National Library of Energy BETA

Sample records for drive electrochemical processes

  1. Electro-Chemical Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electro-Chemical Processes - Sandia Energy Energy Search Icon Sandia Home Locations ... ARPA-E Basic Energy Sciences Materials Sciences and Engineering Chemical Sciences ...

  2. Electro-Chemical Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electro-Chemical Processes - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  3. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  4. Electrochemical device and process of making

    DOE Patents [OSTI]

    Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2004-07-27

    A process of making an electrochemical device comprising providing a trilayer structure comprising an electrode/electrolyte/electrode and simultaneously sintering the trilayer structure.

  5. Quantification of Electrochemical Nanoscale Processes in Lithium...

    Office of Scientific and Technical Information (OSTI)

    in Lithium Batteries By OperandoEC-(S)TEM Citation Details In-Document Search Title: Quantification of Electrochemical Nanoscale Processes in Lithium Batteries By ...

  6. Process for electrochemically gasifying coal using electromagnetism

    DOE Patents [OSTI]

    Botts, Thomas E.; Powell, James R.

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  7. US DRIVE Electrochemical Energy Storage Technical Team Roadmap | Department

    Energy Savers [EERE]

    Sustainability Partnership Plan | Department of Energy Driving Research and Innovation for Vehicle Efficiency and Energy Sustainability Partnership Plan US DRIVE Driving Research and Innovation for Vehicle Efficiency and Energy Sustainability Partnership Plan This document describes the vision, mission, scope, and governing policies of the U.S. DRIVE Partnership ("Partnership"). Dated December 2014. PDF icon U.S. DRIVE Partnership Plan - December 2014 with Addendum.pdf More

  8. Electrochemical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    K. M. Goff; J. C. Wass; G. M. Teske

    2011-08-01

    As part of the Department of Energy’s Fuel Cycle Research and Development Program an electrochemical technology employing molten salts is being developed for recycle of metallic fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. This technology has been deployed for treatment of used fuel from the Experimental Breeder Reactor II (EBR-II) in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory. This process is based on dry (non-aqueous) technologies that have been developed and demonstrated since the 1960s. These technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including preparation of associated high-level waste forms.

  9. Electrochemical processes in recovering metals from ores

    SciTech Connect (OSTI)

    Felker, D.L. ); Bautista, R.G. . Dept. of Chemical and Metallurgical Engineering)

    1990-04-01

    Chalcopyrite (CuFeS{sub 2}) is one of the most abundant copper-bearing minerals in the U.S. Oxidative leaching and smelting and refining are the most common methods used for recovering copper from chalcopyrite. One of the problems associated with oxidative leaching is the formation of an elemental sulfur product layer around the unreacted chalcopyrite core. The sulfur coating slows the reaction by inhibiting both the diffusion of the oxidant to the unreacted core, and the diffusion of the copper and iron species to the bulk solution. Another problem with leaching is that the iron and copper are oxidized simultaneously. Both appear in the bulk solution in their most oxidized states. The direct electrodissolution of copper sulfide ore slurries could reduce the number of steps involved in the copper recovery process, possibly leading to significant reductions in energy consumption and operating costs. The potential application of electrodissolution processes in hydrometallurgy has been reviewed. This paper reviews investigations of the electrochemical dissolution of chalcopyrite, digenite (Cu{sub 1.8}S), chalcocite (Cu{sub 2}S) and covellite (CuS).

  10. Predicting the voltage dependence of interfacial electrochemical processes

    Office of Scientific and Technical Information (OSTI)

    at lithium-intercalated graphite edge planes (Journal Article) | SciTech Connect Predicting the voltage dependence of interfacial electrochemical processes at lithium-intercalated graphite edge planes Citation Details In-Document Search Title: Predicting the voltage dependence of interfacial electrochemical processes at lithium-intercalated graphite edge planes Authors: Leung, Kevin Publication Date: 2014-01-01 OSTI Identifier: 1210241 DOE Contract Number: SC0001160 Resource Type: Journal

  11. Quantification of Electrochemical Nanoscale Processes in Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    By OperandoEC-(S)TEM (Conference) | SciTech Connect Conference: Quantification of Electrochemical Nanoscale Processes in Lithium Batteries By OperandoEC-(S)TEM Citation Details In-Document Search Title: Quantification of Electrochemical Nanoscale Processes in Lithium Batteries By OperandoEC-(S)TEM Lithium (Li)-ion batteries are currently used for a wide variety of portable electronic devices, electric vehicles and renewable energy applications. In addition, extensive worldwide research

  12. Microfluidic electrochemical device and process for chemical imaging and electrochemical analysis at the electrode-liquid interface in-situ

    DOE Patents [OSTI]

    Yu, Xiao-Ying; Liu, Bingwen; Yang, Li; Zhu, Zihua; Marshall, Matthew J.

    2016-03-01

    A microfluidic electrochemical device and process are detailed that provide chemical imaging and electrochemical analysis under vacuum at the surface of the electrode-sample or electrode-liquid interface in-situ. The electrochemical device allows investigation of various surface layers including diffuse layers at selected depths populated with, e.g., adsorbed molecules in which chemical transformation in electrolyte solutions occurs.

  13. Solid oxide electrochemical cell fabrication process

    DOE Patents [OSTI]

    Dollard, Walter J.; Folser, George R.; Pal, Uday B.; Singhal, Subhash C.

    1992-01-01

    A method to form an electrochemical cell (12) is characterized by the steps of thermal spraying stabilized zirconia over a doped lanthanum manganite air electrode tube (14) to provide an electrolyte layer (15), coating conductive particles over the electrolyte, pressurizing the outside of the electrolyte layer, feeding halide vapors of yttrium and zirconium to the outside of the electrolyte layer and feeding a source of oxygen to the inside of the electrolyte layer, heating to cause oxygen reaction with the halide vapors to close electrolyte pores if there are any and to form a metal oxide coating on and between the particles and provide a fuel electrode (16).

  14. Electrochemical process and production of novel complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2013-06-25

    A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

  15. Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication

    SciTech Connect (OSTI)

    Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

    2015-07-01

    This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

  16. Development of the chemical and electrochemical coal cleaning (CECC) process

    SciTech Connect (OSTI)

    Yoon, Roe-Hoan; Basilio, C.I.

    1992-05-01

    The Chemical and Electrochemical Coal Cleaning (CECC) process developed at Virginia Polytechnic Institute and State University was studied further in this project. This process offers a new method of physically cleaning both low- and high-rank coals without requiring fine grinding. The CECC process is based on liberating mineral matter from coal by osmotic pressure. The majority of the work was conducted on Middle Wyodak, Pittsburgh No. 8 and Elkhorn No. 3 coals. The coal samples were characterized for a variety of physical and chemical properties. Parametric studies were then conducted to identify the important operating parameters and to establish the optimum conditions. In addition, fundamental mechanisms of the process were studied, including mineral matter liberation, kinetics of mineral matter and pyrite dissolution, ferric ion regeneration schemes and alternative methods of separating the cleaned coal from the liberated mineral matter. The information gathered from the parametric and fundamental studies was used in the design, construction and testing of a bench-scale continuous CECC unit. Using this unit, the ash content of a Middle Wyodak coal was reduced from 6.96 to 1.61% at a 2 lbs/hr throughput. With an Elkhorn No. 3 sample, the ash content was reduced from 9.43 to 1.8%, while the sulfur content was reduced from 1.57 to 0.9%. The mass balance and liberation studies showed that liberation played a more dominant role than the chemical dissolution in removing mineral matter and inorganic sulfur from the different bituminous coals tested. However, the opposite was found to be the case for the Wyodak coal since this coal contained a significant amount of acid-soluble minerals.

  17. Nanoparticle shape evolution and proximity effects during tip-induced electrochemical processes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Sangmo; Paranthaman, Mariappan Parans; Noh, Tae Won; Kalinin, Sergei V.; Strelcov, Evgheni

    2016-01-08

    The voltage spectroscopies in scanning probe microscopy (SPM) techniques are widely used to investigate the electrochemical processes in nanoscale volumes, which are important for current key applications, such as batteries, fuel cells, catalysts, and memristors. The spectroscopic measurements are commonly performed on a grid of multiple points to yield spatially resolved maps of reversible and irreversible electrochemical functionalities. Hence, the spacing between measurement points is an important parameter to be considered, especially for irreversible electrochemical processes. Here, we report nonlocal electrochemical dynamics in chains of Ag particles fabricated by the SPM tip on a silver ion solid electrolyte. When themore » grid spacing is small compared with the size of the formed Ag particles, anomalous chains of unequally sized particles with double periodicity evolve. This behavior is ascribed to a proximity effect during the tip-induced electrochemical process, specifically, size-dependent silver particle growth following the contact between the particles. In addition, fractal shape evolution of the formed Ag structures indicates that the growth-limiting process changes from Ag+/Ag redox reaction to Ag+-ion diffusion with the increase in the applied voltage and pulse duration. Our study shows that characteristic shapes of the electrochemical products are good indicators for determining the underlying growth-limiting process, and emergence of complex phenomena during spectroscopic mapping of electrochemical functionalities.« less

  18. Static Sankey Diagram of Process Energy in U.S. Manufacturing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process applications (such as process heating, process cooling & refrigeration, machine drive, electro-chemical, and other processes) use this energy to convert raw materials into ...

  19. Glass composition and process for sealing void spaces in electrochemical devices

    DOE Patents [OSTI]

    Meinhardt, Kerry D.; Kirby, Brent W.

    2012-05-01

    A glass foaming material and method are disclosed for filling void spaces in electrochemical devices. The glass material includes a reagent that foams at a temperature above the softening point of the glass. Expansion of the glass fills void spaces including by-pass and tolerance channels of electrochemical devices. In addition, cassette to cassette seals can also be formed while channels and other void spaces are filled, reducing the number of processing steps needed.

  20. Flotation process for removal of precipitates from electrochemical chromate reduction unit

    DOE Patents [OSTI]

    DeMonbrun, James R.; Schmitt, Charles R.; Williams, Everett H.

    1976-01-01

    This invention is an improved form of a conventional electrochemical process for removing hexavalent chromium or other metal-ion contaminants from cooling-tower blowdown water. In the conventional process, the contaminant is reduced and precipitated at an iron anode, thus forming a mixed precipitate of iron and chromium hydroxides, while hydrogen being evolved copiously at a cathode is vented from the electrochemical cell. In the conventional process, subsequent separation of the fine precipitate has proved to be difficult and inefficient. In accordance with this invention, the electrochemical operation is conducted in a novel manner permitting a much more efficient and less expensive precipitate-recovery operation. That is, the electrochemical operation is conducted under an evolved-hydrogen partial pressure exceeding atmospheric pressure. As a result, most of the evolved hydrogen is entrained as bubbles in the blowdown in the cell. The resulting hydrogen-rich blowdown is introduced to a vented chamber, where the entrained hydrogen combines with the precipitate to form a froth which can be separated by conventional techniques. In addition to the hydrogen, two materials present in most blowdown act as flotation promoters for the precipitate. These are (1) air, with which the blowdown water becomes saturated in the course of normal cooling-tower operation, and (2) surfactants which commonly are added to cooling-tower recirculating-water systems to inhibit the growth of certain organisms or prevent the deposition of insoluble particulates.

  1. Process for manufacturing a lithium alloy electrochemical cell

    DOE Patents [OSTI]

    Bennett, William R.

    1992-10-13

    A process for manufacturing a lithium alloy, metal sulfide cell tape casts slurried alloy powders in an organic solvent containing a dissolved thermoplastic organic binder onto casting surfaces. The organic solvent is then evaporated to produce a flexible tape removable adhering to the casting surface. The tape is densified to increase its green strength and then peeled from the casting surface. The tape is laminated with a separator containing a lithium salt electrolyte and a metal sulfide electrode to form a green cell. The binder is evaporated from the green cell at a temperature lower than the melting temperature of the lithium salt electrolyte. Lithium alloy, metal sulfide and separator powders may be tape cast.

  2. Carbon activation process for increased surface accessibility in electrochemical capacitors

    DOE Patents [OSTI]

    Doughty, Daniel H.; Eisenmann, Erhard T.

    2001-01-01

    A process for making carbon film or powder suitable for double capacitor electrodes having a capacitance of up to about 300 F/cm.sup.3 is disclosed. This is accomplished by treating in aqueous nitric acid for a period of about 5 to 15 minutes thin carbon films obtained by carbonizing carbon-containing polymeric material having a high degree of molecular directionality, such as polyimide film, then heating the treated carbon film in a non-oxidizing atmosphere at a non-graphitizing temperature of at least 350.degree. C. for about 20 minutes, and repeating alternately the nitric acid step and the heating step from 7 to 10 times. Capacitors made with this carbon may find uses ranging from electronic devices to electric vehicle applications.

  3. Management of Salt Waste from Electrochemical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    Michael F. Simpson; Michael N. Patterson; Joon Lee; Yifeng Wang; Joshua Versey; Ammon Williams; Supathorn Phongikaroon; James Allensworth; Man-Sung Yim

    2013-10-01

    Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electrorefiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form.

  4. Management of salt waste from electrochemical processing of used nuclear fuel

    SciTech Connect (OSTI)

    Simpson, M.F.; Patterson, M.N.; Lee, J.; Wang, Y.; Versey, J.; Phongikaroon, S.

    2013-07-01

    Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electro-refiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form. (authors)

  5. Correlation of Process Data and Electrochemical Noise to Assess Kraft Digester Corrosion: Spring Grove Experiment

    SciTech Connect (OSTI)

    Pawel, SJ

    2003-06-18

    Electrochemical noise (ECN) probes were deployed in a carbon steel continuous kraft digester at four locations and at one location in the bottom cone of the associated flash tank. The probes consisted of carbon steel electrodes, representing the vessel construction material, and 309LSi stainless steel overlay electrodes, representing the weld overlay repair in a portion of the vessel. Current and potential noise, the temperature at each probe location, and the value of about 32 process parameters (flow rates, liquor chemistry, etc.) were monitored continuously for a period of almost one year. Historical vessel inspection data and post-test evaluation of the probe components were used to assess/compare ECN corrosion activity with physical changes in wall thickness and corrosion patterns on the digester shell. In addition, attempts were made to correlate ECN activity from each electrode type with process parameters. The results indicate the high general corrosion rates of steel observed just below the extraction screens--on the order of 35 mils/y for the past few years--accelerated further during the period of probe deployment. The maximum wastage of steel (normalized to one full year exposure) was about 85 mils/y at the ring 6N probe just below the extraction screens. Consistent with recent historical observations, the steel corrosion rate at the ring 6S probe--at the same elevation but directly across the digester from ring 6N--was significantly lower at about 50 mils/y. Just prior to probe deployment, the digester shell below the extraction screens was overlaid with 309LSi stainless steel, which was observed to be essentially immune to corrosion at this location. While the ECN probes detected differences in electrochemical behavior between steel probes and between 309LSi probes at rings 6N and 6S, there was only poor quantitative correlation of current sums with actual corrosion rates at these locations. A significant contribution of redox reactions on both steel and stainless steel electrodes appears to complicate ECN interpretation for all the probes, but particularly at the ring 6 locations. With the exception of start-up and shutdown activity, including brief upsets for ''hanging columns'' or brief maintenance periods, no correlation was observed between tracked process variables and ECN activity. Based on the ECN data, re-pressurization of the digester and resumption of chip/liquor feed after a brief disruption results in very aggressive corrosion events.

  6. Development of the chemical and electrochemical coal cleaning (CECC) process. Final report

    SciTech Connect (OSTI)

    Yoon, Roe-Hoan; Basilio, C.I.

    1992-05-01

    The Chemical and Electrochemical Coal Cleaning (CECC) process developed at Virginia Polytechnic Institute and State University was studied further in this project. This process offers a new method of physically cleaning both low- and high-rank coals without requiring fine grinding. The CECC process is based on liberating mineral matter from coal by osmotic pressure. The majority of the work was conducted on Middle Wyodak, Pittsburgh No. 8 and Elkhorn No. 3 coals. The coal samples were characterized for a variety of physical and chemical properties. Parametric studies were then conducted to identify the important operating parameters and to establish the optimum conditions. In addition, fundamental mechanisms of the process were studied, including mineral matter liberation, kinetics of mineral matter and pyrite dissolution, ferric ion regeneration schemes and alternative methods of separating the cleaned coal from the liberated mineral matter. The information gathered from the parametric and fundamental studies was used in the design, construction and testing of a bench-scale continuous CECC unit. Using this unit, the ash content of a Middle Wyodak coal was reduced from 6.96 to 1.61% at a 2 lbs/hr throughput. With an Elkhorn No. 3 sample, the ash content was reduced from 9.43 to 1.8%, while the sulfur content was reduced from 1.57 to 0.9%. The mass balance and liberation studies showed that liberation played a more dominant role than the chemical dissolution in removing mineral matter and inorganic sulfur from the different bituminous coals tested. However, the opposite was found to be the case for the Wyodak coal since this coal contained a significant amount of acid-soluble minerals.

  7. Selective Separation of Cs and Sr from LiCl-Based Salt for Electrochemical Processing of Oxide Spent Nuclear Fuel

    SciTech Connect (OSTI)

    P Sachdev

    2008-07-01

    Electrochemical processing technology is currently being used for the treatment of metallic spent fuel from the Experimental Breeder Reactor-II at Idaho National Laboratory. The treatment of oxide-based spent nuclear fuel via electrochemical processing is possible provided there is a front-end oxide reduction step. During this reduction process, certain fission products, including Cs and Sr, partition into the salt phase and form chlorides. Both solid state and molten LiCl-zeolite-A ion exchange tests were conducted for selectively removing Cs and Sr from LiCl-based salt. The solid-state tests produced in excess of 99% removal of Cs and Sr. The molten state tests failed due to phase transformation of the zeolite structure when in contact with the molten LiCl salt.

  8. Quantification of Electrochemical Nanoscale Processes in Lithium Batteries By OperandoEC-(S)TEM

    SciTech Connect (OSTI)

    Mehdi, Beata L.; Qian, Jiangfeng; Nasybulin, Eduard; Welch, David A.; Park, Chiwoo; Faller, Roland; Mehta, Hardeep S.; Henderson, Wesley A.; Xu, Wu; Evans, James E.; Liu, Jun; Zhang, Jiguang; Mueller, Karl T.; Browning, Nigel D.

    2015-07-27

    Lithium (Li)-ion batteries are currently used for a wide variety of portable electronic devices, electric vehicles and renewable energy applications. In addition, extensive worldwide research efforts are now being devoted to more advanced “beyond Li-ion” battery chemistries - such as lithium-sulfur (Li-S) and lithium-air (Li-O2) - in which the carbon anode is replaced with Li metal. However, the practical application of Li metal anode systems has been highly problematic. The main challenges involve controlling the formation of a solid-electrolyte interphase (SEI) layer and the suppression of Li dendrite growth during the charge/discharge process (achieving “dendrite-free” cycling). The SEI layer formation continuously consumes the electrolyte components creating highly resistive layer, which leads to the rapid decrease of cycling performance and degradation of the Li anode. The growth of Li metal dendrites at the anode contributes to rapid capacity fading (the presence of “dead Li” created during the discharge leads to an increased overpotential) and, in the case of continuous growth, leads to internal short circuits and extreme safety issues. Here we demonstrate the application of an operando electrochemical scanning transmission electron microscopy (ec-(S)TEM) cell to study the SEI layer formation and the initial stages of Li dendrite growth - the goal is to develop a mechanism for mitigating the degradation processes and increasing safety. Bright field (BF) STEM images in Figure 1 A-C show Li metal deposition and dissolution processes at the interface between the Pt working electrode and the lithium hexafluorophosphate (LiPF6) in propylene carbonate (PC) electrolyte during three charge/discharge cycles. A contrast reversal caused by Li metal being lighter/less dense than surrounding electrolyte (Li appears brighter than the background in BF STEM images) allows Li to be uniquely identified from the other components in the system - the only solid material that is less dense than the electrolyte is Li metal. Using these images, we can precisely quantify the total volume of Li deposition, the thickness of the SEI layer (observed as a ring of positive contrast around the electrode) and alloy formation due to Li+ ion insertion during each cycle. Furthermore, at the end of each discharge cycle we can quantify the presence of “dead Li” detached from the Pt electrode, thereby demonstrating the degree of irreversibility (and degradation of Pt electrode) associated with insertion/removal of Li+during this process with direct correlation to electrochemical performance. Such analyses provide significant insights into Li metal dendrite growth, which is critical to understand the complex interfacial reactions needed to be controlled for future Li-based and next generation energy storage systems.

  9. Electrochemical capacitor

    DOE Patents [OSTI]

    Anderson, Marc A.; Liu, Kuo -Chuan; Mohr, Charles M.

    1999-10-05

    An inexpensive porous metal oxide material having high surface area, good conductivity and high specific capacitance is advantageously used in an electrochemical capacitor. The materials are formed in a sol-gel process which affords control over the properties of the resultant metal oxide materials.

  10. In situ heat treatment of a tar sands formation after drive process treatment

    DOE Patents [OSTI]

    Vinegar, Harold J.; Stanecki, John

    2010-09-21

    A method for treating a tar sands formation includes providing a drive fluid to a hydrocarbon containing layer of the tar sands formation to mobilize at least some hydrocarbons in the layer. At least some first hydrocarbons from the layer are produced. Heat is provided to the layer from one or more heaters located in the formation. At least some second hydrocarbons are produced from the layer of the formation. The second hydrocarbons include at least some hydrocarbons that are upgraded compared to the first hydrocarbons produced by using the drive fluid.

  11. Electrochemical machining process for forming surface roughness elements on a gas turbine shroud

    DOE Patents [OSTI]

    Lee, Ching-Pang (Cincinnati, OH); Johnson, Robert Alan (Simpsonville, SC); Wei, Bin (Mechanicville, NY); Wang, Hsin-Pang (Rexford, NY)

    2002-01-01

    The back side recessed cooling surface of a shroud defining in part the hot gas path of a turbine is electrochemically machined to provide surface roughness elements and spaces therebetween to increase the heat transfer coefficient. To accomplish this, an electrode with insulating dielectric portions and non-insulating portions is disposed in opposition to the cooling surface. By passing an electrolyte between the cooling surface and electrode and applying an electrical current between the electrode and a shroud, roughness elements and spaces therebetween are formed in the cooling surface in opposition to the insulating and non-insulating portions of the electrode, hence increasing the surface area and heat transfer coefficient of the shroud.

  12. Extending the Range of Organic Compounds that Can Be Destroyed Using the Process of Adsorption Coupled with Electrochemical Regeneration - 13054

    SciTech Connect (OSTI)

    Brown, Nigel; Lodge, Mike; Hilton, Linda; Adams, Alex [Arvia Technology Ltd, Sci-Tech Daresbury, Keckwick Lane, Daresbury, Cheshire, WA4, 4FS (United Kingdom)] [Arvia Technology Ltd, Sci-Tech Daresbury, Keckwick Lane, Daresbury, Cheshire, WA4, 4FS (United Kingdom); Vaudey, Claire-Emilie [AREVA CL BU, AREVA BUA STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France)] [AREVA CL BU, AREVA BUA STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France); Toulemonde, Valerie [AREVA DRD, Tour AREVA, 1, place Jean Millier, 92084 Paris La Defense Cedex (France)] [AREVA DRD, Tour AREVA, 1, place Jean Millier, 92084 Paris La Defense Cedex (France)

    2013-07-01

    The nuclear industry is not a provider of oils and solvents but uses them in motors, equipment and even in chemical processes to extract valuable products. Currently, for old and contaminated oils and solvents, techniques still exist, such as incineration, but not all the oils and solvents are compatible with this technique because the activities of some components inside the oils are too high to be accepted at the incineration facility. For these oils, an alternative technique needs to be found for treatment. A process developed for water treatment using a technique of adsorption coupled with electrochemical regeneration has been investigated to assess its capability to treat these organic wastes. One of the strengths of the process is its flexibility and adaptation to different compositions of oils. This point is important because, in the AREVA case, there are a lot of small volumes of old oils which need to be re-characterized. It takes time and money to do it especially when oils are contaminated; this is one reason why the technique is interesting to investigate. Tests have been performed with different oils coming from different sites to test the feasibility. Results demonstrate the destruction of a range of organics with regeneration energy requirements of 13.4 - 68.7 kWh/l and offer confidence for the future potential of the process. (authors)

  13. iDriving (Intelligent Driving)

    Energy Science and Technology Software Center (OSTI)

    2012-09-17

    iDriving identifies the driving style factors that have a major impact on fuel economy. An optimization framework is used with the aim of optimizing a driving style with respect to these driving factors. A set of polynomial metamodels is constructed to reflect the responses produced in fuel economy by changing the driving factors. The optimization framework is used to develop a real-time feedback system, including visual instructions, to enable drivers to alter their driving stylesmore » in responses to actual driving conditions to improve fuel efficiency.« less

  14. Electrochemical Techniques

    SciTech Connect (OSTI)

    Chen, Gang; Lin, Yuehe

    2008-07-20

    Sensitive and selective detection techniques are of crucial importance for capillary electrophoresis (CE), microfluidic chips, and other microfluidic systems. Electrochemical detectors have attracted considerable interest for microfluidic systems with features that include high sensitivity, inherent miniaturization of both the detection and control instrumentation, low cost and power demands, and high compatibility with microfabrication technology. The commonly used electrochemical detectors can be classified into three general modes: conductimetry, potentiometry, and amperometry.

  15. Electrochemical photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, Terje A.

    1984-01-01

    Improved electrochemical photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  16. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1996-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  17. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1994-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  18. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-02-01

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm[sup 3]; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6[times]10[sup 4] cm[sup 2]/g of Ni. 8 figures.

  19. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1996-07-16

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm{sup 3}; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6{times}10{sup 4}cm{sup 2}/g of Ni. 6 figs.

  20. Drive alignment pays maintenance dividends

    SciTech Connect (OSTI)

    Fedder, R.

    2008-12-15

    Proper alignment of the motor and gear drive on conveying and processing equipment will result in longer bearing and coupling life, along with lower maintenance costs. Selecting an alignment free drive package instead of a traditional foot mounted drive and motor is a major advancement toward these goals. 4 photos.

  1. Electrochemical construction

    DOE Patents [OSTI]

    Einstein, Harry; Grimes, Patrick G.

    1983-08-23

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  2. Electrochemical device

    DOE Patents [OSTI]

    Grimes, Patrick G.; Einstein, Harry; Bellows, Richard J.

    1988-01-12

    A tunnel protected electrochemical device features channels fluidically communicating between manifold, tunnels and cells. The channels are designed to provide the most efficient use of auxiliary power. The channels have a greater hydraulic pressure drop and electrical resistance than the manifold. This will provide a design with the optimum auxiliary energy requirements.

  3. Electrochemical Energy Storage Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    This U.S. DRIVE electrochemical energy storage roadmap describes ongoing and planned efforts to develop electrochemical energy storage technologies for plug-in electric vehicles (PEVs). The Energy Storage activity comprises a number of research areas (including advanced materials research, cell level research, battery development, and enabling R&D which includes analysis, testing and other activities) for advanced energy storage technologies (batteries and ultra-capacitors).

  4. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1994-01-01

    An electrochemical cell having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a .beta." alumina electrolyte and NaAlCl.sub.4 or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose.

  5. Electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-12-23

    This patent describes an electrochemical cell having a metal anode wherein the metal is selected from zinc and cadmium; a bromine cathode; and an aqueous electrolyte containing a metal bromide, the metal bromide having the same metal as the metal of the anode. The improvement described here comprises: a bromine complexing agent in the aqueous metal bromide electrolyte, the complexing agent consisting solely of a quaternary ammonium salt of an N-organo substituted alpha amino acid, ester, or betaine.

  6. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Myles, Kevin M.; Vissers, Donald R.; Prakash, Jai

    1996-01-01

    An electrochemical cell with a positive electrode having an electrochemically active layer of at least one transition metal chloride. A negative electrode of an alkali metal and a compatible electrolyte including an alkali metal salt molten at cell operating temperature is included in the cell. The electrolyte is present at least partially as a corrugated .beta." alumina tube surrounding the negative electrode interior to the positive electrode. The ratio of the volume of liquid electrolyte to the volume of the positive electrode is in the range of from about 0.1 to about 3. A plurality of stacked electrochemical cells is disclosed each having a positive electrode, a negative electrode of an alkali metal molten at cell operating temperature, and a compatible electrolyte. The electrolyte is at least partially present as a corrugated .beta." alumina sheet separating the negative electrode and interior to the positive electrodes. The alkali metal is retained in a porous electrically conductive ceramic, and seals for sealing the junctures of the electrolyte and the adjacent electrodes at the peripheries thereof.

  7. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Myles, K.M.; Vissers, D.R.; Prakash, J.

    1996-07-02

    An electrochemical cell is described with a positive electrode having an electrochemically active layer of at least one transition metal chloride. A negative electrode of an alkali metal and a compatible electrolyte including an alkali metal salt molten at cell operating temperature is included in the cell. The electrolyte is present at least partially as a corrugated {beta}{double_prime} alumina tube surrounding the negative electrode interior to the positive electrode. The ratio of the volume of liquid electrolyte to the volume of the positive electrode is in the range of from about 0.1 to about 3. A plurality of stacked electrochemical cells is disclosed each having a positive electrode, a negative electrode of an alkali metal molten at cell operating temperature, and a compatible electrolyte. The electrolyte is at least partially present as a corrugated {beta}{double_prime} alumina sheet separating the negative electrode and interior to the positive electrodes. The alkali metal is retained in a porous electrically conductive ceramic, and seals for sealing the junctures of the electrolyte and the adjacent electrodes at the peripheries thereof. 8 figs.

  8. Electrochemical cell

    DOE Patents [OSTI]

    Nagy, Zoltan; Yonco, Robert M.; You, Hoydoo; Melendres, Carlos A.

    1992-01-01

    An electrochemical cell has a layer-type or sandwich configuration with a Teflon center section that houses working, reference and counter electrodes and defines a relatively narrow electrolyte cavity. The center section is surrounded on both sides with thin Teflon membranes. The membranes are pressed in place by a pair of Teflon inner frames which are in turn supported by a pair of outer metal frames. The pair of inner and outer frames are provided with corresponding, appropriately shaped slits that are in plane generally transverse to the plane of the working electrode and permit X-ray beams to enter and exit the cell through the Teflon membranes that cover the slits so that the interface between the working electrode and the electrolyte within the cell may be analyzed by transmission geometry. In one embodiment, the center section consists of two parts, one on top of the other. Alternatively, the center section of the electrochemical cell may consist of two intersliding pieces or may be made of a single piece of Teflon sheet material. The electrolyte cavity is shaped so that the electrochemical cell can be rotated 90.degree. in either direction while maintaining the working and counter electrodes submerged in the electrolyte.

  9. Electrochemical cell

    DOE Patents [OSTI]

    Nagy, Z.; Yonco, R.M.; You, H.; Melendres, C.A.

    1992-08-25

    An electrochemical cell has a layer-type or sandwich configuration with a Teflon center section that houses working, reference and counter electrodes and defines a relatively narrow electrolyte cavity. The center section is surrounded on both sides with thin Teflon membranes. The membranes are pressed in place by a pair of Teflon inner frames which are in turn supported by a pair of outer metal frames. The pair of inner and outer frames are provided with corresponding, appropriately shaped slits that are in plane generally transverse to the plane of the working electrode and permit X-ray beams to enter and exit the cell through the Teflon membranes that cover the slits so that the interface between the working electrode and the electrolyte within the cell may be analyzed by transmission geometry. In one embodiment, the center section consists of two parts, one on top of the other. Alternatively, the center section of the electrochemical cell may consist of two intersliding pieces or may be made of a single piece of Teflon sheet material. The electrolyte cavity is shaped so that the electrochemical cell can be rotated 90[degree] in either direction while maintaining the working and counter electrodes submerged in the electrolyte. 5 figs.

  10. Electrochemical components employing polysiloxane-derived binders

    DOE Patents [OSTI]

    Delnick, Frank M.

    2013-06-11

    A processed polysiloxane resin binder for use in electrochemical components and the method for fabricating components with the binder. The binder comprises processed polysiloxane resin that is partially oxidized and retains some of its methyl groups following partial oxidation. The binder is suitable for use in electrodes of various types, separators in electrochemical devices, primary lithium batteries, electrolytic capacitors, electrochemical capacitors, fuel cells and sensors.

  11. Microfabricated microengine for use as a mechanical drive and power source in the microdomain and fabrication process

    DOE Patents [OSTI]

    Garcia, E.J.; Sniegowski, J.J.

    1997-05-20

    A microengine uses two synchronized linear actuators as a power source and converts oscillatory motion from the actuators into rotational motion via direct linkage connection to an output gear or wheel. The microengine provides output in the form of a continuously rotating output gear that is capable of delivering drive torque to a micromechanism. The microengine can be operated at varying speeds and its motion can be reversed. Linear actuators are synchronized in order to provide linear oscillatory motion to the linkage means in the X and Y directions according to a desired position, rotational direction and speed of said mechanical output means. The output gear has gear teeth on its outer perimeter for directly contacting a micromechanism requiring mechanical power. The gear is retained by a retaining means which allows said gear to rotate freely. The microengine is microfabricated of polysilicon on one wafer using surface micromachining batch fabrication. 30 figs.

  12. Microfabricated microengine for use as a mechanical drive and power source in the microdomain and fabrication process

    DOE Patents [OSTI]

    Garcia, Ernest J.; Sniegowski, Jeffry J.

    1997-01-01

    A microengine uses two synchronized linear actuators as a power source and converts oscillatory motion from the actuators into rotational motion via direct linkage connection to an output gear or wheel. The microengine provides output in the form of a continuously rotating output gear that is capable of delivering drive torque to a micromechanism. The microengine can be operated at varying speeds and its motion can be reversed. Linear actuators are synchronized in order to provide linear oscillatory motion to the linkage means in the X and Y directions according to a desired position, rotational direction and speed of said mechanical output means. The output gear has gear teeth on its outer perimeter for directly contacting a micromechanism requiring mechanical power. The gear is retained by a retaining means which allows said gear to rotate freely. The microengine is microfabricated of polysilicon on one wafer using surface micromachining batch fabrication.

  13. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-08-23

    An electrochemical cell is described having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a [beta] alumina electrolyte and NaAlCl[sub 4] or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose. 6 figs.

  14. Electrochemical cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1984-01-01

    An improved secondary electrochemical cell is disclosed having a negative electrode of lithium aluminum, a positive electrode of iron sulfide, a molten electrolyte of lithium chloride and potassium chloride, and the combination that the fully charged theoretical capacity of the negative electrode is in the range of 0.5-1.0 that of the positive electrode. The cell thus is negative electrode limiting during discharge cycling. Preferably, the negative electrode contains therein, in the approximate range of 1-10 volume % of the electrode, an additive from the materials of graphitized carbon, aluminum-iron alloy, and/or magnesium oxide.

  15. Electrochemical cell (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Title: Electrochemical cell An electrochemical cell having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated ...

  16. Electrochemical cell (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Title: Electrochemical cell An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali ...

  17. Electrochemical supercapacitors

    DOE Patents [OSTI]

    Rudge, Andrew J.; Ferraris, John P.; Gottesfeld, Shimshon

    1996-01-01

    A new class of electrochemical capacitors provides in its charged state a positive electrode including an active material of a p-doped material and a negative electrode including an active material of an n-doped conducting polymer, where the p-doped and n-doped materials are separated by an electrolyte. In a preferred embodiment, the positive and negative electrode active materials are selected from conducting polymers consisting of polythiophene, polymers having an aryl group attached in the 3-position, polymers having aryl and alkyl groups independently attached in the 3- and 4-positions, and polymers synthesized from bridged dimers having polythiophene as the backbone. A preferred electrolyte is a tetraalykyl ammonium salt, such as tetramethylammonium trifluoromethane sulphonate (TMATFMS), that provides small ions that are mobile through the active material, is soluble in acetonitrile, and can be used in a variety of capacitor configurations.

  18. Driving Down HB-LED Costs. Implementation of Process Simulation Tools and Temperature Control Methods of High Yield MOCVD Growth

    SciTech Connect (OSTI)

    Quinn, William

    2012-04-30

    The overall objective of this multi-faceted program is to develop epitaxial growth systems that meet a goal of 75% (4X) cost reduction in the epitaxy phase of HB-LED manufacture. A 75% reduction in yielded epitaxy cost is necessary in order to achieve the cost goals for widespread penetration of HB-LED's into back-lighting units (BLU) for LCD panels and ultimately for solid-state lighting (SSL). To do this, the program will address significant improvements in overall equipment Cost of Ownership, or CoO. CoO is a model that includes all costs associated with the epitaxy portion of production. These aspects include cost of yield, capital cost, operational costs, and maintenance costs. We divide the program into three phases where later phases will incorporate the gains of prior phases. Phase one activities are enabling technologies. In collaboration with Sandia National Laboratories we develop a Fluent-compatible chemistry predictive model and a set of mid-infrared and near-ultraviolet pyrometer monitoring tools. Where previously the modeling of the reactor dynamics were studied within FLUENT alone, here, FLUENT and Chemkin are integrated into a comprehensive model of fluid dynamics and the most advanced transport equations developed for Chemkin. Specifically, the Chemkin model offered the key reaction terms for gas-phase nucleation, a key consideration in the optimization of the MOCVD process. This new predictive model is used to design new MOCVD reactors with optimized growth conditions and the newly developed pyrometers are used monitor and control the MOCVD process temperature to within 0.5°C run-to-run and within each wafer. This portion of the grant is in collaboration with partners at Sandia National Laboratories. Phase two activities are continuous improvement projects which extend the current reactor platform along the lines of improved operational efficiency, improved systems control for throughput, and carrier modifications for increased yield. Programmatically, improvements made in Phase I are applied to developments of Phase II when applicable. Phase three is the culmination of the individual tasks from both phases one and two applied to proposed production platforms. We selectively combine previously demonstrated tasks and other options to develop a high-volume production-worthy MOCVD system demonstrating >3x throughput, 1.3x capital efficiency, and 0.7x cost of ownership. In a parallel demonstration we validate the concept of an improved, larger deposition system which utilizes the predictive modeling of chemistry-based flow analysis and extensions of the improvements demonstrated on the current platforms. This validation includes the build and testing of a prototype version of the hardware and demonstration of 69% reduction in the cost of ownership. Also, in this phase we present a stand-alone project to develop a high-temperature system which improves source efficiency by 30% while concurrently increasing growth rate by 1.3x. The material quality is held to the same material quality specifications of our existing baseline processes. The merits of other line item tasks in phase three are discussed for inclusion on next-generation platforms.

  19. Microfluidic electrochemical reactors

    DOE Patents [OSTI]

    Nuzzo, Ralph G.; Mitrovski, Svetlana M.

    2011-03-22

    A microfluidic electrochemical reactor includes an electrode and one or more microfluidic channels on the electrode, where the microfluidic channels are covered with a membrane containing a gas permeable polymer. The distance between the electrode and the membrane is less than 500 micrometers. The microfluidic electrochemical reactor can provide for increased reaction rates in electrochemical reactions using a gaseous reactant, as compared to conventional electrochemical cells. Microfluidic electrochemical reactors can be incorporated into devices for applications such as fuel cells, electrochemical analysis, microfluidic actuation, pH gradient formation.

  20. Electrochemical planarization

    DOE Patents [OSTI]

    Bernhardt, Anthony F. (Berkeley, CA); Contolini, Robert J. (Pleasanton, CA)

    1993-01-01

    In a process for fabricating planarized thin film metal interconnects for integrated circuit structures, a planarized metal layer is etched back to the underlying dielectric layer by electropolishing, ion milling or other procedure. Electropolishing reduces processing time from hours to minutes and allows batch processing of multiple wafers. The etched back planarized thin film interconnect is flush with the dielectric layer.

  1. Electrochemical planarization

    DOE Patents [OSTI]

    Bernhardt, A.F.; Contolini, R.J.

    1993-10-26

    In a process for fabricating planarized thin film metal interconnects for integrated circuit structures, a planarized metal layer is etched back to the underlying dielectric layer by electropolishing, ion milling or other procedure. Electropolishing reduces processing time from hours to minutes and allows batch processing of multiple wafers. The etched back planarized thin film interconnect is flush with the dielectric layer. 12 figures.

  2. Recognized Leader in Electrochemical Purification

    SciTech Connect (OSTI)

    Hoppe, Eric

    2013-11-20

    PNNL scientists developed an electrochemical method for purifying copper, a key material that makes possible radiation detection systems of unprecedented sensitivity. The method begins with the purest copper materials available, and results in the lowest-background copper in the world. Chemist Eric Hoppe explains the process.

  3. Recognized Leader in Electrochemical Purification

    ScienceCinema (OSTI)

    Hoppe, Eric

    2014-07-24

    PNNL scientists developed an electrochemical method for purifying copper, a key material that makes possible radiation detection systems of unprecedented sensitivity. The method begins with the purest copper materials available, and results in the lowest-background copper in the world. Chemist Eric Hoppe explains the process.

  4. System and method for networking electrochemical devices

    DOE Patents [OSTI]

    Williams, Mark C.; Wimer, John G.; Archer, David H.

    1995-01-01

    An improved electrochemically active system and method including a plurality of electrochemical devices, such as fuel cells and fluid separation devices, in which the anode and cathode process-fluid flow chambers are connected in fluid-flow arrangements so that the operating parameters of each of said plurality of electrochemical devices which are dependent upon process-fluid parameters may be individually controlled to provide improved operating efficiency. The improvements in operation include improved power efficiency and improved fuel utilization in fuel cell power generating systems and reduced power consumption in fluid separation devices and the like through interstage process fluid parameter control for series networked electrochemical devices. The improved networking method includes recycling of various process flows to enhance the overall control scheme.

  5. Holiday Food Drive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Food Drive Holiday Food Drive Laboratory employees helped donate 300 boxes of nonperishable food items and 360 frozen turkeys during the 2015 annual food drive. September 16, 2013 LANL employees organize food for the Holiday Food Drive. Contacts Annual Food & Holiday Gift Drives Mike Martinez (505) 699-3388 Community Relations & Partnerships (505) 665-4400 Email Helping feed Northern New Mexico families During the Laboratory's 2015 Annual Food Drive, employees and subcontract workers

  6. Electrochemical methane sensor

    DOE Patents [OSTI]

    Zaromb, S.; Otagawa, T.; Stetter, J.R.

    1984-08-27

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  7. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to their hydride form. In addition to this experimental work, a parallel project was carried out to develop a new model of electrochemical impedance spectroscopy (EIS) that could be used to define the mechanisms of the electrochemical hydrogenation reactions. The EIS technique is capable of probing complex chemical and electrochemical reactions, and our model was written into a computer code that allowed the input of experimental EIS data and the extraction of kinetic parameters based on a best-fit analysis of theoretical reaction schemes. Finally, electrochemical methods for hydrogenating organic and metallo-organic materials have been explored.

  8. US DRIVE Electrochemical Energy Storage Technical Team Roadmap...

    Energy Savers [EERE]

    storage technologies (batteries and ultra-capacitors). PDF icon eesttroadmapjune2013.pdf More Documents & Publications Overview of the Batteries for Advanced Transportation ...

  9. U.S. DRIVE Partnership Releases Accomplishments Report

    Broader source: Energy.gov [DOE]

    The U.S. DRIVE Partnership has released its 2014 Accomplishments Report, which includes significant technical accomplishments in advanced combustion and emission control, electrical and electronics, electrochemical energy storage, fuel cells, materials, vehicle systems analysis, codes and standards, hydrogen storage, grid interaction, fuel pathway integration, hydrogen delivery, and hydrogen production.

  10. Electrochemical formation of field emitters

    DOE Patents [OSTI]

    Bernhardt, Anthony F.

    1999-01-01

    Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area.

  11. Electrochemical cell stack assembly

    DOE Patents [OSTI]

    Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2010-06-22

    Multiple stacks of tubular electrochemical cells having a dense electrolyte disposed between an anode and a cathode preferably deposited as thin films arranged in parallel on stamped conductive interconnect sheets or ferrules. The stack allows one or more electrochemical cell to malfunction without disabling the entire stack. Stack efficiency is enhanced through simplified gas manifolding, gas recycling, reduced operating temperature and improved heat distribution.

  12. Electrochemical thermodynamic measurement system

    DOE Patents [OSTI]

    Reynier, Yvan; Yazami, Rachid; Fultz, Brent T.

    2009-09-29

    The present invention provides systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and electrochemical energy storage and conversion systems. Systems and methods of the present invention are configured for simultaneously collecting a suite of measurements characterizing a plurality of interconnected electrochemical and thermodynamic parameters relating to the electrode reaction state of advancement, voltage and temperature. Enhanced sensitivity provided by the present methods and systems combined with measurement conditions that reflect thermodynamically stabilized electrode conditions allow very accurate measurement of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and electrochemical systems, such as the energy, power density, current rate and the cycle life of an electrochemical cell.

  13. Planar electrochemical device assembly

    DOE Patents [OSTI]

    Jacobson; Craig P. (Lafayette, CA), Visco; Steven J. (Berkeley, CA), De Jonghe; Lutgard C. (Lafayette, CA)

    2010-11-09

    A pre-fabricated electrochemical device having a dense electrolyte disposed between an anode and a cathode preferably deposited as thin films is bonded to a porous electrically conductive support. A second porous electrically conductive support may be bonded to a counter electrode of the electrochemical device. Multiple electrochemical devices may be bonded in parallel to a single porous support, such as a perforated sheet to provide a planar array. Planar arrays may be arranged in a stacked interconnected array. A method of making a supported electrochemical device is disclosed wherein the method includes a step of bonding a pre-fabricated electrochemical device layer to an existing porous metal or porous metal alloy layer.

  14. Planar electrochemical device assembly

    DOE Patents [OSTI]

    Jacobson, Craig P. (Lafayette, CA); Visco, Steven J. (Berkeley, CA); De Jonghe, Lutgard C. (Lafayette, CA)

    2007-06-19

    A pre-fabricated electrochemical device having a dense electrolyte disposed between an anode and a cathode preferably deposited as thin films is bonded to a porous electrically conductive support. A second porous electrically conductive support may be bonded to a counter electrode of the electrochemical device. Multiple electrochemical devices may be bonded in parallel to a single porous support, such as a perforated sheet to provide a planar array. Planar arrays may be arranged in a stacked interconnected array. A method of making a supported electrochemical device is disclosed wherein the method includes a step of bonding a pre-fabricated electrochemical device layer to an existing porous metal or porous metal alloy layer.

  15. Electrode for electrochemical cell

    DOE Patents [OSTI]

    Kaun, T.D.; Nelson, P.A.; Miller, W.E.

    1980-05-09

    An electrode structure for a secondary electrochemical cell includes an outer enclosure defining a compartment containing electrochemical active material. The enclosure includes a rigid electrically conductive metal sheet with perforated openings over major side surfaces. The enclosure can be assembled as first and second trays each with a rigid sheet of perforated electrically conductive metal at major side surfaces and normally extending flanges at parametric margins. The trays can be pressed together with moldable active material between the two to form an expandable electrode. A plurality of positive and negative electrodes thus formed are arranged in an alternating array with porous frangible interelectrode separators within the housing of the secondary electrochemical cell.

  16. Drill drive mechanism

    DOE Patents [OSTI]

    Dressel, Michael O.

    1979-01-01

    A drill drive mechanism is especially adapted to provide both rotational drive and axial feed for a drill of substantial diameter such as may be used for drilling holes for roof bolts in mine shafts. The drill shaft is made with a helical pattern of scroll-like projections on its surface for removal of cuttings. The drill drive mechanism includes a plurality of sprockets carrying two chains of drive links which are arranged to interlock around the drill shaft with each drive link having depressions which mate with the scroll-like projections. As the chain links move upwardly or downwardly the surfaces of the depressions in the links mate with the scroll projections to move the shaft axially. Tangs on the drive links mate with notch surfaces between scroll projections to provide a means for rotating the shaft. Projections on the drive links mate together at the center to hold the drive links tightly around the drill shaft. The entire chain drive mechanism is rotated around the drill shaft axis by means of a hydraulic motor and gear drive to cause rotation of the drill shaft. This gear drive also connects with a differential gearset which is interconnected with a second gear. A second motor is connected to the spider shaft of the differential gearset to produce differential movement (speeds) at the output gears of the differential gearset. This differential in speed is utilized to drive said second gear at a speed different from the speed of said gear drive, this speed differential being utilized to drive said sprockets for axial movement of said drill shaft.

  17. Variable temperature electrochemical strain microscopy of Sm-doped ceria

    SciTech Connect (OSTI)

    Jesse, Stephen; Morozovska, A. N.; Kalinin, Sergei V; Eliseev, E. A.; Yang, Nan; Doria, Sandra; Tebano, Antonello

    2013-01-01

    Variable temperature electrochemical strain microscopy has been used to study the electrochemical activity of Sm-doped ceria as a function of temperature and bias. The electrochemical strain microscopy hysteresis loops have been collected across the surface at different temperatures and the relative activity at different temperatures has been compared. The relaxation behavior of the signal at different temperatures has been also evaluated to relate kinetic process during bias induced electrochemical reactions with temperature and two different kinetic regimes have been identified. The strongly non-monotonic dependence of relaxation behavior on temperature is interpreted as evidence for water-mediated mechanisms.

  18. Electrochemical heat engine

    DOE Patents [OSTI]

    Elliott, Guy R. B.; Holley, Charles E.; Houseman, Barton L.; Sibbitt, Jr., Wilmer L.

    1978-01-01

    Electrochemical heat engines produce electrochemical work, and mechanical motion is limited to valve and switching actions as the heat-to-work cycles are performed. The electrochemical cells of said heat engines use molten or solid electrolytes at high temperatures. One or more reactions in the cycle will generate a gas at high temperature which can be condensed at a lower temperature with later return of the condensate to electrochemical cells. Sodium, potassium, and cesium are used as the working gases for high temperature cells (above 600 K) with halogen gases or volatile halides being used at lower temperature. Carbonates and halides are used as molten electrolytes and the solid electrolyte in these melts can also be used as a cell separator.

  19. Electrochemical Energy Summit 2015

    Broader source: Energy.gov [DOE]

    The Fuel Cell Technologies Office will host several events at the Electrochemical Energy Summit 2015 in Phoenix, Arizona, October 12–14, 2015, to foster increased collaboration between the national...

  20. Solid state electrochemical composite

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (Moraga, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2009-06-30

    Provided is a composite electrochemical device fabricated from highly electronically conductive materials such as metals, metal alloys, or electronically conductive ceramics. The electronic conductivity of the electrode substrate is maximized. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in ionic (electrochemical) devices such as fuel cells and electrolytic gas separation systems including oxygen generation system.

  1. School Supply Drive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    School Supply Drive School Supply Drive Each year, Laboratory employees donate school supplies and backpacks for Northern New Mexico students as they start the new school year. September 16, 2013 Del Norte Credit Union's Baxter Bear takes a moment to pose with some of the backpacks filled with school supplies that will help students start their school year off right. Contact Giving Drives Mike Martinez Community Relations & Partnerships (505) 699-3388 Email Providing students with good start

  2. Holiday Food Drive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community Programs Office (505) 665-4400 Email Get Expertise Helping feed Northern New Mexico families During the Laboratory's 2015 Annual Food Drive, employees and subcontract...

  3. Variable Frequency Drives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marketing Toolkit The Benefits of Variable Frequency Drives (VFDs) VFDs help adjust motor speeds to match loads and improve efficiency while conserving energy. The benefits...

  4. Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Z.; Zhu, Y.; Zhang, W.; Wang, F.; Zhang, Q.; Qiu, B.; Han, S.; Xia, Y.; Liu, Z.

    2015-03-27

    Lithium-rich material owns a particularly high capacity owing to the activation of electrochemical inactive Li2MnO3 phase. But at the same time, MnO2 phase formed after Li2MnO3 activation confronts a severe problem of converting to spinel phase, and resulting in voltage decay. To our knowledge, this phenomenon is inherent property of layered manganese oxide materials and can hardly be overcome. Based on this, unlike previous reports, herein we design a method for the first time to accelerate the phase transformation by tuning the charge upper-limit voltage at a high value, so the phase transformation process can be finished in a fewmore » cycles. Then material structure remains stable while cycling at a low upper-limit voltage. By this novel method voltage decay is eliminated significantly.« less

  5. Piezoelectric drive circuit

    DOE Patents [OSTI]

    Treu, C.A. Jr.

    1999-08-31

    A piezoelectric motor drive circuit is provided which utilizes the piezoelectric elements as oscillators and a Meacham half-bridge approach to develop feedback from the motor ground circuit to produce a signal to drive amplifiers to power the motor. The circuit automatically compensates for shifts in harmonic frequency of the piezoelectric elements due to pressure and temperature changes. 7 figs.

  6. Piezoelectric drive circuit

    DOE Patents [OSTI]

    Treu, Jr., Charles A.

    1999-08-31

    A piezoelectric motor drive circuit is provided which utilizes the piezoelectric elements as oscillators and a Meacham half-bridge approach to develop feedback from the motor ground circuit to produce a signal to drive amplifiers to power the motor. The circuit automatically compensates for shifts in harmonic frequency of the piezoelectric elements due to pressure and temperature changes.

  7. Electrochemical formation of field emitters

    DOE Patents [OSTI]

    Bernhardt, A.F.

    1999-03-16

    Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays is disclosed. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area. 12 figs.

  8. Electrochemical micro sensor

    DOE Patents [OSTI]

    Setter, Joseph R. (Naperville, IL); Maclay, G. Jordan (Maywood, IL)

    1989-09-12

    A micro-amperometric electrochemical sensor for detecting the presence of a pre-determined species in a fluid material is disclosed. The sensor includes a smooth substrate having a thin coating of solid electrolytic material deposited thereon. The working and counter electrodes are deposited on the surface of the solid electrolytic material and adhere thereto. Electrical leads connect the working and counter electrodes to a potential source and an apparatus for measuring the change in an electrical signal caused by the electrochemical oxidation or reduction of the species. Alternatively, the sensor may be fabricated in a sandwich structure and also may be cylindrical, spherical or other shapes.

  9. Electrochemical membrane incinerator

    DOE Patents [OSTI]

    Johnson, Dennis C. (Ames, IA); Houk, Linda L. (Ames, IA); Feng, Jianren (Ames, IA)

    2001-03-20

    Electrochemical incineration of p-benzoquinone was evaluated as a model for the mineralization of carbon in toxic aromatic compounds. A Ti or Pt anode was coated with a film of the oxides of Ti, Ru, Sn and Sb. This quaternary metal oxide film was stable; elemental analysis of the electrolyzed solution indicated the concentration of these metal ions to be 3 .mu.g/L or less. The anode showed good reactivity for the electrochemical incineration of benzoquinone. The use of a dissolved salt matrix as the so-called "supporting electrolyte" was eliminated in favor of a solid-state electrolyte sandwiched between the anode and cathode.

  10. Electrochemical fabrication of capacitors

    DOE Patents [OSTI]

    Mansour, Azzam N. (Fairfax Sta., VA); Melendres, Carlos A. (Lemont, IL)

    1999-01-01

    A film of nickel oxide is anodically deposited on a graphite sheet held in osition on an electrochemical cell during application of a positive electrode voltage to the graphite sheet while exposed to an electrolytic nickel oxide solution within a volumetrically variable chamber of the cell. An angularly orientated x-ray beam is admitted into the cell for transmission through the deposited nickel oxide film in order to obtain structural information while the film is subject to electrochemical and in-situ x-ray spectroscopy from which optimum film thickness, may be determined by comparative analysis for capacitor fabrication purposes.

  11. Separators for electrochemical cells

    DOE Patents [OSTI]

    Carlson, Steven Allen; Anakor, Ifenna Kingsley

    2014-11-11

    Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

  12. Electrochemical nitridation of metal surfaces

    DOE Patents [OSTI]

    Wang, Heli; Turner, John A.

    2015-06-30

    Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.

  13. Control rod drive

    DOE Patents [OSTI]

    Hawke, Basil C.

    1986-01-01

    A control rod drive uses gravitational forces to insert one or more control rods upwardly into a reactor core from beneath the reactor core under emergency conditions. The preferred control rod drive includes a vertically movable weight and a mechanism operatively associating the weight with the control rod so that downward movement of the weight is translated into upward movement of the control rod. The preferred control rod drive further includes an electric motor for driving the control rods under normal conditions, an electrically actuated clutch which automatically disengages the motor during a power failure and a decelerator for bringing the control rod to a controlled stop when it is inserted under emergency conditions into a reactor core.

  14. US DRIVE Driving Research and Innovation for Vehicle Efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US DRIVE Fuel Pathway Integration Technical Team Roadmap Hydrogen Program Goal-Setting Methodologies Report to Congress US DRIVE Hydrogen Production Technical Team Roadmap

  15. Direct drive wind turbine

    DOE Patents [OSTI]

    Bywaters, Garrett Lee; Danforth, William; Bevington, Christopher; Stowell, Jesse; Costin, Daniel

    2006-09-19

    A wind turbine is provided that minimizes the size of the drive train and nacelle while maintaining the power electronics and transformer at the top of the tower. The turbine includes a direct drive generator having an integrated disk brake positioned radially inside the stator while minimizing the potential for contamination. The turbine further includes a means for mounting a transformer below the nacelle within the tower.

  16. Direct drive wind turbine

    DOE Patents [OSTI]

    Bywaters, Garrett; Danforth, William; Bevington, Christopher; Jesse, Stowell; Costin, Daniel

    2007-02-27

    A wind turbine is provided that minimizes the size of the drive train and nacelle while maintaining the power electronics and transformer at the top of the tower. The turbine includes a direct drive generator having an integrated disk brake positioned radially inside the stator while minimizing the potential for contamination. The turbine further includes a means for mounting a transformer below the nacelle within the tower.

  17. Direct drive wind turbine

    DOE Patents [OSTI]

    Bywaters, Garrett; Danforth, William; Bevington, Christopher; Jesse, Stowell; Costin, Daniel

    2006-10-10

    A wind turbine is provided that minimizes the size of the drive train and nacelle while maintaining the power electronics and transformer at the top of the tower. The turbine includes a direct drive generator having an integrated disk brake positioned radially inside the stator while minimizing the potential for contamination. The turbine further includes a means for mounting a transformer below the nacelle within the tower.

  18. Direct drive wind turbine

    DOE Patents [OSTI]

    Bywaters, Garrett; Danforth, William; Bevington, Christopher; Stowell, Jesse; Costin, Daniel

    2006-07-11

    A wind turbine is provided that minimizes the size of the drive train and nacelle while maintaining the power electronics and transformer at the top of the tower. The turbine includes a direct drive generator having an integrated disk brake positioned radially inside the stator while minimizing the potential for contamination. The turbine further includes a means for mounting a transformer below the nacelle within the tower.

  19. Holiday Gift Drive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gift Drive Holiday Gift Drive Every year, Laboratory employees help fulfill the holiday wishes of children and seniors in our communities. In 2015, our employees donated more than 1,200 gifts to 23 nonprofit organizations to help Northern New Mexico children, senior citizens, and families have a brighter holiday season. May 7, 2015 Every holiday season, employees of Los Alamos National Laboratory donate and distribute gifts to families in need throughout Northern New Mexico. Contacts Annual Food

  20. Synthesis of graphene platelets by chemical and electrochemical route

    SciTech Connect (OSTI)

    Ramachandran, Rajendran; Felix, Sathiyanathan [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Joshi, Girish M. [Materials Physics Division, School of Advanced Sciences, VIT University, Vellore 632014, Tamil Nadu (India); Raghupathy, Bala P.C., E-mail: balapraveen2000@yahoo.com [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Research and Advanced Engineering Division (Materials), Renault Nissan Technology and Business Center India (P) Ltd., Chennai, Tamil Nadu (India); Jeong, Soon Kwan, E-mail: jeongsk@kier.re.kr [Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Grace, Andrews Nirmala, E-mail: anirmalagrace@vit.ac.in [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

    2013-10-15

    Graphical abstract: A schematic showing the overall reduction process of graphite to reduced graphene platelets by chemical and electrochemical route. - Highlights: • Graphene was prepared by diverse routes viz. chemical and electrochemical methods. • NaBH{sub 4} was effective for removing oxygen functional groups from graphene oxide. • Sodium borohydride reduced graphene oxide (SRGO) showed high specific capacitance. • Electrochemical rendered a cheap route for production of graphene in powder form. - Abstract: Graphene platelets were synthesized from graphene oxide by chemical and electrochemical route. Under the chemical method, sodium borohydride and hydrazine chloride were used as reductants to produce graphene. In this paper, a novel and cost effective electrochemical method, which can simplify the process of reduction on a larger scale, is demonstrated. The electrochemical method proposed in this paper produces graphene in powder form with good yield. The atomic force microscopic images confirmed that the graphene samples prepared by all the routes have multilayers of graphene. The electrochemical process provided a new route to make relatively larger area graphene sheets, which will have interest for further patterning applications. Attempt was made to quantify the quantum of reduction using cyclic voltammetry and choronopotentiometry techniques on reduced graphene samples. As a measure in reading the specific capacitance values, a maximum specific capacitance value of 265.3 F/g was obtained in sodium borohydride reduced graphene oxide.

  1. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",426121,"*",5,116,1,"*" ," Electro-Chemical Processes",77146,"--","--","--","--","--...rive",36373,"*","*",4,"*","*" ," Electro-Chemical Processes",159,"--","--","--","--","--" ...

  2. Adjustable Speed Drive Part-Load Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Drive Part-Load Efficiency Adjustable Speed Drive Part-Load Efficiency An adjustable speed drive (ASD) is a device that controls the rotational speed of motor-driven equipment. Variable frequency drives (VFDs), the most common type of ASDs, efficiently meet varying process requirements by adjusting the frequency and voltage of the power supplied to an AC motor to enable it to operate over a wide speed range. External sensors monitor flow, liquid levels, or pressure and then transmit a signal to

  3. In-Situ Electrochemical Transmission Electron Microscopy for Battery Research

    SciTech Connect (OSTI)

    Mehdi, Beata L; Gu, Meng; Parent, Lucas; Xu, WU; Nasybulin, Eduard; Chen, Xilin; Unocic, Raymond R; Xu, Pinghong; Welch, David; Abellan, Patricia; Zhang, Ji-Guang; Liu, Jun; Wang, Chongmin; Arslan, Ilke; Evans, James E; Browning, Nigel

    2014-01-01

    The recent development of in-situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details of electrochemical processes under operando conditions. As electrochemical processes are complex, care must be taken to calibrate the system before any in-situ/operando observations. In addition, as the electron beam can cause effects that look similar to electrochemical processes at the electrolyte/electrode interface, an understanding of the role of the electron beam in modifying the operando observations must also be understood. In this paper we describe the design, assembly, and operation of an in-situ electrochemical cell, paying particular attention to the method for controlling and quantifying the experimental parameters. The use of this system is then demonstrated for the lithiation/delithiation of silicon nanowires.

  4. Table 5.4 End Uses of Fuel Consumption, 2010;

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Machine Drive 1,454 * 28 120 3 1 Electro-Chemical Processes 263 -- -- -- -- -- Other ... * 0 Machine Drive 124 * * 4 * * Electro-Chemical Processes 1 -- -- -- -- -- Other Process ...

  5. Electrochemical flow capacitors

    DOE Patents [OSTI]

    Gogotsi, Yury; Presser, Volker; Kumbar, Emin Caglan

    2015-11-05

    The present invention generally relates to devices for energy storage technologies, and more particularly to electrochemical flow capacitor systems and applications. In some aspects, these flow capacitors have at least one electrode comprising a non-stationary solid or semi-solid composition comprising supercapacitive particles and an electrolytic solvent in electrical communication with at least one current collector, and energy is stored and/or released by charging and/or discharging the electrode(s).

  6. Remote electrochemical sensor

    DOE Patents [OSTI]

    Wang, Joseph; Olsen, Khris; Larson, David

    1997-01-01

    An electrochemical sensor for remote detection, particularly useful for metal contaminants and organic or other compounds. The sensor circumvents technical difficulties that previously prevented in-situ remote operations. The microelectrode, connected to a long communications cable, allows convenient measurements of the element or compound at timed and frequent intervals and instrument/sample distances of ten feet to more than 100 feet. The sensor is useful for both downhole groundwater monitoring and in-situ water (e.g., shipboard seawater) analysis.

  7. Electrochemical flow capacitors

    DOE Patents [OSTI]

    Gogotsi, Yury; Presser, Volker; Kumbur, Emin Caglan

    2015-10-27

    The present invention generally relates to devices for energy storage technologies, and more particularly to electrochemical flow capacitor systems and applications. In some aspects, these flow capacitors have at least one electrode comprising a non-stationary solid or semi-solid composition comprising supercapacitive particles and an electrolytic solvent in electrical communication with at least one current collector, and energy is stored and/or released by charging and/or discharging the electrode(s).

  8. Ceramic vane drive joint

    DOE Patents [OSTI]

    Smale, Charles H.

    1981-01-01

    A variable geometry gas turbine has an array of ceramic composition vanes positioned by an actuating ring coupled through a plurality of circumferentially spaced turbine vane levers to the outer end of a metallic vane drive shaft at each of the ceramic vanes. Each of the ceramic vanes has an end slot of bow tie configuration including flared end segments and a center slot therebetween. Each of the vane drive shafts has a cross head with ends thereof spaced with respect to the sides of the end slot to define clearance for free expansion of the cross head with respect to the vane and the cross head being configured to uniformly distribute drive loads across bearing surfaces of the vane slot.

  9. U.S. DRIVE

    SciTech Connect (OSTI)

    2012-03-16

    U.S. DRIVE, which stands for United States Driving Research and Innovation for Vehicle efficiency and Energy sustainability, is an expanded government-industry partnership among the U.S. Department of Energy; USCAR, representing Chrysler Group LLC, Ford Motor Company and General Motors; Tesla Motors; five energy companies – BP America, Chevron Corporation, ConocoPhillips, ExxonMobil Corporation, and Shell Oil Products US; two utilities – Southern California Edison and Michigan-based DTE Energy; and the Electric Power Research Institute (EPRI). The U.S. DRIVE mission is to accelerate the development of pre-competitive and innovative technologies to enable a full range of affordable and clean advanced light-duty vehicles, as well as related energy infrastructure.

  10. CONTROL ROD DRIVE

    DOE Patents [OSTI]

    Chapellier, R.A.; Rogers, I.

    1961-06-27

    Accurate and controlled drive for the control rod is from an electric motor. A hydraulic arrangement is provided to balance a piston against which a control rod is urged by the application of fluid pressure. The electric motor drive of the control rod for normal operation is made through the aforementioned piston. In the event scramming is required, the fluid pressure urging the control rod against the piston is relieved and an opposite fluid pressure is applied. The lack of mechanical connection between the electric motor and control rod facilitates the scramming operation.

  11. Borup wins Electrochemical Society Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borup wins Electrochemical Society Award Borup wins Electrochemical Society Award Rod Borup has won the 2015 Research Award presented annually by the Energy Technology Division of the Electrochemical Society. January 26, 2015 Rod Borup Rod Borup Borup and his team are focused on improving the polymer electrolyte membrane (PEM) fuel cell, which converts hydrogen to electricity for power, but emits only water. Rod Borup of Materials Synthesis and Integrated Devices (MPA-11) has won the 2015

  12. Process Development and Basic Studies of Electrochemically Deposited CdTe-Based Solar Cells: Final Technical Report, 15 May 1998 - 17 August 2001

    SciTech Connect (OSTI)

    Kaydanov, V. I.; Ohno, T. R.

    2002-03-01

    This report describes the long-term research and development issues related to polycrystalline thin-film solar cells. Our general research approach is based on combining activities aimed at improvement of cell performance and stability with activities aimed at increasing our fundamental understanding of the properties of materials making up the cells: CdTe, CdS, multi-layer back-contact, and transparent conducting oxide (TCO) front-contact. We emphasize the relation between structural and electronic material properties and various processing procedures, as well as the microscopic mechanisms responsible for the cell performance and its degradation. There is a lack of knowledge and understanding of basic issues behind the CdTe/CdS cell performance and stability, such as the nature and electronic properties of impurities and defects that control the majority-carrier concentration, mechanisms of the dopant compensation, recombination centers, their nature and properties, diffusion, electro migration and transformation of defects under various processing, stress, and operating conditions. We believe that better basic understanding of the specific influence of polycrystallinity, especially for fine-grain materials characteristic of CdTe-based cells, is now one of the most important issues we must address. We need to clarify the role of grain boundaries in forming the film electronic properties, as well as those of the p-n junction. It is important to study and understand the influence of the grain boundaries on the spatial distribution and migration of impurities and electrically active defects. To fulfill these tasks, one needs to develop new methods and techniques (or adjust existing ones) for material characterization, as well as develop more sophisticated approaches to data analysis and modeling.

  13. ELECTROCHEMICAL DECONTAMINATION AND RECOVERY OF URANIUM VALUES

    DOE Patents [OSTI]

    McLaren, J.A.; Goode, J.H.

    1958-05-13

    An electrochemical process is described for separating uranium from fission products. The method comprises subjecting the mass of uranium to anodic dissolution in an electrolytic cell containing aqueous alkali bicarbonate solution as its electrolyte, thereby promoting a settling from the solution of a solid sludge from about the electrodes and separating the resulting electrolyte solution containing the anodically dissolved uranium from the sludge which contains the rare earth fission products.

  14. Electrochemical cell method

    DOE Patents [OSTI]

    Kaun, T.D.; Eshman, P.F.

    1980-05-09

    A secondary electrochemical cell is prepared by providing positive and negative electrodes having outer enclosures of rigid perforated electrically conductive material defining an internal compartment containing the electrode material in porous solid form. The electrodes are each immersed in molten electrolyte salt prior to cell assembly to incorporate the cell electrolyte. Following solidification of the electrolyte substantially throughout the porous volume of the electrode material, the electrodes are arranged in an alternating positive-negative array with interelectrode separators of porous frangible electrically insulative material. The completed array is assembled into the cell housing and sealed such that on heating the solidified electrolyte flows into the interelectrode separator.

  15. Remote electrochemical sensor

    DOE Patents [OSTI]

    Wang, J.; Olsen, K.; Larson, D.

    1997-10-14

    An electrochemical sensor is described for remote detection, particularly useful for metal contaminants and organic or other compounds. The sensor circumvents technical difficulties that previously prevented in-situ remote operations. The microelectrode, connected to a long communications cable, allows convenient measurements of the element or compound at timed and frequent intervals and instrument/sample distances of ten feet to more than 100 feet. The sensor is useful for both downhole groundwater monitoring and in-situ water (e.g., shipboard seawater) analysis. 21 figs.

  16. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, John W.

    1994-01-01

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR).

  17. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, J.W.

    1994-01-11

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR). 14 figures.

  18. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  19. Table 5.5 End Uses of Fuel Consumption, 2010;

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Drive -- 347,224 * 5 116 1 * -- Electro-Chemical Processes -- 55,414 -- -- -- -- -- -- ... Drive -- 33,354 * * 5 * 0 -- Electro-Chemical Processes -- 5,538 -- -- -- -- -- -- ...

  20. Table 5.6 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive -- 1,185 * 28 120 3 1 -- Electro-Chemical Processes -- 189 -- -- -- -- -- -- Other ... Drive -- 114 * 2 5 * 0 -- Electro-Chemical Processes -- 19 -- -- -- -- -- -- Other ...

  1. Table 5.1 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive -- 347,224 * 5 116 1 * -- Electro-Chemical Processes -- 55,414 -- -- -- -- -- -- ... Drive -- 32,764 * * 4 * * -- Electro-Chemical Processes -- 158 -- -- -- -- -- -- Other ...

  2. Table 5.3 End Uses of Fuel Consumption, 2010;

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Drive 426,121 * 5 116 1 * Electro-Chemical Processes 77,146 -- -- -- -- -- Other ... 0 Machine Drive 36,373 * * 4 * * Electro-Chemical Processes 159 -- -- -- -- -- Other ...

  3. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1731,2,24,129,2,56 ," Electro-Chemical Processes",255,"--","--","--","--","--" ... Drive",121,"*",3,11,"*",0 ," Electro-Chemical Processes","*","--","--","--","--","--" ...

  4. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",507223,"*",4,126,"*",3 ," Electro-Chemical Processes",74825,"--","--","--","--","--... Drive",35339,"*","*",10,"*",0 ," Electro-Chemical Processes",113,"--","--","--","--","--" ...

  5. Table 5.8 End Uses of Fuel Consumption, 2010;

    Gasoline and Diesel Fuel Update (EIA)

    Machine Drive 1,454 * 28 120 3 1 Electro-Chemical Processes 263 -- -- -- -- -- Other ... * 0 Machine Drive 139 * 2 5 * 0 Electro-Chemical Processes 19 -- -- -- -- -- Other ...

  6. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1454,"*",28,120,3,1 ," Electro-Chemical Processes",263,"--","--","--","--","--" ... Drive",124,"*","*",4,"*","*" ," Electro-Chemical Processes",1,"--","--","--","--","--" ," ...

  7. " Row: End Uses;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1454,"*",28,120,3,1 " Electro-Chemical Processes",263,"--","--","--","--","--" ... Drive",139,"*",2,5,"*",0 " Electro-Chemical Processes",19,"--","--","--","--","--" " ...

  8. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1746,2,16,109,4,5,4.8 ," Electro-Chemical Processes",295,"--","--","--","--","--",... Drive",124,0,3,13,"*",0,11 ," Electro-Chemical Processes","*","--","--","--","--","--",...

  9. " Row: End Uses;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",507223,"*",4,126,"*",3 " Electro-Chemical Processes",74825,"--","--","--","--","--... Drive",46977,"*",1,5,"*",0 " Electro-Chemical Processes",6569,"--","--","--","--","--" ...

  10. " Row: End Uses;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1731,2,24,129,2,56 " Electro-Chemical Processes",255,"--","--","--","--","--" ... Drive",160,"*",6,5,"*",0 " Electro-Chemical Processes",22,"--","--","--","--","--" " ...

  11. Table 5.2 End Uses of Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive -- 1,185 * 28 120 3 1 -- Electro-Chemical Processes -- 189 -- -- -- -- -- -- Other ... Drive -- 112 * * 4 * * -- Electro-Chemical Processes -- 1 -- -- -- -- -- -- Other ...

  12. " Row: End Uses;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",426121,"*",5,116,1,"*" " Electro-Chemical Processes",77146,"--","--","--","--","--... Drive",40701,"*","*",5,"*",0 " Electro-Chemical Processes",5597,"--","--","--","--","--" ...

  13. Electrochemical sensor for monitoring electrochemical potentials of fuel cell components

    DOE Patents [OSTI]

    Kunz, Harold R.; Breault, Richard D.

    1993-01-01

    An electrochemical sensor comprised of wires, a sheath, and a conduit can be utilized to monitor fuel cell component electric potentials during fuel cell shut down or steady state. The electrochemical sensor contacts an electrolyte reservoir plate such that the conduit wicks electrolyte through capillary action to the wires to provide water necessary for the electrolysis reaction which occurs thereon. A voltage is applied across the wires of the electrochemical sensor until hydrogen evolution occurs at the surface of one of the wires, thereby forming a hydrogen reference electrode. The voltage of the fuel cell component is then determined with relation to the hydrogen reference electrode.

  14. Drive Diagnostic Filter Wheel Control

    Energy Science and Technology Software Center (OSTI)

    2007-07-17

    DrD Filter Wheel Control is National Instrument's Labview software that drives a Drive Diagnostic filter wheel. The software can drive the filter wheel between each end limit, detect the positive and negative limit and each home position and post the stepper motot values to an Excel spreadsheet. The software can also be used to cycle the assembly between the end limits.

  15. Refractory lining for electrochemical cell

    DOE Patents [OSTI]

    Blander, Milton; Cook, Glenn M.

    1987-01-01

    Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contcat with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  16. Electrochemical catalyst recovery method

    DOE Patents [OSTI]

    Silva, Laura J.; Bray, Lane A.

    1995-01-01

    A method of recovering catalyst material from latent catalyst material solids includes: a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications.

  17. Electrochemical catalyst recovery method

    DOE Patents [OSTI]

    Silva, L.J.; Bray, L.A.

    1995-05-30

    A method of recovering catalyst material from latent catalyst material solids includes: (a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; (b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; (c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and (d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications. 3 figs.

  18. Electrochemical cell design

    DOE Patents [OSTI]

    Arntzen, John D.

    1978-01-01

    An electrochemical cell includes two outer electrodes and a central electrode of opposite polarity, all nested within a housing having two symmetrical halves which together form an offset configuration. The outer electrodes are nested within raised portions within the side walls of each housing half while the central electrode sealingly engages the perimetric margins of the side-wall internal surfaces. Suitable interelectrode separators and electrical insulating material electrically isolate the central electrode from the housing and the outer electrodes. The outer electrodes are electrically connected to the internal surfaces of the cell housing to provide current collection. The nested structure minimizes void volume that would otherwise be filled with gas or heavy electrolyte and also provides perimetric edge surfaces for sealing and supporting at the outer margins of frangible interelectrode separator layers.

  19. Base drive circuit

    DOE Patents [OSTI]

    Lange, A.C.

    1995-04-04

    An improved base drive circuit having a level shifter for providing bistable input signals to a pair of non-linear delays. The non-linear delays provide gate control to a corresponding pair of field effect transistors through a corresponding pair of buffer components. The non-linear delays provide delayed turn-on for each of the field effect transistors while an associated pair of transistors shunt the non-linear delays during turn-off of the associated field effect transistor. 2 figures.

  20. Base drive circuit

    DOE Patents [OSTI]

    Lange, Arnold C.

    1995-01-01

    An improved base drive circuit (10) having a level shifter (24) for providing bistable input signals to a pair of non-linear delays (30, 32). The non-linear delays (30, 32) provide gate control to a corresponding pair of field effect transistors (100, 106) through a corresponding pair of buffer components (88, 94). The non-linear delays (30, 32) provide delayed turn-on for each of the field effect transistors (100, 106) while an associated pair of transistors (72, 80) shunt the non-linear delays (30, 32) during turn-off of the associated field effect transistor (100, 106).

  1. CTO Speaks to Government's Role in Driving Innovation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy CTO Speaks to Government's Role in Driving Innovation CTO Speaks to Government's Role in Driving Innovation December 4, 2014 - 3:13pm Addthis Robert G. Green Robert G. Green Principal Deputy CIO for Enterprise Information Resources Management | Deputy CIO for Architecture Engineering, Technology & Innovation (Acting) Last week, I provided an opening keynote at the Management of Government Technology Annual Summit entitled, Driving Government Innovation: Process and Technology to

  2. Development of Radically Enhanced alnico Magnets (DREAM) for Traction Drive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Motors | The Ames Laboratory Development of Radically Enhanced alnico Magnets (DREAM) for Traction Drive Motors Research Personnel Publications Synthesis In order to enable domestic automobile makers to offer a broad range of vehicles with electric drive motors with either hybrid or purely electric motor drives, this project will utilize a demonstrated science-based process to design and synthesize a high energy product permanent magnet of the alnico type in bulk final shapes without rare

  3. Renewable-reagent electrochemical sensor

    DOE Patents [OSTI]

    Wang, J.; Olsen, K.B.

    1999-08-24

    A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery is described. The probe comprises an integrated membrane sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s). 19 figs.

  4. Renewable-reagent electrochemical sensor

    DOE Patents [OSTI]

    Wang, Joseph; Olsen, Khris B.

    1999-01-01

    A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery. The probe comprises an integrated membrane-sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s).

  5. Electrochemically Modulated Separation for Plutonium Safeguards

    SciTech Connect (OSTI)

    Pratt, Sandra H.; Breshears, Andrew T.; Arrigo, Leah M.; Schwantes, Jon M.; Duckworth, Douglas C.

    2013-12-31

    Accurate and timely analysis of plutonium in spent nuclear fuel is critical in nuclear safeguards for detection of both protracted and rapid plutonium diversions. Gamma spectroscopy is a viable method for accurate and timely measurements of plutonium provided that the plutonium is well separated from the interfering fission and activation products present in spent nuclear fuel. Electrochemically modulated separation (EMS) is a method that has been used successfully to isolate picogram amounts of Pu from nitric acid matrices. With EMS, Pu adsorption may be turned "on" and "off" depending on the applied voltage, allowing for collection and stripping of Pu without the addition of chemical reagents. In this work, we have scaled up the EMS process to isolate microgram quantities of Pu from matrices encountered in spent nuclear fuel during reprocessing. Several challenges have been addressed including surface area limitations, radiolysis effects, electrochemical cell performance stability, and chemical interferences. After these challenges were resolved, 6 ”g Pu was deposited in the electrochemical cell with approximately an 800-fold reduction of fission and activation product levels from a spent nuclear fuel sample. Modeling showed that these levels of Pu collection and interference reduction may not be sufficient for Pu detection by gamma spectroscopy. The main remaining challenges are to achieve a more complete Pu isolation and to deposit larger quantities of Pu for successful gamma analysis of Pu. If gamma analyses of Pu are successful, EMS will allow for accurate and timely on-site analysis for enhanced Pu safeguards.

  6. Borup wins Electrochemical Society Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borup wins Electrochemical Society Award January 26, 2015 Rod Borup of Materials Synthesis and Integrated Devices (MPA-11) has won the 2015 Research Award presented annually by the Energy Technology Division of the Electrochemical Society (ECS). The society recognized him for "his seminal contributions to the fundamental understanding of the durability of polymer electrolyte fuel cells." Borup's achievements Borup and his team are focused on improving the polymer electrolyte membrane

  7. Supported liquid membrane electrochemical separators

    DOE Patents [OSTI]

    Pemsler, J. Paul; Dempsey, Michael D.

    1986-01-01

    Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

  8. Rotary drive mechanism

    DOE Patents [OSTI]

    Kenderdine, Eugene W. (Albuquerque, NM)

    1991-01-01

    A rotary drive mechanism includes a rotary solenoid having a stator and multi-poled rotor. A moving member rotates with the rotor and is biased by a biasing device. The biasing device causes a further rotational movement after rotation by the rotary solenoid. Thus, energization of the rotary solenoid moves the member in one direction to one position and biases the biasing device against the member. Subsequently, de-energization of the rotary solenoid causes the biasing device to move the member in the same direction to another position from where the moving member is again movable by energization and de-energization of the rotary solenoid. Preferably, the moving member is a multi-lobed cam having the same number of lobes as the rotor has poles. An anti-overdrive device is also preferably provided for preventing overdrive in the forward direction or a reverse rotation of the moving member and for precisely aligning the moving member.

  9. Rotary drive mechanism

    SciTech Connect (OSTI)

    Kenderdine, E.W.

    1991-10-08

    This patent describes a rotary drive mechanism which includes a rotary solenoid having a stator and multi-poled rotor. A moving member rotates with the rotor and is biased by a biasing device. The biasing device causes a further rotational movement after rotation by the rotary solenoid. Thus, energization of the rotary solenoid moves the member in one direction to one position and biases the biasing device against the member. Subsequently, de- energization of the rotary solenoid causes the biasing device to move the member in the same direction to another position from where the moving member is again movable by energization and de-energization of the rotary solenoid. Preferably, the moving member is a multi-lobed cam having the same number of lobes as the rotor has poles. An anti- overdrive device is also preferably provided for preventing overdrive in the forward direction or a reverse rotation of the moving member and for precisely aligning the moving member.

  10. Electrochemical polishing of notches

    DOE Patents [OSTI]

    Kephart, A.R.; Alberts, A.H.

    1989-02-21

    An apparatus and method are disclosed for the selective electrochemical polishing of a lateral tip of a deep longitudinal notch in a work piece used to test crack initiation properties of materials. A DC power source is connected to the work piece and to an electrode disposed laterally along the distal end of an insulated body which is inserted in the longitudinal notch. The electrode and distal end of the body are disposed along the tip of the notch, but are spaced from the notch so as to provide a lateral passage for an electrolyte. The electrolyte is circulated through the passage so that the electrolyte only contacts the work piece adjacent the passage. Conveniently, the electrolyte is circulated by use of an inlet tube and an outlet tube provided at opposite ends of the passage. These tubes are preferably detachably located adjacent the ends of the passage and suitable seals are provided. A holding device including arms to which the tubes are attached is conveniently used to rapidly and easily locate the test specimen with the passage aligned with the tubes. The electrode is preferably a wire which is located in grooves along the distal end of the insulated body and up one side of the body or a plastic sheath insulated thin metal strip. 4 figs.

  11. Electrochemical polishing of notches

    DOE Patents [OSTI]

    Kephart, Alan R.; Alberts, Alfred H.

    1989-01-01

    An apparatus and method are disclosed for the selective electrochemical polishing of a lateral tip of a deep longitudinal notch in a work piece used to test crack initiation properties of materials. A DC power source is connected to the work piece and to an electrode disposed laterally along the distal end of an insulated body which is inserted in the longitudinal notch. The electrode and distal end of the body are disposed along the tip of the notch, but are spaced from the notch so as to provide a lateral passage for an electrolyte. The electrolyte is circulated through the passage so that the electrolyte only contacts the work piece adjacent the passage. Conveniently, the electrolyte is circulated by use of an inlet tube and an outlet tube provided at opposite ends of the passage. These tubes are preferably detachably located adjacent the ends of the passage and suitable seals are provided. A holding device including arms to which the tubes are attached is conveniently used to rapidly and easily locate the test specimen with the passage aligned with the tubes. The electrode is preferably a wire which is located in grooves along the distal end of the insulated body and up one side of the body or a plastic sheath insulated thin metal strip.

  12. Designing Effective Incentives to Drive Residential Retrofit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Incentives to Drive Residential Retrofit Program Participation Designing Effective Incentives to Drive Residential Retrofit Program Participation This webinar covered retrofit ...

  13. Next Generation Environmentally Friendly Driving Feedback Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmentally Friendly Driving Feedback Systems Research and Development Next Generation Environmentally Friendly Driving Feedback Systems Research and Development 2012 DOE ...

  14. Sequenced drive for rotary valves

    DOE Patents [OSTI]

    Mittell, Larry C. (Palos Verdes Estates, CA)

    1981-01-01

    A sequenced drive for rotary valves which provides the benefits of applying rotary and linear motions to the movable sealing element of the valve. The sequenced drive provides a close approximation of linear motion while engaging or disengaging the movable element with the seat minimizing wear and damage due to scrubbing action. The rotary motion of the drive swings the movable element out of the flowpath thus eliminating obstruction to flow through the valve.

  15. Driving Skyrmions Along a Racetrack

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Driving Skyrmions Along a Racetrack Driving Skyrmions Along a Racetrack Print Thursday, 14 April 2016 13:41 In a conventional disk drive, data is stored in stationary magnetic domains on a mechanically spinning disk. In a solid-state version of this called "racetrack memory," researchers envision that it's the magnetic domains that would move through a stationary wire (the racetrack), driven by a small electric current. Ideally, such a system would offer higher performance and higher

  16. Distribution Drive | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Distribution Drive Place: Dallas, Texas Zip: 75205 Product: Biodiesel fuel distributor. Coordinates: 32.778155, -96.795404 Show Map Loading map......

  17. Traction Drive Systems Breakout Group

    Broader source: Energy.gov (indexed) [DOE]

    TRACTION DRIVE SYSTEM BREAKOUT GROUP EV Everywhere Workshop July 24, 2012 Breakout Session 1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the...

  18. Test Drive: Honda FCX Clarity

    Broader source: Energy.gov [DOE]

    A member of the Energy Empowers team takes the Honda FCX Clarity for a drive outside the U.S. Department of Energy in Washington, D.C.

  19. Vehicle Technologies Office: US DRIVE Partnership Plan, Roadmaps...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion and Emission Control Technical Team Roadmap Electrical and Electronics: Electrical and Electronics Technical Team Roadmap Electrochemical Energy Storage: Electrochemical ...

  20. Coating Active Materials for Applications in Electrochemical Devices |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Coating Active Materials for Applications in Electrochemical Devices Technology available for licensing: A process that includes suspending/dissolving an electro-active material and a carbon precursor in a solvent; and then depositing the carbon precursor on the electro-active material to form a carbon-coated electro-active material Process reduces manufacturing cost Coating process produces carbon-coated metal oxides without the problems associated with

  1. ElectroChemical Noise Data Acquistion and Interpretation

    Energy Science and Technology Software Center (OSTI)

    2000-01-14

    This software is part of an effort to develop an effective measurement method, using electrochemical noise techniques, to differentiate localized pitting corrosion from general uniform corrosion. It is designed to obtain the electrochemical noise signal from in-situ electrochemical probes in a pipeline and convert the signal from a time-domain to a frequency domain by using a Fourier transform. The converted signal, named "power spectral density'', is then further used to calculate the value of characteristicmore » parameters which describe the mechanism and progress of a corrosion process. The results obtained from this software enable one to differentiate localized pitting corrosion from general uniform corrosion attack in a utility pipeline.« less

  2. Evaluation Of Electrochemical Machining Technology For Surface...

    Office of Scientific and Technical Information (OSTI)

    Evaluation Of Electrochemical Machining Technology For Surface Improvements In Additive Manufactured Components ... ORNL Manufacturing Demonstration Facility worked with ECM ...

  3. Magnetic compression laser driving circuit

    DOE Patents [OSTI]

    Ball, Don G. (Livermore, CA); Birx, Dan (Brentwood, CA); Cook, Edward G. (Livermore, CA)

    1993-01-01

    A magnetic compression laser driving circuit is disclosed. The magnetic compression laser driving circuit compresses voltage pulses in the range of 1.5 microseconds at 20 Kilovolts of amplitude to pulses in the range of 40 nanoseconds and 60 Kilovolts of amplitude. The magnetic compression laser driving circuit includes a multi-stage magnetic switch where the last stage includes a switch having at least two turns which has larger saturated inductance with less core material so that the efficiency of the circuit and hence the laser is increased.

  4. Magnetic compression laser driving circuit

    DOE Patents [OSTI]

    Ball, D.G.; Birx, D.; Cook, E.G.

    1993-01-05

    A magnetic compression laser driving circuit is disclosed. The magnetic compression laser driving circuit compresses voltage pulses in the range of 1.5 microseconds at 20 kilovolts of amplitude to pulses in the range of 40 nanoseconds and 60 kilovolts of amplitude. The magnetic compression laser driving circuit includes a multi-stage magnetic switch where the last stage includes a switch having at least two turns which has larger saturated inductance with less core material so that the efficiency of the circuit and hence the laser is increased.

  5. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, W.R.; Storz, L.J.

    1991-03-26

    An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  6. Sheet electrode for electrochemical systems

    DOE Patents [OSTI]

    Tsien, Hsue C.; Newby, Kenneth R.; Grimes, Patrick G.; Bellows, Richard J.

    1983-04-12

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  7. Electrochemical cell with calcium anode

    DOE Patents [OSTI]

    Cooper, John F.; Hosmer, Pamela K.; Kelly, Benjamin E.

    1979-01-01

    An electrochemical cell comprising a calcium anode and a suitable cathode in an alkaline electrolyte consisting essentially of an aqueous solution of an hydroxide and a chloride. Specifically disclosed is a mechanically rechargeable calcium/air fuel cell with an aqueous NaOH/NaCl electrolyte.

  8. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, Wendy R.; Storz, Leonard J.

    1991-01-01

    An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  9. Upgrading coal plant damper drives

    SciTech Connect (OSTI)

    Hood, N.R.; Simmons, K. [Alamaba Power (United States)

    2009-11-15

    The replacement of damper drives on two coal-fired units at the James H. Miller Jr. electric generating plant by Intelligent Contrac electric rotary actuators is discussed. 2 figs.

  10. Mechanical drive for blood pump

    DOE Patents [OSTI]

    Bifano, N.J.; Pouchot, W.D.

    1975-07-29

    This patent relates to a highly efficient blood pump to be used as a replacement for a ventricle of the human heart to restore people disabled by heart disease. The mechanical drive of the present invention is designed to operate in conjunction with a thermoelectric converter power source. The mechanical drive system essentially converts the output of a rotary power into pulsatile motion so that the power demand from the thermoelectric converter remains essentially constant while the blood pump output is pulsed. (auth)

  11. ARM - SGP Rural Driving Hazards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rural Driving Hazards SGP Related Links Virtual Tour Facilities and Instruments Central Facility Boundary Facility Extended Facility Intermediate Facility Radiometric Calibration Facility Geographic Information ES&H Guidance Statement Operations Science Field Campaigns Visiting the Site Summer Training SGP Fact Sheet Images Information for Guest Scientists Contacts SGP Rural Driving Hazards The rural location of the Southern Great Plains (SGP) site facilities requires that visitors travel on

  12. Direct drive field actuator motors

    DOE Patents [OSTI]

    Grahn, Allen R.

    1998-01-01

    A positive-drive field actuator motor including a stator carrying at least one field actuator which changes in dimension responsive to application of an energy field, and at least one drive shoe movable by the dimensional changes of the field actuator to contact and move a rotor element with respect to the stator. Various embodiments of the motor are disclosed, and the rotor element may be moved linearly or arcuately.

  13. Direct drive field actuator motors

    DOE Patents [OSTI]

    Grahn, A.R.

    1998-03-10

    A positive-drive field actuator motor is described which includes a stator carrying at least one field actuator which changes in dimension responsive to application of an energy field, and at least one drive shoe movable by the dimensional changes of the field actuator to contact and move a rotor element with respect to the stator. Various embodiments of the motor are disclosed, and the rotor element may be moved linearly or arcuately. 62 figs.

  14. Low backlash direct drive actuator

    DOE Patents [OSTI]

    Kuklo, Thomas C. (Oakland, CA)

    1994-01-01

    A low backlash direct drive actuator is described which comprises a motor such as a stepper motor having at least 200 steps per revolution; a two part hub assembly comprising a drive hub coaxially attached to the shaft of the motor and having a plurality of drive pins; a driven hub having a plurality of bores in one end thereof in alignment with the drive pins in the drive hub and a threaded shaft coaxially mounted in an opposite end of the driven hub; and a housing having a central bore therein into which are fitted the drive hub and driven hub, the housing having a motor mount on one end thereof to which is mounted the stepper motor, and a closed end portion with a threaded opening therein coaxial with the central bore in the housing and receiving therein the threaded shaft attached to the driven hub. Limit switches mounted to the housing cooperate with an enlarged lip on the driven hub to limit the lateral travel of the driven hub in the housing, which also acts to limit the lateral travel of the threaded shaft which functions as a lead screw.

  15. Low backlash direct drive actuator

    DOE Patents [OSTI]

    Kuklo, T.C.

    1994-10-25

    A low backlash direct drive actuator is described which comprises a motor such as a stepper motor having at least 200 steps per revolution; a two part hub assembly comprising a drive hub coaxially attached to the shaft of the motor and having a plurality of drive pins; a driven hub having a plurality of bores in one end thereof in alignment with the drive pins in the drive hub and a threaded shaft coaxially mounted in an opposite end of the driven hub; and a housing having a central bore therein into which are fitted the drive hub and driven hub, the housing having a motor mount on one end thereof to which is mounted the stepper motor, and a closed end portion with a threaded opening therein coaxial with the central bore in the housing and receiving therein the threaded shaft attached to the driven hub. Limit switches mounted to the housing cooperate with an enlarged lip on the driven hub to limit the lateral travel of the driven hub in the housing, which also acts to limit the lateral travel of the threaded shaft which functions as a lead screw. 10 figs.

  16. Driving Green com | Open Energy Information

    Open Energy Info (EERE)

    Driving Green com Jump to: navigation, search Name: Driving Green.com Place: Melbourne, Florida Zip: 32904 Sector: Vehicles Product: Driving green.com is a website that allows...

  17. Kelvin Probe Force Microscopy in liquid using Electrochemical Force Microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collins, Liam; Jesse, Stephen; Kilpatrick, J.; Tselev, Alexander; Okatan, Mahmut Baris; Kalinin, Sergei V.; Rodriguez, Brian

    2015-01-01

    Conventional closed loop-Kelvin probe force microscopy (KPFM) has emerged as a powerful technique for probing electric and transport phenomena at the solid-gas interface. The extension of KPFM capabilities to probe electrostatic and electrochemical phenomena at the solid–liquid interface is of interest for a broad range of applications from energy storage to biological systems. However, the operation of KPFM implicitly relies on the presence of a linear lossless dielectric in the probe-sample gap, a condition which is violated for ionically-active liquids (e.g., when diffuse charge dynamics are present). Here, electrostatic and electrochemical measurements are demonstrated in ionically-active (polar isopropanol, milli-Q watermore » and aqueous NaCl) and ionically-inactive (non-polar decane) liquids by electrochemical force microscopy (EcFM), a multidimensional (i.e., bias- and time-resolved) spectroscopy method. In the absence of mobile charges (ambient and non-polar liquids), KPFM and EcFM are both feasible, yielding comparable contact potential difference (CPD) values. In ionically-active liquids, KPFM is not possible and EcFM can be used to measure the dynamic CPD and a rich spectrum of information pertaining to charge screening, ion diffusion, and electrochemical processes (e.g., Faradaic reactions). EcFM measurements conducted in isopropanol and milli-Q water over Au and highly ordered pyrolytic graphite electrodes demonstrate both sample- and solvent-dependent features. Finally, the feasibility of using EcFM as a local force-based mapping technique of material-dependent electrostatic and electrochemical response is investigated. The resultant high dimensional dataset is visualized using a purely statistical approach that does not require a priori physical models, allowing for qualitative mapping of electrostatic and electrochemical material properties at the solid–liquid interface.« less

  18. Kelvin Probe Force Microscopy in liquid using Electrochemical Force Microscopy

    SciTech Connect (OSTI)

    Collins, Liam; Jesse, Stephen; Kilpatrick, J.; Tselev, Alexander; Okatan, Mahmut Baris; Kalinin, Sergei V.; Rodriguez, Brian

    2015-01-01

    Conventional closed loop-Kelvin probe force microscopy (KPFM) has emerged as a powerful technique for probing electric and transport phenomena at the solid-gas interface. The extension of KPFM capabilities to probe electrostatic and electrochemical phenomena at the solid–liquid interface is of interest for a broad range of applications from energy storage to biological systems. However, the operation of KPFM implicitly relies on the presence of a linear lossless dielectric in the probe-sample gap, a condition which is violated for ionically-active liquids (e.g., when diffuse charge dynamics are present). Here, electrostatic and electrochemical measurements are demonstrated in ionically-active (polar isopropanol, milli-Q water and aqueous NaCl) and ionically-inactive (non-polar decane) liquids by electrochemical force microscopy (EcFM), a multidimensional (i.e., bias- and time-resolved) spectroscopy method. In the absence of mobile charges (ambient and non-polar liquids), KPFM and EcFM are both feasible, yielding comparable contact potential difference (CPD) values. In ionically-active liquids, KPFM is not possible and EcFM can be used to measure the dynamic CPD and a rich spectrum of information pertaining to charge screening, ion diffusion, and electrochemical processes (e.g., Faradaic reactions). EcFM measurements conducted in isopropanol and milli-Q water over Au and highly ordered pyrolytic graphite electrodes demonstrate both sample- and solvent-dependent features. Finally, the feasibility of using EcFM as a local force-based mapping technique of material-dependent electrostatic and electrochemical response is investigated. The resultant high dimensional dataset is visualized using a purely statistical approach that does not require a priori physical models, allowing for qualitative mapping of electrostatic and electrochemical material properties at the solid–liquid interface.

  19. EFFECTS OF GAMMA RADIATION ON ELECTROCHEMICAL PROPERTIES OF IONIC LIQUIDS

    SciTech Connect (OSTI)

    Visser, A; Nicholas Bridges, N; Thad Adams, T; John Mickalonis, J; Mark02 Williamson, M

    2009-04-21

    The electrochemical properties of ionic liquids (ILs) make them attractive for possible replacement of inorganic salts in high temperature molten salt electrochemical processing of nuclear fuel. To be a feasible replacement solvent, ILs need to be stable in moderate and high doses of radiation without adverse chemical and physical effects. Here, we exposed seven different ILs to a 1.2 MGy dose of gamma radiation to investigate their physical and chemical properties as they related to radiological stability. The azolium-based ILs experienced the greatest change in appearance, but these ILs were chemically more stable to gamma radiation than some of the other classes of ILs tested, due to the presence of aromatic electrons in the azolium ring. All the ILs exhibited a decrease in their conductivity and electrochemical window (at least 1.1 V), both of which could affect the utility of ILs in electrochemical processing. The concentration of the irradiation decomposition products was less than 3 mole %, with no impurities detectable using NMR techniques.

  20. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January ...

  1. Driving Accountability for Program Performance Using Measured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Driving Accountability for Program Performance Using Measured Energy Savings (201) Driving Accountability for Program Performance Using Measured Energy Savings (201) Better ...

  2. Marketing & Driving Demand Collaborative - Social Media Tools...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Marketing & Driving Demand Collaborative - Social Media Tools & Strategies Presentation slides from the Better Buildings webinar on January 6, 2011. PDF icon Marketing & Driving ...

  3. Cone Drive Operations Inc | Open Energy Information

    Open Energy Info (EERE)

    enveloping worm gear technology. The company supplies azimuth and elevation drives for solar tracking applications. References: Cone Drive Operations Inc1 This article is a...

  4. Marketing & Driving Demand: Social Media Tools & Strategies ...

    Office of Environmental Management (EM)

    Marketing & Driving Demand: Social Media Tools & Strategies - January 16, 2011 (Text Version) Marketing & Driving Demand: Social Media Tools & Strategies - January 16, 2011 (Text...

  5. Manganese Reduction-Oxidation Drives Plant Debris Decomposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Reduction-Oxidation Drives Plant Debris Decomposition Manganese Reduction-Oxidation Drives Plant Debris Decomposition Print Monday, 22 February 2016 00:00 Microbial decomposition of plant debris ("litter") is a keystone ecosystem process because it regulates nutrient availability, ecosystem productivity, and carbon (C) cycling. Historically, climate (primarily temperature and precipitation) has been thought to regulate the rate of litter decomposition, which then influences

  6. Electrochemical synthesis of multisegmented nanowires

    SciTech Connect (OSTI)

    Kok, Kuan-Ying; Ng, Inn-Khuan; Saidin, Nur Ubaidah

    2012-11-27

    Electrochemical deposition has emerged as a promising route for nanostructure fabrication in recent years due to the many inherent advantages it possesses. This study focuses on the synthesis of high-aspect-ratio multisegmented Au/Ni nanowires using template-directed sequential electrochemical deposition techniques. By selectively removing the Ni segments in the nanowires, high-yield of pure gold nanorods of predetermined lengths was obtained. Alternatively, the sacrificial Ni segments in the nanowires can be galvanically displaced with Bi and Te to form barbells structures with Bi{sub x}Te{sub y} nanotubes attached to neighbouring gold segments. Detailed studies on the nanostructures obtained were carried out using various microscopy, diffraction and probebased techniques for structural, morphological and chemical characterizations.

  7. U.S. Army Corps of Engineers and FEMP Partner to Drive Down Federal Energy Costs

    Broader source: Energy.gov [DOE]

    The USACE and FEMP developed a partnership to help drive down the federal government's energy costs through the government-wide adoption of performance contracting processes.

  8. Solid state electrochemical current source

    DOE Patents [OSTI]

    Potanin, Alexander Arkadyevich; Vedeneev, Nikolai Ivanovich

    2002-04-30

    A cathode and a solid state electrochemical cell comprising said cathode, a solid anode and solid fluoride ion conducting electrolyte. The cathode comprises a metal oxide and a compound fluoride containing at least two metals with different valences. Representative compound fluorides include solid solutions of bismuth fluoride and potassium fluoride; and lead fluoride and potassium fluoride. Representative metal oxides include copper oxide, lead oxide, manganese oxide, vanadium oxide and silver oxide.

  9. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, Ronald Alfred; Lewis, Irwin Charles

    1997-01-01

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (i) an x-ray density of at least 2.00 grams per cubic centimeters, (ii) a closed porosity of no greater than 5%, and (iii) an open porosity of no greater than 47%; and (b) graphite having the following properties: (i) an x-ray density of at least 2.20 grams per cubic centimeters, (ii) a closed porosity of no greater than 5%, and (iii) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counterelectrode.

  10. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1997-10-14

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

  11. MULTIPLE DIFFERENTIAL ROTARY MECHANICAL DRIVE

    DOE Patents [OSTI]

    Smits, R.G.

    1964-01-28

    This patent relates to a mechanism suitable for such applications as driving two spaced-apart spools which carry a roll film strip under conditions where the film movement must be rapidly started, stopped, and reversed while maintaining a constant tension on the film. The basic drive is provided by a variable speed, reversible rnotor coupled to both spools through a first differential mechanism and driving both spools in the same direction. A second motor, providing a constant torque, is connected to the two spools through a second differential mechanism and is coupled to impart torque to one spool in a first direction anid to the other spool in the reverse direction thus applying a constant tension to the film passing over the two spools irrespective of the speed or direction of rotation thereof. (AEC)

  12. Electrochemical removal of material from metallic work

    DOE Patents [OSTI]

    Csakvary, Tibor; Fromson, Robert E.

    1980-05-13

    Deburring, polishing, surface forming and the like are carried out by electrochemical machining with conformable electrode means including an electrically conducting and an insulating web. The surface of the work to be processed is covered by a deformable electrically insulating web or cloth which is perforated and conforms with the work. The web is covered by a deformable perforated electrically conducting screen electrode which also conforms with, and is insulated from, the work by the insulating web. An electrolyte is conducted through the electrode and insulating web and along the work through a perforated elastic member which engages the electrode under pressure pressing the electrode and web against the work. High current under low voltage is conducted betwen the electrode and work through the insulator, removing material from the work. Under the pressure of the elastic member, the electrode and insulator continue to conform with the work and the spacing between the electrode and work is maintained constant.

  13. Development of an Electrochemical Separator and Compressor

    SciTech Connect (OSTI)

    Trent Molter

    2011-04-28

    Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

  14. Drive reconfiguration mechanism for tracked robotic vehicle

    DOE Patents [OSTI]

    Willis, W. David

    2000-01-01

    Drive reconfiguration apparatus for changing the configuration of a drive unit with respect to a vehicle body may comprise a guide system associated with the vehicle body and the drive unit which allows the drive unit to rotate about a center of rotation that is located at about a point where the drive unit contacts the surface being traversed. An actuator mounted to the vehicle body and connected to the drive unit rotates the drive unit about the center of rotation between a first position and a second position.

  15. Electrochemical apparatus comprising modified disposable rectangular

    Office of Scientific and Technical Information (OSTI)

    cuvette (Patent) | SciTech Connect Electrochemical apparatus comprising modified disposable rectangular cuvette Citation Details In-Document Search Title: Electrochemical apparatus comprising modified disposable rectangular cuvette Electrochemical apparatus includes a disposable rectangular cuvette modified with at least one hole through a side and/or the bottom. Apparatus may include more than one cuvette, which in practice is a disposable rectangular glass or plastic cuvette modified by

  16. Zelenay wins Electrochemical Society's Research Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    wins Electrochemical Society's Research Award December 11, 2012 Piotr Zelenay of LANL's Sensors and Electrochemical Devices group has won the 2012 Research Award presented by the Energy Technology Division of The Electrochemical Society. The award recognizes Zelenay's "outstanding and original contributions to the science and technology of energy-related research areas that include scientific and technological aspects of fossil fuels and alternative energy sources, energy management and

  17. Shock-activated electrochemical power supplies

    DOE Patents [OSTI]

    Benedick, W.B.; Graham, R.A.; Morosin, B.

    1988-11-08

    A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolytes rendering the electrolyte electrochemically active. 2 figs.

  18. Shock-activated electrochemical power supplies

    DOE Patents [OSTI]

    Benedick, William B.; Graham, Robert A.; Morosin, Bruno

    1988-01-01

    A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolytes rendering the electrolyte electrochemically active.

  19. Shock-activated electrochemical power supplies

    DOE Patents [OSTI]

    Benedick, W.B.; Graham, R.A.; Morosin, B.

    1987-04-20

    A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolyte rendering the electrolyte electrochemically active. 2 figs.

  20. Electrochemical Design Associates EDA | Open Energy Information

    Open Energy Info (EERE)

    Design Associates EDA Jump to: navigation, search Name: Electrochemical Design Associates (EDA) Place: California Zip: 94608-2513 Product: EDA is a technology development company...

  1. Electronic structural and electrochemical properties of lithium...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: Journal of the Electrochemical Society; Journal Volume: 3; Journal Issue: 1 Research Org: National Energy Technology Laboratory - In-house Research ...

  2. GROWTH AND ELECTROCHEMICAL CHARACTERIZATION OF CARBON NANOSPIKE...

    Office of Scientific and Technical Information (OSTI)

    Title: GROWTH AND ELECTROCHEMICAL CHARACTERIZATION OF CARBON NANOSPIKE THIN FILM ELECTRODES Authors: Sheridan, Leah B 1 ; Hensley, Dale K 1 ; Lavrik, Nickolay V 1 ; Smith, ...

  3. Center for Electrochemical Energy Science | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Science Research Program Publications & Presentations News An Energy Frontier Research Center Exploring the electrochemical reactivity of oxide materials and their...

  4. Electrochemical apparatus comprising modified disposable rectangular...

    Office of Scientific and Technical Information (OSTI)

    The apparatus are suitable for a variety of electrochemical experiments, including surface electrochemistry, bulk electrolysis, and flow cell experiments. Authors: Dattelbaum, ...

  5. Solid flexible electrochemical supercapacitor using Tobacco mosaic...

    Office of Scientific and Technical Information (OSTI)

    mosaic virus nanostructures and ALD ruthenium oxide Citation Details In-Document Search Title: Solid flexible electrochemical supercapacitor using Tobacco mosaic virus ...

  6. MIT- Electrochemical Energy Laboratory | Open Energy Information

    Open Energy Info (EERE)

    Name: MIT- Electrochemical Energy Laboratory Address: 77 Massachusetts Avenue Place: Cambridge, Massachusetts Zip: 02139 Region: Greater Boston Area Website: web.mit.edueel...

  7. Evaluation Of Electrochemical Machining Technology For Surface...

    Office of Scientific and Technical Information (OSTI)

    Technology For Surface Improvements In Additive Manufactured Components Citation Details In-Document Search Title: Evaluation Of Electrochemical Machining Technology For ...

  8. Nanomaterial-Based Electrochemical Biosensors and Bioassays

    SciTech Connect (OSTI)

    Liu, Guodong; Mao, Xun; Gurung, Anant; Baloda, Meenu; Lin, Yuehe; He, Yuqing

    2010-08-31

    This book chapter summarizes the recent advance in nanomaterials for electrochemical biosensors and bioassays. Biofunctionalization of nanomaterials for biosensors fabrication and their biomedical applications are discussed.

  9. Zelenay wins Electrochemical Society's Research Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The award includes a monetary prize and membership in the Electrochemical Society's Energy Technology Division. It will be presented at the society's spring meeting in...

  10. Apparatus for combinatorial screening of electrochemical materials

    DOE Patents [OSTI]

    A high throughput combinatorial screening method and apparatus for the evaluation of electrochemical materials using a single voltage source is disclosed wherein temperature changes arising from the application of an electrical load to a cell array are used to evaluate the relative electrochemical efficiency of the materials comprising the array. The apparatus may include an array of electrochemical cells that are connected to each other in parallel or in series, an electronic load for applying a voltage or current to the electrochemical cells , and a device , external to the cells, for monitoring the relative temperature of each cell when the load is applied.

    2009-12-15

    A high throughput combinatorial screening method and apparatus for the evaluation of electrochemical materials using a single voltage source (2) is disclosed wherein temperature changes arising from the application of an electrical load to a cell array (1) are used to evaluate the relative electrochemical efficiency of the materials comprising the array. The apparatus may include an array of electrochemical cells (1) that are connected to each other in parallel or in series, an electronic load (2) for applying a voltage or current to the electrochemical cells (1), and a device (3), external to the cells, for monitoring the relative temperature of each cell when the load is applied.

  11. Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process

    SciTech Connect (OSTI)

    Wei, Z.; Zhu, Y.; Zhang, W.; Wang, F.; Zhang, Q.; Qiu, B.; Han, S.; Xia, Y.; Liu, Z.

    2015-03-27

    Lithium-rich material owns a particularly high capacity owing to the activation of electrochemical inactive Li2MnO3 phase. But at the same time, MnO2 phase formed after Li2MnO3 activation confronts a severe problem of converting to spinel phase, and resulting in voltage decay. To our knowledge, this phenomenon is inherent property of layered manganese oxide materials and can hardly be overcome. Based on this, unlike previous reports, herein we design a method for the first time to accelerate the phase transformation by tuning the charge upper-limit voltage at a high value, so the phase transformation process can be finished in a few cycles. Then material structure remains stable while cycling at a low upper-limit voltage. By this novel method voltage decay is eliminated significantly.

  12. Anomalous-viscosity current drive

    DOE Patents [OSTI]

    Stix, T.H.; Ono, M.

    1986-04-25

    The present invention relates to a method and apparatus for maintaining a steady-state current for magnetically confining the plasma in a toroidal magnetic confinement device using anomalous viscosity current drive. A second aspect of this invention relates to an apparatus and method for the start-up of a magnetically confined toroidal plasma.

  13. Hydromechanical transmission with hydrodynamic drive

    DOE Patents [OSTI]

    Orshansky, Jr., deceased, Elias; Weseloh, William E.

    1979-01-01

    This transmission has a first planetary gear assembly having first input means connected to an input shaft, first output means, and first reaction means, and a second planetary gear assembly having second input means connected to the first input means, second output means, and second reaction means connected directly to the first reaction means by a reaction shaft. First clutch means, when engaged, connect the first output means to an output shaft in a high driving range. A hydrodynamic drive is used; for example, a torque converter, which may or may not have a stationary case, has a pump connected to the second output means, a stator grounded by an overrunning clutch to the case, and a turbine connected to an output member, and may be used in a starting phase. Alternatively, a fluid coupling or other type of hydrodynamic drive may be used. Second clutch means, when engaged, for connecting the output member to the output shaft in a low driving range. A variable-displacement hydraulic unit is mechanically connected to the input shaft, and a fixed-displacement hydraulic unit is mechanically connected to the reaction shaft. The hydraulic units are hydraulically connected together so that when one operates as a pump the other acts as a motor, and vice versa. Both clutch means are connected to the output shaft through a forward-reverse shift arrangement. It is possible to lock out the torque converter after the starting phase is over.

  14. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2012-10-09

    Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

  15. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2008-04-01

    Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

  16. Microfluidic devices with thick-film electrochemical detection

    DOE Patents [OSTI]

    Wang, Joseph; Tian, Baomin; Sahlin, Eskil

    2005-04-12

    An apparatus for conducting a microfluidic process and analysis, including at least one elongated microfluidic channel, fluidic transport means for transport of fluids through the microfluidic channel, and at least one thick-film electrode in fluidic connection with the outlet end of the microfluidic channel. The present invention includes an integrated on-chip combination reaction, separation and thick-film electrochemical detection microsystem, for use in detection of a wide range of analytes, and methods for the use thereof.

  17. Nanoelectrode array for electrochemical analysis

    DOE Patents [OSTI]

    Yelton, William G. (Sandia Park, NM); Siegal, Michael P. (Albuquerque, NM)

    2009-12-01

    A nanoelectrode array comprises a plurality of nanoelectrodes wherein the geometric dimensions of the electrode controls the electrochemical response, and the current density is independent of time. By combining a massive array of nanoelectrodes in parallel, the current signal can be amplified while still retaining the beneficial geometric advantages of nanoelectrodes. Such nanoelectrode arrays can be used in a sensor system for rapid, non-contaminating field analysis. For example, an array of suitably functionalized nanoelectrodes can be incorporated into a small, integrated sensor system that can identify many species rapidly and simultaneously under field conditions in high-resistivity water, without the need for chemical addition to increase conductivity.

  18. Electrolyte composition for electrochemical cell

    DOE Patents [OSTI]

    Vissers, Donald R.; Tomczuk, Zygmunt; Anderson, Karl E.; Roche, Michael F.

    1979-01-01

    A high-temperature, secondary electrochemical cell that employs FeS as the positive electrode reactant and lithium or lithium alloy as the negative electrode reactant includes an improved electrolyte composition. The electrolyte comprises about 60-70 mole percent LiCl and 30-40 percent mole percent KCl which includes LiCl in excess of the eutectic composition. The use of this electrolyte suppresses formation of the J phase and thereby improves the utilization of positive electrode active material during cell cycling.

  19. High temperature sealed electrochemical cell

    DOE Patents [OSTI]

    Valentin Chung, Brice Hoani; Burke, Paul J.; Sadoway, Donald R.

    2015-10-06

    A cell for high temperature electrochemical reactions is provided. The cell includes a container, at least a portion of the container acting as a first electrode. An extension tube has a first end and a second end, the extension tube coupled to the container at the second end forming a conduit from the container to said first end. A second electrode is positioned in the container and extends out of the container via the conduit. A seal is positioned proximate the first end of the extension tube, for sealing the cell.

  20. A new design for a disposable and modifiable electrochemical...

    Office of Scientific and Technical Information (OSTI)

    A new design for a disposable and modifiable electrochemical cell Citation Details In-Document Search Title: A new design for a disposable and modifiable electrochemical cell ...

  1. Advanced Hybrid Water-Heater Using Electrochemical Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybrid Water-Heater Using Electrochemical Compression (ECC) 2016 Building Technologies ... Key Partners: Project Goal: Develop a heat pump water heater utilizing electrochemical ...

  2. Lithium based electrochemical cell systems having a degassing...

    Office of Scientific and Technical Information (OSTI)

    Title: Lithium based electrochemical cell systems having a degassing agent A lithium based electrochemical cell system includes a positive electrode; a negative electrode; an ...

  3. Leveraging National Lab Capabilities in Fuel Cells and Electrochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Leveraging National Lab Capabilities in Fuel Cells and Electrochemical Systems-Phoenix, Arizona Leveraging National Lab Capabilities in Fuel Cells and Electrochemical ...

  4. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...e",511864,"*",3,106,1,"*",4.8 ," Electro-Chemical Processes",86360,"--","--","--","--","--... Drive",36479,0,1,13,"*",0,11 ," Electro-Chemical Processes","Q","--","--","--","--","--",...

  5. " Row: End Uses within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1881,5,13,99,7,7,11.5 ," Electro-Chemical Processes",354,"--","--","--","--","--",... *",8," *",0,1.2 ," Electro-Chemical Processes","*","--","--","--","--","--",...

  6. Method for making an electrochemical cell

    DOE Patents [OSTI]

    Tuller, Harry L.; Kramer, Steve A.; Spears, Marlene A.; Pal, Uday B.

    1996-01-01

    An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is provided.

  7. In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution

    SciTech Connect (OSTI)

    Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

    2010-03-31

    A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

  8. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P.; Stechel, Ellen Beth; Moyer, Connor J.; Ambrosini, Andrea; Key, Robert J.

    2010-09-01

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  9. Bussing Structure In An Electrochemical Cell

    DOE Patents [OSTI]

    Romero, Antonio L.

    2001-06-12

    A bussing structure for bussing current within an electrochemical cell. The bussing structure includes a first plate and a second plate, each having a central aperture therein. Current collection tabs, extending from an electrode stack in the electrochemical cell, extend through the central aperture in the first plate, and are then sandwiched between the first plate and second plate. The second plate is then connected to a terminal on the outside of the case of the electrochemical cell. Each of the first and second plates includes a second aperture which is positioned beneath a safety vent in the case of the electrochemical cell to promote turbulent flow of gasses through the vent upon its opening. The second plate also includes protrusions for spacing the bussing structure from the case, as well as plateaus for connecting the bussing structure to the terminal on the case of the electrochemical cell.

  10. Electrochemical preparation of poly(methylene blue)/graphene nanocomposite thin films

    SciTech Connect (OSTI)

    Erçar?kc?, Elif; Da?c?, Kader; Topçu, Ezgi; Alanyal?o?lu, Murat

    2014-07-01

    Highlights: • Poly(MB)/graphene thin films are prepared by a simple electrochemical approach. • Graphene layers in the film show a broad band in visible region of absorbance spectra. • Morphology of composite films indicates both disordered and ordered regions. • XRD reveals that nanocomposite films include rGO layers after electropolymerization process. • Chemically prepared graphene is better than electrochemically prepared graphene for electrooxidation of nitrite. - Abstract: Poly(methylene blue)/graphene nanocomposite thin films were prepared by electropolymerization of methylene blue in the presence of graphene which have been synthesized by two different methods of a chemical oxidation process and an electrochemical approach. Synthesized nanocomposite thin films were characterized by using cyclic voltammetry, UV–vis. absorption spectroscopy, powder X-ray diffraction, and scanning tunneling microscopy techniques. Electrocatalytical properties of prepared poly(methylene blue)/graphene nanocomposite films were compared toward electrochemical oxidation of nitrite. Under optimized conditions, electrocatalytical effect of nanocomposite films of chemically prepared graphene through electrochemical oxidation of nitrite was better than that of electrochemically prepared graphene.

  11. Electrochemical behavior of carbon aerogels derived from different precursors

    SciTech Connect (OSTI)

    Pekala, R.W.; Alviso, C.T.; Nielson, J.K.; Tran, T.D. [Lawrence Livermore National Lab., CA (United States); Reynolds, G.M.; Dresshaus, M.S. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Physics

    1995-04-01

    The ability to tailor the structure and properties of porous carbons has led to their increased use as electrodes in energy storage devices. Our research focuses on the synthesis and characterization of carbon aerogels for use in electrochemical double layer capacitors. Carbon aerogels are formed from the sol-gel polymerization of (1) resorcinol-formaldehyde or (2) phenolic-furfural, followed by supercritical drying from carbon dioxide, and subsequent pyrolysis in an inert atmosphere. These materials can be produced as monoliths, composites, thin films, powders, or microspheres. In all cases, the areogels have an open-cell structure with an ultrafine pore size (<100 nm), high surface area (400-1 100 m{sup 2}/g), and a solid matrix composed of interconnected particles, fibers, or platelets with characteristic dimensions of 10 nm. This paper examines the effects of the carbon precursor and processing conditions on electrochemical performance in aqueous and organic electrolytes.

  12. The electrochemical oxidation of polyacetylene and its battery applications

    SciTech Connect (OSTI)

    Farrington, G.C.; DeNuzzio, J.; Frydrych, D.; Scrosati, B.

    1984-01-01

    When oxidized in a nonaqueous cell containing 1.0M LiClO/sub 4/ in propylene carbonate, polyacetylene develops a voltage of 3.4-4.0V vs. Li/Li/sup +/ ClO/sub 4//sup -/. Oxidation levels at least as high as (CH(CLO/sub 4/) /SUB 1/10/ ) /SUB x/ can be produced electrochemically and then reduced to the undoped state with nearly 100% coulombic efficiency. The electrochemical doping (oxidation) process is only efficient when carried out with a minimum of liquid electrolyte under ultraclean conditions. Similar results are observed with a LiAsF/sub 6/ electrolyte. Polyacetylene is an extraordinary material of great importance for electrochemistry. However, on the basis of this and other published research, it is not yet clear that it offers major advantages over current electrodes for high energy density nonaqueous batteries.

  13. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2003-08-12

    Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.

  14. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2006-10-10

    Low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures provide solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one aspect the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another aspect, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe and Cu, or alloys thereof.

  15. Structures And Fabrication Techniques For Solid State Electrochemical Devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2005-12-27

    Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.

  16. SE Drive Technik | Open Energy Information

    Open Energy Info (EERE)

    Drive Technik Jump to: navigation, search Name: SE Drive Technik Place: Bochum, Germany Zip: 44791 Product: Germany-based R&D subsidiary of Indian turbine maker Suzlon. References:...

  17. NexxtDrive | Open Energy Information

    Open Energy Info (EERE)

    NexxtDrive Jump to: navigation, search Name: NexxtDrive Place: London, England, United Kingdom Zip: WC2N 5HR Product: London-based firm developing electro-mechanical technologies...

  18. Eco Drive Capital Partners | Open Energy Information

    Open Energy Info (EERE)

    Capital Partners Jump to: navigation, search Name: Eco-Drive Capital Partners Place: New York Product: New York-based Eco-Drive is a European-American investment consortium,...

  19. GenDrive Limited | Open Energy Information

    Open Energy Info (EERE)

    GenDrive Limited Jump to: navigation, search Name: GenDrive Limited Place: Cambridge, United Kingdom Zip: CB23 3GY Sector: Renewable Energy, Solar, Wind energy Product: Developing...

  20. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, Milton; Cook, Glenn M.

    1988-01-01

    Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  1. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1985-05-21

    Disclosed is an apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  2. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1988-05-17

    Apparatus is described for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom. 2 figs.

  3. Indianapolis Offers a Lesson on Driving Demand

    Broader source: Energy.gov [DOE]

    Successful program managers know that understanding the factors that drive homeowners to make upgrades is critical to the widespread adoption of energy efficiency. What better place to learn about driving demand for upgrades than in Indianapolis, America's most famous driving city?

  4. Cathode for an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.; Luck, Christopher F.

    2001-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  5. Electrolyte for an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B.; Dudney, Nancy J.

    1997-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte amorphous lithium phosphorus oxynitride which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  6. Electrolyte for an electrochemical cell

    DOE Patents [OSTI]

    Bates, J.B.; Dudney, N.J.

    1997-01-28

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making the same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte amorphous lithium phosphorus oxynitride which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C. 9 figs.

  7. Fluid cooled vehicle drive module

    DOE Patents [OSTI]

    Beihoff, Bruce C.; Radosevich, Lawrence D.; Meyer, Andreas A.; Gollhardt, Neil; Kannenberg, Daniel G.

    2005-11-15

    An electric vehicle drive includes a support may receive one or more power electronic circuits. The support may aid in removing heat from the circuits through fluid circulating through the support. The support, in conjunction with other packaging features may form a shield from both external EM/RFI and from interference generated by operation of the power electronic circuits. Features may be provided to permit and enhance connection of the circuitry to external circuitry, such as improved terminal configurations. Modular units may be assembled that may be coupled to electronic circuitry via plug-in arrangements or through interface with a backplane or similar mounting and interconnecting structures.

  8. Minimize Adverse Motor and Adjustable Speed Drive Interactions

    Broader source: Energy.gov [DOE]

    Electronic adjustable speed drives (ASDs) are extremely efficient and valuable assets to motor systems. They allow precise process control and provide energy savings within systems that do not need to operate continuously at full output. This tip sheet discusses design considerations to take into account when considering ASDs and offers suggested actions.

  9. Chemically modified graphite for electrochemical cells

    DOE Patents [OSTI]

    Greinke, Ronald Alfred (Medina, OH); Lewis, Irwin Charles (Strongsville, OH)

    1998-01-01

    This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (i) the electrode, (ii) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (iii) a counterelectrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes.

  10. Chemically modified graphite for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1998-05-26

    This invention relates to chemically modified graphite particles: (a) that are useful in alkali metal-containing electrode of a electrochemical cell comprising: (1) the electrode, (2) a non-aqueous electrolytic solution comprising an organic aprotic solvent which solvent tends to decompose when the electrochemical cell is in use, and an electrically conductive salt of an alkali metal, and (3) a counter electrode; and (b) that are chemically modified with fluorine, chlorine, iodine or phosphorus to reduce such decomposition. This invention also relates to electrodes comprising such chemically modified graphite and a binder and to electrochemical cells containing such electrodes. 3 figs.

  11. FMC high power density electric drive technology

    SciTech Connect (OSTI)

    Shafer, G.A.

    1994-12-31

    FMC has developed a unique capability in energy-efficient, high-performance AC induction electric drive systems for electric and hybrid vehicles. These drives will not only be important to future military ground combat vehicles, but will also provide significant competitive advantages to industrial and commercial machinery and vehicles. The product line under development includes drive motors and associated power converters directed at three power/vehicle weight classes. These drive systems cover a broad spectrum of potential vehicle applications, ranging from light pickup trucks to full-size transit buses. The drive motors and power converters are described.

  12. Vehicle Technologies Office: U.S. DRIVE 2014 Technical Accomplishments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. DRIVE 2014 Technical Accomplishments Report Vehicle Technologies Office: U.S. DRIVE 2014 Technical Accomplishments Report The U.S. DRIVE 2014 Highlights of Technical ...

  13. Vehicle Technologies Office: US DRIVE Materials Technical Team...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    US DRIVE Materials Technical Team Roadmap Vehicle Technologies Office: US DRIVE Materials Technical Team Roadmap The Materials Technical Team (MTT) of the U.S. DRIVE Partnership ...

  14. Vehicle Technologies Office: U.S. DRIVE 2015 Technical Accomplishments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. DRIVE 2015 Technical Accomplishments Report Vehicle Technologies Office: U.S. DRIVE 2015 Technical Accomplishments Report The U.S. DRIVE 2015 Highlights of Technical ...

  15. Small Businesses Helping Drive Economy: Clean Energy, Clean Sites...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Businesses Helping Drive Economy: Clean Energy, Clean Sites Small Businesses Helping Drive Economy: Clean Energy, Clean Sites A memo on small businesses helping drive the economy: ...

  16. DOE Tour of Zero Floorplans: Hickory Drive by Glastonbury Housesmith...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hickory Drive by Glastonbury Housesmith DOE Tour of Zero Floorplans: Hickory Drive by Glastonbury Housesmith DOE Tour of Zero Floorplans: Hickory Drive by Glastonbury Housesmith...

  17. US DRIVE Driving Research and Innovation for Vehicle Efficiency and Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sustainability Partnership Plan | Department of Energy Driving Research and Innovation for Vehicle Efficiency and Energy Sustainability Partnership Plan US DRIVE Driving Research and Innovation for Vehicle Efficiency and Energy Sustainability Partnership Plan This document describes the vision, mission, scope, and governing policies of the U.S. DRIVE Partnership ("Partnership"). Dated April 2016. PDF icon US DRIVE Partnership Plan-April 2016 More Documents & Publications US

  18. Bismuth-based electrochemical stripping analysis

    DOE Patents [OSTI]

    Wang, Joseph

    2004-01-27

    Method and apparatus for trace metal detection and analysis using bismuth-coated electrodes and electrochemical stripping analysis. Both anodic stripping voltammetry and adsorptive stripping analysis may be employed.

  19. Rechargeable thin-film electrochemical generator

    DOE Patents [OSTI]

    Rouillard, Roger; Domroese, Michael K.; Hoffman, Joseph A.; Lindeman, David D.; Noel, Joseph-Robert-Gaetan; Radewald, Vern E.; Ranger, Michel; Sudano, Anthony; Trice, Jennifer L.; Turgeon, Thomas A.

    2000-09-15

    An improved electrochemical generator is disclosed. The electrochemical generator includes a thin-film electrochemical cell which is maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of the cell, conducts current into and out of the cell and also conducts thermal energy between the cell and thermally conductive, electrically resistive material disposed on a vessel wall adjacent the conductor. The thermally conductive, electrically resistive material may include an anodized coating or a thin sheet of a plastic, mineral-based material or conductive polymer material. The thermal conductor is fabricated to include a resilient portion which expands and contracts to maintain mechanical contact between the cell and the thermally conductive material in the presence of relative movement between the cell and the wall structure. The electrochemical generator may be disposed in a hermetically sealed housing.

  20. From corrosion to batteries: Electrochemical interface studies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From corrosion to batteries: Electrochemical interface studies Thursday, October 18, 2012 - 11:00am SSRL, Bldg. 137, Rm 226 Dr. Frank Uwe Renner Max-Planck-Institut fr ...

  1. Synthesis and electrochemical properties of NiO nanospindles

    SciTech Connect (OSTI)

    Zhou, Hai; Lv, Baoliang; Xu, Yao; Wu, Dong

    2014-02-01

    Graphical abstract: NiO nanospindles with a different electrochemical activity as compared to those previous reports were synthesized via an agglomeration–dissolution–recrystallization growth process without the addition of any surfactant. - Highlights: ‱ NiO nanospindles were synthesized without the addition of any surfactant. ‱ The agglomeration–dissolution–recrystallization growth process was used to explain the precursors’ formation process of the spindle-like NiO. ‱ As-obtained spindle-like NiO showed a different electrochemical activity as compared to those previous reports. - Abstract: NiO nanospindles were successfully synthesized via a hydrothermal and post-treatment method. The as-synthesized nanospindles were about several hundred nanometers in width and about one micrometer in length. X-ray diffraction (XRD) analysis revealed that the spindle-like structure was cubic NiO phase crystalline. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analysis indicated that these NiO nanospindles were of single crystal nature. On the basis of time-dependent experiments, a possible agglomeration–dissolution–recrystallization growth process was proposed to explain the formation process of the spindle-like precursors. The cyclic voltammetry (CV) measurement showed that the as-prepared spindle-like NiO exhibited a pseudo-capacitance behavior.

  2. Electrochemical and Photophysical Properties of electropolymerized

    Office of Scientific and Technical Information (OSTI)

    Thieno[32-b]thiophene and 22'-Bithiophene polymers: A comparative study. (Journal Article) | SciTech Connect Electrochemical and Photophysical Properties of electropolymerized Thieno[32-b]thiophene and 22'-Bithiophene polymers: A comparative study. Citation Details In-Document Search Title: Electrochemical and Photophysical Properties of electropolymerized Thieno[32-b]thiophene and 22'-Bithiophene polymers: A comparative study. Abstract not provided. Authors: Lambert, Timothy N. ; Steen,

  3. Electronic Structure Modeling of Electrochemical Reactions at

    Office of Scientific and Technical Information (OSTI)

    Electrode/Electrolyte Interfaces in Lithium Ion Batteries (Journal Article) | SciTech Connect Journal Article: Electronic Structure Modeling of Electrochemical Reactions at Electrode/Electrolyte Interfaces in Lithium Ion Batteries Citation Details In-Document Search Title: Electronic Structure Modeling of Electrochemical Reactions at Electrode/Electrolyte Interfaces in Lithium Ion Batteries Authors: Leung, Kevin Publication Date: 2013-01-31 OSTI Identifier: 1105237 DOE Contract Number:

  4. Low-temperature thermally regenerative electrochemical system

    DOE Patents [OSTI]

    Loutfy, R.O.; Brown, A.P.; Yao, N.P.

    1982-04-21

    A thermally regenerative electrochemical system is described including an electrochemical cell with two water-based electrolytes separated by an ion exchange membrane, at least one of the electrolytes containing a complexing agent and a salt of a multivalent metal whose respective order of potentials for a pair of its redox couples is reversible by a change in the amount of the ocmplexing agent in the electrolyte, the complexing agent being removable by distillation to cause the reversal.

  5. Low temperature thermally regenerative electrochemical system

    DOE Patents [OSTI]

    Loutfy, Raouf O.; Brown, Alan P.; Yao, Neng-Ping

    1983-01-01

    A thermally regenerative electrochemical system including an electrochemical cell with two water-based electrolytes separated by an ion exchange membrane, at least one of the electrolytes containing a complexing agent and a salt of a multivalent metal whose respective order of potentials for a pair of its redox couples is reversible by a change in the amount of the complexing agent in the electrolyte, the complexing agent being removable by distillation to cause the reversal.

  6. Progress Towards Commercialization of Electrochemical Membrane Technology

    Office of Scientific and Technical Information (OSTI)

    for CO2 Capture and Power Generation (Journal Article) | SciTech Connect Progress Towards Commercialization of Electrochemical Membrane Technology for CO2 Capture and Power Generation Citation Details In-Document Search Title: Progress Towards Commercialization of Electrochemical Membrane Technology for CO2 Capture and Power Generation To address the concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed Combined Electric

  7. Multi-layer seal for electrochemical devices

    DOE Patents [OSTI]

    Chou, Yeong-Shyung [Richland, WA; Meinhardt, Kerry D [Kennewick, WA; Stevenson, Jeffry W [Richland, WA

    2010-09-14

    Multi-layer seals are provided that find advantageous use for reducing leakage of gases between adjacent components of electrochemical devices. Multi-layer seals of the invention include a gasket body defining first and second opposing surfaces and a compliant interlayer positioned adjacent each of the first and second surfaces. Also provided are methods for making and using the multi-layer seals, and electrochemical devices including said seals.

  8. Multi-layer seal for electrochemical devices

    DOE Patents [OSTI]

    Chou, Yeong-Shyung [Richland, WA; Meinhardt, Kerry D [Kennewick, WA; Stevenson, Jeffry W [Richland, WA

    2010-11-16

    Multi-layer seals are provided that find advantageous use for reducing leakage of gases between adjacent components of electrochemical devices. Multi-layer seals of the invention include a gasket body defining first and second opposing surfaces and a compliant interlayer positioned adjacent each of the first and second surfaces. Also provided are methods for making and using the multi-layer seals, and electrochemical devices including said seals.

  9. Alternative Waste Forms for Electro-Chemical Salt Waste

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

    2009-10-28

    This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

  10. Electric vehicle drive train with contactor protection

    DOE Patents [OSTI]

    Konrad, Charles E.; Benson, Ralph A.

    1994-01-01

    A drive train for an electric vehicle includes a traction battery, a power drive circuit, a main contactor for connecting and disconnecting the traction battery and the power drive circuit, a voltage detector across contacts of the main contactor, and a controller for controlling the main contactor to prevent movement of its contacts to the closed position when the voltage across the contacts exceeds a predetermined threshold, to thereby protect the contacts of the contactor. The power drive circuit includes an electric traction motor and a DC-to-AC inverter with a capacitive input filter. The controller also inhibits the power drive circuit from driving the motor and thereby discharging the input capacitor if the contacts are inadvertently opened during motoring. A precharging contactor is controlled to charge the input filter capacitor prior to closing the main contactor to further protect the contacts of the main contactor.

  11. Electric vehicle drive train with contactor protection

    DOE Patents [OSTI]

    Konrad, C.E.; Benson, R.A.

    1994-11-29

    A drive train for an electric vehicle includes a traction battery, a power drive circuit, a main contactor for connecting and disconnecting the traction battery and the power drive circuit, a voltage detector across contacts of the main contactor, and a controller for controlling the main contactor to prevent movement of its contacts to the closed position when the voltage across the contacts exceeds a predetermined threshold, to thereby protect the contacts of the contactor. The power drive circuit includes an electric traction motor and a DC-to-AC inverter with a capacitive input filter. The controller also inhibits the power drive circuit from driving the motor and thereby discharging the input capacitor if the contacts are inadvertently opened during motoring. A precharging contactor is controlled to charge the input filter capacitor prior to closing the main contactor to further protect the contacts of the main contactor. 3 figures.

  12. Advanced Electric Drive Vehicles … A Comprehensive Education...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Advanced Electric Drive Vehicles A Comprehensive Education, Training, and Outreach Program Advanced Electric Drive Vehicles A Comprehensive ...

  13. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Unocic, Raymond R; Sun, Xiao-Guang; Sacci, Robert L; Adamczyk, Leslie A; Alsem, Daan Hein; Dai, Sheng; Dudney, Nancy J; More, Karren Leslie

    2014-01-01

    Complex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

  14. MASSACHUSETTS DRIVES PERFORMANCE MEASUREMENT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    MASSACHUSETTS DRIVES PERFORMANCE MEASUREMENT MASSACHUSETTS DRIVES PERFORMANCE MEASUREMENT MASSACHUSETTS DRIVES PERFORMANCE MEASUREMENT Massachusetts' longstanding statewide Mass Save energy efficiency program, supported by ratepayer funds and sponsored by utilities, has resulted in the state being named first in energy efficiency by the American Council for an Energy Efficient Economy for the past four years. Even with this accolade, the state wanted to test strategies to achieve more-and

  15. A novel Stirling engine with an elliptic drive

    SciTech Connect (OSTI)

    Fang, H.W.; Herold, K.E.; Holland, H.M.; Beach, E.H.

    1996-12-31

    The concept of the Stirling cycle seems quite simple when presented as a cycle involving two constant temperature and two constant volume processes. The reality of machines that have evolved from the Stirling concept is considerably more complicated. Most real machines employ a drive mechanism that approximates a sinusoidal volume variation for each of the cylinders. This results in an overall volume variation that only poorly approximates the constant volume processes postulated in the classic definition of a Stirling cycle. The difficulties of achieving the piston motions necessary to attain the discontinuous motions of the classic cycle are well known and, as a result, the sinusoidal motions are widely accepted as an inevitable compromise. It is noted that free piston Stirling machines are not constrained in the same manner. However, the discussion here focuses on kinematic drive machines. In the current study, a Rider-type engine with an elliptic drive is modeled with the objective of clarifying the potential of a more ideal volume variation. This drive mechanism is the subject of a US Patent filed with Serial Number 08/360,052 on 20 December 1994.

  16. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 9 PDF icon grandchallengesportfoliopg9.pdf More Documents & Publications ...

  17. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 8 PDF icon grandchallengesportfoliopg8.pdf More Documents & Publications ...

  18. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 6 PDF icon grandchallengesportfoliopg6.pdf More Documents & Publications ...

  19. Centerless-drive solar collector system

    SciTech Connect (OSTI)

    Butler, B. L.

    1985-12-24

    A parabolic-trough solar collector system is disclosed, with each collector driven to track the sun using a ring driven in centerless fashion. The parabolic troughs are made of laminated plywood or molded or formed of plastics or metals. The drive motor moves a flexible belt, i.e., chain or cable, which is routed about the drive ring on each collector. The motion of the cable moves all drive rings together to track the sun. A photodetector senses the position of the sun and provides the signal needed to drive the collectors in the correct direction.

  20. High Efficiency Driving Electronics for General Illumination...

    Office of Scientific and Technical Information (OSTI)

    Driving Electronics for General Illumination LED Luminaires Upadhyay, Anand 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION New generation of standalone LED driver platforms...

  1. DistributionDrive | Open Energy Information

    Open Energy Info (EERE)

    search Name: DistributionDrive Place: Addison, Texas Zip: 75001 Product: Supplier of Biodiesel, Straight Vegetable Oil (SVO), Recycled Vegetable Oil (WVO) and Engine Conversion...

  2. Driving the Future | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Driving the Future At Argonne National Laboratory's Center for Transportation Research, our goal is to accelerate the development and deployment of vehicle technologies that help...

  3. Electric Drive Transportation Association EDTA | Open Energy...

    Open Energy Info (EERE)

    Transportation Association EDTA Jump to: navigation, search Name: Electric Drive Transportation Association (EDTA) Product: EDTA is the preeminent U.S. industry association...

  4. Electric-Drive Vehicle Basics (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2011-04-01

    Describes the basics of electric-drive vehicles, including hybrid electric vehicles, plug-in hybrid electric vehicles, all-electric vehicles, and the various charging options.

  5. Magnetically Coupled Adjustable Speed Motor Drives

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... for the Northwest Energy Effciency Alliance, March 2000. Additional References Dan Greenberg, Platts Research and Consulting, Magnetically Coupled Adjustable-Speed Drives: Going ...

  6. Advanced Electric Drive Vehicles ? A Comprehensive Education...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. PDF icon tiarravt034ferdowsi2010o.pdf More Documents & Publications Advanced Electric Drive Vehicles A Comprehensive Education, Training, and Outreach Program...

  7. Electric Drive Transportation Association Conference | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Image: Photo courtesy of Electric Drive Transportation Association Panel Discussion 2 of 5 Panel Discussion Loan Programs Office Executive Director Peter Davidson speaks during a ...

  8. Electric Drive Component Manufacturing Facilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Drive Component Manufacturing Facilities Technology Roadmap Analysis 2013: Assessing Automotive Technology R&D Relevant to DOE Power Electronics Cost Targets Advanced ...

  9. Control rod drive hydraulic system

    DOE Patents [OSTI]

    Ose, Richard A.

    1992-01-01

    A hydraulic system for a control rod drive (CRD) includes a variable output-pressure CR pump operable in a charging mode for providing pressurized fluid at a charging pressure, and in a normal mode for providing the pressurized fluid at a purge pressure, less than the charging pressure. Charging and purge lines are disposed in parallel flow between the CRD pump and the CRD. A hydraulic control unit is disposed in flow communication in the charging line and includes a scram accumulator. An isolation valve is provided in the charging line between the CRD pump and the scram accumulator. A controller is operatively connected to the CRD pump and the isolation valve and is effective for opening the isolation valve and operating the CRD pump in a charging mode for charging the scram accumulator, and closing the isolation valve and operating the CRD pump in a normal mode for providing to the CRD through the purge line the pressurized fluid at a purge pressure lower than the charging pressure.

  10. Electrochemical synthesis of nanosized hydroxyapatite by pulsed direct current method

    SciTech Connect (OSTI)

    Nur, Adrian; Rahmawati, Alifah; Ilmi, Noor Izzati; Affandi, Samsudin; Widjaja, Arief

    2014-02-24

    Synthesis of nanosized of hydroxyapatite (HA) by electrochemical pulsed direct current (PDC) method has been studied. The aim of this work is to study the influence of various PDC parameters (pH initial, electrode distance, duty cycle, frequency, and amplitude) on particle surface area of HA powders. The electrochemical synthesis was prepared in solution Ca{sup 2+}/EDTA{sup 4?}/PO{sub 4}{sup 3+} at concentration 0.25/0.25/0.15 M for 24 h. The electrochemical cell was consisted of two carbon rectangular electrodes connected to a function generator to produce PDC. There were two treatments for particles after electrosynthesized, namely without aging and aged for 2 days at 40 °C. For both cases, the particles were filtered and washed by demineralized water to eliminate the impurities and unreacted reactants. Then, the particles were dried at 100 °C for 2 days. The dried particles were characterized by X-ray diffraction, surface area analyzer, scanning electron microscopy (SEM), Fourier transform infrared spectra and thermogravimetric and differential thermal analysis. HA particles can be produced when the initial pH > 6. The aging process has significant effect on the produced HA particles. SEM images of HA particles showed that the powders consisted of agglomerates composed of fine crystallites and have morphology plate-like and sphere. The surface area of HA particles is in the range of 25 – 91 m{sup 2}/g. The largest particle surface area of HA was produced at 4 cm electrode distance, 80% cycle duty, frequency 0.1 Hz, amplitude 9 V and with aging process.

  11. Advanced Electric Drive Vehicles | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt039_ti_schwendeman_2011_p.pdf More Documents & Publications Advanced Electric Drive Vehicles Advanced Electric Drive Vehicles 2010 DOE EERE Vehicle Technologies Program Merit Review … Technology Integration

  12. DRIVE Analysis Tool Generates Custom Vehicle Drive Cycles Based on Real-World Data (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-04-01

    This fact sheet from the National Renewable Energy Laboratory describes the Drive-Cycle Rapid Investigation, Visualization, and Evaluation (DRIVE) analysis tool, which uses GPS and controller area network data to characterize vehicle operation and produce custom vehicle drive cycles, analyzing thousands of hours of data in a matter of minutes.

  13. Minimize Adverse Motor and Adjustable Speed Drive Interactions - Motor Tip Sheet #15

    SciTech Connect (OSTI)

    2008-07-01

    Electronic adjustable speed drives (ASDs) are an extremely efficient and valuable asset to motor systems. They allow precise process control and provide energy savings within systems that do not need to continuously operate at full output.

  14. Electrochemical Lithium Ion Battery Performance Model

    Energy Science and Technology Software Center (OSTI)

    2007-03-29

    The Electrochemical Lithium Ion Battery Performance Model allows for the computer prediction of the basic thermal, electrical, and electrochemical performance of a lithium ion cell with simplified geometry. The model solves governing equations describing the movement of lithium ions within and between the negative and positive electrodes. The governing equations were first formulated by Fuller, Doyle, and Newman and published in J. Electrochemical Society in 1994. The present model solves the partial differential equations governingmore » charge transfer kinetics and charge, species, heat transports in a computationally-efficient manner using the finite volume method, with special consideration given for solving the model under conditions of applied current, voltage, power, and load resistance.« less

  15. Electrochemical Polishing Applications and EIS of a Novel Choline Chloride-Based Ionic Liquid

    SciTech Connect (OSTI)

    Wixtrom, Alex I.; Buhler, Jessica E.; Reece, Charles E.; Abdel-Fattah, Tarek M.

    2013-06-01

    Minimal surface roughness is a critical feature for high-field superconducting radio frequency (SRF) cavities used to engineer particle accelerators. Current methods for polishing Niobium cavities typically utilize solutions containing a mixture of concentrated sulfuric and hydrofluoric acid. Polishing processes such as these are effective, yet there are many hazards and costs associated with the use (and safe disposal) of the concentrated acid solutions. An alternative method for electrochemical polishing of the cavities was explored using a novel ionic liquid solution containing choline chloride. Potentiostatic electrochemical impedance spectroscopy (EIS) was used to analyze the ionic polishing solution. Final surface roughness of the Nb was found to be comparable to that of the acid-polishing method, as assessed by atomic force microscopy (AFM). This indicates that ionic liquid-based electrochemical polishing of Nb is a viable replacement for acid-based methods for preparation of SRF cavities.

  16. Table 5.7 End Uses of Fuel Consumption, 2010;

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Drive 426,121 * 5 116 1 * Electro-Chemical Processes 77,146 -- -- -- -- -- Other ... 0 Machine Drive 40,701 * * 5 * 0 Electro-Chemical Processes 5,597 -- -- -- -- -- Released: ...

  17. " Row: End Uses;"

    U.S. Energy Information Administration (EIA) Indexed Site

    Drive",1746,2,16,109,4,5,4.8 " Electro-Chemical Processes",295,"--","--","--","--","--",... Drive",182,"*",2,7,1,0,8.8 " Electro-Chemical Processes",21,"--","--","--","--","--",1 ...

  18. Adjustable Speed Drive Part-Load Efficiency - Motor Tip Sheet #11

    SciTech Connect (OSTI)

    2008-07-01

    An adjustable speed drive (ASD) is a device that controls the rotational speed of motor-driven equipment. Variable frequency drives (VFDs), the most common type of ASDs, efficiently meet varying process requirements by adjusting the frequency and voltage of the power supplied to an AC motor to enable it to operate over a wide speed range. External sensors monitor flow, liquid levels, or pressure and then transmit a signal to a controller that adjusts the frequency and speed to match process requirements.

  19. Method for conducting nonlinear electrochemical impedance spectroscopy

    DOE Patents [OSTI]

    Adler, Stuart B.; Wilson, Jamie R.; Huff, Shawn L.; Schwartz, Daniel T.

    2015-06-02

    A method for conducting nonlinear electrochemical impedance spectroscopy. The method includes quantifying the nonlinear response of an electrochemical system by measuring higher-order current or voltage harmonics generated by moderate-amplitude sinusoidal current or voltage perturbations. The method involves acquisition of the response signal followed by time apodization and fast Fourier transformation of the data into the frequency domain, where the magnitude and phase of each harmonic signal can be readily quantified. The method can be implemented on a computer as a software program.

  20. Tunable Electrochemical Properties of Fluorinated Graphene

    SciTech Connect (OSTI)

    Meduri, Praveen; Chen, Honghao; Xiao, Jie; Martinez, Jayson J.; Carlson, Thomas J.; Zhang, Jiguang; Deng, Zhiqun

    2013-06-18

    The structural and electrochemical properties of fluorinated graphene have been investigated by using a series of graphene fluorides (CFx, x=0.47, 0.66, 0.89). Fluorinated graphene exhibited high capacity retentions of 75-81% of theoretical capacity at moderate rates as cathode materials for primary lithium batteries. Specifically, CF0.47 maintained a capacity of 356 mAhg-1 at a 5C rate, superior to that of traditional fluorinated graphite. The discharged graphene fluorides also provide an electrochemical tool to probe the chemical bonding on the parent graphene substrate.

  1. Electrochemical apparatus comprising modified disposable rectangular cuvette

    DOE Patents [OSTI]

    Dattelbaum, Andrew M; Gupta, Gautam; Morris, David E

    2013-09-10

    Electrochemical apparatus includes a disposable rectangular cuvette modified with at least one hole through a side and/or the bottom. Apparatus may include more than one cuvette, which in practice is a disposable rectangular glass or plastic cuvette modified by drilling the hole(s) through. The apparatus include two plates and some means of fastening one plate to the other. The apparatus may be interfaced with a fiber optic or microscope objective, and a spectrometer for spectroscopic studies. The apparatus are suitable for a variety of electrochemical experiments, including surface electrochemistry, bulk electrolysis, and flow cell experiments.

  2. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A.; Townsend, Carl W.

    1989-01-01

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  3. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  4. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  5. Nanomaterial Labels in Electrochemical Immunosensors and Immunoassays

    SciTech Connect (OSTI)

    Liu, Guodong; Lin, Yuehe

    2007-12-15

    This article reviews recent advances in nanomaterial labels in electrochemical immunosensors and immunoassays. Various nanomaterial labels are discussed, including colloidal gold/silver, semiconductor nanoparticles, and markers loaded nanocarriers (carbon nanotubes, apoferritin, silica nanoparticles, and liposome beads). The enormous signal enhancement associated with the use of nanomaterial labels and with the formation of nanomaterial–antibody-antigen assemblies provides the basis for ultrasensitive electrochemical detection of disease-related protein biomarkers, biothreat agents, or infectious agents. In general, all endeavors cited here are geared to achieve one or more of the following goals: signal amplification by several orders of magnitude, lower detection limits, and detecting multiple targets.

  6. Manganese Reduction-Oxidation Drives Plant Debris Decomposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Reduction-Oxidation Drives Plant Debris Decomposition Print Microbial decomposition of plant debris ("litter") is a keystone ecosystem process because it regulates nutrient availability, ecosystem productivity, and carbon (C) cycling. Historically, climate (primarily temperature and precipitation) has been thought to regulate the rate of litter decomposition, which then influences the rate at which nutrients become available and C contained in the litter is released back into

  7. Manganese Reduction-Oxidation Drives Plant Debris Decomposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Reduction-Oxidation Drives Plant Debris Decomposition Print Microbial decomposition of plant debris ("litter") is a keystone ecosystem process because it regulates nutrient availability, ecosystem productivity, and carbon (C) cycling. Historically, climate (primarily temperature and precipitation) has been thought to regulate the rate of litter decomposition, which then influences the rate at which nutrients become available and C contained in the litter is released back into

  8. Manganese Reduction-Oxidation Drives Plant Debris Decomposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Reduction-Oxidation Drives Plant Debris Decomposition Print Microbial decomposition of plant debris ("litter") is a keystone ecosystem process because it regulates nutrient availability, ecosystem productivity, and carbon (C) cycling. Historically, climate (primarily temperature and precipitation) has been thought to regulate the rate of litter decomposition, which then influences the rate at which nutrients become available and C contained in the litter is released back into

  9. Manganese Reduction-Oxidation Drives Plant Debris Decomposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Reduction-Oxidation Drives Plant Debris Decomposition Print Microbial decomposition of plant debris ("litter") is a keystone ecosystem process because it regulates nutrient availability, ecosystem productivity, and carbon (C) cycling. Historically, climate (primarily temperature and precipitation) has been thought to regulate the rate of litter decomposition, which then influences the rate at which nutrients become available and C contained in the litter is released back into

  10. Efficient electrochemical CO2 conversion powered by renewable energy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R.; Zeng, Chenjie; Jin, Rongchao

    2015-06-29

    The catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspond tomore » conversion rates approaching 0.8–1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 106 mol CO2 molcatalyst–1 during a multiday (36 hours total hours) CO2electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 106 and 4 × 106 molCO2 molcatalyst–1 were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies are sufficient to power larger-scale, tonne per day CO2 conversion systems.« less

  11. Lithium based electrochemical cell systems having a degassing agent

    DOE Patents [OSTI]

    Hyung, Yoo-Eup; Vissers, Donald R.; Amine, Khalil

    2012-05-01

    A lithium based electrochemical cell system includes a positive electrode; a negative electrode; an electrolyte; and a degassing agent.

  12. Electrochemical Discovery Laboratory - Joint Center for Energy Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Electrochemical Discovery Laboratory March 28, 2016, Accomplishments The Electrochemical Discovery Laboratory The Electrochemical Discovery Laboratory (EDL) - a key JCESR discovery tool located at Argonne - synthesizes high-quality materials for testing in beyond-lithium-ion batteries and characterizes their properties with state-of-the-art analytical techniques. Read More Electrochemical Discovery Laboratory February 29, 2016, Accomplishments Water as a Catalyst - Improving how

  13. Electrochemical detector integrated on microfabricated capilliary electrophoresis chips

    DOE Patents [OSTI]

    Mathies, Richard A.; Glazer, Alexander N.; Woolley, Adam T.; Lao, Kaigin

    2000-01-01

    A microfabricated capillary electrophoresis chip which includes an integral thin film electrochemical detector for detecting molecules separated in the capillary.

  14. Electrochemical detector integrated on microfabricated capillary electrophoresis chips

    DOE Patents [OSTI]

    Mathies, Richard A.; Glazer, Alexander N.; Lao, Kaiqin; Woolley, Adam T.

    1999-01-01

    A microfabricated capillary electrophoresis chip which includes an integral thin film electrochemical detector for detecting molecules separated in the capillary.

  15. GPS Data Filtration Method for Drive Cycle Analysis Applications

    SciTech Connect (OSTI)

    Duran, A.; Earleywine, M.

    2013-02-01

    When employing GPS data acquisition systems to capture vehicle drive-cycle information, a number of errors often appear in the raw data samples, such as sudden signal loss, extraneous or outlying data points, speed drifting, and signal white noise, all of which limit the quality of field data for use in downstream applications. Unaddressed, these errors significantly impact the reliability of source data and limit the effectiveness of traditional drive-cycle analysis approaches and vehicle simulation software. Without reliable speed and time information, the validity of derived metrics for drive cycles, such as acceleration, power, and distance, become questionable. This study explores some of the common sources of error present in raw onboard GPS data and presents a detailed filtering process designed to correct for these issues. Test data from both light and medium/heavy duty applications are examined to illustrate the effectiveness of the proposed filtration process across the range of vehicle vocations. Graphical comparisons of raw and filtered cycles are presented, and statistical analyses are performed to determine the effects of the proposed filtration process on raw data. Finally, an evaluation of the overall benefits of data filtration on raw GPS data and present potential areas for continued research is presented.

  16. Evaluation Of Electrochemical Machining Technology For Surface Improvements

    Office of Scientific and Technical Information (OSTI)

    In Additive Manufactured Components (Technical Report) | SciTech Connect Evaluation Of Electrochemical Machining Technology For Surface Improvements In Additive Manufactured Components Citation Details In-Document Search Title: Evaluation Of Electrochemical Machining Technology For Surface Improvements In Additive Manufactured Components ORNL Manufacturing Demonstration Facility worked with ECM Technologies LLC to investigate the use of precision electro-chemical machining technology to

  17. The Electrochemical Discovery Laboratory - Joint Center for Energy Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Electrochemical Discovery Laboratory The Electrochemical Discovery Laboratory (EDL) - a key JCESR discovery tool located at Argonne - synthesizes high-quality materials for testing in beyond-lithium-ion batteries and characterizes their properties with state-of-the-art analytical techniques. Download Electrochemical Discovery Laboratory

  18. A high-fidelity harmonic drive model.

    SciTech Connect (OSTI)

    Preissner, C.; Royston, T. J.; Shu, D.

    2012-01-01

    In this paper, a new model of the harmonic drive transmission is presented. The purpose of this work is to better understand the transmission hysteresis behavior while constructing a new type of comprehensive harmonic drive model. The four dominant aspects of harmonic drive behavior - nonlinear viscous friction, nonlinear stiffness, hysteresis, and kinematic error - are all included in the model. The harmonic drive is taken to be a black box, and a dynamometer is used to observe the input/output relations of the transmission. This phenomenological approach does not require any specific knowledge of the internal kinematics. In a novel application, the Maxwell resistive-capacitor hysteresis model is applied to the harmonic drive. In this model, sets of linear stiffness elements in series with Coulomb friction elements are arranged in parallel to capture the hysteresis behavior of the transmission. The causal hysteresis model is combined with nonlinear viscous friction and spectral kinematic error models to accurately represent the harmonic drive behavior. Empirical measurements are presented to quantify all four aspects of the transmission behavior. These measurements motivate the formulation of the complete model. Simulation results are then compared to additional measurements of the harmonic drive performance.

  19. Chapter 18: Variable Frequency Drive Evaluation Protocol

    SciTech Connect (OSTI)

    Romberger, J.

    2014-11-01

    An adjustable-speed drive (ASD) includes all devices that vary the speed of a rotating load, including those that vary the motor speed and linkage devices that allow constant motor speed while varying the load speed. The Variable Frequency Drive Evaluation Protocol presented here addresses evaluation issues for variable-frequency drives (VFDs) installed on commercial and industrial motor-driven centrifugal fans and pumps for which torque varies with speed. Constant torque load applications, such as those for positive displacement pumps, are not covered by this protocol. Other ASD devices, such as magnetic drive, eddy current drives, variable belt sheave drives, or direct current motor variable voltage drives, are also not addressed. The VFD is by far the most common type of ASD hardware. With VFD speed control on a centrifugal fan or pump motor, energy use follows the affinity laws, which state that the motor electricity demand is a cubic relationship to speed under ideal conditions. Therefore, if the motor runs at 75% speed, the motor demand will ideally be reduced to 42% of full load power; however, with other losses it is about 49% of full load power.

  20. Heating hydrocarbon containing formations in a line drive staged process

    DOE Patents [OSTI]

    Miller, David Scott

    2009-07-21

    Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

  1. Wind turbine ring/shroud drive system

    DOE Patents [OSTI]

    Blakemore, Ralph W.

    2005-10-04

    A wind turbine capable of driving multiple electric generators having a ring or shroud structure for reducing blade root bending moments, hub loads, blade fastener loads and pitch bearing loads. The shroud may further incorporate a ring gear for driving an electric generator. In one embodiment, the electric generator may be cantilevered from the nacelle such that the gear on the generator drive shaft is contacted by the ring gear of the shroud. The shroud also provides protection for the gearing and aids in preventing gear lubricant contamination.

  2. Control rod drive for reactor shutdown

    DOE Patents [OSTI]

    McKeehan, Ernest R.; Shawver, Bruce M.; Schiro, Donald J.; Taft, William E.

    1976-01-20

    A means for rapidly shutting down or scramming a nuclear reactor, such as a liquid metal-cooled fast breeder reactor, and serves as a backup to the primary shutdown system. The control rod drive consists basically of an in-core assembly, a drive shaft and seal assembly, and a control drive mechanism. The control rod is driven into the core region of the reactor by gravity and hydraulic pressure forces supplied by the reactor coolant, thus assuring that common mode failures will not interfere with or prohibit scramming the reactor when necessary.

  3. April Blood Drive Announcement | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April Blood Drive Announcement April Blood Drive Announcement The next American Red Cross Blood Drive will take place Tuesday, April 12th from 10 a.m.-4 p.m. in CEBAF Center, Room F113. New and repeat donors are encouraged to attend. To schedule an appointment you can visit redcrossblood.org and enter Sponsor Code: TJNAF. You can also contact Johnie Banks, jbanks@jlab.org or x7539. For donation eligibility requirements, visit: http://www.redcrossblood.org/donating-blood/eligibility-requirements

  4. Method of constructing an improved electrochemical cell

    DOE Patents [OSTI]

    Grimes, Patrick G.; Einstein, Harry

    1984-10-09

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  5. Separator-spacer for electrochemical systems

    DOE Patents [OSTI]

    Grimes, Patrick G.; Einstein, Harry; Newby, Kenneth R.; Bellows, Richard J.

    1983-08-02

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  6. Gas recombination assembly for electrochemical cells

    DOE Patents [OSTI]

    Levy, Isaac; Charkey, Allen

    1989-01-01

    An assembly for recombining gases generated in electrochemical cells wherein a catalyst strip is enveloped within a hydrophobic, gas-porous film which, in turn, is encased between gas-porous, metallic layers. The sandwich construction of metallic layers and film is formed into a spiral with a tab for connection to the cell.

  7. Minimizing electrode contamination in an electrochemical cell

    DOE Patents [OSTI]

    Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

    2014-12-09

    An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

  8. Predicting Electrochemical Windows of Nitrogen Containing Aromatic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecules - Joint Center for Energy Storage Research October 20, 2014, Research Highlights Predicting Electrochemical Windows of Nitrogen Containing Aromatic Molecules Various nitrogen containing aromatic base molecules and a descriptive relationship derived to predict their reduction potentials is shown. Scientific Achievement A descriptive relationship is derived for computing reduction potentials of quinoxaline derivatives from the orbital energies of the neutral molecules without

  9. Direct Drive Wave Energy Buoy

    SciTech Connect (OSTI)

    Rhinefrank, Ken

    2011-11-02

    Presentation from the 2011 Water Peer Review in which principal investigator discusses project progress and results for this project which will be used to inform the utility-scale design process, improve cost estimates, accurately forecast energy production and to observe system operation and survivability.

  10. Electrochemical process for the preparation of nitrogen fertilizers

    DOE Patents [OSTI]

    Jiang, Junhua; Aulich, Ted R; Ignatchenko, Alexey V

    2015-04-14

    Methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia are disclosed. Embodiments include (1) ammonium nitrate produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source: (3) ammonia produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source.

  11. Electrochemical process for the preparation of nitrogen fertilizers

    DOE Patents [OSTI]

    Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

    2012-04-10

    The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia, at low temperature and pressure, preferably at ambient temperature and pressure, utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen or hydrogen equivalent. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be aqueous, non-aqueous, or solid.

  12. Electrochemical process for the preparation of nitrogen fertilizers

    DOE Patents [OSTI]

    Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua

    2013-03-19

    The present invention provides methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia utilizing a source of carbon, a source of nitrogen, and/or a source of hydrogen. Implementing an electrolyte serving as ionic charge carrier, (1) ammonium nitrate is produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers are produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source; (3) ammonia is produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source at the anode; and (4) urea-ammonium nitrate is produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source. The electrolyte can be solid.

  13. National Drive Electric Week | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Celebrate National Drive Electric Week with ways to make your all-electric or plug-in hybrid cars even greener | Photo courtesy of Dennis Schroeder, National Renewable Energy ...

  14. Universal power transistor base drive control unit

    DOE Patents [OSTI]

    Gale, A.R.; Gritter, D.J.

    1988-06-07

    A saturation condition regulator system for a power transistor is disclosed which achieves the regulation objectives of a Baker clamp but without dumping excess base drive current into the transistor output circuit. The base drive current of the transistor is sensed and used through an active feedback circuit to produce an error signal which modulates the base drive current through a linearly operating FET. The collector base voltage of the power transistor is independently monitored to develop a second error signal which is also used to regulate base drive current. The current-sensitive circuit operates as a limiter. In addition, a fail-safe timing circuit is disclosed which automatically resets to a turn OFF condition in the event the transistor does not turn ON within a predetermined time after the input signal transition. 2 figs.

  15. Universal power transistor base drive control unit

    DOE Patents [OSTI]

    Gale, Allan R.; Gritter, David J.

    1988-01-01

    A saturation condition regulator system for a power transistor which achieves the regulation objectives of a Baker clamp but without dumping excess base drive current into the transistor output circuit. The base drive current of the transistor is sensed and used through an active feedback circuit to produce an error signal which modulates the base drive current through a linearly operating FET. The collector base voltage of the power transistor is independently monitored to develop a second error signal which is also used to regulate base drive current. The current-sensitive circuit operates as a limiter. In addition, a fail-safe timing circuit is disclosed which automatically resets to a turn OFF condition in the event the transistor does not turn ON within a predetermined time after the input signal transition.

  16. Consider Steam Turbine Drives for Rotating Equipment

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on steam turbine drives for rotating equipment provides how-to advice for improving the system using low-cost, proven practices and technologies.

  17. Quasi-periodic quantum dot arrays produced by electrochemical synthesis

    SciTech Connect (OSTI)

    Bandyopadhyay, S.; Miller, A.E.; Yue, D.F.; Banerjee, G.; Ricker, R.E.; Jones, S.; Eastman, J.A.; Baugher, E.; Chandrasekhar, M.

    1994-06-01

    We discuss a ``gentle`` electrochemical technique for fabricating quasi-periodic quantum dot arrays. The technique exploits a self-organizing phenomenon to produce quasi-periodic arrangement of dots and provides excellent control over dot size and interdot spacing. Unlike conventional nanolithography, it does not cause radiation damage to the structures during exposure to pattern delineating beams (e-beam, ion-beam or x-ray). Moreover, it does not require harsh processing steps like reactive ion etching, offers a minimum feature size of {approximately}40 {angstrom}, allows the fabrication of structures on nonplanar surfaces (e.g. spherical or cylindrical substrates), is amenable to mass production (millions of wafers can be processed simultaneously) and is potentially orders of magnitude cheaper than conventional nanofabrication. In this paper, we describe our initial results and show the promise of this technique for low-cost and high-yield nanosynthesis.

  18. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  19. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R.

    1990-01-01

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used.

  20. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, R.R.

    1990-11-20

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used. 5 figs.

  1. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley; Szreders, Bernard E.

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  2. Survey of electrochemical production of inorganic compounds. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

  3. Frequency modulation drive for a piezoelectric motor

    DOE Patents [OSTI]

    Mittas, Anthony

    2001-01-01

    A piezoelectric motor has peak performance at a specific frequency f.sub.1 that may vary over a range of frequencies. A drive system is disclosed for operating such a motor at peak performance without feedback. The drive system consists of the motor and an ac source connected to power the motor, the ac source repeatedly generating a frequency over a range from f.sub.1 -.DELTA.x to f.sub.1 +.DELTA.y.

  4. Direct-drive field actuator motors

    DOE Patents [OSTI]

    Grahn, Allen R.

    1995-01-01

    A high-torque, low speed, positive-drive field actuator motor including a stator carrying at least one field actuator which changes in dimension responsive to application of an energy field, and at least one drive shoe movable by the dimensional changes of the field actuator to contact and move a rotor element with respect to the stator. Various embodiments of the motor are disclosed, and the rotor element may be moved linearly or arcuately.

  5. Direct-drive field actuator motors

    DOE Patents [OSTI]

    Grahn, A.R.

    1995-07-11

    A high-torque, low speed, positive-drive field actuator motor is disclosed including a stator carrying at least one field actuator which changes in dimension responsive to application of an energy field, and at least one drive shoe movable by the dimensional changes of the field actuator to contact and move a rotor element with respect to the stator. Various embodiments of the motor are disclosed, and the rotor element may be moved linearly or arcuately. 37 figs.

  6. Semiclassical instability of dynamical warp drives

    SciTech Connect (OSTI)

    Finazzi, Stefano; Liberati, Stefano; Barcelo, Carlos

    2009-06-15

    Warp drives are very interesting configurations in general relativity: At least theoretically, they provide a way to travel at superluminal speeds, albeit at the cost of requiring exotic matter to exist as solutions of Einstein's equations. However, even if one succeeded in providing the necessary exotic matter to build them, it would still be necessary to check whether they would survive to the switching on of quantum effects. Semiclassical corrections to warp-drive geometries have been analyzed only for eternal warp-drive bubbles traveling at fixed superluminal speeds. Here, we investigate the more realistic case in which a superluminal warp drive is created out of an initially flat spacetime. First of all we analyze the causal structure of eternal and dynamical warp-drive spacetimes. Then we pass to the analysis of the renormalized stress-energy tensor (RSET) of a quantum field in these geometries. While the behavior of the RSET in these geometries has close similarities to that in the geometries associated with gravitational collapse, it shows dramatic differences too. On one side, an observer located at the center of a superluminal warp-drive bubble would generically experience a thermal flux of Hawking particles. On the other side, such Hawking flux will be generically extremely high if the exotic matter supporting the warp drive has its origin in a quantum field satisfying some form of quantum inequalities. Most of all, we find that the RSET will exponentially grow in time close to, and on, the front wall of the superluminal bubble. Consequently, one is led to conclude that the warp-drive geometries are unstable against semiclassical backreaction.

  7. Vehicle Technologies Office: U.S. DRIVE | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office: U.S. DRIVE Vehicle Technologies Office: U.S. DRIVE Logo for U.S. DRIVE - Driving Research and Innovation for Vehicle efficiency and Energy sustainability. U.S. DRIVE stands for Driving Research and Innovation for Vehicle efficiency and Energy sustainability. It is a non-binding and voluntary government-industry partnership focused on advanced automotive and related energy infrastructure technology research and development (R&D). Specifically, the Partnership is a

  8. Charging Up with the Electric Drive Transportation Association | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Charging Up with the Electric Drive Transportation Association Charging Up with the Electric Drive Transportation Association May 20, 2014 - 4:51pm Addthis Test Drive 1 of 5 Test Drive Deputy Assistant Secretary for Transportation Reuben Sarkar drives a Chevrolet Spark EV during the Electric Drive Transportation Association conference in Indianapolis, Indiana on May 20, 2014. The conference brings together industry leaders who are advancing electric vehicle technologies and

  9. Electrochemical arsenic remediation for rural Bangladesh

    SciTech Connect (OSTI)

    Addy, Susan Amrose

    2009-01-01

    Arsenic in drinking water is a major public health problem threatening the lives of over 140 million people worldwide. In Bangladesh alone, up to 57 million people drink arsenic-laden water from shallow wells. ElectroChemical Arsenic Remediation(ECAR) overcomes many of the obstacles that plague current technologies and can be used affordably and on a small-scale, allowing for rapid dissemination into Bangladesh to address this arsenic crisis. In this work, ECAR was shown to effectively reduce 550 - 580 mu g=L arsenic (including both As[III]and As[V]in a 1:1 ratio) to below the WHO recommended maximum limit of 10 mu g=L in synthetic Bangladesh groundwater containing relevant concentrations of competitive ions such as phosphate, silicate, and bicarbonate. Arsenic removal capacity was found to be approximately constant within certain ranges of current density, but was found to change substantially between ranges. In order of decreasing arsenic removal capacity, the pattern was: 0.02 mA=cm2> 0.07 mA=cm2> 0.30 - 1.1 mA=cm2> 5.0 - 100 mA=cm2. Current processing time was found to effect arsenic removal capacity independent of either charge density or current density. Electrode polarization studies showed no passivation of the electrode in the tested range (up to current density 10 mA=cm2) and ruled out oxygen evolution as the cause of decreasing removal capacity with current density. Simple settling and decantation required approximately 3 days to achieve arsenic removal comparable to filtration with a 0.1 mu m membrane. X-ray Absorption Spectroscopy (XAS) showed that (1) there is no significant difference in the arsenic removal mechanism of ECAR during operation at different current densities and (2) the arsenic removal mechanism in ECAR is consistent with arsenate adsorption onto a homogenous Fe(III)oxyhydroxide similar in structure to 2-line ferrihydrite. ECAR effectively reduced high arsenic concentrations (100 - 500 mu g=L) in real Bangladesh tube well water collected from three regions to below the WHO limit of 10 mu g=L. Prototype fabrication and field testing are currently underway.

  10. Countries Launch Initiative to Drive Energy Efficiency in the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Countries Launch Initiative to Drive Energy Efficiency in the Commercial and Industrial Sectors Countries Launch Initiative to Drive Energy Efficiency in the Commercial and ...

  11. Supercomputers Drive Discovery of Materials for More Efficient...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercomputers Drive Discovery of Materials for More Efficient Carbon Capture Advanced ... Supercomputers Drive Discovery of Materials for More Efficient Carbon Capture Researchers ...

  12. Strategies for Marketing and Driving Demand for Commercial Financing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Marketing and Driving Demand for Commercial Financing Products Strategies for Marketing and Driving Demand for Commercial Financing Products Better Buildings Neighborhood Program ...

  13. MHK Technologies/Anaconda bulge tube drives turbine | Open Energy...

    Open Energy Info (EERE)

    Anaconda bulge tube drives turbine < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Anaconda bulge tube drives turbine.jpg Technology Profile...

  14. Light-Duty Reactivity Controlled Compression Ignition Drive Cycle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ignition Drive Cycle Fuel Economy and Emissions Estimates Light-Duty Reactivity Controlled Compression Ignition Drive Cycle Fuel Economy and Emissions Estimates Vehicle ...

  15. Performance and mix measurements of indirect drive Cu doped Be...

    Office of Scientific and Technical Information (OSTI)

    Performance and mix measurements of indirect drive Cu doped Be implosions Citation Details In-Document Search Title: Performance and mix measurements of indirect drive Cu doped Be ...

  16. Electric Drive Component Manufacturing: Magna E-Car Systems of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon arravt027apepeaslee2012p.pdf More Documents & Publications Electric Drive Component Manufacturing: Magna E-Car Systems of America, Inc. Electric Drive Component...

  17. Driving Change in Residential Energy Efficiency: Electric Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Driving Change in Residential Energy Efficiency: Electric Vehicles Advanced Programs (301) Driving Change in Residential Energy Efficiency: Electric Vehicles Advanced Programs ...

  18. Vehicle Technologies Office: U.S. DRIVE 2013 Technical Accomplishments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Technical Accomplishments Report Vehicle Technologies Office: U.S. DRIVE 2013 Technical Accomplishments Report The U.S. DRIVE 2013 Highlights of Technical Accomplishments Report ...

  19. US DRIVE Vehicle Systems and Analysis Technical Team Roadmap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    metrics. PDF icon vsattroadmapjune2013.pdf More Documents & Publications US DRIVE Driving Research and Innovation for Vehicle Efficiency and Energy Sustainability ...

  20. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2011 DOE Hydrogen and Fuel Cells ...

  1. Electric Drive Component Manufacturing: Magna E-Car Systems of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Electric Drive Component Manufacturing: Magna E-Car Systems of America, Inc. Electric Drive Component Manufacturing: Magna E-Car Systems of America, ...

  2. Computer-Aided Engineering for Electric-Drive Vehicle Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer-Aided Engineering for Electric-Drive Vehicle Batteries - Sandia Energy Energy ... Energy Storage Components and Systems Batteries Electric Drive Systems Hydrogen Materials ...

  3. EV Everywhere Grand Challenge - Electric Drive (Power Electronics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Electric Drive (Power Electronics and Electric Machines) Workshop EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop List of ...

  4. EV Everywhere Grand Challenge Introduction for Electric Drive...

    Energy Savers [EERE]

    Introduction for Electric Drive Workshop EV Everywhere Grand Challenge Introduction for Electric Drive Workshop Presentation given by EERE Assistant Secretary David Danielson at ...

  5. Electric Drive and Advanced Battery and Components Testbed (EDAB...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Electric Drive and Advanced Battery and Components Testbed (EDAB) Vehicle Technologies Office Merit Review 2014: Electric Drive and Advanced Battery ...

  6. Center for Electric Drive Transportation at the University of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Drive Transportation at the University of Michigan - Dearborn Center for Electric Drive Transportation at the University of Michigan - Dearborn 2012 DOE Hydrogen and Fuel ...

  7. EV Everywhere Workshop: Traction Drive Systems Breakout Group...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EV Everywhere Workshop: Traction Drive Systems Breakout Group Report Presentation given at the EV Everywhere Grand Challenge Electric Drive (Power Electronics and Electric ...

  8. Electric Drive and Advanced Battery and Components Testbed (EDAB...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Evaluation PDF icon vss033carlson2011o.pdf More Documents & Publications Electric Drive and Advanced Battery and Components Testbed (EDAB) Electric Drive and Advanced ...

  9. The drive toward hydrogen vehicles just got shorter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The drive toward hydrogen vehicles just got shorter The drive toward hydrogen vehicles just got shorter Researchers have revealed a new single-stage method for recharging the...

  10. Airlines & Aviation Alternative Fuels: Our Drive to Be Early...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Airlines & Aviation Alternative Fuels: Our Drive to Be Early Market Adopters Airlines & Aviation Alternative Fuels: Our Drive to Be Early Market Adopters Plenary III: Early Market ...

  11. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, F.A.; Townsend, C.W.

    1989-09-12

    An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

  12. Electrochemical cell operation and system

    DOE Patents [OSTI]

    Maru, Hansraj C.

    1980-03-11

    Thermal control in fuel cell operation is affected through sensible heat of process gas by providing common input manifolding of the cell gas flow passage in communication with the cell electrolyte and an additional gas flow passage which is isolated from the cell electrolyte and in thermal communication with a heat-generating surface of the cell. Flow level in the cell gas flow passage is selected based on desired output electrical energy and flow level in the additional gas flow passage is selected in accordance with desired cell operating temperature.

  13. Environmentally Benign Electrolytes With Wide Electrochemical Windows -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Environmentally Benign Electrolytes With Wide Electrochemical Windows DOE Grant Recipients Arizona Technology Enterprises Contact Arizona Technology Enterprises About This Technology Technology Marketing SummaryAs mobile electronics continue to evolve, the need for safe, long-lasting rechargeable batteries has grown tremendously. In the search for suitable materials from which to construct high energy density solid state batteries, one of the principal obstacles has

  14. electrochemical battery stress-induced degradation mechanisms

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrochemical battery stress-induced degradation mechanisms - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle

  15. Electrochemical sensor/detector system and method

    DOE Patents [OSTI]

    Glass, Robert S.; Perone, Sam P.; Ciarlo, Dino R.; Kimmons, James F.

    1992-01-01

    An electrochemical detection system is described comprising in combination: (a) a multielement, microelectrode array detector containing means for acquiring a plurality of signals; (b) electronic means for receiving said signals and converting said signals into a readout or display providing information with respect to the nature and concentration of elements present in a solution being tested. Also described is the means of making the above described microelectrode detector.

  16. Electrochemical sensor/detector system and method

    DOE Patents [OSTI]

    Glass, Robert S.; Perone, Sam P.; Ciarlo, Dino R.; Kimmons, James F.

    1994-01-01

    An electrochemical detection system is described comprising in combination: (a) a multielement, microelectrode array detector containing means for acquiring a plurality of signals; (b) electronic means for receiving said signals and converting said signals into a readout or display providing information with respect to the nature and concentration of elements present in a solution being tested. Also described is the means of making the above described microelectrode detector.

  17. Microcantilever Counter Electrode Electrochemical Sensor in a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Three-Electrode Cell - Energy Innovation Portal Energy Analysis Energy Analysis Early Stage R&D Early Stage R&D Advanced Materials Advanced Materials Find More Like This Return to Search Microcantilever Counter Electrode Electrochemical Sensor in a Three-Electrode Cell Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryResearchers at ORNL have invented a compact, highly accurate system to detect and measure chemicals in solution. The device

  18. Method of making electrodes for electrochemical cell

    DOE Patents [OSTI]

    Kaun, Thomas D.; Kilsdonk, Dennis J.

    1983-01-01

    A method of making an electrode for an electrochemical cell in which particulate electrode-active material is mixed with a liquid organic carrier chemically inert with respect to the electrode-active material, mixing the liquid carrier to form an extrudable slurry. The liquid carrier is present in an amount of from about 10 to about 50 percent by volume of the slurry, and then the carrier is removed from the slurry leaving the electrode-active material.

  19. Electrochemically controlled charging circuit for storage batteries

    DOE Patents [OSTI]

    Onstott, E.I.

    1980-06-24

    An electrochemically controlled charging circuit for charging storage batteries is disclosed. The embodiments disclosed utilize dc amplification of battery control current to minimize total energy expended for charging storage batteries to a preset voltage level. The circuits allow for selection of Zener diodes having a wide range of reference voltage levels. Also, the preset voltage level to which the storage batteries are charged can be varied over a wide range.

  20. Sealed joint structure for electrochemical device

    DOE Patents [OSTI]

    Tucker, Michael C; Jacobson, Craig P; De Jonghe, Lutgard C; Visco, Steven J

    2013-05-21

    Several members make up a joint in a high-temperature electrochemical device, wherein the various members perform different functions. The joint is useful for joining multiple cells (generally tubular modules) of an electrochemical device to produce a multi-cell segment-in-series stack for a solid oxide fuel cell, for instance. The joint includes sections that bond the joining members to each other; one or more seal sections that provide gas-tightness, and sections providing electrical connection and/or electrical insulation between the various joining members. A suitable joint configuration for an electrochemical device has a metal joint housing, a first porous electrode, a second porous electrode, separated from the first porous electrode by a solid electrolyte, and an insulating member disposed between the metal joint housing and the electrolyte and second electrode. One or more brazes structurally and electrically connects the first electrode to the metal joint housing and forms a gas tight seal between the first electrode and the second electrode.

  1. Electrochemical Deposition of Iron Nanoneedles on Titanium Oxide Nanotubes

    SciTech Connect (OSTI)

    Gan Y. X.; Zhang L.; Gan B.J.

    2011-10-01

    Iron as a catalyst has wide applications for hydrogen generation from ammonia, photodecomposition of organics, and carbon nanotube growth. Tuning the size and shape of iron is meaningful for improving the catalysis efficiency. It is the objective of this work to prepare nanostructured iron with high surface area via electrochemical deposition. Iron nanoneedles were successfully electrodeposited on Ti supported TiO2 nanotube arrays in a chlorine-based electrolyte containing 0.15 M FeCl2 {center_dot} 4H2O and 2.0 M HCl. Transmission electron microscopic analysis reveals that the average length of the nanoneedles is about 200 nm and the thickness is about 10 nm. It has been found that a high overpotential at the cathode made of Ti/TiO2 nanotube arrays is necessary for the formation of the nanoneedles. Cyclic voltammetry test indicates that the electrodeposition of iron nanoneedles is a concentration-limited process.

  2. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, J.B.

    1999-02-16

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition are disclosed. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinyl sulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness. 2 figs.

  3. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, John B.

    1999-12-07

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinylsulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness.

  4. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, John B.

    1999-02-16

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinylsulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness.

  5. Investigation of Electrochemical Recovery of Zirconium from Spent Nuclear Fuels

    SciTech Connect (OSTI)

    Michael Simpson; II-Soon Hwang

    2014-06-01

    This project uses both modeling and experimental studies to design optimal electrochemical technology methods for recovery of zirconium from used nuclear fuel rods for more effective waste management. The objectives are to provide a means of efficiently separating zirconium into metallic high-level waste forms and to support development of a process for decontamination of zircaloy hulls to enable their disposal as low- and intermediate-level waste. Modeling work includes extension of a 3D model previously developed by Seoul National University for uranium electrorefining by adding the ability to predict zirconium behavior. Experimental validation activities include tests for recovery of zirconium from molten salt solutions and aqueous tests using surrogate materials. *This is a summary of the FY 2013 progress for I-NERI project # 2010-001-K provided to the I-NERI office.

  6. Passivation Dynamics in the Anisotropic Deposition and Stripping of Bulk Magnesium Electrodes During Electrochemical Cycling

    SciTech Connect (OSTI)

    Wetzel, David J.; Malone, Marvin A.; Haasch, Richard T.; Meng, Yifei; Vieker, Henning; Hahn, Nathan; Golzhauser, Armin; Zuo, Jian-Min; Zavadil, Kevin R.; Gewirth, Andrew A.; Nuzzo, Ralph G.

    2015-08-10

    Rechargeable magnesium (Mg) batteries show promise for use as a next generation technology for high-density energy storage, though little is known about the Mg anode solid electrolyte interphase and its implications for the performance and durability of a Mg-based battery. We explore in this report passivation effects engendered during the electrochemical cycling of a bulk Mg anode, characterizing their influences during metal deposition and dissolution in a simple, nonaqueous, Grignard electrolyte solution (ethylmagnesium bromide, EtMgBr, in tetrahydrofuran). Scanning electron microscopy images of Mg foil working electrodes after electrochemical polarization to dissolution potentials show the formation of corrosion pits. The pit densities so evidenced are markedly potential-dependent. When the Mg working electrode is cycled both potentiostatically and galvanostatically in EtMgBr these pits, formed due to passive layer breakdown, act as the foci for subsequent electrochemical activity. Detailed microscopy, diffraction, and spectroscopic data show that further passivation and corrosion results in the anisotropic stripping of the Mg {0001} plane, leaving thin oxide-comprising passivated side wall structures that demark the {0001} fiber texture of the etched Mg grains. Upon long-term cycling, oxide side walls formed due to the pronounced crystallographic anisotropy of the anodic stripping processes, leading to complex overlay anisotropic, columnar structures, exceeding 50 ?m in height. Finally, the passive responses mediating the growth of these structures appear to be an intrinsic feature of the electrochemical growth and dissolution of Mg using this electrolyte.

  7. Passivation dynamics in the anisotropic deposition and stripping of bulk magnesium electrodes during electrochemical cycling

    SciTech Connect (OSTI)

    Wetzel, David J.; Malone, Marvin A.; Haasch, Richard T.; Meng, Yifei; Vieker, Henning; Hahn, Nathan; Golzhauser, Armin; Zuo, Jian-Min; Zavadil, Kevin R.; Gewirth, Andrew A.; Nuzzo, Ralph G.

    2015-08-10

    Rechargeable magnesium (Mg) batteries show promise for use as a next generation technology for high-density energy storage, though little is known about the Mg anode solid electrolyte interphase and its implications for the performance and durability of a Mg-based battery. We explore in this report passivation effects engendered during the electrochemical cycling of a bulk Mg anode, characterizing their influences during metal deposition and dissolution in a simple, nonaqueous, Grignard electrolyte solution (ethylmagnesium bromide, EtMgBr, in tetrahydrofuran). Scanning electron microscopy images of Mg foil working electrodes after electrochemical polarization to dissolution potentials show the formation of corrosion pits. The pit densities so evidenced are markedly potential-dependent. When the Mg working electrode is cycled both potentiostatically and galvanostatically in EtMgBr these pits, formed due to passive layer breakdown, act as the foci for subsequent electrochemical activity. Detailed microscopy, diffraction, and spectroscopic data show that further passivation and corrosion results in the anisotropic stripping of the Mg {0001} plane, leaving thin oxide-comprising passivated side wall structures that demark the {0001} fiber texture of the etched Mg grains. Upon long-term cycling, oxide side walls formed due to the pronounced crystallographic anisotropy of the anodic stripping processes, leading to complex overlay anisotropic, columnar structures, exceeding 50 ÎŒm in height. Finally, the passive responses mediating the growth of these structures appear to be an intrinsic feature of the electrochemical growth and dissolution of Mg using this electrolyte.

  8. Flower-like NiO structures: Controlled hydrothermal synthesis and electrochemical characteristic

    SciTech Connect (OSTI)

    Chai, Hui; Chen, Xuan; Key Laboratory of Advanced Functional Materials, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, Xinjiang ; Jia, Dianzeng; Key Laboratory of Advanced Functional Materials, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, Xinjiang ; Bao, Shujuan; Key Laboratory of Advanced Functional Materials, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, Xinjiang ; Zhou, Wanyong

    2012-12-15

    Graphical abstract: Flower-like porous NiO was obtained via thermal decomposition of the precursor prepared by a hydrothermal process using hexamethylenetetramine and polyethylene glycol as hydrolysis-controlling agent and surfactant, respectively. The morphology and microstructure of as-synthesized NiO were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results of electrochemical measurements demonstrated that the flower-like porous NiO has high capacity (340 F g{sup ?1}) with excellent cycling performance as electrode materials of electrochemical capacitors (ECs), which may be attributed to the unique microstrcture of NiO. Data analyses indicated that NiO with novel porous structure attractive for practical and large-scale applications in electrochemical capacitors. Display Omitted Highlights: ? Synthesis and characterization of NiO with novel porous structure is presented in this work. ? The electrochemical performance of product was examined. ? NiO with excellent performance as electrode materials may be due to the unique microstrcture. ? NiO with novel porous structure attractive for practical with high capacity (340 F g{sup ?1}). -- Abstract: Flower-like porous NiO was obtained by thermal decomposition of the precursor prepared by a hydrothermal process with hexamethylenetetramine and polyethylene glycol as hydrolysis-controlling agent and surfactant, respectively. The morphology and microstructure of as-synthesized NiO were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The resulting structures of NiO exhibited porous like petal building blocks. The electrochemical measurements’ results demonstrated that flower-like porous NiO has high capacity (340 F g{sup ?1}) with excellent cycling performance as electrode materials for electrochemical capacitors, which may be attributed to the unique structure of NiO. The results indicated that NiO with novel porous structure has been attractive for practical and large-scale applications in electrochemical capacitors.

  9. Lab school supply drive starts July 15

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab school supply drive starts July 15 Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue:May 2016 all issues All Issues » submit Lab school supply drive starts July 15 Anyone can donate supplies through the Lab's Community Programs Office July 1, 2013 Del Norte Credit Union's Baxter Bear takes a moment to pose with some of the backpacks filled with school supplies that will help students start their school year off right Del Norte Credit

  10. Ride and Drive Webinar | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Learn how on-site plug-in electric vehicle Ride and Drives can create value for your organization, your employees, and your community. Read the text version. Listen to this webinar and follow along using the slides below to learn how on-site plug-in electric vehicle (PEV) Ride and Drives can create value for your organization, your employees, and your community. Participants will learn about the value of creating PEV user experiences for increased PEV adoption and will walk away from this

  11. What Drives U.S. Gasoline Prices?

    U.S. Energy Information Administration (EIA) Indexed Site

    What Drives U.S. Gasoline Prices? October 2014 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | What Drives U.S. Gasoline Prices? i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States

  12. Grand Challenge Portfolio: Driving Innovations in Industrial Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency, January 2011 | Department of Energy Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 PDF icon grand_challenges_portfolio.pdf More Documents & Publications Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 8 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January

  13. Electrochemical Membrane for Carbon Dioxide Separation and Power Generation

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Electrochemical Membrane for Carbon Dioxide Separation and Power Generation Citation Details In-Document Search Title: Electrochemical Membrane for Carbon Dioxide Separation and Power Generation uelCell Energy, Inc. (FCE) has developed a novel system concept for separation of carbon dioxide (CO2) from greenhouse gas (GHG) emission sources using an electrochemical membrane (ECM). The salient feature of the ECM is its capability to produce electric

  14. Leveraging National Lab Capabilities in Fuel Cells and Electrochemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems-Phoenix, Arizona | Department of Energy Leveraging National Lab Capabilities in Fuel Cells and Electrochemical Systems-Phoenix, Arizona Leveraging National Lab Capabilities in Fuel Cells and Electrochemical Systems-Phoenix, Arizona August 26, 2015 - 1:45pm Addthis On October 12 and 13, the U.S. Department of Energy's Fuel Cell Technologies Office will host several events at the Electrochemical Energy Summit 2015 in Phoenix, Arizona, to foster increased collaboration between National

  15. Method of determining methane and electrochemical sensor therefor

    DOE Patents [OSTI]

    Zaromb, Solomon; Otagawa, Takaaki; Stetter, Joseph R.

    1986-01-01

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about about 1.4 volts versus R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  16. Electrochemical and infrared studies of the reduction of organic...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electrochemical and infrared studies of the reduction of organic carbonates Citation Details ... Publication Date: 2001-06-01 OSTI Identifier: 821009 Report ...

  17. Microbial Electrochemical Technology (MxCs): Challenges and Opportunit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrochemical Technology (MxCs): Challenges and ... MxC is a platform technology that integrates ... capacity of WW Limits ion transfer in MFC, resulting low ...

  18. A Two-Dimensional Thermal-Electrochemical Model for Prismatic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Two-Dimensional Thermal-Electrochemical Model for Prismatic Lithium Ion Cells National ... readily implemented onto hardware for interfacing with and controlling lithium ion cells. ...

  19. Electrochemical Characterization of Voltage Fade in LMR-NMC cells...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characterization of Voltage Fade in LMR-NMC cells Electrochemical Characterization of Voltage Fade in LMR-NMC cells 2013 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  20. Device and Software to Measure Thermal Impedance of Electrochemical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Device and Software to Measure Thermal Impedance of Electrochemical Systems National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary ...

  1. Advanced Hybrid Water-Heater Using Electrochemical Compression...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bamdad Bahar bamdad.bahar@xergyinc.com Xergy, Inc. Advanced Hybrid Water-Heater Using ... Project Goal: Develop a heat pump water heater utilizing electrochemical ...

  2. Low-Cost Electrochemical Compressor Utilizing Green Refrigerants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrochemical Compressor Utilizing Green Refrigerants for HVAC Applications Low-Cost ... 31, 2017 Funding Opportunity: Building Energy Efficiency Frontiers and Innovation ...

  3. Vehicle Technologies Office Merit Review 2015: INL Electrochemical Performance Testing

    Broader source: Energy.gov [DOE]

    Presentation given by Idaho National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about INL electrochemical...

  4. Vehicle Technologies Office Merit Review 2014: INL Electrochemical Performance Testing

    Broader source: Energy.gov [DOE]

    Presentation given by [company name] at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about INL electrochemical...

  5. Vehicle Technologies Office Merit Review 2014: Electrochemical Performance Testing

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrochemical...

  6. Vehicle Technologies Office Merit Review 2015: Electrochemical Performance Testing

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrochemical...

  7. Electrochemical NOxSensor for Monitoring Diesel Emissions | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy PDF icon pm_02_glass.pdf More Documents & Publications NOxsensor development Electrochemical NOx Sensors for Monitoring Diesel Emissions NOx Sensor Development

  8. Quantitative Electrochemical TEM to Study Alloying for Advanced...

    Office of Scientific and Technical Information (OSTI)

    Title: Quantitative Electrochemical TEM to Study Alloying for Advanced Battery Anodes. Abstract not provided. Authors: Zavadil, Kevin Robert ; Liu, Yang ; Kotula, Paul Gabriel ; ...

  9. Consider Steam Turbine Drives for Rotating Equipment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steam Turbine Drives for Rotating Equipment Consider Steam Turbine Drives for Rotating Equipment This tip sheet outlines the benefits of steam turbine drives for rotating equipment as part of optimized steam systems. STEAM TIP SHEET #21 PDF icon Consider Steam Turbine Drives for Rotating Equipment (January 2012) More Documents & Publications Improving Steam System Performance: A Sourcebook for Industry, Second Edition Adjustable Speed Drive Part-Load Efficiency Benchmark the Fuel Cost of

  10. Improving Motor and Drive System Performance - A Sourcebook for Industry

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Motor and Drive System Performance - A Sourcebook for Industry Improving Motor and Drive System Performance - A Sourcebook for Industry This sourcebook outlines opportunities to improve motor and drive systems performance. The sourcebook is divided into four main sections: Motor and Drive System Basics: Summarizes important terms, relationships, and system design considerations relating to motor and drive systems. Performance Opportunity Road Map: Details the key

  11. Alternative Fuels Data Center: Efficient Driving Behaviors to Conserve Fuel

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Efficient Driving Behaviors to Conserve Fuel to someone by E-mail Share Alternative Fuels Data Center: Efficient Driving Behaviors to Conserve Fuel on Facebook Tweet about Alternative Fuels Data Center: Efficient Driving Behaviors to Conserve Fuel on Twitter Bookmark Alternative Fuels Data Center: Efficient Driving Behaviors to Conserve Fuel on Google Bookmark Alternative Fuels Data Center: Efficient Driving Behaviors to Conserve Fuel on Delicious Rank Alternative Fuels Data Center: Efficient

  12. Electric Drive Vehicle Climate Control Load Reduction | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Test Drive 1 of 5 Test Drive Deputy Assistant Secretary for Transportation Reuben Sarkar drives a Chevrolet Spark EV during the Electric Drive Transportation Association conference in Indianapolis, Indiana on May 20, 2014. The conference brings together industry leaders who are advancing electric vehicle technologies and expanding the nation's charging infrastructure. Image: Photo courtesy of Electric Drive Transportation Association Panel Discussion 2 of 5 Panel Discussion Loan Programs Office

  13. QER- Comment of Electric Drive Transportation Association

    Broader source: Energy.gov [DOE]

    Please find attached the comments of the Electric Drive Transportation Association regarding the first volume of the Department of Energy’s QER. If you have questions about our submittal or require further information, please contact me using the information provided below. Thank you for the opportunity to comment. Genevieve Cullen

  14. Oscillation control system for electric motor drive

    DOE Patents [OSTI]

    Slicker, J.M.; Sereshteh, A.

    1988-08-30

    A feedback system for controlling mechanical oscillations in the torsionally complaint drive train of an electric or other vehicle. Motor speed is converted in a processor to estimate state signals in which a plant model which are used to electronically modify the torque commands applied to the motor. 5 figs.

  15. Oscillation control system for electric motor drive

    DOE Patents [OSTI]

    Slicker, James M.; Sereshteh, Ahmad

    1988-01-01

    A feedback system for controlling mechanical oscillations in the torsionally complaint drive train of an electric or other vehicle. Motor speed is converted in a processor to estimate state signals in which a plant model which are used to electronically modify thetorque commands applied to the motor.

  16. Technology Test Drive: PNNL Offers Exploratory Licenses

    Broader source: Energy.gov [DOE]

    Signing a two-page agreement and paying just $1,000 can get U.S. companies an opportunity to test drive promising technologies through a new, user-friendly commercialization option being offered at the Department of Energy's Pacific Northwest National Laboratory.

  17. Direct-drive inertial confinement fusion: A review

    SciTech Connect (OSTI)

    Craxton, R. S.; Anderson, K. S.; Boehly, T. R.; Goncharov, V. N.; Harding, D. R.; Knauer, J. P.; McCrory, R. L.; McKenty, P. W.; Meyerhofer, D. D.; Myatt, J. F.; Schmitt, A. J.; Sethian, J. D.; Short, R. W.; Skupsky, S.; Theobald, W.; Kruer, W. L.; Tanaka, K.; Betti, R.; Collins, T. J. B.; Delettrez, J. A.; Hu, S. X.; Marozas, J. A.; Maximov, A. V.; Michel, D. T.; Radha, P. B.; Regan, S. P.; Sangster, T. C.; Seka, W.; Solodov, A. A.; Soures, J. M.; Stoeckl, C.; Zuegel, J. D.

    2015-11-25

    In this study, the direct-drive, laser-based approach to inertial confinement fusion (ICF) is reviewed from its inception following the demonstration of the first laser to its implementation on the present generation of high-power lasers. The review focuses on the evolution of scientific understanding gained from target-physics experiments in many areas, identifying problems that were demonstrated and the solutions implemented. The review starts with the basic understanding of laser–plasma interactions that was obtained before the declassification of laser-induced compression in the early 1970s and continues with the compression experiments using infrared lasers in the late 1970s that produced thermonuclear neutrons. The problem of suprathermal electrons and the target preheat that they caused, associated with the infrared laser wavelength, led to lasers being built after 1980 to operate at shorter wavelengths, especially 0.35 um—the third harmonic of the Nd:glass laser—and 0.248 um (the KrF gas laser). The main physics areas relevant to direct drive are reviewed. The primary absorption mechanism at short wavelengths is classical inverse bremsstrahlung. Nonuniformities imprinted on the target by laser irradiation have been addressed by the development of a number of beam-smoothing techniques and imprint-mitigation strategies. The effects of hydrodynamic instabilities are mitigated by a combination of imprint reduction and target designs that minimize the instability growth rates. Several coronal plasma physics processes are reviewed. The two-plasmon–decay instability, stimulated Brillouin scattering (together with cross-beam energy transfer), and (possibly) stimulated Raman scattering are identified as potential concerns, placing constraints on the laser intensities used in target designs, while other processes (self-focusing and filamentation, the parametric decay instability, and magnetic fields), once considered important, are now of lesser concern for mainline direct-drive target concepts. Filamentation is largely suppressed by beam smoothing. Thermal transport modeling, important to the interpretation of experiments and to target design, has been found to be non-local in nature. Advances in shock timing and equation-of-state measurements relevant to direct-drive ICF are reported. Room-temperature implosions have provided an increased understanding of the importance of stability and uniformity. The evolution of cryogenic implosion capabilities, leading to an extensive series carried out on the 60-beam OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)], is reviewed together with major advances in cryogenic target formation. A polar-drive concept has been developed that will enable direct-drive–ignition experiments to be performed on the National Ignition Facility [C. A. Haynam et al., Appl. Opt. 46 (16), 3276 (2007)]. The advantages offered by the alternative approaches of fast ignition and shock ignition and the issues associated with these concepts are described. The lessons learned from target-physics and implosion experiments are taken into account in ignition and high-gain target designs for laser wavelengths of 1/3 ÎŒm and 1/4 ÎŒm. Substantial advances in direct-drive inertial fusion reactor concepts are reviewed. Overall, the progress in scientific understanding over the past five decades has been enormous, to the point that inertial fusion energy using direct drive shows significant promise as a future environmentally attractive energy source.

  18. Direct-drive inertial confinement fusion: A review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Craxton, R. S.; Anderson, K. S.; Boehly, T. R.; Goncharov, V. N.; Harding, D. R.; Knauer, J. P.; McCrory, R. L.; McKenty, P. W.; Meyerhofer, D. D.; Myatt, J. F.; et al

    2015-11-25

    In this study, the direct-drive, laser-based approach to inertial confinement fusion (ICF) is reviewed from its inception following the demonstration of the first laser to its implementation on the present generation of high-power lasers. The review focuses on the evolution of scientific understanding gained from target-physics experiments in many areas, identifying problems that were demonstrated and the solutions implemented. The review starts with the basic understanding of laser–plasma interactions that was obtained before the declassification of laser-induced compression in the early 1970s and continues with the compression experiments using infrared lasers in the late 1970s that produced thermonuclear neutrons. Themore » problem of suprathermal electrons and the target preheat that they caused, associated with the infrared laser wavelength, led to lasers being built after 1980 to operate at shorter wavelengths, especially 0.35 um—the third harmonic of the Nd:glass laser—and 0.248 um (the KrF gas laser). The main physics areas relevant to direct drive are reviewed. The primary absorption mechanism at short wavelengths is classical inverse bremsstrahlung. Nonuniformities imprinted on the target by laser irradiation have been addressed by the development of a number of beam-smoothing techniques and imprint-mitigation strategies. The effects of hydrodynamic instabilities are mitigated by a combination of imprint reduction and target designs that minimize the instability growth rates. Several coronal plasma physics processes are reviewed. The two-plasmon–decay instability, stimulated Brillouin scattering (together with cross-beam energy transfer), and (possibly) stimulated Raman scattering are identified as potential concerns, placing constraints on the laser intensities used in target designs, while other processes (self-focusing and filamentation, the parametric decay instability, and magnetic fields), once considered important, are now of lesser concern for mainline direct-drive target concepts. Filamentation is largely suppressed by beam smoothing. Thermal transport modeling, important to the interpretation of experiments and to target design, has been found to be non-local in nature. Advances in shock timing and equation-of-state measurements relevant to direct-drive ICF are reported. Room-temperature implosions have provided an increased understanding of the importance of stability and uniformity. The evolution of cryogenic implosion capabilities, leading to an extensive series carried out on the 60-beam OMEGA laser [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)], is reviewed together with major advances in cryogenic target formation. A polar-drive concept has been developed that will enable direct-drive–ignition experiments to be performed on the National Ignition Facility [C. A. Haynam et al., Appl. Opt. 46 (16), 3276 (2007)]. The advantages offered by the alternative approaches of fast ignition and shock ignition and the issues associated with these concepts are described. The lessons learned from target-physics and implosion experiments are taken into account in ignition and high-gain target designs for laser wavelengths of 1/3 ÎŒm and 1/4 ÎŒm. Substantial advances in direct-drive inertial fusion reactor concepts are reviewed. Overall, the progress in scientific understanding over the past five decades has been enormous, to the point that inertial fusion energy using direct drive shows significant promise as a future environmentally attractive energy source.« less

  19. Heteroclite electrochemical stability of an I based Li7P2S8I superionic conductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory; Pilar, Kartik; Sahu, Gayatri; Greenbaum, Steve; Liang, Chengdu

    2015-01-01

    Stability from Instability: A Li7P2S8I solid state Li-ion conductor derived from -Li3PS4 and LiI demonstrates exceptional electrochemical stability. The oxidation instability of I is subverted nullified via its incorporation into the coordinated structure. The inclusion of I also creates stability with metallic Li anode while simultaneously improving the interfacial kinetics. Low temperature membrane processability enables facile fabrication of dense membranes, making it suitable for industrial adoption.

  20. Electrochemical mercerization, souring, and bleaching of textiles

    DOE Patents [OSTI]

    Cooper, John F.

    1995-01-01

    Economical, pollution-free treatment of textiles occurs in a low voltage electrochemical cell that mercerizes (or scours), sours, and optionally bleaches without effluents and without the purchase of bulk caustic, neutralizing acids, or bleaches. The cell produces base in the cathodic chamber for mercerization and an equivalent amount of acid in the anodic chamber for neutralizing the fabric. Gas diffusion electrodes are used for one or both electrodes and may simultaneously generate hydrogen peroxide for bleaching. The preferred configuration is a stack of bipolar electrodes, in which one or both of the anode and cathode are gas diffusion electrodes, and where no hydrogen gas is evolved at the cathode.

  1. Electrochemical mercerization, souring, and bleaching of textiles

    DOE Patents [OSTI]

    Cooper, J.F.

    1995-10-10

    Economical, pollution-free treatment of textiles occurs in a low voltage electrochemical cell that mercerizes (or scours), sours, and optionally bleaches without effluents and without the purchase of bulk caustic, neutralizing acids, or bleaches. The cell produces base in the cathodic chamber for mercerization and an equivalent amount of acid in the anodic chamber for neutralizing the fabric. Gas diffusion electrodes are used for one or both electrodes and may simultaneously generate hydrogen peroxide for bleaching. The preferred configuration is a stack of bipolar electrodes, in which one or both of the anode and cathode are gas diffusion electrodes, and where no hydrogen gas is evolved at the cathode. 5 figs.

  2. Methods for performing electrochemical nitration reactions

    DOE Patents [OSTI]

    Lister, Tedd Edward; Fox, Robert Vincent

    2010-05-11

    A method for the electrochemical synthesis of dinitro compounds is disclosed. The method comprises using an anode to oxidize an inactive chemical mediator, such as a ferrocyanide (Fe(CN).sub.6.sup.-4) ion, to an active chemical mediator or oxidizing agent, such as a ferricyanide (Fe(CN).sub.6.sup.-3) ion, in the presence of a differential voltage. The oxidizing agent reacts with a nitro compound and a nitrite ion to form a geminal dinitro compound. The anode may continuously oxidize ferrocyanide to regenerate active ferricyanide, thus keeping sufficient amounts of ferricyanide available for reaction..

  3. Morphology in electrochemically grown conducting polymer films

    DOE Patents [OSTI]

    Rubinstein, I.; Gottesfeld, S.; Sabatani, E.

    1992-04-28

    A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventionally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol. 2 figs.

  4. Morphology in electrochemically grown conducting polymer films

    DOE Patents [OSTI]

    Rubinstein, Israel; Gottesfeld, Shimshon; Sabatani, Eyal

    1992-01-01

    A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventioonally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol.

  5. Method for manufacturing an electrochemical cell

    DOE Patents [OSTI]

    Kaun, Thomas D.; Eshman, Paul F.

    1982-01-01

    A secondary electrochemical cell is prepared by providing positive and negative electrodes having outer enclosures of rigid perforated electrically conductive material defining an internal compartment containing the electrode material in porous solid form. The electrodes are each immersed in molten electrolyte salt prior to cell assembly to incorporate the cell electrolyte. Following solidification of the electrolyte substantially throughout the porous volume of the electrode material, the electrodes are arranged in an alternating positive-negative array with interelectrode separators of porous frangible electrically insulative material. The completed array is assembled into the cell housing and sealed such that on heating the solidified electrolyte flows into the interelectrode separator.

  6. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, Paul A.; Bloom, Ira D.; Roche, Michael F.

    1987-01-01

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

  7. Electrochemical cell assembled in discharged state

    DOE Patents [OSTI]

    Yao, Neng-Ping; Walsh, William J.

    1976-01-01

    A secondary, electrochemical cell is assembled in a completely discharged state within a sealed containment. As assembled, the cell includes a positive electrode separated from a negative electrode by a molten salt electrolyte. The positive electrode is contained within a porous structure, permitting passage of molten electrolyte, and includes one or more layers of a metallic mesh, e.g. iron, impregnated with an intimate mixture of lithium sulfide and the electrolyte. The negative electrode is a porous plaque of aluminum metal. Prior to using the cell, an electrical charge forms lithium-aluminum alloy within the negative electrode and metal sulfide within the positive electrode.

  8. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, P.A.; Bloom, I.D.; Roche, M.F.

    1986-04-17

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with an ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

  9. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, P.A.; Bloom, I.D.; Roche, M.F.

    1987-04-21

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material. 6 figs.

  10. Drive piston assembly for a valve actuator assembly

    DOE Patents [OSTI]

    Sun, Zongxuan

    2010-02-23

    A drive piston assembly is provided that is operable to selectively open a poppet valve. The drive piston assembly includes a cartridge defining a generally stepped bore. A drive piston is movable within the generally stepped bore and a boost sleeve is coaxially disposed with respect to the drive piston. A main fluid chamber is at least partially defined by the generally stepped bore, drive piston, and boost sleeve. First and second feedback chambers are at least partially defined by the drive piston and each are disposed at opposite ends of the drive piston. At least one of the drive piston and the boost sleeve is sufficiently configured to move within the generally stepped bore in response to fluid pressure within the main fluid chamber to selectively open the poppet valve. A valve actuator assembly and engine are also provided incorporating the disclosed drive piston assembly.

  11. Solid electrolyte-electrode system for an electrochemical cell

    DOE Patents [OSTI]

    Tuller, Harry L.; Kramer, Steve A.; Spears, Marlene A.

    1995-01-01

    An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is also provided.

  12. Solid electrolyte-electrode system for an electrochemical cell

    DOE Patents [OSTI]

    Tuller, H.L.; Kramer, S.A.; Spears, M.A.

    1995-04-04

    An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is also provided. 17 figures.

  13. Electrochemical aspects of stress-corrosion crack growth

    SciTech Connect (OSTI)

    Newman, R.C.; Sieradzki, K.

    1982-06-01

    Some contributions of electrochemical methods to the understanding of stress-corrosion cracking are described, with examples drawn from studies of stainless steels, nickel alloys and brasses. Considerations related to the local alloy composition, solution composition and electrode potential within a crack are classified and illustrated. The relationship between electrochemical and acoustic noise is discussed.

  14. Electrochemical NOx Sensors for Monitoring Diesel Emissions | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs PDF icon deer10_woo.pdf More Documents & Publications NOxsensor development NOx sensor development Electrochemical NOxSensor for Monitoring Diesel Emissions

  15. Porous siliconformation and etching process for use in silicon micromachining

    DOE Patents [OSTI]

    Guilinger, Terry R.; Kelly, Michael J.; Martin, Jr., Samuel B.; Stevenson, Joel O.; Tsao, Sylvia S.

    1991-01-01

    A reproducible process for uniformly etching silicon from a series of micromechanical structures used in electrical devices and the like includes providing a micromechanical structure having a silicon layer with defined areas for removal thereon and an electrochemical cell containing an aqueous hydrofluoric acid electrolyte. The micromechanical structure is submerged in the electrochemical cell and the defined areas of the silicon layer thereon are anodically biased by passing a current through the electrochemical cell for a time period sufficient to cause the defined areas of the silicon layer to become porous. The formation of the depth of the porous silicon is regulated by controlling the amount of current passing through the electrochemical cell. The micromechanical structure is then removed from the electrochemical cell and submerged in a hydroxide solution to remove the porous silicon. The process is subsequently repeated for each of the series of micromechanical structures to achieve a reproducibility better than 0.3%.

  16. Sensor apparatus using an electrochemical cell

    DOE Patents [OSTI]

    Thakur, Mrinal

    2003-07-01

    A method for sensing mechanical quantities such as force, stress, strain, pressure and acceleration is disclosed. This technology is based on a change in the electrochemically generated voltage (electromotive force) with application of force, stress, strain, pressure or acceleration. The change in the voltage is due to a change in the internal resistance of the electrochemical cell with a change in the relative position or orientation of the electrodes (anode and cathode) in the cell. The signal to be detected (e.g. force, stress, strain, pressure or acceleration) is applied to one of the electrodes to cause a change in the relative position or orientation between the electrodes. Various materials, solid, semisolid, gel, paste or liquid can be utilized as the electrolyte. The electrolyte must be an ion conductor. The examples of solid electrolytes include specific polymer conductors, polymer composites, ion conducting glasses and ceramics. The electrodes are made of conductors such as metals with dissimilar electro negativities. Significantly enhanced sensitivities, up to three orders of magnitude higher than that of comparable commercial sensors, are obtained. The materials are substantially less expensive than commercially used materials for mechanical sensors. An apparatus for sensing such mechanical quantities using materials such as doped 1,4 cis-polyisopropene and nafion. The 1,4 cis-polyisopropene may be doped with lithium perchlorate or iodine. The output voltage signal increases with an increase of the sensing area for a given stress. The device can be used as an intruder alarm, among other applications.

  17. Sensor apparatus using an electrochemical cell

    DOE Patents [OSTI]

    Thakur, Mrinal

    2002-01-01

    A novel technology for sensing mechanical quantities such as force, stress, strain, pressure and acceleration has been invented. This technology is based on a change in the electrochemically generated voltage (electromotive force) with application of force, stress, strain, pressure or acceleration. The change in the voltage is due to a change in the internal resistance of the electrochemical cell with a change in the relative position or orientation of the electrodes (anode and cathode) in the cell. The signal to be detected (e.g. force, stress, strain, pressure or acceleration) is applied to one of the electrodes to cause a change in the relative position or orientation between the electrodes. Various materials, solid, semisolid, gel, paste or liquid can be utilized as the electrolyte. The electrolyte must be an ion conductor. The examples of solid electrolytes include specific polymer conductors, polymer composites, ion conducting glasses and ceramics. The electrodes are made of conductors such as metals with dissimilar electronegativities. Significantly enhanced sensitivities, up to three orders of magnitude higher than that of comparable commercial sensors, are obtained. The materials are substantially less expensive than commercially used materials for mechanical sensors.

  18. Modeling the Performance and Cost of Lithium-Ion Batteries for Electric-Drive Vehicles - SECOND EDITION

    SciTech Connect (OSTI)

    Nelson, Paul A.; Gallagher, Kevin G.; Bloom, Ira D.; Dees, Dennis W.

    2012-01-01

    This report details the Battery Performance and Cost model (BatPaC) developed at Argonne National Laboratory for lithium-ion battery packs used in automotive transportation. The model designs the battery for a specified power, energy, and type of vehicle battery. The cost of the designed battery is then calculated by accounting for every step in the lithium-ion battery manufacturing process. The assumed annual production level directly affects each process step. The total cost to the original equipment manufacturer calculated by the model includes the materials, manufacturing, and warranty costs for a battery produced in the year 2020 (in 2010 US$). At the time this report is written, this calculation is the only publicly available model that performs a bottom-up lithium-ion battery design and cost calculation. Both the model and the report have been publicly peer-reviewed by battery experts assembled by the U.S. Environmental Protection Agency. This report and accompanying model include changes made in response to the comments received during the peer-review. The purpose of the report is to document the equations and assumptions from which the model has been created. A user of the model will be able to recreate the calculations and perhaps more importantly, understand the driving forces for the results. Instructions for use and an illustration of model results are also presented. Almost every variable in the calculation may be changed by the user to represent a system different from the default values pre-entered into the program. The distinct advantage of using a bottom-up cost and design model is that the entire power-to-energy space may be traversed to examine the correlation between performance and cost. The BatPaC model accounts for the physical limitations of the electrochemical processes within the battery. Thus, unrealistic designs are penalized in energy density and cost, unlike cost models based on linear extrapolations. Additionally, the consequences on cost and energy density from changes in cell capacity, parallel cell groups, and manufacturing capabilities are easily assessed with the model. New proposed materials may also be examined to translate bench-scale values to the design of full-scale battery packs providing realistic energy densities and prices to the original equipment manufacturer.

  19. Integrated Inverter For Driving Multiple Electric Machines

    DOE Patents [OSTI]

    Su, Gui-Jia [Knoxville, TN; Hsu, John S [Oak Ridge, TN

    2006-04-04

    An electric machine drive (50) has a plurality of inverters (50a, 50b) for controlling respective electric machines (57, 62), which may include a three-phase main traction machine (57) and two-phase accessory machines (62) in a hybrid or electric vehicle. The drive (50) has a common control section (53, 54) for controlling the plurality of inverters (50a, 50b) with only one microelectronic processor (54) for controlling the plurality of inverters (50a, 50b), only one gate driver circuit (53) for controlling conduction of semiconductor switches (S1-S10) in the plurality of inverters (50a, 50b), and also includes a common dc bus (70), a common dc bus filtering capacitor (C1) and a common dc bus voltage sensor (67). The electric machines (57, 62) may be synchronous machines, induction machines, or PM machines and may be operated in a motoring mode or a generating mode.

  20. Heating and current drive systems for TPX

    SciTech Connect (OSTI)

    Swain, D.; Goranson, P.; Halle, A. von; Bernabei, S.; Greenough, N.

    1994-05-24

    The heating and current drive (H and CD) system proposed for the TPX tokamak will consist of ion cyclotron, neutral beam, and lower hybrid systems. It will have 17.5 MW of installed H and CD power initially, and can be upgraded to 45 MW. It will be used to explore advanced confinement and fully current-driven plasma regimes with pulse lengths of up to 1,000 s.

  1. NEUTRONIC REACTOR CONTROL ROD DRIVE APPARATUS

    DOE Patents [OSTI]

    Oakes, L.C.; Walker, C.S.

    1959-12-15

    ABS>A suspension mechanism between a vertically movable nuclear reactor control rod and a rod extension, which also provides information for the operator or an automatic control signal, is described. A spring connects the rod extension to a drive shift. The extension of the spring indicates whether (1) the rod is at rest on the reactor, (2) the rod and extension are suspended, or (3) the extension alone is suspended, the spring controlling a 3-position electrical switch.

  2. Collaboration drives achievement in protein structure research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protein structure research Collaboration drives achievement in protein structure research By tracking down how bacterial defense systems work, the scientists can potentially fight infectious diseases and genetic disorders. September 15, 2014 Thomas Terwilliger Thomas Terwilliger Contact Nancy Ambrosiano Communications Office (505) 667-0471 Email "It is tremendously exciting working with researchers around the world, helping them apply the software and algorithms that we have developed to

  3. MEDIUM VOLTAGE INTEGRATED DRIVE AND MOTOR

    Broader source: Energy.gov [DOE]

    Calnetix Technologies – Cerritos, CA This project will focus on integrating a high voltage SiC device with advanced high-speed machine technology, medium voltage stators, high efficiency magnetic bearings and sensor high frequency drive technology that can work directly with high voltages, switch at high frequencies for low machine losses, and do so very efficiently. The new medium voltage motors are expected to achieve up to eight times the power density of similar traditional systems. Fact sheet coming soon.

  4. Fast wave current drive in DEMO

    SciTech Connect (OSTI)

    Lerche, E.; Van Eestera, D.; Messiaen, A.; Collaboration: EFDA-PPPT Contributors

    2014-02-12

    The ability to non-inductively drive a large fraction of the toroidal plasma current in magnetically confined plasmas is an essential requirement for steady state fusion reactors such as DEMO. Besides neutral beam injection (NBI), electron-cyclotron resonance heating (ECRH) and lower hybrid wave heating (LH), ion-cyclotron resonance heating (ICRH) is a promising candidate to drive current, in particular at the high temperatures expected in fusion plasmas. In this paper, the current drive (CD) efficiencies calculated with coupled ICRF wave / CD numerical codes for the DEMO-1 design case (R{sub 0}=9m, B{sub 0}=6.8T, a{sub p}=2.25m) [1] are presented. It will be shown that although promising CD efficiencies can be obtained in the usual ICRF frequency domain (20-100MHz) by shifting the dominant ion-cyclotron absorption layers to the high-field side, operation at higher frequencies (100-300MHz) has a stronger CD potential, provided the parasitic RF power absorption of the alpha particles can be minimized.

  5. Mediated electrochemical oxidation treatment for Rocky Flats combustible low-level mixed waste. Final report, FY 1993 and 1994

    SciTech Connect (OSTI)

    Chiba, Z.; Lewis, P.R.; Murguia, L.C.

    1994-09-01

    Mediated Electrochemical Oxidation (MEO) is an aqueous process which destroys hazardous organics by oxidizing a mediator at the anode of an electrochemical cell; the mediator in turn oxidizes the organics within the bulk of the electrolyte. With this process organics can be nearly completely destroyed, that is, the carbon and hydrogen present in the hydrocarbon are almost entirely mineralized to carbon dioxide and water. The MEO process is also capable of dissolving radioactive materials, including difficult-to-dissolve compounds such as plutonium oxide. Hence, this process can treat mixed wastes, by destroying the hazardous organic components of the waste, and dissolving the radioactive components. The radioactive material can be recovered if desired, or disposed of as non-mixed radioactive waste. The process is inherently safe, since the hazardous and radioactive materials are completely contained in the aqueous phase, and the system operates at low temperatures (below 80{degree}C) and at ambient pressures.

  6. Dynamic Characterization of Dendrite Deposition and Growth in Li-Surface by Electrochemical Impedance Spectroscopy

    SciTech Connect (OSTI)

    Hernandez-Maya, R; Rosas, O; Saunders, J; Castaneda, H

    2015-01-13

    The evolution of dendrite formation is characterized by DC and AC electrochemical techniques. Interfacial mechanisms for lithium deposition are described and quantified by electrochemical impedance spectroscopy (EIS) between a lithium electrode and a graphite electrode. The initiation and growth of dendrites in the lithium surface due to the cathodic polarization conditions following anodic dissolution emulate long term cycling process occurring in the lithium electrodes. The dendrite initiation at the lithium/organic electrolyte interface is proposed to be performed through a combination of layering and interfacial reactions during different cathodic conditions. The growth is proposed to be performed by surface geometrical deposition. In this work, we use EIS in galvanostatic mode to assess the initiation and growth stages of dendrites by the accumulation of precipitates formed under different current conditions. The lithium/organic solvent experimental system using frequency domain techniques is validated by the theoretical approach using a deterministic model that accounts for the faradaic processes at the interface assuming a coverage fraction of the electrodic surface affected by the dendritic growth. (C) 2015 The Electrochemical Society. All rights reserved.

  7. A hydrogen peroxide electrochemical sensor based on silver nanoparticles decorated three-dimensional graphene

    SciTech Connect (OSTI)

    Zhan, Beibei; Liu, Changbing; Shi, Huaxia; Li, Chen; Wang, Lianhui [Key Laboratory for Organic Electronics and Information Displays (KLOEID), Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Huang, Wei, E-mail: iamxcdong@njtech.edu.cn, E-mail: iamwhuang@njtech.edu.cn; Dong, Xiaochen, E-mail: iamxcdong@njtech.edu.cn, E-mail: iamwhuang@njtech.edu.cn [Key Laboratory for Organic Electronics and Information Displays (KLOEID), Nanjing University of Posts and Telecommunications, Nanjing 210023 (China); Jiangsu-Singapore Joint Research Center for Organic/Bio-Electronics and Information Displays and Institute of Advanced Materials (IAM), Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816 (China)

    2014-06-16

    A facile strategy has been developed to synthesize sliver nanoparticles (Ag NPs) decorated three-dimensional graphene (3DG) through hydrothermal process. The AgNPs-3DG composites are directly fabricated into a free standing sensing electrode for electrochemical detection of hydrogen peroxide (H{sub 2}O{sub 2}) in phosphate buffered solutions. Various techniques equipments including scanning electron microscopy, X-ray diffraction, and Raman spectroscopy are used to characterize the morphology and structure of the as-prepared composite. The electrochemical experiments reveal the AgNPs-3DG based biosensor exhibits fast amperometric sensing, low detection limitation, wide linear responding range, and perfect selectivity for non-enzyme H{sub 2}O{sub 2} detection, indicating the well synergistic effect of Ag NPs high electrocatalytic activity and 3DG high conductivity and large surface area.

  8. Modeling the performance and cost of lithium-ion batteries for electric-drive vehicles.

    SciTech Connect (OSTI)

    Nelson, P. A. Gallagher, K. G. Bloom, I. Dees, D. W.

    2011-10-20

    This report details the Battery Performance and Cost model (BatPaC) developed at Argonne National Laboratory for lithium-ion battery packs used in automotive transportation. The model designs the battery for a specified power, energy, and type of vehicle battery. The cost of the designed battery is then calculated by accounting for every step in the lithium-ion battery manufacturing process. The assumed annual production level directly affects each process step. The total cost to the original equipment manufacturer calculated by the model includes the materials, manufacturing, and warranty costs for a battery produced in the year 2020 (in 2010 US$). At the time this report is written, this calculation is the only publically available model that performs a bottom-up lithium-ion battery design and cost calculation. Both the model and the report have been publically peer-reviewed by battery experts assembled by the U.S. Environmental Protection Agency. This report and accompanying model include changes made in response to the comments received during the peer-review. The purpose of the report is to document the equations and assumptions from which the model has been created. A user of the model will be able to recreate the calculations and perhaps more importantly, understand the driving forces for the results. Instructions for use and an illustration of model results are also presented. Almost every variable in the calculation may be changed by the user to represent a system different from the default values pre-entered into the program. The distinct advantage of using a bottom-up cost and design model is that the entire power-to-energy space may be traversed to examine the correlation between performance and cost. The BatPaC model accounts for the physical limitations of the electrochemical processes within the battery. Thus, unrealistic designs are penalized in energy density and cost, unlike cost models based on linear extrapolations. Additionally, the consequences on cost and energy density from changes in cell capacity, parallel cell groups, and manufacturing capabilities are easily assessed with the model. New proposed materials may also be examined to translate bench-scale values to the design of full-scale battery packs providing realistic energy densities and prices to the original equipment manufacturer. The model will be openly distributed to the public in the year 2011. Currently, the calculations are based in a Microsoft{reg_sign} Office Excel spreadsheet. Instructions are provided for use; however, the format is admittedly not user-friendly. A parallel development effort has created an alternate version based on a graphical user-interface that will be more intuitive to some users. The version that is more user-friendly should allow for wider adoption of the model.

  9. DOE Releases U.S. DRIVE Technical Accomplishments Report

    Office of Energy Efficiency and Renewable Energy (EERE)

    The DOE's Vehicle Technologies Office recently released the 2013 U.S. DRIVE Technical Accomplishments report, which describes nearly 70 key achievements of DOE-funded projects carried out by U.S. DRIVE partners.

  10. Columbia Power Technologies, Inc. Deploys its Direct Drive Wave...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Columbia Power Technologies, Inc. Deploys its Direct Drive Wave Energy Buoy Columbia Power Technologies, Inc. Deploys its Direct Drive Wave Energy Buoy April 9, 2013 - 12:00am ...

  11. Test Driving the Toyota Mirai | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Test Driving the Toyota Mirai Test Driving the Toyota Mirai Watch Secretary Ernest Moniz take a spin in the Toyota Mirai, the first fuel cell electric vehicle available for sale.

  12. U.S. Employers Drive Change with Workplace Charging | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... on employees but also on their local communities. "The savings and benefits recognized ... PEV-driving employees and a best practice goal of meeting all PEV-driving employee demand. ...

  13. DRIVE(tm) Mobile App | Open Energy Information

    Open Energy Info (EERE)

    handle all of the details related to sending incentives, provide real time status of offer accepts, and validate points earned. The DRIVE System includes the DRIVE App as a fun...

  14. Fact #759: December 24, 2012 Rural vs. Urban Driving Differences

    Broader source: Energy.gov [DOE]

    According to the National Household Travel Survey, those living in rural areas drive ten more miles in a day than those who live in cities. People living in the suburbs drive only about three to...

  15. Workplace Charging Challenge: Workplace PEV Ride and Drive

    Broader source: Energy.gov [DOE]

    Workplace plug-in electric vehicle (PEV) Ride and Drive events are one of the most effective ways to drive PEV adoption. By providing staff the opportunity to experience PEVs first hand, they can...

  16. U.S. DRIVE Highlights of Technical Accomplishments 2012 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 U.S. DRIVE Highlights of Technical Accomplishments 2012 This document provides a collection of all U.S. DRIVE Technical Teams achieved in 2012. PDF icon 2012usdriveaccomplishme...

  17. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2012 DOE Hydrogen and Fuel Cells Program ...

  18. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Scientific and Technical Information (OSTI)

    High-Voltage Solid Polymer Batteries for Electric Drive Vehicles Citation Details In-Document Search Title: High-Voltage Solid Polymer Batteries for Electric Drive Vehicles The purpose ...

  19. Vehicle Technologies Office Merit Review 2015: Electric Drive...

    Energy Savers [EERE]

    Electric Drive Inverter R&D Vehicle Technologies Office Merit Review 2015: Electric Drive Inverter R&D Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and ...

  20. Secrets of the Motor That Drives Archaea Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Secrets of the Motor That Drives Archaea Revealed Secrets of the Motor That Drives Archaea Revealed Print Thursday, 14 February 2013 00:00 An international team led by John Tainer...

  1. Marketing & Driving Demand Collaborative - Social Media Tools & Strategies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy & Driving Demand Collaborative - Social Media Tools & Strategies Marketing & Driving Demand Collaborative - Social Media Tools & Strategies Presentation slides from the Better Buildings webinar on January 6, 2011. PDF icon Marketing & Driving Demand Collaborative More Documents & Publications Using Social Media for Long-Term Branding Marketing & Driving Demand: Social Media Tools & Strategies - January 16, 2011 (Text Version) Generating

  2. Using Partnerships to Drive Demand and Provide Services in Communities |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Partnerships to Drive Demand and Provide Services in Communities Using Partnerships to Drive Demand and Provide Services in Communities Better Buildings Neighborhood Program Multifamily and Low-Income Peer Exchange Call: Using Partnerships to Drive Demand and Provide Services in Communities, February 2, 2012. PDF icon Call Slides and Discussion Summary More Documents & Publications Strategies for Marketing and Driving Demand for Commercial Financing Products

  3. Vehicle Technologies Office: 2014 Electric Drive Technologies Annual

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Progress Report | Department of Energy Electric Drive Technologies Annual Progress Report Vehicle Technologies Office: 2014 Electric Drive Technologies Annual Progress Report The Electric Drive Technologies research and development (R&D) subprogram within the DOE Vehicle Technologies Office (VTO) provides support and guidance for many cutting-edge automotive technologies under development. Research is focused on developing power electronics (PE), electric motor, and traction drive system

  4. Vehicle Technologies Office: US DRIVE Partnership Plan, Roadmaps, and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Accomplishments | Department of Energy US DRIVE Partnership Plan, Roadmaps, and Accomplishments Vehicle Technologies Office: US DRIVE Partnership Plan, Roadmaps, and Accomplishments U.S. DRIVE roadmaps and previous accomplishments reports are available for reference and information. Partnership Plan U.S. DRIVE Partnership Plan - April 2016 Roadmaps Advanced Combustion and Emissions Control: Advanced Combustion and Emission Control Technical Team Roadmap Electrical and Electronics: Electrical

  5. Grand Challenge Portfolio: Driving Innovations in Industrial Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency, January 2011 - pg 6 | Department of Energy 6 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 6 PDF icon grand_challenges_portfolio_pg6.pdf More Documents & Publications Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 8 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 9

  6. Center for Electric Drive Transportation at the University of Michigan -

    Broader source: Energy.gov (indexed) [DOE]

    Dearborn | Department of Energy ti020_mi_2012_p.pdf More Documents & Publications Center for Electric Drive Transportation at the University of Michigan - Dearborn Vehicle Technologies Office Merit Review 2014: GATE Center for Electric Drive Transportation at the University of Michigan - Dearborn Vehicle Technologies Office Merit Review 2015: GATE Center for Electric Drive Transportation

  7. Thermal regeneration of an electrochemical concentration cell

    DOE Patents [OSTI]

    Krumpelt, Michael; Bates, John K.

    1981-01-01

    A system and method for thermally regenerating an electrochemical concentration cell having first and second aluminum electrodes respectively positioned in contact with first and second electrolytes separated by an ion exchange member, the first and second electrolytes being composed of different concentrations of an ionic solvent and a salt, preferably an aluminum halide. The ionic solvent may be either organic or inorganic with a relatively low melting point, the ionic solvent and the salt form a complex wherein the free energy of formation of said complex is less than about -5 Kcal/mole. A distillation column using solar heat or low grade industrial waste heat receives the first and second electrolytes and thermally decomposes the salt-solvent complex to provide feed material for the two half cells.

  8. Thermal regeneration of an electrochemical concentration cell

    DOE Patents [OSTI]

    Krumpelt, M.; Bates, J.K.

    1980-05-09

    A system and method are described for thermally regenerating an electrochemical concentration cell having first and second aluminum electrodes respectively positioned in contact with first and second electrolytes separated by an ion exchange member, the first and second electrolytes being composed of different concentrations of an ionic solvent and a salt, preferably an aluminum halide. The ionic solvent may be either organic or inorganic with a relatively low melting point, the ionic solvent and the salt form a complex wherein the free energy of formation of said complex is less than about -5 kcal/mole. A distillation column using solar heat or low grade industrial waste heat receives the first and second electrolytes and thermally decomposes the salt-solvent complex to provide feed material for the two half cells.

  9. Composite electrode for use in electrochemical cells

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Huff, James R.; Leddy, Johna

    1989-01-01

    A porous composite electrode for use in electrochemical cells. The electrode has a first face and a second face defining a relatively thin section therebetween. The electrode is comprised of an ion conducting material, an electron conducting material, and an electrocatalyst. The volume concentration of the ion conducting material is greatest at the first face and is decreased across the section, while the volume concentration of the electron conducting material is greatest at the second face and decreases across the section of the electrode. Substantially all of the electrocatalyst is positioned within the electrode section in a relatively narrow zone where the rate of electron transport of the electrode is approximately equal to the rate of ion transport of the electrode.

  10. Electrochemical cell and negative electrode therefor

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1982-01-01

    A secondary electrochemical cell with the positive and negative electrodes separated by a molten salt electrolyte with the negative electrode comprising a particulate mixture of lithium-aluminum alloy and electrolyte and an additive selected from graphitized carbon, Raney iron or mixtures thereof. The lithium-aluminum alloy is present in the range of from about 45 to about 80 percent by volume of the negative electrode, and the electrolyte is present in an amount not less than about 10 percent by volume of the negative electrode. The additive of graphitized carbon is present in the range of from about 1 to about 10 percent by volume of the negative electrode, and the Raney iron additive is present in the range of from about 3 to about 10 percent by volume of the negative electrode.

  11. Electrochemical Cell Design With A Hollow Gate

    DOE Patents [OSTI]

    Romero, Antonio; Oweis, Salah; Chagnon, Guy; Staniewicz, Robert; Briscoe, Douglas

    2000-02-01

    An electrochemical cell having a spiral winding around a central core, wherein the central core is provided with longitudinal grooves on its outer surface to facilitate electrolyte filing and accommodate overpressure. The core itself improves dissipation of heat generated along the center of the cell, and the hollow core design allows the cell core to have a larger radius, permitting the "jelly roll" winding to begin at a larger radius and thereby facilitate the initial turns of the winding by decreasing the amount of bending required of the electrode laminate at the beginning of the winding operation. The hollow core also provides mechanical support end-to-end. A pair of washers are used at each end of the cell to sandwich current collection tabs in a manner that improves electrical and thermal conductivity while also providing structural integrity.

  12. Method for making an electrochemical cell

    DOE Patents [OSTI]

    Bates, J.B.; Dudney, N.J.

    1996-10-22

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making the same, having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C. 9 figs.

  13. Method for making an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B.; Dudney, Nancy J.

    1996-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  14. Electrochemical cell and method of assembly

    DOE Patents [OSTI]

    Shimotake, Hiroshi; Voss, Ernst C. H.; Bartholme, Louis G.

    1979-01-01

    A method of preparing an electrochemical cell is disclosed which permits the assembly to be accomplished in air. The cell includes a metal sulfide as the positive electrode reactant, lithium alloy as the negative electrode reactant and an alkali metal, molten salt electrolyte. Positive electrode reactant is introduced as Li.sub.2 FeS.sub.2, a single-phase compound produced by the reaction of Li.sub.2 S and FeS. The use of this compound permits introduction of lithium in an oxidized form. Additional lithium can be introduced in the negative electrode structure enclosed within an aluminum foil envelope between layers of porous aluminum. Molten salt electrolyte is added after assembly and evacuation of the cell by including an interelectrode separator that has been prewet with an organic solution of KCl.

  15. Electrochemical cell having cylindrical electrode elements

    DOE Patents [OSTI]

    Nelson, Paul A. (Wheaton, IL); Shimotake, Hiroshi (Hinsdale, IL)

    1982-01-01

    A secondary, high temperature electrochemical cell especially adapted for lithium alloy negative electrodes, transition metal chalcogenide positive electrodes and alkali metal halide or alkaline earth metal halide electrolyte is disclosed. The cell is held within an elongated cylindrical container in which one of the active materials is filled around the outside surfaces of a plurality of perforate tubular current collectors along the length of the container. Each of the current collector tubes contain a concentric tubular layer of electrically insulative ceramic as an interelectrode separator. The active material of opposite polarity in elongated pin shape is positioned longitudinally within the separator layer. A second electrically conductive tube with perforate walls can be swagged or otherwise bonded to the outer surface of the pin as a current collector and the electrically insulative ceramic layer can be coated or otherwise layered onto the outer surface of this second current collector. Alternatively, the central pin electrode can include an axial core as a current collector.

  16. Graphene nanocomposites for electrochemical cell electrodes

    DOE Patents [OSTI]

    Zhamu, Aruna; Jang, Bor Z.; Shi, Jinjun

    2015-11-19

    A composite composition for electrochemical cell electrode applications, the composition comprising multiple solid particles, wherein (a) a solid particle is composed of graphene platelets dispersed in or bonded by a first matrix or binder material, wherein the graphene platelets are not obtained from graphitization of the first binder or matrix material; (b) the graphene platelets have a length or width in the range of 10 nm to 10 .mu.m; (c) the multiple solid particles are bonded by a second binder material; and (d) the first or second binder material is selected from a polymer, polymeric carbon, amorphous carbon, metal, glass, ceramic, oxide, organic material, or a combination thereof. For a lithium ion battery anode application, the first binder or matrix material is preferably amorphous carbon or polymeric carbon. Such a composite composition provides a high anode capacity and good cycling response. For a supercapacitor electrode application, the solid particles preferably have meso-scale pores therein to accommodate electrolyte.

  17. Composite electrode for use in electrochemical cells

    DOE Patents [OSTI]

    Vanderborgh, N.E.; Huff, J.R.; Leddy, J.

    1987-10-16

    A porous composite electrode for use in electrochemical cells. The electrode has a first face and a second face defining a relatively thin section therebetween. The electrode is comprised of an ion conducting material, an electron conducting material, and an electrocatalyst. The volume concentration of the ion conducting material is greatest at the first face and is decreased across the section, while the volume concentration of the electron conducting material is greatest at the second face and decreases across the section of the electrode. Substantially all of the electrocatalyst is positioned within the electrode section in a relatively narrow zone where the rate of electron transport of the electrode is approximately equal to the rate of ion transport of the electrode. 4 figs., 1 tab.

  18. Nanoparticles for Enhanced Sensitivity in Electrochemical Immunoassays

    SciTech Connect (OSTI)

    Lin, Yuehe; Wang, Jun; Wang, Hua; Wu, Hong; Tang, Zhiwen

    2008-10-12

    In this manuscript, we report on electrochemical biosensors based on various nanoparticles (NPs) as labels for sensitive detection of protein biomarkers. We used silica nanoparticle as a carrier to loading a large amount of electroactive species such as poly(guanine) for sensitive immunoassay of tumor necrosis factor-alpha (TNF-a). We took the advantages of the unique hollow structure and reconstruction properties of apoferritin to prepare Cd3(PO4)2 nanoparticles as labels for sensitive assay of TNF-a. A novel immunochromatographic/electro-chemical biosensor based on quantum dots as labels has also been developed for rapid and sensitive detection of prostate-specific antigen (PSA) in human serum. These biosensors are quite sensitive with the detection limit at pM level and these approaches based on nanoparticle labels offer a new avenue for sensitive detection of protein biomarkers.

  19. ELECTROCHEMICALLY MODULATED SEPARATIONS FOR MATERIAL ACCOUNTABILITY MEASUREMENTS

    SciTech Connect (OSTI)

    Hazelton, Sandra G.; Liezers, Martin; Naes, Benjamin E.; Arrigo, Leah M.; Duckworth, Douglas C.

    2012-07-08

    A method for the accurate and timely analysis of accountable materials is critical for safeguards measurements in nuclear fuel reprocessing plants. Non-destructive analysis (NDA) methods, such as gamma spectroscopy, are desirable for their ability to produce near real-time data. However, the high gamma background of the actinides and fission products in spent nuclear fuel limits the use of NDA for real-time online measurements. A simple approach for at-line separation of materials would facilitate the use of at-line detection methods. A promising at-line separation method for plutonium and uranium is electrochemically modulated separations (EMS). Using an electrochemical cell with an anodized glassy carbon electrode, Pu and U oxidation states can be altered by applying an appropriate voltage. Because the affinity of the actinides for the electrode depends on their oxidation states, selective deposition can be turned “on” and “off” with changes in the applied target electrode voltage. A high surface-area cell was designed in house for the separation of Pu from spent nuclear fuel. The cell is shown to capture over 1 ”g of material, increasing the likelihood for gamma spectroscopic detection of Pu extracted from dissolver solutions. The large surface area of the electrode also reduces the impact of competitive interferences from some fission products. Flow rates of up to 1 mL min−1 with >50% analyte deposition efficiency are possible, allowing for rapid separations to be effected. Results from the increased surface-area EMS cell are presented, including dilute dissolver solution simulant data.

  20. ELECTROCHEMICALLY-MODULATED SEPARATIONS FOR SAFEGUARDS MEASUREMENTS

    SciTech Connect (OSTI)

    Green, Michael A.; Arrigo, Leah M.; Liezers, Martin; Orton, Christopher R.; Douglas, Matthew; Peper, Shane M.; Schwantes, Jon M.; Hazelton, Sandra G.; Duckworth, Douglas C.

    2010-08-11

    A critical objective of materials accountability in safeguards is the accurate and timely analysis of fuel reprocessing streams to detect both abrupt and prolonged diversions of nuclear materials. For this reason both on-line nondestructive (NDA) and destructive analysis (DA) approaches are sought-after. Current methods for DA involve grab sampling and laboratory based column extractions that are costly, hazardous, and time consuming. While direct on-line gamma measurements of Pu are desirable, they are not possible due to contributions from other actinides and fission products. Researchers at Pacific Northwest National Laboratory are currently investigating electrochemically-modulated separation (EMS) as a straightforward, cost-effective technology for selective separation of Pu or U from aqueous reprocessing streams. The EMS selectivity is electrochemically controlled and results from the sorption of Pu4+ and U4+ redox states onto the anodized target electrode, allowing for selective accumulation of U or Pu from nitric acid streams to be turned “on” or “off.” It is envisioned that this technology can be utilized to isolate Pu for both NDA and DA analysis. For the NDA approach, rapid Pu analysis by gamma-ray spectroscopy could be performed after chemical clean-up of activation and fission products by EMS. Likewise, in the DA approach, EMS could be used to retain and concentrate the Pu in nanogram quantities on the electrode surface to be transported to the lab for analysis using high precision mass spectrometry. Due to the challenges associated with complex matrices, a systematic investigation of the redox-dependent accumulation of Pu using EMS was necessary, and results will be presented. Approaches to mitigate interelement effects using large surface area cells will also be discussed. The EMS chemistry and spectroscopy for Pu isolation and measurement will be presented, proof-of-principle measurements will be described, and the application of this approach for materials accountability will be discussed.

  1. Microstructure and electrochemical hydrogenation/dehydrogenation performance of melt-spun La-doped Mg{sub 2}Ni alloys

    SciTech Connect (OSTI)

    Hou, Xiaojiang; Hu, Rui; Zhang, Tiebang Kou, Hongchao; Song, Wenjie; Li, Jinshan

    2015-08-15

    This work focuses on microstructure and electrochemical hydrogen storage properties of La-doped Mg{sub 2}Ni alloys. The alloys with nominal compositions of Mg{sub 2}Ni{sub 1−x}La{sub x} (x = 0, 0.1, 0.3, 0.5) were prepared via metallurgical smelting and melt-spun on a rotating copper wheel. The scanning electron microscope, X-ray diffraction, differential scanning calorimetry and transition electron microscope, galvanostatic charging/discharging and other electrochemical measurements were employed to investigate. The results show that the increasing of La content and melt-spinning speed favors the formation of Mg–Ni–La amorphous/nanocrystalline alloys. It is found that the melt-spun ribbons display increased discharge capacities and superior cycle stabilities compared to the as-cast alloys with and without La. The potentiodynamic polarization results indicate that melt-spun La-doped Mg{sub 2}Ni ribbons possess more positive corrosion potential E{sub corr} and exhibit relatively high corrosion resistance against the alkaline solution. The mechanism for electrochemical hydrogenation/dehydrogenation has been proposed based on the effect of microstructures on the mass/charge transfer process for electrode electrochemical reaction. - Highlights: ‱ Nanocrystalline/amorphous Mg–Ni–La alloys are obtained by melt-spinning. ‱ Microstructures of as-cast and rapid quenched Mg{sub 2}Ni{sub 1−x}La{sub x} alloys are investigated. ‱ Electrochemical hydrogenation properties of experimental alloys are characterized. ‱ Electrochemical hydrogen absorption/desorption mechanism is proposed.

  2. Coupling Mechanical with Electrochemical-Thermal Models for Batteries under Abuse

    SciTech Connect (OSTI)

    Wierzbicki, Tomasz; Sahraei, Elham; Dajka, Stephen; Li, Genong; Santhanagopalan, Shriram; Zhang, Chao; Kim, Gi-Heon; Sprague, Michael A.

    2015-06-09

    This presentation provides an update on coupled mechanical-electrochemical-thermal models for batteries under abuse.

  3. Jefferson Lab Visitor's Center - Driving in Virginia

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Driving in virginia Effective January 1, 2004, all applicants for a driver's license or photo ID card must show proof of U.S. Citizenship or Legal Presence in the United States. A U.S. birth certificate or unexpired U.S. passport will serve as both proof of identity and proof of legal presence. It can also be proved using a variety of other documents, such as a Certificate of Citizenship, Resident Alien Card or a valid foreign passport with a visa, I-94 or I-94W from a participating country. If

  4. Selectively-etched nanochannel electrophoretic and electrochemical devices

    DOE Patents [OSTI]

    Surh, Michael P.; Wilson, William D.; Barbee, Jr., Troy W.; Lane, Stephen M.

    2006-06-27

    Nanochannel electrophoretic and electrochemical devices having selectively-etched nanolaminates located in the fluid transport channel. The normally flat surfaces of the nanolaminate having exposed conductive (metal) stripes are selectively-etched to form trenches and baffles. The modifications of the prior utilized flat exposed surfaces increase the amount of exposed metal to facilitate electrochemical redox reaction or control the exposure of the metal surfaces to analytes of large size. These etched areas variously increase the sensitivity of electrochemical detection devices to low concentrations of analyte, improve the plug flow characteristic of the channel, and allow additional discrimination of the colloidal particles during cyclic voltammetry.

  5. Selectively-etched nanochannel electrophoretic and electrochemical devices

    DOE Patents [OSTI]

    Surh, Michael P.; Wilson, William D.; Barbee, Jr., Troy W.; Lane, Stephen M.

    2004-11-16

    Nanochannel electrophoretic and electrochemical devices having selectively-etched nanolaminates located in the fluid transport channel. The normally flat surfaces of the nanolaminate having exposed conductive (metal) stripes are selectively-etched to form trenches and baffles. The modifications of the prior utilized flat exposed surfaces increase the amount of exposed metal to facilitate electrochemical redox reaction or control the exposure of the metal surfaces to analytes of large size. These etched areas variously increase the sensitivity of electrochemical detection devices to low concentrations of analyte, improve the plug flow characteristic of the channel, and allow additional discrimination of the colloidal particles during cyclic voltammetry.

  6. Cross-flow electrochemical reactor cells, cross-flow reactors, and use of cross-flow reactors for oxidation reactions

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Poeppel, Roger B.; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Udovich, Carl A.

    1994-01-01

    This invention discloses cross-flow electrochemical reactor cells containing oxygen permeable materials which have both electron conductivity and oxygen ion conductivity, cross-flow reactors, and electrochemical processes using cross-flow reactor cells having oxygen permeable monolithic cores to control and facilitate transport of oxygen from an oxygen-containing gas stream to oxidation reactions of organic compounds in another gas stream. These cross-flow electrochemical reactors comprise a hollow ceramic blade positioned across a gas stream flow or a stack of crossed hollow ceramic blades containing a channel or channels for flow of gas streams. Each channel has at least one channel wall disposed between a channel and a portion of an outer surface of the ceramic blade, or a common wall with adjacent blades in a stack comprising a gas-impervious mixed metal oxide material of a perovskite structure having electron conductivity and oxygen ion conductivity. The invention includes reactors comprising first and second zones seprated by gas-impervious mixed metal oxide material material having electron conductivity and oxygen ion conductivity. Prefered gas-impervious materials comprise at least one mixed metal oxide having a perovskite structure or perovskite-like structure. The invention includes, also, oxidation processes controlled by using these electrochemical reactors, and these reactions do not require an external source of electrical potential or any external electric circuit for oxidation to proceed.

  7. Oscillatory nonohomic current drive for maintaining a plasma current

    DOE Patents [OSTI]

    Fisch, N.J.

    1984-01-01

    Apparatus and methods are described for maintaining a plasma current with an oscillatory nonohmic current drive. Each cycle of operation has a generation period in which current driving energy is applied to the plasma, and a relaxation period in which current driving energy is removed. Plasma parameters, such as plasma temperature or plasma average ionic charge state, are modified during the generation period so as to oscillate plasma resistivity in synchronism with the application of current driving energy. The invention improves overall current drive efficiencies.

  8. Oscillatory nonhmic current drive for maintaining a plasma current

    DOE Patents [OSTI]

    Fisch, Nathaniel J.

    1986-01-01

    Apparatus and method of the invention maintain a plasma current with an oscillatory nonohmic current drive. Each cycle of operation has a generation period in which current driving energy is applied to the plasma, and a relaxation period in which current driving energy is removed. Plasma parameters, such as plasma temperature or plasma average ionic charge state, are modified during the generation period so as to oscillate plasma resistivity in synchronism with the application of current driving energy. The invention improves overall current drive efficiencies.

  9. Growth, characterization and electrochemical properties of hierarchical CuO nanostructures for supercapacitor applications

    SciTech Connect (OSTI)

    Krishnamoorthy, Karthikeyan; Kim, Sang-Jae

    2013-09-01

    Graphical abstract: - Highlights: • Hierarchical CuO nanostructures were grown on Cu foil. • Monoclinic phase of CuO was grown. • XPS analysis revealed the presence of Cu(2p{sub 3/2}) and Cu(2p{sub 1/2}) on the surfaces. • Specific capacitance of 94 F/g was achieved for the CuO using cyclic voltammetry. • Impedance spectra show their pseudo capacitor applications. - Abstract: In this paper, we have investigated the electrochemical properties of hierarchical CuO nanostructures for pseudo-supercapacitor device applications. Moreover, the CuO nanostructures were formed on Cu substrate by in situ crystallization process. The as-grown CuO nanostructures were characterized using X-ray diffraction (XRD), Fourier transform-infra red spectroscopy (FT-IR), X-ray photoelectron spectroscopy and field emission-scanning electron microscope (FE-SEM) analysis. The XRD and FT-IR analysis confirm the formation of monoclinic CuO nanostructures. FE-SEM analysis shows the formation of leave like hierarchical structures of CuO with high uniformity and controlled density. The electrochemical analysis such as cyclic voltammetry and electrochemical impedance spectroscopy studies confirms the pseudo-capacitive behavior of the CuO nanostructures. Our experimental results suggest that CuO nanostructures will create promising applications of CuO toward pseudo-supercapacitors.

  10. TEM Observations of Corrosion Behaviors of Platinized Carbon Blacks under Thermal and Electrochemical Conditions

    SciTech Connect (OSTI)

    Liu, Z.Y.; Zhang, J.L.; Yu, P.T.; Zhang, J.X.; Makharia, R.; More, Karren Leslie; Stach, Eric

    2010-01-01

    Carbon blacks such as Vulcan XC-72 are widely used to support platinum (Pt) or Pt alloy catalysts in proton exchange membrane fuel cells. Despite their widespread use, carbon blacks are susceptible to corrosion during fuel cell operations. In this work, the corrosion behaviors of platinized Vulcan XC-72 nanoparticles under thermal and electrochemical conditions were monitored by transmission electron microscopy (TEM). The thermal corrosion experiment was carried out in a gas-cell TEM, which allows for a direct observation of the thermal oxidation behavior of the nanoparticles. The electrochemical corrosion experiment was performed outside of the TEM by loading the nanoparticles on a TEM grid and then electrochemically corroding them step by step followed by taking TEM images from exactly the same nanoparticles after each step. This work revealed four types of structural changes: (i) total removal of structurally weak aggregates, (ii) breakdown of aggregates via neck-breaking, (iii) center-hollowed primary particles caused by an inside-out corrosion starting from the center to outer region, and (iv) gradual decrease in the size of primary particles caused by a uniform removal of material from the surface. These structural changes took place in sequence or simultaneously depending on the competition of carbon corrosion dynamical processes. The results obtained from this work provide insight on carbon corrosion and its effects on fuel cells' long-term performance and durability.

  11. Development of a geotechnical and pile driving database, Adriatic Sea

    SciTech Connect (OSTI)

    Carpaneto, R.; Paoletti, L.; Guaita, P.; Pratico, A.

    1996-12-31

    The paper presents a geotechnical and pile driving data base relevant to offshore installations in the Adriatic Sea. The paper discusses sources of information, structure, content, and engineering applications of the data base. Data available from Agip`s platform installations in the Adriatic was reviewed, and 20 representative platforms were chosen. Two relational data bases were created, for geotechnical and installation data respectively. The data bases provide a comprehensive and organized source of information about past experience in the area. Such experience is now quickly available for geotechnical engineering activities. As a main application of the data bases, information was processed to make data sets for training Artificial Neural Networks (ANN) to predict pile driveability. It is envisioned that the data bases will also be used in ongoing installation program design.

  12. Veeco Develops Tools to Drive Down HBLED Costs

    Broader source: Energy.gov [DOE]

    Veeco is working in partnership with Sandia National Laboratories and Philips Lumileds to drive down the cost of high-brightness LEDs by implementing process simulation tools and by improving temperature measurement and control methods to increase MOCVD yield. Veeco is working with Sandia to reduce the cost of ownership (COO) of the deposition equipment by, for example, using a heated flow flange, which reduces the consumption of the expensive precursors (ammonia, nitrogen, hydrogen, and the metal organics) by 40 percent. Two different types of pyrometers developed by Sandia and Veeco are being tested by Philips Lumileds to control the substrate temperature, which helps determine the color of the LED. If all works according to plan, the COO will be reduced by at least 75 percent by improving throughput, growth uniformity, yield, and temperature stabilization.

  13. Passivation dynamics in the anisotropic deposition and stripping of bulk magnesium electrodes during electrochemical cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wetzel, David J.; Malone, Marvin A.; Haasch, Richard T.; Meng, Yifei; Vieker, Henning; Hahn, Nathan; Golzhauser, Armin; Zuo, Jian-Min; Zavadil, Kevin R.; Gewirth, Andrew A.; et al

    2015-08-10

    Rechargeable magnesium (Mg) batteries show promise for use as a next generation technology for high-density energy storage, though little is known about the Mg anode solid electrolyte interphase and its implications for the performance and durability of a Mg-based battery. We explore in this report passivation effects engendered during the electrochemical cycling of a bulk Mg anode, characterizing their influences during metal deposition and dissolution in a simple, nonaqueous, Grignard electrolyte solution (ethylmagnesium bromide, EtMgBr, in tetrahydrofuran). Scanning electron microscopy images of Mg foil working electrodes after electrochemical polarization to dissolution potentials show the formation of corrosion pits. The pitmore » densities so evidenced are markedly potential-dependent. When the Mg working electrode is cycled both potentiostatically and galvanostatically in EtMgBr these pits, formed due to passive layer breakdown, act as the foci for subsequent electrochemical activity. Detailed microscopy, diffraction, and spectroscopic data show that further passivation and corrosion results in the anisotropic stripping of the Mg {0001} plane, leaving thin oxide-comprising passivated side wall structures that demark the {0001} fiber texture of the etched Mg grains. Upon long-term cycling, oxide side walls formed due to the pronounced crystallographic anisotropy of the anodic stripping processes, leading to complex overlay anisotropic, columnar structures, exceeding 50 Όm in height. Finally, the passive responses mediating the growth of these structures appear to be an intrinsic feature of the electrochemical growth and dissolution of Mg using this electrolyte.« less

  14. Template-free electrochemical synthesis of tin nanostructures...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Template-free electrochemical synthesis of tin nanostructures. Citation ... OSTI Identifier: 1185003 Report Number(s): SAND2014-20374J Journal ID: ISSN 0022--2461; ...

  15. Electrochemical cells and methods of manufacturing the same

    DOE Patents [OSTI]

    Bazzarella, Ricardo; Slocum, Alexander H; Doherty, Tristan; Cross, III, James C

    2015-11-03

    Electrochemical cells and methods of making electrochemical cells are described herein. In some embodiments, an apparatus includes a multi-layer sheet for encasing an electrode material for an electrochemical cell. The multi-layer sheet including an outer layer, an intermediate layer that includes a conductive substrate, and an inner layer disposed on a portion of the conductive substrate. The intermediate layer is disposed between the outer layer and the inner layer. The inner layer defines an opening through which a conductive region of the intermediate layer is exposed such that the electrode material can be electrically connected to the conductive region. Thus, the intermediate layer can serve as a current collector for the electrochemical cell.

  16. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D. Noble, J.

    2009-10-01

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  17. Status of the DOE Battery and Electrochemical Technology Program V

    SciTech Connect (OSTI)

    Roberts, R.

    1985-06-01

    The program consists of two activities, Technology Base Research (TBR) managed by the Lawrence Berkeley Laboratory (LBL) and Exploratory Technology Development and Testing (EDT) managed by the Sandia National Laboratories (SNL). The status of the Battery Energy Storage Test (BEST) Facility is presented, including the status of the batteries to be tested. ECS program contributions to the advancement of the lead-acid battery and specific examples of technology transfer from this program are given. The advances during the period December 1982 to June 1984 in the characterization and performance of the lead-acid, iron/nickel-oxide, iron/air, aluminum/air, zinc/bromide, zinc/ferricyanide, and sodium/sulfur batteries and in fuel cells for transport are summarized. Novel techniques and the application of established techniques to the study of electrode processes, especially the electrode/electrolyte interface, are described. Research with the potential of leading to improved ceramic electrolytes and positive electrode container and current-collectors for the sodium/sulfur battery is presented. Advances in the electrocatalysis of the oxygen (air) electrode and the relationship of these advances to the iron/air and aluminum/air batteries and to the fuel cell are noted. The quest for new battery couples and battery materials is reviewed. New developments in the modeling of electrochemical cell and electrode performance with the approaches to test these models are reported.

  18. Fail-Safe, Inexpensive Electrochemical Device Stack Design - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Fail-Safe, Inexpensive Electrochemical Device Stack Design Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryCraig Jacobson, Steven Visco, and Lutgard DeJonghe have invented a robust and low cost electrochemical device stack system based on a modified segmented-cell-in-series design. In this invention a number of small cylindrical cell segments are in contact with a planar metallic interconnect sheet that electrically

  19. Electronic structural and electrochemical properties of lithium zirconates

    Office of Scientific and Technical Information (OSTI)

    and their capabilities of CO2 capture: A first-principles density-functional theory and phonon dynamics approach (Journal Article) | SciTech Connect Journal Article: Electronic structural and electrochemical properties of lithium zirconates and their capabilities of CO2 capture: A first-principles density-functional theory and phonon dynamics approach Citation Details In-Document Search Title: Electronic structural and electrochemical properties of lithium zirconates and their capabilities

  20. GROWTH AND ELECTROCHEMICAL CHARACTERIZATION OF CARBON NANOSPIKE THIN FILM

    Office of Scientific and Technical Information (OSTI)

    ELECTRODES (Journal Article) | SciTech Connect GROWTH AND ELECTROCHEMICAL CHARACTERIZATION OF CARBON NANOSPIKE THIN FILM ELECTRODES Citation Details In-Document Search Title: GROWTH AND ELECTROCHEMICAL CHARACTERIZATION OF CARBON NANOSPIKE THIN FILM ELECTRODES Authors: Sheridan, Leah B [1] ; Hensley, Dale K [1] ; Lavrik, Nickolay V [1] ; Smith, Sean C [1] ; Schwartz, Viviane [1] ; Liang, Chengdu [1] ; Rondinone, Adam Justin [1] + Show Author Affiliations ORNL Publication Date: 2014-01-01 OSTI