National Library of Energy BETA

Sample records for dry process electrode

  1. FINAL REPORT: Transformational electrode drying process

    SciTech Connect (OSTI)

    Claus Daniel, C.; Wixom, M.

    2013-12-19

    This report includes major findings and outlook from the transformational electrode drying project performance period from January 6, 2012 to August 1, 2012. Electrode drying before cell assembly is an operational bottleneck in battery manufacturing due to long drying times and batch processing. Water taken up during shipment and other manufacturing steps needs to be removed before final battery assembly. Conventional vacuum ovens are limited in drying speed due to a temperature threshold needed to avoid damaging polymer components in the composite electrode. Roll to roll operation and alternative treatments can increase the water desorption and removal rate without overheating and damaging other components in the composite electrode, thus considerably reducing drying time and energy use. The objective of this project was the development of an electrode drying procedure, and the demonstration of processes with no decrease in battery performance. The benchmark for all drying data was an 80°C vacuum furnace treatment with a residence time of 18 – 22 hours. This report demonstrates an alternative roll to roll drying process with a 500-fold improvement in drying time down to 2 minutes and consumption of only 30% of the energy compared to vacuum furnace treatment.

  2. Vehicle Technologies Office Merit Review 2015: Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dry process electrode...

  3. Vehicle Technologies Office Merit Review 2014: Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dry process electrode...

  4. Dry Process Electrode Fabrication | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Statistical Process Evaluation Volume 3 | Department of Energy Final Report: Drivers of Success in the Better Buildings Neighborhood Program - Statistical Process Evaluation Final Evaluation Volume 3, American Recovery and Reinvestment Act of 2009, June 2015. PDF icon Drivers of Success in BBNP -- Statistical Process Evaluation More Documents & Publications Process Evaluation of the Better Buildings Neighborhood Program, Final Evaluation Volume 4 Evaluation of the Better Buildings

  5. Vehicle Technologies Office Merit Review 2015: Advanced Drying Process for Lower Manufacturing Cost of Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Lambda Technologies at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced drying process...

  6. Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  7. Automated catalyst processing for cloud electrode fabrication for fuel cells

    DOE Patents [OSTI]

    Goller, Glen J.; Breault, Richard D.

    1980-01-01

    A process for making dry carbon/polytetrafluoroethylene floc material, particularly useful in the manufacture of fuel cell electrodes, comprises of the steps of floccing a co-suspension of carbon particles and polytetrafluoroethylene particles, filtering excess liquids from the co-suspension, molding pellet shapes from the remaining wet floc solids without using significant pressure during the molding, drying the wet floc pellet shapes within the mold at temperatures no greater than about 150.degree. F., and removing the dry pellets from the mold.

  8. Displaced electrode process for welding

    DOE Patents [OSTI]

    Heichel, L.J.

    1975-08-26

    A method is described for the butt-welding of a relatively heavy mass to a relatively small mass such as a thin-wall tube. In butt-welding heat is normally applied at the joint between the two pieces which are butt-welded together. The application of heat at the joint results in overheating the tube which causes thinning of the tube walls and porosity in the tube material. This is eliminated by displacing the welding electrode away from the seam toward the heavier mass so that heat is applied to the heavy mass and not at the butt seam. Examples of the parameters used in welding fuel rods are given. The cladding and end plugs were made of Zircalloy. The electrode used was of 2 percent thoriated tungsten. (auth)

  9. Dry Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    K. M. Goff; M. F. Simpson

    2009-09-01

    Dry (non-aqueous) separations technologies have been used for treatment of used nuclear fuel since the 1960s, and they are still being developed and demonstrated in many countries. Dry technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. Within the Department of Energys Advanced Fuel Cycle Initiative, an electrochemical process employing molten salts is being developed for recycle of fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. Much of the development of this technology is based on treatment of used Experimental Breeder Reactor II (EBR-II) fuel, which is metallic. Electrochemical treatment of the EBR-II fuel has been ongoing in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory since 1996. More than 3.8 metric tons of heavy metal of metallic fast reactor fuel have been treated using this technology. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including high-level waste work. A historic perspective on the background of dry processing will also be provided.

  10. Technical and economical considerations of new DRI melting process

    SciTech Connect (OSTI)

    Ito, Shuzo; Tokuda, Koji; Sammt, F.; Gray, R.

    1997-12-31

    The new DRI melting process can effectively and economically produce high quality molten iron. This process utilizes hot charging of DRI directly from a reduction furnace into a dedicated new melting furnace. The molten iron from this DRI premelter can be charged into a steelmaking furnace, such as an electric arc furnace (EAF), where the molten iron, together with other iron sources, can be processed to produce steel. Alternatively the molten iron can be pigged or granulated for off-site merchant sales. Comprehensive research and development of the new process has been conducted including operational process simulation, melting tests using FASTMET DRI, slag technology development, and refractory corrosion testing. This paper describes the process concept, its operational characteristics and further applications of the process.

  11. Exploring Competing Kinetic Processes in Quantum Dots Linked to Electrode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surfaces | MIT-Harvard Center for Excitonics Competing Kinetic Processes in Quantum Dots Linked to Electrode Surfaces March 14, 2012 at 2:30pm/4-349 Mark Hybertsen Brookhaven National Laboratory, Columbia University Mark_Hybertsen001_000 Abstract: Exploiting the unique properties of nanostructured chromophores for light harvesting applications relies on the balance between competing kinetic processes including energy transfer, carrier relaxation and carrier tunneling. In the first part of

  12. Process for fabricating ribbed electrode substrates and other articles

    DOE Patents [OSTI]

    Goller, Glen J.; Breault, Richard D.; Smith, J. Harold

    1984-01-01

    A process for fabricating a resin bonded carbon fiber article, and in particular electrochemical cell electrode substrates and the like requiring different mean pore sizes in different areas, involves simultaneously heating and compacting different mixtures of carbon fibers and resin in different areas of an article forming mold, wherein the carbon fibers in each of the different mixtures have different, known bulk densities. The different bulk densities of the carbon fibers in the mixtures are chosen to yield the desired mean pore sizes and other properties in the article after heating and compacting the mixtures. Preferably, the different bulk densities are obtained using different carbon fiber lengths in the molding mixtures. The process is well suited to forming ribbed electrode substrates with preselected optimum mean pore sizes, porosities, and densities in the ribs, the webs connecting the ribs, and in the edge seals.

  13. Single Step Electrode Infiltration Process - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Single Step Electrode Infiltration Process National Energy Technology Laboratory Contact NETL About This Technology Technology Marketing Summary Research is active on the patent pending technology titled, "Method of Forming Catalyst Layer by Single Step Infiltration." This invention is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology

  14. Physical processes involved in strip electrode welding using the method of slatted splicing

    SciTech Connect (OSTI)

    Bushma, V. O. [Moscow State Technological University 'Stankin' (Russian Federation)

    2010-12-15

    Physical processes that take place in a strip electrode during welding using the slatted splicing technique are considered. Flowing of the welding current in the electrode is shown to be the key process which determines electrode heating and melting. Technological receipts are proposed that allow obtaining high-quality welds by the method of slatted splicing.

  15. Mechanisms for charge-transfer processes at electrode/solid-electrolyt...

    Office of Scientific and Technical Information (OSTI)

    Mechanisms for charge-transfer processes at electrodesolid-electrolyte interfaces. Citation Details In-Document Search Title: Mechanisms for charge-transfer processes at electrode...

  16. Utilization of geothermal heat in tropical fruit-drying process

    SciTech Connect (OSTI)

    Chen, B.H.; Lopez, L.P.; King, R.; Fujii, J.; Tanaka, M.

    1982-10-01

    The power plant utilizes only the steam portion of the HGP-A well production. There are approximately 50,000 pounds per hour of 360/sup 0/F water produced (approximately 10 million Btu per hour) and the water is currently not used and is considered a waste. This tremendous resource could very well be used in applications such as food processing, food dehydration and other industrial processing that requires low-grade heat. One of the applications is examined, namely the drying of tropical fruits particularly the papaya. The papaya was chosen for the obvious reason that it is the biggest crop of all fruits produced on the Big Island. A conceptual design of a pilot plant facility capable of processing 1000 pounds of raw papaya per day is included. This facility is designed to provide a geothermally heated dryer to dehydrate papayas or other tropical fruits available on an experimental basis to obtain data such as drying time, optimum drying temperature, etc.

  17. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J.; Warner, Kathryn A.

    1999-01-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

  18. The hydro nuclear services dry active waste processing system

    SciTech Connect (OSTI)

    Bunker, A.S.

    1985-04-01

    There is a real need for a dry active waste processing system that can separate clean trash and recoverable items from radwaste safely and efficiently. This paper reports that Hydro Nuclear Services has produced just such a system and is marketing it as a DAW Segregation/Volume Reduction Process. The system is a unique, semi-automated package of sensitive monitoring instruments of volume reduction equipment that separates clean trash from contaminated and recoverable items in the waste stream and prepares the clean trash for unrestricted release. What makes the HNS system truly unique is its end product - clean trash.

  19. Aqueous processing of composite lithium ion electrode material

    DOE Patents [OSTI]

    Li, Jianlin; Armstrong, Beth L; Daniel, Claus; Wood, III, David L

    2015-02-17

    A method of making a battery electrode includes the steps of dispersing an active electrode material and a conductive additive in water with at least one dispersant to create a mixed dispersion; treating a surface of a current collector to raise the surface energy of the surface to at least the surface tension of the mixed dispersion; depositing the dispersed active electrode material and conductive additive on a current collector; and heating the coated surface to remove water from the coating.

  20. Roll-to-Roll Electrode Processing and Materials NDE for Advanced...

    Broader source: Energy.gov (indexed) [DOE]

    Lithium Secondary Batteries Vehicle Technologies Office Merit Review 2014: Roll-to-Roll Electrode Processing NDE for Advanced Lithium Secondary Batteries In-situ ...

  1. Energy-efficient regenerative liquid desiccant drying process

    DOE Patents [OSTI]

    Ko, Suk M.; Grodzka, Philomena G.; McCormick, Paul O.

    1980-01-01

    This invention relates to the use of desiccants in conjunction with an open oop drying cycle and a closed loop drying cycle to reclaim the energy expended in vaporizing moisture in harvested crops. In the closed loop cycle, the drying air is brought into contact with a desiccant after it exits the crop drying bin. Water vapor in the moist air is absorbed by the desiccant, thus reducing the relative humidity of the air. The air is then heated by the used desiccant and returned to the crop bin. During the open loop drying cycle the used desiccant is heated (either fossil or solar energy heat sources may be used) and regenerated at high temperature, driving water vapor from the desiccant. This water vapor is condensed and used to preheat the dilute (wet) desiccant before heat is added from the external source (fossil or solar). The latent heat of vaporization of the moisture removed from the desiccant is reclaimed in this manner. The sensible heat of the regenerated desiccant is utilized in the open loop drying cycle. Also, closed cycle operation implies that no net energy is expended in heating drying air.

  2. Mechanisms for charge-transfer processes at electrode/solid-electrolyte

    Office of Scientific and Technical Information (OSTI)

    interfaces. (Technical Report) | SciTech Connect Mechanisms for charge-transfer processes at electrode/solid-electrolyte interfaces. Citation Details In-Document Search Title: Mechanisms for charge-transfer processes at electrode/solid-electrolyte interfaces. This report summarizes the accomplishments of a Laboratory-Directed Research and Development (LDRD) project focused on developing and applying new x-ray spectroscopies to understand and improve electric charge transfer in

  3. Roll-to-Roll Electrode Processing and Materials NDE for Advanced Lithium

    Broader source: Energy.gov (indexed) [DOE]

    Secondary Batteries | Department of Energy 12 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es165_wood_2012_o.pdf More Documents & Publications Roll-to-Roll Electrode Processing and Materials NDE for Advanced Lithium Secondary Batteries Vehicle Technologies Office Merit Review 2014: Roll-to-Roll Electrode Processing NDE for Advanced Lithium Secondary Batteries In-situ characterization and diagnostics of

  4. Process and composition for drying of gaseous hydrogen halides

    DOE Patents [OSTI]

    Tom, Glenn M.; Brown, Duncan W.

    1989-08-01

    A process for drying a gaseous hydrogen halide of the formula HX, wherein X is selected from the group consisting of bromine, chlorine, fluorine, and iodine, to remove water impurity therefrom, comprising: contacting the water impurity-containing gaseous hydrogen halide with a scavenger including a support having associated therewith one or more members of the group consisting of: (a) an active scavenging moiety selected from one or more members of the group consisting of: (i) metal halide compounds dispersed in the support, of the formula MX.sub.y ; and (ii) metal halide pendant functional groups of the formula -MX.sub.y-1 covalently bonded to the support, wherein M is a y-valent metal, and y is an integer whose value is from 1 to 3; (b) corresponding partially or fully alkylated compounds and/or pendant functional groups, of the metal halide compounds and/or pendant functional groups of (a); wherein the alkylated compounds and/or pendant functional groups, when present, are reactive with the gaseous hydrogen halide to form the corresponding halide compounds and/or pendant functional groups of (a); and M being selected such that the heat of formation, .DELTA.H.sub.f of its hydrated halide, MX.sub.y.(H.sub.2 O).sub.n, is governed by the relationship: .DELTA.H.sub.f .gtoreq.n.times.10.1 kilocalories/mole of such hydrated halide compound wherein n is the number of water molecules bound to the metal halide in the metal halide hydrate. Also disclosed is an appertaining scavenger composition and a contacting apparatus wherein the scavenger is deployed in a bed for contacting with the water impurity-containing gaseous hydrogen halide.

  5. Modified dry limestone process for control of sulfur dioxide emissions

    DOE Patents [OSTI]

    Shale, Correll C.; Cross, William G.

    1976-08-24

    A method and apparatus for removing sulfur oxides from flue gas comprise cooling and conditioning the hot flue gas to increase the degree of water vapor saturation prior to passage through a bed of substantially dry carbonate chips or lumps, e.g., crushed limestone. The reaction products form as a thick layer of sulfites and sulfates on the surface of the chips which is easily removed by agitation to restore the reactive surface of the chips.

  6. Process and apparatus for indirect-fired heating and drying

    DOE Patents [OSTI]

    Abbasi, Hamid Ali; Chudnovsky, Yaroslav

    2005-04-12

    A method for heating flat or curved surfaces comprising injecting fuel and oxidant along the length, width or longitudinal side of a combustion space formed between two flat or curved plates, transferring heat from the combustion products via convection and radiation to the surface being heated on to the material being dried/heated, and recirculating at least 20% of the combustion products to the root of the flame.

  7. Process for producing elements from a fused bath using a metal strap and ceramic electrode body nonconsumable electrode assembly

    DOE Patents [OSTI]

    Byrne, Stephen C.

    1984-01-01

    A nonconsumable electrode assembly suitable for use in the production of metal by electrolytic reduction of a metal compound dissolved in a molten salt, the assembly comprising a ceramic electrode body and a metal subassembly of a metal conductor rod and at least one metal strap affixed to an end of the rod with opposing portions extending radially outwardly from the rod axis and having the ends of the strap attached to the electrode body.

  8. Process for producing elements from a fused bath using a metal strap and ceramic electrode body nonconsumable electrode assembly

    DOE Patents [OSTI]

    Byrne, S.C.

    1984-07-03

    A nonconsumable electrode assembly is described suitable for use in the production of metal by electrolytic reduction of a metal compound dissolved in a molten salt, the assembly comprising a ceramic electrode body and a metal subassembly of a metal conductor rod and at least one metal strap affixed to an end of the rod with opposing portions extending radially outwardly from the rod axis and having the ends of the strap attached to the electrode body. 7 figs.

  9. Electrowinning process with electrode compartment to avoid contamination of electrolyte

    DOE Patents [OSTI]

    Poa, Davis S.; Pierce, R. Dean; Mulcahey, Thomas P.; Johnson, Gerald K.

    1993-01-01

    An electrolytic process and apparatus for reducing calcium oxide in a molten electrolyte of CaCl.sub.2 -CaF.sub.2 with a graphite anode in which particles or other contamination from the anode is restricted by the use of a porous barrier in the form of a basket surrounding the anode which may be removed from the electrolyte to burn the graphite particles, and wherein the calcium oxide feed is introduced to the anode compartment to increase the oxygen ion concentration at the anode.

  10. Sandwich-type electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P.; Garcia, Earl R.

    1983-01-01

    Disclosed is an improvement on a method of making an electrode wherein a suspension in a liquid is prepared of a powdered catalyst containing a noble metal, carbon powder and a binder, and the suspension is poured over a carbon substrate dried, compressed and sintered to form a solid catalyst layer bonded to the carbon substrate. The improvement is placing a carbon paper on the catalyst layer prior to compressing. The improved electrode can be used as either a cathode or an anode in a sulfur dioxide depolarized electrolyzer in a process for producing hydrogen from water.

  11. Doping suppression and mobility enhancement of graphene transistors fabricated using an adhesion promoting dry transfer process

    SciTech Connect (OSTI)

    Cheol Shin, Woo; Hun Mun, Jeong; Yong Kim, Taek; Choi, Sung-Yool; Jin Cho, Byung E-mail: tskim1@kaist.ac.kr; Yoon, Taeshik; Kim, Taek-Soo E-mail: tskim1@kaist.ac.kr

    2013-12-09

    We present the facile dry transfer of graphene synthesized via chemical vapor deposition on copper film to a functional device substrate. High quality uniform dry transfer of graphene to oxidized silicon substrate was achieved by exploiting the beneficial features of a poly(4-vinylphenol) adhesive layer involving a strong adhesion energy to graphene and negligible influence on the electronic and structural properties of graphene. The graphene field effect transistors (FETs) fabricated using the dry transfer process exhibit excellent electrical performance in terms of high FET mobility and low intrinsic doping level, which proves the feasibility of our approach in graphene-based nanoelectronics.

  12. The use of carbon aerogel electrodes for deionizing water and treating aqueous process wastes

    SciTech Connect (OSTI)

    Farmer, J.C.; Mack, G.V.; Fix, D.V.

    1996-07-01

    A wide variety of ionic contaminants can be removed from aqueous solutions by electrosorption on carbon aerogel electrodes. Carbon aerogel is an ideal electrode material because of its low electrical resistivity (< 40 m{Omega}-cm), high specific surface area (400 to 1100 m{sup 2}/g), and controllable pore size distribution (< 50 nm). This approach may avoid the generation of a substantial amount of secondary waste associated with ion exchange processing. Ion exchange resins require concentrated solutions of acid, base, or salt for regeneration, whereas carbon aerogel electrodes require only electrical discharge or reverse polarization. Aqueous solutions of NaCl, NaNO{sub 3}, NH{sub 4}ClO{sub 4}, Na{sub 2}CO{sub 3}, Na{sub 2}SO{sub 4} and Na{sub 3}PO{sub 4} have been separated into concentrate and high-purity product streams. The deionization of a 100 {mu}S/cm NaCl solution with two parallel stacks of carbon aerogel electrodes in a potential-swing mode is discussed in detail. The selective removal of Cu, Zn, Cd, Pb, Cr, Mn, Co and U from a variety of process solutions and natural waters has also been demonstrated. Feasibility tests indicate that the remediation of Cr(VI)-contaminated ground water may be possible.

  13. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Barbour, F.A.; Turner, T.F.; Kang, T.W.; Berggren, M.H.; Hogsett, R.F.; Jha, M.C.

    1990-02-01

    The objective of this research project was to demonstrate a technically feasible and economically viable process for drying and stabilizing high-moisture subbituminous coal. Controlled thermal drying of coal fines was achieved using the inclined fluidized-bed drying and stabilization process developed by the Western Research Institute. The project scope of work required completion of five tasks: (1) project planning, (2) characterization of two feed coals, (3) bench-scale inclined fluidized-bed drying studies, (4) product characterization and testing, and (5) technical and economic evaluation of the process. High moisture subbituminous coals from AMAX Eagle Butte mine located in the Powder River Basin of Wyoming and from Usibelli Coal Mine, Inc. in Healy, Alaska were tested in a 10-lb/hr bench-scale inclined fluidized-bed. Experimental results show that the dried coal contains less than 1.5% moisture and has a heating value over 11,500 Btu/lb. The coal fines entrainment can be kept below 15 wt % of the feed. The equilibrium moisture of dried coal was less than 50% of feed coal equilibrium moisture. 7 refs., 60 figs., 47 tabs.

  14. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Warner, K.A.

    1999-06-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

  15. Microfluidic electrochemical device and process for chemical imaging and electrochemical analysis at the electrode-liquid interface in-situ

    DOE Patents [OSTI]

    Yu, Xiao-Ying; Liu, Bingwen; Yang, Li; Zhu, Zihua; Marshall, Matthew J.

    2016-03-01

    A microfluidic electrochemical device and process are detailed that provide chemical imaging and electrochemical analysis under vacuum at the surface of the electrode-sample or electrode-liquid interface in-situ. The electrochemical device allows investigation of various surface layers including diffuse layers at selected depths populated with, e.g., adsorbed molecules in which chemical transformation in electrolyte solutions occurs.

  16. Drying '84

    SciTech Connect (OSTI)

    Baunack, F.

    1984-01-01

    This book covers the following topics: mechanism of water sorption-desorption in polymers; progress in freeze drying; on drying of materials in through circulation system; safety aspects of spray drying; dewatering process enhanced by electroosmosis; pressure drop and particle circulation studies in modified slot spouted beds; and experience in drying coal slurries.

  17. Development of an advanced process for drying fine coal in an inclined fluidized bed

    SciTech Connect (OSTI)

    Boysen, J.E.; Kang, T.W.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.; AMAX Research and Development Center, Golden, CO )

    1989-10-01

    The main objective of this research is to develop a thermal process for drying fine coal that (1) reduces explosion potential, (2) uses a fluidized bed with minimum elutriation, (3) produces a stable dry coal by preventing moisture reabsorption and autogeneous heating, (4) reduces fugitive dust emissions, and (5) is technically and economically feasible. The project scope of work requires completion of five tasks: (1) project planning, (2) characterization of the two feed coals, (3) bench-scale IFB drying studies, (4) product characterization and testing, and (5) technical and economic process evaluation. The project technical achievements are primarily related to understanding of the behavior of the two coals in the IFB reactor. Solids residence time and solids entrainment can be correlated using the Reynolds number. Gas produced from the coal during drying and the product composition can be correlated to the average dryer temperature. A dry product with minimal proximate moisture and substantially increased heating value can be produced from either of these coals under a wide variety of fluidizing gas-to-solids ratios and IFB operating temperatures. Product characterization indicates that moisture reabsorption can be significantly reduced and that fugitive dust contents can be almost completely reduced. 4 refs., 19 figs., 24 tabs.

  18. Mechanisms of dry SO/sub 2/ control processes. Final report Sep 80-Sep 81

    SciTech Connect (OSTI)

    Apple, C.; Kelly, M.E.

    1982-04-01

    The report discusses physical and chemical processes and reaction mechanisms for lime spray drying and dry injection of sodium compounds in dry flue gas desulfurization (FGD) processes. It includes: chemical reactions, physical changes, proposed reaction mechanisms and mathematical models, process parameters affecting reactions and their rates, and data needed to verify proposed reaction mechanisms and models. Published technical papers were the primary reference sources. The report focuses on coal-fired boiler dry FGD applications. Lime spray drying reactions are primarily gas/liquid-phase reactions, with SO/sub 2/ removal depending on moisture in the lime slurry droplet. Initially, the moisture content is high, and the reaction rate is controlled by diffusion of SO/sub 2/ to the droplet surface; most SO/sub 2/ removal occurs during this phase. As evaporation reduces the moisture, the dissolution of Ca(OH)/sub 2/ into ions limits the SO/sub 2/ removal rate. Later, the precipitation of CaSO/sub 3/.1/2 H/sub 2/O onto the surface of the lime particles retards diffusion of SO/sub 2/ to the unreacted sorbent. Injecting sodium compound powders into flue gas removes SO/sub 2/ via gas/solid reactions. First, NaHCO/sub 3/ is thermally decomposed to Na/sub 2/CO/sub 3/ (small pores in the sorbent particles increase the particles' surface area and reactivity). Then the SO/sub 2/ reacts with Na/sub 2/CO/sub 3/ to form Na/sub 2/SO/sub 3/, starting at the particle surface.

  19. Sensitivity analysis of a dry-processed Candu fuel pellet's design parameters

    SciTech Connect (OSTI)

    Choi, Hangbok; Ryu, Ho Jin

    2007-07-01

    Sensitivity analysis was carried out in order to investigate the effect of a fuel pellet's design parameters on the performance of a dry-processed Canada deuterium uranium (CANDU) fuel and to suggest the optimum design modifications. Under a normal operating condition, a dry-processed fuel has a higher internal pressure and plastic strain due to a higher fuel centerline temperature when compared with a standard natural uranium CANDU fuel. Under a condition that the fuel bundle dimensions do not change, sensitivity calculations were performed on a fuel's design parameters such as the axial gap, dish depth, gap clearance and plenum volume. The results showed that the internal pressure and plastic strain of the cladding were most effectively reduced if a fuel's element plenum volume was increased. More specifically, the internal pressure and plastic strain of the dry-processed fuel satisfied the design limits of a standard CANDU fuel when the plenum volume was increased by one half a pellet, 0.5 mm{sup 3}/K. (authors)

  20. Method of drying passivated micromachines by dewetting from a liquid-based process

    DOE Patents [OSTI]

    Houston, Michael R.; Howe, Roger T.; Maboudian, Roya; Srinivasan, Uthara

    2000-01-01

    A method of fabricating a micromachine includes the step of constructing a low surface energy film on the micromachine. The micromachine is then rinsed with a rinse liquid that has a high surface energy, relative to the low surface energy film, to produce a contact angle of greater than 90.degree. between the low surface energy film and the rinse liquid. This relatively large contact angle causes any rinse liquid on the micromachine to be displaced from the micromachine when the micromachine is removed from the rinse liquid. In other words, the micromachine is dried by dewetting from a liquid-based process. Thus, a separate evaporative drying step is not required, as the micromachine is removed from the liquid-based process in a dry state. The relatively large contact angle also operates to prevent attractive capillary forces between micromachine components, thereby preventing contact and adhesion between adjacent microstructure surfaces. The low surface energy film may be constructed with a fluorinated self-assembled monolayer film. The processing of the invention avoids the use of environmentally harmful, health-hazardous chemicals.

  1. Method for processing aluminum spent potliner in a graphite electrode ARC furnace

    DOE Patents [OSTI]

    O'Connor, William K.; Turner, Paul C.; Addison, Gerald W.

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spent aluminum pot liner is crushed iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine and CO.

  2. Method for processing aluminum spent potliner in a graphite electrode arc furnace

    DOE Patents [OSTI]

    O'Connor, William K.; Turner, Paul C.; Addison, G.W.

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spend aluminum pot liner is crushed, iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine, and CO.

  3. Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process

    DOE Patents [OSTI]

    Balachandran, Uthamalingam

    1996-01-01

    A process for the preparation of amorphous precursor powders for Pb-doped Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x (2223) includes a freeze-drying process incorporating a splat-freezing step. The process generally includes splat freezing a nitrate solution of Bi, Pb, Sr, Ca, and Cu to form flakes of the solution without any phase separation; grinding the frozen flakes to form a powder; freeze-drying the frozen powder; heating the dried powder to form a dry green precursor powders; denitrating the green-powders; heating the denitrated powders to form phase-clean Bi-2223 powders. The grain boundaries of the 2223 grains appear to be clean, leading to good intergrain contact between 2223 grains.

  4. Rapid formation of phase-clean 110 K (Bi-2223) powders derived via freeze-drying process

    DOE Patents [OSTI]

    Balachandran, U.

    1996-06-04

    A process for the preparation of amorphous precursor powders for Pb-doped Bi{sub 2}Sr{sub 2} Ca{sub 2}Cu{sub 3}O{sub x} (2223) includes a freeze-drying process incorporating a splat-freezing step. The process generally includes splat freezing a nitrate solution of Bi, Pb, Sr, Ca, and Cu to form flakes of the solution without any phase separation; grinding the frozen flakes to form a powder; freeze-drying the frozen powder; heating the dried powder to form a dry green precursor powders; denitrating the green-powders; heating the denitrated powders to form phase-clean Bi-2223 powders. The grain boundaries of the 2223 grains appear to be clean, leading to good intergrain contact between 2223 grains. 11 figs.

  5. Preparation of polyaniline/sodium alanate hybrid using a spray-drying process

    SciTech Connect (OSTI)

    Moreira, B. R. E-mail: fabiopassador@gmail.com Passador, F. R. E-mail: fabiopassador@gmail.com Pessan, L. A. E-mail: fabiopassador@gmail.com

    2014-05-15

    Nowadays, hydrogen is highly interesting as an energy source, in particular in the automotive field. In fact, hydrogen is attractive as a fuel because it prevents air pollution and greenhouse emissions. One of the main problems with the utilization of hydrogen as a fuel is its on-board storage. The purpouse of this work was to develop a new hybrid material consisting of a polyaniline matrix with sodium alanate (NaAlH{sub 4}) using a spray-drying process. The polyaniline used for this experiment was synthesized by following a well-established method for the synthesis of the emeraldine base form of polyaniline using dodecylbenzenesulfonic acid as dopant. Micro particles of polyaniline/sodium alanate hybrids with 30 and 50 wt% of sodium alanate were prepared by using a spray-drying technique. Dilute solutions of polyaniline/sodium alanate were first prepared, 10g of the solid materials were mixed with 350 ml of toluene under stirring at room temperature for 24h and the solutions were dried using spray-dryer (Bchi, Switzerland) with 115C of an inlet temperature. The hybrids were analyzed by differential scanning calorimetry, FT-IR and scanning electron microscopy (SEM). The addition of sodium alanate decreased the glass transition temperature of the hybrids when compared to neat polyaniline. FT-IR spectrum analysis was performed to identify the bonding environment of the synthesized material and was observed that simply physically mixture occurred between polyaniline and sodium alanate. The SEM images of the hybrids showed the formation of microspheres with sodium alanate dispersed in the polymer matrix.

  6. Method of fabrication of electrodes and electrolytes

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.

    2004-01-06

    Fuel cell stacks contain an electrolyte layer surrounded on top and bottom by an electrode layer. Porous electrodes are prepared which enable fuel and oxidant to easily flow to the respective electrode-electrolyte interface without the need for high temperatures or pressures to assist the flow. Rigid, inert microspheres in combination with thin-film metal deposition techniques are used to fabricate porous anodes, cathodes, and electrolytes. Microshperes contained in a liquid are randomly dispersed onto a host structure and dried such that the microsperes remain in position. A thin-film deposition technique is subsequently employed to deposit a metal layer onto the microsperes. After such metal layer deposition, the microspheres are removed leaving voids, i.e. pores, in the metal layer, thus forming a porous electrode. Successive repetitions of the fabrication process result in the formation of a continuous fuel cell stack. Such stacks may produce power outputs ranging from about 0.1 Watt to about 50 Watts.

  7. Efficient process for previous metal recovery from cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence; Matlin, Ramail; Heinz, Robert

    2010-05-04

    A method is provided for recovering a catalytic element from a fuel cell membrane electrode assembly. The method includes grinding the membrane electrode assembly into a powder, extracting the catalytic element by forming a slurry comprising the powder and an acid leachate adapted to dissolve the catalytic element into a soluble salt, and separating the slurry into a depleted powder and a supernatant containing the catalytic element salt. The depleted powder is washed to remove any catalytic element salt retained within pores in the depleted powder and the catalytic element is purified from the salt.

  8. Simplified process for leaching precious metals from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence; Matlin, Ramail

    2009-12-22

    The membrane electrode assemblies of fuel cells are recycled to recover the catalyst precious metals from the assemblies. The assemblies are cryogenically embrittled and pulverized to form a powder. The pulverized assemblies are then mixed with a surfactant to form a paste which is contacted with an acid solution to leach precious metals from the pulverized membranes.

  9. Electrically conductive diamond electrodes

    DOE Patents [OSTI]

    Swain, Greg; Fischer, Anne ,; Bennett, Jason; Lowe, Michael

    2009-05-19

    An electrically conductive diamond electrode and process for preparation thereof is described. The electrode comprises diamond particles coated with electrically conductive doped diamond preferably by chemical vapor deposition which are held together with a binder. The electrodes are useful for oxidation reduction in gas, such as hydrogen generation by electrolysis.

  10. Fuel cell electrodes

    DOE Patents [OSTI]

    Strmcnik, Dusan; Cuesta, Angel; Stamenkovic, Vojislav; Markovic, Nenad

    2015-06-23

    A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.

  11. Process for recycling components of a PEM fuel cell membrane electrode assembly

    DOE Patents [OSTI]

    Shore, Lawrence

    2012-02-28

    The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.

  12. Production and Characterization of Atomized U-Mo Powder by the Rotating Electrode Process

    SciTech Connect (OSTI)

    C.R. Clark; B.R. Muntifering; J.F. Jue

    2007-09-01

    In order to produce feedstock fuel powder for irradiation testing, the Idaho National Laboratory has produced a rotating electrode type atomizer to fabricate uranium-molybdenum alloy fuel. Operating with the appropriate parameters, this laboratory-scale atomizer produces fuel in the desired size range for the RERTR dispersion experiments. Analysis of the powder shows a homogenous, rapidly solidified microstructure with fine equiaxed grains. This powder has been used to produce irradiation experiments to further test adjusted matrix U-Mo dispersion fuel.

  13. Initial evaluation of dry storage issues for spent nuclear fuels in wet storage at the Idaho Chemical Processing Plant

    SciTech Connect (OSTI)

    Guenther, R.J.; Johnson, A.B. Jr.; Lund, A.L.; Gilbert, E.R.

    1996-07-01

    The Pacific Northwest Laboratory has evaluated the basis for moving selected spent nuclear fuels in the CPP-603 and CPP-666 storage pools at the Idaho Chemical Processing Plant from wet to dry interim storage. This work is being conducted for the Lockheed Idaho Technologies Company as part of the effort to determine appropriate conditioning and dry storage requirements for these fuels. These spent fuels are from 22 test reactors and include elements clad with aluminum or stainless steel and a wide variety of fuel materials: UAl{sub x}, UAl{sub x}-Al and U{sub 3}O{sub 8}-Al cermets, U-5% fissium, UMo, UZrH{sub x}, UErZrH, UO{sub 2}-stainless steel cermet, and U{sub 3}O{sub 8}-stainless steel cermet. The study also included declad uranium-zirconium hydride spent fuel stored in the CPP-603 storage pools. The current condition and potential failure mechanisms for these spent fuels were evaluated to determine the impact on conditioning and dry storage requirements. Initial recommendations for conditioning and dry storage requirements are made based on the potential degradation mechanisms and their impacts on moving the spent fuel from wet to dry storage. Areas needing further evaluation are identified.

  14. Evaluation of a dry process for conversion of U-AVLIS product to UF{sub 6}. Milestone U361

    SciTech Connect (OSTI)

    1992-05-01

    A technical and engineering evaluation has been completed for a dry UF{sub 6} production system to convert the product of an initial two-line U-AVLIS plant. The objective of the study has been to develop a better understanding of process design requirements, capital and operating costs, and demonstration requirements for this alternate process. This report summarizes the results of the study and presents various comparisons between the baseline and alternate processes, building on the information contained in UF{sub 6} Product Alternatives Review Committee -- Final Report. It also provides additional information on flowsheet variations for the dry route which may warrant further consideration. The information developed by this study and conceptual design information for the baseline process will be combined with information to be developed by the U-AVLIS program and by industrial participants over the next twelve months to permit a further comparison of the baseline and alternate processes in terms of cost, risk, and compatibility with U-AVLIS deployment schedules and strategies. This comparative information will be used to make a final process flowsheet selection for the initial U-AVLIS plant by March 1993. The process studied is the alternate UF{sub 6} production flowsheet. Process steps are (1) electron-beam distillation to reduce enriched product iron content from about 10 wt % or less, (2) hydrofluorination of the metal to UF{sub 4}, (3) fluorination of UF{sub 4} to UF{sub 6}, (4) cold trap collection of the UF{sub 6} product, (5) UF{sub 6} purification by distillation, and (6) final blending and packaging of the purified UF{sub 6} in cylinders. A preliminary system design has been prepared for the dry UF{sub 6} production process based on currently available technical information. For some process steps, such information is quite limited. Comparisons have been made between this alternate process and the baseline plant process for UF{sub 6} production.

  15. New Electrode Manufacturing Process Equipment: Novel High Energy Density Lithium-Ion Cell Designs via Innovative Manufacturing Process Modules for Cathode and Integrated Separator

    SciTech Connect (OSTI)

    2010-07-01

    BEEST Project: Applied Materials is developing new tools for manufacturing Li-Ion batteries that could dramatically increase their performance. Traditionally, the positive and negative terminals of Li-Ion batteries are mixed with glue-like materials called binders, pressed onto electrodes, and then physically kept apart by winding a polymer mesh material between them called a separator. With the Applied Materials system, many of these manually intensive processes will be replaced by next generation coating technology to apply each component. This process will improve product reliability and performance of the cells at a fraction of the current cost. These novel manufacturing techniques will also increase the energy density of the battery and reduce the size of several of the batterys components to free up more space within the cell for storage.

  16. Dry sample storage system for an analytical laboratory supporting plutonium processing

    SciTech Connect (OSTI)

    Treibs, H.A.; Hartenstein, S.D.; Griebenow, B.L.; Wade, M.A.

    1990-07-25

    The Special Isotope Separation (SIS) plant is designed to provide removal of undesirable isotopes in fuel grade plutonium by the atomic vapor laser isotope separation (AVLIS) process. The AVLIS process involves evaporation of plutonium metal, and passage of an intense beam of light from a laser through the plutonium vapor. The laser beam consists of several discrete wavelengths, tuned to the precise wavelength required to ionize the undesired isotopes. These ions are attracted to charged plates, leaving the bulk of the plutonium vapor enriched in the desired isotopes to be collected on a cold plate. Major portions of the process consist of pyrochemical processes, including direct reduction of the plutonium oxide feed material with calcium metal, and aqueous processes for purification of plutonium in residues. The analytical laboratory for the plant is called the Material and Process Control Laboratory (MPCL), and provides for the analysis of solid and liquid process samples.

  17. Methods for and products of processing nanostructure nitride, carbonitride and oxycarbonitride electrode power materials by utilizing sol gel technology for supercapacitor applications

    DOE Patents [OSTI]

    Huang, Yuhong; Wei, Oiang; Chu, Chung-tse; Zheng, Haixing

    2001-01-01

    Metal nitride, carbonitride, and oxycarbonitride powder with high surface area (up to 150 m.sup.2 /g) is prepared by using sol-gel process. The metal organic precursor, alkoxides or amides, is synthesized firstly. The metal organic precursor is modified by using unhydrolyzable organic ligands or templates. A wet gel is formed then by hydrolysis and condensation process. The solvent in the wet gel is then be removed supercritically to form porous amorphous hydroxide. This porous hydroxide materials is sintered to 725.degree. C. under the ammonia flow and porous nitride powder is formed. The other way to obtain high surface area nitride, carbonitride, and oxycarbonitride powder is to pyrolyze polymerized templated metal amides aerogel in an inert atmosphere. The electrochemical capacitors are prepared by using sol-gel prepared nitride, carbonitride, and oxycarbonitride powder. Two methods are used to assemble the capacitors. Electrode is formed either by pressing the mixture of nitride powder and binder to a foil, or by depositing electrode coating onto metal current collector. The binder or coating is converted into a continuous network of electrode material after thermal treatment to provide enhanced energy and power density. Liquid electrolyte is soaked into porous electrode. The electrochemical capacitor assembly further has a porous separator layer between two electrodes/electrolyte and forming a unit cell.

  18. Electrode compositions

    DOE Patents [OSTI]

    Block, Jacob (Rockville, MD); Fan, Xiyun (Orange, TX)

    1998-01-01

    An electrode composition for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C.sub.8 -C.sub.15 alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5-4.5 volts.

  19. Electrode compositions

    DOE Patents [OSTI]

    Block, J.; Fan, X.

    1998-10-27

    An electrode composition is described for use as an electrode in a non-aqueous battery system. The electrode composition contains an electrically active powder in a solid polymer and, as a dispersant, a C{sub 8}-C{sub 15} alkyl capped oligomer of a hexanoic acid that is electrochemically inert at 2.5--4.5 volts.

  20. Magnetohydrodynamic electrode

    DOE Patents [OSTI]

    Boquist, Carl W.; Marchant, David D.

    1978-01-01

    A ceramic-metal composite suitable for use in a high-temperature environment consists of a refractory ceramic matrix containing 10 to 50 volume percent of a continuous high-temperature metal reinforcement. In a specific application of the composite, as an electrode in a magnetohydrodynamic generator, the one surface of the electrode which contacts the MHD fluid may have a layer of varying thickness of nonreinforced refractory ceramic for electrode temperature control. The side walls of the electrode may be coated with a refractory ceramic insulator. Also described is an electrode-insulator system for a MHD channel.

  1. Surface modification of active material structures in battery electrodes

    DOE Patents [OSTI]

    Erickson, Michael; Tikhonov, Konstantin

    2016-02-02

    Provided herein are methods of processing electrode active material structures for use in electrochemical cells or, more specifically, methods of forming surface layers on these structures. The structures are combined with a liquid to form a mixture. The mixture includes a surface reagent that chemically reacts and forms a surface layer covalently bound to the structures. The surface reagent may be a part of the initial liquid or added to the mixture after the liquid is combined with the structures. In some embodiments, the mixture may be processed to form a powder containing the structures with the surface layer thereon. Alternatively, the mixture may be deposited onto a current collecting substrate and dried to form an electrode layer. Furthermore, the liquid may be an electrolyte containing the surface reagent and a salt. The liquid soaks the previously arranged electrodes in order to contact the structures with the surface reagent.

  2. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  3. Investigation on the Charging Process of Li2O2-Based Air Electrodes in Li-O2 Batteries with Organic Carbonate Electrolytes

    SciTech Connect (OSTI)

    Xu, Wu; Viswanathan, Vilayanur V.; Wang, Deyu; Towne, Silas A.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Zhang, Jiguang

    2011-04-15

    The charge processes of Li-O2 batteries were investigated by analyzing the gas evolution by in situ gas chromatography-mass spectroscopy (GC/MS) technique. The mixture of Li2O2/Fe3O4/Super P carbon/polyvinylidene fluoride (PVDF) was used as the starting air electrode material and 1M LiTFSI in carbonate-based solvents was used as electrolyte. It was found that Li2O2 is reactive to 1-methyl-2-pyrrolidinone and PVDF binder used in the electrode preparation. During the 1st charge (up to 4.6 V), O2 was the main component in the gases released. The amount of O2 measured by GC/MS was consistent with the amount of Li2O2 decomposed in the electrochemical process as measured by the charge capacity, indicative of the good chargeability of Li2O2. However, after the cell was discharged to 2.0 V in O2 atmosphere and re-charged to ~ 4.6 V in the second cycle, CO2 was dominant in the released gases. Further analysis of the discharged air electrode by X-ray diffraction and Fourier transform infrared spectroscopy indicated that lithium-containing carbonate species (lithium alkyl carbonate and/or Li2CO3) were the main reaction products. Therefore, compatible electrolyte and electrodes as well as the electrode preparation procedures need to be developed for long term operation of rechargeable Li-O2 or Li-air batteries.

  4. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  5. Electrode films of porous agarose: The effects of physical structure on electron transport processes. [Impregnated with Nafion; immobilized electroactive species

    SciTech Connect (OSTI)

    Moran, K.D.

    1988-02-01

    Potential use of chemically modified electrodes in electrocatalysis has stimulated interest in creation and characterization of electrode films for reagent immobilization. We have created two highly porous electrocatalyst support matrices, with high rates of electron transport. Both are based on immobilization of reagents in agarose gel. In one case, Nafion was impregnated into agarose gel films. Diffusion of methyl viologen in Nafionagarose matrices are higher than in Nafion. In Nafion, the diffusion coefficient decreases with increasing methyl viologen concentration, while in Nafionagarose, the opposite dependence is observed. The faster rate of electron transport in Nafionagarose films is related to the heterogeneous structure and the coupling of the diffusion pathways. In the second application of agarose gels as an electrode coating material, agarose hydroxyl groups were activated in 1,1'carbonyldiimidazole and subsequently reacted with amine derivatives of electroactive mediators. Electron transport between the electroactive sites in the gel is very rapid (on the order of 10/sup -7/ cm/sup 2/s. Interpreting the data in light of the Dahms-Ruff description of electron transport shows that the rate of electron transport through both ferrocene and viologen derivatized gels is limited by the rate of electron self-exchange of the species. 22 figs., 15 tabs

  6. Lithium Ion Electrode Production NDE and QC Considerations |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Ion Electrode Production NDE and QC Considerations Lithium Ion Electrode Production NDE and QC Considerations Review of Oak Ridge process and QC activities by David Wood, ...

  7. Magnetohydrodynamic electrode

    DOE Patents [OSTI]

    Marchant, David D. (Richland, WA); Killpatrick, Don H. (Orland Park, IL)

    1978-01-01

    An electrode capable of withstanding high temperatures and suitable for use as a current collector in the channel of a magnetohydrodynamic (MHD) generator consists of a sintered powdered metal base portion, the upper surface of the base being coated with a first layer of nickel aluminide, an intermediate layer of a mixture of nickel aluminide - refractory ceramic on the first layer and a third or outer layer of a refractory ceramic material on the intermediate layer. The sintered powdered metal base resists spalling by the ceramic coatings and permits greater electrode compliance to thermal shock. The density of the powdered metal base can be varied to allow optimization of the thermal conductivity of the electrode and prevent excess heat loss from the channel.

  8. Cermet electrode

    DOE Patents [OSTI]

    Maskalick, Nicholas J.

    1988-08-30

    Disclosed is a cermet electrode consisting of metal particles of nickel, cobalt, iron, or alloys or mixtures thereof immobilized by zirconia stabilized in cubic form which contains discrete deposits of about 0.1 to about 5% by weight of praseodymium, dysprosium, terbium, or a mixture thereof. The solid oxide electrode can be made by covering a substrate with particles of nickel, cobalt, iron, or mixtures thereof, growing a stabilized zirconia solid oxide skeleton around the particles thereby immobilizing them, contacting the skeleton with a compound of praseodymium, dysprosium, terbium, or a mixture thereof, and heating the skeleton to a temperature of at least 500.degree. C. The electrode can also be made by preparing a slurry of nickel, cobalt, iron, or mixture and a compound of praseodymium, dysprosium, terbium, or a mixture thereof, depositing the slurry on a substrate, heating the slurry to dryness, and growing a stabilized zirconia skeleton around the metal particles.

  9. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  10. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  11. Improved photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, T.A.

    1983-06-29

    Improved photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  12. Electrochemical photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, Terje A.

    1984-01-01

    Improved electrochemical photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  13. Carbon cloth supported electrode

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA); Ammon, Robert L. (Baldwin both of, PA)

    1982-01-01

    A flow-by anode is disclosed made by preparing a liquid suspension of about to about 18% by weight solids, the solids comprising about 3.5 to about 8% of a powdered catalyst of platinum, palladium, palladium oxide, or mixtures thereof; about 60 to about 76% carbon powder (support) having a particle size less than about 20 m.mu.m and about 20 to about 33% of an inert binder having a particle size of less than about 500 m.mu.m. A sufficient amount of the suspension is poured over a carbon cloth to form a layer of solids about 0.01 to about 0.05 cm thick on the carbon cloth when the electrode is completed. A vacuum was applied to the opposite side of the carbon cloth to remove the liquid and the catalyst layer/cloth assembly is dried and compressed at about 10 to about 50 MPa's. The binder is then sintered in an inert atmosphere to complete the electrode. The electrode is used for the oxidation of sulfur dioxide in a sulfur based hybrid cycle for the decomposition of water.

  14. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the third quarter, April 1, 1989-June 30, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Barbour, F.A.; Turner, T.F.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-07-01

    This research project is for the development of a technical and economical feasible process for drying and stability fine particles of high-moisture subbituminous coal. Research conducted in this quarter focused upon thermogravimetric analysis (TGA) of both feed coals; continuation of the bench-scale IFB drying experiments; and initiation of the characterization of the products from the bench-scale drying experiments to determine their moisture reabsorption, dustiness, and spontaneous ignition properties. Thirty 4-hr and six 12-hr bench-scale IFB drying tests were conducted this quarter making a total of forty-one 4-hr (19 using Eagle Butte feed coal and 22 using Usibelli feed coal) and six 12-hr (3 using each feed coal) tests conducted thus far. IFB reactor slopes of 3, 6, 9, 12, and 15 degrees were investigated for each feed coal. During the tests using Eagle Butte coal, gas-to-solids ratios ranging from approximately 0.7 to 9.7 lb/lb (kg/kg) and average IFB reactor temperatures ranging from approximately 370 to 700/degree/F (188 to 371/degree/C) were tested. 5 refs., 41 figs., 7 tabs.

  15. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, D.R.

    1988-08-16

    A stable reference electrode is described for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na[sub 3]AlF[sub 6], wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution. 1 fig.

  16. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1988-01-01

    A stable reference electrode for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na.sub.3 AlF.sub.6, wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution.

  17. Fabrication methods for low impedance lithium polymer electrodes

    DOE Patents [OSTI]

    Chern, T.S.; MacFadden, K.O.; Johnson, S.L.

    1997-12-16

    A process is described for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.

  18. Fabrication methods for low impedance lithium polymer electrodes

    DOE Patents [OSTI]

    Chern, Terry Song-Hsing; MacFadden, Kenneth Orville; Johnson, Steven Lloyd

    1997-01-01

    A process for fabricating an electrolyte-electrode composite suitable for high energy alkali metal battery that includes mixing composite electrode materials with excess liquid, such as ethylene carbonate or propylene carbonate, to produce an initial formulation, and forming a shaped electrode therefrom. The excess liquid is then removed from the electrode to compact the electrode composite which can be further compacted by compression. The resulting electrode exhibits at least a 75% lower resistance.

  19. Lithium battery electrodes with ultra-thin alumina coatings

    DOE Patents [OSTI]

    Se-Hee, Lee; George, Steven M.; Cavanagh, Andrew S.; Yoon Seok, Jung; Dillon, Anne C.

    2015-11-24

    Electrodes for lithium batteries are coated via an atomic layer deposition process. The coatings can be applied to the assembled electrodes, or in some cases to particles of electrode material prior to assembling the particles into an electrode. The coatings can be as thin as 2 .ANG.ngstroms thick. The coating provides for a stable electrode. Batteries containing the electrodes tend to exhibit high cycling capacities.

  20. Atmospheric corrosion of lithium electrodes

    SciTech Connect (OSTI)

    Johnson, C.J.

    1981-10-01

    Atmospheric corrosion of lithium during lithium-cell assembly and the dry storage of cells prior to electrolyte fill has been found to initiate lithium corrosion pits and to form corrosion products. Scanning Electron Microscopy (SEM) was used to investigate lithium pitting and the white floccullent corrosion products. Electron Spectroscopy for Chemical Analysis (ESCA) and Auger spectroscopy in combination with X-ray diffraction were used to characterize lithium surfaces. Lithium surfaces with corrosion products were found to be high in carbonate content indicating the presence of lithium carbonate. Lithium electrodes dry stored in unfilled batteries were found to contain high concentration of lithium flouride a possible corrosion product from gaseous materials from the carbon monofluoride cathode. Future investigations of the corrosion phenomena will emphasize the effect of the corrosion products on the electrolyte and ultimate battery performance. The need to protect lithium electrodes from atmospheric exposure is commonly recognized to minimize corrosion induced by reaction with water, oxygen, carbon dioxide or nitrogen (1). Manufacturing facilities customarily limit the relative humidity to less than two percent. Electrodes that have been manufactured for use in lithium cells are typically stored in dry-argon containers. In spite of these precautions, lithium has been found to corrode over a long time period due to residual gases or slow diffusion of the same into storage containers. The purpose of this investigation was to determine the nature of the lithium corrosion.

  1. Method for fabrication of electrodes

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.; Barksdale, Randy

    2004-06-22

    Described herein is a method to fabricate porous thin-film electrodes for fuel cells and fuel cell stacks. Furthermore, the method can be used for all fuel cell electrolyte materials which utilize a continuous electrolyte layer. An electrode layer is deposited on a porous host structure by flowing gas (for example, Argon) from the bottomside of the host structure while simultaneously depositing a conductive material onto the topside of the host structure. By controlling the gas flow rate through the pores, along with the process conditions and deposition rate of the thin-film electrode material, a film of a pre-determined thickness can be formed. Once the porous electrode is formed, a continuous electrolyte thin-film is deposited, followed by a second porous electrode to complete the fuel cell structure.

  2. Method of electrode fabrication and an electrode for metal chloride...

    Office of Scientific and Technical Information (OSTI)

    Method of electrode fabrication and an electrode for metal chloride battery Title: Method of electrode fabrication and an electrode for metal chloride battery A method of ...

  3. Vehicle Technologies Office Merit Review 2015: Electrode Coating Defect Analysis and Processing NDE for High-Energy Lithium-Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode...

  4. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, David F. (Idaho Falls, ID); Suciu, Dan F. (Idaho Falls, ID); Harris, Taryl L. (Idaho Falls, ID); Ingram, Jani C. (Idaho Falls, ID)

    1993-01-01

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  5. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, D.F.; Suciu, D.F.; Harris, T.L.; Ingram, J.C.

    1993-04-06

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  6. Composite substrate for bipolar electrodes

    DOE Patents [OSTI]

    Tekkanat, B.; Bolstad, J.J.

    1992-12-22

    Substrates for electrode systems, particularly those to be used for bipolar electrodes in zinc-bromine batteries, are disclosed. The substrates preferably include carbon-black as a conductive filler in a polymeric matrix, with reinforcing materials such as glass fibers. Warpage of the zinc-bromine electrodes which was experienced in the prior art and which was believed to be caused by physical expansion of the electrodes due to bromine absorption by the carbon-black, is substantially eliminated when new substrate fabrication techniques are employed. In the present invention, substrates are prepared using a lamination process known as glass mat reinforced thermoplastics technology or, in an alternate embodiment, the substrate is made using a slurry process. 4 figs.

  7. Method of making biocompatible electrodes

    DOE Patents [OSTI]

    Wollam, John S.

    1992-01-01

    A process of improving the sensing function of biocompatible electrodes and the product so made are disclosed. The process is designed to alter the surfaces of the electrodes at their tips to provide increased surface area and therefore decreased contact resistance at the electrode-tissue interface for increased sensitivity and essentially includes rendering the tips atomically clean by exposing them to bombardment by ions of an inert gas, depositing an adhesion layer on the cleaned tips, forming a hillocked layer on the adhesion layer by increasing the temperature of the tips, and applying a biocompatible coating on the hillocked layer. The resultant biocompatible electrode is characterized by improved sensitivity, minimum voltage requirement for organ stimulation and a longer battery life for the device in which it is employed.

  8. Composite substrate for bipolar electrodes

    DOE Patents [OSTI]

    Tekkanat, Bora; Bolstad, James J.

    1992-12-22

    Substrates for electrode systems, particularly those to be used for bipolar electrodes in zinc-bromine batteries, are disclosed. The substrates preferably include carbon-black as a conductive filler in a polymeric matrix, with reinforcing materials such as glass fibers. Warpage of the zinc-bromine electrodes which was experienced in the prior art and which was believed to be caused by physical expansion of the electrodes due to bromine absorption by the carbon-black, is substantially eliminated when new substrate fabrication techniques are employed. In the pesent invention, substrates are prepared using a lamination process known as glass mat reinforced thermoplastics technology or, in an alternate embodiment, the substrate is made using a slurry process.

  9. Full containment spray drying

    SciTech Connect (OSTI)

    Masters, K.

    1999-11-01

    Aspects of safety, environmental protection, and powder quality will continue to influence advances within spray dryer design and operation, and the concept of full containment spray drying offers a means to meet future industrial requirements. Process air recycle and powder containment within the drying chamber leads to no process air discharge to atmosphere, provides a more favorable operator environment around the spray dryer installation, reduces regions within the dryer layout where potential explosive powder/air mixtures can exist, improves yields, reduces powder losses, and provides easier cleaning operations with reduced wash water requirements.

  10. Dry reforming of hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Shah, Yatish T.; Gardner, Todd H.

    2014-09-25

    Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

  11. Capacitance enhancement via electrode patterning

    SciTech Connect (OSTI)

    Ho, Tuan A.; Striolo, Alberto; Department of Chemical Engineering, University College London, Torrington Place, London WC1E 7JE

    2013-11-28

    The necessity of increasing the energy density in electric double layer capacitors to meet current demand is fueling fundamental and applied research alike. We report here molecular dynamics simulation results for aqueous electrolytes near model electrodes. Particular focus is on the effect of electrode patterning on the structure of interfacial electrolytes, and on the potential drop between the solid electrodes and the bulk electrolytes. The latter is estimated by numerically integrating the Poisson equation using the charge densities due to water and ions accumulated near the interface as input. We considered uniform and patterned electrodes, both positively and negatively charged. The uniformly charged electrodes are modeled as graphite. The patterned ones are obtained by removing carbon atoms from the top-most graphene layer, yielding nanoscopic squares and stripes patterns. For simplicity, the patterned electrodes are effectively simulated as insulators (the charge remains localized on the top-most layer of carbon atoms). Our simulations show that the patterns alter the structure of water and the accumulation of ions at the liquid-solid interfaces. Using aqueous NaCl solutions, we found that while the capacitance calculated for three positively charged electrodes did not change much, that calculated for the negatively charged electrodes significantly increased upon patterning. We find that both water structure and orientation, as well as ion accumulation affect the capacitance. As electrode patterning affects differently water structure and ion accumulation, it might be possible to observe ion-specific effects. These results could be useful for advancing our understanding of electric double layer capacitors, capacitive desalination processes, as well as of fundamental interfacial electrolytes properties.

  12. Development of an advanced process for drying fine coal in an inclined fluidized bed: Technical progress report for the second quarter, January 19--March 31, 1989

    SciTech Connect (OSTI)

    Boysen, J.E.; Cha, C.Y.; Berggren, M.H.; Jha, M.C.

    1989-05-01

    This research project is for the development of a technically and economically feasible process for drying and stabilizing of fine particles of high-moisture subbituminous coal. Research activities were initiated with efforts concentrating on characterization of the two feed coals: Eagle Butte coal from AMAX Coal Company's mine located in the Powder River Basin of Wyoming; and coal from Usibelli Coal Mine, Inc.'s mine located in central Alaska. Both of the feed coals are high-moisture subbituminous coals with ''as received'' moisture contents of 29% and 22% for the Eagle Butte and Usibelli coals, respectively. However, physical analyses of the crushed coal samples (--28-mesh particle size range) indicate many differences. The minimum fluidization velocity (MFV) of the feed coals were experimentally determined. The MFV for --28-mesh Eagle Butte coal is approximately 1 ft/min, and the MFV for --28-mesh Usibelli coal is approximately 3 ft/min. 2 refs., 16 figs., 3 tabs.

  13. The influence of the drying medium on high temperature convective drying of single wood chips

    SciTech Connect (OSTI)

    Johansson, A.; Rasmuson, A.

    1997-10-01

    High temperature convective drying of single wood chips with air and superheated steam respectively is studied theoretically. The two-dimensional model presented describes the coupled transport of water, vapor, air and heat. Transport mechanisms included are the convection of gas and liquid, intergas as well as bound water diffusion. In the initial part of the drying process, moisture is transported to the surface mainly due to capillary forces in the transversal direction where evaporation occurs. As the surface becomes dry, the drying front moves towards the center of the particle and an overpressure is simultaneously built up which affects the drying process. The differences between drying in air and steam respectively can be assigned to the physical properties of the drying medium. The period of constant drying rate which does not exist (or is very short) in air drying becomes more significant with decreasing amounts of air in the drying medium and is clearly visible in pure superheated steam drying. The maximal drying rate is larger in air drying, and shorter drying times are obtained since the heat flux to the wood chip particle increases with increasing amounts of air in the drying medium. The period of falling drying rate can be divided into two parts: in the first, the drying rate is dependent upon the humidity of the drying medium whereas in the second, there is no such correlation.

  14. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Mapping Particle Charges in Battery Electrodes Print Friday, 26 July 2013 14:18 The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how

  15. Process for electrically interconnecting electrodes

    DOE Patents [OSTI]

    Carey, Paul G.; Thompson, Jesse B.; Colella, Nicolas J.; Williams, Kenneth A.

    2002-01-01

    Electrical interconnects for solar cells or other electronic components using a silver-silicone paste or a lead-tin (Pb--Sn) no-clean fluxless solder cream, whereby the high breakage of thin (<6 mil thick) solar cells using conventional solder interconnect is eliminated. The interconnects of this invention employs copper strips which are secured to the solar cells by a silver-silicone conductive paste which can be used at room temperature, or by a Pb--Sn solder cream which eliminates undesired residue on the active surfaces of the solar cells. Electrical testing using the interconnects of this invention has shown that no degradation of the interconnects developed under high current testing, while providing a very low contact resistance value.

  16. Chemical Engineering Division fuel cycle programs. Quarterly progress report, April-June 1979. [Pyrochemical/dry processing; waste encapsulation in metal; transport in geologic media

    SciTech Connect (OSTI)

    Steindler, M.J.; Ader, M.; Barletta, R.E.

    1980-09-01

    For pyrochemical and dry processing materials development included exposure to molten metal and salt of Mo-0.5% Ti-0.07% Ti-0.01% C, Mo-30% W, SiC, Si/sub 2/ON/sub 2/, ZrB/sub 2/-SiC, MgAl/sub 2/O/sub 4/, Al/sub 2/O/sub 3/, AlN, HfB/sub 2/, Y/sub 2/O/sub 3/, BeO, Si/sub 3/N/sub 4/, nickel nitrate-infiltrated W, W-coated Mo, and W-metallized alumina-yttria. Work on Th-U salt transport processing included solubility of Th in liquid Cd, defining the Cd-Th and Cd-Mg-Th phase diagrams, ThO/sub 2/ reduction experiments, and electrolysis of CaO in molten salt. Work on pyrochemical processes and associated hardware for coprocessing U and Pu in spent FBR fuels included a second-generation computer model of the transport process, turntable transport process design, work on the U-Cu-Mg system, and U and Pu distribution coefficients between molten salt and metal. Refractory metal vessels are being service-life tested. The chloride volatility processing of Th-based fuel was evaluated for its proliferation resistance, and a preliminary ternary phase diagram for the Zn-U-Pu system was computed. Material characterization and process analysis were conducted on the Exportable Pyrochemical process (Pyro-Civex process). Literature data on oxidation of fissile metals to oxides were reviewed. Work was done on chemical bases for the reprocessing of actinide oxides in molten salts. Flowsheets are being developed for the processing of fuel in molten tin. Work on encapsulation of solidified radioactive waste in metal matrix included studies of leach rate of crystalline waste materials and of the impact resistance of metal-matrix waste forms. In work on the transport properties of nuclear waste in geologic media, adsorption of Sr on oolitic limestone was studied, as well as the migration of Cs in basalt. Fitting of data on the adsorption of iodate by hematite to a mathematical model was attempted.

  17. Flexible retinal electrode array

    DOE Patents [OSTI]

    Okandan, Murat; Wessendorf, Kurt O.; Christenson, Todd R.

    2006-10-24

    An electrode array which has applications for neural stimulation and sensing. The electrode array can include a large number of electrodes each of which is flexibly attached to a common substrate using a plurality of springs to allow the electrodes to move independently. The electrode array can be formed from a combination of bulk and surface micromachining, with electrode tips that can include an electroplated metal (e.g. platinum, iridium, gold or titanium) or a metal oxide (e.g. iridium oxide) for biocompatibility. The electrode array can be used to form a part of a neural prosthesis, and is particularly well adapted for use in an implantable retinal prosthesis where the electrodes can be tailored to provide a uniform gentle contact pressure with optional sensing of this contact pressure at one or more of the electrodes.

  18. Micromachined electrode array

    DOE Patents [OSTI]

    Okandan, Murat; Wessendorf, Kurt O.

    2007-12-11

    An electrode array is disclosed which has applications for neural stimulation and sensing. The electrode array, in certain embodiments, can include a plurality of electrodes each of which is flexibly attached to a common substrate using a plurality of springs to allow the electrodes to move independently. In other embodiments of the electrode array, the electrodes can be fixed to the substrate. The electrode array can be formed from a combination of bulk and surface micromachining, and can include electrode tips having an electroplated metal (e.g. platinum, iridium, gold or titanium) or a metal oxide (e.g. iridium oxide) for biocompatibility. The electrode array can be used to form a part of a neural prosthesis, and is particularly well adapted for use in an implantable retinal prosthesis.

  19. High frequency reference electrode

    DOE Patents [OSTI]

    Kronberg, James W.

    1994-01-01

    A high frequency reference electrode for electrochemical experiments comprises a mercury-calomel or silver-silver chloride reference electrode with a layer of platinum around it and a layer of a chemically and electrically resistant material such as TEFLON around the platinum covering all but a small ring or "halo" at the tip of the reference electrode, adjacent to the active portion of the reference electrode. The voltage output of the platinum layer, which serves as a redox electrode, and that of the reference electrode are coupled by a capacitor or a set of capacitors and the coupled output transmitted to a standard laboratory potentiostat. The platinum may be applied by thermal decomposition to the surface of the reference electrode. The electrode provides superior high-frequency response over conventional electrodes.

  20. High frequency reference electrode

    DOE Patents [OSTI]

    Kronberg, J.W.

    1994-05-31

    A high frequency reference electrode for electrochemical experiments comprises a mercury-calomel or silver-silver chloride reference electrode with a layer of platinum around it and a layer of a chemically and electrically resistant material such as TEFLON around the platinum covering all but a small ring or halo' at the tip of the reference electrode, adjacent to the active portion of the reference electrode. The voltage output of the platinum layer, which serves as a redox electrode, and that of the reference electrode are coupled by a capacitor or a set of capacitors and the coupled output transmitted to a standard laboratory potentiostat. The platinum may be applied by thermal decomposition to the surface of the reference electrode. The electrode provides superior high-frequency response over conventional electrodes. 4 figs.

  1. Controlled porosity in electrodes

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Bae, Chang-Jun; Halloran, John William; Fu, Qiang; Tomsia, Antoni P.; Erdonmez, Can K.

    2015-06-23

    Porous electrodes in which the porosity has a low tortuosity are generally provided. In some embodiments, the porous electrodes can be designed to be filled with electrolyte and used in batteries, and can include low tortuosity in the primary direction of ion transport during charge and discharge of the battery. In some embodiments, the electrodes can have a high volume fraction of electrode active material (i.e., low porosity). The attributes outlined above can allow the electrodes to be fabricated with a higher energy density, higher capacity per unit area of electrode (mAh/cm.sup.2), and greater thickness than comparable electrodes while still providing high utilization of the active material in the battery during use. Accordingly, the electrodes can be used to produce batteries with high energy densities, high power, or both compared to batteries using electrodes of conventional design with relatively highly tortuous pores.

  2. High performance cermet electrodes

    DOE Patents [OSTI]

    Isenberg, Arnold O.; Zymboly, Gregory E.

    1986-01-01

    Disclosed is a method of increasing the operating cell voltage of a solid oxide electrochemical cell having metal electrode particles in contact with an oxygen-transporting ceramic electrolyte. The metal electrode is heated with the cell, and oxygen is passed through the oxygen-transporting ceramic electrolyte to the surface of the metal electrode particles so that the metal electrode particles are oxidized to form a metal oxide layer between the metal electrode particles and the electrolyte. The metal oxide layer is then reduced to form porous metal between the metal electrode particles and the ceramic electrolyte.

  3. Multifunctional reference electrode (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Multifunctional reference electrode Title: Multifunctional reference electrode A multifunctional, low mass reference electrode of a nickel tube, thermocouple means inside the ...

  4. Microwave drying of ferric oxide pellets

    SciTech Connect (OSTI)

    Pickles, C.A.; Xia, D.K.

    1997-12-31

    The application of microwave energy for the drying of ferric oxide pellets has been investigated and evaluated. It is shown that the microwave drying rates are much higher than those observed in the conventional process. Also there is some potential for improved quality of the product. As a stand-alone technology it is unlikely that microwave drying would be economical for pellets due to the low cost of conventional fuels. However, based on an understanding of the drying mechanisms in the conventional process and in the microwave process, it is shown that microwave-assisted drying offers considerable potential. In this hybrid process, the advantages of the two drying techniques are combined to provide an improved drying process.

  5. Gas tungsten arc welder with electrode grinder

    SciTech Connect (OSTI)

    Christiansen, David W.; Brown, William F.

    1984-01-01

    A welder for automated closure of fuel pins by a gas tungsten arc process in which a rotating length of cladding is positioned adjacent a welding electrode in a sealed enclosure. An independently movable axial grinder is provided in the enclosure for refurbishing the used electrode between welds.

  6. Corneal-shaping electrode

    DOE Patents [OSTI]

    Doss, James D.; Hutson, Richard L.

    1982-01-01

    The disclosure relates to a circulating saline electrode for changing corneal shape in eyes. The electrode comprises a tubular nonconductive electrode housing having an annular expanded base which has a surface substantially matched to a subject corneal surface. A tubular conductive electrode connected to a radiofrequency generating source is disposed within the electrode housing and longitudinally aligned therewith. The electrode has a generally hemispherical head having at least one orifice. Saline solution is circulated through the apparatus and over the cornea to cool the corneal surface while radiofrequency electric current emitted from the electrode flows therefrom through the cornea to a second electrode, on the rear of the head. This current heats the deep corneal stroma and thereby effects corneal reshaping as a biological response to the heat.

  7. Multiple input electrode gap controller

    DOE Patents [OSTI]

    Hysinger, Christopher L.; Beaman, Joseph J.; Melgaard, David K.; Williamson, Rodney L.

    1999-01-01

    A method and apparatus for controlling vacuum arc remelting (VAR) furnaces by estimation of electrode gap based on a plurality of secondary estimates derived from furnace outputs. The estimation is preferably performed by Kalman filter. Adaptive gain techniques may be employed, as well as detection of process anomalies such as glows.

  8. Multiple input electrode gap controller

    DOE Patents [OSTI]

    Hysinger, C.L.; Beaman, J.J.; Melgaard, D.K.; Williamson, R.L.

    1999-07-27

    A method and apparatus for controlling vacuum arc remelting (VAR) furnaces by estimation of electrode gap based on a plurality of secondary estimates derived from furnace outputs. The estimation is preferably performed by Kalman filter. Adaptive gain techniques may be employed, as well as detection of process anomalies such as glows. 17 figs.

  9. Compartmented electrode structure

    DOE Patents [OSTI]

    Vissers, Donald R.; Shimotake, Hiroshi; Gay, Eddie C.; Martino, Fredric J.

    1977-06-14

    Electrodes for secondary electrochemical cells are provided with compartments for containing particles of the electrode reactant. The compartments are defined by partitions that are generally impenetrable to the particles of reactant and, in some instances, to the liquid electrolyte used in the cell. During cycling of the cell, reactant material initially loaded into a particular compartment is prevented from migrating and concentrating within the lower portion of the electrode or those portions of the electrode that exhibit reduced electrical resistance.

  10. Nanoengineered membrane electrode assembly interface

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-08-06

    A membrane electrode structure suitable for use in a membrane electrode assembly (MEA) that comprises membrane-affixed metal nanoparticles whose formation is controlled by a photochemical process that controls deposition of the metal nanoparticles using a photocatalyst integrated with a polymer electrolyte membrane, such as an ionomer membrane. Impregnation of the polymer membrane with the photocatalyst prior to metal deposition greatly reduces the required amount of metal precursor in the deposition reaction solution by restricting metal reduction substantially to the formation of metal nanoparticles affixed on or near the surface of the polymer membrane with minimal formation of metallic particles not directly associated with the membrane.

  11. Longitudinal discharge laser electrodes

    DOE Patents [OSTI]

    Warner, B.E.; Miller, J.L.; Ault, E.R.

    1994-08-23

    The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window. 2 figs.

  12. Near-electrode imager

    DOE Patents [OSTI]

    Rathke, Jerome W.; Klingler, Robert J.; Woelk, Klaus; Gerald, II, Rex E.

    2000-01-01

    An apparatus, near-electrode imager, for employing nuclear magnetic resonance imaging to provide in situ measurements of electrochemical properties of a sample as a function of distance from a working electrode. The near-electrode imager uses the radio frequency field gradient within a cylindrical toroid cavity resonator to provide high-resolution nuclear magnetic resonance spectral information on electrolyte materials.

  13. Microresonator electrode design

    DOE Patents [OSTI]

    Olsson, III, Roy H.; Wojciechowski, Kenneth; Branch, Darren W.

    2016-05-10

    A microresonator with an input electrode and an output electrode patterned thereon is described. The input electrode includes a series of stubs that are configured to isolate acoustic waves, such that the waves are not reflected into the microresonator. Such design results in reduction of spurious modes corresponding to the microresonator.

  14. Longitudinal discharge laser electrodes

    DOE Patents [OSTI]

    Warner, Bruce E.; Miller, John L.; Ault, Earl R.

    1994-01-01

    The improved longitudinal discharge laser electrode with IR baffle includes an electrode made up of washers spaced along the laser axis in order to form inter-washer spaces for hollow cathode discharge to take place and for IR radiation to be trapped. Additional IR baffles can be placed between the electrode ann the window.

  15. Drying of fiber webs

    DOE Patents [OSTI]

    Warren, D.W.

    1997-04-15

    A process and an apparatus are disclosed for high-intensity drying of fiber webs or sheets, such as newsprint, printing and writing papers, packaging paper, and paperboard or linerboard, as they are formed on a paper machine. The invention uses direct contact between the wet fiber web or sheet and various molten heat transfer fluids, such as liquefied eutectic metal alloys, to impart heat at high rates over prolonged durations, in order to achieve ambient boiling of moisture contained within the web. The molten fluid contact process causes steam vapor to emanate from the web surface, without dilution by ambient air; and it is differentiated from the evaporative drying techniques of the prior industrial art, which depend on the uses of steam-heated cylinders to supply heat to the paper web surface, and ambient air to carry away moisture, which is evaporated from the web surface. Contact between the wet fiber web and the molten fluid can be accomplished either by submersing the web within a molten bath or by coating the surface of the web with the molten media. Because of the high interfacial surface tension between the molten media and the cellulose fiber comprising the paper web, the molten media does not appreciatively stick to the paper after it is dried. Steam generated from the paper web is collected and condensed without dilution by ambient air to allow heat recovery at significantly higher temperature levels than attainable in evaporative dryers. 6 figs.

  16. Drying of fiber webs

    DOE Patents [OSTI]

    Warren, David W.

    1997-01-01

    A process and an apparatus for high-intensity drying of fiber webs or sheets, such as newsprint, printing and writing papers, packaging paper, and paperboard or linerboard, as they are formed on a paper machine. The invention uses direct contact between the wet fiber web or sheet and various molten heat transfer fluids, such as liquified eutectic metal alloys, to impart heat at high rates over prolonged durations, in order to achieve ambient boiling of moisture contained within the web. The molten fluid contact process causes steam vapor to emanate from the web surface, without dilution by ambient air; and it is differentiated from the evaporative drying techniques of the prior industrial art, which depend on the uses of steam-heated cylinders to supply heat to the paper web surface, and ambient air to carry away moisture, which is evaporated from the web surface. Contact between the wet fiber web and the molten fluid can be accomplished either by submersing the web within a molten bath or by coating the surface of the web with the molten media. Because of the high interfacial surface tension between the molten media and the cellulose fiber comprising the paper web, the molten media does not appreciately stick to the paper after it is dried. Steam generated from the paper web is collected and condensed without dilution by ambient air to allow heat recovery at significantly higher temperature levels than attainable in evaporative dryers.

  17. Negative electrode composition

    DOE Patents [OSTI]

    Kaun, Thomas D.; Chilenskas, Albert A.

    1982-01-01

    A secondary electrochemical cell and a negative electrode composition for use therewith comprising a positive electrode containing an active material of a chalcogen or a transiton metal chalcogenide, a negative electrode containing a lithium-aluminum alloy and an amount of a ternary alloy sufficient to provide at least about 5 percent overcharge capacity relative to a negative electrode solely of the lithium-aluminum alloy, the ternary alloy comprising lithium, aluminum, and iron or cobalt, and an electrolyte containing lithium ions in contact with both of the positive and the negative electrodes. The ternary alloy is present in the electrode in the range of from about 5 percent to about 50 percent by weight of the electrode composition and may include lithium-aluminum-nickel alloy in combination with either the ternary iron or cobalt alloys. A plurality of series connected cells having overcharge capacity can be equalized on the discharge side without expensive electrical equipment.

  18. Report on Biomass Drying Technology

    SciTech Connect (OSTI)

    Amos, W. A.

    1999-01-12

    Using dry fuel provides significant benefits to combustion boilers, mainly increased boiler efficiency, lower air emissions, and improved boiler operation. The three main choices for drying biomass are rotary dryers, flash dryers, and superheated steam dryers. Which dryer is chosen for a particular application depends very much on the material characteristics of the biomass, the opportunities for integrating the process and dryer, and the environmental controls needed or already available.

  19. Use of Liquid Electrodes for Magnetohydrodynamic Power Generation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications | Princeton Plasma Physics Lab Use of Liquid Electrodes for Magnetohydrodynamic Power Generation Applications The use of liquid electrodes in magnetohydrodynamic (MHD) power generation applications is proposed as a means of extending the lifetime of the electrodes in these systems. Previous studies utilized various metals, metal alloys and ceramic materials as electrodes but all suffered from erosion processes in the harsh gas stream used in MHD power generation. This invention

  20. Uncharged positive electrode composition

    DOE Patents [OSTI]

    Kaun, Thomas D.; Vissers, Donald R.; Shimotake, Hiroshi

    1977-03-08

    An uncharged positive-electrode composition contains particulate lithium sulfide, another alkali metal or alkaline earth metal compound other than sulfide, e.g., lithium carbide, and a transition metal powder. The composition along with a binder, such as electrolytic salt or a thermosetting resin is applied onto an electrically conductive substrate to form a plaque. The plaque is assembled as a positive electrode within an electrochemical cell opposite to a negative electrode containing a material such as aluminum or silicon for alloying with lithium. During charging, lithium alloy is formed within the negative electrode and transition metal sulfide such as iron sulfide is produced within the positive electrode. Excess negative electrode capacity over that from the transition metal sulfide is provided due to the electrochemical reaction of the other than sulfide alkali metal or alkaline earth metal compound.

  1. Nanoscopic electrode molecular probes

    DOE Patents [OSTI]

    Krstic, Predrag S. (Knoxville, TN); Meunier, Vincent (Knoxville, TN)

    2012-05-22

    The present invention relates to a method and apparatus for enhancing the electron transport property measurements of a molecule when the molecule is placed between chemically functionalized carbon-based nanoscopic electrodes to which a suitable voltage bias is applied. The invention includes selecting a dopant atom for the nanoscopic electrodes, the dopant atoms being chemically similar to atoms present in the molecule, and functionalizing the outer surface and terminations of the electrodes with the dopant atoms.

  2. Corneal-shaping electrode

    DOE Patents [OSTI]

    Doss, J.D.; Hutson, R.L.

    1979-12-05

    The invention relates to corneal reshaping and more particularly to electrodes utilizing radiofrequency electrical current to heat and thereby induce reshaping of the cornea in humans and animals.

  3. dry-regen | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dry Regenerable Sorbents Project No.: FC26-07NT43089 Schematic of RTI's Dry Carbonate Process (click image to enlarge) Research Triangle Institute (RTI) International completed two projects, NT43089 and NT40923, to investigate the use of sodium carbonate (Na2CO3 or soda ash) as an inexpensive, dry, and regenerable sorbent for carbon dioxide (CO2) capture in the Dry Carbonate Process. In this process, Na2CO3 reacts with CO2 and water to form sodium bicarbonate at the temperature of the flue gas

  4. Uncharged positive electrode composition (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Uncharged positive electrode composition Title: Uncharged positive electrode composition An uncharged positive-electrode composition contains particulate lithium sulfide, another ...

  5. Electrodes for microfluidic applications

    DOE Patents [OSTI]

    Crocker, Robert W.; Harnett, Cindy K.; Rognlien, Judith L.

    2006-08-22

    An electrode device for high pressure applications. These electrodes, designed to withstand pressure of greater than 10,000 psi, are adapted for use in microfluidic devices that employ electrokinetic or electrophoretic flow. The electrode is composed, generally, of an outer electrically insulating tubular body having a porous ceramic frit material disposed in one end of the outer body. The pores of the porous ceramic material are filled with an ion conductive polymer resin. A conductive material situated on the upper surface of the porous ceramic frit material and, thus isolated from direct contact with the electrolyte, forms a gas diffusion electrode. A metal current collector, in contact with the gas diffusion electrode, provides connection to a voltage source.

  6. HIGH VOLTAGE ELECTRODES

    DOE Patents [OSTI]

    Murray, J.J.

    1963-04-23

    S>This patent relates to electrode structure for creating an intense direct current electric field which may have a field strength of the order of two to three times that heretofore obtained, with automatic suppression of arcing. The positive electrode is a conventional conductive material such as copper while the negative electrode is made from a special material having a resistivity greater than that of good conductors and less than that of good insulators. When an incipient arc occurs, the moderate resistivity of the negative electrode causes a momentary, localized decrease in the electric field intensity, thus suppressing the flow of electrons and avoiding arcing. Heated glass may be utilized for the negative electrode, since it provides the desired combination of resistivity, capacity, dielectric strength, mechani-cal strength, and thermal stability. (AEC)

  7. Plasma torch with liquid metal electrodes

    SciTech Connect (OSTI)

    Predtechenskii, M.R.; Tukhto, O.M.

    2006-03-15

    In order to eliminate the negative effect of erosion processes on electrodes in arc plasma generators, a new scheme of arc discharge was proposed in which the surface of a molten metal acts as electrodes. A plasma reactor was designed on the basis of this concept. The electrophysical characteristics of such a discharge in steam and air as plasma gases were studied. Experiments on destruction of toxic polychlorinated biphenyls and steam coal gasification were performed.

  8. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  9. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  10. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  11. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  12. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Spectroscopy of Supercapacitor Electrodes In Operando Print Wednesday, 27 May 2015 00:00 Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS)

  13. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  14. Nanostructured Solid Oxide Fuel Cell Electrodes

    SciTech Connect (OSTI)

    Sholklapper, Tal Zvi

    2007-12-15

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  15. Layered electrode for electrochemical cells

    DOE Patents [OSTI]

    Swathirajan, Swathy; Mikhail, Youssef M.

    2001-01-01

    There is provided an electrode structure comprising a current collector sheet and first and second layers of electrode material. Together, the layers improve catalyst utilization and water management.

  16. Measuring electrode assembly

    DOE Patents [OSTI]

    Bordenick, J.E.

    1988-04-26

    A pH measuring electrode assembly for immersion in a solution includes an enclosed cylindrical member having an aperture at a lower end thereof. An electrolyte is located in the cylindrical member above the level of the aperture and an electrode is disposed in this electrolyte. A ring formed of an ion porous material is mounted relative to the cylindrical member so that a portion of this ring is rotatable relative to and is covering the aperture in the cylindrical member. A suitable mechanism is also provided for indicating which one of a plurality of portions of the ring is covering the aperture and to keep track of which portions of the ring have already been used and become clogged. Preferably, the electrode assembly also includes a glass electrode member in the center thereof including a second electrolyte and electrode disposed therein. The cylindrical member is resiliently mounted relative to the glass electrode member to provide for easy rotation of the cylindrical member relative to the glass electrode member for changing of the portion of the ring covering the aperture. 2 figs.

  17. Measuring electrode assembly

    DOE Patents [OSTI]

    Bordenick, John E.

    1989-01-01

    A pH measuring electrode assembly for immersion in a solution includes an enclosed cylindrical member having an aperture at a lower end thereof. An electrolyte is located in the cylindrical member above the level of the aperture and an electrode is disposed in this electrolyte. A ring formed of an ion porous material is mounted relative to the cylindrical member so that a portion of this ring is rotatable relative to and is covering the aperture in the cylindrical member. A suitable mechanism is also provided for indicating which one of a plurality of portions of the ring is covering the aperture and to keep track of which portions of the ring have already been used and become clogged. Preferably, the electrode assembly also includes a glass electrode member in the center thereof including a second electrolyte and electrode disposed therein. The cylindrical member is resiliently mounted relative to the glass electrode member to provide for easy rotation of the cylindrical member relative to the glass electrode member for changing of the portion of the ring covering the aperture.

  18. Multifunctional reference electrode

    DOE Patents [OSTI]

    Redey, Laszlo; Vissers, Donald R.

    1983-01-01

    A multifunctional, low mass reference electrode of a nickel tube, thermocouple means inside the nickel tube electrically insulated therefrom for measuring the temperature thereof, a housing surrounding the nickel tube, an electrolyte having a fixed sulfide ion activity between the housing and the outer surface of the nickel tube forming the nickel/nickel sulfide/sulfide half-cell. An ion diffusion barrier is associated with the housing in contact with the electrolyte. Also disclosed is a cell using the reference electrode to measure characteristics of a working electrode.

  19. Multifunctional reference electrode

    DOE Patents [OSTI]

    Redey, L.; Vissers, D.R.

    1981-12-30

    A multifunctional, low mass reference electrode of a nickel tube, thermocouple means inside the nickel tube electrically insulated therefrom for measuring the temperature thereof, a housing surrounding the nickel tube, an electrolyte having a fixed sulfide ion activity between the housing and the outer surface of the nickel tube forming the nickel/nickel sulfide/sulfide half-cell are described. An ion diffusion barrier is associated with the housing in contact with the electrolyte. Also disclosed is a cell using the reference electrode to measure characteristics of a working electrode.

  20. Electrode for electrochemical cell

    DOE Patents [OSTI]

    Kaun, T.D.; Nelson, P.A.; Miller, W.E.

    1980-05-09

    An electrode structure for a secondary electrochemical cell includes an outer enclosure defining a compartment containing electrochemical active material. The enclosure includes a rigid electrically conductive metal sheet with perforated openings over major side surfaces. The enclosure can be assembled as first and second trays each with a rigid sheet of perforated electrically conductive metal at major side surfaces and normally extending flanges at parametric margins. The trays can be pressed together with moldable active material between the two to form an expandable electrode. A plurality of positive and negative electrodes thus formed are arranged in an alternating array with porous frangible interelectrode separators within the housing of the secondary electrochemical cell.

  1. Method for making thin carbon foam electrodes

    DOE Patents [OSTI]

    Pekala, R.W.; Mayer, S.T.; Kaschmitter, J.L.; Morrison, R.L.

    1999-08-03

    A method for fabricating thin, flat carbon electrodes by infiltrating highly porous carbon papers, membranes, felts, metal fibers/powders, or fabrics with an appropriate carbon foam precursor material is disclosed. The infiltrated carbon paper, for example, is then cured to form a gel-saturated carbon paper, which is subsequently dried and pyrolyzed to form a thin sheet of porous carbon. The material readily stays flat and flexible during curing and pyrolyzing to form thin sheets. Precursor materials include polyacrylonitrile (PAN), polymethylacrylonitrile (PMAN), resorcinol/formaldehyde, catechol/formaldehyde, phenol/formaldehyde, etc., or mixtures thereof. These thin films are ideal for use as high power and energy electrodes in batteries, capacitors, and fuel cells, and are potentially useful for capacitive deionization, filtration and catalysis.

  2. Method for making thin carbon foam electrodes

    DOE Patents [OSTI]

    Pekala, Richard W.; Mayer, Steven T.; Kaschmitter, James L.; Morrison, Robert L.

    1999-01-01

    A method for fabricating thin, flat carbon electrodes by infiltrating highly porous carbon papers, membranes, felts, metal fibers/powders, or fabrics with an appropriate carbon foam precursor material. The infiltrated carbon paper, for example, is then cured to form a gel-saturated carbon paper, which is subsequently dried and pyrolyzed to form a thin sheet of porous carbon. The material readily stays flat and flexible during curing and pyrolyzing to form thin sheets. Precursor materials include polyacrylonitrile (PAN), polymethylacrylonitrile (PMAN), resorcinol/formaldehyde, catechol/formaldehyde, phenol/formaldehyde, etc., or mixtures thereof. These thin films are ideal for use as high power and energy electrodes in batteries, capacitors, and fuel cells, and are potentially useful for capacitive deionization, filtration and catalysis.

  3. Zinc electrode with cement additive

    DOE Patents [OSTI]

    Charkey, Allen

    1982-06-01

    A zinc electrode having a cement additive, preferably, Portland Cement, distributed in the zinc active material.

  4. Black Conductive Titanium Oxide High-Capacity Materials for Battery Electrodes

    SciTech Connect (OSTI)

    Han, W.

    2011-05-18

    Stoichiometric titanium dioxide (TiO{sub 2}) is one of the most widely studied transitionmetal oxides because of its many potential applications in photoelectrochemical systems, such as dye-sensitized TiO{sub 2} electrodes for photovoltaic solar cells, and water-splitting catalysts for hydrogen generation, and in environmental purification for creating or degrading specific compounds. However, TiO{sub 2} has a wide bandgap and high electrical resistivity, which limits its use as an electrode. A set of non-stoichiometric titanium oxides called the Magneli phases, having a general formula of Ti{sub n}O{sub 2n-1} with n between 4 and 10, exhibits lower bandgaps and resistivities, with the highest electrical conductivities reported for Ti{sub 4}O{sub 7}. These phases have been formulated under different conditions, but in all reported cases the resulting oxides have minimum grain sizes on the order of micrometers, regardless of the size of the starting titanium compounds. In this method, nanoparticles of TiO{sub 2} or hydrogen titanates are first coated with carbon using either wet or dry chemistry methods. During this process the size and shape of the nanoparticles are 'locked in.' Subsequently the carbon-coated nanoparticles are heated. This results in the transformation of the original TiO{sub 2} or hydrogen titanates to Magneli phases without coarsening, so that the original size and shape of the nanoparticles are maintained to a precise degree. People who work on batteries, fuel cells, ultracapacitors, electrosynthesis cells, electro-chemical devices, and soil remediation have applications that could benefit from using nanoscale Magneli phases of titanium oxide. Application of these electrode materials may not be limited to substitution for TiO{sub 2} electrodes. Combining the robustness and photosensitivity of TiO{sub 2} with higher electrical conductivity may result in a general electrode material.

  5. Capacitive de-ionization electrode

    DOE Patents [OSTI]

    Daily, III, William D.

    2013-03-19

    An electrode "cell" for use in a capacitive deionization (CDI) reactor consists of the electrode support structure, a non-reactive conductive material, the electrode accompaniment or substrate and a flow through screen/separator. These "layers" are repeated and the electrodes are sealed together with gaskets between two end plates to create stacked sets of alternating anode and cathode electrodes in the CDI reactor.

  6. Methods and systems for in-situ electroplating of electrodes

    DOE Patents [OSTI]

    Zappi, Guillermo Daniel; Zarnoch, Kenneth Paul; Huntley, Christian Andrew; Swalla, Dana Ray

    2015-06-02

    The present techniques provide electrochemical devices having enhanced electrodes with surfaces that facilitate operation, such as by formation of a porous nickel layer on an operative surface, particularly of the cathode. The porous metal layer increases the surface area of the electrode, which may result in increasing the efficiency of the electrochemical devices. The formation of the porous metal layer is performed in situ, that is, after the assembly of the electrodes into an electrochemical device. The in situ process offers a number of advantages, including the ability to protect the porous metal layer on the electrode surface from damage during assembly of the electrochemical device. The enhanced electrode and the method for its processing may be used in any number of electrochemical devices, and is particularly well suited for electrodes in an electrolyzer useful for splitting water into hydrogen and oxygen.

  7. Dephosphorization when using DRI

    SciTech Connect (OSTI)

    2005-09-21

    The increase in high quality steel production in electric arc furnaces (EAFs) requires the use of scrap substitute materials, such as Direct Reduced Iron (DRI) and Hot Briquetted Iron (HBI). Although DRI and HBI products have lower copper and nickel contents than most scrap materials, they can contain up to ten times more phosphorus. This project, led by Carnegie Mellon Universitys Center for Iron and Steelmaking Research, improves the understanding of how phosphorus behaves when DRI and HBI melt.

  8. Porous electrode preparation method

    DOE Patents [OSTI]

    Arons, R.M.; Dusek, J.T.

    1983-10-18

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder of such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity. 2 figs.

  9. Liquid-permeable electrode

    DOE Patents [OSTI]

    Folser, George R.

    1980-01-01

    Electrodes for use in an electrolytic cell, which are liquid-permeable and have low electrical resistance and high internal surface area are provided of a rigid, porous, carbonaceous matrix having activated carbon uniformly embedded throughout. The activated carbon may be catalyzed with platinum for improved electron transfer between electrode and electrolyte. Activated carbon is mixed with a powdered thermosetting phenolic resin and compacted to the desired shape in a heated mold to melt the resin and form the green electrode. The compact is then heated to a pyrolyzing temperature to carbonize and volatilize the resin, forming a rigid, porous structure. The permeable structure and high internal surface area are useful in electrolytic cells where it is necessary to continuously remove the products of the electrochemical reaction.

  10. Porous electrode preparation method

    DOE Patents [OSTI]

    Arons, Richard M. (Wheaton, IL); Dusek, Joseph T. (Downers Grove, IL)

    1983-01-01

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder of such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity.

  11. Dynamic control of remelting processes

    DOE Patents [OSTI]

    Bertram, Lee A.; Williamson, Rodney L.; Melgaard, David K.; Beaman, Joseph J.; Evans, David G.

    2000-01-01

    An apparatus and method of controlling a remelting process by providing measured process variable values to a process controller; estimating process variable values using a process model of a remelting process; and outputting estimated process variable values from the process controller. Feedback and feedforward control devices receive the estimated process variable values and adjust inputs to the remelting process. Electrode weight, electrode mass, electrode gap, process current, process voltage, electrode position, electrode temperature, electrode thermal boundary layer thickness, electrode velocity, electrode acceleration, slag temperature, melting efficiency, cooling water temperature, cooling water flow rate, crucible temperature profile, slag skin temperature, and/or drip short events are employed, as are parameters representing physical constraints of electroslag remelting or vacuum arc remelting, as applicable.

  12. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1999-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid partides being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy.

  13. Capacitor with a composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1999-04-27

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  14. Combined Corex/DRI technology

    SciTech Connect (OSTI)

    Flickenschild, A.J.; Reufer, F.; Eberle, A.; Siuka, D.

    1996-08-01

    A feasible steelmaking alternative, the Corex/direct reduction/electric arc furnace combination, provides an economic route for the production of high quality steel products. This combination is a major step into a new generation of iron and steel mills. These mills are based on the production of liquid steel using noncoking coal and comply with the increasing demands of environmental protection. The favorable production costs are based on: Utilization of Corex and DRI/HBI plants; Production of hot metal equal to blast furnace quality; Use of low cost raw materials such as noncoking coal and lump ore; Use of process gas as reducing agent for DRI/HBI production; and Use of electric arc furnace with high hot metal input as the steelmaking process. The high flexibility of the process permits the adjustment of production in accordance with the strategy of the steel mills. New but proven technologies and applications of the latest state of art steelmaking process, e.g., Corex, in conjunction with DRI production as basic raw material for an electric arc furnace, will insure high quality, high availability, optimized energy generation at high efficiency rates, and high product quality for steelmaking.

  15. Dual porosity gas evolving electrode

    DOE Patents [OSTI]

    Townsend, C.W.

    1994-11-15

    A dual porosity electrode is described for use in thermoelectrochemical systems where simultaneous transport of gas and liquid into and/or out of the electrode is required. The electrode includes catalytic electrode particles having diameters ranging from about 25 to 100 angstroms. The catalytic electrode particles are anchored to a support network in clusters which have internal pores ranging in size from 25 to 100 angstroms. The pores between the clusters range in size from between about 1 to 20 microns. A method for making the dual porosity electrodes is also disclosed.

  16. Dual porosity gas evolving electrode

    DOE Patents [OSTI]

    Townsend, Carl W.

    1994-01-01

    A dual porosity electrode for use in thermoelectrochemical systems where simultaneous transport of gas and liquid into and/or out of the electrode is required. The electrode includes catalytic electrode particles having diameters ranging from about 25 to 100 angstroms. The catalytic electrode particles are anchored to a support network in clusters which have internal pores ranging in size from 25 to 100 angstroms. The pores between the clusters range in size from between about 1 to 20 microns. A method for making the dual porosity electrodes is also disclosed.

  17. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes. Volume 2, Duct spray drying: Final report

    SciTech Connect (OSTI)

    Jozewicz, W.; Rochelle, G.T.

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide [Ca(OH){sub 2}] slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  18. Virtual electrodes for high-density electrode arrays

    DOE Patents [OSTI]

    Cela, Carlos J.; Lazzi, Gianluca

    2015-10-13

    The present embodiments are directed to implantable electrode arrays having virtual electrodes. The virtual electrodes may improve the resolution of the implantable electrode array without the burden of corresponding complexity of electronic circuitry and wiring. In a particular embodiment, a virtual electrode may include one or more passive elements to help steer current to a specific location between the active electrodes. For example, a passive element may be a metalized layer on a substrate that is adjacent to, but not directly connected to an active electrode. In certain embodiments, an active electrode may be directly coupled to a power source via a conductive connection. Beneficially, the passive elements may help to increase the overall resolution of the implantable array by providing additional stimulation points without requiring additional wiring or driver circuitry for the passive elements.

  19. Electrochemical device and process of making

    DOE Patents [OSTI]

    Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2004-07-27

    A process of making an electrochemical device comprising providing a trilayer structure comprising an electrode/electrolyte/electrode and simultaneously sintering the trilayer structure.

  20. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Durable Fuel Cell Membrane Electrode Assembly (MEA) A revolutionary method of building a membrane electrode assembly (MEA) for...

  1. Desalination with carbon aerogel electrodes

    SciTech Connect (OSTI)

    Farmer, J.C.; Richardson, J.H.; Fix, D.V.

    1996-10-21

    An electrically regenerated electrosorption process known as carbon aerogel CDI was developed for continuously removing ionic impurities from aqueous streams. A salt solution flows in a channel formed by pairs of parallel carbon aerogel electrodes. Each electrode has a very high BET surface area and very low resistivity. After polarization, anions and cations are removed from electrolyte by the electric field and electrosorbed onto the carbon aerogel. The solution is thus separated into two streams, brine and water. Based on this, carbon aerogel CDI appears to be an energy-efficient alternative to evaporation, electrodialysis, and reverse osmosis. The energy required by this process is about QV/2, plus losses. Estimated energy requirement for sea water desalination is 18-27 Wh gal{sup -1}, depending on cell voltage and flow rate. The requirement for brackish water desalination is less, 1.2-2.5 Wh gal{sup -1} at 1600 ppM. This is assuming that stored electrical energy is reclaimed during regeneration.

  2. Battery electrode growth accommodation

    DOE Patents [OSTI]

    Bowen, Gerald K.; Andrew, Michael G.; Eskra, Michael D.

    1992-01-01

    An electrode for a lead acid flow through battery, the grids including a plastic frame, a plate suspended from the top of the frame to hang freely in the plastic frame and a paste applied to the plate, the paste being free to allow for expansion in the planar direction of the grid.

  3. Layered method of electrode for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R. (Murrysville, PA)

    1991-07-30

    A process for fabricating a fuel electrode comprising: slurry dipping to form layers which are structurally graded from all or mostly all stabilized zirconia at a first layer, to an outer most layer of substantially all metal powder, such an nickel. Higher performaance fuel electrodes may be achieved if sinter active stabilized zirconia doped for electronic conductivity is used.

  4. Overcoming Processing Cost Barriers of High-Performance Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing Cost Barriers of High-Performance Lithium-IonBattery Electrodes Overcoming Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes 2012 DOE Hydrogen ...

  5. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R.

    1990-01-01

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used.

  6. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, R.R.

    1990-11-20

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used. 5 figs.

  7. Freeze drying method

    DOE Patents [OSTI]

    Coppa, Nicholas V.; Stewart, Paul; Renzi, Ernesto

    1999-01-01

    The present invention provides methods and apparatus for freeze drying in which a solution, which can be a radioactive salt dissolved within an acid, is frozen into a solid on vertical plates provided within a freeze drying chamber. The solid is sublimated into vapor and condensed in a cold condenser positioned above the freeze drying chamber and connected thereto by a conduit. The vertical positioning of the cold condenser relative to the freeze dryer helps to help prevent substances such as radioactive materials separated from the solution from contaminating the cold condenser. Additionally, the system can be charged with an inert gas to produce a down rush of gas into the freeze drying chamber to also help prevent such substances from contaminating the cold condenser.

  8. Freeze drying apparatus

    DOE Patents [OSTI]

    Coppa, Nicholas V.; Stewart, Paul; Renzi, Ernesto

    2001-01-01

    The present invention provides methods and apparatus for freeze drying in which a solution, which can be a radioactive salt dissolved within an acid, is frozen into a solid on vertical plates provided within a freeze drying chamber. The solid is sublimated into vapor and condensed in a cold condenser positioned above the freeze drying chamber and connected thereto by a conduit. The vertical positioning of the cold condenser relative to the freeze dryer helps to help prevent substances such as radioactive materials separated from the solution from contaminating the cold condenser. Additionally, the system can be charged with an inert gas to produce a down rush of gas into the freeze drying chamber to also help prevent such substances from contaminating the cold condenser.

  9. Freeze drying method

    SciTech Connect (OSTI)

    Coppa, N.V.; Stewart, P.; Renzi, E.

    1999-12-07

    The present invention provides methods and apparatus for freeze drying in which a solution, which can be a radioactive salt dissolved within an acid, is frozen into a solid on vertical plates provided within a freeze drying chamber. The solid is sublimated into vapor and condensed in a cold condenser positioned above the freeze drying chamber and connected thereto by a conduit. The vertical positioning of the cold condenser relative to the freeze dryer helps to help prevent substances such as radioactive materials separated from the solution from contaminating the cold condenser. Additionally, the system can be charged with an inert gas to produce a down rush of gas into the freeze drying chamber to also help prevent such substances from contaminating the cold condenser.

  10. High Performance Binderless Electrodes for Rechargeable Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Performance Binderless Electrodes for Rechargeable Lithium Batteries National ... Electrode for fast-charging Lithium Ion Batteries, Accelerating Innovation Webinar ...

  11. Inert electrode connection

    DOE Patents [OSTI]

    Weyand, John D. (Greensburg, PA); Woods, Robert W. (New Kensington, PA); DeYoung, David H. (Plum Boro, PA); Ray, Siba P. (Plum Boro, PA)

    1985-01-01

    An inert electrode connection is disclosed wherein a layer of inert electrode material is bonded to a layer of conductive material by providing at least one intermediate layer of material therebetween comprising a predetermined ratio of inert material to conductive material. In a preferred embodiment, the connection is formed by placing in a die a layer of powdered inert material, at least one layer of a mixture of powdered inert material and conductive material, and a layer of powdered conductive material. The connection is then formed by pressing the material at 15,000-20,000 psi to form a powder compact and then densifying the powder compact in an inert or reducing atmosphere at a temperature of 1200.degree.-1500.degree. C.

  12. Catalyzed enzyme electrodes

    DOE Patents [OSTI]

    Zawodzinski, Thomas A.; Wilson, Mahlon S.; Rishpon, Judith; Gottesfeld, Shimshon

    1993-01-01

    An enzyme electrode is prepared with a composite coating on an electrical conductor. The composite coating is formed from a casting solution of a perfluorosulfonic acid polymer, an enzyme, and a carbon supported catalyst. The solution may be cast directly on the conductor surface or may be formed as a membrane and applied to the surface. The perfluorosulfonic acid ionomer formed from the casting solution provides an insoluble biocompatible protective matrix for the enzyme and acts to retain the enzyme for long term availability in the electrode structure. The carbon supported catalyst provides catalytic sites throughout the layer for the oxidation of hydrogen peroxide from the enzyme reactions. The carbon support then provides a conductive path for establishing an electrical signal to the electrical conductor. In one embodiment, the electrical conductor is a carbon cloth that permits oxygen or other gas to be introduced to the perfluorosulfonic polymer to promote the enzyme reaction independent of oxygen in the solution being tested.

  13. Magnetohydrodynamic generator electrode

    DOE Patents [OSTI]

    Marchant, David D.; Killpatrick, Don H.; Herman, Harold; Kuczen, Kenneth D.

    1979-01-01

    An improved electrode for use as a current collector in the channel of a magnetohydrodynamid (MHD) generator utilizes an elongated monolithic cap of dense refractory material compliantly mounted to the MHD channel frame for collecting the current. The cap has a central longitudinal channel which contains a first layer of porous refractory ceramic as a high-temperature current leadout from the cap and a second layer of resilient wire mesh in contact with the first layer as a low-temperature current leadout between the first layer and the frame. Also described is a monolithic ceramic insulator compliantly mounted to the frame parallel to the electrode by a plurality of flexible metal strips.

  14. Long life reference electrode

    DOE Patents [OSTI]

    Yonco, R.M.; Nagy, Z.

    1989-04-04

    An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservoir and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved. 2 figs.

  15. Long life reference electrode

    DOE Patents [OSTI]

    Yonco, Robert M.; Nagy, Zoltan

    1989-01-01

    An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservior and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved.

  16. Long life reference electrode

    DOE Patents [OSTI]

    Yonco, R.M.; Nagy, Z.

    1987-07-30

    An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservoir and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved. 2 figs.

  17. Modifying the organic/electrode interface in Organic Solar Cells (OSCs) and improving the efficiency of solution-processed phosphorescent Organic Light-Emitting Diodes (OLEDs)

    SciTech Connect (OSTI)

    Xiao, Teng

    2012-04-27

    Organic semiconductors devices, such as, organic solar cells (OSCs), organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs) have drawn increasing interest in recent decades. As organic materials are flexible, light weight, and potentially low-cost, organic semiconductor devices are considered to be an alternative to their inorganic counterparts. This dissertation will focus mainly on OSCs and OLEDs. As a clean and renewable energy source, the development of OSCs is very promising. Cells with 9.2% power conversion efficiency (PCE) were reported this year, compared to < 8% two years ago. OSCs belong to the so-called third generation solar cells and are still under development. While OLEDs are a more mature and better studied field, with commercial products already launched in the market, there are still several key issues: (1) the cost of OSCs/OLEDs is still high, largely due to the costly manufacturing processes; (2) the efficiency of OSCs/OLEDs needs to be improved; (3) the lifetime of OSCs/OLEDs is not sufficient compared to their inorganic counterparts; (4) the physics models of the behavior of the devices are not satisfactory. All these limitations invoke the demand for new organic materials, improved device architectures, low-cost fabrication methods, and better understanding of device physics. For OSCs, we attempted to improve the PCE by modifying the interlayer between active layer/metal. We found that ethylene glycol (EG) treated poly(3,4-ethylenedioxythiophene): polystyrenesulfonate (PEDOT: PSS) improves hole collection at the metal/polymer interface, furthermore it also affects the growth of the poly(3- hexylthiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM) blends, making the phase segregation more favorable for charge collection. We then studied organic/inorganic tandem cells. We also investigated the effect of a thin LiF layer on the hole-collection of copper phthalocyanine (CuPc)/C70-based small molecular OSCs. A thin LiF layer serves typically as the electron injection layer in OLEDs and electron collection interlayer in the OSCs. However, several reports showed that it can also assist in holeinjection in OLEDs. Here we first demonstrate that it assists hole-collection in OSCs, which is more obvious after air-plasma treatment, and explore this intriguing dual role. For OLEDs, we focus on solution processing methods to fabricate highly efficient phosphorescent OLEDs. First, we investigated OLEDs with a polymer host matrix, and enhanced charge injection by adding hole- and electron-transport materials into the system. We also applied a hole-blocking and electron-transport material to prevent luminescence quenching by the cathode. Finally, we substituted the polymer host by a small molecule, to achieve more efficient solution processed small molecular OLEDs (SMOLEDs); this approach is cost-effective in comparison to the more common vacuum thermal evaporation. All these studies help us to better understand the underlying relationship between the organic semiconductor materials and the OSCs and OLEDs performance and will subsequently assist in further enhancing the efficiencies of OSCs and OLEDs. With better efficiency and longer lifetime, the OSCs and OLEDs will be competitive with their inorganic counterparts.

  18. Membrane reference electrode

    DOE Patents [OSTI]

    Redey, Laszlo; Bloom, Ira D.

    1989-01-01

    A reference electrode utilizes a small thin, flat membrane of a highly conductive glass placed on a small diameter insulator tube having a reference material inside in contact with an internal voltage lead. When the sensor is placed in a non-aqueous ionic electrolytic solution, the concentration difference across the glass membrane generates a low voltage signal in precise relationship to the concentration of the species to be measured with high spatial resolution.

  19. battery electrode percolating network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery electrode percolating network - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  20. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, H.R.; Bevolo, A.J.; Danielson, G.C.; Weber, M.F.

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A/sub x/WO/sub 3/ where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt/sub y/WO/sub 3/ where y is at least 0.8.

  1. Nickel anode electrode

    DOE Patents [OSTI]

    Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

    1987-01-01

    A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

  2. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, Howard R. (Ames, IA); Bevolo, Albert J. (Ames, IA); Danielson, Gordon C. (Ames, IA); Weber, Michael F. (Wichita, KS)

    1980-11-04

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

  3. Membrane reference electrode

    DOE Patents [OSTI]

    Redey, L.; Bloom, I.D.

    1988-01-21

    A reference electrode utilizes a small thin, flat membrane of a highly conductive glass placed on a small diameter insulator tube having a reference material inside in contact with an internal voltage lead. When the sensor is placed in a non-aqueous ionic electrolytic solution, the concentration difference across the glass membrane generates a low voltage signal in precise relationship to the concentration of the species to be measured, with high spatial resolution. 2 figs.

  4. Shielded capacitive electrode

    DOE Patents [OSTI]

    Kireeff Covo, Michel

    2013-07-09

    A device is described, which is sensitive to electric fields, but is insensitive to stray electrons/ions and unlike a bare, exposed conductor, it measures capacitively coupled current while rejecting currents due to charged particle collected or emitted. A charged particle beam establishes an electric field inside the beam pipe. A grounded metallic box with an aperture is placed in a drift region near the beam tube radius. The produced electric field that crosses the aperture generates a fringe field that terminates in the back surface of the front of the box and induces an image charge. An electrode is placed inside the grounded box and near the aperture, where the fringe fields terminate, in order to couple with the beam. The electrode is negatively biased to suppress collection of electrons and is protected behind the front of the box, so the beam halo cannot directly hit the electrode and produce electrons. The measured signal shows the net potential (positive ion beam plus negative electrons) variation with time, as it shall be observed from the beam pipe wall.

  5. Transparent electrode for optical switch

    DOE Patents [OSTI]

    Goldhar, Julius; Henesian, Mark A.

    1986-01-01

    A low pressure gas electrode utilizing ionized gas in a glow discharge regime forms a transparent electrode for electro-optical switches. The transparent electrode comprises a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the electrode is a transparent electrode. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. The plasma can be created either by the main high voltage pulser used to charge up the crystal or by auxiliary discharges or external sources of ionization. A typical configuration utilizes 10 torr argon in the discharge region adjacent to each crystal face.

  6. Electrode array for neural stimulation

    DOE Patents [OSTI]

    Wessendorf, Kurt O.; Okandan, Murat; Stein, David J.; Yang, Pin; Cesarano, III, Joseph; Dellinger, Jennifer

    2011-08-16

    An electrode array for neural stimulation is disclosed which has particular applications for use in a retinal prosthesis. The electrode array can be formed as a hermetically-sealed two-part ceramic package which includes an electronic circuit such as a demultiplexer circuit encapsulated therein. A relatively large number (up to 1000 or more) of individually-addressable electrodes are provided on a curved surface of a ceramic base portion the electrode array, while a much smaller number of electrical connections are provided on a ceramic lid of the electrode array. The base and lid can be attached using a metal-to-metal seal formed by laser brazing. Electrical connections to the electrode array can be provided by a flexible ribbon cable which can also be used to secure the electrode array in place.

  7. Drying '86. Volume 1-2

    SciTech Connect (OSTI)

    Mujumdar, A.S. )

    1986-01-01

    These proceedings contain 123 papers grouped under the headings of: Drying theory and modelling; Drying of granular materials; Spray drying; Drying of paper and wood products; Drying of foodstuff and biomaterials; Drying of agricultural products and grains; Superheated steam drying; Industrial drying systems and novel dryers; Use of solar energy in drying; Measurement and control of humidity and moisture; and Dewatering.

  8. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. [Coal pyrite electrodes

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-01-01

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eighth quarter, wet chemical and dry oxidation tests were done on Upper Freeport coal from the Troutville [number sign]2 Mine, Clearfield County, Pennsylvania. In addition electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania.

  9. Ceramic component for electrodes

    DOE Patents [OSTI]

    Marchant, David D.; Bates, J. Lambert

    1980-01-01

    A ceramic component suitable for preparing MHD generator electrodes having the compositional formula: Y.sub.x (Mg.sub.y Cr.sub.z).sub.w Al.sub.(1-w) O.sub.3 where x=0.9 to 1.05, y=0.02 to 0.2, z=0.8 to 1.05 and w=1.0 to 0.5. The component is resistant to the formation of hydration products in an MHD environment, has good electrical conductivity and exhibits a lower electrochemical corrosion rate than do comparable compositions of lanthanum chromite.

  10. Gelcasting compositions having improved drying characteristics and machinability

    DOE Patents [OSTI]

    Janney, Mark A.; Walls, Claudia A. H.

    2001-01-01

    A gelcasting composition has improved drying behavior, machinability and shelf life in the dried and unfired state. The composition includes an inorganic powder, solvent, monomer system soluble in the solvent, an initiator system for polymerizing the monomer system, and a plasticizer soluble in the solvent. Dispersants and other processing aides to control slurry properties can be added. The plasticizer imparts an ability to dry thick section parts, to store samples in the dried state without cracking under conditions of varying relative humidity, and to machine dry gelcast parts without cracking or chipping. A method of making gelcast parts is also disclosed.

  11. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng; Wen, Jian; Chen, Jinghua; Huang, Zhongping; Wang, Dezhi

    2006-12-12

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  12. Coated carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng; Wen, Jian; Chen, Jinghua; Huang, Zhongping; Wang, Dezhi

    2008-10-28

    The present invention provides conductive carbon nanotube (CNT) electrode materials comprising aligned CNT substrates coated with an electrically conducting polymer, and the fabrication of electrodes for use in high performance electrical energy storage devices. In particular, the present invention provides conductive CNTs electrode material whose electrical properties render them especially suitable for use in high efficiency rechargeable batteries. The present invention also provides methods for obtaining surface modified conductive CNT electrode materials comprising an array of individual linear, aligned CNTs having a uniform surface coating of an electrically conductive polymer such as polypyrrole, and their use in electrical energy storage devices.

  13. Spray-drying FGD

    SciTech Connect (OSTI)

    Yeager, K.

    1984-05-01

    Limited data are available on spray drying for SO/SUB/2 and particulate control to enable utilities to evaluate the claims of vendors. EPRI is sponsoring pilot- and full-scale testing of this technology and some results are presented.

  14. Dry piston coal feeder

    DOE Patents [OSTI]

    Hathaway, Thomas J.; Bell, Jr., Harold S.

    1979-01-01

    This invention provides a solids feeder for feeding dry coal to a pressurized gasifier at elevated temperatures substantially without losing gas from the gasifier by providing a lock having a double-acting piston that feeds the coals into the gasifier, traps the gas from escaping, and expels the trapped gas back into the gasifier.

  15. Biomass drying technologies. Final report, September 1997--May 1998

    SciTech Connect (OSTI)

    Salomaa, E.

    1998-07-01

    The report examines the technologies used for drying of biomass and the energy requirements of biomass dryers. Biomass drying processes, drying methods, and the conventional types of dryers are surveyed generally. Drying methods and dryer studies using superheated steam as the drying medium are discussed more closely, with comparison to the methods of drying using air or flue gas as the drying medium. Available types of steam dryers are described with reference to operating conditions, energy requirements, and types of biomass dried. Energy aspects are considered, as well as possibilities of steam utilization to recover the latent heat of vaporization. Thermal energy required for drying of biomass is calculated using tabulated values of steam properties. The amount of steam to provide the thermal energy needed for biomass drying, at different pressures and temperatures applicable in steam dryers, is calculated for both indirectly and directly heated steam dryers. The calculated heat requirement values of steam dryers have been compared with those reported in the literature. Further, anticipated emissions from flue gas and steam drying processes have been summarized.

  16. Electrical resistance tomography using steel cased boreholes as long electrodes

    SciTech Connect (OSTI)

    Daily, W; Newmark, R L; Ramirez, A

    1999-07-20

    Electrical resistance tomography (ERT) using multiple electrodes installed in boreholes has been shown to be useful for both site characterization and process monitoring. In some cases, however, installing multiple downhole electrodes is too costly (e.g., deep targets) or risky (e.g., contaminated sites). For these cases we have examined the possibility of using the steel casings of existing boreholes as electrodes. Several possibilities can be considered. The first case we investigated uses an array of steel casings as electrodes. This results in very few data and thus requires additional constraints to limit the domain of possible inverse solutions. Simulations indicate that the spatial resolution and sensitivity are understandably low but it is possible to coarsely map the lateral extent of subsurface processes such as steam floods. The second case uses an array of traditional point borehole electrodes combined with long-conductor electrodes (steel casings). Although this arrangement provides more data, in many cases it results in poor reconstructions of test targets. Results indicate that this method may hold promise for low resolution imaging where steel casings can be used as electrodes but the merits depend strongly on details of each application. Field tests using these configurations are currently being conducted.

  17. Electrical resistance tomography using steel cased boreholes as electrodes

    SciTech Connect (OSTI)

    Newmark, R L; Daily, W; Ramirez, A

    1999-03-22

    Electrical resistance tomography (ERT) using multiple electrodes installed in boreholes has been shown to be useful for both site characterization and process monitoring. In some cases, however, installing multiple downhole electrodes is too costly (e.g., deep targets) or risky (e.g., contaminated sites). For these cases we have examined the possibility of using the steel casings of existing boreholes as electrodes. The first case we investigated used an array of steel casings as electrodes. This results in very few data and thus requires additional constraints to limit the domain of possible inverse solutions. Simulations indicate that the spatial resolution and sensitivity are understandably low but it is possible to coarsely map the lateral extent of subsurface processes such as steam floods. A hybrid case uses traditional point electrode arrays combined with long-conductor electrodes (steel casings). Although this arrangement provides more data, in many cases it results in poor reconstructions of test targets. Results indicate that this method may hold promise for low resolution imaging where steel casings can be used as electrodes.

  18. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Print Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS) under operating conditions ("in operando"), researchers have found that the

  19. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Print Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS) under operating conditions ("in operando"), researchers have found that the

  20. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Print Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS) under operating conditions ("in operando"), researchers have found that the

  1. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Print Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS) under operating conditions ("in operando"), researchers have found that the

  2. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Print Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS) under operating conditions ("in operando"), researchers have found that the

  3. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectroscopy of Supercapacitor Electrodes In Operando Print Future technology will require energy storage systems that have much larger storage capability, rapid charge/discharge cycling, and improved endurance. Progress in these areas demands a more complete understanding of the processes involved in energy storage, from the atomic scale to the device level. Now, using soft x-ray absorption spectroscopy (XAS) under operating conditions ("in operando"), researchers have found that the

  4. Electrochromic counter electrode

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Jorgensen, Gary J.

    2005-02-22

    The present invention discloses an amorphous material comprising nickel oxide doped with tantalum that is an anodically coloring electrochromic material. The material of the present invention is prepared in the form of an electrode (200) having a thin film (202) of an electrochromic material of the present invention residing on a transparent conductive film (203). The material of the present invention is also incorporated into an electrochromic device (100) as a thin film (102) in conjunction with a cathodically coloring prior art electrochromic material layer (104) such that the devices contain both anodically coloring (102) and cathodically coloring (104) layers. The materials of the electrochromic layers in these devices exhibit broadband optical complimentary behavior, ionic species complimentary behavior, and coloration efficiency complimentary behavior in their operation.

  5. Low resistance electrode construction

    DOE Patents [OSTI]

    Redey, Laszlo; Karell, Eric J.

    2002-01-01

    An electrochemical cell having a cathode and an anode in contact with an electrolyte. Both electrodes or one of them has an electrically conducting non-metal receptacle defining a chamber with a first metal having a melting point in the range of from about room temperature to about 800.degree. C. inside said receptacle chamber. A second metal with a melting point greater than about 800.degree. C. is in contact with the first metal inside the receptacle chamber and extends outside of the receptacle chamber to form a terminal for the anode. The electrolyte may include the oxides, halides or mixtures thereof of one or more of Li, V, U, Al and the lanthanides. Metal may be produced at the cathode during operation of the cell and oxygen or chlorine at the anode.

  6. Ribbed electrode substrates

    DOE Patents [OSTI]

    Breault, Richard D.; Goller, Glen J.

    1983-01-01

    A ribbed substrate for an electrochemical cell electrode is made from a mixture of carbon fibers and carbonizable resin and has a mean pore size in the ribs which is 60-75% of the mean pore size of the web portions of the substrate which interconnect the ribs. Preferably the mean pore size of the web portion is 25-45 microns; and, if the substrate includes edge seals parallel to the ribs, the edge seals preferably have a mean pore size no greater than about ten microns. Most preferably the substrate has the same ratio of carbon fibers to polymeric carbon in all areas, including the ribs, webs, and edge seals. A substrate according to the present invention will have better overall performance than prior art substrates and minimizes the substrate thickness required for the substrate to perform all its functions well.

  7. Draft dry year tools (generation/planning)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BPA White Book Dry Year Tools Firstgov Dry Year Tools November 9, 2006 - Final Dry Year Guide: The Final Dry Year Guide (PDF, 5 pages, 44 kb) and Figure 1 - Dry Year Strategy (PDF,...

  8. Composite electrode/electrolyte structure

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2004-01-27

    Provided is an electrode fabricated from highly electronically conductive materials such as metals, metal alloys, or electronically conductive ceramics. The electronic conductivity of the electrode substrate is maximized. Onto this electrode in the green state, a green ionic (e.g., electrolyte) film is deposited and the assembly is co-fired at a temperature suitable to fully densify the film while the substrate retains porosity. Subsequently, a catalytic material is added to the electrode structure by infiltration of a metal salt and subsequent low temperature firing. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in ionic (electrochemical) devices such as fuel cells and electrolytic gas separation systems.

  9. Electrode for a lithium cell

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2008-10-14

    This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

  10. Dry Natural Gas

    U.S. Energy Information Administration (EIA) Indexed Site

    Estimated natural gas plant liquids and dry natural gas content of total natural gas proved reserves, 2014 million barrels and billion cubic feet 2014 Dry Natural Gas billion cubic feet billion cubic feet Alaska 6,805 241 6,745 Lower 48 States 382,036 14,788 361,959 Alabama 2,121 59 2,036 Arkansas 12,795 5 12,789 California 2,260 112 2,107 Coastal Region Onshore 277 12 261 Los Angeles Basin Onshore 84 4 80 San Joaquin Basin Onshore 1,823 96 1,690 State Offshore 76 0 76 Colorado 21,992 813 20,851

  11. Session: Hot Dry Rock

    SciTech Connect (OSTI)

    Tennyson, George P. Jr.; Duchane, David V.; Ponden, Raymond F.; Brown, Donald W.

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of four presentations: ''Hot Dry Rock - Summary'' by George P. Tennyson, Jr.; ''HDR Opportunities and Challenges Beyond the Long Term Flow Test'' by David V. Duchane; ''Start-Up Operations at the Fenton Hill HDR Pilot Plant'' by Raymond F. Ponden; and ''Update on the Long-Term Flow Testing Program'' by Donald W. Brown.

  12. Ultrasonic Clothes Drying Technology

    ScienceCinema (OSTI)

    Patel, Viral; Momen, Ayyoub

    2016-05-12

    Oak Ridge National Laboratory researchers Ayyoub Momen and Viral Patel demonstrate a direct contact ultrasonic clothes dryer under development by ORNL in collaboration with General Electric (GE) Appliances. This novel approach uses high-frequency mechanical vibrations instead of heat to extract moisture as cold mist, dramatically reducing drying time and energy use. Funding for this project was competitively awarded by DOE?s Building Technologies Office in 2014. For more information please contact momena@ornl.gov.

  13. Smooth electrode and method of fabricating same

    DOE Patents [OSTI]

    Weaver, Stanton Earl (Northville, NY); Kennerly, Stacey Joy (Albany, NY); Aimi, Marco Francesco (Niskayuna, NY)

    2012-08-14

    A smooth electrode is provided. The smooth electrode includes at least one metal layer having thickness greater than about 1 micron; wherein an average surface roughness of the smooth electrode is less than about 10 nm.

  14. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Screening of Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrodes Vehicle Technologies Office Merit Review 2015: Materials Benchmarking Activities for ...

  15. characterizing lithium-ion electrode microstructures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    characterizing lithium-ion electrode microstructures - Sandia Energy Energy Search Icon ... SunShot Grand Challenge: Regional Test Centers characterizing lithium-ion electrode ...

  16. Simplified Electrode Formation using Stabilized Lithium Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simplified Electrode Formation using Stabilized Lithium Metal Powder (SLMP) Doping of Lithium Ion Battery Electrodes Lawrence Berkeley National Laboratory Contact LBL About This ...

  17. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials ...

  18. Development of Industrially Viable Battery Electrode Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies ...

  19. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the electrode is largely due to the paucity of experimental and theoretical methods for characterization of the electrode electronic structure during operation. A team led by...

  20. Lithium Air Electrodes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Air Electrodes Pacific Northwest National Laboratory Contact PNNL About This Technology A comparison chart illustrates that Li-Air electrodes offer the highest energy ...

  1. MHD Electrode and wall constructions

    DOE Patents [OSTI]

    Way, Stewart; Lempert, Joseph

    1984-01-01

    Electrode and wall constructions for the walls of a channel transmitting the hot plasma in a magnetohydrodynamic generator. The electrodes and walls are made of a plurality of similar modules which are spaced from one another along the channel. The electrodes can be metallic or ceramic, and each module includes one or more electrodes which are exposed to the plasma and a metallic cooling bar which is spaced from the plasma and which has passages through which a cooling fluid flows to remove heat transmitted from the electrode to the cooling bar. Each electrode module is spaced from and electrically insulated from each adjacent module while interconnected by the cooling fluid which serially flows among selected modules. A wall module includes an electrically insulating ceramic body exposed to the plasma and affixed, preferably by mechanical clips or by brazing, to a metallic cooling bar spaced from the plasma and having cooling fluid passages. Each wall module is, similar to the electrode modules, electrically insulated from the adjacent modules and serially interconnected to other modules by the cooling fluid.

  2. Method for producing electrodes using microscale or nanoscale materials obtained from hydrogendriven metallurgical reactions

    DOE Patents [OSTI]

    Reilly, James J.; Adzic, Gordana D.; Johnson, John R.; Vogt, Thomas; McBreen, James

    2003-09-02

    A method is provided for producing electrodes using microscale and nanoscale metal materials formed from hydrogen driven metallurgical processes; such a the HD (hydriding, dehydriding) process, the HDDR (hydriding, dehydriding, disproportionation, and recombination) process, and variants thereof.

  3. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T; Andersson, Anna M

    2014-10-07

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z, or (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001electrodes and storage batteries.

  4. Solid Oxide Fuel Cell Technologies: Improved Electrode-Electrode Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Solid State Electrochemical Devices - Energy Innovation Portal Solid Oxide Fuel Cell Technologies: Improved Electrode-Electrode Structures for Solid State Electrochemical Devices Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryBerkeley Lab researchers Lutgard DeJonghe, Steven Visco, and Craig Jacobson have focused their attention on solid oxide fuel cells (SOFC) and related technologies. Fuel cells "burn" hydrogen or

  5. Cold cap subsidence for in situ vitrification and electrodes therefor

    DOE Patents [OSTI]

    Buelt, James L.; Carter, John G.; Eschbach, Eugene A.; FitzPatrick, Vincent F.; Koehmstedt, Paul L.; Morgan, William C.; Oma, Kenton H.; Timmerman, Craig L.

    1992-01-01

    An electrode for use in in situ vitrification of soil comprises a molybdenum rod received within a conductive sleeve or collar formed of graphite. Electrodes of this type are placed on either side of a region containing buried waste material and an electric current is passed therebetween for vitrifying the soil between the electrodes. The graphite collar enhances the thermal conductivity of the electrode, bringing heat to the surface, and preventing the formation of a cold cap of material above the ground surface. The annulus between the molybdenum rod electrode and the graphite collar is filled with a conductive ceramic powder of a type that sinters upon the molybdenum rod, protecting the same from oxidation as the graphite material is consumed, or a metal powder which liquifies at operating temperatures. The molybdenum rod in the former case may be coated with an oxidation protectant, e.g. of molybdenum disilicide. As insulative blanket is suitably placed on the surface of the soil during processing to promote subsidence by allowing off-gassing and reducing surface heat loss. In other embodiments, connection to vitrification electrodes is provided below ground level to avoid loss of connection due to electrodes deterioration, or a sacrificial electrode may be employed when operation is started. Outboard electrodes can be utilized to square up the vitrified area. Further, the center of the molybdenum rod can be made hollow and filled with a powdered metal, such as copper, which liquifies at operating temperatures. In one embodiment, the molybdenum rod and the graphite collar are physically joined at the bottom.

  6. Method of drying articles

    DOE Patents [OSTI]

    Janney, M.A.; Kiggans, J.O. Jr.

    1999-03-23

    A method of drying a green particulate article includes the steps of: (a) Providing a green article which includes a particulate material and a pore phase material, the pore phase material including a solvent; and (b) contacting the green article with a liquid desiccant for a period of time sufficient to remove at least a portion of the solvent from the green article, the pore phase material acting as a semipermeable barrier to allow the solvent to be sorbed into the liquid desiccant, the pore phase material substantially preventing the liquid desiccant from entering the pores. 3 figs.

  7. Method of drying articles

    DOE Patents [OSTI]

    Janney, Mark A.; Kiggans, Jr., James O.

    1999-01-01

    A method of drying a green particulate article includes the steps of: a. Providing a green article which includes a particulate material and a pore phase material, the pore phase material including a solvent; and b. contacting the green article with a liquid desiccant for a period of time sufficient to remove at least a portion of the solvent from the green article, the pore phase material acting as a semipermeable barrier to allow the solvent to be sorbed into the liquid desiccant, the pore phase material substantially preventing the liquid desiccant from entering the pores.

  8. Solution-processable glass LiI-Li4SnS4 superionic conductors for all-solid-state Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kern Ho Park; Oh, Dae Yang; Choi, Young Eun; Nam, Young Jin; Han, Lili; Kim, Ju -Young; Xin, Huolin; Lin, Feng; Oh, Seung M.; Jung, Yoon Seok

    2015-12-22

    The new, highly conductive (4.1 × 10–4 S cm–1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li4SnS4 is prepared using a homogeneous methanol solution. Furthermore, the solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li4SnS4), resulting in considerable improvements in electrochemical performances of these electrodes over conventional mixture electrodes.

  9. Positive-electrode current collector for liquid-metal cells

    DOE Patents [OSTI]

    Shimotake, H.; Bartholme, L.G.

    1982-09-27

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  10. Positive electrode current collector for liquid metal cells

    DOE Patents [OSTI]

    Shimotake, Hiroshi; Bartholme, Louis G.

    1984-01-01

    A current collector for the positive electrode of an electrochemical cell with a positive electrode including a sulfide. The cell also has a negative electrode and a molten salt electrolyte including halides of a metal selected from the alkali metals and the alkaline earth metals in contact with both the positive and negative electrodes. The current collector has a base metal of copper, silver, gold, aluminum or alloys thereof with a coating thereon of iron, nickel, chromium or alloys thereof. The current collector when subjected to cell voltage forms a sulfur-containing compound on the surface thereby substantially protecting the current collector from further attack by sulfur ions during cell operation. Both electroless and electrolytic processes may be used to deposit coatings.

  11. Eight electrode optical readout gap

    DOE Patents [OSTI]

    Boettcher, G.E.; Crain, R.W.

    1984-01-01

    A protective device for a plurality of electrical circuits includes a plurality of isolated electrodes forming a gap with a common electrode. An output signal, electrically isolated from the circuits being monitored, is obtained by a photosensor viewing the discharge gap through an optical window. Radioactive stabilization of discharge characteristics is provided for slowly changing voltages and carbon tipped dynamic starters provide desirable discharge characteristics for rapidly varying voltages. A hydrogen permeation barrier is provided on external surfaces of the device.

  12. Eight electrode optical readout gap

    DOE Patents [OSTI]

    Boettcher, Gordon E.; Crain, Robert W.

    1985-01-01

    A protective device for a plurality of electrical circuits includes a pluity of isolated electrodes forming a gap with a common electrode. An output signal, electrically isolated from the circuits being monitored, is obtained by a photosensor viewing the discharge gap through an optical window. Radioactive stabilization of discharge characteristics is provided for slowly changing voltages and carbon tipped dynamic starters provide desirable discharge characteristics for rapidly varying voltages. A hydrogen permeation barrier is provided on external surfaces of the device.

  13. High Speed, Low Cost Fabrication of Gas Diffusion Electrodes for Membrane Electrode Assemblies

    SciTech Connect (OSTI)

    DeCastro, Emory S.; Tsou, Yu-Min; Liu, Zhenyu

    2013-09-20

    Fabrication of membrane electrode assemblies (MEAs) depends on creating inks or pastes of catalyst and binder, and applying this suspension to either the membrane (catalyst coated membrane) or gas diffusion media (gas diffusion electrode) and respectively laminating either gas diffusion media or gas diffusion electrodes (GDEs) to the membrane. One barrier to cost effective fabrication for either of these approaches is the development of stable and consistent suspensions. This program investigated the fundamental forces that destabilize the suspensions and developed innovative approaches to create new, highly stable formulations. These more concentrated formulations needed fewer application passes, could be coated over longer and wider substrates, and resulted in significantly lower coating defects. In March of 2012 BASF Fuel Cell released a new high temperature product based on these advances, whereby our customers received higher performing, more uniform MEAs resulting in higher stack build yields. Furthermore, these new materials resulted in an instant increase in capacity due to higher product yields and material throughput. Although not part of the original scope of this program, these new formulations have also led us to materials that demonstrate equivalent performance with 30% less precious metal in the anode. This program has achieved two key milestones in DOEs Manufacturing R&D program: demonstration of processes for direct coating of electrodes and continuous in-line measurement for component fabrication.

  14. Electrodes for solid state gas sensor

    DOE Patents [OSTI]

    Mukundan, Rangachary; Brosha, Eric L.; Garzon, Fernando

    2003-08-12

    A mixed potential electrochemical sensor for the detection of gases has a ceria-based electrolyte with a surface for exposing to the gases to be detected, and with a reference wire electrode and a sensing wire electrode extending through the surface and fixed within the electrolyte as the electrolyte is compressed and sintered. The electrochemical sensor is formed by placing a wire reference electrode and a wire sensing electrode in a die, where each electrode has a first compressed planar section and a second section depending from the first section with the second section of each electrode extending axially within the die. The die is filled with an oxide-electrolyte powder and the powder is pressed within the die with the wire electrodes. The wire-electrodes and the pressed oxide-electrolyte powder are sintered to form a ceramic electrolyte base with a reference wire electrode and a sensing wire electrode depending therefrom.

  15. Electrodes for solid state gas sensor

    DOE Patents [OSTI]

    Mukundan, Rangachary (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM); Garzon, Fernando (Santa Fe, NM)

    2007-05-08

    A mixed potential electrochemical sensor for the detection of gases has a ceria-based electrolyte with a surface for exposing to the gases to be detected, and with a reference wire electrode and a sensing wire electrode extending through the surface and fixed within the electrolyte as the electrolyte is compressed and sintered. The electrochemical sensor is formed by placing a wire reference electrode and a wire sensing electrode in a die, where each electrode has a first compressed planar section and a second section depending from the first section with the second section of each electrode extending axially within the die. The die is filled with an oxide-electrolyte powder and the powder is pressed within the die with the wire electrodes. The wire-electrodes and the pressed oxide-electrolyte powder are sintered to form a ceramic electrolyte base with a reference wire electrode and a sensing wire electrode depending therefrom.

  16. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T.; Andersson, Anna M.

    2012-04-03

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  17. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T.; Andersson, Anna M.

    2008-03-18

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z(A.sub.1-aM''.sub.a).s- ub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  18. Extraction electrode geometry for a calutron

    DOE Patents [OSTI]

    Veach, A.M.; Bell, W.A. Jr.

    1975-09-23

    This patent relates to an improved geometry for the extraction electrode and the ground electrode utilized in the operation of a calutron. The improved electrodes are constructed in a partial-picture-frame fashion with the slits of both electrodes formed by two tungsten elongated rods. Additional parallel spaced-apart rods in each electrode are used to establish equipotential surfaces over the rest of the front of the ion source. (auth)

  19. Mathematical models of cocurrent spray drying

    SciTech Connect (OSTI)

    Negiz, A.; Lagergren, E.S.; Cinar, A.

    1995-10-01

    A steady state mathematical model for a cocurrent spray dryer is developed. The model includes the mass, momentum, and energy balances for a single drying droplet as well as the total energy and mass balances of the drying medium. A log normal droplet size distribution is assumed to hold at the exit of the twin-fluid atomizer located at the top of the drying chamber. The discretization of this log normal distribution with a certain number of bins yields a system of nonlinear coupled first-order differential equations as a function of the axial distance of the drying chamber. This system of equations is used to compute the axial changes in droplet diameter, density, velocity, moisture, and temperature for the droplets at each representative bin. Furthermore, the distributions of important process parameters such as droplet moisture content, diameter, density, and temperature are also obtainable along the length of the chamber. On the basis of the developed model, a constrained nonlinear optimization problem is solved, where the exit particle moisture content is minimized with respect to the process inputs subjected to a fixed mean particle diameter at the chamber exit. Response surface studies based on empirical models are also performed to illustrate the effectiveness of these techniques in achieving the optimal solution when an a priori model is not available. The structure of empirical models obtained from the model is shown to be in agreement with the structure of the empirical models obtained from the experimental studies.

  20. Desalination with carbon aerogel electrodes. Revision 1

    SciTech Connect (OSTI)

    Farmer, J.C.; Richardson, J.H.; Fix, D.V. [Lawrence Livermore National Lab., CA (United States); Thomson, S.L.; May, S.C. [Bechtel National, Inc., San Francisco, CA (United States)

    1996-12-04

    Electrically regenerated electrosorption process (carbon aerogel CDI) was developed by LLNL for continuously removing ionic impurities from aqueous streams. A salt solution flows in a channel formed by numerous pairs of parallel carbon aerogel electrodes. Each electrode has a very high BET surface area (2-5.4x10{sup 6}ft{sup 2}lb{sup -1} or 400-1100 m{sup 2}g{sup -1}) and very low electrical resistivity ({le}40 m{Omega}). Ions are removed from the electrolyte by the electric field and electrosorbed onto the carbon aerogel. It is concluded that carbon aerogel CDI may be an energy-efficient alternative to electrodialysis and reverse osmosis for desalination of brackish water ({le}5000 ppM). The intrinsic energy required by this process is about QV/2, where Q is the stored electrical charge and V is the voltage between the electrodes, plus losses. Estimated requirement for desalination of a 2000 ppM feed is -0.53-2.5 Wh/gal{sup -1} (0.5-2.4 kJ L{sup -1}), depending on voltage, flow rate, cell dimensions, aerogel density, recovery ratio, etc. This assumes that 50-70% of the stored electrical energy is reclaimed during regeneration (electrical discharge). Though the energy requirement for desalination of sea water is also low, this application will be much more difficult. Additional work will be required for desalination of streams that contain more than 5000 ppM total dissolved solids (2000 ppM will require electrochemical cells with extremely tight, demanding tolerances). At this present time, the process is best suited for streams with dilute impurities, as recently demonstrated during a field test at LLNL Treatment Facility C.

  1. Carbon film electrodes for super capacitor applications

    DOE Patents [OSTI]

    Tan, Ming X.

    1999-01-01

    A microporous carbon film for use as electrodes in energy strorage devices is disclosed, which is made by the process comprising the steps of: (1) heating a polymer film material consisting essentially of a copolymer of polyvinylidene chloride and polyvinyl chloride in an inert atmosphere to form a carbon film; and (2) activating said carbon film to form said microporous carbon film having a density between about 0.7 g/cm.sup.2 and 1 g/cm.sup.2 and a gravimetric capacitance of about between 120 F/g and 315 F/g.

  2. Organic light emitting diodes with structured electrodes

    DOE Patents [OSTI]

    Mao, Samuel S.; Liu, Gao; Johnson, Stephen G.

    2012-12-04

    A cathode that contain nanostructures that extend into the organic layer of an OLED has been described. The cathode can have an array of nanotubes or a layer of nanoclusters extending out from its surface. In another arrangement, the cathode is patterned and etched to form protruding nanostructures using a standard lithographic process. Various methods for fabricating these structures are provided, all of which are compatible with large-scale manufacturing. OLEDs made with these novel electrodes have greatly enhanced electron injection, have good environmental stability.

  3. Carbon film electrodes for super capacitor applications

    SciTech Connect (OSTI)

    Tan, M.X.

    1999-11-30

    A microporous carbon film for use as electrodes in energy storage devices is disclosed, which is made by the process comprising the steps of: (1) heating a polymer film material consisting essentially of a copolymer of polyvinylidene chloride and polyvinyl chloride in an inert atmosphere to form a carbon film; and (2) activating said carbon film to form said microporous carbon film having a density between about 0.7 g/cm{sup 2} and 1 g/cm{sup 2} and a gravimetric capacitance of about between 120 F/g and 315 F/g.

  4. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, S.P.; Woods, R.W.

    1998-08-11

    A process is disclosed for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750 C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5--3000 ppm in order to obtain a desired composition in the resulting composite. 2 figs.

  5. Controlled atmosphere for fabrication of cermet electrodes

    DOE Patents [OSTI]

    Ray, Siba P.; Woods, Robert W.

    1998-01-01

    A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.

  6. No Heat Spray Drying Technology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Objective Advance research from prototype dryer ... First commercial market is dry flavors designed to ... change from existing practice Requires novel dryer ...

  7. DRI Companies | Open Energy Information

    Open Energy Info (EERE)

    Irvine, California Zip: 92614 Sector: Solar Product: US-based residential and commercial installer of turnkey solar systems, through subsidiary iDRI Energy. Coordinates:...

  8. Liquid-phase exfoliation of chemical vapor deposition-grown single layer graphene and its application in solution-processed transparent electrodes for flexible organic light-emitting devices

    SciTech Connect (OSTI)

    Wu, Chaoxing; Li, Fushan E-mail: gtl-fzu@hotmail.com; Wu, Wei; Chen, Wei; Guo, Tailiang E-mail: gtl-fzu@hotmail.com

    2014-12-15

    Efficient and low-cost methods for obtaining high performance flexible transparent electrodes based on chemical vapor deposition (CVD)-grown graphene are highly desirable. In this work, the graphene grown on copper foil was exfoliated into micron-size sheets through controllable ultrasonication. We developed a clean technique by blending the exfoliated single layer graphene sheets with conducting polymer to form graphene-based composite solution, which can be spin-coated on flexible substrate, forming flexible transparent conducting film with high conductivity (?8 ?/?), high transmittance (?81% at 550?nm), and excellent mechanical robustness. In addition, CVD-grown-graphene-based polymer light emitting diodes with excellent bendable performances were demonstrated.

  9. Porous-electrode preparation method

    DOE Patents [OSTI]

    Arons, R.M.; Dusek, J.T.

    1981-09-17

    A porous sintered plaque is provided with a bimodal porosity that is especially well suited for use as an electrode within a molten carbonate fuel cell. The coarse porosity is sufficient for admitting gases into contact with the reaction surfaces while the fine porosity is wetted with and retains molten electrolyte on the reaction sites. The electrode structure is prepared by providing a very fine powder such as nickel oxide and blending the powder with a suitable decomposable binder to form a solid mass. The mass is comminuted into agglomerate size particles substantially larger than the fine oxide particles and formed into a cohesive compact for subsequent sintering. Sintering is carried out at sufficient conditions to bind the agglomerates together into a porous structure having both coarse and fine porosity. Where lithiated nickel oxide cathodes are prepared, the sintering conditions can be moderate enough to retain substantial quantities of lithium within the electrode for adequate conductivity.

  10. Control of edge effects of oxidant electrode

    DOE Patents [OSTI]

    Carr, Peter; Chi, Chen H.

    1981-09-08

    Described is an electrode assembly comprising; a. a porous electrode having a first and second exterior face with a cavity formed in the interior between said exterior faces thereby having first and second interior faces positioned opposite the first and second exterior faces; b. a counter electrode positioned facing each of the first and second exterior faces of the porous electrode; c. means for passing an oxidant through said porous electrode; and d. screening means for blocking the interior face of the porous electrode a greater amount than the blocking of the respective exterior face of the porous electrode, thereby maintaining a differential of oxidant electrode surface between the interior face and the exterior face. The electrode assembly is useful in a metal, halogen, halogen hydrate electrical energy storage device.

  11. Method for manufacturing magnetohydrodynamic electrodes

    DOE Patents [OSTI]

    Killpatrick, D.H.; Thresh, H.R.

    1980-06-24

    A method of manufacturing electrodes for use in a magnetohydrodynamic (MHD) generator is described comprising the steps of preparing a billet having a core of a first metal, a tubular sleeve of a second metal, and an outer sheath of an extrusile metal; evacuating the space between the parts of the assembled billet; extruding the billet; and removing the outer jacket. The extruded bar may be made into electrodes by cutting and bending to the shape required for an MHD channel frame. The method forms a bond between the first metal of the core and the second metal of the sleeve strong enough to withstand a hot and corrosive environment.

  12. Ceramic component for MHD electrode

    DOE Patents [OSTI]

    Marchant, David D.; Bates, Junior L.

    1981-01-01

    A ceramic component which exhibits electrical conductivity down to near room temperatures has the formula: Hf.sub.x In.sub.y A.sub.z O.sub.2 where x=0.1 to 0.4, y=0.3 to 0.6, z=0.1 to 0.4 and A is a lanthanide rare earth or yttrium. The component is suitable for use in the fabrication of MHD electrodes or as the current leadout portion of a composite electrode with other ceramic components.

  13. Reference electrode for electrolytic cell

    DOE Patents [OSTI]

    Kessie, R.W.

    1988-07-28

    A reference electrode device is provided for a high temperature electrolytic cell used to electrolytically recover uranium from spent reactor fuel dissolved in an anode pool, the device having a glass tube to enclose the electrode and electrolyte and serve as a conductive membrane with the cell electrolyte, and an outer metal tube about the glass tube to serve as a shield and basket for any glass sections broken by handling of the tube to prevent their contact with the anode pool, the metal tube having perforations to provide access between the bulk of the cell electrolyte and glass membrane. 4 figs.

  14. Nanofiber membrane-electrode-assembly and method of fabricating same

    DOE Patents [OSTI]

    Pintauro, Peter N.; Ballengee, Jason; Brodt, Matthew

    2016-02-02

    In one aspect of the present invention, a fuel cell membrane-electrode-assembly (MEA) has an anode electrode, a cathode electrode, and a membrane disposed between the anode electrode and the cathode electrode. At least one of the anode electrode, the cathode electrode and the membrane is formed of electrospun nanofibers.

  15. Electrode assembly for a fluidized bed apparatus

    DOE Patents [OSTI]

    Schora, Jr., Frank C.; Matthews, Charles W.; Knowlton, Ted M.

    1976-11-23

    An electrode assembly comprising a high voltage electrode having a generally cylindrical shape and being electrically connected to a high voltage source, where the cylinder walls may be open to flow of fluids and solids; an electrically grounded support electrode supporting said high voltage electrode by an electrically insulating support where both of the electrically grounded and electrically insulating support may be hollow; and an electrically grounded liner electrode arranged concentrically around both the high voltage and support electrodes. This assembly is specifically adapted for use in a fluidized bed chemical reactor as an improved heating means therefor.

  16. METHOD OF FABRICATING ELECTRODES INCLUDING HIGH-CAPACITY, BINDER...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    METHOD OF FABRICATING ELECTRODES INCLUDING HIGH-CAPACITY, BINDER-FREE ANODES FOR LITHIUM-I... Binderless Electrodes for Rechargeable Lithium Batteries Abstract: An electrode (110) is ...

  17. "Analysis of SOFCs using reference electrodes?

    SciTech Connect (OSTI)

    Finklea, Harry; Chen,Xiaoke; Gerdes,Kirk; Pakalapati, Suryanarayana; Celik, Ismail

    2013-07-01

    Reference electrodes are frequently applied to isolate the performance of one electrode in a solid oxide fuel cell. However, reference electrode simulations raise doubt to veracity of data collected using reference electrodes. The simulations predict that the reported performance for the one electrode will frequently contain performance of both electrodes. Nonetheless, recent reports persistently treat data so collected as ideally isolated. This work confirms the predictions of the reference electrode simulations on two SOFC designs, and to provides a method of validating the data measured in the 3-electrode configuration. Validation is based on the assumption that a change in gas composition to one electrode does not affect the impedance of the other electrode at open circuit voltage. This assumption is supported by a full physics simulation of the SOFC. Three configurations of reference electrode and cell design are experimentally examined using various gas flows and two temperatures. Impedance data are subjected to deconvolution analysis and equivalent circuit fitting and approximate polarization resistances of the cathode and anode are determined. The results demonstrate that the utility of reference electrodes is limited and often wholly inappropriate. Reported impedances and single electrode polarization values must be scrutinized on this basis.

  18. Sheet electrode for electrochemical systems

    DOE Patents [OSTI]

    Tsien, Hsue C.; Newby, Kenneth R.; Grimes, Patrick G.; Bellows, Richard J.

    1983-04-12

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  19. Some considerations in simulation of superheated steam drying of softwood lumber

    SciTech Connect (OSTI)

    Pang, S. [New Zealand Forest Research Inst., Rotorua (New Zealand). Wood Processing Div.

    1997-05-01

    A mathematical model for high-temperature drying of softwood lumber with moist air has been modified and extended to simulate wood drying with superheated steam. In the simulation, differences between the two types of drying are considered, these include: external heat and mass transfer processes and calculation of equilibrium moisture content. The external mass transfer coefficient in the superheated steam drying was found to be much higher than that in the moist air drying, however, the heat transfer coefficients for these two cases were of the same order. The predicted drying curves and wood temperatures from the superheated steam drying model were compared with experimental data and there was close agreement. Further studies will apply the model to development of commercial drying schedules for wood drying with superheated steam.

  20. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-07-01

    This report describes research conducted between April 1, 2004 and June 30, 2004 on the preparation and use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Support materials and supported sorbents were prepared by spray drying. Sorbents consisting of 20 to 50% sodium carbonate on a ceramic support were prepared by spray drying in batches of approximately 300 grams. The supported sorbents exhibited greater carbon dioxide capture rates than unsupported calcined sodium bicarbonate in laboratory tests. Preliminary process design and cost estimation for a retrofit application suggested that costs of a dry regenerable sodium carbonate-based process could be lower than those of a monoethanolamine absorption system. In both cases, the greatest part of the process costs come from power plant output reductions due to parasitic consumption of steam for recovery of carbon dioxide from the capture medium.

  1. Enhanced electrodes for solid state gas sensors

    DOE Patents [OSTI]

    Garzon, Fernando H.; Brosha, Eric L.

    2001-01-01

    A solid state gas sensor generates an electrical potential between an equilibrium electrode and a second electrode indicative of a gas to be sensed. A solid electrolyte substrate has the second electrode mounted on a first portion of the electrolyte substrate and a composite equilibrium electrode including conterminous transition metal oxide and Pt components mounted on a second portion of the electrolyte substrate. The composite equilibrium electrode and the second electrode are electrically connected to generate an electrical potential indicative of the gas that is being sensed. In a particular embodiment of the present invention, the second electrode is a reference electrode that is exposed to a reference oxygen gas mixture so that the electrical potential is indicative of the oxygen in a gas stream.

  2. Electrically conductive connection for an electrode

    DOE Patents [OSTI]

    Hornack, Thomas R.; Chilko, Robert J.

    1986-01-01

    An electrically conductive connection for an electrode assembly of an electrolyte cell in which aluminum is produced by electrolysis in a molten salt is described. The electrode assembly comprises an electrode flask and a conductor rod. The flask has a collar above an area of minimum flask diameter. The electrically conductive connection comprises the electrode flask, the conductor rod and a structure bearing against the collar and the conductor rod for pulling the conductor rod into compressive and electrical contact with the flask.

  3. Method of making electrodes for electrochemical cell

    DOE Patents [OSTI]

    Kaun, Thomas D.; Kilsdonk, Dennis J.

    1983-01-01

    A method of making an electrode for an electrochemical cell in which particulate electrode-active material is mixed with a liquid organic carrier chemically inert with respect to the electrode-active material, mixing the liquid carrier to form an extrudable slurry. The liquid carrier is present in an amount of from about 10 to about 50 percent by volume of the slurry, and then the carrier is removed from the slurry leaving the electrode-active material.

  4. Alkali metal ion battery with bimetallic electrode

    DOE Patents [OSTI]

    Boysen, Dane A; Bradwell, David J; Jiang, Kai; Kim, Hojong; Ortiz, Luis A; Sadoway, Donald R; Tomaszowska, Alina A; Wei, Weifeng; Wang, Kangli

    2015-04-07

    Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten the alkali metal and the electrode comprising the combined alkali/non-alkali metals.

  5. Minimizing electrode contamination in an electrochemical cell

    DOE Patents [OSTI]

    Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

    2014-12-09

    An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

  6. Drop short control of electrode gap

    DOE Patents [OSTI]

    Fisher, Robert W.; Maroone, James P.; Tipping, Donald W.; Zanner, Frank J.

    1986-01-01

    During vacuum consumable arc remelting the electrode gap between a consumable electrode and a pool of molten metal is difficult to control. The present invention monitors drop shorts by detecting a decrease in the voltage between the consumable electrode and molten pool. The drop shorts and their associated voltage reductions occur as repetitive pulses which are closely correlated to the electrode gap. Thus, the method and apparatus of the present invention controls electrode gap based upon drop shorts detected from the monitored anode-cathode voltage. The number of drop shorts are accumulated, and each time the number of drop shorts reach a predetermined number, the average period between drop shorts is calculated from this predetermined number and the time in which this number is accumulated. This average drop short period is used in a drop short period electrode gap model which determines the actual electrode gap from the drop short. The actual electrode gap is then compared with a desired electrode gap which is selected to produce optimum operating conditions and the velocity of the consumable error is varied based upon the gap error. The consumable electrode is driven according to any prior art system at this velocity. In the preferred embodiment, a microprocessor system is utilized to perform the necessary calculations and further to monitor the duration of each drop short. If any drop short exceeds a preset duration period, the consumable electrode is rapidly retracted a predetermined distance to prevent bonding of the consumable electrode to the molten remelt.

  7. Hot Dry Rock; Geothermal Energy

    SciTech Connect (OSTI)

    1990-01-01

    The commercial utilization of geothermal energy forms the basis of the largest renewable energy industry in the world. More than 5000 Mw of electrical power are currently in production from approximately 210 plants and 10 000 Mw thermal are used in direct use processes. The majority of these systems are located in the well defined geothermal generally associated with crustal plate boundaries or hot spots. The essential requirements of high subsurface temperature with huge volumes of exploitable fluids, coupled to environmental and market factors, limit the choice of suitable sites significantly. The Hot Dry Rock (HDR) concept at any depth originally offered a dream of unlimited expansion for the geothermal industry by relaxing the location constraints by drilling deep enough to reach adequate temperatures. Now, after 20 years intensive work by international teams and expenditures of more than $250 million, it is vital to review the position of HDR in relation to the established geothermal industry. The HDR resource is merely a body of rock at elevated temperatures with insufficient fluids in place to enable the heat to be extracted without the need for injection wells. All of the major field experiments in HDR have shown that the natural fracture systems form the heat transfer surfaces and that it is these fractures that must be for geothermal systems producing from naturally fractured formations provide a basis for directing the forthcoming but, equally, they require accepting significant location constraints on HDR for the time being. This paper presents a model HDR system designed for commercial operations in the UK and uses production data from hydrothermal systems in Japan and the USA to demonstrate the reservoir performance requirements for viable operations. It is shown that these characteristics are not likely to be achieved in host rocks without stimulation processes. However, the long term goal of artificial geothermal systems developed by systematic engineering procedures at depth may still be attained if high temperature sites with extensive fracturing are developed or exploited. [DJE -2005

  8. Lithographic dry development using optical absorption

    DOE Patents [OSTI]

    Olynick, Deirdre; Schuck, P. James; Schmidt, Martin

    2013-08-20

    A novel approach to dry development of exposed photo resist is described in which a photo resist layer is exposed to a visible light source in order to remove the resist in the areas of exposure. The class of compounds used as the resist material, under the influence of the light source, undergoes a chemical/structural change such that the modified material becomes volatile and is thus removed from the resist surface. The exposure process is carried out for a time sufficient to ablate the exposed resist layer down to the layer below. A group of compounds found to be useful in this process includes aromatic calixarenes.

  9. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore » (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.« less

  10. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-15

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached −225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ∼22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  11. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  12. Method for manufacturing magnetohydrodynamic electrodes

    DOE Patents [OSTI]

    Killpatrick, Don H.; Thresh, Henry R.

    1982-01-01

    A method of manufacturing electrodes for use in a magnetohydrodynamic (MHD) generator comprising the steps of preparing a billet having a core 10 of a first metal, a tubular sleeve 12 of a second metal, and an outer sheath 14, 16, 18 of an extrusile metal; evacuating the space between the parts of the assembled billet; extruding the billet; and removing the outer jacket 14. The extruded bar may be made into electrodes by cutting and bending to the shape required for an MDH channel frame. The method forms a bond between the first metal of the core 10 and the second metal of the sleeve 12 strong enough to withstand a hot and corrosive environment.

  13. Continuity and Performance in Composite Electrodes

    SciTech Connect (OSTI)

    Chen, Guoying; Richardson, Thomas J.

    2009-12-23

    It is shown that the rate performance of a lithium battery composite electrode may be compromised by poor internal connectivity due to defects and inhomogeneities introduced during electrode fabrication or subsequent handling. Application of a thin conductive coating to the top surface of the electrode or to the separator surface in contact with the electrode improves the performance by providing alternative current paths to partially isolated particles of electroactive material. Mechanistic implications are discussed and strategies for improvement in electrode design and fabrication are presented.

  14. Control of electrode depth in electroslag remelting

    DOE Patents [OSTI]

    Melgaard, David K.; Shelmidine, Gregory J.; Damkroger, Brian K.

    2002-01-01

    A method of and apparatus for controlling an electroslag remelting furnace by driving the electrode at a nominal speed based upon melting rate and geometry while making minor proportional adjustments based on a measured metric of the electrode immersion depth. Electrode drive speed is increased if a measured metric of electrode immersion depth differs from a set point by a predetermined amount, indicating that the tip is too close to the surface of a slag pool. Impedance spikes are monitored to adjust the set point for the metric of electrode immersion depth based upon one or more properties of the impedance spikes.

  15. Long life lithium batteries with stabilized electrodes

    DOE Patents [OSTI]

    Amine, Khalil; Liu, Jun; Vissers, Donald R.; Lu, Wenquan

    2009-03-24

    The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In some embodiments the additives include a substituted or unsubstituted cyclic or spirocyclic hydrocarbon containing at least one oxygen atom and at least one alkenyl or alkynyl group. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes or olivine or carbon-coated olivine electrodes, the new electrolytes provide batteries with improved calendar and cycle life.

  16. Segmented electrode hall thruster with reduced plume

    DOE Patents [OSTI]

    Fisch, Nathaniel J.; Raitses, Yevgeny

    2004-08-17

    An apparatus and method for thrusting plasma, utilizing a Hall thruster with segmented electrodes along the channel, which make the acceleration region as localized as possible. Also disclosed are methods of arranging the electrodes so as to minimize erosion and arcing. Also disclosed are methods of arranging the electrodes so as to produce a substantial reduction in plume divergence. The use of electrodes made of emissive material will reduce the radial potential drop within the channel, further decreasing the plume divergence. Also disclosed is a method of arranging and powering these electrodes so as to provide variable mode operation.

  17. Non-Sintered Nickel Electrode

    DOE Patents [OSTI]

    Bernard, Patrick; Dennig, Corinne; Cocciantelli, Jean-Michel; Alcorta, Jose; Coco, Isabelle

    2002-01-01

    A non-sintered nickel electrode contains a conductive support and a paste comprising an electrochemically active material containing nickel hydroxide and a binder which is a mixture of an elastomer and a crystalline polymer. The proportion of the elastomer is in the range 25% to 60% by weight of the binder and the proportion of the crystalline polymer is in the range 40% to 75% by weight of the binder.

  18. MODELING OF CHANGING ELECTRODE PROFILES

    SciTech Connect (OSTI)

    Prentice, Geoffrey Allen

    1980-12-01

    A model for simulating the transient behavior of solid electrodes undergoing deposition or dissolution has been developed. The model accounts for ohmic drop, charge transfer overpotential, and mass transport limitations. The finite difference method, coupled with successive overrelaxation, was used as the basis of the solution technique. An algorithm was devised to overcome the computational instabilities associated with the calculations of the secondary and tertiary current distributions. Simulations were performed on several model electrode profiles: the sinusoid, the rounded corner, and the notch. Quantitative copper deposition data were obtained in a contoured rotating cylinder system, Sinusoidal cross-sections, machined on stainless steel cylinders, were used as model geometries, Kinetic parameters for use in the simulation were determined from polarization curves obtained on copper rotating cylinders, These parameters, along with other physical property and geometric data, were incorporated in simulations of growing sinusoidal profiles. The copper distributions on the sinusoidal cross-sections were measured and found to compare favorably with the simulated results. At low Wagner numbers the formation of a slight depression at the profile peak was predicted by the simulation and observed on the profile. At higher Wagner numbers, the simulated and experimental results showed that the formation of a depression was suppressed. This phenomenon was shown to result from the competition between ohmic drop and electrode curvature.

  19. Composite electrode for use in electrochemical cells

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Huff, James R.; Leddy, Johna

    1989-01-01

    A porous composite electrode for use in electrochemical cells. The electrode has a first face and a second face defining a relatively thin section therebetween. The electrode is comprised of an ion conducting material, an electron conducting material, and an electrocatalyst. The volume concentration of the ion conducting material is greatest at the first face and is decreased across the section, while the volume concentration of the electron conducting material is greatest at the second face and decreases across the section of the electrode. Substantially all of the electrocatalyst is positioned within the electrode section in a relatively narrow zone where the rate of electron transport of the electrode is approximately equal to the rate of ion transport of the electrode.

  20. Composite electrode for use in electrochemical cells

    DOE Patents [OSTI]

    Vanderborgh, N.E.; Huff, J.R.; Leddy, J.

    1987-10-16

    A porous composite electrode for use in electrochemical cells. The electrode has a first face and a second face defining a relatively thin section therebetween. The electrode is comprised of an ion conducting material, an electron conducting material, and an electrocatalyst. The volume concentration of the ion conducting material is greatest at the first face and is decreased across the section, while the volume concentration of the electron conducting material is greatest at the second face and decreases across the section of the electrode. Substantially all of the electrocatalyst is positioned within the electrode section in a relatively narrow zone where the rate of electron transport of the electrode is approximately equal to the rate of ion transport of the electrode. 4 figs., 1 tab.

  1. evaluation-dry-sorbent-urs | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of Dry Sorbent Technology for Pre-Combustion CO2 Capture Project No.: DE-FE0000465 Scanning Electron Microsopy (SEM) and Transmission Electron Miscroscopy (TEM) images of a multi-functional sorbent synthesized by a novel method. Scanning Electron Microsopy (SEM) and Transmission Electron Miscroscopy (TEM) images of a multi-functional sorbent synthesized by a novel method. URS and the University of Illinois at Urbana-Champaign are investigating a dry sorbent process configured to

  2. Evaluation residual moisture in lithium-ion battery electrodes and its effect on electrode performance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Jianlin; Daniel, Claus; Wood, III, David L.; An, Seong Jin

    2016-01-11

    Removing residual moisture in lithium-ion battery electrodes is essential for desired electrochemical performance. In this manuscript, the residual moisture in LiNi0.5Mn0.3Co0.2O2 cathodes produced by conventional solvent-based and aqueous processing is characterized and compared. The electrochemical performance has also been investigated for various residual moisture contents. As a result, it has been demonstrated that the residual moisture lowers the first cycle coulombic efficiency, but its effect on short term cycle life is insignificant.

  3. Powder processing for the fabrication of Si{sub 3}N{sub 4} ceramics. 1: Influence of spray-dried granule strength on pore size distribution in green compacts

    SciTech Connect (OSTI)

    Kamiya, Hidehiro; Isomura, Kenji; Jimbo, Genji; Junichiro, Tsubaki

    1995-01-01

    The effect of spray-dried granule strength on the microstructure of green compacts obtained by isostatic pressing was quantitatively analyzed. The fracture strength of single granules of Si{sub 3}N{sub 4} powder made with ultrafine Al{sub 2}O{sub 3} and Y{sub 2}O{sub 3} powders was measured directly by diametral compression. It was found that fracture strength increased notably with the increasing relative density of the granule and the decreasing size of agglomerates in suspension before spray-drying. Even when green bodies were prepared at an isostatic pressure of 200 MPa, intergranular pores, which negatively affected densification of the sintered bodies, occurred between unfractured granules. The volume and size of these pores in the green compacts increased with the increasing fracture strength of the granules. In the case of closely packed granules, an isostatic pressure of 800 MPa was required to completely collapse the intergranular pores. A simple equation was derived to calculate the isostatic pressure necessary for complete collapse of intergranular pores in the green compacts, and it was determined that granule strength must be kept as low as possible to obtain uniform green compacts.

  4. California Dry Natural Gas Reserves Revision Decreases (Billion...

    Gasoline and Diesel Fuel Update (EIA)

    Decreases (Billion Cubic Feet) California Dry Natural Gas Reserves Revision Decreases ... Dry Natural Gas Reserves Revision Decreases California Dry Natural Gas Proved Reserves Dry ...

  5. California Dry Natural Gas Reserves Revision Increases (Billion...

    Gasoline and Diesel Fuel Update (EIA)

    Increases (Billion Cubic Feet) California Dry Natural Gas Reserves Revision Increases ... Dry Natural Gas Reserves Revision Increases California Dry Natural Gas Proved Reserves Dry ...

  6. Texas Dry Natural Gas Expected Future Production (Billion Cubic...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Expected Future Production (Billion Cubic Feet) Texas Dry Natural Gas Expected Future ... Dry Natural Gas Proved Reserves as of Dec. 31 Texas Dry Natural Gas Proved Reserves Dry ...

  7. Method of electrode fabrication and an electrode for metal chloride battery

    DOE Patents [OSTI]

    Bloom, Ira D.; Nelson, Paul A.; Vissers, Donald R.

    1993-01-01

    A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 .OMEGA.cm.sup.2 than those resistivity values of approximately 1.0-1.5 .OMEGA.cm.sup.2 exhibited by currently available electrodes.

  8. Method of electrode fabrication and an electrode for metal chloride battery

    DOE Patents [OSTI]

    Bloom, I.D.; Nelson, P.A.; Vissers, D.R.

    1993-03-16

    A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 [Omega]cm[sup 2] than those resistivity values of approximately 1.0-1.5 [Omega]cm[sup 2] exhibited by currently available electrodes.

  9. Method of making an electrode

    DOE Patents [OSTI]

    Isenberg, A.O.

    1986-07-01

    Disclosed is a method of coating an electrode on a solid oxygen conductive oxide layer. A coating of particles of an electronic conductor is formed on one surface of the oxide layer and a source of oxygen is applied to the opposite surface of the oxide layer. A metal halide vapor is applied over the electronic conductor and the oxide layer is heated to a temperature sufficient to induce oxygen to diffuse through the oxide layer and react with the metal halide vapor. This results in the growing of a metal oxide coating on the particles of electronic conductor, thereby binding them to the oxide layer. 2 figs.

  10. Method of making an electrode

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills Boro, PA)

    1986-01-01

    Disclosed is a method of coating an electrode on a solid oxygen conductive oxide layer. A coating of particles of an electronic conductor is formed on one surface of the oxide layer and a source of oxygen is applied to the opposite surface of the oxide layer. A metal halide vapor is applied over the electronic conductor and the oxide layer is heated to a temperature sufficient to induce oxygen to diffuse through the oxide layer and react with the metal halide vapor. This results in the growing of a metal oxide coating on the particles of electronic conductor, thereby binding them to the oxide layer.

  11. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (Auburn, AL); Dispennette, John M. (Auburn, AL)

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

  12. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  13. Continuous process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    Chern, T.S.H.; Keller, D.G.; MacFadden, K.O.

    1998-05-12

    Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be over coated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance. 1 fig.

  14. Continuous process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    Chern, Terry Song-Hsing; Keller, David Gerard; MacFadden, Kenneth Orville

    1998-01-01

    Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte-electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be overcoated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance.

  15. Drying/self-assembly of nanoparticle suspensions.

    SciTech Connect (OSTI)

    Cheng, Shengfeng; Plimpton, Steven James; Lechman, Jeremy B.; Grest, Gary Stephen

    2010-10-01

    The most feasible way to disperse particles in a bulk material or control their packing at a substrate is through fluidization in a carrier that can be processed with well-known techniques such as spin, drip and spray coating, fiber drawing, and casting. The next stage in the processing is often solidification involving drying by solvent evaporation. While there has been significant progress in the past few years in developing discrete element numerical methods to model dense nanoparticle dispersion/suspension rheology which properly treat the hydrodynamic interactions of the solvent, these methods cannot at present account for the volume reduction of the suspension due to solvent evaporation. As part of LDRD project FY-101285 we have developed and implemented methods in the current suite of discrete element methods to remove solvent particles and volume, and hence solvent mass from the liquid/vapor interface of a suspension to account for volume reduction (solvent drying) effects. To validate the methods large scale molecular dynamics simulations have been carried out to follow the evaporation process at the microscopic scale.

  16. Electrochemical cell and negative electrode therefor

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1982-01-01

    A secondary electrochemical cell with the positive and negative electrodes separated by a molten salt electrolyte with the negative electrode comprising a particulate mixture of lithium-aluminum alloy and electrolyte and an additive selected from graphitized carbon, Raney iron or mixtures thereof. The lithium-aluminum alloy is present in the range of from about 45 to about 80 percent by volume of the negative electrode, and the electrolyte is present in an amount not less than about 10 percent by volume of the negative electrode. The additive of graphitized carbon is present in the range of from about 1 to about 10 percent by volume of the negative electrode, and the Raney iron additive is present in the range of from about 3 to about 10 percent by volume of the negative electrode.

  17. Flow through electrode with automated calibration

    DOE Patents [OSTI]

    Szecsody, James E [Richland, WA; Williams, Mark D [Richland, WA; Vermeul, Vince R [Richland, WA

    2002-08-20

    The present invention is an improved automated flow through electrode liquid monitoring system. The automated system has a sample inlet to a sample pump, a sample outlet from the sample pump to at least one flow through electrode with a waste port. At least one computer controls the sample pump and records data from the at least one flow through electrode for a liquid sample. The improvement relies upon (a) at least one source of a calibration sample connected to (b) an injection valve connected to said sample outlet and connected to said source, said injection valve further connected to said at least one flow through electrode, wherein said injection valve is controlled by said computer to select between said liquid sample or said calibration sample. Advantages include improved accuracy because of more frequent calibrations, no additional labor for calibration, no need to remove the flow through electrode(s), and minimal interruption of sampling.

  18. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  19. Lithium-aluminum-magnesium electrode composition

    DOE Patents [OSTI]

    Melendres, Carlos A.; Siegel, Stanley

    1978-01-01

    A negative electrode composition is presented for use in a secondary, high-temperature electrochemical cell. The cell also includes a molten salt electrolyte of alkali metal halides or alkaline earth metal halides and a positive electrode including a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent and a magnesium-aluminum alloy as a structural matrix. Various binary and ternary intermetallic phases of lithium, magnesium, and aluminum are formed but the electrode composition in both its charged and discharged state remains substantially free of the alpha lithium-aluminum phase and exhibits good structural integrity.

  20. Semiconductor devices having a recessed electrode structure

    DOE Patents [OSTI]

    Palacios, Tomas Apostol; Lu, Bin; Matioli, Elison de Nazareth

    2015-05-26

    An electrode structure is described in which conductive regions are recessed into a semiconductor region. Trenches may be formed in a semiconductor region, such that conductive regions can be formed in the trenches. The electrode structure may be used in semiconductor devices such as field effect transistors or diodes. Nitride-based power semiconductor devices are described including such an electrode structure, which can reduce leakage current and otherwise improve performance.

  1. Semiconductor electrode with improved photostability characteristics

    DOE Patents [OSTI]

    Frank, Arthur J.

    1987-01-01

    An electrode is disclosed for use in photoelectrochemical cells having an electrolyte which includes an aqueous constituent. The electrode includes a semiconductor and a hydrophobic film disposed between the semiconductor and the aqueous constituent. The hydrophobic film is adapted to permit charges to pass therethrough while substantially decreasing the activity of the aqueous constituent at the semiconductor surface thereby decreasing the photodegradation of the semiconductor electrode.

  2. Nanoscopic Electrode Molecular Probes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Nanoscopic Electrode Molecular Probes Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary ORNL researchers invented a nanoscopic electrode system for measuring the electron transport properties of a molecule. This invention offers a means of enhancing measurements of a molecule positioned between two nanoscopic electrodes for study. Currently, molecular sensing and identification

  3. Microcantilever Counter Electrode Electrochemical Sensor in a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Three-Electrode Cell - Energy Innovation Portal Energy Analysis Energy Analysis Early Stage R&D Early Stage R&D Advanced Materials Advanced Materials Find More Like This Return to Search Microcantilever Counter Electrode Electrochemical Sensor in a Three-Electrode Cell Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryResearchers at ORNL have invented a compact, highly accurate system to detect and measure chemicals in solution. The device

  4. Three-Electrode Metal Oxide Reduction Cell

    DOE Patents [OSTI]

    Dees, Dennis W.; Ackerman, John P.

    2005-06-28

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  5. Three-electrode metal oxide reduction cell

    DOE Patents [OSTI]

    Dees, Dennis W.; Ackerman, John P.

    2008-08-12

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  6. Semiconductor electrode with improved photostability characteristics

    DOE Patents [OSTI]

    Frank, A.J.

    1985-02-19

    An electrode is described for use in photoelectrochemical cells having an electrolyte which includes an aqueous constituent. The electrode consists of a semiconductor and a hydrophobic film disposed between the semiconductor and the aqueous constituent. The hydrophobic film is adapted to permit charges to pass therethrough while substantially decreasing the activity of the aqueous constituent at the semiconductor surface thereby decreasing the photodegradation of the semiconductor electrode.

  7. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1997-01-01

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome.

  8. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1997-02-11

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes is described, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome. 1 fig.

  9. Electrode structure and methods of making same

    DOE Patents [OSTI]

    Ruud, James Anthony; Browall, Kenneth Walter; Rehg, Timothy Joseph; Renou, Stephane; Striker, Todd-Michael

    2010-04-06

    A method of making an electrode structure is provided. The method includes disposing an electrocatalytic material on an electrode, applying heat to the electrocatalytic material to form a volatile oxide of the electrocatalytic material, and applying a voltage to the electrode to reduce the volatile oxide to provide a number of nano-sized electrocatalytic particles on or proximate to a triple phase boundary, where the number of nano-sized electrocatalytic particles is greater on or proximate to the triple phase boundary than in an area that is not on or proximate to the triple phase boundary, and where the triple phase boundary is disposed on the electrode.

  10. Negative electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Vaughey, John T.; Fransson, Linda M.; Thackeray, Michael M.

    2005-02-15

    A negative electrode is disclosed for a non-aqueous electrochemical cell. The electrode has an intermetallic compound as its basic structural unit with the formula M.sub.2 M' in which M and M' are selected from two or more metal elements including Si, and the M.sub.2 M' structure is a Cu.sub.2 Sb-type structure. Preferably M is Cu, Mn and/or Li, and M' is Sb. Also disclosed is a non-aqueous electrochemical cell having a negative electrode of the type described, an electrolyte and a positive electrode. A plurality of cells may be arranged to form a battery.

  11. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the structure and bonding of its graphitic carbon electrodes. The research could lead to better, more reliable strategies for improving the capacity and efficiency of...

  12. Electronic Structure Changes in Supercapacitor Electrodes Observed...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The evolution in electronic structure reflects changes in the surface chemistry and morphology induced by polarization of the electrode-electrolyte interface and points to...

  13. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for storing electrical energy. It consists of two electrodes separated by a solid-state dielectric insulator. In a "supercapacitor," the solid-state dielectric is replaced by...

  14. Electrically conductive connection for an electrode

    DOE Patents [OSTI]

    Hornack, T.R.; Chilko, R.J.

    1986-09-02

    An electrically conductive connection for an electrode assembly of an electrolyte cell in which aluminum is produced by electrolysis in a molten salt is described. The electrode assembly comprises an electrode flask and a conductor rod. The flask has a collar above an area of minimum flask diameter. The electrically conductive connection comprises the electrode flask, the conductor rod and a structure bearing against the collar and the conductor rod for pulling the conductor rod into compressive and electrical contact with the flask. 2 figs.

  15. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  16. Electric filter with movable belt electrode

    DOE Patents [OSTI]

    Bergman, W.

    1983-09-20

    A method and apparatus for removing airborne contaminants entrained in a gas or airstream includes an electric filter characterized by a movable endless belt electrode, a grounded electrode, and a filter medium sandwiched there between. Inclusion of the movable, endless belt electrode provides the driving force for advancing the filter medium through the filter, and reduces frictional drag on the filter medium, thereby permitting a wide choice of filter medium materials. Additionally, the belt electrode includes a plurality of pleats in order to provide maximum surface area on which to collect airborne contaminants. 4 figs.

  17. Electric filter with movable belt electrode

    DOE Patents [OSTI]

    Bergman, Werner

    1983-01-01

    A method and apparatus for removing airborne contaminants entrained in a gas or airstream includes an electric filter characterized by a movable endless belt electrode, a grounded electrode, and a filter medium sandwiched therebetween. Inclusion of the movable, endless belt electrode provides the driving force for advancing the filter medium through the filter, and reduces frictional drag on the filter medium, thereby permitting a wide choice of filter medium materials. Additionally, the belt electrode includes a plurality of pleats in order to provide maximum surface area on which to collect airborne contaminants.

  18. Electrode assemblies, plasma apparatuses and systems including electrode assemblies, and methods for generating plasma

    DOE Patents [OSTI]

    Kong, Peter C; Grandy, Jon D; Detering, Brent A; Zuck, Larry D

    2013-09-17

    Electrode assemblies for plasma reactors include a structure or device for constraining an arc endpoint to a selected area or region on an electrode. In some embodiments, the structure or device may comprise one or more insulating members covering a portion of an electrode. In additional embodiments, the structure or device may provide a magnetic field configured to control a location of an arc endpoint on the electrode. Plasma generating modules, apparatus, and systems include such electrode assemblies. Methods for generating a plasma include covering at least a portion of a surface of an electrode with an electrically insulating member to constrain a location of an arc endpoint on the electrode. Additional methods for generating a plasma include generating a magnetic field to constrain a location of an arc endpoint on an electrode.

  19. Drying rate and temperature profile for superheated steam vacuum drying and moist air drying of softwood lumber

    SciTech Connect (OSTI)

    Pang, S.; Dakin, M. [New Zealand Forest Research Inst., Ltd., Rotorua (New Zealand). Mfg. Technologies Portfolio

    1999-07-01

    Two charges of green radiata pine sapwood lumber were dried, ether using superheated steam under vacuum (90 C, 0.2 bar abs.) or conventionally using hot moist air (90/60 C). Due to low density of the drying medium under vacuum, the circulation velocity used was 10 m/s for superheated steam drying and 5.0 m/s for moist air drying, and in both cases, the flow was unidirectional. In drying, stack drying rate and wood temperatures were measured to examine the differences between the superheated steam drying and drying using hot moist air. The experimental results have shown that the stack edge board in superheated steam drying dried faster than in the hot moist air drying. Once again due to the low density of the steam under vacuum, a prolonged maximum temperature drop across load (TDAL) was observed in the superheated steam drying, however, the whole stack dried slower and the final moisture content distribution was more variable than for conventional hot moist air drying.

  20. DRI Renewable Energy Center (REC) (NV)

    SciTech Connect (OSTI)

    Hoekman, S. Kent; Broch, Broch; Robbins, Curtis; Jacobson, Roger; Turner, Robert

    2012-12-31

    The primary objective of this project was to utilize a flexible, energy-efficient facility, called the DRI Renewable Energy Experimental Facility (REEF) to support various renewable energy research and development (R&D) efforts, along with education and outreach activities. The REEF itself consists of two separate buildings: (1) a 1200-ft2 off-grid capable house and (2) a 600-ft2 workshop/garage to support larger-scale experimental work. Numerous enhancements were made to DRI's existing renewable power generation systems, and several additional components were incorporated to support operation of the REEF House. The power demands of this house are satisfied by integrating and controlling PV arrays, solar thermal systems, wind turbines, an electrolyzer for renewable hydrogen production, a gaseous-fuel internal combustion engine/generator set, and other components. Cooling needs of the REEF House are satisfied by an absorption chiller, driven by solar thermal collectors. The REEF Workshop includes a unique, solar air collector system that is integrated into the roof structure. This system provides space heating inside the Workshop, as well as a hot water supply. The Workshop houses a custom-designed process development unit (PDU) that is used to convert woody biomass into a friable, hydrophobic char that has physical and chemical properties similar to low grade coal. Besides providing sufficient space for operation of this PDU, the REEF Workshop supplies hot water that is used in the biomass treatment process. The DRI-REEF serves as a working laboratory for evaluating and optimizing the performance of renewable energy components within an integrated, residential-like setting. The modular nature of the system allows for exploring alternative configurations and control strategies. This experimental test bed is also highly valuable as an education and outreach tool both in providing an infrastructure for student research projects, and in highlighting renewable energy features to the public.

  1. Final Report - Membranes and MEA's for Dry, Hot Operating Conditions

    SciTech Connect (OSTI)

    Hamrock, Steven J.

    2011-06-30

    The focus of this program was to develop a new Proton Exchange Membrane (PEM) which can operate under hotter, dryer conditions than the state of the art membranes today and integrate it into a Membrane Electrode Assembly (MEA). These MEA's should meet the performance and durability requirements outlined in the solicitation, operating under low humidification conditions and at temperatures ranging from -20???ºC to 120???ºC, to meet 2010 DOE technical targets for membranes. This membrane should operate under low humidification conditions and at temperatures ranging from -20???ºC to 120???ºC in order to meet DOE HFCIT 2010 commercialization targets for automotive fuel cells. Membranes developed in this program may also have improved durability and performance characteristics making them useful in stationary fuel cell applications. The new membranes, and the MEA?¢????s comprising them, should be manufacturable at high volumes and at costs which can meet industry and DOE targets. This work included: A) Studies to better understand factors controlling proton transport within the electrolyte membrane, mechanisms of polymer degradation (in situ and ex situ) and membrane durability in an MEA; B) Development of new polymers with increased proton conductivity over the range of temperatures from -20???ºC to 120???ºC and at lower levels of humidification and with improved chemical and mechanical stability; C) Development of new membrane additives for increased durability and conductivity under these dry conditions; D) Integration of these new materials into membranes and membranes into MEA?¢????s, including catalyst and gas diffusion layer selection and integration; E) Verification that these materials can be made using processes which are scalable to commercial volumes using cost effective methods; F) MEA testing in single cells using realistic automotive testing protocols. This project addresses technical barriers A (Durability) and C (Performance) from the Fuel Cells section of the 2005 Hydrogen, Fuel Cells and Infrastructure Technologies Program Multi-Year R&D Plan. In the course of this four-year program we developed a new PEM with improved proton conductivity, chemical stability and mechanical stability. We incorporated this new membrane into MEAs and evaluated performance and durability.

  2. Powder treatment process

    DOE Patents [OSTI]

    Weyand, J.D.

    1988-02-09

    Disclosed are: (1) a process comprising spray drying a powder-containing slurry, the slurry containing a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, while reducing the tendency for oxidation of the constituent by including as a liquid constituent of the slurry an organic liquid; (2) a process comprising spray drying a powder-containing slurry, the powder having been pretreated to reduce content of a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, the pretreating comprising heating the powder to react the constituent; and (3) a process comprising reacting ceramic powder, grinding the reacted powder, slurrying the ground powder, spray drying the slurried powder, and blending the dried powder with metal powder. 2 figs.

  3. Powder treatment process

    DOE Patents [OSTI]

    Weyand, John D. (Greensburg, PA)

    1988-01-01

    (1) A process comprising spray drying a powder-containing slurry, the slurry containing a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, while reducing the tendency for oxidation of the constituent by including as a liquid constituent of the slurry an organic liquid; (2) a process comprising spray drying a powder-containing slurry, the powder having been pretreated to reduce content of a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, the pretreating comprising heating the powder to react the constituent; and (3) a process comprising reacting ceramic powder, grinding the reacted powder, slurrying the ground powder, spray drying the slurried powder, and blending the dried powder with metal powder.

  4. Dielectrophoretic systems without embedded electrodes

    DOE Patents [OSTI]

    Cummings, Eric B.; Singh, Anup K.

    2006-03-21

    Method and apparatus for dielectrophoretic separation of particles in a fluid based using array of insulating structures arranged in a fluid flow channel. By utilizing an array of insulating structures, a spatially inhomogeneous electric field is created without the use of the embedded electrodes conventionally employed for dielectrophoretic separations. Moreover, by using these insulating structures a steady applied electric field has been shown to provide for dielectrophoresis in contrast to the conventional use of an alternating electric field. In a uniform array of posts, dielectrophoretic effects have been produced flows having significant pressure-driven and electrokinetic transport. Above a threshold applied electric field, filaments of concentrated and rarefied particles appear in the flow as a result of dielectrophoresis. Above a higher threshold applied voltage, dielectrophoresis produces zones of highly concentrated and immobilized particles. These patterns are strongly influenced by the angle of the array of insulating structures with respect to the mean applied electric field and the shape of the insulating structures.

  5. Electrochromic Counter Electrode - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search Electrochromic Counter Electrode National Renewable Energy Laboratory Contact NREL About This Technology Publications: PDF Document Publication Nanocomposite Counter Electrode Materials for Electrochromic Windows (692 KB) Technology Marketing Summary Electrochromic materials change optical properties upon the injection of charge or charge carriers into the material,

  6. Means for limiting and ameliorating electrode shorting

    SciTech Connect (OSTI)

    Konynenburg, R.A. van; Farmer, J.C.

    1999-11-09

    A fuse and filter arrangement is described for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  7. Organic conductive films for semiconductor electrodes

    DOE Patents [OSTI]

    Frank, A.J.

    1984-01-01

    According to the present invention, improved electrodes overcoated with conductive polymer films and preselected catalysts are provided. The electrodes typically comprise an inorganic semiconductor over-coated with a charge conductive polymer film comprising a charge conductive polymer in or on which is a catalyst or charge-relaying agent.

  8. Means for limiting and ameliorating electrode shorting

    DOE Patents [OSTI]

    Van Konynenburg, Richard A.; Farmer, Joseph C.

    1999-01-01

    A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  9. Organic conductive films for semiconductor electrodes

    DOE Patents [OSTI]

    Frank, Arthur J.

    1984-01-01

    According to the present invention, improved electrodes overcoated with conductive polymer films and preselected catalysts are provided. The electrodes typically comprise an inorganic semiconductor overcoated with a charge conductive polymer film comprising a charge conductive polymer in or on which is a catalyst or charge-relaying agent.

  10. Lithium-aluminum-iron electrode composition

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1979-01-01

    A negative electrode composition is presented for use in a secondary electrochemical cell. The cell also includes an electrolyte with lithium ions such as a molten salt of alkali metal halides or alkaline earth metal halides that can be used in high-temperature cells. The cell's positive electrode contains a a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent in an alloy of aluminum-iron. Various binary and ternary intermetallic phases of lithium, aluminum and iron are formed. The lithium within the intermetallic phase of Al.sub.5 Fe.sub.2 exhibits increased activity over that of lithium within a lithium-aluminum alloy to provide an increased cell potential of up to about 0.25 volt.

  11. Guides and Case Studies for Hot-Dry and Mixed-Dry Climates | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Dry and Mixed-Dry Climates Guides and Case Studies for Hot-Dry and Mixed-Dry Climates Map of the Hot-Dry and Mixed-Dry Zone of the United States. The zone contains the eastern side of California and follows the US border to cover the western half of Texas. The Department of Energy (DOE) has developed a series of best practices and case studies to help builders improve whole-house energy performance in buildings found in hot-dry and mixed-dry climates. Best Practice Guides 40%

  12. Electrodic voltages in the presence of dissolved sulfide: Implications for monitoring natural microbial activity

    SciTech Connect (OSTI)

    Slater, L.; Ntarlagiannis, D.; Yee, N.; O'Brien, M.; Zhang, C.; Williams, K. H.

    2008-10-01

    There is growing interest in the development of new monitoring strategies for obtaining spatially extensive data diagnostic of microbial processes occurring in the earth. Open-circuit potentials arising from variable redox conditions in the fluid local-to-electrode surfaces (electrodic potentials) were recorded for a pair of silver-silver chloride electrodes in a column experiment, whereby a natural wetland soil containing a known community of sulfate reducers was continuously fed with a sulfate-rich nutrient medium. Measurements were made between five electrodes equally spaced along the column and a reference electrode placed on the column inflow. The presence of a sulfate reducing microbial population, coupled with observations of decreasing sulfate levels, formation of black precipitate (likely iron sulfide),elevated solid phase sulfide, and a characteristic sulfurous smell, suggest microbial-driven sulfate reduction (sulfide generation) in our column. Based on the known sensitivity of a silver electrode to dissolved sulfide concentration, we interpret the electrodic potentials approaching 700 mV recorded in this experiment as an indicator of the bisulfide (HS-) concentration gradients in the column. The measurement of the spatial and temporal variation in these electrodic potentials provides a simple and rapid method for monitoring patterns of relative HS- concentration that are indicative of the activity of sulfate-reducing bacteria. Our measurements have implications both for the autonomous monitoring of anaerobic microbial processes in the subsurface and the performance of self-potential electrodes, where it is critical to isolate, and perhaps quantify, electrochemical interfaces contributing to observed potentials.

  13. Ionization detector, electrode configuration and single polarity charge detection method

    DOE Patents [OSTI]

    He, Zhong

    1998-01-01

    An ionization detector, an electrode configuration and a single polarity charge detection method each utilize a boundary electrode which symmetrically surrounds first and second central interlaced and symmetrical electrodes. All of the electrodes are held at a voltage potential of a first polarity type. The first central electrode is held at a higher potential than the second central or boundary electrodes. By forming the first and second central electrodes in a substantially interlaced and symmetrical pattern and forming the boundary electrode symmetrically about the first and second central electrodes, signals generated by charge carriers are substantially of equal strength with respect to both of the central electrodes. The only significant difference in measured signal strength occurs when the charge carriers move to within close proximity of the first central electrode and are received at the first central electrode. The measured signals are then subtracted and compared to quantitatively measure the magnitude of the charge.

  14. Ionization detector, electrode configuration and single polarity charge detection method

    DOE Patents [OSTI]

    He, Z.

    1998-07-07

    An ionization detector, an electrode configuration and a single polarity charge detection method each utilize a boundary electrode which symmetrically surrounds first and second central interlaced and symmetrical electrodes. All of the electrodes are held at a voltage potential of a first polarity type. The first central electrode is held at a higher potential than the second central or boundary electrodes. By forming the first and second central electrodes in a substantially interlaced and symmetrical pattern and forming the boundary electrode symmetrically about the first and second central electrodes, signals generated by charge carriers are substantially of equal strength with respect to both of the central electrodes. The only significant difference in measured signal strength occurs when the charge carriers move to within close proximity of the first central electrode and are received at the first central electrode. The measured signals are then subtracted and compared to quantitatively measure the magnitude of the charge. 10 figs.

  15. Development of Industrially Viable Battery Electrode Coatings | Department

    Broader source: Energy.gov (indexed) [DOE]

    of Energy 62_tenent_2012_o.pdf More Documents & Publications Development of Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings

  16. Layered Copper-Based Electrode for High-Dielectric Constant Oxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin-Film-Based Devices | Argonne National Laboratory Copper-Based Electrode for High-Dielectric Constant Oxide Thin-Film-Based Devices Technology available for licenisng: A multilayer thin-film device containing copper layers protected by amorphous TiAl oxide and devices incorporating TiAl. Offers high conductivity and protection against oxidation Low-cost process PDF icon copper_based_electrode

  17. The Crystallization of PEDOT:PSS Polymeric Electrodes Probed In Situ during

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printing Crystallization of PEDOT:PSS Polymeric Electrodes Probed In Situ during Printing The Crystallization of PEDOT:PSS Polymeric Electrodes Probed In Situ during Printing Print Wednesday, 15 July 2015 00:00 Organic electronics have emerged into a highly interesting field of research with a great variety of applications. P. Müller-Buschbaum and co-workers demonstrate the importance of in situ investigations during the printing process of organic electronics. In situ grazing-incidence

  18. Steam drying of products containing solvent mixtures

    SciTech Connect (OSTI)

    Pothmann, E.; Schluender, E.U. [Univ. Karlsruhe (Germany). Inst. fuer Thermische Verfahrenstechnik

    1995-12-31

    Drying experiments with single, porous spheres wetted with mixtures of 2-propanol and water were performed using superheated steam, air, or steam-air mixtures as drying agent. Both the drying rate and the moisture composition were determined experimentally for different temperatures and compositions of the drying agent and for different initial compositions of the moisture. It is shown that evaporation of 2-propanol is enhanced by using superheated steam as drying agent instead of air due to steam condensing on the sample. While the overall drying rate increases with rising steam temperature, the evaporation rate of 2-propanol is hardly affected. When drying samples containing mixtures of 2-propanol and water, internal boiling can occur depending on the vapor-liquid equilibrium. Vapor generated inside the sample may cause mechanical dewatering of the sample which greatly increases the drying rate.

  19. Low temperature formation of electrode having electrically conductive metal oxide surface

    DOE Patents [OSTI]

    Anders, Simone; Anders, Andre; Brown, Ian G.; McLarnon, Frank R.; Kong, Fanping

    1998-01-01

    A low temperature process is disclosed for forming metal suboxides on substrates by cathodic arc deposition by either controlling the pressure of the oxygen present in the deposition chamber, or by controlling the density of the metal flux, or by a combination of such adjustments, to thereby control the ratio of oxide to metal in the deposited metal suboxide coating. The density of the metal flux may, in turn, be adjusted by controlling the discharge current of the arc, by adjusting the pulse length (duration of on cycle) of the arc, and by adjusting the frequency of the arc, or any combination of these parameters. In a preferred embodiment, a low temperature process is disclosed for forming an electrically conductive metal suboxide, such as, for example, an electrically conductive suboxide of titanium, on an electrode surface, such as the surface of a nickel oxide electrode, by such cathodic arc deposition and control of the deposition parameters. In the preferred embodiment, the process results in a titanium suboxide-coated nickel oxide electrode exhibiting reduced parasitic evolution of oxygen during charging of a cell made using such an electrode as the positive electrode, as well as exhibiting high oxygen overpotential, resulting in suppression of oxygen evolution at the electrode at full charge of the cell.

  20. Positive and Negative Electrodes: Novel and Optimized Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Positive and Negative Electrodes: Novel and Optimized Materials Positive and Negative Electrodes: Novel and Optimized Materials 2010 DOE Vehicle Technologies and Hydrogen Programs...

  1. Microscale Electrode Design Using Coupled Kinetic, Thermal and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical Modeling Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical Modeling 2009 DOE ...

  2. simulate the dynamic distribution of lithium in the electrode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulate the dynamic distribution of lithium in the electrode - Sandia Energy Energy ... simulate the dynamic distribution of lithium in the electrode HomeTag:simulate the ...

  3. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit ... Screen Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrode ...

  4. Diagnostics for the biased electrode experiment on NSTX (Journal...

    Office of Scientific and Technical Information (OSTI)

    Diagnostics for the biased electrode experiment on NSTX Citation Details In-Document Search Title: Diagnostics for the biased electrode experiment on NSTX A linear array of four ...

  5. Nano-sized structured layered positive electrode materials to...

    Office of Scientific and Technical Information (OSTI)

    positive electrode materials to enable high energy density and high rate capability lithium batteries Title: Nano-sized structured layered positive electrode materials to ...

  6. System of fabricating a flexible electrode array (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    System of fabricating a flexible electrode array Title: System of fabricating a flexible electrode array An image is captured or otherwise converted into a signal in an artificial ...

  7. Long life lithium batteries with stabilized electrodes (Patent...

    Office of Scientific and Technical Information (OSTI)

    The present invention relates to non-aqueous electrolytes having electrode stabilizing ... an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. ...

  8. Towards predicting the voltage drop between electrode and electrolyte...

    Office of Scientific and Technical Information (OSTI)

    drop between electrode and electrolyte in lithium ion batteries. Citation Details In-Document Search Title: Towards predicting the voltage drop between electrode and electrolyte ...

  9. Investigation of critical parameters in Li-ion battery electrodes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    critical parameters in Li-ion battery electrodes Investigation of critical parameters in Li-ion battery electrodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle ...

  10. Long life lithium batteries with stabilized electrodes (Patent...

    Office of Scientific and Technical Information (OSTI)

    Long life lithium batteries with stabilized electrodes Title: Long life lithium batteries with stabilized electrodes The present invention relates to non-aqueous electrolytes ...

  11. Electrode material comprising graphene-composite materials in...

    Office of Scientific and Technical Information (OSTI)

    Title: Electrode material comprising graphene-composite materials in a graphite network A durable electrode material suitable for use in Li ion batteries is provided. The material ...

  12. Long life lithium batteries with stabilized electrodes (Patent...

    Office of Scientific and Technical Information (OSTI)

    Data Explorer Search Results Long life lithium batteries with stabilized electrodes Title: Long life lithium batteries with stabilized electrodes The present invention relates to ...

  13. First Principles Calculations (and NMR Spectroscopy of Electrode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (and NMR Spectroscopy of Electrode Materials) First Principles Calculations (and NMR Spectroscopy of Electrode Materials) 2009 DOE Hydrogen Program and Vehicle Technologies Program ...

  14. First Principles Calculations and NMR Spectroscopy of Electrode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and NMR Spectroscopy of Electrode Materials First Principles Calculations and NMR Spectroscopy of Electrode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle ...

  15. First Principles Calculations and NMR Spectroscopy of Electrode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and NMR Spectroscopy of Electrode Materials First Principles Calculations and NMR Spectroscopy of Electrode Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program ...

  16. Hierarchical electrode architectures for electrical energy storage & conversion.

    SciTech Connect (OSTI)

    Zavadil, Kevin Robert; Missert, Nancy A.; Shelnutt, John Allen; van Swol, Frank B.

    2012-01-01

    The integration and stability of electrocatalytic nanostructures, which represent one level of porosity in a hierarchical structural scheme when combined with a three-dimensional support scaffold, has been studied using a combination of synthetic processes, characterization techniques, and computational methods. Dendritic platinum nanostructures have been covalently linked to common electrode surfaces using a newly developed chemical route; a chemical route equally applicable to a range of metals, oxides, and semiconductive materials. Characterization of the resulting bound nanostructure system confirms successful binding, while electrochemistry and microscopy demonstrate the viability of these electroactive particles. Scanning tunneling microscopy has been used to image and validate the short-term stability of several electrode-bound platinum dendritic sheet structures toward Oswald ripening. Kinetic Monte Carlo methods have been applied to develop an understanding of the stability of the basic nano-scale porous platinum sheets as they transform from an initial dendrite to hole containing sheets. Alternate synthetic strategies were pursued to grow dendritic platinum structures directly onto subunits (graphitic particles) of the electrode scaffold. A two-step photocatalytic seeding process proved successful at generating desirable nano-scale porous structures. Growth in-place is an alternate strategy to the covalent linking of the electrocatalytic nanostructures.

  17. Electrode systems for in situ vitrification

    DOE Patents [OSTI]

    Buelt, James L.; Carter, John G.; Eschbach, Eugene A.; FitzPatrick, Vincent F.; Koehmstedt, Paul L.; Morgan, William C.; Oma, Kenton H.; Timmerman, Craig L.

    1990-01-01

    An electrode comprising a molybdenum rod is received within a conductive collar formed of graphite. The molybdenum rod and the graphite collar may be physically joined at the bottom. A pair of such electrodes are placed in soil containing buried waste material and an electric current is passed therebetween for vitrifying the soil. The graphite collar enhances the thermal conductivity of the combination, bringing heat to the surface, and preventing formation of a cold cap of material above the ground surface. The annulus between the molybdenum rod electrode and the graphite collar is suitably filled with a conductive ceramic powder that sinters upon the molybdenum rod, protecting the same from oxidation as graphite material is consumed, or a metal powder which liquefies at operating temperatures. The center of the molybdenum rod, used with a collar of separately, can be hollow and filled with a powdered metal, such as copper, which liquefies at operating temperatures. Connection to electrodes can be provided below ground level to avoid open circuit due to electrode deterioration, or sacrificial electrodes may be employed when operation is started. Outboard electrodes cna be utilized to square up a vitrified area.

  18. Dry scrubbing of SO/sub 2/

    SciTech Connect (OSTI)

    Shah, N.D.

    1982-06-01

    The advantages of dry scrubbing over wet scrubbing or spray drying are considered. One of the problem areas is that of waste disposal. The most cost-effective solutions are land disposal or landfill in clay cells. The factors influencing the selection of an SO/sub 2/ scrubbing system are discussed. Nahcolite appears to be the most promising agent for dry scrubbing.

  19. Compton Dry-Cask Imaging System

    ScienceCinema (OSTI)

    None

    2013-05-28

    The Compton-Dry Cask Imaging Scanner is a system that verifies and documents the presence of spent nuclear fuel rods in dry-cask storage and determines their isotopic composition without moving or opening the cask. For more information about this project, visit http://www.inl.gov/rd100/2011/compton-dry-cask-imaging-system/

  20. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P.

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  1. Ethanol production with dilute acid hydrolysis using partially dried lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A.; Keller, Fred A.; Tucker, Melvin P.

    2003-12-09

    A process of converting lignocellulosic biomass to ethanol, comprising hydrolyzing lignocellulosic materials by subjecting dried lignocellulosic material in a reactor to a catalyst comprised of a dilute solution of a strong acid and a metal salt to lower the activation energy (i.e., the temperature) of cellulose hydrolysis and ultimately obtain higher sugar yields.

  2. POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING

    SciTech Connect (OSTI)

    R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

    2001-04-30

    Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would suffer from low throughput capacities and high maintenance requirements. In general, surface area-based separators (e.g., shaking tables, magnetic drum separator, electrodynamic separator, etc.) have lower throughput capacities than volume-based separators (e.g., flotation cell, dense-medium bath, cyclones, etc.) by an order of magnitude. Furthermore, the electrodes of the laboratory unit need to be cleaned frequently, creating a high maintenance requirement if it is scaled-up to a commercial unit. The bench-scale continuous TES unit developed at NETL, on the other hand, separates positively and negatively charged particles by splitting the gaseous stream containing these particles in an electric field by means of a flow splitter, so that the oppositely charged particles can be directed into different compartments. This device is fundamentally different from the laboratory unit in that the former is a surface area-based separator, while the latter is a volume-based separator. The bench-scale unit is referred to as an entrained flow separator by the in-house researchers at NETL. Thus, the entrained flow TES unit is a significant improvement over the laboratory unit with regard to throughput capacity. In the present work, the entrained flow separator concept will be utilized for developing a proof-of concept (POC) separator that can be scaled-up to commercial size units. To accomplish this, it is necessary to develop a bench-scale separator that can achieve high Btu recoveries while maintaining the high degree of separation efficiencies. It is the objective of the present investigation to develop an efficient separator by studying the mechanisms of triboelectrification and investigating better ways of separating the charged particles. An important criterion for developing efficient separators is that they not only provide high separation efficiencies but also have high throughput capacities, which are essential ingredients for successful commercialization.

  3. Redox polymer electrodes for advanced batteries

    DOE Patents [OSTI]

    Gregg, Brian A.; Taylor, A. Michael

    1998-01-01

    Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene.

  4. Redox polymer electrodes for advanced batteries

    DOE Patents [OSTI]

    Gregg, B.A.; Taylor, A.M.

    1998-11-24

    Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene. 2 figs.

  5. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A.; Townsend, Carl W.

    1989-01-01

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  6. Trends in powder processing equipment

    SciTech Connect (OSTI)

    Sheppard, L.M.

    1993-05-01

    Spray drying is the most widely used process for producing particles. It is used in industries other than ceramics including food, chemicals, and pharmaceutical. The process involves the atomization of a liquid feed stock into a spray of droplets and contacting the droplets with hot air in a drying chamber. The sprays are produced by either rotary or nozzle atomizers. Evaporation of moisture from the droplets and formation of dry particles proceed under controlled temperature and airflow conditions. Powder is then discharged continuously from the drying chamber. Spray drying equipment is being improved to handle an ever-increasing number of applications. Several developments in particle-size reduction equipment are also described.

  7. Dry-cleaning of graphene

    SciTech Connect (OSTI)

    Algara-Siller, Gerardo; Lehtinen, Ossi; Kaiser, Ute; Turchanin, Andrey

    2014-04-14

    Studies of the structural and electronic properties of graphene in its pristine state are hindered by hydrocarbon contamination on the surfaces. Also, in many applications, contamination reduces the performance of graphene. Contamination is introduced during sample preparation and is adsorbed also directly from air. Here, we report on the development of a simple dry-cleaning method for producing large atomically clean areas in free-standing graphene. The cleanness of graphene is proven using aberration-corrected high-resolution transmission electron microscopy and electron spectroscopy.

  8. Dry Transfer Systems for Used Nuclear Fuel

    SciTech Connect (OSTI)

    Brett W. Carlsen; Michaele BradyRaap

    2012-05-01

    The potential need for a dry transfer system (DTS) to enable retrieval of used nuclear fuel (UNF) for inspection or repackaging will increase as the duration and quantity of fuel in dry storage increases. This report explores the uses for a DTS, identifies associated general functional requirements, and reviews existing and proposed systems that currently perform dry fuel transfers. The focus of this paper is on the need for a DTS to enable transfer of bare fuel assemblies. Dry transfer systems for UNF canisters are currently available and in use for transferring loaded canisters between the drying station and storage and transportation casks.

  9. Federal Offshore--Gulf of Mexico Dry Natural Gas Production ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Dry Natural Gas Production (Million Cubic Feet) Federal Offshore--Gulf of Mexico Dry ... Natural Gas Dry Production Federal Offshore Gulf of Mexico Natural Gas Gross Withdrawals ...

  10. California Dry Natural Gas Reserves Sales (Billion Cubic Feet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Sales (Billion Cubic Feet) California Dry Natural Gas Reserves Sales (Billion Cubic Feet) ... Referring Pages: Dry Natural Gas Reserves Sales California Dry Natural Gas Proved Reserves ...

  11. California--State Offshore Natural Gas Dry Production (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Dry Production (Million Cubic Feet) California--State Offshore Natural Gas Dry Production ... Referring Pages: Natural Gas Dry Production California State Offshore Natural Gas Gross ...

  12. California Dry Natural Gas Reserves Estimated Production (Billion...

    Gasoline and Diesel Fuel Update (EIA)

    Estimated Production (Billion Cubic Feet) California Dry Natural Gas Reserves Estimated ... Dry Natural Gas Reserves Estimated Production California Dry Natural Gas Proved Reserves ...

  13. California Dry Natural Gas Reserves Acquisitions (Billion Cubic...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Acquisitions (Billion Cubic Feet) California Dry Natural Gas Reserves Acquisitions ... Referring Pages: Dry Natural Gas Reserves Acquisitions California Dry Natural Gas Proved ...

  14. California Dry Natural Gas Reserves Extensions (Billion Cubic...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Extensions (Billion Cubic Feet) California Dry Natural Gas Reserves Extensions (Billion ... Referring Pages: Dry Natural Gas Reserves Extensions California Dry Natural Gas Proved ...

  15. California Dry Natural Gas Reserves New Field Discoveries (Billion...

    Gasoline and Diesel Fuel Update (EIA)

    New Field Discoveries (Billion Cubic Feet) California Dry Natural Gas Reserves New Field ... New Field Discoveries of Dry Natural Gas Reserves California Dry Natural Gas Proved ...

  16. California Dry Natural Gas Reserves Adjustments (Billion Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Adjustments (Billion Cubic Feet) California Dry Natural Gas Reserves Adjustments (Billion ... Referring Pages: Dry Natural Gas Reserves Adjustments California Dry Natural Gas Proved ...

  17. Dry borax applicator operator's manual.

    SciTech Connect (OSTI)

    Karsky, Richard, J.

    1999-01-01

    Annosum root rot affects conifers throughout the Northern Hemisphere, infecting their roots and eventually killing the trees. The fungus Heterobasidion annosum causes annosum root rot. The fungus colonizes readily on freshly cut stumps. Partially cut stands have a high risk of infestation because the fungus can colonize on each of the stumps and potentially infect the neighboring trees. Wind and rain carry the annosum spores. Spores that land on freshly cut stumps grow down the stump's root system where they can infect living trees through root grafts or root contacts. Once annosum becomes established, it can remain active for many years in the Southern United States and for several decades in the north. About 7% of the trees that become infected die. When thinning, stumps can be treated successfully using a competing fungus, Phlebia gigantea, and with ''Tim-Bor'' in liquid formulations. These liquid products are no longer approved in the United States. Only the dry powder form is registered and approved by the EPA. Stumps can be treated with a dry formula of borax, (Sporax), significantly reducing one of the primary routes by which Heterobasidion annosum infects a stand of trees. Sporax is used by the USDA Forest Service to control annosum root rot. Sporax is now applied by hand, but once the felled trees are skidded it becomes very hard to locate the stumps. A stump applicator will reduce error, labor costs, and hazards to workers.

  18. Optimization design of electrodes for anode-supported solid oxide fuel cells via genetic algorithm

    SciTech Connect (OSTI)

    Shi, J.; Xue, X.

    2011-01-01

    Porous electrode is the critical component of solid-oxide fuel cells (SOFCs) and provides a functional material backbone for multi-physicochemical processes. Model based electrode designs could significantly improve SOFC performance. This task is usually performed via parameter studies for simple case and assumed property distributions for graded electrodes. When nonlinearly coupled multiparameters of electrodes are considered, it could be very difficult for the model based parameter study method to effectively and systematically search the design space. In this research, the optimization approach with a genetic algorithm is demonstrated for this purpose. An anode-supported proton conducting SOFC integrated with a fuel supply system is utilized as a physical base for the model development and the optimization design. The optimization results are presented, which are difficult to obtain for parametric study method.

  19. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  20. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S.

    2012-07-24

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  1. Manganese oxide composite electrodes for lithium batteries

    DOE Patents [OSTI]

    Johnson, Christopher S.; Kang, Sun-Ho; Thackeray, Michael M.

    2009-12-22

    An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0.5electrode and 0.ltoreq.y<1 in which the Li.sub.2MnO.sub.3 and LiMn.sub.2-yM.sub.yO.sub.4 components have layered and spinel-type structures, respectively, and in which M is one or more metal cations. The electrode is activated by removing lithia, or lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

  2. Surface protected lithium-metal-oxide electrodes

    DOE Patents [OSTI]

    Thackeray, Michael M.; Kang, Sun-Ho

    2016-04-05

    A lithium-metal-oxide positive electrode having a layered or spinel structure for a non-aqueous lithium electrochemical cell and battery is disclosed comprising electrode particles that are protected at the surface from undesirable effects, such as electrolyte oxidation, oxygen loss or dissolution by one or more lithium-metal-polyanionic compounds, such as a lithium-metal-phosphate or a lithium-metal-silicate material that can act as a solid electrolyte at or above the operating potential of the lithium-metal-oxide electrode. The surface protection significantly enhances the surface stability, rate capability and cycling stability of the lithium-metal-oxide electrodes, particularly when charged to high potentials.

  3. Electrode for molten carbonate fuel cell

    DOE Patents [OSTI]

    Iacovangelo, Charles D. (Schenectady, NY); Zarnoch, Kenneth P. (Clifton Park, NY)

    1983-01-01

    A sintered porous electrode useful for a molten carbonate fuel cell is produced which is composed of a plurality of 5 wt. % to 95 wt. % nickel balance copper alloy encapsulated ceramic particles sintered together by the alloy.

  4. Electrode geometry for electrostatic generators and motors

    DOE Patents [OSTI]

    Post, Richard F.

    2016-02-23

    An electrostatic (ES) device is described with electrodes that improve its performance metrics. Devices include ES generators and ES motors, which are comprised of one or more stators (stationary members) and one or more rotors (rotatable members). The stator and rotors are configured as a pair of concentric cylindrical structures and aligned about a common axis. The stator and rotor are comprised of an ensemble of discrete, longitudinal electrodes, which are axially oriented in an annular arrangement. The shape of the electrodes described herein enables the ES device to function at voltages significantly greater than that of the existing art, resulting in devices with greater power-handling capability and overall efficiency. Electrode shapes include, but are not limited to, rods, corrugated sheets and emulations thereof.

  5. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The energy and evolution of the second new peak suggest that strain-induced morphological changes are induced in the 3D-NG electrode during charging. From simulations of...

  6. Field Emission Measurements from Niobium Electrodes

    SciTech Connect (OSTI)

    M. BastaniNejad, P.A. Adderley, J. Clark, S. Covert, J. Hansknecht, C. Hernandez-Garcia, R. Mammei, M. Poelker

    2011-03-01

    Increasing the operating voltage of a DC high voltage photogun serves to minimize space charge induced emittance growth and thereby preserve electron beam brightness, however, field emission from the photogun cathode electrode can pose significant problems: constant low level field emission degrades vacuum via electron stimulated desorption which in turn reduces photocathode yield through chemical poisoning and/or ion bombardment and high levels of field emission can damage the ceramic insulator. Niobium electrodes (single crystal, large grain and fine grain) were characterized using a DC high voltage field emission test stand at maximum voltage -225kV and electric field gradient > 10MV/m. Niobium electrodes appear to be superior to diamond-paste polished stainless steel electrodes.

  7. Magnetron cathodes in plasma electrode pockels cells

    DOE Patents [OSTI]

    Rhodes, Mark A.

    1995-01-01

    Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating. pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal.

  8. Magnetron cathodes in plasma electrode Pockels cells

    DOE Patents [OSTI]

    Rhodes, M.A.

    1995-04-25

    Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal. 5 figs.

  9. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

    1997-06-10

    Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

  10. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, James L.; Tran, Tri D.; Feikert, John H.; Mayer, Steven T.

    1997-01-01

    Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

  11. Spectroscopy of Supercapacitor Electrodes In Operando

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrode in 1 M NaCl (aq) under (a) constant dc biases between +250 and +1000 mV (green), (b) zero bias (orange), and (c) -1000 mV (dark blue). Fits to the experimental...

  12. Understanding the Factors Affecting the Formation of Carbonyl Iron Electrodes in Rechargeable Alkaline Iron Batteries

    SciTech Connect (OSTI)

    Manohar, AK; Yang, CG; Malkhandi, S; Yang, B; Prakash, GKS; Narayanan, SR

    2012-01-01

    Rechargeable iron-based alkaline batteries such as iron - air and nickel - iron batteries are attractive for large-scale electrical energy storage because iron is inexpensive, globally-abundant and environmentally-friendly. Further, the iron electrode is known for its robustness to repeated charge/discharge cycling. During manufacturing these batteries are charged and discharged 20 to 50 times during which the discharge capacity of the iron electrode increases gradually and attains a stable value. This process of achieving stable capacity is called formation. In this study we have focused our efforts on understanding the effect of electrode design on formation. We have investigated the role of wetting agent, pore-former additive, and sulfide additive on the formation of carbonyl iron electrodes. The wetting agent increased the rate of formation while the pore-former additive increased the final capacity. Sodium sulfide added to the electrolyte worked as a de-passivation agent and increased the final discharge capacity. We have proposed a phenomenological model for the formation process that predicts the rate of formation and final discharge capacity given the design parameters for the electrode. The understanding gained here will be useful in reducing the time lost in formation and in maximizing the utilization of the iron electrode. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.021301jes] All rights reserved.

  13. Assessment of superheated steam drying of wood waste

    SciTech Connect (OSTI)

    Woods, B.G.; Nguyen, Y.; Bruce, S.

    1994-12-31

    A 5 MW co-generation facility using wood waste is described which will supply power to Ontario Hydro, steam to the sawmill for process heating, and hot water for district heating customers in the town. The use of superheated steam for drying the wood was investigated to determine the impact on boiler performance, the environmental impact and the economic feasibility. The main benefit with superheated steam drying is the reduction in VOC emissions. The capital cost is currently higher with superheated steam drying, but further investigation is warranted to determine if the cost reductions which could be achieved by manufacturing the major components in North America are sufficient to make the technology cost competitive.

  14. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, M.; Kaun, T.

    1984-01-20

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical c

  15. Germanium Oxide Nanoparticlesfor Superior Battery Electrodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Germanium Oxide Nanoparticlesfor Superior Battery Electrodes Brookhaven National Laboratory Contact BNL About This Technology Technology Marketing Summary Compared to the graphite found in some batteries, similar elements such as tin, silicon, and germanium have much higher theoretical capacities for lithium ions, making them strong candidates for electrode materials. These new amorphous germanium

  16. Membrane-electrode assemblies for electrochemical cells

    DOE Patents [OSTI]

    Swathirajan, Sundararajan; Mikhail, Youssef M.

    1993-01-01

    A combination, unitary, membrane and electrode assembly with a solid polymer electrolyte membrane, and first and second electrodes at least partially embedded in opposed surfaces of the membrane. The electrodes each comprise a respective group of finely divided carbon particles, very finely divided catalytic particles supported on internal and external surfaces of the carbon particles and a proton conductive material intermingled with the catalytic and carbon particles. A first group of finely divided carbon particles forming the first electrode has greater water attraction and retention properties, and is more hydrophilic than a second group of carbon particles forming the second electrode. In a preferred method, the membrane electrode assembly of the invention is prepared by forming a slurry of proton conductive material and at least one group of the carbon and catalyst particles. The slurry is applied to the opposed surfaces of the membrane and heated while being pressed to the membrane for a time and at a temperature and compressive load sufficient to embed at least a portion of the particles into the membrane.

  17. Evaluation of electropolished stainless steel electrodes for use in DC high voltage photoelectron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    BastaniNejad, Mahzad; Elmustafa, Abdelmageed A.; Forman, Eric; Covert, Steven; Hansknecht, John; Hernandez-Garcia, Carlos; Poelker, Matthew; Das, Lopa; Kelley, Michael; Williams, Phillip

    2015-07-01

    DC high voltage photoelectron guns are used to produce polarized electron beams for accelerator-based nuclear and high-energy physics research. Low-level field emission (~nA) from the cathode electrode degrades the vacuum within the photogun and reduces the photoelectron yield of the delicate GaAs-based photocathode used to produce the electron beams. High-level field emission (>μA) can cause significant damage the photogun. To minimize field emission, stainless steel electrodes are typically diamond-paste polished, a labor-intensive process often yielding field emission performance with a high degree of variability, sample to sample. As an alternative approach and as comparative study, the performance of electrodes electropolishedmore » by conventional commercially available methods is presented. Our observations indicate the electropolished electrodes exhibited less field emission upon the initial application of high voltage, but showed less improvement with gas conditioning compared to the diamond-paste polished electrodes. In contrast, the diamond-paste polished electrodes responded favorably to gas conditioning, and ultimately reached higher voltages and field strengths without field emission, compared to electrodes that were only electropolished. The best performing electrode was one that was both diamond-paste polished and electropolished, reaching a field strength of 18.7 MV/m while generating less than 100 pA of field emission. The speculate that the combined processes were the most effective at reducing both large and small scale topography. However, surface science evaluation indicates topography cannot be the only relevant parameter when it comes to predicting field emission performance.« less

  18. Evaluation of electropolished stainless steel electrodes for use in DC high voltage photoelectron guns

    SciTech Connect (OSTI)

    BastaniNejad, Mahzad; Elmustafa, Abdelmageed A.; Forman, Eric; Covert, Steven; Hansknecht, John; Hernandez-Garcia, Carlos; Poelker, Matthew; Das, Lopa; Kelley, Michael; Williams, Phillip

    2015-07-01

    DC high voltage photoelectron guns are used to produce polarized electron beams for accelerator-based nuclear and high-energy physics research. Low-level field emission (~nA) from the cathode electrode degrades the vacuum within the photogun and reduces the photoelectron yield of the delicate GaAs-based photocathode used to produce the electron beams. High-level field emission (>?A) can cause significant damage the photogun. To minimize field emission, stainless steel electrodes are typically diamond-paste polished, a labor-intensive process often yielding field emission performance with a high degree of variability, sample to sample. As an alternative approach and as comparative study, the performance of electrodes electropolished by conventional commercially available methods is presented. Our observations indicate the electropolished electrodes exhibited less field emission upon the initial application of high voltage, but showed less improvement with gas conditioning compared to the diamond-paste polished electrodes. In contrast, the diamond-paste polished electrodes responded favorably to gas conditioning, and ultimately reached higher voltages and field strengths without field emission, compared to electrodes that were only electropolished. The best performing electrode was one that was both diamond-paste polished and electropolished, reaching a field strength of 18.7 MV/m while generating less than 100 pA of field emission. The speculate that the combined processes were the most effective at reducing both large and small scale topography. However, surface science evaluation indicates topography cannot be the only relevant parameter when it comes to predicting field emission performance.

  19. Evaluation of electropolished stainless steel electrodes for use in DC high voltage photoelectron guns

    SciTech Connect (OSTI)

    BastaniNejad, Mahzad Elmustafa, Abdelmageed A.; Forman, Eric; Covert, Steven; Hansknecht, John; Hernandez-Garcia, Carlos; Poelker, Matthew; Das, Lopa; Kelley, Michael; Williams, Phillip

    2015-07-15

    DC high voltage photoelectron guns are used to produce polarized electron beams for accelerator-based nuclear and high-energy physics research. Low-level field emission (?nA) from the cathode electrode degrades the vacuum within the photogun and reduces the photoelectron yield of the delicate GaAs-based photocathode used to produce the electron beams. High-level field emission (>?A) can cause significant damage the photogun. To minimize field emission, stainless steel electrodes are typically diamond-paste polished, a labor-intensive process often yielding field emission performance with a high degree of variability, sample to sample. As an alternative approach and as comparative study, the performance of electrodes electropolished by conventional commercially available methods is presented. Our observations indicate the electropolished electrodes exhibited less field emission upon the initial application of high voltage, but showed less improvement with gas conditioning compared to the diamond-paste polished electrodes. In contrast, the diamond-paste polished electrodes responded favorably to gas conditioning, and ultimately reached higher voltages and field strengths without field emission, compared to electrodes that were only electropolished. The best performing electrode was one that was both diamond-paste polished and electropolished, reaching a field strength of 18.7 MV/m while generating less than 100?pA of field emission. The authors speculate that the combined processes were the most effective at reducing both large and small scale topography. However, surface science evaluation indicates topography cannot be the only relevant parameter when it comes to predicting field emission performance.

  20. Tape method of forming a thin layer of doped lanthanum chromite particles and of bonding such on an electrode

    DOE Patents [OSTI]

    Richards, Von L.; Singhal, Subhash C.; Pal, Uday B.

    1992-01-01

    A combustible polymer film, useful for application of an interconnection on an electrode is made by: (1) providing doped LaCro.sub.3 particles; (2) dispersing doped LaCrO.sub.3 particles in a solvent, to provide a dispersion; (3) screening the dispersion to provide particles in the range of from 30 micrometers to 80 micrometers; (4) admixing a fugitive polymer with the particles; (5) casting the dispersion to provide a film; (6) drying the film; and (7) stripping the film. The film can then be applied to a porous, preheated electrode top surface, and then electrochemical vapor depositing a dense skeletal LaCrO.sub.3 structure, between and around the doped LaCrO.sub.3 particles. Additional solid oxide electrolyte and fuel electrode layers can then be added to provide a fuel cell.

  1. Tape method of forming a thin layer of doped lanthanum chromite particles and of bonding such on an electrode

    DOE Patents [OSTI]

    Richards, V.L.; Singhal, S.C.; Pal, U.B.

    1992-07-21

    A combustible polymer film, useful for application of an interconnection on an electrode is made by: (1) providing doped LaCro[sub 3] particles; (2) dispersing doped LaCrO[sub 3] particles in a solvent, to provide a dispersion; (3) screening the dispersion to provide particles in the range of from 30 micrometers to 80 micrometers; (4) admixing a fugitive polymer with the particles; (5) casting the dispersion to provide a film; (6) drying the film; and (7) stripping the film. The film can then be applied to a porous, preheated electrode top surface, and then a dense skeletal LaCrO[sub 3] structure is electrochemically vapor deposited between and around the doped LaCrO[sub 3] particles. Additional solid oxide electrolyte and fuel electrode layers can then be added to provide a fuel cell. 4 figs.

  2. Reinforced Electrode Architecture for a Flexible Battery with Paperlike Characteristics

    SciTech Connect (OSTI)

    Gaikwad, AM; Chu, HN; Qeraj, R; Zamarayeva, AM; Steingart, DA

    2013-02-10

    Compliant energy storage has not kept pace with flexible electronics. Herein we demonstrate a technique to reinforce arbitrary battery electrodes by supporting them with mechanically tough, low-cost fibrous membranes, which also serve as the separator. The membranes were laminated to form a full cell, and this stacked membrane reinforcement bears the loads during flexing. This technique was used to make a high energy density, nontoxic Zn-MnO2 battery with printed current collectors. The Zn and MnO2 electrodes were prepared by using a solution-based embedding process. The cell had a nominal potential of 1.5 V and an effective capacity of approximately 3 mA h cm(-2). We investigated the effect of bending and fatigue on the electrochemical performance and mechanical integrity of the battery. The battery was able to maintain its capacity even after 1000 flex cycles to a bend radius of 2.54 cm. The battery showed an improvement in discharge capacity (ca. 10%) if the MnO2 electrode was flexed to tension as a result of the improvement of particle-to-particle contact. In a demonstration, the flexible battery was used to power a light-emitting diode display integrated with a strain sensor and microcontroller.

  3. Electrode electrolyte interlayers containing cerium oxide for electrochemical fuel cells

    DOE Patents [OSTI]

    Borglum, Brian P.; Bessette, Norman F.

    2000-01-01

    An electrochemical cell is made having a porous fuel electrode (16) and a porous air electrode (13), with solid oxide electrolyte (15) therebetween, where the air electrode surface opposing the electrolyte has a separate, attached, dense, continuous layer (14) of a material containing cerium oxide, and where electrolyte (16) contacts the continuous oxide layer (14), without contacting the air electrode (13).

  4. Electrode immersion depth determination and control in electroslag remelting furnace

    DOE Patents [OSTI]

    Melgaard, David K.; Beaman, Joseph J.; Shelmidine, Gregory J.

    2007-02-20

    An apparatus and method for controlling an electroslag remelting furnace comprising adjusting electrode drive speed by an amount proportional to a difference between a metric of electrode immersion and a set point, monitoring impedance or voltage, and calculating the metric of electrode immersion depth based upon a predetermined characterization of electrode immersion depth as a function of impedance or voltage.

  5. Second survey of dry SO/sub 2/ control systems. Final report Mar-Sep 80

    SciTech Connect (OSTI)

    Kelly, M.E.; Shareef, S.A.

    1981-02-01

    The report is an updated assessment of dry flue gas desulfurization (FGD) systems. Current and recently completed research, development, and commercial activities in the U.S. since October 1979, are reviewed including: (1) spray dryers with a fabric filter or an electrostatic precipitator (ESP), (2) dry injection of alkaline material into flue gas combined with particulate collection in an ESP or fabric filter, and (3) combustion of coal/alkali fuel mixtures. Spray drying remains the only commercially applied dry FGD process. Since the last survey, completed late in 1979, eight utility and two industrial spray drying systems have been sold. Nine of them use lime as the sorbent, and nine use a fabric filter for particulate collection. Removal guarantees for so/sub 2/ range from 62 to 85%, depending on coal sulfur content. Two full-scale industrial spray drying systems are currently operating. The first large utility system is scheduled for startup early in 1981. Several publicly and privately funded pilot-scale programs have been completed in the past year. EPA is currently funding three such programs (two spray drying and one dry injection), as well as development of two combustion modification processes for SO2 control (combustion of coal/limestone pellets and of a pulverized coal/alkali mixture in a low-NOx burner). The DoE and others are studying dry injection on a pilot scale.

  6. Wetter for fine dry powder

    DOE Patents [OSTI]

    Hall, James E.; Williams, Everett H.

    1977-01-01

    A system for wetting fine dry powders such as bentonite clay with water or other liquids is described. The system includes a wetting tank for receiving water and a continuous flow of fine powder feed. The wetting tank has a generally square horizontal cross section with a bottom end closure in the shape of an inverted pyramid. Positioned centrally within the wetting tank is a flow control cylinder which is supported from the walls of the wetting tank by means of radially extending inclined baffles. A variable speed motor drives a first larger propeller positioned immediately below the flow control cylinder in a direction which forces liquid filling the tank to flow downward through the flow control cylinder and a second smaller propeller positioned below the larger propeller having a reverse pitch to oppose the flow of liquid being driven downward by the larger propeller.

  7. Capacitive, deionization with carbon aerogel electrodes: Carbonate, sulfate, and phosphate

    SciTech Connect (OSTI)

    Farmer, J.C.; Fix, D.V.; Mack, G.V.; Pekala, R.W.; Poco, J.F.

    1995-07-24

    A process for the capacitive deionization (CDI) of water with a stack of carbon aerogel electrodes has been developed by Lawrence Livermore National Laboratory. Unlike ion exchange, one of the more conventional deionization processes, no chemicals are required for regeneration of the system. Electricity is used instead. Water with various anions and cations is pumped through the electrochemical cell. After polarization, ions are electrostatically removed from the water and held in the electric double layers formed at the surfaces of electrodes. The water leaving the cell is purified, as desired. The effects of cell voltage on the electrosorption capacities for Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4}, and Na{sub 2}CO{sub 3} have been investigated and are reported here. Results for NaCl and NaNO{sub 3} have been reported previously. Possible applications for CDI are as a replacement for ion exchange processes which remove heavy metals and radioisotopes from process and waste water in various industries, as well as to remove inorganic ions from feedwater for fossil and nuclear power plants.

  8. Using multivariate analyses to compare subsets of electrodes and potentials

    Office of Scientific and Technical Information (OSTI)

    within an electrode array for predicting sugar concentrations in mixed solutions. (Journal Article) | SciTech Connect Journal Article: Using multivariate analyses to compare subsets of electrodes and potentials within an electrode array for predicting sugar concentrations in mixed solutions. Citation Details In-Document Search Title: Using multivariate analyses to compare subsets of electrodes and potentials within an electrode array for predicting sugar concentrations in mixed solutions. A

  9. Wet/dry cooling tower and method

    DOE Patents [OSTI]

    Glicksman, Leon R.; Rohsenow, Warren R.

    1981-01-01

    A wet/dry cooling tower wherein a liquid to-be-cooled is flowed along channels of a corrugated open surface or the like, which surface is swept by cooling air. The amount of the surface covered by the liquid is kept small compared to the dry part thereof so that said dry part acts as a fin for the wet part for heat dissipation.

  10. DRI Research Parks Ltd | Open Energy Information

    Open Energy Info (EERE)

    Research Parks Ltd Jump to: navigation, search Name: DRI Research Parks Ltd Place: United States Sector: Services Product: General Financial & Legal Services ( Academic Research...

  11. ,"New Mexico Dry Natural Gas Proved Reserves"

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Dry Natural Gas Proved Reserves",10,"Annual",2014,"06301977" ,"Release Date:","11...

  12. Cold vacuum drying system conceptual design report

    SciTech Connect (OSTI)

    Bradshaw, F.W.

    1996-05-01

    This document summarizes the activities involved in the removal of the SNF from the leaking basins and to place it in stable dry storage.

  13. Inert electrode composition having agent for controlling oxide growth on electrode made therefrom

    DOE Patents [OSTI]

    Ray, S.P.

    1986-04-15

    An improved inert electrode composition is suitable for use as an inert electrode in the production of metals such as aluminum by the electrolytic reduction of metal oxide or metal salt dissolved in a molten salt bath. The composition comprises one or more metal alloys and metal compounds which may include oxides of the metals comprising the alloy. The alloy and metal compounds are interwoven in a network which provides improved electrical conductivity and mechanical strength while preserving the level of chemical inertness necessary for such an electrode to function satisfactorily. The electrode composition further includes a metal compound dopant which will aid in controlling the thickness of a protective oxide layer on at least the bottom portion of an electrode made therefrom during use. 12 figs.

  14. Inert electrode composition having agent for controlling oxide growth on electrode made therefrom

    DOE Patents [OSTI]

    Ray, Siba P.

    1986-01-01

    An improved inert electrode composition is suitable for use as an inert electrode in the production of metals such as aluminum by the electrolytic reduction of metal oxide or metal salt dissolved in a molten salt bath. The composition comprises one or more metal alloys and metal compounds which may include oxides of the metals comprising the alloy. The alloy and metal compounds are interwoven in a network which provides improved electrical conductivity and mechanical strength while preserving the level of chemical inertness necessary for such an electrode to function satisfactorily. The electrode composition further includes a metal compound dopant which will aid in controlling the thickness of a protective oxide layer on at least the bottom portion of an electrode made therefrom during use.

  15. Post-test evaluation of the oxygen electrode from a solid oxide electrolysis stack and electrode materials development.

    SciTech Connect (OSTI)

    Mawdsley, J. R.; Carter, J. D.; Yildiz, B.; Call, A. V.; Kropf, A. J.; Ferrandon, M. S.; Myers, D. J.; Maroni, V. A.

    2009-05-01

    The conclusions of this paper are: (1) stack degradation analysis - significant sources of degradation have been identified, (a) oxygen electrode delamination off the electrolyte and (b) chromium contamination of the oxygen electrode and bond layer; (2) electrode materials development - improved electrode materials have been demonstrated, Pr{sub 2}NiO{sub 4} oxygen electrodes show state-of-the-art performance without optimization of fabrication parameters.

  16. Determination of hexabromocyclododecane in waste waters with a bromide-selective electrode

    SciTech Connect (OSTI)

    Paama, L.A.; Kokk, K.Y.

    1985-11-01

    This paper presents a method for the determination of microquantities of hexabromocyclodecane (HBCD), an antipyrene for the reduction of the flammability of frothing polystyrene in industrial waste waters. The method is based on the extraction of HBCD from waste waters with chloroform, evaporation of the chloroform from the extracts in a stream of air, mineralization of the dry residues, and determination of the bromide ions with a bromine-selective electrode. One of the simpler approaches is given as based on alkaline hydrolysis with dimethyl formamide or in the presence of metallic cadmium. The dry residues after evaporation of the chloroform were decomposed by boiling in a KOH solution in the presence of metallic zinc.

  17. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  18. Effect of electrode manufacturing defects on electrochemical performance of lithium-ion batteries: Cognizance of the battery failure sources

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohanty, D.; Hockaday, E.; Li, J.; Hensley, D. K.; Daniel, C.; Wood, D. L.

    2016-02-21

    During LIB electrode manufacturing, it is difficult to avoid the certain defects that diminish LIB performance and shorten the life span of the batteries. This study provides a systematic investigation correlating the different plausible defects (agglomeration/blisters, pinholes/divots, metal particle contamination, and non-uniform coating) in a LiNi0.5Mn0.3Co0.2O2 positive electrode with its electrochemical performance. Additionally, an infrared thermography technique was demonstrated as a nondestructive tool to detect these defects. The findings show that cathode agglomerates aggravated cycle efficiency, and resulted in faster capacity fading at high current density. Electrode pinholes showed substantially lower discharge capacities at higher current densities than baseline NMCmore » 532 electrodes. Metal particle contaminants have an extremely negative effect on performance, at higher C-rates. The electrodes with more coated and uncoated interfaces (non-uniform coatings) showed poor cycle life compared with electrodes with fewer coated and uncoated interfaces. Further, microstructural investigation provided evidence of presence of carbon-rich region in the agglomerated region and uneven electrode coating thickness in the coated and uncoated interfacial regions that may lead to the inferior electrochemical performance. In conclusion, this study provides the importance of monitoring and early detection of the electrode defects during LIB manufacturing processes to minimize the cell rejection rate after fabrication and testing.« less

  19. Effect of electrode manufacturing defects on electrochemical performance of lithium-ion batteries: Cognizance of the battery failure sources

    SciTech Connect (OSTI)

    Mohanty, D.; Hockaday, E.; Li, J.; Hensley, D. K.; Daniel, C.; Wood, D. L.

    2016-01-01

    During LIB electrode manufacturing, it is difficult to avoid the certain defects that diminish LIB performance and shorten the life span of the batteries. This study provides a systematic investigation correlating the different plausible defects (agglomeration/blisters, pinholes/divots, metal particle contamination, and non-uniform coating) in a LiNi0.5Mn0.3Co0.2O2 positive electrode with its electrochemical performance. Additionally, an infrared thermography technique was demonstrated as a nondestructive tool to detect these defects. The findings show that cathode agglomerates aggravated cycle efficiency, and resulted in faster capacity fading at high current density. Electrode pinholes showed substantially lower discharge capacities at higher current densities than baseline NMC 532 electrodes. Metal particle contaminants have an extremely negative effect on performance, at higher C-rates. The electrodes with more coated and uncoated interfaces (non-uniform coatings) showed poor cycle life compared with electrodes with fewer coated and uncoated interfaces. Further, microstructural investigation provided evidence of presence of carbon-rich region in the agglomerated region and uneven electrode coating thickness in the coated and uncoated interfacial regions that may lead to the inferior electrochemical performance. In conclusion, this study provides the importance of monitoring and early detection of the electrode defects during LIB manufacturing processes to minimize the cell rejection rate after fabrication and testing.

  20. Solution-processable glass LiI-Li4SnS4 superionic conductors for all-solid-state Li-ion batteries

    SciTech Connect (OSTI)

    Kern Ho Park; Oh, Dae Yang; Choi, Young Eun; Nam, Young Jin; Han, Lili; Kim, Ju -Young; Xin, Huolin; Lin, Feng; Oh, Seung M.; Jung, Yoon Seok

    2015-12-22

    The new, highly conductive (4.1 × 10–4 S cm–1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li4SnS4 is prepared using a homogeneous methanol solution. Furthermore, the solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li4SnS4), resulting in considerable improvements in electrochemical performances of these electrodes over conventional mixture electrodes.

  1. Manganese oxide composite electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Li, Naichao (Croton on Hudson, NY)

    2007-12-04

    An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor of a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0electrode is activated by removing lithia, or lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

  2. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, F.A.; Townsend, C.W.

    1989-09-12

    An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

  3. Layered electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Johnson, Christopher S.; Thackeray, Michael M.; Vaughey, John T.; Kahaian, Arthur J.; Kim, Jeom-Soo

    2008-04-15

    Lithium metal oxide compounds of nominal formula Li.sub.2MO.sub.2, in which M represents two or more positively charged metal ions, selected predominantly and preferably from the first row of transition metals are disclosed herein. The Li.sub.2MO.sub.2 compounds have a layered-type structure, which can be used as positive electrodes for lithium electrochemical cells, or as a precursor for the in-situ electrochemical fabrication of LiMO.sub.2 electrodes. The Li.sub.2MO.sub.2 compounds of the invention may have additional functions in lithium cells, for example, as end-of-discharge indicators, or as negative electrodes for lithium cells.

  4. Electrochemical cell having cylindrical electrode elements

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Shimotake, Hiroshi (Hinsdale, IL)

    1982-01-01

    A secondary, high temperature electrochemical cell especially adapted for lithium alloy negative electrodes, transition metal chalcogenide positive electrodes and alkali metal halide or alkaline earth metal halide electrolyte is disclosed. The cell is held within an elongated cylindrical container in which one of the active materials is filled around the outside surfaces of a plurality of perforate tubular current collectors along the length of the container. Each of the current collector tubes contain a concentric tubular layer of electrically insulative ceramic as an interelectrode separator. The active material of opposite polarity in elongated pin shape is positioned longitudinally within the separator layer. A second electrically conductive tube with perforate walls can be swagged or otherwise bonded to the outer surface of the pin as a current collector and the electrically insulative ceramic layer can be coated or otherwise layered onto the outer surface of this second current collector. Alternatively, the central pin electrode can include an axial core as a current collector.

  5. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S.

    2008-01-01

    An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

  6. Fuel cell electrode and method of preparation

    DOE Patents [OSTI]

    Kaun, T.D

    1984-03-02

    A fuel cell having good resistance to compressive creep includes electrodes having a superstructure of porous electrically conductive foam with surface sections adjacent to opposing surfaces of an electrolyte matrix impregnated with electrode catalyst materials. The catalyst materials are affixed in sections contiguous to an inner major surface by sinter bonding, electrochemical bonding or restrictive interstitial spacing. The outer sections of the porous plaque thickness are reserved for gas distribution to the electrode catalyst. Oxidant and fuel gases can be separately manifolded into alternate sides of a fuel cell stack by sealing opposing edges of the porous plaques containing the anode material in one set of opposing side surfaces and sealing opposing edges of the porous plaque containing cathode material in alternate side surfaces of the stack.

  7. Method for control of edge effects of oxidant electrode

    DOE Patents [OSTI]

    Carr, Peter; Chi, Chen H.

    1980-12-23

    Described is an electrode assembly comprising; a. a porous electrode having a first and second exterior face with a cavity formed in the interior between said exterior faces thereby having first and second interior faces positioned opposite the first and second exterior faces; b. a counter electrode positioned facing each of the first and second exterior faces of the porous electrode; c. means for passing an oxidant through said porous electrode; and d. screening means for blocking the interior face of the porous electrode a greater amount than the blocking of the respective exterior face of the porous electrode, thereby maintaining a differential of oxidant electrode surface between the interior face and the exterior face. The electrode assembly is useful in a metal, halogen, halogen hydrate electrical energy storage device.

  8. Energy analysis on use of air and superheated steam as drying media

    SciTech Connect (OSTI)

    Tarnawski, W.Z.; Mitera, J.; Borowski, P.; Klepaczka, A. [Technical Univ. of Lodz (Poland). Inst. of Papermaking and Paper Machines

    1996-10-01

    The physical properties of air and superheated steam were analyzed in a range of temperatures applied in paper and paperboard drying processes. On the basis of tests carried out on a pilot stand the values of energy indices for air and steam drying processes are compared. With the drying media temperature as T{sub M} = 300 C, nozzle velocity {nu} = 60 m/s and using the Huang and Mujumdar model as well as relationships given by Chance a comparative analysis of the results has been carried out. Variation of several indices in the range of temperatures 100--600 C and various nozzle velocities was studied.

  9. System of fabricating a flexible electrode array

    DOE Patents [OSTI]

    Krulevitch, Peter; Polla, Dennis L.; Maghribi, Mariam N.; Hamilton, Julie; Humayun, Mark S.; Weiland, James D.

    2010-10-12

    An image is captured or otherwise converted into a signal in an artificial vision system. The signal is transmitted to the retina utilizing an implant. The implant consists of a polymer substrate made of a compliant material such as poly(dimethylsiloxane) or PDMS. The polymer substrate is conformable to the shape of the retina. Electrodes and conductive leads are embedded in the polymer substrate. The conductive leads and the electrodes transmit the signal representing the image to the cells in the retina. The signal representing the image stimulates cells in the retina.

  10. System of fabricating a flexible electrode array

    DOE Patents [OSTI]

    Krulevitch, Peter; Polla, Dennis L.; Maghribi, Mariam N.; Hamilton, Julie; Humayun, Mark S.; Weiland, James D.

    2012-01-28

    An image is captured or otherwise converted into a signal in an artificial vision system. The signal is transmitted to the retina utilizing an implant. The implant consists of a polymer substrate made of a compliant material such as poly(dimethylsiloxane) or PDMS. The polymer substrate is conformable to the shape of the retina. Electrodes and conductive leads are embedded in the polymer substrate. The conductive leads and the electrodes transmit the signal representing the image to the cells in the retina. The signal representing the image stimulates cells in the retina.

  11. Flexible electrode array for artifical vision

    DOE Patents [OSTI]

    Krulevitch, Peter; Polla, Dennis L.; Maghribi, Mariam N.; Hamilton, Julie

    2006-12-05

    An image is captured or otherwise converted into a signal in an artificial vision system. The signal is transmitted to the retina utilizing an implant. The implant consists of a polymer substrate made of a compliant material such as poly(dimethylsiloxane) or PDMS. The polymer substrate is conformable to the shape of the retina. Electrodes and conductive leads are embedded in the polymer substrate. The conductive leads and the electrodes transmit the signal representing the image to the cells in the retina. The signal representing the image stimulates cells in the retina.

  12. Method of manufacturing positive nickel hydroxide electrodes

    DOE Patents [OSTI]

    Gutjahr, M.A.; Schmid, R.; Beccu, K.D.

    1975-12-16

    A method of manufacturing a positive nickel hydroxide electrode is discussed. A highly porous core structure of organic material having a fibrous or reticular texture is uniformly coated with nickel powder and then subjected to a thermal treatment which provides sintering of the powder coating and removal of the organic core material. A consolidated, porous nickel support structure is thus produced which has substantially the same texture and porosity as the initial core structure. To provide the positive electrode including the active mass, nickel hydroxide is deposited in the pores of the nickel support structure.

  13. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  14. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  15. Recent progress of spray drying in China

    SciTech Connect (OSTI)

    Jinxin, T.; Zonglian, W.; Lixin, H.

    1999-10-01

    The development of spray drying technique during past 10 years of China is reviewed. Main achievements in research, development and utilization of three types of atomization are described and summarized. General trend of spray drying research and development in 21st century is forecasted.

  16. Cold vacuum drying facility 90% design review

    SciTech Connect (OSTI)

    O`Neill, C.T.

    1997-05-02

    This document contains review comment records for the CVDF 90% design review. Spent fuels retrieved from the K Basins will be dried at the CVDF. It has also been recommended that the Multi-Conister Overpacks be welded, inspected, and repaired at the CVD Facility before transport to dry storage.

  17. Dry phase reactor for generating medical isotopes

    DOE Patents [OSTI]

    Mackie, Thomas Rockwell; Heltemes, Thad Alexander

    2016-05-03

    An apparatus for generating medical isotopes provides for the irradiation of dry-phase, granular uranium compounds which are then dissolved in a solvent for separation of the medical isotope from the irradiated compound. Once the medical isotope is removed, the dissolved compound may be reconstituted in dry granular form for repeated irradiation.

  18. Nanopowder molding method for creating implantable high-aspect-ratio electrodes on thin flexible substrates

    SciTech Connect (OSTI)

    Hu, Zhiyu [ORNL; Thundat, Thomas George [ORNL

    2006-03-01

    Metal nanoparticles and a nanopowder molding process were used to fabricate 2D and 3D patternable structures having a height-to-width ratio of up to 10:1. By means of this process, an entire neural stimulation circuit, including stimulating electrode, connection trace, and contact pad, can be fused into one continuous, integrated structure where different sections can have different heights, widths, and shapes. The technique is suitable for mass production, and the fabricated electrode is robust and very flexible. More importantly for biomedical applications, the entire fabricated structure can be packed at room temperature onto a biocompatible flexible substrate, such as polydimethylsiloxane, parylene, and polyimide as well as other temperature-sensitive or vacuum-sensitive materials. The electrodes and wires have about the same electrical resistivities as bulk materials and desirable electrochemical properties, including low impedance.

  19. Porous electrode apparatus for electrodeposition of detailed metal structures or microelectronic interconnections

    DOE Patents [OSTI]

    Griffiths, Stewart K.; Nilson, Robert H.; Hruby, Jill M.

    2002-01-01

    An apparatus and procedure for performing microfabrication of detailed metal structures by electroforming metal deposits within small cavities. Two primary areas of application are: the LIGA process which manufactures complex three-dimensional metal parts and the damascene process used for electroplating line and via interconnections of microelectronic devices. A porous electrode held in contact or in close proximity with a plating substrate or mold top to ensure one-dimensional and uniform current flow into all mold cavities is used. Electrolyte is pumped over the exposed surface of the porous electrode to ensure uniform ion concentrations at this external surface. The porous electrode prevents electrolyte circulation within individual mold cavities, avoiding preferential enhancement of ion transport in cavities having favorable geometries. Both current flow and ion transport are one-dimensional and identical in all mold cavities, so all metal deposits grow at the same rate eliminating nonuniformities of the prior art.

  20. Method of preparation of carbon materials for use as electrodes in rechargeable batteries

    DOE Patents [OSTI]

    Doddapaneni, N.; Wang, J.C.F.; Crocker, R.W.; Ingersoll, D.; Firsich, D.W.

    1999-03-16

    A method is described for producing carbon materials for use as electrodes in rechargeable batteries. Electrodes prepared from these carbon materials exhibit intercalation efficiencies of {approx_equal} 80% for lithium, low irreversible loss of lithium, long cycle life, are capable of sustaining a high rates of discharge and are cheap and easy to manufacture. The method comprises a novel two-step stabilization process in which polymeric precursor materials are stabilized by first heating in an inert atmosphere and subsequently heating in air. During the stabilization process, the polymeric precursor material can be agitated to reduce particle fusion and promote mass transfer of oxygen and water vapor. The stabilized, polymeric precursor materials can then be converted to a synthetic carbon, suitable for fabricating electrodes for use in rechargeable batteries, by heating to a high temperature in a flowing inert atmosphere. 4 figs.

  1. Method of preparation of carbon materials for use as electrodes in rechargeable batteries

    DOE Patents [OSTI]

    Doddapaneni, Narayan; Wang, James C. F.; Crocker, Robert W.; Ingersoll, David; Firsich, David W.

    1999-01-01

    A method of producing carbon materials for use as electrodes in rechargeable batteries. Electrodes prepared from these carbon materials exhibit intercalation efficiencies of .apprxeq.80% for lithium, low irreversible loss of lithium, long cycle life, are capable of sustaining a high rates of discharge and are cheap and easy to manufacture. The method comprises a novel two-step stabilization process in which polymeric precursor materials are stabilized by first heating in an inert atmosphere and subsequently heating in air. During the stabilization process, the polymeric precursor material can be agitated to reduce particle fusion and promote mass transfer of oxygen and water vapor. The stabilized, polymeric precursor materials can then be converted to a synthetic carbon, suitable for fabricating electrodes for use in rechargeable batteries, by heating to a high temperature in a flowing inert atmosphere.

  2. Evaluation of spray-drying methods for cellulase preservation

    SciTech Connect (OSTI)

    Himmel, M.; Oh, K.; Tucker, M.; Rivard, C.; Grohmann, K.; Scott, C.D.

    1986-01-01

    Spray drying processes are widely used for the large-scale preservation of biology goods. The application of this technology to the enhancement of the storability of cellulase and related enzymes would improve fermentation processes requiring input of specific quantities of enzyme catalyst of known activity. Very high percentages (90% of original) of filter paper and carboxymethyicellulose hydrolyzing activities can be recovered from conventional spray dryers when operated at inlet air temperatures ranging from 90 to 180 degrees. The beta-glucosidase and beta-xylosidase activity recoveries were somewhat lower and were optimal at temperatures ranging from 120 to 150 degrees. However, the individual performance of the 12 enzyme preparations examined was quite preparation specific. An ultrasonic nozzle adaptation to the Yamato dryer demonstrated the overall feasibility of high energy atomization inasmuch as the filter paper activity was retained after drying. The more labile beta-xylosidase activity was, however, entirely lost.

  3. Dry soldering with hot filament produced atomic hydrogen

    DOE Patents [OSTI]

    Panitz, Janda K. G.; Jellison, James L.; Staley, David J.

    1995-01-01

    A system for chemically transforming metal surface oxides to metal that is especially, but not exclusively, suitable for preparing metal surfaces for dry soldering and solder reflow processes. The system employs one or more hot, refractory metal filaments, grids or surfaces to thermally dissociate molecular species in a low pressure of working gas such as a hydrogen-containing gas to produce reactive species in a reactive plasma that can chemically reduce metal oxides and form volatile compounds that are removed in the working gas flow. Dry soldering and solder reflow processes are especially applicable to the manufacture of printed circuit boards, semiconductor chip lead attachment and packaging multichip modules. The system can be retrofitted onto existing metal treatment ovens, furnaces, welding systems and wave soldering system designs.

  4. Dry soldering with hot filament produced atomic hydrogen

    DOE Patents [OSTI]

    Panitz, J.K.G.; Jellison, J.L.; Staley, D.J.

    1995-04-25

    A system is disclosed for chemically transforming metal surface oxides to metal that is especially, but not exclusively, suitable for preparing metal surfaces for dry soldering and solder reflow processes. The system employs one or more hot, refractory metal filaments, grids or surfaces to thermally dissociate molecular species in a low pressure of working gas such as a hydrogen-containing gas to produce reactive species in a reactive plasma that can chemically reduce metal oxides and form volatile compounds that are removed in the working gas flow. Dry soldering and solder reflow processes are especially applicable to the manufacture of printed circuit boards, semiconductor chip lead attachment and packaging multichip modules. The system can be retrofitted onto existing metal treatment ovens, furnaces, welding systems and wave soldering system designs. 1 fig.

  5. Inspection of Used Fuel Dry Storage Casks

    SciTech Connect (OSTI)

    Dennis C. Kunerth; Tim McJunkin; Mark McKay; Sasan Bakhtiari

    2012-09-01

    ABSTRACT The U.S. Nuclear Regulatory Commission (NRC) regulates the storage of used nuclear fuel, which is now and will be increasingly placed in dry storage systems. Since a final disposition pathway is not defined, the fuel is expected to be maintained in dry storage well beyond the time frame originally intended. Due to knowledge gaps regarding the viability of current dry storage systems for long term use, efforts are underway to acquire the technical knowledge and tools required to understand the issues and verify the integrity of the dry storage system components. This report summarizes the initial efforts performed by researchers at Idaho National Laboratory and Argonne National Laboratory to identify and evaluate approaches to in-situ inspection dry storage casks. This task is complicated by the design of the current storage systems that severely restrict access to the casks.

  6. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y.; Merriam, Norman W.; Boysen, John E.

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  7. Optimization of LiFePO4 Nanoparticle Suspensions with Polyethyleneimine for Aqueous Processing

    SciTech Connect (OSTI)

    Li, Jianlin; Armstrong, Beth L; Kiggans, Jim; Daniel, Claus; Wood III, David L

    2012-01-01

    Addition of dispersants to aqueous based lithium-ion battery electrode formulations containing LiFePO{sub 4} is critical to obtaining a stable suspension. The resulting colloidal suspensions enable dramatically improved coating deposition when processing electrodes. This research examines the colloidal chemistry modifications based on polyethyleneimine (PEI) addition and dispersion characterization required to produce high quality electrode formulations and coatings for LiFePO{sub 4} active cathode material. The isoelectric point, a key parameter in characterizing colloidal dispersion stability, of LiFePO{sub 4} and super P C45 were determined to be pH = 4.3 and 3.4, respectively. PEI, a cationic surfactant, was found to be an effective dispersant. It is demonstrated that 1.0 wt % and 0.5 wt % PEI were required to stabilize the LiFePO{sub 4} and super P C45 suspension, respectively. LiFePO{sub 4} cathode suspensions with 1.5 wt % PEI demonstrated the best dispersibility of all components, as evidenced by viscosity and agglomerate size of the suspensions and elemental distribution within dry cathodes. The addition of PEI significantly improved the LiFePO{sub 4} performance.

  8. Titanium nitride electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Novak, Robert F.; Schmatz, Duane J.; Hunt, Thomas K.

    1987-12-22

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film of titanium nitride as an electrode deposited onto solid electrolyte. The invention is also directed to the method of making same.

  9. Negative Electrode For An Alkaline Cell

    DOE Patents [OSTI]

    Coco, Isabelle; Cocciantelli, Jean-Michel; Villenave, Jean-Jacques

    1998-07-14

    The present invention concerns a negative electrode for an alkaline cell, comprising a current collector supporting a paste containing an electrochemically active material and a binder, characterized in that said binder is a polymer containing hydrophilic and hydrophobic groups, said polymer being selected from an acrylic homopolymer, copolymer and terpolymer, an unsaturated organic acid copolymer and an unsaturated acid anhydride copolymer.

  10. Method Of Making An Ultracapacitor Electrode

    DOE Patents [OSTI]

    Wei, Chang; Jerabek, Elihu Calvin; DeJager, Katherine Dana; LeBlanc, Jr., Oliver Harris

    2003-05-06

    A paste of organic solvent with dissolved organic salt and active carbon is formed and a uniform film of the paste is applied onto a substrate by casting the paste into a clearance between a knife blade and the substrate. The paste is evaporated to form a paste electrode for an ultracapacitor.

  11. Method of making an ultracapacitor electrode

    DOE Patents [OSTI]

    Wei, Chang; Jerabek, Elihu Calvin; DeJager, Katherine Dana; LeBlanc, Jr., Oliver Harris

    2001-10-16

    A paste of organic solvent with dissolved organic salt and active carbon is formed and a uniform film of the paste is applied onto a substrate by casting the paste into a clearance between a knife blade and the substrate. The paste is evaporated to form a paste electrode for an ultracapacitor.

  12. Molybdenum oxide electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Schmatz, Duane J. (Dearborn Heights, MI)

    1989-01-01

    The invention is directed to a composite article suitable for use in thermoelectric generators. The article comprises a thin film comprising molybdenum oxide as an electrode deposited by physical deposition techniques onto solid electrolyte. The invention is also directed to the method of making same.

  13. Long life lithium batteries with stabilized electrodes

    DOE Patents [OSTI]

    Amine, Khalil; Liu, Jun; Vissers, Donald R; Lu, Wenquan

    2015-04-21

    The present invention relates to non-aqueous electrolytes having electrode stabilizing additives, stabilized electrodes, and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, and an electrode stabilizing additive. In certain electrolytes, the alkali metal salt is a bis(chelato)borate and the additives include substituted or unsubstituted linear, branched or cyclic hydrocarbons comprising at least one oxygen atom and at least one aryl, alkenyl or alkynyl group. In other electrolytes, the additives include a substituted aryl compound or a substituted or unsubstituted heteroaryl compound wherein the additive comprises at least one oxygen atom. There are also provided methods of making the electrolytes and batteries employing the electrolytes. The invention also provides for electrode materials. Cathodes of the present invention may be further stabilized by surface coating the particles of the spinel or olivine with a material that can neutralize acid or otherwise lessen or prevent leaching of the manganese or iron ions. In some embodiments the coating is polymeric and in other embodiments the coating is a metal oxide such as ZrO.sub.2, TiO.sub.2, ZnO, WO.sub.3, Al.sub.2O.sub.3, MgO, SiO.sub.2, SnO.sub.2 AlPO.sub.4, Al(OH).sub.3, a mixture of any two or more thereof.

  14. Acoustically enhanced heat exchange and drying apparatus

    DOE Patents [OSTI]

    Bramlette, T.T.; Keller, J.O.

    1987-07-10

    A heat transfer drying apparatus includes an acoustically augmented heat transfer chamber for receiving material to be dried. The chamber includes a first heat transfer gas inlet, a second heat transfer gas inlet, a material inlet, and a gas outlet which also serves as a dried material and gas outlet. A non-pulsing first heat transfer gas source provides a first drying gas to the acoustically augmented heat transfer chamber through the first heat transfer gas inlet. A valveless, continuous second heat transfer gas source provides a second drying gas to the acoustically augmented heat transfer chamber through the second heat transfer gas inlet. The second drying gas also generates acoustic waves which bring about acoustical coupling with the gases in the acoustically augmented heat transfer chamber. The second drying gas itself oscillates at an acoustic frequency of approximately 180 Hz due to fluid mechanical motion in the gas. The oscillations of the second heat transfer gas coupled to the first heat transfer gas in the acoustically augmented heat transfer chamber enhance heat and mass transfer by convection within the chamber. 3 figs.

  15. Advanced Flow Battery Electrodes: Low-cost, High-Performance 50-Year Electrode

    SciTech Connect (OSTI)

    2010-09-01

    GRIDS Project: Primus Power is developing zinc-based, rechargeable liquid flow batteries that could produce substantially more energy at lower cost than conventional batteries. A flow battery is similar to a conventional battery, except instead of storing its energy inside the cell it stores that energy for future use in chemicals that are kept in tanks that sit outside the cell. One of the most costly components in a flow battery is the electrode, where the electrochemical reactions actually occur. Primus Power is investigating and developing mixed-metal materials for their electrodes that could ultimately reduce the lifetime cost of flow batteries because they are more durable and long-lasting than electrodes found in traditional batteries. Using these electrodes, Primus Power’s flow batteries can be grouped together into robust, containerized storage pods for use by utilities, renewable energy developers, businesses, and campuses.

  16. Vehicle Technologies Office Merit Review 2014: Electrode Architecture-Assembly of Battery Materials and Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Hydro-Québec at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode architecture-assembly...

  17. Vehicle Technologies Office Merit Review 2015: Electrode Architecture-Assembly of Battery Materials and Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Hydro Quebec at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode architecture-assembly...

  18. Electrode and method of interconnection sintering on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Ruka, Roswell J.; Kuo, Lewis J. H.

    1994-01-01

    An electrode structure (10) is made by applying a base layer of doped LaCrO.sub.3 particles on a portion of an electrode (16) and then coating the particles with a top layer composition such as CaO+Al.sub.2 O.sub.3, SrO+Al.sub.2 O.sub.3, or BaO+Al.sub.2 O.sub.3, and then heating the composition for a time effective to melt the composition and allow it to fill any open porosity in the base layer of doped LaCrO.sub.3 to form an interconnection (26), after which solid oxide electrolyte (18) can be applied to the remaining portion of the electrode (16) and the electrolyte (18) can be covered with a cermet exterior electrode (20).

  19. Electrode and method of interconnection sintering on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Ruka, R.J.; Kuo, L.J.H.

    1994-01-11

    An electrode structure is made by applying a base layer of doped LaCrO[sub 3] particles on a portion of an electrode and then coating the particles with a top layer composition such as CaO+Al[sub 2]O[sub 3], SrO+Al[sub 2]O[sub 3], or BaO+Al[sub 2]O[sub 3], and then heating the composition for a time effective to melt the composition and allow it to fill any open porosity in the base layer of doped LaCrO[sub 3] to form an interconnection, after which solid oxide electrolyte can be applied to the remaining portion of the electrode and the electrolyte can be covered with a cermet exterior electrode. 2 figures.

  20. Electro-optic device with gap-coupled electrode

    DOE Patents [OSTI]

    Deri, Robert J.; Rhodes, Mark A.; Bayramian, Andrew J.; Caird, John A.; Henesian, Mark A.; Ebbers, Christopher A.

    2013-08-20

    An electro-optic device includes an electro-optic crystal having a predetermined thickness, a first face and a second face. The electro-optic device also includes a first electrode substrate disposed opposing the first face. The first electrode substrate includes a first substrate material having a first thickness and a first electrode coating coupled to the first substrate material. The electro-optic device further includes a second electrode substrate disposed opposing the second face. The second electrode substrate includes a second substrate material having a second thickness and a second electrode coating coupled to the second substrate material. The electro-optic device additionally includes a voltage source electrically coupled to the first electrode coating and the second electrode coating.

  1. NO.sub.x sensing devices having conductive oxide electrodes

    DOE Patents [OSTI]

    Montgomery, Frederick C.; West, David L.; Armstrong, Timothy R.; Maxey, Lonnie C.

    2010-03-16

    A NO.sub.x sensing device includes at least one pair of spaced electrodes, at least one of which is made of a conductive oxide, and an oxygen-ion conducting material in bridging electrical communication with the electrodes.

  2. Lithium metal oxide electrodes for lithium cells and batteries...

    Office of Scientific and Technical Information (OSTI)

    Title: Lithium metal oxide electrodes for lithium cells and batteries A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in ...

  3. Improved zinc electrode and rechargeable zinc-air battery

    DOE Patents [OSTI]

    Ross, P.N. Jr.

    1988-06-21

    The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

  4. Electronically and ionically conducting electrodes for thermoelectric generators

    DOE Patents [OSTI]

    Novak, Robert F.; Weber, Neill

    1987-01-01

    A composite article comprising a porous cermet electrode on a dense solid electrolyte and method of making same. The cerment electrode comprises beta-type-alumina and refractory metal.

  5. Graphene-based battery electrodes having continuous flow paths...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-based battery electrodes having continuous flow paths Some batteries can ... Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show ...

  6. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph; Dispennette, John M.; Blank, Edward; Kolb, Alan C.

    1999-05-25

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  7. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.; Blank, E.; Kolb, A.C.

    1999-01-19

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH{sub 3}CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals. 32 figs.

  8. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. Joseph; Dispennette, John M.; Blank, Edward; Kolb, Alan C.

    1999-01-19

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH.sub.3 CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals.

  9. Multi-electrode double layer capacitor having single electrolyte seal and aluminum-impregnated carbon cloth electrodes

    DOE Patents [OSTI]

    Farahmandi, C. J.; Dispennette, J. M.; Blank, E.; Kolb, A. C.

    1999-05-25

    A single cell, multi-electrode high performance double layer capacitor includes first and second flat stacks of electrodes adapted to be housed in a closeable two-part capacitor case which includes only a single electrolyte seal. Each electrode stack has a plurality of electrodes connected in parallel, with the electrodes of one stack being interleaved with the electrodes of the other stack to form an interleaved stack, and with the electrodes of each stack being electrically connected to respective capacitor terminals. A porous separator sleeve is inserted over the electrodes of one stack before interleaving to prevent electrical shorts between the electrodes. The electrodes are made by folding a compressible, low resistance, aluminum-impregnated carbon cloth, made from activated carbon fibers, around a current collector foil, with a tab of the foils of each electrode of each stack being connected in parallel and connected to the respective capacitor terminal. The height of the interleaved stack is somewhat greater than the inside height of the closed capacitor case, thereby requiring compression of the interleaved electrode stack when placed inside of the case, and thereby maintaining the interleaved electrode stack under modest constant pressure. The closed capacitor case is filled with an electrolytic solution and sealed. A preferred electrolytic solution is made by dissolving an appropriate salt into acetonitrile (CH[sub 3]CN). In one embodiment, the two parts of the capacitor case are conductive and function as the capacitor terminals. 32 figs.

  10. Airless drying -- Developments since IDS'94

    SciTech Connect (OSTI)

    Stubbing, T.J.

    1999-09-01

    Since its introduction to IDS'94 delegates, significant progress has been made with the development of airless drying technology. The ceramic industry internationally is beginning to benefit from both the energy use and drying time reductions it achieves, while on the basis of further theoretical work carried out since 1993 other industries, including the bioenergy sector, should also soon begin to exploit its advantages. As global warming becomes a reality and oil reserves decline, superheated steam drying and gasification of biomass will contribute to the mitigation of those problems.

  11. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    SciTech Connect (OSTI)

    Mehta, Apurva; Stanford Synchrotron Radiation Lightsource; Doeff, Marca M.; Chen, Guoying; Cabana, Jordi; Richardson, Thomas J.; Mehta, Apurva; Shirpour, Mona; Duncan, Hugues; Kim, Chunjoong; Kam, Kinson C.; Conry, Thomas

    2013-04-30

    We describe the use of synchrotron X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) techniques to probe details of intercalation/deintercalation processes in electrode materials for Li ion and Na ion batteries. Both in situ and ex situ experiments are used to understand structural behavior relevant to the operation of devices.

  12. Graphene-based battery electrodes having continuous flow paths (Patent) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect based battery electrodes having continuous flow paths Citation Details In-Document Search Title: Graphene-based battery electrodes having continuous flow paths Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases.

  13. Liquid and gel electrodes for transverse free flow electrophoresis (Patent)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Liquid and gel electrodes for transverse free flow electrophoresis Citation Details In-Document Search Title: Liquid and gel electrodes for transverse free flow electrophoresis The present invention provides a mechanism for separating or isolating charged particles under the influence of an electric field without metal electrodes being in direct contact with the sample solution. The metal electrodes normally in contact with the sample are replaced with high conductivity

  14. MHD generator with improved network coupling electrodes to a load

    DOE Patents [OSTI]

    Rosa, Richard J.

    1977-01-01

    An MHD generator has a plurality of segmented electrodes extending longitudinally of a duct, whereby progressively increasing high DC voltages are derived from a set of cathode electrodes and progressively increasing low DC voltages are derived from a set of anode electrodes. First and second load terminals are respectively connected to the cathode and anode electrodes by separate coupling networks, each of which includes a number of SCR's and a number of diode rectifiers.

  15. Perovskite electrodes and method of making the same

    DOE Patents [OSTI]

    Seabaugh, Matthew M.; Swartz, Scott L.

    2005-09-20

    The invention relates to perovskite oxide electrode materials in which one or more of the elements Mg, Ni, Cu, and Zn are present as minority components that enhance electrochemical performance, as well as electrode products with these compositions and methods of making the electrode materials. Such electrodes are useful in electrochemical system applications such as solid oxide fuel cells, ceramic oxygen generation systems, gas sensors, ceramic membrane reactors, and ceramic electrochemical gas separation systems.

  16. Perovskite electrodes and method of making the same

    DOE Patents [OSTI]

    Seabaugh, Matthew M.; Swartz, Scott L.

    2009-09-22

    The invention relates to perovskite oxide electrode materials in which one or more of the elements Mg, Ni, Cu, and Zn are present as minority components that enhance electrochemical performance, as well as electrode products with these compositions and methods of making the electrode materials. Such electrodes are useful in electrochemical system applications such as solid oxide fuel cells, ceramic oxygen generation systems, gas sensors, ceramic membrane reactors, and ceramic electrochemical gas separation systems.

  17. Using multivariate analyses to compare subsets of electrodes...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 09 BIOMASS FUELS; ELECTRODES; FRUCTOSE; GALACTOSE; GLUCOSE; SACCHAROSE; CONCENTRATION RATIO; ELECTROCHEMICAL CELLS; PERFORMANCE; MIXTURES; ELECTRIC POTENTIAL; MULTIVARIATE ...

  18. Method for uniformly distributing carbon flakes in a positive electrode, the electrode made thereby and compositions

    DOE Patents [OSTI]

    Mrazek, Franklin C.; Smaga, John A.; Battles, James E.

    1983-01-01

    A positive electrode for a secondary electrochemical cell wherein an electrically conductive current collector is in electrical contact with a particulate mixture of gray cast iron and an alkali metal sulfide and an electrolyte including alkali metal halides or alkaline earth metal halides. Also present may be a transition metal sulfide and graphite flakes from the conversion of gray cast iron to iron sulfide. Also disclosed is a method of distributing carbon flakes in a cell wherein there is formed an electrochemical cell of a positive electrode structure of the type described and a suitable electrolyte and a second electrode containing a material capable of alloying with alkali metal ions. The cell is connected to a source of electrical potential to electrochemically convert gray cast iron to an iron sulfide and uniformly to distribute carbon flakes formerly in the gray cast iron throughout the positive electrode while forming an alkali metal alloy in the negative electrode. Also disclosed are compositions useful in preparing positive electrodes.

  19. The use of capacitive deionization with carbon aerogel electrodes to remove inorganic contaminants from water

    SciTech Connect (OSTI)

    Farmer, J.C.; Fix, D.V.; Mack, G.V.; Pekala, R.W.; Poco, J.F.

    1995-02-17

    The capacitive deionization of water with a stack of carbon aerogel electrodes has been successfully demonstrated for the first time. Unlike ion exchange, one of the more conventional deionization processes, no chemicals were required for regeneration of the system. Electricity was used instead. Water with various anions and cations was pumped through the electrochemical cell. After polarization, ions were electrostatically removed from the water and held in the electric double layers formed at electrode surfaces. The water leaving the cell was purified, as desired.

  20. Supercapacitors Based on Metal Electrodes Prepared from Nanoparticle Mixtures at Room Temperature

    SciTech Connect (OSTI)

    Nakanishi, Hideyuki; Grzybowski, Bartosz A.

    2010-01-01

    Films comprising Au and Ag nanoparticles are transformed into porous metal electrodes by desorption of weak organic ligands followed by wet chemical etching of silver. Thus prepared electrodes provide the basis for supercapacitors whose specific capacitances approach 70 F/g. Cyclic voltammetry measurement yield rectangular I-V curves even at high scan rates, indicating that the supercapacitors have low internal resistance. Owing to this property, the supercapacitors have a high power density ~12 kW/kg, comparable with that of the state-of-the-art carbon-based devices. The entire assembly protocol does not require high-temperature processing or the use of organic binders.

  1. High power and high energy electrodes using carbon nanotubes

    DOE Patents [OSTI]

    Martini, Fabrizio; Brambilla, Nicolo Michele; Signorelli, Riccardo

    2015-04-07

    An electrode useful in an energy storage system, such as a capacitor, includes an electrode that includes at least one to a plurality of layers of compressed carbon nanotube aggregate. Methods of fabrication are provided. The resulting electrode exhibits superior electrical performance in terms of gravimetric and volumetric power density.

  2. Method of making an air electrode material having controlled sinterability

    DOE Patents [OSTI]

    Vasilow, T.R.; Kuo, L.J.H.; Ruka, R.J.

    1994-08-30

    A tubular, porous ceramic electrode structure is made from the sintered admixture of doped lanthanum manganite and an additive containing cerium where a solid electrolyte, substantially surrounds the air electrode, and a porous outer fuel electrode substantially surrounds the electrolyte, to form a fuel cell. 2 figs.

  3. Negative Electrodes Improve Safety in Lithium Cells and Batteries | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Negative Electrodes Improve Safety in Lithium Cells and Batteries Technology available for licensing: Enhanced stability at a lower cost Lowers cost for enhanced stability capability. A new class of intermetallic material for the negative electrode that offers a significantly higher volumetric and gravimetric capacity and improves battery stability and safety. PDF icon negative_electrodes

  4. Electrically conductive polycrystalline diamond and particulate metal based electrodes

    DOE Patents [OSTI]

    Swain, Greg M.; Wang, Jian

    2005-04-26

    An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

  5. Screening of Electrode Materials & Cell Chemistries and Streamlining

    Broader source: Energy.gov (indexed) [DOE]

    Optimization of Electrodes | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es028_lu_2012_o.pdf More Documents & Publications Cell Fabrication Facility Team Production and Research Activities Screening of Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrodes Validation of

  6. Oxide modified air electrode surface for high temperature electrochemical cells

    DOE Patents [OSTI]

    Singh, Prabhakar; Ruka, Roswell J.

    1992-01-01

    An electrochemical cell is made having a porous cermet electrode (16) and a porous lanthanum manganite electrode (14), with solid oxide electrolyte (15) between them, where the lanthanum manganite surface next to the electrolyte contains a thin discontinuous layer of high surface area cerium oxide and/or praseodymium oxide, preferably as discrete particles (30) in contact with the air electrode and electrolyte.

  7. Method of making an air electrode material having controlled sinterability

    DOE Patents [OSTI]

    Vasilow, Theodore R.; Kuo, Lewis J. H.; Ruka, Roswell J.

    1994-01-01

    A tubular, porous ceramic electrode structure (3) is made from the sintered admixture of doped lanthanum manganite and an additive containing cerium where a solid electrolyte (4), substantially surrounds the air electrode, and a porous outer fuel electrode (7) substantially surrounds the electrolyte, to form a fuel cell (1).

  8. First Principles Calculations and NMR Spectroscopy of Electrode Materials |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 7_grey.pdf More Documents & Publications First Principles Calculations and NMR Spectroscopy of Electrode Materials: NMR Vehicle Technologies Office Merit Review 2014: First Principles Calculations and NMR Spectroscopy of Electrode Materials First Principles Calculations and NMR Spectroscopy of Electrode Materials

  9. High strength air-dried aerogels

    DOE Patents [OSTI]

    Coronado, Paul R.; Satcher, Jr., Joe H.

    2012-11-06

    A method for the preparation of high strength air-dried organic aerogels. The method involves the sol-gel polymerization of organic gel precursors, such as resorcinol with formaldehyde (RF) in aqueous solvents with R/C ratios greater than about 1000 and R/F ratios less than about 1:2.1. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be air dried at ambient temperatures and pressures. The method significantly reduces the time and/or energy required to produce a dried aerogel compared to conventional methods using either supercritical solvent extraction. The air dried gel exhibits typically less than 5% shrinkage.

  10. Dry Cask Storage Study Feb 1989

    Broader source: Energy.gov [DOE]

    This report on the use of dry-cask-storage technologies at the sites of civilian nuclear power reactors has been prepared by the U.S. Department of Energy (DOE} in response to the requirements of...

  11. Geothermal Food Processors Agricultural Drying Low Temperature...

    Open Energy Info (EERE)

    Processors is an Agricultural Drying low temperature direct use geothermal facility in Brady Hot Springs E of Fernley, Nevada. This article is a stub. You can help OpenEI by...

  12. Bioenergy Impacts … Billion Dry Tons

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    by 2030 at least one billion dry tons of non-food biomass resources, yielding up to 60 billion gallons of biofuels, as well as bio- based chemicals, products, and electricity. ...

  13. A reduced graphene oxide/Co{sub 3}O{sub 4} composite for supercapacitor electrode

    SciTech Connect (OSTI)

    Xiang, Chengcheng; Li, Ming; Zhi, Mingjia; Manivannan, Ayyakkannu; Wu, Nianqiang

    2013-03-15

    20 nm sized Co{sub 3}O{sub 4} nanoparticles are in-situ grown on the chemically reduced graphene oxide (rGO) sheets to form a rGO-Co{sub 3}O{sub 4} composite during hydrothermal processing. The rGO-Co{sub 3}O{sub 4} composite is employed as the pseudocapacitor electrode in the 2 M KOH aqueous electrolyte solution. The rGOCo{sub 3}O{sub 4} composite electrode exhibits a specific capacitance of 472 F/g at a scan rate of 2 mV/s in a two-electrode cell. 82.6% of capacitance is retained when the scan rate increases to 100 mV/s. The rGOCo{sub 3}O{sub 4} composite electrode shows high rate capability and excellent long-term stability. It also exhibits high energy density at relatively high power density. The energy density reaches 39.0 Wh/kg at a power density of 8.3 kW/kg. The super performance of the composite electrode is attributed to the synergistic effects of small size and good redox activity of the Co{sub 3}O{sub 4} particles combined with high electronic conductivity of the rGO sheets.

  14. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing,more » between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.« less

  15. Atomic-Layer-Deposited Transparent Electrodes for Silicon Heterojunction Solar Cells

    SciTech Connect (OSTI)

    Demaurex, Benedicte; Seif, Johannes P.; Smit, Sjoerd; Macco, Bart; Kessels, W. M.; Geissbuhler, Jonas; De Wolf, Stefaan; Ballif, Christophe

    2014-11-01

    We examine damage-free transparent-electrode deposition to fabricate high-efficiency amorphous silicon/crystalline silicon heterojunction solar cells. Such solar cells usually feature sputtered transparent electrodes, the deposition of which may damage the layers underneath. Using atomic layer deposition, we insert thin protective films between the amorphous silicon layers and sputtered contacts and investigate their effect on device operation. We find that a 20-nm-thick protective layer suffices to preserve, unchanged, the amorphous silicon layers beneath. Insertion of such protective atomic-layer-deposited layers yields slightly higher internal voltages at low carrier injection levels. However, we identify the presence of a silicon oxide layer, formed during processing, between the amorphous silicon and the atomic-layer-deposited transparent electrode that acts as a barrier, impeding hole and electron collection.

  16. Spray drying for high-sulfur coal

    SciTech Connect (OSTI)

    Rhudy, R.

    1988-09-01

    Recent pilot plant tests indicate that spray drying, now used to control SO/sub 2/ emissions from low-sulfur coal, can also be effective for high-sulfur coal. Spray drying coupled with baghouse particulate removal is the most effective configuration tested to date, removing over 90% of SO/sub 2/ while easily meeting New Source Performance Standards for particulate emissions. 2 figures, 1 table.

  17. Li-alloy electrode for Li-alloy/metal sulfide cells

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1996-01-01

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Lithium, silicon and nickel is alloyed in a prescribed proportion forming an electroactive material, to provide an improved electrode and cell.

  18. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, J.A.

    1997-08-26

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for (1) cleaning, developing or etching, (2) rinsing, and (3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material. 5 figs.

  19. Moving zone Marangoni drying of wet objects using naturally evaporated solvent vapor

    DOE Patents [OSTI]

    Britten, Jerald A. (Oakley, CA)

    1997-01-01

    A surface tension gradient driven flow (a Marangoni flow) is used to remove the thin film of water remaining on the surface of an object following rinsing. The process passively introduces by natural evaporation and diffusion of minute amounts of alcohol (or other suitable material) vapor in the immediate vicinity of a continuously refreshed meniscus of deionized water or another aqueous-based, nonsurfactant rinsing agent. Used in conjunction with cleaning, developing or wet etching application, rinsing coupled with Marangoni drying provides a single-step process for 1) cleaning, developing or etching, 2) rinsing, and 3) drying objects such as flat substrates or coatings on flat substrates without necessarily using heat, forced air flow, contact wiping, centrifugation or large amounts of flammable solvents. This process is useful in one-step cleaning and drying of large flat optical substrates, one-step developing/rinsing and drying or etching/rinsing/drying of large flat patterned substrates and flat panel displays during lithographic processing, and room-temperature rinsing/drying of other large parts, sheets or continuous rolls of material.

  20. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

    1994-03-08

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.