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Sample records for dow nthrown block

  1. Dow and NREL Partner to Convert Biomass to Ethanol and Other Chemical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Blocks - News Releases | NREL Dow and NREL Partner to Convert Biomass to Ethanol and Other Chemical Building Blocks July 16, 2008 The Dow Chemical Company (Dow) and the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) today announced an agreement to jointly develop and evaluate a process that will convert biomass to ethanol and other chemical building blocks. The collaborative effort demonstrates both Dow and NREL's commitment to deliver sustainable solutions

  2. Dow Building Solutions | Open Energy Information

    Open Energy Info (EERE)

    Dow Building Solutions Jump to: navigation, search Name: Dow Building Solutions Place: Midland, MI Website: www.dowbuildingsolutions.com References: Dow Building Solutions1...

  3. Dow Kokam | Open Energy Information

    Open Energy Info (EERE)

    venture between Dow and Townsend Kokam LLC, to develop a new generation of high-power battery technology to supply the automotive industry. Coordinates: 38.597065, -77.723064...

  4. Dow Chemical Company | Open Energy Information

    Open Energy Info (EERE)

    Company Jump to: navigation, search Name: Dow Chemical Company Place: Midland, MI Zip: 48667 Website: www.dow.com Coordinates: 43.6039709, -84.2370999 Show Map Loading map......

  5. Dow Chemical Co | Open Energy Information

    Open Energy Info (EERE)

    search Name: Dow Chemical Co Place: Midland, Michigan Zip: 48674 Sector: Hydro, Hydrogen Product: Michigan-based global chemical, plastic and agricultural products maker,...

  6. Dow Partners with ORNL to Commercialize Advanced Energy-Saving...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dow Partners with ORNL to Commercialize Advanced Energy-Saving Sealant for Buildings Dow Partners with ORNL to Commercialize Advanced Energy-Saving Sealant for Buildings August 5, ...

  7. October 30, 2008, Visiting Speakers Program - Dow Chemicals Presentation - Dows Approach to Sustainability

    Energy Savers [EERE]

    Catalyst for Change Dow's Approach to Sustainability Dr. Susan Butts Sr. Director, External Science & Technology Programs The Dow Chemical Company Office of Health, Safety & Security Visiting Speaker Program US Department of Energy The Power of the Human Element At The Dow Chemical Company, we view chemistry as the work of humanity. We believe the most important element of all is not found on the periodic table, yet is part of every equation for the future. This element is the Human

  8. Dow Chemical Company: Assessment Leads to Steam System Energy...

    Broader source: Energy.gov (indexed) [DOE]

    Dow Chemical Company saved 272,000 MMBtu and 1.9 million annually after increasing the steam system energy efficiency of a plant in Louisiana. Dow Chemical Company: Assessment...

  9. Dow Chemical Company-Oyster Creek VIII | Open Energy Information

    Open Energy Info (EERE)

    Dow Chemical Company-Oyster Creek VIII Jump to: navigation, search Name: Dow Chemical Company-Oyster Creek VIII Place: Texas Phone Number: 1 989-636-1000; 1 800-331-6451 Website:...

  10. Dow Corning Europe S A | Open Energy Information

    Open Energy Info (EERE)

    Corning Europe S A Jump to: navigation, search Name: Dow Corning Europe S.A. Place: Seneffe, Belgium Zip: 7180 Product: Seneffe is the headquarters for Dow Corning's operations in...

  11. Dow Kokam Lithium Ion Battery Production Facilities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon arravt006_es_pham_2012_p.pdf More Documents & Publications Dow Kokam Lithium Ion Battery Production Facilities Dow/Kokam Cell/Battery

  12. Dow Kokam Lithium Ion Battery Production Facilities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt006_es_pham_2011_p.pdf More Documents & Publications Dow/Kokam Cell/Battery Production Facilities Dow Kokam Lithium Ion Battery

  13. Dynamic Operations Wayfinding System (DOWS) for Nuclear Power Plants

    SciTech Connect (OSTI)

    Boring, Ronald Laurids; Ulrich, Thomas Anthony; Lew, Roger Thomas

    2015-08-01

    A novel software tool is proposed to aid reactor operators in respond- ing to upset plant conditions. The purpose of the Dynamic Operations Wayfind- ing System (DOWS) is to diagnose faults, prioritize those faults, identify paths to resolve those faults, and deconflict the optimal path for the operator to fol- low. The objective of DOWS is to take the guesswork out of the best way to combine procedures to resolve compound faults, mitigate low threshold events, or respond to severe accidents. DOWS represents a uniquely flexible and dy- namic computer-based procedure system for operators.

  14. Vehicle Evaluation of Downsized Dow ACM DPF | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaluation of Downsized Dow ACM DPF Vehicle Evaluation of Downsized Dow ACM DPF Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_mao.pdf More Documents & Publications Advanced Ceramic Filter For Diesel Emission Control Experimental Diesel Particulate Filter Capabilities at PNNL fundamental Modeling and Experimental Studies of Acicular Mullite Diesel

  15. Mr. Thomas Lingafeter Environmental Control Department Dow Chemical

    Office of Legacy Management (LM)

    Mr. Thomas Lingafeter Environmental Control Department Dow Chemical Post Office Box 1398 Pittsburgh, California 94565 Dear Mr. Lingafeter: As you may know, the Department of Energy (DOE) is evaluating the radiological condition of sites that were utilized under the Manhattan Engineer District and the Atomic Energy Commission (AEC) during the early years of nuclear development to determine whether they need remedial action and whether the Department has authority to perform such action. Dow

  16. EERE Success Story-Ford-Dow Partnership Is Linked to Carbon Fiber...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL EERE Success Story-Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL May 16, 2013 - 12:00am Addthis ...

  17. Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a

    Office of Environmental Management (EM)

    Petrochemical Plant | Department of Energy Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant This case study describes how Dow Chemical Company saved 272,000 MMBtu and $1.9 million annually after increasing the steam system energy efficiency of a plant in Louisiana. PDF icon Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a

  18. Dow/Kokam Cell/Battery Production Facilities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dow/Kokam Cell/Battery Production Facilities Dow/Kokam Cell/Battery Production Facilities 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon esarravt006_pham_2010_p.pdf More Documents & Publications Dow Kokam Lithium Ion Battery

  19. WA_00_022_CARGILL_DOW_POLYMERS_LLC_Waiver_of_Domestic_and_Fo.pdf |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 22_CARGILL_DOW_POLYMERS_LLC_Waiver_of_Domestic_and_Fo.pdf WA_00_022_CARGILL_DOW_POLYMERS_LLC_Waiver_of_Domestic_and_Fo.pdf PDF icon WA_00_022_CARGILL_DOW_POLYMERS_LLC_Waiver_of_Domestic_and_Fo.pdf More Documents & Publications WA_04_033_CARGILL_Waiver_of_Patent_Rights_to_CARGILL_DOWN_L.pdf WA_03_029_CARGILL_DOW_LLC_Waiver_of_Domestic_and_Foreign_Pat.pdf WA_02_052_CARGILL_DOW_Waiver_of_Domestic_and_Foreign_Patent_

  20. EERE Success Story-Ford-Dow Partnership Is Linked to Carbon Fiber

    Office of Environmental Management (EM)

    Research at ORNL | Department of Energy Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL EERE Success Story-Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL May 16, 2013 - 12:00am Addthis EERE provided funding to Dow Chemical, Ford Motor Company, and ORNL to demonstrate a novel polymer fiber material and production process technology. These funds support EERE's strategy of investing in emerging technologies that create high-quality, domestic manufacturing jobs

  1. DOW CHEMICAL U.S.A. + WESTERN DIVISION

    Office of Legacy Management (LM)

    DOW CHEMICAL U.S.A. + WESTERN DIVISION 2855 MITCHELL DRIVE WALNUT CREEK. CtyLlFORNlA 94598 October 29,1976 415 944-2300 (., L,'; ! - J. 022 . William J. Thornton Health Protection Branch Safety and Environmental Control Division U.S. Energy Research and Development Administration Oak Ridge Operations P. 0. Box E Oak Ridge, Tennessee 37830 Dear Mr. Thornton: This letter is in response to your request of September 24,1976 for information on records of radiological condition of the laboratories at

  2. Michael Lowe > Senior Chemist - Dow Chemical Company > Center Alumni > The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Materials Center at Cornell Michael Lowe Senior Chemist - Dow Chemical Company As part of the Abruña Group, Michael received his PhD in 2012. He has since joined Dow Chemical at their Michigan area facility where he is a Analytical Chemist for Core R&D

  3. DOE's Oak Ridge and Lawrence Berkeley National Labs Join with Dow Chemical

    Energy Savers [EERE]

    to Develop Next-Generation Cool Roofs | Department of Energy and Lawrence Berkeley National Labs Join with Dow Chemical to Develop Next-Generation Cool Roofs DOE's Oak Ridge and Lawrence Berkeley National Labs Join with Dow Chemical to Develop Next-Generation Cool Roofs April 14, 2011 - 12:00am Addthis Washington, DC - The U.S. Department of Energy today announced that Oak Ridge National Laboratory (ORNL) and Lawrence Berkeley National Laboratory (LBNL) have joined with Dow Chemical Company

  4. Thermal Aging Study of a Dow Corning SE 1700 Porous Structure Made by

    Office of Scientific and Technical Information (OSTI)

    Direct Ink Writing: 1-Year Results and Long-Term Predictions (Technical Report) | SciTech Connect Technical Report: Thermal Aging Study of a Dow Corning SE 1700 Porous Structure Made by Direct Ink Writing: 1-Year Results and Long-Term Predictions Citation Details In-Document Search Title: Thermal Aging Study of a Dow Corning SE 1700 Porous Structure Made by Direct Ink Writing: 1-Year Results and Long-Term Predictions Dow Corning SE 1700 (reinforced polydimethylsiloxane) porous structures

  5. Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL May 16, 2013 - 12:00am Addthis EERE provided funding to Dow Chemical, Ford Motor Company, and ORNL to demonstrate a novel polymer fiber material and production process technology. These funds support EERE's strategy of investing in emerging technologies that create high-quality, domestic manufacturing jobs and enhance the competitiveness of U.S.

  6. EERE Success Story-Dow Partners with ORNL to Commercialize Advanced

    Office of Environmental Management (EM)

    Energy-Saving Sealant for Buildings | Department of Energy Dow Partners with ORNL to Commercialize Advanced Energy-Saving Sealant for Buildings EERE Success Story-Dow Partners with ORNL to Commercialize Advanced Energy-Saving Sealant for Buildings August 5, 2015 - 11:29am Addthis A liquid flashing product invented by Dow and evaluated at Oak Ridge National Laboratory can be brushed or sprayed on surfaces to seal gaps, cracks, and seams and improve a building’s energy efficiency. Photo

  7. Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant

    SciTech Connect (OSTI)

    2007-11-01

    This DOE Save Energy Now case study describes how Dow Chemical Company saves 272,000 MMBtu and $1.9 million annually after increasing the steam system energy efficiency of a plant in Louisiana.

  8. FIA-13-0054- In the Matter of Dow Jones & Company

    Broader source: Energy.gov [DOE]

    On August 19, 2013, The Office of Hearings and Appeals (OHA) granted in part and denied in all other aspects an Appeal filed by Dow Jones & Co. (the Appellant) under the FOIA of a determination...

  9. Hydrogen Generation Rate Scoping Study of DOW Corning Antifoam Agent

    SciTech Connect (OSTI)

    Crawford, Charles

    2005-09-27

    The antifoam agent DOW Corning Q2-3183A will be added to waste streams in the Hanford River Protection Program-Waste Treatment and Immobilization Plant (RPP-WTP) to prevent foaming. It consists mostly of polydimethylsiloxane (PDMS) and polypropylene glycol (PPG). These and other minor constituents of the antifoam have organic constituents that may participate in radiolytic and chemical reactions that produce hydrogen in Hanford waste. It has been recommended by The WTP R&T Department recommended personnel to treat the organic compounds of the antifoam like the in a similar manner as other organic compounds that are native to the Hanford waste with respect to hydrogen production. This testing has investigated the radiolytic and thermal production of hydrogen from antifoam added to simulant waste solutions to determine if the organic components of the antifoam produce hydrogen in the same manner as the native organic species in Hanford waste. Antifoam additions for this testing were in the range of 4 to 10 wt% to ensure adequate hydrogen detection. Test conditions were selected to bound exposures to the antifoam agent in the WTP. These levels are higher than previously recommended values of 350 mg/L for actual applications in WTP tanks containing air spargers and pulse jet mixers. Limited degradation analyses for the organic components of the antifoam were investigated in this study. A more detailed study involving analyses of antifoam degradation and product formation is in progress at SRNL and results from that study will be reported at a later time. The total organic carbon (TOC) content of the Q2-3183A antifoam was measured to be 39.7 {+-} 4.9 wt% TOC. This measurement was performed in triplicate with on three different dilutions of the pure antifoam liquid using a TOC combustion analyzer instrument with catalytic oxidation, followed by CO{sub 2} quantification using an infrared detector. Test results from this study indicate that the WTP HGR correlation conservatively bounds hydrogen generation rates (HGRs) from antifoam-containing simulants if the antifoam organic components are treated the same as other native organics. Tests that used the combination of radiolysis and thermolysis conducted on simulants containing antifoam produced measured hydrogen that was bounded by the WTP correlation. These tests used the bounding WTP temperature of 90 C and a dose rate of 1.8 x 10{sup 5} rad/hr. This dose rate is about ten times higher than the dose rate equivalent calculated for a bounding Hanford sludge slurry composition of 10 Ci/L, or 2 x 10{sup 4} rad/hr. Hydrogen was measured using a quadrupole mass spectroscopy instrument. Based on the analyses from the 4wt% and 10wt% antifoam samples, it is expected that the HGR results are directly proportional to the antifoam concentration added. A native organic-containing simulant that did not contain any added antifoam also produced a measurable radiolytic/thermal hydrogen rates that was in bounded by the WTP correlation. A base simulant with no added organic produced a measurable radiolytic/thermal HGR that was {approx}2X higher than the predicted HGR. Analysis of antifoam-containing simulants after prolonged irradiation of 52 Mrad and heating (23 days at 90 C) indicates that essentially all of the PDMS and greater than 60% of the PPG components are degraded, likely to lower molecular weight species. The antifoam components were analyzed by extraction from the salt simulants, followed by gel permeation chromatography (GPC) by personnel at Dow Corning. A more detailed study of the antifoam degradation and product formation from radiolysis and thermolysis is currently in progress at SRNL. That study uses a dose rate of about 2 x 10{sup 4} rad/hr and bounding temperatures of 90 C. Results from that study will be reported in a future report.

  10. Fuelwood procurement for an industrial power plant: a case study of Dow Corning's program

    SciTech Connect (OSTI)

    Folger, A.G.; Sworden, P.G.; Bond, C.T.

    1984-08-01

    Dow Corning Corporation has developed effective procedures for meeting the fuelwood requirements of a 22.4 megawatt steam and electricity cogenerating power plant. The fuelwood procurement program of Dow Corning's Natural Resources Department involves special arrangements with private landowners, logging and hauling producers, and waste wood suppliers. The program's success is attributable to a favorable location, adequate allowance for advance planning, effective public relations, and flexible management. The program is significant because it demonstrates that industrial fuelwood requirements can be met and that improved production from nonindustrial private forests can be relied upon as a major source of fuelwood. 7 references, 7 figures.

  11. DOE - Office of Legacy Management -- Dow-Detroit Edison Project - MI 0-02

    Office of Legacy Management (LM)

    Dow-Detroit Edison Project - MI 0-02 FUSRAP Considered Sites Site: Dow-Detroit Edison Project (MI.0-02 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Detroit , Michigan MI.0-02-1 Evaluation Year: 1987 MI.0-02-1 Site Operations: Performed reference design work for a special fast breeder type reactor. MI.0-02-1 Site Disposition: Eliminated - No radioactive material handled at the site MI.0-02-1 Radioactive Materials Handled: No

  12. DOE - Office of Legacy Management -- Dow Chemical Co - Midland - MI 06

    Office of Legacy Management (LM)

    Midland - MI 06 FUSRAP Considered Sites Site: Dow Chemical Co. - Midland (MI.06 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Midland , Michigan MI.06-1 Evaluation Year: Circa 1987 MI.06-2 Site Operations: Conducted development work for production of magnesium-thorium alloys. MI.06-1 Site Disposition: Eliminated - AEC licensed site MI.06-1 MI.06-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled:

  13. DOE - Office of Legacy Management -- Dow Chemical Co - Walnut Creek - CA 02

    Office of Legacy Management (LM)

    Walnut Creek - CA 02 FUSRAP Considered Sites Site: Dow Chemical Co. - Walnut Creek (CA.02 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 2800 Mitchell Drive , Walnut Creek , California CA.02-1 Evaluation Year: 1987 CA.02-2 CA.02-3 Site Operations: From 1947 to 1957, conducted process studies and experimental investigations on different uranium and thorium-bearing ores; pilot-scale solvent extraction of uranium from phosphoric acid;

  14. Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant; Industrial Technologies Program (ITP) Save Energy Now Case Study (Brochure)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dow St. Charles Operations in Hahnville, Louisiana Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant Industrial Technologies Program Case Study Benefits * Saves $1.9 million annually * Achieves annual natural gas savings of 272,000 MMBtu * Achieves a simple payback of 1.5 months Key Findings * Quantifying potential energy savings, especially with the assistance of an outside expert, can provide the impetus for management to take action. * Although Dow

  15. Comparison of Dow Corning 544 antifoam to IIT747 antifoam in the 1/240 SRAT

    SciTech Connect (OSTI)

    Koopman, D.C.

    2000-05-12

    The Defense Waste Processing Facility requested that the Immobilization Technology Section compare the relative foaming tendencies of sludge simulant during simulated Chemical Processing Cell operations (HLW-DWPF-TTR-99-0012). Dow Corning 544 antifoam, currently used in DWPF, was compared to a new antifoam formulation developed at the Illinois Institute of Technology. A task plan was written and approved. The task plan deliverables included a recommendation on the choice of antifoam, an evaluation of the influence of solids concentration on foaming, an evaluation on the effect of boil-up rate on foaming, an estimate of the mass of steam stripped to remove 90 percent of the mercury, and a determination of the fate of mercury. Additional parameters to be investigated during experimentation included the maximum foam height observed, hydrogen generation rates, and nitrite destruction rates.

  16. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T. (Pleasant Hill, CA)

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  17. Net Requirements Transparency Process for Slice/Block and Block...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 As part of its Net Requirements Transparency process, on July 31, 2013 BPA published the SliceBlock and Block customers' FY2012 and forecast FY2014 Total Retail Load (TRL) and...

  18. Eikonalization of conformal blocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.; Wang, Junpu

    2015-09-03

    Classical field configurations such as the Coulomb potential and Schwarzschild solution are built from the t-channel exchange of many light degrees of freedom. We study the CFT analog of this phenomenon, which we term the 'eikonalization' of conformal blocks. We show that when an operator T appears in the OPE Ο(x)Ο(0), then the large spin Fock space states [TT···T]ℓ also appear in this OPE with a computable coefficient. The sum over the exchange of these Fock space states in an correlator build the classical 'T field' in the dual AdS description. In some limits the sum of all Fock spacemore » exchanges can be represented as the exponential of a single T exchange in the 4-pt correlator of O. Our results should be useful for systematizing 1/ℓ perturbation theory in general CFTs and simplifying the computation of large spin OPE coefficients. As examples we obtain the leading log ℓ dependence of Fock space conformal block coefficients, and we directly compute the OPE coefficients of the simplest ‘triple-trace’ operators.« less

  19. Help:Blocking users | Open Energy Information

    Open Energy Info (EERE)

    3 What it means to be blocked 4 See Also Blocking Blocking users is fairly straightforward, visit Special:BlockIP and follow these steps: IP Address or username: Enter in...

  20. Help:Range blocks | Open Energy Information

    Open Energy Info (EERE)

    accounts editing from these IP addresses will also be blocked, unless you check the box to only block anonymous editors. Range blocking is enabled on all Wikimedia wikis; to...

  1. Block LancZos PACKage

    Energy Science and Technology Software Center (OSTI)

    2005-05-01

    BLZPACK (for Block LancZos PACKage) is a standard Fortran 77 implementation of the block Lanczos algorithm intended for the solution of the standard eigenvalue problem Ax=ux or the generalized eigenvalue problem Ax=uBx, where A and B are real, sparse symmetric matrices, u and eigenvalue and x and eigenvector. The development of this eigensolver was motivated by the need to solve large, sparse, generalized problems from free vibration analyses in structural engineering. Several upgrades were performedmore »afterwards aiming at the solution of eigenvalues problems from a wider range of applications.« less

  2. Belos Block Linear Solvers Package

    Energy Science and Technology Software Center (OSTI)

    2004-03-01

    Belos is an extensible and interoperable framework for large-scale, iterative methods for solving systems of linear equations with multiple right-hand sides. The motivation for this framework is to provide a generic interface to a collection of algorithms for solving large-scale linear systems. Belos is interoperable because both the matrix and vectors are considered to be opaque objects--only knowledge of the matrix and vectors via elementary operations is necessary. An implementation of Balos is accomplished viamore » the use of interfaces. One of the goals of Belos is to allow the user flexibility in specifying the data representation for the matrix and vectors and so leverage any existing software investment. The algorithms that will be included in package are Krylov-based linear solvers, like Block GMRES (Generalized Minimal RESidual) and Block CG (Conjugate-Gradient).« less

  3. Method for making block siloxane copolymers

    DOE Patents [OSTI]

    Butler, N.L.; Jessop, E.S.; Kolb, J.R.

    1981-02-25

    A method for synthesizing block polysiloxane copolymers is disclosed. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

  4. Method for making block siloxane copolymers

    DOE Patents [OSTI]

    Butler, Nora (Livermore, CA); Jessop, Edward S. (Livermore, CA); Kolb, John R. (Livermore, CA)

    1982-01-01

    A method for synthesizing block polysiloxane copolymers. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

  5. Block Island Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    energy Facility Type Commercial Scale Wind Facility Status Proposed Developer Deepwater Wind Location Offshore from Block Island RI Coordinates 41.1, -71.53 Show Map Loading...

  6. Precision aligned split V-block

    DOE Patents [OSTI]

    George, Irwin S.

    1984-01-01

    A precision aligned split V-block for holding a workpiece during a milling operation having an expandable frame for allowing various sized workpieces to be accommodated, is easily secured directly to the mill table and having key lugs in one base of the split V-block that assures constant alignment.

  7. Light extraction block with curved surface

    DOE Patents [OSTI]

    Levermore, Peter; Krall, Emory; Silvernail, Jeffrey; Rajan, Kamala; Brown, Julia J.

    2016-03-22

    Light extraction blocks, and OLED lighting panels using light extraction blocks, are described, in which the light extraction blocks include various curved shapes that provide improved light extraction properties compared to parallel emissive surface, and a thinner form factor and better light extraction than a hemisphere. Lighting systems described herein may include a light source with an OLED panel. A light extraction block with a three-dimensional light emitting surface may be optically coupled to the light source. The three-dimensional light emitting surface of the block may includes a substantially curved surface, with further characteristics related to the curvature of the surface at given points. A first radius of curvature corresponding to a maximum principal curvature k.sub.1 at a point p on the substantially curved surface may be greater than a maximum height of the light extraction block. A maximum height of the light extraction block may be less than 50% of a maximum width of the light extraction block. Surfaces with cross sections made up of line segments and inflection points may also be fit to approximated curves for calculating the radius of curvature.

  8. Picture of the Week: Supercomputer building blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Supercomputer building blocks The first row of cabinets for the new Trinity supercomputer are being prepared for connection to the water cooling infrastructure at Los Alamos National Laboratory. Each set of 12 cabinets is delivered, connected and tested one row at a time, by the Cray installation team, until all five rows arrive. June 21, 2015 Supercomputer building blocks x View extra-large image on Flickr » The first row of cabinets for the new Trinity supercomputer are being prepared for

  9. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NEP A Determination for the Energy Efficiency and Conservation Block Grant Program Application submitted by the Native Village of Tetlin of AK Energy Efficiency and Conservation Strategies The American Recovery and Reinvestment Act of 2009, Public Law 111-5, appropriates funding for the Department of Energy (DOE) to issue/award formula-based grants to states, U.S. territories, units of local government, and Indian tribes under the Energy Efficiency and Conservation Block Grant (EECBG) Program.

  10. Guidance For Energy Efficiency And Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs U.S. ...

  11. State Energy Program and Energy Efficiency and Conservation Block...

    Energy Savers [EERE]

    and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned State Energy Program and Energy Efficiency and Conservation Block ...

  12. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Conservation Block Grant Financing Program Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy ...

  13. Energy Efficiency and Conservation Block Grant Financing Program...

    Energy Savers [EERE]

    Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy Efficiency and Conservation Block Grant financing programs is ...

  14. Energy Efficiency and Conservation Block Grant Financing Programs...

    Office of Environmental Management (EM)

    Efficiency and Conservation Block Grant Financing Programs After Grant Retirement Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement July 15, ...

  15. Guidance for Energy Efficiency and Conservation Block Grant Program...

    Energy Savers [EERE]

    for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula ...

  16. Exploration of multi-block polymer morphologies using high performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exploration of multi-block polymer morphologies using high performance computing Modern material design increasingly relies on controlling small scale morphologies. Multi-block...

  17. Energy Efficiency and Consveration Block Grant Program National...

    Energy Savers [EERE]

    Consveration Block Grant Program National Evaluation Fact Sheet Energy Efficiency and Consveration Block Grant Program National Evaluation Fact Sheet This fact sheet provides...

  18. Solvothermal Thin Film Deposition of Electron Blocking Layers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers...

  19. Deformation Processes in Block Copolymer Toughened Epoxies (Journal...

    Office of Scientific and Technical Information (OSTI)

    Deformation Processes in Block Copolymer Toughened Epoxies Citation Details In-Document Search Title: Deformation Processes in Block Copolymer Toughened Epoxies Authors:...

  20. A novel power block for CSP systems

    SciTech Connect (OSTI)

    Mittelman, Gur; Epstein, Michael

    2010-10-15

    Concentrating Solar Thermal Power (CSP) and in particular parabolic trough, is a proven large-scale solar power technology. However, CSP cost is not yet competitive with conventional alternatives unless subsidized. Current CSP plants typically include a condensing steam cycle power block which was preferably designed for a continuous operation and higher operating conditions and therefore, limits the overall plant cost effectiveness and deployment. The drawbacks of this power block are as follows: (i) no power generation during low insolation periods (ii) expensive, large condenser (typically water cooled) due to the poor extracted steam properties (high specific volume, sub-atmospheric pressure) and (iii) high installation and operation costs. In the current study, a different power block scheme is proposed to eliminate these obstacles. This power block includes a top Rankine cycle with a back pressure steam turbine and a bottoming Kalina cycle comprising another back pressure turbine and using ammonia-water mixture as a working fluid. The bottoming (moderate temperature) cycle allows power production during low insolation periods. Because of the superior ammonia-water vapor properties, the condensing system requirements are much less demanding and the operation costs are lowered. Accordingly, air cooled condensers can be used with lower economical penalty. Another advantage is that back pressure steam turbines have a less complex design than condensing steam turbines which make their costs lower. All of these improvements could make the combined cycle unit more cost effective. This unit can be applicable in both parabolic trough and central receiver (solar tower) plants. The potential advantage of the new power block is illustrated by a detailed techno-economical analysis of two 50 MW parabolic trough power plants, comparing between the standard and the novel power block. The results indicate that the proposed plant suggests a 4-11% electricity cost saving. (author)

  1. Self-doped microphase separated block copolymer electrolyte

    DOE Patents [OSTI]

    Mayes, Anne M. (Waltham, MA); Sadoway, Donald R. (Waltham, MA); Banerjee, Pallab (Boston, MA); Soo, Philip (Cambridge, MA); Huang, Biying (Cambridge, MA)

    2002-01-01

    A polymer electrolyte includes a self-doped microphase separated block copolymer including at least one ionically conductive block and at least one second block that is immiscible in the ionically conductive block, an anion immobilized on the polymer electrolyte and a cationic species. The ionically conductive block provides a continuous ionically conductive pathway through the electrolyte. The electrolyte may be used as an electrolyte in an electrochemical cell.

  2. Poly(cyclohexylethylene)-block-poly(ethylene oxide) block polymers for metal oxide templating

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schulze, Morgan W.; Sinturel, Christophe; Hillmyer, Marc A.

    2015-09-01

    A series of poly(cyclohexylethylene)-block-poly(ethylene oxide) (CEO) diblock copolymers were synthesized through tandem anionic polymerizations and heterogeneous catalytic hydrogenation. Solvent-annealed CEO diblock films were used to template dense arrays of inorganic oxide nanodots via simple spin coating of an inorganic precursor solution atop the ordered film. The substantial chemical dissimilarity of the two blocks enables (i) selective inclusion of the inorganic precursor within the PEO domain and (ii) the formation of exceptionally small feature sizes due to a relatively large interaction parameter estimated from mean-field analysis of the order–disorder transition temperatures of compositionally symmetric samples. UV/ozone treatment following incorporation produces anmore » ordered arrangement of oxide nanodots and simultaneously removes the block polymer template. However, we report the smallest particles (6 ± 1 nm) templated from a selective precursor insertion method to date using a block polymer scaffold.« less

  3. SF30 Continuation Page, Block 14

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RV 14800 Modification 083 SF30 Continuation Page, Block 14 Purpose of Modification: The following changes are hereby incorporated into the contract: 1. Update Section B as follows: 1 .1 Incorporate costs to transfer the Pretreatment Engineering Platformn from Bechtel National, Inc. (BNI) to Washington River Protection Solutions (WRPS). The addition of this new scope increased the costs of CLIN 3.1, Treatment Planning, Waste Feed Delivcry, and WTP Transition by $1,070,000 and increased fee in the

  4. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title NJ-City-Parsippany-Troy Hills, Township of Location: City Parsippany-Troy NJ Hills, Township of American Recovery and Reinvestment Act: Proposed Action or Project Description 1) Develop energy efficiency and conservation strategy, 2) energy audits of township buildings, 3) traffic light light-emitting diode (LED) retrofits, 4) building

  5. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title NJ-City-Parsippany-Troy Hills, Township of Location: City Parsippany-Troy NJ Hills, Township of American Recovery and Reinvestment Act: Proposed Action or Project Description 1) Develop energy efficiency and conservation strategy, 2) energy audits of township buildings, 3) traffic light light-emitting diode (LED) retrofits, 4) building

  6. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title AK-TRIBE-NANWALEK (AKA ENGLISH BAY) Location: Tribe AK-TRIBE- NANWALEK (AKA ENGLISH BAY) AK American Recovery and Reinvestment Act: Proposed Action or Project Description The Nanwalek IRA Council proposes to explore the feasibility of wind generation capacity specifically for the purpose of determining if wind generation is a viable

  7. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE...

    Energy Savers [EERE]

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 DAVIS-BACON ACT WAGE RATES FOR ...

  8. Solvothermal Thin Film Deposition of Electron Blocking Layers | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers

  9. Measurement of the Magnet Blocks for SSRF Insertion Devices

    SciTech Connect (OSTI)

    He Yongzhou; Zhang Jidong; Zhou Qiaogen; Qian Zhenmei; Li Yang

    2010-06-23

    Two in-vacuum undulators IVU25s and one elliptically polarized undulator EPU100 have been developed for SSRF. Two IVU25s with the same hybrid design contain about 640 Sm{sub 2}Co{sub 17} magnet blocks and the dimension of blocks is 65 Wx25 Hx9 D. The EPU100 of the APPLE-II type contains about 690 NdFeB magnet blocks with the dimension of 35 Wx35 Hx25 D. This paper describes the magnetic measurements of these magnet blocks with the Helmholtz coil measurement system for IVU25 magnet blocks and the Hall probe measurement system for EPU100 magnet blocks. The measured maximum magnetic moment deviation and the maximum angle deviation are less than {+-}1.0% and 1.1 deg. respectively both for Sm{sub 2}Co{sub 17} blocks and NdFeB blocks and satisfy the specifications of undulators.

  10. Guidance for Energy Efficiency and Conservation Block Grant Grantees on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Programs | Department of Energy Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs Provides general guidance to the U.S. Department of Energy's Energy Efficiency and Conservation Block Grant grantees on financing programs. Author: U.S. Department of Energy PDF icon Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing

  11. Energy Efficiency and Conservation Block Grant Program Success Stories

    Broader source: Energy.gov [DOE]

    Energy Efficiency and Conservation Block Grant (EECBG) Program's success stories including news articles, EERE Successes and EERE Blog entries.

  12. About the Energy Efficiency and Conservation Block Grant Program |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » About the Energy Efficiency and Conservation Block Grant Program About the Energy Efficiency and Conservation Block Grant Program The Energy Efficiency and Conservation Block Grant (EECBG) Program's purpose was to reduce fossil fuel emissions and total energy use and create jobs by working with cities, counties, states, U.S. territories, and Indian tribes to implement and manage energy efficiency and

  13. Energy Efficiency and Conservation Block Grant Program Guidance |

    Office of Environmental Management (EM)

    Department of Energy Energy Efficiency & Conservation Block Grant Program » Energy Efficiency and Conservation Block Grant Program Guidance Energy Efficiency and Conservation Block Grant Program Guidance The Energy Efficiency and Conservation Block Grant (EECBG) Program released guidance documents that explain how the recipients of EECBG funds need to report and manage those funds. These documents are listed below by the year they were released. More program guidance documents are

  14. Energy Efficiency and Conservation Block Grant Program Success Stories |

    Office of Environmental Management (EM)

    Department of Energy Energy Efficiency & Conservation Block Grant Program » Energy Efficiency and Conservation Block Grant Program Success Stories Energy Efficiency and Conservation Block Grant Program Success Stories RSS Read Energy Efficiency and Conservation Block Grant Program success stories. August 25, 2014 Pictured here is one of the solar arrays that is providing New Bedford with clean, renewable energy to power its municipally owned buildings. This ground-mounted solar array is

  15. Energy Efficiency and Conservation Block Grant Program | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Energy Efficiency and Conservation Block Grant Program Energy Efficiency and Conservation Block Grant Program With a grant from the Energy Department's Energy Efficiency and Conservation Block Grant Program, the community of Ocean View, Delaware, installed a carport-mounted solar array that is saving taxpayers money on town utility bills. | Photo courtesy of the Town of Ocean View. With a grant from the Energy Department's Energy Efficiency and Conservation Block Grant Program, the

  16. Building blocks for correlated superconductors and magnets

    SciTech Connect (OSTI)

    Sarrao, J. L.; Ronning, F.; Bauer, E. D.; Batista, C. D.; Zhu, J. -X.; Thompson, J. D.

    2015-04-01

    Recent efforts at Los Alamos to discover strongly correlated superconductors and hard ferromagnets are reviewed. While serendipity remains a principal engine of materials discovery, design principles and structural building blocks are beginning to emerge that hold potential for predictive discovery. Successes over the last decade with the so-called 115 strongly correlated superconductors are summarized, and more recent efforts to translate these insights and principles to novel hard magnets are discussed. While true materials by design remains a distant aspiration, progress is being made in coupling empirical design principles to electronic structure simulation to accelerate and guide materials design and synthesis.

  17. Building blocks for correlated superconductors and magnets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarrao, J. L.; Ronning, F.; Bauer, E. D.; Batista, C. D.; Zhu, J. -X.; Thompson, J. D.

    2015-04-01

    Recent efforts at Los Alamos to discover strongly correlated superconductors and hard ferromagnets are reviewed. While serendipity remains a principal engine of materials discovery, design principles and structural building blocks are beginning to emerge that hold potential for predictive discovery. Successes over the last decade with the so-called “115” strongly correlated superconductors are summarized, and more recent efforts to translate these insights and principles to novel hard magnets are discussed. While true “materials by design” remains a distant aspiration, progress is being made in coupling empirical design principles to electronic structure simulation to accelerate and guide materials design and synthesis.

  18. Organic photosensitive optoelectronic device having a phenanthroline exciton blocking layer

    DOE Patents [OSTI]

    Thompson, Mark E. (Anaheim Hills, CA); Li, Jian (Los Angeles, CA); Forrest, Stephen (Princeton, NJ); Rand, Barry (Princeton, NJ)

    2011-02-22

    An organic photosensitive optoelectronic device, having an anode, a cathode, and an organic blocking layer between the anode and the cathode is described, wherein the blocking layer comprises a phenanthroline derivative, and at least partially blocks at least one of excitons, electrons, and holes.

  19. A reciprocating rotating-block engine

    SciTech Connect (OSTI)

    O`Connor, L.

    1995-06-01

    This article describes the Newbold power plant, a lightweight, clean burning, and efficient engine that is designed to be used in a variety of small-engine applications, from ultralight planes to wheelchairs. A new turbo rotary-power engine brings together different design concepts from engine technology, including the rotary motion of a block, which is applied in a rotary engine, and the reciprocating motion of pistons. The new power plant also uses an air delivery system that operates similar to a turbojet engine. The turbo rotary-power engine, developed by Vernon Newbold, founder of Newbold and Associates, in Lyons, CO, produces power from the heat generated by combustion of most liquid or gaseous fuels. Production engines, expected to be built in August, will be optimized to operate using diesel fuel.

  20. Poly(lactide)-block-poly([epsilon]-caprolactone-co-[epsilon]-decalactone)-block-poly(lactide) copolymer elastomers

    SciTech Connect (OSTI)

    Schneiderman, Deborah K.; Hill, Erin M.; Martello, Mark T.; Hillmyer, Marc A.

    2015-08-28

    Batch ring opening transesterification copolymerization of ?-caprolactone and ?-decalactone was used to generate statistical copolymers over a wide range of compositions and molar masses. Reactivity ratios determined for this monomer pair, rCL = 5.9 and rDL = 0.03, reveal ?-caprolactone is added preferentially regardless of the propagating chain end. Relative to poly(?-caprolactone) the crystallinity and melting point of these statistical copolymers were depressed by the addition of ?-decalactone; copolymers containing greater than 31 mol% (46 wt%) ?-decalactone were amorphous. Poly(lactide)-block-poly(?-caprolactone-co-?-decalactone)-block-poly(lactide) triblock polymers were also prepared and used to explore the influence of midblock composition on the temperature dependent Flory-Huggins interaction parameter (?). In addition, uniaxial extension tests were used to determine the effects of midblock composition, poly(lactide) content, and molar mass on the mechanical properties of these new elastomeric triblocks.

  1. Organic photovoltaic cell incorporating electron conducting exciton blocking layers

    DOE Patents [OSTI]

    Forrest, Stephen R.; Lassiter, Brian E.

    2014-08-26

    The present disclosure relates to photosensitive optoelectronic devices including a compound blocking layer located between an acceptor material and a cathode, the compound blocking layer including: at least one electron conducting material, and at least one wide-gap electron conducting exciton blocking layer. For example, 3,4,9,10 perylenetetracarboxylic bisbenzimidazole (PTCBI) and 1,4,5,8-napthalene-tetracarboxylic-dianhydride (NTCDA) function as electron conducting and exciton blocking layers when interposed between the acceptor layer and cathode. Both materials serve as efficient electron conductors, leading to a fill factor as high as 0.70. By using an NTCDA/PTCBI compound blocking layer structure increased power conversion efficiency is achieved, compared to an analogous device using a conventional blocking layers shown to conduct electrons via damage-induced midgap states.

  2. Energy Efficiency and Conservation Block Grant Financing Program Guidance |

    Energy Savers [EERE]

    Department of Energy Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy Efficiency and Conservation Block Grant financing programs is provided below in the Grantee Letter and supporting appendices listed here. PDF icon Appendix 1: EECBG Financing Program Annual Report PDF icon Appendix 2: EECBG Program Notice 09-002D Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs, revised October 17, 2012

  3. Block copolymer adhesion promoters via ring-opening metathesis polymerization

    DOE Patents [OSTI]

    Kent, Michael S. (12320 Pine Ridge, NE, Albuquerque, NM 87112); Saunders, Randall (13201 Fruit Ave., NE, Albuquerque, NM 87123)

    1997-01-01

    Coupling agents based on functionalized block copolymers for bonding thermoset polymers to solid materials. These are polymers which possess at least two types of functional groups, one which is able to attach to and react with solid surfaces, and another which can react with a thermoset resin, which are incorporated as pendant groups in monomers distributed in blocks (typically two) along the backbone of the chain. The block copolymers in this invention are synthesized by living ring-opening metathesis polymerization.

  4. Update on Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Allocations | Department of Energy Update on Energy Efficiency and Conservation Block Grant Program Allocations Update on Energy Efficiency and Conservation Block Grant Program Allocations April 10, 2009 - 12:00am Addthis After a review of eligibility criteria for the Department of Energy's Energy Efficiency and Conservation Block Grant Program, $16,429,000 in additional funding will go to 23 counties in Delaware, Kansas, and Louisiana to support energy efficiency projects. Delaware counties

  5. Guidance For Energy Efficiency And Conservation Block Grant Grantees On

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Programs | Department of Energy Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs U.S. Department of Energy (DOE) Weatherization and Intergovernmental Program (WIP) Energy Efficiency and Conservation Block Grant (EECBG) Program Notice 09-002D modified October 17, 2012 that provides guidance about financing programs for state and local governments,

  6. State Energy Program and Energy Efficiency and Conservation Block Grant

    Energy Savers [EERE]

    Program Guidance 13-001: Guidance for Returning Interest Earned | Department of Energy and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned State Energy Program and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned U.S. Department of Energy (DOE) State Energy Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program guidance document for returning

  7. Guidance for Energy Efficiency and Conservation Block Grant Program

    Energy Savers [EERE]

    Recipients on Formula Grants | Department of Energy for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Energy Efficiency and Conservation Block Grant (EECBG) Program Guidance 10-011 dealing with formula grants. PDF icon eecbg_recovery_act_program_guidance_10-011.pdf More

  8. Energy Efficiency and Conservation Block Grant Financing Programs After

    Office of Environmental Management (EM)

    Grant Retirement | Department of Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement July 15, 2014 - 12:12pm Addthis The information below will help you manage successful Energy Efficiency and Conservation Block Grant (EECBG) financing programs: July 2014 Letter to EECBG Financing Program Managers. This document: Clarifies DOE's ongoing role in monitoring, reporting

  9. Energy Department Announces Energy Efficiency and Conservation Block Grant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program National Evaluation Results | Department of Energy Energy Efficiency and Conservation Block Grant Program National Evaluation Results Energy Department Announces Energy Efficiency and Conservation Block Grant Program National Evaluation Results November 4, 2015 - 11:00am Addthis The Energy Department announced today the results of a major national evaluation of the Energy Efficiency and Conservation Block Grant (EECBG) program funded by the American Recovery and Reinvestment Act

  10. Energy Efficiency and Conservation Block Grant Program National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program National Evaluation Executive Summary Energy Efficiency and Conservation Block Grant Program National Evaluation Executive Summary This document presents findings from an ...

  11. Guidance for Energy Efficiency and Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grant Grantees on Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds Guidance for Energy Efficiency and Conservation Block Grant Grantees on Qualified Energy ...

  12. Guidance for Energy Efficiency and Conservation Block Grant Recipients...

    Broader source: Energy.gov (indexed) [DOE]

    Guidance for Energy Efficiency and Conservation Block Grant Program grantees on planning and conducting program evaluations on Recovery Act funded EECBG programs and activities PDF ...

  13. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. GUIDANCE FOR ENERGY EFFICIENCY AND ...

  14. Net Requirements Transparency Process for Slice/Block Customers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2012 Net Requirements Transparency Process for SliceBlock Customers Description of Changes and a Response to Comments September 24, 2012 Background and Description of Changes:...

  15. Energy Efficiency and Conservation Block Grant Program Success...

    Broader source: Energy.gov (indexed) [DOE]

    Energy Efficiency and Conservation Block Grant Program success stories. August 25, 2014 ... New Bedford with clean, renewable energy to power its municipally owned buildings. ...

  16. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and oversight of Energy Efficiency and Conservation Block Grant-funded financing programs, including Revolving Loan Funds, Loan Loss Reserves, and Interest Rate Buydowns. ...

  17. Microsoft Word - Final Dec 4 Annncmnt of Agg Blocks Adjustmnt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aggregate Blocks and Prepayments BPA will Accept for Prepayment Program, the Adjustment Cap, Market Clearing Purchase Price, and Reservation Price Background Pursuant to Paragraph...

  18. Crystal Engineering on Superpolyhedral Building Blocks in Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Superpolyhedral Building Blocks in Metal-Organic Frameworks Applied in Gas Adsorption. Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 71, 613-618 (2015). DOI:...

  19. Germanium blocked impurity band infrared detectors

    SciTech Connect (OSTI)

    Rossington, C.S.; Haller, E.E.

    1988-08-01

    Germanium blocked impurity band (BIB) photoconductors have been fabricated and characterized for responsivity, dark current, and noise equivalent power. BIB photoconductors theoretically provide an extension of the spectral response, a reduction in sensitivity to cosmic radiation and a reduction in noise characteristics compared with conventional photoconductors. Silicon BIB detectors have been successfully developed by researchers at Rockwell International, which do indeed meet their theoretical potential. In the proper configuration, these same Si BIB detectors are capable of continuous detection of individual photons in the wavelength range from 0.4 to 28 ..mu..m. Until the BIB concept was developed, detection of individual photons was only possible with photomultiplier tubes which detected visible light. Due to the successes of the Si BIB detectors, it seemed natural to extend this concept to Ge detectors, which would then allow an extension of the spectral response over conventional Ge detectors from /approximately/100 ..mu..m to /approximately/200 ..mu..m. 8 refs., 2 figs.

  20. Automatic Blocking Of QR and LU Factorizations for Locality

    SciTech Connect (OSTI)

    Yi, Q; Kennedy, K; You, H; Seymour, K; Dongarra, J

    2004-03-26

    QR and LU factorizations for dense matrices are important linear algebra computations that are widely used in scientific applications. To efficiently perform these computations on modern computers, the factorization algorithms need to be blocked when operating on large matrices to effectively exploit the deep cache hierarchy prevalent in today's computer memory systems. Because both QR (based on Householder transformations) and LU factorization algorithms contain complex loop structures, few compilers can fully automate the blocking of these algorithms. Though linear algebra libraries such as LAPACK provides manually blocked implementations of these algorithms, by automatically generating blocked versions of the computations, more benefit can be gained such as automatic adaptation of different blocking strategies. This paper demonstrates how to apply an aggressive loop transformation technique, dependence hoisting, to produce efficient blockings for both QR and LU with partial pivoting. We present different blocking strategies that can be generated by our optimizer and compare the performance of auto-blocked versions with manually tuned versions in LAPACK, both using reference BLAS, ATLAS BLAS and native BLAS specially tuned for the underlying machine architectures.

  1. Modeling Mechanical Behavior of a Prismatic Replaceable Reflector Block

    SciTech Connect (OSTI)

    Robert Bratton

    2009-04-01

    This report outlines the development of finite element models used to determine temperature and stresses in a prismatic core reflector block. This initial analysis determines an appropriate temperature distribution in a prismatic reflector from limiting conditions in the adjacent fuel block based on simplifying assumptions.

  2. Light-emitting block copolymers composition, process and use

    DOE Patents [OSTI]

    Ferraris, John P.; Gutierrez, Jose J.

    2006-11-14

    Generally, and in one form, the present invention is a composition of light-emitting block copolymer. In another form, the present invention is a process producing a light-emitting block copolymers that intends polymerizing a first di(halo-methyl) aromatic monomer compound in the presence of an anionic initiator and a base to form a polymer and contacting a second di(halo-methyl) aromatic monomer compound with the polymer to form a homopolymer or block copolymer wherein the block copolymer is a diblock, triblock, or star polymer. In yet another form, the present invention is an electroluminescent device comprising a light-emitting block copolymer, wherein the electroluminescent device is to be used in the manufacturing of optical and electrical devices.

  3. NANOSTRUCTURED METAL OXIDE CATALYSTS VIA BUILDING BLOCK SYNTHESES

    SciTech Connect (OSTI)

    Craig E. Barnes

    2013-03-05

    A broadly applicable methodology has been developed to prepare new single site catalysts on silica supports. This methodology requires of three critical components: a rigid building block that will be the main structural and compositional component of the support matrix; a family of linking reagents that will be used to insert active metals into the matrix as well as cross link building blocks into a three dimensional matrix; and a clean coupling reaction that will connect building blocks and linking agents together in a controlled fashion. The final piece of conceptual strategy at the center of this methodology involves dosing the building block with known amounts of linking agents so that the targeted connectivity of a linking center to surrounding building blocks is obtained. Achieving targeted connectivities around catalytically active metals in these building block matrices is a critical element of the strategy by which single site catalysts are obtained. This methodology has been demonstrated with a model system involving only silicon and then with two metal-containing systems (titanium and vanadium). The effect that connectivity has on the reactivity of atomically dispersed titanium sites in silica building block matrices has been investigated in the selective oxidation of phenols to benezoquinones. 2-connected titanium sites are found to be five times as active (i.e. initial turnover frequencies) than 4-connected titanium sites (i.e. framework titanium sites).

  4. Bulk Vitrification Castable Refractory Block Protection Study

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Beck, Andrew E.; Brouns, Thomas M.; Caldwell, Dustin D.; Elliott, Michael L.; Matyas, Josef; Minister, Kevin BC; Schweiger, Michael J.; Strachan, Denis M.; Tinsley, Bronnie P.; Hollenberg, Glenn W.

    2005-05-01

    Bulk vitrification (BV) was selected for a pilot-scale test and demonstration facility for supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the Hanford U.S. DOE Site. During engineering-scale (ES) tests, a small fraction of radioactive Tc (and Re, its nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the castable refractory block (CRB). Laboratory experiments were undertaken to understand the mechanisms of the transport Tc/Re into the CRB during vitrification and to evaluate various means of CRB protection against the deposition of leachable Tc/Re. The tests used Re as a chemical surrogate for Tc. The tests with the baseline CRB showed that the molten LAW penetrates into CRB pores before it converts to glass, leaving deposits of sulfates and chlorides when the nitrate components decompose. Na2O from the LAW reacts with the CRB to create a durable glass phase that may contain Tc/Re. Limited data from a single CRB sample taken from an ES experiment indicate that, while a fraction of Tc/Re is present in the CRB in a readily leachable form, most of the Tc/Re deposited in the refractory is retained in the form of a durable glass phase. In addition, the molten salts from the LAW, mainly sulfates, chlorides, and nitrates, begin to evaporate from BV feeds at temperatures below 800 C and condense on solid surfaces at temperatures below 530 C. Three approaches aimed at reducing or preventing the deposition of soluble Tc/Re within the CRB were proposed: metal lining, sealing the CRB surface with a glaze, and lining the CRB with ceramic tiles. Metal liners were deemed unsuitable because evaluations showed that they can cause unacceptable distortions of the electric field in the BV system. Sodium silicate and a low-alkali borosilicate glaze were selected for testing. The glazes slowed down molten salt condensate penetration, but did little to reduce the penetration of molten salt. Out of several refractory tile candidates, only greystone and fused-cast alumina-zirconia-silica (AZS) refractory remained intact and well bonded to the CRB after firing to 1000 C. The deformation of the refractory-tile composite was avoided by prefiring the greystone tile to 800 C. Condensed vapors did not penetrate the tiles, but Re salts condensed on their surface. Refractory corrosion tests indicated that a 0.25-inch-thick greystone tile would not corrode during a BV melt. Tiles can reduce both vapor penetration and molten salt penetration, but vapor deposition above the melt line will occur even on tiles. The Tc/Re transport scenario was outlined as follows. At temperatures below 700 C, molten ionic salt (MIS) that includes all the Tc/Re penetrates, by capillarity, from the feed into the CRB open porosity. At approximately 750 C, the MIS decomposes through the loss of NOx, leaving mainly sulfate and chloride salts. The Na2O formed in the decomposition of the nitrates reacts with insoluble grains in the feed and with the aluminosilicates in the CRB to form more viscous liquids that reduce further liquid penetration into the CRB. At 800 to 1000 C, a continuous glass phase traps the remains of the MIS in the form of inclusions in the bulk glass melt. At 1000 to 1200 C, the salt inclusions in the glass slowly dissolve but also rise to the surface. The Tc/Re salts also evaporate from the free surface of the glass melt that is rapidly renewed by convective currents. The vapors condense on cooler surfaces in the upper portion of the CRB, the box lid, and the off-gas system.

  5. Block copolymer adhesion promoters via ring-opening metathesis polymerization

    DOE Patents [OSTI]

    Kent, M.S.; Saunders, R.

    1997-02-18

    Coupling agents are disclosed based on functionalized block copolymers for bonding thermoset polymers to solid materials. These are polymers which possess at least two types of functional groups, one which is able to attach to and react with solid surfaces, and another which can react with a thermoset resin, which are incorporated as pendant groups in monomers distributed in blocks (typically two) along the backbone of the chain. The block copolymers in this invention are synthesized by living ring-opening metathesis polymerization. 18 figs.

  6. Virasoro conformal blocks and thermality from classical background fields

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.

    2015-11-30

    We show that in 2d CFTs at large central charge, the coupling of the stress tensor to heavy operators can be re-absorbed by placing the CFT in a non-trivial background metric. This leads to a more precise computation of the Virasoro conformal blocks between heavy and light operators, which are shown to be equivalent to global conformal blocks evaluated in the new background. We also generalize to the case where the operators carry U(1) charges. The refined Virasoro blocks can be used as the seed for a new Virasoro block recursion relation expanded in the heavy-light limit. Furthermore, we commentmore » on the implications of our results for the universality of black hole thermality in AdS3 , or equivalently, the eigenstate thermalization hypothesis for CFT2 at large central charge.« less

  7. NREL: Concentrating Solar Power Research - Power Block R&D

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cycle and s-CO2 for producing high temperatures, leading to higher system efficiencies, lower-cost power blocks, and smaller-volume thermal energy storage. Particle receiver...

  8. Energy Efficiency and Conservation Block Grant Program Success...

    Broader source: Energy.gov (indexed) [DOE]

    like this will grace Gabe Nesbitt Community Park in McKinney, Texas, thanks to an Energy Efficiency and Conservation Block Grant | Photo courtesy of McKinney, Texas EECBG...

  9. Microsoft Word - Posted DSI Amendment of Alcoa Block Power Sales...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No. 1 Contract No. 06PB-11744 DRAFT AMENDMENT executed by the BONNEVILLE POWER ADMINISTRATION and ALCOA INC. This AMENDMENT to the BLOCK POWER SALES AGREEMENT is executed by the...

  10. Big Questions: The Ultimate Building Blocks of Matter

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07

    The Standard Model of particle physics treats quarks and leptons as having no size at all. Quarks are found inside protons and neutrons and the most familiar lepton is the electron. While the best measurements to date support that idea, there is circumstantial evidence that suggests that perhaps the these tiny particles might be composed of even smaller building blocks. This video explains this circumstantial evidence and introduces some very basic ideas of what those building blocks might be.

  11. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Wednesday, 27 January 2010 00:00 Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the

  12. Alternating Current Photovoltaic Building Block - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Alternating Current Photovoltaic Building Block Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (891 KB) Technology Marketing Summary This technology provides a fully integrated and self-containing alternating current (AC) photovoltaic (PV) Building Block device and method that allows photovoltaic applications to become true plug-and-play devices. The

  13. Structural response of a prealigned cylindrical block copolymer melt to

    Office of Scientific and Technical Information (OSTI)

    extensional flow (Journal Article) | SciTech Connect Journal Article: Structural response of a prealigned cylindrical block copolymer melt to extensional flow Citation Details In-Document Search Title: Structural response of a prealigned cylindrical block copolymer melt to extensional flow Authors: McCready, Erica M. ; Burghardt, Wesley R. [1] + Show Author Affiliations (NWU) Publication Date: 2015-08-24 OSTI Identifier: 1179492 Resource Type: Journal Article Resource Relation: Journal Name:

  14. Lower Cost, Nanoporous Block Copolymer Battery Separator - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Lower Cost, Nanoporous Block Copolymer Battery Separator Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication A.K. Jha, S.L. Tsang, A.E. Ozcam, R.D. Offeman, N.P. Balsara. "Master Curve Captures the Effect of Domain Morphology on Ethanol Pervaporation Through Block Copolymer Membranes," Journal of Membrane Science, published online, 2011. (695 KB) Technology Marketing Summary Although the polyolefin polymer

  15. Block Copolymer Separators for Lithium Batteries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Copolymer Separators for Lithium Batteries Block Copolymer Separators for Lithium Batteries 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es088_balsara_2010_p.pdf More Documents & Publications Polymer Electrolytes for Advanced Lithium Batteries Polymers For Advanced Lithium Batteries Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries

  16. Frequently Asked Questions on Energy Efficiency and Conservation Block

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grant Financing Program Compliance and Reporting | Department of Energy Frequently Asked Questions on Energy Efficiency and Conservation Block Grant Financing Program Compliance and Reporting Frequently Asked Questions on Energy Efficiency and Conservation Block Grant Financing Program Compliance and Reporting Find answers to frequently asked questions (FAQs) regarding financing program reporting and compliance for programs developed using U.S. Department of Energy (DOE) Energy Efficiency

  17. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print Wednesday, 30 May 2012 00:00 In principle, tri-block copolymers...

  18. Tobacco mosaic virus: A biological building block for micro/nano...

    Office of Scientific and Technical Information (OSTI)

    Tobacco mosaic virus: A biological building block for micronanobio systems Citation Details In-Document Search Title: Tobacco mosaic virus: A biological building block for micro...

  19. Department of Energy Awards $300,000 Block Grant to the Rocky...

    Broader source: Energy.gov (indexed) [DOE]

    Block Grant to the Rocky Flats Community Reuse Organization Department of Energy Awards 300,000 Block Grant to the Rocky Flats Community Reuse Organization More Documents &...

  20. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C., E-mail: marcus.poindl@ikt.uni-stuttgart.de, E-mail: christian.bonten@ikt.uni-stuttgart.de [Institut fr Kunststofftechnik, University of Stuttgart (Germany)

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  1. Method and structure for skewed block-cyclic distribution of

    Office of Scientific and Technical Information (OSTI)

    lower-dimensional data arrays in higher-dimensional processor grids (Patent) | SciTech Connect skewed block-cyclic distribution of lower-dimensional data arrays in higher-dimensional processor grids Citation Details In-Document Search Title: Method and structure for skewed block-cyclic distribution of lower-dimensional data arrays in higher-dimensional processor grids A method and structure of distributing elements of an array of data in a computer memory to a specific processor of a

  2. Electrically conductive doped block copolymer of polyacetylene and polyisoprene

    DOE Patents [OSTI]

    Aldissi, Mahmoud (Los Alamos, NM)

    1985-01-01

    An electrically conductive block copolymer of polyisoprene and polyacetyl and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I.sub.2 to give it an electrical conductivity in the metallic regime.

  3. Lignin-blocking treatment of biomass and uses thereof

    DOE Patents [OSTI]

    Yang, Bin (Hanover, NH); Wyman, Charles E. (Norwich, VT)

    2009-10-20

    Disclosed is a method for converting cellulose in a lignocellulosic biomass. The method provides for a lignin-blocking polypeptide and/or protein treatment of high lignin solids. The treatment enhances cellulase availability in cellulose conversion. Cellulase efficiencies are improved by the protein or polypeptide treatment. The treatment may be used in combination with steam explosion and acid prehydrolysis techniques. Hydrolysis yields from lignin containing biomass are enhanced 5-20%, and enzyme utilization is increased from 10% to 50%. Thus, a more efficient and economical method of processing lignin containing biomass materials utilizes a polypeptide/protein treatment step that effectively blocks lignin binding of cellulase.

  4. Reordering transitions during annealing of block copolymer cylinder phases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-10-06

    While equilibrium block-copolymer morphologies are dictated by energy-minimization effects, the semi-ordered states observed experimentally often depend on the details of ordering pathways and kinetics. In this study, we explore reordering transitions in thin films of block-copolymer cylinder-forming polystyrene-block-poly(methyl methacrylate). We observe several transient states as films order towards horizontally-aligned cylinders. In particular, there is an early-stage reorganization from randomly-packed cylinders into hexagonally-packed vertically-aligned cylinders; followed by a reorientation transition from vertical to horizontal cylinder states. These transitions are thermally activated. The growth of horizontal grains within an otherwise vertical morphology proceeds anisotropically, resulting in anisotropic grains in the final horizontalmore » state. The size, shape, and anisotropy of grains are influenced by ordering history; for instance, faster heating rates reduce grain anisotropy. These results help elucidate aspects of pathway-dependent ordering in block-copolymer thin films.« less

  5. Energy Efficiency and Conservation Block Grant Program Fact Sheet

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energys (DOE) Energy Efficiency and Conservation Block Grant (EECBG) program represents a Presidential priority to invest in the cheapest, cleanest and most reliable energy technologies we have energy efficiency and conservation which can be deployed immediately.

  6. Manipulating Interfaces through Surface Confinement of Poly(glycidyl methacrylate)-block-poly(vinyldimethylazlactone), a Dually Reactive Block Copolymer

    SciTech Connect (OSTI)

    Lokitz, Bradley S; Wei, Jifeng; Hinestrosa Salazar, Juan P; Ivanov, Ilia N; Browning, James B; Ankner, John Francis; Kilbey, II, S Michael; Messman, Jamie M

    2012-01-01

    The assembly of dually reactive, well-defined diblock copolymers incorporating the chemoselective/functional monomer, 4,4-dimethyl-2-vinylazlactone (VDMA) and the surface-reactive monomer glycidyl methacrylate (GMA) is examined to understand how competition between surface attachment and microphase segregation influences interfacial structure. Reaction of the PGMA block with surface hydroxyl groups not only anchors the copolymer to the surface, but limits chain mobility, creating brush-like structures comprising PVDMA blocks, which contain reactive azlactone groups. The block copolymers are spin coated at various solution concentrations and annealed at elevated temperature to optimize film deposition to achieve a molecularly uniform layer. The thickness and structure of the polymer thin films are investigated by ellipsometry, infrared spectroscopy, and neutron reflectometry. The results show that deposition of PGMA-b-PVDMA provides a useful route to control film thickness while preserving azlactone groups that can be further modified with biotin-poly(ethylene glycol)amine to generate designer surfaces. The method described herein offers guidance for creating highly functional surfaces, films, or coatings through the use of dually reactive block copolymers and postpolymerization modification.

  7. Method of forming oriented block copolymer line patterns, block copolymer line patterns formed thereby, and their use to form patterned articles

    DOE Patents [OSTI]

    Russell, Thomas P.; Hong, Sung Woo; Lee, Doug Hyun; Park, Soojin; Xu, Ting

    2015-10-13

    A block copolymer film having a line pattern with a high degree of long-range order is formed by a method that includes forming a block copolymer film on a substrate surface with parallel facets, and annealing the block copolymer film to form an annealed block copolymer film having linear microdomains parallel to the substrate surface and orthogonal to the parallel facets of the substrate. The line-patterned block copolymer films are useful for the fabrication of magnetic storage media, polarizing devices, and arrays of nanowires.

  8. Periodic nanostructures from self assembled wedge-type block-copolymers

    DOE Patents [OSTI]

    Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.; Weitekamp, Raymond; Miyake, Garret M.; Piunova, Victoria; Daeffler, Christopher Scot

    2015-06-02

    The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.

  9. Blocked impurity band hybrid infrared focal plane arrays for astronomy

    SciTech Connect (OSTI)

    Reynolds, D.B.; Seib, D.H.; Stetson, S.B.; Herter, T.; Rowlands, N.; Schoenwald, J.

    1989-02-01

    High-performance infrared hybrid focal plane arrays using 10 x 50 element Si:As Blocked-Impurity-Band (BIB) detectors (cut-off wavelength = 28 ..mu..m) and matching switched MOSFET multiplexers have been developed and characterized for space astronomy. Use of impurity band conduction technology provides detectors which are nuclear radiation hard and free of the many anomalies associated with conventional silicon photoconductive detectors. Emphasis in this paper is on recent advances in detector material quality which have led to significantly improved detector and hybrid characteristics. Results demonstrating increase quantum efficiency (particular at short wavelength infrared), obtained by varying the Blocked-Impurity-Band detector properties (infrared active layer thickness and arsenic doping profile), are summarized. Read noise and dark current for different temperatures have been measured and are also described. The hybrid array performance achieved clearly demonstrates that BIB detectors are well suited for use in astronomical instrumentation.

  10. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  11. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  12. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  13. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  14. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  15. EIS-0006: Wind Turbine Generator System, Block Island, Rhode Island

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this EIS to evaluate the environmental impacts of installing and operating a large experimental wind turbine, designated the MOD-OA, which is proposed to be installed on a knoll in Rhode Island's New Meadow Hill Swamp, integrated with the adjacent Block Island Power Company power plant and operated to supply electricity to the existing utility network.

  16. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  17. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  18. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  19. Directed Spontaneous Assembly of Membrane Protein with Amphiphilic Block

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copolymers - Energy Innovation Portal Directed Spontaneous Assembly of Membrane Protein with Amphiphilic Block Copolymers Colorado School of Mines Contact CSM About This Technology Technology Marketing SummaryThis invention describes a method for using membrane proteins (MPs) in synthetic systems for biosensor design, high-throughput drug-screening, catalysis or energy harvesting. DescriptionCurrent efforts in the art face a challenge that practical applications involving liposomes have been

  20. Nanopatterning of ultrananocrystalline diamond thin films via block copolymer lithography.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B.; Sumant, A. V.; Auciello, O.

    2010-07-01

    Nanopatterning of diamond surfaces is critical for the development of diamond-based microelectromechanical system/nanoelectromechanical system (MEMS/NEMS), such as resonators or switches. Micro-/nanopatterning of diamond materials is typically done using photolithography or electron beam lithography combined with reactive ion etching (RIE). In this work, we demonstrate a simple process, block copolymer (BCP) lithography, for nanopatterning of ultrananocrystalline diamond (UNCD) films to produce nanostructures suitable for the fabrication of NEMS based on UNCD. In BCP lithography, nanoscale self-assembled polymeric domains serve as an etch mask for pattern transfer. The authors used thin films of a cylinder-forming organic-inorganic BCP, poly(styrene-block-ferrocenyldimethylsilane), PS-b-PFS, as an etch mask on the surface of UNCD films. Orientational control of the etch masking cylindrical PFS blocks is achieved by manipulating the polymer film thickness in concert with the annealing treatment. We have observed that the surface roughness of UNCD layers plays an important role in transferring the pattern. Oxygen RIE was used to etch the exposed areas of the UNCD film underneath the BCP. Arrays of both UNCD posts and wirelike structures have been created using the same starting polymeric materials as the etch mask.

  1. Radical-cured block copolymer-modified thermosets

    SciTech Connect (OSTI)

    Redline, Erica M.; Francis, Lorraine F.; Bates, Frank S.

    2013-01-10

    Poly(ethylene-alt-propylene)-b-poly(ethylene oxide) (PEP-PEO) diblock copolymers were synthesized and added at 4 wt % to 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (BisGMA), a monomer that cures using free radical chemistry. In separate experiments, poly(ethylene glycol) dimethacrylate (PEGDMA) was combined as a secondary monomer with BisGMA and the monomers were loaded with 4 wt % PEP-PEO. The diblock copolymers self-assembled into well-dispersed spherical micelles with PEP cores and PEO coronas. No appreciable change in the final extent of cure of the thermosets was caused by the addition of diblock copolymer, except in the case of BisGMA, where the addition of the block copolymer increased extent of cure by 12%. Furthermore, the extent of cure was increased by 29% and 37% with the addition of 25 and 50 wt % PEGDMA, respectively. Elastic modulus and fracture resistance were also determined, and the values indicate that the addition of block copolymers does not significantly toughen the thermoset materials. This finding is surprising when compared with the large increase in fracture resistance seen in block copolymer-modified epoxies, and an explanation is proposed.

  2. Gas block mechanism for water removal in fuel cells

    DOE Patents [OSTI]

    Issacci, Farrokh; Rehg, Timothy J.

    2004-02-03

    The present invention is directed to apparatus and method for cathode-side disposal of water in an electrochemical fuel cell. There is a cathode plate. Within a surface of the plate is a flow field comprised of interdigitated channels. During operation of the fuel cell, cathode gas flows by convection through a gas diffusion layer above the flow field. Positioned at points adjacent to the flow field are one or more porous gas block mediums that have pores sized such that water is sipped off to the outside of the flow field by capillary flow and cathode gas is blocked from flowing through the medium. On the other surface of the plate is a channel in fluid communication with each porous gas block mediums. The method for water disposal in a fuel cell comprises installing the cathode plate assemblies at the cathode sides of the stack of fuel cells and manifolding the single water channel of each of the cathode plate assemblies to the coolant flow that feeds coolant plates in the stack.

  3. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined...

  4. Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-011 EFFECTIVE DATE: April 21, 2010 SUBJECT: AMERICAN RECOVERY AND REINVESTMENT ACT (ARRA) ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM - FORMULA GRANT GUIDANCE PURPOSE ........................................................................................................................... 3 SCOPE

  5. Hole Blocking, Electron Transporting and Window Layer for Optimized

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Culn(1-x)GaxSe2 Solar Cells - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Hole Blocking, Electron Transporting and Window Layer for Optimized Culn(1-x)GaxSe2 Solar Cells Brookhaven National Laboratory Contact BNL About This Technology <br type="_moz" /> A schematic illustration of an exemplary embodiment of the disclosed CIGS based solar cell, with a quasi-2-dimensional electron

  6. Non-crosslinked, amorphous, block copolymer electrolyte for batteries

    DOE Patents [OSTI]

    Mayes, Anne M.; Ceder, Gerbrand; Chiang, Yet-Ming; Sadoway, Donald R.; Aydinol, Mehmet K.; Soo, Philip P.; Jang, Young-Il; Huang, Biying

    2006-04-11

    Solid battery components are provided. A block copolymeric electrolyte is non-crosslinked and non-glassy through the entire range of typical battery service temperatures, that is, through the entire range of at least from about 0.degree. C. to about 70.degree. C. The chains of which the copolymer is made each include at least one ionically-conductive block and at least one second block immiscible with the ionically-conductive block. The chains form an amorphous association and are arranged in an ordered nanostructure including a continuous matrix of amorphous ionically-conductive domains and amorphous second domains that are immiscible with the ionically-conductive domains. A compound is provided that has a formula of Li.sub.xM.sub.yN.sub.zO.sub.2. M and N are each metal atoms or a main group elements, and x, y and z are each numbers from about 0 to about 1. y and z are chosen such that a formal charge on the M.sub.yN.sub.z portion of the compound is (4-x). In certain embodiments, these compounds are used in the cathodes of rechargeable batteries. The present invention also includes methods of predicting the potential utility of metal dichalgogenide compounds for use in lithium intercalation compounds. It also provides methods for processing lithium intercalation oxides with the structure and compositional homogeneity necessary to realize the increased formation energies of said compounds. An article is made of a dimensionally-stable, interpenetrating microstructure of a first phase including a first component and a second phase, immiscible with the first phase, including a second component. The first and second phases define interphase boundaries between them, and at least one particle is positioned between a first phase and a second phase at an interphase boundary. When the first and second phases are electronically-conductive and ionically-conductive polymers, respectively, and the particles are ion host particles, the arrangement is an electrode of a battery.

  7. Single Helix to Double Gyroid in Chiral Block Copolymers

    SciTech Connect (OSTI)

    C Chen; H Hsueh; Y Chiang; R Ho; S Akasaka; H Hasegawa

    2011-12-31

    An order-order phase transition of chiral block copolymers (BCPs*) from single helix to double gyroid (H* {yields} G) through a nucleation and growth process was demonstrated. The H* and G phases can be obtained by solution casting from fast and slow solvent evaporation, respectively, suggesting that the H* phase is a metastable phase. Consequently, the coexistence of H* and G phases can be found in the solution-cast samples from intermediate solvent evaporation. To truly examine the transition mechanism of the H* {yields} G, electron tomography was carried out to directly visualize the morphological evolution in real space, in particular, the transition zone at interface. Unlike the mechanisms for the transitions of block copolymers (BCPs) by considering the interdomain spacing matching, a significant mismatch in the lattices for the H* {yields} G was found. Consequently, the transition may require an adjustment on the geometric dimensions to justify corresponding lattice mismatch. As a result, the morphological observations from electron tomography offer new insights into BCP phase transitions.

  8. Energy.gov Content Management System Block Types | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Types Energy.gov Content Management System Block Types For Office of Energy Efficiency and Renewable Energy (EERE) websites, learn about the variety of block types available in the Energy.gov Drupal content management system (CMS). Blocks are an integral part of the Drupal CMS. Blocks are chunks of content that can be can be placed on multiple pages or used as part of a page's design or layout. They can display either dynamically generated content or static content that you enter yourself.

  9. Deuteration Can Impact Micellization Pressure and Cloud Pressure of Polystyrene-block-polybutadiene and Polystyrene-block-polyisoprene in Compressible Propane

    SciTech Connect (OSTI)

    Winoto, Winoto; Shen, Youqin; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    The deuterated homopolymers and their corresponding polystyrene-block-polybutadiene and polystyrene-block-polyisoprene copolymers require lower cloud pressures than their hydrogenous analogues to dissolve in a compressible alkane solvent, such as propane. For symmetric diblocks, deuteration reduces the micellization pressure. By contrast, for asymmetric diblocks with a long diene block relative to the styrene block, deuteration can increase the micellization pressure. All in all, however, the deuteration effects, while measurable, do not qualitatively change the principal diblock properties in compressible propane solutions, such as pressure-induced micelle decomposition, micelle formation and micelle size, and their temperature dependence. Therefore, isotope labeling should be a useful approach to neutron-scattering characterization for styrene-diene block copolymers in compressible alkane systems.

  10. Linked supramolecular building blocks for enhanced cluster formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLellan, Ross; Palacios, Maria A.; Beavers, Christine M.; Teat, Simon J.; Piligkos, Stergios; Brechin, Euan K.; Dalgarno, Scott J.

    2015-01-09

    Methylene-bridged calix[4]arenes have emerged as extremely versatile ligand supports in the formation of new polymetallic clusters possessing fascinating magnetic properties. Metal ion binding rules established for this building block allow one to partially rationalise the complex assembly process. The ability to covalently link calix[4]arenes at the methylene bridge provides significantly improved control over the introduction of different metal centres to resulting cluster motifs. Clusters assembled from bis-calix[4]arenes and transition metal ions or 3d-4f combinations display characteristic features of the analogous calix[4]arene supported clusters, thereby demonstrating an enhanced and rational approach towards the targeted synthesis of complex and challenging structures.

  11. Sealed Battery Block Provided With A Cooling System

    DOE Patents [OSTI]

    Verhoog, Roelof (Bordeaux, FR); Barbotin, Jean-Loup (Pompignac, FR)

    1999-11-16

    The present invention relates to a sealed battery block operating at a pressure of at least 1 bar relative, the battery including a container made of a plastics material and made up of a lid and of a case subdivided into wells by at least one partition, said battery being provided with a cooling system including two cheek plates made of a plastics material and co-operating with the outside faces of respective ones of two opposite walls of said case, each cheek plate co-operating with the corresponding wall to define a compartment provided with a plurality of ribs forming baffles for fluid flow purposes, and with an inlet orifice and an outlet orifice for the fluid, said battery being characterized in that each of said ribs extends in a direction that forms an angle relative to the plane of said partition lying in the range 60.degree. to 90.degree..

  12. Nanoporous Gold as a Platform for a Building Block Catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporousmore » gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.« less

  13. Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    investments in cutting-edge energy innovations that are laying the building blocks for ... Manager for Dow Kokam, hosted Deputy Secretary of Energy Poneman on the open press tour. ...

  14. Cooperative storage of shared files in a parallel computing system with dynamic block size

    DOE Patents [OSTI]

    Bent, John M.; Faibish, Sorin; Grider, Gary

    2015-11-10

    Improved techniques are provided for parallel writing of data to a shared object in a parallel computing system. A method is provided for storing data generated by a plurality of parallel processes to a shared object in a parallel computing system. The method is performed by at least one of the processes and comprises: dynamically determining a block size for storing the data; exchanging a determined amount of the data with at least one additional process to achieve a block of the data having the dynamically determined block size; and writing the block of the data having the dynamically determined block size to a file system. The determined block size comprises, e.g., a total amount of the data to be stored divided by the number of parallel processes. The file system comprises, for example, a log structured virtual parallel file system, such as a Parallel Log-Structured File System (PLFS).

  15. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  16. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  17. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  18. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  19. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  20. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  1. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  2. Plains and Eastern Clean Line Transmission Line: Comment from Block Plains

    Energy Savers [EERE]

    and Eastern Clean Line: Arkansas and Oklahoma | Department of Energy from Block Plains and Eastern Clean Line: Arkansas and Oklahoma Plains and Eastern Clean Line Transmission Line: Comment from Block Plains and Eastern Clean Line: Arkansas and Oklahoma Comment submitted on updated Part 2 application. PDF icon Comment from Block Plains & Eastern Clean Line Arkansas and Oklahoma 06-08-15.pdf More Documents & Publications Plains and Eastern Clean Line Transmission Line: Comment from

  3. Thermal-stress analysis of a Fort St. Vrain core-support block under accident conditions

    SciTech Connect (OSTI)

    Carruthers, L.M.; Butler, T.A.; Anderson, C.A.

    1982-01-01

    A thermoelastic stress analysis of a graphite core support block in the Fort St. Vrain High Temperature Gas Cooled Reactor is described. The support block is subjected to thermal stresses caused by a loss of forced circulation accident of the reactor system. Two- and three-dimensional finite element models of the core support block are analyzed using the ADINAT and ADINA codes, and results are given that verify the integrity of this structural component under the given accident condition.

  4. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces...

  5. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print Wednesday, 30 May 2012 00:00 In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks

  6. $300,000 Block Grant Awarded to Tri-City Industrial Development Council

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (TRIDEC) | Department of Energy $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) PDF icon $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) More Documents & Publications Department of Energy Awards $300,000 to Tri-City Industrial Development Council in Washington

  7. Guidance for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines

    Broader source: Energy.gov [DOE]

    Guidance for Energy Efficiency and Conservation Block Grant Program grantees on planning and conducting program evaluations on Recovery Act funded EECBG programs and activities

  8. Collapse transitions in thermosensitive multi-block copolymers: A Monte Carlo study

    SciTech Connect (OSTI)

    Rissanou, Anastassia N.; Tzeli, Despoina S.; Anastasiadis, Spiros H.; Bitsanis, Ioannis A.

    2014-05-28

    Monte Carlo simulations are performed on a simple cubic lattice to investigate the behavior of a single linear multiblock copolymer chain of various lengths N. The chain of type (A{sub n}B{sub n}){sub m} consists of alternating A and B blocks, where A are solvophilic and B are solvophobic and N = 2nm. The conformations are classified in five cases of globule formation by the solvophobic blocks of the chain. The dependence of globule characteristics on the molecular weight and on the number of blocks, which participate in their formation, is examined. The focus is on relative high molecular weight blocks (i.e., N in the range of 5005000 units) and very differing energetic conditions for the two blocks (very goodalmost athermal solvent for A and bad solvent for B). A rich phase behavior is observed as a result of the alternating architecture of the multiblock copolymer chain. We trust that thermodynamic equilibrium has been reached for chains of N up to 2000 units; however, for longer chains kinetic entrapments are observed. The comparison among equivalent globules consisting of different number of B-blocks shows that the more the solvophobic blocks constituting the globule the bigger its radius of gyration and the looser its structure. Comparisons between globules formed by the solvophobic blocks of the multiblock copolymer chain and their homopolymer analogs highlight the important role of the solvophilic A-blocks.

  9. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012

    Broader source: Energy.gov [DOE]

    DAVIS-BACON ACT WAGE RATES FOR ARRA-FUNDED ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM PROJECTS INVOLVING RESIDENTIAL WEATHERIZATION WORK

  10. In Situ SAXS Studies of Structural Relaxation of an Ordered Block...

    Office of Scientific and Technical Information (OSTI)

    In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow Citation Details In-Document Search Title: In Situ ...

  11. Gross Gamma-Ray Calibration Blocks (May 1978) | Department of Energy

    Office of Environmental Management (EM)

    Gross Gamma-Ray Calibration Blocks (May 1978) Gross Gamma-Ray Calibration Blocks (May 1978) Gross Gamma-Ray Calibration Blocks (May 1978) PDF icon Gross Gamma-Ray Calibration Blocks (May 1978) More Documents & Publications Grade Assignments for Models Used for Calibration of Gross-Count Gamma-Ray Logging Systems (December 1983) A Brief Review of the Basis for, and the Procedures Currently Utilized in, Gross Gamma-Ray Log Calibration (October 1976) Parameter Assignments for Spectral Gamma-Ray

  12. Nanostructure of Solid Precipitates Obtained by Expansion of Polystyrene-block-Polybutadiene Solutions in Near Critical Propane: Block Ratio and Micellar Solution Effects

    SciTech Connect (OSTI)

    Green, Jade; Tyrrell, Zachary; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2011-01-01

    In contrast to incompressible liquid solutions, compressible near-critical solutions of block copolymers allow for controlling rapid structure transformations with pressure alone. For example, when dissolved in near-critical propane, polystyrene-block-polybutadiene can form a random molecular solution at high pressures, a micellar solution at moderate pressures, and a solvent-free precipitate at low pressures. In contrast to the unstructured virgin copolymer, such a propane-treated precipitate rapidly self-assembles toward structures characteristic of equilibrated block copolymers, such as lamellae, spheres, or cylinders, which depend on the block ratio rather than on the decompression rate or temperature, at least within the rate and temperature ranges investigated in this work. At lower temperatures, however, say below 40 C, glass transition of the styrene-butadiene diblocks can inhibit independent structure formation, while crystallization of their hydrogenated-butadiene analogues can preserve the micellar-solution structure.

  13. Parallel Block Structured Adaptive Mesh Refinement on Graphics Processing Units

    SciTech Connect (OSTI)

    Beckingsale, D. A.; Gaudin, W. P.; Hornung, R. D.; Gunney, B. T.; Gamblin, T.; Herdman, J. A.; Jarvis, S. A.

    2014-11-17

    Block-structured adaptive mesh refinement is a technique that can be used when solving partial differential equations to reduce the number of zones necessary to achieve the required accuracy in areas of interest. These areas (shock fronts, material interfaces, etc.) are recursively covered with finer mesh patches that are grouped into a hierarchy of refinement levels. Despite the potential for large savings in computational requirements and memory usage without a corresponding reduction in accuracy, AMR adds overhead in managing the mesh hierarchy, adding complex communication and data movement requirements to a simulation. In this paper, we describe the design and implementation of a native GPU-based AMR library, including: the classes used to manage data on a mesh patch, the routines used for transferring data between GPUs on different nodes, and the data-parallel operators developed to coarsen and refine mesh data. We validate the performance and accuracy of our implementation using three test problems and two architectures: an eight-node cluster, and over four thousand nodes of Oak Ridge National Laboratorys Titan supercomputer. Our GPU-based AMR hydrodynamics code performs up to 4.87 faster than the CPU-based implementation, and has been scaled to over four thousand GPUs using a combination of MPI and CUDA.

  14. Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes

    DOE Patents [OSTI]

    Fujimoto, Cy H. (Albuquerque, NM); Hibbs, Michael (Albuquerque, NM); Ambrosini, Andrea (Albuquerque, NM)

    2012-02-07

    Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

  15. Tunable Encapsulation Structure of Block Copolymer Coated Single-Walled Carbon Nanotubes in Aqueous Solution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Youngkyu; Ahn, Suk-Kyun; Zhang, Zhe; Smith, Gregory Scott; Do, Changwoo

    2015-05-15

    The nano-sized and shape-tunable molecular building blocks can provide great opportunities for the fabrication of precisely controlled nanostructures. In this work, we have fabricated a molecular building block of single-walled carbon nanotubes (SWNTs) coated by PPO-PEO-PPO block copolymers whose encapsulation structure can be controlled via temperature or addition of small molecules. The structure and optical properties of SWNT-block copolymers have been investigated by small angle neutron scattering (SANS), ultraviolet-visible (UV-vis) spectroscopy, atomic force microscopy (AFM), and molecular dynamics (MD) simulation. The structure of the hydrated block copolymer layer surrounding SWNT can be controlled reversibly by varying temperature as well asmore » by irreversibly adding 5-methylsalicylic acid (5MS). Increasing hydrophobicity of the polymers with temperature and strong tendency of 5MS to interact with both block copolymers and orbitals of the SWNTs are likely to be responsible for the significant structural change of the block copolymer encapsulation layer, from loose corona shell to tightly encapsulating compact shell. These result shows an efficient and simple way to fabricate and manipulate carbon-based nano building blocks in aqueous systems with tunable structure.« less

  16. Monitoring Plan for Weatherization Assistance Program, State Energy Program, Energy Efficiency and Conservation Block Grants

    Energy Savers [EERE]

    American Recovery and Reinvestment Act Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants Revised: June 30, 2010 U.S. Department of Energy Office of Weatherization and Intergovernmental Program Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants Concurrences:

  17. Sub-5 nm Domains in Ordered Poly(cyclohexylethylene)-block-poly(methyl methacrylate) Block Polymers for Lithography.

    SciTech Connect (OSTI)

    Kennemur, Justin; Yao, Li; Bates, Frank Stephen; Hillmyer, Marc

    2014-01-01

    A series of poly(cyclohexylethylene)-block-poly- (methyl methacrylate) (PCHE PMMA) diblock copolymers with varying molar mass (4.9 kg/mol Mn 30.6 kg/mol) and narrow molar mass distribution were synthesized through a combination of anionic and atom transfer radical polymerization (ATRP) techniques. Heterogeneous catalytic hydrogenation of -(hydroxy)polystyrene (PS-OH) yielded -(hydroxy)poly(cyclohexylethylene) (PCHEOH) with little loss of hydroxyl functionality. PCHE-OH was reacted with -bromoisobutyryl bromide (BiBB) to produce an ATRP macroinitiator used for the polymerization of methyl methacrylate. PCHE PMMA is a glassy, thermally stable material with a large effective segment segment interaction parameter, eff = (144.4 6.2)/T (0.162 0.013), determined by meanfield analysis of order-to-disorder transition temperatures (TODT) measured by dynamic mechanical analysis and differential scanning calorimetry. Ordered lamellar domain pitches (9 D 33 nm) were identified by small-angle X-ray scattering from neat BCPs containing 43 52 vol % PCHE ( f PCHE). Atomic force microscopy was used to show 7.5 nm lamellar features (D = 14.8 nm) which are some of the smallest observed to date. The lowest molar mass sample (Mn = 4.9 kg/mol, f PCHE = 0.46) is characterized by TODT = 173 3 C and sub-5 nm nanodomains, which together with the sacrificial properties of PMMA and the high overall thermal stability place this material at the forefront of high- systems for advanced nanopatterning applications.

  18. High-Pressure Micellar Solutions of Polystyrene-block-Polybutadiene and Polystyrene-block-Polyisoprene Solutions in Propane Exhibit Cloud-Pressure Reduction and Distinct Micellization End Points

    SciTech Connect (OSTI)

    Winoto, Winoto; Radosz, Maciej; Tan, Sugata; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical non-micellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size and ratio, and on the polymer concentration. For a given pressure, the micellization end-point temperature corresponds to the "critical micelle temperature." The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

  19. Non-immunogenic, hydrophilic/cationic block copolymers and uses thereof

    DOE Patents [OSTI]

    Scales, Charles W.; Huang, Faqing; McCormick, Charles L.

    2010-05-18

    The present invention provides novel non-immunogenic, hydrophilic/cationic block copolymers comprising a neutral-hydrophilic polymer and a cationic polymer, wherein both polymers have well-defined chain-end functionality. A representative example of such a block copolymer comprises poly(N-(2-hydroxypropyl)methacrylamide) (PHPMA) and poly(N-[3-(dimethylamino)propyl]methacrylamide) (PDMAPMA). Also provided is a synthesis method thereof in aqueous media via reversible addition fragmentation chain transfer (RAFT) polymerization. Further provided are uses of these block copolymers as drug delivery vehicles and protection agents.

  20. Square Grains in Asymmetric Rod-Coil Block Copolymers (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Square Grains in Asymmetric Rod-Coil Block Copolymers Citation Details In-Document Search Title: Square Grains in Asymmetric Rod-Coil Block Copolymers Unlike the rounded grains that are well known to form in most soft materials, square grains of microphase-separated lamellae are observed in thin films of a rod-coil block copolymer because of hierarchical structuring originating from the molecular packing of the rods. The square grains are oriented with lamellar layers

  1. Organic photosensitive cells having a reciprocal-carrier exciton blocking layer

    DOE Patents [OSTI]

    Rand, Barry P. (Princeton, NJ); Forrest, Stephen R. (Princeton, NJ); Thompson, Mark E. (Anaheim Hills, CA)

    2007-06-12

    A photosensitive cell includes an anode and a cathode; a donor-type organic material and an acceptor-type organic material forming a donor-acceptor junction connected between the anode and the cathode; and an exciton blocking layer connected between the acceptor-type organic material of the donor-acceptor junction and the cathode, the blocking layer consisting essentially of a material that has a hole mobility of at least 10.sup.-7 cm.sup.2/V-sec or higher, where a HOMO of the blocking layer is higher than or equal to a HOMO of the acceptor-type material.

  2. Three-dimensional thermoelastic analysis of a Fort St. Vrain core support block

    SciTech Connect (OSTI)

    Butler, T.A.; Anderson, C.A.

    1981-09-01

    A thermoelastic stress analysis of a graphite core support block in the Fort St. Vrain High-Temperature Gas-Cooled Reactor is described. The support block is subjected to thermal stresses caused by a loss of forced circulation accident of the reactor system. Two- and three-dimensional finite element models of the core support block are analyzed using the ADINAT and ADINA codes, and results are given that verify the integrity of this structural component under the given accident condition. 10 refs., 39 figs.

  3. Method of producing nanopatterned articles using surface-reconstructed block copolymer films

    DOE Patents [OSTI]

    Russell, Thomas P; Park, Soojin; Wang, Jia-Yu; Kim, Bokyung

    2013-08-27

    Nanopatterned surfaces are prepared by a method that includes forming a block copolymer film on a substrate, annealing and surface reconstructing the block copolymer film to create an array of cylindrical voids, depositing a metal on the surface-reconstructed block copolymer film, and heating the metal-coated block copolymer film to redistribute at least some of the metal into the cylindrical voids. When very thin metal layers and low heating temperatures are used, metal nanodots can be formed. When thicker metal layers and higher heating temperatures are used, the resulting metal structure includes nanoring-shaped voids. The nanopatterned surfaces can be transferred to the underlying substrates via etching, or used to prepare nanodot- or nanoring-decorated substrate surfaces.

  4. Video compression of coronary angiograms based on discrete wavelet transform with block classification

    SciTech Connect (OSTI)

    Ho, B.K.T.; Tsai, M.J.; Wei, J.; Ma, M.; Saipetch, P.

    1996-12-01

    A new method of video compression for angiographic images has been developed to achieve high compression ratio ({approximately}20:1) while eliminating block artifacts which leads to loss of diagnostic accuracy. This method adopts motion picture experts group`s (MPEG`s) motion compensated prediction to take advantage of frame to frame correlation. However, in contrast to MPEG, the error images arising from mismatches in the motion estimation are encoded by discrete wavelet transform (DWT) rather than block discrete cosine transform (DCT). Furthermore, the authors developed a classification scheme which label each block in an image as intra, error, or background type and encode it accordingly. This hybrid coding can significantly improve the compression efficiency in certain cases. This method can be generalized for any dynamic image sequences applications sensitive to block artifacts.

  5. Block entropy and quantum phase transition in the anisotropic Kondo necklace model

    SciTech Connect (OSTI)

    Mendoza-Arenas, J. J.; Franco, R.; Silva-Valencia, J.

    2010-06-15

    We study the von Neumann block entropy in the Kondo necklace model for different anisotropies {eta} in the XY interaction between conduction spins using the density matrix renormalization group method. It was found that the block entropy presents a maximum for each {eta} considered, and, comparing it with the results of the quantum criticality of the model based on the behavior of the energy gap, we observe that the maximum block entropy occurs at the quantum critical point between an antiferromagnetic and a Kondo singlet state, so this measure of entanglement is useful for giving information about where a quantum phase transition occurs in this model. We observe that the block entropy also presents a maximum at the quantum critical points that are obtained when an anisotropy {Delta} is included in the Kondo exchange between localized and conduction spins; when {Delta} diminishes for a fixed value of {eta}, the critical point increases, favoring the antiferromagnetic phase.

  6. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thermoelectrics and separations media, to name a few. Yet, by simply attaching one more polymer that is chemically distinct from the other blocks to the end of the di-BCP and by...

  7. Energy Efficiency and Consveration Block Grant Program National Evaluation Fact Sheet

    Broader source: Energy.gov [DOE]

    This fact sheet provides summarized results of the National Evaluation of the Energy Efficiency and Conservation Block Grant Program, a national program funded one-time under the American Recovery and Reinvestment Act of 2009.

  8. How to create formatted blocks to hold OpenEI wiki content |...

    Open Energy Info (EERE)

    format, which you can see in use on the OpenEI frontpage. As an example of the migration, please see below. You can see that classes after "block-v1" moved in addition to...

  9. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    enormous parameter space for the creation of new morphologies. Illustration from F.S. Bates and G.H. Fredrickson, "Block copolymers-designer soft materials," Physics Today 52, 32...

  10. Road Blocks Yield Key Information about a Catalyst | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Road Blocks Yield Key Information about a Catalyst Researchers systematically blocked key chemical reaction pathways to get unambiguous information about how carbon-nitrogen bonds are formed in a catalytic reaction known as hydroamination. Understanding a multi-step catalytic mechanism is like a solving a puzzle where you can't see the pieces. However, you can add your own "pieces" with known shapes to figure out what other pieces of the puzzle then will (or will not) fit.

  11. In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer

    Office of Scientific and Technical Information (OSTI)

    Melt Following Cessation of Uniaxial Extensional Flow (Journal Article) | SciTech Connect In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow Citation Details In-Document Search Title: In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow Authors: McCready, Erica M. ; Burghardt, Wesley R. [1] + Show Author Affiliations (NWU) Publication

  12. Power Block R&D for CSP Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Power Block R&D for CSP Systems Power Block R&D for CSP Systems Power plant components and systems for concentrating solar power (CSP) benefit from a mature and well-understood technology found elsewhere in the power generation industry. The most common cycles employed by conventional CSP plants include subcritical Rankine and Stirling. Gross thermal-to-electric conversion efficiencies are typically 35%-45%. Working fluids include steam, hydrogen, and helium. The primary driver for

  13. Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EECBG PROGRAM NOTICE 09-002D EFFECTIVE DATE (Revised): October 17, 2012 ORIGINALLY ISSUED: December 7, 2009 SUBJECT: GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT GRANTEES ON FINANCING PROGRAMS. PURPOSE To provide guidance to Department of Energy (DOE) Energy Efficiency and Conservation Block Grant (EECBG) grantees on financing programs. This guidance supersedes EECBG Program notice 09-002C issued March 14, 2011. SCOPE The provisions of this guidance apply to prime recipients

  14. Guidance for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    17 EFFECTIVE DATE: July 21, 2010 SUBJECT: GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON PROGRAM EVALUATION GUIDELINES. PURPOSE To provide guidance to Department of Energy's (DOE's) Energy Efficiency and Conservation Block Grant (EECBG) Program grantees on planning and conducting program evaluations. This guidance only applies to those EECBG grantees and sub-grantees (collectively, the State, local units of government, and Indian tribes will be referred to as

  15. Tobacco mosaic virus: A biological building block for micro/nano/bio

    Office of Scientific and Technical Information (OSTI)

    systems (Journal Article) | SciTech Connect Tobacco mosaic virus: A biological building block for micro/nano/bio systems Citation Details In-Document Search Title: Tobacco mosaic virus: A biological building block for micro/nano/bio systems Authors: Fan, Xiao Z ; Pomerantseva, Ekaterina ; Gnerlich, Markus ; Brown, Adam ; Gerasopoulos, K ; McCarthy, M ; Culver, James ; Ghodssi, Reza Publication Date: 2013-01-01 OSTI Identifier: 1160750 DOE Contract Number: SC0001160 Resource Type: Journal

  16. US-Guided Femoral and Sciatic Nerve Blocks for Analgesia During Endovenous Laser Ablation

    SciTech Connect (OSTI)

    Yilmaz, Saim Ceken, Kagan; Alimoglu, Emel; Sindel, Timur

    2013-02-15

    Endovenous laser ablation may be associated with significant pain when performed under standard local tumescent anesthesia. The purpose of this study was to investigate the efficacy of femoral and sciatic nerve blocks for analgesia during endovenous ablation in patients with lower extremity venous insufficiency. During a 28-month period, ultrasound-guided femoral or sciatic nerve blocks were performed to provide analgesia during endovenous laser ablation in 506 legs and 307 patients. The femoral block (n = 402) was performed at the level of the inguinal ligament, and the sciatic block at the posterior midthigh (n = 124), by injecting a diluted lidocaine solution under ultrasound guidance. After the blocks, endovenous laser ablations and other treatments (phlebectomy or foam sclerotherapy) were performed in the standard fashion. After the procedures, a visual analogue pain scale (1-10) was used for pain assessment. After the blocks, pain scores were 0 or 1 (no pain) in 240 legs, 2 or 3 (uncomfortable) in 225 legs, and 4 or 5 (annoying) in 41 legs. Patients never experienced any pain higher than score 5. The statistical analysis revealed no significant difference between the pain scores of the right leg versus the left leg (p = 0.321) and between the pain scores after the femoral versus sciatic block (p = 0.7). Ultrasound-guided femoral and sciatic nerve blocks may provide considerable reduction of pain during endovenous laser and other treatments, such as ambulatory phlebectomy and foam sclerotherapy. They may make these procedures more comfortable for the patient and easier for the operator.

  17. Detecting and Blocking Network Attacks at Ultra High Speeds

    SciTech Connect (OSTI)

    Paxson, Vern

    2010-11-29

    Stateful, in-depth, in-line traffic analysis for intrusion detection and prevention has grown increasingly more difficult as the data rates of modern networks rise. One point in the design space for high-performance network analysis - pursued by a number of commercial products - is the use of sophisticated custom hardware. For very high-speed processing, such systems often cast the entire analysis process in ASICs. This project pursued a different architectural approach, which we term Shunting. Shunting marries a conceptually quite simple hardware device with an Intrusion Prevention System (IPS) running on commodity PC hardware. The overall design goal is was to keep the hardware both cheap and readily scalable to future higher speeds, yet also retain the unparalleled flexibility that running the main IPS analysis in a full general-computing environment provides. The Shunting architecture we developed uses a simple in-line hardware element that maintains several large state tables indexed by packet header fields, including IP/TCP flags, source and destination IP addresses, and connection tuples. The tables yield decision values the element makes on a packet-by-packet basis: forward the packet, drop it, or divert ('shunt') it through the IPS (the default). By manipulating table entries, the IPS can, on a fine-grained basis: (i) specify the traffic it wishes to examine, (ii) directly block malicious traffic, and (iii) 'cut through' traffic streams once it has had an opportunity to 'vet' them, or (iv) skip over large items within a stream before proceeding to further analyze it. For the Shunting architecture to yield benefits, it needs to operate in an environment for which the monitored network traffic has the property that - after proper vetting - much of it can be safely skipped. This property does not universally hold. For example, if a bank needs to examine all Web traffic involving its servers for regulatory compliance, then a monitor in front of one of the bank's server farms cannot safely omit a subset of the traffic from analysis. In this environment, Shunting cannot realize its main performance benefits, and the monitoring task likely calls for using custom hardware instead. However, in many other environments we find Shunting holds promise for delivering major performance gains. This arises due to the the widely documented 'heavy tail' nature of most forms of network traffic, which we might express as 'a few of the connections carry just about all the bytes.' The key additional insight is '... and very often for these few large connections, the very beginning of the connection contains nearly all the information of interest from a security analysis perspective.' We argue that this second claim holds because it is at the beginning of connections that authentication exchanges occur, data or file names and types are specified, request and reply status codes conveyed, and encryption is negotiated. Once these occur, we have seen most of the interesting facets of the dialog. Certainly the remainder of the connection might also yield some grist for analysis, but this is generally less likely, and thus if we want to lower analysis load at as small a loss as possible of information relevant to security analysis, we might best do so by skipping the bulk of large connections. In a different context, the 'Time Machine' work by Kornexl and colleagues likewise shows that in some environments we can realize major reductions in the volume of network traffic processed, by limiting the processing to the first 10-20 KB of each connection. As a concrete example, consider an IPS that monitors SSH traffic. When a new SSH connection arrives and the Shunt fails to find an entry for it in any of its tables (per-address, per-port, per-connection), it executes the default action of diverting the connection through the IPS. The IPS analyzes the beginning of the connection in this fashion. As long as it is satisified with the dialog, it reinjects the packets forwarded to it so that the connection can continue. If the connection successfully

  18. Preventive maintenance system for the photomultiplier detector blocks of PET scanners

    DOE Patents [OSTI]

    Levy, A.V.; Warner, D.

    1995-01-24

    A system including a method and apparatus for preventive maintenance of PET scanner photomultiplier detector blocks is disclosed. The qualitative comparisons used in the method of the present invention to provide an indication in the form of a display or printout advising the user that the photomultiplier block is stable, intermittently unstable, or drifting unstable, and also advising of the expected date of failure of a photomultiplier block in the PET scanner. The system alerts the user to replace the defective photomultiplier block prior to catastrophic failure in a scheduled preventative maintenance program, thus eliminating expensive and unscheduled downtime of the PET scanner due to photomultiplier failure. The apparatus for carrying out the method of the present invention preferably resides in the host computer controlling a PET scanner. It includes a memory adapted for storing a record of a number of iterative adjustments that are necessary to calibrate the gain of a photomultiplier detector block i at a time t[sub 0], a time t[sub 1] and a time T, where T>t[sub 1]>t[sub 0], which is designated as Histo(i,j(t)). The apparatus also includes a processor configured by a software program or a combination of programmed RAM and ROM devices to perform a number of calculations and operations on these values, and also includes a counter for analyzing each photomultiplier detector block i=1 through I of a PET scanner. 40 figures.

  19. Preventive maintenance system for the photomultiplier detector blocks of pet scanners

    DOE Patents [OSTI]

    Levy, Alejandro V. (Center Moriches, NY); Warner, Donald (Shirley, NY)

    1995-01-24

    A system including a method and apparatus for preventive maintenance of PET scanner photomultiplier detector blocks is disclosed. The quantitive comparisons used in the method of the present invention to provide an indication in the form of a display or printout advising the user that the photomultiplier block is stable, intermittently unstable, or drifting unstable, and also advising of the expected date of failure of a photomultiplier block in the PET scanner. The system alerts the user to replace the defective photomultiplier block prior to catastrophic failure in a scheduled preventative maintenance program, thus eliminating expensive and unscheduled downtime of the PET scanner due to photomultiplier failure. The apparatus for carrying out the method of the present invention preferably resides in the host computer controlling a PET scanner. It includes a memory adapted for storing a record of a number of iterative adjustments that are necessary to calibrate the gain of a photomultiplier detector block i at a time t.sub.0, a time t.sub.1 and a time T, where T>t.sub.1 >t.sub.0, which is designated as Histo(i,j(t)). The apparatus also includes a processor configured by a software program or a combination of programmed RAM and ROM devices to perform a number of calculations and operations on these values, and also includes a counter for analyzing each photomultiplier detector block i=1 through I of a PET scanner.

  20. Ordered porous mesostructured materials from nanoparticle-block copolymer self-assembly

    DOE Patents [OSTI]

    Warren, Scott; Wiesner, Ulrich; DiSalvo, Jr., Francis J

    2013-10-29

    The invention provides mesostructured materials and methods of preparing mesostructured materials including metal-rich mesostructured nanoparticle-block copolymer hybrids, porous metal-nonmetal nanocomposite mesostructures, and ordered metal mesostructures with uniform pores. The nanoparticles can be metal, metal alloy, metal mixture, intermetallic, metal-carbon, metal-ceramic, semiconductor-carbon, semiconductor-ceramic, insulator-carbon or insulator-ceramic nanoparticles, or combinations thereof. A block copolymer/ligand-stabilized nanoparticle solution is cast, resulting in the formation of a metal-rich (or semiconductor-rich or insulator-rich) mesostructured nanoparticle-block copolymer hybrid. The hybrid is heated to an elevated temperature, resulting in the formation of an ordered porous nanocomposite mesostructure. A nonmetal component (e.g., carbon or ceramic) is then removed to produce an ordered mesostructure with ordered and large uniform pores.

  1. Influence of shape and skin of matrix-rock blocks on pressure transients in fractured reservoirs

    SciTech Connect (OSTI)

    de Swaan, A.

    1986-01-01

    A formulation of pressure transients in terms of the intrinsic, or core, properties of the two media that compose the fractured reservoir, establishes the influence of these properties, and reciprocally, their corroboration from - the pressure-time relationship observed in well tests and interference tests. The following reservoir characteristics are analyzed: the area of fractures transverse to flow; the dimensions, shape and properties of rectangular parallelepiped matrix-rock blocks; and a permeability reduction in the blocks surface. A restatement of the so-called pseudo-steady state inter-media flow gives to parameters alfa and lambda in the theory of a previous study the physical meaning they lacked, and allows a direct determination of the blocks minimum dimension.

  2. Millisecond ordering of block-copolymer films via photo-thermal gradients

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in lessmore » than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.« less

  3. Computer simulation of shading and blocking: Discussion of accuracy and recommendations

    SciTech Connect (OSTI)

    Lipps, F W

    1992-04-01

    A field of heliostats suffers losses caused by shading and blocking by neighboring heliostats. The complex geometry of multiple shading and blocking events suggests that a processing code is needed to update the boundary vector for each shading or blocking event. A new version, RSABS, (programmer`s manual included) simulates the split-rectangular heliostat. Researchers concluded that the dominant error for the given heliostat geometry is caused by the departure from planarity of the neighboring heliostats. It is recommended that a version of the heliostat simulation be modified to include losses due to nonreflective structural margins, if they occur. Heliostat neighbors should be given true guidance rather than assumed to be parallel, and the resulting nonidentical quadrilateral images should be processed, as in HELIOS, by ignoring overlapping events, rare in optimized fields.

  4. Block Diagram Simulator to Solve a User-Defined Network of Differential Equatios

    Energy Science and Technology Software Center (OSTI)

    1996-12-18

    BDBSIM simulates control and protection systems found in fossil and nuclear power plants. The software is based on the identification of a general equation form that encompasses all control and protection equations encountered in these plants. The user enters his equations in block diagram form as a collection of individual dynamic function, logic, and table blocks. Constructing plant control equations in this manner is analogous to setting up an analog computer for simulation. The capabilitymore » is thus sufficiently general for use in modeling a wide variety of control and protection systems.« less

  5. Capitol Area East End, Block 225: California Department of Education Headquarters

    High Performance Buildings Database

    Sacramento, CA The California Department of Education Headquarters, Block 225 was the first of the five buildings to make up the Capitol Area East End Complex. The entire project is being developed by the California Department of General Services Real Estate Division. At 336,000 square feet and six stories high, Block 225 was the most ambitious green-building initiative to have been undertaken by the State at that time and the largest office building project ever undertaken by the State. The project was delivered through a bridged design-build process.

  6. Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents

    DOE Patents [OSTI]

    Aldissi, M.

    1984-06-27

    An electrically conductive block copolymer of polyisoprene and polyacetylene and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I/sub 2/ to give it an electrical conductivity in the metallic regime.

  7. Exploring the effect of noise on the performance benefit of non-blocking

    Office of Scientific and Technical Information (OSTI)

    MPI_Allreduce. (Conference) | SciTech Connect Exploring the effect of noise on the performance benefit of non-blocking MPI_Allreduce. Citation Details In-Document Search Title: Exploring the effect of noise on the performance benefit of non-blocking MPI_Allreduce. Abstract not provided. Authors: Widener, Patrick ; Ferreira, Kurt Brian ; Levy, Scott N. Publication Date: 2014-05-01 OSTI Identifier: 1145671 Report Number(s): SAND2014-4228C 518355 DOE Contract Number: DE-AC04-94AL85000 Resource

  8. New Materials Family on the Block | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    New Materials Family on the Block Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 12.14.15 New Materials Family on the Block A family of single-phase

  9. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  10. € National Energy Policy Act Guide for State Energy Program and Energy Efficiency and Conservation Block Grant Projects

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    STATE ENERGY PROGRAM NOTICE (10-001) AND ENERGY EFFICIENCY CONSERVATION BLOCK GRANT PROGRAM NOTICE (10-003) EFFECTIVE DATE: December 17, 2009 SUBJECT: NATIONAL ENVIRONMENTAL POLICY ACT GUIDE FOR STATE ENERGY PROGRAM AND ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROJECTS PURPOSE: This guidance is designed to help applicants for or recipients of funds from DOE's State Energy Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) program (Grantees). Grantees may not spend

  11. Materials Dow Select Decisions Made Within DOEs Chemical Hydrogen Storage Center of Excellence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report Submitted by: The Chemical Hydrogen Storage Center of Excellence Coordinating Council Authors: Kevin C. Ott, Los Alamos National Laboratory Sue Linehan, Rohm and Haas Company Frank Lipiecki, Rohm and Haas Company Christopher L. Aardahl, Pacific Northwest National Laboratory May 2008 Acknowledgements The

  12. Ford-Dow Partnership Is Linked to Carbon Fiber Research at ORNL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and ORNL to demonstrate a novel polymer fiber material and production process technology. ... in research and development, materials science, and high-volume polymer processing. ...

  13. Guidance for Energy Efficiency and Conservation Block Grant Grantees on Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds

    Office of Energy Efficiency and Renewable Energy (EERE)

    Guidance for Energy Efficiency and Conservation Block Grant Program grantees regarding Qualified Energy Conservation Bonds (QECBs) and New Clean Renewable Energy Bonds (New CREBs)

  14. EECBG Program Notice 10-020B, Guidance for Energy Efficiency and Conservation Block Grant Recipients on Closeout Procedures

    Broader source: Energy.gov [DOE]

    U.S. Department of Energy Weatherization and Intergovernmental Program guidance for the Energy Efficiency and Conservation Block Grant Program on closeout procedures, revised January 8, 2013.

  15. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS.

    Broader source: Energy.gov [DOE]

    This document provides guidance for energy efficiency and block grant recipients on closeout procedures for non-state energy office recipients.

  16. EECBG Program Notice 09-002B- Guidance for Energy Efficiency and Conservation Block Grant Grantees on financing programs

    Broader source: Energy.gov [DOE]

    This document provides guidance to the Department of Energys (Department or DOE) Energy Efficiency and Conservation Block Grant (EECBG) grantees on financing programs.

  17. Compact microwave lamp having a tuning block and a dielectric located in a lamp cavity

    DOE Patents [OSTI]

    Simpson, James E.

    2000-01-01

    A microwave lamp having a compact structure utilizing a coupling slot which has a dielectric member extending therethrough and a tuning block adjoining the coupling slot. A non-conventional waveguide is used which has about the width of a WR-284 waveguide and about the length of a WR-340 waveguide.

  18. Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs

    Broader source: Energy.gov [DOE]

    U.S. Department of Energy (DOE) Weatherization and Intergovernmental Program (WIP) Energy Efficiency and Conservation Block Grant (EECBG) Program Notice 09-002D modified October 17, 2012 that provides guidance about financing programs for state and local governments, overseas U.S. territories, and Indian tribes that receive EECBG funding from DOE.

  19. Energy Efficiency and Conservation Block Grant Program National Evaluation Executive Summary

    Broader source: Energy.gov [DOE]

    This document presents findings from an evaluation of the Energy Efficiency and Conservation Block Grant Program, a national program operated by the U.S. Department of Energy from 2009 to 2015 that provided grants and technical assistance to local governments, states and territories to support a wide variety of energy efficiency and renewable energy activities.

  20. Efficient block processing of long duration biotelemetric brain data for health care monitoring

    SciTech Connect (OSTI)

    Soumya, I.; Zia Ur Rahman, M.; Rama Koti Reddy, D. V.; Lay-Ekuakille, A.

    2015-03-15

    In real time clinical environment, the brain signals which doctor need to analyze are usually very long. Such a scenario can be made simple by partitioning the input signal into several blocks and applying signal conditioning. This paper presents various block based adaptive filter structures for obtaining high resolution electroencephalogram (EEG) signals, which estimate the deterministic components of the EEG signal by removing noise. To process these long duration signals, we propose Time domain Block Least Mean Square (TDBLMS) algorithm for brain signal enhancement. In order to improve filtering capability, we introduce normalization in the weight update recursion of TDBLMS, which results TD-B-normalized-least mean square (LMS). To increase accuracy and resolution in the proposed noise cancelers, we implement the time domain cancelers in frequency domain which results frequency domain TDBLMS and FD-B-Normalized-LMS. Finally, we have applied these algorithms on real EEG signals obtained from human using Emotive Epoc EEG recorder and compared their performance with the conventional LMS algorithm. The results show that the performance of the block based algorithms is superior to the LMS counter-parts in terms of signal to noise ratio, convergence rate, excess mean square error, misadjustment, and coherence.

  1. Synthesis and Characterization of Stimuli Responsive Block Copolymers, Self-Assembly Behavior and Applications

    SciTech Connect (OSTI)

    Michael Duane Determan

    2005-12-17

    The central theme of this thesis work is to develop new block copolymer materials for biomedical applications. While there are many reports of stimuli-responsive amphiphilic [19-21] and crosslinked hydrogel materials [22], the development of an in situ gel forming, pH responsive pentablock copolymer is a novel contribution to the field, Figure 1.1 is a sketch of an ABCBA pentablock copolymer. The A blocks are cationic tertiary amine methacrylates blocked to a central Pluronic F127 triblock copolymer. In addition to the prerequisite synthetic and macromolecular characterization of these new materials, the self-assembled supramolecular structures formed by the pentablock were experimentally evaluated. This synthesis and characterization process serves to elucidate the important structure property relationships of these novel materials, The pH and temperature responsive behavior of the pentablock copolymer were explored especially with consideration towards injectable drug delivery applications. Future synthesis work will focus on enhancing and tuning the cell specific targeting of DNA/pentablock copolymer polyplexes. The specific goals of this research are: (1) Develop a synthetic route for gel forming pentablock block copolymers with pH and temperature sensitive properties. Synthesis of these novel copolymers is accomplished with ATRP, yielding low polydispersity and control of the block copolymer architecture. Well defined macromolecular characteristics are required to tailor the phase behavior of these materials. (2) Characterize relationship between the size and shape of pentablock copolymer micelles and gel structure and the pH and temperature of the copolymer solutions with SAXS, SANS and CryoTEM. (3) Evaluate the temperature and pH induced phase separation and macroscopic self-assembly phenomenon of the pentablock copolymer. (4) Utilize the knowledge gained from first three goals to design and formulate drug delivery formulations based on the multi-responsive properties of the pentablock copolymer. Demonstrate potential biomedical applications of these materials with in vitro drug release studies from pentablock copolymer hydrogels. The intent of this work is to contribute to the knowledge necessary for further tailoring of these, and other functional block copolymer materials for biomedical applications.

  2. Synthesis and Characterization of Smart Block Copolymers for Biomineralization and Biomedical Applications

    SciTech Connect (OSTI)

    Mathumai Kanapathipillai

    2008-08-18

    Self-assembly is a powerful tool in forming structures with nanoscale dimensions. Self-assembly of macromolecules provides an efficient and rapid pathway for the formation of structures from the nanometer to micrometer range that are difficult, if not impossible to obtain by conventional lithographic techniques [1]. Depending on the morphologies obtained (size, shape, periodicity, etc.) these self-assembled systems have already been applied or shown to be useful for a number of applications in nanotechnology [2], biomineralization [3, 4], drug delivery [5, 6] and gene therapy [7]. In this respect, amphiphilic block copolymers that self-organize in solution have been found to be very versatile [1]. In recent years, polymer-micellar systems have been designed that are adaptable to their environment and able to respond in a controlled manner to external stimuli. In short, synthesis of 'nanoscale objects' that exhibit 'stimulus-responsive' properties is a topic gathering momentum, because their behavior is reminiscent of that exhibited by proteins [8]. By integrating environmentally sensitive homopolymers into amphiphilic block copolymers, smart block copolymers with self assembled supramolecular structures that exhibit stimuli or environmentally responsive properties can be obtained [1]. Several synthetic polymers are known to have environmentally responsive properties. Changes in the physical, chemical or biochemical environment of these polymers results in modulation of the solubility or chain conformation of the polymer [9]. There are many common schemes of engineering stimuli responsive properties into materials [8, 9]. Polymers exhibiting lower critical solution temperature (LCST) are soluble in solvent below a specific temperature and phase separate from solvent above that temperature while polymers exhibiting upper critical solution temperatures (UCST) phase separate below a certain temperature. The solubility of polymers with ionizable moieties depends on the pH of the solution. Polymers with polyzwitterions, anions and cations have been shown to exhibit pH responsive self assembly. Other stimuli responsive polymers include glucose sensitive polymers, calcium ion-sensitive polymers and so on. Progress in living radical polymerization (LRP) methods [10] has made it possible for the facile synthesis of these block copolymer systems with controlled molecular weights and well defined architectures. The overall theme of this work is to develop novel smart block copolymers for biomineralization and biomedical applications. Synthesis and characterization of self-assembling thermoreversible ionic block copolymers as templates in biomimetic nanocomposite synthesis using a bottom-up approach is a novel contribution in this respect. Further, we have extended these families of copolymers to include block copolymer-peptide conjugates to enhance biological specificity. Future directions on this work will focus on enhancing the polymer templating properties for biomineralization by expanding the family of block copolymers with organic polypeptides and biological polypeptide scaffolds as well as a detailed understanding of the polymer-inorganic nanocomposites at the molecular level using small angle scattering analysis. Glucose responsive polymer hydrogels for drug delivery, polymer-ligand conjugates for non-viral therapy and thermoresponsive injectable photocrosslinkable hydrogels for posttraumatic arthritis cartilage healing are other applications of these novel copolymers synthesized in our work.

  3. Block copolymer with simultaneous electric and ionic conduction for use in lithium ion batteries

    SciTech Connect (OSTI)

    ;

    2013-10-08

    Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction. A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO.sub.4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.

  4. Dilute group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2015-02-24

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  5. Dilute Group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2012-07-31

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  6. K+ block is the mechanism of functional asymmetry in bacterial Nav channels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ngo, Van; Wang, Yibo; Haas, Stephan; Noskov, Sergei Y.; Farley, Robert A.; Weinstein, Harel

    2016-01-04

    Crystal structures of several bacterial Nav channels have been recently published and molecular dynamics simulations of ion permeation through these channels are consistent with many electrophysiological properties of eukaryotic channels. Bacterial Nav channels have been characterized as functionally asymmetric, and the mechanism of this asymmetry has not been clearly understood. To address this question, we combined non-equilibrium simulation data with two-dimensional equilibrium unperturbed landscapes generated by umbrella sampling and Weighted Histogram Analysis Methods for multiple ions traversing the selectivity filter of bacterial NavAb channel. This approach provided new insight into the mechanism of selective ion permeation in bacterial Nav channels.more » The non-equilibrium simulations indicate that two or three extracellular K+ ions can block the entrance to the selectivity filter of NavAb in the presence of applied forces in the inward direction, but not in the outward direction. The block state occurs in an unstable local minimum of the equilibrium unperturbed free-energy landscape of two K+ ions that can be ‘locked’ in place bymodest applied forces. In contrast to K+, three Na+ ions move favorably through the selectivity filter together as a unit in a loose “knock-on” mechanism of permeation in both inward and outward directions, and there is no similar local minimum in the two-dimensional free-energy landscape of two Na+ ions for a block state. The useful work predicted by the non-equilibrium simulations that is required to break the K+ block is equivalent to large applied potentials experimentally measured for two bacterial Nav channels to induce inward currents of K+ ions. Here, these results illustrate how inclusion of non-equilibrium factors in the simulations can provide detailed information about mechanisms of ion selectivity that is missing from mechanisms derived from either crystal structures or equilibrium unperturbed free-energy landscapes.« less

  7. Studying the Building Blocks of Matter: Public Talk Planned for Oct. 7 at

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jefferson Lab | Jefferson Lab Studying the Building locks of Matter: Public Talk Planned for Oct. 7 at Jefferson Lab CEBAF Race Track This aerial photo shows the outline of the racetrack-shaped CEBAF accelerator at Jefferson Lab, located in Newport News, Va.. NEWPORT NEWS, VA, Sept. 22, 2014 - In conjunction with Virginia Science Festival events around the Commonwealth, Jefferson Lab Staff Scientist Douglas Higinbotham will present "Studying the Building Blocks of Matter" on Oct.

  8. Revisiting the blocking force test on ferroelectric ceramics using high energy x-ray diffraction

    SciTech Connect (OSTI)

    Daniel, L.; Hall, D. A.; Withers, P. J.; Koruza, J.; Webber, K. G.; King, A.

    2015-05-07

    The blocking force test is a standard test to characterise the properties of piezoelectric actuators. The aim of this study is to understand the various contributions to the macroscopic behaviour observed during this experiment that involves the intrinsic piezoelectric effect, ferroelectric domain switching, and internal stress development. For this purpose, a high energy diffraction experiment is performed in-situ during a blocking force test on a tetragonal lead zirconate titanate (PZT) ceramic (Pb{sub 0.98}Ba{sub 0.01}(Zr{sub 0.51}Ti{sub 0.49}){sub 0.98}Nb{sub 0.02}O{sub 3}). It is shown that the usual macroscopic linear interpretation of the test can also be performed at the single crystal scale, allowing the identification of local apparent piezoelectric and elastic properties. It is also shown that despite this apparent linearity, the blocking force test involves significant non-linear behaviour mostly due to domain switching under electric field and stress. Although affecting a limited volume fraction of the material, domain switching is responsible for a large part of the macroscopic strain and explains the high level of inter- and intra-granular stresses observed during the course of the experiment. The study shows that if apparent piezoelectric and elastic properties can be identified for PZT single crystals from blocking stress curves, they may be very different from the actual properties of polycrystalline materials due to the multiplicity of the physical mechanisms involved. These apparent properties can be used for macroscopic modelling purposes but should be considered with caution if a local analysis is aimed at.

  9. NATIONAL EVALUATION OF THE ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM Executive Summary Prepared for the US Department of Energy Under the Supervision of Oak Ridge National Laboratory Date: June 2015 DNV GL - Energy - www.dnvgl.com/energy ACKNOWLEDGEMENTS We would like to acknowledge the important contributions of the following people: Nick Hall of TecMarket Works was integrally involved with the EECBG National Evaluation from its inception: proposing a study approach; working with DOE and ORNL to prepare a

  10. 50 kW Power Block for Distributed Energy Applications - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Solar Photovoltaic Solar Photovoltaic Industrial Technologies Industrial Technologies Energy Storage Energy Storage Electricity Transmission Electricity Transmission Find More Like This Return to Search 50 kW Power Block for Distributed Energy Applications National Renewable Energy Laboratory Contact NREL About This Technology Actual prototype Actual prototype Technology Marketing Summary Distributed energy (DE) systems have begun to make a significant impact on energy supply and will

  11. Monitoring Plan for Weatherization Assistance Program, State Energy Program and Energy Efficiency and Conservation Block Grants

    Energy Savers [EERE]

    Revised: October 22, 2010 U.S. Department of Energy American Recovery and Reinvestment Act Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Appendix of Compliance Checklists Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants U.S. Department of Energy Appendix of Compliance Checklists October 22, 2010 Concurrences: LeAnn M. Oliver Program Manager, Weatherization &

  12. From: Hope Albright To: Congestion Study Comments Subject: Block Grain Belt

    Office of Environmental Management (EM)

    Hope Albright To: Congestion Study Comments Subject: Block Grain Belt Date: Monday, September 22, 2014 11:52:07 AM I am opposed to the establishment of National Interest Energy Transmission Corridors (NIETC's) for the following reasons. First, the easements place an undo burden on landowners on and near the transmission lines. The compensation cannot begin to cover the all of the losses, tangible and intangible that landowners would suffer. Second, I believe that condemning private property for

  13. From: Kathy Mikels To: Congestion Study Comments Subject: STOP CLEAN LINE, BLOCK GRAIN BELT

    Office of Environmental Management (EM)

    Kathy Mikels To: Congestion Study Comments Subject: STOP CLEAN LINE, BLOCK GRAIN BELT Date: Monday, September 22, 2014 1:33:53 PM I am opposed to the establishment of National Interest Energy Transmission Corridors (NIETC's) for the following reasons. First, the easements place an undo burden on landowners on and near the transmission lines. The compensation cannot begin to cover the all of the losses, tangible and intangible that landowners would suffer. Second, I believe that condemning

  14. Thermally-induced transition of lamellae orientation in block-copolymer films on ‘neutral’ nanoparticle-coated substrates

    SciTech Connect (OSTI)

    Yager, Kevin G.; Forrey, Christopher; Singh, Gurpreet; Satija, Sushil K.; Page, Kirt A.; Patton, Derek L.; Jones, Ronald L.; Karin, Alamgir; Douglas, Jack F.

    2015-06-01

    Block-copolymer orientation in thin films is controlled by the complex balance between interfacial free energies, including the inter-block segregation strength, the surface tensions of the blocks, and the relative substrate interactions. While block-copolymer lamellae orient horizontally when there is any preferential affinity of one block for the substrate, we recently described how nanoparticle-roughened substrates can be used to modify substrate interactions. We demonstrate how such ‘neutral’ substrates can be combined with control of annealing temperature to generate vertical lamellae orientations throughout a sample, at all thicknesses. We observe an orientational transition from vertical to horizontal lamellae upon heating, as confirmed using a combination of atomic force microscopy (AFM), neutron reflectometry (NR) and rotational small-angle neutron scattering (RSANS). Using molecular dynamics (MD) simulations, we identify substrate-localized distortions to the lamellar morphology as the physical basis of the novel behavior. In particular, under strong segregation conditions, bending of horizontal lamellae induce a large energetic cost. At higher temperatures, the energetic cost of conformal deformations of lamellae over the rough substrate is reduced, returning lamellae to the typical horizontal orientation. Thus, we find that both surface interactions and temperature play a crucial role in dictating block-copolymer lamellae orientation. As a result, our combined experimental and simulation findings suggest that controlling substrate roughness should provide a useful and robust platform for controlling block-copolymer orientation in applications of these materials.

  15. Thermally-induced transition of lamellae orientation in block-copolymer films on ‘neutral’ nanoparticle-coated substrates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yager, Kevin G.; Forrey, Christopher; Singh, Gurpreet; Satija, Sushil K.; Page, Kirt A.; Patton, Derek L.; Jones, Ronald L.; Karin, Alamgir; Douglas, Jack F.

    2015-06-01

    Block-copolymer orientation in thin films is controlled by the complex balance between interfacial free energies, including the inter-block segregation strength, the surface tensions of the blocks, and the relative substrate interactions. While block-copolymer lamellae orient horizontally when there is any preferential affinity of one block for the substrate, we recently described how nanoparticle-roughened substrates can be used to modify substrate interactions. We demonstrate how such ‘neutral’ substrates can be combined with control of annealing temperature to generate vertical lamellae orientations throughout a sample, at all thicknesses. We observe an orientational transition from vertical to horizontal lamellae upon heating, as confirmedmore » using a combination of atomic force microscopy (AFM), neutron reflectometry (NR) and rotational small-angle neutron scattering (RSANS). Using molecular dynamics (MD) simulations, we identify substrate-localized distortions to the lamellar morphology as the physical basis of the novel behavior. In particular, under strong segregation conditions, bending of horizontal lamellae induce a large energetic cost. At higher temperatures, the energetic cost of conformal deformations of lamellae over the rough substrate is reduced, returning lamellae to the typical horizontal orientation. Thus, we find that both surface interactions and temperature play a crucial role in dictating block-copolymer lamellae orientation. As a result, our combined experimental and simulation findings suggest that controlling substrate roughness should provide a useful and robust platform for controlling block-copolymer orientation in applications of these materials.« less

  16. Blocking effect of crystalglass interface in lanthanum doped barium strontium titanate glassceramics

    SciTech Connect (OSTI)

    Wang, Xiangrong; Zhang, Yong; Baturin, Ivan; Liang, Tongxiang

    2013-10-15

    Graphical abstract: The blocking effect of the crystalglass interface on the carrier transport behavior in the lanthanum doped barium strontium titanate glassceramics: preparation and characterization. - Highlights: La{sub 2}O{sub 3} addition promotes the crystallization of the major crystalline phase. The Z? and M? peaks exist a significant mismatch for 0.5 mol% La{sub 2}O{sub 3} addition. The Z? and M? peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. Crystallite impedance decreases while crystalglass interface impedance increases. La{sub 2}O{sub 3} addition increases blocking factor of the crystalglass interface. - Abstract: The microstructures and dielectric properties in La{sub 2}O{sub 3}-doped barium strontium titanate glassceramics have been investigated by scanning electron microscopy (SEM) and impedance spectroscopy. SEM analysis indicated that La{sub 2}O{sub 3} additive decreases the average crystallite size. Impedance spectroscopy revealed that the positions of Z? and M? peaks are close for undoped samples. When La{sub 2}O{sub 3} concentration is 0.5 mol%, the Z? and M? peaks show a significant mismatch. Furthermore, these peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. With increasing La{sub 2}O{sub 3} concentration, the contribution of the crystallite impedance becomes smaller, while the contribution of the crystalglass interface impedance becomes larger. More interestingly, it was found that La{sub 2}O{sub 3} additive increases blocking factor of the crystalglass interface in the temperature range of 250450 C. This may be attributed to a decrease of activation energy of the crystallite and an increase of the crystalglass interface area.

  17. Dynamically reassigning a connected node to a block of compute nodes for re-launching a failed job

    DOE Patents [OSTI]

    Budnik, Thomas A. (Rochester, MN); Knudson, Brant L. (Rochester, MN); Megerian, Mark G. (Rochester, MN); Miller, Samuel J. (Rochester, MN); Stockdell, William M. (Byron, MN)

    2012-03-20

    Methods, systems, and products for dynamically reassigning a connected node to a block of compute nodes for re-launching a failed job that include: identifying that a job failed to execute on the block of compute nodes because connectivity failed between a compute node assigned as at least one of the connected nodes for the block of compute nodes and its supporting I/O node; and re-launching the job, including selecting an alternative connected node that is actively coupled for data communications with an active I/O node; and assigning the alternative connected node as the connected node for the block of compute nodes running the re-launched job.

  18. Interpenetrating metal-organic frameworks formed by self-assembly of tetrahedral and octahedral building blocks

    SciTech Connect (OSTI)

    Lu Yongming; Lan Yaqian; Xu Yanhong; Su Zhongmin; Li Shunli; Zang Hongying; Xu Guangjuan

    2009-11-15

    To investigate the relationship between topological types and molecular building blocks (MBBs), we have designed and synthesized a series of three-dimensional (3D) interpenetrating metal-organic frameworks based on different polygons or polyhedra under hydrothermal conditions, namely [Cd(bpib){sub 0.5}(L{sup 1})] (1), [Cd(bpib){sub 0.5}(L{sup 2})].H{sub 2}O (2), [Cd(bpib){sub 0.5}(L{sup 3})] (3) and [Cd(bib){sub 0.5}(L{sup 1})] (4), where bpib=1,4-bis(2-(pyridin-2-yl)-1H-imidazol-1-yl)butane, bib=1,4-bis(1H-imidazol-1-yl)butane, H{sub 2}L{sup 1}=4-(4-carboxybenzyloxy)benzoic acid, H{sub 2}L{sup 2}=4,4'-(ethane-1,2-diylbis(oxy))dibenzoic acid and H{sub 2}L{sup 3}=4,4'-(1,4-phenylenebis(methylene))bis(oxy)dibenzoic acid, respectively. Their structures have been determined by single crystal X-ray diffraction analyses and further characterized by elemental analyses, IR spectra, and thermogravimetric (TG) analyses. Compounds 1-3 display alpha-Po topological nets with different degrees of interpenetration based on the similar octahedral [Cd{sub 2}(-COO){sub 4}] building blocks. Compound 4 is a six-fold interpenetrating diamondoid net based on tetrahedral MBBs. By careful inspection of these structures, we find that various carboxylic ligands and N-donor ligands with different coordination modes and conformations, and metal centers with different geometries are important for the formation of the different MBBs. It is believed that different topological types lie on different MBBs with various polygons or polyhedra. Such as four- and six-connected topologies are formed by tetrahedral and octahedral building blocks. In addition, with the increase of carboxylic ligands' length, the degrees of interpenetration have been changed in the alpha-Po topological nets. And the luminescent properties of these compounds have been investigated in detail. - Graphical abstract: A series of three-dimensional interpenetrating metal-organic frameworks based on different polygons or polyhedra has been synthesized. The crystal structures and topological analysis of these compounds, along with a systematic investigation of the relationship between topological types and molecular building blocks, will be discussed.

  19. Nanoporous polysulfone membranes via a degradable block copolymer precursor for redox flow batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gindt, Brandon P.; Abebe, Daniel G.; Tang, Zhijiang J.; Lindsey, Melanie B.; Chen, Jihua; Elgammal, Ramez A.; Zawodzinski, Thomas A.; Fujiwara, Tomoko

    2016-02-16

    In this study, nanoporous polysulfone (PSU) membranes were fabricated via post-hydrolysis of polylactide (PLA) from PLA–PSU–PLA triblock copolymer membranes. The PSU scaffold was thermally crosslinked before sacrificing PLA blocks. The resulting nanopore surface was chemically modified with sulfonic acid moieties. The membranes were analyzed and evaluated as separators for vanadium redox flow batteries. Nanoporous PSU membranes prepared by this new method and further chemically modified to a slight degree exhibited unique behavior with respect to their ionic conductivity when exposed to solutions of increasing acid concentration.

  20. Nanoscale Building Blocks and DNA "Glue" Help Shape 3D Architectures |

    Office of Science (SC) Website

    U.S. DOE Office of Science (SC) Nanoscale Building Blocks and DNA "Glue" Help Shape 3D Architectures Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More

  1. AMENDMENT OF SOLICITATION/MODIFICATlON OF CONTRACT MI54 I See Block 16C I

    National Nuclear Security Administration (NNSA)

    MI54 I See Block 16C I REQ. NO. Babcock & Wilcox Technical Services Pantex, LLC PO Box 30020 Amarillo, TX 79120 2. AMENDMENTIMODIFICATION NO. 1 3. EFFECTIVE DATE 1 4. REQUlSlTlONlPURCHASE 1 5. PROJECT NO. (If a ~ ~ l i c a b l e ) l.CoNTRACTIDCODE ~ . . U.S. Department of Energy National Nuclear Security Administration Service Center Property and M&O Contract Support Department P.O. Box 5400 Albuquerque, NM 87185-5400 I I 9B. DATED (SEE ITEM 1 1 ) PAGE 1 OF 2 PAGES 6. ISSUED BY CODE 1 7.

  2. Primary arm spacing in chill block melt spun Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient.

  3. Costs Incurred by Selected Tribal Energy Efficiency and Conservation Block Grant Recipients, OAS-RA-13-28

    Energy Savers [EERE]

    Costs Incurred by Selected Tribal Energy Efficiency and Conservation Block Grant Recipients OAS-RA-13-28 July 2013 Department of Energy Washington, DC 20585 July 18, 2013 MEMORANDUM FOR THE ASSISTANT SECRETARY FOR ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Rickey R. Hass Deputy Inspector General for Audits and Inspections Office of Inspector General SUBJECT: INFORMATION: Audit Report on "Costs Incurred by Selected Tribal Energy Efficiency and Conservation Block Grant Recipients"

  4. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT GRANTEES ON Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EECBG PROGRAM NOTICE 10-018 EFFECTIVE DATE: July 27, 2010 SUBJECT: GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT GRANTEES ON QUALIFIED ENERGY CONSERVATION BONDS AND NEW CLEAN RENEWABLE ENERGY BONDS. PURPOSE To provide guidance to the Department of Energy's (Department or DOE) Energy Efficiency and Conservation Block Grant (EECBG) grantees regarding Qualified Energy Conservation Bonds (QECBs) and New Clean Renewable Energy Bonds (New CREBs). SCOPE The provisions of this guidance

  5. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Washington , DC 20585 EECBG PROGRAM NOTICE 10-020a EFFECTIVE DATE: October 3, 2011 SUBJECT: GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. STATE ENERGY OFFICE RECIPIENTS SHOULD FOLLOW THE FORTHCOMING STATE ENERGY PROGRAM NOTICE FOR GUIDANCE ON CLOSEOUT PROCEDURES PURPOSE To provide an overview to Department of Energy's (DOE) Energy Efficiency and Conservation Block Grant (EECBG) Program non-State grant

  6. EECBG Program Notice 09-002B - Guidance for Energy Efficiency and Conservation Block Grant Grantees on financing programs

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    B EFFECTIVE DATE (Revised): August 10, 2010 ORIGINALLY ISSUED: December 7, 2009 SUBJECT: GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT GRANTEES ON FINANCING PROGRAMS. PURPOSE To provide guidance to the Department of Energy's (Department or DOE) Energy Efficiency and Conservation Block Grant (EECBG) grantees on financing programs. This guidance supersedes EECBG Program Notice 09-002A, which was issued on June 29, 2010. SCOPE The provisions of this guidance apply to grantees of EECBG

  7. The Status of Energy Efficiency and Conservation Block Grant Recipients' Obligations, OAS-RA-11-16

    Energy Savers [EERE]

    Management Alert The Status of Energy Efficiency and Conservation Block Grant Recipients' Obligations OAS-RA-11-16 September 2011 Department of Energy Washington, DC 20585 September 1, 2011 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman Inspector General SUBJECT: INFORMATION: Management Alert on "The Status of Energy Efficiency and Conservation Block Grant Recipients' Obligations" IMMEDIATE CONCERN Because of the unprecedented level of funding provided under the American

  8. GaAs Blocked-Impurity-Band Detectors for Far-Infrared Astronomy

    SciTech Connect (OSTI)

    Cardozo, Benjamin Lewin

    2004-12-21

    High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing layer of a BIB detector, has been achieved. The control of the donor concentration, however, was found to be insufficient for detector production. The growth by LPE of a high-purity film onto a commercially grown vapor-phase epitaxial (VPE) n-type GaAs doped absorbing layer resulted in a BIB device that showed a significant reduction in the low-temperature dark current compared to the absorbing layer only. Extended optical response was not detected, most likely due to the high compensation of the commercially grown GaAs absorbing layer, which restricts the depletion width of the device.

  9. Neutral beamline with ion energy recovery based on magnetic blocking of electrons

    DOE Patents [OSTI]

    Stirling, William L.

    1982-01-01

    A neutral beamline generator with energy recovery of the full-energy ion ponent of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the electrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

  10. Neutral beamline with ion energy recovery based on magnetic blocking of electrons

    DOE Patents [OSTI]

    Stirling, W.L.

    1980-07-01

    A neutral beamline generator with energy recovery of the full-energy ion component of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the elecrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

  11. Process Controlled Multiscale Morphologies in Metal-containing Block Copolymer Thin Films

    SciTech Connect (OSTI)

    Ramanathan, Nathan Muruganathan [ORNL] [ORNL; Kilbey, II, S Michael [ORNL; Darling, Seth B. [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL)

    2014-01-01

    Poly(styrene-block-ferrocenyldimethylsilane) (PS-b-PFS) is a metal-containing block copolymer that exhibits certain advantages as a mask for lithographic applications. These advantages include compatibility with a wide range of substrates, ease of control over domain morphologies and robust stability to etch plasma, which aid in the development of high-aspect-ratio patterns. An asymmetric cylinder-forming PS-b-PFS copolymer is subjected to different processing to manipulate the morphology of the phase-separated domains. Control of film structure and domain morphology is achieved by adjusting the film thickness, mode of annealing, and/or annealing time. Changing the process from thermal or solvent annealing to hybrid annealing (thermal and then solvent annealing in sequence) leads to the formation of mesoscale spherulitic and dendritic morphologies. In this communication, we show that reversing the order of the hybrid annealing (solvent annealing first and then thermal annealing) of relatively thick films (>100 nm) on homogeneously thick substrates develops disordered lamellar structure. Furthermore, the same processing applied on a substrate with a thin, mechanically flexible window in the center leads to the formation of sub-micron scale concentric ring patterns. Enhanced material mobility in the thick film during hybrid annealing along with dynamic rippling effects that may arise from the vibration of the thin window during spin casting are likely causes for these morphologies.

  12. Efficient Heterogeneous Execution on Large Multicore and Accelerator Platforms: Case Study Using a Block Tridiagonal Solver

    SciTech Connect (OSTI)

    Park, Alfred J [ORNL] [ORNL; Perumalla, Kalyan S [ORNL] [ORNL

    2013-01-01

    The algorithmic and implementation principles are explored in gainfully exploiting GPU accelerators in conjunction with multicore processors on high-end systems with large numbers of compute nodes, and evaluated in an implementation of a scalable block tridiagonal solver. The accelerator of each compute node is exploited in combination with multicore processors of that node in performing block-level linear algebra operations in the overall, distributed solver algorithm. Optimizations incorporated include: (1) an efficient memory mapping and synchronization interface to minimize data movement, (2) multi-process sharing of the accelerator within a node to obtain balanced load with multicore processors, and (3) an automatic memory management system to efficiently utilize accelerator memory when sub-matrices spill over the limits of device memory. Results are reported from our novel implementation that uses MAGMA and CUBLAS accelerator software systems simultaneously with ACML for multithreaded execution on processors. Overall, using 940 nVidia Tesla X2090 accelerators and 15,040 cores, the best heterogeneous execution delivers a 10.9-fold reduction in run time relative to an already efficient parallel multicore-only baseline implementation that is highly optimized with intra-node and inter-node concurrency and computation-communication overlap. Detailed quantitative results are presented to explain all critical runtime components contributing to hybrid performance.

  13. Chemically directing d-block heterometallics to nanocrystal surfaces as molecular beacons of surface structure

    SciTech Connect (OSTI)

    Rosen, Evelyn L.; Gilmore, Keith; Sawvel, April M.; Hammack, Aaron T.; Doris, Sean E.; Aloni, Shaul; Altoe, Virginia; Nordlund, Dennis; Weng, Tsu -Chien; Sokaras, Dimosthenis; Cohen, Bruce E.; Urban, Jeffrey J.; Ogletree, D. Frank; Milliron, Delia J.; Prendergast, David; Helms, Brett A.

    2015-07-28

    Our understanding of structure and bonding in nanoscale materials is incomplete without knowledge of their surface structure. Needed are better surveying capabilities responsive not only to different atoms at the surface, but also their respective coordination environments. We report here that d-block organometallics, when placed at nanocrystal surfaces through heterometallic bonds, serve as molecular beacons broadcasting local surface structure in atomic detail. This unique ability stems from their elemental specificity and the sensitivity of their d-orbital level alignment to local coordination environment, which can be assessed spectroscopically. Re-surfacing cadmium and lead chalcogenide nanocrystals with iron- or ruthenium-based molecular beacons is readily accomplished with trimethylsilylated cyclopentadienyl metal carbonyls. For PbSe nanocrystals with iron-based beacons, we show how core-level X-ray spectroscopies and DFT calculations enrich our understanding of both charge and atomic reorganization at the surface when beacons are bound.

  14. Relativistic quasiparticle time blocking approximation. II. Pygmy dipole resonance in neutron-rich nuclei

    SciTech Connect (OSTI)

    Litvinova, E.; Ring, P.; Tselyaev, V.; Langanke, K.

    2009-05-15

    Theoretical studies of low-lying dipole strength in even-even spherical nuclei within the relativistic quasiparticle time blocking approximation (RQTBA) are presented. The RQTBA developed recently as an extension of the self-consistent relativistic quasiparticle random-phase approximation (RQRPA) enables one to investigate the effects of the coupling of two-quasiparticle excitations to collective vibrations within a fully consistent calculation scheme based on covariant energy density functional theory. Dipole spectra of even-even {sup 130}Sn-{sup 140}Sn and {sup 68}Ni-{sup 78}Ni isotopes calculated within both RQRPA and RQTBA show two well-separated collective structures: the higher lying giant dipole resonance and the lower lying pygmy dipole resonance, which can be identified by the different behavior of the transition densities of states in these regions.

  15. Vectorization, threading, and cache-blocking considerations for hydrocodes on emerging architectures

    SciTech Connect (OSTI)

    Fung, J.; Aulwes, R. T.; Bement, M. T.; Campbell, J. M.; Ferenbaugh, C. R.; Jean, B. A.; Kelley, T. M.; Kenamond, M. A.; Lally, B. R.; Lovegrove, E. G.; Nelson, E. M.; Powell, D. M.

    2015-07-14

    This work reports on considerations for improving computational performance in preparation for current and expected changes to computer architecture. The algorithms studied will include increasingly complex prototypes for radiation hydrodynamics codes, such as gradient routines and diffusion matrix assembly (e.g., in [1-6]). The meshes considered for the algorithms are structured or unstructured meshes. The considerations applied for performance improvements are meant to be general in terms of architecture (not specifically graphical processing unit (GPUs) or multi-core machines, for example) and include techniques for vectorization, threading, tiling, and cache blocking. Out of a survey of optimization techniques on applications such as diffusion and hydrodynamics, we make general recommendations with a view toward making these techniques conceptually accessible to the applications code developer. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.

  16. Chemically directing d-block heterometallics to nanocrystal surfaces as molecular beacons of surface structure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rosen, Evelyn L.; Gilmore, Keith; Sawvel, April M.; Hammack, Aaron T.; Doris, Sean E.; Aloni, Shaul; Altoe, Virginia; Nordlund, Dennis; Weng, Tsu -Chien; Sokaras, Dimosthenis; et al

    2015-07-28

    Our understanding of structure and bonding in nanoscale materials is incomplete without knowledge of their surface structure. Needed are better surveying capabilities responsive not only to different atoms at the surface, but also their respective coordination environments. We report here that d-block organometallics, when placed at nanocrystal surfaces through heterometallic bonds, serve as molecular beacons broadcasting local surface structure in atomic detail. This unique ability stems from their elemental specificity and the sensitivity of their d-orbital level alignment to local coordination environment, which can be assessed spectroscopically. Re-surfacing cadmium and lead chalcogenide nanocrystals with iron- or ruthenium-based molecular beacons ismore » readily accomplished with trimethylsilylated cyclopentadienyl metal carbonyls. For PbSe nanocrystals with iron-based beacons, we show how core-level X-ray spectroscopies and DFT calculations enrich our understanding of both charge and atomic reorganization at the surface when beacons are bound.« less

  17. Vectorization, threading, and cache-blocking considerations for hydrocodes on emerging architectures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fung, J.; Aulwes, R. T.; Bement, M. T.; Campbell, J. M.; Ferenbaugh, C. R.; Jean, B. A.; Kelley, T. M.; Kenamond, M. A.; Lally, B. R.; Lovegrove, E. G.; et al

    2015-07-14

    This work reports on considerations for improving computational performance in preparation for current and expected changes to computer architecture. The algorithms studied will include increasingly complex prototypes for radiation hydrodynamics codes, such as gradient routines and diffusion matrix assembly (e.g., in [1-6]). The meshes considered for the algorithms are structured or unstructured meshes. The considerations applied for performance improvements are meant to be general in terms of architecture (not specifically graphical processing unit (GPUs) or multi-core machines, for example) and include techniques for vectorization, threading, tiling, and cache blocking. Out of a survey of optimization techniques on applications such asmore » diffusion and hydrodynamics, we make general recommendations with a view toward making these techniques conceptually accessible to the applications code developer. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.« less

  18. Development of HELIOS/CAPP code system for the analysis of block type VHTR cores

    SciTech Connect (OSTI)

    Lee, H. C.; Han, T. Y.; Jo, C. K.; Noh, J. M.

    2012-07-01

    In this paper, the HELIOS/CAPP code system developed for the analysis of block type VHTR cores is presented and verified against several VHTR core configurations. Verification results shows that HELIOS code predicts less negative MTC and RTC than McCARD code does and thus HELIOS code overestimates the multiplication factors at the states with high moderator and reflector temperature especially when the B{sub 4}C BP is loaded. In the depletion calculation for the VHTR single cell fuel element, the error of HELIOS code increases as burnup does. It is ascribed to the fact that HELIOS code treats some fission product nuclides with large resonances as non-resonant nuclides. In the 2-D core depletion calculation, a relatively large reactivity error is observed in the case with BP loading while the reactivity error in the case without BP loading is less than 300 pcm. (authors)

  19. Optimal integrated design of air separation unit and gas turbine block for IGCC systems

    SciTech Connect (OSTI)

    Kamath, R.; Grossman, I.; Biegler, L.; Zitney, S.

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine, US (stand-alone). However, there is very little information on systematic assessment of air extraction, nitrogen injection and configuration and operating conditions of the ASU and it is not clear which scheme is optimal for a given IGCC application. In this work, we address the above mentioned problem systematically using mixed-integer optimization. This approach allows the use of various objectives such as minimizing the investment and operating cost or SOx and NOx emissions, maximizing power output or overall efficiency or a weighted combination of these factors. A superstructure is proposed which incorporates all the integration schemes described above. Simplified models for ASU, gas turbine system and steam cycle are used which provide reasonable estimates for performance and cost (Frey and Zhu, 2006). The optimal structural configuration and operating conditions are presented for several case studies and it is observed that the optimal solution changes significantly depending on the specified objective.

  20. Optimal Integrated Design of Air Separation Unit and Gas Turbine Block for IGCC Systems

    SciTech Connect (OSTI)

    Ravindra S. Kamath; Ignacio E. Grossmann; Lorenz T. Biegler; Stephen E. Zitney

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine, US (stand-alone). However, there is very little information on systematic assessment of air extraction, nitrogen injection and configuration and operating conditions of the ASU and it is not clear which scheme is optimal for a given IGCC application. In this work, we address the above mentioned problem systematically using mixed-integer optimization. This approach allows the use of various objectives such as minimizing the investment and operating cost or SOx and NOx emissions, maximizing power output or overall efficiency or a weighted combination of these factors. A superstructure is proposed which incorporates all the integration schemes described above. Simplified models for ASU, gas turbine system and steam cycle are used which provide reasonable estimates for performance and cost (Frey and Zhu, 2006). The optimal structural configuration and operating conditions are presented for several case studies and it is observed that the optimal solution changes significantly depending on the specified objective.

  1. Davis-Bacon Act Wage Rates for ARRA-Funded Energy Efficiency and Conservation Block Grants Program Projects Involving Residential Weatherization Work

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 EFFECTIVE DATE: May 6, 2010 SUBJECT: DAVIS-BACON ACT WAGE RATES FOR ARRA-FUNDED ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM PROJECTS INVOLVING RESIDENTIAL WEATHERIZATION WORK PURPOSE: To provide guidance on using appropriate prevailing wage rates for Davis-Bacon Act (DBA) covered weatherization work performed under the Energy Efficiency and Conservation Block Grant (EECBG) Program using American Recovery and

  2. Sedimentation and reservoir distribution related to a tilted block system in the Sardinia Oligocene-Miocene rift (Italy)

    SciTech Connect (OSTI)

    Tremolieres, P.; Cherchi, A.; Eschard, R.; De Graciansky, P.C.; Montadert, L.

    1988-08-01

    In the western Mediterranean basin lies a rift system about 250 km long and 50 km wide and its infilling outcrop (central Sardinia). Seismic reflection surveys show its offshore extension. Block tilting started during the late Oligocene and lasted during Aquitanian-early Burdigalian time. Two main fault trends, with synthetic and antithetic throws, define the more-or-less collapsed blocks. This morphology guided the transit and trapping of sediments. The sedimentation started in a continental environment then, since the Chattian, in marine conditions. In the central part, the series can reach a thickness of 2,000 m. The basement composition and the volcanics products related to the main fault motion controlled the nature of the synrift deposits. According to their location in the rift context, the tilted blocks trap either continental deposits or marine siliciclastic or carbonate deposits. In the deeper part of the graben, sands were redeposited by gravity flows into the basinal marls. The younger prerift deposits are from Eocene to early Oligocene age and locally comprise thick coal layers. Postrift deposits, mainly marls, sealed the blocks and synrift sedimentary bodies. In middle and late Miocene time some faults were reactivated during compressional events. Then, a quaternary extensional phase created the Campidano graben, filled with about 1,000 m of sediments superimposed on the Oligocene-Miocene rift.

  3. Cross-Linked Nanoporous Materials from Reactive and Multifunctional Block Polymers

    SciTech Connect (OSTI)

    Seo, Myungeun; Amendt, Mark A.; Hillmyer, Marc A.

    2012-10-10

    Polylactide-b-poly(styrene-co-2-hydroxyethylmethacrylate) (PLA-b-P(S-co-HEMA)) and polylactide-b-poly(styrene-co-2-hydroxyethylacrylate) (PLA-b-P(S-co-HEA)) were synthesized by combination of ring-opening polymerization and reversible addition-fragmentation chain transfer polymerization. {sup 1}H nuclear magnetic resonance spectroscopy and size exclusion chromatography data indicated that the polymerizations were controlled and that hydroxyl groups were successfully incorporated into the block polymers. The polymers were reacted with 4,4{prime}-methylenebis(phenyl isocyanate) (MDI) to form the corresponding cross-linked materials. The materials were annealed at 150 C to complete the coupling reaction. Robust nanoporous materials were obtained from the cross-linked polymers by treatment with aqueous base to hydrolyze the PLA phase. Small-angle X-ray scattering study combined with scanning electron microscopy showed that MDI-cross-linked PLA-b-P(S-co-HEMA)/PLA-b-P(S-co-HEA) can adopt lamellar, hexagonally perforated lamellar, and hexagonally packed cylindrical morphologies after annealing. In particular, the HPL morphology was found to evolve from lamellae due to increase in volume fraction of PS phase as MDI reacted with hydroxyl groups. The reaction also kinetically trapped the morphology by cross-linking. Bicontinuous morphologies were also observed when dibutyltin dilaurate was added to accelerate reaction between the polymer and MDI.

  4. Methods for estimating wake flow and effluent dispersion near simple block-like buildings

    SciTech Connect (OSTI)

    Hosker, R.P. Jr.

    1981-05-01

    This report is intended as an interim guide for those who routinely face air quality problems associated with near-building exhaust stack placement and height, and the resulting concentration patterns. Available data and methods for estimating wake flow and effluent dispersion near isolated block-like structures are consolidated. The near-building and wake flows are described, and quantitative estimates for frontal eddy size, height and extent of roof and wake cavities, and far wake behavior are provided. Concentration calculation methods for upwind, near-building, and downwind pollutant sources are given. For an upwind source, it is possible to estimate the required stack height, and to place upper limits on the likely near-building concentration. The influences of near-building source location and characteristics relative to the building geometry and orientation are considered. Methods to estimate effective stack height, upper limits for concentration due to flush roof vents, and the effect of changes in rooftop stack height are summarized. Current wake and wake cavity models are presented. Numerous graphs of important expressions have been prepared to facilitate computations and quick estimates of flow patterns and concentration levels for specific simple buildings. Detailed recommendations for additional work are given.

  5. Methods And System Suppressing Clutter In A Gain-Block, Radar-Responsive Tag System

    DOE Patents [OSTI]

    Ormesher, Richard C. (Albuquerque, NM); Axline, Robert M. (Albuquerque, NM)

    2006-04-18

    Methods and systems reduce clutter interference in a radar-responsive tag system. A radar transmits a series of linear-frequency-modulated pulses and receives echo pulses from nearby terrain and from radar-responsive tags that may be in the imaged scene. Tags in the vicinity of the radar are activated by the radar's pulses. The tags receive and remodulate the radar pulses. Tag processing reverses the direction, in time, of the received waveform's linear frequency modulation. The tag retransmits the remodulated pulses. The radar uses a reversed-chirp de-ramp pulse to process the tag's echo. The invention applies to radar systems compatible with coherent gain-block tags. The invention provides a marked reduction in the strength of residual clutter echoes on each and every echo pulse received by the radar. SAR receiver processing effectively whitens passive-clutter signatures across the range dimension. Clutter suppression of approximately 14 dB is achievable for a typical radar system.

  6. Microstructured block copolymer surfaces for control of microbe capture and aggregation

    SciTech Connect (OSTI)

    Hansen, Ryan R; Shubert, Katherine R; Morrell, Jennifer L.; Lokitz, Bradley S; Doktycz, Mitchel John; Retterer, Scott T

    2014-01-01

    The capture and arrangement of surface-associated microbes is influenced by biochemical and physical properties of the substrate. In this report, we develop lectin-functionalized substrates containing patterned, three-dimensional polymeric structures of varied shapes and densities and use these to investigate the effects of topology and spatial confinement on lectin-mediated microbe capture. Films of poly(glycidyl methacrylate)-block-4,4-dimethyl-2-vinylazlactone (PGMA-b-PVDMA) were patterned on silicon surfaces into line or square grid patterns with 5 m wide features and varied edge spacing. The patterned films had three-dimensional geometries with 900 nm film thickness. After surface functionalization with wheat germ agglutinin, the size of Pseudomonas fluorescens aggregates captured was dependent on the pattern dimensions. Line patterns with edge spacing of 5 m or less led to the capture of individual microbes with minimal formation of aggregates, while grid patterns with the same spacing also captured individual microbes with further reduction in aggregation. Both geometries allowed for increases in aggregate size distribution with increased in edge spacing. These engineered surfaces combine spatial confinement with affinity-based microbe capture based on exopolysaccharide content to control the degree of microbe aggregation, and can also be used as a platform to investigate intercellular interactions and biofilm formation in microbial populations of controlled sizes.

  7. Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico

    SciTech Connect (OSTI)

    Dunbar, John

    2012-12-31

    Electrical methods offer a geophysical approach for determining the sub-bottom distribution of hydrate in deep marine environments. Methane hydrate is essentially non-conductive. Hence, sediments containing hydrate are more resistive than sediments without hydrates. To date, the controlled source electromagnetic (CSEM) method has been used in marine hydrates studies. This project evaluated an alternative electrical method, direct current resistivity (DCR), for detecting marine hydrates. DCR involves the injection of direct current between two source electrodes and the simultaneous measurement of the electric potential (voltage) between multiple receiver electrodes. The DCR method provides subsurface information comparable to that produced by the CSEM method, but with less sophisticated instrumentation. Because the receivers are simple electrodes, large numbers can be deployed to achieve higher spatial resolution. In this project a prototype seafloor DCR system was developed and used to conduct a reconnaissance survey at a site of known hydrate occurrence in Mississippi Canyon Block 118. The resulting images of sub-bottom resistivities indicate that high-concentration hydrates at the site occur only in the upper 50 m, where deep-seated faults intersect the seafloor. Overall, there was evidence for much less hydrate at the site than previously thought based on available seismic and CSEM data alone.

  8. Nanocluster building blocks of artificial square spin ice: Stray-field studies of thermal dynamics

    SciTech Connect (OSTI)

    Pohlit, Merlin Porrati, Fabrizio; Huth, Michael; Müller, Jens

    2015-05-07

    We present measurements of the thermal dynamics of a Co-based single building block of an artificial square spin ice fabricated by focused electron-beam-induced deposition. We employ micro-Hall magnetometry, an ultra-sensitive tool to study the stray field emanating from magnetic nanostructures, as a new technique to access the dynamical properties during the magnetization reversal of the spin-ice nanocluster. The obtained hysteresis loop exhibits distinct steps, displaying a reduction of their “coercive field” with increasing temperature. Therefore, thermally unstable states could be repetitively prepared by relatively simple temperature and field protocols allowing one to investigate the statistics of their switching behavior within experimentally accessible timescales. For a selected switching event, we find a strong reduction of the so-prepared states' “survival time” with increasing temperature and magnetic field. Besides the possibility to control the lifetime of selected switching events at will, we find evidence for a more complex behavior caused by the special spin ice arrangement of the macrospins, i.e., that the magnetic reversal statistically follows distinct “paths” most likely driven by thermal perturbation.

  9. Design study of 15-Tesla RHQT Nb3Al block type dipole magnet

    SciTech Connect (OSTI)

    Yamada, R.; Ambrosio, G.; Barzi, E.; Kashikin, V.; Kikuchi, A.; Novitski, I.; Takeuchi, T.; Wake, M.; Zlobin, A.; /Fermilab /NIMC, Tsukuba /KEK, Tsukuba

    2005-09-01

    The design study of the block type 15-Tesla RHQT Nb{sub 3}Al dipole magnet, and its merits over Nb{sub 3}Sn magnets are presented. The copper stabilized RHQT Nb{sub 3}Al strand is now becoming commercially available for the application to the accelerator magnets. A 1 mm diameter RHQT Nb{sub 3}Al strand with filament size about 50 {mu}, non-copper Jc about 1000 A/mm{sup 2} at 15 Tesla at 4.2K, copper ratio of 50%, can now be produced over several hundred meters. The stress and strain characteristics of the Nb{sub 3}Al strand are superior to the Nb{sub 3}Sn strand. Another advantage is that it can tolerate a longitudinal strain up to 0.55%. The RHQT Nb{sub 3}Al Rutherford cable will have less chance of contamination of the stabilizer, compared to Nb{sub 3}Sn cable. These characteristics of the RHQT Nb{sub 3}Al will be beneficial for designing and producing 15-Tesla dipole magnets. An example 15-Tesla magnet cross section, utilizing the RHQT Nb{sub 3}Sn strand is presented. A systematic investigation on RHQT Nb{sub 3}Al strands, its Rutherford cables, and building a small racetrack magnet for cable testing are proposed.

  10. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    SciTech Connect (OSTI)

    Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-07-15

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  11. A Block-Structured KIVA Program for Engines with Vertical or Canted Valves

    Energy Science and Technology Software Center (OSTI)

    1999-08-23

    KIVA3VRELEASE2 is a computer program for the numerical calculation of transient, two and three-dimensional, chemically reactive flows with sprays. It is a newer version of the earlier KIVA3 (1993) that has now been extended to model vertical of canted valves in the cylinder head of a gasoline or diesel engine. KIVA3, in turn, was based on the earlier KIVA2 (1989) and uses the same numerical solution procedure and solves the same sort of equations. KIVA3VRELEASE2more » uses a block-structured mesh with connectivity defined through indirect addressing. The departure from a single rectangular structure in logical space allows complex geometries to be modeled with significantly greater efficiency because large regions of deactivated cells are no longer necessary. Cell-face boundary conditions permit greater flexibility and simplification in the application of boundary conditions. KIVA3VRELEASE2 contains a number of significant changes. New features enhance the robustness, efficiency, and usefullness of the overall program for engine modeling. Automatic restart of the cycle with a reduced timestep in case of iteration limit or temperature overflow will reduce code crashes. A new option provides automatic deactivation of a port region when it is closed from the cylinder and reactivation when it communicates with the cylinder. Corrections in the code improve accuracy; extensions to the particle-based liquid wall film model makes the model more complete and a spli injection option has been added. A new subroutine monitors the liquid and gaseous fuel phases and energy balance data and emissions are monitored and printed. New features have been added to the grid generator K3PREP and the graphics post processor, K3POST.« less

  12. Provision of information from Dow regarding use of specific chemicals. Letter discusses chemicals used to remove uranium.

    Office of Legacy Management (LM)

  13. The State of Nevada's Implementation of the Energy Efficiency and Conservation Block Grant Program, OAS-RA-12-02

    Energy Savers [EERE]

    U.S. Department of Energy Office of Inspector General Office of Audits and Inspections Audit Report The State of Nevada's Implementation of the Energy Efficiency and Conservation Block Grant Program OAS-RA-12-02 November 2011 Department of Energy Washington, DC 20585 November 9, 2011 MEMORANDUM FOR THE ACTING ASSISTANT SECRETARY, ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: George W. Collard Assistant Inspector General for Audits Office of Inspector General SUBJECT: INFORMATION: Audit Report on

  14. State Energy Program and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    STATE ENERGY PROGRAM NOTICE 13-001 EECBG PROGRAM NOTICE 13-001 EFFECTIVE DATE: MARCH 21, 2013 SUBJECT: GUIDANCE FOR RETURNING INTEREST EARNED PURPOSE To provide an overview to the Department of Energy' s (DOE) State Energy Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program prime recipients (hereafter refe1Ted to as grantees) on guidance for the procedural requirements of returning interest earned on advanced Federal funds . This guidance does not create new

  15. Pore size distribution and methane equilibrium conditions at Walker Ridge Block 313, northern Gulf of Mexico

    SciTech Connect (OSTI)

    Bihani, Abhishek; Daigle, Hugh; Cook, Ann; Glosser, Deborah; Shushtarian, Arash

    2015-12-15

    Coexistence of three methane phases (liquid (L), gas (G), hydrate (H)) in marine gas hydrate systems may occur according to in-situ pressure, temperature, salinity and pore size. In sediments with salinity close to seawater, a discrete zone of three-phase (3P) equilibrium may occur near the base of the regional hydrate stability zone (RHSZ) due to capillary effects. The existence of a 3P zone influences the location of the bottom-simulating reflection (BSR) and has implications for methane fluxes at the base of the RHSZ. We studied hydrate stability conditions in two wells, WR313-G and WR313-H, at Walker Ridge Block 313 in the northern Gulf of Mexico. We determined pore size distributions (PSD) by constructing a synthetic nuclear magnetic resonance (NMR) relaxation time distribution. Correlations were obtained by non-linear regression on NMR, gamma ray, and bulk density logs from well KC-151 at Keathley Canyon. The correlations enabled construction of relaxation time distributions for WR313-G and WR313-H, which were used to predict PSD through comparison with mercury injection capillary pressure measurements. With the computed PSD, L+H and L+G methane solubility was determined from in-situ pressure and temperature. The intersection of the L+G and L+H curves for various pore sizes allowed calculation of the depth range of the 3P equilibrium zone. As in previous studies at Blake Ridge and Hydrate Ridge, the top of the 3P zone moves upwards with increasing water depth and overlies the bulk 3P equilibrium depth. In clays at Walker Ridge, the predicted thickness of the 3P zone is approximately 35 m, but in coarse sands it is only a few meters due to the difference in absolute pore sizes and the width of the PSD. The thick 3P zone in the clays may explain in part why the BSR is only observed in the sand layers at Walker Ridge, although other factors may influence the presence or absence of a BSR.

  16. Final Technical Report - Commercially Important Carbohydrate Diacids - Building Blocks from Renewable Carbohydrates

    SciTech Connect (OSTI)

    Kiely, Donald E.

    2009-01-07

    The primary objective of this project was to develop oxidation methods appropriate for the conversion of agriculturally derived simple sugars to their corresponding diacids (aldaric acids) for use as biobased chemical building blocks for new biodegradable polymers and other materials. Principal target diacids were D-glucaric, meso-xylaric, D-mannaric and L-arabinaric acid, each to be prepared by nitric acid oxidation of the naturally occurring precursor carbohydrates (monosaccharides) D-glucose, D-xylose, D-mannose and L-arabinose, respectively, all from hydrolysis of naturally abundant plant polysaccharides. These conversions were to be designed for scale up to a level suitable for transfer first to a pilot plant scale, and then to an industrial plant scale. The core of the project involved a comprehensive study of the title oxidation employing a computer controlled reactor. The plan of action involved defining experimental parameters to allow for control of the oxidations with considerable precision and reproducibility. The prototype oxidations were typically run using ca. 0.75 molar amounts of carbohydrate, with a goal of eventually doubling the reaction size when appropriate reaction parameters were established. During the course of the funding period for this grant, the fundamentals of reaction control were established for oxidation of D-glucose, a critical component of the project given the exothermic character of the reaction. The reactions were monitored using a reliable GC/MS protocol. The glucose to glucaric acid conversion represented the most important and potentially highest value conversion. During the grant period we were able to establish one workable system to carry out the glucose to glucaric acid conversion, but were not able to optimize the process or establish a protocol that was satisfactory for a scale up to a pilot plant scale. However, the work carried out showed the possibility that with appropriate innovation and continued effort, a prototype for a successful pilot plant scale operation might be possible. It was not possible to explore oxidations with the other simple sugars indicated during the time frame of this project. A graduate student, J. Brand, and an undergraduate student, B. O??Connor received partial support for research done on the project. A manuscript for publication entitled ANitric Acid Oxidation of D-Glucose to D-Glucaric Acid: Improved Process and Analytical Assessment@, is in preparation for submission to Industrial & Engineering Chemistry Research or Carbohydrate Research.

  17. Mixed-Salt Effects on the Ionic Conductivity of Lithium-Doped PEO-Containing Block Copolymers

    SciTech Connect (OSTI)

    Young, Wen-Shiue; Albert, Julie N.L.; Schantz, A. Benjamin; Epps, III, Thomas H.

    2012-10-10

    We demonstrate a simple, yet effective, mixed-salt method to increase the room temperature ionic conductivity of lithium-doped block copolymer electrolyte membranes by suppressing the crystalline phases in the conducting block. We examined a mixed-salt system of LiClO{sub 4} and LiN(SO{sub 2}CF{sub 3}){sub 2} (LiTFSI) doped into a lamellae-forming poly(styrene-b-ethylene oxide) (PS-PEO) diblock copolymer. The domain spacings, morphologies, thermal behavior, and crystalline phases of salt-doped PS-PEO samples were characterized, and the ionic conductivities of block copolymer electrolytes were obtained through ac impedance measurements. Comparing the ionic conductivity profiles of salt-doped PS-PEO samples at different mixed-salt ratios and total salt concentrations, we found that the ionic conductivity at room temperature can be improved by more than an order of magnitude when coinhibition of crystallite growth is promoted by the concerted behavior of the PEO:LiClO{sub 4} and PEO:LiTFSI phases. Additionally, we examined the influence of mixed-salt ratio and total salt concentration on copolymer energetics, and we found that the slope of the effective interaction parameter ({chi}{sub eff}) vs salt concentration in our lamellae-forming PS-PEO system was lower than that reported for a cylinder-forming PS-PEO system due to the balance between chain stretching and salt segregation in the PEO domains.

  18. Compressible Solution Properties of Amorphous Polystyrene-block-Polybutadiene, Crystalline Polystyrene-block-Poly(Hydrogenated Polybutadiene) and Their Corresponding Homopolymers: Fluid-Fluid, Fluid-Solid and Fluid-Micelle Phase Transitions in Propane and Propylene

    SciTech Connect (OSTI)

    Hong, Kunlun; Mays, Jimmy; Winoto, Winoto; Radosz, Maciej

    2009-01-01

    Abstract Polystyrene, polybutadiene, hydrogenated polybutadiene, and styrene diblock copolymers of these homopolymers can form homogenous solutions in compressible solvents, such as propane and propylene, which separate into two bulk phases upon reducing pressure. The cloud and micellization pressures for homopolymer and diblock copolymers are generally found to be higher in propane than in propylene, except for hydrogenated polybutadiene and polystyrene-block-(hydrogenated polybutadiene). Hydrogenated polybutadiene homopolymers and copolymers exhibit relatively pressure-independent crystallization and melting observed in both propane and propylene solutions.

  19. Sorption (Kd) measurements on cinder block and grout in support of dose assessments for Zion Nuclear Station decommissioning

    SciTech Connect (OSTI)

    Milian L.; Sullivan T.

    2014-06-24

    The Zion Nuclear Power Station is being decommissioned. ZionSolutions proposes to leave much of the below grade structures in place and to fill them with a backfill to provide structural support. Backfills under consideration include clean concrete demolition debris from the above grade parts of the facility, a flowable grout, cinder block construction debris and sand. A previous study (Yim, 2012) examined the sorption behavior of five nuclides (Fe-55, Co-60, Ni-63, Sr-85, and Cs-137) on concrete and local soils. This study, commissioned by ZionSolutions and conducted by the Brookhaven National Laboratory (BNL) examines the sorption behavior on cinder block and grout materials. Specifically, this study measured the distribution coefficient for four radionuclides of concern using site-groundwater and cinder block from the Zion site and a flowable grout. The distributions coefficient is a measure of the amount of the radionuclide that will remain sorbed to the solid material that is present relative to the amount that will remain in solution. A high distribution coefficient indicates most of the radionuclide will remain on the solid material and will not be available for transport by the groundwater. The radionuclides examined in this set of tests were Co-60, Ni-63, Sr-85, and Cs-137. Tests were performed following ASTM C1733-10, Standard Test Methods for Distribution Coefficients of Inorganic Species by the Batch Method. Sr-85 was used in the testing as an analogue for Sr-90 because it behaves similarly with respect to sorption and has a gamma emission that is easier to detect than the beta emission from Sr-90.

  20. Guidance on the Required Period for Grantees to Obligate Funds and the Procedures for Reporting of Obligated Funds for the Energy Efficiency Conservation Block Grant (EECBG) Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Washington, DC 20585 EECBG PROGRAM NOTICE 11-003 EFFECTIVE DATE: NOVEMBER 1, 2011 SUBJECT: GUIDANCE ON THE REQUIRED PERIOD FOR GRANTEES TO OBLIGATE FUNDS AND THE PROCEDURES FOR REPORTING OF OBLIGATED FUNDS FOR THE ENERGY EFFICIENCY CONSERVATION BLOCK GRANT PROGRAM (EECBG) PURPOSE To provide guidance and clarify the required period for obligation of funds as established in the Energy Efciency Conservation Block Grant (EECBG) Program Funding Opportunit Announcements (FOAs) Number DE-FOA-0000013

  1. Lectin-functionalized poly(glycidyl methacrylate)-block-poly(vinyldimethyl azlactone) surface supports for high avidity microbial capture

    SciTech Connect (OSTI)

    Hansen, Ryan R; Hinestrosa Salazar, Juan P; Shubert, Katherine R; Morrell, Jennifer L.; Pelletier, Dale A; Messman, Jamie M; Kilbey, II, S Michael; Lokitz, Bradley S; Retterer, Scott T

    2013-01-01

    Microbial exopolysaccharides (EPS) play a critical and dynamic role in shaping the interactions between microbial community members and their local environment. The capture of targeted microbes using surface immobilized lectins that recognize specific extracellular oligosaccharide moieties offers a non-destructive method for functional characterization based on EPS content. In this report, we evaluate the use of the block co-polymer, poly(glycidyl methacrylate)-block-4,4-dimethyl-2-vinylazlactone (PGMA-b-PVDMA), as a surface support for lectin-specific microbial capture. Arrays of circular polymer supports ten micron in diameter were generated on silicon substrates to provide discrete, covalent coupling sites for Triticum vulgare and Lens culinaris lectins. These supports promoted microbe adhesion and colony formation in a lectin-specific manner. Silicon posts with similar topography containing only physisorbed lectins showed significantly less activity. These results demonstrate that micropatterned PGMA-b-PVDMA supports provide a unique platform for microbial capture and screening based on EPS content by combining high avidity lectin surfaces with three-dimensional topography.

  2. Evaluation of the reliability of a conventional platform installed in South Pass Block 47 of the Mississippi River delta

    SciTech Connect (OSTI)

    Bea, R.G.

    1996-12-31

    In August 1995, the Energy Development Corporation (EDC) installed a conventional drilling and production platform in South Pass Block 47 (SP 47). Due to its proximity to the delta of the Mississippi River, this platform will be subject to the environmental forces developed by hurricanes and movements of the sea floor. This paper summarizes results from probability based study of the reliability characteristics of a conventional platform installed in SP 47. Bases for evaluation of the acceptability of the reliability of the platform are developed. This paper shows how reliability methods can be used to help improve the efficiency of offshore platforms. Application of traditional engineering approaches indicated the need for a mudslide resistant platform. Given that a mudslide resistant platform was required, then the gas reserves could not have been developed.

  3. Mesoporous Silica Films with Long-Range Order Prepared from Strongly Segregated Block Copolymer/Homopolymer Blend Templates

    SciTech Connect (OSTI)

    Tirumala, Vijay R.; Pai, Rajaram A.; Agarwal, Sumit; Testa, Jason J.; Bhatnagar, Gaurav; Romang, Alvin H.; Chandler, Curran; Gorman, Brian P.; Jones, Ronald L.; Lin, Eric K.; Watkins, James J.

    2008-06-30

    Well-ordered mesoporous silica films were prepared by infusion and selective condensation of Si alkoxides within preorganized block copolymer/homopolymer blend templates using supercritical CO{sub 2} as the delivery medium. The morphologies of the mesoporous silica films reflect significant improvements in the strength of segregation and long-range order of template blends of poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) triblock copolymers with selectively associating homopolymers such as poly(acrylic acid) or poly(4-hydroxystyrene) prior as compared to templates comprised of the neat copolymer. Control over film porosity, pore ordering, and morphology of the films is achieved through simple variations in the homopolymer concentration. The films were characterized using X-ray reflectivity, small-angle X-ray scattering, and transmission electron microscopy.

  4. DETECTIONS OF FAINT Ly{alpha} EMITTERS AT z = 5.7: GALAXY BUILDING BLOCKS AND ENGINES OF REIONIZATION

    SciTech Connect (OSTI)

    Dressler, Alan; McCarthy, Patrick; Martin, Crystal L.; Henry, Alaina; Sawicki, Marcin E-mail: sawicki@ap.smu.ca

    2011-10-20

    We report results of an unprecedentedly deep, blind search for Ly{alpha} emitters (LAEs) at z = 5.7 using the Inamori-Magellan Areal Camera and Spectrograph (IMACS), with the goal of identifying missing sources of reionization that could also be basic building blocks for today's L* galaxies. We describe how improvements in wide field imaging with the Baade telescope, upgrades to IMACS, and the accumulation of {approx}20 hr of integration per field in excellent seeing led to the detection of single-emission-line sources as faint as F {approx} 2 x 10{sup -18} erg s{sup -1} cm{sup -2}, a sensitivity five times deeper than our first search. A reasonable correction for foreground interlopers implies a steep rise of approximately an order of magnitude in source density for a factor of four drop in flux, from F = 10{sup -17.0} erg s{sup -1} cm{sup -2} to F = 10{sup -17.6} (2.5 x 10{sup -18}) erg s{sup -1} cm{sup -2}. At this flux the putative LAEs have reached a surface density of {approx}1 arcmin{sup -2}-a comoving volume density of 4 x 10{sup -3} Mpc{sup -3}, several times the density of L* galaxies today. Such a population of faint LAEs would account for a significant fraction of the critical flux density required to complete reionization at this epoch, and would be good candidates for building blocks of stellar mass {approx}10{sup 8}-10{sup 9} M{sub sun} for the young galaxies of this epoch.

  5. High Temperature Reactor (HTR) Deep Burn Core and Fuel Analysis: Design Selection for the Prismatic Block Reactor

    SciTech Connect (OSTI)

    Francesco Venneri; Chang-Keun Jo; Jae-Man Noh; Yonghee Kim; Claudio Filippone; Jonghwa Chang; Chris Hamilton; Young-Min Kim; Ji-Su Jun; Moon-Sung Cho; Hong-Sik Lim; MIchael A. Pope; Abderrafi M. Ougouag; Vincent Descotes; Brian Boer

    2010-09-01

    The Deep Burn (DB) Project is a U.S. Department of Energy sponsored feasibility study of Transuranic Management using high burnup fuel in the high temperature helium cooled reactor (HTR). The DB Project consists of seven tasks: project management, core and fuel analysis, spent fuel management, fuel cycle integration, TRU fuel modeling, TRU fuel qualification, and HTR fuel recycle. In the Phase II of the Project, we conducted nuclear analysis of TRU destruction/utilization in the HTR prismatic block design (Task 2.1), deep burn fuel/TRISO microanalysis (Task 2.3), and synergy with fast reactors (Task 4.2). The Task 2.1 covers the core physics design, thermo-hydraulic CFD analysis, and the thermofluid and safety analysis (low pressure conduction cooling, LPCC) of the HTR prismatic block design. The Task 2.3 covers the analysis of the structural behavior of TRISO fuel containing TRU at very high burnup level, i.e. exceeding 50% of FIMA. The Task 4.2 includes the self-cleaning HTR based on recycle of HTR-generated TRU in the same HTR. Chapter IV contains the design and analysis results of the 600MWth DB-HTR core physics with the cycle length, the average discharged burnup, heavy metal and plutonium consumptions, radial and axial power distributions, temperature reactivity coefficients. Also, it contains the analysis results of the 450MWth DB-HTR core physics and the analysis of the decay heat of a TRU loaded DB-HTR core. The evaluation of the hot spot fuel temperature of the fuel block in the DB-HTR (Deep-Burn High Temperature Reactor) core under full operating power conditions are described in Chapter V. The investigated designs are the 600MWth and 460MWth DB-HTRs. In Chapter VI, the thermo-fluid and safety of the 600MWth DB-HTRs has been analyzed to investigate a thermal-fluid design performance at the steady state and a passive safety performance during an LPCC event. Chapter VII describes the analysis results of the TRISO fuel microanalysis of the 600MWth and 450MWth DB-HTRs. The TRISO fuel microanalysis covers the gas pressure buildup in a coated fuel particle including helium production, the thermo-mechanical behavior of a CFP, the failure probabilities of CFPs, the temperature distribution in a CPF, and the fission product (FP) transport in a CFP and a graphite. In Chapter VIII, it contains the core design and analysis of sodium cooled fast reactor (SFR) with deep burn HTR reactor. It considers a synergistic combination of the DB-MHR and an SFR burner for a safe and efficient transmutation of the TRUs from LWRs. Chapter IX describes the design and analysis results of the self-cleaning (or self-recycling) HTR core. The analysis is considered zero and 5-year cooling time of the spent LWR fuels.

  6. Thickness dependent hierarchical meso/nano scale morphologies of a metal-containing block copolymer thin film induced by hybrid annealing and their pattern transfer abilities.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B.; Center for Nanoscale Materials

    2009-01-01

    In this paper we describe dewetting phenomena in organic (polystyrene, PS)/inorganic (polyferrocenyldimethylsilane, PFS) block copolymer thin films. Mesoscale dendritic structures are induced when the spin-cast thin film of this polymer is subjected to so-called hybrid annealing, which involves both thermal and solvent annealing. We show that the development and arrangement of these mesoscale dendritic structures depends on the initial film thickness in addition to the annealing time. Importantly, there are two criteria that must be fulfilled to achieve these mesoscale morphologies: (i) the film has to be subjected to hybrid annealing, i.e. either only thermal or only solvent annealing does not produce any notable mesostructures and (ii) both PS and PFS blocks must be present during the thermal and solvent annealing procedures; if one of the blocks, for instance PS, is removed before annealing then there is no mesostructure. Various possible mechanisms for the formation of these structures are discussed and results indicate that the PFS block dominates the structure formation. We also observe a ring- or worm-like nanostructure which develops only when the film is subjected to hybrid annealing at a particular film thickness. Apart from these results, here we demonstrate that mesoscale structures can be successfully transferred onto underlying substrates.

  7. State Energy Program Notice (10-004A), Energy Efficiency Conservation Block Grant Program Notice (10-005A), and Appliance Rebate Program Notice (10-001A)

    Broader source: Energy.gov [DOE]

    Guidance on Davis Bacon Act (DBA) requirements for American Reinvestment and Recovery Act of 2009 (ARRA)-funded rebate, grant and financing programs for individual homeowners conducted under the State Energy Program (SEP), Energy Efficiency and Conservation Block Grant (EECBG) program, and the appliance rebate program. Revised April 7, 2010.

  8. Implementation of Generalized Coarse-Mesh Rebalance of NEWTRNX for Acceleration of Parallel Block-Jacobi Transport

    SciTech Connect (OSTI)

    Clarno, Kevin T

    2007-01-01

    The NEWTRNX transport module solves the multigroup, discrete-ordinates source-driven or k-eigenvalue transport equation in parallel on a 3-D unstructured tetrahedral mesh using the extended step characteristics (ESC), also known as the slice-balance approach (SBA), spatial discretization. The spatial domains are decomposed using METIS. NEWTRNX is under development for nuclear reactor analysis on computer hardware ranging from clusters to massively parallel machines, like the Cray XT4. Transport methods that rely on full sweeps across the spatial domain have been shown to display poor scaling for thousands of processors. The Parallel Block-Jacobi (PBJ) algorithm allows each spatial partition to sweep over all discrete-ordinate directions and energies independently of all other domains, potentially allowing for much better scaling than possible with full sweeps. The PBJ algorithm has been implemented in NEWTRNX using a Gauss-Seidel iteration in energy and an asynchronous communication by an energy group, such that each partition utilizes the latest boundary solution available for each group before solving the withingroup scattering in a given group. For each energy group, the within-group scattering converges with a generalized minimum residual (GMRES) solver, preconditioned with beta transport synthetic acceleration ({beta}-TSA).

  9. Deprotonated Water Dimers: The Building Blocks of Segmented Water Chains on Rutile RuO2(110)

    SciTech Connect (OSTI)

    Mu, Rentao; Cantu Cantu, David; Glezakou, Vassiliki Alexandra; Lyubinetsky, Igor; Rousseau, Roger J.; Dohnalek, Zdenek

    2015-10-15

    Despite the importance of RuO2 in photocatalytic water splitting and catalysis in general, the interactions of water with even its most stable (110) surface are not well-understood. In this study we employ a combination of high-resolution scanning tunneling microscopy imaging with density functional theory based ab initio molecular dynamics, and we follow the formation and binding of linear water clusters on coordinatively unsaturated ruthenium rows. We find that clusters of all sizes (dimers, trimers, tetramers, extended chains) are stabilized by donating one proton per every two water molecules to the surface bridge bonded oxygen sites, in contrast with water monomers that do not show a significant propensity for dissociation. The clusters with odd number of water molecules are less stable than the clusters with even number, and are generally not observed under thermal equilibrium. For all clusters with even numbers, the dissociated dimers represent the fundamental building blocks with strong intra-dimer hydrogen bonds and only very weak inter-dimer interactions resulting in segmented water chains.

  10. The benzene metabolite trans,trans-muconaldehyde blocks gap junction intercellular communication by cross-linking connexin43

    SciTech Connect (OSTI)

    Rivedal, Edgar Leithe, Edward

    2008-11-01

    Benzene is used at large volumes in many different human activities. Hematotoxicity and cancer-causation as a result of benzene exposure was recognized many years ago, but the mechanisms involved remain unclear. Aberrant regulation of gap junction intercellular communication (GJIC) has been linked to both cancer induction and interference with normal hematopoietic development. We have previously suggested that inhibition of GJIC may play a role in benzene toxicity since benzene metabolites were found to block GJIC, the ring-opened trans,trans-muconaldehyde (MUC) being the most potent metabolite. In the present work we have studied the molecular mechanisms underlying the MUC-induced inhibition of gap junctional communication. We show that MUC induces cross-linking of the gap junction protein connexin43 and that this is likely to be responsible for the induced inhibition of GJIC, as well as the loss of connexin43 observed in Western blots. We also show that glutaraldehyde possesses similar effects as MUC, and we compare the effects to that of formaldehyde. The fact that glutaraldehyde and formaldehyde have been associated with induction of leukemia as well as disturbance of hematopoiesis, strengthens the possible link between the effect of MUC on gap junctions, and the toxic effects of benzene.

  11. Richland Analytical Building Blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 $ in Thousands Draft Pre-Decisional PBS ABB Title FY 2015 FY 2015 FY 2015 Description (Range $000) Cumulative Range RL-0030 Groundwater Monitoring (GWM), integration & Assessment, and Operations & Maintenance 100,000 - 120,000 100,000 - 120,000 Accomplishes continued integration of Site-wide groundwater and vadose zone cleanup activities, groundwater contamination monitoring, as well as operations, maintenance, and necessary modifications of existing remediation systems. RL-0041 River

  12. Block coordination copolymers

    DOE Patents [OSTI]

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2012-11-13

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  13. Block coordination copolymers

    DOE Patents [OSTI]

    Koh, Kyoung Moo; Wong-Foy, Antek G; Matzger, Adam J; Benin, Annabelle I; Willis, Richard R

    2014-11-11

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  14. Block coordination copolymers

    DOE Patents [OSTI]

    Koh, Kyoung Moo; Wong-Foy, Antek G.; Matzger, Adam J.; Benin, Annabelle I.; Willis, Richard R.

    2012-12-04

    The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

  15. Power Electronics Block Set

    Energy Science and Technology Software Center (OSTI)

    2008-12-31

    The software consists of code that will allow rapid prototyping of advanced power electronics for use in renewable energy systems.

  16. Anasazi Block Eigensolvers Package

    Energy Science and Technology Software Center (OSTI)

    2004-03-01

    ANASAZI is an extensible and interoperable framework for large-scale eigenvalue algorithms. The motivation for this framework is to provide a generic interface to a collection of algorithms for solving large-scale eigenvalue problems. ANASAZI is interoperable because both the matrix and vectors (defining the eigenspace) are considered to be opaque objects---only knowledge of the matrix and vectors via elementary operations is necessary. An implementation of Anasazi is accomplished via the use of interfaces. One of themore » goals of ANASAZI is to allow the user the flexibility to specify the data representation for the matrix and vectors and so leverage any existing software investment. The algorithms that will be included in package are Krylov-based and preconditioned eigensolvers.« less

  17. Richland Analytical Building Blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Min Safe and Essential Services River Corridor Cleanup support services including: waste operations; surveillance and maintenance; utilities; and general support services. These...

  18. Richland Analytical Building Blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Supports deactivation and decommissioning activities for the major PFP facilities to achieve ready-for-demolition status in support of the 2015 Vision and future TPA milestones. ...

  19. Endpoint-based parallel data processing with non-blocking collective instructions in a parallel active messaging interface of a parallel computer

    DOE Patents [OSTI]

    Archer, Charles J; Blocksome, Michael A; Cernohous, Bob R; Ratterman, Joseph D; Smith, Brian E

    2014-11-11

    Endpoint-based parallel data processing with non-blocking collective instructions in a PAMI of a parallel computer is disclosed. The PAMI is composed of data communications endpoints, each including a specification of data communications parameters for a thread of execution on a compute node, including specifications of a client, a context, and a task. The compute nodes are coupled for data communications through the PAMI. The parallel application establishes a data communications geometry specifying a set of endpoints that are used in collective operations of the PAMI by associating with the geometry a list of collective algorithms valid for use with the endpoints of the geometry; registering in each endpoint in the geometry a dispatch callback function for a collective operation; and executing without blocking, through a single one of the endpoints in the geometry, an instruction for the collective operation.

  20. Endpoint-based parallel data processing with non-blocking collective instructions in a parallel active messaging interface of a parallel computer

    DOE Patents [OSTI]

    Archer, Charles J; Blocksome, Michael A; Cernohous, Bob R; Ratterman, Joseph D; Smith, Brian E

    2014-11-18

    Methods, apparatuses, and computer program products for endpoint-based parallel data processing with non-blocking collective instructions in a parallel active messaging interface (`PAMI`) of a parallel computer are provided. Embodiments include establishing by a parallel application a data communications geometry, the geometry specifying a set of endpoints that are used in collective operations of the PAMI, including associating with the geometry a list of collective algorithms valid for use with the endpoints of the geometry. Embodiments also include registering in each endpoint in the geometry a dispatch callback function for a collective operation and executing without blocking, through a single one of the endpoints in the geometry, an instruction for the collective operation.

  1. California Energy Commission ¬ネメ Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    California Energy Commission - Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009 OAS-RA-13-01 October 2012 Department of Energy Washington, DC 20585 October 9, 2012 MEMORANDUM FOR THE ASSISTANT SECRETARY, ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Rickey R. Hass Deputy Inspector General for Audit Services Office of Inspector General SUBJECT: INFORMATION: Examination Report on "California Energy Commission - Energy

  2. The Department's Implementation of Financial Incentive Programs under the Energy Efficiency and Conservation Block Grant Program, OAS-RA-L-13-02

    Energy Savers [EERE]

    Implementation of Financial Incentive Programs under the Energy Efficiency and Conservation Block Grant Program OAS-RA-L-13-02 December 2012 Department of Energy Washington, DC 20585 December 3, 2012 MEMORANDUM FOR THE PROGRAM MANAGER, WEATHERIZATION AND INTERGOVERNMENTAL PROGRAM FROM: George W. Collard Assistant Inspector General for Audits Office of Inspector General SUBJECT: INFORMATION: Audit Report on "The Department's Implementation of Financial Incentive Programs under the Energy

  3. STATE ENERGY PROGRAM NOTICE (10-004A), ENERGY EFFICIENCY CONSERVATION BLOCK GRANT PROGRAM NOTICE (10-005A), AND APPLIANCE REBATE PROGRAM NOTICE (10-001A)

    Energy Savers [EERE]

    REVISION: THIS GUIDANCE HAS BEEN AMENDED FROM THE JANUARY 11, 2010. THE CHANGE IN THIS AMENDED GUIDANCE IS RELATED TO SEP AND EECBG FINANCING PROGRAMS FOR INDIVIDUAL HOMEOWNERS. STATE ENERGY PROGRAM NOTICE (10-004A), ENERGY EFFICIENCY CONSERVATION BLOCK GRANT PROGRAM NOTICE (10-005A), AND APPLIANCE REBATE PROGRAM NOTICE (10-001A) EFFECTIVE DATE: April 7, 2010 SUBJECT: GUIDANCE ON DAVIS BACON ACT (DBA) REQUIREMENTS FOR AMERICAN REINVESTMENT AND RECOVERY ACT OF 2009 (ARRA)- FUNDED REBATE, GRANT

  4. County of Los Angeles Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009, OAS-RA-13-02

    Office of Environmental Management (EM)

    County of Los Angeles - Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009 OAS-RA-13-02 October 2012 Department of Energy Washington, DC 20585 October 9, 2012 MEMORANDUM FOR THE ASSISTANT SECRETARY, ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Rickey R. Hass Deputy Inspector General for Audit Services Office of Inspector General SUBJECT: INFORMATION: Examination Report on "County of Los Angeles - Energy Efficiency and

  5. Testing of TAMU3: a Nb3Sn BlockCoil Dipole with Stress Management

    SciTech Connect (OSTI)

    McIntyre, Peter

    2015-09-20

    The Accelerator Research Lab (ARL) at Texas A&M has recently concluded the construction and testing of a superconducting block-coil dipole TAMU3. TAMU3 reached 85% of the resistive-onset short sample critical current (0.1 ?V/cm criterion) that was measured on extracted strands at the National High Magnetic Field Lab. Peak magnet current was 6603 amps, and all with quenches originated in the vicinity of the hard-way chicane near the exit lead of the TAMU3c inner winding. Leading up to the testing we discovered that we had made two grievous mistakes in the fabrication (we mistakenly used the wrong superconducting wire for the cables of the inner windings) and the heat treatment (we used a heat treatment that was too hot and too long). We extracted strands from the leads of the inner and outer windings, and colleagues at NHMFL performed short-sample measurements upon them. The NHMFL measurements indicated RRR ~ 2-5, which gives very little stability against microquenches. The short-sample tests of the extracted strands exhibited a long resistive transition, in which there was a current Isc(B) beyond which it became resistive, then a higher current In(B) at which it went fully normal. Using the Isc(B) data we predicted a short-sample limit for the revised load line of TAMU3 of 7700 A (9 T) a disappointing reduction from the 14 T objective. On those unhappy notes we undertook the testing of the dipole. The first quench occurred at 5695 A, and the dipole trained thereafter to a maximum quench current of 6600 A (7.6 T), 85% of the compromised short-sample limit. All quenches occurred at a single location, in the region of the S-bend transition and outer lead of one inner winding. Data was collected from stress transducers on the outer windings to evaluate stress management, and on the coil ends to evaluate capture of axial forces by staticfriction lock. The low field reached prevented us from extending those tests to the stress levels where they would have become most interesting, but the designed stress management appeared to be working at the level tested.

  6. DEVELOPMENT AND DEMONSTRATION OF A PILOT SCALE FACILITY FOR FABRICATION AND MARKETING OF LIGHTWEIGHT-COAL COMBUSTION BYPRODUCTS-BASED SUPPORTS AND MINE VENTILATION BLOCKS FOR UNDERGROUND MINES

    SciTech Connect (OSTI)

    Yoginder P. Chugh

    2002-10-01

    The overall goal of this program was to develop a pilot scale facility, and design, fabricate, and market CCBs-based lightweight blocks for mine ventilation control devices, and engineered crib elements and posts for use as artificial supports in underground mines to replace similar wooden elements. This specific project was undertaken to (1) design a pilot scale facility to develop and demonstrate commercial production techniques, and (2) provide technical and marketing support to Fly Lite, Inc to operate the pilot scale facility. Fly Lite, Inc is a joint venture company of the three industrial cooperators who were involved in research into the development of CCBs-based structural materials. The Fly-Lite pilot scale facility is located in McLeansboro, Illinois. Lightweight blocks for use in ventilation stoppings in underground mines have been successfully produced and marketed by the pilot-scale facility. To date, over 16,000 lightweight blocks (30-40 pcf) have been sold to the mining industry. Additionally, a smaller width (6-inch) full-density block was developed in August-September 2002 at the request of a mining company. An application has been submitted to Mine Safety and Health Administration for the developed block approval for use in mines. Commercialization of cribs and posts has also been accomplished. Two generations of cribs have been developed and demonstrated in the field. MSHA designated them suitable for use in mines. To date, over 2,000 crib elements have been sold to mines in Illinois. Two generations of posts were also demonstrated in the field and designated as suitable for use in mines by MSHA. Negotiations are currently underway with a mine in Illinois to market about 1,000 posts per year based on a field demonstration in their mine. It is estimated that 4-5 million tons CCBs (F-fly ash or FBC fly ash) may be utilized if the developed products can be commercially implemented in U.S. coal and non-coal mines.

  7. Michigan's 4th congressional district: Energy Resources | Open...

    Open Energy Info (EERE)

    Energy Companies in Michigan's 4th congressional district Cone Drive Operations Inc Dow Chemical Co Dow Kokam Heritage Sustainable Energy LLC LXE Energy Generation Facilities in...

  8. Midland, Michigan: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    1st congressional district and Michigan's 4th congressional district.12 Registered Energy Companies in Midland, Michigan Dow Chemical Co Dow Kokam References US Census...

  9. Michigan's 1st congressional district: Energy Resources | Open...

    Open Energy Info (EERE)

    Registered Energy Companies in Michigan's 1st congressional district AG Solutions Inc Dow Chemical Co Dow Kokam Energy Generation Facilities in Michigan's 1st congressional...

  10. An Industrial Wish List for Membrane-Based Separations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Solvent Resistance Industrial Bioprocessing Industrial Industrial Sweeteners Food & Beverage Mining Dow is the top ethylene producer in the world * 14 Dow ...

  11. Comparison of the PHISICS/RELAP5-3D Ring and Block Model Results for Phase I of the OECD MHTGR-350 Benchmark

    SciTech Connect (OSTI)

    Gerhard Strydom

    2014-04-01

    The INL PHISICS code system consists of three modules providing improved core simulation capability: INSTANT (performing 3D nodal transport core calculations), MRTAU (depletion and decay heat generation) and a perturbation/mixer module. Coupling of the PHISICS code suite to the thermal hydraulics system code RELAP5-3D has recently been finalized, and as part of the code verification and validation program the exercises defined for Phase I of the OECD/NEA MHTGR 350 MW Benchmark were completed. This paper provides an overview of the MHTGR Benchmark, and presents selected results of the three steady state exercises 1-3 defined for Phase I. For Exercise 1, a stand-alone steady-state neutronics solution for an End of Equilibrium Cycle Modular High Temperature Reactor (MHTGR) was calculated with INSTANT, using the provided geometry, material descriptions, and detailed cross-section libraries. Exercise 2 required the modeling of a stand-alone thermal fluids solution. The RELAP5-3D results of four sub-cases are discussed, consisting of various combinations of coolant bypass flows and material thermophysical properties. Exercise 3 combined the first two exercises in a coupled neutronics and thermal fluids solution, and the coupled code suite PHISICS/RELAP5-3D was used to calculate the results of two sub-cases. The main focus of the paper is a comparison of the traditional RELAP5-3D ring model approach vs. a much more detailed model that include kinetics feedback on individual block level and thermal feedbacks on a triangular sub-mesh. The higher fidelity of the block model is illustrated with comparison results on the temperature, power density and flux distributions, and the typical under-predictions produced by the ring model approach are highlighted.

  12. High-Pressure Micellar Solutions of Symmetric and Asymmetric Styrene?Diene Diblocks in Compressible Near Critical Solvents: Micellization Pressures and Cloud Pressures Respond but Micellar Cloud Pressures Insensitive to Copolymer Molecular Weight, Concentration, and Block Ratio Changes

    SciTech Connect (OSTI)

    Winoto, Winoto; Tan, Sugata; Shen, Youqin; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical nonmicellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Concentration-dependent pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size, and ratio. The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

  13. High Temperature Reactor (HTR) Deep Burn Core and Fuel Analysis: Design Selection for the Prismatic Block Reactor With Results from FY-2011 Activities

    SciTech Connect (OSTI)

    Michael A. Pope

    2011-10-01

    The Deep Burn (DB) Project is a U.S. Department of Energy sponsored feasibility study of Transuranic Management using high burnup fuel in the high temperature helium cooled reactor (HTR). The DB Project consists of seven tasks: project management, core and fuel analysis, spent fuel management, fuel cycle integration, TRU fuel modeling, TRU fuel qualification, and HTR fuel recycle. In the Phase II of the Project, we conducted nuclear analysis of TRU destruction/utilization in the HTR prismatic block design (Task 2.1), deep burn fuel/TRISO microanalysis (Task 2.3), and synergy with fast reactors (Task 4.2). The Task 2.1 covers the core physics design, thermo-hydraulic CFD analysis, and the thermofluid and safety analysis (low pressure conduction cooling, LPCC) of the HTR prismatic block design. The Task 2.3 covers the analysis of the structural behavior of TRISO fuel containing TRU at very high burnup level, i.e. exceeding 50% of FIMA. The Task 4.2 includes the self-cleaning HTR based on recycle of HTR-generated TRU in the same HTR. Chapter IV contains the design and analysis results of the 600MWth DB-HTR core physics with the cycle length, the average discharged burnup, heavy metal and plutonium consumptions, radial and axial power distributions, temperature reactivity coefficients. Also, it contains the analysis results of the 450MWth DB-HTR core physics and the analysis of the decay heat of a TRU loaded DB-HTR core. The evaluation of the hot spot fuel temperature of the fuel block in the DB-HTR (Deep-Burn High Temperature Reactor) core under full operating power conditions are described in Chapter V. The investigated designs are the 600MWth and 460MWth DB-HTRs. In Chapter VI, the thermo-fluid and safety of the 600MWth DB-HTRs has been analyzed to investigate a thermal-fluid design performance at the steady state and a passive safety performance during an LPCC event. Chapter VII describes the analysis results of the TRISO fuel microanalysis of the 600MWth and 450MWth DB-HTRs. The TRISO fuel microanalysis covers the gas pressure buildup in a coated fuel particle including helium production, the thermo-mechanical behavior of a CFP, the failure probabilities of CFPs, the temperature distribution in a CPF, and the fission product (FP) transport in a CFP and a graphite. In Chapter VIII, it contains the core design and analysis of sodium cooled fast reactor (SFR) with deep burn HTR reactor. It considers a synergistic combination of the DB-MHR and an SFR burner for a safe and efficient transmutation of the TRUs from LWRs. Chapter IX describes the design and analysis results of the self-cleaning (or self-recycling) HTR core. The analysis is considered zero and 5-year cooling time of the spent LWR fuels.

  14. Back-junction back-contact n-type silicon solar cell with diffused boron emitter locally blocked by implanted phosphorus

    SciTech Connect (OSTI)

    Mller, Ralph Schrof, Julian; Reichel, Christian; Benick, Jan; Hermle, Martin

    2014-09-08

    The highest energy conversion efficiencies in the field of silicon-based photovoltaics have been achieved with back-junction back-contact (BJBC) silicon solar cells by several companies and research groups. One of the most complex parts of this cell structure is the fabrication of the locally doped p- and n-type regions, both on the back side of the solar cell. In this work, we introduce a process sequence based on a synergistic use of ion implantation and furnace diffusion. This sequence enables the formation of all doped regions for a BJBC silicon solar cell in only three processing steps. We observed that implanted phosphorus can block the diffusion of boron atoms into the silicon substrate by nearly three orders of magnitude. Thus, locally implanted phosphorus can be used as an in-situ mask for a subsequent boron diffusion which simultaneously anneals the implanted phosphorus and forms the boron emitter. BJBC silicon solar cells produced with such an easy-to-fabricate process achieved conversion efficiencies of up to 21.7%. An open-circuit voltage of 674?mV and a fill factor of 80.6% prove that there is no significant recombination at the sharp transition between the highly doped emitter and the highly doped back surface field at the device level.

  15. Aternating current photovoltaic building block

    DOE Patents [OSTI]

    Bower, Ward Issac; Thomas, Michael G.; Ruby, Douglas S.

    2004-06-15

    A modular apparatus for and method of alternating current photovoltaic power generation comprising via a photovoltaic module, generating power in the form of direct current; and converting direct current to alternating current and exporting power via one or more power conversion and transfer units attached to the module, each unit comprising a unitary housing extending a length or width of the module, which housing comprises: contact means for receiving direct current from the module; one or more direct current-to-alternating current inverters; an alternating current bus; and contact means for receiving alternating current from the one or more inverters.

  16. Dynamics of Block Copolymer Nanocomposites

    SciTech Connect (OSTI)

    Mochrie, Simon G. J.

    2014-09-09

    A detailed study of the dynamics of cadmium sulfide nanoparticles suspended in polystyrene homopolymer matrices was carried out using X-ray photon correlation spectroscopy for temperatures between 120 and 180 C. For low molecular weight polystyrene homopolymers, the observed dynamics show a crossover from diffusive to hyper-diffusive behavior with decreasing temperatures. For higher molecular weight polystyrene, the nanoparticle dynamics appear hyper-diffusive at all temperatures studied. The relaxation time and characteristic velocity determined from the measured hyper-diffusive dynamics reveal that the activation energy and underlying forces determined are on the order of 2.14 10?19 J and 87 pN, respectively. We also carried out a detailed X-ray scattering study of the static and dynamic behavior of a styrene isoprene diblock copolymer melt with a styrene volume fraction of 0.3468. At 115 and 120 C, we observe splitting of the principal Bragg peak, which we attribute to phase coexistence of hexagonal cylindrical and cubic double- gyroid structure. In the disordered phase, above 130 C, we have characterized the dynamics of composition fluctuations via X-ray photon correlation spectroscopy. Near the peak of the static structure factor, these fluctuations show stretched-exponential relaxations, characterized by a stretching exponent of about 0.36 for a range of temperatures immediately above the MST. The corresponding characteristic relaxation times vary exponentially with temperature, changing by a factor of 2 for each 2 C change in temperature. At low wavevectors, the measured relaxations are diffusive with relaxation times that change by a factor of 2 for each 8 C change in temperature.

  17. LANSCE-NS Block Schedule

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANSCE Planned Run Schedule - 2015/2016 run_schedule

  18. Blocking S1P interaction with S1P{sub 1} receptor by a novel competitive S1P{sub 1}-selective antagonist inhibits angiogenesis

    SciTech Connect (OSTI)

    Fujii, Yasuyuki; Ueda, Yasuji; Ohtake, Hidenori; Ono, Naoya; Takayama, Tetsuo; Nakazawa, Kiyoshi; Igarashi, Yasuyuki; Goitsuka, Ryo

    2012-03-23

    Highlights: Black-Right-Pointing-Pointer The effect of a newly developed S1P{sub 1}-selective antagonist on angiogenic responses. Black-Right-Pointing-Pointer S1P{sub 1} is a critical component of VEGF-related angiogenic responses. Black-Right-Pointing-Pointer S1P{sub 1}-selective antagonist showed in vitro activity to inhibit angiogenesis. Black-Right-Pointing-Pointer S1P{sub 1}-selective antagonist showed in vivo activity to inhibit angiogenesis. Black-Right-Pointing-Pointer The efficacy of S1P{sub 1}-selective antagonist for anti-cancer therapies. -- Abstract: Sphingosine 1-phosphate receptor type 1 (S1P{sub 1}) was shown to be essential for vascular maturation during embryonic development and it has been demonstrated that substantial crosstalk exists between S1P{sub 1} and other pro-angiogenic growth factors, such as vascular endothelial growth factor (VEGF) and basic fibroblast growth factor. We developed a novel S1P{sub 1}-selective antagonist, TASP0277308, which is structurally unrelated to S1P as well as previously described S1P{sub 1} antagonists. TASP0277308 inhibited S1P- as well as VEGF-induced cellular responses, including migration and proliferation of human umbilical vein endothelial cells. Furthermore, TASP0277308 effectively blocked a VEGF-induced tube formation in vitro and significantly suppressed tumor cell-induced angiogenesis in vivo. These findings revealed that S1P{sub 1} is a critical component of VEGF-related angiogenic responses and also provide evidence for the efficacy of TASP0277308 for anti-cancer therapies.

  19. South Carolina Energy Office … Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009, OAS-RA-13-21

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    South Carolina Energy Office - Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009 OAS-RA-13-21 May 2013 Department of Energy Washington, DC 20585 May 14, 2013 MEMORANDUM FOR THE PROGRAM MANAGER, WEATHERIZATION AND INTERGOVERNMENTAL PROGRAM, OFFICE OF ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Jack Rouch, Director Central Audits Division Office of Inspector General SUBJECT: INFORMATION: Examination Report on "South

  20. The Department of Energy's Energy Efficiency and Conservation Block Grant Program Funded under the American Recovery and Reinvestment Act for the City of Philadelphia, OAS-RA-12-09

    Energy Savers [EERE]

    Energy Efficiency and Conservation Block Grant Program Funded under the American Recovery and Reinvestment Act for the City of Philadelphia OAS-RA-12-09 April 2012 Department of Energy Washington, DC 20585 April 23, 2012 MEMORANDUM FOR THE ASSISTANT SECRETARY FOR ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: George W. Collard Assistant Inspector General for Audits Office of Inspector General SUBJECT: INFORMATION: Audit Report on "The Department of Energy's Energy Efficiency and Conservation

  1. The Department of Energy's Energy Efficiency and Conservation Block Grant Program Funded under the American Recovery and Reinvestment Act for the State of Pennsylvania, OAS-RA-L-11-11

    Energy Savers [EERE]

    State of Pennsylvania OAS-RA-L-11-11 September 2011 Department of Energy Washington, DC 20585 September 23, 2011 MEMORANDUM FOR PROGRAM MANAGER, OFFICE OF WEATHERIZATION AND INTERGOVERNMENTAL PROGRAM MANAGER, GOLDEN FIELD OFFICE FROM: Joanne Hill, Director Energy Audits Division Office of Inspector General SUBJECT: INFORMATION: Audit Report on "The Department of Energy's Energy Efficiency and Conservation Block Grant Program Funded under the American Recovery and Reinvestment Act for the

  2. Examination Report on "The Department of Energy's American Recovery and Reinvestment Act of 2009 Energy Efficiency and Conservation Block Grant Program - Efficiency Maine Trust", OAS-RA-13-04

    Office of Environmental Management (EM)

    The Department of Energy's American Recovery and Reinvestment Act Energy Efficiency and Conservation Block Grant Program - Efficiency Maine Trust OAS-RA-13-04 November 2012 Department of Energy Washington, DC 20585 November 8, 2012 MEMORANDUM FOR THE ASSISTANT SECRETARY FOR ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Rickey R. Hass Deputy Inspector General for Audits and Inspections Office of Inspector General SUBJECT: INFORMATION: Examination Report on "The Department of Energy's American

  3. City of Los Angeles  Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009, OAS-RA-13-12

    Office of Environmental Management (EM)

    City of Los Angeles - Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009 OAS-RA-13-12 February 2013 Department of Energy Washington, DC 20585 February 19, 2013 MEMORANDUM FOR THE ASSISTANT SECRETARY FOR ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Rickey R. Hass Deputy Inspector General for Audits and Inspections Office of Inspector General SUBJECT: INFORMATION: Examination Report on "City of Los Angeles  Energy

  4. Connecticut Department of Energy and Environmental Protection  Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009, OAS-RA-13-14

    Office of Environmental Management (EM)

    Connecticut Department of Energy and Environmental Protection  Energy Efficiency and Conservation Block Grant Program Funds Provided by the American Recovery and Reinvestment Act of 2009 OAS-RA-13-14 February 2013 Department of Energy Washington, DC 20585 February 28, 2013 MEMORANDUM FOR THE ASSISTANT SECRETARY FOR ENERGY EFFICIENCY AND RENEWABLE ENERGY FROM: Rickey R. Hass Deputy Inspector General for Audits and Inspections Office of Inspector General SUBJECT: INFORMATION: Examination Report

  5. STELLAR POPULATIONS OF Ly{alpha} EMITTERS AT z {approx} 6-7: CONSTRAINTS ON THE ESCAPE FRACTION OF IONIZING PHOTONS FROM GALAXY BUILDING BLOCKS

    SciTech Connect (OSTI)

    Ono, Yoshiaki; Shimasaku, Kazuhiro; Okamura, Sadanori; Masami Ouchi; Dunlop, James; Farrah, Duncan; McLure, Ross

    2010-12-01

    We investigate the stellar populations of Ly{alpha} emitters (LAEs) at z = 5.7 and 6.6 in a 0.65 deg{sup 2} sky of the Subaru/XMM-Newton Deep Survey (SXDS) Field, using deep images taken with the Subaru/Suprime-Cam, United Kingdom Infrared Telescope/Wide Field Infrared Camera, and Spitzer/Infrared Array Camera (IRAC). We produce stacked multiband images at each redshift from 165 (z = 5.7) and 91 (z = 6.6) IRAC-undetected objects to derive typical spectral energy distributions (SEDs) of z {approx} 6-7 LAEs for the first time. The stacked LAEs have as blue UV continua as the Hubble Space Telescope (HST)/Wide Field Camera 3 (WFC3) z-dropout galaxies of similar M{sub UV}, with a spectral slope {beta} {approx} -3, but at the same time they have red UV-to-optical colors with detection in the 3.6 {mu}m band. Using SED fitting we find that the stacked LAEs have low stellar masses of {approx}(3-10) x 10{sup 7} M{sub sun}, very young ages of {approx}1-3 Myr, negligible dust extinction, and strong nebular emission from the ionized interstellar medium, although the z = 6.6 object is fitted similarly well with high-mass models without nebular emission; inclusion of nebular emission reproduces the red UV-to-optical colors while keeping the UV colors sufficiently blue. We infer that typical LAEs at z {approx} 6-7 are building blocks of galaxies seen at lower redshifts. We find a tentative decrease in the Ly{alpha} escape fraction from z = 5.7 to 6.6, which may imply an increase in the intergalactic medium neutral fraction. From the minimum contribution of nebular emission required to fit the observed SEDs, we place an upper limit on the escape fraction of ionizing photons of f {sup ion}{sub esc} {approx} 0.6 at z = 5.7 and {approx}0.9 at z = 6.6. We also compare the stellar populations of our LAEs with those of stacked HST/WFC3 z-dropout galaxies.

  6. Synthesis and characterization of CuO nanofibers, and investigation for its suitability as blocking layer in ZnO NPs based dye sensitized solar cell and as photocatalyst in organic dye degradation

    SciTech Connect (OSTI)

    Sahay, R.; Sundaramurthy, J.; Suresh Kumar, P.; Thavasi, V.; Mhaisalkar, S.G.; Ramakrishna, S.

    2012-02-15

    Electrospun copper based composite nanofibers were synthesized using the copper acetate/polyvinyl alcohol/water solution as starting material. Synthesized composite nanofibers were sintered at 500 Degree-Sign C to obtain CuO nanofibers. XRD, FTIR and XPS techniques were used to confirm the presence of pure CuO nanostructures. The effect of annealing cycle on the crystalline structure of the CuO nanofibers was analyzed and observed that the decrease in crystallite size with an increase in the dwelling time improved the orientation of the CuO crystallite. The blue-shift in the band-gap energies of CuO nanofibers was observed as a result of quantum confinement from bulk CuO (1.2 eV) to one dimensional (1D) nanostructures ({approx}1.746 eV). The catalytic activity of the CuO fibers for the degradation of methyl orange was carried out and as a blocking layer in ZnO based DSSC was fabricated and observed a {approx}25% increase in the current density. - Graphical abstract: The study on the suitability of highly crystalline CuO nanofibers as the blocking layer in ZnO based DSSC was demonstrated and fabricated with possible energy applications. Highlights: Black-Right-Pointing-Pointer CuO nanofibers were successfully synthesized by using electrospinning technique. Black-Right-Pointing-Pointer The effect of the dwelling time of the annealing cycle for the formation of the crystallite CuO nanofibers was analyzed. Black-Right-Pointing-Pointer A 25% increase in the current density was observed with the application of CuO as blocking layer.

  7. GaInN light-emitting diodes using separate epitaxial growth for the p-type region to attain polarization-inverted electron-blocking layer, reduced electron leakage, and improved hole injection

    SciTech Connect (OSTI)

    Meyaard, David S., E-mail: meyaad@rpi.edu; Lin, Guan-Bo; Ma, Ming; Fred Schubert, E. [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States)] [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Cho, Jaehee [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States) [Future Chips Constellation, Department of Electrical, Computer, and Systems Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Semiconductor Physics Research Center, School of Semiconductor and Chemical Engineering, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Han, Sang-Heon; Kim, Min-Ho; Shim, HyunWook; Sun Kim, Young [LED Business, Samsung Electronics, Yongin 446-920 (Korea, Republic of)] [LED Business, Samsung Electronics, Yongin 446-920 (Korea, Republic of)

    2013-11-11

    A GaInN light-emitting diode (LED) structure is analyzed that employs a separate epitaxial growth for the p-type region, i.e., the AlGaN electron-blocking layer (EBL) and p-type GaN cladding layer, followed by wafer or chip bonding. Such LED structure has a polarization-inverted EBL and allows for uncompromised epitaxial-growth optimization of the p-type region, i.e., without the need to consider degradation of the quantum-well active region during p-type region growth. Simulations show that such an LED structure reduces electron leakage, reduces the efficiency droop, improves hole injection, and has the potential to extend high efficiencies into the green spectral region.

  8. Midland County, Michigan: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    is classified as ASHRAE 169-2006 Climate Zone Number 5 Climate Zone Subtype A. Registered Energy Companies in Midland County, Michigan Dow Chemical Co Dow Kokam LXE Places in...

  9. Bay County, Michigan: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    is classified as ASHRAE 169-2006 Climate Zone Number 5 Climate Zone Subtype A. Registered Energy Companies in Bay County, Michigan Dow Chemical Co Dow Kokam Places in Bay County,...

  10. Project Profile: Transformational Approach to Reducing the Total System Costs of Building-Integrated Photovoltaics

    Broader source: Energy.gov [DOE]

    The Dow Chemical Company, under the BOS-X funding opportunity, has launched a transformational product in the building-integrated photovoltaics (BIPV) industry: the Dow POWERHOUSE Solar Shingle.

  11. An Industrial Wish List for Membrane-Based Separations

    Broader source: Energy.gov [DOE]

    Presentation by Shawn Feist (The Dow Chemical Company) for the Membrane Technology Workshop held July 24, 2012

  12. Hygroscopic La[B{sub 5}O{sub 8}(OH)]NO{sub 3}·2H{sub 2}O: Insight into the evolution of borate fundamental building blocks

    SciTech Connect (OSTI)

    Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao

    2013-10-15

    Borates have exceptionally diverse fundamental building blocks (FBBs), but factors controlling the formation of borate FBBs are poorly understood. The title compound La[B{sub 5}O{sub 8}(OH)]NO{sub 3}·2H{sub 2}O crystallizes in the space group P2{sub 1}/n with a=6.5396(12) Å, b=15.550(3) Å, c=10.6719(19) Å, β=90.44(1)° and Z=4 at 173(2) K. Its structure has been refined from single-crystal X-ray diffraction data to R{sub 1}=0.049 (for 2465) and wR{sub 2}=0.173 (for 2459 I>2σ(I)). This structure analysis and first-principles calculations show that the change of the FBB from 3Δ2□ in the title compound to 2Δ3□ in La[B{sub 5}O{sub 8}(OH)(H{sub 2}O)]NO{sub 3}·2H{sub 2}O is accompanied by a rotation of the NO{sub 3} group. FTIR, Rietveld and thermal analysis results show that the hygroscopic title compound is partially changed to La[B{sub 5}O{sub 8}(OH)(H{sub 2}O)]NO{sub 3}·2H{sub 2}O, with the conversion of [BO{sub 3}] to [BO{sub 3}(H{sub 2}O)] by water absorption. - Graphical abstract: The change of fundamental building blocks from La[B{sub 5}O{sub 8}(OH)]NO{sub 3}·2H{sub 2}O to La[B{sub 5}O{sub 8}(OH)(H{sub 2}O)]NO{sub 3}·2H{sub 2}O is accompanied by a rotation of the NO{sub 3} group . Display Omitted - Highlights: • Synthesis of a new hydrous lanthanum polyborate nitrate. • Single-crystal XRD structure with the 3Δ2⎕ FBB and an oriented NO{sub 3} group. • DFT calculations locate the H positions in three lanthanide polyborate nitrates. • Rietveld, FTIR and DFT results show hygroscopicity changes the FBBs.

  13. New thermotropic chiral nematic copolymers using (1S,2S,3S,5R)-(+)- and (1R,2R,3R,5S)-([minus])-isopinocampheol as building blocks

    SciTech Connect (OSTI)

    Chen, S.H.; Tsai, M.L. . Dept. of Chemical Engineering and Lab. for Laser Energetics)

    1990-01-01

    Thermotropic chiral nematic side-chain copolymers were synthesized and characterized by using (1S,2S,3S,5R)-(+)- and (1R,2R,3R,5S)-([minus])-isopinocampheol as the chiral building blocks. The helical twisting power was found to correlate with the volume swept out by the chiral pendant group via rotation for a given nematogenic monomer. However, the enhanced mesomorphic order introduced in both the nematogenic and chiral monomers as a result of an increased extent of conjugation or a shortened spacer length was found to reduce the helical twisting power of the resultant copolymer. Hence, both factors have to be taken into account as the helical twisting power of a copolymer system is to be optimized for a specific application. The present work also generalized the previous observation that the inversion of chirality of the pendant group results in helical sense reversal, although the role of the absolute configuration of the chiral moiety is not yet clearly understood.

  14. Bottlebrush Block Polymers: Quantitative Theory and Experiments...

    Office of Scientific and Technical Information (OSTI)

    1225404 GrantContract Number: AC02-06CH11357 Type: Published Article Journal Name: ACS Nano Additional Journal Information: Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN...

  15. Building Blocks for the Future of Manufacturing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AMmachine-500x333 Prabhjot's technical background focused on manufacturing technology. In ... The transducers use a dense array of elements, each converting electrical signals into ...

  16. HUD Community Development Block Grant Program

    Broader source: Energy.gov [DOE]

    The U.S. Department of Housing and Urban Development (HUD) is accepting applications to develop of viable Indian and Alaska Native communities, including the creation of decent housing, suitable living environments, and economic opportunities primarily for persons with low- and moderate-incomes.

  17. Template:FlexiBlock | Open Energy Information

    Open Energy Info (EERE)

    (654px wide instead of 314px) Background: nobg bg-green bg-grey bg-orange bg-pink bg-red bg-purple bg-purple-grey Custom: custom-flite-widget (helps format FLITE widgets with...

  18. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    solar array at city parking areas, 3) replace existing street lights with HE inductionLED lights, 4) install fuel cellengine hybrid power and microgrid for city E911emergency...

  19. Low-Cost Energy Efficiency Goes Block-to-Block | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    An innovative pilot program in Minneapolis, Minnesota, focuses on rallying whole communities around energy efficiency, one neighborhood at a time. Through the program, area residents cash in on a home energy-efficiency upgrade that saves them roughly $130 on their annual energy bill. All they have to contribute is a little time and a small initial payment. "The most effective way to get people involved is for people to tell each other, neighbor to neighbor," says Lola Schoenrich, who

  20. CX-009237: Categorical Exclusion Determination | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    237: Categorical Exclusion Determination CX-009237: Categorical Exclusion Determination The Dow Chemical Company CX(s) Applied: B5.7 Date: 10/02/2012 Location(s): Texas Offices(s): Fossil Energy The Dow Chemical Company (Dow), a Delaware corporation, with its primary place of business in Midland, Michigan, filed an application with the Office of Fossil Energy (FE) on July 13, 2012, seeking authorization to export previously imported liquefied natural gas (LNG) from the Freeport LNG Development,

  1. Mauro Gregorio | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mauro Gregorio About Us Mauro Gregorio - Business President for Energy Solutions, Dow Chemical Mauro Gregorio Mauro Gregorio is president of the Energy Solutions business of The Dow Chemical Company, which includes Energy; Oil, Gas & Mining; and Alternative Energy. He is responsible for driving profit and growth strategies across those four global business units. Previously, Gregorio served in a dual role in Dow's Performance Plastics division. He was business vice president for the global

  2. Evaluation of the Ad Council/DOE Whats Your ExcuseŽ Public...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... even after controlling for preexisting motivation. Results 3-29 Table 3-10d. ... use by 14 percent (http:energy.dow.comenergyplanefficiencyeducation.htm, accessed on 13110). ...

  3. Alejandro Briseo: Department of Polymer Science and Engineering...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has been selected as the 2014 UC Santa Barbara Dow Distinguished Lecturer Crystal Chemistry, Molecular Order, and Charge Transport at Organic Semiconductor Interfaces February...

  4. Interested Parties - NYU | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    3-30-2010_NYU.pdf More Documents & Publications Interested Parties - ARPA-E / National Association of Manufacturers Interested Parties - Myriant Interested Parties - Dow Chemical

  5. Interested Parties - XtremePower | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon 05-12-10_XtremePower.pdf More Documents & Publications Interested Parties - Myriant Interested Parties - Dow Chemical Interested Parties - Shipp

  6. Accounting for All Sugars Produced during Integrated Production...

    Office of Scientific and Technical Information (OSTI)

    Authors: Schell, Daniel J. ; Dowe, Nancy ; Chapeaux, Alexandre ; Nelson, Robert S. ; Jennings, Edward W. Publication Date: 2016-04-01 OSTI Identifier: 1237439 Report Number(s): ...

  7. Advance Patent Waiver W(A)2011-049

    Broader source: Energy.gov [DOE]

    This is a request by DOW CHEMICAL COMPANY for a DOE waiver of domestic and foreign patent rights under agreement DE-EE0003916.

  8. Millie Dresselhaus: Department of Physics and Engineering, Massachuset...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the 2013 UC Santa Barbara Dow Distinguished Lecturer Personal Perspectives on Advancing Energy Sustainability November 20, 2013 | 4:00pm | ESB 1001 Faculty host: John Bowers and...

  9. Advance Patent Waiver W(A)2011-071

    Office of Energy Efficiency and Renewable Energy (EERE)

    This is a request by THE DOW CHEMICAL COMPANY for a DOE waiver of domestic and foreign patent rights under agreement DE-EE0005434.

  10. Industry Group Learns About Light Source Opportunities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Micron, Dow, and others, has partnered with Berkeley Lab's Center for X-Ray Optics to develop world-leading research and development infrastructure to study extreme...

  11. STATEMENT OF CONSIDERATIONS

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    REQUEST BY THE DOW CHEMICAL COMPANY (DOW) FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN PATENT RIGHTS UNDER DOE AWARD NO. DE-EE0002867; W(A)-2011-034 The Petitioner, Dow, has requested a waiver of domestic and foreign patent rights for al1 subject inventions arising from its participation under the above referenced award entitled "Recovery Act: Integrated Pilot-Scale Biorefinery for Producing Ethanol from Hybrid Algae." Dow is a subawardee of Algenol Biofuels, Inc., which is not

  12. Metal Buildings M&V

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Atlas Bolt & Screw Behlen Manufacturing Butler Manufacturing Building Research Systems Kirby Building Systems DOW Lamtec Schulte Building Systems Participants: Bigbee Steel Chief ...

  13. EA-1708: Final Environmental Assessment

    Office of Energy Efficiency and Renewable Energy (EERE)

    Financial Assistance to Dow Kokam Mi, LLC To Manufacture Advanced Lithium Polymer Batteries for Hybrid and Electric Vehicles At Midland, Michigan

  14. PNNL: About PNNL - Laboratory Awards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Previous winners include: Alcoa, Bechtel Group Inc., Dow ... IEEE (www.ieee.org) was established in 1963, uniting the ... of Energy at the Hanford Site and other facilities ...

  15. Day Two of 2012 ARPA-E Summit Will Feature Bill Gates, Secretary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Bart Gordon, K&L Gates, Partner; Former Representative from Tennessee Stefan Heck, McKinsey & Co., Director, Leader of Global Cleantech Practice Carrie Houtman, The Dow Chemical...

  16. Secretary Chu Announces Steps to Implement Cool Roofs at DOE...

    Broader source: Energy.gov (indexed) [DOE]

    ... Labs Join with Dow Chemical to Develop Next-Generation Cool Roofs Energy Department Completes Cool Roof Installation on DC Headquarters Building to Save Money by Saving Energy

  17. Contact - Center for Solar and Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact Prof. Peter Green, CSTEC Director Research Group Leader for Thrust 3 - Energy transport in organic and hybrid systems Materials Science & Engineering Dept. H H Dow ...

  18. Jeff Chamberlain, External Integration Officer | JCESR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chamberlain conducted industrial research at several companies, notably Cabot Microelectronics, Nalco Company and Angus Chemical (owned by The Dow Chemical Company). He...

  19. Advance Patent Waiver W(A)2009-019

    Broader source: Energy.gov [DOE]

    This is a request by DOW CORNING CORPORATION for a DOE waiver of domestic and foreign patent rights under agreement DE-FG36-08GO18068

  20. Studying the Building Blocks of Matter: Public Talk Planned for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studying the Building locks of Matter: Public Talk Planned for Oct. 7 at Jefferson Lab CEBAF Race Track This aerial photo shows the outline of the racetrack-shaped CEBAF...

  1. Directed Assembly of Lamellae Forming Block Copolymer Thin Films...

    Office of Scientific and Technical Information (OSTI)

    Identifier: 1149628 Resource Type: Journal Article Resource Relation: Journal Name: Nano Lett.; Journal Volume: 14; Journal Issue: (1) ; 01, 2014 Research Org: Advanced Photon...

  2. Nanocluster building blocks of artificial square spin ice: Stray...

    Office of Scientific and Technical Information (OSTI)

    Author Affiliations Institute of Physics, Goethe-University Frankfurt, FrankfurtMain (Germany) Laboratory for Nanoelectronics and Spintronics, Research Institute of Electrical...

  3. Method for eliminating gas blocking in electrokinetic pumping systems

    DOE Patents [OSTI]

    Arnold, Don W. (Livermore, CA); Paul, Phillip H. (Livermore, CA); Schoeniger, Joseph S. (Oakland, CA)

    2001-09-11

    A method for eliminating gas bubble blockage of current flow during operation of an electrokinetic pump. By making use of the ability to modify the surface charge on the porous dielectric medium used in electrokinetic pumps, it becomes possible to place electrodes away from the pressurized region of the electrokinetic pump. While gas is still generated at the electrodes they are situated such that the generated gas can escape into a larger buffer reservoir and not into the high pressure region of the pump where the gas bubbles can interrupt current flow. Various combinations of porous dielectric materials and ionic conductors can be used to create pumps that have desirable electrical, material handling, and flow attributes.

  4. 2008-07-31 Draft NR Block Template

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Customer Name acquires from an identified or unidentified electricity-producing unit by contract purchase, and for which the amount received by Customer Name does not...

  5. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    angle and thus dominated by contributions from the PEMair surface contained well-defined spots, indicating the presence of hydrophilic channels oriented perpendicular to the...

  6. One Block Off The Grid | Open Energy Information

    Open Energy Info (EERE)

    discounts and group financing options on their behalf. For its members, 1BOG makes the process of buying solar panels easier, cheaper and safer. Meanwhile, for its partners in...

  7. Microsoft Word - DSI Block 01_16_09.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Requirements ...16 9. Employment Expenditures And Capital Investment ...19 9.1 Employment and Capital...

  8. Fault block kinematics at a releasing stepover of the Eastern...

    Open Energy Info (EERE)

    Coso geothermal area and what Monastero et al. (F.C. Monastero, A.M. Katzenstein, J.S. Miller, J.R. Unruh, M.C. Adams, K. Richards-Dinger, The Coso geothermal field: a nascent...

  9. Fault Block Kinematics at a Releasing Stepover of the Eastern...

    Open Energy Info (EERE)

    Coso geothermal area and what Monastero et al. F.C. Monastero, A.M. Katzenstein, J.S. Miller, J.R. Unruh, M.C. Adams, K. Richards-Dinger, The Coso geothermal field: a nascent...

  10. Method and structure for skewed block-cyclic distribution of...

    Office of Scientific and Technical Information (OSTI)

    A method and structure of distributing elements of an array of data in a computer memory to a specific processor of a multi-dimensional mesh of parallel processors includes ...

  11. Scalable production of mechanically tunable block polymers from...

    Office of Scientific and Technical Information (OSTI)

    Resource Type: Journal Article Resource Relation: Journal Name: Proc. Natl. Acad. Sci. USA; Journal Volume: 111; Journal Issue: (23) ; 06, 2014 Research Org: Advanced Photon...

  12. New York Town Gets Block Grant at Perfect Time

    Broader source: Energy.gov [DOE]

    The town estimates the savings from energy-efficient facility upgrades will add up to $447,547 in just 15 years.

  13. Energy Efficiency and Conservation Block Grant Program Success...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and recycling programs. Learn more. June 24, 2010 The roof of the justice center where a solar panel array will be installed to power a solar thermal water-heating system | Photo...

  14. Energy Efficiency and Conservation Block Grant Program Success...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to consumers is now home to Danville, Virg.'s first renewable energy project - a 154-panel solar energy system. Learn more. November 2, 2010 A new heating and cooling system...

  15. Milling of Sand Blocks to Make Casting Moulds

    SciTech Connect (OSTI)

    Lopez de Lacalle, L. N.; Rodriguez, A.; Lamikiz, A.; Penafiel, F. J. [Department of Mechanical Engineering, University of the Basque Country, ETSII, c/Alameda de Urquijo s/n, 48013 Bilbao (Spain)

    2011-01-17

    In this paper a full procedure to make moulds in sand for direct casting of metallic parts is presented. The technology aims at unique pieces or art pieces, where only one prototype or components is required, but lead times are much reduced. The key of the procedure is to achieve enough tool life when milling with carbide tools, avoiding the risk of sand destruction or damage.The use of inverse techniques is a common input due to the industrial sectors where the direct milling is interesting. Two examples of moulds are presented, evaluating times and costs. A special study of tool wear is also presented.

  16. Energy Efficiency and Conservation Block Grant Program Success...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    November 19, 2011 Installing LED pedestrian and traffic lights like this one are among the improvements made by cities in New Hampshire to cut their energy costs. | DOE photo,...

  17. Energy Efficiency and Conservation Block Grant Program Success...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wed, 19 Sep 2012 14:43:00 +0000 938681 at http:energy.gov EECBG Success Story: Solar LED Light Pilot Project Illuminates the Way in Alabama http:energy.goveerewipo...

  18. Block Copolymer Cathode Binder to Simultaneously Transport Electronic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Berkeley Lab team led by Nitash Balsara has developed a highly efficient lithium ion battery in which a single inactive material-a polymeric binding agent-serves as a binder that ...

  19. Method and structure for skewed block-cyclic distribution of...

    Office of Scientific and Technical Information (OSTI)

    A method and structure of distributing elements of an array of data in a computer memory to a specific processor of a multi-dimensional mesh of parallel processors includes...

  20. The electromechanical battery: The new kid on the block

    SciTech Connect (OSTI)

    Post, R.F.

    1993-08-01

    In a funded program at the Lawrence Livermore National Laboratory new materials and novel designs are being incorporated into a new approach to an old concept -- flywheel energy storage. Modular devices, dubbed ``electromechanical batteries`` (EMB) are being developed that should represent an important alternative to the electrochemical storage battery for use in electric vehicles or for stationary applications, such as computer back-up power or utility load-leveling.

  1. Microsoft Word - BPA analysis summarizing CFAC block contract...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DSI and DSI service of 372 aMW. The average total monthly expense values of the 3,500 games were computed for with and without service to the DSI and the differences were...

  2. Microsoft Word - BPA analysis summarizing PT block contract ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    incremental transmission need under each water condition. The mean value of the 3,500 games for which this was done represents the forecasted cost of the incremental transmission...

  3. Microsoft Word - BPA analysis summarizing ALCOA block contract...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    does not sell to them - all of BPA's surplus sales realize increased revenues because the mean value of prices for electricity in Western power markets are higher than they would...

  4. Structural response of a prealigned cylindrical block copolymer...

    Office of Scientific and Technical Information (OSTI)

    Have feedback or suggestions for a way to improve these results? Save Share this Record Citation Formats MLA APA Chicago Bibtex Export Metadata Endnote Excel CSV XML Save to My ...

  5. Microsoft Word - DSI Block 12_05_08.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    successor. 8.4.5.7 "S&P" shall mean Standard and Poor's Rating Services (a division of McGraw-Hill, Inc.) or its successor. 9. EMPLOYMENT EXPENDITURES AND CAPITAL INVESTMENT 9.1...

  6. Tribal Energy Efficiency and Conservation Block Grant Program (EECBG)

    Energy Savers [EERE]

    Annual Review Denver, CO November 14, 2011 Tsali Cross Project Officer, EECBG Tribal Energy Program, Golden Field Office U.S. Department of Energy EECBG Overview: Program Purpose American Recovery and Reinvestment Act of 2009 To spur economic growth and create/retain jobs Energy Independence and Security Act of 2007: To assist state, local, and tribal governments in implementing strategies to: a. Reduce fossil fuel emissions; b. Reduce total energy use; c. Improve energy efficiency in the

  7. Tribal Energy Efficiency and Conservation Block Grant Program (EECBG)

    Energy Savers [EERE]

    Review November 14, 2011 Paul Dearhouse Project Officer, EECBG Tribal Energy Program, Golden Field Office U.S. Department of Energy OUTLINE * EECBG Overview & EECBG Activities * Current Priorities and Initiatives * Regional Snapshots - AK - NW - SW * Vignettes Eligible Uses of Funds 1. Strategy Development 2. Technical Consultant Services 3. Building Energy Audits 4. Financial Incentive Programs 5. Energy Efficiency Retrofits 6. Energy Efficiency and Conservation Programs for Buildings and

  8. Microsoft Word - Draft Amendment to CFAC block power sales agreement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contract No. 06PB-11745 AMENDMENT executed by the BONNEVILLE POWER ADMINISTRATION and COLUMBIA FALLS ALUMINUM COMPANY, LLC and FLATHEAD ELECTRIC COOPERATIVE, INC This AMENDMENT to...

  9. Microsoft Word - Draft Amendment to CFAC block power sales agreement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amendment No. 1 Contract No. 06PB-11745 AMENDMENT executed by the BONNEVILLE POWER ADMINISTRATION and COLUMBIA FALLS ALUMINUM COMPANY, LLC and FLATHEAD ELECTRIC COOPERATIVE, INC...

  10. 2015 Nuclear and Facility Safety Programs Workshop Block Agenda

    Broader source: Energy.gov (indexed) [DOE]

    Worthington (AU-10) ISM o Colette Broussard (AU-23) QA and Other Data Trending o Pat Lewis (SC-CH) Lessons From Safety Basis Reviews o Carl Sykes (NA-511) Exemptions * Readiness...

  11. Net Requirements Transparency Process for Slice/Block Customers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which of loss of resource was recognized by the Administrator) from FY2011 were carried forward into the CHWM Contracts, and capabilities of those resources were evaluated and...

  12. Advanced Ceramic Filter For Diesel Emission Control | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ceramic Filter For Diesel Emission Control Advanced Ceramic Filter For Diesel Emission Control 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Dow Automotive PDF icon 2004_deer_mao.pdf More Documents & Publications Vehicle Evaluation of Downsized Dow ACM DPF fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate Filters Tailored Acicular Mullite Substrates for Multifunctional Diesel Particulate Filters

  13. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  14. Fall 2013 Working Groups

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 C STEC W orking G roup S chedule Thrust I ( IPV) Selected W ednesdays 1:30---2:30pm September 25 1100 Dow Matt Dejarld (Millunchick), Michael Kuo (Ku) October 16 MSE Conf. Simon Huang (Goldman), Brian Roberts (Ku) November 6 MSE Conf. Mike Abere (Yalisove), Jimmy Chen (Phillips) December 11 MSE Conf. Dylan Bayerl (Kioupakis), Larry Aagesen (Thornton) Thrust I I ( TE) Selected F ridays 1:30---2:30pm September 20 1100 Dow Vladimir Stoica (Clarke) October 18 1100 Dow Wei Liu (Uher) November 8

  15. WA_04_033_CARGILL_Waiver_of_Patent_Rights_to_CARGILL_DOWN_L.pdf |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 33_CARGILL_Waiver_of_Patent_Rights_to_CARGILL_DOWN_L.pdf WA_04_033_CARGILL_Waiver_of_Patent_Rights_to_CARGILL_DOWN_L.pdf PDF icon WA_04_033_CARGILL_Waiver_of_Patent_Rights_to_CARGILL_DOWN_L.pdf More Documents & Publications WA_00_022_CARGILL_DOW_POLYMERS_LLC_Waiver_of_Domestic_and_Fo.pdf WA_05_022_DOW_CHEMICAL_COMPANY_Waiver_of_domestic_and_Foreig.pdf WA_03_029_CARGILL_DOW_LLC_Waiver_of_Domestic_and_Foreign_Pat.pdf

  16. Leon Baker

    Broader source: Energy.gov [DOE]

    Leon is a senior radiation protection technician with Spectra Tech Contracting Services. His previous experience includes serving as a logistics coordinator with DOW Chemical and a health...

  17. FOIA Cases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1980 and concerned a meeting regarding the United States' oil supply agreement with Israel. August 19, 2013 FIA-13-0054 - In the Matter of Dow Jones & Company On August 19,...

  18. Advance Patent Waiver W(A)2008-030

    Office of Energy Efficiency and Renewable Energy (EERE)

    This is a request by DOW CORNING CORPORATION for a DOE waiver of domestic and foreign patent rights under agreement DE-FC36-OBG01B02B

  19. This Week In Petroleum Summary Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    target weighting of Brent from 15.9 percent in 2011 to 22.3 percent in 2013, while dropping WTI from 32.6 to 24.7 percent. Similarly, the Dow Jones-UBS Commodity Index (DJUBS),...

  20. Interested Parties - Myriant | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    06-09-10_Myriant.pdf More Documents & Publications Interested Parties - Dow Chemical Interested Parties - XtremePower Interested Parties - ARPA-E / National Association of Manufacturers

  1. Inhibiting Individual Notch Receptors Improves Treatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    notably with immune-based diseases and regenerative medicine. Research conducted by C. Cain-Hom, C.A. Callahan, Y. Chen, L. Choy, G.J. Dow, D. Finkle, T.J. Hagenbeek, S.G....

  2. Ground Source Heat Pump System Data Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Industrial, ClimateMaster, Dow Chemical, Gate Precast, and the Congress for the New Urbanism 15 | Building Technologies Office eere.energy.gov Next Steps and Future Plans Next ...

  3. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over several years, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana.

  4. This Week In Petroleum Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    Release on July 17, 2002) Are Stocks Going Up or Down? No, were not talking about the stock market (e.g., the Dow, NASDAQ, or the S&P). Theres no question as to which way...

  5. Integrated Projects - Non-DOE Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Validation » Integrated Projects » Integrated Projects - Non-DOE Projects Integrated Projects - Non-DOE Projects In addition to the integrated technology validation projects sponsored by DOE, universities, along with state and local government entities throughout the world are partnering with industry to demonstrate integrated hydrogen and fuel cell technologies in real-world applications. GM/DOW Chemical Partnership The first General Motors fuel cell trailer is in place at the Dow

  6. Alejandro Briseño: Department of Polymer Science and Engineering,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University of Massachusetts Amherst | Center for Energy Efficient Materials Alejandro Briseño: Department of Polymer Science and Engineering, University of Massachusetts Amherst Feb 20, 2014 | 4:00 PM - 5:00 PM Alejandro Briseño Department of Polymer Science and Engineering University of Massachusetts Amherst Dow logo Professor Briseño has been selected as the 2014 UC Santa Barbara Dow Distinguished Lecturer Crystal Chemistry, Molecular Order, and Charge Transport at Organic Semiconductor

  7. Visiting Speaker Program - October 30, 2008. | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    30, 2008. Visiting Speaker Program - October 30, 2008. Dr. Susan Butts is Senior Director of External Science and Technology Programs at The Dow Chemical Company. In this capacity she is responsible for Dow's contract research activities with US and European government agencies and sponsored research programs at over 100 universities, institutes, and national laboratories worldwide. She has also held the role of Global Staffing Leader in which she managed recruiting and hiring activities for the

  8. Cladding Attachment Over Thick Exterior Insulating Sheathing (Fact Sheet), Building America Case Study: Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cladding Attachment Over Thick Exterior Insulating Sheathing Project InformatIon: Project name: Cladding Attachment Over Thick Exterior Insulating Sheathing Partners: Building Science Corporation www.buildingscience.com The Dow Chemical Company www.dow.com James Hardie Building Products www.jameshardie.com Building component: Building envelope component application: New and/or retrofit; Single and/or multifamily Year research conducted: 2011 through 2012 applicable climate Zone(s): All The

  9. Millie Dresselhaus: Department of Physics and Engineering, Massachusetts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute of Technology | Center for Energy Efficient Materials Millie Dresselhaus: Department of Physics and Engineering, Massachusetts Institute of Technology Nov 20, 2013 | 4:00 PM - 5:00 PM Millie Dresselhaus Professor, Department of Physics and Engineering, Massachusetts Institute of Technology Dow logo Professor Dresselhaus has been selected as the 2013 UC Santa Barbara Dow Distinguished Lecturer Personal Perspectives on Advancing Energy Sustainability November 20, 2013 | 4:00pm | ESB

  10. Building America Case Study: Initial and Long Term Movement of Cladding Installed Over Exterior Rigid Insulation (Fact Sheet), Technology Solutions for New and Existing Homes, Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Initial and Long-Term Movement of Cladding Installed Over Exterior Rigid Insulation PROJECT INFORMATION Project Name: Initial and Long-Term Movement of Cladding Installed Over Exterior Rigid Insulation Partners: Building Science Corporation, buildingscience.com The Dow Chemical Company, dow.com James Hardie Building Products, jameshardie.com Building Component: Building envelope component Application: New and/or retrofit; single and/or multi-family Year Research Conducted: 2011 through 2013

  11. Building America Case Study: Measure Guideline: Guidance on Taped Insulating Sheathing Drainage Planes (Fact Sheet), Technology Solutions for New and Existing Homes, Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Measure Guideline: Guidance on Taped Insulating Sheathing Drainage Planes PROJECT INFORMATION Construction: New and retrofit Type: Residential Climate Zones: All TEAM MEMBERS Building Science Corporation, buildingscience.com BASF, basf.com The Dow Chemical Company, dow.com Dupont, dupont.com CODE COMPLIANCE International Code Council Evaluation Service AC71-Acceptance Criteria for Foam Plastic Sheathing Panels Used as Water-Resistive Barriers The energy effciency-based fnancial benefts of adding

  12. Stud Walls With Continuous Exterior Insulation for Factory Built Housing: New York, New York (Fact Sheet), NREL (National Renewable Energy Laboratory), Building America Case Study Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Energy Savers [EERE]

    Stud Walls With Continuous Exterior Insulation for Factory Built Housing New York, New York PROJECT INFORMATION Project Name: Advanced Envelope Research for Factory Built Housing Location: New York, NY Partners: Manufactured and modular home building companies The Levy Partnership, Inc., www.levypartnership.com SBRA, www.research-alliance.org AFM Corp., www.afmcorporation.com BASF, www.basf.com Dow Corp., www.dow.com Johns Manville, www.jm.com Owens Corning, www.owenscorning.com CertainTeed,

  13. Chicago Operations Office 9800 South Cass Avenue

    Office of Legacy Management (LM)

    Office 9800 South Cass Avenue Argonne,, Illinois 60439 James L. Liver-man, Acting Assistant Secretary for Environment, HQ THE DOW CHEMICAL COMPANY On December 8, 1977, Edward J. Jascewsky, Department of Energy (DOE), and Walter Smith, Argonne National Laboratory (ANL), visited The Dow Chemical Company, Walnut'Creek, California. The purpose of the visit was to discuss the past operations at these facilities under Atomic Energy Commission (AEC), Contract AT (40-l)-GEN 236, which involved process

  14. DOE - Office of Legacy Management -- Madison_FUSRAP

    Office of Legacy Management (LM)

    Illinois Madison, Illinois, Site FUSRAP Site Madison Map Background-The Madison Site was remediated under the Formerly Utilized Sites Remedial Action Program (FUSRAP). FUSRAP was established in 1974 to remediate sites where radioactive contamination remained from Manhattan Project and early U.S. Atomic Energy Commission (AEC) operations. History-During the late 1950s and early 1960s, the Dow Metal Products Division of Dow Chemical Company machined and shaped uranium metal and straightened

  15. FORMERLY UTILIZED SITES REMEDIAL ACTION PROGRAM ELIMINATION REPORT

    Office of Legacy Management (LM)

    DOW CHEMICAL COMPANY WALNUT CREEK, CALIFORNIA Department of Energy Office of Nuclear Energy Office of Remedial Action and Waste Technology Division of Facility and Site Decommissioning Projects . CONTENTS INTRODUCTION BACKGROUND Site Function Site Description Radiological History and Status ELIMINATION ANALYSIS REFERENCES Page 1 4 iii _ .._ __.- -.-- ELIMINATION REPORT DOW CHEMICAL COMPANY WALNUT CREEK, CALIFORNIA INTRODUCTION The Department of Energy (DOE), Office of Nuclear Energy, Office of

  16. Scale-up of Novel Low-Cost Carbon Fibers Leading to High-Volume Commercial Launch

    SciTech Connect (OSTI)

    Spalding, Mark A

    2014-08-27

    The project started in September, 2012 with the goal of scaling up from the existing laboratory scale process for producing carbon fiber (CF) from polyolefin (PO) based precursor fiber using a Dow proprietary sulfonation-desulfonation stabilization process. The award was used to develop a process that was capable of producing market development quantities of CF from PO precursor fiber at a rate of 4 kg/h of CF. The CF would target properties that met or exceeded the Department of Energy (DOE) Vehicles Technology [1] standard; i.e., 172 GPa modulus and 1.72 GPa strength at greater than or equal to 1% strain. The Dow proprietary process was capable of meeting and exceeding these targets properties. Project DE-EE0005760 resulted from a Collaborative Research and Development Agreement (CRADA) between Dow and Oak Ridge National Laboratory (ORNL) with support from the Michigan Economic Development Corporation (MEDC) and DOE. In the first budget period, the main goal was to design a sulfonation-desulfonation market development plant capable of stabilizing PO precursor fiber at a rate of 5 kg/h using a sulfonation solution. The detailed design, location, and cost estimate were determined as scheduled in the Project Management Plan (PMP). In parallel with this DOE award project was a fundamentals and economic evaluation funded by The Dow Chemical Company (Dow). The goal of the Dow sponsored project was to finalize the mass balances, energy balances, and levelized cost to produce CF using the Dow process. A Go-No-Go decision was scheduled in June, 2013 based on the findings of the DOE sponsored scale up project and the Dow sponsored project. In June, 2013, Dow made the No-Go decision to halt and abandon the Dow proprietary sulfonation-desulfonation process for stabilizing PO precursor fibers for the manufacturing of CF. This No-Go decision was identified in the original proposal and at the start of this project, and the decision was made as scheduled. The decision was based on the high levelized economic cost of the process relative to the manufacture of CF from polyacrylonitrile (PAN) precursor fibers. The capital required to sulfonate the fibers adds a significant cost to the process due to the need for investment in a sulfuric acid recovery plant. This high additional capital over the capital for a PAN based CF plant, reduces the levelized economic cost to slightly advantaged over PAN based CF. The sulfonation-desulfonation stabilization route failed to meet the Dow’s return on investment criterion and the cost advantage target set forth for the DOE project. The DOE and Dow decided to halt spending on the project until a new PO fiber stabilization process could be identified that met the DOE physical properties standard and the levelized economic cost constraints of Dow. When the new technology was developed, then award DE-EE0005760 would be re-started with the same goals of the development of a market development plant capable of producing CF at 4 kg/h with the properties that met or exceed those set forth by the Department of Energy Vehicles Technology standard. Progress on the development of the new process has been slow and thus has delayed the scale up project. Dow’s efforts to date have not progressed to the point of demonstrating a commercially-viable process for production of low cost CF from PO precursors for Dow’s rigorous economic constraints. After extensive discussions within Dow and consultation with DOE’s Advanced Manufacturing Office (AMO) Headquarters and Golden Field Office teams, Dow has decided to proceed with the formal recommendation to terminate subject project. DOE’s AMO Headquarters and Golden Field Office teams agreed with the termination of the project.

  17. Method and apparatus for setting precise nozzle/belt and nozzle/edge dam block gaps

    DOE Patents [OSTI]

    Carmichael, Robert J. (Colchester, VT); Dykes, Charles D. (Milton, VT); Woodrow, Ronald (Saltsburgh, PA)

    1989-05-16

    A pair of guide pins are mounted on sideplate extensions of the caster and mating roller pairs are mounted on the nozzle assembly. The nozzle is advanced toward the caster so that the roller pairs engage the guide pins. Both guide pins are remotely adjustable in the vertical direction by hydraulic cylinders acting through eccentrics. This moves the nozzle vertically. The guide pin on the inboard side of the caster is similarly horizontally adjustable. The nozzle roller pair which engage the inboard guide pin are flanged so that the nozzle moves horizontally with the inboard guide pin.

  18. Microsoft Word - FINAL Follow up L2R_PO_Decision_BlockRequest...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    POWER SERVICES April 22, 2013 In reply refer to: PS-6 To Regional Customers, Stakeholders, and Other Interested Parties: On March 7, 2013, the Bonneville Power Administration (BPA)...

  19. Communication: Relativistic Fock-space coupled cluster study of small building blocks of larger uranium complexes

    SciTech Connect (OSTI)

    Tecmer, Pawe? Visscher, Lucas; Severo Pereira Gomes, Andr; Knecht, Stefan

    2014-07-28

    We present a study of the electronic structure of the [UO{sub 2}]{sup +}, [UO{sub 2}]{sup 2} {sup +}, [UO{sub 2}]{sup 3} {sup +}, NUO, [NUO]{sup +}, [NUO]{sup 2} {sup +}, [NUN]{sup ?}, NUN, and [NUN]{sup +} molecules with the intermediate Hamiltonian Fock-space coupled cluster method. The accuracy of mean-field approaches based on the eXact-2-Component Hamiltonian to incorporate spinorbit coupling and Gaunt interactions are compared to results obtained with the DiracCoulomb Hamiltonian. Furthermore, we assess the reliability of calculations employing approximate density functionals in describing electronic spectra and quantities useful in rationalizing Uranium (VI) species reactivity (hardness, electronegativity, and electrophilicity)

  20. Policy Building Blocks: Helping Policymakers Determine Policy Staging for the Development of Distributed PV Markets: Preprint

    SciTech Connect (OSTI)

    Doris, E.

    2012-04-01

    There is a growing body of qualitative and a limited body of quantitative literature supporting the common assertion that policy drives development of clean energy resources. Recent work in this area indicates that the impact of policy depends on policy type, length of time in place, and economic and social contexts of implementation. This work aims to inform policymakers about the impact of different policy types and to assist in the staging of those policies to maximize individual policy effectiveness and development of the market. To do so, this paper provides a framework for policy development to support the market for distributed photovoltaic systems. Next steps include mathematical validation of the framework and development of specific policy pathways given state economic and resource contexts.

  1. A Block-Structured KIVA Program for Engines with Vertical or Canted Valves

    SciTech Connect (OSTI)

    2007-04-16

    KIVA-4 is the latest version of the series of KIVA codes. While KIVA-4 maintains the full generality of KIVA-3V, it adds the capability of computing with unstructured grids. Unstructured grids can be generated more easily than structured grids for complex geometries. The unstructured grids can be composed of a variety of elements including hexahedra, prisms, pyramids, and tetrahedra. However the numerical accuracy is less when the grid is not composed of hexahedra. KIVA-4 was developed to work with the many geometries accommodated with KIVA-3V which include 2D axisymmetric, 2D planar, 3D axisymmetric sector geometries, and full 3D geometries. KIVA-4 also features a multicomponent fuel evaporation algorithm. Many of the numerical algorithms in KIVA-3V do generalize nicely to unstructured meshes. However fundamental changes were needed in the solution of the pressure equation and the fluxing of momentum. In addition, KIVA-4 loops over cell faces to compute diffusion terms. More details can be found in Torres, D.J. and Trujillo, M.F., KIVA-4: An unstructured ALE code for compressible gas flow with sprays, Journal of Computational Physics, 2006, vol. 219, pp. 943-975. PACKAGE TESTED USING LINUX OPERATING SYSTEM. MAY BE MODIFIED TO RUN USING UNIX OR WINDOWS.

  2. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conducted by: C. Wang and A. Hexemer (ALS), D.H. Lee (Dankook University, Korea), M.I. Kim (University of California, Berkeley), W. Zhao and T.P. Russell (University of...

  3. Determination of Importance Evaluation for the ESF Enhanced Charcterization of the Repository Block Cross Drift

    SciTech Connect (OSTI)

    S. Goodin

    2002-01-09

    The objective of this DIE is to determine whether the ECRB-Cross-Drift-related activities, as identified in Section 6.0, could potentially impact (1) Yucca Mountain Site Characterization Project (YMP) testing or (2) the waste isolation capabilities of a potential repository at the Yucca Mountain site. Any controls necessary to limit such potential impacts are also identified herein.

  4. How are the energy waves blocked on the way from hot to cold?

    SciTech Connect (OSTI)

    Bai, Xianming; He, Lingfeng; Khafizov, Marat; Yu, Jianguo; Chernatynskiy, Aleksandr

    2013-07-18

    Representing the Center for Materials Science of Nuclear Fuel (CMSNF), this document is one of the entries in the Ten Hundred and One Word Challenge. As part of the challenge, the 46 Energy Frontier Research Centers were invited to represent their science in images, cartoons, photos, words and original paintings, but any descriptions or words could only use the 1000 most commonly used words in the English language, with the addition of one word important to each of the EFRCs and the mission of DOE energy. The mission of CMSNF to develop an experimentally validated multi-scale computational capability for the predictive understanding of the impact of microstructure on thermal transport in nuclear fuel under irradiation, with ultimate application to UO2 as a model system

  5. Energy Efficiency and Conservation Block Grant (EECBG)- Better Buildings Neighborhood Program Final Report

    SciTech Connect (OSTI)

    Brown, Donisha; Harris, Barbara; Blue, Cynthia; Gaskins, Charla

    2014-09-16

    The original BetterBuildings for Greensboro grant program included an outreach campaign to inform 100% of the Greensboro community about the benefits of reducing energy use; a plan to reduce energy consumption in at least 34% of the homes and 10% of the other buildings in the east Greensboro target area; and a plan to create and retain jobs in the energy conservation industry. Under the original program structure the City of Greensboro planned to partner with local and regional lenders to create a diversified portfolio of loan products to meet the needs of various income levels and building types. All participants would participate in the loan programs as a method of meeting the programs 5 to1 private capital match/leverage requirements. In June 2011 the program was restructured to include partnerships with large commercial and multifamily projects, with these partners providing the greater portion of the required match/leverage. The geographic focus was revised to include reducing energy consumption across the entire City of Greensboro, targeting neighborhoods with high concentrations of low-moderate income households and aged housing stock. The community outreach component used a neighborhood-based approach to train community residents and volunteers to conduct door-to-door neighborhood sweeps; delivered high quality information on available program resources; helped residents to evaluate alternative energy efficiency measures and alternative financing sources; assisted with contractor selections and monitoring/evaluation of work; coordinated activities with BetterBuildings program partners; and collected data required by the Department of Energy. Additionally, HERO (Home Energy Response Officers) delivered intro packages (energy efficiency information and products) to thousands of households at the initial point of contact. A pilot program (Early Adopters) was offered from March 1, 2011 through June 30, 2011. The Early Adopters program was designed to offer immediate assistance to property owners ready and able to make their homes more energy efficient, by offering a rebate on their energy assessment and on the cost of upgrades installed. Eligible energy efficient upgrades were inclusive of basic level insulating and weather-stripping, HVAC system and water heater upgrades, to whole home upgrades that include the replacement of windows, doors and appliances. Renewable energy systems such as solar hot water systems were also eligible for the rebate program.

  6. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-004A

    Broader source: Energy.gov [DOE]

    REVISION: THIS GUIDANCE HAS BEEN AMENDED FROM THE DECEMBER 17, 2009. THE CHANGE IN THIS AMENDED GUIDANCE, NOTED IN ITALIC TYPE, IS RELATED TO THE REQUIREMENT TO PROVIDE A WAGE DETERMINATION TO CONTRACTORS AND SUBCONTRACTORS.

  7. Measurements of stress fields near a grain boundary: Exploring blocked arrays of dislocations in 3D

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Y.; Collins, D. M.; Tarleton, E.; Hofmann, F.; Tischler, J.; Liu, W.; Xu, R.; Wilkinson, A. J.; Britton, T. B.

    2015-06-24

    The interaction between dislocation pile-ups and grain boundaries gives rise to heterogeneous stress distributions when a structural metal is subjected to mechanical loading. Such stress heterogeneity leads to preferential sites for damage nucleation and therefore is intrinsically linked to the strength and ductility of polycrystalline metals. To date the majority of conclusions have been drawn from 2D experimental investigations at the sample surface, allowing only incomplete observations. Our purpose here is to significantly advance the understanding of such problems by providing quantitative measurements of the effects of dislocation pile up and grain boundary interactions in 3D. This is accomplished throughmore »the application of differential aperture X-ray Laue micro-diffraction (DAXM) and high angular resolution electron backscatter diffraction (HR-EBSD) techniques. Our analysis demonstrates a similar strain characterization capability between DAXM and HR-EBSD and the variation of stress intensity in 3D reveals that different parts of the same grain boundary may have different strengths in resisting slip transfer, likely due to the local grain boundary curvature.« less

  8. A Block-Structured KIVA Program for Engines with Vertical or Canted Valves

    Energy Science and Technology Software Center (OSTI)

    2007-04-16

    KIVA-4 is the latest version of the series of KIVA codes. While KIVA-4 maintains the full generality of KIVA-3V, it adds the capability of computing with unstructured grids. Unstructured grids can be generated more easily than structured grids for complex geometries. The unstructured grids can be composed of a variety of elements including hexahedra, prisms, pyramids, and tetrahedra. However the numerical accuracy is less when the grid is not composed of hexahedra. KIVA-4 was developedmore » to work with the many geometries accommodated with KIVA-3V which include 2D axisymmetric, 2D planar, 3D axisymmetric sector geometries, and full 3D geometries. KIVA-4 also features a multicomponent fuel evaporation algorithm. Many of the numerical algorithms in KIVA-3V do generalize nicely to unstructured meshes. However fundamental changes were needed in the solution of the pressure equation and the fluxing of momentum. In addition, KIVA-4 loops over cell faces to compute diffusion terms. More details can be found in Torres, D.J. and Trujillo, M.F., KIVA-4: An unstructured ALE code for compressible gas flow with sprays, Journal of Computational Physics, 2006, vol. 219, pp. 943-975. PACKAGE TESTED USING LINUX OPERATING SYSTEM. MAY BE MODIFIED TO RUN USING UNIX OR WINDOWS.« less

  9. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    array of morphologies and properties that make them candidates for applications in biomaterials, fuel cells and batteries, magnetic storage, and more. So far, so good, but the...

  10. The appearance of plasticity on the blocks surfaces in geological media

    SciTech Connect (OSTI)

    Sibiryakov, Boris P.

    2014-11-14

    In present the elasticity and plasticity are absolutely different models of solids, which are not relate to each other. The experimental observations show, that the plasticity arrives and localizes on the surfaces of structures, which contain solid samples. The transition in special state, where a small part of solid volume is in plastic state, while the main part of volume is in elastic state not be describe by classical continuum Cauchy and Poisson model. This classical model requires two alternative states. Either is elastic state in the all volume or plastic one for all elementary volume too. However, the structured model of space gives us a possibility to describe this complicate state. In this paper shown that the sliding surfaces divided to each other by distances equal to the average sizes of microstructures, in the contrary of classical plasticity, where they have not characteristic distance. The energy of plastic transition is very small, because the main part of volume is elastic body. This description means the smooth transition from elasticity to plasticity in vicinity of sliding surfaces.

  11. The effect of block copolymer on the phase behavior of a polymer blend

    SciTech Connect (OSTI)

    Sung, L.; Jackson, C.L.; Hess, D.

    1995-12-31

    The effect of an interfacial modifier on the phase behavior of a blend has been investigated using time-resolved fight scattering and small angle neutron scattering techniques. A low molecular weight binary blend of deuterated polystyrene/polybutadiene (PSD/PB) with PSD-PB diblock copolymer as the added interfacial modifier was studied. We observed that the critical temperature of the blend decreases with increasing copolymer content and the kinetics of the phase separation (via spinodal decomposition) slows down in the presence of the copolymer. The transition from early to late stage spinodal decomposition in a near critical mixture of the binary blend was analyzed and compared to available theories. In addition, transmission electron microscopy and optical microscopy studies were used to examine the morphology of the system under various temperature quench conditions.

  12. New Shielding Is Designed to Put the Block on Neutrons | Jefferson...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transmit the data from the detectors. Over time, the radiation generated in these experiments can damage this equipment. "In modern electronics, the structures in the memory...

  13. Benefits to BPA will equal or exceed costs for the Extended Block...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    does not sell to them - all of BPA's surplus sales realize increased revenues because the mean value of prices for electricity in Western power markets are higher than they would...

  14. Nanocrystal quantum dots: building blocks for tunable optical amplifiers and lasers

    SciTech Connect (OSTI)

    Mikhailovsky, A. A.; Malko, A. V.; Klimov, V. I.; Leatherdale, C. A.; Eisler, H-J.; Bawendi, M.; Hollingsworth, J. A.

    2001-01-01

    We study optical processes relevant to optical amplification and lasing in CdSe nanocrystal quantum dots (NQD). NQDs are freestanding nanoparticles prepared using solution-based organometallic reactions originally developed for the Cd chalcogenides, CdS, CdSe and CdTe [J. Am. Chem. Soc. 115, 8706 (1993)]. We investigate NQDs with diameters ranging from 2 to 8 nm. Due to strong quantum confinement, they exhibit size-dependent spectral tunability over an energy range as wide as several hundred meV. We observe a strong effect of the matrix/solvent on optical gain properties of CdSe NQDs. In most of the commonly used solvents (such as hexane and toluene), gain is suppressed due to strong photoinduced absorption associated with carriers trapped at solvent-related interface states. In contrast, matrix-free close packed NQD films (NQD solids) exhibit large optical gain with a magnitude that is sufficiently high for the optical gain to successfully compete with multiparticle Auger recombination [Science 287, 10117 (2000)]. These films exhibit narrowband stimulated emission at both cryogenic and room temperature, and the emission color is tunable with dot size [Science 290, 314 (2000)]. Moreover, the NQD films can be incorporated into microcavities of different geometries (micro-spheres, wires, tubes) that produce lasing in whispering gallery modes. The facile preparation, chemical flexibility and wide-range spectral tunability due to strong quantum confinement are the key advantages that should motivate research into NQD applications in optical amplifiers and lasers.

  15. SF-30 Block 14 (Continued) DE-AC27-08 RV14800, Modification 074

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... CLIN 3 Sub-CLIN 3.1 9,705 4,009 13,714 wrP Support Sub-CLIN 3.2 3,356 3,420 6,776 ... Protection Program, ISO International Organization for Standard ization 14000, ...

  16. Energy Efficiency and Conservation Block Grant Financing Program Guidance Grantee Letter

    Broader source: Energy.gov [DOE]

    Clarifies DOEs ongoing role in the monitoring, reporting, and oversight of Energy Efficiency and Conservation Grant- funded financing programs.

  17. Synthetic peptides that cause F-actin bundling and block actin depolymerization

    DOE Patents [OSTI]

    Sederoff, Heike; Huber, Steven C; Larabell, Carolyn A

    2011-10-18

    Synthetic peptides derived from sucrose synthase, and having homology to actin and actin-related proteins, sharing a common motif, useful for causing acting bundling and preventing actin depolymerization. Peptides exhibiting the common motif are described, as well as specific synthetic peptides which caused bundled actin and inhibit actin depolymerization. These peptides can be useful for treating a subject suffering from a disease characterized by cells having neoplastic growth, for anti-cancer therapeutics, delivered to subjects solely, or concomitantly or sequentially with other known cancer therapeutics. These peptides can also be used for stabilizing microfilaments in living cells and inhibiting growth of cells.

  18. INFOGRAPHIC: How Do We Know Iran's Paths to a Nuclear Bomb are Blocked?

    Broader source: Energy.gov [DOE]

    Learn about the monitoring and verification measures the IAEA uses to ensure Iran complies with the Iran Deal.

  19. Energy Efficiency and Conservation Block Grant (EECBG): Better Buildings Neighborhood Program Final Report

    SciTech Connect (OSTI)

    Donnelly, Kat A.

    2014-01-10

    The Neighbor to Neighbor Energy Challenge (N2N) brought together a consortium of 14 leading clean energy rural, suburban, and low income communities throughout Connecticut. N2N was awarded $4.2 million from the U.S. Department of Energy (DOE) competitive BetterBuildings Neighborhood Program on August 10, 2010 to run a two-year pilot program (plus one year of transition and evaluation) (Award No. EMCBC- 00969-10). N2N tested innovative program models and hypotheses for improving Connecticut’s existing residential energy efficiency programs that are overseen by the ratepayer fund board and administered by CT utilities. N2N’s original goal was to engage 10 percent of households in participating communities to reduce their energy usage by 20 percent through energy upgrades and clean energy measures. N2N planned for customers to complete more comprehensive whole-home energy efficiency and clean energy measures and to achieve broader penetration than existing utility-administered regulated programs. Since this was an ARRA award, we report the following figures on job creation in Table 1. Since N2N is not continuing in its current form, we do not provide figures on job retention. Table 1 N2N Job Creation by Quarter Jobs Created 2010 Q4 6.65 2011 Q1 7.13 2011 Q2 4.98 2011 Q3 9.66 2011 Q4 5.43 2012 Q1 11.11 2012 Q2 6.85 2012 Q3 6.29 2012 Q4 6.77 2013 Q1 5.57 2013 Q2 8.35 2013 Q3 6.52 Total 85.31 The N2N team encountered several gaps in the existing efficiency program performance that hindered meeting N2N’s and DOE’s short-term program goals, as well as the State of Connecticut’s long-term energy, efficiency, and carbon reduction goals. However, despite the slow program start, N2N found evidence of increasing upgrade uptake rates over time, due to delayed customer action of one to two years from N2N introduction to completion of deeper household upgrades. Two main social/behavioral principles have contributed to driving deeper upgrades in CT: 1. Word of mouth, where people share their experience with others, which leads to others to take action; and 2. Self-herding, where people follow past behavior, which leads to deeper and deeper actions within individual households.

  20. Equipment for nondestructive evaluation of the strength of the Fort St. Vrain core-support blocks

    SciTech Connect (OSTI)

    Morgan, W.C.; Prince, J.M.; Posakony, G.J.

    1982-09-01

    A novel sweep-frequency eddy current instrument has been constructed for measuring density-depth profiles in oxidized graphite. Development work on additional parts of the instrumentation package, that was to be tested in the Fort St. Vrain High Temperature Gas-Cooled Reactor, has been temporarily halted. This report documents the work which has been accomplished to date and presents the current status of the equipment development effort.

  1. Coeur dAlene Tribe Energy Efficiency and Conservation Block Grant Project, Plummer, Idaho

    Office of Environmental Management (EM)

    Stacey J. Fox, Environmental Planner, Coeur d'Alene Tribe Natural Resource Department, Environmental Programs Office, Plummer, Idaho Presentation Outline - Coeur d'Alene Tribe Background - History of the Tribal Natural Resource Department - Energy Work Prior to the EECBG - EECBG Project Objectives - Progress-to-Date - Lessons Learned - Examples of EECBG Energy Audit Report Findings - New Energy Efficiency Feasibility Study Objectives - Contact Information Coeur d'Alene Tribe Background - The

  2. Hydrothermal synthesis and electrochemical performance of NiO microspheres with different nanoscale building blocks

    SciTech Connect (OSTI)

    Wang Ling; Hao Yanjing; Zhao Yan; Lai Qiongyu; Xu Xiaoyun

    2010-11-15

    NiO microspheres were successfully obtained by calcining the Ni(OH){sub 2} precursor, which were synthesized via the hydrothermal reaction of nickel chloride, glucose and ammonia. The products were characterized by TGA, XRD and SEM. The influences of glucose and reaction temperature on the morphologies of NiO samples were investigated. Moreover, the possible growth mechanism for the spherical morphology was proposed. The charge/discharge test showed that the as-prepared NiO microspheres composed of nanoparticles can serve as an ideal electrode material for supercapacitor due to the spherical hollow structure. -- Graphical Abstract: Fig. 5 is the SEM image of NiO that was prepared in the different hydrothermal reaction temperatures. It showed that reaction temperature played a crucial role for the morphology of products.

  3. Block 14 entitled, Description of Amendment/Modification is continued as follows:

    National Nuclear Security Administration (NNSA)

    CONTRACT ID CODE PAGE OF PAGES 1 6 2. AMENDMENT/MODIFICATION NO. 3. EFFECTIVE DATE 4. REQUISITION/PURCHASE REQ. NO. 5. PROJECT NO. (If applicable) 001 1/26/2015 6. ISSUED BY CODE MOSD 7. ADMINISTERED BY (If other than Item 6) Code U.S. DEPARTMENT OF ENERGY NATIONAL NUCLEAR SECURITY ADMINISTRATION M&O CONTRACTING (NA-APM-131) PO BOX 5400, ALBUQUERQUE, NM 87185-5400 8. NAME AND ADDRESS OF CONTRACTOR (No. street, county, State and ZIP Code) (X) 9.A. AMENDMENT OF SOLICITATION NO. DE-SOL-0007749

  4. Research & Development of Materials/Processing Methods for Continuous Fiber Ceramic Composites (CFCC) Phase 2 Final Report.

    SciTech Connect (OSTI)

    Szweda, A.

    2001-01-01

    The Department of Energy's Continuous Fiber Ceramic Composites (CFCC) Initiative that begun in 1992 has led the way for Industry, Academia, and Government to carry out a 10 year R&D plan to develop CFCCs for these industrial applications. In Phase II of this program, Dow Corning has led a team of OEM's, composite fabricators, and Government Laboratories to develop polymer derived CFCC materials and processes for selected industrial applications. During this phase, Dow Corning carried extensive process development and representative component demonstration activities on gas turbine components, chemical pump components and heat treatment furnace components.

  5. Advance Patent Waiver W(A)2011-006 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    06 Advance Patent Waiver W(A)2011-006 This document waives certain patent rights the Department of Energy (DOE) has to inventions conceived or first actually reduced to practice by DOW CORNING CORPORATION under agreement DE-EE0003915, as the DOE has determined that granting such a waiver best serves the interests of the United States and the general public. PDF icon W(A)2011-006 More Documents & Publications WA_05_022_DOW_CHEMICAL_COMPANY_Waiver_of_domestic_and_Foreig.pdf

  6. Application of Spray Foam Insulation Under Plywood and OSB Roof Sheathing (Fact Sheet), Building America Case Study: Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application of Spray Foam Insulation Under Plywood and OSB Roof Sheathing PROJECT aPPliCaTiON Construction: Existing homes with unvented cathedralized roofs. Type: Residential Climate Zones: All TEam mEmbERs Building Science Corporation www.buildingscience.com BASF www.basf.com Dow Chemical Company www.dow.com Honeywell http://honeywell.com Icynene www.icynene.com COdE COmPliaNCE 2012 International Code Council, International Residential Code Spray polyurethane foams (SPFs) have advantages over

  7. NREL: Biomass Research - Video Text

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Fermentation Laboratory Video (Text Version) This is the text version for the NREL Fermentation Laboratory video. The video opens with a collage of researchers. Music plays in the background. The video shows cars/traffic on a highway. Nancy Dowe: "We need a different fuel." (Voiceover) The cars and trucks that clog our roads... Nancy Dowe: "We need to get away from oil." The video shows a fuel nozzle in a car's gas tank then shows a fuel pump sale price window.

  8. Uniter+ States Government

    Office of Legacy Management (LM)

    EFG (07-90) Uniter+ States Government ~L.aQ-i; Department of Energy inemorandum DATE: SEP 2 5 1992 REPLY TO Al-fN OF: EM-421 (W. A. W illiams, 903-8149) SUBJECT: Authorization for Remedial Action at the Former Dow Chemical Company Facility in M a d ison, Illinois TO: L. Price, OR The site of the Former Dow Chemical Company in M a d ison, Illinois, which is currently owned and operated by the Spectrulite Consortium, is designated for inclusion in the Formerly Utilized Sites Remedial Action

  9. C-J

    Office of Legacy Management (LM)

    C-J EH: (07~00) M7iZed- States Government - DATE: OCT 0 8 1992 REPLY TO AlTN OF: EM-421 (W. A. W illiams, 903-8149) SUBJECT: Authorization for Remedial Action at the Former Dow Chemical Company Site in M a d ison, Illinois To' Manager, DOE Oak Ridge F ield O ffice This is to notify you that the former Dow Chemical Company site in M a d ison, Illinois, is designated for remedial action under the Formerly Utilized Sites Remedial Action Program (FUSRAP). This notification does not constitute a

  10. Low-Cost Precursors to Novel Hydrogen Storage Materials

    SciTech Connect (OSTI)

    Suzanne W. Linehan; Arthur A. Chin; Nathan T. Allen; Robert Butterick; Nathan T. Kendall; I. Leo Klawiter; Francis J. Lipiecki; Dean M. Millar; David C. Molzahn; Samuel J. November; Puja Jain; Sara Nadeau; Scott Mancroni

    2010-12-31

    From 2005 to 2010, The Dow Chemical Company (formerly Rohm and Haas Company) was a member of the Department of Energy Center of Excellence on Chemical Hydrogen Storage, which conducted research to identify and develop chemical hydrogen storage materials having the potential to achieve DOE performance targets established for on-board vehicular application. In collaboration with Center co-leads Los Alamos National Laboratory (LANL) and Pacific Northwest National Laboratory (PNNL), and other Center partners, Dow's efforts were directed towards defining and evaluating novel chemistries for producing chemical hydrides and processes for spent fuel regeneration. In Phase 1 of this project, emphasis was placed on sodium borohydride (NaBH{sub 4}), long considered a strong candidate for hydrogen storage because of its high hydrogen storage capacity, well characterized hydrogen release chemistry, safety, and functionality. Various chemical pathways for regenerating NaBH{sub 4} from spent sodium borate solution were investigated, with the objective of meeting the 2010/2015 DOE targets of $2-3/gal gasoline equivalent at the pump ($2-3/kg H{sub 2}) for on-board hydrogen storage systems and an overall 60% energy efficiency. With the September 2007 No-Go decision for NaBH{sub 4} as an on-board hydrogen storage medium, focus was shifted to ammonia borane (AB) for on-board hydrogen storage and delivery. However, NaBH{sub 4} is a key building block to most boron-based fuels, and the ability to produce NaBH{sub 4} in an energy-efficient, cost-effective, and environmentally sound manner is critical to the viability of AB, as well as many leading materials under consideration by the Metal Hydride Center of Excellence. Therefore, in Phase 2, research continued towards identifying and developing a single low-cost NaBH4 synthetic route for cost-efficient AB first fill, and conducting baseline cost estimates for first fill and regenerated AB using a variety of synthetic routes. This project utilized an engineering-guided R&D approach, which involved the rapid down-selection of a large number of options (chemical pathways to NaBH{sub 4}) to a smaller, more manageable number. The research began by conducting an extensive review of the technical and patent literature to identify all possible options. The down-selection was based on evaluation of the options against a set of metrics, and to a large extent occurred before experimentation was initiated. Given the vast amount of literature and patents that has evolved over the years, this approach helped to focus efforts and resources on the options with the highest technical and commercial probability of success. Additionally, a detailed engineering analysis methodology was developed for conducting the cost and energy-efficiency calculations. The methodology utilized a number of inputs and tools (Aspen PEA{trademark}, FCHTool, and H2A). The down-selection of chemical pathways to NaBH{sub 4} identified three options that were subsequently pursued experimentally. Metal reduction of borate was investigated in Dow's laboratories, research on electrochemical routes to NaBH{sub 4} was conducted at Pennsylvania State University, and Idaho National Laboratory researchers examined various carbothermal routes for producing NaBH{sub 4} from borate. The electrochemical and carbothermal studies did not yield sufficiently positive results. However, NaBH{sub 4} was produced in high yields and purities by an aluminum-based metal reduction pathway. Solid-solid reactive milling, slurry milling, and solution-phase approaches to metal reduction were investigated, and while both reactive milling and solution-phase routes point to fully recyclable processes, the scale-up of reactive milling processes to produce NaBH{sub 4} is expected to be difficult. Alternatively, a low-cost solution-phase approach to NaBH{sub 4} has been identified that is based on conventional process unit operations and should be amenable to scale-up. Numerous advances in AB synthesis have been made in recent years to improve AB yields and purities. Process analysis of several leading routes to AB (Purdue's formate-based metathesis route and PNNL's NH{sub 4}BH{sub 4}-based route) indicated the cost to produce first-fill AB to be on the order of $9-10/kg AB, assuming a NaBH{sub 4} cost of $5/kg for a 10,000 metric tons/year sized AB plant. The analysis showed that the dominant cost component for producing first-fill AB is the cost of the NaBH4 raw material. At this AB cost and assuming 2.5 moles hydrogen released per mole of AB, it may be possible to meet DOE's 2010 storage system cost target, but the 2015 target will likely require lower cost AB and demonstrates the importance of having a low-cost route to NaBH{sub 4}. Substantial progress has also been made to define feasible pathways for the regeneration of spent ammonia borane fuel.

  11. Bainbridge Energy Challenge. Energy efficiency and conservation block grant (EECBG) - Better buildings neighborhood program. Final Technical Report

    SciTech Connect (OSTI)

    Kraus, Yvonne X.

    2014-02-14

    RePower Bainbridge and Bremerton (RePower) is a residential energy-efficiency and conservation program designed to foster a sustainable, clean, and renewable energy economy. The program was a 3.5 year effort in the cities of Bainbridge Island and Bremerton, Washington, to conserve and reduce energy use, establish a trained home performance trade ally network, and create local jobs. RePower was funded through a $4.8 million grant from the US Department of Energy, Better Buildings Program. The grant’s performance period was August 1, 2010 through March 30, 2014.

  12. Bay-annulated indigo (BAI) as an excellent electron accepting building block for high performance organic semiconductors

    DOE Patents [OSTI]

    Liu, Yi; He, Bo; Pun, Andrew

    2015-11-24

    A novel electron acceptor based on bay-annulated indigo (BAI) was synthesized and used for the preparation of a series of high performance donor-acceptor small molecules and polymers. The resulting materials possess low-lying LUMO energy level and small HOMO-LUMO gaps, while their films exhibited high crystallinity upon thermal treatment, commensurate with high field effect mobilities and ambipolar transfer characteristics.

  13. Elimination of hydrogenase post-translational modification blocks H2 production and increases ethanol yield in Clostridium thermocellum

    SciTech Connect (OSTI)

    Biswas, Ranjita; Zheng, Tianyong; Olson, Daniel G.; Lynd, Lee R; Guss, Adam M

    2015-01-01

    The native ability of Clostridium thermocellum to rapidly consume cellulose and produce ethanol makes it a leading candidate for a consolidated bioprocessing (CBP) biofuel production strategy. C. thermocellum also synthesizes lactate, formate, acetate, H2, and amino acids that compete with ethanol production for carbon and electrons. Elimination of H2 production could redirect carbon flux towards ethanol production by making more electrons available for acetyl-CoA reduction to ethanol. C. thermocellum encodes four hydrogenases and rather than delete each individually, we targeted a hydrogenase maturase gene (hydG), involved in converting the three [FeFe] hydrogenase apoenzymes into holoenzymes. Further deletion of the [NiFe] hydrogenase (ech) resulted in a mutant that functionally lacks all four hydrogenases. H2 production in hydG ech was undetectable and ethanol yield increased nearly 2-fold compared to wild type. Interestingly, mutant growth improved upon the addition of acetate, which led to increased expression of genes related to sulfate metabolism, suggesting these mutants may use sulfate as a terminal electron acceptor to balance redox reactions. Genomic analysis of hydG revealed a mutation in adhE, resulting in a strain with both NADH- and NADPH-dependent alcohol dehydrogenase activities. While this same adhE mutation is found in ethanol tolerant C. thermocellum strain E50C, hydG and hydG ech are not more ethanol tolerant than wild type, illustrating the complicated interactions between redox balancing and ethanol tolerance in C. thermocellum. The dramatic increase in ethanol production here suggests that targeting protein post-translational modification is a promising new approach for inactivation of multiple enzymes simultaneously for metabolic engineering.

  14. In-situ Neutron Scattering Determination of 3D Phase-Morphology Correlations in Fullerene Block Copolymer Systems

    SciTech Connect (OSTI)

    Karim, Alamgir; Bucknall, David; Raghavan, Dharmaraj

    2015-02-23

    High efficiency solar energy devices can potentially meet all global energy requirements by efficiently harvesting energy from the solar spectrum. However, for solar technologies to be ubiquitous and meet the global power requirements, innovative and revolutionary approaches to trap solar energy are needed. In this regard, organic photovoltaics (OPVs) have drawn much attention, largely due to the ease with which OPVs can be manufactured at much lower costs compared to conventional inorganic PVs. Currently the most efficient OPV devices (at ~10%) are still below a technologically useful efficiency (~15%). It can be argued that to date most of the development of the OPVs has been driven by their electronic properties, without much consideration or understanding of the structure and morphology of the organic components and in particular how these affect the performance of the solar cell devices. It is only in the last few years that the latter has begun to be addressed. Arguably, without a complete understanding of the effect of morphology and structure on device performance, the theoretical maximum efficiency of these devices is unlikely to ever be realized. A thorough understanding of the structure and morphology of the polymers and how this affects device efficiency is vital to achieve the full potential of OPVs. If OPV devices with 15% efficiency can be achieved, coupled with the predicted low cost of processing, such devices would create an enabling technology, making these types of solar cells significant power generators and thereby reduce the dependency on conventional energy sources. This would fulfill the economic solar energy challenge identified by the NAE in their Grand Challenges of the 21st Century. In this project, we conducted a directed series of experiments to determine morphology-property correlations in bulk heterojunction films by careful control of the OPV structure and morphology. Unlike most research undertaken in the PV arena, this is mostly a fundamental study that does not set out to evaluate new materials or produce devices, but rather we wish to understand from first principles how the molecular structure of polymer-fullerene mixtures determined using neutron scattering (small angle neutron scattering and neutron reflection) affects device characteristics and consequently performance. While this seems a very obvious question to ask, this critical understanding is far from being realized despite the wealth of studies into OPVs and is severely limiting organic PV devices from achieving their theoretical potential. Despite the fundamental nature of proposed work, it is essential to remain technologically relevant and therefore to ensure we address these issues we have developed relationships on the fundamental nature of structure-processing-property paradigm as applied to future need for large area, flexible OPV devices. Nanoscale heterojunction systems consisting of fullerenes dispersed in conjugated polymers are promising materials candidates for achieving high performance organic photovoltaic (OPV) devices. In order to understand the phase behavior in these devices, neutron reflection is used to determine the behavior of model conjugated polymer-fullerene mixtures. Neutron reflection is particularly useful for these types of thin film studies since the fullerene generally have a high scattering contrast with respect to most polymers. We are studying model bulk heterojunction (BHJ) films based on mixtures of poly(3-hexyl thiophene)s (P3HT), a widely used photoconductive polymer, and different fullerenes (C60, PCBM and bis-PCBM). The characterization technique of neutron reflectivity measurements have been used to determine film morphology in a direction normal to the film surfaces. The novelty of the approach over previous studies is that the BHJ layer is sandwiched between a PEDOT/PSS and Al layers in real device configuration. Using this model system, the effect of typical thermal annealing processes on the film development as a function of the polythiophene-fullerene mixtures is measured.

  15. Unit-cell thick BaTiO{sub 3} blocks octahedral tilt propagation across oxide heterointerface

    SciTech Connect (OSTI)

    Kan, Daisuke Aso, Ryotaro; Kurata, Hiroki; Shimakawa, Yuichi

    2014-05-14

    We fabricated SrRuO{sub 3}/BaTiO{sub 3}/GdScO{sub 3} heterostructures in which the BaTiO{sub 3} layer is one unit cell thick by pulsed laser deposition and elucidated how the BaTiO{sub 3} layer influences structural and magneto-transport properties of the SrRuO{sub 3} layer through octahedral connections across the heterointerface. Our X-ray-diffraction-based structural characterizations show that while an epitaxial SrRuO{sub 3} layer grown directly on a GdScO{sub 3} substrate is in the monoclinic phase with RuO{sub 6} octahedral tilts, a one-unit-cell-thick BaTiO{sub 3} layer inserted between SrRuO{sub 3} and GdScO{sub 3} stabilizes the tetragonal SrRuO{sub 3} layer with largely reduced RuO{sub 6} tilts. Our high-angle annular dark-field and annular bright-field scanning transmission electron microscopy observations provide an atomic-level view of the octahedral connections across the heterostructure and reveal that the BaTiO{sub 3} layer only one unit cell thick is thick enough to stabilize the RuO{sub 6}-TiO{sub 6} octahedral connections with negligible in-plane oxygen atomic displacements. This results in no octahedral tilts propagating into the SrRuO{sub 3} layer and leads to the formation of a tetragonal SrRuO{sub 3} layer. The magneto-transport property characterizations also reveal a strong impact of the octahedral connections modified by the inserted BaTiO{sub 3} layer on the spin-orbit interaction of the SrRuO{sub 3} layer. The SrRuO{sub 3} layer on BaTiO{sub 3}/ GdScO{sub 3} has in-plane magnetic anisotropy. This is in contrast to the magnetic anisotropy of the monoclinic SrRuO{sub 3} films on the GdScO{sub 3} substrate, in which the easy axis is ?45 to the film surface normal. Our results demonstrate that the one-unit-cell-thick layer of BaTiO{sub 3} can control and manipulate the interfacial octahedral connection closely linked to the structure-property relationship of heterostructures.

  16. Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays

    DOE Patents [OSTI]

    Loewe, Robert S.; Tomizaki, Kin-ya; Lindsey, Jonathan S.

    2005-07-12

    The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I: wherein m is at least 1; X.sup.1 is a charge separation group, and X.sup.2 through X.sup.m+1 are chromophores. At least one of X.sup.2 through X.sup.m+1 has at least one perylene group coupled thereto.

  17. National Energy Policy Act Guide for State Energy Program and Energy Efficiency and Conservation Block Grant Projects

    Broader source: Energy.gov [DOE]

    U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) guidance for the state projects funded under the State Energy Program regarding the National Energy Policy Act (NEPA).

  18. Development of a Low Cost Insulated Foil Substrate for Cu(InGaSe)2 Photovoltaics

    SciTech Connect (OSTI)

    ERTEN ESER

    2012-01-22

    The project validated the use of stainless steel flexible substrate coated with silicone-based resin dielectric, developed by Dow Corning Corporation, for Cu(InGa)Se2 based photovoltaics. The projects driving force was the high performance of Cu(InGa)Se2 based photovoltaics coupled with potential cost reduction that could be achieved with dielectric coated SS web substrate.

  19. Light-Material Interactions in Energy Conversion - Energy Frontier Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center (LMI-EFRC) Partnerships Partners, collaborators and companies impacted by LMI-EFRC research and technology Alta Devices FOM Institute AMOLF DOW JCAP The Molecular Foundry MRL NERSC NCEM Northrop Grumman Resnick Institute If you are interested in partnering with the LMI-EFRC, email lmi-efrc@caltech.edu.

  20. Laboratory data in support of hydraulically fracturing EGSP OH Well No. 3. Final report

    SciTech Connect (OSTI)

    Ahmed, U.; Swartz, G.C.; Scnatz, J.F.

    1980-12-01

    Geologic and geophysical interpretations of data from the EGSP OH Well No. 3 show that an organically lean shale has a gradual transition with depth to an organically rich shale and that two layers (bound each shale formation. The laboratory test program was designed to understand the containment and productivity of a hydraulic fracture induced in this well to enhance gas production from the shale. The porosity in the formations of interest, including the upper barrier, the lower barrier, and the organic shales, varied from 6 to 10 percent. The porosity of each formation averaged about 8%. Densities and ultrasonic velocities were used to evaluate dynamic moduli. Over the tested intervals moduli consistently increased with depth. This indicates the possibility of upward migration of an induced fracture. Perforations, therefore, should be limited to the lower portion of the pay sand and it is also advisable to use low injection rates. Of the four fracturing fluids tested, the two code-named Dow II and Hal I caused, respectively, the least amount of matrix permeability damage to the organically lean and organically rich shales. However, the damage caused by the other fracturing fluids were not severe enough to cause any significant permanent reduction in well productivity. The fracture conductivity tests under the influence of fracturing fluids indicated that Hal I and Dow I caused, respectively, the least amount of multilayered fracture conductivity damage to the organically lean and organically rich samples. For monolayer fracture conductivities Dow I caused least damage to the organically lean shale. With the exception of Dow III all other fluids showed good results in the monolayer tests for organically rich shales. In the situation where both the lean and the rich shales are to be fractured together, the use of either Hal I or Dow I is indicated.

  1. A Constructible and Durable High-Performance Walls System: Extended Plate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Beam | Department of Energy A Constructible and Durable High-Performance Walls System: Extended Plate and Beam A Constructible and Durable High-Performance Walls System: Extended Plate and Beam Photo courtesy of Home Innovation Research Labs. Photo courtesy of Home Innovation Research Labs. Lead Performer: Home Innovation Research Labs-Upper Marlboro, MD Partners: American Chemistry Council, Dow Building Solutions, Forest Products Laboratory, Builders DOE Total Funding: $256,818 Cost

  2. A New CFD Model for understanding and Managing Diesel Particulate Filter

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regeneration | Department of Energy CFD Model for understanding and Managing Diesel Particulate Filter Regeneration A New CFD Model for understanding and Managing Diesel Particulate Filter Regeneration PDF icon 2004_deer_hou.pdf More Documents & Publications Substrate Studies of an Electrically-Assisted Diesel Particulate Filter Diesel Particulate Filter: A Success for Faurecia Exhaust Systems Vehicle Evaluation of Downsized Dow ACM DPF

  3. Preparing for Project Implementation Assigning Accountability for Each Project, April 14, 2010

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    April 14, 2010 5 - Preparing for Project Implementation Assigning Accountability for Each Project Save Energy Now LEADER Web Conference Project Implementation Seminar Series Save Energy Now LEADER Web Conference Agenda  Seminar Series Overview  Recap Seminar # 4 - "After"  Assigning Accountability for each Project Fred Schoeneborn - ORNL team Joe Almaguer - DOW  Questions/Future Seminars 2 Save Energy Now LEADER Web Conference Project Implementation Series  12 One-hour

  4. PV Module Intraconnect Thermomechanical Durability Damage Prediction Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Module Intraconnect Thermomechanical Durability Damage Prediction Model PV Module Intraconnect Thermomechanical Durability Damage Prediction Model Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado PDF icon pvmrw13_ps2_dow_gaston.pdf More Documents & Publications 2014 Propulsion Materials R&D Annual Report Electro-thermal-mechanical Simulation and Reliability for Plug-in Vehicle Converters and Inverters Center for

  5. Urban Heat Islands: Anti-Soiling Cool Roof Coatings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Anti-Soiling Cool Roof Coatings Urban Heat Islands: Anti-Soiling Cool Roof Coatings Performers: Lawrence Berkeley National Laboratory Project Partners: -- Oak Ridge National Laboratory - Oak Ridge, TN -- Dow Chemical Company - Midland, MI DOE Funding: $500,000 Cost Share: $500,000 Project Term: Jan. 2013 - Dec. 2014 Project Objective The U.S.-China Clean Energy Research Center (CERC) is a pioneering research and development (R&D) consortium bringing together governments, key policymakers,

  6. EERE Success Story-Electrolyte Model Helps Researchers Develop Better

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries, Wins R&D 100 Award | Department of Energy Electrolyte Model Helps Researchers Develop Better Batteries, Wins R&D 100 Award EERE Success Story-Electrolyte Model Helps Researchers Develop Better Batteries, Wins R&D 100 Award October 15, 2014 - 1:40pm Addthis Dow Chemical, Hawaii Natural Energy Institute, Argonne National Lab (ANL) and the Idaho National Laboratory (INL), have developed the Advanced Electrolyte Model (AEM), a powerful tool that analyzes and identifies

  7. Directors - Center for Solar and Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Associate Directors Prof. Rachel S. Goldman CSTEC Associate Director Professor, Materials Science and Engineering, Electrical Engineeering and Computer Science, Physics Prof. Ctirad Uher CSTEC Associate Director C. Wilbur Peters Collegiate Professor of Physics Prof. Rachel S. Goldman Dr. Rachel Goldman is a professor of MSE who holds joint appointments in Physics and in Electrical Engineering & Computer Science. Goldman started her academic career at UM in 1997 as the Dow Corning Assistant

  8. NREL: Photovoltaics Research - Company Partners in Photovoltaic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manufacturing R&D Company Partners in Photovoltaic Manufacturing R&D More than 40 private-sector companies partnered with NREL on successful efforts within the PV Manufacturing R&D Project. They included manufacturers of crystalline silicon, thin-film, and concentrator solar technologies. The companies are listed below. Advanced Energy Systems Alpha Solarco ASE Americas AstroPower/GE Energy Boeing Aerospace BP Solar Cronar Crystal Systems Dow Corning Energy Conversion Devices

  9. Critical Materials Workshop Final Participant List

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Critical Materials Workshop April 3, 2012 ■ Arlington, VA Final Participant Listing Georg Abakumov ADMA Products Inc. Anderson Ames Laboratory Julie Anderson Golden Field Office Gretchen Baier The Dow Chemical Company Suresh Baskaran Pacific Northwest National Laboratory James Beals UTRC Bianca Beeks ITECS Innovative Steven Boyd DOE Vehicle Technologies Richard Brotzman Argonne National Laboratory Matt Brown McBee Strategic Consulting Gordon Brown SLAC National Accelerator Laboratory Stephanie

  10. Encapsulant-based Solution to Potential Induced Degradation of Photovoltaic

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modules | Department of Energy Encapsulant-based Solution to Potential Induced Degradation of Photovoltaic Modules Encapsulant-based Solution to Potential Induced Degradation of Photovoltaic Modules Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado PDF icon pvmrw13_ps4_dow_nanjundiah.pdf More Documents & Publications QER - Comment of Edison Electric Institute (EEI) 1 DOE_Technology_TF_Final-Jun.pdf Behavioral Opportunities for Energy Savings in

  11. Bench Scale Integration Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bench Scale Integration WBS 2.4.1.100 2015 DOE BioEnergy Technologies Office (BETO) Project Peer Review Date: March 25, 2015 Technology Area Review: Biochemical Conversion Principal Investigator: Nancy Dowe (Rick Elander, presenter) Organization: National Renewable Energy Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 Goal Statement Goal is to demonstrate, at bench scale, an integrated process to produce HC fuel and a model

  12. Building America Expert Meeting: Cladding Attachment Over Exterior

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Insulation | Department of Energy Cladding Attachment Over Exterior Insulation Building America Expert Meeting: Cladding Attachment Over Exterior Insulation Building Science Corporation (BSC) held an expert meeting on Cladding Attachment Over Exterior Insulation on Saturday, July 28, 2012 at the Westford Regency Hotel in Westford, Massachusetts. Featured speakers included Jay Crandell of ARES Consulting, Peter Baker of BSC, Gary Parsons of DOW Chemical Company, Vladimir Kochkin of the

  13. Microsoft PowerPoint - 090326_stm_poster_IWV.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shallow and Organized Convection With Water-Vapor DIAL and DOW as well as Comparisons with Mesoscale Models during COPS Volker Wulfmeyer 1 , Fumiko Aoshima 1 , Andreas Behrendt 1 , Sandip Pal 1 , Tammy Weckwerth 2 , and Martin Hagen 3 1: University of Hohenheim, Stuttgart, Germany; 2: National Center for Atmospheric Research, USA, 3: DLR Oberpfaffenhofen, Germany 1: University of Hohenheim, Stuttgart, Germany; 2: National Center for Atmospheric Research, USA, 3: DLR Oberpfaffenhofen, Germany 1)

  14. Mr. David B. B. Helfrey Guilfoil Petzell & Shoemake

    Office of Legacy Management (LM)

    Energy Washington, DC 20545 AUG 15 1988 Mr. David B. B. Helfrey Guilfoil Petzell & Shoemake Attorneys at Law 100 North Broadway St. Louis, Missouri 63102 Dear Mr. Helfrey: Enclosed please find two copies of the revised survey consent form for the radiological survey of that portion of the Spectrulite Consortium, Inc., site that was used by DOW Chemical for the processing of uranium metal. We have incorporated a modified version of the addendum that contained your requested changes into the

  15. Building America Expert Meeting: Cladding Attachment Over Exterior

    Energy Savers [EERE]

    Insulation | Department of Energy Cladding Attachment Over Exterior Insulation Building America Expert Meeting: Cladding Attachment Over Exterior Insulation Building Science Corporation (BSC) held an expert meeting on Cladding Attachment Over Exterior Insulation on Saturday, July 28, 2012 at the Westford Regency Hotel in Westford, Massachusetts. Featured speakers included Jay Crandell of ARES Consulting, Peter Baker of BSC, Gary Parsons of DOW Chemical Company, Vladimir Kochkin of the

  16. Stay-Clean and Durable White Elastomeric Roof Coatings (ERCs)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stay-Clean and Durable White 2014 Building Technologies Office Elastomeric Roof Coatings (ERCs) Peer Review CRADA with Dow Chemical aged Challenge: speed the development of high performance white coatings that resist soiling, last longer, and save more energy new Mohamad Sleiman MSleiman@LBL.gov Hugo Destaillats HDestaillats@LBL.gov Ronnen Levinson RMLevinson@LBL.gov Lawrence Berkeley National Laboratory Project Summary Timeline: Start date: 10/2011 Planned end date: 9/2014 Key Milestones *

  17. Electrolyte Model Helps Researchers Develop Better Batteries, Wins R&D 100

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Award | Department of Energy Electrolyte Model Helps Researchers Develop Better Batteries, Wins R&D 100 Award Electrolyte Model Helps Researchers Develop Better Batteries, Wins R&D 100 Award October 15, 2014 - 1:40pm Addthis Dow Chemical, Hawaii Natural Energy Institute, Argonne National Lab (ANL) and the Idaho National Laboratory (INL), have developed the Advanced Electrolyte Model (AEM), a powerful tool that analyzes and identifies potential electrolytes for use in battery systems.

  18. Windows Projects | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    The new building wing of the Saint-Gobain Research Shanghai facility, where LBNL is field testing comercialized electrochromic windows. Advanced Window and Shading Technologies Lead Performer: Lawrence Berkeley National Laboratory - Berkeley, CA Partners: -- Saint-Gobin - Valley Forge, PA -- Sage Electrochromics - Faribault, MN -- Dow Chemical - Midland, MI -- Lutron - Coopersburg, PA -- 3M - Maplewood, MN -- Tongji University - Shanghai, China -- China Academy of Building Research - Beijing,

  19. Accelerating the Clean Energy Transition in South Africa | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Accelerating the Clean Energy Transition in South Africa Accelerating the Clean Energy Transition in South Africa May 28, 2015 - 9:45am Addthis New partnerships between U.S. and South African organizations were recognized during a signing ceremony at the Powering South Africa Conference. From left to right: Jaime Cruz, Millenium Solutions; Edwina Felix, Peer Africa; Carsten Larsen, Dow; Sheila Moynihan, EERE; Bipin Shah, WinBuild; Teresa Scheepers, Municipal Manger of !Khies; Minister

  20. PARAMETRIC EFFECTS OF ANTI-FOAM COMPOSITION, SIMULANT PROPERTIES AND NOBLE METALS ON THE GAS HOLDUP AND RELEASE OF A NON-NEWTONIAN WASTE SLURRY SIMULANT

    SciTech Connect (OSTI)

    Guerrero, H; Charles Crawford, C; Mark Fowley, M

    2008-08-07

    Gas holdup tests were performed in bench-scale and small-scale mechanically-agitated mixing systems at the Savannah River National Laboratory (SRNL) for a simulant of waste from the Hanford Tank 241-AZ-101. These featured additions of DOW Corning Q2-3183A anti-foam agent. Results indicated that this anti-foam agent (AFA) increased gas holdup in the waste simulant by about a factor of four and, counter-intuitively, that the holdup increased as the non-newtonian simulant shear strength decreased (apparent viscosity decreased). Such results raised the potential of increased flammable gas retention in Hanford Waste Treatment and Immobilization Plant (WTP) vessels mixed by air sparging and pulse-jet mixers (PJMs) during a Design Basis Event (DBE). Additional testing was performed to determine the effects of simulant properties, composition of alternate AFAs, and presence of trace noble metals. Key results are that: (1) Increased gas holdup resulting from addition of Q2-3183A is due to a decrease in surface tension that supports small bubbles which have low rise velocities. (2) Dow Corning 1520-US AFA shows it to be a viable replacement to Dow Corning Q2-3183A AFA. This alternative AFA, however, requires significantly higher dosage for the same anti-foam function. (3) Addition of noble metals to the AZ-101 waste simulant does not produce a catalytic gas retention effect with the AFA.

  1. Curcumin blocks interleukin (IL)-2 signaling in T-lymphocytes by inhibiting IL-2 synthesis, CD25 expression, and IL-2 receptor signaling

    SciTech Connect (OSTI)

    Forward, Nicholas A.; Conrad, David M.; Power Coombs, Melanie R.; Doucette, Carolyn D.; Furlong, Suzanne J.; Lin, Tong-Jun; Department of Pediatrics, Dalhousie University, Halifax, Nova Scotia ; Hoskin, David W.

    2011-04-22

    Highlights: {yields} Curcumin inhibits CD4{sup +} T-lymphocyte proliferation. {yields} Curcumin inhibits interleukin-2 (IL-2) synthesis and CD25 expression by CD4{sup +} T-lymphocytes. {yields} Curcumin interferes with IL-2 receptor signaling by inhibiting JAK3 and STAT5 phosphorylation. {yields} IL-2-dependent regulatory T-lymphocyte function and Foxp3 expression is downregulated by curcumin. -- Abstract: Curcumin (diferulomethane) is the principal curcuminoid in the spice tumeric and a potent inhibitor of activation-induced T-lymphocyte proliferation; however, the molecular basis of this immunosuppressive effect has not been well studied. Here we show that micromolar concentrations of curcumin inhibited DNA synthesis by mouse CD4{sup +} T-lymphocytes, as well as interleukin-2 (IL-2) and CD25 ({alpha} chain of the high affinity IL-2 receptor) expression in response to antibody-mediated cross-linking of CD3 and CD28. Curcumin acted downstream of protein kinase C activation and intracellular Ca{sup 2+} release to inhibit I{kappa}B phosphorylation, which is required for nuclear translocation of the transcription factor NF{kappa}B. In addition, IL-2-dependent DNA synthesis by mouse CTLL-2 cells, but not constitutive CD25 expression, was impaired in the presence of curcumin, which demonstrated an inhibitory effect on IL-2 receptor (IL-2R) signaling. IL-2-induced phosphorylation of STAT5A and JAK3, but not JAK1, was diminished in the presence of curcumin, indicating inhibition of critical proximal events in IL-2R signaling. In line with the inhibitory action of curcumin on IL-2R signaling, pretreatment of CD4{sup +}CD25{sup +} regulatory T-cells with curcumin downregulated suppressor function, as well as forkhead box p3 (Foxp3) expression. We conclude that curcumin inhibits IL-2 signaling by reducing available IL-2 and high affinity IL-2R, as well as interfering with IL-2R signaling.

  2. The Quest for Modular Nanocages: tbo-MOF as an Archetype for Mutual Substitution, Functionalization, and Expansion of Quadrangular Pillar Building Blocks

    SciTech Connect (OSTI)

    Eubank, Jarrod F.; Mouttaki, Hasnaa; Cairns, Amy J.; Belmabkhout, Youssef; Wojtas, Lukasz; Luebke, Ryan; Alkordi, Mohamed; Eddaoudi, Mohamed

    2011-12-09

    A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]{sub n} MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications.

  3. Direct detection of a transport-blocking trap in a nanoscaled silicon single-electron transistor by radio-frequency reflectometry

    SciTech Connect (OSTI)

    Villis, B. J.; Sanquer, M.; Jehl, X.; Orlov, A. O.; Barraud, S.; Vinet, M.; Fay, P.; Snider, G.

    2014-06-09

    The continuous downscaling of transistors results in nanoscale devices which require fewer and fewer charged carriers for their operation. The ultimate charge controlled device, the single-electron transistor (SET), controls the transfer of individual electrons. It is also the most sensitive electrometer, and as a result the electron transport through it can be dramatically affected by nearby charges. Standard direct-current characterization techniques, however, are often unable to unambiguously detect and resolve the origin of the observed changes in SET behavior arising from changes in the charge state of a capacitively coupled trap. Using a radio-frequency (RF) reflectometry technique, we are able to unequivocally detect this process, in very close agreement with modeling of the trap's occupation probability.

  4. Method and structure for skewed block-cyclic distribution of lower-dimensional data arrays in higher-dimensional processor grids

    DOE Patents [OSTI]

    Chatterjee, Siddhartha (Yorktown Heights, NY); Gunnels, John A. (Brewster, NY)

    2011-11-08

    A method and structure of distributing elements of an array of data in a computer memory to a specific processor of a multi-dimensional mesh of parallel processors includes designating a distribution of elements of at least a portion of the array to be executed by specific processors in the multi-dimensional mesh of parallel processors. The pattern of the designating includes a cyclical repetitive pattern of the parallel processor mesh, as modified to have a skew in at least one dimension so that both a row of data in the array and a column of data in the array map to respective contiguous groupings of the processors such that a dimension of the contiguous groupings is greater than one.

  5. Interfacial reactions in epitaxial Al/TiN(111) model diffusion barriers: Formation of an impervious self-limited wurtzite-structure AIN(0001) blocking layer

    SciTech Connect (OSTI)

    Chun, J.-S.; Desjardins, P.; Lavoie, C.; Shin, C.-S.; Cabral, C.; Petrov, I.; Greene, J. E.

    2001-06-15

    Single-crystal TiN(111) layers, 45 nm thick, were grown on MgO(111) by ultrahigh vacuum reactive magnetron sputter deposition in pure N{sub 2} discharges at T{sub s}=700{degree}C. Epitaxial Al(111) overlayers, 160 nm thick, were then deposited at T{sub s}=100{degree}C in Ar without breaking vacuum. Interfacial reactions and changes in bilayer microstructure due to annealing at 620 and 650{degree}C were investigated using x-ray diffraction and transmission electron microscopy (TEM). The interfacial regions of samples annealed at 620{degree}C consist of continuous {approx_equal}7-nm-thick epitaxial wurtzite-structure AlN(0001) layers containing a high density of stacking faults, with {approx_equal}22 nm thick tetragonal Al{sub 3}Ti(112) overlayers. Surprisingly, samples annealed at the higher temperature are more stable against Al{sub 3}Ti formation. TEM analyses of bilayers annealed at 650{degree}C (10{degree}C below the Al melting point!) reveal only the self-limited growth of an {approx_equal}3-nm-thick interfacial layer of perfect smooth epitaxial wurtzite-structure AlN(0001) which serves as an extremely effective deterrent for preventing further interlayer reactions. {copyright} 2001 American Institute of Physics.

  6. Plant cyclopeptide RA-V kills human breast cancer cells by inducing mitochondria-mediated apoptosis through blocking PDK1AKT interaction

    SciTech Connect (OSTI)

    Fang, Xian-Ying; Chen, Wei; Fan, Jun-Ting; Song, Ran; Wang, Lu; Gu, Yan-Hong; Zeng, Guang-Zhi; Shen, Yan; Wu, Xue-Feng; Tan, Ning-Hua; Xu, Qiang; Sun, Yang

    2013-02-15

    In the present paper, we examined the effects of a natural cyclopeptide RA-V on human breast cancer cells and the underlying mechanisms. RA-V significantly inhibited the growth of human breast cancer MCF-7, MDA-MB-231 cells and murine breast cancer 4T1 cells. In addition, RA-V triggered mitochondrial apoptotic pathway which was indicated by the loss of mitochondrial membrane potential, the release of cytochrome c, and the activation of caspase cascade. Further study showed that RA-V dramatically inhibited phosphorylation of AKT and 3-phosphoinositide dependent protein kinase 1 (PDK1) in MCF-7 cells. Moreover, RA-V disrupted the interaction between PDK1 and AKT in MCF-7 cells. Furthermore, RA-V-induced apoptosis could be enhanced by phosphatidylinositol 3-kinase inhibitor or attenuated by over-expression of AKT in all the three kinds of breast cancer cells. Taken together, this study shows that RA-V, which can induce mitochondria-mediated apoptosis, exerts strong anti-tumor activity against human breast cancer. The underlying anti-cancer mechanism of RA-V is related to the blockage of the interaction between PDK1 and AKT. - Highlights: ? Plant cyclopeptide RA-V kills human breast cancer cells. ? RA-V triggered mitochondrial apoptotic pathway in human breast cancer cells. ? RA-V inhibited phosphorylation of AKT and PDK1 in breast cancer MCF-7 cells. ? Its mechanism is related to the blockage of the interaction between PDK1 and AKT.

  7. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Gary Harmond; Albert Tsang

    2003-03-14

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead by Gasification Engineering Corporation (GEC), a company of Global Energy Inc., and supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation. Three project phases are planned for execution over a three year period, including: (1) Feasibility study and conceptual design for an integrated demonstration facility, and for fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing to define any technology gaps or critical design and integration issues (3) Engineering design and financing plan to install an integrated commercial demonstration facility at the existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana. The WREL facility is a project selected and co-funded under the Round IV of the U.S. Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now offered commercially by Global Energy, Inc., as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC and an Industrial Consortium are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. During the reporting period, various methods to remove low-level contaminants for the synthesis gas were reviewed. In addition, there was a transition of the project personnel for GEC which has slowed the production of the outstanding project reports.

  8. WABASH RIVER INTEGRATED METHANOL AND POWER PRODUCTION FROM CLEAN COAL TECHNOLOGIES (IMPPCCT)

    SciTech Connect (OSTI)

    Thomas Lynch

    2004-01-07

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is evaluating integrated electrical power generation and methanol production through clean coal technologies. The project is conducted by a multi-industry team lead previously by Gasification Engineering Corporation (GEC). The project is now under the leadership of ConocoPhillips Company (COP) after it acquired GEC and the E-Gas{trademark} gasification technology from Global Energy in July 2003. The Phase I of this project was supported by Air Products and Chemicals, Inc., Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while the Phase II is supported by Gas Technology Institute, TDA Research, Inc., and Nucon International, Inc. The two project phases planned for execution include: (1) Feasibility study and conceptual design for an integrated demonstration facility at Global Energy's existing Wabash River Energy Limited (WREL) plant in West Terre Haute, Indiana, and for a fence-line commercial embodiment plants (CEP) operated at Dow Chemical or Dow Corning chemical plant locations (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. The WREL facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other solid fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-GAS{trademark} technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and now COP and the industrial partners are investigating the use of synthesis gas produced by the E-GAS{trademark} technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort are to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from synthesis gas derived from coal, or, coal in combination with some other carbonaceous feedstock. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  9. Advance Patent Waiver W(A)2011-034 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1-034 Advance Patent Waiver W(A)2011-034 This document waives certain patent rights the Department of Energy (DOE) has to inventions conceived or first actually reduced to practice by DOW CHEMICAL COMPANY under agreement DE-EE0002867, as the DOE has determined that granting such a waiver best serves the interests of the United States and the general public. PDF icon Advance Patent Waiver W(A)2011-034 More Documents & Publications Advance Patent Waiver W(A)2011-006

  10. SSF Experimental Protocols -- Lignocellulosic Biomass Hydrolysis and Fermentation: Laboratory Analytical Procedure (LAP); Issue Date: 10/30/2001

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SSF Experimental Protocols - Lignocellulosic Biomass Hydrolysis and Fermentation Laboratory Analytical Procedure (LAP) Issue Date: 10/30/2001 N. Dowe and J. McMillan Technical Report NREL/TP-510-42630 January 2008 NREL is operated by Midwest Research Institute ● Battelle Contract No. DE-AC36-99-GO10337 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov Operated for the U.S. Department of Energy Office of Energy Efficiency and

  11. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sizes, Fractional Coverage, and Radar Doppler Moments Profiles of Fair-Weather Cumulus Clouds at the TWP ARM Site Kollias, P., Albrecht B.A., and Dow B.J., University of Miami Eleventh Atmospheric Radiation Measurement (ARM) Science Team Meeting Fair-weather cumuli are fundamental in regulating the vertical structure of water vapor and entropy in the lowest 2 km of the Earth's atmosphere over vast areas of the oceans. Using data from the mm-wavelength cloud radar, the micro-pulse lidar and

  12. Advanced Combustion Diagnostics and Control for Furnaces, Fired Heaters and Boilers

    SciTech Connect (OSTI)

    Tate, J. D.; Le, Linh D.; Knittel,Trevor; Cowie, Alan

    2010-03-20

    The objective of this project was to develop and apply enabling tools and methods towards advanced combustion diagnostics and control of fired-equipment in large-scale petrochemical manufacturing. There are a number of technology gaps and opportunities for combustion optimization, including technologies involving advanced in-situ measurements, modeling, and thermal imaging. These technologies intersect most of manufacturing and energy systems within the chemical industry. This project leveraged the success of a previous DOE funded project led by Dow, where we co-developed an in-situ tunable diode laser (TDL) analyzer platform (with Analytical Specialties Inc, now owned by Yokogawa Electric Corp.). The TDL platform has been tested and proven in a number of combustion processes within Dow and outside of Dow. The primary focus of this project was on combustion diagnostics and control applied towards furnaces, fired heaters and boilers. Special emphasis was placed on the development and application of in-situ measurements for O2, CO and methane since these combustion gases are key variables in optimizing and controlling combustion processes safely. Current best practice in the industry relies on measurements that suffer from serious performance gaps such as limited sampling volume (point measurements), poor precision and accuracy, and poor reliability. Phase I of the project addressed these gaps by adding improved measurement capabilities such as CO and methane (ppm analysis at combustion zone temperatures) as well as improved optics to maintain alignment over path lengths up to 30 meters. Proof-of-concept was demonstrated on a modern olefins furnace located at Dow Chemical's facility in Freeport TX where the improved measurements were compared side-by-side to accepted best practice techniques (zirconium oxide and catalytic bead or thick film sensors). After developing and installing the improved combustion measurements (O2, CO, and methane), we also demonstrated the ability to improve control of an olefins furnace (via CO-trim) that resulted in significant energy savings and lower emissions such as NOx and other greenhouse gases. The cost to retrofit measurements on an existing olefins furnace was found to be very attractive, with an estimated payback achieved in 4 months or less.

  13. New Cool Roof Coatings and Affordable Cool Color Asphalt

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Cool Roof Coatings and Affordable Cool Color Asphalt Shingles Meng-Dawn Cheng Oak Ridge National Laboratory chengmd@ornl.gov; 865-241-5918 April 4, 2013 PM: Andre Desjarlais PI: Meng-Dawn Cheng, Ph.D. David Graham, Ph.D. Sue Carroll Steve Allman Dawn Klingeman Susan Pfiffner, Ph.D. (FY12) Karen Cheng (FY12) Partner: Joe Rokowski (Dow) Roof Testing Facility at ORNL Building Technologies Research and Integration Center 2 | Building Technologies Office eere.energy.gov * Building accounted for

  14. Safety analysis report for packaging: the ORNL DOT specification 6M - special form package

    SciTech Connect (OSTI)

    Schaich, R.W.

    1982-07-01

    The ORNL DOT Specification 6M - Special Form Package was fabricated at the Oak Ridge Nation al Laboratory (ORNL) for the transport of Type B solid non-fissile radioactive materials in special form. The package was evaluated on the basis of tests performed by the Dow Chemical Company, Rocky Flats Division, on the DOT-6M container and special form tests performed on a variety of stainless steel capsules at ORNL by Operations Division personnel. The results of these evaluations demonstrate that the package is in compliance with the applicable regulations for the transport of Type B quantities in special form of non-fissile radioactive materials.

  15. Final Report for the DOE Chemical Hydrogen Storage Center of Excellence

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FINAL R EPORT F OR T HE D OE C HEMICAL HYDROGEN S TORAGE C ENTER O F EXCELLENCE Kevin C . O tt, C enter D irector LOS A LAMOS N ATIONAL L ABORATORY PO B ox 1 663 Los A lamos, N M 8 7545 Summarizing C ontributions f rom C enter P artners: Los A lamos N ational L aboratory ( LANL) Pacific N orthwest N ational L aboratory ( PNNL) Millennium C ell, I nc. Northern A rizona U niversity Rohm a nd H aas/Dow C hemical C ompany University o f A labama University o f C alifornia, D avis University o f C

  16. Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Energy Poneman | Department of Energy Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman February 9, 2012 - 4:25pm Addthis Washington, D.C. - Today, U.S. Deputy Secretary of Energy Daniel Poneman toured Dow Kokam's new global battery research and development center, located in Lee's Summit, Missouri, outside of Kansas City, to highlight America's

  17. IL.26

    Office of Legacy Management (LM)

    ixa6-q ?k.m+~ @ lo3 IL.26 -ORNL/TM-11552 OAK RIDGE NATIONAL LABORATORY PRELIMINARY RESULTS OF THE RADIOLOGICAL SURVEY AT THE FORMER DOW CHEMICAL COMPANY SITE, MADISON, ILLINOIS c W . D. Cottrell J. K. W illiams OPERATED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITED STATES DEPARTMENT OF ENERGY This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Techni- cal Information, P.O. Box 62. Oak Ridge, TN

  18. Stay-Clean and Durable White Elastomeric Roof Coatings | Department of

    Energy Savers [EERE]

    Energy Stay-Clean and Durable White Elastomeric Roof Coatings Stay-Clean and Durable White Elastomeric Roof Coatings Lead Performer: Lawrence Berkeley National Laboratory - Berkeley, CA Partner: Dow Chemical - Midland, MI DOE Funding: $570,000 Cost Share: $449,000 Project Term: 10/1/2011 - 9/30/2014 Project Objective This project is developing stay-clean white elastomeric roof coatings (ERCs) with a three-year aged solar reflectance (SR) of at least 0.75 and a service life of 15 years or

  19. DOE - Office of Legacy Management -- Madison - IL 26

    Office of Legacy Management (LM)

    Madison - IL 26 FUSRAP Considered Sites Madison, IL Alternate Name(s): Spectrulite Consortium, Inc. Former Dow Chemical Company Site IL.26-3 IL.26-4 Location: Intersection of College and Weaver Streets, Madison, Illinois IL.26-4 Historical Operations: Conducted experimental work in natural uranium metal extrusion. IL.26-4 IL.26-5 Eligibility Determination: Eligible IL.26-1 IL.26-2 Radiological Survey(s): Assessment Survey, Verification Survey IL.26-4 LTSM00011565 LTSM00013029 LTSM00011563 Site

  20. INSTALLATION MAG~NiX.ILRI DIVI8ION, CAN.fAN,CONN.

    Office of Legacy Management (LM)

    INSTALLATION MAG~NiX.ILRI DIVI8ION, CAN.fAN,CONN. .PERI,jD Aiq~+ 1, i950 TO: August 31, 195 .:\,.:. ,,., WORK SHEET FOR: I b WSIGNOR I. v DowChemical Go. Velasco, Texas ., Azlterprise Meetala cc Brooklyn, New York Meili $Worthin&m Hatboro, ?'a. LOT NO. '... I [ATERIAL SYnB,fJL KEASURED' NET WT. 100,007~ ( 4;020 I ! 19 ~, ANALYBIS % METAL/100 r, Noi. 23) METAL CONTENT INSTRUCTIONS: This sheet% will be Used.ln.preDarlng Haterlal Balance. 'The totals from the various ltams listed above ~111 be