaluate oil recovery efficiency of different chemical solutions. Waterflood oil recovery averaged 46.4 OOIP and alkaline-surfactant-polymer flood oil recovery averaged an additional 18.1% OIP for a total of 64.6% OOIP. Oil cut change due to injection of a 1.5 wt% Na{sub 2}CO{sub 3} plus 0.05 wt% Petrostep B-100 plus 0.05 wt% Stepantan AS1216 plus 2100 mg/L Flopaam 3430S was from 2% to a peak of 23.5%. Additional study might determine the impact on oil recovery of a lower polymer concentration. An alkaline-surfactant-polymer flood field implementation outline report was written.

  7. Measuring CP violation within Effective Field Theory of inflation from CMB

    E-Print Network [OSTI]

    Sayantan Choudhury; Barun Kumar Pal; Banasri Basu; Pratul Bandyopadhyay

    2015-03-26T23:59:59.000Z

    We have derived an effective potential for inflationary scenario from torsion and quanatum gravity correction in terms of the scalar field hidden in torsion. A strict bound on the CP violating $\\theta$ parameter, ${\\cal O}(10^{-10})<\\theta<{\\cal O}(10^{-9})$ has been obtained, using Planck+WMAP9 best fit cosmological parameters.

  8. Lightning-driven electric fields measured in the lower ionosphere: Implications for transient luminous events

    E-Print Network [OSTI]

    Thomas, Jeremy N.

    conductivity enhancement, or it might be evidence of flaws in the electromagnetic pulse mechanism for elves-electrostatic field (QSF) model for sprites and halos and the electromagnetic pulse (EMP) model for elves. In the QSF been successfully accomplished, since it is typically too low in altitude for rockets and satellites

  9. Alkaline industrial waters and wetlands: prospects for effective treatment

    E-Print Network [OSTI]

    Heal, Kate

    - sources · High rates of calcite (CaCO3) precipitation as waters take in atmospheric CO2 Ca2+ + CO3 2- CaCO setting · Two leachate sources: input increases alkalinity (>1500mg/L as CaCO3), pH (>12) and Ca2+ (>600mg/L) · CM2: Pilot CW sized by CaCO3 removal rates from volunteer system · CM3: Monitored through natural

  10. Positive Active Material For Alkaline Electrolyte Storage Battert Nickel Electrodes

    DOE Patents [OSTI]

    Bernard, Patrick (Massy, FR); Baudry, Michelle (Le Pontaroux, FR)

    2000-12-05T23:59:59.000Z

    A method of manufacturing a positive active material for nickel electrodes of alkaline storage batteries which consists of particles of hydroxide containing mainly nickel and covered with a layer of a hydroxide phase based on nickel and yttrium is disclosed. The proportion of the hydroxide phase is in the range 0.15% to 3% by weight of yttrium expressed as yttrium hydroxide relative to the total weight of particles.

  11. Probing the Kondo Lattice Model with Alkaline Earth Atoms

    E-Print Network [OSTI]

    Michael Foss-Feig; Michael Hermele; Ana Maria Rey

    2009-12-24T23:59:59.000Z

    We study transport properties of alkaline-earth atoms governed by the Kondo Lattice Hamiltonian plus a harmonic confining potential, and suggest simple dynamical probes of several different regimes of the phase diagram that can be implemented with current experimental techniques. In particular, we show how Kondo physics at strong coupling, low density, and in the heavy fermion phase is manifest in the dipole oscillations of the conduction band upon displacement of the trap center.

  12. Steady-state superradiance with alkaline earth atoms

    E-Print Network [OSTI]

    D. Meiser; M. J. Holland

    2009-12-03T23:59:59.000Z

    Earth-alkaline-like atoms with ultra-narrow transitions open the door to a new regime of cavity quantum electrodynamics. That regime is characterized by a critical photon number that is many orders of magnitude smaller than what can be achieved in conventional systems. We show that it is possible to achieve superradiance in steady state with such systems. We discuss the basic underlying mechanisms as well as the key experimental requirements

  13. A compact high-performance low-field NMR apparatus for measurements on fluids at very high pressures and temperatures

    SciTech Connect (OSTI)

    Freedman, R.; Anand, V., E-mail: VAnand@slb.com; Ganesan, K.; Tabrizi, P.; Torres, R. [Schlumberger Technology Corp., 110 Schlumberger Drive, Sugar Land, Texas 77478 (United States)] [Schlumberger Technology Corp., 110 Schlumberger Drive, Sugar Land, Texas 77478 (United States); Grant, B. [Grant Innovation, 618 Mesquite Drive, Cedar Creek, Texas 78612 (United States)] [Grant Innovation, 618 Mesquite Drive, Cedar Creek, Texas 78612 (United States); Catina, D. [National Oilwell Varco, 10302 Mula Road, Stafford, Texas 77477 (United States)] [National Oilwell Varco, 10302 Mula Road, Stafford, Texas 77477 (United States); Ryan, D.; Borman, C.; Krueckl, C. [Schlumberger DBR Technology Center, 9450–17 Avenue NW, Edmonton, Alberta (Canada)] [Schlumberger DBR Technology Center, 9450–17 Avenue NW, Edmonton, Alberta (Canada)

    2014-02-15T23:59:59.000Z

    We discuss an innovative new high-performance apparatus for performing low-field Nuclear Magnetic Resonance (NMR) relaxation times and diffusion measurements on fluids at very high pressures and high temperatures. The apparatus sensor design and electronics specifications allow for dual deployment either in a fluid sampling well logging tool or in a laboratory. The sensor and electronics were designed to function in both environments. This paper discusses the use of the apparatus in a laboratory environment. The operating temperature and pressure limits, and the signal-to-noise ratio (SNR) of the new system exceed by a very wide margin what is currently possible. This major breakthrough was made possible by a revolutionary new sensor design that breaks many of the rules of conventional high pressure NMR sensor design. A metallic sample holder capable of operating at high pressures and temperatures is provided to contain the fluid under study. The sample holder has been successfully tested for operation up to 36 Kpsi. A solenoid coil wound on a slotted titanium frame sits inside the metallic sample holder and serves as an antenna to transmit RF pulses and receive NMR signals. The metal sample holder is sandwiched between a pair of gradient coils which provide a linear field gradient for pulsed field gradient diffusion measurements. The assembly sits in the bore of a low-gradient permanent magnet. The system can operate over a wide frequency range without the need for tuning the antenna to the Larmor frequency. The SNR measured on a water sample at room temperature is more than 15 times greater than that of the commercial low-field system in our laboratory. Thus, the new system provides for data acquisition more than 200 times faster than was previously possible. Laboratory NMR measurements of relaxations times and diffusion coefficients performed at pressures up to 25 Kpsi and at temperatures up to 175?°C with crude oils enlivened with dissolved hydrocarbon gases (referred to as “live oils”) are shown. This is the first time low-field NMR measurements have been performed at such high temperatures and pressures on live crude oil samples. We discuss the details of the apparatus design, tuning, calibration, and operation. NMR data acquired at multiple temperatures and pressures on a live oil sample are discussed.

  14. Measurements of the force fields within an acoustic standing wave using holographic optical tweezers

    SciTech Connect (OSTI)

    Bassindale, P. G.; Drinkwater, B. W. [Faculty of Engineering, Queens building, University of Bristol, Bristol BS8 1TR (United Kingdom); Phillips, D. B. [Department of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ (United Kingdom); Barnes, A. C. [Department of Physics, H.H.Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL (United Kingdom)

    2014-04-21T23:59:59.000Z

    Direct measurement of the forces experienced by micro-spheres in an acoustic standing wave device have been obtained using calibrated optical traps generated with holographic optical tweezers. A micro-sphere, which is optically trapped in three dimensions, can be moved through the acoustic device to measure forces acting upon it. When the micro-sphere is subjected to acoustic forces, it's equilibrium position is displaced to a position where the acoustic forces and optical forces are balanced. Once the optical trapping stiffness has been calibrated, observation of this displacement enables a direct measurement of the forces acting upon the micro-sphere. The measured forces are separated into a spatially oscillating component, attributed to the acoustic radiation force, and a constant force, attributed to fluid streaming. As the drive conditions of the acoustic device were varied, oscillating forces (>2.5 pN{sub pp}) and streaming forces (<0.2 pN) were measured. A 5??m silica micro-sphere was used to characterise a 6.8?MHz standing wave, ??=?220??m, to a spatial resolution limited by the uncertainty in the positioning of the micro-sphere (here to within 2?nm) and with a force resolution on the order of 10 fN. The results have application in the design and testing of acoustic manipulation devices.

  15. Investigations Into the Nature of Alkaline Soluble, Non-Pertechnetate Technetium

    SciTech Connect (OSTI)

    Rapko, Brian M.; Bryan, Samuel A.; Chatterjee, Sayandev; Edwards, Matthew K.; Levitskaia, Tatiana G.; Peterson, James M.; Peterson, Reid A.; Sinkov, Sergey I.

    2013-11-14T23:59:59.000Z

    This report summarizes work accomplished in fiscal year (FY) 2013, exploring the chemistry of a low-valence technetium(I) species, [Tc(CO)3(H2O)3]+, a compound of interest due to its implication in the speciation of alkaline-soluble technetium in several Hanford tank waste supernatants. Various aspects of FY 2013’s work were sponsored both by Washington River Protection Solutions and the U.S. Department of Energy’s Office of River Protection; because of this commonality, both sponsors’ work is summarized in this report. There were three tasks in this FY 2013 study. The first task involved examining the speciation of [(CO)3Tc(H2O)3]+ in alkaline solution by 99Tc nuclear magnetic resonance spectroscopy. The second task involved the purchase and installation of a microcalorimeter suitable to study the binding affinity of [(CO)3Tc(H2O)3]+ with various inorganic and organic compounds relevant to Hanford tank wastes, although the actual measure of such binding affinities is scheduled to occur in future FYs. The third task involved examining the chemical reactivity of [(CO)3Tc(H2O)3]+ as relevant to the development of a [(CO)3Tc(H2O)3]+ spectroelectrochemical sensor based on fluorescence spectroscopy.

  16. Luminescence properties of Eu-activated alkaline and alkaline-earth silicate Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}

    SciTech Connect (OSTI)

    Wang, Jing [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Huang, Yanlin, E-mail: huang@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Wang, Xigang, E-mail: wangxigang@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Qin, Lin [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Seo, Hyo Jin, E-mail: hjseo@pknu.ac.kr [Department of Physics and Center for Marine-Integrated Biomedical Technology, Pukyong National University, Busan 608-737 (Korea, Republic of)

    2014-07-01T23:59:59.000Z

    Highlights: • A novel yellow-emitting alkaline and alkaline-earth silicate Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} was first developed. • Under excitation with UV or near UV light the silicate presents broad emission band centered at 580 nm. - Abstract: Yellow-emitting phosphors of Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} was prepared by wet chemistry sol–gel method. X-ray powder diffraction and SEM measurements were applied to characterize the structure and morphology, respectively. The luminescence properties were investigated by the photoluminescence excitation and emission spectra, decay curve (lifetimes), CIE coordinates and the internal quantum efficiencies. The excitation spectra can match well with the emission light of near UV-LED chips (360–400 nm). Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} presents a symmetric emission band from 4f{sup 6}5d{sup 1} ? 4f{sup 7}({sup 8}S{sub 7/2}) transitions of Eu{sup 2+} ions on doping below 3.0 mol%. On increasing Eu-doping levels, the sample contains two kinds of emission centers, i.e., Eu{sup 2+} and Eu{sup 3+} ions, which present the characteristic broad band (5d ? 4f) and narrower (4f ? 4f) luminescence lines, respectively. The energy transfer, the luminescence thermal stability (activation energy ?E for thermal quenching) and luminescence mechanism of Na{sub 2}Ca{sub 3}Si{sub 6}O{sub 16}:Eu{sup 2+} phosphors were discussed by analyzing the relationship between the luminescence characteristics and the crystal structure.

  17. Field comparisons of direct and component measurements of net radiation under clear skies

    SciTech Connect (OSTI)

    Duchon, C.L. [Univ. of Oklahoma, Norman, OK (United States); Wilk, G.E. [National Weather Service, Corpus Christi, TX (United States)

    1994-02-01T23:59:59.000Z

    Accurate measurements of net radiation are basic to all studies of the surface energy budget. In preparation for an energy budget experiment significant differences were found between direct and component measurement of net radiation, which prompted this investigation of their cause. The instruments involved were an all-black single-dome Fritschen-type net pyrradiometer, two Eppley model 8-48 pyranometers, and an Eppley model PIR pyrgeometer. Each had recently been calibrated. The accuracy of the component instruments was considered first. Comparisons of about one hour on each of three nights between the pyrgeometer and five empirical formulas showed that the average departure over all formulas from the pyrgeometer average was {minus}1%. Other comparisons between the pyrgeometer and an infrared thermometer viewing the surface yielded similar results. Alternate shading and unshading of the pyrgeometer looking upward during daytime resulted in a formula that was used to correct the downward longwave radiation under clear skies. The correction is dependent on wind speed, in contrast to a recent paper showing negligible dependence, but is in accord with earlier findings. Based on manufacturer`s specifications, the pyranometer calibrations were considered to be within 2% of the World Radiation Reference. Thus a series of experiments was carried out using what were believed to be reasonably accurate component measurements of net radiation and measurements from the net pyrradiometer.

  18. Filtered x-ray diode diagnostics fielded on the Z-accelerator for source power measurements

    SciTech Connect (OSTI)

    Chandler, G.A.; Deeney, C.; Cuneo, M. [and others

    1998-06-02T23:59:59.000Z

    Filtered x-ray diode, (XRD), detectors are used as primary radiation flux diagnostics on Sandia`s Z-accelerator, which generates nominally a 200 TW, 2 MJ, x-ray pulse. Given such flux levels and XRD sensitivities the detectors are being fielded 23 meters from the source. The standard diagnostic setup and sensitivities are discussed. Vitreous carbon photocathodes are being used to reduce the effect of hydrocarbon contamination present in the Z-machine vacuum system. Nevertheless pre- and post-calibration data taken indicate spectrally dependent changes in the sensitivity of these detectors by up to factors up to 2 or 3.

  19. The measurement and analysis of the magnetic field of a synchrotron light source magnet

    E-Print Network [OSTI]

    Graf, Udo Werner

    1994-01-01T23:59:59.000Z

    section of the magnet shows the symmetric distribution of the coils about the center line of the magnet. The iron yolk which surrounds the conductors is thermally insulated to enhance the efficiency of the cooling system. The entire magnet assembly... of charged particles in a 21 conductor that are exposed to an electric and a magnetic field. The force experienced by these particles is characterized by the Lorentz Equation, F=q(E+vxB) (3) The conductor used for the Hall probe has the shape of a...

  20. Development of three-wavelength CCD image pyrometer used for the temperature field measurements of continuous casting billets

    SciTech Connect (OSTI)

    Xie, Zhi; Bai, Haicheng [State Key Laboratory of Synthetical Automation for Process Industries, School of Information Science and Engineering, Northeastern University, Shenyang 110819 (China)] [State Key Laboratory of Synthetical Automation for Process Industries, School of Information Science and Engineering, Northeastern University, Shenyang 110819 (China)

    2014-02-15T23:59:59.000Z

    This paper develops an imaging based three-color pyrometer for the monitoring of temperature distribution in a continuous casting billet. A novel optical device, together with an embedded electronic system, is designed to sequentially collect a dark image and three thermal images with specified wavelengths on a same monochromatic charge-coupled-device (CCD). The three thermal images provide the basis for the determination of target temperature, while the dark image is used to online eliminate the dark noise of CCD with a differential method. This image pyrometer is not only independent of target emissivity but also overcomes the dissimilarity of measuring accuracy between the micro-sensors of CCD resulted from the non-uniformity of pixels’ intensity response and the vignetting of optical system. Furthermore, a precise two-color temperature field measuring model on the CCD pyrometer is established, based on which a self-adaptive light-integration mechanism is presented. Compared with the traditional fixed light-integration method, the measuring range of the pyrometer is greatly extended and its sensitivity in low temperature segment is improved. The test results in a steel factory demonstrate that the pyrometer is capable of meeting the requirement of surface temperature measurements about casting billets. Reliability and accuracy of measurement results are also discussed herein.

  1. Evaluation of methane emissions from Palermo municipal landfill: Comparison between field measurements and models

    SciTech Connect (OSTI)

    Di Bella, Gaetano, E-mail: dibella@idra.unipa.it [Dipartimento di Ingegneria Civile, Ambientale e Aerospaziale, Universita di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Di Trapani, Daniele, E-mail: ditrapani@idra.unipa.it [Dipartimento di Ingegneria Civile, Ambientale e Aerospaziale, Universita di Palermo, Viale delle Scienze, 90128 Palermo (Italy); Viviani, Gaspare, E-mail: gviv@idra.unipa.it [Dipartimento di Ingegneria Civile, Ambientale e Aerospaziale, Universita di Palermo, Viale delle Scienze, 90128 Palermo (Italy)

    2011-08-15T23:59:59.000Z

    Methane (CH{sub 4}) diffuse emissions from Municipal Solid Waste (MSW) landfills represent one of the most important anthropogenic sources of greenhouse gas. CH{sub 4} is produced by anaerobic biodegradation of organic matter in landfilled MSW and constitutes a major component of landfill gas (LFG). Gas recovery is a suitable method to effectively control CH{sub 4} emissions from landfill sites and the quantification of CH{sub 4} emissions represents a good tool to evaluate the effectiveness of a gas recovery system in reducing LFG emissions. In particular, LFG emissions can indirectly be evaluated from mass balance equations between LFG production, recovery and oxidation in the landfill, as well as by a direct approach based on LFG emission measurements from the landfill surface. However, up to now few direct measurements of landfill CH{sub 4} diffuse emissions have been reported in the technical literature. In the present study, both modeling and direct emission measuring methodologies have been applied to the case study of Bellolampo landfill located in Palermo, Italy. The main aim of the present study was to evaluate CH{sub 4} diffuse emissions, based on direct measurements carried out with the flux accumulation chamber (static, non-stationary) method, as well as to obtain the CH{sub 4} contoured flux map of the landfill. Such emissions were compared with the estimate achieved by means of CH{sub 4} mass balance equations. The results showed that the emissions obtained by applying the flux chamber method are in good agreement with the ones derived by the application of the mass balance equation, and that the evaluated contoured flux maps represent a reliable tool to locate areas with abnormal emissions in order to optimize the gas recovery system efficiency.

  2. Radioactivity measurements of ITER materials using TFTR D-T neutron field

    SciTech Connect (OSTI)

    Kumar, A.; Abdou, M.A. [Univ. of California, Los Angeles, CA (United States); Kugel, H.W. [Princeton Univ., NJ (United States)] [and others

    1994-12-31T23:59:59.000Z

    TFTR successfully initiated trace tritium plasma experiments in mid-November 1993. During the coming year, the TFTR plasma tritium fraction is scheduled to be increased to at least 50%. The availability of larger amounts of D-T fusion neutrons in the high power D-T plasma phase of TFTR provides an useful opportunity to directly measure D-T neutron induced radioactivity in a realistic tokamak-environment in materials of vital interest to ITER. These measurements are invaluable for characterizing short and long lived radioactivity in various ITER candidate materials, for validating complex neutron transport calculations, and for meeting fusion reactor licensing requirements. The radioactivity measurements at TFTR will involve potential ITER materials that include stainless steel 316, vanadium-alloy, copper, iron, nickel, chromium, vanadium, titanium, manganese, cobalt, molybdenum, zinc, niobium, zirconium, tungsten, lead, tin, silicon, etc. Small samples of these materials will be irradiated in varying neutron energy spectra at the vacuum vessel first wall. These irradiated samples will then be counted for {gamma}-radioactivity at different cooling times to get extensive information on as many {gamma}-emitting radioactive products as feasible.

  3. Measurements of magnetic fields over the pulsation cycle in six roAp stars with FORS1 at the VLT

    E-Print Network [OSTI]

    S. Hubrig; D. W. Kurtz; S. Bagnulo; T. Szeifert; M. Schoeller; G. Mathys; W. A. Dziembowski

    2003-09-21T23:59:59.000Z

    With FORS1 at the VLT we have tried for the first time to measure the magnetic field variation over the pulsation cycle in six roAp stars to begin the study of how the magnetic field and pulsation interact. For the star HD101065, which has one of the highest photometric pulsation amplitudes of any roAp star, we found a signal at the known photometric pulsation frequency at the 3 sigma level in one data set; however this could not be confirmed by later observations. A preliminary simple calculation of the expected magnetic variations over the pulsation cycle suggests that they are of the same order as our current noise levels, leading us to expect that further observations with increased S/N have a good chance of achieving an unequivocal detection.

  4. Method Evaluation And Field Sample Measurements For The Rate Of Movement Of The Oxidation Front In Saltstone

    SciTech Connect (OSTI)

    Almond, P. M. [Savannah River Site (SRS), Aiken, SC (United States); Kaplan, D. I. [Savannah River Site (SRS), Aiken, SC (United States); Langton, C. A. [Savannah River Site (SRS), Aiken, SC (United States); Stefanko, D. B. [Savannah River Site (SRS), Aiken, SC (United States); Spencer, W. A. [Savannah River Site (SRS), Aiken, SC (United States); Hatfield, A. [Clemson University, Clemson, SC (United States); Arai, Y. [Clemson University, Clemson, SC (United States)

    2012-08-23T23:59:59.000Z

    The objective of this work was to develop and evaluate a series of methods and validate their capability to measure differences in oxidized versus reduced saltstone. Validated methods were then applied to samples cured under field conditions to simulate Performance Assessment (PA) needs for the Saltstone Disposal Facility (SDF). Four analytical approaches were evaluated using laboratory-cured saltstone samples. These methods were X-ray absorption spectroscopy (XAS), diffuse reflectance spectroscopy (DRS), chemical redox indicators, and thin-section leaching methods. XAS and thin-section leaching methods were validated as viable methods for studying oxidation movement in saltstone. Each method used samples that were spiked with chromium (Cr) as a tracer for oxidation of the saltstone. The two methods were subsequently applied to field-cured samples containing chromium to characterize the oxidation state of chromium as a function of distance from the exposed air/cementitious material surface.

  5. Cloning Hubble Deep Fields I: A Model-Independent Measurement of Galaxy Evolution

    E-Print Network [OSTI]

    Rychard J. Bouwens; Tom Broadhurst; Joseph Silk

    1998-10-29T23:59:59.000Z

    We present a model-independent method of quantifying galaxy evolution in high-resolution images, which we apply to the Hubble Deep Field (HDF). Our procedure is to k-correct all pixels belonging to the images of a complete set of bright galaxies and then to replicate each galaxy image to higher redshift by the product of its space density, 1/V_{max}, and the cosmological volume. The set of bright galaxies is itself selected from the HDF, because presently the HDF provides the highest quality UV images of a redshift-complete sample of galaxies (31 galaxies with I24) are much smaller, more numerous, and less regular than our ``no-evolution'' extrapolation, for any interesting geometry. A higher proportion of HDF galaxies ``dropout'' in both U and B, indicating that some galaxies were brighter at higher redshifts than our ``cloned'' z\\sim0.5 population.

  6. Harmonic propagation on an electric distribution system: Field measurements compared with computer simulation

    SciTech Connect (OSTI)

    Williams, S.M. (Naval Postgraduate School, Monterey, CA (United States)); Brownfield, G.T. (Union Electric Co., St. Louis, MO (United States)); Duffus, J.W. (Univ. of Missouri, Columbia, MO (United States). Power Electronics Research Center)

    1993-04-01T23:59:59.000Z

    Power electronic loads are occupying an increasing fraction of the total load on distribution feeders. Coincidentally, there is a greater use of power factor correction capacitors on the distribution system. These two factors can present poor operating conditions in the form of high harmonic levels propagating through a distribution system. Electric utility engineers are facing an ever increasing number of situations which require the analysis of the propagation of harmonics on a distribution system. HARMFLO was developed by EPRI for use in the analysis of harmonics on a power system. However, for a typical analysis of a distribution system, data for some of the parameters required by HARMFLO are not available. Furthermore, exact load information is usually not available. Harmonic levels determined from field tests on a distribution system are compared to results of HARMFLO simulations to determine if this analysis tool can be expected to provide useful results despite the lack of exact information for load modeling and other system parameters.

  7. ARM - Field Campaign - ARM Airborne Carbon Measurements (ARM-ACME V)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy, science,SpeedingWu,IntelligenceYouQualityAirborne Carbon Measurements

  8. Cropland Field Monitoring: MMV Page 1 Montana Cropland Enrolled Farm Fields Carbon Sequestration Field Sampling, Measurement, Monitoring, and Verification: Application of Visible-Near Infrared Diffuse Reflectance Spectroscopy (VNIR) and Laser-induced Breakdown Spectroscopy (LIBS)

    SciTech Connect (OSTI)

    Lee Spangler; Ross Bricklemyer; David Brown

    2012-03-15T23:59:59.000Z

    There is growing need for rapid, accurate, and inexpensive methods to measure, and verify soil organic carbon (SOC) change for national greenhouse gas accounting and the development of a soil carbon trading market. Laboratory based soil characterization typically requires significant soil processing, which is time and resource intensive. This severely limits application for large-region soil characterization. Thus, development of rapid and accurate methods for characterizing soils are needed to map soil properties for precision agriculture applications, improve regional and global soil carbon (C) stock and flux estimates and efficiently map sub-surface metal contamination, among others. The greatest gains for efficient soil characterization will come from collecting soil data in situ, thus minimizing soil sample transportation, processing, and lab-based measurement costs. Visible and near-infrared diffuse reflectance spectroscopy (VisNIR) and laser-induced breakdown spectroscopy (LIBS) are two complementary, yet fundamentally different spectroscopic techniques that have the potential to meet this need. These sensors have the potential to be mounted on a soil penetrometer and deployed for rapid soil profile characterization at field and landscape scales. Details of sensor interaction, efficient data management, and appropriate statistical analysis techniques for model calibrations are first needed. In situ or on-the-go VisNIR spectroscopy has been proposed as a rapid and inexpensive tool for intensively mapping soil texture and organic carbon (SOC). While lab-based VisNIR has been established as a viable technique for estimating various soil properties, few experiments have compared the predictive accuracy of on-the-go and lab-based VisNIR. Eight north central Montana wheat fields were intensively interrogated using on-the-go and lab-based VisNIR. Lab-based spectral data consistently provided more accurate predictions than on-the-go data. However, neither in situ nor lab-based spectroscopy yielded even semi-quantitative SOC predictions. There was little SOC variability to explain across the eight fields, and on-the-go VisNIR was not able to capture the subtle SOC variability in these Montana soils. With more variation in soil clay content compared to SOC, both lab and on-the-go VisNIR showed better explanatory power. There are several potential explanations for poor on-the-go predictive accuracy: soil heterogeneity, field moisture, consistent sample presentation, and a difference between the spatial support of on-the-go measurements and soil samples collected for laboratory analyses. Though the current configuration of a commercially available on-the-go VisNIR system allows for rapid field scanning, on-the-go soil processing (i.e. drying, crushing, and sieving) could improve soil carbon predictions. Laser-induced breakdown spectroscopy (LIBS) is an emerging elemental analysis technology with the potential to provide rapid, accurate and precise analysis of soil constituents, such as carbon, in situ across landscapes. The research team evaluated the accuracy of LIBS for measuring soil profile carbon in field-moist, intact soil cores simulating conditions that might be encountered by a probe-mounted LIBS instrument measuring soil profile carbon in situ. Over the course of three experiments, more than120 intact soil cores from eight north central Montana wheat fields and the Washington State University (WSU) Cook Agronomy Farm near Pullman, WA were interrogated with LIBS for rapid total carbon (TC), inorganic carbon (IC), and SOC determination. Partial least squares regression models were derived and independently validated at field- and regional scales. Researchers obtained the best LIBS validation predictions for IC followed by TC and SOC. Laser-induced breakdown spectroscopy is fundamentally an elemental analysis technique, yet LIBS PLS2 models appeared to discriminate IC from TC. Regression coefficients from initial models suggested a reliance upon stoichiometric relationships between carbon (247.8 nm) and other elements

  9. Free radially expanding liquid sheet in air: time- and space-resolved measurement of the thickness field

    E-Print Network [OSTI]

    Clara Vernay; Laurence Ramos; Christian Ligoure

    2014-12-12T23:59:59.000Z

    The collision of a liquid drop against a small target results in the formation of a thin liquid sheet that extends radially until it reaches a maximum diameter. The subsequent retraction is due to the air-liquid surface tension. We have used a time- and space-resolved technique to measure the thickness field of this class of liquid sheet, based on the grey level measurement of the image of a dyed liquid sheet recorded using a fast camera. This method enables a precise measurement of the thickness in the range $(10-450) \\, \\mathrm{\\mu m}$, with a temporal resolution equal to that of the camera. We have measured the evolution with time since impact, $t$, and radial position, $r$, of the thickness, $h(r,t)$, for various drop volumes and impact velocities. Two asymptotic regimes for the expansion of the sheet are evidenced. The scalings of the thickness with $t$ and $r$ measured in the two regimes are those that were predicted in \\citet{Rozhkov2004} fort the short-time regime and \\citet{Villermaux2011} for the long time regime, but never experimentally measured before. Interestingly, our experimental data also evidence the existence of a maximum of the film thickness $h_{\\rm{max}}(r)$ at a radial position $r_{\\rm{h_{max}}}(t)$ corresponding to the crossover of these two asymptotic regimes. The maximum moves with a constant velocity of the order of the drop impact velocity, as expected theoretically. Thanks to our visualization technique, we also evidence an azimuthal thickness modulation of the liquid sheets.

  10. Measurement of routinely encountered neutron field doses using portable survey instruments and a Bonner multisphere system

    E-Print Network [OSTI]

    Davis, Donald Reed

    1981-01-01T23:59:59.000Z

    Ludlum Model 15 NSC-A NSC-8 NSC-C NSC-D NSC-E NSC-F NSC-G NSC-H NSC-I NSC-J NSC-K NSC-L NSC-M 30. 19 mRem/hr 4. 38 2. 70 1. 54 4. 08 4. 31 5. 42 10. 91 4. 19 0. 48 0. 46 3. 64 0. 50 1000 mRem/hr 90 58 36 140 125 90 32 25... 20 17 70 10 950 mRem/hr 120 40 32 160 135 80 45 28 16 11 86 8 2 CYC-A CYC-8 CYC-C CYC-D CYC-E CYC-F 31 . 11 25. 23 3. 19 1. 95 1. 02 1. 96 1000 190 75 32 14 20 1550 176 72 23 15 24 denotes measurement made...

  11. Polyelectrolytes in electric fields: Measuring the dynamical effective charge and effective friction

    E-Print Network [OSTI]

    Kai Grass; Christian Holm

    2008-12-13T23:59:59.000Z

    We use a coarse-grained molecular dynamics model to study the electrophoretic behaviour of flexible polyelectrolyte chains. We first characterize the static properties of the model with respect to the chain length, the polyelectrolyte concentration, additional salt and the influence of an applied external field. Next we investigate the dynamic behaviour in the oligomer range and compare to data obtained by two different experimental methods, namely capillary electrophoresis and PFG-NMR. We find excellent agreement of experiments and simulations when hydrodynamic interactions are accounted for in the simulations. We then present novel estimators for the dynamical effective charge during free solution electrophoresis and compare them to static estimators. We find complete agreement between the static and the dynamic estimators. We further evaluate the scaling behaviour of the effective friction of the polyelectrolyte-counterion complex with the surrounding fluid. We identify a hydrodynamic screening length beyond which the friction during electrophoresis is linear depending on the chain length resulting in a constant mobility for long polyelectrolyte chains. Our results show a convincing agreement with experimental data and demonstrate that it is possible to model dynamic behaviour of polyelectrolytes using coarse grained models, provided they include the effects of hydrodynamical interactions.

  12. Cloning Hubble Deep Fields: A Model-Independent Measurement of Galaxy Evolution

    E-Print Network [OSTI]

    Rychard J. Bouwens; Tom Broadhurst; Joseph Silk

    1998-10-26T23:59:59.000Z

    We present a model-independent method of quantifying galaxy evolution in high- resolution images, which we apply to the Hubble Deep Field (HDF). Our procedure is to k-correct the pixels belonging to the images of a complete set of bright galaxies and then to replicate each galaxy image to higher redshift by the product of its space density, 1/V_{max}, and the cosmological volume. The set of bright galaxies is itself selected from the HDF because presently the HDF provides the highest quality UV images of a redshift-complete sample of galaxies (31 galaxies with I24) are much smaller, more numerous, and less regular than our ``no-evolution'' extrapolation, for any relevant geometry. A higher proportion of HDF galaxies ``dropout'' in both U and B, indicating that some galaxies were brighter at higher redshifts than our ``cloned'' z\\sim0.5 population. By simple image transformations we demonstrate that bolometric luminosity evolution generates galaxies which are too large and the contribution of any evolving dwarf population is uninterestingly small. A plausible fit is provided by `mass-conserving' density-evolution, consistent with hierarchical growth of small-scale structure. Finally, we show the potential for improvement using the Advanced Camera, with its superior UV and optical performance.

  13. 2011 Alkaline Membrane Fuel Cell Workshop Final Report

    SciTech Connect (OSTI)

    Pivovar, B.

    2012-02-01T23:59:59.000Z

    A workshop addressing the current state-of-the-art in alkaline membrane fuel cells (AMFCs) was held May 8-9, 2011, at the Crystal Gateway Marriott in Arlington, Virginia. This workshop was the second of its kind, with the first being held December 11-13, 2006, in Phoenix, Arizona. The 2011 workshop and associated workshop report were created to assess the current state of AMFC technology (taking into account recent advances), investigate the performance potential of AMFC systems across all possible power ranges and applications, and identify the key research needs for commercial competitiveness in a variety of areas.

  14. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-04-29T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the previous semi-annual technical progress report (April 1, 2001 through September 30, 2001). During the current reporting period, additional balance of plant impact information was determined for one of the two tests. These additional balance-of-plant results are presented and discussed in this report. There was no other technical progress to report, because all planned testing as part of this project has been completed.

  15. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2001-11-06T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

  16. 2006 Alkaline Membrane Fuel Cell Workshop Final Report | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of BadTHE U.S. DEPARTMENT OFDecember 18,United4Energy 06 Alkaline

  17. Alkaline Membrane Fuel Cell Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platform is alwaysISOSource Heat Pump BasicsAlexander DaneDirector,Alkaline

  18. Breast Imaging Reporting and Data System (BI-RADS) breast composition descriptors: Automated measurement development for full field digital mammography

    SciTech Connect (OSTI)

    Fowler, E. E.; Sellers, T. A.; Lu, B. [Department of Cancer Epidemiology, Division of Population Sciences, H. Lee Moffitt Cancer Center, Tampa, Florida 33612 (United States)] [Department of Cancer Epidemiology, Division of Population Sciences, H. Lee Moffitt Cancer Center, Tampa, Florida 33612 (United States); Heine, J. J. [Department of Cancer Imaging and Metabolism, H. Lee Moffitt Cancer Center, Tampa, Florida 33612 (United States)] [Department of Cancer Imaging and Metabolism, H. Lee Moffitt Cancer Center, Tampa, Florida 33612 (United States)

    2013-11-15T23:59:59.000Z

    Purpose: The Breast Imaging Reporting and Data System (BI-RADS) breast composition descriptors are used for standardized mammographic reporting and are assessed visually. This reporting is clinically relevant because breast composition can impact mammographic sensitivity and is a breast cancer risk factor. New techniques are presented and evaluated for generating automated BI-RADS breast composition descriptors using both raw and calibrated full field digital mammography (FFDM) image data.Methods: A matched case-control dataset with FFDM images was used to develop three automated measures for the BI-RADS breast composition descriptors. Histograms of each calibrated mammogram in the percent glandular (pg) representation were processed to create the new BR{sub pg} measure. Two previously validated measures of breast density derived from calibrated and raw mammograms were converted to the new BR{sub vc} and BR{sub vr} measures, respectively. These three measures were compared with the radiologist-reported BI-RADS compositions assessments from the patient records. The authors used two optimization strategies with differential evolution to create these measures: method-1 used breast cancer status; and method-2 matched the reported BI-RADS descriptors. Weighted kappa (?) analysis was used to assess the agreement between the new measures and the reported measures. Each measure's association with breast cancer was evaluated with odds ratios (ORs) adjusted for body mass index, breast area, and menopausal status. ORs were estimated as per unit increase with 95% confidence intervals.Results: The three BI-RADS measures generated by method-1 had ? between 0.25–0.34. These measures were significantly associated with breast cancer status in the adjusted models: (a) OR = 1.87 (1.34, 2.59) for BR{sub pg}; (b) OR = 1.93 (1.36, 2.74) for BR{sub vc}; and (c) OR = 1.37 (1.05, 1.80) for BR{sub vr}. The measures generated by method-2 had ? between 0.42–0.45. Two of these measures were significantly associated with breast cancer status in the adjusted models: (a) OR = 1.95 (1.24, 3.09) for BR{sub pg}; (b) OR = 1.42 (0.87, 2.32) for BR{sub vc}; and (c) OR = 2.13 (1.22, 3.72) for BR{sub vr}. The radiologist-reported measures from the patient records showed a similar association, OR = 1.49 (0.99, 2.24), although only borderline statistically significant.Conclusions: A general framework was developed and validated for converting calibrated mammograms and continuous measures of breast density to fully automated approximations for the BI-RADS breast composition descriptors. The techniques are general and suitable for a broad range of clinical and research applications.

  19. alkaline-earth metal oxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Berkeley. FOM Institute for Plasma Physics Cohen, Ronald C. 2 Liquid metal batteries : ambipolar electrolysis and alkaline earth electroalloying cells MIT - DSpace...

  20. Hit from both sides: tracking industrial and volcanic plumes in Mexico City with surface measurements and OMI SO2 retrievals during the MILAGRO field campaign

    E-Print Network [OSTI]

    de Foy, B.

    Large sulfur dioxide plumes were measured in the Mexico City Metropolitan Area (MCMA) during the MILAGRO field campaign. This paper seeks to identify the sources of these plumes and the meteorological processes that affect ...

  1. An evaluation of the Gilian TRACEAIR Organic Vapor Monitoring Diffusive Badge in measuring short-term exposure levels of benzene under field conditions 

    E-Print Network [OSTI]

    Pierce, Mark Edward

    1996-01-01T23:59:59.000Z

    The objective of this research is to evaluate the performance of the Gilian TRACEAIR Organic Vapor Monitoring I (OVMI) Diffusive Badge in measuring short-term benzene exposures under field conditions. In general, a diffusive badge is a device which...

  2. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01T23:59:59.000Z

    This document summarizes progress on the Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2000 through September 30, 2000. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid will also be determined, as will the removal of arsenic, a known poison for NOX selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), First Energy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the second reporting period for the subject Cooperative Agreement. During this period, the first of four short-term sorbent injection tests were conducted at the First Energy Bruce Mansfield Plant. This test determined the effectiveness of dolomite injection through out-of-service burners as a means of controlling sulfuric acid emissions from this unit. The tests showed that dolomite injection could achieve up to 95% sulfuric acid removal. Balance of plant impacts on furnace slagging and fouling, air heater fouling, ash loss-on-ignition, and the flue gas desulfurization system were also determined. These results are presented and discussed in this report.

  3. Influence of Alkaline Co-Contaminants on Technetium Mobility in Vadose Zone Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; Jansik, Danielle P.; McKinley, James P.; Hess, Nancy J.

    2014-09-01T23:59:59.000Z

    Pertechnetate was slowly reduced in a natural, untreated arid sediment under anaerobic conditions (0.02 nmol g-1 h-1), which could occur in low permeability zones in the field, most of which was quickly oxidized. A small portion of the surface Tc may be incorporated into slowly dissolving surface phases, so was not readily oxidized/remobilized into pore water. In contrast, pertechnetate reduction in an anaerobic sediment containing adsorbed ferrous iron as the reductant was rapid (15 to 600 nmol g-1 h-1), and nearly all (96 - 98%) was rapidly oxidized/remobilized (2.6 to 6.8 nmol g-1 h-1) within hours. Tc reduction in an anaerobic sediment containing 0.5 to 10 mM sulfide showed a relatively slow reduction rate (0.01 to 0.03 nmol g-1 h-1) that was similar to observations in the natural sediment. Pertechnetate infiltration into sediment with a highly alkaline water resulted in rapid reduction (0.07 to 0.2 nmol g-1 h-1) from ferrous iron released during biotite or magnetite dissolution. Oxidation of NaOH-treated sediments resulted in slow Tc oxidation (~0.05 nmol g-1 h-1) of a small fraction of the surface Tc (13% to 23%). The Tc remaining on the surface was TcIV (by XANES), and autoradiography and elemental maps of Tc (by electron microprobe) showed Tc was present associated with specific minerals, rather than being evenly distributed on the surface. Dissolution of quartz, montmorillonite, muscovite, and kaolinite also occurred in the alkaline water, resulting in significant aqueous silica and aluminum. Over time, aluminosilicates cancrinite, zeolite and sodalite were precipitating. These precipitates may be coating surface Tc(IV) phases, limiting reoxidation.

  4. FIELD EVALUATION OF IMPROVED METHODS FOR MEASURING THE AIR LEAKAGE OF DUCT SYSTEMS UNDER NORMAL OPERATING CONDITIONS IN 51 HOMES

    SciTech Connect (OSTI)

    Paul W. Francisco; Larry Palmiter; Erin Kruse; Bob Davis

    2003-10-18T23:59:59.000Z

    Duct leakage in forced-air distribution systems has been recognized for years as a major source of energy losses in residential buildings. Unfortunately, the distribution of leakage across homes is far from uniform, and measuring duct leakage under normal operating conditions has proven to be difficult. Recently, two new methods for estimating duct leakage at normal operating conditions have been devised. These are called the nulling test and the Delta-Q test. Small exploratory studies have been done to evaluate these tests, but previously no large-scale study on a broad variety of homes has been performed to determine the accuracy of these new methods in the field against an independent benchmark of leakage. This sort of study is important because it is difficult in a laboratory setting to replicate the range of leakage types found in real homes. This report presents the results of a study on 51 homes to evaluate these new methods relative to an independent benchmark and a method that is currently used. An evaluation of the benchmark procedure found that it worked very well for supply-side leakage measurements, but not as well on the return side. The nulling test was found to perform well, as long as wind effects were minimal. Unfortunately, the time and difficulty of setup can be prohibitive, and it is likely that this method will not be practical for general use by contractors except in homes with no return ducts. The Delta-Q test was found to have a bias resulting in overprediction of the leakage, which qualitatively confirms the results of previous laboratory, simulation, and small-scale field studies. On average the bias was only a few percent of the air handler flow, but in about 20% of the homes the bias was large. A primary flaw with the Delta-Q test is the assumption that the pressure between the ducts and the house remain constant during the test, as this assumption does not hold true. Various modifications to the Delta-Q method were evaluated as possible improvements. Only one of these modifications provided improved results. This modification requires measuring the duct pressure relative to the house at either every pressure station within the Delta-Q test or at the extremes of the house pressure range involved in the Delta-Q test. If the pressures are only measured at the extremes, then calculated pressures at the other pressure stations are obtained via interpolation. Using these pressures reduced the bias in the Delta-Q test by about one-third.

  5. Detecting internal corrosion of natural gas transmission pipelines: field tests of probes and systems for real-time corrosion measurement

    SciTech Connect (OSTI)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Kane, R.D. (InterCorr International); Meidinger, B. (Rocky Mountain Oilfield Testing Center)

    2005-01-01T23:59:59.000Z

    A field study was conducted to evaluate the use of automated, multi-technique electrochemical corrosion-rate monitoring devices and probes for detecting corrosion in environments similar to those found in natural gas transmission pipelines. It involved measurement of real-time corrosion signals from operating pipelines. Results and interpretation were reported from four different field test locations. Standard flush-mount and custom flange probes were used in four different environments at a gas-gathering site and one environment but two different probe orientations at a natural gas site. These sites were selected to represent normal and upset conditions common in gas transmission pipelines. The environments consisted of two different levels of humidified natural gas, liquid hydrocarbon, and water from natural gas. Probe locations included the 6 and 12 o?clock positions of a natural gas pipeline carrying 2-phase gas/liquid flow. The probe data was monitored using completely remote solar powered systems that provided real-time data transmission via wireless back to a pipeline control station. Data are also presented comparing the ECR probe data to that for coupons used to determine corrosion rate and to detect the presence of microbiologically influenced corrosion (MIC).

  6. Surfactant-enhanced alkaline flooding for light oil recovery. [Quarterly] report, March 31--June 30, 1993

    SciTech Connect (OSTI)

    Wasan, D.T.

    1993-09-01T23:59:59.000Z

    The overall objective of this project is to develop a very cost- effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultra-low tension. In addition, the novel concept of pH gradient design to optimize flood water conditions will be tested. Last quarter we have investigated the mechanisms responsible for spontaneous emulsification in alkali/acidic crude oil systems with and without added surfactant. We have observed that the roll cell size and formation time depend strongly on the pH and ionic strength of the alkaline solution. For a particular roll cell size, the addition of surfactant causes the cells to take longer to form, causing an interfacial resistance to mass transfer and making the interface more rigid. We have shown that interfacial turbulence is a necessary but not sufficient condition for spontaneous emulsification. Low interfacial tension is also a necessary condition. This quarter a microwave interferometric procedure was developed for the determination of low water content (0. 5 to 10 vol%) of water-in-oil macroemulsions. The apparatus operates at a frequency of 23.48 GHz in the K-band microwave region. The procedure is based on the large differences in dielectric properties between water and oil, and it utilizes the variation in phase shift as sample path length is varied. Measurements are accurate to within 0.5 vol% water.

  7. Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly(diallyldimethylammonium chloride)s

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly to be used in a Solid Alkaline Fuel Cell (SAFC) needs to (i) be insoluble in both aqueous solutions,10% > 320 °C). When used in a fuel cell as a binder in the membrane-electrodes assembly (MEA

  8. Mineral replacement rate of olivine by chrysotile and brucite under high alkaline conditions

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Mineral replacement rate of olivine by chrysotile and brucite under high alkaline conditions Romain Available online 8 March 2012 Keywords: A1. Mineral replacement rate A1. Serpentinization A1. TG analyses B1. Alkaline medium B2. Chrysotile nanotubes a b s t r a c t Olivine mineral replacement by serpentine is one

  9. Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell

    E-Print Network [OSTI]

    Zhao, Tianshou

    Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell S and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China a r t i c l e i n f o Article history: Received 26 carbon supported PtRh catalysts and compare their catalytic activities with that of Pt/C in alkaline

  10. alkaline-earth metals pt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline-earth metals pt First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effects of Alkaline Earth...

  11. Alkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a

    E-Print Network [OSTI]

    optimization is needed for the commercialization of alkaline membrane fuel cell (AMFC) technologiesAlkaline membrane fuel cells with in-situ cross-linked ionomers Yongjun Leng a , Lizhu Wang b membrane fuel cell (AMFC) in-situ cross-linking ionomer net water transport coefficient A B S T R A C

  12. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-10-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the report for the time period April 1, 2002 through September 30, 2002. During the current period, process economic estimates were developed, comparing the costs of the furnace magnesium hydroxide slurry injection process tested as part of this project to a number of other candidate SO{sub 3}/sulfuric acid control technologies for coal-fired power plants. The results of this economic evaluation are included in this progress report.

  13. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-06-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2002 through March 31, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the seventh reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO3 removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the previous report (April 1, 2002 through September 30, 2002). During the current period, there was no technical progress to report, because all planned testing as part of this project has been completed. The project period of performance was extended to allow the conduct of testing of another SO{sub 3} control technology, the sodium bisulfite injection process. However, these additional tests have not yet been conducted.

  14. Coupling field and laboratory measurements to estimate the emission factors of identified and unidentified trace gases for prescribed fires

    SciTech Connect (OSTI)

    Yokelson, Robert J.; Burling, Ian R.; Gilman, Jessica; Warneke, Carsten; Stockwell, Chelsea E.; de Gouw, Joost A.; Akagi, Sheryl; Urbanski, Shawn; Veres, Patrick; Roberts, James M.; Kuster, W. C.; Reardon, James; Griffith, David WT; Johnson, Timothy J.; Hosseini, SeyedEhsan; Miller, J. Wayne; Cocker, David R.; Jung, H.; Weise, David

    2013-01-07T23:59:59.000Z

    Vegetative fuels commonly consumed in prescribed fires were collected from five locations in the southeastern and southwestern U.S. and burned in a series of 77 fires at the U.S. Forest Service Fire Sciences Laboratory in Missoula, Montana. The particulate matter (PM2.5) emissions were measured by gravimetric filter sampling with subsequent analysis for elemental carbon (EC), organic carbon (OC), and 38 elements. The trace gas emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared (OP FTIR) spectrometer, proton-transfer-reaction mass spectrometry (PTR-MS), proton-transfer ion-trap mass spectrometry (PIT-MS), negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS), and gas chromatography with MS detection (GC-MS). 204 trace gas species (mostly non-methane organic compounds (NMOC)) were identified and quantified with the above instruments. An additional 152 significant peaks in the unit mass resolution mass spectra were quantified, but either could not be identified or most of the signal at that molecular mass was unaccounted for by identifiable species. As phase II of this study, we conducted airborne and ground-based sampling of the emissions from real prescribed fires mostly in the same land management units where the fuels for the lab fires were collected. A broad variety, but smaller number of species (21 trace gas species and PM2.5) was measured on 14 fires in chaparral and oak savanna in the southwestern US, as well as pine forest understory in the southeastern US and Sierra Nevada mountains of California. These extensive field measurements of emission factors (EF) for temperate biomass burning are useful both for modeling and to examine the representativeness of our lab fire EF. The lab/field EF ratio for the pine understory fuels was not statistically different from one, on average. However, our lab EF for “smoldering compounds” emitted by burning the semi-arid SW fuels should likely be increased by about a factor of 2.7 to better represent field fires. Based on the lab/field comparison, we present a table with emission factors for 365 pyrogenic species (including unidentified species) for 4 broad fuel types: pine understory, semi-arid shrublands, evergreen canopy, and duff. To our knowledge this is the most complete measurement of biomass burning emissions to date and it should enable improved representation of smoke in atmospheric models. The results provide important insights into the nature of smoke. For example, ~35% (range from 16-71%) of the mass of gas-phase NMOC species was attributed to the species that we could not identify. These unidentified species are likely not represented in most models, but some provision should be made for the fact that they will react in the atmosphere. In addition, the total mass of gas-phase NMOC divided by the mass of co-emitted PM2.5 averaged ~2.6 for the main fire types with a range from ~1.8-8.8. About 36-63% of the NMOC were likely semivolatile or of intermediate volatility. Thus, the gas-phase NMOC represent a large reservoir of potential precursors for secondary formation of organic aerosol. For the one fire in organic soil (Alaskan duff) about 28% of the emitted carbon was present as gas-phase NMOC in contrast to the other fuels for which NMOC accounted for only ~1-3% of emitted carbon. 71% of the mass of NMOC emitted by the smoldering duff was un-identified. The duff results highlight the need to learn more about the emissions from smoldering organic soils. The ?NMOC/“NOx-as-NO” ratio was consistently about ten for the main fire types when accounting for all NMOC, indicating strongly NOx-limited O3 production conditions. Finally, the fuel consumption per unit area was measured on 6 of the 14 prescribed fires and averaged 7.08 ± 2.09 (1?) Mg ha-1.

  15. Measurement Measurement

    E-Print Network [OSTI]

    Type Measurement Type Measurement Type Measurement Type Measurement Catch Composition - Pelagic codes M Male F Female I Indeterminate U Unknown (not inspected) #12;Type Measurement Type Measurement Type Measurement Type Measurement Photos Comment Length 1 Version 1.2 6/2011 HookNo. Species name

  16. Development of alkaline solution separations for potential partitioning of used nuclear fuels

    SciTech Connect (OSTI)

    Jarvinen, Gordon D [Los Alamos National Laboratory; Runde, Wolfgang H [Los Alamos National Laboratory; Goff, George S [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    The processing of used nuclear fuel in alkaline solution provides potentially useful new selectivity for separating the actinides from each other and f rom the fission products. Over the ast decade, several research teams around the world have considered dissolution of used fuel in alkaline solution and further partitioning in this medium as an alternative to acid dissolution. The chemistry of the actinides and fission products in alkaline soilltion requires extensive investigation to more carefully evaluate its potential for developing useful separation methods for used nuclear fueI.

  17. Geochemical evolution of highly alkaline and saline tank wasteplumes during seepage through vadose zone sediments

    SciTech Connect (OSTI)

    Wan, Jiamin; Tokunaga, Tetsu K.; Larsen, Joern T.; Serne, R. Jeff

    2002-12-01T23:59:59.000Z

    Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m )maintained at 70 C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH- neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH>10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past.

  18. Geochemical evolution of highly alkaline and saline tank waste plumes during seepage through vadose zone sediments

    SciTech Connect (OSTI)

    Wan, Jiamin; Tokunaga, Tetsu K.; Larsen, Joern T.; Serne, R JEFFREY.

    2004-02-01T23:59:59.000Z

    Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m) maintained at 70C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH > 10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past.

  19. Measurements of OH and HO2 concentrations during the MCMA-2006 field campaign - Part 2: Model comparison and radical budget

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    ppb Methanol, ethanol, acetonitrile, ethylacetate MeasuredMethanol, ethanol, acetonitrile, acetaldehyde Benzene, C3-

  20. Decomposition Studies of Triphenylboron, Diphenylborinic Acid and Phenylboric Acid in Aqueous Alkaline Solutions Containing Copper

    SciTech Connect (OSTI)

    Crawford, C.L. [Westinghouse Savannah River Company, AIKEN, SC (United States); Peterson, R. A.

    1997-02-11T23:59:59.000Z

    This report documents the copper-catalyzed chemical kinetics of triphenylboron, diphenylborinic acid and phenylboric acid (3PB, 2PB and PBA) in aqueous alkaline solution contained in carbon-steel vessels between 40 and 70 degrees C.

  1. Pore water chemistry of an alkaline rift valley lake: Lake Turkana, Kenya

    SciTech Connect (OSTI)

    Cerling, T.E.; Johnson, T.C.; Halfman, J.D.; Lister, G.

    1985-01-01T23:59:59.000Z

    Lake Turkana is the largest closed basin lake in the African rift system. It has evolved through the past 5000 years to become a moderately alkaline lake. Previous mass balance argument suggest that sulfate is removed from the lake by sulfate reduction in the sediments, and that the lake is accumulating in chloride, sodium, and alkalinity. Studies of pore water from 12 meter cores collected in November 1984 show that sulfate is reduced in the sediment column with a net production of alkalinity. Some sodium is lost from the lake and diffuses into the sediment to maintain charge balance. At several meters depth, organic matter is destroyed by methanogenic bacteria, as shown by the high delta /sup 13/C values for dissolved inorganic carbon. Magnesium and calcium molar ratios change with depth; chloride, sodium, and alkalinity also change with depth.

  2. Hot alkaline treatment to stimulate and consolidate the heavy oil Bachaquero-01 sand

    E-Print Network [OSTI]

    Valera Villarroel, Cesar Amabilis

    2005-02-17T23:59:59.000Z

    An experimental study was conducted to verify experimentally whether sand consolidation by high-temperature alkaline treatment was possible in the heavy oil Bachaquero-01 reservoir. The experiments were conducted using sand samples from a core taken...

  3. A NEW CONCEPT IN AN ELECTRICALLY RECHARGEABLE ZINC-AIR ALKALINE BATTERY

    E-Print Network [OSTI]

    Ross, P.N.

    2010-01-01T23:59:59.000Z

    Study of a New Zinc-Air Battery Concept Using Flowingdiagram of the zinc-air battery single cell prototype usedRECHARGEABLE ZINC-AIR ALKALINE BATTERY Philip N. Ross

  4. Class of 2003 Alumni Compass Project: GOAL 120 compasses = $4,800 Every Warnell student will need a compass for field measurements. Not only will a compass

    E-Print Network [OSTI]

    Teskey, Robert O.

    Class of 2003 Alumni Compass Project: GOAL 120 compasses = $4,800 Every Warnell student will need a compass for field measurements. Not only will a compass literally help each student find their way, a note would like to give a new student a compass when he or she enters the professional program, we would love

  5. Bachelor thesis: "Validation of an engineering model of the near wake wind field of wind turbines based on nacelle based lidar measurements"

    E-Print Network [OSTI]

    Peinke, Joachim

    , in an early stage of wind farm layout optimisation and wind turbine loading calculation in wind farms by Ainslie[1], This is widely used in the industry for wind farming purposes. Scope During this project analysis are performed of near wake measurements of a 5 MW wind turbine at the offshore test field alpha

  6. Unravelling the origin of large-scale magnetic fields in galaxy clusters and beyond through Faraday Rotation Measures with the SKA

    E-Print Network [OSTI]

    Bonafede, A; Brüggen, M; Akahori, T; Carretti, E; Colafrancesco, S; Feretti, L; Ferrari, C; Giovannini, G; Govoni, F; Johnston-Hollitt, M; Murgia, M; Rudnick, L; Scaife, A; Vacca, V

    2015-01-01T23:59:59.000Z

    We investigate the possibility for the SKA to detect and study the magnetic fields in galaxy clusters and in the less dense environments surrounding them using Faraday Rotation Measures. To this end, we produce 3-dimensional magnetic field models for galaxy clusters of different masses and in different stages of their evolution, and derive mock rotation measure observations of background radiogalaxies. According to our results, already in phase I, we will be able to infer the magnetic field properties in galaxy clusters as a function of the cluster mass, down to $10^{13}$ solar-masses. Moreover, using cosmological simulations to model the gas density, we have computed the expected rotation measure through shock-fronts that occur in the intra-cluster medium during cluster mergers. The enhancement in the rotation measure due to the density jump will permit to constraint the magnetic field strength and structure after the shock passage. SKA observations of polarised sources located behind galaxy clusters will an...

  7. Interactions of Silicate Ions with Zinc(II) and Aluminum(III) in Alkaline Aqueous Solution

    E-Print Network [OSTI]

    Sahai, Nita

    Interactions of Silicate Ions with Zinc(II) and Aluminum(III) in Alkaline Aqueous Solution Michel R 16, 2005 We present 29 Si, 27 Al, and 67 Zn NMR evidence to show that silicate ions in alkaline, with aluminate (Al(OH)4 - ). Zincate reacts with monomeric silicate at pH 14-15 to form [(HO)O2Si-O-Zn(OH)3

  8. Experimental data developed to support the selection of a treatment process for West Valley alkaline supernatant

    SciTech Connect (OSTI)

    Bray, L.A.; Holton, L.K.; Myers, T.R.; Richardson, G.M.; Wise, B.M.

    1984-01-01T23:59:59.000Z

    At the request of West Valley Nuclear Services Co., Inc., the Pacific Northwest Laboratory (PNL) has studied alternative treatment processes for the alkaline PUREX waste presently being stored in Tank 8D2 at West Valley, New York. Five tasks were completed during FY 1983: (1) simulation and characterization of the alkaline supernatant and sludge from the tank. The radiochemical and chemical distributions between the aqueous and solid phase were determined, and the efficiency of washing sludge with water to remove ions such as Na/sup +/ and SO/sub 4//sup 2 -/ was investigated; (2) evaluation of a sodium tetraphenylboron (Na-TPB) precipitation process to recover cesium (Cs) and a sodium titanate (Na-TiA) sorption process to recover strontium (Sr) and plutonium (Pu) from the West Valley Alkaline supernatant. These processes were previously developed and tested at the US Department of Energy's Savannah River Plant; (3) evaluation of an organic cation-exchange resin (Duolite CS-100) to recover Cs and Pu from the alkaline supernatant followed by an organic macroreticular cation exchange resin (Amberlite IRC-718) to recover Sr; (4) evaluation of an inorganic ion exchanger (Linde Ionsiv IE-95) to recover Cs, Sr, and Pu from the alkaline supernatant; and (5) evaluation of Dowex-1,X8 organic anion exchange resin to recover technetium (Tc) from alkaline supernatant. The findings of these tasks are reported. 21 references, 36 figures, 34 tables.

  9. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2004-01-01T23:59:59.000Z

    The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

  10. The Characterization of Eu2+-Doped Mixed Alkaline-Earth Iodide Scintillator Crystals

    SciTech Connect (OSTI)

    Neal, John S [ORNL; Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Wisniewski, D. [Institute of Physics, Nicolaus Copernicus University, Toru?, Poland; Kolopus, James A [ORNL; Cherepy, Nerine [Lawrence Livermore National Laboratory (LLNL); Payne, Stephen A. [Lawrence Livermore National Laboratory (LLNL)

    2011-01-01T23:59:59.000Z

    The high-performance inorganic scintillator, SrI2:Eu2+, when activated with divalent europium in the concentration range of 3 to 6%, has shown great promise for use in applications that require high-energy-resolution gamma-ray detection. We have recently grown and tested crystals in which other alkaline-earth ions have been partially substituted for Sr ions. Specifically, europium-doped single crystals have been grown in which up to 30 at % of the strontium ions have been substituted for either by barium, magnesium, or calcium ions. In the case of the strontium iodide scintillator host, a material that is characterized by an orthorhombic crystal structure, there are three other column IIA elements that are obvious choices for investigations whose purpose is to realize potential improvements in the performance of SrI2:Eu2+-based scintillators via the replacement of strontium ions with either Mg2+, Ca2+, or Ba2+. Light yields of up to 81,400 photons/MeV with an associated energy resolution of 3.7% (fwhm for 662 keV gamma-rays) have been observed in the case of a partial substitution of Ba2+ for Sr2+. The measured decay times ranged from 1.1 to 2.0 s, while the peak emission wavelengths ranged from 432 to 438 nm.

  11. Probes for measuring fluctuation-induced Maxwell and Reynolds stresses in the edge of the Madison Symmetric Torus reversed field pinch

    SciTech Connect (OSTI)

    Kuritsyn, A.; Fiksel, G.; Miller, M. C.; Almagri, A. F.; Reyfman, M.; Sarff, J. S. [Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas and Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

    2008-10-15T23:59:59.000Z

    Several probes have been constructed to measure fluctuation-induced Maxwell and Reynolds stresses in the edge of the Madison Symmetric Torus reversed field pinch (RFP). The magnetic probe is composed of six magnetic pickup coil triplets. The triplets are separated spatially, which allows for local measurements of the Maxwell stress. To measure the plasma flow components for evaluation of the Reynolds stress, we employ a combination of an optical probe [Kuritsyn et al., Rev. Sci. Indrum. 77, 10F112 (2006)] and a Mach probe. The optical probe measures the radial ion flow locally using Doppler spectroscopy. The Mach probe consists of four current collectors biased negatively with respect to a reference tip and allows for measurements of the poloidal and toroidal components of the bulk plasma flow. The stresses are observed to play an important role in the momentum balance in the RFP edge during internal reconnection events.

  12. IEEE TRANSACTIONS ON INSTRUMENTATION AND MEASUREMENT, VOL. 58, NO. 1, JANUARY 2009 129 Very-Low-Frequency Electromagnetic Field

    E-Print Network [OSTI]

    Motai, Yuichi

    . This electronic system can be used to monitor VLF electromagnetic radiation in residential and occupational-Low-Frequency Electromagnetic Field Detector With Data Acquisition Saba A. Hanna, Member, IEEE, Yuichi Motai, Member, IEEE-made VLF electromagnetic fields are stronger and have been suspected of causing negative health effects

  13. Measurements of 222Rn, 220Rn, and CO Emissions in Natural CO2 Fields in Wyoming: MVA Techniques for Determining Gas Transport and Caprock Integrity

    SciTech Connect (OSTI)

    Kaszuba, John; Sims, Kenneth

    2014-09-30T23:59:59.000Z

    An integrated field-laboratory program evaluated the use of radon and CO2 flux measurements to constrain source and timescale of CO2 fluxes in environments proximate to CO2 storage reservoirs. By understanding the type and depth of the gas source, the integrity of a CO2 storage reservoir can be assessed and monitored. The concept is based on correlations of radon and CO2 fluxes observed in volcanic systems. This fundamental research is designed to advance the science of Monitoring, Verification, and Accounting (MVA) and to address the Carbon Storage Program goal of developing and validating technologies to ensure 99 percent storage performance. Graduate and undergraduate students conducted the research under the guidance of the Principal Investigators; in doing so they were provided with training opportunities in skills required for implementing and deploying CCS technologies. Although a final method or “tool” was not developed, significant progress was made. The field program identified issues with measuring radon in environments rich in CO2. Laboratory experiments determined a correction factor to apply to radon measurements made in CO2-bearing environments. The field program also identified issues with radon and CO2-flux measurements in soil gases at a natural CO2 analog. A systematic survey of radon and CO2 flux in soil gases at the LaBarge CO2 Field in Southwest Wyoming indicates that measurements of 222Rn (radon), 220Rn (thoron), and CO2 flux may not be a robust method for monitoring the integrity of a CO2 storage reservoir. The field program was also not able to correlate radon and CO2 flux in the CO2-charged springs of the Thermopolis hydrothermal system. However, this part of the program helped to motivate the aforementioned laboratory experiments that determined correction factors for measuring radon in CO2-rich environments. A graduate student earned a Master of Science degree for this part of the field program; she is currently employed with a geologic consulting company. Measurement of radon in springs has improved significantly since the field program first began; however, in situ measurement of 222Rn and particularly 220Rn in springs is problematic. Future refinements include simultaneous salinity measurements and systematic corrections, or adjustments to the partition coefficient as needed for more accurate radon concentration determination. A graduate student earned a Master of Science degree for this part of the field program; he is currently employed with a geologic consulting company. Both graduate students are poised to begin work in a CCS technology area. Laboratory experiments evaluated important process-level fundamentals that effect measurements of radon and CO2. Laboratory tests established that fine-grained source minerals yield higher radon emissivity compared to coarser-sized source minerals; subtleties in the dataset suggest that grain size alone is not fully representative of all the processes controlling the ability of radon to escape its mineral host. Emissivity for both 222Rn and 220Rn increases linearly with temperature due to reaction of rocks with water, consistent with faster diffusion and enhanced mineral dissolution at higher temperatures. The presence of CO2 changes the relative importance of the factors that control release of radon. Emissivity for both 222Rn and 220Rn in CO2-bearing experiments is greater at all temperatures compared to the experiments without CO2, but emissivity does not increase as a simple function of temperature. Governing processes may include a balance between enhanced dissolution versus carbonate mineral formation in CO2-rich waters.

  14. Kerr electro-optic measurements for electric field and space charge distributions using similar and dissimilar electrode pairs

    E-Print Network [OSTI]

    Nowocin, John Kendall

    2013-01-01T23:59:59.000Z

    The electrical breakdown strength of insulating materials is a major limiting factor of reliability in electric power, medical devices, and other high electric field applications. Electrical breakdown strength increase ...

  15. Apparatus and procedure to characterize the surface quality of conductors by measuring the rate of cathode emission as a function of surface electric field strength

    DOE Patents [OSTI]

    Mestayer, Mac; Christo, Steve; Taylor, Mark

    2014-10-21T23:59:59.000Z

    A device and method for characterizing quality of a conducting surface. The device including a gaseous ionizing chamber having centrally located inside the chamber a conducting sample to be tested to which a negative potential is applied, a plurality of anode or "sense" wires spaced regularly about the central test wire, a plurality of "field wires" at a negative potential are spaced regularly around the sense, and a plurality of "guard wires" at a positive potential are spaced regularly around the field wires in the chamber. The method utilizing the device to measure emission currents from the conductor.

  16. Measurement of the internal stress and electric field in a resonating piezoelectric transformer for high-voltage applications using the electro-optic and photoelastic effects

    SciTech Connect (OSTI)

    VanGordon, James A.; Kovaleski, Scott D., E-mail: kovaleskis@missouri.edu; Norgard, Peter; Gall, Brady B. [Department of Electrical and Computer Engineering, University of Missouri, Columbia, Missouri 65211 (United States)] [Department of Electrical and Computer Engineering, University of Missouri, Columbia, Missouri 65211 (United States); Dale, Gregory E. [High Power Electrodynamics Group, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [High Power Electrodynamics Group, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2014-02-15T23:59:59.000Z

    The high output voltages from piezoelectric transformers are currently being used to accelerate charged particle beams for x-ray and neutron production. Traditional methods of characterizing piezoelectric transformers (PTs) using electrical probes can decrease the voltage transformation ratio of the device due to the introduction of load impedances on the order of hundreds of kiloohms to hundreds of megaohms. Consequently, an optical diagnostic was developed that used the photoelastic and electro-optic effects present in piezoelectric materials that are transparent to a given optical wavelength to determine the internal stress and electric field. The combined effects of the piezoelectric, photoelastic, and electro-optic effects result in a time-dependent change the refractive indices of the material and produce an artificially induced, time-dependent birefringence in the piezoelectric material. This induced time-dependent birefringence results in a change in the relative phase difference between the ordinary and extraordinary wave components of a helium-neon laser beam. The change in phase difference between the wave components was measured using a set of linear polarizers. The measured change in phase difference was used to calculate the stress and electric field based on the nonlinear optical properties, the piezoelectric constitutive equations, and the boundary conditions of the PT. Maximum stresses of approximately 10 MPa and electric fields of as high as 6 kV/cm were measured with the optical diagnostic. Measured results were compared to results from both a simple one-dimensional (1D) model of the piezoelectric transformer and a three-dimensional (3D) finite element model. Measured stresses and electric fields along the length of an operating length-extensional PT for two different electrical loads were within at least 50 % of 3D finite element simulated results. Additionally, the 3D finite element results were more accurate than the results from the 1D model for a wider range of electrical load impedances under test.

  17. NUMERICAL MODELING TO ASSESS POSSIBLE INFLUENCE OF THE MINE OPENINGS ON FAR-FIELD IN SITU STRESS MEASUREMENTS AT STRIPA

    E-Print Network [OSTI]

    Chan, T.

    2010-01-01T23:59:59.000Z

    and H. Board, 1980. "Rock Properties and Their Effect oncalculation, and from the rock properties measured undersame point. With the linear rock properties assumed in these

  18. Space-charge compensation measurements in electron cyclotron resonance ion source low energy beam transport lines with a retarding field analyzer

    SciTech Connect (OSTI)

    Winklehner, D.; Leitner, D., E-mail: leitnerd@nscl.msu.edu; Cole, D.; Machicoane, G.; Tobos, L. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)] [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)

    2014-02-15T23:59:59.000Z

    In this paper we describe the first systematic measurement of beam neutralization (space charge compensation) in the ECR low energy transport line with a retarding field analyzer, which can be used to measure the potential of the beam. Expected trends for the space charge compensation levels such as increase with residual gas pressure, beam current, and beam density could be observed. However, the overall levels of neutralization are consistently low (<60%). The results and the processes involved for neutralizing ion beams are discussed for conditions typical for ECR injector beam lines. The results are compared to a simple theoretical beam plasma model as well as simulations.

  19. Current collapse imaging of Schottky gate AlGaN/GaN high electron mobility transistors by electric field-induced optical second-harmonic generation measurement

    SciTech Connect (OSTI)

    Katsuno, Takashi, E-mail: e1417@mosk.tytlabs.co.jp; Ishikawa, Tsuyoshi; Ueda, Hiroyuki; Uesugi, Tsutomu [Toyota Central R and D Laboratories Inc., Nagakute, Aichi 480-1192 (Japan); Manaka, Takaaki; Iwamoto, Mitsumasa [Department of Physical Electronics, Tokyo Institute of Technology, Meguro, Tokyo 152-8552 (Japan)

    2014-06-23T23:59:59.000Z

    Two-dimensional current collapse imaging of a Schottky gate AlGaN/GaN high electron mobility transistor device was achieved by optical electric field-induced second-harmonic generation (EFISHG) measurements. EFISHG measurements can detect the electric field produced by carriers trapped in the on-state of the device, which leads to current collapse. Immediately after (e.g., 1, 100, or 800??s) the completion of drain-stress voltage (200?V) in the off-state, the second-harmonic (SH) signals appeared within 2??m from the gate edge on the drain electrode. The SH signal intensity became weak with time, which suggests that the trapped carriers are emitted from the trap sites. The SH signal location supports the well-known virtual gate model for current collapse.

  20. Measurement of magnetic turbulence structure and nonlinear mode coupling of tearing fluctuations in the Madison Symmetric Torus reversed field pinch edge

    SciTech Connect (OSTI)

    Assadi, S.

    1994-01-01T23:59:59.000Z

    Linear and nonlinear magnetohydrodynamic (MHD) stability of current-driven modes are studied in the MST reversed field pinch. Measured low frequency (f < 35 kHz) magnetic fluctuations are consistent with the global resistive tearing instabilities predicted by 3-D MHD simulations. At frequencies above 35 kHz, the magnetic fluctuations were detected to be localized and externally resonant. Discrete dynamo events, ``sawtooth oscillations,`` have been observed in the experimental RFP plasmas. This phenomenon causes the plasma to become unstable to m = 1 tearing modes. The modes that may be important in different phases of these oscillations are identified. These results then assist in nonlinear studies and also help to interpret the spectral broadening of the measured data during a discrete dynamo event. Three-wave nonlinear coupling of spectral Fourier modes is measured in the MST by applying bispectral analysis to magnetic fluctuations measured at the plasma edge at 64 toroidal locations and 16 poloidal locations, permitting observation of coupling over 8 poloidal and 32 toroidal modes. Comparison to bispectra predicted by resistive MHD computation indicates reasonably good agreement. However, during the crash phase of the sawtooth oscillation the nonlinear coupling is strongly enhanced, concomitant with a broadened k-spectrum. During the sawtooth formation the plasma is undergoing a pure diffusive process. The dynamo only occurs during the sawtooth crash. High frequency activity prior to a sawtooth crash is caused by nonlinear frequency (small-scale) mode coupling. Growth rate and coupling coefficients of toroidal mode spectra are calculated by statistical modeling. Temporal evolution of edge toroidal mode spectra has been predicted by transfer function analysis. The driving sources of electrostatic fields are different than for the magnetic fields. The characteristics of tearing modes can be altered by external field errors and addition of impurities to the plasma.

  1. Geologic and climatic controls on the formation of the Permian coal measures in the Sohagpur coal field, Madhya Pradesh, India

    SciTech Connect (OSTI)

    Milici, R.C.; Warwick, P.D.; Mukhopadhyah, A.; Adhikari, S.; Roy, S.P.; Bhattacharyya, S.

    1999-07-01T23:59:59.000Z

    The U.S. Geological Survey (USGS) and the Geological Survey of India (GSI) are concluding a cooperative study of the coking coal deposits in the Sohagpur coal field in central India. Because of the importance of coal in India's economy, the Coal Wing of the Geological Survey of India has studied the area intensely since the early 1980's. This report summarizes the overall stratigraphic, tectonic, and sedimentologic framework of the Sohagpur coal field area, and the interpretations of the geologic and climatic environments required for the accumulation of the thick Gondwana coal deposits, both coking and non-coking.

  2. Test report for photonic sensors used in electric-field measurement of simulated electromagnetic pulses. Final report, 28-30 Aug 90

    SciTech Connect (OSTI)

    Blocksom, R.; Bucholz, R.

    1991-01-01T23:59:59.000Z

    This report documents the results of tests to record and analyze the characteristic response of three photonic Electric field, E-field sensors to simulated Electromagnetic Pulse (EMP), compared to that of a reference metallic sensor. Work was performed under Naval Research Laboratory (NRL) contract N00014-89-C-2033, sponsored by Naval Air Systems Command (NAVAIR). Tasks included: (1) selection of candidate sensors capable of measuring the E-field content (intensity and frequency spectrum) of simulated EMP phenomena generated by the Horizontally Polarized Dipole (HPD) EMP simulator at the Naval Air Test Center (NATC), Patuxent River, MD; (2) liaison with sensor designers, NATC personnel, and others as necessary to delineate test requirements and constraints; (3) development of a sensor test plan; (4) sensor tests in the HPD EMP simulation; (5) analysis of the test data; and (6) generation of the Test Report. The activities discussed herein were performed during the period of March 1990-January 1991. Since 1985, the Naval Research Laboratory (NRL) and ARC Professional Services Group Defense Systems Division (ARC) have conducted an RD effort to produce a prototype fiber optic sensor system for application to EMP field measurement. The work was sponsored under Fleet Aircraft Assessment for Navy Testing and Analysis for EMP Limitation (FAANTAEL) project managed by NAVAIR Electromagnetic Environmental Effects (E3) Branch, AIR-5161.

  3. EOF-based constrained sensor placement and field reconstruction from noisy ocean measurements: Application to Nantucket Sound

    E-Print Network [OSTI]

    Chryssostomidis, Chryssostomos

    Sensor placement at the extrema of empirical orthogonal functions (EOFs) is efficient and leads to accurate reconstruction of the ocean state from a limited number of measurements. In this paper, we develop important new ...

  4. Radial profile measurement of electron temperature in edge stochastic magnetic field layer of LHD using intensity ratio of extreme ultraviolet line emissions

    SciTech Connect (OSTI)

    Wang Erhui [Department of Fusion Science, Graduate University for Advanced Studies, Toki 509-5292, Gifu (Japan); Morita, Shigeru; Kobayashi, Masahiko; Murakami, Izumi; Goto, Motoshi [Department of Fusion Science, Graduate University for Advanced Studies, Toki 509-5292, Gifu (Japan); National Institute for Fusion Science, Toki 509-5292, Gifu (Japan); Dong Chunfeng [National Institute for Fusion Science, Toki 509-5292, Gifu (Japan)

    2012-10-15T23:59:59.000Z

    Vertical profile of neon line emissions in 30-650 A wavelength range has been observed in horizontally elongated plasma cross section of Large Helical Device (LHD). Intensity ratio between the neon line emissions is studied to measure the radial profile of electron temperature in the edge stochastic magnetic field layer of LHD. The edge temperature profile successfully obtained from the line ratio of NeVIII 2s-3p to 2p-3s transitions is compared with the simulation based on three-dimensional edge transport code. The result shows a reasonably good agreement with the edge temperature profile analyzed from atomic data and analysis structure code. The electron temperature at last closed flux surface measured from the intensity ratio is also in good agreement with that measured from Thomson scattering.

  5. Model for trace metal exposure in filter-feeding flamingos at alkaline Rift Valley Lake, Kenya

    SciTech Connect (OSTI)

    Nelson, Y.M.; DiSante, C.J.; Lion, L.W. [Cornell Univ., Ithaca, NY (United States). School of Civil and Environmental Engineering; Thampy, R.J.; Raini, J.A. [Worldwide Fund for Nature, Nakuru (Kenya). Lake Nakuru Conservation and Development Project; Motelin, G.K. [Egerton Univ., Njoro (Kenya). Dept. of Animal Health

    1998-11-01T23:59:59.000Z

    Toxic trace metals have been implicated as a potential cause of recent flamingo kills at Lake Nakuru, Kenya. Chromium (Cr), copper (Cu), lead (Pb), and zinc (Zn) have accumulated in the lake sediments as a result of unregulated discharges and because this alkaline lake has no natural outlet. Lesser flamingos (Phoeniconaias minor) at Lake Nakuru feed predominantly on the cyanobacterium Spirulina platensis, and because of their filter-feeding mechanism, they are susceptible to exposure to particle-bound metals. Trace metal adsorption isotherms to lake sediments and S. platensis were obtained under simulated lake conditions, and a mathematical model was developed to predict metal exposure via filter feeding based on predicted trace metal phase distribution. Metal adsorption to suspended solids followed the trend Pb {much_gt} Zn > Cr > Cu, and isotherms were linear up to 60 {micro}g/L. Adsorption to S. platensis cells followed the trend Pb {much_gt} Zn > Cu > Cr and fit Langmuir isotherms for Cr, Cu and Zn and a linear isotherm for Pb. Predicted phase distributions indicated that Cr and Pb in Lake Nakuru are predominantly associated with suspended solids, whereas Cu and Zn are distributed more evenly between the dissolved phase and particulate phases of both S. platensis and suspended solids. Based on established flamingo feeding rates and particle size selection, predicted Cr and Pb exposure occurs predominantly through ingestion of suspended solids, whereas Cu and Zn exposure occurs through ingestion of both suspended solids and S. platensis. For the lake conditions at the time of sampling, predicted ingestion rates based on measured metal concentrations in lake suspended solids were 0.71, 6.2, 0.81, and 13 mg/kg-d for Cr, Cu, Pb, and Zn, respectively.

  6. Novel alkaline earth copper germanates with ferro and antiferromagnetic S=1/2 chains

    SciTech Connect (OSTI)

    Brandao, Paula [University of Aveiro, Portugal; Reis, Mario S [Universidade Federal Fluminense, Brasil; Gai, Zheng [ORNL; Moreira Dos Santos, Antonio F [ORNL

    2013-01-01T23:59:59.000Z

    Two new alkaline earth copper(II) germanates were hydrothermally synthesized: CaCuGeO4 center dot H2O (1) and BaCu2Ge3O9 center dot H2O (2), and their structures determined by single crystal X-ray diffraction. Compound (1) crystallizes in space group P2(1)/c with a=5.1320(2) angstrom, b=16.1637(5) angstrom, c=5.4818(2) angstrom, beta=102.609(2)degrees, V=443.76(3) angstrom(3) and Z=4. This copper germanate contains layers of composition [CuGeO4](infinity)(2-) comprising CuO4 square planes and GeO4 tetrahedra with calcium and water molecules in the inter-layer space. Compound (2) crystallizes in the Cmcm space group with a=5.5593(3) angstrom, b=10.8606(9) angstrom, c=13.5409(8) angstrom, V=817.56(9) angstrom(3) and Z=4. This structure contains GeO6 and CuO6 octahedra as well as GeO4 tetrahedra, forming a three-dimensional network of interconnecting six-membered ring channels. The magnetic susceptibility for both samples can be interpreted as S=1/2 chains, in agreement with the copper topology observed in the crystal structure. The susceptibility of (1) exhibits a Bonner-Fisher type behavior, resulting from antiferromagnetic intra-chain interactions without three-dimensional ordering down to 5 K-the lowest measured temperature. This observation, together with the absence of super-exchange paths between the copper chains, make this system particularly promising for the study of low dimensional magnetism. The magnetic properties of (2) show a very weak ferromagnetic near-neighbor interaction along the chain. In this compound a peak the chi T plot seems to indicate the onset of interchain antiferromagentic correlations. However, no ordering temperature is detected in the susceptibility data.

  7. Measurement and effects of polarization fields on one-monolayer-thick InN/GaN multiple quantum wells

    SciTech Connect (OSTI)

    Zhou, Lin; Dimakis, E.; Hathwar, R.; Aoki, Toshihiro; Smith, David J.; Moustakas, T. D.; Goodnick, S. M.; McCartney, Martha R.

    2013-09-25T23:59:59.000Z

    Polarization fields associated with one-monolayer-thick InN/GaN multiple quantum wells (MQWs) cause shifts of the photoluminescence peak that depend on the GaN barrier layer thickness. Diffraction contrast and aberration-corrected scanning transmission electron microscopy show that the InN QWs are well defined and coherently strained. Mapping of electrostatic potential using off-axis electron holography shows that the electric fields inside the GaN barriers decrease from ?0.7 to ?0.2 MV/cm as the barrier layer thickness increases from 5 to 20 nm. Atomistic tight-binding calculations agree closely with experiment, and confirm that changes in optical emission of these III-nitride quantum wells result from changes in the spontaneous and piezoelectric polarization fields in the InN quantum wells and the GaN barrier layers. Overall, this QW system provides the basis for InN-based light-emitting devices operating across a useful band of wavelengths at room temperature.

  8. aqueous alkaline medium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which is essential for the formation Sahai, Nita 2 Ultrasonic measurement of porous medium in an aqueous environment Texas A&M University - TxSpace Summary: August 1995 Major...

  9. Breast radiotherapy in the prone position primarily reduces the maximum out-of-field measured dose to the ipsilateral lung

    E-Print Network [OSTI]

    Brenner, David Jonathan

    to the ipsilateral lung Stewart J. Beckera) Department of Radiation Oncology, New York University Langone Medical, particularly, the breast or the lung. Several dosimetric studies have been reported, based on commercial. Measurements were made using multiple MOSFET dosimeters in various locations in the ipsilateral lung

  10. Measurements of actinide-fission product yields in Caliban and Prospero metallic core reactor fission neutron fields

    SciTech Connect (OSTI)

    Casoli, P.; Authier, N. [CEA, Centre de Valduc, 21120 Is-sur-Tille (France); Laurec, J.; Bauge, E.; Granier, T. [CEA, Centre DIF, 91297 Arpajon (France)

    2011-07-01T23:59:59.000Z

    In the 1970's and early 1980's, an experimental program was performed on the facilities of the CEA Valduc Research Center to measure several actinide-fission product yields. Experiments were, in particular, completed on the Caliban and Prospero metallic core reactors to study fission-neutron-induced reactions on {sup 233}U, {sup 235}U, and {sup 239}Pu. Thick actinide samples were irradiated and the number of nuclei of each fission product was determined by gamma spectrometry. Fission chambers were irradiated simultaneously to measure the numbers of fissions in thin deposits of the same actinides. The masses of the thick samples and the thin deposits were determined by mass spectrometry and alpha spectrometry. The results of these experiments will be fully presented in this paper for the first time. A description of the Caliban and Prospero reactors, their characteristics and performances, and explanations about the experimental approach will also be given in the article. A recent work has been completed to analyze and reinterpret these measurements and particularly to evaluate the associated uncertainties. In this context, calculations have also been carried out with the Monte Carlo transport code Tripoli-4, using the published benchmarked Caliban description and a three-dimensional model of Prospero, to determine the average neutron energy causing fission. Simulation results will be discussed in this paper. Finally, new fission yield measurements will be proposed on Caliban and Prospero reactors to strengthen the results of the first experiments. (authors)

  11. Spin-lattice coupling in uranium dioxide probed by magnetostriction measurements at high magnetic fields (P08358-E001-PF)

    SciTech Connect (OSTI)

    K. Gofryk; M. Jaime

    2014-12-01T23:59:59.000Z

    Conclusions Our preliminary magnetostriction measurements have already shown a strong interplay of lattice dynamic and magnetism in both antiferromagnetic and paramagnetic states, and give unambiguous evidence of strong spin- phonon coupling in uranium dioxide. Further studies are planned to address the puzzling behavior of UO2 in magnetic and paramagnetic states and details of the spin-phonon coupling.

  12. Investigation of the Faraday Rotation Measure and Magnetic Field Structures of Several AGN Jets on Sub-Parsec to Parsec Scales

    E-Print Network [OSTI]

    Shane P. O'Sullivan; Denise C. Gabuzda

    2007-09-30T23:59:59.000Z

    Preliminary VLBA polarisation results on 6 ``blazars'' from 6.5-cm to 7-mm are presented here. Observing at several different wavelengths, separated by short and long intervals, enabled reliable information about the magnetic (B) field structure to be obtained and for the effect of Faraday Rotation to be determined and corrected. For all sources the magnitude of the core Rotation Measure (RM) derived from the shorter wavelength data was greater than that derived from the longer wavelength data, consistent with a higher electron density and/or B-field strength closer to the central engine. A transverse RM gradient was detected in the jet of 0954+658, providing evidence for the presence of a helical B-field surrounding the jet. The RM in the core region of 2200+420 (BL Lac) displays sign changes in different wavelength intervals (on different spatial scales); we suggest an explanation for this in terms of modest bends in a helical B-field surrounding the jet.

  13. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions into the atmosphere2

    E-Print Network [OSTI]

    Boyer, Edmond

    dioxide sequestration process. The overall carbonation reaction includes the following steps: (1)23 CaCarbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions change.20 This study investigates experimentally the aqueous carbonation mechanisms of an alkaline paper

  14. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3....

  15. Residual alkalinity as tracer to estimate the changes induced by forage cultivation in a non-saline irrigated sodic soil

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Residual alkalinity as tracer to estimate the changes induced by forage cultivation in a non, 31000 Toulouse, France Short title: Residual alkalinity and reclamation of sodic soil Summary Soil) the large amount of water supplied during cultivation that induced salt leaching. This is the main

  16. Synthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol fuel cells

    E-Print Network [OSTI]

    Zhao, Tianshou

    Available online 3 August 2010 Keywords: Fuel cell Alkaline direct ethanol fuel cell Oxygen reduction Carbon in large quantities from agricultural products or biomass. Hence, direct ethanol fuel cells (DEFCs) haveSynthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol

  17. Alkaline resistant phosphate glasses and method of preparation and use thereof

    DOE Patents [OSTI]

    Brow, Richard K. (Rolla, MO); Reis, Signo T. (Rolla, MO); Velez, Mariano (Rolla, MO); Day, Delbert E. (Rolla, MO)

    2010-01-26T23:59:59.000Z

    A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.

  18. Author's personal copy An alkaline direct ethylene glycol fuel cell with

    E-Print Network [OSTI]

    Zhao, Tianshou

    ), rather than carbon di- oxide (CO2) [5]. Hence, the actual and maximum electron transfer numbers per), and the product of ethanol oxidation reaction (EOR) in alkaline media is pre- dominated by acetic acid (CH3COOH), respectively. Under this circumstance, the electron transfer rate (ETR) of the ethanol oxidation reaction (EOR

  19. Analysis of Pt/C electrode performance in a flowing-electrolyte alkaline fuel cell

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Analysis of Pt/C electrode performance in a flowing- electrolyte alkaline fuel cell Fikile R cell Electrode characterization X-ray micro-computed tomography Microfluidic fuel cell Carbonates a b a microfluidic H2/O2 fuel cell as an analytical platform. Both anodes and cathodes were investigated

  20. Alkaline stability of cellulose ethers and impact of their degradation products on cement hydration

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Alkaline stability of cellulose ethers and impact of their degradation products on cement-mail address: pourchez@emse.fr emse-00449712,version1-18Sep2010 Author manuscript, published in "Cement the potential role of cellulose ethers degradation on the alteration of the cement hydration kinetics

  1. Poly (vinyl alcohol)/3-(trimethylammonium) propyl-functionalized silica hybrid membranes for alkaline

    E-Print Network [OSTI]

    Zhao, Tianshou

    oxidation and oxygen reduction reactions. As a result, the overall cost of the fuel cell system can for alkaline direct ethanol fuel cells E.D. Wang, T.S. Zhao*, W.W. Yang Department of Mechanical Engineering Accepted 29 December 2009 Available online 8 January 2010 Keywords: Fuel cell Direct ethanol fuel cell

  2. Surface structural changes of perovskite oxides during oxygen evolution in alkaline electrolyte

    E-Print Network [OSTI]

    May, Kevin J. (Kevin Joseph)

    2013-01-01T23:59:59.000Z

    Perovskite oxides such Ba0.5Sr0.5Co0.8Fe0.8O3-6 (BSCF82) are among the most active catalysts for the oxygen evolution reaction (OER) in alkaline solution reported to date. In this work it is shown via high resolution ...

  3. MINERALOGY AND GENESIS OF SMECTITES IN AN ALKALINE-SALINE ENVIRONMENT OF PANTANAL WETLAND, BRAZIL

    E-Print Network [OSTI]

    Ahmad, Sajjad

    MINERALOGY AND GENESIS OF SMECTITES IN AN ALKALINE-SALINE ENVIRONMENT OF PANTANAL WETLAND, BRAZIL, Universidade de Sa~o Paulo (USP), Av. Prof. Dr. Lineu Prestes, 338, 05508-900, Sa~o Paulo, Brazil 2 Soil-saline lake of Nhecola^ndia, a sub-region of the Pantanal wetland, Brazil, and then to identify the mechanisms

  4. Natural Arsenic in Groundwater and Alkaline Lakes at the upper Paraguay basin, Pantanal, Brazil

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Natural Arsenic in Groundwater and Alkaline Lakes at the upper Paraguay basin, Pantanal, Brazil L, Brazil d Université de Provence, Aix Marseille 1, France e Departamento de Geografia, Universidade Federal do Mato Grosso do Sul, Três Lagoas, Brazil f Laboratoire de Géomophologie Appliquée, Université de

  5. The structure and energetics of $^3$He and $^4$He nanodroplets doped with alkaline earth atoms

    E-Print Network [OSTI]

    A. Hernando; R. Mayol; M. Pi; M. Barranco; F. Ancilotto; O. B{ü}nermann; F. Stienkemeier

    2007-05-08T23:59:59.000Z

    We present systematic results, based on density functional calculations, for the structure and energetics of $^3$He and $^4$He nanodroplets doped with alkaline earth atoms. We predict that alkaline earth atoms from Mg to Ba go to the center of $^3$He drops, whereas Ca, Sr, and Ba reside in a deep dimple at the surface of $^4$He drops, and Mg is at their center. For Ca and Sr, the structure of the dimples is shown to be very sensitive to the He-alkaline earth pair potentials used in the calculations. The $5s5p\\leftarrow5s^2$ transition of strontium atoms attached to helium nanodroplets of either isotope has been probed in absorption experiments. The spectra show that strontium is solvated inside $^3$He nanodroplets, supporting the calculations. In the light of our findings, we emphasize the relevance of the heavier alkaline earth atoms for analyzing mixed $^3$He-$^4$He nanodroplets, and in particular, we suggest their use to experimentally probe the $^3$He-$^4$He interface.

  6. Separating natural and bomb-produced radiocarbon in the ocean: The potential alkalinity method

    E-Print Network [OSTI]

    the atmosphere to the ocean on a similar time scale and that they penetrate into the ocean in a similar mannerSeparating natural and bomb-produced radiocarbon in the ocean: The potential alkalinity method M. Key Atmospheric and Oceanic Sciences Program, Princeton University, Princeton, New Jersey, USA

  7. alkaline-earth silicate phosphors: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline-earth silicate phosphors First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Diffusion Raman...

  8. alkaline-earth dihalide molecules: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline-earth dihalide molecules First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 EDM searches based on...

  9. alkaline-earth elements studied: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline-earth elements studied First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 A theoretical study of...

  10. alkali halide-alkaline earth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali halide-alkaline earth First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Long range interactions...

  11. Noncovalent interaction or chemical bonding between alkaline earth cations and benzene? A quantum chemistry study using

    E-Print Network [OSTI]

    Sussman, Joel L.

    Noncovalent interaction or chemical bonding between alkaline earth cations and benzene? A quantum earth metal ion±benzene complexes were performed using the density-functional theory (DFT) B3LYP and ab of the al- kaline earth metal ions to benzene may be attributed to s±p and p±p interactions, which are signi

  12. Geothermal fluxes of alkalinity in the Narayani river system of central Nepal

    E-Print Network [OSTI]

    Derry, Louis A.

    Geothermal fluxes of alkalinity in the Narayani river system of central Nepal Matthew J. Evans hot springs flow within the steeply incised gorges of the central Nepal Himalayan front. The spring of central Nepal, Geochem. Geophys. Geosyst., 5, Q08011, doi:10.1029/2004GC000719. G 3 G 3Geochemistry

  13. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions to reflect, adsorb and emit the solar energy. However, the continuous emissions of CO2 into the atmosphere

  14. Simultaneous measurement of the microscopic dynamics and the mesoscopic displacement field in soft systems by speckle imaging

    E-Print Network [OSTI]

    Luca Cipelletti; Giovanni Brambilla; Simona Maccarrone; Sami Caroff

    2013-06-18T23:59:59.000Z

    The constituents of soft matter systems such as colloidal suspensions, emulsions, polymers, and biological tissues undergo microscopic random motion, due to thermal energy. They may also experience drift motion correlated over mesoscopic or macroscopic length scales, \\textit{e.g.} in response to an internal or applied stress or during flow. We present a new method for measuring simultaneously both the microscopic motion and the mesoscopic or macroscopic drift. The method is based on the analysis of spatio-temporal cross-correlation functions of speckle patterns taken in an imaging configuration. The method is tested on a translating Brownian suspension and a sheared colloidal glass.

  15. Nepheline syenites and related magmatic fluids in the Ditr u Alkaline Massif, Transylvania, Romania Andrs Fall *, Robert J. Bodnar and Csaba Szab

    E-Print Network [OSTI]

    Bodnar, Robert J.

    Nepheline syenites and related magmatic fluids in the Ditr u Alkaline Massif, Transylvania, Romania Carpathians, in Romania, and is a Mesozoic alkaline igneous complex formed during an extensional phase

  16. Self-Management of Patient Body Position, Pose, and Motion Using Wide-Field, Real-Time Optical Measurement Feedback: Results of a Volunteer Study

    SciTech Connect (OSTI)

    Parkhurst, James M. [Developing Technologies, Christie Medical Physics and Engineering, The Christie NHS Foundation Trust, Manchester (United Kingdom); Price, Gareth J., E-mail: gareth.price@christie.nhs.uk [Developing Technologies, Christie Medical Physics and Engineering, The Christie NHS Foundation Trust, Manchester (United Kingdom); Faculty of Medical and Human Sciences, Manchester Academic Health Sciences Centre, University of Manchester, Manchester (United Kingdom); Sharrock, Phil J. [Developing Technologies, Christie Medical Physics and Engineering, The Christie NHS Foundation Trust, Manchester (United Kingdom); Jackson, Andrew S.N. [Clinical Oncology, Southampton University Hospitals Foundation Trust, Southampton (United Kingdom); Stratford, Julie [Department of Radiotherapy, The Christie NHS Foundation Trust, Manchester (United Kingdom); Moore, Christopher J. [Developing Technologies, Christie Medical Physics and Engineering, The Christie NHS Foundation Trust, Manchester (United Kingdom); Faculty of Medical and Human Sciences, Manchester Academic Health Sciences Centre, University of Manchester, Manchester (United Kingdom)

    2013-12-01T23:59:59.000Z

    Purpose: We present the results of a clinical feasibility study, performed in 10 healthy volunteers undergoing a simulated treatment over 3 sessions, to investigate the use of a wide-field visual feedback technique intended to help patients control their pose while reducing motion during radiation therapy treatment. Methods and Materials: An optical surface sensor is used to capture wide-area measurements of a subject's body surface with visualizations of these data displayed back to them in real time. In this study we hypothesize that this active feedback mechanism will enable patients to control their motion and help them maintain their setup pose and position. A capability hierarchy of 3 different level-of-detail abstractions of the measured surface data is systematically compared. Results: Use of the device enabled volunteers to increase their conformance to a reference surface, as measured by decreased variability across their body surfaces. The use of visual feedback also enabled volunteers to reduce their respiratory motion amplitude to 1.7 ± 0.6 mm compared with 2.7 ± 1.4 mm without visual feedback. Conclusions: The use of live feedback of their optically measured body surfaces enabled a set of volunteers to better manage their pose and motion when compared with free breathing. The method is suitable to be taken forward to patient studies.

  17. A Novel Retrieval Algorithm for Cloud Optical Properties from the Atmopsheric Radiation Measurement Program's Two-Channel Narrow-Field-of-View Radiometer

    SciTech Connect (OSTI)

    Wiscombe, Warren J.; Marshak, A.; Chiu, J.-Y. C.; Knyazikhin, Y.; Barnard, James C.; Luo, Yi

    2005-03-14T23:59:59.000Z

    Cloud optical depth is the most important of all cloud optical properties, and vital for any cloud-radiation parameterization. To estimate cloud optical depth, the atmospheric science community has widely used ground-based flux measurements from either broadband or narrowband radiometers in the past decade. However, this type of technique is limited to overcast conditions and, at best, gives us an "effective" cloud optical depth instead of its "local" value. Unlike flux observations, monochromatic narrow-field-of-view (NFOV) radiance measurements contain information of local cloud properties, but unfortunately, the use of radiance to interpret optical depth suffers from retrieval ambiguity. We have pioneered an algorithm to retrieve cloud optical depth in a fully three-dimensional cloud situation using new Atmospheric Radiation Measurement (ARM) ground-based passive two-channel (673 and 870 nm) NFOV measurements. The underlying principle of the algorithm is that these two channels have similar cloud properties but strong spectral contrast in surface reflectance. This algorthm offers the first opportunity to illustrate cloud evolution with high temporal resolution retrievals. A combination of two-channel NFOV radiances with multi-filter rotating shadowband radiometer (MFRSR) fluxes for the retrieval of cloud optical properties is also discussed.

  18. Analysis of carrier behavior in C60/P(VDF-TrFE) double-layer capacitor by using electric-field-induced optical second-harmonic generation measurement

    SciTech Connect (OSTI)

    Cui, Xiaojin [Department of Physical Electronics, Tokyo Institute of Technology 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552 (Japan); State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Taguchi, Dai; Manaka, Takaaki; Iwamoto, Mitsumasa, E-mail: iwamoto@pe.titech.ac.jp [Department of Physical Electronics, Tokyo Institute of Technology 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2013-12-21T23:59:59.000Z

    By using displacement current measurement (DCM) and electric-field-induced optical second-harmonic generation (EFISHG) measurement, we studied the carrier behavior in the indium-tin oxide (ITO)/Poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE))/C60/Au(or Al) capacitors. Two DCM peaks appeared asymmetrically at around ?35.5?V and +30.0?V in the dark. Correspondingly, the EFISHG response from the C60 layer was observed, but the peak positions were different with respect to DCM ones. The results show that the spontaneous polarization of the ferroelectric P(VDF-TrFE) polymeric layer directly affects the electric field in the C60 layer, and thus governs the carrier motion in this layer. As a result, the C60 layer serves like an insulator in the dark, while electrons and holes are captured and released at the interface in response to the turn-over of spontaneous polarization of ferroelectric layer. On the other hand, under white light illumination, C60 layer serves like a conductor due to the increase of photogenerated mobile carriers, and these carriers dominate the carrier motions therein. Our findings here will be helpful for analyzing carrier behaviors in organic electronic devices using ferroelectric polymers.

  19. Mechanism of CO Oxidation on Pt(111) in Alkaline Media J. S. Spendelow, J. D. Goodpaster, P. J. A. Kenis, and A. Wieckowski*

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    of the mechanism of CO oxidation on Pt surfaces would be useful in optimizing Pt-based catalysts for fuel cell fuel cells (DMFCs) and reformate- fed hydrogen fuel cells.1-11 Alkaline electrolytes have been shown carbonation in alkaline media complicates the use of alkaline electrolytes for fuel cells.16 Fuel cells

  20. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  1. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-31T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  2. MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS

    SciTech Connect (OSTI)

    Smith, F; Luther Hamm, L; Sebastian Aleman, S; Johnston Michael, J

    2008-08-26T23:59:59.000Z

    The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.

  3. Surfactant-enhanced alkaline flooding for light oil recovery. Annual report, 1992--1993

    SciTech Connect (OSTI)

    Wasan, D.T.

    1994-08-01T23:59:59.000Z

    In this report, the authors present the results of experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, the authors have (1) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, (2) investigated the mechanisms for spontaneous emulsification, (3) developed a technique to monitor low water content in oil, and (4) developed a technique to study water-in-oil emulsion film properties.

  4. Dark-state suppression and optimization of laser cooling and fluorescence in a trapped alkaline-earth-metal single ion

    E-Print Network [OSTI]

    T. Lindvall; M. Merimaa; I. Tittonen; A. A. Madej

    2012-12-19T23:59:59.000Z

    We study the formation and destabilization of dark states in a single trapped 88Sr+ ion caused by the cooling and repumping laser fields required for Doppler cooling and fluorescence detection of the ion. By numerically solving the time-dependent density matrix equations for the eight-level system consisting of the sublevels of the 5s 2S1/2, 5p 2P1/2, and 4d 2D3/2 states, we analyze the different types of dark states and how to prevent them in order to maximize the scattering rate, which is crucial for both the cooling and the detection of the ion. The influence of the laser linewidths and ion motion on the scattering rate and the dark resonances is studied. The calculations are then compared with experimental results obtained with an endcap ion trap system located at the National Research Council of Canada and found to be in good agreement. The results are applicable also to other alkaline earth ions and isotopes without hyperfine structure.

  5. Shell structure underlying the evolution of quadrupole collectivity in S-38 and S-40 probed by transient-field g-factor measurements on fast radioactive beams

    E-Print Network [OSTI]

    A. E. Stuchbery; A. D. Davies; P. F. Mantica; P. M. Davidson; A. N. Wilson; A. Becerril; B. A. Brown; C. M. Campbell; J. M. Cook; D. C. Dinca; A. Gade; S. N. Liddick; T. J. Mertzimekis; W. F. Mueller; J. R. Terry; B. E. Tomlin; K. Yoneda; H. Zwahlen

    2006-09-21T23:59:59.000Z

    The shell structure underlying shape changes in neutron-rich nuclei between N=20 and N=28 has been investigated by a novel application of the transient field technique to measure the first-excited state g factors in S-38 and S-40 produced as fast radioactive beams. Details of the new methodology are presented. In both S-38 and S-40 there is a fine balance between the proton and neutron contributions to the magnetic moments. Shell model calculations which describe the level schemes and quadrupole properties of these nuclei also give a satisfactory explanation of the g factors. In S-38 the g factor is extremely sensitive to the occupation of the neutron p3/2 orbit above the N=28 shell gap as occupation of this orbit strongly affects the proton configuration. The g factor of deformed S-40 does not resemble that of a conventional collective nucleus because spin contributions are more important than usual.

  6. Magnetic behavior of LaMn{sub 2}(Si{sub (1?x)}Ge{sub x}){sub 2} compounds characterized by magnetic hyperfine field measurements

    SciTech Connect (OSTI)

    Bosch-Santos, B., E-mail: brianna@usp.br; Carbonari, A. W.; Cabrera-Pasca, G. A.; Saxena, R. N. [Instituto de Pesquisas Energéticas e Nucleares, University of São Paulo, 05508-000 São Paulo (Brazil)

    2014-05-07T23:59:59.000Z

    The temperature dependence of the magnetic hyperfine field (B{sub hf}) at Mn atom sites was measured in LaMn{sub 2}(Si{sub (1?x)}Ge{sub x}){sub 2}, with 0???x???1, compounds with perturbed ??? angular correlation spectroscopy using {sup 111}In({sup 111}Cd) as probe nuclei in the temperature range from 20?K to 480?K. The results show a transition from antiferromagnetic to ferromagnetic ordering for all studied compounds when Ge gradually replaces Si and allowed an accurate determination of the Néel temperature (T{sub N}) for each compound. It was observed that T{sub N} decreases when Ge concentration increases. Conversely, the Curie temperature increases with increase of Ge concentration. This remarkable change in the behavior of the transition temperatures is discussed in terms of the Mn-Mn distance and ascribed to a change in the exchange constant J{sub ex}.

  7. Stainless steel anodes for alkaline water electrolysis and methods of making

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev

    2014-01-21T23:59:59.000Z

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  8. Advances in the growth of alkaline-earth halide single crystals for scintillator detectors

    SciTech Connect (OSTI)

    Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Kolopus, James A [ORNL; Neal, John S [ORNL; Cherepy, Nerine [Lawrence Livermore National Laboratory (LLNL); Payne, Stephen A. [Lawrence Livermore National Laboratory (LLNL); Beck, P [Lawrence Livermore National Laboratory (LLNL); Burger, Arnold [Fisk University, Nashville; Rowe, E [Fisk University, Nashville; Bhattacharya, P. [Fisk University, Nashville

    2014-01-01T23:59:59.000Z

    Alkaline-earth scintillators such as strontium iodide and other alkaline-earth halides activated with divalent europium represent some of the most efficient and highest energy resolution scintillators for use as gamma-ray detectors in a wide range of applications. These applications include the areas of nuclear nonproliferation, homeland security, the detection of undeclared nuclear material, nuclear physics and materials science, medical diagnostics, space physics, high energy physics, and radiation monitoring systems for first responders, police, and fire/rescue personnel. Recent advances in the growth of large single crystals of these scintillator materials hold the promise of higher crystal yields and significantly lower detector production costs. In the present work, we describe new processing protocols that, when combined with our molten salt filtration methods, have led to advances in achieving a significant reduction of cracking effects during the growth of single crystals of SrI2:Eu2+. In particular, we have found that extended pumping on the molten crystal-growth charge under vacuum for time periods extending up to 48 hours is generally beneficial in compensating for variations in the alkaline-earth halide purity and stoichiometry of the materials as initially supplied by commercial sources. These melt-pumping and processing techniques are now being applied to the purification of CaI2:Eu2+ and some mixed-anion europium-doped alkaline-earth halides prior to single-crystal growth by means of the vertical Bridgman technique. The results of initial studies of the effects of aliovalent doping of SrI2:Eu2+ on the scintillation characteristics of this material are also described.

  9. Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions

    DOE Patents [OSTI]

    Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

    2001-01-01T23:59:59.000Z

    A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

  10. CHARACTERIZATION OF ACTINIDES IN SIMULATED ALKALINE TANK WASTE SLUDGES AND LEACHATES

    SciTech Connect (OSTI)

    Nash, Kenneth L.

    2008-11-20T23:59:59.000Z

    In this project, both the fundamental chemistry of actinides in alkaline solutions (relevant to those present in Hanford-style waste storage tanks), and their dissolution from sludge simulants (and interactions with supernatants) have been investigated under representative sludge leaching procedures. The leaching protocols were designed to go beyond conventional alkaline sludge leaching limits, including the application of acidic leachants, oxidants and complexing agents. The simulant leaching studies confirm in most cases the basic premise that actinides will remain in the sludge during leaching with 2-3 M NaOH caustic leach solutions. However, they also confirm significant chances for increased mobility of actinides under oxidative leaching conditions. Thermodynamic data generated improves the general level of experiemental information available to predict actinide speciation in leach solutions. Additional information indicates that improved Al removal can be achieved with even dilute acid leaching and that acidic Al(NO3)3 solutions can be decontaminated of co-mobilized actinides using conventional separations methods. Both complexing agents and acidic leaching solutions have significant potential to improve the effectiveness of conventional alkaline leaching protocols. The prime objective of this program was to provide adequate insight into actinide behavior under these conditions to enable prudent decision making as tank waste treatment protocols develop.

  11. ORNL/CDIAC-160 Climatological Distributions of pH, pCO2, Total CO2, Alkalinity,

    E-Print Network [OSTI]

    ORNL/CDIAC-160 NDP-094 Climatological Distributions of pH, pCO2, Total CO2, Alkalinity, and CaCO3, Alkalinity, and CaCO3 Saturation in the Global Surface Ocean. ORNL/CDIAC-160, NDP-094. Carbon Dioxide, total CO2 concentration (TCO2), and the degree of CaCO3 saturation for the global surface ocean waters

  12. Anodically electrodeposited Co+Ni mixed oxide electrode: preparation and electrocatalytic activity for oxygen evolution in alkaline media

    SciTech Connect (OSTI)

    Wu Gang [Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084 (China)]. E-mail: wugang@mail.tsinghua.edu.cn; Li Ning [Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001 (China); Zhou Derui [Department of Applied Chemistry, Harbin Institute of Technology, Harbin 150001 (China); Mitsuo, Kurachi [Faculty of Engineering, Kyoto University, Kyoto 606-8283 (Japan); Xu Boqing [Innovative Catalysis Program, Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084 (China)

    2004-10-01T23:59:59.000Z

    Co+Ni mixed oxides on Ni substrate were prepared through anodic electrodeposition from Co(NO{sub 3}){sub 2} and Ni(NO{sub 3}){sub 2} aqueous solutions with five different Co{sup 2+}/Ni{sup 2+} ratios beside only Co{sup 2+}. By the electrochemical measurements, the optimum performance in electrocatalytic activity for oxygen evolution reaction in alkaline media was obtained on the Co+Ni mixed oxide deposited from the solution containing Co{sup 2+}/Ni{sup 2+} ratio of 1:1. The mixed oxide is corresponding to about 68at% Co contents with spinel-type NiCo{sub 2}O{sub 4} phase and porosity surface structure. The electrochemical kinetic parameters including exchange current density, Tafel slopes, reaction order with respect to [OH{sup -}] and standard electrochemical enthalpy of activation were analyzed also. A possible mechanism involving the formation of a physisorbed hydrogen peroxide intermediate in a slow electrochemical step was presented, which accounts for the values of the experimental results.

  13. Simulating Black Carbon and Dust and their Radiative Forcing in Seasonal Snow: A Case Study over North China with Field Campaign Measurements

    SciTech Connect (OSTI)

    Zhao, Chun; Hu, Zhiyuan; Qian, Yun; Leung, Lai-Yung R.; Huang, J.; Huang, Maoyi; Jin, Jiming; Flanner, M. G.; Zhang, Rudong; Wang, Hailong; Yan, Huiping; Lu, Zifeng; Streets, D. G.

    2014-10-30T23:59:59.000Z

    A state-of-the-art regional model, WRF-Chem, is coupled with the SNICAR model that includes the sophisticated representation of snow metamorphism processes available for climate study. The coupled model is used to simulate the black carbon (BC) and dust concentrations and their radiative forcing in seasonal snow over North China in January-February of 2010, with extensive field measurements used to evaluate the model performance. In general, the model simulated spatial variability of BC and dust mass concentrations in the top snow layer (hereafter BCS and DSTS, respectively) are quantitatively or qualitatively consistent with observations. The model generally moderately underestimates BCS in the clean regions but significantly overestimates BCS in some polluted regions. Most model results fall into the uncertainty ranges of observations. The simulated BCS and DSTS are highest with >5000 ng g-1 and up to 5 mg g-1, respectively, over the source regions and reduce to <50 ng g-1 and <1 ?g g-1, respectively, in the remote regions. BCS and DSTS introduce similar magnitude of radiative warming (~10 W m-2) in snowpack, which is comparable to the magnitude of surface radiative cooling due to BC and dust in the atmosphere. This study represents the first effort in using a regional modeling framework to simulate BC and dust and their direct radiative forcing in snow. Although a variety of observational datasets have been used to attribute model biases, some uncertainties in the results remain, which highlights the need for more observations, particularly concurrent measurements of atmospheric and snow aerosols and the deposition fluxes of aerosols, in future campaigns.

  14. Separation, Concentration, and Immobilization of Technetium and Iodine from Alkaline Supernate Waste

    SciTech Connect (OSTI)

    James Harvey; Michael Gula

    1998-12-07T23:59:59.000Z

    Development of remediation technologies for the characterization, retrieval, treatment, concentration, and final disposal of radioactive and chemical tank waste stored within the Department of Energy (DOE) complex represents an enormous scientific and technological challenge. A combined total of over 90 million gallons of high-level waste (HLW) and low-level waste (LLW) are stored in 335 underground storage tanks at four different DOE sites. Roughly 98% of this waste is highly alkaline in nature and contains high concentrations of nitrate and nitrite salts along with lesser concentrations of other salts. The primary waste forms are sludge, saltcake, and liquid supernatant with the bulk of the radioactivity contained in the sludge, making it the largest source of HLW. The saltcake (liquid waste with most of the water removed) and liquid supernatant consist mainly of sodium nitrate and sodium hydroxide salts. The main radioactive constituent in the alkaline supernatant is cesium-137, but strontium-90, technetium-99, and transuranic nuclides are also present in varying concentrations. Reduction of the radioactivity below Nuclear Regulatory Commission (NRC) limits would allow the bulk of the waste to be disposed of as LLW. Because of the long half-life of technetium-99 (2.1 x 10 5 y) and the mobility of the pertechnetate ion (TcO 4 - ) in the environment, it is expected that technetium will have to be removed from the Hanford wastes prior to disposal as LLW. Also, for some of the wastes, some level of technetium removal will be required to meet LLW criteria for radioactive content. Therefore, DOE has identified a need to develop technologies for the separation and concentration of technetium-99 from LLW streams. Eichrom has responded to this DOE-identified need by demonstrating a complete flowsheet for the separation, concentration, and immobilization of technetium (and iodine) from alkaline supernatant waste.

  15. Influence of Acidic and Alkaline Waste Solution Properties on Uranium Migration in Subsurface Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; Truex, Michael J.; Qafoku, Nikolla; Wellman, Dawn M.; Resch, Charles T.; Zhong, Lirong

    2013-08-01T23:59:59.000Z

    This study shows that acidic and alkaline wastes co-disposed with uranium into subsurface sediments has significant impact on changes in uranium retardation, concentration, and mass during downward migration. For uranium co-disposal with acidic wastes, significant rapid (i.e., hours) carbonate and slow (i.e., 100s of hours) clay dissolution resulted, releasing significant sediment-associated uranium, but the extent of uranium release and mobility change was controlled by the acid mass added relative to the sediment proton adsorption capacity. Mineral dissolution in acidic solutions (pH 2) resulted in a rapid (< 10 h) increase in aqueous carbonate (with Ca2+, Mg2+) and phosphate and a slow (100s of hours) increase in silica, Al3+, and K+, likely from 2:1 clay dissolution. Infiltration of uranium with a strong acid resulted in significant shallow uranium mineral dissolution and deeper uranium precipitation (likely as phosphates and carbonates) with downward uranium migration of three times greater mass at a faster velocity relative to uranium infiltration in pH neutral groundwater. In contrast, mineral dissolution in an alkaline environment (pH 13) resulted in a rapid (< 10 h) increase in carbonate, followed by a slow (10s to 100s of hours) increase in silica concentration, likely from montmorillonite, muscovite, and kaolinite dissolution. Infiltration of uranium with a strong base resulted in uranium-silicate precipitation (presumed Na-boltwoodite) but also desorption of natural uranium on the sediment due to the high ionic strength solution, or 60% greater mass with greater retardation compared with groundwater. Overall, these results show that acidic or alkaline co-contaminant disposal with uranium can result in complex depth- and time-dependent changes in uranium dissolution/precipitation reactions and uranium sorption, which alter the uranium migration mass, concentration, and velocity.

  16. Atmospheric Radiation Measurement (ARM) Data from Los Angeles, California, to Honolulu, Hawaii for the Marine ARM GPCI Investigation of Clouds (MAGIC) Field Campaign (an AMF2 Deployment)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    From October 2012 through September 2013, the second ARM Mobile Facility (AMF2) was deployed on the container ship Spirit, operated by Horizon Lines, for the Marine ARM GPCI* Investigation of Clouds (MAGIC) field campaign. During approximately 20 round trips between Los Angeles, California, and Honolulu, Hawaii, AMF2 obtained continuous on-board measurements of cloud and precipitation, aerosols, and atmospheric radiation; surface meteorological and oceanographic variables; and atmospheric profiles from weather balloons launched every six hours. During two two-week intensive observational periods in January and July 2013, additional instruments were deployed and balloon soundings were be increased to every three hours. These additional data provided a more detailed characterization of the state of the atmosphere and its daily cycle during two distinctly different seasons. The primary objective of MAGIC was to improve the representation of the stratocumulus-to-cumulus transition in climate models. AMF2 data documented the small-scale physical processes associated with turbulence, convection, and radiation in a variety of marine cloud types.

  17. Wide-band-gap, alkaline-earth-oxide semiconductor and devices utilizing same

    DOE Patents [OSTI]

    Abraham, Marvin M. (Oak Ridge, TN); Chen, Yok (Oak Ridge, TN); Kernohan, Robert H. (Oak Ridge, TN)

    1981-01-01T23:59:59.000Z

    This invention relates to novel and comparatively inexpensive semiconductor devices utilizing semiconducting alkaline-earth-oxide crystals doped with alkali metal. The semiconducting crystals are produced by a simple and relatively inexpensive process. As a specific example, a high-purity lithium-doped MgO crystal is grown by conventional techniques. The crystal then is heated in an oxygen-containing atmosphere to form many [Li].degree. defects therein, and the resulting defect-rich hot crystal is promptly quenched to render the defects stable at room temperature and temperatures well above the same. Quenching can be effected conveniently by contacting the hot crystal with room-temperature air.

  18. Laboratory study on the behaviour of spent AA household alkaline batteries in incineration

    SciTech Connect (OSTI)

    Almeida, Manuel F. [LEPAE, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)], E-mail: mfa@fe.up.pt; Xara, Susana M.; Delgado, Julanda; Costa, Carlos A. [LEPAE, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)

    2009-01-15T23:59:59.000Z

    The quantitative evaluation of emissions from incineration is essential when Life Cycle Assessment (LCA) studies consider this process as an end-of-life solution for some wastes. Thus, the objective of this work is to quantify the main gaseous emissions produced when spent AA alkaline batteries are incinerated. With this aim, batteries were kept for 1 h at 1273 K in a refractory steel tube hold in a horizontal electric furnace with temperature control. At one end of the refractory steel tube, a constant air flow input assures the presence of oxygen in the atmosphere and guides the gaseous emissions to a filter system followed by a set of two bubbler flasks having an aqueous solution of 10% (v/v) nitric acid. After each set of experiments, sulphur, chlorides and metals (As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Tl and Zn) were analyzed in both the solutions obtained from the steel tube washing and from the bubblers. Sulphur, chlorides and metals were quantified, respectively, using barium sulfate gravimetry, the Volhard method and atomic absorption spectrometry (AAS). The emissions of zinc, the most emitted metal, represent about 6.5% of the zinc content in the batteries. Emissions of manganese (whose oxide is the main component of the cathode) and iron (from the cathode collector) are negligible when compared with their amount in AA alkaline batteries. Mercury is the metal with higher volatility in the composition of the batteries and was collected even in the second bubbler flask. The amount of chlorides collected corresponds to about 36% of the chlorine in the battery sleeve that is made from PVC. A considerable part of the HCl formed in PVC plastic sleeve incineration is neutralized with KOH, zinc and manganese oxides and, thus, it is not totally released in the gas. Some of the emissions are predictable through a thermodynamic data analysis at temperatures in the range of 1200-1300 K taking into account the composition of the batteries. This analysis was done for most of potential reactions between components in the batteries as well as between them and the surrounding atmosphere and it reasonably agrees the experimental results. The results obtained show the role of alkaline batteries at the acid gases cleaning process, through the neutralization reactions of some of their components. Therefore, LCA of spent AA alkaline batteries at the municipal solid waste (MSW) incineration process must consider this contribution.

  19. In situ atomic force microscopy imaging of electroprecipitated nickel hydrous oxide films in alkaline electrolytes

    SciTech Connect (OSTI)

    Chen, R.; Mo, Y.; Scherson, D.A. (Case Western Reserve Univ., Cleveland, OH (United States))

    1994-11-01T23:59:59.000Z

    In situ atomic force microscopy images of nickel hydrous oxide films electrodeposited on the basal plane of highly oriented pyrolytic graphite in alkaline electrolytes have shown that a stepwise oxidation leads to irreversible formation of wide crevices throughout the material. Upon subsequent stepwise reduction, the gaps close leaving a hairline type crack which follows the profile of the crevice. These potential induced structural rearrangements have been attributed to stresses induced by differences in the densities of the nickel hydrous oxide in the two oxidation states. 9 refs., 5 figs.

  20. Liquefaction process for solid carbonaceous materials containing alkaline earth metal humates

    DOE Patents [OSTI]

    Epperly, William R. (Summit, NJ); Deane, Barry C. (East Brunswick, NJ); Brunson, Roy J. (Buffalo Grove, IL)

    1982-01-01T23:59:59.000Z

    An improved liquefaction process wherein wall scale and particulate agglomeration during the liquefaction of solid carbonaceous materials containing alkaline earth metal humates is reduced and/or eliminated by subjecting the solid carbonaceous materials to controlled cyclic cavitation during liquefaction. It is important that the solid carbonaceous material be slurried in a suitable solvent or diluent during liquefaction. The cyclic cavitation may be imparted via pressure cycling, cyclic agitation and the like. When pressure cycling or the like is employed an amplitude equivalent to at least 25 psia is required to effectively remove scale from the liquefaction vessel walls.

  1. Pilot Implementation of a Field Study Design to Evaluate the Impact of Source Control Measures on Indoor Air Quality in High Performance Homes

    SciTech Connect (OSTI)

    Widder, Sarah H.; Chamness, Michele A.; Petersen, Joseph M.; Singer, Brett C.; Maddalena, Randy L.; Destaillats, Hugo

    2014-10-20T23:59:59.000Z

    To improve the indoor air quality in new, high performance homes, a variety of standards and rating programs have been introduced to identify building materials that are designed to have lower emission rates of key contaminants of concern and a number of building materials are being introduced that are certified to these standards. For example, the U.S. Department of Energy (DOE) Zero Energy Ready Home program requires certification under the U.S. Environmental Protection Agency (EPA) Indoor airPLUS (IaP) label, which requires the use of PS1 or PS2 certified plywood and OSB; low-formaldehyde emitting wood products; low- or no-VOC paints and coatings as certified by Green Seal Standard GS-11, GreenGuard, SCS Indoor Advantage Gold Standard, MPI Green Performance Standard, or another third party rating program; and Green Label-certified carpet and carpet cushions. However, little is known regarding the efficacy of the IAP requirements in measurably reducing contaminant exposures in homes. The goal of this project is to develop a robust experimental approach and collect preliminary data to support the evaluation of indoor air quality (IAQ) measures linked to IAP-approved low-emitting materials and finishes in new residential homes. To this end, the research team of Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) developed a detailed experimental plan to measure IAQ constituents and other parameters, over time, in new homes constructed with materials compliant with IAP’s low-emitting material and ventilation requirements (i.e., section 6.1, 6.2, 6.3, and 7.2) and similar homes constructed to the state building code with conventional materials. The IAQ in IAP and conventional homes of similar age, location, and construction style is quantified as the differences in the speciated VOC and aldehyde concentrations, normalized to dilution rates. The experimental plan consists of methods to evaluate the difference between low-emitting and “conventional” materials as installed in newly constructed residential homes using both (1) highly controlled, short-term active samples to precisely characterize the building-related chemical emissions and building contents and (2) a week-long passive sample designed to capture the impact of occupant behavior and related activities on measured IAQ contaminant levels indoors. The combination of detailed short-term measurements with the home under controlled/consistent conditions during pre- and post-occupancy and the week-long passive sampling data provide the opportunity to begin to separate the different emission sources and help isolate and quantify variability in the monitored homes. Between April and August 2014, the research team performed pre-occupancy and post-occupancy sampling in one conventional home and two homes built with low-emitting materials that were generally consistent with EPA’s Indoor airPLUS guidelines. However, for a number of reasons, the full experimental plan was not implemented. The project was intended to continue for up to three years to asses long-term changes in IAQ but the project was limited to one calendar year. As a result, several of the primary research questions related to seasonal impacts and the long-term trends in IAQ could not be addressed. In addition, there were several unexpected issues related to recruiting, availability of home types, and difficulty coordinating with builders/realtors/homeowners. Several field monitoring issues also came up that provide “lessons learned” that led to improvements to the original monitoring plan. The project produced a good experimental plan that is expected to be be useful for future efforts collecting data to support answering these same or similar research questions.

  2. Plutonium(IV) precipitates formed in alkaline media in the presence of various anions

    SciTech Connect (OSTI)

    Krot, N.N.; Shilov, V.P.; Yusov, A.B.; Tananaev, I.G.; Grigoriev, M.S.; Garnov, A.Yu.; Perminov, V.P.; Astafurova, L.N.

    1998-09-01T23:59:59.000Z

    The tendency of Pu(IV) to hydrolyze and form true solutions, colloid solutions, or insoluble precipitates has been known since the Manhattan Project. Since then, specific studies have been performed to examine in detail the equilibria of Pu(IV) hydrolytic reactions in various media. Great attention also has been paid to the preparation, structure, and properties of Pu(IV) polymers or colloids. These compounds found an important application in sol-gel technology for the preparation of nuclear fuel materials. A most important result of these works was the conclusion that Pu(IV) hydroxide, after some aging, consists of very small PuO{sub 2} crystallites and should therefore be considered to be Pu(IV) hydrous oxide. However, studies of the properties and behavior of solid Pu(IV) hydroxide in complex heterogeneous systems are rare. The primary goal of this investigation was to obtain data on the composition and properties of Pu(IV) hydrous oxide or other compounds formed in alkaline media under different conditions. Such information is important to understand Pu(IV) behavior and the forms of its existence in the Hanford Site alkaline tank waste sludge. This knowledge then may be applied in assessing plutonium criticality hazards in the storage, retrieval, and treatment of Hanford Site tank wastes as well as in understanding its contribution to the transuranic waste inventory (threshold at 100 nCi/g or about 5 {times} 10{sup {minus}6} M) of the separate solution and solid phases.

  3. Surfactant-enhanced alkaline flooding for light oil recovery. Final report 1994--1995

    SciTech Connect (OSTI)

    Wasan, D.T.

    1995-12-01T23:59:59.000Z

    In this report, the authors present the results of their experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12.0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, the authors have (1) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, (2) investigated the mechanisms for spontaneous emulsification, (3) developed a technique to monitor low water content in oil, and (4) developed a technique to study water-in-oil emulsion film properties, (5) investigated the effect of surfactant on the equilibrium and transient interfacial tension, (6) investigated the kinetics of oil removal from a silica surface, and (7) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, accounting for added surfactant. The results of the studies conducted during the course of this project are summarized.

  4. Surfactant-enhanced alkaline flooding for light oil recovery. Final report

    SciTech Connect (OSTI)

    Wasan, D.T.

    1996-05-01T23:59:59.000Z

    In this report, we present the results of our experimental and theoretical studies in surfactant-enhanced alkaline flooding for light oil recovery. The overall objective of this work is to develop a very cost-effective method for formulating a successful surfactant-enhanced alkaline flood by appropriately choosing mixed alkalis which form inexpensive buffers to obtain the desired pH (between 8.5 and 12. 0) for ultimate spontaneous emulsification and ultralow interfacial tension. In addition, we have (1) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, (2) investigated the mechanisms for spontaneous emulsification, (3) developed a technique to monitor low water content in oil and (4) developed a technique to study water-in-oil emulsion film properties, (5) investigated the effect of surfactant on the equilibrium and transient interfacial tension, (6) investigated the kinetics of oil removal from a silica surface, and (7) developed a theoretical interfacial activity model for determining equilibrium interfacial tension, accounting for added surfactant. The results of the studies conducted during the course of this project are discussed.

  5. As part of its continuing cloud computing series, the National Institute of Standards and Technology is hosting a new forum on Cloud and Mobility. Join experts in the fields of cloud, mobility, and measurement for thought-provoking

    E-Print Network [OSTI]

    and Technology is hosting a new forum on Cloud and Mobility. Join experts in the fields of cloud, mobility sessions, and networking. New Frontiers in IT and Measurement Science Rapid advances in mobile cloud computing are bringing sweeping changes to the way mobile computing and communication services are delivered

  6. Microbial field pilot study

    SciTech Connect (OSTI)

    Knapp, R.M.; McInerney, M.J.; Menzie, D.E.; Coates, J.D.; Chisholm, J.L.

    1993-05-01T23:59:59.000Z

    A multi-well microbially enhanced oil recovery field pilot has been performed in the Southeast Vassar Vertz Sand Unit in Payne County, Oklahoma. The primary emphasis of the experiment was preferential plugging of high permeability zones for the purpose of improving waterflood sweep efficiency. Studies were performed to determine reservoir chemistry, ecology, and indigenous bacteria populations. Growth experiments were used to select a nutrient system compatible with the reservoir that encouraged growth of a group of indigenous nitrate-using bacteria and inhibit growth of sulfate-reducing bacteria. A specific field pilot area behind an active line drive waterflood was selected. Surface facilities were designed and installed. Injection protocols of bulk nutrient materials were prepared to facilitate uniform distribution of nutrients within the pilot area. By the end of December, 1991, 82.5 tons (75.0 tonnes) of nutrients had been injected in the field. A tracer test identified significant heterogeneity in the SEVVSU and made it necessary to monitor additional production wells in the field. The tracer tests and changes in production behavior indicate the additional production wells monitored during the field trial were also affected. Eighty two and one half barrels (13.1 m[sup 3]) of tertiary oil have been recovered. Microbial activity has increased CO[sub 2] content as indicated by increased alkalinity. A temporary rise in sulfide concentration was experienced. These indicate an active microbial community was generated in the field by the nutrient injection. Pilot area interwell pressure interference test results showed that significant permeability reduction occurred. The interwell permeabilities in the pilot area between the injector and the three pilot production wells were made more uniform which indicates a successful preferential plugging enhanced oil recovery project.

  7. Microbial field pilot study

    SciTech Connect (OSTI)

    Chisholm, J.L.

    1992-01-01T23:59:59.000Z

    Studies were performed enhanced oil recovery field pilot was performed in Southeast Vassar Vertz Sand Unit (SEVVSU) in Payne County, Oklahoma. The primary emphasis of the experiment was preferential plugging of high permeability zones for the purpose of improving waterflood sweep efficiency. Studies were performed to determine reservoir chemistry, ecology, and indigenous bacteria populations. Studies were performed to determine a nutrient system to encourage growth of a group of indigenous nitrate-using bacteria an inhibit growth of sulfate-reducing bacteria. A specific field pilot area behind an active line drive waterflood was selected. Surface facilities were designed and installed. Injection protocols of bulk nutrient material were prepared to facilitate uniform distribution of nutrients within the pilot area. By the end of December, 1991, 82.5 tons of nutrients had been injected in the field. A tracer test identified significant heterogeneity in the SEVVSU and made it necessary to monitor an additional production well in the field. The tracer tests and changes in production behavior indicated the additional production well monitored during the field trial was also affected. Eighty two and one half barrels of tertiary oil was recovered. Microbial activity increased CO[sub 2] content as indicated by increased alkalinity. A temporary rise in sulphide concentration was experienced. These observations indicate that an active microbial community was generated in the field by the nutrient injection. The three production wells monitored in the pilot area demonstrated significant permeability reduction indicated by interwell pressure interference tests. The interwell permeabilities in the pilot area between the injector and the three pilot production wells were made more uniform (15 md maximum difference between post-treatment permeability values) indicating that preferential plugging had occurred.

  8. Modification of alkaline pulping to facilitate the isolation of aliphatic acids. Part 1. Sodium hydroxide pretreatment of pine wood

    SciTech Connect (OSTI)

    Alen, R.; Niemelae, K.; Sjoestroem, E.

    1984-01-01T23:59:59.000Z

    Pretreating pine chips (Pinus sylvestris) with sodium hydroxide prior to the alkaline delignification kraft, kraft-anthraquinone, and soda-anthraquinone) can facilitate the recovery of the carbohydrate degradation products from alkaline pulping liquors. Under suitable pretreatment conditions large amounts of carbohydrate degradation products (alipahtic acids) were formed relative to lignin. The lignin fraction was composed of comparatively low-molecular-weight fragments. Although the delignification was considerably retarded and the yield (based on wood) was decreased by 1-3%, the properties of the resulting pulp were essentially maintained despite pretreatment. Finally, data are given for the composition of aliphatic acids in liquors resulting from pretreatments.

  9. Methanol Dehydrogenation and Oxidation on Pt(111) in Alkaline Jacob S. Spendelow, Jason D. Goodpaster, Paul J. A. Kenis, and Andrzej Wieckowski*

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Methanol Dehydrogenation and Oxidation on Pt(111) in Alkaline Solutions Jacob S. Spendelow, Jason D, and oxidation of methanol on Pt(111) in alkaline solutions has been examined from a fundamental mechanistic.COhasbeenconfirmedasthemainpoisoningspecies,affectingtherateofmethanoldehydrogenation primarily through repulsive interactions with methanol dehydrogenation intermediates. At direct methanol

  10. Phase behavior and oil recovery investigations using mixed and alkaline-enhanced surfactant systems

    SciTech Connect (OSTI)

    Llave, F.M.; Gall, B.L.; French, T.R.; Noll, L.A.; Munden, S.A.

    1992-03-01T23:59:59.000Z

    The results of an evaluation of different mixed surfactant and alkaline-enhanced surfactant systems for enhanced oil recovery are described. Several mixed surfactant systems have been studies to evaluate their oil recovery potential as well as improved adaptability to different ranges of salinity, divalent ion concentrations, and temperature. Several combinations of screening methods were used to help identify potential chemical formulations and determine conditions where particular chemical systems can be applied. The effects of different parameters on the behavior of the overall surfactant system were also studied. Several commercially available surfactants were tested as primary components in the mixtures used in the study. These surfactants were formulated with different secondary as well as tertiary components, including ethoxylated and non-ethoxylated sulfonates and sulfates. Improved salinity and hardness tolerance was achieved for some of these chemical systems. The salinity tolerance of these systems were found to be dependent on the molecular weight, surfactant type, and concentration of the surfactant components.

  11. Design and Test of a Carbon-Tolerant Alkaline Fuel Cell

    E-Print Network [OSTI]

    Urquidi-Macdonald, M; Grimes, P; Tewari, A; Sambhy, V; Urquidi-Macdonald, Mirna; Sen, Ayusman; Grimes, Patrick; Tewari, Ashutosh; Sambhy, Varun

    2005-01-01T23:59:59.000Z

    This paper presents new results which may constitute a breakthrough in the effort to develop fuel cells truly suitable for use in cars and trucks. For decades, researchers have known that the alkaline fuel cell (AFC) is much cheaper to make, more efficient and more durable than the more popular PEM fuel cell; however, "carbon poisoning" (either from CO2 in air or from contaminants in reformed methanol) causes big problems in the kind of oxygen-hydrogen AFC commonly used in space. This paper reports successful tests of a technique for coating the electrodes with polystyrene which, in conjunction with older common-sense techniques, appears to solve the problem. This kind of design is applicable to cars run on hydrogen fuel, on reformed methanol or even direct methanol. Developing a test methodology was a major part of the work. A foreword by one of the sponsors at NSF discusses the larger importance of this work for energy security and the environment.

  12. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  13. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-24T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  14. Bull. Soc. gol. Fr., 2008, no The alkaline intraplate volcanism of the Antalya nappes (Turkey): a Late

    E-Print Network [OSTI]

    Demouchy, Sylvie

    Bull. Soc. géol. Fr., 2008, no 4 The alkaline intraplate volcanism of the Antalya nappes (Turkey-words. ­ Alkali basalt, Intraplate volcanism, Triassic (Upper), Neotethys, Turkey, Geochemistry. Abstract. ­ Late belonging to the Kara Dere ­ Sayrun unit of the Middle Antalya nappes, southwestern Turkey. New

  15. Historical and Short-Term Controls on Sulfate Reduction and Alkalinity Generation in Three Aquatic Ecosystems of

    E-Print Network [OSTI]

    Vallino, Joseph J.

    precipitation, pyrite, sediments #12;Introduction First described as acid rain in 1852 by Scottish chemist Angus.19 to 13.47 mEq m-2 y-1 in freshwater sediments. Keywords: Sulfate reduction, alkalinity, acid Smith, all forms of atmospheric acid deposition continue to be an environmental problem faced

  16. Simultaneous precipitation of magnesite and lizardite from1 hydrothermal alteration of olivine under high-carbonate alkalinity2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    under high-carbonate alkalinity2 3 Romain Lafaya, b , German Montes-Hernandeza, *, Emilie Janotsb experiments in order to investigate the simultaneous25 serpentinization and carbonation of olivine-situ and in-situ mineral sequestration of27 CO2). For this case, specific experimental conditions were

  17. An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao*

    E-Print Network [OSTI]

    Zhao, Tianshou

    An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao the performance of anion exchange membrane (AEM) direct ethanol fuel cells (DEFCs) is that state-of-the-art AEMs exchange membrane direct ethanol fuel cells (AEM- DEFCs) have received ever-increasing attention, mainly

  18. Oscillatory Increases in Alkalinity Anticipate Growth and May Regulate Actin Dynamics in Pollen Tubes of Lily W OA

    E-Print Network [OSTI]

    Kunkel, Joseph G.

    with a low concentration of the pH-sensitive dye bis-carboxyethyl carboxyfluorescein dextran, show of Massachusetts, Amherst, Massachusetts 01003 b Integrative Cell Biology Laboratory, Durham University, Durham DH1 alkalinity and cell extension. A target for pH may be the actin cytoskeleton, because the apical cortical

  19. Geometric frequency shift for electric dipole searches with trapped spin-1/2 particles in general fields and measurement cells of arbitrary shape with smooth or rough walls

    E-Print Network [OSTI]

    Steyerl, A; Müller, G; Golub, R

    2015-01-01T23:59:59.000Z

    The important role of geometric phases in searches for a permanent electric dipole moment of the neutron, using Ramsey separated oscillatory field nuclear magnetic resonance, was first investigated by Pendlebury $\\textit{et al.}$ [Phys. Rev. A $\\mathbf{70}$, 032102 (2004)]. Their analysis was based on the Bloch equations. In subsequent work using the spin density matrix Lamoreaux and Golub [Phys. Rev. A $\\mathbf{71}$, 032104 (2005)] showed the usual relation between the frequency shifts and the correlation functions of the fields seen by trapped particles in general fields (Redfield theory). More recently we presented a solution of the Schr\\"odinger equation for spin-$1/2$ particles in circular cylindrical traps with smooth walls and exposed to arbitrary fields [Steyerl $\\textit{et al.}$, Phys.Rev. A $\\mathbf{89}$, 052129 (2014)]. Here we extend this work to show how the Redfield theory follows directly from the Schr\\"odinger equation solution and include wall roughness, cylindrical trap geometry with arbitra...

  20. From Measure Theory to CTMDPs Martin Neuhauer

    E-Print Network [OSTI]

    Ábrahám, Erika

    ;Introduction to Measure Theory Basic Definitions Measure Theory Our Setting Assume a set , called sample space to CTMDPs November 9th, 2006 3 / 1 #12;Introduction to Measure Theory Basic Definitions Fields and ­fields / 1 #12;Introduction to Measure Theory Basic Definitions Fields and ­fields Definition (Field) A class

  1. Geometric frequency shift for electric dipole searches with trapped spin-1/2 particles in general fields and measurement cells of arbitrary shape with smooth or rough walls

    E-Print Network [OSTI]

    A. Steyerl; C. Kaufman; G. Müller; R. Golub

    2015-05-13T23:59:59.000Z

    The important role of geometric phases in searches for a permanent electric dipole moment of the neutron, using Ramsey separated oscillatory field nuclear magnetic resonance, was first investigated by Pendlebury $\\textit{et al.}$ [Phys. Rev. A $\\mathbf{70}$, 032102 (2004)]. Their analysis was based on the Bloch equations. In subsequent work using the spin density matrix Lamoreaux and Golub [Phys. Rev. A $\\mathbf{71}$, 032104 (2005)] showed the usual relation between the frequency shifts and the correlation functions of the fields seen by trapped particles in general fields (Redfield theory). More recently we presented a solution of the Schr\\"odinger equation for spin-$1/2$ particles in circular cylindrical traps with smooth walls and exposed to arbitrary fields [Steyerl $\\textit{et al.}$, Phys.Rev. A $\\mathbf{89}$, 052129 (2014)]. Here we extend this work to show how the Redfield theory follows directly from the Schr\\"odinger equation solution and include wall roughness, cylindrical trap geometry with arbitrary cross section, and field perturbations that do not, in the frame of the moving particles, average to zero in time and which, therefore, do not satisfy the prerequisites of the statistical approach based on the spin-density matrix. We show by direct, detailed, calculation the agreement of the results from the Schr\\"odinger equation with the Redfield theory for the cases of a rectangular cell with specular walls and of a circular cell with diffuse reflecting walls.

  2. UONPR No. 1, Elk Hills, 26R Reservoir, Elk Hills oil and gas field, Kern County, California: Management Review: Surface operations and measurements of production and injection volumes

    SciTech Connect (OSTI)

    Not Available

    1987-01-01T23:59:59.000Z

    Evans, Carey and Crozier was given the task to conduct a Management Review of the Surface Operations of the 26R Reservoir in UONPR No. 1, Elk Hills field, Kern County, California. The MER strategy for this reservoir is to maintain pressure, and toward this end, gas injection volumes are scheduled to amount to 110% of calculated withdrawals. In spite of this, however, reservoir pressure continues to decline. The purpose of this study was, therefore, to determine if, and to what extent, field operating practices and accounting procedures may be contributing to this dilemma and to make appropriate recommendations pertaining to correcting any deficiencies which may have been found.

  3. Quantum-state measurement of two-mode entangled field-state in a high-Q cavity RID C-6638-2008

    E-Print Network [OSTI]

    Khosa, A. H.; Zubairy, M. Suhail

    2005-01-01T23:59:59.000Z

    vacuum Rabi frequencies asso- ciated with the cavity mode A and B#4; can be expressed as a function of a one wave vector and one coupling constant. We obtain this by defining kA=#11;kB, and gA=#12;gB, where #11; and #12; are dimensionless constants... field-state from the recorded momentum distribution. From Eq. #1;20#2; it is also clear that the separation between the peaks of the momentum spectrum depends on the parameters of the atom-field interaction, especially #17;, which contains the vacuum...

  4. Measurement of two-dimensional concentration fields of a glycol-based tracer aerosol using laser light sheet illumination and microcomputer video image acquisition and processing

    E-Print Network [OSTI]

    Revi, Frank

    1992-01-01T23:59:59.000Z

    The use of a tracer aerosol with a bulk density close to that of air is a convenient way to study the dispersal of pollutants in ambient room air flow. Conventional point measurement techniques do not permit the rapid and ...

  5. Aerosol plume transport and transformation in high spectral resolution lidar measurements and WRF-Flexpart simulations during the MILAGRO Field Campaign

    E-Print Network [OSTI]

    de Foy, B.

    The Mexico City Metropolitan Area (MCMA) experiences high loadings of atmospheric aerosols from anthropogenic sources, biomass burning and wind-blown dust. This paper uses a combination of measurements and numerical ...

  6. Thermal treatment for recovery of manganese and zinc from zinc-carbon and alkaline spent batteries

    SciTech Connect (OSTI)

    Belardi, G. [Institute for Environmental Engineering and Geosciences (CNR) Area della Ricerca CNR, via Salaria km 29,300, Monterotondo, 00016 Rome (Italy); Lavecchia, R.; Medici, F. [Department of Chemical Engineering, Materials and Environment, Sapienza University of Rome, via Eudossiana 84, 00184 Rome (Italy); Piga, L., E-mail: luigi.piga@uniroma1.it [Department of Chemical Engineering, Materials and Environment, Sapienza University of Rome, via Eudossiana 84, 00184 Rome (Italy)

    2012-10-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer We separated Zn from Mn in zinc-carbon and alkaline batteries after removal of Hg. Black-Right-Pointing-Pointer Almost total removal of Hg is achieved at low temperature in air. Black-Right-Pointing-Pointer Nitrogen atmosphere is needed to reduce zinc and to permit its volatilization. Black-Right-Pointing-Pointer A high grade Zn concentrate was obtained with a high recovery at 1000-1200 Degree-Sign C. Black-Right-Pointing-Pointer The grade of Mn in the residue was enhanced with complete recovery. - Abstract: The aim of this paper is the recovery of manganese and zinc from a mixture of zinc-carbon and alkaline spent batteries, containing 40.9% of Mn and 30.1% of Zn, after preliminary physical treatment followed by removal of mercury. Separation of the metals has been carried out on the basis of their different boiling points, being 357 Degree-Sign C and 906 Degree-Sign C the boiling point of mercury and zinc and 1564 Degree-Sign C the melting point of Mn{sub 2}O{sub 3}. Characterization by chemical analysis, TGA/DTA and X-ray powder diffraction of the mixture has been carried out after comminution sieving and shaking table treatment to remove the anodic collectors and most of chlorides contained in the mixture. The mixture has been roasted at various temperatures and resident times in a flow of air to set the best conditions to remove mercury that were 400 Degree-Sign C and 10 min. After that, the flow of air has been turned into a nitrogen one (inert atmosphere) and the temperatures raised, thus permitting the zinc oxide to be reduced to metallic zinc by the carbon present in the original mixture and recovered after volatilization as a high grade concentrate, while manganese was left in the residue. The recovery and the grade of the two metals, at 1000 Degree-Sign C and 30 min residence time, were 84% and 100% for zinc and 85% and 63% for manganese, respectively. The recovery of zinc increased to 99% with a grade of 97% at 1200 Degree-Sign C and 30 min residence time, while the recovery and grade of manganese were 86% and 87%, respectively, at that temperature. Moreover, the chlorinated compounds that could form by the combustion of the plastics contained in the spent batteries, are destroyed at the temperature required by the process.

  7. A new method of measuring the poloidal magnetic and radial electric fields in a tokamak using a laser-accelerated ion-beam trace probe

    SciTech Connect (OSTI)

    Yang, X. Y.; Chen, Y. H.; Lin, C.; Wang, X. G.; Xiao, C. J., E-mail: cjxiao@pku.edu.cn [State Key Labaratory of Nuclear Physics and Technology, School of Physics, Peking University, Beijing 100871 (China); Wang, L. [Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100190 (China); Xu, M. [Center for Fusion Science of Southwestern Institute of Physics, P.O. Box 432, Chengdu 610041 (China)

    2014-11-15T23:59:59.000Z

    Both the poloidal magnetic field (B{sub p}) and radial electric field (E{sub r}) are significant in magnetic confinement devices. In this paper, a new method was proposed to diagnose both B{sub p} and E{sub r} at the same time, which was named Laser-accelerated Ion-beam Trace Probe (LITP). This method based on the laser-accelerated ion beam, which has three properties: large energy spread, short pulse lengths, and multiple charge states. LITP can provide the 1D profiles, or 2D images of both B{sub p} and E{sub r}. In this paper, we present the basic principle and some preliminary theoretical results.

  8. Comparative Analysis of the Effect of Different Alkaline Catalysts on Biodiesel Yield

    E-Print Network [OSTI]

    Cynthia Ofori-boateng; Ebenezer M. Kwofie; Moses Y. Mensah

    Abstract: A major challenge in the biodiesel industry is the comparatively high cost of raw materials for production. A cost build-up analysis of biodiesel production from J. curcas oil shows that catalyst alone contributes about 50.9 % of the total production cost. This paper aims at highlighting the effects of two different commonly used catalysts on the yield of biodiesel. Samples of biodiesel were produced by three different methods namely single stage transesterification (SST), double stage transesterification (DST) and foolproof (FP) processes in which sodium hydroxide (NaOH) and potassium hydroxide (KOH) were used. The effects of each catalyst on the production yield were analyzed and compared. NaOH gave production yields of 79%, 81% and 84 % for the SST, DST and FP processes respectively. KOH produced comparatively lower yields of 68%, 71 % and 75 % for SST, DST and fool proof processes respectively. Although the use of KOH slightly raises the cost of biodiesel production as compared to NaOH, the local production of KOH from cocoa husks could minimize the production cost. Abbreviations: BDF = Biodiesel fuel; PDF = Petroleum diesel fuel; DF = Diesel fuel Key words: Transesterification Alkaline catalysts Biodiesel yield Biodiesel KOH NaOH

  9. Geochemical Rate/RNA Integration Study (GRIST): A Pilot Field Experiment for Inter-Calibration of Biogeochemistry and Nucleic Acid Measurements Final Report

    SciTech Connect (OSTI)

    Bronk, Deborah

    2007-01-08T23:59:59.000Z

    The Geochemical Rate/RNA Integration Study (GRIST) project sought to correlate biogeochemical flux rates with measurements of gene expression and mRNA abundance to demonstrate the application of molecular approaches to estimate the presence and magnitude of a suite of biogeochemical processes. The study was headed by Lee Kerkhoff of Rutgers University. In this component of the GRIST study, we characterized ambient nutrient concentrations and measured uptake rates for dissolved inorganic nitrogen (DIN, ammonium, nitrate and nitrite) and dissolved organic nitrogen (urea and dissolved free amino acids) during two diel studies at the Long-Term Ecosystem Observatory (LEO-15) on the New Jersey continental shelf.

  10. Methods of use of calcium hexa aluminate refractory linings and/or chemical barriers in high alkali or alkaline environments

    DOE Patents [OSTI]

    McGowan, Kenneth A; Cullen, Robert M; Keiser, James R; Hemrick, James G; Meisner, Roberta A

    2013-10-22T23:59:59.000Z

    A method for improving the insulating character/and or penetration resistance of a liner in contact with at least one of an alkali and/or alkaline environments is provided. The method comprises lining a surface that is subject to wear by an alkali environment and/or an alkaline environment with a refractory composition comprising a refractory aggregate consisting essentially of a calcium hexa aluminate clinker having the formula CA.sub.6, wherein C is equal to calcium oxide, wherein A is equal to aluminum oxide, and wherein the hexa aluminate clinker has from zero to less than about fifty weight percent C.sub.12A.sub.7, and wherein greater than 98 weight percent of the calcium hexa aluminate clinker having a particle size ranging from -20 microns to +3 millimeters, for forming a liner of the surface. This method improves the insulating character/and or penetration resistance of the liner.

  11. Version 3.01 SOP 3b --Total alkalinity (open cell) July 1, 2008 Page 1 of 1

    E-Print Network [OSTI]

    is monitored using a pH glass electrode/reference electrode cell, and the total alkalinity is computed from to weigh1 200 g to within 0.01 g, · 125 cm3 plastic screw-cap bottle with cap. 4.2 Titration cell assembly system. The system is used to buffer the e.m.f. of the combination pH glass electrode/reference electrode

  12. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13T23:59:59.000Z

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  13. The etching process of boron nitride by alkali and alkaline earth fluorides under high pressure and high temperature

    SciTech Connect (OSTI)

    Guo, W., E-mail: guowei1982cry@163.com [College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024 (China); National Key Lab of Superhard Materials, Jilin University, Changchun 130012 (China); Ma, H.A.; Jia, X. [National Key Lab of Superhard Materials, Jilin University, Changchun 130012 (China)

    2014-03-01T23:59:59.000Z

    Graphical abstract: - Highlights: • Appropriate etch processes of hBN and cBN under HPHT are proposed. • The degree of the crystallization of hBN was decreased. • A special cBN growth mechanism with a triangular unit is proposed. • Plate-shape cBN crystals with large ratio of length to thickness were obtained. • A strategy provides useful guidance for controlling the cBN morphology. - Abstract: Some new etching processes of hexagonal boron nitride (hBN) and cubic boron nitride (cBN) under high pressure and high temperature in the presence of alkali and alkaline earth fluorides have been discussed. It is found that hBN is etched distinctly by alkali and alkaline earth fluorides and the morphology of hBN is significantly changed from plate-shape to spherical-shape. Based on the “graphitization index” values of hBN, the degree of the crystallization of hBN under high pressure and high temperature decreases in the sequence of LiF > CaF{sub 2} > MgF{sub 2}. This facilitates the formation of high-quality cBN single crystals. Different etch steps, pits, and islands are observed on cBN surface, showing the strong etching by alkali and alkaline earth fluorides and the tendency of layer-by-layer growth. A special layer growth mechanism of cBN with a triangular unit has been found. Furthermore, the morphologies of cBN crystals are apparently affected by a preferential surface etching of LiF, CaF{sub 2} and MgF{sub 2}. Respectively, the plate-shape and tetrahedral cBN crystals can be obtained in the presence of different alkali and alkaline earth fluorides.

  14. Dedicated to Sharing Information About Water Management and the Florida LAKEWATCH Program Volume 66 (2014) Total Color and Total Alkalinity Analysis

    E-Print Network [OSTI]

    Jawitz, James W.

    Volume 66 (2014) Florida LAKEWATCH Total Color and Total Alkalinity Analysis Recently on total phosphorus, total nitrogen and chlorophyll were similar between equivalent to FDEP's, which were collected using stringent quality assurance (QA

  15. Measurement-Measurement-

    E-Print Network [OSTI]

    Jeong, Jaehoon "Paul"

    Internet Measurement- System A Measurement- System B Control System GPS Satellite GPS Satellite GPS Receiver GPS Receiver 2) measurement 3) data1) command Methodology for One-way IP Performance Measurement This paper proposes a methodology for measurement of one-way IP performance metrics such as one-way delay

  16. Study of electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten as hydrogen electrodes in alkaline water electrolysis

    SciTech Connect (OSTI)

    Fan, C.; Piron, D.L.; Sleb, A.; Paradis, P. (Ecole Polytechnique de Montreal, Quebec (Canada). Dept. de Metallurgie et de Genie des Materiaux)

    1994-02-01T23:59:59.000Z

    Electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten were characterized for the hydrogen evolution reaction (HER) in the electrolysis of 30 w/o KOH alkaline water at 25 C. The rate-determining step (rds) of the HER was suggested based on the Tafel slope of polarization and the capacitance of electrode-solution interface determined by ac impedance measurement. The HER on the nickel- and cobalt-based codeposits was enhanced significantly compared with that o the electrolytic nickel and cobalt with comparable deposit loadings. The decrease in the HER overpotential was more pronounced on the molybdenum-containing codeposits, particularly on cobalt-molybdenum which also showed a high stability. The enhancement of the HER was attributed to both the synergetic composition and the increased active surface of the codeposits. The real electrocatalytic activity of te electrodes and the effect of their and the increased active surface of the codeposits. The real electrocatalytic activity of the electrodes and the effect of their surface increase were distinguished quantitatively. The linear relations between HER overpotential and surface roughness factor of the electrodes on a Y-log(X) plot were obtained experimentally and interpreted based on the Tafel law.

  17. Deltaic sedimentation in saline, alkaline Lake Bogoria, Kenya: Response to environmental change

    SciTech Connect (OSTI)

    Renaut, R.W. (Univ. of Saskatchewan, Saskatoon (Canada). Dept. of Geological Sciences); Tiercelin, J.J. (Univ. Bretagne Occidentale, Brest (France). Domaines Oceaniques)

    1993-03-01T23:59:59.000Z

    Lake Bogoria is a meromictic, saline (90 g/l TDS), alkaline (pH: 10.3) lake with Na-CO[sub 3]-Cl waters, located in a narrow half-graben in the central Kenya Rift. It is fed by hot springs, direct precipitation, and a series of ephemeral streams that discharge into the lake via small deltas and fan-deltas. Examination of the exposed deltas and >50 short cores from the lake floor, have revealed a wide range of deltaic and prodeltaic sediments, including turbidites and subaqueous debris-flow deposits. Studies of 3 long cores and the exposed delta stratigraphy have shown how the style of deltaic sedimentation has responded to environmental changes during the last 30,000 years. During humid periods when lake level is high the lake waters are fresher and less dense. Theoretically, high sediment yield and more constant discharge may promote underflow (hyperpycnal flow), generating low-density turbidity currents. In contrast, during low stages with dense brine, the less dense, inflowing waters carry fine sediment plumes toward the center of the lake where they settle from suspension (hypopycnal flow). Although applicable as a general model, the sediment record shows that reality is more complex. Variations in meromixis and level of the chemocline, together with local and temporal differences in sediment yield and discharge, may permit density flows even when the lake is under a predominant hypopycnal regime. During periods of aridity when sodium carbonate evaporites were forming, exposed delta plains were subject to desiccation with local development of calcrete and zeolitic paleosols.

  18. Americium/Lanthanide Separations in Alkaline Solutions for Advanced Nuclear Fuel Cycles

    SciTech Connect (OSTI)

    Goff, George S. [Los Alamos National Laboratory; Long, Kristy Marie [Los Alamos National Laboratory; Reilly, Sean D. [Los Alamos National Laboratory; Jarvinen, Gordon D. [Los Alamos National Laboratory; Runde, Wolfgang H. [Los Alamos National Laboratory

    2012-06-11T23:59:59.000Z

    Project goals: Can used nuclear fuel be partitioned by dissolution in alkaline aqueous solution to give a solution of uranium, neptunium, plutonium, americium and curium and a filterable solid containing nearly all of the lanthanide fission products and certain other fission products? What is the chemistry of Am/Cm/Ln in oxidative carbonate solutions? Can higher oxidation states of Am be stabilized and exploited? Conclusions: Am(VI) is kinetically stable in 0.5-2.0 M carbonate solutions for hours. Aliquat 336 in toluene has been successfully shown to extract U(VI) and Pu(VI) from carbonate solutions. (Stepanov et al 2011). Higher carbonate concentration gives lower D, SF{sub U/Eu} for = 4 in 1 M K{sub 2}CO{sub 3}. Experiments with Am(VI) were unsuccessful due to reduction by the organics. Multiple sources of reducing organics...more optimization. Reduction experiments of Am(VI) in dodecane/octanol/Aliquat 336 show that after 5 minutes of contact, only 30-40% of the Am(VI) has been reduced. Long enough to perform an extraction. Shorter contact times, lower T, and lower Aliquat 336 concentration still did not result in any significant extraction of Am. Anion exchange experiments using a strong base anion exchanger show uptake of U(VI) with minimal uptake of Nd(III). Experiments with Am(VI) indicate Am sorption with a Kd of 9 (10 minute contact) but sorption mechanism is not yet understood. SF{sub U/Nd} for = 7 and SF{sub U/Eu} for = 19 after 24 hours in 1 M K{sub 2}CO{sub 3}.

  19. Probing shell structure and shape changes in neutron-rich sulfur isotopes through transient-field g factor measurements on fast radioactive beams of 38S and 40S

    E-Print Network [OSTI]

    A. D. Davies; A. E. Stuchbery; P. F. Mantica; P. M. Davidson; A. N. Wilson; A. Becerril; B. A. Brown; C. M. Campbell; J. M. Cook; D. C. Dinca; A. Gade; S. N. Liddick; T. J. Mertzimekis; W. F. Mueller; J. R. Terry; B. E. Tomlin; K. Yoneda; H. Zwahlen

    2006-02-23T23:59:59.000Z

    The shell structure underlying shape changes in neutron-rich nuclei near N=28 has been investigated by a novel application of the transient field technique to measure the first-excited state g factors in 38S and 40S produced as fast radioactive beams. There is a fine balance between proton and neutron contributions to the magnetic moments in both nuclei. The g factor of deformed 40S does not resemble that of a conventional collective nucleus because spin contributions are more important than usual.

  20. The use of wireline pressure measurements to refine reservoir description, Main Body B waterflood, Elk Hills oil field, Kern County, California

    SciTech Connect (OSTI)

    Wilson, M. (Bechtel Petroleum Operations, Inc., Tupman, CA (United States)); Love, C. (Scientific Software Intercomp, Bakersfield, CA (United States)); Fishburn, M. (Dept. of Energy, Los Angeles, CA (United States)); Humphrey, M. (Chevron, USA, San Ramon, CA (United States))

    1991-02-01T23:59:59.000Z

    The Main Body B, one of five large Stevens sand reservoirs at Elk Hills, occupies the eastern half of the 31S anticline. Early in the production history of this reservoir, the Elk Hills unit initiated peripheral water injection to maintain reservoir pressure. Water injection has proceeded at a rate approximately equal to the voidage created by oil and gas production and has moved water upstructure creating an oil bank. Bechtel Petroleum Operations Inc., the current unit operator, drills five to ten new wells each year to fully exploit this oil bank. In 1985, the unit added wireline pressure measurements to the open-hole logging programs of these infill wells for the purpose of evaluating the net effect of injection into and production from the Main Body B reservoir. A typical well provides the opportunity to obtain 8-10 pressures from the Main Body B. To date, the Unit has measured wireline pressures in more than two dozen wells. The wireline measurements have shown a broader than expected range of formation pressures (1,600 {plus minus} psi to 4,200 {plus minus} psi). The pressures show that this is a layered reservoir with little vertical pressure communication between some of the layers. In some parts of the reservoir, wireline pressures indicate horizontal continuity of the layers between wells and in other areas pressure differences between adjacent wells may indicate faults or cementation barriers. Permeabilities calculated from the sampling drawdown are the same order of magnitude as brine permeabilities obtained from core and show that higher-pressured layers of the reservoir have lower permeability. These observations fundamentally alter performance evaluation of the Main Body B waterflood.

  1. In-situ measurement of ethanol tolerance in an operating fuel cell

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    In-situ measurement of ethanol tolerance in an operating fuel cell Matt S. Naughton a , Claire E online xxx Keywords: Alkaline fuel cell Gas diffusion electrodes Ag cathode Electrode characterization for direct ethanol fuel cells and as a source for on-demand production of hydrogen in portable applications

  2. Charge exchange neutral particle measurements with natural diamond detector under the deuterium-deuterium neutron field on JT-60U tokamak

    SciTech Connect (OSTI)

    Ishikawa, M.; Kusama, Y.; Takechi, M.; Nishitani, T.; Morioka, A.; Sasao, M.; Isobe, M.; Krasilnikov, A.; Kaschuck, Yu. A. [Japan Atomic Energy Research Institute, Naka-machi, Naka-gun, Ibaraki 319-0193 (Japan); Tohoku University, Sendai-shi, Miyagi 980-8578 (Japan); National Institute for Fusion Science, Toki, Gihu 509-5292 (Japan); Troitsk Institute of Innovating and Fusion Research (TRINITI) Troitsk, Moscow Region 142092 (Russian Federation)

    2004-10-01T23:59:59.000Z

    A natural diamond detector (NDD) has been installed on the JT-60U tokamak to measure the flux and the energy distribution of charge exchange (CX) fast neutral particles. A NDD has many important advantages to be used as a CX neutral particle analyzer, for example very compact size, high energy resolution, and high radiation hardness etc., while the neutrons and {gamma} rays are a large noise source in the deuterium plasma. The shield was set up around the NDD to reduce those noises. Time-resolved energy distribution of CX neutral particles corresponding to injected beam energy have been successfully obtained under high intensity neutron yield Y{sub n}>10{sup 15} n/s. Further enhanced neutral particle fluxes during sawtooth oscillation and Alfven eigenmodes were observed with the NDD. The performance of the NDD as CX neutral particle spectrometer under high intensity neutron yield was demonstrated for the first time on JT-60U in this work.

  3. Large area graphene ion sensitive field effect transistors with tantalum pentoxide sensing layers for pH measurement at the Nernstian limit

    SciTech Connect (OSTI)

    Fakih, Ibrahim, E-mail: ibrahim.fakih@mail.mcgill.ca; Sabri, Shadi; Szkopek, Thomas, E-mail: thomas.szkopek@mcgill.ca [Department of Electrical and Computer Engineering, McGill University, Montreal, Quebec H3A 2A7 (Canada); Mahvash, Farzaneh [Department of Electrical and Computer Engineering, McGill University, Montreal, Quebec H3A 2A7 (Canada); Département de Chimie et Biochimie, Universite du Québec à Montréal, Montreal, Quebec H3C 3P8 (Canada); Nannini, Matthieu [McGill Nanotools Microfab, McGill University, Montreal, Quebec H3A 2A7 (Canada); Siaj, Mohamed [Département de Chimie et Biochimie, Universite du Québec à Montréal, Montreal, Quebec H3C 3P8 (Canada)

    2014-08-25T23:59:59.000Z

    We have fabricated and characterized large area graphene ion sensitive field effect transistors (ISFETs) with tantalum pentoxide sensing layers and demonstrated pH sensitivities approaching the Nernstian limit. Low temperature atomic layer deposition was used to deposit tantalum pentoxide atop large area graphene ISFETs. The charge neutrality point of graphene, inferred from quantum capacitance or channel conductance, was used to monitor surface potential in the presence of an electrolyte with varying pH. Bare graphene ISFETs exhibit negligible response, while graphene ISFETs with tantalum pentoxide sensing layers show increased sensitivity reaching up to 55?mV/pH over pH 3 through pH 8. Applying the Bergveld model, which accounts for site binding and a Guoy-Chapman-Stern picture of the surface-electrolyte interface, the increased pH sensitivity can be attributed to an increased buffer capacity reaching up to 10{sup 14} sites/cm{sup 2}. ISFET response was found to be stable to better than 0.05 pH units over the course of two weeks.

  4. Toxicity mitigation and solidification of municipal solid waste incinerator fly ash using alkaline activated coal ash

    SciTech Connect (OSTI)

    Ivan Diaz-Loya, E. [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Allouche, Erez N., E-mail: allouche@latech.edu [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States); Eklund, Sven; Joshi, Anupam R. [Department of Chemistry, Louisiana Tech University, Ruston, LA 71272 (United States); Kupwade-Patil, Kunal [Alternative Cementitious Binders Laboratory (ACBL), Department of Civil Engineering, Louisiana Tech University, Ruston, LA 71272 (United States)

    2012-08-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Incinerator fly ash (IFA) is added to an alkali activated coal fly ash (CFA) matrix. Black-Right-Pointing-Pointer Means of stabilizing the incinerator ash for use in construction applications. Black-Right-Pointing-Pointer Concrete made from IFA, CFA and IFA-CFA mixes was chemically characterized. Black-Right-Pointing-Pointer Environmentally friendly solution to IFA disposal by reducing its toxicity levels. - Abstract: Municipal solid waste (MSW) incineration is a common and effective practice to reduce the volume of solid waste in urban areas. However, the byproduct of this process is a fly ash (IFA), which contains large quantities of toxic contaminants. The purpose of this research study was to analyze the chemical, physical and mechanical behaviors resulting from the gradual introduction of IFA to an alkaline activated coal fly ash (CFA) matrix, as a mean of stabilizing the incinerator ash for use in industrial construction applications, where human exposure potential is limited. IFA and CFA were analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD) and Inductive coupled plasma (ICP) to obtain a full chemical analysis of the samples, its crystallographic characteristics and a detailed count of the eight heavy metals contemplated in US Title 40 of the Code of Federal Regulations (40 CFR). The particle size distribution of IFA and CFA was also recorded. EPA's Toxicity Characteristic Leaching Procedure (TCLP) was followed to monitor the leachability of the contaminants before and after the activation. Also images obtained via Scanning Electron Microscopy (SEM), before and after the activation, are presented. Concrete made from IFA, CFA and IFA-CFA mixes was subjected to a full mechanical characterization; tests include compressive strength, flexural strength, elastic modulus, Poisson's ratio and setting time. The leachable heavy metal contents (except for Se) were below the maximum allowable limits and in many cases even below the reporting limit. The leachable Chromium was reduced from 0.153 down to 0.0045 mg/L, Arsenic from 0.256 down to 0.132 mg/L, Selenium from 1.05 down to 0.29 mg/L, Silver from 0.011 down to .001 mg/L, Barium from 2.06 down to 0.314 mg/L and Mercury from 0.007 down to 0.001 mg/L. Although the leachable Cd exhibited an increase from 0.49 up to 0.805 mg/L and Pd from 0.002 up to 0.029 mg/L, these were well below the maximum limits of 1.00 and 5.00 mg/L, respectively.

  5. Interaction of Pu(IV,VI) hydroxides/oxides with metal hydroxides/oxides in alkaline media

    SciTech Connect (OSTI)

    Fedoseev, A.M.; Krot, N.N.; Budantseva, N.A.; Bessonov, A.A.; Nikonov, M.V.; Grigoriev, M.S.; Garnov, A.Y.; Perminov, V.P.; Astafurova, L.N. [Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Physical Chemistry

    1998-08-01T23:59:59.000Z

    The primary goal of this investigation was to obtain data on the possibility, extent, and characteristics of interaction of Pu(IV) and (VI) with hydroxides and oxides of d-elements and other metals [Al(III), LA(III), and U(VI)] in alkaline media. Such information is important in fundamental understanding of plutonium disposition and behavior in Hanford Site radioactive tank waste sludge. These results supply essential data for determining criticality safety and in understanding transuranic waste behavior in storage, retrieval, and treatment of Hanford Site tank waste.

  6. Chemically and compositionally modified solid solution disordered multiphase nickel hydroxide positive electrode for alkaline rechargeable electrochemical cells

    DOE Patents [OSTI]

    Ovshinsky, Stanford R. (Bloomfield Hills, MI); Corrigan, Dennis (Troy, MI); Venkatesan, Srini (Southfield, MI); Young, Rosa (Troy, MI); Fierro, Christian (Troy, MI); Fetcenko, Michael A. (Rochester Hills, MI)

    1994-01-01T23:59:59.000Z

    A high capacity, long cycle life positive electrode for use in an alkaline rechargeable electrochemical cell comprising: a solid solution nickel hydroxide material having a multiphase structure that comprises at least one polycrystalline .gamma.-phase including a polycrystalline .gamma.-phase unit cell comprising spacedly disposed plates with at least one chemical modifier incorporated around the plates, the plates having a range of stable intersheet distances corresponding to a 2.sup.+ oxidation state and a 3.5.sup.+, or greater, oxidation state; and at least one compositional modifier incorporated into the solid solution nickel hydroxide material to promote the multiphase structure.

  7. Experimental investigation of sand consolidation using high-temperature alkaline solution

    E-Print Network [OSTI]

    Moreno Romero, Fidel Enrique

    2000-01-01T23:59:59.000Z

    generated at an oil field undergoing steamflooding using either local ground or surface sources of water. The chemistry of feedwater at a steam generator facility is, therefore, field dependent. The process of steam generation usually produces two...H or temperature. 12 Reed" reported that quartz and other siliceous minerals have very low solubilities at room temperatures, but at elevated temperatures solubilities increase rather sharply. When HCO& ions in steam generator feedwater decompose to COz and OH...

  8. ARM - Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa- PolarizationgovCampaignsSummergovField CampaignsMidlatitudegovMeasurementsSurface

  9. Investigation on the co-precipitation of transuranium elements from alkaline solutions by the method of appearing reagents

    SciTech Connect (OSTI)

    Krot, N.; Shilov, V.; Bessonov, A.; Budantseva, N.; Charushnikova, I.; Perminov, V.; Astafurova, L. [Russian Academy of Science (Russian Federation). Inst. of Physical Chemistry

    1996-06-06T23:59:59.000Z

    Highly alkaline radioactive waste solutions originating from production of plutonium for military purposes are stored in underground tanks at the U.S. Department of Energy Hanford Site. The purification of alkaline solutions from neptunium and plutonium is important in the treatment and disposal of these wastes. This report describes scoping tests with sodium hydroxide solutions, where precipitation techniques were investigated to perform the separation. Hydroxides of iron (III), manganese (II), cobalt (II, III), and chromium (III); manganese (IV) oxide, and sodium uranate were investigated as carriers. The report describes the optimum conditions that were identified to precipitate these carriers homogeneously throughout the solution by reductive, hydrolytic, or catalytic decomposition of alkali-soluble precursor compounds by a technique called the Method of Appearing Reagents. The coprecipitation of pentavalent and hexavalent neptunium and plutonium was investigated for the candidate agents under optimum conditions and is described in this report along with the following results. Plutonium coprecipitated well with all tested materials except manganese (IV) oxide. Neptunium only coprecipitated well with uranate. The report presents a hypothesis to explain these behaviors. Further tests with more complex solution matrices must be performed.

  10. Conceptual Model of Uranium in the Vadose Zone for Acidic and Alkaline Wastes Discharged at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Qafoku, Nikolla; Serne, R. Jeffrey

    2014-09-01T23:59:59.000Z

    Historically, uranium was disposed in waste solutions of varying waste chemistry at the Hanford Site Central Plateau. The character of how uranium was distributed in the vadose zone during disposal, how it has continued to migrate through the vadose zone, and the magnitude of potential impacts on groundwater are strongly influenced by geochemical reactions in the vadose zone. These geochemical reactions can be significantly influenced by the disposed-waste chemistry near the disposal location. This report provides conceptual models and supporting information to describe uranium fate and transport in the vadose zone for both acidic and alkaline wastes discharged at a substantial number of waste sites in the Hanford Site Central Plateau. The conceptual models include consideration of how co-disposed acidic or alkaline fluids influence uranium mobility in terms of induced dissolution/precipitation reactions and changes in uranium sorption with a focus on the conditions near the disposal site. This information, when combined with the extensive information describing uranium fate and transport at near background pH conditions, enables focused characterization to support effective fate and transport estimates for uranium in the subsurface.

  11. advanced distributed measurements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the in situ water distribution within the gas 69 MEASUREMENT OF FLOW FIELD AND WALL TEMPERATURE DISTRIBUTION IN Physics Websites Summary: MEASUREMENT OF FLOW FIELD AND WALL...

  12. Magnetic-field-dosimetry system

    DOE Patents [OSTI]

    Lemon, D.K.; Skorpik, J.R.; Eick, J.L.

    1981-01-21T23:59:59.000Z

    A device is provided for measuring the magnetic field dose and peak field exposure. The device includes three Hall-effect sensors all perpendicular to each other, sensing the three dimensional magnetic field and associated electronics for data storage, calculating, retrieving and display.

  13. Alkaline Leaching of Key, Non-Radioactive Components from Simulants and Hanford Tank Sludge 241-S-110: Results of FY01 Studies

    SciTech Connect (OSTI)

    Rapko, Brian M.; Vienna, John D.; Sinkov, Serguei I.; Kim, Jinseong; Cisar, Alan J.

    2002-09-10T23:59:59.000Z

    This study addressed three aspects in selected alkaline leaching: first, the use of oxidants persulfate, permanganate, and ferrate as selective chromium-leaching agents from washed Hanford Tank S-110 solids under varying conditions of hydroxide concentration, temperature, and time was investigated. Second, the selective dissolution of solids containing mercury(II) oxide under alkaline conditions was examined. Various compounds were studied for their effectiveness in dissolving mercury under varying conditions of time, temperature, and hydroxide concentration in the leachate. Three compounds were studied: cysteine, iodide, and diethyldithiophosphoric acid (DEDTPA). Finally, the possibility of whether an oxidant bound to an anion-exchange resin can be used to effectively oxidize chromium(III) in alkaline solutions was addressed. The experimental results remain ambiguous to date; further work is required to reach any definitive conclusions as to the effectiveness of this approach.

  14. FIELD MEASUREMENT TECHNIQUES: STATUS AND NEEDS

    E-Print Network [OSTI]

    Cook, N.G.W.

    2010-01-01T23:59:59.000Z

    Furthermore, of all rock properties, thermomechanicalthat the information ·on·rock properties available in thethe inherent variability in properties within a rock mass.

  15. F 230 -2012 Forestry Field Measurements

    E-Print Network [OSTI]

    or pencil sharpener Engineer's scale Circular protractor (Sterling #535) Notebooks for lecture notes

  16. Radiation Field on Superspace

    E-Print Network [OSTI]

    P. F. Gonzalez-Diaz

    1994-03-18T23:59:59.000Z

    We study the dynamics of multiwormhole configurations within the framework of the Euclidean Polyakov approach to string theory, incorporating a modification to the Hamiltonian which makes it impossible to interpret the Coleman Alpha parameters of the effective interactions as a quantum field on superspace, reducible to an infinite tower of fields on space-time. We obtain a Planckian probability measure for the Alphas that allows $\\frac{1}{2}\\alpha^{2}$ to be interpreted as the energy of the quanta of a radiation field on superspace whose values may still fix the coupling constants.

  17. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1993-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  18. A Carbon-Supported Copper Complex of 3,5-Diamino-1,2,4-triazole as a Cathode Catalyst for Alkaline Fuel Cell Applications

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Fuel Cell Applications Fikile R. Brushett, Matthew S. Thorum, Nicholas S. Lioutas, Matthew S. Naughton-tri/C) is investigated as a cathode material using an alkaline microfluidic H2/O2 fuel cell. The absolute Cu be realized by optimizing catalyst and electrode preparation procedures. Fuel cell-based systems hold promise

  19. The Nature of Oxide Films on Tungsten in Acidic and Alkaline Solutions

    E-Print Network [OSTI]

    by the mass transport of a loosely bound WO3(H2O)x layer from the surface. Electrochemical impedance spectroscopy measurements found that W dissolution in acidic solution was associated with an adsorption, structure, and hydration as a function of solution pH and applied potential in situ, surface enhanced Raman

  20. Optical Quadratic Measure Eigenmodes

    E-Print Network [OSTI]

    Michael Mazilu; Joerg Baumgartl; Sebastian Kosmeier; Kishan Dholakia

    2010-07-13T23:59:59.000Z

    We report a mathematically rigorous technique which facilitates the optimization of various optical properties of electromagnetic fields. The technique exploits the linearity of electromagnetic fields along with the quadratic nature of their interaction with matter. In this manner we may decompose the respective fields into optical quadratic measure eigenmodes (QME). Key applications include the optimization of the size of a focused spot, the transmission through photonic devices, and the structured illumination of photonic and plasmonic structures. We verify the validity of the QME approach through a particular experimental realization where the size of a focused optical field is minimized using a superposition of Bessel beams.

  1. Accurate measurements of {sup 13}C-{sup 13}C distances in uniformly {sup 13}C-labeled proteins using multi-dimensional four-oscillating field solid-state NMR spectroscopy

    SciTech Connect (OSTI)

    Straasø, Lasse Arnt; Nielsen, Jakob Toudahl; Bjerring, Morten; Nielsen, Niels Chr., E-mail: ncn@inano.au.dk [Center for Insoluble Protein Structures (inSPIN), Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, DK-8000 Aarhus C (Denmark); Khaneja, Navin [Division of Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States)

    2014-09-21T23:59:59.000Z

    Application of sets of {sup 13}C-{sup 13}C internuclear distance restraints constitutes a typical key element in determining the structure of peptides and proteins by magic-angle-spinning solid-state NMR spectroscopy. Accurate measurements of the structurally highly important {sup 13}C-{sup 13}C distances in uniformly {sup 13}C-labeled peptides and proteins, however, pose a big challenge due to the problem of dipolar truncation. Here, we present novel two-dimensional (2D) solid-state NMR experiments capable of extracting distances between carbonyl ({sup 13}C?) and aliphatic ({sup 13}C{sub aliphatic}) spins with high accuracy. The method is based on an improved version of the four-oscillating field (FOLD) technique [L. A. Straasø, M. Bjerring, N. Khaneja, and N. C. Nielsen, J. Chem. Phys. 130, 225103 (2009)] which circumvents the problem of dipolar truncation, thereby offering a base for accurate extraction of internuclear distances in many-spin systems. The ability to extract reliable accurate distances is demonstrated using one- and two-dimensional variants of the FOLD experiment on uniformly {sup 13}C,{sup 15}N-labeled-L-isoleucine. In a more challenging biological application, FOLD 2D experiments are used to determine a large number of {sup 13}C?-{sup 13}C{sub aliphatic} distances in amyloid fibrils formed by the SNNFGAILSS fibrillating core of the human islet amyloid polypeptide with uniform {sup 13}C,{sup 15}N-labeling on the FGAIL fragment.

  2. Solubility Behavior and Phase Stability of Transition Metal Oxides in Alkaline Hydrothermal Environments

    SciTech Connect (OSTI)

    S.E. Ziemniak

    2000-05-18T23:59:59.000Z

    The solubility behavior of transition metal oxides in high temperature water is interpreted by recognizing three types of chemical reaction equilibria: metal oxide hydration/dehydration, metal oxide dissolution and metal ion hydroxocomplex formation. The equilibria are quantified using thermodynamic concepts and the thermochemical properties of the metal oxides/ions representative of the most common constituents of construction metal alloys, i.e., element shaving atomic numbers between Z = 22 (Ti) and Z = 30 (Zn), are summarized on the basis of metal oxide solubility studies conducted in the laboratory. Particular attention is devoted to the uncharged metal ion hydrocomplex, M{sup Z}(OH){sub Z}(aq), since its thermochemical properties define minimum solubilities of the metal oxide at a given temperature. Experimentally-extracted values of standard partial molal entropy (S{sup 0}) for the transition metal ion neutral hydroxocomplex are shown to be influenced by ligand field stabilization energies and complex symmetry.

  3. Field Guide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.New Mexico Feb. 13,Conservation BillingFieldField

  4. Renormalization and quantum field theory

    E-Print Network [OSTI]

    R. E. Borcherds

    2011-03-09T23:59:59.000Z

    The aim of this paper is to describe how to use regularization and renormalization to construct a perturbative quantum field theory from a Lagrangian. We first define renormalizations and Feynman measures, and show that although there need not exist a canonical Feynman measure, there is a canonical orbit of Feynman measures under renormalization. We then construct a perturbative quantum field theory from a Lagrangian and a Feynman measure, and show that it satisfies perturbative analogues of the Wightman axioms, extended to allow time-ordered composite operators over curved spacetimes.

  5. Field Campaign Guidelines (ARM Climate Research Facility)

    SciTech Connect (OSTI)

    Voyles, JW

    2011-01-17T23:59:59.000Z

    The purpose of this document is to establish a common set of guidelines for the Atmospheric Radiation Measurement (ARM) Climate Research Facility for planning, executing, and closing out field campaigns. The steps that guide individual field campaigns are described in the Field Campaign Tracking database tool and are tailored to meet the scope of each specific field campaign.

  6. Tachyonic field interacting with Scalar (Phantom) Field

    E-Print Network [OSTI]

    Surajit Chattopadhyay; Ujjal Debnath

    2009-01-29T23:59:59.000Z

    In this letter, we have considered the universe is filled with the mixture of tachyonic field and scalar or phantom field. If the tachyonic field interacts with scalar or phantom field, the interaction term decays with time and the energy for scalar field is transferred to tachyonic field or the energy for phantom field is transferred to tachyonic field. The tachyonic field and scalar field potentials always decrease, but phantom field potential always increases.

  7. Microbial field pilot study. Final report

    SciTech Connect (OSTI)

    Knapp, R.M.; McInerney, M.J.; Menzie, D.E.; Coates, J.D.; Chisholm, J.L.

    1993-05-01T23:59:59.000Z

    A multi-well microbially enhanced oil recovery field pilot has been performed in the Southeast Vassar Vertz Sand Unit in Payne County, Oklahoma. The primary emphasis of the experiment was preferential plugging of high permeability zones for the purpose of improving waterflood sweep efficiency. Studies were performed to determine reservoir chemistry, ecology, and indigenous bacteria populations. Growth experiments were used to select a nutrient system compatible with the reservoir that encouraged growth of a group of indigenous nitrate-using bacteria and inhibit growth of sulfate-reducing bacteria. A specific field pilot area behind an active line drive waterflood was selected. Surface facilities were designed and installed. Injection protocols of bulk nutrient materials were prepared to facilitate uniform distribution of nutrients within the pilot area. By the end of December, 1991, 82.5 tons (75.0 tonnes) of nutrients had been injected in the field. A tracer test identified significant heterogeneity in the SEVVSU and made it necessary to monitor additional production wells in the field. The tracer tests and changes in production behavior indicate the additional production wells monitored during the field trial were also affected. Eighty two and one half barrels (13.1 m{sup 3}) of tertiary oil have been recovered. Microbial activity has increased CO{sub 2} content as indicated by increased alkalinity. A temporary rise in sulfide concentration was experienced. These indicate an active microbial community was generated in the field by the nutrient injection. Pilot area interwell pressure interference test results showed that significant permeability reduction occurred. The interwell permeabilities in the pilot area between the injector and the three pilot production wells were made more uniform which indicates a successful preferential plugging enhanced oil recovery project.

  8. SHIP VELOCITY FIELDS , Lichuan Guib

    E-Print Network [OSTI]

    Gui, Lichuan

    directions. 1. Introduction Knowledge of flow around ships is important for design, model development, and computational fluid dynamics (CFD) validation. Historically, five-hole pitot probes have been used for measuring of multi-hole pitot and Laser-doppler systems, they both require measurement of ship velocity fields

  9. Alkaline Biofiltration of H2S Odors A R M A N D O G O N Z A L E Z -S A N C H E Z , ,

    E-Print Network [OSTI]

    Alkaline Biofiltration of H2S Odors A R M A N D O G O N Z ´A L E Z - S ´A N C H E Z , , S E R G I. Accepted July 8, 2008. Hydrogen sulfide (H2S) is a very common odor nuisance which is best controlled by chemical or biological scrubbing. Under alkaline pH, the amount of H2S that can be solubilized

  10. Smooth Field Theories and Homotopy Field Theories

    E-Print Network [OSTI]

    Wilder, Alan Cameron

    2011-01-01T23:59:59.000Z

    1 . . . . . . . . 4 Categories of Field Theories 4.1 Functorto super symmetric field theories. CRM Proceedings and0-dimensional super symmetric field theories. preprint 2008.

  11. Measure problem in cosmology

    SciTech Connect (OSTI)

    Gibbons, G. W.; Turok, Neil [DAMTP, Cambridge University, Wilberforce Road, Cambridge CB3 0WA (United Kingdom)

    2008-03-15T23:59:59.000Z

    The Hamiltonian structure of general relativity provides a natural canonical measure on the space of all classical universes, i.e., the multiverse. We review this construction and show how one can visualize the measure in terms of a 'magnetic flux' of solutions through phase space. Previous studies identified a divergence in the measure, which we observe to be due to the dilatation invariance of flat Friedmann-Lemaitre-Robertson-Walker universes. We show that the divergence is removed if we identify universes which are so flat they cannot be observationally distinguished. The resulting measure is independent of time and of the choice of coordinates on the space of fields. We further show that, for some quantities of interest, the measure is very insensitive to the details of how the identification is made. One such quantity is the probability of inflation in simple scalar field models. We find that, according to our implementation of the canonical measure, the probability for N e-folds of inflation in single-field, slow-roll models is suppressed by of order exp(-3N) and we discuss the implications of this result.

  12. Metrology Measurement Capabilities

    SciTech Connect (OSTI)

    Dr. Glen E. Gronniger

    2007-10-02T23:59:59.000Z

    This document contains descriptions of Federal Manufacturing & Technologies (FM&T) Metrology capabilities, traceability flow charts, and the measurement uncertainty of each measurement capability. Metrology provides NIST traceable precision measurements or equipment calibration for a wide variety of parameters, ranges, and state-of-the-art uncertainties. Metrology laboratories conform to the requirements of the Department of Energy Development and Production Manual Chapter 13.2, ANSI/ISO/IEC ANSI/ISO/IEC 17025:2005, and ANSI/NCSL Z540-1. FM&T Metrology laboratories are accredited by NVLAP for the parameters, ranges, and uncertainties listed in the specific scope of accreditation under NVLAP Lab code 200108-0. See the Internet at http://ts.nist.gov/Standards/scopes/2001080.pdf. These parameters are summarized. The Honeywell Federal Manufacturing & Technologies (FM&T) Metrology Department has developed measurement technology and calibration capability in four major fields of measurement: (1) Mechanical; (2) Environmental, Gas, Liquid; (3) Electrical (DC, AC, RF/Microwave); and (4) Optical and Radiation. Metrology Engineering provides the expertise to develop measurement capabilities for virtually any type of measurement in the fields listed above. A strong audit function has been developed to provide a means to evaluate the calibration programs of our suppliers and internal calibration organizations. Evaluation includes measurement audits and technical surveys.

  13. Alkaline-Side Extraction of Cesium from Savannah River Tank Waste Using a Calixarene-Crown Ether Extractant

    SciTech Connect (OSTI)

    Bonnesen, P.V.; Delmau, L.H.; Haverlock, T.J.; Moyer, B.A.

    1998-12-01T23:59:59.000Z

    Results are presented supporting the viability of the alkaline-side CSEX process as a potential replacement for the In-Tank Precipitation process for removal of cesium from aqueous high-level waste (HLW) at the Savannah River Site (SRS). Under funding from the USDOE Efficient Separations and Crosscutting program, a flowsheet was suggested in early June of 1998, and in the following four months, this flowsheet underwent extensive testing, both in batch tests at ORNL and ANL and in two centrifugal-contactor tests at ANL. To carry out these tests, the initial ESP funding was augmented by direct funds from Westinghouse Savannah River Corporation. The flowsheet employed a solvent containing a calixarene-crown hybrid compound called BoBCalixC6 that was invented at ORNL and can now be obtained commercially for government use from IBC Advanced Technologies. This special extractant is so powerful and selective that it can be used at only 0.01 M, compensating for its expense, but a modifier is required for use in an aliphatic diluent, primarily to increase the cesium distribution ratio D{sub Cs} in extraction. The modifier selected is a relatively economical fluorinated alcohol called Cs3, invented at ORNL and so far available. only from ORNL. For the flowsheet, the modifier is used at 0.2 M in the branched aliphatic kerosene Isopar{reg_sign} L. Testing at ORNL and ANL involved simulants of the SRS HLW. After extraction of the Cs from the waste simulant, the solvent is scrubbed with 0.05 M HNO{sub 3} and stripped with a solution comprised of 0.0005 M HNO{sub 3} and 0.0001 M CsNO{sub 3}. The selection of these conditions is justified in this report, both on the basis of experimental data and underlying theory.

  14. Transmission electron microscopy (TEM) investigations of Mn-oxide rich cathodic material from spent disposable alkaline batteries

    SciTech Connect (OSTI)

    Krekeler, Mark P.S. [Department of Environmental Science and Policy, George Mason University, Fairfax, VA 22030 (United States)], E-mail: mark.krekeler@gmail.com

    2008-11-15T23:59:59.000Z

    Transmission electron microscopy (TEM) techniques were used to investigate the spent cathodic material of a single common brand of disposable alkaline batteries. Mn-oxide particles are anhedral and irregular in shape and compose an estimated 99-95% of the <10 {mu}m size fraction of sample material. Diameters of particles vary widely and typically are between 50 nm and 3 {mu}m; however, most particles are approximately 200-400 nm in diameter. Chemical composition varies for Mn-oxide particles with concentrations being SiO{sub 2} (0.00-1.52 wt%), TiO{sub 2} (0.49-4.58 wt%), MnO (65.85-92.06 wt%), ZnO (1.00-7.53 wt%), K{sub 2}O (4.97-20.48 wt%) and SO{sub 3} (0.43-2.21 wt%). Discrete prismatic zinc crystals occur and vary from a maximum of approximately 0.8 {mu}m long x 0.15 {mu}m wide, to 100 nm long x 20 nm wide. Titanium metal was also observed in samples and composes approximately 0.25-1.0% of the <10 {mu}m size fraction of sample material. Results of this study suggest that battery components may be recycled in some special applications. Examples are low energy-low material requirement products such as paint pigments and Zn nanoparticles. This investigation provides detailed constraints on the nature of spent cathodic materials to improve existing recycling methods and develop new technologies.

  15. Field error lottery

    SciTech Connect (OSTI)

    Elliott, C.J.; McVey, B. (Los Alamos National Lab., NM (USA)); Quimby, D.C. (Spectra Technology, Inc., Bellevue, WA (USA))

    1990-01-01T23:59:59.000Z

    The level of field errors in an FEL is an important determinant of its performance. We have computed 3D performance of a large laser subsystem subjected to field errors of various types. These calculations have been guided by simple models such as SWOOP. The technique of choice is utilization of the FELEX free electron laser code that now possesses extensive engineering capabilities. Modeling includes the ability to establish tolerances of various types: fast and slow scale field bowing, field error level, beam position monitor error level, gap errors, defocusing errors, energy slew, displacement and pointing errors. Many effects of these errors on relative gain and relative power extraction are displayed and are the essential elements of determining an error budget. The random errors also depend on the particular random number seed used in the calculation. The simultaneous display of the performance versus error level of cases with multiple seeds illustrates the variations attributable to stochasticity of this model. All these errors are evaluated numerically for comprehensive engineering of the system. In particular, gap errors are found to place requirements beyond mechanical tolerances of {plus minus}25{mu}m, and amelioration of these may occur by a procedure utilizing direct measurement of the magnetic fields at assembly time. 4 refs., 12 figs.

  16. Measurements of submicron aerosols in Houston, Texas during the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of submicron aerosols in Houston, Texas during the 2009 SHARP field campaign. Measurements of submicron aerosols in Houston, Texas during the 2009 SHARP field campaign. Abstract:...

  17. Entomology 489 Field Entomology Field Project Guide

    E-Print Network [OSTI]

    Behmer, Spencer T.

    with information, people, materials). Field Projects (your project should...) FEntomology 489 ­ Field Entomology Field Project Guide A small-group field project is required for ENTO 489 ­ Field Entomology. This guide provides general information about the field-project

  18. Near-field single molecule spectroscopy

    SciTech Connect (OSTI)

    Xie, X.S.; Dunn, R.C.

    1995-02-01T23:59:59.000Z

    The high spatial resolution and sensitivity of near-field fluorescence microscopy allows one to study spectroscopic and dynamical properties of individual molecules at room temperature. Time-resolved experiments which probe the dynamical behavior of single molecules are discussed. Ground rules for applying near-field spectroscopy and the effect of the aluminum coated near-field probe on spectroscopic measurements are presented.

  19. Final Technical Report: Ocean CO{sub 2} Measurements for the WOCE Hydrographic Survey in the Pacific Ocean, 1992-1995 Field Years: Shore Based Analysis of Dissolved Inorganic Carbon January 1, 1993-April 15, 1998

    SciTech Connect (OSTI)

    Keeling, Charles D.

    1998-04-15T23:59:59.000Z

    Participation in the hydrographic survey of the world ocean circulation experiment (WOCE) began in December 1990 with a two year grant from DOE for shore related analyses of inorganic carbon in sea water. These analyses were intended to assure that the measurements carried out under difficult laboratory conditions on board ships were consistent with measurements made under more carefully controlled shore laboratory conditions.

  20. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    University Press, Canberra, Australia, 224 p. Gerasimovsky,University Press, Canberra, Australia, 369 p. Gerasimovsky,

  1. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    Greenland," in Uranium Exploration Geology, Int. AtomicMigration of Uranium and Thorium—Exploration Significance,"interesting for future uranium exploration. The c r i t e r

  2. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    chemical elements uranium zirconium niobium beryllium rarerare earths, niobium, zirconium, uranium, and thorium.respect, uranium and thorium are niobium in carbonatitcs.

  3. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    and Thorium by Gamma-Ray Spectrometry, Exemplified byabundance by gamma-ray spectrometry and, on the basis ofand thorium by gamma-ray spectrometry; exemplified by

  4. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    Heinrich; Petrology and Mineralogy of the Mt. Rosa Area, ElDana 1958 A textbook of mineralogy with an extended treatiseon crystallography and physical mineralogy, Dana, E.S. , and

  5. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    W.W. Patton, Jr. , 1974. "Petrology of the Nepheline SyenitePart I. Geology and Petrology," l? D. 'Nauka , Moscow^ USSR,E. B. & E. Wm. Heinrich; Petrology and Mineralogy of the Mt.

  6. URANIUM IN ALKALINE ROCKS

    E-Print Network [OSTI]

    Murphy, M.

    2011-01-01T23:59:59.000Z

    Mississippi," Amer. Assoc. Petrol. Geol. Bull. , v. 22(7),Coastal Plain," Amer. Assoc. Petrol. Geol. , v. 33(8), ppArkansas," Contrib. Mineral. Petrol. , v. 63, pp 271-294.

  7. Alkaline Membrane Electrolysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of1Albuquerque, NM -Alicia Moulton About Us AliciaRPTnnnn

  8. Electronic field permeameter

    DOE Patents [OSTI]

    Chandler, Mark A. (Madison, WI); Goggin, David J. (Austin, TX); Horne, Patrick J. (Austin, TX); Kocurek, Gary G. (Roundrock, TX); Lake, Larry W. (Austin, TX)

    1989-01-01T23:59:59.000Z

    For making rapid, non-destructive permeability measurements in the field, a portable minipermeameter of the kind having a manually-operated gas injection tip is provided with a microcomputer system which operates a flow controller to precisely regulate gas flow rate to a test sample, and reads a pressure sensor which senses the pressure across the test sample. The microcomputer system automatically turns on the gas supply at the start of each measurement, senses when a steady-state is reached, collects and records pressure and flow rate data, and shuts off the gas supply immediately after the measurement is completed. Preferably temperature is also sensed to correct for changes in gas viscosity. The microcomputer system may also provide automatic zero-point adjustment, sensor calibration, over-range sensing, and may select controllers, sensors, and set-points for obtaining the most precise measurements. Electronic sensors may provide increased accuracy and precision. Preferably one microcomputer is used for sensing instrument control and data collection, and a second microcomputer is used which is dedicated to recording and processing the data, selecting the sensors and set-points for obtaining the most precise measurements, and instructing the user how to set-up and operate the minipermeameter. To provide mass data collection and user-friendly operation, the second microcomputer is preferably a lap-type portable microcomputer having a non-volatile or battery-backed CMOS memory.

  9. On Field Constraint Analysis

    E-Print Network [OSTI]

    Wies, Thomas

    2005-11-03T23:59:59.000Z

    We introduce field constraint analysis, a new technique for verifying data structure invariants. A field constraint for a field is a formula specifying a set of objects to which the field can point. Field constraints ...

  10. 7 SAMPLING AND PREPARATION FOR LABORATORY MEASUREMENTS

    E-Print Network [OSTI]

    . Scanning is an evaluation technique performed by moving a portable radiation detection instrument time. Commonly used radiation detection and measuring equipment for radiological survey field

  11. Generation of Gaussian Density Fields

    E-Print Network [OSTI]

    Hugo Martel

    2005-07-15T23:59:59.000Z

    This document describes analytical and numerical techniques for the generation of Gaussian density fields, which represent cosmological density perturbations. The mathematical techniques involved in the generation of density harmonics in k-space, the filtering of the density fields, and the normalization of the power spectrum to the measured temperature fluctuations of the Cosmic Microwave Background, are presented in details. These techniques are well-known amongst experts, but the current literature lacks a formal description. I hope that this technical report will prove useful to new researchers moving into this field, sparing them the task of reinventing the wheel.

  12. Are Cluster Magnetic Fields Primordial ?

    E-Print Network [OSTI]

    Robi Banerjee; Karsten Jedamzik

    2004-09-07T23:59:59.000Z

    We present results of a detailed and fully non-linear numerical and analytical investigation of magnetic field evolution from the very earliest cosmic epochs to the present. We find that, under reasonable assumptions concerning the efficiency of a putative magnetogenesis era during cosmic phase transitions, surprisingly strong magnetic fields 10^{-13} - 10^{-11} Gauss, on comparatively small scales 100 pc - 10 kpc may survive to the present. Building on prior work on the evolution of magnetic fields during the course of gravitational collapse of a cluster, which indicates that pre-collapse fields of 4\\times 10^{-12} Gauss extant on small scales may suffice to produce clusters with acceptable Faraday rotation measures, we question the widely hold view that cluster magnetic fields may not be entirely of primordial origin.

  13. Smooth Field Theories and Homotopy Field Theories

    E-Print Network [OSTI]

    Wilder, Alan Cameron

    2011-01-01T23:59:59.000Z

    CHAPTER 3. FIELD THEORIES Definition 3.2.1. A smooth fielda ’top down’ definition of field theories. Taking as ourin the following. Definition A field theory is a symmetric

  14. Eighth International Magnetic Measurement Workshop (IMMW-8) presentations

    SciTech Connect (OSTI)

    NONE

    1993-09-01T23:59:59.000Z

    This report contains viewgraphs on magnetic field measurements conducted at the superconducting super collider and other accelerators.

  15. Undulator Long Coil Measurement System Tests

    SciTech Connect (OSTI)

    Wolf, Zachary; Levashov, Yurii; /SLAC; ,

    2010-11-24T23:59:59.000Z

    The first and second field integrals in the LCLS undulators must be below a specified limit. To accurately measure the field integrals, a long coil system is used. This note describes a set of tests which were used to check the performance of the long coil system. A long coil system was constructed to measure the first and second field integrals of the LCLS undulators. The long coil measurements of the background fields were compared to field integrals obtained by sampling the background fields and numerically calculating the integrals. This test showed that the long coil has the sensitivity required to measure at the levels specified for the field integrals. Tests were also performed by making long coil measurements of short magnets of known strength placed at various positions The long coil measurements agreed with the known field integrals obtained by independent measurements and calculation. Our tests showed that the long coil measurements are a valid way to determine whether the LCLS undulator field integrals are below the specified limits.

  16. Purification of alkaline solutions and wastes from actinides and technetium by coprecipitation with some carriers using the method of appearing reagents: Final Report

    SciTech Connect (OSTI)

    Peretrukhin, V.F.; Silin, V.I.; Kareta, A.V.; Gelis, A.V.; Shilov, V.P.; German, K.E.; Firsova, E.V.; Maslennikov, A.G.; Trushina, V.E. [Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Physical Chemistry

    1998-09-01T23:59:59.000Z

    The coprecipitation of transuranium elements (TRU) and technetium from alkaline solutions and from simulants of Hanford Site tank wastes has been studied in reducing and oxidizing conditions on uranium(IV,VI) hydroxocompounds, tetraalkylammonium perrhenate and perchlorate, and on hydroxides of Fe(III), Co(III), Mn(II), and Cr(III) using the method of appearing reagents (MAR). Coprecipitations in alkaline solution have been shown to give high decontamination factors (DF) at low content of carrier and in the presence of high salt concentrations. Uranium(IV) hydroxide in concentrations higher than 3 {times} 10{sup {minus}3} M coprecipitates Pu and Cm in any oxidation state from 0.2 to 4 M NaOH with DFs of 110 to 1000 and Np and Tc with DFs of 51 to 176. Technetium (VII) coprecipitates with (5 to 8) {times} 10{sup {minus}4} M tetrabutylammonium (TBA) perrhenate in 0.01 to 0.02 M TBA hydroxide from 0.5 to 1.5 M NaOH to give DFs of 150 to 200. Coprecipitations of Np and Pu with Co(OH){sub 3}, Fe(OH){sub 3}, Cr(OH){sub 3}, and Mn(OH){sub 2} obtained by the MAR from precursors in the range from pH 10.5 to 0.4 M NaOH give DFs from 80 to 400.

  17. Development of a portable neutron coincidence counter for field measurements of nuclear materials using the advanced multiplicity capabilities of MCNPX 2.5.F and the neutron coincidence point model

    E-Print Network [OSTI]

    Thornton, Angela Lynn

    2008-10-10T23:59:59.000Z

    . I would also like to thank Los Alamos National Laboratory for the opportunity to work on this project. It was with the help of the Howard Menlove, Mike Miller, Martyn Swinhoe, and Carlos Rael, and other N-1 Safeguards Science and Technology staff... .................................................................................... 20 Limitations ...................................................................................... 21 III PLUTONIUM MEASUREMENTS ..................................................... 23 Plutonium Standards...

  18. Development of a portable neutron coincidence counter for field measurements of nuclear materials using the advanced multiplicity capabilities of MCNPX 2.5.F and the neutron coincidence point model

    E-Print Network [OSTI]

    Thornton, Angela Lynn

    2009-05-15T23:59:59.000Z

    . I would also like to thank Los Alamos National Laboratory for the opportunity to work on this project. It was with the help of the Howard Menlove, Mike Miller, Martyn Swinhoe, and Carlos Rael, and other N-1 Safeguards Science and Technology staff... .................................................................................... 20 Limitations ...................................................................................... 21 III PLUTONIUM MEASUREMENTS ..................................................... 23 Plutonium Standards...

  19. Linear electric field mass spectrometry

    DOE Patents [OSTI]

    McComas, D.J.; Nordholt, J.E.

    1992-12-01T23:59:59.000Z

    A mass spectrometer and methods for mass spectrometry are described. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field. 8 figs.

  20. Discovery of magnetic fields in hot subdwarfs

    E-Print Network [OSTI]

    S. J. O'Toole; S. Jordan; S. Friedrich; U. Heber

    2005-03-10T23:59:59.000Z

    We present polarisation measurements of sdB and sdO stars using FORS1 on the VLT. The observations were made as part of a project to determine whether magnetic fields in two super-metal-rich stars can explain their extreme abundance peculiarities. Field strengths of up to ~1.5 kG have been measured at varying levels of significance in each of our six targets, however no clear evidence was found between apparently normal subdwarfs and the metal-rich objects. The origin of the magnetic fields is unknown. We also discuss the implications of our measurements for magnetic flux conservation in late stages of stellar evolution.