Sample records for fbsr na-al-si nas

  1. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM Flash2011-12 OPAMGeneralGuiding Documents and LinkslDeep DigAWasteLow

  2. Fluidized Bed Steam Reformed (FBSR) Mineral Waste Forms: Characterization and Durability Testing

    SciTech Connect (OSTI)

    Jantzen, Carol M.; Lorier, Troy H.; Pareizs, John M.; Marra, James C. [Savannah River National Laboratory, Aiken, SC, 29803 (United States)

    2007-07-01T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a mineralizing technology for the immobilization of a wide variety of wastes that are high in organics, nitrates-nitrites, halides, and/or sulfates. These wastes include the decontaminated High Level Waste (HLW) supernates referred to as low activity waste (LAW) at Department of Energy (DOE) sites in the United States and waste streams that may be generated by the advanced nuclear fuel cycle flowsheets that are being considered by the Global Nuclear Energy Partnership (GNEP) initiative. The organics are pyrolyzed into CO{sub 2} and steam in the absence of air. The FBSR mineral waste form is a granular but can subsequently be made into a monolith for disposal if necessary. The waste form is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals (sodalite, nosean, and nepheline) with cage and ring structures that sequester radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. Iron bearing spinel minerals are also formed and these phases stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Dissolution rates ({eta}) and activation energies of dissolution are parameters needed for Performance Assessments (PA) to be completed on the FBSR mineral waste form. These parameters are defined in this study by Single Pass Flow Through (SPFT) testing. The dissolution rate ({eta}) and the activation energies for dissolution calculated in this study agree with the available rate and activation energy data for natural single crystal nepheline. (authors)

  3. FLUIDIZED BED STEAM REFORMER (FBSR) PRODUCT: MONOLITH FORMATION AND CHARACTERIZATION

    SciTech Connect (OSTI)

    Jantzen, C

    2006-09-13T23:59:59.000Z

    The most important requirement for Hanford's low activity waste (LAW) form for shallow land disposal is the chemical durability of the product. A secondary, but still essential specification, is the compressive strength of the material with regards to the strength of the material under shallow land disposal conditions, e.g. the weight of soil overburden and potential intrusion by future generations, because the term ''near-surface disposal'' indicates disposal in the uppermost portion, or approximately the top 30 meters, of the earth's surface. The THOR{reg_sign} Treatment Technologies (TTT) mineral waste form for LAW is granular in nature because it is formed by Fluidized Bed Steam Reforming (FBSR). As a granular product it has been shown to be as durable as Hanford's LAW glass during testing with ASTM C-1285-02 known as the Product Consistency Test (PCT) and with the Single Pass Flow Through Test (SPFT). Hanford Envelope A and Envelope C simulants both performed well during PCT and SPFT testing and during subsequent performance assessment modeling. This is partially due to the high aluminosilicate content of the mineral product which provides a natural aluminosilicate buffering mechanism that inhibits leaching and is known to occur in naturally occurring aluminosilicate mineral analogs. In order for the TTT Na-Al-Si (NAS) granular mineral product to meet the compressive strength requirements (ASTM C39) for a Hanford waste form, the granular product needs to be made into a monolith or disposed of in High Integrity Containers (HIC's). Additionally, the Hanford intruder scenario for disposal in the Immobilized Low Activity Waste (ILAW) trench is mitigated as there is reduced intruder exposure when a waste form is in a monolithic form. During the preliminary testing of a monolith binder for TTT's FBSR mineral product, four parameters were monitored: (1) waste loading (not optimized for each waste form tested); (2) density; (3) compressive strength; and (4) durability must not be compromised--binding agent should not react with the NAS product and binding agent should not create an unfavorable pH environment that may cause accelerated leaching. It is the goal of the present study to survey cementitious waste forms based on Ordinary Portland Cement (OPC), Ceramicrete, and hydroceramic binders by correlating waste loading, density and compressive strength and then determine if these binders affect the product performance in terms of the PCT response. This will be done by making a one-to-one comparison of the PCT response measured on granular NAS mineral product (mixed bed and fines products) with the PCT response of the monolithed NAS product in the different binders. Future studies may include, refining the above binders, and examining other binders. It is likely that binders formed from kaolin would be most compatible with the chemistry of the THOR{reg_sign} mineral waste form which is made by steam reforming of kaolin and sodium rich wastes. The economics of production on a large scale have yet to be investigated for any of the binders tested.

  4. Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...

    Office of Environmental Management (EM)

    Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3...

  5. Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

    2012-10-22T23:59:59.000Z

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

  6. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Brown, Christopher F.; Peterson, Reid A.

    2013-10-01T23:59:59.000Z

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. This goal of this campaign was study the durability of the FBSR mineral product and the mineral product encapsulated in a monolith to meet compressive strength requirements. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory.

  7. Characterization and Leaching Tests of the Fluidized Bed Steam Reforming (FBSR) Waste Form for LAW Immobilization - 13400

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla P.; Peterson, Reid A.; Brown, Christopher F. [Pacific Northwest National Laboratory, Richland, WA (United States)] [Pacific Northwest National Laboratory, Richland, WA (United States)

    2013-07-01T23:59:59.000Z

    Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) have been evaluated. One such immobilization technology is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Pacific Northwest National Laboratory (PNNL) was involved in an extensive characterization campaign. The goal of this campaign was to study the durability of the FBSR mineral product and the encapsulated FBSR product in a geo-polymer monolith. This paper gives an overview of results obtained using the ASTM C 1285 Product Consistency Test (PCT), the EPA Test Method 1311 Toxicity Characteristic Leaching Procedure (TCLP), and the ASTMC 1662 Single-Pass Flow-Through (SPFT) test. Along with these durability tests an overview of the characteristics of the waste form has been collected using Scanning Electron Microscopy (SEM), X-ray Diffraction (XRD), microwave digestions for chemical composition, and surface area from Brunauer, Emmett, and Teller (BET) theory. (authors)

  8. A thermodynamic model for hydrous silicate melts in the system NaAlSi3O8KAlSi3O8Si4O8H2O

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A thermodynamic model for hydrous silicate melts in the system NaAlSi3O8­KAlSi3O8­Si4O8­H2O Marcus ­ remplacé par UMR6113 - ISTO Abstract Computation of crystal­liquid equilibria in hydrous silicate systems system. Author Keywords: Haplogranite system; Hydrous silicate melt; Liquidus phase equilibria; Linear

  9. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS

    SciTech Connect (OSTI)

    Jantzen, C

    2006-01-06T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied.

  10. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12T23:59:59.000Z

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  11. MINERALIZATION OF RADIOACTIVE WASTES BY FLUIDIZED BED STEAM REFORMING (FBSR): COMPARISONS TO VITREOUS WASTE FORMS, AND PERTINENT DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C

    2008-12-26T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) was requested to generate a document for the Washington State Department of Ecology and the U.S. Environmental Protection Agency that would cover the following topics: (1) A description of the mineral structures produced by Fluidized Bed Steam Reforming (FBSR) of Hanford type Low Activity Waste (LAW including LAWR which is LAW melter recycle waste) waste, especially the cage structured minerals and how they are formed. (2) How the cage structured minerals contain some contaminants, while others become part of the mineral structure (Note that all contaminants become part of the mineral structure and this will be described in the subsequent sections of this report). (3) Possible contaminant release mechanisms from the mineral structures. (4) Appropriate analyses to evaluate these release mechanisms. (5) Why the appropriate analyses are comparable to the existing Hanford glass dataset. In order to discuss the mineral structures and how they bond contaminants a brief description of the structures of both mineral (ceramic) and vitreous waste forms will be given to show their similarities. By demonstrating the similarities of mineral and vitreous waste forms on atomic level, the contaminant release mechanisms of the crystalline (mineral) and amorphous (glass) waste forms can be compared. This will then logically lead to the discussion of why many of the analyses used to evaluate vitreous waste forms and glass-ceramics (also known as glass composite materials) are appropriate for determining the release mechanisms of LAW/LAWR mineral waste forms and how the durability data on LAW/LAWR mineral waste forms relate to the durability data for LAW/LAWR glasses. The text will discuss the LAW mineral waste form made by FBSR. The nanoscale mechanism by which the minerals form will be also be described in the text. The appropriate analyses to evaluate contaminant release mechanisms will be discussed, as will the FBSR test results to date and how they compare to testing performed on LAW glasses. Other details about vitreous waste form durability and impacts of REDuction/OXidation (REDOX) on durability are given in Appendix A. Details about the FBSR process, various pilot scale demonstrations, and applications are given in Appendix B. Details describing all the different leach tests that need to be used jointly to determine the leaching mechanisms of a waste form are given in Appendix C. Cautions regarding the way in which the waste form surface area is measured and in the choice of leachant buffers (if used) are given in Appendix D.

  12. Durability Testing of Fluidized Bed Steam Reforming Products

    SciTech Connect (OSTI)

    JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

    2005-07-01T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

  13. CRUCIBLE TESTING OF TANK 48 RADIOACTIVE WASTE SAMPLE USING FBSR TECHNOLOGY FOR ORGANIC DESTRUCTION

    SciTech Connect (OSTI)

    Hammond, C; William Pepper, W

    2008-09-19T23:59:59.000Z

    The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be >99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that {approx}75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

  14. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank Farm Blend) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-08-21T23:59:59.000Z

    The U.S. Department of Energys Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanfords tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTPs LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanfords blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a tie back between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for to

  15. FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION

    SciTech Connect (OSTI)

    Jantzen, C

    2006-12-22T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as an alternative technology for the immobilization of a wide variety of aqueous high sodium containing radioactive wastes at various DOE facilities in the United States. The addition of clay, charcoal, and a catalyst as co-reactants converts aqueous Low Activity Wastes (LAW) to a granular or ''mineralized'' waste form while converting organic components to CO{sub 2} and steam, and nitrate/nitrite components, if any, to N{sub 2}. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage-like structures that atomically bond radionuclides like Tc-99 and anions such as SO{sub 4}, I, F, and Cl. The granular product has been shown to be as durable as LAW glass. Shallow land burial requires that the mineralized waste form be able to sustain the weight of soil overburden and potential intrusion by future generations. The strength requirement necessitates binding the granular product into a monolith. FBSR mineral products were formulated into a variety of monoliths including various cements, Ceramicrete, and hydroceramics. All but one of the nine monoliths tested met the <2g/m{sup 2} durability specification for Na and Re (simulant for Tc-99) when tested using the Product Consistency Test (PCT; ASTM C1285). Of the nine monoliths tested the cements produced with 80-87 wt% FBSR product, the Ceramicrete, and the hydroceramic produced with 83.3 wt% FBSR product, met the compressive strength and durability requirements for an LAW waste form.

  16. Experimental determination of the speciation, partitioning, and release of perrhenate as a chemical surrogate for pertechnetate from a sodalite-bearing multiphase ceramic waste form

    SciTech Connect (OSTI)

    Pierce, Eric M.; Lukens, Wayne W.; Fitts, Jeff. P.; Jantzen, Carol. M.; Tang, G.

    2013-12-01T23:59:59.000Z

    A key component to closing the nuclear fuel cycle is the storage and disposition of nuclear waste in geologic systems. Multiphase ceramic waste forms have been studied extensively as a potential host matrix for nuclear waste. Understanding the speciation, partitioning, and release behavior of radionuclides immobilized in multiphase ceramic waste forms is a critical aspect of developing the scientific and technical basis for nuclear waste management. In this study, we evaluated a sodalite-bearing multiphase ceramic waste form (i.e., fluidized-bed steam reform sodium aluminosilicate [FBSR NAS] product) as a potential host matrix for long-lived radionuclides, such as technetium (99Tc). The FBSR NAS material consists primarily of nepheline (ideally NaAlSiO4), anion-bearing sodalites (ideally M8[Al6Si6O24]X2, where M refers to alkali and alkaline earth cations and X refers to monovalent anions), and nosean (ideally Na8[AlSiO4]6SO4). Bulk X-ray absorption fine structure analysis of the multiphase ceramic waste form, suggest rhenium (Re) is in the Re(VII) oxidation state and has partitioned to a Re-bearing sodalite phase (most likely a perrhenate sodalite Na8[Al6Si6O24](ReO4)2). Rhenium was added as a chemical surrogate for 99Tc during the FBSR NAS synthesis process. The weathering behavior of the FBSR NAS material was evaluated under hydraulically unsaturated conditions with deionized water at 90 ?C. The steady-state Al, Na, and Si concentrations suggests the weathering mechanisms are consistent with what has been observed for other aluminosilicate minerals and include a combination of ion exchange, network hydrolysis, and the formation of an enriched-silica surface layer or phase. The steady-state S and Re concentrations are within an order of magnitude of the nosean and perrhenate sodalite solubility, respectively. The order of magnitude difference between the observed and predicted concentration for Re and S may be associated with the fact that the anion-bearing sodalites contained in the multiphase ceramic matrix are present as mixed-anion sodalite phases. These results suggest the multiphase FBSR NAS material may be a viable host matrix for long-lived, highly mobilie radionuclides which is a critical aspect in the management of nuclear waste.

  17. Experimental Determination of the Speciation, Partitioning, and Release of Perrhenate as a Chemical Surrogate for Pertechnetate from a Sodalite-Bearing Multiphase Ceramic Waste Form

    SciTech Connect (OSTI)

    Pierce, Eric M [ORNL] [ORNL; Lukens, Wayne W [Lawrence Berkeley National Laboratory (LBNL)] [Lawrence Berkeley National Laboratory (LBNL); Fitts, Jeffrey P [Princeton University] [Princeton University; Tang, Guoping [ORNL] [ORNL; Jantzen, C M [Savannah River National Laboratory (SRNL)] [Savannah River National Laboratory (SRNL)

    2013-01-01T23:59:59.000Z

    A key component to closing the nuclear fuel cycle is the storage and disposition of nuclear waste in geologic systems. Multiphase ceramic waste forms have been studied extensively as a potential host matrix for nuclear waste. Understanding the speciation, partitioning, and release behavior of radionuclides immobilized in multiphase ceramic waste forms is a critical aspect of developing the scientific and technical basis for nuclear waste management. In this study, we evaluated a sodalite-bearing multiphase ceramic waste form (i.e., fluidized-bed steam reform sodium aluminosilicate [FBSR NAS] product) as a potential host matrix for long-lived radionuclides, such as technetium (99Tc). The FBSR NAS material consists primarily of nepheline (ideally NaAlSiO4), anion-bearing sodalites (ideally M8[Al6Si6O24]X2, where M refers to alkali and alkaline earth cations and X refers to monovalent anions), and nosean (ideally Na8[AlSiO4]6SO4). Bulk x-ray absorption fine structure analysis of the multiphase ceramic waste form, suggest rhenium (Re) is in the Re(VII) oxidation state and has partitioned to a Re-bearing sodalite phase (most likely a perrhenate sodalite Na8[Al6Si6O24](ReO4)2). Rhenium was added as a chemical surrogate for 99Tc during the FBSR NAS synthesis process. The weathering behavior of the FBSR NAS material was evaluated under hydraulically unsaturated conditions with deionized water at 90 C. The steady-state Al, Na, and Si concentrations suggests the weathering mechanisms are consistent with what has been observed for other aluminosilicate minerals and include a combination of ion exchange, network hydrolysis, and the formation of an enriched-silica surface layer or phase. The steady-state S and Re concentrations are within an order of magnitude of the nosean and perrhenate sodalite solubility, respectively. The order of magnitude difference between the observed and predicted concentration for Re and S may be associated with the fact that the anion-bearing sodalites contained in the multiphase ceramic matrix are present as mixed-anion sodalite phases. These results suggest the multiphase FBSR NAS material may be a viable host matrix for long-lived, highly mobilie radionuclides which is a critical aspect in the management of nuclear waste.

  18. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105, Tank AN-103, And AZ-101/102) By Fluidized Bed Steam Reformation (FBSR)

    SciTech Connect (OSTI)

    Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

    2013-09-18T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

  19. Storage : DAS / SAN / NAS Dploiement

    E-Print Network [OSTI]

    Collette. Sbastien

    CH8 Divers Agenda Storage : DAS / SAN / NAS Dploiement VLAN 802.1Q Gestion d Scurisation de Windows Scurisation de UNIX Qu'est-ce que... Firewall, VPN, IDS/IPS, PKI Storage : DAS, NAS, SAN #12;Storage : DAS, NAS, SAN Direct Attached Storage Network Attached Storage Storage

  20. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE (WTP-SW) BY FLUIDIZED BED STEAM REFORMING (FBSR) USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, G.; Jantzen, C.; Missimer, D.

    2014-08-21T23:59:59.000Z

    The U.S. Department of Energys Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanfords tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanfords WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing. The granular products (both simulant and radioactive) were tested and a subset of the granular material (both simulant and radioactive) were stabilized in a geopolymer matrix. Extensive testing and characterization of the granular and monolith material were made including the following: ? ASTM C1285 (Product Consistency Test) testing of granular and monolith; ? ASTM C1308 accelerated leach testing of the radioactive monolith; ? ASTM C192 compression testing of monoliths; and ? EPA Method 1311 Toxicity Characteristic Leaching Procedure (TCLP) testing. The significant findings of the testing completed on simulant and radioactive WTP-SW are given below: ? Data indicates {sup 99}Tc, Re, Cs, and I

  1. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2006-12-06T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  2. FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING

    SciTech Connect (OSTI)

    Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

    2007-03-31T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

  3. UAS Integration in the NAS Project

    E-Print Network [OSTI]

    with the national strategy consistent with NextGen. Objectives: UAS Integration in the NAS ConOps; Ensure UAS

  4. GaInNAs laser gain

    SciTech Connect (OSTI)

    CHOW,WENG W.; JONES,ERIC D.; MODINE,NORMAND A.; KURTZ,STEVEN R.; ALLERMAN,ANDREW A.

    2000-05-23T23:59:59.000Z

    The optical gain spectra for GaInNAs/GaAs quantum wells are computed using a microscopic laser theory. From these spectra, the peak gain and carrier radiative decay rate as functions of carrier density are determined. These dependences allow the study of the lasing threshold current density of GaInNAs/GaAs quantum well structures.

  5. Porting the NAS-NPB Conjugate Gradient

    E-Print Network [OSTI]

    Crawford, T. Daniel

    .kr/Center_for_Manycore_Programming/SNU_NPB_Suite.html NPB Benchmarks #12;! "A conjugate gradient method is used to compute an approximation to the smallestPorting the NAS-NPB Conjugate Gradient Benchmark to CUDA NVIDIA Corporation #12;Outline ! Overview coding methodologies and architectures. ! Suite of benchmarks: ! Integer Sort ! Conjugate Gradient ! CFD

  6. NAs-Ns-3034(Revm) OF TITANIUM

    E-Print Network [OSTI]

    NAs-Ns-3034(Revm) R OF TITANIUM NUCLEAR SCIENCE SERIES National Academy of Sciences of `Titanium by Vincent J. Landis San DiegoState University San Diego, California and James H. Kaye Battelle of the Inorganic Chemistryof Titanium and Analytical 11. General Reviews of the Radiochemistryof Titanium III

  7. Carrier spin relaxation in GaInNAsSb/GaNAsSb/GaAs quantum well

    SciTech Connect (OSTI)

    Asami, T.; Nosho, H.; Tackeuchi, A. [Department of Applied Physics, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Li, L. H.; Harmand, J. C. [Laboratory for Photonics and Nanostructures-CNRS, Site Alcatel de Marcoussis, Route de Nozay, 91460 Marcoussis (France); Lu, S. L. [Suzhou Institute of Nano-tech and Nano-bionics, CAS, Dushu, Lake Higher Education Town, Ruoshui Road 398, Suzhou Industrial Park, Suzhou 215125 (China)

    2011-12-23T23:59:59.000Z

    We have investigated the carrier spin relaxation in GaInNAsSb/GaNAsSb/GaAs quantum well (QW) by time-resolved photoluminescence (PL) measurement. The sample consists of an 8-nm-thick GaIn{sub 0.36}N{sub 0.006}AsSb{sub 0.015} well, 5-nm-thick GaN{sub 0.01}AsSb{sub 0.11} intermediate barriers and 100-nm-thick GaAs barriers grown by molecular beam epitaxy on a GaAs(100) substrate. The spin relaxation time and recombination lifetime at 10 K are measured to be 228 ps and 151 ps, respectively. As a reference, we have also obtained a spin relaxation time of 125 ps and a recombination lifetime of 63 ps for GaInNAs/GaNAs/GaAs QW. This result shows that crystal quality is slightly improved by adding Sb, although these short carrier lifetimes mainly originate from a nonradiative recombination. These spin relaxation times are longer than the 36 ps spin relaxation time of InGaAs/InP QWs and shorter than the 2 ns spin relaxation time of GaInNAs/GaAs QW.

  8. acacia dealbata nas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the significant effort underway to integrate UAV operations in the NAS, a preliminary hazard analysis was conducted for two critical hazards of UAV operation. Models were...

  9. agua nas palhadas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Agenda Storage : DAS SAN NAS Dploiement VLAN - 802.1Q Gestion d Scurisation de Windows Scurisation de UNIX Qu'est-ce...

  10. atendimento nas unidades: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Agenda Storage : DAS SAN NAS Dploiement VLAN - 802.1Q Gestion d Scurisation de Windows Scurisation de UNIX Qu'est-ce...

  11. ALSEP TECHNICAL SPECIFICATION Contract NAS 9-5829

    E-Print Network [OSTI]

    Rathbun, Julie A.

    . ", ., ,I',: , t "' ,- EXHIBIT 13 ALSEP TECHNICAL SPECIFICATION Contract NAS 9-5829 -~ t. ".' . THE MncfYCORPORATION BENDIX SYSTEMS DIVISION' ANN ARBOR MICHIGAN' #12;EXHIBIT B ALSEP TECHNICAL SPECIFICATION Contract NAS 9-5829 March 10, 1966 #12;TABLE OF CONTENTS 1.0 SCOPE 1.1 Scope 1. 2 Associated

  12. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2, 2015 - January

  13. Propuesta de autorizacin para entornos Grid basada en la arquitectura NAS-SAML

    E-Print Network [OSTI]

    Sánchez Cuenca, Manuel

    Propuesta de autorización para entornos Grid basada en la arquitectura NAS-SAML Manuel Sánchez1 que acceden a sus recursos. Se han propuesto varias arquitecturas de autorización para este tipo de como un recurso más. La arquitectura AAA fue diseñada para resolver este problema usando diferentes

  14. Segmentao da parede torcica nas imagens de ressonncia Leila Pereira de Morais (bolsista), Aline Barbosa Alves (bolsista) e

    E-Print Network [OSTI]

    Carvalho, Joo Luiz

    Segmentao da parede torcica nas imagens de ressonncia Leila Pereira de Morais (bolsista), Aline de imagens de ressonncia magntica com o objetivo de avaliarmos a relao entre respirao. Palavras chaves- ressonncia magntica, segmentao torcica, processamento de imagens. 1. Introduo O

  15. Effect of antimony on the deep-level traps in GaInNAsSb thin films

    SciTech Connect (OSTI)

    Islam, Muhammad Monirul, E-mail: islam.monir.ke@u.tsukuba.ac.jp; Miyashita, Naoya; Ahsan, Nazmul; Okada, Yoshitaka [Research Center for Advanced Science and Technology (RCAST), The University of Tokyo, 4-6-1 Komaba, Meguro ku, Tokyo 153-8904 (Japan); Sakurai, Takeaki; Akimoto, Katsuhiro [Institute of Applied Physics, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan)

    2014-09-15T23:59:59.000Z

    Admittance spectroscopy has been performed to investigate the effect of antimony (Sb) on GaInNAs material in relation to the deep-level defects in this material. Two electron traps, E1 and E2 at an energy level 0.12 and 0.41?eV below the conduction band (E{sub C}), respectively, were found in undoped GaInNAs. Bias-voltage dependent admittance confirmed that E1 is an interface-type defect being spatially localized at the GaInNAs/GaAs interface, while E2 is a bulk-type defect located around mid-gap of GaInNAs layer. Introduction of Sb improved the material quality which was evident from the reduction of both the interface and bulk-type defects.

  16. Proceedings of Institute of Mathematics of NAS of Ukraine 2000, Vol. 30, Part 2, 341342. On -Wild Algebras

    E-Print Network [OSTI]

    Popovych, Roman

    Proceedings of Institute of Mathematics of NAS of Ukraine 2000, Vol. 30, Part 2, 341­342. On -Wild) be the group C-algebra. Definition (see [1]). We call a discrete group F -wild if there exist n N of -wild groups (other than the semi-direct products F G, where F is a wild group). Note that the group W

  17. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP)

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2Uranium Transferon the PassingRoutingEnergy Technologist inKey

  18. Study of a 1?eV GaNAsSb photovoltaic cell grown on a silicon substrate

    SciTech Connect (OSTI)

    Tan, K. H.; Loke, W. K.; Wicaksono, S.; Li, D.; Leong, Y. R.; Yoon, S. F. [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore)] [School of Electrical and Electronic Engineering, Nanyang Technological University, Nanyang Avenue, Singapore 639798 (Singapore); Sharma, P.; Milakovich, T.; Bulsara, M. T.; Fitzgerald, E. A. [Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, Massachusetts 02139 (United States)] [Massachusetts Institute of Technology, 77 Massachusetts Ave., Cambridge, Massachusetts 02139 (United States)

    2014-03-10T23:59:59.000Z

    We report the performance of a 1?eV GaNAsSb photovoltaic cell grown on a Si substrate with a SiGe graded buffer grown using molecular beam epitaxy. For comparison, the performance of a similar 1?eV GaN{sub 0.018}As{sub 0.897}Sb{sub 0.085} photovoltaic cell grown on a GaAs substrate was also reported. Both devices were in situ annealed at 700?C for 5?min, and a significant performance improvement over our previous result was observed. The device on the GaAs substrate showed a low open circuit voltage (V{sub OC}) of 0.42?V and a short circuit current density (J{sub SC}) of 23.4?mA/cm{sup 2} while the device on the Si substrate showed a V{sub OC} of 0.39?V and a J{sub SC} of 21.3?mA/cm{sup 2}. Both devices delivered a quantum efficiency of 50%55% without any anti-reflection coating.

  19. Report for Treating Hanford LAW and WTP SW Simulants: Pilot Plant Mineralizing Flowsheet

    SciTech Connect (OSTI)

    Arlin Olson

    2012-02-28T23:59:59.000Z

    The US Department of Energy is responsible for managing the disposal of radioactive liquid waste in underground storage tanks at the Hanford site in Washington State. The Hanford waste treatment and immobilization plant (WPT) will separate the waste into a small volume of high level waste (HLW), containing most of the radioactive constituents, and a larger volume of low activity waste (LAW), containing most of the non-radioactive chemical and hazardous constituents. The HLW and LAW will be converted into immobilized waste forms for disposal. Currently there is inadequate LAW vitrification capacity planned at the WTP to complete the mission within the required timeframe. Therefore additional LAW capacity is required. One candidate supplemental treatment technology is the fluidized bed steam reformer process (FBSR). This report describes the demonstration testing of the FBSR process using a mineralizing flowsheet for treating simulated Hanford LAW and secondary waste from the WTP (WTP SW). The FBSR testing project produced leach-resistant solid products and environmentally compliant gaseous effluents. The solid products incorporated normally soluble ions into an alkali alumino-silicate (NaS) mineral matrix. Gaseous emissions were found to be within regulatory limits. Cesium and rhenium were captured in the mineralized products with system removal efficiencies of 99.999% and 99.998 respectively. The durability and leach performance of the FBSR granular solid were superior to the low activity reference material (LMR) glass standards. Normalized product consistency test (PCT) release rates for constituents of concern were approximately 2 orders of magnitude less than that of sodium in the Hanford glass [standard].

  20. Molecular beam epitaxy of GaNAs alloys with high As content for potential photoanode applications in hydrogen production

    SciTech Connect (OSTI)

    Novikov, S. V.; Staddon, C. R.; Foxon, C. T.; Yu, K. M.; Broesler, R.; Hawkridge, M.; Liliental-Weber, Z.; Walukiewicz, W.; Denlinger, J.; Demchenko, I.

    2009-10-06T23:59:59.000Z

    The authors have succeeded in growing GaN1?xAsx alloys over a large composition range (0 < x < 0.8) by plasma-assisted molecular beam epitaxy. The enhanced incorporation of As was achieved by growing the films with high As{sub 2} flux at low (as low as 100 C) growth temperatures, which is much below the normal GaN growth temperature range. Using x-ray and transmission electron microscopy, they found that the GaNAs alloys with high As content x > 0.17 are amorphous. Optical absorption measurements together with x-ray absorption and emission spectroscopy results reveal a continuous gradual decrease in band gap from -3.4 to < 1 eV with increasing As content. The energy gap reaches its minimum of -0.8 eV at x - 0.8. The composition dependence of the band gap of the crystalline GaN{sub 1?x}As{sub x} alloys follows the prediction of the band anticrossing model (BAC). However, our measured band gap of amorphous GaN{sub 1?x}As{sub x} with 0.3 < x < 0.8 are larger than that predicted by BAC. The results seem to indicate that for this composition range the amorphous GaN{sub 1?x}As{sub x} alloys have short-range ordering that resembles random crystalline GaN{sub 1?x}As{sub x} alloys. They have demonstrated the possibility of the growth of amorphous GaN{sub 1?x}As{sub x} layers with variable As content on glass substrates

  1. DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER WASTE FORMS FOR SODIUM BEARING WASTE AT IDAHO NATIONAL LABORATORY

    SciTech Connect (OSTI)

    Crawford, C; Carol Jantzen, C

    2007-08-27T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) processing of Sodium Bearing Waste simulants was performed in December 2006 by THOR{sup sm} Treatment Technologies LLC (TTT) The testing was performed at the Hazen Research Inc. (HRI) pilot plant facilities in Golden, CO. FBSR products from these pilot tests on simulated waste representative of the SBW at the Idaho Nuclear Technology and Engineering Center (INTEC) were subsequently transferred to the Savannah River National Laboratory (SRNL) for characterization and leach testing. Four as-received Denitration and Mineralization Reformer (DMR) granular/powder samples and four High Temperature Filter (HTF) powder samples were received by SRNL. FBSR DMR samples had been taken from the ''active'' bed, while the HTF samples were the fines collected as carryover from the DMR. The process operated at high fluidizing velocities during the mineralization test such that nearly all of the product collected was from the HTF. Active bed samples were collected from the DMR to monitor bed particle size distribution. Characterization of these crystalline powder samples shows that they are primarily Al, Na and Si, with > 1 wt% Ca, Fe and K. The DMR samples contained less than 1 wt% carbon and the HTF samples ranged from 13 to 26 wt% carbon. X-ray diffraction analyses show that the DMR samples contained significant quantities of the Al{sub 2}O{sub 3} startup bed. The DMR samples became progressively lower in starting bed alumina with major Na/Al/Si crystalline phases (nepheline and sodium aluminosilicate) present as cumulative bed turnover occurred but 100% bed turnover was not achieved. The HTF samples also contained these major crystalline phases. Durability testing of the DMR and HTF samples using the ASTM C1285 Product Consistency Test (PCT) 7-day leach test at 90 C was performed along with several reference glass samples. Comparison of the normalized leach rates for the various DMR and HTF components was made with the reference glasses and the Low Activity Waste (LAW) specification for the Hanford Waste Treatment and Vitrification Plant (WTP). Normalized releases from the DMR and HTF samples were all less than 1 g/m{sup 2}. For comparison, normalized release from the High-Level Waste (HLW) benchmark Environmental Assessment (EA) glass for Si, Li, Na and B ranges from 2 to 8 g/m{sup 2}. The normalized release specification for LAW glass for the Hanford WTP is 2 g/m{sup 2}. The Toxicity Characteristic Leach Test (TCLP) was performed on DMR and HTF as received samples and the tests showed that these products meet the criteria for the EPA RCRA Universal Treatment Standards for all of the constituents contained in the starting simulants such as Cr, Pb and Hg (RCRA characteristically hazardous metals) and Ni and Zn (RCRA metals required for listed wastes).

  2. My Documents\\Presentations\\IFE\\NAS\\JCF_IFE_NAS_LANL_V4Operated by Los Alamos National Security, LLC for the U.S. Department of Energy's NNSA U N C L A S S I F I E D Slide 1

    E-Print Network [OSTI]

    for the U.S. Department of Energy's NNSA U N C L A S S I F I E D Slide 1 Prospects for Inertial Fusion\\Presentations\\IFE\\NAS\\JCF_IFE_NAS_LANL_V4Operated by Los Alamos National Security, LLC for the U.S. Department of Energy's NNSA U N C L, LLC for the U.S. Department of Energy's NNSA U N C L A S S I F I E D Slide 3 LANL fully supports

  3. CX-004176: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Making Nepheline (NaAlSiO4), Phase Pure StandardsCX(s) Applied: B3.6Date: 09/23/2010Location(s): Aiken, South CarolinaOffice(s): Environmental Management, Savannah River Operations Office

  4. nas82d5.tmp

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , (Energy97 UpperJointmoveLINQnalmsnarac |

  5. Emergency services to conduct laboratory research concerning appropriate additions at NAS Patuxent River Fuel Farm in-situ bioreclamation. Final report, Apr 87-Sep 89

    SciTech Connect (OSTI)

    Watts, R.J.; McGuire, P.N.

    1992-06-01T23:59:59.000Z

    The effect of total petroleum hydrocarbon (TPH) concentration on the biological treatment of contaminated soils collected from NAS Patuxent River, MD fuel farm was investigated in closed-shake flasks as a basis for future full-scale in situ biological treatment. Soil samples with a TPH concentration of 2,000 mg/Kg were mixed with uncontaminated sand to provide a concentration gradient from 180 to 1,570 mg/Kg TPH. Biological treatment experiments resulted in degradation of hydrocarbons to below detectable levels within 61 days for samples with TPH concentrations of = or < 490 mg/ Kg. In samples with TPH concentrations of = or >830 mg/Kg, biological treatment resulted in minimal TPH loss over the study period. Specific substrate utilization rates decreased and specific growth rates were not significantly different with increasing TPH concentrations. The data show that microbial growth processes during the logarithmic growth phase were not inhibited at higher TPH concentrations. However, mass transfer limitations and/or toxicity from metabolities formed during logarithmic growth may have caused a decline in microbial numbers resulting in undegraded petroleum residuals in the systems with initial TPH concentrations of = or >830 mg/Kg. In an attempt to increase biological degradation rates, soil samples with an initial TPH concentration of 2,000 mg/Kg were amended with methanol. Treatment with the added methanol resulted in greater TPH degradation over a 34-day period relative to control treatments. Venting of sand and peat soils was investigated to assess the amount of hydrocarbons removed from the vadose zone.

  6. --No Title--

    Broader source: Energy.gov (indexed) [DOE]

    A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on SRS Low Activity Waste (LAW) modified to simulate Hanford waste....

  7. UESC Success Stories at NAS Pensacola

    Broader source: Energy.gov [DOE]

    Presentation covers utility energy service contract (UESC) success stories at Naval Facilities Engineering Command (NAVFAC) Southeast PWD given at the Federal Utility Partnership Working Group (FUPWG) Spring 2008 meeting in Destin, Florida.

  8. Response to Questions on Presentation to NAS

    SciTech Connect (OSTI)

    Meier, W R

    2011-03-17T23:59:59.000Z

    Response to questions on the presentation 'Overview to Chamber and Power Plant Designs for IFE' made at the 1/29-31 meeting of the National Academies Committee on the Prospects for Inertial Confinement Fusion Energy Systems.

  9. EEG Response to NAS WIPP Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField Campaign:INEA :Work with E=mc2 - What's the Speed ofEnergyCool Down |EEG

  10. Mobilizing aluminum in crustal and mantle fluids Craig E. Manning

    E-Print Network [OSTI]

    Manning, Craig

    Mobilizing aluminum in crustal and mantle fluids Craig E. Manning Department of Earth and Space December 2005 Available online 9 March 2006 Abstract Aluminum is a major rock-forming element, but its low by formation of polynuclear NaAlSiO clusters and/or polymers. Aluminum should not be assumed to be immobile

  11. SUMMARY PLAN FOR BENCH-SCALE REFORMER AND PRODUCT TESTING TREATABILITY STUDIES USING HANFORD TANK WASTE

    SciTech Connect (OSTI)

    ROBBINS RA

    2011-02-11T23:59:59.000Z

    This paper describes the sample selection, sample preparation, environmental, and regulatory considerations for shipment of Hanford radioactive waste samples for treatability studies of the FBSR process at the Savannah River National Laboratory and the Pacific Northwest National Laboratory.

  12. DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST

    SciTech Connect (OSTI)

    BANNING DL

    2010-08-03T23:59:59.000Z

    This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required. The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.

  13. Summary - Savannah River Site Tank 48H Waste Treatment Project

    Office of Environmental Management (EM)

    ng (FBSR). Th deciding which ng the Tank 48 he TRA Team m determined t ts (CTEs) and t ess Level (TRL) on Process: stem (TRL3) atment System RA reports, please v govPages...

  14. --No Title--

    Broader source: Energy.gov (indexed) [DOE]

    This work (Module A) involves performing the fluidized bed steam reforming (FBSR) process on caustic DWPF Offgas Condensate Tank (OGCT) in SRNL HLC, A-block. The DWPF OGCT...

  15. alta resolucao nas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de Computacion Cientifica y Programacion Paralela http:luna.inf.um.esgrupo investigacion San Alberto, 14 noviembre 2014 Computacion de Altas Prestaciones San...

  16. Kathy Yelick Appointed to NAS Computer Science and Telecommunications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Appointed to National Academies Computer Science and Telecommunications Board Kathy Yelick Appointed to National Academies Computer Science and Telecommunications Board September...

  17. area rural nas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (PVSSWTP) based on technologies that can be transferred. KeywordsRenewable energy sources, Photovoltaic, small-scale projects, wastewater treatment. I. Fadia M. A. Ghali 20 37...

  18. automation system nas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ioannou A, utomatic is todesign and test avehicle control system in order toachieve full vehicle automation in the longitudinal vehicle following isan important feature of a fully...

  19. HPC Symposium, NAS 2008R. L. Winslow Raimond L. Winslow

    E-Print Network [OSTI]

    Winslow, Raimond

    -scale) Cell (Meso-scale) Integrative Modeling of the Heart: The Challenge Molecular Biology Cell Biology

  20. Negociao-Colaborao nas Revises Tcnicas Formais de Especificaes Funcionais

    E-Print Network [OSTI]

    Antunes, Pedro

    processo de negociação-colaboração e propõe o aperfeiçoamento do apoio metodológico e computacional ao

  1. alto impacto nas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    North & South Exit Sand Hill Road east toward Stanford Straight, Aaron 2 EVALUACIN DEL IMPACTO AMBIENTAL Environmental Sciences and Ecology Websites Summary: EVALUACI?N DEL...

  2. ambiente nas cidades: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions using ambient air quality data Mulholland, James A. 8 EVALUACIN DEL IMPACTO AMBIENTAL Environmental Sciences and Ecology Websites Summary: EVALUACI?N DEL...

  3. Comparison of leading parallel NAS file systems on commodity hardware

    SciTech Connect (OSTI)

    Hedges, R; Fitzgerald, K; Gary, M; Stearman, D M

    2010-11-08T23:59:59.000Z

    High performance computing has experienced tremendous gains in system performance over the past 20 years. Unfortunately other system capabilities, such as file I/O, have not grown commensurately. In this activity, we present the results of our tests of two leading file systems (GPFS and Lustre) on the same physical hardware. This hardware is the standard commodity storage solution in use at LLNL and, while much smaller in size, is intended to enable us to learn about differences between the two systems in terms of performance, ease of use and resilience. This work represents the first hardware consistent study of the two leading file systems that the authors are aware of.

  4. Kathy Yelick Appointed to NAS Computer Science and Telecommunications Board

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as ReadyAppointed to National Academies Computer

  5. NAS Report and Microsite Trace SSL Evolution and Future Promise |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaeferApril 1,(EAC)TABLE OFDepartmentTechno-economicNARUC Cybersecurity

  6. Radioactive Demonstration Of Mineralized Waste Forms Made From Hanford Low Activity Waste (Tank SX-105 And AN-103) By Fluidized Bed Steam Reformation

    SciTech Connect (OSTI)

    Jantzen, Carol; Herman, Connie; Crawford, Charles; Bannochie, Christopher; Burket, Paul; Daniel, Gene; Cozzi, Alex; Nash, Charles; Miller, Donald; Missimer, David

    2014-01-10T23:59:59.000Z

    One of the immobilization technologies under consideration as a Supplemental Treatment for Hanfords Low Activity Waste (LAW) is Fluidized Bed Steam Reforming (FBSR). The FBSR technology forms a mineral waste form at moderate processing temperatures thus retaining and atomically bonding the halides, sulfates, and technetium in the mineral phases (nepheline, sodalite, nosean, carnegieite). Additions of kaolin clay are used instead of glass formers and the minerals formed by the FBSR technology offers (1) atomic bonding of the radionuclides and constituents of concern (COC) comparable to glass, (2) short and long term durability comparable to glass, (3) disposal volumes comparable to glass, and (4) higher Na2O and SO{sub 4} waste loadings than glass. The higher FBSR Na{sub 2}O and SO{sub 4} waste loadings contribute to the low disposal volumes but also provide for more rapid processing of the LAW. Recent FBSR processing and testing of Hanford radioactive LAW (Tank SX-105 and AN-103) waste is reported and compared to previous radioactive and non-radioactive LAW processing and testing.

  7. Steam Reforming, 6-in. Bench-Scale Design and Testing Project -- Technical and Functional Requirements Description

    SciTech Connect (OSTI)

    Losinski, Sylvester John; Marshall, Douglas William

    2002-08-01T23:59:59.000Z

    Feasibility studies and technology development work are currently being performed on several processes to treat radioactive liquids and solids currently stored at the Idaho Nuclear Technology and Engineering Center (INTEC), located within the Idaho National Engineering and Environmental Laboratory (INEEL). These studies and development work will be used to select a treatment process for treatment of the radioactive liquids and solids to meet treatment milestones of the Settlement Agreement between the Department of Energy and the State of Idaho. One process under consideration for treating the radioactive liquids and solids, specifically Sodium-Bearing Waste (SBW) and tank heel solids, is fluid bed steam reforming (FBSR). To support both feasibility and development studies a bench-scale FBSR is being designed and constructed. This report presents the technical and functional requirements, experimental objectives, process flow sheets, and equipment specifications for the bench-scale FBSR.

  8. Thermoelectric and electrical characterization of Si nanowires and GaNAs

    E-Print Network [OSTI]

    Pichanusakorn, Paothep

    2012-01-01T23:59:59.000Z

    1.1.2 Peltier and Thompson effects . . . . . . . . . . 1.2and (b) Peltier cooler. . . . . . . . . . . . . . .leading to larger |S|. Peltier and Thompson effects The

  9. NAS-NAE National Convocation on "Rising Above the Gathering Storm...

    Energy Savers [EERE]

    developing and deploying renewable energy technologies . . . to producing conventional fossil fuels more cleanly . . . to increasing our energy efficiency - our basic research...

  10. Thermoelectric and electrical characterization of Si nanowires and GaNAs

    E-Print Network [OSTI]

    Pichanusakorn, Paothep

    2012-01-01T23:59:59.000Z

    2400 source-measure unit (SMU). ?, n, , and S can all beat a fixed voltage with the SMU to generates a temperature

  11. E-Print Network 3.0 - agulha fina nas Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Source: Escolano, Francisco - Departamento de Ciencia de la Computacin e Inteligencia Artificial, Universitat d'Alacant Collection: Engineering Page: << < 1 2 3 4 5 > >> Page:...

  12. Crdito e Confiana: a influncia das normas sociais nas relaes de crdito

    E-Print Network [OSTI]

    Flores Filho, Edgar Gastn Jacobs; Lopes, Lucas Miotto

    2009-01-01T23:59:59.000Z

    of Brazil. MIT Press, 2005. BRASIL. Cdigo Civil. So Paulo:da Repblica Federativa do Brasil. Braslia: Senado, 2006.na Nota do Banco Central do Brasil de 25-08-2008). Edio de

  13. Thermoelectric and electrical characterization of Si nanowires and GaNAs

    E-Print Network [OSTI]

    Pichanusakorn, Paothep

    2012-01-01T23:59:59.000Z

    1 Introduction to Thermoelectric phenomena and theory . . .1.1 Thermoelectric139 5.1.1 Thermoelectric application for highly-mismatch

  14. NAS battery demonstration at American Electric Power:a study for the DOE energy storage program.

    SciTech Connect (OSTI)

    Newmiller, Jeff (Endecon Engineering, San Ramon, CA); Norris, Benjamin L. (Norris Energy Consulting Company, Martinez, CA); Peek, Georgianne Huff

    2006-03-01T23:59:59.000Z

    The first U.S. demonstration of the NGK sodium/sulfur battery technology was launched in August 2002 when a prototype system was installed at a commercial office building in Gahanna, Ohio. American Electric Power served as the host utility that provided the office space and technical support throughout the project. The system was used to both reduce demand peaks (peak-shaving operation) and to mitigate grid power disturbances (power quality operation) at the demonstration site. This report documents the results of the demonstration, provides an economic analysis of a commercial sodium/sulfur battery energy storage system at a typical site, and describes a side-by-side demonstration of the capabilities of the sodium/sulfur battery system, a lead-acid battery system, and a flywheel-based energy storage system in a power quality application.

  15. SEAB MEMORANDUM ON NAS REPORT, ALIGNING THE GOVERNANCE STRUCTURE OF THE

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you sure you wantJoin us for| DepartmentReduce Hot WaterReviewsCharter SEABNNSA

  16. NAS-NAE National Convocation on "Rising Above the Gathering Storm Two Years

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China 2015of 2005 attheMohammed Khan - Technology ProjectEnergyNAICS Codes

  17. NAS-NAE National Convocation on "Rising Above the Gathering Storm Two Years

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in Many Devils Wash, Shiprock, New Mexico |MyriantSafetyLater:

  18. Two-Meter Temperature Surveys for Geothermal Exploration Project at NAS

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTown of Ladoga, IndianaTurtle Airships Jump to:TwiggsJemez

  19. BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE

    SciTech Connect (OSTI)

    Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

    2008-09-25T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The radioactive Tank 48H DMR product was primarily made up of soluble carbonates. The three most abundant species were thermonatrite, [Na{sub 2}CO{sub 3} {center_dot} H{sub 2}O], sodium carbonate, [Na{sub 2}CO{sub 3}], and trona, [Na{sub 3}H(CO{sub 3}){sub 2} {center_dot} 2H{sub 2}O] the same as the ESTD FBSR. (6) Insoluble solids analyzed by X-Ray Diffraction (XRD) did not detect insoluble carbonate species. However, they still may be present at levels below 2 wt%, the sensitivity of the XRD methodology. Insoluble solids XRD characterization indicated that various Fe/Ni/Cr/Mn phases are present. These crystalline phases are associated with the insoluble sludge components of Tank 48H slurry and impurities in the Erwin coal ash. The percent insoluble solids, which mainly consist of un-burnt coal and coal ash, in the products were 4 to 11 wt% for the radioactive runs. (7) The Fe{sup +2}/Fe{sub total} REDOX measurements ranged from 0.58 to 1 for the three radioactive Bench-scale tests. REDOX measurements > 0.5 showed a reducing atmosphere was maintained in the DMR indicating that pyrolysis was occurring. (8) Greater than 90% of the radioactivity was captured in the product for all three runs. (9) The collective results from the FBSR simulant tests and the BSR simulant tests indicate that the same chemistry occurs in the two reactors. (10) The collective results from the BSR simulant runs and the BSR radioactive waste runs indicates that the same chemistry occurs in the simulant as in the real waste. The FBSR technology has been proven to destroy the organics and nitrates in the Tank 48H waste and form the anticipated solid carbonate phases as expected.

  20. DWPF COAL CARBON WASTE ACCEPTANCE CRITERIA LIMIT EVALUATION

    SciTech Connect (OSTI)

    Lambert, D.; Choi, A.

    2010-06-21T23:59:59.000Z

    A paper study was completed to assess the impact on the Defense Waste Processing Facility (DWPF)'s Chemical Processing Cell (CPC) acid addition and melter off-gas flammability control strategy in processing Sludge Batch 10 (SB10) to SB13 with an added Fluidized Bed Steam Reformer (FBSR) stream and two Salt Waste Processing Facility (SWPF) products (Strip Effluent and Actinide Removal Stream). In all of the cases that were modeled, an acid mix using formic acid and nitric acid could be achieved that would produce a predicted Reducing/Oxidizing (REDOX) Ratio of 0.20 Fe{sup +2}/{Sigma}Fe. There was sufficient formic acid in these combinations to reduce both the manganese and mercury present. Reduction of manganese and mercury are both necessary during Sludge Receipt and Adjustment Tank (SRAT) processing, however, other reducing agents such as coal and oxalate are not effective in this reduction. The next phase in this study will be experimental testing with SB10, FBSR, and both SWPF simulants to validate the assumptions in this paper study and determine whether there are any issues in processing these streams simultaneously. The paper study also evaluated a series of abnormal processing conditions to determine whether potential abnormal conditions in FBSR, SWPF or DWPF would produce melter feed that was too oxidizing or too reducing. In most of the cases that were modeled with one parameter at its extreme, an acid mix using formic acid and nitric acid could be achieved that would produce a predicted REDOX of 0.09-0.30 (target 0.20). However, when a run was completed with both high coal and oxalate, with minimum formic acid to reduce mercury and manganese, the final REDOX was predicted to be 0.49 with sludge and FBSR product and 0.47 with sludge, FBSR product and both SWPF products which exceeds the upper REDOX limit.

  1. Vitrification and chemical durability of simulated high-level nuclear waste glasses with high concentrations of Cr{sub 2}O{sub 3} and Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Li, H.; Hrma, P.; Langowski, M.H. [Pacific Northwest Lab., Richland, WA (United States)] [and others

    1996-12-31T23:59:59.000Z

    Borosilicate glasses were loaded with 30 to 55 wt% of simulated high-level tank waste, rich in Cr{sub 2}O{sub 3} and Al{sub 2}O{sub 3}, obtained from Hanford Site (Richland, Washington). No segregated chromate was observed on molten glass at the melting temperature. Eskolaite (Cr{sub 2}O{sub 3} with iron) and chromite (FeCr{sub 2}O{sub 4}) crystals were found in all quenched glasses. At waste loadings {ge}50 wt%, nephelme (NaAlSiO{sub 4}) and beta-eucryptite ({beta}-LiAlSiO{sub 4}) became major crystalline phases. Precipitation of these phases decreased melt viscosity and glass corrosion resistance.

  2. Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 1, 196203 Symmetries of Differential Equations

    E-Print Network [OSTI]

    Popovych, Roman

    , Snezhinsk, Chelyabinsk Region, Russia E-mail: morozov@sfti.snz.ru Applications of Cartan's equivalence

  3. Proceedings of Institute of Mathematics of NAS of Ukraine 2000, Vol. 30, Part 1, 239244. On Invariant Wave Patterns

    E-Print Network [OSTI]

    Popovych, Roman

    substances ­ concrete, air- liquid mixtures, polymers and so on. When studying high-speed high-frequency) sound velocity, is the time of relaxation, is equal to the square of frozen (high-frequency) sound

  4. Molecular beam epitaxy of GaNAs alloys with high As content for potential photoanode applications in hydrogen production

    E-Print Network [OSTI]

    Novikov, S. V.

    2011-01-01T23:59:59.000Z

    photoanode applications in hydrogen production S. V.of sunlight into hydrogen by pho- toelectrochemical ͑PEC͒is crucial for efficient hydrogen production using the PEC

  5. Applying MPI Derived Datatypes to the NAS Benchmarks: A Case Study Qingda Lu Jiesheng Wu Dhabaleswar Panda P. Sadayappan

    E-Print Network [OSTI]

    Panda, Dhabaleswar K.

    by Department of Energy's Grant #DE-FC02-01ER25506, and National Science Foundation's grants #EIA- 9986052, #CCR Dhabaleswar Panda P. Sadayappan Computer and Information Science, The Ohio State University luq, wuj, panda evolved as a de facto parallel programming model for distributed memory systems. As one of its most impor

  6. Proceedings of Institute of Mathematics of NAS of Ukraine 2002, Vol. 43, Part 2, 774776 "Leonard Pairs" in Classical Mechanics

    E-Print Network [OSTI]

    Popovych, Roman

    ]). Terwilliger showed [5, 10] that a Leonard pair X, Y satisfies a certain algebraic relations with respect to commutators. In turn, the Terwilliger relations follow from to the so-called relations of the AW

  7. Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 1, 6976 Bogoyavlenskij Symmetries of Isotropic

    E-Print Network [OSTI]

    Popovych, Roman

    but are not limited to the problem of controlled thermonuclear fusion, astrophysical applications (star formation

  8. Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 3, 14151422 Visualisation and Animation

    E-Print Network [OSTI]

    Popovych, Roman

    of Science and Mathematics, University of Nis, Visegradska 33, 18000 Nis, Serbia and Montenegro E-mail: ema to Wulff's principle [10], the shape of a crystal is uniquely defined by its surface energy function. A surface energy function is a real-valued function depending on a direction in space. Let Bn denote

  9. Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

    2012-05-01T23:59:59.000Z

    The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

  10. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    SciTech Connect (OSTI)

    DUNCAN JB; HUBER HJ

    2011-04-21T23:59:59.000Z

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.

  11. DWPF COAL-CARBON WASTE ACCEPTANCE CRITERIA LIMIT EVALUATION BASED ON EXPERIMENTAL WORK (TANK 48 IMPACT STUDY)

    SciTech Connect (OSTI)

    Lambert, D.; Choi, A.

    2010-10-15T23:59:59.000Z

    This report summarizes the results of both experimental and modeling studies performed using Sludge Batch 10 (SB10) simulants and FBSR product from Tank 48 simulant testing in order to develop higher levels of coal-carbon that can be managed by DWPF. Once the Fluidized Bed Steam Reforming (FBSR) process starts up for treatment of Tank 48 legacy waste, the FBSR product stream will contribute higher levels of coal-carbon in the sludge batch for processing at DWPF. Coal-carbon is added into the FBSR process as a reductant and some of it will be present in the FBSR product as unreacted coal. The FBSR product will be slurried in water, transferred to Tank Farm and will be combined with sludge and washed to produce the sludge batch that DWPF will process. The FBSR product is high in both water soluble sodium carbonate and unreacted coal-carbon. Most of the sodium carbonate is removed during washing but all of the coal-carbon will remain and become part of the DWPF sludge batch. A paper study was performed earlier to assess the impact of FBSR coal-carbon on the DWPF Chemical Processing Cell (CPC) operation and melter off-gas flammability by combining it with SB10-SB13. The results of the paper study are documented in Ref. 7 and the key findings included that SB10 would be the most difficult batch to process with the FBSR coal present and up to 5,000 mg/kg of coal-carbon could be fed to the melter without exceeding the off-gas flammability safety basis limits. In the present study, a bench-scale demonstration of the DWPF CPC processing was performed using SB10 simulants spiked with varying amounts of coal, and the resulting seven CPC products were fed to the DWPF melter cold cap and off-gas dynamics models to determine the maximum coal that can be processed through the melter without exceeding the off-gas flammability safety basis limits. Based on the results of these experimental and modeling studies, the presence of coal-carbon in the sludge feed to DWPF is found to have both positive (+) and negative (-) impact as summarized below: (-) Coal-carbon is a melter reductant. If excess coal-carbon is present, the resulting melter feed may be too reducing, potentially shortening the melter life. During this study, the Reduction/Oxidation Potential (REDOX) of the melter could be controlled by varying the ratio of nitric and formic acid. (-) The addition of coal-carbon increases the amount of nitric acid added and decreases the amount of formic acid added to control melter REDOX. This means that the CPC with the FBSR product is much more oxidizing than current CPC processing. In this study, adequate formic acid was present in all experiments to reduce mercury and manganese, two of the main goals of CPC processing. (-) Coal-carbon will be oxidized to carbon dioxide or carbon monoxide in the melter. The addition of coal-carbon to the FBSR product will lead to approximately 55% higher offgas production from formate, nitrate and carbon due to the decomposition of the carbon at the maximum levels in this testing. Higher offgas production could lead to higher cold cap coverage or melter foaming which could decrease melt rate. No testing was performed to evaluate the impact of the higher melter offgas flow. (+) The hydrogen production is greatly reduced in testing with coal as less formic acid is added in CPC processing. In the high acid run without coal, the peak hydrogen generation was 15 times higher than in the high acid run with added coal-carbon. (+) Coal-carbon is a less problematic reducing agent than formic acid, since the content of both carbon and hydrogen are important in evaluating the flammability of the melter offgas. Processing with coal-carbon decreases the amount of formic acid added in the CPC, leading to a lower flammability risk in processing with coal-carbon compared to the current DWPF flowsheet. (+) The seven SB10 formulations which were tested during the bench-scale CPC demonstration were all determined to be within the off-gas flammability safety basis limits during the 9X/5X off-gas surge for normal bubbled melter

  12. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02T23:59:59.000Z

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  13. JET MIXING ANALYSIS FOR SRS HIGH-LEVEL WASTE RECOVERY

    SciTech Connect (OSTI)

    Lee, S.

    2011-07-05T23:59:59.000Z

    The process of recovering the waste in storage tanks at the Savannah River Site (SRS) typically requires mixing the contents of the tank to ensure uniformity of the discharge stream. Mixing is accomplished with one to four slurry pumps located within the tank liquid. The slurry pump may be fixed in position or they may rotate depending on the specific mixing requirements. The high-level waste in Tank 48 contains insoluble solids in the form of potassium tetraphenyl borate compounds (KTPB), monosodium titanate (MST), and sludge. Tank 48 is equipped with 4 slurry pumps, which are intended to suspend the insoluble solids prior to transfer of the waste to the Fluidized Bed Steam Reformer (FBSR) process. The FBSR process is being designed for a normal feed of 3.05 wt% insoluble solids. A chemical characterization study has shown the insoluble solids concentration is approximately 3.05 wt% when well-mixed. The project is requesting a Computational Fluid Dynamics (CFD) mixing study from SRNL to determine the solids behavior with 2, 3, and 4 slurry pumps in operation and an estimate of the insoluble solids concentration at the suction of the transfer pump to the FBSR process. The impact of cooling coils is not considered in the current work. The work consists of two principal objectives by taking a CFD approach: (1) To estimate insoluble solids concentration transferred from Tank 48 to the Waste Feed Tank in the FBSR process and (2) To assess the impact of different combinations of four slurry pumps on insoluble solids suspension and mixing in Tank 48. For this work, several different combinations of a maximum of four pumps are considered to determine the resulting flow patterns and local flow velocities which are thought to be associated with sludge particle mixing. Two different elevations of pump nozzles are used for an assessment of the flow patterns on the tank mixing. Pump design and operating parameters used for the analysis are summarized in Table 1. The baseline pump orientations are chosen by the previous work [Lee et. al, 2008] and the initial engineering judgement for the conservative flow estimate since the modeling results for the other pump orientations are compared with the baseline results. As shown in Table 1, the present study assumes that each slurry pump has 900 gpm flowrate for the tank mixing analysis, although the Standard Operating Procedure for Tank 48 currently limits the actual pump speed and flowrate to a value less than 900 gpm for a 29 inch liquid level. Table 2 shows material properties and weight distributions for the solids to be modeled for the mixing analysis in Tank 48.

  14. CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101/102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER

    SciTech Connect (OSTI)

    DUNCAN JB; HUBER HJ

    2011-06-08T23:59:59.000Z

    This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'

  15. Performance of the Fluidized Bed Steam Reforming product under hydraulically unsaturated conditions

    SciTech Connect (OSTI)

    Neeway, James J [ORNL] [ORNL; Rod, Kenton A. [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Bowden, Mark E [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Pierce, Eric M [ORNL] [ORNL; Qafoku, Nikolla [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Williams, Benjamin D [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Brown, Christopher F [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL)

    2014-01-01T23:59:59.000Z

    Several candidates for supplemental low-activity waste (LAW) immobilization at the Hanford site in Washington State, USA are being considered. One waste sequestering technology considered is Fluidized Bed Steam Reforming (FBSR). The granular product resulting from the FBSR process is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals with a 1:1:1 molar ratio of Na, Al and Si. To demonstrate the durability of the product, which can be disposed of at the unsaturated Integrated Disposal Facility (IDF) at Hanford, a series of tests has been performed using the Pressurized Unsaturated Flow (PUF) system, which allows for the accelerated weathering of the solid materials. The system maintains hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that will be present at the IDF. Two materials were tested using the system: 1) the FBSR granular product and 2) the FBSR granular product encapsulated in a geopolymer to form a monolith. Results of the experiments show a trend of relatively constant effluent concentration of Na, Si, Al, and Cs as a function of time from both materials. The elements I and Re show a steady release throughout the yearlong test from the granular material but their concentrations seem to be increasing at one year from the monolith material. This result suggests that these two elements may be present in the sodalite cage structure rather than in the predominant nepheline phase because their release occurs at a different rate compared to nepheline phase. Also, these elements to not seem to reprecipitate when released from the starting material. Calculated one-year release rates for Si are on the order of 10 6 g/(m2 d) for the granular material and 10 5 g/(m2 d) for the monolith material while Re release is seen to be two orders of magnitude higher than Si release rates. SEM imaging and XRD analysis show how the alteration of the two materials is dependent on their depth in the column. This phenomenom is a result of depth-dependent solution concentrations giving rise chemical environments that may be supersaturated with respect to a number of mineral phases.

  16. Proceedings of Institute of Mathematics of NAS of Ukraine 2002, Vol. 43, Part 1, 339343 High-Frequency Absorption by a Soliton Gas

    E-Print Network [OSTI]

    Popovych, Roman

    -Frequency Absorption by a Soliton Gas in One-Dimensional Magnet Galyna OKSYUK Institute for Low Temperature Physics & Engineering, 47 Lenin Ave., Kharkov 61103, Ukraine E-mail: oksyuk@ilt.kharkov.ua The additional mechanism for some values of the external magnetic field. The quantity of the effect is detectable. 1 Introduction We

  17. Proceedings of Institute of Mathematics of NAS of Ukraine 2002, Vol. 43, Part 1, 111119 Some Invariant Solutions of the SavageHutter Model

    E-Print Network [OSTI]

    Popovych, Roman

    sliding friction with basal angle of friction and gradients of the basal topography height, b, above-dimensional parameter = L/R. The function = K cos , (4) where the earth pressure coefficient K was proposed to take function or a constant earth pressure coefficient is more realistic. In this paper it is therefore assumed

  18. December 1415, 2007 Meeting BOARD ON PHYSICS AND ASTRONOMY Tel 202-334-3520 Fax 202-334-3575 E-mail bpa@nas.edu

    E-Print Network [OSTI]

    Japanese participation in ITER and research plans S. Matsuda, Japan Atomic Energy Agency 3:00 pm Break 3 Activities of the U.S. BPO long-range burning plasma program strategy subcommittee E. Marmar, MIT 5:00 pm U.S. engagement in ITER technology research S. Milora, ORNL 5:45 pm Adjourn #12;6:30 pm Working dinner at local

  19. Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 3, 13901395 Numerical Simulation of Replacing Oil by Water

    E-Print Network [OSTI]

    Popovych, Roman

    1395 Numerical Simulation of Replacing Oil by Water in a Scale-Invariant Porous Medium Ekaterina P. KUROCHKINA with 2563 grid in spatial variables. 1 Introduction The interface of oil displaced by water is unstable a significant influence on the transport of water and oil. The permeability heterogenei- ty is often identified

  20. Proceedings of Institute of Mathematics of NAS of Ukraine 2004, Vol. 50, Part 1, 374381 On Construction of Zero-Curvature Representations

    E-Print Network [OSTI]

    Popovych, Roman

    + bwe- 2u , (3a) f = av2 e2u + bw2 e-2u , (3b) f = av2 e2u + bwe-u , (3c) f = aveu + bwe-u , (3d) f to these functions have the following forms utx = 2 ave 2u - bwe- 2u , vtx = b-1 e- 2u + wvxvt, wtx = a-1 e 2u + vwxwt, (4) and utx = aveu - bwe-u , vtx = b-1 e-u + wvtvx, wtx = a-1 eu + vwtwx. (5) It was shown in [3

  1. Performance of the Fluidized Bed Steam Reforming Product Under Hydraulically Unsaturated Conditions

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Rod, Kenton A.; Bowden, Mark E.; Brown, Christopher F.; Pierce, Eric M.

    2014-05-01T23:59:59.000Z

    Currently, several candidates for secondary waste immobilization at the Hanford site in the State of Washington, USA are being considered. To demonstrate the durability of the product in the unsaturated Integrated Disposal Facility (IDF) at the site, a series of tests have been performed one of the candidate materials using the Pressurized Unsaturated Flow (PUF) system. The material that was tested was the Fluidized Bed Steam Reformer (FBSR) granular product and the granular product encapsulated in a geopolymer matrix. The FBSR product is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals mostly nepheline, sodalite, and nosean. The PUF test method allows for the accelerated weathering of materials, including radioactive waste forms, under hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that most likely will be present at the IDF. The experiments show a trend of decreasing tracer release as a function of time for several of the elements released from the material including Na, Si, Al, and Cs. However, some of the elements, notably I and Re, show a steady release throughout the yearlong test. This result suggests that the release of these minerals from the sodalite cage occurs at a different rate compared with the dissolution of the predominant nepheline phase.

  2. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24T23:59:59.000Z

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  3. STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138

    SciTech Connect (OSTI)

    Burket, P

    2009-02-24T23:59:59.000Z

    This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

  4. Chemical and Hydrostatic Pressure in Natrolites: Pressure Induced Hydration of an Aluminogermanate Natrolite

    SciTech Connect (OSTI)

    Lee, Y.; Kao, C.; Seoung,D.H.,Bai,J., Kao,C.C.; Parise,J.B.; Vogt, T.

    2010-09-24T23:59:59.000Z

    The ambient structure and pressure-induced structural changes of a synthetic sodium aluminogermanate with a natrolite (NAT) framework topology (Na-AlGe-NAT) were characterized by using Rietveld refinements of high-resolution synchrotron X-ray powder diffraction data at ambient and high pressures. Unlike a previously established model for Na{sub 8}Al{sub 8}Ge{sub 12}O{sub 40} {center_dot} 8H{sub 2}O based on a single-crystal study, the ambient structure of the Na-AlGe-NAT is found to adopt a monoclinic space group Cc (or Fd) with a ca. 6% expanded unit cell. The refined ambient structure of Na{sub 8}Al{sub 8}Ge{sub 12}O{sub 40} {center_dot} 12H{sub 2}O indicates an increased water content of 50%, compared to the single-crystal structure. The unit-cell volume and water-content relationships observed between the two Na-AlGe-NAT structures at ambient conditions with 8 and 12 H{sub 2}O respectively seem to mirror the ones found under hydrostatic pressure between the Na{sub 8}Al{sub 8}Ge{sub 12}O{sub 40} {center_dot} 8H{sub 2}O and the parantrolite phase Na{sub 8}Al{sub 8}Ge{sub 12}O{sub 40} {center_dot} 12H{sub 2}O. Under hydrostatic pressures mediated by a pore-penetrating alcohol and water mixture, the monoclinic Na-AlGe-NAT exhibits a gradual decrease of the unit-cell volume up to ca. 2.0 GPa, where the unit-cell volume then contracts abruptly by ca. 4.6%. This is in marked contrast to what is observed in the Na-AlSi-NAT and Na-GaSi-NAT systems, where one observes a pressure-induced hydration and volume expansion due to the auxetic nature of the frameworks. Above 2 GPa, the monoclinic phase of Na-AlGe-NAT transforms into a tetragonal structure with the unit-cell composition of Na{sub 8}Al{sub 8}Ge{sub 12}O{sub 40} {center_dot} 16H{sub 2}O, revealing pressure-induced hydration and a unit cell volume contraction. Unlike in the Na-Al,Si-paranatrolite phase, however, the sodium cations in the Na-AlGe-NAT maintain a 6-fold coordination in the monoclinic structure and only become 7-fold coordinated at higher pressures in the tetragonal structure. When comparing the pressure-induced hydration in the observed natrolite-type zeolites, Na-AlGe-NAT appears to have a nonauxetic framework and reveals the highest onset pressure for complete superhydration.

  5. To appear in, Proc. of NAS Workshop on Assessing the Economic Impacts of Climate Change, April 2010, and special issue of, Energy Economics Uncertainties in Technology Experience Curves for

    E-Print Network [OSTI]

    , and special issue of, Energy Economics Uncertainties in Technology Experience Curves for Energy curves) relating reductions in the unit cost of energy and environmental technologies to their cumulative: Experience curve, learning curve, learning-by-doing, uncertainties, endogenous technological change, energy

  6. Two Ohio State researchers elected to National Academy of Sciences Two Ohio State professors have been elected to the National Academy of Sciences (NAS), one of the most prestigious

    E-Print Network [OSTI]

    Henkin, professor and chair of microbiology and the Robert W. and Estelle S. Bingham Professor-effective replacement for precious metal cathodes in batteries and fuels. Award celebrates research that improves health

  7. Effects of alteration product precipitation on glass dissolution

    SciTech Connect (OSTI)

    Strachan, Denis M.; Neeway, James J.

    2014-04-02T23:59:59.000Z

    Silicate glasses dissolve in water at a rate dependent on the solution concentration of orthosilicic acid (H4SiO4). In general, higher [H4SiO4] leads to lower dissolution rates. It has often been observed that the precipitation of certain silica-bearing alteration products can cause the dissolution of the glass to increase, even after the rate has decreased significantly. However, it has also been observed that in the concentrations of these silica-bearing solution species do not significantly decrease while other elements continue to be released. In this study, we have used the Geochemists Workbench code to investigate the relationship between glass dissolution rates and the precipitation rate of a silica-bearing alteration product, analcime (Na(AlSi2O6)?H2O). In this initial study and to simplify the calculations, we suppressed all alteration products except analcime, gibbsite (Al(OH)3), and amorphous silica. The cross affinity code option allowed us to account for the fact that glass is a thermodynamically unstable solid with respect to its alteration products in contact with water. The cross-affinity option in the Geochemists Workbench geochemical code allowed us to substitute the amorphous silica equilibrium-constant matrix for the glass equilibrium-constant matrix. In this article, we present the results of our calculations of the glass dissolution rate at different values for the analcime precipitation rate constant and the effects of varying the glass dissolution rate constant at a constant analcime precipitation rate constant. In all cases, our results indicate that the glass dissolution rate controls the rate of analcime precipitation in the long term. Our results, compared in general terms with experiments, show the importance of the gel layer that forms during glass alteration. The meaning of these results pertinent to long-term glass durability is discussed.

  8. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25T23:59:59.000Z

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  9. EVALUATION OF THOR MINERALIZED WASTE FORMS FOR THE DOE ADVANCED REMEDIATION TECHNOLOGIES PHASE 2 PROJECT

    SciTech Connect (OSTI)

    Crawford, C.; Jantzen, C.

    2012-02-02T23:59:59.000Z

    The U.S. Department of Energy's (DOE) Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW Vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product, which is one of the objectives of this current study, is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. FBSR testing of a Hanford LAW simulant and a WTP-SW simulant at the pilot scale was performed by THOR Treatment Technologies, LLC at Hazen Research Inc. in April/May 2008. The Hanford LAW simulant was the Rassat 68 tank blend and the target concentrations for the LAW was increased by a factor of 10 for Sb, As, Ag, Cd, and Tl; 100 for Ba and Re (Tc surrogate); 1,000 for I; and 254,902 for Cs based on discussions with the DOE field office and the environmental regulators and an evaluation of the Hanford Tank Waste Envelopes A, B, and C. It was determined through the evaluation of the actual tank waste metals concentrations that some metal levels were not sufficient to achieve reliable detection in the off-gas sampling. Therefore, the identified metals concentrations were increased in the Rassat simulant processed by TTT at HRI to ensure detection and enable calculation of system removal efficiencies, product retention efficiencies, and mass balance closure without regard to potential results of those determinations or impacts on product durability response such as Toxicity Characteristic Leach Procedure (TCLP). A WTP-SW simulant based on melter off-gas analyses from Vitreous State Laboratory (VSL) was also tested at HRI in the 15-inch diameter Engineering Scale Test Demonstration (ESTD) dual reformer at HRI in 2008. The target concentrations for the Resource Conservation and Recovery Act (RCRA) metals were increased by 16X for Se, 29X for Tl, 42X for Ba, 48X for Sb, by 100X for Pb and Ni, 1000X for Ag, and 1297X for Cd to ensure detection by the an

  10. Fast Automated Demand Response to Enable the Integration of Renewable Resources

    E-Print Network [OSTI]

    Watson, David S.

    2013-01-01T23:59:59.000Z

    Sodium Sulfur (NaS) Zinc- Air Battery Demand Response CostsSodium Sulfur (NaS) Zinc- Air Battery Low High AverageSodium Sulfur (NaS) Zinc- Air Battery Demand Response Costs

  11. GLASS SELECTION STRATEGY: DEVELOPMENT OF US AND KRI TEST MATRICIES

    SciTech Connect (OSTI)

    Fox, K; Tommy Edwards, T; David Peeler, D

    2007-02-06T23:59:59.000Z

    High-level radioactive wastes are stored as liquids in underground storage tanks at the Department of Energy's (DOE) Savannah River Site (SRS) and Hanford Reservation. These wastes are to be prepared for permanent disposition in a geologic repository by vitrification with glass forming additives (e.g., frit), creating a waste form with long-term durability. Wastes at SRS are being vitrified in the Defense Waste Processing Facility (DWPF). Vitrification of the wastes stored at Hanford is planned for the Waste Treatment and Immobilization Plant (WTP) when completed. Some of the wastes at SRS, and particularly those at Hanford, contain high concentrations of aluminum, chromium and sulfate. These elements make it more difficult to produce a waste glass with a high waste loading (WL) without crystallization occurring in the glass (either within the melter or upon cooling of the glass), potentially exceeding the solubility limit of critical components, having negative impacts on durability, and/or resulting in the formation of a sulfate salt layer on the molten glass surface. Although the overall scope of the task is focused on all three critical, chemical components, the current work will primarily address the potential for crystallization (e.g., nepheline and/or spinel) in high level waste (HLW) glasses. Recent work at the Savannah River National Laboratory (SRNL) and by other groups has shown that nepheline (NaAlSiO{sub 4}), which is likely to crystallize in high-alumina glasses, has a detrimental effect on the durability of the glass. The objective of this task is to develop glass formulations for specific SRS and Hanford waste streams to avoid nepheline formation while meeting waste loading and waste throughput expectations, as well as satisfying critical process and product performance related constraints. Secondary objectives of this task are to assess the sulfate solubility limit for the DWPF composition and spinel settling for the WTP composition. SRNL has partnered with Pacific Northwest National Laboratory (PNNL) and the V.G. Khlopin Radium Institute (KRI) to complete this task.

  12. BIOTROPICA 38(6): 743753 2006 10.1111/j.1744-7429.2006.00202.x A New Independently Derived Social Spider with Explosive Colony Proliferation

    E-Print Network [OSTI]

    Agnarsson, Ingi

    muy poco usual en ara~nas. Aqui describimos comportamiento social en un genero de la familia miles de ara~nas adultas. Las ara~nas cooperaron en la captura de la presa y compartieron su alimento favor de las hembras, sugiriendo una poblacion altamente subdividida, como en otras ara~nas de

  13. Universidade de Braslia Decanato de Ensino de Graduao

    E-Print Network [OSTI]

    Lucero, Jorge Carlos

    seccional no Moodle: insero da Radiologia Oral nas novas diretrizes curriculares no curso de Odontologia 1

  14. DEVELOPMENT QUALIFICATION AND DISPOSAL OF AN ALTERNATIVE IMMOBILIZED LOW-ACTIVITY WASTE FORM AT THE HANFORD SITE

    SciTech Connect (OSTI)

    SAMS TL; EDGE JA; SWANBERG DJ; ROBBINS RA

    2011-01-13T23:59:59.000Z

    Demonstrating that a waste form produced by a given immobilization process is chemically and physically durable as well as compliant with disposal facility acceptance criteria is critical to the success of a waste treatment program, and must be pursued in conjunction with the maturation of the waste processing technology. Testing of waste forms produced using differing scales of processing units and classes of feeds (simulants versus actual waste) is the crux of the waste form qualification process. Testing is typically focused on leachability of constituents of concern (COCs), as well as chemical and physical durability of the waste form. A principal challenge regarding testing immobilized low-activity waste (ILAW) forms is the absence of a standard test suite or set of mandatory parameters against which waste forms may be tested, compared, and qualified for acceptance in existing and proposed nuclear waste disposal sites at Hanford and across the Department of Energy (DOE) complex. A coherent and widely applicable compliance strategy to support characterization and disposal of new waste forms is essential to enhance and accelerate the remediation of DOE tank waste. This paper provides a background summary of important entities, regulations, and considerations for nuclear waste form qualification and disposal. Against this backdrop, this paper describes a strategy for meeting and demonstrating compliance with disposal requirements emphasizing the River Protection Project (RPP) Integrated Disposal Facility (IDF) at the Hanford Site and the fluidized bed steam reforming (FBSR) mineralized low-activity waste (LAW) product stream.

  15. Secondary Waste Form Screening Test ResultsTHOR Fluidized Bed Steam Reforming Product in a Geopolymer Matrix

    SciTech Connect (OSTI)

    Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

    2011-07-14T23:59:59.000Z

    Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

  16. Radionuclide Retention Mechanisms in Secondary Waste-Form Testing: Phase II

    SciTech Connect (OSTI)

    Um, Wooyong; Valenta, Michelle M.; Chung, Chul-Woo; Yang, Jungseok; Engelhard, Mark H.; Serne, R. Jeffrey; Parker, Kent E.; Wang, Guohui; Cantrell, Kirk J.; Westsik, Joseph H.

    2011-09-26T23:59:59.000Z

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory (PNNL) for Washington River Protection Solutions (WRPS) to evaluate candidate stabilization technologies that have the potential to successfully treat liquid secondary waste stream effluents produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). WRPS is considering the design and construction of a Solidification Treatment Unit (STU) for the Effluent Treatment Facility (ETF) at Hanford. The ETF, a multi-waste, treatment-and-storage unit that has been permitted under the Resource Conservation and Recovery Act (RCRA), can accept dangerous, low-level, and mixed wastewaters for treatment. The STU needs to be operational by 2018 to receive secondary liquid waste generated during operation of the WTP. The STU will provide the additional capacity needed for ETF to process the increased volume of secondary waste expected to be produced by WTP. This report on radionuclide retention mechanisms describes the testing and characterization results that improve understanding of radionuclide retention mechanisms, especially for pertechnetate, {sup 99}TcO{sub 4}{sup -} in four different waste forms: Cast Stone, DuraLith alkali aluminosilicate geopolymer, encapsulated fluidized bed steam reforming (FBSR) product, and Ceramicrete phosphate bonded ceramic. These data and results will be used to fill existing data gaps on the candidate technologies to support a decision-making process that will identify a subset of the candidate waste forms that are most promising and should undergo further performance testing.

  17. Nmero de bolseiros no ensino superior

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    existiam dvidas fiscais ou contributivas nas famlias e que esto agora a contac- tar os servios das

  18. WETLANDS, Vol. 24, No. 4, December 2004, pp. 756765 2004, The Society of Wetland Scientists

    E-Print Network [OSTI]

    Nassauer, Joan Iverson

    appreciated (Zube 1974, Herzog 1985, Schrad- er 1995, Bixler 1997, Ryan 1998, Decamps 2001, Nas- sauer et al

  19. Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions

    SciTech Connect (OSTI)

    Watkins, J.M.; DePaolo, D.J.; Ryerson, F.J.; Peterson, B.

    2011-03-01T23:59:59.000Z

    Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl{sub 2}Si{sub 2}O{sub 8}; denoted AN), albite (NaAlSi{sub 3}O{sub 8}; denoted AB), and diopside (CaMgSi{sub 2}O{sub 6}; denoted DI) were held at 1450C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the ABAN experiment, D{sub Ca}/D{sub Si} ~ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D{sub Ca}/D{sub Si} ~ 1. In the ABDI experiment, D{sub Ca}/D{sub Si} ~ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the ABAN experiment. In the ABDI experiment, D{sub Mg}/D{sub Si} ~ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivitythe ratio of the diffusivity of the cation (D{sub Ca}) to the diffusivity of silicon (D{sub Si}). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D{sub cation}/D{sub Si}. Cations diffusing in aqueous solutions display a similar relationship between isotopic separation efficiency and D{sub cation} =D{sub H 2 O} , although the efficiencies are smaller than in silicate liquids. Our empirical relationship provides a tool for predicting the magnitude of diffusive isotopic effects in many geologic environments and a basis for a more comprehensive theory of isotope separation in liquid solutions. We present a conceptual model for the relationship between diffusivity and liquid structure that is consistent with available data.

  20. Radioactive Bench-scale Steam Reformer Demonstration of a Monolithic Steam Reformed Mineralized Waste Form for Hanford Waste Treatment Plant Secondary Waste - 12306

    SciTech Connect (OSTI)

    Evans, Brent; Olson, Arlin; Mason, J. Bradley; Ryan, Kevin [THOR Treatment Technologies, LLC - 106 Newberry St. SW, Aiken, SC 29801 (United States); Jantzen, Carol; Crawford, Charles [Savannah River Nuclear Solutions (SRNL), LLC, Aiken, SC 29808 (United States)

    2012-07-01T23:59:59.000Z

    Hanford currently has 212,000 m{sup 3} (56 million gallons) of highly radioactive mixed waste stored in the Hanford tank farm. This waste will be processed to produce both high-level and low-level activity fractions, both of which are to be vitrified. Supplemental treatment options have been under evaluation for treating portions of the low-activity waste, as well as the liquid secondary waste from the low-activity waste vitrification process. One technology under consideration has been the THOR{sup R} fluidized bed steam reforming process offered by THOR Treatment Technologies, LLC (TTT). As a follow-on effort to TTT's 2008 pilot plant FBSR non-radioactive demonstration for treating low-activity waste and waste treatment plant secondary waste, TTT, in conjunction with Savannah River National Laboratory, has completed a bench scale evaluation of this same technology on a chemically adjusted radioactive surrogate of Hanford's waste treatment plant secondary waste stream. This test generated a granular product that was subsequently formed into monoliths, using a geo-polymer as the binding agent, that were subjected to compressibility testing, the Product Consistency Test and other leachability tests, and chemical composition analyses. This testing has demonstrated that the mineralized waste form, produced by co-processing waste with kaolin clay using the TTT process, is as durable as low-activity waste glass. Testing has shown the resulting monolith waste form is durable, leach resistant, and chemically stable, and has the added benefit of capturing and retaining the majority of Tc-99, I-129, and other target species at high levels. (authors)

  1. Secondary Waste Form Down-Selection Data PackageFluidized Bed Steam Reforming Waste Form

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

    2011-09-12T23:59:59.000Z

    The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

  2. Structural Analysis of Southern Dixie Valley using LiDAR and...

    Open Energy Info (EERE)

    Structural Analysis of Southern Dixie Valley using LiDAR and Low-Sun-Angle Aerial Photography, NAS Fallon Geothermal Exploration Project, Dixie Valley, Nevada Jump to: navigation,...

  3. Primeira-Dama Tropical: A cidade e o corpo feminino na fico de Jlia Lopes de Almeida

    E-Print Network [OSTI]

    Eisenhart, Vanina

    2006-01-01T23:59:59.000Z

    e polmicas literarias no Brasil. So Paulo: Companhia dase Terra, 1984. Telles, Norma. Brasil. "Escritoras, escritas,tambm segundo Brbara Brasil XXXV (2006) participou nas

  4. Application of the Software as a Service Model to the Control of Complex Building Systems

    E-Print Network [OSTI]

    Stadler, Michael

    2011-01-01T23:59:59.000Z

    in the form of a 12 MWh battery bank manufactured by NGK. InNGK sodium-sulfur (NaS) battery bank had been proposed for

  5. A Green Prison: Santa Rita Jail Creeps Towards Zero Net Energy (ZNE)

    E-Print Network [OSTI]

    Marnay, Chris

    2011-01-01T23:59:59.000Z

    in the form of a 12 MWh battery bank manufactured by NGK. InNGK sodium-sulfur (NaS) battery bank had been proposed for

  6. Environmental Assessment for the Methane Energy and Agricultural...

    Broader source: Energy.gov (indexed) [DOE]

    DOEEA-1402 vi MW Megawatts NAAQS National Ambient Air Quality Standards NAS Naval Air Station NDPES National Pollution Discharge Elimination System NEPA National...

  7. Vozes dos Pores: A literatura perifrica do Brasil

    E-Print Network [OSTI]

    Reyes Arias, Alejandro

    2011-01-01T23:59:59.000Z

    do Morro, que continha imagens captadas nas nossas viagensprocurado do pas. As nicas imagens que foram para o arurbano. Hoje, Tepito evoca imagens contraditrias, algumas

  8. LIFE Economics and Delivery Pathway Presentation to

    E-Print Network [OSTI]

    utilities Install Process Equipment infrastructure Install & commission LRUs Inert / low yield commissioning design 7 years build 7 years qualification Anklam--NAS/NA

  9. Multiple Precision, Multiple Processor Vortex Sheet Roll-Up Computation David H. Bailey, Robert Krasny and Richard Pelz

    E-Print Network [OSTI]

    Bailey, David H.

    Krasny and Richard Pelz October 9, 1992 Ref: Proc. Sixth SIAM Conference on Parallel Processing: dbailey@nas.nasa.gov. Computer time was provided by the NAS Systems Division at NASA Ames. Krasny: Dept. of Mathematics, University of Michigan, Ann Arbor, MI 48109 email: krasny@math.lsa.umich.edu. This work

  10. LEVANTAMENTO DOSLEVANTAMENTO DOS PROBLEMAS AMBIENTAIS DASPROBLEMAS AMBIENTAIS DAS

    E-Print Network [OSTI]

    imagens de satliteInterpretao visual de imagens de satlite #12;Analise nas imagens sobre nascente, foz,Analise nas imagens sobre nascente, foz, Lago, onde o rio passa, vegetaoLago, onde o rio passa, vegetaoCirculamos parte do lago identificando os estudos das imagensestudos das imagens #12

  11. Improved Alumina Loading in High-Level Waste Glasses

    SciTech Connect (OSTI)

    Kim, D.; Vienna, J.D. [Pacific Northwest National Laboratory, Richland, WA (United States); Peeler, D.K.; Fox, K.M. [Savannah River National Laboratory, Aiken, SC (United States); Aloy, A.; Trofimenko, A.V. [V.G. Khlopin Radium Institute, St. Petersburg (Russian Federation); Gerdes, K.D. [EM-21, Office of Waste Processing, U.S. Department of Energy, Washington, DC (United States)

    2008-07-01T23:59:59.000Z

    Recent tank retrieval, blending, and treatment strategies at both the Savannah River Site (SRS) and Hanford have identified increased amounts of high-Al{sub 2}O{sub 3} waste streams that are scheduled to be processed through their respective high-level waste (HLW) vitrification facilities. It is well known that the addition of small amounts of Al{sub 2}O{sub 3} to borosilicate glasses generally enhances the durability of the waste glasses. However, at higher Al{sub 2}O{sub 3} concentrations nepheline (NaAlSiO{sub 4}) formation can result in a severe deterioration of the chemical durability of the slowly cooled glass near the center of the canister. Additionally, higher concentrations of Al{sub 2}O{sub 3} generally increase the liquidus temperature of the melt and decrease the processing rate. Pacific Northwest National Laboratory (PNNL), Savannah River National Laboratory (SRNL), and Khlopin Radium Institute (KRI) are jointly performing laboratory and scaled-melter tests, through US Department of Energy, EM-21 Office of Waste Processing program, to develop glass formulations with increased Al{sub 2}O{sub 3} concentrations. These glasses are formulated for specific DOE waste compositions at Hanford and Savannah River Site. The objectives are to avoid nepheline formation while maintaining or meeting waste loading and/or waste throughput expectations as well as satisfying critical process and product performance related constraints such as viscosity, liquidus temperature, and glass durability. This paper summarizes the results of recent tests of simulated Hanford HLW glasses containing up to 26 wt% Al{sub 2}O{sub 3} in glass. In summary: Glasses with Al{sub 2}O{sub 3} loading ranging from 25 to 27 wt% were formulated and tested at a crucible scale. Successful glass formulations with up to 26 wt% Al{sub 2}O{sub 3} that do not precipitate nepheline during CCC treatment and had spinel crystals 1 vol% or less after 24 hr heat treatment at 950 deg. C were obtained. The selected glass, HAL-17 with 26 wt% Al{sub 2}O{sub 3}, had viscosity and electrical conductivity within the boundaries for adequate processing in the Joule heated melters operated at 1150 deg. C. This HAL-17 glass was successfully processed using small-scale (SMK) and larger scale (EP-5) melters. There was no indication of spinel settling during processing. The product glass samples from these melter tests contained 1 to 4 vol% spinel crystals that are likely formed during cooling. The PCT tests on the product glasses are underway. The present study demonstrated that it is possible to formulate the glasses with up to 26 wt% Al{sub 2}O{sub 3} that satisfy the property requirements and is processable with Joule-heated melters operated at 1150 deg. C. The 'nepheline discriminator' for HAL-17 glass is 0.45, which supports that claim that the current rule ('nepheline discriminator' < 0.62) is too restrictive. Considering that the cost of HLW treatment is highly dependent on loading of waste in glass, this result provides a potential for significant cost saving for Hanford. The maximum Al{sub 2}O{sub 3} loading that can be achieved will also depend on concentrations of other components in wastes. For example, the loading of waste used in this study was also limited by the spinel crystallization after 950 deg. C 24 hr heat treatment, which suggests that the concentrations of spinel-forming components such as Fe{sub 2}O{sub 3}, Cr{sub 2}O{sub 3}, NiO, ZnO, and MnO would be critical in addition to Al{sub 2}O{sub 3} for the maximum Al{sub 2}O{sub 3} loading achievable. The observed glass production rate per unit melter surface area of 0.75 MT/(d.m{sup 2}) for SMK test is comparable to the design capacity of WTP HLW melters at 0.8 MT/(d.m{sup 2}). However, the test with EP-5 melter achieved 0.38 MT/(d.m{sup 2}), which is roughly a half of the WTP design capacity. This result may imply that the glass with 26 wt% Al{sub 2}O{sub 3} may not achieve the WTP design production rate. However, this hypothesis is not conclusive because of unknown effects of melter size and operation

  12. Nepheline Formation Study for Sludge Batch 4 (SB4): Phase 1 Experimental Results

    SciTech Connect (OSTI)

    Peeler, D. K.; Edwards, T. B.; Reamer, I.A.; Workman, R. J.

    2005-09-30T23:59:59.000Z

    Although it is well known that the addition of Al{sub 2}O{sub 3} to borosilicate glasses enhances the durability of the waste form (through creation of network-forming tetrahedral Na+-[AlO{sub 4/2}]{sup -} pairs), the combination of high Al{sub 2}O{sub 3} and Na{sub 2}O can lead to the formation of nepheline (NaAlSiO{sub 4})--which can negatively impact durability. Given the projected high concentration of Al{sub 2}O{sub 3} in SB4 (Lilliston 2005) and the potential use of a high Na{sub 2}O based frit to improve melt rate and a high Na{sub 2}O sludge due to settling problems, the potential formation of nepheline in various SB4 systems continues to be assessed. Twelve SB4-based glasses were fabricated and their durabilities (via the Product Consistency Test [PCT]) measured to assess the potential for nepheline formation and its potential negative impact on durability. In terms of ''acceptability'', the results indicate that all of the study glasses produced are acceptable with respect to durability as defined by the PCT (normalized boron release values for all nepheline (NEPH) glasses were much lower than that of the Environmental Assessment (EA) glass (16.695 g/L)). The most durable glass is NEPH-04 (quenched) with a normalized boron release (NL [B]) of 0.61 g/L, while the least durable glass is NEPH-01 centerline canister cooled (ccc) with an NL [B] of 2.47 g/L (based on the measured composition). In terms of predictability, most of the study glasses are predictable by the {Delta}G{sub p} model. Those that are not predictable (i.e., they fall outside of the prediction limits) actually fall below the prediction interval (i.e., they are over predicted by the model) suggesting the model is conservative. The Phase 1 PCT results suggest that for those glasses prone to nepheline formation (using the 0.62 value developed by Li et al. (2003) as a guide), a statistically significant difference in PCT response was observed for the two heat treatments but the impact on durability was of little or no practical concern. When one couples the PCT responses with the X-Ray Diffraction (XRD) results and/or visual observations, one could conclude that the formation of nepheline in these glasses does have a negative impact on durability. However, that impact may be of statistical significance, but the practical impact may not be sufficient to avoid a specific candidate frit for the SB4 glass system. The results of this study not only suggest that the 0.62 value appears to be a reasonable guide to monitor sludge--frit systems with respect to potential nepheline formation, but also that the impact of nepheline, although statistically significant, has little or no practical impact in the SB4 system to durability as measured by the PCT. This latter statement must be qualified to some extent given only two glasses were selected which were actually ''prone to nepheline formation'' based on this general guide and the relatively volume % of nepheline formed based on XRD results ({approx} 0.5 vol%). If the presence of nepheline has no appreciable, adverse impact on durability for the recently revised SB4 systems, then as decisions regarding the viability of the SB4 options and the down select of candidate frits are pursued, little weight will be given to minimizing the likelihood of nepheline and the decisions will be dominated by waste throughput criteria. That is, the frit selection process will not have to consider the impact of nepheline on the ultimate durability of the product and can focus on recommending a frit that when coupled with the sludge can be processed over a waste loading (WL) interval of interest to the Defense Waste Processing Facility (DWPF) with melt rates meeting production expectations.

  13. REFINEMENT OF THE NEPHELINE DISCRIMINATOR: RESULTS OF A PHASE I STUDY

    SciTech Connect (OSTI)

    Fox, K; James Newell, J; Tommy Edwards, T; David Best, D; Irene Reamer, I; Phyllis Workman, P

    2008-02-13T23:59:59.000Z

    The performance of a glass used for immobilization of high-level nuclear waste (HLW) is generally quantified by its resistance to chemical degradation, or durability. The durability of a HLW glass is dependent on its composition. If crystalline phases form within a glass during cooling, the composition of the residual glass network is altered, therefore affecting the durability of the glass. Crystallization of nepheline (NaAlSiO{sub 4}) has been shown to adversely impact the durability of HLW glasses since it removes glass forming species (in this case, Al and Si) from the glass network. The propensity for nepheline crystallization in a HLW glass increases with increasing concentrations of Al{sub 2}O{sub 3} and Na{sub 2}O in the glass. Nepheline crystallization is therefore of concern for processing of HLW at the Defense Waste Processing Facility (DWPF) since the sludge waste streams at the Savannah River Site (SRS) can contain high concentrations of Al{sub 2}O{sub 3} and Na{sub 2}O. Currently, a 'nepheline discriminator' is included as a process control constraint at the DWPF. The nepheline discriminator relates the concentrations of SiO{sub 2}, Na{sub 2}O and Al{sub 2}O{sub 3} (as weight percentages in glass) to a critical value of 0.62. The discriminator defines a boundary line on the SiO{sub 2}-Na{sub 2}O-Al{sub 2}O{sub 3} ternary diagram above which (or toward the SiO{sub 2} corner of the ternary) nepheline is not predicted to crystallize in the glass upon quenching or slow cooling. The current equation uses only the concentrations of the SiO{sub 2}, Na{sub 2}O and Al{sub 2}O{sub 3} components in the glass in predicting whether or not nepheline is likely to crystallize. However, several other components have been shown to impact the propensity for nepheline crystallization, including B{sub 2}O{sub 3} and CaO among others. Therefore, the potential exists to further refine the nepheline discriminator to include these components. In addition, recently studied HLW glasses with relatively high Al{sub 2}O{sub 3} compositions of 25 wt % or greater and nepheline discriminator values well below 0.62 have been shown to be free of nepheline crystallization upon quenching and slow cooling. Thus, the current nepheline discriminator equation also appears to be conservative for some HLW glass compositions. Refining the nepheline discriminator to include other important components and to reduce conservatism may provide access to high Al{sub 2}O{sub 3} concentration glass compositions for the DWPF, which could in turn allow access to higher waste loadings, decreased washing and improved waste throughput. The objective of this study was to develop and characterize a series of HLW glass compositions based on a projected composition of Sludge Batch 5 (SB5), the next sludge batch to be processed in the DWPF. The selected glass compositions all had nepheline discriminator values below the current limit of 0.62. They cover a range of locations on the SiO{sub 2}-Na{sub 2}O-Al{sub 2}O{sub 3} diagram. They also include varying amounts of B{sub 2}O{sub 3} and CaO to support an evaluation of the impact of these components on the propensity for nepheline crystallization. The results described in this report confirm that some conservatism exists in the current nepheline discriminator. Several glass compositions, particularly compositions that target higher Al{sub 2}O{sub 3} concentrations, were shown to be very durable (i.e., PCT responses that were more than an order of magnitude better than that of the Environmental Assessment benchmark glass) while their nepheline discriminator values were well below the current nepheline discriminator limit of 0.62. Increased concentrations of B{sub 2}O{sub 3} and increased concentrations of CaO were shown to improve durability responses and suppress the formation of nepheline. This provides incentive to revise the nepheline discriminator to reduce some of this conservatism and incorporate the influence of B{sub 2}O{sub 3}. The revised nepheline discriminator could potentially change from a constant line on

  14. Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles

    SciTech Connect (OSTI)

    Corbus, D.

    1992-09-01T23:59:59.000Z

    Recycling and disposal of spent sodium-sulfur (Na/S) batteries are important issues that must be addressed as part of the commercialization process of Na/S battery-powered electric vehicles. The use of Na/S batteries in electric vehicles will result in significant environmental benefits, and the disposal of spent batteries should not detract from those benefits. In the United States, waste disposal is regulated under the Resource Conservation and Recovery Act (RCRA). Understanding these regulations will help in selecting recycling and disposal processes for Na/S batteries that are environmentally acceptable and cost effective. Treatment processes for spent Na/S battery wastes are in the beginning stages of development, so a final evaluation of the impact of RCRA regulations on these treatment processes is not possible. The objectives of tills report on battery recycling and disposal are as follows: Provide an overview of RCRA regulations and requirements as they apply to Na/S battery recycling and disposal so that battery developers can understand what is required of them to comply with these regulations; Analyze existing RCRA regulations for recycling and disposal and anticipated trends in these regulations and perform a preliminary regulatory analysis for potential battery disposal and recycling processes. This report assumes that long-term Na/S battery disposal processes will be capable of handling large quantities of spent batteries. The term disposal includes treatment processes that may incorporate recycling of battery constituents. The environmental regulations analyzed in this report are limited to US regulations. This report gives an overview of RCRA and discusses RCRA regulations governing Na/S battery disposal and a preliminary regulatory analysis for Na/S battery disposal.

  15. Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles. Volume 2, Battery recycling and disposal

    SciTech Connect (OSTI)

    Corbus, D.

    1992-09-01T23:59:59.000Z

    Recycling and disposal of spent sodium-sulfur (Na/S) batteries are important issues that must be addressed as part of the commercialization process of Na/S battery-powered electric vehicles. The use of Na/S batteries in electric vehicles will result in significant environmental benefits, and the disposal of spent batteries should not detract from those benefits. In the United States, waste disposal is regulated under the Resource Conservation and Recovery Act (RCRA). Understanding these regulations will help in selecting recycling and disposal processes for Na/S batteries that are environmentally acceptable and cost effective. Treatment processes for spent Na/S battery wastes are in the beginning stages of development, so a final evaluation of the impact of RCRA regulations on these treatment processes is not possible. The objectives of tills report on battery recycling and disposal are as follows: Provide an overview of RCRA regulations and requirements as they apply to Na/S battery recycling and disposal so that battery developers can understand what is required of them to comply with these regulations; Analyze existing RCRA regulations for recycling and disposal and anticipated trends in these regulations and perform a preliminary regulatory analysis for potential battery disposal and recycling processes. This report assumes that long-term Na/S battery disposal processes will be capable of handling large quantities of spent batteries. The term disposal includes treatment processes that may incorporate recycling of battery constituents. The environmental regulations analyzed in this report are limited to US regulations. This report gives an overview of RCRA and discusses RCRA regulations governing Na/S battery disposal and a preliminary regulatory analysis for Na/S battery disposal.

  16. airborne profiling laser: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to be a powerful technique not only for characte... Corts, Angela; Guesalaga, Andrs; Osborn, James; Rigaut, Francois; Guzman, Dani 2012-01-01 32 Curso 1 -Novos Avanos nas...

  17. Review and evaluation of national airspace system models

    E-Print Network [OSTI]

    Odoni, Amedeo R.

    1979-01-01T23:59:59.000Z

    Abstract from Technical Report Documentation Page: This report is intended to serve as a guide to the availability and capability of state-of-the-art analytical and simulation models of the National Airspace System (NAS). ...

  18. Using tactical flight level resource allocation to alleviate congested en-route airspace

    E-Print Network [OSTI]

    Abad, Antonio Manuel, 1976-

    2004-01-01T23:59:59.000Z

    A motivation exists to formulate and implement new tools and methodologies to address the problem of congestion in the National Airspace System (NAS). This thesis presents a novel methodology for allocating aircraft among ...

  19. Evaluating the depiction of complex RNAV/RNP procedures and analyzing a potential de-cluttering technique

    E-Print Network [OSTI]

    Butchibabu, Abhizna

    2012-01-01T23:59:59.000Z

    Performance Based Navigation (PBN) is a key element of the Federal Aviation Administration's (FAA) NextGen Program. In order to increase National Airspace System (NAS) capacity and efficiency, PBN routes and procedures are ...

  20. PHYSICAL REVIEW B 86, 155320 (2012) Unconventional Hall effect near charge neutrality point in a two-dimensional electron-hole system

    E-Print Network [OSTI]

    Gusev, Guennady

    2012-01-01T23:59:59.000Z

    . N. Mikhailov,3 S. A. Dvoretsky,3 and J. C. Portal4,5,6 1 Institute of Semiconductor Physics, NAS, 135960-170 S~ao Paulo, SP, Brazil 3 Institute of Semiconductor Physics, Novosibirsk 630090, Russia 4

  1. The Wide-Area Energy Storage and Management System Battery Storage Evaluation

    SciTech Connect (OSTI)

    Lu, Ning; Weimar, Mark R.; Makarov, Yuri V.; Ma, Jian; Viswanathan, Vilayanur V.

    2009-07-01T23:59:59.000Z

    This report presents the modeling approach, methodologies, and results of the sodium sulfur (NaS) battery evaluation study, which was conducted by Battelle for the California Energy Commission (CEC).

  2. List of Participants 1. Igor ANDERS (Institute for Low Temperature Physics, Kharkov, UKRAINE),

    E-Print Network [OSTI]

    Popovych, Roman

    List of Participants 1. Igor ANDERS (Institute for Low Temperature Physics, Kharkov, UKRAINE), e Welding Institute of NAS of Ukraine, Kyiv, UKRAINE), e-mail: boris@consult.kiev.ua 24. Ivan FEDORCHUK

  3. Metabolomic and transcriptomic analysis of the rice response to the bacterial blight pathogen Xanthomonas oryzae pv. oryzae

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    system in Xanthomonas oryzae pv. oryzae required for AvrXa212002). The Xanthomonas oryzae pv. lozengeoryzae raxP andPf1 against Xanthomo- nas oryzae pv. oryzae in rice leaves.

  4. Metabolomic and transcriptomic analysis of the rice response to the bacterial blight pathogen Xanthomonas oryzae pv. oryzae.

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    system in Xanthomonas oryzae pv. oryzae required for AvrXa212002). The Xanthomonas oryzae pv. lozengeoryzae raxP andPf1 against Xanthomo- nas oryzae pv. oryzae in rice leaves.

  5. NASA/CP-2003-212448 Design and Application of Strategies/Tactics

    E-Print Network [OSTI]

    Muoz, Csar A.

    NASA Center for Aerospace Information 7121 Standard Drive Hanover, MD 21076-1320 #12;NAS A/CP-2003 Information (CASI) 7121 Standard Drive Hanover, MD 21076-1320 (301) 621-0390 National Technical Information

  6. Evaluating passenger delays in the US domestic air transportation system

    E-Print Network [OSTI]

    Umang, Nitish

    2010-01-01T23:59:59.000Z

    A fundamental component of any National Airspace System (NAS) performance evaluation is the cost impact of air traffic delays, and more generally capacity limitations, on the traveling passengers. In previous research it ...

  7. Projections of Full-Fuel-Cycle Energy and Emissions Metrics

    E-Print Network [OSTI]

    Coughlin, Katie

    2013-01-01T23:59:59.000Z

    NAS. 1995. Coal: Energy for the Future. http://value of the FFC energy for coal. 3.2.4 Issue for Furtherapproximately 65% of energy used in coal production is from

  8. Geothermal Update NATIONAL ACADEMY OF SCIENCES / NOVEMBER 4,...

    Broader source: Energy.gov (indexed) [DOE]

    GTO-NAS.pdf More Documents & Publications GEA Geothermal Summit Presentation Lauren Boyd Geothermal R&D: The DOE Perspective U.S. Department of Energy progress in geothermal...

  9. Dynamic reconfiguration of terminal airspace during convective weather

    E-Print Network [OSTI]

    Michalek, Diana

    Dynamic airspace configuration (DAC) algorithms strive to restructure the U.S. National Airspace System (NAS) in ways that allow air traffic control to better manage aircraft flows. Although past research has largely focused ...

  10. Sandia National Laboratories: DOE Wind Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Nation-al Air Space (NAS) radar system, which has led to a blanket rejection of several wind-farm developments. To improve the siting and ... Last Updated: December 3, 2014...

  11. Sandia National Laboratories: Tool for Siting Planning and Encroachmen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nation-al Air Space (NAS) radar system, which has led to a blanket rejection of several wind-farm developments. To improve the siting and ... Tool for Siting, Planning, and...

  12. Sandia National Laboratories: TSPEAR toolkit

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nation-al Air Space (NAS) radar system, which has led to a blanket rejection of several wind-farm developments. To improve the siting and ... Tool for Siting, Planning, and...

  13. Safety considerations for operation of different classes of unmanned aerial vehicles in the National Airspace System

    E-Print Network [OSTI]

    Weibel, Roland E. (Roland Everett)

    2005-01-01T23:59:59.000Z

    There is currently a broad effort underway in the United States and internationally by several organizations to craft regulations enabling the safe operation of UAVs in the NAS. Current federal regulations governing unmanned ...

  14. Safety Considerations for Operation of Unmanned Aerial Vehicles in the National Airspace System

    E-Print Network [OSTI]

    Weibel, Roland E

    2006-11-21T23:59:59.000Z

    There is currently a broad effort underway in the United States and internationally by several organizations to craft regulations enabling the safe operation of UAVs in the NAS. Current federal regulations governing unmanned ...

  15. Aircraft Cabin Environmental Quality Sensors

    E-Print Network [OSTI]

    Gundel, Lara

    2010-01-01T23:59:59.000Z

    O3.pdf Ozone_Optec _Battelle_EVS_Optec2008.pdf Ref A1.13studies (NAS/ NRC, ASHRAE/Battelle), and continuing byof the ASHRAE-sponsored Battelle study collected passenger

  16. Mobilizing the Grassroots from Above: Political Engagement among AIDS Associations in Democratic Brazil

    E-Print Network [OSTI]

    Rich, Jessica A. J.

    2009-01-01T23:59:59.000Z

    seja nas relaes governo/sociedade civil local. Entosinalizador de como que o governo local est vendo essascivil se relaciona com o governo. Ento para mim , onde

  17. EXPERIMENTO MENTAL I: A CONCEPO CONTRATUALISTA CLSSICA, O MODELO DA TRAGDIA DOS COMUNS E AS CONDIES DE EMERGNCIA DA COOPERAO. LOCKE, ROUSSEAU E KANT

    E-Print Network [OSTI]

    Leister, Carolina; Chiappin, J. R. N.

    2007-01-01T23:59:59.000Z

    o colocam nas mos do governo instituindo um novo mecanismoreconhecimento por parte do governo a seu direito natural mais do que reconhec-la, o governo deve ser o fiador desse

  18. Characterization of Novel Semiconductor Alloys for Band Gap Engineering

    E-Print Network [OSTI]

    Broesler, Robert Joseph

    2010-01-01T23:59:59.000Z

    and pulsed laser melting (PLM) to crystallize the amorphousrich crystalline phases, where as PLM results in GaAs-richFurther study into the effects of PLM on amorphous GaNAs is

  19. MFR PAPER 1029 Comminuted fish flesh treated

    E-Print Network [OSTI]

    \\IA 01930. T'he re earch reported here nas conducted nhile he \\\\as on temporar) as ignment to the Food Irradiation Labora- ton, L.S. Amn Natick Labora- tories, "'atick, ~las . Fred Heilig- man and Eugen Wierbicki

  20. The 1996 U.S. Purse Seine Fishery for Tropical Tunas in the Central-Western Pacific Ocean

    E-Print Network [OSTI]

    for tropical tu nas (yellowfin, Thunnus albacares; skipjack, Katsuwonus pelamis; and big eye, T. obesus, and skipjack tuna, Katsuwonus pelamis, and continued a de clining trend that started in 1995. Catch rates also

  1. Identification of Robust Routes using Convective Weather Forcasts

    E-Print Network [OSTI]

    Michalek, Diana

    Convective weather is responsible for large delays and widespread disruptions in the U.S. National Airspace System (NAS), especially during summer months when travel demand is high. This has been the motivation for Air ...

  2. DOE Launches the Advanced Research Projects Agency-Energy, or...

    Broader source: Energy.gov (indexed) [DOE]

    and many other technological breakthroughs. ARPA-E was recommended by the National Academy of Sciences (NAS) and was authorized by Congress in 2007, but it received its first...

  3. Development of a comprehensive reporting system for a school reform organization: The Accelerated Schools Project

    E-Print Network [OSTI]

    Stephens, Jennifer Anne

    2006-04-12T23:59:59.000Z

    of these organizations include the New American Schools (NAS) Corporation (Bodilly, 1998; Stringfield, Ross, & Smith, 1996) and the Core Knowledge Foundation (Datnow, McHugh, Stringfield, & Hackler, 1998). Such models provide a wide range from which schools may...

  4. Presentation to the NSF Review Panel

    Broader source: Energy.gov (indexed) [DOE]

    9 NRC NNSA Study (2013) * Congress directed DOE to request the National Academy of Sciences (NAS) to review the quality and management of research at the NNSA labs* * The study...

  5. Degradao Ultra Violeta de Geomembranas Polimricas Paulo Csar Lodi

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    seguinte: RH + O2 + h R + ROO + RO + OH (1) RH a cadeia polimrica, h a energia de um fton com h. Como nas poliolefinas muito mais fcil liberar energia para formar radicais livres do que para

  6. Universidades portuguesas

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    mais presentes, as mulheres ainda no ocupam mui- tos lugares de topo nas institui- es. "Uma questo avalia a propor- o de universidades de nvel mundial num pas atravs de aspe- tos como o nmero e

  7. Sandia National Laboratories: evaluating wind-turbine/radar impacts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Space (NAS) radar system, which has led to a blanket rejection of several wind-farm developments. To improve the siting and ... Last Updated: December 3, 2014 Go To...

  8. Sandia National Laboratories: SAND2014-20235M

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Space (NAS) radar system, which has led to a blanket rejection of several wind-farm developments. To improve the siting and ... Last Updated: December 3, 2014 Go To...

  9. Sandia National Laboratories: Interagency Field Test and Evaluation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Air Space (NAS) radar system, which has led to a blanket rejection of several wind-farm developments. To improve the siting and ... Last Updated: December 3, 2014 Go To...

  10. Microsoft Word - Fossil Fuel EA Final EA

    Office of Environmental Management (EM)

    The National Academy of Sciences (NAS) estimates that 15,400 to 21,800 people in the United States die from lung cancer attributable to radon, although the number could be as...

  11. Biblioteca Universitria -Novas aquisies

    E-Print Network [OSTI]

    Floeter, Sergio Ricardo

    /6 - Ciencias t. ex.: 1CARTAGENA, Sarah Marcela Chinchilla. Reduo de riscos de desastres nas escolas/ [Texto Sarah Marcela Chinchilla Cartagena]. Florianpolis: CEPED/UFSC, 2012. 9 p. ( Reduo de Riscos de

  12. CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION

    SciTech Connect (OSTI)

    Crawford, C

    2008-07-31T23:59:59.000Z

    The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be >99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that {approx}75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

  13. OpenSHMEM Performance and Potential: A NPB Experimental Study

    SciTech Connect (OSTI)

    Pophale, Swaroop [University of Houston, Houston] [University of Houston, Houston; Nanjegowda, Ramachandra [University of Houston, Houston] [University of Houston, Houston; Curtis, Anthony R [ORNL] [ORNL; Chapman, Barbara [University of Houston, Houston] [University of Houston, Houston; Jin, Haoqiang [NASA Ames Research Center] [NASA Ames Research Center; Poole, Stephen W [ORNL] [ORNL; Kuehn, Jeffery A [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    OpenSHMEM is a recently introduced open stan- dard for all SHMEM libraries. In this paper we discuss the dif- ferent aspects of porting the NAS parallel benchmarks from their MPI 1 implementations to those that use the new OpenSHMEM library API. We compare performance and scalability of these unoptimized OpenSHMEM NAS benchmarks with their MPI 1, and in some cases, MPI 2 counter parts. Through the perfor- mance results of the OpenSHMEM NAS parallel benchmarks on three different platforms that use different OpenSHMEM library implementations we show that even without optimizations these benchmarks have performance comparable to MPI 1 and better than MPI 2 on more mature library implementations. We also do an in-depth analysis of the performance and expect that with hardware support and better implementation of collectives the OpenSHMEM implementations can outperform MPI.

  14. Perinuclear Mlp proteins downregulate gene expression in response to a defect in mRNA export

    E-Print Network [OSTI]

    Bedwell, David M.

    Perinuclear Mlp proteins downregulate gene expression in response to a defect in mRNA export of Cell Biology, Sciences III, University of Geneva, Geneva, Switzerland The mRNA export adaptor Yra1p/REF contributes to nas- cent mRNP assembly and recruitment of the export recep- tor Mex67p. yra1 mutants exhibit m

  15. ON ALGEBRATCPROPERTIESOF ALGEBRASOF AUTOMORPHICFORMS Igor Dolgachev

    E-Print Network [OSTI]

    Dolgachev, Igor V.

    factor L. The direct sum \\(f ) = _@_ AL(r), nas a natural struc- - meZ ture of a graded commutatlve that the algebra Ar = @_ Ho(Xtr1,tm;ls also flnltely meZ ctFha7qfarl ml . rr)Ii We n invariants At', G = ldentlfv

  16. Welcome to the Computational Fluid Dynamics Matt de Stadler

    E-Print Network [OSTI]

    Wang, Deli

    applications Wake behind Guadalupe island http://www.nasaimages.org/luna/servlet/detail/nasaNAS~10~10~8 4390 flow over a ridge [movie] #12;Stratified turbulent wakes Wakes are generated by every moving body is the energy distributed? What characteristic

  17. Welcome to the Computational Fluid Dynamics Matt de Stadler

    E-Print Network [OSTI]

    Wang, Deli

    applications Wake behind Guadalupe island http://www.nasaimages.org/luna/servlet/detail/nasaNAS~1 0 Wakes are generated by every moving body and flow past any fixed body Application sizes range from spray will the wake last? How is the energy distributed? What characteristic features emerge? Low-level winds rushing

  18. ICF Program StatusSNL Z Facility UR/LLE OMEGA Presented to

    E-Print Network [OSTI]

    ICF Program StatusSNL Z Facility UR/LLE OMEGA Presented to: Fusion Power Associates Annual Meeting on planned path High energy density physics is recognized as an important and emerging scientific field NAS, OSTP reports Budget outlook remains tight FY2006 appropriation Outyear plans #12

  19. Dan Martin Watson Department of Physics and Astronomy

    E-Print Network [OSTI]

    panel. 2008, 2011, 2013 NASA: Research Opportunities in Space and Earth Science: Origins of Solar Postoctoral Fellowship Program review panel. 2012 NSF: Experimental Program to Stimulate Competitive Research review panel 2009-2011 National Academy of Sciences (NAS)/National Research Council (NRC) 2010 Decadal

  20. 3700713 IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, VOL. 19, NO. 2, MARCH/APRIL 2013 Runtime Management of Laser Power

    E-Print Network [OSTI]

    Joshi, Ajay

    the multibus NoC architecture and runtime laser power management technique on a 64-core system running NAS by more than 49% with minimal impact on the system performance. Index Terms--Laser power management, many and several times lower energy cost compared to the projected electrical link technology [7], [22

  1. 52 MRS BULLETIN/AUGUST 2000 Introduction

    E-Print Network [OSTI]

    for solar cells and flat-panel displays (FPDs). Automatically dimming rear-view mirrors for automobiles, invisible security circuits on windows, and transparent radio anten- nas built into automobile windows Roy G. Gordon Table I: History of Processes for MakingTransparent Conductors. Materials and Process

  2. Crystal Structure and Computational Analyses Provide Insights into the Catalytic Mechanism of 2,4-Diacetylphloroglucinol

    E-Print Network [OSTI]

    Zhao, Huimin

    and School of Life Sciences, University of Science and Technology of China, Hefei, Anhui 230026, ChinaG from Pseudomo- nas fluorescens catalyzes hydrolytic carbon-carbon (CC) bond cleavage of the antibiotic (MAPG) by cleaving one of the carbon-carbon (CC) bonds linking the acetyl groups to the phenolic ring

  3. IDENTIFICATION OF LEUCOCYTOZOON TODDI GROUP (HAEMOSPORIDA: LEUCOCYTOZOIDAE), WITH REMARKS ON THE SPECIES TAXONOMY

    E-Print Network [OSTI]

    Sehgal, Ravinder

    ON THE SPECIES TAXONOMY OF LEUCOCYTOZOIDS Gediminas Valkiunas, Ravinder N. M. Sehgal*, Tatjana A. Iezhova. e-mail: gedvalk@ekoi.lt ABSTRACT: The current taxonomy of leucocytozoids (Haemosporida identified species of avian haemosporidians. Based on the current taxonomy, Leucocytozoon toddi is the sole

  4. The dynamic structure underlying subthreshold oscillatory activity and the onset

    E-Print Network [OSTI]

    Rotstein, Horacio G.

    stellate cells display subthresh- old oscillations (STOs). We study a single compartment biophysical model and a reset voltage. We show that the synchronization properties in networks made up of the NAS cells established that the SCs develop low-amplitude (1-4 mV) rhythmic subthreshold membrane potential oscillations

  5. Results Conclusions & Future Work TRADEOFF ANALYSIS OF Design of a Green Campus Motor Fleet Decision Support System

    E-Print Network [OSTI]

    Greenhouse Gas (GHG) emissions from owned or leased vehicles by 12.3% by 2020 compared to a FY 2008 baseline (NAS) - Resources include more than 48,000 employees and a 2013 budget of $15.2 billion Mission: Our fueled by December 31 2015, Hybrid, electric, compre

  6. Title 40 CFR Part 191 Subparts B and C

    E-Print Network [OSTI]

    Institute for Regulatory Science SNL Sandia National Laboratories SRS Savannah River Site T transmissivity National Laboratory MP Management Procedure NAS National Academy of Sciences NEA/OECD Nuclear Energy Agency and Abbreviations BCLDP Battelle Columbus Laboratory Decommissioning Project CAO Carlsbad Area Office CARD

  7. Vegetation changes on an abandoned rice field following herbicide and fertilizer treatments

    E-Print Network [OSTI]

    Cwik, Michael Joseph

    1973-01-01T23:59:59.000Z

    ass (pa icum ~v(r turn L. ), a d rownseed nasn I (~nas alum plicat I ~ Michx. ). In co treat, vegetation of abend ed rice land is composed principally of annual forbs intermixed with three-awns (Aristida spp. ). Forbs, as used in this paper, wili...

  8. Uncertainty in Experience CurvesUncertainty in Experience Curves for Climate Policy Analysis:for Climate Policy Analysis

    E-Print Network [OSTI]

    Pittsburgh, Pennsylvania Presentation to the NAS Workshop on Modeling the Economics of Greenhouse Gas converters installed on automobiles No "natural" markets for these technologies; rather, major markets in Service CumulativeGWe Japan Germany Others U.S. FGD = Flue Gas Desulfurization system (typical SO2 removal

  9. GPS RISK ASSESSMENT STUDY FINAL REPORT

    E-Print Network [OSTI]

    Ladkin, Peter B.

    S. Pullen (consultant) T. Thompson #12;iii ABSTRACT The Federal Aviation Administration (FAA) has, GPS alone will not meet all aviation positioning requirements. To meet the National Airspace System (NAS) requirements, the FAA has proposed two augmentations to GPS: a Wide Area Augmentation System

  10. NEXTOR: The National Center of Excellence for Aviation Operations Research

    E-Print Network [OSTI]

    Shapiro, Benjamin

    Administration (FAA) established The National Center of Excellence for Aviation Operations Research (NEXTOR for the Federal Aviation Administration to analyze the impact of new technologies for the entire NAS and devise Mathematics, Economics, Civil Engineering and Electrical Engineering. BACKGROUND The Federal Aviation

  11. EXECUTIVE SUMMARY CCoonntteexxtt

    E-Print Network [OSTI]

    de Weck, Olivier L.

    dense air traffic picture the Federal Aviation Administration (FAA) is attempting to manage while also of an UAS Program Office within the FAA; the stand-up of a sense-and-avoid standards body by the FAA federal operations in the NAS. These included an effort by the National Aeronautics and Space Administration (NASA

  12. TCP SPLITTING PROTOCOL FOR BROADBAND AERONAUTICAL SATELLITE NETWORK

    E-Print Network [OSTI]

    Baras, John S.

    . According to the Federal Aviation Administration (FAA) Aerospace Forecasts 2002-2013, domestic operations (e end-to-end TCP, especially in burst error environment. Introduction America's aviation industry in 2013 [1]. The National Airspace System (NAS) is one of the safest and most secure aviation systems

  13. A DME Based Area Navigation Systems for GPS/WAAS Interference Mitigation In General Aviation Applications

    E-Print Network [OSTI]

    Stanford University

    States. The Federal Aviation Administration (FAA) is leading the e ort to mod- ernize the NAS, Stanford University Abstract The Federal Aviation Administration is leading the National Airspace SystemA DME Based Area Navigation Systems for GPS/WAAS Interference Mitigation In General Aviation

  14. Calculo Diferencial e Integral II Semestre 2013/2014 MEAmbi e MEBiol

    E-Print Network [OSTI]

    Ventura, Joana

    aula da pratica e sobre o desem- penho em determinados exercicios escritos realizados nas aulas e que. (8) Havera uma lista de exercicios propostos para cada aula pratica. Estes exercicios devem ser resolvidos pelos alunos antes das respectivas aulas praticas. Durante as aulas praticas os alunos trabalhar

  15. Reciclagem de lixo oferece boa economia de energia e, hoje,

    E-Print Network [OSTI]

    de Aguiar, Marcus A. M.

    Reciclagem de lixo oferece boa economia de energia e, hoje, é fonte de sustento não apenas para no Brasil", apresentando propostas para atender ao núme- ro crescente de jovens que buscam assento nas parte do Brasil. Especialistas afirmam que nós consumimos carne de gado europeu antes de fevereiro deste

  16. Reconstruc~ao de Imagens de Resson^ancia Magnetica de Fluxo com Compressed Sensing

    E-Print Network [OSTI]

    Carvalho, João Luiz

    ´obitos no Brasil. A visualiza¸c~ao e quantifica¸c~ao do fluxo cardiovascular trazem informa) reconstru¸c~ao por energia m´inima, (d) reconstru¸c~ao por CS [3]. s~ao as diferen¸cas finitas nas dire a energia do sinal esteja fortemente concentrada em

  17. PROBCAST: A Web-Based Portal to Mesoscale Probabilistic Forecasts Clifford Mass1

    E-Print Network [OSTI]

    Mass, Clifford F.

    1 PROBCAST: A Web-Based Portal to Mesoscale Probabilistic Forecasts Clifford Mass1 , Susan Joslyn over the Pacific Northwest. PROBCAST products are derived from the output of a mesoscale ensemble-processing of mesoscale, short-range ensembles. The NAS report also noted current deficiencies in the communication

  18. CX-010909: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bench-Scale Development of a Non-Aqueous Solvent (NAS) Carbon Dioxide (CO2) Capture Process for Coal-Fired Power Plants CX(s) Applied: A9, A11 Date: 09/25/2013 Location(s): New Jersey Offices(s): National Energy Technology Laboratory

  19. Forest ecology Introduction

    E-Print Network [OSTI]

    Johnson, Edward A.

    Forest ecology Introduction Forest ecology is a part of ecology that is con- cerned with forests as opposed to grasslands, savan- nas, or tundra. Ecology is the study of the processes of interaction among organisms and between organ- isms and their environment. Ecology is often subdi- vided into physiological

  20. NUCLEAR SCIENCE SERIES National Academy of Sciences-National Research Council

    E-Print Network [OSTI]

    by Technical Information Center, Office of Information Services UNITED STATES ATOMIC ENERGY COMMISSION #12 George Rogo=, U. S, Atomic Energy Commission Subcommittee on Radiochemistry Grago~ R. Choppin, Chairman National LaboratoW Kurt Wolfsberg, Los Alarnos Scientific LaboratoW #12;NAS-N.WOW AEC Distriktion c%egory U

  1. Programa Integrado de Monitoria Remota de Fragmentos Florestais e

    E-Print Network [OSTI]

    pontos para alimentar a base de dados do projeto. ? valido destacar que tais tabelas foram geradas nas-se as favelas a partir da base de dados disponíveis pelo Instituto Pereira Passos do ano de 1999. Assim, o de Campo e Pós-processamento dos Dados Ao longo dos meses de Julho e Agosto a equipe do INEA realizou

  2. Anurio Estatstico 2013 (2008-2012)

    E-Print Network [OSTI]

    Maier, Rudolf Richard

    anuário foi organizado com base nas informações prestadas pelas unidades acadêmicas e administrativas, pelos centros, órgãos complementares e sistemas eletrônicos de dados da Universidade de Brasília ........................................................................................................... 26 1. Informações e Dados Gerais

  3. FEVEREIRO DE 2011 RELATRIO FINAL

    E-Print Network [OSTI]

    nas discussões sobre as mudanças climáticas e seus impactos sobre as políticas públicas e o processo condução do Programa de Mudanças Climáticas na Secretaria do Verde e do Meio Ambiente, pela coordenação e

  4. Y AND RELIABILITY: LOGO MANUAL COLOR SCHEME

    E-Print Network [OSTI]

    Bordenstein, Seth

    AND RELIABILITY: LOGO MANUAL COLOR SCHEME TYPOGRAPHY RECOMMENDED DISPLAY SPACE PMS 131C PMS COOL GRAY 11C VERSION HORIZONTAL 1J COLOR SCHEME R=203 G=163 B=57 C=21 M=34 Y=93 K=2 20,0 @Me Nas $10M in equipment Machine shop equipped conference facility All-purpose machine shop Skilled engineering staff

  5. Galp e seis universidades lanam Instituto do Petrleo e do Gs

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    Galp e seis universidades lanam Instituto do Petrleo e do Gs ? ENSINO A GALP Energia e as seis maiores universidades portuguesas anuncia- ram a criao do Instituto do Petr- leo e do Gs para desenvolver inves- tigao e formao nas reas do pe- trleo e do gs no mundo lusfono. O Instituto do

  6. Growth, spore germination and infection studies on a peanut leaf-spot fungus

    E-Print Network [OSTI]

    Das, Gopinath

    1951-01-01T23:59:59.000Z

    , iooording to tho other Lncestlgators different noxphoiLogLoal faxcxe of this foe+Re bAwe been ro~ Soseverc after oxeainatilgl of tho oxganbw g. sFecd~dL~~ cchioh nas orlginaoy deeoribod in 1917 by Hoxi in depone it cess suggested that this fonyu ie also...

  7. SENSORIAMENTO REMOTO NO ESTUDO DA DENGUE COM ALUNOS

    E-Print Network [OSTI]

    de leitura, pesquisa e comunicao dos alunos. #12;SJC - Distribudo Carta imagens de So Jos dos/Resultados Gerao de mapas a partir da interpretao de imagens de satlite; So Jos dos Campos - Google Earth Rio municpios no tiveram dificuldade para identificar o nvel scio econmico dos bairros nas imagens de alta

  8. ANLISE AMBIENTAL DA SUB BACIA DO RIO TIMBU ATRAVS

    E-Print Network [OSTI]

    tecnologias, como o uso do sensoriamento remoto e uso de imagens de satlite no ensino da geografia COMEC DE 1986 (ESCALA: 1:20.000) 3 IDENTIFICAR O CURSO DO RIO EM IMAGENS DE SATLITE CEDIDAS PELO INPE MAPA DE USO DO SOLO NA CARTA E NAS IMAGENS 6 OBSERVAR AS ALTERAES AMBIENTAIS OCORRIDAS NOS TRS

  9. Simulation du transfert de polluants dans les sols et les eaux souterraines : recommandations pour le choix du modle

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    'obtention de résultats exploitables pour parvenir à une gestion raisonnée et proportionnée d'une pollution. Or 1.5 2 2.5 3 3.5 ConcentrationenPCE(µg/l) S-2 S-3 PLPR-3S-5 BV BIOCHLOR NAS ANTEA ENVIROS INERIS

  10. EMC PERSPECTIVE: THE POWER OF WINDOWS SERVER 2012 AND EMC

    E-Print Network [OSTI]

    Chaudhuri, Surajit

    EMC PERSPECTIVE: THE POWER OF WINDOWS SERVER 2012 AND EMC INFRASTRUCTURE FOR MICROSOFT PRIVATE and storage optimization features of intelligent storage arrays, such as the EMC® Symmetrix® VMAX® storage family, the EMC® VNX® series, and the EMC® Isilon® scale-out NAS family. With new technologies

  11. FCT vai aprovar mais 350 bolsas de investigao depois dos protestos

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    requisi- tos de qualidade e que tero de ser usados em recursos humanos. Este incentivo poder abranger externa FCT, Miguel Seabra considera que " uma tima ideia. Estamos aber- tos e daremos toda a colaborao". Nas ltimas semanas, os protes- tos dos bolseiros, que garantem em grande parte o funcionamento

  12. PALAVRAS-CHAVE Braz. J. Food Technol., 6:77-83, 2003 77 Recebido / Received: 29/01/2002. Aprovado / Approved: 14/10/2002.

    E-Print Network [OSTI]

    Ferreira, Mrcia M. C.

    aplicados aos dados dos espectros (305 pontos por espectro) foi possvel determinar o teor de sacarose nas data obtained from standard sucrose solutions in the mid infrared region. The spectra were registered O mtodo tradicional empregado para determinar o teor de sacarose em amostras de acar ou sucos o

  13. Waste Examination Assay Facility operations: TRU waste certification

    SciTech Connect (OSTI)

    Schultz, F.J.; Caylor, B.A.; Coffey, D.E.; Phoenix, L.B.

    1987-01-01T23:59:59.000Z

    The ORNL Waste Examination Assay Facility (WEAF) was established to nondestructively assay (NDA) transuranic (TRU) waste generated at Oak Ridge National Laboratory (ORNL). The present facility charter encompasses the NDA and nondestructive examination (NDE) of both TRU and low-level wastes (LLW). Presently, equipment includes a Neutron Assay System (NAS), a Segmented Gamma Scanner (SGS), a drum-sized Real-Time Radiography (RTR) system, and a Neutron Slab Detector (NSD). The first three instruments are computer interfaced. Approximately 2300 TRU waste drums have been assayed with the NAS and the SGS. Another 3000 TRU and LLW drums have been examined with the RTR unit. Computer data bases have been developed to collate the large amount of data generated during the assays and examinations. 6 refs., 1 tab.

  14. Note I: A Translation of the Biography of the Mahasiddha Indrabhuti with Notes

    E-Print Network [OSTI]

    Katz, Nathan

    1975-02-11T23:59:59.000Z

    of TLlo.pa., Na.ro.pa., and others. 2 S. "attain a good house": Probably an idiom referring to Indrabhuti's getting the affairs of state in order for the transferrance of power to his son. 27 3 I. "the first bhumi": Tib. sa.dang.po. 32. "sat down... . Fhrad. nas. rgya1.bu.gL yu1. duo chas.pa. la./ inndrabhutis. rat. dang. glang.bo. dang. gser. dngul. la. sogs. ba'i. skyes.mang.mo. bEkur. nas. btang. ngo.// des. rang. gi. yul. duo phyin.pa. dang./ phas. chung.ma. ga.re: zer.ba. la.fbu.mo chung. bas...

  15. Excess plutonium disposition: The deep borehole option

    SciTech Connect (OSTI)

    Ferguson, K.L.

    1994-08-09T23:59:59.000Z

    This report reviews the current status of technologies required for the disposition of plutonium in Very Deep Holes (VDH). It is in response to a recent National Academy of Sciences (NAS) report which addressed the management of excess weapons plutonium and recommended three approaches to the ultimate disposition of excess plutonium: (1) fabrication and use as a fuel in existing or modified reactors in a once-through cycle, (2) vitrification with high-level radioactive waste for repository disposition, (3) burial in deep boreholes. As indicated in the NAS report, substantial effort would be required to address the broad range of issues related to deep bore-hole emplacement. Subjects reviewed in this report include geology and hydrology, design and engineering, safety and licensing, policy decisions that can impact the viability of the concept, and applicable international programs. Key technical areas that would require attention should decisions be made to further develop the borehole emplacement option are identified.

  16. Rev. Filos., Aurora, Curitiba, v. 22, n. 31, p. 495-513, jul./dez. 2010 ISSN 0104-4443

    E-Print Network [OSTI]

    Rev. Filos., Aurora, Curitiba, v. 22, n. 31, p. 495-513, jul./dez. 2010 ISSN 0104-4443 Licenciado a psicanálise reverte, nas suas teorizações, as categorias fenomenológicas #12;AYOUCH, T. Rev. Filos., Aurora. Filos., Aurora, Curitiba, v. 22, n. 31, p. 495-513, jul./dez. 2010 497 Assim começa o soneto 130 de

  17. Poly(lactide)-containing Multifunctional Nanoparticles: Synthesis, Domain-selective Degradation and Therapeutic Applicability

    E-Print Network [OSTI]

    Samarajeewa, Sandani

    2013-02-14T23:59:59.000Z

    acrylate OLA Oligo(lactic acid) OVCAR Ovarian adenocarcinoma PAA Poly(acrylic acid) PAEA Poly(acrylamidoethylamine) PDI Polydispersity index PDLLA Poly(DL-lactide) PEG Poly(ethylene glycol) PLA Poly(lactide) PLE Porcine liver esterase PLLA Poly... xii LIST OF FIGURES FIGURE Page 2.1 1H NMR spectra: (a) diblock copolymer P(NAS0.24-co-NAM0.76)210-b -PLLA43 in CDCl3; (b...

  18. Molten carbonate fuel cell product development test. Final report, September 30, 1992--March 31, 1997

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    This report summarizes the work performed for manufacturing and demonstrating the performance of its 250-kW molten carbonate fuel cell (MCFC) stack in an integrated system at the Naval Air Station Miramar (NAS Miramar) located in San Diego, California. The stack constructed for the demonstration test at the NAS Miramar consisted of 250 cells. It was manufactured using M-C Power`s patented Internally Manifolded Heat Exchanger (IMHEX{reg_sign}) stack design. The demonstration test at NAS Miramar was designed to operate the 250-kW MCFC stack in a cogeneration mode. This test represented the first attempt to thermally integrate an MCFC stack in a cogeneration system. The test was started on January 10, 1997, and voluntarily terminated on May 12, 1997, after 2,350 hours of operation at temperatures above 1,100 F and at a pressure of three atmospheres. It produced 160 MWh of d.c. power and 346,000 lbs of 110 psig steam for export during 1,566 hours of on-load operations. The test demonstrated a d.c. power output of 206 kW. Most of the balance of the plant (BOP) equipment operated satisfactorily. However, the off-the-shelf automotive turbocharger used for supplying air to the plant failed on numerous occasions and the hot gas blower developed seal leakage problems which impacted continuous plant operations. Overall the demonstration test at NAS Miramar was successful in demonstrating many critical features of the IMHEX technology. Lessons learned from this test will be very useful for improving designs and operations for future MCFC power plants.

  19. The catalytic reduction of nitric oxide with ammonia over tetraamminecopper (II) complexes

    E-Print Network [OSTI]

    Oates, Margaret Deron

    1979-01-01T23:59:59.000Z

    . Jack H. Lunsford The catalytic activity of tetraamminecopper(II) complexes in aque- ous solution in the reduction of nitric oxide with ammonia nas been in- vestigated. Kinetic data for the nitric oxide reduction reaction were determined in a closed... circulating system. Electron paramagnetic reso- spectroscopy was used to determine the zelative quantity of copper in the +2 oxidation state at different temperatures. A reaction mechanism is proposed from these experimental investigations in order...

  20. Caustic Recycle from Hanford Tank Waste Using Large Area NaSICON Structures (LANS)

    SciTech Connect (OSTI)

    Fountain, Matthew S.; Sevigny, Gary J.; Balagopal, S.; Bhavaraju, S.

    2009-03-31T23:59:59.000Z

    This report presents the results of a 5-day test of an electrochemical bench-scale apparatus using a proprietary (NAS-GY) material formulation of a (Na) Super Ion Conductor (NaSICON) membrane in a Large Area NaSICON Structures (LANS) configuration. The primary objectives of this work were to assess system performance, membrane seal integrity, and material degradation while removing Na from Group 5 and 6 tank waste from the Hanford Site.

  1. Geothermal heat pumps for heating and cooling

    SciTech Connect (OSTI)

    Garg, S.C.

    1994-03-01T23:59:59.000Z

    Naval Facilities Engineering Service Center (NFESC) has been tasked by Naval Shore Facilities Energy Office to evaluate the NAS Patuxent River ground-source heat pump (GHP) installation. A large part of a building`s energy consumption consists of heating and air conditioning for occupant comfort. The space heating requirements are normally met by fossil-fuel-fired equipment or electric resistance heating. Cooling is provided by either air conditioners or heat pumps, both using electricity as an energy source.

  2. Comparison of Different Methods of Harvesting Cotton.

    E-Print Network [OSTI]

    Smith, H. P. (Harris Pearson)

    1946-01-01T23:59:59.000Z

    - - TEXAS AGRICULTURAL EXPERIMENT STATION R. D. LEWIS, Director College Station. Texas BULLETIN NO. 683 OCTOBER, 1946 COMPARISON OF DIFFERENT METHODS OF HARVESTING COTTON Division of Agricultural Engineering . and Division of Agronomy... on the rougher methods of harvesting cotton, such as hand-snapping and machine harvesting both with the picker type and the stripper type mechanical harvesters. This n-as largely because the lint from the roughly harvested cottons contained more foreign...

  3. Notice Type: Presolicitation

    E-Print Network [OSTI]

    a requirement for 1 each EMC VNX 5300 - NAS - 18 TB - Rack-Mountable - Serial Attached SCSI 2 - HD 3 TB X 6 - Raid 0,1,3,5,6,10 - 8GB Fiber Channel - ISCSI - 3U P/N: VNX53D153T72M, 5 each EMC Drive Enclosure - Rack-Mountable - 15 X Total Bay - 15 X 3.5" P/N: V31-DAE-N- 15, 1 each EMC VNX Second Control Station

  4. N E U R O C I N C I A 4 2 G A L I L E U | S E T E M B R O 2 0 0 7

    E-Print Network [OSTI]

    Valero-Cuevas, Francisco

    EUA em relação ao programa nuclear de seu país e analisa acidentes aéreos no Brasil >> Não é incomum Meshkati é um especialista em segurança industrial nas áreas de energia nuclear, química e aeronáutica Chernobyl em solo iraniano. Meshkati também acredita que os grandes acidentes que aconteceram no Brasil nos

  5. Certificao Sun Para Programador

    E-Print Network [OSTI]

    Energia Espaço Informática Materiais Mecânica Meio ambiente Nanotecnologia Robótica Plantão Modelio System/ cel. no Brasil Pague menos nas suas chamadas Apenas 0,08 ¢ p/ min. para celular www.local03.com/8centtoBrasil Anúncios Google Monitorar Rede Flutuantes Monitoramento Rede Sign Up for mail.com Mail

  6. Sesso Temtica: Monitoramento orbital das pastagens Brasileiras: em busca de uma pecuria mais produtiva e ambientalmente sustentvel (Orbital monitoring of the Brazilian pasturelands: in search of a more productive and environmentally sustainable cattle

    E-Print Network [OSTI]

    Brasil alcançar suas metas de redução de gases de efeito estufa, bem como reduzir a perda de habitats a área e a localização das pastagens degradadas no Brasil? 2) Quais são os impactos das pastagens degradadas nos fluxos de carbono e energia? 3) Quais são as tendências de produtividade das pastagens nas

  7. Comportamento espectro-temporal da cana-de-acar: uma nova proposta na distribuio espacial dos pontos de controle utilizados na interpolao de

    E-Print Network [OSTI]

    Hammerton, James

    Campos - SP, Brasil {pupin, bernardo, daniel}@dsr.inpe.br 2 Universidade Federal de Viçosa - UFV Campus Universitário ­ 36570-000 - Viçosa - MG, Brasil carlos.vieira@ufv.br Abstract. The major attribute of remotely do Brasil quanto nas questões ambientais internacionais relacionadas com a redução da emissão de

  8. Waste Management

    SciTech Connect (OSTI)

    NONE

    1999-10-01T23:59:59.000Z

    Subjects covered in this section are: (1) DOE's draft EIS on Yucca Mountain an important milestone; (2) EPA issues draft standards for Yucca Mountain; (3) Wisconsin Electric files spent fuel suit against DOE, asks for stay; (4) Transportation impacts considered in amended NRC rule; (5) Chem-Nuclear for sale: Bechtel/NAS pact: and other business developments; and (6) Rollin' up the river: Trojan's last voyage.

  9. FSICA MODERNA I -2o SEMESTRE 2008 6a LISTA DE EXERCCIOS

    E-Print Network [OSTI]

    Ribas, Roberto Vicençotto

    potencial de altura Vo nas mesmas condições. 5.- Uma reação de fusão importante na produção de energia solar obtido em medidas da quantidade de movimento da partícula neste estado? (b) ? a energia mecânica conservada neste estado? Se sua resposta for positiva, determine o valor da energia. Se for negativa

  10. Mec^anica Geometrica A entregar ate `a aula de Quarta-feira dia 27 de Outubro

    E-Print Network [OSTI]

    Natário, José

    Sistema Solar conservam o momento angular mas tendem a dissipar energia). 3. (a) Mostre que a express¸c~oes em torno de e3 s~ao est´aveis. (c) Se I1 > I2 > I3 ent~ao para um dado momento angular a energia cin~ao local da energia cin´etica de um corpo r´igido com um ponto fixo e I1 = I2 nas coordenadas de TSO(3

  11. MESTRADO EM MICROBIOLOGIA GENMICA FUNCIONAL E COMPARATIVA Instituto Superior Tcnico

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    de proteínas 3. Análise filogenética com base em mapas de sintenia 4. Análise quantitativa de geis bidimensionais 5. Interpretação do significado biológico de dados à escala do genoma 6. Análise de dados de Edições Técnicas, Lisboa, Portugal, 2007 *Sá-Correia I., Teixeira M.C., Two-dimensional Electrophoresis-based

  12. ISSN 0103-9741 Monografias em Cincia da Computao

    E-Print Network [OSTI]

    Endler, Markus

    proteínas. Palavras-chave: Esquema Lógico, Base de Dados Biológicos, Integração de Dados, Alinhamento de uma grande quantidade de dados, e permitido à comunidade científica o estudo da estrutura, organização desses dados biológicos, sem que haja comprometimento da interpretação e compreensão dos sistemas

  13. Anlise Preliminar de um Processo para Identificao

    E-Print Network [OSTI]

    Neshich, Goran

    Homology-derived Structures of Proteins (HSSP) é uma base de dados que agrega informações de proteínas com arquivo que relata um alinhamento formado por seqüências homólogas obtidas da base de dados de seqüências disponível para arquivos PDBs recentes e ainda não processados pelo HSSP. Além disso, como os dados do HSSP

  14. Um quinto dos cursos tem taxa

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    Eco- nómico teve acesso - que está a servir de base para a decisão das novas vagas a abrir nas uni no primeiro trimestre deste ano. ? a partir destes dados, for- necidos pelo lEFP, que a tutela actualiza o os estudantes associem es- tes dados à qualidade das insti- tuições e frisa: "O que estes da- dos

  15. Reconstruc~ao de Objetos 3D usando Modelos Deform aveis Rosana Marques da Silva

    E-Print Network [OSTI]

    ~ao A reconstruc~ao de modelos 3D a partir de imagens pode ser, convenientemente, separado em dois est a- gios. O amostrados nas imagens, enquanto o segundo concentra-se na transformac~ao dessas in- formac~oes em um modelo equilibrio energia m nima. As forcas externas s~ao estimadas a partir de informac~oes extra das das imagens

  16. reconstrudos ALERTA Peritos acusam Gover-

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    primeiro regulamento de estruturas que impunha o cál- culo dos efeitos dos sismos nas construções. Cerca de custos materiais e humanos. "Para ter o mesmo número de mortes de 1755 não é preciso um sismo igual Lisboa a vi- ver em casas não construídas a contar com os sismos é hoje muito maior do que era nessa

  17. Inertial confinement fusion. Quarterly report, July--September 1995, Volume 5, Number 4

    SciTech Connect (OSTI)

    NONE

    1996-06-01T23:59:59.000Z

    The 1990 National Academy of Sciences (NAS) final report recommended proceeding with the construction of a 1- to 2-MJ Nd-doped glass laser designed to achieve ignition in the laboratory (a laser originally called the Nova Upgrade, but now called the National Ignition Facility, or NIF, and envisioned as a national user facility). As a prerequisite, the report recommended completion of a series of target physics objectives on the Nova laser in use at the Lawrence Livermore National Laboratory (LLNL). Meeting these objectives, which were called the Nova Technical Contract (NTC), would demonstrate (the Academy committee believed) that the physics of ignition targets was understood well enough that the laser requirements could be accurately specified. Completion of the NTC objectives was given the highest priority in the NAS report. The NAS committee also recommended a concentrated effort on advanced target design for ignition. As recommended in the report, completion of these objectives has been the joint responsibility of LLNL and the Los Alamos National Laboratory. Most of the articles in this issue of the ICF Quarterly were written jointly by scientists from both institutions. Several of the NTC objectives required the completion of improvements to Nova`s power balance and pointing accuracy and of new diagnostics and new target fabrication capabilities. These improvements were called {open_quotes}Precision Nova{close_quotes} and are documented. The original NTC objectives have been largely met. This Introduction summarizes those objectives and their motivation in the context of the requirements for ignition. The articles that follow describe the NIF ignition target designs and summarize the principal accomplishments in the various elements of the NTC.

  18. Weapons-grade plutonium dispositioning. Volume 2: Comparison of plutonium disposition options

    SciTech Connect (OSTI)

    Brownson, D.A.; Hanson, D.J.; Blackman, H.S. [and others

    1993-06-01T23:59:59.000Z

    The Secretary of Energy requested the National Academy of Sciences (NAS) Committee on International Security and Arms Control to evaluate disposition options for weapons-grade plutonium. The Idaho National Engineering Laboratory (INEL) offered to assist the NAS in this evaluation by investigating the technical aspects of the disposition options and their capability for achieving plutonium annihilation levels greater than 90%. This report was prepared for the NAS to document the gathered information and results from the requested option evaluations. Evaluations were performed for 12 plutonium disposition options involving five reactor and one accelerator-based systems. Each option was evaluated in four technical areas: (1) fuel status, (2) reactor or accelerator-based system status, (3) waste-processing status, and (4) waste disposal status. Based on these evaluations, each concept was rated on its operational capability and time to deployment. A third rating category of option costs could not be performed because of the unavailability of adequate information from the concept sponsors. The four options achieving the highest rating, in alphabetical order, are the Advanced Light Water Reactor with plutonium-based ternary fuel, the Advanced Liquid Metal Reactor with plutonium-based fuel, the Advanced Liquid Metal Reactor with uranium-plutonium-based fuel, and the Modular High Temperature Gas-Cooled Reactor with plutonium-based fuel. Of these four options, the Advanced Light Water Reactor and the Modular High Temperature Gas-Cooled Reactor do not propose reprocessing of their irradiated fuel. Time constraints and lack of detailed information did not allow for any further ratings among these four options. The INEL recommends these four options be investigated further to determine the optimum reactor design for plutonium disposition.

  19. PRIMEIRA LISTA -FI-195 1. Considere uma particula em queda livre vertical onde a dist^ancia inicial

    E-Print Network [OSTI]

    de Aguiar, Marcus A. M.

    , ..., xn)dxi = 0 . Um v´inculo desse tipo ´e holon^omico apenas se existir uma fun¸c~ao f(x1, x2, ..., xn´inculos s~ao n~ao-holon^omicos. 5. Duas rodas de raio a s~ao montadas nas pontas de um eixo de tamanho b de´inculos n~ao-holon^omicos dados por cos dx + sin dy = 0 sin dx - cos dy = a 2 (d + d ) e um v´inculo holon

  20. High-current, fast-switching transistor development

    SciTech Connect (OSTI)

    Hower, P.L.

    1981-03-15T23:59:59.000Z

    Work that shows how the results obtained under a previous contract (NAS3-18916) have been applied to a larger-diameter (33-mm) transistor are described. An improved base contact for equalizing the base-emitter voltage at high currents has been developed along with an improved emitter contact preform which increases the silicon area available for current conduction. The electrical performance achieved is consistent with the proposed optimum design. The device design, wafer-processing techniques, and various measurements which include forward SOA, dc characteristics, and switching times are described.

  1. A phenological study of selected vascular plants of Brazos and Leon Counties, Texas, 1972

    E-Print Network [OSTI]

    Clark, Carolyn A

    1973-01-01T23:59:59.000Z

    flowering initially. February 28 - March 5 Carukunine panvi gona var. anenicoLa Senecio ampuUaceus Cents canadenaia Tnadeacantia aubacauLQ CongdaLia aunea Pea cunaini a pinnata Pnunua merci cana Saw a)nas aLbidum CaakiLLeja indivisa VioLa Lang... miaaowuenaia February '14 - February 20 Jaaminum paimuGnum Ceecia canadenaka February 21 - February 27 February 28 - Harch 5 Paunua angua&)olia hledi cago polgamapha var. vulgaaia Loni ceaa a empeaviaena Caalille ja indiviaa Queacua kleflaia Phlox...

  2. Attachment 3 Segmented Gate System

    E-Print Network [OSTI]

    7500-912 MOD 0.42 0.63 06/3.3/00 0 6 / 2 9 / 0 0165103 67 IS0 THORIUM (SHORT CT) NAS & DOE MOD p C i-725 orium 228 0.54 J 0.25 0.16 06/13/00 06/16/0 0165257 67 Thorium 230 0.58 J 0.25 0.03 06/13/00 06/16/0 0165257 67 0.64 J 0.26 0.05 0-6/13/00 06/16/0 0165257 67Thorium 232 a I NOTE (9) Data arm incamplate

  3. Magnetization relaxation in (Ga,Mn)As ferromagnetic semiconductors

    E-Print Network [OSTI]

    Sinova, Jairo; Jungwirth, T.; Liu, X.; Sasaki, Y.; Furdyna, JK; Atkinson, WA; MacDonald, AH.

    2004-01-01T23:59:59.000Z

    description of ferromagnetism in many diluted magnetic semiconductors ~DMS?s!, ~Ga,M- n!As in particular.2,3 Exchange-coupling between local mo- ments and itinerant electrons should also contribute signifi- 0163-1829/2004/69~8!/085209~6!/$22.50 69 085209... suggests g contributes significantly to the damping rate of the g the theoretical Gilbert coefficient with the values typical critical current for spin-transfer magnetization s low as ;105 A cm22. PACS number~s!: 73.20.Mf, 73.40.2c, 85.75.2d curate...

  4. A Previously Unrecorded Fragment of the Middle English Short Metrical Chronicle in Bibliotheca Philosophica Hermetica M199

    E-Print Network [OSTI]

    Grund, Peter

    2006-06-01T23:59:59.000Z

    be teo (CFR), to be (D), comen (different word order A), absent (B) 43 his is (BDFR), e (C), & when at Bladud was ded (different construction, A) 44 yeade wende 45 was nas (ABDFR), ne was (C) 56 gonnehold Denewold 62 had he he hadde 63 ye... bathe: BPH M199 seems to intend the actual salt bath, while the other manuscripts mention the city of Bath. 43 his mr: his probably refer to sowle in line 44. The other manuscripts use this, the or use a different construction (see the table...

  5. A Dharani-mantra in the Vinaya-vastu

    E-Print Network [OSTI]

    Pathak, Suniti K.

    1989-01-01T23:59:59.000Z

    offence (Vinaya-pitaka, Culla-vagga, V. 8.2. (PTS edn). See also' KevaUa SuUa (No. 11) Vol. p 214 (PTS edn). 4. Dutt, N. Early Monastic Buddhism p. 153-158, Calcutta, 1960. 5. Sukomal Choudhuri : Contemporary Buddhism in Bangladesh pp 116... dag gis zas sbyar na ji Ita bu yin pa ma ses nasI de rnams kyi sman pa la dris pa dan{ des _ smras pal 'phags pa dag kyed nyid kyi Slon pa beom Idan 'das ei thams cad (46b:2) mkhyen pa thams edd gzigs pa kho ns nyid yin tel de nyid mkhyen Ie zhes...

  6. Coping with Hot Work Environments (Spanish)

    E-Print Network [OSTI]

    Smith, David

    2005-04-28T23:59:59.000Z

    exter- nas. Bajo condiciones moderadas, el cerebro autom?ti- camente balancea el calor del cuerpo al monitorear el calor de la sangre. Sin embargo, cuando la temperatura de la sangre excede 98.6 grados F, el cerebro autom?ti- camente toma medidas para... y obtenga una buena nu- trici?n para poder tolerar el calor. ? Evite tomar bebidas alcoh?licas ya que causan deshidrataci?n adicional. ? Consulte a su m?dico si usted toma medicinas especiales. ? Evite la p?rdida significativa de peso causada por...

  7. Reconstruc~ao de Objetos 3D usando Modelos Deform'aveis Rosana Marques da Silva \\Lambda Wu, ShinTing

    E-Print Network [OSTI]

    ¸c~ao A reconstru¸c~ao de modelos 3D a partir de imagens pode ser, convenientemente, separado em dois est'a­ gios. O¸c~ao, de pontos amostrados nas imagens, enquanto o segundo concentra­se na transforma¸c~ao dessas in­ forma a partir de informa¸c~oes extra'idas das imagens. O m'etodo proposto por n'os est'a baseado no modelo de

  8. Deteco Automtica de Contornos com Gerao de Superfcies em Dados Volumtricos

    E-Print Network [OSTI]

    Imagens, Imagens Médicas e Visualização Volumétrica. 1. Introdução Com o avanço tecnológico, novos métodos principalmente nas imagens oriundas de exames (CT, RM, ultra­som, etc.) como forma de auxílio para o diagnóstico exemplos para o estudo de imagens médicas, embora tudo o que for discutido seja também válido para

  9. Comparison of Vehicle Efficiency Technology Attributes and Synergy Estimates

    SciTech Connect (OSTI)

    Duleep, G.

    2011-02-01T23:59:59.000Z

    Analyzing the future fuel economy of light-duty vehicles (LDVs) requires detailed knowledge of the vehicle technologies available to improve LDV fuel economy. The National Highway Transportation Safety Administration (NHTSA) has been relying on technology data from a 2001 National Academy of Sciences (NAS) study (NAS 2001) on corporate average fuel economy (CAFE) standards, but the technology parameters were updated in the new proposed rulemaking (EPA and NHTSA 2009) to set CAFE and greenhouse gas standards for the 2011 to 2016 period. The update is based largely on an Environmental Protection Agency (EPA) analysis of technology attributes augmented by NHTSA data and contractor staff assessments. These technology cost and performance data were documented in the Draft Joint Technical Support Document (TSD) issued by EPA and NHTSA in September 2009 (EPA/NHTSA 2009). For these tasks, the Energy and Environmental Analysis (EEA) division of ICF International (ICF) examined each technology and technology package in the Draft TSD and assessed their costs and performance potential based on U.S. Department of Energy (DOE) program assessments. ICF also assessed the technologies? other relevant attributes based on data from actual production vehicles and from recently published technical articles in engineering journals. ICF examined technology synergy issues through an ICF in-house model that uses a discrete parameter approach.

  10. Understanding and Mitigating Multicore Performance Issues on theAMD Opteron Architecture

    SciTech Connect (OSTI)

    Levesque, John; Larkin, Jeff; Foster, Martyn; Glenski, Joe; Geissler, Garry; Whalen, Stephen; Waldecker, Brian; Carter, Jonathan; Skinner, David; He, Helen; Wasserman, Harvey; Shalf, John; Shan,Hongzhang; Strohmaier, Erich

    2007-03-07T23:59:59.000Z

    Over the past 15 years, microprocessor performance hasdoubled approximately every 18 months through increased clock rates andprocessing efficiency. In the past few years, clock frequency growth hasstalled, and microprocessor manufacturers such as AMD have moved towardsdoubling the number of cores every 18 months in order to maintainhistorical growth rates in chip performance. This document investigatesthe ramifications of multicore processor technology on the new Cray XT4?systems based on AMD processor technology. We begin by walking throughthe AMD single-core and dual-core and upcoming quad-core processorarchitectures. This is followed by a discussion of methods for collectingperformance counter data to understand code performance on the Cray XT3?and XT4? systems. We then use the performance counter data to analyze theimpact of multicore processors on the performance of microbenchmarks suchas STREAM, application kernels such as the NAS Parallel Benchmarks, andfull application codes that comprise the NERSC-5 SSP benchmark suite. Weexplore compiler options and software optimization techniques that canmitigate the memory bandwidth contention that can reduce computingefficiency on multicore processors. The last section provides a casestudy of applying the dual-core optimizations to the NAS ParallelBenchmarks to dramatically improve their performance.

  11. Establishment of the United States Navy Mine Warfare Center of Excellence in the Corpus Christi Bay Area, Texas

    SciTech Connect (OSTI)

    Kosclski, J.L.; Boyer, R. [Turner Collie and Braden, Inc., Houston, TX (United States); Sloger, W. [Naval Facilities Engineering Command, North Charleston, SC (United States). Southern Div.

    1997-08-01T23:59:59.000Z

    The proposed establishment of the US Navy Mine Warfare Center of Excellence (MWCE) in the Corpus Christi Bay Area, Texas, involved the collocation of the Navy`s Mine Warfare and Mine Counter Measures assets in proximity to each other at Naval Station (NAVSTA) Ingleside and Naval Air Station (NAS) Corpus Christi, Texas. Collocation of these Navy forces would provide significant advantages in meeting mission and operational requirements. This action would improve the operational training and readiness of the forces. In addition to new construction or modifications at NAVSTA Ingleside, NAS Corpus Christi, and off-base; the establishment of offshore training and operating areas was required. When the project was first proposed in 1993, considerable concern was expressed by environmental interests, shrimpers, and state and federal resource agencies regarding the impact of the proposed training activities within Gulf waters. The Navy and Turner Collie and Braden, Inc., under contract to the Navy, conducted several technical studies and extensive coordination with concerned interests during the environmental impact statement process to identify and document the potential intensity, magnitude, and duration of impact from each proposed training activity.

  12. Study of plutonium disposition using existing GE advanced Boiling Water Reactors

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    The end of the cold war and the resulting dismantlement of nuclear weapons has resulted in the need for the US to dispose of 50 to 100 metric tons of excess of plutonium in a safe and proliferation resistant manner. A number of studies, including the recently released National Academy of Sciences (NAS) study, have recommended conversion of plutonium into spent nuclear fuel with its high radiation barrier as the best means of providing permanent conversion and long-term diversion resistance to this material. The NAS study ``Management and Disposition of Excess Weapons Plutonium identified Light Water Reactor spent fuel as the most readily achievable and proven form for the disposition of excess weapons plutonium. The study also stressed the need for a US disposition program which would enhance the prospects for a timely reciprocal program agreement with Russia. This summary provides the key findings of a GE study where plutonium is converted into Mixed Oxide (MOX) fuel and a typical 1155 MWe GE Boiling Water Reactor (BWR) is utilized to convert the plutonium to spent fuel. A companion study of the Advanced BWR has recently been submitted. The MOX core design work that was conducted for the ABWR enabled GE to apply comparable fuel design concepts and consequently achieve full MOX core loading which optimize plutonium throughput for existing BWRs.

  13. Federal Aviation Administration National Engine Generator Replacement Project

    SciTech Connect (OSTI)

    Sturm, C.C.

    1995-12-31T23:59:59.000Z

    The Federal Aviation Administration (FAA) is undertaking a major project to replace aging engine generators over the next few years. The engine generators currently installed at various National Airspace System (NAS) facilities such as airport traffic control towers and radars provide standby power critical to the safe operation of air traffic in the NAS. This paper will describe the FAA engine generator set (EGS) replacement decision process, procurement options, technical requirements and installation criteria to replace up to 3,000 existing EGS`s and establish additional EGS`s for new equipment installations. Each EGS includes an engine, alternator, automatic transfer switch, load bank, environmentally safe day tank and battery charger. Buying commercial-off-the-shelf (COTS) EGS equipment instead of using a development procurement with a detailed technical specification, provides an opportunity to do business in a new way for the FAA and a vehicle to procure EGS`s with proven quality and performance. Logistics support (parts support) will be provided by the COTS EGS supplier at a fixed cost over the five year contract life. Pre-award EGS benchmark testing gave the FAA an opportunity to closely look at EGS`s recently manufactured and configured to simulate an actual FAA installation.

  14. Key Geomechanics Issues at the Waste Isolation Pilot Plant Geomechanics

    SciTech Connect (OSTI)

    HANSEN,FRANCIS D.

    1999-09-01T23:59:59.000Z

    Mechanical and hydrological properties of rock salt provide excellent bases for geological isolation of hazardous materials. Regulatory compliance determinations for the Waste Isolation Pilot Plant (WIPP) stand as testament to the widely held conclusion that salt provides excellent isolation properties. The WIPP saga began in the 1950s when the U.S. National Academy of Sciences (NAS) recommended a salt vault as a promising solution to the national problem of nuclear waste disposal. For over 20 years, the Scientific basis for the NAS recommendation has been fortified by Sandia National Laboratories through a series of large scale field tests and laboratory investigations of salt properties. These scientific investigations helped develop a comprehensive understanding of salt's 4 reformational behavior over an applicable range of stresses and temperatures. Sophisticated constitutive modeling, validated through underground testing, provides the computational ability to model long-term behavior of repository configurations. In concert with advancement of the mechanical models, fluid flow measurements showed not only that the evaporite lithology was essentially impermeable but that the WIPP setting was hydrologically inactive. Favorable mechanical properties ensure isolation of materials placed in a salt geological setting. Key areas of the geomechanics investigations leading to the certification of WIPP are in situ experiments, laboratory tests, and shaft seal design.

  15. Characterizing Computation-Communication Overlap in Message-Passing Systems

    SciTech Connect (OSTI)

    David E. Bernholdt; Jarek Nieplocha; P. Sadayappan; Aniruddha G. Shet; Vinod Tipparaju

    2008-01-31T23:59:59.000Z

    Effective overlap of computation and communication is a well understood technique for latency hiding and can yield significant performance gains for applications on high-end computers. In this report, we describe an instrumentation framework developed for messagepassing systems to characterize the degree of overlap of communication with computation in the execution of parallel applications. The inability to obtain precise time-stamps for pertinent communication events is a significant problem, and is addressed by generation of minimum and maximum bounds on achieved overlap. The overlap measures can aid application developers and system designers in investigating scalability issues. The approach has been used to instrument two MPI implementations as well as the ARMCI system. The implementation resides entirely within the communication library and thus integrates well with existing approaches that operate outside the library. The utility of the framework is demonstrated by analyzing communication-computation overlap for micro-benchmarks and the NAS benchmarks, and the insights obtained are used to modify the NAS SP benchmark, resulting in improved overlap.

  16. National Assessment of Energy Storage for Grid Balancing and Arbitrage: Phase 1, WECC

    SciTech Connect (OSTI)

    Kintner-Meyer, Michael CW; Balducci, Patrick J.; Colella, Whitney G.; Elizondo, Marcelo A.; Jin, Chunlian; Nguyen, Tony B.; Viswanathan, Vilayanur V.; Zhang, Yu

    2012-06-01T23:59:59.000Z

    To examine the role that energy storage could play in mitigating the impacts of the stochastic variability of wind generation on regional grid operation, the Pacific Northwest National Laboratory (PNNL) examined a hypothetical 2020 grid scenario in which additional wind generation capacity is built to meet renewable portfolio standard targets in the Western Interconnection. PNNL developed a stochastic model for estimating the balancing requirements using historical wind statistics and forecasting error, a detailed engineering model to analyze the dispatch of energy storage and fast-ramping generation devices for estimating size requirements of energy storage and generation systems for meeting new balancing requirements, and financial models for estimating the life-cycle cost of storage and generation systems in addressing the future balancing requirements for sub-regions in the Western Interconnection. Evaluated technologies include combustion turbines, sodium sulfur (Na-S) batteries, lithium ion batteries, pumped-hydro energy storage, compressed air energy storage, flywheels, redox flow batteries, and demand response. Distinct power and energy capacity requirements were estimated for each technology option, and battery size was optimized to minimize costs. Modeling results indicate that in a future power grid with high-penetration of renewables, the most cost competitive technologies for meeting balancing requirements include Na-S batteries and flywheels.

  17. MOLECULAR APPROACHES FOR IN SITU IDENTIFCIATION OF NITRATE UTILIZATION BY MARINE BACTERIA AND PHYTOPLANKTON

    SciTech Connect (OSTI)

    Frischer, Marc E. [Skidaway Institute of Oceanography; Verity, Peter G.; Gilligan, Mathew R.; Bronk, Deborah A.; Zehr, Jonathan P.; Booth, Melissa G.

    2013-09-12T23:59:59.000Z

    Traditionally, the importance of inorganic nitrogen (N) for the nutrition and growth of marine phytoplankton has been recognized, while inorganic N utilization by bacteria has received less attention. Likewise, organic N has been thought to be important for heterotrophic organisms but not for phytoplankton. However, accumulating evidence suggests that bacteria compete with phytoplankton for nitrate (NO3-) and other N species. The consequences of this competition may have a profound effect on the flux of N, and therefore carbon (C), in ocean margins. Because it has been difficult to differentiate between N uptake by heterotrophic bacterioplankton versus autotrophic phytoplankton, the processes that control N utilization, and the consequences of these competitive interactions, have traditionally been difficult to study. Significant bacterial utilization of DIN may have a profound effect on the flux of N and C in the water column because sinks for dissolved N that do not incorporate inorganic C represent mechanisms that reduce the atmospheric CO2 drawdown via the ?biological pump? and limit the flux of POC from the euphotic zone. This project was active over the period of 1998-2007 with support from the DOE Biotechnology Investigations ? Ocean Margins Program (BI-OMP). Over this period we developed a tool kit of molecular methods (PCR, RT-PCR, Q-PCR, QRT-PCR, and TRFLP) and combined isotope mass spectrometry and flow-cytometric approaches that allow selective isolation, characterization, and study of the diversity and genetic expression (mRNA) of the structural gene responsible for the assimilation of NO3- by heterotrophic bacteria (nasA). As a result of these studies we discovered that bacteria capable of assimilating NO3- are ubiquitous in marine waters, that the nasA gene is expressed in these environments, that heterotrophic bacteria can account for a significant fraction of total DIN uptake in different ocean margin systems, that the expression of nasA is differentially regulated in genetically distinct NO3- assimilating bacteria, and that the best predictors of nasA gene expression are either NO3- concentration or NO3- uptake rates. These studies provide convincing evidence of the importance of bacterial utilization of NO3-, insight into controlling processes, and provide a rich dataset that are being used to develop linked C and N modeling components necessary to evaluate the significance of bacterial DIN utilization to global C cycling. Furthermore, as a result of BI-OMP funding we made exciting strides towards institutionalizing a research and education based collaboration between the Skidaway Institute of Oceanography (SkIO) and Savannah State University (SSU), an historically black university within the University System of Georgia with undergraduate and now graduate programs in marine science. The BI-OMP program, in addition to supporting undergraduate (24) graduate (10) and postdoctoral (2) students, contributed to the development of a new graduate program in Marine Sciences at SSU that remains an important legacy of this project. The long-term goals of these collaborations are to increase the capacity for marine biotechnology research and to increase representation of minorities in marine, environmental and biotechnological sciences.

  18. Installation of the first Distributed Energy Storage System (DESS) at American Electric Power (AEP).

    SciTech Connect (OSTI)

    Nourai, Ali (American Electric Power Company, Columbus, OH)

    2007-06-01T23:59:59.000Z

    AEP studied the direct and indirect benefits, strengths, and weaknesses of distributed energy storage systems (DESS) and chose to transform its entire utility grid into a system that achieves optimal integration of both central and distributed energy assets. To that end, AEP installed the first NAS battery-based, energy storage system in North America. After one year of operation and testing, AEP has concluded that, although the initial costs of DESS are greater than conventional power solutions, the net benefits justify the AEP decision to create a grid of DESS with intelligent monitoring, communications, and control, in order to enable the utility grid of the future. This report details the site selection, construction, benefits and lessons learned of the first installation, at Chemical Station in North Charleston, WV.

  19. Sodium/sulfur battery engineering for stationary energy storage. Final report

    SciTech Connect (OSTI)

    Koenig, A.; Rasmussen, J. [Silent Power, Inc., Salt Lake City, UT (United States)

    1996-04-01T23:59:59.000Z

    The use of modular systems to distribute power using batteries to store off-peak energy and a state of the art power inverter is envisioned to offer important national benefits. A 4-year, cost- shared contract was performed to design and develop a modular, 300kVA/300-kWh system for utility and customer applications. Called Nas-P{sub AC}, this system uses advanced sodium/sulfur batteries and requires only about 20% of the space of a lead-acid-based system with a smaller energy content. Ten, 300-VDC, 40-kWh sodium/sulfur battery packs are accommodated behind a power conversion system envelope with integrated digital control. The resulting design facilities transportation, site selection, and deployment because the system is quiet and non-polluting, and can be located in proximity to the load. This report contains a detailed description of the design and supporting hardware development performed under this contract.

  20. Exploiting Processor Groups to Extend Scalability of the GA Shared Memory Programming Model

    SciTech Connect (OSTI)

    Nieplocha, Jarek; Krishnan, Manoj Kumar; Palmer, Bruce J.; Tipparaju, Vinod; Zhang, Yeliang

    2005-05-04T23:59:59.000Z

    Exploiting processor groups is becoming increasingly important for programming next-generation high-end systems composed of tens or hundreds of thousands of processors. This paper discusses the requirements, functionality and development of multilevel-parallelism based on processor groups in the context of the Global Array (GA) shared memory programming model. The main effort involves management of shared data, rather than interprocessor communication. Experimental results for the NAS NPB Conjugate Gradient benchmark and a molecular dynamics (MD) application are presented for a Linux cluster with Myrinet and illustrate the value of the proposed approach for improving scalability. While the original GA version of the CG benchmark lagged MPI, the processor-group version outperforms MPI in all cases, except for a few points on the smallest problem size. Similarly, the group version of the MD application improves execution time by 58% on 32 processors.

  1. An economic study of the grain sorghum industry

    E-Print Network [OSTI]

    Williamson, Marion Newton

    1939-01-01T23:59:59.000Z

    ~ This 51?sp is has?a os haelillge xa these sea?trios they aro kskportaat articles of hosea 41st, as& fee4s fer it@est?eh as4 pealtryo Ivory portico ef tho pl?lit ie ?sod is e~ %aye 5 The first pmsaseat iaire4?otiose of 5saia s?r&hess is tho Celt?4 St.... Dicdcsoa& Oraia ~aalu&uae Versus ~ra pbr ctteaicN Lambs ~ 884, ~ ~oxXse~ae 4Ioxas ~~eu terai Sapor i~en Statiou, Bullotia No. 599, p. 8, April, 1988. Naa. & pp. 8-9. 0 %. Sarburtoa, ~ Soa-~~her 8e ~ger n~as Uaited States De~i o! Agriculture, Parasrs Bu...

  2. An efficient parallel algorithm for matrix-vector multiplication

    SciTech Connect (OSTI)

    Hendrickson, B.; Leland, R.; Plimpton, S.

    1993-03-01T23:59:59.000Z

    The multiplication of a vector by a matrix is the kernel computation of many algorithms in scientific computation. A fast parallel algorithm for this calculation is therefore necessary if one is to make full use of the new generation of parallel supercomputers. This paper presents a high performance, parallel matrix-vector multiplication algorithm that is particularly well suited to hypercube multiprocessors. For an n x n matrix on p processors, the communication cost of this algorithm is O(n/[radical]p + log(p)), independent of the matrix sparsity pattern. The performance of the algorithm is demonstrated by employing it as the kernel in the well-known NAS conjugate gradient benchmark, where a run time of 6.09 seconds was observed. This is the best published performance on this benchmark achieved to date using a massively parallel supercomputer.

  3. Study of plutonium disposition using the GE Advanced Boiling Water Reactor (ABWR)

    SciTech Connect (OSTI)

    NONE

    1994-04-30T23:59:59.000Z

    The end of the cold war and the resulting dismantlement of nuclear weapons has resulted in the need for the U.S. to disposition 50 to 100 metric tons of excess of plutonium in parallel with a similar program in Russia. A number of studies, including the recently released National Academy of Sciences (NAS) study, have recommended conversion of plutonium into spent nuclear fuel with its high radiation barrier as the best means of providing long-term diversion resistance to this material. The NAS study {open_quotes}Management and Disposition of Excess Weapons Plutonium{close_quotes} identified light water reactor spent fuel as the most readily achievable and proven form for the disposition of excess weapons plutonium. The study also stressed the need for a U.S. disposition program which would enhance the prospects for a timely reciprocal program agreement with Russia. This summary provides the key findings of a GE study where plutonium is converted into Mixed Oxide (MOX) fuel and a 1350 MWe GE Advanced Boiling Water Reactor (ABWR) is utilized to convert the plutonium to spent fuel. The ABWR represents the integration of over 30 years of experience gained worldwide in the design, construction and operation of BWRs. It incorporates advanced features to enhance reliability and safety, minimize waste and reduce worker exposure. For example, the core is never uncovered nor is any operator action required for 72 hours after any design basis accident. Phase 1 of this study was documented in a GE report dated May 13, 1993. DOE`s Phase 1 evaluations cited the ABWR as a proven technical approach for the disposition of plutonium. This Phase 2 study addresses specific areas which the DOE authorized as appropriate for more in-depth evaluations. A separate report addresses the findings relative to the use of existing BWRs to achieve the same goal.

  4. Hydrogen Scenario Analysis Summary Report: Analysis of the Transition to Hydrogen Fuel Cell Vehicles and the Potential Hydrogen Energy Infrastructure Requirements

    SciTech Connect (OSTI)

    Greene, David L [ORNL; Leiby, Paul Newsome [ORNL; James, Brian [Directed Technologies, Inc.; Perez, Julie [Directed Technologies, Inc.; Melendez, Margo [National Renewable Energy Laboratory (NREL); Milbrandt, Anelia [National Renewable Energy Laboratory (NREL); Unnasch, Stefan [Life Cycle Associates; Rutherford, Daniel [TIAX, LLC; Hooks, Matthew [TIAX, LLC

    2008-03-01T23:59:59.000Z

    Achieving a successful transition to hydrogen-powered vehicles in the U.S. automotive market will require strong and sustained commitment by hydrogen producers, vehicle manufacturers, transporters and retailers, consumers, and governments. The interaction of these agents in the marketplace will determine the real costs and benefits of early market transformation policies, and ultimately the success of the transition itself. The transition to hydrogen-powered transportation faces imposing economic barriers. The challenges include developing and refining a new and different power-train technology, building a supporting fuel infrastructure, creating a market for new and unfamiliar vehicles, and achieving economies of scale in vehicle production while providing an attractive selection of vehicle makes and models for car-buyers. The upfront costs will be high and could persist for a decade or more, delaying profitability until an adequate number of vehicles can be produced and moved into consumer markets. However, the potential rewards to the economy, environment, and national security are immense. Such a profound market transformation will require careful planning and strong, consistent policy incentives. Section 811 of the Energy Policy Act (EPACT) of 2005, Public Law 109-59 (U.S. House, 2005), calls for a report from the Secretary of Energy on measures to support the transition to a hydrogen economy. The report was to specifically address production and deployment of hydrogen-fueled vehicles and the hydrogen production and delivery infrastructure needed to support those vehicles. In addition, the 2004 report of the National Academy of Sciences (NAS, 2004), The Hydrogen Economy, contained two recommendations for analyses to be conducted by the U.S. Department of Energy (DOE) to strengthen hydrogen energy transition and infrastructure planning for the hydrogen economy. In response to the EPACT requirement and NAS recommendations, DOE's Hydrogen, Fuel Cells and Infrastructure Technologies Program (HFCIT) has supported a series of analyses to evaluate alternative scenarios for deployment of millions of hydrogen fueled vehicles and supporting infrastructure. To ensure that these alternative market penetration scenarios took into consideration the thinking of the automobile manufacturers, energy companies, industrial hydrogen suppliers, and others from the private sector, DOE held several stakeholder meetings to explain the analyses, describe the models, and solicit comments about the methods, assumptions, and preliminary results (U.S. DOE, 2006a). The first stakeholder meeting was held on January 26, 2006, to solicit guidance during the initial phases of the analysis; this was followed by a second meeting on August 9-10, 2006, to review the preliminary results. A third and final meeting was held on January 31, 2007, to discuss the final analysis results. More than 60 hydrogen energy experts from industry, government, national laboratories, and universities attended these meetings and provided their comments to help guide DOE's analysis. The final scenarios attempt to reflect the collective judgment of the participants in these meetings. However, they should not be interpreted as having been explicitly endorsed by DOE or any of the stakeholders participating. The DOE analysis examined three vehicle penetration scenarios: Scenario 1--Production of thousands of vehicles per year by 2015 and hundreds of thousands per year by 2019. This option is expected to lead to a market penetration of 2.0 million fuel cell vehicles (FCV) by 2025. Scenario 2--Production of thousands of FCVs by 2013 and hundreds of thousands by 2018. This option is expected to lead to a market penetration of 5.0 million FCVs by 2025. Scenario 3--Production of thousands of FCVs by 2013, hundreds of thousands by 2018, and millions by 2021 such that market penetration is 10 million by 2025. Scenario 3 was formulated to comply with the NAS recommendation: 'DOE should map out and evaluate a transition plan consistent with developing the infrastructure and hydrogen res

  5. Advanced Simulation Capability for Environmental Management (ASCEM) Phase II Demonstration

    SciTech Connect (OSTI)

    Freshley, M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hubbard, S. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Flach, G. [Savannah River National Lab. (SRNL), Aiken, SC (United States); Freedman, V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Agarwal, D. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Andre, B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Bott, Y. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Chen, X. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Davis, J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Faybishenko, B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Gorton, I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Murray, C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Moulton, D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Meyer, J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Rockhold, M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Shoshani, A. [LBNL; Steefel, C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wainwright, H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Waichler, S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2012-09-28T23:59:59.000Z

    In 2009, the National Academies of Science (NAS) reviewed and validated the U.S. Department of Energy Office of Environmental Management (EM) Technology Program in its publication, Advice on the Department of Energys Cleanup Technology Roadmap: Gaps and Bridges. The NAS report outlined prioritization needs for the Groundwater and Soil Remediation Roadmap, concluded that contaminant behavior in the subsurface is poorly understood, and recommended further research in this area as a high priority. To address this NAS concern, the EM Office of Site Restoration began supporting the development of the Advanced Simulation Capability for Environmental Management (ASCEM). ASCEM is a state-of-the-art scientific approach that uses an integration of toolsets for understanding and predicting contaminant fate and transport in natural and engineered systems. The ASCEM modeling toolset is modular and open source. It is divided into three thrust areas: Multi-Process High Performance Computing (HPC), Platform and Integrated Toolsets, and Site Applications. The ASCEM toolsets will facilitate integrated approaches to modeling and site characterization that enable robust and standardized assessments of performance and risk for EM cleanup and closure activities. During fiscal year 2012, the ASCEM project continued to make significant progress in capabilities development. Capability development occurred in both the Platform and Integrated Toolsets and Multi-Process HPC Simulator areas. The new Platform and Integrated Toolsets capabilities provide the user an interface and the tools necessary for end-to-end model development that includes conceptual model definition, data management for model input, model calibration and uncertainty analysis, and model output processing including visualization. The new HPC Simulator capabilities target increased functionality of process model representations, toolsets for interaction with the Platform, and model confidence testing and verification for quality assurance. The Platform and HPC capabilities are being tested and evaluated for EM applications through a suite of demonstrations being conducted by the Site Applications Thrust. In 2010, the Phase I Demonstration focused on testing initial ASCEM capabilities. The Phase II Demonstration, completed in September 2012, focused on showcasing integrated ASCEM capabilities. For Phase II, the Hanford Site Deep Vadose Zone (BC Cribs) served as an application site for an end-to-end demonstration of ASCEM capabilities on a site with relatively sparse data, with emphasis on integration and linkages between the Platform and HPC components. Other demonstrations included in this Phase II report included addressing attenuation-based remedies at the Savannah River Site F-Area, to exercise linked ASCEM components under data-dense and complex geochemical conditions, and conducting detailed simulations of a representative waste tank. This report includes descriptive examples developed by the Hanford Site Deep Vadose Zone, the SRS F-Area Attenuation-Based Remedies for the Subsurface, and the Waste Tank Performance Assessment working groups. The integrated Phase II Demonstration provides test cases to accompany distribution of the initial user release (Version 1.0) of the ASCEM software tools to a limited set of users in 2013. These test cases will be expanded with each new release, leading up to the release of a version that is qualified for regulatory applications in the 2015 time frame.

  6. SOLIDS PRECIPITATION EVENT IN MCU CAUSAL ANALYSIS AND RECOMMENDATIONS FROM SOLIDS RECOVERY TEAM

    SciTech Connect (OSTI)

    Garrison, A.; Aponte, C.

    2014-08-15T23:59:59.000Z

    A process upset occurred in the Modular Caustic-Side Solvent Extraction Unit (MCU) facility on April 6th, 2014. During recovery efforts, a significant amount of solids were found in the Salt Solution Feed Tank (SSFT), Salt Solution Receipt Tanks (SSRTs), two extraction contactors, and scrub contactors. The solids were identified by Savannah River National Laboratory (SRNL) as primarily sodium oxalate and sodium alumina silicate (NAS) with the presence of some aluminum hydroxide. NAS solids have been present in the SSFT since simulant runs during cold chemical startup of MCU in 2007, and have not hindered operations since that time. During the process upset in April 2014, the oxalate solids partially blocked the aqueous outlet of the extraction contactors, causing salt solution to exit through the contactor organic outlet to the scrub contactors with the organic phase. This salt solution overwhelmed the scrub contactors and passed with the organic phase to the strip section of MCU. The partially reversed flow of salt solution resulted in a Strip Effluent (SE) stream that was high in Isopar L, pH and sodium. The primary cause of the excessive solids accumulation in the SSRTs and SSFT at MCU is attributed to an increase in the frequency of oxalic acid cleaning of the 512-S primary filter. Agitation in the SSRTs at MCU in response to cold weather likely provided the primary mechanism to transfer the solids to the contactors. Sources of the sodium oxalate solids are attributed to the oxalic acid cleaning solution used to clean the primary filter at the Actinide Removal Process (ARP) filtration at 512-S, as well as precipitation from the salt batch feed, which is at or near oxalate saturation. The Solids Recovery Team was formed to determine the cause of the solids formation and develop recommendations to prevent or mitigate this event in the future. A total of 53 recommendations were generated. These recommendations were organized into 4 focus areas: Improve understanding of oxalate equilibrium and kinetics in salt solutions Reduction/elimination of oxalic acid cleaning in 512-S Flowsheet optimization Improving diagnostic capability The recommendations implemented prior to resumption of MCU operations provide a risk mitigation or detection function through additional sampling and observation. The longer term recommendations provide a framework to increase the basic process knowledge of both oxalate chemistry and filtration behavior and then facilitate decisions that improve the salt flowsheet as a system.

  7. Weapons-grade plutonium dispositioning. Volume 3: A new reactor concept without uranium or thorium for burning weapons-grade plutonium

    SciTech Connect (OSTI)

    Ryskamp, J.M.; Schnitzler, B.G.; Fletcher, C.D. [and others

    1993-06-01T23:59:59.000Z

    The National Academy of Sciences (NAS) requested that the Idaho National Engineering Laboratory (INEL) examine concepts that focus only on the destruction of 50,000 kg of weapons-grade plutonium. A concept has been developed by the INEL for a low-temperature, low-pressure, low-power density, low-coolant-flow-rate light water reactor that destroys plutonium quickly without using uranium or thorium. This concept is very safe and could be designed, constructed, and operated in a reasonable time frame. This concept does not produce electricity. Not considering other missions frees the design from the paradigms and constraints used by proponents of other dispositioning concepts. The plutonium destruction design goal is most easily achievable with a large, moderate power reactor that operates at a significantly lower thermal power density than is appropriate for reactors with multiple design goals. This volume presents the assumptions and requirements, a reactor concept overview, and a list of recommendations. The appendices contain detailed discussions on plutonium dispositioning, self-protection, fuel types, neutronics, thermal hydraulics, off-site radiation releases, and economics.

  8. Some evidence on determinants of fuel economy as a function of driving cycle and test type

    SciTech Connect (OSTI)

    Santini, D.J.; Anderson, J.

    1993-08-01T23:59:59.000Z

    Statistical methods are used with 107 vehicles whose fuel economy was presented and reported for five test types in a single publication by Consumers Union (CU) for 1986--1988 vehicles. Standard loglinear statistical formulations (i.e., multiplicative models of interactions) are used with data from this and supplementary sources to develop coefficients estimating the percent fuel economy gain per percent change in engine/vehicle design characteristic. The coefficients are developed for the five different test conditions evaluated by CU and are compared with each other on the basis of attributes of the tests. The insights of engineering models are used to develop expectations regarding the shift in size of coefficients as driving cycles change. In both the engineering models and the statistical model, the effect of weight is estimated to be higher in urban driving than in highway driving. For two test categories -- field tests and dynamometer tests -- the benefits of weight reduction are statistically estimated to be greatest in urban driving conditions. The effect on idle fuel flow rate of designing vehicles to hold performance roughly constant by maintaining power per kilogram and/or displacement per kilogram is examined, and its implication for the size of the weight effect is simply approximated from Sovran`s 1983 engineering model results. The fuel-economy-decreasing effect of the desire for performance is estimated to be somewhat larger in the statistical analysis than in the NAS study, when engine technology is held constant.

  9. Fusion Energy Advisory Committee (FEAC): Panel 7 report on Inertial Fusion Energy

    SciTech Connect (OSTI)

    Davidson, R.; Ripin, B.; Abdou, M.; Baldwin, D.E.; Commisso, R.; Dean, S.O.; Herrmannsfeldt, W.; Lee, E.; Lindl, J.; McCrory, R. [Princeton Univ., NJ (United States)] [and others

    1994-09-01T23:59:59.000Z

    The charge to FEAC Panel 7 on inertial fusion energy (IFE) is encompassed in the four articles of correspondence. To briefly summarize, the scope of the panel`s review and analysis adhered to the following guidelines. (1) Consistent with previous recommendations by the Fusion Policy Advisory Committee (FPAC) and the National Academy of Science (NAS) panel on inertial fusion, the principal focus of FEAC Panel 7`s review and planning activities for next-generation experimental facilities in IFE was limited to heavy ions. (2) The panel considered the three budget cases: $5M, $10M, and $15M annual funding at constant level-of-effort (FY92 dollars), with a time horizon of about five years. (3) While limiting the analysis of next-generation experimental facilities to heavy ions, the panel assessed both the induction and rf linac approaches, and factored European plans into its considerations as well. (4) Finally, the panel identified high-priority areas in system studies and supporting IFE technologies, taking into account how IFE can benefit from related activities funded by the Office of Fusion Energy and by Defense Programs. This report presents the technical assessment, findings, and recommendations on inertial fusion energy prepared by FEAC Panel 7.

  10. Development and evaluation of probability density functions for a set of human exposure factors

    SciTech Connect (OSTI)

    Maddalena, R.L.; McKone, T.E.; Bodnar, A.; Jacobson, J.

    1999-06-01T23:59:59.000Z

    The purpose of this report is to describe efforts carried out during 1998 and 1999 at the Lawrence Berkeley National Laboratory to assist the U.S. EPA in developing and ranking the robustness of a set of default probability distributions for exposure assessment factors. Among the current needs of the exposure-assessment community is the need to provide data for linking exposure, dose, and health information in ways that improve environmental surveillance, improve predictive models, and enhance risk assessment and risk management (NAS, 1994). The U.S. Environmental Protection Agency (EPA) Office of Emergency and Remedial Response (OERR) plays a lead role in developing national guidance and planning future activities that support the EPA Superfund Program. OERR is in the process of updating its 1989 Risk Assessment Guidance for Superfund (RAGS) as part of the EPA Superfund reform activities. Volume III of RAGS, when completed in 1999 will provide guidance for conducting probabilistic risk assessments. This revised document will contain technical information including probability density functions (PDFs) and methods used to develop and evaluate these PDFs. The PDFs provided in this EPA document are limited to those relating to exposure factors.

  11. Final Technical Summary: Center for Fundamental and Applied Research in Nanostructured and Lightweight Materials

    SciTech Connect (OSTI)

    Michael Mullins, Tony Rogers, Julia King, Jason Keith, Bahne Cornilsen, Jeffrey Allen, Ryan Gilbert, Joseph Holles.

    2010-09-28T23:59:59.000Z

    The core projects for this DOE-sponsored Center at Michigan Tech have focused on several of the materials problems identified by the NAS. These include: new electrode materials, enhanced PEM materials, lighter and more effective bipolar plates, and improvement of the carbon used as a current carrier. This project involved fundamental and applied research in the development and testing of lightweight and nanostructured materials to be used in fuel cell applications and for chemical synthesis. The advent of new classes of materials engineered at the nanometer level can produce materials that are lightweight and have unique physical and chemical properties. The grant was used to obtain and improve the equipment infrastructure to support this research and also served to fund seven research projects. These included: 1. Development of lightweight, thermally conductive bipolar plates for improved thermal management in fuel cells; 2. Exploration of pseudomorphic nanoscale overlayer bimetallic catalysts for fuel cells; 3. Development of hybrid inorganic/organic polymer nanocomposites with improved ionic and electronic properties; 4. Development of oriented polymeric materials for membrane applications; 5. Preparation of a graphitic carbon foam current collectors; 6. The development of lightweight carbon electrodes using graphitic carbon foams for battery and fuel cell applications; and 7. Movement of water in fuel cell electrodes.

  12. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01T23:59:59.000Z

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150C. The cells can even operate at 95C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  13. A Green Prison: Santa Rita Jail Creeps Towards Zero Net Energy (ZNE)

    SciTech Connect (OSTI)

    Marnay, Chris; DeForest, Nicholas; Stadler, Michael; Donadee, Jon; Dierckxsens, Carlos; Mendes, Goncalo; Lai, Judy; Cardoso, Goncalo Ferreira

    2011-03-18T23:59:59.000Z

    A large project is underway at Alameda County's twenty-year old 45 ha 4,000-inmate Santa Rita Jail, about 70 km east of San Francisco. Often described as a green prison, it has a considerable installed base of distributed energy resources including a seven-year old 1.2 MW PV array, a four-year old 1 MW fuel cell with heat recovery, and efficiency investments. A current US$14 M expansion will add approximately 2 MW of NaS batteries, and undetermined wind capacity and a concentrating solar thermal system. This ongoing effort by a progressive local government with considerable Federal and State support provides some excellent lessons for the struggle to lower building carbon footprint. The Distributed Energy Resources Customer Adoption Model (DER-CAM) finds true optimal combinations of equipment and operating schedules for microgrids that minimize energy bills and/or carbon emissions without 2 of 12 significant searching or rules-of-thumb prioritization, such as"efficiency first then on-site generation." The results often recommend complex systems, and sensitivities show how policy changes will affect choices. This paper reports an analysis of the historic performance of the PV system and fuel cell, describes the complex optimization applied to the battery scheduling, and shows how results will affect the jail's operational costs, energy consumption, and carbon footprint. DER-CAM is used to assess the existing and proposed DER equipment in its ability to reduce tariff charges.

  14. Integrating mechanistic and polymorphism data to characterize human genetic susceptibility for environmental chemical risk assessment in the 21st century

    SciTech Connect (OSTI)

    Mortensen, Holly M., E-mail: mortensen.holly@epa.gov [Office of Research and Development, US Environmental Protection Agency, National Center for Computational Toxicology, US EPA, 109 TW Alexander Dr., Mailcode B205-01, Research Triangle Park, NC 27711 (United States); Euling, Susan Y. [Office of Research and Development, US Environmental Protection Agency, National Center for Environmental Assessment, US EPA, 1200 Pennsylvania Ave., NW, Mail Code 8623P, Washington, DC 20460 (United States)

    2013-09-15T23:59:59.000Z

    Response to environmental chemicals can vary widely among individuals and between population groups. In human health risk assessment, data on susceptibility can be utilized by deriving risk levels based on a study of a susceptible population and/or an uncertainty factor may be applied to account for the lack of information about susceptibility. Defining genetic susceptibility in response to environmental chemicals across human populations is an area of interest in the NAS' new paradigm of toxicity pathway-based risk assessment. Data from high-throughput/high content (HT/HC), including -omics (e.g., genomics, transcriptomics, proteomics, metabolomics) technologies, have been integral to the identification and characterization of drug target and disease loci, and have been successfully utilized to inform the mechanism of action for numerous environmental chemicals. Large-scale population genotyping studies may help to characterize levels of variability across human populations at identified target loci implicated in response to environmental chemicals. By combining mechanistic data for a given environmental chemical with next generation sequencing data that provides human population variation information, one can begin to characterize differential susceptibility due to genetic variability to environmental chemicals within and across genetically heterogeneous human populations. The integration of such data sources will be informative to human health risk assessment.

  15. Machine characterization and benchmark performance prediction

    SciTech Connect (OSTI)

    Saavedra-Barrera, R.H.

    1988-12-01T23:59:59.000Z

    From runs of standard benchmarks or benchmark suites, it is not possible to characterize the machine nor to predict the run time of other benchmarks which have not been run. A new approach to benchmarking and machine characterization is reported. The creation and use of a machine analyzer is described, which measures the performance of a given machine on FORTRAN source language constructs. The machine analyzer yields a set of parameters which characterize the machine and spotlight its strong and weak points. Also described is a program analyzer, which analyzes FORTRAN programs and determines the frequency of execution of each of the same set of source language operations. It is then shown that by combining a machine characterization and a program characterization, we are able to predict with good accuracy the run time of a given benchmark on a given machine. Characterizations are provided for the Cray-X-MP/48, Cyber 205, IBM 3090/200, Amdahl 5840, Convex C-1, VAX 8600, VAX 11/785, VAX 11/780, SUN 3/50, and IBM RT-PC/125, and for the following benchmark programs or suites: Los Alamos (BMK8A1), Baskett, Linpack, Livermore Loops, Madelbrot Set, NAS Kernels, Shell Sort, Smith, Whetstone and Sieve of Erathostenes.

  16. Evaluation of Simple Causal Message Logging for Large-Scale Fault Tolerant HPC Systems

    SciTech Connect (OSTI)

    Bronevetsky, G; Meneses, E; Kale, L V

    2011-02-25T23:59:59.000Z

    The era of petascale computing brought machines with hundreds of thousands of processors. The next generation of exascale supercomputers will make available clusters with millions of processors. In those machines, mean time between failures will range from a few minutes to few tens of minutes, making the crash of a processor the common case, instead of a rarity. Parallel applications running on those large machines will need to simultaneously survive crashes and maintain high productivity. To achieve that, fault tolerance techniques will have to go beyond checkpoint/restart, which requires all processors to roll back in case of a failure. Incorporating some form of message logging will provide a framework where only a subset of processors are rolled back after a crash. In this paper, we discuss why a simple causal message logging protocol seems a promising alternative to provide fault tolerance in large supercomputers. As opposed to pessimistic message logging, it has low latency overhead, especially in collective communication operations. Besides, it saves messages when more than one thread is running per processor. Finally, we demonstrate that a simple causal message logging protocol has a faster recovery and a low performance penalty when compared to checkpoint/restart. Running NAS Parallel Benchmarks (CG, MG and BT) on 1024 processors, simple causal message logging has a latency overhead below 5%.

  17. Consortia Focused on Photovoltaic R&D, Manufacturing, and Testing: A Review of Existing Models and Structures

    SciTech Connect (OSTI)

    Coggeshall, C.; Margolis, R. M.

    2010-03-01T23:59:59.000Z

    As the U.S. Department of Energy's (DOE's) Solar Energy Technologies Program prepares to initiate a new cost-shared research and development (R&D) effort on photovoltaic (PV) manufacturing, it is useful to review the experience to date with consortia focused on PV R&D, manufacturing, and testing. Information was gathered for this report by conducting interviews and accessing Web sites of 14 U.S. consortia and four European consortia, each with either a primary focus on or an emerging interest in PV technology R&D, manufacturing, or testing. Additional input was collected from several workshops held by the DOE and National Academy of Sciences (NAS) in 2009, which examined the practical steps -- including public-private partnerships and policy support -- necessary to enhance the United States' capacity to competitively manufacture photovoltaics. This report categorizes the 18 consortia into three groups: university-led consortia, industry-led consortia, and manufacturing and testing facilities consortia. The first section summarizes the organizations within the different categories, with a particular focus on the key benefits and challenges for each grouping. The second section provides a more detailed overview of each consortium, including the origins, goals, organization, membership, funding sources, and key contacts. This survey is a useful resource for stakeholders interested in PV manufacturing R&D, but should not imply endorsement of any of these groups.

  18. Hp-41CV flight performance advisory system (FPAS) for the E-2c, E-2B, and C-2A aircraft. Final technical report Apr-Jun 82

    SciTech Connect (OSTI)

    Ferrell, D.R.

    1982-06-01T23:59:59.000Z

    This report describes follow-on work performed under the auspices of AE 4900, Directed Studies in Aeronautical Engineering at the Naval Postgraduate School, to complement the original design of a Flight Performance Advisory System (FPAS) for the E-2C aircraft. The original design fulfilled the requirements of AE 3001, Aircraft Energy Conservation. AE 3001, offered in the Fall Quarter 1981, and conducted by Professor Allen E. Fuhs, was sponsored in part by the Naval Air Development Center (NADC). NADC desired to obtain the input of several fleet experienced aviators in order to design program code for the HP-41CV handheld, programmable calculator that would benefit pilots by providing them with fuel efficiency parameters in flight. Calculators were made available to the participants with the proviso that a completed and operable code for each aircraft be submitted by the end of the academic quarter, September 1981. Upon completion of the E-2C program, attempts were made to use the calculator in flight. One test was conducted informally in an E-2C at RVAW-110, NAS Miramar. Unfortunately, the voltage field induced in the cockpit by the main lobe of the radar passing over the cockpit caused the calculator to cease functioning. The need to devise shielding for the calculator, plus the desire to simplify and improve the existing code lead to this effort.

  19. Scalable, efficient ion-photon coupling with phase Fresnel lenses for large-scale quantum computing

    E-Print Network [OSTI]

    E. W. Streed; B. G. Norton; J. J. Chapman; D. Kielpinski

    2008-05-16T23:59:59.000Z

    Efficient ion-photon coupling is an important component for large-scale ion-trap quantum computing. We propose that arrays of phase Fresnel lenses (PFLs) are a favorable optical coupling technology to match with multi-zone ion traps. Both are scalable technologies based on conventional micro-fabrication techniques. The large numerical apertures (NAs) possible with PFLs can reduce the readout time for ion qubits. PFLs also provide good coherent ion-photon coupling by matching a large fraction of an ion's emission pattern to a single optical propagation mode (TEM00). To this end we have optically characterized a large numerical aperture phase Fresnel lens (NA=0.64) designed for use at 369.5 nm, the principal fluorescence detection transition for Yb+ ions. A diffraction-limited spot w0=350+/-15 nm (1/e^2 waist) with mode quality M^2= 1.08+/-0.05 was measured with this PFL. From this we estimate the minimum expected free space coherent ion-photon coupling to be 0.64%, which is twice the best previous experimental measurement using a conventional multi-element lens. We also evaluate two techniques for improving the entanglement fidelity between the ion state and photon polarization with large numerical aperture lenses.

  20. Realizacao domestica e escolar de foto e video 3D

    E-Print Network [OSTI]

    Jose J. Lunazzi

    2012-12-19T23:59:59.000Z

    English: Industry does not give attention to the small domestic or professional market of digital technologies for 3D images. What was done on the XX century by using photographic film is not know available to the common people, though the facilities are even better. Some technique developed in Brasil twenty years ago and the use of conventional domestic photo or video cameras allows fot making pictures and films at home by using digital conversions for editing, and two-color goggles. The anaglyphic technique, the same NASA employs to show Mars images to the public, is not employed in Brazil yet. We must analize the reasons for that. Portugues: A industria nao tem dado atencao ao mercado domestico ou profissional de pequena escala nas novas tecnologias digitais para imagem 3D. O que foi feito ao longo do seculo XX usando filme fotografico nao esta hoje ao alcance das pessoas, sendo que a facilidade de uso e muito maior. Tecnicas desenvolvidas no Brasil ha mais de vinte anos, e o uso de simples cameras convencionais de fotografia e video permitem realizar fotos e filmes caseiros por meio de conversoes digitais na edicao e o uso de oculos bicolor. A tecnica anagifica, a mesma que a NASA usa para mostrar ao publico as imagens de Marte, por exemplo, nao teve espaco no Brasil ainda. Devemos analisar os motivos que podem estar influenciando e os caminhos para mudar isso.

  1. LLW Notes, Volume 12, Number 8

    SciTech Connect (OSTI)

    Norris, C.; Brown, H. [eds.; Gedden, R.; Lovinger, T.; Scheele, L.; Shaker, M.A.

    1997-12-31T23:59:59.000Z

    Contents include articles entitled: Chem-Nuclear documents new plan for Barnwell; Nebraska releases technical analysis of LLRW facility; Southeast Compact suspends funding for NC facility development; NC governor and Southeast Compact differ on proposed MOU; Midwest Compact to return export fees; State legislators` group revises radioactive waste policy; Internal documents discuss administration`s policy on Ward Valley; BLM issues EA for Ward Valley testing; California DHS, NRC criticize DOI`s testing protocols; Army removes training mines from Ward Valley site; The 1997 gubernatorial elections and a look ahead to 1998; Court throws out case challenging Pennsylvania`s siting law; DOE files notice of appeal in WCS suit; Central Compact moves to dismiss ``Veto`` authority suit; Congress exempts NAS from FACA; Judge sets schedule for Ward Valley case; Court won`t order DOE to accept spent fuel by deadline; NRC chairman expresses concern re CERCLA reauthorization; Senators question EPA`s guidance on remediation; EPA issues guidance, criticizes NRC decommissioning rule; Members of Congress clarify FUSRAP transfer; HLW legislation passes House by wide margin; Takings legislation passes House; Energy and water bill signed into law; and Senate confirms 5 of 6 DOE appointees.

  2. Band gap reduction in GaNSb alloys due to the anion mismatch

    SciTech Connect (OSTI)

    Veal, T.D.; Piper, L.F.J.; Jollands, S.; Bennett, B.R.; Jefferson, P.H.; Thomas, P.A.; McConville, C.F.; Murdin, B.N.; Buckle, L.; Smith, G.W.; Ashley, T. [Department of Physics, University of Warwick, Coventry, CV4 7AL (United Kingdom); School of Electronics and Physical Sciences, University of Surrey, Guildford, GU2 5XH (United Kingdom); QinetiQ Ltd., St. Andrews Road, Malvern, Worcestershire, WR14 3PS (United Kingdom)

    2005-09-26T23:59:59.000Z

    The structural and optoelectronic properties in GaN{sub x}Sb{sub 1-x} alloys (0{<=}x<0.02) grown by molecular-beam epitaxy on both GaSb substrates and AlSb buffer layers on GaAs substrates are investigated. High-resolution x-ray diffraction (XRD) and reciprocal space mapping indicate that the GaN{sub x}Sb{sub 1-x} epilayers are of high crystalline quality and the alloy composition is found to be independent of substrate, for identical growth conditions. The band gap of the GaNSb alloys is found to decrease with increasing nitrogen content from absorption spectroscopy. Strain-induced band-gap shifts, Moss-Burstein effects, and band renormalization were ruled out by XRD and Hall measurements. The band-gap reduction is solely due to the substitution of dilute amounts of highly electronegative nitrogen for antimony, and is greater than observed in GaNAs with the same N content.

  3. Energy Storage for Variable Renewable Energy Resource Integration - A Regional Assessment for the Northwest Power Pool (NWPP)

    SciTech Connect (OSTI)

    Kintner-Meyer, Michael CW; Jin, Chunlian; Balducci, Patrick J.; Elizondo, Marcelo A.; Guo, Xinxin; Nguyen, Tony B.; Tuffner, Francis K.; Viswanathan, Vilayanur V.

    2011-03-20T23:59:59.000Z

    This paper addresses the following key questions in the discussion on the integration of renewable energy resources in the Pacific Northwest power grid: a) what will be the future balancing requirement to accommodate a simulated expansion of wind energy resources from 3.3 GW in 2008 to 14.4 GW in 2019 in the Northwest Power Pool (NWPP), and b) what are the most cost effective technological solutions for meeting the balancing requirements in the Northwest Power Pool (NWPP). A life-cycle analysis was performed to assess the least-cost technology option for meeting the new balancing requirement. The technologies considered in this study include conventional turbines (CT), sodium sulfur (NaS) batteries, lithium ion (Li-ion) batteries, pumped hydro energy storage (PH), and demand response (DR). Hybrid concepts that combine 2 or more of the technologies above are also evaluated. This analysis was performed with collaboration by the Bonneville Power Administration and funded by the Energy Storage Systems Program of the U.S. Department of Energy.

  4. Bandgap Engineering in High-Efficiency Multijunction Concentrator Cells

    SciTech Connect (OSTI)

    King, R. R.; Sherif, R. A.; Kinsey, G. S.; Kurtz, S.; Fetzer, C. M.; Edmondson, K. M.; Law, D. C.; Cotal, H. L.; Krut, D. D.; Ermer, J. H.; Karam, N. H.

    2005-08-01T23:59:59.000Z

    This paper discusses semiconductor device research paths under investigation with the aim of reaching the milestone efficiency of 40%. A cost analysis shows that achieving very high cell efficiencies is crucial for the realization of cost-effective photovoltaics, because of the strongly leveraging effect of efficiency on module packaging and balance-of systems costs. Lattice-matched (LM) GaInP/ GaInAs/ Ge 3-junction cells have achieved the highest independently confirmed efficiency at 175 suns, 25?C, of 37.3% under the standard AM1.5D, low-AOD terrestrial spectrum. Lattice-mismatched, or metamorphic (MM), materials offer still higher potential efficiencies, if the crystal quality can be maintained. Theoretical efficiencies well over 50% are possible for a MM GaInP/ 1.17-eV GaInAs/ Ge 3-junction cell limited by radiative recombination at 500 suns. The bandgap - open circuit voltage offset, (Eg/q) - Voc, is used as a valuable theoretical and experimental tool to characterize multijunction cells with subcell bandgaps ranging from 0.7 to 2.1 eV. Experimental results are presented for prototype 6-junction cells employing an active {approx}1.1-eV dilute nitride GaInNAs subcell, with active-area efficiency greater than 23% and over 5.3 V open-circuit voltage under the 1-sun AM0 space spectrum. Such cell designs have theoretical efficiencies under the terrestrial spectrum at 500 suns concentration exceeding 55% efficiency, even for lattice-matched designs.

  5. Weapons-grade plutonium dispositioning. Volume 4. Plutonium dispositioning in light water reactors

    SciTech Connect (OSTI)

    Sterbentz, J.W.; Olsen, C.S.; Sinha, U.P.

    1993-06-01T23:59:59.000Z

    This study is in response to a request by the Reactor Panel Subcommittee of the National Academy of Sciences (NAS) Committee on International Security and Arms Control (CISAC) to evaluate the feasibility of using plutonium fuels (without uranium) for disposal in existing conventional or advanced light water reactor (LWR) designs and in low temperature/pressure LWR designs that might be developed for plutonium disposal. Three plutonium-based fuel forms (oxides, aluminum metallics, and carbides) are evaluated for neutronic performance, fabrication technology, and material and compatibility issues. For the carbides, only the fabrication technologies are addressed. Viable plutonium oxide fuels for conventional or advanced LWRs include plutonium-zirconium-calcium oxide (PuO{sub 2}-ZrO{sub 2}-CaO) with the addition of thorium oxide (ThO{sub 2}) or a burnable poison such as erbium oxide (Er{sub 2}O{sub 3}) or europium oxide (Eu{sub 2}O{sub 3}) to achieve acceptable neutronic performance. Thorium will breed fissile uranium that may be unacceptable from a proliferation standpoint. Fabrication of uranium and mixed uranium-plutonium oxide fuels is well established; however, fabrication of plutonium-based oxide fuels will require further development. Viable aluminum-plutonium metallic fuels for a low temperature/pressure LWR include plutonium aluminide in an aluminum matrix (PuAl{sub 4}-Al) with the addition of a burnable poison such as erbium (Er) or europium (Eu). Fabrication of low-enriched plutonium in aluminum-plutonium metallic fuel rods was initially established 30 years ago and will require development to recapture and adapt the technology to meet current environmental and safety regulations. Fabrication of high-enriched uranium plate fuel by the picture-frame process is a well established process, but the use of plutonium would require the process to be upgraded in the United States to conform with current regulations and minimize the waste streams.

  6. A perspective on safeguarding and monitoring of excess military plutonium

    SciTech Connect (OSTI)

    Sutcliffe, W.G.

    1994-10-02T23:59:59.000Z

    The purpose of this paper is to provide a perspective and framework for the development of safeguarding and monitoring procedures for the various stages of disposition of excess military plutonium. The paper briefly outlines and comments on some of the issues involved in safeguarding and monitoring excess military plutonium as it progresses from weapons through dismantlement, to fabrication as reactor fuel, to use in a reactor, and finally to storage and disposal as spent fuel. {open_quotes}Military{close_quotes} refers to ownership, and includes both reactor-grade and weapon-grade plutonium. {open_quotes}Excess{close_quotes} refers to plutonium (in any form) that a government decides is no longer needed for military use and can be irrevocably removed from military stockpiles. Many of the issues and proposals presented in this paper are based on, or are similar to, those mentioned in the National Academy of Sciences (NAS) report on excess military plutonium. Safeguards for plutonium disposition are discussed elsewhere in terms of requirements established by the U.S. Department of Energy (DOE), the U.S. Nuclear Regulatory Commission (NRC), and the International Atomic Energy Agency (IAEA). Here, the discussion is less specific. The term {open_quotes}safeguarding{close_quotes} is used broadly to refer to materials control and accountancy (MC&A), containment and surveillance (C&S), and physical protection of nuclear materials by the state that possesses those materials. This is also referred to as material protection, control, and accountancy (MPCA). The term {open_quotes}safeguarding{close_quotes} was chosen for brevity and to distinguish MPCA considered in this paper from international or IAEA safeguards. {open_quotes}Monitoring{close_quotes} is used to refer to activities designed to assure another party (state or international organization) that the nuclear materials of the host state (the United States or Russia) are secure and not subject to unauthorized use.

  7. Optimization of Trona/Limestone Injection for SO2 Control in Coal-Fired Boilers

    SciTech Connect (OSTI)

    None

    2005-09-01T23:59:59.000Z

    Mobotec USA develops and markets air pollution control systems for utility boilers and other combustion systems. They have a particular interest in technologies that can reduce NOx, SOx, and mercury emissions from coal-fired boilers, and have been investigating the injection of sorbents such as limestone and trona into a boiler to reduce SOx and Hg emissions. WRI proposed to use the Combustion Test Facility (CTF) to enable Mobotec to conduct a thorough evaluation of limestone and trona injection for SO{sub 2} control. The overall goal of the project was to characterize the SO{sub 2} reductions resulting from the injection of limestone and trona into the CTF when fired with a high-sulfur eastern bituminous coal used in one of Mobotec's Midwest installations. Results revealed that when limestone was injected at Ca:S molar ratios of 1.5 to 3.0, the resulting SO{sub 2} reductions were 35-55%. It is believed that further reductions can be attained with improved mixing of the sorbent with the combustion gases. When limestone was added to the coal, at Ca:S molar ratios of 0.5 to 1.5, the SO{sub 2} reductions were 13-21%. The lower reductions were attributed to dead-burning of the sorbent in the high temperature flame zone. In cases where limestone was both injected into the furnace and added to the coal, the total SO{sub 2} reductions for a given Ca:S molar ratio were similar to the reductions for furnace injection only. The injection of trona into the mid-furnace zone, for Na:S molar ratios of 1.4 to 2.4, resulted in SO{sub 2} reductions of 29-43%. Limestone injection did not produce any slag deposits on an ash deposition probe while trona injection resulted in noticeable slag deposition.

  8. Commercialization of New Lattice-Matched Multi-Junction Solar Cells Based on Dilute Nitrides: July 8, 2010 - March 7, 2012

    SciTech Connect (OSTI)

    Herb, J.

    2012-04-01T23:59:59.000Z

    Final Technical Progress Report for PV Incubator subcontract NAT-0-99013-03. The overall objective of this Incubator subcontract was to complete the work necessary to make commercial ready solar cells using the dilute nitride technology. The specific objectives of this program were aimed at completing the development of a triple-junction solar cell that incorporates a GaInNAs {approx}1eV subcell to the point of commercial readiness, and determining the cell reliability and, if necessary, identifying and eliminating process or material related issues that lead to early-life cell failures. There were three major objectives for Phase 1, each of which focuses on a key element of the solar cell that determines its performance in a commercial CPV system. One objective was to optimize the quality and performance of the key individual components making up the solar cell structure and then to optimize the integration of these components into a complete triple-junction cell. A second objective was to design and test anti-reflective coating that maximizes the light coupled into a 3J cell with a {approx}1 eV bottom cell bandgap. The third objective was to develop Highly Accelerated Life Tests (HALT) protocols and tools for identifying and correcting potential reliability problems. The Phase 2 objectives were a continuation of the work begun in Phase 1 but aimed at optimizing cell performance for commercial requirements. Phase 2 had four primary objectives: (1) develop a glass-matched anti-reflective coating (ARC) and optimize the cell/ARC to give good performance at 60C operating temperature, (2) optimize the cell for good operation at 60C and high concentration, and (3) complete the light biased HALT system and use it to determine what, if any, failures are observed, and (4) determine the reliability limits of the optimized cell.

  9. Smart Infrared Inspection System Field Operational Test Final Report

    SciTech Connect (OSTI)

    Siekmann, Adam [ORNL; Capps, Gary J [ORNL; Franzese, Oscar [ORNL; Lascurain, Mary Beth [ORNL

    2011-06-01T23:59:59.000Z

    The Smart InfraRed Inspection System (SIRIS) is a tool designed to assist inspectors in determining which vehicles passing through the SIRIS system are in need of further inspection by measuring the thermal data from the wheel components. As a vehicle enters the system, infrared cameras on the road measure temperatures of the brakes, tires, and wheel bearings on both wheel ends of commercial motor vehicles (CMVs) in motion. This thermal data is then presented to enforcement personal inside of the inspection station on a user friendly interface. Vehicles that are suspected to have a violation are automatically alerted to the enforcement staff. The main goal of the SIRIS field operational test (FOT) was to collect data to evaluate the performance of the prototype system and determine the viability of such a system being used for commercial motor vehicle enforcement. From March 2010 to September 2010, ORNL facilitated the SIRIS FOT at the Greene County Inspection Station (IS) in Greeneville, Tennessee. During the course of the FOT, 413 CMVs were given a North American Standard (NAS) Level-1 inspection. Of those 413 CMVs, 384 were subjected to a SIRIS screening. A total of 36 (9.38%) of the vehicles were flagged by SIRIS as having one or more thermal issues; with brakes issues making up 33 (91.67%) of those. Of the 36 vehicles flagged as having thermal issues, 31 (86.11%) were found to have a violation and 30 (83.33%) of those vehicles were placed out-of-service (OOS). Overall the enforcement personnel who have used SIRIS for screening purposes have had positive feedback on the potential of SIRIS. With improvements in detection algorithms and stability, the system will be beneficial to the CMV enforcement community and increase overall trooper productivity by accurately identifying a higher percentage of CMVs to be placed OOS with minimal error. No future evaluation of SIRIS has been deemed necessary and specifications for a production system will soon be drafted.

  10. A Job Pause Service under LAM/MPI+BLCR for Transparent Fault Tolerance

    SciTech Connect (OSTI)

    Wang, Chao [North Carolina State University; Mueller, Frank [North Carolina State University; Engelmann, Christian [ORNL; Scott, Steven L [ORNL

    2007-01-01T23:59:59.000Z

    Checkpoint/restart (C/R) has become a requirement for long-running jobs in large-scale clusters due to a meantime- to-failure (MTTF) in the order of hours. After a failure, C/R mechanisms generally require a complete restart of an MPI job from the last checkpoint. A complete restart, however, is unnecessary since all but one node are typically still alive. Furthermore, a restart may result in lengthy job requeuing even though the original job had not exceeded its time quantum. In this paper, we overcome these shortcomings. Instead of job restart, we have developed a transparent mechanism for job pause within LAM/MPI+BLCR. This mechanism allows live nodes to remain active and roll back to the last checkpoint while failed nodes are dynamically replaced by spares before resuming from the last checkpoint. Our methodology includes LAM/MPI enhancements in support of scalable group communicationwith fluctuating number of nodes, reuse of network connections, transparent coordinated checkpoint scheduling and a BLCR enhancement for job pause. Experiments in a cluster with the NAS Parallel Benchmark suite show that our overhead for job pause is comparable to that of a complete job restart. A minimal overhead of 5.6% is only incurred in case migration takes place while the regular checkpoint overhead remains unchanged. Yet, our approach alleviates the need to reboot the LAM run-time environment, which accounts for considerable overhead resulting in net savings of our scheme in the experiments. Our solution further provides full transparency and automation with the additional benefit of reusing existing resources. Executing continues after failures within the scheduled job, i.e., the application staging overhead is not incurred again in contrast to a restart. Our scheme offers additional potential for savings through incremental checkpointing and proactive diskless live migration, which we are currently working on.

  11. Preliminary Assessment of Overweight Mainline Vehicles

    SciTech Connect (OSTI)

    Siekmann, Adam [ORNL; Capps, Gary J [ORNL; Lascurain, Mary Beth [ORNL

    2011-11-01T23:59:59.000Z

    The Federal Motor Carrier Safety Administration requested information regarding overweight and oversized vehicle traffic entering inspection stations (ISs) in order to develop strategies for future research efforts and possibly help guide regulatory issues involving overweight commercial motor vehicles (CMVs). For a period of one month, inspection stations in Knox County and Greene County, Tennessee, recorded overweight and oversized vehicles that entered these ISs. During this period, 435 CMVs were recorded using an electronic form filled out by enforcement personnel at the IS. Of the 435 CMVs recorded, 381 had weight information documented with them. The majority (52.2%) of the vehicles recorded were five-axle combination vehicles, and 50.6% of all the vehicles were permitted to operate above the legal weight limit in Tennessee, which is 80,000 lb for vehicles with five or more axles. Only 16.8% of the CMVs recorded were overweight gross (11.5% of permitted vehicles) and 54.1% were overweight on an axle group. The low percentage of overweight gross CMVs was because only 45 of the vehicles over 80,000 lb. were not permitted. On average, axles that were overweight were 2,000 lb. over the legal limit for an axle or group of axles. Of the vehicles recorded, 172 vehicles were given a North American Standard (NAS) inspection during the assessment. Of those, 69% of the inspections were driver-only inspections (Level III) and only 25% of the inspections had a vehicle component (such as a Level I or Level II). The remaining 6% of inspections did not have valid Aspen numbers; the type of was inspection unknown. Data collected on the types of trailers of each vehicle showed that about half of the recorded CMVs could realistically be given a Level I (full vehicle and driver) inspection; this estimate was solely based on trailer type. Enforcement personnel at ISs without an inspection pit have difficulty fully inspecting certain vehicles due to low clearance below the trailer. Because of this, overweight and oversized vehicles were normally only given a Level III (driver) inspection; thus, little is known about the safety of these vehicles. The out-of-service (OOS) rate of all the inspected vehicles (driver and vehicle inspections) was 18.6%, while the OOS rate for vehicle inspections (Level I and II) was 52.4%. Future work will focus on performing Level I inspections on five-axle combination tractor-trailers and the types of violations that overweight vehicles may have. This research will be conducted in Tennessee and possibly in other states as well.

  12. A HOLISTIC APPROACH FOR DISPOSITION OF LONG-LIVED RADIOACTIVE MATERIALS

    SciTech Connect (OSTI)

    Eriksson, Leif G.; Dials, George E.; Parker, Frank L.

    2003-02-27T23:59:59.000Z

    During the past 45 years, one of the most challenging scientific, engineering, socio-economic, and political tasks and obligations of our time has been to site and develop technical, politically acceptable, solutions to the safe disposition of long-lived radioactive materials (LLRMs). However, at the end of the year 2002, the Waste Isolation Pilot Plant (WIPP) site in the United States of America (USA) hosts the world's only operating LLRM-disposal system, which (1) is based on the LLRM-disposal principles recommended by the National Academy of Sciences (NAS) in 1957, i.e., deep geological disposal in a ''stable'' salt vault/repository, (2) complies with the nation's ''Environmental Radiation Protection Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes'', and (3) may receive 175,584 cubic meters (m3) of transuranic radioactive waste (TRUW)a. Pending the scheduled opening of repositories for once-used nuclear fuel (OUNF) in the USA, Sweden, and Finland in the years 2010, 2015, and 2017, respectively, LLRM-disposal solutions remain the missing link in all national LLRM-disposition programs. Furthermore, for a variety of reasons, many nations with nuclear programs have chosen a ''spectator'' stance in terms of enhancing the global nuclear safety culture and the nuclear renaissance, and have either ''slow-tracked'' or deferred their LLRM-disposal programs to allow time for an informed national consensus to evolve based on LLRM-disposition experiences and solutions gained elsewhere. In the meantime, LLRMs will continue to amass in different types and levels of safeguarded storage facilities around the world. In an attempt to contribute to the enhancement of the global nuclear safety culture and the nuclear renaissance, the authors developed the sample holistic approach for synergistic disposition of LLRMs comprising LLRM-disposition components considered either ''proven'' or ''promising'' by the authors. The fundamental principles of the holistic approach are: (1) Risk minimization; (2) Minimization of the LLRM volume requiring deep geological disposal; and (3) LLRM-disposition flexibility. An integral element of these principles is to allow time for LLRM-disposition solutions to evolve/mature technically, financially, and politically. Furthermore, contingent upon the desired outcome(s), available financial, scientific, and technical resources, and political will, these components may be implemented separately or in combinations by one or a group of nations.

  13. Cost Effective Surfactant Formulations for Improved Oil Recovery in Carbonate Reservoirs

    SciTech Connect (OSTI)

    William A. Goddard; Yongchun Tang; Patrick Shuler; Mario Blanco; Yongfu Wu

    2007-09-30T23:59:59.000Z

    This report summarizes work during the 30 month time period of this project. This was planned originally for 3-years duration, but due to its financial limitations, DOE halted funding after 2 years. The California Institute of Technology continued working on this project for an additional 6 months based on a no-cost extension granted by DOE. The objective of this project is to improve the performance of aqueous phase formulations that are designed to increase oil recovery from fractured, oil-wet carbonate reservoir rock. This process works by increasing the rate and extent of aqueous phase imbibition into the matrix blocks in the reservoir and thereby displacing crude oil normally not recovered in a conventional waterflood operation. The project had three major components: (1) developing methods for the rapid screening of surfactant formulations towards identifying candidates suitable for more detailed evaluation, (2) more fundamental studies to relate the chemical structure of acid components of an oil and surfactants in aqueous solution as relates to their tendency to wet a carbonate surface by oil or water, and (3) a more applied study where aqueous solutions of different commercial surfactants are examined for their ability to recover a West Texas crude oil from a limestone core via an imbibition process. The first item, regarding rapid screening methods for suitable surfactants has been summarized as a Topical Report. One promising surfactant screening protocol is based on the ability of a surfactant solution to remove aged crude oil that coats a clear calcite crystal (Iceland Spar). Good surfactant candidate solutions remove the most oil the quickest from the surface of these chips, plus change the apparent contact angle of the remaining oil droplets on the surface that thereby indicate increased water-wetting. The other fast surfactant screening method is based on the flotation behavior of powdered calcite in water. In this test protocol, first the calcite power is pre-treated to make the surface oil-wet. The next step is to add the pre-treated powder to a test tube and add a candidate aqueous surfactant formulation; the greater the percentage of the calcite that now sinks to the bottom rather than floats, the more effective the surfactant is in changing the solids to become now preferentially water-wet. Results from the screening test generally are consistent with surfactant oil recovery performance reported in the literature. The second effort is a more fundamental study. It considers the effect of chemical structures of different naphthenic acids (NA) dissolved in decane as model oils that render calcite surfaces oil-wet to a different degree. NAs are common to crude oil and are at least partially responsible for the frequent observation that carbonate reservoirs are oil-wet. Because pure NA compounds are used, trends in wetting behavior can be related to NA molecular structure as measured by solid adsorption, contact angle and our novel, simple flotation test with calcite. Experiments with different surfactants and NA-treated calcite powder provide information about mechanisms responsible for sought after reversal to a water-wet state. Key findings include: (1) more hydrophobic NA's are more prone to induce oil-wetting, and (2) recovery of the model oil from limestone core was better with cationic surfactants, but one nonionic surfactant, Igepal CO-530, also had favorable results. This portion of the project included theoretical calculations to investigate key basic properties of several NAs such as their acidic strength and their relative water/oil solubility, and relate this to their chemical structure. The third category of this project focused on the recovery of a light crude oil from West Texas (McElroy Field) from a carbonate rock (limestone outcrop). For this effort, the first item was to establish a suite of surfactants that would be compatible with the McElroy Field brine. Those were examined further for their ability to recover oil by imbibition. Results demonstrate several types of promising candida

  14. Aquatic Natural Areas Analysis and Evaluation: Oak Ridge Reservation

    SciTech Connect (OSTI)

    Baranski, Dr. Michael J. [Catawba College

    2011-04-01T23:59:59.000Z

    This report presents an assessment of the natural area value of eight Aquatic Natural Areas (ANAs) and seven Aquatic Reference Areas (ARAs) on the Oak Ridge Reservation (ORR) in Anderson and Roane Counties in east Tennessee. It follows a previous study in 2009 that analyzed and evaluated terrestrial natural areas on the Reservation. The purpose of both studies was to evaluate and rank those specially designated areas on the Reservation that contain sensitive species, special habitats, and natural area value. Natural areas receive special protections through established statutes, regulations, and policies. The ORR contains 33,542 acres (13,574 ha) administered by the Department of Energy. The surface waters of the Reservation range from 1st-order to 5th-order streams, but the majority of the streams recognized as ANAs and ARAs are 1st- and 2nd-order streams. East Fork Poplar Creek is a 4th-order stream and the largest watershed that drains Reservation lands. All the waters of the Reservation eventually reach the Clinch River on the southern and western boundaries of the ORR. All available information was collected, synthesized, and evaluated. Field observations were made to support and supplement the available information. Geographic information system mapping techniques were used to develop several quantitative attributes about the study areas. Narrative descriptions of each ANA and ARA and tables of numerical data were prepared. Criteria for assessment and evaluation were developed, and eight categories of factors were devised to produce a ranking system. The evaluation factors used in the ranking system were: (A) size of area, (B) percentage of watershed protected, (C) taxa present with protected status, (D) overall biotic diversity, (E) stream features, (F) water quality and use support ratings, (G) disturbance regime, and (H) other factors. Each factor was evaluated on a 5-point ranking scale (0-4), and each area received a composite score, where 32 was the maximum score possible. A highly ranked ANA or ARA is one that is large in size compared to other areas, includes a greater proportion of the watershed within Reservation boundaries, contains a number of status taxa at high densities, exhibits a high overall biodiversity, has very good or excellent habitat and water quality, is well protected and isolated from disturbances, and shows several other characteristics that contribute to natural area value. In this report, the term 'natural area' is loosely defined as a terrestrial or aquatic system that exhibits, or is thought to exhibit, high natural integrity and other significant natural values. The purpose of the present study is to evaluate and rank the currently recognized Aquatic Natural Areas (ANAs) and Aquatic Reference Areas (ARAs) on the Oak Ridge Reservation (ORR) for their natural area value. A previous study (Baranski 2009) analyzed, evaluated, and ranked terrestrial areas (Natural Areas [NAs], Reference Areas [RAs], and Cooperative Management Areas [CMAs]) on the ORR for natural area value, and a precise methodology for natural area evaluation was developed. The present study is intended to be a complement and companion to the terrestrial area study and attempts to employ a similar methodology for aquatic areas so that aquatic and terrestrial areas can be compared on a similar scale. This study specifically develops criteria for assessing the ecological, biodiversity, and natural area importance and significance of aquatic systems on the Reservation in a relevant and consistent manner. The information can be integrated into the Tennessee Natural Heritage Program (http://tn.gov/environment/na/nhp.shtml) system and applied to potential new aquatic areas. Further, the information will be useful in planning, management, and protection efforts on the ORR.

  15. Full-Scale Cask Testing and Public Acceptance of Spent Nuclear Fuel Shipments - 12254

    SciTech Connect (OSTI)

    Dilger, Fred [Black Mountain Research, Henderson, NV 81012 (United States); Halstead, Robert J. [State of Nevada Agency for Nuclear Projects Carson City, NV 80906 (United States); Ballard, James D. [Department of Sociology, California State University, Northridge Northridge, CA 91330 (United States)

    2012-07-01T23:59:59.000Z

    Full-scale physical testing of spent fuel shipping casks has been proposed by the National Academy of Sciences (NAS) 2006 report on spent nuclear fuel transportation, and by the Presidential Blue Ribbon Commission (BRC) on America's Nuclear Future 2011 draft report. The U.S. Nuclear Regulatory Commission (NRC) in 2005 proposed full-scale testing of a rail cask, and considered 'regulatory limits' testing of both rail and truck casks (SRM SECY-05-0051). The recent U.S. Department of Energy (DOE) cancellation of the Yucca Mountain project, NRC evaluation of extended spent fuel storage (possibly beyond 60-120 years) before transportation, nuclear industry adoption of very large dual-purpose canisters for spent fuel storage and transport, and the deliberations of the BRC, will fundamentally change assumptions about the future spent fuel transportation system, and reopen the debate over shipping cask performance in severe accidents and acts of sabotage. This paper examines possible approaches to full-scale testing for enhancing public confidence in risk analyses, perception of risk, and acceptance of spent fuel shipments. The paper reviews the literature on public perception of spent nuclear fuel and nuclear waste transportation risks. We review and summarize opinion surveys sponsored by the State of Nevada over the past two decades, which show consistent patterns of concern among Nevada residents about health and safety impacts, and socioeconomic impacts such as reduced property values along likely transportation routes. We also review and summarize the large body of public opinion survey research on transportation concerns at regional and national levels. The paper reviews three past cask testing programs, the way in which these cask testing program results were portrayed in films and videos, and examines public and official responses to these three programs: the 1970's impact and fire testing of spent fuel truck casks at Sandia National Laboratories, the 1980's regulatory and demonstration testing of MAGNOX fuel flasks in the United Kingdom (the CEGB 'Operation Smash Hit' tests), and the 1980's regulatory drop and fire tests conducted on the TRUPACT II containers used for transuranic waste shipments to the Waste Isolation Pilot Plant in New Mexico. The primary focus of the paper is a detailed evaluation of the cask testing programs proposed by the NRC in its decision implementing staff recommendations based on the Package Performance Study, and by the State of Nevada recommendations based on previous work by Audin, Resnikoff, Dilger, Halstead, and Greiner. The NRC approach is based on demonstration impact testing (locomotive strike) of a large rail cask, either the TAD cask proposed by DOE for spent fuel shipments to Yucca Mountain, or a similar currently licensed dual-purpose cask. The NRC program might also be expanded to include fire testing of a legal-weight truck cask. The Nevada approach calls for a minimum of two tests: regulatory testing (impact, fire, puncture, immersion) of a rail cask, and extra-regulatory fire testing of a legal-weight truck cask, based on the cask performance modeling work by Greiner. The paper concludes with a discussion of key procedural elements - test costs and funding sources, development of testing protocols, selection of testing facilities, and test peer review - and various methods of communicating the test results to a broad range of stakeholder audiences. (authors)

  16. LONG-TERM TECHNETIUM INTERACTIONS WITH REDUCING CEMENTITIOUS MATERIALS

    SciTech Connect (OSTI)

    Kaplan, D.; Lilley, M.; Almond, P.; Powell, B.

    2011-03-15T23:59:59.000Z

    Technetium is among the key risk drivers at the Saltstone Facility. The way that it is immobilized in this cementitious waste form is by converting its highly mobile Tc(VII) form to a much less mobile Tc(IV) form through reduction by the cement's blast furnace slag. This report includes a review of published data and experimental results dealing with Tc leaching from Portland cement waste forms. The objectives for the literature study were to document previous reports of Tc interactions with slag-containing cementitious materials. The objectives for the laboratory study were to measure Tc-saltstone Kd values under reducing conditions. From the literature it was concluded: (1) Spectroscopic evidence showed that when Tc(IV) in a slag-cement was exposed to an oxidizing environment, it will convert to the more mobile Tc(VII) species within a short time frame, 2.5 years. (2) SRS saltstone will reduce Tc(VII) in the absence of NaS or sodium dithionite in a reducing atmosphere. (3) Only trace concentrations of atmospheric oxygen (30 to 60 ppm O{sub 2}; Eh 120 mV) at the high pH levels of cementitious systems is required to maintain Tc as Tc(VII). (4) Experimental conditions must be responsible for wide variability of measured K{sub d} values, such that they are either very low, {approx}1 mL/g, or they are very high {approx}1000 mL/g, suggesting that Tc(VII) or Tc(IV) dominate the systems. Much of this variability appears to be the result of experimental conditions, especially direct controls of oxygen contact with the sample. (5) A field study conducted at SRS in the 1980s indicated that a slag-saltstone immobilized Tc for 2.5 years. Below background concentrations of Tc leached out of the slag-containing saltstone, whereas Tc leached out of the slag-free saltstone at the rate of nitrate loss. One possible explanation for the immobilization of Tc in this study was that the slag-saltstone maintained reducing conditions within the core of the 55-gallon sample, whereas in the small-scale lab experiments, where samples were crushed to <1mm, oxygen diffused through the particles and reoxidize the slag during the contact period. (6) Present site specific reduction capacity value of 820 {micro}eq/g is in the realm of literature values that were either measured or theoretically estimated based on thermodynamic calculations. (7) Almond and Kaplan (2011) measured desorption K{sub d} values from a Vault 4 saltstone core sample. Desorption leaching tests were conducted in a glovebag maintained at 30 to 60 ppm O2. A ground olive-colored saltstone sample, as compared to black monolith sample, was used in this study, indicating the sample had been exposed to O2, which is likely the cause for the lower then anticipated Kd value measured, 139 mL/g. Tc adsorption experiments were conducted under reducing conditions (<0.5 ppm O{sub 2}(g) -585 mV, 2% H{sub 2}, pH 11.66) and obtained K{sub d} values of {approx}1000 mL/g in a saltstone formulated with 45% slag (nominal concentration) and a K{sub d} of 10,000 mL/g when the saltstone contained 95% slag. The K{sub d} values logarithmically increased from 1 day to 56 days, with little sorption generally occurring in the first eight days. Steady state had not been achieved during the initial 56 days. However, the slag-free cement control samples also had K{sub d} values near 1000 mL/g and extremely low redox conditions, due to the 2% H{sub 2} atmosphere. A key concept that this literature review and the experimental results provide is that Tc immobilization is dependent on experimental conditions, specifically, the available oxygen that can oxidize technetium in a portland cement or saltstone-like monolith. The shrinking core model used in the saltstone performance assessment describes the existence of an oxidized outer layer of concrete surrounding a shrinking core of reducing intact saltstone. A sharp boundary between the two zones moves slowly inward, resulting in oxidation of Tc(IV). This work largely reinforced our conceptual model of the shrinking core model, but more importantly provided cla