National Library of Energy BETA

Sample records for driver cr eek

  1. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    U.S. Energy Information Administration (EIA) Indexed Site

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  2. Hypernuclear Spectroscopy using the (e,e'K+) Reaction

    SciTech Connect (OSTI)

    Yuan, Lulin; Sarsour, Murad; Miyoshi, Toshinobu; Zhu, Zhengmao; Ahmidouch, Abdellah; Androic, Darko; Angelescu, Tatiana; Asaturyan, Razmik; Avery, Steven; Baker, O.; Bertovic, I.; Breuer, Herbert; Carlini, Roger; Cha, Jinseok; Chrien, Robert; Christy, Michael; Cole, Leon; Danagoulian, Samuel; Dehnhard, Dietrich; Elaasar, Mostafa; Empl, A.; Ent, Rolf; Fenker, Howard; Fujii, Yu; Furic, Miroslav; Gan, Liping; Garrow, Kenneth; Gasparian, Ashot; Gueye, Paul; Harvey, Mark; Hashimoto, Osamu; Hinton, Wendy; Hu, Bitao; Hungerford, Ed; Jackson, Caesar; Johnston, Kathleen; Juengst, Henry; Keppel, Cynthia; Lan, Kejian; Liang, Yongguang; LIKHACHEV, V.; Likhachev, V.; Liu, Jinghua; Mack, David; Margaryan, Amur; Markowitz, Pete; Mkrtchyan, Hamlet; Nakamura, Satoshi; Petkovic, Tomislav; Reinhold, Joerg; Roche, Julie; Sato, Yoshinori; Sawafta, Reyad; Simicevic, Neven; Smith, G.; Stepanyan, Samuel; Tadevosyan, Vardan; Takahashi, Toshiyuki; Tanida, K.; Tang, Liguang; Ukai, Mifuyu; Uzzle, Alicia; Vulcan, William; Wells, Steven; Wood, Stephen; Xu, Guanghua; Yamaguchi, Hiroshi

    2006-04-01

    A pioneering experiment in Lambda hypernuclear spectroscopy, undertaken at the Thomas Jefferson National Accelerator Facility (Jlab), was recently reported. The experiment used the high- precision, continuous electron beam at Jlab, and a special arrangement of spectrometer magnets to measure the spectrum from {nat}C and 7Li targets using the (e,e' K+)reaction. The 12B hypernuclear spectrum was previously published. This experiment is now reported in more detail, with improved results for the 12B hypernuclear spectrum. In addition, unpublished results of the 7He hypernuclear spectrum are also shown. This later spectrum indicates the need for a more detailed few-body calculation of the hypernucleus and the reaction process. The success of this experiment demonstrates that the (e,e'K+) reaction can be effectively used as a high resolution tool to study hypernuclear spectra, ant its use should be vigorously pursued.

  3. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    U.S. Energy Information Administration (EIA) Indexed Site

    WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK ... Authors: Sam Limerick (1), Lucy Luo (1), Gary Long (2), David Morehouse (2), Jack Perrin ...

  4. WH ITNEY CAN YON-CART ER CR K YELLOW CR EEK_WY_D PIN EVIEW AN

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline WY UT ID INDEX MAP...

  5. WH ITNEY CAN YON-CART ER CR K YELLOW CR EEK_WY_D PIN EVIEW AN

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Basin Outline WY UT ID INDEX MAP 2001...

  6. WH ITNEY CAN YON-CART ER CR K YELLOW CR EEK_WY_D PIN EVIEW AN

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Basin Outline WY UT ID INDEX MAP ...

  7. WH ITNEY CAN YON-CART ER CR K YELLOW CR EEK_WY_D PIN EVIEW AN

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Basin Outline WY UT ID INDEX MAP 2001 ...

  8. WH ITNEY CAN YON-CART ER CR K YELLOW CR EEK_WY_D PIN EVIEW AN

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Basin Outline WY UT ID INDEX ...

  9. WH ITNEY CAN YON-CART ER CR K YELLOW CR EEK_WY_D PIN EVIEW AN

    U.S. Energy Information Administration (EIA) Indexed Site

    - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Basin Outline WY UT ID INDEX MAP 2001 Reserve Summary for Wyoming Thrust Belt Fields Wyoming Thrust Belt Oil & Gas Fields ...

  10. Spectroscopic Investigation of p-Shell Lambda Hypernuclei by the (e,e'K+) Reaction

    SciTech Connect (OSTI)

    Chen, Chunhua

    2014-08-01

    Hypernuclear spectroscopy is a powerful tool to investigate Lambda-N interaction. Compared with other Lambda hypernuclei productions, electroproduction via the (e,e'K+) reaction has the advantage of exciting states deeply inside of the hypernucleus and achieving sub-MeV energy resolution. The E05-115 experiment, which was successfully performed in 2009, is the third generation hypernuclear experiment in JLab Hall C. A new splitter magnet and electron spectrometer were installed, and beam energy of 2.344 GeV was selected in this experiment. These new features gave better field uniformity, optics quality and made the ?tilt method? more effective in improving yield-to-background ratio. The magnetic optics of the spectrometers were carefully studied with GEANT simulation, and corrections were applied to compensate for the fringe field cross talk between the compact spectrometer magnets. The non-linear least chi-squared method was used to further calibrate the spectrometer with the events from Lambda, Sigma0 and B12Lambda and uniform magnetic optics as well as precise kinematics were achieved. Several p-shell Lambda hypernuclear spectra, including B12Lambda, Be10Lambda, He7Lambda, were obtained with high energy resolution and good accuracy. For B12Lambda, eight peaks were recognized with the resolution of ~540keV (FWHM), and the ground state binding energy was obtained as 11.529 0.012(stat.) 0.110(syst.) MeV. Be10Lambda, twelve peaks were recognized with the resolution of ~520keV (FWHM), and the binding energy of the ground state was determined as 8.710 0.059(stat.) 0.114(syst.) MeV. For He7Lambda, three peaks were recognized with the resolution of ~730keV, and the ground state binding energy was obtained as 5.510 0.050(stat.) 0.120(syst.) MeV. Compared with the published data of B12Lambda from the JLab Hall A experiment, four extra peaks were fitted and interpreted thanks to the highest ever energy resolution and sufficient statistics. The determined

  11. LOOKOU T U-87 U-70 PEC ONI C COM AN CHE CR EEK U-107 HUGO CLIFF

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Denver Basin Outline The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface

  12. LOOKOU T U-87 U-70 PEC ONI C COM AN CHE CR EEK U-107 HUGO CLIFF

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Denver Basin Outline The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface

  13. LOOKOU T U-87 U-70 PEC ONI C COM AN CHE CR EEK U-107 HUGO CLIFF

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Denver Basin Outline The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by subsurface structural

  14. LOOKOU T U-87 U-70 PEC ONI C COM AN CHE CR EEK U-107 HUGO CLIFF

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquids Reserve Class No 2001 liquids reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl 10,000.1 - 100,000 Mbbl Denver Basin Outline The mapped oil ...

  15. LOOKOU T U-87 U-70 PEC ONI C COM AN CHE CR EEK U-107 HUGO CLIFF

    U.S. Energy Information Administration (EIA) Indexed Site

    BOE Reserve Class No 2001 reserves 0.1 - 10 MBOE 10.1 - 100 MBOE 100.1 - 1,000 MBOE 1,000.1 - 10,000 MBOE 10,000.1 - 100,000 MBOE > 100,000 MBOE Denver Basin Outline The mapped oil ...

  16. LOOKOU T U-87 U-70 PEC ONI C COM AN CHE CR EEK U-107 HUGO CLIFF

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Reserve Class No 2001 gas reserves 0.1 - 10 MMCF 10.1 - 100 MMCF 100.1 - 1,000 MMCF 1,000.1 - 10,000 MMCF 10,000.1 - 100,000 MMCF > 100,000 MMCF Denver Basin Outline The mapped ...

  17. LANL GPIB Driver

    Energy Science and Technology Software Center (OSTI)

    2004-04-15

    This driver code adds a GPIB infrastructure and API features to 2.6 series Linux kernels. Currently supported hardware is National Instruments PCI-GPIB cards built on either the TNT4882 controller chip, or the TNT5004 controller chip. This driver is an improvement over previous GPIB drivers in Linux because it has all the features of the GPL, high performance DMA, supports Linux 2.6 and the new driver model, and has a cleaner API than the previous drivers.more » GPIB is the "general purpose interface bus", commonly used to control oscilloscopes, digital multimeters, function generators, and other electronic test equipment.« less

  18. Market Drivers for Biofuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MARKET DRIVERS FOR BIOFUELS Brian Duff Chief Engineer Bioenergy Technologies Office 3 rd Annual MSW to Biofuels Summit, Orlando, FL February 20-21, 2013 2 | Bioenergy Technologies ...

  19. Drivers, Trends and Mitigation

    SciTech Connect (OSTI)

    Blanco, Arthur S.; Gerlagh, Reyer; Suh, Sangwon; Barrett, John A.; de Coninck, Heleen; Diaz Morejon, Cristobal Felix; Mathur, Ritu; Nakicenovic, Nebojsa; Ahenkorah, Alfred Ofosu; Pan, Jiahua; Pathak, Himanshu; Rice, Jake; Richels, Richard G.; Smith, Steven J.; Stern, David; Toth, Ferenc L.; Zhou, Peter

    2014-12-01

    Chapter 5 analyzes the anthropogenic greenhouse gas (GHG) emission trends until the present and the main drivers that explain those trends. The chapter uses different perspectives to analyze past GHG-emissions trends, including aggregate emissions flows and per capita emissions, cumulative emissions, sectoral emissions, and territory-based vs. consumption-based emissions. In all cases, global and regional trends are analyzed. Where appropriate, the emission trends are contextualized with long-term historic developments in GHG emissions extending back to 1750.

  20. Robotic Intelligence Kernel: Driver

    Energy Science and Technology Software Center (OSTI)

    2009-09-16

    The INL Robotic Intelligence Kernel-Driver is built on top of the RIK-A and implements a dynamic autonomy structure. The RIK-D is used to orchestrate hardware for sensing and action as well as software components for perception, communication, behavior and world modeling into a single cognitive behavior kernel that provides intrinsic intelligence for a wide variety of unmanned ground vehicle systems.

  1. Sandia Material Model Driver

    Energy Science and Technology Software Center (OSTI)

    2005-09-28

    The Sandia Material Model Driver (MMD) software package allows users to run material models from a variety of different Finite Element Model (FEM) codes in a standalone fashion, independent of the host codes. The MMD software is designed to be run on a variety of different operating system platforms as a console application. Initial development efforts have resulted in a package that has been shown to be fast, convenient, and easy to use, with substantialmore » growth potential.« less

  2. ECOdriving - Widespread Implementation for Learner Drivers and...

    Open Energy Info (EERE)

    programs for licensed drivers in 13 European countries. ECOWILL also promotes the education of eco-driving for learner drivers. This website provides information about...

  3. Proton driver power supply system

    SciTech Connect (OSTI)

    C. Jach and D. Wolff

    2002-06-03

    This paper describes magnet power supply system for a proposed Proton Driver at Fermilab. The magnet power supply system consists of resonant dipole/quadrupole power supply system, quadrupole tracking, dipole correction (horizontal and vertical) and sextupole power supply systems. This paper also describes preliminary design of the power distribution system supplying 13.8 kV power to all proton Driver electrical systems.

  4. Lawrence Co. Scioto Co. Greenup Co. Jack

    U.S. Energy Information Administration (EIA) Indexed Site

    LYNAM CR EEK MCGRAW-CBM TEAYS VALLEY DOT Y BRANCH ISLAN D CREEK RITC HIE GREEN GROVE WILL IAM SBU RG BEECH Y C REEK YELLOW CR EEK GROUN DHOG CREEK ST FK-BLST N CK SLAB F OR K-CBM ...

  5. UWB dual burst transmit driver

    DOE Patents [OSTI]

    Dallum, Gregory E.; Pratt, Garth C.; Haugen, Peter C.; Zumstein, James M.; Vigars, Mark L.; Romero, Carlos E.

    2012-04-17

    A dual burst transmitter for ultra-wideband (UWB) communication systems generates a pair of precisely spaced RF bursts from a single trigger event. An input trigger pulse produces two oscillator trigger pulses, an initial pulse and a delayed pulse, in a dual trigger generator. The two oscillator trigger pulses drive a gated RF burst (power output) oscillator. A bias driver circuit gates the RF output oscillator on and off and sets the RF burst packet width. The bias driver also level shifts the drive signal to the level that is required for the RF output device.

  6. Eaton AF5000+Genesis Communication Driver

    Energy Science and Technology Software Center (OSTI)

    1995-05-25

    Communication driver allows the Genesis Control Series software to interact with Eaton AF5000+ frequency drives via RS-232 communications. All Eaton AF5000+ parameters that support communications are supported by the Genesis driver. Multidrop addressing to multiple units is available with the Genesis communication driver.

  7. Drivers of Future Energy Demand

    U.S. Energy Information Administration (EIA) Indexed Site

    Drivers of Future Energy Demand in China Asian Energy Demand Outlook 2014 EIA Energy Conference July 14, 2014 Valerie J. Karplus MIT Sloan School of Management 2 www.china.org.cn www.flickr.com www.wikimedia.org globalchange.mit.edu Global Climate Change Human Development Local Pollution Industrial Development & Resource Needs How to balance? 0 500 1000 1500 2000 2500 3000 3500 4000 1981 1991 2001 2011 Non-material Sectors/Other Construction Commercial consumption Residential consumption

  8. Market Drivers for Biofuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Market Drivers for Biofuels Market Drivers for Biofuels This presentation, entitled "Market Drivers for Biofuels," was given at the Third Annual MSW to Biofuels Summit in February, 2013, by Brian Duff. duff_msw_to_biofuels_summit.pdf (2.42 MB) More Documents & Publications Office of the Biomass Program Educational Opportunities in Bioenergy Intro Webinar Webinar: Using the New Bioenergy KDF for Data Discovery and Research Sustainability for the Global Biofuels Industry: Minimizing

  9. Physics at an upgraded Fermilab proton driver

    SciTech Connect (OSTI)

    Geer, S.; /Fermilab

    2005-07-01

    In 2004 the Fermilab Long Range Planning Committee identified a new high intensity Proton Driver as an attractive option for the future, primarily motivated by the recent exciting developments in neutrino physics. Over the last few months a physics study has developed the physics case for the Fermilab Proton Driver. The potential physics opportunities are discussed.

  10. V-217: Microsoft Windows NAT Driver ICMP Packet Handling Denial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7: Microsoft Windows NAT Driver ICMP Packet Handling Denial of Service Vulnerability V-217: Microsoft Windows NAT Driver ICMP Packet Handling Denial of Service Vulnerability August...

  11. Renewable Energy Technology Costs and Drivers | Open Energy Informatio...

    Open Energy Info (EERE)

    Technology Costs and Drivers Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Renewable Energy Technology Costs and Drivers AgencyCompany Organization: National...

  12. Drivers and Barriers in the Current Concentrated Solar Power...

    Open Energy Info (EERE)

    Drivers and Barriers in the Current Concentrated Solar Power (CSP) Market (Webinar) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Drivers and Barriers in the Current...

  13. PowerPoint Presentation

    Gasoline and Diesel Fuel Update (EIA)

    COAL D EGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL D EGAS BLU FF COR INNE MOU NDVILLE COAL D EGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F ERRY LEXIN GT ON PET ERSON COAL

  14. OAK GROVE C OAL D EGAS CEDAR COVE COAL D EGAS BLU E CREEK COAL DEGAS

    U.S. Energy Information Administration (EIA) Indexed Site

    OAK GROVE C OAL D EGAS CEDAR COVE COAL D EGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL D EGAS BLU FF COR INNE MOU NDVILLE COAL D EGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F

  15. Pontotoc Co. Greene Co. Hale Co. OAK GROVE C OAL D EGAS CEDAR COVE

    U.S. Energy Information Administration (EIA) Indexed Site

    COAL D EGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL D EGAS BLU FF COR INNE MOU NDVILLE COAL D EGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F ERRY LEXIN GT ON PET ERSON COAL

  16. Pontotoc Co. Greene Co. Hale Co. OAK GROVE C OAL D EGAS CEDAR COVE COAL DEGAS

    U.S. Energy Information Administration (EIA) Indexed Site

    COAL DEGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL DEGAS BLU FF COR INNE MOU NDVILLE COAL DEGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F ERRY LEXIN GT ON PET ERSON COAL

  17. ODU Researcher Visits JLab to Talk About Living in the Arctic (Daily Press)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GROVE C OAL D EGAS CEDAR COVE COAL D EGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL D EGAS BLU FF COR INNE MOU NDVILLE COAL D EGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F

  18. Popular Science Recognizes Innovative Solar Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    COAL D EGAS BLU E CREEK COAL DEGAS BR OOKWOOD C OAL D EGAS ST AR ROBIN SONS BEND COAL D EGAS BLU FF COR INNE MOU NDVILLE COAL D EGAS BLU EGU T CR EEK WH ITE OAK CREEK COAL DEGAS BEAVERT ON BLU FF FAYETTE W SN EAD S CREEK SPLU NGE PAR HAM N MUSGR OVE CR EEK MCCRAC KEN MOU NTAIN DAVIS C HAPEL BAC ON BLOOMING GROVE MT Z ION FAIRVIEW JASPER BLOWHORN CREEK MAPLE BRAN CH KEN NEDY COAL F IRE CR EEK MCGEE LAKE SILOAM MILLPOR T FERNBANK DAVIS C HAPEL NE DETROIT E BEANS F ERRY LEXIN GT ON PET ERSON COAL

  19. Driver circuit for solid state light sources

    DOE Patents [OSTI]

    Palmer, Fred; Denvir, Kerry; Allen, Steven

    2016-02-16

    A driver circuit for a light source including one or more solid state light sources, a luminaire including the same, and a method of so driving the solid state light sources are provided. The driver circuit includes a rectifier circuit that receives an alternating current (AC) input voltage and provides a rectified AC voltage. The driver circuit also includes a switching converter circuit coupled to the light source. The switching converter circuit provides a direct current (DC) output to the light source in response to the rectified AC voltage. The driver circuit also includes a mixing circuit, coupled to the light source, to switch current through at least one solid state light source of the light source in response to each of a plurality of consecutive half-waves of the rectified AC voltage.

  20. OMEGA Laser Drivers - Laboratory for Laser Energetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Drivers - Laboratory for Laser Energetics Laboratory for Laser Energetics Logo Search Home Around the Lab Past Issues Past Quick Shots About Office of the Director Map to LLE LLE ...

  1. Physics at a new Fermilab proton driver

    SciTech Connect (OSTI)

    Geer, Steve; /Fermilab

    2006-04-01

    In 2004, motivated by the recent exciting developments in neutrino physics, the Fermilab Long Range Planning Committee identified a new high intensity Proton Driver as an attractive option for the future. At the end of 2004 the APS ''Study on the Physics of Neutrinos'' concluded that the future US neutrino program should have, as one of its components, ''A proton driver in the megawatt class or above and neutrino superbeam with an appropriate very large detector capable of observing Cp violation and measuring the neutrino mass-squared differences and mixing parameters with high precision''. The presently proposed Fermilab Proton Driver is designed to accomplish these goals, and is based on, and would help develop, Linear Collider technology. In this paper the Proton Driver parameters are summarized, and the potential physics program is described.

  2. Linear transformer driver for pulse generation

    DOE Patents [OSTI]

    Kim, Alexander A; Mazarakis, Michael G; Sinebryukhov, Vadim A; Volkov, Sergey N; Kondratiev, Sergey S; Alexeenko, Vitaly M; Bayol, Frederic; Demol, Gauthier; Stygar, William A

    2015-04-07

    A linear transformer driver includes at least one ferrite ring positioned to accept a load. The linear transformer driver also includes a first power delivery module that includes a first charge storage devices and a first switch. The first power delivery module sends a first energy in the form of a first pulse to the load. The linear transformer driver also includes a second power delivery module including a second charge storage device and a second switch. The second power delivery module sends a second energy in the form of a second pulse to the load. The second pulse has a frequency that is approximately three times the frequency of the first pulse. The at least one ferrite ring is positioned to force the first pulse and the second pulse to the load by temporarily isolating the first pulse and the second pulse from an electrical ground.

  3. TMACS Test Procedure TP009: Acromag Driver

    SciTech Connect (OSTI)

    Washburn, S.J.

    1994-05-31

    The TMACS Software Project Test Procedures translate the project`s acceptance criteria into test steps. Software releases are certified when the affected Test Procedures are successfully performed and the customers authorize installation of these changes. This Test Procedure tests the TMACS Acromag Software Driver (Bridge Code).

  4. Drivers of Success in the Better Buildings Neighborhood Program --

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Statistical Process Evaluation Volume 3 | Department of Energy Drivers of Success in the Better Buildings Neighborhood Program -- Statistical Process Evaluation Volume 3 Drivers of Success in the Better Buildings Neighborhood Program -- Statistical Process Evaluation Volume 3 Final Report: Drivers of Success in the Better Buildings Neighborhood Program - Statistical Process Evaluation Final Evaluation Volume 3, American Recovery and Reinvestment Act of 2009, June 2015. Drivers of Success in

  5. Tank monitor and control system (TMACS) software project Westronics Driver acceptance test

    SciTech Connect (OSTI)

    Glasscock, J.A.

    1998-08-18

    The acceptance test for the Westronics driver. This driver connects the Westronics Smart Multiplexer with the TMACS monitoring system.

  6. Alternative Fuel Driver Training Companion Manual

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    EPAct Regulated Fleets Alternative Fuel Driver Training Companion Manual Notice This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use

  7. A material model driver for DYNA3D

    SciTech Connect (OSTI)

    Hallquist, J.O.; Whirley, R.G.

    1990-02-22

    This report describes a material model driver which has recently been implemented in the DYNA3D code. The material model driver allows plotting of the constitutive response predicted by a material model under a given load path. This capability is particularly useful when fitting complex material models to experimental data. The plotting capability of the material model driver facilitates comparison of the simulated material stress-strain behavior with actual material test results. 1 ref., 6 figs., 4 tabs.

  8. Vehicle Technologies Office Merit Review 2015: Gate Driver Optimizatio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gate Driver Optimization for WBG Applications Vehicle Technologies Office Merit Review ... Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells ...

  9. OLED Luminaire with Panel Integrated Drivers and Advanced Controls...

    Broader source: Energy.gov (indexed) [DOE]

    DC current drivers integrated with each panel, and a base station that interfaces with ... More Documents & Publications High-Performance OLED Panel and Luminaire Luminaires for ...

  10. Brazil's Biofuels Scenario: What are the Main Drivers Which will...

    Broader source: Energy.gov (indexed) [DOE]

    in Bioenergy Brazil's Biofuels Scenario: What are the Main Drivers Which will Shape Investments in the Long Term? Artur Milanez, Manager of Biofuels Department, Brazilian ...

  11. BG/Q Drivers Status | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Blue GeneQ Versus Blue GeneP BGQ Drivers Status Machine Overview Machine Partitions Torus Network Data Storage & File Systems Compiling & Linking Queueing & Running Jobs Data...

  12. Microsoft Word - ContractManagementPlanningDRIVERS.doc | Department...

    Broader source: Energy.gov (indexed) [DOE]

    ContractManagementPlanningDRIVERS.doc More Documents & Publications Microsoft Word - ARRAAttachment2.doc Microsoft Word - ARRAModelWAS.doc Microsoft Word - ARRAMOModelMod.doc...

  13. High Temperature, High Voltage Fully Integrated Gate Driver Circuit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. PDF icon ape003tolbert2010p.pdf More Documents & Publications High Temperature, High Voltage Fully Integrated Gate Driver Circuit Wide Bandgap Materials Smart ...

  14. High Temperature, High Voltage Fully Integrated Gate Driver Circuit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -- Washington D.C. PDF icon ape03marlino.pdf More Documents & Publications High Temperature, High Voltage Fully Integrated Gate Driver Circuit Smart Integrated Power Module ...

  15. Drivers of Success in the Better Buildings Neighborhood Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Neighborhood Program -- Statistical Process Evaluation Volume 3 Drivers of Success in the Better Buildings Neighborhood Program -- Statistical Process Evaluation Volume 3 ...

  16. Alternative Fuel Vehicles: What Do the Drivers Say?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What Do the Drivers Say? For more information contact: e:mail: Public Affairs Golden, Colo., Nov. 19, 1997 -- What do the people who drive them really think about alternative fuel vehicles (AFVs)? That was the question on the table when the U.S. Department of Energy (DOE) launched a nationwide survey of federal fleet managers and AFV drivers in 1996. The answers are in Perspectives on AFVs: 1996 Federal Fleet Driver Survey. Two hundred and fifty drivers were surveyed during each quarter of 1996.

  17. Inertially confined fusion using heavy ion drivers

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B. ); Bangerter, R.O. ); Bock, R. ); Hogan, W.J.; Lindl, J.D. )

    1991-10-01

    The various technical issues of HIF will be briefly reviewed in this paper. It will be seen that there are numerous areas in common in all the approaches to HIF. In the recent International Symposium on Heavy Ion Inertial Fusion, the attendees met in specialized workshop sessions to consider the needs for research in each area. Each of the workshop groups considered the key questions of this report: (1) Is this an appropriate time for international collaboration in HIF (2) Which problems are most appropriate for such collaboration (3) Can the sharing of target design information be set aside until other driver and systems issues are better resolved, by which time it might be supposed that there could be a relaxation of classification of target issues (4) What form(s) of collaboration are most appropriate, e.g., bilateral or multilateral (5) Can international collaboration be sensibly attempted without significant increases in funding for HIF The authors of this report share the conviction that collaboration on a broad scale is mandatory for HIF to have the resources, both financial and personnel, to progress to a demonstration experiment. Ultimately it may be possible for a single driver with the energy, power, focusibility, and pulse shape to satisfy the needs of the international community for target physics research. Such a facility could service multiple experimental chambers with a variety of beam geometries and target concepts.

  18. Inertially confined fusion using heavy ion drivers

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B.; Bangerter, R.O.; Bock, R.; Hogan, W.J.; Lindl, J.D.

    1991-10-01

    The various technical issues of HIF will be briefly reviewed in this paper. It will be seen that there are numerous areas in common in all the approaches to HIF. In the recent International Symposium on Heavy Ion Inertial Fusion, the attendees met in specialized workshop sessions to consider the needs for research in each area. Each of the workshop groups considered the key questions of this report: (1) Is this an appropriate time for international collaboration in HIF? (2) Which problems are most appropriate for such collaboration? (3) Can the sharing of target design information be set aside until other driver and systems issues are better resolved, by which time it might be supposed that there could be a relaxation of classification of target issues? (4) What form(s) of collaboration are most appropriate, e.g., bilateral or multilateral? (5) Can international collaboration be sensibly attempted without significant increases in funding for HIF? The authors of this report share the conviction that collaboration on a broad scale is mandatory for HIF to have the resources, both financial and personnel, to progress to a demonstration experiment. Ultimately it may be possible for a single driver with the energy, power, focusibility, and pulse shape to satisfy the needs of the international community for target physics research. Such a facility could service multiple experimental chambers with a variety of beam geometries and target concepts.

  19. Fact #922: April 25, 2016 Share of Older Population Holding Driver's

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Licenses is Up and Share of Younger Population Holding Driver's Licenses is Down | Department of Energy 2: April 25, 2016 Share of Older Population Holding Driver's Licenses is Up and Share of Younger Population Holding Driver's Licenses is Down Fact #922: April 25, 2016 Share of Older Population Holding Driver's Licenses is Up and Share of Younger Population Holding Driver's Licenses is Down SUBSCRIBE to the Fact of the Week Examining the share of population holding driver's licenses in

  20. WIPP Driver Makes History, Again | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WIPP Driver Makes History, Again WIPP Driver Makes History, Again August 31, 2011 - 12:00pm Addthis Media Contact Deb Gill www.wipp.energy.gov 575-234-7270 CARLSBAD, N.M. - A brand-new shipping package arrived at the Department of Energy's Waste Isolation Pilot Plant (WIPP) during the early evening hours of August 25, but an all-too familiar face was behind the wheel of the vehicle carrying the package. Long-time WIPP driver Randy Anderson made history, again, when he guided the new TRUPACT-III

  1. Driver performance data acquisition system for ergonomics research

    SciTech Connect (OSTI)

    Carter, R.J.; Goodman, M.J.

    1994-12-31

    A portable ergonomics data acquisition system consisting of state-of-the-art hardware being designed is described here. It will be employed to record driver, vehicle, and environment parameter data from a wide range of vehicles and trucks. The system will be unobtrusive to the driver and inconspicuous to the outside world. It will have three modes of data gathering and provide for extended periods of data collection. Modularity, flexibility, and cost will be key drivers in the development effort. The ergonomics data acquisition system project is being conducted in two phases--a feasibility study and a development, construction, and validation phase.

  2. FFAG ACCELERATOR PROTON DRIVER FOR NEUTRINO FACTORY.

    SciTech Connect (OSTI)

    RUGGIERO, A.

    2005-06-21

    This paper is the summary of a conceptual study of a Proton Driver for Neutrino Factory based on the use of a Fixed-Field Alternating-Gradient (FFAG) Accelerator. The required proton energy range for an optimum neutrino production is 5 to 12 GeV. This can be accomplished with a group of three concentric rings each with 807 m circumference [1]. FFAG Accelerators [2] have the capability to accelerate charged particles over a large momentum range ({+-}30-50%) and the feature of constant bending and focusing fields. Particles can be accelerated very fast at the rate given by the accelerating field of RF cavities placed in proper locations between magnets. The performance of FFAG accelerators is to be placed between that of Super-Conducting Linear Accelerators (SCL), with which they share the fast acceleration rate, and Rapid-Cycling Synchrotrons (RCS), as they allow the beam to re-circulate over fewer revolutions. Brookhaven National Laboratory is involved in the study of feasibility of FFAG Accelerators to accelerate intense beams of protons in the GeV energy range for a variety of applications the most important of which is the Upgrade of the Alternating Gradient Synchrotron (AGS) with a new FFAG injector [3] accelerating from 400 MeV to 1.5 GeV. The ring would be housed in the AGS tunnel and has henceforth a circumference of 807 m.

  3. Process for depositing Cr-bearing layer

    DOE Patents [OSTI]

    Ellis, Timothy W.; Lograsso, Thomas A.; Eshelman, Mark A.

    1995-05-09

    A method of applying a Cr-bearing layer to a substrate, comprises introducing an organometallic compound, in vapor or solid powder form entrained in a carrier gas to a plasma of an inductively coupled plasma torch or device to thermally decompose the organometallic compound and contacting the plasma and the substrate to be coated so as to deposit the Cr-bearing layer on the substrate. A metallic Cr, Cr alloy or Cr compound such as chromium oxide, nitride and carbide can be provided on the substrate. Typically, the organometallic compound is introduced to an inductively coupled plasma torch that is disposed in ambient air so to thermally decompose the organometallic compound in the plasma. The plasma is directed at the substrate to deposit the Cr-bearing layer or coating on the substrate.

  4. Process for depositing Cr-bearing layer

    DOE Patents [OSTI]

    Ellis, T.W.; Lograsso, T.A.; Eshelman, M.A.

    1995-05-09

    A method of applying a Cr-bearing layer to a substrate, comprises introducing an organometallic compound, in vapor or solid powder form entrained in a carrier gas to a plasma of an inductively coupled plasma torch or device to thermally decompose the organometallic compound and contacting the plasma and the substrate to be coated so as to deposit the Cr-bearing layer on the substrate. A metallic Cr, Cr alloy or Cr compound such as chromium oxide, nitride and carbide can be provided on the substrate. Typically, the organometallic compound is introduced to an inductively coupled plasma torch that is disposed in ambient air so to thermally decompose the organometallic compound in the plasma. The plasma is directed at the substrate to deposit the Cr-bearing layer or coating on the substrate. 7 figs.

  5. Oil and natural gas market outlook and drivers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFS | Oil and natural gas market outlook and drivers, May 18, 2016 Global supply has ... WTI price dollars per barrel EIA expects WTI oil prices to remain low compared to recent ...

  6. Arbitrary waveform generator to improve laser diode driver performance

    DOE Patents [OSTI]

    Fulkerson, Jr, Edward Steven

    2015-11-03

    An arbitrary waveform generator modifies the input signal to a laser diode driver circuit in order to reduce the overshoot/undershoot and provide a "flat-top" signal to the laser diode driver circuit. The input signal is modified based on the original received signal and the feedback from the laser diode by measuring the actual current flowing in the laser diode after the original signal is applied to the laser diode.

  7. Science Drivers and Technical Challenges for Advanced Magnetic Resonance

    SciTech Connect (OSTI)

    Mueller, Karl T.; Pruski, Marek; Washton, Nancy M.; Lipton, Andrew S.

    2013-03-07

    This report recaps the "Science Drivers and Technical Challenges for Advanced Magnetic Resonance" workshop, held in late 2011. This exploratory workshop's goal was to discuss and address challenges for the next generation of magnetic resonance experimentation. During the workshop, participants from throughout the world outlined the science drivers and instrumentation demands for high-field dynamic nuclear polarization (DNP) and associated magnetic resonance techniques, discussed barriers to their advancement, and deliberated the path forward for significant and impactful advances in the field.

  8. Drivers of Success in the Better Buildings Neighborhood Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Report Drivers of Success in the Better Buildings Neighborhood Program - Statistical Process Evaluation Final Evaluation Volume 3 American Recovery and Reinvestment Act of 2009 June 2015 DOE/EE-1204 DOE/EE-1204 Final Report Drivers of Success in the Better Buildings Neighborhood Program - Statistical Process Evaluation Final Evaluation Volume 3 American Recovery and Reinvestment Act of 2009 June 2015 Funded By: Prepared By: Research Into Action, Inc. Prepared For: U.S. Department of

  9. Van Allen probes pinpoint driver of speeding electrons

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Van Allen probes pinpoint driver of speeding electrons Van Allen probes pinpoint driver of speeding electrons Los Alamos researchers believe they have solved a lingering mystery about how electrons within Earth's radiation belt can suddenly become energetic enough to kill orbiting satellites. July 25, 2013 Artist's rendering of mechanism within Van Allen radiation belts An artist's rendering of a mechanism within the Van Allen radiation belts that can accelerate electrons to satellite-killing

  10. Look-ahead driver feedback and powertrain management

    SciTech Connect (OSTI)

    Verma, Rajeev

    2014-12-31

    Commercial medium and heavy vehicles, though only a small portion of total vehicle population, play a significant role in energy consumption. In 2012, these vehicles accounted for about 5775.5 trillion btu of energy consumption and 408.8 million tons of CO2 emissions annually, which is a quarter of the total energy burden of highway transportation in the United States [1]. This number is expected to surpass passenger car fuel use within the next few decades. In the meantime, most commercial vehicle fleets are running at a very low profit margin. It is a well known fact that fuel economy can vary significantly between drivers, even when they operate the same vehicle on the same route. According to the US Environmental Protection Agency (EPA) and Natural Resource Canada (NRCan), there is up to 35% fuel economy difference between drivers within the same commercial fleet [2] [3], [4]. Similar results were obtained from a Field Operation Test conducted by Eaton Corporation [5]. During this test as much as 30% fuel economy difference was observed among pick-up-and-delivery drivers and 11% difference was observed among line-haul drivers. The driver variability can be attributed to the fact that different drivers react differently to driving conditions such as road grade, traffic, speed limits, etc. For instance, analysis of over 600k miles of naturalistic heavy duty truck driving data [5] indicates that an experienced driver anticipates a downhill and eases up on the throttle to save fuel while an inexperienced driver lacks this judgment.

  11. X- And y-axis driver for rotating microspheres

    DOE Patents [OSTI]

    Weinstein, Berthold W.

    1979-01-01

    Apparatus for precise control of the motion and position of microspheres for examination of their interior and/or exterior. The apparatus includes an x- and y-axis driver mechanism controlled, for example, by a minicomputer for selectively rotating microspheres retained between a pair of manipulator arms having flat, smooth end surfaces. The driver mechanism includes an apertured plate and ball arrangement which provided for coupled equal and opposite movement of the manipulator arms in two perpendicular directions.

  12. Nucleation of Cr precipitates in Fe-Cr alloy under irradiation

    SciTech Connect (OSTI)

    Dai, Y. Y.; Ao, L.; Sun, Qing- Qiang; Yang, L.; Nie, JL; Peng, SM; Long, XG; Zhou, X. S.; Zu, Xiaotao; Liu, L.; Sun, Xin; Terentyev, Dimtry; Gao, Fei

    2015-04-01

    The nucleation of Cr precipitates induced by overlapping of displacement cascades in Fe-Cr alloys has been investigated using the combination of molecular dynamics (MD) and Metropolis Monte Carlo (MMC) simulations. The results reveal that the number of Frenkel pairs increases with the increasing of overlapped cascades. Overlapping cascades could promote the formation of Cr precipitates in Fe-Cr alloys, as analyzed using short range order (SRO) parameters to quantify the degree of ordering and clustering of Cr atoms. In addition, the simulations using MMC approach show that the presence of small Cr clusters and vacancy clusters formed within cascade overlapped region enhance the nucleation of Cr precipitates, leading to the formation of large Cr dilute precipitates.

  13. Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy...

    Office of Scientific and Technical Information (OSTI)

    In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography. ... Therefor laser assisted atom probe tomography (APT) was utilized to study the phase ...

  14. Fact #574: June 8, 2009 Vehicles per Licensed Driver Rising | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 4: June 8, 2009 Vehicles per Licensed Driver Rising Fact #574: June 8, 2009 Vehicles per Licensed Driver Rising The number of vehicles in operation per licensed driver has risen steadily since 1950. In 1985, for the first time, there was one vehicle for every licensed driver. Since 1985, the number of vehicles in operation has exceeded the number of licensed drivers reaching a level of 1.21 vehicles per licensed driver in 2007. Vehicles per Licensed Driver, 1950-2007 Line graph

  15. Microsoft Word - CR.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 2004 Table 1. Estimated composition of REDOX HLW released from Tank 108 to the vadose zone in 1969 (from Jones et al., 2000). Temperature (° C) 100 H 2 O mole fraction 0.539 H 2 O weight fraction 0.304 Solution density (g/cm 3 ) 2.09 Ionic strength 18.02 Primary Chemical Species (mol/L) Al(OH) 4 - 3.36 K + 7.39 x 10 -2 Na + 19.6 OH - 5.25 NO 3 - 5.46 NO 2 - 4.42 Cl - 0.34 CO 3 2- 3.25 x 10 -2 SO 4 2- 2.77 x 10 -2 CrO 4 2- 4.13 x 10 -1 137 Cs + 6.51 x 10 -5 Table 1. Estimated composition

  16. Structural analysis of Cr aggregation in ferromagnetic semiconductor (Zn,Cr)Te

    SciTech Connect (OSTI)

    Kobayashi, H.; Yamawaki, K.; Nishio, Y.; Kanazawa, K.; Kuroda, S.; Mitome, M.; Bando, Y.

    2013-12-04

    The Cr aggregation in a ferromagnetic semiconductor (Zn,Cr)Te was studied by performing precise analyses using TEM and XRD of microscopic structure of the Cr-aggregated regions formed in iodine-doped Zn{sub 1?x}Cr{sub x}Te films with a relatively high Cr composition x ? 0.2. It was found that the Cr-aggregated regions are composed of Cr{sub 1??}Te nanocrystals of the hexagonal structure and these hexagonal precipitates are stacked preferentially on the (111)A plane of the zinc-blende (ZB) structure of the host ZnTe crystal with its c-axis nearly parallel to the (111){sub ZB} plane.

  17. Analyzing Vehicle Fuel Saving Opportunities through Intelligent Driver Feedback

    SciTech Connect (OSTI)

    Gonder, J.; Earleywine, M.; Sparks, W.

    2012-06-01

    Driving style changes, e.g., improving driver efficiency and motivating driver behavior changes, could deliver significant petroleum savings. This project examines eliminating stop-and-go driving and unnecessary idling, and also adjusting acceleration rates and cruising speeds to ideal levels to quantify fuel savings. Such extreme adjustments can result in dramatic fuel savings of over 30%, but would in reality only be achievable through automated control of vehicles and traffic flow. In real-world driving, efficient driving behaviors could reduce fuel use by 20% on aggressively driven cycles and by 5-10% on more moderately driven trips. A literature survey was conducted of driver behavior influences, and pertinent factors from on-road experiments with different driving styles were observed. This effort highlighted important driver influences such as surrounding vehicle behavior, anxiety over trying to get somewhere quickly, and the power/torque available from the vehicle. Existing feedback approaches often deliver efficiency information and instruction. Three recommendations for maximizing fuel savings from potential drive cycle improvement are: (1) leveraging applications with enhanced incentives, (2) using an approach that is easy and widely deployable to motivate drivers, and (3) utilizing connected vehicle and automation technologies to achieve large and widespread efficiency improvements.

  18. Plans for a proton driver at Fermilab

    SciTech Connect (OSTI)

    Kephart, R.D.; /Fermilab

    2005-01-01

    , and will certainly have important implications for our understanding of cosmology and the evolution of the early Universe. The current Fermilab Program is an important part of the world-wide accelerator based effort to explore and understand the physics of neutrino oscillations. By early 2005, with both MINOS and MiniBooNE taking data, Fermilab will be able to answer some of the most pressing first-round questions raised by the discovery that neutrinos have mass. Fermilab's high-intensity neutrino beams are derived from 8- and 120-GeV proton beams. MiniBooNE is currently taking data using 8 GeV Protons from the Booster. The 120 GeV NuMI beam will start to operate in early 2005 using a 0.25 MW proton beam power from the Main Injector. Future neutrino programs will build on these existing facilities. New short and long baseline experiments have been proposed. There are proposals to increase the available number of protons at 8 and 120 GeV with the goal of addressing the full range of questions presented by neutrino oscillations. Key to that vision is a new intense proton source that usually is referred to as the Proton Driver.

  19. Interstitial loop transformations in FeCr

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Béland, Laurent Karim; Osetsky, Yuri N.; Stoller, Roger E.; Xu, Haixuan

    2015-03-27

    Here, we improve the Self-Evolving Atomistic Kinetic Monte Carlo (SEAKMC) algorithm by integrating the Activation Relaxation Technique nouveau (ARTn), a powerful open-ended saddle-point search method, into the algorithm. We use it to investigate the reaction of 37-interstitial 1/2[1 1 1] and 1/2[View the MathML source] loops in FeCr at 10 at.% Cr. They transform into 1/2[1 1 1], 1/2[View the MathML source], [1 0 0] and [0 1 0] 74-interstitial clusters with an overall barrier of 0.85 eV. We find that Cr decoration locally inhibits the rotation of crowdions, which dictates the final loop orientation. Moreover, the final loop orientationmore » depends on the details of the Cr decoration. Generally, a region of a given orientation is favored if Cr near its interface with a region of another orientation is able to inhibit reorientation at this interface more than the Cr present at the other interfaces. Also, we find that substitutional Cr atoms can diffuse from energetically unfavorable to energetically favorable sites within the interlocked 37-interstitial loops conformation with barriers of less than 0.35 eV.« less

  20. BEAM SIMULATIONS USING VIRTUAL DIAGNOSTICS FOR THE DRIVER LINAC

    SciTech Connect (OSTI)

    R. C. York; X. Wu; Q. Zhao

    2011-12-21

    End-to-end beam simulations for the driver linac have shown that the design meets the necessary performance requirements including having adequate transverse and longitudinal acceptances. However, to achieve reliable operational performance, the development of appropriate beam diagnostic systems and control room procedures are crucial. With limited R&D funding, beam simulations provide a cost effective tool to evaluate candidate beam diagnostic systems and to provide a critical basis for developing early commissioning and later operational activities. We propose to perform beam dynamic studies and engineering analyses to define the requisite diagnostic systems of the driver linac and through simulation to develop and test commissioning and operational procedures.

  1. Emerson: ENERGY STAR Referral (CR289E)

    Broader source: Energy.gov [DOE]

    DOE referred the matter of Emerson-brand refrigerator, model CR289E, to the EPA for appropriate action after DOE testing showed that the model does not meet the ENERGY STAR specification.

  2. NUREG/CR-6150 EGG-2720

    Office of Scientific and Technical Information (OSTI)

    ... damaged TMI-2 core.62 The experiments in Germany and Japan have revealed the existence of ... revealed by out-of pile experiments in Germany 54,55959 and 4-57 IViJREiGlCR-6150 Fuel ...

  3. Midea: ENERGY STAR Referral (MWF-08CR)

    Broader source: Energy.gov [DOE]

    DOE referred the matter of Westpointe-brand room air conditioner model MWF-08CR to the EPA for appropriate action after DOE testing showed that the model does not meet the ENERGY STAR specification.

  4. TMACS test procedure TP009: Acromag driver. Revision 5

    SciTech Connect (OSTI)

    Bass, R.B.; Washburn, S.J.

    1994-09-01

    The TMACS Software Project Test Procedures translate the project`s acceptance criteria into test steps. Software releases are certified when the affected Test Procedures are successfully performed and the customers authorize installation of these changes. This Test Procedure addresses the testing of the functionality of the TMACS Acromag driver software in conjunction with a new bridge for the Panalarm Annunciator system.

  5. U-226: Linux Kernel SFC Driver TCP MSS Option Handling Denial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6: Linux Kernel SFC Driver TCP MSS Option Handling Denial of Service Vulnerability U-226: Linux Kernel SFC Driver TCP MSS Option Handling Denial of Service Vulnerability August 2,...

  6. Fact #761: January 7, 2013 Smaller Share of Teenagers Have a Driver's License in 2010

    Broader source: Energy.gov [DOE]

    In the 1980's, more than half of all teenagers 15 to 19 years old had a driver's license. But that has changed. Since 1995, less than half of that age group has a driver's license. In 2010, the...

  7. Fact #922: April 25, 2016 Share of Older Population Holding Driver...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    922: April 25, 2016 Share of Older Population Holding Driver's Licenses is Up and Share of Younger Population Holding Driver's Licenses is Down Fact 922: April 25, 2016 Share of ...

  8. Final Report on the Fuel Saving Effectiveness of Various Driver Feedback Approaches

    SciTech Connect (OSTI)

    Gonder, J.; Earleywine, M.; Sparks, W.

    2011-03-01

    This final report quantifies the fuel-savings opportunities from specific driving behavior changes, identifies factors that influence drivers' receptiveness to adopting fuel-saving behaviors, and assesses various driver feedback approaches.

  9. LaCrO{sub 3}-dispersed Cr for metallic interconnect of planar SOFC

    SciTech Connect (OSTI)

    Song, Rak-Hyun; Shin, Dong Ryul; Dokiya, Masayuki

    1996-12-31

    In the planar SOFC, the interconnect materials plays two roles as an electrical connection and as a gas separation plate in a cell stack. The interconnect materials must be chemically stable in reducing and oxidizing environments, and have high electronic conductivity, high thermal conductivity, matching thermal expansion with an electrolyte, high mechanical strength, good fabricability, and gas tightness. Lanthanum chromite so far has been mainly used as interconnect materials in planar SOFC. However, the ceramic materials are very weak in mechanical strength and have poor machining property as compared with metal. Also the metallic materials have high electronic conductivity and high thermal conductivity. Recently some researchers have studied metallic interconnects such as Al{sub 2}O{sub 3}/Inconel 600 cermet, Ni-20Cr coated with (LaSr)CoO{sub 3}, and Y{sub 2}O{sub 3-} or La{sub 2}O{sub 3}-dispersed Cr alloy. These alloys have still some problems because Ni-based alloys have high thermal expansion, the added Al{sub 2}O{sub 3}, Y{sub 2}O{sub 3} and La{sub 2}O{sub 3} to metals have no electronic conductivity, and the oxide formed on the surface of Cr alloy has high volatility. To solve these problems, in this study, LaCrO{sub 3}-dispersed Cr for metallic interconnect of planar SOFC was investigated. The LaCrO{sub 3}-dispersed Cr can be one candidate of metallic interconnect because LaCrO{sub 3} possesses electronic conductivity and Cr metal has relatively low thermal expansion. The content of 25 vol.% LaCrO{sub 3} Was selected on the basis of a theoretically calculated thermal expansion. The thermal expansion, electrical and oxidation properties were examined and the results were discussed as related to SOFC requirements.

  10. Heavy ion induction linac drivers for inertial confinement fusion

    SciTech Connect (OSTI)

    Lee, E.P.; Hovingh, J.

    1988-10-01

    Intense beams of high energy heavy ions (e.g., 10 GeV Hg) are an attractive option for an ICF driver because of their favorable energy deposition characteristics. The accelerator systems to produce the beams at the required power level are a development from existing technologies of the induction linac, rf linac/storage ring, and synchrotron. The high repetition rate of the accelerator systems, and the high efficiency which can be realized at high current make this approach especially suitable for commercial ICF. The present report gives a summary of the main features of the induction linac driver system, which is the approach now pursued in the USA. The main subsystems, consisting of injector, multiple beam accelerator at low and high energy, transport and pulse compression lines, and final focus are described. Scale relations are given for the current limits and other features of these subsystems. 17 refs., 1 fig., 1 tab.

  11. Microstructural and mechanical characteristics of Ni–Cr thin films

    SciTech Connect (OSTI)

    Petley, Vijay; Sathishkumar, S.; Thulasi Raman, K.H.; Rao, G.Mohan; Chandrasekhar, U.

    2015-06-15

    Highlights: • Ni–Cr thin films of varied composition deposited by DC magnetron co-sputtering. • Thin film with Ni–Cr: 80–20 at% composition exhibits most distinct behavior. • The films were tensile tested and exhibited no cracking till the substrate yielding. - Abstract: Ni–Cr alloy thin films have been deposited using magnetron co-sputtering technique at room temperature. Crystal structure was evaluated using GIXRD. Ni–Cr solid solution upto 40 at% of Cr exhibited fcc solid solution of Cr in Ni and beyond that it exhibited bcc solid solution of Ni in Cr. X-ray diffraction analysis shows formation of (1 1 1) fiber texture in fcc and (2 2 0) fiber texture in bcc Ni–Cr thin films. Electron microscopy in both in-plane and transverse direction of the film surface revealed the presence of columnar microstructure for films having Cr upto 40 at%. Mechanical properties of the films are evaluated using nanoindentation. The modulus values increased with increase of Cr at% till the film is fcc. With further increase in Cr at% the modulus values decreased. Ni–Cr film with 20 at% Ni exhibits reduction in modulus and is correlated to the poor crystallization of the film as reflected in XRD analysis. The Ni–Cr thin film with 80 at% Ni and 20 at% Cr exhibited the most distinct columnar structure with highest electrical resistivity, indentation hardness and elastic modulus.

  12. NEVADA NATIONAL SECURITY SITE (NNSS) DRIVERS ROUTE/SHIPMENT INFORMATION

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (NNSS) DRIVERS ROUTE/SHIPMENT INFORMATION (12/2014 Log No. 2014-229) NOTE: THIS FORM IS TWO (2) PAGES - YOU MUST COMPLETE BOTH PAGES NNSS SHIPMENT NUMBER: CARRIER NAME: TRACTOR NO.: TRAILER NO.: AT ORIGIN AT NNSS Main Gate NNSS OFFICE USE ONLY DEPARTURE DATE: ARRIVAL DATE: DESTINATION AREA: Area 5 DEPARTURE TIME: ARRIVAL TIME: NNSS DEPARTURE TIME: LOCATION: HELD OVER? No Yes REASON: ROUTE INFORMATION REVIEWED BY: ONSITE SHIPMENT (MAP NOT APPLICABLE) DROP YARD; LEAVE THIS FORM WITH SHIPPING

  13. Morphology, deformation, and defect structures of TiCr{sub 2} in Ti-Cr alloys

    SciTech Connect (OSTI)

    Chen, K.C.; Allen, S.M.; Livingston, J.D.

    1992-12-31

    The morphologies and defect structures of TiCr{sub 2} in several Ti-Cr alloys have been examined by optical metallography, x-ray diffraction, and transmission electron microscopy (TEM), in order to explore the room-temperature deformability of the Laves phase TiCr{sub 2}. The morphology of the Laves phase was found to be dependent upon alloy composition and annealing temperature. Samples deformed by compression have also been studied using TEM. Comparisons of microstructures before and after deformation suggest an increase in twin, stacking fault, and dislocation density within the Laves phase, indicating some but not extensive room-temperature deformability.

  14. Kinetics and Mechanism of the Hydrogenation of CpCr(CO)3/[CpCr(CO)3]2 Equilibrium to CpCr(CO)3H

    SciTech Connect (OSTI)

    Norton, Jack R.; Spataru, Tudor; Camaioni, Donald M.; Lee, Suh-Jane; Li, Gang; Choi, Jongwook; Franz, James A.

    2014-05-26

    The kinetics of the hydrogenation of 2 CpCr(CO)3/[CpCr(CO)3]2 to CpCr(CO)3H has been investigated. The reaction is second-order in Cr and first-order in H2, with a rate constant of 45 M 2s 1 at 25 C in benzene. DFT calculations rule out an H2 complex as an intermediate, and suggest (a) end-on approach of H2 to one Cr of [CpCr(CO)3]2 as the Cr-Cr bond undergoes heterolytic cleavage, (b) heterolytic cleavage of the coordinated H2 between O and Cr, and (c) isomerization of the resulting O-protonated CpCr(CO)2(COH) to CpCr(CO)3H. The work at Pacific Northwest National Laboratory (PNNL) was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences; Battelle operates PNNL for DOE.

  15. Growth of Cr-Nitrides on Commercial Ni-Cr and Fe-Cr Base Alloys to Protect PEMFC Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P; Wang, Heli; Yang, Bing; Turner, John; Bordignon, Melanie; Molins, Regine; Abdelhamid, Mahmoud; Lipp, Ludwig; Walker, Larry R

    2007-01-01

    Nitridation of Cr-bearing alloys can yield low interfacial contact resistance (ICR), electrically- conductive and corrosion-resistant CrN or Cr2N base surfaces of interest for a range of electrochemical devices, including fuel cells, batteries, and sensors. This paper presents results of exploratory studies of the nitridation of two high Cr (30-35 wt%) commercially available Ni-Cr alloys and a ferritic high Cr (29 wt.%) stainless steel for proton exchange membrane fuel cell (PEMFC) bipolar plates. A high degree of corrosion resistance in sulfuric acid solutions designed to simulate bipolar plate conditions and low ICR values were achieved via nitridation. Oxygen impurities in the nitriding environment were observed to play a significant role in the nitrided surface structures that formed, with detrimental effects for the Ni-Cr base alloys, but beneficial effects for the stainless steel alloy. Results of single-cell fuel cell testing are also presented.

  16. Hazard Evaluation for 244-CR Vault

    SciTech Connect (OSTI)

    GRAMS, W.H.

    1999-08-19

    This document presents the results of a hazards identification and evaluation performed on the 244-CR Vault to close a USQ (USQ No.TF-98-0785, Potential Inadequacy in Authorization Basis (PIAB): To Evaluate Miscellaneous Facilities Listed In HNF-2503 And Not Addressed In The TWRS Authorization Basis) that was generated as part of an evaluation of inactive TWRS facilities.

  17. Attachment I CHPRC CONDITION REPORT FORM Status: Analysis CR NUMBER: CR-2011I 2037

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CHPRC CONDITION REPORT FORM Status: Analysis CR NUMBER: CR-2011I 2037 Issue Identification and Processing Initiator: Initiating IDetifed Bannister, Roland J Document: 6/23/2011d Title of Issue: Extent of Condition review for S3000 containers Description of Issue: Extent of Condition Review arose from the Causal Analysis regarding the breached drum found in 2404WB on April 26, 2011. The scope of the review was to assess all other known S3000 (homogenous solids) waste streams to identify

  18. Dual-phase Cr-Ta alloys for structural applications

    DOE Patents [OSTI]

    Liu, Chain T.; Brady, Michael P.; Zhu, Jiahong; Tortorelli, Peter F.

    2001-01-01

    Dual phase alloys of chromium containing 2 to 11 atomic percent tantalum with minor amounts of Mo, Cr, Ti, Y, La, Cr, Si and Ge are disclosed. These alloys contain two phases including Laves phase and Cr-rich solid solution in either eutectic structures or dispersed Laves phase particles in the Cr-rich solid solution matrix. The alloys have superior mechanical properties at high temperature and good oxidation resistance when heated to above 1000.degree. C. in air.

  19. Fundamental Drivers of the Cost and Price of Operating Reserves

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fundamental Drivers of the Cost and Price of Operating Reserves Marissa Hummon, Paul Denholm, Jennie Jorgenson, and David Palchak National Renewable Energy Laboratory Brendan Kirby Consultant Ookie Ma U.S. Department of Energy Technical Report NREL/TP-6A20-58491 July 2013 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National

  20. Projecting Fatalities in Crashes Involving Older Drivers, 2000-2025

    SciTech Connect (OSTI)

    Hu, P.S.

    2001-03-23

    As part of this research effort, we developed a new methodology for projecting elderly traffic crash fatalities. This methodology separates exposure to crashes from crash risk per se, and further divides exposure into two components, the number of miles driven and the likelihood of being a driver. This component structure permits conceptually different determinants of traffic fatalities to be projected separately and has thorough motivation in behavioral theory. It also permits finer targeting of particular aspects of projections that need improvement and closer linking of projections to possible policy instruments for influencing them.

  1. Unemployed Truck Driver Trains for New Career in Weatherization |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Maya Payne Smart Former Writer for Energy Empowers, EERE What does this mean for me? Workers across the country are being retrained for careers in the new clean energy economy. Tyrone Bailey had been out of work for 14 months when an unemployment office staffer told him about a home-weatherization training program offered by the state of New Jersey. The former truck driver and construction worker jumped at the opportunity to acquire new skills and began training January

  2. What Use Patterns Were Observed for PEV Drivers at Publicly Accessible AC Level 2 EVSE Sites?

    SciTech Connect (OSTI)

    Francfort, James Edward

    2015-12-01

    The EV Project deployed over 4,000 ACL2 EVSE for drivers to charge their plug-in electric vehicle (PEV) when away-from-home. The vast majority of these EVSE stations were installed to be available to all PEV drivers at publicly accessible locations. Some were also deployed for use at workplaces and fleets. This paper examines only the use patterns of PEV drivers using the EVSE intended to be publicly accessible.

  3. Cr-doped scandium borate laser

    DOE Patents [OSTI]

    Chai, Bruce H.; Lai, Shui T.; Long, Margaret N.

    1989-01-01

    A broadly wavelength-tunable laser is provided which comprises as the laser medium a single crystal of MBO.sub.3 :Cr.sup.3+, where M is selected from the group of Sc, In and Lu. The laser may be operated over a broad temperature range from cryogenic temperatures to elevated temperatures. Emission is in a spectral range from red to infrared, and the laser is useful in the fields of defense, communications, isotope separation, photochemistry, etc.

  4. Drivers` activities and information needs in an automated highway system. Working paper, August 1995-May 1996

    SciTech Connect (OSTI)

    Levitan, L.; Bloomfield, J.

    1996-10-01

    In most visions of the AHS--including that of the National Automated Highway System Consortium--it has been assumed that when a vehicle was under automated control, the driver would be allowed to engage in any of a variety of activities not related to driving (e.g, working, reading, sleeping). The objective of the first study reported here--one of the noncommuter studies--was to determine what drivers do when traveling under automated control, and whether the age of and/gender or the driver and/or the intrastring gap have an influence on those activities. One the objectives of the commuter experiment--of relevance for this report--was to determine whether what drivers do when traveling under automated control changes as a function of experience with the AHS (i.e., across trials). As conceptualization of the AHS proceeds, the details of the interface between the driver and the in-vehicle system will become more important. One part of that interface will be information supplied by the AHS to the driver, perhaps about such things as traffic conditions ahead predicted trip time to the driver`s selected exit, and so on. To maximize the utility of that information, it is important to determine what it is that drivers would like to know when traveling under automated control. The objective of the third study reported here--the second of the five noncommuter experiments--was to provide a first investigation of that issue.

  5. Philips Light Sources & Electronics is Developing an Efficient, Smaller, Cost-Effective Family of LED Drivers

    Broader source: Energy.gov [DOE]

    With the help of DOE funding, Philips Light Sources & Electronics is developing a new family of LED drivers that are more efficient and cost-effective as well as smaller in size than currently available drivers. The new drivers are switch-mode power supplies that are similar to today's drivers, but with an improved design. In addition, they have a different topology—boost plus LLC—for wattages of 40W and above, but they retain the commonly used flyback topology at lower wattages.

  6. Aiming to Green NASCAR's Future: Q&A with Driver Leilani Munter...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Free Girl Leilani Mnter is not your usual NASCAR driver. An avid environmentalist, Mnter's goal is to spread an energy efficiency and green message to NASCAR's 75 ...

  7. UWB multi-burst transmit driver for averaging receivers

    DOE Patents [OSTI]

    Dallum, Gregory E

    2012-11-20

    A multi-burst transmitter for ultra-wideband (UWB) communication systems generates a sequence of precisely spaced RF bursts from a single trigger event. There are two oscillators in the transmitter circuit, a gated burst rate oscillator and a gated RF burst or RF power output oscillator. The burst rate oscillator produces a relatively low frequency, i.e., MHz, square wave output for a selected transmit cycle, and drives the RF burst oscillator, which produces RF bursts of much higher frequency, i.e., GHz, during the transmit cycle. The frequency of the burst rate oscillator sets the spacing of the RF burst packets. The first oscillator output passes through a bias driver to the second oscillator. The bias driver conditions, e.g., level shifts, the signal from the first oscillator for input into the second oscillator, and also controls the length of each RF burst. A trigger pulse actuates a timing circuit, formed of a flip-flop and associated reset time delay circuit, that controls the operation of the first oscillator, i.e., how long it oscillates (which defines the transmit cycle).

  8. Temporal evolution of ion energy distribution functions and ion charge states of Cr and Cr-Al pulsed arc plasmas

    SciTech Connect (OSTI)

    Tanaka, Koichi; Anders, André

    2015-11-15

    To study the temporal evolution of ion energy distribution functions, charge-state-resolved ion energy distribution functions of pulsed arc plasmas from Cr and Cr-Al cathodes were recorded with high time resolution by using direct data acquisition from a combined energy and mass analyzer. The authors find increases in intensities of singly charged ions, which is evidence that charge exchange reactions took place in both Cr and Cr-Al systems. In Cr-Al plasmas, the distributions of high-charge-state ions exhibit high energy tails 50 μs after discharge ignition, but no such tails were observed at 500 μs. The energy ratios of ions of different charge states at the beginning of the pulse, when less neutral atoms were in the space in front of the cathode, suggest that ions are accelerated by an electric field. The situation is not so clear after 50 μs due to particle collisions. The initial mean ion charge state of Cr was about the same in Cr and in Cr-Al plasmas, but it decreased more rapidly in Cr-Al plasmas compared to the decay in Cr plasma. The faster decay of the mean ion charge state and ion energy caused by the addition of Al into a pure Cr cathode suggests that the mean ion charge state is determined not only by ionization processes at the cathode spot but also by inelastic collision between different elements.

  9. Study of CSR Effects in the Jefferson Laboratory FEL Driver

    SciTech Connect (OSTI)

    Hall, C. C.; Biedron, S.; Burleson, Theodore A.; Milton, Stephen V.; Morin, Auralee L.; Benson, Stephen V.; Douglas, David R.; Evtushenko, Pavel E.; Hannon, Fay E.; Li, Rui; Tennant, Christopher D.; Zhang, Shukui; Carlsten, Bruce E.; Lewellen, John W.

    2013-08-01

    In a recent experiment conducted on the Jefferson Laboratory IR FEL driver the effects of Coherent Synchrotron Radiation (CSR) on beam quality were studied. The primary goal of this work was to explore CSR output and effect on the beam with variation of the bunch compression in the IR chicane. This experiment also provides a valuable opportunity to benchmark existing CSR models in a system that may not be fully represented by a 1-D CSR model. Here we present results from this experiment and compare to initial simulations of CSR in the magnetic compression chicane of the machine. Finally, we touch upon the possibility for CSR induced microbunching gain in the magnetic compression chicane, and show that parameters in the machine are such that it should be thoroughly damped.

  10. Cr segregation at the FeCr surface and the origin of corrosion resistance in ferritic steels

    SciTech Connect (OSTI)

    De Caro, M S; Morse, B; Egiebor, N; Farmer, J; Caro, A

    2008-11-22

    Structural materials in Gen-IV nuclear reactors will face severe conditions of high operating temperatures, high neutron flux exposure, and corrosive environment. Radiation effects and corrosion and chemical compatibility issues are factors that will limit the materials lifetime. Low-chromium (9-12 Cr wt.%) ferritic martensitic (F/M) steels are being considered as possible candidates because they offer good swelling resistance and good mechanical properties under extreme conditions of radiation dose and irradiation temperature. The surface chemistry of FeCr alloys, responsible for the corrosion properties, is complex. It exists today a controversy between equilibrium thermodynamic calculations, which suggest Cr depletion at the surface driven by the higher surface energy of Cr, and experimental data which suggest the oxidation process occurs in two stages, first forming a Fe-rich oxide, followed by a duplex oxide layer, and ending with a Cr-rich oxide. Moreover, it has been shown experimentally that corrosion resistance of F/M steels depends significantly on Cr content, increasing with increasing Cr content and with a threshold around 10% Cr, below which, the alloy behaves as pure Fe. In an attempt to rationalize these two contradicting observations and to understand the physical mechanism behind corrosion resistance in these materials we perform atomistic simulations using our FeCr empirical potential and analyze Cr equilibrium distributions at different compositions and temperatures in single and polycrystalline samples. We analyze the controversy in terms of thermodynamic and kinetic considerations.

  11. Mechanical properties of irradiated 9Cr-2WVTa steel

    SciTech Connect (OSTI)

    Klueh, R.L.; Alexander, D.J.; Rieth, M.

    1998-09-01

    An Fe-9Cr-2W-0.25V-0.07Ta-0.1C (9Cr-2WVTa) steel has excellent strength and impact toughness before and after irradiation in the Fast Flux Test Facility and the High Flux Reactor (HFR). The ductile-brittle transition temperature (DBTT) increased only 32 C after 28 dpa at 365 C in FFTF, compared to a shift of {approx}60 C for a 9Cr-2WV steel--the same as the 9Cr-2WVTa steel but without tantalum. This difference occurred despite the two steels having similar tensile but without tantalum. This difference occurred despite the two steels having similar tensile properties before and after irradiation. The 9Cr-2WVTa steel has a smaller prior-austenite grain size, but otherwise microstructures are similar before irradiation and show similar changes during irradiation. The irradiation behavior of the 9Cr-2WVTa steel differs from the 9Cr-2WV steel and other similar steels in two ways: (1) the shift in DBTT of the 9Cr-2WVTa steel irradiated in FFTF does not saturate with fluence by {approx}28 dpa, whereas for the 9Cr-2WV steel and most similar steels, saturation occurs at <10 dpa, and (2) the shift in DBTT for 9Cr-2WVTa steel irradiated in FFTF and HFR increased with irradiation temperature, whereas it decreased for the 9Cr-2WV steel, as it does for most similar steels. The improved properties of the 9Cr-2WVTa steel and the differences with other steels were attributed to tantalum in solution.

  12. Development of Surface Complexation Models of Cr(VI) Adsorption...

    Office of Scientific and Technical Information (OSTI)

    Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, ... into aquifers and shallow sediments and soils via many anthropogenic activities. ...

  13. SF6432-CR (02-01-13) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Government site to perform work shall have Control : SF 6432-CR Title: Standard Terms & Conditions for Cost Reimbursement Owner: Procurement Policy & Quality Dept Release...

  14. SF6432-CR (02-01-12) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... prior to any attempts to enter a government site as shown ... premises are subject to search. (e) Contractor will ... SF 6432-CR Title: Standard Terms & Conditions for Cost ...

  15. SF6432-CR (02-01-13) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... who will enter a Government site to perform work shall have Control : SF 6432-CR Title: Standard Terms & Conditions ... premises are subject to search. (e) Contractor will ...

  16. SF6432-CR (02-01-13) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    labor are authorized as direct charges Control : SF 6432-CR Title: Standard Terms & Conditions for Cost Reimbursement Owner: Procurement Policy Department Release Date: 11...

  17. SF6432-CR (02-01-12) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as direct charges to this contract Control : SF 6432-CR Title: Standard Terms & Conditions for Cost Reimbursement Owner: Procurement Policy & Quality Dept Release Date:...

  18. SF6432-CR (02-01-13) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by Part 931 of the DEAR by a Sandia audit. Control : SF 6432-CR Title: Standard Terms & Conditions for Cost Reimbursement Owner: Procurement Policy Department Release Date: 04...

  19. Spin-driven ordering of Cr in the equiatomic high entropy alloy NiFeCrCo

    SciTech Connect (OSTI)

    Niu, C.; Zaddach, A. J.; Oni, A. A.; Sang, X.; LeBeau, J. M.; Koch, C. C.; Irving, D. L.; Hurt, J. W.

    2015-04-20

    Spin-driven ordering of Cr in an equiatomic fcc NiFeCrCo high entropy alloy (HEA) was predicted by first-principles calculations. Ordering of Cr is driven by the reduction in energy realized by surrounding anti-ferromagnetic Cr with ferromagnetic Ni, Fe, and Co in an alloyed L1{sub 2} structure. The fully Cr-ordered alloyed L1{sub 2} phase was predicted to have a magnetic moment that is 36% of that for the magnetically frustrated random solid solution. Three samples were synthesized by milling or casting/annealing. The cast/annealed sample was found to have a low temperature magnetic moment that is 44% of the moment in the milled sample, which is consistent with theoretical predictions for ordering. Scanning transmission electron microscopy measurements were performed and the presence of ordered nano-domains in cast/annealed samples throughout the equiatomic NiFeCrCo HEA was identified.

  20. Magnetic properties and hyperfine interactions in Cr8, Cr7Cd, and Cr7Ni molecular rings from 19F-NMR

    SciTech Connect (OSTI)

    Bordonali, L; Garlatti, E; Casadei, C M; Furukawa, Y; Lascialfari, A; Carretta, S; Troiani, F; Timco, G; Winpenny, R E; Borsa, F

    2014-04-14

    A detailed experimental investigation of the 19F nuclear magnetic resonance is made on single crystals of the homometallic Cr8 antiferromagnetic molecular ring and heterometallic Cr7Cd and Cr7 Ni rings in the low temperature ground state. Since the F? ion is located midway between neighboring magnetic metal ions in the ring, the 19F-NMR spectra yield information about the local electronic spin density and 19F hyperfine interactions. In Cr8, where the ground state is a singlet with total spin S T = 0, the 19F-NMR spectra at 1.7 K and low external magnetic field display a single narrow line, while when the magnetic field is increased towards the first level crossing field, satellite lines appear in the 19F-NMR spectrum, indicating a progressive increase in the Boltzmann population of the first excited state S T = 1. In the heterometallic rings, Cr7Cd and Cr7 Ni, whose ground state is magnetic with S T = 3/2 and S T = 1/2, respectively, the 19F-NMR spectrum has a complicated structure which depends on the strength and orientation of the magnetic field, due to both isotropic and anisotropic transferred hyperfine interactions and classical dipolar interactions. From the 19F-NMR spectra in single crystals we estimated the transferred hyperfine constants for both the F?-Ni2+ and the F?-Cd2+ bonds. The values of the hyperfine constants compare well to the ones known for F?-Ni2+ in KNiF3 and NiF2 and for F?-Cr3+ in K2NaCrF6. The results are discussed in terms of hybridization of the 2s, 2p orbitals of the F? ion and the d orbitals of the magnetic ion. Finally, we discuss the implications of our results for the electron-spin decoherence.

  1. Characterization of Cr-rich Cr-Sb multilayer films: Syntheses of a new metastable phase using modulated elemental reactants

    SciTech Connect (OSTI)

    Regus, Matthias; Mankovsky, Sergiy; Polesya, Svitlana; Kuhn, Gerhard; Ditto, Jeffrey; Schürmann, Ulrich; Jacquot, Alexandre; Bartholomé, Kilian; Näther, Christian; Winkler, Markus; König, Jan D.; Böttner, Harald; Kienle, Lorenz; Johnson, David C.; Ebert, Hubert; Bensch, Wolfgang

    2015-10-15

    The new metastable compound Cr{sub 1+x}Sb with x up to 0.6 has been prepared via a thin film approach using modulated elemental reactants and investigated by in-situ X-ray reflectivity, X-ray diffraction, differential scanning calorimetry, energy dispersive X-ray analysis as well as transmission electron microscopy and atomic force microscopy. The new Cr-rich antimonide crystallizes in a structure related to the Ni{sub 2}In-type structure, where the crystallographic position (1/3, 2/3, 3/4) is partially occupied by excess Cr. The elemental layers of the pristine material interdiffused significantly before Cr{sub 1+x}Sb crystallized. A change in the activation energy was observed for the diffusion process when crystal growth starts. First-principles electronic structure calculations provide insight into the structural stability, magnetic properties and resistivity of Cr{sub 1+x}Sb. - Graphical abstract: 1 amorphous multilayered film 2 interdiffused amorphous film 3 metastable crystalline phase 4 thermodynamic stable phase (and by-product). - Highlights: • Interdiffusion of amorphous Cr and Sb occurs before crystallization. • Crystallization of a new metastable phase Cr{sub 1.6}Sb in Ni{sub 2}In-type structure. • The new Cr-rich phase shows half-metallic behavior.

  2. Lumileds Develops High-Voltage LED Light Engine with Integrated Driver

    Broader source: Energy.gov [DOE]

    With the help of DOE funding, Lumileds has developed a high-voltage LED light engine with an integrated driver, achieving an efficacy greater than 128 lm/W at a luminous flux greater than 4,100 lm...

  3. Vehicle Technologies Office Merit Review 2014: Look-Ahead Driver Feedback and Powertrain Management

    Broader source: Energy.gov [DOE]

    Presentation given by Eaton at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about look-ahead driver feedback and...

  4. Science Driver Requirements for Seeded Soft X-ray Free Electron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Driver Requirements for Seeded Soft X-ray Free Electron Lasers Wednesday, December 2, 2015 - 2:00pm SLAC, Redtail Hawk Conference Room 108A Speaker: Fulvio Parmigiani,...

  5. Vehicle Technologies Office Merit Review 2015: Gate Driver Optimization for WBG Applications

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about gate driver...

  6. Science Drivers of Particle Physics | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science Drivers of Particle Physics High Energy Physics (HEP) HEP Home About Research Science Drivers of Particle Physics Energy Frontier Intensity Frontier Cosmic Frontier Theoretical and Computational Physics Advanced Technology R&D Accelerator Stewardship Facilities Science Highlights Benefits of HEP Funding Opportunities Advisory Committees Community Resources Contact Information High Energy Physics U.S. Department of Energy SC-25/Germantown Building 1000 Independence Ave., SW

  7. 244-CR Vault Interim Stabilization Project Plan

    SciTech Connect (OSTI)

    PARKMAN, D.B.

    2000-04-25

    The 244-CR Vault is a two-level, multi-cell structure of reinforced concrete constructed below grade. The lower cell contains four individual compartments, each containing a steel process storage tank and equipped with a concrete sump. The upper cell contains the piping and support equipment, and has two compartments for each of the tanks. The ''pump pit'' is accessed by the removal of concrete cover blocks, while the smaller ''riser pit'' is accessed by steel cover plates. The facility most recently was used as a double-contained receiver tank (DCRT). A DCRT is a type of waste transfer tank that together with its related equipment constitutes a short-term storage area for liquid waste and has a pump pit for waste transfer operations. This vault most recently was used for short-term storage and waste routing for saltwell liquid pumped from the 241-C Tank Farm in the 200 East Area. Waste transfer lines are connected inside the pump pit by a jumper installed between connecting nozzles. An active ventilation system is in operation at the 244-CR vault. Ventilation supply air enters the upper vault section through an inlet header with some leakage through the spaces between the cell cover blocks. The upper and lower vaults are connected by exhauster ports, which allow airflow between the two sections. Normal flow moves air from the upper cell to the lower cell where it is removed and routed into a filter plenum; there the air is treated by a bank of four prefilters and two banks of high-efficiency particulate air (HEPA) filters (each containing four HEPAs). The air is exhausted to the atmosphere through the 296-C-05 Stack. The stack is equipped with a record sampler and continuous air monitor. Two fans (each rated at 4,200 cubic feet per minute) installed downstream of the filtration system provide the motive force for exhausting the vaults and the tanks. As an active system, it is operated continuously with only one of the two fans required to operate at a time. A

  8. Interlayer coupling in Fe/Cr/Gd multilayer structures

    SciTech Connect (OSTI)

    Drovosekov, A. B. Kreines, N. M.; Savitsky, A. O.; Kravtsov, E. A.; Blagodatkov, D. V.; Ryabukhina, M. V.; Milyaev, M. A.; Ustinov, V. V.; Pashaev, E. M.; Subbotin, I. A.; Prutskov, G. V.

    2015-06-15

    The effect of the chromium layer thickness on the magnetic state of an [Fe/Cr/Gd/Cr]{sub n} multilayer structure is studied. A series of Fe/Cr/Gd structures with Cr spacer thicknesses of 4–30 Å is studied by SQUID magnetometry and ferromagnetic resonance in the temperature range 4.2–300 K. The obtained experimental results are described in terms of an effective field model, which takes into account a biquadratic contribution to the interlayer coupling energy and a nonuniform magnetization distribution inside the gadolinium layer (which was detected earlier). Depending on the magnetic field and temperature, the following types of magnetic ordering are identified at various chromium layer thicknesses: ferromagnetic, antiferromagnetic, and canted ordering. A comparison of the experimental and calculated curves allowed us to determine the dependence of the bilinear (J{sub 1}) and biquadratic (J{sub 2}) exchange constants on chromium layer thickness t{sub Cr}. Weak oscillations at a period of about 18 Å are detected in the J{sub 1}(t{sub Cr}) dependence in the range 8–30 Å. The interlayer coupling oscillations in the system under study are assumed to be related to the RKKY exchange interaction mechanism via the conduction electrons of Cr.

  9. Effects of Cr and Ni on Interdiffusion and Reaction between U and Fe-Cr-Ni Alloys

    SciTech Connect (OSTI)

    K. Huang; Y. Park; L. Zhou; K.R. Coffey; Y.H. Sohn; B.H. Sencer; J. R. Kennedy

    2014-08-01

    Metallic U-alloy fuel cladded in steel has been examined for high temperature fast reactor technology wherein the fuel cladding chemical interaction is a challenge that requires a fundamental and quantitative understanding. In order to study the fundamental diffusional interactions between U with Fe and the alloying effect of Cr and Ni, solid-to-solid diffusion couples were assembled between pure U and Fe, Fe–15 wt.%Cr or Fe–15 wt.%Cr–15 wt.%Ni alloy, and annealed at high temperature ranging from 580 to 700 °C. The microstructures and concentration profiles that developed from the diffusion anneal were examined by scanning electron microscopy, and X-ray energy dispersive spectroscopy (XEDS), respectively. Thick U6Fe and thin UFe2 phases were observed to develop with solubilities: up to 2.5 at.% Ni in U6(Fe,Ni), up to 20 at.%Cr in U(Fe, Cr)2, and up to 7 at.%Cr and 14 at.% Ni in U(Fe, Cr, Ni)2. The interdiffusion and reactions in the U vs. Fe and U vs. Fe–Cr–Ni exhibited a similar temperature dependence, while the U vs. Fe–Cr diffusion couples, without the presence of Ni, yielded greater activation energy for the growth of intermetallic phases – lower growth rate at lower temperature but higher growth rate at higher temperature.

  10. Large Synoptic Survey Telescope: From Science Drivers to Reference Design

    SciTech Connect (OSTI)

    Ivezic, Z.; Axelrod, T.; Brandt, W.N.; Burke, D.L.; Claver, C.F.; Connolly, A.; Cook, K.H.; Gee, P.; Gilmore, D.K.; Jacoby, S.H.; Jones, R.L.; Kahn, S.M.; Kantor, J.P.; Krabbendam, V.; Lupton, R.H.; Monet, D.G.; Pinto, P.A.; Saha, A.; Schalk, T.L.; Schneider, D.P.; Strauss, Michael A.; /Washington U., Seattle, Astron. Dept. /LSST Corp. /Penn State U., Astron. Astrophys. /KIPAC, Menlo Park /NOAO, Tucson /LLNL, Livermore /UC, Davis /Princeton U., Astrophys. Sci. Dept. /Naval Observ., Flagstaff /Arizona U., Astron. Dept. - Steward Observ. /UC, Santa Cruz /Harvard U. /Johns Hopkins U. /Illinois U., Urbana

    2011-10-14

    LSST science drivers led to these choices of system parameters.

  11. Audit of Controls Over the ADP Support Services Contract, CR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Audit Report Number: CR-B-97-04 SUMMARY The Federal Acquisition Regulation requires the Department of Energy ... and best practices in other Federal agencies and the private sector. ...

  12. TI--CR--AL--O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F.; Schmid, Anthony P.

    2000-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  13. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  14. Phase stability and elastic properties of Cr-V alloys

    SciTech Connect (OSTI)

    Gao, M. C.; Suzuki, Y.; Schweiger, H.; Do?an, .N.; Hawk, J.; Widom M.

    2013-02-20

    V is the only element in the periodic table that forms a complete solid solution with Cr and thus is particularly important in alloying strategy to ductilize Cr. This study combines first-principles density functional theory calculations and experiments to investigate the phase stability and elastic properties of CrV binary alloys. The cluster expansion study reveals the formation of various ordered compounds at low temperatures that were not previously known. These compounds become unstable due to the configurational entropy of bcc solid solution as the temperature is increased. The elastic constants of ordered and disordered compounds are calculated at both T = 0 K and finite temperatures. The overall trends in elastic properties are in agreement with measurements using the resonant ultrasound spectroscopy method. The calculations predict that addition of V to Cr decreases both the bulk modulus and the shear modulus, and enhances the Poissons ratio, in agreement with experiments. Decrease in the bulk modulus is correlated to decrease in the valence electron density and increase in the lattice constant. An enhanced Poissons ratio for bcc CrV alloys (compared to pure Cr) is associated with an increased density of states at the Fermi level. Furthermore, the difference charge density in the bonding region in the (110) slip plane is highest for pure Cr and decreases gradually as V is added. The present calculation also predicts a negative Cauchy pressure for pure Cr, and it becomes positive upon alloying with V. The intrinsic ductilizing effect from V may contribute, at least partially, to the experimentally observed ductilizing phenomenon in the literature.

  15. Enhanced magnetization at the Cr/MgO(001) interface

    SciTech Connect (OSTI)

    Leroy, M.-A.; Bataille, A. M. Ott, F.; Wang, Q.; Fitzsimmons, M. R.; Bertran, F.; Le Fèvre, P.; Taleb-Ibrahimi, A.; Vlad, A.; Coati, A.; Garreau, Y.; Hauet, T.; Andrieu, S.; Gatel, C.

    2015-12-21

    We report on the magnetization at the Cr/MgO interface, which we studied through two complementary techniques: angle-resolved photoemission spectroscopy and polarized neutron reflectivity. We experimentally observe an enhanced interface magnetization at the interface, yet with values much smaller than the ones reported so far by theoretical and experimental studies on Cr(001) surfaces. Our findings cast some doubts on the interpretations on previous works and could be useful in antiferromagnetic spin torque studies.

  16. Effect of driver impedance on dense plasma focus Z-pinch neutron yield

    SciTech Connect (OSTI)

    Sears, Jason E-mail: schmidt36@llnl.gov; Link, Anthony E-mail: schmidt36@llnl.gov; Schmidt, Andrea E-mail: schmidt36@llnl.gov; Welch, Dale

    2014-12-15

    The Z-pinch phase of a dense plasma focus (DPF) heats the plasma by rapid compression and accelerates ions across its intense electric fields, producing neutrons through both thermonuclear and beam-target fusion. Driver characteristics have empirically been shown to affect performance, as measured by neutron yield per unit of stored energy. We are exploring the effect of driver characteristics on DPF performance using particle-in-cell (PIC) simulations of a kJ scale DPF. In this work, our PIC simulations are fluid for the run-down phase and transition to fully kinetic for the pinch phase, capturing kinetic instabilities, anomalous resistivity, and beam formation during the pinch. The anode-cathode boundary is driven by a circuit model of the capacitive driver, including system inductance, the load of the railgap switches, the guard resistors, and the coaxial transmission line parameters. It is known that the driver impedance plays an important role in the neutron yield: first, it sets the peak current achieved at pinch time; and second, it affects how much current continues to flow through the pinch when the pinch inductance and resistance suddenly increase. Here we show from fully kinetic simulations how total neutron yield depends on the impedance of the driver and the distributed parameters of the transmission circuit. Direct comparisons between the experiment and simulations enhance our understanding of these plasmas and provide predictive design capability for neutron source applications.

  17. Influence of Cr on the nanoclusters formation and superferromagnetic behavior of Fe-Cr-Nb-B glassy alloys

    SciTech Connect (OSTI)

    Chiriac, H.; Whitmore, L.; Grigoras, M.; Ababei, G.; Stoian, G.; Lupu, N.

    2015-05-07

    High resolution imaging and electron diffraction confirm that in the as-quenched state the structure of Fe{sub 79.7−x}Cr{sub x}Nb{sub 0.3}B{sub 20} (x = 11–13 at. %) melt-spun ribbons is completely amorphous, independent of the Cr content. Energy-dispersive X-ray spectroscopy mapping emphasizes clearly the presence of Fe and Cr clusters varying from approximately 1 to 2–3 nm in size with the increase of Cr content from 11 to 13 at. %. The Fe and Cr atoms segregate the atomic scale to form nanometer sized clusters, influencing strongly the macroscopic magnetic behavior. The Curie temperature of the system, T{sub C}{sup system}, confirmed by the magnetic susceptibility versus temperature measurements, gives the strength of the magnetic interactions between clusters. The inter-cluster interactions are much stronger for lower contents of Cr, the microstructure is less uniform, and T{sub C}{sup system} increases from 290 K for 13 at. % Cr to 330 K for 11.5 at. % Cr. The whole system transforms to a ferromagnetic state through interactions between the clusters. Zero-field cooling and field cooling curves confirm the cluster behavior with a blocking temperature, T{sub b}, of about 250 K. Above T{sub b}, the ribbons behave as a superferromagnetic system, whilst below the blocking temperature a classical ferromagnetic behavior is observed.

  18. Grid Parity for Residential Photovoltaics in the United States: Key Drivers and Sensitivities; Preprint

    SciTech Connect (OSTI)

    Ong, S.; Denholm, P.; Clark, N.

    2012-08-01

    In this report, we analyze PV break-even costs for U.S. residential customers. We evaluate some key drivers of grid parity both regionally and over time. We also examine the impact of moving from flat to time-of-use (TOU) rates, and we evaluate individual components of the break-even cost, including effect of rate structure and various incentives. Finally, we examine how PV markets might evolve on a regional basis considering the sensitivity of the break-even cost to four major drivers: technical performance, financing parameters, electricity prices and rates, and policies. We find that electricity price rather than technical parameters are in general the key drivers of the break-even cost of PV. Additionally, this analysis provides insight about the potential viability of PV markets.

  19. Drivers of U.S. Household Energy Consumption, 1980-2009

    U.S. Energy Information Administration (EIA) Indexed Site

    Drivers of U.S. Household Energy Consumption, 1980-2009 February 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Drivers of U.S. Household Energy Consumption, 1980-2009 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any

  20. Summer gasoline price forecast slightly higher, but drivers still pay less than last year

    U.S. Energy Information Administration (EIA) Indexed Site

    Summer gasoline price forecast slightly higher, but drivers still pay less than last year Rising crude oil prices are likely to be passed on to consumers at the pump, but U.S. drivers are still expected to pay the lowest summer gasoline prices since 2004, and for all of 2016 the average household will spend $900 less on gasoline than it did two years ago." In its new monthly forecast, the U.S. Energy Information Administration said the retail price for regular grade gasoline will average

  1. Chromium Isotope Fractionation During Reduction of Cr(VI) Under Saturated Flow Conditions

    SciTech Connect (OSTI)

    Jamieson-Hanes, Julia H.; Gibson, Blair D.; Lindsay, Matthew B.J.; Kim, Yeongkyoo; Ptacek, Carol J.; Blowes, David W.

    2012-10-25

    Chromium isotopes are potentially useful indicators of Cr(VI) reduction reactions in groundwater flow systems; however, the influence of transport on Cr isotope fractionation has not been fully examined. Laboratory batch and column experiments were conducted to evaluate isotopic fractionation of Cr during Cr(VI) reduction under both static and controlled flow conditions. Organic carbon was used to reduce Cr(VI) in simulated groundwater containing 20 mg L{sup -1} Cr(VI) in both batch and column experiments. Isotope measurements were performed on dissolved Cr on samples from the batch experiments, and on effluent and profile samples from the column experiment. Analysis of the residual solid-phase materials by scanning electron microscopy (SEM) and by X-ray absorption near edge structure (XANES) spectroscopy confirmed association of Cr(III) with organic carbon in the column solids. Decreases in dissolved Cr(VI) concentrations were coupled with increases in {delta}{sup 53}Cr, indicating that Cr isotope enrichment occurred during reduction of Cr(VI). The {delta}{sup 53}Cr data from the column experiment was fit by linear regression yielding a fractionation factor ({alpha}) of 0.9979, whereas the batch experiments exhibited Rayleigh-type isotope fractionation ({alpha} = 0.9965). The linear characteristic of the column {delta}{sup 53}Cr data may reflect the contribution of transport on Cr isotope fractionation.

  2. Surface structure of ?-Cr2O3(0001) after activated oxygen exposure

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Chamberlin, Sara E.; Chambers, Scott A.

    2013-09-13

    The surface structure of a-Cr2O3(0001) before and after exposure to activated oxygen from an ECR plasma source was investigated by x-ray photoelectron spectroscopy (XPS) and x-ray photoelectron diffraction (XPD). Epitaxial Cr2O3(0001) thin films were deposited on Al2O3(0001) substrates by oxygen-plasma-assisted molecular beam epitaxy (OPA-MBE). When cooled or annealed in vacuum, strong evidence for a Cr-Cr-O3- termination was obtained by comparing the Cr3+ XPD azimuthal scan to single scattering simulations. However, after plasma exposure, a high binding energy feature was observed in the Cr 2p XPS spectrum that possesses an ordered structure distinct from the underlying Cr3+ of Cr2O3, which remains Cr-Cr-O3-like. Investigation of this new surface structure with simulations of various candidate structures tentatively rules out CrO2-like configurations. The high binding energy feature likely arises from a higher oxidation state of Cr. One possibility is the oxidation of the surface layer of Cr to Cr6- with a double chromyl structure (O=Cr=O).

  3. Gamma-ray decay of levels in /sup 53/Cr

    SciTech Connect (OSTI)

    Dickens, J.K.; Larson, D.C.

    1987-11-01

    Gamma-ray decay of levels in the stable isotope /sup 53/Cr has been studied using /sup 53/Cr(n,n'..gamma..) reactions for incident neutron energies between threshold and 10 MeV. Of the 65 gamma rays or gamma-ray groups observed for neutron interactions with /sup 53/Cr, 50 have been placed or tentatively placed among 34 levels in /sup 53/Cr up to an excitation energy of 4.36 MeV. Deduced branching ratios are in reasonable agreement with previous measurements except for decay of the E/sub x/ = 1537-keV level. For the decay of the E/sub x/ = 1537-keV level we are unable to explain variations in the branching ratios of the transition gamma rays as a function of incident neutron energy within the framework of the presently known level structure of /sup 53/Cr and suggest the possibility of a second energy level at E/sub x/ = 1537 keV. 59 refs., 13 figs., 2 tabs.

  4. Room-temperature ferromagnetism in Cr-doped Si achieved by controlling atomic structure, Cr concentration, and carrier densities: A first-principles study

    SciTech Connect (OSTI)

    Wei, Xin-Yuan; Yang, Zhong-Qin; Zhu, Yan; Li, Yun

    2015-04-28

    By using first-principles calculations, we investigated how to achieve a strong ferromagnetism in Cr-doped Si by controlling the atomic structure and Cr concentration as well as carrier densities. We found that the configuration in which the Cr atom occupies the tetrahedral interstitial site can exist stably and the Cr atom has a large magnetic moment. Using this doping configuration, room-temperature ferromagnetism can be achieved in both n-type and p-type Si by tuning Cr concentration and carrier densities. The results indicate that the carrier density plays a crucial role in realizing strong ferromagnetism in diluted magnetic semiconductors.

  5. Grain boundary depletion and migration during selective oxidation of Cr in a Ni-5Cr binary alloy exposed to high-temperature hydrogenated water

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

    2014-10-01

    High-resolution microscopy of a high-purity Ni-5Cr alloy exposed to 360C hydrogenated water reveals intergranular selective oxidation of Cr accompanied by local Cr depletion and diffusion-induced grain boundary migration (DIGM). The corrosion-product oxide consists of a porous, interconnected network of Cr2O3 platelets with no further O ingress into the metal ahead. Extensive grain boundary depletion of Cr (to <0.05at.%) is observed typically 20100 nm wide as a result of DIGM and reaching depths of many micrometers beyond the oxidation front.

  6. Importance of Doping and Frustration in Itinerant Fe-doped Cr2Al

    SciTech Connect (OSTI)

    Susner, Michael A; Parker, David S; Safa-Sefat, Athena

    2015-01-01

    We have performed an experimental and theoretical study comparing the effects of Fe-doping of Cr2Al, an antiferromagnet with a N el temperature of 670 K, with known results on Fe-doping of antiferromagnetic bcc Cr. (Cr1-xFex)2Al materials are found to exhibit a rapid suppression of antiferromagnetic order with the presence of Fe, decreasing TN to 170 K for x=0.10. Antiferromagnetic behavior disappears entirely at x 0.125 after which point increasing paramagnetic behavior is exhibited. This is unlike the effects of Fe doping of bcc antiferromagnetic Cr, in which TN gradually decreases followed by the appearance of a ferromagnetic state. Theoretical calculations explain that the Cr2Al-Fe suppression of magnetic order originates from two effects: the first is band narrowing caused by doping of additional electrons from Fe substitution that weakens itinerant magnetism; the second is magnetic frustration of the Cr itinerant moments in Fe-substituted Cr2Al. In pure-phase Cr2Al, the Cr moments have an antiparallel alignment; however, these are destroyed through Fe substitution and the preference of Fe for parallel alignment with Cr. This is unlike bulk Fe-doped Cr alloys in which the Fe anti-aligns with the Cr atoms, and speaks to the importance of the Al atoms in the magnetic structure of Cr2Al and Fe-doped Cr2Al.

  7. Importance of Doping and Frustration in Itinerant Fe-doped Cr2Al

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Susner, Michael A; Parker, David S; Safa-Sefat, Athena

    2015-01-01

    We have performed an experimental and theoretical study comparing the effects of Fe-doping of Cr2Al, an antiferromagnet with a N el temperature of 670 K, with known results on Fe-doping of antiferromagnetic bcc Cr. (Cr1-xFex)2Al materials are found to exhibit a rapid suppression of antiferromagnetic order with the presence of Fe, decreasing TN to 170 K for x=0.10. Antiferromagnetic behavior disappears entirely at x 0.125 after which point increasing paramagnetic behavior is exhibited. This is unlike the effects of Fe doping of bcc antiferromagnetic Cr, in which TN gradually decreases followed by the appearance of a ferromagnetic state. Theoretical calculationsmore » explain that the Cr2Al-Fe suppression of magnetic order originates from two effects: the first is band narrowing caused by doping of additional electrons from Fe substitution that weakens itinerant magnetism; the second is magnetic frustration of the Cr itinerant moments in Fe-substituted Cr2Al. In pure-phase Cr2Al, the Cr moments have an antiparallel alignment; however, these are destroyed through Fe substitution and the preference of Fe for parallel alignment with Cr. This is unlike bulk Fe-doped Cr alloys in which the Fe anti-aligns with the Cr atoms, and speaks to the importance of the Al atoms in the magnetic structure of Cr2Al and Fe-doped Cr2Al.« less

  8. Metastable bcc phase formation in the Nb-Cr system

    SciTech Connect (OSTI)

    Thoma, D.J.; Schwarz, R.B.; Perepezko, J.H.; Plantz, D.H.

    1993-08-01

    Extended metastable bcc solid solutions of Nb-Xat.%Cr (X = 35, 50, 57, 77, 82, and 94) were synthesized by two-anvil splat-quenching. In addition, bcc (Nb-67at.%Cr) was prepared by mechanically alloying mixtures of niobium and chromium powders. The lattice parameters were measured by X-ray diffraction and the Young`s moduli were measured by low-load microindentation. The composition dependence of the lattice parameters and elastic moduli show a positive deviation with respect to a rule of mixtures. During continuous heating at 15C/min., the metastable precursor bcc phases decomposed at temperatures above 750C to uniformly refined microstructures.

  9. Evaluation of Negative-Ion-Beam Driver Concepts for Heavy Ion Fusion

    SciTech Connect (OSTI)

    Grisham, Larry R.

    2003-03-15

    The feasibility of producing and using atomically neutral heavy ion beams produced from negative ions as drivers for an inertial confinement fusion reactor is evaluated. Bromine and iodine appear to be the most attractive elements for the driver beams. Fluorine and chlorine appear to be the most appropriate feedstocks for initial tests of extractable negative-ion current densities. With regard to ion sources, photodetachment neutralizers, and vacuum requirements for accelerators and beam transport, this approach appears feasible within existing technology, and the vacuum requirements are essentially identical to those for positive-ion drivers except in the target chamber. The principal constraint is that this approach requires harder vacuums in the target chamber than do space-charge-neutralized positive-ion drivers. With realistic (but perhaps pessimistic) estimates of the total ionization cross section, limiting the ionization of a neutral beam to <5% while traversing a 3-m path would require a chamber pressure of no more than 1.3 x 10{sup -5} torr. However, it appears that substantial improvements in the beam spot size on target might be achieved at pressures a factor of 10 or more higher than this. Alternatively, even at still higher chamber pressures that would strongly ionize atomically neutral beams, the negative-ion approach may still have significant appeal, since it precludes the possibly challenging problem of electron contamination of a positive-ion beam during acceleration, drift compression, and focusing.

  10. Evaluation of Negative-Ion-Beam Driver Concepts for Heavy Ion Fusion

    SciTech Connect (OSTI)

    Larry R. Grisham

    2002-01-14

    We evaluate the feasibility of producing and using atomically neutral heavy ion beams produced from negative ions as drivers for an inertial confinement fusion reactor. Bromine and iodine appear to be the most attractive elements for the driver beams. Fluorine and chlorine appear to be the most appropriate feedstocks for initial tests of extractable negative ion current densities. With regards to ion sources, photodetachment neutralizers, and vacuum requirements for accelerators and beam transport, this approach appears feasible within existing technology, and the vacuum requirements are essentially identical to those for positive ion drivers except in the target chamber. The principal constraint is that this approach requires harder vacuums in the target chamber than do space-charge-neutralized positive ion drivers. With realistic (but perhaps pessimistic) estimates of the total ionization cross section, limiting the ionization of a neutral beam to less than 5% while traversing a four -meter path would require a chamber pressure of no more than 5 x 10{sup -5} torr. Alternatively, even at chamber pressures that are too high to allow propagation of atomically neutral beams, the negative ion approach may still have appeal, since it precludes the possibly serious problem of electron contamination of a positive ion beam during acceleration, drift compression, and focusing.

  11. Refueling Behavior of Flexible Fuel Vehicle Drivers in the Federal Fleet

    SciTech Connect (OSTI)

    Daley, R.; Nangle, J.; Boeckman, G.; Miller, M.

    2014-05-01

    Federal fleets are a frequent subject of legislative and executive efforts to lead a national transition to alternative fuels and advanced vehicle technologies. Section 701 of the Energy Policy Act of 2005 requires that all dual-fueled alternative fuel vehicles in the federal fleet be operated on alternative fuel 100% of the time when they have access to it. However, in Fiscal Year (FY) 2012, drivers of federal flex fuel vehicles (FFV) leased through the General Services Administration refueled with E85 24% of the time when it was available--falling well short of the mandate. The U.S. Department of Energy's National Renewable Energy Laboratory completed a 2-year Laboratory Directed Research and Development project to identify the factors that influence the refueling behavior of federal FFV drivers. The project began with two primary hypotheses. First, information scarcity increases the tendency to miss opportunities to purchase E85. Second, even with perfect information, there are limits to how far drivers will go out of their way to purchase E85. This paper discusses the results of the project, which included a June 2012 survey of federal fleet drivers and an empirical analysis of actual refueling behavior from FY 2009 to 2012. This research will aid in the design and implementation of intervention programs aimed at increasing alternative fuel use and reducing petroleum consumption.

  12. Current status of the superconducting RF linac driver for the JAERI Free Electron Laser Facility

    SciTech Connect (OSTI)

    Minehara, E.J.; Sugimoto, M.; Sawamura, M.

    1995-12-31

    The commissioning of the superconducting rf linac driver for the JAERI free electron laser facility has been successfully performed at 10{approx}20 MeV before the end of the 1994 Japanese fiscal year. The performance obtained during the commissioning and current status of the JAERI FEL program at Tokai will be reported in detail.

  13. What kind of charging infrastructure do Chevrolet Volts Drivers in The EV Project use?

    SciTech Connect (OSTI)

    John Smart

    2013-09-01

    This report summarizes key conclusions from analysis of data collected from Chevrolet Volts participating in The EV Project. Topics include how much Volt drivers charge at level 1 vs. level 2 rates and how much they charge at home vs. away from home.

  14. Advanced beam-dynamics simulation tools for the RIA driver linac,Part I: Low energy beam transport and radiofrequency quadrupole

    SciTech Connect (OSTI)

    Wangler, Thomas P.; Crandall, Kenneth R.; Garnett, Robert W.; Gorelov, Dmitry; Ostroumov, Petr; Qiang, Ji; Ryne, Robert; York, Richard

    2003-08-26

    Advanced Beam-Dynamics Simulation Tools for the RIA Driver Linac; Low Energy Beam Transport and Radiofrequency Quadrupole.

  15. Shell model description of band structure in 48Cr

    SciTech Connect (OSTI)

    Vargas, Carlos E.; Velazquez, Victor M.

    2007-02-12

    The band structure for normal and abnormal parity bands in 48Cr are described using the m-scheme shell model. In addition to full fp-shell, two particles in the 1d3/2 orbital are allowed in order to describe intruder states. The interaction includes fp-, sd- and mixed matrix elements.

  16. CR-39 track etching and blow-up method

    DOE Patents [OSTI]

    Hankins, Dale E. (Livermore, CA)

    1987-01-01

    This invention is a method of etching tracks in CR-39 foil to obtain uniformly sized tracks. The invention comprises a step of electrochemically etching the foil at a low frequency and a "blow-up" step of electrochemically etching the foil at a high frequency.

  17. Magnetization reversal in TmCrO{sub 3}

    SciTech Connect (OSTI)

    Yoshii, Kenji

    2012-11-15

    Highlights: ► We observed two magnetization reversals in TmCrO{sub 3}. ► The reversal at 28 K is attributed to antiparallel coupling between Cr{sup 3+} and Tm{sup 3+}. ► The other reversal originates from spin reorientation. ► Magnetocaloric effect is observed at the spin reorientation temperature. ► Characteristic magnetization switching is demonstrated. -- Abstract: The perovskite chromite TmCrO{sub 3} shows magnetization reversal at two temperatures. The reversal at ∼28 K is attributed to the antiparallel coupling between Tm{sup 3+} and Cr{sup 3+} moments, while that at the lower temperature (∼6–7 K) is rooted in a rotation of the magnetic moments. Magnetocaloric measurements offer a relatively large entropy change (∼4–5 J kg{sup −1} K{sup −1}) at the lower temperature. The reversal at ∼28 K is accompanied by a sign change of an exchange-bias-like field. The absence of the training effect suggests that this behavior is rooted in unidirectional magnetic anisotropy. The existence of the two magnetization reversals offers the characteristic switching of magnetization. For example, the magnetization is flipped without changing the direction of the applied magnetic field.

  18. Audit Report: CR-FS-99-01

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MANAGEMENT REPORT AUDIT OF THE DEPARTMENT OF ENERGY'S CONSOLIDATED FINANCIAL STATEMENTS FOR FISCAL YEAR 1998 Report Number: CR-FS-99-01 Capital Regional Audit Office Date of Issue: June 15, 1999 Germantown, MD 20874 MANAGEMENT REPORT AUDIT OF THE DEPARTMENT OF ENERGY'S CONSOLIDATED FINANCIAL STATEMENTS FOR FISCAL YEAR 1998 TABLE OF CONTENTS Page SUMMARY.................................................................................. 1 PART I - APPROACH AND

  19. Audit Report: CR-B-96-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Audit Report: CR-B-96-01 May 24, 1996 The Federal Energy Regulatory Commission Leased Warehouse Space PDF icon Audit Report: CR-B-96-01 More Documents & Publications Semiannual ...

  20. Audit Report: CR-FS-96-03 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Audit Report: CR-FS-96-03 April 15, 1996 Report on Matters Identified at Strategic Petroleum Reserve During Audit of Statement of Financial Position Audit Report: CR-FS-96-03 ...

  1. Audit Report: CR-B-95-06 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5-06 Audit Report: CR-B-95-06 June 30, 1995 Audit of Department of Energy Support Service Contracting PDF icon Audit Report: CR-B-95-06 More Documents & Publications Audit Report: ...

  2. Pressure dependence of the magnetic order in CrAs: A neutron...

    Office of Scientific and Technical Information (OSTI)

    Pressure dependence of the magnetic order in CrAs: A neutron diffraction investigation Citation Details In-Document Search Title: Pressure dependence of the magnetic order in CrAs:...

  3. Uniform Corrosion of model FeCrAl Alloys in LWR Coolants (Conference...

    Office of Scientific and Technical Information (OSTI)

    Conference: Uniform Corrosion of model FeCrAl Alloys in LWR Coolants Citation Details In-Document Search Title: Uniform Corrosion of model FeCrAl Alloys in LWR Coolants Authors: ...

  4. Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized...

    Office of Scientific and Technical Information (OSTI)

    Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter deposition Title: Solid-solution CrCoCuFeNi high-entropy alloy thin films synthesized by sputter ...

  5. Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system...

    Office of Scientific and Technical Information (OSTI)

    Ti3CrCu4: A possible 2-D ferromagnetic spin fluctuating system Title: Ti3CrCu4: A possible ... Country of Publication: United States Language: English Word Cloud More Like This Free ...

  6. Audit Report: CR-B-95-03 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Audit Report: CR-B-95-03 February 6, 1995 Audit of the Department of Energy's Security Police Officer Training PDF icon Audit Report: CR-B-95-03 More Documents & Publications Type...

  7. Audit Report: CR-B-01-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Audit Report: CR-B-01-01 May 9, 2001 Issues Regarding Fee Structure for Three Environmental Management Contracts PDF icon Audit Report: CR-B-01-01 More Documents & Publications ...

  8. Technology Implimentation Plan - ATF FeCrAl Cladding for LWR Application

    SciTech Connect (OSTI)

    Snead, Mary A.; Snead, Lance; Terrani, Kurt A.; Field, Kevin G.; Worrall, Andrew; Robb, Kevin R.; Yamamoto, Yukinori; Powers, Jeffrey J.; Dryepondt, Sebastien N.; Pint, Bruce A.; Hu, Xunxiang

    2015-06-01

    Technology implimentation plan for FeCrAl development under the FCRD Advanced Fuel program. The document describes the activities required to get FeCrAl clad ready for LTR testing

  9. Audit Report: CR-B-97-02 | Department of Energy

    Office of Environmental Management (EM)

    2 Audit Report: CR-B-97-02 April 4, 1997 Audit of Department of Energy's Contractor Salary Increase Funds Audit Report: CR-B-97-02 More Documents & Publications Inspection Report:...

  10. Audit Report: CR-FS-97-02 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FS-97-02 Audit Report: CR-FS-97-02 May 1, 1997 Audit of the Department of Energy's Consolidated Financial Statements for Fiscal Year 1996 Audit Report: CR-FS-97-02 More Documents &...

  11. Radiation effects on interface reactions of U/Fe, U/(Fe+Cr), and U/(Fe+Cr+Ni)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Chen, Di; Wei, Chaochen; Martin, Michael S.; Wang, Xuemei; Park, Youngjoo; Dein, Ed; Coffey, Kevin R.; Sohn, Yongho; Sencer, Bulent H.; et al

    2014-10-01

    We study the effects of radiation damage on interdiffusion and intermetallic phase formation at the interfaces of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni) diffusion couples. Magnetron sputtering is used to deposit thin films of Fe, Fe + Cr, or Fe + Cr + Ni on U substrates to form the diffusion couples. One set of samples are thermally annealed under high vacuum at 450 C or 550 C for one hour. A second set of samples are annealed identically but with concurrent 3.5 MeV Fe++ ion irradiation. The Fe++ ion penetration depth is sufficient to reachmore »the original interfaces. Rutherford backscattering spectrometry analysis with high fidelity spectral simulations is used to obtain interdiffusion profiles, which are used to examine differences in U diffusion and intermetallic phase formation at the buried interfaces. For all three diffusion systems, Fe++ ion irradiations enhance U diffusion. Furthermore, the irradiations accelerate the formation of intermetallic phases. In U/Fe couples, for example, the unirradiated samples show typical interdiffusion governed by Fick’s laws, while the irradiated ones show step-like profiles influenced by Gibbs phase rules.« less

  12. Non-classical nuclei and growth kinetics of Cr precipitates in FeCr alloys during ageing

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Zhang, Lei; Sun, Xin

    2014-01-10

    In this manuscript, we quantitatively calculated the thermodynamic properties of critical nuclei of Cr precipitates in FeCr alloys. The concentration profiles of the critical nuclei and nucleation energy barriers were predicted by the constrained shrinking dimer dynamics (CSDD) method. It is found that Cr concentration distribution in the critical nuclei strongly depend on the overall Cr concentration as well as temperature. The critical nuclei are non-classical because the concentration in the nuclei is smaller than the thermodynamic equilibrium value. These results are in agreement with atomic probe observation. The growth kinetics of both classical and non-classical nuclei was investigated by the phase field approach. The simulations of critical nucleus evolution showed a number of interesting phenomena: 1) a critical classical nucleus first shrinks toward its non-classical nucleus and then grows; 2) a non-classical nucleus has much slower growth kinetics at its earlier growth stage compared to the diffusion-controlled growth kinetics. 3) a critical classical nucleus grows faster at the earlier growth stage than the non-classical nucleus. All of these results demonstrate that it is critical to introduce the correct critical nuclei in order to correctly capture the kinetics of precipitation.

  13. Radiation effects on interface reactions of U/Fe, U/(Fe+Cr), and U/(Fe+Cr+Ni)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Chen, Di; Wei, Chaochen; Martin, Michael S.; Wang, Xuemei; Park, Youngjoo; Dein, Ed; Coffey, Kevin R.; Sohn, Yongho; Sencer, Bulent H.; et al

    2014-10-01

    We study the effects of radiation damage on interdiffusion and intermetallic phase formation at the interfaces of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni) diffusion couples. Magnetron sputtering is used to deposit thin films of Fe, Fe + Cr, or Fe + Cr + Ni on U substrates to form the diffusion couples. One set of samples are thermally annealed under high vacuum at 450 C or 550 C for one hour. A second set of samples are annealed identically but with concurrent 3.5 MeV Fe++ ion irradiation. The Fe++ ion penetration depth is sufficient to reachmore » the original interfaces. Rutherford backscattering spectrometry analysis with high fidelity spectral simulations is used to obtain interdiffusion profiles, which are used to examine differences in U diffusion and intermetallic phase formation at the buried interfaces. For all three diffusion systems, Fe++ ion irradiations enhance U diffusion. Furthermore, the irradiations accelerate the formation of intermetallic phases. In U/Fe couples, for example, the unirradiated samples show typical interdiffusion governed by Fick’s laws, while the irradiated ones show step-like profiles influenced by Gibbs phase rules.« less

  14. Radiation effects on interface reactions of U/Fe, U/(Fe+Cr), and U/(Fe+Cr+Ni)

    SciTech Connect (OSTI)

    Shao, Lin; Chen, Di; Wei, Chaochen; Martin, Michael S.; Wang, Xuemei; Park, Youngjoo; Dein, Ed; Coffey, Kevin R.; Sohn, Yongho; Sencer, Bulent H.; Rory Kennedy, J.

    2014-10-01

    We study the effects of radiation damage on interdiffusion and intermetallic phase formation at the interfaces of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni) diffusion couples. Magnetron sputtering is used to deposit thin films of Fe, Fe + Cr, or Fe + Cr + Ni on U substrates to form the diffusion couples. One set of samples are thermally annealed under high vacuum at 450 C or 550 C for one hour. A second set of samples are annealed identically but with concurrent 3.5 MeV Fe++ ion irradiation. The Fe++ ion penetration depth is sufficient to reach the original interfaces. Rutherford backscattering spectrometry analysis with high fidelity spectral simulations is used to obtain interdiffusion profiles, which are used to examine differences in U diffusion and intermetallic phase formation at the buried interfaces. For all three diffusion systems, Fe++ ion irradiations enhance U diffusion. Furthermore, the irradiations accelerate the formation of intermetallic phases. In U/Fe couples, for example, the unirradiated samples show typical interdiffusion governed by Fick’s laws, while the irradiated ones show step-like profiles influenced by Gibbs phase rules.

  15. Surface half-metallicity of CrS thin films and perfect spin filtering and spin diode effects of CrS/ZnSe heterostructure

    SciTech Connect (OSTI)

    Gao, G. Y. Yao, K. L.

    2014-11-03

    Recently, ferromagnetic zinc-blende Mn{sub 1−x}Cr{sub x}S thin films (above x = 0.5) were fabricated experimentally on ZnSe substrate, which confirmed the previous theoretical prediction of half-metallic ferromagnetism in zinc-blende CrS. Here, we theoretically reveal that both Cr- and S-terminated (001) surfaces of the CrS thin films retain the half-metallicity. The CrS/ZnSe(001) heterogeneous junction exhibits excellent spin filtering and spin diode effects, which are explained by the calculated band structure and transmission spectra. The perfect spin transport properties indicate the potential applications of half-metallic CrS in spintronic devices. All computational results are obtained by using the density functional theory combined with nonequilibrium Green's function.

  16. Accounting for the Variation of Driver Aggression in the Simulation of Conventional and Advanced Vehicles

    SciTech Connect (OSTI)

    Neubauer, J.; Wood, E.

    2013-01-01

    Hybrid electric vehicles, plug-in hybrid electric vehicles, and battery electric vehicles offer the potential to reduce both oil imports and greenhouse gases, as well as to offer a financial benefit to the driver. However, assessing these potential benefits is complicated by several factors, including the driving habits of the operator. We focus on driver aggression, i.e., the level of acceleration and velocity characteristic of travel, to (1) assess its variation within large, real-world drive datasets, (2) quantify its effect on both vehicle efficiency and economics for multiple vehicle types, (3) compare these results to those of standard drive cycles commonly used in the industry, and (4) create a representative drive cycle for future analyses where standard drive cycles are lacking.

  17. Accounting for the Variation of Driver Aggression in the Simulation of Conventional and Advanced Vehicles: Preprint

    SciTech Connect (OSTI)

    Neubauer, J.; Wood, E.

    2013-03-01

    Hybrid electric vehicles, plug-in hybrid electric vehicles, and battery electric vehicles offer the potential to reduce both oil imports and greenhouse gases, as well as to offer a financial benefit to the driver. However, assessing these potential benefits is complicated by several factors, including the driving habits of the operator. We focus on driver aggression, i.e., the level of acceleration and velocity characteristic of travel, to (1) assess its variation within large, real-world drive datasets, (2) quantify its effect on both vehicle efficiency and economics for multiple vehicle types, (3) compare these results to those of standard drive cycles commonly used in the industry, and (4) create a representative drive cycle for future analyses where standard drive cycles are lacking.

  18. Drivers and barriers to e-invoicing adoption in Greek large scale manufacturing industries

    SciTech Connect (OSTI)

    Marinagi, Catherine E-mail: ptrivel@yahoo.com Trivellas, Panagiotis E-mail: ptrivel@yahoo.com Reklitis, Panagiotis E-mail: ptrivel@yahoo.com; Skourlas, Christos

    2015-02-09

    This paper attempts to investigate the drivers and barriers that large-scale Greek manufacturing industries experience in adopting electronic invoices (e-invoices), based on three case studies with organizations having international presence in many countries. The study focuses on the drivers that may affect the increase of the adoption and use of e-invoicing, including the customers demand for e-invoices, and sufficient know-how and adoption of e-invoicing in organizations. In addition, the study reveals important barriers that prevent the expansion of e-invoicing, such as suppliers’ reluctance to implement e-invoicing, and IT infrastructures incompatibilities. Other issues examined by this study include the observed benefits from e-invoicing implementation, and the financial priorities of the organizations assumed to be supported by e-invoicing.

  19. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes

    SciTech Connect (OSTI)

    Cummings, James; Withers, Charles; Martin, Eric; Moyer, Neil

    2012-10-01

    This report is a revision of an earlier report titled: Measure Guideline: Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single-Family Homes. Revisions include: Information in the text box on page 1 was revised to reflect the most accurate information regarding classifications as referenced in the 2012 International Residential Code. “Measure Guideline” was dropped from the title of the report. An addition was made to the reference list.

  20. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  1. Session 4: "Short-Term Energy Prices - What Drivers Matter Most?"

    U.S. Energy Information Administration (EIA) Indexed Site

    4: "Short-Term Energy Prices - What Drivers Matter Most?" Speakers: Howard K. Gruenspecht, EIA David M. Arseneau, Federal Reserve Board Guy F. Caruso, Center for Strategic and International Studies Christopher Ellsworth, Federal Energy Regulatory Commission Edward L. Morse, Credit Suisse Securities [Note: Recorders did not pick up introduction of panel (see biographies for details on the panelists) or introduction of session.] Howard: And this presentation could not be more timely,

  2. Design of a new main injector cavity for the Fermilab Proton Driver era

    SciTech Connect (OSTI)

    Wu, V.; Chen, A.; Qian, Z.; Wildman, D.W.; /Fermilab

    2005-05-01

    In the design report of the Fermilab Proton Driver [1], the Main Injector (MI) needs to be upgraded to a 2 MW machine. For the Main Injector radiofrequency (rf) upgrade, R&D efforts are launched to design and build a new rf system. This paper presents the new cavity design study for the rf system. The cavity is simulated with the design code Mafia [2].

  3. Creating a Well-focused Laser-accelerated Proton Beam as a Driver for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Fast Ignition | U.S. DOE Office of Science (SC) Creating a Well-focused Laser-accelerated Proton Beam as a Driver for Proton Fast Ignition Fusion Energy Sciences (FES) FES Home About Research Facilities Science Highlights Benefits of FES Funding Opportunities Fusion Energy Sciences Advisory Committee (FESAC) Community Resources Contact Information Fusion Energy Sciences U.S. Department of Energy SC-24/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301)

  4. Reliable, high repetition rate thyratron grid driver used with a magnetic modulator

    SciTech Connect (OSTI)

    Hill, J.V.; Ball, D.G.; Garrett, D.N.

    1991-06-14

    The Atomic Vapor Laser Isotope Separation (AVLIS) Program at Lawrence Livermore National Laboratory uses a magnetic modulator switched by a high voltage thyratron to drive a gas discharge laser. The thyratron trigger source must provide an extremely reliable, low jitter, high- rep-rate grid pulse. This paper describes a thyratron grid driver which delivers a 1.2 kV, 80 ns rise time grid pulse into a 50 ohm load at up to 4.5 kHz repetition rate and has demonstrated approximately 10,000 hours MTBF. Since the thyratron is used with a magnetic compression circuit having a delay time of 1.4 ms this grid driver incorporates a jitter compensation circuit to adjust the trigger timing of the thyratron to provide overall modulator/laser jitter of less than {plus minus} 2 ns. The specific grid driver requirements will be discussed followed by a description of the circuit design and theory of operation. Construction comments will be followed by performance data (for a specific thyratron and magnetic compression circuit), including pulse shape, jitter, and lifetime. 1 ref., 10 figs.

  5. Can we estimate plasma density in ICP driver through electrical parameters in RF circuit?

    SciTech Connect (OSTI)

    Bandyopadhyay, M. Sudhir, Dass Chakraborty, A.

    2015-04-08

    To avoid regular maintenance, invasive plasma diagnostics with probes are not included in the inductively coupled plasma (ICP) based ITER Neutral Beam (NB) source design. Even non-invasive probes like optical emission spectroscopic diagnostics are also not included in the present ITER NB design due to overall system design and interface issues. As a result, negative ion beam current through the extraction system in the ITER NB negative ion source is the only measurement which indicates plasma condition inside the ion source. However, beam current not only depends on the plasma condition near the extraction region but also on the perveance condition of the ion extractor system and negative ion stripping. Nevertheless, inductively coupled plasma production region (RF driver region) is placed at distance (∼ 30cm) from the extraction region. Due to that, some uncertainties are expected to be involved if one tries to link beam current with plasma properties inside the RF driver. Plasma characterization in source RF driver region is utmost necessary to maintain the optimum condition for source operation. In this paper, a method of plasma density estimation is described, based on density dependent plasma load calculation.

  6. Survey of Laser Markets Relevant to Inertial Fusion Energy Drivers, information for National Research Council

    SciTech Connect (OSTI)

    Bayramian, A J; Deri, R J; Erlandson, A C

    2011-02-24

    Development of a new technology for commercial application can be significantly accelerated by leveraging related technologies used in other markets. Synergies across multiple application domains attract research and development (R and D) talent - widening the innovation pipeline - and increases the market demand in common components and subsystems to provide performance improvements and cost reductions. For these reasons, driver development plans for inertial fusion energy (IFE) should consider the non-fusion technology base that can be lveraged for application to IFE. At this time, two laser driver technologies are being proposed for IFE: solid-state lasers (SSLs) and KrF gas (excimer) lasers. This document provides a brief survey of organizations actively engaged in these technologies. This is intended to facilitate comparison of the opportunities for leveraging the larger technical community for IFE laser driver development. They have included tables that summarize the commercial organizations selling solid-state and KrF lasers, and a brief summary of organizations actively engaged in R and D on these technologies.

  7. HESFIRE: a global fire model to explore the role of anthropogenic and weather drivers

    SciTech Connect (OSTI)

    Le Page, Yannick LB; Morton, Douglas; Bond-Lamberty, Benjamin; Pereira, Jose M.; Hurtt, George C.

    2015-02-13

    Vegetation fires are a major driver of ecosystem dynamics and greenhouse gas emissions. Anticipating potential changes in fire activity and their impacts relies first on a realistic model of fire activity (e.g., fire incidence and interannual variability) and second on a model accounting for fire impacts (e.g., mortality and emissions). In this paper, we focus on our understanding of fire activity and describe a new fire model, HESFIRE (Human–Earth System FIRE), which integrates the influence of weather, vegetation characteristics, and human activities on fires in a stand-alone framework. It was developed with a particular emphasis on allowing fires to spread over consecutive days given their major contribution to burned areas in many ecosystems. A subset of the model parameters was calibrated through an optimization procedure using observation data to enhance our knowledge of regional drivers of fire activity and improve the performance of the model on a global scale. Modeled fire activity showed reasonable agreement with observations of burned area, fire seasonality, and interannual variability in many regions, including for spatial and temporal domains not included in the optimization procedure. Significant discrepancies are investigated, most notably regarding fires in boreal regions and in xeric ecosystems and also fire size distribution. The sensitivity of fire activity to model parameters is analyzed to explore the dominance of specific drivers across regions and ecosystems. The characteristics of HESFIRE and the outcome of its evaluation provide insights into the influence of anthropogenic activities and weather, and their interactions, on fire activity.

  8. Accounting for the Variation of Driver Aggression in the Simulation of Conventional and Advanced Vehicles (Presentation)

    SciTech Connect (OSTI)

    Neubauer, J.; Wood, E.

    2013-05-01

    This presentation discusses a method of accounting for realistic levels of driver aggression to higher-level vehicle studies, including the impact of variation in real-world driving characteristics (acceleration and speed) on vehicle energy consumption and different powertrains (e.g., conventionally powered vehicles versus electrified drive vehicles [xEVs]). Aggression variation between drivers can increase fuel consumption by more than 50% or decrease it by more than 20% from average. The normalized fuel consumption deviation from average as a function of population percentile was found to be largely insensitive to powertrain. However, the traits of ideal driving behavior are a function of powertrain. In conventional vehicles, kinetic losses dominate rolling resistance and aerodynamic losses. In xEVs with regenerative braking, rolling resistance and aerodynamic losses dominate. The relation of fuel consumption predicted from real-world drive data to that predicted by the industry-standard HWFET, UDDS, LA92, and US06 drive cycles was not consistent across powertrains, and varied broadly from the mean, median, and mode of real-world driving. A drive cycle synthesized by NREL's DRIVE tool accurately and consistently reproduces average real-world for multiple powertrains within 1%, and can be used to calculate the fuel consumption effects of varying levels of driver aggression.

  9. Break-Even Cost for Residential Photovoltaics in the United States: Key Drivers and Sensitivities

    SciTech Connect (OSTI)

    Denholm, P.; Margolis, R. M.; Ong, S.; Roberts, B.

    2009-12-01

    Grid parity--or break-even cost--for photovoltaic (PV) technology is defined as the point where the cost of PV-generated electricity equals the cost of electricity purchased from the grid. Break-even cost is expressed in $/W of an installed system. Achieving break-even cost is a function of many variables. Consequently, break-even costs vary by location and time for a country, such as the United States, with a diverse set of resources, electricity prices, and other variables. In this report, we analyze PV break-even costs for U.S. residential customers. We evaluate some key drivers of grid parity both regionally and over time. We also examine the impact of moving from flat to time-of-use (TOU) rates, and we evaluate individual components of the break-even cost, including effect of rate structure and various incentives. Finally, we examine how PV markets might evolve on a regional basis considering the sensitivity of the break-even cost to four major drivers: technical performance, financing parameters, electricity prices and rates, and policies. We find that local incentives rather than ?technical? parameters are in general the key drivers of the break-even cost of PV. Additionally, this analysis provides insight about the potential viability of PV markets.

  10. Where do Chevrolet Volt drivers in The EV Project charge when they have the opportunity to charge at work?

    SciTech Connect (OSTI)

    John Smart; Don Scoffield

    2014-03-01

    This paper investigates where Chevy Volt drivers in the EV Project charge when they have the opportunity to charge at work. Do they charge at home, work, or some other location.

  11. Where do Nissan Leaf drivers in The EV Project charge when they have the opportunity to charge at work?

    SciTech Connect (OSTI)

    John Smart; Don Scoffield

    2014-03-01

    This paper invesigates where Nissan Leaf drivers in the EV Project charge when they have the opportunity to charge at work. Do they charge at work, home, or some other location?

  12. Transport signatures of quantum critically in Cr at high pressure.

    SciTech Connect (OSTI)

    Jaramillo, R.; Feng, Y.; Wang, J.; Rosenbaum, T. F.

    2010-08-03

    The elemental antiferromagnet Cr at high pressure presents a new type of naked quantum critical point that is free of disorder and symmetry-breaking fields. Here we measure magnetotransport in fine detail around the critical pressure, P{sub c} {approx} 10 GPa, in a diamond anvil cell and reveal the role of quantum critical fluctuations at the phase transition. As the magnetism disappears and T {yields} 0, the magntotransport scaling converges to a non-mean-field form that illustrates the reconstruction of the magnetic Fermi surface, and is distinct from the critical scaling measured in chemically disordered Cr:V under pressure. The breakdown of itinerant antiferromagnetism only comes clearly into view in the clean limit, establishing disorder as a relevant variable at a quantum phase transition.

  13. Cr/sup 3 +/-doped colquiriite solid state laser material

    DOE Patents [OSTI]

    Payne, S.A.; Chase, L.L.; Newkirk, H.W.; Krupke, W.F.

    1988-03-31

    Chromium doped colquiriite, LiCaAlF/sub 6/:Cr/sup 3 +/, is useful as a tunable laser crystal that has a high intrinsic slope efficiency, comparable to or exceeding that of alexandrite, the current leading performer of vibronic sideband Cr/sup 3 +/ lasers. The laser output is tunable from at least 720 nm to 840 nm with a measured slope efficiency of about 60% in a Kr laser pumped laser configuration. The intrinsic slope efficiency (in the limit of large output coupling) may approach the quantum defect limited value of 83%. The high slope efficiency implies that excited state absorption (ESA) is negligible. The potential for efficiency and the tuning range of this material satisfy the requirements for a pump laser for a high density storage medium incorporating Nd/sup 3 +/ or Tm/sup 3 +/ for use in a multimegajoule single shot fusion research facility. 4 figs.

  14. Cr.sup.3+ -doped colquiriite solid state laser material

    DOE Patents [OSTI]

    Payne, Stephen A.; Chase, Lloyd L.; Newkirk, Herbert W.; Krupke, William F.

    1989-01-01

    Chromium doped colquiriite, LiCaAlF.sub.6 :Cr.sup.3+, is useful as a tunable laser crystal that has a high intrinsic slope efficiency, comparable to or exceeding that of alexandrite, the current leading performer of vibronic sideband Cr.sup.3+ lasers. The laser output is tunable from at least 720 nm to 840 nm with a measured slop efficiency of about 60% in a Kr laser pumped laser configuration. The intrinsic slope efficiency (in the limit of large output coupling) may approach the quantum defect limited value of 83%. The high slope efficiency implies that excited state absorption (ESA) is negligible. The potential for efficiency and the tuning range of this material satisfy the requirements for a pump laser for a high density storage medium incorporating Nd.sup.3+ or Tm.sup.3+ for use in a multimegajoule single shot fusion research facility.

  15. Cr{sub 2}Nb-based alloy development

    SciTech Connect (OSTI)

    Liu, C.T.; Horton, J.A.; Carmichael, C.A.

    1996-05-01

    This paper summarizes recent progress in developing Cr{sub 2}Nb/Cr(Nb) alloys for structural use in advanced fossil energy conversion systems. Alloy additions were added to control the microstructure and mechanical properties. Two beneficial elements have been identified among all alloying additions added to the alloys. One element is effective in refining the coarse eutectic structure and thus substantially improves the compressive strength and ductility of the alloys. The other element enhances oxidation resistance without sacrificing the ductility. The tensile properties are sensitive to cast defects, which can not be effectively reduced by HIPping at 1450-1580{degrees}C and/or directionally solidifying via a floating zone remelting method.

  16. Reactions of hydrogen with V-Cr-Ti alloys

    SciTech Connect (OSTI)

    DiStefano, J.R.; DeVan, J.H.; Chitwood, L.D.; Roehrig, D.H.

    1998-09-01

    In the absence of increases in oxygen concentration, additions of up to 400 ppm hydrogen to V-4 Cr-4 Ti did not result in significant embrittlement as determined by room temperature tensile tests. However, when hydrogen approached 700 ppm after exposure at 325 C, rapid embrittlement occurred. In this latter case, hydride formation is the presumed embrittlement cause. When oxygen was added during or prior to hydrogen exposure, synergistic effects led to significant embrittlement by 100 ppm hydrogen.

  17. SF6432-CR (02-01-13) Cost Reimbursement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department Release Date: 11/17/15 Page 1 of 25 Printed copies of this document are uncontrolled. Retrieve latest version electronically. SANDIA CORPORATION SF 6432-CR (11/2015) SECTION II STANDARD TERMS AND CONDITIONS FOR COST-REIMBURSEMENT CONTRACTS THE FOLLOWING CLAUSES APPLY TO THIS CONTRACT AS INDICATED UNLESS SPECIFICALLY DELETED, OR EXCEPT TO THE EXTENT THEY ARE SPECIFICALLY IDENTIFIED AS BEING CHANGED, SUPPLEMENTED, OR AMENDED IN WRITING ISSUED BY THE SANDIA CONTRACTING REPRESENTATIVE.

  18. AmeriFlux CR-Lse La Selva

    SciTech Connect (OSTI)

    Loescher, Hank

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site CR-Lse La Selva. Site Description - Site was occupied by Native Americans since 3000 B.P. practicing shifting cultivation. Some selective cutting along rivers (heart of palm). Charcoal dating indicate fires 2400 B.P. and 1100 B.P. Some clearing for pasture/cocoa production, second growth, humid tropical rain forest. Site resides on land presently owned by the Organization for Tropical Studies.

  19. Watermelon-like iron nanoparticles: Cr doping effect on magnetism and magnetization interaction reversal

    SciTech Connect (OSTI)

    Kaur, Maninder; Dai, Qilin; Bowden, Mark E.; Engelhard, Mark H.; Wu, Yaqiao; Tang, Jinke; Qiang, You

    2013-06-26

    Chromium (Cr) forms a solid solution with iron (Fe) lattice when doped in core-shell iron -iron oxide nanocluster (NC) and shows a mixed phase of sigma (?) FeCr and bcc Fe. The Cr dopant affects heavily the magnetization and magnetic reversal process, and causes the hysteresis loop to shrink near the zero field axis. Dramatic transformation happens from dipolar interaction (0 at. % Cr) to strong exchange interaction (8 at. % of Cr) is confirmed from the Henkel plot and delta M plot, and is explained by a water-melon model of core-shell NC system.

  20. Cr{sub 2}Nb-based alloy development

    SciTech Connect (OSTI)

    Liu, C.T.; Tortorelli, P.F.; Horton, J.A.; Easton, D.S.; Heatherly, L.

    1996-06-01

    The objective of this work is to develop a new generation of structural materials based on intermetallic alloys for use at high temperatures in advanced fossil energy conversion systems. Target applications of such ultrahigh strength alloys include hot components (for example, air heat exchangers) in advanced energy conversion systems and heat engines. However, these materials may also find use as wear-resistant parts in coal handling systems (for example, nozzles), drill bits for oil/gas wells, and valve guides in diesel engines. One potential class of such alloys is that based on Cr-Cr{sub 2}Nb alloys. The intermetallic phase, Cr{sub 2}Nb, with a complex cubic structure (C-15) has been selected for initial development because of its high melting point (1770{degrees}C), relatively low material density (7.7 g/cm{sup 2}), and excellent high-temperature strength (at 1000 to 1250{degrees}C). This intermetallic phase, like many other Laves phases, has a wide range of compositional homogeneity suggesting the possibility of improving its mechanical and metallurgical properties by alloying additions.

  1. Low temperature spin dynamics in Cr{sub 7}Ni-Cu-Cr{sub 7}Ni coupled molecular rings

    SciTech Connect (OSTI)

    Bordonali, L.; Furukawa, Y.; Mariani, M.; Sabareesh, K. P. V.; Garlatti, E.; Borsa, F.

    2014-05-07

    Proton Nuclear Magnetic Resonance (NMR) relaxation measurements have been performed down to very low temperature (50 mK) to determine the effect of coupling two Cr{sub 7}Ni molecular rings via a Cu{sup 2+} ion. No difference in the spin dynamics was found from nuclear spin lattice relaxation down to 1.5 K. At lower temperature, the {sup 1}H-NMR line broadens dramatically indicating spin freezing. From the plot of the line width vs. magnetization, it is found that the freezing temperature is higher (260 mK) in the coupled ring with respect to the single Cr{sub 7}Ni ring (140 mK)

  2. Optical and electron paramagnetic resonance studies of Cr doped Ga{sub 2}O{sub 3} nanoparticles

    SciTech Connect (OSTI)

    Popa, A. Toloman, D.; Stan, M.; Silipas, T. D.; Biris, A. R.

    2015-12-23

    In the present work we report the experimental results obtained on Ga{sub 2}O{sub 3} nanoparticles doped with Cr ions. X-ray diffraction analysis confirms the substitution of Ga ions with Cr ions. A secondary phase of Cr{sub 2}O{sub 5} oxides was evidence at high doping Cr concentration by Raman spectroscopy. Different valence state of Cr ions was highlighted by UV-VIS spectroscopy. EPR spectroscopy data show the presence of different environments for Cr ions, depending on the Cr addition.

  3. Cr(OH)₃(s) Oxidation Induced by Surface Catalyzed Mn(II) Oxidation

    SciTech Connect (OSTI)

    Namgung, Seonyi; Kwon, M.; Qafoku, Nikolla; Lee, Gie Hyeon

    2014-09-16

    This study examined the feasibility of Cr(OH)₃(s) oxidation mediated by surface catalyzed Mn(II) oxidation under common groundwater pH conditions as a potential pathway of natural Cr(VI) contaminations. Dissolved Mn(II) (50 μM) was reacted with or without synthesized Cr(OH)₃(s) (1.0 g/L) at pH 7 – 9 under oxic or anoxic conditions. In the absence of Cr(OH)₃(s), homogeneous Mn(II) oxidation by dissolved O₂ was not observed at pH ≤ 8.0 for 50 d. At pH 9.0, by contrast, dissolved Mn(II) was completely removed within 8 d and precipitated as hausmannite. When Cr(OH)₃(s) was present, this solid was oxidized and released substantial amounts of Cr(VI) as dissolved Mn(II) was added into the suspension at pH ≥ 8.0 under oxic conditions. Our results suggest that Cr(OH)₃(s) was readily oxidized by a newly formed Mn oxide as a result of Mn(II) oxidation catalyzed on Cr(OH)₃(s) surface. XANES analysis of the residual solids after the reaction between 1.0 g/L Cr(OH)₃(s) and 204 μM Mn(II) at pH 9.0 for 22 d revealed that the product of surface catalyzed Mn(II) oxidation resembled birnessite. The rate and extent of Cr(OH)₃(s) oxidation was likely controlled by those of surface catalyzed Mn(II) oxidation as the production of Cr(VI) increased with increasing pH and initial Mn(II) concentrations. This study evokes the potential environmental hazard of sparingly soluble Cr(OH)₃(s) that can be a source of Cr(VI) in the presence of dissolved Mn(II).

  4. HESFIRE: a global fire model to explore the role of anthropogenic and weather drivers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Le Page, Yannick LB; Morton, Douglas; Bond-Lamberty, Benjamin; Pereira, Jose M.; Hurtt, George C.

    2015-02-13

    Vegetation fires are a major driver of ecosystem dynamics and greenhouse gas emissions. Anticipating potential changes in fire activity and their impacts relies first on a realistic model of fire activity (e.g., fire incidence and interannual variability) and second on a model accounting for fire impacts (e.g., mortality and emissions). In this paper, we focus on our understanding of fire activity and describe a new fire model, HESFIRE (Human–Earth System FIRE), which integrates the influence of weather, vegetation characteristics, and human activities on fires in a stand-alone framework. It was developed with a particular emphasis on allowing fires to spreadmore » over consecutive days given their major contribution to burned areas in many ecosystems. A subset of the model parameters was calibrated through an optimization procedure using observation data to enhance our knowledge of regional drivers of fire activity and improve the performance of the model on a global scale. Modeled fire activity showed reasonable agreement with observations of burned area, fire seasonality, and interannual variability in many regions, including for spatial and temporal domains not included in the optimization procedure. Significant discrepancies are investigated, most notably regarding fires in boreal regions and in xeric ecosystems and also fire size distribution. The sensitivity of fire activity to model parameters is analyzed to explore the dominance of specific drivers across regions and ecosystems. The characteristics of HESFIRE and the outcome of its evaluation provide insights into the influence of anthropogenic activities and weather, and their interactions, on fire activity.« less

  5. Battery Electric Vehicles: Range Optimization and Diversification for the U.S. Drivers

    SciTech Connect (OSTI)

    Lin, Zhenhong

    2012-01-01

    Properly selecting the driving range is critical for accurately predicting the market acceptance and the resulting social benefits of BEVs. Analysis of transportation technology transition could be biased against battery electric vehicles (BEV) and mislead policy making, if BEVs are not represented with optimal ranges. This study proposes a coherent method to optimize the BEV driving range by minimizing the range-related cost, which is formulated as a function of range, battery cost, energy prices, charging frequency, access to backup vehicles, and the cost and refueling hassle of operating the backup vehicle. This method is implemented with a sample of 36,664 drivers, representing U.S. new car drivers, based on the 2009 National Household Travel Survey data. Key findings are: 1) Assuming the near term (2015) battery cost at $405/kWh, about 98% of the sampled drivers are predicted to prefer a range below 200 miles, and about 70% below 100 miles. The most popular 20-mile band of range is 57 to77 miles, unsurprisingly encompassing the Leaf s EPA-certified 73-mile range. With range limited to 4 or 7 discrete options, the majority are predicted to choose a range below 100 miles. 2) Found as a statistically robust rule of thumb, the BEV optimal range is approximately 0.6% of one s annual driving distance. 3) Reducing battery costs could motivate demand for larger range, but improving public charging may cause the opposite. 4) Using a single range to represent BEVs in analysis could significantly underestimate their competitiveness e.g. by $3226/vehicle if BEVs are represented with 73-mile range only or by $7404/BEV if with 150-mile range only. Range optimization and diversification into 4 or 7 range options reduce such analytical bias by 78% or 90%, respectively.

  6. Electrorefining Experience For Pyrochemical Reprocessing of Spent EBR-II Driver Fuel

    SciTech Connect (OSTI)

    S. X. Li; T. A. Johnson; B. R. Westphal; K. M. Goff; R. W. Benedict

    2005-10-01

    Pyrochemical processing has been implemented for the treatment of spent fuel from the Experimental Breeder Reactor-II (EBR-II) at Idaho National Laboratory since 1996. This report summarizes technical advancements made in electrorefining of spent EBR-II driver fuel in the Mk-IV electrorefiner since the pyrochemical processing was integrated into the AFCI program in 2002. The significant advancements include improving uranium dissolution and noble metal retention from chopped fuel segments, increasing cathode current efficiency, and achieving co-collection of zirconium along with uranium from the cadmium pool.

  7. Overview of proton drivers for neutrino super beams and neutrino factories

    SciTech Connect (OSTI)

    Chou, W.; /Fermilab

    2006-06-01

    There has been a world-wide interest in Proton Drivers in the past decade. Numerous design proposals have been presented in Asia, Europe and North America, ranging from low energy rapid cycling synchrotrons, normal or superconducting linacs to high energy slow cycling synchrotrons and FFAGs. One thing in common is that all these machines provide MW beam power and are used primarily for neutrino experiments. This paper gives an overview of these activities. In the last section the author expresses his personal opinion on the future of this field.

  8. Low-jitter high-power thyristor array pulse driver and generator

    DOE Patents [OSTI]

    Hanks, Roy L. (Byron, CA)

    2002-01-01

    A method and apparatus for generating low-jitter, high-voltage and high-current pulses for driving low impedance loads such as detonator fuses uses a MOSFET driver which, when triggered, discharges a high-voltage pre-charged capacitor into the primary of a toroidal current-multiplying transformer with multiple isolated secondary windings. The secondary outputs are suitable for driving an array of thyristors that discharge a precharged high-voltage capacitor and thus generating the required high-voltage and high-current pulse.

  9. Linear beam raster magnet driver based on H-bridge technique

    DOE Patents [OSTI]

    Sinkine, Nikolai I.; Yan, Chen; Apeldoorn, Cornelis; Dail, Jeffrey Glenn; Wojcik, Randolph Frank; Gunning, William

    2006-06-06

    An improved raster magnet driver for a linear particle beam is based on an H-bridge technique. Four branches of power HEXFETs form a two-by-two switch. Switching the HEXFETs in a predetermined order and at the right frequency produces a triangular current waveform. An H-bridge controller controls switching sequence and timing. The magnetic field of the coil follows the shape of the waveform and thus steers the beam using a triangular rather than a sinusoidal waveform. The system produces a raster pattern having a highly uniform raster density distribution, eliminates target heating from non-uniform raster density distributions, and produces higher levels of beam current.

  10. Characterization of modified 9 Cr-1 Mo steel extruded pipe

    SciTech Connect (OSTI)

    Sikka, V.K.; Hart, M.D.

    1985-04-01

    The fabrication of hot-extruded pipe of modified 9 Cr-1 Mo steel at Cameron Iron Works is described. The report also deals with the tempering response; tensile, Charpy impact, and creep properties; and microstructure of the hot-extruded pipe. The tensile properties of the pipe are compared with the average and average -1.65 standard error of estimate curves for various product forms of several commercial heats of this alloy. The creep-rupture properties are compared with the average curve for various product forms of the commercial heats.

  11. High temperature tensile properties of V-4Cr-4Ti

    SciTech Connect (OSTI)

    Zinkle, S.J.; Rowcliffe, A.F.; Stevens, C.O.

    1998-09-01

    Tensile tests have been performed on V-4Cr-4Ti at 750 and 800 C in order to extend the data base beyond the current limit of 700 C. From comparison with previous measurements, the yield strength is nearly constant and tensile elongations decrease slightly with increasing temperature between 300 and 800 C. The ultimate strength exhibits an apparent maximum near 600 C (attributable to dynamic strain aging) but adequate strength is maintained up to 800 C. The reduction in area measured on tensile specimens remained high ({approximately}80%) for test temperatures up to 800 C, in contrast to previous reported results.

  12. Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, K.; Baxter, D.J.

    1983-07-26

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

  13. Oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, Ken; Baxter, David J.

    1984-01-01

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1-8 wt. % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500.degree.-1000.degree. C.

  14. Microsoft Word - CR-AH Policy.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    After-Hours Policy Original: 11/04 Revised: 2//05 CAMD strives to maintain and improve laboratory and User safety along with User efficiency. After- Hours work inside the cleanroom (CR-AH) is an access privilege that requires deliberate selection of requested Users to maintain a safe, productive environment. * Workdays = 7am - 10pm weekdays * After-Hours = 10pm - 7am workdays + all hours on weekends + all hours of LSU Staff holidays. After-Hours Access Request * Cleanroom-trained Users can apply

  15. Microsoft Word - chapter FeCrMo_ver2.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference on Hydrogen Compatibility of Materials Low-Alloy Ferritic Steels: Tempered Fe-Cr-Mo Alloys (code 1211) Prepared by: B.P. Somerday, Sandia National Laboratories Editors C. San Marchi B.P. Somerday Sandia National Laboratories This report may be updated and revised periodically in response to the needs of the technical community; up-to-date versions can be requested from the editors at the address given below or downloaded at http://www.ca.sandia.gov/matlsTechRef/ . The success of this

  16. Ferromagnetism at room temperature in Cr-doped anodic titanium dioxide nanotubes

    SciTech Connect (OSTI)

    Liao, Yulong E-mail: hwzhang@uestc.edu.cn; Zhang, Huaiwu E-mail: hwzhang@uestc.edu.cn; Li, Jie; Yu, Guoliang; Zhong, Zhiyong; Bai, Feiming; Jia, Lijun; Zhang, Shihong; Zhong, Peng

    2014-05-07

    This study reports the room-temperature ferromagnetism in Cr-doped TiO{sub 2} nanotubes (NTs) synthesized via the electrochemical method followed by a novel Cr-doping process. Scanning electron microscopy and transmission electron microscopy showed that the TiO{sub 2} NTs were highly ordered with length up to 26 ?m, outer diameter about 110 nm, and inner diameter about 100 nm. X-ray diffraction results indicated there were no magnetic contaminations of metallic Cr clusters or any other phases except anatase TiO{sub 2}. The Cr-doped TiO{sub 2} NTs were further annealed in oxygen, air and argon, and room-temperature ferromagnetism was observed in all Cr-doped samples. Moreover, saturation magnetizations and coercivities of the Cr-doped under various annealing atmosphere were further analyzed, and results indicate that oxygen content played a critical role in the room-temperature ferromagnetism.

  17. Effects of Cr doping on the magnetic properties of multiferroic YMnO{sub 3}

    SciTech Connect (OSTI)

    Han, Tai-Chun Wu, I-Chu; Hsu, Hsin-Kai

    2014-05-07

    We have synthesized a series of YMn{sub 1?x}Cr{sub x}O{sub 3} (0???x???0.1) samples and study the effect of Cr-doping on their magnetic properties. The magnetic characterization indicates that with increasing Cr-content up to 0.1, the antiferromagnetic (AFM) transition temperature increases from 73 to 89?K. Our experiment results also indicate that the Cr-doped samples exhibit the characteristics of spin-glass state at low temperature. Moreover, the magnetic hysteresis curves of the doped samples show a weak ferromagnetic (FM) behavior. It is found that the spin-glass state of the Cr-doped samples is due to the competition between AFM superexchange and FM double-exchange interaction, induced by the Cr doping.

  18. Irradiation-enhanced α' precipitation in model FeCrAl alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Edmondson, Philip D.; Briggs, Samuel A.; Yamamoto, Yukinori; Howard, Richard H.; Sridharan, Kumar; Terrani, Kurt A.; Field, Kevin G.

    2016-02-17

    Model FeCrAl alloys with varying compositions (Fe(10–18)Cr(10–6)Al at.%) have been neutron irradiated at ~ 320 to damage levels of ~ 7 displacements per atom (dpa) to investigate the compositional influence on the formation of irradiation-induced Cr-rich α' precipitates using atom probe tomography. In all alloys, significant number densities of these precipitates were observed. Cluster compositions were investigated and it was found that the average cluster Cr content ranged between 51.1 and 62.5 at.% dependent on initial compositions. This is significantly lower than the Cr-content of α' in binary FeCr alloys. As a result, significant partitioning of the Al from themore » α' precipitates was also observed.« less

  19. The response of CR-39 nuclear track detector to 1-9 MeV protons

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sinenian, N.; Rosenberg, M. J.; Manuel, M.; McDuffee, S. C.; Casey, D. T.; Zylstra, A. B.; Rinderknecht, H. G.; Johnson, M. Gatu; Seguin, F. H.; Frenje, J. A.; et al

    2011-10-28

    The response of CR-39 nuclear track detector (TasTrak®) to protons in the energy range of 0.92-9.28 MeV has been studied. Previous studies of the CR-39 response to protons have been extended by examining the piece-to-piece variability in addition to the effects of etch time and etchant temperature; it is shown that the shape of the CR-39 response curve to protons can vary from piece-to-piece. The effects due to the age of CR-39 have also been studied using 5.5 MeV alpha particles over a 5-year period. Track diameters were found to degrade with the age of the CR-39 itself rather thanmore » the age of the tracks, consistent with previous studies utilizing different CR-39 over shorter time periods.« less

  20. Unusual Mott transition in multiferroic PbCrO 3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Shanmin; Zhu, Jinlong; Zhang, Yi; Yu, Xiaohui; Zhang, Jianzhong; Wang, Wendan; Bai, Ligang; Qian, Jiang; Yin, Liang; Sullivan, Neil S.; et al

    2015-11-24

    The Mott insulator in correlated electron systems arises from classical Coulomb repulsion between carriers to provide a powerful force for electron localization. When turning such an insulator into a metal, the so-called Mott transition, is commonly achieved by "bandwidth" control or "band filling." However, both mechanisms deviate from the original concept of Mott, which attributes such a transition to the screening of Coulomb potential and associated lattice contraction. We report a pressure-induced isostructural Mott transition in cubic perovskite PbCrO3. At the transition pressure of similar to 3 GPa, PbCrO3 exhibits significant collapse in both lattice volume and Coulomb potential. Concurrentmore » with the collapse, it transforms from a hybrid multiferroic insulator to a metal. For the first time to our knowledge, these findings validate the scenario conceived by Mott. Close to the Mott criticality at similar to 300 K, fluctuations of the lattice and charge give rise to elastic anomalies and Laudau critical behaviors resembling the classic liquid-gas transition. Moreover, the anomalously large lattice volume and Coulomb potential in the low-pressure insulating phase are largely associated with the ferroelectric distortion, which is substantially suppressed at high pressures, leading to the first-order phase transition without symmetry breaking.« less

  1. Reliability and Failure Modes of Solid-State Lighting Electrical Drivers Subjected to Accelerated Aging

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lall, Pradeep; Sakalaukus, Peter; Davis, Lynn

    2015-02-19

    An investigation of an off-the-shelf solid-state lighting device with the primary focus on the accompanied light-emitting diode (LED) electrical driver (ED) has been conducted. A set of 10 EDs were exposed to temperature humidity life testing of 85% RH and 85 C (85/85) without an electrical bias per the JEDEC standard JESD22-A101C in order to accelerate the ingress of moisture into the aluminum electrolytic capacitor (AEC) and the EDs in order to assess the reliability of the LED drivers for harsh environment applications. The capacitance and equivalent series resistance for each AEC inside the ED were measured using a handheldmore » LCR meter as possible leading indications of failure. The photometric quantities of a single pristine light engine were monitored in order to investigate the interaction between the light engine and the EDs. These parameters were used in assessing the overall reliability of the EDs. In addition, a comparative analysis has been conducted between the 85/85 accelerated test data and a previously published high-temperature storage life accelerated test of 135°C. The results of the 85/85 acceleration test and the comparative analysis are presented in this paper.« less

  2. Breakeven Cost for Residential Photovoltaics in the United States: Key Drivers and Sensitivities (Report Summary) (Presentation)

    SciTech Connect (OSTI)

    Denholm, P.; Margolis, R. M.; Ong, S.; Roberts, B.

    2009-12-01

    "Break-even cost" for photovoltaic (PV) technology is defined as the point where the cost of PV-generated electricity equals the cost of electricity purchased from the grid. Break-even cost is expressed in $/W of an installed system. Achieving break-even cost is a function of many variables. Consequently, break-even costs vary by location and time for a country, such as the United States, with a diverse set of resources, electricity prices, and other variables. In this presentation, we introduce an analysis of PV break-even costs for residential customers in the United States, including an evaluation of some of the key drivers of PV breakeven both regionally and over time. This presentation includes our methodology and presents results for both near-term residential breakeven costs(2009) and future market sensitivities of break-even costs (2015). See also the the report "Break-Even Cost for Residential Photovoltaics in the United States: Key Drivers and Sensitivities". Presentation for NREL/TP-6A2-45991.

  3. Reliability and Failure Modes of Solid-State Lighting Electrical Drivers Subjected to Accelerated Aging

    SciTech Connect (OSTI)

    Lall, Pradeep; Sakalaukus, Peter; Davis, Lynn

    2015-02-19

    An investigation of an off-the-shelf solid-state lighting device with the primary focus on the accompanied light-emitting diode (LED) electrical driver (ED) has been conducted. A set of 10 EDs were exposed to temperature humidity life testing of 85% RH and 85 C (85/85) without an electrical bias per the JEDEC standard JESD22-A101C in order to accelerate the ingress of moisture into the aluminum electrolytic capacitor (AEC) and the EDs in order to assess the reliability of the LED drivers for harsh environment applications. The capacitance and equivalent series resistance for each AEC inside the ED were measured using a handheld LCR meter as possible leading indications of failure. The photometric quantities of a single pristine light engine were monitored in order to investigate the interaction between the light engine and the EDs. These parameters were used in assessing the overall reliability of the EDs. In addition, a comparative analysis has been conducted between the 85/85 accelerated test data and a previously published high-temperature storage life accelerated test of 135°C. The results of the 85/85 acceleration test and the comparative analysis are presented in this paper.

  4. Optimizing and Diversifying Electric Vehicle Driving Range for U.S. Drivers

    SciTech Connect (OSTI)

    Lin, Zhenhong

    2014-08-11

    Properly determining the driving range is critical for accurately predicting the sales and social benefits of battery electric vehicles (BEVs). This study proposes a framework for optimizing the driving range by minimizing the sum of battery price, electricity cost, and range limitation cost referred to as the "range-related cost" as a measurement of range anxiety. The objective function is linked to policy-relevant parameters, including battery cost and price markup, battery utilization, charging infrastructure availability, vehicle efficiency, electricity and gasoline prices, household vehicle ownership, daily driving patterns, discount rate, and perceived vehicle lifetime. Qualitative discussion of the framework and its empirical application to a sample (N=36664) representing new car drivers in the United States is included. The quantitative results strongly suggest that ranges of less than 100 miles are likely to be more popular in the BEV market for a long period of time. The average optimal range among U.S. drivers is found to be largely inelastic. Still, battery cost reduction significantly drives BEV demand toward longer ranges, whereas improvement in the charging infrastructure is found to significantly drive BEV demand toward shorter ranges. In conclusion, the bias of a single-range assumption and the effects of range optimization and diversification in reducing such biases are both found to be significant.

  5. Elise - the next step in development of induction heavy ion drivers for inertial fusion energy

    SciTech Connect (OSTI)

    Lee, E.; Bangerter, R.O.; Celata, C.; Faltens, A.; Fessenden, T.; Peters, C.; Pickrell, J.; Reginato, L.; Seidl, P.; Yu, S.

    1994-11-01

    LBL, with the participation of LLNL and industry, proposes to build Elise, an electric-focused accelerator as the next logical step towards the eventual goal of a heavy-ion induction linac powerful enough to implode or {open_quotes}drive{close_quotes} inertial-confinement fusion targets. Elise will be at full driver scale in several important parameters-most notably line charge density (a function of beam size), which was not explored in earlier experiments. Elise will be capable of accelerating and electrostatically focusing four parallel, full-scale ion beams and will be designed to be extendible, by successive future construction projects, to meet the goal of the USA DOE Inertial Fusion Energy program (IFE). This goal is to address all remaining issues in heavy-ion IFE except target physics, which is currently the responsibility of DOE Defense Programs, and the target chamber. Thus Elise is the first step of a program that will provide a solid foundation of data for further progress toward a driver, as called for in the National Energy Strategy and National Energy Policy Act.

  6. Optimizing and Diversifying Electric Vehicle Driving Range for U.S. Drivers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Zhenhong

    2014-08-11

    Properly determining the driving range is critical for accurately predicting the sales and social benefits of battery electric vehicles (BEVs). This study proposes a framework for optimizing the driving range by minimizing the sum of battery price, electricity cost, and range limitation cost referred to as the "range-related cost" as a measurement of range anxiety. The objective function is linked to policy-relevant parameters, including battery cost and price markup, battery utilization, charging infrastructure availability, vehicle efficiency, electricity and gasoline prices, household vehicle ownership, daily driving patterns, discount rate, and perceived vehicle lifetime. Qualitative discussion of the framework and its empiricalmore » application to a sample (N=36664) representing new car drivers in the United States is included. The quantitative results strongly suggest that ranges of less than 100 miles are likely to be more popular in the BEV market for a long period of time. The average optimal range among U.S. drivers is found to be largely inelastic. Still, battery cost reduction significantly drives BEV demand toward longer ranges, whereas improvement in the charging infrastructure is found to significantly drive BEV demand toward shorter ranges. In conclusion, the bias of a single-range assumption and the effects of range optimization and diversification in reducing such biases are both found to be significant.« less

  7. Optimizing and Diversifying Electric Vehicle Driving Range for U.S. Drivers

    SciTech Connect (OSTI)

    Lin, Zhenhong

    2014-01-01

    Properly determining the driving range is critical for accurately predicting the sales and social benefits of battery electric vehicles (BEVs). This study proposes a framework for optimizing the driving range by minimizing the sum of battery price, electricity cost, and range limitation cost referred to as the range-related cost as a measurement of range anxiety. The objective function is linked to policy-relevant parameters, including battery cost and price markup, battery utilization, charging infrastructure availability, vehicle efficiency, electricity and gasoline prices, household vehicle ownership, daily driving patterns, discount rate, and perceived vehicle lifetime. Qualitative discussion of the framework and its empirical application to a sample (N=36,664) representing new car drivers in the United States is included. The quantitative results strongly suggest that ranges of less than 100 miles are likely to be more popular in the BEV market for a long period of time. The average optimal range among U.S. drivers is found to be largely inelastic. Still, battery cost reduction significantly drives BEV demand toward longer ranges, whereas improvement in the charging infrastructure is found to significantly drive BEV demand toward shorter ranges. The bias of a single-range assumption and the effects of range optimization and diversification in reducing such biases are both found to be significant.

  8. Electronic and magnetic properties of Cr doped graphene; Full potential approach

    SciTech Connect (OSTI)

    Thakur, Jyoti Kashyap, Manish K.; Saini, Hardev S.

    2015-08-28

    The electronic and magnetic properties of pristine and Cr doped graphene have been calculated using WIEN2k implementation of full potential linearized augmented plane wave (FPLAPW) method based on Density Functional Theory (DFT). The exchange and correlation (XC) effects were taken into account by generalized gradient approximation (GGA). The calculated results show that Cr doping introduces appropriate magnetic moment on graphene. The p-d interaction between 3d states of Cr atom and p-states of C atom are responsible for half metallicity in graphene. The calculated Half-metallic behavior of Cr-doped graphene makes it an ideal candidate for spintronic applications.

  9. Phase Diagram of CuCrO2 in a Magnetic Field

    SciTech Connect (OSTI)

    Fishman, Randy Scott

    2011-01-01

    The magnetic phase diagram of CuCrO2 is constructed as a function of magnetic field and anisotropy using a trial spin state built from harmonics of a fundamental ordering wavevector. Whereas the multiferroic phase of CuCrO2 is a modified spin spiral with a 3-sublattice (SL) period, the phase diagram also contains 1-SL, 2-SL, 4-SL, and 5-SL collinear states which may be accessi- ble in the nonstoichiometric compound CuCrO2+ . For small anisotropy, CuCrO2 is predicted to undergo a transition between two modified spiral states with an intervening 3-SL collinear phase.

  10. Structural studies and band gap tuning of Cr doped ZnO nanoparticles

    SciTech Connect (OSTI)

    Srinet, Gunjan Kumar, Ravindra Sajal, Vivek

    2014-04-24

    Structural and optical properties of Cr doped ZnO nanoparticles prepared by the thermal decomposition method are presented. X-ray diffraction studies confirmed the substitution of Cr on Zn sites without changing the wurtzite structure of ZnO. Modified form of W-H equations was used to calculate various physical parameters and their variation with Cr doping is discussed. Significant red shift was observed in band gap, i.e., a band gap tuning is achieved by Cr doping which could eventually be useful for optoelectronic applications.

  11. Magnetic Interaction Reversal In Watermelon Nanostructured Cr-doped Fe Nanoclusters

    SciTech Connect (OSTI)

    Kaur, Maninder; Dai, Qilin; Bowden, Mark E.; Engelhard, Mark H.; Wu, Yaqiao; Tang, Jinke; Qiang, You

    2013-11-11

    Cr-doped core-shell Fe/Fe-oxide nanoclusters (NCs) were synthesized at varied atomic percentages of Cr from 0 at. % to 8 at. %. The low concentrations of Cr (<10 at. %) were selected in order to inhibit the complete conversion of the Fe-oxide shell to Cr2O3 and the Fe core to FeCr alloy. The magnetic interaction in Fe/Fe-oxide NCs (rv25 nm) can be controlled by antiferromagnetic Cr-dopant. We report the origin of r-FeCr phase at very low Cr concentration (2 at. %) unlike in previous studies, and the interaction reversal from dipolar to exchange interaction in watermelon-like Cr-doped core-shell NCs. The giant magnetoresistance (GMR) effect,1,2 where an antiferromagnetic (AFM) exchange coupling exists between two ferromagnetic (FM) layers separated by a certain type of magnetic or non-magnetic spacer,3 has significant potential for application in the magnetic recording industry. Soon after the discovery of the GMR, the magnetic properties of multilayer systems (FeCr) became a subject of intensive study. The application of bulk iron-chromium (Fe-Cr) alloys has been of great interest, as these alloys exhibit favorable prop- erties including corrosion resistance, high strength, hardness, low oxidation rate, and strength retention at elevated temper- ature. However, the structural and magnetic properties of Cr-doped Fe nanoclusters (NCs) have not been investigated in-depth. Of all NCs, Fe-based clusters have unique magnetic properties as well as favorable catalytic characteristics in reactivity, selectivity, and durability.4 The incorporation of dopant of varied type and concentration in Fe can modify its chemical ordering, thereby optimizing its electrical, optical, and magnetic properties and opening up many new applications. The substitution of an Fe atom (1.24 A˚ ) by a Cr atom (1.25 A˚ ) can easily modify the magnetic properties, since (i) the curie temperature (Tc ) of Fe is 1043 K, while Cr is an itinerant AFM with a bulk Neel temperature TN =311 K, and (ii) Fe

  12. Improving thermostability of CrO{sub 2} thin films by doping with Sn

    SciTech Connect (OSTI)

    Ding, Yi; Wang, Ziyu; Liu, Shuo; Shi, Jing; Yin, Di; Yuan, Cheng; Lu, Zhihong; Xiong, Rui

    2014-09-01

    Chromium dioxide (CrO{sub 2}) is an ideal material for spin electronic devices since it has almost 100% spin polarization near Fermi level. However, it is thermally unstable and easily decomposes to Cr{sub 2}O{sub 3} even at room temperature. In this study, we try to improve the thermal stability of CrO{sub 2} thin films by doping with Sn whose oxide has the same structure as CrO{sub 2}. High quality epitaxial CrO{sub 2} and Sn-doped CrO{sub 2} films were grown on single crystalline TiO{sub 2} (100) substrates by chemical vapor deposition. Sn{sup 4+} ions were believed to be doped into CrO{sub 2} lattice and take the lattice positions of Cr{sup 4+}. The magnetic measurements show that Sn-doping leads to a decrease of magnetocrystalline anisotropy. The thermal stabilities of the films were evaluated by annealing the films at different temperatures. Sn-doped films can withstand a temperature up to 510 °C, significantly higher than what undoped films can do (lower than 435 °C), which suggests that Sn-doping indeed enhances the thermal stability of CrO{sub 2} films. Our study also indicates that Sn-doping may not change the essential half metallic properties of CrO{sub 2}. Therefore, Sn-doped CrO{sub 2} is expected to be very promising for applications in spintronic devices.

  13. Melting of Pb Charge Glass and Simultaneous Pb-Cr Charge Transfer in PbCrO3 as the Origin of Volume Collapse

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Runze; Hojo, Hajime; Watanuki, Tetsu; Mizumaki, Masaichiro; Mizokawa, Takashi; Okada, Kengo; Kim, Hyunjeong; Machida, Akihiko; Sakaki, Kouji; Nakamura, Yumiko; et al

    2015-09-15

    A metal to insulator transition in integer or half integer charge systems can be regarded as crystallization of charges. The insulating state tends to have a glassy nature when randomness or geometrical frustration exists. In this paper, we report that the charge glass state is realized in a perovskite compound PbCrO3, which has been known for almost 50 years, without any obvious inhomogeneity or triangular arrangement in the charge system. PbCrO3 has a valence state of Pb2+0.5Pb4+0.5Cr3+O3 with Pb2+–Pb4+ correlation length of three lattice-spacings at ambient condition. A pressure induced melting of charge glass and simultaneous Pb–Cr charge transfer causesmore » an insulator to metal transition and ~10% volume collapse.« less

  14. Global and Regional Ecosystem Modeling: Databases of Model Drivers and Validation Measurements

    SciTech Connect (OSTI)

    Olson, R.J.

    2002-03-19

    Understanding global-scale ecosystem responses to changing environmental conditions is important both as a scientific question and as the basis for making policy decisions. The confidence in regional models depends on how well the field data used to develop the model represent the region of interest, how well the environmental model driving variables (e.g., vegetation type, climate, and soils associated with a site used to parameterize ecosystem models) represent the region of interest, and how well regional model predictions agree with observed data for the region. To assess the accuracy of global model forecasts of terrestrial carbon cycling, two Ecosystem Model-Data Intercomparison (EMDI) workshops were held (December 1999 and April 2001). The workshops included 17 biogeochemical, satellite-driven, detailed process, and dynamic vegetation global model types. The approach was to run regional or global versions of the models for sites with net primary productivity (NPP) measurements (i.e., not fine-tuned for specific site conditions) and analyze the model-data differences. Extensive worldwide NPP data were assembled with model driver data, including vegetation, climate, and soils data, to perform the intercomparison. This report describes the compilation of NPP estimates for 2,523 sites and 5,164 0.5{sup o}-grid cells under the Global Primary Production Data Initiative (GPPDI) and the results of the EMDI review and outlier analysis that produced a refined set of NPP estimates and model driver data. The EMDI process resulted in 81 Class A sites, 933 Class B sites, and 3,855 Class C cells derived from the original synthesis of NPP measurements and associated driver data. Class A sites represent well-documented study sites that have complete aboveground and below ground NPP measurements. Class B sites represent more numerous ''extensive'' sites with less documentation and site-specific information available. Class C cells represent estimates of NPP for 0.5{sup o

  15. Metastable bcc phase formation in the Nb-Cr-Ti system

    SciTech Connect (OSTI)

    Thoma, D.J.; Perepezko, J.H.

    1994-08-01

    Metastable disordered bcc phases have been formed from the melt in the Nb-Cr-Ti system where primary Laves phases would develop under equilibrium solidification conditions. Three vertical temperature-composition sections in the ternary system incorporating NbCr, were evaluated: the Nb-Cr binary, the TiCr{sub 2}-NbCr{sub 2} isoplethal section, and the NbCr{sub 2}-Ti plethal section. In the rapid solidification of NbCr{sub 2}, metastable bcc phase formation was not observed, but deviations from NbCr{sub 2} stoichiometry or alloying with Ti was found to promote bcc phase formation by decreasing the required liquid undercooling to reach the metastable bcc liquidus and solidus. The metastable phases were characterized through x-ray diffraction (XRD), and systematic deviations from Vegard`s Rule have been defined in the three plethal sections. The metastable bcc phases decompose at temperatures >800{degrees}C to uniformly refined microstructures. As a result, novel microstructural tailoring schemes are possible through the metastable precursor microstructures.

  16. Structural, thermal, and photoacoustic study of nanocrystalline Cr{sub 3}Ge produced by mechanical alloying

    SciTech Connect (OSTI)

    Prates, P. B.; Maliska, A. M.; Ferreira, A. S.; Borges, Z. V.; Lima, J. C. de

    2015-10-21

    A thermodynamic analysis of the Cr-Ge system suggested that it was possible to produce a nanostructured Cr{sub 3}Ge phase by mechanical alloying. The same analysis showed that, due to low activation energies, Cr-poor crystalline and/or amorphous alloy could also be formed. In fact, when the experiment was performed, Cr{sub 11}Ge{sub 19} and amorphous phases were present for small milling times. For milling times larger than 15 h these additional phases decomposed and only the nanostructured Cr{sub 3}Ge phase remained up to the highest milling time used (32 h). From the differential scanning calorimetry measurements, the Avrami exponent n was obtained, indicating that the nucleation and growth of the nanostructured Cr{sub 3}Ge phase may be restricted to one or two dimensions, where the Cr and Ge atoms diffuse along the surface and grain boundaries. In addition, contributions from three-dimensional diffusion with a constant nucleation rate may be present. The thermal diffusivity of the nanostructured Cr{sub 3}Ge phase was determined by photoacoustic absorption spectroscopy measurements.

  17. Audit Report: CR-B-95-02 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5-02 Audit Report: CR-B-95-02 November 10, 1994 Audit of Management Controls Over Selected Energy Research Major System Acquisitions Audit Report: CR-B-95-02 (1.84 MB) More Documents & Publications Audit Report: IG-0389 Audit Report: IG-0403 Audit Report: IG-0476

  18. Audit Report: CR-MA-95-02 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MA-95-02 Audit Report: CR-MA-95-02 February 10, 1995 Management Advisory Report on Universities Research Association's Documentation and Technical Closeout Activities Audit Report: CR-MA-95-02 (535.76 KB) More Documents & Publications Audit Report: IG-0389 Audit Report: IG-0407 Audit Report: IG-0520

  19. Solid state phase equilibria and intermetallic compounds of the Al-Cr-Ho system

    SciTech Connect (OSTI)

    Pang, Mingjun; SAIC-GM-Wuling Automobile Co., Ltd., Liuzhou, Guangxi 545007 ; Zhan, Yongzhong; Du, Yong

    2013-02-15

    The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C were experimentally investigated. The phase relations at 500 Degree-Sign C are governed by 14 three-phase regions, 29 two-phase regions and 15 single-phase regions. The existences of 10 binary compounds and 2 ternary phases have been confirmed. Al{sub 11}Cr{sub 2}, Al{sub 11}Cr{sub 4} and Al{sub 17}Ho{sub 2} were not found at 500 Degree-Sign C. Crystal structures of Al{sub 9}Cr{sub 4} and Al{sub 8}Cr{sub 4}Ho were determined by the Rietveld X-ray powder data refinement. Al{sub 9}Cr{sub 4} was found to exhibit cubic structure with space group I4-bar 3m (no. 217) and lattice parameters a=0.9107(5) nm. Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} structure type with space group I4/mmm (no. 139) and lattice parameters a=0.8909(4) nm, c=0.5120(5) nm. It is concluded that the obtained Al{sub 4}Cr phase in this work should be {mu}-Al{sub 4}Cr by comparing with XRD pattern of the hexagonal {mu}-Al{sub 4}Mn compound. - Graphical abstract: The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Al-Cr-Ho system has been investigated. Black-Right-Pointing-Pointer Al{sub 9}Cr{sub 4} has cubic structure with space group I4-bar 3m. Black-Right-Pointing-Pointer Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} type with space group I4/mmm. Black-Right-Pointing-Pointer Al{sub 4}Cr phase is {mu}-type at 500 Degree-Sign C.

  20. HIGH-POWER FFAG-BASED HEAVY-ION AND PROTON DRIVERS

    SciTech Connect (OSTI)

    RUGGIERO,A.

    2007-10-01

    Fixed-Field Alternating-Gradient (FFAG) accelerators are being proposed as an alternative to Super-conducting Linacs (SCL), Rapid-Cycling Synchrotrons (RCS) and Cyclotrons for the acceleration of very intense Heavy-Ion and Proton beams in the medium energy range. One application is the acceleration of ions of Uranium-238 to an energy of 400 MeV/u, and the average power of 400 kWatt, and the other a 1-GeV Proton Driver with an average beam power of 10 MWatt. One or two FFAG rings are needed for acceleration of both beams. They adopt a Non-Scaling Lattice (NSL) to reduce the size and the cost of the accelerator. The continuous wave (CW) mode of operation is achieved with the method of Harmonic Number Jump (HNJ).

  1. Laser-seeded modulation instability in a proton driver plasma wakefield accelerator

    SciTech Connect (OSTI)

    Siemon, Carl; Khudik, Vladimir; Austin Yi, S.; Shvets, Gennady; Pukhov, Alexander

    2013-10-15

    A new method for initiating the modulation instability (MI) of a proton beam in a proton driver plasma wakefield accelerator using a short laser pulse preceding the beam is presented. A diffracting laser pulse is used to produce a plasma wave that provides a seeding modulation of the proton bunch with the period equal to that of the plasma wave. Using the envelope description of the proton beam, this method of seeding the MI is analytically compared with the earlier suggested seeding technique that involves an abrupt truncation of the proton bunch. The full kinetic simulation of a realistic proton bunch is used to validate the analytic results. It is further used to demonstrate that a plasma density ramp placed in the early stages of the laser-seeded MI leads to its stabilization, resulting in sustained accelerating electric fields (of order several hundred MV/m) over long propagation distances (∼100–1000 m)

  2. Rotating fiber array molecular driver and molecular momentum transfer device constructed therewith

    DOE Patents [OSTI]

    Milleron, Norman

    1983-01-01

    A rotating fiber array molecular driver is disclosed which includes a magnetically suspended and rotated central hub to which is attached a plurality of elongated fibers extending radially therefrom. The hub is rotated so as to straighten and axially extend the fibers and to provide the fibers with a tip speed which exceeds the average molecular velocity of fluid molecules entering between the fibers. Molecules colliding with the sides of the rotating fibers are accelerated to the tip speed of the fiber and given a momentum having a directional orientation within a relatively narrow distribution angle at a point radially outward of the hub, which is centered and peaks at the normal to the fiber sides in the direction of fiber rotation. The rotating fiber array may be used with other like fiber arrays or with other stationary structures to form molecular momentum transfer devices such as vacuum pumps, molecular separators, molecular coaters, or molecular reactors.

  3. NEUTRON-INDUCED SWELLING OF Fe-Cr BINARY ALLOYS IN FFTF AT ~400 DEGREES C

    SciTech Connect (OSTI)

    Garner, Francis A.; Greenwood, Lawrence R.; Okita, Taira; Sekimura, Naoto; Wolfer, W. G.

    2002-12-31

    The purpose of this effort is to determine the influence of dpa rate, He/dpa ratio and composition on the void swelling of simple binary Fe-Cr alloys. Contrary to the behavior of swelling of model fcc Fe-Cr-Ni alloys irradiated in the same FFTF-MOTA experiment, model bcc Fe-Cr alloys do not exhibit a dependence of swelling on dpa rate at approximately 400 degrees C. This is surprising in that an apparent flux-sensitivity was observed in an earlier comparative irradiation of Fe-Cr binaries conducted in EBR-II and FFTF. The difference in behavior is ascribed to the higher helium generation rates of Fe-Cr alloys in EBR-II compared to that of FFTF, and also the fact that lower dpa rates in FFTF are accompanied by progressively lower helium generation rates.

  4. Computational prediction and characterization of single-layer CrS{sub 2}

    SciTech Connect (OSTI)

    Zhuang, Houlong L.; Blonsky, Michael N.; Hennig, Richard G.; Johannes, Michelle D.

    2014-01-13

    Using first-principles calculations, we predict a previously unreported bulk CrS{sub 2} phase that is stable against competing phases and a low energy dynamically stable single-layer CrS{sub 2} phase. We characterize the electronic, optical, and piezoelectric properties of this single-layer material. Like single-layer MoS{sub 2}, CrS{sub 2} has a direct bandgap and valley polarization. The optical bandgap of CrS{sub 2} is 1.3?eV, close to the ideal bandgap of 1.4?eV for photovoltaic applications. Applying compressive strain increases the bandgap and optical absorbance, transforming it into a promising photocatalyst for solar water splitting. Finally, we show that single-layer CrS{sub 2} possesses superior piezoelectric properties to single-layer MoS{sub 2}.

  5. Cr(VI) Occurrence and Geochemistry in Water From Public-Supply Wells in California

    SciTech Connect (OSTI)

    Izbicki, John A.; Wright, Michael T.; Seymour, Whitney A.; McCleskey, R. Blaine; Fram, Miranda S.; Belitz, Kenneth; Esser, Bradley K.

    2015-08-18

    Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment Program—Priority Basin Project (GAMA—PBP) ranged from less than the study reporting limit (SRL) of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of sampled wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of sampled wells. Cr(VI) data collected for regulatory purposes overestimate Cr(VI) occurrence. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and at higher concentrations in alkaline (pH > 8), oxic water, and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium abundance in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.

  6. Integrated Ecogenomics Study for Bioremediation of Cr(VI) at Hanford 100H Area

    SciTech Connect (OSTI)

    Chakraborty, Romy; Chakraborty, Romy

    2008-08-12

    Hexavalent chromium is a widespread contaminant found in groundwater. In order to stimulate microbially mediated Cr(VI)-reduction, a poly-lactate compound was injected into Cr(VI)-contaminated aquifers at site 100H at Hanford. Investigation of bacterial community composition using high-density DNA microarray analysis of 16S rRNA gene products revealed a stimulation of Pseudomonas, Desulfovibrio and Geobacter species amongst others. Enrichment of these organisms coincided with continued Cr(VI) depletion. Functional gene-array analysis of DNA from monitoring well indicated high abundance of genes involved in nitrate-reduction, sulfate-reduction, iron-reduction, methanogenesis, chromium tolerance/reduction. Clone-library data revealed Psedomonas was the dominant genus in these samples. Based on above results, we conducted lab investigations to study the dominant anaerobic culturable microbial populations present at this site and their role in Cr(VI)-reduction. Enrichments using defined anaerobic media resulted in isolation of an iron-reducing, a sulfate-reducing and a nitrate-reducing isolate among several others. Preliminary 16S rDNA sequence analysis identified the isolates as Geobacter metallireducens, Pseudomonas stutzeri and Desulfovibrio vulgaris species respectively. The Pseudomonas isolate utilized acetate, lactate, glycerol and pyruvate as alternative carbon sources, and reduced Cr(VI). Anaerobic washed cell suspension of strain HLN reduced almost 95?M Cr(VI) within 4 hr. Further, with 100?M Cr(VI) as sole electron-acceptor, cells grew to 4.05 x 107 /ml over 24 h after an initial lag, demonstrating direct enzymatic Cr(VI) reduction coupled to growth. These results demonstrate that Cr(VI)-immobilization at Hanford 100H site could be mediated by direct microbial metabolism in addition to indirect chemical reduction of Cr(VI) by end-products of microbial activity.

  7. Cr(VI) Occurrence and Geochemistry in Water From Public-Supply Wells in California

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Izbicki, John A.; Wright, Michael T.; Seymour, Whitney A.; McCleskey, R. Blaine; Fram, Miranda S.; Belitz, Kenneth; Esser, Bradley K.

    2015-08-18

    Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment Program—Priority Basin Project (GAMA—PBP) ranged from less than the study reporting limit (SRL) of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of sampled wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of sampled wells. Cr(VI) data collected for regulatory purposes overestimate Cr(VI) occurrence. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and atmore » higher concentrations in alkaline (pH > 8), oxic water, and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium abundance in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.« less

  8. Brazil’s Biofuels Scenario: What are the Main Drivers Which will Shape Investments in the Long Term?

    Broader source: Energy.gov [DOE]

    Breakout Session 3C—Fostering Technology Adoption III: International Market Opportunities in Bioenergy Brazil’s Biofuels Scenario: What are the Main Drivers Which will Shape Investments in the Long Term? Artur Milanez, Manager of Biofuels Department, Brazilian Development Bank

  9. Geological characterization of permian submarine fan reservoirs of the driver waterflood unit, Spraberry Trend, Midland Basin, Texas

    SciTech Connect (OSTI)

    Guevara, E.H.

    1989-01-01

    This book discusses the geological characterization and assessment of the relationship between reservoir stratigraphy and oil recovery of the Driver waterflood unit of the Spraberry Trend, Midland Basin, West Texas. In this study , the author focuses on the Driver waterflood unit, which is located in Midland, Glasscock, Upton, and Reagan Counties and is part of the giant Spraberry Trend currently being studied by the Bureau. Gamma-ray logs and scout cards from more than 350 wells and slabbed cores from 2 wells, along with core analyses and production data, provided the main sources of information for the study. Fifteen log-defined genetic-stratigraphic operational units were delineated in the Spraberry Formation and were correlated throughout the study area to define the stratigraphic framework. The text presents net sandstone and siltstone maps, cross sections, depth plots of core analyses, and maps of production data. The author describes the depositional systems and hydrocarbon distribution in the Driver unit (currently operated by Standard Oil), details the influence of reservoir stratigraphy on oil recovery, and outlines opportunities for additional recovery. He notes that reservoir management strategies must take into account the stratigraphic heterogeneities of accumulations in the unit. He concludes that a program of selective recompletions and infill drilling based on knowledge of both reservoir stratigraphy and natural fractures is the key to improving oil recovery from the Driver unit in particular and from the Spraberry Trend in general.

  10. Development of ODS FeCrAl alloys for accident-tolerant fuel cladding

    SciTech Connect (OSTI)

    Dryepondt, Sebastien N.; Hoelzer, David T.; Pint, Bruce A.; Unocic, Kinga A.

    2015-09-18

    FeCrAl alloys are prime candidates for accident-tolerant fuel cladding due to their excellent oxidation resistance up to 1400 C and good mechanical properties at intermediate temperature. Former commercial oxide dispersion strengthened (ODS) FeCrAl alloys such as PM2000 exhibit significantly better tensile strength than wrought FeCrAl alloys, which would alloy for the fabrication of a very thin (~250 m) ODS FeCrAl cladding and limit the neutronic penalty from the replacement of Zr-based alloys by Fe-based alloys. Several Fe-12-Cr-5Al ODS alloys where therefore fabricated by ball milling FeCrAl powders with Y2O3 and additional oxides such as TiO2 or ZrO2. The new Fe-12Cr-5Al ODS alloys showed excellent tensile strength up to 800 C but limited ductility. Good oxidation resistance in steam at 1200 and 1400 C was observed except for one ODS FeCrAl alloy containing Ti. Rolling trials were conducted at 300, 600 C and 800 C to simulate the fabrication of thin tube cladding and a plate thickness of ~0.6mm was reached before the formation of multiple edge cracks. Hardness measurements at different stages of the rolling process, before and after annealing for 1h at 1000 C, showed that a thinner plate thickness could likely be achieved by using a multi-step approach combining warm rolling and high temperature annealing. Finally, new Fe-10-12Cr-5.5-6Al-Z gas atomized powders have been purchased to fabricate the second generation of low-Cr ODS FeCrAl alloys. The main goals are to assess the effect of O, C, N and Zr contents on the ODS FeCrAl microstructure and mechanical properties, and to optimize the fabrication process to improve the ductility of the 2nd gen ODS FeCrAl while maintaining good mechanical strength and oxidation resistance.

  11. Progress in the material development of LiCaAlF sub 6 :Cr sup 3+ laser crystals

    SciTech Connect (OSTI)

    Michelle D. Shinn.; Chase, L.L.; Caird, J.A.; Payne, S.A.; Atherton, L.J.; Kway, W.L.

    1990-03-01

    High Cr{sup 3+} doping levels, up to 8 mole percent, and low losses have been obtained with the tunable solid-state laser material LiCaAlF{sub 6}:Cr{sup 3+} (Cr:LiCAF). Measurements and calculations show that high pumping and extraction efficiencies are possible with the improved material. 13 refs., 4 figs., 1 tab.

  12. Magnetic properties and hyperfine interactions in Cr{sub 8}, Cr{sub 7}Cd, and Cr{sub 7}Ni molecular rings from {sup 19}F-NMR

    SciTech Connect (OSTI)

    Bordonali, L.; Borsa, F.; Consorzio INSTM, Via Giusti 9, I-50121 Firenze; Department of Physics and Astronomy, Ames Laboratory, Iowa State University, Ames, Iowa 50011 ; Garlatti, E.; Dipartimento di Fisica e Scienze della Terra, Università di Parma, Viale G. P. Usberti 7 Casadei, C. M.; Department of Physics and Astronomy, Ames Laboratory, Iowa State University, Ames, Iowa 50011 ; Furukawa, Y.; Lascialfari, A.; Consorzio INSTM, Via Giusti 9, I-50121 Firenze; Department of Physics, Università degli Studi di Milano, Via Celoria 16, 20133 Milano ; Carretta, S.; Timco, G.; Winpenny, R. E. P.

    2014-04-14

    A detailed experimental investigation of the {sup 19}F nuclear magnetic resonance is made on single crystals of the homometallic Cr{sub 8} antiferromagnetic molecular ring and heterometallic Cr{sub 7}Cd and Cr{sub 7}Ni rings in the low temperature ground state. Since the F{sup −} ion is located midway between neighboring magnetic metal ions in the ring, the {sup 19}F-NMR spectra yield information about the local electronic spin density and {sup 19}F hyperfine interactions. In Cr{sub 8}, where the ground state is a singlet with total spin S{sub T} = 0, the {sup 19}F-NMR spectra at 1.7 K and low external magnetic field display a single narrow line, while when the magnetic field is increased towards the first level crossing field, satellite lines appear in the {sup 19}F-NMR spectrum, indicating a progressive increase in the Boltzmann population of the first excited state S{sub T} = 1. In the heterometallic rings, Cr{sub 7}Cd and Cr{sub 7}Ni, whose ground state is magnetic with S{sub T} = 3/2 and S{sub T} = 1/2, respectively, the {sup 19}F-NMR spectrum has a complicated structure which depends on the strength and orientation of the magnetic field, due to both isotropic and anisotropic transferred hyperfine interactions and classical dipolar interactions. From the {sup 19}F-NMR spectra in single crystals we estimated the transferred hyperfine constants for both the F{sup −}-Ni{sup 2+} and the F{sup −}-Cd{sup 2+} bonds. The values of the hyperfine constants compare well to the ones known for F{sup −}-Ni{sup 2+} in KNiF{sub 3} and NiF{sub 2} and for F{sup −}-Cr{sup 3+} in K{sub 2}NaCrF{sub 6}. The results are discussed in terms of hybridization of the 2s, 2p orbitals of the F{sup −} ion and the d orbitals of the magnetic ion. Finally, we discuss the implications of our results for the electron-spin decoherence.

  13. Ferromagnetic superexchange in insulating Cr2MoO6 by controlling orbital hybridization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, M.; Do, D.; Dela Cruz, Clarina R.; Dun, Zhiling; Cheng, J. -G.; Goto, H.; Uwatoko, Yoshiya; Zou, T.; Zhou, Haidon D.; Mahanti, Subhendra D.; et al

    2015-09-11

    We report the magnetic and electronic structures of the newly synthesized inverse-trirutile compound Cr2MoO6. Despite the same crystal symmetry and similar bond-lengths and bond-angles to Cr2TeO6, Cr2MoO6 possesses a magnetic structure of the Cr2MoO6 type, different from that seen in Cr2TeO6. Ab-initio electronic structure calculations show that the sign and strength of the Cr-O-Cr exchange coupling is strongly influenced by the hybridization between Mo 4d and O 2p orbitals. This result further substantiates our recently proposed mechanism for tuning the exchange interaction between two magnetic atoms by modifying the electronic states of the non-magnetic atoms in the exchange path throughmore » orbital hybridization. This approach is fundamentally different from the conventional methods of controlling the exchange interaction by either carrier injection or through structural distortions.« less

  14. Probe Mssbauer spectroscopy of mechanical alloying in binary Cr?{sup 57}Fe(1 at%) system

    SciTech Connect (OSTI)

    Elsukov, Evgeny P. Kolodkin, Denis A. Ul'yanov, Alexander L. Porsev, Vitaly E.

    2014-10-27

    Solid state reactions during mechanical alloying (MA) in a binary mixture of powdered Cr and {sup 57}Fe in atomic ratio of 99:1 have been studied using {sup 57}Fe Mssbauer spectroscopy, X-ray diffraction and Auger spectrometry. The proposed model of MA includes formation of Cr(Fe){sub x}O{sub y} oxides at the contact places of Cr and Fe particles, formation of nanostructure with simultaneous dissolution of the oxides, penetration of Fe atoms along grain boundaries in close-to-boundary distorted zones of interfaces in a substitutional position, formation of the substitutional solid solution of Fe in Cr in the body of grains. It was shown that the increase in the BCC lattice parameter on increasing the milling time is due to the dissolution of oxides and formation of interstitial solid solution of O in Cr. There were established substantial differences in consumption of BCC Fe in a Mg ? Al ? Si ? Cr sequence due to the major role of chemical interaction of Mg(Al,Si,Cr) with Fe.

  15. Temperature-dependent study of ion-channeling in Fe/Cr superlattices

    SciTech Connect (OSTI)

    Rueders, F.; Rehn, L.E.; Baldo, P.M.; Fullerton, E.E.; Bader, S.D.

    1996-05-01

    Giant-Magneto-Resistance (GMR), as large as 150% at 4K, occurs in Fe/Cr superlattices as a result of antiferromagnetic interlayer coupling. The authors have successfully grown epitaxial single-crystal Fe/Cr multilayers using magnetron sputtering. Ion channeling was employed to study the structural and vibrational properties of the sputter-deposited Fe/Cr superlattices, and of a Cr thin film, between temperatures of 100 and 330K. Channeling in the latter specimen was used to investigate the importance of depositing a Cr buffer-layer in order to obtain superlattices with large GMR values. Once the buffer layer exceeded a critical thickness, a high quality Cr film was observed. The epitaxial quality of the superlattices grown on such buffer layers by sputtering was found to be excellent. Minimum yields nearly equal to theoretical predictions were found for channeling along the <001> growth direction; slightly higher values were found along the <111> axis. Because of the high structural quality of the sputter-deposited films, it was possible to investigate changes in thermal vibration amplitudes, even though their magnitude is only of the order of a few pm (10{sup {minus}12} m). No unusual structural changes of this magnitude were observed in angular channeling scans obtained while cooling the Fe/Cr superlattice form 330 down to 100 K.

  16. Effects of competing magnetic interactions on the electronic transport properties of CuCrSe{sub 2}

    SciTech Connect (OSTI)

    Tewari, Girish C.; Jawaharlal Nehru University, New Delhi 110067 ; Karppinen, Maarit; Rastogi, Ashok K.

    2013-02-15

    We have synthesized single-phase samples of the CuCrSe{sub 2} phase that exhibits hexagonal-rhombohedral layered crystal structure with space group R3m. Here we present a detailed study of electronic transport and magnetic properties of CuCrSe{sub 2}. We moreover investigate the heat capacity of CuCrSe{sub 2} in comparison to that of CuCrS{sub 2}. The electrical resistivity of CuCrSe{sub 2} shows metallic-like behavior down to 2 K, while the thermoelectric power is large around 100 {mu}V K{sup -1} at 300 K. A weak anomaly in resistivity and a rounded maximum in magnetic susceptibility are observed around 55 K. No sharp transition at 55 K is observed in the heat capacity of CuCrSe{sub 2}, rather a visible maximum is seen. At low temperatures from 2 to 14 K, the magnetic heat capacity follows T{sup 2}-dependence. We tentatively believe this behavior of CuCrSe{sub 2} to be due to competing magnetic interactions between intralayer Cr atoms. The ferromagnetic Cr-Se-Cr indirect exchange among intralayer Cr atoms is enhanced in the selenide compound (that is more metallic than the sulfide compound), and competes with the antiferromagnetic Cr-Cr direct interactions. The interlayer antiferromagnetic exchange through Cu atoms leads to magnetic ordering at low temperature at T{sub N}=55 K. - Graphical abstract: Comparison of magnetic properties of CuCrSe{sub 2} and CuCrS{sub 2} indicates a sharp cusp-like anomaly in magnetic susceptibility at the antiferromagnetic transition of CuCrS{sub 2} while the maximum of CuCrSe{sub 2} is well rounded. Magnetization is reversible after field-cooling (FC) and zero-field-cooling (ZFC) for both compounds. Highlights: Black-Right-Pointing-Pointer Layered CuCrSe{sub 2} can be synthesized in both fully and partially cation-ordered forms. Black-Right-Pointing-Pointer Contrary to previously believed insulating nature the cation-ordered phase is metallic. Black-Right-Pointing-Pointer Magnetic property of CuCrSe{sub 2} is somewhat different from

  17. Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Experiments And Simulation

    SciTech Connect (OSTI)

    Devaraj, Arun; Kaspar, Tiffany C.; Ramanan, Sathvik; Walvekar, Sarita K.; Bowden, Mark E.; Shutthanandan, V.; Kurtz, Richard J.

    2014-11-21

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxial (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation it is very challenging to characterize by conventional techniques. Therefor laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr0.61Mo0.39, Cr0.77Mo0.23, and Cr0.32V0.68 alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were thus confirmed.

  18. Nanoscale phase separation in epitaxial Cr-Mo and Cr-V alloy thin films studied using atom probe tomography: Comparison of experiments and simulation

    SciTech Connect (OSTI)

    Devaraj, A.; Ramanan, S.; Walvekar, S.; Bowden, M. E.; Shutthanandan, V.; Kaspar, T. C.; Kurtz, R. J.

    2014-11-21

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxy (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However, the presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation, it is very challenging to characterize by conventional techniques. Therefore, laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr{sub 0.61}Mo{sub 0.39}, Cr{sub 0.77}Mo{sub 0.23}, and Cr{sub 0.32}V{sub 0.68} alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus, the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were confirmed.

  19. Thermodynamic Modeling and Experimental Study of the Fe-Cr-Zr System

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Bei, Hongbin; Busby, Jeremy T

    2013-01-01

    Wide applications of zircaloys, stainless steels and their interactions in nuclear reactors require the knowledge on phase stability and thermodynamic property of the Fe-Cr-Zr system. This knowledge is also important to develop new Zr-contained Fe-Cr ferritic steels. This work aims at developing thermodynamic models for describing phase stability and thermodynamic property of the Fe-Cr-Zr system using the Calphad approach coupled with experimental study. Thermodynamic descriptions of the Fe-Cr and Cr-Zr systems were either directly adopted or slightly modified from literature. The Fe-Zr system has been remodeled to accommodate recent ab-initio calculation of formation enthalpies of various Fe-Zr compounds. Reliable ternary experimental data and thermodynamic models were mainly available in the Zr-rich region. Therefore, selected ternary alloys located in the vicinity of the eutectic valley of (Fe,Cr,Zr) and (Fe,Cr)2Zr laves phase in the Fe-rich region have been experimentally investigated in this study. Microstructure has been examined by using scanning electron microscope, energy-dispersive Xray spectroscopy and X-ray diffraction. These experimental results, along with the literature data were then used to develop thermodynamic models for phases in the Fe-Cr-Zr system. Calculated phase equilibria and thermodynamic properties of the ternary system yield satisfactory agreements with available experimental data, which gives the confidence to use these models as building blocks for developing a Zr, Fe and Cr contained multicomponent thermodynamic database for broader applications in nuclear reactors.

  20. Influence of cassette type on the DQE of CR systems

    SciTech Connect (OSTI)

    Monnin, P.; Holzer, Z.; Wolf, R.; Neitzel, U.; Vock, P.; Gudinchet, F.; Verdun, F. R.

    2006-10-15

    In our recent paper by Monnin et al. [Med. Phys.33, 411-420 (2006)], an objective analysis of the relative performance of a computed radiography (CR) system using both standard single-side (ST-VI) and prototype dual-side read (ST-BD) plates was reported. The presampled modulation transfer function (MTF), noise power spectrum (NPS), and detective quantum efficiency (DQE) for the systems were determined at three different beam qualities representative of paediatric chest radiography, at an entrance detector air kerma of 5 {mu}Gy. Experiments demonstrated that, compared to the standard single-side read system, the MTF for the dual-side read system was slightly reduced, but a significant decrease in image noise resulted in a marked increase in DQE (+40%) in the low spatial frequency range. However, the DQE improvement for the ST-BD plate decreased with increasing spatial frequency, and, at spatial frequencies above 2.2 mm{sup -1}, the DQE of the dual-side read system was lower than that of the single-side one.

  1. Steamside Oxidation Behavior of Experimental 9%Cr Steels

    SciTech Connect (OSTI)

    Dogan, O.N.; Holcomb, G.R.; Alman, D.E.; Jablonski, P.D.

    2007-10-01

    Reducing emissions and increasing economic competitiveness require more efficient steam power plants that utilize fossil fuels. One of the major challenges in designing these plants is the availability of materials that can stand the supercritical and ultra-supercritical steam conditions at a competitive cost. There are several programs around the world developing new ferritic and austenitic steels for superheater and reheater tubes exposed to the advanced steam conditions. The new steels must possess properties better than current steels in terms of creep strength, steamside oxidation resistance, fireside corrosion resistance, and thermal fatigue resistance. This paper introduces a series of experimental 9%Cr steels containing Cu, Co, and Ti. Stability of the phases in the new steels is discussed and compared to the phases in the commercially available materials. The steels were tested under both the dry and moist conditions at 650C for their cyclical oxidation resistance. Results of oxidation tests are presented. Under the moist conditions, the experimental steels exhibited significantly less mass gain compared to the commercial P91 steel. Microstructural characterization of the scale revealed different oxide compositions.

  2. Electrochemical Testing of Ni-Cr-Mo-Gd Alloys

    SciTech Connect (OSTI)

    T. E. Lister; R. E. Mizia; H. Tian

    2005-10-01

    The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

  3. CASL - Mixing and non-stoichiometry in Fe-Ni-Cr-Zn-O spinel compounds:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Density functional theory calculations Mixing and non-stoichiometry in Fe-Ni-Cr-Zn-O spinel compounds: Density functional theory calculations Mixing and non-stoichiometry in Fe-Ni-Cr-Zn-O spinel compounds: Density functional theory calculations D.A. Andersson and C.R. Stanek Materials Science and Technology Division Los Alamos National Laboratory Density functional theory (DFT) calculations have been employed to better understand the thermodynamic properties of AB2O4 (where A=Fe2+, Ni2+ or

  4. Epitaxial Cr on n-SrTiO3(001)An ideal Ohmic contact

    SciTech Connect (OSTI)

    Capan, Cigdem; Sun, Guangyuan; Bowden, Mark E.; Chambers, Scott A.

    2012-01-30

    Epitaxial Cr metallizations grown on n-SrTiO3(001) by molecular beam epitaxy are shown to result in an ordered interface with Cr bound to O in the terminal TiO2 layer, no reduction of the SrTiO3, and a near-perfect Ohmic contact. Cr/n-SrTiO3(001) thus constitutes an ideal interface between a pure metal and wide gap oxide in which interface redox chemistry does not occur, and the Fermi level remains unpinned.

  5. Epitaxial Cr on n-SrTiO{sub 3}(001) - An ideal Ohmic contact

    SciTech Connect (OSTI)

    Capan, C.; Sun, G. Y.; Bowden, M. E.; Chambers, S. A.

    2012-01-30

    Epitaxial Cr metallizations grown on n-SrTiO{sub 3}(001) by molecular beam epitaxy are shown to result in an ordered interface with Cr bound to O in the terminal TiO{sub 2} layer, no reduction of the SrTiO{sub 3}, and a near-perfect Ohmic contact. Cr/n-SrTiO{sub 3}(001) thus constitutes an ideal interface between a pure metal and wide gap oxide in which interface redox chemistry does not occur, and the Fermi level remains unpinned.

  6. Hydrothermal synthesis and magnetic properties of ErCrO{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Sundarayya, Y. Kumar, K. Ashwini Sondge, Rajesh Srinath, S. Kaul, S. N.

    2014-04-24

    Homogeneous single phase ErCrO{sub 4} nanoparticles have been synthesized by a modified sol-gel followed by hydrothermal method. X-ray diffraction reveals that the compound crystallizes into tetragonal structure with space group I41/amd. The average crystallite size was estimated to be 21(1) nm. Morphological analysis of the sample confirms uniform particles of size 20 nm. DC magnetic measurements show that ErCrO{sub 4} undergoes a paramagnetic-antiferromagnetic transition at 16 K, due to the superexchange Er-O-Cr-O-Er antiferromagnetic interactions.

  7. Oxygen-induced immediate onset of the antiferromagnetic stacking in thin Cr films on Fe(001)

    SciTech Connect (OSTI)

    Berti, Giulia Brambilla, Alberto; Calloni, Alberto; Bussetti, Gianlorenzo; Finazzi, Marco; Duò, Lamberto; Ciccacci, Franco

    2015-04-20

    We investigated the magnetic coupling of ultra-thin Cr films grown at 600 K on a Fe(001)-p(1 × 1)O substrate by means of spin-polarized photoemission spectroscopy. Our findings show that the expected antiferromagnetic stacking of the magnetization in Cr(001) layers occurs right from the first atomic layer at the Cr/Fe interface. This is at variance with all previous observations in similar systems, prepared in oxygen-free conditions, which always reported on a delayed onset of the magnetic oscillations due to the occurrence of significant chemical alloying at the interface, which is substantially absent in our preparation.

  8. Remediation of Cr(VI) by biogenic magnetic nanoparticles: An x-ray magnetic circular dichroism study

    SciTech Connect (OSTI)

    Telling, N. D.; Coker, V. S.; Cutting, R. S.; van der Laan, G.; Pearce, C. I.; Pattrick, R. A. D.; Arenholz, E.; Lloyd, J. R.

    2009-09-04

    Biologically synthesized magnetite (Fe{sub 3}O{sub 4}) nanoparticles are studied using x-ray absorption and x-ray magnetic circular dichroism following exposure to hexavalent Cr solution. By examining their magnetic state, Cr cations are shown to exist in trivalent form on octahedral sites within the magnetite spinel surface. The possibility of reducing toxic Cr(VI) into a stable, non-toxic form, such as a Cr{sup 3+}-spinel layer, makes biogenic magnetite nanoparticles an attractive candidate for Cr remediation.

  9. The Preparation of an Ultrastable Mesoporous Cr(III)-MOF via...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abstract: Kinetic labilization of the Fe(III)-O coordination bond in a mesoporous metal-organic framework, PCN-333-Fe(III), is realized by the reduction of Fe(III) by Cr(II). The ...

  10. Cr/B4C multilayer mirrors: Study of interfaces and X-ray reflectance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burcklen, C.; Soufli, R.; Gullikson, E.; Meltchakov, E.; Dennetiere, D.; Polack, F.; Capitanio, B.; Thomasset, M.; Jerome, A.; de Rossi, S.; et al

    2016-03-24

    Here, we present an experimental study of the effect of layer interfaces on the x-ray reflectance in Cr/B4C multilayer interference coatings with layer thicknesses ranging from 0.7 nm to 5.4 nm. The multilayers were deposited by magnetron sputtering and by ion beam sputtering. Grazing incidence x-ray reflectometry, soft x-ray reflectometry, and transmission electron microscopy reveal asymmetric multilayer structures with a larger B4C-on-Cr interface, which we modeled with a 1–1.5 nm thick interfacial layer. Reflectance measurements in the vicinity of the Cr L2,3 absorption edge demonstrate fine structure that is not predicted by simulations using the currently tabulated refractive index (opticalmore » constants) values for Cr.« less

  11. Qualification of welded super 13%Cr martensitic stainless steels for the Sgard field

    SciTech Connect (OSTI)

    Enerhaug, J.; Kvaale, P.E.; Bjordal, M.; Drugli, J.M.; Rogne, T.

    1999-11-01

    A test program was conducted to qualify welded super 13%Cr (S13%Cr) stainless steel for the Asgard Field, a mildly sour service. The test program involved girth welding, optimization of post weld heat treatment (PWHT) cycles, assessment of mechanical properties, examination of low cycle fatigue testing, and different corrosion testing and evaluation of S13%Cr steels from three different steel mills. The alloy with 0.015%C max, 11.9%Cr min, 2.4%Mo min and 6.O%Ni min, has been qualified for use as flowline material in the actual field. The results show acceptable weldability and corrosion properties. Post weld heat treatment (PWHT) of the welds improved the resistance against sulfide stress corrosion cracking.

  12. Audit Report: CR-B-99-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Audit Report: CR-B-99-01 October 1, 1998 Department's Working Capital Fund The Department established the Working Capital Fund (Fund) in January 1996 as a financial management tool ...

  13. Audit Report: CR-B-97-04 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 1997 Audit of Controls Over the ADP Support Services Contract PDF icon Audit Report: CR-B-97-04 More Documents & Publications Audit of Selected Hazardous Waste Remedial Actions ...

  14. Audit Report: CR-B-02-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Audit Report: CR-B-02-01 October 15, 2001 Fixed-Price Contracting for Department of ... The objective of our audit was to determine if the cost savings anticipated from the use ...

  15. Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional...

    Office of Scientific and Technical Information (OSTI)

    As a result, the ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable ... Type: Accepted Manuscript Journal Name: Journal of Materials Chemistry. C Additional ...

  16. Half-metallic ferromagnetism in Cr-doped semiconducting Ge-chalcogenide: Density functional approach

    SciTech Connect (OSTI)

    Saini, Hardev S.; Singh, Mukhtiyar; Thakur, Jyoti; Kashyap, Manish K.

    2014-04-24

    A supercell approach has been used to calculate the electronic and magnetic properties of Cr-doped Ge chalcogenide, Ge{sub 1−x}Cr{sub x}Te (x = 0.25 and 0.125). The calculations have been performed using full potential Linear Augmented Plane Wave (FPLAPW) method within generalized gradient approximation (GGA) as exchange-correlation (XC) potential. The calculated results show that the doping of Cr induces the 100% spin polarization at Fermi level (EF) and showed the robust half metallic ferromagnetism in this compound. Thus, the compound at both dopant concentrations behave as dilute magnetic semiconductor (DMS) showing metallic property in majority and semiconducting for minority spin channels which is best suited for spintronic applications. The total magnetic moments of this compound are mainly due to Cr-d states present at E{sup F} with negligible contribution from electronic states of other atoms.

  17. Process for producing Ti-Cr-Al-O thin film resistors

    DOE Patents [OSTI]

    Jankowski, Alan F.; Schmid, Anthony P.

    2001-01-01

    Thin films of Ti-Cr-Al-O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti-Cr-Al-O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti-Cr-Al-O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti-Cr-Al-O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  18. Flat panel display using Ti-Cr-Al-O thin film

    DOE Patents [OSTI]

    Jankowski, Alan F.; Schmid, Anthony P.

    2002-01-01

    Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

  19. Cr(VI) reduction in aqueous solutions by using copper smelter slag

    SciTech Connect (OSTI)

    Kiyak, B.; Oezer, A.; Altundogan, H.S.; Erdem, M.; Tuemen, F. )

    1999-01-01

    The ability of Copper Smelter Slag (CSS) to reduce Cr(VI) in aqueous solutions has been investigated. The extent of reduction if dependent on the amounts of acid and reductant, contact time, Cr(VI) concentration, temperature of the solution and particle size of CSS. The amount of acid is the most important variable affecting the reduction process. When twice the amount of acid required with respect to Cr(VI) was used, Cr(VI) in 100 ml solution (100 mg/l) was completely reduced in a contact period less than 5 min by a 10 g/l dosage of CSS. Reduction efficiency increased with increase in temperature of solution, showing that the process is endothermic. Reduced chromium, and iron and other metals dissolved from CSS were effectively precipitated by using NaOH or calcinated carbonation sludge from sugar plant.

  20. Cr(VI) reduction in aqueous solutions by using copper smelter slag

    SciTech Connect (OSTI)

    Kiyak, B.; Oezer, A.; Altundogan, H.S.; Erdem, M.; Tuemen, F.

    1999-11-01

    The ability of Copper Smelter Slag (CSS) to reduce Cr(VI) in aqueous solutions has been investigated. The extent of reduction if dependent on the amounts of acid and reductant, contact time, Cr(VI) concentration, temperature of the solution and particle size of CSS. The amount of acid is the most important variable affecting the reduction process. When twice the amount of acid required with respect to Cr(VI) was used, Cr(VI) in 100 ml solution (100 mg/l) was completely reduced in a contact period less than 5 min by a 10 g/l dosage of CSS. Reduction efficiency increased with increase in temperature of solution, showing that the process is endothermic. Reduced chromium, and iron and other metals dissolved from CSS were effectively precipitated by using NaOH or calcinated carbonation sludge from sugar plant.

  1. Development of a Full-core Reactivity Equivalence for FeCrAl...

    Office of Scientific and Technical Information (OSTI)

    Reactivity Equivalence for FeCrAl Enhanced Accident Tolerant Fuel in BWRs Citation Details In-Document Search Title: Development of a Full-core Reactivity Equivalence for ...

  2. In Situ Long-Term Reductive Bioimmobilization of Cr(VI) in Groundwater...

    Office of Scientific and Technical Information (OSTI)

    injection into Cr(VI)-contaminated groundwater stimulates an average increase in biomass by up to 50 times, from-5105 to 2.5107 cellsmL. The results also show a...

  3. A pseudo binary y-Gd solidification diagram for Ni-Cr-Mo-Gd alloys...

    Office of Scientific and Technical Information (OSTI)

    Title: A pseudo binary y-Gd solidification diagram for Ni-Cr-Mo-Gd alloys. No abstract prepared. Authors: Dupont, John Neuman 1 ; Minicozzi, Michael J. 1 ; Robino, Charles ...

  4. Microstructural Stability of 9-12 Cr Steels at Elevated Temperatures

    SciTech Connect (OSTI)

    Dogan, Omer N.; Hawk, Jeffrey A.

    2005-09-01

    The objective of this report is to explore new substitutional solute solution (Cu, Co) and precipitate (TiC) hardening mechanisms for improved strength of 9-12 Cr martensitic steels.

  5. Irradiation creep of the US Heat 832665 of V-4Cr-4Ti (Journal...

    Office of Scientific and Technical Information (OSTI)

    The paper presents irradiation creep data for V-4Cr-4Ti irradiated to 3.7 dpa at 425 and 600 C in the HFIR-17J experiment. Creep deformation was characterized by measuring ...

  6. C/CrC nanocomposite coating deposited by magnetron sputtering at high ion irradiation conditions

    SciTech Connect (OSTI)

    Zhou, Z.; Rainforth, W. M.; Gass, M. H.; Bleloch, A.; Ehiassarian, A. P.; Hovsepian, P. Eh.

    2011-10-01

    CrC with the fcc NaCl (B1) structure is a metastable phase that can be obtained under the non-equilibrium conditions of high ion irradiation. A nano-composite coating consisting of amorphous carbon embedded in a CrC matrix was prepared via the unbalanced magnetron sputtering of graphite and Cr metal targets in Ar gas with a high ionized flux (ion-to-neutral ratio Ji/Jn = 6). The nanoscale amorphous carbon clusters self-assembled into layers alternated by CrC, giving the composite a multilayer structure. The phase, microstructure, and composition of the coating were characterized using x-ray diffraction, transmission electron microscopy, and aberration corrected scanning transmission electron microscopy coupled with electron energy loss spectroscopy. The interpretation of the true coating structure, in particular the carbide type, is discussed.

  7. Microsoft Word - chapter FeNiCrMo_ver4.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The carbon and alloy steel categories selected for the Technical Reference for Hydrogen ... Since a full range of data is not available for each steel, data for all Ni-Cr-Mo steels ...

  8. Audit Report: CR-B-95-05 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    of the Federal Enegy Regulatory Commission's Office of Chief Accountant Audit Report: CR-B-95-05 More Documents & Publications Audit Report: IG-0811 Audit Manual Audit Report:...

  9. Optical Absorption and Band Gap Reduction in (Fe 1-x Cr x ) 2...

    Office of Scientific and Technical Information (OSTI)

    Broadening of the valence band due to hybridization of the O 2p states with Fe and Cr 3d states also contributes to band gap reduction. Authors: Wang, Yong ; Lopata, Kenneth ; ...

  10. Exceptionally high glass-forming ability of an FeCoCrMoCBY alloy...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Exceptionally ... Here we report the exceptionally high GFA of an FeCoCrMoCBY ... OSTI Identifier: 20702296 Resource Type: Journal Article ...

  11. Studies Of Coherent Synchrotron Radiation And Longitudinal Space Charge In The Jefferson Lab FEL Driver

    SciTech Connect (OSTI)

    Tennant, Christopher D.; Douglas, David R.; Li, Rui; Tsai, C.-Y.

    2014-12-01

    The Jefferson Laboratory IR FEL Driver provides an ideal test bed for studying a variety of beam dynamical effects. Recent studies focused on characterizing the impact of coherent synchrotron radiation (CSR) with the goal of benchmarking measurements with simulation. Following measurements to characterize the beam, we quantitatively characterized energy extraction via CSR by measuring beam position at a dispersed location as a function of bunch compression. In addition to operating with the beam on the rising part of the linac RF waveform, measurements were also made while accelerating on the falling part. For each, the full compression point was moved along the backleg of the machine and the response of the beam (distribution, extracted energy) measured. Initial results of start-to-end simulations using a 1D CSR algorithm show remarkably good agreement with measurements. A subsequent experiment established lasing with the beam accelerated on the falling side of the RF waveform in conjunction with positive momentum compaction (R56) to compress the bunch. The success of this experiment motivated the design of a modified CEBAF-style arc with control of CSR and microbunching effects.

  12. Simple Limits on Achieving A Quasi-Linear Magnetic Compression for an FEL Driver

    SciTech Connect (OSTI)

    Sun, Yipeng; /SLAC

    2012-02-16

    Free electron lasers (FEL) need a very bright electron beam in three dimensions and a high peak charge density. In order to compress an initially longer electron bunch generated from the photoinjector, magnetic bunch compression systems are widely employed. In this paper, first harmonic RF linearization and its associated requirements are reviewed. Meanwhile it is also briefly discussed what is the relation between a proper initial bunch length and main RF frequency, when a harmonic RF linearization is included. Then given a reasonable bunch compression ratio, a proper initial bunch length as a function of the main RF frequency and RF phase is estimated analytically by several approaches, assuming that no harmonic RF section is needed to linearize the energy modulation introduced during main RF acceleration, and at the same time still linearly compress the bunch length. Next the upper limit of the bunch compression ratio in a single stage is evaluated analytically. The analytical relations derived on choosing a proper initial bunch length as a function of main RF frequency are confirmed by numerical simulation. These simple limit provide rough estimations and may be beneficial for choosing bunch compression ratios in different stages of an FEL driver, especially in a first stage bunch compression where there is usually a harmonic RF linearization applied. It may also be useful in evaluating the possibility of low charge operation mode without any harmonic RF linearization, where a shorter initial bunch length can be achieved from the photoinjector.

  13. Performance of the accelerator driver of Jefferson Laboratory's free-electron laser

    SciTech Connect (OSTI)

    Bohn, C.L.; Benson, S.; Biallas, G.

    1999-04-01

    The driver of Jefferson Lab's kW-level infrared free-electron laser (FEL) is a superconducting, recirculating accelerator that recovers about 75% of the electron-beam power and converts it to radiofrequency power. In achieving first lasing, the accelerator operated straight-ahead to deliver 38 MeV, 1.1 mA cw current through the wiggler for lasing at wavelengths in the vicinity of 5 {mu}m. Just prior to first lasing, measured rms beam properties at the wiggler were 7.5{+-}1.5 mm-mr normalized transverse emittance, 26{+-}7 keV-deg longitudinal emittance, and 0.4{+-}0.1 ps bunch length which yielded a peak current of 60{+-}15A. The waste beam was then sent directly to a dump, bypassing the recirculation loop. Stable operation at up to 311 W cw was achieved in this mode. Commissioning the recirculation loop then proceeded. As of this Conference, the machine has recirculated cw average current up to 4 mA, and has lased cw with energy recover up to 710 W.

  14. Low impedance z-pinch drivers without post-hole convolute current adders.

    SciTech Connect (OSTI)

    Savage, Mark Edward; Seidel, David Bruce; Mendel, Clifford Will, Jr.

    2009-09-01

    Present-day pulsed-power systems operating in the terawatt regime typically use post-hole convolute current adders to operate at sufficiently low impedance. These adders necessarily involve magnetic nulls that connect the positive and negative electrodes. The resultant loss of magnetic insulation results in electron losses in the vicinity of the nulls that can severely limit the efficiency of the delivery of the system's energy to a load. In this report, we describe an alternate transformer-based approach to obtaining low impedance. The transformer consists of coils whose windings are in parallel rather than in series, and does not suffer from the presence of magnetic nulls. By varying the pitch of the coils windings, the current multiplication ratio can be varied, leading to a more versatile driver. The coupling efficiency of the transformer, its behavior in the presence of electron flow, and its mechanical strength are issues that need to be addressed to evaluate the potential of transformer-based current multiplication as a viable alternative to conventional current adder technology.

  15. Design of the SRF Driver ERL for the Jefferson Lab UV FEL

    SciTech Connect (OSTI)

    David R. Douglas; Stephen Benson; George Biallas; Keith Blackburn; James Boyce; Donald Bullard; James Coleman; Cody Dickover; Forrest Ellingsworth; Pavel Evtushenko; Christopher Gould; Joseph Gubeli; Fay Hannon; David Hardy; Carlos Hernandez-Garcia; Kevin Jordan; Michael Klopf; James Kortze; Matthew Marchlik; Steven Moore; George Neil; Thomas Powers; Daniel Sexton; Michelle D. Shinn; Christopher Tennant; Richard Walker; Frederick Wilson; Shukui Zhang

    2011-03-01

    We describe the design of the SRF Energy-Recovering Linac (ERL) providing the CW electron drive beam at the Jefferson Lab UV FEL. Based on the same 135 MeV linear accelerator as – and sharing portions of the recirculator with – the Jefferson Lab 10 kW IR Upgrade FEL, the UV driver ERL uses a novel bypass geometry to provide transverse phase space control, bunch length compression, and nonlinear aberration compensation (including correction of RF curvature effects) without the use of magnetic chicanes or harmonic RF. Stringent phase space requirements at the wiggler, low beam energy, high beam current, and use of a pre-existing facility and legacy hardware subject the design to numerous constraints. These are imposed not only by the need for both transverse and longitudinal phase space management, but also by the potential impact of collective phenomena (space charge, wakefields, beam break-up (BBU), and coherent synchrotron radiation (CSR)), and by interactions between the FEL and the accelerator RF system. This report addresses these issues and presents the accelerator design solution that is now in operation.

  16. Use of Multipass Recirculation and Energy Recovery In CW SRF X-FEL Driver Accelerators

    SciTech Connect (OSTI)

    Douglas, David; Akers, Walt; Benson, Stephen V.; Biallas, George; Blackburn, Keith; Boyce, James; Bullard, Donald; Coleman, James; Dickover, Cody; Ellingsworth, Forrest; Evtushenko, Pavel; Fisk, Sally; Gould, Christopher; Gubeli, Joseph; Hannon, Fay; Hardy, David; Hernandez-Garcia, Carlos; Jordan, Kevin; Klopf, John; Kortze, J.; Legg, Robert; Li, Rui; Marchlik, Matthew; Moore, Steven W.; Neil, George; Powers, Thomas; Sexton, Daniel; Shin, Ilkyoung; Shinn, Michelle D.; Tennant, Christopher; Terzic, Balsa; Walker, Richard; Williams, Gwyn P.; Wilson, G.; Zhang, Shukui

    2010-08-01

    We discuss the use of multipass recirculation and energy recovery in CW SRF drivers for short wavelength FELs. Benefits include cost management (through reduced system footprint, required RF and SRF hardware, and associated infrastructure - including high power beam dumps and cryogenic systems), ease in radiation control (low drive beam exhaust energy), ability to accelerate and deliver multiple beams of differing energy to multiple FELs, and opportunity for seamless integration of multistage bunch length compression into the longitudinal matching scenario. Issues include all those associated with ERLs compounded by the challenge of generating and preserving the CW electron drive beam brightness required by short wavelength FELs. We thus consider the impact of space charge, BBU and other environmental wakes and impedances, ISR and CSR, potential for microbunching, intra-beam and beam-residual gas scattering, ion effects, RF transients, and halo, as well as the effect of traditional design, fabrication, installation and operational errors (lattice aberrations, alignment, powering, field quality). Context for the discussion is provided by JLAMP, the proposed VUV/X-ray upgrade to the existing Jefferson Lab FEL.

  17. Heat treatment of NiCrFe alloy 600 to optimize resistance to intergranular stress corrosion

    DOE Patents [OSTI]

    Steeves, A.F.; Bibb, A.E.

    A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprises heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cooling the alloy body, and heating the cooled body to a temperature between 1100 to 1500/sup 0/F for about 1 to 30 hours.

  18. Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion

    DOE Patents [OSTI]

    Steeves, Arthur F.; Bibb, Albert E.

    1984-01-01

    A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

  19. Surface modification to improve fireside corrosion resistance of Fe-Cr ferritic steels

    DOE Patents [OSTI]

    Park, Jong-Hee; Natesan, Krishnamurti; Rink, David L.

    2010-03-16

    An article of manufacture and a method for providing an Fe--Cr ferritic steel article of manufacture having a surface layer modification for corrosion resistance. Fe--Cr ferritic steels can be modified to enhance their corrosion resistance to liquid coal ash and other chemical environments, which have chlorides or sulfates containing active species. The steel is modified to form an aluminide/silicide passivating layer to reduce such corrosion.

  20. Audit Report: CR-B-97-03 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Audit Report: CR-B-97-03 May 6, 1997 Followup Audit on the Procurement of Support Services for the Energy Information Administration Audit Report: CR-B-97-03 (58.94 KB) More Documents & Publications Aligning Contract Incentives & Contract Mgt Trends - David Leotta, Director, Office of Contract Management, OAPM OPAM Policy Acquisition Guides Microsoft Word - AcqGuide16pt1 Nov 2010

  1. Optimizing Cr(VI) and Tc(VII) remediation through nano-scale biomineral engineering

    SciTech Connect (OSTI)

    Cutting, R. S.; Coker, V. S.; Telling, N. D.; Kimber, R. L.; Pearce, C. I.; Ellis, B.; Lawson, R; van der Laan, G.; Pattrick, R.A.D.; Vaughan, D.J.; Arenholz, E.; Lloyd, J. R.

    2009-09-09

    To optimize the production of biomagnetite for the bioremediation of metal oxyanion contaminated waters, the reduction of aqueous Cr(VI) to Cr(III) by two biogenic magnetites and a synthetic magnetite was evaluated under batch and continuous flow conditions. Results indicate that nano-scale biogenic magnetite produced by incubating synthetic schwertmannite powder in cell suspensions of Geobacter sulfurreducens is more efficient at reducing Cr(VI) than either biogenic nano-magnetite produced from a suspension of ferrihydrite 'gel' or synthetic nano-scale Fe{sub 3}O{sub 4} powder. Although X-ray Photoelectron Spectroscopy (XPS) measurements obtained from post-exposure magnetite samples reveal that both Cr(III) and Cr(VI) are associated with nanoparticle surfaces, X-ray Magnetic Circular Dichroism (XMCD) studies indicate that some Cr(III) has replaced octahedrally coordinated Fe in the lattice of the magnetite. Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) measurements of total aqueous Cr in the associated solution phase indicated that, although the majority of Cr(III) was incorporated within or adsorbed to the magnetite samples, a proportion ({approx}10-15 %) was released back into solution. Studies of Tc(VII) uptake by magnetites produced via the different synthesis routes also revealed significant differences between them as regards effectiveness for remediation. In addition, column studies using a {gamma}-camera to obtain real time images of a {sup 99m}Tc(VII) radiotracer were performed to visualize directly the relative performances of the magnetite sorbents against ultra-trace concentrations of metal oxyanion contaminants. Again, the magnetite produced from schwertmannite proved capable of retaining more ({approx}20%) {sup 99m}Tc(VII) than the magnetite produced from ferrihydrite, confirming that biomagnetite production for efficient environmental remediation can be fine-tuned through careful selection of the initial Fe(III) mineral substrate

  2. Networks of ultrasmall Pd/Cr bilayer nanowires as high performance hydrogen sensors.

    SciTech Connect (OSTI)

    Zeng, X.-Q.; Wang, Y.-L.; Deng, H.; Latimer, M. L.; Xiao, Z.-L.; Pearson, J.; Xu, T.; Wang, H.-H.; Welp, U.; Crabtree, G. W.; Kwok, W.-K.

    2011-01-01

    The newly developed hydrogen sensor, based on a network of ultrasmall pure palladium nanowires sputter-deposited on a filtration membrane, takes advantage of single palladium nanowires' characteristics of high speed and sensitivity while eliminating their nanofabrication obstacles. However, this new type of sensor, like the single palladium nanowires, cannot distinguish hydrogen concentrations above 3%, thus limiting the potential applications of the sensor. This study reports hydrogen sensors based on a network of ultrasmall Cr-buffered Pd (Pd/Cr) nanowires on a filtration membrane. These sensors not only are able to outperform their pure Pd counterparts in speed and durability but also allow hydrogen detection at concentrations up to 100%. The new networks consist of a thin layer of palladium deposited on top of a Cr adhesion layer 1-3 nm thick. Although the Cr layer is insensitive to hydrogen, it enables the formation of a network of continuous Pd/Cr nanowires with thicknesses of the Pd layer as thin as 2 nm. The improved performance of the Pd/Cr sensors can be attributed to the increased surface area to volume ratio and to the confinement-induced suppression of the phase transition from Pd/H solid solution ({alpha}-phase) to Pd hydride ({beta}-phase).

  3. Microstructure and Mechanical Properties of n-irradiated Fe-Cr Model Alloys

    SciTech Connect (OSTI)

    Matijasevic, Milena; Al Mazouzi, Abderrahim

    2008-07-01

    High chromium ( 9-12 wt %) ferritic/martensitic steels are candidate structural materials for future fusion reactors and other advanced systems such as accelerator driven systems (ADS). Their use for these applications requires a careful assessment of their mechanical stability under high energy neutron irradiation and in aggressive environments. In particular, the Cr concentration has been shown to be a key parameter to be optimized in order to guarantee the best corrosion and swelling resistance, together with the least embrittlement. In this work, the characterization of the neutron irradiated Fe-Cr model alloys with different Cr % with respect to microstructure and mechanical tests will be presented. The behavior of Fe-Cr alloys have been studied using tensile tests at different temperature range ( from -160 deg. C to 300 deg. C). Irradiation-induced microstructure changes have been studied by TEM for two different irradiation doses at 300 deg. C. The density and the size distribution of the defects induced have been determined. The tensile test results indicate that Cr content affects the hardening behavior of Fe-Cr binary alloys. Hardening mechanisms are discussed in terms of Orowan type of approach by correlating TEM data to the measured irradiation hardening. (authors)

  4. Radiation Tolerance of Neutron-Irradiated Model Fe-Cr-Al Alloys

    SciTech Connect (OSTI)

    Field, Kevin G; Hu, Xunxiang; Littrell, Ken; Yamamoto, Yukinori; Snead, Lance Lewis

    2015-01-01

    The Fe Cr Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe Cr Al alloys has not been fully established. In this study, a series of Fe Cr Al alloys with 10 18 wt % Cr and 2.9 4.9 wt % Al were neutron irradiated at 382 C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2 111 and a 100 were detected and quantified. Results indicate precipitation of Cr-rich is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. A structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich precipitates at sufficiently high chromium contents after irradiation.

  5. Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Ming -Wei; Zhung, Houlong L.; Yan, Jiaqiang; Ward, Thomas Zac; Puretzky, Alexander A.; Rouleau, Christopher M.; Gai, Zheng; Liang, Liangbo; Meunier, Vincent; Ganesh, Panchapakesan; et al

    2015-11-27

    Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have recently shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained elusive. In this work we for the first time exfoliate the CrSiTe3, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO2 substrate. The Raman spectra show the good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra ofmore » 2D CrSiTe3, giving a strong evidence for the existence of 2D CrSiTe3 crystals. When the thickness of the CrSiTe3 crystals is reduced to few-layers, we observed a clear change in resistivity at 80~120 K, consistent with the theoretical calculations on the Curie temperature (Tc) of ~80 K for the magnetic ordering of 2D CrSiTe3 crystals. As a result, the ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable numerous applications in nano-spintronics.« less

  6. Magnetic properties and spin polarization of Ru doped half metallic CrO{sub 2}

    SciTech Connect (OSTI)

    West, Kevin G.; Dao, Nam N. H.; Lu, Jiwei; Osofsky, Michael; Mazin, I. I.; Wolf, Stuart A.

    2015-07-06

    Chromium dioxide (CrO{sub 2}) is a half metal that is of interest for spintronic devices. It has not been synthesized through traditional physical vapor deposition (PVD) techniques because of its thermodynamic instability in low oxygen pressures. Epitaxial thin films of Ru doped tetragonal rutile CrO{sub 2} were synthesized by a PVD technique. The as-deposited Ru{sub x}Cr{sub 1−x}O{sub 2} was ferrimagnetic with the saturation magnetization moment showing a strong dependence on the Ru concentration. Curie temperature as high as 241 K has been obtained for ∼23 at. % Ru. The Ru substitution increased the electrical conductivity by increasing the minority spin concentration. The spin polarization was found to be as high as 70% for 9 at. % Ru and decreased to ∼60% with Ru concentrations up to ∼44 at. %, which is determined by the Fermi velocities of the majority and minority spins. First principle calculations were performed to understand the effect of Ru content on the properties of CrO{sub 2}. The PVD processes of Ru doped CrO{sub 2} could lead to the practical applications of the high spin polarization of CrO{sub 2} in spintronic devices.

  7. Hydrogen permeation in FeCrAl alloys for LWR cladding application

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Xunxiang; Terrani, Kurt A.; Wirth, Brian D.; Snead, Lance L.

    2015-03-19

    FeCrAl is an advanced oxidation-resistant iron-based alloy class, is a highly prevalent candidate as an accident-tolerant fuel cladding material. Compared with traditional zirconium alloy fuel cladding, increased tritium permeation through FeCrAl fuel cladding to the primary coolant is expected, raising potential safety concerns. In our study, the hydrogen permeability of several FeCrAl alloys was obtained using a static permeation test station, which was calibrated and validated using 304 stainless steel. The high hydrogen permeability of FeCrAl alloys leads to concerns with respect to potentially significant tritium release when used for fuel cladding in LWRs. Also, the total tritium inventory insidemore » the primary coolant of a light water reactor was quantified by applying a 1-dimensional steady state tritium diffusion model to demonstrate the dependence of tritium inventory on fuel cladding type. Furthermore, potential mitigation strategies for tritium release from FeCrAl fuel cladding were discussed and indicate the potential for application of an alumina layer on the inner clad surface to serve as a tritium barrier. More effort is required to develop a robust, economical mitigation strategy for tritium permeation in reactors using FeCrAl clad fuel assemblies.« less

  8. Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Field, Kevin G.; Hu, Xunxiang; Littrell, Kenneth C.; Yamamoto, Yukinori; Snead, Lance Lewis

    2015-07-14

    The Fe Cr Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe Cr Al alloys has not been fully established. In this study, a series of Fe Cr Al alloys with 10 18 wt % Cr and 2.9 4.9 wt % Al were neutron irradiated at 382 C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition.more » Dislocation loops with Burgers vector of a/2 111 and a 100 were detected and quantified. Results indicate precipitation of Cr-rich is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. Furthermore, a structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich α' precipitates at sufficiently high chromium contents after irradiation.« less

  9. Hydrogen permeation in FeCrAl alloys for LWR cladding application

    SciTech Connect (OSTI)

    Hu, Xunxiang; Terrani, Kurt A.; Wirth, Brian D.; Snead, Lance L.

    2015-03-19

    FeCrAl is an advanced oxidation-resistant iron-based alloy class, is a highly prevalent candidate as an accident-tolerant fuel cladding material. Compared with traditional zirconium alloy fuel cladding, increased tritium permeation through FeCrAl fuel cladding to the primary coolant is expected, raising potential safety concerns. In our study, the hydrogen permeability of several FeCrAl alloys was obtained using a static permeation test station, which was calibrated and validated using 304 stainless steel. The high hydrogen permeability of FeCrAl alloys leads to concerns with respect to potentially significant tritium release when used for fuel cladding in LWRs. Also, the total tritium inventory inside the primary coolant of a light water reactor was quantified by applying a 1-dimensional steady state tritium diffusion model to demonstrate the dependence of tritium inventory on fuel cladding type. Furthermore, potential mitigation strategies for tritium release from FeCrAl fuel cladding were discussed and indicate the potential for application of an alumina layer on the inner clad surface to serve as a tritium barrier. More effort is required to develop a robust, economical mitigation strategy for tritium permeation in reactors using FeCrAl clad fuel assemblies.

  10. Radiation tolerance of neutron-irradiated model Fe-Cr-Al alloys

    SciTech Connect (OSTI)

    Field, Kevin G.; Hu, Xunxiang; Littrell, Kenneth C.; Yamamoto, Yukinori; Snead, Lance Lewis

    2015-07-14

    The Fe Cr Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe Cr Al alloys has not been fully established. In this study, a series of Fe Cr Al alloys with 10 18 wt % Cr and 2.9 4.9 wt % Al were neutron irradiated at 382 C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2 111 and a 100 were detected and quantified. Results indicate precipitation of Cr-rich is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. Furthermore, a structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich α' precipitates at sufficiently high chromium contents after irradiation.

  11. Molecular beam epitaxy growth and magnetic properties of Cr-Co-Ga Heusler alloy films

    SciTech Connect (OSTI)

    Feng, Wuwei Wang, Weihua; Zhao, Chenglong; Van Quang, Nguyen; Cho, Sunglae; Dung, Dang Duc

    2015-11-15

    We have re-investigated growth and magnetic properties of Cr{sub 2}CoGa films using molecular beam epitaxy technique. Phase separation and precipitate formation were observed experimentally again in agreement with observation of multiple phases separation in sputtered Cr{sub 2}CoGa films by M. Meinert et al. However, significant phase separation could be suppressed by proper control of growth conditions. We showed that Cr{sub 2}CoGa Heusler phase, rather than Co{sub 2}CrGa phase, constitutes the majority of the sample grown on GaAs(001) at 450 {sup o}C. The measured small spin moment of Cr{sub 2}CoGa is in agreement with predicted HM-FCF nature; however, its Curie temperature is not as high as expected from the theoretical prediction probably due to the off-stoichiometry of Cr{sub 2}CoGa and the existence of the disorders and phase separation.

  12. Anodic reactions in the Ca/CaCrO/sub 4/ thermal battery

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1985-09-01

    The reaction of Ca with a CaCrO/sub 4/-(LiCl-KCl eutectic) solution at temperatures of 400/sup 0/C to 500/sup 0/C was studied to better understand the nature of the chemical reactions and electrochemical processes that occur in the Ca/CaCrO/sub 4/ thermal battery at the anode during activation and discharge. Limited tests also were conducted with a CaCrO/sub 4/-(CaCl/sub 2/-NaCl-KCl eutectic) solution at 550/sup 0/C. Ca/CaCrO/sub 4/ and CaLi/sub 2//CaCrO/sub 4/ single cells were tested to observe the relative performance differences of Ca and CaLi/sub 2/ anodes. The discharged cells were analyzed by optical microscopy, electron microprobe, Auger electron spectroscopy, and secondary-ion mass spectroscopy. These analytical data were used in conjunction with the results of chemical-reaction experiments to propose a discharge mechanism for the Ca/CaCrO/sub 4/ thermal battery, consistent with experimental observations.

  13. Assessing Energy Impact of Plug-In Hybrid Electric Vehicles: Significance of Daily Distance Variation over Time and Among Drivers

    SciTech Connect (OSTI)

    Lin, Zhenhong [ORNL; Greene, David L [ORNL

    2012-01-01

    Accurate assessment of the impact of plug-in hybrid electric vehicles (PHEVs) on petroleum and electricity consumption is a necessary step toward effective policies. Variations in daily vehicle miles traveled (VMT) over time and among drivers affect PHEV energy impact, but the significance is not well understood. This paper uses a graphical illustration, a mathematical derivation, and an empirical study to examine the cause and significance of such an effect. The first two methods reveal that ignoring daily variation in VMT always causes underestimation of petroleum consumption and overestimation of electricity consumption by PHEVs; both biases increase as the assumed PHEV charge-depleting (CD) range moves closer to the average daily VMT. The empirical analysis based on national travel survey data shows that the assumption of uniform daily VMT over time and among drivers causes nearly 68% underestimation of expected petroleum use and nearly 48% overestimation of expected electricity use by PHEVs with a 40-mi CD range (PHEV40s). Also for PHEV40s, consideration of daily variation in VMT over time but not among drivers similar to the way the utility factor curve is derived in SAE Standard SAE J2841 causes underestimation of expected petroleum use by more than 24% and overestimation of expected electricity use by about 17%. Underestimation of petroleum use and overestimation of electricity use increase with larger-battery PHEVs.

  14. Feasibility of developing a portable driver performance data acquisition system for human factors research: Design specifications. Volume 3

    SciTech Connect (OSTI)

    Carter, R.J.; Barickman, F.S.

    1998-01-01

    A two-phase, multi-year research program entitled ``development of a portable driver performance data acquisition system for human factors research was recently completed. The primary objective of the project was to develop a portable data acquisition system for crash avoidance research (DASCAR) that will allow driver performance data to be collected using a large variety of vehicle types and that would be capable of being installed on a given vehicle type within a relatively short-time frame. During Phase 1 a feasibility study for designing and fabricating DASCAR was conducted. In phase 2 of the research DASCAR was actually developed and validated. This technical memorandum documents the results from the feasibility study. It is subdivided into three volumes. Volume one addresses the last five items in the phase 1 research and the first issue in the second phase of the project. Volume 2 presents the related appendices. Volume three (this report) displays the design specifications developed for DASCAR during the ``develop design requirements and specifications for a portable driver performance data acquisition system`` task. Design specifications were assembled for each DASCAR element. The specifications were prepared in sufficient detail to allow a third party to use them to design, develop, procure, and subsequently construct the data acquisition system. This report also covers the background to the program.

  15. Electronic structure, magnetism, and antisite disorder in CoFeCrGe and CoMnCrAl quaternary Heusler alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Enamullah, .; Venkateswara, Y.; Gupta, Sachin; Varma, Manoj Raama; Singh, Prashant; Suresh, K. G.; Alam, Aftab

    2015-12-10

    In this study, we present a combined theoretical and experimental study of two quaternary Heusler alloys CoFeCrGe (CFCG) and CoMnCrAl (CMCA), promising candidates for spintronics applications. Magnetization measurement shows the saturation magnetization and transition temperature to be 3 μB, 866 K and 0.9 μB, 358 K for CFCG and CMCA respectively. The magnetization values agree fairly well with our theoretical results and also obey the Slater-Pauling rule, a prerequisite for half metallicity. A striking difference between the two systems is their structure; CFCG crystallizes in fully ordered Y-type structure while CMCA has L21 disordered structure. The antisite disorder adds amore » somewhat unique property to the second compound, which arises due to the probabilistic mutual exchange of Al positions with Cr/Mn and such an effect is possibly expected due to comparable electronegativities of Al and Cr/Mn. Ab initio simulation predicted a unique transition from half metallic ferromagnet to metallic antiferromagnet beyond a critical excess concentration of Al in the alloy.« less

  16. Electronic structure, magnetism, and antisite disorder in CoFeCrGe and CoMnCrAl quaternary Heusler alloys

    SciTech Connect (OSTI)

    Enamullah, .; Venkateswara, Y.; Gupta, Sachin; Varma, Manoj Raama; Singh, Prashant; Suresh, K. G.; Alam, Aftab

    2015-12-10

    In this study, we present a combined theoretical and experimental study of two quaternary Heusler alloys CoFeCrGe (CFCG) and CoMnCrAl (CMCA), promising candidates for spintronics applications. Magnetization measurement shows the saturation magnetization and transition temperature to be 3 μB, 866 K and 0.9 μB, 358 K for CFCG and CMCA respectively. The magnetization values agree fairly well with our theoretical results and also obey the Slater-Pauling rule, a prerequisite for half metallicity. A striking difference between the two systems is their structure; CFCG crystallizes in fully ordered Y-type structure while CMCA has L21 disordered structure. The antisite disorder adds a somewhat unique property to the second compound, which arises due to the probabilistic mutual exchange of Al positions with Cr/Mn and such an effect is possibly expected due to comparable electronegativities of Al and Cr/Mn. Ab initio simulation predicted a unique transition from half metallic ferromagnet to metallic antiferromagnet beyond a critical excess concentration of Al in the alloy.

  17. High pressure synthesis and properties of Bi{sub 0.5}Pb{sub 0.5}CrO{sub 3}: A novel Cr{sup 4+}/Cr{sup 3+} perovskite

    SciTech Connect (OSTI)

    Pirrotta, Ivan; Schmidt, Rainer; Morán, Emilio; and others

    2015-05-15

    We have synthesized a new Bi{sub 0.5}Pb{sub 0.}5CrO{sub 3} perovskite phase by means of a high pressure reaction at 70 kbar and 1000 °C. The distorted orthorhombic perovskite structure can be indexed in the space group Pnma with lattice parameters a=5.4768 (1) Å, b=7.7450 (2) Å, and c=5.4574 (1) Å at room temperature, but undergoes a structural phase transition and enters into a P2{sub 1}/m monoclinic distorted perovskite phase below 150 K with a=5.4173 (2), b=7.7286 (4) and c=5.4930 (3). The structural transition is coincident with the onset of magnetic interactions. At lower temperatures a weak ferromagnetic structure is evident related to antiferromagnetic Cr-spin canting and a spin-glass transition is observed at ≈40 K. The semiconducting-type electrical resistivity is relatively low, associated with Cr{sup 3+}/Cr{sup 4+} electron hopping, and shows considerable magneto-resistance (up to 15%). Due to the low resistivity the dielectric permittivity ε{sub r} could be determined only below T<80 K to be ≈300 and did not show any strong temperature-dependence. Ferroelectricity was not detected in the T-range investigated and no magnetocapacitance effects were observed. - Graphical abstract: A new Bi{sub 0.5}Pb{sub 0.}5CrO{sub 3} perovskite phase has been synthesized under high pressure (70 kbar) and high temperature (1000 °C) conditions. The room temperature structure is orthorhombic and can be indexed in the space group Pnma but below 150 K undergoes a structural phase transition and enters into a P2{sub 1}/m monoclinic distorted perovskite phase. The structural transition is coincident with the onset of magnetic interactions. Mott variable-range hopping charge transport and magnetoresistance effects are evident. - Highlights: • A new Bi{sub 0.5}Pb{sub 0.}5CrO{sub 3} perovskite has been synthesized under HP/HT conditions. • An orthorhombic-to monoclinic phase transition takes place at 150 K. • The structural transition is coincident with the onset

  18. An insight into actual energy use and its drivers in high-performance buildings

    SciTech Connect (OSTI)

    Li, Cheng; Hong, Tianzhen; Yan, Da

    2014-07-12

    Using portfolio analysis and individual detailed case studies, we studied the energy performance and drivers of energy use in 51 high-performance office buildings in the U.S., Europe, China, and other parts of Asia. Portfolio analyses revealed that actual site energy use intensity (EUI) of the study buildings varied by a factor of as much as 11, indicating significant variation in real energy use in HPBs worldwide. Nearly half of the buildings did not meet the American Society of Heating, Refrigerating, and Air Conditioning Engineers (ASHRAE) Standard 90.1-2004 energy target, raising questions about whether a building’s certification as high performing accurately indicates that a building is energy efficient and suggesting that improvement in the design and operation of HPBs is needed to realize their energy-saving potential. We studied the influence of climate, building size, and building technologies on building energy performance and found that although all are important, none are decisive factors in building energy use. EUIs were widely scattered in all climate zones. There was a trend toward low energy use in small buildings, but the correlation was not absolute; some small HPBs exhibited high energy use, and some large HPBs exhibited low energy use. We were unable to identify a set of efficient technologies that correlated directly to low EUIs. In two case studies, we investigated the influence of occupant behavior as well as operation and maintenance on energy performance and found that both play significant roles in realizing energy savings. We conclude that no single factor determines the actual energy performance of HPBs, and adding multiple efficient technologies does not necessarily improve building energy performance; therefore, an integrated design approach that takes account of climate, technology, occupant behavior, and operations and maintenance practices should be implemented to maximize energy savings in HPBs. As a result, these findings are

  19. First Argon Gas Puff Experiments With 500 ns Implosion Time On Sphinx Driver

    SciTech Connect (OSTI)

    Zucchini, F.; Calamy, H.; Lassalle, F.; Loyen, A.; Maury, P.; Grunenwald, J.; Georges, A.; Morell, A.; Bedoch, J.-P.; Ritter, S.; Combes, P.; Smaniotto, O.; Lample, R.; Coleman, P. L.; Krishnan, M.

    2009-01-21

    Experiments have been performed at the SPHINX driver to study potential of an Argon Gas Puff load designed by AASC. We present here the gas Puff hardware and results of the last shot series.The Argon Gas Puff load used is injected thanks to a 20 cm diameter nozzle. The nozzle has two annuli and a central jet. The pressure and gas type in each of the nozzle plena can be independently adjusted to tailor the initial gaz density distribution. This latter is selected as to obtain an increasing radial density from outer shell towards the pinch axis in order to mitigate the RT instabilities and to increase radiating mass on axis. A flashboard unit produces a high intensity UV source to pre-ionize the Argon gas. Typical dimensions of the load are 200 mm in diameter and 40 mm height. Pressures are adjusted to obtain an implosion time around 550 ns with a peak current of 3.5 MA.With the goal of improving k-shell yield a mass scan of the central jet was performed and implosion time, mainly given by outer and middle plena settings, was kept constant. Tests were also done to reduce the implosion time for two configurations of the central jet. Strong zippering of the radiation production was observed mainly due to the divergence of the central jet over the 40 mm of the load height. Due to that feature k-shell radiation is mainly obtained near cathode. Therefore tests were done to mitigate this effect first by adjusting local pressure of middle and central jet and second by shortening the pinch length.At the end of this series, best shot gave 5 kJ of Ar k-shell yield. PCD detectors showed that k-shell x-ray power was 670 GW with a FWHM of less than 10 ns.

  20. Energy for 500 Million Homes: Drivers and Outlook for Residential Energy Consumption in China

    SciTech Connect (OSTI)

    Zhou, Nan; McNeil, Michael A.; Levine, Mark

    2009-06-01

    China's rapid economic expansion has propelled it to the rank of the largest energy consuming nation in the world, with energy demand growth continuing at a pace commensurate with its economic growth. The urban population is expected to grow by 20 million every year, accompanied by construction of 2 billion square meters of buildings every year through 2020. Thus residential energy use is very likely to continue its very rapid growth. Understanding the underlying drivers of this growth helps to identify the key areas to analyze energy efficiency potential, appropriate policies to reduce energy use, as well as to understand future energy in the building sector. This paper provides a detailed, bottom-up analysis of residential building energy consumption in China using data from a wide variety of sources and a modelling effort that relies on a very detailed characterization of China's energy demand. It assesses the current energy situation with consideration of end use, intensity, and efficiency etc, and forecast the future outlook for the critical period extending to 2020, based on assumptions of likely patterns of economic activity, availability of energy services, technology improvement and energy intensities. From this analysis, we can conclude that Chinese residential energy consumption will more than double by 2020, from 6.6 EJ in 2000 to 15.9 EJ in 2020. This increase will be driven primarily by urbanization, in combination with increases in living standards. In the urban and higher income Chinese households of the future, most major appliances will be common, and heated and cooled areas will grow on average. These shifts will offset the relatively modest efficiency gains expected according to current government plans and policies already in place. Therefore, levelling and reduction of growth in residential energy demand in China will require a new set of more aggressive efficiency policies.

  1. An insight into actual energy use and its drivers in high-performance buildings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Cheng; Hong, Tianzhen; Yan, Da

    2014-07-12

    Using portfolio analysis and individual detailed case studies, we studied the energy performance and drivers of energy use in 51 high-performance office buildings in the U.S., Europe, China, and other parts of Asia. Portfolio analyses revealed that actual site energy use intensity (EUI) of the study buildings varied by a factor of as much as 11, indicating significant variation in real energy use in HPBs worldwide. Nearly half of the buildings did not meet the American Society of Heating, Refrigerating, and Air Conditioning Engineers (ASHRAE) Standard 90.1-2004 energy target, raising questions about whether a building’s certification as high performing accuratelymore » indicates that a building is energy efficient and suggesting that improvement in the design and operation of HPBs is needed to realize their energy-saving potential. We studied the influence of climate, building size, and building technologies on building energy performance and found that although all are important, none are decisive factors in building energy use. EUIs were widely scattered in all climate zones. There was a trend toward low energy use in small buildings, but the correlation was not absolute; some small HPBs exhibited high energy use, and some large HPBs exhibited low energy use. We were unable to identify a set of efficient technologies that correlated directly to low EUIs. In two case studies, we investigated the influence of occupant behavior as well as operation and maintenance on energy performance and found that both play significant roles in realizing energy savings. We conclude that no single factor determines the actual energy performance of HPBs, and adding multiple efficient technologies does not necessarily improve building energy performance; therefore, an integrated design approach that takes account of climate, technology, occupant behavior, and operations and maintenance practices should be implemented to maximize energy savings in HPBs. As a result, these

  2. Thermal conductivity of nitride films of Ti, Cr, and W deposited by reactive magnetron sputtering

    SciTech Connect (OSTI)

    Jagannadham, Kasichainula

    2015-05-15

    Nitride films of Ti, Cr, and W were deposited using reactive magnetron sputtering from metal targets in argon and nitrogen plasma. TiN films with (200) orientation were achieved on silicon (100) at the substrate temperature of 500 and 600?C. The films were polycrystalline at lower temperature. An amorphous interface layer was observed between the TiN film and Si wafer deposited at 600?C. TiN film deposited at 600?C showed the nitrogen to Ti ratio to be near unity, but films deposited at lower temperature were nitrogen deficient. CrN film with (200) orientation and good stoichiometry was achieved at 600?C on Si(111) wafer but the film deposited at 500?C showed cubic CrN and hexagonal Cr{sub 2}N phases with smaller grain size and amorphous back ground in the x-ray diffraction pattern. An amorphous interface layer was not observed in the cubic CrN film on Si(111) deposited at 600?C. Nitride film of tungsten deposited at 600?C on Si(100) wafer was nitrogen deficient, contained both cubic W{sub 2}N and hexagonal WN phases with smaller grain size. Nitride films of tungsten deposited at 500?C were nonstoichiometric and contained cubic W{sub 2}N and unreacted W phases. There was no amorphous phase formed along the interface for the tungsten nitride film deposited at 600?C on the Si wafer. Thermal conductivity and interface thermal conductance of all the nitride films of Ti, Cr, and W were determined by transient thermoreflectance technique. The thermal conductivity of the films as function of deposition temperature, microstructure, nitrogen stoichiometry and amorphous interaction layer at the interface was determined. Tungsten nitride film containing both cubic and hexagonal phases was found to exhibit much higher thermal conductivity and interface thermal conductance. The amorphous interface layer was found to reduce effective thermal conductivity of TiN and CrN films.

  3. Influence of the hydration by the environmental humidity on the metallic speciation and the photocatalytic activity of Cr/MCM-41

    SciTech Connect (OSTI)

    Elías, Verónica R.; Sabre, Ema V.; Winkler, Elin L.; Andrini, Leandro; Requejo, Félix G.; Casuscelli, Sandra G.; Eimer, Griselda A.

    2014-05-01

    The influence of the environmental humidity on the Cr species deposited on inorganic supports like MCM-41 silicates was analyzed by UV–vis Diffuse Reflectance (UV–vis RD), Electronic Spin Resonance (ESR) and X-ray near-edge (XANES) spectroscopy. Metal speciation could be inferred, finding that prolonged exposure periods under environmental humidity provoked the reduction of the active Cr{sup 6+} species and thus, the decrease of the Cr/MCM-41 photoactivity. After the Ti loading over the Cr modified samples, Cr species and the photoactivity were not notably influenced by the humidity exposure. Thus, it could be concluded that the presence of Ti is important because the TiO{sub 2} cover protects the oxidized Cr species, stabilizing them. - Graphical abstract: The load of Ti on the Cr modified MCM-41 produces a TiO{sub 2} cover that protects the active Cr species from their reduction by the environmental humidity. - Highlights: • Spectroscopic analysis shows presence of Cr{sup 6+}/Cr{sup 5+} in calcined/re-calcined samples. • Cr{sup 3+} species increase for hydrated samples causing their photoactivity decrease. • Samples with high Cr loadings are more sensitive to environmental humidity presence. • TiO{sub 2} cover protects oxidized Cr species from their reduction by the water. • Ti is important to allow a synergistic effect and to stabilize active Cr{sup 6+}/Cr{sup 5+}.

  4. Enhanced piezoelectric output voltage and Ohmic behavior in Cr-doped ZnO nanorods

    SciTech Connect (OSTI)

    Sinha, Nidhi; Ray, Geeta; Godara, Sanjay; Gupta, Manoj K.; Kumar, Binay

    2014-11-15

    Highlights: • Low cost highly crystalline Cr-doped ZnO nanorods were synthesized. • Enhancement in dielectric, piezoelectric and ferroelectric properties were observed. • A high output voltage was obtained in AFM. • Cr-doping resulted in enhanced conductivity and better Ohmic behavior in ZnO/Ag contact. - Abstract: Highly crystalline Cr-doped ZnO nanorods (NRs) were synthesized by solution technique. The size distribution was analyzed by high resolution tunneling electron microscope (HRTEM) and particle size analyzer. In atomic force microscope (AFM) studies, peak to peak 8 mV output voltage was obtained on the application of constant normal force of 25 nN. It showed high dielectric constant (980) with phase transition at 69 °C. Polarization vs. electric field (P–E) loops with remnant polarization (6.18 μC/cm{sup 2}) and coercive field (0.96 kV/cm) were obtained. In I–V studies, Cr-doping was found to reduce the rectifying behavior in the Ag/ZnO Schottky contact which is useful for field effect transistor (FET) and solar cell applications. With these excellent properties, Cr-doped ZnO NRs can be used in nanopiezoelectronics, charge storage and ferroelectric applications.

  5. Magnetic susceptibilities of liquid Cr-Au, Mn-Au and Fe-Au alloys

    SciTech Connect (OSTI)

    Ohno, S.; Shimakura, H.; Tahara, S.; Okada, T.

    2015-08-17

    The magnetic susceptibility of liquid Cr-Au, Mn-Au, Fe-Au and Cu-Au alloys was investigated as a function of temperature and composition. Liquid Cr{sub 1-c}Au{sub c} with 0.5 ≤ c and Mn{sub 1-c}Au{sub c} with 0.3≤c obeyed the Curie-Weiss law with regard to their dependence of χ on temperature. The magnetic susceptibilities of liquid Fe-Au alloys also exhibited Curie-Weiss behavior with a reasonable value for the effective number of Bohr magneton. On the Au-rich side, the composition dependence of χ for liquid TM-Au (TM=Cr, Mn, Fe) alloys increased rapidly with increasing TM content, respectively. Additionally, the composition dependences of χ for liquid Cr-Au, Mn-Au, and Fe-Au alloys had maxima at compositions of 50 at% Cr, 70 at% Mn, and 85 at% Fe, respectively. We compared the composition dependences of χ{sub 3d} due to 3d electrons for liquid binary TM-M (M=Au, Al, Si, Sb), and investigated the relationship between χ{sub 3d} and E{sub F} in liquid binary TM-M alloys at a composition of 50 at% TM.

  6. Irradiation-induced formation of a spinel phase at the FeCr/MgO interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Yun; Yadav, Satyesh Kumar; Aguiar, Jeffery A.; Anderoglu, Osman; Baldwin, Jon Kevin; Wang, Yongqiang; Misra, Amit; Luo, Hongmei; Uberuaga, Blas P.; Li, Nan

    2015-04-27

    Oxide dispersion strengthened ferritic/martensitic alloys have attracted significant attention for their potential uses in future nuclear reactors and storage vessels, as the metal/oxide interfaces act as stable high-strength sinks for point defects while also dispersing helium. Here, in order to unravel the evolution and interplay of interface structure and chemistry upon irradiation in these types of materials, an atomically sharp FeCr/MgO interface was synthesized at 500 °C and separately annealed and irradiated with Ni3+ ions at 500 °C. After annealing, a slight enrichment of Cr atoms was observed at the interface, but no other structural changes were found. However, undermore » irradiation, sufficient Cr diffuses across the interface into the MgO to form a Cr-enriched transition layer that contains spinel precipitates. First-principles calculations indicate that it is energetically favorable to incorporate Cr, but not Fe, substitutionally into MgO. Furthermore, our results indicate that irradiation can be used to form new phases and complexions at interfaces, which may have different radiation tolerance than the pristine structures.« less

  7. Ablation and cone formation mechanism on CR-39 by ArF laser irradiation

    SciTech Connect (OSTI)

    Shakeri Jooybari, B. E-mail: hafarideh@aut.ac.ir; Afarideh, H. E-mail: hafarideh@aut.ac.ir; Lamehi-Rachti, M.; Ghergherehchi, M.

    2015-03-07

    In this work, chemical properties, surface modification, and micro structures formation on ablated polyallyl di-glycol carbonate (CR-39) polymer by ArF laser irradiation (λ = 193 nm) at various fluences and pulse number were investigated. CR-39 samples have been irradiated with an ArF laser (193 nm) at a repetition rate of 1 Hz. Threshold fluence of ablation and effective absorption coefficient of CR-39 were determined. Conical microstructures (Taylor cone) formed on laser-ablated CR-39 exhibit: smooth, Taylor cone shape walls and sharp tips together with interference and well defined fringe-structure with a period of 230 nm, around cone base. Mechanism of cone formation and cone evolution of CR-39 ablated surface were investigated by change of fluences (at a given pulse number) and pulse number (at a given fluence). Cone height, cone base, and region of interface were increased in micrometer steps by increasing the total fluence. Depression on the base of the cone and the circular fringe were simulated. FTIR spectra were measured and energy dispersive x-ray analysis of irradiated and un-irradiated samples was performed.

  8. Irradiation-induced formation of a spinel phase at the FeCr/MgO interface

    SciTech Connect (OSTI)

    Xu, Yun; Yadav, Satyesh Kumar; Aguiar, Jeffery A.; Anderoglu, Osman; Baldwin, Jon Kevin; Wang, Yongqiang; Misra, Amit; Luo, Hongmei; Uberuaga, Blas P.; Li, Nan

    2015-04-27

    Oxide dispersion strengthened ferritic/martensitic alloys have attracted significant attention for their potential uses in future nuclear reactors and storage vessels, as the metal/oxide interfaces act as stable high-strength sinks for point defects while also dispersing helium. Here, in order to unravel the evolution and interplay of interface structure and chemistry upon irradiation in these types of materials, an atomically sharp FeCr/MgO interface was synthesized at 500 °C and separately annealed and irradiated with Ni3+ ions at 500 °C. After annealing, a slight enrichment of Cr atoms was observed at the interface, but no other structural changes were found. However, under irradiation, sufficient Cr diffuses across the interface into the MgO to form a Cr-enriched transition layer that contains spinel precipitates. First-principles calculations indicate that it is energetically favorable to incorporate Cr, but not Fe, substitutionally into MgO. Furthermore, our results indicate that irradiation can be used to form new phases and complexions at interfaces, which may have different radiation tolerance than the pristine structures.

  9. Development of ODS FeCrAl for compatibility in fusion and fission energy applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pint, Bruce A.; Dryepondt, Sebastien N.; Unocic, Kinga A.; Hoelzer, David T.

    2014-11-15

    In this paper, oxide dispersion strengthened (ODS) FeCrAl alloys with 12–15% Cr are being evaluated for improved compatibility with Pb-Li for a fusion energy application and with high temperature steam for a more accident-tolerant light water reactor fuel cladding application. A 12% Cr content alloy showed low mass losses in static Pb-Li at 700°C, where a LiAlO2 surface oxide formed and inhibited dissolution into the liquid metal. All the evaluated compositions formed a protective scale in steam at 1200°C, which is not possible with ODS FeCr alloys. However, most of the compositions were not protective at 1400°C, which is amore » general and somewhat surprising problem with ODS FeCrAl alloys that is still being studied. More work is needed to optimize the alloy composition, microstructure and oxide dispersion, but initial promising tensile and creep results have been obtained with mixed oxide additions, i.e. Y2O3 with ZrO2, HfO2 or TiO2.« less

  10. Development of ODS FeCrAl for compatibility in fusion and fission energy applications

    SciTech Connect (OSTI)

    Pint, Bruce A.; Dryepondt, Sebastien N.; Unocic, Kinga A.; Hoelzer, David T.

    2014-11-15

    In this paper, oxide dispersion strengthened (ODS) FeCrAl alloys with 12–15% Cr are being evaluated for improved compatibility with Pb-Li for a fusion energy application and with high temperature steam for a more accident-tolerant light water reactor fuel cladding application. A 12% Cr content alloy showed low mass losses in static Pb-Li at 700°C, where a LiAlO2 surface oxide formed and inhibited dissolution into the liquid metal. All the evaluated compositions formed a protective scale in steam at 1200°C, which is not possible with ODS FeCr alloys. However, most of the compositions were not protective at 1400°C, which is a general and somewhat surprising problem with ODS FeCrAl alloys that is still being studied. More work is needed to optimize the alloy composition, microstructure and oxide dispersion, but initial promising tensile and creep results have been obtained with mixed oxide additions, i.e. Y2O3 with ZrO2, HfO2 or TiO2.

  11. Production of Ni-Cr-Ti-natural fibres composite and investigation of mechanical properties

    SciTech Connect (OSTI)

    Pesmen, G.; Erol, A.

    2015-03-30

    Intermetallic materials such as Ni{sub 2}Ti, Cr{sub 2}Ti are among advanced technology materials that have outstanding mechanical and physical properties for high temperature applications. Especially creep resistance, low density and high hardness properties stand out in such intermetallics. The microstructure, mechanical properties of (%50Ni-%48Cr-%2Ti)-%10Naturel Fibres and (%64Ni-%32Cr-%4Ti)-%10Naturel Fibres powders were investigated using specimens produced by tube furnace sintering at 1000-1200-1400C temperature. A composite consisting of ternary additions, a metallic phase, Ti,Cr and Ni have been prepared under Ar shroud and then tube furnace sintered. XRD, SEM (Scanning Electron Microscope), were investigated to characterize the properties of the specimens. Experimental results carried out for composition (%64Ni-%32Cr-%4Ti)-%10Naturel at 1400C suggest that the best properties as 112.09HV and 5,422g/cm{sup 3} density were obtained at 1400C.

  12. Phase decomposition in an Fe-40 at.% Cr alloy after isothermal aging and its effect on hardening

    SciTech Connect (OSTI)

    Lopez-Hirata, Victor M. Soriano-Vargas, Orlando; Rosales-Dorantes, Hector J.; Saucedo Munoz, Maribel L.

    2011-08-15

    The phase decomposition process of an Fe-40 at.% Cr alloy was studied after isothermal aging at 475 and 500 deg. C using a high-resolution transmission electron microscope, as well as hardness measurements. High-resolution transmission electron microscope observations showed that the hardening behavior is associated with the formation of the nanometric coherent decomposed Cr-rich and Fe-rich phases with irregular shape and interconnected as expected for a spinodally-decomposed alloy. As the aging progressed, coherent rounded Cr-rich phase precipitates were observed in the Fe-rich phase matrix. The coarsening process of the Cr-rich phase was observed for aging times up to 750 h. Nevertheless, no decrease in hardness with time was observed because of the nanometric size of the Cr-rich phase, less than 10 nm. Aging hardening was higher at 500 deg. C because of the higher decomposition kinetics. - Research Highlights: {yields} Spinodally-decomposed phases showed an interconnected and irregular shape in aged Fe-Cr alloy. {yields} Further aging promoted the formation of nanometric coherent rounded Cr-rich precipitates. {yields} Nanometric Cr-rich phases are responsible for the age hardening. {yields} Coarsening process of these nanometric Cr-rich precipitates caused no decrease in hardness.

  13. Atom probe study of irradiation-enhanced α' precipitation in neutron-irradiated Fe–Cr model alloys

    SciTech Connect (OSTI)

    Chen, Wei -Ying; Miao, Yinbin; Wu, Yaqiao; Tomchik, Carolyn A.; Mo, Kun; Gan, Jian; Okuniewski, Maria A.; Maloy, Stuart A.; Stubbins, James F.

    2015-07-01

    Atom probe tomography (APT) was performed to study the effects of Cr concentrations, irradiation doses and irradiation temperatures on a' phase formation in Fe-Cr model alloys (10-16 at.%) irradiated at 300 and 450°C to 0.01, 0.1 and 1 dpa. For 1 dpa specimens, α' precipitates with an average radius of 1.0-1.3 nm were observed. The precipitate density varied significantly from 1.1x10²³ to 2.7x10²⁴ 1/m³, depending on Cr concentrations and irradiation temperatures. The volume fraction of α' phase in 1 dpa specimens qualitatively agreed with the phase diagram prediction. For 0.01 dpa and 0.1 dpa, frequency distribution analysis detected slight Cr segregation in high-Cr specimens, but not in Fe-10Cr specimens. Proximity histogram analysis showed that the radial Cr concentration was highest at the center of a' precipitates. For most precipitates, the Cr contents were significantly lower than that predicted by the phase diagram. The Cr concentration at precipitate center increased with increasing precipitate size.

  14. Agricultural green revolution as a driver of increasing atmospheric CO2 seasonal amplitude

    SciTech Connect (OSTI)

    Zeng, Ning; Zhao, Fang; Collatz, George; Kalnay, Eugenia; Salawitch, Ross J.; West, Tristram O.; Guanter, Luis

    2014-11-20

    The atmospheric carbon dioxide (CO2) record displays a prominent seasonal cycle that arises mainly from changes in vegetation growth and the corresponding CO2 uptake during the boreal spring and summer growing seasons and CO2 release during the autumn and winter seasons. The CO2 seasonal amplitude has increased over the past five decades, suggesting an increase in Northern Hemisphere biospheric activity. It has been proposed that vegetation growth may have been stimulated by higher concentrations of CO2 as well as by warming in recent decades, but such mechanisms have been unable to explain the full range and magnitude of the observed increase in CO2 seasonal amplitude. Here we suggest that the intensification of agriculture (the Green Revolution, in which much greater crop yield per unit area was achieved by hybridization, irrigation and fertilization) during the past five decades is a driver of changes in the seasonal characteristics of the global carbon cycle. Our analysis of CO2 data and atmospheric inversions shows a robust 15 per cent long-term increase in CO2 seasonal amplitude from 1961 to 2010, punctuated by large decadal and interannual variations. Using a terrestrial carbon cycle model that takes into account high-yield cultivars, fertilizer use and irrigation, we find that the long-term increase in CO2 seasonal amplitude arises from two major regions: the mid-latitude cropland between 256N and 606N and the high-latitude natural vegetation between 506N and 706 N. The long-term trend of seasonal amplitude increase is 0.311 ± 0.027 percent per year, of which sensitivity experiments attribute 45, 29 and 26 per cent to land-use change, climate variability and change, and increased productivity due to CO2 fertilization, respectively. Vegetation growth was earlier by one to two weeks, as measured by the mid-point of vegetation carbon uptake, and took up 0.5 petagrams more carbon in July, the height of the growing season, during 2001–2010 than in 1961–1970

  15. The North American Carbon Program Multi-scale Synthesis and Terrestrial Model Intercomparison Project – Part 2: Environmental driver data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Yaxing; Liu, Shishi; Huntzinger, Deborah N.; Michalak, Anna M.; Viovy, Nicolas; Post, Wilfred M.; Schwalm, Christopher R.; Schaeffer, Kevin; Jacobson, Andrew R.; Lu, Chaoqun; et al

    2014-12-05

    Ecosystems are important and dynamic components of the global carbon cycle, and terrestrial biospheric models (TBMs) are crucial tools in further understanding of how terrestrial carbon is stored and exchanged with the atmosphere across a variety of spatial and temporal scales. Improving TBM skills, and quantifying and reducing their estimation uncertainties, pose significant challenges. The Multi-scale Synthesis and Terrestrial Model Intercomparison Project (MsTMIP) is a formal multi-scale and multi-model intercomparison effort set up to tackle these challenges. The MsTMIP protocol prescribes standardized environmental driver data that are shared among model teams to facilitate model model and model observation comparisons. Inmore » this article, we describe the global and North American environmental driver data sets prepared for the MsTMIP activity to both support their use in MsTMIP and make these data, along with the processes used in selecting/processing these data, accessible to a broader audience. Based on project needs and lessons learned from past model intercomparison activities, we compiled climate, atmospheric CO2 concentrations, nitrogen deposition, land use and land cover change (LULCC), C3 / C4 grasses fractions, major crops, phenology and soil data into a standard format for global (0.5⁰ x 0.5⁰ resolution) and regional (North American: 0.25⁰ x 0.25⁰ resolution) simulations. In order to meet the needs of MsTMIP, improvements were made to several of the original environmental data sets, by improving the quality, and/or changing their spatial and temporal coverage, and resolution. The resulting standardized model driver data sets are being used by over 20 different models participating in MsTMIP. Lastly, the data are archived at the Oak Ridge National Laboratory Distributed Active Archive Center (ORNL DAAC, http://daac.ornl.gov) to provide long-term data management and distribution.« less

  16. Key regulatory drivers affecting shipments of mixed transuranic waste from Los Alamos National Laboratory to the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Schumann, P.B.; Bacigalupa, G.A.; Kosiewicz, S.T.; Sinkule, B.J.

    1997-02-01

    A number of key regulatory drivers affect the nature, scope, and timing of Los Alamos National Laboratory`s (LANL`s) plans for mixed transuranic (MTRU) waste shipments to the Waste Isolation Pilot Plant (WIPP), which are planned to commence as soon as possible following WIPP`s currently anticipated November, 1997 opening date. This paper provides an overview of some of the key drivers at LANL, particularly emphasizing those associated with the hazardous waste component of LANL`s MTRU waste (MTRU, like any mixed waste, contains both a radioactive and a hazardous waste component). The key drivers discussed here derive from the federal Resource Conservation and Recovery Act (RCRA) and its amendments, including the Federal Facility Compliance Act (FFCAU), and from the New Mexico Hazardous Waste Act (NMHWA). These statutory provisions are enforced through three major mechanisms: facility RCRA permits; the New Mexico Hazardous Waste Management Regulations, set forth in the New Mexico Administrative Code, Title 20, Chapter 4, Part 1: and compliance orders issued to enforce these requirements. General requirements in all three categories will apply to MTRU waste management and characterization activities at both WIPP and LANL. In addition, LANL is subject to facility-specific requirements in its RCRA hazardous waste facility permit, permit conditions as currently proposed in RCRA Part B permit applications presently being reviewed by the New Mexico Environment Department (NNED), and facility-specific compliance orders related to MTRU waste management. Likewise, permitting and compliance-related requirements specific to WIPP indirectly affect LANL`s characterization, packaging, record-keeping, and transportation requirements for MTRU waste. LANL must comply with this evolving set of regulatory requirements to begin shipments of MTRU waste to WIPP in a timely fashion.

  17. Multiband Optical Absorption Controlled by Lattice Strain in Thin-Film LaCrO3

    SciTech Connect (OSTI)

    Sushko, Peter; Qiao, Liang; Bowden, Mark E.; Varga, Tamas; Exarhos, Gregory J.; Urban, III, Frank K.; Barton, David; Chambers, Scott A.

    2013-02-11

    Experimental measurements and ab initio modeling of the optical transitions in strained G-type antiferromagnetic LaCrO3 resolve two decades of debate regarding the magnitude of the optical band gap and the character of the corresponding transitions in this material. Using time-dependent density functional theory and accounting for thermal disorder effects, we demonstrate that the fourmost prominent low-energy absorption features are due to intra-Cr t2g {eg (2.4, 3.6 eV), inter-Crt2g {t2g (4.4 eV), and inter-ion O 2p { Cr 3d (from ?5 eV) transitions and show that the excitation energies of the latter type can be strongly affected by the lattice strain.

  18. Electronic and magnetic properties of epitaxial perovskite SrCrO3(001)

    SciTech Connect (OSTI)

    Zhang, Hongliang; Du, Yingge; Sushko, Petr; Bowden, Mark E.; Shutthanandan, V.; Qiao, Liang; Cao, Guixin; Gai, Zheng; Sallis, Shawn; Piper, L.F.J.; Chambers, Scott A.

    2015-06-24

    We have investigated the intrinsic properties of SrCrO3 epitaxial thin films synthesized by molecular beam epitaxy. We find compelling evidence that SrCrO3 is a correlated metal. X-ray photoemission valence band and O K-edge x-ray absorption spectra indicate a strongly hybridized Cr3d-O2p state crossing the Fermi level, leading to metallic behavior. Comparison between valence band spectra near the Fermi level and the densities of states calculated using density functional theory (DFT) also suggests the presence of coherent and incoherent states and points to a strong electron-electron correlation effects. The magnetic susceptibility can be described by Pauli paramagnetism at temperatures above 100 K, but reveals antiferromagnetic behavior at lower temperatures resulting from orbital ordering as suggested by Ortega-San-Martin et al. [Phys. Rev. Lett. 99, 255701 (2007)].

  19. Response of 9Cr-ODS Steel to Proton Irradiation at 400 °C

    SciTech Connect (OSTI)

    Jianchao He; Farong Wan; Kumar Sridharan; Todd R. Allen; A. Certain; Y. Q. Wu

    2014-09-01

    The stability of Y–Ti–O nanoclusters, dislocation structure, and grain boundary segregation in 9Cr-ODS steels has been investigated following proton irradiation at 400 °C with damage levels up to 3.7 dpa. A slight coarsening and a decrease in number density of nanoclusters were observed as a result of irradiation. The composition of nanoclusters was also observed to change with a slight increase of Y and Cr concentration in the nanoclusters following irradiation. Size, density, and composition of the nanoclusters were investigated as a function of nanocluster size, specifically classified to three groups. In addition to the changes in nanoclusters, dislocation loops were observed after irradiation. Finally, radiation-induced enrichment of Cr and depletion of W were observed at grain boundaries after irradiation.

  20. Characterization of cathodic corrosion products in the Ca/CaCrO/sub 4/ thermal battery

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.; Venturini, E.L.; Rogers, J.W. Jr.; Cathey, W.N.

    1985-05-01

    Using thermal analysis techniques, we investigated the corrosion process resulting from the reaction of iron, nickel, and stainless steel (used as current collectors in Ca/CaCrO/sub 4/ thermal batteries) with CaCrO/sub 4/ dissolved in LiCl-KCl eutectic. The reaction product for iron was synthesized in bulk external to the battery and was characterized by chemical analysis, X-ray diffraction, Moessbauer spectroscopy, X-ray photoelectron spectroscopy, static magnetization, and electrical conductivity. This characterization provides a better understanding of the cathodic corrosion processes that occur in the Ca/CaCrO/sub 4/ thermal battery, and how the properties of the reaction layer at the catholyte-current collector interface influence battery performance.

  1. Qualification of welded super 13%Cr martensitic stainless steels for sour service applications

    SciTech Connect (OSTI)

    Enerhaug, J.; Eliassen, S.L.; Kvaale, P.E.

    1997-08-01

    A test program has been carried out to qualify welded super 13%Cr stainless steels for sour service applications. The test program included weldability trials, weld simulations, mechanical testing and corrosion testing of 13%Cr steels from five different steel mills. Two of the tested steels have been qualified for use as flowline materials in some parts of new sour service fields. The result shows excellent weldability properties and acceptable corrosion properties. Post weld heat treatment (PWHT) of the welds improved the resistance towards sulfide stress corrosion cracking significantly.

  2. Oxygen-17 NMR Shifts Caused by Cr{Sup ++} in Aqueous Solutions

    DOE R&D Accomplishments [OSTI]

    Jackson, J. A.; Lemons, J. F.; Taube, H.

    1962-01-01

    Cr{sup ++} in solution produces a paramagnetic shift in the NMR absorption of O{sup 17} in ClO{sub 4}{sup -}, as well as the expected paramagnetic shift for O{sup 17} in H{sub 2}O. As the concentration of ClO{sub 4}{sup -} increases, the shift in the H{sub 2}O{sup 17} absorption is diminished, and eventually changes sign. The effects are ascribed to preferential replacement by ClO{sub 4}{sup -} of water molecules from the axial positions in the first coordination sphere about Cr{sup ++}.

  3. Ultrahigh sensitivity of anomalous Hall effect sensor based on Cr-doped

    Office of Scientific and Technical Information (OSTI)

    Bi2Te3 topological insulator thin films (Journal Article) | SciTech Connect Ultrahigh sensitivity of anomalous Hall effect sensor based on Cr-doped Bi2Te3 topological insulator thin films Citation Details In-Document Search This content will become publicly available on July 1, 2017 Title: Ultrahigh sensitivity of anomalous Hall effect sensor based on Cr-doped Bi2Te3 topological insulator thin films Anomalous Hall effect (AHE) was recently discovered in magnetic element-doped topological

  4. Development and quality assessments of commercial heat production of ATF FeCrAl tubes

    SciTech Connect (OSTI)

    Yamamoto, Yukinori

    2015-09-01

    Development and quality assessment of the 2nd generation ATF FeCrAl tube production with commercial manufacturers were conducted. The manufacturing partners include Sophisticated Alloys, Inc. (SAI), Butler, PA for FeCrAl alloy casting via vacuum induction melting, Oak Ridge National Laboratory (ORNL) for extrusion process to prepare the master bars/tubes to be tube-drawn, and Rhenium Alloys, Inc. (RAI), North Ridgeville, OH, for tube-drawing process. The masters bars have also been provided to Los Alamos National Laboratory (LANL) who works with Century Tubes, Inc., (CTI), San Diego, CA, as parallel tube production effort under the current program.

  5. Elastic Modulus Measurement of ORNL ATF FeCrAl Alloys

    SciTech Connect (OSTI)

    Thompson, Zachary T.; Terrani, Kurt A.; Yamamoto, Yukinori

    2015-10-01

    Elastic modulus and Poisson’s ratio for a number of wrought FeCrAl alloys, intended for accident tolerant fuel cladding application, are determined via resonant ultrasonic spectroscopy. The results are reported as a function of temperature from room temperature to 850°C. The wrought alloys were in the fully annealed and unirradiated state. The elastic modulus for the wrought FeCrAl alloys is at least twice that of Zr-based alloys over the temperature range of this study. The Poisson’s ratio of the alloys was 0.28 on average and increased very slightly with increasing temperature.

  6. Advanced ODS FeCrAl alloys for accident-tolerant fuel cladding

    SciTech Connect (OSTI)

    Dryepondt, Sebastien N; Unocic, Kinga A; Hoelzer, David T; Pint, Bruce A

    2014-09-01

    ODS FeCrAl alloys are being developed with optimum composition and properties for accident tolerant fuel cladding. Two oxide dispersion strengthened (ODS) Fe-15Cr-5Al+Y2O3 alloys were fabricated by ball milling and extrusion of gas atomized metallic powder mixed with Y2O3 powder. To assess the impact of Mo on the alloy mechanical properties, one alloy contained 1%Mo. The hardness and tensile properties of the two alloys were close and higher than the values reported for fine grain PM2000 alloy. This is likely due to the combination of a very fine grain structure and the presence of nano oxide precipitates. The nano oxide dispersion was however not sufficient to prevent grain boundary sliding at 800 C and the creep properties of the alloys were similar or only slightly superior to fine grain PM2000 alloy. Both alloys formed a protective alumina scale at 1200 C in air and steam and the mass gain curves were similar to curves generated with 12Cr-5Al+Y2O3 (+Hf or Zr) ODS alloys fabricated for a different project. To estimate the maximum temperature limit of use for the two alloys in steam, ramp tests at a rate of 5 C/min were carried out in steam. Like other ODS alloys, the two alloys showed a significant increase of the mas gains at T~ 1380 C compared with ~1480 C for wrought alloys of similar composition. The beneficial effect of Yttrium for wrought FeCrAl does not seem effective for most ODS FeCrAl alloys. Characterization of the hardness of annealed specimens revealed that the microstructure of the two alloys was not stable above 1000 C. Concurrent radiation results suggested that Cr levels <15wt% are desirable and the creep and oxidation results from the 12Cr ODS alloys indicate that a lower Cr, high strength ODS alloy with a higher maximum use temperature could be achieved.

  7. GNU Bug Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  8. EPR and optical investigations of LaMgAl{sub 11}O{sub 19}:Cr{sup 3+} phosphor

    SciTech Connect (OSTI)

    Singh, Vijay; Sivaramaiah, G.; Rao, J.L.; Kim, S.H.

    2014-12-15

    Graphical abstract: The EPR spectrum of as-prepared LaMgAl{sub 11}O{sub 19}:Cr{sup 3+} phosphor at 110 K. - Highlights: • Using the combustion synthesis, LaMgAl{sub 11}O{sub 19}:Cr{sup 3+} phosphor has been prepared in a few minutes. • Optical investigation indicates that Cr{sup 3+} ions are present in octahedral symmetry. • The EPR signals indicate that exchange coupled Cr{sup 3+}–Cr{sup 3+} ion pairs in weakly distorted sites. - Abstract: The LaMgAl{sub 11}O{sub 19}:Cr{sup 3+} phosphor has been prepared by a low-temperature combustion synthesis method. As-prepared combustion synthesized powder was characterized using powder X-ray diffraction (XRD), diffuse reflectance (DRS), electron paramagnetic resonance (EPR) and photoluminescence (PL) studies. The X-ray diffraction pattern reveals crystalline hexagonal phases. The UV–vis diffuse reflectance spectrum exhibits three broad bands characteristic of Cr{sup 3+} ions in octahedral symmetry. The EPR spectrum exhibits several resonance signals. The signals with the effective g values at g = 4.84, 3.64 and 2.26 have been attributed to the isolated Cr{sup 3+} ions. The signal with the effective g value at g = 1.94 has been attributed to exchange coupled Cr{sup 3+}–Cr{sup 3+} ion pairs. The PL studies exhibit several bands characteristic of Cr{sup 3+} ions in octahedral symmetry.

  9. Dual and Triple Ion-Beam Irradiations of Fe, Fe(Cr) and Fe(Cr)-ODS Final Report: IAEA SMoRE CRP

    SciTech Connect (OSTI)

    Fluss, M J; Hsiung, L L; Marian, J

    2011-11-20

    Structures of nanoparticles in Fe-16Cr-4.5Al-0.3Ti-2W-0.37Y2O3 (K3) and Fe-20Cr-4.5Al-0.34Ti-0.5Y2O3 (MA956) oxide dispersion strengthened (ODS) ferritic steels produced by mechanical alloying (MA) and followed by hot extrusion have been studied using high-resolution transmission electron microscopy (HRTEM) techniques to gain insight about the formation mechanism of nanoparticles in MA/ODS steels. The observations of Y-Al-O complex-oxide nanoparticles in both ODS steels imply that decomposition of Y2O3 in association with internal oxidation of Al occurred during mechanical alloying. While the majority of oxide nanoparticles formed in both steels is Y4Al2O9, a few oxide particles of YAlO3 are also occasionally observed. These results reveal that Ti (0.3 wt %) plays an insignificant role in forming oxide nanoparticles in the presence of Al (4.5 wt %). HRTEM observations of crystalline nanoparticles larger than {approx}2 nm and amorphous or disordered cluster domains smaller than {approx}2 nm provide an insight into the formation mechanism of oxide nanoparticle in MA/ODS steels, which we believe from our observations involves a solid-state amorphous precursor followed by recrystallization. Dual ion-beam irradiations using He{sup +} + Fe{sup +8} ions were employed to gain more detailed insight about the role of nanoparticles in suppressing radiation-induced swelling. This is elaborated through TEM examinations of cavity distributions in ion-irradiated Fe-14Cr and K3-ODS ferritic steels. HRTEM observations of helium-filled cavities (helium bubbles) preferably trapped at nanoscale oxide particles and clusters in ion-irradiated K3-ODS are presented. Finally, we describe the results from triple ion-beam irradiations using H{sup +} + He{sup +} + Fe{sup +8} ions to emulate fusion first wall radiation effects. Preliminary work is reported that confirms the existence of significant hydrogen synergistic effects described earlier by Tanaka et al., for Fe(Cr) and by Wakai et al

  10. Ab initio study of structural stability and electronic properties of Ti{sub 1-x}Mg{sub x}Cr{sub 2} and TiMg{sub x}Cr{sub 2-x} laves phase

    SciTech Connect (OSTI)

    Sari, A. Merad, G.

    2015-03-30

    The structural stability and electronic properties of TiMgCr{sub 2} laves phase have been calculated and compared. It is found that Mg prefer to substitutes titanium than chromium. The values of entalpies of formation show that Ti{sub 1-x}Mg{sub x}Cr{sub 2} may exist for only one concentration x=0.125 and the more favorable alloy is Ti{sub 0.875}Mg{sub 0.125}Cr{sub 2}. For TiCr{sub 2}, the optimized structural parameters were in good agreement with experimental values, while for TiMgCr{sub 2}, there is not experimental data. The electronic densities of states (DOS) are given and the nature of bonds are also discussed.

  11. Break-Even Cost for Residential Solar Water Heating in the United States: Key Drivers and Sensitivities

    SciTech Connect (OSTI)

    Cassard, H.; Denholm, P.; Ong, S.

    2011-02-01

    This paper examines the break-even cost for residential rooftop solar water heating (SWH) technology, defined as the point where the cost of the energy saved with a SWH system equals the cost of a conventional heating fuel purchased from the grid (either electricity or natural gas). We examine the break-even cost for the largest 1,000 electric and natural gas utilities serving residential customers in the United States as of 2008. Currently, the break-even cost of SWH in the United States varies by more than a factor of five for both electricity and natural gas, despite a much smaller variation in the amount of energy saved by the systems (a factor of approximately one and a half). The break-even price for natural gas is lower than that for electricity due to a lower fuel cost. We also consider the relationship between SWH price and solar fraction and examine the key drivers behind break-even costs. Overall, the key drivers of the break-even cost of SWH are a combination of fuel price, local incentives, and technical factors including the solar resource location, system size, and hot water draw.

  12. Highly-Selective and Reversible O2 Binding inCr3(1,3,5-benzenetricarb...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soc., 2010, 132 (23), pp 7856-7857 DOI: 10.1021ja1027925 Abstract Image Abstract: Reaction of Cr(CO)6 with trimesic acid in DMF affords the metal-organic framework Cr3(BTC)2*nDMF ...

  13. Understanding the solidification and microstructure evolution during CSC-MIG welding of FeCrB-based alloy

    SciTech Connect (OSTI)

    Sorour, A.A. Chromik, R.R. Gauvin, R. Jung, I.-H. Brochu, M.

    2013-12-15

    The present is a study of the solidification and microstructure of Fe28.2%Cr3.8%B1.5%Si1.5%Mn (wt.%) alloy deposited onto a 1020 plain carbon steel substrate using the controlled short-circuit metal inert gas welding process. The as-solidified alloy was a metal matrix composite with a hypereutectic microstructure. Thermodynamic calculation based on the ScheilGulliver model showed that a primary (Cr,Fe){sub 2}B phase formed first during solidification, followed by an eutectic formation of the (Cr,Fe){sub 2}B phase and a body-centered cubic Fe-based solid solution matrix, which contained Cr, Mn and Si. Microstructure analysis confirmed the formation of these phases and showed that the shape of the (Cr,Fe){sub 2}B phase was irregular plate. As the welding heat input increased, the weld dilution increased and thus the volume fraction of the (Cr,Fe){sub 2}B plates decreased while other microstructural characteristics were similar. - Highlights: We deposit FeCrB-based alloy onto plain carbon steel using the CSC-MIG process. We model the solidification behavior using thermodynamic calculation. As deposited alloy consists of (Cr,Fe){sub 2}B plates embedded in Fe-based matrix. We study the effect of the welding heat input on the microstructure.

  14. Changes induced in a ZnS:Cr-based electroluminescent waveguide structure by intrinsic near-infrared laser radiation

    SciTech Connect (OSTI)

    Vlasenko, N. A. Oleksenko, P. F.; Mukhlyo, M. A.; Veligura, L. I.

    2013-08-15

    The causes of changes that occur in a thin-film electroluminescent metal-insulator-semiconductor-insulator-metal waveguide structure based on ZnS:Cr (Cr concentration of {approx}4 Multiplication-Sign 10{sup 20} cm{sup -3}) upon lasing ({lambda} Almost-Equal-To 2.6 {mu}m) and that induce lasing cessation are studied. It is established that lasing ceases because of light-scattering inhomogeneities formed in the structure and, hence, optical losses enhance. The origin of the inhomogeneities and the causes of their formation are clarified by studying the surface topology and the crystal structure of constituent layers of the samples before and after lasing. The studies are performed by means of atomic force microscopy and X-ray radiography. It is shown that a substantial increase in the sizes of grains on the surface of the structure is the manifestation of changes induced in the ZnS:Cr film by recrystallization. Recrystallization is initiated by local heating by absorbed laser radiation in existing Cr clusters and quickened by a strong electric field (>1 MV cm{sup -1}). The changes observed in the ZnS:Cr film are as follows: the textured growth of ZnS crystallites, an increase in the content of Cr clusters, and the appearance of some CrS and a rather high ZnO content. Some ways for improving the stability of lasing in the ZnS:Cr-based waveguide structures are proposed.

  15. Computational discovery of ferromagnetic semiconducting single-layer CrSnTe3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhuang, Houlong L.; Xie, Yu; Kent, P. R. C.; Ganesh, P.

    2015-07-06

    Despite many single-layer materials being reported in the past decade, few of them exhibit magnetism. Here we perform first-principles calculations using accurate hybrid density functional methods (HSE06) to predict that single-layer CrSnTe3 (CST) is a ferromagnetic semiconductor, with band gaps of 0.9 and 1.2 eV for the majority and minority spin channels, respectively. We determine the Curie temperature as 170 K, significantly higher than that of single-layer CrSiTe3 (90K) and CrGeTe3 (130 K). This is due to the enhanced ionicity of the Sn-Te bond, which in turn increases the superexchange coupling between the magnetic Cr atoms. We further explore themore » mechanical and dynamical stability and strain response of this single-layer material for possible epitaxial growth. Lastly, our study provides an intuitive approach to understand and design novel single-layer magnetic semiconductors for a wide range of spintronics and energy applications.« less

  16. Oxidation resistance of 9-12% Cr steels: effect of rare earth surface treatment

    SciTech Connect (OSTI)

    Dogan, Omer N.; Alman, David A.; Jablonski, Paul D.

    2005-02-01

    Medium Cr steels have been used in fossil fired power plants for many years because of their excellent high temperature stability and mechanical properties. The environment in a fossil fired power plant is extremely aggressive in terms of corrosion, especially oxidation. This is only accelerated as the operating temperature increases to 650C and beyond. For any new steel to be qualified for power plant use, in addition to adequate strength at the operating temperature, material wastage from all corrosion processes must be kept to a minimum acceptable level. The use of medium Cr steels provides a means to improve overall corrosion resistance. Three medium Cr are under development for use as high temperature power plant steels: 0.08C-(9-12)Cr-1.2Ni-0.7Mo-3.0Cu-3.0Co-0.5Ti. Oxidation tests were performed on the steels for times greater than 1000 hours in order to determine the oxidation kinetics and extent of material wastage. Also, rare earth oxides were incorporated into the outer surface layers of the steels to see if the oxidation resistance could be improved. These results will be compared to current power plant steels.

  17. Investigation on growth and laser properties of GGG:(Nd,Cr) single crystals

    SciTech Connect (OSTI)

    Zhang; Lin; Liu; Liu; Zhu

    1986-04-04

    Investigation on the growth and laser properties of gadolinium gallium garnet crystal doped with neodymium and chromium is reported. As the segregation coefficient of Nd in GGG is less than 1 and that of Cr is greater than 1, a modified Czochralski method for growth is adopted in order to keep the dopants being uniform in the grown crystal.

  18. Zinc protects human peripheral blood lymphocytes from Cr(III)(phenanthroline){sub 3}-induced apoptosis

    SciTech Connect (OSTI)

    Sankaramanivel, Sundararaj; Rajaram, Anantanarayanan; Rajaram, Rama

    2010-03-15

    We have studied the effect of Cr(III)(phen){sub 3} [(tris(1,10-phenanthroline) chromium(III) chloride)] on lymphocytes in order to find out if metallothioneins (MTs) are produced in the process. We also investigated whether zinc pretreatment is able to protect cells from apoptosis reported to occur for this compound. Our results indicate that MT synthesis is induced by Cr(III)(phen){sub 3}, and it has been identified as the MT-3 isoform through RT-PCR which has not been reported earlier. By zinc pretreatment, this apoptosis is reversed as inferred from cytotoxicity studies, Annexin-V/PI staining, ethidium bromide/acridine orange staining and DNA fragmentation pattern and ultrastructural investigations using TEM and SEM. The zinc pretreatment reduces the amount of ROS produced by Cr(III)(phen){sub 3} . The MT-1a and 1b synthesized by zinc (also evidenced through RT-PCR experiments) is possibly able to scavenge ROS which is one of the early signaling molecules that lead to apoptosis. Zinc pretreatment also reverses the changes in downstream signaling events such as mitochondrial membrane potential, ATP levels and the activation of caspase-3. This is the first report on the induction of MT-3 in lymphocytes due to a metal stress or any other stimuli. Even though MT-3 is synthesized here, apoptosis still occurs due to ROS production on Cr(III)(phen){sub 3} exposure when the cells have not been primed with zinc.

  19. Understanding phase stability of Al-Co-Cr-Fe-Ni high entropy alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Chuan; Zhang, Fan; Diao, Haoyan; Gao, Michael C.; Tang, Zhi; Poplawsky, Jonathan D.; Liaw, Peter K.

    2016-07-19

    The concept of high entropy alloy (HEA) opens a vast unexplored composition range for alloy design. As a well-studied system, Al-Co-Cr-Fe-Ni has attracted tremendous amount of attention to develop new-generation low-density structural materials for automobile and aerospace applications. In spite of intensive investigations in the past few years, the phase stability within this HEA system is still poorly understood and needs to be clarified, which poses obstacles to the discovery of promising Al-Co-Cr-Fe-Ni HEAs. In the present work, the CALPHAD approach is employed to understand the phase stability and explore the phase transformation within the Al-Co-Cr-Fe-Ni system. As a result,more » the phase-stability mapping coupled with density contours is then constructed within the composition - temperature space, which provides useful guidelines for the design of low-density Al-Co-Cr-Fe-Ni HEAs with desirable properties.« less

  20. Ion irradiation testing and characterization of FeCrAl candidate alloys

    SciTech Connect (OSTI)

    Anderoglu, Osman; Aydogan, Eda; Maloy, Stuart Andrew; Wang, Yongqiang

    2014-10-29

    The Fuel Cycle Research and Development program’s Advanced Fuels Campaign has initiated a multifold effort aimed at facilitating development of accident tolerant fuels. This effort involves development of fuel cladding materials that will be resistant to oxidizing environments for extended period of time such as loss of coolant accident. Ferritic FeCrAl alloys are among the promising candidates due to formation of a stable Al₂O₃ oxide scale. In addition to being oxidation resistant, these promising alloys need to be radiation tolerant under LWR conditions (maximum dose of 10-15 dpa at 250 – 350°C). Thus, in addition to a number of commercially available alloys, nuclear grade FeCrAl alloys developed at ORNL were tested using high energy proton irradiations and subsequent characterization of irradiation hardening and damage microstructure. This report summarizes ion irradiation testing and characterization of three nuclear grade FeCrAl cladding materials developed at ORNL and four commercially available Kanthal series FeCrAl alloys in FY14 toward satisfying FCRD campaign goals.

  1. Pressure-induced electronic phase separation of magnetism and superconductivity in CrAs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khasanov, Rustem; Guguchia, Zurab; Eremin, Ilya; Luetkens, Hubertus; Amato, Alex; Biswas, Pabitra K.; Ruegg, Christian; Susner, Michael A.; Sefat, Athena S.; Zhigadlo, Nikolai D.; et al

    2015-09-08

    We report that the recent discovery of pressure (p) induced superconductivity in the binary helimagnet CrAs has raised questions on how superconductivity emerges from the magnetic state and on the mechanism of the superconducting pairing. In the present work the suppression of magnetism and the occurrence of superconductivity in CrAs were studied by means of muon spin rotation. The magnetism remains bulk up to p ≃ 3.5 kbar while its volume fraction gradually decreases with increasing pressure until it vanishes at p ≃ 7 kbar. At 3.5 kbar superconductivity abruptly appears with its maximum Tc ≃ 1.2 K which decreasesmore » upon increasing the pressure. In the intermediate pressure region (3.5≲ p ≲ 7 kbar) the superconducting and the magnetic volume fractions are spatially phase separated and compete for phase volume. Our results indicate that the less conductive magnetic phase provides additional carriers (doping) to the superconducting parts of the CrAs sample thus leading to an increase of the transition temperature (Tc) and of the superfluid density (ρs). A scaling of ρs with Tc3.2 as well as the phase separation between magnetism and superconductivity point to a conventional mechanism of the Cooper-pairing in CrAs.« less

  2. Pressure-induced electronic phase separation of magnetism and superconductivity in CrAs

    SciTech Connect (OSTI)

    Khasanov, Rustem; Guguchia, Zurab; Eremin, Ilya; Luetkens, Hubertus; Amato, Alex; Biswas, Pabitra K.; Ruegg, Christian; Susner, Michael A.; Sefat, Athena S.; Zhigadlo, Nikolai D.; Morenzoni, Elvezio

    2015-09-08

    We report that the recent discovery of pressure (p) induced superconductivity in the binary helimagnet CrAs has raised questions on how superconductivity emerges from the magnetic state and on the mechanism of the superconducting pairing. In the present work the suppression of magnetism and the occurrence of superconductivity in CrAs were studied by means of muon spin rotation. The magnetism remains bulk up to p ≃ 3.5 kbar while its volume fraction gradually decreases with increasing pressure until it vanishes at p ≃ 7 kbar. At 3.5 kbar superconductivity abruptly appears with its maximum Tc ≃ 1.2 K which decreases upon increasing the pressure. In the intermediate pressure region (3.5≲ p ≲ 7 kbar) the superconducting and the magnetic volume fractions are spatially phase separated and compete for phase volume. Our results indicate that the less conductive magnetic phase provides additional carriers (doping) to the superconducting parts of the CrAs sample thus leading to an increase of the transition temperature (Tc) and of the superfluid density (ρs). A scaling of ρs with Tc3.2 as well as the phase separation between magnetism and superconductivity point to a conventional mechanism of the Cooper-pairing in CrAs.

  3. Cr-doped TiSe2 - A layered dichalcogenide spin glass

    SciTech Connect (OSTI)

    Luo, Huixia; Tao, Jing; Krizan, Jason W.; Seibel, Elizabeth M.; Xie, Weiwei; Sahasrabudhe, Girija S.; Bergman, Susanna L.; Phelan, Brendan F.; Wang, Zhen; Zhang, Jiandi; Cava, R. J.

    2015-09-17

    We report the magnetic characterization of the Cr-doped layered dichalcogenide TiSe2. The temperature dependent magnetic susceptibilities are typical of those seen in geometrically frustrated insulating antiferromagnets. The Cr moment is close to the spin-only value, and the Curie–Weiss temperatures (θcw) are between –90 and –230 K. Freezing of the spin system, which is glassy, characterized by peaks in the ac and dc susceptibility and specific heat, does not occur until below T/θcw = 0.05. The CDW transition seen in the resistivity for pure TiSe2 is still present for 3% Cr substitution but is absent by 10% substitution, above which the materials are metallic and p-type. Structural refinements, magnetic characterization, and chemical considerations indicate that the materials are of the type Ti1–xCrxSe2-x/2 for 0 ≤ x ≤ 0.6.

  4. Synthesis, Hardness, and Electronic Properties of Stoichiometric VN and CrN

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Shanmin; Yu, Xiaohui; Zhang, Jianzhong; Wang, Liping; Leinenweber, Kurt; He, Duanwei; Zhao, Yusheng

    2015-11-09

    Here, we report synthesis of single-crystal VN and CrN through high-pressure ionexchange reaction routes. The final products are stoichiometric and have crystallite sizes in the range of 50-120 mu m. We also prepared VN and TiN crystals using high-pressure sintering of nitride powders. On the basis of single-crystal indentation testing, the determined asymptotic Vickers hardness for TiN, VN, and CrN is 18 (1), 10 (1), and 16 (1) GPa, respectively. Moreover, the relatively low hardness in VN indicates that the metallic bonding prevails due to the overfilled metallic a bonds, although the cation-anion covalent hybridization in this compound is muchmore » stronger than that in TiN and CrN. All three nitrides are intrinsically excellent metals at ambient pressure. In particular, VN exhibits superconducting transition at T-c approximate to 7.8 K, which is slightly lower than the reported values for nitrogen-deficient or crystallinedisordered samples due to unsuppressed "spin fluctuation" in the well-crystallized stoichiometric VN. The magnetostructural transition in CrN correlates with a metal metal transition at T-N = 240(5) K and is accompanied by a similar to 40% drop in electrical resistivity. Additionally, more detailed electronic properties are presented with new insights into these nitrides.« less

  5. Microstructures and Mechanical Properties of Compositionally Complex Co-free FeNiMnCr18 FCC Solid Solution Alloy

    SciTech Connect (OSTI)

    Wu, Zhenggang; Bei, Hongbin

    2015-01-01

    Recently,a structurally-simplebutcompositionally-complex FeNiCoMnCr highentropyalloywasfoundto haveexcellentmechanicalproperties(e.g.,highstrengthandductility).Tounderstandthepotentialof using highentropyalloysasstructuralmaterialsforadvancednuclearreactorandpowerplants,itis necessary tohaveathoroughunderstandingoftheirstructuralstabilityandmechanicalpropertiesde- gradation underneutronirradiation.ThisrequiresustodevelopasimilarmodelalloywithoutCobe- cause materialwithCowillmakepost-neutron-irradiationtestingdifficult duetotheproductionofthe 60Co radioisotope.Toachievethisgoal,aFCC-structuredsingle-phasealloywithacompositionof FeNiMnCr18 wassuccessfullydeveloped.Thisnear-equiatomicFeNiMnCr18 alloy hasgoodmalleability and itsmicrostructurecanbecontrolledbythermomechanicalprocessing.Byrollingandannealing,the as-cast elongated-grained-microstructureisreplacedbyhomogeneousequiaxedgrains.Themechanical properties (e.g.,strengthandductility)oftheFeNiMnCr18 alloy arecomparabletothoseoftheequiatomic FeNiCoMnCr highentropyalloy.Bothstrengthandductilityincreasewithdecreasingdeformation temperature,withthelargestdifferenceoccurringbetween293and77K.Extensivetwin-bandswhich are bundlesofnumerousindividualtwinsareobservedwhenitistensile-fracturedat77K.Notwin bands aredetectedbyEBSDformaterialsdeformedat293Kandhigher.Theunusualtemperature-de- pendencies ofUTSanduniformelongationcouldbecausedbythedevelopmentofthedensetwin substructure, twin-dislocationinteractionsandtheinteractionsbetweenprimaryandsecondarytwin- ning systemswhichresultinamicrostructurerefinement andhencecauseenhancedstrainhardening and postponednecking.

  6. Photochemistry of Methyl Bromide on the α-Cr2O3(0001) Surface

    SciTech Connect (OSTI)

    Henderson, Michael A.

    2010-09-30

    The photochemical properties of the Cr-terminated α-Cr2O3(0001) surface were explored using methyl bromide (CH3Br) as a probe molecule. CH3Br adsorbed and desorbed molecularly from the Cr-terminated α-Cr2O3(0001) surface without detectable thermal decomposition. Temperature programmed desorption (TPD) revealed a CH3Br desorption state at 240 K for coverages up to 0.5 ML, followed by more weakly bound molecules desorbing at 175 K for coverages up to 1 ML. Multilayer exposures led to desorption at ~130 K. The CH3Br sticking coefficient was unity at 105 K for coverages up to monolayer saturation, but decreased as the multilayer formed. In contrast, pre-oxidation of the surface (using an oxygen plasma source) led to capping of surface Cr3+ sites and near complete removal of CH3Br TPD states above 150 K. The photochemistry of chemisorbed CH3Br was explored on the Cr-terminated surface using post-irradiation TPD and photon stimulated desorption (PSD). Irradiation of adsorbed CH3Br with broad band light from a Hg arc lamp resulted in both photodesorption and photodecomposition of the parent molecule at a combined cross section of ~10-22 cm2. Parent PSD was indicative of molecular photodesorption, but CH3 was also detected in PSD and Br atoms were left on the surface, both reflective of photo-induced CH3-Br bond dissociation. Use of a 385 nm cut-off filter effectively shut down the photodissociation pathway but not the parent molecule photodesorption process. From these observations it is inferred that d-to-d transitions in α-Cr2O3, occurring at photon energies <3 eV, are not responsible for photodecomposition of 2 adsorbed CH3Br. It is unclear to what extent band-to-band versus direct CH3Br photolysis play in CH3-Br bond dissociation initiated by more energetic photons.

  7. Fate of Cu, Cr, and As during combustion of impregnated wood with and without peat additive

    SciTech Connect (OSTI)

    Karin Lundholm; Dan Bostroem; Anders Nordin; Andrei Shchukarev

    2007-09-15

    The EU Directive on incineration of waste regulates the harmful emissions of particles and twelve toxic elements, including copper, chromium, and arsenic. Using a 15 kW pellets-fueled grate burner, experiments were performed to determine the fate of copper, chromium, and arsenic during combustion of chromate copper arsenate (CCA) preservative wood. The fate and speciation of copper, chromium, and arsenic were determined from analysis of the flue gas particles and the bottom ash using SEM-EDS, XRD, XPS, and ICP-AES. Chemical equilibrium model calculations were performed to interpret the experimental findings. The results revealed that about 5% copper, 15% chromium, and 60% arsenic were volatilized during combustion of pure CCA-wood, which is lower than predicted volatilization from the individual arsenic, chromium, and copper oxides. This is explained by the formation of more stable refractory complex oxide phases for which the stability trends and patterns are presented. When co-combusted with peat, an additional stabilization of these phases was obtained and thus a small but noteworthy decrease in volatilization of all three elements was observed. The major identified phases for all fuels were CuCrO{sub 2}(s), (Fe,Mg,Cu)(Cr,Fe,Al)O{sub 4}(s), Cr{sub 2}O{sub 3}(s), and Ca{sub 3}(AsO{sub 4}){sub 2}(s). Arsenic was also identified in the fine particles as KH{sub 2}AsO{sub 4}(s) and As{sub 2}O{sub 3}). A strong indication of hexavalent chromium in the form of K{sub 2}CrO{sub 4} or as a solid solution between K{sub 3}Na(CrO{sub 4}){sub 2} and K{sub 3}Na(SO{sub 4}){sub 2} was found in the fine particles. Good qualitative agreement was observed between experimental data and chemical equilibrium model calculations. 38 refs., 6 figs., 2 tabs.

  8. Tensile properties of V-Cr-Ti alloys after exposure in hydrogen-containing environments

    SciTech Connect (OSTI)

    Natesan, K.; Soppet, W.K.

    1998-09-01

    A systematic study has been initiated at Argonne National Laboratory to evaluate the performance of several V-Cr-Ti alloys after exposure to environments containing hydrogen at various partial pressures. The goal is to correlate the chemistry of the exposure environment with hydrogen uptake in the samples and its influence on the microstructure and tensile properties of the alloys. At present, the principal effort has focused on the V-4Cr-4Ti alloy of heat identified as BL-71; however other alloys (V-5Cr-5Ti alloy of heats BL-63, and T87, plus V-4Cr-4Ti alloy from General Atomics [GA]) are also being evaluated. Other variables of interest are the effect of initial grain size on the tensile behavior of the alloys. Experiments conducted on specimens of various V-Cr-Ti alloys exposed to pH{sub 2} levels of 0.01 and 3 {times} 10{sup {minus}6} torr showed negligible effect of H{sub 2} on either maximum engineering stress or uniform and total elongation. However, uniform and total elongation decreased substantially when the alloys were exposed to 1.0 torr H{sub 2} pressure. Preliminary data from sequential exposures of the materials to low-pO{sub 2} and several low-pH{sub 2} environments did not reveal an adverse effect on the maximum engineering stress or on uniform and total elongation. Further, tests in H{sub 2} environments on specimens annealed at different temperatures showed that grain-size variation by a factor of {approx}2 had little or no effect on tensile properties.

  9. Solute redistribution and phase stability at FeCr/TiO2–x interfaces under ion irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Y.; Aguiar, J. A.; Yadav, S. K.; Anderoglu, O.; Baldwin, J. K.; Wang, Y. Q.; Valdez, James A.; Misra, A.; Luo, H. M.; Uberuaga, B. P.; et al

    2015-02-26

    Cr diffusion in trilayer thin films of 100 nm Fe–18Cr/125 nm TiO2–x/100 nm Fe–18Cr deposited on MgO substrates at 500 °C was studied by either annealing at 500 °C or Ni3+ ion irradiation at 500 °C. Microchemistry and microstructure evolution at the metal/oxide interfaces were investigated using (high-resolution) transmission electron microscopy, energy-dispersive X-ray spectroscopy and electron energy loss spectroscopy. Diffusion of Cr into the O-deficient TiO2 layer, with negligible segregation to the FeCr/TiO2–x interface itself, was observed under both annealing and irradiation. Cr diffusion into TiO2–x was enhanced in ion-irradiated samples as compared to annealed. Irradiation-induced voids and amorphization ofmore » TiO2–x was also observed. The experimental results are rationalized using first-principles calculations that suggest an energetic preference for substituting Ti with Cr in sub-stoichiometric TiO2. Furthermore, the implications of these results on the irradiation stability of oxide-dispersed ferritic alloys are discussed.« less

  10. Ferromagnetic superexchange in insulating Cr2MoO6 by controlling orbital hybridization

    SciTech Connect (OSTI)

    Zhu, M.; Do, D.; Dela Cruz, Clarina R.; Dun, Zhiling; Cheng, J. -G.; Goto, H.; Uwatoko, Yoshiya; Zou, T.; Zhou, Haidon D.; Mahanti, Subhendra D.; Ke, Xianglin

    2015-09-11

    We report the magnetic and electronic structures of the newly synthesized inverse-trirutile compound Cr2MoO6. Despite the same crystal symmetry and similar bond-lengths and bond-angles to Cr2TeO6, Cr2MoO6 possesses a magnetic structure of the Cr2MoO6 type, different from that seen in Cr2TeO6. Ab-initio electronic structure calculations show that the sign and strength of the Cr-O-Cr exchange coupling is strongly influenced by the hybridization between Mo 4d and O 2p orbitals. This result further substantiates our recently proposed mechanism for tuning the exchange interaction between two magnetic atoms by modifying the electronic states of the non-magnetic atoms in the exchange path through orbital hybridization. This approach is fundamentally different from the conventional methods of controlling the exchange interaction by either carrier injection or through structural distortions.

  11. Analysis of the FeCrAl Accident Tolerant Fuel Concept Benefits during BWR Station Blackout Accidents

    SciTech Connect (OSTI)

    Robb, Kevin R

    2015-01-01

    Iron-chromium-aluminum (FeCrAl) alloys are being considered for fuel concepts with enhanced accident tolerance. FeCrAl alloys have very slow oxidation kinetics and good strength at high temperatures. FeCrAl could be used for fuel cladding in light water reactors and/or as channel box material in boiling water reactors (BWRs). To estimate the potential safety gains afforded by the FeCrAl concept, the MELCOR code was used to analyze a range of postulated station blackout severe accident scenarios in a BWR/4 reactor employing FeCrAl. The simulations utilize the most recently known thermophysical properties and oxidation kinetics for FeCrAl. Overall, when compared to the traditional Zircaloy-based cladding and channel box, the FeCrAl concept provides a few extra hours of time for operators to take mitigating actions and/or for evacuations to take place. A coolable core geometry is retained longer, enhancing the ability to stabilize an accident. Finally, due to the slower oxidation kinetics, substantially less hydrogen is generated, and the generation is delayed in time. This decreases the amount of non-condensable gases in containment and the potential for deflagrations to inhibit the accident response.

  12. Tensile and impact properties of General Atomics 832864 heat of V-4Cr-4Ti alloy

    SciTech Connect (OSTI)

    Tsai, H.; Nowicki, L.J.; Gazda, J.; Billone, M.C.; Smith, D.L.; Johnson, W.R.; Trester, P.

    1998-09-01

    A 1300-kg heat of V-4Cr-4Ti alloy was procured by General Atomics (GA) for the DIII-D radiative divertor program. To determine the mechanical properties of this alloy, tensile and Charpy tests were conducted on specimens prepared from pieces of 4.8-mm-thick as-rolled plates, a major product form for the DIII-D application. The tensile tests were conducted at three temperatures, 26, 280 and 380 C, the last two being the anticipated peak temperatures during DIII-D boronization and postvent bake-out, respectively. Results from these tests show that the tensile and impact properties of the 832864 heat are comparable to those of the other smaller V-(4-5)Cr-(4-5)Ti alloy heats previously developed by the US Fusion Materials Program and that scale-up of vanadium alloy production can be successfully achieved as long as reasonable process control is implemented.

  13. Handbook for electron beam welding of 8-inch thick 2-1/4 Cr-1 Mo

    SciTech Connect (OSTI)

    Weber, Charles M.

    1980-08-01

    Purpose of this handbook is to provide a detailed procedure for electron beam welding 8 in. thick SA387 Grade 22 Class 2. Adherence to the procedure will allow others to produce electron beam welds in 8 in. thick 2-1/4 Cr-1 Mo. A justification or description of the effects of alterations of the welding procedure is not included in this report. These effects, along with a metallographic characterization and the mechanical properties produced by the welding procedure, etc., are described in report DOE/10244-10, Electron Beam Welding of 8-in. thick 2-1/4 Cr-1 Mo, Final Report under Contract DE-AC05-77OR10244.

  14. An image quality comparison of standard and dual-side read CR systems for pediatric radiology

    SciTech Connect (OSTI)

    Monnin, P.; Holzer, Z.; Wolf, R.; Neitzel, U.; Vock, P.; Gudinchet, F.; Verdun, F.R.

    2006-02-15

    An objective analysis of image quality parameters was performed for a computed radiography (CR) system using both standard single-side and prototype dual-side read plates. The pre-sampled modulation transfer function (MTF), noise power spectrum (NPS), and detective quantum efficiency (DQE) for the systems were determined at three different beam qualities representative of pediatric chest radiography, at an entrance detector air kerma of 5 {mu}Gy. The NPS and DQE measurements were realized under clinically relevant x-ray spectra for pediatric radiology, including x-ray scatter radiations. Compared to the standard single-side read system, the MTF for the dual-side read system is reduced, but this is offset by a significant decrease in image noise, resulting in a marked increase in DQE (+40%) in the low spatial frequency range. Thus, for the same image quality, the new technology permits the CR system to be used at a reduced dose level.

  15. Cyclic Corrosion and Chlorination of an FeCrAl Alloy in the Presence of KCl

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Israelsson, Niklas; Unocic, Kinga A.; Hellström, K.; Svensson, J-E; Johansson, L-G

    2015-05-30

    The KCl-induced corrosion of the FeCrAl alloy Kanthal® APMT in an O2 + N2 + H2O environment was studied at 600 °C. The samples were pre-oxidized prior to exposure in order to investigate the protective nature of alumina scales in the present environment. The microstructure and composition of the corroded surface was investigated in detail. Corrosion started at flaws in the pre-formed α-alumina scales, i.e. α-alumina was protective in itself. Consequently, KCl-induced corrosion started locally and, subsequently, spread laterally. An electrochemical mechanism is proposed here by which a transition metal chloride forms in the alloy and K2CrO4 forms at themore » scale/gas interface. Scale de-cohesion is attributed to the formation of a sub-scale transition metal chloride.« less

  16. Fuel Performance Calculations for FeCrAl Cladding in BWRs

    SciTech Connect (OSTI)

    George, Nathan; Sweet, Ryan; Maldonado, G. Ivan; Wirth, Brian D.; Powers, Jeffrey J.; Worrall, Andrew

    2015-01-01

    This study expands upon previous neutronics analyses of the reactivity impact of alternate cladding concepts in boiling water reactor (BWR) cores and directs focus toward contrasting fuel performance characteristics of FeCrAl cladding against those of traditional Zircaloy. Using neutronics results from a modern version of the 3D nodal simulator NESTLE, linear power histories were generated and supplied to the BISON-CASL code for fuel performance evaluations. BISON-CASL (formerly Peregrine) expands on material libraries implemented in the BISON fuel performance code and the MOOSE framework by providing proprietary material data. By creating material libraries for Zircaloy and FeCrAl cladding, the thermomechanical behavior of the fuel rod (e.g., strains, centerline fuel temperature, and time to gap closure) were investigated and contrasted.

  17. EXTENDED ANALYSIS OF THE SPECTRUM OF SINGLY IONIZED CHROMIUM (Cr II)

    SciTech Connect (OSTI)

    Sansonetti, Craig J.; Nave, Gillian

    2014-08-01

    We have made new observations of the spectrum of singly ionized chromium (Cr II) in the region 2850-37900 Å with the National Institute of Standards and Technology 2 m Fourier transform spectrometer. These data extend our previously reported observations in the near-ultra-violet region. We present a comprehensive list of more than 5300 Cr II lines classified as transitions among 456 even and 457 odd levels, 179 of which are newly located in this work. Using highly excited levels of the 3d {sup 4}({sup 5} D)5g, 3d {sup 4}({sup 5} D)6g, and 3d {sup 4}({sup 5}D)6h configurations, we derive an improved ionization energy of 132971.02 ± 0.12 cm{sup –1} (16.486305 ± 0.000015 eV)

  18. Néel temperature of Cr{sub 2}O{sub 3} in Cr{sub 2}O{sub 3}/Co exchange-coupled system: Effect of buffer layer

    SciTech Connect (OSTI)

    Pati, Satya Prakash E-mail: phy-satya@yahoo.co.in; Shimomura, Naoki; Nozaki, Tomohiro; Sahashi, Masashi; Shibata, Tatsuo

    2015-05-07

    The lattice parameter dependence of the Néel temperature T{sub N} of thin Cr{sub 2}O{sub 3} in a Cr{sub 2}O{sub 3}/Co exchange-coupled system is investigated. Lattice-mismatch-induced strain is generated in Cr{sub 2}O{sub 3} by using different buffer layers. The lattice parameters are determined from out-of-plane and in-plane X-ray diffraction measurements. The Néel temperature is detected by direct temperature-dependent magnetization measurement as well as the temperature-dependent interface exchange coupling energy. It is observed that in-plane lattice contraction can enhance T{sub N} in Cr{sub 2}O{sub 3}, which is consistent with theoretical calculations.

  19. X-ray absorption and resonant inelastic x-ray scattering (RIXS) show the presence of Cr{sup +} at the surface and in the bulk of CrF{sub 2}

    SciTech Connect (OSTI)

    Jiménez-Mier, J.; Olalde-Velasco, P.; Yang, W.-L.; Denlinger, J.

    2015-07-23

    X-Ray absorption and resonant inelastic x-ray scattering (RIXS) spectra of CrF{sub 2} recorded at the chromium L{sub 2,3} are presented. An atomic multiplet crystal field calculation is compared with the experimental data. Experiment and theory are in agreement once the calculation includes three chromium oxidation states, namely Cr{sup +}, Cr{sup 2+}, and Cr{sup 3+}. X-Ray absorption allows a direct determination of the surface oxidation, while the RIXS spectra shows the presence of these three oxidation states in the sample bulk. To give a quantitative interpretation of the RIXS data the effect of the incomming and outgoing photon penetration depth and self-absorption must be considered. For the much simpler case of MnF{sub 2}, with only one metal oxidation state, the measured RIXS spectra relative intensities are found to be proportional to the square of the sample attenuation length.

  20. Thermophysical and mechanical properties of Fe-(8-9)%Cr reduced activation steels

    SciTech Connect (OSTI)

    Zinkle, S.J.; Robertson, J.P.; Klueh, R.L.

    1998-09-01

    The key thermophysical and mechanical properties for 8--9%Cr reduced activation ferritic/martensitic steels are summarized, including temperature-dependent tensile properties in the unirradiated and irradiated conditions, stress-rupture behavior, elastic constants, thermal conductivity, thermal expansion, specific heat, and ductile-to-brittle transition temperature. The estimated lower and upper temperatures limits for structural applications are 250 and 550 C due to radiation hardening/embrittlement and thermal creep considerations, respectively.

  1. Audit Report: CR-B-02-02 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Audit Report: CR-B-02-02 August 22, 2002 Procurement Administration at Brookhaven National Laboratory In May 1999, the Office of Inspector General evaluated certain aspects of Brookhaven National Laboratory's (Brookhaven) procurement function and found that Brookhaven had not fully enforced the terms of its subcontracts for health physics technicians. This audit, Health Physics Technician Subcontracts at Brookhaven National Laboratory (ER-B-99-08, May 1999), recommended that Brookhaven

  2. Audit Report: CR-B-97-04 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5, 1997 Audit OF Controls Over The ADP Support Services Contract The Federal Acquisition Regulation requires the Department of Energy (Department) to ensure that efficient methods and effective cost controls are used over its cost-reimbursement contracts. Our objective was to determine whether the program offices at the Department's Headquarters were managing their Automated Data Processing (ADP) support services contract costs. Audit Report: CR-B-97-04 (60.63 KB) More Documents &

  3. Audit Report: CR-B-98-02 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Audit Report: CR-B-98-02 November 14, 1997 Audit of Management of the Laboratory Directed Research and Development Program at the Lawrence Livermore National Laboratory The Department's national laboratories, since their establishment, have been permitted to conduct a limited amount of discretionary research activities. The Department's Defense Program laboratories, such as the Lawrence Livermore National Laboratory, generate funding for Laboratory Directed Research and Development (LDRD)

  4. Audit Report: CR-FS-99-01 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9-01 Audit Report: CR-FS-99-01 June 15, 1999 Management Report Audit of the Department of Energy's Consolidated Financial Statements for Fiscal Year 1998 As required by the Government Management Reform Act of 1994, we audited the U.S. Department of Energy's (Department) consolidated financial statements as of and for the years ended September 30, 1998 and 1997 to determine whether they presented fairly, in all material respects, the Department's financial position, net cost, changes in net

  5. Magnetic and structural properties of nanostructured Fe–20Al–2Cr powder mixtures

    SciTech Connect (OSTI)

    Zerniz, N.; Azzaza, S.; Chater, R.; Abbas, H.; Bououdina, M.; Bouchelaghem, W.

    2015-02-15

    Nanostructured Fe–20Al–2Cr (wt.%) powders have been prepared using high energy planetary ball-mill. Changes in structural, morphological and magnetic properties of the powders during mechanical alloying (MA) and during subsequent annealing have been examined by X-ray diffraction, scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM). The observed structural and microstructural changes have been related to several processes occurring during MA. After MA, the material becomes significantly disordered and refines to nanoscale grain sizes (~ 14 nm). The obtained bcc α-Fe(Al,Cr) solid solution shows a ferromagnetic behavior. Upon subsequent annealing at 400 °C, α-Fe{sub 2}O{sub 3} and spinel oxides are formed at the surface of particles, while structural defects disappeared as Fe(Al,Cr) solid solution becomes more ordered and grain growth occurs. The saturation magnetization (Ms) shows lower values after annealing, attributed to the formation of metal oxides with low magnetic moment. - Graphical abstract: Display Omitted - Highlights: • Nanostructured Fe–Al–Cr powders were prepared by MA. • Careful analysis of the XRD patterns by using the Rietveld refinement • The lattice distortion is evidenced by the increase of both the lattice parameter and the static Debye Waller parameter. • Annealing at 400 °C stabilizes the microstructure at the nanometer range and leads to the formation of Fe{sub 3}O{sub 4} and Fe{sub 2}O{sub 3} oxides. • Both the milled and annealed samples are ferromagnetic.

  6. Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

    SciTech Connect (OSTI)

    Wang, Li; Li, Li

    2015-10-22

    The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in natural systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport

  7. Audit Report: CR-L-01-06 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    L-01-06 Audit Report: CR-L-01-06 February 8, 2001 Federal Managers' Financial Integrity Act Audit Report We reviewed the Department of Energy's (Department) progress in implementing the Federal Managers' Financial Integrity Act (FMFIA) of 1982. The review was made to assist you in determining whether the evaluations of the systems of management, accounting, and administrative controls were carried out in a reasonable and prudent manner by the Department for Fiscal Year 2000. Audit Report:

  8. The MSFR as a flexible CR reactor: the viewpoint of safety

    SciTech Connect (OSTI)

    Fiorina, C.; Cammi, A.; Franceschini, F.; Krepel, J.

    2013-07-01

    In this paper, the possibility has first been discussed of using the liquid-fuelled Molten Salt Fast Reactor (MSFR) as a flexible conversion ratio (CR) reactor without design modification. By tuning the reprocessing rate it is possible to determine the content of fission products in the core, which in turn can significantly affect the neutron economy without incurring in solubility problems. The MSFR can thus be operated as U-233 breeder (CR>1), iso-breeder (CR=1) and burner reactor (CR<1). In particular a 40 year doubling time can be achieved, as well as a considerable Transuranics and MA (minor actinide) burning rate equal to about 150 kg{sub HN}/GWE-yr. The safety parameters of the MSFR have then been evaluated for different fuel cycle strategies. Th use and a softer spectrum combine to give a strong Doppler coefficient, one order of magnitude higher compared to traditional fast reactors (FRs). The fuel expansion coefficient is comparable to the Doppler coefficient and is only mildly affected by core compositions, thus assisting the fuel cycle flexibility of the MSFR. ?eff and generation time are comparable to the case of traditional FRs, if a static fuel is assumed. A notable reduction of ?eff is caused by salt circulation, but a low value of this parameter is a limited concern in the MSFR thanks to the lack of a burnup reactivity swing and of positive feedbacks. A simple approach has also been developed to evaluate the MSFR capabilities to withstand all typical double-fault accidents, for different fuel cycle options.

  9. First-principles study of the structural and elastic properties of Cr{sub 2}AlX (X=N, C) compounds

    SciTech Connect (OSTI)

    Cui Shouxin; Wei Dongqing; Hu Haiquan; Feng Wenxia; Gong Zizheng

    2012-07-15

    The structural, electronic and elastic properties of Cr{sub 2}AlX, with X=N, C, have been investigated at the density functional theory level by applying a plane-wave pseudopotential approach. The band structure and density of states reveal the metallic features of Cr{sub 2}AlX. The total and projected density of states indicate that the bonding is achieved through a hybridization of Cr 3d states with Al and X-atom p states. The Cr 3d-X2p bonds are lower in energy and are stiffer than Cr 3d-Al 3p bonds. The charge density distributions indicate that there exist soft Cr-Al and relatively strong Cr-X covalent bonds, which might be responsible for their hardness. The elastic constants were obtained in the pressure range 0-100 GPa, and satisfy the stability conditions for hexagonal crystal, which indicates that these two compounds are stable in the pressure regime studied. By analyzing bulk modulus to shear modulus ratio and Cauchy pressure, Cr{sub 2}AlC is predicted to be brittleness and Cr{sub 2}AlN is ductile. The Debye temperature was obtained from the average sound velocity. - Graphical abstract: The heterogeneity of chemical bonds in Cr{sub 2}AlX (X=N, C) is observed: soft Cr-Al and relatively strong Cr-X covalent bonds might be contributed to their hardness. Highlights: Black-Right-Pointing-Pointer Cr 3d-X2p (X=N, C) bonds are lower in energy and stiffer than Cr 3d-Al 3p bonds for Cr{sub 2}AlX. Black-Right-Pointing-Pointer The hardness of Cr{sub 2}AlX might be ascribed to soft Cr-Al and relatively strong Cr-X covalent bonds. Black-Right-Pointing-Pointer The predicted brittleness of Cr{sub 2}AlC and ductility of Cr{sub 2}AlN originated from their novel structure.

  10. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed intomore » the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.« less

  11. Rapid preparation and magnetodielectric properties of trirutile Cr{sub 2}WO{sub 6}

    SciTech Connect (OSTI)

    Gaultois, Michael W.; Kemei, Moureen C.; Harada, Jaye K.; Seshadri, Ram

    2015-01-07

    Dense pellets of > 99% purity trirutile Cr{sub 2}WO{sub 6} were prepared in one step from starting oxides using spark plasma sintering, leading to simultaneous reaction and consolidation in 3 min at 1473 K. The reducing environment during processing may be partly responsible for the rapid reaction time in these oxides, with partial reduction of Cr{sup 3+} and the associated oxygen vacancies allowing rapid diffusion of cations. The low-temperature physical properties of Cr{sub 2}WO{sub 6} were examined, and a new transition at T = 5.9 K was observed as an anomaly in the temperature-dependent dielectric permittivity and a corresponding anomaly in the specific heat. A strong enhancement of the magnetocapacitance is observed below this transition temperature at T = 5.9 K and may be associated with a change from collinear spin order to more complex spin order.

  12. Ferromagnetic ordering of Cr and Fe doped p-type diamond: An ab initio study

    SciTech Connect (OSTI)

    Benecha, E. M.; Lombardi, E. B.

    2014-02-21

    Ferromagnetic ordering of transition metal dopants in semiconductors holds the prospect of combining the capabilities of semiconductors and magnetic systems in single hybrid devices for spintronic applications. Various semiconductors have so far been considered for spintronic applications, but low Curie temperatures have hindered room temperature applications. We report ab initio DFT calculations on the stability and magnetic properties of Fe and Cr impurities in diamond, and show that their ground state magnetic ordering and stabilization energies depend strongly on the charge state and type of co-doping. We predict that divacancy Cr{sup +2} and substitutional Fe{sup +1} order ferromagnetically in p-type diamond, with magnetic stabilization energies (and magnetic moment per impurity ion) of 16.9 meV (2.5 μ{sub B}) and 33.3 meV (1.0 μ{sub B}), respectively. These magnetic stabilization energies are much larger than what has been achieved in other semiconductors at comparable impurity concentrations, including the archetypal dilute magnetic semiconductor GaAs:Mn. In addition, substitutional Fe{sup +1} exhibits a strong half-metallic character, with the Fermi level crossing bands in only the spin down channel. These results, combined with diamond’s extreme properties, demonstrate that Cr or Fe dopedp-type diamond may successfully be considered in the search for room temperature spintronic materials.

  13. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed into the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.

  14. Redox Dynamics of Mixed Metal (Mn, Cr, and Fe) Ultrafine Particles

    SciTech Connect (OSTI)

    Nico, Peter S.; Kumfer, Benjamin M.; Kennedy, Ian M.; Anastasio, Cort

    2008-08-01

    The impact of particle composition on metal oxidation state, and on changes in oxidation state with simulated atmospheric aging, are investigated experimentally in flame-generated nanoparticles containing Mn, Cr, and Fe. The results demonstrate that the initial fraction of Cr(VI) within the particles decreases with increasing total metal concentration in the flame. In contrast, the initial Mn oxidation state was only partly controlled by metal loading, suggesting the importance of other factors. Two reaction pathways, one reductive and one oxidative, were found to be operating simultaneously during simulated atmospheric aging. The oxidative pathway depended upon the presence of simulated sunlight and O{sub 3}, whereas the reductive pathway occurred in the presence of simulated sunlight alone. The reductive pathway appears to be rapid but transient, allowing the oxidative pathway to dominate with longer aging times, i.e. greater than {approx}8 hours. The presence of Mn within the particles enhanced the importance of the oxidative pathway, leading to more net Cr oxidation during aging implying that Mn can mediate oxidation by removal of electrons from other particulate metals.

  15. Cr-doped TiSe2 - A layered dichalcogenide spin glass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Huixia; Tao, Jing; Krizan, Jason W.; Seibel, Elizabeth M.; Xie, Weiwei; Sahasrabudhe, Girija S.; Bergman, Susanna L.; Phelan, Brendan F.; Wang, Zhen; Zhang, Jiandi; et al

    2015-09-17

    We report the magnetic characterization of the Cr-doped layered dichalcogenide TiSe2. The temperature dependent magnetic susceptibilities are typical of those seen in geometrically frustrated insulating antiferromagnets. The Cr moment is close to the spin-only value, and the Curie–Weiss temperatures (θcw) are between –90 and –230 K. Freezing of the spin system, which is glassy, characterized by peaks in the ac and dc susceptibility and specific heat, does not occur until below T/θcw = 0.05. The CDW transition seen in the resistivity for pure TiSe2 is still present for 3% Cr substitution but is absent by 10% substitution, above which themore » materials are metallic and p-type. Structural refinements, magnetic characterization, and chemical considerations indicate that the materials are of the type Ti1–xCrxSe2-x/2 for 0 ≤ x ≤ 0.6.« less

  16. Sintered Cr/Pt and Ni/Au ohmic contacts to B12P2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Frye, Clint D.; Kucheyev, Sergei O.; Edgar, James H.; Voss, Lars F.; Conway, Adam M.; Shao, Qinghui; Nikolic, Rebecca J.

    2015-04-09

    With this study, icosahedral boron phosphide (B12P2) is a wide-bandgap semiconductor possessing interesting properties such as high hardness, chemical inertness, and the reported ability to self-heal from irradiation by high energy electrons. Here, the authors developed Cr/Pt and Ni/Au ohmic contacts to epitaxially grown B12P2 for materials characterization and electronic device development. Cr/Pt contacts became ohmic after annealing at 700 °C for 30 s with a specific contact resistance of 2×10–4 Ω cm2, as measured by the linear transfer length method. Ni/Au contacts were ohmic prior to any annealing, and their minimum specific contact resistance was ~l–4 × 10–4 Ωmore » cm2 after annealing over the temperature range of 500–800 °C. Rutherford backscattering spectrometry revealed a strong reaction and intermixing between Cr/Pt and B12P2 at 700 °C and a reaction layer between Ni and B12P2 thinner than ~25 nm at 500 °C.« less

  17. Blending Cr2O3 into a NiO-Ni electrocatalyst for sustained water splitting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gong, Ming; Zhou, Wu; Kenney, Michael James; Kapusta, Rich; Cowley, Sam; Wu, Yingpeng; Lu, Bingan; Lin, Meng -Chang; Wang, Di -Yan; Yang, Jiang; et al

    2015-08-24

    The rising H2 economy demands active and durable electrocatalysts based on low-cost, earth-abundant materials for water electrolysis/photolysis. Here we report nanoscale Ni metal cores over-coated by a Cr2O3-blended NiO layer synthesized on metallic foam substrates. The Ni@NiO/Cr2O3 triphase material exhibits superior activity and stability similar to Pt for the hydrogen-evolution reaction in basic solutions. The chemically stable Cr2O3 is crucial for preventing oxidation of the Ni core, maintaining abundant NiO/Ni interfaces as catalytically active sites in the heterostructure and thus imparting high stability to the hydrogen-evolution catalyst. The highly active and stable electrocatalyst enables an alkaline electrolyzer operating at 20more » mA cm–2 at a voltage lower than 1.5 V, lasting longer than 3 weeks without decay. Thus, the non-precious metal catalysts afford a high efficiency of about 15 % for light-driven water splitting using GaAs solar cells.« less

  18. Stability of precipitate phases in Fe-rich Fe-Cr-Ni-Mo alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T

    2015-01-01

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the and phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. Two key findings resulted from this work. One is that the phase is stable at high temperature and transformed into the phase at lowmoretemperature. The other is that both the and phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.less

  19. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed into the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.

  20. HIGH TEMPERATURE BRAZING ALLOY FOR JOINT Fe-Cr-Al MATERIALS AND AUSTENITIC AND FERRITIC STAINLESS STEELS

    DOE Patents [OSTI]

    Cost, R.C.

    1958-07-15

    A new high temperature brazing alloy is described that is particularly suitable for brazing iron-chromiumaluminum alloys. It consists of approximately 20% Cr, 6% Al, 10% Si, and from 1.5 to 5% phosphorus, the balance being iron.

  1. LaCrO{sub 3} heteroepitaxy on SrTiO{sub 3}(001) by molecular beam epitaxy

    SciTech Connect (OSTI)

    Qiao, L.; Droubay, T. C.; Bowden, M. E.; Shutthanandan, V.; Kaspar, T. C.; Chambers, S. A.

    2011-08-08

    Stoichiometric, epitaxial LaCrO{sub 3} films have been grown on SrTiO{sub 3}(001) by molecular beam epitaxy using O{sub 2} as the oxidant. Films grew in a layer-by-layer fashion, giving rise to coherently strained, structurally excellent films and surfaces which preserve the step-terrace structure of the substrate. The critical thickness is in excess of 500 A. Cr(III) near the surface is easily oxidized to Cr(V) upon exposure to atomic oxygen and reduction back to Cr(III) is readily achieved by vacuum annealing, resulting in tunability of the charge state at the B-site cation.

  2. LaCrO3 heteroepitaxy on SrTiO3(001) by molecular beam epitaxy

    SciTech Connect (OSTI)

    Qiao, Liang; Droubay, Timothy C.; Bowden, Mark E.; Shutthanandan, V.; Kaspar, Tiffany C.; Chambers, Scott A.

    2011-08-09

    Stoichiometric, epitaxial LaCrO3 films have been grown on TiO2-terminated SrTiO3(001) substrates by molecular beam epitaxy using O2 as the oxidant. Film growth occurred in a layer-by-layer fashion, giving rise to structurally excellent films and surfaces which preserve the step-terrace structure of the substrate. The critical thickness is in excess of 500 . Near-surface Cr(III) is highly susceptible to further oxidation to Cr(V), leading to the formation of a disordered phase upon exposure to atomic oxygen. Recovery of the original epitaxial LaCrO3 phase is readily achieved by vacuum annealing.

  3. Effect of lattice deformation on exchange coupling constants in Cr{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Kota, Yohei; Imamura, Hiroshi; Sasaki, Munetaka

    2014-05-07

    We studied lattice deformation effect on exchange interaction in the corundum-type Cr{sub 2}O{sub 3} theoretically. First-principles electronic structure calculations were performed to evaluate the total energy and exchange coupling constants of Cr{sub 2}O{sub 3} under lattice deformation. We found that a few percent elastic deformation is expected via misfit strain and that the first- and second-nearest neighbor exchange coupling constants of Cr{sub 2}O{sub 3} strongly depend on the lattice deformation. These results imply a possibility for improving the thermal stability of Cr{sub 2}O{sub 3} based magnetoelectric devices by lattice deformation.

  4. Cr-W-V bainitic/ferritic steel with improved strength and toughness and method of making

    DOE Patents [OSTI]

    Klueh, Ronald L.; Maziasz, Philip J.

    1994-01-01

    A high strength, high toughness Cr-W-V ferritic steel composition suitable for fast induced-radioactivity (FIRD) decay after irradiation in a fusion reactor comprises 2.5-3.5 wt % Cr, 2. This invention was made with Government support under contract DE-AC05-840R21400 awarded by the U.S. Department of Energy to Martin Marietta Energy Systems, Inc. and the Government has certain rights in this invention.

  5. Strain induced ferromagnetism in epitaxial Cr{sub 2}O{sub 3} thin films integrated on Si(001)

    SciTech Connect (OSTI)

    Punugupati, Sandhyarani Narayan, Jagdish; Hunte, Frank

    2014-09-29

    We report on the epitaxial growth and magnetic properties of antiferromagnetic and magnetoelectric (ME) Cr{sub 2}O{sub 3} thin films deposited on cubic yttria stabilized zirconia (c-YSZ)/Si(001) using pulsed laser deposition. The X-ray diffraction (2ϴ and Φ) and TEM characterizations confirm that the films were grown epitaxially. The Cr{sub 2}O{sub 3}(0001) growth on YSZ(001) occurs with twin domains. There are four domains of Cr{sub 2}O{sub 3} with in-plane rotation of 30° or 150° from each other about the [0001] growth direction. The epitaxial relation between the layers is given as [001]Si ‖ [001]YSZ ‖ [0001]Cr{sub 2}O{sub 3} and [100]Si ǁ [100]YSZ ǁ [101{sup ¯}0] Cr{sub 2}O{sub 3} or [112{sup ¯}0] Cr{sub 2}O{sub 3}. Though the bulk Cr{sub 2}O{sub 3} is an antiferromagnetic with T{sub N} = 307 K, we found that the films exhibit ferromagnetic like hysteresis loops with high saturation and finite coercive field up to 400 K. The thickness dependent magnetizations together with oxygen annealing results suggest that the ferromagnetism (FM) is due to oxygen related defects whose concentration is controlled by strain present in the films. This FM, in addition to the intrinsic magneto-electric properties of Cr{sub 2}O{sub 3}, opens the door to relevant spintronics applications.

  6. CR108, a novel vitamin K3 derivative induces apoptosis and breast tumor inhibition by reactive oxygen species and mitochondrial dysfunction

    SciTech Connect (OSTI)

    Yang, Chun-Ru; Liao, Wei-Siang; Wu, Ya-Hui; Murugan, Kaliyappan; Chen, Chinpiao; Chao, Jui-I

    2013-12-15

    Vitamin K3 derivatives have been shown to exert anticancer activities. Here we show a novel vitamin K3 derivative (S)-2-(2-hydroxy-3-methylbutylthio)naphthalene-1,4-dione, which is named as CR108 that induces apoptosis and tumor inhibition through reactive oxygen species (ROS) and mitochondrial dysfunction in human breast cancer. CR108 is more effective on the breast cancer cell death than other vitamin K3 derivatives. Moreover, CR108 induced apoptosis in both the non-HER-2-overexpressed MCF-7 and HER-2-overexpressed BT-474 breast cancer cells. CR108 caused the loss of mitochondrial membrane potential, cytochrome c released from mitochondria to cytosol, and cleaved PARP proteins for apoptosis induction. CR108 markedly increased ROS levels in breast cancer cells. N-acetylcysteine (NAC), a general ROS scavenger, completely blocked the CR108-induced ROS levels, mitochondrial dysfunction and apoptosis. Interestingly, CR108 increased the phosphorylation of p38 MAP kinase but conversely inhibited the survivin protein expression. NAC treatment prevented the activation of p38 MAP kinase and rescued the survivin protein levels. SB202190, a specific p38 MAP kinase inhibitor, recovered the survivin protein levels and attenuated the cytotoxicity of CR108-treated cells. Furthermore, CR108 inhibited the xenografted human breast tumor growth in nude mice. Together, we demonstrate that CR108 is a novel vitamin K3 derivative that induces apoptosis and tumor inhibition by ROS production and mitochondrial dysfunction and associates with the phosphorylation of p38 MAP kinase and the inhibition of survivin in the human breast cancer. - Highlights: CR108 is more effective on the cell death than other vitamin K3 derivatives. CR108 induces apoptosis and tumor inhibition by ROS and mitochondrial dysfunction. CR108 induces apoptosis by p38 kinase activation and survivin inhibition. CR108 is a potent vitamin K3 analog that can develop for breast cancer therapy.

  7. Molecular dynamical simulation of the behavior of early precipitated stage in aging process in dilute Cu-Cr alloy

    SciTech Connect (OSTI)

    Feng, J.; Liu, L.; Chen, J.; Du, Y.; Zhou, R.; Xiao, B.

    2010-06-15

    The aging behaviors of Cu-Cr alloys in the early stage at different temperatures are investigated by molecular dynamics simulations. First principles potentials are used for the interactions between Cu and Cr atoms. The initial behavior of precipitation is characterized by transmission electron microscope and electron energy disperse spectroscopy. The results showed that Cu-Cr supersaturated solid solution is thermodynamically unstable. The mean-square displacements of the atoms are used to describe the diffusivity. At room temperature, the atoms only show harmonic vibrations near the equilibrium positions. The mutual diffusion at 873 K is different from the unidirectional diffusion in low temperatures. The calculation shows that aging process is accelerated with increasing temperature, which is not only due to the lower diffusion activation energy of Cr at higher temperature, but also because Cu atoms are also participated in the aging process. When ''aging'' at 1073 K, the precipitation of Cr element is dissolved again into Cu matrix, which is an ''over-aging'' state of Cu-Cr alloy at high temperature.

  8. Synthesis and characterization of Cr-doped ZnO nanorod-array photocatalysts with improved activity

    SciTech Connect (OSTI)

    Chang, Chi-Jung Yang, Tsung-Lin; Weng, Yu-Ching

    2014-06-01

    Immobilized photocatalysts with high catalytic activity under UV light were prepared by growing Cr-doped ZnO nanorods on glass substrates by a hydrothermal method. The effects of Cr dopant on the surface texture, crystallinity, surface chemistry, and photoinduced charge separation and their relation with the photocatalytic degradation of Cr-doped ZnO were investigated by scanning electron microscopy, diffuse reflectance spectra, photoelectrochemical scanning electrochemical microscopy, and X-ray photoemission spectroscopy. Adding the appropriate amount of Cr dopant is a powerful way to enhance the separation of charge carriers in ZnO photocatalyst. The photocatalytic activity was improved due to the increase in surface oxygen vacancies, the separation of charge carriers, modification of the band gap, and the large surface area of the doped ZnO nanorod photocatalyst. - Graphical abstract: Photoinduced charge separation and its relation with the photocatalytic degradation activity of Cr-doped ZnO were investigated by photoelectrochemical scanning electrochemical microscopy. - Highlights: Cr dopant enhances separation of charge carries in ZnO nanorod photocatalyst. Photoinduced charge carries separation monitored by PEC-SECM. The higher the photocurrent is, the higher the photocatalytic activity is. Degradation of DB86 dye solutions under visible light finished within 50 min. Higher activity due to more oxygen vacancy, tuned band gap and more surface area.

  9. Hole-induced insulator-to-metal transition in La1-xSrxCrO3 epitaxial films

    SciTech Connect (OSTI)

    Zhang, Hongliang; Du, Yingge; Sushko, Petr; Bowden, Mark E.; Shutthanandan, V.; Sallis, Shawn; Piper, Louis F. J.; Chambers, Scott A.

    2015-04-01

    We have investigated the evolution of the structural and electronic properties of La1-xSrxCrO3 (0 ? x ? 1) epitaxial films deposited by molecular beam epitaxy (MBE) using x-ray diffraction, x-ray photoemission spectroscopy, x-ray absorption spectroscopy, electrical transport, and ab initio modeling. LaCrO3 is an antiferromagnetic Mott insulator whereas stoichiometric SrCrO3 is a metal. Substituting Sr2+ for La3+ in LaCrO3 effectively dopes holes into the top of valence band, leading to Cr4+ (3d2) local electron configurations. Core-level and valence-band features monotonically shift to lower binding energy with increasing x, indicating downward movement of the Fermi level toward the valence band maximum. An insulator-to-metal like transition is observed at x ? 0. 65 even as the material becomes a p-type semiconductor at lower doping level and eventually becomes degenerately doped. Valence band x-ray photoemission spectroscopy reveals diminution of electronic state density at the top of the valence band while O K-edge x-ray absorption spectroscopy shows the development of a new unoccupied state above the Fermi level as holes are doped into LaCrO3. These results indicate a pronounced redistribution of electronic state density of states upon hole doping, a result that is also obtained by density functional theory with a Hubbard U correction.

  10. Characterization of Cr poisoning in a solid oxide fuel cell cathode using a high-energy x-ray microbeam.

    SciTech Connect (OSTI)

    Liu, D. J.; Almer, J.; Cruse, T.

    2010-01-01

    A key feature of planar solid oxide fuel cells (SOFCs) is the feasibility of using metallic interconnects made of high temperature ferritic stainless steels, which reduce system cost while providing excellent electric conductivity. Such interconnects, however, contain high levels of chromium, which has been found to be associated with SOFC cathode performance degradation at SOFC operating temperatures; a phenomenon known as Cr poisoning. Here, we demonstrate an accurate measurement of the phase and concentration distributions of Cr species in a degraded SOFC, as well as related properties including deviatoric strain, integrated porosity, and lattice parameter variation, using high energy microbeam X-ray diffraction and radiography. We unambiguously identify (MnCr){sub 3}O{sub 4} and Cr{sub 2}O{sub 3} as the two main contaminant phases and find that their concentrations correlate strongly with the cathode layer composition. Cr{sub 2}O{sub 3} deposition within the active cathode region reduces porosity and produces compressive residual strains, which hinders the reactant gas percolation and can cause structural breakdown of the SOFC cathode. The information obtained through this study can be used to better understand the Cr-poisoning mechanism and improve SOFC design.

  11. Ultrathin nanosheets of CrSiTe3. A semiconducting two-dimensional ferromagnetic material

    SciTech Connect (OSTI)

    Lin, Ming -Wei; Zhung, Houlong L.; Yan, Jiaqiang; Ward, Thomas Zac; Puretzky, Alexander A.; Rouleau, Christopher M.; Gai, Zheng; Liang, Liangbo; Meunier, Vincent; Ganesh, Panchapakesan; Kent, Paul R. C.; Sumpter, Bobby G.; Mandrus, David G.; Geohegan, David B.; Xiao, Kai

    2015-11-27

    Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have recently shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained elusive. In this work we for the first time exfoliate the CrSiTe3, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO2 substrate. The Raman spectra show the good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra of 2D CrSiTe3, giving a strong evidence for the existence of 2D CrSiTe3 crystals. When the thickness of the CrSiTe3 crystals is reduced to few-layers, we observed a clear change in resistivity at 80~120 K, consistent with the theoretical calculations on the Curie temperature (Tc) of ~80 K for the magnetic ordering of 2D CrSiTe3 crystals. As a result, the ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable numerous applications in nano-spintronics.

  12. Effect of annealing treatment on the electrical characteristics of Pt/Cr-embedded ZnO/Pt resistance random access memory devices

    SciTech Connect (OSTI)

    Chang, Li-Chun; Kao, Hsuan-Ling; Liu, Keng-Hao

    2014-03-15

    ZnO/Cr/ZnO trilayer films sandwiched with Pt electrodes were prepared for nonvolatile resistive memory applications. The threshold voltage of a ZnO device embedded with a 3-nm Cr interlayer was approximately 50% lower than that of a ZnO monolayer device. This study investigated threshold voltage as a function of Cr thickness. Both the ZnO monolayer device and the Cr-embedded ZnO device structures exhibited resistance switching under electrical bias both before and after rapid thermal annealing (RTA) treatment, but resistive switching effects in the two cases exhibited distinct characteristics. Compared with the as-fabricated device, the memory cell after RTA demonstrated remarkable device parameter improvements, including a lower threshold voltage, a lower write current, and a higher R{sub off}/R{sub on} ratio. Both transmission electron microscope observations and Auger electron spectroscopy revealed that the Cr charge trapping layer in Cr-embedded ZnO dispersed uniformly into the storage medium after RTA, and x-ray diffraction and x-ray photoelectron spectroscopy analyses demonstrated that the Cr atoms lost electrons to become Cr{sup 3+} ions after dispersion. These results indicated that the altered status of Cr in ZnO/Cr/ZnO trilayer films during RTA treatment was responsible for the switching mechanism transition.

  13. Correlation between morphology, chemical environment, and ferromagnetism in the intrinsic-vacancy dilute magnetic semiconductor Cr-doped Ga2Se3/Si(001)

    SciTech Connect (OSTI)

    Yitamben, E.N.; Arena, D.; Lovejoy, T.C.; Pakhomov, A.B.; Heald, S.M.; Negusse, E.; Ohuchi, F.S.; Olmstead, M.A.

    2011-01-28

    Chromium-doped gallium sesquiselenide, Cr:Ga{sub 2}Se{sub 3}, is a member of a new class of dilute magnetic semiconductors exploiting intrinsic vacancies in the host material. The correlation among room-temperature ferromagnetism, surface morphology, electronic structure, chromium concentration, and local chemical and structural environments in Cr:Ga{sub 2}Se{sub 3} films grown epitaxially on silicon is investigated with magnetometry, scanning tunneling microscopy, photoemission spectroscopy, and x-ray absorption spectroscopy. Inclusion of a few percent chromium in Ga{sub 2}Se{sub 3} results in laminar, semiconducting films that are ferromagnetic at room temperature with a magnetic moment 4{micro}{sub B}/Cr. The intrinsic-vacancy structure of defected-zinc-blende {beta}-Ga{sub 2}Se{sub 3} enables Cr incorporation in a locally octahedral site without disrupting long-range order, determined by x-ray absorption spectroscopy, as well as strong overlap between Cr 3d states and the Se 4p states lining the intrinsic-vacancy rows, observed with photoemission. The highest magnetic moment per Cr is observed near the solubility limit of roughly one Cr per three vacancies. At higher Cr concentrations, islanded, metallic films result, with a magnetic moment that depends strongly on surface morphology. The effective valence is Cr{sup 3+} in laminar films, with introduction of Cr{sup 0} upon islanding. A mechanism is proposed for laminar films whereby ordered intrinsic vacancies mediate ferromagnetism.

  14. Synchrotron-based imaging of chromium and  γ-H2AX immunostaining in the duodenum following repeated exposure to Cr(VI) in drinking water

    SciTech Connect (OSTI)

    Thompson, Chad M.; Seiter, Jennifer; Chappell, Mark A.; Tappero, Ryan V.; Proctor, Deborah M.; Suh, Mina; Wolf, Jeffrey C.; Haws, Laurie C.; Vitale, Rock; Mittal, Liz; Kirman, Christopher R.; Hays, Sean M.; Harris, Mark A.

    2014-10-28

    Current drinking water standards for chromium are for the combined total of both hexavalent and trivalent chromium (Cr(VI) and Cr(III)). However, recent studies have shown that Cr(III) is not carcinogenic to rodents, whereas mice chronically exposed to high levels of Cr(VI) developed duodenal tumors. These findings may suggest the need for environmental standards specific for Cr(VI). Whether the intestinal tumors arose through a mutagenic or non-mutagenic mode of action (MOA) greatly impacts how drinking water standards for Cr(VI) are derived. Herein, X-ray fluorescence (spectro)microscopy (µ-XRF) was used to image the Cr content in the villus and crypt regions of duodena from B6C3F1 mice exposed to 180 mg/l Cr(VI) in drinking water for 13 weeks. DNA damage was also assessed by γ-H2AX immunostaining. Exposure to Cr(VI) induced villus blunting and crypt hyperplasia in the duodenum—the latter evidenced by lengthening of the crypt compartment by ~2-fold with a concomitant 1.5-fold increase in the number of crypt enterocytes. γ-H2AX immunostaining was elevated in villi, but not in the crypt compartment. µ-XRF maps revealed mean Cr levels >30 times higher in duodenal villi than crypt regions; mean Cr levels in crypt regions were only slightly above background signal. Despite the presence of Cr and elevated γ-H2AX immunoreactivity in villi, no aberrant foci indicative of transformation were evident. Lastly, these findings do not support a MOA for intestinal carcinogenesis involving direct Cr-DNA interaction in intestinal stem cells, but rather support a non-mutagenic MOA involving chronic wounding of intestinal villi and crypt cell hyperplasia.

  15. Synchrotron-based imaging of chromium and  γ-H2AX immunostaining in the duodenum following repeated exposure to Cr(VI) in drinking water

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thompson, Chad M.; Seiter, Jennifer; Chappell, Mark A.; Tappero, Ryan V.; Proctor, Deborah M.; Suh, Mina; Wolf, Jeffrey C.; Haws, Laurie C.; Vitale, Rock; Mittal, Liz; et al

    2014-10-28

    Current drinking water standards for chromium are for the combined total of both hexavalent and trivalent chromium (Cr(VI) and Cr(III)). However, recent studies have shown that Cr(III) is not carcinogenic to rodents, whereas mice chronically exposed to high levels of Cr(VI) developed duodenal tumors. These findings may suggest the need for environmental standards specific for Cr(VI). Whether the intestinal tumors arose through a mutagenic or non-mutagenic mode of action (MOA) greatly impacts how drinking water standards for Cr(VI) are derived. Herein, X-ray fluorescence (spectro)microscopy (µ-XRF) was used to image the Cr content in the villus and crypt regions of duodenamore » from B6C3F1 mice exposed to 180 mg/l Cr(VI) in drinking water for 13 weeks. DNA damage was also assessed by γ-H2AX immunostaining. Exposure to Cr(VI) induced villus blunting and crypt hyperplasia in the duodenum—the latter evidenced by lengthening of the crypt compartment by ~2-fold with a concomitant 1.5-fold increase in the number of crypt enterocytes. γ-H2AX immunostaining was elevated in villi, but not in the crypt compartment. µ-XRF maps revealed mean Cr levels >30 times higher in duodenal villi than crypt regions; mean Cr levels in crypt regions were only slightly above background signal. Despite the presence of Cr and elevated γ-H2AX immunoreactivity in villi, no aberrant foci indicative of transformation were evident. Lastly, these findings do not support a MOA for intestinal carcinogenesis involving direct Cr-DNA interaction in intestinal stem cells, but rather support a non-mutagenic MOA involving chronic wounding of intestinal villi and crypt cell hyperplasia.« less

  16. Effect of Corrosion Film Composition and Structure on the Corrosion Kinetics of Ni-Cr-Fe Alloys in High Temperature Water

    SciTech Connect (OSTI)

    P.M. Rosecrans; N. Lewis; D.J. Duquette

    2002-02-27

    Nickel alloys such as Alloy 600 undergo Stress Corrosion Cracking (SCC) in pure water at temperatures between about 260 C and the critical point. Increasing the level of Cr in Ni-Fe-Cr alloys increases SCC resistance in aerated and deaerated water. The mechanism is not understood. The effect of Cr composition on oxide microstructure and corrosion kinetics of Ni-Fe-Cr alloys was determined experimentally, to evaluate whether the anodic dissolution model for SCC can account for the effect of Cr on SCC. The alloy corrosion rate and corrosion product oxide microstructure is strongly influenced by the Cr composition. Corrosion kinetics are parabolic and influenced by chromium concentration, with the parabolic constant first increasing then decreasing as Cr increases from 5 to 39%. Surface analyses using Analytical Electron microscopy (AEM) and Auger Electron Spectroscopy (AES) show that the corrosion product film that forms initially on all alloys exposed to high purity high temperature water is a nickel rich oxide. With time, the amount of chromium in the oxide film increases and corrosion proceeds toward the formation of the more thermodynamically stable spinel or hexagonal Cr-rich oxides, similar to high temperature gaseous oxidation. Due to the slower diffusion kinetics at the temperatures of water corrosion compared to those in high temperature gaseous oxidation, however, the films remain as a mixture of NiO, mixed Ni, Fe and Cr spinels, NiCrO{sub 3} and FeCrO{sub 3}. As the amount of Cr in the film increases and the nature of the film changes from NiO to spinel or hexagonal oxides, cation diffusion through the films slows, slowing the corrosion rate. These observations are qualitatively consistent with an anodic dissolution SCC mechanism. However, parametric modeling of the SCC growth process, applying available creep, oxide rupture strain and corrosion kinetics data, indicates that the anodic dissolution mechanism accounts for only a fraction of the effect of Cr

  17. Design of a 7-MV Linear Transformer Driver (LTD) for down-hole flash x-ray radiography.

    SciTech Connect (OSTI)

    Cordova, Steve Ray; Welch, Dale Robert; Oliver, Bryan Velten; Rose, David Vincent; Johnson, David Lee; Bruner, Nichelle Lee; Leckbee, Joshua J.

    2008-09-01

    Pulsed power driven flash x-ray radiography is a valuable diagnostic for subcritical experiments at the Nevada Test Site. The existing dual-axis Cygnus system produces images using a 2.25 MV electron beam diode to produce intense x-rays from a small source. Future hydrodynamic experiments will likely use objects with higher areal mass, requiring increased x-ray dose and higher voltages while maintaining small source spot size. A linear transformer driver (LTD) is a compact pulsed power technology with applications ranging from pulsed power flash x-ray radiography to high current Z-pinch accelerators. This report describes the design of a 7-MV dual-axis system that occupies the same lab space as the Cygnus accelerators. The work builds on a design proposed in a previous report [1]. This new design provides increased diode voltage from a lower impedance accelerator to improve coupling to low impedance diodes such as the self magnetic pinch (SMP) diode. The design also improves the predicted reliability by operating at a lower charge voltage and removing components that have proven vulnerable to failure. Simulations of the new design and experimental results of the 1-MV prototype are presented.

  18. Wire number dependence of the implosion dynamics, stagnation, and radiation output of tungsten wire arrays at Z driver

    SciTech Connect (OSTI)

    Mazarakis, Michael G.; Stygar, William A.; Sinars, Daniel B.; Cuneo, Michael E.; Nash, Thomas J.; Chandler, Gordon A.; Keith Matzen, M.; Porter, John L.; Struve, Kenneth W.; McDaniel, Dillon H.; Deeney, Christopher E.; Douglas, Melissa R.; Chittenden, Jerry

    2011-11-15

    We report results of the experimental campaign, which studied the initiation, implosion dynamics, and radiation yield of tungsten wire arrays as a function of the wire number. The wire array dimensions and mass were those of interest for the Z-pinch driven Inertial Confinement Fusion (ICF) program. An optimization study of the x-ray emitted peak power, rise time, and full width at half maximum was effectuated by varying the wire number while keeping the total array mass constant and equal to {approx}5.8 mg. The driver utilized was the {approx}20-MA Z accelerator before refurbishment in its usual short pulse mode of 100 ns. We studied single arrays of 20-mm diameter and 1-cm height. The smaller wire number studied was 30 and the largest 600. It appears that 600 is the highest achievable wire number with present day's technology. Radial and axial diagnostics were utilized including crystal monochromatic x-ray backlighter. An optimum wire number of {approx}375 was observed which was very close to the routinely utilized 300 for the ICF program in Sandia.

  19. Thermal aging modeling and validation on the Mo containing Fe-Cr-Ni alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-04-01

    Thermodynamics of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys is critical knowledge to understand thermal aging effect on the phase stability of Mo-containing austenitic steels, which subsequently facilitates alloy design/improvement and degradation mitigation of these materials for reactor applications. Among the intermetallic phases, Chi (χ), Laves, and Sigma (σ) are often of concern because of their tendency to cause embrittlement of the materials. The focus of this study is thermal stability of the Chi and Laves phases as they were less studied compared to the Sigma phase. Coupled with thermodynamic modeling, thermal stability of intermetallic phases in Mo containing Fe-Cr-Ni alloys was investigated at 1000, 850 and 700 C for different annealing times. The morphologies, compositions and crystal structures of the precipitates of the intermetallic phases were carefully examined by scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and transmission electron microscopy. Three key findings resulted from this study. First, the Chi phase is stable at high temperature, and with decreasing temperature it transforms into the Laves phase that is stable at low temperature. Secondly, Cr, Mo, Ni are soluble in both the Chi and Laves phases, with the solubility of Mo playing a major role in the relative stability of the intermetallic phases. Thirdly, in situ transformation from Chi phase to Laves phase was directly observed, which increased the local strain field, generated dislocations in the intermetallic phases, and altered the precipitate phase orientation relationship with the austenitic matrix. The thermodynamic models that were developed and validated were then applied to evaluating the effect of Mo on the thermal stability of intermetallic phases in type 316 and NF709 stainless steels.

  20. Effects of Partial Phase Transformation on Characteristics of 9Cr Nanostructured Ferritic Alloy

    SciTech Connect (OSTI)

    Ji Hyun, Yoon; Byun, Thak Sang; Hoelzer, David T

    2014-01-01

    The core structures of future nuclear systems require tolerance to extreme irradiation, and some critical components, for example, the fuel cladding in Sodium-cooled Fast Reactors (SFRs), have to maintain mechanical integrity to very high doses of 200 -400 dpa at high temperatures up to 700 degrees C. The high Cr nanostructured ferritic alloys (NFAs) are under intense research worldwide as a candidate core material. Although the NFAs have some admirable characteristics for high-temperature applications, their crack sensitivity is very high at high temperatures. The fracture toughness of high strength NFAs is unacceptably low above 300 degrees C. The objective of this study is to develop processes and microstructures with improved high temperature fracture toughness and ductility. To optimize the afterextrusion heat treatment condition, both the computational simulation technique on phase equilibrium and the basic microstructural and mechanical characterization have been carried out. 9 Cr-NFA was produced by the mechanical alloying of pre-alloyed Fe-9Cr base metallic powder and yttria particles, and subsequent extrusion. The post-extrusion heat-treatments of various conditions were applied to the asextruded NFA. The tensile and fracture toughness tests were conducted for as-extruded and heat-treated samples at up to 700 degrees C. Fracture toughness of the NFA has increased by more than 40% at every testing temperature after heat-treatment in the inter-critical temperature range. The increment of fracture toughness of the NFA after post-extrusion heat-treatment is attributed to the increased strength at below 500 degrees C, and an increased ductility at 700 degrees C.

  1. Conceptual design for a linear-transformer driver (LTD)-based refurbishment and upgrade of the Saturn accelerator pulse-power system.

    SciTech Connect (OSTI)

    Mazarakis, Michael Gerrassimos; Struve, Kenneth William

    2006-09-01

    The purpose of this work was to develop a conceptual design for the Saturn accelerator using the modular Liner-Transformer Driver (LTD) technology to identify risks and to focus development and research for this new technology. We present a reference design for a Saturn class driver based on a number of linear inductive voltage adders connected in parallel. This design is very similar to a design reported five years ago [1]. However, with the design reported here we use 1-MA, 100-kV LTD cavities as building blocks. These cavities have already been built and are currently in operation at the HCEI in Tomsk, Russia [2]. Therefore, this new design integrates already-proven individual components into a full system design.

  2. Alloy Design and Development of Cast Cr-W-V Ferritic Steels for Improved High-Temperature Strength for Power Generation Applications

    SciTech Connect (OSTI)

    Klueh, R.L.; Maziasz, P.J.; Vitek, J.M.; Evans, N.D.; Hashimoto, N.

    2006-09-23

    Economic and environmental concerns demand that the power-generation industry seek increased efficiency for gas turbines. Higher efficiency requires higher operating temperatures, with the objective temperature for the hottest sections of new systems {approx} 593 C, and increasing to {approx} 650 C. Because of their good thermal properties, Cr-Mo-V cast ferritic steels are currently used for components such as rotors, casings, pipes, etc., but new steels are required for the new operating conditions. The Oak Ridge National Laboratory (ORNL) has developed new wrought Cr-W-V steels with 3-9% Cr, 2-3% W, 0.25% V (compositions are in wt.%), and minor amounts of additional elements. These steels have the strength and toughness required for turbine applications. Since cast alloys are expected to behave differently from wrought material, work was pursued to develop new cast steels based on the ORNL wrought compositions. Nine casting test blocks with 3, 9, and 11% Cr were obtained. Eight were Cr-W-V-Ta-type steels based on the ORNL wrought steels; the ninth was COST CB2, a 9Cr-Mo-Co-V-Nb cast steel, which was the most promising cast steel developed in a European alloy-development program. The COST CB2 was used as a control to which the new compositions were compared, and this also provided a comparison between Cr-W-V-Ta and Cr-Mo-V-Nb compositions. Heat treatment studies were carried out on the nine castings to determine normalizing-and-tempering treatments. Microstructures were characterized by both optical and transmission electron microscopy (TEM). Tensile, impact, and creep tests were conducted. Test results on the first nine cast steel compositions indicated that properties of the 9Cr-Mo-Co-V-Nb composition of COST CB2 were better than those of the 3Cr-, 9Cr-, and 11Cr-W-V-Ta steels. Analysis of the results of this first iteration using computational thermodynamics raised the question of the effectiveness in cast steels of the Cr-W-V-Ta combination versus the Cr

  3. Creep and oxidation behavior of modified CF8C-plus with W, Cu, Ni, and Cr

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Unocic, Kinga A.; Dryepondt, Sebastien N.; Yamamoto, Yukinori; Maziasz, Philip J.

    2016-02-01

    Here, the microstructures of modified CF8C-Plus (Fe-19Cr-12Ni-0.4W-3.8Mn-0.2Mo-0.6Nb-0.5Si-0.9C) with W and Cu (CF8CPWCu) and CF8CPWCu enhanced with 21Cr + 15Ni or 22Cr + 17.5Ni were characterized in the as-cast condition and after creep testing. When imaged at lower magnifications, the as-cast microstructure was similar among all three alloys as they all contained a Nb-rich interdendritic phase and Mn-based inclusions. Transmission electron microscopy (TEM) analysis showed the presence of nanoscale Cu-rich nanoprecipitates distributed uniformly throughout the matrix of CF8CPWCu, whereas in CF8CPWCu22/17, Cu precipitates were found primarily at the grain boundaries. The presence of these nanoscale Cu-rich particles, in addition to W-richmore » Cr23C6, nanoscale Nb carbides, and Z-phase (Nb2Cr2N2), improved the creep strength of the CF8CPWCu steel. Modification of CF8CPWCu with Cr and Ni contents slightly decreased the creep strength but significantly improved the oxidation behavior at 1073 K (800 °C). In particular, the addition of 22Cr and 17.5Ni strongly enhanced the oxidation resistance of the stainless steel resulting in a 100 degrees or greater temperature improvement, and this composition provided the best balance between improving both mechanical properties and oxidation resistance.« less

  4. Audit Report: CR-B-99-02 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Audit Report: CR-B-99-02 September 30, 1999 Management of Unneeded Materials and Chemicals For more than 50 years, the U.S. Department of Energy (Department) and its contractors operated large production facilities and laboratories that acquired and produced directly or as by-products enormous amounts of non-nuclear materials such as sodium, lead, chemicals, and scrap metal. However, a mission change resulting from the end of the Cold War called into question the need for continued stockpiling

  5. Model independent interpretation of recent CR lepton data after AMS-02

    SciTech Connect (OSTI)

    Gaggero, Daniele; Maccione, Luca E-mail: luca.maccione@lmu.de

    2013-12-01

    We model the CR leptonic fluxes above 20 GeV in terms of a superposition of a standard and a charge symmetric extra component, which we generically describe as power-laws in momentum. We investigate under these hypotheses the compatibility between AMS-02, Fermi-LAT and PAMELA datasets on positron fraction, electron+positron spectrum and electron spectrum respectively. We find that it is possible to reconcile AMS and Fermi-LAT data within uncertainties, if energy-dependent effects are present in Fermi-LAT systematics. We also study possible deviations from charge symmetry in the extra component and find no compelling evidence for them.

  6. Effect of specimen size on the fracture toughness of V-4Cr-4Ti

    SciTech Connect (OSTI)

    Kurtz, R.J.; Jones, R.H.; Li, Huaxin

    1996-04-01

    J-R curves were generated using the single specimen unload-compliance technique on four specimens of V-4Cr-4Ti to determine the effect of specimen dimensions on the fracture behavior. Ductile crack initiation and growth was observed in the 6.35 mm thick specimens but not in the 12.70 mm thick specimens. The J-R curves determined from these tests were not valid per ASTM validity criteria so quantitative measures of the resistance to ductile crack initiation and growth were not obtained. These data suggests that standard fracture toughness tests were performed with small-scale DCT specimens may also not be valid.

  7. Corrosion and degradation of a polyurethane/Co-Ni-Cr-Mo pacemaker lead

    SciTech Connect (OSTI)

    Sung, P.; Fraker, A.C.

    1987-12-01

    An investigation to study changes in the metal surfaces and the polyurethane insulation of heart pacemaker leads under controlled in vitro conditions was conducted. A polyurethane (Pellethane 2363-80A)/Co-Ni-Cr-Mo (MP35N) wire lead was exposed in Hanks' physiological saline solution for 14 months and then analyzed using scanning electron microscopy, x-ray energy dispersive analysis, and small angle x-ray scattering. Results showed that some leakage of solution into the lead had occurred and changes were present on both the metal and the polyurethane surfaces.

  8. (Evaluations of neutron reactions with sup 52 Cr, sup 56 Fe, sup 58 Ni)

    SciTech Connect (OSTI)

    Fu, C.Y.

    1990-12-21

    The traveler organized and chaired the meeting of the NEANDC/NEACRP Nuclear Data Evaluation Cooperation Subgroup-I: Intercomparison of USA, European, and Japanese Evaluations for {sup 52}Cr, {sup 56}Fe, and {sup 58}Ni, held on December 3, 1990, at the NEA Data Bank in Saclay, France. The traveler held discussions with Subgroup-II members to keep track of the activities of this group in which the traveler is a member. Highlights and/or recommendations of these meetings, as well as observations of the EAF, EFF, and JEF meetings, are included in this report.

  9. Atomic-scale microstructure underneath nanoindentation in Al-Cr-N ceramic films

    SciTech Connect (OSTI)

    Zhuang, Chunqiang Li, Zhipeng; Lin, Songsheng

    2015-12-15

    In this work, Al-Cr-N ceramic films deformed by nanoindentation were peeled off from silicon substrates and their atomic-scale microstructures underneath the indenter were investigated by high resolution transmission electron microscope (HR-TEM). Dislocations were formed underneath the indenter and they accumulated along nano-grain boundaries. The accumulative dislocations triggered the crack initiation along grain boundaries, and further resulted in the crack propagation. Dislocations were also observed in nano-grains on the lateral contact area. A model was proposed to describe the variation of microstructures under nanoindentation.

  10. Nanostructured Cu-Cr alloy with high strength and electrical conductivity

    SciTech Connect (OSTI)

    Islamgaliev, R. K. Nesterov, K. M.; Bourgon, J.; Champion, Y.; Valiev, R. Z.

    2014-05-21

    The influence of nanostructuring by high pressure torsion (HPT) on strength and electrical conductivity in the Cu-Cr alloy has been investigated. Microstructure of HPT samples was studied by transmission electron microscopy with special attention on precipitation of small chromium particles after various treatments. Effect of dynamic precipitation leading to enhancement of strength and electrical conductivity was observed. It is shown that nanostructuring leads to combination of high ultimate tensile strength of 790–840 MPa, enhanced electrical conductivity of 81%–85% IACS and thermal stability up to 500 °C. The contributions of grain refinement and precipitation to enhanced properties of nanostructured alloy are discussed.

  11. Testing Novel CR-39 Detector Deployment System For Identification of Subsurface Fractures, Soda Springs, ID

    SciTech Connect (OSTI)

    McLing, Travis; Carpenter, Michael; Brandon, William; Zavala, Bernie

    2015-06-01

    The Environmental Protection Agency (EPA) has teamed with Battelle Energy Alliance, LLC (BEA) at Idaho National Laboratory (INL) to facilitate further testing of geologic-fracture-identification methodology at a field site near the Monsanto Superfund Site located in Soda Springs, Idaho. INL has the necessary testing and technological expertise to perform this work. Battelle Memorial Institute (BMI) has engaged INL to perform this work through a Work for Others (WFO) Agreement. This study continues a multi-year collaborative effort between INL and EPA to test the efficacy of using field deployed Cr-39 radon in soil portals. This research enables identification of active fractures capable of transporting contaminants at sites where fractures are suspected pathways into the subsurface. Current state of the art methods for mapping fracture networks are exceedingly expensive and notoriously inaccurate. The proposed WFO will evaluate the applicability of using cheap, readily available, passive radon detectors to identify conductive geologic structures (i.e. fractures, and fracture networks) in the subsurface that control the transport of contaminants at fracture-dominated sites. The proposed WFO utilizes proven off-the-shelf technology in the form of CR-39 radon detectors, which have been widely deployed to detect radon levels in homes and businesses. In an existing collaborative EPA/INL study outside of this workscope,. CR-39 detectors are being utilized to determine the location of active transport fractures in a fractured granitic upland adjacent to a landfill site at the Fort Devens, MA that EPA-designated as National Priorities List (NPL) site. The innovative concept of using an easily deployed port that allows the CR-39 to measure the Rn-222 in the soil or alluvium above the fractured rock, while restricting atmospheric Rn-222 and soil sourced Ra from contaminating the detector is unique to INL and EPA approach previously developed. By deploying a series of these

  12. Comparison of electric and magnetic quadrupole focusing for the low energy end of an induction-linac-ICF (Inertial-Confinement-Fusion) driver

    SciTech Connect (OSTI)

    Kim, C.H.

    1987-04-01

    This report compares two physics designs of the low energy end of an induction linac-ICF driver: one using electric quadrupole focusing of many parallel beams followed by transverse combining; the other using magnetic quadrupole focusing of fewer beams without beam combining. Because of larger head-to-tail velocity spread and a consequent rapid current amplification in a magnetic focusing channel, the overall accelerator size of the design using magnetic focusing is comparable to that using electric focusing.

  13. Reactive oxygen species mediate Cr(VI)-induced carcinogenesis through PI3K/AKT-dependent activation of GSK-3β/β-catenin signaling

    SciTech Connect (OSTI)

    Son, Young-Ok; Pratheeshkumar, Poyil; Wang, Lei; Wang, Xin; Fan, Jia; Kim, Dong-Hern; Lee, Ju-Yeon; Zhang, Zhuo; Lee, Jeong-Chae; Shi, Xianglin

    2013-09-01

    Cr(VI) compounds are known human carcinogens that primarily target the lungs. Cr(VI) produces reactive oxygen species (ROS), but the exact effects of ROS on the signaling molecules involved in Cr(VI)-induced carcinogenesis have not been extensively studied. Chronic exposure of human bronchial epithelial cells to Cr(VI) at nanomolar concentrations (10–100 nM) for 3 months not only induced cell transformation, but also increased the potential of these cells to invade and migrate. Injection of Cr(VI)-stimulated cells into nude mice resulted in the formation of tumors. Chronic exposure to Cr(VI) increased levels of intracellular ROS and antiapoptotic proteins. Transfection with catalase or superoxide dismutase (SOD) prevented Cr(VI)-mediated increases in colony formation, cell invasion, migration, and xenograft tumors. While chronic Cr(VI) exposure led to activation of signaling cascades involving PI3K/AKT/GSK-3β/β-catenin and PI3K/AKT/mTOR, transfection with catalase or SOD markedly inhibited Cr(VI)-mediated activation of these signaling proteins. Inhibitors specific for AKT or β-catenin almost completely suppressed the Cr(VI)-mediated increase in total and active β-catenin proteins and colony formation. In particular, Cr(VI) suppressed autophagy of epithelial cells under nutrition deprivation. Furthermore, there was a marked induction of AKT, GSK-3β, β-catenin, mTOR, and carcinogenic markers in tumor tissues formed in mice after injection with Cr(VI)-stimulated cells. Collectively, our findings suggest that ROS is a key mediator of Cr(VI)-induced carcinogenesis through the activation of PI3K/AKT-dependent GSK-3β/β-catenin signaling and the promotion of cell survival mechanisms via the inhibition of apoptosis and autophagy. - Highlights: • Chronic exposure to Cr(VI) induces carcinogenic properties in BEAS-2B cells. • ROS play an important role in Cr(VI)-induced tumorigenicity of BEAS-2B cells. • PI3K/AKT/GSK-3β/β-catenin signaling involved in Cr

  14. Prospects for inertial fusion energy based on a diode-pumped solid-state laser (DPSSL) driver: Overview and development path

    SciTech Connect (OSTI)

    Orth, C.D.

    1997-03-01

    It is now known with certainty that the type of fusion known as inertial fusion will work with sufficient energy input, so inertial fusion is really beyond the ``scientific breakeven`` point in many respects. The most important question that remains for inertial fusion energy (IFE) is whether this type of fusion can operate with sufficiently low input energy to make it economically feasible for energy production. The constraint for low input energy demands operation near the inertial fusion ignition threshold, and such operation creates enormous challenges to discover a target design that will produce sufficient energy gain. There are also multiple issues relating to the scientific feasibility of using a laboratory-type ``driver`` to energize a target, such as those concerning bandwidth and beam smoothing for ``direct drive,`` and extension of hohlraum plasma physics to the IFE scale for ``indirect drive.`` One driver that appears as though it will be able to meet the IFE requirements, assuming modest development and sufficient target gain, is a diode-pumped solid-state laser (DPSSL). We give an overview of this type of laser system, and explain what development remains for the economic production of electricity using this type of driver for IFE.

  15. Overview spectra and axial distribution of spectral line intensities in a high-current vacuum arc with CuCr electrodes

    SciTech Connect (OSTI)

    Lisnyak, M.; Pipa, A. V.; Gorchakov, S. E-mail: weltmann@inp-greifswald.de; Iseni, S.; Franke, St.; Khapour, A.; Methling, R.; Weltmann, K.-D. E-mail: weltmann@inp-greifswald.de

    2015-09-28

    Spectroscopic investigations of free-burning vacuum arcs in diffuse mode with CuCr electrodes are presented. The experimental conditions of the investigated arc correspond to the typical system for vacuum circuit breakers. Spectra of six species Cu I, Cu II, Cu III, Cr I, Cr II, and Cr III have been analyzed in the wavelength range 350–810 nm. The axial intensity distributions were found to be strongly dependent on the ionization stage of radiating species. Emission distributions of Cr II and Cu II can be distinguished as well as the distributions of Cr III and Cu III. Information on the axial distribution was used to identify the spectra and for identification of overlapping spectral lines. The overview spectra and some spectral windows recorded with high resolution are presented. Analysis of axial distributions of emitted light, which originates from different ionization states, is presented and discussed.

  16. Room temperature ferromagnetism in epitaxial Cr{sub 2}O{sub 3} thin films grown on r-sapphire

    SciTech Connect (OSTI)

    Punugupati, Sandhyarani Narayan, Jagdish; Hunte, Frank

    2015-05-21

    We report on the epitaxial growth and magnetic properties of Cr{sub 2}O{sub 3} thin films grown on r-sapphire substrate using pulsed laser deposition. The X-ray diffraction (XRD) (2θ and Φ) and TEM characterization confirm that the films are grown epitaxially. The r-plane (011{sup ¯}2) of Cr{sub 2}O{sub 3} grows on r-plane of sapphire. The epitaxial relations can be written as [011{sup ¯}2] Cr{sub 2}O{sub 3} ‖ [011{sup ¯}2] Al{sub 2}O{sub 3} (out-of-plane) and [1{sup ¯}1{sup ¯}20] Cr{sub 2}O{sub 3} ‖ [1{sup ¯}1{sup ¯}20] Al{sub 2}O{sub 3} (in-plane). The as-deposited films showed ferromagnetic behavior up to 400 K but ferromagnetism almost vanishes with oxygen annealing. The Raman spectroscopy data together with strain measurements using high resolution XRD indicate that ferromagnetism in r-Cr{sub 2}O{sub 3} thin films is due to the strain caused by defects, such as oxygen vacancies.

  17. Corrosion property of 9Cr-ODS steel in nitric acid solution for spent nuclear fuel reprocessing

    SciTech Connect (OSTI)

    Takeuchi, M.; Koizumi, T.; Inoue, M.; Koyama, S.I.

    2013-07-01

    Corrosion tests of oxide dispersion strengthened with 9% Cr (9Cr-ODS) steel, which is one of the desirable materials for cladding tube of sodium-cooled fast reactors, in pure nitric acid solution, spent FBR fuel solution, and its simulated solution were performed to understand the corrosion behavior in a spent nuclear fuel reprocessing. In this study, the 9Cr-ODS steel with lower effective chromium content was evaluated to understand the corrosion behavior conservatively. As results, the tube-type specimens of the 9Cr-ODS steels suffered severe weight loss owing to active dissolution at the beginning of the immersion test in pure nitric acid solution in the range from 1 to 3.5 M. In contrast, the weight loss was decreased and they showed a stable corrosion in the higher nitric acid concentration, the dissolved FBR fuel solution, and its simulated solution by passivation. The corrosion rates of the 9Cr-ODS steel in the dissolved FBR fuel solution and its simulated solution were 1-2 mm/y and showed good agreement with each other. The passivation was caused by the shift of corrosion potential to noble side owing to increase in nitric acid concentration or oxidative ions in the dissolved FBR fuel solution and the simulated spent fuel solution. (authors)

  18. Impact of x-ray dose on track formation and data analysis for CR-39-based proton diagnostics

    SciTech Connect (OSTI)

    Rinderknecht, H. G. Rojas-Herrera, J.; Zylstra, A. B.; Frenje, J. A.; Gatu Johnson, M.; Sio, H.; Sinenian, N.; Rosenberg, M. J.; Li, C. K.; Séguin, F. H.; Petrasso, R. D.; Filkins, T.; Steidle, Jessica A.; Traynor, N.; Freeman, C.; Steidle, Jeffrey A.

    2015-12-15

    The nuclear track detector CR-39 is used extensively for charged particle diagnosis, in particular proton spectroscopy, at inertial confinement fusion facilities. These detectors can absorb x-ray doses from the experiments in the order of 1–100 Gy, the effects of which are not accounted for in the previous detector calibrations. X-ray dose absorbed in the CR-39 has previously been shown to affect the track size of alpha particles in the detector, primarily due to a measured reduction in the material bulk etch rate [Rojas-Herrera et al., Rev. Sci. Instrum. 86, 033501 (2015)]. Similar to the previous findings for alpha particles, protons with energies in the range 0.5–9.1 MeV are shown to produce tracks that are systematically smaller as a function of the absorbed x-ray dose in the CR-39. The reduction of track size due to x-ray dose is found to diminish with time between exposure and etching if the CR-39 is stored at ambient temperature, and complete recovery is observed after two weeks. The impact of this effect on the analysis of data from existing CR-39-based proton diagnostics on OMEGA and the National Ignition Facility is evaluated and best practices are proposed for cases in which the effect of x rays is significant.

  19. Highly tunable magnetism in silicene doped with Cr and Fe atoms under isotropic and uniaxial tensile strain

    SciTech Connect (OSTI)

    Zheng, Rui; Ni, Jun; Chen, Ying

    2015-12-28

    We have investigated the magnetic properties of silicene doped with Cr and Fe atoms under isotropic and uniaxial tensile strain by the first-principles calculations. We find that Cr and Fe doped silicenes show strain-tunable magnetism. (1) The magnetism of Cr and Fe doped silicenes exhibits sharp transitions from low spin states to high spin states by a small isotropic tensile strain. Specially for Fe doped silicene, a nearly nonmagnetic state changes to a high magnetic state by a small isotropic tensile strain. (2) The magnetic moments of Fe doped silicene also show a sharp jump to ∼2 μ{sub B} at a small threshold of the uniaxial strain, and the magnetic moments of Cr doped silicene increase gradually to ∼4 μ{sub B} with the increase of uniaxial strain. (3) The electronic and magnetic properties of Cr and Fe doped silicenes are sensitive to the magnitude and direction of the external strain. The highly tunable magnetism may be applied in the spintronic devices.

  20. Development and property evaluation of nuclear grade wrought FeCrAl fuel cladding for light water reactors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yamamoto, Yukinori; Pint, Bruce A.; Terrani, Kurt A.; Field, Kevin G.; Yang, Ying; Snead, Lance Lewis

    2015-10-19

    Development of nuclear grade, iron-based wrought FeCrAl alloys has been initiated for light water reactor (LWR) fuel cladding to serve as a substitute for zirconium-based alloys with enhanced accident tolerance. Ferritic alloys with sufficient chromium and aluminum additions can exhibit significantly improved oxidation kinetics in high-temperature steam environments when compared to zirconium-based alloys. In the first phase, a set of model FeCrAl alloys containing 10–20Cr, 3–5Al, and 0–0.12Y in weight percent, were prepared by conventional arc-melting and hot-working processes to explore the effect of composition on the properties of FeCrAlY alloys. It was found that the tensile properties were insensitivemore » to the alloy compositions studied; however, the steam oxidation resistance strongly depended on both the chromium and the aluminum contents. The second phase development focused on strengthening Fe-13Cr-5Al with minor alloying additions of molybdenum, niobium, and silicon. Combined with an optimized thermo-mechanical treatment, a thermally stable microstructure was produced with improved tensile properties at temperatures up to 741°C.« less

  1. Development and property evaluation of nuclear grade wrought FeCrAl fuel cladding for light water reactors

    SciTech Connect (OSTI)

    Yamamoto, Yukinori; Pint, Bruce A.; Terrani, Kurt A.; Field, Kevin G.; Yang, Ying; Snead, Lance Lewis

    2015-10-19

    Development of nuclear grade, iron-based wrought FeCrAl alloys has been initiated for light water reactor (LWR) fuel cladding to serve as a substitute for zirconium-based alloys with enhanced accident tolerance. Ferritic alloys with sufficient chromium and aluminum additions can exhibit significantly improved oxidation kinetics in high-temperature steam environments when compared to zirconium-based alloys. In the first phase, a set of model FeCrAl alloys containing 10–20Cr, 3–5Al, and 0–0.12Y in weight percent, were prepared by conventional arc-melting and hot-working processes to explore the effect of composition on the properties of FeCrAlY alloys. It was found that the tensile properties were insensitive to the alloy compositions studied; however, the steam oxidation resistance strongly depended on both the chromium and the aluminum contents. The second phase development focused on strengthening Fe-13Cr-5Al with minor alloying additions of molybdenum, niobium, and silicon. Combined with an optimized thermo-mechanical treatment, a thermally stable microstructure was produced with improved tensile properties at temperatures up to 741°C.

  2. Impact of x-ray dose on track formation and data analysis for CR-39-based proton diagnostics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rinderknecht, H. G.; Rojas-Herrera, J.; Zylstra, A. B.; Frenje, J. A.; Gatu Johnson, M.; Sio, H.; Sinenian, N.; Rosenberg, M. J.; Li, C. K.; Seguin, F. H.; et al

    2015-12-23

    The nuclear track detector CR-39 is used extensively for charged particle diagnosis, in particular proton spectroscopy, at inertial confinement fusion facilities. These detectors can absorb x-ray doses from the experiments in the order of 1–100 Gy, the effects of which are not accounted for in the previous detector calibrations. X-ray dose absorbed in the CR-39 has previously been shown to affect the track size of alpha particles in the detector, primarily due to a measured reduction in the material bulk etch rate [Rojas-Herrera et al., Rev. Sci. Instrum. 86, 033501 (2015)]. Similar to the previous findings for alpha particles, protonsmore » with energies in the range 0.5–9.1 MeV are shown to produce tracks that are systematically smaller as a function of the absorbed x-ray dose in the CR-39. The reduction of track size due to x-ray dose is found to diminish with time between exposure and etching if the CR-39 is stored at ambient temperature, and complete recovery is observed after two weeks. Lastly, the impact of this effect on the analysis of data from existing CR-39-based proton diagnostics on OMEGA and the National Ignition Facility is evaluated and best practices are proposed for cases in which the effect of x rays is significant.« less

  3. On the peculiar properties of triangular-chain EuCr{sub 3}(BO{sub 3}){sub 4} antiferromagnet

    SciTech Connect (OSTI)

    Gondek, ?.; Szytu?a, A.; Przewo?nik, J.; ?ukrowski, J.; Prokhorov, A.; Chernush, L.; Zubov, E.; Dyakonov, V.; Tyvanchuk, Yu.

    2014-02-15

    In this paper we report studies on EuCr{sub 3}(BO{sub 3}){sub 4} compound, that is a member of newly discovered family of huntite-related specimens for non-linear optics. For the first time, the uncommon temperature dependence of the EuCr{sub 3}(BO{sub 3}){sub 4} lattice parameters is reported. Additionally, the magnetism of this compound is extremely interesting. Namely, a possible interplay in between potentially magnetic rare-earth ions and 3d metal stacked within quasi-1D chain that can lead to a great variety of magnetic behaviour. Indeed, in our studies we have found 3D-long range ordering with metamagnetic behaviour, while at higher temperature the magnetic chains become uncoupled. - Graphical abstract: Torsion-like vibrations are the key to understand negative thermal expansion along the a-axis. Display Omitted - Highlights: EuCr{sub 3}(BO{sub 3}){sub 4} is a peculiar triangular-chain antiferromagnet. Rare earth sublattice is non-magnetic with Eu{sup 3+} configuration. Cr{sup 3+} magnetic moments show 1-D behaviour along with spin fluctuations. Torsion vibrations of Cr triangular tubes lead to anomalous expansion of unit cell.

  4. Microstructural characterization of external and internal oxide products on V-4Cr-4Ti

    SciTech Connect (OSTI)

    Pint, B.A.; Rice, P.M.; Chitwood, L.D.; DeVan, J.H.; DiStefano, J.R.

    1998-09-01

    Air oxidation of V-4Cr-4Ti at 500 C at 1 atm resulted in the formation of a thin (100--150 nm) external vanadium nitride layer which was identified beneath a thicker (1.5 {micro}m) vanadium oxide scale. This nitride layer would only be detected by high-resolution, analytical electron microscopy techniques. Subsequent tests comparing room temperature tensile properties for exposure in laboratory air, dry air and dry oxygen at 1 atm showed more embrittlement in air than in O{sub 2}. Internal oxidation of coarse-grained V-4Cr-4Ti at low oxygen pressures at 500 C was followed by TEM examination. In a sample with a 1400 ppmw O addition, which is sufficient to reduce the ductility to near zero, there appeared to be an oxygen denuded zone (150--250 nm) near the grain boundaries with precipitates at the grain boundaries and uniform ultra-fine (<5 nm) oxygen particles in the matrix. In a similar O-loaded specimen that was subsequently annealed for 4h at 950 C to restore ductility, large oxide particles were observed in the matrix and at the grain boundaries.

  5. Subtask 12B1: Welding development for V-Cr-Ti alloys

    SciTech Connect (OSTI)

    King, J.F.; Goodwin, G.M.; Grossbeck, M.L.; Alexander, D.J.

    1995-03-01

    Development of the metallurgical and technological basis for the welding of thick sections of V-Cr-Ti alloys. The weldability and weldment properties of the V-5Cr-5Ti alloy have been evaluated. Results for the Sigmajig test of the vanadium alloy were similar to the cracking resistance of stainless steels, and indicates hot-cracking is unlikely to be a problem. Subsize Charpy test results for GTA weld metal in the as-welded condition have shown a significant reduction in toughness compared to the base metal. The weld metal toughness properties were restored to approximately that of the base metal after exposure to a PWHT 950{degrees}C. The subsize Charpy toughness results for the EB weld metal from this same heat of vanadium alloy has shown significant improvement in properties compared to the GTA weld metal and the base metal. Further testing and analysis will be conducted to more fully characterize the properties of weld metal for each welding process and develop a basic understanding of the cause of the toughness decrease in the GTA welds. 5 figs., 1 tab.

  6. Magnetic Correlations in the Quasi-Two-Dimensional Semiconducting Ferromagnet CrSiTe3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Williams, Travis J.; Aczel, Adam A.; Lumsden, Mark D.; Nagler, Stephen E.; Stone, Matthew B.; Yan, Jiaqiang -Q.; Mandrus, D.

    2015-10-02

    Intrinsic, 2D ferromagnetic semiconductors are an important class of materials for overcoming dilute magnetic semiconductors’ limitations for spintronics. CrSiTe3 is a particularly interesting material of this class, since it can likely be exfoliated to single layers, for which Tc is predicted to increase dramatically. Establishing the nature of the bulk material’s magnetism is necessary for understanding the thin-film magnetic behavior and the material’s possible applications. In this work, we use elastic and inelastic neutron scattering to measure the magnetic properties of single crystalline CrSiTe3. We find a very small single ion anisotropy that favors magnetic ordering along the c-axis andmore » that the measured spin waves fit well to a model in which the moments are only weakly coupled along that direction. Then, we find that both static and dynamic correlations persist within the ab-plane up to at least 300 K, which is strong evidence of the material's 2D characteristics that are relevant for future studies on thin film and monolayer samples.« less

  7. Hydrogen permeation and diffusion in a 0. 2C-13Cr martensitic stainless steel

    SciTech Connect (OSTI)

    Xu, J.; Sun, X.K. . State Key Lab. of RSA); Yuan, X.Z.; Wei, B.M. . Dept. of Applied Chemistry)

    1993-10-01

    The phenomenon of hydrogen embrittlement for engineering alloys, especially for alloy steels, has long attracted the attention of material researchers. Presently, it is thought that the occurrence of the phenomenon correlates with the processes of hydrogen entry and transport in metals. Therefore, a great effort has been made to understand the hydrogen permeation and diffusion in metals and alloys. Even so, the knowledge of the hydrogen permeation and diffusion in steels with a martensitic structure is still limited. In most of the investigations performed on martensite, the electrochemical permeation technique was employed for measurement; hence, only limited data near ambient temperature have been determined. A few results obtained at higher temperature are very scattered also. For instance, the hydrogen diffusivity of AISI 4130 steel in the quenched and tempered (martensite) condition is 2 orders of magnitude higher than of cryoformed 301 stainless steel (containing 90% of [alpha][prime] martensite). In the present work, the hydrogen permeability and diffusivity of a 0.2C-13Cr martensitic stainless steel (2Cr13), roughly corresponding to AISI 420, was determined by means of the gaseous permeation technique. Measurements were made above ambient temperature.

  8. Unusual Mott transition in multiferroic PbCrO 3

    SciTech Connect (OSTI)

    Wang, Shanmin; Zhu, Jinlong; Zhang, Yi; Yu, Xiaohui; Zhang, Jianzhong; Wang, Wendan; Bai, Ligang; Qian, Jiang; Yin, Liang; Sullivan, Neil S.; Jin, Changqing; He, Duanwei; Xu, Jian; Zhao, Yusheng

    2015-11-24

    The Mott insulator in correlated electron systems arises from classical Coulomb repulsion between carriers to provide a powerful force for electron localization. When turning such an insulator into a metal, the so-called Mott transition, is commonly achieved by "bandwidth" control or "band filling." However, both mechanisms deviate from the original concept of Mott, which attributes such a transition to the screening of Coulomb potential and associated lattice contraction. We report a pressure-induced isostructural Mott transition in cubic perovskite PbCrO3. At the transition pressure of similar to 3 GPa, PbCrO3 exhibits significant collapse in both lattice volume and Coulomb potential. Concurrent with the collapse, it transforms from a hybrid multiferroic insulator to a metal. For the first time to our knowledge, these findings validate the scenario conceived by Mott. Close to the Mott criticality at similar to 300 K, fluctuations of the lattice and charge give rise to elastic anomalies and Laudau critical behaviors resembling the classic liquid-gas transition. Moreover, the anomalously large lattice volume and Coulomb potential in the low-pressure insulating phase are largely associated with the ferroelectric distortion, which is substantially suppressed at high pressures, leading to the first-order phase transition without symmetry breaking.

  9. Magnetic Correlations in the Quasi-2D Semiconducting Ferromagnet CrSiTe3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Williams, Travis J.; Aczel, Adam A.; Lumsden, Mark D.; Nagler, Stephen E.; Stone, Matthew B.; Yan, Jiaqiang; Mandrus, D.

    2015-10-02

    Intrinsic, two-dimensional ferromagnetic semiconductors are an important class of materials for overcoming the limitations of dilute magnetic semiconductors for spintronics applications. CrSiTe3 is a particularly interesting member of this class, since it can likely be exfoliated down to single layers, where Tc is predicted to increase dramatically. Establishing the nature of the magnetism in the bulk is a necessary precursor to understanding the magnetic behavior in thin film samples and the possible applications of this material. In this work, we use elastic and inelastic neutron scattering to measure the magnetic properties of single crystalline CrSiTe3. We find that there ismorea very small single ion anisotropy favoring magnetic ordering along the c-axis and that the measured spin waves fit well to a model where the moments are only weakly coupled along that direction. Finally, we find that both static and dynamic correlations persist within the ab-plane up to at least 300 K, strong evidence of this material's two-dimensional characteristics that are relevant for future studies on thin film and monolayer samples.less

  10. Localized Corrosion of a Neutron Absorbing Ni-Cr-Mo-Gd Alloy

    SciTech Connect (OSTI)

    R.E. Mizia; T. E. Lister; P. J. Pinhero; T. L. Trowbridge

    2005-04-01

    The National Spent Nuclear Fuel Program, located at the Idaho National Laboratory (INL), has developed a new nickel-chromium-molybdenum-gadolinium structural alloy for storage and long-term disposal of spent nuclear fuel (SNF). The new alloy will be used for SNF storage container inserts for nuclear criticality control. Gadolinium has been chosen as the neutron absorption alloying element due to its high thermal neutron absorption cross section. This alloy must be resistant to localized corrosion when exposed to postulated Yucca Mountain in-package chemistries. The corrosion resistance properties of three experimental heats of this alloy are presented. The alloys performance are be compared to Alloy 22 and borated stainless steel. The results show that initially the new Ni-Cr-Mo-Gd alloy is less resistant to corrosion as compared to another Ni-Cr-Mo-Gd alloy (Alloy 22); but when the secondary phase that contains gadolinium (gadolinide) is dissolved, the alloy surface becomes passive. The focus of this work is to qualify these gadolinium containing materials for ASME code qualification and acceptance in the Yucca Mountain Repository.

  11. Oxidation Resistant, Cr Retaining, Electrically Conductive Coatings on Metallic Alloys for SOFC Interconnects

    SciTech Connect (OSTI)

    Vladimir Gorokhovsky

    2008-03-31

    This report describes significant results from an on-going, collaborative effort to enable the use of inexpensive metallic alloys as interconnects in planar solid oxide fuel cells (SOFCs) through the use of advanced coating technologies. Arcomac Surface Engineering, LLC, under the leadership of Dr. Vladimir Gorokhovsky, is investigating filtered-arc and filtered-arc plasma-assisted hybrid coating deposition technologies to promote oxidation resistance, eliminate Cr volatility, and stabilize the electrical conductivity of both standard and specialty steel alloys of interest for SOFC metallic interconnect (IC) applications. Arcomac has successfully developed technologies and processes to deposit coatings with excellent adhesion, which have demonstrated a substantial increase in high temperature oxidation resistance, stabilization of low Area Specific Resistance values and significantly decrease Cr volatility. An extensive matrix of deposition processes, coating compositions and architectures was evaluated. Technical performance of coated and uncoated sample coupons during exposures to SOFC interconnect-relevant conditions is discussed, and promising future directions are considered. Cost analyses have been prepared based on assessment of plasma processing parameters, which demonstrate the feasibility of the proposed surface engineering process for SOFC metallic IC applications.

  12. Pressure dependence of the magnetic order in CrAs: a neutron diffraction investigation

    SciTech Connect (OSTI)

    Keller, L.; White, J. S.; Babkevich, P.; Susner, Michael A.; Sims, Zachary C; Safa-Sefat, Athena; Ronnow, H. M.; Ruegg, Ch.

    2015-01-29

    The suppression of magnetic order with pressure concomitant with the appearance of pressure-induced superconductivity was recently discovered in CrAs. Here we present a neutron diffraction study of the pressure evolution of the helimagnetic ground-state towards and in the vicinity of the superconducting phase. Neutron diffraction on polycrystalline CrAs was employed from zero pressure to 0.65 GPa and at various temperatures. The helimagnetic long-range order is sustained under pressure and the magnetic propagation vector does not show any considerable change. The average ordered magnetic moment is reduced from 1.73(2) μB at ambient pressure to 0.4(1) μB close to the critical pressure Pc ≈ 0.7 GPa, at which magnetic order is completely suppressed. The width of the magnetic Bragg peaks strongly depends on temperature and pressure, showing a maximum in the region of the onset of superconductivity. In conclusion, we interpret this as associated with competing ground-states in the vicinity of the superconducting phase.

  13. Influence of fatigue on the nanohardness of NiTiCr-wires

    SciTech Connect (OSTI)

    Frotscher, M.; Young, M. L.; Bei, Hongbin; George, Easo P; Neuking, K.; Eggeler, G.

    2009-01-01

    Testing parameters, such as rotational speed and bending radius, have a strong influence on the fatigue life of pseudoelastic NiTi shape-memory alloys during bending rotation fatigue (BRF) experiments [M. F. X. Wagner, Int. J. Mat. Res. 97 (2006), p. 1687-1696. and M. Frotscher, et al., Thermomechanical processing, microstructure and bending rotation fatigue of ultra-fine grained NiTiCr-wires, Proceedings of the International Conference for Shape Memory and Superelastic Technologies (SMST 2007), Tsukuba, Japan, ASM International, (2008), p. 149-158.]. Previous studies showed a decrease in the fatigue life for smaller bending radius (i.e. higher equivalent strain) and larger rotational speed. This observation is associated with an increase of dislocation density, the stabilization of stressinduced martensite during cycling, and an increase of the plateau stresses due to self-heating. In the present study, we examine the influence of these fatigue parameters on the nanohardness and shape recovery of pseudoelastic NiTiCr shape-memory alloy wires by nanoindentation. We show that nanoindentation is a suitable method for the characterization of fatigue-related microstructural changes, which affect the mechanical properties.

  14. Origin of spin gapless semiconductor behavior in CoFeCrGa: Theory and Experiment

    SciTech Connect (OSTI)

    Bainsla, Lakhan; Mallick, A. I.; Raja, M. Manivel; Coelho, A. A.; Nigam, A. K.; Johnson, D. D.; Alam, Aftab; Suresh, K. G.

    2015-07-08

    Despite a plethora of materials suggested for spintronic applications, a new class of materials has emerged, namely spin gapless semiconductors (SGS), which offers potentially more advantageous properties than existing ones. These magnetic semiconductors exhibit a finite band gap for one spin channel and a closed gap for the other. Supported by electronic-structure calculations, we report evidence of SGS behavior in equiatomic quaternary CoFeCrGa, having a cubic Heusler (prototype LiMgPdSn) structure but exhibiting chemical disorder (DO3 structure). CoFeCrGa is found to transform from SGS to half-metallic phase under pressure, which is attributed to unique electronic-structure features. The saturation magnetization (MS) was obtained at 8K agrees with the Slater-Pauling rule and the Curie temperature (TC) is found to exceed 400K. Carrier concentration (up to 250K) and electrical conductivity are observed to be nearly temperature independent, prerequisites for SGS. The anomalous Hall coefficient is estimated to be 185S/cm at 5K. Considering the SGS properties and high TC, this material appears to be promising for spintronic applications.

  15. Origin of spin gapless semiconductor behavior in CoFeCrGa: Theory and Experiment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bainsla, Lakhan; Mallick, A. I.; Raja, M. Manivel; Coelho, A. A.; Nigam, A. K.; Johnson, D. D.; Alam, Aftab; Suresh, K. G.

    2015-07-08

    Despite a plethora of materials suggested for spintronic applications, a new class of materials has emerged, namely spin gapless semiconductors (SGS), which offers potentially more advantageous properties than existing ones. These magnetic semiconductors exhibit a finite band gap for one spin channel and a closed gap for the other. Supported by electronic-structure calculations, we report evidence of SGS behavior in equiatomic quaternary CoFeCrGa, having a cubic Heusler (prototype LiMgPdSn) structure but exhibiting chemical disorder (DO3 structure). CoFeCrGa is found to transform from SGS to half-metallic phase under pressure, which is attributed to unique electronic-structure features. The saturation magnetization (MS) wasmore » obtained at 8K agrees with the Slater-Pauling rule and the Curie temperature (TC) is found to exceed 400K. Carrier concentration (up to 250K) and electrical conductivity are observed to be nearly temperature independent, prerequisites for SGS. The anomalous Hall coefficient is estimated to be 185S/cm at 5K. Considering the SGS properties and high TC, this material appears to be promising for spintronic applications.« less

  16. INFLUENCE OF CARBON AND DPA RATE ON NEUTRON-INDUCED SWELLING OF Fe-15Cr-16Ni-0.25Ti IN FFTF AT ~400 DEGREES C

    SciTech Connect (OSTI)

    Okita, Taira; Sekimura, Naoto; Garner, Francis A.; Wolfer, W. G.

    2002-12-31

    The purpose of this effort is to determine the influence of dpa rate and composition on the void swelling of simple austenitic Fe-Cr-Ni alloys. Contrary to the swelling behavior of fcc Fe-15Cr-16Ni and Fe-15Cr-16Ni-0.25Ti alloys irradiated in the same FFTF-MOTA experiment, Fe-15Cr-16Ni-0.25Ti-0.04C does not exhibit a dependence of swelling on dpa rate at approximately 400 degrees C. The transient regime of swelling is prolonged by carbon addition, however.

  17. Feasibility of developing a portable driver performance data acquisition system for human factors research: Technical tasks. Volume 1

    SciTech Connect (OSTI)

    Carter, R.J.; Barickman, F.S.; Spelt, P.F.; Schmoyer, R.L.; Kirkpatrick, J.R.

    1998-01-01

    A two-phase, multi-year research program entitled ``development of a portable driver performance data acquisition system for human factors research`` was recently completed. The primary objective of the project was to develop a portable data acquisition system for crash avoidance research (DASCAR) that will allow drive performance data to be collected using a large variety of vehicle types and that would be capable of being installed on a given vehicle type within a relatively short-time frame. During phase 1 a feasibility study for designing and fabricating DASCAR was conducted. In phase 2 of the research DASCAR was actually developed and validated. This technical memorandum documents the results from the feasibility study. It is subdivided into three volumes. Volume one (this report) addresses the last five items in the phase 1 research and the first issue in the second phase of the project. Volumes two and three present the related appendices, and the design specifications developed for DASCAR respectively. The six tasks were oriented toward: identifying parameters and measures; identifying analysis tools and methods; identifying measurement techniques and state-of-the-art hardware and software; developing design requirements and specifications; determining the cost of one or more copies of the proposed data acquisition system; and designing a development plan and constructing DASCAR. This report also covers: the background to the program; the requirements for the project; micro camera testing; heat load calculations for the DASCAR instrumentation package in automobile trunks; phase 2 of the research; the DASCAR hardware and software delivered to the National Highway Traffic Safety Administration; and crash avoidance problems that can be addressed by DASCAR.

  18. Magnetic and Structural Phase Transitions in the Spinel Compound Fe1+xCr2 xO4

    SciTech Connect (OSTI)

    Ma, Jie; Garlea, Vasile O; Rondinone, Adam Justin; Aczel, Adam A; Calder, Stuart A; Dela Cruz, Clarina R; Sinclair, R.; Tian, Wei; Chi, Songxue; Kiswandhi, Andhika; Brooks, James S.; Zhou, Haidong; Matsuda, Masaaki

    2014-01-01

    Neutron diffraction, X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2 xO4 (0.0 x 1.0). The temperature versus Fe concentration (x) phase diagram contains two magnetically ordered phases and four structural phases below 420 K. The complicated transitions are closely related to the change in the spin and orbital degrees of freedom induced by substitution of Fe ions for Cr ions. The systematic change in the crystal structure is explained by the combined effects of Jahn-Teller distortion, spin-lattice interaction, Fe2+-Fe3+ hopping, and disorder among Fe2+, Fe3+, and Cr3+ ions.

  19. Weldability of Fe-Al-Cr Overlay Coatings for CorrosionProtection in Oxidizing/Sulfidizing Environments

    SciTech Connect (OSTI)

    Regina, JR

    2003-03-04

    The effect of chromium additions to the weldability of Fe-Al based overlay claddings are currently being investigated for the corrosion protection of boiler tubes in Low NOx furnaces. The primary objective of this research is to identify weldable (crack-free) Fe-Al-Cr weld overlay coating compositions that provide corrosion resistance over long exposure times. During the current project phase, preliminary corrosion testing was conducted on several ternary Fe-Al-Cr alloys in two types of gaseous corrosion environments. These long-term corrosion tests were used to develop a target weld composition matrix and serve as a base line for future corrosion tests. Preliminary Fe-Al based welds with various aluminum concentrations and one ternary Fe-Al-Cr weld overlay were successfully deposited using a Gas Tungsten Arc Welding (GTAW) process and cracking susceptibility was evaluated on these coatings.

  20. Total Reducing Capacity in Aquifer Minerals and Sediments: Quantifying the Potential to Attenuate Cr(VI) in Groundwater

    SciTech Connect (OSTI)

    Sisman, S. Lara

    2015-07-20

    Hexavalent chromium, Cr(VI), is present in the environment as a byproduct of industrial processes. Due to its mobility and toxicity, it is crucial to attenuate or remove Cr(VI) from the environment. The objective of this investigation was to quantify potential natural attenuation, or reduction capacity, of reactive minerals and aquifer sediments. Samples of reduced-iron containing minerals such as ilmenite, as well as Puye Formation sediments representing a contaminated aquifer in New Mexico, were reacted with chromate. The change in Cr(VI) during the reaction was used to calculate reduction capacity. This study found that minerals that contain reduced iron, such as ilmenite, have high reducing capacities. The data indicated that sample history may impact reduction capacity tests due to surface passivation. Further, this investigation identified areas for future research including: a) refining the relationships between iron content, magnetic susceptibility and reduction capacity, and b) long term kinetic testing using fresh aquifer sediments.

  1. Low voltage tunneling magnetoresistance in CuCrO{sub 2}-based semiconductor heterojunctions at room temperature

    SciTech Connect (OSTI)

    Li, X. R.; Han, M. J.; Shan, C.; Hu, Z. G. Zhu, Z. Q.; Chu, J. H.; Wu, J. D.

    2014-12-14

    CuCrO{sub 2}-based heterojunction diodes with rectifying characteristics have been fabricated by combining p-type Mg-doped CuCrO{sub 2} and n-type Al-doped ZnO. It was found that the current for the heterojunction in low bias voltage region is dominated by the trap-assisted tunneling mechanism. Positive magnetoresistance (MR) effect for the heterojunction can be observed at room temperature due to the tunneling-induced antiparallel spin polarization near the heterostructure interface. The MR effect becomes enhanced with the magnetic field, and shows the maximum at a bias voltage around 0.5 V. The phenomena indicate that the CuCrO{sub 2}-based heterojunction is a promising candidate for low-power semiconductor spintronic devices.

  2. Evaluation on the Effect of Composition on Radiation Hardening and Embrittlement in Model FeCrAl Alloys

    SciTech Connect (OSTI)

    Field, Kevin G.; Briggs, Samuel A.; Edmondson, Philip; Hu, Xunxiang; Littrell, Kenneth C.; Howard, Richard; Parish, Chad M.; Yamamoto, Yukinori

    2015-09-18

    This report details the findings of post-radiation mechanical testing and microstructural characterization performed on a series of model and commercial FeCrAl alloys to assist with the development of a cladding technology with enhanced accident tolerance. The samples investigated include model alloys with simple ferritic grain structure and two commercial alloys with minor solute additions. These samples were irradiated in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) up to nominal doses of 7.0 dpa near or at Light Water Reactor (LWR) relevant temperatures (300-400 C). Characterization included a suite of techniques including small angle neutron scattering (SANS), atom probe tomography (APT), and transmission based electron microscopy techniques. Mechanical testing included tensile tests at room temperature on sub-sized tensile specimens. The goal of this work was to conduct detailed characterization and mechanical testing to begin establishing empirical and/or theoretical structure-property relationships for radiation-induced hardening and embrittlement in the FeCrAl alloy class. Development of such relationships will provide insight on the performance of FeCrAl alloys in an irradiation environment and will enable further development of the alloy class for applications within a LWR environment. A particular focus was made on establishing trends, including composition and radiation dose. The report highlights in detail the pertinent findings based on this work. This report shows that radiation hardening in the alloys is primarily composition dependent due to the phase separation in the high-Cr FeCrAl alloys. Other radiation induced/enhanced microstructural features were less dependent on composition and when observed at low number densities, were not a significant contributor to the observed mechanical responses. Pre-existing microstructure in the alloys was found to be important, with grain boundaries and pre-existing dislocation

  3. Ab initio study on noncompensated CrO codoping of GaN for enhanced solar energy conversion

    SciTech Connect (OSTI)

    Pan, Hui; Gu, Baohua; Eres, Gyula; Zhang, Zhenyu

    2010-03-01

    We describe a novel photocatalyst obtained by codoping GaN with CrO, according to a new "noncompensated" codoping concept based on first-principles calculations. The approach enables controllable narrowing of the GaN band gap with significantly enhanced carrier mobility and photocatalytic activity in the visible light region and thus offers immense potential for application in solar energy conversion, water splitting, and a variety of solar-assisted photocatalysis. Our calculations indicate that the formation energy for the cation doping is greatly reduced by noncompensated codoping with an anion. Although Cr doping alone can split the band gap with the formation of an intermediate band, the mobility is low due to carrier trapping by the localized states. The first-principles calculations also demonstrate that CrO codoping of GaN shifts the Fermi level into the conduction band resulting in high carrier density and mobility.

  4. Microstructure evolution during annealing of TiAl/NiCoCrAl multilayer composite prepared by EB-PVD

    SciTech Connect (OSTI)

    Zhang, Rubing; Zhang, Deming; Chen, Guiqing; Wang, Yuesheng

    2014-07-01

    TiAl/NiCoCrAl laminate composite sheet with a thickness of 0.4–0.6 mm as well as a dimension of 150 mm × 100 mm was fabricated successfully by using electron beam physical vapor deposition (EB-PVD) method. The annealing treatment was processed at 1123 and 1323 K for 3 h in a high vacuum atmosphere, respectively. The phase composition and microstructure of TiAl/NiCoCrAl microlaminated sheet have been analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Based on the sheet characterization and results of the microstructure evolution during annealing treatment process, the diffusion mechanism of interfacial reaction in TiAl/NiCoCrAl microlaminate was investigated and discussed.

  5. MASS MEASUREMENT OF {sup 45}Cr AND ITS IMPACT ON THE Ca-Sc CYCLE IN X-RAY BURSTS

    SciTech Connect (OSTI)

    Yan, X. L.; Xu, H. S.; Litvinov, Yu. A.; Zhang, Y. H.; Tu, X. L.; Zhou, X. H.; He, J. J.; Sun, Y.; Wang, M.; Yuan, Y. J.; Xia, J. W.; Yang, J. C.; Jia, G. B.; Hu, Z. G.; Ma, X. W.; Mao, R. S.; Schatz, H.; Blaum, K.; Sun, B. H.; Audi, G.; and others

    2013-03-20

    Masses of neutron-deficient {sup 58}Ni projectile fragments have been measured at the HIRFL-CSR facility in Lanzhou, China employing the isochronous mass spectrometry technique. Masses of a series of short-lived T{sub z} = -3/2 nuclides including the {sup 45}Cr nucleus have been measured with a relative uncertainty of about 10{sup -6}-10{sup -7}. The new {sup 45}Cr mass turned out to be essential for modeling the astrophysical rp-process. In particular, we find that the formation of the predicted Ca-Sc cycle in X-ray bursts can be excluded.

  6. Note: Application of CR-39 plastic nuclear track detectors for quality assurance of mixed oxide fuel pellets

    SciTech Connect (OSTI)

    Kodaira, S. Kurano, M.; Hosogane, T.; Ishikawa, F.; Kageyama, T.; Sato, M.; Kayano, M.; Yasuda, N.

    2015-05-15

    A CR-39 plastic nuclear track detector was used for quality assurance of mixed oxide fuel pellets for next-generation nuclear power plants. Plutonium (Pu) spot sizes and concentrations in the pellets are significant parameters for safe use in the plants. We developed an automatic Pu detection system based on dense α-radiation tracks in the CR-39 detectors. This system would greatly improve image processing time and measurement accuracy, and will be a powerful tool for rapid pellet quality assurance screening.

  7. Stress-corrosion cracking and surface-pitting tests of NiCrFe alloy bolts (LWBR development program)

    SciTech Connect (OSTI)

    Keller, K.L.

    1983-02-01

    Accelerated corrosion tests confirmed the adequate resistance to stress corrosion cracking (SCC) of the specific heats of NiCrFe X-750 and NiCrFe 600 used as bolts in the LWBR. SCC acceleration was achieved by running autoclave corrosion tests at 680/sup 0/F (well above the LWBR core operating temperatures of approximately 525/sup 0/F to 560/sup 0/F). Component stress levels were representative of maximum service stresses. No specimens from heats of either alloy suffered SCC.

  8. Letter Report Documenting Progress of Second Generation ATF FeCrAl Alloy Fabrication

    SciTech Connect (OSTI)

    Yamamoto, Y.; Yang, Y.; Field, K. G.; Terrani, K.; Pint, B. A.; Snead, L. L.

    2014-06-10

    Development of the 2nd generation ATF FeCrAl alloy has been initiated, and a candidate alloy was selected for trial tube fabrication through hot-extrusion and gun-drilling processes. Four alloys based on Fe-13Cr-4.5Al-0.15Y in weight percent were newly cast with minor alloying additions of Mo, Si, Nb, and C to promote solid-solution and second-phase precipitate strengthening. The alloy compositions were selected with guidance from computational thermodynamic tools. The lab-scale heats of ~ 600g were arc-melted and drop-cast, homogenized, hot-forged and -rolled, and then annealed producing plate shape samples. An alloy with Mo and Nb additions (C35MN) processed at 800°C exhibits very fine sub-grain structure with the sub-grain size of 1-3μm which exhibited more than 25% better yield and tensile strengths together with decent ductility compared to the other FeCrAl alloys at room temperature. It was found that the Nb addition was key to improving thermal stability of the fine sub-grain structure. Optimally, grains of less than 30 microns are desired, with grains up to and order of magnitude in desired produced through Nb addition. Scale-up effort of the C35MN alloy was made in collaboration with a commercial cast company who has a capability of vacuum induction melting. A 39lb columnar ingot with ~81mm diameter and ~305mm height (with hot-top) was commercially cast, homogenized, hot-extruded, and annealed providing 10mm-diameter bar-shape samples with the fine sub-grain structure. This commercial heat proved consistent with materials produced at ORNL at the lab-scale. Tubes and end caps were machined from the bar sample and provided to another work package for the ATF-1 irradiation campaign in the milestone M3FT-14OR0202251.

  9. Luteolin inhibits Cr(VI)-induced malignant cell transformation of human lung epithelial cells by targeting ROS mediated multiple cell signaling pathways

    SciTech Connect (OSTI)

    Pratheeshkumar, Poyil; Son, Young-Ok; Divya, Sasidharan Padmaja; Roy, Ram Vinod; Hitron, John Andrew; Wang, Lei; Kim, Donghern; Dai, Jin; Asha, Padmaja; Zhang, Zhuo; Wang, Yitao; Shi, Xianglin

    2014-12-01

    Hexavalent chromium [Cr(VI)] is a well-known human carcinogen associated with the incidence of lung cancer. Inhibition of metal induced carcinogenesis by a dietary antioxidant is a novel approach. Luteolin, a natural dietary flavonoid found in fruits and vegetables, possesses potent antioxidant and anti-inflammatory activity. We found that short term exposure of human bronchial epithelial cells (BEAS-2B) to Cr(VI) (5 μM) showed a drastic increase in ROS generation, NADPH oxidase (NOX) activation, lipid peroxidation, and glutathione depletion, which were significantly inhibited by the treatment with luteolin in a dose dependent manner. Treatment with luteolin decreased AP-1, HIF-1α, COX-2, and iNOS promoter activity induced by Cr(VI) in BEAS-2B cells. In addition, luteolin protected BEAS-2B cells from malignant transformation induced by chronic Cr(VI) exposure. Moreover, luteolin also inhibited the production of pro-inflammatory cytokines (IL-1β, IL-6, IL-8, TNF-α) and VEGF in chronic Cr(VI) exposed BEAS-2B cells. Western blot analysis showed that luteolin inhibited multiple gene products linked to survival (Akt, Fak, Bcl-2, Bcl-xL), inflammation (MAPK, NF-κB, COX-2, STAT-3, iNOS, TNF-α) and angiogenesis (HIF-1α, VEGF, MMP-9) in chronic Cr(VI) exposed BEAS-2B cells. Nude mice injected with BEAS-2B cells chronically exposed to Cr(VI) in the presence of luteolin showed reduced tumor incidence compared to Cr(VI) alone treated group. Overexpression of catalase (CAT) or SOD2, eliminated Cr(VI)-induced malignant transformation. Overall, our results indicate that luteolin protects BEAS-2B cells from Cr(VI)-induced carcinogenesis by scavenging ROS and modulating multiple cell signaling mechanisms that are linked to ROS. Luteolin, therefore, serves as a potential chemopreventive agent against Cr(VI)-induced carcinogenesis. - Highlights: • Luteolin inhibited Cr(VI)-induced oxidative stress. • Luteolin inhibited chronic Cr(VI)-induced malignant transformation.

  10. Super-High Temperature Alloys and Composites from NbW-Cr Systems

    SciTech Connect (OSTI)

    Shailendra Varma

    2008-12-31

    Nickel base superalloys must be replaced if the demand for the materials continues to rise for applications beyond 1000{sup o}C which is the upper limit for such alloys at this time. There are non-metallic materials available for such high temperature applications but they all present processing difficulties because of the lack of ductility. Metallic systems can present a chance to find materials with adequate room temperature ductility. Obviously the system must contain elements with high melting points. Nb has been chosen by many investigators which has a potential of being considered as a candidate if alloyed properly. This research is exploring the Nb-W-Cr system for the possible choice of alloys to be used as a high temperature material.

  11. Laser-welded V-Cr-Ti alloys: Microstructure and mechanical properties

    SciTech Connect (OSTI)

    Natesan, K.; Smith, D.L.; Xu, Z.; Leong, K.H.

    1998-09-01

    A systematic study has been in progress at Argonne National Laboratory to examine the use of YaG or CO{sub 2} lasers to weld sheet materials of V-Cr-Ti alloys and to characterize the microstructural and mechanical properties of the laser-welded materials. In addition, several postwelding heat treatments are being applied to the welded samples to evaluate their benefits, if any, to the structure and properties of the weldments. Hardness measurements are made across the welded regions of different samples to evaluate differences in the characteristics of various weldments. Several weldments were used to fabricate specimens for four-point bend tests. Several additional weldments were made with a YaG laser; here, the emphasis was on determining the optimal weld parameters to achieve deep penetration in the welds. A preliminary assessment was then made of the weldments on the basis of microstructure, hardness profiles, and defects.

  12. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R.; Garner, Francis A.

    1987-01-01

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  13. Effect of oxygen and oxidation on tensile properties of V-5Cr-5Ti alloy

    SciTech Connect (OSTI)

    Natesan, K.; Soppet, W.K.

    1995-09-01

    Oxidation studies were conducted on V-5Cr-5Ti alloy specimens in an air environment to evaluate the oxygen uptake behavior of the alloy as a function of temperature and exposure time. The oxidation rates calculated from parabolic kinetic measurements of thermogravimetric testing and confirmed by microscopic analyses of cross sections of exposed specimens were 5, 17, and 27 {mu}m per year after exposure at 300, 400, and 500{degrees}C, respectively. Uniaxial-tensile tests were conducted at room temperature and at 500C on preoxidized specimens of the alloy to examine the effects of oxidation and oxygen migration on tensile strength and ductility. Microstructural characteristics of several of the tested specimens were determined by electron optics techniques. Correlations were developed between tensile strength and ductility of the oxidized alloy and microstructural characteristics such as oxide thickness, depth of hardened layer, depth of intergranular fracture zone, and transverse crack length.

  14. Ion polished Cr/Sc attosecond multilayer mirrors for high water window reflectivity

    SciTech Connect (OSTI)

    Guggenmos, Alexander; Radünz, Stefan; Rauhut, Roman; Hofstetter, Michael; Venkatesan, Sriram; Wochnik, Angela; Gullikson, Eric M.; Fischer, Stefan; Nickel, Bert; Scheu, Christina; Kleineberg, Ulf

    2014-01-20

    Recent advances in the development of attosecond soft X-ray sources ranging into the water window spectral range, between the 1s states of carbon and oxygen (284 eV–543 eV), are also driving the development of suited broadband multilayer optics for steering and shaping attosecond pulses. The relatively low intensity of current High Harmonic Generation (HHG) soft X-ray sources calls for an efficient use of photons, thus the development of low-loss multilayer optics is of uttermost importance. Here, we report about the realization of broadband Cr/Sc attosecond multilayer mirrors with nearly atomically smooth interfaces by an optimized ion beam deposition and assisted interface polishing process. This yields to our knowledge highest multilayer mirror reflectivity at 300 eV near normal incidence. The results are verified by transmission electron microscopy (TEM) and soft/hard X-ray reflectometry.

  15. 2011 Honda CR-Z 4466 - Hybrid Electric Vehicle Battery Test Results

    SciTech Connect (OSTI)

    Tyler Gray; Matthew Shirk; Jeffrey Wishart

    2014-09-01

    The U.S. Department of Energy’s Advanced Vehicle Testing Activity Program consists of vehicle, battery, and infrastructure testing on advanced technology related to transportation. The activity includes tests on hybrid electric vehicles, including testing traction batteries when both the vehicles and batteries are new and at the conclusion of 160,000 miles of on-road fleet testing. This report documents battery testing performed for the 2011 Honda CR-Z (VIN JHMZF1C67BS004466). Battery testing was performed by Intertek Testing Services NA. The Idaho National Laboratory and Intertek collaborate on the Advanced Vehicle Testing Activity for the Vehicle Technologies Office of the U.S. Department of Energy.

  16. 2011 HONDA CR-Z 2982 - HYBRID ELECTRIC VEHICLE BATTERY TEST RESULTS

    SciTech Connect (OSTI)

    Gray, Tyler; Shirk, Matthew; Wishart, Jeffrey

    2014-09-01

    The U.S. Department of Energy’s Advanced Vehicle Testing Activity Program consists of vehicle, battery, and infrastructure testing on advanced technology related to transportation. The activity includes tests on hybrid electric vehicles, including testing traction batteries when both the vehicles and batteries are new and at the conclusion of 160,000 miles of on-road fleet testing. This report documents battery testing performed for the 2011 Honda CR-Z (VIN JHMZF1C64BS002982). Battery testing was performed by Intertek Testing Services NA. The Idaho National Laboratory and Intertek collaborate on the Advanced Vehicle Testing Activity for the Vehicle Technologies Office of the U.S. Department of Energy.

  17. High-temperature fatigue behavior of unirradiated V-15Cr-5Ti tested in vacuum

    SciTech Connect (OSTI)

    Liu, K.C.

    1981-01-01

    Limited results of in-vacuum fatigue tests are presented for unirradiated V-15Cr-5Ti tested at room temperature, 550, and 650/sup 0/C, respectively. The test data were analyzed using a power law equation to correlate the total strain range and cycles to failure. Comparison with data for 20% cold-worked Type 316 stainless steel tested at 550/sup 0/C shows that on the basis of strain range the vanadium alloy is about the same as the stainless steel below 10,000 cycles to failure but becomes superior above the point. The general data trend further suggests that endurance limits may exist at strain ranges of approximately 0.7 and 0.6% at 550 and 650/sup 0/C, respectively.

  18. Photo-transport properties of Pb{sub 2}CrO{sub 5} single crystals

    SciTech Connect (OSTI)

    Mondal, P. S.; Okazaki, R. Taniguchi, H.; Terasaki, I.

    2014-11-21

    We report photo-thermoelectric transport phenomena in Pb{sub 2}CrO{sub 5} single crystals. Without illumination, this material exhibits an insulating behavior characterized by an activation-type temperature variation of the electrical conductivity. The Seebeck coefficient contrastingly shows a crossover from high-temperature insulating to low-temperature metallic behavior, which is attributed to degenerate carriers in a donor level. We have found that under illumination, both the conductivity and the Seebeck coefficient increase in magnitude with increasing photon flux density in the degenerate-conduction regime. This result is difficult to understand within a simple photo-doping effect, which usually leads to a decrease in the Seebeck coefficient under illumination. The observed phenomenon is discussed in terms of a two-carrier contribution to the transport properties.

  19. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke; Zhang, F; Miller, Michael K; Liu, Chain T; Huang, Shenyan; Chou, Y.T.; Tien, R; Chang, Y A; Liaw, Peter K

    2012-01-01

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  20. Heat treated 9 Cr-1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-08-21

    The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

  1. Structure of Oxide Nanoparticles in Fe-16Cr MA/ODS Ferritic Steel

    SciTech Connect (OSTI)

    Hsiung, L; Fluss, M; Kimura, A

    2010-04-06

    Oxide nanoparticles in Fe-16Cr ODS ferritic steel fabricated by mechanical alloying (MA) method have been examined using high-resolution transmission electron microscopy (HRTEM) techniques. A partial crystallization of oxide nanoparticles was frequently observed in as-fabricated ODS steel. The crystal structure of crystalline oxide particles is identified to be mainly Y{sub 4}Al{sub 2}O{sub 9} (YAM) with a monoclinic structure. Large nanoparticles with a diameter larger than 20 nm tend to be incoherent and have a nearly spherical shape, whereas small nanoparticles with a diameter smaller than 10 nm tend to be coherent or semi-coherent and have faceted boundaries. The oxide nanoparticles become fully crystallized after prolonged annealing at 900 C. These results lead us to propose a three-stage formation mechanism of oxide nanoparticles in MA/ODS steels.

  2. Thermo-mechanical processing (TMP) of Ti-48Al-2Nb-2Cr based alloys

    SciTech Connect (OSTI)

    Fuchs, G.E.

    1995-02-01

    The effects of heat treatment and deformation processing on the microstructures and properties of {gamma}-TiAl based alloys produced by ingot metallurgy (I/M) and powder metallurgy (P/M) techniques were examined. The alloy selected for this work is the second generation {gamma}-TiAl based alloy -- Ti-48Al-2Nb-2Cr (at %). Homogenization of I/M samples was performed at a variety of temperatures, followed by hot working by isothermal forging. P/M samples were prepared from gas atomized powders, consolidated by both HIP and extrusion and some of the HIPed material was then hot worked by isothermal forging. The effects of processing, heat treatment and hot working on the microstructures and properties will be discussed.

  3. The Russian-American Gallium Experiment (SAGE) Cr Neutrino Source Measurement

    SciTech Connect (OSTI)

    Abdurashitov, J.; Gavrin, V.; Girin, S.; Gorbachev, V.; Ibragimova, T.; Kalikhov, A.; Khairnasov, N.; Knodel, T.; Kornoukhov, V.; Mirmov, I.; Shikhin, A.; Veretenkin, E.; Vermul, V.; Yants, V.; Zatsepin, G.; Bowles, T.; Nico, J.; Teasdale, W.; Wark, D.; Cherry, M.; Karaulov, V.; Levitin, V.; Maev, V.; Nazarenko, P.; Shkolnik, V.; Skorikov, N.; Cleveland, B.; Daily, T.; Davis, R. Jr.; Lande, K.; Lee, C.; Wildenhain, P.; Khomyakov, Y.; Zvonarev, A.; Elliott, S.; Wilkerson, J.

    1996-12-01

    The solar neutrino capture rate measured by SAGE is well below that predicted by solar models. To check the overall experimental efficiency, we exposed 13tonnes of Ga metal to a reactor-produced 517kCi source of {sup 51}Cr. The ratio of the measured production rate to that predicted from the source activity is 0.95{plus_minus}0.11(stat)+0.05/{minus}0.08(syst). This agreement verifies that the experimental efficiency is measured correctly, establishes that there are no unknown systematic errors at the 10{percent} level, and provides considerable evidence for the reliability of the solar neutrino measurement. {copyright} {ital 1996 The American Physical Society.}

  4. Defects in Ga, Cr, and In-doped CoO

    SciTech Connect (OSTI)

    Chen, S.P.; Yan, M.; Grimes, R.W.; Vyas, S.

    1995-07-01

    From simulation, trivalent cations, Ga(3+), Cr(3+), Co(3+) and In(3+), bind with Co vacancy to form singly pairs with binding energies of about 0.7 to 0.8 eV. These binding energies are in reasonable agreement with experimental measurement of about 0.5 eV. In ion prefers the second nearest neighbor position from a Co vacancy, while other cations prefer the third nearest neighbor sites. Two cations can also forma triplet with a Co vacancy with binding energies of about 1.2 to 1.5 eV. These valves are in fair agreement with the 0.8 to 1.1 eV measured from the tracer diffusion experiments.

  5. Ion polished Cr/Sc attosecond multilayer mirrors for high water window reflectivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guggenmos, Alexander; Radünz, Stefan; Rauhut, Roman; Hofstetter, Michael; Venkatesan, Sriram; Wochnik, Angela; Gullikson, Eric M.; Fischer, Stefan; Nickel, Bert; Scheu, Christina; et al

    2014-01-20

    Recent advances in the development of attosecond soft X-ray sources ranging into the water window spectral range, between the 1s states of carbon and oxygen (284 eV–543 eV), are also driving the development of suited broadband multilayer optics for steering and shaping attosecond pulses. The relatively low intensity of current High Harmonic Generation (HHG) soft X-ray sources calls for an efficient use of photons, thus the development of low-loss multilayer optics is of uttermost importance. Here, we report about the realization of broadband Cr/Sc attosecond multilayer mirrors with nearly atomically smooth interfaces by an optimized ion beam deposition and assistedmore » interface polishing process. This yields to our knowledge highest multilayer mirror reflectivity at 300 eV near normal incidence. The results are verified by transmission electron microscopy (TEM) and soft/hard X-ray reflectometry.« less

  6. Thermomechanical treatment for improved neutron irradiation resistance of austenitic alloy (Fe-21Cr-32Ni)

    SciTech Connect (OSTI)

    L. Tan; J. T. Busby; H. J. M. Chichester; K. Sridharan; T. R. Allen

    2013-06-01

    An optimized thermomechanical treatment (TMT) applied to austenitic alloy 800H (Fe-21Cr-32Ni) had shown significant improvements in corrosion resistance and basic mechanical properties. This study examined its effect on radiation resistance by irradiating both the solution-annealed (SA) and TMT samples at 500 degrees C for 3 dpa. Microstructural characterization using transmission electron microscopy revealed that the radiation-induced Frank loops, voids, and y'-Ni3(Ti,Al) precipitates had similar sizes between the SA and TMT samples. The amounts of radiation-induced defects and more significantly y' precipitates, however, were reduced in the TMT samples. These reductions would approximately reduce by 40.9% the radiation hardening compared to the SA samples. This study indicates that optimized-TMT is an economical approach for effective overall property improvements.

  7. Properties and features of structure formation CuCr-contact alloys in electron beam cladding

    SciTech Connect (OSTI)

    Durakov, Vasiliy G.; Dampilon, Bair V. E-mail: gnusov@rambler.ru; Gnyusov, Sergey F. E-mail: gnusov@rambler.ru

    2014-11-14

    The microstructure and properties of the contact CuCr alloy produced by electron-beam cladding have been investigated. The effect of the electron beam cladding parameters and preheating temperature of the base metal on the structure and the properties of the coatings has been determined. The bimodal structure of the cladding coating has been established. The short circuit currents tests have been carried out according to the Weil-Dobke synthetic circuit simulating procedure developed for vacuum circuit breakers (VCB) test in real electric circuits. Test results have shown that the electron beam cladding (EBC) contact material has better breaking capacity than that of commercially fabricated sintered contact material. The application of the technology of electron beam cladding for production of contact material would significantly improve specific characteristics and reliability of vacuum switching equipment.

  8. Bose-Einstein condensation of triplons in Ba3Cr2O8

    SciTech Connect (OSTI)

    Jaime, Marcelo [Los Alamos National Laboratory; Kohama, Y [Los Alamos National Laboratory; Aczel, A [MCMASTER UNIV; Ninios, K [UNIV OF FL; Chan, H [UNIV OF FL; Balicas, L [NHMFL; Dabkowska, H [MCMASTER UNIV; Like, G [MCMASTER UNIV

    2009-01-01

    By performing heat capacity, magnetocaloric effect, torque magnetometry and force magnetometry measurements up to 33 T, we have mapped out the T-H phase diagram of the S = 1/2 spin dimer compound Ba{sub 3}Cr{sub 2}O{sub 8}. We found evidence for field-induced magnetic order between H{sub cl} = 12.52(2) T and H{sub c2} = 23.65(5) T, with the maximum transition temperature T{sub c} {approx} 2.7 K at H {approx} 18 T. The lower transition can likely be described by Bose-Einstein condensation of triplons theory, and this is consistent with the absence of any magnetization plateaus in our magnetic torque and force measurements. In contrast, the nature of the upper phase transition appears to be quite different as our measurements suggest that this transition is actually first order.

  9. Feasibility of correlating V-Cr-Ti alloy weld strength with weld chemistry. CRADA final report

    SciTech Connect (OSTI)

    Grossbeck, M.L.; Odom, R.W.

    1998-06-01

    The mechanical properties of refractory metals such as vanadium are determined to a large extent by the interstitial impurities in the alloy. In the case of welding, interstitial impurities are introduced in the welding process from the atmosphere and by dissolution of existing precipitates in the alloy itself. Because of the necessity of having an ultra-pure atmosphere, a vacuum chamber or a glove box is necessary. In the V-Cr-Ti system, the titanium serves as a getter to control the concentration of oxygen and nitrogen in solid solution in the alloy. In this project the secondary ion mass spectrometry (SIMS) technique was used to detect, measure, and map the spacial distribution of impurity elements in welds in the alloy V-4Cr-4Ti. An attempt was then made to correlate the concentrations and distributions of the impurities with mechanical properties of the welds. Mechanical integrity of the welds was determined by Charpy V-notch testing. Welds were prepared by the gas-tungsten-arc (GTA) method. Charpy testing established a correlation between weld impurity concentration and the ductile to brittle transition temperature (DBTT). Higher concentrations of oxygen resulted in a higher DBTT. An exception was noted in the case of a low-oxygen weld which had a high hydrogen concentration resulting in a brittle weld. The concentrations and distributions of the impurities determined by SIMS could not be correlated with the mechanical properties of the welds. This research supports efforts to develop fusion reactor first wall and blanket structural materials.

  10. Microstructural characterization of as-cast biocompatible Co-Cr-Mo alloys

    SciTech Connect (OSTI)

    Giacchi, J.V.; Morando, C.N.; Fornaro, O.; Palacio, H.A.

    2011-01-15

    The microstructure of a cobalt-base alloy (Co-Cr-Mo) obtained by the investment casting process was studied. This alloy complies with the ASTM F75 standard and is widely used in the manufacturing of orthopedic implants because of its high strength, good corrosion resistance and excellent biocompatibility properties. This work focuses on the resulting microstructures arising from samples poured under industrial environment conditions, of three different Co-Cr-Mo alloys. For this purpose, we used: 1) an alloy built up from commercial purity constituents, 2) a remelted alloy and 3) a certified alloy for comparison. The characterization of the samples was achieved by using optical microscopy (OM) with a colorant etchant to identify the present phases and scanning electron microscopy (SE-SEM) and energy dispersion spectrometry (EDS) techniques for a better identification. In general the as-cast microstructure is a Co-fcc dendritic matrix with the presence of a secondary phase, such as the M{sub 23}C{sub 6} carbides precipitated at grain boundaries and interdendritic zones. These precipitates are the main strengthening mechanism in this type of alloys. Other minority phases were also reported and their presence could be linked to the cooling rate and the manufacturing process variables and environment. - Research Highlights: {yields}The solidification microstructure of an ASTM-F75 type alloy were studied. {yields}The alloys were poured under an industrial environment. {yields}Carbides and sigma phase identified by color metallography and scanning microscopy (SEM and EDS). {yields}Two carbide morphologies were detected 'blocky type' and 'pearlite type'. {yields}Minority phases were also detected.

  11. Optimizing and Diversifying the Electric Range of Plug-in Hybrid Electric Vehicles for U.S. Drivers

    SciTech Connect (OSTI)

    Lin, Zhenhong

    2012-01-01

    To provide useful information for automakers to design successful plug-in hybrid electric vehicle (PHEV) products and for energy and environmental analysts to understand the social impact of PHEVs, this paper addresses the question of how many of the U.S. consumers, if buying a PHEV, would prefer what electric ranges. The Market-oriented Optimal Range for PHEV (MOR-PHEV) model is developed to optimize the PHEV electric range for each of 36,664 sampled individuals representing U.S. new vehicle drivers. The optimization objective is the minimization of the sum of costs on battery, gasoline, electricity and refueling hassle. Assuming no battery subsidy, the empirical results suggest that: 1) the optimal PHEV electric range approximates two thirds of one s typical daily driving distance in the near term, defined as $450/kWh battery delivered price and $4/gallon gasoline price. 2) PHEVs are not ready to directly compete with HEVs at today s situation, defined by the $600/kWh battery delivered price and the $3-$4/gallon gasoline price, but can do so in the near term. 3) PHEV10s will be favored by the market over longer-range PHEVs in the near term, but longer-range PHEVs can dominate the PHEV market if gasoline prices reach as high as $5-$6 per gallon and/or battery delivered prices reach as low as $150-$300/kWh. 4) PHEVs can become much more attractive against HEVs in the near term if the electric range can be extended by only 10% with multiple charges per day, possible with improved charging infrastructure or adapted charging behavior. 5) the impact of a $100/kWh decrease in battery delivered prices on the competiveness of PHEVs against HEVs can be offset by about $1.25/gallon decrease in gasoline prices, or about 7/kWh increase in electricity prices. This also means that the impact of a $1/gallon decrease in gasoline prices can be offset by about 5/kWh decrease in electricity prices.

  12. The high current, fast, 100ns, Linear Transformer Driver (LTD) developmental project at Sandia Laboratories and HCEI.

    SciTech Connect (OSTI)

    Ward, Kevin S.; Long, Finis W.; Sinebryukhov, Vadim A. , Tomsk, Russia); Kim, Alexandre A. , Tomsk, Russia); Wakeland, Peter Eric; McKee, G. Randall; Woodworth, Joseph Ray; McDaniel, Dillon Heirman; Fowler, William E.; Mazarakis, Michael Gerrassimos; Porter, John Larry, Jr.; Struve, Kenneth William; Savage, Mark Edward; Stygar, William A.; LeChien, Keith R.; Matzen, Maurice Keith

    2010-09-01

    Sandia National Laboratories, Albuquerque, N.M., USA, in collaboration with the High Current Electronic Institute (HCEI), Tomsk, Russia, is developing a new paradigm in pulsed power technology: the Linear Transformer Driver (LTD) technology. This technological approach can provide very compact devices that can deliver very fast high current and high voltage pulses straight out of the cavity with out any complicated pulse forming and pulse compression network. Through multistage inductively insulated voltage adders, the output pulse, increased in voltage amplitude, can be applied directly to the load. The load may be a vacuum electron diode, a z-pinch wire array, a gas puff, a liner, an isentropic compression load (ICE) to study material behavior under very high magnetic fields, or a fusion energy (IFE) target. This is because the output pulse rise time and width can be easily tailored to the specific application needs. In this paper we briefly summarize the developmental work done in Sandia and HCEI during the last few years, and describe our new MYKONOS Sandia High Current LTD Laboratory. An extensive evaluation of the LTD technology is being performed at SNL and the High Current Electronic Institute (HCEI) in Tomsk Russia. Two types of High Current LTD cavities (LTD I-II, and 1-MA LTD) were constructed and tested individually and in a voltage adder configuration (1-MA cavity only). All cavities performed remarkably well and the experimental results are in full agreement with analytical and numerical calculation predictions. A two-cavity voltage adder is been assembled and currently undergoes evaluation. This is the first step towards the completion of the 10-cavity, 1-TW module. This MYKONOS voltage adder will be the first ever IVA built with a transmission line insulated with deionized water. The LTD II cavity renamed LTD III will serve as a test bed for evaluating a number of different types of switches, resistors, alternative capacitor configurations, cores

  13. HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3...

    Office of Scientific and Technical Information (OSTI)

    ...6Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel Citation Details In-Document Search Title: HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel You are accessing a ...

  14. Investigations of the optical and EPR properties of LiGa{sub 5}O{sub 8}:Cr{sup 3+} phosphor

    SciTech Connect (OSTI)

    Singh, Vijay; Ravikumar, R.V.S.S.N.; Sivaramaiah, G.; Rao, J.L.; Kim, S.H.

    2015-01-15

    Highlights: • Cr{sup 3+} doped LiGa{sub 5}O{sub 8} phosphor was synthesized by solution combustion synthesis. • Morphological studies show the non-uniform distribution of particles. • Photoluminescence spectra of Cr{sup 3+} doped LiGa{sub 5}O{sub 8} showed the characteristic Cr{sup 3+} peaks. • EPR spectrum showed Cr{sup 3+} ions in tetragonally distorted octahedral symmetry. - Abstract: Red emitting LiGa{sub 5}O{sub 8} doped with Cr{sup 3+} ions has been prepared by a low temperature solution combustion route. The as-prepared phosphor was studied using X-ray diffraction and scanning electron microscopic techniques. The optical spectrum exhibits two broad bands characteristic of Cr{sup 3+} ions in an octahedral symmetry. Upon excitation at 590 nm, the material displays narrow red emission line centered at 715 nm due to the {sup 2}E{sub g} → {sup 4}A{sub 2g} transition of Cr{sup 3+} ions. Electron paramagnetic resonance analyses of the sample confirm the presence of Cr{sup 3+} in the LiGa{sub 5}O{sub 8} matrix.

  15. HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3...

    Office of Scientific and Technical Information (OSTI)

    HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ODS Steel Citation Details In-Document Search Title: HRTEM Study of Oxide Nanoparticles in 16Cr-4Al-2W-0.3Ti-0.3Y2O3 ...

  16. Modulation of physical and photocatalytic properties of (Cr, N) codoped TiO{sub 2} nanorods using soft solution processing

    SciTech Connect (OSTI)

    Lu, Wen-Chung; Nguyen, Hoang-Diem; Wu, Chun-Yi; Chang, Kao-Shuo Yoshimura, Masahiro

    2014-04-14

    Facile polymerized complex reactions together with a hydrothermal reaction were implemented to make single crystalline TiO{sub 2} nanorods for the first time. Chromium (Cr) and nitrogen (N{sub 2}) co-doping was performed to tailor the physical properties. Transmission electron microscopy and x-ray diffraction study illustrated that highly reactive facets of (101), (111), and (001) dominated rutile TiO{sub 2} nanorods. A growth model, based on formation of complex species, was proposed to elucidate effectiveness of the soft solution processing in making TiO{sub 2} nanorods. X-ray photoelectron spectroscopy analysis and consideration of fundamentals of charge neutrality showed N{sub 2} doping could inhibit formation of Cr{sup 6+} and oxygen vacancies (V{sub O}{sup 2+}). An investigation of the photocatalytic properties exhibited high efficiency of photodegradation of methylene blue in 15 min under pH = 10, using a nanocomposite of (7% Cr, 0.0021% N) codoped and 3% Cr doped TiO{sub 2} nanorods.

  17. Measuring the activity of a {sup 51}Cr neutrino source based on the gamma-radiation spectrum

    SciTech Connect (OSTI)

    Gorbachev, V. V. Gavrin, V. N.; Ibragimova, T. V.; Kalikhov, A. V.; Malyshkin, Yu. M.; Shikhin, A. A.

    2015-12-15

    A technique for the measurement of activities of intense β sources by measuring the continuous gamma-radiation (internal bremsstrahlung) spectra is developed. A method for reconstructing the spectrum recorded by a germanium semiconductor detector is described. A method for the absolute measurement of the internal bremsstrahlung spectrum of {sup 51}Cr is presented.

  18. Magnetic behavior in Cr{sub 2}@Ge{sub n} (1?n?12) clusters: A density functional investigation

    SciTech Connect (OSTI)

    Dhaka, Kapil Trivedi, Ravi Bandyopadhyay, Debashis

    2014-04-24

    With a goal to produce magnetic moment in Cr{sub 2} Doped Ge{sub n} clusters which will be useful for practical applications, we have considered the structure and magnetic properties of Pure Germanium clusters and substitutionally doped it with Cr dimer to produce Cr{sub 2}@Ge{sub n} clusters. As the first step of calculation, geometrical optimizations of the nanoclusters have been done. These optimized geometries have been used in calculate the average binding energy per atom (BE), HOMO-LUMO gap and hence the relative stability of the clusters. These parameters have been demonstrated as structural and electronic properties of the clusters. Gap between highest occupied molecular orbital and lowest unoccupied molecular orbital indicate cluster to be a potential motif for generating magnetic cluster assembled materials. Based on these values a comparative study on different sized clusters has been done in order to understand the origin of structures, electronic and magnetic properties of Cr{sub 2}@Ge{sub n} nanoclusters.

  19. Re-Evaluation of Results in NUREG/CR-6674 for Carbon and Low-Alloy Steel Components (MRP-76)

    SciTech Connect (OSTI)

    A. Deardorff; D. Harris; D. Dedhia

    2002-11-30

    This report evaluates the conservatisms and uncertainties reported in NUREG/CR-6674 that lead to high probabilities of cracking in carbon and low-alloy steel for reactor piping. The report uses additional data generated since the completion of the report to eliminate uncertainties and show lower probabilities of cracking.

  20. Giant magnetocaloric effect and temperature induced magnetization jump in GdCrO{sub 3} single crystal

    SciTech Connect (OSTI)

    Yin, L. H.; Yang, J.; Kan, X. C.; Song, W. H.; Dai, J. M.; Sun, Y. P.

    2015-04-07

    We report on a systematic study of the single-crystal GdCrO{sub 3}, which shows various novel magnetic features, such as temperature-induced magnetization reversal (TMR), temperature-induced magnetization jump (TMJ), spin reorientation, and giant magnetocaloric effect (MCE). In the field-cooled cooling process with modest magnetic field along the c axis, GdCrO{sub 3} first shows a TMR at T{sub comp}∼120−130 K and then an abrupt TMJ with a sign change of magnetization at T{sub jump}∼52−120 K, and finally a spin reorientation at T{sub SR}∼4−7 K. Interestingly, the remarkable TMJ behavior, which was not reported ever before, persists at higher fields up to 10 kOe even when TMR disappears. In addition, giant MCE with the maximum value of magnetic entropy change reaching ∼31.6 J/kg K for a field change of 44 kOe was also observed in GdCrO{sub 3} single crystal, suggesting it could be a potential material for low-T magnetic refrigeration. A possible mechanism for these peculiar magnetic behaviors is discussed based on the various competing magnetic interactions between the 3d electrons of Cr{sup 3+} ions and 4f electrons of Gd{sup 3+} ions.