Sample records for dp dry sorbent

  1. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Jeffrey W. Portzer; Raghubir P. Gupta; William J. McMichael; Thomas Nelson

    2004-07-01T23:59:59.000Z

    This report describes research conducted between April 1, 2004 and June 30, 2004 on the preparation and use of dry regenerable sorbents for removal of carbon dioxide from flue gas. Support materials and supported sorbents were prepared by spray drying. Sorbents consisting of 20 to 50% sodium carbonate on a ceramic support were prepared by spray drying in batches of approximately 300 grams. The supported sorbents exhibited greater carbon dioxide capture rates than unsupported calcined sodium bicarbonate in laboratory tests. Preliminary process design and cost estimation for a retrofit application suggested that costs of a dry regenerable sodium carbonate-based process could be lower than those of a monoethanolamine absorption system. In both cases, the greatest part of the process costs come from power plant output reductions due to parasitic consumption of steam for recovery of carbon dioxide from the capture medium.

  2. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Raghubir P. Gupta

    2006-03-31T23:59:59.000Z

    This report describes research conducted between January 1, 2006, and March 31, 2006, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. An integrated system composed of a downflow co-current contact absorber and two hollow screw conveyors (regenerator and cooler) was assembled, instrumented, debugged, and calibrated. A new batch of supported sorbent containing 15% sodium carbonate was prepared and subjected to surface area and compact bulk density determination.

  3. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box; Andreas Weber; Raghubir P. Gupta

    2006-01-01T23:59:59.000Z

    This report describes research conducted between October 1, 2005, and December 31, 2005, on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from flue gas from coal combustion. A field test was conducted to examine the extent to which RTI's supported sorbent can be regenerated in a heated, hollow screw conveyor. This field test was conducted at the facilities of a screw conveyor manufacturer. The sorbent was essentially completely regenerated during this test, as confirmed by thermal desorption and mass spectroscopy analysis of the regenerated sorbent. Little or no sorbent attrition was observed during 24 passes through the heated screw conveyor system. Three downflow contactor absorption tests were conducted using calcined sodium bicarbonate as the absorbent. Maximum carbon dioxide removals of 57 and 91% from simulated flue gas were observed at near ambient temperatures with water-saturated gas. These tests demonstrated that calcined sodium carbonate is not as effective at removing CO{sub 2} as are supported sorbents containing 10 to 15% sodium carbonate. Delivery of the hollow screw conveyor for the laboratory-scale sorbent regeneration system was delayed; however, construction of other components of this system continued during the quarter.

  4. Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents

    SciTech Connect (OSTI)

    Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

    2007-06-30T23:59:59.000Z

    Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

  5. Economics of dry FGD by sorbent injection

    SciTech Connect (OSTI)

    Naulty, D.J.; Hooper, R.G.; McDowell, D.A.; Scheck, R.W.

    1983-06-01T23:59:59.000Z

    The body of information in this paper is directed to engineers involved in desulfurization of boiler flue gas. The problems of wet scrubbing SO/sub 2/ from power plant flue gases have been well documented. The utility industry has been interested in developing new processes that would overcome problems associated with wet slurry systems. While spray dryer technology for FGD may alleviate many of these problems, this concept has problems as well. Dry injection FGD takes the development process one step further to a totally dry system, thus eliminating the difficulties of wet slurry handling. The concept of using the fabric filter as a chemical contactor for the SO/sub 2/ absorption was proposed in the late 1960s by Chaffee and Hill. In the early 1970s, Superior Oil Company, Wheelabrator Frye, Carborundum, and others investigated the use of nahcolite for SO/sub 2/ removal. Nahcolite is a natural occurring sodium bicarbonate found in great quantities in the oil shale regions of Colorado. In general, these developments were found viable in certain circumstances, but commercialization was hampered by the lack of nahcolite suppliers.

  6. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir Gupta; Alejandro Lopez-Ortiz

    2001-01-01T23:59:59.000Z

    Four grades of sodium bicarbonate and two grades of trona were characterized in terms of particle size distribution, surface area, pore size distribution, and attrition. Surface area and pore size distribution determinations were conducted after calcination of the materials. The sorbent materials were subjected to thermogravimetric testing to determine comparative rates and extent of calcination (in inert gas) and sorption (in a simulated coal combustion flue gas mixture). Selected materials were exposed to five calcination/sorption cycles and showed no decrease in either sorption capacity or sorption rate. Process simulations were conducted involving different heat recovery schemes. The process is thermodynamically feasible. The sodium-based materials appear to have suitable physical properties for use as regenerable sorbents and, based on thermogravimetric testing, are likely to have sorption and calcination rates that are rapid enough to be of interest in full-scale carbon sequestration processes.

  7. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Douglas P. Harrison; Ya Liang

    2001-10-01T23:59:59.000Z

    The objective of this project is to develop a simple, inexpensive process to separate CO{sub 2} as an essentially pure stream from a fossil fuel combustion system using a regenerable, sodium-based sorbent. The sorbent being used in this project is sodium carbonate which is converted to sodium bicarbonate, ''baking soda,'' through reaction with carbon dioxide and water vapor. Sodium bicarbonate is regenerated to sodium carbonate when heated, producing a nearly pure CO{sub 2} stream after condensation of water vapor. Testing conducted previously confirmed that the reaction rate and achievable CO{sub 2} capacity of sodium carbonate decreased with increasing temperature, and that the global rate of reaction of sodium carbonate to sodium bicarbonate increased with an increase in both CO{sub 2} and H{sub 2}O concentrations. Energy balance calculations indicated that the rate of heat removal from the particle surface may determine the reaction rate for a particular particle system. This quarter, thermogravimetric analyses (TGA) were conducted which indicated that calcination of sodium bicarbonate at temperatures as high as 200 C did not cause a significant decrease in activity in subsequent carbonation testing. When sodium bicarbonate was subjected to a five cycle calcination/carbonation test, activity declined slightly over the first two cycles but was constant thereafter. TGA tests were also conducted with two other potential sorbents. Potassium carbonate was found to be less active than sodium carbonate, at conditions of interest in preliminary TGA tests. Sodium carbonate monohydrate showed negligible activity. Testing was also conducted in a 2-inch internal diameter quartz fluidized-bed reactor system. A five cycle test demonstrated that initial removals of 10 to 15 percent of the carbon dioxide in a simulated flue gas could be achieved. The carbonation reaction proceeded at temperatures as low as 41 C. Future work by TGA and in fixed-bed, fluidized-bed, and transport reactor systems is planned to demonstrate the feasibility of this process in large scale operations to separate carbon dioxide from flue gas.

  8. Evaluation of Dry Sorbent Injection Technology for Pre-Combustion CO{sub 2} Capture

    SciTech Connect (OSTI)

    Richardson, Carl [URS Group, Inc., Austin, TX (United States); Steen, William [URS Group, Inc., Austin, TX (United States); Triana, Eugenio [URS Group, Inc., Austin, TX (United States); Machalek, Thomas [URS Group, Inc., Austin, TX (United States); Davila, Jenny [URS Group, Inc., Austin, TX (United States); Schmit, Claire [URS Group, Inc., Austin, TX (United States); Wang, Andrew [URS Group, Inc., Austin, TX (United States); Temple, Brian [URS Group, Inc., Austin, TX (United States); Lu, Yongqi [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Lu, Hong [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Zhang, Luzheng [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Ruhter, David [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Rostam-Abadi, Massoud [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Sayyah, Maryam [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Ito, Brandon [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States); Suslick, Kenneth [Illinois State Geological Survey - University of Illinois at Urbana-Champaign (United States)

    2013-09-30T23:59:59.000Z

    This document summarizes the work performed on Cooperative Agreement DE-FE0000465, “Evaluation of Dry Sorbent Technology for Pre-Combustion CO{sub 2} Capture,” during the period of performance of January 1, 2010 through September 30, 2013. This project involves the development of a novel technology that combines a dry sorbent-based carbon capture process with the water-gas-shift reaction for separating CO{sub 2} from syngas. The project objectives were to model, develop, synthesize and screen sorbents for CO{sub 2} capture from gasified coal streams. The project was funded by the DOE National Energy Technology Laboratory with URS as the prime contractor. Illinois Clean Coal Institute and The University of Illinois Urbana-Champaign were project co-funders. The objectives of this project were to identify and evaluate sorbent materials and concepts that were suitable for capturing carbon dioxide (CO{sub 2}) from warm/hot water-gas-shift (WGS) systems under conditions that minimize energy penalties and provide continuous gas flow to advanced synthesis gas combustion and processing systems. Objectives included identifying and evaluating sorbents that efficiently capture CO{sub 2} from a gas stream containing CO{sub 2}, carbon monoxide (CO), and hydrogen (H{sub 2}) at temperatures as high as 650 °C and pressures of 400-600 psi. After capturing the CO{sub 2}, the sorbents would ideally be regenerated using steam, or other condensable purge vapors. Results from the adsorption and regeneration testing were used to determine an optimal design scheme for a sorbent enhanced water gas shift (SEWGS) process and evaluate the technical and economic viability of the dry sorbent approach for CO{sub 2} capture. Project work included computational modeling, which was performed to identify key sorbent properties for the SEWGS process. Thermodynamic modeling was used to identify optimal physical properties for sorbents and helped down-select from the universe of possible sorbent materials to seven that were deemed thermodynamically viable for the process. Molecular modeling was used to guide sorbent synthesis through first principles simulations of adsorption and regeneration. Molecular dynamics simulations also modeled the impact of gas phase impurities common in gasified coal streams (e.g., H{sub 2}S) on the adsorption process. The role of inert dopants added for mechanical durability to active sorbent materials was also investigated through molecular simulations. Process simulations were conducted throughout the project to help determine the overall feasibility of the process and to help guide laboratory operating conditions. A large component of the program was the development of sorbent synthesis methods. Three different approaches were used: mechanical alloying (MA), flame spray pyrolysis (FSP), and ultrasonic spray pyrolysis (USP). Sorbents were characterized by a host of analytical techniques and screened for SEWGS performance using a thermogravimetric analyzer (TGA). A feedback loop from screening efforts to sorbent synthesis was established and used throughout the project lifetime. High temperature, high pressure reactor (HTPR) systems were constructed to test the sorbents at conditions mimicking the SEWGS process as identified through process modeling. These experiments were conducted at the laboratory scale to examine sorbents for their CO{sub 2} capacity, conversion of CO to CO{sub 2}, and impacts of adsorption and regeneration conditions, and syngas composition (including impurities and H2O:CO ratio). Results from the HTPR testing showed sorbents with as high as 0.4 g{sub CO{sub 2}}/g{sub sorbent} capacity with the ability to initially shift the WGS completely towards CO{sub 2}/H{sub 2}. A longer term experiment with a simple syngas matrix and N{sub 2}/steam regeneration stream showed a USP sorbent to be stable through 50 adsorption-regeneration cycles, though the sorbent tested had a somewhat diminished initial capacity. The program culminated in a technoeconomic assessment in which two different approaches were taken; one

  9. CARBON DIOXIDE CAPTURE FROM FLUE GAS USING DRY REGENERABLE SORBENTS

    SciTech Connect (OSTI)

    David A. Green; Brian S. Turk; Raghubir P. Gupta; Alejandro Lopez-Ortiz; Douglas P. Harrison; Ya Liang

    2001-05-01T23:59:59.000Z

    Electrobalance studies of calcination and carbonation of sodium bicarbonate materials were conducted at Louisiana State University. Calcination in an inert atmosphere was rapid and complete at 120 C. Carbonation was temperature dependent, and both the initial rate and the extent of reaction were found to decrease as temperature was increased between 60 and 80 C. A fluidization test apparatus was constructed at RTI and two sodium bicarbonate materials were fluidized in dry nitrogen at 22 C. The bed was completely fluidized at between 9 and 11 in. of water pressure drop. Kinetic rate expression derivations and thermodynamic calculations were conducted at RTI. Based on literature data, a simple reaction rate expression, which is zero order in carbon dioxide and water, was found to provide the best fit against reciprocal temperature. Simulations based on process thermodynamics suggested that approximately 26 percent of the carbon dioxide in flue gas could be recovered using waste heat available at 240 C.

  10. Highly Attrition Resistant Zinc Oxide-Based Sorbents for H2S Removal by Spray Drying Technique

    SciTech Connect (OSTI)

    Ryu, C.K.; Lee, J.B.; Ahn, D.H.; Kim, J.J.; Yi, C.K.

    2002-09-19T23:59:59.000Z

    Primary issues for the fluidized-bed/transport reactor process are high attrition resistant sorbent, its high sorption capacity and regenerability, durability, and cost. The overall objective of this project is the development of a superior attrition resistant zinc oxide-based sorbent for hot gas cleanup in integrated coal gasification combined cycle (IGCC). Sorbents applicable to a fluidized-bed hot gas desulfurization process must have a high attrition resistance to withstand the fast solid circulation between a desulfurizer and a regenerator, fast kinetic reactions, and high sulfur sorption capacity. The oxidative regeneration of zinc-based sorbent usually initiated at greater than 600 C with highly exothermic nature causing deactivation of sorbent as well as complication of sulfidation process by side reaction. Focusing on solving the sorbent attrition and regenerability of zinc oxide-based sorbent, we have adapted multi-binder matrices and direct incorporation of regeneration promoter. The sorbent forming was done with a spray drying technique that is easily scalable to commercial quantity.

  11. Integrated dry NO{sub x}/SO{sub 2} emissions control system calcium-based dry sorbent injection. Test report, April 30--November 2, 1993

    SciTech Connect (OSTI)

    Shiomoto, G.H.; Smith, R.A.; Muzio, L.J. [Fossil Energy Research Corp., Laguna Hills, CA (United States); Hunt, T. [Public Service Company of Colorado, Denver, CO (United States)

    1994-12-01T23:59:59.000Z

    The DOE sponsored Integrated Dry NO{sub x}SO{sub 2} Emissions Control System program, which is a Clean Coal Technology III demonstration, is being conducted by Public Service Company of Colorado. The test site is Arapahoe Generating Station Unit 4, which is a 100 MWe, down-fired utility boiler burning a low sulfur Western coal. The project goal is to demonstrate up to 70 percent reductions in NO{sub x} and SO{sub 2} emissions through the integration of: (1) down-fired low-NO{sub x} burners with overfire air; (2) Selective Non-Catalytic Reduction (SNCR) for additional NO{sub x} removal; and (3) dry sorbent injection and duct humidification for SO{sub 2} removal. The effectiveness of the integrated system on a high-sulfur coal will also be investigated. This report documents the fifth phase of the test program, where the performance of the dry sorbent injection of calcium was evaluated as an SO{sub 2} removal technique. Dry sorbent injection with humidification was performed downstream of the air heater (in-duct). Calcium injection before the economizer was also investigated. The in-duct calcium sorbent and humidification retrofit resulted in SO{sub 2} reductions of 28 to 40 percent, with a Ca/S of 2, and a 25 to 30{degrees}F approach to adiabatic saturation temperature. The results of the economizer calcium injection tests were disappointing with less than 10 percent SO{sub 2} removal at a Ca/S of 2. Poor sorbent distribution due to limited access into the injection cavity was partially responsible for the low overall removals. However, even in areas of high sorbent concentration (local Ca/S ratios of approximately 6), SO{sub 2} removals were limited to 30 percent. It is suspected that other factors (sorbent properties and limited residence times) also contributed to the poor performance.

  12. Investigation and Demonstration of Dry Carbon-Based Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Jim Butz; Terry Hunt

    2005-11-01T23:59:59.000Z

    Public Service Company of Colorado and ADA Technologies, Inc. have performed a study of the injection of activated carbon for the removal of vapor-phase mercury from coal-fired flue gas streams. The project was completed under contract to the US Department of Energy's National Energy Technology Laboratory, with contributions from EPRI and Public Service Company. The prime contractor for the project was Public Service Company, with ADA Technologies as the major subcontractor providing technical support to all aspects of the project. The research and development effort was conducted in two phases. In Phase I a pilot facility was fabricated and tests were performed using dry carbon-based sorbent injection for mercury control on a coal-fired flue gas slipstream extracted from an operating power plant. Phase II was designed to move carbon injection technology towards commercial application on coal-fired power plants by addressing key reliability and operability concerns. Phase II field work included further development work with the Phase I pilot and mercury measurements on several of PSCo's coal-fired generating units. In addition, tests were run on collected sorbent plus fly ash to evaluate the impact of the activated carbon sorbent on the disposal of fly ash. An economic analysis was performed where pilot plant test data was used to develop a model to predict estimated costs of mercury removal from plants burning western coals. Testing in the pilot plant was undertaken to quantify the effects of plant configuration, flue gas temperature, and activated carbon injection rate on mercury removal. All three variables were found to significantly impact the mercury removal efficiency in the pilot. The trends were clear: mercury removal rates increased with decreasing flue gas temperature and with increasing carbon injection rates. Mercury removal was much more efficient with reverse-gas and pulse-jet baghouse configurations than with an ESP as the particulate control device. The native fly ash of the host unit provided significant mercury removal capacity, so that the activated carbon sorbent served as an incremental mercury removal mechanism. Tests run to characterize the waste product, a combination of fly ash and activated carbon on which mercury was present, showed that mercury and other RCRA metals of interest were all below Toxic Characteristic Leaching Procedure (TCLP) regulatory limits in the leachate. The presence of activated carbon in the fly ash was shown to have an effect on the use of fly ash as an additive in the manufacture of concrete, which could limit the salability of fly ash from a plant where activated carbon was used for mercury control.

  13. Regeneration of FGD dry-sorbent materials. Phase I. Final report

    SciTech Connect (OSTI)

    Kapsalopoulou, A.J.; Sargent, D.H.; Rissman, E.F.

    1982-05-01T23:59:59.000Z

    Sodium-based sorbent injection directly into the flue gas duct of a coal-burning power plant has been investigated since 1975 by GFETC (using laboratory and pilot plant apparatus) as an SO/sub 2/ control technology. Regeneration of sorbent from spent sorbent material is highly desirable to reduce the sorbent cost, and to alleviate the leaching and potential pollution problems of soluble sodium compounds when disposing of spent sorbent materials in landfills. The work reported herein was initiated to develop a continuous, aqueous-based process for regeneration of sodium carbonate-type sorbents from spent sodium-base sorbent/flyash materials. Specific project objectives are to: (1) retain process simplicity and to avoid difficult process conditions; (2) maximize recovery of sodium from spent sorbents; (3) minimize process costs and energy requirements; (4) maximize reactivity of the regenerated sodium bicarbonate sorbent; and (5) produce process waste materials that may be disposed of in an environmental acceptable manner. The sorbent regeneration process which has been developed during the laboratory investigation (Phase I) of this project may be divided into three parts: (1) leaching of the spent sodium-based sorbent; (2) conversion of the leachate to a NaCl brine; and (3) production of NaHCO/sub 3/ (regenerated sorbent) using commercially-proven Solvay (ammonia-soda) process technology. Significant results from the laboratory study are as given.

  14. Development of a Dry Sorbent-based Post-Combustion CO2 Capture Technology for Retrofit in Existing Power Plants

    SciTech Connect (OSTI)

    Nelson, Thomas; Coleman, Luke; Anderson, Matthew; Gupta, Raghubir; Herr, Joshua; Kalluri, Ranjeeth; Pavani, Maruthi

    2009-12-31T23:59:59.000Z

    The objective of this research and development (R&D) project was to further the development of a solid sorbent-based CO2 capture process based on sodium carbonate (i.e. the Dry Carbonate Process) that is capable of capturing>90% of the CO2 as a nearly pure stream from coal-fired power plant flue gas with <35% increase in the cost of electrictiy (ICOE).

  15. Integrated dry NO{sub x}/SO{sub 2} emissions control system sodium-based dry sorbent injection test report. Test period: August 4, 1993--July 29, 1995

    SciTech Connect (OSTI)

    Smith, R.A.; Shimoto, G.H.; Muzio, L.J. [Fossil Energy Research Corp., Laguna Hills, CA (United States)] [Fossil Energy Research Corp., Laguna Hills, CA (United States); Hunt, T. [Public Service Co. of Colorado, Denver, CO (United States)] [Public Service Co. of Colorado, Denver, CO (United States)

    1997-04-01T23:59:59.000Z

    The project goal is to demonstrate up to 70% reductions in NOx and SO{sub 2} emissions through the integration of: (1) down-fired low-NOx burners with overfire air; (2) Selective Non-Catalytic Reduction (SNCR) for additional NOx removal; and (3) dry sorbent injection and duct humidification for SO{sub 2} removal. This report documents the sixth phase of the test program, where the performance of dry sorbent injection with sodium compounds was evaluated as a SO{sub 2} removal technique. Dry sorbent injection was performed in-duct downstream of the air heater (ahead of the fabric filter), as well as at a higher temperature location between the economizer and air heater. Two sodium compounds were evaluated during this phase of testing: sodium sesquicarbonate and sodium bicarbonate. In-duct sodium injection with low levels of humidification was also investigated. This sixth test phase was primarily focused on a parametric investigation of sorbent type and feed rate, although boiler load and sorbent preparation parameters were also varied.

  16. Removal of Particles and Acid Gases (SO2 or HCl) with a Ceramic Filter by Addition of Dry Sorbents

    SciTech Connect (OSTI)

    Hemmer, G.; Kasper, G.; Wang, J.; Schaub, G.

    2002-09-20T23:59:59.000Z

    The present investigation intends to add to the fundamental process design know-how for dry flue gas cleaning, especially with respect to process flexibility, in cases where variations in the type of fuel and thus in concentration of contaminants in the flue gas require optimization of operating conditions. In particular, temperature effects of the physical and chemical processes occurring simultaneously in the gas-particle dispersion and in the filter cake/filter medium are investigated in order to improve the predictive capabilities for identifying optimum operating conditions. Sodium bicarbonate (NaHCO{sub 3}) and calcium hydroxide (Ca(OH){sub 2}) are known as efficient sorbents for neutralizing acid flue gas components such as HCl, HF, and SO{sub 2}. According to their physical properties (e.g. porosity, pore size) and chemical behavior (e.g. thermal decomposition, reactivity for gas-solid reactions), optimum conditions for their application vary widely. The results presented concentrate on the development of quantitative data for filtration stability and overall removal efficiency as affected by operating temperature. Experiments were performed in a small pilot unit with a ceramic filter disk of the type Dia-Schumalith 10-20 (Fig. 1, described in more detail in Hemmer 2002 and Hemmer et al. 1999), using model flue gases containing SO{sub 2} and HCl, flyash from wood bark combustion, and NaHCO{sub 3} as well as Ca(OH){sub 2} as sorbent material (particle size d{sub 50}/d{sub 84} : 35/192 {micro}m, and 3.5/16, respectively). The pilot unit consists of an entrained flow reactor (gas duct) representing the raw gas volume of a filter house and the filter disk with a filter cake, operating continuously, simulating filter cake build-up and cleaning of the filter medium by jet pulse. Temperatures varied from 200 to 600 C, sorbent stoichiometric ratios from zero to 2, inlet concentrations were on the order of 500 to 700 mg/m{sup 3}, water vapor contents ranged from zero to 20 vol%. The experimental program with NaHCO{sub 3} is listed in Table 1. In addition, model calculations were carried out based on own and published experimental results that estimate residence time and temperature effects on removal efficiencies.

  17. Field evaluation of natural gas and dry sorbent injection for MWC emissions control

    SciTech Connect (OSTI)

    Wohadlo, S.; Abbasi, H.; Cygan, D. [Institute of Gas Technology, Chicago, IL (United States)] Institute of Gas Technology, Chicago, IL (United States)

    1993-10-01T23:59:59.000Z

    The Institute of Gas Technology (IGT), in cooperation with the Olmsted Waste-to-Energy Facility (OWEF) and with subcontracted engineering services from the Energy and Environmental Research Corporation (EER), has completed the detailed engineering and preparation of construction specifications for an Emissions Reduction Testing System (ERTS). The ERTS has been designed for retrofit to one of two 100-ton/day municipal waste combustors at the OWEF, located in Rochester, Minnesota. The purpose of the retrofit is to conduct a field evaluation of a combined natural gas and sorbent injection process (IGT`s METHANE de-TOX{sup SM}, IGT Patent No. 5,105,747) for reducing the emissions of oxides of nitrogen (NO{sub x}), hydrochloric acid (HCI), oxides of sulfur (SO{sub x}), carbon monoxide (CO), total hydrocarbons (THC), and chlorinated hydrocarbons (dioxin/furans). In addition, the design includes modifications for the control of heavy metals (HM). Development of the process should allow the waste-to-energy industry to meet the Federal New Source Performance Standards for these pollutants at significantly lower costs when compared to existing technology of Thermal deNO{sub x} combined with spray dryer scrubber/fabric filters. Additionally, the process should reduce boiler corrosion and increase both the thermal and power production efficiency of the facility.

  18. Zinc titanate sorbents

    DOE Patents [OSTI]

    Gupta, R.P.; Gangwal, S.K.; Jain, S.C.

    1998-02-03T23:59:59.000Z

    The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about 750 to about 950 C. The dry blend is formed by mixing between about 0.5 to about 2 parts zinc oxide having a median particle size of less than about 0.5 microns, and about 1 part titanium dioxide having a median particle size of less than about 1 micron. The slurry contains substantially no free silica and may be prepared by the process including (1) preparing an aqueous solution of organic binder, (2) adding the dry blend to the aqueous solution of organic binder, and (3) adding the inorganic binder to the solution of organic binder, and blend. Additional reagents, such as a surfactant, may also be incorporated into the sorbent material. The present invention also provides a process for desulfurizing a gaseous stream. The process includes passing a gaseous stream through a reactor containing an attrition resistant zinc titanate sorbent material of the present invention.

  19. Low temperature SO{sub 2} removal with solid sorbents in a circulating fluidized bed absorber. Final report

    SciTech Connect (OSTI)

    Lee, S.K.; Keener, T.C.

    1994-10-10T23:59:59.000Z

    A novel flue gas desulfurization technology has been developed at the University of Cincinnati incorporating a circulating fluidized bed absorber (CFBA) reactor with dry sorbent. The main features of CFBA are high sorbent/gas mixing ratios, excellent heat and mass transfer characteristics, and the ability to recycle partially utilized sorbent. Subsequently, higher SO{sub 2} removal efficiencies with higher overall sorbent utilization can be realized compared with other dry sorbent injection scrubber systems.

  20. Decontamination formulation with sorbent additive

    DOE Patents [OSTI]

    Tucker; Mark D. (Albuquerque, NM), Comstock; Robert H. (Gardendale, AL)

    2007-10-16T23:59:59.000Z

    A decontamination formulation and method of making that neutralizes the adverse health effects of both chemical and biological compounds, especially chemical warfare (CW) and biological warfare (BW) agents, and toxic industrial chemicals. The formulation provides solubilizing compounds that serve to effectively render the chemical and biological compounds, particularly CW and BW compounds, susceptible to attack, and at least one reactive compound that serves to attack (and detoxify or kill) the compound. The formulation includes at least one solubilizing agent, a reactive compound, a bleaching activator, a sorbent additive, and water. The highly adsorbent, water-soluble sorbent additive (e.g., sorbitol or mannitol) is used to "dry out" one or more liquid ingredients, such as the liquid bleaching activator (e.g., propylene glycol diacetate or glycerol diacetate) and convert the activator into a dry, free-flowing powder that has an extended shelf life, and is more convenient to handle and mix in the field.

  1. Fluidized-bed sorbents

    SciTech Connect (OSTI)

    Gangwal, S.K.; Gupta, R.P.

    1994-10-01T23:59:59.000Z

    The objectives of this project are to identify and demonstrate methods for enhancing long-term chemical reactivity and attrition resistance of zinc oxide-based mixed metal-oxide sorbents for desulfurization of hot coal-derived gases in a high-temperature, high-pressure (HTHP) fluidized-bed reactor. In this program, regenerable ZnO-based mixed metal-oxide sorbents are being developed and tested. These include zinc ferrite, zinc titanate, and Z-SORB sorbents. The Z-SORB sorbent is a proprietary sorbent developed by Phillips Petroleum Company (PPCo).

  2. Regenerable solid imine sorbents

    DOE Patents [OSTI]

    Gray, McMahan; Champagne, Kenneth J.; Fauth, Daniel; Beckman, Eric

    2013-09-10T23:59:59.000Z

    Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO.sub.2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20.degree. C. upwards to 90.degree. C. and can be regenerated by heating upwards to 100.degree. C.

  3. Desulfurization sorbent regeneration

    DOE Patents [OSTI]

    Jalan, V.M.; Frost, D.G.

    1982-07-07T23:59:59.000Z

    A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500/sup 0/C to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent. This method may be used for high-temperature fuel cells.

  4. Sorbent preparation/modification/additives. Final report, September 1, 1992--November 30, 1993

    SciTech Connect (OSTI)

    Prudich, M.E.; Venkataramakrishnan, R. [Ohio Univ., Athens, OH (United States)

    1994-02-01T23:59:59.000Z

    Sorbent preparation techniques used today have generally been adapted from techniques traditionally used by the lime industry. Traditional dry hydration and slaking processes have been optimized to produce materials intended for use in the building industry. These preparation techniques should be examined with an eye to optimization of properties important to the SO{sub 2} capture process. The study of calcium-based sorbents for sulfur dioxide capture is complicated by two factors: (1) little is known about the chemical mechanisms by which the standard sorbent preparation and enhancement techniques work, and (2) a sorbent preparation technique that produces a calcium-based sorbent that enjoys enhanced calcium utilization in one regime of operation [flame zone (>2400 F), in-furnace (1600--2400 F), economizer (800--1100 F), after air preheater (<350 F)] may not produce a sorbent that enjoys enhanced calcium utilization in the other reaction zones. Again, an in-depth understanding of the mechanism of sorbent enhancement is necessary if a systematic approach to sorbent development is to be used. As a long-term goal, an experimental program is being carried out for the purpose of (1) defining the effects of slaking conditions on the properties of calcium-based sorbents, (2) determining how the parent limestone properties of calcium-based sorbents, and (3) elucidating the mechanism(s) relating to the activity of various dry sorbent additives. An appendix contains a one-dimensional duct injection model with modifications to handle the sodium additives.

  5. SO{sub 2} reactivity studies with BENMOL sorbents - CRADA 90-002. Final report

    SciTech Connect (OSTI)

    Markussen, J.M.; Pennline, H.W.; Brodd, C.F. [Dept. of Energy Pittsburgh Energy Technology Center, PA (United States)]|[BENMOL Corp., Alexandria, VA (United States)

    1990-12-01T23:59:59.000Z

    BENMOL sorbents have been purported to be reactive with sulfur dioxide (SO{sub 2}) in flue gas at post-air-preheater temperatures (350{degrees}F and below), thus making them possible candidates for dry sorbent injection desulfurization processes. As an initial step to determine the reactivity of these sorbents, microbalance studies were conducted at the Pittsburgh Energy Technology Center (PETC) under the Cooperative Research and Development Agreement (CRADA) program. Initial reactivity rates and total absorption capacities were determined and compared to those obtained with hydrated lime, which is the chosen sorbent for most duct injection flue gas desulfurization processes.

  6. Inorganic ion sorbent method

    DOE Patents [OSTI]

    Teter, David M. (Edgewood, NM); Brady, Patrick V. (Albuquerque, NM); Krumhansl, James L. (Albuquerque, NM)

    2007-07-17T23:59:59.000Z

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  7. Inorganic ion sorbents

    DOE Patents [OSTI]

    Teter, David M.; Brady, Patrick V.; Krumhansl, James L.

    2006-10-17T23:59:59.000Z

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  8. ADVANCED SORBENT DEVELOPMENT PROGRAM

    SciTech Connect (OSTI)

    Unknown

    1998-06-16T23:59:59.000Z

    The overall objective of this program was to develop regenerable sorbents for use in the temperature range of 343 to 538 C (650 to 1000 F) to remove hydrogen sulfide (H{sub 2}S) from coal-derived fuel gases in a fluidized-bed reactor. The goal was to develop sorbents that are capable of reducing the H{sub 2}S level in the fuel gas to less than 20 ppmv in the specified temperature range and pressures in the range of 1 to 20 atmospheres, with chemical characteristics that permit cyclic regeneration over many cycles without a drastic loss of activity, as well as physical characteristics that are compatible with the fluidized bed application.

  9. Supported-sorbent injection. Final report

    SciTech Connect (OSTI)

    Nelson, S. Jr.

    1997-07-01T23:59:59.000Z

    A new retrofitable, wastefree acid-rain control concept was pilot-tested at Ohio Edison`s high-sulfur coal-fired R.E. Burger generating station at the 2-MWe level. During the project, moistened {open_quotes}supported{close_quotes} sorbents, made from a combination of lime and vermiculite or perlite, were injected into a humidified 6,500-acfm flue-gas slipstream. After the sorbents reacted with the sulfur dioxide in the flue gas, they were removed from ductwork with a cyclone and baghouse. The $1.0 million project was co-funded by Sorbent Technologies Corporation, the Ohio Edison Company, and the Ohio Coal Development Office. The project included a preliminary bench-scale testing phase, construction of the pilot plant, parametric studies, numerous series of recycle tests, and a long-term run. The project proceeded as anticipated and achieved its expected results. This duct injection technology successfully demonstrated SO{sub 2}-removal rates of 80 to 90% using reasonable stoichiometric injection ratios (2:1 Ca:S) and approach temperatures (20-25F). Under similar conditions, dry injection of hydrated lime alone typically only achieves 40 to 50% SO{sub 2} removal. During the testing, no difficulties were encountered with deposits in the ductwork or with particulate control, which have been problems in tests of other duct-injection schemes.

  10. DP Awards | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Social Media DP Awards DP Awards Congrats to the Nat'l Security Campus teams that won Defense Program awards for work supporting stockpilestewardship http:1.usa.gov1rEZg2r...

  11. Investigation of regenerable sorbents for CO{sub 2} capture

    SciTech Connect (OSTI)

    Hoffman, J.S.; Pennline, H.W.

    1999-07-01T23:59:59.000Z

    An experimental investigation was undertaken in pursuit of identifying novel dry, regenerable scrubbing processes for the capture of CO{sub 2} from a gaseous stream. Recent investigations by Japanese researchers have identified supported alkali carbonate materials that can remove CO{sub 2} in the presence of water vapor to form an alkali bicarbonate. The sorbent is thermally regenerated by heating, yielding CO{sub 2} and H{sub 2}O as products. Conceptually, the water could be condensed and separated from the gaseous product stream of regeneration, yielding a concentrated stream of CO{sub 2} to be further processed into either a usable byproduct or disposed of as a waste. A bench-scale microbalance study of prepared sorbents was performed by exposing the sorbents initially to CO{sub 2}, followed by thermal regeneration. The experimental approach involved utilizing a thermogravimetric analyzer (TGA) to track sorbent weight change as the material was exposed to gases under conditions representative of absorption or regeneration. Change in sorbent weight was linked to the extent of chemical reaction, from which kinetic rate information was extracted. By conducting parametric evaluations of prepared sorbents, the impact of temperature and flue gas components on the absorption chemistry was studied. Temperature, and possible reducing agents, were investigated for the regeneration chemistry. Sorbents were prepared by impregnating various alkali- and alkaline-earth materials onto a substrate composed of high-surface area activated alumina. The first sorbent studied consisted of potassium carbonate deposited on alumina. Alkaline earth sorbents would likely include the investigation of magnesium and calcium materials. A preliminary thermodynamic analysis was conducted for some proposed sorbents of interest. Enthalpy and free energy changes were calculated for both absorption and regeneration reactions. Equilibrium constants were formulated over a temperature range of 77--212 F. Results for alkali-based sorbents are generally favorable in that the forward (CO{sub 2} absorption) reaction rate is typically much larger than the reverse reaction. Per the Japanese study using potassium, the absorption reaction of KOH with CO{sub 2} to form KHCO{sub 3} was calculated to be extremely favorable over the reverse reaction.

  12. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01T23:59:59.000Z

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  13. High capacity immobilized amine sorbents

    DOE Patents [OSTI]

    Gray, McMahan L. (Pittsburgh, PA); Champagne, Kenneth J. (Fredericktown, PA); Soong, Yee (Monroeville, PA); Filburn, Thomas (Granby, CT)

    2007-10-30T23:59:59.000Z

    A method is provided for making low-cost CO.sub.2 sorbents that can be used in large-scale gas-solid processes. The improved method entails treating an amine to increase the number of secondary amine groups and impregnating the amine in a porous solid support. The method increases the CO.sub.2 capture capacity and decreases the cost of utilizing an amine-enriched solid sorbent in CO.sub.2 capture systems.

  14. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01T23:59:59.000Z

    A test program is being sponsored by the US Department of Energy (DOE), EPRI, FirstEnergy, and TVA to investigate furnace injection of alkaline sorbents as a means of reducing sulfuric acid concentrations in the flue gas from coal-fired boilers. This test program is being conducted at the FirstEnergy Bruce Mansfield Plant (BMP), although later testing will be conducted at a TVA plant. A sorbent injection test was conducted the week of April 18, 2000. The test was the first of several short-term (one- to two-week duration) tests to investigate the effectiveness of various alkaline sorbents for sulfuric acid control and the effects of these sorbents on boiler equipment performance. This first short-term test investigated the effect of injecting dry dolomite powder (CaCO{sub 3} {center_dot} MgCO{sub 3}), a mineral similar to limestone, into the furnace of Unit 2. During the test program, various analytical techniques were used to assess the effects of sorbent injection. These primarily included sampling with the controlled condensation system (CCS) for determining flue gas SO{sub 3} content and an acid dew-point (ADP) meter for determining the sulfuric acid dew point (and, indirectly, the concentration of sulfuric acid) of the flue gas. EPA Reference Method 26a was used for determining hydrochloric acid (HCl) and hydrofluoric acid (HF), as well and chlorine (Cl{sub 2}) and fluorine (F{sub 2}) concentrations in the flue gas. Fly ash resistivity was measured using a Southern Research Institute (SRI) point-to-plane resistivity probe, and unburned carbon in fly ash was determined by loss on ignition (LOI). Coal samples were also collected and analyzed for a variety of parameters. Finally, visual observations were made of boiler furnace and convective pass surfaces prior to and during sorbent injection.

  15. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

    1988-01-01T23:59:59.000Z

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  16. Parametric study of solid amine sorbents for the capture of carbon dioxide

    SciTech Connect (OSTI)

    M.L. Gray; J.S. Hoffman; D.C. Hreha; D.J. Fauth; S.W. Hedges; K.J. Champagne; H.W. Pennline [United States Department of Energy, Pittsburgh, PA (United States). National Energy Technology Laboratory

    2009-09-15T23:59:59.000Z

    Solid amine sorbents were prepared using mixtures of linear and branched primary, secondary, and tertiary amines. These amines were immobilized within polystyrene (PS)-, silicon dioxide (SiO{sub 2})-, or polymethylmethacrylate (PMMA)-based substrates at various weight ratios. Testing was conducted in various reactor systems, where the reactive water required for the capture of carbon dioxide (CO{sub 2}) was tracked during the adsorption/desorption cycles by mass spectrometer gas analysis. The water management for these sorbents was quantified and used to assess the technical feasibility of the operating conditions for the capture of CO{sub 2} from simulated flue gas streams. In addition, the heats of reaction and performance capture loading capacities of these sorbents were also determined by differential scanning calorimetry (DSC) and thermogravimetric analyses (TGAs), respectively, in both dry and humidified CO{sub 2} gas streams. The regenerable solid amine sorbents investigated in this study exhibit acceptable CO{sub 2}-capture loading capacities of 2.5-3.5 mol of CO{sub 2}/kg of sorbent by TGA and a laboratory-scale fixed-bed reactor. These sorbents were stable over the adsorption/desorption temperature range of 25-105{sup o}C for 10 cyclic tests. According to the DSC analysis, the heat of reaction generated by these sorbents was in the range of 400-600 Btu/lb. CO{sub 2}, which will require a reactor with heat management capabilities. 6 refs., 4 figs., 3 tabs.

  17. Sol-gel derived sorbents

    DOE Patents [OSTI]

    Sigman, Michael E.; Dindal, Amy B.

    2003-11-11T23:59:59.000Z

    Described is a method for producing copolymerized sol-gel derived sorbent particles for the production of copolymerized sol-gel derived sorbent material. The method for producing copolymerized sol-gel derived sorbent particles comprises adding a basic solution to an aqueous metal alkoxide mixture for a pH.ltoreq.8 to hydrolyze the metal alkoxides. Then, allowing the mixture to react at room temperature for a precalculated period of time for the mixture to undergo an increased in viscosity to obtain a desired pore size and surface area. The copolymerized mixture is then added to an immiscible, nonpolar solvent that has been heated to a sufficient temperature wherein the copolymerized mixture forms a solid upon the addition. The solid is recovered from the mixture, and is ready for use in an active sampling trap or activated for use in a passive sampling trap.

  18. Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode

    SciTech Connect (OSTI)

    Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

    2012-07-01T23:59:59.000Z

    Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

  19. Regenerable sorbents for CO.sub.2 capture from moderate and high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    2008-01-01T23:59:59.000Z

    A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO.sub.4.2H.sub.2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

  20. Process for the manufacture of an attrition resistant sorbent used for gas desulfurization

    DOE Patents [OSTI]

    Venkataramani, Venkat S.; Ayala, Raul E.

    2003-09-16T23:59:59.000Z

    This process produces a sorbent for use in desulfurization of coal gas. A zinc titanate compound and a metal oxide are mixed by milling the compounds in an aqueous medium, the resulting mixture is dried and then calcined, crushed, sleved and formed into pellets for use in a moving-bed reactor. Metal oxides suitable for use as an additive in this process include: magnesium oxide, magnesium oxide plus molybdenum oxide, calcium oxide, yttrium oxide, hafnium oxide, zirconium oxide, cupric oxide, and tin oxide. The resulting sorbent has a percentage of the original zinc or titanium ions substituted for the oxide metal of the chosen additive.

  1. Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas

    SciTech Connect (OSTI)

    Lee, S.H.D.; Swift, W.M.; Johnson, I.

    1980-01-01T23:59:59.000Z

    Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

  2. Agglomeration of sorbent and ash carry-over for use in atmospheric fluidized-bed combustors

    SciTech Connect (OSTI)

    Rohargi, N.D.T.

    1983-04-01T23:59:59.000Z

    Agglomeration of elutriated sorbent, ash and char from a fluidized-bed boiler, with spent bed overflow material and water, has been identified as a potentially attractive technique for reducing sorbent consumption in atmospheric fluidized-bed combustors. The agglomerated products are returned to the combustor to improve the calcium utilization of the sorbent and to complete the combustion of elutriated carbon material. In this experimental programme, agglomerates were collected during test runs on the 1.8 m x 1.8 m fluidized-bed combustor. Agglomerate characteristics, such as handling strength, sulfur capture activity carbon utilization and resistance to attrition, were determined as functions of agglomeration processing variables. These variables include feed composition, feed particle size, amount of water addition, curing time, and curing atmosphere or drying conditions. Ca/S feed ratio requirements for a commercial AFBC that uses the agglomeration process were projected on the basis of the Westinghouse model for fluidized-bed desulphurization.

  3. ZnO-based regenerable sulfur sorbents for fluid-bed/transport reactor applications

    DOE Patents [OSTI]

    Slimane, Rachid B.; Abbasian, Javad; Williams, Brett E.

    2004-09-21T23:59:59.000Z

    A method for producing regenerable sulfur sorbents in which a support material precursor is mixed with isopropanol and a first portion of deionized water at an elevated temperature to form a sol mixture. A metal oxide precursor comprising a metal suitable for use as a sulfur sorbent is dissolved in a second portion of deionized water, forming a metal salt solution. The metal salt solution and the sol mixture are mixed with a sol peptizing agent while heating and stirring, resulting in formation of a peptized sol mixture. The metal oxide precursor is dispersed substantially throughout the peptized sol mixture, which is then dried, forming a dry peptized sol mixture. The dry peptized sol mixture is then calcined and the resulting calcined material is then converted to particles.

  4. Enhancing the use of coals by gas reburning-sorbent injection: Volume 3 -- Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x} and SO{sub 2} from a wall fired unit at Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the as found baseline of 0.98 lb/MBtu and to reduce emissions of SO{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an SO{sub 2} limit of 1.8 lb/MBtu, the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with SO{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The system was designed to inject sorbent at a rate corresponding to a calcium (sorbent) to sulfur (coal) molar ratio of 2.0. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  5. Sorbent utilization prediction methodology: sulfur control in fluidized-bed combustors

    SciTech Connect (OSTI)

    Fee, D.C.; Wilson, W.I.; Shearer, J.A.; Smith, G.W.; Lenc, J.F.; Fan, L.S.; Myles, K.M.; Johnson, I.

    1980-09-01T23:59:59.000Z

    The United States Government has embarked on an ambitious program to develop and commercialize technologies to efficiently extract energy from coal in an environmentally acceptable manner. One of the more promising new technologies for steam and power generation is the fluidized-bed combustion of coal. In this process, coal is burned in a fluidized bed composed mainly of calcined limestone sorbent. The calcium oxide reacts chemically to capture the sulfur dioxide formed during the combustion and to maintain the stack gas sulfur emissions at acceptable levels. The spent sulfur sorbent, containing calcium sulfate, is a dry solid that can be disposed of along with coal ash or potentially used. Other major advantages of fluidized-bed combustion are the reduction in nitrogen oxide emissions because of the relatively low combustion temperatures, the capability of burning wide varieties of fuel, the high carbon combustion efficiencies, and the high heat-transfer coefficients. A key to the widespread commercialization of fluidized-bed technology is the ability to accurately predict the amount of sulfur that will be captured by a given sorbent. This handbook meets this need by providing a simple, yet reliable, user-oriented methodology (the ANL method) that allows performance of a sorbent to be predicted. The methodology is based on only three essential sorbent parameters, each of which can be readily obtained from standardized laboratory tests. These standard tests and the subsequent method of data reduction are described in detail.

  6. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

    2014-09-02T23:59:59.000Z

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  7. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

    2008-10-14T23:59:59.000Z

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  8. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

    2012-05-01T23:59:59.000Z

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  9. evaluation-dry-sorbent-urs | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+eGallon:FinalTheNumerical

  10. Effects of Dilute Acid Pretreatment on Cellulose DP and the Relationship Between DP Reduction and Cellulose Digestibility

    SciTech Connect (OSTI)

    Wang, W.; Chen, X.; Tucker, M.; Himmel, M. E.; Johnson, D. K.

    2012-01-01T23:59:59.000Z

    The degree of polymerization(DP) of cellulose is considered to be one of the most important properties affecting the enzymatic hydrolysis of cellulose. Various pure cellulosic and biomass materials have been used in a study of the effect of dilute acid treatment on cellulose DP. A substantial reduction in DP was found for all pure cellulosic materials studied even at conditions that would be considered relatively mild for pretreatment. The effect of dilute acid pretreatment on cellulose DP in biomass samples was also investigated. Corn stover pretreated with dilute acid under the most optimal conditions contained cellulose with a DPw in the range of 1600{approx}3500, which is much higher than the level-off DP(DPw 150{approx}300) obtained with pure celluloses. The effect of DP reduction on the saccharification of celluloses was also studied. From this study it does not appear that cellulose DP is a main factor affecting cellulose saccharification.

  11. Stabilization of spent calcium-based sorbent

    SciTech Connect (OSTI)

    Shires, P.J.; Katta, S.; Henningsen, G.B.

    1994-10-01T23:59:59.000Z

    The overall objective of this project is to obtain experimental data on the reactions of calcium-based sorbents applicable to both air-blown coal gasification systems and second generation fluid bed coal combustion systems (partial gasification). The project is a 40-month effort. A key technical issue for the utilization of calcium sorbents in advanced coal technologies is the subsequent stabilization of the solid wastes (calcium sulfide/ash) produced by such systems.

  12. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, C.D.; Petersen, J.N.; Davison, B.H.

    1996-07-09T23:59:59.000Z

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, and larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. 8 figs.

  13. Continuous fluidized-bed contactor with recycle of sorbent

    DOE Patents [OSTI]

    Scott, Charles D. (Oak Ridge, TN); Petersen, James N. (Moscow, ID); Davison, Brian H. (Knoxville, TN)

    1996-01-01T23:59:59.000Z

    A continuous fluidized-bed contactor containing sorbent particles is used to remove solutes from liquid solvents. As the sorbent particles, for example gel beads, sorb the solute, for example metal ion species, the sorbent particles tend to decrease in diameter. These smaller loaded sorbent particles rise to the top of the contactor, as larger sorbent particles remain at the bottom of the contactor as a result of normal hydraulic forces. The smaller loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor. Alternatively, the loaded sorbent particles may also slightly increase in diameter, or exhibit no change in diameter but an increase in density. As a result of normal hydraulic forces the larger loaded sorbent particles fall to the bottom of the contactor. The larger loaded sorbent particles are then recovered, regenerated, and reintroduced into the contactor.

  14. Method of removing hydrogen sulfide from gases utilizing a zinc oxide sorbent and regenerating the sorbent

    DOE Patents [OSTI]

    Jalan, Vinod M. (Concord, MA); Frost, David G. (Maynard, MA)

    1984-01-01T23:59:59.000Z

    A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500.degree. C. to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent.

  15. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2004-01-01T23:59:59.000Z

    The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

  16. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    SciTech Connect (OSTI)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01T23:59:59.000Z

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at SRI and RTI to conduct tests at high-temperature, high-pressure conditions (HTHP). The HTHP tests confirmed the ability of nahcolite pellets and granules to reduce the HCl vapor levels to less than 1 ppm levels with a very high sorbent utilization for chloride capture. The effect of several operating variables such as temperature, pressure, presence of hydrogen sulfide, and sorbent preparation methods was studied on the efficacy of HCl removal by the sorbent. Pilot-scale tests were performed in the fluidized-bed mode at the gasifier facility at the GE-CRD. Sorbent exposure tests were also conducted using a hot coal gas stream from the DOE/FETC's fluidized-bed gasifier at Morgantown, WV. These tests confirmed the results obtained at SRI and RTI. A preliminary economic assessment showed that the cost of HCl removal in a commercial IGCC system will be about $0.001/kWh (1 mills/kWh).

  17. Sulfur tolerant highly durable CO.sub.2 sorbents

    DOE Patents [OSTI]

    Smirniotis, Panagiotis G. (Cincinnati, OH); Lu, Hong (Urbana, IL)

    2012-02-14T23:59:59.000Z

    A sorbent for the capture of carbon dioxide from a gas stream is provided, the sorbent containing calcium oxide (CaO) and at least one refractory dopant having a Tammann temperature greater than about 530.degree. C., wherein the refractory dopant enhances resistance to sintering, thereby conserving performance of the sorbent at temperatures of at least about 530.degree. C. Also provided are doped CaO sorbents for the capture of carbon dioxide in the presence of SO.sub.2.

  18. Topical Report 5: Sorbent Performance Report

    SciTech Connect (OSTI)

    Krutka, Holly; Sjostrom, Sharon

    2011-05-31T23:59:59.000Z

    ADA-ES has completed an extensive sorbent screening program funded primarily through DOE NETL cooperative agreement DE-NT0005649 with support from EPRI and industry cost-share participants. Tests were completed on simulated and actual flue gas. The overall project objective is to address the viability and accelerate development of a solid-based postcombustion CO2 capture technology that can be retrofit to the existing fleet of coal-fired power plants. An important component of the viability assessment was to evaluate the state of development of sorbents and measure key performance characteristics under realistic operating conditions.

  19. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2003-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  20. Alkaline sorbent injection for mercury control

    DOE Patents [OSTI]

    Madden, Deborah A. (Boardman, OH); Holmes, Michael J. (Washington Township, Stark County, OH)

    2002-01-01T23:59:59.000Z

    A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

  1. Carbon dioxide capture process with regenerable sorbents

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

    2002-05-14T23:59:59.000Z

    A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

  2. Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani (Morgantown, WV)

    2010-08-03T23:59:59.000Z

    Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

  3. Remarks on D_p and D_{p-2} with each carrying a flux

    E-Print Network [OSTI]

    J. X. Lu; Shan-Shan Xu

    2009-09-04T23:59:59.000Z

    We explore various properties of interaction between D$_p$ and D$_{p'}$ with each carrying a worldvolume flux and with the $p'$-branes placed along $p'$ spatial worldvolume directions of the p-branes at a separation when $p - p' = 2$. Carefully analyzing the annulus amplitudes calculated via the boundary state approach, we find that many features of amplitudes remain similar to those studied when $p = p'$ such as the nature of force on the brane separation, the onset of various instabilities when the brane-separation is on the order of string scale and the occurrence of pair production of open strings when there is a relevant electric flux present. In addition, we have also found many new features of interaction which don't appear in the absence of fluxes or when $p = p'$ in the presence of fluxes, for examples, the nature of interaction can be repulsive and there is no onset of tachyonic instability under certain conditions. Even in the absence of a magnetic flux, we can have an exponential enhancement of the rate of pair production of open strings in certain cases, which may be significant enough to give observational consequences.

  4. Pilot-scale testing of a new sorbent for combined SO{sub 2}/NO{sub x} removal. Final report

    SciTech Connect (OSTI)

    Nelson, S. Jr. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1994-06-01T23:59:59.000Z

    A new regenerable sorbent concept for SO{sub 2} and NOx removal was pilot-tested at Ohio Edison`s Edgewater generating station at a 1.5 to 2-MW(e) level. A radial panel-bed filter of a new dry, granular sorbent was exposed to flue gas and regenerated in an experimental proof-of-concept program. The project was successful in demonstrating the new sorbent`s ability to achieve 90% SO{sub 2} removal, 30% NOx removal, and over 80% removal of residual particulates with realistic approach temperatures and low pressure drops. Based on the results of this project, the retrofit cost of this technology is expected to be on the order of $400 per ton of SO{sub 2} and $900 per ton of NOx removed. This assumes that gas distribution is even and methane regeneration is used for a 30% average utilization. For a 2.5%-sulfur Ohio coal, this translates to a cost of approximately $17 per ton of coal. Two by-product streams were generated in the process that was tested: a solid, spent-sorbent stream and a highly-concentrated SO{sub 2} or elemental-sulfur stream. While not within the scope of the project, it was found possible to process these streams into useful products. The spent sorbent materials were shown to be excellent substrates for soil amendments; the elemental sulfur produced is innocuous and eminently marketable.

  5. KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS

    SciTech Connect (OSTI)

    K.C. Kwon

    2002-01-01T23:59:59.000Z

    Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. The reactivity of MCRH-67 was examined in this report. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 130 mm particles are reacted with 18000-ppm hydrogen sulfide at 350-525 C. The range of space time of reaction gas mixtures is 0.069-0.088 s. The range of reaction duration is 4-180 s.

  6. Layered solid sorbents for carbon dioxide capture

    SciTech Connect (OSTI)

    Li, Bingyun; Jiang, Bingbing; Gray, McMahan L; Fauth, Daniel J; Pennline, Henry W; Richards, George A

    2014-11-18T23:59:59.000Z

    A solid sorbent for the capture and the transport of carbon dioxide gas is provided having at least one first layer of a positively charged material that is polyethylenimine or poly(allylamine hydrochloride), that captures at least a portion of the gas, and at least one second layer of a negatively charged material that is polystyrenesulfonate or poly(acryclic acid), that transports the gas, wherein the second layer of material is in juxtaposition to, attached to, or crosslinked with the first layer for forming at least one bilayer, and a solid substrate support having a porous surface, wherein one or more of the bilayers is/are deposited on the surface of and/or within the solid substrate. A method of preparing and using the solid sorbent is provided.

  7. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1990-10-20T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. Progress is discussed.

  8. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1990-07-19T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, is on hold'' because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80{endash}85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  9. Cesium removal demonstration utilizing crystalline silicotitanate sorbent for processing Melton Valley Storage Tank supernate: Final report

    SciTech Connect (OSTI)

    Walker, J.F. Jr.; Taylor, P.A.; Cummins, R.L. [and others] [and others

    1998-03-01T23:59:59.000Z

    This report provides details of the Cesium Removal Demonstration (CsRD), which was conducted at Oak Ridge National Laboratory (ORNL) on radioactive waste from the Melton Valley Storage Tanks. The CsRD was the first large-scale use of state-of-the-art sorbents being developed by private industry for the selective removal of cesium and other radionuclides from liquid wastes stored across the DOE complex. The crystalline silicotitanate sorbent used in the demonstration was chosen because of its effectiveness in laboratory tests using bench-scale columns. The demonstration showed that the cesium could be removed from the supernate and concentrated on a small-volume, solid waste form that would meet the waste acceptance criteria for the Nevada Test Site. During this project, the CsRD system processed > 115,000 L (30,000 gal) of radioactive supernate with minimal operational problems. Sluicing, drying, and remote transportation of the sorbent, which could not be done on a bench scale, were successfully demonstrated. The system was then decontaminated to the extent that it could be contact maintained with the use of localized shielding only. By utilizing a modular, transportable design and placement within existing facilities, the system can be transferred to different sites for reuse. The initial unit has now been removed from the process building and is presently being reinstalled for use in baseline operations at ORNL.

  10. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1989-09-27T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  11. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1988-12-22T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace, at the superheater exit or into the ducting following the air heater. The sorbents trap SO{sub x} as solid sulfates and sulfites, which are collected in the particulate control device.

  12. Agglomeration of sorbent and ash carry-over for use in atmospheric fluidized-bed combustors

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.; Kealrns, D.L.; Newby, R.A.; Ulerich, N.H.

    1983-04-01T23:59:59.000Z

    Agglomeration of elutriated sorbent, ash, and char from a fluidized-bed boiler, with spent bed overflow material and water, has been identified as a potentially attractive technique for reducing sorbent consumption in atmospheric fluidized-bed combustors (AFBC). The agglomerated products are returned to the combustor to improv the calcium utilization of the sorbent and to complete the combustion of elutriated carbon material. In this experimental program, agglomerates were formed from Babcock and Wilcox (BandW) raw materials (Carbon limestone, spent bed overflow, cyclone and baghouse catch) collected during test runs on the 1.8 m X 1.8 m fluidized-bed combustor. Agglomerate characteristics, such as handling strength, sulfur capture activity, carbon utilization, and resistance to attrition, were determined as functions of agglomeration processing variables. These variables include feed composition, feed particle size, amount of water addition, curing time, and curing atmosphere or drying conditions. Calcium-to-sulfur (Ca/S) feed ratio requirements for a commercial AFBC that uses the agglomeration process were projected on the basis of the Westinghouse model for fluidized-bed desulfurization.

  13. ADVANCED SORBENT DEVELOPMENT PROGRAM DEVELOPMENT OF SORBENTS FOR MOVING-BED AND FLUIDIZED-BED APPLICATIONS

    SciTech Connect (OSTI)

    R.E Ayala; V.S. Venkataramani; Javad Abbasian; Rachid B. Slimane; Brett E. Williams; Minoo K. Zarnegar; James R. Wangerow; Andy H. Hill

    2000-03-31T23:59:59.000Z

    The integrated gasification combined cycle (IGCC) power system using high-temperature coal gas cleanup is one of the most promising advanced technologies for the production of electric power from coal in an environmentally acceptable manner. Unlike conventional low-temperature cleanup systems that require costly heat exchangers, high-temperature coal gas cleanup systems can be operated near 482-538 C (900-1000 F) or higher, conditions that are a closer match with the gasifier and turbine components in the IGCC system, thus resulting is a more efficient overall system. GE is developing a moving-bed, high-temperature desulfurization system for the IGCC power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other proprietary zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.'s (TECo) Polk Power Station. Under cold startup conditions at TECo, desulfurization and regeneration may be carried out at temperatures as low as 343 C (650 F), hence a versatile sorbent is desirable to perform over this wide temperature range. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The overall objective of this program is to develop regenerable sorbents for hydrogen sulfide removal from coal-derived fuel gases in the temperature range 343-538 C (650-1000 F). Two categories of reactor configurations are being considered: moving-bed reactors and fluidized-bed (bubbling and circulating) reactors. In addition, a cost assessment and a market plan for large-scale fabrication of sorbents were developed. As an optional task, long-term bench-scale tests of the best moving-bed sorbents were conducted. Starting from thermodynamic calculations, several metal oxides were identified for potential use as hot gas cleanup sorbents using constructed phase stability diagrams and laboratory screening of various mixed-metal oxide formulations. Modified zinc titanates and other proprietary metal oxide formulations were evaluated at the bench scale and many of them found to be acceptable for operation in the target desulfurization temperature range of 370 C (700 F) to 538 C (1000 F) and regeneration temperatures up to 760 C (1400 F). Further work is still needed to reduce the batch-to-batch repeatability in the fabrication of modified zinc titanates for larger scale applications. The information presented in this Volume 1 report contains the results of moving-bed sorbent development at General Electric's Corporate Research and Development (GE-CRD). A separate Volume 2 report contains the results of the subcontract on fluidized-bed sorbent development at the Institute of Gas Technology (IGT).

  14. Regenerable sorbent technique for capturing CO.sub.2 using immobilized amine sorbents

    DOE Patents [OSTI]

    Pennline, Henry W; Hoffman, James S; Gray, McMahan L; Fauth, Daniel J; Resnik, Kevin P

    2013-08-06T23:59:59.000Z

    The disclosure provides a CO.sub.2 absorption method using an amine-based solid sorbent for the removal of carbon dioxide from a gas stream. The method disclosed mitigates the impact of water loading on regeneration by utilizing a conditioner following the steam regeneration process, providing for a water loading on the amine-based solid sorbent following CO.sub.2 absorption substantially equivalent to the moisture loading of the regeneration process. This assists in optimizing the CO.sub.2 removal capacity of the amine-based solid sorbent for a given absorption and regeneration reactor size. Management of the water loading in this manner allows regeneration reactor operation with significant mitigation of energy losses incurred by the necessary desorption of adsorbed water.

  15. Sorbents and Carbon-Based Materials for Hydrogen Storage R &...

    Broader source: Energy.gov (indexed) [DOE]

    for storing hydrogen in high-surface-area sorbents such as hybrid carbon nanotubes, aerogels, and nanofibers, as well as metal-organic frameworks and conducting polymers. A...

  16. sorbent-univerisity-north-dakota | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report PDF (Nov 2012) Evaluation of Carbon Dioxide Capture from Existing Coal Fired Power Plants by Hybrid Sorption Using Solid Sorbents PDF (Sept 2012) Project Review...

  17. Sorbents and Carbon-Based Materials for Hydrogen Storage Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for storing hydrogen in high-surface-area sorbents such as hybrid carbon nanotubes, aerogels, and nanofibers, as well as metal-organic frameworks and conducting polymers. A...

  18. Benchmark on neutron capture extracted from $(d,p)$ reactions

    E-Print Network [OSTI]

    A. M. Mukhamedzhanov; F. M. Nunes; P. Mohr

    2008-05-30T23:59:59.000Z

    Direct neutron capture reactions play an important role in nuclear astrophysics and applied physics. Since for most unstable short-lived nuclei it is not possible to measure the $(n, \\gamma)$ cross sections, $(d,p)$ reactions have been used as an alternative indirect tool. We analyze simultaneously $^{48}{\\rm Ca}(d,p)^{49}{\\rm Ca}$ at deuteron energies $2, 13, 19$ and 56 MeV and the thermal $(n,\\gamma)$ reaction at 25 meV. We include results for the ground state and the first excited state of $^{49}$Ca. From the low-energy $(d,p)$ reaction, the neutron asymptotic normalization coefficient (ANC) is determined. Using this ANC, we extract the spectroscopic factor (SF) from the higher energy $(d,p)$ data and the $(n, \\gamma)$ data. The SF obtained through the 56 MeV $(d,p)$ data are less accurate but consistent with those from the thermal capture. We show that to have a similar dependence on the single particle parameters as in the $(n, \\gamma)$, the (d,p) reaction should be measured at 30 MeV.

  19. Separable Optical Potentials for (d,p) Reactions

    E-Print Network [OSTI]

    Ch. Elster; L. Hlophe; V. Eremenko; F. M. Nunes; G. Arbanas; J. E. Escher; I. J. Thompson

    2014-10-05T23:59:59.000Z

    An important ingredient for applications of nuclear physics to e.g. astrophysics or nuclear energy are the cross sections for reactions of neutrons with rare isotopes. Since direct measurements are often not possible, indirect methods like (d,p) reactions must be used instead. Those (d,p) reactions may be viewed as effective three-body reactions and described with Faddeev techniques. An additional challenge posed by (d,p) reactions involving heavier nuclei is the treatment of the Coulomb force. To avoid numerical complications in dealing with the screening of the Coulomb force, recently a new approach using the Coulomb distorted basis in momentum space was suggested. In order to implement this suggestion, one needs not only to derive a separable representation of neutron- and proton-nucleus optical potentials, but also compute the Coulomb distorted form factors in this basis.

  20. Functionalized sorbent for chemical separations and sequential forming process

    DOE Patents [OSTI]

    Fryxell, Glen E. (Kennewick, WA); Zemanian, Thomas S. (Richland, WA)

    2012-03-20T23:59:59.000Z

    A highly functionalized sorbent and sequential process for making are disclosed. The sorbent includes organic short-length amino silanes and organic oligomeric polyfunctional amino silanes that are dispersed within pores of a porous support that form a 3-dimensional structure containing highly functionalized active binding sites for sorption of analytes.

  1. DEVELOPMENT OF A CATALYST/SORBENT FOR METHANE REFORMING

    SciTech Connect (OSTI)

    B.H. Shanks; T.D. Wheelock; Justinus A. Satrio; Timothy Diehl; Brigitte Vollmer

    2004-09-27T23:59:59.000Z

    This work has led to the initial development of a very promising material that has the potential to greatly simplify hydrocarbon reforming for the production of hydrogen and to improve the overall efficiency and economics of the process. This material, which was derived from an advanced calcium-based sorbent, was composed of core-in-shell pellets such that each pellet consisted of a CaO core and an alumina-based shell. By incorporating a nickel catalyst in the shell, a combined catalyst and sorbent was prepared to facilitate the reaction of hydrocarbons with steam. It was shown that this material not only catalyzes the reactions of methane and propane with steam, it also absorbs CO{sub 2} simultaneously, and thereby separates the principal reaction products, H{sub 2} and CO{sub 2}. Furthermore, the absorption of CO{sub 2} permits the water gas shift reaction to proceed much further towards completion at temperatures where otherwise it would be limited severely by thermodynamic equilibrium. Therefore, an additional water gas shift reaction step would not be required to achieve low concentrations of CO. In a laboratory test of methane reforming at 600 C and 1 atm it was possible to produce a gaseous product containing 96 mole% H{sub 2} (dry basis) while also achieving a H{sub 2} yield of 95%. Methane reforming under these conditions without CO{sub 2} absorption provided a H{sub 2} concentration of 75 mole% and yield of 82%. Similar results were achieved in a test of propane reforming at 560 C and 1 atm which produced a product containing 96 mole% H{sub 2} while CO{sub 2} was being absorbed but which contained only 69 mole% H{sub 2} while CO{sub 2} was not being absorbed. These results were achieved with an improved catalyst support that was developed by replacing a portion of the {alpha}-alumina in the original shell material with {gamma}-alumina having a much greater surface area. This replacement had the unfortunate consequence of reducing the overall compressive strength of the core-in-shell pellets. Therefore, a preliminary study of the factors that control the surface area and compressive strength of the shell material was conducted. The important factors were identified as the relative concentrations and particle size distributions of the {alpha}-alumina, {gamma}-alumina, and limestone particles plus the calcination temperature and time used for sintering the shell material. An optimization of these factors in the future could lead to the development of a material that has both the necessary mechanical strength and catalytic activity.

  2. Activities of the University Fusion Association! D.P. Brennan

    E-Print Network [OSTI]

    .universityfusion.org! #12;STABILITY is extremely important in university funding! Our university programs in fusion science.! The stability of funding for fusion research is Key to the sustainment of a robust university communityActivities of the University Fusion Association! D.P. Brennan Princeton University Presented

  3. ERIA-DP-2011-03 ERIA Discussion Paper Series

    E-Print Network [OSTI]

    ERIA-DP-2011-03 ERIA Discussion Paper Series Harmonizing Biodiesel Fuel Standards in East Asia Asia (ERIA), Indonesia Shinichi GOTO Research Center for New Fuels and Vehicle Technology (NFV), National Institute of Advanced Industrial Science and Technology (AIST), Japan May 2011 Abstract

  4. The ADESORB Process for Economical Production of Sorbents for Mercury Removal from Coal Fired Power Plants

    SciTech Connect (OSTI)

    Robin Stewart

    2008-03-12T23:59:59.000Z

    The DOE's National Energy Technology Laboratory (NETL) currently manages the largest research program in the country for controlling coal-based mercury emissions. NETL has shown through various field test programs that the determination of cost-effective mercury control strategies is complex and highly coal- and plant-specific. However, one particular technology has the potential for widespread application: the injection of activated carbon upstream of either an electrostatic precipitator (ESP) or a fabric filter baghouse. This technology has potential application to the control of mercury emissions on all coal-fired power plants, even those with wet and dry scrubbers. This is a low capital cost technology in which the largest cost element is the cost of sorbents. Therefore, the obvious solutions for reducing the costs of mercury control must focus on either reducing the amount of sorbent needed or decreasing the cost of sorbent production. NETL has researched the economics and performance of novel sorbents and determined that there are alternatives to the commercial standard (NORIT DARCO{reg_sign} Hg) and that this is an area where significant technical improvements can still be made. In addition, a key barrier to the application of sorbent injection technology to the power industry is the availability of activated carbon production. Currently, about 450 million pounds ($250 million per year) of activated carbon is produced and used in the U.S. each year - primarily for purification of drinking water, food, and beverages. If activated carbon technology were to be applied to all 1,100 power plants, EPA and DOE estimate that it would require an additional $1-$2 billion per year, which would require increasing current capacity by a factor of two to eight. A new facility to produce activated carbon would cost approximately $250 million, would increase current U.S. production by nearly 25%, and could take four to five years to build. This means that there could be significant shortages in supply if response to new demand is not well-timed.

  5. Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    None

    1998-09-01T23:59:59.000Z

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

  6. Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    None

    1998-06-01T23:59:59.000Z

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

  7. Enhancing the use of coals by gas reburning-sorbent injection. Volume 3, Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x}, and SO{sub 2} from a wall fired unit. A GR-SI system was designed for Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The unit is rated at 117 MW(e) (net) and is front wall fired with a pulverized bituminous coal blend. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the ``as found`` baseline of 0.98 lb/MBtu (420 mg/MJ), and to reduce emissions of S0{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an S0{sub 2} limit Of 1.8 lb/MBtu (770 mg/MJ), the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. The design natural gas input corresponds to 18% of the total heat input. Burnout (overfire) air is injected at a higher elevation to burn out fuel combustible matter at a normal excess air level of 18%. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with S0{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  8. Interaction Between Trace Metals, Sodium and Sorbents in Combustion.

    SciTech Connect (OSTI)

    Wendt, O.L.; Davis, S.

    1997-10-17T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  9. SOx/NOx sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1993-01-19T23:59:59.000Z

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilizing spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

  10. SOX/NOX sorbent and process of use

    DOE Patents [OSTI]

    Ziebarth, M.S.; Hager, M.J.; Beeckman, J.W.; Plecha, S.

    1995-05-09T23:59:59.000Z

    An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 600 C is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and dripped to form the stabilized spheroidal alumina particles. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths. 3 figs.

  11. Octahedral molecular sieve sorbents and catalysts

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2010-04-20T23:59:59.000Z

    Octahedral molecular sieve sorbents and catalysts are disclosed, including silver hollandite and cryptomelane. These materials can be used, for example, to catalyze the oxidation of CO.sub.x (e.g., CO), NO.sub.x (e.g., NO), hydrocarbons (e.g., C.sub.3H.sub.6) and/or sulfur-containing compounds. The disclosed materials also may be used to catalyze other reactions, such as the reduction of NO.sub.2. In some cases, the disclosed materials are capable of sorbing certain products from the reactions they catalyze. Silver hollandite, in particular, can be used to remove a substantial portion of certain sulfur-containing compounds from a gas or liquid by catalysis and/or sorption. The gas or liquid can be, for example, natural gas or a liquid hydrocarbon.

  12. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2005-12-30T23:59:59.000Z

    The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at Laramie River Station Unit 3, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program is to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL are to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the benchmark established by DOE of $60,000/lb mercury removed. The goals of the program were exceeded at Laramie River Station by achieving over 90% mercury removal at a sorbent cost of $3,980/lb ($660/oz) mercury removed for a coal mercury content of 7.9 lb/TBtu.

  13. Gauge symmetries decrease the number of Dp-brane dimensions

    SciTech Connect (OSTI)

    Nikolic, B.; Sazdovic, B. [Institute of Physics, 11001 Belgrade, P.O. Box 57 (Serbia and Montenegro)

    2006-08-15T23:59:59.000Z

    It is known that the presence of the antisymmetric background field B{sub {mu}}{sub {nu}} leads to the noncommutativity of the Dp-brane manifold. The addition of the linear dilaton field in the form {phi}(x)={phi}{sub 0}+a{sub {mu}}x{sup {mu}} causes the appearance of the commutative Dp-brane coordinate x=a{sub {mu}}x{sup {mu}}. In the present article we show that for some particular choices of the background fields, a{sup 2}{identical_to}G{sup {mu}}{sup {nu}}a{sub {mu}}a{sub {nu}}=0 and a-tilde{sup 2}{identical_to}[(G-4BG{sup -1}B){sup -1}]{sup {mu}}{sup {nu}}a{sub {mu}}a{sub {nu}}=0, the local gauge symmetries appear in the theory. They turn some Neuman boundary conditions into the Dirichlet ones, and consequently decrease the number of the Dp-brane dimensions.

  14. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, B.S.; Gupta, R.P.

    1999-06-22T23:59:59.000Z

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream. 1 fig.

  15. Process for preparing zinc oxide-based sorbents

    DOE Patents [OSTI]

    Gangwal, Santosh Kumar (Cary, NC); Turk, Brian Scott (Durham, NC); Gupta, Raghubir Prasad (Durham, NC)

    2011-06-07T23:59:59.000Z

    The disclosure relates to zinc oxide-based sorbents, and processes for preparing and using them. The sorbents are preferably used to remove one or more reduced sulfur species from gas streams. The sorbents comprise an active zinc component, optionally in combination with one or more promoter components and/or one or more substantially inert components. The active zinc component is a two phase material, consisting essentially of a zinc oxide (ZnO) phase and a zinc aluminate (ZnAl.sub.2O.sub.4) phase. Each of the two phases is characterized by a relatively small crystallite size of typically less than about 500 Angstroms. Preferably the sorbents are prepared by converting a precursor mixture, comprising a precipitated zinc oxide precursor and a precipitated aluminum oxide precursor, to the two-phase, active zinc oxide containing component.

  16. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Hopper, J.R.

    1996-06-01T23:59:59.000Z

    Experiments were conducted in a 1-in. quartz fluidized bed combustor enclosed in an electric furnace. Coal samples were burned in the bed with a sorbent under specific combustion conditions and the amount of metal capture by the sorbent determined. Three different cao samples from the Illinois Basin Coal Sample Bank were tested. Metals involved were Cd, Pb, and Cr; the sorbents included bauxite, zeolite, and lime. Potential metal-sorbent reactions were identified. Results indicated that metal capture by sorbent can be as high as 96%, depending on the metal species and sorbent. All 3 sorbents were capable of capturing Pb, zeolite and lime were able to capture Cr, and bauxite was the only sorbent capable of capturing Cd. Thermodynamic equilibrium calculations suggested the formation of metal-sorbent compounds such as Pb{sub 2}SiO{sub 4}, CdAl{sub 2}O{sub 4}, and CdSiO{sub 3} solids under the combustion conditions.

  17. Engineered sorbent barriers for low-level waste disposal.

    SciTech Connect (OSTI)

    Freeman, H.D.; Mitchell, S.J.; Buelt, J.L.

    1986-12-01T23:59:59.000Z

    The Engineered Sorbent Barriers Program at Pacific Northwest Laboratory is investigating sorbent materials to prevent the migration of soluble radio nuclides from low-level waste sites. These materials would allow water to pass, preventing the bathtub effect at humid sites. Laboratory studies identifield promising sorbent materials for three key radionuclides: for cesium, greensand; for cobalt, activated charcoal; and for strontium, synthetic zeolite or clinoptilolite. Mixtures of these sorbent materials were tested in 0.6-m-diameter columns using radioactive leachates. To simulate expected worst-case conditions, the leachate solution contained the radionuclides, competing cations, and a chelating agent and was adjusted to a pH of 5. A sorbent barrier comprised of greensand (1 wt%), activated charcoal (6 wt%), synthetic zeolite (20 wt%), and local soil (73 wt%) achieved the decontamination factors necessary to meet the regulatory performance requirements established for this study. Sorbent barriers can be applied to shallow-land burial, as backfill around the waste or engineered structures, or as backup to other liner systems. 7 refs., 14 figs., 12 tabs.

  18. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 11, April 1--June 30, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-07-19T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, is ``on hold`` because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80{endash}85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  19. Evaluation of Sorbent Injection for Mercury Control

    SciTech Connect (OSTI)

    Sharon Sjostrom

    2006-04-30T23:59:59.000Z

    The power industry in the U.S. is faced with meeting new regulations to reduce the emissions of mercury compounds from coal-fired plants. These regulations are directed at the existing fleet of nearly 1,100 boilers. These plants are relatively old with an average age of over 40 years. Although most of these units are capable of operating for many additional years, there is a desire to minimize large capital expenditures because of the reduced (and unknown) remaining life of the plant to amortize the project. Injecting a sorbent such as powdered activated carbon into the flue gas represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. This is the final site report for tests conducted at DTE Energy's Monroe Power Plant, one of five sites evaluated in this DOE/NETL program. The overall objective of the test program was to evaluate the capabilities of activated carbon injection at five plants: Sunflower Electric's Holcomb Station Unit 1, AmerenUE's Meramec Station Unit 2, Missouri Basin Power Project's Laramie River Station Unit 3, Detroit Edison's Monroe Power Plant Unit 4, and AEP's Conesville Station Unit 6. These plants have configurations that together represent 78% of the existing coal-fired generation plants. The goals for the program established by DOE/NETL were to reduce the uncontrolled mercury emissions by 50 to 70% at a cost 25 to 50% lower than the target established by DOE of $60,000/lb mercury removed. The results from Monroe indicate that using DARCO{reg_sign} Hg would result in higher mercury removal (80%) at a sorbent cost of $18,000/lb mercury, or 70% lower than the benchmark. These results demonstrate that the goals established by DOE/NETL were exceeded during this test program. The increase in mercury removal over baseline conditions is defined for this program as a comparison in the outlet emissions measured using the Ontario Hydro method during the baseline and long-term test periods. The change in outlet emissions from baseline to long-term testing was 81%.

  20. DOE-DP-STD-3016-99 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"WaveInteractionsMaterialsDevelopEnergyofDepartmentDP-STD-3016-99

  1. DOCUMENT DE TRAVAIL -L.E.S.T.-UMR 6123 !"#$#%&'(0)&123# #$ 4 5 6789$46&9 '(A@12BDCDEF6&GH I9P"QDRTS S UVBW)9CX@X`YacbFBcRedfBcDS gFhRed`iRpiRTqFReb rs&5 Ptvuw6&#v6&xtwyDP @DP CHP #EP yy`BDQ36w twyDP @HP"@XHP #DP 02 e&9d e fg$ehji k9l

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    &¢#v6&¨xtwy¥DP ¥@DP C¥HP #E¥P y¥y`BDQ36w twy¥DP ¥@HP"@¥XHP #DP 02 e&9d e f£g$ehji k9l m (n2t oo c5

  2. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and...

    Office of Environmental Management (EM)

    Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power - Fact Sheet, 2015 Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power - Fact Sheet, 2015 TDA Research...

  3. P R O D U C T N O T E Size Exclusion Chromatography Sorbents

    E-Print Network [OSTI]

    Lebendiker, Mario

    . These characteristics allow Trisacryl® GF05 sorbents to perform chromato- graphic separations quickly and with great: Chemical structure of Trisacryl GF05 sorbents. * Calculated on the basis of a standard experimental curve

  4. Chalcogen-Based Aerogels as Sorbents for Radionuclide Remediation

    SciTech Connect (OSTI)

    Riley, Brian J.; Chun, Jaehun; Um, Wooyong; Lepry, William C.; Matyas, Josef; Olszta, Matthew J.; Li, Xiaohong; Polychronopoulou, Kyriaki; Kanatzidis, Mercouri G.

    2013-06-13T23:59:59.000Z

    The efficient capture of radionuclides having long half-lives such as technetium-99 (99Tc), uranium-238 (238U), and iodine-129 (129I) is pivotal to prevent their transport into groundwater and/or release into the atmosphere. While different sorbents have been considered for capturing each of them, in the current work, a new nanostructured chalcogen-based aerogel, called a chalcogel, is shown to be very effective to capture ionic forms of 99Tc and 238U, as well as nonradioactive gaseous iodine (i.e., a surrogate for 129I), irrespective of the sorbent polarity. Some of the chalcogels performed better than others but the PtGeS sorbent performed the best with capture efficiencies of 98% and 99.4% for 99Tc and 238U, respectively. All sorbents showed >99% capture efficiency for iodine over the test duration. This unified sorbent would be an attractive option in environmental remediation for various radionuclides associated with legacy wastes from nuclear weapons production, wastes from nuclear power production, or potential future nuclear fuel reprocessing.

  5. Friction Stir Spot Welding of DP780 Carbon Steel

    SciTech Connect (OSTI)

    Santella, Michael L [ORNL; Hovanski, Yuri [ORNL; Frederick, David Alan [ORNL; Grant, Glenn J [ORNL; Dahl, Michael E [ORNL

    2010-01-01T23:59:59.000Z

    Friction stir spot welds were made in uncoated and galvannealed DP780 sheets using polycrystalline boron nitride stir tools. The tools were plunged at either a single continuous rate or in two segments consisting of a relatively high rate followed by a slower rate of shorter depth. Welding times ranged from 1 to 10 s. Increasing tool rotation speed from 800 to 1600 rev min{sup -1} increased strength values. The 2-segment welding procedures also produced higher strength joints. Average lap shear strengths exceeding 10 {center_dot} 3 kN were consistently obtained in 4 s on both the uncoated and the galvannealed DP780. The likelihood of diffusion and mechanical interlocking contributing to bond formation was supported by metallographic examinations. A cost analysis based on spot welding in automobile assembly showed that for friction stir spot welding to be economically competitive with resistance spot welding the cost of stir tools must approach that of resistance spot welding electrode tips.

  6. Neuronal differentiation modulates the dystrophin Dp71d binding to the nuclear matrix

    SciTech Connect (OSTI)

    Rodriguez-Munoz, Rafael; Villarreal-Silva, Marcela; Gonzalez-Ramirez, Ricardo [Departamento de Genetica y Biologia Molecular, Centro de Investigacion y de Estudios Avanzados del IPN, Avenida Instituto Politecnico Nacional 2508, Apartado Postal 14-740, C.P. 07360, Mexico D.F. (Mexico); Garcia-Sierra, Francisco [Departamento de Biologia Celular, Centro de Investigacion y de Estudios Avanzados del IPN, Avenida Instituto Politecnico Nacional 2508, Apartado Postal 14-740, C.P. 07360, Mexico D.F. (Mexico); Mondragon, Monica; Mondragon, Ricardo [Departamento de Bioquimica, Centro de Investigacion y de Estudios Avanzados del IPN, Avenida Instituto Politecnico Nacional 2508, Apartado Postal 14-740, C.P. 07360, Mexico D.F. (Mexico); Cerna, Joel [Facultad de Medicina, Universidad de Colima, Avenida Universidad 333. C.P. 28040 Colima, Col. (Mexico); Cisneros, Bulmaro [Departamento de Genetica y Biologia Molecular, Centro de Investigacion y de Estudios Avanzados del IPN, Avenida Instituto Politecnico Nacional 2508, Apartado Postal 14-740, C.P. 07360, Mexico D.F. (Mexico)], E-mail: bcisnero@cinvestav.mx

    2008-10-24T23:59:59.000Z

    The function of dystrophin Dp71 in neuronal cells remains unknown. To approach this issue, we have selected the PC12 neuronal cell line. These cells express both a Dp71f cytoplasmic variant and a Dp71d nuclear isoform. In this study, we demonstrated by electron and confocal microscopy analyses of in situ nuclear matrices and Western blotting evaluation of cell extracts that Dp71d associates with the nuclear matrix. Interestingly, this binding is modulated during NGF-induced neuronal differentiation of PC12 cells with a twofold increment in the differentiated cells, compared to control cells. Also, distribution of Dp71d along the periphery of the nuclear matrix observed in the undifferentiated cells is replaced by intense fluorescent foci localized in Center of the nucleoskeletal structure. In summary, we revealed that Dp71d is a dynamic component of nuclear matrix that might participate in the nuclear modeling occurring during neuronal differentiation.

  7. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    SciTech Connect (OSTI)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

    2002-09-20T23:59:59.000Z

    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  8. Deep Bed Iodine Sorbent Testing FY 2011 Report

    SciTech Connect (OSTI)

    Nick Soelberg; Tony Watson

    2011-08-01T23:59:59.000Z

    Nuclear fission results in the production of fission products (FPs) and activation products that increasingly interfere with the fission process as their concentrations increase. Some of these fission and activation products tend to evolve in gaseous species during used nuclear fuel reprocessing. Analyses have shown that I129, due to its radioactivity, high potential mobility in the environment, and high longevity (half life of 15.7 million years), can require control efficiencies of up to 1,000x or higher to meet regulatory emission limits. Deep-bed iodine sorption testing has been done to evaluate the performance of solid sorbents for capturing iodine in off-gas streams from nuclear fuel reprocessing plants. The objectives of the FY 2011 deep bed iodine sorbent testing are: (1) Evaluate sorbents for iodine capture under various conditions of gas compositions and operating temperature (determine sorption efficiencies, capacities, and mass transfer zone depths); and (2) Generate data for dynamic iodine sorption modeling. Three tests performed this fiscal year on silver zeolite light phase (AgZ-LP) sorbent are reported here. Additional tests are still in progress and can be reported in a revision of this report or a future report. Testing was somewhat delayed and limited this year due to initial activities to address some questions of prior testing, and due to a period of maintenance for the on-line GC. Each test consisted of (a) flowing a synthetic blend of gases designed to be similar to an aqueous dissolver off-gas stream over the sorbent contained in three separate bed segments in series, (b) measuring each bed inlet and outlet gas concentrations of iodine and methyl iodide (the two surrogates of iodine gas species considered most representative of iodine species expected in dissolver off-gas), (c) operating for a long enough time to achieve breakthrough of the iodine species from at least one (preferably the first two) bed segments, and (d) post-test purging with pure N2 to drive loosely or physisorbed iodine species off of the sorbent. Post-test calculations determine the control efficiencies for each bed, iodine loadings on the sorbent, and mass transfer zone depths. Portions of the iodine-laden sorbent from the first bed of two of the tests have been shipped to SNL for waste form studies. Over the past three years, we have explored a full range of inlet iodine and methyl iodide concentrations ranging from {approx}100 ppb to {approx}100 ppm levels, and shown adequate control efficiencies within a bed depth as shallow as 2 inches for lower concentrations and 4 inches for higher concentrations, for the AgZ-type sorbents. We are now performing a limited number of tests in the NC-77 sorbent from SNL. Then we plan to continue to (a) fill in data gaps needed for isotherms and dynamic sorbent modeling, and (b) test the performance of additional sorbents under development.

  9. Characteristics of mercury desorption from sorbents at elevated temperatures

    SciTech Connect (OSTI)

    Ho, T.C.; Yang, P.; Kuo, T.H.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering

    1998-12-31T23:59:59.000Z

    This study investigated the dynamic desorption characteristics of mercury during the thermal treatment of mercury-loaded sorbents at elevated temperatures under fixed-bed operations. Experiments were carried out in a 25.4 mm ID quartz bed enclosed in an electric furnace. Elemental mercury and mercuric chloride were tested with activated carbon and bauxite. The experimental results indicated that mercury desorption from sorbents was strongly affected by the desorption temperature and the mercury-sorbent pair. Elemental mercury was observed to desorb faster than mercuric chloride and activated carbon appeared to have higher desorption limits than bauxite at low temperatures. A kinetic model considering the mechanisms of surface equilibrium, pore diffusion and external mass transfer was proposed to simulate the observed desorption profiles. The model was found to describe reasonably well the experimental results.

  10. An investigation of sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Haddad, G.J.; Hargis, R.A. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technology Center

    1998-12-31T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from a carrier gas. An on-line atomic fluorescence spectrophotometer, used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  11. Direct sulfur recovery during sorbent regeneration. Final report

    SciTech Connect (OSTI)

    Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1993-08-01T23:59:59.000Z

    The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

  12. Kinetics of the reaction of iron blast furnace slag/hydrated lime sorbents with SO{sub 2} at low temperatures: effects of the presence of CO{sub 2}, O{sub 2}, and NOx

    SciTech Connect (OSTI)

    Liu, C.F.; Shih, S.M. [Industrial Technological Research Institute, Hsinchu (Taiwan)

    2009-09-15T23:59:59.000Z

    The effects of the presence of CO{sub 2}, O{sub 2}, and NOx in the flue gas on the kinetics of the sulfation of blast furnace slag/hydrated lime sorbents at low temperatures were studied using a differential fixed-bed reactor. When O{sub 2} and NOx were not present simultaneously, the reaction kinetics was about the same as that under the gas mixtures containing SO{sub 2}, H{sub 2}O, and N{sub 2} only, being affected mainly by the relative humidity. The sulfation of sorbents can be described by the surface coverage model and the model equations derived for the latter case. When both O{sub 2} and NOx, were present, the sulfation of sorbents was greatly enhanced, forming a great amount of sulfate in addition to sulfite. The surface coverage model is still valid in this case, but the model equations obtained show a more marked effect of relative humidity and negligible effects of SO{sub 2} concentration and temperature on the reaction. The effect of sorbent composition on the reaction kinetics was entirely represented by the effects of the initial specific surface area (S{sub g0}) and the Ca molar content (M{sup -1}) of sorbent. The initial conversion rate of sorbent increased linearly with increasing S{sub g0}, and the ultimate conversion increased linearly with increasing S{sub g0}M{sup -1}. The model equations obtained in this work are applicable to describe the kinetics of the sulfation of the sorbents in the low-temperature dry and semidry fine gas desulfurization processes either with an upstream NOx, removal unit or without.111

  13. Sorbent-Based Gas Phase Air Cleaning for VOCs in CommercialBuildings

    SciTech Connect (OSTI)

    Fisk, William J.

    2006-05-01T23:59:59.000Z

    This paper provides a review of current knowledge about the suitability of sorbent-based air cleaning for removing volatile organic compounds (VOCs) from the air in commercial buildings as needed to enable reductions in ventilation rates and associated energy savings. The fundamental principles of sorbent air cleaning are introduced, criteria are suggested for sorbent systems that can counteract indoor VOC concentration increases from reduced ventilation, major findings from research on sorbent performance for this application are summarized, novel sorbent technologies are described, and related priority research needs are identified. Major conclusions include: sorbent systems can remove a broad range of VOCs with moderate to high efficiency, sorbent technologies perform effectively when challenged with VOCs at the low concentrations present indoors, and there is a large uncertainty about the lifetime and associated costs of sorbent air cleaning systems when used in commercial buildings for indoor VOC control. Suggested priority research includes: experiments to determine sorbent system VOC removal efficiencies and lifetimes considering the broad range and low concentration of VOCs indoors; evaluations of in-situ regeneration of sorbents; and an updated analysis of the cost of sorbent air cleaning relative to the cost of ventilation.

  14. Solid sorbents for removal of carbon dioxide from gas streams at low temperatures

    DOE Patents [OSTI]

    Sirwardane, Ranjani V. (Morgantown, WV)

    2005-06-21T23:59:59.000Z

    New low-cost CO.sub.2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and/or an ether so that the amine and/or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and/or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and/or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO.sub.2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35.degree. C.

  15. Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures

    SciTech Connect (OSTI)

    Sirwardane, Ranjani V.

    2005-06-21T23:59:59.000Z

    New low-cost CO2 sorbents are provided that can be used in large-scale gas-solid processes. A new method is provided for making these sorbents that involves treating substrates with an amine and/or an ether so that the amine and/or ether comprise at least 50 wt. percent of the sorbent. The sorbent acts by capturing compounds contained in gaseous fluids via chemisorption and/or physisorption between the unit layers of the substrate's lattice where the polar amine liquids and solids and/or polar ether liquids and solids are located. The method eliminates the need for high surface area supports and polymeric materials for the preparation of CO2 capture systems, and provides sorbents with absorption capabilities that are independent of the sorbents' surface areas. The sorbents can be regenerated by heating at temperatures in excess of 35 degrees C.

  16. Surfactant-Templated Mesoporous Silicate Materials as Sorbents for

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    Surfactant-Templated Mesoporous Silicate Materials as Sorbents for Organic Pollutants in Water H O hexadecyltrimethylammonium bromide(HDTMA)andtetramethyl-orthosilicate(TMOS)orNa- silicate. Products with (as of quartz and amorphous silica. Si dissolution rates for as-synthesized (using Na-silicate) products at pH 7

  17. Novel sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    1999-07-01T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons, as well as novel sorbents, were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  18. Novel sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, E.J.; Pennline, H.W.; Hargis, R.A.

    2000-04-01T23:59:59.000Z

    A laboratory-scale packed-bed reactor system is used to screen sorbents for their capability to remove elemental mercury from various carrier gases. When the carrier gas is argon, an on-line atomic fluorescence spectrophotometer (AFS), used in a continuous mode, monitors the elemental mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the inlet and outlet streams of the packed-bed reactor. The mercury concentration in the reactor inlet gas and the reactor temperature are held constant during a test. For more complex carrier gases, the capacity is determined off-line by analyzing the spent sorbent with either a cold vapor atomic absorption spectrophotometer (CVAAS) or an inductively coupled argon plasma atomic emission spectrophotometer (ICP-AES). The capacities and breakthrough times of several commercially available activated carbons as well as novel sorbents were determined as a function of various parameters. The mechanisms of mercury removal by the sorbents are suggested by combining the results of the packed-bed testing with various analytical results.

  19. Inorganic ion sorbents and methods for using the same

    DOE Patents [OSTI]

    Teter, David M. (Edgewood, NM); Brady, Patrick V. (Albuquerque, NM); Krumhansl, James L. (Albuquerque, NM)

    2006-07-11T23:59:59.000Z

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  20. Drying Foods at Home Safely Drying Herbs

    E-Print Network [OSTI]

    jars, freezer bags, and airtight plastic containers. Like other foods dried at home, dried herbs in an airtight container and store in a cool, dry, and dark place. Recommended containers include glass canning

  1. Dry effluent

    SciTech Connect (OSTI)

    Brady, J.D. (Anderson, 2000 Inc., Peachtree City, GA (US))

    1988-01-01T23:59:59.000Z

    The available choices of pollution control systems depend on what is being burned and how stringent the regulations are. The common systems are gas cooling by a waste heat boiler or an air-air heat exchanger followed by fabric filtration or electrostatic precipitation for particulate removal; alkaline spray absorbers followed by fabric filters (dry scrubbers) for particulate and acid gas removal; wet scrubbers for simultaneous particulate and acid gas removal, and; the newest - spray evaporation, followed by wet scrubbing for particulate and acid gas removal. Each has advantages and each has disadvantages. This paper discusses the advantages and disadvantages of the spray evaporator and wet scrubber combination.

  2. CAN SORBENT-BASED GAS PHASE AIR CLEANING FOR VOCS SUBSTITUTE FOR VENTILATION IN COMMERCIAL BUILDINGS?

    SciTech Connect (OSTI)

    Fisk, William; Fisk, William J.

    2007-08-01T23:59:59.000Z

    This paper reviews current knowledge about the suitability of sorbent-based air cleaning for removing volatile organic compounds (VOCs) from the air in commercial buildings, as needed to enable reductions in ventilation rates and associated energy savings. The principles of sorbent air cleaning are introduced, criteria are suggested for sorbent systems that can counteract indoor VOC concentration increases from reduced ventilation, major findings from research on sorbent performance for this application are summarized, and related priority research needs are identified. Major conclusions include: sorbent systems can remove a broad range of VOCs with moderate to high efficiency, sorbent technologies perform effectively when challenged with VOCs at the low concentrations present indoors, and there is a large uncertainty about the lifetime and associated costs of sorbent air cleaning systems when used in commercial buildings for indoor VOC control. Suggested priority research includes: experiments to determine sorbent system VOC removal efficiencies and lifetimes considering the broad range and low concentration of VOCs indoors; evaluations of in-situ regeneration of sorbents; and an updated analysis of the cost of sorbent air cleaning relative to the cost of ventilation.

  3. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 23, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-15T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x} and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. Specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. In phase AIII at Hennepin - Testing, Data Collection, Reporting and Disposition - Gas Reburning runs were made that indicate as high as 77% reduction in NO{sub x} emission using about 18% gas. Gas Reburning - Sorbent Injection test results indicated as high as 62% reduction in S0{sub 2}. A year of long term testing was completed in October, 1992.

  4. Subject:Announcing New DP & PIR Tool Date:Tue, 03 May 2011 10:29:54 -0500

    E-Print Network [OSTI]

    Balser, Teri C.

    Subject:Announcing New DP & PIR Tool Date:Tue, 03 May 2011 10:29:54 -0500 From:Ramer, Hua the payment requests for direct payment (DP) and payment to individuals (PIR) by automatically filling in the account codes, creating correct forms (DP or PIR form), required tax calculations and the instructions

  5. Evaluation of Dry Sorbent Injection Technology for Pre-Combustion CO{sub 2}

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist. Category UC-l 1, 13Evacuation EmergencyCloudSat, ARM,Cloud

  6. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Wang, K.S.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1997-07-01T23:59:59.000Z

    This study investigated the potential of employing suitable sorbents to capture toxic trace metallic substances during fluidized bed coal combustion. Metal capture experiments were carried out in a 25.4 mm (1 inch) quartz fluidized bed combustor enclosed in an electric furnace. The metals involved were cadmium, lead, chromium, arsenic and selenium, and the sorbents tested included bauxite, zeolite and lime. In addition to the experimental investigations, potential metal-sorbent reactions were also identified through chemical equilibrium calculations based on the minimization of system free energy. The observed experimental results indicated that metal capture by sorbents can be as high as 88% depending on the metal species and sorbent involved. Results from thermodynamic equilibrium simulations suggested the formation of metal-sorbent compounds such as Pb{sub 2}SiO{sub 4}(s), CdAl{sub 2}O{sub 4}(s) and CdSiO{sub 3}(s) under the combustion conditions.

  7. Amine enriched solid sorbents for carbon dioxide capture

    DOE Patents [OSTI]

    Gray, McMahan L. (Pittsburgh, PA); Soong, Yee (Monroeville, PA); Champagne, Kenneth J. (Fredericktown, PA)

    2003-04-15T23:59:59.000Z

    A new method for making low-cost CO.sub.2 sorbents that can be used in large-scale gas-solid processes. The new method entails treating a solid substrate with acid or base and simultaneous or subsequent treatment with a substituted amine salt. The method eliminates the need for organic solvents and polymeric materials for the preparation of CO.sub.2 capture systems.

  8. New ZnO-Based Regenerable Sulfur Sorbents for Fluid-Bed/Transport Reactor Applications

    SciTech Connect (OSTI)

    Slimane, R.B.; Lau, F.S.; Abbasian, J.; Ho, K.H.

    2002-09-19T23:59:59.000Z

    The overall objective of the ongoing sorbent development work at GTI is the advancement to the demonstration stage of a promising ZnO-TiO2 sulfur sorbent that has been developed under DCCA/ICCI and DOE/NETL sponsorship. This regenerable sorbent has been shown to possess an exceptional combination of excellent chemical reactivity, high effective capacity for sulfur absorption, high resistance to attrition, and regenerability at temperatures lower than required by typical zinc titanates.

  9. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report no. 8-A, June 1--August 31, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-09-27T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  10. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report no. 6, September 1, 1988--November 30, 1988

    SciTech Connect (OSTI)

    Not Available

    1988-12-22T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace, at the superheater exit or into the ducting following the air heater. The sorbents trap SO{sub x} as solid sulfates and sulfites, which are collected in the particulate control device.

  11. EA-1184: Transfer of the DP Road Tract to the County of Los Alamos, New Mexico

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to transfer ownership of the undeveloped DP Road Property from the U.S. Department of Energy to Los Alamos County, New Mexico.

  12. Fixed bed testing of durable, steam resistant zinc oxide containing sorbents

    SciTech Connect (OSTI)

    Siriwardane, R.V.; Grimm, U.; Poston, J. [USDOE Morgantown Energy Technology Center, WV (United States); Monaco, S.J. [EG& G dTechnical Services of West Virginia, Inc., Morgantown, WV (United States)

    1994-12-31T23:59:59.000Z

    The US Department of Energy is currently developing Integrated Gasification combined Cycle (IGCC) systems for electrical power generation. It has been predicted that IGCC plants with hot gas cleanup will be superior to conventional pulverized coal-fired power plants in overall plant efficiency and environmental performance. Development of a suitable regenerable sorbent is a major barrier issue in the hot gas cleanup program for IGCC systems. This has been a challenging problem during the last 20 years, since many of the sorbents developed in the program could not retain their reactivity and physical integrity during repeated cycles of sulfidation and regeneration reactions. Two promising sorbents and (METC6), which were capable of sustaining their reactivity and physical integrity during repeated sulfidation/regeneration cycles, have been developed at the Morgantown Energy Technology Center (METC) during the past year. These sorbents were tested (sulfided) both in low-pressure (260 kPa/37.7 psia) and high-pressure (1034 kPa/150 psia) fixed-bed reactors at 538{degrees}C (1000{degrees}F) with simulated KRW coal gas. High-pressure testing was continued for 20 cycles with steam regeneration. There were no appreciable changes in sulfidation capacity of the sorbents during the 20-cycle testing. The crush strength of the sorbent actually improved after 20 cycles and there were no indications of spalling or any other physical deterioration of the sorbents. In testing to date, these sorbents exhibit better overall sulfur capture performance than the conventional sorbents.

  13. Sorbents for mercury capture from fuel gas with application to gasification systems

    SciTech Connect (OSTI)

    Granite, E.J.; Myers, C.R.; King, W.P.; Stanko, D.C.; Pennline, H.W. [US DOE, Pittsburgh, PA (United States)

    2006-06-21T23:59:59.000Z

    In regard to gasification for power generation, the removal of mercury by sorbents at elevated temperatures preserves the higher thermal efficiency of the integrated gasification combined cycle system. Unfortunately, most sorbents display poor capacity for elemental mercury at elevated temperatures. Previous experience with sorbents in flue gas has allowed for judicious selection of potential high-temperature candidate sorbents. The capacities of many sorbents for elemental mercury from nitrogen, as well as from four different simulated fuel gases at temperatures of 204-371{sup o}C, have been determined. The simulated fuel gas compositions contain varying concentrations of carbon monoxide, hydrogen, carbon dioxide, moisture, and hydrogen sulfide. Promising high-temperature sorbent candidates have been identified. Palladium sorbents seem to be the most promising for high-temperature capture of mercury and other trace elements from fuel gases. A collaborative research and development agreement has been initiated between the Department of Energy's National Energy Technology Laboratory (NETL) and Johnson Matthey for optimization of the sorbents for trace element capture from high-temperature fuel gas. Future directions for mercury sorbent development for fuel gas application will be discussed.

  14. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power Improving Desulfurization to Enable Fuel Cell Utilization of Digester Gases This project will develop a new,...

  15. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOE Patents [OSTI]

    Gangwal, S.; Jothimurugesan, K.

    1999-07-27T23:59:59.000Z

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

  16. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power- Fact Sheet, 2011

    Broader source: Energy.gov [DOE]

    Factsheet describing project objective to develop a new, high-capacity, expendable sorbent to remove sulfur species from anaerobic digester gas

  17. Post-Combustion and Pre-Combustion CO2 Capture Solid Sorbents

    SciTech Connect (OSTI)

    Siriwardane, R.V.; Stevens, R.W.; Robinson, Clark

    2007-11-01T23:59:59.000Z

    Combustion of fossil fuels is one of the major sources of the greenhouse gas CO2. Pressure swing adsorption/sorption (PSA/PSS) and temperature swing adsorption/sorption (TSA/TSS) are some of the potential techniques that could be utilized for removal of CO2 from fuel gas streams. It is very important to develop sorbents to remove CO2 from fuel gas streams that are applicable for a wide range of temperatures. NETL researchers have developed novel CO2 capture sorbents for low, moderate, and high temperature applications. A novel liquid impregnated solid sorbent was developed for CO2 removal in the temperature range of ambient to 60 °C. The sorbent is regenerable at 60 – 80 °C. The sorbent formulations were prepared to be suitable for various reactor configurations (i.e., fixed and fluidized bed). Minimum fluidization gas velocities were also determined. Multi-cycle tests conducted in an atmospheric bench scale reactor with simulated flue gas indicated that the sorbent retains its CO2 sorption capacity with a CO2 removal efficiency of approximately 99% and was unaffected by presence of water vapor. The sorbent was subsequently commercially prepared by Süd Chemie to determine the viability of the sorbent for mass production. Subsequent testing showed that the commercially-synthesized sorbent possesses the same properties as the lab-synthesized equivalent. An innovative solid sorbent containing mixture of alkali earth and alkali compounds was developed for CO2 removal at 200 – 315°C from high pressure gas streams suitable for IGCC systems. The sorbent showed very high capacity for CO2 removal from a gas streams containing 28% CO2 at 200 °C and at 20 atm during a lab scale reactor test. This sorbent can be regenerated at 20 atm and at 375 °C utilizing a gas stream containing steam. High pressure enhanced the CO2 sorption process. Bench scale testing showed consistent capacities and regenerability. A unique high temperature solid sorbent was developed for CO2 capture at temperatures of 500 – 700°C. Bench scale testing of the sorbent yielded very high CO2 capture capacity from a gas stream containing 10% CO2, 30% H2, 15% H2O, and 25% He. Regeneration of the sorbent is possible at 800 – 900 °C.

  18. Factors in reactor design for carbon dioxide capture with solid, regenerable sorbents

    SciTech Connect (OSTI)

    Hoffman, J.S.; Richards, G.A.; Pennline, H.W.; Fischer, Daniel (Mid-Atlantic Technology Research & Innovation Center, South Charleston, WV); Keller, George (Mid-Atlantic Technology Research & Innovation Center, South Charleston, WV)

    2008-06-01T23:59:59.000Z

    Fossil-fuel burning power plants, which produce a substantial amount of electric power within the United States, are point sources that can emit significant quantities of carbon dioxide (CO2). In a carbon sequestration scenario, the CO2 must first be captured from the point source, or flue gas, and then be permanently stored. Since the capture/separation step dominates the cost of sequestration, various capture/separation technologies are being investigated, and regenerable, solid sorbents are the basis for one promising technique for capturing CO2 from flue gas. The solid sorbent must be able to absorb the CO2 in the first step and then be regenerated by releasing the CO2 in the second step. Due to the low operating pressure of a conventional pulverized coal-fired combustor and its subsequent low partial pressure of CO2, it is envisioned that temperature swing absorption is applicable to the sorbent capture technology. Various CO2 capture sorbents are being examined in this research area, for example physical adsorbents as well as chemical absorbents. However, with respect to process development, various reactor configurations are presently being considered. The reactor designs range from stationary beds of sorbent to those systems where the sorbent is transported between the absorber and regenerator. Emphasis is placed on design implications of employing a regenerable solid sorbent system. Key sorbent parameters required for the sorbents have been identified, including the heat of adsorption, heat capacity of the solid, delta CO2 loading between the absorption and regeneration steps, and any role co-sorption of competitive gases, such as moisture, may play. Other sorbent properties, such as the effect of acid gases within the flue gas or the attrition of the sorbent, must be considered in the reactor design. These factors all impact the reactor design for a particular type of sorbent. For a generic sorbent, reactor designs have been formulated, including a stationary, isothermal reactor, a fluidized bed, and a moving bed. Through calculations, benefits and disadvantages of the designs have been outlined. The implication of the sorbent properties (and thus desired experimental information) on sorbent reactor design are described, and recommendations for operation of these types of capture systems are discussed.

  19. Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams

    SciTech Connect (OSTI)

    Siriwardane, Ranjan

    1999-09-30T23:59:59.000Z

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  20. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01T23:59:59.000Z

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  1. Mercury Control with Calcium-Based Sorbents and Oxidizing Agents

    SciTech Connect (OSTI)

    Thomas K. Gale

    2005-07-01T23:59:59.000Z

    This Final Report contains the test descriptions, results, analysis, correlations, theoretical descriptions, and model derivations produced from many different investigations performed on a project funded by the U.S. Department of Energy, to investigate calcium-based sorbents and injection of oxidizing agents for the removal of mercury. Among the technologies were (a) calcium-based sorbents in general, (b) oxidant-additive sorbents developed originally at the EPA, and (c) optimized calcium/carbon synergism for mercury-removal enhancement. In addition, (d) sodium-tetrasulfide injection was found to effectively capture both forms of mercury across baghouses and ESPs, and has since been demonstrated at a slipstream treating PRB coal. It has been shown that sodium-tetrasulfide had little impact on the foam index of PRB flyash, which may indicate that sodium-tetrasulfide injection could be used at power plants without affecting flyash sales. Another technology, (e) coal blending, was shown to be an effective means of increasing mercury removal, by optimizing the concentration of calcium and carbon in the flyash. In addition to the investigation and validation of multiple mercury-control technologies (a through e above), important fundamental mechanism governing mercury kinetics in flue gas were elucidated. For example, it was shown, for the range of chlorine and unburned-carbon (UBC) concentrations in coal-fired utilities, that chlorine has much less effect on mercury oxidation and removal than UBC in the flyash. Unburned carbon enhances mercury oxidation in the flue gas by reacting with HCl to form chlorinated-carbon sites, which then react with elemental mercury to form mercuric chloride, which subsequently desorbs back into the flue gas. Calcium was found to enhance mercury removal by stabilizing the oxidized mercury formed on carbon surfaces. Finally, a model was developed to describe these mercury adsorption, desorption, oxidation, and removal mechanisms, including the synergistic enhancement of mercury removal by calcium.

  2. Iodine Sorbent Performance in FY 2012 Deep Bed Tests

    SciTech Connect (OSTI)

    Nick Soelberg; Tony Watson

    2012-08-01T23:59:59.000Z

    Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I-129, due to its radioactivity, high potential mobility in the environment, and high longevity (half life of 15.7 million years), can require control efficiencies of up to 1,000x or higher to meet regulatory emission limits. Iodine capture is an important aspect of the Separations and Waste Forms Campaign Off-gas Sigma Team (Jubin 2011, Pantano 2011). Deep-bed iodine sorption tests for both silver-functionalized Aerogel and silver zeolite sorbents were performed during Fiscal Year 2012. These tests showed that: • Decontamination factors were achieved that exceed reasonably conservative estimates for DFs needed for used fuel reprocessing facilities in the U.S. to meet regulatory requirements for I-129 capture. • Silver utilizations approached or exceeded 100% for high inlet gas iodine concentrations, but test durations were not long enough to approach 100% silver utilization for lower iodine concentrations. • The depth of the mass transfer zone was determined for both low iodine concentrations (under 10 ppmv) and for higher iodine concentrations (between 10-50 ppmv); the depth increases over time as iodine is sorbed. • These sorbents capture iodine by chemisorption, where the sorbed iodine reacts with the silver to form very non-volatile AgI. Any sorbed iodine that is physisorbed but not chemically reacted with silver to form AgI might not be tightly held by the sorbent. The portion of sorbed iodine that tends to desorb because it is not chemisorbed (reacted to form AgI) is small, under 1%, for the AgZ tests, and even smaller, under 0.01%, for the silver-functionalized Aerogel.

  3. Metal sorbents for high temperature mercury capture from fuel gas

    SciTech Connect (OSTI)

    Poulston, S. (Johnson Matthey Technology Centre, Reading, UK); Granite, E.J.; Pennline, H.W.; Myers, C.R.; Stanko, D.P.; Hamilton, H. (Johnson Matthey Technology Centre, Reading, UK); Rowsell, L. (Johnson Matthey Technology Centre, Reading, UK); Smith, A.W.J. (Johnson Matthey Technology Centre, Reading, UK); Ilkenhans, T. (Johnson Matthey Technology Centre, Reading, UK); Chu, W. (Johnson Matthey, Malvern, PA)

    2007-09-01T23:59:59.000Z

    We have determined the Hg removal capacities of Pt and Pd supported on alumina at a range of different metal loadings from 2 to 9 wt% using Hg vapour in a simulated fuel gas feed. In the temperature range studied (204–388 °C) Pd proved far superior to Pt for Hg removal. The Hg removal capacity for both Pt and Pd increased with metal loading, though decreased with sorbent temperature. A shift in the 2{theta} position of the Pd XRD diffraction peak from 82.1 to 79.5 after Hg adsorption at 204 °C was consistent with the formation of a solid solution of Hg in Pd.

  4. novel-carbon-sorbents | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, ,Development of Novel Carbon Sorbents for CO2 Capture

  5. Approved Sorbents, Stabilizers, and Void Fillers - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumni AlumniFederal Facility AgreementSorbents, Stabilizers, and

  6. Hot gas desulfurization with sorbents containing oxides of zinc, iron, vanadium and copper

    SciTech Connect (OSTI)

    Akyurtlu, A.; Akyurtlu, J.F.

    1992-01-01T23:59:59.000Z

    The main objective of this research is to evaluate the desulfurization performance of novel sorbents consisting of different combinations of zinc, iron, vanadium and copper oxides; and to develop a sorbent which can reduce H{sub 2}S levels to less than 1 ppmv, which can stabilize zinc, making operations above 650{degrees}C possible, and which can produce economically recoverable amounts of elemental sulfur during regeneration. This objective will be accomplished by evaluating the sorbent performance using fixed-bed and TGA experiments supported by sorbent characterization at various reaction extents. In the seventh quarter, the screening of the promoted sorbents in the packed bed reactor was continued. The results of this work were presented at the 1992 University Coal Research Contractors, Review Conference at Pittsburgh, PA.

  7. Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV); Rockey, John M. (Westover, WV)

    1994-01-01T23:59:59.000Z

    The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.

  8. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01T23:59:59.000Z

    This document summarizes progress on the Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2000 through September 30, 2000. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid will also be determined, as will the removal of arsenic, a known poison for NOX selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), First Energy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the second reporting period for the subject Cooperative Agreement. During this period, the first of four short-term sorbent injection tests were conducted at the First Energy Bruce Mansfield Plant. This test determined the effectiveness of dolomite injection through out-of-service burners as a means of controlling sulfuric acid emissions from this unit. The tests showed that dolomite injection could achieve up to 95% sulfuric acid removal. Balance of plant impacts on furnace slagging and fouling, air heater fouling, ash loss-on-ignition, and the flue gas desulfurization system were also determined. These results are presented and discussed in this report.

  9. Methods and sorbents for utilizing a hot-side electrostatic precipitator for removal of mercury from combustion gases

    DOE Patents [OSTI]

    Nelson, Sidney (Hudson, OH)

    2011-02-15T23:59:59.000Z

    Methods are provided for reducing emission of mercury from a gas stream by treating the gas with carbonaceous mercury sorbent particles to reduce the mercury content of the gas; collecting the carbonaceous mercury sorbent particles on collection plates of a hot-side ESP; periodically rapping the collection plates to release a substantial portion of the collected carbonaceous mercury sorbent particles into hoppers; and periodically emptying the hoppers, wherein such rapping and emptying are done at rates such that less than 70% of mercury adsorbed onto the mercury sorbent desorbs from the collected mercury sorbent into the gas stream.

  10. Performance of copper chloride-impregnated sorbents on mercury vapor control in an entrained-flow reactor system

    SciTech Connect (OSTI)

    Sang-Sup Lee; Joo-Youp Lee; Tim C. Keener [University of Cincinnati, Cincinnati, OH (United States). Department of Civil and Environmental Engineering

    2008-11-15T23:59:59.000Z

    An entrained-flow system has been designed and constructed to simulate in-flight mercury (Hg) capture by sorbent injection in ducts of coal-fired utility plants. The test conditions of 1.2-sec residence time, 140{degree}C gas temperature, 6.7 m/sec (22 ft/sec) gas velocity, and 0-0.24 g/m{sup 3} (0-15 lbs of sorbent per 1 million actual cubic feet of flue gas sorbent injection rates were chosen to simulate conditions in the ducts. Four kinds of sorbents were used in this study. Darco Hg-LH (lignite-based) served as a benchmark sorbent with which Hg control capability of other sorbents could be compared. Also, Darco-FGD (lignite-based) was used as a representative raw activated carbon sorbent. Two different copper chloride-impregnated sorbents were developed in the laboratory and tested in the entrained-flow system to examine the possibility of using these sorbents at coal-fired power plants. The test results showed that one of the copper chloride sorbents has remarkable elemental mercury (Hg{sup 0}) oxidation capability, and the other sorbent demonstrated a better performance in Hg removal than Darco Hg-LH. 13 refs., 4 figs., 3 tabs.

  11. Development of Highly Durable and Reactive Regenerable Magnesium-Based Sorbents for CO2 Separation in Coal Gasification Process

    SciTech Connect (OSTI)

    Javad Abbasian; Armin Hassanzadeh Khayyat; Rachid B. Slimane

    2005-06-01T23:59:59.000Z

    The specific objective of this project was to develop physically durable and chemically regenerable MgO-based sorbents that can remove carbon dioxide from raw coal gas at operating condition prevailing in IGCC processes. A total of sixty two (62) different sorbents were prepared in this project. The sorbents were prepared either by various sol-gel techniques (22 formulations) or modification of dolomite (40 formulations). The sorbents were prepared in the form of pellets and in granular forms. The solgel based sorbents had very high physical strength, relatively high surface area, and very low average pore diameter. The magnesium content of the sorbents was estimated to be 4-6 % w/w. To improve the reactivity of the sorbents toward CO{sub 2}, The sorbents were impregnated with potassium salts. The potassium content of the sorbents was about 5%. The dolomite-based sorbents were prepared by calcination of dolomite at various temperature and calcination environment (CO{sub 2} partial pressure and moisture). Potassium carbonate was added to the half-calcined dolomite through wet impregnation method. The estimated potassium content of the impregnated sorbents was in the range of 1-6% w/w. In general, the modified dolomite sorbents have significantly higher magnesium content, larger pore diameter and lower surface area, resulting in significantly higher reactivity compared to the sol-gel sorbents. The reactivities of a number of sorbents toward CO{sub 2} were determined in a Thermogravimetric Analyzer (TGA) unit. The results indicated that at the low CO{sub 2} partial pressures (i.e., 1 atm), the reactivities of the sorbents toward CO{sub 2} are very low. At elevated pressures (i.e., CO{sub 2} partial pressure of 10 bar) the maximum conversion of MgO obtained with the sol-gel based sorbents was about 5%, which corresponds to a maximum CO{sub 2} absorption capacity of less than 1%. The overall capacity of modified dolomite sorbents were at least one order of magnitude higher than those of the sol-gel based sorbents. The results of the tests conducted with various dolomite-based sorbent indicate that the reactivity of the modified dolomite sorbent increases with increasing potassium concentration, while higher calcination temperature adversely affects the sorbent reactivity. Furthermore, the results indicate that as long as the absorption temperature is well below the equilibrium temperature, the reactivity of the sorbent improves with increasing temperature (350-425 C). As the temperature approaches the equilibrium temperature, because of the significant increase in the rate of reverse (i.e., regeneration) reaction, the rate of CO{sub 2} absorption decreases. The results of cyclic tests show that the reactivity of the sorbent gradually decreases in the cyclic process. To improve long-term durability (i.e., reactivity and capacity) of the sorbent, the sorbent was periodically re-impregnated with potassium additive and calcined. The results indicate that, in general, re-treatment improves the performance of the sorbent, and that, the extent of improvement gradually decreases in the cyclic process. The presence of steam significantly enhances the sorbent reactivity and significantly decreases the rate of decline in sorbent deactivation in the cyclic process.

  12. Capture of toxic metals by vaious sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Hopper, J.R.

    1995-12-31T23:59:59.000Z

    This study investigated the potential of employing suitable sorbents to capture trace metallic substances during fluidized bed coal combustion. The objectives of the study were to demonstrate the capture process, identify effective sorbents, and characterize the capture efficiency. Experiments were carried out in a 25.4 mm (1 ``) quartz fluidized bed coal combustor enclosed in an electric furnace. In an experiment, a coal sample from the DOE Coal Sample Bank or the Illinois Basin Coal Sample Bank was burned in the bed with a sorbent under various combustion conditions and the amount of metal capture by the sorbent was determined. The metals involved in the study were arsenic, cadmium, lead, mercury and selenium, and the sorbents tested included bauxite, zeolite and lime. The combustion conditions examined included bed temperature, particle size, fluidization velocity (percent excess air), and sorbent bed height. In addition to the experimental investigations, potential metal-sorbent reactions were also identified through performing chemical equilibrium analyses based on the minimization of system free energy.

  13. Performance of immobilized tertiary amine solid sorbents for the capture of carbon dioxide

    SciTech Connect (OSTI)

    Gray, M.L.; Champagne, K.J.; Fauth, D.J.; Baltrus, J.P.; Pennline, H.W.

    2008-01-01T23:59:59.000Z

    The capture of carbon dioxide (CO2) from a simulated flue gas stream was achieved by utilizing immobilized tertiary amine solid sorbents. The tertiary amine immobilized in these solid substrates was 1, 8 Diazabicyclo-[5.4.0]-undec-7-ene (DBU) and it has the stoichiometric capability of capturing carbon dioxide at a 1:1 R-NH2:CO2 molar ratio. This is a unique feature compared to other primary and secondary amines which capture CO2 at a 2:1 molar ratio, thus making the immobilized DBU solid sorbents competitive with existing commercially available sorbents and liquid amine-based capture systems. The immobilized DBU solid sorbents prepared in this study exhibit acceptable CO2 capture capacities of 3.0 mol CO2/kg sorbent at 298 K; however, at the critical operational temperature of 338 K, the capacity was reduced to 2.3 mol/kg sorbent. The DBU sorbents did exhibit acceptable stability over the adsorption/desorption temperature range of 298–360 K based on XPS and TGA analyses.

  14. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  15. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  16. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  17. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-04-29T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the previous semi-annual technical progress report (April 1, 2001 through September 30, 2001). During the current reporting period, additional balance of plant impact information was determined for one of the two tests. These additional balance-of-plant results are presented and discussed in this report. There was no other technical progress to report, because all planned testing as part of this project has been completed.

  18. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2001-11-06T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

  19. Development and Evaluation of Nanoscale Sorbents for Mercury Capture from Warm Fuel Gas

    SciTech Connect (OSTI)

    Raja A. Jadhav

    2006-05-31T23:59:59.000Z

    Several different types of nanocrystalline metal oxide sorbents were synthesized and evaluated for capture of mercury (Hg) from coal-gasifier warm fuel gas. Detailed experimental studies were carried out to understand the fundamental mechanism of interaction between mercury and nanocrystalline sorbents over a range of fuel gas conditions. The metal oxide sorbents evaluated in this work included those prepared by GTI's subcontractor NanoScale Materials, Inc. (NanoScale) as well as those prepared in-house. These sorbents were evaluated for mercury capture in GTI's Mercury Sorbent Testing System. Initial experiments were focused on sorbent evaluation for mercury capture in N{sub 2} stream over the temperature range 423-533 K. These exploratory studies demonstrated that NanoActive Cr{sub 2}O{sub 3} along with its supported form was the most active of the sorbent evaluated. The capture of Hg decreased with temperature, which suggested that physical adsorption was the dominant mechanism of Hg capture. Desorption studies on spent sorbents indicated that a major portion of Hg was attached to the sorbent by strong bonds, which suggested that Hg was oxidized by the O atoms of the metal oxides, thus forming a strong Hg-O bond with the oxide. Initial screening studies also indicated that sulfided form of CuO/alumina was the most active for Hg capture, therefore was selected for detailed evaluation in simulated fuel gas (SFG). It was found that such supported CuO sorbents had high Hg-sorption capacity in the presence of H{sub 2}, provided the gas also contained H{sub 2}S. Exposure of supported CuO sorbent to H{sub 2}S results in the formation of CuS, which is an active sorbent for Hg capture. Sulfur atom in CuS forms a bond with Hg that results into its capture. Although thermodynamically CuS is predicted to form unreactive Cu{sub 2}S form when exposed to H{sub 2}, it is hypothesized that Cu atoms in such supported sorbents are in ''dispersed'' form, with two Cu atoms separated by a distance longer than required to form a Cu{sub 2}S molecule. Thus CuS remains in the stable reactive form as long as H{sub 2}S is present in the gas phase. It was also found that the captured Hg on such supported sorbents could be easily released when the spent sorbent is exposed to a H2-containing stream that is free of Hg and H{sub 2}S. Based on this mechanism, a novel regenerative process has been proposed to remove Hg from fuel gas at high temperature. Limited multicyclic studies carried out on the supported Cu sorbents showed their potential to capture Hg from SFG in a regenerative manner. This study has demonstrated that supported nanocrystalline Cu-based sorbents have potential to capture mercury from coal syngas over multiple absorption/regeneration cycles. Further studies are recommended to evaluate their potential to remove arsenic and selenium from coal fuel gas.

  20. a tp ' m n m nt n n ; p - m Dp(a; tp' < p ' D(

    E-Print Network [OSTI]

    p '+' 0 m. 0. n. ; p - m. 0. Dp(a; tp'. ) = qp ' ' 0. < p '. Page 39, line 15: we nd a power series expansion of a = P1. i='. ti pi. Page 39, line 20: D(. 1. 6. ;3 1 +1+3+3 2 +.

  1. EVOLUTIONARY DESIGN OF PROCESS CONTROLLERS DP Searson, MJ Willis and GA Montague

    E-Print Network [OSTI]

    Fernandez, Thomas

    and the parameters of the controller are matched in some way to the parameters and structure of the process modelEVOLUTIONARY DESIGN OF PROCESS CONTROLLERS DP Searson, MJ Willis and GA Montague University framework for `intelligent' controller design due to its inherent matching of structure to utility

  2. Friction Stir Welding of Hydrided Titanium Alloys Mark Taylor, D.P. Field

    E-Print Network [OSTI]

    Collins, Gary S.

    Friction Stir Welding of Hydrided Titanium Alloys Mark Taylor, D.P. Field Multi-Scale Engineering for Undergraduates program under grant number EEC-0754370 During Friction Stir Welding (FSW), a non-consumable tool-state welding process, much frictional heating and force is required of the tool. This steep demand on the tool

  3. Advanced in-duct sorbent injection for SO{sub 2} control. Topical report number 3, Subtask 2.3: Sorbent optimization

    SciTech Connect (OSTI)

    Rosenhoover, W.A.; Maskew, J.T.; Withum, J.A.; Stouffer, M.R.

    1994-11-01T23:59:59.000Z

    The objective of this research project is to develop second-generation duct injection technology as a cost-effective compliance option for the 1990 Clean Air Act Amendments. Specific process performance goals are to achieve 90% SO{sub 2} removal and 60% sorbent utilization efficiency. Research is focused on the Advanced Coolside process, which has shown the potential of achieving these targets. The objective of Subtask 2.3, Sorbent Optimization, was to explore means of improving performance and economics of the Advanced Coolside process through optimizing the sorbent system. Pilot plant tests of commercial and specially prepared hydrated limes showed that the process is relatively insensitive to sorbent source. This can be an important economic advantage, allowing the use of the lowest cost sorbent available at a site. A pilot plant hydration study conducted in cooperation with Dravo Lime Company further indicated the relative insensitivity of process performance to lime source and to lime physical properties. Pilot plant tests indicated that the use of very small amounts of additives in the Advanced Coolside process can improve performance under some circumstances; however, additives are not necessary to exceed process performance targets.

  4. Regenerable immobilized aminosilane sorbents for carbon dioxide capture applications

    DOE Patents [OSTI]

    Gay, McMahan; Choi, Sunho; Jones, Christopher W

    2014-09-16T23:59:59.000Z

    A method for the separation of carbon dioxide from ambient air and flue gases is provided wherein a phase separating moiety with a second moiety are simultaneously coupled and bonded onto an inert substrate to create a mixture which is subsequently contacted with flue gases or ambient air. The phase-separating moiety is an amine whereas the second moiety is an aminosilane, or a Group 4 propoxide such as titanium (IV) propoxide (tetrapropyl orthotitanate, C.sub.12H.sub.28O.sub.4Ti). The second moiety makes the phase-separating moiety insoluble in the pores of the inert substrate. The new sorbents have a high carbon dioxide loading capacity and considerable stability over hundreds of cycles. The synthesis method is readily scalable for commercial and industrial production.

  5. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and...

    Broader source: Energy.gov (indexed) [DOE]

    Energy, will develop a new, high-capacity sorbent to remove sulfur from anaerobic digester gas. This technology will enable the production of a nearly sulfur-free biogas to...

  6. Bench-scale testing of fluidized-bed sorbents -- ZT-4

    SciTech Connect (OSTI)

    Gangwal, S.K.; Gupta, R.P.

    1995-12-01T23:59:59.000Z

    The objectives of this project are to identify and demonstrate methods for enhancing long-term chemical reactivity and attrition resistance of zinc oxide-based mixed metal-oxide sorbents for desulfurization of hot coal-derived gases in a high-temperature, high-pressure (HTHP) fluidized-bed reactor. Specific objectives of this study are the following: {sm_bullet} Investigating various manufacturing methods to produce fluidizable zinc ferrite and zinc titanate sorbents in a particle size range of 50 to 400 {mu}m; Characterizating and screening the formulations for chemical reactivity, attrition resistance, and structural properties; Testing selected formulations in an HTHP bench-scale fluidized-bed reactor to obtain an unbiased ranking of the promising sorbents; Investigating the effect of various process variables, such as temperature, nature of coal gas, gas velocity, and chemical composition of the sorbent, on the performance of the sorbent; Life-cycle testing of the superior zinc ferrite and zinc titanate formulations under HTHP conditions to determine their long-term chemical reactivity and mechanical strength; Addressing various reactor design issues; Generating a database on sorbent properties and performance (e.g., rates of reaction, attrition rate) to be used in the design and scaleup of future commercial hot-gas desulfurization systems; Transferring sorbent manufacturing technology to the private sector; Producing large batches (in tonnage quantities) of the sorbent to demonstrate commercial feasibility of the preparation method; and Coordinate testing of superior formulations in pilot plants with real and/or simulated coal gas.

  7. Sorbent Testing for Solidification of Organic Plutonium/Uranium Extraction Waste - Phase IV

    SciTech Connect (OSTI)

    Bickford, J.L.; Joyce, H.O. [MSE Technology Applications, Inc., P.O. Box 4078, Butte, MT 59701 (United States); Holmes-Burns, H. [Westinghouse Savannah River Company, Building 705-3C, P.O. Box A, Aiken SC 29802 (United States)

    2006-07-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) is evaluating various sorbents to solidify and immobilize hazardous constituents of the organic fraction of plutonium/uranium extraction (PUREX) process waste at the Savannah River Site (SRS).[5] The purpose of the solidification is to provide a cost-effective alternative to incineration of the waste. Incineration at the Consolidated Incinerator Facility (CIF) at SRS is currently identified as the treatment technology for PUREX waste. However, the CIF is not in operation at this time, so SRS is interested in pursuing alternatives to incineration for treatment of this waste. The DOE Western Environmental Technology Office in Butte, MT was designated as the facility for conducting the sorbent testing and evaluation for the organic PUREX waste surrogate. MSE Technology Applications, Inc. tested and evaluated two clay and two polymer sorbents with the capability of solidifying organic PUREX waste. A surrogate organic PUREX waste recipe was utilized, and sorbents were tested and evaluated at bench-scale, 22-liter (5-gallon) scale, and 242-liter (55-gallon) scale. This paper presents experimental results evaluating four sorbent materials including: Imbiber Beads{sup TM} IMB230301-R, Nochar A610 Petrobond{sup TM}, Petroset II{sup TM}, and Petroset II Granular{sup TM}. Previous work at SRS indicated that these products could solidify organic PUREX waste on a bench scale [1]. The sorbents were evaluated using operational criteria and final wasteform properties. Operational criteria included: sorbent capacity; sorption rate; sorbent handling; and mixing requirements. Final wasteform evaluation properties included: ignitability; thermal stability; offgas generation, leachability tests and volumetric expansion. Bench-scale tests, 22-liter (5-gallon) tests, and initial 242-liter (55-gallon) tests are complete. This paper summarizes the results of the bench-scale, 22-liter (5-gallon) scale, and 242-liter (55-gallon) scale tests performed during FY05 with an aqueous/PUREX surrogate. (authors)

  8. Innovative Nano-Layered Solid Sorbents for CO{sub 2} Capture

    SciTech Connect (OSTI)

    Li, Bengyun; Jiang, Bingbing; Fauth, Daniel J; Gray, McMahan L; Pennline, Henry W; Richards, George A

    2011-01-01T23:59:59.000Z

    Nano-layered sorbents for CO{sub 2} capture, for the first time, were developed using layer-by-layer nanoassembly. A CO{sub 2}-adsorbing polymer and a strong polyelectrolyte were alternately immobilized within porous particles. The developed sorbents had fast CO{sub 2} adsorption and desorption properties and their CO{sub 2} capture capacity increased with increasing nano-layers of the CO{sub 2}-adsorbing polymer.

  9. Theoretical Predictions of the thermodynamic Properties of Solid Sorbents Capture CO2 Applications

    SciTech Connect (OSTI)

    Duan, Yuhua; Sorescu, Dan; Luebke David; Pennline, Henry

    2012-05-02T23:59:59.000Z

    We are establishing a theoretical procedure to identify most potential candidates of CO{sub 2} solid sorbents from a large solid material databank to meet the DOE programmatic goal for energy conversion; and to explore the optimal working conditions for the promising CO{sub 2} solid sorbents, especially from room to warm T ranges with optimal energy usage, used for both pre- and post-combustion capture technologies.

  10. Strategic Design and Optimization of Inorganic Sorbents for Cesium, Strontium and Actinides

    SciTech Connect (OSTI)

    Maginn, Edward J.

    2005-07-01T23:59:59.000Z

    The basic science goal in this project is to identify structure/affinity relationships for selected radionuclides and existing sorbents. The research will then apply this knowledge to the design and synthesis of sorbents that will exhibit increased cesium, strontium and actinide removal. The target problem focuses on the treatment of high-level nuclear wastes. The general approach can likewise be applied to non-radioactive separations.

  11. Theoretical Screening of Mixed Solid Sorbents for CO{sub 2} Capture

    SciTech Connect (OSTI)

    Duan, Y [NETL; Sorescu, D C [NETL; Luebke, D [NETL; Li, B Y; Zhang, K; King, D

    2013-05-16T23:59:59.000Z

    We are establishing a theoretical procedure to identify most potential candidates of CO{sub 2} solid sorbents from a large solid material databank to meet the DOE programmatic goal for energy conversion; A further objective is to explore the optimal working conditions for the promised CO{sub 2} solid sorbents, especially from room to warm T ranges with optimal energy usage, used for both pre- and post-combustion capture technologies.

  12. Strategic Design and Optimization of Inorganic Sorbents For Cesium, Strontium and Actinides

    SciTech Connect (OSTI)

    Hobbs, D.; Nyman, M.; Clearfield, A.; Maginn, E.

    2006-06-01T23:59:59.000Z

    The basic science goal in this project identifies structure/affinity relationships for selected radionuclides and existing sorbents. The task will apply this knowledge to the design and synthesis of new sorbents that will exhibit increased affinity for cesium, strontium and actinide separations. The target problem focuses on the treatment of high-level nuclear wastes. The general approach can likewise be applied to nonradioactive separations.

  13. Novel Sorbent-Based Process for High Temperature Trace Metal Removal

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2008-09-30T23:59:59.000Z

    The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

  14. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Srinivasachar, Srivats; Laudal, Daniel; Browers, Bruce

    2014-12-31T23:59:59.000Z

    A novel hybrid solid sorbent technology for CO2 capture and separation from coal combustion-derived flue gas was evaluated. The technology – Capture of CO2 by Hybrid Sorption (CACHYS™) – is a solid sorbent technology based on the following ideas: 1) reduction of energy for sorbent regeneration, 2) utilization of novel process chemistry, 3) contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and 4) low-cost method of heat management. This report provides key information developed during the course of the project that includes sorbent performance, energy for sorbent regeneration, physical properties of the sorbent, the integration of process components, sizing of equipment, and overall capital and operational cost of the integrated CACHYS™ system. Seven sorbent formulations were prepared and evaluated at the lab-scale for energy requirements and CO2 capture performance. Sorbent heat of regeneration ranged from 30-80 kJ/mol CO2 and was found to be dependent on process conditions. Two sorbent formulations (designated HCK-4 & HCK-7) were down-selected for additional fixed-bed testing. Additional testing involved subjecting the sorbents to 100 continuous cycles in the fixed-bed reactor to determine performance as a function of time. The working capacity achieved for HCK-4 sorbent ranged from 5.5-8.0 g CO2/100 g sorbent, while the HCK-7 typically ranged from 8.0-10.0 g CO2/100 g sorbent. Overall, there was no deterioration in capacity with continuous cycling for either sorbent. The CACHYS™ bench-scale testing system designed and fabricated under this award consists of a dual circulating fluidized-bed adsorber and a moving-bed regenerator. The system takes a flue gas slipstream from the University of North Dakota’s coal-fired steam plant. Prior to being sent to the adsorber, the flue gas is scrubbed to remove SO2 and particulate. During parametric testing of the adsorber, CO2 capture achieved using the 2-bed configuration with recirculation in both beds was 65-70% with a high flue gas CO2 loading (~7%) and up to 85% with a low flue gas CO2 loading (~4%). A sorbent regenerator system consisting of a pre-heater, desorber, and cooler is used to heat the CO2-rich sorbent with direct and indirect steam producing a nearly 100% pure stream of CO2. Parametric testing of the regenerator system demonstrated the impact of process conditions on both desorption rate and the heat of regeneration. Clear evidence of the use of specific process conditions that lower the overall energy of desorption was identified. This observation validates measurements made at the laboratory-scale. Several longer-term continuous tests were conducted to evaluate the performance of the sorbent/process as a function of time. Using a 2-bed configuration, sustained capture efficiency of 40-60% with a high flue gas CO2 loading (~8%) and 70-80% with a low flue gas CO2 loading (~4%) were achieved. However, sorbent working capacity was found to be considerably lower than laboratory-scale measurements. The low working capacity is attributed to insufficient sorbent/gas contact time in the adsorber. Sorbent properties that had a significant impact on CO2 capture performance were identified. The results show that controlling these sorbent properties substantially improves CO2 capture performance, with preliminary estimates indicating that relative improvement of ~30% is possible. Testing culminated with an operationally trouble-free test of 15 hours with sustainable performance. Overall, several practical strategies to increase performance of the sorbent and process were identified. The initial technical and economic assessment of the CACHYS™ process estimated the cost of CO2 capture was $36.19/ton with a 48.6% increase in levelized cost of electricity (LCOE) for the 550 MWe net plant. Using additional data gathered over the course of the project, and with revised technical and economic assumptions, the estimated cost of CO2 capture with the CACHYS™ process is $39/ton (only includes the cost of the CO2 capture system

  15. Ultrafine calcium aerosol: Generation and use as a sorbent for sulfur in coal combustion. Volume 1, Experimental work: Final report, August 1, 1988--October 31, 1991

    SciTech Connect (OSTI)

    Alam, M.K.; Nahar, N.U.; Stewart, G.D.; Prudich, M.E. [comps.] [Ohio Coal Research Center, Athens, OH (United States)

    1991-11-01T23:59:59.000Z

    Studies conducted at Ohio University and elsewhere have demonstrated that ultrafine aerosols, which have the highest surface area per unit mass, have enhanced potential to efficiently remove sulfur dioxide form combustion gases. Therefore it is proposed to generate a very fine aerosol calcium-rich sorbent (or similar aerosols) for gas conditioning. The aerosol will be generated by vaporization of the sorbent compound and subsequent homogeneous nucleation. In experimental studies liquids as well as solids will be converted into ultrafine aerosols by using suitable aerosol generator. The aerosol generator could be a simple bubbler or a flame spray jet using powders of calcium ``Compounds. Studies will then be carried out, to determine the dynamics of sulfur dioxide capture by the ultrafine aerosol. The primary objective of this research was to generate fine aerosols and to use them for coal combustion SO{sub 2}/NO{sub x} gas removal purposes. From the background study on the dry scrubbing system, it can be concluded that the most important experimental parameters are addition ratio, reactor temperature, residence time, total inlet flow rate and inlet SO{sub 2} concentration. Addition ratio is the inlet molar ratio of calcium to sulfur. Before any experimentation, it was necessary to decide and investigate the values of each of the parameters. Each of these parameters were investigated individually and the effects on SO{sub 2} removal were determined.

  16. Development of a Catalyst/Sorbent for Methane Reforming

    SciTech Connect (OSTI)

    B.H. Shans; T.D. Wheelock; Justinus Satrio; Karl Albrecht; Tanya Harris Janine Keeley; Ben Silva; Aaron Shell; Molly Lohry; Zachary Beversdorf

    2008-12-31T23:59:59.000Z

    This project led to the further development of a combined catalyst and sorbent for improving the process technology required for converting CH{sub 4} and/or CO into H{sub 2} while simultaneously separating the CO{sub 2} byproduct all in a single step. The new material is in the form of core-in-shell pellets such that each pellet consists of a CaO core surrounded by an alumina-based shell capable of supporting a Ni catalyst. The Ni is capable of catalyzing the reactions of steam with CH{sub 4} or CO to produce H{sub 2} and CO{sub 2}, whereas the CaO is capable of absorbing the CO{sub 2} as it is produced. The absorption of CO{sub 2} eliminates the reaction inhibiting effects of CO{sub 2} and provides a means for recovering the CO{sub 2} in a useful form. The present work showed that the lifecycle performance of the sorbent can be improved either by incorporating a specific amount of MgO in the material or by calcining CaO derived from limestone at 1100 C for an extended period. It also showed how to prepare a strong shell material with a large surface area required for supporting an active Ni catalyst. The method combines graded particles of {alpha}-alumina with noncrystalline alumina having a large specific surface area together with a strength promoting additive followed by controlled calcination. Two different additives produced good results: 3 {micro}m limestone and lanthanum nitrate which were converted to their respective oxides upon calcination. The oxides partially reacted with the alumina to form aluminates which probably accounted for the strength enhancing properties of the additives. The use of lanthanum made it possible to calcine the shell material at a lower temperature, which was less detrimental to the surface area, but still capable of producing a strong shell. Core-in-shell pellets made with the improved shell materials and impregnated with a Ni catalyst were used for steam reforming CH{sub 4} at different temperatures and pressures. Under all conditions tested, the CH{sub 4} conversion was large (>80%) and nearly equal to the predicted thermodynamic equilibrium level as long as CO{sub 2} was being rapidly absorbed. Similar results were obtained with both shell material additives. Limited lifecycle tests of the pellets also produced similar results that were not affected by the choice of additive. However, during each lifecycle test the period during which CO{sub 2} was rapidly absorbed declined from cycle to cycle which directly affected the corresponding period when CH{sub 4} was reformed rapidly. Therefore, the results showed a continuing need for improving the lifecycle performance of the sorbent. Core-in-shell pellets with the improved shell materials were also utilized for conducting the water gas shift reaction in a single step. Three different catalyst formulations were tested. The best results were achieved with a Ni catalyst, which proved capable of catalyzing the reaction whether CO{sub 2} was being absorbed or not. The calcined alumina shell material by itself also proved to be a very good catalyst for the reaction as long as CO{sub 2} was being fully absorbed by the core material. However, neither the alumina nor a third formulation containing Fe{sub 2}O{sub 3} were good catalysts for the reaction when CO{sub 2} was not absorbed by the core material. Furthermore, the Fe{sub 2}O{sub 3}-containing catalyst was not as good as the other two catalysts when CO{sub 2} was being absorbed.

  17. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-10-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the report for the time period April 1, 2002 through September 30, 2002. During the current period, process economic estimates were developed, comparing the costs of the furnace magnesium hydroxide slurry injection process tested as part of this project to a number of other candidate SO{sub 3}/sulfuric acid control technologies for coal-fired power plants. The results of this economic evaluation are included in this progress report.

  18. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-06-01T23:59:59.000Z

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2002 through March 31, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the seventh reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO3 removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the previous report (April 1, 2002 through September 30, 2002). During the current period, there was no technical progress to report, because all planned testing as part of this project has been completed. The project period of performance was extended to allow the conduct of testing of another SO{sub 3} control technology, the sodium bisulfite injection process. However, these additional tests have not yet been conducted.

  19. Development of Novel Sorbents for Uranium Extraction from Seawater

    SciTech Connect (OSTI)

    Lin, Wenbin; Taylor-Pashow, Kathryn

    2014-01-08T23:59:59.000Z

    As the uranium resource in terrestrial ores is limited, it is difficult to ensure a long-term sustainable nuclear energy technology. The oceans contain approximately 4.5 billion tons of uranium, which is one thousand times the amount of uranium in terrestrial ores. Development of technologies to recover the uranium from seawater would greatly improve the uranium resource availability, sustaining the fuel supply for nuclear energy. Several methods have been previously evaluated including solvent extraction, ion exchange, flotation, biomass collection, and adsorption; however, none have been found to be suitable for reasons such as cost effectiveness, long term stability, and selectivity. Recent research has focused on the amidoxime functional group as a promising candidate for uranium sorption. Polymer beads and fibers have been functionalized with amidoxime functional groups, and uranium adsorption capacities as high as 1.5 g U/kg adsorbent have recently been reported with these types of materials. As uranium concentration in seawater is only ~3 ppb, great improvements to uranium collection systems must be made in order to make uranium extraction from seawater economically feasible. This proposed research intends to develop transformative technologies for economic uranium extraction from seawater. The Lin group will design advanced porous supports by taking advantage of recent breakthroughs in nanoscience and nanotechnology and incorporate high densities of well-designed chelators into such nanoporous supports to allow selective and efficient binding of uranyl ions from seawater. Several classes of nanoporous materials, including mesoporous silica nanoparticles (MSNs), mesoporous carbon nanoparticles (MCNs), meta-organic frameworks (MOFs), and covalent-organic frameworks (COFs), will be synthesized. Selective uranium-binding liagnds such as amidoxime will be incorporated into the nanoporous materials to afford a new generation of sorbent materials that will be evaluated for their uranium extraction efficiency. The initial testing of these materials for uranium binding will be carried out in the Lin group, but more detailed sorption studies will be carried out by Dr. Taylor-Pashow of Savannah River National Laboratory in order to obtain quantitative uranyl sorption selectivity and kinetics data for the proposed materials. The proposed nanostructured sorbent materials are expected to have higher binding capacities, enhanced extraction kinetics, optimal stripping efficiency for uranyl ions, and enhanced mechanical and chemical stabilities. This transformative research will significantly impact uranium extraction from seawater as well as benefit DOE’s efforts on environmental remediation by developing new materials and providing knowledge for enriching and sequestering ultralow concentrations of other metals.

  20. Study of the dp-elastic scattering at 2 GeV

    E-Print Network [OSTI]

    Terekhin, A A; Isupov, A Yu; Khrenov, A N; Kurilkin, A K; Kurilkin, P K; Ladygin, V P; Ladygina, N B; Piyadin, S M; Reznikov, S G; Vnukov, I E

    2015-01-01T23:59:59.000Z

    The results on the measurements of dp-elastic scattering cross section at the energy 2 GeV at Internal Target Station at the Nuclotron JINR are reported. The data were obtained for the angular range of 70-107 deg. in the c.m.s. by using CH2 and C targets. The results are compared with the existing data and with the theoretical calculations based on the relativistic multiple scattering theory.

  1. The X-ray Behavior of Two CVs: TT Ari and DP Leo

    E-Print Network [OSTI]

    Craig R. Robinson; France A. Cordova

    1993-11-01T23:59:59.000Z

    We present ROSAT PSPC observations of the nova-like, or intermediate polar, TT Ari and the eclipsing polar DP Leo. Observations of TT Ari were performed as part of a simultaneous multiwavelength campaign. The X-ray spectrum of TT Ari from ROSAT was combined with Ginga observations to suggest the presence of three distinct emission components: an optically thin plasma, a dominating bremsstrahlung continuum and one or more iron emission lines. Simultaneous and later IUE observations show modulation in the absorption component of the P Cygni-like CIV line on the spectroscopic period indicating a complex wind structure. Three eclipses were observed from the DP Leo system with intensity dips, not previously observed, occurring prior to each eclipse. The dips are interpreted as the eclipse of the main emission region by an accretion stream varying in impact position or stream shape with time. The DP Leo spectrum is well fit by either a 25 eV blackbody or a soft power law. No evidence exists for accretion onto the stronger magnetic pole and severe limits were placed upon the flux from any hard bremsstrahlung component. We constrained distances to this system based upon model fits to the data.

  2. Natural-sorbent attrition and elutriation characteristics in fluidized-bed coal combustors

    SciTech Connect (OSTI)

    Wilson, W.I.; Fee, D.C.; Myles, K.M.; Johnson, I.; Fan, L.S.

    1981-01-01T23:59:59.000Z

    Laboratory test methods have been developed to measure the attrition and elutriation characteristics of limestones in an atmospheric-pressure fluidized-bed coal combustor (AFBC) at 850/sup 0/C. The attrition constant and elutriation rate were determined for a group of limestones when the system is assumed to be at steady state; that is, after sorbent breakup due to thermal shock and decrepitation during calcination of the sorbent feed are completed. An attrition model has been developed to analyze the laboratory data to predict sorbent performance in AFBCs. The attrition model assumes that the particle disintegration occurs from the abrasive removal of material from the surface of the particle rather than by particle fracture. The attrition constants of the limestones tested ranged from 1.5 x 10/sup -6/ sec/sup -1/ to 9.2 x 10/sup -8/ sec/sup -1/, and the elutriation rate had a fractional mass loss which ranged from 8.1 x 10/sup -8/ min/sup -1/ to 1.0 x 10/sup -3/ min/sup -1/. The test methods and techniques utilized by the model are undergoing refinement to improve the accuracy of the prediction. The attrition and elutriation of a sorbent in a fluidized-bed combustor affects the sorbent performance in a complex manner. The obvious case is the extreme situation where so much sorbent material is lost from the bed via attrition and elutriation that a constant bed height cannot be maintained. Because this aspect is an important consideration in sorbent selection, standard laboratory test methods have been developed to measure the attrition and elutriation characteristics of limestones in AFBCs.

  3. Development of Improved Sorbents for Radiochemical Separations at the SRS

    SciTech Connect (OSTI)

    HOBBS, DAVID

    2005-01-20T23:59:59.000Z

    High-level nuclear waste produced from fuel reprocessing operations at the Savannah River Site (SRS) requires pretreatment to remove Cs-137, Sr-90 and alpha-emitting radionuclides (i.e., actinides) prior to disposal. Separation processes planned at SRS include caustic side solvent extraction, for Cs-137 removal, and ion exchange/sorption of Sr-90 and alpha-emitting radionuclides with monosodium titanate (MST). The predominant alpha-emitting radionuclides in the highly alkaline waste solutions include plutonium isotopes Pu-238, Pu-239 and Pu-240. This paper describes results from a project funded by the U.S. Department of Energy Office of Cleanup Technology to produce sorbents that exhibit increased removal kinetics and capacity for Sr-90 and alpha-emitting radionuclides versus that of the baseline MST material. Testing indicated that MST samples prepared in the presence of organic-based templating reagents showed limited improvements in performance compared to the baseline MST. We observed significantly improved plutonium and neptunium removal performance with MST samples prepared upon the addition of a proprietary reagent. The modified MST offers the possibility of increased throughput and reduced solids handling in waste processing facilities at the SRS.

  4. Hybrid Heat Pumps Using Selective Water Sorbents (SWS)

    SciTech Connect (OSTI)

    Ally, M. R.

    2006-11-30T23:59:59.000Z

    The development of the ground-coupled and air-coupled Heating Ventilation and Air-Conditioning (HVAC) system is essential in meeting the goals of Zero Energy Houses (ZEH), a viable concept vigorously pursued under DOE sponsorship. ORNL has a large Habitat for Humanity complex in Lenoir City where modem buildings technology is incorporated on a continual basis. This house of the future is planned for lower and middle income families in the 21st century. The work undertaken in this CRADA is an integral part of meeting DOE's objectives in the Building America program. SWS technology is a prime candidate for reducing the footprint, cost and improve the performance of ground-coupled heat pumps. The efficacy of this technique to exchange energy with the ground is a topic of immense interest to DOE, builders and HVAC equipment manufacturers. If successful, the SWS concept will become part of a packaged ZEH kit for affordable and high-end houses. Lennox Industries entered into a CRADA with Oak Ridge National Laboratory in November 2004. Lennox, Inc. agreed to explore ways of using Selective Water Sorbent materials to boost the efficiency of air-coupled heat pumps whereas ORNL concentrated on ground-coupled applications. Lennox supplied ORNL with heat exchangers and heat pump equipment for use at ORNL's Habitat for Humanity site in Lenoir City, Tennessee. Lennox is focused upon air-coupled applications of SWS materials at the Product Development and Research Center in Carrollton, TX.

  5. Process development for production of coal/sorbent agglomerates

    SciTech Connect (OSTI)

    Rapp, D.M.; Lytle, J.M.; Hackley, K.C.; Moran, D.L.; Becvar, S. (Illinois State Geological Survey, Champaign, IL (USA)); Berger, R.L. (Illinois Univ., Urbana, IL (USA)); Griggs, K. (Army Construction Engineering Research Lab., Champaign, IL (USA))

    1991-01-01T23:59:59.000Z

    Current coal mining and processing procedures produce significant quantities of fine coal with limited marketability. The objective of this work is to pelletize these fines with a sulfur capturing sorbent such as calcium hydroxide to produce a fuel which will meet future sulfur dioxide emission levels. To decrease binder costs, carbonation, which is the reaction of calcium hydroxide with carbon dioxide in the presence of moisture to produce calcium carbonate, is being investigated as a method for improving pellet quality. The calcium carbonate formed acts as a cementitious matrix which improves pellet strength. In previous work utilizing IBC-106 from the Illinois Basin Coal Sample Program, carbonation was determined to be effective at significantly improving pellet compressive strength, impact and attrition resistance and weatherability. In combustion tests conducted at 850{degree}C, sulfur capture of 80% was achieved for pellets having 17.5% calcium hydroxide (a Ca/S ration of 2/1). In this years work, a flotation concentrate collected from an operating Illinois preparation plant is being used for testing. Results indicate carbonation significantly increases the compressive strength of pellets formed with 10% calcium hydroxide. 6 refs., 1 fig., 5 tabs.

  6. Process development for production of coal/sorbent agglomerates

    SciTech Connect (OSTI)

    Rapp, D.M.

    1991-01-01T23:59:59.000Z

    The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to proceed. The process has been successfully demonstrated on a pilot-scale as a method of hardening iron ore pellets (Imperato, 1966). Two potential combustion options are being considered for the coal/calcium hydroxide pellets: fluidized bed combustors and industrial stoker boilers.

  7. Process development for production of coal/sorbent agglomerates

    SciTech Connect (OSTI)

    Rapp, D.M.; Lytle, J.M.; Hackley, K.C.; Moran, D.L.; Becvar, S. (Illinois State Geological Survey, Champaign, IL (United States)); Berger, R.L. (Illinois Univ., Urbana, IL (United States)); Griggs, K. (Army Construction Engineering Research Lab., Champaign, IL (United States))

    1991-01-01T23:59:59.000Z

    The objective of this work is to pelletize these fines with a sulfur capturing sorbent such as calcium hydroxide to produce a fuel which will meet future sulfur dioxide emission levels. To decrease binder costs, carbonation, which is the reaction of calcium hydroxide with carbon dioxide in the presence of moisture to produce calcium carbonate, is being investigated as a method for improving pellet quality. The calcium carbonate formed acts as a cementitious matrix which improves pellet strength. Two potential combustion options are being considered -- fluidized bed combustors and industrial stoker boilers. During this quarter a pellet characterization test program was conducted using a fine coal (-28 mesh) concentrate collected from a southern Illinois preparation plant. Results indicate that carbonation produces significant improvements in compressive strength, impact and attrition resistance and weatherability. Also, 20 combustion tests were conducted on pellets formed with 0, 5 and 10% levels of calcium hydroxide (10% calcium hydroxide is a 2.3:1 Ca/S ratio for this sample). Tests were conducted at 850 and 1350 {degrees}C. Chemical analyses of the combustion residues are not yet complete so results will be reported next quarter. 8 refs., 7 tabs.

  8. Dry Process Electrode Fabrication

    Broader source: Energy.gov (indexed) [DOE]

    with good mechanical properties - Loading approaching targets - Process parameter optimization necessary to make thinner films with better density characteristics Images of dry...

  9. Transporting Dry Ice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Requirements for Shipping Dry Ice IATA PI 904 Source: Reg of the Day from ERCweb 2006 Environmental Resource Center | 919-469-1585 | webmaster@ercweb.com http:...

  10. Cooking with Dry Beans

    E-Print Network [OSTI]

    Anding, Jenna

    2008-12-09T23:59:59.000Z

    This fact sheet describes the nutritonal value and safe storage of dry beans, a commodity food. It also offers food preparation ideas....

  11. Sandia National Laboratories: DRI

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DRI ECIS-Princeton Power Systems, Inc.: Demand Response Inverter On March 19, 2013, in DETL, Distribution Grid Integration, Energy, Energy Surety, Facilities, Grid Integration,...

  12. Energy and environmental research emphasizing low-rank coal: Task 5.7, Coal char fuel evaporation canister sorbent

    SciTech Connect (OSTI)

    Aulich, T.R.; Grisanti, A.A.; Knudson, C.L.

    1995-08-01T23:59:59.000Z

    Atomobile evaporative emission canisters contain activated carbon sorbents that trap and store fuel vapors emitted from automobile fuel tanks during periods of hot ambient temperatures and after engine operation. When a vehicle is started, combustion air is pulled through the canister, and adsorbed vapors are removed from the sorbent and routed to the intake manifold for combustion along with fuel from the tank. The two primary requirements of an effective canister sorbent are that (1) it must be a strong enough adsorbent to hold on to the fuel vapors that contact it and (2) it must be a weak enough adsorbent to release the captured vapors in the presence of the airflow required by the engine for fuel combustion. Most currently available commercial canister sorbents are made from wood, which is reacted with phosphoric acid and heat to yield an activated carbon with optimum pore size for gasoline vapor adsorption. The objectives of Task 5.7 were to (1) design and construct a test system for evaluating the performance of different sorbents in trapping and releasing butane, gasoline, and other organic vapors; (2) investigate the use of lignite char as an automobile fuel evaporation canister sorbent; (3) compare the adsorbing and desorbing characteristics of lignite chars with those of several commercial sorbents; and (4) investigate whether the presence of ethanol in fuel vapors affects sorbent performance in any way. Tests with two different sorbents (a wood-derived activated carbon and a lignite char) showed that with both sorbents, ethanol vapor breakthrough took about twice as long as hydrocarbon vapor breakthrough. Possible reasons for this, including an increased sorbent affinity for ethanol vapors, will be investigated. If this effect is real (i.e., reproducible over an extensive series of tests under varying conditions), it may help explain why ethanol vapor concentrations in SHED test evaporative emissions are often lower than would be expected.

  13. Theoretical Screening of Solid Sorbents for CO{sub 2} Capture Applications

    SciTech Connect (OSTI)

    Duan, Y [NETL

    2013-08-07T23:59:59.000Z

    The work reported in this presentation was establishing a theoretical procedure to identify most potential candidates of CO{sub 2} solid sorbents from a large solid material databank; and to explore the optimal working conditions for the promised CO{sub 2} solid sorbents and provide guidelines to the experimentalists. Our methodology can predict thermodynamic properties of solid materials and their CO{sub 2} capture reactions. Single solid may not satisfy the industrial operating conditions as CO{sub 2} sorbent, however, by mixing two or more solids, the new formed solid may satisfy the industrial needs. By exploring series of lithium silicates with different Li{sub 2}O/SiO{sub 2} ratio, we found that with decreasing Li{sub 2}O/SiO{sub 2} ratio the corresponding silicate has a lower turnover temperature and vice versa. Compared to pure MgO, the Na{sub 2}CO{sub 3}, K{sub 2}CO{sub 3} and CaCO{sub 3} promoted MgO sorbent has a higher turnover T. These results provide guidelines to synthesize sorbent materials by mixing different solids with different ratio.

  14. Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

    SciTech Connect (OSTI)

    Hepworth, M.T.; Slimane, R.B.

    1994-11-01T23:59:59.000Z

    The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

  15. Land application uses for dry FGD by-products

    SciTech Connect (OSTI)

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W. (Ohio State Univ., Columbus, OH (United States)); Haefner, R. (Geological Survey, Columbus, OH (United States). Water Resources Div.)

    1993-04-01T23:59:59.000Z

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. Presently FGD by-product materials are treated as solid wastes and must be landfilled. However, landfill sites are becoming more scarce and tipping fees are constantly increasing. It is, therefore, highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. In summary Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD byproduct materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  16. Performance of Amine-Multilayered Solid Sorbents for CO{sub 2} Removal: Effect of Fabrication Variables

    SciTech Connect (OSTI)

    Jiang, Bingbing; Kish, Vincent; Li, Bingyun; Fauth, Daniel J; Gray, McMahan L; Pennline, Henry W; Richards, George A.

    2011-09-01T23:59:59.000Z

    The emission of fossil fuel carbon dioxide (CO{sub 2) to the atmosphere is implicated as the predominant cause of global climate change; therefore, advanced CO{sub 2} capture technologies are of the utmost importance. In this study, innovative amine-multilayered sorbents were fabricated using layer-by-layer (LbL) nanoassembly technology via alternate deposition of a CO{sub 2}-adsorbing amine polymer (e.g. polyethylenimine or PEI) and an oppositely-charged polymer (e.g. polystyrene sulfonate or PSS). We found that the developed sorbents could be used for CO{sub 2} capture and that LbL nanoassembly allows us to engineer their CO{sub 2} capture performance through the fabrication variables (e.g. deposition polymers, deposition media, and number of bilayers). PEI/PSS was found to be the best polymer combination for developing sorbents with relatively high CO{sub 2} capture capacity. The amine-multilayered solid sorbents possessed fine microstructures and may have similar polymer deposition within and on the surface of solid sorbents. These amine-multilayered sorbents had much faster CO{sub 2} desorption rates compared to sorbents prepared using the current PEI-impregnation approach. Such fast CO{sub 2} desorption could make sorbents a good option for CO{sub 2} removal from power plants and even the atmosphere.

  17. Hot gas desulfurization with sorbents containing oxides of zinc, iron, vanadium and copper. Quarterly technical progress report, July 1992

    SciTech Connect (OSTI)

    Akyurtlu, A.; Akyurtlu, J.F.

    1992-09-01T23:59:59.000Z

    The main objective of this research is to evaluate the desulfurization performance of novel sorbents consisting of different combinations of zinc, iron, vanadium and copper oxides; and to develop a sorbent which can reduce H{sub 2}S levels to less than 1 ppmv, which can stabilize zinc, making operations above 650{degrees}C possible, and which can produce economically recoverable amounts of elemental sulfur during regeneration. This objective will be accomplished by evaluating the sorbent performance using fixed-bed and TGA experiments supported by sorbent characterization at various reaction extents. In the seventh quarter, the screening of the promoted sorbents in the packed bed reactor was continued. The results of this work were presented at the 1992 University Coal Research Contractors, Review Conference at Pittsburgh, PA.

  18. CO{sub 2} Capture from Flue Gas Using Solid Molecular Basket Sorbents

    SciTech Connect (OSTI)

    Fillerup, Eric; Zhang, Zhonghua; Peduzzi, Emanuela; Wang, Dongxiang; Guo, Jiahua; Ma, Xiaoliang; Wang, Xiaoxing; Song, Chunshan

    2012-08-31T23:59:59.000Z

    The objective of this project is to develop a new generation of solid, regenerable polymeric molecular basket sorbent (MBS) for more cost-efficient capture and separation of CO{sub 2} from flue gas of coal-fired power plants. The primary goal is to develop a cost-effective MBS sorbent with better thermal stability. To improve the cost-effectiveness of MBS, we have explored commercially available and inexpensive support to replace the more expensive mesoporous molecular sieves like MCM-41 and SBA- 15. In addition, we have developed some advanced sorbent materials with 3D pore structure such as hexagonal mesoporous silica (HMS) to improve the CO{sub 2} working capacity of MBS, which can also reduce the cost for the whole CO{sub 2} capture process. During the project duration, the concern regarding the desorption rate of MBS sorbents has been raised, because lower desorption rate increases the desorption time for complete regeneration of the sorbent which in turn leads to a lower working capacity if the regeneration time is limited. Thus, the improvement in the thermal stability of MBS became a vital task for later part of this project. The improvement in the thermal stability was performed via increasing the polymer density either using higher molecular weight PEI or PEI cross-linking with an organic compound. Moreover, we have used the computational approach to estimate the interaction of CO{sub 2} with different MBSs for the fundamental understanding of CO{sub 2} sorption, which may benefit the development, design and modification of the sorbents and the process.

  19. Decoupling of gravity on non-susy D$p$ branes

    E-Print Network [OSTI]

    Kuntal Nayek; Shibaji Roy

    2015-06-29T23:59:59.000Z

    We study the graviton scattering in the background of non-susy D$p$ branes of type II string theories consisting of a metric, a dilaton and a $(p+1)$ form gauge field. We show numerically that in these backgrounds graviton experiences a scattering potential which takes the form of an infinite barrier in the low energy (near brane) limit for $p\\leq 5$ and therefore is never able to reach the branes. This shows, contrary to what is known in the literature, that gravity indeed decouples from the non-susy D$p$ brane for $p \\leq 5$. For non-susy D6 brane, gravity couples as there is no such barrier for the potential. To give further credence to our claim we solve the scattering equation in certain situation analytically and calculate the graviton absorption cross-section on the non-susy branes and show that it vanishes for $p \\leq 4$ and diverges for $p=6$ in the low energy limit. This shows, as in the case of BPS branes, that gravity does decouple for non-susy D$p$ brane for $p\\leq 4$ but it does not decouple for D6 brane as the potential here is always attractive. We argue for the non-susy D5 brane that depending on one of the parameters of the solution gravity either always decouples (unlike the BPS D5 brane) or it decouples when the energy of the graviton is below certain critical value, otherwise it couples, very similar to BPS D5 brane.

  20. EPA-600/4-82-061 DOE/DP/00539-046

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell: GasEPA-600/4-82-061 DOE/DP/00539-046

  1. Dry Process Electrode Fabrication

    Broader source: Energy.gov (indexed) [DOE]

    Ratecapacity match cathode 12 8. Down-select low cost anode process 50% vs baseline capex + opex 13 9. Scale cathode film to support task 16 10 m 17 10. Lab prototype cell dry...

  2. Freeze drying method

    DOE Patents [OSTI]

    Coppa, Nicholas V. (Malvern, PA); Stewart, Paul (Youngstown, NY); Renzi, Ernesto (Youngstown, NY)

    1999-01-01T23:59:59.000Z

    The present invention provides methods and apparatus for freeze drying in which a solution, which can be a radioactive salt dissolved within an acid, is frozen into a solid on vertical plates provided within a freeze drying chamber. The solid is sublimated into vapor and condensed in a cold condenser positioned above the freeze drying chamber and connected thereto by a conduit. The vertical positioning of the cold condenser relative to the freeze dryer helps to help prevent substances such as radioactive materials separated from the solution from contaminating the cold condenser. Additionally, the system can be charged with an inert gas to produce a down rush of gas into the freeze drying chamber to also help prevent such substances from contaminating the cold condenser.

  3. Freeze drying apparatus

    DOE Patents [OSTI]

    Coppa, Nicholas V. (Malvern, PA); Stewart, Paul (Youngstown, NY); Renzi, Ernesto (Youngstown, NY)

    2001-01-01T23:59:59.000Z

    The present invention provides methods and apparatus for freeze drying in which a solution, which can be a radioactive salt dissolved within an acid, is frozen into a solid on vertical plates provided within a freeze drying chamber. The solid is sublimated into vapor and condensed in a cold condenser positioned above the freeze drying chamber and connected thereto by a conduit. The vertical positioning of the cold condenser relative to the freeze dryer helps to help prevent substances such as radioactive materials separated from the solution from contaminating the cold condenser. Additionally, the system can be charged with an inert gas to produce a down rush of gas into the freeze drying chamber to also help prevent such substances from contaminating the cold condenser.

  4. targetDP: an Abstraction of Lattice Based Parallelism with Portable Performance

    E-Print Network [OSTI]

    Alan Gray; Kevin Stratford

    2014-07-31T23:59:59.000Z

    To achieve high performance on modern computers, it is vital to map algorithmic parallelism to that inherent in the hardware. From an application developer's perspective, it is also important that code can be maintained in a portable manner across a range of hardware. Here we present targetDP (target Data Parallel), a lightweight programming layer that allows the abstraction of data parallelism for applications that employ structured grids. A single source code may be used to target both thread level parallelism (TLP) and instruction level parallelism (ILP) on either SIMD multi-core CPUs or GPU-accelerated platforms. targetDP is implemented via standard C preprocessor macros and library functions, can be added to existing applications incrementally, and can be combined with higher-level paradigms such as MPI. We present CPU and GPU performance results for a benchmark taken from the lattice Boltzmann application that motivated this work. These demonstrate not only performance portability, but also the optimisation resulting from the intelligent exposure of ILP.

  5. Ab initio screening of metal sorbents for elemental mercury capture in syngas streams

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Ab initio screening of metal sorbents for elemental mercury capture in syngas streams Anubhav Jain to produce a combustible syngas, a mixture of carbon monoxide and hydrogen gas. Power plants incorporating prior to combustion, i.e. in the pre-combustion syngas mixture rather than the flue gas; as such

  6. Development of novel copper-based sorbents for hot-gas cleanup. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Abbasian, J.; Hill, A.H.; Wangerow, J.R. [Institute of Gas Technology, Chicago, IL (United States); Flytzani-Stephanopoulos, M.; Bo, L.; Patel, C. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1992-10-01T23:59:59.000Z

    The objective of this investigation is to evaluate several novel copper-based binary oxides for their suitability as regenerable sorbents for hot gas cleanup application in the temperature range of 650{degrees} to 850{degrees}C. During this quarter cyclic sulfidation/regeneration tests of the sorbents Cu{sub 2}Cr-O and Cu-Ce-0 were conducted using different compositions of the feed gases to investigate the effects of H{sub 2}0, H{sub 2} and CO. These tests were conducted in a packed-bed microreactor at 850{degrees}C. The results of these tests showed that H{sub 2} and CO (along with C02) had a significant effect on the H{sub 2}S pre-breakthrough levels, whereas H{sub 2}0 did not have an effect. The physical properties of the fresh and reacted samples of the Cu-2Cr-O and Cu-Ce-0 sorbents prepared in this program and used in the cyclic sulfidation/regeneration tests were also measured. In addition, sulfidation/regeneration tests were conducted using two commercial copper chromite sorbents (G-13 and G-89, United Catalyst, Inc.) and a zinc titanate sorbent (L-3014) in a one-inch fluidized-bed reactor at 650{degrees}C. The G-13 sorbent appears to have a much higher sulfur capacity than the G-89 sorbent.

  7. Development of novel copper-based sorbents for hot-gas cleanup. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Abbasian, J.; Hill, A.H. [Inst. of Gas Technology, Chicago, IL (United States); Flytzani-Stephanopoulos, M.; Li, Z. [Tufts Univ., Medford, MA (United States)

    1994-09-01T23:59:59.000Z

    The objective of this investigation is to evaluate two novel copper-based sorbents, namely copper-chromium and copper-cerium, for their effectiveness in removing hydrogen sulfide from fuel gas in the temperature range of 650 to 850 C. Such high temperatures will be required for the new generation of gas turbines (inlet > 750 C) in Integrated Gasification Combined Cycle (IGCC) systems. Results of fixed-bed reactor tests conducted in this quarter, indicate that, at 750 C, pre-reduction with H{sub 2} in the presence of H{sub 2}O does not effect the performance of either sorbent for H{sub 2}S removal. For the pre-reduced CuCr{sub 2}O{sub 4} sorbent, copper utilization before the first H{sub 2}S breakthrough is substantially higher in synthesis feed gas mixture than in feed gas containing 30 Vol% H{sub 2}, and slightly lower than in 10 vol% H{sub 2}. In sulfidation-regeneration testing of copper- and additive-rich sorbents, chromium-rich CuO-3Cr{sub 2}O{sub 4} sorbent demonstrated very high H{sub 2}S removal efficiency and high copper conversion levels (comparable to that of the 1:1 molar composition sorbent). Similar results were obtained with the cerium-rich CuO-3CeO{sub 2} sorbent, but only for the first cycle. The H{sub 2}S removal performance of both copper-rich sorbents was inferior to that of the respective 1:1 molar compositions. CuO-CeO{sub 2} sorbent testing in a TGA indicates no appreciable decrease in the sulfidation rate over 5 1/2 cycles. However, weight changes during regeneration of the CuO-CeO{sub 2} suggest that some copper or cerium sulfates formed.

  8. Analysis of HLA-DP association with beryllium disease susceptibility in pooled exposed populations

    SciTech Connect (OSTI)

    Cesare Saltini, Massimo Amicosante

    2009-12-19T23:59:59.000Z

    Berylliosis or Chronic Beryllium Disease is a chronic granulomatous disorder primarily involving the lung associated with the exposition to low doses of Beryllium (Be) in the workplace. Berylliosis risk has been associated with the presence of a glutamate at position 69 of the HLA-DP beta chain (HLA-DPbetaGlu69) that is expressed in about 97% of disease cases and in 27% of the unaffected Be-exposed controls (p<0.0001) (Richeldi et al. Science 1993; 262: 242-244.12). Since this first observation of an immunogenetic association between berylliosis and HLA-DPbetaGlu69 a number of studies have confirmed the role of this marker as the primary gene of susceptibility of berylliosis (Richeldi et al Am J Ind Med. 1997; 32:337-40; Wang et al J. Immunol. 1999; 163: 1647-53; Saltini et al Eur Respir J. 2001 18:677-84; Rossman et al Am J Respir Crit Care Med. 2002 165:788-94). Moreover, a structure/function interaction between HLA-DP molecules carrying Glu69 and beryllium in driving and developing the immune response against beryllium itself has been observed as: (1) Be-specific T-cells clones obtained from berylliosis patients recognize beryllium as antigen only when presented in the context of the HLA-DP{beta}Glu69 molecules but not in the context of HLA-DP allelic variants carrying Lys69 (Lombardi G et al. J Immunol 2001; 166: 3549-3555), and (2) beryllium presents an affinity for the HLA-DP2, carrying the berylliosis marker of susceptibility HLA-DPGlu69, from 40 to 100 times higher that the HLA-DP molecule carrying Lys69 (Amicosante M. et al Hum. Immunol. 2001; 62: 686-93). However, although the immunogenetic studies performed have been addressed a number of different questions about the genetic association between berylliosis and/or beryllium sensitization, exposure levels to beryllium and HLA markers, a number of questions are still open in the field mainly due to the limitation imposed by the low number of subjects carrying berylliosis or beryllium sensitization enrolled in each immunogenetic study. In this context, the populations of the study already performed in this field by the University of Modena and Rome (by Prof. C. Saltini) and the University of Pennsylvania (by Prof. M. Rossman) have been evaluated by using similar HLA molecular typing methodologies and that both populations have now been followed up for a period of 4 to 7 years. The general objective of this study has to generate a larger data base comprising the two population with which analyze gene disease association with greater statistical power and ascertain the effect of lesser common gener variants which may be missed when analyzing associations on small populations. In particular addressing the role suggested in previous study such as: (1) the role of HLA-DP rare alleles and polymorphisms, and (2) the role of the HLA markers in disease progression from sensitization. The two populations from the already published studies (Saltini et al Eur Respir J. 2001 18:677-84; Rossman et al Am J Respir Crit Care Med. 2002 165:788-94) present similar aspects about: ethnicity, type and length of exposure to Be dust, a broadly similar association between beryllium related abnormalities and HLA. The two population have been pooled and evaluated using common criteria of diagnosis (Sensitized subject: at least 2 positive BeLPT tests each with 2 positive wells; CBD-affected subject: identification of well formed non-caseating granulomas on biopsy), follow up and HLA typing technique (complete HLA-DRB, DQB, DPB high resolution typing using amplification with sequence specific primers or sequence based typing). The two populations included 137 subjects with Beryllium hypersensitized (BH) and 155 Be-exposed controls. Inclusion criteria were met by one hundred and six subjects with Be-hypersensitivity of whom 55 were affected by CBD (age 52 {+-} 11 years; 50 caucasians, 2 African-Americans 2 Hispanics and 1 Asian; 46 males and 9 females; mean duration of Be-exposure 15 {+-} 9 years) and 51 showed Be-sensitization without lung granulomas detected by trans-bronchial biopsy (ag

  9. A Low Cost, High Capacity Regenerable Sorbent for Pre-combustion CO{sub 2} Capture

    SciTech Connect (OSTI)

    Alptekin, Gokhan

    2012-09-30T23:59:59.000Z

    The overall objective of the proposed research is to develop a low cost, high capacity CO{sub 2} sorbent and demonstrate its technical and economic viability for pre-combustion CO{sub 2} capture. The specific objectives supporting our research plan were to optimize the chemical structure and physical properties of the sorbent, scale-up its production using high throughput manufacturing equipment and bulk raw materials and then evaluate its performance, first in bench-scale experiments and then in slipstream tests using actual coal-derived synthesis gas. One of the objectives of the laboratory-scale evaluations was to demonstrate the life and durability of the sorbent for over 10,000 cycles and to assess the impact of contaminants (such as sulfur) on its performance. In the field tests, our objective was to demonstrate the operation of the sorbent using actual coal-derived synthesis gas streams generated by air-blown and oxygen-blown commercial and pilot-scale coal gasifiers (the CO{sub 2} partial pressure in these gas streams is significantly different, which directly impacts the operating conditions hence the performance of the sorbent). To support the field demonstration work, TDA collaborated with Phillips 66 and Southern Company to carry out two separate field tests using actual coal-derived synthesis gas at the Wabash River IGCC Power Plant in Terre Haute, IN and the National Carbon Capture Center (NCCC) in Wilsonville, AL. In collaboration with the University of California, Irvine (UCI), a detailed engineering and economic analysis for the new CO{sub 2} capture system was also proposed to be carried out using Aspen PlusTM simulation software, and estimate its effect on the plant efficiency.

  10. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 4, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Davis, S.

    1995-10-15T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  11. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 3, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.

    1995-09-06T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  12. Cooking with Dried Potatoes

    E-Print Network [OSTI]

    Anding, Jenna

    2008-12-09T23:59:59.000Z

    make a tasty vegetable dish. For added flavor, you can add salt and pepper along with small amounts of grated cheese, margarine or butter. Be careful: Adding large amounts of cheese, butter or margarine can turn a low-fat vegetable, such as potatoes..., into a high-fat dish. How to store them Store packages of dried potatoes in a cool, dry, place. After the package is opened, store the potatoes in an airtight container. Store cooked potatoes in a covered dish in the refrigerator. Use within 3 days...

  13. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2007-06-30T23:59:59.000Z

    In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

  14. Impact of tool wear on joint strength in friction stir spot welding of DP 980 steel

    SciTech Connect (OSTI)

    Miles, Michael; Ridges, Chris; Hovanski, Yuri; Peterson, Jeremy; Santella, M. L.; Steel, Russel

    2011-09-14T23:59:59.000Z

    Friction stir spot welding has been shown to be a viable method of joining ultra high strength steel (UHSS), both in terms of joint strength and process cycle time. However, the cost of tooling must be reasonable in order for this method to be adopted as an industrial process. Recently a new tool alloy has been developed, using a blend of PCBN and tungsten rhenium (W-Re) in order to improve the toughness of the tool. Wear testing results are presented for two of these alloys: one with a composition of 60% PCBN and 40% W-Re, and one with 70% PCBN and 30% W-Re. The sheet material used for all wear testing was 1.4 mm DP 980. Lap shear testing was used to show the relationship between tool wear and joint strength. The Q70 tool provided the best combination of wear resistance and joint strength.

  15. X-ray Variability and Period Determinations in the Eclipsing Polar DP Leo

    E-Print Network [OSTI]

    C. R. Robinson; F. A. Cordova

    1994-08-15T23:59:59.000Z

    An analysis of ROSAT observations for the eclipsing magnetic cataclysmic binary DP Leo provides constraints on the origin, size, temperature, variability and structure of the soft X-ray emission region on the surface of the white dwarf. These data, when combined with prior observations, show a progression of approximately 2 degrees per year in the impact position of the accretion stream onto the white dwarf. One explanation for the observed drift in stream position is that a magnetic activity cycle on the secondary produces orbital period oscillations. These oscillations result in an orbital period which cycles above and below the rotational period of the nearly synchronous white dwarf. The accretion stream and X-ray emission regions are modeled to fit the observational data. A distance to the system is also calculated. [An erroneous value for the cyclotron luminosity, included in an earlier paper version of the preprint, is corrected here.

  16. Spectroscopy of /sup 87,88,89/Sr with (n,. gamma. ) and (d,p) reactions

    SciTech Connect (OSTI)

    Winter, C.; Krusche, B.; Lieb, K.P.; Hlawatsch, G.; Egidy, T.V.; Hoyler, F.; Casten, R.F.

    1988-01-01T23:59:59.000Z

    Over the recent years the nuclear structure around the N = 50 shell closure, which is very pronounced in the strontium and zirconium isotopes, has been the subject of extensive experimental and theoretical work. On the proton side Z = 38 and Z = 40 provide fairly closed sub-shells. In the strontium isotopes the lg/sub 9/2/ neutron shell is closed at /sup 88/Sr, supplying relatively pure neutron-hole and neutron-particle states with large spectroscopic factors in /sup 87/Sr and /sup 89/Sr, as well as core-coupled states. The mass region is thus ideally suited to examine the transition from a correlated to an uncorrelated (chaotic.) excitational behavior. These two types are characterized e.g. by the density of excited states, the transition strengths, and the spectroscopic factors observed in transfer reactions. We conducted (n,..gamma..) and (d,p) reactions leading to /sup 87,88,89/Sr in addition to /sup 88/Sr(d,t)/sup 87/Sr and 24 keV neutron capture in /sup 88/Sr. The vast amounts of data were used to analyze the level densities and transition strengths in the statistical model. Correlations were found between the selective population of states dominating the (d,p) process, and the statistical decay of the compound state formed after thermal neutron capture. In the course of the analyses we established essentially complete level schemes (within limited spin windows centered around the spin of the capture state) up to around half the neutron binding energy. The E1 partial decay widths were found to agree with results of giant resonance calculations. We intend to give an overview of the experiments and outline the results of the model calculations. 24 refs., 4 figs.

  17. Cooling Dry Cows

    E-Print Network [OSTI]

    Stokes, Sandra R.

    2000-07-17T23:59:59.000Z

    , little work has been done on the responses of cooling cows in this period. The dry period is particularly crucial because it involves regen- eration of the mammary gland and rapid fetal growth. This is also when follicles begin develop- ing and maturing...

  18. Sorbent selection and design considerations for uranium trapping. [H-151 alumina, XF-100 alumina, F-1 alumina, sodium fluoride

    SciTech Connect (OSTI)

    Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

    1981-07-01T23:59:59.000Z

    The efficient removal of UF/sub 6/ from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications.

  19. EFFICIENT THEORETICAL SCREENING OF SOLID SORBENTS FOR CO2 CAPTURE APPLICATIONS

    SciTech Connect (OSTI)

    Duan, Yuhua; Sorescu, Dan C; Luebke, David

    2011-01-01T23:59:59.000Z

    Carbon dioxide is a major combustion product of coal, which once released into the air can contribute to global climate change. Current CO2 capture technologies for power generation processes including amine solvents and CaO-based sorbent materials require very energy intensive regeneration steps which result in significantly decreased efficiency. Hence, there is a critical need for new materials that can capture and release CO2 reversibly with acceptable energy costs if CO2 is to be captured and sequestered economically. Inorganic sorbents are one such class of materials which typically capture CO2 through the reversible formation of carbonates. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO2 sorbent candidates from the vast array of possible solid materials has been proposed and validated. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO2 capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. For a given solid, the first step is to attempt to extract thermodynamic properties from thermodynamic databases and available literatures. If the thermodynamic properties of the compound of interest are unknown, an ab initio thermodynamic approach is used to calculate them. These properties expressed conveniently as chemical potentials and heat of reactions, either from databases or from calculations, are further used for computing the thermodynamic reaction equilibrium properties of the CO2 absorption/desorption cycle based on the chemical potential and heat of reaction. Only those solid materials for which lower capture energy costs are predicted at the desired process conditions are selected as CO2 sorbent candidates and further considered for experimental validations. Solid sorbents containing alkali and alkaline earth metals have been reported in several previous studies to be good candidates for CO2 sorbent applications due to their high CO2 absorption capacity at moderate working temperatures. In addition to introducing our selection process in this presentation, we will present our results for solid systems of alkali and alkaline metal oxides, hydroxides and carbonates/bicarbonates to validate our methodology. Additionally, applications of our computational method to mixed solid systems of Li2O and SiO2 with different mixing ratios, we showed that increasing the Li2O/SiO2 ratio in lithium silicates increases their corresponding turnover temperatures for CO2 capture reactions. These theoretical predictions are in good agreement with available experimental findings.

  20. Regeneration of carboxylic acid-laden basic sorbents by leaching with a volatile base in an organic solvent

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); Husson, Scott M. (Berkeley, CA)

    1999-01-01T23:59:59.000Z

    Carboxylic acids are sorbed from aqueous feedstocks onto a solid adsorbent. The acids are freed from the sorbent phase by treating it with an organic solution of alkylamine thus forming an alkylamine/carboxylic acid complex which is decomposed with improved efficiency to the desired carboxylic acid and the alkylamine. Carbon dioxide addition can be used to improve the adsorption or the carboxylic acids by the solid phase sorbent.

  1. DP97, a DEAD box DNA/RNA helicase, is a target gene-selective co-regulator of the constitutive androstane receptor

    SciTech Connect (OSTI)

    Kanno, Yuichiro, E-mail: ykanno@phar.toho-u.ac.jp [Faculty of Pharmaceutical Sciences, Toho University, Chiba (Japan)] [Faculty of Pharmaceutical Sciences, Toho University, Chiba (Japan); Serikawa, Takafumi; Inajima, Jun; Inouye, Yoshio [Faculty of Pharmaceutical Sciences, Toho University, Chiba (Japan)] [Faculty of Pharmaceutical Sciences, Toho University, Chiba (Japan)

    2012-09-14T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer DP97 interacts with nuclear receptor CAR. Black-Right-Pointing-Pointer DP97 enhances CAR-mediated transcriptional activation. Black-Right-Pointing-Pointer DP97 synergistically enhances transactivity of CAR by the co-expression of SRC-1 or PGC1{alpha}. Black-Right-Pointing-Pointer DP97 is a gene-selective co-activator for hCAR. -- Abstract: The constitutive androstane receptor (CAR) plays a key role in the expression of xenobiotic/steroid and drug metabolizing enzymes and their transporters. In this study, we demonstrated that DP97, a member of the DEAD box DNA/RNA helicase protein family, is a novel CAR-interacting protein. Using HepG2 cells expressing human CAR in the presence of tetracycline, we showed that knockdown of DP97 with small interfering RNAs suppressed tetracycline-inducible mRNA expression of CYP2B6 and UGT1A1 but not CYP3A4. Thus, DP97 was found to be a gene (or promoter)-selective co-activator for hCAR. DP97-mediated CAR transactivation was synergistically enhanced by the co-expression of SRC-1 or PGC1{alpha}, therefore it might act as mediator between hCAR and appropriate co-activators.

  2. Investigation of combined S02/N0x Removal by Ceria Sorbents

    SciTech Connect (OSTI)

    Ates Akyurtlu; Jale F. Akyurtlu

    1996-11-01T23:59:59.000Z

    This final report describes the work done under the sponsorship of the U.S. DOE for the support of advanced fossil resource utilization research at historically black colleges and universities, Grant No. DE-Ps22-92MT920 on "Investigation of Combined S02/NOx Removal by Ceria Sorbents". The work was conducted at the Department of Chemical Engineering of Hampton University. The industrial partner was Malcolm Pirnie,Inc. Environmental Engineers, Scientists and Planners, who handled the metal analysis and XRD measurements on the solid sorbents; they have also supplied the flyash used in the experimental program. The development of a commercial process concept, economic analysis, and evaluation of process alternatives were undertaken by TECOGEN of Waltham, MA.

  3. Immobilizing tyrosinase within chitosan gels: A combination catalyst and sorbent for phenol removal

    SciTech Connect (OSTI)

    Sun, Wei-Qiang; Payne, G.F. [Univ. of Maryland, Baltimore, MD (United States)

    1995-12-01T23:59:59.000Z

    Phenols are common contaminants in chemical process effluents. To remove we developed a two step bioremediation approach in which an these contaminants, we developed a two step bioremediation approach in which an enzymatic reaction was coupled with absorption. In the first step, weakly adsorbable phenols are converted to reactive o-quinones by the enzyme tyrosinase. The quinones are then strongly adsorbed onto the surface of a chitosan sorbent in the second steel. Our results show that this two step approach can selectively and efficiently remove phenols from solution. To reduce this approach into practice, we immobilized the tyrosinase within a chitosan gel yielding a combined catalyst-sorbent film. Using this tyrosinase-containing chitosan gel, phenols (i.e. phenol, cresol and catechol) can be completely removed from solution.

  4. Drying of fiber webs

    DOE Patents [OSTI]

    Warren, David W. (9253 Glenoaks Blvd., Sun Valley, CA 91352)

    1997-01-01T23:59:59.000Z

    A process and an apparatus for high-intensity drying of fiber webs or sheets, such as newsprint, printing and writing papers, packaging paper, and paperboard or linerboard, as they are formed on a paper machine. The invention uses direct contact between the wet fiber web or sheet and various molten heat transfer fluids, such as liquified eutectic metal alloys, to impart heat at high rates over prolonged durations, in order to achieve ambient boiling of moisture contained within the web. The molten fluid contact process causes steam vapor to emanate from the web surface, without dilution by ambient air; and it is differentiated from the evaporative drying techniques of the prior industrial art, which depend on the uses of steam-heated cylinders to supply heat to the paper web surface, and ambient air to carry away moisture, which is evaporated from the web surface. Contact between the wet fiber web and the molten fluid can be accomplished either by submersing the web within a molten bath or by coating the surface of the web with the molten media. Because of the high interfacial surface tension between the molten media and the cellulose fiber comprising the paper web, the molten media does not appreciately stick to the paper after it is dried. Steam generated from the paper web is collected and condensed without dilution by ambient air to allow heat recovery at significantly higher temperature levels than attainable in evaporative dryers.

  5. Drying of fiber webs

    DOE Patents [OSTI]

    Warren, D.W.

    1997-04-15T23:59:59.000Z

    A process and an apparatus are disclosed for high-intensity drying of fiber webs or sheets, such as newsprint, printing and writing papers, packaging paper, and paperboard or linerboard, as they are formed on a paper machine. The invention uses direct contact between the wet fiber web or sheet and various molten heat transfer fluids, such as liquefied eutectic metal alloys, to impart heat at high rates over prolonged durations, in order to achieve ambient boiling of moisture contained within the web. The molten fluid contact process causes steam vapor to emanate from the web surface, without dilution by ambient air; and it is differentiated from the evaporative drying techniques of the prior industrial art, which depend on the uses of steam-heated cylinders to supply heat to the paper web surface, and ambient air to carry away moisture, which is evaporated from the web surface. Contact between the wet fiber web and the molten fluid can be accomplished either by submersing the web within a molten bath or by coating the surface of the web with the molten media. Because of the high interfacial surface tension between the molten media and the cellulose fiber comprising the paper web, the molten media does not appreciatively stick to the paper after it is dried. Steam generated from the paper web is collected and condensed without dilution by ambient air to allow heat recovery at significantly higher temperature levels than attainable in evaporative dryers. 6 figs.

  6. Development of a Calicum-Based Sorbent for Hot Gas Cleanup.

    SciTech Connect (OSTI)

    Wheelock, T.W.; Constant, K.; Doraiswamy, L.K.; Akiti, T.; Zhu, J.; Amanda, A.; Roe, R.

    1997-09-01T23:59:59.000Z

    Further review of the technical literature has provided additional information which will support the development of a superior calcium-based sorbent for hot gas cleanup in IGCC systems. Two general methods of sorbent preparation are being investigated. One method involves impregnating a porous refractory substrate with calcium while another method involves pelletizing lime or other calcium containing materials with a suitable binder. Several potential substrates, which are made of alumina and are commercially available, have been characterized by various methods. The surface area and apparent density of the materials have been measured, and it has been shown that some of the high surface area materials (i.e., 200-400 m{sub 2}/g) undergo a large decrease in surface area when heated to higher temperatures. Some of the lower surface area materials (i.e., 1-30 m{sub 2}/g) have been successfully impregnated with calcium by soaking them in a calcium nitrate solution and then heat treating them to decompose the nitrate. Potentially useful sorbents have also been prepared by pelletizing type I Portland cement and mixtures of cement and lime.

  7. Strategic Design and Optimization of Inorganic Sorbents for Cesium, Strontium and Actinides

    SciTech Connect (OSTI)

    Clearfield, Abraham

    2005-07-01T23:59:59.000Z

    It has been determined that poorly crystalline CST and SNT prepared at low temperature (100-150 C) exhibit much faster kinetics in uptake of Sr2+. In-situ X-ray studies has shown that SNT is a precursor phase to the formation of CST. It is possible to form mixtures of CST and SNT in a single reactant mix by control of temperature and time of reaction. It has been found that addition of a small amount of Cs+ to the reactant mix for the preparation of Nb-CST allows formation of the crystals in one day rather than ten days at 200 C. These discoveries suggest that a proper mix of sorbents (SNT, CST, Nb-CST) can be made easily at low cost that would remove all the HLW at the Savannah River site with a single in-tank procedure. The basic science goal in this project is to identify structure/affinity relationships for selected radionuclides and existing sorbents. The research will then apply this knowledge to the design and synthesis of sorbents that will exhibit increased cesium, strontium and actinide removal. The target problem focuses on the treatment of high-level nuclear wastes. The general approach can likewise be applied to non-radioactive separations.

  8. Strategic Design and Optimization of Inorganic Sorbents for Cesium, Strontium and Actinides

    SciTech Connect (OSTI)

    Clearfield, Abraham

    2005-07-01T23:59:59.000Z

    It has been determined that poorly crystalline CST and SNT prepared at low temperature (100-150 deg. C) exhibit much faster kinetics in uptake of Sr2+. 2. In-situ X-ray studies has shown that SNT is a precursor phase to the formation of CST. 3. It is possible to form mixtures of CST and SNT in a single reactant mix by control of temperature and time of reaction. 4. It has been found that addition of a small amount of Cs+ to the reactant mix for the preparation of Nb-CST allows formation of the crystals in one day rather than ten days at 200 deg. C. 5. These discoveries suggest that a proper mix of sorbents (SNT, CST, Nb-CST) can be made easily at low cost that would remove all the HLW at the Savannah River site with a single in-tank procedure. Research Objective The basic science goal in this project is to identify structure/affinity relationships for selected radionuclides and existing sorbents. The research will then apply this knowledge to the design and synthesis of sorbents that will exhibit increased cesium, strontium and actinide removal. The target problem focuses on the treatment of high-level nuclear wastes. The general approach can likewise be applied to non-radioactive separations.

  9. Process for CO.sub.2 capture using a regenerable magnesium hydroxide sorbent

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Stevens, Jr., Robert W

    2013-06-25T23:59:59.000Z

    A process for CO.sub.2 separation using a regenerable Mg(OH).sub.2 sorbent. The process absorbs CO.sub.2 through the formation of MgCO.sub.3 and releases water product H.sub.2O. The MgCO.sub.3 is partially regenerated through direct contact with steam, which acts to heat the magnesium carbonate to a higher temperature, provide heat duty required to decompose the magnesium carbonate to yield MgO and CO.sub.2, provide an H.sub.2O environment over the magnesium carbonate thereby shifting the equilibrium and increasing the potential for CO.sub.2 desorption, and supply H.sub.2O for rehydroxylation of a portion of the MgO. The mixture is polished in the absence of CO.sub.2 using water product H.sub.2O produced during the CO.sub.2 absorption to maintain sorbent capture capacity. The sorbent now comprised substantially of Mg(OH).sub.2 is then available for further CO.sub.2 absorption duty in a cyclic process.

  10. 2010 Dry Bean Research Report

    E-Print Network [OSTI]

    2010 Dry Bean Research Report Assessment of Narrow Row Technology Michigan Dry Edible Bean Production RESEARCH ADVISORY BOARD #12;The Michigan Bean Commission was awarded a grant from the MDA Technology for the Michigan Dry Bean Industry". Expected outcomes from this project are: 1. Identification

  11. 2012 Dry Bean Research Report

    E-Print Network [OSTI]

    2012 Dry Bean Research Report Assessment of Narrow Row Technology Michigan Dry Edible Bean Production Research Advisory Board #12;The Michigan Bean Commission was awarded a grant from the MDA Technology for the Michigan Dry Bean Industry". Expected outcomes from this project are: 1. Identification

  12. Hot coal gas desulfurization with manganese-based sorbents

    SciTech Connect (OSTI)

    Hepworth, M.T.; Ben-Slimane, R.

    1995-11-01T23:59:59.000Z

    The primary major deposit of manganese in the US which can be readily mined by an in situ process is located in the Emily district of Minnesota. The US Bureau of Mines Research Centers at both the Twin Cities and Salt Lake City have developed a process for extracting and refining manganese in the form of a high-purity carbonate product. This product has been formulated into pellets by a multi-step process of drying, calcination, and induration to produce relatively high-strength formulations which are capable of being used for hot fuel gas desulfurization. These pellets, which have been developed at the University of Minnesota under joint sponsorship of the US Department of Energy and the US Bureau of Mines, appear superior to other, more expensive, formulations of zinc titanate and zinc ferrite which have previously been studied for multi-cycle loading (desulfurization) and regeneration (evolution of high-strength SO{sub 2} and restoration of pellet reactivity). Although these other formulations have been under development for the past twelve years, their prices still exceed $7 per pound. If manganese pellets perform as predicted in fixed bed testing, and if a significant number of utilities which burn high-sulfur coals incorporate combined-cycle gasification with hot coal gas desulfurization as a viable means of increasing conversion efficiencies, then the potential market for manganese pellets may be as high as 200,000 tons per year at a price not less than $3 per pound. This paper discusses the role of manganese pellets in the desulfurization process with respect to the integrated gasification combined-cycle (IGCC) for power generation.

  13. Drying Rough Rice in Storage.

    E-Print Network [OSTI]

    Sorenson, J. W. Jr.; Crane, L. E.

    1960-01-01T23:59:59.000Z

    Drying. Rough Rice in Storage Ih AGRf""' TURP YPERIMENT STAT10 I. TEXAS SUMMARY Research was conducted at the Rice-Pasture Experiment Station near Beaumont during 7 crop years (1952-53 through 1958-59) to determine the engineering problems... and the practicability of dry- ing rough rice in storage in Texas. Drying rice in storage means drying rice in the same bin in which it is to be stored. Rough rice, with initial moisture contents of 15.0 to 23.0 percent, was dried at depths of 4 to 10 feet...

  14. Proof of concept testing of an integrated dry injection system for SO{sub 2}/NO{sub x} control. Final report

    SciTech Connect (OSTI)

    Helfritch, D.J.; Bortz, S.J. [Research-Cottrell, Inc., Somerville, NJ (United States); Beittel, R. [Riley Stoker Corp., Worcester, MA (United States)

    1994-03-01T23:59:59.000Z

    The integrated Dry Injection Process (IDIP) consists of combustion modification using low NO{sub x} burners to reduce NO{sub x} emissions, dry injection of hydrated line at economizer temperatures for primary capture of SO{sub 2}, dry injection of a commercial grade sodium bicarbonate at the air heater exit for additional SO{sub 2} and NO{sub x} removal, and humidification for precipitator conditioning. IDIP offers the potential for simultaneously achieving 90% SO{sub 2} removal, and 65% NO{sub x} removal from a high sulfur flue gas. The process is well suited for new or retrofit applications since it can be incorporated within existing economizer and downstream ductwork. Subscale tests were performed in order to identify the best calcium and sodium sorbents. These tests involved the injection of calcium hydroxide and sodium sorbents at various points of the flue gas system downstream of a 0.25 MM BTU/hr. coal fired combustor, and the gas residence times, cooling rates and temperatures were comparable to those found for full-scale utility boilers. These tests verified that a high surface area hydrated lime provides maximum sorbent utilization and identified an alcohol-water hydrated lime as yielding the highest surface area and the best SO{sub 2} removal capability. The tests also identified sodium bicarbonate to be somewhat more effective than sodium sesquicarbonate for SO{sub 2} removal. The proof of concept demonstration was conducted on the large combustor at the Riley Stoker Research Facility in Worcester, MA. When economically compared to conventional limestone slurry scrubbing on a 300 MW plant, the dry injection process shows lower capital cost but higher operating cost. Hydrated lime injection can be less costly than limestone scrubbing when two or more of the following conditions exist: plant is small (less than 100MW); yearly operating hours are small (less than 3000); and the remaining plant lifetime is small (less than 10 years).

  15. Wear testing of friction stir spot welding tools for joining of DP 980 Steel

    SciTech Connect (OSTI)

    Ridges, Chris; Miles, Michael; Hovanski, Yuri; Peterson, Jeremy; Steel, Russell

    2011-06-06T23:59:59.000Z

    Friction stir spot welding has been shown to be a viable method of joining ultra high strength steel (UHSS), both in terms of joint strength and process cycle time. However, the cost of tooling must be reasonable in order for this method to be adopted as an industrial process. Several tooling materials have been evaluated in prior studies, including silicon nitride and polycrystalline cubic boron nitride (PCBN). Recently a new tool alloy has been developed, where a blend of PCBN and tungsten rhenium (W-Re) was used in order to improve the toughness of the tool. Wear testing results are presented for two of these alloys: one with a composition of 60% PCBN and 40% W-Re (designated as Q60), and one with 70% PCBN and 30% W-Re (designated at Q70). The sheet material used for all wear testing was DP 980. Tool profiles were measured periodically during the testing process in order to show the progression of wear as a function of the number of spots produced. Lap shear testing was done each time a tool profile was taken in order to show the relationship between tool wear and joint strength. For the welding parameters chosen for this study the Q70 tool provided the best combination of wear resistance and joint strength.

  16. Joint strength in high speed friction stir spot welded DP 980 steel

    SciTech Connect (OSTI)

    Saunders, Nathan; Miles, Michael; Hartman, Trent; Hovanski, Yuri; Hong, Sung Tae; Steel, Russell

    2014-05-01T23:59:59.000Z

    High speed friction stir spot welding was applied to 1.2 mm thick DP 980 steel sheets under different welding conditions, using PCBN tools. The range of vertical feed rates used during welding was 2.5 mm – 102 mm per minute, while the range of spindle speeds was 2500 – 6000 rpm. Extended testing was carried out for five different sets of welding conditions, until tool failure. These welding conditions resulted in vertical welding loads of 3.6 – 8.2 kN and lap shear tension failure loads of 8.9 – 11.1 kN. PCBN tools were shown, in the best case, to provide lap shear tension fracture loads at or above 9 kN for 900 spot welds, after which tool failure caused a rapid drop in joint strength. Joint strength was shown to be strongly correlated to bond area, which was measured from weld cross sections. Failure modes of the tested joints were a function of bond area and softening that occurred in the heat-affected zone.

  17. Radar Imaging and Characterization of Binary Near-Earth Asteroid (185851) 2000 DP107

    E-Print Network [OSTI]

    Naidu, Shantanu P; Taylor, Patrick A; Nolan, Michael C; Busch, Michael W; Benner, Lance A M; Brozovic, Marina; Giorgini, Jon D; Jao, Joseph S; Magri, Chris

    2015-01-01T23:59:59.000Z

    Potentially hazardous asteroid (185851) 2000 DP107 was the first binary near-Earth asteroid to be imaged. Radar observations in 2000 provided images at 75 m resolution that revealed the shape, orbit, and spin-up formation mechanism of the binary. The asteroid made a more favorable flyby of the Earth in 2008, yielding images at 30 m resolution. We used these data to obtain shape models for the two components and to improve the estimates of the mutual orbit, component masses, and spin periods. The primary has a sidereal spin period of 2.7745 +/- 0.0007 h and is roughly spheroidal with an equivalent diameter of 863 m +/- 5%. It has a mass of 4.656 +/- 0.56 x 10^11 kg and a density of 1381 +/- 268 kg/m^3. It exhibits an equatorial ridge similar to the (66391) 1999 KW4 primary, however the equatorial ridge in this case is not as regular and has a ~300 m diameter concavity on one side. The secondary has a sidereal spin period of 1.77 +/- 0.02 days commensurate with the orbital period. The secondary is slightly elon...

  18. Method of drying articles

    DOE Patents [OSTI]

    Janney, M.A.; Kiggans, J.O. Jr.

    1999-03-23T23:59:59.000Z

    A method of drying a green particulate article includes the steps of: (a) Providing a green article which includes a particulate material and a pore phase material, the pore phase material including a solvent; and (b) contacting the green article with a liquid desiccant for a period of time sufficient to remove at least a portion of the solvent from the green article, the pore phase material acting as a semipermeable barrier to allow the solvent to be sorbed into the liquid desiccant, the pore phase material substantially preventing the liquid desiccant from entering the pores. 3 figs.

  19. Method of drying articles

    DOE Patents [OSTI]

    Janney, Mark A. (Knoxville, TN); Kiggans, Jr., James O. (Oak Ridge, TN)

    1999-01-01T23:59:59.000Z

    A method of drying a green particulate article includes the steps of: a. Providing a green article which includes a particulate material and a pore phase material, the pore phase material including a solvent; and b. contacting the green article with a liquid desiccant for a period of time sufficient to remove at least a portion of the solvent from the green article, the pore phase material acting as a semipermeable barrier to allow the solvent to be sorbed into the liquid desiccant, the pore phase material substantially preventing the liquid desiccant from entering the pores.

  20. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31T23:59:59.000Z

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  1. Integrated Ingredients Dehydrated Agricultural Drying Low Temperature...

    Open Energy Info (EERE)

    Ingredients Dehydrated Agricultural Drying Low Temperature Geothermal Facility Jump to: navigation, search Name Integrated Ingredients Dehydrated Agricultural Drying Low...

  2. Solid molecular basket sorbent for CO2 capture from gas streams with low CO2 concentration at ambient conditions

    SciTech Connect (OSTI)

    Wang, Xiaoxing [Pennsylvania State University; Ma, Xiaoliang [Pennsylvania State University; Schwartz, Viviane [ORNL; Clark, Jason C [ORNL; Overbury, Steven {Steve} H [ORNL; Zhao, Shuqi [Pennsylvania State University, University Park, PA; Xu, Xiaochun [Pennsylvania State University; Song, Chunshan [Pennsylvania State University

    2012-01-01T23:59:59.000Z

    In this paper, a solid molecular basket sorbent, 50 wt% PEI/SBA-15 was studied for CO2 capture from gas streams with low CO2 concentration at ambient conditions. The sorbent was able to effectively and selectively capture CO2 from a gas stream containing 1% CO2 at 75 C, with a breakthrough and saturation capacity of 63.1 and 66.7 mg/g, respectively, and a selectivity of 14 for CO2/CO and 185 for CO2/Ar. The sorption performance of the sorbent was influenced greatly by the operating temperature. The CO2-TPD study showed that the sorbent could be regenerated at mild conditions (50-110 C) and was stable in the cyclical operations for at least 20 cycles. Furthermore, the possibility for CO2 capture from air using the PEI/SBA-15 sorbent was studied by FTIR and proved by TPD. A capacity of 22.5 mg/g was attained at 75 C via TPD method using a simulated air with 400 ppmv CO2 in N2.

  3. DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2005-01-30T23:59:59.000Z

    For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

  4. Development of Novel Carbon Sorbents for CO{sub 2} Capture

    SciTech Connect (OSTI)

    Krishnan, Gopala; Hornbostel, Marc; Bao, Jianer; Perez, Jordi; Nagar, Anoop; Sanjurjo, Angel

    2013-11-30T23:59:59.000Z

    An innovative, low-cost, and low-energy-consuming carbon dioxide (CO{sub 2}) capture technology was developed, based on CO{sub 2}adsorption on a high-capacity and durable carbon sorbent. This report describes the (1) performance of the concept on a bench-scale system; (2) results of parametric tests to determine the optimum operating conditions; (3) results of the testing with a flue gas from coal-fired boilers; and (4) evaluation of the technical and economic viability of the technology. The process uses a falling bed of carbon sorbent microbeads to separate the flue gas into two streams: a CO{sub 2} -lean flue gas stream from which > 90% of the CP{sub 2} is removed and a pure stream of CO{sub 2} that is ready for compression and sequestration. The carbo sorbent microbeads have several unique properties such as high CO{sub 2} capacity, low heat of adsorption and desorption (25 to 28 kJ/mole), mechanically robust, and rapid adsorption and desorption rates. The capture of CO{sub 2} from the flue gas is performed at near ambient temperatures in whic the sorbent microbeads flow down by gravity counter-current with the up-flow of the flue gas. The adsorbed CO{sub 2} is stripped by heating the CO{sub 2}-loaded sorbent to - 100°C, in contact with low-pressure (- 5 psig) steam in a section at the bottom of the adsorber. The regenerated sorben is dehydrated of adsorbed moisture, cooled, and lifted back to the adsorber. The CO{sub 2} from the desorber is essentially pure and can be dehydrated, compressed, and transported to a sequestration site. Bench-scale tests using a simulated flue gas showed that the integrated system can be operated to provide > 90% CO{sub 2} capture from a 15% CO{sub 2} stream in the adsorber and produce > 98% CO{sub 2} at the outlet of the stripper. Long-term tests ( 1,000 cycles) showed that the system can be operated reliably without sorbent agglomeration or attrition. The bench-scale reactor was also operated using a flue gas stream from a coal-fired boil at the University of Toledo campus for about 135 h, comprising 7,000 cycles of adsorption and desorption using the desulfurized flue gas that contained only 4.5% v/v CO{sub 2}. A capture efficiency of 85 to 95% CO{sub 2} was achieved under steady-state conditi ons. The CO{sub 2} adsorption capacity did not change significantly during the field test, as determined from the CO{sub 2} adsorptio isotherms of fresh and used sorbents. The process is also being tested using the flue gas from a PC-fired power plant at the National Carbon Capture Center (NCCC), Wilsonville, AL. The cost of electricity was calculated for CO{sub 2} capture using the carbon sorbent and compared with the no-CO{sub 2} capture and CO{sub 2} capture with an amine-based system. The increase i the levelized cost of electricity (L-COE) is about 37% for CO{sub 2} capture using the carbon sorbent in comparison to 80% for an amine-based system, demonstrating the economic advantage of C capture using the carbon sorbent. The 37% increase in the L-COE corresponds to a cost of capture of $30/ton of CO{sub 2}, including compression costs, capital cost for the capture system, and increased plant operating and capital costs to make up for reduced plant efficiency. Preliminary sensitivity analyses showed capital costs, pressure drops in the adsorber, and steam requirement for the regenerator are the major variables in determining the cost of CO{sub 2} capture. The results indicate that further long-term testing with a flue gas from a pulverized coal­ fired boiler should be performed to obtain additional data relating to the effects of flue gas contaminants, the ability to reduce pressure drop by using alternate structural packing , and the use of low-cost construction materials.

  5. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01T23:59:59.000Z

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  6. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 5, October 1, 1995--December 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Davis, S.

    1996-06-01T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures,which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined. The research is divided into the following five tasks: (1) combustor modifications; (2) screening experiments; (3) mechanisms; (4) applications and (5) mathematical modelling. Accomplishments for this past quarter are briefly described for tasks 1 and 2.

  7. Studies of in-situ calcium based sorbents in advanced pressurized coal conversion systems. Final report, June 1991--October 1994

    SciTech Connect (OSTI)

    Katta, S.; Shires, P.J.; Campbell, W.M.; Henningsen, G.

    1994-10-01T23:59:59.000Z

    The overall objective of this project was to obtain experimental data on the reactions of calcium-based sorbents in both air-blown coal gasification systems and second generation fluid bed coal combustion systems (partial gasification) as well as stabilization of the spent sorbent produced. The project consisted of six tasks: Tasks 1 and 2 dealt mostly with project-related activities and preparation of test equipment, Task 3 -- study on sulfidation of calcium-based sorbents, Task 4 -- kinetic studies on calcium-catalyzed carbon gasification reactions, and Task 5 -- oxidation of CaS present in LASHs and DASHs (mixtures of coal ash and limestone or dolomite respectively) to CaSO{sub 4} and absorption of SO{sub 2} on various solids, and Task 6 -- economic evaluation of the most promising CaS oxidation method developed under this program. Experimental studies were conducted primarily to address Task 5 issues, and are discussed in this report.

  8. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Rupp, E.C.; Stanko, D.C.; Howard, B.; Pennline, H.W.

    2011-01-01T23:59:59.000Z

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur. and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide. but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur. resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  9. Theoretical Screening of Mixed Solid Sorbent for Applications to CO{sub 2} Capture Technology

    SciTech Connect (OSTI)

    Duan, Yuhua

    2014-01-01T23:59:59.000Z

    Since current technologies for capturing CO{sub 2} to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO{sub 2} reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO{sub 2} capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO{sub 2} sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO{sub 2} adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO{sub 2} capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO{sub 2} sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO{sub 2} capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we apply our screening methodology to mixing solid systems to adjust the turnover temperature to help on developing CO{sub 2} capture Technologies.

  10. Theoretical calculating the thermodynamic properties of solid sorbents for CO{sub 2} capture applications

    SciTech Connect (OSTI)

    Duan, Yuhua

    2012-11-02T23:59:59.000Z

    Since current technologies for capturing CO{sub 2} to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO{sub 2} reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO{sub 2} capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO{sub 2} sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO{sub 2} adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO{sub 2} capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO{sub 2} sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO{sub 2} capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we first introduce our screening methodology and the results on a testing set of solids with known thermodynamic properties to validate our methodology. Then, by applying our computational method to several different kinds of solid systems, we demonstrate that our methodology can predict the useful information to help developing CO{sub 2} capture Technologies.

  11. Theoretical Screening of Mixed Solid Sorbent for Applications to CO{sub 2} Capture Technology

    SciTech Connect (OSTI)

    Duan, Yuhua

    2014-03-30T23:59:59.000Z

    Since current technologies for capturing CO{sub 2} to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO{sub 2} reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO{sub 2} capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO{sub 2} sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO{sub 2} adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO{sub 2} capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO{sub 2} sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO{sub 2} capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we apply our screening methodology to mixing solid systems to adjust the turnover temperature to help on developing CO{sub 2} capture Technologies.

  12. Computational Modeling of Mixed Solids for CO2 CaptureSorbents

    SciTech Connect (OSTI)

    Duan, Yuhua

    2015-01-01T23:59:59.000Z

    Since current technologies for capturing CO2 to fight global climate change are still too energy intensive, there is a critical need for development of new materials that can capture CO2 reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO2 capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO2 sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO2 adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO2 capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. Only those selected CO2 sorbent candidates were further considered for experimental validations. The ab initio thermodynamic technique has the advantage of identifying thermodynamic properties of CO2 capture reactions without any experimental input beyond crystallographic structural information of the solid phases involved. Such methodology not only can be used to search for good candidates from existing database of solid materials, but also can provide some guidelines for synthesis new materials. In this presentation, we apply our screening methodology to mixing solid systems to adjust the turnover temperature to help on developing CO2 capture Technologies.

  13. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Browers, Bruce; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-31T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, a Technical and Economic Feasibility Study was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment developed a process flow diagram, major equipment list, heat balances for the SCPC power plant, capital cost estimate, operating cost estimate, levelized cost of electricity, cost of CO2 capture ($/ton) and three sensitivity cases for the CACHYS™ process.

  14. LONG-TERM DEMONSTRATION OF SORBENT ENHANCEMENT ADDITIVE TECHNOLOGY FOR MERCURY CONTROL

    SciTech Connect (OSTI)

    Jason D. Laumb; Dennis L. Laudal; Grant E. Dunham; John P. Kay; Christopher L. Martin; Jeffrey S. Thompson; Nicholas B. Lentz; Alexander Azenkeng; Kevin C. Galbreath; Lucinda L. Hamre

    2011-05-27T23:59:59.000Z

    Long-term demonstration tests of advanced sorbent enhancement additive (SEA) technologies have been completed at five coal-fired power plants. The targeted removal rate was 90% from baseline conditions at all five stations. The plants included Hawthorn Unit 5, Mill Creek Unit 4, San Miguel Unit 1, Centralia Unit 2, and Hoot Lake Unit 2. The materials tested included powdered activated carbon, treated carbon, scrubber additives, and SEAs. In only one case (San Miguel) was >90% removal not attainable. The reemission of mercury from the scrubber at this facility prevented >90% capture.

  15. Theoretical Screening of Solid Sorbents for CO{sub 2} Capture

    SciTech Connect (OSTI)

    Duan, Y [NETL; Sorescu, D C [NETL; Luebke, D [NETL; Morreale, B [NETL; Li, B Y; Zhang, B; Johnson, J K; Zhang, K; Li, X S; King, D

    2013-04-11T23:59:59.000Z

    By combining thermodynamic database searches with density functional theory and lattice phonon dynamics, a screening methodology was developed to identify promising solid sorbent candidates for CO{sub 2} capture. This methodology has been used to screen hundreds of solid compounds and some of the promising candidates to date have been reported in literature. This screening methodology is particularly relevant for the case of materials for which experimental thermodynamic data is not available. Such areas of interest are represented by the case of solid mixtures and doped materials, where thermodynamic data are generally not available but for which the crystallographic structure is known or can be easily determined.

  16. Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

    2010-01-01T23:59:59.000Z

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  17. 2013 Dry Bean Research Report

    E-Print Network [OSTI]

    Page 1 2013 Dry Bean Research Report Black Bean Color Retention and White Mold Control in Narrow Row Production Systems Michigan Dry Edible Bean Production Research Advisory Board #12;Page 2 The Michigan Bean Commission was awarded a grant from the MDARD Specialty Crop Block Grant Program-Farm Bill

  18. Land application uses for dry FGD by-products, Phase 1 report

    SciTech Connect (OSTI)

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W.

    1993-04-01T23:59:59.000Z

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. FGD by-product materials are treated as solid wastes and must be landfilled. It is highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. The results indicated the chemical composition of the FGD by-product materials were dominated by Ca, S, Al, and Si. Many of the elements regulated by the US Environmental Protection Agency reside primarily in the fly ash. Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD by-product materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  19. LIFAC sorbent injection desulfurization demonstration project. Final report, volume II: Project performance and economics

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    This publication discusses the demonstration of the LIFAC sorbent injection technology at Richmond Power and Light`s Whitewater Valley Unit No. 2, performed under the auspices of the U.S. Department of Energy`s (DOE) Clean Coal Technology Program. LIFAC is a sorbent injection technology capable of removing 75 to 85 percent of a power plant`s SO{sub 2} emissions using limestone at calcium to sulfur molar ratios of between 2 and 2.5 to 1. The site of the demonstration is a coal-fired electric utility power plant located in Richmond, Indiana. The project is being conducted by LIFAC North America (LIFAC NA), a joint venture partnership of Tampella Power Corporation and ICF Kaiser Engineers, in cooperation with DOE, RP&L, and Research Institute (EPRI), the State of Indiana, and Black Beauty Coal Company. The purpose of Public Design Report Volume 2: Project Performance and Economics is to consolidate, for public use, the technical efficiency and economy of the LIFAC Process. The report has been prepared pursuant to the Cooperative Agreement No. DE-FC22-90PC90548 between LIFAC NA and the U.S. Department of Energy.

  20. High-intensity drying processes: Impulse drying. Annual report

    SciTech Connect (OSTI)

    Orloff, D.I.; Phelan, P.M.

    1993-12-01T23:59:59.000Z

    Experiments were conducted on a sheet-fed pilot-scale shoe press to compare impulse drying and double-felted pressing. Both an IPST (Institute of Paper Science and Technology) ceramic coated and Beloit Type A press roll were evaluated for lienrboard sheet structures having a wide range of z-direction permeability. Purpose was to find ways of correcting sheet sticking problems observed in previous pilot-scale shoe press experiments. Results showed that impulse drying was superior to double felted pressing in both press dryness and in important paper physical properties. Impulse drying critical temperature was found to depend on specific surface of the heated layer of the sheet, thermal properties of the press roll surface, and choice of felt. Impulse drying of recycled and two-ply liner was demonstrated for both Southern Pile and Douglas fir-containing furnishes.

  1. EVALUATION OF SOLID SORBENTS AS A RETROFIT TECHNOLOGY FOR CO2 CAPTURE FROM COAL-FIRED POWER PLANTS

    SciTech Connect (OSTI)

    Holly Krutka; Sharon Sjostrom

    2011-07-31T23:59:59.000Z

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process/equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines; 31 carbon based materials; 6 zeolites; 7 supported carbonates (evaluated under separate funding); and 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant's Martin Lake Steam Electric Station and Xcel Energy's Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO{sub 2} removal with the sorbents evaluated under this program, it was useful to compare the CO{sub 2} removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the cocurrent adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO{sub 2} for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO{sub 2} removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO{sub 2} capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO{sub 2} uptake rate. Three additional supported amine materials, so

  2. Preparation and study of the adsorption properties of microporous sorbents based on montmorillonite and basic aluminum salts

    SciTech Connect (OSTI)

    Tarasevich, Yu.I.; Doroshenko, V.E.; Rudenko, V.M.; Ivanova, Z.G.

    1986-11-01T23:59:59.000Z

    Sorbents based on montmorillonite and basic aluminum chlorides with platelike micropores 0.77 nm thick were synthesized. The parameters of the primary and secondary pore structure of these materials were estimated from adsorption and x-ray data. A method was proposed for estimating the amount of initial montmorillonite stacks and stacks modified by the basic aluminum cations.

  3. Evaluation of Solid Sorbents As A Retrofit Technology for CO{sub 2} Capture from Coal-Fired Power Plants

    SciTech Connect (OSTI)

    Krutka, Holly; Sjostrom, Sharon

    2011-07-31T23:59:59.000Z

    Through a U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) funded cooperative agreement DE-NT0005649, ADA Environmental Solutions (ADA) has begun evaluating the use of solid sorbents for CO{sub 2} capture. The project objective was to address the viability and accelerate development of a solid-based CO{sub 2} capture technology. To meet this objective, initial evaluations of sorbents and the process / equipment were completed. First the sorbents were evaluated using a temperature swing adsorption process at the laboratory scale in a fixed-bed apparatus. A slipstream reactor designed to treat flue gas produced by coal-fired generation of nominally 1 kWe was designed and constructed, which was used to evaluate the most promising materials on a more meaningful scale using actual flue gas. In a concurrent effort, commercial-scale processes and equipment options were also evaluated for their applicability to sorbent-based CO{sub 2} capture. A cost analysis was completed that can be used to direct future technology development efforts. ADA completed an extensive sorbent screening program funded primarily through this project, DOE NETL cooperative agreement DE-NT0005649, with support from the Electric Power Research Institute (EPRI) and other industry participants. Laboratory screening tests were completed on simulated and actual flue gas using simulated flue gas and an automated fixed bed system. The following types and quantities of sorbents were evaluated: 87 supported amines, 31 carbon based materials, 6 zeolites, 7 supported carbonates (evaluated under separate funding), 10 hydrotalcites. Sorbent evaluations were conducted to characterize materials and down-select promising candidates for further testing at the slipstream scale. More than half of the materials evaluated during this program were supported amines. Based on the laboratory screening four supported amine sorbents were selected for evaluation at the 1 kW scale at two different field sites. ADA designed and fabricated a slipstream pilot to allow an evaluation of the kinetic behavior of sorbents and provide some flexibility for the physical characteristics of the materials. The design incorporated a transport reactor for the adsorber (co-current reactor) and a fluidized-bed in the regenerator. This combination achieved the sorbent characterization goals and provided an opportunity to evaluate whether the potential cost savings associated with a relatively simple process design could overcome the sacrifices inherent in a co-current separation process. The system was installed at two field sites during the project, Luminant’s Martin Lake Steam Electric Station and Xcel Energy’s Sherburne County Generating Station (Sherco). Although the system could not maintain continuous 90% CO{sub 2} removal with the sorbents evaluated under this program, it was useful to compare the CO{sub 2} removal properties of several different sorbents on actual flue gas. One of the supported amine materials, sorbent R, was evaluated at both Martin Lake and Sherco. The 1 kWe pilot was operated in continuous mode as well as batch mode. In continuous mode, the sorbent performance could not overcome the limitations of the co-current adsorbent design. In batch mode, sorbent R was able to remove up to 90% CO{sub 2} for several cycles. Approximately 50% of the total removal occurred in the first three feet of the adsorption reactor, which was a transport reactor. During continuous testing at Sherco, CO{sub 2} removal decreased to approximately 20% at steady state. The lack of continuous removal was due primarily to the combination of a co-current adsorption system with a fluidized bed for regeneration, a combination which did not provide an adequate driving force to maintain an acceptable working CO{sub 2} capacity. In addition, because sorbent R consisted of a polymeric amine coated on a silica substrate, it was believed that the 50% amine loaded resulted in mass diffusion limitations related to the CO{sub 2} uptake rate. Three additional supported amine materials,

  4. Low Cost Sorbent for Capturing CO{sub 2} Emissions Generated by Existing Coal-fired Power Plants

    SciTech Connect (OSTI)

    Elliott, Jeannine

    2013-08-31T23:59:59.000Z

    TDA Research, Inc. has developed a novel sorbent based post-combustion CO{sub 2} removal technology. This low cost sorbent can be regenerated with low-pressure (ca. 1 atm) superheated steam without temperature swing or pressure-swing. The isothermal and isobaric operation is a unique and advantageous feature of this process. The objective of this project was to demonstrate the technical and economic merit of this sorbent based CO{sub 2} capture approach. Through laboratory, bench-scale and field testing we demonstrated that this technology can effectively and efficiently capture CO{sub 2} produced at an existing pulverized coal power plants. TDA Research, Inc is developing both the solid sorbent and the process designed around that material. This project addresses the DOE Program Goal to develop a capture technology that can be added to an existing or new coal fired power plant, and can capture 90% of the CO{sub 2} produced with the lowest possible increase in the cost of energy. .

  5. DOE/FETC/TR--98-01 SORBENTS FOR MERCURY REMOVAL FROM FLUE GAS

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451 Clean Energy5655994DP-1513 . Di

  6. Spent fuel drying system test results (second dry-run)

    SciTech Connect (OSTI)

    Klinger, G.S.; Oliver, B.M.; Abrefah, J.; Marschman, S.C.; MacFarlan, P.J.; Ritter, G.A.

    1998-07-01T23:59:59.000Z

    The water-filled K-Basins in the Hanford 100 Area have been used to store N-Reactor spent nuclear fuel (SNF) since the 1970s. Because some leaks have been detected in the basins and some of the fuel is breached due to handling damage and corrosion, efforts are underway to remove the fuel elements from wet storage. An Integrated Process Strategy (IPS) has been developed to package, dry, transport, and store these metallic uranium fuel elements in an interim storage facility on the Hanford Site (WHC 1995). Information required to support the development of the drying processes, and the required safety analyses, is being obtained from characterization tests conducted on fuel elements removed from the K-Basins. A series of whole element drying tests (reported in separate documents, see Section 7.0) have been conducted by Pacific Northwest National Laboratory (PNNL) on several intact and damaged fuel elements recovered from both the K-East and K-West Basins. This report documents the results of the second dry-run test, which was conducted without a fuel element. With the concurrence of project management, the test protocol for this run, and subsequent drying test runs, was modified. These modifications were made to allow for improved data correlation with drying procedures proposed under the IPS. Details of these modifications are discussed in Section 3.0.

  7. Textile Drying Via Wood Gasification 

    E-Print Network [OSTI]

    McGowan, T. F.; Jape, A. D.

    1983-01-01T23:59:59.000Z

    This project was carried out to investigate the possibility of using wood gas as a direct replacement for natural gas in textile drying. The Georgia Tech updraft gasifier was used for the experimental program. During preliminary tests, the 1 million...

  8. Textile Drying Via Wood Gasification

    E-Print Network [OSTI]

    McGowan, T. F.; Jape, A. D.

    1983-01-01T23:59:59.000Z

    This project was carried out to investigate the possibility of using wood gas as a direct replacement for natural gas in textile drying. The Georgia Tech updraft gasifier was used for the experimental program. During preliminary tests, the 1 million...

  9. Geothermal Food Processors Agricultural Drying Low Temperature...

    Open Energy Info (EERE)

    Food Processors Agricultural Drying Low Temperature Geothermal Facility Jump to: navigation, search Name Geothermal Food Processors Agricultural Drying Low Temperature Geothermal...

  10. Surface characterization of Pd/Al2O3 sorbents for mercury capture from fuel gas

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Stanko, D.C.; Pennline, H.W.

    2008-01-01T23:59:59.000Z

    The surface composition of a series of Pd/alumina sorbents has been characterized to better understand the factors influencing their ability to adsorb mercury from fuel gas. Both a temperature effect and a dispersion effect were found. Maximum adsorption of Hg occurred at the -lowest temperature tested, 204°C, and decreased with increasing temperatures. Maximum adsorption of Hg on a per-atom basis of Pd is observed at low loadings of Pd ( < 8.5% Pd) due to better dispersion of Pd at those loadings; a change in its partitioning occurs at higher loadings. The presence of H2S 'in the fuel gas acts to promote the adsorption of Hg through its association with Hg in the Pd lattice.

  11. Surface characterization of Pd/Al2O3 sorbents for mercury capture from fuel gas

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Stanko, D.C.; Pennline, H.W.

    2008-09-01T23:59:59.000Z

    The surface composition of a series of Pd/alumina sorbents has been characterized to better understand the factors influencing their ability to adsorb mercury from fuel gas. Both a temperature effect and a dispersion effect were found. Maximum adsorption of Hg occurred at the lowest temperature tested, 2048C, and decreased with increasing temperatures. Maximum adsorption of Hg on a per-atom basis of Pd is observed at low loadings of Pd (58.5% Pd) due to better dispersion of Pd at those loadings; a change in its partitioning occurs at higher loadings. The presence of H2S in the fuel gas acts to promote the adsorption of Hg through its association with Hg in the Pd lattice.

  12. EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Palo, Daniel; Srinivasachar, Srivats; Laudal, Daniel

    2014-12-01T23:59:59.000Z

    Under contract DE-FE0007603, the University of North Dakota conducted the project Evaluation of Carbon Dioxide Capture from Existing Coal Fired Plants by Hybrid Sorption Using Solid Sorbents. As an important element of this effort, an Environmental Health and Safety (EH&S) Assessment was conducted by Barr Engineering Co. (Barr) in association with the University of North Dakota. The assessment addressed air and particulate emissions as well as solid and liquid waste streams. The magnitude of the emissions and waste streams was estimated for evaluation purposes. EH&S characteristics of materials used in the system are also described. This document contains data based on the mass balances from both the 40 kJ/mol CO2 and 80 kJ/mol CO2 desorption energy cases evaluated in the Final Technical and Economic Feasibility study also conducted by Barr Engineering.

  13. Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants

    SciTech Connect (OSTI)

    M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

    2003-12-31T23:59:59.000Z

    This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

  14. Spent fuel drying system test results (first dry-run)

    SciTech Connect (OSTI)

    Klinger, G.S.; Oliver, B.M.; Abrefah, J.; Marschman, S.C.; MacFarlan, P.J.; Ritter, G.A.

    1998-07-01T23:59:59.000Z

    The water-filled K-Basins in the Hanford 100 Area have been used to store N-Reactor spent nuclear fuel (SNF) since the 1970s. Because some leaks in the basin have been detected and some of the fuel is breached due to handling damage and corrosion, efforts are underway to remove the fuel elements from wet storage. An Integrated Process Strategy (IPS) has been developed to package, dry, transport, and store these metallic uranium fuel elements in an interim storage facility on the Hanford Site. Information required to support the development of the drying processes, and the required safety analyses, is being obtained from characterization tests conducted on fuel elements removed from the K-Basins. A series of whole element drying tests (reported in separate documents, see Section 7.0) have been conducted by Pacific Northwest National Laboratory (PNNL) on several intact and damaged fuel elements recovered from both the K-East and K-West Basins. This report documents the results of the first dry-run test, which was conducted without a fuel element. The empty test apparatus was subjected to a combination of low- and high-temperature vacuum drying treatments that were intended to mimic, wherever possible, the fuel treatment strategies of the IPS. The data from this dry-run test can serve as a baseline for the first two fuel element tests, 1990 (Run 1) and 3128W (Run 2). The purpose of this dry-run was to establish the background levels of hydrogen in the system, and the hydrogen generation and release characteristics attributable to the test system without a fuel element present. This test also serves to establish the background levels of water in the system and the water release characteristics. The system used for the drying test series was the Whole Element Furnace Testing System, described in Section 2.0, which is located in the Postirradiation Testing Laboratory (PTL, 327 Building). The test conditions and methodology are given in section 3.0, and the experimental results provided in Section 4.0. These results are further discussed in Section 5.0.

  15. PRELIMINARY CARBON DIOXIDE CAPTURE TECHNICAL AND ECONOMIC FEASIBILITY STUDY EVALUATION OF CARBON DIOXIDE CAPTURE FROM EXISTING COAL FIRED PLANTS BY HYBRID SORPTION USING SOLID SORBENTS

    SciTech Connect (OSTI)

    Benson, Steven; Envergex, Srivats; Browers, Bruce; Thumbi, Charles

    2013-01-01T23:59:59.000Z

    Barr Engineering Co. was retained by the Institute for Energy Studies (IES) at University of North Dakota (UND) to conduct a technical and economic feasibility analysis of an innovative hybrid sorbent technology (CACHYS™) for carbon dioxide (CO2) capture and separation from coal combustion–derived flue gas. The project team for this effort consists of the University of North Dakota, Envergex LLC, Barr Engineering Co., and Solex Thermal Science, along with industrial support from Allete, BNI Coal, SaskPower, and the North Dakota Lignite Energy Council. An initial economic and feasibility study of the CACHYS™ concept, including definition of the process, development of process flow diagrams (PFDs), material and energy balances, equipment selection, sizing and costing, and estimation of overall capital and operating costs, is performed by Barr with information provided by UND and Envergex. The technology—Capture from Existing Coal-Fired Plants by Hybrid Sorption Using Solid Sorbents Capture (CACHYS™)—is a novel solid sorbent technology based on the following ideas: reduction of energy for sorbent regeneration, utilization of novel process chemistry, contactor conditions that minimize sorbent-CO2 heat of reaction and promote fast CO2 capture, and a low-cost method of heat management. The technology’s other key component is the use of a low-cost sorbent.

  16. Polarized deuteron charge-exchange reaction $dp->{pp}_sN\\pi$ in the Delta-isobar region

    E-Print Network [OSTI]

    Uzikov, Yu N; Wilkin, C

    2015-01-01T23:59:59.000Z

    Mechanisms of the charge exchange reaction $dp\\to \\{pp\\}_{\\!s} N\\pi$, where $\\{pp\\}_{\\!s}$ is a two-proton system at low excitation energy, are studied at beam energies 1 -- 2 GeV and for invariant masses $M_X$ of the final $N\\pi $ system that correspond to the formation of the $\\Delta(1232)$ isobar. The direct mechanism, where the initial proton is excited into the $\\Delta(1232)$, dominates and explains the existing data on the unpolarized differential cross section and spherical tensor analyzing power $T_{22}$ for $M_X> 1.2$ GeV/$c^2$. However, this model fails to describe $T_{20}.

  17. Synthesis of Functionalized Superparamagnetic Iron Oxide Nanoparticles from a Common Precursor and their Application as Heavy Metal and Actinide Sorbents

    SciTech Connect (OSTI)

    Warner, Marvin G.; Warner, Cynthia L.; Addleman, Raymond S.; Droubay, Timothy C.; Engelhard, Mark H.; Davidson, Joseph D.; Cinson, Anthony D.; Nash, Michael A.; Yantasee, Wassana

    2009-10-12T23:59:59.000Z

    We describe the use of a simple and versatile technique to generate a series of ligand stabilized iron oxide nanoparticles containing different ? functionalities with specificities toward heavy metals and actinides at the periphery of the stabilizing ligand shell from a common, easy to synthesize precursor nanoparticle. The resulting nanoparticles are designed to contain affinity ligands that make them excellent sorbent materials for a variety of heavy metals from contaminated aqueous systems such as river water and ground water as well as actinides from clinical samples such as blood and urine. Functionalized superparamagnetic nanoparticles make ideal reagents for extraction of heavy metal and actinide contaminants from environmental and clinical samples since they are easily removed from the media once bound to the contaminant by simply applying a magnetic field. In addition, these engineered nanomaterials have an inherently high active surface area (often > 100 m2/g) making them ideal sorbent materials for these types of applications

  18. Brominated Sorbents for Small Cold-Side ESPs, Hot-Side ESPs and Fly Ash Use in Concrete

    SciTech Connect (OSTI)

    Ronald Landreth

    2008-06-30T23:59:59.000Z

    This report summarizes the work conducted from September 16, 2005 through December 31, 2008 on the project entitled �Brominated Sorbents for Small Cold-Side ESPs, Hot-Side ESPs and Fly Ash Use in Concrete�. The project covers testing at three host sites: Progress Energy H.F. Lee Station and the Midwest Generation Crawford and Will County Stations. At Progress Energy Lee 1, parametric tests were performed both with and without SO{sub 3} injection in order to determine the impact on the mercury sorbent performance. In addition, tests were performed on the hot-side of the air preheater, before the SO{sub 3} is injected, with H-PAC� sorbents designed for use at elevated temperatures. The BPAC� injection provided the expected mercury removal when the SO{sub 3} injection was off. A mercury removal rate due to sorbent of more than 80% was achieved at an injection rate of 8 lb/MMacf. The operation with SO{sub 3} injection greatly reduced the mercury sorbent performance. An important learning came from the injection of H-PAC� on the hot-side of the air preheater before the SO{sub 3} injection location. The H-PAC� injected in this manner appeared to be independent of the SO{sub 3} injection and provided better mercury removal than with injecting on the cold-side with SO{sub 3} injection. Consequently, one solution for plants like Lee, with SO{sub 3} injection, or plants with SO{sub 3} generated by the SCR catalyst, is to inject H-PAC� on the hot-side before the SO{sub 3} is in the flue gas. Even better performance is possible by injecting on the cold-side without the SO{sub 3}, however. During the parametric testing, it was discovered that the injection of B-PAC� (or H-PAC�) was having a positive impact upon ESP performance. It was decided to perform a 3-day continuous injection run with B-PAC� in order to determine whether Lee 1 could operate without SO{sub 3} injection. If the test proved positive, the continuous injection would continue as part of the long-term test. The injection of B-PAC� did allow for the operation of Lee 1 without SO{sub 3} injection and the long-term test was conducted from March 8 through April 7, 2006. The total mercury removal for the 30-day long-term test, excluding the first day when SO{sub 3} was injected and the last day when a plain PAC was used, averaged 85%. The achievement of 85% Hg removal over the 30 days longterm test is another milestone in the history of achievement of the Albemarle Environmental f/k/a Sorbent Technologies Corporation B-PAC� sorbent. A clear indication of the impact of B-PAC� on opacity came at the end of the long-term test. It was hoped that Lee 1 could be operated for several days after the end of the long-term test. It took less than a day before the opacity began to increase. The discovery that B-PAC� can improve ESP performance while capturing a large amount of mercury is another milestone for the B-PAC� mercury sorbent. The parametric testing at the Midwest Generation Crawford Station was divided into two phases; the first using C-PAC�, the concrete friendly sorbent, and the other using nonconcrete friendly materials. The first phase of the parametric tests was conducted before the long-term test. The second phase of the parametric testing was performed after the long-term test in order to avoid contaminating the fly ash containing the concrete friendly sorbents. The parametric test began with an injection rate of 1 lb/MMacf and, after a period to allow the mercury concentration to stabilize, the rate was increased to 3 lb/MMacf. The Hg removal for this test was about 60% due to sorbent and 69% total at the injection rate of 1 lb/MMacf and 80% due to sorbent and 84% total for the 3 lb/MMacf injection rate. The average total vapor phase mercury removal for the first 21 days of the long-term test was 82% at an injection rate o

  19. Characterization of mercury-enriched coal combustion residues from electric utilities using enhanced sorbents for mercury control

    SciTech Connect (OSTI)

    Sanchez, F.; Keeney, R.; Kosson, D.; Delapp, R. [Vanderbilt University, Nashville, TN (United States). Dept. of Civil and Environmental Engineering

    2006-02-15T23:59:59.000Z

    This report evaluates changes that may occur to coal-fired power plant air pollution control residues from the use of activated carbon and other enhanced sorbents for reducing air emissions of mercury and evaluates the potential for captured pollutants leaching during the disposal or use of these residues. Leaching of mercury, arsenic, and selenium during land disposal or beneficial use of coal combustion residues (CCRs) is the environmental impact pathway evaluated in this report. Coal combustion residues refer collectively to fly ash and other air pollution control solid residues generated during the combustion of coal collected through the associated air pollution control system. This research is part of an on-going effort by US Environmental protection Agency (EPA) to use a holistic approach to account for the fate of mercury and other metals in coal throughout the life-cycle stages of CCR management. This report focuses on facilities that use injected sorbents for mercury control. It includes four facilities with activated carbon injection (ACI) and two facilities using brominated ACI. Fly ash has been obtained from each facility with and without operation of the sorbent injection technology for mercury control. Each fly ash sampled was evaluated in the laboratory for leaching as a function of pH and liquid-to-solid ratio. Mercury, arsenic and selenium were the primary constituent of interest; results for these elements are presented here. 30 refs., 30 figs., 14 tabs., 10 apps.

  20. Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams

    SciTech Connect (OSTI)

    Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

    2013-10-01T23:59:59.000Z

    The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

  1. Comp Eng 2DP4 Microprocessor Systems Design Jan 2010 Instructor: Dr. D. Capson, P.Eng. Room: ITB-A111/A email: capson@mcmaster.ca

    E-Print Network [OSTI]

    Haykin, Simon

    Comp Eng 2DP4 Microprocessor Systems Design Jan 2010 Instructor: Dr. D. Capson, P.Eng. Room operational concepts and design methodology for modern microprocessor-based systems, to introduce software to Microprocessors Historical perspective on microprocessor evolution; Overview and comparison of microprocessor

  2. The Passivity and Breakdown of Beryllium in Aqueous Solutions M.A. Hill, D.P. Butt, and R.S. Lillard

    E-Print Network [OSTI]

    The Passivity and Breakdown of Beryllium in Aqueous Solutions M.A. Hill, D.P. Butt, and R beryllium (Be) has been studied as a function of pH. Below pH 2, Be exhibited active dissolution at all, the presence of the fluoride increased the passive current density of beryllium, but had no effect

  3. Corrosion of 304 Stainless Steel Exposed To Nitric Acid -Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson

    E-Print Network [OSTI]

    Corrosion of 304 Stainless Steel Exposed To Nitric Acid - Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson Materials Corrosion and Environmental Effects Laboratory Los AlamosCl, and temperature on the general corrosion behavior of 304 stainless steel (SS), electrochemical studies were

  4. Land application uses for dry FGD by-products. Phase 1, [Annual report], December 1, 1991--November 30, 1992

    SciTech Connect (OSTI)

    Bigham, J.; Dick, W.; Forster, L.; Hitzhusen, F.; McCoy, E.; Stehouwer, R.; Traina, S.; Wolfe, W. [Ohio State Univ., Columbus, OH (United States); Haefner, R. [Geological Survey, Columbus, OH (United States). Water Resources Div.

    1993-04-01T23:59:59.000Z

    The 1990 amendments to the Clean Air Act have spurred the development of flue gas desulfurization (FGD) processes, several of which produce a dry, solid by-product material consisting of excess sorbent, reaction products containing sulfates and sulfites, and coal fly ash. Presently FGD by-product materials are treated as solid wastes and must be landfilled. However, landfill sites are becoming more scarce and tipping fees are constantly increasing. It is, therefore, highly desirable to find beneficial reuses for these materials provided the environmental impacts are minimal and socially acceptable. Phase 1 results of a 4 and 1/2 year study to demonstrate large volume beneficial uses of FGD by-products are reported. The purpose of the Phase 1 portion of the project was to characterize the chemical, physical, mineralogical and engineering properties of the FGD by-product materials obtained from various FGD technologies being developed in the state of Ohio. Phase 1 also involved the collection of baseline economic data related to the beneficial reuse of these FGD materials. A total of 58 samples were collected and analyzed. In summary Phase 1 results revealed that FGD by-product materials are essentially coal fly ash materials diluted with unreacted sorbent and reaction products. High volume beneficial reuses will depend on the economics of their substituting for existing materials for various types of applications (e.g. as an agricultural liming material, soil borrow for highway embankment construction, and reclamation of active and abandoned surface coal mines). Environmental constraints to the beneficial reuse of dry FGD byproduct materials, based on laboratory and leachate studies, seem to be less than for coal fly ash.

  5. A Novel Theoretical Method to Search Good Candidates of Solid Sorbents for CO2 Capture

    SciTech Connect (OSTI)

    Duan, Yuhua

    2008-07-01T23:59:59.000Z

    The increasing atmospheric CO2 concentration is the most important environmental issue of global warming that the world faces today. During past few decades, many technologies have been developing to separate and capture CO2 from coal gasifier. As high temperature CO2 absorbents, solid materials are potential candidates. Lithium silicate(Li4SiO4) and zirconate(Li2ZrO3) have been studying for CO2 capture by researchers at Toshiba and found that they absorb CO2 at 773K and release CO2 around 973K. Based on these well-known experimental exploring results on these lithium salts, we have been developing a novel theoretical methodology to search better solid materials for CO2 capture: (1) Based on the crystal structures of solids, the density functional calculations are performed to obtain their electronic structural properties and their binding energies. The energy change(?E) for the reaction solid_sorbent+CO2 ? sorbent_CO2+ solid are evaluated. (2) For a vast of data-bank of solid materials, as our first filter if |?E|<|?GLi2SiO4|, where ?G is the free energy change for reaction of Li2SiO4+CO2? Li2CO3 +Li2SiO3, we select this solid as a potential good candidate for CO2 capture. (3) For these possible candidates, we further perform phonon calculations and obtain their vibration frequencies. With them, partition functions of solids(Z) can be calculated out. With Z, the thermal dynamical properties (zero point energy, entropy, enthalpy, free energy, etc.) under different conditions (temperature(T), pressure(P)) can be readily calculated. With them, the chemical potentials(??)(functional of T and P) for the sorption/desorption reaction are evaluated. (4) Using ?? as our second filter, we can reduce the number of our selected good candidates to a small number of better candidates. (5) The last step is to make the fine tune (the 3rd filter) the better candidates to a small set of the best candidates by considering the operating conditions(T, P, etc.), absorbing CO2 weight percentage, stabilities, and the associated costs, etc.

  6. Laboratory scale studies of Pd/y-Al2O3 sorbents for the removal of trace contaminents from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J.; Stanko, Dennis C.

    2010-12-31T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150-540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/{gamma}-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  7. Thermodynamic Properties of CO{sub 2} Capture Reaction by Solid Sorbents: Theoretical Predictions and Experimental Validations

    SciTech Connect (OSTI)

    Duan, Yuhua; Luebke, David; Pennline, Henry; Li, Liyu; King, David; Zhang; Keling; Zhao; Lifeng; Xiao, Yunhan

    2012-01-01T23:59:59.000Z

    It is generally accepted that current technologies for capturing CO{sub 2} are still too energy intensive. Hence, there is a critical need for development of new materials that can capture CO{sub 2} reversibly with acceptable energy costs. Accordingly, solid sorbents have been proposed to be used for CO{sub 2} capture applications through a reversible chemical transformation. By combining thermodynamic database mining with first principles density functional theory and phonon lattice dynamics calculations, a theoretical screening methodology to identify the most promising CO{sub 2} sorbent candidates from the vast array of possible solid materials has been proposed and validated. The calculated thermodynamic properties of different classes of solid materials versus temperature and pressure changes were further used to evaluate the equilibrium properties for the CO{sub 2} adsorption/desorption cycles. According to the requirements imposed by the pre- and post- combustion technologies and based on our calculated thermodynamic properties for the CO{sub 2} capture reactions by the solids of interest, we were able to screen only those solid materials for which lower capture energy costs are expected at the desired pressure and temperature conditions. These CO{sub 2} sorbent candidates were further considered for experimental validations. In this presentation, we first introduce our screening methodology with validating by solid dataset of alkali and alkaline metal oxides, hydroxides and bicarbonates which thermodynamic properties are available. Then, by studying a series of lithium silicates, we found that by increasing the Li{sub 2}O/SiO{sub 2} ratio in the lithium silicates their corresponding turnover temperatures for CO{sub 2} capture reactions can be increased. Compared to anhydrous K{sub 2}CO{sub 3}, the dehydrated K{sub 2}CO{sub 3}?1.5H{sub 2}O can only be applied for post-combustion CO{sub 2} capture technology at temperatures lower than its phase transition (to anhydrous phase) temperature, which depends on the CO{sub 2} pressure and the steam pressure with the best range being PH{sub 2}O?1.0 bar. Above the phase-transition temperature, the sorbent will be regenerated into anhydrous K{sub 2}CO{sub 3}. Our theoretical investigations on Na-promoted MgO sorbents revealed that the sorption process takes place through formation of the Na{sub 2}Mg(CO{sub 3}){sub 2} double carbonate with better reaction kinetics over porous MgO, that of pure MgO sorbent. The experimental sorption tests also indicated that the Na-promoted MgO sorbent has high reactivity and capacity towards CO{sub 2} sorption and can be easily regenerated either through pressure or temperature swing processes.

  8. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.N.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1996-12-31T23:59:59.000Z

    Toxic trace metallic elements such as arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, and selenium are usually contained in coal in various forms and trace amounts. These metals will either stay in the ash or be vaporized during high temperature combustion. Portions of the vaporized metals may eventually be emitted from a combustion system in the form of metal fumes or particulates with diameters less than 1 micron, which are potentially hazardous to the environment. Current practice of controlling trace metal emissions during coal combustion employs conventional air pollution control devices (APCDs), such as electrostatic precipitators and baghouses, to collect fly ash and metal fumes. The control may not always be effective on metal fumes due to their extremely fine sizes. This study is to explore the opportunities for improved control of toxic trace metal emissions from coal-fired combustion systems. Specifically, the technology proposed is to employ suitable sorbents to reduce the amount of metal volatilization and capture volatilized metal vapors during fluidized bed coal combustion. The objective of the study was to investigate experimentally and theoretically the metal capture process.

  9. Design and Development of New Carbon-Based Sorbent Systems for an Effective Containment of Hydrogen

    SciTech Connect (OSTI)

    Alan C. Cooper

    2012-05-03T23:59:59.000Z

    This is a summary for work performed under cooperative agreement DE FC36 04GO14006 (Design and Development of New Carbon-based Sorbent Systems for an Effective Containment of Hydrogen). The project was directed to discover new solid and liquid materials that use reversible catalytic hydrogenation as the mechanism for hydrogen capture and storage. After a short period of investigation of solid materials, the inherent advantages of storing and transporting hydrogen using liquid-phase materials focused our attention exclusively on organic liquid hydrogen carriers (liquid carriers). While liquid carriers such as decalin and methylcyclohexane were known in the literature, these carriers suffer from practical disadvantages such as the need for very high temperatures to release hydrogen from the carriers and difficult separation of the carriers from the hydrogen. In this project, we were successful in using the prediction of reaction thermodynamics to discover liquid carriers that operate at temperatures up to 150 C lower than the previously known carriers. The means for modifying the thermodynamics of liquid carriers involved the use of certain molecular structures and incorporation of elements other than carbon into the carrier structure. The temperature decrease due to the more favorable reaction thermodynamics results in less energy input to release hydrogen from the carriers. For the first time, the catalytic reaction required to release hydrogen from the carriers could be conducted with the carrier remaining in the liquid phase. This has the beneficial effect of providing a simple means to separate the hydrogen from the carrier.

  10. Demonstration of a hydration process for reactivating partially sulfated limestone sorbents

    SciTech Connect (OSTI)

    Smith, G.W.; Hajicek, D.R.; Myles, K.M.; Goblirsch, G.M.; Mowry, R.W.; Teats, F.G.

    1981-10-01T23:59:59.000Z

    The utilization of limestione sorbent for the removal of SO/sub 2/ in coal combustion in an atmospheric fluidized-bed combustor (AFBC) can be markedly increased by reactivating the partially sulfated limestone for reuse in the combustor. Such reuse would reduce costs and the environmental impact of quarrying and disposing of large quantities of limestone. The reactivation process consists of hydrating the partially sulfated limestone by treatment with water. A demonstration of the hydration process and the reuse of the reactivated limestone were carried out at Grand Forks Energy Technology Center (GFETC) in cooperation with Argonne National Laboratory (ANL). The data obtained in the GFETC 0.2-m/sup 2/ AFBC are compared with those obtained earlier in the ANL 0.02-m/sup 2/ AFBC. Marked enhancement of calcium utilization was achieved in both studies, but differences were noted in the degree of enhancement and in the Ca/S mole ratios required to maintain SO/sub 2/ in the off-gas at an acceptable level.

  11. Tyrosinase-containing chitosan gels: A combined catalyst and sorbent for selective phenol removal

    SciTech Connect (OSTI)

    Sun, W.Q.; Payne, G.F. [Univ. of Maryland, Baltimore, MD (United States)] [Univ. of Maryland, Baltimore, MD (United States)

    1996-07-05T23:59:59.000Z

    There are a series of examples in which phenols appear as contaminants in process streams and their selective removal is required for waste minimization. For the selective removal of a phenol from a mixture, the authors are exploiting the substrate specificity of the enzyme tyrosinase to convert phenols into reactive o-quinones which are then adsorbed onto the amine-containing polymer chitosan. To effectively package the enzyme and sorbent, tyrosinase was immobilized between two chitosan gel films. The entrapment of tyrosinase between the films led to little loss of activity during immobilization, while tyrosinase leakage during incubation was limited. The chitosan gels rapidly adsorb the tyrosinase-generated product(s) of phenol oxidation while the capacity of the gels is substantially greater than the capacity of chitosan flakes. The performance of tyrosinase-containing chitosan gels significantly depends on the ratio of tyrosinase-to-chitosan. High tyrosinase-to-chitosan ratios result in less efficient use of tyrosinase, presumably due to suicide inactivation. However, the efficiency of chitosan use increases with increased tyrosinase-to-chitosan ratios.

  12. The simulation of condensation removal of a heavy metal from exhaust gases onto sorbent particles

    SciTech Connect (OSTI)

    Rodriguez, A.; Hall, M.J

    2003-07-01T23:59:59.000Z

    A numerical model BAEROSOL for solving the general dynamic equation (GDE) of aerosols is presented. The goal was to model the capture of volatilized metals by sorbents under incinerator-like conditions. The model is based on algorithms presented by Jacobson and Turco [Aerosol Science and Technology 22 (1995) 73]. A hybrid size bin was used to model growth and formation of particles from the continuum phase and the coagulation of existing particles. Condensation and evaporation growth were calculated in a moving size bin approach, where coagulation and nucleation was modeled in the fixed size bin model of the hybrid grid. To account for the thermodynamic equilibrium in the gas phase, a thermodynamic equilibrium code CET89 was implemented. The particle size distribution (PSD) calculated with the model was then compared to analytical solutions provided for growth, coagulation and both combined. Finally, experimental findings by Rodriguez and Hall [Waste Management 21 (2001) 589-607] were compared to the PSD predicted by the developed model and the applicability of the model under incineration conditions is discussed.

  13. Nonlinear Dynamics of Dry Friction

    E-Print Network [OSTI]

    Franz-Josef Elmer

    1997-07-01T23:59:59.000Z

    The dynamical behavior caused by dry friction is studied for a spring-block system pulled with constant velocity over a surface. The dynamical consequences of a general type of phenomenological friction law (stick-time dependent static friction, velocity dependent kinetic friction) are investigated. Three types of motion are possible: Stick-slip motion, continuous sliding, and oscillations without sticking events. A rather complete discussion of local and global bifurcation scenarios of these attractors and their unstable counterparts is present.

  14. Drying and Storing Sorghum Grain.

    E-Print Network [OSTI]

    Hutchison, J. E.

    1959-01-01T23:59:59.000Z

    Drying and Storing Sorghum Grain W. S. ALLEN AND J. W. SORENSON. JR.* lead to insect. niold and heat damage in stored grain. They cause most of the problems encountered in storing grain. High moisture may result from leak- age of outside... moisture through hin walls or from placing high-moisture grain in storage. If the following recornrnendations and procedures are followed. sorghum grain can be stored safely. The! are based on research conducted at Beeville by the Texas Agricultural...

  15. Compton Dry-Cask Imaging System

    ScienceCinema (OSTI)

    None

    2013-05-28T23:59:59.000Z

    The Compton-Dry Cask Imaging Scanner is a system that verifies and documents the presence of spent nuclear fuel rods in dry-cask storage and determines their isotopic composition without moving or opening the cask. For more information about this project, visit http://www.inl.gov/rd100/2011/compton-dry-cask-imaging-system/

  16. Compton Dry-Cask Imaging System

    SciTech Connect (OSTI)

    None

    2011-01-01T23:59:59.000Z

    The Compton-Dry Cask Imaging Scanner is a system that verifies and documents the presence of spent nuclear fuel rods in dry-cask storage and determines their isotopic composition without moving or opening the cask. For more information about this project, visit http://www.inl.gov/rd100/2011/compton-dry-cask-imaging-system/

  17. Drying and Storing Cooperative Extension Service

    E-Print Network [OSTI]

    Mukhtar, Saqib

    . Sunflowers Joseph P. Harner Extension Agriculture Engineer The fire hazard is DECREASED when the fan can draw for attachment to the drying fan. Guidelines for drying sunflowers are: 1. 2. 3. 4. Use good housekeeping practices. Clean up around the dryer and in the plenum chamber daily. Do not over dry. Ensure continuous

  18. Dry Transfer Systems for Used Nuclear Fuel

    SciTech Connect (OSTI)

    Brett W. Carlsen; Michaele BradyRaap

    2012-05-01T23:59:59.000Z

    The potential need for a dry transfer system (DTS) to enable retrieval of used nuclear fuel (UNF) for inspection or repackaging will increase as the duration and quantity of fuel in dry storage increases. This report explores the uses for a DTS, identifies associated general functional requirements, and reviews existing and proposed systems that currently perform dry fuel transfers. The focus of this paper is on the need for a DTS to enable transfer of bare fuel assemblies. Dry transfer systems for UNF canisters are currently available and in use for transferring loaded canisters between the drying station and storage and transportation casks.

  19. Drying Fruits and Vegetables at Home.

    E-Print Network [OSTI]

    Putnam, Peggy H.

    1981-01-01T23:59:59.000Z

    that are responsible for their maturation, or their becoming ripe. These enzymes cause color and flavor changes, some of which may become more extensive when food surfaces are cut and exposed to air. The changes con tinue during drying and storage unless the enzyme... in recommendations for treatment before dry ing, for methods of drying, for temperatures and length of drying time, and for conditioning prior to storage. You may have to use the "trial and error" approach in finding out which drying technique works best for your...

  20. Microwave drying of ferric oxide pellets

    SciTech Connect (OSTI)

    Pickles, C.A.; Xia, D.K. [Queens` Univ., Kingston, Ontario (Canada). Dept. of Materials and Metallurgical Engineering

    1997-12-31T23:59:59.000Z

    The application of microwave energy for the drying of ferric oxide pellets has been investigated and evaluated. It is shown that the microwave drying rates are much higher than those observed in the conventional process. Also there is some potential for improved quality of the product. As a stand-alone technology it is unlikely that microwave drying would be economical for pellets due to the low cost of conventional fuels. However, based on an understanding of the drying mechanisms in the conventional process and in the microwave process, it is shown that microwave-assisted drying offers considerable potential. In this hybrid process, the advantages of the two drying techniques are combined to provide an improved drying process.

  1. Dry-cleaning of graphene

    SciTech Connect (OSTI)

    Algara-Siller, Gerardo [Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, Ulm University, Albert-Einstein-Allee 11, Ulm 89081 (Germany); Department of Chemistry, Technical University Ilmenau, Weimarer Strasse 25, Ilmenau 98693 (Germany); Lehtinen, Ossi; Kaiser, Ute, E-mail: ute.kaiser@uni-ulm.de [Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, Ulm University, Albert-Einstein-Allee 11, Ulm 89081 (Germany); Turchanin, Andrey [Faculty of Physics, University of Bielefeld, Universitätsstr. 25, Bielefeld 33615 (Germany)

    2014-04-14T23:59:59.000Z

    Studies of the structural and electronic properties of graphene in its pristine state are hindered by hydrocarbon contamination on the surfaces. Also, in many applications, contamination reduces the performance of graphene. Contamination is introduced during sample preparation and is adsorbed also directly from air. Here, we report on the development of a simple dry-cleaning method for producing large atomically clean areas in free-standing graphene. The cleanness of graphene is proven using aberration-corrected high-resolution transmission electron microscopy and electron spectroscopy.

  2. Vapor Transport in Dry Soils

    SciTech Connect (OSTI)

    Gee, Glendon W.; Ward, Anderson L.

    2001-11-16T23:59:59.000Z

    Water-vapor movement in soils is a complex process, controlled by both diffusion and advection and influenced by pressure and thermal gradients acting across tortuous flow paths. Wide-ranging interest in water-vapor transport includes both theoretical and practical aspects. Just how pressure and thermal gradients enhance water-vapor flow is still not completely understood and subject to ongoing research. Practical aspects include dryland farming (surface mulching), water harvesting (aerial wells), fertilizer placement, and migration of contaminants at waste-sites. The following article describes the processes and practical applications of water-vapor transport, with emphasis on unsaturated (dry) soil systems.

  3. Dry melting of high albite

    SciTech Connect (OSTI)

    Anovitz, L.M.: Blencoe, J.G.

    1999-12-01T23:59:59.000Z

    The properties of albitic melts are central to thermodynamic models for synthetic and natural granitic liquids. The authors have analyzed published phase-equilibrium and thermodynamic data for the dry fusion of high albite to develop a more accurate equation for the Biggs free energy of this reaction to 30 kbar and 1,400 C. Strict criteria for reaction reversal were sued to evaluate the phase-equilibrium data, and the thermodynamic properties of solid and liquid albite were evaluated using the published uncertainties in the original measurements. Results suggest that neither available phase-equilibrium experiments nor thermodynamic data tightly constrain the location of the reaction. Experimental solidus temperatures at 1 atm range from 1,100 to 1,120 C. High-pressure experiments were not reversed completely and may have been affected by several sources of error, but the apparent inconsistencies among the results of the various experimentalists are eliminated when only half-reversal data are considered. Uncertainties in thermodynamic data yield large variations in permissible reaction slopes. Disparities between experimental and calculated melting curves are, therefore, largely attributable to these difficulties, and there is no fundamental disagreement between the available phase-equilibrium and thermodynamic data for the dry melting of albite. Consequently, complex speciation models for albitic melts, based on the assumption that these discrepancies represent a real characteristic of the system, are unjustified at this time.

  4. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  5. CarlsonDP.PDF

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTubahq.na.gov Office of theNuclear Security Administration Tracy

  6. Freeze-drying bovine spermatozoa

    E-Print Network [OSTI]

    Faris, Harvey Lee

    1965-01-01T23:59:59.000Z

    ~~to t~ roi'ipxg QQ ca dry ai gjuu QQjQigog aud ta Qst~~co cho ~~grso Qg 86lhVdratiea KXpkos Q~Kd Wlthstsud?. V~4MK Qhaersat9ZBE3 Vora used apprs~w~~~ a%oct@ a8 virious uaistma Eoroko as assess hot~& driad. OC WQQ QVBSd Chat horaous gQ Sud 2' hours...KK Hmm 'tiaao ZXZ"d. XnCEICno ~. ?n~ cpa~ Vms::Hach. . UIadpicoKdSq. X6, ESP& S&~o~c. L947, Tha Eccaaacii"cLBCII @IE HacCai. 'La Ljy Uqrlaj. ':. J? QvaacaL EELaoabiaKagyp X. " HSR;. K7p EESCKQ~~UZp g. 8 X956. ParCELU HaIILaa Saciemi HHCaC THicaa...

  7. LONG-TERM STABILITY TESTING RESULTS USING SURROGATES AND SORBENTS FOR SAVANNAH RIVER SITE ORGANIC AND AQUEOUS WASTESTREAMS - 10016

    SciTech Connect (OSTI)

    Burns, H.

    2009-11-10T23:59:59.000Z

    The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating the long-term stability of various commercially available sorbent materials to solidify two organic surrogate wastestreams (both volatile and nonvolatile), a volatile organic surrogate with a residual aqueous phase, an aqueous surrogate, and an aqueous surrogate with a residual organic phase. The Savannah River Site (SRS) Legacy and F-Canyon plutonium/uranium extraction (PUREX) process waste surrogates constituted the volatile organic surrogates, and various oils constituted the nonvolatile organic surrogates. The aqueous surrogates included a rainwater surrogate and an aqueous organic surrogate. MSE also evaluated the PUREX surrogate with a residual aqueous component with and without aqueous type sorbent materials. Solidification of the various surrogate wastestreams listed above was performed from 2004 to 2006 at the MSE Test Facility located in Butte, Montana. This paper summarizes the comparison of the initial liquid release test (LRT) values with LRT results obtained during subsequent sampling events in an attempt to understand and define the long-term stability characteristics for the solidified wastestreams.

  8. Adsorption Isotherms for Xenon and Krypton using INL HZ-PAN and AgZ-PAN Sorbents

    SciTech Connect (OSTI)

    Troy G. Garn; Mitchell Greenhalgh; Veronica J. Rutledge; Jack D. Law

    2014-08-01T23:59:59.000Z

    The generation of adsorption isotherms compliments the scale-up of off-gas processes used to control the emission of encapsulated radioactive volatile fission and activation products released during Used Nuclear Fuel (UNF) reprocessing activities. A series of experiments were conducted to obtain capacity results for varying Kr and Xe gas concentrations using HZ-PAN and AgZ-PAN engineered form sorbents. Gas compositions for Kr ranged from 150-40,000 ppmv and 250-5020 ppmv for Xe in a helium balance. The experiments were all performed at 220 K at a flowrate of 50 sccm. Acquired capacities were then respectively fit to the Langmuir equation using the Langmuir linear regression method to obtain the equilibrium parameters Qmax and Keq. Generated experimental adsorption isotherms were then plotted with the Langmuir predicted isotherms to illustrate agreement between the two. The Langmuir parameters were provided for input into the OSPREY model to predict breakthrough of single component adsorption of Kr and Xe on HZ-PAN and AgZ-PAN sorbents at the experimental conditions tested. Kr and Xe capacities resulting from model breakthrough predictions were then compared to experimental capacities for model validation.

  9. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1997-01-01T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  10. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1997-12-30T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  11. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1999-02-02T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  12. Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1999-01-01T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  13. Wet/dry cooling tower and method

    DOE Patents [OSTI]

    Glicksman, Leon R. (Lynnfield, MA); Rohsenow, Warren R. (Waban, MA)

    1981-01-01T23:59:59.000Z

    A wet/dry cooling tower wherein a liquid to-be-cooled is flowed along channels of a corrugated open surface or the like, which surface is swept by cooling air. The amount of the surface covered by the liquid is kept small compared to the dry part thereof so that said dry part acts as a fin for the wet part for heat dissipation.

  14. Using and Storing Nonfat Dry Milk Nonfat dry milk is convenient to store, easy to use and

    E-Print Network [OSTI]

    in a cool, dry place. s Dry milk products are very sensitive to temperature and humidity. The area where your dry milk is stored should be kept as cool as possible. s Dry milk will absorb moisture and odorsUsing and Storing Nonfat Dry Milk Nonfat dry milk is convenient to store, easy to use

  15. A new class of non-zeolitic sorbents for air separations: Lithium ion exchanged pillared clays

    SciTech Connect (OSTI)

    Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States). Dept. of Chemical Engineering

    1995-06-01T23:59:59.000Z

    Zeolites are the only known sorbents that adsorb N{sub 2} selectively over O{sub 2}, and are used for industrial air separation. Pillared clays (PILCs) have a high Broensted acidity (k.e., high proton density). It is found in this study that when the protons are exchanged by alkali metal ions, in particular Li{sup +}, the ion exchanged pillared clays can exhibit a high N{sub 2}/O{sub 2} adsorption selectivity that rivals that of the zeolites. The first result shows a pure-component adsorption ratio of N{sub 2}/O{sub 2} = 3.2 (at 25 C and 1 atm) for Li{sup +}-exchanged PILC. The N{sub 2} capacity, however, is only 20% that of the zeolite, and remains to be improved. A systematic investigation is conducted on the effects of three factors on the N{sub 2}/O{sub 2} selectivity: (1) starting clays (tetrahedral vs octahedral isomorphous substitution and clays with different charge densities), (2) different metal oxides as pillars, and (3) different ion exchange alkali metal cations (Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, and Cs{sup +}). The highest N{sub 2}/O{sub 2} selectivities are achieved by using clays with the highest charge densities, metal oxides forming pillars with the narrowest gallery spaces, and ion exchange cations with the smallest ionic radii. Effects by all three factors are qualitatively understood. The high N{sub 2}/O{sub 2} selectivity on the Li{sup +} exchanged PILC is the result of the small ionic radius (and hence high polarizing power) of Li{sup +} and the strong quadrupole moment of the N{sub 2} molecule. Moreover, a technique is developed with which the amount of the exchanged cations can exceed that allowed by the original cation exchange capacity of the clay by using a high pH value in the ion exchange solution.

  16. Cold vacuum drying system conceptual design report

    SciTech Connect (OSTI)

    Bradshaw, F.W.

    1996-05-01T23:59:59.000Z

    This document summarizes the activities involved in the removal of the SNF from the leaking basins and to place it in stable dry storage.

  17. FINAL REPORT: Transformational electrode drying process

    SciTech Connect (OSTI)

    Claus Daniel, C.; Wixom, M. (A123 Systems, Inc.)

    2013-12-19T23:59:59.000Z

    This report includes major findings and outlook from the transformational electrode drying project performance period from January 6, 2012 to August 1, 2012. Electrode drying before cell assembly is an operational bottleneck in battery manufacturing due to long drying times and batch processing. Water taken up during shipment and other manufacturing steps needs to be removed before final battery assembly. Conventional vacuum ovens are limited in drying speed due to a temperature threshold needed to avoid damaging polymer components in the composite electrode. Roll to roll operation and alternative treatments can increase the water desorption and removal rate without overheating and damaging other components in the composite electrode, thus considerably reducing drying time and energy use. The objective of this project was the development of an electrode drying procedure, and the demonstration of processes with no decrease in battery performance. The benchmark for all drying data was an 80°C vacuum furnace treatment with a residence time of 18 – 22 hours. This report demonstrates an alternative roll to roll drying process with a 500-fold improvement in drying time down to 2 minutes and consumption of only 30% of the energy compared to vacuum furnace treatment.

  18. Cold vacuum drying facility design requirements

    SciTech Connect (OSTI)

    IRWIN, J.J.

    1999-07-01T23:59:59.000Z

    This document provides the detailed design requirements for the Spent Nuclear Fuel Project Cold Vacuum Drying Facility. Process, safety, and quality assurance requirements and interfaces are specified.

  19. Cooking with Non-fat Dry Milk

    E-Print Network [OSTI]

    Anding, Jenna

    2008-12-09T23:59:59.000Z

    This fact sheet describes the nutritional value and safe storage of non-fat dry milk, a commodity food. It also offers food preparation ideas....

  20. Precipitation scavenging, dry deposition, and resuspension. Volume 2: dry deposition and resuspension

    SciTech Connect (OSTI)

    Pruppacher, H.R.; Semanin, R.G.; Slinn, W.G.N.

    1983-01-01T23:59:59.000Z

    Papers are presented under the headings: dry deposition of gases, dry deposition of particles, wind erosion, plutonium deposition and resuspension, air-sea exchange, tropical and polar, global scale, and future studies.

  1. An experimental investigation of high temperature, high pressure paper drying

    E-Print Network [OSTI]

    Patel, Kamal Raoji

    1994-01-01T23:59:59.000Z

    % moisture removed oven dried mass of handsheet, g mass of handsheet after drying test, g mass of handsheet before drying test, g relative moisture removed from handsheet moisture removed by drying, % initial moisture (im) initial handsheet sample mass..., and the effects on the paper sheet and drying felt can be detrimental. Elevated temperatures reduce water viscosity which permits reduced resistance to water flow in the sheet. Pressing with a drying temperature of 95 C gives increased drying capacity, reduced...

  2. Infrared Dry-peeling Technology for Tomatoes

    E-Print Network [OSTI]

    Infrared Dry-peeling Technology for Tomatoes Saves Energy Energy Efficiency Research Office PIER This research will use infrared heating technology for peeling tomatoes. Infrared dry peeling, a device, producing less wastewater and preserving product quality. Infrared drypeeling is expected to reduce

  3. Cooking and Using Dried Beans and Peas

    E-Print Network [OSTI]

    Cooking and Using Dried Beans and Peas Beans and peas are good for you Beans and peas beans with rice or corn to provide high quality complete protein. If you are on a special diet, remember that beans and peas are low in sodium and fat. How to store dried beans and peas Store beans and peas

  4. Growing Dry Beans for an Emerging Market

    E-Print Network [OSTI]

    Hayden, Nancy J.

    Growing Dry Beans for an Emerging Market JOIN US FOR AN EVENING WITH JACK LAZOR, OF BUTTERWORKS FARM AND JOE BOSSEN, OF VERMONT BEAN CRAFTERS APRIL 10TH , 2012, 6:15-8PM AT THE KELLOGG-HUBBARD LIBRARY EAST MONTPELIER ROOM 135 MAIN ST., MONTPELIER, VT 05602 Jack Lazor has grown dry beans for local

  5. Inspection of Used Fuel Dry Storage Casks

    SciTech Connect (OSTI)

    Dennis C. Kunerth; Tim McJunkin; Mark McKay; Sasan Bakhtiari

    2012-09-01T23:59:59.000Z

    ABSTRACT The U.S. Nuclear Regulatory Commission (NRC) regulates the storage of used nuclear fuel, which is now and will be increasingly placed in dry storage systems. Since a final disposition pathway is not defined, the fuel is expected to be maintained in dry storage well beyond the time frame originally intended. Due to knowledge gaps regarding the viability of current dry storage systems for long term use, efforts are underway to acquire the technical knowledge and tools required to understand the issues and verify the integrity of the dry storage system components. This report summarizes the initial efforts performed by researchers at Idaho National Laboratory and Argonne National Laboratory to identify and evaluate approaches to in-situ inspection dry storage casks. This task is complicated by the design of the current storage systems that severely restrict access to the casks.

  6. Investigation of combined SO{sub 2}/NO{sub x} removal by ceria sorbents. Quarterly technical progress report, January 1995--March 1995

    SciTech Connect (OSTI)

    Akyurtlu, A.; Akyurtlu, J.F.

    1995-04-01T23:59:59.000Z

    Simultaneous removal of SO{sub 2} and NO{sub x}using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. Recent studies at PETC considered cerium oxide as an alternate sorbent to CuO. The present study aims to determine the effects of ammonia on the sulfation of the sorbent and to obtain a rate expression for the regeneration of alumina-supported CeO{sub 2} sorbents. The sulfation experiments indicated that 100 % conversion of ceria can be attained. Activation energy for the sulfation reaction was found to be 19 kJ/mol. The rate of sulfation reaction is first order with respect to SO{sub 2} and solid reactant concentrations. For regeneration with hydrogen, the activation energy and the reaction order with respect to hydrogen was found to be 114 kJ/mol and 0.56, respectively. The ceria sorbent preserved its activity and structural stability after 6 cycles. In the last quarter regeneration with methane was studied. Since regeneration with methane is more complicated than regeneration with hydrogen, the evaluation of data needs the development of new methods. The information obtained from these studies will be used to develop models for reactor-regenerator configurations. Subsequently, the SO{sub 2}/NO{sub x} removal facility will be integrated into the power production process using a commercial process simulation software.

  7. Development of advanced, dry, SO{sub x}/NO{sub x} emission control technologies for high-sulfur coal. Final report, April 1, 1993--December 31, 1994

    SciTech Connect (OSTI)

    Amrhein, G.T.

    1994-12-23T23:59:59.000Z

    Dry Scrubbing is a common commercial process that has been limited to low- and medium-sulfur coal applications because high-sulfur coal requires more reagent than can be efficiently injected into the process. Babcock & Wilcox has made several advances that extend dry scrubbing technologies to higher sulfur coals by allowing deposit-free operation at low scrubber exit temperatures. This not only increases the amount of reagent that can be injected into the scrubber, but also increases SO{sub 2} removal efficiency and sorbent utilization. The objectives of this project were to demonstrate, at pilot scale, that advanced, dry-scrubbing-based technologies can attain the performance levels specified by the 1990 Clean Air Act Amendments for SO{sub 2} and NO{sub x} emissions while burning high-sulfur coal, and that these technologies are economically competitive with wet scrubber systems. The use of these technologies by utilities in and around Ohio, on new or retrofit applications, will ensure the future of markets for high-sulfur coal by creating cost effective options to coal switching.

  8. TAILORING INORGANIC SORBENTS FOR SRS STRONTIUM AND ACTINIDE SEPARATIONS: OPTIMIZED MONOSODIUM TITANATE PHASE II FINAL REPORT

    SciTech Connect (OSTI)

    Hobbs, D; Thomas Peters, T; Michael Poirier, M; Mark Barnes, M; Major Thompson, M; Samuel Fink, S

    2007-06-29T23:59:59.000Z

    This document provides a final report of Phase II testing activities for the development of a modified monosodium titanate (MST) that exhibits improved strontium and actinide removal characteristics compared to the baseline MST material. The activities included determining the key synthesis conditions for preparation of the modified MST, preparation of the modified MST at a larger scale by a commercial vendor, demonstration of the strontium and actinide removal characteristics with actual tank waste supernate and measurement of filtration characteristics. Key findings and conclusions include the following. Testing evaluated three synthetic methods and eleven process parameters for the optimum synthesis conditions for the preparation on an improved form of MST. We selected the post synthesis method (Method 3) for continued development based on overall sorbate removal performance. We successfully prepared three batches of the modified MST using Method 3 procedure at a 25-gram scale. The laboratory prepared modified MST exhibited increased sorption kinetics with simulated and actual waste solutions and similar filtration characteristics to the baseline MST. Characterization of the modified MST indicated that the post synthesis treatment did not significantly alter the particle size distribution, but did significantly increase the surface area and porosity compared to the original MST. Testing indicated that the modified MST exhibits reduced affinity for uranium compared to the baseline MST, reducing risk of fissile loading. Shelf-life testing indicated no change in strontium and actinide performance removal after storing the modified MST for 12-months at ambient laboratory temperature. The material releases oxygen during the synthesis and continues to offgas after the synthesis at a rapidly diminishing rate until below a measurable rate after 4 months. Optima Chemical Group LLC prepared a 15-kilogram batch of the modified MST using the post synthesis procedure (Method 3). Performance testing with simulated and actual waste solutions indicated that the material performs as well as or better than batches of modified MST prepared at the laboratory-scale. Particle size data of the vendor-prepared modified MST indicates a broader distribution centered at a larger particle size and microscopy shows more irregular particle morphology compared to the baseline MST and laboratory prepared modified MST. Stirred-cell (i.e., dead-end) filter testing revealed similar filtration rates relative to the baseline MST for both the laboratory and vendor-prepared modified MST materials. Crossflow filtration testing indicated that with MST-only slurries, the baseline MST produced between 30-100% higher flux than the vendor-prepared modified MST at lower solids loadings and comparable flux at higher solids loadings. With sludge-MST slurries, the modified MST produced 1.5-2.2 times higher flux than the baseline MST at all solids loadings. Based on these findings we conclude that the modified MST represents a much improved sorbent for the separation of strontium and actinides from alkaline waste solutions and recommend continued development of the material as a replacement for the baseline MST for waste treatment facilities at the Savannah River Site.

  9. Hot Dry Rock; Geothermal Energy

    SciTech Connect (OSTI)

    None

    1990-01-01T23:59:59.000Z

    The commercial utilization of geothermal energy forms the basis of the largest renewable energy industry in the world. More than 5000 Mw of electrical power are currently in production from approximately 210 plants and 10 000 Mw thermal are used in direct use processes. The majority of these systems are located in the well defined geothermal generally associated with crustal plate boundaries or hot spots. The essential requirements of high subsurface temperature with huge volumes of exploitable fluids, coupled to environmental and market factors, limit the choice of suitable sites significantly. The Hot Dry Rock (HDR) concept at any depth originally offered a dream of unlimited expansion for the geothermal industry by relaxing the location constraints by drilling deep enough to reach adequate temperatures. Now, after 20 years intensive work by international teams and expenditures of more than $250 million, it is vital to review the position of HDR in relation to the established geothermal industry. The HDR resource is merely a body of rock at elevated temperatures with insufficient fluids in place to enable the heat to be extracted without the need for injection wells. All of the major field experiments in HDR have shown that the natural fracture systems form the heat transfer surfaces and that it is these fractures that must be for geothermal systems producing from naturally fractured formations provide a basis for directing the forthcoming but, equally, they require accepting significant location constraints on HDR for the time being. This paper presents a model HDR system designed for commercial operations in the UK and uses production data from hydrothermal systems in Japan and the USA to demonstrate the reservoir performance requirements for viable operations. It is shown that these characteristics are not likely to be achieved in host rocks without stimulation processes. However, the long term goal of artificial geothermal systems developed by systematic engineering procedures at depth may still be attained if high temperature sites with extensive fracturing are developed or exploited. [DJE -2005

  10. Dynamic modeling and transient studies of a solid-sorbent adsorber for CO{sub 2} capture

    SciTech Connect (OSTI)

    Modekurti, Srinivasarao [WVU; Bhattacharyya, Debangsu [WVU; Zitney, Stephen E. [U.S. DOE

    2012-01-01T23:59:59.000Z

    The U.S. Department of Energy’s Carbon Capture Simulation Initiative (CCSI) is dedicated to accelerating the commercialization of carbon capture technologies from discovery to development, demonstration, and ultimately the widespread deployment to hundreds of power plants. In this multi-lab initiative in partnership with academic and industrial institutions, the National Energy Technology Laboratory (NETL) leads the development of a multi-scale modeling and simulation toolset for rapid evaluation and deployment of carbon capture systems. One element of the CCSI is focused on optimizing the operation and control of carbon capture systems since this can have a significant impact on the extent and the rate at which commercial-scale capture processes will be scaled-up, deployed, and used in the years to come. Capture processes must be capable of operating over a wide range of transient events, malfunctions, and disturbances, as well as under uncertainties. As part of this work, dynamic simulation and control models, methods, and tools are being developed for CO{sub 2} capture and compression processes and their integration with a baseline commercial-scale supercritical pulverized coal (SCPC) power plant. Solid-sorbent-based post-combustion capture technology was chosen as the first industry challenge problem for CCSI because significant work remains to define and optimize the reactors and processes needed for successful sorbent capture systems. Sorbents offer an advantage because they can reduce the regeneration energy associated with CO{sub 2} capture, thus reducing the parasitic load. In view of this, the current paper focuses on development of a dynamic model of a solid-sorbent CO{sub 2} adsorber-reactor and an analysis of its transient performance with respect to several typical process disturbances. A one-dimensional, non-isothermal, pressure-driven dynamic model of a two-stage bubbling fluidized bed (BFB) adsorber-reactor is developed in Aspen Custom Modeler (ACM). The BFB stages are of overflow-type configuration where the solids leave the stage by flowing over the overflow-weir. Each bed is divided into three regions, namely emulsion, bubble, and cloud-wake regions. In all three regions, the model considers mass and energy balances. Along with the models of the BFB stages, models of other associated hardware are developed and integrated in a single flowsheet. A valid pressure-flow network is developed and a lower-level control system is designed so that the overall CO{sub 2} capture can be maintained at a desired level in face of the typical disturbances. The dynamic model is used for studying the transient responses of a number of important process variables as a result of the disturbances that are typical of post-combustion CO{sub 2} capture processes.

  11. Acoustically enhanced heat exchange and drying apparatus

    DOE Patents [OSTI]

    Bramlette, T.T.; Keller, J.O.

    1987-07-10T23:59:59.000Z

    A heat transfer drying apparatus includes an acoustically augmented heat transfer chamber for receiving material to be dried. The chamber includes a first heat transfer gas inlet, a second heat transfer gas inlet, a material inlet, and a gas outlet which also serves as a dried material and gas outlet. A non-pulsing first heat transfer gas source provides a first drying gas to the acoustically augmented heat transfer chamber through the first heat transfer gas inlet. A valveless, continuous second heat transfer gas source provides a second drying gas to the acoustically augmented heat transfer chamber through the second heat transfer gas inlet. The second drying gas also generates acoustic waves which bring about acoustical coupling with the gases in the acoustically augmented heat transfer chamber. The second drying gas itself oscillates at an acoustic frequency of approximately 180 Hz due to fluid mechanical motion in the gas. The oscillations of the second heat transfer gas coupled to the first heat transfer gas in the acoustically augmented heat transfer chamber enhance heat and mass transfer by convection within the chamber. 3 figs.

  12. Development of impregnated sorbents for the control of elemental mercury emissions from coal-fired power plants

    SciTech Connect (OSTI)

    Vidic, R.D.; Kwon, S.J.; Siler, D.P.

    1999-07-01T23:59:59.000Z

    Sulfur-impregnated activated carbon developed in the laboratory showed superior performance for mercury uptake in comparison to other potential sorbents. The objective of this study was to evaluate whether a different sulfur impregnation protocol using hydrogen sulfide as a sulfur source can produce an equally effective mercury sorbent. In addition, several other impregnates (copper chloride, anthraquinone, picolyl amine, and thiol) were evaluated for their ability to enhance adsorptive capacity of virgin activated carbon for elemental mercury. The effect of sulfur impregnation method on mercury removal efficiency was examined using impregnation with elemental sulfur (BPLS) at high temperature and hydrogen sulfide oxidation (BPLH-series) at low impregnation temperature. The performance of both BPLS and BPLH-series increased significantly over the virgin BPL carbon. BPL impregnated for 0.25 hr (BPLH-0.25) showed best performance for mercury adsorption. Although BPLS and BPLH-0.25 had similar sulfur content, BPLS showed much better performance. The dynamic adsorption capacity of BPL carbon impregnated with copper chloride (BPLC) was found to increase with an increase in empty bed contact time and chloride content and to decrease with an increase in process temperature. All chloride impregnated activated carbons exhibited appreciable initial mercury breakthrough due to slow kinetics of mercury uptake, while substantial concentrations of oxidized mercury species were detected in the effluent from a fixed-bed adsorber. The BPL impregnated with anthraquinone and thiol exhibited high dynamic adsorption capacities at 25 C, but had much lower dynamic adsorption capacities at 140 C. BPL impregnated with picolyl amine (BPLP) exhibited very poor dynamic adsorption capacities at both 25 and 140 C. The chelating agent-impregnated carbons exhibited lower dynamic adsorption capacities than BPLS.

  13. Sub-Nyquist Field Trial Using Time Frequency Packed DP-QPSK Super-Channel Within Fixed ITU-T Grid

    E-Print Network [OSTI]

    Potě, L; Berrettini, G; Fresi, F; Foggi, T; Secondini, M; Giorgi, L; Cavaliere, F; Hackett, S; Petronio, A; Nibbs, P; Forgan, R; Leong, A; Masciulli, R; Pfander, C

    2015-01-01T23:59:59.000Z

    Sub-Nyquist time frequency packing technique was demonstrated for the first time in a super channel field trial transmission over long-haul distances. The technique allows a limited spectral occupancy even with low order modulation formats. The transmission was successfully performed on a deployed Australian link between Sydney and Melbourne which included 995 km of uncompensated SMF with coexistent traffic. 40 and 100 Gb/s co-propagating channels were transmitted together with the super-channel in a 50 GHz ITU-T grid without additional penalty. The super-channel consisted of eight sub-channels with low-level modulation format, i.e. DP-QPSK, guaranteeing better OSNR robustness and reduced complexity with respect to higher order formats. At the receiver side, coherent detection was used together with iterative maximum-a-posteriori (MAP) detection and decoding. A 975 Gb/s DP-QPSK super-channel was successfully transmitted between Sydney and Melbourne within four 50GHz WSS channels (200 GHz). A maximum potential...

  14. Advanced wet-dry cooling tower concept

    E-Print Network [OSTI]

    Snyder, Troxell Kimmel

    The purpose of this years' work has been to test and analyze the new dry cooling tower surface previously developed. The model heat transfer test apparatus built last year has been instrumented for temperature, humidity ...

  15. Cold vacuum drying facility design requirements

    SciTech Connect (OSTI)

    Irwin, J.J.

    1997-09-24T23:59:59.000Z

    This release of the Design Requirements Document is a complete restructuring and rewrite to the document previously prepared and released for project W-441 to record the design basis for the design of the Cold Vacuum Drying Facility.

  16. Dry cooling: Perspectives on future needs

    SciTech Connect (OSTI)

    Guyer, E.C. (Yankee Scientific, Inc., Ashland, MA (United States))

    1991-08-01T23:59:59.000Z

    The factors that can be expected to determine the future role of dry cooling in the United States electric power generation industry are identified and characterized. Focus is primarily on the issues of water availability for the electric power industry and the environmental impacts of evaporative cooling systems. The question of future water availability is addressed in terms of both limitations and opportunities facing the industry. A brief review of the status of dry cooling applications is provided. Included is a summary of an extensive survey of electric utility industry perspectives on the future requirements and role for dry cooling. Some regional assessments of the expected future requirements for this technology are also provided. Conclusions are a qualitative characterization of the expected future role of dry cooling in the electric power industry. 72 refs., 7 figs., 13 tabs.

  17. Dry Cask Storage Study Feb 1989

    Broader source: Energy.gov [DOE]

    This report on the use of dry-cask-storage technologies at the sites of civilian nuclear power reactors has been prepared by the U.S. Department of Energy (DOE} in response to the requirements of...

  18. Resuspension and dry deposition research needs

    SciTech Connect (OSTI)

    Sehmel, G.A.

    1983-01-01T23:59:59.000Z

    The author concludes that better predictive models are needed for the signifcant health, ecological, and economic impacts of resuspended particles and their subsequent dry deposition. Both chemical and radioactive aerosols are discussed. (PSB)

  19. High strength air-dried aerogels

    DOE Patents [OSTI]

    Coronado, Paul R.; Satcher, Jr., Joe H.

    2012-11-06T23:59:59.000Z

    A method for the preparation of high strength air-dried organic aerogels. The method involves the sol-gel polymerization of organic gel precursors, such as resorcinol with formaldehyde (RF) in aqueous solvents with R/C ratios greater than about 1000 and R/F ratios less than about 1:2.1. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be air dried at ambient temperatures and pressures. The method significantly reduces the time and/or energy required to produce a dried aerogel compared to conventional methods using either supercritical solvent extraction. The air dried gel exhibits typically less than 5% shrinkage.

  20. Compression of cooked freeze-dried carrots

    E-Print Network [OSTI]

    Macphearson, Bruce Alan

    1973-01-01T23:59:59.000Z

    to precompression characteristics (Brockmann, 1966). Hsmdy (1962) found that acceptable, compressed and freeze-dried spinach could be obtained by plasticizing the product to a moisture content of 9X before compression. Ishler (1962) reported that spraying... the dehydrated food before compression with either water, glycerine or propylene glycol produced bars with excellent rehydra- tion characteristics. He recommended spraying freeze-dried cellu- lar foods to 5-13X moisture, compressing, and redrying to lees than...

  1. Determination of Water Saturation in Relatively Dry Porous Media...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Saturation in Relatively Dry Porous Media Using Gas-phase Tracer Tests. Determination of Water Saturation in Relatively Dry Porous Media Using Gas-phase Tracer Tests....

  2. Wet-dry cooling demonstration. Test results

    SciTech Connect (OSTI)

    Allemann, R.T.; DeBellis, D.E.; Werry, E.V.; Johnson, B.M.

    1986-05-01T23:59:59.000Z

    A large-scale test of dry/wet cooling using the ammonia phase-change system, designated the Advanced Concepts Test (ACT), has been operated at Pacific Gas and Electric Company's Kern Station at Bakersfield, California. The facility is capable of condensing 60,000 lbs/h of steam from a small house turbine. Two different modes of combining dry and evaporative cooling have been tested. One uses deluge cooling in which water is allowed to flow over the fins of the dry (air-cooled) heat exchanger on hot days; the other uses a separate evaporative condenser in parallel to the dry heat exchanger. A third mode of enhancing the dry cooling system, termed capacitive cooling has been tested. In this system, the ammonia-cooled steam condenser is supplemented by a parallel conventional water-cooled condenser with water supplied from a closed system. This water is cooled during off-peak hours each night by an ammonia heat pump which rejects heat through the ACT Cooling Tower. If operated over the period of a year, each of the wet/dry systems would use only 25% of the water normally required to reject this heat load in an evaporative cooling tower. The third would consume no water, the evaporative cooling being replaced by the delayed cooling of the closed system water supply.

  3. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

    1994-03-08T23:59:59.000Z

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.

  4. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Doyle, Edward F. (Dedham, MA); DiBella, Francis A. (Roslindale, MA)

    1994-01-01T23:59:59.000Z

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculated through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried The dryer comprises a vessel which enables the feedstock and steam to enter recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard.

  5. Rate of drying and stresses in the first period of drying

    SciTech Connect (OSTI)

    Kowalski, S.J.; Rybicki, A.

    2000-03-01T23:59:59.000Z

    The paper presents a computer simulated processes and illustrate how the drying induced stresses are influenced by the rate of drying. It is shown that the moisture transport coefficient, and thus the rate of drying, depends on the thermal state of the drying material, defined by the wet-bulb temperature. Through these simulated processes one can observe the evolution of the moisture content and stress distributions during drying at constant, but in each process different, wet-bulb temperatures. A convective drying process of a bar with rectangular cross-section is considered as example, and a two-dimensional initial-boundary value problem is solved numerically with the use of the finite element method. The numerical results are visualized in spatial diagrams.

  6. Sorbent Testing for the Solidification of Organic Process Waste streams from the Radiochemical Engineering Development Center at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Bickford, J.; Foote, M. [MSE Technology Applications, Inc., Montana (United States); Taylor, P. [Oak Ridge National Laboratory, Oak Ridge, Tennessee (United States)

    2008-07-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) has tasked MSE Technology Applications, Inc. (MSE) with evaluating various sorbents to solidify the radioactive liquid organic waste from the Radiochemical Engineering Development Center (REDC) at Oak Ridge National Laboratory (ORNL). REDC recovers and purifies heavy elements (berkelium, californium, einsteinium, and fermium) from irradiated targets for research and industrial applications. Both aqueous and organic waste streams are discharged from REDC. Organic waste is generated from the plutonium/uranium extraction (PUREX), Cleanex, and Pubex processes.1 The PUREX waste derives from an organic-aqueous isotope separation process for plutonium and uranium fission products, the Cleanex waste derives from the removal of fission products and other impurities from the americium/curium product, and the Pubex waste is derived from the separation process of plutonium from dissolved targets. An aqueous waste stream is also produced from these separation processes. MSE has been tasked to test a grouting formula for the aqueous waste stream that includes specially formulated radioactive shielding materials developed by Science and Technology Applications, LLC. This paper will focus on the sorbent testing work. Based on work performed at Savannah River Site (SRS) (Refs. 1, 2), ORNL tested and evaluated three sorbents capable of solidifying the PUREX, Pubex, and Cleanex waste streams and a composite of the three organic waste streams: Imbiber Beads{sup R} IMB230301 (Imbiber Beads), Nochar A610 Petro Bond, and Petroset II Granular{sup TM} (Petroset II-G). Surrogates of the PUREX, Pubex, Cleanex, and a composite organic waste were used for the bench-scale testing. Recommendations resulting from the ORNL testing included follow-on testing by MSE for two of the three sorbents: Nochar Petro Bond and Petroset II-G. MSE recommended that another clay sorbent, Organoclay BM-QT-199, be added to the test sequence. The sorbent/surrogate combinations were tested at bench scale, 19-liter (L) [5-gallon (gal)] bucket scale, and 208-L (55-gal) drum scale. The testing performed by MSE will help ORNL select the right solidification materials and wasteform generation methods for the design of a new treatment facility. The results could also be used to help demonstrate that ORNL could meet the waste acceptance criteria for the ultimate disposal site for the waste-forms. The organics will be solidified as transuranic waste for disposal at the Waste Isolation Pilot Plant, and the aqueous waste stream will be grouted and disposed of at the Nevada Test Site as low-level waste if real waste testing indicates similar results to the surrogate testing. The objective of this work was to identify a sorbent capable of solidifying PUREX, Pubex, and Cleanex organic wastes individually and a composite of the three organic waste streams. The sorbent and surrogate combinations must also be compatible with processing equipment and maintain stability under a variety of conditions that could occur during storage/shipment of the solidified wastes. (authors)

  7. A Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture

    E-Print Network [OSTI]

    to form calcium carbonate (CaCO3) in the exothermic, non-solar carbonation reaction, CaO + CO2 CaCO3, Żh0 CO2 and regener- ated CaO sorbent in the endothermic, solar-driven calcination reaction, CaCO3 Ca consists of two solid-phase species, CaCO3 and CaO, and two fluid-phase species, CO2 and air. The numerical

  8. Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a , Eric Blond1, b , Alain Gasser1 Forbach, France a damintode.kolani@univ-orleans.fr, b eric.blond@univ-orleans.fr Keywords: coal, drying: drying process and pyrolysis of coal. A heat and mass transfer model was developed to simulate the drying

  9. Method and apparatus for drying web

    DOE Patents [OSTI]

    Orloff, David I. (Atlanta, GA); Kloth, Gerald R. (Kennesaw, GA); Rudemiller, Gary R. (Paducah, KY)

    1992-01-01T23:59:59.000Z

    The present invention is directed to a method and apparatus for drying a web of paper utilizing impulse drying techniques. In the method of the invention for drying a paper web, the paper web is transported through a pair of rolls wherein at least one of the rolls has been heated to an elevated temperature. The heated roll is provided with a surface having a low thermal diffusivity of less than about 1.times.10.sup.-6 m.sup.2 /s. The surface material of the roll is preferably prepared from a material selected from the group consisting of ceramics, polymers, glass, inorganic plastics, composite materials and cermets. The heated roll may be constructed entirely from the material having a low thermal diffusivity or the roll may be formed from metal, such as steel or aluminum, or other suitable material which is provided with a surface layer of a material having a low thermal diffusivity.

  10. Dry etching method for compound semiconductors

    DOE Patents [OSTI]

    Shul, R.J.; Constantine, C.

    1997-04-29T23:59:59.000Z

    A dry etching method is disclosed. According to the present invention, a gaseous plasma comprising, at least in part, boron trichloride, methane, and hydrogen may be used for dry etching of a compound semiconductor material containing layers including aluminum, or indium, or both. Material layers of a compound semiconductor alloy such as AlGaInP or the like may be anisotropically etched for forming electronic devices including field-effect transistors and heterojunction bipolar transistors and for forming photonic devices including vertical-cavity surface-emitting lasers, edge-emitting lasers, and reflectance modulators. 1 fig.

  11. Annotated Bibliography for Drying Nuclear Fuel

    SciTech Connect (OSTI)

    Rebecca E. Smith

    2011-09-01T23:59:59.000Z

    Internationally, the nuclear industry is represented by both commercial utilities and research institutions. Over the past two decades many of these entities have had to relocate inventories of spent nuclear fuel from underwater storage to dry storage. These efforts were primarily prompted by two factors: insufficient storage capacity (potentially precipitated by an open-ended nuclear fuel cycle) or deteriorating quality of existing underwater facilities. The intent of developing this bibliography is to assess what issues associated with fuel drying have been identified, to consider where concerns have been satisfactorily addressed, and to recommend where additional research would offer the most value to the commercial industry and the U. S. Department of Energy.

  12. Adsorptive Drying of Organic Liquids- An Update

    E-Print Network [OSTI]

    Joshi, S.; Humphrey, J. L.; Fair, J. R.

    (which is very heat sensitive and can poly merize in the presence of adsorbents) by freeze drying at -20 0 C and centrifuging the ice crystals. The water oontent was reduced from 700 ppm to 1~0 ppm. Pervaporation One of the recent advances... at The University of Texas at Austin will also be given. INTRODUCTION In the process industries it is often necessary to dry fluids before they can be processed further. For example, if a liquid is to be subjected to cryo genic conditions, its frost point must...

  13. Hog Fuel Drying Using Vapour Recompression

    E-Print Network [OSTI]

    Azarniouch, M. K.; MacEachen, I.

    1984-01-01T23:59:59.000Z

    complicated and capital intensive drying process, yields a product of approximately 15% moisture, which due to its particle size, may only be burnt in suspension. iii) From an energy standpotnt the processes are inefficient as only a fractton... fuel. TR.e evaporated moisture is sep rated from the dried hog fuel-oil slurry n 768 ESL-IE-84-04-133 Proceedings from the Sixth Annual Industrial Energy Technology Conference Volume II, Houston, TX, April 15-18, 1984 l'ltlwr d separate vessel...

  14. Dry-Mass Sensing for Microfluidics

    E-Print Network [OSTI]

    Müller, T.; White, D. A.; Knowles, T. P. J.

    2014-11-25T23:59:59.000Z

    Dry-Mass Sensing for Microfluidics T. Mu¨ller,1 D. A. White,1 and T. P. J. Knowles1, a) Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom (Dated: 25 November 2014) We present an approach... for interfacing an electromechanical sensor with a microfluidic device for the accurate quantification of the dry mass of analytes within microchannels. We show that depositing solutes onto the active surface of a quartz crystal microbalance by means of an on...

  15. Acoustically enhanced heat exchange and drying apparatus

    DOE Patents [OSTI]

    Bramlette, T. Tazwell (Livermore, CA); Keller, Jay O. (Oakland, CA)

    1989-01-01T23:59:59.000Z

    A heat transfer apparatus includes a first chamber having a first heat transfer gas inlet, a second heat transfer gas inlet, and an outlet. A first heat transfer gas source provides a first gas flow to the first chamber through the first heat transfer gas inlet. A second gas flow through a second chamber connected to the side of the first chamber, generates acoustic waves which bring about acoustical coupling of the first and second gases in the acoustically augmented first chamber. The first chamber may also include a material inlet for receiving material to be dried, in which case the gas outlet serves as a dried material and gas outlet.

  16. Self-protection in dry recycle technologies

    SciTech Connect (OSTI)

    Hannum, W.H.; Wade, D.; Stanford, G.

    1995-12-01T23:59:59.000Z

    In response to the INFCE conclusions, the U.S. undertook development of a new dry fuel cycle. Dry recycle processes have been demonstrated to be feasible. Safeguarding such fuel cycles will be dramatically simpler than the PUREX fuel cycle. At every step of the processes, the materials meet the {open_quotes}spent-fuel standard.{close_quotes} The scale is compatible with collocation of power reactors and their recycle facility, eliminating off-site transportation and storage of plutonium-bearing materials. Material diverted either covertly or overtly would be difficult (relative to material available by other means) to process into weapons feedstock.

  17. Dry etching method for compound semiconductors

    DOE Patents [OSTI]

    Shul, Randy J. (Albuquerque, NM); Constantine, Christopher (Safety Harbor, FL)

    1997-01-01T23:59:59.000Z

    A dry etching method. According to the present invention, a gaseous plasma comprising, at least in part, boron trichloride, methane, and hydrogen may be used for dry etching of a compound semiconductor material containing layers including aluminum, or indium, or both. Material layers of a compound semiconductor alloy such as AlGaInP or the like may be anisotropically etched for forming electronic devices including field-effect transistors and heterojunction bipolar transistors and for forming photonic devices including vertical-cavity surface-emitting lasers, edge-emitting lasers, and reflectance modulators.

  18. Measurement of vapor phase mercury emissions at coal-fired power plants using regular and speciating sorbent traps with in-stack and out-of-stack sampling methods

    SciTech Connect (OSTI)

    Chin-Min Cheng; Chien-Wei Chen; Jiashun Zhu; Chin-Wei Chen; Yao-Wen Kuo; Tung-Han Lin; Shu-Hsien Wen; Yong-Siang Zeng; Juei-Chun Liu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

    2009-09-15T23:59:59.000Z

    A systematic investigation of sorbent-trap sampling, which is a method that uses paired sorbent traps to measure total vapor phase mercury (Hg), was carried out at two coal-fired power plants. The objective of the study was to evaluate the effects (if any) on data quality when the following aspects of the sorbent trap method are varied: (a) sorbent trap configuration; (b) sampling time; and (c) analytical technique. Also, the performance of a speciating sorbent trap (i.e., a trap capable of separating elemental Hg from oxidized Hg), was evaluated by direct comparison against the Ontario Hydro (OH) reference method. Flue gas samples were taken using both 'regular' and modified sorbent trap measurement systems. Both short-term (1.5 h) and long-term (18 h to 10 days) samples were collected. The in-stack and out-of-stack sampling methods produced satisfactory relative accuracy results for both the short-term and long-term testing. For the short-term tests, the in-stack sampling results compared more favorably to the OH method than did the out-of-stack results. The relative deviation between the paired traps was considerably higher for the short-term out-of-stack tests than for the long-term tests. A one-way analysis of variance (ANOVA), showed a statistically significant difference (p < 0.1) between the direct combustion and wet-chemistry analytical methods used in the study; the results from the direct combustion method were consistently higher than the wet-chemistry results. The evaluation of the speciating mercury sorbent trap demonstrated that the trap is capable of providing reasonably accurate total mercury concentrations and speciation data that are somewhat comparable to data obtained with the OH method. 5 refs., 4 figs., 8 tabs.

  19. Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

    2013-01-01T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150–540 °C) to hot (>540 °C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 °C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  20. Sorbent Testing For Solidification of Process Waste streams from the Radiochemical Engineering Development Center at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Bickford, J. [MSE Technology Applications, Inc., MT (United States); Taylor, P. [Oak Ridge National Laboratory, Oak Ridge, TN (United States)

    2007-07-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) tasked MSE Technology Applications, Inc. (MSE) to evaluate sorbents identified by Oak Ridge National Laboratory (ORNL) to solidify the radioactive liquid organic waste from the Radiochemical Engineering Development Center (REDC) at ORNL. REDC recovers and purifies heavy elements (berkelium, californium, einsteinium, and fermium) from irradiated targets for research and industrial applications. Both organic and aqueous waste streams are discharged from REDC. The organic waste is generated from the plutonium/uranium extraction (Purex), Cleanex, and Pubex processes. The Purex waste derives from an organic-aqueous isotope separation process for plutonium and uranium fission products, the Cleanex waste derives from the removal of fission products and other impurities from the americium/curium product, and the Pubex waste is derived from the separation process of plutonium from dissolved targets. MSE had also been tasked to test a grouting formula for the aqueous waste stream that includes radioactive shielding material. The aqueous waste is a mixture of the raffinate streams from the various extraction processes plus the caustic solution that is used to dissolve the aluminum cladding from the irradiated targets. (authors)

  1. REMOVAL OF H2S AND SO2 BY CaCO3-BASED SORBENTS AT HIGH PRESSURES

    SciTech Connect (OSTI)

    Prof. Stratis V. Sotirchos

    2000-09-01T23:59:59.000Z

    The mechanism of the removal of SO{sub 2} and H{sub 2}S by CaCO{sub 3}-based sorbents in pressurized fluidized-bed coal combustors (PFBC) and high pressure gasifiers was investigated in this project. Reactivity evolution experiments were carried out in thermogravimetric apparatuses both under simulated high pressure conditions and at high pressures. Experiments at high pressure were conducted in a high pressure thermogravimetric arrangement that was set up and developed under this project. Two calcitic solids of high calcium carbonate content (over 97%) were employed in the experiments: a fine-grained distributed by Greer Limestone Co. (Greer Limestone) and a solid supplied in the form of large calcitic crystals (Iceland Spar). The decision to work with these solids was mainly based on the fact that they have been employed in several past studies of sulfation, sulfidation, and calcination in our laboratory, and therefore, a large volume of data on their performance under different conditions was available for comparison purposes. In addition to the experimental studies, work was also done on the development of rigorous mathematical models for the description of the occurrence of simultaneous processes (e.g., calcination and sulfation and carbonation and sulfation) in the interior of porous solids and for the simulation of the evolution of the pore structure of porous solids that undergo chemical transformation in their interior.

  2. Process development for production of coal/sorbent agglomerates. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Rapp, D.M.

    1991-12-31T23:59:59.000Z

    The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to proceed. The process has been successfully demonstrated on a pilot-scale as a method of hardening iron ore pellets (Imperato, 1966). Two potential combustion options are being considered for the coal/calcium hydroxide pellets: fluidized bed combustors and industrial stoker boilers.

  3. Integrated dry NO{sub x}/SO{sub 2} emissions control system. Final report, Volume 1: Public design

    SciTech Connect (OSTI)

    Hunt, T.; Hanley, T.J.

    1997-11-01T23:59:59.000Z

    The U.S. Department of Energy (DOE)/Pittsburgh Energy Technology Center (PETC) and the Public Services Company of Colorado (PSCo) signed the cooperative agreement for the Integrated Dry NO{sub x}/SO{sub 2} Emissions Control System in March 1991. This project integrates various combinations of five existing and emerging technologies onto a 100 MWe, down-fired, load-following unit that burns pulverized coal. The project is expected to achieve up to 70% reductions in both oxides of nitrogen (NO{sub x}) and sulfur dioxide (SO{sub 2}) emissions. Various combinations of low-NO{sub x} burners (LNBs), overfire air (OFA) ports, selective non-catalytic reduction (SNCR), dry sorbent injection (DSI) using both calcium- and sodium-based reagents, and flue-gas humidification are expected to integrate synergistically and control both NO{sub x} and SO{sub 2} emissions better than if each technology were used alone. For instance, ammonia emissions from the SNCR system are expected to reduce NO{sub 2} emissions and allow the DSI system (sodium-based reagents) to achieve higher removals of SO{sub 2}. Unlike tangentially or wall-fired units, down-fired require substantial modification to their pressure parts to retrofit LNBs and OFA ports, substantially increasing the cost of retrofit. Conversely, the retrofitting of SNCR, DSI, or humidification systems does not require any major boiler modifications and are easily retrofitted to all boiler types. However, existing furnace geometry and flue-gas temperatures can limit their placement and effectiveness. In particular, SNCR requires injecting the SNCR chemicals into the furnace where the temperature is within a very narrow temperature range.

  4. Method for dry etching of transition metals

    DOE Patents [OSTI]

    Ashby, Carol I. H. (Edgewood, NM); Baca, Albert G. (Albuquerque, NM); Esherick, Peter (Albuquerque, NM); Parmeter, John E. (Albuquerque, NM); Rieger, Dennis J. (Tijeras, NM); Shul, Randy J. (Albuquerque, NM)

    1998-01-01T23:59:59.000Z

    A method for dry etching of transition metals. The method for dry etching of a transition metal (or a transition metal alloy such as a silicide) on a substrate comprises providing at least one nitrogen- or phosphorous-containing .pi.-acceptor ligand in proximity to the transition metal, and etching the transition metal to form a volatile transition metal/.pi.-acceptor ligand complex. The dry etching may be performed in a plasma etching system such as a reactive ion etching (RIE) system, a downstream plasma etching system (i.e. a plasma afterglow), a chemically-assisted ion beam etching (CAIBE) system or the like. The dry etching may also be performed by generating the .pi.-acceptor ligands directly from a ligand source gas (e.g. nitrosyl ligands generated from nitric oxide), or from contact with energized particles such as photons, electrons, ions, atoms, or molecules. In some preferred embodiments of the present invention, an intermediary reactant species such as carbonyl or a halide ligand is used for an initial chemical reaction with the transition metal, with the intermediary reactant species being replaced at least in part by the .pi.-acceptor ligand for forming the volatile transition metal/.pi.-acceptor ligand complex.

  5. Undesired drying of concrete and cement paste

    E-Print Network [OSTI]

    Langendoen, Koen

    Undesired drying of concrete and cement paste is a nightmare for any construction engineer of the concrete or cement paste surface. Inspired by the art of molecular cooking a team of TU Delft scientists for instance sodium alginates. When sprayed on the surface of concrete or cement paste, a rapid chemical

  6. Hot-dry-rock geothermal resource 1980

    SciTech Connect (OSTI)

    Heiken, G.; Goff, F.; Cremer, G. (ed.)

    1982-04-01T23:59:59.000Z

    The work performed on hot dry rock (HDR) geothermal resource evaluation, site characterization, and geophysical exploration techniques is summarized. The work was done by region (Far West, Pacific Northwest, Southwest, Rocky Mountain States, Midcontinent, and Eastern) and limited to the conterminous US.

  7. Spent fuel integrity during dry storage

    SciTech Connect (OSTI)

    McKinnon, M.A.

    1995-07-01T23:59:59.000Z

    Information on spent fuel integrity is of interest in evaluating the impact of long-term dry storage on the behavior of spent fuel rods. Spent fuel used during cask performance tests at the Idaho National Engineering Laboratory (INEL) offers significant opportunities for confirmation of the benign nature of long-term dry storage. The cask performance tests conducted at INEL included visual observation and ultrasonic examination of the condition of cladding, fuel rods, and fuel assembly hardware before dry storage and consolidation of the fuel; and a qualitative determination of the effect of dry storage and fuel consolidation on fission gas release from the spent fuel rods. A variety of cover gases and cask orientations were used during the cask performance tests. Cover gases included vacuum, nitrogen, and helium. The nitrogen and helium backfills were sampled and analyzed to detect leaking spent fuel rods. At the conclusion of each performance test, periodic gas sampling was conducted on each cask as part of a surveillance and monitoring activity. Continued surveillance and monitoring activities are being conducted for intact fuel in a CASTOR V/21 cask and for consolidated fuel in a VSC-17 cask. The results of the gas sampling activities are reported in this paper.

  8. Hog Fuel Drying Using Vapour Recompression 

    E-Print Network [OSTI]

    Azarniouch, M. K.; MacEachen, I.

    1984-01-01T23:59:59.000Z

    A continuous hog fuel drying pilot plant based on the principle of mixing hog fuel with a hot oil (e.g., crude tall oil) as the heat transfer medium, and recirculating the suspension through a steam heated exchanger was designed, built...

  9. Non-Linear Drying Diffusion and Viscoelastic Drying Shrinkage Modeling in Hardened Cement Pastes

    E-Print Network [OSTI]

    Leung, Chin K.

    2010-07-14T23:59:59.000Z

    modeling with an average diffusion coefficient and with determined viscoelastic parameters from creep tests agreed well compared to the shrinkage data from experiments, indicating that drying shrinkage of cement paste may be considered as a poroviscoelastic...

  10. Non-Linear Drying Diffusion and Viscoelastic Drying Shrinkage Modeling in Hardened Cement Pastes 

    E-Print Network [OSTI]

    Leung, Chin K.

    2010-07-14T23:59:59.000Z

    of diffusion rate over short drops of ambient relative humidity. Techniques to determine drying isotherms prior to full equilibration of mass loss, as well as converting mass loss into concentration of water vapor were developed. Using the measured water vapor...

  11. 1997 DRY BEAN VARIETY CANNING TRIALS MICHIGAN DRY BEAN PRODUCTION RESEARCH ADVISORY BOARD

    E-Print Network [OSTI]

    1997 DRY BEAN VARIETY CANNING TRIALS MICHIGAN DRY BEAN PRODUCTION RESEARCH ADVISORY BOARD Rating 1=poor, 2=fair, 3=good, 4=above average, 5=excellent NAVY LIGHT RED KIDNEY BEANS VARIETY GRATIOT HURON 8.4 3.3 ASG96YT8 2.1 1.8 DARK RED KIDNEY BEANS ASG96YT37 3.4 2.1 VARIETY MONTCALM BAY 7 YEAR AVE ASG96YT

  12. Flue-gas carbon capture on carbonaceous sorbents: Toward a low-cost multifunctional Carbon Filter for 'Green' energy producers

    SciTech Connect (OSTI)

    Radosz, M.; Hu, X.D.; Krutkramelis, K.; Shen, Y.Q. [University of Wyoming, Laramie, WY (United States)

    2008-05-15T23:59:59.000Z

    A low-pressure Carbon Filter Process (patent pending) is proposed to capture carbon dioxide (CO{sub 2}) from flue gas. This filter is filled with a low-cost carbonaceous sorbent, such as activated carbon or charcoal, which has a high affinity (and, hence, high capacity) to CO{sub 2} but not to nitrogen (N{sub 2}). This, in turn, leads to a high CO{sub 2}/N{sub 2} selectivity, especially at low pressures. The Carbon Filter Process proposed in this work can recover at least 90% of flue-gas CO{sub 2} of 90%+ purity at a fraction of the cost normally associated with the conventional amine absorption process. The Carbon Filter Process requires neither expensive materials nor flue-gas compression or refrigeration, and it is easy to heat integrate with an existing or grassroots power plant without affecting the cost of the produced electricity too much. An abundant supply of low-cost CO{sub 2} from electricity producers is good news for enhanced oil recovery (EOR) and enhanced coal-bed methane recovery (ECBMR) operators, because it will lead to higher oil and gas recovery rates in an environmentally sensitive manner. A CO{sub 2}-rich mixture that contains some nitrogen is much less expensive to separate from flue-gas than pure CO{sub 2}; therefore, mixed CO{sub 2}/N{sub 2}-EOR and CO{sub 2}/N{sub 2}-ECBMR methods are proposed to maximize the overall carbon capture and utilization efficiency.

  13. Clean Coal Technology: Reduction of NO{sub x} and SO{sub 2} using gas reburning, sorbent injection, and integrated technologies. Topical report No. 3, Revision 1

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program (also referred to as the CCT Program), is a unique government/industry cost-shared effort to develop these advanced coal-based technologies. The CCT Program provides numerous options for addressing a wide range of energy and environmental issues, including acid rain, global climate change, improved energy efficiency, energy security, and environmental qualitiy. It is intended to demonstrate a new generation of full-scale, ``showcase`` facilities built through the United States. Gas Reburning, Sorbent Injection and Integrated Technologies -- the subject of this Topical Report -- are one such set of promising innovative developments. In addition to discussing the technologies involved, this report will describe two specific projects, results to date, and the commercial promise of these processes. The objectives of Gas Reburning and Sorbent Injection were to have a 60% reduction in NO{sub x} emissions and a 50% reduction in SO{sub 2} emissions. These objectives have been achieved at the tangentially-fired boiler at the Hennepin site of Illinois Power and at the cyclone-fired boiler operated by City Water, Light and Power in Springfield, Illinois. The other project, Gas Reburning and Low NO{sub x} Burners had the goal of a 70% NO{sub x} reduction from the wall-fired boiler operated by Public Service of Colorado at Denver. In early preliminary testing, this goal was also achieved. Energy and Environmental Research (EER) is now ready to design and install Gas Rebunting and Sorbent Injection systems, and Gas Reburning-Low NO{sub x}, Burner systems for any utility or industrial application. These technologies are offered with performance and emission control guarantees.

  14. Dry-Mass Sensing for Microfluidics

    E-Print Network [OSTI]

    Müller, T; Knowles, T P J

    2014-01-01T23:59:59.000Z

    We present an approach for interfacing an electromechanical sensor with a microfluidic device for the accurate quantification of the dry mass of analytes within microchannels. We show that depositing solutes onto the active surface of a quartz crystal microbalance by means of an on-chip microfluidic spray nozzle and subsequent solvent removal provides the basis for the real-time determination of dry solute mass. Moreover, this detection scheme does not suffer from the decrease in the sensor quality factor and the viscous drag present if the measurement is performed in a liquid environment, yet allows solutions to be analysed. We demonstrate the sensitivity and reliability of our approach by controlled deposition of nanogram levels of salt and protein from a micrometer-sized channel.

  15. Horizontal modular dry irradiated fuel storage system

    DOE Patents [OSTI]

    Fischer, Larry E. (Los Gatos, CA); McInnes, Ian D. (San Jose, CA); Massey, John V. (San Jose, CA)

    1988-01-01T23:59:59.000Z

    A horizontal, modular, dry, irradiated fuel storage system (10) includes a thin-walled canister (12) for containing irradiated fuel assemblies (20), which canister (12) can be positioned in a transfer cask (14) and transported in a horizontal manner from a fuel storage pool (18), to an intermediate-term storage facility. The storage system (10) includes a plurality of dry storage modules (26) which accept the canister (12) from the transfer cask (14) and provide for appropriate shielding about the canister (12). Each module (26) also provides for air cooling of the canister (12) to remove the decay heat of the irradiated fuel assemblies (20). The modules (26) can be interlocked so that each module (26) gains additional shielding from the next adjacent module (26). Hydraulic rams (30) are provided for inserting and removing the canisters (12) from the modules (26).

  16. Wall Drying in Hot and Humid Climates

    E-Print Network [OSTI]

    Boone, K.; Weston, T.; Pascual, X.

    2004-01-01T23:59:59.000Z

    WALL DRYING IN HOT AND HUMID CLIMATES Kimdolyn Boone Theresa Weston, PhD Xuaco Pascual Product Development Engineer Building Scientist Field Services Engineer E.I. du Pont de Nemours and Company Richmond, VA ABSTRACT... time based on the varying weather conditions. Constant interior conditions of 70?F and 55% RH were chosen. This corresponds to typical interior temperatures and a high level of moisture production within the house. This was chosen as a worse...

  17. Cold Vacuum Drying Facility hazard analysis report

    SciTech Connect (OSTI)

    Krahn, D.E.

    1998-02-23T23:59:59.000Z

    This report describes the methodology used in conducting the Cold Vacuum Drying Facility (CVDF) hazard analysis to support the CVDF phase 2 safety analysis report (SAR), and documents the results. The hazard analysis was performed in accordance with DOE-STD-3009-94, Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, and implements the requirements of US Department of Energy (DOE) Order 5480.23, Nuclear Safety Analysis Reports.

  18. PULSE DRYING EXPERIMENT AND BURNER CONSTRUCTION

    SciTech Connect (OSTI)

    Robert States

    2006-07-15T23:59:59.000Z

    Non steady impingement heat transfer is measured. Impingement heating consumes 130 T-BTU/Yr in paper drying, but is only 25% thermally efficient. Pulse impingement is experimentally shown to enhance heat transfer by 2.8, and may deliver thermal efficiencies near 85%. Experimental results uncovered heat transfer deviations from steady theory and from previous investigators, indicating the need for further study and a better theoretical framework. The pulse burner is described, and its roll in pulse impingement is analyzed.

  19. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 27, April 1, 1994--June 30, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-07-15T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal-fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone-fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions through a combination of two technologies, gas reburning and sorbent injection.

  20. Effects of O{sub 2} and SO{sub 2} on the Capture Capacity of a Primary-Amine Based Polymeric CO{sub 2} Sorbent

    SciTech Connect (OSTI)

    Hallenbeck, Alexander P.; Kitchin, John R.

    2013-08-01T23:59:59.000Z

    Post combustion CO{sub 2} capture is most commonly carried out using an amine solution that results in a high parasitic energy cost in the stripper unit due to the need to heat the water which comprises a majority of the amine solution. It is also well known that amine solvents suffer from stability issues due to amine leaching and poisoning by flue gas impurities. Solid sorbents provide an alternative to solvent systems that would potentially reduce the energy penalty of carbon capture. However, the cost of using a particular sorbent is greatly affected by the usable lifetime of the sorbent. This work investigated the stability of a primary amine-functionalized ion exchange resin in the presence of O{sub 2} and SO{sub 2}, both of which are constituents of flue gas that have been shown to cause degradation of various amines in solvent processes. The CO{sub 2} capture capacity was measured over multiple capture cycles under continuous exposure to two simulated flue gas streams, one containing 12 vol% CO{sub 2}, 4% O{sub 2}, 84% N{sub 2}, and the other containing 12.5 vol% CO{sub 2}, 4% O{sub 2}, 431 ppm SO{sub 2}, balance N{sub 2} using a custom-built packed bed reactor. The resin maintained its CO{sub 2} capture capacity of 1.31 mol/kg over 17 capture cycles in the presence of O{sub 2} without SO{sub 2}. However, the CO{sub 2} capture capacity of the resin decreased rapidly under exposure to SO{sub 2} by an amount of 1.3 mol/kg over 9 capture cycles. Elemental analysis revealed the resin adsorbed 1.0 mol/kg of SO{sub 2}. Thermal regeneration was determined to not be possible. The poisoned resin was, however, partially regenerated with exposure to 1.5M NaOH for 3 days resulting in a 43% removal of sulfur, determined through elemental analysis, and a 35% recovery of CO{sub 2} capture capacity. Evidence was also found for amine loss upon prolonged (7 days) continuous exposure to high temperatures (120 #14;C) in air. It is concluded that desulfurization of the flue gas stream prior to CO{sub 2} capture will greatly improve the economic viability of using this solid sorbent in a post-combustion CO{sub 2} capture process.

  1. Hot Dry Rock Geothermal Energy Development Program

    SciTech Connect (OSTI)

    Smith, M.C.; Hendron, R.H.; Murphy, H.D.; Wilson, M.G.

    1989-12-01T23:59:59.000Z

    During Fiscal Year 1987, emphasis in the Hot Dry Rock Geothermal Energy Development Program was on preparations for a Long-Term Flow Test'' of the Phase II'' or Engineering'' hot dry rock energy system at Fenton Hill, New Mexico. A successful 30-day flow test of the system during FY86 indicated that such a system would produce heat at a temperature and rate that could support operation of a commercial electrical power plant. However, it did not answer certain questions basic to the economics of long-term operation, including the rate of depletion of the thermal reservoir, the rate of water loss from the system, and the possibility of operating problems during extended continuous operation. Preparations for a one-year flow test of the system to answer these and more fundamental questions concerning hot dry rock systems were made in FY87: design of the required surface facilities; procurement and installation of some of their components; development and testing of slimline logging tools for use through small-diameter production tubing; research on temperature-sensitive reactive chemical tracers to monitor thermal depletion of the reservoir; and computer simulations of the 30-day test, extended to modeling the planned Long-Term Flow Test. 45 refs., 34 figs., 5 tabs.

  2. Dry Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    K. M. Goff; M. F. Simpson

    2009-09-01T23:59:59.000Z

    Dry (non-aqueous) separations technologies have been used for treatment of used nuclear fuel since the 1960s, and they are still being developed and demonstrated in many countries. Dry technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. Within the Department of Energy’s Advanced Fuel Cycle Initiative, an electrochemical process employing molten salts is being developed for recycle of fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. Much of the development of this technology is based on treatment of used Experimental Breeder Reactor II (EBR-II) fuel, which is metallic. Electrochemical treatment of the EBR-II fuel has been ongoing in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory since 1996. More than 3.8 metric tons of heavy metal of metallic fast reactor fuel have been treated using this technology. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including high-level waste work. A historic perspective on the background of dry processing will also be provided.

  3. Transfer of hot dry rock technology

    SciTech Connect (OSTI)

    Smith, M.C.

    1985-11-01T23:59:59.000Z

    The Hot Dry Rock Geothermal Energy Development Program has focused worldwide attention on the facts that natural heat in the upper part of the earth's crust is an essentially inexhaustible energy resource which is accessible almost everywhere, and that practical means now exist to extract useful heat from the hot rock and bring it to the earth's surface for beneficial use. The Hot Dry Rock Program has successfully constructed and operated a prototype hot, dry rock energy system that produced heat at the temperatures and rates required for large-scale space heating and many other direct uses of heat. The Program is now in the final stages of constructing a larger, hotter system potentially capable of satisfying the energy requirements of a small, commercial, electrical-generating power plant. To create and understand the behavior of such system, it has been necessary to develop or support the development of a wide variety of equipment, instruments, techniques, and analyses. Much of this innovative technology has already been transferred to the private sector and to other research and development programs, and more is continuously being made available as its usefulness is demonstrated. This report describes some of these developments and indicates where this new technology is being used or can be useful to industry, engineering, and science.

  4. On the dry deposition of submicron particles

    SciTech Connect (OSTI)

    Wesely, M. L.

    1999-10-08T23:59:59.000Z

    The air-surface exchange of particles can have a strong role in determining the amount, size, and chemical composition of particles in the troposphere. Here the authors consider only dry processes (deposition processes not directly aided by precipitation) and mostly address particles less than about 2 {micro}m in diameter (often referred to as submicron particles because most of such particles are less than 1 {micro}m in diameter). The processes that control the dry exchange of particulate material between the atmosphere and the surface of the Earth are numerous, highly varied, and sometimes poorly understood. As a result, determining which of the surface processes to parameterize or simulate in modeling the tropospheric mass budget of a particulate substance can be a significant challenge. Dry deposition, for example, can be controlled by a combination of Brownian diffusion, impaction, interception, and gravitational settling, depending on the size of the particles, the roughness of the surface on both micrometeorological and microscopic scales, the geometrical structure of vegetative canopies, and other surface characteristics such as wetness. Particles can be added to the lower atmosphere by resuspension from land surfaces and sea spray. The roles of rapid gas-to-particle conversion and growth or shrinkage of particles as a result of water condensation or evaporation in the lower few meters of the atmosphere can also have a significant impact on particle concentrations in the lower atmosphere. Here, a few micrometeorological observations and inferences on particle air-surface exchange are briefly addressed.

  5. Summary Report for Capsule Dry Storage Project

    SciTech Connect (OSTI)

    JOSEPHSON, W S

    2003-09-04T23:59:59.000Z

    There are 1.936 cesium (Cs) and strontium (Sr) capsules stored in pools at the Waste Encapsulation and Storage Facility (WESF). These capsules will be moved to dry storage on the Hanford Site as an interim measure to reduce risk. The Cs/Sr Capsule Dry Storage Project (CDSP) is conducted under the assumption the capsules will eventually be moved to the repository at Yucca Mountain, and the design criteria include requirements that will facilitate acceptance at the repository. The storage system must also permit retrieval of capsules in the event vitrification of the capsule contents is pursued. A cut away drawing of a typical cesium chloride (CsCI) capsule and the capsule property and geometry information are provided in Figure 1.1. Strontium fluoride (SrF{sub 2}) capsules are similar in design to CsCl capsules. Further details of capsule design, current state, and reference information are given later in this report and its references. Capsule production and life history is covered in WMP-16938, Capsule Characterization Report for Capsule Dry Storage Project, and is briefly summarized in Section 5.2 of this report.

  6. Roles of Dry Friction in Fluctuating Motion of Adiabatic Piston

    E-Print Network [OSTI]

    Tomohiko G. Sano; Hisao Hayakawa

    2014-03-08T23:59:59.000Z

    The motion of an adiabatic piston under dry friction is investigated to clarify the roles of dry friction in non-equilibrium steady states. We clarify that dry friction can reverse the direction of the piston motion and causes a discontinuity or a cusp-like singularity for velocity distribution functions of the piston. We also show that the heat fluctuation relation is modified under dry friction.

  7. Heat-transfer characteristics of a dry and wet/dry advanced condenser for cooling towers

    SciTech Connect (OSTI)

    Fricke, H.D.; McIlroy, K.; Webster, D.J.

    1982-06-01T23:59:59.000Z

    An EPRI-funded, experimental evaluation of two types of advanced, air-cooled ammonia condensers for a phase-change dry/wet cooling system for electric power plants is described. Condensers of similar design, but much bigger, are being tested in a 15 MWe demonstration plant at the Pacific Gas and Electric Kern Power Station in Bakersfield, California. These condensers, featuring different air-side augmentation, were tested in Union Carbide's ammonia phase-change pilot plant (0.3 MWe). The first unit consisted of the Curtiss-Wright integral shaved-fin extruded aluminum tubing designed for dry operation. Heat transfer and air-side pressure loss characteristics were measured under varying air face velocities (600 to 1000 FPM) and initial temperature differences, ITD (20 to 60/sup 0/F). Overall heat transfer coefficients (based on air-side surface), U, ranged between 7.0 to 8.6 Btu/hr ft/sup 2/ F. The second configuration constituted the Hoterv aluminum plate-fin/tube assembly of which two different sizes (5 ft/sup 2/ and 58 ft/sup 2/ frontal area) were performance tested; in both dry and wet modes at 200 to 800 FPM air face velocities, ITD's of 10 to 60/sup 0/F and at water deluge rates up to 3.0 gpm/ft. of core width. In the dry mode, U's ranged from 7.0 to 12.0 Btu/hr ft/sup 2/ F. Increasing water deluge greatly enhanced the heat rejection capacity over dry operation - as high as 4 times, depending on operating conditions. This deluge augmentation was greater for lower air relative humidities and lower ITD's. A brief description of the recently completed ammonia phase-change dry/wet-dry cooling demonstration plant at the Kern Power Station concludes this document.

  8. A Benchmarking Analysis for Five Radionuclide Vadose Zone Models (Chain, Multimed{_}DP, Fectuz, Hydrus, and Chain 2D) in Soil Screening Level Calculations

    SciTech Connect (OSTI)

    Chen, J-S.; Drake, R.; Lin, Z.; Jewett, D. G.

    2002-02-26T23:59:59.000Z

    Five vadose zone models with different degrees of complexity (CHAIN, MULTIMED{_}DP, FECTUZ, HYDRUS, and CHAIN 2D) were selected for use in radionuclide soil screening level (SSL) calculations. A benchmarking analysis between the models was conducted for a radionuclide ({sup 99}Tc) release scenario at the Las Cruces Trench Site in New Mexico. Sensitivity of three model outputs to the input parameters were evaluated and compared among the models. The three outputs were peak contaminant concentrations, time to peak concentrations at the water table, and time to exceed the contaminants maximum critical level at a representative receptor well. Model parameters investigated include soil properties such as bulk density, water content, soil water retention parameters and hydraulic conductivity. Chemical properties examined include distribution coefficient, radionuclide half-life, dispersion coefficient, and molecular diffusion. Other soil characteristics, such as recharge rate, also were examined. Model sensitivity was quantified in the form of sensitivity and relative sensitivity coefficients. Relative sensitivities were used to compare the sensitivities of different parameters. The analysis indicates that soil water content, recharge rate, saturated soil water content, and soil retention parameter, {beta}, have a great influence on model outputs. In general, the results of sensitivities and relative sensitivities using five models are similar for a specific scenario. Slight differences were observed in predicted peak contaminant concentrations due to different mathematical treatment among models. The results of benchmarking and sensitivity analysis would facilitate the model selection and application of the model in SSL calculations.

  9. Dry friction avalanches: Experiment and theory Sergey V. Buldyrev,1

    E-Print Network [OSTI]

    Buldyrev, Sergey

    Dry friction avalanches: Experiment and theory Sergey V. Buldyrev,1 John Ferrante,2 and Fredy R and theoretical models are presented supporting the conjecture that dry friction stick-slip is described by self in systems presenting stick-slip due to dry friction has been under scrutiny 11 . Experimental evidence

  10. 11 The Prandtl-Tomlinson Model for Dry Photodetector

    E-Print Network [OSTI]

    Berlin,Technische Universität

    11 The Prandtl-Tomlinson Model for Dry Friction Cantilever Photodetector Laser Beam 11-Verlag Berlin Heidelberg 2010 #12;156 11 The Prandtl-Tomlinson Model for Dry Friction model." Prandtl considered properties of dry friction. Actually, we must apply a minimum force to the body so that a mac- roscopic

  11. Torsion Spring Oscillator with Dry Friction Eugene I. Butikov

    E-Print Network [OSTI]

    Butikov, Eugene

    by viscous and dry (Coulomb) friction are investigated analytically and with the help of computer simulations-state oscillations. 1. Introduction Mechanical vibration systems with combined viscous and dry (Coulomb) friction. Even the simplest dry friction model, the Coulomb friction, can explain the principal peculiarities

  12. Torsion Spring Oscillator with Dry Friction Eugene Butikov

    E-Print Network [OSTI]

    Butikov, Eugene

    at investigation of free oscillations of a torsion spring pendulum damped by dry (Coulomb) friction. An idealizedTorsion Spring Oscillator with Dry Friction Manual Eugene Butikov Annotation. The manual includes as a prerequisite for the virtual lab "Torsion Spring Oscillator with Dry Friction." The manual includes also a set

  13. Review of Drying Methods for Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Large, W.S.

    1999-10-21T23:59:59.000Z

    SRTC is developing technology for direct disposal of aluminum spent nuclear fuel (SNF). The development program includes analyses and tests to support design and safe operation of a facility for ''road ready'' dry storage of SNF-filled canisters. The current technology development plan includes review of available SNF drying methods and recommendation of a drying method for aluminum SNF.

  14. Modified Dry Grind Ethanol Process Vijay Singh1

    E-Print Network [OSTI]

    Modified Dry Grind Ethanol Process Vijay Singh1 , Kent D. Rausch1 *, Ping Yang2 , Hosein Shapouri3-265-0697). #12;Modified Dry Grind Ethanol Process ­ University of Illinois 2 Table of Contents 1. Introductory.....................................................................................................7 3.2. Dry Grind Ethanol

  15. Project W-441, cold vacuum drying facility design requirements document

    SciTech Connect (OSTI)

    O`Neill, C.T.

    1997-05-08T23:59:59.000Z

    This document has been prepared and is being released for Project W-441 to record the design basis for the design of the Cold Vacuum Drying Facility. This document sets forth the physical design criteria, Codes and Standards, and functional requirements that were used in the design of the Cold Vacuum Drying Facility. This document contains section 3, 4, 6, and 9 of the Cold Vacuum Drying Facility Design Requirements Document. The remaining sections will be issued at a later date. The purpose of the Facility is to dry, weld, and inspect the Multi-Canister Overpacks before transport to dry storage.

  16. DRI Renewable Energy Center (REC) (NV)

    SciTech Connect (OSTI)

    Hoekman, S. Kent; Broch, Broch; Robbins, Curtis; Jacobson, Roger; Turner, Robert

    2012-12-31T23:59:59.000Z

    The primary objective of this project was to utilize a flexible, energy-efficient facility, called the DRI Renewable Energy Experimental Facility (REEF) to support various renewable energy research and development (R&D) efforts, along with education and outreach activities. The REEF itself consists of two separate buildings: (1) a 1200-ft2 off-grid capable house and (2) a 600-ft2 workshop/garage to support larger-scale experimental work. Numerous enhancements were made to DRI's existing renewable power generation systems, and several additional components were incorporated to support operation of the REEF House. The power demands of this house are satisfied by integrating and controlling PV arrays, solar thermal systems, wind turbines, an electrolyzer for renewable hydrogen production, a gaseous-fuel internal combustion engine/generator set, and other components. Cooling needs of the REEF House are satisfied by an absorption chiller, driven by solar thermal collectors. The REEF Workshop includes a unique, solar air collector system that is integrated into the roof structure. This system provides space heating inside the Workshop, as well as a hot water supply. The Workshop houses a custom-designed process development unit (PDU) that is used to convert woody biomass into a friable, hydrophobic char that has physical and chemical properties similar to low grade coal. Besides providing sufficient space for operation of this PDU, the REEF Workshop supplies hot water that is used in the biomass treatment process. The DRI-REEF serves as a working laboratory for evaluating and optimizing the performance of renewable energy components within an integrated, residential-like setting. The modular nature of the system allows for exploring alternative configurations and control strategies. This experimental test bed is also highly valuable as an education and outreach tool both in providing an infrastructure for student research projects, and in highlighting renewable energy features to the public.

  17. Hot dry rock venture risks investigation:

    SciTech Connect (OSTI)

    Not Available

    1988-01-01T23:59:59.000Z

    This study assesses a promising resource in central Utah as the potential site of a future commerical hot dry rock (HDR) facility for generating electricity. The results indicate that, if the HDR reservoir productivity equals expectations based on preliminary results from research projects to date, a 50 MWe HDR power facility at Roosevelt Hot Springs could generate power at cost competitive with coal-fired plants. However, it is imperative that the assumed productivity be demonstrated before funds are committed for a commercial facility. 72 refs., 39 figs., 38 tabs.

  18. Lithographic dry development using optical absorption

    DOE Patents [OSTI]

    Olynick, Deirdre; Schuck, P. James; Schmidt, Martin

    2013-08-20T23:59:59.000Z

    A novel approach to dry development of exposed photo resist is described in which a photo resist layer is exposed to a visible light source in order to remove the resist in the areas of exposure. The class of compounds used as the resist material, under the influence of the light source, undergoes a chemical/structural change such that the modified material becomes volatile and is thus removed from the resist surface. The exposure process is carried out for a time sufficient to ablate the exposed resist layer down to the layer below. A group of compounds found to be useful in this process includes aromatic calixarenes.

  19. Cold Vacuum Drying Facility - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization2Climate,CobaltCold Vacuum Drying

  20. Dry lake reveals evidence of Southwestern 'megadroughts'

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContract ManagementDiscovering HowAna MooreDrought-induced treeDry lake

  1. Dry Creek Ventures | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A Potential MicrohydroDistrict ofDongjin Semichem CoDow CorningDrive5Drum)Dry

  2. Dry Process Electrode Fabrication | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No53197E TDrew Bittner About Us Drew BittnerHomeDry Process

  3. dry-regen | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, , ., ..., ,+ .-detonation7 ComparisonDry Regenerable

  4. Dynamic modeling and control of a solid-sorbent CO{sub 2} capture process with two-stage bubbling fluidized bed adsorber reactor

    SciTech Connect (OSTI)

    Modekurti, S.; Bhattacharyya, D.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Solid-sorbent-based CO{sub 2} capture processes have strong potential for reducing the overall energy penalty for post-combustion capture from the flue gas of a conventional pulverized coal power plant. However, the commercial success of this technology is contingent upon it operating over a wide range of capture rates, transient events, malfunctions, and disturbances, as well as under uncertainties. To study these operational aspects, a dynamic model of a solid-sorbent-based CO{sub 2} capture process has been developed. In this work, a one-dimensional (1D), non-isothermal, dynamic model of a two-stage bubbling fluidized bed (BFB) adsorber-reactor system with overflow-type weir configuration has been developed in Aspen Custom Modeler (ACM). The physical and chemical properties of the sorbent used in this study are based on a sorbent (32D) developed at National Energy Technology Laboratory (NETL). Each BFB is divided into bubble, emulsion, and cloud-wake regions with the assumptions that the bubble region is free of solids while both gas and solid phases coexist in the emulsion and cloud-wake regions. The BFB dynamic model includes 1D partial differential equations (PDEs) for mass and energy balances, along with comprehensive reaction kinetics. In addition to the two BFB models, the adsorber-reactor system includes 1D PDE-based dynamic models of the downcomer and outlet hopper, as well as models of distributors, control valves, and other pressure-drop devices. Consistent boundary and initial conditions are considered for simulating the dynamic model. Equipment items are sized and appropriate heat transfer options, wherever needed, are provided. Finally, a valid pressure-flow network is developed and a lower-level control system is designed. Using ACM, the transient responses of various process variables such as flue gas and sorbent temperatures, overall CO{sub 2} capture, level of solids in the downcomer and hopper have been studied by simulating typical disturbances such as change in the temperature, flowrate, and composition of the flue gas. To maintain the overall CO{sub 2} capture at a desired level in face of the typical disturbances, two control strategies were considered–a proportional-integral-derivative (PID)-based feedback control strategy and a feedforward-augmented feedback control strategy. Dynamic simulation results show that both the strategies result in unacceptable overshoot/undershoot and a long settling time. To improve the control system performance, a linear model predictive controller (LMPC) is designed. In summary, the overall results illustrate how optimizing the operation and control of carbon capture systems can have a significant impact on the extent and the rate at which commercial-scale capture processes will be scaled-up, deployed, and used in the years to come.

  5. Analysis of environment, safety, and health (ES{ampersand}H) management systems for Department of Energy (DOE) Defense Programs (DP) facilities

    SciTech Connect (OSTI)

    Neglia, A. V., LLNL

    1998-03-01T23:59:59.000Z

    The purpose of this paper is to provide a summary analysis and comparison of various environment, safety, and health (ES&H) management systems required of, or suggested for use by, the Departrnent of Energy Defense Programs` sites. The summary analysis is provided by means of a comparison matrix, a set of Vean diagrams that highlights the focus of the systems, and an `End Gate` filter diagram that integrates the three Vean diagrams. It is intended that this paper will act as a starting point for implementing a particular system or in establishing a comprehensive site-wide integrated ES&H management system. Obviously, the source documents for each system would need to be reviewed to assure proper implementation of a particular system. The matrix compares nine ES&H management systems against a list of elements generated by identifying the unique elements of all the systems. To simplify the matrix, the elements are listed by means of a brief title. An explanation of the matrix elements is provided in Attachment 2 entitled, `Description of System Elements.` The elements are categorized under the Total Quality Management (TQM) `Plan, Do, Check, Act` framework with the added category of `Policy`. (The TQM concept is explained in the `DOE Quality Management implementation Guidelines,` July 1997 (DOE/QM- 0008)). The matrix provides a series of columns and rows to compare the unique elements found in each of the management systems. A `V` is marked if the element is explicitly identified as part of the particular ES&H management system. An `X` is marked if the element is not found in the particular ES&H management system, or if it is considered to be inadequately addressed. A `?` is marked if incorporation of the element is not clear. Attachment I provides additional background information which explains the justification for the marks in the matrix cells. Through the Vean diagrams and the `End Gate` filter in Section 3, the paper attempts to pictorially display the focus of each system with respect to ES&H, the hazard of concern, and any limitations with respect to the TQM categories. A summary evaluation and explanation of each of the systems is provided in Section 4 of the paper. Several other ES&H systems were reviewed in preparation of the paper, but were not specifically included as a system in this matrix. Only those ES&H management systems that are potentially applicable to DOE Defense Program sites were included as part of the matrix comparison. A description of other ES&H management systems that were evaluated, but not specifically incorporated in this matrix comparison, are provided in Attachment 3 entitled, `Other ES&H Management Systems Reviewed.` In the past, it has been difficult integrating ES&H into work planning for several reasons. One barrier to this integration has been the complexity caused by the existence of several `stove pipe` ES&H systems. By analyzing the unique elements of the various ES&H systems, as well as their strengths and limitations, and their similarities and differences, it is envisioned that this paper will aid in facilitating the integration of ES&H into work planning. This paper was developed by the Office of Defense Programs (DP-45) and all questions or comments should be directed to Anthony Neglia of that office at (301) 903-3531 or Anthony.Neglia@dp.doe.gov.

  6. Self drying roofs: What! No dripping!

    SciTech Connect (OSTI)

    Desjarlais, A.

    1995-12-31T23:59:59.000Z

    Many roofs are replaced because water accumulates in portions of the roofing system.These accumulations can cause dripping, accelerated membrane failure, poor thermal performance, the threat of structural decay, and the depreciation of building assets. Traditionally, the roofing industry has been concerned with controlling the inflow of water into the roof. An example of this strategy would be the development of a more reliable membrane. However, roof membranes inevitably leak. For this reason, the roof design strategy of the future must be concerned with controlling water outflow. The requirements of this type of roof system are described. Under normal operating conditions (no leaks), the total moisture content of a self-drying roof system shall not increase with time and condensation shall not occur under the membrane during winter uptake. Moisture vapor movement by convection must be eliminated and the flow of water by gravity through imperfections in the roof system must be controlled. After a leak has occurred, no condensation on the upper surface of the deck shall be tolerated and the water introduced by the leak must be dissipated to the building interior in a minimum amount of time. Finite difference computer modeling is used to demonstrate the effectiveness of the design. The impact of deck and insulation permeance, climate, leaks, and wintertime water uptake are simulated. A database of simulations is qualitatively described; this database will be used in future work to produce a simplified means of assessing the design parameters of a self-drying roof system.

  7. Storage capacity in hot dry rock reservoirs

    DOE Patents [OSTI]

    Brown, Donald W. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    A method of extracting thermal energy, in a cyclic manner, from geologic strata which may be termed hot dry rock. A reservoir comprised of hot fractured rock is established and water or other liquid is passed through the reservoir. The water is heated by the hot rock, recovered from the reservoir, cooled by extraction of heat by means of heat exchange apparatus on the surface, and then re-injected into the reservoir to be heated again. Water is added to the reservoir by means of an injection well and recovered from the reservoir by means of a production well. Water is continuously provided to the reservoir and continuously withdrawn from the reservoir at two different flow rates, a base rate and a peak rate. Increasing water flow from the base rate to the peak rate is accomplished by rapidly decreasing backpressure at the outlet of the production well in order to meet periodic needs for amounts of thermal energy greater than a baseload amount, such as to generate additional electric power to meet peak demands. The rate of flow of water provided to the hot dry rock reservoir is maintained at a value effective to prevent depletion of the liquid

  8. Storage capacity in hot dry rock reservoirs

    DOE Patents [OSTI]

    Brown, D.W.

    1997-11-11T23:59:59.000Z

    A method is described for extracting thermal energy, in a cyclic manner, from geologic strata which may be termed hot dry rock. A reservoir comprised of hot fractured rock is established and water or other liquid is passed through the reservoir. The water is heated by the hot rock, recovered from the reservoir, cooled by extraction of heat by means of heat exchange apparatus on the surface, and then re-injected into the reservoir to be heated again. Water is added to the reservoir by means of an injection well and recovered from the reservoir by means of a production well. Water is continuously provided to the reservoir and continuously withdrawn from the reservoir at two different flow rates, a base rate and a peak rate. Increasing water flow from the base rate to the peak rate is accomplished by rapidly decreasing backpressure at the outlet of the production well in order to meet periodic needs for amounts of thermal energy greater than a baseload amount, such as to generate additional electric power to meet peak demands. The rate of flow of water provided to the hot dry rock reservoir is maintained at a value effective to prevent depletion of the liquid inventory of the reservoir. 4 figs.

  9. Effects of H{sub 2}O and particles on the simultaneous removal of SO{sub 2} and fly ash using a fluidized-bed sorbent/catalyst reactor

    SciTech Connect (OSTI)

    Rau, J.Y.; Chen, J.C.; Wey, M.Y.; Lin, M.D. [National Chung Hsing University, Taichung (Taiwan). Dept. of Environmental Engineering

    2009-12-15T23:59:59.000Z

    This study investigated the potential of a fluidized-bed sorbent/catalyst reactor for the simultaneous removals of SO{sub 2} and fly ash from a simulated flue gas containing different H{sub 2}O and particles. Experimental results showed that the removal efficiency of particles and SO{sub 2} was 85%-96% and 5.75-2.97 mg SO{sub 2}/g, respectively, as the H{sub 2}O content was 1.5-5.3%. The activities of sorbent/catalysts for simultaneous removals of SO{sub 2} and particles were inhibited by H{sub 2}O and particles, and the inhibition effects increased with the content of H{sub 2}O. As the H{sub 2}O content increased, the particle size distribution (PSD) of fine particles shifted to the coarse particles. The results of BET analysis show that the obstruction phenomenon of the sorbent/catalyst caused by the particles was diminished with the increased content of H{sub 2}O. The results showed this aggregation phenomenon of fine particles shifted to the coarse particles may cause increased water vapor content in fluidized-bed sorbent/catalyst reactor.

  10. Heat Transfer Performance of a Dry and Wet / Dry Advanced Cooling Tower Condenser

    E-Print Network [OSTI]

    Fricke, H. D.; Webster, D. J.; McIlroy, K.; Bartz, J. A.

    1981-01-01T23:59:59.000Z

    This paper describes an EPRI-funded experimental evaluation of advanced air-cooled ammonia condensers for a phase. Change dry/wet cooling system for power plants. Two condenser surfaces with different air-side augmentation were tested in an ammonia...

  11. Mathematical and experimental modelling of heat pump assisted microwave drying

    SciTech Connect (OSTI)

    Xiguo Jia (Univ. of Queensland (Australia))

    1993-01-01T23:59:59.000Z

    Drying is one of the most energy intensive operations in industry and agriculture. In the quest to increase drying efficiency and product quality, new technologies and methods are constantly being sought. Of these technologies, heat pump assisted drying and microwave drying have proved to be the most promising contenders. In order to achieve a better understanding and provide a computer design tool for heat pump assisted convective and microwave drying, both mathematical modelling and experimental investigations of heat pump assisted microwave dryers have been undertaken in this study. A mathematical model has been developed to predict the steady-state performance of a heat pump assisted continuous microwave dryer, with emphasis on the simulation of heat and mass transfer processes in the evaporator and drying chamber. The model is intend to serve as a design tool in the study of heat pump dryers. To achieve the optimum design, the influences of the key design and operating parameters, as well as the comparison of different drying configurations, have been examined. Based on investigation results, several methods have been proposed to improve the performance of heat pump assisted microwave drying, such as the use of a recuperator. To validate the above mathematical model, extensive drying tests using foam rubber as the test material have been conducted on a prototype heat pump assisted microwave dryer. The prototype heat pump input power was 5 kW with a maximum microwave input power of 10 kW. The experimental performance data confirmed the veracity of the simulation model. The experimental results on drying test materials indicate that with careful design heat pump assisted microwave drying is comparable to convective drying in energy consumption while with a much higher drying speed.

  12. Dynamics of Dry Friction: A Numerical Investigation

    E-Print Network [OSTI]

    Y. F. Lim; Kan Chen

    1998-03-18T23:59:59.000Z

    We perform extended numerical simulation of the dynamics of dry friction, based on a model derived from the phenomenological description proposed by T. Baumberger et al.. In the case of small deviation from the steady sliding motion, the model is shown to be equivalent to the state- and rate-dependent friction law which was first introduced by Rice and Ruina on the basis of experiments on rocks. We obtain the dynamical phase diagram that agrees well with the experimental results on the paper-on-paper systems. In particular, the bifurcation between stick-slip and steady sliding are shown to change from a direct (supercritical) Hopf type to an inverted (subcritical) one as the driving velocity increases, in agreement with the experiments.

  13. Dry lubricant films for aluminum forming.

    SciTech Connect (OSTI)

    Wei, J.; Erdemir, A.; Fenske, G. R.

    1999-03-30T23:59:59.000Z

    During metal forming process, lubricants are crucial to prevent direct contact, adhesion, transfer and scuffing of workpiece materials and tools. Boric acid films can be firmly adhered to the clean aluminum surfaces by spraying their methanol solutions and provide extremely low friction coefficient (about 0.04). The cohesion strengths of the bonded films vary with the types of aluminum alloys (6061, 6111 and 5754). The sheet metal forming tests indicate that boric acid films and the combined films of boric acid and mineral oil can create larger strains than the commercial liquid and solid lubricants, showing that they possess excellent lubricities for aluminum forming. SEM analyses indicate that boric acid dry films separate the workpiece and die materials, and prevent their direct contact and preserve their surface qualities. Since boric acid is non-toxic and easily removed by water, it can be expected that boric acid films are environmentally friendly, cost effective and very efficient lubricants for sheet aluminum cold forming.

  14. Curing and drying effects upon the quality of Spanish peanuts

    E-Print Network [OSTI]

    Aristizabal, Leon

    1968-01-01T23:59:59.000Z

    . Treatments . Atmospheric Drying Pr ewa s hing Vacuum Drying Air Separation Roasting Chemical Analyses Moisture Content Oil Content Reducing Sugars Physical Analyses Surface Color Percent Transmittance of the Oil Tenure . Density Organoleptic... PEANUTS 48 Table Pa ge THE EFFECTS OF VACUUM DRYING TREAT- MENTS ON THE ORGANOLEPTIC AND PHYSICAL ATTRIBUTES OF IMMATURE (I) AND MATURE (M) SPANISH PEANUTS 52 10 SIMPLE CORRELATIONS AMONG THE CHEMICAL, PHYSICA L AND ORGANOLEPTIC ATTRIBUTES...

  15. TAILORING INORGANIC SORBENTS FOR SRS STRONTIUM AND ACTINIDE SEPARATIONS: OPTIMIZED MONOSODIUM TITANATEPHASE II INTERIM REPORT FOR EXTERNAL RELEASE

    SciTech Connect (OSTI)

    Hobbs, D; Michael Poirier, M; Mark Barnes, M; Mary Thompson, M

    2006-08-31T23:59:59.000Z

    This document provides an interim summary report of Phase II testing activities for the development of a modified monosodium titanate (MST) that exhibits improved strontium and actinide removal characteristics compared to the baseline MST materials. The activities included determining the key synthesis conditions for preparation of the modified MST, preparation of the modified MST at a larger laboratory scale, demonstration of the strontium and actinide removal characteristics with actual tank waste supernate and characterization of the modified MST. Key findings and conclusions include the following: (1) Samples of the modified MST prepared by Method 2 and Method 3 exhibited the best combination of strontium and actinide removal. (2) We selected Method 3 to scale up and test performance with actual waste solution. (3) We successfully prepared three batches of the modified MST using the Method 3 procedure at a 25-gram scale. (4) Performance tests indicated successful scale-up to the 25-gram scale with excellent performance and reproducibility among each of the three batches. For example, the plutonium decontamination factors (6-hour contact time) for the modified MST samples averaged 13 times higher than that of the baseline MST sample at half the sorbent concentration (0.2 g L{sup -1} for modified MST versus 0.4 g L{sup -1} for baseline MST). (5) Performance tests with actual waste supernate demonstrated that the modified MST exhibited better strontium and plutonium removal performance than that of the baseline MST. For example, the decontamination factors for the modified MST measured 2.6 times higher for strontium and between 5.2 to 11 times higher for plutonium compared to the baseline MST sample. The modified MST did not exhibit improved neptunium removal performance over that of the baseline MST. (6) Two strikes of the modified MST provided increased removal of strontium and actinides from actual waste compared to a single strike. The improved performance exhibited by the modified MST indicates that fewer strikes of the modified MST would be needed to successfully treat waste that contain very high activities of {sup 90}Sr and alpha-emitting radionuclides compared to the baseline MST. (7) Reuse tests with actual waste confirmed that partially loaded MST exhibits reduced removal of strontium and actinides when contacted with fresh waste. (8) Samples of modified MST prepared by Method 3 and the baseline MST exhibited very similar particle size distributions. (9) Dead-end filtration tests showed that the modified MST samples exhibited similar filtration characteristics as the baseline MST sample. (10) Performance testing indicated no change in strontium and neptunium removal after storing the modified MST for 6-months at ambient temperature. The results suggested that plutonium removal performance may be decreased slightly after 6-months of storage. However, the change in plutonium removal is not statistically significant at the 95% confidence limit. Based on these findings we recommend continued development of the modified MST as a replacement for the baseline MST for waste treatment facilities at the Savannah River Site.

  16. High Burnup Dry Storage Cask Research and Development Project...

    Broader source: Energy.gov (indexed) [DOE]

    potentially significant impact on nuclear plant licensing and operations. While dry storage of lower burnup SNF less than 45 gigawatt days per metric ton uranium (GWD MTU)...

  17. antarctic dry valley: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UK b Department of Geological Sciences and Institute.V. All rights reserved. Keywords: Uranium isotopes; Dry Valleys; Antarctica; Weathering; Lake chemistry 1 isotopes. The supply...

  18. antarctic dry valleys: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UK b Department of Geological Sciences and Institute.V. All rights reserved. Keywords: Uranium isotopes; Dry Valleys; Antarctica; Weathering; Lake chemistry 1 isotopes. The supply...

  19. Reservoir Investigations on the Hot Dry Rock Geothermal System...

    Open Energy Info (EERE)

    Mexico- Tracer Test Results Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Reservoir Investigations on the Hot Dry Rock Geothermal System,...

  20. aerosol dry deposition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    43 Drying and deposition of poly(ethylene oxide) droplets determined by Pclet number Condensed Matter (arXiv) Summary: We report results of a detailed experimental...

  1. atmospheric dry deposition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    water vapor, and we confirm such predictions in a numerical model. There have been a number 38 Dual nitrate isotopes in dry deposition: Utility for partitioning NOx source...

  2. Vehicle Technologies Office Merit Review 2014: Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dry process electrode...

  3. Membranes and MEAs for Dry, Hot Operating Conditions

    Broader source: Energy.gov (indexed) [DOE]

    durability and performance characteristics making them useful in stationary fuel cell applications. Membranes and MEA's for Dry, Hot Operating Conditions - Kick off 4 3...

  4. Water volume okay; early runoff leads to dry year declaration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water-volume-okay-early-runoff-leads-to-dry-year-declaration Sign In About | Careers | Contact | Investors | bpa.gov Search News & Us Expand News & Us Projects & Initiatives...

  5. Vehicle Technologies Office Merit Review 2015: Dry Process Electrode Fabrication

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dry process electrode...

  6. Gas Composition Transients in the Cold Vacuum Drying (CVD) Facility

    SciTech Connect (OSTI)

    PACKER, M.J.

    1999-07-01T23:59:59.000Z

    Calculations with plotted results presented as confirmation bases for selected problems involving the prediction of transient gas compositions during Cold Vacuum Drying Operations.

  7. ,"New York Dry Natural Gas Reserves Extensions (Billion Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Extensions (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

  8. ,"New York Dry Natural Gas Reserves New Field Discoveries (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)",1,"Annual",2013...

  9. ,"New York Dry Natural Gas Reserves Acquisitions (Billion Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Acquisitions (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

  10. ,"New York Dry Natural Gas Reserves Estimated Production (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Estimated Production (Billion Cubic Feet)",1,"Annual",2013...

  11. ,"New York Dry Natural Gas Reserves Revision Decreases (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Revision Decreases (Billion Cubic Feet)",1,"Annual",2013...

  12. ,"New York Dry Natural Gas Reserves Sales (Billion Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Sales (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

  13. ,"New York Dry Natural Gas Reserves Adjustments (Billion Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Adjustments (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

  14. ,"New York Dry Natural Gas Reserves Revision Increases (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Dry Natural Gas Reserves Revision Increases (Billion Cubic Feet)",1,"Annual",2013...

  15. air dried soil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    102 Concentration, size distribution, and dry deposition rate of particle-associated metals in the Los Angeles region University of California eScholarship Repository Summary:...

  16. Hydrogen storage materials and method of making by dry homogenation

    DOE Patents [OSTI]

    Jensen, Craig M. (Kailua, HI); Zidan, Ragaiy A. (Honolulu, HI)

    2002-01-01T23:59:59.000Z

    Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

  17. Fundamental mechanisms in flue-gas conditioning. Topical report No. 1, Literature review and assembly of theories on the interactions of ash and FGD sorbents

    SciTech Connect (OSTI)

    Dahlin, R.S.; Vann Bush, P.; Snyder, T.R.

    1992-01-09T23:59:59.000Z

    The overall goal of this research project is to formulate a mathematical model of flue gas conditioning. This model will be based on an understanding of why ash properties, such as cohesivity and resistivity, are changed by conditioning. Such a model could serve as a component of the performance models of particulate control devices where flue gas conditioning is used. There are two specific objectives of this research project, which divide the planned research into two main parts. One part of the project is designed to determine how ash particles are modified by interactions with sorbent injection processes and to describe the mechanisms by which these interactions affect fine particle collection. The objective of the other part of the project is to identify the mechanisms by which conditioning agents, including chemically active compounds, modify the key properties of fine fly ash particles.

  18. Development of Dodecaniobate Keggin Chain Materials as Alternative Sorbents for SR and Actinide Removal from High-Level Nuclear Waste Solutions

    SciTech Connect (OSTI)

    Nyman, May; Bonhomme, Francois

    2004-03-28T23:59:59.000Z

    The current baseline sorbent (monosodium titanate) for Sr and actinide removal from Savannah River Site's high level wastes has excellent adsorption capabilities for Sr but poor performance for the actinides. We are currently investigating the development of alternative materials that sorb radionuclides based on chemical affinity and/or size selectivity. The polyoxometalates, negatively-charged metal oxo clusters, have known metal binding properties and are of interest for radionuclide sequestration. We have developed a class of Keggin-ion based materials, where the Keggin ions are linked in 1- dimensional chains separated by hydrated, charge-balancing cations. These Nb-based materials are stable in the highly basic nuclear waste solutions and show good selectivity for Sr and Pu. Synthesis, characterization and structure of these materials in their native forms and Sr-exchanged forms will be presented.

  19. Integrated dry NO{sub x}/SO{sub 2} emissions control system: integrated system test report

    SciTech Connect (OSTI)

    Smith, R.A.; Muzio, L.J. [Fossil Energy Research Corp., Laguna Hills, CA (United States); Hunt, T. [Public Service Co. of Colorado, Denver, CO (United States)

    1997-04-01T23:59:59.000Z

    The DOE sponsored Integrated Dry NO{sub x}/SO{sub 2} Emissions Control System Program, is a Clean Coal Technology III demonstration, being conducted by Public Service Company of Colorado. The test site is Arapahoe Generating Station Unit 4, a 100 MWe, down-fired utility boiler burning a low-sulfur Western coal. The project goal is to demonstrate up to 70 percent reductions in NO{sub x} and SO{sub 2} emissions through the integration of: (1) down-fired low NO{sub x} burners with overfire air; (2) Selective Non-Catalytic Reduction (SNCR) for additional NO{sub x} removal; and (3) Dry Sorbent Injection (DSI) and duct humidification for SO{sub 2} removal. This report documents the final phase of the test program, in which the overall performance of the integrated system was evaluated. Previous testing has shown that the goal of 70 percent NO{sub x} removal was easily achieved with the combination of low-NO{sub x} burners, overfire air, and urea-based SNCR. Similarly, the ability of the sodium-based DSI system to achieve 70 percent SO{sub 2} removal was also demonstrated previously. The integrated tests demonstrated the synergistic benefit of operating the SNCR and sodium-based DSI systems concurrently. With the automatic control system set to limit the NH{sub 3} emissions to less than 8 ppm, the NO{sub 2} emissions from the sodium-based DSI system were reduced by nominally 50 percent compared to operation with the DSI system alone. Comparably, the combined operation reduced NH{sub 3} emissions, as reflected by a higher urea injection rate for a fixed NH{sub 3} emission limit. With combined DSI and SNCR operation, an ammonia odor problem was encountered around the Unit 4 ash silo (this did not occur with the SNCR system operated alone at comparable NH{sub 3} slip levels). This odor problem is attributed to the sodium changing the rate at which NH{sub 3} is released from the ash when it is wetted for truck transport to the disposal site.

  20. Penetration rate prediction for percussive drilling via dry friction model

    E-Print Network [OSTI]

    Krivtsov, Anton M.

    Penetration rate prediction for percussive drilling via dry friction model Anton M. Krivtsov a of percussive drilling assuming a dry friction mechanism to explain the experimentally observed drop in pene as a frictional pair, and this can generate the pattern of the impact forces close to reality. Despite quite

  1. Biomass Logistics and Particle Technology Group Purdue Improved Drying

    E-Print Network [OSTI]

    Ginzel, Matthew

    to maintain quality of grain in storage. n Farmers primarily depended on open air solar drying after logistics Grain & pest management Pre-Harvest losses from: Insect, molds and birds Harvesting & handling of PICS, technology Open Air Solar Drying of Maize in Ejura Market, Ashanti Region, Ghana #12;4 Chronology

  2. Horizontal Air Flow Drying Foods at Home Safely

    E-Print Network [OSTI]

    Horizontal Air Flow Drying Foods at Home Safely Choosing a Food Dehydrator Drying is one. The thermostat should go up to 160 degrees F. The unit should have a fan or blower for air circulation. Mesh purposes. Types of Dehydrators There are two main types of dehydrators: those with vertical air flow

  3. How to make dried blood dots for genetic studies

    E-Print Network [OSTI]

    Schall, Joseph J.

    How to make dried blood dots for genetic studies If a vertebrate is in-hand, and blood being taken, it is easy to make both a blood smear and dried blood dots. Modern research on malaria parasites demands that BOTH a blood smear and blood samples be taken. Blood can be stored in lysis buffers of various kinds

  4. RISO-M-2438 Dry deposition and resuspension of

    E-Print Network [OSTI]

    CO RISO-M-2438 2 S Dry deposition and resuspension of particulate matter in city environments N 1984 fĺ #12;RISŘ-M-2438 DRY DEPOSITION AND RESUSPENSION OF PARITUCLATE NATTER IN CITY ENVIRONMENTS N.O. Jensen Abstract. The report describes, mostly in qualitative terms, the deposition and resuspension

  5. Moisture Distribution and Flow During Drying of Wood and Fiber

    SciTech Connect (OSTI)

    Zink-Sharp, Audrey; Hanna, Robert B.

    2001-12-28T23:59:59.000Z

    New understanding, theories, and techniques for moisture flow and distribution were developed in this research on wood and wood fiber. Improved understanding of the mechanisms of flake drying has been provided. Observations of flake drying and drying rate curves revealed that rate of moisture loss consisted of two falling rate periods and no constant rate drying period was observed. Convective heat transfer controls the first period, and bound water diffusion controls the second period. Influence of lower drying temperatures on bending properties of wood flakes was investigated. Drying temperature was found to have a significant influence on bending stiffness and strength. A worksheet for calculation of the energy required to dry a single strandboard flake was developed but has not been tested in an industrial setting yet. A more complete understanding of anisotropic transverse shrinkage of wood is proposed based on test results and statistical analysis. A simplified mod el of a wood cell's cross-section was drawn for calculating differential transverse shrinkage. The model utilizes cell wall thickness and microfibrillar packing density and orientation. In spite of some phenomena of cell wall structure not yet understood completely, the results might explain anisotropic transverse shrinkage to a major extent. Boundary layer theory was found useful for evaluating external moisture resistance during drying. Simulated moisture gradients were quire comparable to the actual gradients in dried wood. A mathematical procedure for determining diffusion and surface emission coefficients was also developed. Thermal conductivity models of wood derived from its anatomical structure were created and tested against experimental values. Model estimations provide insights into changes in heat transfer parameters during drying. Two new techniques for measuring moisture gradients created in wood during drying were developed. A new technique that utilizes optical properties of cobalt chloride was developed for nondestructive determination of surface moisture content. Fundamental new understanding of drying characteristics in wood and fiber has been provided that can be used by researchers to improve drying of wood and fiber. The three techniques for measuring moisture content and gradients provided in this study are efficient, practical, and economical - easy to apply by industry and researchers. An energy consumption worksheet is provided as a first step toward reducing energy consumed during drying of lumber and strandboard flakes. However, it will need additional verification and testing.

  6. Heat transfer modeling of dry spent nuclear fuel storage facilities

    SciTech Connect (OSTI)

    Lee, S.Y.

    1999-07-01T23:59:59.000Z

    The present work was undertaken to provide heat transfer model that accurately predicts the thermal performance of dry spent nuclear fuel storage facilities. One of the storage configurations being considered for DOE Aluminum-clad Spent Nuclear Fuel (Al-SNF), such as the Material and Testing Reactor (MTR) fuel, is in a dry storage facility. To support design studies of storage options a computational and experimental program has been conducted at the Savannah River Site (SRS). The main objective is to develop heat transfer models including natural convection effects internal to an interim dry storage canister and to geologic codisposal Waste Package (WP). Calculated temperatures will be used to demonstrate engineering viability of a dry storage option in enclosed interim storage and geologic repository WP and to assess the chemical and physical behaviors of the Al-SNF in the dry storage facilities. The current paper describes the modeling approaches and presents the computational results along with the experimental data.

  7. Heat Transfer Modeling of Dry Spent Nuclear Fuel Storage Facilities

    SciTech Connect (OSTI)

    Lee, S.Y.

    1999-01-13T23:59:59.000Z

    The present work was undertaken to provide heat transfer model that accurately predicts the thermal performance of dry spent nuclear fuel storage facilities. One of the storage configurations being considered for DOE Aluminum-clad Spent Nuclear Fuel (Al-SNF), such as the Material and Testing Reactor (MTR) fuel, is in a dry storage facility. To support design studies of storage options a computational and experimental program has been conducted at the Savannah River Site (SRS). The main objective is to develop heat transfer models including natural convection effects internal to an interim dry storage canister and to geological codisposal Waste Package (WP). Calculated temperatures will be used to demonstrate engineering viability of a dry storage option in enclosed interim storage and geological repository WP and to assess the chemical and physical behaviors of the Al-SNF in the dry storage facilities. The current paper describes the modeling approaches and presents the computational results along with the experimental data.

  8. The US Hot Dry Rock project

    SciTech Connect (OSTI)

    Hendron, R.H.

    1987-01-01T23:59:59.000Z

    The Hot Dry Rock geothermal energy project began in the early 1970's with the objective of developing a technology to make economically available the large ubiquitous thermal energy of the upper earth crust. The program has been funded by the Department of Energy (and its predecessors) and for a few years with participation by West Germany and Japan. An energy reservoir was accessed by drilling and hydraulically fracturing in the precambrian basement rock outside the Valles Caldera of north-central New Mexico. Water was circulated through the reservoir (Phase I, 1978-1980) producing up to 5 MWt at 132/sup 0/C. A second (Phase II) reservoir has been established with a deeper pair of holes and an initial flow test completed producing about 10 MWt at 190/sup 0/C. These accomplishments have been supported and paralleled by developments in drilling, well completion and instrumentation hardware. Acoustic or microseismic fracture mapping and geochemistry studies in addition to hydraulic and thermal data contribute to reservoir analyses. Studies of some of the estimated 430,000 quads of HDR resources in the United States have been made with special attention focused on sites most advantageous for early development.

  9. DRY TRANSFER FACILITY WORKER DOSE ASSESSMENT

    SciTech Connect (OSTI)

    J.S. Tang

    2004-09-23T23:59:59.000Z

    The purpose of this calculation is to estimate radiation doses received by personnel working in the Dry Transfer Facility No.1 (DTF-1) performing operations to receive transportation casks, transfer wastes, prepare waste packages, and ship out loaded waste packages and empty casks. Doses received by workers due to maintenance operations are also included in this revision. The specific scope of work contained in this calculation covers both collective doses and individual worker group doses on an annual basis, and includes the contributions due to external and internal radiation from normal operation, excluding the remediation area of the building. The results of this calculation will be used to support the design of the DTF-1 and to provide occupational dose estimates for the License Application. The calculations contained in this document were developed by Environmental and Nuclear Engineering of the Design and Engineering Organization and are intended solely for the use of the Design and Engineering Organization in its work regarding facility operation. Yucca Mountain Project personnel from the Environmental and Nuclear Engineering should be consulted before use of the calculations for purposes other than those stated herein or use by individuals other than authorized personnel in the Environmental and Nuclear Engineering.

  10. Thermal Analysis of a Dry Storage Concept for Capsule Dry Storage Project

    SciTech Connect (OSTI)

    JOSEPHSON, W S

    2003-09-04T23:59:59.000Z

    There are 1,936 cesium (Cs) and strontium (Sr) capsules stored in pools at the Waste Encapsulation and Storage Facility (WESF). These capsules will be moved to dry storage on the Hanford Site as an interim measure to reduce risk. The Cs/Sr Capsule Dry Storage Project is conducted under the assumption that the capsules will eventually be moved to the repository at Yucca Mountain, and the design criteria include requirements that will facilitate acceptance at the repository. The storage system must also permit retrieval of capsules in the event that vitrification of the capsule contents is pursued. The Capsule Advisory Panel (CAP) was created by the Project Manager for the Hanford Site Capsule Dry Storage Project (CDSP). The purpose of the CAP is to provide specific technical input to the CDSP; to identify design requirements; to ensure design requirements for the project are conservative and defensible; to identify and resolve emerging, critical technical issues, as requested; and to support technical reviews performed by regulatory organizations, as requested. The CAP will develop supporting and summary documents that can be used as part of the technical and safety bases for the CDSP. The purpose of capsule dry storage thermal analysis is to: (1) Summarize the pertinent thermal design requirements sent to vendors, (2) Summarize and address the assumptions that underlie those design requirements, (3) Demonstrate that an acceptable design exists that satisfies the requirements, (4) Identify key design features and phenomena that promote or impede design success, (5) Support other CAP analyses such as corrosion and integrity evaluations, and (6) Support the assessment of proposed designs. It is not the purpose of this report to optimize or fully analyze variations of postulated acceptable designs. The present evaluation will indicate the impact of various possible design features, but not systematically pursue design improvements obtainable through analysis refinements and/or relaxation of conservatisms. However, possible design improvements will be summarized for future application. All assumptions and related design features, while appropriate for conceptual designs, must be technically justified for the final design. The pertinent thermal design requirements and underlying assumptions are summarized in Section 1.3. The majority of the thermal analyses, as described in Sections 4.2 and 4.3, focus on an acceptable conceptual design arrived at by refinement of a preliminary but unacceptable design. The results of the subject thermal analyses, as presented in Section 4.0, satisfy items 3 and 4 above.

  11. Structural Sensitivity of Dry Storage Canisters

    SciTech Connect (OSTI)

    Klymyshyn, Nicholas A.; Karri, Naveen K.; Adkins, Harold E.; Hanson, Brady D.

    2013-09-27T23:59:59.000Z

    This LS-DYNA modeling study evaluated a generic used nuclear fuel vertical dry storage cask system under tip-over, handling drop, and seismic load cases to determine the sensitivity of the canister containment boundary to these loads. The goal was to quantify the expected failure margins to gain insight into what material changes over the extended long-term storage lifetime could have the most influence on the security of the containment boundary. It was determined that the tip-over case offers a strong challenge to the containment boundary, and identifies one significant material knowledge gap, the behavior of welded stainless steel joints under high-strain-rate conditions. High strain rates are expected to increase the material’s effective yield strength and ultimate strength, and may decrease its ductility. Determining and accounting for this behavior could potentially reverse the model prediction of a containment boundary failure at the canister lid weld. It must be emphasized that this predicted containment failure is an artifact of the generic system modeled. Vendor specific designs analyze for cask tip-over and these analyses are reviewed and approved by the Nuclear Regulatory Commission. Another location of sensitivity of the containment boundary is the weld between the base plate and the canister shell. Peak stresses at this location predict plastic strains through the whole thickness of the welded material. This makes the base plate weld an important location for material study. This location is also susceptible to high strain rates, and accurately accounting for the material behavior under these conditions could have a significant effect on the predicted performance of the containment boundary. The handling drop case was largely benign to the containment boundary, with just localized plastic strains predicted on the outer surfaces of wall sections. It would take unusual changes in the handling drop scenario to harm the containment boundary, such as raising the drop height or changing the impact angle. The seismic load case was derived from the August 23, 2011 earthquake that affected the North Anna power station. The source of the data was a monitoring station near Charlottesville, Virginia, so the ground motion is not an exact match. Stresses on the containment boundary were so low, even from a fatigue standpoint, that the seismic load case is generally not a concern. Based on this study, it is recommended that high strain rate testing of welded stainless steel test samples be pursued to define the currently unknown material behavior. Additional modeling is recommended to evaluate specific dry storage cask system designs subjected to tip-over loads using a high level of model detail. Additional modeling of the canister interior components (basket, fuel assemblies, etc.) is also recommended, to evaluate the feasibility of fuel retrievability after a tip-over incident. Finally, additional modeling to determine how much degradation a system could undergo and still maintain the integrity of the confinement barrier should be performed.

  12. Kinetics of the clay roofing tile convection drying

    SciTech Connect (OSTI)

    Thomas, S. (Univ. of Osijek (Croatia). Faculty of Food Technology); Skansi, D. (Univ. of Zagreb (Croatia). Faculty of Chemical Engineering and Technology); Sokele, M. (Croatian Post and Telecommunications, Zagreb (Croatia). Telecommunications Center)

    1993-01-01T23:59:59.000Z

    Kinetics of the convection drying process of flat tile has been investigated experimentally in an industrial tunnel dryer. Several velocities of wet tile movement through the dryer were tested to obtain maximum allowable drying rate curve. As there are various models to describe the kinetics of convection drying, finding a model that would fairly well approximate the kinetics of the whole drying process was part of the research. Especially the polynomial and exponential models were tested. It was found that exponential model of the type: B(t) = (a[minus]B[sub e])[center dot]EXP([minus]bt[sup 2])+B[sub e], ([minus]dB(t)/dt) = 2bt(B(t)[minus]B[sub e]) significantly correlates the kinetics of the whole tile drying process. Applying the maximum allowable drying rate curve obtained for flat tile in the first period of drying, a grapho-analytic model for the optimal conducting of the process has been developed.

  13. Energy-efficient regenerative liquid desiccant drying process

    DOE Patents [OSTI]

    Ko, Suk M. (Huntsville, AL); Grodzka, Philomena G. (Huntsville, AL); McCormick, Paul O. (Athens, AL)

    1980-01-01T23:59:59.000Z

    This invention relates to the use of desiccants in conjunction with an open oop drying cycle and a closed loop drying cycle to reclaim the energy expended in vaporizing moisture in harvested crops. In the closed loop cycle, the drying air is brought into contact with a desiccant after it exits the crop drying bin. Water vapor in the moist air is absorbed by the desiccant, thus reducing the relative humidity of the air. The air is then heated by the used desiccant and returned to the crop bin. During the open loop drying cycle the used desiccant is heated (either fossil or solar energy heat sources may be used) and regenerated at high temperature, driving water vapor from the desiccant. This water vapor is condensed and used to preheat the dilute (wet) desiccant before heat is added from the external source (fossil or solar). The latent heat of vaporization of the moisture removed from the desiccant is reclaimed in this manner. The sensible heat of the regenerated desiccant is utilized in the open loop drying cycle. Also, closed cycle operation implies that no net energy is expended in heating drying air.

  14. Steam atmosphere drying concepts using steam exhaust recompression

    SciTech Connect (OSTI)

    DiBella, F.A. (TECOGEN, Inc., Waltham, MA (United States))

    1992-08-01T23:59:59.000Z

    In the US industrial drying accounts for approximately 1.5 quads of energy use per year. Annual industrial dryer expenditures are estimated to be in the $500 million range. Industrial drying is a significant energy and monetary expense. For the thermal drying processes in which water is removed via evaporation from the feedstock, attempts have been made to reduce the consumption of energy using exhaust waste heat recovery techniques, improved dryer designs, or even the deployment of advanced mechanical dewatering techniques. Despite these efforts, it is obvious that a large amount of thermal energy is often still lost if the latent heat of evaporation from the evaporated water cannot be recovered and/or in some way be utilized as direct heat input into the dryer. Tecogen Inc. is conducting research and development on an industrial drying concept. That utilizes a directly or indirectly superheated steam cycle atmosphere with exhaust steam recompression to recover the latent heat in the exhaust that would otherwise be lost. This approach has the potential to save 55 percent of the energy required by a conventional air dryer. Other advantages to the industrial dryer user include: A 35-percent reduction in the yearly cost per kg[sub evap] to dry wet feedstock, Reduced airborne emissions, Reduced dry dust fire/explosion risks, Hot product not exposed to oxygen thus, the product quality is enhanced, Constant rate drying in steam atmosphere, Reduced dryer size and cost, Reduced dryer heat losses due to lower dryer inlet temperatures. Tecogen has projected that the steam atmosphere drying system is most suitable as a replacement technology for state-of-the-art spray, flash, and fluidized bed drying systems. Such systems are utilized in the food and kindred products; rubber products; chemical and allied products; stone, clay, and glass; textiles; and pulp and paper industrial sectors.

  15. Steam atmosphere drying concepts using steam exhaust recompression

    SciTech Connect (OSTI)

    DiBella, F.A. [TECOGEN, Inc., Waltham, MA (United States)

    1992-08-01T23:59:59.000Z

    In the US industrial drying accounts for approximately 1.5 quads of energy use per year. Annual industrial dryer expenditures are estimated to be in the $500 million range. Industrial drying is a significant energy and monetary expense. For the thermal drying processes in which water is removed via evaporation from the feedstock, attempts have been made to reduce the consumption of energy using exhaust waste heat recovery techniques, improved dryer designs, or even the deployment of advanced mechanical dewatering techniques. Despite these efforts, it is obvious that a large amount of thermal energy is often still lost if the latent heat of evaporation from the evaporated water cannot be recovered and/or in some way be utilized as direct heat input into the dryer. Tecogen Inc. is conducting research and development on an industrial drying concept. That utilizes a directly or indirectly superheated steam cycle atmosphere with exhaust steam recompression to recover the latent heat in the exhaust that would otherwise be lost. This approach has the potential to save 55 percent of the energy required by a conventional air dryer. Other advantages to the industrial dryer user include: A 35-percent reduction in the yearly cost per kg{sub evap} to dry wet feedstock, Reduced airborne emissions, Reduced dry dust fire/explosion risks, Hot product not exposed to oxygen thus, the product quality is enhanced, Constant rate drying in steam atmosphere, Reduced dryer size and cost, Reduced dryer heat losses due to lower dryer inlet temperatures. Tecogen has projected that the steam atmosphere drying system is most suitable as a replacement technology for state-of-the-art spray, flash, and fluidized bed drying systems. Such systems are utilized in the food and kindred products; rubber products; chemical and allied products; stone, clay, and glass; textiles; and pulp and paper industrial sectors.

  16. Meat Alternate Cookery: Eggs, Nuts, Soybeans, Dried Beans and Peas

    E-Print Network [OSTI]

    Sweeten, Mary K.

    1980-01-01T23:59:59.000Z

    sources of B vitamins . Nuts, because of the high fat content, are more readily digested if eaten in combination with cereals, vegetables or fruits . Dried beans and peas make nourishing dishes which are very filling. These legumes are good sources... . Soybeans are the best vegetable protein source to re place meat. Dry soybeans contain 1 V2 times as much protein as other dried beans and 11 times as much fat. Soybeans are limited in one of the essential amino acids so they must be combined...

  17. Insights into the historical construction of species-rich Mesoamerican seasonally dry tropical forests: the diversification

    E-Print Network [OSTI]

    Olson, Mark

    Insights into the historical construction of species-rich Mesoamerican seasonally dry tropical, Mesoamerica, niche conservatism, seasonally dry tropical forests. Summary · Mesoamerican arid biomes epitomize the vast species richness of Meso- american seasonally dry tropical forests (SDTFs), and to evaluate

  18. Drilling Complete on Australian Hot Dry Rock Project

    Broader source: Energy.gov [DOE]

    The first commercial attempt to create a commercial geothermal power plant using hot dry rock technology reached a crucial milestone on January 22, when a production well successfully reached its target depth.

  19. Technical and economical considerations of new DRI melting process

    SciTech Connect (OSTI)

    Ito, Shuzo; Tokuda, Koji; Sammt, F.; Gray, R.

    1997-12-31T23:59:59.000Z

    The new DRI melting process can effectively and economically produce high quality molten iron. This process utilizes hot charging of DRI directly from a reduction furnace into a dedicated new melting furnace. The molten iron from this DRI premelter can be charged into a steelmaking furnace, such as an electric arc furnace (EAF), where the molten iron, together with other iron sources, can be processed to produce steel. Alternatively the molten iron can be pigged or granulated for off-site merchant sales. Comprehensive research and development of the new process has been conducted including operational process simulation, melting tests using FASTMET DRI, slag technology development, and refractory corrosion testing. This paper describes the process concept, its operational characteristics and further applications of the process.

  20. Managing Aging Effects on Dry Cask Storage Systems for Extended...

    Broader source: Energy.gov (indexed) [DOE]

    Electric Grid Workshop, April 19-20, 2011 Before the House Energy and Commerce Subcommittee on Energy and Power Effects of Multiple Drying Cycles on HBU PWR Cladding Alloys...

  1. Disneyland’s Dry Cleaning Gets an Energy Efficient Upgrade

    Broader source: Energy.gov [DOE]

    As the provider of laundry and dry cleaning services for Disneyland Resort’s costumes and hospitality supply items, L&N Costume and Linen Service knows a little something about both quantity and quality.

  2. Cold Vacuum Drying (CVD) Facility Diesel Generator Fire Protection

    SciTech Connect (OSTI)

    SINGH, G.

    2000-04-25T23:59:59.000Z

    This Acceptance Test Procedure (ATP) has been prepared to demonstrate that the Fire Protection and Detection System installed by Project W-441 (Cold Vacuum Drying Facility and Diesel Generator Building) functions as required by project specifications.

  3. Precipitation scavenging, dry deposition, and resuspension. Volume 2. Proceedings

    SciTech Connect (OSTI)

    Pruppacher, H.R.; Semonin, R.G.; Slinn, W.G.N.

    1983-01-01T23:59:59.000Z

    Volume 2 of these proceedings contains papers on dry deposition and resuspension of airborne pollutants. Items within the scope of EDB have been entered separately into the data base. (ACR)

  4. ,"New York Dry Natural Gas Production (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,"(202) 586-8800",,,"2262015 9:22:39 AM" "Back to Contents","Data 1: New York Dry Natural Gas Production (Million Cubic Feet)" "Sourcekey","NA1160SNY2"...

  5. Supply chain management in the dry bulk shipping industry

    E-Print Network [OSTI]

    Nicholson, Bryan E. (Bryan Edward)

    2006-01-01T23:59:59.000Z

    This paper is intended to show the importance of supply chain management in the dry-bulk shipping industry. A hypothetical company, the Texas Grain and Bakery Corporation, was created. The values and calculations used are ...

  6. Cold Vacuum Drying (CVD) Facility, Diesel Generator Fire Protection

    E-Print Network [OSTI]

    Singh, G

    2000-01-01T23:59:59.000Z

    This Acceptance Test Procedure (ATP) has been prepared to demonstrate that the Fire Protection and Detection System installed by Project W-441 (Cold Vacuum Drying Facility and Diesel Generator Building) functions as required by project specifications.

  7. Drying studies for corroded DOE aluminum plate fuels

    SciTech Connect (OSTI)

    Lords, R.E.; Windes, W.E. [Idaho National Engineering Lab., Idaho Falls, ID (United States); Crepeau, J.C.; Sidwell, R.W. [Idaho Univ., Idaho Falls, ID (United States) Dept. of Mechanical Engineering

    1996-05-01T23:59:59.000Z

    The Idaho National Engineering Laboratory (INEL) currently stores a wide variety of spent nuclear fuel. The fuel was originally intended to be stored underwater for a short period of thermal cooling, then removed and reprocessed. However, it has been stored underwater for much longer thank originally anticipated. During this time dust and airborne desert soil have entered the oldest INEL pool, accumulating on the fuel. Also, the aluminum fuel cladding has corroded compromising the exposed surfaces of the fuel. Plans are now underway to move some the the more vulnerable aluminum plate type fuels into dry storage in an existing vented and filtered fuel storage facility. In preparation for dry storage of the fuel a drying and canning station is being built at the INEL. The two primary objectives of this facility are to determine the influence of corrosion products on the drying process and to establish temperature distribution inside the canister during heating.

  8. GEOLOGY O F THE NORTHERN PCIRT O F DRY MOUNTAXN,

    E-Print Network [OSTI]

    Seamons, Kent E.

    GEOLOGY O F THE NORTHERN PCIRT O F DRY MOUNTAXN, SOUTHERN UASCSTCH H Q - W T A X H E i i - UT&H #12;BRIGHAM YOUNG UNIVERSITY RESEARCH STUDIES Geology Seri,es Vol. 3 No. 2 April, 1956 GEOLOGY OF THE NORTHERN Department of Gedogy Provo, Utah #12;GEOLOGY OF THE NORTHERN PART OF DRY MOUNTAIN, SOUTHERN WASATCH M O U N

  9. Dry scrubber reduces SO sub 2 in calciner flue gas

    SciTech Connect (OSTI)

    Brown, G.W. (Refining Consulting Services, Englewood, CO (US)); Roderick, D. (Western Slope Refining Co., Fruita, CO (US)); Nastri, A. (NATEC Resources Inc., Dallas, TX (US))

    1991-02-18T23:59:59.000Z

    This paper discusses the installation of a dry sulfur dioxide scrubber for an existing petroleum coke calciner at its Fruita, Colo., refinery. The dry scrubbing process was developed by the power industry to help cope with the acid rain problem. It is the first application of the process in an oil refinery. The process could also remove SO{sub 2} from the flue gas of a fluid catalytic cracker, fluid coker, or other refinery sources.

  10. Dynamic Modeling and Control Studies of a Two-Stage Bubbling Fluidized Bed Adsorber-Reactor for Solid-Sorbent CO{sub 2} Capture

    SciTech Connect (OSTI)

    Modekurti, Srinivasarao; Bhattacharyya, Debangsu; Zitney, Stephen E.

    2013-07-31T23:59:59.000Z

    A one-dimensional, non-isothermal, pressure-driven dynamic model has been developed for a two-stage bubbling fluidized bed (BFB) adsorber-reactor for solid-sorbent carbon dioxide (CO{sub 2}) capture using Aspen Custom Modeler® (ACM). The BFB model for the flow of gas through a continuous phase of downward moving solids considers three regions: emulsion, bubble, and cloud-wake. Both the upper and lower reactor stages are of overflow-type configuration, i.e., the solids leave from the top of each stage. In addition, dynamic models have been developed for the downcomer that transfers solids between the stages and the exit hopper that removes solids from the bottom of the bed. The models of all auxiliary equipment such as valves and gas distributor have been integrated with the main model of the two-stage adsorber reactor. Using the developed dynamic model, the transient responses of various process variables such as CO{sub 2} capture rate and flue gas outlet temperatures have been studied by simulating typical disturbances such as change in the temperature, flowrate, and composition of the incoming flue gas from pulverized coal-fired power plants. In control studies, the performance of a proportional-integral-derivative (PID) controller, feedback-augmented feedforward controller, and linear model predictive controller (LMPC) are evaluated for maintaining the overall CO{sub 2} capture rate at a desired level in the face of typical disturbances.

  11. Proof of concept testing of an integrated dry injection system for SO sub x /NO sub x control

    SciTech Connect (OSTI)

    Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States). Environmental Services and Technologies Div.); Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))

    1990-01-01T23:59:59.000Z

    The objective of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the temperature range of 200{degrees}F--400{degrees}F. Identify the best NO{sub 2} suppressing additive among the group of ammonia, urea, and activated carbon.

  12. Proof of concept testing of an integrated dry injection system for SO sub x /NO sub x control

    SciTech Connect (OSTI)

    Helfritch, D.J.; Bortz, S.J. (Research-Cottrell, Inc., Somerville, NJ (United States). Environmental Services and Technologies Div.); Beittel, R. (Riley Stoker Corp., Worcester, MA (United States))

    1989-01-01T23:59:59.000Z

    The objectives of the subscale test program were designed to provide sorbent and additive selection guidance, and, in so doing, supply answers to the questions posed in the preceding section. The objectives are: Identify the best commercial hydrate sorbent and the best enhanced hydrate sorbent from a list of nine types, based upon S0{sub 2} removal at Ca/S=2. Determine the relative effectiveness of sodium sesquicarbonate versus sodium bicarbonate for S0{sub 2} and NO{sub x} control over the temperature range of 200{degrees}F--400{degrees}F. Identify the best NO{sub 2} suppressing additive among the group of ammonia, urea, and activated carbon.

  13. Water quality investigation of Kingston Fossil Plant dry ash stacking

    SciTech Connect (OSTI)

    Bohac, C.E.

    1990-04-01T23:59:59.000Z

    Changing to a dry ash disposal systems at Kingston Fossil Plant (KFP) raises several water quality issues. The first is that removing the fly ash from the ash pond could alter the characteristics of the ash pond discharge to the river. The second concerns proper disposal of the runoff and possibly leachate from the dry ash stack. The third is that dry ash stacking might change the potential for groundwater contamination at the KFP. This report addresses each of these issues. The effects on the ash pond and its discharge are described first. The report is intended to provide reference material to TVA staff in preparation of environmental review documents for new ash disposal areas at Kingston. Although the investigation was directed toward analysis of dry stacking, considerations for other disposal options are also discussed. This report was reviewed in draft form under the title Assessment of Kingston Fossil Plant Dry Ash Stacking on the Ash Pond and Groundwater Quality.'' 11 refs., 3 figs., 18 tabs.

  14. Hot dry rock energy: Hot dry rock geothermal development program. Progress report. Fiscal year 1993

    SciTech Connect (OSTI)

    Salazar, J.; Brown, M. [eds.

    1995-03-01T23:59:59.000Z

    Extended flow testing at the Fenton Hill Hot Dry Rock (HDR) test facility concluded in Fiscal Year 1993 with the completion of Phase 2 of the long-term flow test (LTFT) program. As is reported in detail in this report, the second phase of the LTFT, although only 55 days in duration, confirmed in every way the encouraging test results of the 112-day Phase I LTFT carried out in Fiscal Year 1992. Interim flow testing was conducted early in FY 1993 during the period between the two LTFT segments. In addition, two brief tests involving operation of the reservoir on a cyclic schedule were run at the end of the Phase 2 LTFT. These interim and cyclic tests provided an opportunity to conduct evaluations and field demonstrations of several reservoir engineering concepts that can now be applied to significantly increase the productivity of HDR systems. The Fenton Hill HDR test facility was shut down and brought into standby status during the last part of FY 1993. Unfortunately, the world`s largest, deepest, and most productive HDR reservoir has gone essentially unused since that time.

  15. Linear Extrusion 400 Tons/Day Dry Solids Pump

    SciTech Connect (OSTI)

    Kenneth Sprouse; David Matthews

    2008-04-30T23:59:59.000Z

    Pratt & Whitney Rocketdyne (PWR) has developed an innovative gasifier concept that uses rocket engine experience to significantly improve gasifier performance, life, and cost compared to current state-of-the-art systems. The PWR gasifier concept uses a compact and highly efficient (>50%) dry solids pump that has excellent availability (>99.5%). PWR is currently developing this dry solids pump under a U.S. Department of Energy (DOE) cooperative agreement. The conceptual design on two dry solids pumps were completed under this agreement and one pump concept was selected for preliminary design. A preliminary design review (PDR) of the selected pump was presented on September 20, 2007 to PWR management and numerous technical specialists. Feedback from the PDR review team has been factored into the design and a Delta-PDR was held on April 9, 2008.

  16. Spent nuclear fuel project cold vacuum drying facility operations manual

    SciTech Connect (OSTI)

    IRWIN, J.J.

    1999-05-12T23:59:59.000Z

    This document provides the Operations Manual for the Cold Vacuum Drying Facility (CVDF). The Manual was developed in conjunction with HNF-SD-SNF-SAR-002, Safety Analysis Report for the Cold Vacuum Drying Facility, Phase 2, Supporting Installation of Processing Systems (Garvin 1998) and, the HNF-SD-SNF-DRD-002, 1997, Cold Vacuum Drying Facility Design Requirements, Rev. 3a. The Operations Manual contains general descriptions of all the process, safety and facility systems in the CVDF, a general CVD operations sequence, and has been developed for the SNFP Operations Organization and shall be updated, expanded, and revised in accordance with future design, construction and startup phases of the CVDF until the CVDF final ORR is approved.

  17. Standard review plan for dry cask storage systems. Final report

    SciTech Connect (OSTI)

    NONE

    1997-01-01T23:59:59.000Z

    The Standard Review Plan (SRP) For Dry Cask Storage Systems provides guidance to the Nuclear Regulatory Commission staff in the Spent Fuel Project Office for performing safety reviews of dry cask storage systems. The SRP is intended to ensure the quality and uniformity of the staff reviews, present a basis for the review scope, and clarification of the regulatory requirements. Part 72, Subpart B generally specifies the information needed in a license application for the independent storage of spent nuclear fuel and high level radioactive waste. Regulatory Guide 3.61 {open_quotes}Standard Format and Content for a Topical Safety Analysis Report for a Spent Fuel Dry Storage Cask{close_quotes} contains an outline of the specific information required by the staff. The SRP is divided into 14 sections which reflect the standard application format. Regulatory requirements, staff positions, industry codes and standards, acceptance criteria, and other information are discussed.

  18. Alternative barrier layers for surface covers in dry climates

    SciTech Connect (OSTI)

    Stormont, J.C.

    1994-09-01T23:59:59.000Z

    Surface covers are one of the most widespread remediation and waste management options in all climates. Barrier layers to limit percolation through cover systems are principal features of engineered, multi-component cover designs. Conventional barrier layer components developed for humid climates have limitations in dry climates. One alternative barrier layer is a capillary barrier, which consists of a fine-over-coarse soil arrangement. The capacity of capillary barrier to laterally divert downward moving water is the key to their success. Another alternative is a dry barrier, in which atmospheric air is circulated through a coarse layer within the cover to remove water vapor. Incorporating a coarse layer which stores water for subsequent removal by air flow reduces the requirements for the air flow velocity and increases the applicability of the dry barrier.

  19. Cold Vacuum Drying (CVD) Facility Technical Safety Requirements

    SciTech Connect (OSTI)

    KRAHN, D.E.

    2000-08-08T23:59:59.000Z

    The Technical Safety Requirements (TSRs) for the Cold Vacuum Drying Facility define acceptable conditions, safe boundaries, bases thereof, and management or administrative controls required to ensure safe operation during receipt of multi-canister overpacks (MCOs) containing spent nuclear fuel. removal of free water from the MCOs using the cold vacuum drying process, and inerting and testing of the MCOs before transport to the Canister Storage Building. Controls required for public safety, significant defense in depth, significant worker safety, and for maintaining radiological and toxicological consequences below risk evaluation guidelines are included.

  20. Saving for dry days: Aquifer storage and recovery may help 

    E-Print Network [OSTI]

    Wythe, Kathy

    2008-01-01T23:59:59.000Z

    tx H2O | pg. 2 Saving for dry days Story by Kathy Wythe tx H2O | pg. 3 Aquifer storage and recovery may help With reoccurring droughts and growing population, Texas will always be looking for better ways to save or use water. Some water... suppliers in Texas are turning to aquifer storage and recovery. During the dry summer of 2008, the San Antonio Water System (SAWS) had enough assets in its ?bank? (of water) to make with- drawals to meet the needs of its customers. The water bank...

  1. Nevada Dry Natural Gas Production (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthrough 1996) in DelawareTotal ConsumptionThousand CubicfromDry NaturalDry

  2. Missouri Dry Natural Gas Production (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office of Coal,CubicWithdrawals6,992 6,895Vehicle FuelFeet)(Dollars 2012DryDry

  3. Drying of a model soil P. Faure, P. Coussot

    E-Print Network [OSTI]

    Boyer, Edmond

    depend on the paste structure. With a kaolin suspension the CRP lasts down to very low water densities plays a critical role in agriculture: an inadequate water supply may limit crop production, and soilDrying of a model soil P. Faure, P. Coussot Université Paris-Est, Laboratoire Navier, Champs sur

  4. Cold Vacuum Drying (CVD) Facility Technical Safety Requirements

    SciTech Connect (OSTI)

    KRAHN, D.E.

    1999-12-16T23:59:59.000Z

    The Technical Safety Requirements (TSRs) for the Cold Vacuum Drying Facility define acceptable conditions, safe boundaries, bases thereof, and management or administrative controls required to ensure safe operation. Controls required for public safety, significant defense-in-depth, significant worker safety, and for maintaining radiological and toxicological consequences below risk evaluation guidelines are included.

  5. STUDIES OF THE DYNAMICS OF DRY-FRICTION-DAMPED BLADE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    STUDIES OF THE DYNAMICS OF DRY-FRICTION-DAMPED BLADE ASSEMBLIES by J er^ome Guillen A dissertation . . . . . . . . . . . . . . . . . . . . . . . . . 17 2.3 Multi-DOF systems with a single friction damper . . . . . . . 20 2.3.1 System model with multiple friction dampers . . . . . . 31 2.5 Conclusion

  6. Evaluation of the Technical Basis for Extended Dry Storage and

    E-Print Network [OSTI]

    -- Executive Summary U.S. Nuclear Waste Technical Review Board December 2010 #12;U.S.U.S. Nuclear Waste Technical Review Board Authors This report was prepared for the U.S. Nuclear Waste Technical Review Board.NWTRB.GOV ii #12;Extended Dry Storage and Transportation of Used Nuclear Fuel U.S. Nuclear Waste Technical

  7. Fire Hazard Analysis for the Cold Vacuum Drying (CVD) Facility

    SciTech Connect (OSTI)

    JOHNSON, B.H.

    1999-08-19T23:59:59.000Z

    This Fire Hazard Analysis assesses the risk from fire within individual fire areas in the Cold Vacuum Drying Facility at the Hanford Site in relation to existing or proposed fire protection features to ascertain whether the objectives of DOE Order 5480.7A Fire Protection are met.

  8. Ethanol production with dilute acid hydrolysis using partially dried lignocellulosics

    DOE Patents [OSTI]

    Nguyen, Quang A. (Chesterfield, MO); Keller, Fred A. (Lakewood, CO); Tucker, Melvin P. (Lakewood, CO)

    2003-12-09T23:59:59.000Z

    A process of converting lignocellulosic biomass to ethanol, comprising hydrolyzing lignocellulosic materials by subjecting dried lignocellulosic material in a reactor to a catalyst comprised of a dilute solution of a strong acid and a metal salt to lower the activation energy (i.e., the temperature) of cellulose hydrolysis and ultimately obtain higher sugar yields.

  9. Cold Vacuum Drying (CVD) Facility Design Basis Accident Analysis Documentation

    SciTech Connect (OSTI)

    PIEPHO, M.G.

    1999-10-20T23:59:59.000Z

    This document provides the detailed accident analysis to support HNF-3553, Annex B, Spent Nuclear Fuel Project Final Safety Analysis Report, ''Cold Vacuum Drying Facility Final Safety Analysis Report (FSAR).'' All assumptions, parameters and models used to provide the analysis of the design basis accidents are documented to support the conclusions in the FSAR.

  10. Anionic Salt Programs for Close-Up Dry Cows

    E-Print Network [OSTI]

    Stokes, Sandra R.

    1998-12-17T23:59:59.000Z

    Dairy farmers can improve long-term milk production by having a well-managed program for dry cows during the last 3 weeks before calving. This publication explains how an anionic salt program can help control subclinical hypocalcemia and "droopy cow...

  11. Radiation budget changes with dry forest clearing in temperate Argentina

    E-Print Network [OSTI]

    Nacional de San Luis, Universidad

    Radiation budget changes with dry forest clearing in temperate Argentina J A V I E R H O U S P A N, Argentina, Catedra de Climatologia Agricola, Facultad de Ciencias Agropecuarias, Universidad Nacional de Entre Rios, Oro Verde, Argentina Abstract Land cover changes may affect climate and the energy balance

  12. Cold Vacuum Drying (CVD) Electrical System Design Description

    SciTech Connect (OSTI)

    BRISBIN, S.A.

    1999-06-17T23:59:59.000Z

    This document provides a technical explanation of the design and operation of the electrical system for the Cold Vacuum Drying Facility. This document identifies the requirements, and the basis for the requirements and details on how the requirements have been implemented in the design and construction of the facility. This document also provides general guidance for the surveillance, testing, and maintenance of this system.

  13. Photocatalytic properties of titania pillared clays by different drying methods

    SciTech Connect (OSTI)

    Ding, Z.; Zhu, H.Y.; Lu, G.Q.; Greenfield, P.F. [Univ. of Queensland, Brisbane, Queensland (Australia). Dept. of Chemical Engineering] [Univ. of Queensland, Brisbane, Queensland (Australia). Dept. of Chemical Engineering

    1999-01-01T23:59:59.000Z

    Photocatalysts based on titania pillared clays (TiO{sub 2} PILCs) have been prepared through a sol-gel method. Different drying methods, air drying (AD), air drying after ethanol extraction (EAD), and supercritical drying (SCD) have been employed and found to have significant effects on the photocatalytic efficiency of the resultant catalysts for the oxidation of phenol in water. Titania pillared clay (TiO{sub 2} PILC) obtained by SCD has the highest external and micropore surface area, largest amount and smallest crystallite size of anatase, and exhibited the highest photocatalytic activity. Furthermore, silica titania pillared clay (SiO{sub 2}-TiO{sub 2} PILC) after SCD, titania coated TiO{sub 2} PILC (SCD) and SiO{sub 2}-TiO{sub 2} PILC (SCD) were synthesized to study the key factors controlling the photocatalytic activity. It is concluded that the dispersion of nanometer-sized anatase on the surface of the PILC particles and the suspensibility of the particles are the most important factors for high photocatalytic efficiency.

  14. Tropical mountain cradles of dry forest diversity Christopher W. Dick*

    E-Print Network [OSTI]

    Bermingham, Eldredge

    * *Smithsonian Tropical Research Institute, Apartado 0843-03092, Balboa, Panama´; and Department of Ecology radiated at vastly different times, so fo- cus on a single taxon would be mislead- ing. On the side of rain- ple, the dry forest legume clade Leu- caena underwent endemic radiation in southwest Mexico beginning

  15. EFFECT OF DRYING CONDITIONS OF DEHYDRATED LUCERNE ON GROWTH PERFORMANCES

    E-Print Network [OSTI]

    Boyer, Edmond

    EFFECT OF DRYING CONDITIONS OF DEHYDRATED LUCERNE ON GROWTH PERFORMANCES OF RABBITS RECEIVING DIETS CONTAINING LUCERNE F. LEBAS, J. DOLZ Annie ESPAIGNET* Marie-Oaude COUSIN e G. SARDI Station de Recherches sur * Station expérimentale de l'I. T. C. F., 91920 Boigneville In 1972, 18 different adjustments of the lucerne

  16. Precipitation scavenging, dry deposition, and resuspension. Volume 1. Precipitation scavenging

    SciTech Connect (OSTI)

    Pruppacher, H.R.; Semonin, R.G.; Slinn, W.G.N. (eds.)

    1983-01-01T23:59:59.000Z

    These two volumes contain papers prepared for and presented at the Fourth International Conference on Precipitation Scavenging, Dry Deposition, and Resuspension (the Chamberlain Meeting) held during 29 November to 3 December, 1982 in Santa Monica, California. Papers presented are abstracted separately.

  17. Seismic Behavior of Spent Fuel Dry Cask Storage Systems

    SciTech Connect (OSTI)

    Shaukat, Syed K. [U.S. Nuclear Regulatory Commission, Washington, DC 20555-0001 (United States); Luk, Vincent K. [Sandia National Laboratories, PO Box 5800. Albuquerque, New Mexico 87185-0744 (United States)

    2002-07-01T23:59:59.000Z

    The U. S. Nuclear Regulatory Commission (NRC) is conducting a research program to investigate technical issues concerning the dry cask storage systems of spent nuclear fuel by conducting confirmatory research for establishing criteria and review guidelines for the seismic behavior of these systems. The program focuses on developing 3-D finite element analysis models that address the dynamic coupling of a module/cask, a flexible concrete pad, and an underlying soil/rock foundation, in particular, the soil-structure-interaction. Parametric analyses of the coupled models are performed to include variations in module/cask geometry, site seismicity, underlying soil properties, and cask/pad interface friction. The analyses performed include: 1) a rectangular dry cask module typical of Transnuclear West design at a site in Western USA where high seismicity is expected; 2) a cylindrical dry cask typical of Holtec design at a site in Eastern USA where low seismicity is expected; and 3) a cylindrical dry cask typical of Holtec design at a site in Western USA with medium high seismicity. The paper includes assumptions made in seismic analyses performed, results, and conclusions. (authors)

  18. TECHNICAL POLLUTION PREVENTION GUIDE FOR DRY BULK TERMINALS

    E-Print Network [OSTI]

    Practices 24 4.4 4.5 Pollutants 26 4.4.1 Fugitive Dust 26 4.4.2 Commodity Spillage 27 4.4.3 Oil, lubricant#12;TECHNICAL POLLUTION PREVENTION GUIDE FOR DRY BULK TERMINALS IN THE LOWER FRASER BASIN DOE FRAP 1996-19 Prepared for: Enviromnent Canada Environmental Protection Fraser Pollution Abatement North

  19. Cold Vacuum Drying Facility Stack Air Sampling System Qualification Tests

    SciTech Connect (OSTI)

    Glissmeyer, John A.

    2001-01-24T23:59:59.000Z

    This report documents tests that were conducted to verify that the air monitoring system for the Cold Vacuum Drying Facility ventilation exhaust stack meets the applicable regulatory criteria regarding the placement of the air sampling probe, sample transport, and stack flow measurement accuracy.

  20. Using HPM-Sampling to Drive Dynamic Compilation Dries Buytaert

    E-Print Network [OSTI]

    Eeckhout, Lieven

    Using HPM-Sampling to Drive Dynamic Compilation Dries Buytaert Andy Georges Michael Hind Matthew the frequently executed methods. We de- scribe and comprehensively evaluate HPM-sampling, a sim- ple) that addresses the aforementioned limitations. We show that HPM-sampling is more accurate; has low overhead