National Library of Energy BETA

Sample records for fabricated metal products

  1. MECS 2006- Fabricated Metals

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Fabricated Metals (NAICS 332) Sector with Total Energy Input, October 2012 (MECS 2006)

  2. Fabricated Metals (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fabricated Metals (2010 MECS) Fabricated Metals (2010 MECS) Manufacturing Energy and Carbon Footprint for Fabricated Metals Sector (NAICS 332) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint Fabricated Metals (124.58 KB) More Documents & Publications MECS 2006 - Fabricated Metals Cement (2010 MECS) Glass and Glass Products (2010 MECS) Manufacturing Energy Sankey

  3. Fabrication of metal shells

    SciTech Connect (OSTI)

    O'Holleran, T.P.; Henderson, T.M.; Downs, R.L.; Nolen, R.L.

    1980-01-01

    Small hollow metal spheres are needed as targets for particle-beam fusion experiments and as the inner fuel container for multi-shell targets. For the multishell application, shells fabricated of materials with high atomic numbers, e.g., gold, are of particular interest because they may effectively reduce preheating of the fuel. Because the shells must also contain the fuel mixture (deuterium and tritium) at high pressures, high strength materials, e.g., iron, are also of considerable interest. With the objective of proof of principle we have investigated several techniques of fabricating shells of metal or materials containing large fractions of high atomic number elements. These techniques, our experimental results and their evaluation are presented.

  4. Fabrication of metallic glass structures

    DOE Patents [OSTI]

    Cline, C.F.

    1983-10-20

    Amorphous metal powders or ribbons are fabricated into solid shapes of appreciable thickness by the application of compaction energy. The temperature regime wherein the amorphous metal deforms by viscous flow is measured. The metal powders or ribbons are compacted within the temperature regime.

  5. Waste container fabrication from recycled DOE metal

    SciTech Connect (OSTI)

    Motl, G.P.; Burns, D.D.

    1994-02-15

    The Department of Energy (DOE) has more than 2.5 million tons of radioactive scrap metal (RSM) that is either in inventory or expected to be generated over the next 25 years as major facilities within the weapons complex are decommissioned. Much of this material cannot be surface decontaminated. In an attempt to conserve natural resources and to avoid burial of this material at DOE disposal sites, options are now being explored to {open_quotes}beneficially reuse{close_quotes} this material in applications where small amounts of radioactivity are not a detriment. One example is where RSM is currently being beneficially used to fabricate shield blocks for use in DOE medium energy physics programs. This paper describes other initiatives now underway within DOE to utilize RSM to fabricate other products, such as radioactive waste shipping, storage and disposal containers.

  6. Composite metal foil and ceramic fabric materials

    DOE Patents [OSTI]

    Webb, Brent J.; Antoniak, Zen I.; Prater, John T.; DeSteese, John G.

    1992-01-01

    The invention comprises new materials useful in a wide variety of terrestrial and space applications. In one aspect, the invention comprises a flexible cloth-like material comprising a layer of flexible woven ceramic fabric bonded with a layer of metallic foil. In another aspect, the invention includes a flexible fluid impermeable barrier comprising a flexible woven ceramic fabric layer having metal wire woven therein. A metallic foil layer is incontinuously welded to the woven metal wire. In yet another aspect, the invention includes a material comprising a layer of flexible woven ceramic fabric bonded with a layer of an organic polymer. In still another aspect, the invention includes a rigid fabric structure comprising a flexible woven ceramic fabric and a resinous support material which has been hardened as the direct result of exposure to ultraviolet light. Inventive methods for producing such material are also disclosed.

  7. Composite metal foil and ceramic fabric materials

    DOE Patents [OSTI]

    Webb, B.J.; Antoniak, Z.I.; Prater, J.T.; DeSteese, J.G.

    1992-03-24

    The invention comprises new materials useful in a wide variety of terrestrial and space applications. In one aspect, the invention comprises a flexible cloth-like material comprising a layer of flexible woven ceramic fabric bonded with a layer of metallic foil. In another aspect, the invention includes a flexible fluid impermeable barrier comprising a flexible woven ceramic fabric layer having metal wire woven therein. A metallic foil layer is incontinuously welded to the woven metal wire. In yet another aspect, the invention includes a material comprising a layer of flexible woven ceramic fabric bonded with a layer of an organic polymer. In still another aspect, the invention includes a rigid fabric structure comprising a flexible woven ceramic fabric and a resinous support material which has been hardened as the direct result of exposure to ultraviolet light. Inventive methods for producing such material are also disclosed. 11 figs.

  8. Method of electrode fabrication and an electrode for metal chloride...

    Office of Scientific and Technical Information (OSTI)

    Method of electrode fabrication and an electrode for metal chloride battery Title: Method of electrode fabrication and an electrode for metal chloride battery A method of ...

  9. Enforcement Letter, Diversified Metal Products, Inc- October 28, 2004

    Broader source: Energy.gov [DOE]

    Issued to Diversified Metal Products, Inc. related to Transportainer Fabrication Deficiencies for the Waste Isolation Pilot Plant

  10. Fabrication of metallic microstructures by micromolding nanoparticles

    DOE Patents [OSTI]

    Morales, Alfredo M.; Winter, Michael R.; Domeier, Linda A.; Allan, Shawn M.; Skala, Dawn M.

    2002-01-01

    A method is provided for fabricating metallic microstructures, i.e., microcomponents of micron or submicron dimensions. A molding composition is prepared containing an optional binder and nanometer size (1 to 1000 nm in diameter) metallic particles. A mold, such as a lithographically patterned mold, preferably a LIGA or a negative photoresist mold, is filled with the molding composition and compressed. The resulting microstructures are then removed from the mold and the resulting metallic microstructures so provided are then sintered.

  11. Light metal production

    DOE Patents [OSTI]

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  12. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. [Harriman, TN; Anovitz, Lawrence M. [Knoxville, TN; Palmer, Donald A. [Oliver Springs, TN; Beard, James S. [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  13. Design Fabrication and Characterization of Metal Micromachined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for operation at 3 THz have been designed and fabricated using thick gold micromachining. ... Assuming perfectly smooth ideal gold, the calculated loss at 3 THz is 10 dBm. However, ...

  14. METAL PRODUCTION AND CASTING

    DOE Patents [OSTI]

    Magel, T.T.

    1958-03-01

    This patent covers a method and apparatus for collecting the molten metal produced by high temperature metal salt reduction. It consists essentially of subjecting the reaction vessel to centrifugal force in order to force the liberatcd molten metal into a coherent molten mass, and allowing it to solidify there. The apparatus is particularly suitable for use with small quantities of rare metals.

  15. Metallic Fast Reactor Fuel Fabrication for Global Nuclear Energy Partnership

    SciTech Connect (OSTI)

    Douglas E. Burkes; Randall S. Fielding; Douglas L. Porter

    2009-07-01

    Fast reactors are once again being considered for nuclear power generation, in addition to transmutation of long-lived fission products resident in spent nuclear fuels. This re-consideration follows with intense developmental programs for both fuel and reactor design. One of the two leading candidates for next generation fast reactor fuel is metal alloys, resulting primarily from the successes achieved in the 1960s to early 1990s with both the experimental breeding reactor-II and the fast flux test facility. The goal of the current program is to develop and qualify a nuclear fuel system that performs all of the functions of a conventional, fast-spectrum nuclear fuel while destroying recycled actinides, thereby closing the nuclear fuel cycle. In order to meet this goal, the program must develop efficient and safe fuel fabrication processes designed for remote operation. This paper provides an overview of advanced casting processes investigated in the past, and the development of a gaseous diffusion calculation that demonstrates how straightforward process parameter modification can mitigate the loss of volatile minor actinides in the metal alloy melt.

  16. PRODUCTION OF PLUTONIUM METAL

    DOE Patents [OSTI]

    Lyon, W.L.; Moore, R.H.

    1961-01-17

    A process is given for producing plutonium metal by the reduction of plutonium chloride, dissolved in alkali metal chloride plus or minus aluminum chloride, with magnesium or a magnesium-aluminum alloy at between 700 and 800 deg C and separating the plutonium or plutonium-aluminum alloy formed from the salt.

  17. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G.; Anovitz, Lawrence M.; Palmer, Donald A.; Beard, James S.

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  18. Highly efficient and controllable method to fabricate ultrafine metallic nanostructures

    SciTech Connect (OSTI)

    Cai, Hongbing; Zhang, Kun; Pan, Nan E-mail: xpwang@ustc.edu.cn; Luo, Yi; Wang, Xiaoping E-mail: xpwang@ustc.edu.cn; Yu, Xinxin; Tian, Yangchao

    2015-11-15

    We report a highly efficient, controllable and scalable method to fabricate various ultrafine metallic nanostructures in this paper. The method starts with the negative poly-methyl-methacrylate (PMMA) resist pattern with line-width superior to 20 nm, which is obtained from overexposing of the conventionally positive PMMA under a low energy electron beam. The pattern is further shrunk to sub-10 nm line-width through reactive ion etching. Using the patter as a mask, we can fabricate various ultrafine metallic nanostructures with the line-width even less than 10 nm. This ion tailored mask lithography (ITML) method enriches the top-down fabrication strategy and provides potential opportunity for studying quantum effects in a variety of materials.

  19. Simulations of optical sensors fabricated from metallic rods couplers

    SciTech Connect (OSTI)

    Singh, M. R.; Balakrishanan, Shankar

    2014-03-31

    We have developed the optical sensing mechanism of photonic couplers fabricated from the periodically arranged metallic rods. The metallic rod lattice is embedded between two dielectric material waveguides. This structure is called metallic coupler. Using the transfer matrix method, expressions for the reflection and transmission coefficients of electromagnetic wave propagating in waveguides have been obtained. We found that for certain energies, the electromagnetic wave is totally reflected from the coupler. Similarly, for a certain energy range the light is totally transmitted. It has also been found that by changing the periodicity of the metallic rods, the transmitted energy can be reflected. The periodicity of the metallic lattice can be modified by applying an external stress or pressure. In other words, the system can be used as stress and pressure sensors. The present findings can be used to make new types photonic sensors.

  20. Tubular hydrogen permeable metal foil membrane and method of fabrication

    DOE Patents [OSTI]

    Paglieri, Stephen N.; Birdsell, Stephen A.; Barbero, Robert S.; Snow, Ronny C.; Smith, Frank M.

    2006-04-04

    A tubular hydrogen permeable metal membrane and fabrication process comprises obtaining a metal alloy foil having two surfaces, coating the surfaces with a metal or metal alloy catalytic layer to produce a hydrogen permeable metal membrane, sizing the membrane into a sheet with two long edges, wrapping the membrane around an elongated expandable rod with the two long edges aligned and overlapping to facilitate welding of the two together, placing the foil wrapped rod into a surrounding fixture housing with the two aligned and overlapping foil edges accessible through an elongated aperture in the surrounding fixture housing, expanding the elongated expandable rod within the surrounding fixture housing to tighten the foil about the expanded rod, welding the two long overlapping foil edges to one another generating a tubular membrane, and removing the tubular membrane from within the surrounding fixture housing and the expandable rod from with the tubular membrane.

  1. PRODUCTION OF ACTINIDE METAL

    DOE Patents [OSTI]

    Knighton, J.B.

    1963-11-01

    A process of reducing actinide oxide to the metal with magnesium-zinc alloy in a flux of 5 mole% of magnesium fluoride and 95 mole% of magnesium chloride plus lithium, sodium, potassium, calcium, strontium, or barium chloride is presented. The flux contains at least 14 mole% of magnesium cation at 600-- 900 deg C in air. The formed magnesium-zinc-actinide alloy is separated from the magnesium-oxide-containing flux. (AEC)

  2. Method of fabricating a homogeneous wire of inter-metallic alloy

    DOE Patents [OSTI]

    Ohriner, Evan Keith (Knoxville, TN); Blue, Craig Alan (Knoxville, TN)

    2001-01-01

    A method for fabricating a homogeneous wire of inter-metallic alloy comprising the steps of providing a base-metal wire bundle comprising a metal, an alloy or a combination thereof; working the wire bundle through at least one die to obtain a desired dimension and to form a precursor wire; and, controllably heating the precursor wire such that a portion of the wire will become liquid while simultaneously maintaining its desired shape, whereby substantial homogenization of the wire occurs in the liquid state and additional homogenization occurs in the solid state resulting in a homogenous alloy product.

  3. Fabrication and characterization of metal-semiconductor-metal nanorod using template synthesis

    SciTech Connect (OSTI)

    Kim, Kyohyeok; Kwon, Namyong; Hong, Junki; Chung, Ilsub

    2009-07-15

    The authors attempted to fabricate and characterize one dimensional metal-semiconductor-metal (MSM) nanorod using a template. Cadmium selenide (CdSe) and polypyrrole (Ppy) were chosen as n-type and p-type semiconductor materials, respectively, whereas Au was chosen as a metal electrode. The fabrication of the nanorod was achieved by ''template synthesis'' method using polycarbonate membrane. The structure of the fabricated nanorod was analyzed using scanning electron microscopy and energy dispersive spectroscopy. In addition, the electrical properties of MSM nanorods were characterized using scanning probe microscopy (Seiko Instruments, SPA 300 HV) by probing with a conductive cantilever. I-V characteristics as a function of the temperature give the activation energy, as well as the barrier height of a metal-semiconductor contact, which is useful to understand the conduction mechanism of MSM nanorods.

  4. Method for fabricating prescribed flaws in the interior of metals

    DOE Patents [OSTI]

    Hsu, David K.; Thompson, Donald O.

    1989-03-07

    The method for fabricating a metal body having a flaw of predetermined size and shape located therein comprises placing half of the metal powder required to make the metal body in the die of a press and pressing it to create a flat upper surface thereon. A piece of copper foil is cut to the size and shape of the desired interior crack and placed on the upper surface of the powder and centered in position. The remaining powder is then placed in the die to cover the copper foil. The powder is first cold pressed and removed from the press. The powder metal piece is then sintered in a furnace at a temperature above the melting point of the copper and below the melting point of the metal. It is then removed from the furnace, cooled to room temperature, and placed back in the die and pressed further. This procedure results in an interior flaw or crack. Modified forms of the method involve using a press-sinter-press-sinter cycle with the first sinter being below the melting point of the copper and the second sinter being above the melting point of the copper and below the melting point of the metal.

  5. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas Citation Details In-Document Search Title: Metallic Membrane Materials Development for...

  6. Apparatus for the electrolytic production of metals

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1993-01-01

    Improved electrolytic cells for producing metals by the electrolytic reduction of a compound dissolved in a molten electrolyte are disclosed. In the improved cells, at least one electrode includes a protective layer comprising an oxide of the cell product metal formed upon an alloy of the cell product metal and a more noble metal. In the case of an aluminum reduction cell, the electrode can comprise an alloy of aluminum with copper, nickel, iron, or combinations thereof, upon which is formed an aluminum oxide protective layer.

  7. Development of uranium metal targets for {sup 99}Mo production

    SciTech Connect (OSTI)

    Wiencek, T.C.; Hofman, G.L.

    1993-10-01

    A substantial amount of high enriched uranium (HEU) is used for the production of medical-grade {sup 99}Mo. Promising methods of producing irradiation targets are being developed and may lead to the reduction or elimination of this HEU use. To substitute low enriched uranium (LEU) for HEU in the production of {sup 99}Mo, the target material may be changed to uranium metal foil. Methods of fabrication are being developed to simplify assembly and disassembly of the targets. Removal of the uranium foil after irradiation without dissolution of the cladding is a primary goal in order to reduce the amount of liquid radioactive waste material produced in the process. Proof-of-concept targets have been fabricated. Destructive testing indicates that acceptable contact between the uranium foil and the cladding can be achieved. Thermal annealing tests, which simulate the cladding/uranium diffusion conditions during irradiation, are underway. Plans are being made to irradiate test targets.

  8. CASTING SLIPS FOR FABRICATION OF REFRACTORY METAL WARE

    DOE Patents [OSTI]

    Stoddard, S.D.; Nuckolls, D.E.; Cowan, R.E.

    1962-09-01

    A composition is given for slip casting tungsten metal. The composition consists essentially of tungsten metal with an average particle size of 0.9 micron, an organic vehicle such as methyl chloroform, o-xylene, n-butyl acetate, isobutyl acetate, and 1, 1, 2, 2-tetrachlorethane, and a suspending agent such as ethyl cellulose, with the approximate ratio of said vehicle to the tungsten metal being 12 cc of a solution containing from 5 to about 20 grams of said ethyl cellulose in 400 cc of said organic vehicle per 100 grams of metal. (AEC)

  9. Process for the fabrication of aluminum metallized pyrolytic graphite sputtering targets

    DOE Patents [OSTI]

    Makowiecki, Daniel M.; Ramsey, Philip B.; Juntz, Robert S.

    1995-01-01

    An improved method for fabricating pyrolytic graphite sputtering targets with superior heat transfer ability, longer life, and maximum energy transmission. Anisotropic pyrolytic graphite is contoured and/or segmented to match the erosion profile of the sputter target and then oriented such that the graphite's high thermal conductivity planes are in maximum contact with a thermally conductive metal backing. The graphite contact surface is metallized, using high rate physical vapor deposition (HRPVD), with an aluminum coating and the thermally conductive metal backing is joined to the metallized graphite target by one of four low-temperature bonding methods; liquid-metal casting, powder metallurgy compaction, eutectic brazing, and laser welding.

  10. Utilizing Metalized Fabrics for Liquid and Rip Detection and Localization

    SciTech Connect (OSTI)

    Holland, Stephen; Mahan, Cody; Kuhn, Michael J; Rowe, Nathan C

    2013-01-01

    This paper proposes a novel technique for utilizing conductive textiles as a distributed sensor for detecting and localizing liquids (e.g., blood), rips (e.g., bullet holes), and potentially biosignals. The proposed technique is verified through both simulation and experimental measurements. Circuit theory is utilized to depict conductive fabric as a bounded, near-infinite grid of resistors. Solutions to the well-known infinite resistance grid problem are used to confirm the accuracy and validity of this modeling approach. Simulations allow for discontinuities to be placed within the resistor matrix to illustrate the effects of bullet holes within the fabric. A real-time experimental system was developed that uses a multiplexed Wheatstone bridge approach to reconstruct the resistor grid across the conductive fabric and detect liquids and rips. The resistor grid model is validated through a comparison of simulated and experimental results. Results suggest accuracy proportional to the electrode spacing in determining the presence and location of discontinuities in conductive fabric samples. Future work is focused on refining the experimental system to provide more accuracy in detecting and localizing events as well as developing a complete prototype that can be deployed for field testing. Potential applications include intelligent clothing, flexible, lightweight sensing systems, and combat wound detection.

  11. APPARATUS FOR THE PRODUCTION OF LITHIUM METAL

    DOE Patents [OSTI]

    Baker, P.S.; Duncan, F.R.; Greene, H.B.

    1961-08-22

    Methods and apparatus for the production of high-purity lithium from lithium halides are described. The apparatus is provided for continuously contacting a molten lithium halide with molten barium, thereby forming lithium metal and a barium halide, establishing separate layers of these reaction products and unreacted barium and lithium halide, and continuously withdrawing lithium and barium halide from the reaction zone. (AEC)

  12. Solid materials for removing metals and fabrication method

    DOE Patents [OSTI]

    Coronado, Paul R.; Reynolds, John G.; Coleman, Sabre J.

    2004-10-19

    Solid materials have been developed to remove contaminating metals and organic compounds from aqueous media. The contaminants are removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the metals and the organics leaving a purified aqueous stream. The materials are sol-gel and or sol-gel and granulated activated carbon (GAC) mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards the contaminant(s). The contaminated solid materials can then be disposed of or the contaminant can be removed and the solids recycled.

  13. Low resistance barrier layer for isolating, adhering, and passivating copper metal in semiconductor fabrication

    DOE Patents [OSTI]

    Weihs, Timothy P.; Barbee, Jr., Troy W.

    2002-01-01

    Cubic or metastable cubic refractory metal carbides act as barrier layers to isolate, adhere, and passivate copper in semiconductor fabrication. One or more barrier layers of the metal carbide are deposited in conjunction with copper metallizations to form a multilayer characterized by a cubic crystal structure with a strong (100) texture. Suitable barrier layer materials include refractory transition metal carbides such as vanadium carbide (VC), niobium carbide (NbC), tantalum carbide (TaC), chromium carbide (Cr.sub.3 C.sub.2), tungsten carbide (WC), and molybdenum carbide (MoC).

  14. Method of electrode fabrication and an electrode for metal chloride battery

    DOE Patents [OSTI]

    Bloom, I.D.; Nelson, P.A.; Vissers, D.R.

    1993-03-16

    A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 [Omega]cm[sup 2] than those resistivity values of approximately 1.0-1.5 [Omega]cm[sup 2] exhibited by currently available electrodes.

  15. Method of electrode fabrication and an electrode for metal chloride battery

    DOE Patents [OSTI]

    Bloom, Ira D.; Nelson, Paul A.; Vissers, Donald R.

    1993-01-01

    A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 .OMEGA.cm.sup.2 than those resistivity values of approximately 1.0-1.5 .OMEGA.cm.sup.2 exhibited by currently available electrodes.

  16. Using Direct Metal Deposition to Fabricate Mold Plates for an Injection Mold Machine Allowing for the Evaluation of Cost Effective Near-Sourcing Opportunities in Larger, High Volume Consumer Products

    SciTech Connect (OSTI)

    Duty, Chad E; Groh, Bill

    2014-10-31

    ORNL collaborated with Radio Systems Corporation to investigate additive manufacturing (AM) of mold plates for plastic injection molding by direct metal deposition. The team s modelling effort identified a 100% improvement in heat transfer through use of conformal cooling lines that could be built into the mold using a revolutionary design enabled by additive manufacturing. Using the newly installed laser deposition system at the ORNL Manufacturing Demonstration Facility (MDF) a stainless steel mold core was printed.

  17. Method for fabricating an ignitable heterogeneous stratified metal structure

    DOE Patents [OSTI]

    Barbee, Jr., Troy W.; Weihs, Timothy

    1996-01-01

    A multilayer structure has a selectable, (i) propagating reaction front velocity V, (ii) reaction initiation temperature attained by application of external energy and (iii) amount of energy delivered by a reaction of alternating unreacted layers of the multilayer structure. Because V is selectable and controllable, a variety of different applications for the multilayer structures are possible, including but not limited to their use as ignitors, in joining applications, in fabrication of new materials, as smart materials and in medical applications and devices. The multilayer structure has a period D, and an energy release rate constant K. Two or more alternating unreacted layers are made of different materials and separated by reacted zones. The period D is equal to a sum of the widths of each single alternating reaction layer of a particular material, and also includes a sum of reacted zone widths, t.sub.i, in the period D. The multilayer structure has a selectable propagating reaction front velocity V, where V=K(1/D.sup.n).times.[1-(t.sub.i /D)]and n is about 0.8 to 1.2.

  18. Method for fabricating an ignitable heterogeneous stratified metal structure

    DOE Patents [OSTI]

    Barbee, T.W. Jr.; Weihs, T.

    1996-08-20

    A multilayer structure has a selectable: (1) propagating reaction front velocity V; (2) reaction initiation temperature attained by application of external energy; and (3) amount of energy delivered by a reaction of alternating unreacted layers of the multilayer structure. Because V is selectable and controllable, a variety of different applications for the multilayer structures are possible, including but not limited to their use as igniters, in joining applications, in fabrication of new materials, as smart materials and in medical applications and devices. The multilayer structure has a period D, and an energy release rate constant K. Two or more alternating unreacted layers are made of different materials and separated by reacted zones. The period D is equal to a sum of the widths of each single alternating reaction layer of a particular material, and also includes a sum of reacted zone widths, t{sub i}, in the period D. The multilayer structure has a selectable propagating reaction front velocity V, where V=K(1/D{sup n}){times}[1-(t{sub i}/D)] and n is about 0.8 to 1.2. 8 figs.

  19. Process for production of a metal hydride

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-12

    A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.

  20. Process for the fabrication of aluminum metallized pyrolytic graphite sputtering targets

    DOE Patents [OSTI]

    Makowiecki, D.M.; Ramsey, P.B.; Juntz, R.S.

    1995-07-04

    An improved method is disclosed for fabricating pyrolytic graphite sputtering targets with superior heat transfer ability, longer life, and maximum energy transmission. Anisotropic pyrolytic graphite is contoured and/or segmented to match the erosion profile of the sputter target and then oriented such that the graphite`s high thermal conductivity planes are in maximum contact with a thermally conductive metal backing. The graphite contact surface is metallized, using high rate physical vapor deposition (HRPVD), with an aluminum coating and the thermally conductive metal backing is joined to the metallized graphite target by one of four low-temperature bonding methods; liquid-metal casting, powder metallurgy compaction, eutectic brazing, and laser welding. 11 figs.

  1. Titanium Metal Powder Production by the Plasma Quench Process

    SciTech Connect (OSTI)

    R. A. Cordes; A. Donaldson

    2000-09-01

    The goals of this project included the scale-up of the titanium hydride production process to a production rate of 50 kg/hr at a purity level of 99+%. This goal was to be achieved by incrementally increasing the production capability of a series of reactor systems. This methodic approach was designed to allow Idaho Titanium Technologies to systematically address the engineering issues associated with plasma system performance, and powder collection system design and performance. With quality powder available, actual fabrication with the titanium hydride was to be pursued. Finally, with a successful titanium production system in place, the production of titanium aluminide was to be pursued by the simultaneously injection of titanium and aluminum precursors into the reactor system. Some significant accomplishments of the project are: A unique and revolutionary torch/reactor capable of withstanding temperatures up to 5000 C with high thermal efficiency has been operated. The dissociation of titanium tetrachloride into titanium powder and HC1 has been demonstrated, and a one-megawatt reactor potentially capable of producing 100 pounds per hour has been built, but not yet operated at the powder level. The removal of residual subchlorides and adsorbed HC1 and the sintering of powder to form solid bodies have been demonstrated. The production system has been operated at production rates up to 40 pounds per hour. Subsequent to the end of the project, Idaho Titanium Technologies demonstrated that titanium hydride powder can indeed be sintered into solid titanium metal at 1500 C without sintering aids.

  2. Properties of near-net shape metallic components made by the directed light fabrication process

    SciTech Connect (OSTI)

    Lewis, G.K.; Milewski, J.O.; Thoma, D.B.; Nemec, R.B.

    1997-10-01

    Directed Light Fabrication (DLF) is a process invented at Los Alamos National Laboratory that can be used to fuse any metal powder directly to a fully dense, near-net shape component with full structural integrity. A solid model design of a desired component is first developed on a computer work station. A motion path, produced from the solid model definition, is translated to actual machine commands through a post-processor, specific to the deposition equipment. The DLF process uses a multi-axis positioning system to move the laser focal zone over the part cross section defined by the part boundaries and desired layer thickness. Metal powders, delivered in an argon stream, enter the focal zone where they melt and continuously form a molten pool of material that moves with the laser focal spot. Position and movement of the spot is controlled through the post-processor. Successive cross-sectional layers are added by advancing the spot one layer thickness beyond the previous layer until the entire part is deposited. The system has 4 powder feeders attached for co-deposition of multiple materials to create alloys at the focal zone or form dissimilar metal joint combinations by changing powder composition from one material to another. Parts produced by the DLF process vary in complexity from simple bulk solid forms to detailed components fabricated from difficult to process metals and alloys. Parts have been deposited at rates up to 33 cm{sup 3}/hr with 12 cm{sup 3}/hr more typical. Feasibility of processing any metal ranging in melting point from aluminium to tungsten has been demonstrated. Mechanical properties for bulk DLF deposits of three alloy powders were measured for this study. Ti-6Al-4V and 316 stainless steel powders were fabricated into rectangular bar, and Inconel 690 powder was fabricated into a solid cylinder.

  3. A U. S. Perspective on Fast Reactor Fuel Fabrication Technology and Experience Part I: Metal Fuels and Assembly Design

    SciTech Connect (OSTI)

    Douglas E. Burkes; Randall S. Fielding; Douglas L. Porter; Douglas C. Crawford; Mitchell K. Meyer

    2009-06-01

    This paper is Part I of a review focusing on the United States experience with metallic fast reactor fuel fabrication and assembly design for the Experimental Breeder Reactor-II and the Fast Flux Test Facility, and it also refers to the impact of development in other nations. Experience with metal fuel fabrication in the United States is extensive, including over 60 years of research conducted by the government, national laboratories, industry, and academia. This experience has culminated into a foundation of research and resulted in significant improvements to the technologies employed to fabricate metallic fast reactor fuel. This part of the review documents the current state of fuel fabrication technologies for metallic fuels, some of the challenges faced by previous researchers, and how these were overcome. Knowledge gained from reviewing previous investigations will aid both researchers and policy makers in forming future decisions relating to nuclear fuel fabrication technologies.

  4. Method for the production of fabricated hollow microspheroids...

    Office of Scientific and Technical Information (OSTI)

    Solvent exchange produces a fabricated hollow microsphere comprised of a densified outer skin surrounding a macroporous inner layer, which surrounds a hollow interior. In an ...

  5. Novel electrochemical method of fast and reproducible fabrication of metallic nanoelectrodes

    SciTech Connect (OSTI)

    Silva, E. L. Silva, R. F.; Oliveira, F. J.; Zheludkevich, M.

    2014-09-15

    A novel electrochemical wire etching method of fabrication of ultrasharp nanoelectrodes is reported. Tungsten wires can be sharpened to less than 10 nm tip radius in a reproducible manner in less than 1 min by using controllable hydrodynamic electrolyte flow combined with optimized electrochemical etching parameters. The method relies on the variations of the electric field at the surface of a metal wire, while the electrolyte solution is in motion, rather than on the ionic gradient generated in a static solution.

  6. Method and device for fabricating dispersion fuel comprising fission product collection spaces

    SciTech Connect (OSTI)

    Shaber, Eric L; Fielding, Randall S

    2015-05-05

    A method of fabricating a nuclear fuel comprising a fissile material, one or more hollow microballoons, a phenolic resin, and metal matrix. The fissile material, phenolic resin and the one or more hollow microballoons are combined. The combined fissile material, phenolic resin and the hollow microballoons are heated sufficiently to form at least some fissile material carbides creating a nuclear fuel particle. The resulting nuclear fuel particle comprises one or more fission product collection spaces. In a preferred embodiment, the fissile material, phenolic resin and the one or more hollow microballoons are combined by forming the fissile material into microspheres. The fissile material microspheres are then overcoated with the phenolic resin and microballoon. In another preferred embodiment, the fissile material, phenolic resin and the one or more hollow microballoons are combined by overcoating the microballoon with the fissile material, and phenolic resin.

  7. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  8. Anisotropic porous metals production by melt processing

    SciTech Connect (OSTI)

    Shapovalov, V.; Boiko, L.; Baldwin, M.D.; Maguire, M.C.; Zanner, F.J.

    1997-02-01

    The collapse of the Soviet Union has left many of its scientific institutes and technical universities without their traditional backbone of financial support. In an effort to stem the export of science to nations advocating nuclear proliferation, and to acquire potentially useful technology, several US government-sponsored programs have arise to mine the best of former USSR scientific advances. In the field of metallurgy, the earliest institutes to be investigated by Sandia National Laboratories are located in Ukraine. In particular, scientists at the State Metallurgical Academy have developed unique porous metals, resembling what could be described as gas-solid ``eutectic``. While porous metals are available in the US and other western countries, none have the remarkable structure and properties of these materials. Sandia began a collaborative program with the Ukrainian scientists to bring this technology to the US, verify the claims regarding these materials, and begin production of the so-called Gasars. This paper will describe the casting process technology and metallurgy associated with the production of Gasars, and will review the progress of the collaborative project.

  9. Method for the production of fabricated hollow microspheroids

    SciTech Connect (OSTI)

    Wickramanayake, Shan; Luebke, David R.

    2015-06-09

    The method relates to the fabrication of a polymer microspheres comprised of an asymmetric layer surrounding a hollow interior. The fabricated hollow microsphere is generated from a nascent hollow microsphere comprised of an inner core of core fluid surrounded by a dope layer of polymer dope, where the thickness of the dope layer is at least 10% and less than 50% of the diameter of the inner core. The nascent hollow microsphere is exposed to a gaseous environment, generating a vitrified hollow microsphere, which is subsequently immersed in a coagulation bath. Solvent exchange produces a fabricated hollow microsphere comprised of a densified outer skin surrounding a macroporous inner layer, which surrounds a hollow interior. In an embodiment, the polymer is a polyimide or a polyamide-imide, and the non-solvent in the core fluid and the coagulation bath is water. The fabricated hollow microspheres are particularly suited as solvent supports for gas separation processes.

  10. Fabrication and Characterization of Graded Impedance Gas Gun Impactors from Tape Cast Metal Powders

    SciTech Connect (OSTI)

    Martin, L P; Nguyen, J H

    2005-11-21

    Fabrication of compositionally graded structures for use as light-gas gun impactors has been demonstrated using a tape casting technique. Mixtures of metal powders in the Mg-Cu system were cast into a series of tapes with uniform compositions ranging from 100% Mg to 100% Cu. The individual compositions were fabricated into monolithic pellets for characterization by laminating multiple layers together, thermally removing the organics, and hot-pressing to near-full density. The pellets were characterized by optical and scanning electron microscopy, X-ray diffraction, and measurement of density and sound wave velocity. The density and acoustic impedance were observed to vary monotonically (and nearly linearly) with composition. Graded structures were fabricated by stacking layers of different compositions in a sequence calculated to yield a desired acoustic impedance profile. The measured physical properties of the graded structures compare favorably with those predicted from the monolithic-pellet characteristics. Fabrication of graded impactors by this technique is of significant interest for providing improved control of the pressure profile in gas gun experiments.

  11. Waste minimization assessment for a manufacturer of iron castings and fabricated sheet metal parts

    SciTech Connect (OSTI)

    Fleischman, M.; Harris, J.J.; Handmaker, A.; Looby, G.P.

    1995-08-01

    The U.S. Environmental Protection Agency (EPA) has funded a pilot project to assist small and medium-size manufacturers who want to minimize their generation of waste but who lack the expertise to do so. Waste Minimization Assessment Centers (WMACs) were established at selected universities and procedures were adapted from the EPA Waste Minimization Opportunity Assessment Manual. That document has been superseded by the Facility Pollution Prevention Guide. The WMAC team at the University of Louisville performed an assessment at a plant that manufactures iron castings and fabricated sheet metal parts. Foundry operations include mixing and mold formation, core making, metal pouring, shakeout, finishing, and painting. Cutting, shaping, and welding are the principal metal fabrication operations. The team`s report, detailing findings and recommendations indicated that paint-related wastes are generated in large quantities, and that significant waste reduction and cost savings could be realized by installing a dry powder coating system or by replacing conventional air spray paint guns with high-volume low-pressure spray guns. This research brief was developed by the principal investigators and EPA`s National Risk Management Research Laboratory, Cincinnati, OH, to announce key findings of an ongoing research project that is fully documented in a separate report of the same title available from University City Science Center.

  12. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, Richard S.; Slegeir, William A.; Foran, Michael T.

    1984-01-01

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150.degree.-260.degree. C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO.sub.4 and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect.

  13. Catalytic production of metal carbonyls from metal oxides

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

    1984-01-06

    This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

  14. New Metallization Technique Suitable for 6-MW Pilot Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metallization Technique Suitable for 6-MW Pilot Production of Efficient Multicrystalline Solar Cells Using Upgraded Metallurgical Silicon: Final Technical Progress Report, December ...

  15. Production of aluminum metal by electrolysis of aluminum sulfide

    DOE Patents [OSTI]

    Minh, Nguyen Q.; Loutfy, Raouf O.; Yao, Neng-Ping

    1984-01-01

    Production of metallic aluminum by the electrolysis of Al.sub.2 S.sub.3 at 700.degree.-800.degree. C. in a chloride melt composed of one or more alkali metal chlorides, and one or more alkaline earth metal chlorides and/or aluminum chloride to provide improved operating characteristics of the process.

  16. Process for improving metal production in steelmaking processes

    DOE Patents [OSTI]

    Pal, Uday B.; Gazula, Gopala K. M.; Hasham, Ali

    1996-01-01

    A process and apparatus for improving metal production in ironmaking and steelmaking processes is disclosed. The use of an inert metallic conductor in the slag containing crucible and the addition of a transition metal oxide to the slag are the disclosed process improvements.

  17. Process for improving metal production in steelmaking processes

    DOE Patents [OSTI]

    Pal, U.B.; Gazula, G.K.M.; Hasham, A.

    1996-06-18

    A process and apparatus for improving metal production in ironmaking and steelmaking processes is disclosed. The use of an inert metallic conductor in the slag containing crucible and the addition of a transition metal oxide to the slag are the disclosed process improvements. 6 figs.

  18. PRODUCTION OF URANIUM METAL BY CARBON REDUCTION

    DOE Patents [OSTI]

    Holden, R.B.; Powers, R.M.; Blaber, O.J.

    1959-09-22

    The preparation of uranium metal by the carbon reduction of an oxide of uranium is described. In a preferred embodiment of the invention a charge composed of carbon and uranium oxide is heated to a solid mass after which it is further heated under vacuum to a temperature of about 2000 deg C to produce a fused uranium metal. Slowly ccoling the fused mass produces a dendritic structure of uranium carbide in uranium metal. Reacting the solidified charge with deionized water hydrolyzes the uranium carbide to finely divide uranium dioxide which can be separated from the coarser uranium metal by ordinary filtration methods.

  19. Quantum confinement effect in cheese like silicon nano structure fabricated by metal induced etching

    SciTech Connect (OSTI)

    Saxena, Shailendra K. Sahu, Gayatri; Sagdeo, Pankaj R.; Kumar, Rajesh

    2015-08-28

    Quantum confinement effect has been studied in cheese like silicon nano-structures (Ch-SiNS) fabricated by metal induced chemical etching using different etching times. Scanning electron microscopy is used for the morphological study of these Ch-SiNS. A visible photoluminescence (PL) emission is observed from the samples under UV excitation at room temperature due to quantum confinement effect. The average size of Silicon Nanostructures (SiNS) present in the samples has been estimated by bond polarizability model using Raman Spectroscopy from the red-shift observed from SiNSs as compared to its bulk counterpart. The sizes of SiNS present in the samples decreases as etching time increase from 45 to 75 mintunes.

  20. Fabrication of carbon nanotube films from alkyne-transition metal complexes

    DOE Patents [OSTI]

    Iyer, Vivekanantan S. (Delft, NL); Vollhardt, K. Peter C. (Oakland, CA)

    2007-08-28

    A simple method for the production or synthesis of carbon nanotubes as free-standing films or nanotube mats by the thermal decomposition of transition metal complexed alkynes with aryl, alkyl, alkenyl, or alkynyl substituents. In particular, transition metal (e.g. Co, Ni, Fe, Mo) complexes of diarylacetylenes, e.g. diphenylacetylene, and solid mixtures of these complexes with suitable, additional carbon sources are heated in a vessel. More specifically, the heating of the transition metal complex is completed at a temperature between 400-800.degree. C. and more particularly 550-700.degree. C. for between 0.1 to 24 hours and more particularly 0.5-3 hours in a sealed vessel under a partial pressure of argon or helium.

  1. The Electrolytic Production of Metallic Uranium

    DOE Patents [OSTI]

    Rosen, R.

    1950-08-22

    This patent covers a process for producing metallic uranium by electrolyzing uranium tetrafluoride at an elevated temperature in a fused bath consisting essentially of mixed alkali and alkaline earth halides.

  2. Fabrication of metal matrix composite by semi-solid powder processing

    SciTech Connect (OSTI)

    Wu, Yufeng

    2012-11-28

    Various metal matrix composites (MMCs) are widely used in the automotive, aerospace and electrical industries due to their capability and flexibility in improving the mechanical, thermal and electrical properties of a component. However, current manufacturing technologies may suffer from insufficient process stability and reliability and inadequate economic efficiency and may not be able to satisfy the increasing demands placed on MMCs. Semi-solid powder processing (SPP), a technology that combines traditional powder metallurgy and semi-solid forming methods, has potential to produce MMCs with low cost and high efficiency. In this work, the analytical study and experimental investigation of SPP on the fabrication of MMCs were explored. An analytical model was developed to understand the deformation mechanism of the powder compact in the semi-solid state. The densification behavior of the Al6061 and SiC powder mixtures was investigated with different liquid fractions and SiC volume fractions. The limits of SPP were analyzed in terms of reinforcement phase loading and its impact on the composite microstructure. To explore adoption of new materials, carbon nanotube (CNT) was investigated as a reinforcing material in aluminum matrix using SPP. The process was successfully modeled for the mono-phase powder (Al6061) compaction and the density and density distribution were predicted. The deformation mechanism at low and high liquid fractions was discussed. In addition, the compaction behavior of the ceramic-metal powder mixture was understood, and the SiC loading limit was identified by parametric study. For the fabrication of CNT reinforced Al6061 composite, the mechanical alloying of Al6061-CNT powders was first investigated. A mathematical model was developed to predict the CNT length change during the mechanical alloying process. The effects of mechanical alloying time and processing temperature during SPP were studied on the mechanical, microstructural and

  3. Electricity in the production of metals: From aluminum to zinc

    SciTech Connect (OSTI)

    Evans, J.W.

    1995-04-01

    This article treats some electrometallurgical and electromagnetic metals. but it opens with an examination of whether there is ``electricity`` (i.e., vitality) in the primary metals industries, particularly within the United States of America. That question is examined in terms of the economics of two examples: aluminum and zinc. Then, three examples are provided of potential improvements in the production of metals arising front industrial and university research: use of new electrode materials in Hall-Heroult cells to reduce energy consumption in aluminum smelting, the fluidized bed electrowinning of copper and other metals, and the employment of electromagnetic forces in metals processing, particularly electromagnetic casting. The article concludes with observations on the paucity of United States support for research and development (R and D) in primary metals production, compared with that of the industrial activities and of other nations. and suggests a prognosis for the future of arcade research and teaching in extractive and process metallurgy.

  4. Apparatus and method for the electrolytic production of metals

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1991-01-01

    Improved electrolytic cells and methods for producing metals by electrolytic reduction of a compound dissolved in a molten electrolyte are disclosed. In the improved cells and methods, a protective surface layer is formed upon at least one electrode in the electrolytic reduction cell and, optionally, upon the lining of the cell. This protective surface layer comprises a material that, at the operating conditions of the cell: (a) is not substantially reduced by the metal product; (b) is not substantially reactive with the cell electrolyte to form materials that are reactive with the metal product; and, (c) has an electrochemical potential that is more electronegative than that of the compound undergoing electrolysis to produce the metal product of the cell. The protective surface layer can be formed upon an electrode metal layer comprising a material, the oxide of which also satisfies the protective layer selection criteria. The protective layer material can also be used on the surface of a cell lining.

  5. Metallic Membrane Materials Development for Hydrogen Production from Coal

    Office of Scientific and Technical Information (OSTI)

    Derived Syngas (Conference) | SciTech Connect Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas Citation Details In-Document Search Title: Metallic Membrane Materials Development for Hydrogen Production from Coal Derived Syngas The goals of Office of Clean Coal are: (1) Improved energy security; (2) Reduced green house gas emissions; (3) High tech job creation; and (4) Reduced energy costs. The goals of the Hydrogen from Coal Program are: (1) Prove the

  6. Characterization of an aluminum alloy hemispherical shell fabricated via direct metal laser melting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Holesinger, T. G.; Carpenter, J. S.; Lienert, T. J.; Patterson, B. M.; Papin, P. A.; Swenson, H.; Cordes, N. L.

    2016-01-11

    The ability of additive manufacturing to directly fabricate complex shapes provides characterization challenges for part qualification. The orientation of the microstructures produced by these processes will change relative to the surface normal of a complex part. In this work, the microscopy and x-ray tomography of an AlSi10Mg alloy hemispherical shell fabricated using powder bed metal additive manufacturing are used to illustrate some of these challenges. The shell was manufactured using an EOS M280 system in combination with EOS-specified powder and process parameters. The layer-by-layer process of building the shell with the powder bed additive manufacturing approach results in a position-dependentmore » microstructure that continuously changes its orientation relative to the shell surface normal. X-ray tomography was utilized to examine the position-dependent size and distribution of porosity and surface roughness in the 98.6% dense part. Optical and electron microscopy were used to identify global and local position-dependent structures, grain morphologies, chemistry, and precipitate sizes and distributions. The rapid solidification processes within the fusion zone (FZ) after the laser transit results in a small dendrite size. Cell spacings taken from the structure in the middle of the FZ were used with published relationships to estimate a cooling rate of ~9 × 105 K/s. Uniformly-distributed, nanoscale Si precipitates were found within the primary α-Al grains. A thin, distinct boundary layer containing larger α-Al grains and extended regions of the nanocrystalline divorced eutectic material surrounds the FZ. Moreover, subtle differences in the composition between the latter layer and the interior of the FZ were noted with scanning transmission electron microscopy (STEM) spectral imaging.« less

  7. Recycling Of Uranium- And Plutonium-Contaminated Metals From Decommissioning Of The Hanau Fuel Fabrication Plant

    SciTech Connect (OSTI)

    Kluth, T.; Quade, U.; Lederbrink, F. W.

    2003-02-26

    Decommissioning of a nuclear facility comprises not only actual dismantling but also, above all, management of the resulting residual materials and waste. Siemens Decommissioning Projects (DP) in Hanau has been involved in this task since 1995 when the decision was taken to decommission and dismantle the Hanau Fuel Fabrication Plant. Due to the decommissioning, large amounts of contaminated steel scrap have to be managed. The contamination of this metal scrap can be found almost exclusively in the form of surface contamination. Various decontamination technologies are involved, as there are blasting and wiping. Often these methods are not sufficient to meet the free release limits. In these cases, SIEMENS has decided to melt the scrap at Siempelkamp's melting plant. The plant is licensed according to the German Radiation Protection Ordinance Section 7 (issue of 20.07.2001). The furnace is a medium frequency induction type with a load capacity of 3.2 t and a throughput of 2 t/h for steel melting. For safety reasons, the furnace is widely operated by remote handling. A highly efficient filter system of cyclone, bag filter and HEPA-filter in two lines retains the dust and aerosol activity from the off-gas system. The slag is solidified at the surface of the melt and gripped before pouring the liquid iron into a chill. Since 1989, in total 15,000 t have been molten in the plant, 2,000 t of them having been contaminated steel scrap from the decommissioning of fuel fabrication plants. Decontamination factors could be achieved between 80 and 100 by the high affinity of the uranium to the slag former. The activity is transferred to the slag up to nearly 100 %. Samples taken from metal, slag and dust are analyzed by gamma measurements of the 186 keV line of U235 and the 1001 keV line of Pa234m for U238. All produced ingots showed a remaining activity less than 1 Bq/g and could be released for industrial reuse.

  8. Production of sintered porous metal fluoride pellets

    DOE Patents [OSTI]

    Anderson, L.W.; Stephenson, M.J.

    1973-12-25

    Porous pellets characterized by a moderately reactive crust and a softer core of higher reactivity are produced by forming agglomerates containing a metal fluoride powder and a selected amount ofwater. The metal fluoride is selected to be sinterable and essentially non-reactive with gaseous fluorinating agents. The agglomerates are contacted with a gaseous fluorinating agent under controlled conditions whereby the heat generated by localized reaction of the agent and water is limited to values effccting bonding by localized sintering. Porous pellets composed of cryolite (Na/sub 3/AlF/sub 6/) can be used to selectively remove trace quantities of niobium pentafluoride from a feed gas consisting predominantly of uranium hexafluoride. (Official Gazette)

  9. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    PRODUCTION; GREENHOUSE GASES The goals of Office of Clean Coal are: (1) Improved energy security; (2) Reduced green house gas emissions; (3) High tech job creation; and...

  10. For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua; Weirauch, Douglas A.

    2002-01-01

    A cermet inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode comprises a ceramic phase including an oxide of Ni, Fe and M, where M is at least one metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths, preferably Zn and/or Co. Preferred ceramic compositions comprise Fe.sub.2 O.sub.3, NiO and ZnO or CoO. The cermet inert anode also comprises a metal phase such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. A preferred metal phase comprises Cu and Ag. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

  11. Nonconsumable electrode assembly and use thereof for the electrolytic production of metals and silicon

    DOE Patents [OSTI]

    Byrne, Stephen C.; Ray, Siba P.

    1984-01-01

    A nonconsumable electrode assembly suitable for use in the production of metal by electrolytic reduction of a metal compound dissolved in a molten salt, the assembly comprising a metal conductor attached to a ceramic electrode body by a metal bond on a portion of the body having a level of free metal or metal alloy sufficient to effect a metal bond.

  12. Graphitized hollow carbon spheres and yolk-structured carbon spheres fabricated by metal-catalyst-free chemical vapor deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xufan; Chi, Miaofang; Mahurin, Shannon Mark; Liu, Rui; Chuang, Yen -Jun; Dai, Sheng; Pan, Zhengwei

    2016-01-18

    Hard-sphere-templating method has been widely used to synthesize hollow carbon spheres (HCSs), in which the spheres were firstly coated with a carbon precursor, followed by carbonization and core removal. The obtained HCSs are generally amorphous or weakly graphitized (with the help of graphitization catalysts). In this work, we report on the fabrication of graphitized HCSs and yolk–shell Au@HCS nanostructures using a modified templating method, in which smooth, uniform graphene layers were grown on SiO2 spheres or Au@SiO2 nanoparticles via metal-catalyst-free chemical vapor deposition (CVD) of methane. Furthermore, our work not only provides a new method to fabricate high-quality, graphitized HCSsmore » but also demonstrates a reliable approach to grow quality graphene on oxide surfaces using CVD without the presence of metal catalysts.« less

  13. Process for continuous production of metallic uranium and uranium alloys

    DOE Patents [OSTI]

    Hayden, H.W. Jr.; Horton, J.A.; Elliott, G.R.B.

    1995-06-06

    A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO{sub 3}), or any other substantially stable uranium oxide, to form the uranium dioxide (UO{sub 2}). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl{sub 4}), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation. 4 figs.

  14. Process for continuous production of metallic uranium and uranium alloys

    DOE Patents [OSTI]

    Hayden, Jr., Howard W.; Horton, James A.; Elliott, Guy R. B.

    1995-01-01

    A method is described for forming metallic uranium, or a uranium alloy, from uranium oxide in a manner which substantially eliminates the formation of uranium-containing wastes. A source of uranium dioxide is first provided, for example, by reducing uranium trioxide (UO.sub.3), or any other substantially stable uranium oxide, to form the uranium dioxide (UO.sub.2). This uranium dioxide is then chlorinated to form uranium tetrachloride (UCl.sub.4), and the uranium tetrachloride is then reduced to metallic uranium by reacting the uranium chloride with a metal which will form the chloride of the metal. This last step may be carried out in the presence of another metal capable of forming one or more alloys with metallic uranium to thereby lower the melting point of the reduced uranium product. The metal chloride formed during the uranium tetrachloride reduction step may then be reduced in an electrolysis cell to recover and recycle the metal back to the uranium tetrachloride reduction operation and the chlorine gas back to the uranium dioxide chlorination operation.

  15. Metal finishing and vacuum processes groups, Materials Fabrication Division progress report, March-May 1984

    SciTech Connect (OSTI)

    Dini, J.W.; Romo, J.G.; Jones, L.M.

    1984-07-11

    Progress is reported in fabrication and coating activities being conducted for the weapons program, nuclear test program, nuclear design program, magnetic fusion program, and miscellaneous applications. (DLC)

  16. Diffusion welded nonconsumable electrode assembly and use thereof for electrolytic production of metals and silicon

    DOE Patents [OSTI]

    Byrne, Stephen C.; Vasudevan, Asuri K.

    1984-01-01

    A nonconsumable electrode assembly suitable for use in the production of metal by electrolytic reduction of a metal compound dissolved in a molten salt, the assembly comprising a metal conductor diffusion welded to a portion of a ceramic electrode body having a level of free metal or metal alloy sufficient to effect a metal bond.

  17. Comparative Study of Laboratory-Scale and Prototypic Production-Scale Fuel Fabrication Processes and Product Characteristics

    SciTech Connect (OSTI)

    Douglas W. Marshall

    2014-10-01

    An objective of the High Temperature Gas Reactor fuel development and qualification program for the United States Department of Energy has been to qualify fuel fabricated in prototypic production-scale equipment. The quality and characteristics of the tristructural isotropic coatings on fuel kernels are influenced by the equipment scale and processing parameters. Some characteristics affecting product quality were suppressed while others have become more significant in the larger equipment. Changes to the composition and method of producing resinated graphite matrix material has eliminated the use of hazardous, flammable liquids and enabled it to be procured as a vendor-supplied feed stock. A new method of overcoating TRISO particles with the resinated graphite matrix eliminates the use of hazardous, flammable liquids, produces highly spherical particles with a narrow size distribution, and attains product yields in excess of 99%. Compact fabrication processes have been scaled-up and automated with relatively minor changes to compact quality to manual laboratory-scale processes. The impact on statistical variability of the processes and the products as equipment was scaled are discussed. The prototypic production-scale processes produce test fuels that meet fuel quality specifications.

  18. Updated Life-Cycle Assessment of Aluminum Production and Semi-fabrication for the GREET Model

    SciTech Connect (OSTI)

    Dai, Qiang; Kelly, Jarod C.; Burnham, Andrew; Elgowainy, Amgad

    2015-09-01

    This report serves as an update for the life-cycle analysis (LCA) of aluminum production based on the most recent data representing the state-of-the-art of the industry in North America. The 2013 Aluminum Association (AA) LCA report on the environmental footprint of semifinished aluminum products in North America provides the basis for the update (The Aluminum Association, 2013). The scope of this study covers primary aluminum production, secondary aluminum production, as well as aluminum semi-fabrication processes including hot rolling, cold rolling, extrusion and shape casting. This report focuses on energy consumptions, material inputs and criteria air pollutant emissions for each process from the cradle-to-gate of aluminum, which starts from bauxite extraction, and ends with manufacturing of semi-fabricated aluminum products. The life-cycle inventory (LCI) tables compiled are to be incorporated into the vehicle cycle model of Argonne National Laboratory’s Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) Model for the release of its 2015 version.

  19. Production of negative hydrogen ions on metal grids

    SciTech Connect (OSTI)

    Oohara, W.; Maetani, Y.; Takeda, Takashi; Takeda, Toshiaki; Yokoyama, H.; Kawata, K.

    2015-03-15

    Negative hydrogen ions are produced on a nickel grid with positive-ion irradiation. In order to investigate the production mechanism, a copper grid without the chemisorption of hydrogen atoms and positive helium ions without negative ionization are used for comparison. Positive hydrogen ions reflected on the metal surface obtain two electrons from the surface and become negatively ionized. It is found that the production yield of negative ions by desorption ionization of chemisorbed hydrogen atoms seems to be small, and the production is a minor mechanism.

  20. Thin-Film Solar Cell Fabricated on a Flexible Metallic Substrate

    DOE Patents [OSTI]

    Tuttle, J. R.; Noufi, R.; Hasoon, F. S.

    2006-05-30

    A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).

  1. Thin-film solar cell fabricated on a flexible metallic substrate

    DOE Patents [OSTI]

    Tuttle, John R.; Noufi, Rommel; Hasoon, Falah S.

    2006-05-30

    A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).

  2. FABRICATION PROCESS AND PRODUCT QUALITY IMPROVEMENTS IN ADVANCED GAS REACTOR UCO KERNELS

    SciTech Connect (OSTI)

    Charles M Barnes

    2008-09-01

    A major element of the Advanced Gas Reactor (AGR) program is developing fuel fabrication processes to produce high quality uranium-containing kernels, TRISO-coated particles and fuel compacts needed for planned irradiation tests. The goals of the AGR program also include developing the fabrication technology to mass produce this fuel at low cost. Kernels for the first AGR test (“AGR-1) consisted of uranium oxycarbide (UCO) microspheres that werre produced by an internal gelation process followed by high temperature steps tot convert the UO3 + C “green” microspheres to first UO2 + C and then UO2 + UCx. The high temperature steps also densified the kernels. Babcock and Wilcox (B&W) fabricated UCO kernels for the AGR-1 irradiation experiment, which went into the Advance Test Reactor (ATR) at Idaho National Laboratory in December 2006. An evaluation of the kernel process following AGR-1 kernel production led to several recommendations to improve the fabrication process. These recommendations included testing alternative methods of dispersing carbon during broth preparation, evaluating the method of broth mixing, optimizing the broth chemistry, optimizing sintering conditions, and demonstrating fabrication of larger diameter UCO kernels needed for the second AGR irradiation test. Based on these recommendations and requirements, a test program was defined and performed. Certain portions of the test program were performed by Oak Ridge National Laboratory (ORNL), while tests at larger scale were performed by B&W. The tests at B&W have demonstrated improvements in both kernel properties and process operation. Changes in the form of carbon black used and the method of mixing the carbon prior to forming kernels led to improvements in the phase distribution in the sintered kernels, greater consistency in kernel properties, a reduction in forming run time, and simplifications to the forming process. Process parameter variation tests in both forming and sintering steps led

  3. Recent developments in high purity niobium metal production at CBMM

    SciTech Connect (OSTI)

    Abdo, Gustavo Giovanni Ribeiro Sousa, Clovis Antonio de Faria Guimarães, Rogério Contato Ribas, Rogério Marques Vieira, Alaércio Salvador Martins Menezes, Andréia Duarte Fridman, Daniel Pallos Cruz, Edmundo Burgos

    2015-12-04

    CBMM is a global supplier of high quality niobium products including pure niobium, the focus of this paper. CBMM’s position has been consolidated over three decades of producing high purity niobium metal ingots. The company supplies, among other products, commercial and reactor grade niobium ingots. One of the main uses of CBMM’s ingots is for the manufacture of particle accelerators (superconducting radio frequency – SRF – cavities), where the purity and homogeneity of niobium metal is essentially important for good performance. CBMM constantly strives to improve process controls and product quality, and is currently implementing innovations in production, research and development to further improve ingot quality. The main aim is to reduce the content of interstitial elements, such as nitrogen (N), oxygen (O), carbon (C), and hydrogen (H), starting with the raw materials through the final step of ingot production. CBMM held the first trial to produce the world’s largest-diameter niobium ingot (as cast 535 mm). The results of this initial trial presented very low levels of interstitial impurities (N, O, C, H), allowing the achievement of residual resistivity ratio (RRR) values very close to 300 in a six-melt process in an electron beam furnace. These values were reached with 850 ppm of tantalum. SRF cavities will be produced with this material in order to study the effect of low impurities and high RRR on the Q factor and accelerating gradient.

  4. Fabrication and characterization of organic solar cells using metal complex of phthalocyanines

    SciTech Connect (OSTI)

    Kida, Tomoyasu Suzuki, Atsushi Akiyama, Tsuyoshi Oku, Takeo

    2015-02-27

    Fabrication and characterization of organic solar cells using shuttle-cock-type phthalocyanines were carried out. Photovoltaic properties of the solar cells with inverted structures were investigated by current density-voltage characteristics. Effects of phase transition between H and J aggregates on the photovoltaic and optical properties were investigated. The photovoltaic mechanisms, energy levels and band gap of active layers were discussed.

  5. Friction welded nonconsumable electrode assembly and use thereof for electrolytic production of metals and silicon

    DOE Patents [OSTI]

    Byrne, Stephen C. (Monroeville, PA); Ray, Siba P. (Pittsburgh, PA); Rapp, Robert A. (Columbus, OH)

    1984-01-01

    A nonconsumable electrode assembly suitable for use in the production of metal by electrolytic reduction of a metal compound dissolved in a molten salt, the assembly comprising a metal conductor and a ceramic electrode body connected by a friction weld between a portion of the body having a level of free metal or metal alloy sufficient to effect such a friction weld and a portion of the metal conductor.

  6. Method for fabricating a seal between a ceramic and a metal alloy

    DOE Patents [OSTI]

    Kelsey, P.V. Jr.; Siegel, W.T.

    1983-08-16

    A method of fabricating a seal between a ceramic and an alloy comprising the steps of prefiring the alloy in an atmosphere with a very low partial pressure of oxygen, firing the assembled alloy and ceramic in air, and gradually cooling the fired assembly to avoid the formation of thermal stress in the ceramic. The method forms a bond between the alloy and the ceramic capable of withstanding the environment of a pressurized water reactor and suitable for use in an electrical conductivity sensitive liquid level transducer.

  7. Method for fabricating a seal between a ceramic and a metal alloy

    DOE Patents [OSTI]

    Kelsey, Jr., Paul V.; Siegel, William T.

    1983-01-01

    A method of fabricating a seal between a ceramic and an alloy comprising the steps of prefiring the alloy in an atmosphere with a very low partial pressure of oxygen, firing the assembled alloy and ceramic in air, and gradually cooling the fired assembly to avoid the formation of thermal stress in the ceramic. The method forms a bond between the alloy and the ceramic capable of withstanding the environment of a pressurized water reactor and suitable for use in an electrical conductivity sensitive liquid level transducer.

  8. Use of metallic glasses for fabrication of structures with submicron dimensions

    DOE Patents [OSTI]

    Wiley, John D.; Perepezko, John H.

    1986-01-01

    Patterned structures of submicron dimension formed of supported or unsupported amorphous metals having submicron feature sizes characterized by etching behavior sufficient to allow delineation of sharp edges and smooth flat flanks, resistance to time-dependent dimensional changes caused by creep, flow, in-diffusion of unwanted impurities, out-diffusion of constituent atoms, void formation, grain growth or phase separation and resistance to phase transformations or compound formation.

  9. A novel fabrication technique for thin metallic vacuum chambers with low eddy current losses

    SciTech Connect (OSTI)

    Kouptsidis, J.; Banthau, R.; Hartwig, H.

    1985-10-01

    Eddy current problems in synchrotrons have been avoided until now by using costly and thick ceramic vacuum chambers which reduce the free magnet aperture. These disadvantages are eliminated by a novel fabrication technique developed for the chambers of the new 9 GeV electron synchrotron DESY II operating with 12.5 Hz repetion rate. The elliptical chambers 80x40 mm are made from .3 mm thick stainless steel tubes reinforced by thin ribs. The ribs are brazed on the tubes by a high temperature Ni-base brazing alloy. The linear eddy current losses are 60 W/m and increase the chamber temperature to only 50/sup 0/C. The available beam aperture is now 93% of the magnet gap. A still higher repetion rate up to 100 Hz can be achieved by reducing the wall thickness to .1 mm and using tubes made from a Ti-alloy having higher resistivity than stainless steel.

  10. Electrolytic production of metals using a resistant anode

    DOE Patents [OSTI]

    Tarcy, G.P.; Gavasto, T.M.; Ray, S.P.

    1986-11-04

    An electrolytic process is described comprising evolving oxygen on an anode in a molten salt, the anode comprising an alloy comprising a first metal and a second metal, both metals forming oxides, the oxide of the first metal being more resistant than the second metal to attack by the molten salt, the oxide of the second metal being more resistant than the first metal to the diffusion of oxygen. The electrode may also be formed of CuAlO[sub 2] and/or Cu[sub 2]O. 2 figs.

  11. Method of fabricating metal- and ceramic- matrix composites and functionalized textiles

    DOE Patents [OSTI]

    Maxwell, James L.; Chavez, Craig A.; Black, Marcie R.

    2012-04-17

    A method of manufacturing an article comprises providing a first sheet, wetting the first sheet with a liquid precursor to provide a first wet sheet, and irradiating the first wet sheet in a pattern corresponding to a first cross section of the article such that the liquid precursor is at least partially converted to a solid in the first cross section. A second sheet is disposed adjacent to the first sheet. The method further comprises wetting the second sheet with the liquid precursor to provide a second wet sheet, and irradiating the second wet sheet in a pattern corresponding to a second cross section of the article such that the liquid precursor is at least partially converted to a solid in the second cross section. In particular the liquid precursor may be converted to a metal, ceramic, semiconductor, semimetal, or a combination of these materials.

  12. Amorphous semiconducting and conducting transparent metal oxide thin films and production thereof

    DOE Patents [OSTI]

    Perkins, John; Van Hest, Marinus Franciscus Antonius Maria; Ginley, David; Taylor, Matthew; Neuman, George A.; Luten, Henry A.; Forgette, Jeffrey A.; Anderson, John S.

    2010-07-13

    Metal oxide thin films and production thereof are disclosed. An exemplary method of producing a metal oxide thin film may comprise introducing at least two metallic elements and oxygen into a process chamber to form a metal oxide. The method may also comprise depositing the metal oxide on a substrate in the process chamber. The method may also comprise simultaneously controlling a ratio of the at least two metallic elements and a stoichiometry of the oxygen during deposition. Exemplary amorphous metal oxide thin films produced according to the methods herein may exhibit highly transparent properties, highly conductive properties, and/or other opto-electronic properties.

  13. Production of aluminum metal by electrolysis of aluminum sulfide

    DOE Patents [OSTI]

    Minh, N.Q.; Loutfy, R.O.; Yao, N.P.

    1982-04-01

    Metallic aluminum may be produced by the electrolysis of Al/sub 2/S/sub 3/ at 700 to 800/sup 0/C in a chloride melt composed of one or more alkali metal chlorides, and one or more alkaline earth metal chlorides and/or aluminum chloride to provide improved operating characteristics of the process.

  14. GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE FRIT B COMPOSITION FOR PLUTONIUM DISPOSITION

    SciTech Connect (OSTI)

    Marra, J

    2006-01-19

    The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) to disposition excess weapons-usable plutonium. A plutonium glass waste form is a leading candidate for immobilization of the plutonium for subsequent disposition in a geologic repository. A reference glass composition (Lanthanide Borosilicate (LaBS) Frit B) was developed during the Plutonium Immobilization Program (PIP) to immobilize plutonium. A limited amount of performance testing was performed on this baseline composition before efforts to further pursue Pu disposition via a glass waste form ceased. Therefore, the objectives of this present task were to fabricate plutonium loaded LaBS Frit B glass and perform additional testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the Yucca Mountain Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit B composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL) and for additional performance testing at Argonne National Laboratory (ANL) and Pacific Northwest National Laboratory (PNNL). The glass was characterized using x-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. A series of PCTs were conducted at SRNL with varying exposed surface area and test durations. The leachates from these tests were analyzed to determine the dissolved concentrations of key elements. Acid stripping of leach vessels was performed to determine the concentration of the glass constituents that may have sorbed on the vessels during leach testing. Additionally, the

  15. Apparatus and method for making metal chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Homer Glen, IL); Richmann, Michael K. (Carlsbad, NM)

    2007-05-15

    A method of producing metal chlorides is disclosed in which chlorine gas is introduced into liquid Cd. CdCl.sub.2 salt is floating on the liquid Cd and as more liquid CdCl.sub.2 is formed it separates from the liquid Cd metal and dissolves in the salt. The salt with the CdCl.sub.2 dissolved therein contacts a metal which reacts with CdCl.sub.2 to form a metal chloride, forming a mixture of metal chloride and CdCl.sub.2. After separation of bulk Cd from the salt, by gravitational means, the metal chloride is obtained by distillation which removes CdCl.sub.2 and any Cd dissolved in the metal chloride.

  16. LIFE CYCLE INVENTORY ANALYSIS IN THE PRODUCTION OF METALS USED IN PHOTOVOLTAICS.

    SciTech Connect (OSTI)

    FTHENAKIS,V.M.; KIM, H.C.; WANG, W.

    2007-03-30

    Material flows and emissions in all the stages of production of zinc, copper, aluminum, cadmium, indium, germanium, gallium, selenium, tellurium, and molybdenum were investigated. These metals are used selectively in the manufacture of solar cells, and emission and energy factors in their production are used in the Life Cycle Analysis (LCA) of photovoltaics. Significant changes have occurred in the production and associated emissions for these metals over the last 10 years, which are not described in the LCA databases. Furthermore, emission and energy factors for several of the by-products of the base metal production were lacking. This report aims in updating the life-cycle inventories associated with the production of the base metals (Zn, Cu, Al, Mo) and in defining the emission and energy allocations for the minor metals (Cd, In, Ge, Se, Te and Ga) used in photovoltaics.

  17. Metal-doped single-walled carbon nanotubes and production thereof

    DOE Patents [OSTI]

    Dillon, Anne C.; Heben, Michael J.; Gennett, Thomas; Parilla, Philip A.

    2007-01-09

    Metal-doped single-walled carbon nanotubes and production thereof. The metal-doped single-walled carbon nanotubes may be produced according to one embodiment of the invention by combining single-walled carbon nanotube precursor material and metal in a solution, and mixing the solution to incorporate at least a portion of the metal with the single-walled carbon nanotube precursor material. Other embodiments may comprise sputter deposition, evaporation, and other mixing techniques.

  18. Method and apparatus for the production of metal oxide powder

    DOE Patents [OSTI]

    Harris, M.T.; Scott, T.C.; Byers, C.H.

    1992-06-16

    The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed. 2 figs.

  19. Method and apparatus for the production of metal oxide powder

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Byers, Charles H. (Oak Ridge, TN)

    1992-01-01

    The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.

  20. Method and apparatus for the production of metal oxide powder

    DOE Patents [OSTI]

    Harris, Michael T. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Byers, Charles H. (Oak Ridge, TN)

    1993-01-01

    The present invention provides a method for preparing metal oxide powder. A first solution, which is substantially organic, is prepared. A second solution, which is an aqueous solution substantially immiscible in the first solution, is prepared and delivered as drops to the first solution. The drops of the second solution are atomized by a pulsed electric field forming micro-drops of the second solution. Reagents in the first solution diffuse into and react with reactants in the micro-drops of the second solution forming metal hydroxide or oxalate particles. The metal hydroxide or metal oxalate particles are then recovered and dried to produce the metal oxide powder. An apparatus for preparing a metal oxide powder is also disclosed.

  1. DOE - Office of Legacy Management -- Enterprise Metal Products - NY 0-10

    Office of Legacy Management (LM)

    Enterprise Metal Products - NY 0-10 FUSRAP Considered Sites Site: Enterprise Metal Products (NY.0-10 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Brooklyn , New York NY.0-10-1 Evaluation Year: 1987 NY.0-10-1 Site Operations: Machined magnesium metal NY.0-10-1 Site Disposition: Eliminated - Potential for contamination remote NY.0-10-1 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Indicated

  2. REMOVAL OF CERTAIN FISSION PRODUCT METALS FROM LIQUID BISMUTH COMPOSITIONS

    DOE Patents [OSTI]

    Dwyer, O.E.; Howe, H.E.; Avrutik, E.R.

    1959-11-24

    A method is described for purifying a solution of urarium in liquid bismuth containing at least one metal from the group consisting of selenium, tellurium, palladium, ruthenium, rhodium, niobium, and zirconium. The solution is contacted with zinc in an inert atmosphere to form a homogeneous melt, a solid zinc phase is formed, and the zinc phase containing the metal is separated from the melt.

  3. Process for fabrication of cermets

    DOE Patents [OSTI]

    Landingham, Richard L.

    2011-02-01

    Cermet comprising ceramic and metal components and a molten metal infiltration method and process for fabrication thereof. The light weight cermets having improved porosity, strength, durability, toughness, elasticity fabricated from presintered ceramic powder infiltrated with a molten metal or metal alloy. Alumina titanium cermets biocompatible with the human body suitable for bone and joint replacements.

  4. Method of making metal-doped organic foam products

    DOE Patents [OSTI]

    Rinde, James A.

    1981-01-01

    Organic foams having a low density and very small cell size and method for roducing same in either a metal-loaded or unloaded (nonmetal loaded) form are described. Metal-doped foams are produced by soaking a polymer gel in an aqueous solution of desired metal salt, soaking the gel successively in a solvent series of decreasing polarity to remove water from the gel and replace it with a solvent of lower polarity with each successive solvent in the series being miscible with the solvents on each side and being saturated with the desired metal salt, and removing the last of the solvents from the gel to produce the desired metal-doped foam having desired density cell size, and metal loading. The unloaded or metal-doped foams can be utilized in a variety of applications requiring low density, small cell size foam. For example, rubidium-doped foam made in accordance with the invention has utility in special applications, such as in x-ray lasers.

  5. Bacterial Production of Mixed Metal Oxide Nanoparticles - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    may be applied to cultures of a variety of metal-reducing bacteria to reduce the toxicity of dopant species to bacteria. In addition, the method provides a means by which...

  6. Production summary for extended barrel module fabrication at Argonne for the ATLAS tile calorimeter.

    SciTech Connect (OSTI)

    Guarino, V.; Hill, N.; Petereit, E.; Skrzecz, F.; Wood, K.; Proudfoot, J.; Anderson, S.; Caird, A.; Keyser, C.; Kocenko, L.; Matijas, Z.; Nephew, T.; Stanek, R.; Franchini, F.; High Energy Physics

    2007-11-14

    The Tile Calorimeter is one of the main hadronic calorimeters to be used in the ATLAS experiment at CERN [1,2]. It is a steel/scintillator sampling calorimeter which is built by stacking 64 segments in azimuth and 3 separate cylinders to provide a total structure whose length is approximately 12m and whose diameter is a little over 8.4m. It has a total weight of about 2630 metric tons. Important features of this calorimeter are: A minimum gap (1.5mm) between modules in azimuth; Pockets in the structure to hold the scintillator tiles; Recessed channels at the edges of the module into which the readout fibers will sit; and Holes in the structure through which a radioactive source will pass. The mechanical structure for one of the 3 calorimeter sections, the Extended Barrel (EBA) was constructed at Argonne. A schematic of the calorimeter sampling structure and the layout of one of the 64 segments, termed a module, are shown in figure 1. Each module comprises mechanically of a precision machined, structural girder to which 10 submodules are bolted. One of these submodules, the ITC, has a customized shape to accommodate services for other detector elements. Each submodule weighs 850Kg and the assembled mechanical structure of the module weighs approximately 9000Kg (a fully instrumented Extended Barrel modules weighs {approx}9600Kg). A crucial issue for the tile calorimeter assembly is the minimization of the un-instrumented gap between modules when they are stacked on top of each other during final assembly. The design goal was originally 1mm gap which was eventually relaxed to 1.5mm following a careful evaluation of all tolerances in the construction and assembly process as shown in figure 2 [3]. Submodules for this assembly were produced at 4 locations [4] using tooling and procedures which were largely identical [5]. An important issue was the height of each submodule on the stacking fixture on which they were fabricated as this defines the length along the girder

  7. Method and apparatus for fabricating a composite structure consisting of a filamentary material in a metal matrix

    DOE Patents [OSTI]

    Banker, J.G.; Anderson, R.C.

    1975-10-21

    A method and apparatus are provided for preparing a composite structure consisting of filamentary material within a metal matrix. The method is practiced by the steps of confining the metal for forming the matrix in a first chamber, heating the confined metal to a temperature adequate to effect melting thereof, introducing a stream of inert gas into the chamber for pressurizing the atmosphere in the chamber to a pressure greater than atmospheric pressure, confining the filamentary material in a second chamber, heating the confined filamentary material to a temperature less than the melting temperature of the metal, evacuating the second chamber to provide an atmosphere therein at a pressure, placing the second chamber in registry with the first chamber to provide for the forced flow of the molten metal into the second chamber to effect infiltration of the filamentary material with the molten metal, and thereafter cooling the metal infiltrated-filamentary material to form said composite structure.

  8. RARE-EARTH METAL FISSION PRODUCTS FROM LIQUID U-Bi

    DOE Patents [OSTI]

    Wiswall, R.H.

    1960-05-10

    Fission product metals can be removed from solution in liquid bismuth without removal of an appreciable quantity of uranium by contacting the liquid metal solution with fused halides, as for example, the halides of sodium, potassium, and lithium and by adding to the contacted phases a quantity of a halide which is unstable relative to the halides of the fission products, a specific unstable halide being MgCl/sub 3/.

  9. In-Situ Production of Microbial Pigments for Metal and Actinide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Immobilization - Energy Innovation Portal In-Situ Production of Microbial Pigments for Metal and Actinide Immobilization Unique in-situ method shown to dramatically reduce the mobility of contaminants in the soil without need for excavation Savannah River National Laboratory Contact SRNL About This Technology The stimulation of melanin production by subsurface bacteria offers a means to accelerate the immobilization rates of metal and radionuclide contaminants in the subsurface, even at low

  10. Method for fabricating .sup.99 Mo production targets using low enriched uranium, .sup.99 Mo production targets comprising low enriched uranium

    DOE Patents [OSTI]

    Wiencek, Thomas C.; Matos, James E.; Hofman, Gerard L.

    2000-12-12

    A radioisotope production target and a method for fabricating a radioisotope production target is provided, wherein the target comprises an inner cylinder, a foil of fissionable material circumferentially contacting the outer surface of the inner cylinder, and an outer hollow cylinder adapted to receive the substantially foil-covered inner cylinder and compress tightly against the foil to provide good mechanical contact therewith. The method for fabricating a primary target for the production of fission products comprises preparing a first substrate to receive a foil of fissionable material so as to allow for later removal of the foil from the first substrate, preparing a second substrate to receive the foil so as to allow for later removal of the foil from the second substrate; attaching the first substrate to the second substrate such that the foil is sandwiched between the first substrate and second substrate to prevent foil exposure to ambient atmosphere, and compressing the exposed surfaces of the first and second substrate to assure snug mechanical contact between the foil, the first substrate and the second substrate.

  11. Method for fabricating .sup.99 Mo production targets using low enriched uranium, .sup.99 Mo production targets comprising low enriched uranium

    DOE Patents [OSTI]

    Wiencek, Thomas C.; Matos, James E.; Hofman, Gerard L.

    1997-01-01

    A radioisotope production target and a method for fabricating a radioisotope production target is provided, wherein the target comprises an inner cylinder, a foil of fissionable material circumferentially contacting the outer surface of the inner cylinder, and an outer hollow cylinder adapted to receive the substantially foil-covered inner cylinder and compress tightly against the foil to provide good mechanical contact therewith. The method for fabricating a primary target for the production of fission products comprises preparing a first substrate to receive a foil of fissionable material so as to allow for later removal of the foil from the first substrate, preparing a second substrate to receive the foil so as to allow for later removal of the foil from the second substrate; attaching the first substrate to the second substrate such that the foil is sandwiched between the first substrate and second substrate to prevent foil exposure to ambient atmosphere, and compressing the exposed surfaces of the first and second substrate to assure snug mechanical contact between the foil, the first substrate and the second substrate.

  12. Method for fabricating {sup 99}Mo production targets using low enriched uranium, {sup 99}Mo production targets comprising low enriched uranium

    DOE Patents [OSTI]

    Wiencek, T.C.; Matos, J.E.; Hofman, G.L.

    1997-03-25

    A radioisotope production target and a method for fabricating a radioisotope production target is provided, wherein the target comprises an inner cylinder, a foil of fissionable material circumferentially contacting the outer surface of the inner cylinder, and an outer hollow cylinder adapted to receive the substantially foil-covered inner cylinder and compress tightly against the foil to provide good mechanical contact therewith. The method for fabricating a primary target for the production of fission products comprises preparing a first substrate to receive a foil of fissionable material so as to allow for later removal of the foil from the first substrate, preparing a second substrate to receive the foil so as to allow for later removal of the foil from the second substrate; attaching the first substrate to the second substrate such that the foil is sandwiched between the first substrate and second substrate to prevent foil exposure to ambient atmosphere, and compressing the exposed surfaces of the first and second substrate to assure snug mechanical contact between the foil, the first substrate and the second substrate. 3 figs.

  13. Production of crystalline refractory metal oxides containing colloidal metal precipitates and useful as solar-effective absorbers

    DOE Patents [OSTI]

    Narayan, Jagdish; Chen, Yok

    1983-01-01

    This invention is a new process for producing refractory crystalline oxides having improved or unusual properties. The process comprises the steps of forming a doped-metal crystal of the oxide; exposing the doped crystal in a bomb to a reducing atmosphere at superatmospheric pressure and a temperature effecting precipitation of the dopant metal in the crystal lattice of the oxide but insufficient to effect net diffusion of the metal out of the lattice; and then cooling the crystal. Preferably, the cooling step is effected by quenching. The process forms colloidal precipitates of the metal in the oxide lattice. The process may be used, for example, to produce thermally stable black MgO crystalline bodies containing magnetic colloidal precipitates consisting of about 99% Ni. The Ni-containing bodies are solar-selective absorbers, having a room-temperature absorptivity of about 0.96 over virtually all of the solar-energy spectrum and exhibiting an absorption edge in the region of 2 .mu.m. The process parameters can be varied to control the average size of the precipitates. The process can produce a black MgO crystalline body containing colloidal Ni precipitates, some of which have the face-centered-cubic structure and others of which have the body-centered cubic structure. The products of the process are metal-precipitate-containing refractory crystalline oxides which have improved or unique optical, mechanical, magnetic, and/or electronic properties.

  14. In situ production of ceramic reinforcement in metallic parts by thermal degradation of organometallics

    SciTech Connect (OSTI)

    Shivkumar, S.; Cournoyer, J.; Makhlouf, M. )

    1993-08-15

    The ability to enhance the physical and mechanical properties of metallic components by particulate ceramic reinforcement is well documented. Several methods have been used to incorporate the ceramic particles in the metallic matrix. These methods can be classified into three groups based on the physical state of the metallic phase during processing: (1) liquid phase methods, (2) solid state methods and (3) semi-solid state methods. Liquid phase methods have generated considerable interest because they offer the most economical route for the production of near-net-shape components. In order to realize the full benefits of the ceramic reinforcement, it is imperative that the interfacial bond strength between the ceramic and the metal be maximized. This interfacial bond strength depends to a large extent on the ability of the molten metal to wet the ceramic. It is often difficult to achieve good wetting between molten metals and ceramics because of the large surface tension commonly associated with metals. Several techniques have been used to improve metal/ceramic wetting characteristics. These methods include application of coatings on the ceramic, alloying the metal with reactive elements such as Li, Mg, Ca, Ti or Zr and heat treating the ceramic. A variety of new technologies are also emerging for the in situ production of the reinforcing phase. The in situ production of the ceramic could potentially enhance the wetting characteristics and may probide improved control of the size and level of reinforcement. In this contribution, the feasibility of producing ceramic reinforcements in situ by thermal degradation of a suitable organometallic in a liquid metal bath has been explored.

  15. Periodic dielectric structure for production of photonic band gap and method for fabricating the same

    DOE Patents [OSTI]

    Ozbay, Ekmel; Tuttle, Gary; Michel, Erick; Ho, Kai-Ming; Biswas, Rana; Chan, Che-Ting; Soukoulis, Costas

    1995-01-01

    A method for fabricating a periodic dielectric structure which exhibits a photonic band gap. Alignment holes are formed in a wafer of dielectric material having a given crystal orientation. A planar layer of elongate rods is then formed in a section of the wafer. The formation of the rods includes the step of selectively removing the dielectric material of the wafer between the rods. The formation of alignment holes and layers of elongate rods and wafers is then repeated to form a plurality of patterned wafers. A stack of patterned wafers is then formed by rotating each successive wafer with respect to the next-previous wafer, and then placing the successive wafer on the stack. This stacking results in a stack of patterned wafers having a four-layer periodicity exhibiting a photonic band gap.

  16. Periodic dielectric structure for production of photonic band gap and method for fabricating the same

    DOE Patents [OSTI]

    Ozbay, E.; Tuttle, G.; Michel, E.; Ho, K.M.; Biswas, R.; Chan, C.T.; Soukoulis, C.

    1995-04-11

    A method is disclosed for fabricating a periodic dielectric structure which exhibits a photonic band gap. Alignment holes are formed in a wafer of dielectric material having a given crystal orientation. A planar layer of elongate rods is then formed in a section of the wafer. The formation of the rods includes the step of selectively removing the dielectric material of the wafer between the rods. The formation of alignment holes and layers of elongate rods and wafers is then repeated to form a plurality of patterned wafers. A stack of patterned wafers is then formed by rotating each successive wafer with respect to the next-previous wafer, and then placing the successive wafer on the stack. This stacking results in a stack of patterned wafers having a four-layer periodicity exhibiting a photonic band gap. 42 figures.

  17. Energy requirements for metals production: comparison between ocean nodules and land-based resources. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-09-01

    A methodology was developed to compare the energy requirements of technologies for production of metals from ocean nodules with production of same metals from land based ores using conventional processes. The energy requirements for production of copper, nickel, cobalt, and manganese from ocean nodules are based on an ocean mining operation of 3 million tons per year of dry nodules. A linear relationship exists between the amount of nodules processed and the total energy so that the energy can be easily converted to other processing rates if desired.

  18. Design, fabrication, and integration testing of the Garden Banks 388 subsea production template

    SciTech Connect (OSTI)

    Ledbetter, W.R.; Smith, D.W.; Pierce, D.M.; Padilla, J.R.

    1995-12-31

    Enserch Exploration`s Garden Banks 388 development has a production scheme based around a floating drilling and production facility and subsea drilling/production template. The Floating Production Facility (FPF) is a converted semisubmersible drilling rig that will drill and produce through a 24-well slot subsea template. This development is located in Block 388 of the Garden Banks area in the Gulf of Mexico approximately 200 miles southwest of New Orleans, Louisiana. The production system is being installed in an area of known oil and gas reserves and will produce to a shallow water platform 54 miles away at Eugene Island 315. The FPF will be permanently moored above the template. The subsea template has been installed in 2190 feet of water and will produce through a 2,000 foot free-standing production riser system to the FPF. The produced fluids are partially separated on the FPF before oil and gas are pumped through the template to export gathering lines that are connected to the shallow water facility. The system designed through-put is 40,000 BOPD of oil and 120 MMSCFD of gas.

  19. Industrial recovered-materials-utilization targets for the metals and metal-products industry

    SciTech Connect (OSTI)

    1980-03-01

    The National Energy Conservation Policy Act of 1978 directs DOE to set targets for increased utilization of energy-saving recovered materials for certain industries. These targets are to be established at levels representing the maximum feasible increase in utilization of recovered materials that can be achieved progressively by January 1, 1987 and is consistent with technical and economic factors. A benefit to be derived from the increased use of recoverable materials is in energy savings, as state in the Act. Therefore, emhasis on different industries in the metals sector has been related to their energy consumption. The ferrous industry (iron and steel, ferrour foundries and ferralloys), as defined here, accounts for approximately 3%, and all others for the remaining 3%. Energy consumed in the lead and zinc segments is less than 1% each. Emphasis is placed on the ferrous scrap users, followed by the aluminum and copper industries. A bibliography with 209 citations is included.

  20. Method of fabricating graphite for use as a skeletal prosthesis and product thereof

    DOE Patents [OSTI]

    Eatherly, Walter P.; Robbins, J. M.; Rosson, Sr., David E.

    1978-01-01

    A method for producing porous graphite for use as bone replacement with a structure for osteon penetration. Graphite is produced with ordered circular pores of 100 to 1000 microns in diameter covering at least 25% of the exposed surfaces. A cylindrical fiber is coated with a carbon flour-pitch mix and is then wound on a bobbin in a predetermined manner. The product of winding is dried, pressed, carbonized, and then graphitized. The fibers are removed either chemically or by volatilization during carbonization or graphitization.

  1. Report on Development of Concepts for the Advanced Casting System in Support of the Deployment of a Remotely Operable Research Scale Fuel Fabrication Facility for Metal Fuel

    SciTech Connect (OSTI)

    Ken Marsden

    2007-03-01

    Demonstration of recycle processes with low transuranic losses is key to the successful implementation of the Global Nuclear Energy Partnership strategy to manage spent fuel. It is probable that these recycle processes will include remote fuel fabrication. This report outlines the strategy to develop and implement a remote metal fuel casting process with minimal transuranic losses. The approach includes a bench-scale casting system to develop materials, methods, and perform tests with transuranics, and an engineering-scale casting system to demonstrate scalability and remote operability. These systems will be built as flexible test beds allowing exploration of multiple fuel casting approaches. The final component of the remote fuel fabrication demonstration culminates in the installation of an advanced casting system in a hot cell to provide integrated remote operation experience with low transuranic loss. Design efforts and technology planning have begun for the bench-scale casting system, and this will become operational in fiscal year 2008, assuming appropriate funding. Installation of the engineering-scale system will follow in late fiscal year 2008, and utilize materials and process knowledge gained in the bench-scale system. Assuming appropriate funding, the advanced casting system will be installed in a remote hot cell at the end of fiscal year 2009.

  2. Physical understanding of electron mobility in asymmetrically strained InGaAs-on-insulator metal-oxide-semiconductor field-effect transistors fabricated by lateral strain relaxation

    SciTech Connect (OSTI)

    Kim, SangHyeon E-mail: sh-kim@kist.re.kr; Yokoyama, Masafumi; Ikku, Yuki; Nakane, Ryosho; Takenaka, Mitsuru; Takagi, Shinichi; Ichikawa, Osamu; Osada, Takenori; Hata, Masahiko

    2014-03-17

    In this paper, we fabricated asymmetrically tensile-strained In{sub 0.53}Ga{sub 0.47}As-on-insulator (-OI) metal-oxide-semiconductor field-effect transistors (MOSFETs) using a lateral strain relaxation technique. A stripe-like line structure, fabricated in biaxially strained In{sub 0.53}Ga{sub 0.47}As-OI can lead to the lateral strain relaxation and asymmetric strain configuration in In{sub 0.53}Ga{sub 0.47}As-OI with the channel width of 100 nm. We have found that the effective mobility (μ{sub eff}) enhancement in In{sub 0.53}Ga{sub 0.47}As-OI MOSFETs with uniaxial-like asymmetric strain becomes smaller than that in In{sub 0.53}Ga{sub 0.47}As-OI MOSFETs with biaxial strain. We have clarified from a systematic analysis between the strain values and the μ{sub eff} characteristics that this mobility behavior can be understood by the change of the energy level of the conduction band minimum due to the lateral strain relaxation.

  3. Fabrication of superconducting metal-oxide textiles by heating impregnated polymeric material in a weakly oxidizing atmosphere

    SciTech Connect (OSTI)

    Van den Sype, J.S.

    1993-07-13

    A process is described for producing crystalline fibers, textiles or shapes comprised of YBa[sub 2]Cu[sub 3]O[sub 7[minus]x] where x varies from about 0 to about 0.4, said process comprising: (a) impregnating a preformed organic polymeric material with three metal compounds to provide metal elements in said material in substantially the atomic ratio occurring in said YBa[sub 2]Cu[sub 3]O[sub 7[minus]x]; (b) heating said impregnated material in a weakly oxidizing atmosphere containing from about 0.05% to about 2% oxygen by volume to a temperature sufficiently high to at least partially pyrolize and oxidize said organic material and at least partially oxidize said metal compounds substantially without ignition of said organic material and without formation of a molten phase or reaching a decomposition temperature of said YBa[sub 2]Cu[sub 3]O[sub 7[minus]x]; and (c) cooling the resulting material in at least a moderately oxidizing atmosphere to room temperature so as to obtain said fibers, textiles or shapes.

  4. Method of manufacturing metallic products such as sheet by cold working and flash anealing

    DOE Patents [OSTI]

    Hajaligol, Mohammad R.; Sikka, Vinod K.

    2001-01-01

    A metallic alloy composition is manufactured into products such as press formed or stamped products or rolled products such as sheet, strip, rod, wire or band by one or more cold working steps with intermediate or final flash annealing. The method can include cold rolling an iron, nickel or titanium aluminide alloy and annealing the cold worked product in a furnace by infrared heating. The flash annealing is preferably carried out by rapidly heating the cold worked product to an elevated temperature for less than one minute. The flash annealing is effective to reduce surface hardness of the cold worked product sufficiently to allow further cold working. The product to be cold worked can be prepared by casting the alloy or by a powder metallurgical technique such as tape casting a mixture of metal powder and a binder, roll compacting a mixture of the powder and a binder or plasma spraying the powder onto a substrate. In the case of tape casting or roll compaction, the initial powder product can be heated to a temperature sufficient to remove volatile components. The method can be used to form a cold rolled sheet which is formed into an electrical resistance heating element capable of heating to 900.degree. C. in less than 1 second when a voltage up to 10 volts and up to 6 amps is passed through the heating element.

  5. Method of manufacturing metallic products such as sheet by cold working and flash annealing

    DOE Patents [OSTI]

    Hajaligol, Mohammad R.; Sikka, Vinod K.

    2000-01-01

    A metallic alloy composition is manufactured into products such as press formed or stamped products or rolled products such as sheet, strip, rod, wire or band by one or more cold working steps with intermediate or final flash annealing. The method can include cold rolling an iron, nickel or titanium aluminide alloy and annealing the cold worked product in a furnace by infrared heating. The flash annealing is preferably carried out by rapidly heating the cold worked product to an elevated temperature for less than one minute. The flash annealing is effective to reduce surface hardness of the cold worked product sufficiently to allow further cold working. The product to be cold worked can be prepared by casting the alloy or by a powder metallurgical technique such as tape casting a mixture of metal powder and a binder, roll compacting a mixture of the powder and a binder or plasma spraying the powder onto a substrate. In the case of tape casting or roll compaction, the initial powder product can be heated to a temperature sufficient to remove volatile components. The method can be used to form a cold rolled sheet which is formed into an electrical resistance heating element capable of heating to 900.degree. C. in less than 1 second when a voltage up to 10 volts and up to 6 amps is passed through the heating element.

  6. Mass production of multi-wall carbon nanotubes by metal dusting process with high yield

    SciTech Connect (OSTI)

    Ghorbani, H.; Rashidi, A.M.; Rastegari, S.; Mirdamadi, S.; Alaei, M.

    2011-05-15

    Research highlights: {yields} Synthesis of carbon nanotubes over Fe-Ni nanoparticles supported alloy 304L. {yields} Production of carbon nanotubes with high yield (700-1000%) and low cost catalyst. {yields} Optimum growth condition is CO/H{sub 2} = 1/1, 100 cm{sup 3}/min, at 620 {sup o}C under long term repetitive thermal cycling. {yields} Possibility of the mass production by metal dusting process with low cost. -- Abstract: Carbon nanotube materials were synthesized over Fe-Ni nanoparticles generated during disintegration of the surface of alloy 304L under metal dusting environment. The metal dusting condition was simulated and optimized through exposing stainless steel samples during long term repetitive thermal cycling in CO/H{sub 2} = 1/1, total gas flow rate 100 cm{sup 3}/min, at 620 {sup o}C for 300 h. After reaction, surface morphology of the samples and also carbonaceous deposition which had grown on sample surfaces were examined by stereoscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Results revealed that multi-wall carbon nanotubes could be formed over nanocatalyst generated on the alloy surface by exploiting metal dusting process. By optimization of reaction parameters the yields of carbon nanotube materials obtained were 700-1000%. Also it has been shown herein that the amount of carbon nanotube materials remarkably increases when the reaction time is extended up to 300 h, indicating a possibility of the mass production by this easy method.

  7. A New Process for Hot Metal Production at Low Fuel Rate - Phase 1 Feasibility Study

    SciTech Connect (OSTI)

    Dr. Wei-Kao Lu

    2006-02-01

    The project is part of the continuing effort by the North American steel industry to develop a coal-based, cokeless process for hot metal production. The objective of Phase 1 is to determine the feasibility of designing and constructing a pilot scale facility with the capacity of 42,000 mtpy of direct reduced iron (DRI) with 95% metallization. The primary effort is performed by Bricmont, Inc., an international engineering firm, under the supervision of McMaster University. The study focused on the Paired Straight Hearth furnace concept developed previously by McMaster University, The American Iron and Steel Institute and the US Department of Energy.

  8. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.; S.K. Dua, Ph.D., C.H.P.; Hillol Guha, Ph.D.

    2001-01-01

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 {micro}m) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 {micro}m, arising from

  9. Directed light fabrication

    SciTech Connect (OSTI)

    Lewis, G.K.; Nemec, R.; Milewski, J.; Thoma, D.J.; Cremers, D.; Barbe, M.

    1994-09-01

    Directed Light Fabrication (DLF) is a rapid prototyping process being developed at Los Alamos National Laboratory to fabricate metal components. This is done by fusing gas delivered metal powder particles in the focal zone of a laser beam that is, programmed to move along or across the part cross section. Fully dense metal is built up a layer at a time to form the desired part represented by a 3 dimensional solid model from CAD software. Machine ``tool paths`` are created from the solid model that command the movement and processing parameters specific to the DLF process so that the part can be built one layer at a time. The result is a fully dense, near net shape metal part that solidifies under rapid solidification conditions.

  10. Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

    SciTech Connect (OSTI)

    Li, Q.S.; Chen, J.J.; Li, Y.C.

    2008-02-15

    Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months of plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.

  11. Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua; Weirauch, Jr., Douglas A.

    2002-01-01

    An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and CoO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and CoO: 0.15 to 0.99 NiO; 0.0001 to 0.85 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.45 CoO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

  12. Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P.; Weirauch, Jr., Douglas A.; Liu, Xinghua

    2002-01-01

    An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and ZnO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and ZnO: 0.2 to 0.99 NiO; 0.0001 to 0.8 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.3 ZnO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

  13. In-bed accountability of tritium in production scale metal hydride storage beds

    SciTech Connect (OSTI)

    Klein, J.E.

    1995-10-01

    An `in-bed accountability` (IBA) flowing gas calorimetric measurement method has been developed and implemented to eliminate the need to remove tritium from production scale metal hydride storage beds for inventory measurement purposes. Six-point tritium IBA calibration curves have been completed for two, 390 gram tritium metal hydride storage beds. The calibration curves for the two tritium beds are similar to those obtained from the `cold` test program. Tritium inventory errors at the 95 percent confidence level ranged from {+-} 7.3 to 8.6 grams for the cold test results compared to {+-} 4.2 to 7.5 grams obtained for the two tritium calibrated beds. 5 refs., 4 figs., 1 tab.

  14. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-06-01

    This sixteenth quarterly report describes work done during the sixteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, and making and responding to several outside contacts.

  15. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-01-01

    This seventeenth quarterly report describes work done during the seventeenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, giving a presentation, submitting a manuscript and making and responding to one outside contact.

  16. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  17. Fabricator tees up with golf-car redesign

    SciTech Connect (OSTI)

    Hallum, D.L.

    1994-09-01

    EZ-Go Textron, Augusta, USA, manufactures 40 models of gasoline- and electric-powered utility vehicles, personnel carriers, and golf cars. Despite its popular product line, EZ-Go management recognized it had a problem; fabricating processes and product design hadn`t changed for 25 years and, at peak production, workers cloistered in dark, dingy shops were fabricating over-designed chassis and car frames using manual gas-metal arc welding. A global production plan, involving redesign of the product and plant modernization, was presented 3 years ago. The plan established volume outputs and shutdown steps for migrating from the old to the new design. The author describes the plan which incorporates linking product redesign, complex stampings, conveyor lines, and robotic welding.

  18. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, Michael D.; Kramer, Daniel P.

    1987-11-10

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  19. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, M.D.; Kramer, D.P.

    1985-01-04

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  20. Effects of Dopant Metal Variation and Material Synthesis Method on the Material Properties of Mixed Metal Ferrites in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leonard, Jeffrey; Reyes, Nichole; Allen, Kyle M.; Randhir, Kelvin; Li, Like; AuYeung, Nick; Grunewald, Jeremy; Rhodes, Nathan; Bobek, Michael; Klausner, James F.

    2015-01-01

    Mixed metal ferrites have shown much promise in two-step solar-thermochemical fuel production. Previous work has typically focused on evaluating a particular metal ferrite produced by a particular synthesis process, which makes comparisons between studies performed by independent researchers difficult. A comparative study was undertaken to explore the effects different synthesis methods have on the performance of a particular material during redox cycling using thermogravimetry. This study revealed that materials made via wet chemistry methods and extended periods of high temperature calcination yield better redox performance. Differences in redox performance between materials made via wet chemistry methods were minimal andmore » these demonstrated much better performance than those synthesized via the solid state method. Subsequently, various metal ferrite samples (NiFe 2 O 4 , MgFe 2 O 4 , CoFe 2 O 4 , and MnFe 2 O 4 ) in yttria stabilized zirconia (8YSZ) were synthesized via coprecipitation and tested to determine the most promising metal ferrite combination. It was determined that 10 wt.% CoFe 2 O 4 in 8YSZ produced the highest and most consistent yields of O 2 and CO. By testing the effects of synthesis methods and dopants in a consistent fashion, those aspects of ferrite preparation which are most significant can be revealed. More importantly, these insights can guide future efforts in developing the next generation of thermochemical fuel production materials.« less

  1. Application of modified direct denitration to support the ORNL coupled-end-to-end demonstration in production of mixed oxides suitable for pellet fabrication

    SciTech Connect (OSTI)

    Walker, E.A.; Vedder, R.J.; Felker, L.K.; Marschman, S.C.

    2007-07-01

    The current and future development of the Modified Direct Denitration (MDD) process is in support of Oak Ridge National Laboratory's (ORNL) Coupled End-to-End (CETE) research, development, and demonstration (R and D) of proposed advanced fuel reprocessing and fuel fabrication processes. This work will involve the co-conversion of the U/Pu/Np product streams from the UREX+3 separation flow sheet utilizing the existing MDD glove-box setup and the in-cell co-conversion of the U/Pu/Np/Am/Cm product streams from the UREX+1a flow sheet. Characterization equipment is being procured and installed. Oxide powder studies are being done on calcination/reduction variables, as well as pressing and sintering of pellets to permit metallographic examinations. (authors)

  2. Method for the preparation of metal colloids in inverse micelles and product preferred by the method

    DOE Patents [OSTI]

    Wilcoxon, Jess P.

    1992-01-01

    A method is provided for preparing catalytic elemental metal colloidal particles (e.g. gold, palladium, silver, rhodium, iridium, nickel, iron, platinum, molybdenum) or colloidal alloy particles (silver/iridium or platinum/gold). A homogeneous inverse micelle solution of a metal salt is first formed in a metal-salt solvent comprised of a surfactant (e.g. a nonionic or cationic surfactant) and an organic solvent. The size and number of inverse micelles is controlled by the proportions of the surfactant and the solvent. Then, the metal salt is reduced (by chemical reduction or by a pulsed or continuous wave UV laser) to colloidal particles of elemental metal. After their formation, the colloidal metal particles can be stabilized by reaction with materials that permanently add surface stabilizing groups to the surface of the colloidal metal particles. The sizes of the colloidal elemental metal particles and their size distribution is determined by the size and number of the inverse micelles. A second salt can be added with further reduction to form the colloidal alloy particles. After the colloidal elemental metal particles are formed, the homogeneous solution distributes to two phases, one phase rich in colloidal elemental metal particles and the other phase rich in surfactant. The colloidal elemental metal particles from one phase can be dried to form a powder useful as a catalyst. Surfactant can be recovered and recycled from the phase rich in surfactant.

  3. A NOVEL LOW THERMAL BUDGET THIN-FILM POLYSILICON FABRICATION PROCESS FOR LARGE-AREA, HIGH-THROUGHPUT SOLAR CELL PRODUCTION

    SciTech Connect (OSTI)

    Yue Kuo

    2010-08-15

    A novel thin-film poly-Si fabrication process has been demonstrated. This low thermal budget process transforms the single- and multi-layer amorphous silicon thin films into a poly-Si structure in one simple step over a pulsed rapid thermal annealing process with the enhancement of an ultrathin Ni layer. The complete poly-Si solar cell was fabricated in a short period of time without deteriorating the underneath glass substrate. The unique vertical crystallization process including the mechanism is discussed. Influences of the dopant type and process parameters on crystal structure will be revealed. The poly-Si film structure has been proved using TEM, XRD, Raman, and XPS methods. The poly-Si solar cell structure and the performance have been examined. In principle, the new process is potentially applicable to produce large-area thin-film poly-Si solar cells at a high throughput and low cost. A critical issue in this process is to prevent the excessive dopant diffusion during crystallization. Process parameters and the cell structure have to be optimized to achieve the production goal.

  4. Advanced Safeguards Approaches for New TRU Fuel Fabrication Facilities

    SciTech Connect (OSTI)

    Durst, Philip C.; Ehinger, Michael H.; Boyer, Brian; Therios, Ike; Bean, Robert; Dougan, A.; Tolk, K.

    2007-12-15

    This second report in a series of three reviews possible safeguards approaches for the new transuranic (TRU) fuel fabrication processes to be deployed at AFCF – specifically, the ceramic TRU (MOX) fuel fabrication line and the metallic (pyroprocessing) line. The most common TRU fuel has been fuel composed of mixed plutonium and uranium dioxide, referred to as “MOX”. However, under the Advanced Fuel Cycle projects custom-made fuels with higher contents of neptunium, americium, and curium may also be produced to evaluate if these “minor actinides” can be effectively burned and transmuted through irradiation in the ABR. A third and final report in this series will evaluate and review the advanced safeguards approach options for the ABR. In reviewing and developing the advanced safeguards approach for the new TRU fuel fabrication processes envisioned for AFCF, the existing international (IAEA) safeguards approach at the Plutonium Fuel Production Facility (PFPF) and the conceptual approach planned for the new J-MOX facility in Japan have been considered as a starting point of reference. The pyro-metallurgical reprocessing and fuel fabrication process at EBR-II near Idaho Falls also provided insight for safeguarding the additional metallic pyroprocessing fuel fabrication line planned for AFCF.

  5. Final LDRD report : metal oxide films, nanostructures, and heterostructures for solar hydrogen production.

    SciTech Connect (OSTI)

    Kronawitter, Coleman X.; Antoun, Bonnie R.; Mao, Samuel S.

    2012-01-01

    The distinction between electricity and fuel use in analyses of global power consumption statistics highlights the critical importance of establishing efficient synthesis techniques for solar fuels-those chemicals whose bond energies are obtained through conversion processes driven by solar energy. Photoelectrochemical (PEC) processes show potential for the production of solar fuels because of their demonstrated versatility in facilitating optoelectronic and chemical conversion processes. Tandem PEC-photovoltaic modular configurations for the generation of hydrogen from water and sunlight (solar water splitting) provide an opportunity to develop a low-cost and efficient energy conversion scheme. The critical component in devices of this type is the PEC photoelectrode, which must be optically absorptive, chemically stable, and possess the required electronic band alignment with the electrochemical scale for its charge carriers to have sufficient potential to drive the hydrogen and oxygen evolution reactions. After many decades of investigation, the primary technological obstacle remains the development of photoelectrode structures capable of efficient conversion of light with visible frequencies, which is abundant in the solar spectrum. Metal oxides represent one of the few material classes that can be made photoactive and remain stable to perform the required functions.

  6. Method of producing metallized chloroplasts and use thereof in the photochemical production of hydrogen and oxygen

    DOE Patents [OSTI]

    Greenbaum, Elias

    1987-01-01

    The invention is primarily a metallized chloroplast composition for use in a photosynthetic reaction. A catalytic metal is precipitated on a chloroplast membrane at the location where a catalyzed reduction reaction occurs. This metallized chloroplast is stabilized by depositing it on a support medium such as fiber so that it can be easily handled. A possible application of this invention is the splitting of water to form hydrogen and oxygen that can be used as a renewable energy source.

  7. Structure and yarn sensor for fabric

    DOE Patents [OSTI]

    Mee, David K.; Allgood, Glenn O.; Mooney, Larry R.; Duncan, Michael G.; Turner, John C.; Treece, Dale A.

    1998-01-01

    A structure and yarn sensor for fabric directly determines pick density in a fabric thereby allowing fabric length and velocity to be calculated from a count of the picks made by the sensor over known time intervals. The structure and yarn sensor is also capable of detecting full length woven defects and fabric. As a result, an inexpensive on-line pick (or course) density measurement can be performed which allows a loom or knitting machine to be adjusted by either manual or automatic means to maintain closer fiber density tolerances. Such a sensor apparatus dramatically reduces fabric production costs and significantly improves fabric consistency and quality for woven or knitted fabric.

  8. Inertial fusion target fabrication using polystyrene mandrels

    SciTech Connect (OSTI)

    Kim, H.; Powers, T.F.; Mason, J.F.

    1984-04-01

    Large-aspect-ratio, plastic-coated, metal shells are useful targets for obtaining valuable information on thermal transport in laser implosion experiments. We have found that by using polystyrene as a leachable mandrel, it is possible to fabricate such complex, inertial-fusion targets. The present fabrication technique offers advantages over previous techniques, including the hemispherical-shell approach, the leachable-metal-mandrel approach, and the coating of a prefabricated metal shell. For fabrication of such diagnostic targets, comprised of a high-aspect-ratio, plastic-coated, metal shell, a polystyrene sphere is mounted on a stalk, then coated with metal and parylene layers. A hole of 5--10 ..mu..m is drilled with a laser pulse through the layers and the polystyrene is then leached out by immersing the system in toluene. The concept of the present technique presents a number of possibilities for the fabrication of complex targets not possible previously.

  9. PRODUCTION OF {sup 9}Be THROUGH THE {alpha}-FUSION REACTION OF METAL-POOR COSMIC RAYS AND STELLAR FLARES

    SciTech Connect (OSTI)

    Kusakabe, Motohiko; Kawasaki, Masahiro E-mail: kawasaki@icrr.u-tokyo.ac.jp

    2013-04-10

    Spectroscopic observations of metal-poor stars have indicated possible {sup 6}Li abundances that are much larger than the primordial abundance predicted in the standard big bang nucleosynthesis model. Possible mechanisms of {sup 6}Li production in metal-poor stars include pregalactic and cosmological cosmic-ray (CR) nucleosynthesis and nucleosynthesis by flare-accelerated nuclides. We study {sup 9}Be production via two-step {alpha}-fusion reactions of CR or flare-accelerated {sup 3,4}He through {sup 6}He and {sup 6,7}Li, in pregalactic structure, intergalactic medium, and stellar surfaces. We solve transfer equations of CR or flare particles and calculate nuclear yields of {sup 6}He, {sup 6,7}Li, and {sup 9}Be taking account of probabilities of processing {sup 6}He and {sup 6,7}Li into {sup 9}Be via fusions with {alpha} particles. Yield ratios, i.e., {sup 9}Be/{sup 6}Li, are then calculated for the CR and flare nucleosynthesis models. We suggest that the future observations of {sup 9}Be in metal-poor stars may find enhanced abundances originating from metal-poor CR or flare activities.

  10. Process for making surfactant capped metal oxide nanocrystals, and products produced by the process

    DOE Patents [OSTI]

    Alivisatos, A. Paul; Rockenberger, Joerg

    2006-01-10

    Disclosed is a process for making surfactant capped nanocrystals of metal oxides which are dispersable in organic solvents. The process comprises decomposing a metal cupferron complex of the formula MXCupX, wherein M is a metal, and Cup is a N-substituted N-Nitroso hydroxylamine, in the presence of a coordinating surfactant, the reaction being conducted at a temperature ranging from about 150 to about 400.degree. C., for a period of time sufficient to complete the reaction. Also disclosed are compounds made by the process.

  11. Application of the metal compression forming process for the production of an aluminum alloy component

    SciTech Connect (OSTI)

    Viswanathan, S.; Porter, W.D.; Ren, W.; Purgert, R.M.

    1997-01-01

    Metal Compression Forming (MCF) is a variant of the squeeze casting process, in which molten metal is allowed to solidify under pressure in order to close porosity and form a sound part. MCF applies pressure on the entire mold face, thereby directing pressure on all regions of the casting. It also enhances the solidification rate of the metal, promoting a very fine grain structure which results in improved properties. Consequently, the process is capable of producing parts with properties close to that of forgings, while retaining the near net shape, complex geometry, and relatively low cost of the casting process.

  12. Fabrication and characterization of nanostructured Fe{sub 3}S{sub 4}, an isostructural compound of half-metallic Fe{sub 3}O{sub 4}

    SciTech Connect (OSTI)

    Li, Peng; Xia, Chuan; Zhang, Qiang; Alshareef, Husam N.; Zhang, Xi-xiang; Guo, Zaibing; Cui, Wenyao; Bai, Haili

    2015-06-14

    High-purity, well-crystallized spinel Fe{sub 3}S{sub 4} nanoplatelets were synthesized by the hydrothermal method, and the saturation magnetic moment of Fe{sub 3}S{sub 4} was measured at 1.83 μ{sub B}/f.u. The temperature-dependent resistivity of Fe{sub 3}S{sub 4} was metallic-like for T < 180 K: room-temperature resistivity was measured at 7.711 × 10{sup 3 }μΩ cm. The anomalous Hall conductivity of Fe{sub 3}S{sub 4} decreased with increasing longitudinal conductivity, in sharp contrast with the accepted theory of the anomalous Hall effect in a dirty-metal regime. Furthermore, negligible spin-dependent magnetoresistance was observed. Band structure calculations confirmed our experimental observations that Fe{sub 3}S{sub 4} is a metal and not a half metal as expected.

  13. Fabrication and characterization of inverted organic solar cells using shuttle cock-type metal phthalocyanine and PCBM:P3HT

    SciTech Connect (OSTI)

    Suzuki, Atsushi Furukawa, Ryo Akiyama, Tsuyoshi Oku, Takeo

    2015-02-27

    Inverted organic solar cells using shuttle cock-type phthalocyanine, semiconducting polymer and fullerenes were fabricated and characterized. Photovoltaic and optical properties of the solar cells with inverted structures were investigated by optical absorption, current density-voltage characteristics. The photovoltaic properties of the tandem organic solar cell using titanyl phthalocyanine, vanadyl phthalocyanine, poly(3-hexylthiophene) (P3HT) and [6, 6]-phenyl C{sub 61}-butyric acid methyl ester (PCBM) were improved. Effect of annealing and solvent treatment on surface morphologies of the active layer was investigated. The photovoltaic mechanisms, energy levels and band gap of active layers were discussed for improvement of the photovoltaic performance.

  14. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A.

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  15. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  16. Method for hydrogen production and metal winning, and a catalyst/cocatalyst composition useful therefor

    DOE Patents [OSTI]

    Dhooge, Patrick M.

    1987-10-13

    A catalyst/cocatalyst/organics composition of matter is useful in electrolytically producing hydrogen or electrowinning metals. Use of the catalyst/cocatalyst/organics composition causes the anode potential and the energy required for the reaction to decrease. An electrolyte, including the catalyst/cocatalyst composition, and a reaction medium composition further including organic material are also described.

  17. A Novel Thermal Electrochemical Synthesis Method for Production of Stable Colloids of "Naked" Metal (Ag) Nanocrystals

    SciTech Connect (OSTI)

    Hu, Michael Z.; Easterly, Clay E

    2009-01-01

    Solution synthesis of nanocrystal silver is reviewed. This paper reports a novel thermal electrochemical synthesis (TECS) for producing metal Ag nanocrystals as small as a few nanometers. The TECS method requires mild conditions (25-100oC), low voltage (1-50 V DC) on Ag electrodes, and simple water or aqueous solutions as reaction medium. Furthermore, a tubular dialysis membrane surround electrodes proves favorable to produce nanosized (<10 nm) Ag nanocrystals. Different from those nanocrystals reported in literature, our nanocrystals have several unique features: (1) small nanometer size, (2) nakedness , i.e., surfaces of metal nanocrystals are free of organic ligands or capping molecules and no need of dispersant in synthesis solutions, and (3) colloidally stable in water solutions. It was discovered that Ag nanoparticles with initially large size distribution can be homogenized into near-monodispersed system by a low power (< 15 mW) He-Ne laser exposure treatment. The combination of the TECS technique and the laser treatment could lead to a new technology that produces metal nanoparticles that are naked, stable, and uniform sized. In the presence of stabilizing agent (also as supporting electrolyte) such as polyvinyl alcohol (PVA), large yield of silver nanoparticles (<100nm) in the form of thick milky sols are produced.

  18. Ultrathin body GaSb-on-insulator p-channel metal-oxide-semiconductor field-effect transistors on Si fabricated by direct wafer bonding

    SciTech Connect (OSTI)

    Yokoyama, Masafumi Takenaka, Mitsuru; Takagi, Shinichi; Yokoyama, Haruki

    2015-02-16

    We have realized ultrathin body GaSb-on-insulator (GaSb-OI) on Si wafers by direct wafer bonding technology using atomic-layer deposition (ALD) Al{sub 2}O{sub 3} and have demonstrated GaSb-OI p-channel metal-oxide-semiconductor field-effect transistors (p-MOSFETs) on Si. A 23-nm-thick GaSb-OI p-MOSFET exhibits the peak effective mobility of ∼76 cm{sup 2}/V s. We have found that the effective hole mobility of the thin-body GaSb-OI p-MOSFETs decreases with a decrease in the GaSb-OI thickness or with an increase in Al{sub 2}O{sub 3} ALD temperature. The InAs passivation of GaSb-OI MOS interfaces can enhance the peak effective mobility up to 159 cm{sup 2}/V s for GaSb-OI p-MOSFETs with the 20-nm-thick GaSb layer.

  19. DEVELOPMENT OF GLASS COMPOSITIONS TO IMMOBILIZE ALKALI, ALKALINE EARTH, LANTHANIDE AND TRANSITION METAL FISSION PRODUCTS FROM NUCLEAR FUEL REPROCESSING

    SciTech Connect (OSTI)

    Marra, J.; Billings, A.

    2009-06-24

    The Advanced Fuel Cycle Initiative (AFCI) waste management strategy revolves around specific treatment of individual or groups of separated waste streams. A goal for the separations processes is to efficiently manage the waste to be dispositioned as high level radioactive waste. The Advanced Fuel Cycle Initiative (AFCI) baseline technology for immobilization of the lanthanide (Ln) and transition metal fission product (TM) wastes is vitrification into a borosilicate glass. A current interest is to evaluate the feasibility of vitrifying combined waste streams to most cost effectively immobilize the wastes resulting from aqueous fuel reprocessing. Studies showed that high waste loadings are achievable for the Ln only (Option 1) stream. Waste loadings in excess of 60 wt % (on a calcined oxide basis) were demonstrated via a lanthanide borosilicate (LaBS) glass. The resulting glasses had excellent relative durability as determined by the Product Consistency Test (PCT). For a combined Ln and TM waste stream glass (Option 2), noble metal solubility was found to limit waste loading. However, the measured PCT normalized elemental releases for this glass were at least an order of magnitude below that of Environmental Assessment (EA) glass. Current efforts to evaluate the feasibility of vitrifying combined Ln, TM, alkali (Cs is the primary radionuclide of concern) and alkaline earth (Sr is the primary radionuclide of concern) wastes (Option 3) have shown that these approaches are feasible. However, waste loading limitations with respect to heat load (Cs/Sr loading), molybdenum solubility and/or noble metal solubility will likely be realized and must be considered in determining the cost effectiveness of these approaches.

  20. DEVELOPMENT OF GLASS COMPOSITIONS TO IMMOBILIZE ALKALI, ALKALINE EARTH, LANTHANIDE AND TRANSITION METAL FISSION PRODUCTS FROM NUCLEAR FUEL REPROCESSING

    SciTech Connect (OSTI)

    Marra, James C.; Billings, Amanda Y.; Crum, Jarrod V.; Ryan, Joseph V.; Vienna, John D.

    2010-02-26

    The Advanced Fuel Cycle Initiative (AFCI) waste management strategy revolves around specific treatment of individual or groups of separated waste streams. A goal for the separations processes is to efficiently manage the waste to be dispositioned as high level radioactive waste. The Advanced Fuel Cycle Initiative (AFCI) baseline technology for immobilization of the lanthanide (Ln) and transition metal fission product (TM) wastes is vitrification into a borosilicate glass. A current interest is to evaluate the feasibility of vitrifying combined waste streams to most cost effectively immobilize the wastes resulting from aqueous fuel reprocessing. Studies showed that high waste loadings are achievable for the Ln only (Option 1) stream. Waste loadings in excess of 60 wt % (on a calcined oxide basis) were demonstrated via a lanthanide borosilicate (LaBS) glass. The resulting glasses had excellent relative durability as determined by the Product Consistency Test (PCT). For a combined Ln and TM waste stream glass (Option 2), noble metal solubility was found to limit waste loading. However, the measured PCT normalized elemental releases for this glass were at least an order of magnitude below that of Environmental Assessment (EA) glass. Current efforts to evaluate the feasibility of vitrifying combined Ln, TM, alkali (Cs is the primary radionuclide of concern) and alkaline earth (Sr is the primary radionuclide of concern) wastes (Option 3) have shown that these approaches are feasible. However, waste loading limitations with respect to heat load (Cs/Sr loading), molybdenum solubility and/or noble metal solubility will likely be realized and must be considered in determining the cost effectiveness of these approaches.

  1. Method of forming a thin unbacked metal foil

    SciTech Connect (OSTI)

    Duchane, D.V.; Barthell, B.L.

    1983-02-23

    The present invention relates generally to metal foils and methods of making the same. More particularly, this invention pertains to the fabrication of very thin, unbacked metal foils.

  2. Application of pyroelectric crystal and ionic liquid to the production of metal compounds

    SciTech Connect (OSTI)

    Imashuku, Susumu; Imanishi, Akira; Kawai, Jun

    2013-04-19

    Zinc fluoride (ZnF{sub 2}) was deposited on a silicon substrate by changing temperature of a pyroelectric crystal of LiTaO{sub 3} on which ionic liquid (EMI-Tf{sub 2}N) containing zinc ions was dripped at 1 Pa. ZnF{sub 2} was also obtained by bombarding argon ions on EMI-Tf{sub 2}N containing zinc ions. From these results, it is concluded that EMI-Tf{sub 2}N containing zinc ions on the LiTaO{sub 3} crystal was evaporated on the silicon substrate by changing temperature of the LiTaO{sub 3} crystal in vacuum and that the evaporated EMI-Tf{sub 2}N containing metal zinc ions was decomposed to ZnF{sub 2} by the bombardment of electrons accelerated by the electric field between the LiTaO{sub 3} crystal and the silicon substrate.

  3. Fabrication Flaw Density and Distribution In Repairs to Reactor Pressure Vessel and Piping Welds

    SciTech Connect (OSTI)

    GJ Schuster, FA Simonen, SR Doctor

    2008-04-01

    The Pacific Northwest National Laboratory is developing a generalized fabrication flaw distribution for the population of nuclear reactor pressure vessels and for piping welds in U.S. operating reactors. The purpose of the generalized flaw distribution is to predict component-specific flaw densities. The estimates of fabrication flaws are intended for use in fracture mechanics structural integrity assessments. Structural integrity assessments, such as estimating the frequency of loss-of-coolant accidents, are performed by computer codes that require, as input, accurate estimates of flaw densities. Welds from four different reactor pressure vessels and a collection of archived pipes have been studied to develop empirical estimates of fabrication flaw densities. This report describes the fabrication flaw distribution and characterization in the repair weld metal of vessels and piping. This work indicates that large flaws occur in these repairs. These results show that repair flaws are complex in composition and sometimes include cracks on the ends of the repair cavities. Parametric analysis using an exponential fit is performed on the data. The relevance of construction records is established for describing fabrication processes and product forms. An analysis of these records shows there was a significant change in repair frequency over the years when these components were fabricated. A description of repair flaw morphology is provided with a discussion of fracture mechanics significance. Fabrication flaws in repairs are characterized using optimized-access, high-sensitivity nondestructive ultrasonic testing. Flaw characterizations are then validated by other nondestructive evaluation techniques and complemented by destructive testing.

  4. Titania Composites with 2 D Transition Metal Carbides as Photocatalysts for Hydrogen Production under Visible-Light Irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Hui; Peng, Rui; Hood, Zachary D.; Naguib, Michael; Adhikari, Shiba P.; Wu, Zili

    2016-05-24

    In the MXenes family of two-dimensional transition-metal carbides there were successful demonstrations of co-catalysts with rutile TiO2 for visible-light-induced solar hydrogen production from water splitting. The physicochemical properties of Ti3C2Tx MXene coupled with TiO2 were investigated by a variety of characterization techniques. The effect of the Ti3C2Tx loading on the photocatalytic performance of the TiO2/Ti3C2Tx composites was elucidated. Moreover, with an optimized Ti3C2Tx content of 5 wt %, the TiO2/Ti3C2Tx composite shows a 400 % enhancement in the photocatalytic hydrogen evolution reaction compared with that of pure rutile TiO2. We also expanded our exploration to other MXenes (Nb2CTx and Ti2CTx)more » as co-catalysts coupled with TiO2, and these materials also exhibited enhanced hydrogen production. These results manifest the generality of MXenes as effective co-catalysts for solar hydrogen production.« less

  5. Tritium production from a low voltage deuterium discharge on palladium and other metals

    SciTech Connect (OSTI)

    Claytor, T.N.; Jackson, D.D.; Tuggle, D.G.

    1995-09-01

    Over the past year the authors have been able to demonstrate that a plasma loading method produces an exciting and unexpected amount of tritium from small palladium wires. In contrast to electrochemical hydrogen or deuterium loading of palladium, this method yields a reproducible tritium generation rate when various electrical and physical conditions are met. Small diameter wires (100--250 microns) have been used with gas pressures above 200 torr at voltages and currents of about 2,000 V at 3--5 A. By carefully controlling the sputtering rate of the wire, runs have been extended to hundreds of hours allowing a significant amount (> 10`s nCi) of tritium to accumulate. they show tritium generation rates for deuterium-palladium foreground runs that are up to 25 times larger than hydrogen-palladium control experiments using materials from the same batch. They illustrate the difference between batches of annealed palladium and as received palladium from several batches as well as the effect of other metals (Pt, Ni, Nb, Zr, V, W, Hf) to demonstrate that the tritium generation rate can vary greatly from batch to batch.

  6. Neutronic fuel element fabrication

    DOE Patents [OSTI]

    Korton, George

    2004-02-24

    This disclosure describes a method for metallurgically bonding a complete leak-tight enclosure to a matrix-type fuel element penetrated longitudinally by a multiplicity of coolant channels. Coolant tubes containing solid filler pins are disposed in the coolant channels. A leak-tight metal enclosure is then formed about the entire assembly of fuel matrix, coolant tubes and pins. The completely enclosed and sealed assembly is exposed to a high temperature and pressure gas environment to effect a metallurgical bond between all contacting surfaces therein. The ends of the assembly are then machined away to expose the pin ends which are chemically leached from the coolant tubes to leave the coolant tubes with internal coolant passageways. The invention described herein was made in the course of, or under, a contract with the U.S. Atomic Energy Commission. It relates generally to fuel elements for neutronic reactors and more particularly to a method for providing a leak-tight metal enclosure for a high-performance matrix-type fuel element penetrated longitudinally by a multiplicity of coolant tubes. The planned utilization of nuclear energy in high-performance, compact-propulsion and mobile power-generation systems has necessitated the development of fuel elements capable of operating at high power densities. High power densities in turn require fuel elements having high thermal conductivities and good fuel retention capabilities at high temperatures. A metal clad fuel element containing a ceramic phase of fuel intimately mixed with and bonded to a continuous refractory metal matrix has been found to satisfy the above requirements. Metal coolant tubes penetrate the matrix to afford internal cooling to the fuel element while providing positive fuel retention and containment of fission products generated within the fuel matrix. Metal header plates are bonded to the coolant tubes at each end of the fuel element and a metal cladding or can completes the fuel-matrix enclosure

  7. Fuel Fabrication Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Programs CONVERT Fuel Fabrication Development (CONVERT) The nation looks to our uranium-processing capabilities to optimize fabrication of a fuel, which will enable certain ...

  8. Structure and yarn sensor for fabric

    DOE Patents [OSTI]

    Mee, D.K.; Allgood, G.O.; Mooney, L.R.; Duncan, M.G.; Turner, J.C.; Treece, D.A.

    1998-10-20

    A structure and yarn sensor for fabric directly determines pick density in a fabric thereby allowing fabric length and velocity to be calculated from a count of the picks made by the sensor over known time intervals. The structure and yarn sensor is also capable of detecting full length woven defects and fabric. As a result, an inexpensive on-line pick (or course) density measurement can be performed which allows a loom or knitting machine to be adjusted by either manual or automatic means to maintain closer fiber density tolerances. Such a sensor apparatus dramatically reduces fabric production costs and significantly improves fabric consistency and quality for woven or knitted fabric. 13 figs.

  9. AN INITIAL ASSESSMENT OF POTENTIAL PRODUCTION TECHNOLOGIES FOR EPSILON-METAL WASTE FORMS

    SciTech Connect (OSTI)

    Rohatgi, Aashish; Strachan, Denis M.

    2011-03-01

    This report examines and ranks a total of seven materials processing techniques that may be potentially utilized to consolidate the undissolved solids from nuclear fuel reprocessing into a low-surface area form. Commercial vendors of processing equipment were contacted and literature researched to gather information for this report. Typical equipment and their operation, corresponding to each of the seven techniques, are described in the report based upon the discussions and information provided by the vendors. Although the report does not purport to describe all the capabilities and issues of various consolidation techniques, it is anticipated that this report will serve as a guide by highlighting the key advantages and disadvantages of these techniques. The processing techniques described in this report were broadly classified into those that employed melting and solidification, and those in which the consolidation takes place in the solid-state. Four additional techniques were examined that were deemed impractical, but were included for completeness. The techniques were ranked based on criteria such as flexibility in accepting wide-variety of feed-stock (chemistry, form, and quantity), ease of long-term maintenance, hot cell space requirements, generation of additional waste streams, cost, and any special considerations. Based on the assumption of ~2.5 L of waste to be consolidated per day, sintering based techniques, namely, microwave sintering, spark plasma sintering and hot isostatic pressing, were ranked as the top-3 choices, respectively. Melting and solidification based techniques were ranked lower on account of generation of volatile phases and difficulties associated with reactivity and containment of the molten metal.

  10. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, Donald C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power.

  11. Ion traps fabricated in a CMOS foundry

    SciTech Connect (OSTI)

    Mehta, K. K.; Ram, R. J.; Eltony, A. M.; Chuang, I. L.; Bruzewicz, C. D.; Sage, J. M. Chiaverini, J.

    2014-07-28

    We demonstrate trapping in a surface-electrode ion trap fabricated in a 90-nm CMOS (complementary metal-oxide-semiconductor) foundry process utilizing the top metal layer of the process for the trap electrodes. The process includes doped active regions and metal interconnect layers, allowing for co-fabrication of standard CMOS circuitry as well as devices for optical control and measurement. With one of the interconnect layers defining a ground plane between the trap electrode layer and the p-type doped silicon substrate, ion loading is robust and trapping is stable. We measure a motional heating rate comparable to those seen in surface-electrode traps of similar size. This demonstration of scalable quantum computing hardware utilizing a commercial CMOS process opens the door to integration and co-fabrication of electronics and photonics for large-scale quantum processing in trapped-ion arrays.

  12. Update On Monolithic Fuel Fabrication Development

    SciTech Connect (OSTI)

    C. R Clark; J. M. Wight; G. C. Knighton; G. A. Moore; J. F. Jue

    2005-11-01

    Efforts to develop a viable monolithic research reactor fuel plate have continued at Idaho National Laboratory. These efforts have concentrated on both fabrication process refinement and scale-up to produce full sized fuel plates. Advancements have been made in the production of U-Mo foil including full sized foils. Progress has also been made in the friction stir welding and transient liquid phase bonding fabrication processes resulting in better bonding, more stable processes and the ability to fabricate larger fuel plates.

  13. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, D.C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power. 1 fig.

  14. Measurements of actinide-fission product yields in Caliban and Prospero metallic core reactor fission neutron fields

    SciTech Connect (OSTI)

    Casoli, P.; Authier, N. [CEA, Centre de Valduc, 21120 Is-sur-Tille (France); Laurec, J.; Bauge, E.; Granier, T. [CEA, Centre DIF, 91297 Arpajon (France)

    2011-07-01

    In the 1970's and early 1980's, an experimental program was performed on the facilities of the CEA Valduc Research Center to measure several actinide-fission product yields. Experiments were, in particular, completed on the Caliban and Prospero metallic core reactors to study fission-neutron-induced reactions on {sup 233}U, {sup 235}U, and {sup 239}Pu. Thick actinide samples were irradiated and the number of nuclei of each fission product was determined by gamma spectrometry. Fission chambers were irradiated simultaneously to measure the numbers of fissions in thin deposits of the same actinides. The masses of the thick samples and the thin deposits were determined by mass spectrometry and alpha spectrometry. The results of these experiments will be fully presented in this paper for the first time. A description of the Caliban and Prospero reactors, their characteristics and performances, and explanations about the experimental approach will also be given in the article. A recent work has been completed to analyze and reinterpret these measurements and particularly to evaluate the associated uncertainties. In this context, calculations have also been carried out with the Monte Carlo transport code Tripoli-4, using the published benchmarked Caliban description and a three-dimensional model of Prospero, to determine the average neutron energy causing fission. Simulation results will be discussed in this paper. Finally, new fission yield measurements will be proposed on Caliban and Prospero reactors to strengthen the results of the first experiments. (authors)

  15. Ceramic nanostructures and methods of fabrication

    SciTech Connect (OSTI)

    Ripley, Edward B.; Seals, Roland D.; Morrell, Jonathan S.

    2009-11-24

    Structures and methods for the fabrication of ceramic nanostructures. Structures include metal particles, preferably comprising copper, disposed on a ceramic substrate. The structures are heated, preferably in the presence of microwaves, to a temperature that softens the metal particles and preferably forms a pool of molten ceramic under the softened metal particle. A nano-generator is created wherein ceramic material diffuses through the molten particle and forms ceramic nanostructures on a polar site of the metal particle. The nanostructures may comprise silica, alumina, titania, or compounds or mixtures thereof.

  16. Fabrication of transparent ceramics using nanoparticles

    DOE Patents [OSTI]

    Cherepy, Nerine J; Tillotson, Thomas M; Kuntz, Joshua D; Payne, Stephen A

    2012-09-18

    A method of fabrication of a transparent ceramic using nanoparticles synthesized via organic acid complexation-combustion includes providing metal salts, dissolving said metal salts to produce an aqueous salt solution, adding an organic chelating agent to produce a complexed-metal sol, heating said complexed-metal sol to produce a gel, drying said gel to produce a powder, combusting said powder to produce nano-particles, calcining said nano-particles to produce oxide nano-particles, forming said oxide nano-particles into a green body, and sintering said green body to produce the transparent ceramic.

  17. Polymorphous computing fabric

    DOE Patents [OSTI]

    Wolinski, Christophe Czeslaw; Gokhale, Maya B.; McCabe, Kevin Peter

    2011-01-18

    Fabric-based computing systems and methods are disclosed. A fabric-based computing system can include a polymorphous computing fabric that can be customized on a per application basis and a host processor in communication with said polymorphous computing fabric. The polymorphous computing fabric includes a cellular architecture that can be highly parameterized to enable a customized synthesis of fabric instances for a variety of enhanced application performances thereof. A global memory concept can also be included that provides the host processor random access to all variables and instructions associated with the polymorphous computing fabric.

  18. Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons

    SciTech Connect (OSTI)

    Continental Shelf Associates, Inc.

    1999-08-16

    This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. Concentrations in produced water discharge plume/receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentrations of metals and hydrocarbons determined in the samples.

  19. Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons.

    SciTech Connect (OSTI)

    1997-06-01

    This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. concentrations in produced water discharge plume / receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentration of metals and hydrocarbons determined in the samples.

  20. Fabricated Metals Footprint, October 2012 (MECS 2006)

    SciTech Connect (OSTI)

    2012-10-19

    Manufacturing energy and carbon footprints map energy consumption and losses, as well as greenhouse gas emissions from fuel consumption, for fifteen individual U.S. manufacturing sectors (representing 94% of all manufacturing energy use) and for the entire manufacturing sector. By providing energy consumption and emissions figures broken down by end use, the footprints allow for comparisons of energy use and emissions sources both within and across sectors. The footprints portray a large amount of information for each sector, including: * Comparison of the energy generated offsite and transferred to facilities versus that generated onsite * Nature and amount of energy consumed by end use within facilities * Magnitude of the energy lost both outside and inside facility boundaries * Magnitude of the greenhouse gas emissions released as a result of manufacturing energy use. Energy losses indicate opportunities to improve efficiency by implementing energy management best practices, upgrading energy systems, and developing new technologies. Footprints are available below for each sector. Data is presented in two levels of detail. The first page provides a high- level snapshot of the offsite and onsite energy flow, and the second page shows the detail for onsite generation and end use of energy. The principle energy use data source is the U.S. Department of Energy (DOE) Energy Information Administration's (EIA's) Manufacturing Energy Consumption Survey (MECS), for consumption in the year 2006, when the survey was last completed.

  1. Fabricated Metals Footprint, December 2010 (MECS 2006)

    SciTech Connect (OSTI)

    none,

    2010-06-01

    Manufacturing energy and carbon footprints map fuel energy consumption and losses, as well as greenhouse gas emissions from fuel consumption, for fifteen individual U.S. manufacturing sectors (representing 94% of all manufacturing energy use) and for the entire manufacturing industry sector. By providing energy consumption and emissions figures broken down by end use, the footprints allow for comparisons of energy use and emissions sources both within and across sectors. The footprints portray a large amount of information for each sector, including: * Comparison of the energy generated offsite and transferred to facilities versus that generated onsite * Nature and amount of energy consumed by end use within facilities * Magnitude of the energy lost both outside and inside facility boundaries * Magnitude of the greenhouse gas emissions released due to the combustion of fuel. Energy losses indicate opportunities to improve efficiency by implementing energy management best practices, upgrading energy systems, and developing new technologies. Footprints are available below for each sector. Data is presented in two levels of detail. The first page provides a high-level snapshot of the offsite and onsite energy flow, and the second page shows the detail for onsite generation and end use of energy. The energy data is primarily provided by the U.S. Department of Energy (DOE) Energy Information Administration's (EIA's) Manufacturing Energy Consumption Survey (MECS), and therefore reflects consumption in the year 2006, when the survey was last completed.

  2. Foil fabrication for the ROMANO event

    SciTech Connect (OSTI)

    Romo, J.; Weed, J.; Griggs, G.; Brown, T.; Tassano, P.

    1984-02-22

    Activities reported include: nuclear target foil fabrication, parylene substrate preparation and production, calibration foil fabrication, and foil and substrate inspections. The processes developed and the techniques used to produce the foils are documented, and future directions of work are suggested. (LEW)

  3. Method of fabrication of electrodes and electrolytes

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.

    2004-01-06

    Fuel cell stacks contain an electrolyte layer surrounded on top and bottom by an electrode layer. Porous electrodes are prepared which enable fuel and oxidant to easily flow to the respective electrode-electrolyte interface without the need for high temperatures or pressures to assist the flow. Rigid, inert microspheres in combination with thin-film metal deposition techniques are used to fabricate porous anodes, cathodes, and electrolytes. Microshperes contained in a liquid are randomly dispersed onto a host structure and dried such that the microsperes remain in position. A thin-film deposition technique is subsequently employed to deposit a metal layer onto the microsperes. After such metal layer deposition, the microspheres are removed leaving voids, i.e. pores, in the metal layer, thus forming a porous electrode. Successive repetitions of the fabrication process result in the formation of a continuous fuel cell stack. Such stacks may produce power outputs ranging from about 0.1 Watt to about 50 Watts.

  4. Fabrication of boron sputter targets

    DOE Patents [OSTI]

    Makowiecki, Daniel M.; McKernan, Mark A.

    1995-01-01

    A process for fabricating high density boron sputtering targets with sufficient mechanical strength to function reliably at typical magnetron sputtering power densities and at normal process parameters. The process involves the fabrication of a high density boron monolithe by hot isostatically compacting high purity (99.9%) boron powder, machining the boron monolithe into the final dimensions, and brazing the finished boron piece to a matching boron carbide (B.sub.4 C) piece, by placing aluminum foil there between and applying pressure and heat in a vacuum. An alternative is the application of aluminum metallization to the back of the boron monolithe by vacuum deposition. Also, a titanium based vacuum braze alloy can be used in place of the aluminum foil.

  5. Fabrication of boron sputter targets

    DOE Patents [OSTI]

    Makowiecki, D.M.; McKernan, M.A.

    1995-02-28

    A process is disclosed for fabricating high density boron sputtering targets with sufficient mechanical strength to function reliably at typical magnetron sputtering power densities and at normal process parameters. The process involves the fabrication of a high density boron monolithe by hot isostatically compacting high purity (99.9%) boron powder, machining the boron monolithe into the final dimensions, and brazing the finished boron piece to a matching boron carbide (B{sub 4}C) piece, by placing aluminum foil there between and applying pressure and heat in a vacuum. An alternative is the application of aluminum metallization to the back of the boron monolithe by vacuum deposition. Also, a titanium based vacuum braze alloy can be used in place of the aluminum foil. 7 figs.

  6. Reference Alloy Waste Form Fabrication and Initiation of Reducing Atmosphere and Reductive Additives Study on Alloy Waste Form Fabrication

    SciTech Connect (OSTI)

    S.M. Frank; T.P. O'Holleran; P.A. Hahn

    2011-09-01

    This report describes the fabrication of two reference alloy waste forms, RAW-1(Re) and RAW-(Tc) using an optimized loading and heating method. The composition of the alloy materials was based on a generalized formulation to process various proposed feed streams resulting from the processing of used fuel. Waste elements are introduced into molten steel during alloy fabrication and, upon solidification, become incorporated into durable iron-based intermetallic phases of the alloy waste form. The first alloy ingot contained surrogate (non-radioactive), transition-metal fission products with rhenium acting as a surrogate for technetium. The second alloy ingot contained the same components as the first ingot, but included radioactive Tc-99 instead of rhenium. Understanding technetium behavior in the waste form is of particular importance due the longevity of Tc-99 and its mobility in the biosphere in the oxide form. RAW-1(Re) and RAW-1(Tc) are currently being used as test specimens in the comprehensive testing program investigating the corrosion and radionuclide release mechanisms of the representative alloy waste form. Also described in this report is the experimental plan to study the effects of reducing atmospheres and reducing additives to the alloy material during fabrication in an attempt to maximize the oxide content of waste streams that can be accommodated in the alloy waste form. Activities described in the experimental plan will be performed in FY12. The first aspect of the experimental plan is to study oxide formation on the alloy by introducing O2 impurities in the melt cover gas or from added oxide impurities in the feed materials. Reducing atmospheres will then be introduced to the melt cover gas in an attempt to minimize oxide formation during alloy fabrication. The second phase of the experimental plan is to investigate melting parameters associated with alloy fabrication to allow the separation of slag and alloy components of the melt.

  7. Neutron generators with size scalability, ease of fabrication and multiple ion source functionalities

    DOE Patents [OSTI]

    Elizondo-Decanini, Juan M

    2014-11-18

    A neutron generator is provided with a flat, rectilinear geometry and surface mounted metallizations. This construction provides scalability and ease of fabrication, and permits multiple ion source functionalities.

  8. Supported metal alloy catalysts

    DOE Patents [OSTI]

    Barrera, Joseph; Smith, David C.

    2000-01-01

    A process of preparing a Group IV, V, or VI metal carbonitride including reacting a Group IV, V, or VI metal amide complex with ammonia to obtain an intermediate product; and, heating the intermediate product to temperatures and for times sufficient to form a Group IV, V, or VI metal carbonitride is provided together with the product of the process and a process of reforming an n-alkane by use of the product.

  9. Photochemical cutting of fabrics

    DOE Patents [OSTI]

    Piltch, Martin S.

    1994-01-01

    Apparatus for the cutting of garment patterns from one or more layers of fabric. A laser capable of producing laser light at an ultraviolet wavelength is utilized to shine light through a pattern, such as a holographic phase filter, and through a lens onto the one or more layers of fabric. The ultraviolet laser light causes rapid photochemical decomposition of the one or more layers of fabric, but only along the pattern. The balance of the fabric of the one or more layers of fabric is undamaged.

  10. Spacecraft fabrication and test MODIL. Final report

    SciTech Connect (OSTI)

    Saito, T.T.

    1994-05-01

    This report covers the period from October 1992 through the close of the project. FY 92 closed out with the successful briefing to industry and with many potential and important initiatives in the spacecraft arena. Due to the funding uncertainties, we were directed to proceed as if our funding would be approximately the same as FY 92 ($2M), but not to make any major new commitments. However, the MODIL`s FY 93 funding was reduced to $810K and we were directed to concentrate on the cryocooler area. The cryocooler effort completed its demonstration project. The final meetings with the cryocooler fabricators were very encouraging as we witnessed the enthusiastic reception of technology to help them reduce fabrication uncertainties. Support of the USAF Phillips Laboratory cryocooler program was continued including kick-off meetings for the Prototype Spacecraft Cryocooler (PSC). Under Phillips Laboratory support, Gill Cruz visited British Aerospace and Lucas Aerospace in the United Kingdom to assess their manufacturing capabilities. In the Automated Spacecraft & Assembly Project (ASAP), contracts were pursued for the analysis by four Brilliant Eyes prime contractors to provide a proprietary snap shot of their current status of Integrated Product Development. In the materials and structure thrust the final analysis was completed of the samples made under the contract (``Partial Automation of Matched Metal Net Shape Molding of Continuous Fiber Composites``) to SPARTA. The Precision Technologies thrust funded the Jet Propulsion Laboratory to prepare a plan to develop a Computer Aided Alignment capability to significantly reduce the time for alignment and even possibly provide real time and remote alignment capability of systems in flight.

  11. Cost-Effective Fabrication Routes for the Productionof Quantum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost-Effective Fabrication Routes for the Production of Quantum Well Type Structures and Recovery of Waste Heat from Heavy Duty Trucks Automotive Thermoelectric Generators and HVAC ...

  12. Logomatic Gmbh Grinding Machines Fabrication | Open Energy Information

    Open Energy Info (EERE)

    Machines Fabrication Place: Mainaschaff, Germany Zip: D-63814 Sector: Solar Product: German manufacturer of capital equipment for semiconductor and solar industries; for solar,...

  13. Metal & Alloy Services | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal & Alloy Services The MPC specializes in the preparation, purification, and fabrication of high-purity rare earth metals, refractory metals, alkaline earth metals, and alloys in single and polycrystalline forms. Arc Casting. The interior of an arc casting furnace is shown. Arc casting has been employed for many years at ISU and Ames Laboratory, for preparing alloys and inter-metallic compounds for materials research. The molten metal in the center is zirconium, #40 on the periodic

  14. Integrated Recycling Test Fuel Fabrication

    SciTech Connect (OSTI)

    R.S. Fielding; K.H. Kim; B. Grover; J. Smith; J. King; K. Wendt; D. Chapman; L. Zirker

    2013-03-01

    The Integrated Recycling Test is a collaborative irradiation test that will electrochemically recycle used light water reactor fuel into metallic fuel feedstock. The feedstock will be fabricated into a metallic fast reactor type fuel that will be irradiation tested in a drop in capsule test in the Advanced Test Reactor on the Idaho National Laboratory site. This paper will summarize the fuel fabrication activities and design efforts. Casting development will include developing a casting process and system. The closure welding system will be based on the gas tungsten arc burst welding process. The settler/bonder system has been designed to be a simple system which provides heating and controllable impact energy to ensure wetting between the fuel and cladding. The final major pieces of equipment to be designed are the weld and sodium bond inspection system. Both x-radiography and ultrasonic inspection techniques have been examine experimentally and found to be feasible, however the final remote system has not been designed. Conceptual designs for radiography and an ultrasonic system have been made.

  15. Integrated System for Nanofiber Production | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated System for Nanofiber Production Technology available for licensing: Achieves true continuous scalable fabrication of oxide/metallic nanofibers or nanotubes by integrating electrospinning with controlled nanofiber deposition orientation, fast IR heating and pneumatic collection of nanofiber/nanotubes. It not only makes the production scalable, but also provides precise morphology control of the nanofiber/nanotubes. It can be easily switched between configurations to produce high

  16. Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication

    SciTech Connect (OSTI)

    Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

    2015-07-01

    This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

  17. METAL COMPOSITIONS

    DOE Patents [OSTI]

    Seybolt, A.U.

    1959-02-01

    Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

  18. BPAonFabric_jk

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is designed for practitioners who routinely examine bloodstained fabrics and other textiles and are required to assess, interpret and report on bloodstain patterns as part of...

  19. Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology

    SciTech Connect (OSTI)

    Sun, Z.H.I.; Xiao, Y.; Sietsma, J.; Agterhuis, H.; Visser, G.; Yang, Y.

    2015-01-15

    Highlights: • New characterisation methodology has been established to understand an industrially processed ICT waste. • Particle size distribution, composition, thermal–chemical behaviour and occurrence of metals were considered. • The characterisation provides direct guidelines for values recovery from the waste. - Abstract: Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process.

  20. Update on US High Density Fuel Fabrication Development

    SciTech Connect (OSTI)

    C.R. Clark; G.A. Moore; J.F. Jue; B.H. Park; N.P. Hallinan; D.M. Wachs; D.E. Burkes

    2007-03-01

    Second generation uranium molybdenum fuel has shown excellent in-reactor irradiation performance. This metallic fuel type is capable of being fabricated at much higher loadings than any presently used research reactor fuel. Due to the broad range of fuel types this alloy system encompasses—fuel powder to monolithic foil and binary fuel systems to multiple element additions—significant amounts of research and development have been conducted on the fabrication of these fuels. This paper presents an update of the US RERTR effort to develop fabrication techniques and the fabrication methods used for the RERTR-9A miniplate test.

  1. Recent results from the Spacecraft Fabrication and Test MODIL

    SciTech Connect (OSTI)

    Saito, T.T.

    1993-04-01

    The Spacecraft Fabrication and Test Manufacturing Operations Development and Integration Laboratory (SF&T MODIL) is working with SDIO program offices and contractors to reduce schedule and budget risks for SDIO systems as they go into production. The concurrent engineering thrust has identified potential high payoff areas. A materials and structures demonstration project has been successfully completed in partial automated closing of matched metal molds for a continuous fiber composite. In addition to excellent accuracy, the parts demonstrated excellent predictability and repeatability of physical properties. The cryocooler thrust successfully demonstrated and inserted precision technologies into a generic cryocooler part. The precision technologies thrust outlined two potentially high payoff areas in precision alignment and miniature rocket thrust measurement. The Producible Technology Working Group (PTWG) efforts identified the need for a test and assembly thrust. Due to funding limitations, continuing efforts are limited to the cryocooler thrust.

  2. Development of processes for the production of solar grade silicon from halides and alkali metals, Phase 1 and Phase 2. Final report, October 1979 - February 1981

    SciTech Connect (OSTI)

    Dickson, C.R.; Gould, R.K.; Felder, W.

    1981-03-01

    High temperature reactions of silicon halides with alkali metals for the production of solar grade silicon are described. Product separation and collection processes were evaluated, measure heat release parameters for scaling purposes and effects of reactants and/or products on materials of reactor construction were determined, and preliminary engineering and economic analysis of a scaled up process were made. The feasibility of the basic process to make and collect silicon was demonstrated. The jet impaction/separation process was demonstrated to be a purification process. The rate at which gas phase species from silicon particle precursors, the time required for silane decomposition to produce particles, and the competing rate of growth of silicon seed particles injected into a decomposing silane environment were determined. The extent of silane decomposition as a function of residence time, temperature, and pressure was measured by infrared absorption spectroscopy. A simplistic model is presented to explain the growth of silicon in a decomposing silane enviroment.

  3. Method of fabricating composite superconducting wire

    DOE Patents [OSTI]

    Strauss, Bruce P.; Reardon, Paul J.; Remsbottom, Robert H.

    1977-01-01

    An improvement in the method for preparing composite rods of superconducting alloy and normal metal from which multifilament composite superconducting wire is fabricated by bending longitudinally a strip of normal metal around a rod of superconductor alloy and welding the edges to form the composite rod. After the rods have preferably been provided with a hexagonal cross-sectional shape, a plurality of the rods are stacked into a normal metal extrusion can, sealed and worked to reduce the cross-sectional size and form multifilament wire. Diffusion barriers and high-electrical resistance barriers can easily be introduced into the wire by plating or otherwise coating the faces of the normal metal strip with appropriate materials.

  4. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

    1997-06-10

    Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

  5. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, James L.; Tran, Tri D.; Feikert, John H.; Mayer, Steven T.

    1997-01-01

    Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

  6. Method for fabricating laminated uranium composites

    DOE Patents [OSTI]

    Chapman, L.R.

    1983-08-03

    The present invention is directed to a process for fabricating laminated composites of uranium or uranium alloys and at least one other metal or alloy. The laminated composites are fabricated by forming a casting of the molten uranium with the other metal or alloy which is selectively positioned in the casting and then hot-rolling the casting into a laminated plate in or around which the casting components are metallurgically bonded to one another to form the composite. The process of the present invention provides strong metallurgical bonds between the laminate components primarily since the bond disrupting surface oxides on the uranium or uranium alloy float to the surface of the casting to effectively remove the oxides from the bonding surfaces of the components.

  7. Method to fabricate hollow microneedle arrays

    DOE Patents [OSTI]

    Kravitz, Stanley H.; Ingersoll, David; Schmidt, Carrie; Flemming, Jeb

    2006-11-07

    An inexpensive and rapid method for fabricating arrays of hollow microneedles uses a photoetchable glass. Furthermore, the glass hollow microneedle array can be used to form a negative mold for replicating microneedles in biocompatible polymers or metals. These microneedle arrays can be used to extract fluids from plants or animals. Glucose transport through these hollow microneedles arrays has been found to be orders of magnitude more rapid than natural diffusion.

  8. Metal Aminoboranes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Metal Aminoboranes Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction

  9. Fabricated torque shaft

    SciTech Connect (OSTI)

    Mashey, Thomas Charles

    2002-01-01

    A fabricated torque shaft is provided that features a bolt-together design to allow vane schedule revisions with minimal hardware cost. The bolt-together design further facilitates on-site vane schedule revisions with parts that are comparatively small. The fabricated torque shaft also accommodates stage schedules that are different one from another in non-linear inter-relationships as well as non-linear schedules for a particular stage of vanes.

  10. Mixed Oxide Fuel Fabrication Facility

    National Nuclear Security Administration (NNSA)

    0%2A en Mixed Oxide (MOX) Fuel Fabrication Facility http:nnsa.energy.govfieldofficessavannah-river-field-officemixed-oxide-mox-fuel-fabrication-facility

  11. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S.

    1992-01-01

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  12. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of cultivation systems.

  13. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, November 1994--February 1995

    SciTech Connect (OSTI)

    1995-03-01

    This second quarterly report describes work during the second three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSI) and the Center for Hazardous Materials Research (CHMR). The report describes the activities of the project team during the reporting period. The principal work has focussed upon the acquisition of by-product samples and their initial analysis. Other efforts during the second quarter have been directed toward identifying the first hazardous waste samples and preparing for their treatment and analysis. Relatively little data has yet been collected. Major presentation of technical details and data will appear for the first time in the third quarterly report. The activity on the project during the second quarter of Phase One, as presented in the following sections, has fallen into seven areas: (1) Acquiring by-products, (2) Analyzing by-products, (3) Identifying, analyzing and treating suitable hazardous wastes, (4) Carrying out the quality assurance/quality control program, (5) Developing background, and (6) Initiating public relations

  14. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  15. Microjet formation and hard x-ray production from a liquid metal target irradiated by intense femtosecond laser pulses

    SciTech Connect (OSTI)

    Lar'kin, A. Uryupina, D.; Ivanov, K.; Savel'ev, A.; Bonnet, T.; Gobet, F.; Hannachi, F.; Tarisien, M.; Versteegen, M.; Spohr, K.; Breil, J.; Chimier, B.; Dorchies, F.; Fourment, C.; Leguay, P.-M.; Tikhonchuk, V. T.

    2014-09-15

    By using a liquid metal as a target one may significantly enhance the yield of hard x-rays with a sequence of two intense femtosecond laser pulses. The influence of the time delay between the two pulses is studied experimentally and interpreted with numerical simulations. It was suggested that the first arbitrary weak pulse produces microjets from the target surface, while the second intense pulse provides an efficient electron heating and acceleration along the jet surface. These energetic electrons are the source of x-ray emission while striking the target surface. The microjet formation is explained based on the results given by both optical diagnostics and hydrodynamic modeling by a collision of shocks originated from two distinct zones of laser energy deposition.

  16. Micro-fabrication Techniques for Target Components

    SciTech Connect (OSTI)

    Miles, R; Hamilton, J; Crawford, J; Ratti, S; Trevino, J; Graff, T; Stockton, C; Harvey, C

    2008-06-10

    Micro-fabrication techniques, derived from the semi-conductor industry, can be used to make a variety of useful mechanical components for targets. A selection of these components including supporting cooling arms for prototype cryogenic inertial confinement fusion targets, stepped and graded density targets for materials dynamics experiments are described. Micro-fabrication enables cost-effective, simultaneous fabrication of multiple high-precision components with complex geometries. Micro-fabrication techniques such as thin-film deposition, photo-lithographic patterning and etch processes normally used in the semi-conductor manufacture industry, can be exploited to make useful mechanical target components. Micro-fabrication processes have in recent years been used to create a number of micro-electro-mechanical systems (MEMS) components such as pressure sensors, accelerometers, ink jet printer heads, microfluidics platforms and the like. These techniques consist primarily of deposition of thin films of material, photo-lithographic patterning and etching processes performed sequentially to produce three dimensional structures using essentially planar processes. While the planar technology can be limiting in terms of the possible geometries of the final product, advantages of using these techniques include the ability to make multiple complex structures simultaneously and cost-effectively. Target components fabricated using these techniques include the supporting cooling arms for cryogenic prototype fusion ignition targets, stepped targets for equation-of-state experiments, and graded density reservoirs for material strength experiments.

  17. High Speed, Low Cost Fabrication of Gas Diffusion Electrodes for Membrane Electrode Assemblies

    SciTech Connect (OSTI)

    DeCastro, Emory S.; Tsou, Yu-Min; Liu, Zhenyu

    2013-09-20

    Fabrication of membrane electrode assemblies (MEAs) depends on creating inks or pastes of catalyst and binder, and applying this suspension to either the membrane (catalyst coated membrane) or gas diffusion media (gas diffusion electrode) and respectively laminating either gas diffusion media or gas diffusion electrodes (GDEs) to the membrane. One barrier to cost effective fabrication for either of these approaches is the development of stable and consistent suspensions. This program investigated the fundamental forces that destabilize the suspensions and developed innovative approaches to create new, highly stable formulations. These more concentrated formulations needed fewer application passes, could be coated over longer and wider substrates, and resulted in significantly lower coating defects. In March of 2012 BASF Fuel Cell released a new high temperature product based on these advances, whereby our customers received higher performing, more uniform MEAs resulting in higher stack build yields. Furthermore, these new materials resulted in an “instant” increase in capacity due to higher product yields and material throughput. Although not part of the original scope of this program, these new formulations have also led us to materials that demonstrate equivalent performance with 30% less precious metal in the anode. This program has achieved two key milestones in DOE’s Manufacturing R&D program: demonstration of processes for direct coating of electrodes and continuous in-line measurement for component fabrication.

  18. Microfluidic channel fabrication method

    DOE Patents [OSTI]

    Arnold, Don W.; Schoeniger, Joseph S.; Cardinale, Gregory F.

    2001-01-01

    A new channel structure for microfluidic systems and process for fabricating this structure. In contrast to the conventional practice of fabricating fluid channels as trenches or grooves in a substrate, fluid channels are fabricated as thin walled raised structures on a substrate. Microfluidic devices produced in accordance with the invention are a hybrid assembly generally consisting of three layers: 1) a substrate that can or cannot be an electrical insulator; 2) a middle layer, that is an electrically conducting material and preferably silicon, forms the channel walls whose height defines the channel height, joined to and extending from the substrate; and 3) a top layer, joined to the top of the channels, that forms a cover for the channels. The channels can be defined by photolithographic techniques and are produced by etching away the material around the channel walls.

  19. Method for fabricating transistors using crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, Anthony M.

    1997-01-01

    A method for fabricating transistors using single-crystal silicon devices on glass. This method overcomes the potential damage that may be caused to the device during high voltage bonding and employs a metal layer which may be incorporated as part of the transistor. This is accomplished such that when the bonding of the silicon wafer or substrate to the glass substrate is performed, the voltage and current pass through areas where transistors will not be fabricated. After removal of the silicon substrate, further metal may be deposited to form electrical contact or add functionality to the devices. By this method both single and gate-all-around devices may be formed.

  20. MOX Fabrication Isolation Considerations

    SciTech Connect (OSTI)

    Eric L. Shaber; Bradley J Schrader

    2005-08-01

    This document provides a technical position on the preferred level of isolation to fabricate demonstration quantities of mixed oxide transmutation fuels. The Advanced Fuel Cycle Initiative should design and construct automated glovebox fabrication lines for this purpose. This level of isolation adequately protects the health and safety of workers and the general public for all mixed oxide (and other transmutation fuel) manufacturing efforts while retaining flexibility, allowing parallel development and setup, and minimizing capital expense. The basis regulations, issues, and advantages/disadvantages of five potential forms of isolation are summarized here as justification for selection of the preferred technical position.

  1. Nuclear Fabrication Consortium

    SciTech Connect (OSTI)

    Levesque, Stephen

    2013-04-05

    This report summarizes the activities undertaken by EWI while under contract from the Department of Energy (DOE) – Office of Nuclear Energy (NE) for the management and operation of the Nuclear Fabrication Consortium (NFC). The NFC was established by EWI to independently develop, evaluate, and deploy fabrication approaches and data that support the re-establishment of the U.S. nuclear industry: ensuring that the supply chain will be competitive on a global stage, enabling more cost-effective and reliable nuclear power in a carbon constrained environment. The NFC provided a forum for member original equipment manufactures (OEM), fabricators, manufacturers, and materials suppliers to effectively engage with each other and rebuild the capacity of this supply chain by : • Identifying and removing impediments to the implementation of new construction and fabrication techniques and approaches for nuclear equipment, including system components and nuclear plants. • Providing and facilitating detailed scientific-based studies on new approaches and technologies that will have positive impacts on the cost of building of nuclear plants. • Analyzing and disseminating information about future nuclear fabrication technologies and how they could impact the North American and the International Nuclear Marketplace. • Facilitating dialog and initiate alignment among fabricators, owners, trade associations, and government agencies. • Supporting industry in helping to create a larger qualified nuclear supplier network. • Acting as an unbiased technology resource to evaluate, develop, and demonstrate new manufacturing technologies. • Creating welder and inspector training programs to help enable the necessary workforce for the upcoming construction work. • Serving as a focal point for technology, policy, and politically interested parties to share ideas and concepts associated with

  2. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quartery report, August 1994--November 1994

    SciTech Connect (OSTI)

    1994-12-01

    This first quarterly report describes work during the first three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSO and the Center for Hazardous Materials Research (CHMR)). The report states the goals of the project - both general and specific - and then describes the activities of the project team during the reporting period. All of this work has been organizational and developmental in nature. No data has yet been collected. Technical details and data will appear for the first time in the second quarterly report and be the major topic of subsequent reports.

  3. Mechanistic studies aimed at the development of single site metal alkoxide catalysts for the production of polyoxygenates from renewable resources.

    SciTech Connect (OSTI)

    Chisholm, Malcolm H.

    2015-12-15

    The work proposed herein follows on directly from the existing 3 year grant and the request for funding is for 12 months to allow completion of this work and graduation of current students supported by DOE. The three primary projects are as follows. 1.) A comparative study of the reactivity of LMg(OR) (solvent), where L= a β-diiminate or pyrromethene ligand, in the ring-opening of cyclic esters. 2.) The homopolymerization of expoxides, particularly propylene oxide and styrene oxide, and their copolymerizations with carbon dioxide or organic anhydrides to yield polycarbonates or polyesters, respectively. 3.) The development of well-defined bismuth (III) complexes for ring-opening polymerizations that are tolerant of both air and water. In each of these topics special emphasis is placed on developing a detailed mechanistic understanding of the ring-opening event and how this is modified by the employment of specific metal and ligand combinations. This document also provides a report on findings of the past grant period that are not yet in the public domain/published and shows how the proposed work will bring the original project to conclusion.

  4. Lithographic fabrication of nanoapertures

    DOE Patents [OSTI]

    Fleming, James G.

    2003-01-01

    A new class of silicon-based lithographically defined nanoapertures and processes for their fabrication using conventional silicon microprocessing technology have been invented. The new ability to create and control such structures should significantly extend our ability to design and implement chemically selective devices and processes.

  5. Fabrication of fiber supported ionic liquids and methods of use

    DOE Patents [OSTI]

    Luebke, David R; Wickramanayake, Shan

    2013-02-26

    One or more embodiments relates to the production of a fabricated fiber having an asymmetric polymer network and having an immobilized liquid such as an ionic liquid within the pores of the polymer network. The process produces the fabricated fiber in a dry-wet spinning process using a homogenous dope solution, providing significant advantage over current fabrication methods for liquid-supporting polymers. The fabricated fibers may be effectively utilized for the separation of a chemical species from a mixture based on the selection of the polymer, the liquid, and the solvent utilized in the dope.

  6. Upgrading platform using alkali metals

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  7. Polymer micromold and fabrication process

    DOE Patents [OSTI]

    Lee, A.P.; Northrup, M.A.; Ahre, P.E.; Dupuy, P.C.

    1997-08-19

    A mold assembly is disclosed with micro-sized features in which the hollow portion thereof is fabricated from a sacrificial mandrel which is surface treated and then coated to form an outer shell. The sacrificial mandrel is then selectively etched away leaving the outer shell as the final product. The sacrificial mandrel is fabricated by a precision lathe, for example, so that when removed by etching the inner or hollow area has diameters as small as 10`s of micros ({micro}m). Varying the inside diameter contours of the mold can be accomplished with specified ramping slopes formed on the outer surface of the sacrificial mandrel, with the inside or hollow section being, for example, 275 {micro}m in length up to 150 {micro}m in diameter within a 6 mm outside diameter (o.d.) mold assembly. The mold assembly itself can serve as a micronozzle or microneedle, and plastic parts, such as microballoons for angioplasty, polymer microparts, and microactuators, etc., may be formed within the mold assembly. 6 figs.

  8. Polymer micromold and fabrication process

    DOE Patents [OSTI]

    Lee, Abraham P. (1428 Whitecliff Way, Walnut Creek, CA 94596); Northrup, M. Allen (923 Creston Rd., Berkeley, CA 94708); Ahre, Paul E. (1299 Gonzaga Ct., Livermore, CA 94550); Dupuy, Peter C. (1736 Waldo Ct., Modesto, CA 95358)

    1997-01-01

    A mold assembly with micro-sized features in which the hollow portion thereof is fabricated from a sacrificial mandrel which is surface treated and then coated to form an outer shell. The sacrificial mandrel is then selectively etched away leaving the outer shell as the final product. The sacrificial mandrel is fabricated by a precision lathe, for example, so that when removed by etching the inner or hollow area has diameters as small as 10's of micros (.mu.m). Varying the inside diameter contours of the mold can be accomplished with specified ramping slopes formed on the outer surface of the sacrificial mandrel, with the inside or hollow section being, for example, 275 .mu.m in length up to 150 .mu.m in diameter within a 6 mm outside diameter (o.d.) mold assembly. The mold assembly itself can serve as a micronozzle or microneedle, and plastic parts, such as microballoons for angioplasty, polymer microparts, and microactuators, etc., may be formed within the mold assembly.

  9. Method of fabricating a flow device

    DOE Patents [OSTI]

    Hale, Robert L.

    1978-01-01

    This invention is a novel method for fabricating leak-tight tubular articles which have an interior flow channel whose contour must conform very closely with design specifications but which are composed of metal which tends to warp if welded. The method comprises designing two longitudinal half-sections of the article, the half-sections being contoured internally to cooperatively form the desired flow passageway. Each half-section is designed with a pair of opposed side flanges extending between the end flanges and integral therewith. The half-sections are positioned with their various flanges in confronting relation and with elongated metal gaskets extending between the confronting flanges for the length of the array. The gaskets are a deformable metal which is fusion-weldable to the end flanges. The mating side flanges are joined mechanically to deform the gaskets and provide a longitudinally sealed assembly. The portions of the end flanges contiguous with the ends of the gaskets then are welded to provide localized end welds which incorporate ends of the gaskets, thus transversely sealing the assembly. This method of fabrication provides leak-tight articles having the desired precisely contoured flow channels, whereas various conventional methods have been found unsatisfactory.

  10. Innovative forming and fabrication technologies : new opportunities.

    SciTech Connect (OSTI)

    Davis, B.; Hryn, J.; Energy Systems; Kingston Process Metallurgy, Inc.

    2008-01-31

    The advent of light metal alloys and advanced materials (polymer, composites, etc.) have brought the possibility of achieving important energy reductions into the full life cycle of these materials, especially in transportation applications. 1 These materials have gained acceptance in the aerospace industry but use of light metal alloys needs to gain wider acceptance in other commercial transportation areas. Among the main reasons for the relatively low use of these materials are the lack of manufacturability, insufficient mechanical properties, and increased material costs due to processing inefficiencies. Considering the enormous potential energy savings associated with the use of light metal alloys and advanced materials in transportation, there is a need to identify R&D opportunities in the fields of materials fabrication and forming aimed at developing materials with high specific mechanical properties combined with energy efficient processes and good manufacturability. This report presents a literature review of the most recent developments in the areas of fabrication and metal forming focusing principally on aluminum alloys. In the first section of the document, the different sheet manufacturing technologies including direct chill (DC) casting and rolling, spray forming, spray rolling, thin slab, and strip casting are reviewed. The second section of the document presents recent research on advanced forming processes. The various forming processes reviewed are: superplastic forming, electromagnetic forming, age forming, warm forming, hydroforming, and incremental forming. Optimization of conventional forming processes is also discussed. Potentially interesting light metal alloys for high structural efficiency including aluminum-scandium, aluminum-lithium, magnesium, titanium, and amorphous metal alloys are also reviewed. This section concludes with a discussion on alloy development for manufacturability. The third section of the document reviews the latest

  11. Mesoporous Silica-Supported Metal Oxide-Promoted Rh Nanocatalyst for Selective Production of Ethanol from Syngas

    SciTech Connect (OSTI)

    George Kraus

    2010-09-30

    The objective is to develop a process that will convert synthesis gas from coal into ethanol and then transform the ethanol into hydrogen. Principal investigators from Iowa State University include Dr. George Kraus, Dr. Victor Lin, Marek Pruski, and Dr. Robert Brown. Task 1 involves catalyst development and catalyst scale up. Mesoporous manganese silicate mixed oxide materials will be synthesized, characterized and evaluated. The first-and secondgeneration catalysts have been prepared and scaled up for use in Task 2. The construction of a high-pressure reactor system for producing synthetic liquid fuel from simulated synthesis gas stream has been completed as the first step in Task 2. Using the first- and second generation catalysts, the reactor has demonstrated the production of synthetic liquid fuel from a simulated synthesis gas stream.

  12. Method of producing catalytic materials for fabricating nanostructures

    SciTech Connect (OSTI)

    Seals, Roland D; Menchhofer, Paul A; Howe, Jane Y; Wang, Wei

    2013-02-19

    Methods of fabricating nano-catalysts are described. In some embodiments the nano-catalyst is formed from a powder-based substrate material and is some embodiments the nano-catalyst is formed from a solid-based substrate material. In some embodiments the substrate material may include metal, ceramic, or silicon or another metalloid. The nano-catalysts typically have metal nanoparticles disposed adjacent the surface of the substrate material. The methods typically include functionalizing the surface of the substrate material with a chelating agent, such as a chemical having dissociated carboxyl functional groups (--COO), that provides an enhanced affinity for metal ions. The functionalized substrate surface may then be exposed to a chemical solution that contains metal ions. The metal ions are then bound to the substrate material and may then be reduced, such as by a stream of gas that includes hydrogen, to form metal nanoparticles adjacent the surface of the substrate.

  13. Composite fabrication via resin transfer molding technology

    SciTech Connect (OSTI)

    Jamison, G.M.; Domeier, L.A.

    1996-04-01

    The IMPReS (Integrated Modeling and Processing of Resin-based Structures) Program was funded in FY95 to consolidate, evaluate and enhance Sandia`s capabilities in the design and fabrication of composite structures. A key driver of this and related programs was the need for more agile product development processes and for model based design and fabrication tools across all of Sandia`s material technologies. A team of polymer, composite and modeling personnel was assembled to benchmark Sandia`s existing expertise in this area relative to industrial and academic programs and to initiate the tasks required to meet Sandia`s future needs. RTM (Resin Transfer Molding) was selected as the focus composite fabrication technology due to its versatility and growing use in industry. Modeling efforts focused on the prediction of composite mechanical properties and failure/damage mechanisms and also on the uncured resin flow processes typical of RTM. Appropriate molds and test composites were fabricated and model validation studies begun. This report summarizes and archives the modeling and fabrication studies carried out under IMPReS and evaluates the status of composite technology within Sandia. It should provide a complete and convenient baseline for future composite technology efforts within Sandia.

  14. Materials & Fabrication

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fabrication - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  15. Sumitomo Metal Industries Ltd Sumitomo Metals | Open Energy Informatio...

    Open Energy Info (EERE)

    Industries Ltd (Sumitomo Metals) Place: Osaka-shi, Osaka, Japan Zip: 540-0041 Sector: Solar Product: Engaged in the steel, engineering, and electronics businesses; works on...

  16. Anchored nanostructure materials and method of fabrication

    SciTech Connect (OSTI)

    Seals, Roland D; Menchhofer, Paul A; Howe, Jane Y; Wang, Wei

    2012-11-27

    Anchored nanostructure materials and methods for their fabrication are described. The anchored nanostructure materials may utilize nano-catalysts that include powder-based or solid-based support materials. The support material may comprise metal, such as NiAl, ceramic, a cermet, or silicon or other metalloid. Typically, nanoparticles are disposed adjacent a surface of the support material. Nanostructures may be formed as anchored to nanoparticles that are adjacent the surface of the support material by heating the nano-catalysts and then exposing the nano-catalysts to an organic vapor. The nanostructures are typically single wall or multi-wall carbon nanotubes.

  17. Thin film lithium-based batteries and electrochromic devices fabricated with nanocomposite electrode materials

    DOE Patents [OSTI]

    Gillaspie, Dane T; Lee, Se-Hee; Tracy, C. Edwin; Pitts, John Roland

    2014-02-04

    Thin-film lithium-based batteries and electrochromic devices (10) are fabricated with positive electrodes (12) comprising a nanocomposite material composed of lithiated metal oxide nanoparticles (40) dispersed in a matrix composed of lithium tungsten oxide.

  18. MEA Fabrication | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MEA Fabrication MEA Fabrication Presented at the 2009 High Temperature Membrane Working Group Meeting held May 18, 2009, in Arlington, Virginia htmwg_may09_mea_fabrication.pdf (678.88 KB) More Documents & Publications Integration of Non-Traditional Membranes into MEAs FSEC's MEA Test Protocol Membrane Performance and Durability Overview for Automotive Fuel Cell Applications

  19. Method of fabricating conductive electrodes on the front and backside of a thin film structure

    DOE Patents [OSTI]

    Tabada, Phillipe J.; Tabada, legal representative, Melody; Pannu, Satinderpall S.

    2011-05-22

    A method of fabricating a thin film device having conductive front and backside electrodes or contacts. Top-side cavities are first formed on a first dielectric layer, followed by the deposition of a metal layer on the first dielectric layer to fill the cavities. Defined metal structures are etched from the metal layer to include the cavity-filled metal, followed by depositing a second dielectric layer over the metal structures. Additional levels of defined metal structures may be formed in a similar manner with vias connecting metal structures between levels. After a final dielectric layer is deposited, a top surface of a metal structure of an uppermost metal layer is exposed through the final dielectric layer to form a front-side electrode, and a bottom surface of a cavity-filled portion of a metal structure of a lowermost metal layer is also exposed through the first dielectric layer to form a back-side electrode.

  20. Method of producing adherent metal oxide coatings on metallic surfaces

    DOE Patents [OSTI]

    Lane, Michael H.; Varrin, Jr., Robert D.

    2001-01-01

    Provided is a process of producing an adherent synthetic corrosion product (sludge) coating on metallic surfaces. The method involves a chemical reaction between a dry solid powder mixture of at least one reactive metal oxide with orthophosphoric acid to produce a coating in which the particles are bound together and the matrix is adherent to the metallic surface.

  1. Fiber metal interlayer improves ceramic coating performance

    SciTech Connect (OSTI)

    Jarrabet, G.P.

    1994-11-01

    This article is a review of the use of a compliant fiber metal inner layer between a ceramic coating and metal. The material used is Zirconia with phase stabilizers of magnesium oxide, calcium oxide, and yttrium oxide. Design, fabrication, and testing of the stabilized zirconia is discussed.

  2. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  3. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N.; Watkin, John G.

    1992-01-01

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  4. SF 6431-E;ARTICLES FOR PROCESS AND FABRICATION LABORATORY PROCUREMENT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (7-2013) Supersedes (4-2000) issue Procurement Center Albuquerque, New Mexico 87185 ARTICLES FOR PROCESS AND FABRICATION LABORATORY PROCUREMENT 1. GENERAL PRODUCT and INSPECTION...

  5. Fabrication of boron articles

    DOE Patents [OSTI]

    Benton, Samuel T.

    1976-01-01

    This invention is directed to the fabrication of boron articles by a powder metallurgical method wherein the articles are of a density close to the theoretical density of boron and are essentially crackfree. The method comprises the steps of admixing 1 to 10 weight percent carbon powder with amorphous boron powder, cold pressing the mixture and then hot pressing the cold pressed compact into the desired article. The addition of the carbon to the mixture provides a pressing aid for inhibiting the cracking of the hot pressed article and is of a concentration less than that which would cause the articles to possess significant concentrations of boron carbide.

  6. Mask fabrication process

    DOE Patents [OSTI]

    Cardinale, Gregory F.

    2000-01-01

    A method for fabricating masks and reticles useful for projection lithography systems. An absorber layer is conventionally patterned using a pattern and etch process. Following the step of patterning, the entire surface of the remaining top patterning photoresist layer as well as that portion of an underlying protective photoresist layer where absorber material has been etched away is exposed to UV radiation. The UV-exposed regions of the protective photoresist layer and the top patterning photoresist layer are then removed by solution development, thereby eliminating the need for an oxygen plasma etch and strip and chances for damaging the surface of the substrate or coatings.

  7. Electrochemical fabrication of capacitors

    DOE Patents [OSTI]

    Mansour, Azzam N. (Fairfax Sta., VA); Melendres, Carlos A. (Lemont, IL)

    1999-01-01

    A film of nickel oxide is anodically deposited on a graphite sheet held in osition on an electrochemical cell during application of a positive electrode voltage to the graphite sheet while exposed to an electrolytic nickel oxide solution within a volumetrically variable chamber of the cell. An angularly orientated x-ray beam is admitted into the cell for transmission through the deposited nickel oxide film in order to obtain structural information while the film is subject to electrochemical and in-situ x-ray spectroscopy from which optimum film thickness, may be determined by comparative analysis for capacitor fabrication purposes.

  8. Intraocular lens fabrication

    DOE Patents [OSTI]

    Salazar, Mike A.; Foreman, Larry R.

    1997-01-01

    This invention describes a method for fabricating an intraocular lens made rom clear Teflon.TM., Mylar.TM., or other thermoplastic material having a thickness of about 0.025 millimeters. These plastic materials are thermoformable and biocompatable with the human eye. The two shaped lenses are bonded together with a variety of procedures which may include thermosetting and solvent based adhesives, laser and impulse welding, and ultrasonic bonding. The fill tube, which is used to inject a refractive filling material is formed with the lens so as not to damage the lens shape. A hypodermic tube may be included inside the fill tube.

  9. FUEL ELEMENT FABRICATION METHOD

    DOE Patents [OSTI]

    Hix, J.N.; Cooley, G.E.; Cunningham, J.E.

    1960-05-31

    A method is given for assembling and fabricating a fuel element comprising a plurality of spaced parallel fuel plates of a bowed configuration supported by and between a pair of transperse aluminum side plates. In this method, a brasing alloy is preplated on one surface of the aluminum side plates in the form of a cladding or layer-of uniform thickness. Grooves are then cut into the side plates through the alloy layer and into the base aluminum which results in the utilization of thinner aluminum side plates since a portion of the necessary groove depth is supplied by the brazing alloy.

  10. Intraocular lens fabrication

    DOE Patents [OSTI]

    Salazar, M.A.; Foreman, L.R.

    1997-07-08

    This invention describes a method for fabricating an intraocular lens made from clear Teflon{trademark}, Mylar{trademark}, or other thermoplastic material having a thickness of about 0.025 millimeters. These plastic materials are thermoformable and biocompatable with the human eye. The two shaped lenses are bonded together with a variety of procedures which may include thermosetting and solvent based adhesives, laser and impulse welding, and ultrasonic bonding. The fill tube, which is used to inject a refractive filling material is formed with the lens so as not to damage the lens shape. A hypodermic tube may be included inside the fill tube. 13 figs.

  11. Microstructure fabrication process induced modulations in CVD graphene

    SciTech Connect (OSTI)

    Matsubayashi, Akitomo Zhang, Zhenjun; Lee, Ji Ung; LaBella, Vincent P.

    2014-12-15

    The systematic Raman spectroscopic study of a mimicked graphene device fabrication is presented. Upon photoresist baking, compressive stress is induced in the graphene which disappears after it is removed. The indirect irradiation from the electron beam (through the photoresist) does not significantly alter graphene characteristic Raman peaks indicating that graphene quality is preserved upon the exposure. The 2D peak shifts and the intensity ratio of 2D and G band, I(2D)/I(G), decreases upon direct metal deposition (Co and Py) suggesting that the electronic modulation occurs due to sp{sup 2} C-C bond weakening. In contrast, a thin metal oxide film deposited graphene does not show either the significant 2D and G peaks shift or I(2D)/I(G) decrease upon the metal deposition suggesting the oxide protect the graphene quality in the fabrication process.

  12. Project Plan Remote Target Fabrication Refurbishment Project

    SciTech Connect (OSTI)

    Bell, Gary L; Taylor, Robin D

    2009-08-01

    In early FY2009, the DOE Office of Science - Nuclear Physics Program reinstated a program for continued production of {sup 252}Cf and other transcurium isotopes at the Radiochemical Engineering Development Center (REDC) at Oak Ridge National Laboratory (ORNL). The FY2009 major elements of the workscope are as follows: (1) Recovery and processing of seven transuranium element targets undergoing irradiation at the High Flux Isotope Reactor (HFIR) at ORNL; (2) Development of a plan to manufacture new targets for irradiation beginning in early- to mid-FY10 to supply irradiated targets for processing Campaign 75 (TRU75); and (3) Refurbishment of the target manufacturing equipment to allow new target manufacture in early FY10 The {sup 252}Cf product from processing Campaign 74 (recently processed and currently shipping to customers) is expected to supply the domestic demands for a period of approximately two years. Therefore it is essential that new targets be introduced for irradiation by the second quarter of FY10 (HFIR cycle 427) to maintain supply of {sup 252}Cf; the average irradiation period is {approx}10 HFIR cycles, requiring about 1.5 calendar years. The strategy for continued production of {sup 252}Cf depends upon repairing and refurbishing the existing pellet and target fabrication equipment for one additional target production campaign. This equipment dates from the mid-1960s to the late 1980s, and during the last target fabrication campaign in 2005- 2006, a number of component failures and operations difficulties were encountered. It is expected that following the target fabrication and acceptance testing of the targets that will supply material for processing Campaign 75 a comprehensive upgrade and replacement of the remote hot-cell equipment will be required prior to subsequent campaigns. Such a major refit could start in early FY 2011 and would take about 2 years to complete. Scope and cost estimates for the repairs described herein were developed, and

  13. Fabrication and Testing of Deflecting Cavities for APS

    SciTech Connect (OSTI)

    Mammosser, John; Wang, Haipeng; Rimmer, Robert; Jim, Henry; Katherine, Wilson; Dhakal, Pashupati; Ali, Nassiri; Jim, Kerby; Jeremiah, Holzbauer; Genfa, Wu; Joel, Fuerst; Yawei, Yang; Zenghai, Li

    2013-09-01

    Jefferson Lab (Newport News, Virginia) in collaboration with Argonne National Laboratory (Argonne, IL) has fabricated and tested four first article, 2.8 GHz, deflecting SRF cavities, for Argonne's Short-Pulse X-ray (SPX) project. These cavities are unique in many ways including the fabrication techniques in which the cavity cell and waveguides were fabricated. These cavity subcomponents were milled from bulk large grain niobium ingot material directly from 3D CAD files. No forming of sub components was used with the exception of the beam-pipes. The challenging cavity and helium vessel design and fabrication results from the stringent RF performance requirements required by the project and operation in the APS ring. Production challenges and fabrication techniques as well as testing results will be discussed in this paper.

  14. Method of making patterned helical metallic ribbon for continuous edge winding applications

    DOE Patents [OSTI]

    Liebermann, Howard H.; Frischmann, Peter G.; Rosenberry, Jr., George M.

    1982-08-10

    Metallic ribbon having cutout patterns therein is fabricated in continuous helical form by directing a melt stream or jet onto a rapidly moving patterned substrate surface.

  15. Method of making patterned helical metallic ribbon for continuous edge winding applications

    DOE Patents [OSTI]

    Liebermann, H.H.; Frischmann, P.G.; Rosenberry, G.M. Jr.

    1982-08-10

    Metallic ribbon having cutout patterns therein is fabricated in continuous helical form by directing a melt stream or jet onto a rapidly moving patterned substrate surface. 10 figs.

  16. Fuel Fabrication Capability Research and Development Plan

    SciTech Connect (OSTI)

    Senor, David J.; Burkes, Douglas

    2014-04-17

    is between now and 2016 when the candidate processes are down-selected in preparation for the MP-1, FSP-1, and MP-2 plate manufacturing campaigns. A number of key risks identified by the FFC are discussed in this plan, with recommended mitigating actions for those activities within FFC, and identification of risks that are impacted by activities in other areas of the Convert Program. The R&D Plan does not include discussion of FFC initiatives related to production-scale manufacturing of fuel (e.g., establishment of the Pilot Line Production Facility), rather, the goal of this plan is to document the R&D activities needed ultimately to enable high-quality and cost-effective production of the fuel by the commercial fuel fabricator. The intent is for this R&D Plan to be a living document that will be reviewed and updated on a regular basis (e.g., annually) to ensure that FFC R&D activities remain properly aligned to the needs of the Convert Program. This version of the R&D Plan represents the first annual review and revision.

  17. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J.

    1984-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  18. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, Lawrence J.

    1986-01-01

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  19. Electroless metal plating of plastics

    DOE Patents [OSTI]

    Krause, L.J.

    1982-09-20

    Process for plating main group metals on aromatic polymers is carried out by the use of a nonaqueous solution of a salt of an alkali metal in a positive valence state and a main group metal in a negative valence state with contact between the solution and polymer providing a redox reaction causing the deposition of the main group metal and the reduction of the polymer. Products from the process exhibit useful decorative and electrical properties.

  20. Fate of Noble Metals during the Pyroprocessing of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; D. Vaden; S.X. Li; G.L. Fredrickson; R.D. Mariani

    2009-09-01

    During the pyroprocessing of spent nuclear fuel by electrochemical techniques, fission products are separated as the fuel is oxidized at the anode and refined uranium is deposited at the cathode. Those fission products that are oxidized into the molten salt electrolyte are considered active metals while those that do not react are considered noble metals. The primary noble metals encountered during pyroprocessing are molybdenum, zirconium, ruthenium, rhodium, palladium, and technetium. Pyroprocessing of spent fuel to date has involved two distinctly different electrorefiner designs, in particular the anode to cathode configuration. For one electrorefiner, the anode and cathode collector are horizontally displaced such that uranium is transported across the electrolyte medium. As expected, the noble metal removal from the uranium during refining is very high, typically in excess of 99%. For the other electrorefiner, the anode and cathode collector are vertically collocated to maximize uranium throughput. This arrangement results in significantly less noble metals removal from the uranium during refining, typically no better than 20%. In addition to electrorefiner design, operating parameters can also influence the retention of noble metals, albeit at the cost of uranium recovery. Experiments performed to date have shown that as much as 100% of the noble metals can be retained by the cladding hulls while affecting the uranium recovery by only 6%. However, it is likely that commercial pyroprocessing of spent fuel will require the uranium recovery to be much closer to 100%. The above mentioned design and operational issues will likely be driven by the effects of noble metal contamination on fuel fabrication and performance. These effects will be presented in terms of thermal properties (expansion, conductivity, and fusion) and radioactivity considerations. Ultimately, the incorporation of minor amounts of noble metals from pyroprocessing into fast reactor metallic fuel

  1. AFIP-4 Fabrication Summary Report

    SciTech Connect (OSTI)

    Glenn A. Moore

    2010-02-01

    The AFIP-4 (ATR Full –size-plate In center flux trap Position) experiment was designed to evaluate the performance of monolithic fuels at a scale prototypic of research reactor fuel plates. Twelve qualified fueled plates were fabricated for the AFIP-4 experiment; to be irradiated in the INL Advanced Test Reactor (ATR). This report provides details of the fuel fabrication efforts; including material selection, fabrication processes, and fuel plate qualification.

  2. AFIP-6 Fabrication Summary Report

    SciTech Connect (OSTI)

    Glenn A. Moore; M. Craig Marshall

    2011-09-01

    The AFIP-6 (ATR Full-size plate In center flux trap Position) experiment was designed to evaluate the performance of monolithic fuels at a scale prototypic of research reactor fuel plates. Two qualified fueled plates were fabricated for the AFIP-6 experiment; to be irradiated in the INL Advanced Test Reactor (ATR). This report provides details of the fuel fabrication efforts, including material selection, fabrication processes, and fuel plate qualification.

  3. AFIP-2 Fabrication Summary Report

    SciTech Connect (OSTI)

    Glenn Moore

    2010-02-01

    The Advanced Test Reactor (ATR) Full-size Plate In Center Flux Trap Position (AFIP)-2 experiment was designed to evaluate the performance of monolithic fuels at a scale prototypic of research reactor fuel plates. Two qualified fueled plates were fabricated for the AFIP 2 experiment to be irradiated in the Idaho National Laboratory ATR. This report provides details of the fuel fabrication efforts, including material selection, fabrication processes, and fuel plate qualification.

  4. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, Oscar H.; Curtis, Paul G.

    1992-01-01

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof.

  5. Method of coating metal surfaces to form protective metal coating thereon

    DOE Patents [OSTI]

    Krikorian, O.H.; Curtis, P.G.

    1992-03-31

    A process is disclosed for forming a protective metal coating on a metal surface using a flux consisting of an alkali metal fluoride, an alkaline earth metal fluoride, an alkali metal fluoaluminate, an alkali metal fluosilicate, and mixtures thereof. The flux, in particulate form, is mixed with particles of a metal coating material which may comprise aluminum, chromium, mixtures thereof, and alloys containing at least 50 wt. % aluminum and the particulate mixture is applied to the metal surface in a single step, followed by heating the coated metal surface to a temperature sufficient to cause the metal coating material to react with the metal surface to form a protective reaction product in the form of a metal coating bonded to the metal surface. The metal surface which reacts with the metal coating material to form the protective coating may comprise Fe, Co, Ni, Ti, V, Cr, Mn, Zr, Nb, Mo, Tc, Hf, Ta, W, Re and alloys thereof. 1 figure.

  6. Integrated porous-silicon light-emitting diodes: A fabrication process using graded doping profiles

    SciTech Connect (OSTI)

    Barillaro, G.; Diligenti, A.; Pieri, F.; Fuso, F.; Allegrini, M.

    2001-06-25

    A fabrication process, compatible with an industrial bipolar+complementary metal{endash}oxide{endash}semiconductor (MOS)+diffusion MOS technology, has been developed for the fabrication of efficient porous-silicon-based light-emitting diodes. The electrical contact is fabricated with a double n{sup +}/p doping, achieving a high current injection efficiency and thus lower biasing voltages. The anodization is performed as the last step of the process, thus reducing potential incompatibilities with industrial processes. The fabricated devices show yellow-orange electroluminescence, visible with the naked eye in room lighting. A spectral characterization of light emission is presented and briefly discussed. {copyright} 2001 American Institute of Physics.

  7. BNL 56 MHz HOM Damper Prototype Fabrication at JLab

    SciTech Connect (OSTI)

    Huque, Naeem A.; Daly, Edward F.; Clemens, William A.; McIntyre, Gary T.; Wu, Qiong; Seberg, Scott; Bellavia, Steve

    2015-09-01

    A prototype Higher-Order Mode (HOM) Damper was fabricated at JLab for the Relativistic Heavy-Ion Collider's (RHIC) 56 MHz cavity at Brookhaven National Laboratory (BNL). Primarily constructed from high RRR Niobium and Sapphire, the coaxial damper presented significant challenges in electron-beam welding (EBW), brazing and machining via acid etching. The results of the prototype operation brought about changes in the damper design, due to overheating braze alloys and possible multi-pacting. Five production HOM dampers are currently being fabricated at JLab. This paper outlines the challenges faced in the fabrication process, and the solutions put in place.

  8. Nuclear target foil fabrication for the Romano Event

    SciTech Connect (OSTI)

    Weed, J.W.; Romo, J.G. Jr.; Griggs, G.E.

    1984-06-19

    The Vacuum Processes Lab, of LLNL's M.E. Dept. - Material Fabrication Division, was requested to provide 250 coated Parylene target foils for a nuclear physics experiment titled the ROMANO Event. Due to the developmental nature of some of the fabrication procedures, approximately 400 coated foils were produced to satisfy the event's needs. The foils were used in the experiment as subkilovolt x-ray, narrow band pass filters, and wide band ultraviolet filters. This paper is divided into three sections describing: (1) nuclear target foil fabrication, (2) Parylene substrate preparation and production, and (3) foil and substrate inspections.

  9. Fabrication Routes for High Strength High Conductivity Wires

    SciTech Connect (OSTI)

    Han, K.; Embury, J.D.; Sims, J.R.; Pantsyrnyi, V.I.; Shikov, A.; Bochvar, A.A.

    1998-10-01

    The development of suitable wires for magnet windings requires both the attainment of suitable combinations of properties (electrical conductivity and strength), the development of a production route capable of fabricating suitable quantity of wire of required dimension (5.2x7.6mm{sup 2} cross-section and 120 m in length) and a product with acceptable fabricability, joinability and service life. In this survey, the authors consider methods of producing suitable wire products by the codeformation of in-situ composites. This will include details of the quality control of the processing of Cu-Ag and Cu-Nb and the assessment of their detailed mechanical properties.

  10. Near-Net Shape Fabrication Using Low-Cost Titanium Alloy Powders

    SciTech Connect (OSTI)

    Dr. David M. Bowden; Dr. William H. Peter

    2012-03-31

    The use of titanium in commercial aircraft production has risen steadily over the last half century. The aerospace industry currently accounts for 58% of the domestic titanium market. The Kroll process, which has been used for over 50 years to produce titanium metal from its mineral form, consumes large quantities of energy. And, methods used to convert the titanium sponge output of the Kroll process into useful mill products also require significant energy resources. These traditional approaches result in product forms that are very expensive, have long lead times of up to a year or more, and require costly operations to fabricate finished parts. Given the increasing role of titanium in commercial aircraft, new titanium technologies are needed to create a more sustainable manufacturing strategy that consumes less energy, requires less material, and significantly reduces material and fabrication costs. A number of emerging processes are under development which could lead to a breakthrough in extraction technology. Several of these processes produce titanium alloy powder as a product. The availability of low-cost titanium powders may in turn enable a more efficient approach to the manufacture of titanium components using powder metallurgical processing. The objective of this project was to define energy-efficient strategies for manufacturing large-scale titanium structures using these low-cost powders as the starting material. Strategies include approaches to powder consolidation to achieve fully dense mill products, and joining technologies such as friction and laser welding to combine those mill products into near net shape (NNS) preforms for machining. The near net shape approach reduces material and machining requirements providing for improved affordability of titanium structures. Energy and cost modeling was used to define those approaches that offer the largest energy savings together with the economic benefits needed to drive implementation. Technical

  11. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  12. Metal-organic frameworks with exceptionally large pore aperatures

    DOE Patents [OSTI]

    Yaghi, Omar M.; Furukawa, Hiroyasu; Deng, Hexiang

    2015-07-14

    The disclosure relates to metal organic frameworks or isoreticular metal organic frameworks, methods of production thereof, and methods of use thereof.

  13. Large-area metallic photonic lattices for military applications.

    SciTech Connect (OSTI)

    Luk, Ting Shan

    2007-11-01

    In this project we developed photonic crystal modeling capability and fabrication technology that is scaleable to large area. An intelligent optimization code was developed to find the optimal structure for the desired spectral response. In terms of fabrication, an exhaustive survey of fabrication techniques that would meet the large area requirement was reduced to Deep X-ray Lithography (DXRL) and nano-imprint. Using DXRL, we fabricated a gold logpile photonic crystal in the <100> plane. For the nano-imprint technique, we fabricated a cubic array of gold squares. These two examples also represent two classes of metallic photonic crystal topologies, the connected network and cermet arrangement.

  14. Degenerate doping of metallic anodes

    SciTech Connect (OSTI)

    Friesen, Cody A; Zeller, Robert A; Johnson, Paul B; Switzer, Elise E

    2015-05-12

    Embodiments of the invention relate to an electrochemical cell comprising: (i) a fuel electrode comprising a metal fuel, (ii) a positive electrode, (iii) an ionically conductive medium, and (iv) a dopant; the electrodes being operable in a discharge mode wherein the metal fuel is oxidized at the fuel electrode and the dopant increases the conductivity of the metal fuel oxidation product. In an embodiment, the oxidation product comprises an oxide of the metal fuel which is doped degenerately. In an embodiment, the positive electrode is an air electrode that absorbs gaseous oxygen, wherein during discharge mode, oxygen is reduced at the air electrode. Embodiments of the invention also relate to methods of producing an electrode comprising a metal and a doped metal oxidation product.

  15. Silicon micro-mold and method for fabrication

    DOE Patents [OSTI]

    Morales, Alfredo M.

    2005-01-11

    The present invention describes a method for rapidly fabricating a robust 3-dimensional silicon micro-mold for use in preparing complex metal micro-components. The process begins by depositing a conductive metal layer onto one surface of a silicon wafer. A thin photoresist and a standard lithographic mask are then used to transfer a trace image pattern onto the opposite surface of the wafer by exposing and developing the resist. The exposed portion of the silicon substrate is anisotropically etched through the wafer thickness down to conductive metal layer to provide an etched pattern consisting of a series of rectilinear channels and recesses in the silicon which serve as the silicon micro-mold. Microcomponents are prepared with this mold by first filling the mold channels and recesses with a metal deposit, typically by electroplating, and then removing the silicon micro-mold by chemical etching.

  16. High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions

    SciTech Connect (OSTI)

    G Zhou; L Barrio; S Agnoli; S Senanayake; J Evans; A Kubacka; M Estrella; J Hanson; A Martinez-Arias; et al.

    2011-12-31

    The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.

  17. Biaxial Creep Specimen Fabrication

    SciTech Connect (OSTI)

    JL Bump; RF Luther

    2006-02-09

    This report documents the results of the weld development and abbreviated weld qualification efforts performed by Pacific Northwest National Laboratory (PNNL) for refractory metal and superalloy biaxial creep specimens. Biaxial creep specimens were to be assembled, electron beam welded, laser-seal welded, and pressurized at PNNL for both in-pile (JOYO reactor, O-arai, Japan) and out-of-pile creep testing. The objective of this test campaign was to evaluate the creep behavior of primary cladding and structural alloys under consideration for the Prometheus space reactor. PNNL successfully developed electron beam weld parameters for six of these materials prior to the termination of the Naval Reactors program effort to deliver a space reactor for Project Prometheus. These materials were FS-85, ASTAR-811C, T-111, Alloy 617, Haynes 230, and Nirnonic PE16. Early termination of the NR space program precluded the development of laser welding parameters for post-pressurization seal weldments.

  18. METAL PHTHALOCYANINES

    DOE Patents [OSTI]

    Frigerio, N.A.

    1962-03-27

    A process is given for preparing heavy metal phthalocyanines, sulfonated or not. The process comprises mixing an inorganic metal salt with dimethyl formamide or methyl sulfoxide; separating the metal complex formed from the solution; mixing the complex with an equimolar amount of sodium, potassium, lithium, magnesium, or beryllium sulfonated or unsulfonated phthalocyanine whereby heavy-metal phthalocyanine crystals are formed; and separating the crystals from the solution. Uranyl, thorium, lead, hafnium, and lanthanide rare earth phthalocyanines can be produced by the process. (AEC)

  19. Fabrication of Emissible Metallic Layer-by-Layer Photonic Crystals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    polymer is coated on the first polymer. A substrate or a multi-layer polymer structure is placed on the filled mold and the resulting structure is exposed to UV light (i.e., is UV...

  20. Fabrication of Emissible Metallic Layer-by-Layer Photonic Crystals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lighting technologies, such as compact fluorescent bulbs or light-emitting diodes (LEDs) have gained increasing interest with energy security becoming an important national...

  1. Spray casting of metallic preforms

    DOE Patents [OSTI]

    Flinn, John E.; Burch, Joseph V.; Sears, James W.

    2000-01-01

    A metal alloy is melted in a crucible and ejected from the bottom of the crucible as a descending stream of molten metal. The descending stream is impacted with a plurality of primary inert gas jets surrounding the molten metal stream to produce a plume of atomized molten metal droplets. An inert gas is blown onto a lower portion of the plume with a plurality of auxiliary inert gas jets to deflect the plume into a more restricted pattern of high droplet density, thereby substantially eliminating unwanted overspray and resulting wasted material. The plume is projected onto a moving substrate to form a monolithic metallic product having generally parallel sides.

  2. Chemical Fabrication of Heterometallic Nanogaps for Molecular Transport Junctions

    SciTech Connect (OSTI)

    Chen, Xiaodong; Yeganeh, Sina; Qin, Lidong; Li, Shuzhou; Xue, Can; Braunschweig, Adam B.; Schatz, George C.; Ratner, Mark A.; Mirkin, Chad A.

    2009-01-01

    We report a simple and reproducible method for fabricating heterometallic nanogaps, which are made of two different metal nanorods separated by a nanometer-sized gap. The method is based upon on-wire lithography, which is a chemically enabled technique used to synthesize a wide variety of nanowire-based structures (e.g., nanogaps and disk arrays). This method can be used to fabricate pairs of metallic electrodes, which exhibit distinct work functions and are separated by gaps as small as 2 nm. Furthermore, we demonstrate that a symmetric thiol-terminated molecule can be assembled into such heterometallic nanogaps to form molecular transport junctions (MTJs) that exhibit molecular diode behavior. Theoretical calculations demonstrate that the coupling strength between gold and sulfur (Au-S) is 2.5 times stronger than that of Pt-S. In addition, the structures form Raman hot spots in the gap, allowing the spectroscopic characterization of the molecules that make up the MTJs.

  3. Method for fabricating transistors using crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, A.M.

    1997-09-02

    A method for fabricating transistors using single-crystal silicon devices on glass. This method overcomes the potential damage that may be caused to the device during high voltage bonding and employs a metal layer which may be incorporated as part of the transistor. This is accomplished such that when the bonding of the silicon wafer or substrate to the glass substrate is performed, the voltage and current pass through areas where transistors will not be fabricated. After removal of the silicon substrate, further metal may be deposited to form electrical contact or add functionality to the devices. By this method both single and gate-all-around devices may be formed. 13 figs.

  4. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2006-12-05

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  5. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  6. Fabrication of catalyzed ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis; Kibby, Charles Leonard

    2013-06-04

    Process for fabricating a catalyzed ion transport membrane (ITM). In one embodiment, an uncatalyzed ITM is (a) contacted with a non-reducing gaseous stream while heating to a temperature and for a time period sufficient to provide an ITM possessing anion mobility; (b) contacted with a reducing gaseous stream for a time period sufficient to provide an ITM having anion mobility and essentially constant oxygen stoichiometry; (c) cooled while contacting the ITM with the reducing gaseous stream to provide an ITM having essentially constant oxygen stoichiometry and no anion mobility; and (d) treated by applying catalyst to at least one of (1) a porous mixed conducting multicomponent metallic oxide (MCMO) layer contiguous with a first side of a dense layer of MCMO and (2) a second side of the dense MCMO layer. In another embodiment, these steps are carried out in the alternative order of (a), (d), (b), and (c).

  7. Fabrication methods for low impedance lithium polymer electrodes

    DOE Patents [OSTI]

    Chern, T.S.; MacFadden, K.O.; Johnson, S.L.

    1997-12-16

    A process is described for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.

  8. Fabrication methods for low impedance lithium polymer electrodes

    DOE Patents [OSTI]

    Chern, Terry Song-Hsing; MacFadden, Kenneth Orville; Johnson, Steven Lloyd

    1997-01-01

    A process for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.

  9. Novel Fabrication and Simple Hybridization of Exotic Material MEMS

    SciTech Connect (OSTI)

    Datskos, P.G.; Rajic, S.

    1999-11-13

    Work in materials other than silicon for MEMS applications has typically been restricted to metals and metal oxides instead of more ''exotic'' semiconductors. However, group III-V and II-VI semiconductors form a very important and versatile collection of material and electronic parameters available to the MEMS and MOEMS designer. With these materials, not only are the traditional mechanical material variables (thermal conductivity, thermal expansion, Young's modulus, etc.) available, but also chemical constituents can be varied in ternary and quaternary materials. This flexibility can be extremely important for both friction and chemical compatibility issues for MEMS. In addition, the ability to continually vary the bandgap energy can be particularly useful for many electronics and infrared detection applications. However, there are two major obstacles associated with alternate semiconductor material MEMS. The first issue is the actual fabrication of non-silicon devices and the second impediment is communicating with these novel devices. We will describe an essentially material independent fabrication method that is amenable to most group III-V and II-VI semiconductors. This technique uses a combination of non-traditional direct write precision fabrication processes such as diamond turning, ion milling, laser ablation, etc. This type of deterministic fabrication approach lends itself to an almost trivial assembly process. We will also describe in detail the mechanical, electrical, and optical self-aligning hybridization technique used for these alternate-material MEMS.

  10. Methods for fabricating a micro heat barrier

    DOE Patents [OSTI]

    Marshall, Albert C.; Kravitz, Stanley H.; Tigges, Chris P.; Vawter, Gregory A.

    2004-01-06

    Methods for fabricating a highly effective, micron-scale micro heat barrier structure and process for manufacturing a micro heat barrier based on semiconductor and/or MEMS fabrication techniques. The micro heat barrier has an array of non-metallic, freestanding microsupports with a height less than 100 microns, attached to a substrate. An infrared reflective membrane (e.g., 1 micron gold) can be supported by the array of microsupports to provide radiation shielding. The micro heat barrier can be evacuated to eliminate gas phase heat conduction and convection. Semi-isotropic, reactive ion plasma etching can be used to create a microspike having a cusp-like shape with a sharp, pointed tip (<0.1 micron), to minimize the tip's contact area. A heat source can be placed directly on the microspikes. The micro heat barrier can have an apparent thermal conductivity in the range of 10.sup.-6 to 10.sup.-7 W/m-K. Multiple layers of reflective membranes can be used to increase thermal resistance.

  11. Energy Systems Fabrication Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Energy Systems Fabrication Laboratory at the Energy Systems Integration Facility. The Energy Systems Fabrication Laboratory at NREL's Energy Systems Integration Facility (ESIF) manufactures components for fuel cells and electrochemical cells using a variety of manufacturing techniques. Fabricated components include catalysts, thin-film and gas diffusion electrodes, and membrane electrode assemblies (MEAs). The laboratory supports NREL's fuel cell and electrochemical cell related research. The main focus of the laboratory is to provide support for fuel cell research that is performed in adjacent laboratories. The laboratory enables NREL to manufacture fuel cells in-house using, for example, experimental catalyst developed at NREL. It further enables the creation of MEAs containing artificial defects required for the systematic study of performance and lifetime effects and the evaluation of in-house and externally developed quality control diagnostics for high volume production of fuel cell. Experiments performed in the laboratory focus mainly on the development of alternative fuel cell manufacturing methods.

  12. LIFE Target Fabrication Research Plan Sept 2008

    SciTech Connect (OSTI)

    Miles, R; Biener, J; Kucheyev, S; Montesanti, R; Satcher, J; Spadaccini, C; Rose, K; Wang, M; Hamza, A; Alexander, N; Brown, L; Hund, J; Petzoldt, R; Sweet, W; Goodin, D

    2008-11-10

    The target-system for the baseline LIFE fast-ignition target was analyzed to establish a preliminary estimate for the costs and complexities involved in demonstrating the technologies needed to build a prototype LIFE plant. The baseline fast-ignition target upon which this analysis was developed is shown in Figure 1.0-1 below. The LIFE target-system incorporates requirements for low-cost, high throughput manufacture, high-speed, high accuracy injection of the target into the chamber, production of sufficient energy from implosion and recovery and recycle of the imploded target material residue. None of these functions has been demonstrated to date. Existing target fabrication techniques which lead to current 'hot spot' target costs of {approx}$100,000 per target and at a production rate of 2/day are unacceptable for the LIFE program. Fabrication techniques normally used for low-cost, low accuracy consumer products such as toys must be adapted to the high-accuracy LIFE target. This will be challenge. A research program resulting is the demonstration of the target-cycle technologies needed for a prototype LIFE reactor is expected to cost {approx}$51M over the course of 5 years. The effort will result in targets which will cost an estimated $0.23/target at a rep-rate of 20 Hz or about 1.73M targets/day.

  13. JLab SRF Cavity Fabrication Errors, Consequences and Lessons Learned

    SciTech Connect (OSTI)

    Frank Marhauser

    2011-09-01

    Today, elliptical superconducting RF (SRF) cavities are preferably made from deep-drawn niobium sheets as pursued at Jefferson Laboratory (JLab). The fabrication of a cavity incorporates various cavity cell machining, trimming and electron beam welding (EBW) steps as well as surface chemistry that add to forming errors creating geometrical deviations of the cavity shape from its design. An analysis of in-house built cavities over the last years revealed significant errors in cavity production. Past fabrication flaws are described and lessons learned applied successfully to the most recent in-house series production of multi-cell cavities.

  14. Planarization of metal films for multilevel interconnects

    DOE Patents [OSTI]

    Tuckerman, David B.

    1987-01-01

    In the fabrication of multilevel integrated circuits, each metal layer is anarized by heating to momentarily melt the layer. The layer is melted by sweeping laser pulses of suitable width, typically about 1 microsecond duration, over the layer in small increments. The planarization of each metal layer eliminates irregular and discontinuous conditions between successive layers. The planarization method is particularly applicable to circuits having ground or power planes and allows for multilevel interconnects. Dielectric layers can also be planarized to produce a fully planar multilevel interconnect structure. The method is useful for the fabrication of VLSI circuits, particularly for wafer-scale integration.

  15. Planarization of metal films for multilevel interconnects

    DOE Patents [OSTI]

    Tuckerman, D.B.

    1989-03-21

    In the fabrication of multilevel integrated circuits, each metal layer is planarized by heating to momentarily melt the layer. The layer is melted by sweeping laser pulses of suitable width, typically about 1 microsecond duration, over the layer in small increments. The planarization of each metal layer eliminates irregular and discontinuous conditions between successive layers. The planarization method is particularly applicable to circuits having ground or power planes and allows for multilevel interconnects. Dielectric layers can also be planarized to produce a fully planar multilevel interconnect structure. The method is useful for the fabrication of VLSI circuits, particularly for wafer-scale integration. 6 figs.

  16. Planarization of metal films for multilevel interconnects

    DOE Patents [OSTI]

    Tuckerman, D.B.

    1985-06-24

    In the fabrication of multilevel integrated circuits, each metal layer is planarized by heating to momentarily melt the layer. The layer is melted by sweeping lase pulses of suitable width, typically about 1 microsecond duration, over the layer in small increments. The planarization of each metal layer eliminates irregular and discontinuous conditions between successive layers. The planarization method is particularly applicable to circuits having ground or power planes and allows for multilevel interconnects. Dielectric layers can also be planarized to produce a fully planar multilevel interconnect structure. The method is useful for the fabrication of VLSI circuits, particularly for wafer-scale integration.

  17. Planarization of metal films for multilevel interconnects

    DOE Patents [OSTI]

    Tuckerman, David B.

    1989-01-01

    In the fabrication of multilevel integrated circuits, each metal layer is anarized by heating to momentarily melt the layer. The layer is melted by sweeping laser pulses of suitable width, typically about 1 microsecond duration, over the layer in small increments. The planarization of each metal layer eliminates irregular and discontinuous conditions between successive layers. The planarization method is particularly applicable to circuits having ground or power planes and allows for multilevel interconnects. Dielectric layers can also be planarized to produce a fully planar multilevel interconnect structure. The method is useful for the fabrication of VLSI circuits, particularly for wafer-scale integration.

  18. Planarization of metal films for multilevel interconnects

    DOE Patents [OSTI]

    Tuckerman, D.B.

    1985-08-23

    In the fabrication of multilevel integrated circuits, each metal layer is planarized by heating to momentarily melt the layer. The layer is melted by sweeping laser pulses of suitable width, typically about 1 microsecond duration, over the layer in small increments. The planarization of each metal layer eliminates irregular and discontinuous conditions between successive layers. The planarization method is particularly applicable to circuits having ground or power planes and allows for multilevel interconnects. Dielectric layers can also be planarized to produce a fully planar multilevel interconnect structure. The method is useful for the fabrication of VLSI circuits, particularly for wafer-scale integration.

  19. Electrolytic systems and methods for making metal halides and refining metals

    SciTech Connect (OSTI)

    Holland, Justin M.; Cecala, David M.

    2015-05-26

    Disclosed are electrochemical cells and methods for producing a halide of a non-alkali metal and for electrorefining the halide. The systems typically involve an electrochemical cell having a cathode structure configured for dissolving a hydrogen halide that forms the halide into a molten salt of the halogen and an alkali metal. Typically a direct current voltage is applied across the cathode and an anode that is fabricated with the non-alkali metal such that the halide of the non-alkali metal is formed adjacent the anode. Electrorefining cells and methods involve applying a direct current voltage across the anode where the halide of the non-alkali metal is formed and the cathode where the non-alkali metal is electro-deposited. In a representative embodiment the halogen is chlorine, the alkali metal is lithium and the non-alkali metal is uranium.

  20. Enforcement Letter, Parsons Technology Development & Fabrication...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Development & Fabrication Complex - April 13, 2010 Enforcement Letter, Parsons Technology Development & Fabrication Complex - April 13, 2010 April 13, 2010 Issued to...

  1. Synthesis and processing of composites by reactive metal penetration

    SciTech Connect (OSTI)

    Loehman, R.E.; Ewsuk, K.G.; Tomsia, A.P.

    1997-04-01

    Achieving better performance in commercial products and processes often is dependent on availability of new and improved materials. Ceramic-metal composites have advantages over more conventional materials because of their high stiffness-to-weight ratios, good fracture toughness, and because their electrical and thermal properties can be varied through control of their compositions and microstructures. However, ceramic composites will be more widely used only when their costs are competitive with other materials and when designers have more confidence in their reliability. Over the past four years reactive metal penetration has been shown to be a promising technique for making ceramic and metal-matrix composites to near-net-shape with control of both composition and microstructure. It appears that, with sufficient development, reactive metal penetration could be an economical process for manufacturing many of the advanced ceramic composites that are needed for light-weight structural and wear applications for transportation and energy conversion devices. Near-net-shape fabrication of parts is a significant advantage because costly and energy intensive grinding and machining operations are substantially reduced, and the waste generated from such finishing operations is minimized. The most promising compositions to date consist of Al and Al{sub 2}O{sub 3}; thus, these composites should be of particular interest to the aluminum industry. The goals of this ceramic-metal composite research and development program are: (1) to identify compositions favorable for making composites by reactive metal penetration; (2) to understand the mechanism(s) by which these composites are formed; (3) to control and optimize the process so that composites and composite coatings can be made economically; and (4) to apply R&D results to problems of interest to the aluminum industry.

  2. Production plant separator system conceptual design

    SciTech Connect (OSTI)

    Ng, E.; Kan, T.

    1994-12-31

    A full conceptual design has been completed for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant capable of producing {approximately}1700 metric tons of enriched uranium per year (MTU/y). This plant is the first step in the deployment of AVLIS enrichment technology, which will provide inexpensive, dependable, and environmentally safe uranium enrichment services to utility customers. Previous issues of the ISAM Semiannual Report describe other major systems in the plant, namely the laser, feed and product systems. This article describes the design of the separator system. The separator system is a a key component in the plant. After the feed conversion system converts uranium trioxide (UO{sub 3}) to a uranium-iron alloy, the alloy enters the separator system. In the separator, and intense electron beam vaporizes uranium metal in a vacuum chamber. In the laser system, fixed-frequency copper-vapor lasers pump tunable dye lasers. These precisely tuned dye lasers then selectively excite and ionize uranium-235 atoms in the vapor stream, leaving the uranium-238 atoms untouched. The photo-ions of uranium-235 are then drawn to an electrically biased collector, producing the enriched product stream. The remaining vapor flows through, producing the depleted tails stream. Both product and tails streams are continuously removed from the separator pod as flowing liquid uranium metal. Withdrawal containers are used to collect separately the enriched and depleted uranium. The enriched product will be converted by fuel fabricators to uranium dioxide (UO{sub 2}) and used to fabricate reactor fuel assemblies for utility customers.

  3. Epsilon Metal Waste Form for Immobilization of Noble Metals from Used Nuclear Fuel

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Strachan, Denis M.; Rohatgi, Aashish; Zumhoff, Mac R.

    2013-10-01

    Epsilon metal (?-metal), an alloy of Mo, Pd, Rh, Ru, and Tc, is being developed as a waste form to treat and immobilize the undissolved solids and dissolved noble metals from aqueous reprocessing of commercial used nuclear fuel. Epsilon metal is an attractive waste form for several reasons: increased durability relative to borosilicate glass, it can be fabricated without additives (100% waste loading), and in addition it also benefits borosilicate glass waste loading by eliminating noble metals from the glass and thus the processing problems related there insolubility in glass. This work focused on the processing aspects of the epsilon metal waste form development. Epsilon metal is comprised of refractory metals resulting in high reaction temperatures to form the alloy, expected to be 1500 - 2000C making it a non-trivial phase to fabricate by traditional methods. Three commercially available advanced technologies were identified: spark-plasma sintering, microwave sintering, and hot isostatic pressing, and investigated as potential methods to fabricate this waste form. Results of these investigations are reported and compared in terms of bulk density, phase assemblage (X-ray diffraction and elemental analysis), and microstructure (scanning electron microscopy).

  4. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst

    SciTech Connect (OSTI)

    McGuiggan, M.F.; Kuch, P.L.

    1984-05-08

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

  5. Preliminary safety assessment for an IFE target fabrication facility

    SciTech Connect (OSTI)

    Latkowski, J F; Reyes, S; Besenbruch, G E; Goodin, D T

    2000-10-13

    We estimate possible ranges of tritium inventories for an inertial fusion energy (IFE) target fabrication facility producing various types of targets and using various production technologies. Target fill is the key subtask in determining the overall tritium inventory for the plant. By segmenting the inventory into multiple, parallel production lines--each with its own fill canister--and including an expansion tank to limit releases, we are able to ensure that a target fabrication facility would meet the accident dose goals of 10 mSv (1 rem) set forth in the Department of Energy's Fusion Safety Standards. For indirect-drive targets, we calculate release fractions for elements from lithium to bismuth and show that nearly all elements meet the dose goal. Our work suggests directions for future R&D that will help reduce total tritium inventories and increase the flexibility of target fabrication facilities.

  6. Methods for batch fabrication of cold cathode vacuum switch tubes

    DOE Patents [OSTI]

    Walker, Charles A.; Trowbridge, Frank R.

    2011-05-10

    Methods are disclosed for batch fabrication of vacuum switch tubes that reduce manufacturing costs and improve tube to tube uniformity. The disclosed methods comprise creating a stacked assembly of layers containing a plurality of adjacently spaced switch tube sub-assemblies aligned and registered through common layers. The layers include trigger electrode layer, cathode layer including a metallic support/contact with graphite cathode inserts, trigger probe sub-assembly layer, ceramic (e.g. tube body) insulator layer, and metallic anode sub-assembly layer. Braze alloy layers are incorporated into the stacked assembly of layers, and can include active metal braze alloys or direct braze alloys, to eliminate costs associated with traditional metallization of the ceramic insulator layers. The entire stacked assembly is then heated to braze/join/bond the stack-up into a cohesive body, after which individual switch tubes are singulated by methods such as sawing. The inventive methods provide for simultaneously fabricating a plurality of devices as opposed to traditional methods that rely on skilled craftsman to essentially hand build individual devices.

  7. Nanostructured metal foams: synthesis and applications

    SciTech Connect (OSTI)

    Luther, Erik P; Tappan, Bryce; Mueller, Alex; Mihaila, Bogdan; Volz, Heather; Cardenas, Andreas; Papin, Pallas; Veauthier, Jackie; Stan, Marius

    2009-01-01

    Fabrication of monolithic metallic nanoporous materials is difficult using conventional methodology. Here they report a relatively simple method of synthesizing monolithic, ultralow density, nanostructured metal foams utilizing self-propagating combustion synthesis of novel metal complexes containing high nitrogen energetic ligands. Nanostructured metal foams are formed in a post flame-front dynamic assembly with densities as low as 0.011 g/cc and surface areas as high as 270 m{sup 2}/g. They have produced metal foams via this method of titanium, iron, cobalt, nickel, zirconium, copper, palladium, silver, hafnium, platinum and gold. Microstructural features vary as a function of composition and process parameters. Applications for the metal foams are discussed including hydrogen absorption in palladium foams. A model for the sorption kinetics of hydrogen in the foams is presented.

  8. Northern States Metals Company | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Northern States Metals Company Address: 3207 Innovation Place Place: Youngstown, Ohio Zip: 44509 Sector: Solar Product: Manufacturing Phone...

  9. Nitrided Metallic Bipolar Plates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Nitrided Metallic Bipolar Plates Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2008 Update High ...

  10. Nitrided Metallic Bipolar Plates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Nitrided Metallic Bipolar Plates Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2010 Update Mass ...

  11. Microsystem product development.

    SciTech Connect (OSTI)

    Polosky, Marc A.; Garcia, Ernest J.

    2006-04-01

    Over the last decade the successful design and fabrication of complex MEMS (MicroElectroMechanical Systems), optical circuits and ASICs have been demonstrated. Packaging and integration processes have lagged behind MEMS research but are rapidly maturing. As packaging processes evolve, a new challenge presents itself, microsystem product development. Product development entails the maturation of the design and all the processes needed to successfully produce a product. Elements such as tooling design, fixtures, gages, testers, inspection, work instructions, process planning, etc., are often overlooked as MEMS engineers concentrate on design, fabrication and packaging processes. Thorough, up-front planning of product development efforts is crucial to the success of any project.

  12. Reduction of Metal Oxide to Metal using Ionic Liquids

    SciTech Connect (OSTI)

    Dr. Ramana Reddy

    2012-04-12

    A novel pathway for the high efficiency production of metal from metal oxide means of electrolysis in ionic liquids at low temperature was investigated. The main emphasis was to eliminate the use of carbon and high temperature application in the reduction of metal oxides to metals. The emphasis of this research was to produce metals such as Zn, and Pb that are normally produced by the application of very high temperatures. The reduction of zinc oxide to zinc and lead oxide to lead were investigated. This study involved three steps in accomplishing the final goal of reduction of metal oxide to metal using ionic liquids: 1) Dissolution of metal oxide in an ionic liquid, 2) Determination of reduction potential using cyclic voltammetry (CV) and 3) Reduction of the dissolved metal oxide. Ionic liquids provide additional advantage by offering a wide potential range for the deposition. In each and every step of the process, more than one process variable has been examined. Experimental results for electrochemical extraction of Zn from ZnO and Pb from PbO using eutectic mixtures of Urea ((NH2)2CO) and Choline chloride (HOC2H4N(CH3)3+Cl-) or (ChCl) in a molar ratio 2:1, varying voltage and temperatures were carried out. Fourier Transform Infra-Red (FTIR) spectroscopy studies of ionic liquids with and without metal oxide additions were conducted. FTIR and induction coupled plasma spectroscopy (ICPS) was used in the characterization of the metal oxide dissolved ionic liquid. Electrochemical experiments were conducted using EG&G potentiostat/galvanostat with three electrode cell systems. Cyclic voltammetry was used in the determination of reduction potentials for the deposition of metals. Chronoamperometric experiments were carried out in the potential range of -0.6V to -1.9V for lead and -1.4V to -1.9V for zinc. The deposits were characterized using XRD and SEM-EDS for phase, morphological and elemental analysis. The results showed that pure metal was deposited on the cathode

  13. Joined ceramic product

    DOE Patents [OSTI]

    Henager, Jr., Charles W [Kennewick, WA; Brimhall, John L. (West Richland, WA) [West Richland, WA

    2001-08-21

    According to the present invention, a joined product is at least two ceramic parts, specifically bi-element carbide parts with a bond joint therebetween, wherein the bond joint has a metal silicon phase. The bi-element carbide refers to compounds of MC, M.sub.2 C, M.sub.4 C and combinations thereof, where M is a first element and C is carbon. The metal silicon phase may be a metal silicon carbide ternary phase, or a metal silicide.

  14. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan F.; Yu, Conrad

    2006-10-17

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  15. CONTROL ROD ALLOY CONTAINING NOBLE METAL ADDITIONS

    DOE Patents [OSTI]

    Anderson, W.K.; Ray, W.E.

    1960-05-01

    Silver-base alloys suitable for use in the fabrication of control rods for neutronic reactors are given. The alloy consists of from 0.5 wt.% to about 1.5 wt.% of a noble metal of platinum, ruthenium, rhodium, osmium, or palladium, up to 10 wt.% of cadmium, from 2 to 20 wt.% indium, the balance being silver.

  16. Metal hydride fuel storage and method thereof

    DOE Patents [OSTI]

    Morse, Jeffrey D [Martinez, CA; Jankowski, Alan F [Livermore, CA; Yu, Conrad [Antioch, CA

    2009-05-05

    Disclosed herein is a metal hydride fuel storage cartridge having integrated resistive heaters that can be used in conjunction with fuel cells such as MEMS-based fuel cells. The cartridge is fabricated using micromachining methods and thin/thick film materials synthesis techniques.

  17. Deterministic, Nanoscale Fabrication of Mesoscale Objects

    SciTech Connect (OSTI)

    Jr., R M; Shirk, M; Gilmer, G; Rubenchik, A

    2004-09-24

    Neither LLNL nor any other organization has the capability to perform deterministic fabrication of mm-sized objects with arbitrary, {micro}m-sized, 3-dimensional features with 20-nm-scale accuracy and smoothness. This is particularly true for materials such as high explosives and low-density aerogels. For deterministic fabrication of high energy-density physics (HEDP) targets, it will be necessary both to fabricate features in a wide variety of materials as well as to understand and simulate the fabrication process. We continue to investigate, both in experiment and in modeling, the ablation/surface-modification processes that occur with the use of laser pulses that are near the ablation threshold fluence. During the first two years, we studied ablation of metals, and we used sub-ps laser pulses, because pulses shorter than the electron-phonon relaxation time offered the most precise control of the energy that can be deposited into a metal surface. The use of sub-ps laser pulses also allowed a decoupling of the energy-deposition process from the ensuing movement/ablation of the atoms from the solid, which simplified the modeling. We investigated the ablation of material from copper, gold, and nickel substrates. We combined the power of the 1-D hydrocode ''HYADES'' with the state-of-the-art, 3-D molecular dynamics simulations ''MDCASK'' in our studies. For FY04, we have stretched ourselves to investigate laser ablation of carbon, including chemically-assisted processes. We undertook this research, because the energy deposition that is required to perform direct sublimation of carbon is much higher than that to stimulate the reaction 2C + O{sub 2} => 2CO. Thus, extremely fragile carbon aerogels might survive the chemically-assisted process more readily than ablation via direct laser sublimation. We had planned to start by studying vitreous carbon and move onto carbon aerogels. We were able to obtain flat, high-quality vitreous carbon, which was easy to work on

  18. Nonwoven fabrics made from nickel and stainless steel fibers

    SciTech Connect (OSTI)

    Stepro, J.A.

    1996-11-01

    Nonwoven fabrics made from metal fiber have uses in a variety of applications due to their alloy composition, heat resistivity, conductivity and durability. Applications include: filtration media, battery current collectors, EMI/RFI shielding, insulation and conductive fillers. The ability to form metal fibers into fabrics of non-directionalized fiber webs has led to improved materials in a variety of applications. The non-orientation of the fibers provides a three dimensional structure that is filled with materials such as nickel hydroxide, cadmium oxide and MH alloy used for battery applications or to act as a contaminate trap for filtration. Fibers made from nickel, stainless steel, iron, cobalt, monel and copper are all possibilities for use in nonwoven fabrics. The density, porosity and thickness are all controllable during the web formation process. Fiber diameter is also a critical consideration when specific pore sizes are targeted. Fiber diameters are controlled during the fiber formation process. Diameters as low as 6 microns in stainless steel and 9 microns in other alloys are possible.

  19. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  20. Metallic Fuel Casting Development and Parameter Optimization Simulations

    SciTech Connect (OSTI)

    R.S. Fielding; J. Crapps; C. Unal; J.R. Kennedy

    2013-03-01

    One of the advantages of metallic fuel is the abilility to cast the fuel slugs to near net shape with little additional processing. However, the high aspect ratio of the fuel is not ideal for casting. EBR-II fuel was cast using counter gravity injection casting (CGIC) but, concerns have been raised concerning the feasibility of this process for americium bearing alloys. The Fuel Cycle Research and Development program has begun developing gravity casting techniques suitable for fuel production. Compared to CGIC gravity casting does not require a large heel that then is recycled, does not require application of a vacuum during melting, and is conducive to re-usable molds. Development has included fabrication of two separate benchscale, approximately 300 grams, systems. To shorten development time computer simulations have been used to ensure mold and crucible designs are feasible and to identify which fluid properties most affect casting behavior and therefore require more characterization.

  1. Supported molten-metal catalysts

    DOE Patents [OSTI]

    Datta, Ravindra; Singh, Ajeet; Halasz, Istvan; Serban, Manuela

    2001-01-01

    An entirely new class of catalysts called supported molten-metal catalysts, SMMC, which can replace some of the existing precious metal catalysts used in the production of fuels, commodity chemicals, and fine chemicals, as well as in combating pollution. SMMC are based on supporting ultra-thin films or micro-droplets of the relatively low-melting (<600.degree. C.), inexpensive, and abundant metals and semimetals from groups 1, 12, 13, 14, 15 and 16, of the periodic table, or their alloys and intermetallic compounds, on porous refractory supports, much like supported microcrystallites of the traditional solid metal catalysts. It thus provides orders of magnitude higher surface area than is obtainable in conventional reactors containing molten metals in pool form and also avoids corrosion. These have so far been the chief stumbling blocks in the application of molten metal catalysts.

  2. Effects of Dopant Metal Variation and Material Synthesis Method...

    Office of Scientific and Technical Information (OSTI)

    in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production Citation ... in Yttria Stabilized Zirconia for Solar Thermochemical Fuel Production Mixed metal ...

  3. Selective niobium anodization process for fabricating Josephson tunnel junctions

    SciTech Connect (OSTI)

    Kroger, H.; Smith, L.N.; Jillie, D.W.

    1981-08-01

    A novel process for fabricating refractory sperconducting tunnel junctions is described, which is useful with both deposited and native oxide barriers. The distinguishing feature of the method is that the entire superconductor-barrier-superconductor sandwich is formed before the patterning of any layer. Isolated Josephson junctions are then formed by anodizing through the upper electrode, while the devices themselves are protected by a photoresist mask. Using this process, Nb-Si:H-Nb junctions have been fabricated, whose product of critical current and subgap resistance exceeds 10 mV and whose critical current density varies by about 50% over a 2-in. diameter wafer.

  4. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a multi-metal oxide/sulfide catalyst

    SciTech Connect (OSTI)

    Jevnikar, M. G.; Kuch, Ph. L.

    1985-02-19

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a catalytic composition containing an oxide and/or sulfide of at least one of molybdenum, tungsten, iron, chromium and vanadium in combination with at least one promoter metal, e.g. a catalyst of the formula Cs Cu /SUB 0.2/ Zn /SUB 0.5/ Mn /SUB 0.5/ Sn /SUB 2.4/ Mo O /SUB x/ S /SUB y/ .

  5. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quarterly report, December 30, 1996--March 30, 1997

    SciTech Connect (OSTI)

    1997-12-31

    The objective of this project is to utilize coal ashes to process hazardous materials such as industrial waste water treatment residues, contaminated soils, and air pollution control dusts from the metal industry and municipal waste incineration. This report describes the activities of the project team during the reporting period. The principal work has focused upon continuing evaluation of aged samples from Phase 1, planning supportive laboratory studies for Phase 2, completing scholarly work, reestablishing MAX Environmental Technologies, Inc., as the subcontractor for the field work of Phase 2, proposing two presentations for later in 1997, and making and responding to several outside contacts.

  6. Metals 2000

    SciTech Connect (OSTI)

    Allison, S.W.; Rogers, L.C.; Slaughter, G.; Boensch, F.D.; Claus, R.O.; de Vries, M.

    1993-05-01

    This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

  7. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Hydrides Theodore Motyka Savannah River National Laboratory Metal Hydride System Architect Jose-Miguel Pasini, & Bart van Hassel UTRC Claudio Corgnale & Bruce Hardy SRNL Kevin Simmons and Mark Weimar PNNL Darsh Kumar GM, Matthew Thornton NREL, Kevin Drost OSU DOE Materials-Based Hydrogen Storage Summit Defining Pathways for Onboard Automotive Applications 2 Outline * Background and MH History * MH HSECoE Results * Material Operating Requirements * Modeling and Analyses * BOP and

  8. Thin, porous metal sheets and methods for making the same

    SciTech Connect (OSTI)

    Liu, Wei; Li, Xiaohong Shari; Canfield, Nathan L.

    2015-07-14

    Thin, porous metal sheets and methods for forming them are presented to enable a variety of applications and devices. The thin, porous metal sheets are less than or equal to approximately 200 .mu.m thick, have a porosity between 25% and 75% by volume, and have pores with an average diameter less than or equal to approximately 2 .mu.m. The thin, porous metal sheets can be fabricated by preparing a slurry having between 10 and 50 wt % solvent and between 20 and 80 wt % powder of a metal precursor. The average particle size in the metal precursor powder should be between 100 nm and 5 .mu.m.

  9. Process for fabricating composite material having high thermal conductivity

    DOE Patents [OSTI]

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    2001-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  10. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R.

    1990-01-01

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used.

  11. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, R.R.

    1990-11-20

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used. 5 figs.

  12. Intermetallic alloy welding wires and method for fabricating the same

    DOE Patents [OSTI]

    Santella, Michael L.; Sikka, Vinod K.

    1996-01-01

    Welding wires for welding together intermetallic alloys of nickel aluminides, nickel-iron aluminides, iron aluminides, or titanium aluminides, and preferably including additional alloying constituents are fabricated as two-component, clad structures in which one component contains the primary alloying constituent(s) except for aluminum and the other component contains the aluminum constituent. This two-component approach for fabricating the welding wire overcomes the difficulties associated with mechanically forming welding wires from intermetallic alloys which possess high strength and limited ductilities at elevated temperatures normally employed in conventional metal working processes. The composition of the clad welding wires is readily tailored so that the welding wire composition when melted will form an alloy defined by the weld deposit which substantially corresponds to the composition of the intermetallic alloy being joined.

  13. Intermetallic alloy welding wires and method for fabricating the same

    DOE Patents [OSTI]

    Santella, M.L.; Sikka, V.K.

    1996-06-11

    Welding wires for welding together intermetallic alloys of nickel aluminides, nickel-iron aluminides, iron aluminides, or titanium aluminides, and preferably including additional alloying constituents are fabricated as two-component, clad structures in which one component contains the primary alloying constituent(s) except for aluminum and the other component contains the aluminum constituent. This two-component approach for fabricating the welding wire overcomes the difficulties associated with mechanically forming welding wires from intermetallic alloys which possess high strength and limited ductilities at elevated temperatures normally employed in conventional metal working processes. The composition of the clad welding wires is readily tailored so that the welding wire composition when melted will form an alloy defined by the weld deposit which substantially corresponds to the composition of the intermetallic alloy being joined. 4 figs.

  14. Laser target fabrication, structure and method for its fabrication

    DOE Patents [OSTI]

    Farnum, Eugene H.; Fries, R. Jay

    1985-01-01

    The disclosure is directed to a laser target structure and its method of fabrication. The target structure comprises a target plate containing an orifice across which a pair of crosshairs are affixed. A microsphere is affixed to the crosshairs and enclosed by at least one hollow shell comprising two hemispheres attached together and to the crosshairs so that the microsphere is juxtapositioned at the center of the shell.

  15. Inverter-based GTA welding machines improve fabrication

    SciTech Connect (OSTI)

    Sammons, M.

    2000-05-01

    While known as precision process, many fabricators using the gas tungsten arc welding (GTAW) process fight several common problems that hinder quality, slow production, frustrate the operator and otherwise prevent the process from achieving its full potential. These include a limited ability to tailor the weld bead profile, poor control of the arc direction and arc wandering, poor arc starting, unstable or inconsistent arcs in the AC mode, high-frequency interference with electronics and tungsten contamination. Fortunately, new GTA welding technology--made possible by advances with inverter-based power sources and micro-processor controls--can eliminate common productivity gremlins. Further, new AC/DC inverter-based GTA power sources provide advanced arc shaping capabilities. As a result, many fabricators adopting this new technology have experienced phenomenal production increases, taken on new types of projects and reduced costs. Most importantly, the operators enjoy welding more.

  16. Processing of Refractory Metal Alloys for JOYO Irradiations

    SciTech Connect (OSTI)

    RF Luther; ME Petrichek

    2006-02-21

    This is a summary of the refractory metal processing experienced by candidate Prometheus materiats as they were fabricated into specimens destined for testing within the JOYO test reactor, ex-reactor testing at Oak Ridge National Laboratory (ORNL), or testing within the NRPCT. The processing is described for each alloy from the point of inception to the point where processing was terminated due to the cancellation of Naval Reactor's involvement in the Prometheus Project. The alloys included three tantalum-base alloys (T-111, Ta-10W, and ASTAR-811C), a niobium-base alloy, (FS-85), and two molybdenum-rhenium alloys, one containing 44.5 w/o rhenium, and the other 47.5 w/o rhenium. Each of these alloys was either a primary candidate or back-up candidate for cladding and structural applications within the space reactor. Their production was intended to serve as a forerunner for large scale production ingots that were to be procured from commercial refractory metal vendors such as Wah Chang.

  17. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A.; Song, Yujiang; Pereira, Eulalia F.; Medforth, Craig J.

    2010-08-31

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  18. Inertial Confinement Fusion Target Component Fabrication and Technology Development Support

    SciTech Connect (OSTI)

    Steinman, D.

    1993-03-01

    On December 31, 1990, the US Department of Energy entered into a contract with General Atomics (GA) to be the Inertial Confinement Fusion (ICF) Target Component Fabrication and Technology Development Support contractor. This report documents the technical activities of the period January 1, 1991 through September 30, 1992. During this period, GA was assigned 15 tasks in support of the Inertial Confinement Fusion program and its laboratories. These tasks included Facilities Activation, Staff Development, and Capabilities Validation to establish facilities and equipment, and demonstrate capability to perform ICF target fabrication research, development and production activities. The capabilities developed and demonstrated are those needed for fabrication and precise characterization of polymer shells and polymer coatings. We made progress toward production capability for glass shells, barrier layer coatings, and gas idling of shells. We fabricated over 1000 beam diagnostic foil targets for Sandia National Laboratory Albuquerque and provided full-time on-site engineering support for target fabrication and characterization. We initiated development of methods to fabricate polymer shells by a controlled mass microencapsulation technique, and performed chemical syntheses of several chlorine- and silicon-doped polymer materials for the University of Rochester's Laboratory for Laser Energetics (UR/LLE). We performed the conceptual design of a cryogenic target handling system for UR/LLE that will fill, transport, layer, and characterize targets filled with cryogenic deuterium or deuterium-tritium fuel, and insert these cryogenic targets into the OMEGA-Upgrade target chamber for laser implosion experiments. This report summarizes and documents the technical progress made on these tasks.

  19. LAMPF transition-region mechanical fabrication

    SciTech Connect (OSTI)

    Bush, E.D. Jr.; Gallegos, J.D.F.; Harrison, R.; Hart, V.E.; Hunter, W.T.; Rislove, S.E.; Sims, J.R.; Van Dyke, W.J.

    1984-07-01

    The primary purpose of the new Transition Region (TR-II) is to optimize the phase matching of the H/sup +/ and H/sup -/ beams during simultaneous transport. TR-II incorporates several design improvements that include larger aperture, a straight beam track, greater beam-path length adjustments, and utility lines integrated with the support system. The close pack density of magnets and beam-line hardware required innovative solutions to magnet design and mounting, vacuum manifolding, and utility routing. Critical magnet placement was accomplished using a new three-dimensional alignment system that does real-time vector calculations on a computer with input from two digital theodolites. All assembly and a large fraction of the mechanical fabrication were done by LAMPF personnel. The TR-II has been operational since September 1983 and routinely transports production beams up to 900-..mu..A current with no major problems.

  20. Method of fabricating a honeycomb structure

    DOE Patents [OSTI]

    Holleran, Louis M.; Lipp, G. Daniel

    1999-01-01

    A method of fabricating a monolithic honeycomb structure product involves shaping a first mixture of raw materials and a binder into a green honeycomb, extruding a second mixture of raw materials and a binder into one or more green members that each define an opening extending longitudinally therethrough. The raw materials of the second mixture are compatible with the raw materials of the first mixture. The green honeycomb and member(s) are dried. The binders of the green honeycomb and member(s) are softened at the surfaces that are to be bonded. The green member(s) is inserted into the honeycomb and bonded to the honeycomb to form an assembly thereof, which is then dried and fired to form a unified monolithic honeycomb structure. The insertion is best carried out by mounting a member in the shape of a tube on a mandrel, and inserting the mandrel into the honeycomb opening to bond the tube to the honeycomb.

  1. Method of fabricating a honeycomb structure

    DOE Patents [OSTI]

    Holleran, L.M.; Lipp, G.D.

    1999-08-03

    A method of fabricating a monolithic honeycomb structure product involves shaping a first mixture of raw materials and a binder into a green honeycomb, extruding a second mixture of raw materials and a binder into one or more green members that each define an opening extending longitudinally therethrough. The raw materials of the second mixture are compatible with the raw materials of the first mixture. The green honeycomb and member(s) are dried. The binders of the green honeycomb and member(s) are softened at the surfaces that are to be bonded. The green member(s) is inserted into the honeycomb and bonded to the honeycomb to form an assembly thereof, which is then dried and fired to form a unified monolithic honeycomb structure. The insertion is best carried out by mounting a member in the shape of a tube on a mandrel, and inserting the mandrel into the honeycomb opening to bond the tube to the honeycomb. 7 figs.

  2. Method of fabricating silicon carbide coatings on graphite surfaces

    DOE Patents [OSTI]

    Varacalle, D.J. Jr.; Herman, H.; Burchell, T.D.

    1994-07-26

    The vacuum plasma spray process produces well-bonded, dense, stress-free coatings for a variety of materials on a wide range of substrates. The process is used in many industries to provide for the excellent wear, corrosion resistance, and high temperature behavior of the fabricated coatings. In this application, silicon metal is deposited on graphite. This invention discloses the optimum processing parameters for as-sprayed coating qualities. The method also discloses the effect of thermal cycling on silicon samples in an inert helium atmosphere at about 1,600 C which transforms the coating to silicon carbide. 3 figs.

  3. Method of fabricating silicon carbide coatings on graphite surfaces

    DOE Patents [OSTI]

    Varacalle, Jr., Dominic J.; Herman, Herbert; Burchell, Timothy D.

    1994-01-01

    The vacuum plasma spray process produces well-bonded, dense, stress-free coatings for a variety of materials on a wide range of substrates. The process is used in many industries to provide for the excellent wear, corrosion resistance, and high temperature behavior of the fabricated coatings. In this application, silicon metal is deposited on graphite. This invention discloses the optimum processing parameters for as-sprayed coating qualities. The method also discloses the effect of thermal cycling on silicon samples in an inert helium atmosphere at about 1600.degree.C. which transforms the coating to silicon carbide.

  4. I-NERI ANNUAL TECHNICAL PROGRESS REPORT: 2006-002-K, Separation of Fission Products from Molten LiCl-KCl Salt Used for Electrorefining of Metal Fuels

    SciTech Connect (OSTI)

    S. Frank

    2009-09-01

    An attractive alternative to the once-through disposal of electrorefiner salt is to selectively remove the active fission products from the salt and recycle the salt back to the electrorefiner (ER). This would allow salt reuse for some number of cycles before ultimate disposal of the salt in a ceramic waste form. Reuse of ER salt would, thus, greatly reduce the volume of ceramic waste produced during the pyroprocessing of spent nuclear fuel. This final portion of the joint I-NERI research project is to demonstrate the separation of fission products from molten ER salt by two methods previously selected during phase two (FY-08) of this project. The two methods selected were salt/zeolite contacting and rare-earth fission product precipitation by oxygen bubbling. The ER salt used in these tests came from the Mark-IV electrorefiner used to anodically dissolved driver fuel from the EBR-II reactor on the INL site. The tests were performed using the Hot Fuel Dissolution Apparatus (HFDA) located in the main cell of the Hot Fuels Examination Facility (HFEF) at the Materials and Fuels complex on the INL site. Results from these tests were evaluated during a joint meeting of KAERI and INL investigators to provide recommendations as to the future direction of fission product removal from electrorefiner salt that accumulate during spent fuel treatment. Additionally, work continued on kinetic measurements of surrogate quaternary salt systems to provide fundamental kinetics on the ion exchange system and to expand the equilibrium model system developed during the first two phases of this project. The specific objectives of the FY09 I-NERI research activities at the INL include the following: Perform demonstration tests of the selected KAERI precipitation and INL salt/zeolite contacting processes for fission product removal using radioactive, fission product loaded ER salt Continue kinetic studies of the quaternary Cs/Sr-LiCl-KCl system to determine the rate of ion exchange

  5. Fabrication of Uranium Oxycarbide Kernels for HTR Fuel

    SciTech Connect (OSTI)

    Charles Barnes; CLay Richardson; Scott Nagley; John Hunn; Eric Shaber

    2010-10-01

    Babcock and Wilcox (B&W) has been producing high quality uranium oxycarbide (UCO) kernels for Advanced Gas Reactor (AGR) fuel tests at the Idaho National Laboratory. In 2005, 350-µm, 19.7% 235U-enriched UCO kernels were produced for the AGR-1 test fuel. Following coating of these kernels and forming the coated-particles into compacts, this fuel was irradiated in the Advanced Test Reactor (ATR) from December 2006 until November 2009. B&W produced 425-µm, 14% enriched UCO kernels in 2008, and these kernels were used to produce fuel for the AGR-2 experiment that was inserted in ATR in 2010. B&W also produced 500-µm, 9.6% enriched UO2 kernels for the AGR-2 experiments. Kernels of the same size and enrichment as AGR-1 were also produced for the AGR-3/4 experiment. In addition to fabricating enriched UCO and UO2 kernels, B&W has produced more than 100 kg of natural uranium UCO kernels which are being used in coating development tests. Successive lots of kernels have demonstrated consistent high quality and also allowed for fabrication process improvements. Improvements in kernel forming were made subsequent to AGR-1 kernel production. Following fabrication of AGR-2 kernels, incremental increases in sintering furnace charge size have been demonstrated. Recently small scale sintering tests using a small development furnace equipped with a residual gas analyzer (RGA) has increased understanding of how kernel sintering parameters affect sintered kernel properties. The steps taken to increase throughput and process knowledge have reduced kernel production costs. Studies have been performed of additional modifications toward the goal of increasing capacity of the current fabrication line to use for production of first core fuel for the Next Generation Nuclear Plant (NGNP) and providing a basis for the design of a full scale fuel fabrication facility.

  6. Metal hydrides

    SciTech Connect (OSTI)

    Carnes, J.R.; Kherani, N.P.

    1987-11-01

    Metal hydride information is not available for most hydrides in a consolidated quick-reference source. This report's objective is to fill the need for such a document providing basic thermodynamic data for as many metal hydrides as possible. We conduced a computerized library search to access as many sources as possible and screened each source for such thermodynamic data as pressure-temperature graphs, van't Hoff curves, and impurity effects. We included any other relevant information and commented on it. A primary concern to be investigated in the future is the behavior of metal tritides. This would be important in the area of emergency tritium cleanup systems. The hydride graphs are useful, however, as tritides may be expected in most cases to behave similarly and at least follow trends of their respective hydrides. 42 refs., 40 figs., 5 tabs.

  7. Mixed ligand chelate therapy for plutonium and toxic metals from energy power production. Final report, April 15, 1977-October 14, 1980. [Mice

    SciTech Connect (OSTI)

    Schubert, J.

    1980-10-14

    The results of experiments are summarized on the ability of combinations of chelating agents to modify the genotoxicity or tissue distributions. The mutagenicities of Cr and of chelating agents were determined. The metals described in the report are Pu(IV), Cd(II), Cr(III), and Cr(VI). Accurate measurements were made of the ability of CaNa/sub 2/EDTA, CaNa/sub 3/DTPA, and DMPS to reduce mortality in mice given doses (i.p.) of CdCl/sub 2/ well above the 100% lethal level. The efficacy in terms of the mmoles/kg needed to reduce the mortality was: DTPA > EDTA > DMPS. The combination of DTPA + DMPS proved most promising though little evidence for mixed complex formation was noted. Potentiometric titration studies the case of Pu(IV) a few combinations proved effective, but only when given shortly after Pu administration and then only in the liver but not the skeleton. It is recommended that metabolically stable chelating agents be used in combinations, especially for those combinations which may form very stable mixed ligand chelates.

  8. Displacement method and apparatus for reducing passivated metal powders and metal oxides

    SciTech Connect (OSTI)

    Morrell; Jonathan S. , Ripley; Edward B.

    2009-05-05

    A method of reducing target metal oxides and passivated metals to their metallic state. A reduction reaction is used, often combined with a flux agent to enhance separation of the reaction products. Thermal energy in the form of conventional furnace, infrared, or microwave heating may be applied in combination with the reduction reaction.

  9. Crashworthiness Assessment of Auto-body Members Considering the Fabrication Histories

    SciTech Connect (OSTI)

    Huh, Hoon; Song, Jung-Han; Kim, Kee-Poong; Kim, Hyun-Sub

    2005-08-05

    This paper is concerned with crashworthiness of auto-body members considering the effect of fabrication. Most auto-body members are fabricated with sheet metal forming process and welding process that induce fabrication histories such as the plastic work hardening, non-uniform thickness distribution and residual stress. Crash simulation is carried out for auto-body members with LS-DYNA3D in order to identify the fabrication effect on the crashworthiness. The analysis calculated crash mode, the reaction force and the energy absorption for crashworthiness assessment with the forming effect. The result shows that the crash analysis with considering the forming history leads to a different result from that without considering the forming effect. The analysis results demonstrate that the design of auto-body members should be carried out considering the forming history for accurate assessment of the crashworthiness.

  10. metals Fischer, S.H.; Grubelich, M.C. 37 INORGANIC, ORGANIC,...

    Office of Scientific and Technical Information (OSTI)

    IGNITION; MIXTURES; PRODUCTION; REACTION HEAT; SPECIFIC HEAT; STABILITY Thermite (metal oxide) mixtures, intermetallic reactants, and metal fuels have long been used in...

  11. Safe disposal of metal values in slag

    SciTech Connect (OSTI)

    Halpin, P.T.; Zarur, G.L.

    1982-10-26

    The method of safely disposing of sludge containing metal values capable of displaying toxic ecological properties includes the steps of deriving from an organic or inorganic sludge an intermediate product such as a dewatered sludge or an incinerated ash, and adding this intermediate product to a metal smelting step of a type producing a slag such that most of the metal values become encapsulated in the slag. Some precious metal values may be recovered with the metal being smelted, and may be subsequently separated therefrom by appropriate metal winning steps. The sludge product brings to the smelting process certain additives needed therein such as silica and phosphates for the slag, alumina and magnesium to lower the viscosity of the molten slag, and organic matter serving as reducing agents.

  12. Titanium metal: extraction to application

    SciTech Connect (OSTI)

    Gambogi, Joseph; Gerdemann, Stephen J.

    2002-09-01

    In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

  13. Damascene fabrication of nonplanar microcoils

    DOE Patents [OSTI]

    Adams, David P.; Vasile, Michael J.

    2003-06-17

    A process for fabricating coils using a Damascene process uses a curved substrate having a surface extending along and about an axis made of a first material. A groove is formed in the curved surface along and around said axis, and the groove is filled with a second material that is different from the first material to form a coil of second material in said first material. Excess second material is then removed from the surface of the first material, leaving the coil of second material in the groove.

  14. New Metallization Technique Suitable for 6-MW Pilot Production of Efficient Multicrystalline Solar Cells Using Upgraded Metallurgical Silicon: Final Technical Progress Report, December 17, 2007-- June 16, 2009

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report describes CaliSolar's work as a Photovoltaic Technology Incubator awardee within the U.S. Department of Energy's Solar Energy Technologies Program. The term of this subcontract with the National Renewable Energy Laboratory was two years. During this time, CaliSolar evolved from a handful of employees to over 100 scientists, engineers, technicians, and operators. On the technical side, the company transitioned from a proof-of-concept through pilot-scale to large-scale industrial production. A fully automated 60-megawatt manufacturing line was commissioned in Sunnyvale, California. The facility converts upgraded metallurgical-grade silicon feedstock to ingots, wafers, and high-efficiency multicrystalline solar cells.

  15. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M.; Dye, Robert C.; Snow, Ronny C.; Birdsell, Stephan A.

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  16. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  17. Felt-metal-wick heat-pipe solar receiver

    SciTech Connect (OSTI)

    Andraka, C.E.; Adkins, D.R.; Moss, T.A.; Cole, H.M.; Andreas, N.H.

    1994-12-31

    Reflux heat-pipe receivers have been identified as a desirable interface to couple a Stirling-cycle engine with a parabolic dish solar concentrator. The reflux receiver provides power nearly isothermally to the engine heater heads while decoupling the heater head design from the solar absorber surface design. The independent design of the receiver and engine heater head leads to higher system efficiency. Heat pipe reflux receivers have been demonstrated at approximately 65 kW{sub t} power throughput. Several 25 to 30-kW{sub e} Stirling-cycle engines are under development, and will soon be incorporated in commercial dish-Stirling systems. These engines will require reflux receivers with power throughput limits reaching 90-kW{sub t}. The extension of heat pipe technology from 60 kW{sub t} to 100 kW{sub t} is not trivial. Current heat pipe wick technology is pushed to its limits. It is necessary to develop and test advanced wick structure technologies to perform this task. Sandia has developed and begun testing a Bekaert Corporation felt metal wick structure fabricated by Porous Metal Products Inc. This wick is about 95% porous, and has liquid permeability a factor of 2 to 8 times higher than conventional technologies for a given maximum pore radius. The wick has been successfully demonstrated in a bench-scale heat pipe, and a full-scale on-sun receiver has been fabricated. This report details the wick design, characterization and installation into a heat pipe receiver, and the results of the bench-scale tests are presented. The wick performance is modeled, and the model results are compared to test results.

  18. Commercial Implementation of Model-Based Manufacturing of Nanostructured Metals

    SciTech Connect (OSTI)

    Lowe, Terry C.

    2012-07-24

    Computational modeling is an essential tool for commercial production of nanostructured metals. Strength is limited by imperfections at the high strength levels that are achievable in nanostructured metals. Processing to achieve homogeneity at the micro- and nano-scales is critical. Manufacturing of nanostructured metals is intrinsically a multi-scale problem. Manufacturing of nanostructured metal products requires computer control, monitoring and modeling. Large scale manufacturing of bulk nanostructured metals by Severe Plastic Deformation is a multi-scale problem. Computational modeling at all scales is essential. Multiple scales of modeling must be integrated to predict and control nanostructural, microstructural, macrostructural product characteristics and production processes.

  19. Experiences in Large Grain-Single Crystal Cavity Fabrication

    SciTech Connect (OSTI)

    Pekeler, Michael; Schwellenbach, Johannes; Tradt, Marco

    2007-08-09

    At ACCEL instruments several single cell and 9-cell cavities have been produced out of large grain niobium sheets from different suppliers. The fabrication experience and difference to the production out of fine grain niobium sheets will be described. In addition two cavities were produced using single crystal niobium sheets. The final cavities showed no grain boundaries at all in the cavity cell, even not in the electron beam welding seam.

  20. Kaizen Innovative Products Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Innovative Products Pvt Ltd Jump to: navigation, search Name: Kaizen Innovative Products Pvt. Ltd Place: Mumbai, Maharashtra, India Sector: Solar Product: Mumbai-based metal sheet...

  1. Direct electrochemical reduction of metal-oxides

    DOE Patents [OSTI]

    Redey, Laszlo I.; Gourishankar, Karthick

    2003-01-01

    A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

  2. Highly reproducible and reliable metal/graphene contact by ultraviolet-ozone treatment

    SciTech Connect (OSTI)

    Li, Wei [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China); Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Hacker, Christina A.; Cheng, Guangjun; Hight Walker, A. R.; Richter, Curt A.; Gundlach, David J., E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn [Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Liang, Yiran; Tian, Boyuan; Liang, Xuelei, E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn; Peng, Lianmao [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China)

    2014-03-21

    Resist residue from the device fabrication process is a significant source of contamination at the metal/graphene contact interface. Ultraviolet Ozone (UVO) treatment is proven here, by X-ray photoelectron spectroscopy and Raman measurement, to be an effective way of cleaning the metal/graphene interface. Electrical measurements of devices that were fabricated by using UVO treatment of the metal/graphene contact region show that stable and reproducible low resistance metal/graphene contacts are obtained and the electrical properties of the graphene channel remain unaffected.

  3. Flexible transparent conductors based on metal nanowire networks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Chuan Fei; Ren, Zhifeng

    2015-04-01

    Few conductors are transparent and flexible. Metals have the best electrical conductivity, but they are opaque and stiff in bulk form. However, metals can be transparent and flexible when they are very thin or properly arranged on the nanoscale. This review focuses on the flexible transparent conductors based on percolating networks of metal. Specifically, we discuss the fabrication, the means to improve the electrical conductivity, the large stretchability and its mechanism, and the applications of these metal networks. We also suggest some criteria for evaluating flexible transparent conductors and propose some new research directions in this emerging field.

  4. Foil fabrication for the ROMANO event. Revision 1

    SciTech Connect (OSTI)

    Romo, J.G. Jr.; Weed, J.W.; Griggs, G.E.; Brown, T.G.; Tassano, P.L.

    1984-06-13

    The Vacuum Processes Lab (VPL), of LLNL's M.E. Dept. - Material Fabrication Division (MFD), conducted various vacuum related support activities for the ROMANO nuclear physics experiment. This report focuses on the foil fabrication activities carried out between July and November 1983 for the ROMANO event. Other vacuum related activities for ROMANO, such as outgassing tests of materials, are covered in separate documentation. VPL was asked to provide 270 coated Parylene foils for the ROMANO event. However, due to the developmental nature of some of the procedures, approximately 400 coated foils were processed. In addition, VPL interacted with MFD's Plastics Shop to help supply Parylene substrates to other organizations (i.e., LBL and commercial vendors) which had also been asked to provide coated foils for ROMANO. The purposes of this report are (A) to document the processes developed and the techniques used to produce the foils, and (B) to suggest future directions. The report is divided into four sections describing: (1) nuclear target foil fabrication, (2) Parylene substrate preparation and production, (3) calibration foil fabrication, and (4) foil and substrate inspections.

  5. Metal Matrix Microencapsulated (M3) fuel neutronics performance in PWRs

    SciTech Connect (OSTI)

    Fratoni, Massimiliano; Terrani, Kurt A

    2012-01-01

    Metal Matrix Microencapsulated (M3) fuel consists of TRISO or BISO coated fuel particles directly dispersed in a matrix of zirconium metal to form a solid rod (Fig. 1). In this integral fuel concept the cladding tube and the failure mechanisms associated with it have been eliminated. In this manner pellet-clad-interactions (PCI), thin tube failure due to oxidation and hydriding, and tube pressurization and burst will be absent. M3 fuel, given the high stiffness of the integral rod design, could as well improve grid-to-rod wear behavior. Overall M3 fuel, compared to existing fuel designs, is expected to provide greatly improved operational performance. Multiple barriers to fission product release (ceramic coating layers in the coated fuel particle and te metal matrix) and the high thermal conductivity zirconium alloy metal matrix contribute to the enhancement in fuel behavior. The discontinuous nature of fissile material encapsulated in coated particles provides additional assistance; for instance if the M3 fuel rod is snapped into multiple pieces, only the limited number of fuel particles at the failure cross section are susceptible to release fission products. This is in contrast to the conventional oxide fuel where the presence of a small opening in the cladding provides the pathway for release of the entire inventory of fission products from the fuel rod. While conventional metal fuels (e.g. U-Zr and U-Mo) are typically expected to experience large swelling under irradiation due to the high degree of damage from fission fragments and introduction of fission gas into the lattice, this is not the case for M3 fuels. The fissile portion of the fuel is contained within the coated particle where enough room is available to accommodate fission gases and kernel swelling. The zirconium metal matrix will not be exposed to fission products and its swelling is known to be very limited when exposed solely to neutrons. Under design basis RIA and LOCA, fuel performance will be

  6. Fusion welding of refractory metals

    SciTech Connect (OSTI)

    Robino, C.V.

    1991-01-01

    The refractory metals of Groups 5B and 6B and their alloys display a variety of unique physical and mechanical characteristics in addition to their high melting points. In turn, these characteristics make these materials strong candidates for severe service and specialized applications. However, these materials also present a variety of challenges with respect to both fabrication weldability and the in-service behavior of weldments, many of which are related to the dominant effects of interstitial impurities. This work reviews current understanding of the physical and joining metallurgy of these metals and their alloys with emphasis on fusion welding. Of specific interest are the role of impurities and alloy chemistry in fabrication and service weldability, the material processing route, eg. vacuum melting vs. powder metallurgy, the importance of welding process procedures and variables, weldment mechanical properties, and fracture behavior. Specific examples from the various alloy systems are used to illustrate general metallurgical and joining characteristics of this class of materials. 34 refs., 14 figs., 3 tabs.

  7. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

    2006-08-01

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

  8. WINCO Metal Recycle annual report, FY 1993

    SciTech Connect (OSTI)

    Bechtold, T.E.

    1993-12-01

    This report is a summary of the first year progress of the WINCO Metal Recycle Program. Efforts were directed towards assessment of radioactive scrap metal inventories, economics and concepts for recycling, technology development, and transfer of technology to the private sector. Seven DOE laboratories worked together to develop a means for characterizing scrap metal. Radioactive scrap metal generation rates were established for several of these laboratories. Initial cost estimates indicate that recycle may be preferable over burial if sufficient decontamination factors can be achieved during melt refining. Radiation levels of resulting ingots must be minimized in order to keep fabrication costs low. Industry has much of the expertise and capability to execute the recycling of radioactive scrap metal. While no single company can sort, melt, refine, roll and fabricate, a combination of two to three can complete this operation. The one process which requires development is in melt refining for removal of radionuclides other than uranium. WINCO is developing this capability in conjunction with academia and industry. This work will continue into FY-94.

  9. Silicon-nitride and metal composite

    DOE Patents [OSTI]

    Landingham, R.L.; Huffsmith, S.A.

    A composite and a method for bonding the composite are described. The composite includes a ceramic portion of silicon nitride, a refractory metal portion and a layer of MoSi/sub 2/ indirectly bonding the composite together. The method includes contacting the layer of MoSi/sub 2/ with a surface of the silicon nitride and with a surface of the metal; heating the layer to a temperature below 1400/sup 0/C; and, simultaneously, compressing the layer such that the contacting is with a pressure of at least 30 MPa. This composite overcomes useful life problems in the fabrication of parts for a helical expander for use in power generation.

  10. Silicon-nitride and metal composite

    DOE Patents [OSTI]

    Landingham, Richard L.; Huffsmith, Sarah A.

    1981-01-01

    A composite and a method for bonding the composite. The composite includes a ceramic portion of silicon nitride, a refractory metal portion and a layer of MoSi.sub.2 indirectly bonding the composite together. The method includes contacting the layer of MoSi.sub.2 with a surface of the silicon nitride and with a surface of the metal; heating the layer to a temperature below 1400.degree. C.; and, simultaneously with the heating, compressing the layer such that the contacting is with a pressure of at least 30 MPa. This composite overcomes useful life problems in the fabrication of parts for a helical expander for use in power generation.

  11. Cost-Effective Fabrication Routes for the Production of Quantum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quantum-Well-Type Structures and Recovoery of Waste Heat from Heavy-Duty Trucks Thermoelectric Developments for Vehicular Applications Automotive Thermoelectric Generators and HVAC

  12. Method of fabricating nested shells and resulting product

    DOE Patents [OSTI]

    Henderson, Timothy M. (Ann Arbor, MI); Kool, Lawrence B. (Ann Arbor, MI)

    1982-01-01

    A multiple shell structure and a method of manufacturing such structure wherein a hollow glass microsphere is surface treated in an organosilane solution so as to render the shell outer surface hydrophobic. The surface treated glass shell is then suspended in the oil phase of an oil-aqueous phase dispersion. The oil phase includes an organic film-forming monomer, a polymerization initiator and a blowing agent. A polymeric film forms at each phase boundary of the dispersion and is then expanded in a blowing operation so as to form an outer homogeneously integral monocellular substantially spherical thermoplastic shell encapsulating an inner glass shell of lesser diameter.

  13. Cell Fabrication Facility Team Production and Research Activities

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  14. Electronics Design and Fabrication | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronics Design and Fabrication Electronics Design and Fabrication The HEP Electronics Support Group provides electronics engineering, design, fabrication, and support services for a wide variety of research projects at the laboratory. Historically, the group has been part of the High Energy Physics (HEP) division, providing electronics support for HEP experiments around the world. Several years ago, we expanded our operations to provide electronics design and support services for the entire

  15. Sandia National Laboratories: Fabrication, Testing and Validation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capabilities Microsystems Science & Technology Center Rad-Hard and Trusted Systems Fabrication, Testing and Validation Capabilities RF & Photonics Quantum Systems Sensors MicroElectroMechanical Systems (MEMS) Power Electronics IPIMI Facebook Twitter YouTube Flickr RSS Microsystems Science & Technology Center Fabrication, Testing and Validation Capabilities Fabrication, Testing and Validation Capabilities The MESAFab complex develops and maintains core semiconductor processing

  16. CONTAINER MATERIALS, FABRICATION AND ROBUSTNESS

    SciTech Connect (OSTI)

    Dunn, K.; Louthan, M.; Rawls, G.; Sindelar, R.; Zapp, P.; Mcclard, J.

    2009-11-10

    The multi-barrier 3013 container used to package plutonium-bearing materials is robust and thereby highly resistant to identified degradation modes that might cause failure. The only viable degradation mechanisms identified by a panel of technical experts were pressurization within and corrosion of the containers. Evaluations of the container materials and the fabrication processes and resulting residual stresses suggest that the multi-layered containers will mitigate the potential for degradation of the outer container and prevent the release of the container contents to the environment. Additionally, the ongoing surveillance programs and laboratory studies should detect any incipient degradation of containers in the 3013 storage inventory before an outer container is compromised.

  17. Method for fabrication of electrodes

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.; Barksdale, Randy

    2004-06-22

    Described herein is a method to fabricate porous thin-film electrodes for fuel cells and fuel cell stacks. Furthermore, the method can be used for all fuel cell electrolyte materials which utilize a continuous electrolyte layer. An electrode layer is deposited on a porous host structure by flowing gas (for example, Argon) from the bottomside of the host structure while simultaneously depositing a conductive material onto the topside of the host structure. By controlling the gas flow rate through the pores, along with the process conditions and deposition rate of the thin-film electrode material, a film of a pre-determined thickness can be formed. Once the porous electrode is formed, a continuous electrolyte thin-film is deposited, followed by a second porous electrode to complete the fuel cell structure.

  18. Options for converting excess plutonium to feed for the MOX fuel fabrication facility

    SciTech Connect (OSTI)

    Watts, Joe A; Smith, Paul H; Psaras, John D; Jarvinen, Gordon D; Costa, David A; Joyce, Jr., Edward L

    2009-01-01

    The storage and safekeeping of excess plutonium in the United States represents a multibillion-dollar lifecycle cost to the taxpayers and poses challenges to National Security and Nuclear Non-Proliferation. Los Alamos National Laboratory is considering options for converting some portion of the 13 metric tons of excess plutonium that was previously destined for long-term waste disposition into feed for the MOX Fuel Fabrication Facility (MFFF). This approach could reduce storage costs and security ri sks, and produce fuel for nuclear energy at the same time. Over the course of 30 years of weapons related plutonium production, Los Alamos has developed a number of flow sheets aimed at separation and purification of plutonium. Flow sheets for converting metal to oxide and for removing chloride and fluoride from plutonium residues have been developed and withstood the test oftime. This presentation will address some potential options for utilizing processes and infrastructure developed by Defense Programs to transform a large variety of highly impure plutonium into feedstock for the MFFF.

  19. Fabrication and Characterization of Suspended Carbon Nanotube...

    Office of Scientific and Technical Information (OSTI)

    of Suspended Carbon Nanotube Devices in Liquid Citation Details In-Document Search Title: Fabrication and Characterization of Suspended Carbon Nanotube Devices in ...

  20. Fabricate-on-Demand Vacuum Insulating Glazings

    Broader source: Energy.gov [DOE]

    PPG is working to design a fabricate-on-demand process to overcome the cost and supply chain issues preventing widespread adoption of vacuum insulating glazings (VIGs).

  1. Improved Design of Optical MEMS Using the SUMMiT Fabrication Process

    SciTech Connect (OSTI)

    Michalicek, M.A.; Comtois, J.H.; Barron, C.C.

    1997-12-31

    This paper describes the design and fabrication of optical Microelectromechanical Systems (MEMS) devices using the Sandia Ultra planar Multilevel MEMS Technology (SUMMiT) fabrication process. This state of the art process, offered by Sandia National Laboratories, provides unique and very advantageous features which make it ideal for optical devices. This enabling process permits the development of micromirror devices with near ideal characteristics which have previously been unrealizable in standard polysilicon processes. This paper describes such characteristics as elevated address electrodes, individual address wiring beneath the device, planarized mirror surfaces, unique post-process metallization, and the best active surface area to date.

  2. Metal dusting

    SciTech Connect (OSTI)

    Edited by K. Natesan

    2004-01-01

    This workshop was held soon after the September 11th incident under a climate of sorrow and uncertainty among the people of the world, in particular the Workshop participants and their host organizations. With considerable help from the partiicpants, the Workshop was conducted as planed and we had excellent participation in spite of the circumstances. A good fraction of the attendees in the Workshop were from abroad and from several industries, indicating the importance and relevance of the subject for the chemical process industry. Degradation of structural metallic alloys by metal dusting has been an issue for over 40 years in the chemical, petrochemical, syngas, and iron ore reduction plants. However, the fundamental scientific reasons for the degradation of complex alloys in high carbon activity environments are not clear. one of the major parameters of importance is the variation in gas chemistry in both the laboratory experiments and in the plant-service environments. the industry has questioned the applicability of the laboratory test data, obtained in low steam environments, in assessment and life prediction for the materials in plant service where the environments contain 25-35% steam. Several other variables such as system pressure, gas flow velocity, incubation time, alloy chemistry, surface finish, and weldments, were also identified in the literature as to having an effect on the initiatino and propagation of metal dusting attack. It is the purpose of this Workshop to establish a forum in which the researchers from scientific and industrial laboratories, alloy manufacturers, end users, and research and development sponsors can exchange information, discuss different points of view, prioritize the issues, and to elaborate on the trends in industry for the future. We believe that we accomplished these goals successfully and sincerely thank the participants for their contributions.

  3. Precipitation of metal nitrides from chloride melts

    SciTech Connect (OSTI)

    Slater, S.A.; Miller, W.E.; Willit, J.L.

    1996-12-31

    Precipitation of actinides, lanthanides, and fission products as nitrides from molten chloride melts is being investigated for use as a final cleanup step in treating radioactive salt wastes generated by electrometallurgical processing of spent nuclear fuel. The radioactive components (eg, fission products) need to be removed to reduce the volume of high-level waste that requires disposal. To extract the fission products from the salt, a nitride precipitation process is being developed. The salt waste is first contacted with a molten metal; after equilibrium is reached, a nitride is added to the metal phase. The insoluble nitrides can be recovered and converted to a borosilicate glass after air oxidation. For a bench-scale experimental setup, a crucible was designed to contact the salt and metal phases. Solubility tests were performed with candidate nitrides and metal nitrides for which there are no solubility data. Experiments were performed to assess feasibility of precipitation of metal nitrides from chloride melts.

  4. Mechanochemical processing for metals and metal alloys

    DOE Patents [OSTI]

    Froes, Francis H.; Eranezhuth, Baburaj G.; Prisbrey, Keith

    2001-01-01

    A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

  5. FY-87 packing fabrication techniques (commercial waste form) results

    SciTech Connect (OSTI)

    Werry, E.V.; Gates, T.E.; Cabbage, K.S.; Eklund, J.D.

    1988-04-01

    This report covers the investigation of fabrication techniques associated with the development of suitable materials and methods to provide a prefabricated packing for waste packages for the Basalt Waste Isolation Project (BWIP). The principal functions of the packing are to minimize container corrosion during the 300 to 1000 years following repository closure and provide long-term control of the release of radionuclides from the waste package. The investigative work, discussed in this report, was specifically conceived to develop the design criteria for production of full-scale prototypical packing rings. The investigative work included the preparation of procedures, the preparation of fabrication materials, physical properties, and the determination of the engineering properties. The principal activities were the preparation of the materials and the determination of the physical properties. 21 refs., 20 figs., 14 tabs.

  6. DOE - Office of Legacy Management -- Nuclear Metals Inc - MA 09

    Office of Legacy Management (LM)

    Metals Inc - MA 09 FUSRAP Considered Sites Site: NUCLEAR METALS, INC. (MA.09) Eliminated from consideration under FUSRAP - Licensed facility - included in NRC action plan (Site Decommissioning Management Plan) in 1990 for cleanup Designated Name: Not Designated Alternate Name: None Location: 1555 Massachusetts Ave. , Cambridge , Massachusetts MA.09-2 Evaluation Year: 1987 MA.09-1 Site Operations: Produced natural uranium tubes for Savannah River reactor program and fabricated power reactor fuel

  7. Steel-SiC Metal Matrix Composite Development

    SciTech Connect (OSTI)

    Smith, Don D.

    2005-07-17

    The goal of this project is to develop a method for fabricating SiC-reinforced high-strength steel. We are developing a metal-matrix composite (MMC) in which SiC fibers are be embedded within a metal matrix of steel, with adequate interfacial bonding to deliver the full benefit of the tensile strength of the SiC fibers in the composite.

  8. In vitro dissolution of metal tritides

    SciTech Connect (OSTI)

    Cheng, Yung-Sung; Jow, Hong-Nian; Dahl, A.R.

    1994-11-01

    Metal tritides including titanium, zirconium, and erbium tritide have been used as components of neutron generators. These compounds can be released to the air as aerosols during fabrication, assembling, and testing of components or in accidental or fugitive releases, and as a result, workers may inhale them. Our understanding of metal tritides and their radiation dosimetry for internal exposure is very limited. Current radiation protection guidelines for metal tritide particles are based on the assumption that their biological behavior is similar to tritiated water which could be easily absorbed into body fluid, and, therefore, has a relatively short biological half-life (10 d). However, a few papers in the literature suggest that the solubility of metal tritide could be low. If this is true, the biological half-life of metal tritide particles and the dosimetry of inhalation exposure to these particles could be quite different from tritiated water, and this would have significant implications in the current health protection guidelines. The purpose of this study was to investigate the dissolution behavior of metal tritide particles in simulated biological fluids and in rats. Data from these studies will provide information with which to estimate the dosimetry of inhaled metal tritides. A dosimetric model can then be used as the technical basis for setting health protection limits, including annual limits on intake and derived air concentrations for DOE facilities.

  9. Apparatus and method for fabricating a microbattery

    DOE Patents [OSTI]

    Shul, Randy J.; Kravitz, Stanley H.; Christenson, Todd R.; Zipperian, Thomas E.; Ingersoll, David

    2002-01-01

    An apparatus and method for fabricating a microbattery that uses silicon as the structural component, packaging component, and semiconductor to reduce the weight, size, and cost of thin film battery technology is described. When combined with advanced semiconductor packaging techniques, such a silicon-based microbattery enables the fabrication of autonomous, highly functional, integrated microsystems having broad applicability.

  10. Fuel Fabrication Capability Research and Development Plan

    SciTech Connect (OSTI)

    Senor, David J.; Burkes, Douglas

    2013-06-28

    The purpose of this document is to provide a comprehensive review of the mission of the Fuel Fabrication Capability (FFC) within the Global Threat Reduction Initiative (GTRI) Convert Program, along with research and development (R&D) needs that have been identified as necessary to ensuring mission success. The design and fabrication of successful nuclear fuels must be closely linked endeavors.

  11. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  12. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides

  13. Fabrication of an optical component

    DOE Patents [OSTI]

    Nichols, Michael A.; Aikens, David M.; Camp, David W.; Thomas, Ian M.; Kiikka, Craig; Sheehan, Lynn M.; Kozlowski, Mark R.

    2000-01-01

    A method for forming optical parts used in laser optical systems such as high energy lasers, high average power lasers, semiconductor capital equipment and medical devices. The optical parts will not damage during the operation of high power lasers in the ultra-violet light range. A blank is first ground using a fixed abrasive grinding method to remove the subsurface damage formed during the fabrication of the blank. The next step grinds and polishes the edges and forms bevels to reduce the amount of fused-glass contaminants in the subsequent steps. A loose abrasive grind removes the subsurface damage formed during the fixed abrasive or "blanchard" removal process. After repolishing the bevels and performing an optional fluoride etch, the surface of the blank is polished using a zirconia slurry. Any subsurface damage formed during the loose abrasive grind will be removed during this zirconia polish. A post polish etch may be performed to remove any redeposited contaminants. Another method uses a ceria polishing step to remove the subsurface damage formed during the loose abrasive grind. However, any residual ceria may interfere with the optical properties of the finished part. Therefore, the ceria and other contaminants are removed by performing either a zirconia polish after the ceria polish or a post ceria polish etch.

  14. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  15. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  16. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed...

    Office of Scientific and Technical Information (OSTI)

    In the first mechanism, products of the fermentation process can act as chelators for metals and radionuclides increasing their transport through underlying geological media. The ...

  17. Process for the production of hydrogen from water

    DOE Patents [OSTI]

    Miller, William E.; Maroni, Victor A.; Willit, James L.

    2010-05-25

    A method and device for the production of hydrogen from water and electricity using an active metal alloy. The active metal alloy reacts with water producing hydrogen and a metal hydroxide. The metal hydroxide is consumed, restoring the active metal alloy, by applying a voltage between the active metal alloy and the metal hydroxide. As the process is sustainable, only water and electricity is required to sustain the reaction generating hydrogen.

  18. Composite Metal-hydrogen Electrodes for Metal-Hydrogen Batteries

    SciTech Connect (OSTI)

    Ruckman, M W; Wiesmann, H; Strongin, M; Young, K; Fetcenko, M

    1997-04-01

    The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries. The anodes could be incorporated in thin film solid state Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped metal-hydrogen ratios exceeding and fast hydrogen charging and Nb films, these studies suggested that materials with those of commercially available metal hydride materials discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films-and multiiayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 µm thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for

  19. Three-dimensional stacked structured ASIC devices and methods of fabrication thereof

    DOE Patents [OSTI]

    Shinde, Subhash L.; Teifel, John; Flores, Richard S.; Jarecki Jr., Robert L.; Bauer, Todd

    2015-11-19

    A 3D stacked sASIC is provided that includes a plurality of 2D reconfigurable structured structured ASIC (sASIC) levels interconnected through hard-wired arrays of 3D vias. The 2D sASIC levels may contain logic, memory, analog functions, and device input/output pad circuitry. During fabrication, these 2D sASIC levels are stacked on top of each other and fused together with 3D metal vias. Such 3D vias may be fabricated as through-silicon vias (TSVs). They may connect to the back-side of the 2D sASIC level, or they may be connected to top metal pads on the front-side of the 2D sASIC level.

  20. Method for fabricating hafnia films

    DOE Patents [OSTI]

    Hu, Michael Z [Knoxville, TN

    2007-08-21

    The present invention comprises a method for fabricating hafnia film comprising the steps of providing a substrate having a surface that allows formation of a self-assembled monolayer thereon via covalent bonding; providing an aqueous solution that provides homogeneous hafnium ionic complexes and hafnium nanoclusters wherein the aqueous solution is capable of undergoing homogeneous precipitation under controlled conditions for a desired period of time at a controlled temperature and controlled solution acidity for desired nanocluster nucleation and growth kinetics, desired nanocluster size, desired growth rate of film thickness and desired film surface characteristics. The method further comprising forming the self-assembled monolayer on the surface of the substrate wherein the self-assembled monolayer comprises a plurality of hydrocarbon chains cross-linked together along the surface of the substrate, the hydrocarbon chains being uniformly spaced from one another and wherein each of the hydrocarbon chains having a functional anchoring group at a first end of the chain covalently bonded with the surface of the substrate and each of the hydrocarbon chains having a functional terminating group projected away from the surface wherein the functional terminating group provides a bonding site for the hafnium film to grow; and exposing the substrate to the aqueous solution for a desired period of time at a controlled temperature wherein the hafnium ionic complexes and the hafnium nanoclusters are deposited on the bonding site of the functional terminating group thereby forming the hafnia film wherein the hafnium bonded to the hydrocarbons and to one another provide a uniform ordered arrangement defined by the uniform arrangement of the hydrocarbons.

  1. Guidelines for waste reduction and recycling: Metal finishing, electroplating, printed circuit board manufacturing

    SciTech Connect (OSTI)

    Not Available

    1989-07-01

    The guidance manual describes waste reduction techniques for metal finishing, metal fabricating, electroplating, and printed circuitboard manufacturing operations. Techniques which can be applied to a wide range of industrial processes and those which are process-specific are discussed. Evaporation, reverse osmosis, ion exchange, electrodialysis, ultrafiltration, and electrolytic recovery are described. The manual also describes waste reduction assessment procedures.

  2. Mechanical properties of vapor-deposited thin metallic films: a status report

    SciTech Connect (OSTI)

    Adler, P.H.

    1982-12-17

    The mechanical properties of vapor-deposited thin metallic films are being studied in conjunction with the target fabrication group associated with the laser-fusion energy program. The purpose of the work is to gain an understanding as to which metals are structurally best suited to contain a glass microsphere filled with deuterium-tritium (D-T) gas at large internal pressures.

  3. Metallic Membrane Materials Development for Hydrogen Production...

    Office of Scientific and Technical Information (OSTI)

    Derived Syngas The goals of Office of Clean Coal are: (1) Improved energy security; (2) Reduced green house gas emissions; (3) High tech job creation; and (4) Reduced energy costs. ...

  4. PRODUCTION OF METALS AND THEIR COMPOUNDS

    DOE Patents [OSTI]

    Arden, T.V.; Burstall, F.H.; Davies, G.R.; Linstead, R.P.; Wells, R.A.

    1958-11-18

    Zirconium nitrate can be separated from hafnium nitrate by mixing the nitrates with ethyl cellulose pulp, eluting the mass with diethyl ether containing nitric acid, and passing the eluent through a column of cellulose pulp the outflow of which is substantially free of hafnium.

  5. Methods of fabricating cermet materials and methods of utilizing same

    DOE Patents [OSTI]

    Kong, Peter C.

    2006-04-04

    Methods of fabricating cermet materials and methods of utilizing the same such as in filtering particulate and gaseous pollutants from internal combustion engines having intermetallic and ceramic phases. The cermet material may be made from a transition metal aluminide phase and an aluminia phase. The mixture may be pressed to form a green compact body and then heated in a nitrogen-containing atmosphere so as to melt aluminum particles and form the cermet. Filler materials may be added to increase the porosity or tailor the catalytic properties of the cermet material. Additionally, the cermet material may be reinforced with fibers or screens. The cermet material may also be formed so as to pass an electrical current therethrough to heat the material during use.

  6. Microchannel crossflow fluid heat exchanger and method for its fabrication

    DOE Patents [OSTI]

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1982-08-31

    A microchannel crossflow fluid heat exchanger and a method for its fabrication are disclosed. The heat exchanger is formed from a stack of thin metal sheets which are bonded together. The stack consists of alternating slotted and unslotted sheets. Each of the slotted sheets includes multiple parallel slots which form fluid flow channels when sandwiched between the unslotted sheets. Successive slotted sheets in the stack are rotated ninety degrees with respect to one another so as to form two sets of orthogonally extending fluid flow channels which are arranged in a crossflow configuration. The heat exchanger has a high surface to volume ratio, a small dead volume, a high heat transfer coefficient, and is suitable for use with fluids under high pressures. The heat exchanger has particular application in a Stirling engine that utilizes a liquid as the working substance.

  7. Method for fabricating beryllium-based multilayer structures

    DOE Patents [OSTI]

    Skulina, Kenneth M.; Bionta, Richard M.; Makowiecki, Daniel M.; Alford, Craig S.

    2003-02-18

    Beryllium-based multilayer structures and a process for fabricating beryllium-based multilayer mirrors, useful in the wavelength region greater than the beryllium K-edge (111 .ANG. or 11.1 nm). The process includes alternating sputter deposition of beryllium and a metal, typically from the fifth row of the periodic table, such as niobium (Nb), molybdenum (Mo), ruthenium (Ru), and rhodium (Rh). The process includes not only the method of sputtering the materials, but the industrial hygiene controls for safe handling of beryllium. The mirrors made in accordance with the process may be utilized in soft x-ray and extreme-ultraviolet projection lithography, which requires mirrors of high reflectivity (>60%) for x-rays in the range of 60-140 .ANG. (60-14.0 nm).

  8. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley; Szreders, Bernard E.

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  9. Design & Fabrication of a High-Voltage Photovoltaic Cell

    SciTech Connect (OSTI)

    Felder, Jennifer; /North Carolina State U. /SLAC

    2012-09-05

    Silicon photovoltaic (PV) cells are alternative energy sources that are important in sustainable power generation. Currently, applications of PV cells are limited by the low output voltage and somewhat low efficiency of such devices. In light of this fact, this project investigates the possibility of fabricating high-voltage PV cells on float-zone silicon wafers having output voltages ranging from 50 V to 2000 V. Three designs with different geometries of diffusion layers were simulated and compared in terms of metal coverage, recombination, built-in potential, and conduction current density. One design was then chosen and optimized to be implemented in the final device design. The results of the simulation serve as a feasibility test for the design concept and provide supportive evidence of the effectiveness of silicon PV cells as high-voltage power supplies.

  10. Method of fabricating high-density hermetic electrical feedthroughs

    DOE Patents [OSTI]

    Shah, Kedar G.; Pannu, Satinderpall S.; Delima, Terri L.

    2015-06-02

    A method of fabricating electrical feedthroughs selectively removes substrate material from a first side of an electrically conductive substrate (e.g. a bio-compatible metal) to form an array of electrically conductive posts in a substrate cavity. An electrically insulating material (e.g. a bio-compatible sealing glass) is then flowed to fill the substrate cavity and surround each post, and solidified. The solidified insulating material is then exposed from an opposite second side of the substrate so that each post is electrically isolated from each other as well as the bulk substrate. In this manner a hermetic electrically conductive feedthrough construction is formed having an array of electrical feedthroughs extending between the first and second sides of the substrate from which it was formed.

  11. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  12. Thermodynamic Evaluation of Hydrogen Absorption by Niobium During SRF Fabrication

    SciTech Connect (OSTI)

    Ricker, R. E.; Myneni, G. R.

    2011-03-31

    The properties and performance of the ultra high purity Nb used to fabricate superconducting radio frequency (SRF) particle accelerator cavities have been found to vary with processing conditions. One hypothesis for these variations is that hydrogen, absorbed during processing, is responsible for this behavior. The key assumption behind this hypothesis is that niobium can absorb hydrogen from one or more of the processing environments. This paper reviews work examining the validity of this assumption. It was determined that Nb will spontaneously react with water producing adsorbed atomic hydrogen that is readily absorbed into the metal. The passivating oxide film normally prevents this reaction, but this film is frequently removed during processing and it is attacked by the fluoride ion used in the polishing solutions for SRF cavities. However, during electropolishing that cathodic reduction of hydrogen is transferred to the auxiliary electrode and this should suppress hydrogen absorption.

  13. Microchannel crossflow fluid heat exchanger and method for its fabrication

    DOE Patents [OSTI]

    Swift, G.W.; Migliori, A.; Wheatley, J.C.

    1985-05-14

    A microchannel crossflow fluid heat exchanger and a method for its fabrication are disclosed. The heat exchanger is formed from a stack of thin metal sheets which are bonded together. The stack consists of alternating slotted and unslotted sheets. Each of the slotted sheets includes multiple parallel slots which form fluid flow channels when sandwiched between the unslotted sheets. Successive slotted sheets in the stack are rotated ninety degrees with respect to one another so as to form two sets of orthogonally extending fluid flow channels which are arranged in a crossflow configuration. The heat exchanger has a high surface to volume ratio, a small dead volume, a high heat transfer coefficient, and is suitable for use with fluids under high pressures. The heat exchanger has particular application in a Stirling engine that utilizes a liquid as the working substance. 9 figs.

  14. Microchannel crossflow fluid heat exchanger and method for its fabrication

    DOE Patents [OSTI]

    Swift, Gregory W.; Migliori, Albert; Wheatley, John C.

    1985-01-01

    A microchannel crossflow fluid heat exchanger and a method for its fabrication are disclosed. The heat exchanger is formed from a stack of thin metal sheets which are bonded together. The stack consists of alternating slotted and unslotted sheets. Each of the slotted sheets includes multiple parallel slots which form fluid flow channels when sandwiched between the unslotted sheets. Successive slotted sheets in the stack are rotated ninety degrees with respect to one another so as to form two sets of orthogonally extending fluid flow channels which are arranged in a crossflow configuration. The heat exchanger has a high surface to volume ratio, a small dead volume, a high heat transfer coefficient, and is suitable for use with fluids under high pressures. The heat exchanger has particular application in a Stirling engine that utilizes a liquid as the working substance.

  15. Fabricating porous materials using interpenetrating inorganic-organic composite gels

    DOE Patents [OSTI]

    Seo, Dong-Kyun; Volosin, Alex

    2016-06-14

    Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite material can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.

  16. Literature on fabrication of tungsten for application in pyrochemical processing of spent nuclear fuels

    SciTech Connect (OSTI)

    Edstrom, C.M.; Phillips, A.G.; Johnson, L.D.; Corle, R.R.

    1980-10-11

    The pyrochemical processing of nuclear fuels requires crucibles, stirrers, and transfer tubing that will withstand the temperature and the chemical attack from molten salts and metals used in the process. This report summarizes the literature that pertains to fabrication (joining, chemical vapor deposition, plasma spraying, forming, and spinning) is the main theme. This report also summarizes a sampling of literature on molbdenum and the work previously performed at Argonne National Laboratory on other container materials used for pyrochemical processing of spent nuclear fuels.

  17. Note: Fabrication and characterization of molybdenum tips for scanning tunneling microscopy and spectroscopy

    SciTech Connect (OSTI)

    Carrozzo, P.; Tumino, F.; Facibeni, A.; Passoni, M.; Casari, C. S.; Li Bassi, A.

    2015-01-15

    We present a method for the preparation of bulk molybdenum tips for Scanning Tunneling Microscopy and Spectroscopy and we assess their potential in performing high resolution imaging and local spectroscopy by measurements on different single crystal surfaces in UHV, namely, Au(111), Si(111)-7 × 7, and titanium oxide 2D ordered nanostructures supported on Au(111). The fabrication method is versatile and can be extended to other metals, e.g., cobalt.

  18. Fabrication of thin-wall hollow nickel spheres and low density syntactic foams

    SciTech Connect (OSTI)

    Clancy, R.B.; Sanders, T.H. Jr.; Cochran, J.K.

    1991-12-31

    A process has been developed to fabricate thin-wall hollow spheres from conventional oxide powders at room temperature. The polymer- bonded powder shells are fired in air to sinter the walls, leaving the shells either impervious or porous. Alternatively, the oxide shells can be preferentially reduced to produce thin-wall hollow metal spheres which can be bonded together to produce an ultra light weight closed-cell foam. Processing and properties of this class of low density structures will be discussed.

  19. UPDATE ON MONOLITHIC FUEL FABRICATION METHODS

    SciTech Connect (OSTI)

    C. R. Clark; J. F. Jue; G. A. Moore; N. P. Hallinan; B. H. Park; D. E. Burkes

    2006-10-01

    Efforts to develop a viable monolithic research reactor fuel plate have continued at Idaho National Laboratory. These efforts have concentrated on both fabrication process refinement and scale-up to produce full sized fuel plates. Progress at INL has led to fabrication of hot isostatic pressed uranium-molybdenum bearing monolithic fuel plates. These miniplates are part of the RERTR-8 miniplate irradiation test. Further progress has also been made on friction stir weld processing which has been used to fabricate full size fuel plates which will be irradiated in the ATR and OSIRIS reactors.

  20. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  1. TOWARD LOW-COST FABRICATION OF MICROCHANNEL PROCESS TECHNOLOGIES - COST MODELING FOR MANUFACTURING DEVELOPMENT

    SciTech Connect (OSTI)

    Leith, Steven D.; King, Dale A.; Paul, Brian

    2010-11-07

    Chemical and energy conversion systems based on microchannel process technology (MPT) demonstrate high performance in applications in which rates are controlled by diffusive heat and mass transfer flux. The performance of MPT-based heat exchangers, absorbers/desorbers and chemical reactors all benefit from process intensification and have been used in a variety of mobile energy conversion systems including fuel reformers/converters, heat pumps and waste heat scavenging technologies. The service environments typical of MPTs often require the devices to be fabricated from metals such as aluminum, titanium, stainless steel or high temperature super alloys. Flow channels and associated critical dimensions in these devices can be as small as 50 um, but generally range from 100 to 1000 um in width and height with characteristic flow channel lengths normally in the mm to cm range. High surface area architectures (e.g. wicks or textured surfaces) are often included in the flow channels as well for enhanced mass transfer and/or catalytic functionality. Fabrication of MPT devices has historically been performed using a stacked-shim approach in which individual metal sheets are first patterned with micro- and meso-scale flow channels and subsequently bonded in a stack to create an array of miniaturized, parallel flow paths. Typical proof-of-concept fabrication efforts have utilized photo chemical machining (PCM) for shim patterning and diffusion bonding or diffusion brazing for joining of shim stacks. While flexible and capable of supporting technology demonstration, however, these techniques can be expensive at prototyping volumes. The high fabrication cost associated with these prototyping processes has contributed to a perception that MPT technology is expensive and will be relegated to a small application space. Recent work at the Microproducts Breakthrough Institute (MBI) has focused on exploring the cost structure of high volume manufacturing of MPT devices in effort to

  2. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  3. Working with SRNL - Our Facilities- Rapid Fabrication Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rapid Fabrication Facility Working with SRNL Our Facilities - Rapid Fabrication Facility At SRNL's Rapid Fabrication Facility, low-cost prototypes are produced, as well as parts and complete working models

  4. Micro-turbo-generator design and fabrication: A preliminary study

    SciTech Connect (OSTI)

    Wiegele, T.G.

    1996-12-31

    The size and weight of portable electronic products are often dictated by the physical characteristics of the power supply system. The design of energy storage systems is therefore critical to market competitiveness. An alternative to energy storage is proposed in this paper which relies on a very small power generation system which converts a pressure difference in a gas into electrical power: a micro-turbo-generator. The design of the micro-turbo-generator involved combining two very different machines, a micro-generator and a micro-turbine, into a single device which could be fabricated within the constraints of current microelectronic processing techniques. Research into power generation on the micro-scale has begun to take place in the form of electromagnetic micro-motor design and fabrication. These variable reluctance machines can be transformed into power generation devices by implementing accurate rotor position sensing, high-speed current switching and a means for inducing rotor motion. This leads to the implementation of a switched reluctance generator, which is well-understood on the macro-scale but has not been attempted on the micro-scale. The most significant hurdle facing researchers is the task of coupling a prime mover, such as a micro-turbine, to the rotor of a power generation device efficiently and effectively while maintaining relative simplicity in the fabrication procedures. The design presented here offers a potential solution to this problem.

  5. Rapid low-temperature processing of metal-oxide thin film transistors with combined far ultraviolet and thermal annealing

    SciTech Connect (OSTI)

    Leppniemi, J. Ojanper, K.; Kololuoma, T.; Huttunen, O.-H.; Majumdar, H.; Alastalo, A.; Dahl, J.; Tuominen, M.; Laukkanen, P.

    2014-09-15

    We propose a combined far ultraviolet (FUV) and thermal annealing method of metal-nitrate-based precursor solutions that allows efficient conversion of the precursor to metal-oxide semiconductor (indium zinc oxide, IZO, and indium oxide, In{sub 2}O{sub 3}) both at low-temperature and in short processing time. The combined annealing method enables a reduction of more than 100?C in annealing temperature when compared to thermally annealed reference thin-film transistor (TFT) devices of similar performance. Amorphous IZO films annealed at 250?C with FUV for 5?min yield enhancement-mode TFTs with saturation mobility of ?1?cm{sup 2}/(Vs). Amorphous In{sub 2}O{sub 3} films annealed for 15?min with FUV at temperatures of 180?C and 200?C yield TFTs with low-hysteresis and saturation mobility of 3.2?cm{sup 2}/(Vs) and 7.5?cm{sup 2}/(Vs), respectively. The precursor condensation process is clarified with x-ray photoelectron spectroscopy measurements. Introducing the FUV irradiation at 160?nm expedites the condensation process via in situ hydroxyl radical generation that results in the rapid formation of a continuous metal-oxygen-metal structure in the film. The results of this paper are relevant in order to upscale printed electronics fabrication to production-scale roll-to-roll environments.

  6. Blunt Trauma Performance of Fabric Systems Utilizing Natural Rubber Coated High Strength Fabrics

    SciTech Connect (OSTI)

    Ahmad, M. R.; Ahmad, W. Y. W.; Samsuri, A.; Salleh, J.; Abidin, M. H.

    2010-03-11

    The blunt trauma performance of fabric systems against 9 mm bullets is reported. Three shots were fired at each fabric system with impact velocity of 367+-9 m/s and the depth of indentation on the modeling clay backing was measured. The results showed that 18-layer and 21-layer all-neat fabric systems failed the blunt trauma test. However, fabric systems with natural rubber (NR) latex coated fabric layers gave lower blunt trauma of between 25-32 mm indentation depths. Deformations on the neat fabrics upon impact were identified as broken yarns, yarn stretching and yarn pull-out. Deflections of the neat fabrics were more localised. For the NR latex coated fabric layers, no significant deformation can be observed except for peeled-off regions of the NR latex film at the back surface of the last layer. From the study, it can be said that the NR latex coated fabric layers were effective in reducing the blunt trauma of fabric systems.

  7. Hydrogen-permeable composite metal membrane and uses thereof

    DOE Patents [OSTI]

    Edlund, David J.; Friesen, Dwayne T.

    1993-06-08

    Various hydrogen production and hydrogen sulfide decomposition processes are disclosed that utilize composite metal membranes that contain an intermetallic diffusion barrier separating a hydrogen-permeable base metal and a hydrogen-permeable coating metal. The barrier is a thermally stable inorganic proton conductor.

  8. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the...

  9. REFRACTORY METAL TUBE DRAWING

    DOE Patents [OSTI]

    Bean, C.H.; Karasek, F.J.

    1963-01-29

    A lubricant for drawing Zr and other refractory metals is described. Metallic Cu powder is added to a solution of acrylic resin in chlorinated hydrocarbon solvent. (AEC)

  10. ALT-GTS-Stem Fabrication

    SciTech Connect (OSTI)

    Thuan Nguyen

    2008-09-25

    In 2007, a study investigated options to manufacture stems utilizing methods that would replace crush form grinding while maintaining or improving quality at a comparative cost. Crush form grinding is a special process used at the Kansas City Plant to finish stem sections of reservoir products. However, crush form grinding is a complex process with many variables affecting the final product. This study identified two potential methods that can be applied to stems. Profile grinding was investigated in 2007. This project continued in 2008 proving that single point turning on a multi-turret is an option with additional benefits. It is an economical way to meet floor space limitations for our KCRIMS mission.

  11. Robotic thermal battery pellet fabrication

    SciTech Connect (OSTI)

    Kimbler, D.L.; Townsend, A.S.; Walton, R.D.; Jones, C.W.

    1985-03-01

    Thermal battery manufacturing at the General Electric Neutron Devices Department (GEND) is a sequence of operations involving materials processing, component manufacture, and assembly. These operations, for the most part, have been manually performed although some operations have been computer- or fixture-assisted. The high labor intensity and the need for process consistency in these operations made the conversion to a robotic work cell appealing in that it could increase productivity while allowing the reassignment of highly-trained workers to other duties. An Alpha robot (Microbot, Inc.) was coupled with a Hewlett-Packard HP-9816 microcomputer, and custom software was developed to control the thermal battery manufacturing process. The software provided a menu-driven main program with feedback at virtually every step to allow technicians with little or no computer experience to operate the system. Previously, one or two workers were assigned to each of several industrial presses used in the manufacture of thermal batteries. With the introduction of a robotic operator and a microcomputer process control, one worker alone could support two to three presses, thus freeing as many as five workers to be assigned to other labor intensive duties. The production rate of the robotic work cell was approximately the same as the manual method, but the consistency of production and yield showed significant improvement.

  12. FUEL & TARGET FABRICATION Aiken County, South Carolina

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M Area is the site of Savannah River Plant's fuel and target fabrication facilities operated from 1955 through the end of the Cold War, producing fuel elements to be irradiated in ...

  13. Free form fabrication of thermoplastic composites

    SciTech Connect (OSTI)

    Kaufman, S.G.; Spletzer, B.L.; Guess, T.R.

    1998-02-01

    This report describes the results of composites fabrication research sponsored by the Laboratory Directed Research and Development (LDRD) program at Sandia National Laboratories. They have developed, prototyped, and demonstrated the feasibility of a novel robotic technique for rapid fabrication of composite structures. Its chief innovation is that, unlike all other available fabrication methods, it does not require a mold. Instead, the structure is built patch by patch, using a rapidly reconfigurable forming surface, and a robot to position the evolving part. Both of these components are programmable, so only the control software needs to be changed to produce a new shape. Hence it should be possible to automatically program the system to produce a shape directly from an electronic model of it. It is therefore likely that the method will enable faster and less expensive fabrication of composites.

  14. Fabrication of 3D Silicon Sensors

    SciTech Connect (OSTI)

    Kok, A.; Hansen, T.E.; Hansen, T.A.; Lietaer, N.; Summanwar, A.; Kenney, C.; Hasi, J.; Da Via, C.; Parker, S.I.; /Hawaii U.

    2012-06-06

    Silicon sensors with a three-dimensional (3-D) architecture, in which the n and p electrodes penetrate through the entire substrate, have many advantages over planar silicon sensors including radiation hardness, fast time response, active edge and dual readout capabilities. The fabrication of 3D sensors is however rather complex. In recent years, there have been worldwide activities on 3D fabrication. SINTEF in collaboration with Stanford Nanofabrication Facility have successfully fabricated the original (single sided double column type) 3D detectors in two prototype runs and the third run is now on-going. This paper reports the status of this fabrication work and the resulted yield. The work of other groups such as the development of double sided 3D detectors is also briefly reported.

  15. Precise carbon control of fabricated stainless steel

    DOE Patents [OSTI]

    Nilsen, R.J.

    1975-12-01

    A process is described for controlling the carbon content of fabricated stainless steel components including the steps of heat treating the component in hydrogen atmospheres of varying dewpoints and carbon potentials.

  16. Electronic Fabrication & Repair | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Fabrication & Repair The Electronics group provides custom design and fabrication of electronic equipment.. We convert ideas into custom-finished equipment in our shop using ORCAD Schematic Capture and PCB Layout software in conjunction with our PCB machine to make prototype circuit boards in-house. Our technicians also aid in automating and controlling research project instrumentation using Texas Instruments LabView. We repair all kinds of scientific and laboratory electronic and

  17. Carbon nanotube collimator fabrication and application

    DOE Patents [OSTI]

    Chow, Lee; Chai, Guangyu; Schenkel, Thomas

    2010-07-06

    Apparatus, methods, systems and devices for fabricating individual CNT collimators. Micron size fiber coated CNT samples are synthesized with chemical vapor deposition method and then the individual CNT collimators are fabricated with focused ion beam technique. Unfocused electron beams are successfully propagated through the CNT collimators. The CNT nano-collimators are used for applications including single ion implantation and in high-energy physics, and allow rapid, reliable testing of the transmission of CNT arrays for transport of molecules.

  18. Fabrication of thorium bearing carbide fuels

    DOE Patents [OSTI]

    Gutierrez, R.L.; Herbst, R.J.; Johnson, K.W.R.

    Thorium-uranium carbide and thorium-plutonium carbide fuel pellets have been fabricated by the carbothermic reduction process. Temperatures of 1750/sup 0/C and 2000/sup 0/C were used during the reduction cycle. Sintering temperatures of 1800/sup 0/C and 2000/sup 0/C were used to prepare fuel pellet densities of 87% and > 94% of theoretical, respectively. The process allows the fabrication of kilogram quantities of fuel with good reproductibility of chemical and phase composition.

  19. Fabrication of glass microspheres with conducting surfaces

    DOE Patents [OSTI]

    Elsholz, William E.

    1984-01-01

    A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

  20. Fabrication of glass microspheres with conducting surfaces

    DOE Patents [OSTI]

    Elsholz, W.E.

    1982-09-30

    A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

  1. Method to fabricate layered material compositions

    DOE Patents [OSTI]

    Fleming, James G.; Lin, Shawn-Yu

    2002-01-01

    A new class of processes suited to the fabrication of layered material compositions is disclosed. Layered material compositions are typically three-dimensional structures which can be decomposed into a stack of structured layers. The best known examples are the photonic lattices. The present invention combines the characteristic features of photolithography and chemical-mechanical polishing to permit the direct and facile fabrication of, e.g., photonic lattices having photonic bandgaps in the 0.1-20.mu. spectral range.

  2. Method to fabricate layered material compositions

    DOE Patents [OSTI]

    Fleming, James G.; Lin, Shawn-Yu

    2004-11-02

    A new class of processes suited to the fabrication of layered material compositions is disclosed. Layered material compositions are typically three-dimensional structures which can be decomposed into a stack of structured layers. The best known examples are the photonic lattices. The present invention combines the characteristic features of photolithography and chemical-mechanical polishing to permit the direct and facile fabrication of, e.g., photonic lattices having photonic bandgaps in the 0.1-20.mu. spectral range.

  3. Fabrication of Single Donor Devices for Quantum Computation using...

    Office of Scientific and Technical Information (OSTI)

    Fabrication of Single Donor Devices for Quantum Computation using Focused Top-Down Ion Implantation. Citation Details In-Document Search Title: Fabrication of Single Donor Devices ...

  4. Sandia Energy - Self-Regulated Fabrication of Size-Controlled...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Self-Regulated Fabrication of Size-Controlled Quantum Nanostructures Home Highlights - Energy Research Self-Regulated Fabrication of Size-Controlled Quantum Nanostructures Previous...

  5. System of fabricating a flexible electrode array (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    System of fabricating a flexible electrode array Title: System of fabricating a flexible electrode array An image is captured or otherwise converted into a signal in an artificial ...

  6. Ultrafast Laser Fabrication: a Rapid Prototyping Capability for...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Ultrafast Laser Fabrication: a Rapid Prototyping Capability for CINT Citation Details In-Document Search Title: Ultrafast Laser Fabrication: a Rapid Prototyping...

  7. Thermoelectric FabricsŽ based on carbon nanotube composites...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Fabrics based on carbon nanotube composites Composite films of ... multiple element modules, results in thermoelectric fabrics with increased power output ...

  8. Fabrication and current optical performance of a large diamond...

    Office of Scientific and Technical Information (OSTI)

    Fabrication and current optical performance of a large diamond-machined ZnSe immersion grating Citation Details In-Document Search Title: Fabrication and current optical ...

  9. Ultrafast Laser Fabrication: a Rapid Prototyping Capability for...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Ultrafast Laser Fabrication: a Rapid Prototyping Capability for CINT Citation Details In-Document Search Title: Ultrafast Laser Fabrication: a Rapid Prototyping ...

  10. Rapid Freeform Sheet Metal Forming Project Touted in the News | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Rapid Freeform Sheet Metal Forming Project Touted in the News Rapid Freeform Sheet Metal Forming Project Touted in the News April 28, 2014 - 4:47pm Addthis Fabricating and Forming Journal's April issue includes "Forming the Future," a feature story about AMO's Innovative Manufacturing Initiative (IMI) Project - Rapid Freeform Sheet Metal Forming. This project, begun in 2013, involves Ford, Boeing, Northwestern University, Penn State, and MIT. Dr. David Forrest, AMO

  11. Characterization of candidate DOE sites for fabricating MOX fuel for lead assemblies

    SciTech Connect (OSTI)

    Holdaway, R.F.; Miller, J.W.; Sease, J.D.; Moses, R.J.; O`Connor, D.G.; Carrell, R.D.; Jaeger, C.D.; Thompson, M.L.; Strasser, A.A.

    1998-03-01

    The Office of Fissile Materials Disposition (MD) of the Department of Energy (DOE) is directing the program to disposition US surplus weapons-usable plutonium. For the reactor option for disposition of this surplus plutonium, MD is seeking to contract with a consortium, which would include a mixed-oxide (MOX) fuel fabricator and a commercial US reactor operator, to fabricate and burn MOX fuel in existing commercial nuclear reactors. This option would entail establishing a MOX fuel fabrication facility under the direction of the consortium on an existing DOE site. Because of the lead time required to establish a MOX fuel fabrication facility and the need to qualify the MOX fuel for use in a commercial reactor, MD is considering the early fabrication of lead assemblies (LAs) in existing DOE facilities under the technical direction of the consortium. The LA facility would be expected to produce a minimum of 1 metric ton heavy metal per year and must be operational by June 2003. DOE operations offices were asked to identify candidate sites and facilities to be evaluated for suitability to fabricate MOX fuel LAs. Savannah River Site, Argonne National Laboratory-West, Hanford, Lawrence Livermore National Laboratory, and Los Alamos National Laboratory were identified as final candidates to host the LA project. A Site Evaluation Team (SET) worked with each site to develop viable plans for the LA project. SET then characterized the suitability of each of the five plans for fabricating MOX LAs using 28 attributes and documented the characterization to aid DOE and the consortium in selecting the site for the LA project. SET concluded that each option has relative advantages and disadvantages in comparison with other options; however, each could meet the requirements of the LA project as outlined by MD and SET.

  12. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cobalt Discovery Replaces Precious Metals Cobalt discovery replaces precious metals as industrial catalyst Cobalt holds promise as an industrial catalyst with potential applications in such energy-related technologies such as production of biofuels and reduction of carbon dioxide. November 26, 2012 The artwork depicts the substitution of cobalt for precious metals in catalysis as a variation on the ancient alchemical theme of transmuting base metals into precious ones. The artwork depicts the

  13. Cobalt discovery replaces precious metals as industrial catalyst

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cobalt Discovery Replaces Precious Metals Cobalt discovery replaces precious metals as industrial catalyst Cobalt holds promise as an industrial catalyst with potential applications in such energy-related technologies such as production of biofuels and reduction of carbon dioxide. November 26, 2012 The artwork depicts the substitution of cobalt for precious metals in catalysis as a variation on the ancient alchemical theme of transmuting base metals into precious ones. The artwork depicts the

  14. Co-Design: Fabrication of Unalloyed Plutonium

    SciTech Connect (OSTI)

    Korzekwa, Deniece R. [Los Alamos National Laboratory; Knapp, Cameron M. [Los Alamos National Laboratory; Korzekwa, David A. [Los Alamos National Laboratory; Gibbs, John W [Northwestern University

    2012-07-25

    The successful induction casting of plutonium is a challenge which requires technical expertise in areas including physical metallurgy, surface and corrosion chemistry, materials science, electromagnetic engineering and a host of other technologies all which must be applied in concert. Here at LANL, we are employing a combined experimental and computational approach to design molds and develop process parameters needed to produce desired temperature profiles and improved castings. Computer simulations are performed using the commercial code FLOW-3D and the LANL ASC computer code TRUCHAS to reproduce the entire casting process starting with electromagnetic or radiative heating of the mold and metal and continuing through pouring with coupled fluid flow, heat transfer and non-isothermal solidification. This approach greatly reduces the time required to develop a new casting designs and also increases our understanding of the casting process, leading to a more homogeneous, consistent product and better process control. We will discuss recent casting development results in support of unalloyed plutonium rods for mechanical testing.

  15. Method of fabricating a 3-dimensional tool master

    DOE Patents [OSTI]

    Bonivert, William D. (Pleasanton, CA); Hachman, John T. (Stockton, CA)

    2002-01-01

    The invention is a method for the fabrication of an imprint tool master. The process begins with a metallic substrate. A layer of photoresist is placed onto the metallic substrate and a image pattern mask is then aligned to the mask. The mask pattern has opaque portions that block exposure light and "open" or transparent portions which transmit exposure light. The photoresist layer is then exposed to light transmitted through the "open" portions of the first image pattern mask and the mask is then removed. A second layer of photoresist then can be placed onto the first photoresist layer and a second image pattern mask may be placed on the second layer of photoresist. The second layer of photoresist is exposed to light, as before, and the second mask removed. The photoresist layers are developed simultaneously to produce a multi-level master mandrel upon which a conductive film is formed. A tool master can now be formed onto the conductive film. An imprint tool is then produced from the tool master. In one embodiment, nickel is electroplated onto the tool master to produce a three-dimensional imprint tool.

  16. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  17. Ceramic to metal seal

    DOE Patents [OSTI]

    Snow, Gary S.; Wilcox, Paul D.

    1976-01-01

    Providing a high strength, hermetic ceramic to metal seal by essentially heating a wire-like metal gasket and a ceramic member, which have been chemically cleaned, while simultaneously deforming from about 50 to 95 percent the metal gasket against the ceramic member at a temperature of about 30 to 75 percent of the melting temperature of the metal gasket.

  18. PRODUCTION OF TRIFLUOROACETIC ACID

    DOE Patents [OSTI]

    Haworth, W.N.; Stacey, M.

    1949-07-19

    A method is given for the production of improved yields of trifluoroacetic acid. The compound is prepared by oxidizing m-aminobenzotrifluoride with an alkali metal or alkaline earth metal permanganate at a temperature in the range of 80 deg C to 100 deg C while dissolved ln a mixture of water with glacial acetic acid and/or trifluoroacetic acid. Preferably a mixture of water and trifluoroacetic acid ls used as the solvent.

  19. METAL MEDIA FILTERS, AG-1 SECTION FI

    SciTech Connect (OSTI)

    Adamson, D.

    2012-05-23

    One application of metal media filters is in various nuclear air cleaning processes including applications for protecting workers, the public and the environment from hazardous and radioactive particles. To support this application the development of the ASME AG-1 FI Standard on Metal Media has been under way for more than ten years. Development of the proposed section has required resolving several difficult issues associated with operating conditions (media velocity, pressure drop, etc.), qualification testing, and quality acceptance testing. Performance characteristics of metal media are dramatically different than the glass fiber media with respect to parameters like differential pressures, operating temperatures, media strength, etc. These differences make existing data for a glass fiber media inadequate for qualifying a metal media filter for AG-1. In the past much work has been conducted on metal media filters at facilities such as Lawrence Livermore National Laboratory (LLNL) and Savannah River National Laboratory (SRNL) to qualify the media as High Efficiency Particulate Air (HEPA) Filters. Particle retention testing has been conducted at Oak Ridge Filter Test Facility and at Air Techniques International (ATI) to prove that the metal media meets or exceeds the 99.97% particle retention required for a HEPA Filter. Even with his testing, data was lacking to complete an AG-1 FI Standard on metal media. With funding secured by Mississippi State University (MSU) from National Nuclear Security Administration (NNSA), a research test stand is being designed and fabricated at MSU's Institute for Clean Energy Technology (ICET) Facility to obtain qualification data on metal media. This in turn will support required data needed for the FI Standard. The paper will discuss in detail how the test stand at MSU will obtain the necessary data to complete the FI Standard.

  20. Performance limit analysis of a metallic fuel for Kalimer

    SciTech Connect (OSTI)

    Lee, Byoung Oon; Cheon, J.S.; Lee, C.B.

    2007-07-01

    A metallic fuel is being considered as the fuel for SFR in Korea. The metal fuel development for SFR in Korea started in 2007 in the areas of metal fuel fabrication, cladding materials and fuel performance evaluation. The MACSIS code for a metallic fuel has been developed as a steady-state performance computer code. Present study represents the preliminary parametric results for evaluating the design limits of the metal fuel for SFR in Korea. The operating limits were analyzed by the MACSIS code. The modules of the creep rupture strength for the Mod.HT9 and the barrier cladding were inserted. The strain limits and the CDF limit were analyzed for the HT9, and the Mod.HT9. To apply the concept of a barrier cladding, the burnup limit of the barrier cladding was analyzed. (authors)

  1. Fabrication of miniaturized electrostatic deflectors using LIGA

    SciTech Connect (OSTI)

    Jackson, K.H.; Khan-Malek, C.; Muray, L.P.

    1997-04-01

    Miniaturized electron beam columns ({open_quotes}microcolumns{close_quotes}) have been demonstrated to be suitable candidates for scanning electron microscopy (SEM), e-beam lithography and other high resolution, low voltage applications. In the present technology, microcolumns consist of {open_quotes}selectively scaled{close_quotes} micro-sized lenses and apertures, fabricated from silicon membranes with e-beam lithography, reactive ion beam etching and other semiconductor thin-film techniques. These miniaturized electron-optical elements provide significant advantages over conventional optics in performance and ease of fabrication. Since lens aberrations scale roughly with size, it is possible to fabricate simple microcolumns with extremely high brightness sources and electrostatic objective lenses, with resolution and beam current comparable to conventional e-beam columns. Moreover since microcolumns typically operate at low voltages (1 KeV), the proximity effects encountered in e-beam lithography become negligible. For high throughput applications, batch fabrication methods may be used to build large parallel arrays of microcolumns. To date, the best reported performance with a 1 keV cold field emission cathode, is 30 nm resolution at a working distance of 2mm in a 3.5mm column. Fabrication of the microcolumn deflector and stigmator, however, have remained beyond the capabilities of conventional machining operations and semiconductor processing technology. This work examines the LIGA process as a superior alternative to fabrication of the deflectors, especially in terms of degree of miniaturization, dimensional control, placement accuracy, run-out, facet smoothness and choice of suitable materials. LIGA is a combination of deep X-ray lithography, electroplating, and injection molding processes which allow the fabrication of microstructures.

  2. Enhanced photoresponse of conformal TiO{sub 2}/Ag nanorod array-based Schottky photodiodes fabricated via successive glancing angle and atomic layer deposition

    SciTech Connect (OSTI)

    Haider, Ali; Biyikli, Necmi; Cansizoglu, Hilal; Cansizoglu, Mehmet Fatih; Karabacak, Tansel; Okyay, Ali Kemal

    2015-01-01

    In this study, the authors demonstrate a proof of concept nanostructured photodiode fabrication method via successive glancing angle deposition (GLAD) and atomic layer deposition (ALD). The fabricated metal-semiconductor nanorod (NR) arrays offer enhanced photoresponse compared to conventional planar thin-film counterparts. Silver (Ag) metallic NR arrays were deposited on Ag-film/Si templates by utilizing GLAD. Subsequently, titanium dioxide (TiO{sub 2}) was deposited conformally on Ag NRs via ALD. Scanning electron microscopy studies confirmed the successful formation of vertically aligned Ag NRs deposited via GLAD and conformal deposition of TiO{sub 2} on Ag NRs via ALD. Following the growth of TiO{sub 2} on Ag NRs, aluminum metallic top contacts were formed to complete the fabrication of NR-based Schottky photodiodes. Nanostructured devices exhibited a photo response enhancement factor of 1.49??10{sup 2} under a reverse bias of 3 V.

  3. Amorphous metal composites

    DOE Patents [OSTI]

    Byrne, Martin A. (Troy, NY); Lupinski, John H. (Scotia, NY)

    1984-01-01

    An improved amorphous metal composite and process of making the composite. The amorphous metal composite comprises amorphous metal (e.g. iron) and a low molecular weight thermosetting polymer binder. The process comprises placing an amorphous metal in particulate form and a thermosetting polymer binder powder into a container, mixing these materials, and applying heat and pressure to convert the mixture into an amorphous metal composite.

  4. Bioactive glass coatings for orthopedic metallic implants

    SciTech Connect (OSTI)

    Lopez-Esteban, Sonia; Saiz, Eduardo; Fujino, Sigheru; Oku, Takeo; Suganuma, Katsuaki; Tomsia, Antoni P.

    2003-06-30

    The objective of this work is to develop bioactive glass coatings for metallic orthopedic implants. A new family of glasses in the SiO2-Na2O-K2O-CaO-MgO-P2O5 system has been synthesized and characterized. The glass properties (thermal expansion, softening and transformation temperatures, density and hardness) are in line with the predictions of established empirical models. The optimized firing conditions to fabricate coatings on Ti-based and Co-Cr alloys have been determined and related to the glass properties and the interfacial reactions. Excellent adhesion to alloys has been achieved through the formation of 100-200 nm thick interfacial layers (Ti5Si3 on Ti-based alloys and CrOx on Co-Cr). Finally, glass coatings, approximately 100 mu m thick, have been fabricated onto commercial Ti alloy-based dental implants.

  5. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  6. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.

    1998-01-01

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  7. Electrolytic fabrication of atomic clock cells

    SciTech Connect (OSTI)

    Gong, F.; Jau, Y.-Y.; Jensen, K.; Happer, W.

    2006-07-15

    We describe an electrolytic method to release controlled amounts of free alkali metal into miniature cells in a silicon wafer with anodically bonded glass windows.

  8. Powder Metallurgy Fabrication of Molybdenum Accelerator Target Disks

    SciTech Connect (OSTI)

    Lowden, Richard Andrew; Kiggans Jr., James O.; Nunn, Stephen D.; Parten, Randy J.

    2015-12-01

    Powder metallurgy approaches for the fabrication of accelerator target disks are being examined to support the development of Mo-99 production by NorthStar Medical Technologies, LLC. An advantage of powder metallurgy is that very little material is wasted and at present, dense, quality parts are routinely produced from molybdenum powder. The proposed targets, however, are thin wafers, 29 mm in diameter with a thickness of 0.5 mm, with very stringent dimensional tolerances. Although tooling can be machined to very high tolerance levels, the operations of powder feed, pressing and sintering involve complicated mechanisms, each of which affects green density and shrinkage, and therefore the dimensions and shape of the final product. Combinations of powder morphology, lubricants and pressing technique have been explored to produce target disks with minimal variations in thickness and little or no distortion. In addition, sintering conditions that produce densities for optimum target dissolvability are being determined.

  9. Development of Metal Substrate for Denox Catalysts and Particulate Trap

    SciTech Connect (OSTI)

    Pollard, Michael; Habeger, Craig; Frary, Megan; Haines, Scott; Fluharty, Amy; Dakhoul, Youssef; Carr, Michael; Park, Paul; Stefanick, Matthew; DaCosta, Herbert; Balmer-Millar, M Lou; Readey, Michael; McCluskey, Philip

    2005-12-31

    The objective of this project was to develop advanced metallic catalyst substrate materials and designs for use in off-highway applications. The new materials and designs will be used as catalyst substrates and diesel particulate traps. They will increase durability, reduce flow resistance, decrease time to light-off, and reduce cost relative to cordierite substrates. Metallic catalyst substrates are used extensively for diesel oxidation catalysts and have the potential to be used in other catalytic systems for diesel engines. Metallic substrates have many advantages over ceramic materials including improved durability and resistance to thermal shock and vibration. However, the cost is generally higher than cordierite. The most common foil material used for metallic substrates is FeCr Alloy, which is expensive and has temperature capabilities beyond what is necessary for diesel applications. The first task in the project was Identification and Testing of New Materials. In this task, several materials were analyzed to determine if a low cost substitute for FeCr Alloy was available or could be developed. Two materials were identified as having lower cost while showing no decrease in mechanical properties or oxidation resistance at the application temperatures. Also, the ability to fabricate these materials into a finished substrate was not compromised, and the ability to washcoat these materials was satisfactory. Therefore, both candidate materials were recommended for cost savings depending on which would be less expensive in production quantities. The second task dealt with the use of novel flow designs to improve the converter efficiency while possibly decreasing the size of the converter to reduce cost even more. A non-linear flow path was simulated to determine if there would be an increase in efficiency. From there, small samples were produced for bench testing. Bench tests showed that the use of non-linear channels significantly reduced the light

  10. Ethanol production method and system

    DOE Patents [OSTI]

    Chen, M.J.; Rathke, J.W.

    1983-05-26

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  11. Methanol production method and system

    DOE Patents [OSTI]

    Chen, Michael J.; Rathke, Jerome W.

    1984-01-01

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  12. Reaction-Forming Method for Producing Near Net-Shape Refractory Metal Carbides

    DOE Patents [OSTI]

    Palmisiano, Marc N.; Jakubenas, Kevin J.; Baranwal, Rita

    2004-07-20

    A method for reaction forming refractory metal carbides. The method involves the fabrication of a glassy carbon preform by casting an organic, resin-based liquid mixture into a mold and subsequently heat treating it in two steps, which cures and pyrolizes the resin resulting in a porous carbon preform. By varying the amounts of the constituents in the organic, resin-based liquid mixture, control over the density of the carbon preform is obtained. Control of the density and microstructure of the carbon preform allows for determination of the microstructure and properties of the refractory metal carbide material produced. The glassy carbon preform is placed on a bed of refractory metal or refractory metal--silicon alloy. The pieces are heated above the melting point of the metal or alloy. The molten metal wicks inside the porous carbon preform and reacts, forming the refractory metal carbide or refractory metal carbide plus a minor secondary phase.

  13. Diffraction limited focusing and routing of gap plasmons by a metal-dielectric-metal lens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dennis, Brian S.; Czaplewski, David A.; Haftel, Michael I.; Lopez, Daniel; Blumberg, Girsh; Aksyuk, Vladimir

    2015-08-12

    Passive optical elements can play key roles in photonic applications such as plasmonic integrated circuits. Here we experimentally demonstrate passive gap-plasmon focusing and routing in two-dimensions. This is accomplished using a high numerical-aperture metal-dielectric-metal lens incorporated into a planar-waveguide device. Fabrication via metal sputtering, oxide deposition, electron- and focused-ion- beam lithography, and argon ion-milling is reported on in detail. Diffraction-limited focusing is optically characterized by sampling out-coupled light with a microscope. The measured focal distance and full-width-half-maximum spot size agree well with the calculated lens performance. The surface plasmon polariton propagation length is measured by sampling light from multiple out-couplermoreslits.less

  14. Epoxy bond and stop etch fabrication method

    DOE Patents [OSTI]

    Simmons, Jerry A.; Weckwerth, Mark V.; Baca, Wes E.

    2000-01-01

    A class of epoxy bond and stop etch (EBASE) microelectronic fabrication techniques is disclosed. The essence of such techniques is to grow circuit components on top of a stop etch layer grown on a first substrate. The first substrate and a host substrate are then bonded together so that the circuit components are attached to the host substrate by the bonding agent. The first substrate is then removed, e.g., by a chemical or physical etching process to which the stop etch layer is resistant. EBASE fabrication methods allow access to regions of a device structure which are usually blocked by the presence of a substrate, and are of particular utility in the fabrication of ultrafast electronic and optoelectronic devices and circuits.

  15. Method of fabricating a multilayer insulation blanket

    DOE Patents [OSTI]

    Gonczy, John D. (Oak Lawn, IL); Niemann, Ralph C. (Downers Grove, IL); Boroski, William N. (Aurora, IL)

    1993-01-01

    An improved multilayer insulation blanket for insulating cryogenic structures operating at very low temperatures is disclosed. An apparatus and method for fabricating the improved blanket are also disclosed. In the improved blanket, each successive layer of insulating material is greater in length and width than the preceding layer so as to accommodate thermal contraction of the layers closest to the cryogenic structure. The fabricating apparatus has a rotatable cylindrical mandrel having an outer surface of fixed radius that is substantially arcuate, preferably convex, in cross-section. The method of fabricating the improved blanket comprises (a) winding a continuous sheet of thermally reflective material around the circumference of the mandrel to form multiple layers, (b) binding the layers along two lines substantially parallel to the edges of the circumference of the mandrel, (c) cutting the layers along a line parallel to the axle of the mandrel, and (d) removing the bound layers from the mandrel.

  16. Multilayer insulation blanket, fabricating apparatus and method

    DOE Patents [OSTI]

    Gonczy, John D. (Oak Lawn, IL); Niemann, Ralph C. (Downers Grove, IL); Boroski, William N. (Aurora, IL)

    1992-01-01

    An improved multilayer insulation blanket for insulating cryogenic structures operating at very low temperatures is disclosed. An apparatus and method for fabricating the improved blanket are also disclosed. In the improved blanket, each successive layer of insulating material is greater in length and width than the preceding layer so as to accommodate thermal contraction of the layers closest to the cryogenic structure. The fabricating apparatus has a rotatable cylindrical mandrel having an outer surface of fixed radius that is substantially arcuate, preferably convex, in cross-section. The method of fabricating the improved blanket comprises (a) winding a continuous sheet of thermally reflective material around the circumference of the mandrel to form multiple layers, (b) binding the layers along two lines substantially parallel to the edges of the circumference of the mandrel, (c) cutting the layers along a line parallel to the axle of the mandrel, and (d) removing the bound layers from the mandrel.

  17. Method of fabricating a multilayer insulation blanket

    DOE Patents [OSTI]

    Gonczy, J.D.; Niemann, R.C.; Boroski, W.N.

    1993-07-06

    An improved multilayer insulation blanket for insulating cryogenic structures operating at very low temperatures is disclosed. An apparatus and method for fabricating the improved blanket are also disclosed. In the improved blanket, each successive layer of insulating material is greater in length and width than the preceding layer so as to accommodate thermal contraction of the layers closest to the cryogenic structure. The fabricating apparatus has a rotatable cylindrical mandrel having an outer surface of fixed radius that is substantially arcuate, preferably convex, in cross-section. The method of fabricating the improved blanket comprises (a) winding a continuous sheet of thermally reflective material around the circumference of the mandrel to form multiple layers, (b) binding the layers along two lines substantially parallel to the edges of the circumference of the mandrel, (c) cutting the layers along a line parallel to the axle of the mandrel, and (d) removing the bound layers from the mandrel.

  18. Multilayer insulation blanket, fabricating apparatus and method

    DOE Patents [OSTI]

    Gonczy, J.D.; Niemann, R.C.; Boroski, W.N.

    1992-09-01

    An improved multilayer insulation blanket for insulating cryogenic structures operating at very low temperatures is disclosed. An apparatus and method for fabricating the improved blanket are also disclosed. In the improved blanket, each successive layer of insulating material is greater in length and width than the preceding layer so as to accommodate thermal contraction of the layers closest to the cryogenic structure. The fabricating apparatus has a rotatable cylindrical mandrel having an outer surface of fixed radius that is substantially arcuate, preferably convex, in cross-section. The method of fabricating the improved blanket comprises (a) winding a continuous sheet of thermally reflective material around the circumference of the mandrel to form multiple layers, (b) binding the layers along two lines substantially parallel to the edges of the circumference of the mandrel, (c) cutting the layers along a line parallel to the axle of the mandrel, and (d) removing the bound layers from the mandrel. 7 figs.

  19. Career Map: Assembler and Fabricator | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assembler and Fabricator Career Map: Assembler and Fabricator A fabricator works at assembling a wind turbine blade. Assembler and Fabricator Position Title Assembler and Fabricator Alternate Title(s) Education & Training Level Bachelor's degree generally not expected. Education & Training Level Description The education level and qualifications needed to enter these jobs vary depending on the industry and employer. Although a high school diploma is enough for most jobs, experience and

  20. Radioactive scrap metal decontamination technology assessment report

    SciTech Connect (OSTI)

    Buckentin, J.M.; Damkroger, B.K.; Schlienger, M.E.

    1996-04-01

    Within the DOE complex there exists a tremendous quantity of radioactive scrap metal. As an example, it is estimated that within the gaseous diffusion plants there exists in excess of 700,000 tons of contaminated stainless steel. At present, valuable material is being disposed of when it could be converted into a high quality product. Liquid metal processing represents a true recycling opportunity for this material. By applying the primary production processes towards the material`s decontamination and re-use, the value of the strategic resource is maintained while drastically reducing the volume of material in need of burial. Potential processes for the liquid metal decontamination of radioactively contaminated metal are discussed and contrasted. Opportunities and technology development issues are identified and discussed. The processes compared are: surface decontamination; size reduction, packaging and burial; melting technologies; electric arc melting; plasma arc centrifugal treatment; air induction melting; vacuum induction melting; and vacuum induction melting and electroslag remelting.

  1. Method of handling radioactive alkali metal waste

    DOE Patents [OSTI]

    Wolson, Raymond D.; McPheeters, Charles C.

    1980-01-01

    Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.

  2. Method of handling radioactive alkali metal waste

    DOE Patents [OSTI]

    Wolson, R.D.; McPheeters, C.C.

    Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.

  3. Energy-beam-driven rapid fabrication system

    DOE Patents [OSTI]

    Keicher, David M.; Atwood, Clinton L.; Greene, Donald L.; Griffith, Michelle L.; Harwell, Lane D.; Jeantette, Francisco P.; Romero, Joseph A.; Schanwald, Lee P.; Schmale, David T.

    2002-01-01

    An energy beam driven rapid fabrication system, in which an energy beam strikes a growth surface to form a molten puddle thereon. Feed powder is then injected into the molten puddle from a converging flow of feed powder. A portion of the feed powder becomes incorporated into the molten puddle, forcing some of the puddle contents to freeze on the growth surface, thereby adding an additional layer of material. By scanning the energy beam and the converging flow of feed powder across the growth surface, complex three-dimensional shapes can be formed, ready or nearly ready for use. Nearly any class of material can be fabricated using this system.

  4. Simplified fabrication of magnetically coupled Josephson circuits

    SciTech Connect (OSTI)

    Smith, L.N.; Jillie, D.W.; Kroger, H.

    1985-03-01

    The authors describe a technique for fabricating magnetically coupled Josephson logic and memory circuits and SQUIDs which uses only two superconducting layers. These two layers perform multiple functions as the base and counterelectrodes of the tunnel junctions, the SQUID inductance and control lines, and the signal lines and groundplane between gates. This technique is illustrated by the specific example of a two junction, resistively damped SQUID designed to be fabricated using an all-refractory process which employs a total of five masking levels.

  5. An Overview of Current and Past W-UO[2] CERMET Fuel Fabrication Technology

    SciTech Connect (OSTI)

    Douglas E. Burkes; Daniel M. Wachs; James E. Werner; Steven D. Howe

    2007-06-01

    Studies dating back to the late 1940s performed by a number of different organizations and laboratories have established the major advantages of Nuclear Thermal Propulsion (NTP) systems, particularly for manned missions. A number of NTP projects have been initiated since this time; none have had any sustained fuel development work that appreciably contributed to fuel fabrication or performance data from this era. As interest in these missions returns and previous space nuclear power researchers begin to retire, fuel fabrication technologies must be revisited, so that established technologies can be transferred to young researchers seamlessly and updated, more advanced processes can be employed to develop successful NTP fuels. CERMET fuels, specifically W-UO2, are of particular interest to the next generation NTP plans since these fuels have shown significant advantages over other fuel types, such as relatively high burnup, no significant failures under severe transient conditions, capability of accommodating a large fission product inventory during irradiation and compatibility with flowing hot hydrogen. Examples of previous fabrication routes involved with CERMET fuels include hot isostatic pressing (HIPing) and press and sinter, whereas newer technologies, such as spark plasma sintering, combustion synthesis and microsphere fabrication might be well suited to produce high quality, effective fuel elements. These advanced technologies may address common issues with CERMET fuels, such as grain growth, ductile to brittle transition temperature and UO2 stoichiometry, more effectively than the commonly accepted ‘traditional’ fabrication routes. Bonding of fuel elements, especially if the fabrication process demands production of smaller element segments, must be investigated. Advanced brazing techniques and compounds are now available that could produce a higher quality bond segment with increased ease in joining. This paper will briefly address the history of

  6. PRODUCTION OF PURIFIED URANIUM

    DOE Patents [OSTI]

    Burris, L. Jr.; Knighton, J.B.; Feder, H.M.

    1960-01-26

    A pyrometallurgical method for processing nuclear reactor fuel elements containing uranium and fission products and for reducing uranium compound; to metallic uranium is reported. If the material proccssed is essentially metallic uranium, it is dissolved in zinc, the sulution is cooled to crystallize UZn/sub 9/ , and the UZn/sub 9/ is distilled to obtain uranium free of fission products. If the material processed is a uranium compound, the sollvent is an alloy of zinc and magnesium and the remaining steps are the same.

  7. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  8. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  9. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  10. Reduction of VOC emissions from metal dip coating applications -- Canam Steel Corporation Point of Rocks, MD case study

    SciTech Connect (OSTI)

    Monfet, J.P.

    1997-12-31

    The reduction of VOC emissions from metal dip coating applications is not an environmental constraint, it is an economic opportunity. This case study shows how the industry can reap economic benefits from VOC reductions while improving air quality. The Canam Steel Corporation plant located in Point of Rocks, MD operates dip tanks for primer application on fabricated steel joists and joist girders. This process is presently subject to a regulation that limits the paint VOC content to 3.5 pounds per gallon of coating less water. As a result of the high paint viscosity associated with that regulation, the paint thickness of the dipped steel is thicker than the customers` specifications. Most of the VOC emissions can therefore be associated with the excess of paint applied to the products rather than to the required thickness of the coating. The higher paint usage rate has more than environmental consequences, it increases the cost of the applied coating. The project is to reduce the paint usage by controlling the viscosity of the coating in the tank. Experimental results as well as actual mass balance calculations show that using a higher VOC content paint would reduce the overall VOC emissions. The author explained the project to the Maryland Department of the Environment (MDE) Air and Radiation Management Administration. First, the MDE agreed to develop a new RACT determination for fabricated steel dipping operations. The new regulation would limit the amount of VOC than can be emitted to dip coat a ton of fabricated steel. Second, the MDE agreed to allow experimentation of the higher VOC content paint as a pilot project for the new regulation. This paper demonstrates the need for a RACT determination specific to fabricated steel dipping operations.

  11. Use of triphenyl phosphate as risk mitigant for metal amide hydrogen storage materials

    DOE Patents [OSTI]

    Cortes-Concepcion, Jose A.; Anton, Donald L.

    2016-04-26

    A process in a resulting product of the process in which a hydrogen storage metal amide is modified by a ball milling process using an additive of TPP. The resulting product provides for a hydrogen storage metal amide having a coating that renders the hydrogen storage metal amide resistant to air, ambient moisture, and liquid water while improving useful hydrogen storage and release kinetics.

  12. Method of fabrication of anchored nanostructure materials

    SciTech Connect (OSTI)

    Seals, Roland D; Menchhofer, Paul A; Howe, Jane Y; Wang, Wei

    2013-11-26

    Methods for fabricating anchored nanostructure materials are described. The methods include heating a nano-catalyst under a protective atmosphere to a temperature ranging from about 450.degree. C. to about 1500.degree. C. and contacting the heated nano-catalysts with an organic vapor to affix carbon nanostructures to the nano-catalysts and form the anchored nanostructure material.

  13. Method to control artifacts of microstructural fabrication

    DOE Patents [OSTI]

    Shul, Randy J.; Willison, Christi G.; Schubert, W. Kent; Manginell, Ronald P.; Mitchell, Mary-Anne; Galambos, Paul C.

    2006-09-12

    New methods for fabrication of silicon microstructures have been developed. In these methods, an etching delay layer is deposited and patterned so as to provide differential control on the depth of features being etched into a substrate material. Compensation for etching-related structural artifacts can be accomplished by proper use of such an etching delay layer.

  14. Method of fabricating a solar cell

    DOE Patents [OSTI]

    Pass, Thomas; Rogers, Robert

    2014-02-25

    Methods of fabricating solar cells are described. A porous layer may be formed on a surface of a substrate, the porous layer including a plurality of particles and a plurality of voids. A solution may be dispensed into one or more regions of the porous layer to provide a patterned composite layer. The substrate may then be heated.

  15. Target fabrication for particle beam fusion

    SciTech Connect (OSTI)

    Bieg, K.W.; Chang, J.

    1980-01-01

    Near-term exploding pusher targets for electron or light ion beam driven fusion are typically several mm in diameter and have relatively thick shells (rho r approx. 0.001 to 0.03 gm/cm/sup 2/). Current fabrication techniques utilize parylene polymer coatings on leachable mandrels.

  16. Method of fabricating a solar cell

    DOE Patents [OSTI]

    Pass, Thomas; Rogers, Robert

    2016-02-16

    Methods of fabricating solar cells are described. A porous layer may be formed on a surface of a substrate, the porous layer including a plurality of particles and a plurality of voids. A solution may be dispensed into one or more regions of the porous layer to provide a patterned composite layer. The substrate may then be heated.

  17. Metal to semiconductor transition in metallic transition metal dichalcogenides

    SciTech Connect (OSTI)

    Li, Yan; Kang, Jun; Li, Jingbo; Tongay, Sefaattin; Wu, Junqiao; Yue, Qu

    2013-11-07

    We report on tuning the electronic and magnetic properties of metallic transition metal dichalcogenides (mTMDCs) by 2D to 1D size confinement. The stability of the mTMDC monolayers and nanoribbons is demonstrated by the larger binding energy compared to the experimentally available semiconducting TMDCs. The 2D MX{sub 2} (M?=?Nb, Ta; X?=?S, Se) monolayers are non-ferromagnetic metals and mechanically softer compared to their semiconducting TMDCs counterparts. Interestingly, mTMDCs undergo metal-to-semiconductor transition when the ribbon width approaches to ?13? and ?7? for zigzag and armchair edge terminations, respectively; then these ribbons convert back to metal when the ribbon widths further decrease. Zigzag terminated nanoribbons are ferromagnetic semiconductors, and their magnetic properties can also be tuned by hydrogen edge passivation, whereas the armchair nanoribbons are non-ferromagnetic semiconductors. Our results display that the mTMDCs offer a broad range of physical properties spanning from metallic to semiconducting and non-ferromagnetic to ferromagnetic that is ideal for applications where stable narrow bandgap semiconductors with different magnetic properties are desired.

  18. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P; Toops, Todd J; Tortorelli, Peter F; More, Karren Leslie; Meyer III, Harry M; Pihl, Josh A; Wang, Heli; Turner, John; Garzon, Fernando; Rockward, Tommy; Gervasio, Don; Rakowski, Jim; EstevezGenCell, Francisco

    2010-01-01

    Effort devoted to scale up and demonstration of thin stamped metallic bipolar plates. Overall goal is to demonstrate potential for metallic bipolar plates to meet 5000 h automotive durability goal at a cost of less than $5/kW.

  19. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E.; Lyons, James E.

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  20. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.