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1

Fast Pyrolysis Conversion Tests of Forest Concepts’ Crumbles.  

SciTech Connect (OSTI)

The report describes the work done by PNNL on assessing Forest Concept's engineered feedstock using the bench-scale continuous fast pyrolysis system to produce liquid bio-oil, char and gas. Specifically, bio-oil from the following process were evaluated for its yield and quality to determine impact of varying feed size parameters. Furthermore, the report also describes the handling process of the biomass and the challenges of operating the system with above average particle size.

Santosa, Daniel M.; Zacher, Alan H.; Eakin, David E.

2012-04-02T23:59:59.000Z

2

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case Production of Gasoline and Diesel from Biomass via Fast Pyrolysis,...

3

Catalytic fast pyrolysis of lignocellulosic biomass  

SciTech Connect (OSTI)

Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

2014-11-21T23:59:59.000Z

4

Transportation fuels from biomass via fast pyrolysis and hydroprocessing  

SciTech Connect (OSTI)

Biomass is a renewable source of carbon, which could provide a means to reduce the greenhouse gas impact from fossil fuels in the transportation sector. Biomass is the only renewable source of liquid fuels, which could displace petroleum-derived products. Fast pyrolysis is a method of direct thermochemical conversion (non-bioconversion) of biomass to a liquid product. Although the direct conversion product, called bio-oil, is liquid; it is not compatible with the fuel handling systems currently used for transportation. Upgrading the product via catalytic processing with hydrogen gas, hydroprocessing, is a means that has been demonstrated in the laboratory. By this processing the bio-oil can be deoxygenated to hydrocarbons, which can be useful replacements of the hydrocarbon distillates in petroleum. While the fast pyrolysis of biomass is presently commercial, the upgrading of the liquid product by hydroprocessing remains in development, although it is moving out of the laboratory into scaled-up process demonstration systems.

Elliott, Douglas C.

2013-09-21T23:59:59.000Z

5

Specialists' workshop on fast pyrolysis of biomass  

SciTech Connect (OSTI)

This workshop brought together most of those who are currently working in or have published significant findings in the area of fast pyrolysis of biomass or biomass-derived materials, with the goal of attaining a better understanding of the dominant mechanisms which produce olefins, oxygenated liquids, char, and tars. In addition, background papers were given in hydrocarbon pyrolysis, slow pyrolysis of biomass, and techniques for powdered-feedstock preparation in order that the other papers did not need to introduce in depth these concepts in their presentations for continuity. In general, the authors were requested to present summaries of experimental data with as much interpretation of that data as possible with regard to mechanisms and process variables such as heat flux, temperatures, partial pressure, feedstock, particle size, heating rates, residence time, etc. Separate abstracts have been prepared of each presentation for inclusion in the Energy Data Base. (DMC)

Not Available

1980-01-01T23:59:59.000Z

6

Understanding the product distribution from biomass fast pyrolysis.  

E-Print Network [OSTI]

??Fast pyrolysis of biomass is an attractive route to transform solid biomass into a liquid bio-oil, which has been envisioned as a renewable substitute for… (more)

Patwardhan, Pushkaraj Ramchandra

2010-01-01T23:59:59.000Z

7

The effects of biomass pretreatments on the products of fast pyrolysis.  

E-Print Network [OSTI]

??Fast pyrolysis thermochemically degrades lignocellulosic material into solid char, organic liquids, and gaseous products. Using fast pyrolysis to produce renewable liquid bio-oil to replace crude… (more)

Kasparbauer, Randall Dennis

2009-01-01T23:59:59.000Z

8

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

9

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

10

Lignin Fast Pyrolysis: Results from an International Collaboration  

SciTech Connect (OSTI)

An international study of fast pyrolysis of lignin was undertaken. Fourteen laboratories in eight different countries contributed. Two lignin samples were distributed to the laboratories for analysis and bench-scale process testing in fast pyrolysis. Analyses included proximate and ultimate analysis, thermogravimetric analysis, and analytical pyrolysis. The bench-scale test included bubbling fluidized bed reactors and entrained flow systems. Based on the results of the various analyses and tests it was concluded that a concentrated lignin (estimated at about 50% lignin and 50% cellulose) behaved like a typical biomass, producing a slightly reduced amount of a fairly typical bio-oil, while a purified lignin material was difficult to process in the fast pyrolysis reactors and produced a much lower amount of a different kind of bio-oil. It was concluded that for highly concentrated lignin feedstocks new reactor designs will be required other than the typical fluidized bed fast pyrolysis systems.

Nowakowski, Daniel J.; Bridgwater, Anthony V.; Elliott, Douglas C.; Meier, Dietrich; de Wild, Paul

2010-05-01T23:59:59.000Z

11

Entrained-Flow, Fast Ablative Pyrolysis of Biomass - Annual Report, 1 December 1984 - 31 December 1985  

SciTech Connect (OSTI)

The ablative, fast pyrolysis system was relocated to SERI's new, permanent Field Test Laboratory. Pyrolysis system modifications were made to increase the energy available to the vortex reactor and to enhance the collection efficiency of primary pyrolysis vapors. Mathematical modeling of the vapor cracker has resulted in the ability to accurately predict experimental results with respect to the thermal cracking of the primary vapors, the generation of noncondensible gases, and the gas composition. The computer algorithm of this model can be readily used to perform experimental simulation and/or reactor scale-up due to its fundamental nature. Preliminary screening tests with pure ZSM-5 zeolite catalyst, supplied by Mobil Research and Development Corporation, have shown promise for the conversion of primary pyrolysis oil vapors to aromatic hydrocarbons; i.e., gasoline.

Diebold, J. P.; Scahill, J. W.; Evans, R. J.

1986-07-01T23:59:59.000Z

12

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

13

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect (OSTI)

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

14

Upgrading of Fast Pyrolysis Oil via HDO Using Nano-Structured Catalysts.  

E-Print Network [OSTI]

??The effects of type of solvents (hydro-treated or upgraded pyrolysis oil and ethanol) on hydro-de-oxygenation (HDO) of fast pyrolysis oil were studied. The presence and… (more)

Ahmadi, Shima

2014-01-01T23:59:59.000Z

15

Thermochemical Conversion Research and Development: Gasification and Pyrolysis (Fact Sheet)  

SciTech Connect (OSTI)

Biomass gasification and pyrolysis research and development activities at the National Renewable Energy Laboratory and Pacific Northwest National Laboratory.

Not Available

2009-09-01T23:59:59.000Z

16

Bioenergy Technologies Office R&D Pathways: Fast Pyrolysis and Hydroprocessing  

Broader source: Energy.gov [DOE]

In fast pyrolysis and hydrotreating, biomass is rapidly heated in a fluidized bed to create bio-oils, which can then be used to create hydrocarbon biofuel blendstocks.

17

Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis  

Broader source: Energy.gov [DOE]

In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks.

18

Design Case Summary: Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating, and Hydrocracking  

Broader source: Energy.gov [DOE]

The Biomass Program develops design cases to understand the current state of conversiontechnologies and to determine where improvements need to take place in the future. The bestavailable bench and pilot-scale conversion data are integrated with detailed process flow andengineering models to identify technical barriers where research and development could leadto significant cost improvements and to calculate production costs. Past design cases focusedon finding pathways toward cost-competitive production of ethanol. This design case is thefirst to establish detailed cost targets for the production of diesel and gasoline blendstock frombiomass via a fast pyrolysis process.

19

Sala Dolomite-Catalysed Conversion of Tar from Biomass Pyrolysis  

Science Journals Connector (OSTI)

Dolomite from the Swedish Sala quarry has been examined as a possible catalyst for cracking and steam reforming of tar produced during pyrolysis of biomass.

K. Sjöström; G. Taralas; L. Liinanki

1988-01-01T23:59:59.000Z

20

Bio-mass for biomass: biological mass spectrometry techniques for biomass fast pyrolysis oils.  

E-Print Network [OSTI]

??Biomass fast pyrolysis oils, or bio-oils, are a promising renewable energy source to supplement or replace petroleum-based products and fuels. However, there is a current… (more)

Dalluge, Erica A.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Design, optimization and evaluation of a free-fall biomass fast pyrolysis reactor and its products.  

E-Print Network [OSTI]

??The focus of this work is a radiatively heated, free-fall, fast pyrolysis reactor. The reactor was designed and constructed for the production of bio-oil from… (more)

Ellens, Cody James

2009-01-01T23:59:59.000Z

22

Summary of Fast Pyrolysis and Upgrading GHG Analyses  

SciTech Connect (OSTI)

The Energy Independence and Security Act (EISA) of 2007 established new renewable fuel categories and eligibility requirements (EPA 2010). A significant aspect of the National Renewable Fuel Standard 2 (RFS2) program is the requirement that the life cycle greenhouse gas (GHG) emissions of a qualifying renewable fuel be less than the life cycle GHG emissions of the 2005 baseline average gasoline or diesel fuel that it replaces. Four levels of reduction are required for the four renewable fuel standards. Table 1 lists these life cycle performance improvement thresholds. Table 1. Life Cycle GHG Thresholds Specified in EISA Fuel Type Percent Reduction from 2005 Baseline Renewable fuel 20% Advanced biofuel 50% Biomass-based diesel 50% Cellulosic biofuel 60% Notably, there is a specialized subset of advanced biofuels that are the cellulosic biofuels. The cellulosic biofuels are incentivized by the Cellulosic Biofuel Producer Tax Credit (26 USC 40) to stimulate market adoption of these fuels. EISA defines a cellulosic biofuel as follows (42 USC 7545(o)(1)(E)): The term “cellulosic biofuel” means renewable fuel derived from any cellulose, hemicellulose, or lignin that is derived from renewable biomass and that has lifecycle greenhouse gas emissions, as determined by the Administrator, that are at least 60 percent less than the baseline lifecycle greenhouse gas emissions. As indicated, the Environmental Protection Agency (EPA) has sole responsibility for conducting the life cycle analysis (LCA) and making the final determination of whether a given fuel qualifies under these biofuel definitions. However, there appears to be a need within the LCA community to discuss and eventually reach consensus on discerning a 50–59 % GHG reduction from a ? 60% GHG reduction for policy, market, and technology development. The level of specificity and agreement will require additional development of capabilities and time for the sustainability and analysis community, as illustrated by the rich dialogue and convergence around the energy content and GHG reduction of cellulosic ethanol (an example of these discussions can be found in Wang 2011). GHG analyses of fast pyrolysis technology routes are being developed and will require significant work to reach the levels of development and maturity of cellulosic ethanol models. This summary provides some of the first fast pyrolysis analyses and clarifies some of the reasons for differing results in an effort to begin the convergence on assumptions, discussion of quality of models, and harmonization.

Snowden-Swan, Lesley J.; Male, Jonathan L.

2012-12-07T23:59:59.000Z

23

Bio-methane via fast pyrolysis of biomass  

Science Journals Connector (OSTI)

Bio-methane, a renewable vehicle fuel, is today produced by anaerobic digestion and a 2nd generation production route via gasification is under development. This paper proposes a poly-generation plant that produces bio-methane, bio-char and heat via fast pyrolysis of biomass. The energy and material flows for the fuel synthesis are calculated by process simulation in Aspen Plus®. The production of bio-methane and bio-char amounts to 15.5 MW and 3.7 MW, when the total inputs are 23 MW raw biomass and 1.39 MW electricity respectively (HHV basis). The results indicate an overall efficiency of 84% including high-temperature heat and the biomass to bio-methane yield amounts to 83% after allocation of the biomass input to the final products (HHV basis). The overall energy efficiency is higher for the suggested plant than for the gasification production route and is therefore a competitive route for bio-methane production.

Martin Görling; Mårten Larsson; Per Alvfors

2013-01-01T23:59:59.000Z

24

Techno-Economic Analysis of Biomass Fast Pyrolysis to Transportation Fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biomass Fast Pyrolysis to Biomass Fast Pyrolysis to Transportation Fuels Mark M. Wright, Justinus A. Satrio, and Robert C. Brown Iowa State University Daren E. Daugaard ConocoPhillips Company David D. Hsu National Renewable Energy Laboratory Technical Report NREL/TP-6A20-46586 November 2010 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 1617 Cole Boulevard Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Techno-Economic Analysis of Biomass Fast Pyrolysis to Transportation Fuels Mark M. Wright, Justinus A. Satrio, and Robert C. Brown Iowa State University

25

State-of-the-art of fast pyrolysis in IEA bioenergy member countries  

Science Journals Connector (OSTI)

Fast pyrolysis of biomass is becoming increasingly important in some member countries of the International Energy Agency (IEA). Six countries have joined the IEA Task 34 of the Bioenergy Activity: Canada, Finland, Germany, Netherlands, UK, and USA. The National Task Leaders give an overview of the current activities in their countries both on research, pilot and demonstration level.

Dietrich Meier; Bert van de Beld; Anthony V. Bridgwater; Douglas C. Elliott; Anja Oasmaa; Fernando Preto

2013-01-01T23:59:59.000Z

26

Life Cycle Environmental and Economic Tradeoffs of Using Fast Pyrolysis Products for Power Generation  

Science Journals Connector (OSTI)

ash ... To find favorable locations for a 200 dry metric ton/day fast pyrolysis plant in Pennsylvania (PA), analysis was undertaken using GIS tools that considered locations and the availability of corn farms, fuel oil-fired power plants, and coal-fired power plants in the state. ...

Ghasideh Pourhashem; Sabrina Spatari; Akwasi A. Boateng; Andrew J. McAloon; Charles A. Mullen

2013-03-19T23:59:59.000Z

27

Life Cycle Assessment of Gasoline and Diesel Produced via Fast Pyrolysis and Hydroprocessing  

SciTech Connect (OSTI)

In this work, a life cycle assessment (LCA) estimating greenhouse gas (GHG) emissions and net energy value (NEV) of the production of gasoline and diesel from forest residues via fast pyrolysis and hydroprocessing, from production of the feedstock to end use of the fuel in a vehicle, is performed. The fast pyrolysis and hydrotreating and hydrocracking processes are based on a Pacific Northwest National Laboratory (PNNL) design report. The LCA results show GHG emissions of 0.142 kg CO2-equiv. per km traveled and NEV of 1.00 MJ per km traveled for a process using grid electricity. Monte Carlo uncertainty analysis shows a range of results, with all values better than those of conventional gasoline in 2005. Results for GHG emissions and NEV of gasoline and diesel from pyrolysis are also reported on a per MJ fuel basis for comparison with ethanol produced via gasification. Although pyrolysis-derived gasoline and diesel have lower GHG emissions and higher NEV than conventional gasoline does in 2005, they underperform ethanol produced via gasification from the same feedstock. GHG emissions for pyrolysis could be lowered further if electricity and hydrogen are produced from biomass instead of from fossil sources.

Hsu, D. D.

2011-03-01T23:59:59.000Z

28

Flexible Conversion Ratio Fast Reactor Systems Evaluation  

SciTech Connect (OSTI)

Conceptual designs of lead-cooled and liquid salt-cooled fast flexible conversion ratio reactors were developed. Both concepts have cores reated at 2400 MWt placed in a large-pool-type vessel with dual-free level, which also contains four intermediate heat exchanges coupling a primary coolant to a compact and efficient supercritical CO2 Brayton cycle power conversion system. Decay heat is removed passively using an enhanced Reactor Vessel Auxiliary Cooling System and a Passive Secondary Auxiliary Cooling System. The most important findings were that (1) it is feasible to design the lead-cooled and salt-cooled reactor with the flexible conversion ratio (CR) in the range of CR=0 and CR=1 n a manner that achieves inherent reactor shutdown in unprotected accidents, (2) the salt-cooled reactor requires Lithium thermal Expansion Modules to overcme the inherent salt coolant's large positive coolant temperature reactivity coefficient, (3) the preferable salt for fast spectrum high power density cores is NaCl-Kcl-MgCl2 as opposed to fluoride salts due to its better themal-hydraulic and neutronic characteristics, and (4) both reactor, but attain power density 3 times smaller than that of the sodium-cooled reactor.

Neil Todreas; Pavel Hejzlar

2008-06-30T23:59:59.000Z

29

Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils  

SciTech Connect (OSTI)

This University of Massachusetts, Amherst project, "Fast Pyrolysis Oil Stabilization: An Integrated Catalytic and Membrane Approach for Improved Bio-oils" started on 1st February 2009 and finished on August 31st 2011. The project consisted following tasks: Task 1.0: Char Removal by Membrane Separation Technology The presence of char particles in the bio-oil causes problems in storage and end-use. Currently there is no well-established technology to remove char particles less than 10 micron in size. This study focused on the application of a liquid-phase microfiltration process to remove char particles from bio-oil down to slightly sub-micron levels. Tubular ceramic membranes of nominal pore sizes 0.5 and 0.8 ���µm were employed to carry out the microfiltration, which was conducted in the cross-flow mode at temperatures ranging from 38 to 45 C and at three different trans-membrane pressures varying from 1 to 3 bars. The results demonstrated the removal of the major quantity of char particles with a significant reduction in overall ash content of the bio-oil. The results clearly showed that the cake formation mechanism of fouling is predominant in this process. Task 2.0 Acid Removal by Membrane Separation Technology The feasibility of removing small organic acids from the aqueous fraction of fast pyrolysis bio-oils using nanofiltration (NF) and reverse osmosis (RO) membranes was studied. Experiments were carried out with a single solute solutions of acetic acid and glucose, binary solute solutions containing both acetic acid and glucose, and a model aqueous fraction of bio-oil (AFBO). Retention factors above 90% for glucose and below 0% for acetic acid were observed at feed pressures near 40 bar for single and binary solutions, so that their separation in the model AFBO was expected to be feasible. However, all of the membranes were irreversibly damaged when experiments were conducted with the model AFBO due to the presence of guaiacol in the feed solution. Experiments with model AFBO excluding guaiacol were also conducted. NF membranes showed retention factors of glucose greater than 80% and of acetic acid less than 15% when operated at transmembrane pressures near 60 bar. Task 3.0 Acid Removal by Catalytic Processing It was found that the TAN reduction in bio-oil was very difficult using low temperature hydrogenation in flow and batch reactors. Acetic acid is very resilient to hydrogenation and we could only achieve about 16% conversion for acetic acid. Although it was observed that acetic acid was not responsible for instability of aqueous fraction of bio-oil during ageing studies (described in task 5). The bimetallic catalyst PtRe/ceria-zirconia was found to be best catalyst because its ability to convert the acid functionality with low conversion to gas phase carbon. Hydrogenation of the whole bio-oil was carried out at 125���°C, 1450 psi over Ru/C catalyst in a flow reactor. Again, negligible acetic acid conversion was obtained in low temperature hydrogenation. Hydrogenation experiments with whole bio-oil were difficult to perform because of difficulty to pumping the high viscosity oil and reactor clogging. Task 4.0 Acid Removal using Ion Exchange Resins DOWEX M43 resin was used to carry out the neutralization of bio-oil using a packed bed column. The pH of the bio-oil increased from 2.43 to 3.7. The GC analysis of the samples showed that acetic acid was removed from the bio-oil during the neutralization and recovered in the methanol washing. But it was concluded that process would not be economical at large scale as it is extremely difficult to regenerate the resin once the bio-oil is passed over it. Task 5.0 Characterization of Upgraded Bio-oils We investigated the viscosity, microstructure, and chemical composition of bio-oils prepared by a fast pyrolysis approach, upon aging these fuels at 90���ºC for periods of several days. Our results suggest that the viscosity increase is not correlated with the acids or char present in the bio-oils. The

George W. Huber, Aniruddha A Upadhye, David M. Ford, Surita R. Bhatia, Phillip C. Badger

2012-10-19T23:59:59.000Z

30

Implications of Fast Reactor Transuranic Conversion Ratio  

SciTech Connect (OSTI)

Theoretically, the transuranic conversion ratio (CR), i.e. the transuranic production divided by transuranic destruction, in a fast reactor can range from near zero to about 1.9, which is the average neutron yield from Pu239 minus 1. In practice, the possible range will be somewhat less. We have studied the implications of transuranic conversion ratio of 0.0 to 1.7 using the fresh and discharge fuel compositions calculated elsewhere. The corresponding fissile breeding ratio ranges from 0.2 to 1.6. The cases below CR=1 (“burners”) do not have blankets; the cases above CR=1 (“breeders”) have breeding blankets. The burnup was allowed to float while holding the maximum fluence to the cladding constant. We graph the fuel burnup and composition change. As a function of transuranic conversion ratio, we calculate and graph the heat, gamma, and neutron emission of fresh fuel; whether the material is “attractive” for direct weapon use using published criteria; the uranium utilization and rate of consumption of natural uranium; and the long-term radiotoxicity after fuel discharge. For context, other cases and analyses are included, primarily once-through light water reactor (LWR) uranium oxide fuel at 51 MWth-day/kg-iHM burnup (UOX-51). For CR<1, the heat, gamma, and neutron emission increase as material is recycled. The uranium utilization is at or below 1%, just as it is in thermal reactors as both types of reactors require continuing fissile support. For CR>1, heat, gamma, and neutron emission decrease with recycling. The uranium utilization exceeds 1%, especially as all the transuranic elements are recycled. exceeds 1%, especially as all the transuranic elements are recycled. At the system equilibrium, heat and gamma vary by somewhat over an order of magnitude as a function of CR. Isotopes that dominate heat and gamma emission are scattered throughout the actinide chain, so the modest impact of CR is unsurprising. Neutron emitters are preferentially found among the higher actinides, so the neutron emission varies much stronger with CR, about three orders of magnitude.

Steven J. Piet; Edward A. Hoffman; Samuel E. Bays

2010-11-01T23:59:59.000Z

31

Comparative analysis of pinewood, peanut shell, and bamboo biomass derived biochars produced via hydrothermal conversion and pyrolysis  

Science Journals Connector (OSTI)

Abstract Biochars were produced from pinewood, peanut shell, and bamboo biomass through hydrothermal conversion (HTC) at 300 °C and comparatively by slow pyrolysis over a temperature range of 300, 400, and 500 °C. These biochars were characterized by FT-IR, cation exchange capacity (CEC) assay, methylene blue adsorption, as well as proximate and elemental analysis. The experimental results demonstrated higher retained oxygen content in biochars produced at lower pyrolysis temperatures and through HTC, which also correlated to the higher CEC of respective biochars. Furthermore, all types of biochar studied herein were capable of adsorption of methylene blue from solution and the adsorption did not appear to strongly correlate with CEC, indicating that the methylene blue adsorption appears to be dependent more upon the non-electrostatic molecular interactions such as the likely dispersive ?–? interactions between the graphene-like sheets of the biochar with the aromatic ring structure of the dye, than the electrostatic CEC. A direct comparison of hydrothermal and pyrolysis converted biochars reveals that biochars produced through HTC have much higher CEC than the biochars produced by slow pyrolysis. Analysis by FT-IR reveals a higher retention of oxygen functional groups in HTC biochars; additionally, there is an apparent trend of increasing aromaticity of the pyrolysis biochars when produced at higher temperatures. The CEC value of the HTC biochar appears correlated with its oxygen functional group content as indicated by the FT-IR measurements and its O:C ratio.

Matthew D. Huff; Sandeep Kumar; James W. Lee

2014-01-01T23:59:59.000Z

32

Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials  

DOE Patents [OSTI]

A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

Chum, Helena L. (8448 Allison Ct., Arvada, CO 80005); Black, Stuart K. (4976 Raleigh St., Denver, CO 80212); Diebold, James P. (57 N. Yank Way, Lakewood, CO 80228); Kreibich, Roland E. (4201 S. 344th, Auburn, WA 98001)

1993-01-01T23:59:59.000Z

33

Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials  

DOE Patents [OSTI]

A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

Chum, H.L.; Black, S.K.; Diebold, J.P.; Kreibich, R.E.

1993-08-10T23:59:59.000Z

34

Using mobile distributed pyrolysis facilities to deliver a forest residue resource for bio-fuel production.  

E-Print Network [OSTI]

??Distributed mobile conversion facilities using either fast pyrolysis or torrefaction processes can be used to convert forest residues to more energy dense substances (bio-oil, bio-slurry… (more)

Brown, Duncan

2013-01-01T23:59:59.000Z

35

Experimental Investigation of the Effects of Fuel Aging on Combustion Performance and Emissions of Biomass Fast Pyrolysis Liquid-Ethanol Blends in a Swirl Burner.  

E-Print Network [OSTI]

??Biomass fast pyrolysis liquid is a renewable fuel for stationary heat and power generation; however degradation of bio-oil by time, a.k.a. aging, has an impact… (more)

Zarghami-Tehran, Milad

2012-01-01T23:59:59.000Z

36

Experimental Investigation of the Effects of Fuel Properties on Combustion Performance and Emissions of Biomass Fast Pyrolysis Liquid-ethanol Blends in a Swirl Burner.  

E-Print Network [OSTI]

??Biomass fast pyrolysis liquid, also known as bio-oil, is a promising renewable fuel for heat and power generation; however, implementing crude bio-oil in some current… (more)

Moloodi, Sina

2011-01-01T23:59:59.000Z

37

Pyrolysis Gas Chromatography Mass Spectrometry Studies to Evaluate High-Temperature Aqueous Pretreatment as a Way to Modify the Composition of Bio-Oil from Fast Pyrolysis of Wheat Straw  

Science Journals Connector (OSTI)

Pyrolysis Gas Chromatography Mass Spectrometry Studies to Evaluate High-Temperature Aqueous Pretreatment as a Way to Modify the Composition of Bio-Oil from Fast Pyrolysis of Wheat Straw ... ?-Cellulose was obtained from Sigma-Aldrich (St. Louis, Missouri). ... This evidence suggests that CHW pretreatment may produce bio-oil that is composed of a greater amount of sugars and furanics and fewer small molecules and may therefore be a viable option to modify the chemical composition of bio-oils. ...

Robert Lee Johnson; Shi-Shen Liaw; Manuel Garcia-Perez; Su Ha; Sean S.-Y. Lin; Armando G. McDonald; Shulin Chen

2009-10-07T23:59:59.000Z

38

Comparison of Biological and Thermal (Pyrolysis) Pathways for Conversion of Lignocellulose to Biofuels  

E-Print Network [OSTI]

D study. This journey was great because of her and Tinku being around! Thanks to my advisor Dr. Capareda for the diverse bio-energy research opportunity at BETA lab, Dr. El-Halwagi for the unconditional care in every step since I joined TX A... to produce bio-energy from biomass ....................... 3 1.2.2 Pretreatment and hydrolysis in lignocellulose breakdown ....................... 5 1.2.3 Pyrolysis oil upgrade technology...

Imam, Tahmina 1983-

2012-11-30T23:59:59.000Z

39

Guidelines for Transportation, Handling, and Use of Fast Pyrolysis Bio-Oil. 1. Flammability and Toxicity  

Science Journals Connector (OSTI)

The first bio-oil burner fuel standard in ASTM D7544 was approved in 2010. ... A technical specification for a quality specification for pyrolysis oil suitable for gasification feedstock for production of syngas and synthetic biofuels ... Because of the severity of the dermal changes (erythema/edema i.e., burns) and for ethical reasons, the eye irritation test was not run. ...

Anja Oasmaa; Anssi Källi; Christian Lindfors; Douglas C. Elliott; Dave Springer; Cordner Peacocke; David Chiaramonti

2012-05-04T23:59:59.000Z

40

A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin  

Science Journals Connector (OSTI)

Abstract The conversion of biomass by thermochemical means is very promising for the substitution of fossil materials in many energy applications. Given the complexity of biomass the main challenge in its use is to obtain products with high yield and purity. For a better understanding of biomass thermochemical conversion, many authors have studied in TG analyzer or at bed scale the individual pyrolysis of its main constituents (i.e. cellulose, hemicelluloses and lignin). Based on these studies, this original work synthesizes the main steps of conversion and the composition of the products obtained from each constituent. Pyrolysis conversion can be described as the superposition of three main pathways (char formation, depolymerization and fragmentation) and secondary reactions. Lignin, which is composed of many benzene rings, gives the highest char yield and its depolymerization leads to various phenols. The depolymerization of the polysaccharides is a source of anhydro-saccharides and furan compounds. The fragmentation of the different constituents and the secondary reactions produce CO, CO2 and small chain compounds. For temperature higher than 500 °C, the residues obtained from the different constituents present a similar structure, which evolves towards a more condensed polyaromatic form by releasing CH4, CO and H2. As the aromatic rings and their substituent composition have a critical influence on the reactivity of pyrolysis products, a particular attention has been given to their formation. Some mechanisms are proposed to explain the formation of the main products. From the results of this study it is possible to predict the reactivity and energy content of the pyrolysis products and evaluate their potential use as biofuels in renewable applications.

François-Xavier Collard; Joël Blin

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Tritium minority heating with mode conversion of fast waves  

SciTech Connect (OSTI)

A new ion-heating scenario in tokamak plasmas, based on cyclotron damping of ion Bernstein waves (IBWs) by tritium minority at the first ion cyclotron harmonic (i.e., omega=2OMEGA{sub cT}), is proposed. The IBWs are coupled by mode conversion of fast magnetosonic waves in a D-H(T) (tritium minority in hydrogen-deuterium) plasma. The mode conversion layer is located near the center of the plasma column as well as the resonant layer of the tritium minority. A possible scenario for the JET (Joint European Torus) tokamak [J. Wesson, JET Report No. 99, 1999], based on the present idea, has been analyzed by means of the numerical codes TORIC and SSFPQL (toroidal ion cyclotron and steady state Fokker-Planck quasilinear) [M. Brambilla, Nucl. Fusion 34, 1121 (1994); Plasma Phys. Controlled Fusion 41, 1 (1999)]. As a result, tritium ions are accelerated up to energies close to the peak value of the DT cross section and steady state breakeven condition (Qapprox =1.3) can be reached with 25% minority tritium concentration.

Castaldo, Carmine; Cardinali, Alessandro [Euratom ENEA Association, Via Enrico Fermi 45, CP65, 00044 Frascati (Rome) (Italy)

2010-07-15T23:59:59.000Z

42

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: 2012 State of Technology and Projections to 2017  

SciTech Connect (OSTI)

This report summarizes the economic impact of the work performed at PNNL during FY12 to improve fast pyrolysis oil upgrading via hydrotreating. A comparison is made between the projected economic outcome and the actual results based on experimental data. Sustainability metrics are also included.

Jones, Susanne B.; Snowden-Swan, Lesley J.

2013-08-27T23:59:59.000Z

43

Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids  

SciTech Connect (OSTI)

The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

2013-01-18T23:59:59.000Z

44

Influence of inorganic compounds on char formation and quality of fast pyrolysis oils  

SciTech Connect (OSTI)

Inorganic compounds, especially potassium, calcium, sodium, silicon, phosphorus, and chlorine, are the main constituents of ash in biomass feedstocks. The concentrations of ash in biomass feedstocks range from less than 1% in softwoods to 15% in herbaceous biomass and agricultural residues. During biomass pyrolysis, these inorganics, especially potassium and calcium, catalyze both decomposition and char formation reactions. Decomposition reactions may either result in levoglucosan-rich or hydroxyacetaldehyde-rich pyrolysis products depending on the concentration of the ash in the feedstocks. The catalytic effect of the ash levels off at high organic ion concentrations. Chars formed during these reactions invariably end up in the pyrolysis oils (biofuel oils). A high proportion of the alkali metals in the ash are sequestered in the chars. The presence of high concentrations of alkali metals in the biofuel oils make them unsuitable for combustion in boilers, diesel engines, and in turbine operations. The highest concentration of alkali metals are found in herbaceous feedstocks and agricultural residue biofuel oils. Leaching studies conducted on the chars suspended in the oils showed no leaching of the alkali metals from the chars into the oils. Our data suggest that hot gas filtration of the oils can effectively reduce the alkali metals contents of the biofuel oils to acceptable levels to be used as turbine, diesel engine, and boiler fuels.

Agbleyor, F.A.; Besler, S.; Montane, D. [National Renewable Energy Lab., Golden, CO (United States)

1995-12-01T23:59:59.000Z

45

Fast Pyrolysis and Hydrotreating 2013 State of Technology R&D and Projections to 2017  

SciTech Connect (OSTI)

This report documents the FY13 modeled costs and experimental basis for those costs for fast pyrolyis and hydrotreating to liquid fuels. The report also documents the projected costs to 2013.

Jones, Susanne B.; Snowden-Swan, Lesley J.; Meyer, Pimphan A.; Zacher, Alan H.; Olarte, Mariefel V.; Drennan, Corinne

2014-04-16T23:59:59.000Z

46

Biomass Feedstocks for Renewable Fuel Production: A review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors  

SciTech Connect (OSTI)

Renewable transportation fuels from biomass have the potential to substantially reduce greenhouse gas emissions and diversify global fuel supplies. Thermal conversion by fast pyrolysis converts up to 75% of the starting plant material (and its energy content) to a bio-oil intermediate suitable for upgrading to motor fuel. Woody biomass, by far the most widely-used and researched material, is generally preferred in thermochemical processes due to its low ash content and high quality bio-oil produced. However, the availability and cost of biomass resources, e.g. forest residues, agricultural residues, or dedicated energy crops, vary greatly by region and will be key determinates in the overall economic feasibility of a pyrolysis-to-fuel process. Formulation or blending of various feedstocks, combined with thermal and/or chemical pretreatment, could facilitate a consistent, high-volume, lower-cost biomass supply to an emerging biofuels industry. However, the impact of biomass type and pretreatment conditions on bio-oil yield and quality, and the potential process implications, are not well understood. This literature review summarizes the current state of knowledge regarding the effect of feedstock and pretreatments on the yield, product distribution, and upgradability of bio-oil.

Daniel Carpenter; Stefan Czernik; Whitney Jablonski; Tyler L. Westover

2014-02-01T23:59:59.000Z

47

Integration of biomass fast pyrolysis and precedent feedstock steam drying with a municipal combined heat and power plant  

Science Journals Connector (OSTI)

Abstract Biomass fast pyrolysis (BFP) is a promising pre-treatment technology for converting biomass to transport fuel and in the future also for high-grade chemicals. BFP can be integrated with a municipal combined heat and power (CHP) plant. This paper shows the influence of BFP integration on a CHP plant's main parameters and its effect on the energetic and environmental performance of the connected district heating network. The work comprises full- and part-load operation of a CHP plant integrated with BFP and steam drying. It also evaluates different usage alternatives for the BFP products (char and oil). The results show that the integration is possible and strongly beneficial regarding energetic and environmental performance. Offering the possibility to provide lower district heating loads, the operation hours of the plant can be increased by up to 57%. The BFP products should be sold rather than applied for internal use as this increases the district heating network's primary energy efficiency the most. With this integration strategy future CHP plants can provide valuable products at high efficiency and also can help to mitigate global CO2 emissions.

Thomas Kohl; Timo P. Laukkanen; Mika P. Järvinen

2014-01-01T23:59:59.000Z

48

THREE-DIMENSIONAL NUMERICAL SIMULATIONS OF FAST-TO-ALFVEN CONVERSION IN SUNSPOTS  

SciTech Connect (OSTI)

The conversion of fast waves to the Alfven mode in a realistic sunspot atmosphere is studied through three-dimensional numerical simulations. An upward propagating fast acoustic wave is excited in the high-{beta} region of the model. The new wave modes generated at the conversion layer are analyzed from the projections of the velocity and magnetic field in their characteristic directions, and the computation of their wave energy and fluxes. The analysis reveals that the maximum efficiency of the conversion to the slow mode is obtained for inclinations of 25 Degree-Sign and low azimuths, while the Alfven wave conversions peak at high inclinations and azimuths between 50 Degree-Sign and 120 Degree-Sign . Downward propagating Alfven waves appear at the regions of the sunspot where the orientation of the magnetic field is in the direction opposite to the wave propagation, since at these locations the Alfven wave couples better with the downgoing fast magnetic wave which is reflected due to the gradients of the Alfven speed. The simulations show that the Alfven energy at the chromosphere is comparable to the acoustic energy of the slow mode, being even higher at high inclined magnetic fields.

Felipe, T., E-mail: tobias@cora.nwra.com [NorthWest Research Associates, Colorado Research Associates, Boulder, CO 80301 (United States)

2012-10-20T23:59:59.000Z

49

Modelling and experimental studies of biomass and organic pyrolysis.  

E-Print Network [OSTI]

??Pyrolysis is a thermal conversion process that decomposes organic materials into liquid hydrocarbons, carbonaceous residues and combustible gases in the absence of oxygen. Depending on… (more)

Lam, Ka Leung

2012-01-01T23:59:59.000Z

50

Mode conversion and absorption of fast waves at high ion cyclotron harmonics in inhomogeneous magnetic fields  

SciTech Connect (OSTI)

The propagation and absorption of high harmonic fast waves is of interest for non-inductive current drives in fusion experiments. The fast wave can be coupled with the ion Bernstein wave that propagates in the high magnetic field side of an ion cyclotron harmonic resonance layer. This coupling and the absorption are analyzed using the hot plasma dispersion relation and a wave equation that was converted from an approximate dispersion relation for the case where ?{sub i}=k{sub ?}{sup 2}?{sub i}{sup 2}/2?1 (where k{sub ?} is the perpendicular wave number and ?{sub i} is the ion Larmor radius). It is found that both reflection and conversion may occur near the harmonic resonance layer but that they decrease rapidly, giving rise to a sharp increase in the absorption as the parallel wave number increases.

Cho, Suwon, E-mail: swcho@kgu.ac.kr [Department of Physics, Kyonggi University, Suwon, Kyonggi-Do 443-760 (Korea, Republic of)] [Department of Physics, Kyonggi University, Suwon, Kyonggi-Do 443-760 (Korea, Republic of); Kwak, Jong-Gu [National Fusion Research Institute, Daejeon 305-806 (Korea, Republic of)] [National Fusion Research Institute, Daejeon 305-806 (Korea, Republic of)

2014-04-15T23:59:59.000Z

51

Tunneling and mode conversion of fast magnetosonic waves in the magnetospheres of Earth and Mercury  

E-Print Network [OSTI]

Narrow-band linearly polarized waves, having a resonant structure and a peak frequency between the local cyclotron frequency of protons and heavy ions, have been detected in the magnetospheres of Earth and of Mercury. Some of these wave events have been suggested to be driven by linear mode conversion (MC) of the fast magnetosonic waves at the ion-ion hybrid (IIH) resonances. Since the resonant IIH frequency is linked to the plasma composition, solving the inverse problem allows one to infer the concentration of the heavy ions from the measured frequency spectra. In this paper, we identify the conditions when the MC efficiency is maximized in the magnetospheric plasmas and discuss how this can be applied for estimating the heavy ion concentration in the magnetospheres of Earth and Mercury.

Kazakov, Yevgen O

2014-01-01T23:59:59.000Z

52

Environmental impacts of thermochemical biomass conversion. Final report  

SciTech Connect (OSTI)

Thermochemical conversion in this study is limited to fast pyrolysis, upgrading of fast pyrolysis oils, and gasification. Environmental impacts of all types were considered within the project, but primary emphasis was on discharges to the land, air, and water during and after the conversion processes. The project discussed here is divided into five task areas: (1) pyrolysis oil analysis; (2) hydrotreating of pyrolysis oil; (3) gas treatment systems for effluent minimization; (4) strategic analysis of regulatory requirements; and (5) support of the IEA Environmental Systems Activity. The pyrolysis oil task was aimed at understanding the oil contaminants and potential means for their removal. The hydrotreating task was undertaken to better define one potential means for both improving the quality of the oil but also removing contaminants from the oil. Within Task 3, analyses were done to evaluate the results of gasification product treatment systems. Task 4 was a review and collection of regulatory requirements which would be applicable to the subject processes. The IEA support task included input to and participation in the IEA Bioenergy activity which directly relates to the project subject. Each of these tasks is described along with the results. Conclusions and recommendations from the overall project are given.

Elliott, D.C.; Hart, T.R.; Neuenschwander, G.G.; McKinney, M.D.; Norton, M.V.; Abrams, C.W. [Pacific Northwest Lab., Richland, WA (United States)

1995-06-01T23:59:59.000Z

53

Large-Scale Pyrolysis Oil Production: A Technology Assessment and Economic Analysis  

SciTech Connect (OSTI)

A broad perspective of pyrolysis technology as it relates to converting biomass substrates to a liquid bio-oil product and a detailed technical and economic assessment of a fast pyrolysis plant.

Ringer, M.; Putsche, V.; Scahill, J.

2006-11-01T23:59:59.000Z

54

The best use of biomass? Greenhouse gas lifecycle analysis of predicted pyrolysis biochar systems   

E-Print Network [OSTI]

to pessimistic scenarios are used for system operation. Slow pyrolysis is compared to fast pyrolysis and biomass co-firing for GHG abatement and electricity production, using various scenarios for availability of indigenous Scottish feedstocks....

Hammond, James A R

2009-01-01T23:59:59.000Z

55

Biomass Thermochemical Conversion Program. 1983 Annual report  

SciTech Connect (OSTI)

Highlights of progress achieved in the program of thermochemical conversion of biomass into clean fuels during 1983 are summarized. Gasification research projects include: production of a medium-Btu gas without using purified oxygen at Battelle-Columbus Laboratories; high pressure (up to 500 psia) steam-oxygen gasification of biomass in a fluidized bed reactor at IGT; producing synthesis gas via catalytic gasification at PNL; indirect reactor heating methods at the Univ. of Missouri-Rolla and Texas Tech Univ.; improving the reliability, performance, and acceptability of small air-blown gasifiers at Univ. of Florida-Gainesville, Rocky Creek Farm Gasogens, and Cal Recovery Systems. Liquefaction projects include: determination of individual sequential pyrolysis mechanisms at SERI; research at SERI on a unique entrained, ablative fast pyrolysis reactor for supplying the heat fluxes required for fast pyrolysis; work at BNL on rapid pyrolysis of biomass in an atmosphere of methane to increase the yields of olefin and BTX products; research at the Georgia Inst. of Tech. on an entrained rapid pyrolysis reactor to produce higher yields of pyrolysis oil; research on an advanced concept to liquefy very concentrated biomass slurries in an integrated extruder/static mixer reactor at the Univ. of Arizona; and research at PNL on the characterization and upgrading of direct liquefaction oils including research to lower oxygen content and viscosity of the product. Combustion projects include: research on a directly fired wood combustor/gas turbine system at Aerospace Research Corp.; adaptation of Stirling engine external combustion systems to biomass fuels at United Stirling, Inc.; and theoretical modeling and experimental verification of biomass combustion behavior at JPL to increase biomass combustion efficiency and examine the effects of additives on combustion rates. 26 figures, 1 table.

Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

1984-08-01T23:59:59.000Z

56

Minor Actinide Transmutation Physics for Low Conversion Ratio Sodium Fast Reactors  

SciTech Connect (OSTI)

The effects of varying the reprocessing strategy used in the closed cycle of a Sodium Fast Reactor (SNF) prototype are presented in this paper. The isotopic vector from the aqueous separation of transuranic (TRU) elements in Light Water Reactor (LWR) spent nuclear fuel (SNF) is assumed to also vary according to the reprocessing strategy of the closed fuel cycle. The decay heat, gamma energy, and neutron emission of the fuel discharge at equilibrium are found to vary depending on the separation strategy. The SFR core used in this study corresponds to a burner configuration with a conversion ratio of ~0.5 based on the Super-PRISM design. The reprocessing strategies stemming from the choice of either metal or oxide fuel for the SFR are found to have a large impact on the equilibrium discharge decay heat, gamma energy, and neutron emission. Specifically, metal fuel SFR with pyroprocessing of the discharge produces the largest amount of TRU consumption (166 kg per Effective Full Power Year or EFPY), but also the highest decay heat, gamma energy, and neutron emission. On the other hand, an oxide fuel SFR with PUREX reprocessing minimizes the decay heat and related parameters of interest to a minimum, even when compared to thermal Mixed Oxide (MOX) or Inert Matrix Fuel (IMF) on a per mass basis. On an assembly basis, however, the metal SFR discharge has a lower decay heat than an equivalent oxide SFR assembly for similar minor actinide consumptions (~160 kg/EFPY.) Another disadvantage in the oxide PUREX reprocessing scenario is that there is no consumption of americium and curium, since PUREX reprocessing separates these minor actinides (MA) and requires them to be disposed of externally.

Mehdi Asgari; Samuel E. Bays; Benoit Forget; Rodolfo Ferrer

2007-09-01T23:59:59.000Z

57

Silane pyrolysis  

Science Journals Connector (OSTI)

We show that silane pyrolysis is initiated by decomposition on the amorphous silicon surface, with an activation energy Ea of 56 kcal/mole. The observed surface decomposition rate is only weakly dependent on silane pressure. Much faster delayed decomposition rates, approximately independent of surface area and proportional to pressure, are shown to be initiated by surface reactons. A model for surface decomposition is given. Also a model for gas reactions is suggested based on H atom or SiH3 release by surface decomposition, causing chain reactions that process the gas to higher silanes that decompose rapidly. This model can explain the previous observations that the initial disilane formation rate and the delayed decomposition rate were independent of the surface area to volume ratio A/V, which had misled previous investigators to suggest homogeneous initiation processes.

R. Robertson; D. Hils; A. Gallagher

1984-01-01T23:59:59.000Z

58

Fuel and fuel blending components from biomass derived pyrolysis oil  

DOE Patents [OSTI]

A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

2012-12-11T23:59:59.000Z

59

Ab Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 C  

E-Print Network [OSTI]

reserves in lignocellulosic biomass.1 Fast pyrolysis of lignocellulosic biomass, which involves rapidAb Initio Dynamics of Cellulose Pyrolysis: Nascent Decomposition Pathways at 327 and 600 °C Vishal pyrolysis at 327 and 600 °C using Car-Parrinello molecular dynamics (CPMD) simulations with rare events

Auerbach, Scott M.

60

APPLICATION OF PYROLYSIS-GC/MS TO THE STUDY OF BIOMASS AND BIOMASS CONSTITUENTS.  

E-Print Network [OSTI]

??Fast pyrolysis, the rapid thermal decomposition of organic material in the absence of oxygen, is a process that can be used to convert biomass into… (more)

Ware, Anne E

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

FAST  

Energy Science and Technology Software Center (OSTI)

002363MLTPL00 FAST - A Framework for Agile Software Testing v. 2.0  https://software.sandia.gov/trac/fast 

62

Flash pyrolysis of sewage sludge  

Science Journals Connector (OSTI)

Flash pyrolysis of sewage sludge ... Influence of the Pyrolysis Temperature on Sewage Sludge Product Distribution, Bio-Oil, and Char Properties ... Influence of the Pyrolysis Temperature on Sewage Sludge Product Distribution, Bio-Oil, and Char Properties ...

Jan Piskorz; Donald S. Scott; Ian B. Westerberg

1986-01-01T23:59:59.000Z

63

Biomass pyrolysis for chemicals.  

E-Print Network [OSTI]

??Biomass Pyrolysis for Chemicals The problems associated with the use of fossil fuels demand a transition to renewable sources (sun, wind, water, geothermal, biomass) for… (more)

Wild, Paul de

2011-01-01T23:59:59.000Z

64

Solar energy conversion and storage: Fast Green FCF-Fructose photogalvanic cell  

Science Journals Connector (OSTI)

Abstract Photogalvanic cells are photoelectrochemical devices involving ions as mobile charges moving in solution through diffusion process. These cells are capable of solar power generation at low cost with inherent storage capacity. This property of photogalvanic cell needs to be exploited as this technology is cleaner and promising for application in daily life. Therefore, a photogalvanic cell consisting of Fast Green FCF as photosensitizer, Fructose as reductant and NaOH as alkaline medium has been studied with observed value of maximum potential 1083 mV, maximum photocurrent 431 ?A, short-circuit current 380 ?A, power at power point 138.60 ?W, efficiency 1.33%, and storage capacity (as half change time) 70 min. The observed results are higher and encouraging enough for ultimate aim of development of applicable and affordable photogalvanic cells in future.

Pooran Koli

2014-01-01T23:59:59.000Z

65

A Generalized Pyrolysis Model for Combustible Solids  

E-Print Network [OSTI]

processes of wood and biomass pyrolysis,” to appear ineffect during biomass pyrolysis,” Industrial & Engineeringprocesses during pyrolysis of a large biomass particle,”

Lautenberger, Chris

2007-01-01T23:59:59.000Z

66

A Generalized Pyrolysis Model for Combustible Solids  

E-Print Network [OSTI]

processes such as flash pyrolysis [187], but it has not yetreaction model for flash wood pyrolysis,” Fuel 68: 1408–

Lautenberger, Chris

2007-01-01T23:59:59.000Z

67

Nitrogen chemistry during oil shale pyrolysis  

SciTech Connect (OSTI)

Real time evolution of ammonia (NH{sub 3}) and hydrogen cyanide (HCN), two major nitrogen-containing volatiles evolved during oil shale pyrolysis, was measured by means of a mass spectrometer using chemical ionization and by infrared spectroscopy. While the on-line monitoring of NH{sub 3} in oil shale pyrolysis games was possible by both techniques, HCN measurements were only possible by IR. We studied one Green River Formation oil shale and one New Albany oil shale. The ammonia from the Green River oil shale showed one broad NH{sub 3} peak maximizing at a high temperature. For both oil shales, most NH{sub 3} evolves at temperatures above oil-evolving temperature. The important factors governing ammonia salts such as Buddingtonite in Green River oil shales, the distribution of nitrogen functional groups in kerogen, and the retorting conditions. The gas phase reactions, such as NH{sub 3} decomposition and HCN conversion reactions, also play an important role in the distribution of nitrogen volatiles, especially at high temperatures. Although pyrolysis studies of model compounds suggests the primary nitrogen product from kerogen pyrolysis to be HCN at high temperatures, we found only a trace amount of HCN at oil-evolving temperatures and none at high temperatures (T {gt} 600{degree}C). 24 refs., 6 figs., 2 tabs.

Oh, Myongsook S.; Crawford, R.W.; Foster, K.G.; Alcaraz, A.

1990-01-10T23:59:59.000Z

68

Fluidized bed pyrolysis of terrestrial biomass feedstocks  

SciTech Connect (OSTI)

Hybrid poplar, switchgrass, and corn stover were pyrolyzed in a bench scale fluidized-bed reactor to examine the influence of storage time on thermochemical converting of these materials. The influence of storage on the thermochemical conversion of the biomass feedstocks was assessed based on pyrolysis product yields and chemical and instrumental analyses of the pyrolysis products. Although char and gas yields from corn stover feedstock were influenced by storage time, hybrid poplar and switchgrass were not significantly affected. Liquid, char, and gas yields were feedstock dependent. Total liquid yields (organic+water) varied from 58%-73% depending on the feedstock. Char yields varied from 14%-19% while gas yields ranged from 11%-15%. The chemical composition of the pyrolysis oils from hybrid polar feedstock was slightly changed by storage, however, corn stover and switchgrass feedstock showed no significant changes. Additionally, stored corn stover and hybrid poplar pyrolysis oils showed a significant decrease in their higher heating values compared to the fresh material.

Besler, S.; Agblevor, F.A.; Davis, M.F. [National Renewable Energy Lab., Golden, CO (United States)] [and others

1994-12-31T23:59:59.000Z

69

The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene  

SciTech Connect (OSTI)

Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

Solak, Agnieszka; Rutkowski, Piotr, E-mail: piotr.rutkowski@pwr.wroc.pl

2014-02-15T23:59:59.000Z

70

Fuel Cycle System Analysis Implications of Sodium-Cooled Metal-Fueled Fast Reactor Transuranic Conversion Ratio  

SciTech Connect (OSTI)

If advanced fuel cycles are to include a large number of fast reactors (FRs), what should be the transuranic (TRU) conversion ratio (CR)? The nuclear energy era started with the assumption that they should be breeder reactors (CR > 1), but the full range of possible CRs eventually received attention. For example, during the recent U.S. Global Nuclear Energy Partnership program, the proposal was burner reactors (CR < 1). Yet, more recently, Massachusetts Institute of Technology's "Future of the Nuclear Fuel Cycle" proposed CR [approximately] 1. Meanwhile, the French company EDF remains focused on breeders. At least one of the reasons for the differences of approach is different fuel cycle objectives. To clarify matters, this paper analyzes the impact of TRU CR on many parameters relevant to fuel cycle systems and therefore spans a broad range of topic areas. The analyses are based on a FR physics parameter scan of TRU CR from 0 to [approximately]1.8 in a sodium-cooled metal-fueled FR (SMFR), in which the fuel from uranium-oxide-fueled light water reactors (LWRs) is recycled directly to FRs and FRs displace LWRs in the fleet. In this instance, the FRs are sodium cooled and metal fueled. Generally, it is assumed that all TRU elements are recycled, which maximizes uranium ore utilization for a given TRU CR and waste radiotoxicity reduction and is consistent with the assumption of used metal fuel separated by electrochemical means. In these analyses, the fuel burnup was constrained by imposing a neutron fluence limit to fuel cladding to the same constant value. This paper first presents static, time-independent measures of performance for the LWR [right arrow] FR fuel cycle, including mass, heat, gamma emission, radiotoxicity, and the two figures of merit for materials for weapon attractiveness developed by C. Bathke et al. No new fuel cycle will achieve a static equilibrium in the foreseeable future. Therefore, additional analyses are shown with dynamic, time-dependent measures of performance including uranium usage, TRU inventory, and radiotoxicity to evaluate the complex impacts of transition from the current uranium-fueled LWR system, and other more realistic impacts that may not be intuited from the time-independent steady-state conditions of the end-state fuel cycle. These analyses were performed using the Verifiable Fuel Cycle Simulation Model VISION. Compared with static calculations, dynamic results paint a different picture of option space and the urgency of starting a FR fleet. For example, in a static analysis, there is a sharp increase in uranium utilization as CR exceeds 1.0 (burner versus breeder). However, in dynamic analyses that examine uranium use over the next 1 to 2 centuries, behavior as CR crosses the 1.0 threshold is smooth, and other parameters such as the time required outside of reactors to recycle fuel become important. Overall, we find that there is no unambiguously superior value of TRU CR; preferences depend on the relative importance of different fuel cycle system objectives.

Steven J. Piet; Edward A. Hoffman; Samuel E. Bays; Gretchen E. Matthern; Jacob J. Jacobson; Ryan Clement; David W. Gerts

2013-03-01T23:59:59.000Z

71

Chapter 15 - Catalytic Thermochemical Processes for Biomass Conversion to Biofuels and Chemicals  

Science Journals Connector (OSTI)

Abstract Biomass is the most abundant and biorenewable resource with great potential for sustainable production of chemicals and fuels. Thermochemical conversion technologies (pyrolysis, gasification and hydrothermal liquefaction) are a promising option for transforming biomass feedstocks into liquid oils and chemicals. In the article, for the thermal process of biomass for biofuels and chemicals, the effect of reaction conditions, reactors, solvents and catalysts on the yield and distribution of the products are reviewed. Fast pyrolysis of cellulose is primarily conducted over catalysts with proper acidity/basicity and has undergone many pilot tests. Gasification is typically conducted over supported noble metal catalysts and has been profiled as being CO2-neutral, having a high potential to provide power, chemicals and fuels. Catalytically hydrothermal liquefaction of biomass produces a very complex mixture of liquid products; therefore, novel technology for separation and extraction of downstream products from hydrothermal liquefaction of lignocellulosic biomass need to be developed.

Lin Mei Wu; Chun Hui Zhou; Dong Shen Tong; Wei Hua Yu

2014-01-01T23:59:59.000Z

72

Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1998-01-01T23:59:59.000Z

73

Bremsstrahlung and K(alpha) fluorescence measurements for inferring conversion efficiencies into fast ignition relevant hot electrons  

SciTech Connect (OSTI)

The Bremsstrahlung and K-shell emission from 1 mm x 1 mm x 1 mm planar targets irradiated by a short-pulse 3 x 10{sup 18}-8 x 10{sup 19} W/cm{sup 2} laser were measured. The Bremsstrahlung was measured using a filter stack spectrometer with spectral discrimination up to 500 keV. K-shell emission was measured using a single photon counting charge coupled device (CCD). From Monte Carlo modeling of the target emission, conversion efficiencies into 1-3 MeV electrons of 3-12%, representing 20-40% total conversion efficiencies were inferred for intensities up to 8 x 10{sup 19} W/cm{sup 2}. Comparisons to scaling laws using synthetic energy spectra generated from the intensity distribution of the focal spot imply slope temperatures less than the ponderomotive potential of the laser. Resistive transport effects may result in potentials of a few hundred kV in the first few tens of microns in the target. This would lead to higher total conversion efficiencies than inferred from Monte Carlo modeling but lower conversion efficiencies into 1-3 MeV electrons.

Chen, C D; Patel, P K; Hey, D S; Mackinnon, A J; Key, M H; Akli, K U; Bartal, T; Beg, F N; Chawla, S; Chen, H; Freeman, R R; Higginson, D P; Link, A; Ma, T Y; MacPhee, A G; Stephens, R B; Van Woerkom, L D; Westover, B; Porkolab, M

2009-07-24T23:59:59.000Z

74

Flash pyrolysis and hydropyrolysis of biomass  

SciTech Connect (OSTI)

Process chemistry data on the flash pyrolysis and hydropyrolysis of wood is being obtained in a 1'' downflow entrained tubular reactor. The data indicates that at residence times of <1 second, and 900 to 1000/sup 0/C and 500 psi pressure, the flash hydropyrolysis of wood yields mainly methane and water. As the residence time increases to >3 seconds, the products are methane and CO. Almost complete conversion of the carbon to methane and CO are obtained in these experiments. At lower temperatures, in the order of 800/sup 0/C, 500 psi and residence times <4 seconds, significant amounts of benzene and ethane are produced. The experimental process chemistry data have been used to design and evaluate two processes in a preliminary manner. One process converts wood to high BTU pipeline gas and the other to methanol and chemical feedstocks consisting of benzene and ethylene. Reasonable plant investments which compare favorably with coal conversion plant estimates are derived.

Not Available

1982-08-01T23:59:59.000Z

75

PPPL-3151 -Preprint Date: December 1995, UC-420, 426 Enhanced Loss of Fast Ions During Mode Conversion Ion Bernstein  

E-Print Network [OSTI]

rate, and heats the lost particles to several MeV. The lost ions are observed at the passing. Herrmann, M. C. Herrmann, M. C. Zarnstorff, and S. J. Zweben Princeton University, Plasma Physics is of interest because it illuminates the physics of the interactions between the IBWs and the fast ions. In TFTR

76

PPPL3151 Preprint Date: December 1995, UC420, 426 Enhanced Loss of Fast Ions During Mode Conversion Ion Bernstein  

E-Print Network [OSTI]

rate, and heats the lost particles to several MeV. The lost ions are observed at the passing. Herrmann, M. C. Herrmann, M. C. Zarnstorff, and S. J. Zweben Princeton University, Plasma Physics is of interest because it illuminates the physics of the interactions between the IBWs and the fast ions. In TFTR

77

Recovery of valuable chemical feedstocks from waste automotive plastics via pyrolysis processes  

SciTech Connect (OSTI)

Each year in North America over 9 million scrap vehicles are shredded to recover approximately 10 million tons of ferrous metal. The process also produces 3 million tons of waste known as automobile shredder residue (ASR) which consists of plastics, rubber, foams, textiles, glass, dirt, rust, etc. This waste is currently landfilled. In this study the authors present the results obtained in three different pyrolysis processes when ASR was used as the pyrolysis feedstock. The pyrolysis processes examined included: (1) a fast pyrolysis process, featuring rapid heat transfer and short residence times. This process produced primarily a gas stream that was rich in C{sub 1} to C{sub 3} hydrocarbons; (2) a screw kiln unit, characterized by slow heating and long residence times. This process produced a liquid stream that was high in aromatics; (3) a bench-scale autoclave reactor which, in the presence of water, produced a pyrolysis liquid containing large quantities of oxygenated hydrocarbons.

Shen, Z.; Day, M.; Cooney, D. [National Research Council Canada, Ottawa, Ontario (Canada). Inst. for Environmental Research and Technology

1995-11-01T23:59:59.000Z

78

NREL: Biomass Research - Thermochemical Conversion Capabilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion Capabilities Conversion Capabilities NREL researchers are developing gasification and pyrolysis processes for the cost-effective thermochemical conversion of biomass to biofuels. Gasification-heating biomass with about one-third of the oxygen necessary for complete combustion-produces a mixture of carbon monoxide and hydrogen, known as syngas. Pyrolysis-heating biomass in the absence of oxygen-produces a liquid bio-oil. Both syngas and bio-oil can be used directly or can be converted to clean fuels and other valuable chemicals. Areas of emphasis in NREL's thermochemical conversion R&D are: Gasification and fuel synthesis R&D Pyrolysis R&D Thermochemical process integration. Gasification and Fuel Synthesis R&D Get the Adobe Flash Player to see this video.

79

Pyrolysis of polystyrene - polyphenylene oxide to recover styrene and useful products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a polystyrene and polyphenylene oxide plastic waste to a given polystyrene and polyphenylene oxide prior to pyrolysis of other plastic components therein comprising: selecting a first temperature range to cause pyrolysis of given polystyrene and polyphenylene oxide and its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and a support and treating the feed stream with the catalyst to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of high value monomeric constituent of styrene from polystyrene and polyphenylene oxide in the first temperature range; differentially heating the feed stream at a heat rate within the first temperature range to provide differential pyrolysis for selective recovery of the high value monomeric constituent of styrene from polystyrene and polyphenylene oxide prior to pyrolysis of other plastic components; separating the high value monomer constituent of styrene; selecting a second higher temperature range to cause pyrolysis to a different derived high value product of polyphenylene oxide from the plastic waste and differentially heating the feed stream at the higher temperature range to cause pyrolysis of the plastic into a polyphenylene oxide derived product; and separating the different derived high value polyphenylene oxide product.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1995-01-01T23:59:59.000Z

80

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polycarbonate and plastic waste to recover monomers  

DOE Patents [OSTI]

A process is described using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents. 68 figs.

Evans, R.J.; Chum, H.L.

1994-06-14T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Controlled catalystic and thermal sequential pyrolysis and hydrolysis of polycarbonate and plastic waste to recover monomers  

DOE Patents [OSTI]

A process of using fast pyrolysis to convert a plastic waste feed stream containing polycarbonate and ABS to high value monomeric constituents prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of a given polymer to its high value monomeric constituents prior to a temperature range that causes pyrolysis of other plastic components; selecting an acid or base catalysts and an oxide or carbonate support for treating the feed stream to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of the high value monomeric constituents of polycarbonate and ABS in the first temperature program range; differentially heating the feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituents prior to pyrolysis or other plastic components; separating the high value monomeric constituents from the polycarbonate to cause pyrolysis to a different high value monomeric constituent of the plastic waste and differentially heating the feed stream at the second higher temperature program range to cause pyrolysis of different high value monomeric constituents; and separating the different high value monomeric constituents.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

82

A review of the toxicity of biomass pyrolysis liquids formed at low temperatures  

SciTech Connect (OSTI)

The scaleup of biomass fast pyrolysis systems to large pilot and commercial scales will expose an increasingly large number of personnel to potential health hazards, especially during the evaluation of the commercial use of the pyrolysis condensates. Although the concept of fast pyrolysis to optimize liquid products is relatively new, low-temperature pyrolysis processes have been used over the aeons to produce charcoal and liquid by-products, e.g., smoky food flavors, food preservatives, and aerosols containing narcotics, e.g., nicotine. There are a number of studies in the historical literature that concern the hazards of acute and long-term exposure to smoke and to the historical pyrolysis liquids formed at low temperatures. The reported toxicity of smoke, smoke food flavors, and fast pyrolysis oils is reviewed. The data found for these complex mixtures suggest that the toxicity may be less than that of the individual components. It is speculated that there may be chemical reactions that take place that serve to reduce the toxicity during aging. 81 refs.

Diebold, J.P. [Thermalchemie, Inc., Lakewood, CO (United States)

1997-04-01T23:59:59.000Z

83

Chapter 1 - Reactor configurations and design parameters for thermochemical conversion of biomass into fuels, energy, and chemicals  

Science Journals Connector (OSTI)

Abstract This chapter describes reactors for thermochemical conversion of lignocellulosic biomass into fuels, energy, and chemicals. The chapter covers basic definitions and concepts involved in biofuels and thermochemical conversion of biomass, and it also includes more advanced topics such as the main reactor configurations currently in use for thermochemical technologies, important parameters for reactor design, discussion of how parameters affect reactor performance, and several examples and case studies. The focus is on fast pyrolysis and gasification systems. The topics discussed include energy and carbon efficiencies, convenience of operation and scale-up, and several other parameters related to reactor design. After reading this chapter, the reader will understand the main characteristics of reactors for thermochemical conversion of biomass, their strengths, and their weaknesses for specific applications.

Fernando L.P. Resende

2014-01-01T23:59:59.000Z

84

Pyrolysis and hydrolysis of mixed polymer waste comprising polyethylene-terephthalate and polyethylene to sequentially recover [monomers  

DOE Patents [OSTI]

A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feed stream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

Evans, R.J.; Chum, H.L.

1998-10-13T23:59:59.000Z

85

Methods and apparatuses for preparing upgraded pyrolysis oil  

DOE Patents [OSTI]

Methods and apparatuses for preparing upgraded pyrolysis oil are provided herein. In an embodiment, a method of preparing upgraded pyrolysis oil includes providing a biomass-derived pyrolysis oil stream having an original oxygen content. The biomass-derived pyrolysis oil stream is hydrodeoxygenated under catalysis in the presence of hydrogen to form a hydrodeoxygenated pyrolysis oil stream comprising a cyclic paraffin component. At least a portion of the hydrodeoxygenated pyrolysis oil stream is dehydrogenated under catalysis to form the upgraded pyrolysis oil.

Brandvold, Timothy A; Baird, Lance Awender; Frey, Stanley Joseph

2013-10-01T23:59:59.000Z

86

Pyrolysis, combustion and gasification characteristics of miscanthus and sewage sludge  

Science Journals Connector (OSTI)

Abstract The energetic conversion of biomass into syngas is considered as reliable energy source. In this context, biomass (miscanthus) and sewage sludge have been investigated. A simultaneous thermal analyzer and mass spectrometer was used for the characterization of samples and identified the volatiles evolved during the heating of the sample up to 1100 °C under combustion and gasification conditions. The TG and DTA results were discussed in argon, oxygen, steam and steam blended gas atmospheres. Different stages of pyrolysis, combustion and gasification of the samples have been examined. It was shown that the combustion and gasification of char were occurred in two different temperature zones. The DTA–MS profile of the sample gives information on combustion and gasification process of the samples (ignition, peak combustion and burnout temperatures) and gases released (H2, O2, CO and CO2). The results showed that the different processes were mainly dependent on temperature. The evolution of the gas species was consistent with the weight loss of the samples during pyrolysis, combustion and gasification process. The effect of the ambiences during pyrolysis, combustion and gasification of the samples were reported. The appropriate temperature range to the sludge and miscanthus gasification was evaluated. The kinetic parameters of the biomass and sewage sludge were estimated for TGA using two models based on first-order reactions with distributed activation energies. The presence of ash in the biomass char was more influential during the gasification process.

Kandasamy Jayaraman; Iskender Gökalp

2015-01-01T23:59:59.000Z

87

Pyrolysis/Gas Chromatography: Application in the Study of Biomass Pyrolysis  

Science Journals Connector (OSTI)

The analytical chemistry technique of pyrolysis/gas chromatography has been applied to the study of biomass pyrolysis. Very small samples of biomass feedstocks were pyrolyzed in a controlled, reproducible manner....

John C. Franklin; James L. Kuester

1988-01-01T23:59:59.000Z

88

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1993-01-01T23:59:59.000Z

89

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

90

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents, selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 87 figures.

Evans, R.J.; Chum, H.L.

1994-04-05T23:59:59.000Z

91

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents, selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

92

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

Evans, R.J.; Chum, H.L.

1994-10-25T23:59:59.000Z

93

Study of Surface Cleaning Methods and Pyrolysis Temperature on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface Cleaning Methods and Pyrolysis Temperature on Nano-Structured Carbon Films using X-ray Photoelectron Study of Surface Cleaning Methods and Pyrolysis Temperature on...

94

Efficiency and Emissions Study of a Residential Micro-cogeneration System based on a Modified Stirling Engine and Fuelled by a Wood Derived Fas Pyrolysis Liquid-ethanol Blend.  

E-Print Network [OSTI]

??A residential micro-cogeneration system based on a Stirling engine unit was modified to operate with wood derived fast pyrolysis liquid (bio-oil)-ethanol blend. A pilot stabilized… (more)

Khan, Umer

2012-01-01T23:59:59.000Z

95

Cellulose Pyrolysis A Literature, Review.  

Office of Scientific and Technical Information (OSTI)

Reaction Mechanisms in Reaction Mechanisms in Cellulose Pyrolysis A Literature, Review. - - pacific N o r t h ~ ~ ~ , baboratwies I - - bCL-T-,,;, .,- , . . . I ' I . - " 1- jl,! # . .' , . - --h 1 , i b - . "I 1.- . . ., .. ' N O T - I C E , , If PACIF tC NORTHWLST U B O R A T ~ R Y .4peiild by B h m E far c h t ,EP4ERGY RESEARCH AN0 PEVELOPMEM ADMtNlSTRAnQN U m h Contract Z Y - ~ ~ - C ~ & I # D w n : m a , m & l 3 Q j l m OIdrfrn m y - !*? 1SI71Y9 1 - m-u3 2s-m .**-2?3 ,Sbca lcPa w m *a0 Iffy &a It- w-% w w @.a SlO.0 m u 6 REACTION MECHANISMS IN CELLULOSE PYROLYSIS A LITERATURE REVIEW by Peter M. Molton T.F. Demmitt Chemical Technology Department BATTELLE Pacific Northwest Laboratories Richland, Washington 99352 CONTENTS . . . . . . . . . . . . . . L I S T OF F I G U R E S iii L I S T O F T A B L E S . . . . . . . . . . . . . . i v . . . . . . . . . . . . . I . INTRODUCTION 1

96

Waste tire recycling by pyrolysis  

SciTech Connect (OSTI)

This project examines the City of New Orleans' waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans' waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city's limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city's waste tire problem. Pending state legislation could improve the city's ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

Not Available

1992-10-01T23:59:59.000Z

97

Conversion of raw carbonaceous fuels  

DOE Patents [OSTI]

Three configurations for an electrochemical cell are utilized to generate electric power from the reaction of oxygen or air with porous plates or particulates of carbon, arranged such that waste heat from the electrochemical cells is allowed to flow upwards through a storage chamber or port containing raw carbonaceous fuel. These configurations allow combining the separate processes of devolatilization, pyrolysis and electrochemical conversion of carbon to electric power into a single unit process, fed with raw fuel and exhausting high BTU gases, electric power, and substantially pure CO.sub.2 during operation.

Cooper, John F. (Oakland, CA)

2007-08-07T23:59:59.000Z

98

Volatile constituents in a wood pyrolysis oil  

E-Print Network [OSTI]

Science VOLATILE CONSTITUTENTS IN A WOOD PYROLYSIS OIL A Thesis SHIH-CHIEN LIN Appro d as to style and content by: (Chairman of Committee) Head of epa tmen (Member Member Nay 1978 442936 ABSTRACT Volatile Constituents in a Wood Pyrolysis Oil.../120 Supelcoport. Other trace constituents of volatile acid were also 'dentifi="' by trap- ping the substances from the C. C. column into i: n;- 0-sh ped capillary tube and subjecting to mass spectrometry. The corrosivity of pyrolysis oil and it, volati'e acids...

Lin, Shih-Chien

1978-01-01T23:59:59.000Z

99

Pyrolysis of shale oil residual fractions  

SciTech Connect (OSTI)

The freezing point of JP-5, the Navy jet fuel, has been related to the n-alkane content, specifically n-hexadecane. In general, jet fuels from shale oil have the highest n-alkanes. The formation of n-alkanes in the jet fuel distillation range can be explained if large n-alkanes are present in the crude oil source. Quantities of large n-alkanes are insufficient, however, to explain the amounts found - up to 37% n-alkanes in the jet fuel range. Other possible precursors to small straight chain molecules are substituted cyclic compounds. Attack in the side chain obviously afford a path to an n-alkane. Aromatic hydrocarbons, esters, acids, amines, and ethers also have the potential to form n-alkanes if an unbranched alkyl chain is present in the molecule. Investigations showed that the best yield of the JP-5 cut comes at different times for the various fractions, but a time in the 60 to 120 min range would appear to be the optimum time for good yield at 450/sup 0/C. The longer time would be preferred with respect to lower potential n-alkane yield. None of the fractions gave n-alkane yields approaching the 37% amount found in the Shale-I JP-5. A temperature different than the 450/sup 0/C used here might affect the conversion percentage. Further the combined saturate, aromatic, and polar fractions may interact under pyrolysis conditions to give higher potential n-alkane yields than the fractions stressed independently.

Hazlett, R.N.; Beal, E.; Vetter, T.; Sonntag, R.; Moniz, W.

1980-01-01T23:59:59.000Z

100

Waste tire recycling by pyrolysis  

SciTech Connect (OSTI)

This project examines the City of New Orleans` waste tire problem. Louisiana State law, as of January 1, 1991, prohibits the knowing disposal of whole waste tires in landfills. Presently, the numerous waste tire stockpiles in New Orleans range in size from tens to hundreds of tires. New Orleans` waste tire problem will continue to increase until legal disposal facilities are made accessible and a waste tire tracking and regulatory system with enforcement provisions is in place. Tires purchased outside of the city of New Orleans may be discarded within the city`s limits; therefore, as a practical matter this study analyzes the impact stemming from the entire New Orleans metropolitan area. Pyrolysis mass recovery (PMR), a tire reclamation process which produces gas, oil, carbon black and steel, is the primary focus of this report. The technical, legal and environmental aspects of various alternative technologies are examined. The feasibility of locating a hypothetical PMR operation within the city of New Orleans is analyzed based on the current economic, regulatory, and environmental climate in Louisiana. A thorough analysis of active, abandoned, and proposed Pyrolysis operations (both national and international) was conducted as part of this project. Siting a PMR plant in New Orleans at the present time is technically feasible and could solve the city`s waste tire problem. Pending state legislation could improve the city`s ability to guarantee a long term supply of waste tires to any large scale tire reclamation or recycling operation, but the local market for PMR end products is undefined.

Not Available

1992-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Ammonia evolution during oil shale pyrolysis  

Science Journals Connector (OSTI)

Ammonia evolution during oil shale pyrolysis ... Parallel pyrolytic studies were carried out on an immature, ultralaminae-rich, type I kerogen (Göynük oil shale kerogen) and a related algaenan (isolated from the extant green microalga Scenedesmus communis). ...

Myongsook S. Oh; Robert W. Taylor; Thomas T. Coburn; Richard W. Crawford

1988-01-01T23:59:59.000Z

102

Pyrolysis of waste tyres: A review  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Pyrolysis of waste tyres produces oil, gas and char, and recovered steel. • Batch, screw kiln, rotary kiln, vacuum and fluidised-bed are main reactor types. • Product yields are influenced by reactor type, temperature and heating rate. • Pyrolysis oils are complex and can be used as chemical feedstock or fuel. • Research into higher value products from the tyre pyrolysis process is reviewed. - Abstract: Approximately 1.5 billion tyres are produced each year which will eventually enter the waste stream representing a major potential waste and environmental problem. However, there is growing interest in pyrolysis as a technology to treat tyres to produce valuable oil, char and gas products. The most common reactors used are fixed-bed (batch), screw kiln, rotary kiln, vacuum and fluidised-bed. The key influence on the product yield, and gas and oil composition, is the type of reactor used which in turn determines the temperature and heating rate. Tyre pyrolysis oil is chemically very complex containing aliphatic, aromatic, hetero-atom and polar fractions. The fuel characteristics of the tyre oil shows that it is similar to a gas oil or light fuel oil and has been successfully combusted in test furnaces and engines. The main gases produced from the pyrolysis of waste tyres are H{sub 2}, C{sub 1}–C{sub 4} hydrocarbons, CO{sub 2}, CO and H{sub 2}S. Upgrading tyre pyrolysis products to high value products has concentrated on char upgrading to higher quality carbon black and to activated carbon. The use of catalysts to upgrade the oil to a aromatic-rich chemical feedstock or the production of hydrogen from waste tyres has also been reported. Examples of commercial and semi-commercial scale tyre pyrolysis systems show that small scale batch reactors and continuous rotary kiln reactors have been developed to commercial scale.

Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk

2013-08-15T23:59:59.000Z

103

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polymer waste comprising nylon 6 and a polyolefin or mixtures of polyolefins to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

Evans, R.J.; Chum, H.L.

1994-10-25T23:59:59.000Z

104

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of polymer waste comprising nylon 6 and a polyolefin or mixtures of polyolefins to sequentially recover monomers or other high value products  

DOE Patents [OSTI]

A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

1994-01-01T23:59:59.000Z

105

Recycling of automobile shredder residue with a microwave pyrolysis combined with high temperature steam gasification  

Science Journals Connector (OSTI)

Presently, there is a growing need for handling automobile shredder residues – ASR or “car fluff”. One of the most promising methods of treatment ASR is pyrolysis. Apart of obvious benefits of pyrolysis: energy and metals recovery, there is serious concern about the residues generated from that process needing to be recycled. Unfortunately, not much work has been reported providing a solution for treatment the wastes after pyrolysis. This work proposes a new system based on a two-staged process. The ASR was primarily treated by microwave pyrolysis and later the liquid and solid products become the feedstock for the high temperature gasification process. The system development is supported within experimental results conducted in a lab-scale, batch-type reactor at the Royal Institute of Technology (KTH). The heating rate, mass loss, gas composition, LHV and gas yield of producer gas vs. residence time are reported for the steam temperature of 1173 K. The sample input was 10 g and the steam flow rate was 0.65 kg/h. The conversion reached 99% for liquids and 45–55% for solids, dependently from the fraction. The H2:CO mol/mol ratio varied from 1.72 solids and 1.4 for liquid, respectively. The average LHV of generated gas was 15.8 MJ/N m3 for liquids and 15 MJ/N m3 for solids fuels.

Pawel Donaj; Weihong Yang; W?odzimierz B?asiak; Christer Forsgren

2010-01-01T23:59:59.000Z

106

Molecular beam mass spectrometric characterization of biomass pyrolysis products for fuels and chemicals  

SciTech Connect (OSTI)

Converting biomass feedstocks to fuels and chemicals requires rapid characterization of the wide variety of possible feedstocks. The combination of pyrolysis molecular beam mass spectrometry (Py-MBMS) and multivariate statistical analysis offers a unique capability for characterizing these feedstocks. Herbaceous and woody biomass feedstocks that were harvested at different periods were used in this study. The pyrolysis mass spectral data were acquired in real time on the MBMS, and multivariate statistical analysis (factor analysis) was used to analyze and classify Py-MBMS data into compound classes. The effect of harvest times on the thermal conversion of these feedstocks was assessed from these data. Apart from sericea lespedeza, the influence of harvest time on the pyrolysis products of the various feedstocks was insignificant. For sericea lespedeza, samples harvested before plant defoliation were significantly different from those harvested after defoliation. The defoliated plant samples had higher carbohydrate-derived pyrolysis products than the samples obtained from the foliated plant. Additionally, char yields from the defoliated plant samples were lower than those from the foliated plant samples.

Agblevor, F.A.; Davis, M.F.; Evans, R.J. [National Renewal Energy Lab., Golden, CO (United States)

1994-12-31T23:59:59.000Z

107

Fast pyrolysis of a waste fraction of high impact polystyrene (HIPS) containing brominated flame retardants in a fluidized bed reactor: The effects of various Ca-based additives (CaO, Ca(OH)2 and oyster shells) on the removal of bromine  

Science Journals Connector (OSTI)

A waste fraction of high impact polystyrene (HIPS) containing brominated flame retardants and antimony trioxide (Sb2O3) as a synergist was pyrolyzed in a bench-scale system equipped with a fluidized bed and char separation system. Experiments were carried out to observe the effects of the reaction temperature and three additives (CaO, Ca(OH)2, oyster shells) on the removal of bromine. An analysis of the pyrolysis oils obtained showed the oils were mainly composed of toluene, ethyl-benzene, styrene, cumene, ?-methylstyrene, 1,3-diphenylpropane, 1,3-diphenylbutane and (1-bromoethyl)-benzene. When the Ca-based additives were used, the concentration of styrene was markedly increased; whereas, those of ethlybenzene and cumene were reduced. The total bromine content of pyrolysis oil produced without any additive at 459 °C was about 5 wt.%. When Ca(OH)2 and oyster shells were applied, the total bromine contents of the pyrolysis oils were decreased to 1.3 and 2.7 wt.%, respectively. The antimony content in the pyrolysis oil was relatively small due to the efficient operation of the char separation system.

Su-Hwa Jung; Seon-Jin Kim; Joo-Sik Kim

2012-01-01T23:59:59.000Z

108

Overview of Applications of Biomass Fast Pyrolysis Oil  

Science Journals Connector (OSTI)

National Bioenergy Center NREL, 1617 Cole Boulevard, Golden, Colorado 80401, and Bio-Energy Research Group, Aston University, Birmingham B4 7ET, UK ... The paper critically reviews scientific and technical developments in applications of bio-oil to date and concludes with some suggestions for research and strategic developments. ... Literature Review. ...

S. Czernik; A. V. Bridgwater

2004-02-26T23:59:59.000Z

109

BIOMASS PRETREATMENT FOR INCREASED ANHYDROSUGARS YIELD DURING FAST PYROLYSIS.  

E-Print Network [OSTI]

??Production of liquid fuels is a high national priority to provide transporation fuels. Production of liquid bio-fuels from biomass has been idenfied as a viable… (more)

Li, Qi

2009-01-01T23:59:59.000Z

110

Pyrolysis Research: Bioenergy Testing and Analysis Laboratory BIOENERGY PROGRAM  

E-Print Network [OSTI]

Pyrolysis Research: Bioenergy Testing and Analysis Laboratory BIOENERGY PROGRAM Pyrolysis research is conducted at Texas A&M University at the Bioenergy Testing and Analysis Laboratory. Our researchers create

111

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

SciTech Connect (OSTI)

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2014-10-07T23:59:59.000Z

112

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

DOE Patents [OSTI]

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christpher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

113

Controlled catalytic and thermal sequential pyrolysis and hydrolysis of mixed polymer waste streams to sequentially recover monomers or other high value products  

SciTech Connect (OSTI)

A process of using fast pyrolysis in a carrier gas to convert a polyamide containing a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polyamide and its high value monomeric constituent or derived high value products occurs prior to pyrolysis of other plastic components is described therein comprising: (a) selecting a first temperature program range to cause pyrolysis of said given polyamide and its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; (b) selecting a catalyst and a support and treating said feed stream with said catalyst to affect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent or high value product of said polyamide in said first temperature program range; (c) differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of said high value monomeric constituent or high value product of said polyamide prior to pyrolysis of other plastic components therein; (d) separating said high value monomer constituent or derived high value product of said polyamide; (e) selecting a second higher temperature program range to cause pyrolysis to a different high value monomeric constituent of said plastic waste and differentially heating said feed stream of said higher temperature program range to cause pyrolysis of said plastic into a different high value monomeric constituent or derived product; and (f) separating said different high value monomeric constituent or derived high value product.

Evans, R.J.; Chum, H.L.

1993-06-01T23:59:59.000Z

114

Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride  

SciTech Connect (OSTI)

Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

1995-12-31T23:59:59.000Z

115

Energy Evaluation for Lignite Pyrolysis by Solid Heat Carrier Coupled with Gasification  

Science Journals Connector (OSTI)

Between the two reactors, solid heat carriers are circulated to carry the heat from the gasifier to the pyrolyzer. ... With the purpose of revealing the features of energy use and chemical element conversion, and the feasibility and the rationality of the coupled system, some related experiments were performed, and the simulation flow sheet for lignite pyrolysis by a solid heat carrier coupled with gasification was established by Aspen Plus 11.1 on the basis of the experimental data. ... The amount of the solid heat carrier was determined by two factors: (1) the temperature of the solid heat carrier should be heated to 750 °C in the combustion furnace; (2) the energy carried by the solid heat carrier must be sufficient to satisfy the energy demands of the drying and pyrolysis units. ...

Qun Yi; Jie Feng; Bingchuan Lu; Jing Deng; Changlian Yu; Wenying Li

2013-07-12T23:59:59.000Z

116

Pyrolysis of Organic Molecules Relevant to Combustion as Monitored by Photoionization Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

of Small Molecules by Flash Pyrolysis, University ofapproach of coupling flash pyrolysis of the compound ofZhang, Chairperson Flash pyrolysis coupled to molecular beam

Weber, Kevin Howard

2010-01-01T23:59:59.000Z

117

Thermal Decomposition of Molecules Relevant to Combustion and Chemical Vapor Deposition by Flash Pyrolysis Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

of Small Molecules by Flash Pyrolysis, University ofwas performed using flash pyrolysis vacuum-ultraviolet time-Vapor Deposition by Flash Pyrolysis Time-of-Flight Mass

Lemieux, Jessy Mario

2013-01-01T23:59:59.000Z

118

Catalytic pyrolysis using UZM-44 aluminosilicate zeolite  

DOE Patents [OSTI]

A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2014-04-29T23:59:59.000Z

119

Catalytic pyrolysis using UZM-44 aluminosilicate zeolite  

DOE Patents [OSTI]

A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula Na.sub.nM.sub.m.sup.k+T.sub.tAl.sub.1-xE.sub.xSi.sub.yO.sub.z where "n" is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, "m" is the mole ratio of M to (Al+E), "k" is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-44 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

120

Conversion Tables  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Dioxide Information Analysis Center - Conversion Tables Carbon Dioxide Information Analysis Center - Conversion Tables Contents taken from Glossary: Carbon Dioxide and Climate, 1990. ORNL/CDIAC-39, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, Oak Ridge, Tennessee. Third Edition. Edited by: Fred O'Hara Jr. 1 - International System of Units (SI) Prefixes 2 - Useful Quantities in CO2 3 - Common Conversion Factors 4 - Common Energy Unit Conversion Factors 5 - Geologic Time Scales 6 - Factors and Units for Calculating Annual CO2 Emissions Using Global Fuel Production Data Table 1. International System of Units (SI) Prefixes Prefix SI Symbol Multiplication Factor exa E 1018 peta P 1015 tera T 1012 giga G 109 mega M 106 kilo k 103 hecto h 102 deka da 10 deci d 10-1 centi c 10-2

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Biomass Conversion  

Science Journals Connector (OSTI)

Accounting for all of the factors that go into energy demand (population, vehicle miles traveled per ... capita, vehicle efficiency) and land required for energy production (biomass land yields, biomass conversion

Stephen R. Decker; John Sheehan…

2012-01-01T23:59:59.000Z

122

Fuel nitrogen release during black liquor pyrolysis; Part 1: Laboratory measurements at different conditions  

SciTech Connect (OSTI)

Fuel nitrogen release during black liquor pyrolysis is high. There is only minor release during the drying stage. Ammonia is the main fixed nitrogen species formed. The rate of fixed nitrogen release increases with increasing temperature. The level of fixed nitrogen released by birch liquor is almost twice the level for pine liquor. Assuming complete conversion to NO, fixed nitrogen yields gave NO concentrations near typically measured values for flue gases in full scale recovery boilers. The purpose of this work was to gain more detailed information about the behavior of the fuel nitrogen in black liquor combustion. The work focused on the pyrolysis or devolatilization of the combustion process. Devolatilization is the stage at which the majority (typically 50--80%) of the liquor organics release from a fuel particle or droplet as gaseous species due to the rapid destruction of the organic macromolecules in the liquor. In this paper, the authors use the terms devolatilization and pyrolysis interchangeably with no difference in their meaning.

Aho, K.; Vakkilainen, E. (A. Ahistrom Corp., Varkaus (Finland)); Hupa, M. (Abo Akademi Univ., Turku (Finland). Chemical Engineering Dept.)

1994-05-01T23:59:59.000Z

123

Effects of torrefaction and densification on switchgrass pyrolysis products  

SciTech Connect (OSTI)

Abstract The pyrolysis behaviors of four types of pretreated switchgrass (torrefied at 230 and 270 °C, densification, and torrefaction at 270 ºC followed by densification) were studied at three temperatures (500, 600, 700 ºC) using a pyroprobe attached to a gas chromatogram mass spectroscopy (Py-GC/MS). The torrefaction of switchgrass improved its oxygen to carbon ratio and energy content. Contents of anhydrous sugars and phenols in pyrolysis products of torrefied switchgrass were higher than those in pyrolysis products of raw switchgrass. As the torrefaction temperature increased from 230 to 270 °C, the contents of anhydrous sugars and phenols in pyrolysis products increased whereas content of guaiacols decreased. High pyrolysis temperature (600 and 700 °C as compared to 500 °C) enhanced decomposition of lignin and anhydrous sugars, leading to increase in phenols, aromatics and furans. Densification enhanced depolymerization of cellulose and hemicellulose during pyrolysis.

Yang, Z; Sarkar, M; Kumar, A; Jaya Shankar Tumuluru; R.L. Huhnke

2014-10-01T23:59:59.000Z

124

Accepted Manuscript Kinetic modelling of high density polyethylene pyrolysis: Part 2. Reduction of existing  

E-Print Network [OSTI]

Accepted Manuscript Kinetic modelling of high density polyethylene pyrolysis: Part 2. Reduction density polyethylene pyrolysis: Part 2. Reduction of existing detailed mechanism, Polymer Degradation Modelling of High Density PolyEthylene Pyrolysis: Part 2. Reduction of existing detailed mechanism. N

Paris-Sud XI, Université de

125

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network [OSTI]

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

126

Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina*  

E-Print Network [OSTI]

1/28 Dynamic study of coupled heavy hydrocarbon pyrolysis and combustion. N. Gascoina* , P of the heat transfer dynamics. Finally, the combustion mechanism is applied and validated experimentally for kerosene pyrolysis application. Keywords Regenerative cooling; Hydrocarbon pyrolysis; Supersonic Combustion

Boyer, Edmond

127

U.S., Canada, and Finland Pyrolysis Collaborations  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

feeds to compare bio-oil product quality - Evaluate pyrolysis oil vapor quality by small scale analysis - Understand upgrading requirements for bio-oil from low quality...

128

U.S., Canada, and Finland Pyrolysis Collaborations  

Broader source: Energy.gov [DOE]

Jonathan Male, PNNL, presentation at the December 5, 2012, Biomass Program-hosted International webinar on U.S., Canada, and Finland pyrolysis collaborations.

129

Utilization of pyrolysis oil in industrial scale boilers.  

E-Print Network [OSTI]

??The performance of pyrolysis oil in a large-scale combustion system is investigated to determine the feasibility of displacing fuel oil or natural gas in current… (more)

Redfern, Kyle D.

2013-01-01T23:59:59.000Z

130

Coke resistant coating technology for applications in ethylene pyrolysis heaters.  

E-Print Network [OSTI]

?? This dissertation begins with a description of the history of the events leading to ethylene pyrolysis tube failure. During service, hydrocarbons pass through the… (more)

Chauhan, Alok Pratap Singh

2008-01-01T23:59:59.000Z

131

Process for minimizing solids contamination of liquids from coal pyrolysis  

DOE Patents [OSTI]

In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.

Wickstrom, Gary H. (Yorba Linda, CA); Knell, Everett W. (Los Alamitos, CA); Shaw, Benjamin W. (Costa Mesa, CA); Wang, Yue G. (West Covina, CA)

1981-04-21T23:59:59.000Z

132

Technical Information Exchange on Pyrolysis Oil: Potential for...  

Broader source: Energy.gov (indexed) [DOE]

renewable heating oil substitution Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution Two-day agenda from the workshop: Technical...

133

Study of the mechanism of pyrolysis and gasification of Mallee biomass.  

E-Print Network [OSTI]

??Mechanisms of pyrolysis/gasification (steam and carbon dioxide) of mallee biomass were investigated. Wood biochar obtained under slow pyrolysis kept botanical structure but lost its original… (more)

Yang, Yanwu

2012-01-01T23:59:59.000Z

134

Catalytic microwave torrefaction and pyrolysis of Douglas fir pellet to improve biofuel quality .  

E-Print Network [OSTI]

??The aims of this dissertation were to understand the effects of torrefaction as pretreatment on biomass pyrolysis and catalytic pyrolysis for improving biofuel quality, and… (more)

[No author

2012-01-01T23:59:59.000Z

135

Pyrolysis behavior of coal and petroleum coke at high temperature and high pressure.  

E-Print Network [OSTI]

??While pyrolysis of coal is a well-studied thermal process, little is known about pressurized pyrolysis of coal and petroleum coke. This study aims to interpret… (more)

Wagner, David Ray

2011-01-01T23:59:59.000Z

136

Fast Beam Studies of Free Radical Photodissociation  

E-Print Network [OSTI]

radicals. 37 They employ a flash pyrolysis source, having abond on undergoing flash pyrolysis. Our approach to the

Cyr, D.R.

2010-01-01T23:59:59.000Z

137

Pyrolysis of automotive shredder residues: a lumped kinetic characterization  

Science Journals Connector (OSTI)

A lumped kinetic model for the pyrolysis of industrial wastes of unknown chemical composition is developed. The model is applied to the pyrolysis of automotive shredder residues (ASRs), studied by means of thermogravimetric and calorimetric analyses, in isothermal and non-isothermal conditions.

Oreste Patierno; Paola Cipriani; Fausto Pochetti; Massimiliano Giona

1998-01-01T23:59:59.000Z

138

Accepted Manuscript Title: Fuel Pyrolysis through Porous Media: Coke Formation  

E-Print Network [OSTI]

Accepted Manuscript Title: Fuel Pyrolysis through Porous Media: Coke Formation and Coupled effect. Gascoin, P. Gillard, M. Bouchez, J. Steelant, Fuel Pyrolysis through Porous Media: Coke Formation Coke Formation and Coupled effect on Permeability2 G. Fau1* , N. Gascoin1 , P. Gillard1 , M. Bouchez2

Paris-Sud XI, Université de

139

NITROGEN EVOLUTION AND SOOT FORMATION DURING SECONDARY COAL PYROLYSIS  

E-Print Network [OSTI]

NITROGEN EVOLUTION AND SOOT FORMATION DURING SECONDARY COAL PYROLYSIS by Haifeng Zhang DURING SECONDARY COAL PYROLYSIS Haifeng Zhang Department of Chemical Engineering Doctor of Philosophy Economical NOx control techniques used in pulverized coal furnaces, such as air/fuel staging, promote

Fletcher, Thomas H.

140

Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a  

E-Print Network [OSTI]

in the coal without chemical decomposition and pyrolysis converts dry coal into gas and coke [1]. The final1 Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a , Eric Blond1, b , Alain Gasser1 Forbach, France a damintode.kolani@univ-orleans.fr, b eric.blond@univ-orleans.fr Keywords: coal, drying

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Vacuum pyrolysis of bark residues and primary sludges  

SciTech Connect (OSTI)

Black spruce bark residues and primary sludges derived from the operation of the Daishowa pulp and paper plant in Quebec City, PQ, were processed by vacuum pyrolysis in a laboratory-scale batch reactor. The pyrolysis oil, water, charcoal, and gas were recovered and analyzed. The bark residues yielded 30.6% oil and 34.1% charcoal, and the primary sludges gave 40.1% oil and 30.1% charcoal on a feedstock air-dry basis. The oil phases recovered from the two pyrolysis experiments were fractionated into eight fractions; they were analyzed by gas chromatography/mass spectrometry. Both pyrolysis oil samples had a high content of phenolic compounds. These oils contained various fine chemicals that have possible commercial potential. Aliphatic and aromatic hydrocarbons, as well as long- and short-chain carboxylic acids, are also present in both pyrolysis oils.

Pakdel, H.; Couture, G.; Roy, C. (Univ. Laval, Ste-Foy, Quebec (Canada))

1994-07-01T23:59:59.000Z

142

Chemistry of Furan Conversion into Aromatics and Olefins over HZSM-5: A Model Biomass Conversion Reaction  

Science Journals Connector (OSTI)

(5, 6) The ideal process to produce biofuels from lignocellulosic biomass would be a single step reactor at short residence times where solid biomass is directly converted into a liquid fuel. ... with converting plant biomass into commodity products are considered relative to overcoming the recalcitrance of cellulosic biomass (converting cellulosic biomass into reactive intermediates) and product diversification (converting reactive intermediates into useful products). ... conversion processes that include combustion, gasification, liquefaction, hydrogenation and pyrolysis, have been used to convert the biomass into various energy products. ...

Yu-Ting Cheng; George W. Huber

2011-04-26T23:59:59.000Z

143

New Framework Transforms FAST Wind Turbine Modeling Tool (Fact...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for modeling multisegmented mooring quasi-static behaviors of floating offshore wind turbines; and full conversion of FAST into the new modularization framework. Features of...

144

The conversion of acetol during the concentration process from wood vinegar  

Science Journals Connector (OSTI)

Acetol, as one of the components of biomass pyrolysis liquid, is a high value-added compound for medicine synthesis. If acetol can be extracted from the renewable pyrolysis liquid, much environmental and economic benefit may be obtained; but the instability of acetol makes its concentration difficult. To clarify what compounds are formed from acetol during the distillation process, the components in different distillation systems were analysed and the mechanisms of the conversions were speculated on. It was found that acetol may undergo aldol self-condensation reactions followed by a series of intramolecular dehydrations to form five-ring or six-ring compounds.

Ze Wang; Weigang Lin; Wenli Song; Jianzhong Yao

2009-01-01T23:59:59.000Z

145

Effect of biomass feedstock chemical and physical properties on energy conversion processes: Volume 1, Overview  

SciTech Connect (OSTI)

Pacific Northwest Laboratory has completed an initial investigation of the effects of physical and chemical properties of biomass feedstocks relative to their performance in biomass energy conversion systems. Both biochemical conversion routes (anaerobic digestion and ethanol fermentation) and thermochemical routes (combustion, pyrolysis, and gasification) were included in the study. Related processes including chemical and physical pretreatment to improve digestibility, and size and density modification processes such as milling and pelletizing were also examined. This overview report provides background and discussion of feedstock and conversion relationships, along with recommendations for future research. The recommendations include (1) coordinate production and conversion research programs; (2) quantify the relationship between feedstock properties and conversion priorities; (3) develop a common framework for evaluating and characterizing biomass feedstocks; (4) include conversion effects as part of the criteria for selecting feedstock breeding programs; and (5) continue emphasis on multiple feedstock/conversion options for biomass energy systems. 9 refs., 3 figs., 2 tabs.

Butner, R.S.; Elliott, D.C.; Sealock, L.J. Jr.; Pyne, J.W.

1988-12-01T23:59:59.000Z

146

Diesel Engine Combustion of Biomass Pyrolysis Oils  

Science Journals Connector (OSTI)

Biomass pyrolysis oils are manufactured through a moderate-temperature process (?500 °C) in which the biomass feedstock is subjected to rapid heating in the absence of air, where it vaporizes, cracks, and is condensed after a short residence time (?500 ms) into a dark brown liquid composed of a complex mixture of oxygenated hydrocarbons whose heating value is approximately half that of No. 2 diesel fuel. ... The combustion air inlet temperature can be preheated up to 130 °C through the use of an in-line electric heater, which allows engine operation with fuels that have long ignition delay, without relying on any ignition additives. ... Their data showed that in addition to reducing the peak heat release magnitude, slower chemical kinetics resulted in reduced rate of instantaneous heat release (the slope of the instantaneous heat release curve) in the early combustion phase, resulting in delayed peak heat release timing relative to SOC. ...

Alan Shihadeh; Simone Hochgreb

2000-02-15T23:59:59.000Z

147

Fluidized bed selective pyrolysis of coal  

DOE Patents [OSTI]

The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

Shang, Jer Y. (McLean, VA); Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY)

1992-01-01T23:59:59.000Z

148

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of US Navy jet fuel (JP-5) has been related to the amounts of large n-alkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how the n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30, and 32 ppM in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-01-01T23:59:59.000Z

149

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of U.S. Navy jet fuel (JP-5) has been related to the amounts of large nalkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how th n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30 and 32 ppm in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-02-01T23:59:59.000Z

150

Multistep pyrolysis kinetics of North Korean oil shale  

Science Journals Connector (OSTI)

In this paper, multistep pyrolysis kinetics of North Korean oil shale was investigated by thermogravimetric analysis. All the...?1...from room temperature to 873 K under nitrogen atmosphere. The main oil-producin...

Wei Wang; Shuyuan Li; Changtao Yue; Yue Ma

2014-10-01T23:59:59.000Z

151

CATALYTIC MICROWAVE PYROLYSIS OF BIOMASS FOR RENEWABLE PHENOLS AND FUELS .  

E-Print Network [OSTI]

??Bio-oil is an unstable intermediate and needs to be upgraded before its use. This study focused on improving the selectivity of bio-oilby catalytic pyrolysis of… (more)

[No author

2013-01-01T23:59:59.000Z

152

Pyrolysis—Gas Chromatography: A Bibliography (1960–1963)  

Science Journals Connector (OSTI)

......THE PYROLYSIS OF TOULENE, Price, S. J., Can. J. Chem...CHROMATOGRAPHIC ANALYSIS OF POLY(ETHYLENE ETHYLACRYLATE) AND POLY(ETHYLENE VINYL ACETATE) PYROLY- SATES...CHROMATOGRAPHIC ANALYSIS OF POLY(ETHYLENE ETHYL ACRYLATE) AND POLY......

R. W. McKinney

1964-12-01T23:59:59.000Z

153

Technical Information Exchange on Pyrolysis Oil: Potential for...  

Broader source: Energy.gov (indexed) [DOE]

Renewab;e Heating Oil Substation Fuel in New England Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England This...

154

Analysis and comparison of biomass pyrolysis/gasification condensates: Final report  

SciTech Connect (OSTI)

This report provides results of chemical and physical analysis of condensates from eleven biomass gasification and pyrolysis systems. The samples were representative of the various reactor configurations being researched within the Department of Energy, Biomass Thermochemical Conversion program. The condensates included tar phases and aqueous phases. The analyses included gross compositional analysis (elemental analysis, ash, moisture), physical characterization (pour point, viscosity, density, heat of combustion, distillation), specific chemical analysis (gas chromatography/mass spectrometry, infrared spectrophotometry, proton and carbon-13 nuclear magnetic resonance spectrometry) and biological activity (Ames assay and mouse skin tumorigenicity tests). These results are the first step of a longer term program to determine the properties, handling requirements, and utility of the condensates recovered from biomass gasification and pyrolysis. The analytical data demonstrates the wide range of chemical composition of the organics recovered in the condensates and suggests a direct relationship between operating temperature and chemical composition of the condensates. A continuous pathway of thermal degradation of the tar components as a function of temperature is proposed. Variations in the chemical composition of the organic components in the tars are reflected in the physical properties of tars and phase stability in relation to water in the condensate. The biological activity appears to be limited to the tars produced at high temperatures. 56 refs., 25 figs., 21 tabs.

Elliott, D.C.

1986-06-01T23:59:59.000Z

155

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents [OSTI]

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

156

Isothermal pyrolysis and char combustion of oil shales  

SciTech Connect (OSTI)

Yields and rates of hydrocarbons evolved during pyrolysis of oil shales have been measured with improved accuracy. Green River and New Albany oil shales were heated in a fluidized sand bed, and volatile pyrolysis products were transferred to a combustion tube and burned. Resulting H/sub 2/O and CO/sub 2 were detected in real time by mass spectrometry. Residual char was subsequently burned to allow complete C and H balances. Good closure was obtained. Proportions of organic C and H released as pyrolysis products and retained as char were determined. Shale oil loss due to the presence of oxidized shale in the fluidized bed was measured accurately. We find that all of the experimental apparatus that the pyrolysis gas contacts must be near pyrolysis temperature to avoid condensation of heavy oil which subsequently forms coke and secondary products. We observe a faster release of products with all transfer lines 450/degree/C than when they are at 300/degree/C. The current uncertainty in pyrolysis rates is due in part to such difficulties with experimental techniques. 12 refs., 7 figs., 1 tab.

Coburn, T.T.; Taylor, R.W.; Morris, C.J.; Duval, V.

1988-02-03T23:59:59.000Z

157

Low oxygen biomass-derived pyrolysis oils and methods for producing the same  

DOE Patents [OSTI]

Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

2013-08-27T23:59:59.000Z

158

Kinetic Model Development for Lignin Pyrolysis  

SciTech Connect (OSTI)

Lignin pyrolysis poses a significant barrier to the formation of liquid fuel products from biomass. Lignin pyrolyzes at higher temperatures than other biomass components (e.g. cellulose and hemi-cellulose) and tends to form radicals species that lead to cross-linking and ultimately char formation. A first step in the advancement of biomass-to-fuel technology is to discover the underlying mechanisms that lead to the breakdown of lignin at lower temperatures into more stable and usable products. We have investigated the thermochemistry of the various inter-linkage units found in lignin (B-O4, a-O4, B-B, B-O5, etc) using electronic structure calculations at the M06-2x/6-311++G(d,p) on a series of dimer model compounds. In addition to bond homolysis reactions, a variety of concerted elimination pathways are under investigation that tend to produce closed-shell stable products. Such a bottom-up approach could aid in the targeted development of catalysts that produce more desirable products under less severe reactor conditions.

Clark, J.; Robichaud, D.; Nimlos, M.

2012-01-01T23:59:59.000Z

159

Autothermal oxidative pyrolysis of biomass feedstocks over noble metal catalysts to liquid products.  

E-Print Network [OSTI]

??Two thermal processing technologies have emerged for processing biomass into renewable liquid products: pyrolysis and gasification/Fischer-Tropsch processing. The work presented here will demonstrate oxidative pyrolysis… (more)

Balonek, Christine Marie

2011-01-01T23:59:59.000Z

160

Pyrolysis of Municipal Solid Waste for Syngas Production by Microwave Irradiation  

Science Journals Connector (OSTI)

In the present study, we discuss the application of microwave-irradiated pyrolysis of municipal solid waste (MSW) for total recovery of useful gases and energy. The MSW pyrolysis under microwave irradiation hi...

Vidyadhar V. Gedam; Iyyaswami Regupathi

2012-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Biomass pyrolysis processes: performance parameters and their influence on biochar system benefits   

E-Print Network [OSTI]

This study focuses on performance of biomass pyrolysis processes for use in biochar systems. Objectives are to understand the range of control of such processes and how this affects potential benefits of pyrolysis biochar ...

Brownsort, Peter A

2009-01-01T23:59:59.000Z

162

Computational Analysis of the Pyrolysis of ..beta..-O4 Lignin Model Compounds: Concerted vs. Homolytic Fragmentation  

SciTech Connect (OSTI)

The thermochemical conversion of biomass to liquid transportation fuels is a very attractive technology for expanding the utilization of carbon neutral processes and reducing dependency on fossil fuel resources. As with all such emerging technologies, biomass conversion through gasification or pyrolysis has a number of obstacles that need to be overcome to make these processes cost competitive with the refining of fossil fuels. Our current efforts have focused on the investigation of the thermochemistry of the linkages between lignin units using ab initio calculations on dimeric lignin model compounds. All calculations were carried out using M062X density functional theory at the 6-311++G(d,p) basis set. The M062X method has been shown to be consistent with the CBS-QB3 method while being significantly less computationally expensive. To date we have only completed the study on the b-O4 compounds. The theoretical calculations performed in the study indicate that concerted elimination pathways dominate over bond homolysis reactions under typical pyrolysis conditions. However, this does not mean that concerted elimination will be the dominant loss process for lignin. Bimolecular radical chemistry could very well dwarf the unimolecular pathways investigated in this study. These concerted pathways tend to form stable, reasonably non-reactive products that would be more suited producing a fungible bio-oil for the production of liquid transportation fuels.

Clark, J. M.; Robichaud, D. J.; Nimlos, M. R.

2012-01-01T23:59:59.000Z

163

Pyrolysis of lignin for phenols with alkaline additive  

Science Journals Connector (OSTI)

Abstract This study is devoted to investigating the effect of alkaline additives on lignin pyrolysis for producing phenols. The effects of different types and amounts of alkaline additives, i.e., 0–20 wt.% NaOH, KOH, Na2CO3 or K2CO3, on lignin pyrolysis were tested in a fixed bed reactor. The chemicals in the pyrolysis liquid from a commercial alkali lignin with and without alkaline additive were mainly phenols including 2-methoxy-phenol, 2,6-dimethoxy-phenol, alkyl-phenols (free of methoxyl group) and 2-methoxy-4-alkyl-phenols. More vanillin and dimethoxy-benzene appeared in the pyrolysis liquid of alkali lignin and lignin purified from black liquor, respectively. While carbonate additives facilitated the production of methxoy-phenols, more alkyl-phenols were formed with the hydroxide additives. Analysis showed that all the alkaline additives promoted the reactions of decarboxylation or decarbonylation and the removal of unsaturated alkyl branch chains. The strong alkalescence of NaOH and KOH facilitated more deoxygenation of methoxyl groups so that there were more phenols free of methoxyl groups. The pyrolysis of PL resulted in the liquid yields of up to 30 wt.% (dry base), and the content of phenols was above 80% in the liquid.

Cuina Peng; Guangyi Zhang; Junrong Yue; Guangwen Xu

2014-01-01T23:59:59.000Z

164

Auto shredder residue recycling: Mechanical separation and pyrolysis  

Science Journals Connector (OSTI)

Directive 2000/53/EC sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a “waste-to-chemicals” perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

Alessandro Santini; Fabrizio Passarini; Ivano Vassura; David Serrano; Javier Dufour; Luciano Morselli

2012-01-01T23:59:59.000Z

165

Solar coal gasification reactor with pyrolysis gas recycle  

DOE Patents [OSTI]

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

166

Formation characteristics of PCDD and PCDF during pyrolysis processes  

Science Journals Connector (OSTI)

In recent years, pyrolysis processes have become technologies developed to industrial scale and discussed as alternatives to the existing waste combustion technology. However, little information is published regarding PCDD/F formation characteristics during pyrolysis processes. Two common shredder fractions – industrial light shredder (ILS) and refrigerators (REF) – both with high chlorine and copper content were pyrolysed for this pyrolysis study using a pilot plant with a capacity of 100 kg/h. At oxygen concentrations below 2% and temperatures between 430°C and 470°C, considerable amounts of PCDD/F were formed during the pyrolysis. More than 90% of total TEQ was found in the oil fraction (gas phase). The PCDD/PCDF ratio and the homologue pattern differed significantly from those formed during waste incineration. Considering mono- to octachlorinated congeners, up to 400 times more PCDF were formed compared to PCDD. For the investigated pyrolysis conditions, the formation of low chlorinated congeners was highly favoured. The distribution of TEQ within the individual congeners were very similar in all investigated runs. More than 80% of total TEQ stem from 2,3,7,8-substituted T4CDF and P5CDF. The isomer pattern, however, did not show significant differences compared to the common waste incineration pattern suggesting that the basic formation routes are similar.

Roland Weber; Takeshi Sakurai

2001-01-01T23:59:59.000Z

167

ENERGY AND ENVIRONMENT DIVISION. INTERACTION OF ORGANIC SOLVENT WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

~. ~. ~. ~. Procedure . . . . . . . . . . . Coal and Solventon Subbiturninous Coal Below Pyrolysis Temperatures, LBL-Treatment of Extract Solution Coal Residue Treatment. Yield

Lindsey, D.

2011-01-01T23:59:59.000Z

168

Thermal Decomposition of Dichlorosilane Investigated by Pulsed Laser Powered Homogeneous Pyrolysis  

E-Print Network [OSTI]

of vacuum flash pyrolysis of SiH 2Cl2. Ban and Gilbert6 observed SiCl2 by mass spectrometry under sili- conThermal Decomposition of Dichlorosilane Investigated by Pulsed Laser Powered Homogeneous Pyrolysis powered homogeneous pyrolysis of dichlorosilane are reported. Pyrolyses at temperatures of 1350 to 1700 K

Swihart, Mark T.

169

1 Solvent-Extractable Polycyclic Aromatic Hydrocarbons in Biochar: 2 Influence of Pyrolysis Temperature and Feedstock  

E-Print Network [OSTI]

combustion (or 30 pyrolysis) of plant biomass are important natural constituents 31 of soils and sediments.1 45 different starting materials. 46 Pyrolysis of biomass is known to produce a wide variety of 47 low and high molecular weight (LMW and HMW, respectively) 48 PAHs depending on the biomass type, pyrolysis

170

Flash Pyrolysis -A Powerful Method for Characterization of Polymers Helge Egsgaard  

E-Print Network [OSTI]

;Analytical flash pyrolysis Direct analysis of polymers including biopolymers & biomass Products detectedFlash Pyrolysis - A Powerful Method for Characterization of Polymers Helge Egsgaard Biosystems Department Risø National Laboratory DK-4000 Roskilde, Denmark The rational behind the pyrolysis technique

171

"Optimization of Zero Length Chromatographic System and Measuring Properties of Model Compounds from Biomass Pyrolysis"  

E-Print Network [OSTI]

Compounds from Biomass Pyrolysis" Ross Kendall Faculty Mentor: Dr. Paul Dauenhauer, Chemical Engineering by using what he made to measure many of the compounds involved in biomass pyrolysis. If we can understand to retrieve diffusion coefficients of many intermediates of the biomass pyrolysis reaction. From this data

Mountziaris, T. J.

172

Catalytic Conversion of Tars, Carbon Black and Methane from Pyrolysis/Gasification of Biomass  

Science Journals Connector (OSTI)

The use of catalysts in biomass gasification has been suggested for a long time.1 Fung and Graham found that potassium carbonate and calcium oxide have catalytic influences on the gasification rate and the produc...

Clas Ekström; Nils Lindman; Rune Pettersson

1985-01-01T23:59:59.000Z

173

BETO Conversion Program  

Broader source: Energy.gov [DOE]

Breakout Session 2A—Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing BETO Conversion Program Bryna Berendzen, Technology Manager, Bioenergy Technologies Office, U.S. Department of Energy

174

Photoelectrochemical solar energy conversion  

Science Journals Connector (OSTI)

In the present paper the progress in the field of solar energy conversion for the production of electricity and storable ... critically analyzed in view of their stability and conversion efficiency. A number of factors

Rüdiger Memming

1988-01-01T23:59:59.000Z

175

Solar Thermoelectric Energy Conversion  

Broader source: Energy.gov (indexed) [DOE]

SOLID-STATE SOLAR-THERMAL ENERGY CONVERSION CENTER NanoEngineering Group Solar Thermoelectric Energy Conversion Gang Chen, 1 Daniel Kraemer, 1 Bed Poudel, 2 Hsien-Ping Feng, 1 J....

176

Interaction of Plastics in Mixed-Plastics Pyrolysis  

Science Journals Connector (OSTI)

The pyrolysis of mixed-plastic waste has been proposed as a means of recycling to produce petrochemical feedstock. ... The main gases produced from the individual plastics were hydrogen, methane, ethane, ethene, propane, propene, butane, and butene and for the PET plastic carbon dioxide and carbon monoxide. ...

Paul T. Williams; Elizabeth A. Williams

1998-12-17T23:59:59.000Z

177

European Market Study for BioOil (Pyrolysis Oil)  

E-Print Network [OSTI]

European Market Study for BioOil (Pyrolysis Oil) Dec 15, 2006 Doug Bradley President Climate Change Solutions National Team Leader- IEA Bioenergy Task 40- Bio-trade 402 Third Avenue ·Ottawa, Ontario ·Canada K. Market Determining Factors 5. EU Country Perspectives 6. Potential European Markets 6.1. Pulp Mill Lime

178

Pyrolysis in Porous Media: Numerical Analysis and Comparison to Experiments.  

E-Print Network [OSTI]

reactions which contribute to the heat flux absorption. The formation of a thin film inside the combustion hydrocarbon fuel pyrolysis, which can be of practical interest for the active cooling of head loaded is an additional way to investigate the related phenomena (heat and mass transfer with chemistry). After a first

Paris-Sud XI, Université de

179

Synthetic and Jet Fuels Pyrolysis for Cooling and Combustion Applications.  

E-Print Network [OSTI]

phenomenon (heat and mass transfers, pyrolysis, combustion) in a cooling channel surrounding a SCRamjet regeneratively cooled SCRamjet is provided to get a large vision of the fuel nature impact on the system of supersonic combustion ramjet (SCRamjet) [1]. For such high velocity, the total temperature of external air

Boyer, Edmond

180

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network [OSTI]

1 Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management : United States (2008)" #12;2 I. Introduction One of the main issues of the development of scramjet, an air to the endothermicity of its thermal decomposition. Because of the large heat load found in a scramjet, engine

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Mineral Nutrient Recovery from Pyrolysis Co-Products  

E-Print Network [OSTI]

Pyrolysis is the thermo-chemical degradation of biomass in an oxygen-free environment to product liquid, gaseous, and solid co-products. The liquid co-product, known as bio-oil, can be used as a transportation fuel. The gaseous co-product, known...

Wise, Jatara Rob

2012-07-16T23:59:59.000Z

182

Plasmonic conversion of solar energy  

E-Print Network [OSTI]

a novel method of solar energy conversion that can lead tofundamentals of plasmonic energy conversion are reviewed in3. Plasmonic energy conversion fundamentals Surface plasmons

Clavero, Cesar

2014-01-01T23:59:59.000Z

183

Laser pyrolysis of explosives combined with mass spectral studies of the ignition zone  

Science Journals Connector (OSTI)

By combining a laser ignition technique with mass spectroscopic analysis we have developed a means of rapid determination of some of the molecules involved in the thermal ignition process of a high explosive. This technique also enables the study of how parameters such as initial gas pressure (0.1–5.0 MPa), type of gas (helium, air or nitrogen), laser wavelength (9–11 ?m), laser pulse width (1 ms?1 s) and laser power (10–180 W) influence the production of major decomposition products (N2O, HCN, NO2, H2CO, NO and CO2) and some of the larger fragments in the reaction zone. It also permits the detection and identification of some of the larger molecule fragments involved in the ignition process. The experimental equipment consists mainly of a 180 W CO2 laser, an explosives test vessel, and a mass spectrometer. This paper describes in detail the techniques and apparatus used and gives an introductory study of the fast laser pyrolysis/laser ignition for 1,3,5-trinitrohexahydro-1,3,5-triazine (RDX). The combined laser ignition/mass spectroscopy method gives advantages over earlier pyrolysis-MS methods in that it permits us to follow the transition from a slow thermal decomposition to a self-sustained deflagration. The method also makes it possible to study these processes at elevated pressures (up to 5.0 MPa). In the RDX pre-ignition zone some decomposition intermediates were identified: triazine (C3N3H3) and possibly (CN)2. In the pre-ignition zone of RDX we have also identified both condensed-phase and gas-phase processes. In order to show the general applicability of the method results are also presented for other high explosives: HNS, PETN, TNT and Tetryl.

Henric Östmark; Helena Bergman; Katrin Ekvall

1992-01-01T23:59:59.000Z

184

Iterated multidimensional wave conversion  

SciTech Connect (OSTI)

Mode conversion can occur repeatedly in a two-dimensional cavity (e.g., the poloidal cross section of an axisymmetric tokamak). We report on two novel concepts that allow for a complete and global visualization of the ray evolution under iterated conversions. First, iterated conversion is discussed in terms of ray-induced maps from the two-dimensional conversion surface to itself (which can be visualized in terms of three-dimensional rooms). Second, the two-dimensional conversion surface is shown to possess a symplectic structure derived from Dirac constraints associated with the two dispersion surfaces of the interacting waves.

Brizard, A. J. [Dept. Physics, Saint Michael's College, Colchester, VT 05439 (United States); Tracy, E. R.; Johnston, D. [Dept. Physics, College of William and Mary, Williamsburg, VA 23187-8795 (United States); Kaufman, A. N. [LBNL and Physics Dept., UC Berkeley, Berkeley, CA 94720 (United States); Richardson, A. S. [T-5, LANL, Los Alamos, NM 87545 (United States); Zobin, N. [Dept. Mathematics, College of William and Mary, Williamsburg, VA 23187-8795 (United States)

2011-12-23T23:59:59.000Z

185

Method of producing pyrolysis gases from carbon-containing materials  

DOE Patents [OSTI]

A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

1989-01-01T23:59:59.000Z

186

Processing and Conversion  

Broader source: Energy.gov [DOE]

The strategic goal of Conversion Research and Development (R&D) is to develop technologies for converting feedstocks into commercially viable liquid transportation fuels, as well as bioproducts...

187

Algae Harvest Energy Conversion  

Science Journals Connector (OSTI)

Resolution of many workshops on algae harvest energy conversion is that low productivity, high capital intensity ... and maintenance, respiration, and photoinhibition are few factors militating against viability ...

Yung-Tse Hung Ph.D.; P.E.; DEE; O. Sarafadeen Amuda Ph.D.…

2010-01-01T23:59:59.000Z

188

QUANTUM CONVERSION IN PHOTOSYNTHESIS  

E-Print Network [OSTI]

QUANTUM CONVERSION IN PHOTOSYNTHESIS Melvin Calvin Januaryas it occurs in modern photosynthesis can only take place inof the problem or photosynthesis, or any specific aspect of

Calvin, Melvin

2008-01-01T23:59:59.000Z

189

Experimental Flash Pyrolysis of High Density1 PolyEthylene under Hybrid Propulsion Conditions2  

E-Print Network [OSTI]

1/25 Experimental Flash Pyrolysis of High Density1 PolyEthylene under Hybrid Propulsion Conditions2 Poly-Ethylene (HDPE) is studied6 up to 20 000 K.s-1 , under pressure up to 3.0 MPa and at temperature Pyrolysis (2013) 1-11" DOI : 10.1016/j.jaap.2013.02.014 #12;2/25 Keywords: Polyethylene; flash pyrolysis

Boyer, Edmond

190

Catalytic pyrolysis of straight-run gasoline on a promoted vanadium catalyst  

SciTech Connect (OSTI)

Over the years the catalytic pyrolysis has been studied of various hydrocarbon materials - from gaseous (ethane, propane and n-butane) to heavy petroleum fractions with an end boiling point higher than 500/sup 0/C. The process indices for all the raw materials studied were significantly better than those from thermal pyrolysis. Improvement of operational properties for the vanadium catalyst for pyrolysis involved the selecting a better acceptor and the use of promotor additives which inhibit coke formation.

Chernykh, S.P.; Adel'son, S.V.; Rudyk, E.M.; Zhagfarov, F.G.; Motorina, I.A.; Nikonov, V.I.; Mukhina, T.N.; Barabanov, N.L.; Pyatiletov, V.I.

1983-04-01T23:59:59.000Z

191

Staged Catalytic Gasification/Steam Reforming of Pyrolysis Oil  

Science Journals Connector (OSTI)

While the slag can be used in the current industry infrastructure as a construction material, up-scaling of biomass utilization will lead to land depletion because the mineral and metal balances are not closed. ... Table 4 shows gasification results at similar temperatures for two different types of pyrolysis oil (pine and beech) and of another liquid biomass stream, a “light” and a “heavy” sugar waste stream. ... The sugar waste streams that were gasified are a side product from lactic acid production. ...

Guus van Rossum; Sascha R. A. Kersten; Wim P. M. van Swaaij

2009-05-21T23:59:59.000Z

192

Fast valve  

DOE Patents [OSTI]

A fast valve is disclosed that can close on the order of 7 milliseconds. It is closed by the force of a compressed air spring with the moving parts of the valve designed to be of very light weight and the valve gate being of wedge shaped with O-ring sealed faces to provide sealing contact without metal to metal contact. The combination of the O-ring seal and an air cushion create a soft final movement of the valve closure to prevent the fast air acting valve from having a harsh closing. 4 figs.

Van Dyke, W.J.

1992-04-07T23:59:59.000Z

193

Fast valve  

DOE Patents [OSTI]

A fast valve is disclosed that can close on the order of 7 milliseconds. It is closed by the force of a compressed air spring with the moving parts of the valve designed to be of very light weight and the valve gate being of wedge shaped with O-ring sealed faces to provide sealing contact without metal to metal contact. The combination of the O-ring seal and an air cushion create a soft final movement of the valve closure to prevent the fast air acting valve from having a harsh closing.

Van Dyke, William J. (Grafton, VA)

1992-01-01T23:59:59.000Z

194

Reactive gases evolved during pyrolysis of Devonian oil shale  

SciTech Connect (OSTI)

Computer modeling of oil shale pyrolysis is an important part of the Lawrence Livermore National Laboratory (LLNL) Oil Shale Program. Models containing detailed chemistry have been derived from an investigation of Colorado oil shale. We are currently attempting to use models to treat more completely reactions of nitrogen and sulfur compounds in the retort to better understand emissions. Batch retorting work on Devonian oil shale is proving particularly useful for this study of nitrogen/sulfur chemistry. Improved analytical methods have been developed to quantitatively determine reactive volatiles at the parts-per-million level. For example, the triple quadrupole mass spectrometer (TQMS) is used in the chemical ionization (CI) mode to provide real-time analytical data on ammonia evolution as the shale is pyrolyzed. A heated transfer line and inlet ensure rapid and complete introduction of ammonia to the instrument by preventing water condensation. Ammonia and water release data suitable for calculating kinetic parameters have been obtained from a New Albany Shale sample. An MS/MS technique with the TQMS in the electron ionization (EI) mode allows hydrogen sulfide, carbonyl sulfide, and certain trace organic sulfur compounds to be monitored during oil shale pyrolysis. Sensitivity and selectivity for these compounds have been increased by applying artificial intelligence techniques to tuning of the spectrometer. Gas evolution profiles (100 to 900/sup 0/C) are reported for hydrogen sulfide, water, ammonia, and trace sulfur species formed during pyrolysis of Devonian oil shale. Implications for retorting chemistry are discussed. 18 refs., 11 figs., 3 tabs.

Coburn, T.T.; Crawford, R.W.; Gregg, H.R.; Oh, M.S.

1986-11-01T23:59:59.000Z

195

Pore Scale Analysis of Oil Shale/Sands Pyrolysis  

SciTech Connect (OSTI)

There are important questions concerning the quality and volume of pore space that is created when oil shale is pyrolyzed for the purpose of producing shale oil. In this report, 1.9 cm diameter cores of Mahogany oil shale were pyrolyzed at different temperatures and heating rates. Detailed 3D imaging of core samples was done using multiscale X-ray computed tomography (CT) before and after pyrolysis to establish the pore structure. The pore structure of the unreacted material was not clear. Selected images of a core pyrolyzed at 400oC were obtained at voxel resolutions from 39 microns (?m) to 60 nanometers (nm). Some of the pore space created during pyrolysis was clearly visible at these resolutions and it was possible to distinguish between the reaction products and the host shale rock. The pore structure deduced from the images was used in Lattice Boltzmann simulations to calculate the permeability in the pore space. The permeabilities of the pyrolyzed samples of the silicate-rich zone were on the order of millidarcies, while the permeabilities of the kerogen-rich zone after pyrolysis were very anisotropic and about four orders of magnitude higher.

Lin, Chen-Luh; Miller, Jan

2011-03-01T23:59:59.000Z

196

Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution  

Broader source: Energy.gov [DOE]

Two-day agenda from the workshop: Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution fuel in New England.

197

Pyrolysis Kinetics and Chemical Structure Considerations of a Green River Oil Shale and Its Derivatives.  

E-Print Network [OSTI]

??This work had the objective of determining both the kinetic parameters for the pyrolysis of oil shale and kerogen as well as using analytical techniques… (more)

Hillier, James L

2011-01-01T23:59:59.000Z

198

The best use of biomass? Greenhouse gas lifecycle analysis of predicted pyrolysis biochar systems.  

E-Print Network [OSTI]

??Life cycle analysis is carried out for 11 predicted configurations of pyrolysis biochar systems to determine greenhouse gas balance, using an original spreadsheet model. System… (more)

Hammond, James A R

2009-01-01T23:59:59.000Z

199

Biomass pyrolysis processes: performance parameters and their influence on biochar system benefits.  

E-Print Network [OSTI]

??This study focuses on performance of biomass pyrolysis processes for use in biochar systems. Objectives are to understand the range of control of such processes… (more)

Brownsort, Peter A

2009-01-01T23:59:59.000Z

200

Product Analysis and Thermodynamic Simulations from the Pyrolysis of Several Biomass Feedstocks  

Science Journals Connector (OSTI)

Product Analysis and Thermodynamic Simulations from the Pyrolysis of Several Biomass Feedstocks ... Forestry residue is one of the most viable biomass feedstocks for liq. ...

Jieling Zhang; Hossein Toghiani; Dinesh Mohan; Charles U. Pittman, Jr.; Rebecca K. Toghiani

2007-05-25T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents [OSTI]

A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

Steinberg, M.; Grohse, E.W.

1995-06-27T23:59:59.000Z

202

Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol  

DOE Patents [OSTI]

A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

1995-01-01T23:59:59.000Z

203

Photovoltaic Energy Conversion  

E-Print Network [OSTI]

Photovoltaic Energy Conversion Frank Zimmermann #12;Solar Electricity Generation Consumes no fuel Make solar cells more efficient Theoretical energy conversion efficiency limit of single junction-bandgap photons are not absorbed: Carrier relaxation to band edges: Photon energy exceeding bandgap is lost

Glashausser, Charles

204

NREL: Biomass Research - Thermochemical Conversion Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fuel synthesis reactor. NREL investigates thermochemical processes for converting biomass and its residues to fuels and intermediates using gasification and pyrolysis...

205

Analysis and comparison of biomass pyrolysis/gasification condensates: an interim report  

SciTech Connect (OSTI)

This report provides results of chemical and physical analysis of condensates from eleven biomass gasification and pyrolysis systems. The analyses were performed in order to provide more detailed data concerning these condensates for the different process research groups and to allow a determination of the differences in properties of the condensates as a function of reactor environment. The samples were representative of the various reactor configurations being researched within the Department of Energy, Biomass Thermochemical Conversion program. The condensates included tar phases, aqueous phases and, in some cases, both phases depending on the output of the particular reactor system. The analyses included gross compositional analysis (elemental analysis, ash, moisture), physical characterization (pour point, viscosity, density, heat of combustion, distillation), specific chemical analysis (gas chromatography/mass spectrometry, infrared spectrophotometry, proton and carbon-13 nuclear magnetic resonance spectrometry) and biological activity (Ames assay). The analytical data demonstrate the wide range of chemical composition of the organics recovered in the condensates and suggests a direct relationship between operating temperature and chemical composition of the condensates. A continuous pathway of thermal degradation of the tar components as a function of temperature is proposed. Variations in the chemical composition of the organic components in the tars are reflected in the physical properties of tars and phase stability in relation to water in the condensate. The biological activity appears to be limited to the tars produced at high temperatures as a result of formation of polycyclic aromatic hydrocarbons in high concentrations. 55 refs., 13 figs., 6 tabs.

Elliott, D.C.

1985-09-01T23:59:59.000Z

206

Infra red spectroscopy, flash pyrolysis, thermally assisted hydrolysis and methylation (THM) in the presence of tetramethylammonium hydroxide  

E-Print Network [OSTI]

Infra red spectroscopy, flash pyrolysis, thermally assisted hydrolysis and methylation (THM to sporopollenin or algaenan. This is in agreement with flash pyrolysis­gas chromatography­mass spectrometry (py

207

Known Challenges Associated with the Production, Transportation, Storage and Usage of Pyrolysis Oil in Residential and Industrial Settings  

Broader source: Energy.gov [DOE]

Dr. Jani Lehto presentation at the May 9 Pyrolysis Oil Workshop on Known Challenges Associated with the Production, Transportation, Storage and Usage of Pyrolysis Oil in Residential and Industrial Settings.

208

Liquid-phase Processing of Fast Pyrolysis Bio-oil using Pt/HZSM-5 Catalyst  

E-Print Network [OSTI]

such as switchgrass, sorghum and miscanthus, agriculture crops such as corn and sugarcane, municipal solid waste, agriculture wastes and forest residues. Energy crops are more preferred since they produce high yield, low fertilizer application requirements and low...), plastic wastes (Bhattacharya et al., 2009; Karaduman et al., 2001; Rutkowski and 7 Kubacki, 2006; Scott et al., 1990), waste biomass like oil cakes (?zbay et al., 2001), energy crops (He et al., 2009), and forest residues (Ingram et al., 2007...

Santos, Bjorn Sanchez

2013-05-01T23:59:59.000Z

209

Production of Gasoline and Diesel from Biomass via Fast Pyrolysis, Hydrotreating and Hydrocracking: A Design Case  

Broader source: Energy.gov [DOE]

The goal of the U.S. Department of Energy’s Bioenergy Technologies Office (BETO) is to enable the development of biomass technologies.

210

Inorganic Compounds in Biomass Feedstocks. 1. Effect on the Quality of Fast Pyrolysis Oils  

Science Journals Connector (OSTI)

Inorganic Compounds in Biomass Feedstocks. 1. ... Inorganic compoundsespecially potassium, calcium, sodium, silicon, phosphorus, and chlorineare the main constituents of the ash in biomass feedstocks. ...

F. A. Agblevor; S. Besler

1996-03-20T23:59:59.000Z

211

Production of Bio-oil from Alfalfa Stems by Fluidized-Bed Fast Pyrolysis  

Science Journals Connector (OSTI)

Findings included a lower-than-average yield of bio-oil and a higher-than-average yield of charcoal from alfalfa stems, compared to previous results for other biomass feedstocks. ...

Akwasi A. Boateng; Charles A. Mullen; Neil Goldberg; Kevin B. Hicks; Hans-Joachim G. Jung; JoAnn F. S. Lamb

2008-05-21T23:59:59.000Z

212

Development of a Computational Fluid Dynamics Model for Combustion of Fast Pyrolysis Liquid (Bio-oil).  

E-Print Network [OSTI]

??A study was carried out into the computational fluid dynamic simulation of bio-oil combustion. Measurements were taken in an empirical burner to obtain information regarding… (more)

McGrath, Arran Thomas

2011-01-01T23:59:59.000Z

213

Conversion of waste polyvinyl chloride (PVC) to useful chemicals  

SciTech Connect (OSTI)

Developments of recycling technologies are expected one of the most important keys for saving energy and resources, and minimization impact for environment. For instance, combustion of waste for power generation and conversion of plastics into liquid fuels have been studying for thermal energy recycling. However, PVC has been excepted from the most of these experiments. Because, heat of combustion of PVC is almost a half of other plastics, hydrogen chloride, which is produced at low temperature, corrodes the combustion chamber, and PVC causes coking reaction during pyrolysis of plastics. Numerous investigations have been conducted on degradation of PVC. However, most of these experiments were done to improve heat resistance of PVC or to study reaction mechanism of PVC degradation. Pyrolysis of PVC into liquid products have been studying since 1960`s from a view of environmental protection. Recently, Y. Maezawa et al. reported PVC was converted into oil at 600 T with sodium hydroxide. However, more than 50 % of hydrocarbon fraction of PVC was converted to residue and gas in their experiment. We are going to develop a new technology to convert of PVC into useful chemicals or liquid fuels at high efficiency by using hydrogen donor solvent.

Kamo, T.; Yamamoto, Y.; Miki, K.; Sato, Y. [National Institute for Resources and Environment, Tsukuba-shi, Ibaraki (Japan)

1995-12-31T23:59:59.000Z

214

Carbonization of Coal Evaluation of Effects of Rate of Heating and of Maximum Temperature on Pyrolysis of a Coking Coal  

Science Journals Connector (OSTI)

Carbonization of Coal Evaluation of Effects of Rate of Heating and of Maximum Temperature on Pyrolysis of a Coking Coal ...

William B. Warren

1935-01-01T23:59:59.000Z

215

Peculiarities of Rapid Pyrolysis of Biomass Covering Medium- and High-Temperature Ranges  

Science Journals Connector (OSTI)

Peculiarities of Rapid Pyrolysis of Biomass Covering Medium- and High-Temperature Ranges ... It is considered that rapid pyrolysis is the first step in both gasification and combustion, which occurs at the same temperature of gasification or combustion in an industrial gasifier or boiler. ...

Yan Zhang; Shiro Kajitani; Masami Ashizawa; Kouichi Miura

2006-10-17T23:59:59.000Z

216

Cell Wall Chemotyping for Functional Applications of PyrolysisGas Chromatography / Mass  

E-Print Network [OSTI]

Cell Wall Chemotyping for Functional Genomics Applications of Pyrolysis­Gas Chromatography / Mass, Umeå 2012 #12;Cell Wall Chemotyping for Functional Genomics Applications of Pyrolysis.4.1 The Basic Tool-set 27 1.5 Wood Formation and Functional Genomics 31 2 Objectives 33 3 Methodological

217

American Institute of Aeronautics and Astronautics Modeling the motion of pyrolysis gas through charring  

E-Print Network [OSTI]

1 American Institute of Aeronautics and Astronautics Modeling the motion of pyrolysis gas through problem with gas motion through the porous media employing finite element based Galerkin and Discontinuous t = time Subscripts c = char g = pyrolysis gas r = resin I. Introduction pace vehicles enter earth's (or

Roy, Subrata

218

Metal Oxide Laser Ioniza2on Mass Spectrometry for the Direct Profiling of Pyrolysis Oil Cons2tuents  

E-Print Network [OSTI]

from the anoxic pyrolysis of biomass (py-oils) represent a promising, renewable of Pyrolysis Oil Cons2tuents Casey R. McAlpin and Kent J. Voorhees Colorado School: ·MOLI MS produces profiles of pyrolysis oil consGtuents without separa

219

Forensic Discrimination of Automotive Paint Samples Using Pyrolysis-Gas Chromatography–Mass Spectrometry with Multivariate Statistics  

Science Journals Connector (OSTI)

......Analytical pyrolysis-gas chromatography (Py-GC...Analytical pyrolysis-gas chromatography (Py-GC...development, pyrolysis-gas chromatography (Py...considerations, such as lower cost, can lead one to change...does not vary between production sites, subtle differences......

Brian K. Kochanowski; Stephen L. Morgan

2000-03-01T23:59:59.000Z

220

BIOMASS ENERGY CONVERSION IN HAWAII  

E-Print Network [OSTI]

Jones and w.s. Fong, Biomass Conversion of Biomass to Fuels11902 UC-61a BIOMASS ENERGY CONVERSION IN HAWAII RonaldLBL-11902 Biomass Energy Conversion in Hawaii Ronald 1.

Ritschard, Ronald L.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Enhancing The Mode Conversion Efficiency In JET Plasmas With Multiple Mode Conversion Layers  

SciTech Connect (OSTI)

The constructive interference effect described by Fuchs et al. [1] shows that the mode conversion and thereby the overall heating efficiency can be enhanced significantly when an integer number of fast wave wavelengths can be folded in between the high field side fast wave cutoff and the ion-ion hybrid layer(s) at which the ion Bernstein or ion cyclotron waves are excited. This effect was already experimentally identified in ({sup 3}He)-D plasmas [2] and was recently tested in ({sup 3}He)-H JET plasmas. The latter is an 'inverted' scenario, which differs significantly from the ({sup 3}He)-D scenarios since the mode-conversion layer is positioned between the low field side edge of the plasma and the ion-cyclotron layer of the minority {sup 3}He ions (whereas the order in which a wave entering the plasma from the low field side encounters these layers is inverted in a 'regular' scenario), and because much lower {sup 3}He concentrations are needed to achieve the mode-conversion heating regime. The presence of small amounts of {sup 4}He and D in the discharges gave rise to an additional mode conversion layer on top of the expected one associated with {sup 3}He-H, which made the interpretation of the results more complex but also more interesting: Three different regimes could be distinguished as a function of X[{sup 3}He], and the differing dynamics at the various concentrations could be traced back to the presence of these two mode conversion layers and their associated fast wave cutoffs. Whereas (1-D and 2-D) numerical modeling yields quantitative information on the RF absorptivity, recent analytical work by Kazakov [3] permits to grasp the dominant underlying wave interaction physics.

Van Eester, D.; Lerche, E.; Ongena, J. [LPP-ERM/KMS, Association Euratom-'Belgian State', TEC Partner, Brussels (Belgium); Johnson, T.; Hellsten, T. [Fusion Plasma Physics, Association Euratom-VR, KTH, Stockholm (Sweden); Mayoral, M.-L.; Beaumont, P.; Blackman, T.; Brennan, D.; Brett, A.; Coffey, I.; Coyne, A.; Felton, R.; Giroud, C.; Jacquet, P.; Kiptily, V.; Knipe, S.; Monakhov, I.; Noble, C.; Pangioni, L. [Euratom-CCFE Fusion Association, Culham Science Centre (United Kingdom)

2011-12-23T23:59:59.000Z

222

Wave Energy Conversion Technology  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wave Energy Conversion Technology Wave Energy Conversion Technology Speaker(s): Mirko Previsic Date: August 2, 2001 - 12:00pm Location: Bldg. 90 Seminar Host/Point of Contact: Julie Osborn Scientists have been working on wave power conversion for the past twenty years, but recent advances in offshore and IT technologies have made it economically competitive. Sea Power & Associates is a Berkeley-based renewable energy technology company. We have developed patented technology to generate electricity from ocean wave energy using a system of concrete buoys and highly efficient hydraulic pumps. Our mission is to provide competitively priced, non-polluting, renewable energy for coastal regions worldwide. Mirko Previsic, founder and CEO, of Sea Power & Associates will discuss ocean wave power, existing technologies for its conversion into

223

Avatar augmented online conversation  

E-Print Network [OSTI]

One of the most important roles played by technology is connecting people and mediating their communication with one another. Building technology that mediates conversation presents a number of challenging research and ...

Vilhjálmsson, Hannes Högni

2003-01-01T23:59:59.000Z

224

Modern Biomass Conversion Technologies  

Science Journals Connector (OSTI)

This article gives an overview of the state-of-the-art of key biomass conversion technologies currently deployed and technologies that may...2...capture and sequestration technology (CCS). In doing so, special at...

Andre Faaij

2006-03-01T23:59:59.000Z

225

DANISHBIOETHANOLCONCEPT Biomass conversion for  

E-Print Network [OSTI]

DANISHBIOETHANOLCONCEPT Biomass conversion for transportation fuel Concept developed at RISÃ? and DTU Anne Belinda Thomsen (RISÃ?) Birgitte K. Ahring (DTU) #12;DANISHBIOETHANOLCONCEPT Biomass: Biogas #12;DANISHBIOETHANOLCONCEPT Pre-treatment Step Biomass is macerated The biomass is cut in small

226

Semiconductor Nanowires and Nanotubes for Energy Conversion  

E-Print Network [OSTI]

of applications, notably energy conversion. As researchnanowires for energy conversion. Chemical Reviews, 2010.Implications for solar energy conversion. Physical Review

Fardy, Melissa Anne

2010-01-01T23:59:59.000Z

227

Structured luminescence conversion layer  

DOE Patents [OSTI]

An apparatus device such as a light source is disclosed which has an OLED device and a structured luminescence conversion layer deposited on the substrate or transparent electrode of said OLED device and on the exterior of said OLED device. The structured luminescence conversion layer contains regions such as color-changing and non-color-changing regions with particular shapes arranged in a particular pattern.

Berben, Dirk; Antoniadis, Homer; Jermann, Frank; Krummacher, Benjamin Claus; Von Malm, Norwin; Zachau, Martin

2012-12-11T23:59:59.000Z

228

Conversion Plan | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

document the conversion plan that clearly defines the system or project's conversion procedures; outlines the installation of new and converted filesdatabases; coordinates the...

229

Plasmonic conversion of solar energy  

E-Print Network [OSTI]

of solar energy into electricity in photovoltaic cells orsolar energy conversion aimed at photovoltaic applicationsenergy conversion, opening a new venue for photovoltaic and

Clavero, Cesar

2014-01-01T23:59:59.000Z

230

Plasmonic conversion of solar energy  

E-Print Network [OSTI]

of carriers allows maintaining the energy conversionenergy conversion 8 Timescale of charge separation, carrierin this energy conversion method, i.e. carrier regeneration

Clavero, Cesar

2014-01-01T23:59:59.000Z

231

Hydrocracking of a Plastics Pyrolysis Gas Oil to Naphtha  

Science Journals Connector (OSTI)

1 Of the approximately 80 billion pounds of plastics currently produced in the United States, most eventually ends up in landfills, with only 2?3% being recycled. ... Disposal of these waste plastics by direct incineration would lead to increased greenhouse gas emissions, primarily carbon dioxide, and particulate pollutants, while direct mechanical recycling of plastics is limited by the fact that reconstituted objects generally possess a downgraded appearance in comparison with virgin plastics. ... 14 On the other hand, there has been little study of the hydrocracking of waste plastic-derived pyrolysis liquids. ...

H. S. Joo; James A. Guin

1997-05-20T23:59:59.000Z

232

Test plan for ISV laboratory-pyrolysis testing  

SciTech Connect (OSTI)

The objective of the laboratory-pyrolysis studies is to obtain information on the high temperature (< 1200{degree}C) degradation and alteration of organic chemicals and materials similar to those found in the Radioactive Waste Management Complex, Pit 9. This test plan describes experimental procedures, sampling and analysis strategy, sampling procedures, sample control, and document management. It addresses safety issues in the experimental apparatus and procedures, personal training, and hazardous waste disposal. Finally, it describes the data quality objectives using the EPA tiered approach to treatability studies to define where research/scoping tests fit into these studies and the EPA analytical levels required for the tests.

McAtee, R.E.

1991-09-01T23:59:59.000Z

233

Experimental and theoretical investigation of heat and mass transfer processes during wood pyrolysis  

SciTech Connect (OSTI)

Thermal decomposition of 25.4 mm diameter dry wood spheres is studied both experimentally and theoretically. Wood spheres were pyrolyzed in a vertical tube furnace at temperatures ranging from 638 K to 879 K. Mass loss and temperatures of the sample were measured during pyrolysis. Center temperature measurements showed two distinct thermal events consisting of sequential endothermic and exothermic reactions. A numerical investigation of these endo/exothermic reactions using various pyrolysis kinetics models was conducted to determine the pyrolysis mechanism and the heats of the pyrolysis reactions. A comparison of the experimental and numerical results showed that (i) Contrary to the suggestions in the literature, the contributions of the secondary tar decomposition and lignin decomposition to the center temperature exothermic peak are small. (ii) Exothermic decomposition of the intermediate solid is responsible for the center temperature peak. (iii) The center temperature plateau is caused by the endothermic decomposition of cellulose. (iv) Internal pressure generation was found to be quite important because it controls the pyrolyzate mass transfer and thus affects both the heat transfer and the residence time of the pyrolysis gases for secondary decomposition. Based on the experimental and numerical results, a new wood pyrolysis model is proposed. The model consists of three endothermic parallel reactions producing tar, gas and intermediate solid and subsequent exothermic decomposition of the intermediate solid to char and exothermic decomposition of tar to char and gas. The proposed pyrolysis model shows good agreement with the experiments. Pressure calculations based on the new pyrolysis model revealed that high pressure is generated inside the biomass particle during pyrolysis and sample splitting was observed during the experiments. The splitting is due to both weakening of the structure and internal pressure generation during pyrolysis. At low heating rates, structural weakness is the primary factor, whereas at high heating rates, internal pressure is the determining factor. It is expected that moisture, while not considered in this work will have a similar effect, but at lower temperatures. (author)

Park, Won Chan; Atreya, Arvind [Department of Mechanical Engineering, University of Michigan, 2158 GGBL 2350 Hayward St., Ann Arbor, MI 48109 (United States); Baum, Howard R. [Department of Fire Protection Engineering, University of Maryland, 3106-D J.M. Patterson Building, College Park, MD 20742 (United States)

2010-03-15T23:59:59.000Z

234

Surface Tension Mediated Conversion of Light to Work David Okawa,,  

E-Print Network [OSTI]

to a high energy intermediate (e.g., electrical potential, thermal loading, or chemical fuel), which- taics for conversion to electricity, solar thermal for water heating, fast growing plants to produce rely on weak momentum transfer from photons. Harnessing the energy of photons is a far more powerful

Zettl, Alex

235

Isolation of levoglucosan from pyrolysis oil derived from cellulose  

DOE Patents [OSTI]

High purity levoglucosan is obtained from pyrolysis oil derived from cellulose by: mixing pyrolysis oil with water and a basic metal hydroxide, oxide, or salt in amount sufficient to elevate pH values to a range of from about 12 to about 12.5, and adding an amount of the hydroxide, oxide, or salt in excess of the amount needed to obtain the pH range until colored materials of impurities from the oil are removed and a slurry is formed; drying the slurry azeotropically with methyl isobutyl ketone solvent to form a residue, and further drying the residue by evaporation; reducing the residue into a powder; continuously extracting the powder residue with ethyl acetate to provide a levoglucosan-rich extract; and concentrating the extract by removing ethyl acetate to provide crystalline levoglucosan. Preferably, Ca(OH)[sub 2] is added to adjust the pH to the elevated values, and then Ca(OH)[sub 2] is added in an excess amount needed. 3 figures.

Moens, L.

1994-12-06T23:59:59.000Z

236

Flash Pyrolysis of Biomass with Reactive and Non-Reactive Gases: Summary Report for Period July 1983 through September 1984  

SciTech Connect (OSTI)

The purpose of this program is to study the conversion of biomass to liquid and gaseous hydrocarbon fuels and chemical feedstocks by a flash or rapid pyrolysis technique. During this period of study pine wood was flash pyrolyzed in atmospheres of methane and helium at a pressure of 50 psi and at temperatures up to 1050 C. The 1-inch I.D. entrained downflow tubular reactor was used in these experiments. Product yields of methane, ethane, ethylene, BTX, carbon monoxide and carbon dioxide were determined as a function of temperature and gas to wood ratio. Of particular interest were the ethylene and BTX yields. These represented as much as 29.6% and 24.6% of the carbon contained in the feed wood respectively when flash pyrolyzing in methane (flash methanolysls) and 14.7% and 9.7% when pyrolyzing in helium. In the case of flash methanolysis of wood the yields of ethylene and benzene increased with increasing methane to wood feed ratios. In the case of flash pyrolysis in helium the yields of ethylene and BTX decreased with increasing helium gas to wood feed ratios. These results indicate a mechanism by which a free radical reactive species originating from the wood interacts with the methane pyrolyzing gas to produce an enhanced yield of ethylene and benzene. The flash methanolysis of lignin extract from wood produced lower yields of ethylene, indicating the yields mainly originate from the cellulosic fractions of the wood. Some work was also performed on substituting wood ash for sillca flour (Cab-O-Sil) to allow free flow of wood particles through the entrained flow reactor. Preliminary process design and analysis indicates an economically competitive process for the flash methanolysis of wood for the production of methanol, benzene and ethylene. Future plans include completing the studies on obtaining the process chemistry of the flash methanolysis of woods, to obtain a better understanding of the enhanced ethylene and benzene yield and to investigate other biomass forms.

Steinberg M.; Fallon, P.T.; Sundaram, M.S.

1984-10-01T23:59:59.000Z

237

Digital optical conversion module  

DOE Patents [OSTI]

A digital optical conversion module used to convert an analog signal to a computer compatible digital signal including a voltage-to-frequency converter, frequency offset response circuitry, and an electrical-to-optical converter. Also used in conjunction with the digital optical conversion module is an optical link and an interface at the computer for converting the optical signal back to an electrical signal. Suitable for use in hostile environments having high levels of electromagnetic interference, the conversion module retains high resolution of the analog signal while eliminating the potential for errors due to noise and interference. The module can be used to link analog output scientific equipment such as an electrometer used with a mass spectrometer to a computer.

Kotter, Dale K. (North Shelley, ID); Rankin, Richard A. (Ammon, ID)

1991-02-26T23:59:59.000Z

238

Digital optical conversion module  

DOE Patents [OSTI]

A digital optical conversion module used to convert an analog signal to a computer compatible digital signal including a voltage-to-frequency converter, frequency offset response circuitry, and an electrical-to-optical converter. Also used in conjunction with the digital optical conversion module is an optical link and an interface at the computer for converting the optical signal back to an electrical signal. Suitable for use in hostile environments having high levels of electromagnetic interference, the conversion module retains high resolution of the analog signal while eliminating the potential for errors due to noise and interference. The module can be used to link analog output scientific equipment such as an electrometer used with a mass spectrometer to a computer. 2 figs.

Kotter, D.K.; Rankin, R.A.

1988-07-19T23:59:59.000Z

239

Co-pyrolysis of low rank coals and biomass: Product distributions  

SciTech Connect (OSTI)

Pyrolysis and gasification of combined low rank coal and biomass feeds are the subject of much study in an effort to mitigate the production of green house gases from integrated gasification combined cycle (IGCC) systems. While co-feeding has the potential to reduce the net carbon footprint of commercial gasification operations, the effects of co-feeding on kinetics and product distributions requires study to ensure the success of this strategy. Southern yellow pine was pyrolyzed in a semi-batch type drop tube reactor with either Powder River Basin sub-bituminous coal or Mississippi lignite at several temperatures and feed ratios. Product gas composition of expected primary constituents (CO, CO{sub 2}, CH{sub 4}, H{sub 2}, H{sub 2}O, and C{sub 2}H{sub 4}) was determined by in-situ mass spectrometry while minor gaseous constituents were determined using a GC-MS. Product distributions are fit to linear functions of temperature, and quadratic functions of biomass fraction, for use in computational co-pyrolysis simulations. The results are shown to yield significant nonlinearities, particularly at higher temperatures and for lower ranked coals. The co-pyrolysis product distributions evolve more tar, and less char, CH{sub 4}, and C{sub 2}H{sub 4}, than an additive pyrolysis process would suggest. For lignite co-pyrolysis, CO and H{sub 2} production are also reduced. The data suggests that evolution of hydrogen from rapid pyrolysis of biomass prevents the crosslinking of fragmented aromatic structures during coal pyrolysis to produce tar, rather than secondary char and light gases. Finally, it is shown that, for the two coal types tested, co-pyrolysis synergies are more significant as coal rank decreases, likely because the initial structure in these coals contains larger pores and smaller clusters of aromatic structures which are more readily retained as tar in rapid co-pyrolysis.

Soncini, Ryan M.; Means, Nicholas C.; Weiland, Nathan T.

2013-10-01T23:59:59.000Z

240

Oil production by entrained pyrolysis of biomass and processing of oil and char  

DOE Patents [OSTI]

Entrained pyrolysis of lignocellulosic material proceeds from a controlled pyrolysis-initiating temperature to completion of an oxygen free environment at atmospheric pressure and controlled residence time to provide a high yield recovery of pyrolysis oil together with char and non-condensable, combustible gases. The residence time is a function of gas flow rate and the initiating temperature is likewise a function of the gas flow rate, varying therewith. A controlled initiating temperature range of about 400.degree. C. to 550.degree. C. with corresponding gas flow rates to maximize oil yield is disclosed.

Knight, James A. (Atlanta, GA); Gorton, Charles W. (Atlanta, GA)

1990-01-02T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Influences of alcoholic solvents on spray pyrolysis deposition of TiO{sub 2} blocking layer films for solid-state dye-sensitized solar cells  

SciTech Connect (OSTI)

Influences of alcoholic solvents for titanium diisopropoxide bis(acetylacetonate) (TPA) precursor solutions on the spray pyrolysis deposited TiO{sub 2} films and the photovoltaic performance of the solid-state dye-sensitized solar cells (SDSCs) using these TiO{sub 2} films as the blocking layers were investigated. Smooth TiO{sub 2} films were obtained by spray pyrolysis deposition of a TPA solution in isopropanol (IPA) at a relatively low temperature of 260 Degree-Sign C. On the other hand, when ethanol was used as solvent, the TiO{sub 2} films fabricated at the same temperature showed much rougher surfaces with many pinholes. Our results showed that ethanol reacts with TPA to form titanium diethoxide bis(acetylacetonate) (TEA), which requires a higher thermal decomposition temperature than that of TPA. SDSCs with TiO{sub 2} blocking layer films fabricated using a TPA solution in IPA showed higher power conversion efficiencies with smaller variations. - Graphical abstract: Alcoholic solvents used for the TiO{sub 2} precursor play a critical role in determining the surface morphology of blocking layers and thus the photovoltaic performance of the SDSCs. Highlights: Black-Right-Pointing-Pointer Solvent influences morphology of spray pyrolysis deposited TiO{sub 2} blocking layer. Black-Right-Pointing-Pointer Ethanol reacts with TPA, resulting poor quality of blocking layer. Black-Right-Pointing-Pointer Isopropanol is better than ethanol for obtaining smooth blocking layer. Black-Right-Pointing-Pointer SDSC with blocking layer made with isopropanol showed better performance.

Jiang, Changyun, E-mail: jiangc@imre.a-star.edu.sg [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)] [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore); Koh, Wei Lin; Leung, Man Yin [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)] [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore); Hong, Wei [Department of Chemical Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave West ON, Waterloo, Canada N2L 3G1 (Canada)] [Department of Chemical Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave West ON, Waterloo, Canada N2L 3G1 (Canada); Li, Yuning, E-mail: yuning.li@uwaterloo.ca [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore) [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore); Department of Chemical Engineering and Waterloo Institute for Nanotechnology (WIN), University of Waterloo, 200 University Ave West ON, Waterloo, Canada N2L 3G1 (Canada); Zhang, Jie [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)] [Institute of Materials Research and Engineering, A-STAR, 3 Research Link, 117602 Singapore (Singapore)

2013-02-15T23:59:59.000Z

242

The flash pyrolysis and methanolysis of biomass (wood) for production of ethylene, benzene and methanol  

SciTech Connect (OSTI)

The process chemistry of the flash pyrolysis of biomass (wood) with the reactive gases, H{sub 2} and CH{sub 4} and with the non-reactive gases He and N{sub 2} is being determined in a 1 in. downflow tubular reactor at pressures from 20 to 1000 psi and temperatures from 600 to 1000{degrees}C. With hydrogen, flash hydropyrolysis leads to high yields of methane and CO which can be used for SNG and methanol fuel production. With methane, flash methanolysis leads to high yields of ethylene, benzene and CO which can be used for the production of valuable chemical feedstocks and methanol transportation fuel. At reactor conditions of 50 psi and 1000{degrees}C and approximately 1 sec residence time, the yields based on pine wood carbon conversion are up to 25% for ethylene, 25% for benzene, and 45% for CO, indicating that over 90% of the carbon in pine is converted to valuable products. Pine wood produces higher yields of hydrocarbon products than Douglas fir wood; the yield of ethylene is 2.3 times higher with methane than with helium or nitrogen, and for pine, the ratio is 7.5 times higher. The mechanism appears to be a free radical reaction between CH{sub 4} and the pyrolyzed wood. There appears to be no net production or consumption of methane. A preliminary process design and analysis indicates a potentially economical competitive system for the production of ethylene, benzene and methanol based on the methanolysis of wood. 10 refs., 18 figs., 1 tab.

Steinberg, M.; Fallon, P.T.; Sundaram, M.S.

1990-02-01T23:59:59.000Z

243

Energy Conversion to Electricity  

Science Journals Connector (OSTI)

30 May 1974 research-article Energy Conversion to Electricity D. Clark...continuing growth in the demand for energy, and of electricity as the route...the electricity share of the total energy market and of the substitution of electricity...

1974-01-01T23:59:59.000Z

244

Solar Energy Conversion  

Science Journals Connector (OSTI)

If solar energy is to become a practical alternative to fossil fuels we must have efficient ways to convert photons into electricity fuel and heat. The need for better conversion technologies is a driving force behind many recent developments in biology materials and especially nanoscience.

George W. Crabtree; Nathan S. Lewis

2008-01-01T23:59:59.000Z

245

Campus Conversations: CLIMATE CHANGE  

E-Print Network [OSTI]

review and input from scholars with expertise in climate change and communication. #12; Welcome Thank youCampus Conversations: CLIMATE CHANGE AND THE CAMPUS Southwestern Pennsylvania Program booklet is an adaptation and updating of Global Warming and Climate Change, a brochure developed in 1994

Attari, Shahzeen Z.

246

Solar energy conversion.  

SciTech Connect (OSTI)

If solar energy is to become a practical alternative to fossil fuels, we must have efficient ways to convert photons into electricity, fuel, and heat. The need for better conversion technologies is a driving force behind many recent developments in biology, materials, and especially nanoscience. The Sun has the enormous untapped potential to supply our growing energy needs. The barrier to greater use of the solar resource is its high cost relative to the cost of fossil fuels, although the disparity will decrease with the rising prices of fossil fuels and the rising costs of mitigating their impact on the environment and climate. The cost of solar energy is directly related to the low conversion efficiency, the modest energy density of solar radiation, and the costly materials currently required. The development of materials and methods to improve solar energy conversion is primarily a scientific challenge: Breakthroughs in fundamental understanding ought to enable marked progress. There is plenty of room for improvement, since photovoltaic conversion efficiencies for inexpensive organic and dye-sensitized solar cells are currently about 10% or less, the conversion efficiency of photosynthesis is less than 1%, and the best solar thermal efficiency is 30%. The theoretical limits suggest that we can do much better. Solar conversion is a young science. Its major growth began in the 1970s, spurred by the oil crisis that highlighted the pervasive importance of energy to our personal, social, economic, and political lives. In contrast, fossil-fuel science has developed over more than 250 years, stimulated by the Industrial Revolution and the promise of abundant fossil fuels. The science of thermodynamics, for example, is intimately intertwined with the development of the steam engine. The Carnot cycle, the mechanical equivalent of heat, and entropy all played starring roles in the development of thermodynamics and the technology of heat engines. Solar-energy science faces an equally rich future, with nanoscience enabling the discovery of the guiding principles of photonic energy conversion and their use in the development of cost-competitive new technologies.

Crabtree, G. W.; Lewis, N. S. (Materials Science Division); (California Inst. of Tech.)

2008-03-01T23:59:59.000Z

247

Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town |  

Broader source: Energy.gov (indexed) [DOE]

Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town December 16, 2011 - 12:10pm Addthis Jonathan Peters, a researcher at RTI International (an ARPA-E awardee), characterizes the water content of a bio-oil sample. | Courtesy of RTI International. Jonathan Peters, a researcher at RTI International (an ARPA-E awardee), characterizes the water content of a bio-oil sample. | Courtesy of RTI International. April Saylor April Saylor Former Digital Outreach Strategist, Office of Public Affairs How does it work? This ARPA-E awardee removes the oxygen and other contaminants in the biomass to be turned into fuel with a novel "catalytic biomass pyrolysis" approach. This substance is more carbon efficient, requires less hydrogen to

248

Feasibility study for thermal treatment of solid tire wastes in Bangladesh by using pyrolysis technology  

SciTech Connect (OSTI)

In this study on the basis of lab data and available resources in Bangladesh, feasibility study has been carried out for pyrolysis process converting solid tire wastes into pyrolysis oils, solid char and gases. The process considered for detailed analysis was fixed-bed fire-tube heating pyrolysis reactor system. The comparative techno-economic assessment was carried out in US$ for three different sizes plants: medium commercial scale (144 tons/day), small commercial scale (36 tons/day), pilot scale (3.6 tons/day). The assessment showed that medium commercial scale plant was economically feasible, with the lowest unit production cost than small commercial and pilot scale plants for the production of crude pyrolysis oil that could be used as boiler fuel oil and for the production of upgraded liquid-products.

Islam, M.R., E-mail: mrislam1985@yahoo.com [Department of Mechanical Engineering, Rajshahi University of Engineering and Technology, Rajshahi 6204 (Bangladesh); Joardder, M.U.H.; Hasan, S.M. [Department of Mechanical Engineering, Rajshahi University of Engineering and Technology, Rajshahi 6204 (Bangladesh); Takai, K.; Haniu, H. [Department of Mechanical Engineering, National University Corporation Kitami Institute of Technology, 165 Koen-cho, Kitami City, Hokkaido 090-8507 (Japan)

2011-09-15T23:59:59.000Z

249

Pyrolysis, combustion and steam gasification of various types of scrap tires for energy recovery  

Science Journals Connector (OSTI)

The energy recovery from carbonaceous materials is considered as reliable energy source. In this context, pyrolysis, combustion and gasification characteristics of scrap truck and car tire samples were investigated using a thermo-gravimetric analyzer ...

Jayaraman KANDASAMY; Iskender Gökalp

2014-12-05T23:59:59.000Z

250

Reaction mechanism and kinetics of pressurized pyrolysis of Chinese oil shale in the presence of water  

Science Journals Connector (OSTI)

A study of reaction mechanisms and chemical kinetics of pressurized pyrolysis of Chinese Liushuhe oil shale in the presence of water were conducted ... thermal degradation. It was found that the oil shale was fir...

Chaohe Fang; Shuyuan Li; Guili Ma; Hongyan Wang; Zhilong Huang

2012-12-01T23:59:59.000Z

251

Study on HCl removal for medical waste pyrolysis and combustion using a TG-FTIR analyzer  

Science Journals Connector (OSTI)

Under both pyrolysis and combustion condition, HCl removal efficiency for medical waste with Cabased additives was semi-quantitatively studied by means of ... TG-FTIR. Additionally, the difference of HCl removal ...

Hongmei Zhu; Weiying Chen; Xuguang Jiang…

2014-02-01T23:59:59.000Z

252

Detailed kinetic study of anisole pyrolysis and oxidation to understand tar formation during biomass  

E-Print Network [OSTI]

biomass combustion and gasification Milena Nowakowska, Olivier Herbinet, Anthony Dufour, Pierre. Methoxyphenols are one of the main precursors of PAH and soot in biomass combustion and gasification. Keywords: Anisole; Pyrolysis; Oxidation; Tars; Biomass; Kinetic modeling Corresponding author

Paris-Sud XI, Université de

253

Production of Liquid Feedstock from Biomass via Steam Pyrolysis in a Fluidized Bed Reactor  

Science Journals Connector (OSTI)

Dry basis. ... loss on ignition ... A pre-charred, wood-based carbonaceous precursor was activated using a two-step process (steam-pyrolysis activation) to investigate the potential for optimizing an activation protocol for the prodn. of powd. ...

Efthymios Kantarelis; Weihong Yang; Wlodzimierz Blasiak

2013-06-25T23:59:59.000Z

254

Pyrolysis in Porous Media:1 Part 1. Numerical model and parametric study.2  

E-Print Network [OSTI]

due to the formation of light species and heavy ones (up to solid coke particles). The1 presence by the formation of3 permeable char [10,11]. The coal pyrolysi

Boyer, Edmond

255

Pyrolysis products from amino acids and protein: Highest mutagenicity requires cytochrome P1-450  

Science Journals Connector (OSTI)

...and halogenated dibenzo-p-dioxins present in combustion processes (e.g., charcoal cooking, cigarette...etiology of envi- ronmental carcinogenesis caused by combustion processes. Pyrolysis Products Are Ineffective as Inducers...

Daniel W. Nebert; Sanford W. Bigelow; Allan B. Okey; Takie Yahagi; Yuko Mori; Minako Nagao; Takashi Sugimura

1979-01-01T23:59:59.000Z

256

Combustion Tests of Bio-Oils Derived from Biomass Slow Pyrolysis  

Science Journals Connector (OSTI)

ENEL in collaboration with Region Abruzzo and Tecnars has carried out some experimental combustion tests of bio-oil produced with a conventional slow pyrolysis process, with a partial economic support of EEC.

C. Rossi; R. Frandi; E. Bonfitto…

1993-01-01T23:59:59.000Z

257

Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town |  

Broader source: Energy.gov (indexed) [DOE]

Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town Move Over Flash Pyrolysis, There's a New Bioenergy Sheriff in Town December 16, 2011 - 12:10pm Addthis Jonathan Peters, a researcher at RTI International (an ARPA-E awardee), characterizes the water content of a bio-oil sample. | Courtesy of RTI International. Jonathan Peters, a researcher at RTI International (an ARPA-E awardee), characterizes the water content of a bio-oil sample. | Courtesy of RTI International. April Saylor April Saylor Former Digital Outreach Strategist, Office of Public Affairs How does it work? This ARPA-E awardee removes the oxygen and other contaminants in the biomass to be turned into fuel with a novel "catalytic biomass pyrolysis" approach. This substance is more carbon efficient, requires less hydrogen to

258

Fast company | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fast company Fast company High performance computing accelerates scientific advances EMSL's NWChem software is being used for applications in biology such as modeling metabolic...

259

Influences of Additives on Steam Gasification of Biomass. 1. Pyrolysis Procedure  

Science Journals Connector (OSTI)

To remove tar and upgrade the quality of gaseous product, researchers have extensively studied the influences of various additives(2-6) and diverse reactors(7-9) on biomass gasification. ... For the pyrolysis procedure, there are two effectual methods, improving operating conditions and adding additives into reactors, to control the formations of tar and CnHm. ... The chemical components of additives added in the related pyrolysis procedure are shown in Table 2. ...

Yu R. Xie; Lai H. Shen; Jun Xiao; Da X. Xie; Jing Zhu

2009-09-23T23:59:59.000Z

260

Pyrolysis for Biochar Purposes: A Review to Establish Current Knowledge Gaps and Research Needs  

Science Journals Connector (OSTI)

Khalil(28) reported very low surface areas for charcoals (from a wide variety of biomass feedstocks) pyrolyzed at temperatures near 550 °C. ... Cetin and co-workers(33) reported a slight decrease of the total surface area by increasing pressure during the pyrolysis of several biomass feedstocks (radiata pine, eucalyptus wood, and sugar cane bagasse). ... Table 1 reports several experimental data from the literature for slow pyrolysis of different biomass feedstocks under various operating conditions. ...

Joan J. Manyà

2012-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Group pyrolysis, ignition, and combustion of a spherical cloud of coal particles  

E-Print Network [OSTI]

GROUP PYROLYSIS, IGNITION, AND COMBUSTION OF A SPHERICAL CLOUD OF COAL PARTICLES A Thesis by WILLIAM RICHARD RYAN, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree MASTER OF SCIENCE December 1988 Major Subject: Mechanical Engineering GROUP PYROLYSIS, IGNITION, AND COMBUSTION OF A SPHERICAL CLOUD OF COAL PARTICLES A Thesis by WIL LI AM RI C HA RD RYA N ~ JR Approved ss to style and content by...

Ryan, William Richard

1988-01-01T23:59:59.000Z

262

Wind energy conversion system  

DOE Patents [OSTI]

The wind energy conversion system includes a wind machine having a propeller connected to a generator of electric power, the propeller rotating the generator in response to force of an incident wind. The generator converts the power of the wind to electric power for use by an electric load. Circuitry for varying the duty factor of the generator output power is connected between the generator and the load to thereby alter a loading of the generator and the propeller by the electric load. Wind speed is sensed electro-optically to provide data of wind speed upwind of the propeller, to thereby permit tip speed ratio circuitry to operate the power control circuitry and thereby optimize the tip speed ratio by varying the loading of the propeller. Accordingly, the efficiency of the wind energy conversion system is maximized.

Longrigg, Paul (Golden, CO)

1987-01-01T23:59:59.000Z

263

Session: Energy Conversion  

SciTech Connect (OSTI)

This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of five presentations: ''Hydrothermal Energy Conversion Technology'' by David Robertson and Raymond J. LaSala; ''Materials for Geothermal Production'' by Lawrence E. Kukacka; ''Supersaturated Turbine Expansions for Binary Geothermal Power Plants'' by Carl J. Bliem; ''Geothermal Waster Treatment Biotechnology: Progress and Advantages to the Utilities'' by Eugen T. Premuzic; and ''Geothermal Brine Chemistry Modeling Program'' by John H. Weare.

Robertson, David; LaSala, Raymond J.; Kukacka, Lawrence E.; Bliem, Carl J.; Premuzic, Eugene T.; Weare, John H.

1992-01-01T23:59:59.000Z

264

Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils  

DOE Patents [OSTI]

A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous layer with ethyl acetate, and discarding the ethyl acetate fraction to obtain a brown-colored solution not susceptible to gelling or solidification upon heating; i) heating the solution to distill off water and other light components and concentrating a bottoms fraction comprising hydroxyacetaldehyde and other non-volatile components having high boiling points; and j) decolorizing the stabilized brown solution with activated carbon to obtain a colorless solution.

Agblevor, Foster A. (Blacksburg, VA); Besler-Guran, Serpil (Flemington, NJ)

2001-01-01T23:59:59.000Z

265

Conversion of Questionnaire Data  

SciTech Connect (OSTI)

During the survey, respondents are asked to provide qualitative answers (well, adequate, needs improvement) on how well material control and accountability (MC&A) functions are being performed. These responses can be used to develop failure probabilities for basic events performed during routine operation of the MC&A systems. The failure frequencies for individual events may be used to estimate total system effectiveness using a fault tree in a probabilistic risk analysis (PRA). Numeric risk values are required for the PRA fault tree calculations that are performed to evaluate system effectiveness. So, the performance ratings in the questionnaire must be converted to relative risk values for all of the basic MC&A tasks performed in the facility. If a specific material protection, control, and accountability (MPC&A) task is being performed at the 'perfect' level, the task is considered to have a near zero risk of failure. If the task is performed at a less than perfect level, the deficiency in performance represents some risk of failure for the event. As the degree of deficiency in performance increases, the risk of failure increases. If a task that should be performed is not being performed, that task is in a state of failure. The failure probabilities of all basic events contribute to the total system risk. Conversion of questionnaire MPC&A system performance data to numeric values is a separate function from the process of completing the questionnaire. When specific questions in the questionnaire are answered, the focus is on correctly assessing and reporting, in an adjectival manner, the actual performance of the related MC&A function. Prior to conversion, consideration should not be given to the numeric value that will be assigned during the conversion process. In the conversion process, adjectival responses to questions on system performance are quantified based on a log normal scale typically used in human error analysis (see A.D. Swain and H.E. Guttmann, 'Handbook of Human Reliability Analysis with Emphasis on Nuclear Power Plant Applications,' NUREG/CR-1278). This conversion produces the basic event risk of failure values required for the fault tree calculations. The fault tree is a deductive logic structure that corresponds to the operational nuclear MC&A system at a nuclear facility. The conventional Delphi process is a time-honored approach commonly used in the risk assessment field to extract numerical values for the failure rates of actions or activities when statistically significant data is absent.

Powell, Danny H [ORNL] [ORNL; Elwood Jr, Robert H [ORNL] [ORNL

2011-01-01T23:59:59.000Z

266

Semiconductor Nanowires and Nanotubes for Energy Conversion  

E-Print Network [OSTI]

Nanowires and Nanotubes for Energy Conversion By MelissaNanowires and Nanotubes for Energy Conversion by MelissaNanowires and Nanotubes for Energy Conversion by Melissa

Fardy, Melissa Anne

2010-01-01T23:59:59.000Z

267

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion (OTEC) Draft Programmaticof ocean thermal energy conversion technology. U.S. Depart~on Ocean TherUial Energy Conversion, June 18, 1979. Ocean

Sands, M.Dale

2013-01-01T23:59:59.000Z

268

Advanced Conversion Roadmap Workshop | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Advanced Conversion Roadmap Workshop DOE introduction slides to the Advanced Conversion Roadmap Workshop webinar. ctabwebinardoe.pdf More Documents & Publications Conversion...

269

Experimental and Analytical Studies on Pyroelectric Waste Heat Energy Conversion  

E-Print Network [OSTI]

energy conversion . . . . . . . . . . . . . . . . . . . . . . . . . .other pyroelectric energy conversion methods . . . . Chapter6 Pyroelectric Energy Conversion using PLZT and

Lee, Felix

2012-01-01T23:59:59.000Z

270

Semi-Open Pyrolysis of Oil Shale from the Garden Gulch Member of the Green River Formation  

Science Journals Connector (OSTI)

Semi-Open Pyrolysis of Oil Shale from the Garden Gulch Member of the Green River Formation ... Energy Fuels, Article ASAP ...

Alan K. Burnham; James R. McConaghy

2014-11-27T23:59:59.000Z

271

A component based model for the prediction of the product yields of the pyrolysis of a biomass particle.  

E-Print Network [OSTI]

??Pyrolysis of biomass can produce several useful, renewable products: biochar for soil amendment and long-term carbon sequestration; tars for chemicals and biofuels; and syngas as… (more)

Eberly, Brian C.

2010-01-01T23:59:59.000Z

272

Zinc phosphate conversion coatings  

DOE Patents [OSTI]

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

Sugama, Toshifumi (Wading River, NY)

1997-01-01T23:59:59.000Z

273

Zinc phosphate conversion coatings  

DOE Patents [OSTI]

Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

Sugama, T.

1997-02-18T23:59:59.000Z

274

Deactivation and regeneration of ZSM-5 zeolite in catalytic pyrolysis of plastic wastes  

SciTech Connect (OSTI)

Highlights: > Pyrolysis transforms plastic wastes in valuable liquids and gases useful as fuels or source of chemicals. > The use of ZSM-5 zeolite in pyrolysis favours the production of gases and of lighter and more aromatic liquids. > ZSM-5 zeolite is almost completely deactivated after one plastics pyrolysis experiment. > ZSM-5 zeolite used in plastic wastes pyrolysis can be regenerated by burning the deposited coke in an air stream. > Regenerated ZSM-5 recovers its activity and produces liquids and gases equivalent to those obtained with fresh catalyst. - Abstract: In this work, a study of the regeneration and reuse of ZSM-5 zeolite in the pyrolysis of a plastic mixture has been carried out in a semi-batch reactor at 440 deg. C. The results have been compared with those obtained with fresh-catalyst and in non-catalytic experiments with the same conditions. The use of fresh catalyst produces a significant change in both the pyrolysis yields and the properties of the liquids and gases obtained. Gases more rich in C3-C4 and H{sub 2} are produced, as well as lower quantities of aromatic liquids if compared with those obtained in thermal decomposition. The authors have proved that after one pyrolysis experiment the zeolite loses quite a lot of its activity, which is reflected in both the yields and the products quality; however, this deactivation was found to be reversible since after regeneration heating at 550 deg. C in oxygen atmosphere, this catalyst recovered its initial activity, generating similar products and in equivalent proportions as those obtained with fresh catalyst.

Lopez, A., E-mail: alex.lopez@ehu.es [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda Urquijo s/n, 48013 Bilbao (Spain); Marco, I. de; Caballero, B.M.; Adrados, A.; Laresgoiti, M.F. [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda Urquijo s/n, 48013 Bilbao (Spain)

2011-08-15T23:59:59.000Z

275

Modelling of heating and evaporation of n-Heptane droplets: Towards a generic model for fuel droplet/particle conversion  

E-Print Network [OSTI]

is a part of a project that is targeted to optimize the pyrolysis process of biomass pellets for bio, study of pyrolysis of the biomass pellets and evaporation of the pyrolysis bio-oil droplets are two key of the biomass pellets in the pyrolysis reactor, for the purpose of optimiz- ing the pyrolysis process. Modelling

Yin, Chungen

276

Real-time method for the identification and quantification of hydrocarbon pyrolysis products: Part II. Application to transient pyrolysis and validation by numerical simulation.  

E-Print Network [OSTI]

is expected to be achieved with Supersonic Combustion Ramjet engine [1]-[4]. Due to the large heat load applied on the structure (elevated total temperature in case of high speed [5],[6] and combustion heat such a technology, the combustion of the hydrocarbon pyrolysis products should be assessed and this requires

Paris-Sud XI, Université de

277

Investigation on syngas production via biomass conversion through the integration of pyrolysis and air–steam gasification processes  

Science Journals Connector (OSTI)

Abstract Fuel production from agro-waste has become an interesting alternative for energy generation due to energy policies and greater understanding of the importance of green energy. This research was carried out in a lab-scale gasifier and coconut shell was used as feedstock in the integrated process. In order to acquire the optimum condition of syngas production, the effect of the reaction temperature, equivalence ratio (ER) and steam/biomass (S/B) ratio was investigated. Under the optimized condition, H2 and syngas yield achieved to 83.3 g/kg feedstock and 485.9 g/kg feedstock respectively, while LHV of produced gases achieved to 12.54 MJ/N m3.

Reza Alipour Moghadam; Suzana Yusup; Wan Azlina; Shahab Nehzati; Ahmad Tavasoli

2014-01-01T23:59:59.000Z

278

22 - Conversion Factors  

Science Journals Connector (OSTI)

Abstract This chapter details the viscosity and pressure conversion chart. To convert absolute or dynamic viscosity from one set of units to another, one must locate the given set of units in the left-hand column then multiply the numerical value by the factor shown horizontally to the right-hand side, under the set of units desired. The chapter also explains that to convert kinematic viscosity from one set of units to another, one must locate the given set of units in the left-hand column and multiply the numerical value by the factor shown horizontally to the right-hand side, under the set of units desired. The chapter also defines how the conversion from natural gas to other fuels has progressed from possibility to reality for many companies and will become necessary for many others in months and years ahead. Fuels that are considered practical replacements for gas include coal, heavy fuel oils, middle distillates (such as kerosine–typeturbo fuel and burner fuel oils) and liquefied petroleum gas.

2014-01-01T23:59:59.000Z

279

Energy conversion system  

DOE Patents [OSTI]

The energy conversion system includes a photo-voltaic array for receiving solar radiation and converting such radiation to electrical energy. The photo-voltaic array is mounted on a stretched membrane that is held by a frame. Tracking means for orienting the photo-voltaic array in predetermined positions that provide optimal exposure to solar radiation cooperate with the frame. An enclosure formed of a radiation transmissible material includes an inside containment space that accommodates the photo-voltaic array on the stretched membrane, the frame and the tracking means, and forms a protective shield for all such components. The enclosure is preferably formed of a flexible inflatable material and maintains its preferred form, such as a dome, under the influence of a low air pressure furnished to the dome. Under this arrangement the energy conversion system is streamlined for minimizing wind resistance, sufficiently weatherproof for providing protection against weather hazards such as hail, capable of using diffused light, lightweight for low-cost construction, and operational with a minimal power draw.

Murphy, Lawrence M. (Lakewood, CO)

1987-01-01T23:59:59.000Z

280

Energy conversion system  

DOE Patents [OSTI]

The energy conversion system includes a photo-voltaic array for receiving solar radiation and converting such radiation to electrical energy. The photo-voltaic array is mounted on a stretched membrane that is held by a frame. Tracking means for orienting the photo-voltaic array in predetermined positions that provide optimal exposure to solar radiation cooperate with the frame. An enclosure formed of a radiation transmissible material includes an inside containment space that accommodates the photo-voltaic array on the stretched membrane, the frame and the tracking means, and forms a protective shield for all such components. The enclosure is preferably formed of a flexible inflatable material and maintains its preferred form, such as a dome, under the influence of a low air pressure furnished to the dome. Under this arrangement the energy conversion system is streamlined for minimizing wind resistance, sufficiently weathproof for providing protection against weather hazards such as hail, capable of using diffused light, lightweight for low-cost construction and operational with a minimal power draw.

Murphy, L.M.

1985-09-16T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Modeling a set of heavy oil aqueous pyrolysis experiments  

SciTech Connect (OSTI)

Aqueous pyrolysis experiments, aimed at mild upgrading of heavy oil, were analyzed using various computer models. The primary focus of the analysis was the pressure history of the closed autoclave reactors obtained during the heating of the autoclave to desired reaction temperatures. The models used included a means of estimating nonideal behavior of primary components with regard to vapor liquid equilibrium. The modeling indicated that to match measured autoclave pressures, which often were well below the vapor pressure of water at a given temperature, it was necessary to incorporate water solubility in the oil phase and an activity model for the water in the oil phase which reduced its fugacity below that of pure water. Analysis also indicated that the mild to moderate upgrading of the oil which occurred in experiments that reached 400{degrees}C or more using a FE(III) 2-ethylhexanoate could be reasonably well characterized by a simple first order rate constant of 1.7xl0{sup 8} exp(-20000/T)s{sup {minus}l}. Both gas production and API gravity increase were characterized by this rate constant. Models were able to match the complete pressure history of the autoclave experiments fairly well with relatively simple equilibria models. However, a consistent lower than measured buildup in pressure at peak temperatures was noted in the model calculations. This phenomena was tentatively attributed to an increase in the amount of water entering the vapor phase caused by a change in its activity in the oil phase.

Thorsness, C.B.; Reynolds, J.G.

1996-11-01T23:59:59.000Z

282

Characterization and pyrolysis behavior of novel anthracene oil derivatives  

SciTech Connect (OSTI)

The characterization and pyrolysis behavior of a set of pitches prepared from anthracene oil have been described. The pitches were obtained from four successive cycles of a sequential process that begins with blowing air through the heated anthracene oil, to bring about recombination reactions. Reaction products are distilled to give a pitch residue and a lighter fraction. Thermal treatment/distillation cycles of this reaction product yield a pitch and a distillate fraction (unreacted anthracene oil) during each subsequent stage. Products obtained during the process have been characterized by elemental analysis, Fourier transform infrared (FTIR) and ultraviolet (UV)-fluorescence spectroscopy, and size-exclusion chromatography (SEC). The pyrolytic behavior of the anthracene oil derivatives was examined using a thermogravimetric balance. Thermal treatment of the anthracene oil and its (distilled) reaction products at 440-460{degree}C under 5 bar pressure leads to a partially anisotropic pitch with the formation of a liquid crystal phase (mesophase). The formation and evolution of these mesophases were analyzed by optical microscopy. 25 refs., 9 figs., 3 tabs.

P. Alvarez; M. Granda; J. Sutil; R. Menendez; J.J. Fernandez; J.A. Vina; T.J. Morgan; M. Millan; A.A. Herod; R. Kandiyoti [Instituto Nacional del Carbon, Oviedo (Spain)

2008-11-15T23:59:59.000Z

283

Coke formation during pyrolysis of 1,2-dichloroethane  

SciTech Connect (OSTI)

Most processes involving hydrocarbons or carbon oxides at high temperatures suffer from the disadvantage of coke formation. The formation of coke deposits during pyrolysis of hydrocarbons or chlorinated hydrocarbons is of significant practical importance. Examples of such processes are the steam cracking of alkanes to produce olefins and the thermal decomposition of 1,2-dichloroethane (EDC) for the production of vinyl chloride monomer (VCM). Even id the rate of coke production is low, the cumulative nature of the solid product will result in reactor fouling. The present work deals with the thermal decomposition of EDC. Coke formation has been studied on metal surfaces in a quartz tubular reactor. The rate of coke deposition was measures on metal foils hanging from one arm of a microbalance. A complete analysis of the product gas was accomplished using on-line gas chromatography. The results show that coke deposition during thermal decomposition of EDC depends on the composition of the feed as well as on the nature of the surface of the metal foil. Small amounts of other components (contamination with other chlorinated hydrocarbons as an example) may have a large influence on the rate of coke formation. The results are discussed in terms of surface composition/morphology of the metal foil and the free radical mechanism for thermal decomposition of FDC.

Holmen, A. [Norwegian Institute of Technology, Trondheim (Norway); Lindvag, O.A. [SINTEF Applied Chemistry, Trondheim (Norway)

1995-12-31T23:59:59.000Z

284

Wind energy conversion system  

SciTech Connect (OSTI)

This patent describes a wind energy conversion system comprising: a propeller rotatable by force of wind; a generator of electricity mechanically coupled to the propeller for converting power of the wind to electric power for use by an electric load; means coupled between the generator and the electric load for varying the electric power drawn by the electric load to alter the electric loading of the generator; means for electro-optically sensing the speed of the wind at a location upwind from the propeller; and means coupled between the sensing means and the power varying means for operating the power varying means to adjust the electric load of the generator in accordance with a sensed value of wind speed to thereby obtain a desired ratio of wind speed to the speed of a tip of a blade of the propeller.

Longrigg, P.

1987-03-17T23:59:59.000Z

285

Quantum optical waveform conversion  

E-Print Network [OSTI]

Currently proposed architectures for long-distance quantum communication rely on networks of quantum processors connected by optical communications channels [1,2]. The key resource for such networks is the entanglement of matter-based quantum systems with quantum optical fields for information transmission. The optical interaction bandwidth of these material systems is a tiny fraction of that available for optical communication, and the temporal shape of the quantum optical output pulse is often poorly suited for long-distance transmission. Here we demonstrate that nonlinear mixing of a quantum light pulse with a spectrally tailored classical field can compress the quantum pulse by more than a factor of 100 and flexibly reshape its temporal waveform, while preserving all quantum properties, including entanglement. Waveform conversion can be used with heralded arrays of quantum light emitters to enable quantum communication at the full data rate of optical telecommunications.

D Kielpinski; JF Corney; HM Wiseman

2010-10-11T23:59:59.000Z

286

BIOMASS ENERGY CONVERSION IN HAWAII  

E-Print Network [OSTI]

Operations, vol. 2 of Biomass Energy (Stanford: StanfordPhotosynthethic Pathway Biomass Energy Production," ~c:_! _LBL-11902 UC-61a BIOMASS ENERGY CONVERSION IN HAWAII

Ritschard, Ronald L.

2013-01-01T23:59:59.000Z

287

Biochemical Conversion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

by enhancing fuel yields in integrated biorefineries which combine conversion types with heat and power efficiencies to produce fuel and products. Lignocellulose (mainly lignin,...

288

Energy conversion by gravitational waves  

Science Journals Connector (OSTI)

... out that if such particles are charged, the accelerations will constitute a mechanism for the conversion of gravitational ... of gravitational energy into electromagnetic ...

H. BONDI; F. A. E. PIRANI

1988-03-17T23:59:59.000Z

289

Reduction of iron oxide as an oxygen carrier by coal pyrolysis and steam char gasification intermediate products  

SciTech Connect (OSTI)

The feasibility of the reduction of oxygen carrier Fe{sub 2}O{sub 3} in chemical-looping combustion using solid fuel (lignite) provided a gasifying agent like steam was introduced into the reactor was investigated with a fixed-bed reactor. The X-ray diffractometer and scanning electron microscope were used for the characterization of the Fe{sub 2}O{sub 3} and its reduction residue. Results strongly supported the feasibility of Fe{sub 2}O{sub 3} reduction by lignite and obtaining pure CO{sub 2} from the off-gases. Fe{sub 2}O{sub 3} can be fully converted to Fe{sub 3}O{sub 4} by pyrolysis and gasification intermediates primarily H{sub 2} and CO, which was confirmed by both the off-gas concentrations and X-ray diffractometer analysis. A 0.75 g portion of Fe{sub 2}O{sub 3} can be completely reduced to Fe{sub 3}O{sub 4} by the volatile matter released from 0.1 g coal, and Fe{sub 2}O{sub 3} can be fully reduced to Fe{sub 3}O{sub 4} by steam char gasification products provided that the molar ratio of carbon in char to Fe{sub 2}O{sub 3} is 1:6. The purity of CO{sub 2} in the outlet gases was higher than 85% when Fe{sub 2}O{sub 3} was reduced by intermediate products during coal pyrolysis, and the purity of CO{sub 2} in the off-gases was higher than 95% when Fe{sub 2}O{sub 3} was reduced by intermediate products resulting from steam char gasification, making CO{sub 2} sequestration disposal desirable for high purity CO{sub 2}. The char gasification reaction rate was slow compared with the reactivity of the iron oxide with the char gasified intermediates, indicating that char gasification was the rate-limiting step in the reduction process. In the steam char gasification process, the times it took to reach 90% carbon conversion for K-10-char and Ca-10-char were 15 and 30 min, respectively, at 1123 K, but the time for the raw char was 50 min at 1173 K. 40 refs., 15 figs., 3 tabs.

Jing-biao Yang; Ning-sheng Cai; Zhen-shan Li [Tsinghua University, Beijing (China). Key Laboratory of Thermal Science and Power Engineering of Ministry of Education

2007-12-15T23:59:59.000Z

290

Synthesis of Mixed Metal Oxides for Hydrodeoxygenation of Pyrolysis Oil for Alternative Fuels Sarah McNew, Tiorra Ross and Carsten Sievers  

E-Print Network [OSTI]

· Flash pyrolysis on biomass [1] · Short residence times and flexible feed · Bio-oils produced are close to dissociate hydrogen Goal: synthesize metal free, sulfur free, catalysts for HDO Biomass Pyrolysis OilSynthesis of Mixed Metal Oxides for Hydrodeoxygenation of Pyrolysis Oil for Alternative Fuels Sarah

Das, Suman

291

Alternative Fuels Data Center: Conversion Regulations  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Conversion Regulations Conversion Regulations to someone by E-mail Share Alternative Fuels Data Center: Conversion Regulations on Facebook Tweet about Alternative Fuels Data Center: Conversion Regulations on Twitter Bookmark Alternative Fuels Data Center: Conversion Regulations on Google Bookmark Alternative Fuels Data Center: Conversion Regulations on Delicious Rank Alternative Fuels Data Center: Conversion Regulations on Digg Find More places to share Alternative Fuels Data Center: Conversion Regulations on AddThis.com... Conversion Regulations All vehicle and engine conversions must meet standards instituted by the U.S. Environmental Protection Agency (EPA), the National Highway Traffic Safety Administration (NHTSA), and state agencies like the California Air Resources Board (CARB).

292

Fast-Neutron Handbook  

Science Journals Connector (OSTI)

... FAST neutron physics, in the present context, concerns the study of interactions of atomic nuclei with neutrons ...

J. H. MONTAGUE

1961-06-10T23:59:59.000Z

293

Characterisation and Evaluation of Wastes for Treatment in the Batch Pyrolysis Plant in Studsvik, Sweden - 13586  

SciTech Connect (OSTI)

The new batch pyrolysis plant in Studsvik is built primarily for treatment of uranium containing dry active waste, 'DAW'. Several other waste types have been identified that are considered or assumed suitable for treatment in the pyrolysis plant because of the possibility to carefully control the atmosphere and temperature of the thermal treatment. These waste types must be characterised and an evaluation must be made with a BAT perspective. Studsvik have performed or plan to perform lab scale pyrolysis tests on a number of different waste types. These include: - Pyrophoric materials (uranium shavings), - Uranium chemicals that must be oxidised prior to being deposited in repository, - Sludges and oil soaks (this category includes NORM-materials), - Ion exchange resins (both 'free' and solidified/stabilised), - Bitumen solidified waste. Methodology and assessment criteria for various waste types, together with results obtained for the lab scale tests that have been performed, are described. (authors)

Lindberg, Maria; Oesterberg, Carl; Vernersson, Thomas [Studsvik Nuclear AB, Studsvik Nuclear AB, 611 82 Nykoeping (Sweden)] [Studsvik Nuclear AB, Studsvik Nuclear AB, 611 82 Nykoeping (Sweden)

2013-07-01T23:59:59.000Z

294

Transformation of alkali metals during pyrolysis and gasification of a lignite  

SciTech Connect (OSTI)

Transformation of Na and K in a lignite was investigated during pyrolysis and gasification in a fixed-bed by using a serial dissolution method with H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solutions. The evolution of the fractions of four forms in solid and alkali volatilization during pyrolysis and gasification was determined. The results show that a different mode of occurrence between Na and of K in coal existed. Na in coal can be nearly completely dissolved by H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solution. However, K in coal exists almost in the stable forms. Both H{sub 2}O soluble and CH{sub 3}COONH{sub 4} soluble Na and K fractions decline during pyrolysis and early gasification stage and increase a little with the process of char gasification. The stable form Na in the char produced during pyrolysis is transferred to other forms during char gasification via the pore opening and a series of chemical reactions. Na{sub 2}SO{sub 4} (K{sub 2}SO{sub 4}) may play an important role in producing stable forms such as Na{sub 2}O.Al{sub 2}O{sub 3}2SiO{sub 2} and K{sub 2}O.Al{sub 2}O{sub 3}.2SiO{sub 2} during pyrolysis. The fraction of HCl soluble K increases during pyrolysis but decreases markedly during the early gasification stage. 20 refs., 7 figs., 1 tabs.

Xiaofang Wei; Jiejie Huang; Tiefeng Liu; Yitian Fang; Yang Wang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2008-05-15T23:59:59.000Z

295

CO2 Gasification Kinetics of Biomass Char Derived from High-Temperature Rapid Pyrolysis  

Science Journals Connector (OSTI)

CO2 Gasification Kinetics of Biomass Char Derived from High-Temperature Rapid Pyrolysis ... The rapid pyrolysis char produced was isothermally gasified in a thermogravimetric analyzer (TGA) under a CO2 atmosphere. ... In the study by Zhang and co-workers, where as much as 14 biomass chars were gasified, gasification rates of all of the wooden biomass chars present a similar feature as Figure 7a (PS char), but this feature has not been found from gasification rates of the herbaceous biomass char. ...

Shuai Yuan; Xue-li Chen; Jun Li; Fu-chen Wang

2011-03-30T23:59:59.000Z

296

Biofuels from Pyrolysis in Perspective: Trade-offs between Energy Yields and Soil-Carbon Additions  

Science Journals Connector (OSTI)

Biofuels from Pyrolysis in Perspective: Trade-offs between Energy Yields and Soil-Carbon Additions ... We then apply this model to quantify the trade-offs between energy and biochar yields in BEBCS for a range of possible biofuel pathways for the coproduction of biochar with liquid or gaseous biofuels. ... (43) Thus, we can see that when biochar prices (per Mg C) are less than 33 times the price (per GJ) of gaseous fuels or 21 times the price of liquid pyrolysis fuels, coproduction of biochar with biofuels will reduce revenues compared to biofuel-only production. ...

Dominic Woolf; Johannes Lehmann; Elizabeth M. Fisher; Largus T. Angenent

2014-04-30T23:59:59.000Z

297

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents [OSTI]

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

Rashid Khan, M.

1988-05-05T23:59:59.000Z

298

Decaking of coal or oil shale during pyrolysis in the presence of iron oxides  

DOE Patents [OSTI]

A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

Khan, M. Rashid (Morgantown, WV)

1989-01-01T23:59:59.000Z

299

Pyrolysis Using Microwave Heating: A Sustainable Process for Recycling Used Car Engine Oil  

Science Journals Connector (OSTI)

Pyrolysis Using Microwave Heating: A Sustainable Process for Recycling Used Car Engine Oil ... A reaction temperature of 600 °C provided the greatest yield of commercially valuable products: the recovered liquid oils were composed of light paraffins and aromatic hydrocarbons that could be used as industrial feedstock; the remaining incondensable gases comprised light hydrocarbons that could potentially be used as a fuel source to power the process. ... The pyrolysis products leave the reactor and pass through a system of three water-cooled Liebig condensers [5, 6, 7], which collect condensed hydrocarbons in main and secondary collection flasks [8, 9]. ...

Su Shiung Lam; Alan D. Russell; Howard A. Chase

2010-06-18T23:59:59.000Z

300

Production of higher quality bio-oils by in-line esterification of pyrolysis vapor  

DOE Patents [OSTI]

The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.

Hilten, Roger Norris; Das, Keshav; Kastner, James R; Bibens, Brian P

2014-12-02T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Fuel nitrogen release during black liquor pyrolysis; Part 2: Comparisons between different liquors  

SciTech Connect (OSTI)

This continuation of earlier work reports fuel nitrogen release for black liquors at two temperatures during pyrolysis of single droplets in an oxygen-free environment. Approximately half of the 20--60% fuel nitrogen released was ammonia and half was molecular nitrogen. The total amount of fixed nitrogen released during pyrolysis was almost linearly proportional to the liquor nitrogen content. The yield of fixed nitrogen for birch liquors was significantly higher than for pine liquors, and the yield for bagasse liquor was extremely high.

Aho, K.; Nikkanen, S. (A. Ahlstrom Corp., Varkaus (Finland)); Hupa, M. (Abo Akademi Univ., Turku (Finland). Chemical Engineering Dept.)

1994-08-01T23:59:59.000Z

302

5, 35333559, 2005 Catalytic conversion  

E-Print Network [OSTI]

measurement technique, employing selective gas- phase catalytic conversion of methanol to formaldehyde it the second most abundant organic trace gas after methane. Methanol can play an important role in upper tropoACPD 5, 3533­3559, 2005 Catalytic conversion of methanol to formaldehyde S. J. Solomon et al. Title

Paris-Sud XI, Université de

303

The Alpha–Bet(a) of Glucose Pyrolysis: Computational and Experimental Investigations of 5-Hydroxymethylfurfural and Levoglucosan Formation Reveal Implications for Cellulose Pyrolysis  

Science Journals Connector (OSTI)

The Alpha–Bet(a) of Glucose Pyrolysis: Computational and Experimental Investigations of 5-Hydroxymethylfurfural and Levoglucosan Formation Reveal Implications for Cellulose Pyrolysis ... For example, there are several proposed mechanisms for evolution of an important product and platform chemical, 5-hydroxymethylfurfural (5-HMF), but evaluation with different methodologies has hindered comparison. ... (12, 17) The remaining 41% is composed of water (from dehydration) and products that individually account for less than 7 wt % of the yield, including 6.7 wt % glycolaldehyde, 4.1 wt % of the furanose form of levoglucosan (1,6-anhydro-?-d-glucofuranose), and 2.8 wt % 5-hydroxymethylfurfural (5-HMF), as reported in the meticulous study by Patwardhan et al. conducted at 500 °C with pure cellulose feed, rapid heating, and minimization of secondary reactions. ...

Heather B. Mayes; Michael W. Nolte; Gregg T. Beckham; Brent H. Shanks; Linda J. Broadbelt

2014-04-23T23:59:59.000Z

304

Management and Uses Conversion Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion Conversion Depleted UF6 Conversion DOE is planning to build two depleted UF6 conversion facilities, and site-specific environmental impact statements (EISs) to evaluate project alternatives. The Final Plan for Conversion and the Programmatic EIS The eventual disposition of depleted UF6 remains the subject of considerable interest within the U.S. Congress, and among concerned citizens and other stakeholders. Congress stated its intentions in Public Law (P. L.) 105-204, signed by the President in July 1998. P. L. 105-204 required DOE to develop a plan to build two depleted UF6 conversion facilities, one each at Portsmouth, Ohio, and Paducah, Kentucky. DOE submitted the required plan, Final Plan for the Conversion of Depleted Uranium Hexafluoride, to Congress in July 1999. This document provided a discussion of DOE's technical approach and schedule to implement this project. Although much of the information provided in this report is still valid, a few aspects of this plan have changed since its publication.

305

EPA Redesigns Conversion Certification Policies  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

EPA Redesigns EPA Redesigns Conversion Certification Policies At a recent meeting held in Washington, DC, officials from the U.S. Environmental Protection Agency (EPA) opened dialogue about proposed changes to its emission certification policies that affect alternative fuel vehicles (AFVs). "We are trying to accommo- date the Energy Policy Act (EPAct) and Executive Order requirements while trying to change enforce- ment policies and guidance with respect to conversions," said Rich Ackerman of EPA's Enforcement Office. The meeting, attended by representatives of more than 60 organizations, was held to discuss actions addressing AFV emission certification. Specifically, topics included * Conversion emissions perfor- mance data * Status of environmental laws pertaining to alternative fuel

306

Thermal Conversion Process (TCP) Technology  

Broader source: Energy.gov (indexed) [DOE]

Changing World Technologies' Changing World Technologies' Thermal Conversion Process Commercial Demonstration Plant DOE/EA 1506 Weld County, Colorado December 2004 U.S. DEPARTMENT OF ENERGY GOLDEN FIELD OFFICE 1617 Cole Boulevard Golden, Colorado 80401 Thermal Conversion Process (TCP) Technology Commercial Demonstration - Weld County, CO TABLE OF CONTENTS Environmental Assessment Thermal Conversion Process (TCP) Technology Commercial Demonstration Project Weld County, Colorado SUMMARY............................................................................................................................. S-1 1.0 INTRODUCTION.........................................................................................................1-1 1.1. National Environmental Policy Act and Related Procedures...........................1-1

307

Comparative assessment of municipal sewage sludge incineration, gasification and pyrolysis for a sustainable sludge-to-energy management in Greece  

SciTech Connect (OSTI)

Highlights: • The high output of MSS highlights the need for alternative routes of valorization. • Evaluation of 3 sludge-to-energy valorisation methods through SWOT analysis. • Pyrolysis is an energy and material recovery process resulting to ‘zero waste’. • Identification of challenges and barriers for MSS pyrolysis in Greece was investigated. • Adopters of pyrolysis systems face the challenge of finding new product markets. - Abstract: For a sustainable municipal sewage sludge management, not only the available technology, but also other parameters, such as policy regulations and socio-economic issues should be taken in account. In this study, the current status of both European and Greek Legislation on waste management, with a special insight in municipal sewage sludge, is presented. A SWOT analysis was further developed for comparison of pyrolysis with incineration and gasification and results are presented. Pyrolysis seems to be the optimal thermochemical treatment option compared to incineration and gasification. Sewage sludge pyrolysis is favorable for energy savings, material recovery and high added materials production, providing a ‘zero waste’ solution. Finally, identification of challenges and barriers for sewage sludge pyrolysis deployment in Greece was investigated.

Samolada, M.C. [Dept. Secretariat of Environmental and Urban Planning – Decentralized Area Macedonian Thrace, Taki Oikonomidi 1, 54008 Thessaloniki (Greece); Zabaniotou, A.A., E-mail: azampani@auth.gr [Aristotle University of Thessaloniki, Dept. of Chemical Engineering, University Box 455, University Campus, 541 24 Thessaloniki (Greece)

2014-02-15T23:59:59.000Z

308

Acid-catalyzed conversion of mono- and poly-sugars into platform chemicals: Effects of molecular structure of sugar substrate  

Science Journals Connector (OSTI)

Hydrolysis/pyrolysis of lignocellulosic biomass always produces a mixture of sugars with distinct structures as intermediates or products. This study tried to elucidate the effects of molecular structure of sugars on their acid-catalyzed conversions in ethanol/water. Location of carbonyl group in sugars (fructose versus glucose) and steric configuration of hydroxyl groups (glucose versus galactose) significantly affected yields of levulinic acid/ester (fructose > glucose > galactose). The dehydration of fructose to 5-(hydroxymethyl)furfural produces much less soluble polymer than that from glucose and galactose, which results in high yields of levulinic acid/ester from fructose. Anhydrate sugar such as levoglucosan tends to undergo the undesirable decomposition to form less levulinic acid/ester. Catalytic behaviors of the poly-sugars (sucrose, maltose, raffinose, ?-cyclodextrins) were determined much by their basic units. However, their big molecular sizes create the steric hindrance that significantly affects their followed conversion over solid acid catalyst.

Xun Hu; Liping Wu; Yi Wang; Yao Song; Daniel Mourant; Richard Gunawan; Mortaza Gholizadeh; Chun-Zhu Li

2013-01-01T23:59:59.000Z

309

John L Gaunt and Johannes Lehmann Energy balance and emissions associated with biochar sequestration and pyrolysis  

E-Print Network [OSTI]

2 Table S1. Energy inputs (Mj ha-1 ) associated with bio-energy crop production Forage Corn CropS1 John L Gaunt and Johannes Lehmann Energy balance and emissions associated with biochar sequestration and pyrolysis bioenergy production Summary of tables Data are provided energy inputs (Mj ha-1

Lehmann, Johannes

310

Pyrolysis of polycyclic perhydroarenes. 3: 1-n-decylperhydropyrene and structure-reactivity relations  

SciTech Connect (OSTI)

Naphthenic (perhydroarene) moieties decorated with n-alkyl substituents exist in heavy hydrocarbon resources such as coal, heavy oils, and asphaltenes. 1-n-Decylperhydropyrene (DPP) was pyrolyzed neat at temperatures between 400 and 475 C. DPP disappearance followed first-order kinetics, and the Arrhenius parameters for the first-order rate constant were A (s{sup {minus}1}) = 10{sup 9.55.0} and E = 42.9 {+-} 16.5 kcal/mol, where the uncertainties are the 95% confidence intervals. DPP pyrolysis generated numerous primary products, and the primary products with the highest initial selectivities were, in order of decreasing abundance, perhydropyrene plus 1-decene, methylene perhydropyrene plus n-nonane, tetradecahydropyrene plus n-decane, and methylperhydropyrene plus nonene. This ordering of product pairs is completely analogous to that observed from pyrolysis of an alkylcyclohexane, but it differed from that observed for the pyrolysis of other polycyclic n-alkylnaphthenes. Eight other n-alkylperhydroarenes were pyrolyzed at temperatures between 400 and 450 C. The resulting kinetics data were used to test three structure-reactivity correlations in the literature for the pyrolysis kinetics of saturated cyclic compounds and to update one of these correlations so that it becomes consistent with the kinetics of long-chain n-alkylperhydroarenes.

Savage, P.E.; Ratz, S.; Diaz, J. [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering] [Univ. of Michigan, Ann Arbor, MI (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

311

Quantitative Determination of Aliphatic Sulfur-Containing Additives by Pyrolysis-Gas Chromatography  

Science Journals Connector (OSTI)

......pyrolysis (7), infrared (8), combustion to SO4 = with subsequent determination...Drushel. The Analytical Chemistry of Sulfur and Its Compounds...London, p. 358. Sulfur in Coal and Coke by the Bomb Washing...organic materials by oxygen bomb combustion. Anal. Chem. 33:1760......

J.W. Sinclair; L. Schall; N.T. Crabb

1980-01-01T23:59:59.000Z

312

Accepted Manuscript Kinetic Modelling of High Density PolyEthylene Pyrolysis: Part 1. Comparison of  

E-Print Network [OSTI]

Accepted Manuscript Kinetic Modelling of High Density PolyEthylene Pyrolysis: Part 1. Comparison this article as: Gascoin N, Navarro-Rodriguez A, Gillard P, Mangeot A, Kinetic Modelling of High Density PolyEthylene.polymdegradstab.2012.05.008 #12;M ANUSCRIPT ACCEPTED ACCEPTED MANUSCRIPT 1 Kinetic Modelling of High Density PolyEthylene

Paris-Sud XI, Université de

313

Pyrolysis in Porous Media: Part 2.1 Numerical Analysis and Comparison to Experiments.2  

E-Print Network [OSTI]

to the heat flux absorption. The formation of a thin film inside the combustion13 chamber, the so-called film, France17 Only limited studies are available experimentally to investigate18 hydrocarbon fuel pyrolysis investigate the related phenomena (heat and mass transfer with chemistry).22 After a first code validation

Boyer, Edmond

314

A Study on the Relationship between Fuel Composition and Pyrolysis Kinetics  

Science Journals Connector (OSTI)

A Study on the Relationship between Fuel Composition and Pyrolysis Kinetics ... ‡ Foster Wheeler Energy Corporation, Clinton, New Jersey 08809, United States ... The DTR system, illustrated in Figure 1, consists of four main components: a fuel feeder, a preheater, a furnace, and a sample collection probe. ...

Laura C. Bradley; Sharon Falcone Miller; Bruce G. Miller; David A. Tillman

2011-03-26T23:59:59.000Z

315

The Intramolecular Isotope Effect in the Pyrolysis of 1-$^{14}$C Propane  

Science Journals Connector (OSTI)

...Intramolecular Isotope Effect in the Pyrolysis of 1- C Propane H. M. Frey C. J. Danby Cyril Hinshelwood 1- C propane has been synthesized from active barium carbonate in 50% yield. This propane has been pyrolyzed at temperatures from 550 to 603...

1956-01-01T23:59:59.000Z

316

Preparation of BaTiO3 nanoparticles by combustion spray pyrolysis Sangjin Leea  

E-Print Network [OSTI]

], hydrothermal [6], and spray pyrolysis [7­9] have been developed to prepare stoichiometric, ultra- fine BaTiO3 process. Hydrothermal BaTiO3 powders [6] are usually a paraelectric cubic phase, which needs additional freedom from hydrocarbon-based chem- icals, and thus avoiding carbon-contamination problems. As a result

Messing, Gary L.

317

CaO-based sorbents for CO2 capture prepared by ultrasonic spray pyrolysis  

E-Print Network [OSTI]

of additives in the CaO matrix and the relatively high surface area materials obtained via USP explain are currently under investigation for CO2 capture, both for post- combustion (e.g., silica supported amines,2 of metal oxides, even on an industrial scale.18,19 We report here the rst use of ultrasonic spray pyrolysis

Suslick, Kenneth S.

318

Pyrolysis and ignition behavior of coal, cattle biomass, and coal/cattle biomass blends  

E-Print Network [OSTI]

derived from biomass. Current research at Texas A&M University is focused on the effectiveness of using cattle manure biomass as a fuel source in conjunction with coal burning utilities. The scope of this project includes fuel property analysis, pyrolysis...

Martin, Brandon Ray

2009-05-15T23:59:59.000Z

319

Theoretical principles of the use of coal fractions with different densities for pyrolysis  

SciTech Connect (OSTI)

To obtain process gas and liquid products upon thermal action on low-grade (D, DG, and G) coals, it is reasonable to pyrolyze the lightest organic fractions with enhanced quality characteristics in terms of both the yield of liquid products (pyrolysis tar) and the component composition of the gas (hydrogen and methane hydrocarbons).

A.M. Gyul'maliev; S.G. Gagarin [Institute for Fossil Fuels, Moscow (Russian Federation)

2009-07-01T23:59:59.000Z

320

Experimental Study on Microwave Pyrolysis of an Indonesian Low-Rank Coal  

Science Journals Connector (OSTI)

Microwave pyrolysis of an Indonesian lignite is investigated in this study. ... About half of the world’s coal reserves are low-rank coals. ... Considerable amts. of 3,4-dihydro-1(2H)-naphthalenone (alpha-tetralone) were found in the oil fractions of lignites treated by microwave energy. ...

Nan Wang; Jianglong Yu; Arash Tahmasebi; Yanna Han; John Lucas; Terry Wall; Yu Jiang

2013-10-14T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Photovoltaic and photoelectrochemical conversion of solar energy  

Science Journals Connector (OSTI)

...multiple carrier generation...renewable energy|solar energy conversion|photovoltaic...photovoltaic energy conversion process...minority carriers in the p-type...efficiency carrier multiplication...for solar energy conversion. Phys...

2007-01-01T23:59:59.000Z

322

Alternative Fuels Data Center: Vehicle Conversions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Conversions Conversions Printable Version Share this resource Send a link to Alternative Fuels Data Center: Vehicle Conversions to someone by E-mail Share Alternative Fuels Data Center: Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center: Vehicle Conversions on AddThis.com... Vehicle Conversions Photo of converted to run on propane. What kinds of conversions are available? Natural Gas Propane Electric Hybrid Ethanol An aftermarket conversion is a vehicle or engine modified to operate using

323

Alternative Fuels Data Center: Propane Vehicle Conversions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Conversions to someone by E-mail Conversions to someone by E-mail Share Alternative Fuels Data Center: Propane Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Propane Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Propane Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Propane Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Propane Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center: Propane Vehicle Conversions on AddThis.com... More in this section... Propane Basics Benefits & Considerations Stations Vehicles Availability Conversions Emissions Laws & Incentives Propane Vehicle Conversions Related Information Conversion Basics Regulations Vehicle conversions provide alternative fuel options beyond what is

324

Chemical Conversions of Natural Precursors  

Science Journals Connector (OSTI)

Many products from the flavour industry are primary products from renewable resources or secondary products obtained by chemical conversions of the primary products. In general these secondary products are key...

Peter H. van der Schaft

2007-01-01T23:59:59.000Z

325

Solar Energy Conversion Efficiency Project  

Science Journals Connector (OSTI)

Report of a discussion on possible collaborative experimentation to test and refine biomass production models based on the conversion of solar energy by plant stands, and to evaluate alternative models.

J. S. Pereira; J. J. Landsberg

1989-01-01T23:59:59.000Z

326

Plasmonic conversion of solar energy  

E-Print Network [OSTI]

Basic Research Needs for Solar Energy Utilization, BasicS. Pillai and M. A. Green, Solar Energy Materials and SolarPlasmonic conversion of solar energy César Clavero Plasma

Clavero, Cesar

2014-01-01T23:59:59.000Z

327

Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas  

DOE Patents [OSTI]

In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

Durai-Swamy, Kandaswamy (Culver City, CA)

1982-01-01T23:59:59.000Z

328

Pyrolysis Autoclave Technology Demonstration Program for Treatment of DOE Solidified Organic Wastes  

SciTech Connect (OSTI)

In the summer of 2005, MSE Technologies Applications, Inc. (MSE) and THOR Treatment Technologies, LLC (TTT) conducted a demonstration test of the Thermal Organic Reduction (THOR{sup sm}) in-drum pyrolysis autoclave system under contract to the Department of Energy. The purpose of the test was to demonstrate that the THOR{sup sm} pyrolysis autoclave system could successfully treat solidified organic waste to remove organics from the waste drums. The target waste was created at Rocky Flats and currently resides at the Radioactive Waste Management Complex (RWMC) at the Idaho National Laboratory (INL). Removing the organics from these drums would allow them to be shipped to the Waste Isolation Pilot Plant for disposal. Two drums of simulated organic setup waste were successfully treated. The simulated waste was virtually identical to the expected waste except for the absence of radioactive components. The simulated waste included carbon tetrachloride, trichloroethylene, perchloroethylene, Texaco Regal oil, and other organics mixed with calcium silicate and Portland cement stabilization agents. The two-stage process consisted of the THOR{sup sm} electrically heated pyrolysis autoclave followed by the MSE off gas treatment system. The treatment resulted in a final waste composition that meets the requirements for WIPP transportation and disposal. There were no detectable volatile organic compounds in the treated solid residues. The destruction and removal efficiency (DRE) for total organics in the two drums ranged from >99.999% to >99.9999%. The operation of the process proved to be easily controllable using the pyrolysis autoclave heaters. Complete treatment of a fully loaded surrogate waste drum including heat-up and cooldown took place over a two-day period. This paper discusses the results of the successful pyrolysis autoclave demonstration testing. (authors)

Roesener, W.S.; Mason, J.B.; Ryan, K. [THOR Treatment Technologies, LLC, 7800 E Union Ave, Denver, CO 80237 (United States); Bryson, S. [MSE Technologies Applications, Inc., 200 Technology Way, Butte, MT 59702 (United States); Eldredge, H.B. [Eldredge Engineering, P.A., 1090 Blue Ridge Dr., Idaho Falls, ID 83402 (United States)

2006-07-01T23:59:59.000Z

329

Energy Conversion Devices | Open Energy Information  

Open Energy Info (EERE)

Jump to: navigation, search Name: Energy Conversion Devices Place: Rochester Hills, MI Website: http:www.energyconversiondev References: Energy Conversion Devices1...

330

Fast reactor safety  

Science Journals Connector (OSTI)

... SIR, - In his article on fast reactor safety (26 July, page 270) Norman Dombey claims to introduce to non-specialists ... , page 270) Norman Dombey claims to introduce to non-specialists some features of fast reactors that are not available outside the technical literature. The non-specialist would do well ...

R.D. SMITH

1979-08-23T23:59:59.000Z

331

Proceedings of the Biomass Pyrolysis Oil Properties and Combustion Meeting, 26-28 September 1994, Estes Park, Colorado  

SciTech Connect (OSTI)

The increasing scale-up of fast pyrolysis in North America and Europe, as well as the exploration and expansion of markets for the energy use of biocrude oils that now needs to take place, suggested that it was timely to convene an international meeting on the properties and combustion behavior of these oils. A common understanding of the state-of-the-art and technical and other challenges which need to be met during the commercialization of biocrude fuel use, can be achieved. The technical issues and understanding of combustion of these oils are rapidly being advanced through R&D in the United States. Canada, Europe and Scandinavia. It is obvious that for the maximum economic impact of biocrude, it will be necessary to have a common set of specifications so that oils can be used interchangeably with engines and combustors which require minimal modification to use these renewable fuels. Fundamental and applied studies being pursued in several countries are brought together in this workshop so that we can arrive at common strategies. In this way, both the science and the commercialization are advanced to the benefit of all, without detracting from the competitive development of both the technology and its applications. This United States-Canada-Finland collaboration has led to the two and one half day specialists meeting at which the technical basis for advances in biocrude development is discussed. The goal is to arrive at a common agenda on issues that cross national boundaries in this area. Examples of agenda items are combustion phenomena, the behavior of trace components of the oil (N, alkali metals), the formation of NOx in combustion, the need for common standards and environmental safety and health issues in the handling, storage and transportation of biocrudes.

Milne, T.

1995-01-01T23:59:59.000Z

332

The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol  

Science Journals Connector (OSTI)

...The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol G. R. Freeman The two modes of decomposition of ethanol at 525 degrees C, namely dehydration and dehydrogenation, are affected...

1958-01-01T23:59:59.000Z

333

Thermochemical Analysis of U.S. Argonne Premium Coal Samples by Time-Resolved Pyrolysis-Field ionization Mass Spectrometry  

Science Journals Connector (OSTI)

Analytical pyrolysis techniques are widely used for the thermochemical analysis of coals and coal-derived products. During heating, complex mixtures of chemical substances are released from coal by distillatio...

Norbert Simmleit; Hans-Rolf Schulten; Yongseung Yun…

1992-01-01T23:59:59.000Z

334

Feedstock Logistics of a Mobile Pyrolysis System and Assessment of Soil Loss Due to Biomass Removal for Bioenergy Production  

E-Print Network [OSTI]

The purpose of this study was to assess feedstock logistics for a mobile pyrolysis system and to quantify the amount of soil loss caused by harvesting agricultural feedstocks for bioenergy production. The analysis of feedstock logistics...

Bumguardner, Marisa

2012-10-19T23:59:59.000Z

335

Review and analysis of the 1980-1989 biomass thermochemical conversion program  

SciTech Connect (OSTI)

In the period between 1980 and 1989, the U.S. Department of Energy (DOE) sponsored research and development projects through its Biomass Thermochemical Conversion (BTC) Program. Thermochemical conversion technologies use elevated temperatures to convert biomass into more useful forms of energy such as fuel gases or transportation fuels. The BTC Program included a wide range of biomass conversion projects in the areas of gasification, pyrolysis, liquefaction, and combustion. This work formed the basis of the present DOE research and development efforts on advanced liquid fuel and power generation systems. At the beginning of Fiscal Year 1989, the management of the BTC Program was transferred from Pacific Northwest Laboratory (PNL) to National Renewable Energy Laboratory (NREL, formerly Solar Energy Research Institute). This document presents a summary of the research which was performed under the BTC Program during the 1981-1989 time frame. The document consists of an analysis of the research projects which were funded by the BTC Program and a bibliography of published documents. This work will help ensure that information from PNL`s BTC Program is available to those interested in biomass conversion technologies. The background of the BTC Program is discussed in the first chapter of this report. In addition, a brief summary of other related biomass research and development programs funded by the U.S. Department of Energy and others is presented with references where additional information can be found. The remaining chapters of the report present a detailed summary of the research projects which were funded by the BTC Program. The progress which was made on each project is summarized, the overall impact on biomass conversion is discussed, and selected references are provided.

Stevens, D.J.

1994-09-01T23:59:59.000Z

336

Conversion Electrons of Radium D  

Science Journals Connector (OSTI)

The conversion electrons of radium D have been studied with thin sources on thin backings in a beta-ray spectrograph using calibrated photographic emulsions. The number of conversion electrons due to the 47-kev gamma-ray has been measured to be 74±5 per hundred disintegrations. The L:M:N ratio is 1:0.26:0.077. This implies a complex decay scheme for radium D, since earlier results give 3.5 unconverted 47-kev gamma-rays per hundred disintegrations.

Lawrence Cranberg

1950-01-15T23:59:59.000Z

337

Recirculation in multiple wave conversions  

SciTech Connect (OSTI)

A one-dimensional multiple wave-conversion model is constructed that allows energy recirculation in ray phase space. Using a modular eikonal approach, the connection coefficients for this model are calculated by ray phase-space methods. Analytical results (confirmed numerically) show that all connection coefficients exhibit interference effects that depend on an interference phase, calculated from the coupling constants and the area enclosed by the intersecting rays. This conceptual model, which focuses on the topology of intersecting rays in phase space, is used to investigate how mode conversion between primary and secondary waves is modified by the presence of a tertiary wave.

Kaufman, A. N.; Brizard, A.J.; Kaufman, A.N.; Tracy, E.R.

2008-07-30T23:59:59.000Z

338

Effect of the Temperature on the Composition of Lignin Pyrolysis Products  

Science Journals Connector (OSTI)

Bioenergy Research Group, Aston University, Birmingham B4 7ET, United Kingdom ... There is a lack of quantitative information on the temperature dependence of the interesting phenolic compounds in the literature, which is important for converting lignin into value-added aromatic compounds through the pyrolysis route. ... The maximum temperature for the PyGC?MS study was set at 800 °C after reviewing the yield of phenolic compounds, which peaked around 600 °C. ...

Guozhan Jiang; Daniel J. Nowakowski; Anthony V. Bridgwater

2010-07-21T23:59:59.000Z

339

The kerogen types and pyrolysis kinetics of several Chinese carbonate source rocks  

SciTech Connect (OSTI)

The kerogen types and pyrolysis kinetics of several Chinese carbonate source rocks are studied in this paper. Samples involved are from Proterozoic to Neogene, including marine and lacustrine environments. Their TOC range from 0.15% to 1.69%. The carbonate contents are more than 80% except the Paleozoic Pingliang marl, Shanganning Basin. The maturations range from immature to late stage of oil generation. The Green River calcareous shale and Ghareb marl, Jordan are included for comparison. The study of kerogen types is based on analyses of kerogens including: optical method, elemental analysis, infrared spectrum, rock eval pyrolysis, pyrolysis-gas chromatography, and C-13 Nuclear Magnetic Resonance Spectrometry. The results of the study shows that most of the kerogens studied belong to type 1 or sapropelic type 2 (2a), while the kerogens from Triassic Qinglong limestone (restricted by), Jiangsu and Neogene Guantao limestone (small fault lacustrine), Shandong belong to mixed type 2 (2b). The study of pyrolysis kinetics is based on standard Rock Eval information (5 C/min.), a two-stage first order reaction model and optimization method which has been confirmed to be a simple, practical and effective method by a previous study. The current study reveals that different kerogen types have their own kinetic characteristics. Generally, kinetics parameters of type 1 and type 2a kerogens are greater than those of type 2b. However, high-sulfur type 1 and type 2a kerogens, such as those from Ghareb marl, Jordan, and Proterozoic kerogen, North China have relatively low kinetics parameters. The study also shows that kerogens with similar hydrocarbon potential (HI) and elemental composition (atomic H/C, O/C) may have very different kinetic processes.

Zhang, Youcheng (Texas A and M Univ., College Station, TX (United States). Dept. of Oceanography); Shisheng Hao (Petroleum Univ., Beijing (China). Dept. of Geosciences)

1992-01-01T23:59:59.000Z

340

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel  

Science Journals Connector (OSTI)

Initiation Mechanisms and Kinetics of Pyrolysis and Combustion of JP-10 Hydrocarbon Jet Fuel ... We found that the primary decomposition reactions involve either (1) dissociation of ethylene from JP-10, resulting in the formation of a C8 hydrocarbon intermediate, or (2) the production of two C5 hydrocarbons. ... Heats of combustion (kcal/mole) were measured via O bomb calorimetry; adamantane (I) (c), -1441.95 ...

Kimberly Chenoweth; Adri C. T. van Duin; Siddharth Dasgupta; William A. Goddard III

2009-02-11T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Effect of pretreatment and additives on boron release during pyrolysis and gasification of coal  

SciTech Connect (OSTI)

Boron is one of the most toxic and highly volatile elements present in coal. As part of a series of studies carried out on coal cleaning to prevent environmental problems and to promote efficient coal utilization processes, the removal of boron by leaching with water and acetic acid has been investigated. The effects of the addition of ash components, that is, SiO{sub 2}, Al{sub 2}O{sub 3}, and CaO on the control of boron release during pyrolysis and gasification were investigated. Here, 20-70% of boron in coal was removed by leaching the coal with water and acetic acid. Boron leached by water and acetic acid was related to the volatiles released from coal in pyrolysis below 1173 K. The addition of ash components such as SiO{sub 2} and Al{sub 2}O{sub 3} was found to be effective in suppressing the release of boron during pyrolysis at temperatures below and above 1173 K, respectively. The addition of CaO to coal was effective in suppressing the release of boron during gasification at 1173 K. 26 refs., 7 figs., 3 tabs.

Yuuki Mochizuki; Katsuyasu Sugawara; Yukio Enda [Akita University, Akita (Japan). Faculty of Engineering and Resources Science

2009-09-15T23:59:59.000Z

342

Co-pyrolysis of oil shale and High density polyethylene: Structural characterization of the oil  

Science Journals Connector (OSTI)

This study describes a detailed characterization of the oil obtained by co-pyrolysis of Tarfaya oil shale (Morocco) and high density polyethylene (HDPE) and by pyrolysis of oil shale and HDPE individually. The oil (obtained under the most suitable conditions, temperature of 500–525 °C and heating rate of 10 °C/min) was characterised by elemental analysis, nuclear magnetic resonance spectroscopy (1H NMR) and Fourier transform infrared spectroscopy (FTIR). In addition, column chromatography was used group composition of oil was determined. Gas chromatography was achieved on n-hexane fractions. Adding HDPE to the oil shale results in increased oil yields, which indicates synergetic effect between the oil shale and HDPE. The addition of HDPE to oil shale improved fuel properties of shale oil leading to a decrease in the oxygen content of shale oil. The results show that the oil obtained by co-pyrolysis has similar properties with commercial gasoline. HDPE acts as a hydrogenation medium for the oil shale product as revealed by FTIR results.

A. Aboulkas; T. Makayssi; L. Bilali; K. El harfi; M. Nadifiyine; M. Benchanaa

2012-01-01T23:59:59.000Z

343

Fabrication of ZnO nanorod using spray-pyrolysis and chemical bath deposition method  

SciTech Connect (OSTI)

ZnO thin films with nanorod structure were deposited using Ultrasonic Spray Pyrolysis method for seed growth, and Chemical Bath Deposition (CBD) for nanorod growth. High purity Zn-hydrate and Urea are used to control Ph were dissolved in ethanol and aqua bidest in Ultrasonic Spray Pyrolysis process. Glass substrate was placed above the heater plate of reaction chamber, and subsequently sprayed with the range duration of 5, 10 and 20 minutes at the temperatures of 3500 C. As for the Chemical Bath Deposition, the glass substrate with ZnO seed on the surface was immerse to Zn-hydrate, HMTA (Hexa Methylene Tetra Amine) and deionized water solution for duration of 3, 5 and 7 hour and temperatures of 600 C, washed in distilled water, dried, and annealed at 3500 C for an hour. The characterization of samples was carried out to reveal the surface morphology using Scanning Electron Microscopy (SEM). From the data, the combination of 5 minutes of Ultrasonic Spray Pyrolysis process and 3 hour of CBD has showed the best structure of nanorod. Meanwhile the longer Spraying process and CBD yield the bigger nanorod structure that have been made, and it makes the films more dense which make the nanorod collide each other and as a result produce unsymetric nanorod structure.

Ramadhani, Muhammad F., E-mail: brian@tf.itb.ac.id; Pasaribu, Maruli A. H., E-mail: brian@tf.itb.ac.id; Yuliarto, Brian, E-mail: brian@tf.itb.ac.id; Nugraha, E-mail: brian@tf.itb.ac.id [Advanced Functional Materials Laboratory, Engineering Physics Department Faculty of Industrial Technology, Institut Teknologi Bandung (Indonesia)

2014-02-24T23:59:59.000Z

344

MUTUAL CONVERSION SOLAR AND SIDEREAL  

E-Print Network [OSTI]

TABLES FOR THE MUTUAL CONVERSION OF SOLAR AND SIDEREAL TIME BY EDWARD SANG, F.R.S.E. EDINBURGH in the third example. Sang converts 3.27 seconds of solar time into 3.26 seconds of sidereal time. But sidereal time elapses faster than solar time, and the correct value is 3.28 sec- onds. In the fourth example

Roegel, Denis

345

HELIOPHYSICS II. ENERGY CONVERSION PROCESSES  

E-Print Network [OSTI]

of a solar flare 11 2.3.1 Flare luminosity and mechanical energy 11 2.3.2 The impulsive phase (hard X with the term "solar flare" dominate our thinking about energy conversion from magnetic storage to other forms approaches to the problems involved in phys- ically characterizing the solar atmosphere; see also the lecture

Hudson, Hugh

346

The potential of pyrolysis technology in climate change mitigation – influence of process design and –parameters, simulated in SuperPro Designer Software.  

E-Print Network [OSTI]

??This report investigates whether or not it would be possible to produce carbon-negative energy from pyrolysis of wheat straw in a series of Danish agricultural… (more)

Ahrenfeldt, Jesper

2011-01-01T23:59:59.000Z

347

Chuaria circularis from the early Mesoproterozoic Suket Shale, Vindhyan Supergroup, India: Insights from light and electron microscopy and pyrolysis-gas chromatography  

Science Journals Connector (OSTI)

Chuaria circularis (Walcott 1899) from the Suket Shale of the Vindhyan Supergroup (central India) ... composition using biostatistics, electron microscopy and pyrolysis-gas chromatography. Morpho...

Suryendu Dutta; Michael Steiner; Santanu Banerjee…

2006-02-01T23:59:59.000Z

348

Alternative Fuels Data Center: Vehicle Conversion Basics  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Vehicle Conversion Vehicle Conversion Basics to someone by E-mail Share Alternative Fuels Data Center: Vehicle Conversion Basics on Facebook Tweet about Alternative Fuels Data Center: Vehicle Conversion Basics on Twitter Bookmark Alternative Fuels Data Center: Vehicle Conversion Basics on Google Bookmark Alternative Fuels Data Center: Vehicle Conversion Basics on Delicious Rank Alternative Fuels Data Center: Vehicle Conversion Basics on Digg Find More places to share Alternative Fuels Data Center: Vehicle Conversion Basics on AddThis.com... Vehicle Conversion Basics Photo of a Ford Transit Connect converted to run on compressed natural gas. A Ford Transit Connect converted to run on compressed natural gas. A converted vehicle or engine is one modified to use a different fuel or

349

Photovoltaic and photoelectrochemical conversion of solar energy  

Science Journals Connector (OSTI)

...photoelectrochemical conversion of solar energy Michael Gratzel * * ( michael...industry, have dominated photovoltaic solar energy converters. These systems have...promising perspectives. renewable energy|solar energy conversion|photovoltaic...

2007-01-01T23:59:59.000Z

350

Grounded Situation Models for Situated Conversational Assistants  

E-Print Network [OSTI]

A Situated Conversational Assistant (SCA) is a system with sensing, acting and speech synthesis/recognition abilities, which engages in physically situated natural language conversation with human partners and assists them ...

Mavridis, Nikolaos

2007-01-01T23:59:59.000Z

351

Biofuel Conversion Basics | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Biofuel Conversion Basics Biofuel Conversion Basics Biofuel Conversion Basics August 14, 2013 - 12:31pm Addthis The conversion of biomass solids into liquid or gaseous biofuels is a complex process. Today, the most common conversion processes are biochemical- and thermochemical-based. However, researchers are also exploring photobiological conversion processes. Biochemical Conversion Processes In biochemical conversion processes, enzymes and microorganisms are used as biocatalysts to convert biomass or biomass-derived compounds into desirable products. Cellulase and hemicellulase enzymes break down the carbohydrate fractions of biomass to five- and six-carbon sugars in a process known as hydrolysis. Yeast and bacteria then ferment the sugars into products such as ethanol. Biotechnology advances are expected to lead to dramatic

352

Photochemical conversion and storage of solar energy  

Science Journals Connector (OSTI)

Photochemical conversion and storage of solar energy ... In this article, the author considers the use of inorganic photochemical reactions for the conversion and storage of solar energy. ... HOMO?LUMO energy difference values compared ... ...

Charles Kutal

1983-01-01T23:59:59.000Z

353

The National Conversion Pilot Project  

SciTech Connect (OSTI)

The National Conversion Pilot Project (NCPP) is a recycling project under way at the U.S. Department of Energy (DOE) Rocky Flats Environmental Technology Site (RFETS) in Colorado. The recycling aim of the project is threefold: to reuse existing nuclear weapon component production facilities for the production of commercially marketable products, to reuse existing material (uranium, beryllium, and radioactively contaminated scrap metals) for the production of these products, and to reemploy former Rocky Flats workers in this process.

Roberts, A.V. [BNFL, Inc., Golden, CO (United States)

1995-12-31T23:59:59.000Z

354

Methanol conversion to higher hydrocarbons  

SciTech Connect (OSTI)

Several indirect options exist for producing chemicals and transportation fuels from coal, natural gas, or biomass. All involve an initial conversion step to synthesis gas (CO and H{sub 2}). Presently, there are two commercial technologies for converting syngas to liquids: Fischer-Tropsch, which yields a range of aliphatic hydrocarbons with molecular weights determined by Schulz-Flory kinetics, and methanol synthesis. Mobil`s diversity of technology for methanol conversion gives the methanol synthesis route flexibility for production of either gasoline, distillate or chemicals. Mobil`s ZSM-5 catalyst is the key in several processes for producing chemicals and transportation fuels from methanol: MTO for light olefins, MTG for gasoline, MOGD for distillates. The MTG process has been commercialized in New Zealand since 1985, producing one-third of the country`s gasoline supply, while MTO and MOGD have been developed and demonstrated at greater than 100 BPD scale. This paper will discuss recent work in understanding methanol conversion chemistry and the various options for its use.

Tabak, S.A. [Mobil Research and Development Corp., Princeton, NJ (United States). Central Research Lab.

1994-12-31T23:59:59.000Z

355

Optimization of direct conversion of wet algae to biodiesel under supercritical methanol conditions  

Science Journals Connector (OSTI)

This study demonstrated a one-step process for direct liquefaction and conversion of wet algal biomass containing about 90% of water to biodiesel under supercritical methanol conditions. This one-step process enables simultaneous extraction and transesterification of wet algal biomass. The process conditions are milder than those required for pyrolysis and prevent the formation of by-products. In the proposed process, fatty acid methyl esters (FAMEs) can be produced from polar phospholipids, free fatty acids, and triglycerides. A response surface methodology (RSM) was used to analyze the influence of the three process variables, namely, the wet algae to methanol (wt./vol.) ratio, the reaction temperature, and the reaction time, on the \\{FAMEs\\} conversion. Algal biodiesel samples were analyzed by ATR-FTIR and GC–MS. Based on the experimental analysis and RSM study, optimal conditions for this process are reported as: wet algae to methanol (wt./vol.) ratio of around 1:9, reaction temperature and time of about 255 °C, and 25 min respectively. This single-step process can potentially be an energy efficient and economical route for algal biodiesel production.

Prafulla D. Patil; Veera Gnaneswar Gude; Aravind Mannarswamy; Shuguang Deng; Peter Cooke; Stuart Munson-McGee; Isaac Rhodes; Pete Lammers; Nagamany Nirmalakhandan

2011-01-01T23:59:59.000Z

356

Ocean Thermal Energy Conversion LUIS A. VEGA  

E-Print Network [OSTI]

Ocean Thermal Energy Conversion LUIS A. VEGA Hawaii Natural Energy Institute, School of Ocean depths of 20 m (surface water) and 1,000 m. OTEC Ocean Thermal Energy Conversion, the process Energy Conversion. At first, OTEC plantships providing electricity, via submarine power cables, to shore

357

3. Energy conversion, balances, efficiency, equilibrium  

E-Print Network [OSTI]

1/124 3. Energy conversion, balances, efficiency, equilibrium (Introduction to Thermodynamics) Ron h�dm, h = u + p/ Picture: SEHB06 56/124 3.5: Energy balances; Conversion work work, work heat 96/124 Energy conversion heat work /1 "the essential rules" Picture:IO06 #12;97/124 Energy

Zevenhoven, Ron

358

Energy Conversion Technologies 1.0 Introduction  

E-Print Network [OSTI]

1 Energy Conversion Technologies 1.0 Introduction In these notes, we describe the infrastructure. By "energy conversion," we mean the conversion of energy into some form of electric energy. By "available now that is available to be considered in the generation and planning functions. We classify this information by Energy

McCalley, James D.

359

GUIDED ANGLER FISH ANNUAL CONVERSION FACTORS  

E-Print Network [OSTI]

GUIDED ANGLER FISH ANNUAL CONVERSION FACTORS FOR THE 2014 FISHING YEAR NOAA FISHERIES, ALASKA via the GAF electronic reporting system. If no GAF were harvested in a year, the conversion factor is the first calendar year that GAF regulations will be in effect. Therefore, the conversion factors are based

360

Ionic Liquids as Solvents for Catalytic Conversion of Lignocellulosic Feedstocks  

E-Print Network [OSTI]

to the development of biomass conversion technologies, it isefficient and selective biomass conversion technologies is athe conversion of both carbohydrate components of biomass.

Dee, Sean Joseph

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

OCEAN THERMAL ENERGY CONVERSION: AN OVERALL ENVIRONMENTAL ASSESSMENT  

E-Print Network [OSTI]

1980. Ocean Thermal Energy Conversion Draft ProgrammaticPlan. Ocean Thermal Energy Conversion. U.S. DOE Assistantl OCEAN THERMAL ENERGY CONVERSION: ENVIRONMENTAL ASSESSMENT

Sands, M.Dale

2013-01-01T23:59:59.000Z

362

Semiconductor nanowires for photovoltaic and photoelectrochemical energy conversion  

E-Print Network [OSTI]

cost and improve the energy conversion efficiency, to enableefficiency solar energy conversion devices. AcknowledgementsPhotoelectrochemical Energy Conversion Neil P. Dasgupta and

Dasgupta, Neil

2014-01-01T23:59:59.000Z

363

Explorations of Novel Energy Conversion and Storage Systems  

E-Print Network [OSTI]

of Steady-State Energy Conversion. Applied ScientificElectrokinetic energy conversion efficiency in nanofluidicElectrokinetic energy conversion efficiency in nanofluidic

Duffin, Andrew Mark

2010-01-01T23:59:59.000Z

364

OCEAN THERMAL ENERGY CONVERSION (OTEC) PROGRAMMATIC ENVIRONMENTAL ANALYSIS  

E-Print Network [OSTI]

of ocean thermal energy conversion technology. U.S. DOE.ocean thermal energy conversion. A preliminary engineeringCompany. Ocean thermal energy conversion mission analysis

Sands, M. D.

2011-01-01T23:59:59.000Z

365

ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion (OTEC) plants byFifth Ocean Thermal Energy Conversion Conference, February1980. Ocean thermal energy conversion (OTEC) pilot plant

Sullivan, S.M.

2014-01-01T23:59:59.000Z

366

DRAFT. ENVIRONMENTAL ASSESSMENT OCEAN THERMAL ENERGY CONVERSION (OTEC) PILOT PLANTS  

E-Print Network [OSTI]

Commercial ocean thermal energy conversion ( OTEC) plants byfield of ocean thermal energy conversion discharges. I~. L.Sixth Ocean Thermal Energy conversion Conference. June 19-

Sullivan, S.M.

2014-01-01T23:59:59.000Z

367

Recycling of wasted energy : thermal to electrical energy conversion  

E-Print Network [OSTI]

Nanoporous Thermal-to-Electrical Energy Conversion System (of Wasted Energy : Thermal to Electrical Energy Conversion AArticles: 1. “ Thermal to electrical energy conversion” , Yu

Lim, Hyuck

2011-01-01T23:59:59.000Z

368

Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization Fourier  

E-Print Network [OSTI]

with greater than 1% relative abundance in either phase are shown. Pyrolysis of solid biomass, in this case: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization of nitrogen-containing species identified in the peanut hull pyrolysis oil by FT-ICR mass spectrometry

Weston, Ken

369

2008 Guidelines to Defra's GHG Conversion Factors Guidelines to Defra's GHG Conversion Factors  

E-Print Network [OSTI]

with the standard conversion factors at Annex 1. If, however, you export energy or heat to another business (or2008 Guidelines to Defra's GHG Conversion Factors 2008 Guidelines to Defra's GHG Conversion Factors yellow = Calculation results Page 1 of 15 #12;2008 Guidelines to Defra's GHG Conversion Factors Annex 1

370

Fabrication of hydrophobic, electrically conductive and flame-resistant carbon aerogels by pyrolysis of regenerated cellulose aerogels  

Science Journals Connector (OSTI)

Abstract In this paper, we reported miscellaneous carbon aerogels prepared by pyrolysis of regenerated cellulose aerogels that were fabricated by dissolution in a mild NaOH/PEG solution, freeze ? thaw treatment, regeneration, and freeze drying. The as-prepared carbon aerogels were subsequently characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), nitrogen adsorption measurements, X-ray diffraction (XRD), Raman spectroscopy, and water contact angle (WCA) tests. The results showed that the carbon aerogels with pore diameters of 1 ? 60 nm maintained interconnected three-dimensional (3D) network after the pyrolysis, and showed type ? IV adsorption isotherm. The pyrolysis process leaded to the decomposition of oxygen-containing functional groups, the destruction of cellulose crystalline structure, and the formation of highly disordered amorphous graphite. Moreover, the carbon aerogels also had strong hydrophobicity, electrical conductivity and flame retardance, which held great potential in the fields of waterproof, electronic devices and fireproofing.

Caichao Wan; Yun Lu; Yue Jiao; Chunde Jin; Qingfeng Sun; Jian Li

2014-01-01T23:59:59.000Z

371

NREL: Biomass Research - Biochemical Conversion Capabilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biochemical Conversion Capabilities Biochemical Conversion Capabilities NREL researchers are working to improve the efficiency and economics of the biochemical conversion process by focusing on the most challenging steps in the process. Biochemical conversion of biomass to biofuels involves three basic steps: Converting biomass to sugar or other fermentation feedstock through: Pretreatment Conditioning and enzymatic hydrolysis Enzyme development. Fermenting these biomass-derived feedstocks using: Microorganisms for fermentation. Processing the fermentation product to produce fuel-grade ethanol and other fuels, chemicals, heat, and electricity by: Integrating the bioprocess. Get the Adobe Flash Player to see this video. This video is a narrated animation that explains the biochemical conversion

372

VUV photoionization time-of-flight mass spectrometry of flash pyrolysis of silane and disilane  

Science Journals Connector (OSTI)

Flash pyrolysis of silane, SiH4, and disilane, Si2H6, diluted in He or Ar (1%), was carried out at temperatures ranging from ?700 to ?1500 K. After a short reaction time of ?20 ?s, the initial products were isolated in a supersonic molecular beam and detected by single vacuum ultra-violet (VUV) photon (?=118 or 121 nm) ionization time-of-flight mass spectrometry (TOFMS). Initial decomposition and reaction products, both free radical intermediates and stable species, were directly observed, which included SiH2 and Si2H4.

Steven D. Chambreau; Jingsong Zhang

2001-01-01T23:59:59.000Z

373

Upgrading of heavy oil from the San Joaquin valley of California by aqueous pyrolysis  

SciTech Connect (OSTI)

Midway Sunset crude oil and well-head oil were treated at elevated temperatures in a closed system with the presence of water. Mild to moderate upgrading, as measured by increasing in API gravity, was observed at 400 C or above. Reduced pressure operation exhibited upgrading activity comparable to upgrading under normal aqueous pyrolysis conditions. Reduced pressure operation was obtained by the use of specific blending methods, a surfactant, and the proper amount of water. The use of metal complexes provided additional upgrading. The best of the minimum set tested was Co(II) 2-ethylhexanoate. Fe, Zn, Mo, Cu, and Ni complexes also showed some levels of activity.

Reynolds, J.G.; Murray, A.M.; Nuxoll, E.V.; Fox, G.A.; Thorsness, C.B. [Lawrence Livermore National Lab., CA (United States); Khan, M.R. [Texaco R and D, Beacon, NY (United States)

1997-08-01T23:59:59.000Z

374

Transparent and conducting ZnO films grown by spray pyrolysis  

Science Journals Connector (OSTI)

ZnO films were prepared using the simple, flexible and cost-effective spray pyrolysis technique at different substrate temperatures and precursor molarity values. The films' structural, optical and electrical properties were investigated by x-ray diffraction, UV–VIS transmittance spectroscopy, profilometry and voltage–current–temperature (VIT) measurements. The films prepared at substrate temperatures above 400 °C appear better crystallized with (0?0?2) preferred orientation and exhibit higher visible transmittance (65–80%), higher electrical n-type semiconductor conductivity (10–50 (? cm)?1), lower activation energy (

Lazhar Hadjeris; Labidi Herissi; M Badreddine Assouar; Thomas Easwarakhanthan; Jamal Bougdira; Nadhir Attaf; M Salah Aida

2009-01-01T23:59:59.000Z

375

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents [OSTI]

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

376

MATLAB tensor classes for fast algorithm prototyping.  

SciTech Connect (OSTI)

Tensors (also known as mutidimensional arrays or N-way arrays) are used in a variety of applications ranging from chemometrics to psychometrics. We describe four MATLAB classes for tensor manipulations that can be used for fast algorithm prototyping. The tensor class extends the functionality of MATLAB's multidimensional arrays by supporting additional operations such as tensor multiplication. The tensor as matrix class supports the 'matricization' of a tensor, i.e., the conversion of a tensor to a matrix (and vice versa), a commonly used operation in many algorithms. Two additional classes represent tensors stored in decomposed formats: cp tensor and tucker tensor. We descibe all of these classes and then demonstrate their use by showing how to implement several tensor algorithms that have appeared in the literature.

Bader, Brett William; Kolda, Tamara Gibson (Sandia National Laboratories, Livermore, CA)

2004-10-01T23:59:59.000Z

377

Multiscale molecular modeling can be an effective tool to aid the development of biomass conversion technology: A perspective  

Science Journals Connector (OSTI)

Abstract Lignocellulosic biomass is an alternate and renewable source of carbon. However, due to high oxygen content and diverse functionality, its conversion to fuels and chemicals is technologically challenging. Since physico-chemical characteristics of biomass and its derived components are very different from petroleum, fundamental understanding of their interactions with catalysts and solvents and of their behavior during thermochemical processing needs to be developed. In the present paper, we provide a perspective on how multiscale molecular modeling can assist in developing the science of biomass processing. The scope of this paper is limited to liquid phase catalytic and pyrolytic conversion of biomass. Car–Parrinello molecular dynamics (CPMD), a multiscale method that combines quantum mechanics and classical molecular dynamics and is an excellent choice to simulate biomass interactions in the condensed phase, is discussed. An overview of metadynamics, a method to accelerate CPMD dynamics, is also given. Revealing the chemistry of biomass pyrolysis, identifying liquid phase catalytic reaction mechanisms and developing a fundamental understanding of the role of solvents in biomass processing are the three main areas highlighted in this paper. Molecular modeling based investigations in these areas are reviewed and key findings are summarized. Limitations of the current approaches are discussed and the relevance of multiscale methods like CPMD and metadynamics is discussed. Potential studies that could implement multiscale molecular modeling methods to solve some of the challenging problems in developing biomass conversion technology are elaborated and an outlook is provided.

Samir H. Mushrif; Vallabh Vasudevan; Chethana B. Krishnamurthy; Boddu Venkatesh

2015-01-01T23:59:59.000Z

378

2011 Biomass Program Platform Peer Review: Thermochemical Conversion...  

Broader source: Energy.gov (indexed) [DOE]

Thermochemical Conversion 2011 Biomass Program Platform Peer Review: Thermochemical Conversion "This document summarizes the recommendations and evaluations provided by an...

379

Electrochemical Conversion of Oxide Precursors to Consolidated Zr and Zr?2.5Nb Tubes  

Science Journals Connector (OSTI)

Electrochemical Conversion of Oxide Precursors to Consolidated Zr and Zr?2.5Nb ... Electrochemical reduction of tubular oxide precursors in molten calcium chloride and the subsequent in situ consolidation induced by electro-deoxygenation promise a low energy and fast route for manufacturing of zirconium-alloy-based artifacts, such as the nuclear fuel cladding tubes. ... Zircaloy) in a mold of Plaster of Paris. ...

Junjun Peng; Kai Jiang; Wei Xiao; Dihua Wang; Xianbo Jin; George Z. Chen

2008-11-11T23:59:59.000Z

380

Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds  

DOE Patents [OSTI]

A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

Khan, M. Rashid (Morgantown, WV)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint  

DOE Patents [OSTI]

A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350 and 375 C to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan. 2 figs.

Moens, L.

1995-07-11T23:59:59.000Z

382

A study of the pyrolysis behaviors of pelletized recovered municipal solid waste fuels  

Science Journals Connector (OSTI)

Pelletized recovered solid waste fuel is often applied in gasification systems to provide feedstock with a stabilized quality and high heating value and to avoid the bridging behavior caused by high moisture content, low particle density, and irregular particle size. However, the swelling properties and the sticky material generated from pyrolysis of the plastic group components also tend to trigger bridging in the retorting zone. It is well known that the plastic group materials, which occupy a considerable proportion of municipal solid waste, can melt together easily even under low temperature. This study investigates the pyrolysis behaviors of typical recovered solid waste pellets, including the devolatilization rate, heat transfer properties, char properties, and swelling/shrinkage properties, in a small fixed-bed facility over a wide temperature range, from 900 °C to 450 °C. The results are also compared with those from wheat straw pellets, a typical cellulosic fuel. Moreover, the SEM images and BET analysis of the char structure are further analyzed to provide additional explanation for the mechanisms of swelling/shrinkage phenomena observed during heating.

Chunguang Zhou; Qinglin Zhang; Leonie Arnold; Weihong Yang; Wlodzimierz Blasiak

2013-01-01T23:59:59.000Z

383

Process and economic model of in-field heavy oil upgrading using aqueous pyrolysis  

SciTech Connect (OSTI)

A process and economic model for aqueous pyrolysis in-field upgrading of heavy oil has been developed. The model has been constructed using the ASPEN PLUS chemical process simulator. The process features cracking of heavy oil at moderate temperatures in the presence of water to increase oil quality and thus the value of the oil. Calculations with the model indicate that for a 464 Mg/day (3,000 bbl/day) process, which increases the oil API gravity of the processed oil from 13.5{degree} to 22.4{degree}, the required value increase of the oil would need to be at least $2.80/Mg{center_dot}{degree}API($0.40/bbl{center_dot}{degree}API) to make the process economically attractive. This level of upgrading has been demonstrated in preliminary experiments with candidate catalysts. For improved catalysts capable of having the coke make and increasing the pyrolysis rate, a required price increase for the oil as low as $1.34/Mg{center_dot}{degree}API ($0.21/bbl{center_dot}{degree}API)has been calculated.

Thorsness, C. B., LLNL

1997-01-21T23:59:59.000Z

384

Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint  

DOE Patents [OSTI]

A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

Moens, Luc (Lakewood, CO)

1995-01-01T23:59:59.000Z

385

Energy Calculator- Common Units and Conversions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy Calculator - Common Units and Conversions Energy Calculator - Common Units and Conversions Calculators for Energy Used in the United States: Coal Electricity Natural Gas Crude Oil Gasoline Diesel & Heating Oil Coal Conversion Calculator Short Tons Btu Megajoules Metric Tons Clear Calculate 1 Short Ton = 20,169,000 Btu (based on U.S. consumption, 2007) Electricity Conversion Calculator KilowattHours Btu Megajoules million Calories Clear Calculate 1 KilowattHour = 3,412 Btu Natural Gas Conversion Calculator Cubic Feet Btu Megajoules Cubic Meters Clear Calculate 1 Cubic Foot = 1,028 Btu (based on U.S. consumption, 2007); 1 therm = 100,000 Btu; 1 terajoule = 1,000,000 megajoules Crude Oil Conversion Calculator Barrels Btu Megajoules Metric Tons* Clear Calculate 1 Barrel = 42 U.S. gallons = 5,800,000 Btu (based on U.S. consumption,

386

Documents: DUF6 Conversion EIS Supporting Documents  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DUF6 Conversion EIS DUF6 Conversion EIS Search Documents: Search PDF Documents View a list of all documents NEPA Compliance: DUF6 Conversion EIS Supporting Documents PDF Icon Notice of Change in National Environmental Policy Act (NEPA) Compliance Approach for the Depleted Uranium Hexafluoride (DUF6) Conversion Facilities Project 38 KB details PDF Icon Press Release: DOE Seeks Public Input for Depleted Uranium Hexafluoride Environmental Impact Statement 90 KB details PDF Icon Advance Notice of Intent To Prepare an Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities 52 KB details PDF Icon Notice of Intent to Prepare an Environmental Impact Statement for Depleted Uranium Hexafluoride Conversion Facilities 60 KB details PDF Icon Overview: Depleted Uranium Hexafluoride (DUF6) Management Program

387

DUF6 Conversion Facility EIS Alternatives  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alternatives Alternatives Depleted UF6 Conversion Facility EIS Alternatives Alternatives included in the Depleted UF6 Conversion Facility EISs. Proposed Action The proposed action evaluated in each EIS is to construct and operate a conversion facility at each site for conversion of the DOE DUF6 inventory. The time period considered is a construction period of approximately 2 years, an operational period of 25 years at Paducah and 18 years at Portsmouth, and the decontamination and decommissioning (D&D) of the facility of about 3 years. The EISs assess the potential environmental impacts from the following proposed activities: Construction, operation, maintenance, and D&D of the proposed DUF6 conversion facility at each site; Transportation of uranium conversion products and waste materials to a disposal facility;

388

Boron neutron capture enhancement of fast neutron radiotherapy  

Science Journals Connector (OSTI)

Clinical trials have revealed a therapeutic advantage for fast neutron radiation over conventional photon radiation for salivary gland cancer prostate cancer sarcoma and a subgroup of lung cancer. Conversely fast neutron treatment of high grade astrocytic brain tumors [glioblastoma multiforme (GBM)] resulted in tumor sterilization but also caused significant brain injury such that no therapeutic gain was attained. This effect was important however in that photon radiation and other conventional treatments have not demonstrated sterilization of GBM at any dose. Recent laboratory studies demonstrated that the hospital-based fast neutron beam from the University of Washington cyclotron has a thermal neutron component that may be used in a boron-10 neutron capture (BNC) reaction to enhance cell kill. The degree of enhancement was approximately 10 fold and was dependent upon the boron-10 concentration the boron-10 carrier agent and the fast neutron dose per fraction. The results of these experiments will be discussed in the context of creating a therapeutic window for treatment of glioblastoma using BNC-enhanced fast neutron radiation in a clinically tolerable regimen.

K. J. Stelzer; G. E. Laramore; R. Risler; L. Wiens; T. W. Griffin

1997-01-01T23:59:59.000Z

389

Advanced Coal Conversion Process Demonstration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Clean Coal Technology Program Clean Coal Technology Program Advanced Coal Conversion Process Demonstration A DOE Assessment DOE/NETL-2005/1217 U.S. Department of Energy Office of Fossil Energy National Energy Technology Laboratory April 2005 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name,

390

Power conversion apparatus and method  

DOE Patents [OSTI]

A power conversion apparatus includes an interfacing circuit that enables a current source inverter to operate from a voltage energy storage device (voltage source), such as a battery, ultracapacitor or fuel cell. The interfacing circuit, also referred to as a voltage-to-current converter, transforms the voltage source into a current source that feeds a DC current to a current source inverter. The voltage-to-current converter also provides means for controlling and maintaining a constant DC bus current that supplies the current source inverter. The voltage-to-current converter also enables the current source inverter to charge the voltage energy storage device, such as during dynamic braking of a hybrid electric vehicle, without the need of reversing the direction of the DC bus current.

Su, Gui-Jia (Knoxville, TN)

2012-02-07T23:59:59.000Z

391

Thermophotovoltaic Energy Conversion for Space  

Science Journals Connector (OSTI)

Heat is converted to electricity by using a heated surface (the emitter) that radiates infrared (IR) photons to an adjacent low bandgap photovoltaic cell (typically made with binary, ternary, or quaternary semiconductors such as InGaAs, GaSb, InAs, or InGaAsSb), which converts these IR photons to electricity. ... Solid-state TPV energy conversion uses photovoltaic devices in the form of a p?n diode to convert radiant thermal photons directly into electricity. ... The overall system efficiency of a TPV system is the product of factors attributable to the TPV cell efficiency, the spectral filter, and the cell module factor which includes effects of parasitic photon absorption in the nonactive diode area and is defined as the total photonic energy absorbed in the active diode area divided by the total photonic energy absorption. ...

V. L. Teofilo; P. Choong; J. Chang; Y.-L. Tseng; S. Ermer

2008-05-22T23:59:59.000Z

392

NMR Determination of Carbon Aromatization during Hydrous Pyrolysis of Coals from the Mesaverde Group, Greater Green River Basin  

Science Journals Connector (OSTI)

NMR Determination of Carbon Aromatization during Hydrous Pyrolysis of Coals from the Mesaverde Group, Greater Green River Basin ... This process is thought to activate capillary seals and could lead to abnormally pressured compartments, which represent a new class of hydrocarbon gas resources. ...

Francis P. Miknis; Daniel A. Netzel; Ronald C. Surdam

1996-01-18T23:59:59.000Z

393

Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England  

Broader source: Energy.gov [DOE]

This report summarizes the results of an information exchange sponsored by the DOE/EERE Bioenergy Technologies Office in Manchester, New Hampshire, on May 9-10, 2012. The participand identifies top challenges regarding feedstocks and production, logistics and compatibility, and operational issues, then prioritized next steps for expanding use of pyrolysis oil as a replacement for home heating oil in the Northeast

394

Deposition of high-density silicon carbide coatings by fluidized-bed pyrolysis of chlorinated silane derivatives  

Science Journals Connector (OSTI)

Comparative analysis of the processes for preparation of high-density silicon carbide coatings by the fluidized-bed pyrolysis of the SiCl4 + CH4 + H2 + Ar and CH3SiCl3 + H2 + Ar mixtures on pyrocarboncoated zirco...

S. D. Kurbakov; T. A. Mireev

2009-04-01T23:59:59.000Z

395

Early maturation processes in coal.1 Part 1: Pyrolysis mass balances and structural evolution of coalified wood from the2  

E-Print Network [OSTI]

Early maturation processes in coal.1 Part 1: Pyrolysis mass balances and structural evolution of coalified wood from the2 Morwell Brown Coal seam3 4 Elodie Salmon a, c , Françoise Behar a , François Lorant force21 field to simulate the thermal stress. The Morwell coal has been selected to study the thermal22

Paris-Sud XI, Université de

396

Investigation of the Effect of In-Situ Catalyst on the Steam Hydrogasification of Biomass  

E-Print Network [OSTI]

Yi, W. , Li, B. , Flash pyrolysis of agricultural residuesalthough fast or flash pyrolysis technologies can achieve a

FAN, XIN

2012-01-01T23:59:59.000Z

397

The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification  

E-Print Network [OSTI]

overview of fast pyrolysis of biomass, Organic Geochemistry,presented a Pyrolysis and Gasification of Biomass and waste,

Luo, Qian

2012-01-01T23:59:59.000Z

398

Measuring and moderating the water resource impact of biofuel production and trade  

E-Print Network [OSTI]

from   biomass  via  fast  pyrolysis,  hydrotreating  and  2.3   gal/gal  for  pyrolysis  of  woody  biomass  (Jones,  

Fingerman, Kevin Robert

2012-01-01T23:59:59.000Z

399

Next-Generation Thermionic Solar Energy Conversion  

Broader source: Energy.gov (indexed) [DOE]

Thermionic Solar Energy Conversion SLAC National Accelerator Laboratory Award Number: CPS 25659 | April 15, 2013 | Melosh * Fabricate heterostructure semiconductor cathodes based...

400

Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

will enable energy-efficient biochemical conversion of lignocellulosic biomass into biofuels that are compatible with today's vehicles and infrastructure. Photos (clockwise from...

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Solar Energy, Its Conversion and Utilization  

Science Journals Connector (OSTI)

The basis of the discussions is the University of Florida Solar Energy and Energy Conversion Laboratory with its Solar House and its Solar-Electric Car.

Erich A. Farber

1974-01-01T23:59:59.000Z

402

Economic Considerations of Biomass Conversion Processes  

Science Journals Connector (OSTI)

Earlier chapters have described various biomass conversion processes and processing procedures. This chapter provides a systematic method of estimating biomass process economics and determining the revenue requir...

Fred A. Schooley

1981-01-01T23:59:59.000Z

403

LED Street Lighting Conversion Workshop Presentations  

Broader source: Energy.gov [DOE]

This page provides links to the presentations given at the National League of Cities Mobile Workshop, LED Street Lighting Conversion: Saving Your Community Money, While Improving Public Safety,...

404

Conversion Technologies for Advanced Biofuels - Carbohydrates...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production Conversion Technologies for Advanced Biofuels - Carbohydrates Production Purdue University report-out presentation at the CTAB webinar on Carbohydrates Production....

405

Conversion Technologies for Advanced Biofuels - Carbohydrates...  

Broader source: Energy.gov (indexed) [DOE]

Upgrading Conversion Technologies for Advanced Biofuels - Carbohydrates Upgrading PNNL report-out presentation at the CTAB webinar on carbohydrates upgrading. ctabwebinarcarbohyd...

406

Automotive Waste Heat Conversion to Power Program  

Broader source: Energy.gov (indexed) [DOE]

or otherwise restricted information Project ID ace47lagrandeur Automotive Waste Heat Conversion to Power Program- 2009 Hydrogen Program and Vehicle Technologies Program...

407

Automotive Waste Heat Conversion to Power Program  

Broader source: Energy.gov (indexed) [DOE]

Start Date: Oct '04 Program End date: Oct '10 Percent Complete: 80% 2 Automotive Waste Heat Conversion to Power Program- Vehicle Technologies Program Annual Merit Review- June...

408

Developing Functionalized Graphene Materials for Biomass Conversion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Developing Functionalized Graphene Materials for Biomass Conversion The goal of this research is to develop low cost catalysts based on graphene-derived nanomaterials, and use them...

409

Surreptitious interception of conversations with lasers  

Science Journals Connector (OSTI)

Methods are described for surreptitiously intercepting conversations by reflecting a low-power laser beam from a window pane. The essential components and optical configurations of...

Mims III, Forrest M

1985-01-01T23:59:59.000Z

410

Project Profile: Brayton Solar Power Conversion System  

Broader source: Energy.gov [DOE]

Brayton Energy, under the CSP R&D FOA, is looking to demonstrate the viability and economics of a new concentrating solar thermal power conversion system.

411

Energy Conversion, an Energy Frontier Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electricity, will become increasingly important. Indeed enhancements in efficiencies of energy conversion technologies that are readily adaptable in any environment will con-...

412

Energy Conversion, an Energy Frontier Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

most pressing problems. Indeed, our success at discovering new paradigms for efficient energy conversion, with minimal environmental impact, will largely determine humankind's...

413

Solid-State Energy Conversion Overview  

Broader source: Energy.gov (indexed) [DOE]

eere.energy.gov 1 Solid-State Energy Conversion Overview John W. Fairbanks Department of Energy Vehicle Technologies Annual Merit Review June 11, 2010 Vehicle Technologies Program...

414

Conversion Technologies for Advanced Biofuels ? Carbohydrates...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

balance measurements Biological Conversion of Sugars to Hydrocarbons - R&D Activities Energy Efficiency & Renewable Energy eere.energy.gov 5 Feedstocks Organism design for...

415

Next-Generation Thermionic Solar Energy Conversion  

Broader source: Energy.gov (indexed) [DOE]

Microscale-enhanced thermionic emitters will enable high-efficiency, solar-to-electrical conversion by taking advantage of both heat and light. Image from Stanford University...

416

"Approaches to Ultrahigh Efficiency Solar Energy Conversion"...  

Office of Science (SC) Website

"Approaches to Ultrahigh Efficiency Solar Energy Conversion" Webinar Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events EFRC News...

417

"Fundamental Challenges in Solar Energy Conversion" workshop...  

Office of Science (SC) Website

Fundamental Challenges in Solar Energy Conversion" workshop hosted by LMI-EFRC Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events...

418

Thermochemical Conversion Related Links | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

website's Information Resources section. Some key publications are: Using Heat and Chemistry to Make Fuel and Power: Thermochemical Conversion (January 2011) Thermochemical...

419

Fast Ignitor coupling physics  

SciTech Connect (OSTI)

The Fast Ignitor is an alternate approach to ICF in which short pulse lasers are used to initiate burn at the surface of the compressed DT fuel. The aim is to avoid the need for careful central focusing of final shocks, and possibly to lower substantially the energy requirements for ignition. Ultimately, both goals may prove crucial to Science Based Stockpile Stewardship (SBSS). This will be the case should either emerging energetic needs, or finding difficulties render the presently planned radiative fusion approach to ignition with the NIF impractical. Ignition is a first step towards the achievement of substantial energy and neutron outputs for such Stewardship.

Mason, R.J. [Los Alamos National Lab., NM (United States); Tabak, M. [Lawrence Livermore National Lab., CA (United States)

1997-10-01T23:59:59.000Z

420

Conversion of microalgae to jet fuel: Process design and simulation  

Science Journals Connector (OSTI)

Abstract Microalgae’s aquatic, non-edible, highly genetically modifiable nature and fast growth rate are considered ideal for biomass conversion to liquid fuels providing promise for future shortages in fossil fuels and for reducing greenhouse gas and pollutant emissions from combustion. We demonstrate adaptability of PRO/II software by simulating a microalgae photo-bio-reactor and thermolysis with fixed conversion isothermal reactors adding a heat exchanger for thermolysis. We model a cooling tower and gas floatation with zero-duty flash drums adding solids removal for floatation. Properties data are from PRO/II’s thermodynamic data manager. Hydrotreating is analyzed within PRO/II’s case study option, made subject to Jet B fuel constraints, and we determine an optimal 6.8% bioleum bypass ratio, 230 °C hydrotreater temperature, and 20:1 bottoms to overhead distillation ratio. Process economic feasibility occurs if cheap CO2, H2O and nutrient resources are available, along with solar energy and energy from byproduct combustion, and hydrotreater H2 from product reforming.

Hui-Yuan Wang; David Bluck; Bernard J. Van Wie

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Agro-industry sugarcane residues disposal: The trends of their conversion into energy carriers in Cuba  

Science Journals Connector (OSTI)

The goal of the present work was to carry out a review of the disposal practices for the agro-industry’s sugarcane residue and the trends of energy use in Cuba. The lack of an alternative energy carrier to electricity with storage capability for use in off-season has to date been an unsolvable question. The improvement of cogeneration capacity via implementation of CEST or BIG/GTCC and the barriers for their implementation, the introduction of a medium size (3 ton/h) fast pyrolysis module (FPM3) as a solution for off-season energy demand in the agro-industry, and an assessment of the energy required to do so, were also analyzed. Bio-oil production from bagasse and sugarcane agriculture residues (SCAR) and their particularities at the sugar mill are treated. The influence of sugar facility production process configuration is analyzed. The fast pyrolysis products and the trends of their end uses in Cuba are presented. The production cost of a ton of Bio-oil for FPM3 conditions was calculated at 155 USD/ton and the payback time as a function of selling price between 160 and 110 USD/ton was estimated to be from 1.5 to 4 years. The economic feasibility of the FPM3 was estimated, comparing the added values for three scenarios: 1st case, currently-used sugar production, 16.5 USD/ton of cane; 2nd case, factoring in the cogeneration improvement, 27 USD/ton of cane; and 3rd case, with cogeneration improvement and Bio-oil production, 40 USD/ton of cane. The energy use of SCAR and the introduction of FPM3 in the sugar mill are promising improvements that could result in a potential surplus of 80 kW he/ton of cane in-season, or 6 × 106 ton of Bio-oil (LHV=15 MJ/kg) for use off-season in a milling season of 4 million tons of raw sugar.

W. Alonso Pippo; P. Garzone; G. Cornacchia

2007-01-01T23:59:59.000Z

422

Energy Conversion DevicesEnergy Conversion Devices Fuel Cell Electrocatalyst Development Program  

E-Print Network [OSTI]

for several groups of electrocatalysts ECD PEMFC Catalyst Development Evaluation programs exist for severalEnergy Conversion Devices PEMFC Electrocatalyst Development Program Contact information: Dr. Peter Faguy pfaguyEnergy Conversion DevicesEnergy Conversion Devices Fuel Cell Electrocatalyst Development Program

423

Gene conversion in the rice genome  

E-Print Network [OSTI]

. Over 60% of the conversions we detected were between chromosomes. We found that the inter-chromosomal conversions distributed between chromosome 1 and 5, 2 and 6, and 3 and 5 are more frequent than genome average (Z-test, P < 0.05). The frequencies...

Xu, Shuqing; Clark, Terry; Zheng, Hongkun; Vang, SÃ ¸ ren; Li, Ruiqiang; Wong, Gane Ka-Shu; Wang, Jun; Zheng, Xiaoguang

2008-02-25T23:59:59.000Z

424

Approaches for biological and biomimetic energy conversion  

Science Journals Connector (OSTI)

...biological and biomimetic energy conversion 10.1073...that are related to energy conversion: specifically...synthetic and/or hybrid devices is still...systems that produce energy in an efficient...costs are related to infrastructure, such as supporting...inverters, and grid connections. For...

David A. LaVan; Jennifer N. Cha

2006-01-01T23:59:59.000Z

425

Parameterizing energy conversion on rough topography  

E-Print Network [OSTI]

Parameterizing energy conversion on rough topography using bottom pressure sensors to measure form and mixing U0 Form drag pressure Tidal energy conversion Form drag causes: - internal wave generation - eddy Sound, WA Point Three Tree Previous work McCabe et al., 2006 > Measured the internal form drag

Warner, Sally

426

Fast SCR Thyratron Driver  

SciTech Connect (OSTI)

As part of an improvement project on the linear accelerator at SLAC, it was necessary to replace the original thyratron trigger generator, which consisted of two chassis, two vacuum tubes, and a small thyratron. All solid-state, fast rise, and high voltage thyratron drivers, therefore, have been developed and built for the 244 klystron modulators. The rack mounted, single chassis driver employs a unique way to control and generate pulses through the use of an asymmetric SCR, a PFN, a fast pulse transformer, and a saturable reactor. The resulting output pulse is 2 kV peak into 50 {Omega} load with pulse duration of 1.5 {mu}s FWHM at 180 Hz. The pulse risetime is less than 40 ns with less than 1 ns jitter. Various techniques are used to protect the SCR from being damaged by high voltage and current transients due to thyratron breakdowns. The end-of-line clipper (EOLC) detection circuit is also integrated into this chassis to interrupt the modulator triggering in the event a high percentage of line reflections occurred.

Nguyen, M.N.; /SLAC

2007-06-18T23:59:59.000Z

427

Application of Planck's law to thermionic conversion  

SciTech Connect (OSTI)

A simple, highly accurate, mathematical model of heat-to-electricity conversion is developed from Planck's law for the distribution of the radiant exitance of heat at a selected temperature. An electrical power curve is calculated by integration of the heat law over a selected range of electromagnetic wavelength corresponding to electrical voltage. A novel wavelength-voltage conversion factor, developed from the known wavelength-electron volt conversion factor, establishes the wavelength ({lambda}) for the integration. The Planck law is integrated within the limits {lambda} to 2{lambda}. The integration provides the ideal electrical power that is available from heat at the emitter temperature. When multiplied by a simple ratio, the calculated ideal power closely matches published thermionic converter experimental data. The thermal power model of thermionic conversion is validated by experiments with thermionic emission of ordinary electron tubes. A theoretical basis for the heat law based model of thermionic conversion is found in linear oscillator theory.

Caldwell, F.

1998-07-01T23:59:59.000Z

428

Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions  

Science Journals Connector (OSTI)

Abstract To investigate the kinetic characteristics of coking coal mixed with biomass during pyrolysis, thermogravimetric (TG) and thermo-balance reactor (TBR) analyses were conducted under non-isothermal and isothermal condition. Yellow poplar as a biomass (B) was mixed with weak coking coal (WC) and hard coking coal (HC), respectively. The calculated activation energies of WC/B blends were higher than those of HC/B blends under non-isothermal and isothermal conditions. The coal/biomass blends show increased reactivity and decreased activation energy with increasing biomass blend ratio, regardless of the coking properties of the coal. The different char structures of the WC/B and HC/B blends were analyzed by BET and SEM.

Ha Myung Jeong; Myung Won Seo; Sang Mun Jeong; Byung Ki Na; Sang Jun Yoon; Jae Goo Lee; Woon Jae Lee

2014-01-01T23:59:59.000Z

429

KINETIC STUDY OF COAL AND BIOMASS CO-PYROLYSIS USING THERMOGRAVIMETRY  

SciTech Connect (OSTI)

The objectives of this study are to investigate thermal behavior of coal and biomass blends in inert gas environment at low heating rates and to develop a simplified kinetic model using model fitting techniques based on TGA experimental data. Differences in thermal behavior and reactivity in co-pyrolysis of Powder River Basin (PRB) sub-bituminous coal and pelletized southern yellow pine wood sawdust blends at low heating rates are observed. Coal/wood blends have higher reactivity compared to coal alone in the lower temperature due to the high volatile matter content of wood. As heating rates increase, weight loss rates increase. The experiment data obtained from TGA has a better fit with proposed two step first order reactions model compared single first order reaction model.

Wang, Ping; Hedges, Sheila; Chaudharib, Kiran; Turtonb, Richard

2013-10-29T23:59:59.000Z

430

Thermal characterization and pyrolysis kinetics of tropical biomass feedstocks for energy recovery  

Science Journals Connector (OSTI)

Abstract This paper aims to analyse energy related properties, thermal degradation behaviour and devolatilization kinetics of five Cameroonian biomasses namely, Palm Kernel Shells (PKS), Mesocarp Fibres (PMF), Coffee Husk (CH), Corn Cob (CC) and Peanut Shell (PNS). The thermal degradation was performed using thermogravimetric analysis (TG). Different behaviours related to the presence of chemical constituents such as cellulose, hemicellulose and lignin were obtained. Comparison of the thermal characterization shows that PMF is the most interesting feedstock with the highest heating values and reactivity due to higher volatile content. Decomposition of TG data was analysed by applying diffusion and chemical reaction kinetic models. Obtained results show that biomass pyrolysis is represented by two successive steps. The devolatilization stage characterized by high weight loss rate is well described by diffusion reaction models. In contrast, the char formation stage characterized by low weight loss rate is well described by third order chemical reaction models.

M. Jeguirim; J. Bikai; Y. Elmay; L. Limousy; E. Njeugna

2014-01-01T23:59:59.000Z

431

Estimation of Arrhenius parameters for the 1,1 elimination of hydrogen from disilane and the role of chemically activated disilane in silane pyrolysis  

Science Journals Connector (OSTI)

Estimation of Arrhenius parameters for the 1,1 elimination of hydrogen from disilane and the role of chemically activated disilane in silane pyrolysis ... Thermal Decomposition Mechanism of Disilane ... Thermal Decomposition Mechanism of Disilane ...

Harry K. Moffat; Klavs F. Jensen; Robert W. Carr

1992-01-01T23:59:59.000Z

432

Highly Unsaturated Hydrogenated Silicon Clusters, SinHx (n = 3?10, x = 0?3), in Flash Pyrolysis of Silane and Disilane  

Science Journals Connector (OSTI)

Highly Unsaturated Hydrogenated Silicon Clusters, SinHx (n = 3?10, x = 0?3), in Flash Pyrolysis of Silane and Disilane ... Bare and partially hydrogenated neutral silicon clusters, SinHx (n = 3?10, x = 0?3), were produced upon flash pyrolysis of dilute (1%) mixtures of disilane, Si2H6, in Ar and of silane, SiH4, in He at temperatures above ?1000 K. Immediately following the flash pyrolysis of the precursors (on an ?20 ?s time scale), the clusters were isolated in a supersonic molecular beam and detected by single vacuum ultraviolet (VUV) photon (? = 118.2 ... 6 Other conventional methods of pyrolysis of silane and disilane have resulted in the production of silicon particles (>5 nm) that contain ?10?30% mole fraction of hydrogen, have near saturation surface coverage with hydrogen, and are suspected precursors to a-Si:H growth. ...

Steven D. Chambreau; Liming Wang; Jingsong Zhang

2002-05-01T23:59:59.000Z

433

Conversion of Units of Measurement Gordon S. Novak Jr. \\Lambda  

E-Print Network [OSTI]

by the programmer; this can be both burdensome and error­prone, since the conversion factors used by the programmer guidelines for use of SI units and tables of conversion factors. Several books provide conversion factors, the accuracy of the conversion factors, and the algorithms that some books present for unit conversion

Novak Jr., Gordon S.

434

Theory of Fast Electron Transport for Fast Ignition  

E-Print Network [OSTI]

Fast Ignition Inertial Confinement Fusion is a variant of inertial fusion in which DT fuel is first compressed to high density and then ignited by a relativistic electron beam generated by a fast (laser pulse, which is usually brought in to the dense plasma via the inclusion of a re-entrant cone. The transport of this beam from the cone apex into the dense fuel is a critical part of this scheme, as it can strongly influence the overall energetics. Here we review progress in the theory and numerical simulation of fast electron transport in the context of Fast Ignition. Important aspects of the basic plasma physics, descriptions of the numerical methods used, a review of ignition-scale simulations, and a survey of schemes for controlling the propagation of fast electrons are included. Considerable progress has taken place in this area, but the development of a robust, high-gain FI `point design' is still an ongoing challenge.

Robinson, A P L; Davies, J R; Gremillet, L; Honrubia, J J; Johzaki, T; Kingham, R J; Sherlock, M; Solodov, A A

2013-01-01T23:59:59.000Z

435

The effect of storage on the chemical composition and thermochemical conversion of biomass  

SciTech Connect (OSTI)

The effects of storage on different biomass feedstocks, including short rotation woody crops, herbaceous crops, and agricultural residues have been studied. Results of the analysis of fresh and stored material from four short rotation woody species using traditional wet chemical analysis showed differences in the chemical composition of the feedstocks harvested at different times. Changes that occurred in the material after unprotected storage outside for 26 weeks were measured. Over the period of the storage study, small changes were observed in the structural cell wall components including cellulose, hemicellulose and lignin. Larger changes were observed in the materials that could be extracted with 95% ethanol. Also presented are results from a rapid analytical technique using pyrolysis-mass spectrometry combined with multivariate statistical analysis to assess the influence of storage on the composition and thermochemical conversion of the different biomass feedstocks. Because of the rapid nature of this technique, a large number of samples could be screened to determine the extent of degradation throughout the piles. Application of this technique to the samples in this study indicated that, for the most part, significant changes did not occur in the composition of biomass taken from the centers of the piles. However, significant changes were detected in biomass taken from the outer layers and isolated regions in the piles where most advanced degradation had occurred.

Davis, M.F.; Agblevor, F.A.; Johnson, D.K. [National Renewable Energy Lab., Golden, CO (United States)] [and others

1994-12-31T23:59:59.000Z

436

S-1041 Multistate Research Project The Science and Engineering for a Biobased Industry  

E-Print Network [OSTI]

, Vonore, TN 37885 (865-441-1123) kgoddar3@utk.edu DISTRIBUTED FAST PYROLYSIS FOR CONVERSION OF BIOMASS Industry 2010 Symposium Proceedings 4 THERMOCHEMICAL CONVERSION OF BIOMASS TO ADVANCED BIOFUELS, U.S. DEPARTMENT OF ENERGY, BIOMASS PROGRAM............................................41 Jonathan L. Male

437

CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

3% Zn and 14% CH oH (50 g coal 9 300 g melt) Atomic TempVermeulen, "High-Yield Coal Conversion in a Zinc Chloride/H. Shinn, and T. Vermeulen, "Coal Lic;uefaction Catalysis by

Vermeulen, T.

2012-01-01T23:59:59.000Z

438

Technician's Perspective on an Ever-Changing Research Environment: Catalytic Conversion of Biomass to Fuels  

SciTech Connect (OSTI)

The biomass thermochemical conversion platform at the National Renewable Energy Laboratory (NREL) develops and demonstrates processes for the conversion of biomass to fuels and chemicals including gasification, pyrolysis, syngas clean-up, and catalytic synthesis of alcohol and hydrocarbon fuels. In this talk, I will discuss the challenges of being a technician in this type of research environment, including handling and working with catalytic materials and hazardous chemicals, building systems without being given all of the necessary specifications, pushing the limits of the systems through ever-changing experiments, and achieving two-way communication with engineers and supervisors. I will do this by way of two examples from recent research. First, I will describe a unique operate-to-failure experiment in the gasification of chicken litter that resulted in the formation of a solid plug in the gasifier, requiring several technicians to chisel the material out. Second, I will compare and contrast bench scale and pilot scale catalyst research, including instances where both are conducted simultaneously from common upstream equipment. By way of example, I hope to illustrate the importance of researchers 1) understanding the technicians' perspective on tasks, 2) openly communicating among all team members, and 3) knowing when to voice opinions. I believe the examples in this talk will highlight the crucial role of a technical staff: skills attained by years of experience to build and operate research and production systems. The talk will also showcase the responsibilities of NREL technicians and highlight some interesting behind-the-scenes work that makes data generation from NREL's thermochemical process development unit possible.

Thibodeaux, J.; Hensley, J.

2013-01-01T23:59:59.000Z

439

Utilizing Nature's Designs for Solar Energy Conversion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nature's Designs for Solar Energy Conversion Nature's Designs for Solar Energy Conversion Create new materials that: capture, convert, store sunlight Learn from Nature... ...build with chemistry ANL Photosynthesis Group Fundamental Studies  Solar energy conversion in natural and artificial photosynthesis Resolve mechanisms, design principles  Unique capabilities Time-resolved, multi-frequency EPR Time-resolved synchrotron X-ray Ultrafast spectroscopy Multi-molecular: Artificial systems for H 2 photocatalysis  Limitations:  Large solvent, molecular dependencies  Diffusion  Lifetimes  Uncontrolled back-reactions  Most PS contain noble metals  Organic solvent/high proton

440

Fast Ignition Program Presented at  

E-Print Network [OSTI]

Laser drive Direct Laser drive #12;Fast Ignition may allow longer wavelength laser implosion systemsFast Ignition Program Presented at FESAC Development Path Panel General Atomics January 14, 2003 E. Michael Campbell ·Promise ·Status ·Challenges ·Implementation ·Plan #12;The original FI concept uses laser

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Investigation of proton focusing and conversion efficiency for proton fast ignition  

E-Print Network [OSTI]

Temporal, and Honrubia, Nuclear Fusion (2002) [22]. . . . .injected triggers,” Nuclear Fusion, vol. 36, no. 6, p. 745,laser-accelerated protons,” Nuclear Fusion, vol. 42, p. L1,

Bartal, Teresa Jean

2012-01-01T23:59:59.000Z

442

Investigation of proton focusing and conversion efficiency for proton fast ignition  

E-Print Network [OSTI]

data tabulated by J. R. McNally Jr. [5]. . . Figure 1.3:data tabulated by J. R. McNally Jr. [5]. Concept of Inertial

Bartal, Teresa Jean

2012-01-01T23:59:59.000Z

443

Investigation of proton focusing and conversion efficiency for proton fast ignition  

E-Print Network [OSTI]

After ignition, a thermonuclear burn wave spreads radiallythe shell to create the thermonuclear burn wave. At 10 keV,heating the plasma to thermonuclear temperatures. Protons

Bartal, Teresa Jean

2012-01-01T23:59:59.000Z

444

Investigation of proton focusing and conversion efficiency for proton fast ignition  

E-Print Network [OSTI]

as a step towards laser fusion ignition,” nature, vol. 412,laser in order for the ignition laser to be absorbed in areason being that the ignition laser energy would otherwise

Bartal, Teresa Jean

2012-01-01T23:59:59.000Z

445

Fast Spectrum Molten Salt Reactor Options  

SciTech Connect (OSTI)

During 2010, fast-spectrum molten-salt reactors (FS-MSRs) were selected as a transformational reactor concept for light-water reactor (LWR)-derived heavy actinide disposition by the Department of Energy-Nuclear Energy Advanced Reactor Concepts (ARC) program and were the subject of a preliminary scoping investigation. Much of the reactor description information presented in this report derives from the preliminary studies performed for the ARC project. This report, however, has a somewhat broader scope-providing a conceptual overview of the characteristics and design options for FS-MSRs. It does not present in-depth evaluation of any FS-MSR particular characteristic, but instead provides an overview of all of the major reactor system technologies and characteristics, including the technology developments since the end of major molten salt reactor (MSR) development efforts in the 1970s. This report first presents a historical overview of the FS-MSR technology and describes the innovative characteristics of an FS-MSR. Next, it provides an overview of possible reactor configurations. The following design features/options and performance considerations are described including: (1) reactor salt options-both chloride and fluoride salts; (2) the impact of changing the carrier salt and actinide concentration on conversion ratio; (3) the conversion ratio; (4) an overview of the fuel salt chemical processing; (5) potential power cycles and hydrogen production options; and (6) overview of the performance characteristics of FS-MSRs, including general comparative metrics with LWRs. The conceptual-level evaluation includes resource sustainability, proliferation resistance, economics, and safety. The report concludes with a description of the work necessary to begin more detailed evaluation of FS-MSRs as a realistic reactor and fuel cycle option.

Gehin, Jess C [ORNL; Holcomb, David Eugene [ORNL; Flanagan, George F [ORNL; Patton, Bruce W [ORNL; Howard, Rob L [ORNL; Harrison, Thomas J [ORNL

2011-07-01T23:59:59.000Z

446

Paducah DUF6 Conversion Final EIS - Appendix G: Consultation Letters  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Paducah DUF Paducah DUF 6 Conversion Final EIS APPENDIX G: CONSULTATION LETTERS Consultation Letters G-2 Paducah DUF 6 Conversion Final EIS Consultation Letters G-3 Paducah DUF 6 Conversion Final EIS U.S. DEPARTMENT OF ENERGY LETTERS TO STATE AGENCIES AND RECOGNIZED NATIVE AMERICAN GROUPS Consultation Letters G-4 Paducah DUF 6 Conversion Final EIS Consultation Letters G-5 Paducah DUF 6 Conversion Final EIS Consultation Letters G-6 Paducah DUF 6 Conversion Final EIS Consultation Letters G-7 Paducah DUF 6 Conversion Final EIS Consultation Letters G-8 Paducah DUF 6 Conversion Final EIS Consultation Letters G-9 Paducah DUF 6 Conversion Final EIS Consultation Letters G-10 Paducah DUF 6 Conversion Final EIS Consultation Letters G-11 Paducah DUF 6 Conversion Final EIS Consultation Letters G-12 Paducah DUF 6 Conversion Final EIS

447

Micro Electret Energy Harvesting Device with Analogue Impedance Conversion Circuit  

E-Print Network [OSTI]

Micro Electret Energy Harvesting Device with Analogue Impedance Conversion Circuit Yuji Suzuki1 using a low-power-consumption impedance conversion circuit. Key words: Energy harvesting, Electret, CYTOP, Parylene spring, Impedance conversion 1. INTRODUCTION Energy harvesting from environmental

Kasagi, Nobuhide

448

Health Risks Associated with Conversion of Depleted UF6  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion Conversion DUF6 Health Risks line line Accidents Storage Conversion Manufacturing Disposal Transportation Conversion A discussion of health risks associated with conversion of depleted UF6 to another chemical form. General Health Risks of Conversion The potential environmental impacts, including potential health risks, associated with conversion activities will be evaluated in detail as part of the Depleted Uranium Hexafluoride management program after a contract is awarded for conversion services. This section discusses in general the types of health risks associated with the conversion process. The conversion of depleted UF6 to another chemical form will be done in an industrial facility dedicated to the conversion process. Conversion will involve the handling of depleted UF6 cylinders. Hazardous chemicals, such

449

NREL: Biomass Research - Biochemical Conversion Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biochemical Conversion Projects Biochemical Conversion Projects A photo of a woman looking at the underside of a clear plastic tray. The tray has a grid of small holes to hold sample tubes. An NREL researcher examines a sample tray used in the BioScreen C, an instrument used to monitor the growth of microorganisms under different conditions. NREL's projects in biochemical conversion involve three basic steps to convert biomass feedstocks to fuels: Converting biomass to sugar or other fermentation feedstock Fermenting these biomass intermediates using biocatalysts (microorganisms including yeast and bacteria) Processing the fermentation product to yield fuel-grade ethanol and other fuels. Among the current biochemical conversion RD&D projects at NREL are: Pretreatment and Enzymatic Hydrolysis

450

Depleted UF6 Conversion facility EIS Topics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Topics Topics Depleted UF6 Conversion Facility EIS Topics A listing of topics included in the Depleted UF6 Conversion Facility EISs. DOE addressed the following environmental issues when assessing the potential environmental impacts of the alternatives in the two site-specific EISs. DOE solicited comment from the Federal agencies, Native American tribes, state and local governments, and the general public on these and any other issues as part of the public scoping process: Potential impacts on health from DUF6 conversion activities, including potential impacts to workers and the public from exposure to radiation and chemicals during routine and accident conditions for the construction, operation, maintenance, and decontamination and decommissioning of DUF6 conversion facilities.

451

Overview of Capabilities Conversion System Technology  

E-Print Network [OSTI]

cycles Heat exchanger design and optimization TES Material Integration & Optimization: Solar power plantOverview of Capabilities Conversion System Technology - Power System Demonstrations - Systems Conceptual Design/Trade Space Exploration - Simulation Modeling for Manufacturing - Hybrid Energy Systems

Lee, Dongwon

452

Summer Series 2012 - Conversation with Omar Yaghi  

ScienceCinema (OSTI)

Jeff Miller, head of Public Affairs, sat down in conversation with Omar Yaghi, director of the Molecular Foundry, in the first of a series of "powerpoint-free" talks on July 11th 2012, at Berkeley Lab.

Omar Yaghi

2013-06-24T23:59:59.000Z

453

Ris Energy Report 2 Bioenergy conversion  

E-Print Network [OSTI]

6.3 Risø Energy Report 2 Bioenergy conversion There is a wide range of technologies to derive operate automatically and are in many regions an economic alternative, e.g. Austria and Finland

454

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the Fischer–Tropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

455

Chapter 13 - Heterogeneous Catalysts and Biomass Conversion  

Science Journals Connector (OSTI)

Abstract The application of heterogeneous catalysts to conversion processes based on biomasses is described and discussed. The role of heterogeneous catalysts in the development of renewable industrial chemistry is emphasized.

Guido Busca

2014-01-01T23:59:59.000Z

456

CO2 Conversion to CH4  

Science Journals Connector (OSTI)

A power-to-gas technology that converts renewable energy to methane...16]. Conversion of renewable energy, that is, solar or wind, into fuel is an easy way to store solar energy, characterized by low energy densi...

V. Barbarossa; C. Bassano; P. Deiana; G. Vanga

2013-01-01T23:59:59.000Z

457

Energy Balances for Biomass Conversion Systems  

Science Journals Connector (OSTI)

Biomass conversion systems of any type, irrespective of ... measured on a consistent scale which identifies the energy efficiency of the process and of the overall system. Accurate energy balances, as well as mat...

Raphael Katzen

1983-01-01T23:59:59.000Z

458

Energy conversions of a desert depression  

Science Journals Connector (OSTI)

This work is concerned with the energy conversions of a developing atmospheric system in subtropical ... and temporal variations of various components of the energy budget are presented in a detailed analysis. T...

H. Abdel Basset

2001-04-01T23:59:59.000Z

459

The Conversion of Waste to Energy  

E-Print Network [OSTI]

Almost every industrial operation produces some combustible waste, but conversion of this to useful energy is often more difficult than with other energy recovery projects and requires careful attention to design, operating and maintaining...

John, T.; Cheek, L.

1980-01-01T23:59:59.000Z

460

Energy Conversion, an Energy Frontier Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

11 Awards ... 12 S p r I N g 2 0 1 1 Intermediate Band Solar Energy Conversion in ZnTe:O and ZnTeZnSe Affordable photovoltaic solar cells are highly...

Note: This page contains sample records for the topic "fast pyrolysis conversion" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Principles of photoelectrochemical, solar energy conversion  

Science Journals Connector (OSTI)

Photoelectrochemical devices for conversion of solar energy into both electrical energy and chemical energy are discussed with emphasis on how the ... parameters as band gap, doping level, minority carrier lifeti...

M. A. Butler; D. S. Ginley

1980-01-01T23:59:59.000Z

462

Materials aspects of photoelectrochemical energy conversion  

Science Journals Connector (OSTI)

Stabilization of the light-harvesting semiconductor electrode is a key factor in the design of a photoelectrochemical (PEC) system for solar energy conversion. Approaches to circumvent the problem of PEC...

K. Rajeshwar

1985-01-01T23:59:59.000Z

463

Status of Solar Thermal Conversion in China  

Science Journals Connector (OSTI)

China has an abundant solar energy resource. Solar thermal conversion systems have been studied for more than 25 years and solar thermal industry has been developing since 1990’s....2 solar collectors were sold a...

Yin Zhiqiang

2009-01-01T23:59:59.000Z

464

Network Analysis of Photovoltaic Energy Conversion  

Science Journals Connector (OSTI)

Photovoltaic energy conversion in photovoltaic cells has been analyzed by the detailed balance approach or by thermodynamic arguments. Here we introduce a network representation to analyze the performance of such systems once a suitable kinetic model (...

Mario Einax; Abraham Nitzan

2014-11-03T23:59:59.000Z

465

Assessment of ocean thermal energy conversion  

E-Print Network [OSTI]

Ocean thermal energy conversion (OTEC) is a promising renewable energy technology to generate electricity and has other applications such as production of freshwater, seawater air-conditioning, marine culture and chilled-soil ...

Muralidharan, Shylesh

2012-01-01T23:59:59.000Z

466

Summer Series 2012 - Conversation with Kathy Yelick  

ScienceCinema (OSTI)

Jeff Miller, head of Public Affairs, sat down in conversation with Kathy Yelick, Associate Berkeley Lab Director, Computing Sciences, in the second of a series of "powerpoint-free" talks on July 18th 2012, at Berkeley Lab.

Kathy Yelick

2013-06-24T23:59:59.000Z

467

Atlantic Biomass Conversions Inc | Open Energy Information  

Open Energy Info (EERE)

Conversions Inc Conversions Inc Jump to: navigation, search Name Atlantic Biomass Conversions Inc Place Frederick, Maryland Sector Biomass Product Atlantic Biomass Conversions is working on a system and a genetically modified bacteria to convert sugar beet pulp waste into methanol. Coordinates 45.836395°, -98.507249° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":45.836395,"lon":-98.507249,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

468

E-Print Network 3.0 - advanced conversion technologies Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

establish efficient clean energy systems, we offer education Summary: * Advanced Energy Conversion * Highly Qualified Energy Conversion * Functional Energy Conversion...

469

Lattice effect in solid state internal conversion  

SciTech Connect (OSTI)

The effect of the crystal lattice on nuclear fusion reactions p+d{yields}{sup 3}He taking place in internal conversion channels is studied. Fusionable particles solved in the investigated crystalline material form a sublattice. Fusion reaction is generated by a flux of incoming fusionable particles. The calculated cross sections are compared with those of an ordinary fusion reaction. The internal conversion coefficients are also calculated.

Kalman, Peter; Keszthelyi, Tamas [Budapest University of Technology and Economics, Department of Experimental Physics, Budafoki ut 8. F. I.I.10, H-1521 Budapest (Hungary)

2009-03-15T23:59:59.000Z

470

Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel Alternative Fuel Vehicle (AFV) Conversion to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Vehicle (AFV) Conversion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Vehicle (AFV) Conversion

471

The Southern California Conversion Technology Demonstration Project | Open  

Open Energy Info (EERE)

The Southern California Conversion Technology Demonstration Project The Southern California Conversion Technology Demonstration Project Jump to: navigation, search Tool Summary Name: The Southern California Conversion Technology Demonstration Project Agency/Company /Organization: The Southern California Conversion Technology Demonstration Project Sector: Energy, Land Focus Area: - Waste to Energy Phase: Create a Vision Resource Type: Publications User Interface: Website Website: www.socalconversion.org/resources.html Cost: Free The Southern California Conversion Technology Demonstration Project website is focused on a specific conversion technology demonstration project in L. A. County. Overview The Southern California Conversion Technology Demonstration Project website is focused on a specific conversion technology demonstration project in L.

472

First-of-its-Kind Carbon Capture and Conversion Demonstration...  

Broader source: Energy.gov (indexed) [DOE]

First-of-its-Kind Carbon Capture and Conversion Demonstration Technology Opening in Texas First-of-its-Kind Carbon Capture and Conversion Demonstration Technology Opening in Texas...

473

Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...  

Broader source: Energy.gov (indexed) [DOE]

Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity Presents successful...

474

Novel Energy Conversion Equipment for Low Temperature Geothermal...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Novel Energy Conversion Equipment for Low Temperature Geothermal Resources Novel Energy Conversion Equipment for Low Temperature Geothermal Resources Project objective: Develop...

475

WEC up! Energy Department Announces Wave Energy Conversion Prize...  

Broader source: Energy.gov (indexed) [DOE]

WEC up Energy Department Announces Wave Energy Conversion Prize Administrator WEC up Energy Department Announces Wave Energy Conversion Prize Administrator September 24, 2014 -...

476

Advanced, High Power, Next Scale, Wave Energy Conversion Device...  

Broader source: Energy.gov (indexed) [DOE]

Advanced, High Power, Next Scale, Wave Energy Conversion Device Advanced, High Power, Next Scale, Wave Energy Conversion Device Advanced, High Power, Next Scale, Wave Energy...

477

Potential Impacts of Hydrokinetic and Wave Energy Conversion...  

Broader source: Energy.gov (indexed) [DOE]

Potential Impacts of Hydrokinetic and Wave Energy Conversion Technologies on Aquatic Environments Potential Impacts of Hydrokinetic and Wave Energy Conversion Technologies on...

478

Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The...

479

Process Design and Economics for the Conversion of Lignocellulosic...  

Broader source: Energy.gov (indexed) [DOE]

Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion...

480

2011 Biomass Program Platform Peer Review: Biochemical Conversion...  

Broader source: Energy.gov (indexed) [DOE]

Biochemical Conversion 2011 Biomass Program Platform Peer Review: Biochemical Conversion This document summarizes the recommendations and evaluations provided by an independent...

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to obtain the most current and comprehensive results.


481

New process speeds conversion of biomass to fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion of Biomass to Fuels New process speeds conversion of biomass to fuels Scientists made a major step forward recently towards transforming biomass-derived molecules into...

482

New process speeds conversion of biomass to fuels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion of biomass to fuels New process speeds conversion of biomass to fuels Scientists made a major step forward recently towards transforming biomass-derived molecules into...

483

Thermoelectric Conversion of Waste Heat to Electricity in an...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

truck system. schock.pdf More Documents & Publications Thermoelectric Conversion of Wate Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of Waste...

484

Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversions to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicle...

485

Conversation/Culture Partner Program Would you like to help  

E-Print Network [OSTI]

Conversation/Culture Partner Program Would you like to help another student improve their English different cultures; *Help another student improve their conversation English; and *Assist another student

Thomas, Andrew

486

Left Coast Electric Formerly Left Coast Conversions | Open Energy...  

Open Energy Info (EERE)

Left Coast Electric Formerly Left Coast Conversions Jump to: navigation, search Name: Left Coast Electric (Formerly Left Coast Conversions) Place: California Sector: Services...

487

Golden Fuel Systems formerly Greasel Conversions Inc | Open Energy...  

Open Energy Info (EERE)

Golden Fuel Systems formerly Greasel Conversions Inc Jump to: navigation, search Name: Golden Fuel Systems (formerly Greasel Conversions Inc) Place: Drury, Montana Zip: 65638...

488

EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

60: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site Summary This...

489

Evaluation of Thermal to Electrical Energy Conversion of High...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal to Electrical Energy Conversion of High Temperature Skutterudite-Based Thermoelectric Modules Evaluation of Thermal to Electrical Energy Conversion of High Temperature...

490

Single-step conversion of cellulose to 5-hydroxymethylfurfural...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Single-step conversion of cellulose to 5-hydroxymethylfurfural (HMF), a versatileplatform chemical. Single-step conversion of cellulose to 5-hydroxymethylfurfural (HMF), a...

491

Penrose Landfill Gas Conversion LLC | Open Energy Information  

Open Energy Info (EERE)

Penrose Landfill Gas Conversion LLC Place: Los Angeles, California Product: Owner of landfill gas plant. References: Penrose Landfill Gas Conversion LLC1 This article is a stub....

492

Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Alternative Fuel and Alternative Fuel and Conversion Definitions to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Conversion Definitions on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel and Conversion Definitions

493

Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Ethanol Flexible Fuel Ethanol Flexible Fuel Vehicle Conversions to someone by E-mail Share Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center: Ethanol Flexible Fuel Vehicle Conversions on AddThis.com... Ethanol Flexible Fuel Vehicle Conversions Updated July 29, 2011 Rising gasoline prices and concerns about climate change have greatly

494

Light-Material Interactions in Energy Conversion - Energy Frontier...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

conversion efficiency for non-tracking converters must be reasonably independent of light incidence angle. To improve energy conversion efficiency with photonic design and...

495

U.S. domestic reactor conversion program  

SciTech Connect (OSTI)

The RERTR U.S. Domestic Conversion program continues in its support of the Global Treat Reduction Initiative (GTRI) to convert seven U.S reactors to low enriched uranium (LEU) by 2010. These reactors are located at the University of Florida, Texas A and M University, Purdue University, Washington State University, Oregon State University, the University of Wisconsin, and the Idaho National Laboratory. The reactors located at the University of Florida and Texas A and M Nuclear Science Center were successfully converted to LEU in September of 2006 through an integrated and collaborative effort involving INL, Argonne National Laboratory (ANL), DOE (headquarters and the field office), the Nuclear Regulatory Commission (NRC), the universities, and the contractors involved in analyses, fuel design and fabrication, and spent nuclear fuel (SNF) shipping and disposition. With this work completed and in anticipation of other impending conversion projects, a meeting was established to engage the project participants in a structured discussion to capture the lessons learned. The objectives of this meeting were to document the observations, insights, issues, concerns, and ideas of those involved in the reactor conversions so that future efforts could be conducted with greater effectiveness, efficiency, and with fewer challenges. The lessons learned from completing the University of Florida and Texas A and M conversions, the Purdue reactor conversion status, and an overview of the upcoming reactor conversions will be presented at the meeting. (author)

Meyer, Dana M.; Woolstenhulme, Eric C. [Idaho National Laboratory, Idaho Falls, Idaho 83415 (United States)

2008-07-15T23:59:59.000Z

496

Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems  

E-Print Network [OSTI]

clean and efficient energy conversion in power systems," inSteam Power Plant," in Energy conversion, YG Goswami and Fazeotropic mixture energy conversion," Energy Conversion and

Ho, Tony

2012-01-01T23:59:59.000Z

497

THE MATERIALS OF FAST BREEDER REACTORS  

E-Print Network [OSTI]

metal fast breeder reactor (LMFBR) concern the behavior ofmetal fast breeder reactor (LMFBR). Despite the simplicityinduced by irradiation. LMFBR funding is the largest single

Olander, Donald R.

2013-01-01T23:59:59.000Z

498

Fast Pulsing Neutron Generators for Security Application  

E-Print Network [OSTI]

FAST PULSING NEUTRON GENERATORS FOR SECURITY APPLICATION* Q.time/fast pulsing neutron generator is needed primarily forA compact neutron generator, currently being developed in

Ji, Q.

2010-01-01T23:59:59.000Z

499

Alternative Fuels Data Center: Natural Gas Vehicle Conversions  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Conversions to someone by E-mail Conversions to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center: Natural Gas Vehicle Conversions on AddThis.com... More in this section... Natural Gas Basics Benefits & Considerations Stations Vehicles Availability Conversions Emissions Maintenance & Safety Laws & Incentives Natural Gas Vehicle Conversions Related Information Conversion Basics

500

Electron Generation and Transport in Intense Relativistic Laser-Plasma Interactions Relevant to Fast Ignition ICF  

SciTech Connect (OSTI)

The reentrant cone approach to Fast Ignition, an advanced Inertial Confinement Fusion scheme, remains one of the most attractive because of the potential to efficiently collect and guide the laser light into the cone tip and direct energetic electrons into the high density core of the fuel. However, in the presence of a preformed plasma, the laser energy is largely absorbed before it can reach the cone tip. Full scale fast ignition laser systems are envisioned to have prepulses ranging between 100 mJ to 1 J. A few of the imperative issues facing fast ignition, then, are the conversion efficiency with which the laser light is converted to hot electrons, the subsequent transport characteristics of those electrons, and requirements for maximum allowable prepulse this may put on the laser system. This dissertation examines the laser-to-fast electron conversion efficiency scaling with prepulse for cone-guided fast ignition. Work in developing an extreme ultraviolet imager diagnostic for the temperature measurements of electron-heated targets, as well as the validation of the use of a thin wire for simultaneous determination of electron number density and electron temperature will be discussed.

Ma, T

2010-04-21T23:59:59.000Z