National Library of Energy BETA

Sample records for ffalo tioga silver

  1. Tioga Energy | Open Energy Information

    Open Energy Info (EERE)

    Energy Jump to: navigation, search Logo: Tioga Energy Name: Tioga Energy Address: 2755 Campus Drive Place: San Mateo, California Zip: 94403 Region: Bay Area Sector: Solar Product:...

  2. Tioga County, New York: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Tioga County, New York: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 42.1256317, -76.3637285 Show Map Loading map... "minzoom":false,"mappin...

  3. LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    81 § ¨ ¦ 81 LAKESHORE AVON BR ANT-EDEN ALD EN-LANC ASTER AU BURN W SH ELDON CALEDONIA HURON C REEK LEIC EST ER COL DEN ASH FORD INDIAN FALLS LAWTONS SAR DINIA RPD-037 -2 GLENWOOD PU LASKI PAVILION CON CORD COL LINS N ELM A ORC HARD PARK-H AMBU RG DANLEY CORNERS ST ILLWAT ER CHAFF EE-ARCAD E FAYETT E-WATERLOO LAKEVIEW JAVA SEN EC A W ELLER Y AU RORA E ZOAR BU FFALO TIOGA SILVER LAKE AKR ON ROM E RAT HBON E ALM A BET HANY WYOMING ULYSSES BR ANCH W SAN DY CREEK COL LINS BLOOMFIELD E LEBANON

  4. Jonathan Silver

    Broader source: Energy.gov [DOE]

    Jonathan Silver was named Executive Director of the U.S. Department of Energy’s Loan Programs Office in November 2009. Mr. Silver leads the Obama Administration’s $70 billion dollar investment...

  5. Reclaiming silver from silver zeolite

    SciTech Connect (OSTI)

    Reimann, G.A.

    1991-10-01

    Silver zeolite is used to capture radioiodines from air cleaning systems in some nuclear facilities at the Idaho National Engineering Laboratory. It may become radioactively contaminated and/or poisoned by hydrocarbon vapors, which diminishes its capacity for iodine. Silver zeolite contains up to 38 wt% silver. A pyrometallurgical process was developed to reclaim the silver before disposing of the unserviceable zeolite as a radioactive waste. A flux was formulated to convert the refractory aluminosilicate zeolite structure into a low-melting fluid slag, with Na[sub 2]O added as NAOH instead of Na[sub 2]CO[sub 3] to avoid severe foaming due to CO[sub 2] evolution. A propane-fired furnace was built to smelt 45 kg charges at 1300C in a carbon-bonded silicon carbide crucible. A total of 218 kg (7000 tr oz) of silver was reclaimed from 1050 kg of unserviceable zeolite. Silver recoveries of 97% were achieved, and the radioisotopes were fixed as stable silicates in a vitreous slag that was disposed of as a low level waste. Recovered silver was refined using oxygen and cast into 100 tr oz bars assaying 99.8+% silver and showing no radioactive contamination.

  6. Reclaiming silver from silver zeolite

    SciTech Connect (OSTI)

    Reimann, G.A.

    1991-10-01

    Silver zeolite is used to capture radioiodines from air cleaning systems in some nuclear facilities at the Idaho National Engineering Laboratory. It may become radioactively contaminated and/or poisoned by hydrocarbon vapors, which diminishes its capacity for iodine. Silver zeolite contains up to 38 wt% silver. A pyrometallurgical process was developed to reclaim the silver before disposing of the unserviceable zeolite as a radioactive waste. A flux was formulated to convert the refractory aluminosilicate zeolite structure into a low-melting fluid slag, with Na{sub 2}O added as NAOH instead of Na{sub 2}CO{sub 3} to avoid severe foaming due to CO{sub 2} evolution. A propane-fired furnace was built to smelt 45 kg charges at 1300C in a carbon-bonded silicon carbide crucible. A total of 218 kg (7000 tr oz) of silver was reclaimed from 1050 kg of unserviceable zeolite. Silver recoveries of 97% were achieved, and the radioisotopes were fixed as stable silicates in a vitreous slag that was disposed of as a low level waste. Recovered silver was refined using oxygen and cast into 100 tr oz bars assaying 99.8+% silver and showing no radioactive contamination.

  7. Dosimetry using silver salts

    DOE Patents [OSTI]

    Warner, Benjamin P.

    2003-06-24

    The present invention provides a method for detecting ionizing radiation. Exposure of silver salt AgX to ionizing radiation results in the partial reduction of the salt to a mixture of silver salt and silver metal. The mixture is further reduced by a reducing agent, which causes the production of acid (HX) and the oxidized form of the reducing agent (R). Detection of HX indicates that the silver salt has been exposed to ionizing radiation. The oxidized form of the reducing agent (R) may also be detected. The invention also includes dosimeters employing the above method for detecting ionizing radiation.

  8. Silver Award - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DOE Human Resources Management Division DOE Employment Recognition and Awards Program Gold Awards Silver Award Federal Employees Union (AFGE Local 788) Work Schedules Pay and...

  9. Method for the recovery of silver from silver zeolite

    DOE Patents [OSTI]

    Reimann, George A. (Idaho Falls, ID)

    1986-01-01

    High purity silver is recovered from silver exchanged zeolite used to capture radioactive iodine from nuclear reactor and nuclear fuel reprocessing environments. The silver exchanged zeolite is heated with slag formers to melt and fluidize the zeolite and release the silver, the radioactivity removing with the slag. The silver containing metallic impurities is remelted and treated with oxygen and a flux to remove the metal impurities. About 98% of the silver in the silver exchanged zeolite having a purity of 99% or better is recoverable by the method.

  10. Method for the recovery of silver from silver zeolite

    DOE Patents [OSTI]

    Reimann, G.A.

    1985-03-05

    High purity silver is recovered from silver exchanged zeolite used to capture radioactive iodine from nuclear reactor and nuclear fuel reprocessing environments. The silver exchanged zeolite is heated with slag formers to melt and fluidize the zeolite and release the silver, the radioactivity removing with the slag. The silver containing metallic impurities is remelted and treated with oxygen and a flux to remove the metal impurities. About 98% of the silver in the silver exchanged zeolite having a purity of 99% or better is recoverable by the method.

  11. Jonathan Silver | Department of Energy

    Office of Environmental Management (EM)

    Jonathan Silver About Us Jonathan Silver - Executive Director of the Loan Programs Office Photo of Jonathan Silver Jonathan Silver was named Executive Director of the U.S. Department of Energy's Loan Programs Office in November 2009. Mr. Silver leads the Obama Administration's $70 billion dollar investment program in alternative energy, financing a wide range of solar, wind, geothermal, biofuels, fossil and nuclear energy projects. He also heads the government's $20 billion investment program in

  12. Silver Sage Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Sage Wind Farm Jump to: navigation, search Name Silver Sage Wind Farm Facility Silver Sage Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  13. Silver Star Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Star Wind Farm Jump to: navigation, search Name Silver Star Wind Farm Facility Silver Star Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  14. Corrosion protection for silver reflectors

    DOE Patents [OSTI]

    Arendt, Paul N. (Los Alamos, NM); Scott, Marion L. (Los Alamos, NM)

    1991-12-31

    A method of protecting silver reflectors from damage caused by contact with gaseous substances which are often present in the atmosphere and a silver reflector which is so protected. The inventive method comprises at least partially coating a reflector with a metal oxide such as aluminum oxide to a thickness of 15 .ANG. or less.

  15. Process for making silver metal filaments

    DOE Patents [OSTI]

    Bamberger, Carlos E. (Oak Ridge, TN)

    1997-01-01

    A process for making silver metal particles from silver salt particles having the same morphology. Precursor silver salt particles selected from the group consisting of silver acetate and silver sulfide having a selected morphology are contained in a reactor vessel having means for supporting the particles in an air suspension to prevent the agglomeration of the particles. Air is flowed through the reactor vessel at a flow rate sufficient to suspend the particles in the reactor vessel. The suspended precursor silver salt particles are heated to a processing temperature and at a heating rate below which the physical deterioration of the suspended precursor silver salt particles takes place. The suspended precursor silver salt particles are maintained at the processing temperature for a period of time sufficient to convert the particles into silver metal particles having the same morphology as the precursor silver salt particles.

  16. Silver State Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    State Geothermal Project Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Silver State Geothermal Project Project Location Information Coordinates...

  17. Durable silver coating for mirrors

    DOE Patents [OSTI]

    Wolfe, Jesse D. (Discovery Bay, CA); Thomas, Norman L. (Livermore, CA)

    2000-01-01

    A durable multilayer mirror includes reflective layers of aluminum and silver and has high reflectance over a broad spectral range from ultraviolet to visible to infrared. An adhesion layer of a nickel and/or chromium alloy or nitride is deposited on an aluminum surface, and a thin layer of silver is then deposited on the adhesion layer. The silver layer is protected by a passivation layer of a nickel and/or chromium alloy or nitride and by one or more durability layers made of metal oxides and typically a first layer of metal nitride. The durability layers may include a composite silicon aluminum nitride and an oxinitride transition layer to improve bonding between nitride and oxide layers.

  18. Historical impacts of environmental regulation of silver

    SciTech Connect (OSTI)

    Purcell, T.W.; Peters, J.J.

    1999-01-01

    Exposure to silver, and hence its possible environmental effects, has been regulated since the 1960s. Rules were first developed in the United States to protect against potential negative effects to humans due to ingestion of drinking water containing silver. As regulations for other environmental media were developed, silver was generally included because of its designation as a drinking water chemical of concern. Ambient water quality criteria were developed based on the toxic action of ionic silver. In the early 1990s the US Environmental Protection Agency`s Office of Drinking Water downgraded silver from a primary to a secondary maximum contaminant level because the effects of exposure to silver were judged to be cosmetic. Regulations pertaining to solid waste, surface waters, and occupational exposure have not been changed, but may be changed in the near future as the fate and toxic mechanisms of silver become better understood.

  19. Silver Peak Innovative Exploration Project

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Reduce the high level of risk during the early stages of geothermal project development by conducting a multi-faceted and innovative exploration and drilling program at Silver Peak. Determine the combination of techniques that are most useful and cost-effective in identifying the geothermal resource through a detailed, post-project evaluation of the exploration and drilling program.

  20. Silver Spring Networks Inc | Open Energy Information

    Open Energy Info (EERE)

    Spring Networks Inc Jump to: navigation, search Name: Silver Spring Networks Inc Place: Redwood City, California Zip: 94063 Product: California-based, developer of utility...

  1. Down-conversion photoluminescence sensitizing plasmonic silver...

    Office of Scientific and Technical Information (OSTI)

    sensitizing plasmonic silver nanoparticles on ZnO nanorods to generate hydrogen by water splitting photochemistry Citation Details In-Document Search Title:...

  2. Silver Star Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Silver Star Hot Springs Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Silver Star Hot Springs Geothermal Area Contents 1 Area Overview 2 History and...

  3. Development Wells At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Silver Peak Area (DOE GTP) Exploration Activity...

  4. Pressure Temperature Log At Silver Peak Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Pressure Temperature Log At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak...

  5. Silver Creek Farms Aquaculture Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Creek Farms Aquaculture Low Temperature Geothermal Facility Jump to: navigation, search Name Silver Creek Farms Aquaculture Low Temperature Geothermal Facility Facility Silver...

  6. Magnetotellurics At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Silver Peak Area (DOE GTP) Exploration Activity...

  7. Geothermometry At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Silver Peak Area (DOE GTP) Exploration Activity...

  8. Cuttings Analysis At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At Silver Peak Area (DOE GTP) Exploration Activity...

  9. Ground Magnetics At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Magnetics At Silver Peak Area (DOE GTP) Exploration Activity...

  10. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  11. Silver-hafnium braze alloy

    DOE Patents [OSTI]

    Stephens, Jr., John J.; Hosking, F. Michael; Yost, Frederick G.

    2003-12-16

    A binary allow braze composition has been prepared and used in a bonded article of ceramic-ceramic and ceramic-metal materials. The braze composition comprises greater than approximately 95 wt % silver, greater than approximately 2 wt % hafnium and less than approximately 4.1 wt % hafnium, and less than approximately 0.2 wt % trace elements. The binary braze alloy is used to join a ceramic material to another ceramic material or a ceramic material, such as alumina, quartz, aluminum nitride, silicon nitride, silicon carbide, and mullite, to a metal material, such as iron-based metals, cobalt-based metals, nickel-based metals, molybdenum-based metals, tungsten-based metals, niobium-based metals, and tantalum-based metals. A hermetic bonded article is obtained with a strength greater than 10,000 psi.

  12. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, Jr., Charles Q. (Benton, WA)

    1981-01-01

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  13. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  14. Silver-catalyzed synthesis of amides from amines and aldehydes

    DOE Patents [OSTI]

    Madix, Robert J; Zhou, Ling; Xu, Bingjun; Friend, Cynthia M; Freyschlag, Cassandra G

    2014-11-18

    The invention provides a method for producing amides via the reaction of aldehydes and amines with oxygen adsorbed on a metallic silver or silver alloy catalyst. An exemplary reaction is shown in Scheme 1: (I), (II), (III). ##STR00001##

  15. Silver Spring, Maryland: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    You can help OpenEI by expanding it. Silver Spring is a census-designated place in Montgomery County, Maryland.1 Registered Energy Companies in Silver Spring, Maryland CPV Wind...

  16. Sintered silver joints via controlled topography of electronic packaging subcomponents

    DOE Patents [OSTI]

    Wereszczak, Andrew A.

    2014-09-02

    Disclosed are sintered silver bonded electronic package subcomponents and methods for making the same. Embodiments of the sintered silver bonded EPSs include topography modification of one or more metal surfaces of semiconductor devices bonded together by the sintered silver joint. The sintered silver bonded EPSs include a first semiconductor device having a first metal surface, the first metal surface having a modified topography that has been chemically etched, grit blasted, uniaxial ground and/or grid sliced connected to a second semiconductor device which may also include a first metal surface with a modified topography, a silver plating layer on the first metal surface of the first semiconductor device and a silver plating layer on the first metal surface of the second semiconductor device and a sintered silver joint between the silver plating layers of the first and second semiconductor devices which bonds the first semiconductor device to the second semiconductor device.

  17. Green chemical synthesis of silver nanomaterials with maltodextrin.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Green chemical synthesis of silver nanomaterials with maltodextrin. Citation Details In-Document Search Title: Green chemical synthesis of silver nanomaterials with maltodextrin. Silver nanomaterials have significant application resulting from their optical properties related to surface enhanced Raman spectroscopy, high electrical conductivity, and anti-microbial impact. A 'green chemistry' synthetic approach for silver nanomaterials minimizes the

  18. Silver Spring Networks comments on DOE NBP RFI: Comms Requirements |

    Energy Savers [EERE]

    Department of Energy Comms Requirements Silver Spring Networks comments on DOE NBP RFI: Comms Requirements Comments of Silver Spring Networks on Implementing the National Broadband Plan by Studying the Communications Requirements of Electric Utilities to Inform Federal Smart Grid Policy PDF icon Silver Spring Networks comments on DOE NBP RFI: Comms Requirements More Documents & Publications Silver Spring Networks comments on DOE NBP RFI: Data Access NBP RFI: Communications Requirements-

  19. Silver doped catalysts for treatment of exhaust

    DOE Patents [OSTI]

    Park, Paul Worn [Peoria, IL; Boyer, Carrie L [Shiloh, IL

    2006-12-26

    A method of making an exhaust treatment catalyst includes dispersing a metal-based material in a first solvent to form a first slurry and allowing polymerization of the first slurry to occur. Polymerization of the first slurry may be quenched and the first slurry may be allowed to harden into a solid. This solid may be redistributed in a second solvent to form a second slurry. The second slurry may be loaded with a silver-based material, and a silver-loaded powder may be formed from the second slurry.

  20. Biosynthesis and structural characterization of silver nanoparticles from bacterial isolates

    SciTech Connect (OSTI)

    Zaki, Sahar; El Kady, M.F.; Abd-El-Haleem, Desouky

    2011-10-15

    Graphical abstract: In this study five bacterial isolates belong to different genera were found to be able to biosynthesize silver nanoparticles. Biosynthesis and spectral characterization are reported here. Highlights: {yields} About 300 bacterial isolates were screened for their ability to produce nanosilvers {yields} Five of them were potential candidates for synthesis of silver nanoparticles {yields} Production of silver nanoparticles was examined using UV-Vis, XRD, SEM and EDS. {yields} The presence of nanoparticles with all five bacterial isolates was confirmed. -- Abstract: This study aimed to develop a green process for biosynthesis of silver nanomaterials by some Egyptian bacterial isolates. This target was achieved by screening an in-house culture collection consists of 300 bacterial isolates for silver nanoparticle formation. Through screening process, it was observed that strains belonging to Escherichia coli (S30, S78), Bacillus megaterium (S52), Acinetobacter sp. (S7) and Stenotrophomonas maltophilia (S54) were potential candidates for synthesis of silver nanoparticles. The extracellular production of silver nanoparticles by positive isolates was investigated by UV-Vis spectroscopy, X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results demonstrated that UV-visible spectrum of the aqueous medium containing silver ion showed a peak at 420 nm corresponding to the plasmon absorbance of silver nanoparticles. Scanning electron microscopy micrograph showed formation of silver nanoparticles in the range of 15-50 nm. XRD-spectrum of the silver nanoparticles exhibited 2{theta} values corresponding to the silver nanocrystal that produce in hexagonal and cubic crystal configurations with different plane of orientation. In addition, the signals of the silver atoms were observed by EDS-spectrum analysis that confirms the presence of silver nanoparticles (AgNPs) in all positive bacterial isolates.

  1. PIXE analysis of medieval silver coins

    SciTech Connect (OSTI)

    Abdelouahed, H. Ben; Gharbi, F.; Roumie, M.; Baccouche, S.; Romdhane, K. Ben; Nsouli, B.; Trabelsi, A.

    2010-01-15

    We applied the proton-induced X-ray emission (PIXE) analytical technique to twenty-eight medieval silver coins, selected from the Tunisian treasury. The purpose is to study the fineness evolution from the beginning of the 7th to the 15th centuries AD. Each silver coin was cleaned with a diluted acid solution and then exposed to a 3 MeV proton beam from a 1.7 MV tandem accelerator. To allow the simultaneous detection of light and heavy elements, a funny aluminum filter was positioned in front of the Si(Li) detector entrance which is placed at 135{sup o} to the beam direction. The elements Cu, Pb, and Au were observed in the studied coins along with the major component silver. The concentration of Ag, presumably the main constituent of the coins, varies from 55% to 99%. This significant variation in the concentration of the major constituent reveals the economical difficulties encountered by each dynasty. It could be also attributed to differences in the composition of the silver mines used to strike the coins in different locations. That fineness evolution also reflects the poor quality of the control practices during this medieval period. In order to verify the ability of PIXE analytical method to distinguish between apparently similar coins, we applied hierarchical cluster analysis to our results to classify them into different subgroups of similar elemental composition.

  2. Silver doped catalysts for treatment of exhaust

    DOE Patents [OSTI]

    Park, Paul Worn; Hester, Virgil Raymond; Ragle, Christie Susan; Boyer, Carrie L.

    2009-06-02

    A method of making an exhaust treatment element includes washcoating a substrate with a slurry that includes a catalyst support material. At least some of the catalyst support material from the slurry may be transferred to the substrate, and silver metal (Ag) is dispersed within the catalyst support material.

  3. Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Performance, Low-Cost CSP Collector Systems | Department of Energy Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems PDF icon csp_review_meeting_042313_angel.pdf More Documents &

  4. Durable Corrosion and Ultraviolet-Resistant Silver Mirror

    DOE Patents [OSTI]

    Jorgensen, G. J.; Gee, R.

    2006-01-24

    A corrosion and ultra violet-resistant silver mirror for use in solar reflectors; the silver layer having a film-forming protective polymer bonded thereto, and a protective shield overlay comprising a transparent multipolymer film that incorporates a UV absorber. The corrosion and ultraviolet resistant silver mirror retains spectral hemispherical reflectance and high optical clarity throughout the UV and visible spectrum when used in solar reflectors.

  5. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel...

    Office of Scientific and Technical Information (OSTI)

    Bed Adsorption Testing using Silver-Functionalized Aerogel Nick Soelberg; Tony Watson 12 MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES aerogel; iodine...

  6. Silver Ink for Conductor Printing - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flake suspended in a suitable solvent amenable to printing. These silver metal suspension formulations require high processing temperatures to sinter the particles (180 C)....

  7. DNA Origami Directed Self-Assembly of Discrete Silver Nanoparticle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as spatially addressable templates to organize noble-metal nanoparticles of silver and gold into well-defined discrete architectures visualized by TEM. Date of online publication:...

  8. Multispectral Imaging At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Multispectral Imaging At Silver Peak Area (DOE GTP) Exploration Activity Details...

  9. There is no Silver Bullet: Regionalization and Market Fragmentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Greenhouse Gas Mitigation Strategies There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies 2004 Diesel Engine Emissions ...

  10. Advanced Manufacture of Second-Surface, Silvered Glass Reflectors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems PDF icon cspreviewmeeting042313angel.pdf More Documents & ...

  11. Green chemical synthesis of silver nanomaterials with maltodextrin...

    Office of Scientific and Technical Information (OSTI)

    Deposit morphology and optical properties are characterized using SEM and UV-vis techniques. Silver nanoparticles are generated under alkaline conditions by a dissolution-reduction ...

  12. Rock Density At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Density At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak Area...

  13. Density Log at Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Density Log at Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak...

  14. Flow Test At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak Area...

  15. 2-M Probe At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak...

  16. Gamma Log At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gamma Log At Silver Peak Area (DOE GTP) Exploration Activity Details...

  17. Neutron Log At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Neutron Log At Silver Peak Area (DOE GTP) Exploration Activity Details...

  18. Slim Holes At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Silver Peak Area (DOE GTP) Exploration Activity Details...

  19. Core Analysis At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Core Analysis At Silver Peak Area (DOE GTP) Exploration Activity...

  20. Silver Spring Networks comments on DOE NBP RFI: Data Access | Department of

    Energy Savers [EERE]

    Energy Data Access Silver Spring Networks comments on DOE NBP RFI: Data Access Silver Spring Networks comments on DOE NBP RFI: Data Access PDF icon Silver Spring Networks comments on DOE NBP RFI: Data Access More Documents & Publications Silver Spring Networks comments on DOE NBP RFI: Comms Requirements NBP RFI: Data Access RE: NBP RFI: Data Access

  1. Properties of Bulk Sintered Silver As a Function of Porosity

    SciTech Connect (OSTI)

    Wereszczak, Andrew A; Vuono, Daniel J; Wang, Hsin; Ferber, Mattison K; Liang, Zhenxian

    2012-06-01

    This report summarizes a study where various properties of bulk-sintered silver were investigated over a range of porosity. This work was conducted within the National Transportation Research Center's Power Device Packaging project that is part of the DOE Vehicle Technologies Advanced Power Electronics and Electric Motors Program. Sintered silver, as an interconnect material in power electronics, inherently has porosity in its produced structure because of the way it is made. Therefore, interest existed in this study to examine if that porosity affected electrical properties, thermal properties, and mechanical properties because any dependencies could affect the intended function (e.g., thermal transfer, mechanical stress relief, etc.) or reliability of that interconnect layer and alter how its performance is modeled. Disks of bulk-sintered silver were fabricated using different starting silver pastes and different sintering conditions to promote different amounts of porosity. Test coupons were harvested out of the disks to measure electrical resistivity and electrical conductivity, thermal conductivity, coefficient of thermal expansion, elastic modulus, Poisson's ratio, and yield stress. The authors fully recognize that the microstructure of processed bulk silver coupons may indeed not be identical to the microstructure produced in thin (20-50 microns) layers of sintered silver. However, measuring these same properties with such a thin actual structure is very difficult, requires very specialized specimen preparation and unique testing instrumentation, is expensive, and has experimental shortfalls of its own, so the authors concluded that the herein measured responses using processed bulk sintered silver coupons would be sufficient to determine acceptable values of those properties. Almost all the investigated properties of bulk sintered silver changed with porosity content within a range of 3-38% porosity. Electrical resistivity, electrical conductivity, thermal conductivity, elastic modulus, Poisson's ratio, and yield stress all depended on the porosity content in bulk-sintered silver. The only investigated property that was independent of porosity in that range was coefficient of thermal expansion.

  2. Adsorption of silver dimer on graphene - A DFT study

    SciTech Connect (OSTI)

    Kaur, Gagandeep, E-mail: gaganj1981@yahoo.com [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014, India and Chandigarh Engineering College, Landran, Mohali-140307, Punjab (India); Gupta, Shuchi [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014, India and University Institute of Engineering and Technology, Panjab University, Chandigarh -160014 (India); Rani, Pooja; Dharamvir, Keya [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014 (India)

    2014-04-24

    We performed a systematic density functional theory (DFT) study of the adsorption of silver dimer (Ag{sub 2}) on graphene using SIESTA (Spanish Initiative for Electronic Simulations with Thousands of Atoms) package, in the generalized gradient approximation (GGA). The adsorption energy, geometry, and charge transfer of Ag2-graphene system are calculated. The minimum energy configuration for a silver dimer is parallel to the graphene sheet with its two atoms directly above the centre of carbon-carbon bond. The negligible charge transfer between the dimer and the surface is also indicative of a weak bond. The methodology demonstrated in this paper may be applied to larger silver clusters on graphene sheet.

  3. Energetics Measurements of Silver Halfraum Targets at the National...

    Office of Scientific and Technical Information (OSTI)

    Title: Energetics Measurements of Silver Halfraum Targets at the National Ignition Facility Authors: May, M J ; Fournier, K B ; Brown, C G ; Dunlop, W H ; Kane, J O ; Mirkarimi, P ...

  4. Silver Peak, Nevada: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    This article is a stub. You can help OpenEI by expanding it. Silver Peak is a city in Esmeralda County, Nevada. References USGS GNIS Retrieved from "http:en.openei.orgw...

  5. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel...

    Office of Scientific and Technical Information (OSTI)

    The silver-functionalized Aerogel appears to have potential to be a very effective and efficient iodine sorbent. Authors: Nick Soelberg ; Tony Watson Publication Date: 2012-06-01 ...

  6. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Citation Details In-Document Search Title: Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I129, due to its radioactivity, high

  7. Energetics Measurements of Silver Halfraum Targets at the National Ignition

    Office of Scientific and Technical Information (OSTI)

    Facility (Journal Article) | SciTech Connect Journal Article: Energetics Measurements of Silver Halfraum Targets at the National Ignition Facility Citation Details In-Document Search Title: Energetics Measurements of Silver Halfraum Targets at the National Ignition Facility Authors: May, M J ; Fournier, K B ; Brown, C G ; Dunlop, W H ; Kane, J O ; Mirkarimi, P B ; Moody, J ; Patterson, R ; Schneider, M ; Widmann, K Publication Date: 2013-09-09 OSTI Identifier: 1229821 Report Number(s):

  8. There is no Silver Bullet: Regionalization and Market Fragmentation in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Greenhouse Gas Mitigation Strategies | Department of Energy There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Joint Global Change Research Institute PDF icon 2004_deer_stokes.pdf More Documents & Publications Analysis Activities at Pacific Northwest

  9. Synthesis Of Silver Sulfide Stratified Photocatalyst

    SciTech Connect (OSTI)

    Baba, Y.; Yokoyama, S.; Takahashi, H.; Tohji, K.

    2008-02-25

    In this report, silver sulfide (Ag{sub 2}S) was selected as a new H{sub 2}S splitting photocatalyst material, and considered the synthesis method of Ag{sub 2}S photocatalyst particles with stratified structure. Previous stratified particles were synthesized by using metal oxide (hydroxide) as the precursor. Ag{sub 2}O particles as the precursor of Ag{sub 2}S were synthesized by mixing AgNO{sub 3} solution and NaOH, and their particle sizes could be controlled by the solutions' concentration. Then, Ag{sub 2}S particles were obtained by adding Na{sub 2}S solution into suspending solution of Ag{sub 2}O particles with optimum sizes. Particle sizes of Ag{sub 2}S were changed by Na{sub 2}S concentration control, and remaining Ag{sub 2}O precursor could be dissolved by adding NH{sub 3} solution. The photocatalytic H{sub 2}S splitting could be realized by UV-light irradiation on the Ag{sub 2}S particles without co-catalyst like Pt.

  10. Size-dependent structure of silver nanoparticles under high pressure

    SciTech Connect (OSTI)

    Koski, Kristie Jo

    2008-12-31

    Silver noble metal nanoparticles that are<10 nm often possess multiply twinned grains allowing them to adopt shapes and atomic structures not observed in bulk materials. The properties exhibited by particles with multiply twinned polycrystalline structures are often far different from those of single-crystalline particles and from the bulk. I will present experimental evidence that silver nanoparticles<10 nm undergo a reversible structural transformation under hydrostatic pressures up to 10 GPa. Results for nanoparticles in the intermediate size range of 5 to 10 nm suggest a reversible linear pressure-dependent rhombohedral distortion which has not been previously observed in bulk silver. I propose a mechanism for this transitiion that considers the bond-length distribution in idealized multiply twinned icosahedral particles. Results for nanoparticles of 3.9 nm suggest a reversible linear pressure-dependent orthorhombic distortion. This distortion is interpreted in the context of idealized decahedral particles. In addition, given these size-dependent measurements of silver nanoparticle compression with pressure, we have constructed a pressure calibration curve. Encapsulating these silver nanoparticles in hollow metal oxide nanospheres then allows us to measure the pressure inside a nanoshell using x-ray diffraction. We demonstrate the measurement of pressure gradients across nanoshells and show that these nanoshells have maximum resolved shear strengths on the order of 500 MPa to IGPa.

  11. Tin-silver-bismuth solders for electronics assembly

    DOE Patents [OSTI]

    Vianco, Paul T. (Albuquerque, NM); Rejent, Jerome A. (Albuquerque, NM)

    1995-01-01

    A lead-free solder alloy for electronic assemblies composed of a eutectic alloy of tin and silver with a bismuth addition, x, of 0silver composition to a desired level. Melting point ranges from about 218.degree. C. down to about 205.degree. C. depending an the amount of bismuth added to the eutectic tin-silver alloy as determined by DSC analysis, 10.degree. C./min. A preferred alloy composition is 91.84Sn-3.33Ag-4.83Bi (weight percent based on total alloy weight).

  12. PATCHY SILICA-COATED SILVER NANOWIRES AS SERS SUBSTRATES

    SciTech Connect (OSTI)

    Murph, S.; Murphy, C.

    2013-03-29

    We report a class of core-shell nanomaterials that can be used as efficient surface-enhancement Raman scattering (SERS) substrates. The core consists of silver nanowires, prepared through a chemical reduction process, that are used to capture 4- mercaptobenzoic acid (4-MBA), a model analyte. The shell was prepared through a modified Stber method and consists of patchy or full silica coats. The formation of silica coats was monitored via transmission electron microscopy, UV-visible spectroscopy and phase-analysis light scattering for measuring effective surface charge. Surprisingly, the patchy silica coated silver nanowires are better SERS substrate than silver nanowires; nanomolar concentration of 4-MBA can be detected. In addition, nano-matryoshka configurations were used to quantitate/explore the effect of the electromagnetic field at the tips of the nanowire (hot spots) in the Raman scattering experiment.

  13. Tin-silver-bismuth solders for electronics assembly

    DOE Patents [OSTI]

    Vianco, P.T.; Rejent, J.A.

    1995-08-08

    A lead-free solder alloy is disclosed for electronic assemblies composed of a eutectic alloy of tin and silver with a bismuth addition, x, of 0silver composition to a desired level. Melting point ranges from about 218 C down to about 205 C depending an the amount of bismuth added to the eutectic tin-silver alloy as determined by DSC analysis, 10 C/min. A preferred alloy composition is 91.84Sn-3.33Ag-4.83Bi (weight percent based on total alloy weight). 4 figs.

  14. Silver Peak Innovative Exploration Project (Ram Power Inc.)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miller, Clay

    2010-01-01

    Data generated from the Silver Peak Innovative Exploration Project, in Esmeralda County, Nevada, encompasses a “deep-circulation (amagmatic)” meteoric-geothermal system circulating beneath basin-fill sediments locally blanketed with travertine in western Clayton Valley (lithium-rich brines from which have been mined for several decades). Spring- and shallow-borehole thermal-water geochemistry and geothermometry suggest that a Silver Peak geothermal reservoir is very likely to attain the temperature range 260- 300oF (~125-150oC), and may reach 300-340oF (~150-170oC) or higher (GeothermEx, Inc., 2006). Results of detailed geologic mapping, structural analysis, and conceptual modeling of the prospect (1) support the GeothermEx (op. cit.) assertion that the Silver Peak prospect has good potential for geothermal-power production; and (2) provide a theoretical geologic framework for further exploration and development of the resource. The Silver Peak prospect is situated in the transtensional (regional shearing coupled with extension) Walker Lane structural belt, and squarely within the late Miocene to Pliocene (11 Ma to ~5 Ma) Silver Peak-Lone Mountain metamorphic core complex (SPCC), a feature that accommodated initial displacement transfer between major right-lateral strike- slip fault zones on opposite sides of the Walker Lane. The SPCC consists essentially of a ductiley-deformed lower plate, or “core,” of Proterozoic metamorphic tectonites and tectonized Mesozoic granitoids separated by a regionally extensive, low-angle detachment fault from an upper plate of severely stretched and fractured structural slices of brittle, Proterozoic to Miocene-age lithologies. From a geothermal perspective, the detachment fault itself and some of the upper-plate structural sheets could function as important, if secondary, subhorizontal thermal-fluid aquifers in a Silver Peak hydrothermal system.

  15. Silver Peak Innovative Exploration Project (Ram Power Inc.)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miller, Clay

    2010-01-01

    Data generated from the Silver Peak Innovative Exploration Project, in Esmeralda County, Nevada, encompasses a deep-circulation (amagmatic) meteoric-geothermal system circulating beneath basin-fill sediments locally blanketed with travertine in western Clayton Valley (lithium-rich brines from which have been mined for several decades). Spring- and shallow-borehole thermal-water geochemistry and geothermometry suggest that a Silver Peak geothermal reservoir is very likely to attain the temperature range 260- 300oF (~125-150oC), and may reach 300-340oF (~150-170oC) or higher (GeothermEx, Inc., 2006). Results of detailed geologic mapping, structural analysis, and conceptual modeling of the prospect (1) support the GeothermEx (op. cit.) assertion that the Silver Peak prospect has good potential for geothermal-power production; and (2) provide a theoretical geologic framework for further exploration and development of the resource. The Silver Peak prospect is situated in the transtensional (regional shearing coupled with extension) Walker Lane structural belt, and squarely within the late Miocene to Pliocene (11 Ma to ~5 Ma) Silver Peak-Lone Mountain metamorphic core complex (SPCC), a feature that accommodated initial displacement transfer between major right-lateral strike- slip fault zones on opposite sides of the Walker Lane. The SPCC consists essentially of a ductiley-deformed lower plate, or core, of Proterozoic metamorphic tectonites and tectonized Mesozoic granitoids separated by a regionally extensive, low-angle detachment fault from an upper plate of severely stretched and fractured structural slices of brittle, Proterozoic to Miocene-age lithologies. From a geothermal perspective, the detachment fault itself and some of the upper-plate structural sheets could function as important, if secondary, subhorizontal thermal-fluid aquifers in a Silver Peak hydrothermal system.

  16. Silver Peak Innovative Exploration Project (Ram Power Inc.)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miller, Clay

    Data generated from the Silver Peak Innovative Exploration Project, in Esmeralda County, Nevada, encompasses a deep-circulation (amagmatic) meteoric-geothermal system circulating beneath basin-fill sediments locally blanketed with travertine in western Clayton Valley (lithium-rich brines from which have been mined for several decades). Spring- and shallow-borehole thermal-water geochemistry and geothermometry suggest that a Silver Peak geothermal reservoir is very likely to attain the temperature range 260- 300oF (~125-150oC), and may reach 300-340oF (~150-170oC) or higher (GeothermEx, Inc., 2006). Results of detailed geologic mapping, structural analysis, and conceptual modeling of the prospect (1) support the GeothermEx (op. cit.) assertion that the Silver Peak prospect has good potential for geothermal-power production; and (2) provide a theoretical geologic framework for further exploration and development of the resource. The Silver Peak prospect is situated in the transtensional (regional shearing coupled with extension) Walker Lane structural belt, and squarely within the late Miocene to Pliocene (11 Ma to ~5 Ma) Silver Peak-Lone Mountain metamorphic core complex (SPCC), a feature that accommodated initial displacement transfer between major right-lateral strike- slip fault zones on opposite sides of the Walker Lane. The SPCC consists essentially of a ductiley-deformed lower plate, or core, of Proterozoic metamorphic tectonites and tectonized Mesozoic granitoids separated by a regionally extensive, low-angle detachment fault from an upper plate of severely stretched and fractured structural slices of brittle, Proterozoic to Miocene-age lithologies. From a geothermal perspective, the detachment fault itself and some of the upper-plate structural sheets could function as important, if secondary, subhorizontal thermal-fluid aquifers in a Silver Peak hydrothermal system.

  17. Silver chromate and silver dichromate nanostructures: Sonochemical synthesis, characterization, and photocatalytic properties

    SciTech Connect (OSTI)

    Soofivand, Faezeh; Mohandes, Fatemeh; Salavati-Niasari, Masoud

    2013-06-01

    Graphical abstract: In this work, Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures have been sonochemically prepared using silver salicylate. The effect of preparation parameters on the morphology of the products was investigated by SEM images. Highlights: ? Herein, Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures have been sonochemically prepared. ? The effect of preparation parameters on the morphology of the products was investigated. ? The photocatalytic activity of the as-prepared Ag{sub 2}CrO{sub 4} nanoparticles was tested. ? XPS spectra indicated the high purity of Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures obtained. - Abstract: In this work, Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures have been produced via a sonochemical method using silver salicylate as precursor. Besides silver salicylate, Na{sub 2}CrO{sub 4} and (NH{sub 4}){sub 2}Cr{sub 2}O{sub 7} as starting reagents were applied. To investigate the effect of preparation parameters on the morphology and particle size of Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7}, sonication time, type of surfactant and its concentration were changed. The as-produced nanostructures were characterized by techniques like powder X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. The scanning electron micrographs showed that particle-like and rod-like nanostructures of Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} were produced using different surfactants. To investigate the catalytic properties of Ag{sub 2}CrO{sub 4} nanoparticles, photooxidation of methyl orange (MO) was performed. According to the obtained results, it was found that the methyl orange degradation was about 87.3% after 280 min irradiation of visible light.

  18. The silver bullet myth of sustainable energy savings

    SciTech Connect (OSTI)

    Pasqualetti, Martin J.; Tabbert, Michael K.; Boscamp, Robert L.

    2010-10-15

    Especially in the U.S., people like to think that solving problems just requires finding the proper ''silver bullet.'' Such fixes are not sustainable. Any utility company wanting sustainable long-term savings in personal energy demand requires a more thorough commitment that might be referred to as ''head'' (education), ''heart'' (motivation), and ''hands'' (action). (author)

  19. AGING AND IODINE LOADING OF SILVER-FUNCTIONALIZED AEROGELS

    SciTech Connect (OSTI)

    Bruffey, Stephanie H [ORNL; Jubin, Robert Thomas [ORNL; Anderson, Kaara K [ORNL; Walker Jr, Joseph Franklin [ORNL

    2013-01-01

    Engineered silver-functionalized silica aerogels are being investigated for their application in off-gas treatment at a used nuclear fuel reprocessing facility. Reprocessing will release several key volatile radionuclides, including iodine-129. To achieve regulatory compliance, iodine-129 must be removed from any off-gas stream prior to environmental discharge. Silver-functionalized aerogels have been demonstrated to have high iodine capture capacity, high porosity and potential for conversion into a waste form. Capture materials used in off-gas treatment may be exposed to a heated, high humidity, acidic gas stream for months. Extended exposure to this stream could affect sorbent performance. It was the aim of this study to evaluate what impacts might be observed when Ag0-functionalized aerogels prepared at Pacific Northwest National Laboratory were contacted with a dry air stream for up to 6 months and then used to adsorb iodine from a synthetic off-gas stream. Results demonstrate that there is some loss of iodine capture capacity caused by aging, but that this loss is not as marked as for aging of more traditional iodine sorbents, such as silver-impregnated mordenite. Specifically, aging silver-functionalized aerogel under a dry air stream for up to 6 months can decrease its iodine capacity from 41wt% to 32wt%.

  20. Method for extracting copper, silver and related metals

    DOE Patents [OSTI]

    Moyer, B.A.; McDowell, W.J.

    1987-10-23

    A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

  1. Method for extracting copper, silver and related metals

    DOE Patents [OSTI]

    Moyer, Bruce A.; McDowell, W. J.

    1990-01-01

    A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

  2. Azine bridged silver coordination polymers: Powder X-ray diffraction route to crystal structure determination of silver benzotriazole

    SciTech Connect (OSTI)

    Rajeswaran, Manju . E-mail: manju.rajeswaran@kodak.com; Blanton, Thomas N.; Giesen, David J.; Whitcomb, David R.; Zumbulyadis, Nicholas; Antalek, Brian J.; Neumann, Marcus M.; Misture, Scott T.

    2006-04-15

    In continuation of our interest in solid-state structures of silver complexes of photographic importance, the structure for silver benzotriazole (AgBZT), has now been obtained. The preferred method for solving crystal structures is via single-crystal X-ray diffraction (XRD). However, for some materials, growing single crystals of appropriate size and quality is often difficult or even impossible. AgBZT is an example of such a silver complex with poor solubility. The usual routes to preparing single crystals using recrystallization from a cooperating solvent resulted in polycrystalline powder samples. We propose a crystal structure for AgBZT, solved from synchrotron X-ray powder diffraction data, using a direct-space Monte Carlo simulated annealing approach. AgBZT crystals are monoclinic (P2{sub 1} /c), with unit cell dimensions, a=14.8052(3) A, b=3.7498(4) A, c=12.3495(12) A, and {beta}=114.200(6){sup o}. The AgBZT complex is constructed from all three of the Benzotriazole (BZT) nitrogens bonding to a separate silver atom. As a consequence of this bonding mode, the structure is a highly cross-linked, coordination polymer.

  3. Super-Joule heating in graphene and silver nanowire network

    SciTech Connect (OSTI)

    Maize, Kerry; Das, Suprem R.; Sadeque, Sajia; Mohammed, Amr M. S.; Shakouri, Ali E-mail: alam@purdue.edu; Janes, David B.; Alam, Muhammad A. E-mail: alam@purdue.edu

    2015-04-06

    Transistors, sensors, and transparent conductors based on randomly assembled nanowire networks rely on multi-component percolation for unique and distinctive applications in flexible electronics, biochemical sensing, and solar cells. While conduction models for 1-D and 1-D/2-D networks have been developed, typically assuming linear electronic transport and self-heating, the model has not been validated by direct high-resolution characterization of coupled electronic pathways and thermal response. In this letter, we show the occurrence of nonlinear super-Joule self-heating at the transport bottlenecks in networks of silver nanowires and silver nanowire/single layer graphene hybrid using high resolution thermoreflectance (TR) imaging. TR images at the microscopic self-heating hotspots within nanowire network and nanowire/graphene hybrid network devices with submicron spatial resolution are used to infer electrical current pathways. The results encourage a fundamental reevaluation of transport models for network-based percolating conductors.

  4. Advanced ultraviolet-resistant silver mirrors for use in solar reflectors

    DOE Patents [OSTI]

    Jorgensen, Gary J. (Pine, CO); Gee, Randy (Arvada, CO)

    2009-11-03

    A silver mirror construction that maintains a high percentage of hemispherical reflectance throughout the UV and visible spectrum when used in solar reflectors, comprising:a) a pressure sensitive adhesive layer positioned beneath a silver overlay;b) a polymer film disposed on the silver overlay;c) an adhesive layer positioned on the polymer film; andd) a UV screening acrylic film disposed on the adhesive layer.

  5. Electrical studies on silver based fast ion conducting glassy materials

    SciTech Connect (OSTI)

    Rao, B. Appa Kumar, E. Ramesh Kumari, K. Rajani Bhikshamaiah, G.

    2014-04-24

    Among all the available fast ion conductors, silver based glasses exhibit high conductivity. Further, glasses containing silver iodide enhances fast ion conducting behavior at room temperature. Glasses of various compositions of silver based fast ion conductors in the AgI?Ag{sub 2}O?[(1?x)B{sub 2}O{sub 3}?xTeO{sub 2}] (x=0 to1 mol% in steps of 0.2) glassy system have been prepared by melt quenching method. The glassy nature of the compounds has been confirmed by X-ray diffraction. The electrical conductivity (AC) measurements have been carried out in the frequency range of 1 KHz3MHz by Impedance Analyzer in the temperature range 303423K. The DC conductivity measurements were also carried out in the temperature range 300523K. From both AC and DC conductivity studies, it is found that the conductivity increases and activation energy decreases with increasing the concentration of TeO{sub 2} as well as with temperature. The conductivity of the present glass system is found to be of the order of 10{sup ?2} S/cm at room temperature. The ionic transport number of these glasses is found to be 0.999 indicating that these glasses can be used as electrolyte in batteries.

  6. Aging and iodine loading of silver-functionalized aerogels

    SciTech Connect (OSTI)

    Bruffey, S.H.; Jubin, R.T.; Anderson, K.K.; Walker, J.F. [Oak Ridge National Laboratory, P.O. Box 2008, MS-6223, Oak Ridge, TN 37831 (United States)

    2013-07-01

    Engineered silver-functionalized silica aerogels are being investigated for their potential application in off-gas treatment at a used nuclear fuel reprocessing facility. Reprocessing will release several key volatile radionuclides, including iodine-129. To achieve regulatory compliance, iodine-129 must be removed from any off-gas stream prior to environmental discharge. Ag{sup 0}-functionalized aerogels have been demonstrated to have high iodine-capture capacity, high porosity, and potential for conversion into a waste form. Capture materials used in off-gas treatment may be exposed to a heated, high-humidity, acidic gas stream for months. Extended exposure to this stream could affect sorbent performance. It was the aim of this study to evaluate what impacts might be observed when Ag{sup 0}-functionalized aerogels prepared at Pacific Northwest National Laboratory were contacted with a dry air stream for up to 6 months and then used to adsorb iodine from a synthetic off-gas stream. Results demonstrate that there is some loss of iodine-capture capacity caused by aging, but that this loss is not as marked as for aging of more traditional iodine sorbents, such as silver-impregnated mordenite. Specifically, aging silver-functionalized aerogel under a dry air stream for up to 6 months can decrease its iodine capacity from 41 wt% to 32 wt%. (authors)

  7. Water Sampling At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Silver Peak Area (Henkle, Et Al., 2005) Exploration Activity Details...

  8. Mercury Vapor At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Silver Peak Area (Henkle, Et Al., 2005) Exploration Activity Details...

  9. Durable silver mirror with ultra-violet thru far infra-red reflection

    DOE Patents [OSTI]

    Wolfe, Jesse D. (Discovery Bay, CA)

    2010-11-23

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  10. Thermal Gradient Holes At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Silver Peak Area (DOE GTP) Exploration Activity Details Location...

  11. Thermal And-Or Near Infrared At Silver Peak Area (DOE GTP) |...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal And-Or Near Infrared At Silver Peak Area (DOE GTP) Exploration Activity Details...

  12. Characterization of Dry-Air Aged Granules of Silver-Functionalized...

    Office of Scientific and Technical Information (OSTI)

    Silica Aerogel Matyas, Josef; Fryxell, Glen E.; Robinson, Matthew J. Reprocessing; Silver-functionalized arogel; Radioiodine; Aging; Sorption; BET; SEM; XRD...

  13. Durable silver thin film coating for diffraction gratings

    DOE Patents [OSTI]

    Wolfe, Jesse D. (Discovery Bay, CA); Britten, Jerald A. (Oakley, CA); Komashko, Aleksey M. (San Diego, CA)

    2006-05-30

    A durable silver film thin film coated non-planar optical element has been developed to replace Gold as a material for fabricating such devices. Such a coating and resultant optical element has an increased efficiency and is resistant to tarnishing, can be easily stripped and re-deposited without modifying underlying grating structure, improves the throughput and power loading of short pulse compressor designs for ultra-fast laser systems, and can be utilized in variety of optical and spectrophotometric systems, particularly high-end spectrometers that require maximized efficiency.

  14. Green synthesis and characterization of silver nanoparticle using Aloe barbadensis

    SciTech Connect (OSTI)

    Thappily, Praveen E-mail: shiiuvenus@gmail.com; Shiju, K. E-mail: shiiuvenus@gmail.com

    2014-10-15

    Green synthesis of silver nanoparticles was achieved by simple visible light irradiation using aloe barbadensis leaf extract as reducing agent. UV-Vis spectroscopic analysis was used for confirmation of the successful formation of nanoparticles. Investigated the effect of light irradiation time on the light absorption of the nanoparticles. It is observed that upto 25 minutes of light irradiation, the absorption is linearly increasing with time and after that it becomes saturated. Finally, theoretically fitted the time-absorption graph and modeled a relation between them with the help of simulation software.

  15. Silver-bearing, high-temperature, superconducting (HTS) paint

    SciTech Connect (OSTI)

    Ferrando, W.A.

    1990-02-15

    A substantial set of device applications awaits development of a workable, durable, high-temperature superconducting (HTS) paint. Such a paint should be truly superconducting with its critical temperature T sub c>77K. For most of these applications, a high critical current (J sub c) is not required, although probably desirable. A process is described which can be used to produce silver-bearing HTS paint coatings on many engineering materials. Preliminary tests have shown good adherence to several ceramics and the ability to meet the superconducting criteria. Moreover, the coatings withstand multiple thermal cycling and stability under laboratory ambient storage conditions for periods of at least several months.

  16. Infrared laser induced plasma diagnostics of silver target

    SciTech Connect (OSTI)

    Ahmat, L. Nadeem, Ali; Ahmed, I.

    2014-09-15

    In the present work, the optical emission spectra of silver (Ag) plasma have been recorded and analyzed using the laser induced breakdown spectroscopy technique. The emission line intensities and plasma parameters were investigated as a function of lens to sample distance, laser irradiance, and distance from the target surface. The electron number density (n{sub e}) and electron temperature (T{sub e}) were determined using the Stark broadened line profile and Boltzmann plot method, respectively. A gradual increase in the spectral line intensities and the plasma parameters, n{sub e} from 2.89??10{sup 17} to 3.92??10{sup 17?}cm{sup ?3} and T{sub e} from 4662 to 8967?K, was observed as the laser irradiance was increased 2.29??10{sup 10}1.06??10{sup 11} W cm{sup ?2}. The spatial variations in n{sub e} and T{sub e} were investigated from 0 to 5.25?mm from the target surface, yielding the electron number density from 4.78??10{sup 17} to 1.72??10{sup 17?}cm{sup ?3} and electron temperature as 98693789?K. In addition, the emission intensities and the plasma parameters of silver were investigated by varying the ambient pressure from 0.36 to 1000 mbars.

  17. Alternate protection concepts for second surface silver/glass solar mirrors

    SciTech Connect (OSTI)

    Buckwalter, C.Q.; Dake, L.S.; Hartman, J.S.; Lind, M.A.

    1980-10-01

    Investigations into three technologies having the potential of significantly enhancing the durability of solar mirrors are reported. The approaches are based on the assumption that sealing the silver layer on second surface mirrors from the external environment with protective overcoats will significantly extend their useful service life. Considered are: (1) edge sealing a second sheet of glass over the silver layer using solder glasses, (2) overcoating the silver layer with liquid applied SiO/sub 2/ or TiO/sub 2/ coatings, and (3) overcoating the silver layer with an electroless nickel film. Preliminary experiments were performed using Sb/sub 2/O/sub 5/-K/sub 2/O and PbO based solder glasses to edge seal a second sheet of glass over the silver mirror surface. Problems encountered in the formulation of the Sb/sub 2/O/sub 5/-K/sub 2/O glasses forced abandonment of these low melting point solder glass experiments. Materials compatibility problems were encountered when using several of the commercially available PbO based solder glasses alternatives. A cursory evaluation of liquid SiO/sub 2/ and TiO/sub 2/ coatings was also undertaken. The films were applied as direct overcoats on both silver only and silver/copper mirror substrates. Although the process appeared to yield visually acceptable coatings, under microscopic examination the films were found to be porous and pinhole riddled after the final curing step. Consequently, they did not stand up well to salt spray and HCl vapor tests. Background data were collected in an investigation of overcoating the silver or silver/copper mirrors with an electroless deposited nickel film. Two formulations, one a basic solution, the other a commercial acidic solution, were attempted. Film integrity problems were encountered for fairly thick films in the feasibility experiments attempted. Nevertheless, the concept appears sound and merits further investigation.

  18. Wetting and Mechanical Performance of Zirconia Brazed with Silver/Copper Oxide and Silver/Vanadium Oxide Alloys

    SciTech Connect (OSTI)

    Sinnamon, Kathleen E.; Meier, Alan; Joshi, Vineet V.

    2014-12-01

    The wetting behavior and mechanical strength of silver/copper oxide and silver/vanadium oxide braze alloys were investigated for both magnesia-stabilized and yttria-stabilized (Mg-PSZ and Y-TZP) transformation toughened zirconia substrates. The temperatures investigated were 1000 to 1100C, with oxide additions of 1 to 10 weight percent V2O5 or CuO, and hold times of 0.9 to 3.6 ks. Increasing either the isothermal hold temperature or time had a distinctly negative effect on the joint strength. The maximum strengths for both braze alloys were obtained for 5 wt. % oxide additions at 1050C with a hold time of 0.9 ks. The Mg-PSZ/Ag-CuO system exhibited a average fracture strength of 255 MPa (45% of the reported monolithic strength), and the Y-TZP/Ag-CuO system had an average fracture strength of 540 MPa (30% of the reported monolithic strength). The fracture strengths were lower for the Ag-V2O5 braze alloys, with fracture strengths of approximately 180 MPa (30% of the monolithic strength) for Mg-PSZ versus approximately 160 MPa (10% of the monolithic strength) for Y-TZP. No interfacial products were observed in low magnification SEM analysis for the brazing alloys containing V2O5 additions, while there were interfacial products present for brazes prepared with CuO additions in the braze alloy.

  19. Interactions between silver nanoparticles and polyvinyl alcohol nanofibers

    SciTech Connect (OSTI)

    Chou, H. L.; Wu, C. M.; Lin, F. D.; Rick, J.

    2014-08-15

    The interaction of polyvinylalcohol (PVA) nanofibers with silver (Ag) nanoparticles (mean diameter 8nm) has been modeled using density functional theory (DFT) calculations. The physical adsorption of PVA through the hydroxyl group, to the Ag, and its corresponding molecular orientation was compared with experimental results obtained from surface-enhanced Raman scattering (SERS) studies of the same material. A good agreement was found between the computational model of the vibrational spectrum of the adsorbate and the experimentally observed SERS. In general, aliphatic capping molecules are used to passivate the surface of Ag{sub 55} nanocrystals (55 = atomic number of Ag). In this study, a DFT simulation was employed to show binding energies and electron contour map analyses of Ag{sub 55} with PVA. Here we show that the PVA interacts with the Ag nanoparticle's surface, through the OH group, thereby contributing significantly to the increase in SERS activity.

  20. Precursor composites for oxygen dispersion hardened silver sheathed superconductor composites

    DOE Patents [OSTI]

    Podtburg, E.R.

    1999-06-22

    An oxide superconductor composite having improved texture and durability is disclosed. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor. 1 fig.

  1. Efficient incorporation of silver to improve superconducting fibers

    DOE Patents [OSTI]

    Gleixner, Richard A.; LaCount, Dale F.; Finnemore, Douglas K.

    1994-04-26

    An improved method for the efficient incorporation of a metal such as silver in a superconducting material includes blending the metal with a high temperature superconductor or precursor powder and consolidating the same into pellets. The pellets are charged directly into a heating assembly where it is melted and heated sufficiently to a uniform temperature prior to fiberization. Droplets of the melted blend fall through a collar into a nozzle where they are subjected to a high velocity gas to break the melted material into ligaments which solidify into improved flexible fibers having the metal homogeneously dis This invention was made with Government support under a contract with the Department of Energy (DOE) and Ames Laboratory, Contract No. SC-91-225, our reference No. CRD-1272. The Government has certain rights in this invention.

  2. Precursor composites for oxygen dispersion hardened silver sheathed superconductor composites

    DOE Patents [OSTI]

    Podtburg, Eric R. (Natick, MA)

    1999-01-01

    An oxide superconductor composite having improved texture and durability. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor.

  3. NPDES compliance monitoring report: Silver bell mine, Pima County, Arizona. Final report

    SciTech Connect (OSTI)

    Ganter, W.

    1992-10-01

    This presents the findings of a compliance evaluation inspection of the Silver Bell Mine in Pima County, Arizona, conducted on August 19, 1992. It is part of a series of inspections of uncontrolled discharges of mine drainage.

  4. The Science Behind the Silver Screen | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Science Behind the Silver Screen News News Home Featured Articles 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 Science Headlines Science Highlights Presentations & Testimony News Archives Communications and Public Affairs Contact Information Office of Science U.S. Department of Energy 1000 Independence Ave., SW Washington, DC 20585 P: (202) 586-5430 05.11.15 The Science Behind the Silver Screen Academy Award winner Doug Roble described the art - and science - of movie

  5. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized

    Office of Scientific and Technical Information (OSTI)

    Silica Aerogel (Technical Report) | SciTech Connect Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel Citation Details In-Document Search Title: Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel The U.S. Department of Energy is currently investigating alternative sorbents for the removal and immobilization of radioiodine from the gas streams in a nuclear fuel reprocessing plant. One of these new sorbents,

  6. Testimony of Jonathan Silver, Executive Director Loan Programs Office, U.S.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Before the Subcommittee on Oversight and Investigations Committee on Energy and Commerce U.S. House of Representatives | Department of Energy Testimony of Jonathan Silver, Executive Director Loan Programs Office, U.S. Department of Energy Before the Subcommittee on Oversight and Investigations Committee on Energy and Commerce U.S. House of Representatives Testimony of Jonathan Silver, Executive Director Loan Programs Office, U.S. Department of Energy Before the

  7. Silver-Mordenite for Radiologic Gas Capture from Complex Streams: Dual

    Office of Scientific and Technical Information (OSTI)

    Catalytic CH3I Decomposition and I Confinement (Journal Article) | SciTech Connect Journal Article: Silver-Mordenite for Radiologic Gas Capture from Complex Streams: Dual Catalytic CH3I Decomposition and I Confinement Citation Details In-Document Search Title: Silver-Mordenite for Radiologic Gas Capture from Complex Streams: Dual Catalytic CH3I Decomposition and I Confinement The effective capture and storage of radiological iodine (129I) remains a strong concern for safe nuclear waste

  8. Schneider Electric Goes Platinum-and Silver-in Superior Energy

    Energy Savers [EERE]

    Performance | Department of Energy Technical Assistance » Superior Energy Performance » Schneider Electric Goes Platinum-and Silver-in Superior Energy Performance Schneider Electric Goes Platinum-and Silver-in Superior Energy Performance October 1, 2014 - 11:33am Addthis Schneider Electric's Lexington, Kentucky facility. <em>Photo courtesy of Schneider Electric.</em> Schneider Electric's Lexington, Kentucky facility. Photo courtesy of Schneider Electric. AMO is proud to

  9. Aging of Iodine-Loaded Silver Mordenite in NO2

    SciTech Connect (OSTI)

    Bruffey, Stephanie H.; Jubin, Robert Thomas; Patton, Kaara K.; Walker Jr, Joseph Franklin

    2014-04-01

    Used nuclear fuel facilities need to control and minimize radioactive emissions. Off-gas systems are designed to remove radioactive contaminants, such as 85Kr, 14C, 3H, and 129I. In an off-gas system, any capture material will be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water, NOx gas, or a variety of other constituents comprising the dissolver off-gas stream in a nuclear fuel reprocessing plant. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed capture materials. One material under consideration is reduced silver mordenite (Ag0Z), which is recognized for its efficient iodine capture properties. Iodine is immobilized on Ag0Z as AgI, a solid with low volatility (m.p. ? 500C). The aim of this study was to determine whether extended aging at elevated temperature in a nominally 2% NO2 environment would result in a loss of immobilized iodine from this material due to either physical or chemical changes that might occur during aging. Charges of iodine-loaded reduced silver mordenite (I2-Ag0Z) were exposed to a 2% NO2 environment for 1, 2, 3, and 4 months at 150C, then analyzed for iodine losses The aging study was completed successfully. The material did not visibly change color or form. The results demonstrate that no significant iodine loss was observed over the course of 4 months of 2% NO2 aging of I2-Ag0Z at elevated temperature within the margin of error and the variability (~10%) in the loading along the beds. This provides assurance that iodine will remain immobilized on Ag0Z during extended online use in an off-gas capture treatment system. Future tests should expose I2-Ag0Z to progressively more complex feed gases in an effort to accurately replicate the conditions expected in a reprocessing facility.

  10. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel

    SciTech Connect (OSTI)

    Nick Soelberg; Tony Watson

    2012-06-01

    Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I129, due to its radioactivity, high potential mobility in the environment, and high longevity (half life of 15.7 million years), can require control efficiencies of up to 1,000x or higher to meet regulatory emission limits. Two Aerogel sorption tests that have been performed this fiscal year. The maximum iodine decontamination factor (DF) was measured to be over 10,000, above the 1,000-10,000 target DF range. The mass transfer zone may be as short as 0.5 inches under the sorption conditions of the first test. Only a small fraction of the iodine sorbed on Bed 1 was desorbed during the purge periods. The silver-functionalized Aerogel appears to have potential to be a very effective and efficient iodine sorbent.

  11. Rapid Responding Palladium-Silver Surface Modified Microsensor for Hydrogen

    SciTech Connect (OSTI)

    Patton, James; Hunter, Scott Robert; Sepaniak, Michael; Datskos, Panos G; Smith, Barton

    2010-01-01

    Most palladium thin film based hydrogen gas sensors have response and recovery times that are too long to make them useful in vehicular and stationary gas leak detection applications. In contrast, a palladium-silver thin film based microcantilever (MC) hydrogen gas microsensor is reported herein with near ideal response characteristics for use in these hydrogen economy related applications. Specifically, 3-10 second response and recovery times have been measured for these sensors in contrast to previous sensor response measurements of several to tens of minutes using Pd thin film and MC based sensing techniques. The much reduced response times observed in the present study are attributed to a wet chemical Pd-Ag thin film deposition technique and a gas conditioning protocol that produces a highly nanostructured, porous film that rapidly adsorbs and desorbs H2, allowing rapid equilibration with the H2 concentration in the surrounding air. The wet chemical process and gas phase conditioning offer a novel approach at creating highly structured surfaces that have not been reported for MC devices. Additionally, these sensors have very low H2 detection thresholds, wide dynamic range and very good selectivity relative to common interferents.

  12. California's 12th congressional district: Energy Resources |...

    Open Energy Info (EERE)

    Biodiesel Inc TerraPass Inc Tesla Motors Tesla Motors Inc The Gordon and Betty Moore Foundation The Vote Solar Initiative Tioga Energy Tioga Energy Inc Trilliant Inc...

  13. Method for the recovery of silver from waste photographic fixer solutions

    DOE Patents [OSTI]

    Posey, Franz A. (Concord, TN); Palko, Aloysius A. (Oak Ridge, TN)

    1984-01-01

    The method of the present invention is directed to the recovery of silver from spent photographic fixer solutions and for providing an effluent essentially silver-free that is suitable for discharge into commercial sewage systems. The present method involves the steps of introducing the spent photographic fixer solution into an alkaline hypochlorite solution. The oxidizing conditions of the alkaline hypochlorite solution are maintained during the addition of the fixer solution so that the silver ion complexing agents of thiosulfate and sulfite ions are effectively destroyed. Hydrazine monohydrate is then added to the oxidizing solution to form a reducing solution to effect the formation of a precipitate of silver which can be readily removed by filtration or decanting. Experimental tests indicate that greater than 99.99% of the original silver in the spent photographic fixer can be efficiently removed by practicing the present method. Also, the chemical and biological oxygen demand of the remaining effluent is significantly reduced so as to permit the discharge thereof into sewage systems at levels in compliance with federal and state environmental standards.

  14. Studies of n-butane conversion over silica-supported platinum, platinum-silver and platinum-copper catalysts

    SciTech Connect (OSTI)

    Gu, Junhua

    1992-06-09

    The present work was undertaken to elucidate effect of adding silver and copper to silica-supported platinum catalyst on the activity and selectivity in the n-butane reactions. At the conditions of this study n-butane underwent both hydrogenolysis and structural isomerization. The catalytic activity and selectivities between hydrogenolysis and isomerization and within hydrogenolysis were measured at temperature varying from 330 C to 370 C. For platinum-silver catalysts, at lower temperatures studied the catalytic activity per surface platinum atom (turnover frequency) remained constant at lower silver content (between 0 at. % and 30 at. %) and decreased with further increased silver loading, suggesting that low- index planes could be dominant in the hydrogenolysis of n-butane. Moreover, increasing silver content resulted in an enhancement of the selectivity of isomerization products relative to hydrogenolysis products. At the higher temperature studied, no suppression in catalytic activity was observed. It is postulated that surface structure could change due to the mobility of surface silver atoms, leading to surface silver atoms forming islands or going to the bulk, and leaving large portions of basal planes exposed with active platinum atoms. It is also suggested that the presence of inert silver atoms results in weakening of the H-surface bond. This results in increased mobility of hydrogen atoms on the surface and hence, higher reactivity with other adsorbed species. For platinum copper catalysts, the mixed ensembles could play an active role in the hydrogenolysis of n-butane.

  15. Method of bonding silver to glass and mirrors produced according to this method

    DOE Patents [OSTI]

    Pitts, John R. (Golden, CO); Thomas, Terence M. (Arvada, CO); Czanderna, Alvin W. (Lakewood, CO)

    1985-01-01

    A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

  16. Method of bonding silver to glass and mirrors produced according to this method

    DOE Patents [OSTI]

    Pitts, J.R.; Thomas, T.M.; Czanderna, A.W.

    1984-07-31

    A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

  17. Localized surface plasmon and exciton interaction in silver-coated cadmium sulphide quantum dots

    SciTech Connect (OSTI)

    Ghosh, P.; Rustagi, K. C.; Vasa, P.; Singh, B. P.

    2015-05-15

    Localized surface plasmon and exciton coupling has been investigated on colloidal solutions of silver-coated CdS nanoparticles (NPs), synthesized by gamma irradiation. Two broad photoluminescence (PL) bands (blue/red) corresponding to band to band and defect state transitions have been observed for the bare and coated samples. In case of bare CdS NPs, the intensity of the red PL peak is about ten times higher than the blue PL peak intensity. However, on coating the CdS NPs with silver, the peak intensity of the blue PL band gets enhanced and becomes equal to that of the red PL band. High-resolution transmission electron microscopic (HRTEM) images adequately demonstrate size distribution of these metal/semiconductor nanocomposites. UV-Vis absorption studies show quantum confinement effect in these semiconductor quantum dot (SQD) systems. Absorption spectrum of silver-coated SQDs shows signature of surface plasmon-exciton coupling which has been theoretically verified.

  18. Fabrication and characterization of silver- and copper-coated Nylon 6 forcespun nanofibers by thermal evaporation

    SciTech Connect (OSTI)

    Mihut, Dorina M., E-mail: dorinamm@yahoo.com; Lozano, Karen [Department of Mechanical Engineering, The University of Texas Pan American, 1201 W University Drive, Edinburg, Texas 78539 (United States); Foltz, Heinrich [Department of Electrical Engineering, The University of Texas Pan American, 1201 W University Drive, Edinburg, Texas 78539 (United States)

    2014-11-01

    Silver and copper nanoparticles were deposited as thin films onto substrates consisting of Nylon 6 nanofibers manufactured using forcespinning{sup } equipment. Different rotational speeds were used to obtain continuous nanofibers of various diameters arranged as nonwoven mats. The Nylon 6 nanofibers were collected as successive layers on frames, and a high-vacuum thermal evaporation method was used to deposit the silver and copper thin films on the nanofibers. The structures were investigated using scanning electron microscopyscanning transmission electron microscopy, atomic force microscopy, x-ray diffraction, and electrical resistance measurements. The results indicate that evaporated silver and copper nanoparticles were successfully deposited on Nylon 6 nanofibers as thin films that adhered well to the polymer substrate while the native morphology of the nanofibers were preserved, and electrically conductive nanostructures were achieved.

  19. Cavitation erosion of silver plated coating at different temperatures and pressures

    SciTech Connect (OSTI)

    Hattori, Shuji; Motoi, Yoshihiro; Kikuta, Kengo; Tomaru, Hiroshi

    2014-04-11

    Cavitation often occurs in inducer pumps used for space rockets. Silver plated coating on the inducer liner faces the damage of cavitation. Therefore, it is important to study about the cavitation erosion resistance for silver plated coating at several operating conditions in the inducer pumps. In this study, the cavitation erosion tests were carried for silver plated coating in deionized water and ethanol at several liquid temperatures (273K400K) and pressures (0.10MPa0.48MPa). The mass loss rate is evaluated in terms of thermodynamic parameter ? proposed by Brennen [9], suppression pressure pp{sub v} (p{sub v}: saturated vapor pressure) and acoustic impedance ?c (?: density and c: sound speed). Cavitation bubble behaviors depending on the thermodynamic effect and the liquid type were observed by high speed video camera. The mass loss rate is formulated by thermodynamic parameter ?, suppression pressure pp{sub v} and acoustic impedance ?c.

  20. Spectroscopic evidence for Ag(III) in highly oxidized silver films by x-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.; Bagus, Paul S.

    2010-12-16

    In situ x-ray photoelectron spectroscopy (XPS) was utilized to identify the chemical state of silver in a range of silver oxide thin films obtained by co-deposition of silver and atomic oxygen. A highly oxidized silver species was observed at an unexpectedly low Ag 3d5/2 binding energy (BE) of 366.8 eV with an associated broad satellite at 368.2 eV; this species was assigned as Ag(III). It was found to be highly unstable in vacuum, but could be regenerated by further exposure to atomic oxygen. Both BE shifts and intensity changes of the O 1s peak were found to correlate with changes in the silver oxidation state. Theoretical calculations of the expected XPS of high spin Ag(III) provide insight into the significance of satellite structure and shake features in the Ag 3d spectra.

  1. From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produced | Department of Energy From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced June 17, 2015 - 9:42am Addthis First Solar acquired TetraSun and its unique crystalline silicon solar cell technology, which will soon begin mass production. First Solar acquired TetraSun and its unique crystalline silicon solar cell technology, which will soon begin mass production. Consumers will

  2. Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica

    Office of Scientific and Technical Information (OSTI)

    Aerogel (Technical Report) | SciTech Connect Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel Citation Details In-Document Search Title: Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel This is a letter report to complete level 3 milestone "Assess aging characteristics of silica aerogels" for DOE FCRD program. Recently, samples of Ag0-functionalized silica aerogel were aged in flowing dry air for up to 6 months and then loaded with

  3. Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerogel (Technical Report) | SciTech Connect Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel Citation Details In-Document Search Title: Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel This is a letter report to complete level 3 milestone "Assess aging characteristics of silica aerogels" for DOE FCRD program. Recently, samples of Ag0-functionalized silica aerogel were aged in flowing dry air for up to 6 months and

  4. From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produced | Department of Energy From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced June 17, 2015 - 9:42am Addthis First Solar acquired TetraSun and its unique crystalline silicon solar cell technology, which will soon begin mass production. First Solar acquired TetraSun and its unique crystalline silicon solar cell technology, which will soon begin mass production. Consumers will

  5. The Effect of Atmosphere on the Interdiffusion of Silver and Palladium

    SciTech Connect (OSTI)

    Garino, Terry; Rodriguez, Mark

    1999-07-14

    Conductor inks containing silver and palladium, used in ceramic co-fired circuits, sometimes undergo an anomalously large expansion during heating in the temperature range where interdiffusion occurs. Therefore, the interdiffusion of silver and palladium was studied during heating in both air and argon using both powder and foil samples. Measurements on a powder compact made of a mixture of Ag and Pd (80% Ag) particles indicated that a very rapid expansion occurred between 375 and 400 C when heated in air but only a slight expansion occurred in Ar. A pre-alloyed powder with the same composition did not expand during heating. In situ high temperature x-ray diffraction studies indicated that both powders oxidized during heating in air, with the mixture oxidizing more and that interdiffusion occurred between 300 and 500 C. Microstructural examination indicated that larger particles with internal pores had formed in the mixture heated in air to 375 C due to rearrangement during interdiffusion. A porous region much thicker than the original silver film formed on a palladium foil sample when it was heated in air, whereas in inert atmosphere pores formed only in the silver film, indicating a Kirkendall effect occurs in both cases. Based on these results, it was concluded that the expansion of the Ag-Pd powder mixture was due to interdiffusion in the presence of oxygen, not solely to the oxidation of the Pd.

  6. Copper-silver-titanium-tin filler metal for direct brazing of structural ceramics

    DOE Patents [OSTI]

    Moorhead, Arthur J. (Knoxville, TN)

    1988-04-05

    A method of joining ceramics and metals to themselves and to one another at about 800.degree. C. is described using a brazing filler metal consisting essentially of 35 to 50 at. % copper, 40 to 50 at. % silver, 1 to 15 at. % titanium, and 2 to 8 at. % tin. This method produces strong joints that can withstand high service temperatures and oxidizing environments.

  7. Pure silver ohmic contacts to N- and P- type gallium arsenide materials

    DOE Patents [OSTI]

    Hogan, Stephen J. (Golden, CO)

    1986-01-01

    Disclosed is an improved process for manufacturing gallium arsenide semiconductor devices having as its components an n-type gallium arsenide substrate layer and a p-type gallium arsenide diffused layer. The improved process comprises forming a pure silver ohmic contact to both the diffused layer and the substrate layer, wherein the n-type layer comprises a substantially low doping carrier concentration.

  8. Process for forming pure silver ohmic contacts to N- and P-type gallium arsenide materials

    DOE Patents [OSTI]

    Hogan, S.J.

    1983-03-13

    Disclosed is an improved process for manufacturing gallium arsenide semiconductor devices having as its components a n-type gallium arsenide substrate layer and a p-type gallium arsenide diffused layer. The improved process comprises forming a pure silver ohmic contact to both the diffuse layer and the substrate layer wherein the n-type layer comprises a substantially low doping carrier concentration.

  9. Copper-silver-titanium filler metal for direct brazing of structural ceramics

    DOE Patents [OSTI]

    Moorhead, Arthur J. (Knoxville, TN)

    1987-01-01

    A method of joining ceramics and metals to themselves and to one another is described using a brazing filler metal consisting essentially of 35 to 50 atomic percent copper, 15 to 50 atomic percent silver and 10 to 45 atomic percent titanium. This method produces strong joints that can withstand high service temperatures and oxidizing environments.

  10. Synthesis of silver nanoparticles by chemical reduction at various fraction of MSA and their structure characterization

    SciTech Connect (OSTI)

    Diantoro, Markus Fitrianingsih, Rina Mufti, Nandang Fuad, Abdulloh

    2014-03-24

    Nanosilver is currently one of the most common engineered nanomaterials and is used in many applications that lead to the release of silver nanoparticles and silver ions into aqueous systems. Nanosilver also possesses enhanced antimicrobial activity and bioavailability that may less environmental risk compared with other manufactured nanomaterials. Described in this research are the synthesis of silver nanoparticle produced by chemical reduction from silver nitrate (AgNO{sub 3}) solution. As a reducing agent, Sodium Borohydride (NaBH{sub 4}) was used and mercaptosuccinic Acid (MSA) as stabilizer to prevent the nanoparticle from aglomerating. It was also used two kinds of solvent, they are water and methanol. In typical experiment MSA was dissolve in methanol with a number of variation of molarity i.e. 0,03 M, 0,06 M, 0,12 M, 0,15 M, and the mixture was kept under vigorous stirring in an ice bath. A solution of silver nitrate of 340 mg in 6,792 ml water was added. A freshly prepared aqueous solution of sodium borohydride (756,6 mL in 100 mL of water) was added drop wisely. The solution was kept for half an hour for stirring and were allowed to settle down in methanol. The obtained samples then characterized by means of x-ray diffractometer, and scanning electron microscopy, as well as transmission electron microscopy to obtain their structures of silver nanoparticles, morphology, and sizes. It is shown that diameter of silver nanoparticle sized about 24.3 nm (Ag@MSA 0.03 M), 20.4 nm (Ag@MSA 0.06 M), 16.8 nm (Ag@MSA 0.12 M), 16.9 nm (Ag@MSA 0.15 M) which was calculated by Scherrer formula by taking the FWHM from fitting to Gaussian. The phases and lattice parameter showed that there is no significant change in its volume by increasing molarity of stabilizer. In contrast, the size of particles is decreasing.

  11. Identification of Silver and Palladium in Irradiated TRISO Coated Particles of the AGR-1 Experiment

    SciTech Connect (OSTI)

    van Rooyen, Y. J.; Lillo, T. M.; Wu, Y. Q.

    2014-03-01

    Evidence of the release of certain metallic fission product through intact tristructural isotropic (TRISO) particles has been seen for decades around the world, as well as in the recent AGR-1 experiment at Idaho National Laboratory (INL). However, understanding the basic mechanism of transport is still lacking. This understanding is important because the TRISO coating is part of the high temperature gas reactor functional containment and critical for the safety strategy for licensing purposes. Our approach to identify fission products in irradiated AGR-1 TRISO fuel using scanning transmission electron microscopy (STEM), Electron Energy Loss Spectroscopy (EELS) and Energy Filtered TEM (EFTEM), has led to first-of-a-kind data at the nano-scale indicating the presence of silver at triple points and grain boundaries of the SiC layer in the TRISO particle. Cadmium was also found in the triple junctions. In this initial study, the silver was only identified in SiC grain boundaries and triple points on the edge of the SiC-IPyC interface up to a depth of approximately 0.5 um. Palladium was identified as the main constituent of micron-sized precipitates present at the SiC grain boundaries. Additionally spherical nano-sized palladium rich precipitates were found inside the SiC grains. These nano-sized Pd precipitates were distributed up to a depth of 5 um away from the SiC-IPyC interlayer. No silver was found in the center of the micron-sized fission product precipitates using these techniques, although silver was found on the outer edge of one of the Pd-U-Si containing precipitates which was facing the IPyC layer. Only Pd-U containing precipitates were identified in the IPyC layer and no silver was identified in the IPyC layer. The identification of silver alongside the grain boundaries and the findings of Pd alongside grain boundaries as well as inside the grains, provide significant knowledge for understanding silver and palladium transport in TIRSO fuel, which has been the topic of international research for the past forty years. Additionally the usefulness of the advanced electron microscopic techniques for TRISO coated particle research is demonstrated in this paper.

  12. Thermal conductivity studies of novel nanofluids based on metallic silver decorated mesoporous silica nanoparticles

    SciTech Connect (OSTI)

    Tadjarodi, Azadeh; Zabihi, Fatemeh

    2013-10-15

    Graphical abstract: - Highlights: Metallic silver was decorated in mSiO{sub 2} with grafted hemiaminal functional groups. Synthesized nanoparticles were used for preparation of glycerol based nanofluids. The effect of temperature, weight fraction of mSiO{sub 2} and concentration of silver nanoparticles on thermal conductivity of nanofluids was investigated. - Abstract: In the present study, the mesoporous structure of silica (mSiO{sub 2}) nanoparticles as well as hemiaminal grafted mSiO{sub 2} decorated by metallic silver (Ag/mSiO{sub 2}) has been used for the preparation of glycerol based nanofluids. Structural and morphological characterization of the synthesized products have been carried out using Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), UVvis spectroscopy, inductively coupled plasma (ICP) and N{sub 2} adsorptiondesorption isotherms. The thermal conductivity and viscosity of the nanofluids have been measured as a function of temperature for various weight fractions and silver concentrations of mSiO{sub 2} and Ag/mSiO{sub 2} nanoparticles, respectively. The results show that the thermal conductivity of the nanofluids increase up to 9.24% as the weight fraction of mSiO{sub 2} increases up to 4 wt%. Also, increasing the percent of the silver decorated mSiO{sub 2} (Ag/mSiO{sub 2}) up to 2.98% caused an enhancement in the thermal conductivity of the base fluid up to 10.95%. Furthermore, the results show that the nanofluids have Newtonian behavior in the tested temperature range for various concentrations of nanoparticles.

  13. Large magnetoresistance in non-magnetic silver chalcogenides and new class of magnetoresistive compounds

    DOE Patents [OSTI]

    Saboungi, Marie-Louis; Price, David C. L.; Rosenbaum, Thomas F.; Xu, Rong; Husmann, Anke

    2001-01-01

    The heavily-doped silver chalcogenides, Ag.sub.2+.delta. Se and Ag.sub.2+.delta. Te, show magnetoresistance effects on a scale comparable to the "colossal" magnetoresistance (CMR) compounds. Hall coefficient, magnetoconductivity, and hydrostatic pressure experiments establish that elements of narrow-gap semiconductor physics apply, but both the size of the effects at room temperature and the linear field dependence down to fields of a few Oersteds are surprising new features.

  14. Silver decorated titanate/titania nanostructures for efficient solar driven photocatalysis

    SciTech Connect (OSTI)

    Gong, Dangguo; Ho, Weng Chye Jeffrey; Tang Yuxin; Tay Qiuling; Lai Yuekun; Highfield, James George; Chen Zhong

    2012-05-15

    Photocatalysis has attracted significant interest to solve both the energy crisis and effectively combat environmental contamination. However, as the most widely used photocatalyst, titania (TiO{sub 2}) suffers from inefficient utilization of solar energy due to its wide band gap. In the present paper, we describe a method to extend the absorption edge of photocatalyst to visible region by the surface plasmon effect of silver. Silver ions are photo-reduced onto the surface of titanate nanotubes, which are synthesized by a conventional hydrothermal method. The as-synthesized Ag/titanate composite is transformed into Ag/titania nanoparticles by annealing at different temperatures. It is found that the interaction of Ag nanoparticles with the supports (titanate/titania) plays a key role for the visible light activity. The samples annealed at low temperature (<350 Degree-Sign C) do not show significant activity under our conditions, while the one annealed at 450 Degree-Sign C shows fast-degradation of methyl orange (MO) under visible light irradiation. The detailed mechanisms are also discussed. - Graphical abstract: Silver nanoparticles decorated titanate/titania as visible light active photocatalysts: silver nanoparticles could be excited by visible light due to its surface plasmon effect and excited electrons could be transferred to the conduction band of the semiconductor, where the reduction process occurs. Highlights: Black-Right-Pointing-Pointer Uniform Ag nanoparticles are photo-reduced onto titanate and titania nanostructures. Black-Right-Pointing-Pointer Titania crystal is formed by annealing hydrogen titanate at different temperatures. Black-Right-Pointing-Pointer Best visible-light activity is achieved by Ag-loaded titania annealed at 450 Degree-Sign C. Black-Right-Pointing-Pointer The visible light activity is attributed to the surface plasmonic resonance effect.

  15. Rolling contact fatigue in high vacuum using ion plated nickel-copper-silver solid lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2011-01-15

    Ion plated, nickel-copper-silver coated steel ball bearings that were tested in rolling contact fatigue (RCF) experiments in high vacuum are presented in this article. ANSI T5 ball bearings were coated with approximately 10 nm of nickel-copper followed by 100 nm of silver using a dc ion plating process. The balls were then tested for RCF in vacuum in the 10{sup -7} Torr range at 130 Hz rotational speed and at 4.1 GPa Hertzian contact stress. The significance of this work is in the extension of RCF testing to an ultrahigh vacuum (UHV) application using silver as a lubricant instead of oil. The effects of pressure and voltage on the ion plating process were also investigated using scanning electron microscopy and RCF life testing in UHV. Test results with a ball size of 5/16 in. in UHV show that deposition at voltages greater than 2.5 kV shortens the RCF life and introduces a unique failure mode. Voltage and pressure fluctuations during the deposition process result in significant thickness monitor measurement errors as well. A regulator control scheme that minimizes the process pressure overshoot is also simulated.

  16. Selective light sintering of Aerosol-Jet printed silver nanoparticle inks on polymer substrates

    SciTech Connect (OSTI)

    Schuetz, K. E-mail: hoerber@faps.uni-erlangen.de Hoerber, J. E-mail: hoerber@faps.uni-erlangen.de Franke, J. E-mail: hoerber@faps.uni-erlangen.de

    2014-05-15

    Printing silver nanoparticle inks to generate conductive structures for electronics on polymer substrates has gained increasing relevance in recent years. In this context, the Aerosol-Jet Technology is well suited to print silver ink on 3D-Molded Interconnect Devices (MID). The deposited ink requires thermal post-treatment to obtain sufficient electrical conductivity and adhesion. However, commonly used oven sintering cannot be applied for many thermoplastic substrates due to low melting temperatures. In this study a new sintering technology, selective light sintering, is presented, based on the focused, continuous light beam of a xenon lamp. Sintering experiments were conducted with Aerosol-Jet printed structures on various polycarbonate (PC) substrates. Especially on neat, light transparent PC, silver tracks were evenly sintered with marginal impact to the substrate. Electrical conductivities significantly exceed the values obtained with conventional oven sintering. Adhesive strength is sufficient for conductive tracks. Experiments with non-transparent PC substrates led to substrate damage due to increased light absorption. Therefore a concept for a variation of light sintering was developed, using optical filters. First experiments showed significant reduction of substrate damage and good sintering qualities. The highly promising results of the conducted experiments provide a base for further investigations to increase adhesion and qualifying the technology for MID applications and a broad spectrum of thermoplastic substrates.

  17. The surface structure of silver-coated gold nanocrystals and its influence on shape control

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Padmos, J. Daniel; Personick, Michelle L.; Tang, Qing; Duchesne, Paul N.; Jiang, De-en; Mirkin, Chad A.; Zhang, Peng

    2015-07-08

    Understanding the surface structure of metal nanocrystals with specific facet indices is important due to its impact on controlling nanocrystal shape and functionality. However, this is particularly challenging for halide-adsorbed nanocrystals due to the difficulty in analysing interactions between metals and light halides (for example, chloride). Here we uncover the surface structures of chloride-adsorbed, silver-coated gold nanocrystals with {111}, {110}, {310} and {720} indexed facets by X-ray absorption spectroscopy and density functional theory modelling. The silver–chloride, silver–silver and silver–gold bonding structures are markedly different between the nanocrystal surfaces, and are sensitive to their formation mechanism and facet type. A uniquemore » approach of combining the density functional theory and experimental/simulated X-ray spectroscopy further verifies the surface structure models and identifies the previously indistinguishable valence state of silver atoms on the nanocrystal surfaces. Overall, this work elucidates the thus-far unknown chloride–metal nanocrystal surface structures and sheds light onto the halide-induced growth mechanism of anisotropic nanocrystals.« less

  18. The surface structure of silver-coated gold nanocrystals and its influence on shape control

    SciTech Connect (OSTI)

    Padmos, J. Daniel; Personick, Michelle L.; Tang, Qing; Duchesne, Paul N.; Jiang, De-en; Mirkin, Chad A.; Zhang, Peng

    2015-07-08

    Understanding the surface structure of metal nanocrystals with specific facet indices is important due to its impact on controlling nanocrystal shape and functionality. However, this is particularly challenging for halide-adsorbed nanocrystals due to the difficulty in analysing interactions between metals and light halides (for example, chloride). Here we uncover the surface structures of chloride-adsorbed, silver-coated gold nanocrystals with {111}, {110}, {310} and {720} indexed facets by X-ray absorption spectroscopy and density functional theory modelling. The silver–chloride, silver–silver and silver–gold bonding structures are markedly different between the nanocrystal surfaces, and are sensitive to their formation mechanism and facet type. A unique approach of combining the density functional theory and experimental/simulated X-ray spectroscopy further verifies the surface structure models and identifies the previously indistinguishable valence state of silver atoms on the nanocrystal surfaces. Overall, this work elucidates the thus-far unknown chloride–metal nanocrystal surface structures and sheds light onto the halide-induced growth mechanism of anisotropic nanocrystals.

  19. Unusual adsorption properties of silver adlayers on the Pt(111) electrode surface

    SciTech Connect (OSTI)

    Marinkovic, N.S.; Wang, J.X.; Adzic, R.R.; Marinkovic, J.S.

    1999-01-07

    Adsorption properties of silver monolayer and bilayer deposited at underpotentials on a Pt(111) electrode were studied by means of linear sweep voltammetry, in situ surface X-ray scattering and infrared spectroelectrochemistry. Surface X-ray scattering measurements show a pseudomorphic Ag monolayer and an incommensurate expanded bilayer on Pt(111) formed at underpotentials. Unusual adsorption properties of the silver layers with respect to the bulk silver are observed. The two Ag adlayers were found to have intermediate adsorption/oxidation characteristics between those of metallic Ag and Pt surfaces with (111) orientation. The Ag monolayer has properties that facilitate adsorption of bisulfate anions and adsorption and oxidation of CO. These properties are closer to the adsorption properties of the Pt(111) surface than to those of Ag(111), which adsorbs sulfate anions and does not adsorb CO. The Ag bilayer on the Pt(111) surface adsorbs sulfate anions as Ag(111) does, but in contrast to the behavior of Ag(111), it adsorbs CO. These properties of the Ag adlayers appear to be a consequence of the charge-transfer process and the electron distribution in the Ag/Pt(111) surface.

  20. Hypoxia inducible factor-1 (HIF-1)flavin containing monooxygenase-2 (FMO-2) signaling acts in silver nanoparticles and silver ion toxicity in the nematode, Caenorhabditis elegans

    SciTech Connect (OSTI)

    Eom, Hyun-Jeong; Ahn, Jeong-Min; Kim, Younghun; Choi, Jinhee

    2013-07-15

    In the present study, nanotoxicity mechanism associated with silver nanoparticles (AgNPs) exposure was investigated on the nematode, Caenorhabditis elegans focusing on the hypoxia response pathway. In order to test whether AgNPs-induced hypoxia inducible factor-1 (HIF-1) activation was due to hypoxia or to oxidative stress, depletion of dissolved oxygen (DO) in the test media and a rescue effect using an antioxidant were investigated, respectively. The results suggested that oxidative stress was involved in activation of the HIF-1 pathway. We then investigated the toxicological implications of HIF-1 activation by examining the HIF-1 mediated transcriptional response. Of the genes tested, increased expression of the flavin containing monooxygenase-2 (FMO-2) gene was found to be the most significant as induced by AgNPs exposure. We found that AgNPs exposure induced FMO-2 activation in a HIF-1 and p38 MAPK PMK-1 dependent manner, and oxidative stress was involved in it. We conducted all experiments to include comparison of AgNPs and AgNO{sub 3} in order to evaluate whether any observed toxicity was due to dissolution or particle specific. The AgNPs and AgNO{sub 3} did not produce any qualitative differences in terms of exerting toxicity in the pathways observed in this study, however, considering equal amount of silver mass, in every endpoint tested the AgNPs were found to be more toxic than AgNO{sub 3}. These results suggest that Ag nanotoxicity is dependent not only on dissolution of Ag ion but also on particle specific effects and HIF-1FMO-2 pathway seems to be involved in it. - Highlights: HIF-1 signaling was investigated in C. elegans exposed to AgNPs and AgNO{sub 3}. HIF-1 and PMK-1 were needed for AgNPs- and AgNO{sub 3}-induced fmo-2 gene expression. PMK-1HIF-1FMO-2 pathway was dependent on oxidative stress. AgNPs and AgNO{sub 3} did not produce any qualitative differences in HIF-1 signaling. AgNPs were more toxic than an equal amount of silver mass contained in AgNO{sub 3}.

  1. Copper- and silver-zirconia aerogels: Preparation, structural properties and catalytic behavior in methanol synthesis from carbon dioxide

    SciTech Connect (OSTI)

    Koeppel, R.A.; Stoecker, C.; Baiker, A. [Swiss Federal Inst. of Technology, Zuerich (Switzerland). Lab. of Technical Chemistry] [Swiss Federal Inst. of Technology, Zuerich (Switzerland). Lab. of Technical Chemistry

    1998-10-25

    Copper- and silver-zirconia aerogels containing 10 at% IB metal were prepared from tetra-n-butoxy zirconium(IV) and IB metal acetates using the solution sol-gel method and ensuring high-temperature (HT) and low-temperature (LT) supercritical drying, respectively. The influence of preparation parameters and calcination on the structural and catalytic properties of the aerogels for the synthesis of methanol from carbon dioxide and hydrogen was investigated. After calcination in air at 573 K, the catalysts had BET surface areas in the range of 100--143 m{sup 2}/g (Cu/ZrO{sub 2}) and 77--125 m{sup 2}/g (Ag/ZrO{sub 2}), respectively. Due to the reductive alcoholic atmosphere during high-temperature supercritical drying, metallic copper and silver existed in all raw HT-aerogels. The mean size of the copper crystallites wa/s 30 nm. The silver crystallite size for the HT-aerogel prepared with nitric acid was 10 nm, whereas for samples prepared with acetic acid it was 5--7 nm. Calcination in air at 573 K led to the formation of highly dispersed amorphous copper oxide and silver. Comparing the catalytic behavior of the calcined copper-zirconia aerogels with corresponding xerogels prepared by coprecipitation revealed highest activity for the LT-aerogel, whereas the HT-aerogels were least active. In contrast, similar catalytic behavior was observed for the differently dried silver-zirconia samples. Generally, CO{sub 2}-conversion of the copper-zirconia samples. Generally, CO{sub 2}-conversion of the copper-zirconia aerogels was markedly higher than that of the corresponding silver-zirconia aerogels, whereas methanol selectivity was similar.

  2. Size dependence of cubic to trigonal structural distortion in silver micro- and nanocrystals under high pressure

    SciTech Connect (OSTI)

    Guo, Qixum; Zhao, Yusheng; Zin, Zhijun; Wang, Zhongwu; Skrabalak, Sara E; Xia, Younan

    2008-01-01

    Silver micro- and nanocrystals with sizes of {approx}2--3.5 {mu}m and {approx}50--100 nm were uniaxially compressed under nonhydrostatic pressures (strong deviatoric stress) up to {approx}30 GPa at room temperature in a symmetric diamond-anvil cell and studied in situ using angle-dispersive synchrotron X-ray diffraction. A cubic to trigonal structural distortion along a 3-fold rotational axis was discovered by careful and comprehensive analysis of the apparent lattice parameter and full width at half-maximum, which are strongly dependent upon the Miller index and crystal size.

  3. Preparation of silver nanoparticles/graphene nanosheets as a catalyst for electrochemical oxidation of methanol

    SciTech Connect (OSTI)

    Han, Kun; Miao, Peng; Tang, Yuguo; Tong, Hui; Zhu, Xiaoli; Liu, Tao; Cheng, Wenbo

    2014-02-03

    In this report, silver nanoparticles (AgNPs) decorated graphene nanosheets have been prepared based on the reduction of Ag ions by hydroquinone, and their catalytic performance towards the electrochemical oxidation of methanol is investigated. The synthesis of the nano-composite is confirmed by transmission electron microscope measurements and UV-vis absorption spectra. Excellent electrocatalytic performance of the material is demonstrated by cyclic voltammograms. This material also contributes to the low peak potential of methanol oxidation compared with most of the other materials.

  4. Thermal expansion of multiwall carbon nanotube reinforced nanocrystalline silver matrix composite

    SciTech Connect (OSTI)

    Sharma, Manjula Sharma, Vimal; Pal, Hemant

    2014-04-24

    Multiwall carbon nanotube reinforced silver matrix composite was fabricated by novel molecular level mixing method, which involves nucleation of Ag ions inside carbon nanotube dispersion at the molecular level. As a result the carbon nanotubes get embedded within the powder rather than on the surfaces. Micro structural characterization by X- ray diffraction and scanning electron microscopy reveals that the nanotubes are homogeneously dispersed and anchored within the matrix. The thermal expansion of the composite with the multiwall nanotube content (0, 1.5 vol%) were investigated and it is found that coefficient of thermal expansion decreases with the addition of multiwall nanotube content and reduce to about 63% to that of pure Ag.

  5. Microsoft Word - Rockwood _CFC_ Silver Peak Area Final EA V4 _dec date_.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Interior Bureau of Land Management Environmental Assessment # DOI-BLM-NV-B020-2012-0214-EA DOE/EA-1921 DATE: December 2012 Silver Peak Area Geothermal Exploration Project ENVIRONMENTAL ASSESSMENT Geothermal Lease: N-87008 Tonopah Field Office P.O. Box 911 1553 S. Main Street Tonopah, NV 89049 Phone: 775-482-7800 Fax: 775-482-7810 BLM Mission Statement It is the mission of the Bureau of Land Management to sustain the health, diversity, and productivity of the public lands for the use and

  6. Sintering Kinetics of Inkjet Printed Conductive Silver Lines on Insulating Plastic Substrate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Wenchao; List, III, Frederick Alyious; Duty, Chad E; Babu, Sudarsanam Suresh

    2015-01-24

    This paper focuses on sintering kinetics of inkjet printed lines containing silver nanoparticles deposited on a plastic substrate. Upon heat treatment, the change of resistance in the printed lines was measured as a function of time and sintering temperatures from 150 to 200 C. A critical temperature was observed for the sintering process, beyond which there was no further reduction in resistance. Analysis shows the critical temperature correlates to the boiling point of the solvent, which is attributed to a liquid-mediated sintering mechanism. It is demonstrated that the sintering process shuts down after the solvent has completely evaporated.

  7. Synthesis of supported silver nano-spheres on zinc oxide nanorods for visible light photocatalytic applications

    SciTech Connect (OSTI)

    Saoud, Khaled; Alsoubaihi, Rola; Bensalah, Nasr; Bora, Tanujjal; Bertino, Massimo; Dutta, Joydeep

    2015-03-15

    Highlights: Synthesis of supported Ag NPs on ZnO nanorods using open vessel microwave reactor. Use of the Ag/ZnO NPs as an efficient visible light photocatalyst. Complete degradation of methylene blue in 1 h with 0.5 g/L Ag/ZnO NPs. - Abstract: We report the synthesis of silver (Ag) nano-spheres (NS) supported on zinc oxide (ZnO) nanorods through two step mechanism, using open vessel microwave reactor. Direct reduction of ZnO from zinc nitrates was followed by deposition precipitation of the silver on the ZnO nanorods. The supported Ag/ZnO nanoparticles were then characterized by electron microscopy, X-ray diffraction, FTIR, photoluminescence and UVvis spectroscopy. The visible light photocatalytic activity of Ag/ZnO system was investigated using a test contaminant, methylene blue (MB). Almost complete removal of MB in about 60 min for doses higher than 0.5 g/L of the Ag/ZnO photocatalyst was achieved. This significant improvement in the photocatalytic efficiency of Ag/ZnO photocatalyst under visible light irradiation can be attributed to the presence of Ag nanoparticles on the ZnO nanoparticles which greatly enhances absorption in the visible range of solar spectrum enabled by surface plasmon resonance effect from Ag nanoparticles.

  8. Characterization of silver/polystyrene nanocomposites prepared by in situ bulk radical polymerization

    SciTech Connect (OSTI)

    Vukoje, Ivana D.; Vodnik, Vesna V.; Dunuzovi?, Jasna V.; Dunuzovi?, Enis S.; Marinovi?-Cincovi?, Milena T.; Jeremi?, Katarina; Nedeljkovi?, Jovan M.

    2014-01-01

    Graphical abstract: - Highlights: Synthesis and characterization of polystyrene nanocomposites based on Ag nanoparticles. The glass transition temperature decreased in nanocomposites with respect to the pure polymer. Resistance of the polymer to thermal degradation enhanced with Ag nanoparticles content. - Abstract: Nanocomposites (NCs) with different content of silver nanoparticles (Ag NPs) embeded in polystyrene (PS) matrix were prepared by in situ bulk radical polymerization. The nearly monodisperse Ag NPs protected with oleylamine were synthesized via organic solvo-thermal method and further used as a filler. The as-prepared spherical Ag NPs with diameter of 7.0 1.5 nm were well dispersed in the PS matrix. The structural properties of the resulting Ag/PS NCs were characterized by transmission electron microscope (TEM) and Fourier transform infrared (FTIR) spectroscopy, while optical properties were characterized using optical absorption measurements. The gel permeation chromatography (GPC) measurements showed that the presence of Ag NPs stabilized with oleylamine has no influence on the molecular weight and polydispersity of the PS matrix. The influence of silver content on the thermal properties of Ag/PS NCs was investigated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicated that resistance of PS to thermal degradation was improved upon incorporation of Ag NPs. The Ag/PS NCs have lower glass transition temperatures than neat PS because loosely packed oleylamine molecules at the interface caused the increase of free volume and chain segments mobility near the surface of Ag NPs.

  9. Removal of dissolved humic acid from water by photocatalytic oxidation using a silver orthophosphate semiconductor

    SciTech Connect (OSTI)

    Hatakeyama, Keisuke; Okuda, Masukazu; Kuki, Takahiro; Esaka, Takao

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? The photocatalytic property of a silver orthophosphate (Ag{sub 3}PO{sub 4}) was investigated for humic acid degradation. ? The Ag{sub 3}PO{sub 4} shows high photocatalytic activity under visible light. ? The photocatalytic activity was greatly improved by employing the precipitation method. -- Abstract: In order to remove dissolved organic matter such as humic acid from water, a silver orthophosphate (Ag{sub 3}PO{sub 4}) was newly employed as a heterogeneous photocatalyst. Here, Ag{sub 3}PO{sub 4} was prepared by simple ion-exchange and precipitation methods, and the physico-chemical properties were characterized by X-ray diffraction, ultravioletvisible diffuse reflectance spectroscopy, scanning electron microscopy, particle distribution measurements and BrunauerEmmettTeller (BET) analysis. The degradation of humic acid was faster over Ag{sub 3}PO{sub 4} catalyst than over conventional TiO{sub 2} (P-25). The total photocatalytic properties were improved by employing not an ion-exchange method but a precipitation method; humic acid degradation was performed with a removal ratio of dissolved organic carbon of 75% under visible light (? = 451 nm) for 2-h irradiation.

  10. Comparison of 20 nm silver nanoparticles synthesized with and without a gold core. Structure, dissolution in cell culture media, and biological impact on macrophages

    SciTech Connect (OSTI)

    Munusamy, Prabhakaran; Wang, Chongmin; Engelhard, Mark H.; Baer, Donald R.; Smith, Jordan N.; Liu, Chongxuan; Kodali, Vamsi K.; Thrall, Brian D.; Chen, Shu; Porter, Alexandra E.; Ryan, Mary P.

    2015-07-15

    Widespread use of silver nanoparticles raises questions of environmental impact and toxicity. Both silver particles and silver ions formed by particle dissolution may impact biological systems. Therefore it is important to understand the characteristics of silver nanoparticles and their stability in relevant media. The synthesis route can impact physical and chemical characteristics of the particles and we report the characterization and solution stability of three types of silver nanoparticles (20 nm particles with and without gold cores and 110 nm particles with gold cores) in cell culture media with serum proteins: FBS10%/RPMI. These nanoparticles were synthesized in aqueous solution and characterized using both in situ and ex situ analysis methods. Dissolution studies were carried at particle concentrations from 1 g/ml to 50 g/ml. Particles with gold cores had smaller crystallite size and higher apparent solubility than pure silver particles. A dissolution model was found to describe the time variation of particle size and amount of dissolved silver for particle loadings above 9 g/ml. An effective solubility product obtained from fitting the data was higher for the 20 nm gold core particles in comparison to the pure silver or 110 nm particles. Dissolution of the nanoparticles was enhanced by presence of serum proteins contained in fetal bovine serum. In addition, the protocol of the dispersion in the medium was found to influence particle agglomeration and dissolution. Results show that particle structure can impact the concentration of dissolved silver and the dose to which cells would be exposed during in vitro studies.

  11. Comparison of 20 nm silver nanoparticles synthesized with and without a gold core. Structure, dissolution in cell culture media, and biological impact on macrophages

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Munusamy, Prabhakaran; Wang, Chongmin; Engelhard, Mark H.; Baer, Donald R.; Smith, Jordan N.; Liu, Chongxuan; Kodali, Vamsi K.; Thrall, Brian D.; Chen, Shu; Porter, Alexandra E.; et al

    2015-07-15

    Widespread use of silver nanoparticles raises questions of environmental impact and toxicity. Both silver particles and silver ions formed by particle dissolution may impact biological systems. Therefore it is important to understand the characteristics of silver nanoparticles and their stability in relevant media. The synthesis route can impact physical and chemical characteristics of the particles and we report the characterization and solution stability of three types of silver nanoparticles (20 nm particles with and without gold cores and 110 nm particles with gold cores) in cell culture media with serum proteins: FBS10%/RPMI. These nanoparticles were synthesized in aqueous solution andmore » characterized using both in situ and ex situ analysis methods. Dissolution studies were carried at particle concentrations from 1 µg/ml to 50 µg/ml. Particles with gold cores had smaller crystallite size and higher apparent solubility than pure silver particles. A dissolution model was found to describe the time variation of particle size and amount of dissolved silver for particle loadings above 9 µg/ml. An effective solubility product obtained from fitting the data was higher for the 20 nm gold core particles in comparison to the pure silver or 110 nm particles. Dissolution of the nanoparticles was enhanced by presence of serum proteins contained in fetal bovine serum. In addition, the protocol of the dispersion in the medium was found to influence particle agglomeration and dissolution. Results show that particle structure can impact the concentration of dissolved silver and the dose to which cells would be exposed during in vitro studies.« less

  12. Silver Vanadates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H. Peng, J. Im, A. Freeman, N. Perry, A. Zakutayev, P. Ndione, D. Ginley, J. Perkins, Chem. Mater. 24(17), 3346-3354 (2012). (Left) Calculated density of states (DOS)....

  13. Kondo decoherence : finding the right spin model for iron impurities in gold and silver.

    SciTech Connect (OSTI)

    Costi, T. A.; Bergqvist, L.; Weichselbaum, A.; von Delft, J.; Micklitz, T.; Rosch, A.; Mavropoulos, P.; Dederichs, P. H.; Mallet, F.; Saminadayar, L.; Bauerle, C.

    2009-02-01

    We exploit the decoherence of electrons due to magnetic impurities, studied via weak localization, to resolve a long-standing question concerning the classic Kondo systems of Fe impurities in the noble metals gold and silver: which Kondo-type model yields a realistic description of the relevant multiple bands, spin, and orbital degrees of freedom? Previous studies suggest a fully screened spin S Kondo model, but the value of S remained ambiguous. We perform density functional theory calculations that suggest S=3/2. We also compare previous and new measurements of both the resistivity and decoherence rate in quasi-one-dimensional wires to numerical renormalization group predictions for S=1/2, 1, and 3/2, finding excellent agreement for S=3/2.

  14. Highly fluorescent silver nanoclusters in alumina-silica composite optical fiber

    SciTech Connect (OSTI)

    Halder, A.; Chattopadhyay, R.; Majumder, S.; Paul, M. C.; Das, S.; Bhadra, S. K.; Bysakh, S.; Unnikrishnan, M.

    2015-01-05

    An efficient visible fluorescent optical fiber embedded with silver nanoclusters (Ag-NCs) having size ∼1 nm, uniformly distributed in alumina-silica composite core glass, is reported. Fibers are fabricated in a repetitive controlled way through modified chemical vapour deposition process associated with solution doping technique. Fibers are drawn from the transparent preforms by conventional fiber drawing process. Structural characteristics of the doped fibers are studied using transmission electron microscopy and electron probe micro analysis. The oxidation state of Ag within Ag-NCs is investigated by X-ray photo electron spectroscopy. The observed significant fluorescence of the metal clusters in fabricated fibers is correlated with electronic model. The experimentally observed size dependent absorption of the metal clusters in fabricated fibers is explained with the help of reported results calculated by ab-initio density functional theory. These optical fibers may open up an opportunity of realizing tunable wavelength fiber laser without the help of rare earth elements.

  15. Deformation twinning of a silver nanocrystal under high pressure. Supplementary materials

    SciTech Connect (OSTI)

    Huang, X. J.; Yang, W. G.; Harder, R.; Sun, Y.; Lu, M.; Chu, Y. S.; Robinson, I. K.; Mao, H. K.

    2015-10-20

    Within a high-pressure environment, crystal deformation is controlled by complex processes such as dislocation motion, twinning, and phase transitions, which change materials microscopic morphology and alter their properties. Likewise, understanding a crystals response to external stress provides a unique opportunity for rational tailoring of its functionalities. It is very challenging to track the strain evolution and physical deformation from a single nanoscale crystal under high-pressure stress. Here, we report an in situ three-dimensional mapping of morphology and strain evolutions in a single-crystal silver nanocube within a high-pressure environment using the Bragg Coherent Diffractive Imaging (CDI) method. We also observed a continuous lattice distortion, followed by a deformation twining process at a constant pressure. The ability to visualize stress-introduced deformation of nanocrystals with high spatial resolution and prominent strain sensitivity provides an important route for interpreting and engineering novel properties of nanomaterials.

  16. Expanded Analysis of Hot Isostatic Pressed Iodine-Loaded Silver-Exchanged Mordenite

    SciTech Connect (OSTI)

    Jubin, R. T. [ORNL; Bruffey, S. H. [ORNL; Patton, K. K. [ORNL

    2014-09-30

    Reduced silver-exchanged mordenite (Ag0Z) is being evaluated as a potential material to control the release of radioactive iodine that is released during the reprocessing of used nuclear fuel into the plant off-gas streams. The purpose of this study was to determine if hot pressing could directly convert this iodine loaded sorbent into a waste form suitable for long-term disposition. The minimal pretreatment required for production of pressed pellets makes hot pressing a technically and economically desirable process. Initial scoping studies utilized hot uniaxial pressing (HUPing) to prepare samples of non-iodine-loaded reduced silver exchanged mordenite (Ag0Z). The resulting samples were very fragile due to the low pressure (~ 28 MPa) used. It was recommended that hot isostatic pressing (HIPing), performed at higher temperatures and pressures, be investigated. HIPing was carried out in two phases, with a third and final phase currently underway. Phase I evaluated the effects of pressure and temperature conditions on the manufacture of a pressed sample. The base material was an engineered form of silver zeolite. Six samples of Ag0Z and two samples of I-Ag0Z were pressed. It was found that HIPing produced a pressed pellet of high density. Analysis of each pressed pellet by scanning electron microscopy-energy dispersive spectrophotometry (SEM-EDS) and X-ray diffraction (XRD) demonstrated that under the conditions used for pressing, the majority of the material transforms into an amorphous structure. The only crystalline phase observed in the pressed Ag0Z material was SiO2. For the samples loaded with iodine (I-Ag0Z) iodine was present as AgI clusters at low temperatures, and transformed into AgIO4 at high temperatures. Surface mapping and EDS demonstrate segregation between silver iodide phases and silicon dioxide phases. Based on the results of the Phase I study, an expanded test matrix was developed to examine the effects of multiple source materials, compositional variations, and an expanded temperature range. Each sample was analyzed with the approach used in Phase I. In all cases, there is nothing in the SEM or XRD analyses that indicates creation of any AgI-containing silicon phase, with the samples being found to be largely amorphous. Phase III of this study has been initiated and is the final phase of scoping tests. It will expand upon the test matrix completed in Phase II and will examine the durability of the pressed pellets through product consistency testing (PCT) studies. Transformation of the component material into a well-characterized iodine-containing mineral phase would be desirable. This would limit the additional experimental testing and modeling required to determine the long-term stability of the pressed pellet, as much of that information has already been learned for several common iodine-containing minerals. However, this is not an absolute requirement, especially if pellets produced by hot isostatic pressing can be demonstrated through initial PCT studies to retain iodine well despite their amorphous composition.

  17. Deformation twinning of a silver nanocrystal under high pressure. Supplementary materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, X. J.; Yang, W. G.; Harder, R.; Sun, Y.; Lu, M.; Chu, Y. S.; Robinson, I. K.; Mao, H. K.

    2015-10-20

    Within a high-pressure environment, crystal deformation is controlled by complex processes such as dislocation motion, twinning, and phase transitions, which change materials’ microscopic morphology and alter their properties. Likewise, understanding a crystal’s response to external stress provides a unique opportunity for rational tailoring of its functionalities. It is very challenging to track the strain evolution and physical deformation from a single nanoscale crystal under high-pressure stress. Here, we report an in situ three-dimensional mapping of morphology and strain evolutions in a single-crystal silver nanocube within a high-pressure environment using the Bragg Coherent Diffractive Imaging (CDI) method. We also observed amore » continuous lattice distortion, followed by a deformation twining process at a constant pressure. The ability to visualize stress-introduced deformation of nanocrystals with high spatial resolution and prominent strain sensitivity provides an important route for interpreting and engineering novel properties of nanomaterials.« less

  18. Low-Cost Nano-Patterning Process Makes Millions of Holes in Silver Film, Boosting Light-Capturing Qualities of Solar Cells (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01

    NREL researchers have demonstrated a simple, low-cost way to pattern nano-sized holes in thin silver films in order to trap light waves and boost the transmission of photons into usable energy.

  19. Influence of process parameters on rolling-contact-fatigue life of ion plated nickel-copper-silver lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2012-05-15

    In this paper, we present a connection between argon ion flux, element-mixing, and rolling contact fatigue (RCF) life of a thin film nickel-copper-silver lubricant on ball bearings. The film is deposited on the balls using an ion plating process and tested for RCF in high vacuum. The ion flux is measured using a Langmuir probe and the plane stress within the film during deposition is calculated using a thin film model. Experiments reveal that there is an inverse relationship between ion flux and RCF life for most deposition voltage and pressure combinations tested, specifically, 15.5-18.5 mTorr and 1.5-3.5 kV. For voltages up to 2.5 kV, RCF life decreases as ion flux increases due to increased compressive stress within the film, reaching as high as 2.6 GPa. For voltages between 2.5 and 3.5 kV, interlayer mixing of nickel and copper with the silver layer reduces RCF life due to contamination, even as ion flux and corresponding film compressive stress are reduced. A Monte Carlo-based simulation tool, SRIM is used to track collision cascades of the argon ions and metal atoms within the coating layers. At process voltages above 2.5 kV we observe elemental mixing of copper and nickel with the silver layer using Auger electron spectroscopy of coated steel and Si{sub 3}N{sub 4} balls. The authors conclude that an ion flux greater than 5.0 x 10{sup 14} cm{sup -2} s{sup -1} leads to reduced RCF life due to high film stress. In addition, process voltages greater than 2.5 kV also reduce RCF life due to contamination and interlayer mixing of nickel and copper within the silver layer.

  20. Silver-halide/organic-composite structures: Toward materials with multiple photographic functionalities

    SciTech Connect (OSTI)

    Bringley, Joseph F. . E-mail: joseph.bringley@kodak.com; Rajeswaran, Manju; Olson, Leif P.; Liebert, Nancy M.

    2005-10-15

    We report the synthesis and structure of the novel silver-halide-based organic-inorganic hybrids Ag{sub 2}Br{sub 6}(PPD){sub 2}, Ag{sub 2}Br{sub 6}(CD-2){sub 2}.H{sub 2}O, Ag{sub 2}Br{sub 4}(TMBD), and Ag{sub 2}I{sub 6}(CD-2){sub 2}.H{sub 2}O. 1,4-phenylenediammonium hexabromodiargentate(I) [Ag{sub 2}Br{sub 6}(PPD){sub 2}] crystals are monoclinic (P2{sub 1}/n), with unit-cell dimensions, a=10.1915(3)A, b=7.7562(2)A, c=12.4340(5)A and {beta}=93.109(1){sup o}. N,N-diethyl-2-methyl-1,4-benzenediammonium hexabromodiargentate(I) monohydrate [Ag{sub 2}Br{sub 6}(CD-2){sub 2}.H{sub 2}O] crystals are monoclinic (space group P2{sub 1}/c) with a=10.8434(2)A, b=11.4293(2)A, c=14.3729(1)A, and {beta}=96.153(1){sup o}. N,N,N',N'-tetramethyl-1,4-benzenediammonium tetrabromodiargentate(I) [Ag{sub 2}Br{sub 4}(TMBD)] crystals are orthorhombic (space group Pbcn) with a=17.0030(6)A, b=6.6163(2)A, and c=15.9762(6)A. N,N-diethyl-2-methyl-1,4-benzenediammonium hexaiododiargentate(I) monohydrate, [Ag{sub 2}I{sub 6}(CD-2){sub 2}.H{sub 2}O], are monoclinic (C2/c), with unit-cell dimensions, a=21.4691(4)A, b=12.1411(2)A, c=14.3102(2)A, and {beta}=98.657(1){sup o}. The novel structures are members of a class of silver-halide-based organic-inorganic hybrids based upon the assembly of [Ag{sub a}X{sub b}]{sup n-} clusters and protonated organoamines in aqueous mineral acids. The clusters display short intracluster Ag-Ag distances, and computational methods are used to evaluate intracluster Ag-Ag bonding. The diverse stoichiometries and cluster connectivities observed suggest a rich compositional and structural chemistry based upon the general assembly method. We have extended the methodology to include a silver-halide-organoamonium chemistry in which the organic moiety is chosen to serve a specific photographic function and demonstrate the first examples of such materials. The methodology allows for the direct assembly of [Ag{sub a}X{sub b}]{sup n-} clusters with commercial photographic color developer molecules, and we show that development is repressed but can later be 'switched on' in a unique photographic scheme. The photographic properties of Ag{sub 2}Br{sub 6}(PPD){sub 2} are examined and show an extremely facile development rate owing to the fact that the developer molecules are within molecular proximity to the clusters. As a result of their molecular nature, we anticipate that such materials could enable conventional or completely new imaging technologies with very fast image access rates and very high resolution.

  1. Evaluation of Iodine and Water Co-adsorption on Silver-Functionalized Aerogel

    SciTech Connect (OSTI)

    Spencer, B. B.; Bruffey, S. H.; Walker, J. F.

    2015-04-30

    The co-adsorption of iodine and water on silver-functionalized silica aerogel was evaluated using research quantities of the aerogel prepared at Pacific Northwest National Laboratory. A macro thermogravimetric analyzer was used to measure weight changes in a thin bed of the aerogel as air streams containing moisture and/or iodine flowed through the bed. The total gas flow in all tests was adjusted to achieve a velocity of 10 m/min through the bed. Initial heating of the aerogel sample to 150C in dry air (dew point < -60C) resulted in weight loss on the order of 1 wt %. Because subsequent phases of the tests indicated that the aerogel did not sorb water, the weight loss was speculated to be caused by volatilization of material that may have been used in the manufacture of the aerogel. Follow-on tests are recommended to ascertain if the aerogel sorbs water at low temperatures, such as 25Cthis would help to determine if a manufacturing reagent is volatilized when raising the sample to iodine sorption temperatures (i.e., 150C). Alternatively, the off-gas released upon heating could be condensed and analyzed. In tests using humidified air streams with dew points between -60C and +10C, the aerogel did not adsorb water at test temperatures of either 75C or 150C. Because water alone was not adsorbed, tests were performed to ascertain if iodine sorption varied between cases when nearly no water was present in the gas stream and when water was present. In one experiment, the gas stream consisted of dry air (dew point < -60C) with an iodine concentration of 50 ppmv. In the other experiment, the gas stream consisted of air with a water dew point of 0C and an iodine concentration of 50 ppmv. The ultimate weight gain was nearly the same in both experiments and was presumed to be due entirely to adsorption of iodine. However, a reduced rate of iodine uptake is indicated when water vapor is present. The reason for this is unclear. In both cases, purging the sample with dry, iodine-free air resulted in some weight loss (~2 wt %). It is recommended that the gas phase chemistry of the iodinewater system be reviewed to ascertain if iodine species that are less reactive with silver than molecular iodine are present; this could explain the reduced sorption rates when water is present. Further evaluation of the desorption is recommended, especially to determine how raising the temperature would affect desorption.

  2. Measurements of Aerosol Charge and Size Distribution for Graphite, Gold, Palladium, and Silver Nanoparticles

    SciTech Connect (OSTI)

    Simones, Matthew P.; Gutti, Veera R.; Meyer, Ryan M.; Loyalka, Sudarshan K.

    2011-11-01

    The role of charge on aerosol evolution and hence the nuclear source term has been an issue of interest, and there is a need for both experimental techniques and modeling for quantifying this role. Our focus here is on further exploration of a tandem differential mobility analyzer (TDMA) technique to simultaneously measure both the size and charge (positive, negative and neutral) dependent aerosol distributions. We have generated graphite, gold, silver, and palladium nanoparticles (aerosol) using a spark generator. We measure the electrical mobility-size distributions for these aerosols using a TDMA, and from these data we deduce the full charge-size distributions. We observe asymmetry in the particle size distributions for negative and positive charges. This asymmetry could have a bearing on the dynamics of charged aerosols, indicating that the assumption of symmetry for size distributions of negatively and positively charged particles in source term simulations may not be always appropriate. Also, the experimental technique should find applications in measurements of aerosol rate processes that are affected by both particle charge and size (e.g. coagulation, deposition, resuspension), and hence in modeling and simulation of the nuclear source term.

  3. The 3D-architecture of individual free silver nanoparticles captured by X-ray scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barke, Ingo; Hartmann, Hannes; Rupp, Daniela; Flückiger, Leonie; Sauppe, Mario; Adolph, Marcus; Schorb, Sebastian; Bostedt, Christoph; Treusch, Rolf; Peltz, Christian; et al

    2015-02-04

    The diversity of nanoparticle shapes generated by condensation from gaseous matter reflects the fundamental competition between thermodynamic equilibration and the persistence of metastable configurations during growth. In the kinetically limited regime, intermediate geometries that are favoured only in early formation stages can be imprinted in the finally observed ensemble of differently structured specimens. Here we demonstrate that single-shot wide-angle scattering of femtosecond soft X-ray free-electron laser pulses allows three-dimensional characterization of the resulting metastable nanoparticle structures. For individual free silver particles, which can be considered frozen in space for the duration of photon exposure, both shape and orientation are uncoveredmore » from measured scattering images. We identify regular shapes, including species with fivefold symmetry and surprisingly large aspect ratio up to particle radii of the order of 100 nm. Our approach includes scattering effects beyond Born’s approximation and is remarkably efficient—opening up new routes in ultrafast nanophysics and free-electron laser science« less

  4. Stress Intensity of Delamination in a Sintered-Silver Interconnection: Preprint

    SciTech Connect (OSTI)

    DeVoto, D. J.; Paret, P. P.; Wereszczak, A. A.

    2014-08-01

    In automotive power electronics packages, conventional thermal interface materials such as greases, gels, and phase-change materials pose bottlenecks to heat removal and are also associated with reliability concerns. The industry trend is toward high thermal performance bonded interfaces for large-area attachments. However, because of coefficient of thermal expansion mismatches between materials/layers and resultant thermomechanical stresses, adhesive and cohesive fractures could occur, posing a reliability problem. These defects manifest themselves in increased thermal resistance. This research aims to investigate and improve the thermal performance and reliability of sintered-silver for power electronics packaging applications. This has been experimentally accomplished by the synthesis of large-area bonded interfaces between metalized substrates and copper base plates that have subsequently been subjected to thermal cycles. A finite element model of crack initiation and propagation in these bonded interfaces will allow for the interpretation of degradation rates by a crack-velocity (V)-stress intensity factor (K) analysis. A description of the experiment and the modeling approach are discussed.

  5. Effects of molybdenum and silver on iodine transport in primary circuit on severe nuclear accidents

    SciTech Connect (OSTI)

    Kalilainen, J.; Rantanen, P.; Karkela, T.; Lipponen, M.; Auvinen, A.; Jokiniemi, J.

    2012-07-01

    This experimental study was a continuation of the study conducted at VTT to investigate the effects of reactions on primary circuit surfaces to transport of gaseous and aerosol phase iodine during the hypothetical severe nuclear accident. Cesium iodide was used as a precursor in every experiment. In the experiments it was observed that the hydrogen in the atmosphere decreased the fraction of released gaseous iodine. As the temperature was lowered, less iodine was released, but the fraction of gaseous iodine from the overall released iodine was increased. As molybdenum trioxide was introduced to the precursor, the fraction of gaseous iodine from the overall released iodine was increased significantly. Also, Mo decreased the transport of Cs and caused significant depositions to the reaction furnace. Addition of silver to the CsI precursor at 650 deg. C decreased the release of iodine as well as the fraction of gaseous iodine. At 400 deg. C, Ag + CsI as well as Ag + MoO{sub 3} + CsI precursor significantly increased the release of gaseous iodine, where almost no aerosol particles were released. With B{sub 2}O{sub 3} + CsI precursor it was observed that in the atmosphere without H{sub 2}O, the released iodine was mostly in gaseous form. (authors)

  6. NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels

    SciTech Connect (OSTI)

    Patton, K K [ORNL; Bruffey, S H [ORNL; Walker, J F [ORNL; Jubin, R T [ORNL

    2014-07-31

    Off-gas treatment systems in used fuel reprocessing which use fixed-bed adsorbers are typically designed to operate for an extended period of time before replacement or regeneration of the adsorbent. During this time, the sorbent material will be exposed to the off-gas stream. Exposure could last for months, depending on the replacement cycle time. The gas stream will be at elevated temperature and will possibly contain a mixture of water vapor, NOx, nitric acid vapors, and a variety of other constituents in addition to the radionuclides of capture interest. A series of studies were undertaken to evaluate the effects of long-term exposure, or aging, on proposed iodine sorbent materials under increasingly harsh off-gas conditions. Previous studies have evaluated the effects of up to 6 months of aging under dry air and under humid air conditions on the iodine loading behavior of Ag0-functionalized aerogels. This study examines the effects of extended exposure (up to 6 months) to NO2 on the iodine loading capacity of Ag0- functionalized aerogels. Material aged for 1 and 2 months appeared to have a similar total loading capacity to fresh material. Over an aging period of 4 months, a loss of approximately 15% of the total iodine capacity was seen. The iodine capacity loss on silver-functionalized aerogels due to NO2 was smaller than the iodine capacity loss due to humid or dry air aging.

  7. Electric radiation mapping of silver/zinc oxide nanoantennas by using electron holography

    SciTech Connect (OSTI)

    Sanchez, J. E.; Mendoza-Santoyo, F.; Cantu-Valle, J.; Velazquez-Salazar, J.; Jos Yacaman, M.; Ponce, A.; Gonzlez, F. J.; Diaz de Leon, R.

    2015-01-21

    In this work, we report the fabrication of self-assembled zinc oxide nanorods grown on pentagonal faces of silver nanowires by using microwaves irradiation. The nanostructures resemble a hierarchal nanoantenna and were used to study the far and near field electrical metal-semiconductor behavior from the electrical radiation pattern resulting from the phase map reconstruction obtained using off-axis electron holography. As a comparison, we use electric numerical approximations methods for a finite number of ZnO nanorods on the Ag nanowires and show that the electric radiation intensities maps match closely the experimental results obtained with electron holography. The time evolution of the radiation pattern as generated from the nanostructure was recorded under in-situ radio frequency signal stimulation, in which the generated electrical source amplitude and frequency were varied from 0 to 5 V and from 1 to 10?MHz, respectively. The phase maps obtained from electron holography show the change in the distribution of the electric radiation pattern for individual nanoantennas. The mapping of this electrical behavior is of the utmost importance to gain a complete understanding for the metal-semiconductor (Ag/ZnO) heterojunction that will help to show the mechanism through which these receiving/transmitting structures behave at nanoscale level.

  8. The 3D-architecture of individual free silver nanoparticles captured by X-ray scattering

    SciTech Connect (OSTI)

    Barke, Ingo; Hartmann, Hannes; Rupp, Daniela; Flckiger, Leonie; Sauppe, Mario; Adolph, Marcus; Schorb, Sebastian; Bostedt, Christoph; Treusch, Rolf; Peltz, Christian; Bartling, Stephan; Fennel, Thomas; Meiwes-Broer, Karl-Heinz; Mller, Thomas

    2015-02-04

    The diversity of nanoparticle shapes generated by condensation from gaseous matter reflects the fundamental competition between thermodynamic equilibration and the persistence of metastable configurations during growth. In the kinetically limited regime, intermediate geometries that are favoured only in early formation stages can be imprinted in the finally observed ensemble of differently structured specimens. Here we demonstrate that single-shot wide-angle scattering of femtosecond soft X-ray free-electron laser pulses allows three-dimensional characterization of the resulting metastable nanoparticle structures. For individual free silver particles, which can be considered frozen in space for the duration of photon exposure, both shape and orientation are uncovered from measured scattering images. We identify regular shapes, including species with fivefold symmetry and surprisingly large aspect ratio up to particle radii of the order of 100 nm. Our approach includes scattering effects beyond Borns approximation and is remarkably efficientopening up new routes in ultrafast nanophysics and free-electron laser science

  9. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A; Toops, Todd J; Fisher, Galen; West, Brian H

    2014-01-01

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  10. Validation of Methods for Computational Catalyst Design: Geometries, Structures, and Energies of Neutral and Charged Silver Clusters

    SciTech Connect (OSTI)

    Duanmu, Kaining; Truhlar, Donald G.

    2015-04-30

    We report a systematic study of small silver clusters, Agn, Agn+, and Agn–, n = 1–7. We studied all possible isomers of clusters with n = 5–7. We tested 42 exchange–correlation functionals, and we assess these functionals for their accuracy in three respects: geometries (quantitative prediction of internuclear distances), structures (the nature of the lowest-energy structure, for example, whether it is planar or nonplanar), and energies. We find that the ingredients of exchange–correlation functionals are indicators of their success in predicting geometries and structures: local exchange–correlation functionals are generally better than hybrid functionals for geometries; functionals depending on kinetic energy density are the best for predicting the lowest-energy isomer correctly, especially for predicting two-dimensional to three-dimenstional transitions correctly. The accuracy for energies is less sensitive to the ingredient list. Our findings could be useful for guiding the selection of methods for computational catalyst design.

  11. Percolation network in resistive switching devices with the structure of silver/amorphous silicon/p-type silicon

    SciTech Connect (OSTI)

    Liu, Yanhong; Gao, Ping; Bi, Kaifeng; Peng, Wei [School of Physics and Optoelectronic Engineering, Dalian University of Technology, No. 2 Linggong Road, Ganjingzi District, Dalian 116024 (China); Jiang, Xuening; Xu, Hongxia [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, Dalian University of Technology, No. 2 Linggong Road, Ganjingzi District, Dalian116024 (China)

    2014-01-27

    Conducting pathway of percolation network was identified in resistive switching devices (RSDs) with the structure of silver/amorphous silicon/p-type silicon (Ag/a-Si/p-Si) based on its gradual RESET-process and the stochastic complex impedance spectroscopy characteristics (CIS). The formation of the percolation network is attributed to amounts of nanocrystalline Si particles as well as defect sites embedded in a-Si layer, in which the defect sites supply positions for Ag ions to nucleate and grow. The similar percolation network has been only observed in Ag-Ge-Se based RSD before. This report provides a better understanding for electric properties of RSD based on the percolation network.

  12. Effect of silver doping on the surface of La{sub 5/8}Ca{sub 3/8}MnO{sub 3} epitaxial films

    SciTech Connect (OSTI)

    Tselev, A. Vasudevan, R. K.; Kalinin, S. V.; Baddorf, A. P.

    2014-09-08

    Thin film manganese oxides (manganites) display remarkable properties, such as colossal magnetoresistance and charge ordered phases, and became a focal point of research in the past two decades owing to potential applications ranging from oxide spintronics to resistive switching-based memories. La{sub x}Ca{sub 1−x}MnO{sub 3} (LCMO), a widely studied manganite, is known to substantially improve its transport properties when doped with Ag. However, despite the abundance of studies on LCMO, the effect of silver on the surface structure is unknown. Here, through in-situ methods, scanning tunneling microscopy (STM) is performed on La{sub 5/8}Ca{sub 3/8}MnO{sub 3} films grown by pulsed laser deposition. Films doped by silver, as confirmed by in-situ X-ray photoelectron spectroscopy, display large-scale reconstructions, interpreted as being of type (√10 × √10)R18.4°, while films lacking silver display a (√2 × √2)R45° reconstruction that may be associated with a surface charge-ordered state. It is posited that the possible cause of the varied reconstructions is due to a vacancy ordering on top of the existing (√2 × √2)R45° reconstruction. These studies highlight the influence of Ag on the surface structure, and therefore a route towards modifying the surface properties of manganites.

  13. Effect of silver doping on the surface of La5/8Ca3/8MnO3 epitaxial films

    SciTech Connect (OSTI)

    Tselev, Alexander; Vasudevan, Rama K; Kalinin, Sergei V; Baddorf, Arthur P

    2014-01-01

    Thin film manganese oxides (manganites) display remarkable properties such as colossal magnetoresistance and charge ordered phases, and became a focal point of research in the past two decades owing to potential applications ranging from oxide spintronics to resistive switching-based memories. LaxCa1-xMnO3 (LCMO), a widely studied manganite, is known to substantially improve its transport properties when doped with Ag. However, despite the abundance of studies on LCMO, the effect of silver on the surface structure is unknown. Here, through in-situ methods, scanning tunneling microscopy (STM) is performed on La5/8Ca3/8MnO3 films grown by pulsed laser deposition. Films doped by silver, as confirmed by in-situ X-ray photoelectron spectroscopy (XPS), display large-scale reconstructions, interpreted as being of type ( 10 10)R18.4 , while films lacking silver display a ( 2 2)R45 reconstruction that may be associated with a surface charge-ordered state. It is posited that the possible cause of the varied reconstructions is due to a vacancy ordering on top of the existing ( 2 2)R45 reconstruction. These studies highlight the influence of Ag on the surface structure, and therefore a route towards modifying the surface properties of manganites.

  14. Silver-mordenite for radiologic gas capture from complex streams. Dual catalytic CH3I decomposition and I confinement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nenoff, Tina M.; Rodriguez, Mark A.; Soelberg, Nick R.; Chapman, Karena W.

    2014-05-09

    The selective capture of radiological iodine (129I) is a persistent concern for safe nuclear energy. In these nuclear fuel reprocessing scenarios, the gas streams to be treated are extremely complex, containing several distinct iodine-containing molecules amongst a large variety of other species. Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I2) to form AgI. However the mechanisms for organoiodine capture is not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of the recovered sorbent.more » Tools applied include infrared spectroscopy, thermogravimetric analysis with mass spectrometry, micro X-ray fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. Moreover, the MOR zeolite catalyzes decomposition of the methyl iodide through formation of surface methoxy species (SMS), which subsequently reacts with water in the mixed gas stream to form methanol, and with methanol to form dimethyl ether, which are both detected downstream in the effluent. The liberated iodine reacts with Ag in the MOR pore to the form subnanometer AgI clusters, smaller than the MOR pores, suggesting that the iodine is both physically and chemically confined within the zeolite.« less

  15. Determining Orientational Structure of Diamondoid Thiols Attached to Silver Using Near Edge X-ray Absorption Fine Structure Spectroscopy

    SciTech Connect (OSTI)

    Willey, T M; Lee, J I; Fabbri, J D; Wang, D; Nielsen, M; Randel, J C; Schreiner, P R; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J P; Carlson, R K; Terminello, L J; Melosh, N A; van Buuren, T

    2008-10-07

    Near-edge x-ray absorption fine structure spectroscopy (NEXAFS) is a powerful tool for determination of molecular orientation in self-assembled monolayers and other surface-attached molecules. A general framework for using NEXAFS to simultaneously determine molecular tilt and twist of rigid molecules attached to surfaces is presented. This framework is applied to self-assembled monolayers of higher diamondoid, hydrocarbon molecules with cubic-diamond-cage structures. Diamondoid monolayers chemisorbed on metal substrates are known to exhibit interesting electronic and surface properties. This work compares molecular orientation in monolayers prepared on silver substrates using two different thiol positional isomers of [121]tetramantane, and thiols derived from two different pentamantane structural isomers, [1212]pentamantane and [1(2,3)4]pentamantane. The observed differences in monolayer structure demonstrate the utility and limitations of NEXAFS spectroscopy and the framework. The results also demonstrate the ability to control diamondoid assembly, in particular the molecular orientational structure, providing a flexible platform for the modification of surface properties with this exciting new class of nanodiamond materials.

  16. Synthesis of silver particles on copper substrates using ethanol-based solution for surface-enhanced Raman spectroscopy

    SciTech Connect (OSTI)

    Chen, Li Zhang, Zuojun; Chen, Gang; Zhou, Hui; Lai, Chunhong; School of Physics and Electronic Information, China West Normal University, NanChong 637002

    2014-03-15

    The displacement reaction of AgNO{sub 3} and copper metal is an effective and economical way to fabricate Ag-Cu surface enhanced Raman scattering (SERS) substrates. Aqueous solutions of AgNO{sub 3} are usually used for substrate preparation. In this work, a new method for Ag-Cu SERS substrate preparation is proposed, which uses an ethanol solution rather than an aqueous AgNO{sub 3} solution. Analysis of the surface morphologies of sample substrates by field emission scanning electron microscopy (FESEM) showed that the silver nanoparticles prepared by this new method were more regular than those prepared in the traditional aqueous solution. The SERS spectra of Rhodamine 6G (R6G) adsorbed on these Ag-Cu substrates were then investigated and compared. It was found that the Ag-Cu substrates prepared by this method provide significant improvements in Raman signal sensitivity and large-area uniformity. The enhancement factor of this new substrate is about 330 times higher than that prepared using an aqueous AgNO{sub 3} solution under identical experimental conditions. It was also found that 70% of the original sensitivity of the substrate remains after 15 days of exposure to air.

  17. Comparison of small photon beams measured using radiochromic and silver-halide films in solid water phantoms

    SciTech Connect (OSTI)

    Zeidan, Omar A.; Li, Jonathan G.; Low, Daniel A.; Dempsey, James F.

    2004-10-01

    In this study, we compared the dosimetric properties of four of the most commonly used films for megavoltage photon-beam dosimetry when irradiated under identical conditions by small multileaf-collimator (MLC) defined beamlets. Two silver-halide films (SHFs), Kodak XV2 and EDR2, and two radiochromic films (RCFs), Gafchromic HS and MD55-2, were irradiated by MLC-defined 1x1 cm{sup 2} beamlets from a Varian 2100 C/D linac equipped with a 120-leaf MLC. The beamlets were delivered with the accelerator gantry set laterally (90 deg. rotation) upon a solid-water compression film phantom at 100 cm source-to-surface distance which was positioned with the films parallel to the beam axis. Beamlets were delivered at central axis, 5.0 cm, and 10.5 cm off-axis for both leaf-end and leaf-side defined beamlets. The film dosimetry was performed using a quantitative optical density (OD) imaging system that was validated in a previous study. No significant differences between SHF and RCF measurements were observed in percentage depth doses, horizontal depth profiles, or two-dimension spatial isodose distributions in both the central axis and off-axis measurements. We found that regardless of the type of film used, RCF or SHF, a consistent data set for small beam dose modeling was generated. Previous validation studies based on the use of RCF and OD imaging system would indicate that all film produce an accurate result for small beam characterization.

  18. Optical and Durability Evaluation for Silvered Polymeric Mirrors and Reflectors: Cooperative Research and Development Final Report, CRADA Number, CRD-08-316

    SciTech Connect (OSTI)

    Gray, M.

    2014-08-01

    3M is currently developing silvered polymeric mirror reflectors as low-cost replacements for glass mirrors in concentrating solar power (CSP) systems. This effort is focused on development of reflectors comprising both metallized polymeric mirror films based on improved versions of ECP-305+ or other durable mirror film concepts and appropriate mechanically robust substrates. The objectives for this project are to reduce the system capital and operating costs and to lower the levelized cost of energy for CSP installations. The development of mirror reflectors involves work on both full reflectors and mirror films with and without coatings. Mirror reflectors must meet rigid optical specifications in terms of radius of curvature, slope errors and specularity. Mirror films must demonstrate long-term durability and maintain high reflectivity. 3M would like to augment internal capabilities to validate product performance with methods and tools developed at NREL to address these areas.

  19. Silver-mordenite for radiologic gas capture from complex streams. Dual catalytic CH3I decomposition and I confinement

    SciTech Connect (OSTI)

    Nenoff, Tina M.; Rodriguez, Mark A.; Soelberg, Nick R.; Chapman, Karena W.

    2014-05-09

    The selective capture of radiological iodine (129I) is a persistent concern for safe nuclear energy. In these nuclear fuel reprocessing scenarios, the gas streams to be treated are extremely complex, containing several distinct iodine-containing molecules amongst a large variety of other species. Silver-containing mordenite (MOR) is a longstanding benchmark for radioiodine capture, reacting with molecular iodine (I2) to form AgI. However the mechanisms for organoiodine capture is not well understood. Here we investigate the capture of methyl iodide from complex mixed gas streams by combining chemical analysis of the effluent gas stream with in depth characterization of the recovered sorbent. Tools applied include infrared spectroscopy, thermogravimetric analysis with mass spectrometry, micro X-ray fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. Moreover, the MOR zeolite catalyzes decomposition of the methyl iodide through formation of surface methoxy species (SMS), which subsequently reacts with water in the mixed gas stream to form methanol, and with methanol to form dimethyl ether, which are both detected downstream in the effluent. The liberated iodine reacts with Ag in the MOR pore to the form subnanometer AgI clusters, smaller than the MOR pores, suggesting that the iodine is both physically and chemically confined within the zeolite.

  20. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  1. Silver_Mountain_Resort.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  2. Photo-induced valence change of the sulfur atom in an L-cysteine thin film grown on a silver metal substrate in a saliva-emulated aqueous solution

    SciTech Connect (OSTI)

    Tsujibayashi, Toru; Azuma, Junpei; Yamamoto, Isamu; Takahashi, Kazutoshi; Kamada, Masao

    2015-04-27

    A thin film of L-cysteine (HSCH{sub 2}CH(NH{sub 2})COOH) is grown on a silver substrate in saliva-emulated aqueous solution. X-ray photoemission spectroscopic measurements have revealed that the sulfur atom shows valence change under IR laser irradiation at 825?nm. The valence change maintains for about a minute at room temperature and more than an hour between 110 and 250?K after stopping the laser irradiation. It is not observed at all at temperatures lower than 110?K. This temperature-dependent behavior indicates that the photo-excited electronic change should be accompanied by a conformational change in the L-cysteine molecule. It is strongly suggested that the reversible valence change of the sulfur atom is applicable to a memory used around room temperature.

  3. Feasibility Study of Economics and Performance of Solar Photovoltaics at the Chino Mine in Silver City, New Mexico. A Study Prepared in Partnership with the Environmental Protection Agency for the RE-Powering America's Land Initiative: Siting Renewable Energy on Potentially Contaminated Land and Mine Sites

    SciTech Connect (OSTI)

    Kiatreungwattana, K.; Geiger, J.; Healey, V.; Mosey, G.

    2013-04-01

    The U.S. Environmental Protection Agency (EPA), in accordance with the RE-Powering America's Land initiative, selected the Chino Mine site in Silver City, New Mexico, for a feasibility study of renewable energy production. The National Renewable Energy Laboratory (NREL) provided technical assistance for this project. The purpose of this report is to assess the site for a possible photovoltaic (PV) system installation and estimate the cost, performance, and site impacts of different PV options. In addition, the report recommends financing options that could assist in the implementation of a PV system at the site.

  4. Transport and magnetization current in a thin layer of Bi{sub 1.8}Pb{sub 0.4}Sr{sub 2.0}Ca{sub 2.2}Cu{sub 3.0}O{sub y} adjacent to silver sheathing in BSCCO-2223 tapes

    SciTech Connect (OSTI)

    Lelovic, M.; Krishnaraj, P.; Deis, T.

    1995-07-01

    The thin superconducting region next to the silver sheath appears to be the region of high critical current density in BSCCO-2223 tapes. Transport current measurements on Bi{sub 1.8}Pb{sub 0.4}Sr{sub 2.0}Ca{sub 2.2}Cu{sub 3.0}O{sub y} tape at 77 K in a low magnetic field applied parallel to the tape thickness indicate an exponential field dependence [J / J{sub c} {proportional_to} exp (- B / B{sub 0})] for transport currents. Magnetic hysteresis was measured in a 10-{mu}m-thick layer of superconductor near the silver sheath as a function of temperature, intensity, and orientation of applied field with respect to the tape. The characteristic field for full penetration depth, B*, for a superconducting slab was found to have a power law dependence on temperature. Magnetization currents as a function of temperature and applied field oriented parallel to the tape thickness, J{sub c,m}(B,T), were determined from the magnetization loop width with a Bean- model expression adapted for an orthorhombic sample. The critical-state model, adjusted for scaling and magnetic relaxation, correlates well with the magnetization current of the thin layer at 77 K.

  5. Silver Peak Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    EFAULT","autoinfowindows":false,"kml":,"gkml":,"fusiontables":,"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":,"markercluster":false,"searchmarkers...

  6. Biomedical silver-109m isotope generator

    DOE Patents [OSTI]

    Wanek, Philip M. (Los Alamos, NM); Steinkruger, Frederick J. (Los Alamos, NM); Moody, David C. (Los Alamos, NM)

    1987-01-01

    A method, composition of matter, and apparatus for producing substantially pure Ag-109m for use in biomedical imaging techniques. Cd-109, which decays with a half-life of 453 days to Ag-109m is loaded onto an ion exchange column consisting of particulate tin phosphate. After secular equilibrium is reached in about ten minutes, Ag-109m may be selectively eluted from the column by means of a physiologically acceptable aqueous buffered eluent solution of sodium thiosulfate, and either ascorbic acid or dextrose. The breakthrough of toxic Cd-109 is on the order of 1.times.10.sup.-7, which is sufficiently low to permit administration of the Ag-109m-containing eluate, with but a minor pH adjustment, directly to a human patient within a matter of seconds.

  7. Biomedical silver-109m isotope generator

    DOE Patents [OSTI]

    Wanek, P.M.; Steinkruger, F.J.; Moody, D.C.

    1985-03-05

    A method, composition of matter, and apparatus for producing substantially pure Ag-109m for use in biomedical imaging techniques. Cd-109, which decays with a half-life of 453 days to Ag-109m, is loaded onto an ion exchange column consisting of particulate tin phosphate. After secular equilibrium is reached in about ten minutes, Ag-109m may be selectively eluted from the column by means of a physiologically acceptable aqueous buffered eluent solution of sodium thiosulfate, and either ascorbic acid or dextrose. The breakthrough of toxic Cd-109 is on the order of 1 x 10-7, which is sufficiently low to permit administration of the Ag-109m-containing eluate, with but a minor pH adjustment, directly to a human patient within a matter of seconds. 1 fig.

  8. Silver Peak Innovative Exploration Project Geothermal Project...

    Open Energy Info (EERE)

    Institute; William Cumming, Cumming Geoscience; Jerry Hamblin Subsurface Excellence; Stephen Hallinan, Western Geco; John Deymonaz Targets Milestones - Reduce the high level of...

  9. Silver Peak Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    (Reservoir): Depth to Top of Reservoir: Depth to Bottom of Reservoir: Average Depth to Reservoir: Use the "Edit with Form" button at the top of the page to add a Well Field...

  10. Silver Peak Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Sanyal Classification (Reservoir): Depth to Top of Reservoir: Depth to Bottom of Reservoir: Average Depth to Reservoir: Use the "Edit with Form" button at the top of the...

  11. Spectroscopic studies of silver boro tellurite glasses

    SciTech Connect (OSTI)

    Kumar, E. Ramesh Kumari, K. Rajani Rao, B. Appa Bhikshamaiah, G.

    2014-04-24

    The FTIR absorption and Raman scattering studies were used to obtain the structural information of AgI?Ag{sub 2}O?[(1?x)B{sub 2}O{sub 3}?xTeO{sub 2}] (x=0 to 1 mol% in steps of 0.2) glasses. The glassy nature of the compounds has been confirmed by X-ray diffraction. FTIR and Raman spectra were recorded for all samples at room temperature. FTIR spectra which provides the information about the change in bond structure of the glasses. Raman spectra provide the effect of TeO{sub 2} on SBT glass system is that as increasing the concentration of TeO{sub 2} the band intensity at 707 cm{sup ?1} increase.

  12. Silver Spring Networks | Open Energy Information

    Open Energy Info (EERE)

    Broadway Street Place: Redwood City, California Zip: 94063 Region: Bay Area Sector: Efficiency Product: Energy efficiency Website: www.silverspringnetworks.com Coordinates:...

  13. Cleanable and Hardcoat Coatings for Increased Durability of Silvered...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    System for CSP component evaluation under plant-like conditions, including tracking, on-sun experiments. Static corrosion test samples after 2063 hrs. of salt exposure awaiting...

  14. 14,700 tons of silver at Y-12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    calutron magnets was because of a shortage of copper during the war. As you will recall, Gen. Groves sent Col. Nichols to arrange for the purchase of as much uranium ore as could...

  15. Microsoft Word - Chemetall Foote_Kings Mountain and Silver Peak...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    footprint of the transportation sector. 3.2.2 Solid and Hazardous Wastes 3.2.2.1 Affected Environment 3.2.2.1.1 Kings Mountain The major materials used at the site include sand...

  16. Silicon nitride protective coatings for silvered glass mirrors

    DOE Patents [OSTI]

    Tracy, C.E.; Benson, D.K.

    1984-07-20

    A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate prior to metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

  17. Silver particles improve performance of battery material | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the battery wears out after only 10 to 40 charge-discharge cycles; a typical electric vehicle requires a thousand cycles or more. It is believed that once these issues are...

  18. From Silver to Lead, SRS Turns Trash to Treasure

    Broader source: Energy.gov [DOE]

    AIKEN, S.C. – EM’s contractor for the nuclear cleanup at the Savannah River Site (SRS) operates a robust recycling program that allows for the reuse of precious metals, electronics, scrap metal, and shell casings from trainings for the site’s security force.

  19. 5-3-11_Final_Testimony_(Silver).pdf

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    domestic clean energy sources can help us regain control of our energy future and reduce oil consumption. Clean energy not only has long-term, strategic benefits, it is also an...

  20. Radiometrics At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  1. Silver Lake, Kansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Kansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.104166, -95.8585978 Show Map Loading map... "minzoom":false,"mappingservice":"google...

  2. PJM Presentation- The Silver Bullet: Storage! (July 12, 2011)

    Broader source: Energy.gov [DOE]

    Presentation by Terry Boston, President and CEO pf PJM Interconnection before the Electricity Advisorty Committee, July 12, 2011, on storage for the smart grid.

  3. Testimony of Jonathan Silver, Executive Director Loan Programs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... the market study and the financial modeling suggested that ... the loan guarantee gave the U.S. taxpayer the best chance of ... suffered from an economic crisis that has significantly ...

  4. Cobalt stabilization of silver extraordinary optical transmission sensing platforms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Farah, Annette E.; Davidson, Roderick B.; Pooser, Raphael C.; Lawrie, Benjamin J.; Kalyanaraman, Ramki; Malasi, A.

    2016-01-25

    In this study, plasmon-mediated extraordinary optical transmission (EOT) is finding increased interest for biosensing applications. While Ag nanostructures are capable of the highest plasmonic quality factor of all metals, the performance reliability of pure Ag EOT devices is limited by degradation through environmental interactions. Here we show that EOT devices consisting of nanostructured hole arrays in Ag/Co bilayers show comparable transmission with that of identical hole arrays in Agthin films as well as enhanced reliability measured by the rate of resonance peak redshift and broadening with time. The Ag/Co EOT devices showed 2.6× and 1.9× smaller red shift in shortmore » timescales (20 days) and after 100 days, respectively, while they showed a 1.7× steady-state decrease in rate of bandwidth broadening. This improvement is likely due to the Co metal stabilizing the Agfilm from morphological changes by reducing its propensity to diffuse or dewet on the underlying substrate. The improved reliability of Ag/Co bilayer EOT devices could enable the use of their superior plasmonic properties for optical detection of trace chemicals.« less

  5. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel...

    Office of Scientific and Technical Information (OSTI)

    Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species ...

  6. Silver-Mordenite for Radiologic Gas Capture from Complex Streams...

    Office of Scientific and Technical Information (OSTI)

    In nuclear fuel reprocessing scenarios, complex gas streams will be present and the need ... infrared spectroscopy, thermogravimetric analysis with mass spectrometry, Micro-X-ray ...

  7. Silicon nitride protective coatings for silvered glass mirrors

    DOE Patents [OSTI]

    Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

    1988-01-01

    A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

  8. Multispectral Imaging At Silver Peak Area (Laney, 2005) | Open...

    Open Energy Info (EERE)

    geothermal field. References Patrick Laney (2005) Federal Geothermal Research Program Update - Fiscal Year 2004 Additional References Retrieved from "http:en.openei.orgw...

  9. Energetics Measurements of Silver Halfraum Targets at the National...

    Office of Scientific and Technical Information (OSTI)

    Service, Springfield, VA at www.ntis.gov. Authors: May, M J ; Fournier, K B ; Brown, C G ; Dunlop, W H ; Kane, J O ; Mirkarimi, P B ; Moody, J ; Patterson, R ; Schneider,...

  10. Silver (Ag) Transport Mechanisms in TRISO Coated Particles: A Critical Review

    SciTech Connect (OSTI)

    IJ van Rooyen; ML Dunzik-Gougar; PM van Rooyen

    2014-05-01

    Transport of 110mAg in the intact SiC layer of TRISO coated particles has been studied for approximately 30 years without arriving at a satisfactory explanation of the transport mechanism. In this paper the possible mechanisms postulated in previous experimental studies, both in-reactor and out-of reactor research environment studies are critically reviewed and of particular interest are relevance to very high temperature gas reactor operating and accident conditions. Among the factors thought to influence Ag transport are grain boundary stoichiometry, SiC grain size and shape, the presence of free silicon, nano-cracks, thermal decomposition, palladium attack, transmutation products, layer thinning and coated particle shape. Additionally new insight to nature and location of fission products has been gained via recent post irradiation electron microscopy examination of TRISO coated particles from the DOEs fuel development program. The combined effect of critical review and new analyses indicates a direction for investigating possible the Ag transport mechanism including the confidence level with which these mechanisms may be experimentally verified.

  11. Controlling the Nucleation and Growth of Silver on Palladium Nanocubes by Manipulating the Reaction Kinetics

    SciTech Connect (OSTI)

    Zeng J.; Tao J.; Zhu, C.; Jin, M.; Zhang, H.; Li, Z.-Y.; Zhu, Y.; Xia, Y.

    2012-03-05

    By manipulating the rate at which Ag atoms were generated from a precursor, the nucleation and growth of Ag on Pd nanocubes with six equivalent {l_brace}100{r_brace} facets were controlled to generate three different types of bimetallic nanocrystals: Pd-Ag hybrid dimers, Pd-Ag eccentric nanobars, and Pd{at}Ag core-shell nanocrystals.

  12. Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors

    SciTech Connect (OSTI)

    Padiyath, Raghunath

    2013-04-01

    We have successfully developed coating formulations which significantly increasethe abrasion resistance of mirror films. We have demonstrated manufacturing scale-up of these films to full width andproduction volumes. Implementation of these films in commercial test sites is planned for Q2 2013(Abengoa, Gossamer Space Frames). This slide show outlines the background and objectives of the project, technical approach and results, and key lessons. It also presents the need and opportunity for reduction of costs for CSP and collectors. It also presents an approach for a large aperture parabolic trough collector with reflective film and a high concentration factor, including demonstration and results.

  13. EERE Success Story-From Silver to Copper: SunShot Awardee TetraSun...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    According to First Solar, these solar cells boast 21% minimum efficiency, which will make these among the most efficient solar panels commercially available today. TetraSun's ...

  14. In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures

    SciTech Connect (OSTI)

    Bell, Nelson S.; Dunphy, Darren R.; Lambert, Timothy N.; Lu, Ping; Boyle, Timothy J.

    2015-06-26

    In this study, the use of maltodextrin supramolecular structures (MD SMS) as a reducing agent and colloidal stabilizing agent for the synthesis of Ag nanoparticles (Ag NPs) identified three key points. First, the maltodextrin (MD) solutions are effective in the formation of well-dispersed Ag NPs utilizing alkaline solution conditions, with the resulting Ag NPs ranging in size from 5 to 50 nm diameter. Second, in situ characterization by Raman spectroscopy and small angle X-ray scattering (SAXS) are consistent with initial nucleation of Ag NPs within the MD SMS up to a critical size of ca. 1 nm, followed by a transition to more rapid growth by aggregation and fusion between MD SMS, similar to micelle aggregation reactions. Third, the stabilization of larger Ag NPs by adsorbed MD SMS is similar to hemi-micelle stabilization, and monomodal size distributions are proposed to relate to integer surface coverage of the Ag NPs. Conditions were identified for preparing Ag NPs with monomodal distributions centered at 30–35 nm Ag NPs.

  15. Microsoft Word - Rockwood _CFC_ Silver Peak Area Final EA V4...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ......... 7 Table 2: Well Drilling Specifics, Per Well ... and Chemicals Commonly Used During Well Drilling (Quantities Per Well) . 10 Table 4: ...

  16. Efficient surface plasmon amplification in gain-assisted silver nanotubes and associated dimers

    SciTech Connect (OSTI)

    Yu, HaiQun; Jiang, ShuMin; Wu, DaJian

    2015-04-21

    SPASER (surface plasmon amplification by stimulated emission of radiation) properties in active SiO{sub 2}Ag nanotubes and associated dimers have been investigated by using the scattering theory and the finite element method. In the active Ag nanotube, as the gain coefficient of the core increases to a critical value, a super-resonance occurs. The SPASER phenomenon also can be found in the active Ag nanotube dimer. The strong couplings between two nanotubes lead to larger gain threshold for the active Ag nanotube dimer compared with the active Ag nanotube. At the super-resonance, the maximal surface enhanced Raman scattering factor at the hot spot in the active Ag nanotube dimer can achieve about 8??10{sup 18}, which is large enough for single molecule detection. Furthermore, with increasing the separation between two Ag nanotubes, the gain threshold value for the super-resonance of the active Ag nanotube dimer decreases, while the corresponding super-resonance wavelength increases first and then decreases.

  17. Development of silver and zinc oxide decorated nanoclay containing polymeric composites for water disinfection applications

    SciTech Connect (OSTI)

    Motshekga, Sarah C.; Ray, Suprakas Sinha; Momba, Maggie N. B.

    2015-05-22

    Contaminated drinking water has serious implications to the human health that could lead to death. The rapid growth of bacterial contamination in drinking water is alarming, and yet a robust and cost effective method with less limitation has not been developed. The current study is aimed at evaluating the performance of nanoclay composites dispersed in chitosan biopolymer as an antibacterial material. The performances of the composites were evaluated using the batch kinetic studies. Three composites of Ag-CtsB, ZnO-CtsB and Ag/ZnO-CtsB were prepared and evaluated against gram negative Escherichia coli and gram positive Enterococcus faecalis bacteria. The composites were characterized by powder X-ray diffraction, scanning electron microscope, energy dispersive spectroscopy and BET surface area measurements. Antibacterial activity results showed that the composites can be a potent bactericide material for water disinfection as they are highly effective against both gram negative and gram positive bacteria tested. Whereas both Ag-CtsB and ZnO-CtsB composites showed good antibacterial activity against bacteria with removal efficiency from 51%, best antibacterial activity was observed with Ag/ZnO-CtsB composite with removal efficiency from 78%. The results revealed that Ag/ZnO-CtsB composite is a promising bactericide that is highly effective against both gram negative and gram positive bacteria tested.

  18. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionaliz...

    Office of Scientific and Technical Information (OSTI)

    and with high-resolution scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS) for the extent of densification and distribution of individual elements. ...

  19. A hydrogen peroxide electrochemical sensor based on silver nanoparticles decorated three-dimensional graphene

    SciTech Connect (OSTI)

    Zhan, Beibei; Liu, Changbing; Shi, Huaxia; Li, Chen; Wang, Lianhui [Key Laboratory for Organic Electronics and Information Displays (KLOEID), Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Huang, Wei, E-mail: iamxcdong@njtech.edu.cn, E-mail: iamwhuang@njtech.edu.cn; Dong, Xiaochen, E-mail: iamxcdong@njtech.edu.cn, E-mail: iamwhuang@njtech.edu.cn [Key Laboratory for Organic Electronics and Information Displays (KLOEID), Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Jiangsu-Singapore Joint Research Center for Organic/Bio-Electronics and Information Displays and Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816 (China)

    2014-06-16

    A facile strategy has been developed to synthesize sliver nanoparticles (Ag NPs) decorated three-dimensional graphene (3DG) through hydrothermal process. The AgNPs-3DG composites are directly fabricated into a free standing sensing electrode for electrochemical detection of hydrogen peroxide (H{sub 2}O{sub 2}) in phosphate buffered solutions. Various techniques equipments including scanning electron microscopy, X-ray diffraction, and Raman spectroscopy are used to characterize the morphology and structure of the as-prepared composite. The electrochemical experiments reveal the AgNPs-3DG based biosensor exhibits fast amperometric sensing, low detection limitation, wide linear responding range, and perfect selectivity for non-enzyme H{sub 2}O{sub 2} detection, indicating the well synergistic effect of Ag NPs high electrocatalytic activity and 3DG high conductivity and large surface area.

  20. 12-20-12-Signed-Chemetall-Foote-Silver-Peak-FONSI.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  1. EA-1921: Silver Peak Area Geothermal Exploration Project Environmental Assessment, Esmeralda County, Nevada

    Broader source: Energy.gov [DOE]

    The Bureau of Land Management (BLM)(lead agency) and DOE are jointly preparing this EA, which evaluates the potential environmental impacts of a project proposed by Rockwood Lithium Inc (Rockwood), formerly doing business as Chemetall Foote Corporation.

  2. Characterization of Dry-Air Aged Granules of Silver-Functionalized...

    Office of Scientific and Technical Information (OSTI)

    X-ray diffraction (XRD), and high resolution scanning electron microscopy (SEM). ... Radioiodine; Aging; Sorption; BET; SEM; XRD Word Cloud More Like This Full Text preview ...

  3. From Silver to Copper: SunShot Awardee TetraSun's Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consumers will soon have new options in their quest for the most efficient rooftop solar panels, thanks in part to former SunShot awardee TetraSun. Solar industry leader First ...

  4. In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bell, Nelson S.; Dunphy, Darren R.; Lambert, Timothy N.; Lu, Ping; Boyle, Timothy J.

    2015-06-26

    In this study, the use of maltodextrin supramolecular structures (MD SMS) as a reducing agent and colloidal stabilizing agent for the synthesis of Ag nanoparticles (Ag NPs) identified three key points. First, the maltodextrin (MD) solutions are effective in the formation of well-dispersed Ag NPs utilizing alkaline solution conditions, with the resulting Ag NPs ranging in size from 5 to 50 nm diameter. Second, in situ characterization by Raman spectroscopy and small angle X-ray scattering (SAXS) are consistent with initial nucleation of Ag NPs within the MD SMS up to a critical size of ca. 1 nm, followed by amore » transition to more rapid growth by aggregation and fusion between MD SMS, similar to micelle aggregation reactions. Third, the stabilization of larger Ag NPs by adsorbed MD SMS is similar to hemi-micelle stabilization, and monomodal size distributions are proposed to relate to integer surface coverage of the Ag NPs. Conditions were identified for preparing Ag NPs with monomodal distributions centered at 30–35 nm Ag NPs.« less

  5. "Self-assembly of uniform polyhedral silver nanocrystals into densest packings and exotic superlattices"

    SciTech Connect (OSTI)

    Henzie, Joel; Grunwald, Michael; Widmer-Cooper, Asaph; Geissler, Phillip L.; Yang, Peidong

    2011-03-01

    Understanding how polyhedra pack into extended arrangements is integral to the design and discovery of crystalline materials at all length scales. Much progress has been made in enumerating and characterizing the packing of polyhedral shapes, and the self-assembly of polyhedral nanocrystals into ordered superstructures. However, directing the self-assembly of polyhedral nanocrystals into densest packings requires precise control of particle shape, polydispersity,interactions and driving forces. Here we show with experiment and computer simulation that a range of nanoscale Ag polyhedra can self-assemble into their conjectured densest packings. When passivated with adsorbing polymer, the polyhedra behave as quasi-hard particles and assemble into millimetre-sized three-dimensional supercrystals by sedimentation.We also show, by inducing depletion attraction through excess polymer in solution, that octahedra form an exotic superstructure with complex helical motifs rather than the densest Minkowski lattice. Such large-scale Ag supercrystals may facilitate the design of scalable three-dimensional plasmonic metamaterials for sensing, nanophotonics, and photocatalysis.

  6. Soil Sampling At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  7. Field Mapping At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  8. Carlsbad Field Office Receives New Mexico’s Silver Award for Environmental Excellence

    Broader source: Energy.gov [DOE]

    CARLSBAD, N.M. – For the second year in a row, the New Mexico Environment Department (NMED) recognized the Carlsbad Field Office (CBFO) for its environmental stewardship by implementing pollution prevention practices and for excellence in long-term environmental and economic sustainability at the Waste Isolation Pilot Plant (WIPP).

  9. Lifetime of PWR silver-indium-cadmium control rods. Final report

    SciTech Connect (OSTI)

    Sipush, P.J.; Woodcock, J.; Chickering, R.W.

    1986-03-01

    A hot cell examination was performed on selected rodlets of a lead rod cluster control assembly (RCCA) which had experienced eleven cycles of operation in Point Beach Unit 1. The principal purpose of the program was to evaluate the performance of RCCAs. The hot cell examination of the rodlets involved detailed visual inspections, profilometry, metallography, cladding chemistry, dosimetry, scanning electron microscopy, corrosion tests, microhardness tests, absorber density measurements, and cladding tensile tests. Wear scars and a hairline crack in the cladding were evaluated. The results of the examinations and analysis of WEPCO site photographs led to an estimate of the service life for RCCAs which are used in Westinghouse 14 x 14 fuel assemblies. Also, wear scar widths were correlated with wear scar depths. The correlation may be used to estimate wear scar depths based on site photographs of wear scars for 14 x 14 RCCAs. The results of the program may be used as guidelines for RCCAs for 15 x 15 and 17 x 17 Westinghouse fuel designs. 10 refs., 89 figs., 26 tabs.

  10. 1,"Salt River Proj Ag I & P Dist",16572,1999,"Coronado","Silver...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 15,"Anchorage City of",599,1999,"Sub 15","APA Sub Tap",115,"Single Pole",0,0,"397 MCM ACSR",1 16,"Anchorage City of",599,1999,"APA Sub Tap","APA Sub",115,"Single Pole",0,0,"397 ...

  11. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionaliz...

    Office of Scientific and Technical Information (OSTI)

    with high-resolution scanning electron microscopy and energy dispersive spectroscopy (SEM-EDS) for the extent of densification and distribution of individual elements. The...

  12. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionaliz...

    Office of Scientific and Technical Information (OSTI)

    silica aerogels powders, with or without organic moiety and with or without sintering additive (colloidal silica), with three commercially available techniques: 1) hot uniaxial ...

  13. High Temperature Strength of YSZ Joints Brazed with Palladium Silver Copper Oxide Filler Metals

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2010-06-09

    The Ag-CuOx system is being investigated as potential filler metals for use in air brazing high-temperature electrochemical devices such as solid oxide fuel cells and gas concentrators. The current study examines the effects of palladium addition on the high temperature joint strength of specimens prepared from yttria stabilized zirconia (YSZ) bars brazed with the binary Ag-CuOx, and 15Pd-Ag-CuO. It was found that while the binary Ag-CuOx system exhibits stronger room temperature strength than the 15Pd system the strength is reduced to values equivalent of the 15Pd system at 800C. The 15Pd system exhibits a lower ambient temperature strength that is retained at 800C. In both systems the failure mechanism at high temperature appears to be peeling of the noble metal component from the oxide phases and tearing through the noble metal phase whereas sufficient adhesion is retained at lower temperatures to cause fracture of the YSZ substrate.

  14. Silver (Ag) Transport Mechanisms in TRISO coated particles: A Critical Review

    SciTech Connect (OSTI)

    I J van Rooyen; J H Neethling; J A A Engelbrecht; P M van Rooyen; G Strydom

    2012-10-01

    Transport of 110mAg in the intact SiC layer of TRISO coated particles has been studied for approximately 30 years without arriving at a satisfactory explanation of the transport mechanism. In this paper the possible mechanisms postulated in previous experimental studies, both in-reactor and out-of reactor research environment studies are critically reviewed and of particular interest are relevance to very high temperature gas reactor operating and accident conditions. Among the factors thought to influence Ag transport are grain boundary stoichiometry, SiC grain size and shape, the presence of free silicon, nano-cracks, thermal decomposition, palladium attack, transmutation products, layer thinning and coated particle shape. Additionally new insight to nature and location of fission products has been gained via recent post irradiation electron microscopy examination of TRISO coated particles from the DOEs fuel development program. The combined effect of critical review and new analyses indicates a direction for investigating possible the Ag transport mechanism including the confidence level with which these mechanisms may be experimentally verified.

  15. Schneider Electric Goes Platinum-and Silver-in Superior Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Performance(tm) (SEP) program and ISO 50001. Two Platinum level ... And all five earned certification in the ISO 50001 standard for energy management systems ...

  16. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionaliz...

    Office of Scientific and Technical Information (OSTI)

    removal and immobilization of radioiodine from the gas streams in a nuclear fuel reprocessing plant. One of these new sorbents, Ag0-functionalized silica aerogels, shows great...

  17. Amperometric detection and electrochemical oxidation of aliphatic amines and ammonia on silver-lead oxide thin-film electrodes

    SciTech Connect (OSTI)

    Ge, Jisheng

    1996-01-08

    This thesis comprises three parts: Electrocatalysis of anodic oxygen-transfer reactions: aliphatic amines at mixed Ag-Pb oxide thin-film electrodes; oxidation of ammonia at anodized Ag-Pb eutectic alloy electrodes; and temperature effects on oxidation of ethylamine, alanine, and aquated ammonia.

  18. Effect of Front-Side Silver Metallization on Underlying n+-p Junction in Multicrystalline Silicon Solar Cells: Preprint

    SciTech Connect (OSTI)

    Jiang, C. S.; Li, Z. G.; Moutinho, H. R.; Liang, L.; Ionkin, A.; Al-Jassim, M. M.

    2012-06-01

    We report on the effect of front-side Ag metallization on the underlying n+-p junction of multicrystalline Si solar cells. The junction quality beneath the contacts was investigated by characterizing the uniformities of the electrostatic potential and doping concentration across the junction, using scanning Kelvin probe force microscopy and scanning capacitance microscopy. We investigated cells with a commercial Ag paste (DuPont PV159) and fired at furnace setting temperatures of 800 degrees, 840 degrees, and 930 degrees C, which results in actual cell temperatures ~100 degrees C lower than the setting temperature and the three cells being under-, optimal-, and over-fired. We found that the uniformity of the junction beneath the Ag contact was significantly degraded by the over-firing, whereas the junction retained good uniformity with the optimal- and under-fire temperatures. Further, Ag crystallites with widely distributed sizes from <100 nm to several ?m were found at the Ag/Si interface of the over-fired cell. Large crystallites were imaged as protrusions into Si deeper than the junction depth. However, the junction was not broken down; instead, it was reformed on the entire front of the crystallite/Si interface. We propose a mechanism of the junction-quality degradation, based on emitter Si melting at the temperature around the Ag-Si eutectic point during firing, and subsequent recrystallization with incorporation of impurities in the Ag paste and with formation of crystallographic defects during quenching.

  19. Building America Whole-House Solutions for New Homes: Winchester Homes and Camberly Homes- Silver Spring, Maryland (Fact Sheet)

    Broader source: Energy.gov [DOE]

    The Partnership for Home Innovation team worked with the builder to develop a new set of high performance home designs—including advanced wall and HVAC systems—that could be applicable on a...

  20. Investigation of the Distribution of Fission Products Silver, Palladium and Cadmium in Neutron Irradiated SIC using a Cs Corrected HRTEM

    SciTech Connect (OSTI)

    I. J. van Rooyen; E. Olivier; J. H Neethlin

    2014-10-01

    Electron microscopy examinations of selected coated particles from the first advanced gas reactor experiment (AGR-1) at Idaho National Laboratory (INL) provided important information on fission product distribution and chemical composition. Furthermore, recent research using STEM analysis led to the discovery of Ag at SiC grain boundaries and triple junctions. As these Ag precipitates were nano-sized, high resolution transmission electron microscopy (HRTEM) examination was used to provide more information at the atomic level. This paper describes some of the first HRTEM results obtained by examining a particle from Compact 4-1-1, which was irradiated to an average burnup of 19.26% fissions per initial metal atom (FIMA), a time average, volume-averaged temperature of 1072C; a time average, peak temperature of 1182C and an average fast fluence of 4.13 x 1021 n/cm2. Based on gamma analysis, it is estimated that this particle may have released as much as 10% of its available Ag-110m inventory during irradiation. The HRTEM investigation focused on Ag, Pd, Cd and U due to the interest in Ag transport mechanisms and possible correlation with Pd, Ag and U previously found. Additionally, Compact 4-1-1 contains fuel particles fabricated with a different fuel carrier gas composition and lower deposition temperatures for the SiC layer relative to the Baseline fabrication conditions, which are expected to reduce the concentration of SiC defects resulting from uranium dispersion. Pd, Ag, and Cd were found to co-exist in some of the SiC grain boundaries and triple junctions whilst U was found to be present in the micron-sized precipitates as well as separately in selected areas at grain boundaries. This study confirmed the presence of Pd both at inter- and intragranular positions; in the latter case specifically at stacking faults. Small Pd nodules were observed at a distance of about 6.5 micron from the inner PyC/SiC interface.

  1. Triple plasmon resonance of bimetal nanoshell

    SciTech Connect (OSTI)

    Shirzaditabar, Farzad; Saliminasab, Maryam; Arghavani Nia, Borhan

    2014-07-15

    In this paper, light absorption spectra properties of a bimetal multilayer nanoshell based on quasi-static approach are investigated. Comparing with silver-dielectric-silver and silver-dielectric-gold nanoshells, gold-dielectric-silver nanoshells have three intense and separated plasmon peaks which are more suitable for multiplex biosensing. Calculations show that relatively small thickness of outer silver shell and large dielectric constant of middle dielectric layer of gold-dielectric-silver nanoshell are suitable to obtain the triple plasmon resonance.

  2. Redwood City, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Registered Energy Companies in Redwood City, California Codexis Inc Nanostellar Inc Potter Drilling Silver Spring Networks Silver Spring Networks Inc Trilliant Inc Trilliant...

  3. Power Right. Power Smart. Efficient Computer Power Supplies and...

    Energy Savers [EERE]

    to introduce higher efficiency levels of Certification in 2008: Bronze, Silver, and Gold. 80+ Bronze 80+ Silver 80+ Gold Load Efficiency Efficiency Efficiency 20% 82% 85% 87%...

  4. Prediction of the thermodynamic properties of gold, arsenic,...

    Office of Scientific and Technical Information (OSTI)

    The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver Brad Bessinger ... The HKF equation of state parameters for gold, arsenic, antimony, mercury, and silver ...

  5. ACEEE SEP Paper with contacts.pptx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 4 Performance Characteristics Silver Gold Platinum Energy Performance Pathway Energy ... via Energy Performance Pathway Silver Gold Platinum Issue - Understanding the SEP ...

  6. OI

    Office of Scientific and Technical Information (OSTI)

    ... of pounds of potentially useful, valuable metals, including gold, silver and copper. ... metals such as gold, silver, and copper, after the vitrified waste cools. ...

  7. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Silver Functionalized Silica Aerogel Matyas Josef Fryxell Glen E Robinson Matthew J Reprocessing Silver functionalized arogel Radioiodine Aging Sorption BET SEM XRD Reprocessing...

  8. Before the Senate Energy and Natural Resources Committee

    Office of Energy Efficiency and Renewable Energy (EERE)

    Subject: DOE Loan Guarantee Program By: Jonathan Silver, Executive Director Office of Loan Guarantee Programs

  9. EERE Success Story—From Silver to Copper: SunShot Awardee TetraSun’s Technology to be Mass Produced

    Broader source: Energy.gov [DOE]

    Consumers will soon have new options in their quest for the most efficient rooftop solar panels, thanks in part to former SunShot awardee TetraSun. Solar industry leader First Solar, which operates...

  10. Winchester Homes and Camberley Homes, Silver Spring, Maryland (Fact Sheet), Building America Case Study: Whole-House Solutions for New Homes, Building Technologies Office (BTO)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EFFICIENCY MEASURESS * Single seasonal energy efficiency ratio 15 AC; 2-stage 92.5% annual fuel utilization efficiency furnace with electronically commutated motor (ECM) blower * Continuously operating ECM air handler motor * Duct system entirely in conditioned space. Duct leakage to outside = 43 cfm @ 25 Pa * Supply-only ventilation; fresh air introduced in return ducts, damper programmed to open 60% of time ENVELOPE * 2×6 frame, 24-in. on-center with structural rim headers, R-24 blown

  11. Winchester Homes and Camberley Homes, Silver Spring, Maryland (Fact Sheet), Building America Case Study: Whole-House Solutions for New Homes, Building Technologies Office (BTO)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EFFICIENCY MEASURES * Single seasonal energy efficiency ratio 15 AC; 2-stage 92.5% annual fuel utilization efficiency furnace with electronically commutated motor (ECM) blower * Continuously operating ECM air handler motor * Duct system entirely in conditioned space. Duct leakage to outside = 43 cfm @ 25 Pa * Supply-only ventilation; fresh air introduced in return ducts, damper programmed to open 60% of time ENVELOPE * 2×6 frame, 24-in. on-center with structural rim headers, R-24 blown

  12. DOI-BLM-NV-B020-2011-0017-CX | Open Energy Information

    Open Energy Info (EERE)

    17-CX Jump to: navigation, search NEPA Document Collection for: DOI-BLM-NV-B020-2011-0017-CX CX at Silver Peak Geothermal Area for GeothermalExploration CX at Silver Peak...

  13. DOI-BLM-NV-B020-2011-0048-CX | Open Energy Information

    Open Energy Info (EERE)

    48-CX Jump to: navigation, search NEPA Document Collection for: DOI-BLM-NV-B020-2011-0048-CX CX at Silver Peak Geothermal Area for GeothermalExploration CX at Silver Peak...

  14. DOI-BLM-NV-B020-2008-????-CX | Open Energy Information

    Open Energy Info (EERE)

    CX Jump to: navigation, search NEPA Document Collection for: DOI-BLM-NV-B020-2008-????-CX CX at Silver Peak Geothermal Area for GeothermalExploration CX at Silver Peak Geothermal...

  15. Application Of Fluid Inclusion And Rock-Gas Analysis In Mineral...

    Open Energy Info (EERE)

    to analyze these gases in fluid inclusions in jasperoid around the Pueblo Viejo gold-silver deposit, in vein minerals from the Creede silver-lead-zinc deposit, and from...

  16. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    measurements of the equation of state of a Gold-Silver alloy (23.5 wt-% Ag) at room ... EOS curves of silver and gold, taken from the literature, are shown for comparison. We fit ...

  17. DOE ZERH Webinar: Going Green and Building Strong: Building FORTIFIED...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... is a hazard- specific program that is divided into three levels, Bronze, Silver, and Gold. ... and the attic. Silver, we focus on the openings, and in Gold, we fortify the structure. ...

  18. Au-Ag Alloy Static High Pressure EOS measurements: FY09 summary...

    Office of Scientific and Technical Information (OSTI)

    Static high-pressure measurements of the equation of state of a Gold-Silver alloy (23.5 ... EOS curves of silver and gold, taken from the literature, are shown for comparison. We fit ...

  19. Piezoelectric and luminescent properties of ZnO nanostructures...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 36 MATERIALS SCIENCE; NANOSTRUCTURES; ZINC OXIDES; PIEZOELECTRICITY; LUMINESCENCE; SILVER; SUBSTRATES Word Cloud ...

  20. EA-1715: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Chemetall Foote Corporation, Electric Drive Vehicle Battery and Component Manufacturing Initiative, Kings Mountain, North Carolina and Silver Peak, Nevada

  1. EA-1715: Final Environmental Assessment

    Broader source: Energy.gov [DOE]

    Chemetall Foote Corporation Electric Drive Vehicle Battery and Component Manufacturing Initiative Kings Mountain, NC and Silver Peak, Nevada

  2. Biomolecular interactions and responses of human epithelial and...

    Office of Scientific and Technical Information (OSTI)

    lines that were exposed to different sized gold and silver nanoparticles using advanced ... CHEMISTRY; CLOTHING; FLUORESCENCE; GOLD; MACROPHAGES; MASS SPECTROSCOPY; ...

  3. McLeod County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Minnesota Lester Prairie, Minnesota Plato, Minnesota Silver Lake, Minnesota Stewart, Minnesota Winsted, Minnesota Retrieved from "http:en.openei.orgw...

  4. Thin film solar energy collector

    DOE Patents [OSTI]

    Aykan, Kamran (Monmouth Beach, NJ); Farrauto, Robert J. (Westfield, NJ); Jefferson, Clinton F. (Millburn, NJ); Lanam, Richard D. (Westfield, NJ)

    1983-11-22

    A multi-layer solar energy collector of improved stability comprising: (1) a substrate of quartz, silicate glass, stainless steel or aluminum-containing ferritic alloy; (2) a solar absorptive layer comprising silver, copper oxide, rhodium/rhodium oxide and 0-15% by weight of platinum; (3) an interlayer comprising silver or silver/platinum; and (4) an optional external anti-reflective coating, plus a method for preparing a thermally stable multi-layered solar collector, in which the absorptive layer is undercoated with a thin film of silver or silver/platinum to obtain an improved conductor-dielectric tandem.

  5. Nuclear radiation-warning detector that measures impedance

    DOE Patents [OSTI]

    Savignac, Noel Felix; Gomez, Leo S; Yelton, William Graham; Robinson, Alex; Limmer, Steven

    2013-06-04

    This invention is a nuclear radiation-warning detector that measures impedance of silver-silver halide on an interdigitated electrode to detect light or radiation comprised of alpha particles, beta particles, gamma rays, X rays, and/or neutrons. The detector is comprised of an interdigitated electrode covered by a layer of silver halide. After exposure to alpha particles, beta particles, X rays, gamma rays, neutron radiation, or light, the silver halide is reduced to silver in the presence of a reducing solution. The change from the high electrical resistance (impedance) of silver halide to the low resistance of silver provides the radiation warning that detected radiation levels exceed a predetermined radiation dose threshold.

  6. Method and etchant to join Ag-clad BSSCO superconducting tape

    DOE Patents [OSTI]

    Balachandran, U.; Iyer, A.N.; Huang, J.Y.

    1999-03-16

    A method of removing a silver cladding from high temperature superconducting material clad in silver (HTS) is disclosed. The silver clad HTS is contacted with an aqueous solution of HNO{sub 3} followed by an aqueous solution of NH{sub 4}OH and H{sub 2}O{sub 2} for a time sufficient to remove the silver cladding from the superconducting material without adversely affecting the superconducting properties of the superconducting material. A portion of the silver cladding may be masked with a material chemically impervious to HNO{sub 3} and to a combination of NH{sub 4}OH and H{sub 2}O{sub 2} to preserve the Ag coating. A silver clad superconductor is disclosed, made in accordance with the method discussed. 3 figs.

  7. Method and etchant to join ag-clad BSSCO superconducting tape

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Iyer, Anand N. (Downers Grove, IL); Huang, Jiann Yuan (Hsinchu, TW)

    1999-01-01

    A method of removing a silver cladding from high temperature superconducting material clad in silver (HTS) is disclosed. The silver clad HTS is contacted with an aqueous solution of HNO.sub.3 followed by an aqueous solution of NH.sub.4 OH and H.sub.2 O.sub.2 for a time sufficient to remove the silver cladding from the superconducting material without adversely affecting the superconducting properties of the superconducting material. A portion of the silver cladding may be masked with a material chemically impervious to HNO.sub.3 and to a combination of NH.sub.4 OH and H.sub.2 O.sub.2 to preserve the Ag coating. A silver clad superconductor is disclosed, made in accordance with the method discussed.

  8. Hanford Blog Archive - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 2013 January 23, 2013 ORP Chief of Staff Receives NNSA Silver Medal Erik Olds, Chief of Staff for the Office of River Protection, has received the NNSA Silver Medal. Presented by Tom D'Agostino, Undersecretary for Nuclear Security and Administrator of the National Nuclear Security Administration, the Silver Medal Award is one of the highest awards given by the NNSA, and acknowledges the recipient's excellence in service. January 17, 2013 PHOTO GALLERY: Tokyo Electric Power Company Visits

  9. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Koermer, Gerald S. (Basking Ridge, NJ); Moini, Ahmad (Princeton, NJ); Furbeck, Howard (Hamilton, NJ); Castellano, Christopher R. (Ringoes, NJ)

    2012-05-08

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver on a particulate alumina support, the silver having a diameter of less than about 20 nm. Methods of manufacturing catalysts are described in which ionic silver is impregnated on particulate hydroxylated alumina particles.

  10. METAL COATED ARTICLES AND METHOD OF MAKING

    DOE Patents [OSTI]

    Eubank, L.D.

    1958-08-26

    A method for manufacturing a solid metallic uranium body having an integral multiple layer protective coating, comprising an inner uranium-aluminum alloy firmly bonded to the metallic uranium is presented. A third layer of silver-zinc alloy is bonded to the zinc-aluiminum layer and finally a fourth layer of lead-silver alloy is firmly bonded to the silver-zinc layer.

  11. Project Profile: Cleanable and Hardcoat Coatings for Increased Durability

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Silvered Polymeric Mirrors | Department of Energy Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors Project Profile: Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors 3M logo 3M, under the CSP R&D FOA, is developing optical coatings for solar mirrors that are durable, easily maintained, and more cost-effective. Approach Diagram of the most successful coatings identified by the research team based on the mix of

  12. METHOD OF REMOVING IODINE FROM GASES AND FILTER MEDIUM THEREFOR

    DOE Patents [OSTI]

    Silverman, L.

    1961-08-01

    A method for the removal of iodine from large gas volumes is described. The gaseous medium is heated to a temperature not exceeding 400 deg C. Water vapor is then added to the medium in approximate amounts of 1 lb/cu ft of the medium. The medium is then passed through a porous copper fibrous pad having deposited thereon a coating of silver, the silver coating being treated with hydrogen sulfide forming a layer of silver sulfide. (AEC)

  13. Building America Whole-House Solutions for New Homes: Winchester Homes and

    Energy Savers [EERE]

    Camberly Homes - Silver Spring, Maryland (Fact Sheet) | Department of Energy Winchester Homes and Camberly Homes - Silver Spring, Maryland (Fact Sheet) Building America Whole-House Solutions for New Homes: Winchester Homes and Camberly Homes - Silver Spring, Maryland (Fact Sheet) The Partnership for Home Innovation team worked with the builder to develop a new set of high performance home designs-including advanced wall and HVAC systems-that could be applicable on a production scale. PDF

  14. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    for Municipal Buildings The first building completed under this policy was the Jack Evans Police Headquarters, which obtained LEED Silver certification in December 2005. As of...

  15. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Policy for Municipal Buildings The first building completed under this policy was the Jack Evans Police Headquarters, which obtained LEED Silver certification in December 2005....

  16. CPV Wind Ventures LLC | Open Energy Information

    Open Energy Info (EERE)

    Ventures LLC Jump to: navigation, search Name: CPV Wind Ventures LLC Place: Silver Spring, Maryland Zip: 20910 Sector: Wind energy Product: Wind power project developer....

  17. Madison County, Montana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Number 6 Climate Zone Subtype B. Places in Madison County, Montana Alder, Montana Big Sky, Montana Ennis, Montana Harrison, Montana Norris, Montana Sheridan, Montana Silver...

  18. Electrochemical and Antimicrobial Properties of Diamondlike Carbon-Metal Composite Films

    SciTech Connect (OSTI)

    MORRISON, M. L.; BUCHANAN, R. A.; LIAW, P. K.; BERRY, C. J.; BRIGMON, R.; RIESTER, L.; JIN, C.; NARAYAN, R. J.

    2005-05-11

    Implants containing antimicrobial metals may reduce morbidity, mortality, and healthcare costs associated with medical device-related infections. We have deposited diamondlike carbon-silver (DLC-Ag), diamondlike carbon-platinum (DLC-Pt), and diamondlike carbon-silver-platinum (DLC-AgPt) thin films using a multicomponent target pulsed laser deposition process. Transmission electron microscopy of the DLC-silver and DLC-platinum composite films revealed that the silver and platinum self-assemble into nanoparticle arrays within the diamondlike carbon matrix. The diamondlike carbon-silver film possesses hardness and Young's modulus values of 37 GPa and 331 GPa, respectively. The diamondlike carbon-metal composite films exhibited passive behavior at open-circuit potentials. Low corrosion rates were observed during testing in a phosphate-buffered saline (PBS) electrolyte. In addition, the diamondlike carbon-metal composite films were found to be immune to localized corrosion below 1000 mV (SCE). DLC-silver-platinum films demonstrated exceptional antimicrobial properties against Staphylococcus bacteria. It is believed that a galvanic couple forms between platinum and silver, which accelerates silver ion release and provides more robust antimicrobial activity. Diamondlike carbon-silver-platinum films may provide unique biological functionalities and improved lifetimes for cardiovascular, orthopaedic, biosensor, and implantable microelectromechanical systems.

  19. New Director to lead Technology Development and Commercialization...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of photographic imaging supports, the creation of a silver nanomaterials-based antimicrobial business and was a Director with the Corporate Venture Capital group; and at Union...

  20. Suresh Sunderrajan | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of photographic imaging supports, the creation of a silver nanomaterials-based antimicrobial business, and was a Director of the Corporate Venture Capital group; and at Union...

  1. EM News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at DOE headquarters. November 25, 2015 SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. Passive...

  2. Nevada/Geothermal | Open Energy Information

    Open Energy Info (EERE)

    Confirmation Silver Peak Geothermal Area Walker-Lane Transition Zone Geothermal Region Smith Creek Geothermal Project Ormat Phase I - Resource Procurement and Identification Smith...

  3. Platinum Nanoclusters Out-Perform Single Crystals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in platinum. Exploring metals that catalyze other important reactions-such as palladium, silver, copper, rhodium, iron, and cobalt-might also help researchers determine...

  4. Hydrostatic extrusion of Cu-Ag melt spun ribbon

    DOE Patents [OSTI]

    Hill, M.A.; Bingert, J.F.; Bingert, S.A.; Thoma, D.J.

    1998-09-08

    The present invention provides a method of producing high-strength and high-conductance copper and silver materials comprising the steps of combining a predetermined ratio of the copper with the silver to produce a composite material, and melt spinning the composite material to produce a ribbon of copper and silver. The ribbon of copper and silver is heated in a hydrogen atmosphere, and thereafter die pressed into a slug. The slug then is placed into a high-purity copper vessel and the vessel is sealed with an electron beam. The vessel and slug then are extruded into wire form using a cold hydrostatic extrusion process. 5 figs.

  5. City of Plano- Green Building Policy for Municipal Buildings

    Broader source: Energy.gov [DOE]

    Return on investment will be considered when determining feasibility of implementing green features. While pursuing the highest level of LEED certification possible, the level (certified, silver,...

  6. Other Participants 1999 | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    School , Milwaukee , WI Mira Loma High School , Sacramento , CA Mississippi School for Math & Science, Columbus , MS Montgomery Blair High School , Silver Spring , MD Montgomery ...

  7. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    50% of the building occupants to relocate, or involves replacing the HVAC systems. The Green Buildings Program encourages certification beyond Silver (to Gold or Platinum) when...

  8. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Deep Bed Adsorption Testing using Silver Functionalized Aerogel Nick Soelberg Tony Watson MGMT OF RADIOACTIVE AND NON RADIOACTIVE WASTES FROM NUCLEAR FACILITIES aerogel iodine...

  9. ZPower | Open Energy Information

    Open Energy Info (EERE)

    Place: Camarillo, California Zip: 93012 Product: Maker of rechargeable, silver-zinc batteries for mobile electronics. Coordinates: 34.222895, -119.050719 Show Map Loading...

  10. Building America Whole-House Solutions for New Homes: Winchester...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Whole-House Solutions for New Homes: Winchester Homes and Camberly Homes - Silver Spring, Maryland (Fact Sheet) Building America Whole-House Solutions for New ...

  11. SunShot-Supported Companies to Build One of the World's Largest...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    enhanced chemical vapor deposition thin-film manufacturing tool, leveraging tool ... From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced ...

  12. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    feet in size are required to be designed, contracted, and built to achieve the U.S. Green Building Council's Leadership in Energy and Environmental Design (LEED) Silver...

  13. Property:GEADevelopmentPhase | Open Energy Information

    Open Energy Info (EERE)

    San Jacinto Geothermal Area Silver Peak Geothermal Area Simbach Braunau Geothermal Area Smith Creek Valley Geothermal Area Soda Lake Geothermal Area Soultz Geothermal Area South...

  14. Lyon County, Nevada: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Places in Lyon County, Nevada Dayton, Nevada Fernley, Nevada Silver Springs, Nevada Smith Valley, Nevada Wabuska, Nevada Yerington, Nevada Retrieved from "http:en.openei.org...

  15. Guides and Case Studies for Mixed-Humid Climates | Department...

    Broader source: Energy.gov (indexed) [DOE]

    homes features SIP walls, geothermal heat pumps, solar PV, and a proprietary energy management system. Project: Winchester Homes and Camberly Homes - Silver Spring...

  16. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    and Environmental Design (LEED) Silver certification level or two Green Globes under the Green Globes Design Rating System. Future major renovations and non-occupied City...

  17. Metal nanoparticle inks

    DOE Patents [OSTI]

    Lewis, Jennifer A. (Urbana, IL); Ahn, Bok Yeop (Champaign, IL); Duoss, Eric B. (Urbana, IL)

    2011-04-12

    Stabilized silver particles comprise particles comprising silver, a short-chain capping agent adsorbed on the particles, and a long-chain capping agent adsorbed on the particles. The short-chain capping agent is a first anionic polyelectrolyte having a molecular weight (Mw) of at most 10,000, and the long-chain capping agent is a second anionic polyelectrolyte having a molecular weight (Mw) of at least 25,000. The stabilized silver particles have a solid loading of metallic silver of at least 50 wt %.

  18. Site-Specific Synthesis and In Situ Immobilization of Fluorescent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Site-Specific Synthesis and In Situ Immobilization of Fluorescent Silver Nanoclusters on DNA Nanoscaffolds by Use of the Tollens Reaction Authors: Pal, S., Varghese, R., Deng, Z.,...

  19. Characterization of Pipes, Drain Lines, and Ducts using the Pipe...

    Office of Scientific and Technical Information (OSTI)

    ... The inorganic scintillator, silver-activated zinc sulfide (ZnSAg), offers an attractive alternative to plastic scintillators. It has a much higher light output than the plastic ...

  20. C:\\Documents and Settings\\utigerkc\\My Documents\\EDITING\\spie...

    Office of Scientific and Technical Information (OSTI)

    ... It consists of zinc sulfide (silver) (ZnSAg) phosphor embedded in a clear hydrogenous ... recoil interaction in the scintillator, the proton being detected by the zinc sulfide. ...

  1. Mimbres Hot Springs Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Spa Low Temperature Geothermal Facility Facility Mimbres Hot Springs Sector Geothermal energy Type Pool and Spa Location Silver City, New Mexico Coordinates 32.770075,...

  2. The Wilderness Lodge Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Low Temperature Geothermal Facility Facility The Wilderness Lodge Sector Geothermal energy Type Pool and Spa Location Silver City, New Mexico Coordinates 32.770075,...

  3. Barkell's Hot Springs Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Spa Low Temperature Geothermal Facility Facility Barkell's Hot Springs Sector Geothermal energy Type Pool and Spa Location Silver Star, Montana Coordinates 45.690204,...

  4. Nucleation of AgInSbTe films employed in phase-change media ...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 36 MATERIALS SCIENCE; ANTIMONY ... MATERIALS; SILVER COMPOUNDS; TELLURIUM COMPOUNDS; TEMPERATURE DEPENDENCE; THIN FILMS Word Cloud More Like This ...

  5. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    constructed by and for the town to achieve a Silver level certification in the U.S. Green Building... Eligibility: Construction, Local Government Savings Category: Solar -...

  6. Interested Parties- LGPO

    Broader source: Energy.gov [DOE]

    Jonathan Silver, Executive Director of the Loan Program Office, reporting has contact with lobbyists from the American Wind Energy Association, Geothermal Energy Association, Solar Energy...

  7. Hoke County, North Carolina: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    Carolina Dundarrach, North Carolina Five Points, North Carolina Raeford, North Carolina Red Springs, North Carolina Rockfish, North Carolina Silver City, North Carolina Retrieved...

  8. Environmental Assessments (EA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Draft Environmental Assessment Silver Peak Area Geothermal Exploration Project, Esmeralda County, NV October 1, 2012 EA-1863: Final Environmental Assessment Vegetation...

  9. Findings of No Significant Impact (FONSI) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Finding of No Significant Impact Silver Peak Area Geothermal Exploration Project, Esmeralda County, NV December 7, 2012 EA-1863: Finding of No Significant Impact Vegetation...

  10. EA-1921: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Finding of No Significant Impact Silver Peak Area Geothermal Exploration Project, Esmeralda County, NV Based on the evaluations in the final EA and subject to the mitigations...

  11. Environmental Assessments (EA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment Silver Peak Area Geothermal Exploration Project Environmental Assessment, Esmeralda County, NV December 12, 2012 EA-1919: Draft Programmatic Environmental Assessment...

  12. DOI-BLM-NV-B020-2011-0026-EA | Open Energy Information

    Open Energy Info (EERE)

    Environmental Analysis Type EA Applicant Ram Power Consultant EPG, Inc., Environmental Management Associates Geothermal Area Silver Peak Geothermal Area Project Location Nevada...

  13. Project Profile: Cleanable and Hardcoat Coatings for Increased...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved abrasion resistance and cleanability of the front surface of a silvered polymeric mirror is expected to decrease the rate of reflectance loss and irreversible soiling by ...

  14. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    the Department of Education offers an additional reimbursement to schools that build or renovate to LEED silver or higher, or achieve two or more... Eligibility: Schools...

  15. Demand Response Research Center and Open Automated Demand Response

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...penAutomatedDemandResponse Signaling-conInuous,2-way, ... Dedicated Display Cell Phone Web TV SmartMeter (ItronorSilverSpring) ...

  16. Merrick County, Nebraska: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Platte Valley Fuel Ethanol Places in Merrick County, Nebraska Central City, Nebraska Chapman, Nebraska Clarks, Nebraska Palmer, Nebraska Silver Creek, Nebraska Retrieved from...

  17. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    and design costs associated with new buildings meeting this standard, the goal of Gold can be reduced to Silver for projects where the payback period for earning Gold......

  18. City of Bloomington - Green Building Requirements for Municipal...

    Broader source: Energy.gov (indexed) [DOE]

    HVAC systems. The Green Buildings Program encourages certification beyond Silver (to Gold or Platinum) when possible. Furthermore, the ordinance establishes that the city's...

  19. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    HVAC systems. The Green Buildings Program encourages certification beyond Silver (to Gold or Platinum) when possible. Furthermore, the ordinance... Eligibility: Local Government...

  20. Creation of Light and/or Surface Plasmons with Heated Metallic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plasmonic device can be made from different metals such as tungsten, gold and silver or other combinations of materials. The wavelength of the emitted light can...

  1. Electrical Resistivity and Self-Potential Surveys Blue Mountain...

    Open Energy Info (EERE)

    and induced polarization anomalies also correspond to the main known occurrence of gold-silver which is associated with pyrite mineralization. Authors Howard P. Ross, David R....

  2. Recognition and Awards Program - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DOE Human Resources Management Division DOE Employment Recognition and Awards Program Gold Awards Silver Award Federal Employees Union (AFGE Local 788) Work Schedules Pay and...

  3. EIS-0393: Final Environmental Impact Statement | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    issued a Final EIS that evaluates the potential environmental impacts of a proposed copper and silver underground mine about 18 miles south of Libby, Montana. DOE's Bonneville...

  4. EIS-0393: EPA Notice of Availability of Final Environmental Impact...

    Energy Savers [EERE]

    of Environmental Quality to evaluate the potential environmental impacts of a proposed copper and silver underground mine about 18 miles south of Libby, Montana. DOE's Bonneville...

  5. EIS-0393: Montanore Project, Montana | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    prepared an EIS that evaluates the potential environmental impacts of a proposed copper and silver underground mine about 18 miles south of Libby, Montana. DOE's Bonneville...

  6. Hydrostatic extrusion of Cu-Ag melt spun ribbon

    DOE Patents [OSTI]

    Hill, Mary Ann (Los Alamos, NM); Bingert, John F. (Jemez Springs, NM); Bingert, Sherri A. (Jemez Springs, NM); Thoma, Dan J. (Los Alamos, NM)

    1998-01-01

    The present invention provides a method of producing high-strength and high-conductance copper and silver materials comprising the steps of combining a predetermined ratio of the copper with the silver to produce a composite material, and melt spinning the composite material to produce a ribbon of copper and silver. The ribbon of copper and silver is heated in a hydrogen atmosphere, and thereafter die pressed into a slug. The slug then is placed into a high-purity copper vessel and the vessel is sealed with an electron beam. The vessel and slug then are extruded into wire form using a cold hydrostatic extrusion process.

  7. Volume Visualization

    Office of Scientific and Technical Information (OSTI)

    ... Visualization of biological sequence similarity search results. In Gregory M. Nielson and Deborah Silver, editors, Proceedings of IEEE Vi- sualization 1995, IEEE Visualization, ...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (ARPA-E) USDOE Energy Information Administration (EI) ... States) USDOE Office of Electricity Delivery and Energy ... Rothamsted:) ; et al August 2015 Silver speciation and ...

  9. Most Viewed Documents for Geosciences: September 2014 | OSTI...

    Office of Scientific and Technical Information (OSTI)

    ... using the New Zealand geothermal system Glassley, W. (1992) 17 The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver Bessinger, Brad; Apps, John A. (2003) 16

  10. Superior Energy Performance: Certifying Increased Energy Productivity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... years + 30 Best Practice Scorecard points Gold 10% energy performance improvement over 3 ... 2) Schneider Electric Columbia, MO GOLD SILVER 3M Company Cordova, IL Olam Spices ...

  11. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... lines that were exposed to different sized gold and silver nanoparticles using advanced ... Highly Ordered Tailored Three-Dimensional Hierarchical Porous Gold Architectures. Polsky, ...

  12. September 2013 Most Viewed Documents for Geosciences | OSTI,...

    Office of Scientific and Technical Information (OSTI)

    OF OIL RESERVOIRS Innocent J. Aluka (2004) 16 > The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver Bessinger, Brad; Apps, John A. (2003) 16 > High ...

  13. 2007 Federal Energy and Water Management Award Winners | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FEMP expressed appreciation for these efforts by presenting an additional team award to three groups. Gold Award United States Air Force Kirtland Air Force Base, New Mexico Silver ...

  14. Most Viewed Documents for Geosciences: December 2014 | OSTI,...

    Office of Scientific and Technical Information (OSTI)

    Sonia; Spycher, Nicolas; Sonnenthal, Eric L. (2003) 16 The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver Bessinger, Brad; Apps, John A. (2003) 16 ...

  15. Schneider Electric Boasts Ten Facilities Certified to Superior...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    over three years. Facilities in Peru, Indiana and Columbia, South Carolina earned Gold level certification, while the Rojo Gomez, Mexico location earned Silver level certification. ...

  16. Industrial Ratepayer-Funded SEP Toolkit | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ISO 50001. An independent third party audits each facility to verify its achievements and qualify it at the Silver, Gold, or Platinum level based on energy performance improvement. ...

  17. June 2014 Most Viewed Documents for Geosciences | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    Eric; Spycher, Nicolas; Pruess, Karsten (2004) 12 > The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver Bessinger, Brad; Apps, John A. (2003) 12 > ...

  18. Fiscal Year 2014 GreenBuy Award Winners Announced | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gold Level Award Winners:Argonne National Laboratory Lawrence Livermore National ... Sites can qualify for GreenBuy Awards at three levels - Gold, Silver, or Bronze - based on ...

  19. The Superior Energy Performance program, administered by DOE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SEP Certified facilities can earn silver, gold, or platinum designation according to the ... Gold Allsteel Muscatine, IA CCP Composites US LLC Houston, TX Coca-Cola ...

  20. Lead-Free Solder Paste | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hazard, that's not its only advantage," says Ames Lab's Iver Anderson, co-inventor of a new solder from tin, silver and copper. "We worked with different alloy...

  1. CX-009210: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Silver Butte Fiber Burial Project CX(s) Applied: B.47 Date: 08/28/2012 Location(s): Montana, Montana Offices(s): Bonneville Power Administration

  2. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    While pursuing the highest level of LEED certification possible, the level (certified, silver,... Eligibility: Local Government Savings Category: Solar - Passive, Solar Water...

  3. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    LEED Silver rating, a two-globe rating on the Green Building Initiative Green Globe rating system, or a comparable numeric rating from another accredited sustainable building...

  4. FY 2014 Annual Progress Report - Propulsion Materials Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... thermal management of advanced power ... Program Organization The Propulsion Materials Program consists of the following five R&D ... Silver Sintering A journal article was ...

  5. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Northwest National Laboratory (PNNL), Richland, WA (US)","USDOE","Reprocessing; Silver-functionalized arogel; Radioiodine; Aging; Sorption; BET; SEM; XRD",,"This...

  6. Cetech America | Open Energy Information

    Open Energy Info (EERE)

    Cetech America Jump to: navigation, search Logo: Cetech America Name: Cetech America Address: 711 Silver Birch Place Place: Longwood, Florida Zip: 32750 Sector: Solar Year...

  7. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  8. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  9. Epoxidation catalyst and process

    DOE Patents [OSTI]

    Linic, Suljo (Ann Arbor, MI); Christopher, Phillip (Ann Arbor, MI)

    2010-10-26

    Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

  10. FINE GRAIN NUCLEAR EMULSION

    DOE Patents [OSTI]

    Oliver, A.J.

    1962-04-24

    A method of preparing nuclear track emulsions having mean grain sizes less than 0.1 microns is described. The method comprises adding silver nitrate to potassium bromide at a rate at which there is always a constant, critical excess of silver ions. For minimum size grains, the silver ion concentration is maintained at the critical level of about pAg 2.0 to 5.0 during prectpitation, pAg being defined as the negative logarithm of the silver ion concentration. It is preferred to eliminate the excess silver at the conclusion of the precipitation steps. The emulsion is processed by methods in all other respects generally similar to the methods of the prior art. (AEC)

  11. Method for producing microcomposite powders using a soap solution

    DOE Patents [OSTI]

    Maginnis, Michael A. (Coker, AL); Robinson, David A. (Mobile, AL)

    1996-01-01

    A method for producing microcomposite powders for use in superconducting and non-superconducting applications. A particular method to produce microcomposite powders for use in superconducting applications includes the steps of: (a) preparing a solution including ammonium soap; (b) dissolving a preselected amount of a soluble metallic such as silver nitrate in the solution including ammonium soap to form a first solution; (c) adding a primary phase material such as a single phase YBC superconducting material in particle form to the first solution; (d) preparing a second solution formed from a mixture of a weak acid and an alkyl-mono-ether; (e) adding the second solution to the first solution to form a resultant mixture; (f) allowing the resultant mixture to set until the resultant mixture begins to cloud and thicken into a gel precipitating around individual particles of the primary phase material; (g) thereafter drying the resultant mixture to form a YBC superconducting material/silver nitrate precursor powder; and (h) calcining the YBC superconducting material/silver nitrate precursor powder to convert the silver nitrate to silver and thereby form a YBC/silver microcomposite powder wherein the silver is substantially uniformly dispersed in the matrix of the YBC material.

  12. Application of a new coordination compound for the preparation of AgI nanoparticles

    SciTech Connect (OSTI)

    Mohandes, Fatemeh; Salavati-Niasari, Masoud

    2013-10-15

    Graphical abstract: Silver iodide nanoparticles have been sonochemically synthesized by using silver salicylate complex, [Ag(HSal)], as silver precursor. A series of control experiments were carried out to investigate the effects of solvent, surfactant concentration, sonication time and temperature on the morphology of AgI nanostructures. - Highlights: Silver salicylate as a new precursor was applied to fabricate ?-AgI nanoparticles. To further decrease the particle size of AgI, SDS was used as surfactant. The effect of preparation parameters on the particle size of AgI was investigated. - Abstract: AgI nanoparticles have been sonochemically synthesized by using silver salicylate, [Ag(HSal)], as silver precursor. To investigate the effects of solvent, surfactant concentration, sonication time and temperature on the morphology of AgI nanostructures, several experiments were carried out. The products were characterized by SEM, TEM, XRD, TGA/DTA, UVvis, and FT-IR. Based on the experimental findings in this research, it was found that the size of AgI nanoparticles was dramatically dependent on the silver precursor, sonochemical irradiation, and surfactant concentration. Sodium dodecyl sulfate (SDS) was applied as surfactant. When the concentration of SDS was 0.055 mM, very uniform sphere-like AgI nanoparticles with grain size of about 2530 nm were obtained. These results indicated that the high concentration of SDS could prevent the aggregation between colloidal nanoparticles due to its steric hindrance effect.

  13. Surface-enhanced raman spectroscopy substrate for arsenic sensing in groundwater

    DOE Patents [OSTI]

    Yang, Peidong; Mulvihill, Martin; Tao, Andrea R.; Sinsermsuksakul, Prasert; Arnold, John

    2015-06-16

    A surface-enhanced Raman spectroscopy (SERS) substrate formed from a plurality of monolayers of polyhedral silver nanocrystals, wherein at least one of the monolayers has polyvinypyrrolidone (PVP) on its surface, and thereby configured for sensing arsenic is described. Highly active SERS substrates are formed by assembling high density monolayers of differently shaped silver nanocrystals onto a solid support. SERS detection is performed directly on this substrate by placing a droplet of the analyte solution onto the nanocrystal monolayer. Adsorbed polymer, polyvinypyrrolidone (PVP), on the surface of the nanoparticles facilitates the binding of both arsenate and arsenite near the silver surface, allowing for highly accurate and sensitive detection capabilities.

  14. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Woods, Robert W. (New Kensington, PA)

    1998-01-01

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  15. Surface plasmon-enhanced photovoltaic device

    DOE Patents [OSTI]

    Kostecki, Robert; Mao, Samuel

    2014-10-07

    Photovoltaic devices are driven by intense photoemission of "hot" electrons from a suitable nanostructured metal. The metal should be an electron source with surface plasmon resonance within the visible and near-visible spectrum range (near IR to near UV (about 300 to 1000 nm)). Suitable metals include silver, gold, copper and alloys of silver, gold and copper with each other. Silver is particularly preferred for its advantageous opto-electronic properties in the near UV and visible spectrum range, relatively low cost, and simplicity of processing.

  16. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  17. Fort Collins- Green Building Requirement for City-Owned Buildings

    Broader source: Energy.gov [DOE]

    To control the construction and design costs associated with new buildings meeting this standard, the goal of Gold can be reduced to Silver for projects where the payback period for earning Gold...

  18. EDG Fuels | Open Energy Information

    Open Energy Info (EERE)

    search Name: EDG Fuels Place: Silver City, Arizona Zip: 88062 Product: Arizona-based biodiesel producer. References: EDG Fuels1 This article is a stub. You can help OpenEI...

  19. CX-005261: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Silver Creek Substation Fiber ProjectCX(s) Applied: B4.7Date: 02/15/2011Location(s): Lewis County, WashingtonOffice(s): Bonneville Power Administration

  20. EERE Success Story-California: TetraCell Silicon Solar Cell Improves...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This innovative PV technology reduces costs with a simplified process that replaces silver-a high-cost commodity used in traditional screen printed solar cells-with copper, which ...

  1. City of Dallas- Green Building Policy for Municipal Buildings

    Broader source: Energy.gov [DOE]

    The first building completed under this policy was the Jack Evans Police Headquarters, which obtained LEED Silver certification in December 2005. As of 2015, Dallas has 26 LEED certified...

  2. Seventy-three New Mexico students receive Los Alamos Employees...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    annual, four-year silver scholarships: Sarah Colvin of the New Mexico School for the Arts, Jesse Yelvington of Pojoaque High School and Na Hyun Park of St. Michael's High School...

  3. NNSA Administrator Recognizes Los Alamos Employees for Exceptional...

    National Nuclear Security Administration (NNSA)

    team leader Ward Hawkins (second from left) with the NNSA Silver Medal, and team members Richard Kelley, left, and Aviva Sussman, second from right with the NNSA Excellence Medal....

  4. Integrated Field Exercise

    National Nuclear Security Administration (NNSA)

    team leader Ward Hawkins (second from left) with the NNSA Silver Medal, and team members Richard Kelley, left, and Aviva Sussman, second from right with the NNSA Excellence Medal....

  5. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    sole use of state entities achieve US Green Building Council LEED Silver rating, a two-globe rating on the Green Building Initiative Green Globe rating system, or a comparable...

  6. High Performance Building Standards in New State Construction...

    Broader source: Energy.gov (indexed) [DOE]

    sole use of state entities achieve US Green Building Council LEED Silver rating, a two-globe rating on the Green Building Initiative Green Globe rating system, or a comparable...

  7. Butte, Montana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    is a stub. You can help OpenEI by expanding it. Butte is a city in Silver Bow County, Montana. It falls under Montana's At-large congressional district.12 Registered Energy...

  8. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    additional height up to 3 stories for special exception site plan requests. The site plan proposal must guarantee a minimum level of energy savings and a LEED rating at the Silver,...

  9. Salt Lake City- High Performance Buildings Requirement

    Broader source: Energy.gov [DOE]

    Salt Lake City's mayor issued an executive order in July 2005 requiring that all public buildings owned and controlled by the city be built or renovated to meet the requirements of LEED "silver"...

  10. San Bernardino County- Green Building Requirement

    Broader source: Energy.gov [DOE]

    In August 2007, the San Bernardino County Board of Supervisors approved a policy requiring that all new county buildings and major renovations be built to LEED Silver standards. The decision was...

  11. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Deep Bed Adsorption Testing using Silver-Functionalized Aerogel","Nick Soelberg; Tony Watson","2012-06-01T04:00:00Z",1062194,"10.21721062194","INLEXT-12-26522","DE-AC07-05ID14517...

  12. EM Newsletters | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    tubes for recycling at the SRS Recycling Center. From Silver to Lead, SRS Turns Trash to Treasure AIKEN, S.C. - EM's contractor for the nuclear cleanup at the Savannah...

  13. Indian Energy News Archive | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nevada. Part of DOE's silver-level sponsorship of RES 2014, the forum will take place on March 17, 2014, from 9 a.m.-5:30 p.m. and will feature the following roundtable sessions:...

  14. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.

    2010-11-01

    The flux of atomic oxygen generated in a electron cyclotron resonance (ECR) microwave plasma source was quantified by two different methods. The commonly applied approach of monitoring the frequency change of a silver-coated quartz crystal microbalance (QCM) deposition rate monitor as the silver is oxidized was found to underestimate the atomic oxygen flux by an order of magnitude compared to a more direct deposition approach. In the mixed-phase Ag/Ag2O deposition method, silver films were deposited in the presence of the plasma such that the films were partially oxidized to Ag2O; x-ray photoelectron spectroscopy (XPS) was utilized for quantification of the oxidized fraction. The inaccuracy of the QCM oxidation method was tentatively attributed to efficient catalytic recombination of O atoms on the silver surface.

  15. Town of Chapel Hill- Energy Conservation Requirements for Town Buildings

    Broader source: Energy.gov [DOE]

    The Town of Chapel Hill’s energy-conservation ordinance requires all new or expanded buildings constructed by and for the town to achieve a Silver level certification in the U.S. Green Building...

  16. Customer Acquisition | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Soft Costs Customer Acquisition Customer Acquisition Photo of a woman, man, and child looking at a silver box on the outside of a home. Customer acquisition costs in the solar ...

  17. A Christmas letter from Leon Love

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    publish Leon's Christmas Letter. It gives insight into the isotope separation process in Building 9731 and also dates the final removal of the 67 tons of silver in the calutrons,...

  18. Department of Energy Issues Loan Guarantee Supported by Recovery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nevada Senator Harry Reid. "Secretary Chu has been to Nevada many times and I thank him for recognizing the Silver State as a leader in developing these clean energy resources." ...

  19. DOE Announces New Executive Director of Loan Guarantee Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... He has also served on numerous non-profit boards, including, for many years serving as Chairman of the board of American Forests. Silver is a graduate of Harvard University and did ...

  20. Geology of the Florida Canyon gold deposit, Pershing County,...

    Open Energy Info (EERE)

    Pershing County, Nevada, in: Gold and Silver Deposits of Western Nevada Authors Hastings, J.S., Burkhart, T.H., and Richardson and R.E. Published Geological Society of Nevada 1993...

  1. City of Philadelphia- Energy Standards for Public Buildings

    Broader source: Energy.gov [DOE]

    As part of this goal, Philadelphia enacted Bill Number 080025 in December 2009. The bill requires all new construction or major renovations to achieve LEED Silver certification if more than 50% o...

  2. Micromolding of a Highly Fluorescent Reticular Coordination Polymer: Solvent-Mediated Reconfigurable Polymerization in a Soft Lithographic Mold

    SciTech Connect (OSTI)

    Y You; H Yang; J Chung; J Kim; Y Jung; S Park

    2011-12-31

    Coordination polymerization of pyridine-based ligands and zinc or silver ions was controlled by soft lithographic micromolding in capillaries. The polymer patterns that are produced are highly fluorescent and supramolecularly structured.

  3. Underwater radiation detector

    DOE Patents [OSTI]

    Kruse, Lyle W. (Albuquerque, NM); McKnight, Richard P. (Albuquerque, NM)

    1986-01-01

    A detector apparatus for differentiating between gamma and neutron radiation is provided. The detector includes a pair of differentially shielded Geiger-Mueller tubes. The first tube is wrapped in silver foil and the second tube is wrapped in lead foil. Both the silver and lead foils allow the passage of gamma rays at a constant rate in a gamma ray only field. When neutrons are present, however, the silver activates and emits beta radiation that is also detected by the silver wrapped Geiger-Mueller tube while the radiation detected by the lead wrapped Geiger-Mueller tube remains constant. The amount of radiation impinging on the separate Geiger-Mueller tubes is then correlated in order to distinguish between the neutron and gamma radiations.

  4. Los Angeles County- LEED for County Buildings

    Broader source: Energy.gov [DOE]

    In January 2007, the Los Angeles County Board of Supervisors adopted rules to require that all new county buildings greater than 10,000 square feet be LEED Silver certified. All buildings...

  5. CX-010233: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Cleanable and Hardcoat Coatings for Increased Durability of Silvered Polymeric Mirrors CX(s) Applied: A9, B5.15, B5.17 Date: 02/07/2013 Location(s): Minnesota Offices(s): Golden Field Office

  6. NanoMas Technologies Inc | Open Energy Information

    Open Energy Info (EERE)

    Product: NanoMas develops silver nanoparticle-based dyes which can be used in printable solar cells and other printable electronics. References: NanoMas Technologies Inc.1 This...

  7. Iodine Sorbent Performance in FY 2012 Deep Bed Tests (Technical...

    Office of Scientific and Technical Information (OSTI)

    0.01%, for the silver-functionalized Aerogel. less Authors: Nick Soelberg ; Tony Watson Publication Date: 2012-08-01 OSTI Identifier: 1056019 Report Number(s): INL...

  8. Picasolar

    Broader source: Energy.gov [DOE]

    Picasolar wholly owns the hydrogen selective emitter (HSE) technology. HSE can increase the efficiency of solar cells by up to 15 percent and remove up to 33 percent of the silver grid lines in a conventional silicon solar cell.

  9. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    must guarantee a minimum level of energy savings and a LEED rating at the Silver, Gold or Platinum level, for the bonus to be approved. An additional 0.10 FAR may be awarded...

  10. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    29, 2009- Very tiny wires, called nanowires, made from such metals as silver and gold, may play a crucial role as electrical or mechanical switches in the development of...

  11. Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining...

    Open Energy Info (EERE)

    Banded, epithermal quartz-adularia veins have produced about 1.5 million ounces of gold and 7 million ounces of silver from the Bodie mining district, eastern California. The...

  12. Temporal Relations of Volcanism and Hydrothermal Systems in Two...

    Open Energy Info (EERE)

    and oxygen-isotope data provide strong evidence that the epithermal quartz-vein-hosted gold-silver mineralization at Cochiti and the sub-ore grade molybdenite at VC-2A were...

  13. Our Hidden Past: Precious Metals | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4:24 min. Y-12's calutrons required electrical conductor material, but during the war, copper was in short supply. The U.S. Treasury loaned Y-12 14,700 tons of silver, valued at...

  14. Thermodynamic aspects of dehydrogenation reactions on noble metal surfaces

    SciTech Connect (OSTI)

    Svane, K. L. Hammer, B.

    2014-11-07

    The reaction free energy for dehydrogenation of phenol, aniline, thiophenol, benzoic acid, and 1,4-benzenediol on the close packed copper, silver, and gold surfaces has been studied by density functional theory calculations. Dehydrogenation of thiophenol is found to be favourable on all three surfaces while aniline does not dehydrogenate on any of them. For phenol, benzenediol and benzoic acid dehydrogenation is favourable on copper and silver only, following the general trend of an increasing reaction free energy when going form gold to silver to copper. This trend can be correlated with the changes in bond lengths within the molecule upon dehydrogenation. While copper is able to replace hydrogen, leaving small changes in the bond lengths of the aromatic ring, the metal-molecule bond is weaker for silver and gold, resulting in a partial loss of aromaticity. This difference in bond strength leads to pronounced differences in adsorption geometries upon multiple dehydrogenations.

  15. FORM EIA-28

    U.S. Energy Information Administration (EIA) Indexed Site

    ... By that definition, these resources include, but are not limited to: (1) crude oil and natural gas; (2) metals, such as copper, gold, iron, nickel, platinum, silver, tin, titanium, ...

  16. ITP Mining: Energy and Environmental Profile of the U.S. Mining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Chapter 5 - Copper PDF icon Chapter 6 - Lead and Zinc PDF icon Chapter 7 - Gold and Silver PDF icon Chapter 8 - Phosphate PDF icon Chapter 9 - Limestone and Crushed ...

  17. Low-Interest Rates Entice Philadelphians to Reach for the Stars...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    For example, "Gold Star" projects, which are guided by an energy assessment and consist of ... As an alternative to the Gold Star level, the Silver Star allows homeowners to initiate ...

  18. CX-003638: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Silver (Ag) Extraction of SedimentsCX(s) Applied: B3.6Date: 07/30/2010Location(s): Aiken, South CarolinaOffice(s): Savannah River Operations Office

  19. Westinghouse Earns Mine Safety Award for 16th Consecutive Year

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    was recently awarded the "Mine Operator of the Year Award" at the annual New Mexico Mining Association Convention held in Silver City, N.M. WTS, the management and operating...

  20. NREL: Learning - Fuel Cell Vehicle Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    showing a silver four-door sedan being driven on a roadway and containing the words "hydrogen fuel cell electric" across the front and rear doors. This prototype hydrogen fuel...

  1. 2013 SPR Report to Congress | Department of Energy

    Energy Savers [EERE]

    at Big Hill and 611,000 barrels of ullage was created in sour caverns at West Hackberry. Environment, Safety, and Health The Strategic Petroleum Reserve received the DOE Silver...

  2. CX-000496: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    F Area Hazardous Waste Management Facility Silver Chloride Solution Injection WellsCX(s) Applied: B6.2Date: 06/15/2009Location(s): Aiken, South CarolinaOffice(s): Environmental Management, Savannah River Operations Office

  3. CX-000493: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    H-Area Hazardous Waste Management Facility Base and Silver Chloride InjectionCX(s) Applied: B6.1Date: 05/28/2009Location(s): Aiken, South CarolinaOffice(s): Environmental Management, Savannah River Operations Office

  4. Los Alamos Employees' Scholarship

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    silver scholarships: Kathy Lin of Los Alamos High School, Ian McMahon of Monte del Sol in Santa Fe, and Dennis Trujillo of McCurdy School in Espaola. And two students are...

  5. Superconductor Composite

    DOE Patents [OSTI]

    Dorris, Stephen E. (La Grange Park, IL); Burlone, Dominick A. (Asheville, NC); Morgan; Carol W. (Asheville, NC)

    1999-02-02

    A superconducting conductor fabricated from a plurality of wires, e.g., fine silver wires, coated with a superconducting powder. A process of applying superconducting powders to such wires, to the resulting coated wires and superconductors produced therefrom.

  6. High Performance Green Schools Planning Grants

    Broader source: Energy.gov [DOE]

    In addition to planning grant opportunities, the Department of Education offers an additional reimbursement to schools that build or renovate to LEED silver or higher, or achieve two or more...

  7. Buildings Energy Data Book [EERE]

    3 LEED for Core and Shell, by Version v2.0 v2009 Total Platinum 34 1 35 Gold 326 5 331 Silver 224 10 234 Certified 61 6 67 Total 645 22 667

  8. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    silver-based mineral that was discovered in 2005 about 180 miles southeast of Lima, Peru, by William Pinch and characterized by a University of Arizona mineralogy team led by...

  9. Catalysts to reduce NO.sub.x in an exhaust gas stream and methods of preparation

    DOE Patents [OSTI]

    Castellano, Christopher R. (Ringoes, NJ); Moini, Ahmad (Princeton, NJ); Koermer, Gerald S. (Basking Ridge, NJ); Furbeck, Howard (Hamilton, NJ); Schmieg, Steven J. (Troy, MI); Blint, Richard J. (Shelby Township, MI)

    2011-05-17

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having a catalyst comprising silver and a platinum group metal on a particulate alumina support, the atomic fraction of the platinum group metal being less than or equal to about 0.25. Methods of manufacturing catalysts are described in which silver is impregnated on alumina particles.

  10. For your calendar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For your calendar Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue:Mar. 2016 all issues All Issues » submit For your calendar Native American Economic Summit; LAESF application deadline for two-year scholarships; and more May 1, 2015 Los Alamos Employees' Scholarship Fund's 2015 Silver Scholar Mahalia Bohsali. The next application deadline for LAESF's two-year scholarships is June 15. Los Alamos Employees' Scholarship Fund's 2015 Silver

  11. All-of-the-Above, In Action | Department of Energy

    Energy Savers [EERE]

    Above, In Action All-of-the-Above, In Action May 10, 2012 - 1:53pm Addthis Secretary of the Interior Ken Salazar speaks with First Solar and Enbridge leadership at the Enbridge Silver State North solar project in Nevada. | Photo courtesy of Interior Department, credit Tami A. Heilemann. Secretary of the Interior Ken Salazar speaks with First Solar and Enbridge leadership at the Enbridge Silver State North solar project in Nevada. | Photo courtesy of Interior Department, credit Tami A. Heilemann.

  12. An Update on the Department's Loan Programs | Department of Energy

    Energy Savers [EERE]

    the Department's Loan Programs An Update on the Department's Loan Programs May 10, 2011 - 2:30pm Addthis Jonathan Silver Jonathan Silver Executive Director of the Loan Programs Office What are the key facts? The Department has issued loans, loan guarantees, and conditional commitments for loan guarantees to 28 clean energy projects. Project sponsors estimate these projects will create or save over 61,000 jobs, including construction and operating jobs. Section 1705 loan guarantees from the

  13. Passive Groundwater Cleanup Measures Save Savannah River Site Millions of

    Energy Savers [EERE]

    Dollars | Department of Energy Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars November 25, 2015 - 12:20pm Addthis SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. AIKEN, S.C. - The EM program

  14. Diamond Green Diesel: Diversifying Our Transportation Fuel Supply |

    Office of Environmental Management (EM)

    Department of Energy Diamond Green Diesel: Diversifying Our Transportation Fuel Supply Diamond Green Diesel: Diversifying Our Transportation Fuel Supply January 20, 2011 - 3:48pm Addthis Jonathan Silver Jonathan Silver Executive Director of the Loan Programs Office What does this project do? Nearly triples the amount of renewable diesel produced domestically Diversifies the U.S. fuel supply Today, Secretary Chu announced the offer of a conditional commitment for a $241 million loan guarantee

  15. Effect of sulfur isotopic composition of zinc and lead sulfides on the E. M. F. of electrochemical cells

    SciTech Connect (OSTI)

    Lusk, J.; Krouse, H.R.; Batts, B.D.

    1988-03-01

    A new effect is reported in which unexpectedly large voltages are produced by electrochemical cells containing sulfides at natural isotopic abundance levels. Room temperature experiments were undertaken to determine whether electrochemical cells employing silver bromide and silver beta alumina as solid electrolytes would be sufficiently sensitive to detect small variations in sulfur isotopic composition for zinc and lead sulfides. Voltages obtained for silver bromide cells tended to increase progressively over at least 20 days, and increased in a regular fashion with increasing differences in isotopic composition between charges. Voltages exceeding 150 mV were obtained for /sup delta/S/sup 3,4/ differences up to 85 per mil for zinc sulfide, but reached only about 20 mV for lead sulfide. Silver beta alumina cells with opposing zinc and lead sulfide charges yielded larger voltages and E.M.F. minimum corresponding to a +8(/plus minus/2) per mil difference. This value shows reasonable agreement with interpolated 20/degrees/C equilibrium values of between +7.5 to +9.8 obtained from the literature. Matured silver bromide cells with opposed zinc and lead sulfide charges behaved similarly but yielded lower voltages. Silver concentration cells of the opposed type are thus able to detect isotopic equilibrium and this will permit calibration of sulfur isotope thermometers down to unexpectedly low temperatures.

  16. Method for treating a nuclear process off-gas stream

    DOE Patents [OSTI]

    Pence, Dallas T.; Chou, Chun-Chao

    1984-01-01

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

  17. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, R.D.; Roe, L.H.; Migliori, A.

    1995-11-14

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements. 12 figs.

  18. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Roe, Lawrence H. (Los Alamos, NM); Migliori, Albert (Santa Fe, NM)

    1995-01-01

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements.

  19. Compact cladding-pumped planar waveguide amplifier and fabrication method

    DOE Patents [OSTI]

    Bayramian, Andy J.; Beach, Raymond J.; Honea, Eric; Murray, James E.; Payne, Stephen A.

    2003-10-28

    A low-cost, high performance cladding-pumped planar waveguide amplifier and fabrication method, for deployment in metro and access networks. The waveguide amplifier has a compact monolithic slab architecture preferably formed by first sandwich bonding an erbium-doped core glass slab between two cladding glass slabs to form a multi-layer planar construction, and then slicing the construction into multiple unit constructions. Using lithographic techniques, a silver stripe is deposited and formed at a top or bottom surface of each unit construction and over a cross section of the bonds. By heating the unit construction in an oven and applying an electric field, the silver stripe is then ion diffused to increase the refractive indices of the core and cladding regions, with the diffusion region of the core forming a single mode waveguide, and the silver diffusion cladding region forming a second larger waveguide amenable to cladding pumping with broad area diodes.

  20. NREL: Technology Deployment - Climate Neutral Research Campuses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate Neutral Research Campuses Technology Deployment Four photos in a row across the top of the page. The first photo shows the profile of a wind turbine at dusk; the second of two women in white laboratory coats and glasses observing a piece of equipment; the third of a blue car moving downhill with a red rock in the background; the fourth of a walkway to a sandstone building that has a silver tower in the front and a silver walkway into the second story. Climate Neutral Research Campuses

  1. Surface-Plasmon Enhanced Transparent Electrodes in Organic Photovoltaics

    SciTech Connect (OSTI)

    Reilly III, T. H.; van de Lagemaat, J.; Tenent, R. C.; Morfa, A. J.; Rowlen, K. L.

    2008-01-01

    Random silver nanohole films were created through colloidal lithography techniques and metal vapor deposition. The transparent electrodes were characterized by uv-visible spectroscopy and incorporated into an organic solar cell. The test cells were evaluated for solar power-conversion efficiency and incident photon-to-current conversion efficiency. The incident photon-to-current conversion efficiency spectra displayed evidence that a nanohole film with 92 nm diameter holes induces surface-plasmon-enhanced photoconversion. The nanohole silver films demonstrate a promising route to removing the indium tin oxide transparent electrode that is ubiquitous in organic optoelectronics.

  2. DRAFT EESA LOBBYING DISCLOSURE AND CERTIFICATION FORM

    Broader source: Energy.gov (indexed) [DOE]

    21/2011 1:15 PM EST Jonathan Silver Executive Director Loan Programs U.S. Department of Energy Jonathan Silver gave the group a broad overview of the work done by the LPO, and discussed the possible future of clean energy investment. Name of the Employee(s) who prepared this form: Ann Shikany Date: 8/23/2011 Registered Lobbyist(s) Name: Colleen Quinn Title: Vice President of Government Relations and Public Policy Firm or Organization, if applicable: Silicon Valley Leadership Group Client:

  3. Clamshell microwave cavities having a superconductive coating

    DOE Patents [OSTI]

    Cooke, D. Wayne (Los Alamos, NM); Arendt, Paul N. (Los Alamos, NM); Piel, Helmut (Wuppertal, DE)

    1994-01-01

    A microwave cavity including a pair of opposing clamshell halves, such halves comprised of a metal selected from the group consisting of silver, copper, or a silver-based alloy, wherein the cavity is further characterized as exhibiting a dominant TE.sub.011 mode is provided together with an embodiment wherein the interior concave surfaces of the clamshell halves are coated with a superconductive material. In the case of copper clamshell halves, the microwave cavity has a Q-value of about 1.2.times.10.sup.5 as measured at a temperature of 10K and a frequency of 10 GHz.

  4. Comparison of the National Green Building Standard (ICC 700-2008) and LEED for Homes to the Residential Provisions of the 2009 IECC for the Delaware Green for Green Program

    SciTech Connect (OSTI)

    Britt, Michelle L.; Makela, Eric J.

    2011-01-30

    Adhering to Delawares Green for Green program specifications results in homes being built to more energy-efficient levels than the 2009 IECC levels. Specifically: Certifying at the Silver Performance Level for the ICC 700 standard using either the Prescriptive or Performance Paths will result in a residential building that is more efficient than if the building only complied with the 2009 IECC. Certifying at the Silver level under LEED for Homes standard, including mandatory compliance with ENERGY STAR 2006 and earning two additional energy points will result in a residential building that is more efficient than if the building only complied with the 2009 IECC.

  5. Closed end regeneration method

    DOE Patents [OSTI]

    Yang, Arthur Jing-Min; Zhang, Yuehua

    2006-06-27

    A nanoporous reactive adsorbent incorporates a relatively small number of relatively larger reactant, e.g. metal, enzyme, etc. particles (10) forming a discontinuous or continuous phase interspersed among and surrounded by a continuous phase of smaller adsorbent particles (12) and connected interstitial pores (14) therebetween. The reactive adsorbent can effectively remove inorganic or organic impurities in a liquid by causing the liquid to flow through the adsorbent. For example, silver ions may be adsorbed by the adsorbent particles (12) and reduced to metallic silver by reducing metal, such as irons, as the reactant particles (10). The column can be regenerated by backwashing with the liquid effluent containing, for example, acetic acid.

  6. Nanopore reactive adsorbents for the high-efficiency removal of waste species

    DOE Patents [OSTI]

    Yang, Arthur Jing-Min; Zhang, Yuehua

    2005-01-04

    A nanoporous reactive adsorbent incorporates a relatively small number of relatively larger reactant, e.g., metal, enzyme, etc., particles (10) forming a discontinuous or continuous phase interspersed among and surrounded by a continuous phase of smaller adsorbent particles (12) and connected interstitial pores (14) therebetween. The reactive adsorbent can effectively remove inorganic or organic impurities in a liquid by causing the liquid to flow through the adsorbent. For example, silver ions may be adsorbed by the adsorbent particles (12) and reduced to metallic silver by reducing metal, such as ions, as the reactant particles (10). The column can be regenerated by backwashing with the liquid effluent containing, for example, acetic acid.

  7. Final Report of the Mid-Atlantic Marine Wildlife Surveys, Modeling, and Data: Workshop to Establish Coordination & Communication: Appendix A, Workshop Agenda

    Energy Savers [EERE]

    A: Workshop Agenda July 2013 Appendix A: Workshop Agenda Mid-Atlantic Marine Wildlife Surveys, Modeling, and Data: Workshop to Establish Coordination & Communication Dates: July 24-25 Location: NOAA's Silver Spring headquarters: NOAA Science Center 1301 East-West Hwy, Silver Spring, MD 20910 July 24 - Science Center 8:00-8:30 - Arrival and check-in (please allow half an hour to go through security and sign- in) 8:30-8:45 - Welcome and Introductions 8:45-9:00 - Meeting Scope and Objectives

  8. Phase transformations during the Ag-In plating and bonding of vertical diode elements of multijunction solar cells

    SciTech Connect (OSTI)

    Klochko, N. P. Khrypunov, G. S.; Volkova, N. D.; Kopach, V. R.; Lyubov, V. N.; Kirichenko, M. V.; Momotenko, A. V.; Kharchenko, N. M.; Nikitin, V. A.

    2013-06-15

    The conditions of the bonding of silicon multijunction solar cells with vertical p-n junctions using Ag-In solder are studied. The compositions of electrodeposited indium films on silicon wafers silver plated by screen printing and silver and indium films fabricated by layer-by-layer electrochemical deposition onto the surface of silicon vertical diode cells silver plated in vacuum are studied. Studying the electrochemical-deposition conditions, structure, and surface morphology of the grown layers showed that guaranteed bonding is provided by 8-min heat treatment at 400 Degree-Sign C under the pressure of a stack of metallized silicon wafers; however, the ratio of the indium and silver layer thicknesses should not exceed 1: 3. As this condition is satisfied, the solder after wafer bonding has the InAg{sub 3} structure (or InAg{sub 3} with an Ag phase admixture), due to which the junction melting point exceeds 700 Degree-Sign C, which guarantees the functioning of such solar cells under concentrated illumination.

  9. Metal/ceramic composites with high hydrogen permeability

    DOE Patents [OSTI]

    Dorris, Stephen E.; Lee, Tae H.; Balachandran, Uthamalingam

    2003-05-27

    A membrane for separating hydrogen from fluids is provided comprising a sintered homogenous mixture of a ceramic composition and a metal. The metal may be palladium, niobium, tantalum, vanadium, or zirconium or a binary mixture of palladium with another metal such as niobium, silver, tantalum, vanadium, or zirconium.

  10. Thin film solar energy collector

    SciTech Connect (OSTI)

    Farrauto, R.J.; Myers, H.; Williams, J.C.

    1982-03-23

    A solar energy collector has improved absorptance and emissivity levels comprising: (1) a silver-copper oxide-rhodium oxide solar absorption film, (2) a cerium oxide interlayer and a substrate of quartz, silica glass or metal. The cerium oxide interlayer minimizes agglomeration of the metal particles, maintains a relatively low thermal emittance and improves overall stability.

  11. Breakthrough: Lead-free Solder

    ScienceCinema (OSTI)

    Anderson, Iver

    2013-03-01

    Ames Laboratory senior metallurgist Iver Anderson explains the importance of lead-free solder in taking hazardous lead out of the environment by eliminating it from discarded computers and electronics that wind up in landfills. Anderson led a team that developed a tin-silver-copper replacement for traditional lead-tin solder that has been adopted by more than 50 companies worldwide.

  12. Summary of FY 2010 Iodine Capture Studies at the INL

    SciTech Connect (OSTI)

    Daryl R. Haefner; Tony L. Watson; Michael G. Jones

    2010-08-01

    Three breakthrough runs using silver mordenite sorbents were conducted and a dynamic sorption capacity estimated based on MeI analysis from a 2" bed. However, it is now believed the data for the first 2 runs is incomplete because the contributions from elemental iodine were not included. Although the only source of iodine was MeI, elemental iodine was generated within the sorbent bed, presumably from a recombination reaction likely catalyzed by silver mordenite. On-line effluent analysis with a GC was only capable of analyzing MeI, not I2. Scrub samples drawn during Run #3, which are specific for I2, show significant levels of I2 being emitted from a partially spent Ag-mordenite bed. By combining MeI and I2 analyses, a well defined total iodine breakthrough curve can be generated for Run #3. At the conclusion of Run #3 (IONEX Ag-900 was the sorbent) the effluent level from Bed 2 was approaching 70% of the feed concentration. The leading bed (Bed 1) had an estimated average loading of 66 mg I/g sorbent, Bed 2's was 52 mg I/g. The corresponding silver utilizations (assuming formation of AgI) were about 59% and 46%, respectively. The spent sorbents are being sent to Sandia National Laboratories for confirmatory analysis of iodine and silver utilization as well as source material for waste form development.

  13. Dosimeter and method for using the same

    DOE Patents [OSTI]

    Warner, Benjamin P. (Los Alamos, NM); Johns, Deidre M. (Boulder, CO)

    2003-06-24

    A very sensitive dosimeter that detects ionizing radiation is described. The dosimeter includes a breakable sealed container. A solution of a reducing agent is inside the container. The dosimeter has an air-tight dosimeter body with a transparent portion and an opaque portion. The transparent portion includes a transparent chamber that holds the breakable container with the reducing agent. The opaque portion includes an opaque chamber that holds an emulsion of silver salt (AgX) selected from silver chloride, silver bromide, silver iodide, and combinations of them. A passageway in the dosimeter provides fluid communication between the transparent chamber and the opaque chamber. The dosimeter may also include a chemical pH indicator in the breakable container that provides a detectable color change to the solution for a pH of about 3-10. The invention also includes a method of detecting ionizing radiation that involves producing the dosimeter, breaking the breakable container, allowing the solution to flow through the passageway and contact the emulsion, detecting any color change in the solution and using the color change to determine a radiation dosage.

  14. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    DeVoto, Douglas

    2015-06-10

    This is a technical review of the DOE VTO EDT project EDT063, Performance and Reliability of Bonded Interfaces for High-Temperature Packaging. A procedure for analyzing the reliability of sintered-silver through experimental thermal cycling and crack propagation modeling has been outlined and results have been presented.

  15. Mirror Film Company Has 'Concentrated' Plans for Expansion

    Broader source: Energy.gov [DOE]

    ReflecTech Inc. is using a silvered polymer-based film -- instead of glass -- to make mirror panels for focusing sunlight onto a heat generator. Their innovation helped them land a Recovery Act tax credit to expand their Colorado company.

  16. Alternative Fuels Market and Policy Trends (Presentation)

    SciTech Connect (OSTI)

    Schroeder, A. N.

    2013-09-01

    Market forces and policies are increasing opportunities for alternative fuels. There is no one-size-fits-all, catch-all, silver-bullet fuel. States play a critical role in the alternative fuel market and are taking a leading role.

  17. Milestone Report - M4FT-14OR0312022 - Co-absorption studies - Design system complete/test plan complete

    SciTech Connect (OSTI)

    Bruffey, Stephanie H.; Spencer, Barry B.; Jubin, Robert Thomas

    2013-12-01

    The objective of this test plan is to describe research that will determine the effectiveness of silver mordenite and molecular sieve beds to remove iodine and water (tritium) from off-gas streams arising from used nuclear fuel recycling processes, and to demonstrate that the iodine and water can be recovered separately from one another.

  18. Parasitic corrosion resistant anode for use in metal/air or metal/O.sub.2 cells

    DOE Patents [OSTI]

    Joy, Richard W.; Smith, David F.

    1983-01-01

    A consumable metal anode which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

  19. Parasitic corrosion-resistant anode for use in metal/air or metal/O/sub 2/ cells

    DOE Patents [OSTI]

    Joy, R.W.; Smith, D.F.

    1982-09-20

    A consumable metal anode is described which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

  20. Reduced temperature aluminum production in an electrolytic cell having an inert anode

    DOE Patents [OSTI]

    Dawless, Robert K. (Monroeville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA); Kozarek, Robert L. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

    2000-01-01

    Aluminum is produced by electrolytic reduction of alumina in a cell having a cathode, an inert anode and a molten salt bath containing metal fluorides and alumina. The inert anode preferably contains copper, silver and oxides of iron and nickel. Reducing the molten salt bath temperature to about 900-950.degree. C. lowers corrosion on the inert anode constituents.

  1. CX-100103: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Silver-free Metallization Technology for Producing High Efficiency, Industrial Silicon Solar Cells Award Number: DE-EE0006814 CX(s) Applied: A9, B3.6 Date: 10/16/2014 Location(s): Rhode Island Office(s): Golden Field Office

  2. Photocatalytic probing of DNA sequence by using TiO{sub 2}/dopamine-DNA triads.

    SciTech Connect (OSTI)

    Liu, J.; de la Garza, L.; Zhang, L.; Dimitrijevic, N. M.; Zuo, X.; Tiede, D. M.; Rajh, T.

    2007-10-15

    A method to control charge transfer reaction in DNA using hybrid nanometer-sized TiO{sub 2} nanoparticles was developed. In this system extended charge separation reflects the sequence of DNA and was measured using metallic silver deposition or by photocurrent response. Light-induced extended charge separation in these systems was found to be dependent on the DNA-bridge length and sequence. The yield of photocatalytic deposition of silver was studied in systems having GG accepting sites imbedded in AT runs at varying distances from the TiO{sub 2} nanoparticle surface. Weak distance dependence of charge separation indicative of a hole hopping through mediating adenine (A) sites was found. The quantum yield of silver deposition in the system having a GG accepting site placed 8.5 {angstrom} from the nanoparticle surface was found to be {Phi} = 0.70 (70%) and {Phi} = 0.56 (56%) for (A){sub n} and (AT){sub n/2} bridge, respectively. Hole injection to GG trapping sites as far as 70 {angstrom} from a nanoparticle surface in the absence of G hopping sites was measured. Introduction of G hopping sites increased the efficiency of hole injection. The efficiency of photocatalytic deposition of metallic silver was found to be sensitive to the presence of a single nucleobase mismatch in the DNA sequence.

  3. CX-008581: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Advance Manufacture of Second-surface, Silvered Glass Reflectors for High Performance, Low-cost Concentrated Solar Power Collector Systems CX(s) Applied: B3.6 Date: 07/25/2012 Location(s): Arizona Offices(s): Golden Field Office

  4. CX-006406: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Silver Chloride Injection at the F Area Hazardous Waste Management Facilities Barrier WallCX(s) Applied: B6.9Date: 05/13/2011Location(s): Aiken, South CarolinaOffice(s): Environmental Management, Savannah River Operations Office

  5. Lobbyist Disclosure Form - First Solar | Department of Energy

    Office of Environmental Management (EM)

    First Solar Lobbyist Disclosure Form - First Solar Susan Richardson, Energy Department loan programs chief counsel; Douglas Schultz, Energy Department senior investment officer; Andrzej Potasinski, Energy Department senior investment officer; Nancy Donovan, Energy Department general counsel; and Jonathan Silver, Energy Department loans program executive director, discussed the status of the First Solar Topaz Project with Kathleen Weiss, First Solar government relations vice president. PDF icon

  6. Apparatus for measurement of critical current in superconductive tapes

    DOE Patents [OSTI]

    Coulter, J. Yates (Santa Fe, NM); DePaula, Raymond (Santa Fe, NM)

    2002-01-01

    A cryogenic linear positioner which is primarily used for characterizing coated conductor critical current homogeneity at 75K is disclosed. Additionally, this tool can be used to measure the positional dependence of the coated conductor resistance at room temperature, and the room temperature resistance of the underlying YBCB coating without the overlaying protective cover of silver.

  7. Probe and method for DNA detection

    DOE Patents [OSTI]

    Yeh, Hsin-Chih; Werner, James Henry; Sharma, Jaswinder Kumar; Martinez, Jennifer Suzanne

    2013-07-02

    A hybridization probe containing two linear strands of DNA lights up upon hybridization to a target DNA using silver nanoclusters that have been templated onto one of the DNA strands. Hybridization induces proximity between the nanoclusters on one strand and an overhang on the other strand, which results in enhanced fluorescence emission from the nanoclusters.

  8. CX-001237: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Silver Peak Innovative Exploration ProjectCX(s) Applied: A9, B3.1, B5.1Date: 03/15/2010Location(s): Esmerelda County, Reno, NevadaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  9. Buildings Energy Data Book: 9.2 LEED

    Buildings Energy Data Book [EERE]

    3 LEED for Core and Shell, by Version v2.0 v2009 Total Platinum 34 1 35 Gold 326 5 331 Silver 224 10 234 Certified 61 6 67 Total 645 22 667 Note(s): Source(s):

  10. Buildings Energy Data Book: 9.2 LEED

    Buildings Energy Data Book [EERE]

    4 LEED for Commercial Interiors, by Version v2.0 v2009 Total Platinum 88 46 0 134 Gold 617 207 1 825 Silver 524 186 3 713 Certified 308 78 2 388 Total 1,537 517 6 2,060 Note(s): Source(s): Retail v2009

  11. Buildings Energy Data Book: 9.2 LEED

    Buildings Energy Data Book [EERE]

    6 LEED for Schools, by Version v2.0 v2009 Total Platinum 14 1 15 Gold 103 8 111 Silver 78 5 83 Certified 39 3 42 Total 234 17 251 Note(s): Source(s): Includes only buildings in the United States. Pilots

  12. Buildings Energy Data Book [EERE]

    4 LEED for Commercial Interiors, by Version v2.0 v2009 Retail v2009 Total Platinum 88 46 0 134 Gold 617 207 1 825 Silver 524 186 3 713 Certified 308 78 2 388 Total 1,537 517 6 2,060

  13. Buildings Energy Data Book [EERE]

    6 LEED for Schools, by Version v2.0 v2009 Total Platinum 14 1 15 Gold 103 8 111 Silver 78 5 83 Certified 39 3 42 Total 234 17 251 Note(s): Includes only buildings in the United States

  14. Mechanical stabilization of BSCCO-2223 superconducting tapes

    SciTech Connect (OSTI)

    King, C.G.; Grey, D.A.; Mantone, A.

    1996-12-31

    A system to provide mechanical stabilization to high temperature BSCCO-2223 superconducting tape by laminating 0.081 mm thick, spring hard, copper foil to both sides with lead-tin eutectic solder has been successfully optimized. This system has been applied as a method to create a strong, windable composite from pure silver BSCCO tapes with a minimum of critical current (I{sub c}) degradation. The {open_quotes}as received{close_quotes} conductor is evaluated for physical consistency of width and thickness over the 3000 meters that were later strengthened, insulated and wound into a demonstration coil. Electrical degradation in the strengthened tape as a result of lamination was found to average 24 percent with a range from 4 to 51 percent. This was less than the degradation that would have occurred in an unstrengthened tape during subsequent insulation and coil winding processes. Additional work was performed to evaluate the mechanical properties of the strengthened tapes. The copper can double the ultimate tensile strength of the pure silver tapes. Additionally, pure silver and dispersion strengthened silver matrix tapes are laminated with 0.025 mm thick copper and 304 stainless steel foil to investigate minimization of the cross sectional area of the strengthening component. The stainless steel can increase the UTS of the pure silver tapes sixfold. Metallography is used to examine the laminate and the conductor. Mechanical properties and critical currents of these tapes are also reported both before and after strengthening. The I{sub c} is also measured as a function of strain on the laminated tapes.

  15. Associations of Pd, U and Ag in the SiC layer of neutron-irradiated TRISO fuel

    SciTech Connect (OSTI)

    Lillo, Thomas; Rooyen, Isabella Van

    2015-05-01

    Knowledge of the associations and composition of fission products in the neutron irradiated SiC layer of high-temperature gas reactor TRISO fuel is important to the understanding of various aspects of fuel performance that presently are not well understood. Recently, advanced characterization techniques have been used to examine fuel particles from the Idaho National Laboratorys AGR-1 experiment. Nano-sized Ag and Pd precipitates were previously identified in grain boundaries and triple points in the SiC layer of irradiated TRISO nuclear fuel. Continuation of this initial research is reported in this paper and consists of the characterization of a relatively large number of nano-sized precipitates in three areas of the SiC layer of a single irradiated TRISO nuclear fuel particle using standardless EDS analysis on focused ion beam-prepared transmission electron microscopy samples. Composition and distribution analyses of these precipitates, which were located on grain boundaries, triple junctions and intragranular precipitates, revealed low levels, generally <10 atomic %, of palladium, silver and/or uranium with palladium being the most common element found. Palladium by itself, or associated with either silver or uranium, was found throughout the SiC layer. A small number of precipitates on grain boundaries and triple junctions were found to contain only silver or silver in association with palladium while uranium was always associated with palladium but never found by itself or in association with silver. Intergranular precipitates containing uranium were found to have migrated ~23 ?m along a radial direction through the 35 ?m thick SiC coating during the AGR-1 experiment while silver-containing intergranular precipitates were found at depths up to ~24 ?m in the SiC layer. Also, Pd-rich, nano-precipitates (~10 nm in diameter), without evidence for the presence of either Ag or U, were revealed in intragranular regions throughout the SiC layer. Because not all grain boundaries and triple junctions contained precipitates with fission products and/or uranium, along with the differences in migration behavior between Pd, Ag and U, it was concluded that crystallographic grain boundary and triple junction parameters likely influence migration behavior.

  16. Electrode for a lithium cell

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Dees, Dennis W. (Downers Grove, IL)

    2008-10-14

    This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

  17. Solar cell array interconnects

    DOE Patents [OSTI]

    Carey, P.G.; Thompson, J.B.; Colella, N.J.; Williams, K.A.

    1995-11-14

    Electrical interconnects are disclosed for solar cells or other electronic components using a silver-silicone paste or a lead-tin (Pb-Sn) no-clean fluxless solder cream, whereby the high breakage of thin (<6 mil thick) solar cells using conventional solder interconnect is eliminated. The interconnects of this invention employs copper strips which are secured to the solar cells by a silver-silicone conductive paste which can be used at room temperature, or by a Pb-Sn solder cream which eliminates undesired residue on the active surfaces of the solar cells. Electrical testing using the interconnects of this invention has shown that no degradation of the interconnects developed under high current testing, while providing a very low contact resistance value. 4 figs.

  18. Distribution of Pd, Ag & U in the SiC Layer of an Irradiated TRISO Fuel Particle

    SciTech Connect (OSTI)

    Thomas M. Lillo; Isabella J. van Rooyen

    2014-08-01

    The distribution of silver, uranium and palladium in the silicon carbide (SiC) layer of an irradiated TRISO fuel particle was studied using samples extracted from the SiC layer using focused ion beam (FIB) techniques. Transmission electron microscopy in conjunction with energy dispersive x-ray spectroscopy was used to identify the presence of the specific elements of interest at grain boundaries, triple junctions and precipitates in the interior of SiC grains. Details on sample fabrication, errors associated with measurements of elemental migration distances and the distances migrated by silver, palladium and uranium in the SiC layer of an irradiated TRISO particle from the AGR-1 program are reported.

  19. Self Aligned Cell: Scaling Up Manufacture of a Cost Effective Cell Architecture for Multicrystalline Silicon Photovoltaics

    SciTech Connect (OSTI)

    Gabor, A.; van Mierlo, F.

    2010-12-01

    Two areas of technology for fabrication of higher efficiency Si-wafer solar cells were addressed: (1) the formation of structured texturing that is an improvement over the industry-standard isotexture process for multicrystalline wafers. (2) the formation of fine line (<50 micron) metallization seed layers in a self-aligned manner where the fingers can be automatically and perfectly lined up to a selective emitter and where expensive silver screen printing paste can be mostly replaced by plating up the seed layers with silver or copper. The benefits are: a) Lower reflectivity , b) Decoupling the performance of the texture from the saw damage, thus allowing for better advances in sawing and a more robust wet process. 1366 Technologies developed 2 pilot machines for 1) deposition and patterning of low-cost resist layers to enable simultaneous Honeycomb front texturing and groove formation for multicrystalline Si wafers, and 2) fine-line dispensing of materials that are self aligned to the grooves.

  20. Parametric Optimization of the MEO Process for Treatment of Mixed Waste Residues

    SciTech Connect (OSTI)

    Cournoyer, M.E.; Smith, W.H.

    1999-02-28

    A series of bench-scale experiments were conducted to determine the optimum reaction conditions for destruction of styrene-divinyl benzene based cation resin and methylene chloride by the mediated electrochemical oxidation (MEO) process. Reaction parameters examined include choice of electron transfer mediator, reaction temperature and solvent system. For the cation exchange resins, maximum destruction efficiencies were obtained using cerium (IV) as mediator in nitric acid at a temperature of 70 C. Reasonable efficiencies were also realized with silver(II) and cobalt (III) at ambient temperature in the same solvent. Use of sulfuric acid as the solvent yielded much lower efficiencies under equivalent conditions. Methylene chloride was found to react only with silver (II) at ambient temperature in nitric acid media, cobalt (III) and cerium (IV) were totally ineffective. These results demonstrate a need to perform bench-scale experiments to determine optimum operating conditions for each organic substrate targeted for treatment by the MEO process.

  1. High frequency reference electrode

    DOE Patents [OSTI]

    Kronberg, J.W.

    1994-05-31

    A high frequency reference electrode for electrochemical experiments comprises a mercury-calomel or silver-silver chloride reference electrode with a layer of platinum around it and a layer of a chemically and electrically resistant material such as TEFLON around the platinum covering all but a small ring or halo' at the tip of the reference electrode, adjacent to the active portion of the reference electrode. The voltage output of the platinum layer, which serves as a redox electrode, and that of the reference electrode are coupled by a capacitor or a set of capacitors and the coupled output transmitted to a standard laboratory potentiostat. The platinum may be applied by thermal decomposition to the surface of the reference electrode. The electrode provides superior high-frequency response over conventional electrodes. 4 figs.

  2. High frequency reference electrode

    DOE Patents [OSTI]

    Kronberg, James W.

    1994-01-01

    A high frequency reference electrode for electrochemical experiments comprises a mercury-calomel or silver-silver chloride reference electrode with a layer of platinum around it and a layer of a chemically and electrically resistant material such as TEFLON around the platinum covering all but a small ring or "halo" at the tip of the reference electrode, adjacent to the active portion of the reference electrode. The voltage output of the platinum layer, which serves as a redox electrode, and that of the reference electrode are coupled by a capacitor or a set of capacitors and the coupled output transmitted to a standard laboratory potentiostat. The platinum may be applied by thermal decomposition to the surface of the reference electrode. The electrode provides superior high-frequency response over conventional electrodes.

  3. Antimicrobial Polymer

    DOE Patents [OSTI]

    McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

    2004-09-28

    A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The polymeric composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from metals, metal alloys, metal salts, metal complexes and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one example embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl; and the metallic antimicrobial agent is selected from chelated silver ions, silver metal, chelated copper ions, copper metal, chelated zinc ions, zinc metal and mixtures thereof.

  4. Octahedral molecular sieve sorbents and catalysts

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2010-04-20

    Octahedral molecular sieve sorbents and catalysts are disclosed, including silver hollandite and cryptomelane. These materials can be used, for example, to catalyze the oxidation of CO.sub.x (e.g., CO), NO.sub.x (e.g., NO), hydrocarbons (e.g., C.sub.3H.sub.6) and/or sulfur-containing compounds. The disclosed materials also may be used to catalyze other reactions, such as the reduction of NO.sub.2. In some cases, the disclosed materials are capable of sorbing certain products from the reactions they catalyze. Silver hollandite, in particular, can be used to remove a substantial portion of certain sulfur-containing compounds from a gas or liquid by catalysis and/or sorption. The gas or liquid can be, for example, natural gas or a liquid hydrocarbon.

  5. Method and apparatus for forming high-critical-temperature superconducting layers on flat and/or elongated substrates

    DOE Patents [OSTI]

    Ciszek, Theodore F. (Evergreen, CO)

    1994-01-01

    An elongated, flexible superconductive wire or strip is fabricated by pulling it through and out of a melt of metal oxide material at a rate conducive to forming a crystalline coating of superconductive metal oxide material on an elongated, flexible substrate wire or strip. A coating of crystalline superconductive material, such as Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.8, is annealed to effect conductive contact between adjacent crystalline structures in the coating material, which is then cooled to room temperature. The container for the melt can accommodate continuous passage of the substrate through the melt. Also, a second pass-through container can be used to simultaneously anneal and overcoat the superconductive coating with a hot metallic material, such as silver or silver alloy. A hollow, elongated tube casting method of forming an elongated, flexible superconductive wire includes drawing the melt by differential pressure into a heated tubular substrate.

  6. Hybrid CFxAg2V4O11 as a high-energy, power density cathode for application in an underwater acoustic microtransmitter

    SciTech Connect (OSTI)

    Meduri, Praveen; Chen, Honghao; Chen, Xilin; Xiao, Jie; Gross, Mark E.; Carlson, Thomas J.; Zhang, Jiguang; Deng, Zhiqun

    2011-12-01

    This study demonstrates the excellent electrochemical performance of the hybrid carbon fluoride(CFx)/silver vanadium oxide(SVO)/graphene(G) cathode and its potential utilization in Acoustic Telemetry System Transmitter (ATST). The impedance increase issue caused by LiF formation from CFx is effectively addressed by the deposition of conductive silver metal from the reduction of SVO aided by the coexistence of graphene additive thus a prolonged operation voltage is observed with enhanced electronic conductivity throughout the whole discharge process. In particular, the hybrid shows capacity retention of {approx}462 mAhg-1 at 5C rate and 661 mAhg-1 at 1C rate. The peak current delivered from the as-designed hybrid cathode is improved compared with that of commercial Zn/Ag2O batteries suggesting the possibility of the further reduction on the size/weight of the micro batteries which is critical for the transmitters.

  7. Ion generation and CPC detection efficiency studies in sub 3-nm size range

    SciTech Connect (OSTI)

    Kangasluoma, J.; Junninen, H.; Sipilae, M.; Kulmala, M.; Petaejae, T.; Lehtipalo, K.; Mikkilae, J.; Vanhanen, J.; Attoui, M.; Worsnop, D.

    2013-05-24

    We studied the chemical composition of commonly used condensation particle counter calibration ions with a mass spectrometer and found that in our calibration setup the negatively charged ammonium sulphate, sodium chloride and tungsten oxide are the least contaminated whereas silver on both positive and negative and the three mentioned earlier in positive mode are contaminated with organics. We report cut-off diameters for Airmodus Particle Size Magnifier (PSM) 1.1, 1.3, 1.4, 1.6 and 1.6-1.8 nm for negative sodium chloride, ammonium sulphate, tungsten oxide, silver and positive organics, respectively. To study the effect of sample relative humidity on detection efficiency of the PSM we used different humidities in the differential mobility analyzer sheath flow and found that with increasing relative humidity also the detection efficiency of the PSM increases.

  8. Solar cell array interconnects

    DOE Patents [OSTI]

    Carey, Paul G. (Mountain View, CA); Thompson, Jesse B. (Brentwood, CA); Colella, Nicolas J. (Livermore, CA); Williams, Kenneth A. (Livermore, CA)

    1995-01-01

    Electrical interconnects for solar cells or other electronic components using a silver-silicone paste or a lead-tin (Pb-Sn) no-clean fluxless solder cream, whereby the high breakage of thin (<6 mil thick) solar cells using conventional solder interconnect is eliminated. The interconnects of this invention employs copper strips which are secured to the solar cells by a silver-silicone conductive paste which can be used at room temperature, or by a Pb-Sn solder cream which eliminates undesired residue on the active surfaces of the solar cells. Electrical testing using the interconnects of this invention has shown that no degradation of the interconnects developed under high current testing, while providing a very low contact resistance value.

  9. Spin and orbital magnetism of coinage metal trimers (Cu{sub 3}, Ag{sub 3}, Au{sub 3}): A relativistic density functional theory study

    SciTech Connect (OSTI)

    Afshar, Mahdi; Sargolzaei, Mohsen

    2013-11-15

    We have demonstrated electronic structure and magnetic properties of Cu{sub 3}, Ag{sub 3} and Au{sub 3} trimers using a full potential local orbital method in the framework of relativistic density functional theory. We have also shown that the non-relativistic generalized gradient approximation for the exchange-correlation energy functional gives reliable magnetic properties in coinage metal trimers compared to experiment. In addition we have indicated that the spin-orbit coupling changes the structure and magnetic properties of gold trimer while the structure and magnetic properties of copper and silver trimers are marginally affected. A significant orbital moment of 0.21?{sub B} was found for most stable geometry of the gold trimer whereas orbital magnetism is almost quenched in the copper and silver trimers.

  10. Process for electrically interconnecting electrodes

    DOE Patents [OSTI]

    Carey, Paul G. (Mountain View, CA); Thompson, Jesse B. (Brentwood, CA); Colella, Nicolas J. (Livermore, CA); Williams, Kenneth A. (Livermore, CA)

    2002-01-01

    Electrical interconnects for solar cells or other electronic components using a silver-silicone paste or a lead-tin (Pb--Sn) no-clean fluxless solder cream, whereby the high breakage of thin (<6 mil thick) solar cells using conventional solder interconnect is eliminated. The interconnects of this invention employs copper strips which are secured to the solar cells by a silver-silicone conductive paste which can be used at room temperature, or by a Pb--Sn solder cream which eliminates undesired residue on the active surfaces of the solar cells. Electrical testing using the interconnects of this invention has shown that no degradation of the interconnects developed under high current testing, while providing a very low contact resistance value.

  11. Method and apparatus for forming high-critical-temperature superconducting layers on flat and/or elongated substrates

    DOE Patents [OSTI]

    Ciszek, T.F.

    1994-04-19

    An elongated, flexible superconductive wire or strip is fabricated by pulling it through and out of a melt of metal oxide material at a rate conducive to forming a crystalline coating of superconductive metal oxide material on an elongated, flexible substrate wire or strip. A coating of crystalline superconductive material, such as Bi[sub 2]Sr[sub 2]CaCu[sub 2]O[sub 8], is annealed to effect conductive contact between adjacent crystalline structures in the coating material, which is then cooled to room temperature. The container for the melt can accommodate continuous passage of the substrate through the melt. Also, a second pass-through container can be used to simultaneously anneal and overcoat the superconductive coating with a hot metallic material, such as silver or silver alloy. A hollow, elongated tube casting method of forming an elongated, flexible superconductive wire includes drawing the melt by differential pressure into a heated tubular substrate. 8 figures.

  12. Double dumbbell shaped AgNi alloy by pulsed electrodeposition

    SciTech Connect (OSTI)

    Dhanapal, K.; Vasumathi, M.; Santhi, Kalavathy; Narayanan, V. Stephen, A.

    2014-01-28

    Silver-Nickel is the well-known thermally immiscible system that makes them quite complex for the formation of alloy. This kind of alloy can be attained from electrodeposition method. In the present work, AgNi alloy was synthesized by pulsed electrodeposition in a single bath two electrode system with the use of anodic alumina membrane. The prepared AgNi alloy and pure Ag were characterized with X-ray Diffraction (XRD) for structural confirmation, Scanning Electron Microscopy (SEM) for morphological, and magnetic properties by Vibrating Sample Magnetometer, respectively. The X-ray Diffraction study shows the formation of cubic structure for pure Ag. SEM analysis reveals the double dumbbell morphology for AgNi alloy and spherically agglomeration for pure silver. Hysteresis behaviour from VSM measurement indicates that the AgNi alloy have good ferro-magnetic properties.

  13. Solid state electrochemical current source

    DOE Patents [OSTI]

    Potanin, Alexander Arkadyevich (Sarov, RU); Vedeneev, Nikolai Ivanovich (Sarov, RU)

    2002-04-30

    A cathode and a solid state electrochemical cell comprising said cathode, a solid anode and solid fluoride ion conducting electrolyte. The cathode comprises a metal oxide and a compound fluoride containing at least two metals with different valences. Representative compound fluorides include solid solutions of bismuth fluoride and potassium fluoride; and lead fluoride and potassium fluoride. Representative metal oxides include copper oxide, lead oxide, manganese oxide, vanadium oxide and silver oxide.

  14. SNL Sigma Off-Gas Team Contribution to the FY15 DOE/NE-MRWFD Campaign Accomplishments Report.

    SciTech Connect (OSTI)

    Nenoff, Tina M.

    2015-08-21

    This program at Sandia is focused on Iodine waste form development for Fuel Cycle R&D needs. Our research has a general theme of Capture and Storage of Iodine Fission Gas in which we are focused on silver loaded zeolite waste forms, evaluation of iodine loaded getter materials (eg., mordenite zeolite), and the development of low temperature glass waste forms that successfully incorporate iodine loaded getter materials from I2, organic iodide, etc. containing off-gas streams.

  15. Recap and Conclusions to Tc/I in Hanford Flowsheet Presentations

    Office of Environmental Management (EM)

    Recap & Conclusions to Tc/I in Hanford Flowsheet Presentations Gary Smith Office of Waste Processing (EM-31) November 18, 2010 2 Rough Flowsheet Diagram Tank Farm Evaporator Pretreatment Evaporator IDF ETF HLW LAW Vit Secondary SBS WESP Melter Supplemental ? Repository Secondary -Caustic Scrub (LAW Vit) -HEPA Filters -Carbon Beds -Silver Mordenite (HLW Vit) -Other operating wastes Fate of Tc-99 at WTP * WTP flowsheet Tc partitions: - approximately 77.1% to supplemental LAW treatment -

  16. Introduction to Tc/I in Hanford Flowsheet

    Office of Environmental Management (EM)

    Introduction to Tc/I in Hanford Flowsheet Gary Smith Office of Waste Processing (EM-31) November 18, 2010 2 Rough Flowsheet Diagram Tank Farm Evaporator Pretreatment Evaporator IDF ETF HLW LAW Vit Secondary SBS WESP Melter Supplemental ? Repository Secondary -Caustic Scrub (LAW Vit) -HEPA Filters -Carbon Beds -Silver Mordenite (HLW Vit) -Other operating wastes Recycle Options * Continuous recycle of the SBS/WESP bottoms from LAW vitrification are assumed in baseline - could consider purges and

  17. Before the Senate Energy and Natural Resources Committee | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy Before the Senate Energy and Natural Resources Committee By: Jonathan Silver, Executive Director Loan Program Office Subject: Energy Efficiency and Alternative Fuel Vehicles PDF icon Final_Testimony_JSilver.pdf More Documents & Publications Before the Subcommittee on Economic Growth, Job Creation and Regulatory Affairs - House Committee on Oversight and Governmant Reform Advanced Technology Vehicles Manufacturing Loan Program ATVM Guidance for Applicants 11.4.14

  18. Table B-1: Analytical Results Statistical Mean Upper Confidence

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B-1: Analytical Results Statistical Mean Upper Confidence Limit Statistical Mean Upper Confidence Limit TCLP Metals: TCLP Semivolatiles: Arsenic o-Cresol Barium p-Cresol Cadmium m-Cresol Chromium Cresol Lead 2,4-Dinitrotoluene Mercury Hexachlorobenzene Selenium Hexachlorobutadiene Silver Nitrobenzene TCLP Volatiles Pentachlorophenol Benzene 2,4,5-Trichlorophenol Carbon Tetrachloride 2,4,6-Trichlorophenol Chlorobenzene Hexachloroethane Chloroform TCLP Pesticides and Herbicides:

  19. DRAFT EESA LOBBYING DISCLOSURE AND CERTIFICATION FORM

    Broader source: Energy.gov (indexed) [DOE]

    7/19/2011 2:00 PM EST Jonathan Silver Executive Director Loan Programs U.S. Department of Energy Discussion of AltEn biofuels project. Participants received information on existing on DOE programs. Name of the Employee(s) who prepared this form: Ann Shikany Date: 7/19/2011 Registered Lobbyist(s) Name: Eric Bursch Title: Legislative Assistant Firm or Organization, if applicable: OFW Law (Olsson Frank Weeda) Client: AltEn

  20. DRAFT EESA LOBBYING DISCLOSURE AND CERTIFICATION FORM

    Broader source: Energy.gov (indexed) [DOE]

    15/2011 3:00 PM EST Susan Richardson Chief Counsel Loan Programs U.S. Department of Energy Douglas Schultz Senior Investment Officer Andrzej Potasinski Senior Investment Officer Nancy Donovan General Counsel Jonathan Silver Executive Director - (Did not attend) Participants discussed the status of First Solar's Topaz project. Name of the Employee(s) who prepared this form: Ann Shikany Date: 9/22/2011 Registered Lobbyist(s) Name: Kathleen Weiss Title: Vice President, Government Relations Firm or

  1. Mineral resources and mineral resource potential of the Panamint Dunes Wilderness Study Area, Inyo County, California

    SciTech Connect (OSTI)

    Kennedy, G.L.; Kilburn, J.E.; Conrad, J.E.; Leszcykowski, A.M.

    1984-01-01

    This report presents the results of a mineral survey of the Panamint Dunes Wilderness Study Area (CDCA-127), California Desert Conservation Area, Inyo County, California. The Panamint Dunes Wilderness Study Area has an identified volcanic cinder resource and few areas with mineral resource potential. Hydrothermal deposits of lead-zinc-silver occur in veins and small replacement bodies along and near the Lemoigne thrust fault on the eastern side of the wilderness study area. Two workings, the Big Four mine with 35,000 tons of inferred subeconomic lead-zinc-silver resources and a moderate potential for additional resources, and the Apple 1 claim with low potential for lead-zinc-silver resources, are surrounded by the study area but are specifically excluded from it. A low resource potential for lead-zinc-silver is assigned to other exposures along the Lemoigne thrust, although metallic minerals were not detected at these places. The Green Quartz prospect, located near the northern tip of the study area, has low resource potential for copper in quartz pegmatities in quartz monzonite of the Hunter Mountain batholith. Nonmetallic mineral resources consist of volcanic cinders and quartz sand. An estimated 900,000 tons of inferred cinder reserves are present at Cal Trans borrow pit MS 242, on the southern margin of the study area. The Panamint Valley dune field, encompassing 480 acres in the north-central part of the study area, has only low resource potential for silica because of impurities. Other sources of silica and outside the study area are of both higher purity and closer to possible markets. 19 refs., 2 figs., 1 tab.

  2. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, V.A.

    1991-04-23

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

  3. EIS-0005-FS: Bonneville Power Administration Proposed FY 1979 Program, Facility Location on Supplement, Southwest Oregon Area Service, Buckley-Summer Lake 500 kV Line, Supplemental

    Broader source: Energy.gov [DOE]

    This Bonneville Power Administration document assesses the environmental impacts of constructing transmission facilities, which will coordinate with the Midpoint-Malin 500-kV line to be constructed by the Pacific Power and Light (PP&L) Company. The proposed action includes the construction of the 1.56-mile Buckley-Summer Lake 500-kV transmission line; the proposed Buckley Substation near Maupin, Oregon; and the proposed Summer Lake Substation near Silver Lake, Oregon.

  4. FUEL ELEMENTS FOR THERMAL-FISSION NUCLEAR REACTORS

    DOE Patents [OSTI]

    Flint, O.

    1961-01-10

    Fuel elements for thermal-fission nuclear reactors are described. The fuel element is comprised of a core of alumina, a film of a metal of the class consisting of copper, silver, and nickel on the outer face of the core, and a coating of an oxide of a metal isotope of the class consisting of Un/sup 235/, U/ sup 233/, and Pu/sup 239/ on the metal f ilm.

  5. Precious Metals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precious Metals General Information: The Materials Handling group provides Precious Metals receiving and documentation (PM's) for research programs funded by the Department of Energy (DOE). Precious metals are obtained from the DOE's Business Center for Precious Metals Sales and Recovery (BCPMSR). The return of scrap and excess precious metals to the BCPMSR is also provided by this group. Metals under this control are: GOLD - SILVER - PLATINUM - RHODIUM - PALLADIUM - IRIDIUM - OSMIUM - RUTHENIUM

  6. SOLAR PANELS ON HUDSON COUNTY FACILITIES

    SciTech Connect (OSTI)

    BARRY, KEVIN

    2014-06-06

    This project involved the installation of an 83 kW grid-connected photovoltaic system tied into the energy management system of Hudson County's new 60,000 square foot Emergency Operations and Command Center and staff offices. Other renewable energy features of the building include a 15 kW wind turbine, geothermal heating and cooling, natural daylighting, natural ventilation, gray water plumbing system and a green roof. The County intends to seek Silver LEED certification for the facility.

  7. Residential Windows and Window Coverings: A Detailed View of the Installed Base and User Behavior

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Windows and Window Coverings: A Detailed View of the Installed Base and User Behavior SEPTEMBER 2013 Prepared for: Building Technologies Office Office of Energy Efficiency and Renewable Energy U.S. Department of Energy Prepared by: D&R International, Ltd. September 2013 Prepared for: Building Technologies Office Office of Energy Efficiency and Renewable Energy U.S. Department of Energy Prepared By: D&R International, Ltd. 1300 Spring Street, Suite 500 Silver Spring, MD 20910

  8. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D.; Bond, Walter D.; Lauf, Robert J.

    1993-01-01

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  9. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  10. EIS-0393: EPA Notice of Availability of Final Environmental Impact

    Energy Savers [EERE]

    Statement | Department of Energy EPA Notice of Availability of Final Environmental Impact Statement EIS-0393: EPA Notice of Availability of Final Environmental Impact Statement Montanore Project; Montana EPA announced the availability of a Final EIS prepared by USDA Forest Service (Kootenai National Forest) and the Montana Department of Environmental Quality to evaluate the potential environmental impacts of a proposed copper and silver underground mine about 18 miles south of Libby,

  11. Sierra Geothermal's Key Find in Southern Nevada

    Broader source: Energy.gov [DOE]

    In May 2010, Sierra Geothermal determined temperature at the bottom of a well drilled at the company's Alum project near Silver Peak, Nev., was hot enough for commercial-sized geothermal energy production - measured as 147 degrees Celsius (297 degrees Fahrenheit). A promising discovery by a geothermal energy company that could boost use of the renewable source in southwest Nevada, power thousands of homes and create jobs.

  12. Final Report: Experimental and Theoretical Studies of Surface Oxametallacycles - Connections to Heterogeneous Olefin Epoxidation

    SciTech Connect (OSTI)

    Mark A. Barteau

    2009-09-15

    This project has aimed at the rational design of catalysts for direct epoxidation of olefins. This chemistry remains one of the most challenging problems in heterogeneous catalysis. Although the epoxidation of ethylene by silver catalysts to form ethylene oxide (EO) has been practiced for decades, little progress has been made in expanding this technology to other products and processes. We have made significant advances through the combination of surface science experiments, Density Functional Theory (DFT) calculations, and catalytic reactor experiments, toward understanding the mechanism of this reaction on silver catalysts, and to the rational improvement of selectivity. The key has been our demonstration of surface oxametallacycle intermediates as the species that control reaction selectivity. This discovery permits the influence of catalyst promoters on selectivity to be probed, and new catalyst formulations to be developed. It also guides the development of new chemistry with potential for direct epoxidation of more complex olefins. During the award period we have focused on 1. the formation and reaction selectivity of complex olefin epoxides on silver surfaces, and 2. the influence of co-adsorbed oxygen atoms on the reactions of surface oxametallacycles on silver, and 3. the computational prediction, synthesis, characterization and experimental evaluation of bimetallic catalysts for ethylene epoxidation. The significance of these research thrusts is as follows. Selective epoxidation of olefins more complex than ethylene requires suppression of not only side reactions available to the olefin such as C-H bond breaking, but it requires formation and selective ring closure of the corresponding oxametallacycle intermediates. The work carried out under this grant has significantly advanced the field of catalyst design from first principles. The combination of computational tools, surface science, and catalytic reactor experiments in a single laboratory has few other examples. We have successfully predicted and validated new bimetallic catalyst for ethylene epoxidation. In so doing, we have established one of the first examples of successful catalyst design from first principles to achieve improved reaction selectivity.

  13. Device Tosses Out Unusable PV Wafers - News Feature | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Device Tosses Out Unusable PV Wafers January 11, 2013 Photo of a scientist in safety glasses using tweezers to hold a rectangular gray silicon wafer. He is about to load it into a large silver-metallic instrument. Enlarge image NREL postdoctoral scientist Rene Rivero readies a wafer for the Silicon Photovoltaic Wafer Screening System. Credit: Dennis Schroeder Silicon wafers destined to become photovoltaic (PV) cells can take a bruising through assembly lines, as they are oxidized, annealed,

  14. Kurtz, Sprunger, Zhao, Kizilkaya

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reducing Dimensions: Wiry Metals and Skinny Oxides 1. Electronic Structure of Silver Nanowires on Cu(110) Self-assembled nanomaterials with reduced dimensionality, or at least one dimension that is on the nanoscale, such as one-dimensional nanowires, have been studied intensively in recent years. The nanostructured materials are promising building blocks for manufacturing devices of nanoelectronics and photonics from a bottom-up approach. STM results (see Fig.1) show that the Ag nanowires grown

  15. Preparation of nanoporous metal foam from high nitrogen transition metal complexes

    DOE Patents [OSTI]

    Tappan, Bryce C.; Huynh, My Hang V.; Hiskey, Michael A.; Son, Steven F.; Oschwald, David M.; Chavez, David E.; Naud, Darren L.

    2006-11-28

    Nanoporous metal foams are prepared by ignition of high nitrogen transition metal complexes. The ammonium salts of iron(III) tris[bi(tetrazolato)-amine], cobalt(III) tris(bi(tetrazolato)amine), and high nitrogen compounds of copper and silver were prepared as loose powders, pressed into pellets and wafers, and ignited under an inert atmosphere to form nanoporous metal foam monoliths having very high surface area and very low density.

  16. NREL: Transportation Research Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation Research Silver Toyota Prius being driven in front of NREL entrance sign. NREL helps industry partners develop the next generation of energy efficient, high performance vehicles and fuels. Thermal image of two men standing in front of tractor trailer cab. NREL conducts research on the full range of vehicle types, from light-duty passenger cars to heavy-duty freight trucks. Female researcher holding coin cell battery. NREL's transportation research spans from the materials to the

  17. Global Climate Change and the Unique (?) Challenges Posed by the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transportation Sector | Department of Energy Change and the Unique (?) Challenges Posed by the Transportation Sector Global Climate Change and the Unique (?) Challenges Posed by the Transportation Sector 2002 DEER Conference Presentation: Joint Global Change Research Institute - Battelle PDF icon 2002_deer_dooley.pdf More Documents & Publications There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies EAC Presentation - Roadmap 2050: A

  18. High conductivity composite metal

    DOE Patents [OSTI]

    Zhou, R.; Smith, J.L.; Embury, J.D.

    1998-01-06

    Electrical conductors and methods of producing them are disclosed, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps. 10 figs.

  19. Catalyst and process for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.

    1987-01-01

    The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  20. Creation of Light and/or Surface Plasmons with Heated Metallic Films

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2012-03-13

    Thin Metal Film Plasmonic Device Ultrasmooth thin metal films with a nanoscale bull’s eye pattern of circular concentric grooves produce a monochromatic beam of collimated light when heated. The plasmonic device can be made from different metals such as tungsten, gold and silver or other combinations of materials. The wavelength of the emitted light can be tuned by changing the metal and the spacing of the concentric grooves of the bull’s...