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Sample records for dl dolomitic limestone

  1. Hydrothermal dolomitization of Jurassic-Cretaceous limestones in the southern Alps (Italy): Relation to tectonics and volcanism

    SciTech Connect (OSTI)

    Cervato, C. )

    1990-05-01

    Dolomitization has affected up to 750m of the Jurassic and Cretaceous pelagic carbonate sequence of the southern continental margin of the Alpine Tethys; the sequence crops out in the southern Alps of Italy (Monti Lessini). Late Paleocene to Miocene extrusion of basaltic tuffs, breccias, and lavas was contemporaneous with the dolomitization was was associated with extensive tectonism in an ancient back-arc basin. More than 200 samples were analyzed by X-ray diffraction, cathodoluminescence, scanning electron microscopy, stable isotope ratios (carbon, oxygen, strontium), and clay mineralogy. The dolomite contains 40% to 50% MgCO{sub 3}. In thin sections, the crystal size distribution is unimodal (about 100 {mu}m), possibly indicating a single nucleation for the main crystallization phase. The {delta}{sup 13}C of the dolomite is not appreciably different from the undolomitized pelagic limestone (+1.0{per thousand} to +2.0{per thousand} Peedee belemnite (PDB)). The {delta}{sup 18}O variation (-5.0{per thousand} to -13.0{per thousand} PDB) is due to temperature variation in the system. The {sup 87}Sr/{sup 86}Sr ratio in the dolomite (0.70839-0.70867) is consistent with the ratio in late Oligocene-Miocene marine water. Clay minerals in limestone and dolomite differ in the presence of neoformed Mg-chlorite, indicating a maximum temperature of about 150C for dolomitization. The dolomite is suggested to have a hydrothermal origin. The heat flow associated with the volcanism allowed marine water to penetrate the system and circulate in convective cells through the tectonic breccias, locally dolomitizing the limestone.

  2. Multiple dolomitization events in Triassic Latemar buildup, the Dolomites, northern Italy

    SciTech Connect (OSTI)

    Wilson, E.N.

    1988-01-01

    Partially dolomitized grainstones of the Middle Triassic Latemar buildup (Dolomites, northern Italy) exhibit a range of texturally distinct dolomite types. Petrographic and field observations of spatial associations and cross-cutting relationships among dolomites allow unravelling of the paragenesis of dolomitization events. Three generations of dolomite are preserved in the Latemar. Microdolomite, the earliest generation, occurs as replacement of allochems and as cement in thin (5-15 cm) exposure caps of meter-scale subtidal cycles. These dolomite crusts are texturally and chemically analogous to the Holocene supratidal crusts of Florida and the Bahamas. Saddle dolomite cements, the second generation, fill or line pores and fractures through the platform. The final generation is massive replacement of limestone by coarse, crystalline dolomite, which occupies a 2-3 km/sup 3/ mushroom-shaped zone in the center of the buildup and includes a wide array of fabrics. Here, subtidal limestones are altered to porous sucrosic dolomite, while microdolomite caps are altered to dense dolomite mosaics. Saddle dolomite cements remain as relics surrounded by replacement rhombs. Two important conclusions are (1) early dolomite is preserved as poorly ordered microdolomite (unless overprinted by a later dolomitization event) and accounts for an insignificant volume of the Latemar dolomite, and (2) saddle dolomite cements, often regarded as late-stage burial, occur before massive replacement.

  3. Multiple dolomitization events in Triassic latemar buildup, the dolomites, northern Italy

    SciTech Connect (OSTI)

    Wilson, E.N.

    1988-02-01

    Partially dolomitized grainstones of the Middle Triassic Latemar buildup (Dolomites, northern Italy) exhibit a range of texturally distinct dolomite types. Petrographic and field observations of spatial associations and cross-cutting relationships among dolomites allow unravelling of the paragenesis of dolomitization events. Three generations of dolomite are preserved in the Latemar. Microdolomite, the earliest generation, occurs as replacement of allochems and as cement in thin (5-15 cm) exposure caps of meter-scale subtidal cycles. These dolomite crusts are texturally and chemically analogous to the Holocene supratidal crusts of Florida and the Bahamas. Saddle dolomite cements, the second generation, fill or line pores and fractures through the platform. The final generation is massive replacement of limestone by coarse, crystalline dolomite, which occupies a 2-3 km/sup 3/ mushroom-shaped zone in the center of the buildup and includes a wide array of fabrics. Here, subtidal limestones are altered to porous sucrosic dolomite, while microdolomite caps are altered to dense dolomite mosaics. Saddle dolomite cements remain as relics surrounded by replacement rhombs. Two important conclusions are (1) early dolomite is preserved as poorly ordered microdolomite (unless overprinted by a later dolomitization event) and accounts for an insignificant volume of the Latemar dolomite, and (2) saddle dolomite cements, often regarded as late-stage burial, occur before massive replacement. Standard textural classification of Latemar dolomites hindered the resolution of the timing of dolomitization events. Instead, paragenetic relationships provided a powerful tool for grouping dolomites into generations representing specific diagenetic events in specific dolomitizing environments.

  4. Indiana's Trenton limestone geology

    SciTech Connect (OSTI)

    Keith, B.D.

    1981-03-01

    The term Trenton limestone is the stratigraphic designation for a unit in northern Indiana composed of both limestone and dolomite. The Trenton is Middle Ordovician (Champlainian) in age and related clearly to the position of the Cincinnati arch. The limestone is thickest in northern Indiana and thins toward the southeast. Isopach maps of the Trenton limestone and the Maquoketa group above it indicate that the Cincinnati arch did not exist as a positive structural influence to sedimentation until after Ordovician time. Preliminary results of an ongoing study of the Trenton reservoir suggest that second and tertiary recovery there will be limited. Because of the low density of drilling on the Trenton's north flank, however, large areas remain virtually untested; more structural or stratigraphic traps similar to those of the Urbana field could exist. A better definition of the distribution of the dolomite facies will lead to a more accurate assessment of the Trenton's potential.

  5. An example of mixing-zone dolomite, Middle Eocene Avon Park Formation, Floridan aquifer system

    SciTech Connect (OSTI)

    Cander, H.S. )

    1994-07-01

    A late-formed dolomite cement in a core of the Middle Eocene Avon Park Formation, peninsular Florida, provides an example of dolomite cement from a mixing zone and illustrates how dolomite textural alteration and stabilization can occur at earth-surface conditions. The Avon Park Formation is a pervasively dolomitized peritidal platform carbonate 400 m thick in the Florida aquifer system. Typical Avon Park dolomite is inclusion-rich, fine-grained (< 40 mm), noncathodoluminescent, highly porous (average, 20%), and formed during the Eocene by normal to hypersaline seawater ([delta][sup 18]O = + 3.7[per thousand] PDB; [delta][sup 13]C = + 2.0[per thousand]; [sup 87]Sr/[sup 86]Sr = 0.70778; Sr = 167 ppm). In a 20 m interval in a core from southwest Florida, inclusion-free, cathodoluminescent dolomite overgrows the early-formed noncathodoluminescent marine dolomite. The cathodoluminescent dolomite cement profoundly alters the texture of Avon Park dolomite from typical Cenozoic-like porous, poorly crystalline dolomite to hard, dense, low-porosity, highly crystalline Paleozoic-like dolomite. The dolomite cement is not a replacement of limestone but an overgrowth of early-formed marine dolomite and pore-occluding cement. This study demonstrates that: (1) dolomite precipitated from a 75% seawater mixing-zone fluid that was both calcite saturated and sulfate-rich, and (2) dramatic textural maturation and stabilization in dolomite can occur in the near surface environment, without elevated temperature and burial conditions.

  6. ARM - Instrument - dl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsdl Documentation DL : Handbook ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Doppler Lidar (DL) Instrument Categories Cloud Properties Picture of the Doppler Lidar General Overview The Doppler Lidar (DL) is an active remote sensing instrument that provides range- and time-resolved measurements of radial velocity and attenuated backscatter. The principle of operation is similar to radar

  7. Doppler Lidar (DL) Handbook

    SciTech Connect (OSTI)

    Newsom, RK

    2012-02-13

    The Doppler lidar (DL) is an active remote sensing instrument that provides range- and time-resolved measurements of radial velocity and attenuated backscatter. The principle of operation is similar to radar in that pulses of energy are transmitted into the atmosphere; the energy scattered back to the transceiver is collected and measured as a time-resolved signal. From the time delay between each outgoing transmitted pulse and the backscattered signal, the distance to the scatterer is inferred. The radial or line-of-sight velocity of the scatterers is determined from the Doppler frequency shift of the backscattered radiation. The DL uses a heterodyne detection technique in which the return signal is mixed with a reference laser beam (i.e., local oscillator) of known frequency. An onboard signal processing computer then determines the Doppler frequency shift from the spectra of the heterodyne signal. The energy content of the Doppler spectra can also be used to determine attenuated backscatter.

  8. DL-36361 UC-414 I

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DL-36361 UC-414 I * Discovery of the Most Distant Supernovae and the Quest for L l Gerson Goldhaber and Saul Perlmutter Lawrence Berkeley Laboratory and Center for Particle Astrophysics University of California, Berkeley, CA 94720 Silvia Gabi, Ariel Goobar, Alex Kim, Mathew Kim, and Reynald Pain Lawrence Berkeley Laboratory, University of California Berkeley, CA 94720 Carl Pennypacker and Ivan Small Lawrence Berkeley Laboratory and Space Sciences Laboratory University of California, Berkeley, CA

  9. Water/rock interaction efficiency and seawater dolomitization in the Eocene Avon Park Formation, Floridan Aquifer

    SciTech Connect (OSTI)

    Cander, H.S. )

    1990-05-01

    The Floridan aquifer has often been proposed as a system of extensive meteoric carbonate diagenesis and mixing zone dolomitization. However, the dominance of marine isotope (C, O, {sup 87}Sr/{sup 86}Sr) and trace element (Sr, Fe, Mn) compositions in dolomites and limestones in the Eocene Avon Park Formation, Floridan aquifer, suggests that the very active low temperature meteoric groundwater system has, over the past 40 m.y., been an inefficient mechanism of diagenesis. {delta}{sup 18}O values of all but two replacement dolomites sampled range from +2.0 to +5.1 (PDB) with high Sr concentrations (90-325 ppm), indicating dolomitization by near-normal marine water involving no significant interaction with meteoric groundwater. The two {delta}{sup 18}O-depleted (0.0 {plus minus} 1) dolomites have low Sr concentrations ({approximately}100 ppm) suggesting limited recrystallization in meteoric water. Several dolomite samples have radiogenic {sup 87}Sr/{sup 86}Sr compositions (0.70810-0.70883 {plus minus} 2), but have heavy oxygen isotope compositions (> +2.0) and high Sr concentrations (<200 ppm) suggesting precipitation from cold Miocene age or younger seawater that circulated through the Florida platform. Most limestone stable isotope compositions cluster around marine values (({delta}{sup 18}O = {minus}1 to +1, PDB) {delta}{sup 13}C = +0.5 to +2.5) and have Eocene seawater {sup 87}Sr/{sup 86}Sr compositions (0.70775 {plus minus} 2 to 0.70779 {plus minus} 2) with 400 to 500 ppm Sr. Isotopic compositions of limestones from the east coast of Florida are all within these ranges. Only some limestones from central Florida and the west coast contain depleted stable isotopic compositions and low Sr concentrations. The sample with the most depleted stable isotope values has a radiogenic {sup 87}Sr/{sup 86}Sr composition (0.70870 {plus minus} 2), suggesting that diagenetic meteoric water migrated through post-Miocene strata.

  10. Treating tar sands formations with dolomite

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2013-10-15

    A method for treating a karsted formation containing heavy hydrocarbons and dolomite includes providing heat to at least part of one or more karsted layers in the formation from one or more heaters located in the karsted layers. A temperature in at least one of the karsted layers is allowed to reach a decomposition temperature of dolomite in the formation. The dolomite is allowed to decompose and at least some hydrocarbons are produced from at least one of the karsted layers of the formation.

  11. Treating tar sands formations with dolomite

    DOE Patents [OSTI]

    Vinegar, Harold J.; Karanikas, John Michael

    2010-06-08

    Methods for treating a tar sands formation are described herein. The tar sands formation may include dolomite and hydrocarbons. Methods may include providing heat at less than the decomposition temperature of dolomite from one or more heaters to at least a portion of the formation. At least some of the hydrocarbon fluids are mobilized in the formation. At least some of the hydrocarbon fluids may be produced from the formation.

  12. The Mississippian Leadville Limestone Exploration Play, Utah and Colorado-Exploration Techniques and Studies for Independents

    SciTech Connect (OSTI)

    Thomas Chidsey

    2008-09-30

    The Mississippian (late Kinderhookian to early Meramecian) Leadville Limestone is a shallow, open-marine, carbonate-shelf deposit. The Leadville has produced over 53 million barrels (8.4 million m{sup 3}) of oil/condensate from seven fields in the Paradox fold and fault belt of the Paradox Basin, Utah and Colorado. The environmentally sensitive, 7500-square-mile (19,400 km{sup 2}) area that makes up the fold and fault belt is relatively unexplored. Only independent producers operate and continue to hunt for Leadville oil targets in the region. The overall goal of this study is to assist these independents by (1) developing and demonstrating techniques and exploration methods never tried on the Leadville Limestone, (2) targeting areas for exploration, (3) increasing deliverability from new and old Leadville fields through detailed reservoir characterization, (4) reducing exploration costs and risk especially in environmentally sensitive areas, and (5) adding new oil discoveries and reserves. The final results will hopefully reduce exploration costs and risks, especially in environmentally sensitive areas, and add new oil discoveries and reserves. The study consists of three sections: (1) description of lithofacies and diagenetic history of the Leadville at Lisbon field, San Juan County, Utah, (2) methodology and results of a surface geochemical survey conducted over the Lisbon and Lightning Draw Southeast fields (and areas in between) and identification of oil-prone areas using epifluorescence in well cuttings from regional wells, and (3) determination of regional lithofacies, description of modern and outcrop depositional analogs, and estimation of potential oil migration directions (evaluating the middle Paleozoic hydrodynamic pressure regime and water chemistry). Leadville lithofacies at Libon field include open marine (crinoidal banks or shoals and Waulsortian-type buildups), oolitic and peloid shoals, and middle shelf. Rock units with open-marine and restricted-marine facies constitute a significant reservoir potential, having both effective porosity and permeability when dissolution of skeletal grains, followed by dolomitization, has occurred. Two major types of diagenetic dolomite are observed in the Leadville Limestone at Lisbon field: (1) tight 'early' dolomite consisting of very fine grained (<5 {micro}m), interlocking crystals that faithfully preserve depositional fabrics; and (2) porous, coarser (>100-250 {micro}m), rhombic and saddle crystals that discordantly replace limestone and earlier very fine grained dolomite. Predating or concomitant with late dolomite formation are pervasive leaching episodes that produced vugs and extensive microporosity. Most reservoir rocks within Lisbon field appear to be associated with the second, late type of dolomitization and associated leaching events. Other diagenetic products include pyrobitumen, syntaxial cement, sulfide minerals, anhydrite cement and replacement, and late macrocalcite. Fracturing (solution enlarged) and brecciation (autobrecciation) caused by hydrofracturing are widespread within Lisbon field. Sediment-filled cavities, related to karstification of the exposed Leadville, are present in the upper third of the formation. Pyrobitumen and sulfide minerals appear to coat most crystal faces of the rhombic and saddle dolomites. The fluid inclusion and mineral relationships suggest the following sequence of events: (1) dolomite precipitation, (2) anhydrite deposition, (3) anhydrite dissolution and quartz precipitation, (4) dolomite dissolution and late calcite precipitation, (5) trapping of a mobile oil phase, and (6) formation of bitumen. Fluid inclusions in calcite and dolomite display variable liquid to vapor ratios suggesting reequilibration at elevated temperatures (50 C). Fluid salinities exceed 10 weight percent NaCl equivalent. Low ice melting temperatures of quartz- and calcite-hosted inclusions suggest chemically complex Ca-Mg-bearing brines associated with evaporite deposits were responsible for mineral deposition. The overall conclusion from th

  13. Diagenetic features of Trenton Limestone in northern Indiana: petrographic evidence for Late (Mesogenetic) Dolostone

    SciTech Connect (OSTI)

    Fara, D.R.

    1986-08-01

    Three conventional cores of the entire Trenton section were examined in detail by in-depth visual description, analysis of more than 250 thin sections, scanning electron microscopy, and x-ray diffraction. The cores are located in the northern half of Indiana where they span the major dolostone pinch-out that is the trap for the prolific Trenton oil and gas field. The Trenton Limestone is completely dolomitized in northern Indiana. Dolostone abundance decreases to the south where the dolostone is restricted to the upper few feet of the formation. Two major types of dolostone are recognized. The top 5-20 ft of the Trenton cores consists of medium crystalline nonporous xenotopic ferroan dolostone. Mesogenetic dewatering of the overlying Maquoketa shale is the proposed dolomitizing mechanisms for this ferroan dolostone cap. Below the ferroan dolostone cap in northern Indiana is coarsely crystalline dolostone, which consists of thin intercalated subfacies of porous idiotopic and nonporous xenotopic dolostone. This is the dominant dolostone type and is the reservoir in the Trenton field. The coarsely crystalline dolostone postdates the ferroan dolostone cap, chert nodule formation, and initial pressure solution. Therefore, this dolostone is considered to have formed relatively late in the diagenetic history of the Trenton under mesogenetic conditions. In the northernmost core, nearly all of the secondary dolomitic porosity is plugged by poikilotopic gypsum and minor amounts of calcite and celestite. Other diagenetic features observed in Trenton are also discussed, including silicification, ferroan calcite cement, upper Trenton contact formation, hardgrounds, and pressure solution.

  14. Summary of Research through Phase II/Year 2 of Initially Approved 3 Phase/3 Year Project - Establishing the Relationship between Fracture-Related Dolomite and Primary Rock Fabric on the Distribution of Reservoirs in the Michigan Basin

    SciTech Connect (OSTI)

    G. Grammer

    2007-09-30

    This final scientific/technical report covers the first 2 years (Phases I and II of an originally planned 3 Year/3 Phase program). The project was focused on evaluating the relationship between fracture-related dolomite and dolomite constrained by primary rock fabric in the 3 most prolific reservoir intervals in the Michigan Basin. The characterization of select dolomite reservoirs was the major focus of our efforts in Phases I and II of the project. Structural mapping and log analysis in the Dundee (Devonian) and Trenton/Black River (Ordovician) suggest a close spatial relationship among gross dolomite distribution and regional-scale, wrench fault-related NW-SE and NE-SW structural trends. A high temperature origin for much of the dolomite in these 2 studied intervals (based upon fluid inclusion homogenization temperatures and stable isotopic analyses,) coupled with persistent association of this dolomite in reservoirs coincident with wrench fault-related features, is strong evidence for these reservoirs being influenced by hydrothermal dolomitization. In the Niagaran (Silurian), there is a general trend of increasing dolomitization shelfward, with limestone predominant in more basinward positions. A major finding is that facies types, when analyzed at a detailed level, are directly related to reservoir porosity and permeability in these dolomites which increases the predictability of reservoir quality in these units. This pattern is consistent with our original hypothesis of primary facies control on dolomitization and resulting reservoir quality at some level. The identification of distinct and predictable vertical stacking patterns within a hierarchical sequence and cycle framework provides a high degree of confidence at this point that the results should be exportable throughout the basin. Much of the data synthesis and modeling for the project was scheduled to be part of Year 3/Phase III, but the discontinuation of funding after Year 2 precluded those efforts. Therefore, the results presented in this document are not final, and in many cases represent a report of 'progress to date' as numerous tasks were scheduled to extend into Year 3.

  15. Limestone County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Datasets Community Login | Sign Up Search Page Edit with form History Limestone County, Texas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates...

  16. Intermediate-scale tests of sodium interactions with calcite and dolomite aggregate concretes. [LMFBR

    SciTech Connect (OSTI)

    Randich, E.; Acton, R.U.

    1983-09-01

    Two intermediate-scale tests were performed to compare the behavior of calcite and dolomite aggregate concretes when attacked by molten sodium. The tests were performed as part of an interlaboratory comparison between Sandia National Laboratories and Hanford Engineering Development Laboratories. Results of the tests at Sandia National Laboratories are reported here. The results show that both concretes exhibit similar exothermic reactions with molten sodium. The large difference in reaction vigor suggested by thermodynamic considerations of CO/sub 2/ release from calcite and dolomite was not realized. Penetration rates of 1.4 to 1.7 mm/min were observed for short periods of time with reaction zone temperatures in excess of 800/sup 0/C during the energetic attack. The penetration was not uniform over the entire sodium-concrete contact area. Rapid attack may be localized due to inhomogeneities in the concrete. The chemical reaction zone is less then one cm thick for the calcite concrete but is about seven cm thick for the dolomite concrete.

  17. dlCC Opt: Optimization Software for Renewable Energy Projects - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Wind Energy Wind Energy Solar Thermal Solar Thermal Solar Photovoltaic Solar Photovoltaic Energy Analysis Energy Analysis Find More Like This Return to Search dlCC Opt: Optimization Software for Renewable Energy Projects National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary There are numerous options for renewable energy systems development. Location, size, type of system, and a number of other criteria need to be considered.

  18. SLAM: a sodium-limestone concrete ablation model

    SciTech Connect (OSTI)

    Suo-Anttila, A.J.

    1983-12-01

    SLAM is a three-region model, containing a pool (sodium and reaction debris) region, a dry (boundary layer and dehydrated concrete) region, and a wet (hydrated concrete) region. The model includes a solution to the mass, momentum, and energy equations in each region. A chemical kinetics model is included to provide heat sources due to chemical reactions between the sodium and the concrete. Both isolated model as well as integrated whole code evaluations have been made with good results. The chemical kinetics and water migration models were evaluated separately, with good results. Several small and large-scale sodium limestone concrete experiments were simulated with reasonable agreement between SLAM and the experimental results. The SLAM code was applied to investigate the effects of mixing, pool temperature, pool depth and fluidization. All these phenomena were found to be of significance in the predicted response of the sodium concrete interaction. Pool fluidization is predicted to be the most important variable in large scale interactions.

  19. Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash

    SciTech Connect (OSTI)

    De Weerdt, K.; Haha, M. Ben; Le Saout, G.; Kjellsen, K.O.; Justnes, H.; Lothenbach, B.

    2011-03-15

    The effect of minor additions of limestone powder on the properties of fly ash blended cements was investigated in this study using isothermal calorimetry, thermogravimetry (TGA), X-ray diffraction (XRD), scanning electron microscopy (SEM) techniques, and pore solution analysis. The presence of limestone powder led to the formation of hemi- and monocarbonate and to a stabilisation of ettringite compared to the limestone-free cements, where a part of the ettringite converted to monosulphate. Thus, the presence of 5% of limestone led to an increase of the volume of the hydrates, as visible in the increase in chemical shrinkage, and an increase in compressive strength. This effect was amplified for the fly ash/limestone blended cements due to the additional alumina provided by the fly ash reaction.

  20. ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH Al\rD SAFETY DlVlSlON

    Office of Legacy Management (LM)

    em IVIL, u-3 1' 1L, I -' I ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH Al\rD SAFETY DlVlSlON 1956 1. H.# fL22 Industrial Hygiene or Medical Dept. Sample Nor& 3 Date Collected- 5117 by --Route to CES CES r Location IQJKER-PEMJNS Co- Type of Sample-waternalyzed for F Alpha Remarks -&I GG -- u - Beta Samples of water discharged to river during Steam clean- No, Ra ing of equipment. Oil PH Be Th Sample No. Hour Sample Description (RT Please analyze for gm/U/gal. BP-1 P- RO-Kneader BP-2 K-

  1. ANALYTICAL DATA SHEET hlul ANALYTICAL DEPT. - HEALTH ANI SAFETY DlVlSlON

    Office of Legacy Management (LM)

    hlul ANALYTICAL DEPT. - HEALTH ANI SAFETY DlVlSlON Industrial Hygiene or Medical Dept. 1956 I. H.# 1093 Sample Nos. 9 -Date Collected- 812 by-L!LP Route to I"? Lo,--tionr\OGERS IRON CO. Type of Sample air %X!LAnalyzed for F Alphcxx Remarks JOYLIN, ~!ISSo~I -U Beta Four people involved in the test were H. Ruhe and W. K)epper No Ka -- of NLO. and J. Jones and L. Jones of Rogers Iron. No res- Oil3 PH piratory equipment used. -Be Th __- Sample No. Hour Sample Description )R T Q 9001 _ 1330 BZ

  2. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    SciTech Connect (OSTI)

    MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

    2000-08-01

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

  3. ANALYTICAL DATA SHEET ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlDN

    Office of Legacy Management (LM)

    ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlDN I -. . Industrial Hygiene or Medical Dept. 1956 I. H.# 984 Sample Nos. l2 Date Collected- o/2g by&- Route to J" Location SSi4.X CUiTn! CXJitP. Type of Sample&-dust Analyzed for F Alpha x Remarks P~UXC~JGIi.' ON. 14lCI11~ U Beta - IIoll0Wi.n~ slucs - NO, Ra Oil PH Be Th Sample No. 7573p Hour Sample Description 1355 CZ Orxxator sets slul: into place, closes shield over machine S starts &ill. oil coolant flows through hollow drill ____

  4. DEPXRTMEKT OF ENV]RO~:MENTAL F'ROTECTION DlVklOh OF

    Office of Legacy Management (LM)

    . * @.+<, .-- v 7, -e -5 u i' ;. - - : ,.:,, 4-.1M-4. a". : ' - l-1 &dp d 3-m 3jPr5Py DEPXRTMEKT OF ENV]RO~:MENTAL F'ROTECTION DlVklOh OF ~NVIR0N~Eh~A.L OUR' tiIn - . BUREAU OF R&DllmcN t=ROTE~lOH ' 1 ,_ jBD 5cOTCH ROAD. ~R~%~obi. fd. 1. 08628 .' - ._ -_ _ . . : S=_srterrjer 27, 1977 - ,. _ :.- ,_..I \ L . x=- a-. JEC): f' eust C--l L-9 ,c:c- -*r 2ze E&f&y _3=iz=Et=g cr;i\' ==Siq ' ---res"LE;, c2iiIps - de- ~-z7~~to3, Bew --d Jersey DE540 3ez' -- . w- Tecsk: i 25,

  5. Seismic model of a progradational carbonate platform, Picco di Vallandro, the Dolomites, northern Italy

    SciTech Connect (OSTI)

    Biddle, K.T.; Bush, T.L. ); Schlager, W. ); Rudolph, K.W. )

    1992-01-01

    The authors present a seismic model of a well-exposed carbonate platform-to-basin transition from the Triassic succession at Picco di Vallandro, the Dolomites, northern Italy. The core of this model is a detailed lithologic cross section that represents 1,500 m of stratigraphic section over a distance of 3.5 km. The cross section is based on detailed measured sections, photo interpretation, and careful projection of surface mapping into the plane of section. Samples from the measured sections provide control on velocity and density distribution, and these data were used to generate an impedance model from the cross section. The impedance model was convolved with a zero-phase, 25-Hz peak-frequency wavelet to produce the seismic model. The results illustrate how the platform-to-basin transition might be imaged by conventional seismic reflection data, how the reflections relate to the distribution of lithology and through-going geological surfaces, and how constructive and destructive interference and seismic resolution combine to produce individual reflections.

  6. Rate of reaction of hydrogen sulfide-carbonyl sulfide mixtures with fully calcined dolomite

    SciTech Connect (OSTI)

    Kamath, V.S.; Petrie, T.W.

    1981-01-01

    Kinetic data are obtained by a gravimetric technique for rates of reaction of calcium oxide in fully calcined dolomite with hydrogen sulfide and hydrogen sulfide-carbonyl sulfide mixtures. The data are presented as values for a factor k defined by d(CAO) = -k (CAO) dt. At 600, 700, and 800 degrees C with (H/sub 2/S) from 0.5% to 5.0% by volume and (H/sub 2/S)/(COS) = 20 for mixtures, expressions for k show apparent rate constants and the dependence on sulfurous gas concentration. For example, at 700 degrees C, k = 1.43 x 10/sup -4/ (h2s) 1.06/S and k = 1.70 x 10/sup -4/ (H/sub 2/S + COS) 1.00/s. Since the date show first-order dependence on calcium oxide, k's for H/sub 2/S alone as the sulfurous gas and h2s-cos mixtures can be obtained for the same sample, free from scatter due to variations from sample to sample. Addition of values for k from runs with H/sub 2/S as the only sulfurous gas and runs with COS as the only sulfurous gas are compared to measurements with actual mixtures. K's for the mixtures are approximately 30% higher than the sum of the appropriate separate values.

  7. Petrography study of two siliceous limestones submitted to alkali-silica reaction

    SciTech Connect (OSTI)

    Monnin, Y. . E-mail: monnin@ensm-douai.fr; Degrugilliers, P.; Bulteel, D.; Garcia-Diaz, E.

    2006-08-15

    This study presents the contribution of petrography to the comprehension of the alkali-silica reaction mechanism applied to two siliceous limestones. A petrography study was made on the two aggregates before reaction to define their relative proportions and types of reactive silica and to observe their distribution in the microstructure. Then a model reactor, constituted by the reactive siliceous limestone aggregate, portlandite and NaOH, was used to measure the swelling due to reaction of the silica with alkalis and the free expansion of the aggregates. The volume evolution between both aggregates was very different and could be explained by the preliminary petrographic study. It appears that the swelling of the aggregates is conditioned by the microstructure of the carbonated matrix, the quantity and the distribution of the reactive silica.

  8. Intermediate-scale sodium-concrete reaction tests with basalt and limestone concrete

    SciTech Connect (OSTI)

    Hassberger, J.A.; Muhlestein, L.D.

    1981-01-01

    Ten tests were performed to investigate the chemical reactions and rate and extent of attack between sodium and basalt and limestone concretes. Test temperatures ranged from 510 to 870/sup 0/C (950 to 1600/sup 0/F) and test times from 2 to 24 hours. Sodium hydroxide was added to some of the tests to assess the impact of a sodium hydroxide-aided reaction on the overall penetration characteristics. Data suggest that the sodium penetration of concrete surfaces is limited. Penetration of basalt concrete in the presence of sodium hydroxide is shown to be less severe than attack by the metallic sodium alone. Presence of sodium hydroxide changes the characteristics of sodium penetration of limestone concrete, but no major differences in bulk penetration were observed as compared to penetration by metallic sodium.

  9. Establishing the Relationship between Fracture-Related Dolomite and Primary Rock Fabric on the Distribution of Reservoirs in the Michigan Basin

    SciTech Connect (OSTI)

    G. Michael Grammer

    2006-09-30

    This topical report covers the year 2 of the subject 3-year grant, evaluating the relationship between fracture-related dolomite and dolomite constrained by primary rock fabric in the 3 most prolific reservoir intervals in the Michigan Basin (Ordovician Trenton-Black River Formations; Silurian Niagara Group; and the Devonian Dundee Formation). The characterization of select dolomite reservoirs has been the major focus of our efforts in Phase II/Year 2. Fields have been prioritized based upon the availability of rock data for interpretation of depositional environments, fracture density and distribution as well as thin section, geochemical, and petrophysical analyses. Structural mapping and log analysis in the Dundee (Devonian) and Trenton/Black River (Ordovician) suggest a close spatial relationship among gross dolomite distribution and regional-scale, wrench fault related NW-SE and NE-SW structural trends. A high temperature origin for much of the dolomite in the 3 studied intervals (based upon initial fluid inclusion homogenization temperatures and stable isotopic analyses,) coupled with persistent association of this dolomite in reservoirs coincident with wrench fault-related features, is strong evidence for these reservoirs being influenced by hydrothermal dolomitization. For the Niagaran (Silurian), a comprehensive high resolution sequence stratigraphic framework has been developed for a pinnacle reef in the northern reef trend where we had 100% core coverage throughout the reef section. Major findings to date are that facies types, when analyzed at a detailed level, have direct links to reservoir porosity and permeability in these dolomites. This pattern is consistent with our original hypothesis of primary facies control on dolomitization and resulting reservoir quality at some level. The identification of distinct and predictable vertical stacking patterns within a hierarchical sequence and cycle framework provides a high degree of confidence at this point that results will be exportable throughout the basin. Ten petrophysically significant facies have been described in the northern reef trend, providing significantly more resolution than the standard 4-6 that are used most often in the basin (e.g. Gill, 1977). Initial petrophysical characterization (sonic velocity analysis under confining pressures) shows a clear pattern that is dependent upon facies and resulting pore architecture. Primary facies is a key factor in the ultimate diagenetic modification of the rock and the resulting pore architecture. Facies with good porosity and permeability clearly show relatively slow velocity values as would be expected, and low porosity and permeability samples exhibit fast sonic velocity values, again as expected. What is significant is that some facies that have high porosity values, either measured directly or from wireline logs, also have very fast sonic velocity values. This is due to these facies having a pore architecture characterized by more localized pores (vugs, molds or fractures) that are not in communication.

  10. Seismic models of a carbonate foreslope-to-basin transition, Picco di Vallandro, Dolomite Alps, northern Italy

    SciTech Connect (OSTI)

    Rudolph, K.W. ); Schlager, W. ); Biddle, K.T. )

    1989-05-01

    Detailed geologic cross sections, augmented by laboratory calibration of lithology and acoustic impedance, have been used to produce synthetic reflection seismic sections of a carbonate foreslope-to-basin transition. Two areas from the Picco di Vallandro region of the Dolomite Alps were modeled: a progradational section and a retrogradational (backstepping) section. The resulting models show how these complex areas of strata interfingering might be displayed on conventional reflection seismic lines. In the area of progradation, rapid stratigraphic thinning below seismic detectibility, coupled with abrupt impedance changes, produces a reflection discontinuity between steeply dipping reflections of the foreslope and gently dipping paralle reflections of the basin section. This apparent downlap surface marks the toe-of-slope for successive clinoforms but dose not correspond to a discrete stratigraphic surface. In the backstepping example, similar stratigraphic thinning and impedance changes create an apparent onlap surface. Wavelet interference causes complications in both examples. These models indicate how stratigraphic complexity can be simplified by the seismic reflection process and suggest that caution should be exercised when using seismic data to construct general models in areas of complex depositional geometries and rapidly changing facies.

  11. Laboratory evaluation of limestone and lime neutralization of acidic uranium mill tailings solution. Progress report

    SciTech Connect (OSTI)

    Opitz, B.E.; Dodson, M.E.; Serne, R.J.

    1984-02-01

    Experiments were conducted to evaluate a two-step neutralization scheme for treatment of acidic uranium mill tailings solutions. Tailings solutions from the Lucky Mc Mill and Exxon Highland Mill, both in Wyoming, were neutralized with limestone, CaCO/sub 3/, to an intermediate pH of 4.0 or 5.0, followed by lime, Ca(OH)/sub 2/, neutralization to pH 7.3. The combination limestone/lime treatment methods, CaCO/sub 3/ neutralization to pH 4 followed by neutralization with Ca(OH)/sub 2/ to pH 7.3 resulted in the highest quality effluent solution with respect to EPA's water quality guidelines. The combination method is the most cost-effective treatment procedure tested in our studies. Neutralization experiments to evaluate the optimum solution pH for contaminant removal were performed on the same two tailings solutions using only lime Ca(OH)/sub 2/ as the neutralizing agent. The data indicate solution neutralization above pH 7.3 does not significantly increase removal of pH dependent contaminants from solution. Column leaching experiments were performed on the neutralized sludge material (the precipitated solid material which forms as the acidic tailings solutions are neutralized to pH 4 or above). The sludges were contacted with laboratory prepared synthetic ground water until several effluent pore volumes were collected. Effluent solutions were analyzed for macro ions, trace metals and radionuclides in an effort to evaluate the long term effectiveness of attenuating contaminants in sludges formed during solution neutralization. Neutralized sludge leaching experiments indicate that Ca, Na, Mg, Se, Cl, and SO/sub 4/ are the only constituents which show solution concentrations significantly higher than the synthetic ground water in the early pore volumes of long-term leaching studies.

  12. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    Office of Scientific and Technical Information (OSTI)

    3 (2014) 4684 - 4707 Energy Procedia GHGT-12 Geochemical impacts of carbon dioxide, brine, trace metal and organic leakage into an unconfined, oxidizing limestone aquifer Diana H. Bacon3'* *, Zhenxue Daib, Liange Zhengc "Pacific Northwest National Laboratory, Richland, Washington, USA bLos Alamos National Laboratory, Los Alamos, New Mexico, USA cLawrence Berkeley National Laboratory, Berkeley, California, USA Abstract An important risk at CO2 storage sites is the potential for groundwater

  13. Regional analysis of rhythmic bedding in the Fort Hays limestone member, Niobrara Formation (Upper Cretaceous), US western interior

    SciTech Connect (OSTI)

    Laferriere, A.P.

    1987-01-01

    Results of a regional stratigraphic investigation of the rhythmically bedded Fort Hays limestone member of Kansas, Colorado, and New Mexico indicate at least two levels of cyclicity. Regional development of these cycles strongly supports the hypothesis that they are climatic in origin. Departures from simple cyclical patterns resulted from sedimentary effects of Late Cretaceous orogenic activity, erosional events associated with eustatic sea level changes, diagenetic modification, and possibly from interference between orbital parameters having different periodicities. The vulnerability of Milankovitch-type cyclicity to overprinting by tectono-sedimentologic effects makes units such as the Fort Hays useful as indicators of subtle tectonic activity. Regional thickness changes in groups of shale-limestone couplets were identified, correlated, and mapped in the subsurface using geophysical well log information in order to locate subtle structural elements that influenced Fort Hays sedimentation. In the Denver-Julesburg Basin of Colorado and western Kansas, thinning of the section between Fort Hays marker horizons occurs dominantly along northeastwardly trending belts that resulted apparently from Late Cretaceous reactivation of the Transcontinental Arch. Isotopic and petrographic analyses were conducted on pelagic (carbonate matrix) and benthic (inoceramid bivalve) constituents of selected shale/limestone couplets. These data suggest that there was little difference in temperature or salinity between times of terrigenous detrital input and times of nearly pure carbonate deposition. Isotopic information from matrix samples suggests a westward decrease in salinity of surface water in the Western Interior Sea. Isotopic data from largely unaltered inoceramid bivalves indicate bottom-water conditions of near-normal marine salinity.

  14. Phase I (Year 1) Summary of Research--Establishing the Relationship between Fracture-Related Dolomite and Primary Rock Fabric on the Distribution of Reservoirs in the Michigan Basin

    SciTech Connect (OSTI)

    G. Michael Grammer

    2005-11-09

    This topical report covers the first 12 months of the subject 3-year grant, evaluating the relationship between fracture-related dolomite and dolomite constrained by primary rock fabric in the 3 most prolific reservoir intervals in the Michigan Basin (Ordovician Trenton-Black River Formations; Silurian Niagara Group; and the Devonian Dundee Formation). Phase I tasks, including Developing a Reservoir Catalog for selected dolomite reservoirs in the Michigan Basin, Characterization of Dolomite Reservoirs in Representative Fields and Technology Transfer have all been initiated and progress is consistent with our original scheduling. The development of a reservoir catalog for the 3 subject formations in the Michigan Basin has been a primary focus of our efforts during Phase I. As part of this effort, we currently have scanned some 13,000 wireline logs, and compiled in excess of 940 key references and 275 reprints that cover reservoir aspects of the 3 intervals in the Michigan Basin. A summary evaluation of the data in these publications is currently ongoing, with the Silurian Niagara Group being handled as a first priority. In addition, full production and reservoir parameter data bases obtained from available data sources have been developed for the 3 intervals in Excel and Microsoft Access data bases. We currently have an excess of 25 million cells of data for wells in the Basin. All Task 2 objectives are on time and on target for Phase I per our original proposal. Our mapping efforts to date, which have focused in large part on the Devonian Dundee Formation, have important implications for both new exploration plays and improved enhanced recovery methods in the Dundee ''play'' in Michigan--i.e. the interpreted fracture-related dolomitization control on the distribution of hydrocarbon reservoirs. In an exploration context, high-resolution structure mapping using quality-controlled well data should provide leads to convergence zones of fault/fracture trends that are not necessarily related to structural elevation. Further work in Phase II will be focused on delineating the relative contribution to fracture-only dolomitization to that which occurs in conjunction with primary facies and/or sequence stratigraphic framework.

  15. Numerical simulation of ground-water flow in the Culebra dolomite at the Waste Isolation Pilot Plant (WIPP) site: Second interim report

    SciTech Connect (OSTI)

    LaVenue, A.M.; Haug, A.; Kelley, V.A.

    1988-03-01

    This hydrogeologic modeling study has been performed as part of the regional hydrologic characterization of the Waste Isolation Pilot Plant (WIPP) Site in southeastern New Mexico. The study resulted in an estimation of the transmissivity distrubution, hydraulic potentials, flow field, and fluid densities in the Culebra Dolomite Member of the Permian Rustler Formation at the WIPP site. The three-dimensional finite-difference code SWIFT-II was employed for the numerical modeling, using variable-fluid-density and a single-porosity formulation. The modeled area includes and extends beyond the WIPP controlled zone (Zone 3). The work performed consisted of modeling the hydrogeology of the Culebra using two approaches: (1) steady-state modeling to develop the best estimate of the undisturbed head distribution, i.e., of the situation before sinking if the WIPP shafts, which began in 1981; and (2) superimposed transient modeling of local hydrologic responses to excavation of the three WIPP shafts at the center of the WIPP site, as well as to various well tests. Boundary conditions (prescribed constant fluid pressures and densities) were estimated using hydraulic-head and fluid-density data obtained from about 40 wells at and near the WIPP site. The transient modeling used the calculated steady-state freshwater heads as initial conditions. 107 refs., 112 figs., 22 tabs.

  16. Retrofit costs for lime/limestone FGD and lime spray drying at coal-fired utility boilers

    SciTech Connect (OSTI)

    Emmel, T.E.; Jones, J.W.

    1990-01-01

    The paper gives results of a research program the objective of which was to significantly improve engineering cost estimates currently being used to evaluate the economic effects of applying SO2 controls to existing coal-fired utility boilers. The costs of retrofitting conventional lime/limestone wet flue gas desulfurization (L/LS FGD) and lime spray drying (LSD) FGD at 100-200 coal-fired power plants are being estimated under this program. The retrofit capital cost estimating procedures used for L/LS FGD and LSD FGD make two cost adjustments to current procedures used to estimate FGD costs: cost adders (for items not normally included in FGD system costs; e.g., demolition and relocation of existing facilities) and cost multipliers (to adjust capital costs for site access, congestion, and underground obstructions).

  17. Pilot-scale limestone emission control (LEC) process: A development project. Volume 1: Main report and appendices A, B, C, and D. Final report

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    ETS, Inc., a pollution consulting firm with headquarters in Roanoke, Virginia, has developed a dry, limestone-based flue gas desulfurization (FGD) system. This SO{sub 2} removal system, called Limestone Emission Control (LEC), can be designed for installation on either new or existing coal-fired boilers. In the LEC process, the SO{sub 2} in the flue gas reacts with wetted granular limestone that is contained in a moving bed. A surface layer of principally calcium sulfate (CaSO{sub 4}) is formed on the limestone. Periodic removal of this surface layer by mechanical agitation allows high utilization of the limestone granules. The primary goal of the current study is the demonstration of the techno/economic capability of the LEC system as a post-combustion FGD process capable of use in both existing and future coal-fired boiler facilities burning high-sulfur coal. A nominal 5,000 acfm LEC pilot plant has been designed, fabricated and installed on the slipstream of a 70,000 pph stoker boiler providing steam to Ohio University`s Athens, Ohio campus. The pilot plant was normally operated on the slipstream of the Ohio Univ. boiler plant flue gas, but also had the capability of operating at higher inlet SO{sub 2} concentrations (typically equivalent to 3-1/2% sulfur coal) than those normally available from the flue gas slipstream. This was accomplished by injecting SO{sub 2} gas into the slipstream inlet. The pilot plant was instrumented to provide around-the-clock operation and was fully outfitted with temperature, SO{sub 2}, gas flow and pressure drop monitors.

  18. Sequence stratigraphy of carbonate buildups developed in an active tectonic/volcanic setting: Triassic (Late Ladinian and Carnian) of the Dolomites, northern Italy

    SciTech Connect (OSTI)

    Yose, L.A. ); Littmann, P. )

    1991-03-01

    Late Ladinian and Carnian deposits of the Dolomites record the evolution of carbonate buildups developed during the waning phases of a major period of volcanism and strike-slip tectonics. Each separate buildup provides an independent record of eustasy, tectonism, and competing carbonate and volcaniclastic sedimentation. Palynomorphs, calibrated with ammonites, are used to correlate between buildups and provide a means for distinguishing local variations in buildup histories from regional, synchronous trends in sedimentation which may record third-order eustasy. Although individual buildup histories vary dramatically, two depositional sequences may be recorded at a regional scale: one of late Ladinian age (early to late Longobardian) and another of late Ladinian to middle Carnian age (late Longobardian to Cordevolian). A relative sea-level fall in the late Ladinian resulted in an increased supply of volcaniclastics that onlap the flanks of many buildups and/or downslope shifts in carbonate production. Buildups of the second sequence developed in response to a relative sea-level rise and are similar in diversity to those of the first sequence. Extensive buildup progradation and accretion during this phase, concomitant with mixed-carbonate/volcaniclastic basin filling and diminished tectonic activity, result in a regional suturing of the complex paleogeography developed during the middle Ladinian. Local paleogeography, determined by the distribution of earlier platforms in addition to tectonic and volcanogenic processes, is interpreted as the primary control over buildup geometries and the variability of buildups within sequences. However, the regional extent and synchroneity of the sequences described above many record third-order eustasy.

  19. Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system

    SciTech Connect (OSTI)

    Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

    1991-01-01

    Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

  20. TEAM0.5DL.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Instrument preparation Show how to check basic vacuum functionality and target pressure values (Gun: 1, Liner: 18-20 and Octagon: < 10) Check Gun operate "ON" and ...

  1. Microsoft Word - mitchell-dl.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterizing Particle Size, Water Path and Photon Tunneling in Ice and Water Clouds David L. Mitchell Atmospheric Sciences Division Desert Research Institute Reno, Nevada Robert P. d'Entremont Satellite Meteorology Group Atmospheric and Environmental Research, Inc. Lexington, Massachusetts Abstract Global information of ice water path (IWP) in ice clouds is urgently needed for testing of global climate models (GCMs) and other applications, but satellite retrievals of IWP are still in the

  2. CM200DL-Final.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Core Status: new users must complete 2 trouble free training sessions and pass the drivers test to work independently during Core sessions. Flex Status: core users must complete 5...

  3. Petrology of lower and middle Eocene carbonate rocks, Floridan aquifer, central Florida

    SciTech Connect (OSTI)

    Thayer, P.A.; Miller, J.A.

    1984-09-01

    Study of cores from a US Geological Survey test well near Polk City, Florida, indicates that the Avon Park-Lake City (Claibornian) and Oldsmar (Sabinian) Limestones, which comprise most of the Floridan aquifer in central Florida, can be divided into six microfacies: foraminiferal mudstone, foraminiferal wackestone-packstone, foraminiferal grainstone, nodular anhydrite, laminated dolomicrite, and replacement dolomite. Dolomite containing variable amounts of nodular anhydrite forms more than 90% of the Avon Park-Lake city interval, whereas thte Oldsmar is chiefly limestone. Several episodes of dolomite formation are recognized. Laminated dolomicrite formed syngenetically in a supratidal-sabhka environment. Crystalline dolomite with nodular anhydrite formed early by replacement of limestone through reflux of dense, magnesium-rich brines. Replacement dolomite not associated with evaporites and containing limpid crystals probably formed later by a mixed-water process in the subsurface environment. Late diagenetic processes affecting crystalline dolomites include hydration of anhydrite to gypsum, partial dissolution of gypsum, minor alteration of gypsum to calcite, and dissolution of calcian dolomite cores in stoichiometric crystals. Crystalline dolomite and grainstone are the only rock types that have high enough porosities and permeabilities to provide significant yields of water. Medium and finely crystalline dolomites show best values of porosity and permeability because they have high percentages of intercrystal and moldic pores that are well connected. Filling of pores by anhydrite or gypsum can significantly reduce porosity and permeability.

  4. Generalized thickness and configuration of the top of the intermediate aquifer, West-Central Florida

    SciTech Connect (OSTI)

    Corral, M.A. Jr.; Wolansky, R.M.

    1984-01-01

    The water-bearing units of the intermediate aquifer consist of discontinuous sand, gravel, shell, and limestone and dolomite beds in the Tamiami Formation of late Miocene age and the Hawthorn Formation of middle Miocene age. Within parts of Polk, Manatee, Hardee, De Soto, Sarasota, and Charlotte Counties, sand and clay beds within the Tampa Limestone that are hydraulically connected to the Hawthorn Formation are also included in the intermediate aquifer. 15 refs.

  5. Mineral resources of the Cross Mountain Wilderness Study Area, Moffat County, Colorado

    SciTech Connect (OSTI)

    Evans, K.V.; Frisken, J.G.; Kulik, D.M.; Thompson, J.R.

    1989-01-01

    The Cross Mountain Wilderness Study Area, in northwestern Colorado, contains high-purity limestone suitable for industrial and agricultural use; dolomitic limestone suitable for agricultural use; and limestone, dolomite, sandstone, and sand and gravel suitable for use as construction materials. There has been no mining within this study area. This entire study area has a low mineral resource potential for sediment-hosted copper in the Uinta Mountain Group, and parts of this study area have a low resource potential for sandstone-type uranium-vanadium in sedimentary rocks. The entire study area has a low resource potential for all other metals and geothermal resources. It has a high energy resource potential for oil and gas in the eastern part of the area and moderate potential elsewhere. This study area has no mineral resource potential for coal.

  6. Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams

    SciTech Connect (OSTI)

    Towler, G.P.; Lynn, S.

    1993-05-01

    Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

  7. Limestone County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ardmore, Alabama Athens, Alabama Decatur, Alabama Elkmont, Alabama Huntsville, Alabama Lester, Alabama Madison, Alabama Mooresville, Alabama Retrieved from "http:en.openei.orgw...

  8. Early rifting deposition: examples from carbonate sequences of Sardinia (Cambrian) and Tuscany (Triassic-Jurassic), Italy: an analogous tectono-sedimentary and climatic context

    SciTech Connect (OSTI)

    Cocozza, T.; Gandin, A.

    1987-05-01

    Lower Cambrian Ceroide Limestone (Sardinia) and Lower Jurassic Massiccio Limestone (Tuscany) belong to sequences deposited in analogous tectono-sedimentary context: the former linked to the Caledonian Sardic Phase, the latter to the Alpine Orogeny. Both units consist of massive pure limestone characterized by marginal and lagoonal sequences repeatedly interfingering in the same geological structure. This distribution indicates a morphology of the platforms composed of banks (marginal facies) and shallow basins (lagoonal facies) comparable with a Bahamian complex. Dolomitization affects patchily the massive limestone bodies, and karstic features, breccias, and sedimentary dikes occur at their upper boundary. Both units overlie early dolomite and evaporites (sabkha facies) containing siliciclastic intercalations in their lower and/or upper part and are unconformably covered by open-shelf red (hematitic), nodular limestone Ammonitico Rosso facies). The sedimentary evolution of the two sequences appears to have been controlled by synsedimentary tectonics whose major effects are the end of the terrigenous input, the bank-and-basin morphology of the platform, the irregular distribution of the dolomitization, and the nodular fabric of the overlying facies. The end of the Bahamian-type system is marked by the karstification of the emerged blocks and is followed by their differential sinking and burial under red-nodular facies. From a geodynamic viewpoint, sequences composed of Bahamian-like platform carbonates followed by Ammonitico Rosso facies imply deposition along continental margins subjected to block-faulting during an extensional regime connected with the beginning of continental rifting. Moreover, the variation from sabkha to Bahamian conditions suggests the drifting of the continent from arid to humid, tropical areas.

  9. 3.1.1.2 Feed Processing and Handling DL2 Final Report

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Magnuson, Jon K.; Wend, Christopher F.

    2006-09-30

    This milestone report is the deliverable for our Feed Processing and Handling project. It includes results of wet biomass feedstock analysis, slurry pumping information, fungal processing to produce a lignin-rich biorefinery residue and two subcontracted efforts to quantify the amount of wet biomass feedstocks currently available within the corn processing and paper processing industries.

  10. Formation of dl-limonene in used tire vacuum pyrolysis oils. [dipentene

    SciTech Connect (OSTI)

    Pakdel, H.; Roy, C.; Aubin, H.; Jean, G. ); Coulombe, S. )

    1991-09-01

    Tire recycling has become an important environmental issue recently due to the huge piles of tires that threaten the environment. Thermal decomposition of tire, a synthetic rubber material, enables the recovery of carbon black and liquid hydrocarbon oils. Both have potential economic values. Pyrolysis oils obtained under vacuum conditions contain a significant portion of a volatile, naptha-like fraction with an octane number similar to petroleum naphtha fraction, in addition, contains approximately 15% limonene. Potential applications of vacuum pyrolysis oil and carbon black have been investigated. However, the process economics is greatly influenced by the quality of the oil and carbon black products. This paper discusses limonene formation during used tire vacuum pyrolysis and its postulated reaction mechanism. The limonene separation method from pyrolysis oil, as well as its purification in laboratory scale, and structural characterization are discussed. Large-scale limonene separation and purification is under investigation.

  11. PMC*Fr.. U.S. Dl?PARThIENT OFFNFRGY EERE PROJECT MANAGEMENT CE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... and *22.1.4 (ocean deployment), due to insufficient information and required consultation with the National Marine Fisheries Service, per Section 7 of the Endangered Species Act. ...

  12. DOE/SC-ARM-13-003 ARM Lead Mentor Selection Process DL Sisterson

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    facility. The ARM Climate Research Facility currently operates more than 300 instrument systems that provide ground-based observations of the atmospheric column. To keep ARM at...

  13. CREATING A GEOLOGIC PLAY BOOK FOR TRENTON-BLACK RIVER APPALACHIAN BASIN EXPLORATION

    SciTech Connect (OSTI)

    Douglas G. Patchen; Katharine Lee Avary; John M. Bocan; Michael Hohn; John B. Hickman; Paul D. Lake; James A. Drahovzal; Christopher D. Laughrey; Jaime Kostelnik; Taury Smith; Ron Riley; Mark Baranoski

    2005-04-01

    The Trenton-Black River Appalachian Basin Research Consortium has made significant progress toward their goal of producing a geologic play book for the Trenton-Black River gas play. The final product will include a resource assessment model of Trenton-Black River reservoirs; possible fairways within which to concentrate further studies and seismic programs; and a model for the origin of Trenton-Black River hydrothermal dolomite reservoirs. All seismic data available to the consortium have been examined. Synthetic seismograms constructed for specific wells have enabled researchers to correlate the tops of 15 stratigraphic units determined from well logs to seismic profiles in New York, Pennsylvania, Ohio, West Virginia and Kentucky. In addition, three surfaces for the area have been depth converted, gridded and mapped. A 16-layer velocity model has been developed to help constrain time-to-depth conversions. Considerable progress was made in fault trend delineation and seismic-stratigraphic correlation within the project area. Isopach maps and a network of gamma-ray cross sections supplemented with core descriptions allowed researchers to more clearly define the architecture of the basin during Middle and Late Ordovician time, the control of basin architecture on carbonate and shale deposition and eventually, the location of reservoirs in Trenton Limestone and Black River Group carbonates. The basin architecture itself may be structurally controlled, and this fault-related structural control along platform margins influenced the formation of hydrothermal dolomite reservoirs in original limestone facies deposited in high energy environments. This resulted in productive trends along the northwest margin of the Trenton platform in Ohio. The continuation of this platform margin into New York should provide further areas with good exploration potential. The focus of the petrographic study shifted from cataloging a broad spectrum of carbonate rocks that occur in the Trenton-Black River interval to delineation of regional limestone diagenesis in the basin. A consistent basin-wide pattern of marine and burial diagenesis that resulted in relatively low porosity and permeability in the subtidal facies of these rocks has been documented across the study area. Six diagenetic stages have been recognized: four marine diagenesis stages and two burial diagenesis stages. This dominance of extensive marine and burial diagenesis yielded rocks with low reservoir potential, with the exception of fractured limestone and dolostone reservoirs. Commercial amounts of porosity, permeability and petroleum accumulation appear to be restricted to areas where secondary porosity developed in association with hydrothermal fluid flow along faults and fractures related to basement tectonics. A broad range of geochemical and fluid inclusion analyses have aided in a better understanding of the origin of the dolomites in the Trenton and Black River Groups over the study area. The results of these analyses support a hydrothermal origin for all of the various dolomite types found to date. The fluid inclusion data suggest that all of the dolomite types analyzed formed from hot saline brines. The dolomite is enriched in iron and manganese, which supports a subsurface origin for the dolomitizing brine. Strontium isotope data suggest that the fluids passed through basement rocks or immature siliciclastic rocks prior to forming the dolomites. All of these data suggest a hot, subsurface origin for the dolomites. The project database continued to be redesigned, developed and deployed. Production data are being reformatted for standard relational database management system requirements. Use of the project intranet by industry partners essentially doubled during the reporting period.

  14. STRATIGRAPHY OF THE CAMBO-ORDOVICIAN SUCCESSION IN ILLINOIS

    SciTech Connect (OSTI)

    Lasemi, Yaghoob; Khorasgani, Zohreh; Leetaru, Hannes

    2014-09-30

    The Upper Cambrian through Lower Ordovician succession (Sauk II-III sequences) in the Illinois Basin covers the entire state of Illinois and most of the states of Indiana and Kentucky. To determine lateral and vertical lithologic variations of the rocks within the Cambro-Ordovician deposits that could serve as reservoir or seal for CO2 storage, detailed subsurface stratigraphic evaluation of the succession in Illinois was conducted. The Cambro-Ordovician succession in the Illinois Basin consists of mixed carbonate-siliciclastic deposits. Its thickness ranges from nearly 800 feet in the extreme northwest to nearly 8000 feet in the Reelfoot Rift in the extreme southeastern part of the state. In northern and central Illinois, the Cambro-Ordovician rocks are classified as the Cambrian Knox and the Ordovician Prairie du Chien Groups, which consist of alternating dolomite and siliciclastic units. In the southern and deeper part of the Illinois Basin, the Cambro-Ordovician deposits consist chiefly of fine to coarsely crystalline dolomite capped by the Middle Ordovician Everton Formation. Detailed facies analysis indicates that the carbonate units consist mainly of mudstone to grainstone facies (fossiliferous/oolitic limestone and dolomite) with relics of bioclasts, ooids, intraclasts and peloids recording deposition on a shallow marine ramp setting. The dominant lithology of the Knox and the overlying Prairie du Chien Group is fine to coarsely crystalline, dense dolomite. However, porous and permeable vugular or fractured/cavernous dolomite intervals that grade to dense fine to coarsely crystalline dolomite are present within the dolomite units. Several hundred barrels of fluid were lost in some of these porous intervals during drilling, indicating high permeability. The sandstone intervals are porous and permeable and are texturally and compositionally mature. The permeable sandstone and porous dolomite intervals are laterally extensive and could serve as important reservoirs to store natural gas, CO2 or hazardous waste material. Results of this study show that the Cambro-Ordovician Knox Group in the Illinois Basin and adjacent Midwestern regions may be an attractive target for CO2 sequestration because these rocks are 1) laterally extensive, 2) consist of some porous and permeable dolomite and sandstone intervals, and 3) contain abundant impermeable shale and carbonate seals.

  15. Petroleum potential of lower and middle Paleozoic rocks in Nebraska portion of Mid-Continent

    SciTech Connect (OSTI)

    Carlson, M.P. )

    1989-08-01

    Central North America during the Paleozoic was characterized by northern (Williston) and southern (Anadarko) depositional regimes separated by a stable Transcontinental arch. Nebraska lies on the southern flank of this arch and contains the northern zero edges of the lower and middle Paleozoic rocks of the southern regime. Most of these rocks are secondary dolomites with zones of excellent intercrystalline porosity. The Reagan-LaMotte Sandstones and the overlying Arbuckle dolomites are overlapped by Middle Ordovician rocks toward the Transcontinental arch. Rocks equivalent to the Simpson consist of a basal sand (St. Peter) and overlying interbedded gray-green shales and dolomitic limestones. An uppermost shale facies is present in the Upper Ordovician (Viola-Maquoketa) eastward and southward across Nebraska. The dolomite facies extends northward into the Williston basin. The Silurian dolomites, originally more widely deposited, are overlapped by Devonian dolomites in southeastern Nebraska. Upper Devonian rocks exhibit a regional facies change from carbonate to green-gray shale to black shale southeastward across the Mid-Continent. Mississippian carbonates overlap the Devonian westward and northward across the Transcontinental arch. Pennsylvanian uplift and erosion were widespread, producing numerous stratigraphic traps. Sands related to the basal Pennsylvanian unconformity produce along the Cambridge arch. Arbuckle, Simpson, Viola, and Hunton production is present in the Forest City basin and along the Central Kansas uplift. Although source rocks are scarce and the maturation is marginal, current theories of long-distance oil migration encourage exploration in the extensive lower and middle Paleozoic reservoirs in this portion of the Mid-Continent.

  16. Removal of H{sub 2}S by spray-calcined calcium acetate

    SciTech Connect (OSTI)

    Nimmo, W.; Agnew, J.; Hampartsoumian, E.; Jones, J.M.

    1999-08-01

    The effectiveness of wet-spraying calcium acetate as an alternative to limestone and dolomite for the desulfurization of flue gases (in particular, H{sub 2}S removal from coal gas) has been investigated by experimental studies using drop tube (DTR) and fixed-bed flow reactors (FBR). Calcium acetate solution was spray-calcined in the DTR at temperatures of 1073 and 1323 K. At the lower temperature, conversions approaching 80% were found at the longest residence time studied, 0.8 s. On the other hand, the higher temperature condition initially showed a much greater rate of calcination, indicated by greater conversion at shorter residence times, but was then followed by a much slower rate beyond 0.4 s. The final degree of conversion was in the region of 70%. Batches of spray-calcined calcium acetate (SCA), limestone, and dolomite, prepared in the DTR at 1323 K, to 70% conversion, were sulfided in the FBR at temperatures of 873 and 1173 K to assess their relative sulfur capture reactivities. Significantly higher conversions were achieved by the spray-calcined material, especially at the higher FBR temperature (1173 K) where a difference in conversion of more than 40% was observed. The physical structure of the particles formed from wet-spray calcination were determined by electron microscopy and showed highly porous cenospheres with large internal voids and an outside surface characterized by blowholes of between 1 and 10 {micro}m in diameter. As a consequence, the available surface area for reaction with H{sub 2}S is greater than with limestone or dolomite, producing a 4-fold difference in the level of particle conversion.

  17. Reviving Abandoned Reservoirs with High-Pressure Air Injection: Application in a Fractured and Karsted Dolomite Reservoir

    SciTech Connect (OSTI)

    Robert Loucks; Stephen C. Ruppel; Dembla Dhiraj; Julia Gale; Jon Holder; Jeff Kane; Jon Olson; John A. Jackson; Katherine G. Jackson

    2006-09-30

    Despite declining production rates, existing reservoirs in the United States contain vast volumes of remaining oil that is not being effectively recovered. This oil resource constitutes a huge target for the development and application of modern, cost-effective technologies for producing oil. Chief among the barriers to the recovery of this oil are the high costs of designing and implementing conventional advanced recovery technologies in these mature, in many cases pressure-depleted, reservoirs. An additional, increasingly significant barrier is the lack of vital technical expertise necessary for the application of these technologies. This lack of expertise is especially notable among the small operators and independents that operate many of these mature, yet oil-rich, reservoirs. We addressed these barriers to more effective oil recovery by developing, testing, applying, and documenting an innovative technology that can be used by even the smallest operator to significantly increase the flow of oil from mature U.S. reservoirs. The Bureau of Economic Geology and Goldrus Producing Company assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The Permian Basin, the largest oil-bearing basin in North America, contains more than 70 billion barrels of remaining oil in place and is an ideal venue to validate this technology. We have demonstrated the potential of HPAI for oil-recovery improvement in preliminary laboratory tests and a reservoir pilot project. To more completely test the technology, this project emphasized detailed characterization of reservoir properties, which were integrated to access the effectiveness and economics of HPAI. The characterization phase of the project utilized geoscientists and petroleum engineers from the Bureau of Economic Geology and the Department of Petroleum Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. The successful development of HPAI technology has tremendous potential for increasing the flow of oil from deep carbonate reservoirs in the Permian Basin, a target resource that can be conservatively estimated at more than 1.5 billion barrels. Successful implementation in the field chosen for demonstration, for example, could result in the recovery of more than 34 million barrels of oil that will not otherwise be produced. Geological and petrophysical analysis of available data at Barnhart field reveals the following important observations: (1) the Barnhart Ellenburger reservoir is similar to most other Ellenburger reservoirs in terms of depositional facies, diagenesis, and petrophysical attributes; (2) the reservoir is characterized by low to moderate matrix porosity much like most other Ellenburger reservoirs in the Permian Basin; (3) karst processes (cave formation, infill, and collapse) have substantially altered stratigraphic architecture and reservoir properties; (4) porosity and permeability increase with depth and may be associated with the degree of karst-related diagenesis; (5) tectonic fractures overprint the reservoir, improving overall connectivity; (6) oil-saturation profiles show that the oil-water contact (OWC) is as much as 125 ft lower than previous estimations; (7) production history and trends suggest that this reservoir is very similar to other solution-gas-drive reservoirs in the Permian Basin; and (8) reservoir simulation study showed that the Barnhart reservoir is a good candidate for HPAI and that application of horizontal-well technology can improve ultimate resource recovery from the reservoir.

  18. REVIVING ABANDONED RESERVOIRS WITH HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect (OSTI)

    Robert Loucks; Steve Ruppel; Julia Gale; Jon Holder; Jon Olson; Deanna Combs; Dhiraj Dembla

    2004-06-01

    The Bureau of Economic Geology (BEG) and Goldrus Producing Company have assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The characterization phase of the project is utilizing geoscientists and petroleum engineers from the Bureau of Economic Geology (BEG) and the Department of Petroleum and Geosystems Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. This model will be used to define a field deployment plan that Goldrus, a small independent oil company, will implement by drilling both vertical and horizontal wells during the demonstration phase of the project. Additional reservoir data were to be generated during the demonstration phase to improve the accuracy of the reservoir model. The demonstration phase has been delayed by Goldrus because of funding problems. Since the first of the year, Goldrus has been active in searching for partners to help finance the project. To this end it has commissioned several small consulting studies to technically support its effort to secure a partner. After financial support is obtained, the demonstration phase of the project will proceed. Since just after the beginning of the year, BEG has curtailed project activities and spending of DOE funds except for the continued support of one engineering student. This student has now completed his work and has written a thesis describing his research (titled ''Stimulating enhanced oil recovery (EOR) by high-pressure air injection (HPAI) in west Texas light oil reservoir''). We plan to recommence our work on the project as soon as the operator obtains necessary funding to carry out the demonstration phase of the project. In order to complete all activities specified in the proposal, it will be necessary to request an extension of the project from the originally defined completion date. We are confident that Goldrus will obtain the necessary funding to continue and that we can complete the project if an extension is granted. We strongly believe that the results of this study will provide the impetus for a new approach to enhanced oil recovery in the Permian Basin and elsewhere in the United States.

  19. REVIVING ABANDONED RESERVOIRS WITH HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR

    SciTech Connect (OSTI)

    Robert Loucks; Steve Ruppel; Julia Gale; Jon Holder; Jon Olsen; Deanna Combs; Dhiraj Dembla; Leonel Gomez

    2003-06-01

    The Bureau of Economic Geology and Goldrus Producing Company have assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The characterization phase of the project is utilizing geoscientists and petroleum engineers from the bureau of Economic Geology and the Department of Petroleum Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. This model will be used to define a field deployment plant that Goldrus, a small independent oil company, will implement by drilling both vertical and horizontal wells during the demonstration phase of the project. Additional reservoir data are being gathered during the demonstration phase to improve the accuracy of the reservoir model. The results of the demonstration are being closely monitored to provide a basis for improving the design of the HPAI field deployment plan. The results of the reservoir characterization field demonstration and monitoring program will be documented and widely disseminated to facilitate adoption of this technology by oil operators in the Permian Basin and elsewhere in the US.

  20. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  1. Paint Rock and southwest Paint Rock fields, Concho County, Texas: Strawn analogs of modern island carbonate facies of Ambergris Cay, Belize

    SciTech Connect (OSTI)

    Reid, A.M.; Mazzullo, S.J.

    1987-02-01

    Lower Strawn (Desmoinesian Goen Limestone) reservoirs at Paint Rock and Southwest Paint Rock fields are a complex of carbonate and associated facies interpreted as having been deposited in various environments on and around large, emergent islands on shallow carbonate shelves. The origin and geometries of the component lithofacies in these fields, and their reservoir diagenetic histories, are similar to those presently accumulating on Ambergris Cay, a linear island complex on the northern shelf of Belize. Paint Rock field originated as a narrow, elongate Chaetetes reef trend that formed the foundation on which the overlying island facies were deposited. As on Ambergris Cay, these reef limestones developed extensive porosity during postdepositional subaerial exposure due to meteoric leaching. In contrast, Southwest Paint Rock field is cored by older island deposits rather than reef limestones. With ensuing stillstand or subsequent sea level rise, beach grainstones were deposited along the windward and leeward margins of the foundation highs in these fields. Tight lagoonal micrites and coals (peat-swamp facies) comprise the inner island facies, and are locally associated with porous supratidal dolomites. These island complexes are transected locally by tidal channels that are filled with nonporous micrites. Repeated sea level fluctuations during the history of these fields resulted in a characteristic cyclic stratigraphy of stacked island facies and reservoirs. The reservoirs in the field are developed in the bedrock or older island cores, as well as in the overlying beach facies and supratidal dolomites. These fields are mappable as linear stratigraphic traps with low-relief closure, and are readily identified by subsurface geologic and facies analyses. Similar shelf island-type fields analogous to these strawn and Holocene Belizean examples are found throughout the Midland basin and Eastern shelf.

  2. Engineering characteristics of bedrock for the proposed superconducting super collider in Illinois

    SciTech Connect (OSTI)

    Bauer, R.A.; Curry, B.; Vaiden, R.C.; Graese, A.M.; Dixon, W.; Su, W.J.

    1985-01-01

    Sixteen test holes were drilled in a 36-township area in northeastern Illinois as part of a geological feasibility study for the proposed Superconducting Super Collider. Bedrock tunneling suitability is being characterized by comprehensive testing of continuous core of lower Silurian, Ordovician and upper Cambrian units. Tests include unconfined compressive (UCS) and indirect tensile strength (ITS), fracture spacing, rock quality designation, drilling rate and water injection tests. Preliminary results indicate that the 38-m thick Wise Lake Formation of the Ordovician Galena Group is best suited for tunnel construction. The Wise Lake is a vuggy, fossiliferous dolomite with subordinate limestone. Two joint sets oriented N50E and N50W are found in this unit with spacings between joints of about 0.8 m. The overlying Maquoketa Shale Group consists of basal shales from 1 to 22 m thick which are overlain by interbeds of dolomitic shale and dolomite. The Silurian Formations are composed chiefly of fine-grained cherty dolomite; engineering characteristics are similar to the Wise Lake Formation. The upper 3 to 4 m of bedrock can be severely jointed and weathered; permeability ranges from 1.0 x 10/sup -3/ to 1.0 x 10/sup -4/ cm/sec. Although the ring design and national location have not been decided, the geotechnical data indicate that the most favorable tunneling conditions at the Illinois site are 130 to 150 m below the ground surface in the Wise Lake Formation of the Galena Group. By comparison, conditions are more favorable than similar test data developed for the successful TARP project in Chicago.

  3. Mineral Resource Information System for Field Lab in the Osage Mineral Reservation Estate

    SciTech Connect (OSTI)

    Carroll, H.B.; Johnson, William I.

    1999-04-27

    The Osage Mineral Reservation Estate is located in Osage County, Oklahoma. Minerals on the Estate are owned by members of the Osage Tribe who are shareholders in the Estate. The Estate is administered by the Osage Agency, Branch of Minerals, operated by the U.S. Bureau of Indian Affairs (BIA). Oil, natural gas, casinghead gas, and other minerals (sand, gravel, limestone, and dolomite) are exploited by lessors. Operators may obtain from the Branch of Minerals and the Osage Mineral Estate Tribal Council leases to explore and exploit oil, gas, oil and gas, and other minerals on the Estate. Operators pay a royalty on all minerals exploited and sold from the Estate. A mineral Resource Information system was developed for this project to evaluate the remaining hydrocarbon resources located on the Estate. Databases on Microsoft Excel spreadsheets of operators, leases, and production were designed for use in conjunction with an evaluation spreadsheet for estimating the remaining hydrocarbons on the Estate.

  4. Platform/foreslope facies and buildup geometry resulting from short-term and long-term eustatic sea level fluctuations: latemar buildup (Middle Triassic), Dolomites, northern Italy

    SciTech Connect (OSTI)

    Harris, M.T.; Goldhammer, R.

    1987-05-01

    Superimposed short-term and long-term eustatic sea level fluctuations directly controlled Latemar platform stratigraphy and indirectly influenced the deeper water facies and overall buildup geometry. Deeper water facies, the foreslope and toe of slope, are a function of platform submergence (highstand shedding) and subaerial exposure (lowstand lithification and erosion) and thus only indirectly reflect eustatic fluctuations. The Latemar consists of a platform core (3-4 km wide, 700 m thick) with a narrow margin, flanked by foreslope (30-35/sup 0/ dips), toe of slope, and basin deposits. The shallowing-upward platform sequence records a long-term (about 10 m.y.) eustatic sea level oscillation with an amplitude of about 150 m. The lower 250 m marks an initial catch-up phase (subtidal carbonates); the upper 450 m marks the sequential keep-up phase (meter-scale cyclic carbonates). These cycles record platform submergence and exposure caused by short-term (10/sup 4/-10/sup 5/ years) Milankovitch eustatic oscillations superimposed on the long-term trend. Platform submergence and exposure conditions result in contrasting foreslope deposits. During highstands, platform-derived sands bypass the foreslope, accumulating as toe-of-slope graded beds and basin turbidites. During lowstands, sand supply ceases, producing basin hard-grounds. Foreslope megabreccias contain margin-derived boundstone clasts, with only minor platform-derived sands (highstands) and lithified clasts (lowstands). As the platform margin/foreslope contact is nearly vertical, a progressively increasing volume of foreslope megabreccia was needed to maintain the depositional geometry. This coincides with the most commonly exposed platform interval, suggesting that platform exposure determines buildup flank geometry by controlling megabreccia clast production.

  5. Failure mode analysis for lime/limestone FGD system. Volume III. Plant profiles. Part 1 of 3

    SciTech Connect (OSTI)

    Kenney, S.M.; Rosenberg, H.S.; Nilsson, L.I.O.; Oxley, J.H.

    1984-08-01

    This volume contains plant profiles for: Petersburg 3; Hawthorn 3, 4; La Cygne 1; Jeffry 1, 2; Lawrence 4, 5; Green River 1-3; Cane Run 4, 5; Mill Creek 1, 3; Paddy's Run 6; Clay Boswell 4; Milton R. Young 2; Pleasants 1, 2; and Colstrip 1, 2. (DLC)

  6. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  7. Application of coiled-tubing-drilling technology on a deep underpressured gas reservoir

    SciTech Connect (OSTI)

    1997-06-01

    The Upper-Mississippian Elkton formation is a dolomitized shallow-water carbonate consisting of dense limestones and porous dolomites. The Elkton was deposited in an open-shelf environment as crinoid grainstones, coral packstones, and lime muds. Deposition of impermeable shales and siltstones of the Lower Cretaceous created the lateral and updip seals. Reservoir thickness can be up to 20 m, with porosities reaching 20% and averaging 10%. The reservoir gas contains approximately 0.5% hydrogen sulfide. Well 11-18 was to be completed in the Harmatten Elkton pool. The pool went on production in 1967 at an initial pressure of 23,500 kPa. At the current pressure of 16,800 kPa, the remaining reserves are underpressured at 6.5 kPa/m, and underbalanced horizontal drilling was selected as the most suitable technique for exploiting remaining reserves. Coiled-tubing (CT) technology was selected to ensure continuous underbalanced conditions and maintain proper well control while drilling. The paper describes the equipment, CT drilling summary, and drilling issues.

  8. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  9. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  10. LIMB Demonstration Project Extension and Coolside Demonstration. [Final report

    SciTech Connect (OSTI)

    Goots, T.R.; DePero, M.J.; Nolan, P.S.

    1992-11-10

    This report presents results from the limestone Injection Multistage Burner (LIMB) Demonstration Project Extension. LIMB is a furnace sorbent injection technology designed for the reduction of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions from coal-fired utility boilers. The testing was conducted on the 105 Mwe, coal-fired, Unit 4 boiler at Ohio Edison`s Edgewater Station in Lorain, Ohio. In addition to the LIMB Extension activities, the overall project included demonstration of the Coolside process for S0{sub 2} removal for which a separate report has been issued. The primary purpose of the DOE LIMB Extension testing, was to demonstrate the generic applicability of LIMB technology. The program sought to characterize the S0{sub 2} emissions that result when various calcium-based sorbents are injected into the furnace, while burning coals having sulfur content ranging from 1.6 to 3.8 weight percent. The four sorbents used included calcitic limestone, dolomitic hydrated lime, calcitic hydrated lime, and calcitic hydrated lime with a small amount of added calcium lignosulfonate. The results include those obtained for the various coal/sorbent combinations and the effects of the LIMB process on boiler and plant operations.

  11. LIMB Demonstration Project Extension and Coolside Demonstration

    SciTech Connect (OSTI)

    Goots, T.R.; DePero, M.J.; Nolan, P.S.

    1992-11-10

    This report presents results from the limestone Injection Multistage Burner (LIMB) Demonstration Project Extension. LIMB is a furnace sorbent injection technology designed for the reduction of sulfur dioxide (SO[sub 2]) and nitrogen oxides (NO[sub x]) emissions from coal-fired utility boilers. The testing was conducted on the 105 Mwe, coal-fired, Unit 4 boiler at Ohio Edison's Edgewater Station in Lorain, Ohio. In addition to the LIMB Extension activities, the overall project included demonstration of the Coolside process for S0[sub 2] removal for which a separate report has been issued. The primary purpose of the DOE LIMB Extension testing, was to demonstrate the generic applicability of LIMB technology. The program sought to characterize the S0[sub 2] emissions that result when various calcium-based sorbents are injected into the furnace, while burning coals having sulfur content ranging from 1.6 to 3.8 weight percent. The four sorbents used included calcitic limestone, dolomitic hydrated lime, calcitic hydrated lime, and calcitic hydrated lime with a small amount of added calcium lignosulfonate. The results include those obtained for the various coal/sorbent combinations and the effects of the LIMB process on boiler and plant operations.

  12. Development of a Geologic Exploration Model foe the Permo-Pennsylvanian Petroleum System in South-Central Montana

    SciTech Connect (OSTI)

    David A. Lopez

    2007-06-30

    Eolian sands are the main Pennsylvanian Tensleep Sandstone reservoir rocks, and were deposited in a near-shore environment interbedded with near-shore marine and sabkha calcareous and dolomitic rocks. Within the Tensleep, numerous cycles are characterized by basal marine or sabkha calcareous sandstone or dolomitic sandstone overlain by porous and permeable eolian sandstone, which in turn is capped by marine sandstone. The cycles represent the interplay of near-shore marine, sabkha, and eolian environments. On the west side of the project area, both the lower and upper Tensleep are present and the total thickness reaches a maximum of about 240 ft. The lower Tensleep is 100 to 120 ft thick and consists of a sequence of repeating cycles of limey shallow marine sandstone, sandy limestone, and sandy dolomite. The upper Tensleep is generally characterized by cycles of sandy limestone or dolomite, overlain by light-colored, eolian dune sandstone capped by marine limey sandstone. In the central and eastern parts of the project area, only the lower Tensleep is present, but here eolian sandstones are in cycles much like those in the west in the upper Tensleep. The lower Tensleep is quite variable in thickness, ranging from about 25 ft to over 200 ft. Oil accumulations in the Tensleep are best described as structurally modified paleostratigraphic accumulations. At Frannie Field, the irregular oil column can be explained by a post-Tensleep channel scour on the west flank of the anticline. On the Powder River Basin side of the project area, the Soap Creek and Lodge Grass Fields produce from the Permo-Pennsylvanian system. In these two fields, erosional remnants of eolian sandstone control the production, similar to the situation at Frannie Field. At Soap Creek the trap is enhanced by structural closure. In the Lodge Grass area, Tensleep oil is trapped in preserved dunes in the footwall of a Laramide reverse fault. Oil generation and migration was early. Two hypotheses have been presented: migration occurred (1) before mid-Jurassic erosion produced a major regional unconformity or (2) about 82 million years ago. Migration pre-Laramide occurred because oil in both the Bighorn Basin and the Powder River Basin are part of the same petroleum system. Geochemical analyses of oils from producing fields across the region show the oils are all similar and have the same source and generation history. No Phosphoria source rocks exist in the project area of south-central Montana, requiring that oil migrated from distant source areas, probably in central and southwestern Wyoming. Oil shows and production in the Tensleep are absent in the northern part of the project area. This appears to be controlled by the merging of the top of the Tensleep Sandstone and the Jurassic unconformity (top of the Triassic Chugwater Formation). There should be potential for the discovery of oil in Tensleep stratigraphic traps or combination traps everywhere south of the Jurassic-Pennsylvanian Isopach zero contour except where the Tensleep has been exposed by uplift and erosion. Known Tensleep fields in south-central Montana are generally small in area, which agrees with outcrop studies that show eolian dune sequences are generally quite small in lateral extent, on the order of 10 to 40 acres. Although existing fields are small in area, they are very productive; individual wells will probably make 300,000 to 500,000 barrels of oil. In the project area, hydrodynamic considerations are important. All the existing Tensleep fields have active water drives. In many cases, the reservoir pressure today is as it was when initially discovered. In areas of high structural complexity, such as the Lodge Grass-Crow Agency fault and the Lake Basin fault zone, significant structural closure may be necessary to trap oil because of the strong hydrodynamic influence exerted by the underlying Madison Formation aquifer.

  13. Wettability and Oil Recovery by Imbibition and Viscous Displacement from Fractured and Heterogeneous Carbonates

    SciTech Connect (OSTI)

    Norman R. Morrow; Jill Buckley

    2006-04-01

    About one-half of U.S. oil reserves are held in carbonate formations. The remaining oil in carbonate reservoirs is regarded as the major domestic target for improved oil recovery. Carbonate reservoirs are often fractured and have great complexity even at the core scale. Formation evaluation and prediction is often subject to great uncertainty. This study addresses quantification of crude oil/brine/rock interactions and the impact of reservoir heterogeneity on oil recovery by spontaneous imbibition and viscous displacement from pore to field scale. Wettability-alteration characteristics of crude oils were measured at calcite and dolomite surfaces and related to the properties of the crude oils through asphaltene content, acid and base numbers, and refractive index. Oil recovery was investigated for a selection of limestones and dolomites that cover over three orders of magnitude in permeability and a factor of four variation in porosity. Wettability control was achieved by adsorption from crude oils obtained from producing carbonate reservoirs. The induced wettability states were compared with those measured for reservoir cores. The prepared cores were used to investigate oil recovery by spontaneous imbibition and viscous displacement. The results of imbibition tests were used in wettability characterization and to develop mass transfer functions for application in reservoir simulation of fractured carbonates. Studies of viscous displacement in carbonates focused on the unexpected but repeatedly observed sensitivity of oil recovery to injection rate. The main variables were pore structure, mobility ratio, and wettability. The potential for improved oil recovery from rate-sensitive carbonate reservoirs by increased injection pressure, increased injectivity, decreased well spacing or reduction of interfacial tension was evaluated.

  14. Lithological influence of aggregate in the alkali-carbonate reaction

    SciTech Connect (OSTI)

    Lopez-Buendia, A.M. . E-mail: angel.lopez@aidico.es; Climent, V. . E-mail: vcliment@grupogla.com; Verdu, P.

    2006-08-15

    The reactivity of carbonate rock with the alkali content of cement, commonly called alkali-carbonate reaction (ACR), has been investigated. Alkali-silica reaction (ASR) can also contribute in the alkali-aggregate reaction (AAR) in carbonate rock, mainly due to micro- and crypto-crystalline quartz or clay content in carbonate aggregate. Both ACR and ASR can occur in the same system, as has been also evidenced on this paper. Carbonate aggregate samples were selected using lithological reactivity criteria, taking into account the presence of dedolomitization, partial dolomitization, micro- and crypto-crystalline quartz. Selected rocks include calcitic dolostone with chert (CDX), calcitic dolostone with dedolomitization (CDD), limestone with chert (LX), marly calcitic dolostone with partial dolomitization (CD), high-porosity ferric dolostone with clays (FD). To evaluate the reactivity, aggregates were studied using expansion tests following RILEM AAR-2, AAR-5, a modification using LiOH AAR-5Li was also tested. A complementary study was done using petrographic monitoring with polarised light microscopy on aggregates immersed in NaOH and LiOH solutions after different ages. SEM-EDAX has been used to identify the presence of brucite as a product of dedolomitization. An ACR reaction showed shrinkage of the mortar bars in alkaline solutions explained by induced dedolomitization, while an ASR process typically displayed expansion. Neither shrinkage nor expansion was observed when mortar bars were immersed in solutions of lithium hydroxide. Carbonate aggregate classification with AAR pathology risk has been elaborated based on mechanical behaviours by expansion and shrinkage. It is proposed to be used as a petrographic method for AAR diagnosis to complement the RILEM AAR1 specifically for carbonate aggregate. Aggregate materials can be classified as I (non-reactive), II (potentially reactive), and III (probably reactive), considering induced dedolomitization ACR (dedolomitization degree) and ASR.

  15. Mesozoic stratigraphy and paleoenvironments of the Exxon 975-1 well, Georges Bank Basin, U. S. North Atlantic outer continental shelf

    SciTech Connect (OSTI)

    Poppe, L.J.; Poag, C.W. . Quissett Labs.)

    1993-03-01

    The Exxon 975--1 well, located in the southeastern part of the Georges Bank Basin, was drilled to a total depth of 4,452 m relative to the Kelly Bushing. The oldest sediments penetrated by the well are Middle Jurassic (Bajocian-Early Bathonian), but unambiguous seismic correlations with the COST G--1 and G--2 wells show that about 6,860 m of Mesozoic and Cenozoic sedimentary rocks rest on the Paleozoic basement at the 975--1 wellsite. The Jurassic/Cretaceous boundary in the well is placed at 1,673 m; the Cretaceous/Tertiary boundary occurs at 384 m. Limestone is predominant below 3,966 m (Iroquois Formation), and at the intervals 3,810--3,246 m and 1,897--1,654 m (lower and upper tongues of the Abenaki Formation). Siliciclastics of the Mohican, undivided Mic Mac-Mohawk, Missisauga, Logan Canyon, and Dawson Canyon Formations dominate the remainder of the Mesozoic section. The Exxon 975--1 well penetrated updip, more terrestrial lithofacies than the COST G--2, Conoco 145--1, and Mobil 312--1 wells. Salt, anhydrite, dolomite, and the micritic textures of the carbonates in the Iroquois Formation of the Exxon 975--1 well suggest hypersaline restricted marine and supratidal depositional environments. The predominantly nonmarine deltaic siliciclastics of the Mohican, Misaine Shale, and Mic Mac-Mohawk units are thicker in the Exxon 975--1 well, whereas marine carbonates of the Scatarie and Bacarro Limestones are usually thinner than at the downdip (seaward) wellsites. Similarly, the Early Cretaceous Missisauga and Logan Canyon Formations represent lower delta plain (alluvial and swamp) and delta front (beach, bar, and lagoon) facies at the Exxon 975--1 wellsite, whereas correlative downdip facies represent shallow marine to delta front deposition.

  16. A 50-month gasifier mechanistic study and downstream unit process development program for the pressurized ash-agglomerating fluidized-bed gasification system

    SciTech Connect (OSTI)

    Haldipur, G.B.; Schmidt, D.K.; Smith, K.J.

    1989-03-01

    This technology development program scope included studies of those processes and components necessary to convert coal, oxidant and steam into a clean fuel gas. The configuration of the processes and components constitutes a Gasifier Island which is a key concept in the application of the KRW gasification and cleanup technologies. This Gasifier Island typically consists of process units that perform the following functions: feedstock preparation, gasification, desulfurization, heat recovery, particulate removal, and solid waste treatment. The processing has been conducted in a variety of gasifier operating modes including air-blown and oxygen-blown, both with and without in-bed desulfurization which includes injection of limestone or dolomite sorbent. Process configurations downstream of the gasifier have included recycle and non-recycle cyclones, sintered filters, and zinc ferrite fixed beds. Because of the developmental nature of the KRW technology program and the flexibility of the pilot plant itself, a wide range of gasifier-cleanup process configurations has been investigated. The KRW pilot plant program evaluated a system comprised of the following major process elements: gasifier and in-bed desulfurizer, particulate cleanup train, external sulfur polishing bed, and solid waste disposal system.

  17. DILUTE SURFACTANT METHODS FOR CARBONATE FORMATIONS

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2004-01-01

    There are many carbonate reservoirs in US (and the world) with light oil and fracture pressure below its minimum miscibility pressure (or reservoir may be naturally fractured). Many carbonate reservoirs are naturally fractured. Waterflooding is effective in fractured reservoirs, if the formation is water-wet. Many fractured carbonate reservoirs, however, are mixed-wet and recoveries with conventional methods are low (less than 10%). Thermal and miscible tertiary recovery techniques are not effective in these reservoirs. Surfactant flooding (or huff-n-puff) is the only hope, yet it was developed for sandstone reservoirs in the past. The goal of this research is to evaluate dilute (hence relatively inexpensive) surfactant methods for carbonate formations and identify conditions under which they can be effective. Anionic surfactants (SS-6656, Alfoterra 35, 38, 63,65,68) have been identified which can change the wettability of the calcite surface to intermediate/water-wet condition as well or better than the cationic surfactant DTAB with a West Texas crude oil in the presence of Na{sub 2}CO{sub 3}. All the carbonate surfaces (Lithographic Limestone, Marble, Dolomite and Calcite) show similar behavior with respect to wettability alteration with surfactant 4-22. Anionic surfactants (5-166, Alfoterra-33 and Alfoterra-38 and Alfoterra-68), which lower the interfacial tension with a West Texas crude oil to very low values (<10{sup -2} nM/m), have also been identified. Plans for the next quarter include conducting wettability, mobilization, and imbibition studies.

  18. RPSEA Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 1 Figure 2 Crossplot of permeability vs. porosity of the Arbuckle dolomite core samples from Ogallah unit...

  19. Marine carbonate embayment system in an Eolian dune terrain, Permian Upper Minnelusa Formation, Rozet Area, Powder River Basin, Wyoming

    SciTech Connect (OSTI)

    Achauer, C.W.

    1987-05-01

    The eolian origin for Minnelusa sandstones has been stressed in numerous published articles. However, the dolomites that are interbedded with the eolian sandstones have received little attention. Isopach mapping of one of the dolomite units (Dolomite I) reflects a marine embayment system whose individual embayments range from 1/2 to 1 mi in width and trend primarily in a northwest direction. Consistently the embayment dolomites pinch out against the flanks of reworked, low relief, broad, eolian dune ridges. So far, 108 mi/sup 2/ of the Dolomite I marine embayment system have been mapped, but the overall extent of the system is undoubtedly much greater. Dolomite I is rarely cored, but cores from stratigraphically higher embayment dolomites in the upper Minnelusa show that these dolomites display the following, shoaling-upward sequence: (1) subtidal, sparingly fossiliferous dolomite; (2) intertidal, algal-laminated or brecciated or mud-cracked dolomite; and (3) very thin, supratidal, nodular anhydrite. The embayments, therefore, became the sites of marine sabkhas located between eolian dunes. Two main conclusions emerge from this study: (1) the juxtaposition of eolian sandstones and marine dolomites in a tectonically stable area suggests that eustatic sea level changes and a very arid climate were responsible for the marked environmental and lithologic changes observed in the upper Minnelusa, and (2) arid, coastal, evaporitic sabkhas bordered by eolian dunes are known from a number of modern and ancient cases, but marine carbonate embayments and associated evaporitic sabkhas that penetrate deeply into eolian sandstone terrains are rare.

  20. THE OHIO RIVER VALLEY CO2 STORAGE PROJECT - PRELIMINARY ASSESSMENT OF DEEP SALINE RESERVOIRS AND COAL SEAMS

    SciTech Connect (OSTI)

    Michael J. Mudd; Howard Johnson; Charles Christopher; T.S. Ramakrishnan, Ph.D.

    2003-08-01

    This report describes the geologic setting for the Deep Saline Reservoirs and Coal Seams in the Ohio River Valley CO{sub 2} Storage Project area. The object of the current project is to site and design a CO{sub 2} injection facility. A location near New Haven, WV, has been selected for the project. To assess geologic storage reservoirs at the site, regional and site-specific geology were reviewed. Geologic reports, deep well logs, hydraulic tests, and geologic maps were reviewed for the area. Only one well within 25 miles of the site penetrates the deeper sedimentary rocks, so there is a large amount of uncertainty regarding the deep geology at the site. New Haven is located along the Ohio River on the border of West Virginia and Ohio. Topography in the area is flat in the river valley but rugged away from the Ohio River floodplain. The Ohio River Valley incises 50-100 ft into bedrock in the area. The area of interest lies within the Appalachian Plateau, on the western edge of the Appalachian Mountain chain. Within the Appalachian Basin, sedimentary rocks are 3,000 to 20,000 ft deep and slope toward the southeast. The rock formations consist of alternating layers of shale, limestone, dolomite, and sandstone overlying dense metamorphic continental shield rocks. The Rome Trough is the major structural feature in the area, and there may be some faults associated with the trough in the Ohio-West Virginia Hinge Zone. The area has a low earthquake hazard with few historical earthquakes. Target injection reservoirs include the basal sandstone/Lower Maryville and the Rose Run Sandstone. The basal sandstone is an informal name for sandstones that overlie metamorphic shield rock. Regional geology indicates that the unit is at a depth of approximately 9,100 ft below the surface at the project site and associated with the Maryville Formation. Overall thickness appears to be 50-100 ft. The Rose Run Sandstone is another potential reservoir. The unit is located approximately 1,100 ft above the basal sandstone and is 100-200 ft thick. The storage capacity estimates for a 20-mile radius from the injection well ranged from 39-78 million tons (Mt) for each formation. Several other oil and gas plays have hydraulic properties conducive for injection, but the formations are generally only 5-50 ft thick in the study area. Overlying the injection reservoirs are thick sequences of dense, impermeable dolomite, limestone, and shale. These layers provide containment above the potential injection reservoirs. In general, it appears that the containment layers are much thicker and extensive than the injection intervals. Other physical parameters for the study area appear to be typical for the region. Anticipated pressures at maximum depths are approximately 4,100 psi based on a 0.45 psi/ft pressure gradient. Temperatures are likely to be 150 F. Groundwater flow is slow and complex in deep formations. Regional flow directions appear to be toward the west-northwest at less than 1 ft per year within the basal sandstone. Vertical gradients are downward in the study area. A review of brine geochemistry indicates that formation fluids have high salinity and dissolved solids. Total dissolved solids ranges from 200,000-325,000 mg/L in the deep reservoirs. Brine chemistry is similar throughout the different formations, suggesting extensive mixing in a mature basin. Unconsolidated sediments in the Ohio River Valley are the primary source of drinking water in the study area.

  1. Completion Report for Well ER-12-3 Corrective Action Unit 99: Rainier Mesa - Shoshone Mountain

    SciTech Connect (OSTI)

    U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office; Bechtel Nevada Corporation

    2006-05-01

    Well ER-12-3 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. The well was drilled in March and April 2005 as part of a hydrogeologic investigation program for the Rainier Mesa-Shoshone Mountain Corrective Action Unit. The overall purpose of the well was to gather subsurface data to better characterize the hydrogeology of central Rainier Mesa, especially in the older Tertiary volcanic rocks and Paleozoic sedimentary rocks. The main 47.0-centimeter hole was drilled to a depth of 799.2 meters and cased with 33.97-centimeter casing to 743.1 meters. The hole diameter was then decreased to 31.1 centimeters, and the well was drilled to a total depth of 1,496.0 meters. The completion string consisted of 13.97-centimeter stainless steel casing, with two slotted intervals open to the lower carbonate aquifer, suspended from 19.37-centimeter carbon steel casing. A piezometer string was installed outside the 33.97-centimeter casing to a depth of 467.1 meters to monitor a zone of perched water within the Tertiary volcanic section. Data gathered during and shortly after hole construction include composite drill cuttings samples collected every 3 meters (extra cuttings samples were collected from the Paleozoic rocks for paleontological analyses), sidewall core samples from 35 depths, various geophysical logs, and water level measurements. These data indicate that the well penetrated 674.2 meters of Tertiary volcanic rocks and 821.7 meters of Paleozoic dolomite and limestone. Forty-nine days after the well was completed, but prior to well development and testing, the water level inside the main hole was tagged at the depth of 949.1 meters, and the water level inside the piezometer string was tagged at 379.9 meters.

  2. Composition and chemistry of particulates from the Tidd Clean Coal Demonstration Plant pressurized fluidized bed combustor, cyclone, and filter vessel

    SciTech Connect (OSTI)

    Smith, D.H.; Grimm, U.; Haddad, G.

    1995-12-31

    In a Pressurized Fluidized Bed Combustion (PFBC)/cyclone/filter system ground coal and sorbent are injected as pastes into the PFBC bed; the hot gases and entrained fine particles of ash and calcined or reacted sorbent are passed through a cyclone (which removes the larger entrained particles); and the very-fine particles that remain are then filtered out, so that the cleaned hot gas can be sent through a non-ruggedized hot-gas turbine. The 70 MWe Tidd PFBC Demonstration Plant in Brilliant, Ohio was completed in late 1990. The initial design utilized seven strings of primary and secondary cyclones to remove 98% of the particulate matter. However, the Plant also included a pressurized filter vessel, placed between the primary and secondary cyclones of one of the seven strings. Coal and dolomitic limestone (i.e, SO{sub 2} sorbent) of various nominal sizes ranging from 12 to 18 mesh were injected into the combustor operating at about 10 atm pressure and 925{degree}C. The cyclone removed elutriated particles larger than about 0.025 mm, and particles larger than ca. 0.0005 mm were filtered at about 750{degree}C by ceramic candle filters. Thus, the chemical reaction times and temperatures, masses of material, particle-size distributions, and chemical compositions were substantially different for particulates removed from the bed drain, the cyclone drain, and the filter unit. Accordingly, we have measured the particle-size distributions and concentrations of calcium, magnesium, sulfur, silicon, and aluminum for material taken from the three units, and also determined the chemical formulas and predominant crystalline forms of the calcium and magnesium sulfate compounds formed. The latter information is particularly novel for the filter-cake material, from which we isolated the ``new`` compound Mg{sub 2}Ca(SO{sub 4}){sub 3}.

  3. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T. ); Dunbar, N.W. ); Tixier, J.S.; Powell, T.D. )

    1992-11-01

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were [sup 137]Cs and [sup 90]Sr, with lesser amounts of [sup 6O]Co, [sup 241]Am, and [sup 239,240]Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the [sup 137]Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of [sup 90]Sr, [sup 241]Am, or [sup 239,240]Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500[degrees]C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  4. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T.; Dunbar, N.W.; Tixier, J.S.; Powell, T.D.

    1992-11-01

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were {sup 137}Cs and {sup 90}Sr, with lesser amounts of {sup 6O}Co, {sup 241}Am, and {sup 239,240}Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the {sup 137}Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of {sup 90}Sr, {sup 241}Am, or {sup 239,240}Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500{degrees}C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  5. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    aragonite, dolomite, crystal nucleation, crystallization, interface, catalysis, EBSD, XRD, TEM Authors: Xu, Huifang ; Zhou, Mo ; Zhang, Fangfu ; Konishi, Hiromi ; Shen, Zhizhang ...

  6. Property:HostRockLithology | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Area + Basalt Amedee Geothermal Area + granite; granodiorite B Bac-Man Laguna Geothermal Area + Volcanic Bad Blumau Geothermal Area + Dolomite Beowawe Hot...

  7. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    CYCLONE OPTIMIZATON Gerald H Luttrell Chris J Barbee Peter J Bethell Chris J Wood COAL LIGNITE AND PEAT COAL DESIGN DIAMONDS DOLOMITE ECONOMICS EFFICIENCY EVALUATION...

  8. DENSE MEDIUM CYCLONE OPTIMIZATON Gerald H. Luttrell; Chris J...

    Office of Scientific and Technical Information (OSTI)

    OPTIMIZATON Gerald H. Luttrell; Chris J. Barbee; Peter J. Bethell; Chris J. Wood 01 COAL, LIGNITE, AND PEAT; COAL; DESIGN; DIAMONDS; DOLOMITE; ECONOMICS; EFFICIENCY;...

  9. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Report",,,,"Virginia Polytech Institute and State University","USDOE","01 COAL, LIGNITE, AND PEAT; COAL; DESIGN; DIAMONDS; DOLOMITE; ECONOMICS; EFFICIENCY;...

  10. NREL: Photovoltaics Research - David L. Young, Ph.D.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p. 073502. Young, D.L., B. Egaas, S. Pinegar, and P. Stradins. A new real-time quantum efficiency measurement system. in 33rd IEEE PVSC 2008. San Diego, CA: IEEE. Young, D.L.,...

  11. Gas turbines and acid rain - Looking at some solutions

    SciTech Connect (OSTI)

    May, W.

    1989-01-01

    This article examines the technology available for reducing the sulfur emissions of gas turbines that are implicated in the production of acid rain. The alternatives reviewed are limestone scrubbing, spray dryer absorption and limestone injection into boilers. The last process is not feasible for gas turbines and of the other two the author recommends limestone scrubbing.

  12. Carbonaceous fuel combustion with improved desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Shen, Ming-shing (Rocky Point, NY)

    1980-01-01

    Lime utilization for sulfurous oxides adsorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. The iron oxide present in the spent limestone is found to catalyze the regeneration rate of the spent limestone in a reducing environment. Thus both the calcium and iron components may be recycled.

  13. Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

    DOE Patents [OSTI]

    Shen, Ming-Shing (Rocky Point, NY); Yang, Ralph T. (Middle Island, NY)

    1980-01-01

    Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

  14. Geomechanical Analysis and Design Considerations for Thin-Bedded Salt Caverns

    SciTech Connect (OSTI)

    Michael S. Bruno

    2005-06-15

    The bedded salt formations located throughout the United States are layered and interspersed with non-salt materials such as anhydrite, shale, dolomite and limestone. The salt layers often contain significant impurities. GRI and DOE have initialized this research proposal in order to increase the gas storage capabilities by providing operators with improved geotechnical design and operating guidelines for thin bedded salt caverns. Terralog has summarized the geologic conditions, pressure conditions, and critical design factors that may lead to: (1) Fracture in heterogeneous materials; (2) Differential deformation and bedding plane slip; (3) Propagation of damage around single and multiple cavern; and (4) Improved design recommendations for single and multiple cavern configurations in various bedded salt environments. The existing caverns within both the Permian Basin Complex and the Michigan and Appalachian Basins are normally found between 300 m to 1,000 m (1,000 ft to 3,300 ft) depth depending on local geology and salt dissolution depth. Currently, active cavern operations are found in the Midland and Anadarko Basins within the Permian Basin Complex and in the Appalachian and Michigan Basins. The Palo Duro and Delaware Basins within the Permian Basin Complex also offer salt cavern development potential. Terralog developed a number of numerical models for caverns located in thin bedded salt. A modified creep viscoplastic model has been developed and implemented in Flac3D to simulate the response of salt at the Permian, Michigan and Appalachian Basins. The formulation of the viscoplastic salt model, which is based on an empirical creep law developed for Waste Isolation Pilot Plant (WIPP) Program, is combined with the Drucker-Prager model to include the formation of damage and failure. The Permian salt lab test data provided by Pfeifle et al. 1983, are used to validate the assumptions made in the material model development. For the actual cavern simulations two baseline models are developed for single and multiple caverns, respectively. Different parameters that affect damage propagation and deformation of salt cavern, such as cavern pressure, operating conditions, cavern height/diameter ratio, overburden stiffness and roof thickness are analyzed and the respective results summarized. For multiple horizontal caverns numerical models are developed to determine the cavern interaction and the minimum safe center to center distance. A step by step methodology for operators to assess critical cavern design parameters for thin bedded salt formations is also presented.

  15. Well ER-6-1 Tracer Test Analysis: Yucca Flat, Nevada Test Site, Nye County, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Greg Ruskauff

    2006-09-01

    The ER-6-1 multiple-well aquifer test-tracer test (MWAT-TT) investigated groundwater flow and transport processes relevant to the transport of radionuclides from sources on the Nevada Test Site (NTS) through the lower carbonate aquifer (LCA) hydrostratigraphic unit (HSU). The LCA, which is present beneath much of the NTS, is the principal aquifer for much of southern Nevada. This aquifer consists mostly of limestone and dolomite, and is pervasively fractured. Groundwater flow in this aquifer is primarily in the fractures, and the hydraulic properties are primarily related to fracture frequency and fracture characteristics (e.g., mineral coatings, aperture, connectivity). The objective of the multiple-well aquifer test (MWAT) was to determine flow and hydraulic characteristics for the LCA in Yucca Flat. The data were used to derive representative flow model and parameter values for the LCA. The items of specific interest are: Hydraulic conductivity; Storage parameters; Dual-porosity behavior; and Fracture flow characteristics. The objective of the tracer transport experiment was to evaluate the transport properties and processes of the LCA and to derive representative transport parameter values for the LCA. The properties of specific interest are: Effective porosity; Matrix diffusion; Longitudinal dispersivity; Adsorption characteristics; and Colloid transport characteristics. These properties substantially control the rate of transport of contaminants in the groundwater system and concentration distributions. To best support modeling at the scale of the corrective action unit (CAU), these properties must be investigated at the field scale. The processes represented by these parameters are affected by in-situ factors that are either difficult to investigate at the laboratory scale or operate at a much larger scale than can be reproduced in the laboratory. Measurements at the field scale provide a better understanding of the effective average parameter values. The scale of this tracer test is still small compared to the scale of a CAU, but is of sufficient scale to be generally representative of the processes that affect in-situ transport. The scale of the tracer test undertaken is limited by the rate of transport in the formation and the resultant time frame required for completing such a test. The measurements at the field scale will provide information for relating laboratory measurements for transport processes to the larger scale. This report describes the analysis of the tracer test data and development of a conceptual model of transport in the LCA in Yucca Flat.

  16. Completion Report for Well ER-16-1 Corrective Action Unit 99: Rainier Mesa - Shoshone Mountain

    SciTech Connect (OSTI)

    NSTec Geology Services

    2006-12-01

    Well ER-16-1 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. The well was drilled in June and July 2005 as part of a hydrogeologic investigation program for the Rainier Mesa-Shoshone Mountain Corrective Action Unit, Number 99. The overall purpose of the well was to gather subsurface data to better characterize the hydrogeology of the Shoshone Mountain area, especially in the older Tertiary and pre-Tertiary strata. The main 46.99-centimeter hole was drilled to a depth of 702.9 meters and cased with 33.97-centimeter casing to 663.7 meters. The hole diameter was then decreased to 31.1 centimeters, and the well was drilled to total depth of 1,220.7 meters. A completion string set at the depth of 1,162.4 meters consisted of 13.97-centimeter stainless-steel casing, with one continuous slotted interval open to the lower carbonate aquifer. The fluid level in the borehole soon dropped, so the borehole was deepened in July 2006. To deepen the borehole, the slotted section was cemented and a 12.1-centimeter hole was drilled through the bottom of the completion string to the new total depth of 1,391.7 meters, which is 171.0 meters deeper than the original borehole. A string of 6.03-centimeter carbon-steel tubing with one continuous slotted interval at 1,361.8 to 1,381.4 meters, and open to the lower carbonate aquifer, was installed in the well with no gravel packing or cement, to serve as a monitoring string. Data gathered during and shortly after hole construction include composite drill cuttings samples collected every 3 meters (extra cuttings samples were collected from the Paleozoic rocks for paleontological analyses), sidewall core samples from 37 depths, various geophysical logs, and water level measurements. These data indicate that the well penetrated 646.8 meters of Tertiary volcanic rocks and 744.9 meters of Paleozoic dolomite, quartzite, shale, and limestone. Three weeks after the monitoring string was installed, the water level was tagged at the drill hole depth of 1,271.9 meters, which equates to an estimated elevation of 761.7 meters, accounting for the borehole angle.

  17. UNBIASED MOMENT-RATE SPECTRA AND ABSOLUTE SITE EFFECTS IN THE KACHCHH BASIN, INDIA, FROM THE ANALYSIS OF THE AFTERSHOCKS OF THE 2001 Mw 7.6 BHUJ EARTHQUAKE

    SciTech Connect (OSTI)

    Malagnini, L; Bodin, P; Mayeda, K; Akinci, A

    2005-05-04

    What can be learned about absolute site effects on ground motions and about earthquake source spectra from recordings at temporary seismic stations, none of which could be considered a 'reference' (hard rock) site, for which no geotechnical information is available, in a very poorly instrumented region? This challenge motivated our current study of aftershocks of the 2001 Mw 7.6 Bhuj earthquake, in Western India. Crustal attenuation and spreading relationships based on the same data used here were determined in an earlier study. In this paper we decouple the ambiguity between absolute source radiation and site effects by first computing robust estimates of moment-rate spectra of about 200 aftershocks in each of two depth ranges. Using these new estimates of sourcespectra, and our understanding of regional wave propagation, we extract the absolute site terms of the sites of the temporary deployment. Absolute site terms (one for each component of the ground motion, for each station) are computed in an average sense, via an L{sub 1}-norm minimization, and results for each site are averaged over wide ranges of azimuths and takeoff angles. The Bhuj deployment is characterized by a variable shallow geology, mostly of soft sedimentary units. Vertical site terms in the region were observed to be almost featureless and slightly < 1.0 within wide frequency ranges. As a result, H/V spectral ratios mimic the absolute behaviors of absolute horizontal site terms, and they generally overpredict them. On the contrary, with respect to the results for sedimentary rock sites (limestone, dolomite) obtained by Malagnini et al. (2004), H/V spectral ratios in their study did not have much in common with absolute horizontal site terms. Spectral ratios between the vector sum of the computed horizontal site terms for the temporary deployment with respect to the same quantity computed at the hardest rock station available, BAC1, are seriously biased by its non-flat, non-unitary site response. This indicates that often the actual behavior of a rock outcrop is far from that of an ideal, reference site.

  18. Improving Gas Flooding Efficiency

    SciTech Connect (OSTI)

    Reid Grigg; Robert Svec; Zheng Zeng; Alexander Mikhalin; Yi Lin; Guoqiang Yin; Solomon Ampir; Rashid Kassim

    2008-03-31

    This study focuses on laboratory studies with related analytical and numerical models, as well as work with operators for field tests to enhance our understanding of and capabilities for more efficient enhanced oil recovery (EOR). Much of the work has been performed at reservoir conditions. This includes a bubble chamber and several core flood apparatus developed or modified to measure interfacial tension (IFT), critical micelle concentration (CMC), foam durability, surfactant sorption at reservoir conditions, and pressure and temperature effects on foam systems.Carbon dioxide and N{sub 2} systems have been considered, under both miscible and immiscible conditions. The injection of CO2 into brine-saturated sandstone and carbonate core results in brine saturation reduction in the range of 62 to 82% brine in the tests presented in this paper. In each test, over 90% of the reduction occurred with less than 0.5 PV of CO{sub 2} injected, with very little additional brine production after 0.5 PV of CO{sub 2} injected. Adsorption of all considered surfactant is a significant problem. Most of the effect is reversible, but the amount required for foaming is large in terms of volume and cost for all considered surfactants. Some foams increase resistance to the value beyond what is practical in the reservoir. Sandstone, limestone, and dolomite core samples were tested. Dissolution of reservoir rock and/or cement, especially carbonates, under acid conditions of CO2 injection is a potential problem in CO2 injection into geological formations. Another potential change in reservoir injectivity and productivity will be the precipitation of dissolved carbonates as the brine flows and pressure decreases. The results of this report provide methods for determining surfactant sorption and can be used to aid in the determination of surfactant requirements for reservoir use in a CO{sub 2}-foam flood for mobility control. It also provides data to be used to determine rock permeability changes during CO{sub 2} flooding due to saturation changes, dissolution, and precipitation.

  19. Geologic reconnaissance of natural fore-reef slope and a large submarine rockfall exposure, Enewetak Atoll

    SciTech Connect (OSTI)

    Halley, R.B.; Slater, R.A.

    1987-05-01

    In 1958 a submarine rockfall exposed a cross section through the reef and fore-reef deposits along the northwestern margin of Enewetak Atoll, Marshall Islands. Removal of more than 10/sup 8/ MT of rock left a cirque-shaped submarine scarp 220 m high, extending back 190 m into the modern reef, and 1000 m along the reef trend. The scarp exposed older, steeply dipping beds below 220 m along which the rockfall detached. They sampled this exposure and the natural fore-reef slope surrounding it in 1984 and 1985 using a manned submersible. The natural slope in this area is characterized by three zone: (1) the reef plate, crest, and near fore reef that extends from sea level to -16 m, with a slope of less than 10/sup 0/, (2) the bypass slope that extends from -16 to -275 m, with slopes of 55/sup 0/ decreasing to 35/sup 0/ near the base, and (3) a debris slope of less than 35/sup 0/ below -275 m. Vertical walls, grooves, and chutes, common on other fore-reef slopes, are sparse on the northwestern slope of Enewetak. The scarp exposes three stratigraphic units that are differentiated by surficial appearance: (1) a near-vertical wall from the reef crest to 76 m that appears rubbly, has occasional debris-covered ledges, and is composed mainly of coral; (2) a vertical to overhanging wall from -76 m to -220 m that is massive and fractured, and has smooth, blocky surfaces; and (3) inclined bedding below -220 m along which the slump block has fractured, exposing a dip slope of hard, dense, white limestone and dolomite that extends below -400 m. Caves occur in all three units. Open cement-lined fractures and voids layered with cements are most common in the middle unit, which now lies within the thermocline. Along the sides of the scarp are exposed fore-reef boulder beds dipping at 30/sup 0/ toward the open sea; the steeper (55/sup 0/) dipping natural surface truncates these beds, which gives evidence of the erosional nature of the bypass slope.

  20. An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins: Part 1: Evaluation of Phase 2 CO{sub 2} Injection Testing in the Deep Saline Gunter Sandstone Reservoir (Cambro-Ordovician Knox Group), Marvin Blan No. 1 Hancock County, Kentucky Part 2: Time-lapse Three-Dimensional Vertical Seismic Profile (3D-VSP) of Sequestration Target Interval with Injected Fluids

    SciTech Connect (OSTI)

    Richard Bowersox; John Hickman; Hannes Leetaru

    2012-12-01

    Part 1 of this report focuses on results of the western Kentucky carbon storage test, and provides a basis for evaluating injection and storage of supercritical CO{sub 2} in Cambro-Ordovician carbonate reservoirs throughout the U.S. Midcontinent. This test demonstrated that the Cambro- Ordovician Knox Group, including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite in stratigraphic succession from shallowest to deepest, had reservoir properties suitable for supercritical CO{sub 2} storage in a deep saline reservoir hosted in carbonate rocks, and that strata with properties sufficient for long-term confinement of supercritical CO{sub 2} were present in the deep subsurface. Injection testing with brine and CO{sub 2} was completed in two phases. The first phase, a joint project by the Kentucky Geological Survey and the Western Kentucky Carbon Storage Foundation, drilled the Marvin Blan No. 1 carbon storage research well and tested the entire Knox Group section in the open borehole â?? including the Beekmantown Dolomite, Gunter Sandstone, and Copper Ridge Dolomite â?? at 1152â??2255 m, below casing cemented at 1116 m. During Phase 1 injection testing, most of the 297 tonnes of supercritical CO{sub 2} was displaced into porous and permeable sections of the lowermost Beekmantown below 1463 m and Gunter. The wellbore was then temporarily abandoned with a retrievable bridge plug in casing at 1105 m and two downhole pressure-temperature monitoring gauges below the bridge plug pending subsequent testing. Pressure and temperature data were recorded every minute for slightly more than a year, providing a unique record of subsurface reservoir conditions in the Knox. In contrast, Phase 2 testing, this study, tested a mechanically-isolated dolomitic-sandstone interval in the Gunter. Operations in the Phase 2 testing program commenced with retrieval of the bridge plug and long-term pressure gauges, followed by mechanical isolation of the Gunter by plugging the wellbore with cement below the injection zone at 1605.7 m, then cementing a section of a 14-cm casing at 1470.4â??1535.6. The resultant 70.1-m test interval at 1535.6â??1605.7 m included nearly all of the Gunter sandstone facies. During the Phase 2 injection, 333 tonnes of CO{sub 2} were injected into the thick, lower sand section in the sandy member of the Gunter. Following the completion of testing, the injection zone below casing at 1116 m in the Marvin Blan No. 1 well, and wellbore below 305 m was permanently abandoned with cement plugs and the wellsite reclaimed. The range of most-likely storage capacities found in the Knox in the Marvin Blan No. 1 is 1000 tonnes per surface hectare in the Phase 2 Gunter interval to 8685 tonnes per surface hectare if the entire Knox section were available including the fractured interval near the base of the Copper Ridge. By itself the Gunter lacks sufficient reservoir volume to be considered for CO{sub 2} storage, although it may provide up to 18% of the reservoir volume available in the Knox. Regional extrapolation of CO{sub 2} storage potential based on the results of a single well test can be problematic, although indirect evidence of porosity and permeability can be demonstrated in the form of active saltwater-disposal wells injecting into the Knox. The western Kentucky region suitable for CO{sub 2} storage in the Knox is limited updip, to the east and south, by the depth at which the base of the Maquoketa shale lies above the depth required to ensure storage of CO{sub 2} in its supercritical state and the deepest a commercial well might be drilled for CO{sub 2} storage. The resulting prospective region has an area of approximately 15,600 km{sup 2}, beyond which it is unlikely that suitable Knox reservoirs may be developed. Faults in the subsurface, which serve as conduits for CO{sub 2} migration and compromise sealing strata, may mitigate the area with Knox reservoirs suitable for CO{sub 2} storage. The results of the injection tests in the Marvin Blan No. 1, however, provide a basis for evaluating supercritical CO{sub 2} storage in Cambro-Ordovician carbonate reservoirs throughout the Midcontinent. Reservoir seals were evaluated in the Knox and overlying strata. Within the Knox, permeabilities measured in vertical core plugs from the Beekmantown and Copper Ridge suggest that intraformational seals may problematic. Three stratigraphic intervals overlying the Knox in the Marvin Blan No. 1 well may provide seals for potential CO{sub 2} storage reservoirs in western Kentucky: Dutchtown Limestone, Black River Group, and Maquoketa Shale. The Dutchtown and Black River had permeabilities suggest that these intervals may act as secondary sealing strata. The primary reservoir seal for the Knox, however, is the Maquoketa. Maximum seal capacity calculated from permeabilities measured in vertical core plugs from the Maquoketa exceeded the net reservoir height in the Knox by about two orders of magnitude. Rock strength measured in core plugs from the Maquoketa suggest that it is unlikely that any CO{sub 2} migrating from the Knox would have sufficient pressure to fracture the Maquoketa. Part 2 of this report reviews the results of vertical seismic profiling in the Marvin Blan No. 1 well to model post-injection CO{sub 2} plume migration. Two three-dimensional vertical seismic profiles (3D-VSPâ??s) were acquired at the Kentucky Geological Survey Marvin Blan No. 1 CO{sub 2} sequestration research well, Hancock County, Kentucky. The initial (pre-injection) survey was performed on September 15â??16, 2010. This was followed by the injection of 333 tonnes of supercritical CO{sub 2} and then 584 m3 of 2% KCl water (to displace the remaining CO{sub 2} in the wellbore) on September 22, 2010. After injection, the well was shut in with a downhole pressure of 17.5 MPa at the injected reservoir depth of 1545.3 m. The second 3D-VSP was acquired on September 25â??26, 2010. These two 3D-VSP's were combined to produce a time-lapse 3D-VSP data volume in an attempt to monitor and image the subsurface changes caused by the injection. Less than optimum surface access and ambient subsurface noise from a nearby active petroleum pipeline hampered quality of the data, resulting in the inability to image the CO{sub 2} plume in the subsurface. However, some changes in the seismic response post-injection (both wavelet character and an apparent seismic "pull-down" within the injection zone) are interpreted to be a result of the injection process and imply that the technique could still be valid under different circumstances.

  1. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic

    Office of Scientific and Technical Information (OSTI)

    Leakage into an Unconfined, Oxidizing Limestone Aquifer (Journal Article) | SciTech Connect Journal Article: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer An important risk at CO2 storage sites is the potential for groundwater quality impacts. As

  2. Search for: All records | SciTech Connect

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    Electronic Full Text1 Citations0 Multimedia0 Datasets0 Filter Results Filter by Subject coal (1) coal, lignite, and peat (1) design (1) diamonds (1) dolomite (1) economics (1)...

  3. DENSE MEDIUM CYCLONE OPTIMIZATON (Technical Report) | SciTech...

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    that cannot be upgraded in static dense medium separators, can be found in most modern coal plants and in a variety of mineral plants treating iron ore, dolomite, diamonds, potash...

  4. Environmental Assessment for Conducting Astrophysics and Other...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... In English, it means "dune country." low-income population A population where 25 percent or more of the population is identified as living in poverty. Magenta Dolomite The upper of ...

  5. 3.27 Why Dinosaurs Are Extinct

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    Walter Alvarez discovered a layer of red clay between fossil- containing limestone deposits in Italy. His father, Nobel laureate Luis Alvarez, suggested how to analyze it. ...

  6. X-Ray Microcomputed Tomography for the Durability Characterization...

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    Conference: X-Ray Microcomputed Tomography for the Durability Characterization of Limestone Aggregate Citation Details In-Document Search Title: X-Ray Microcomputed Tomography for...

  7. Mass Transfer Constraints On The Chemical Evolution Of An Active...

    Open Energy Info (EERE)

    component required to maintain observed calcite saturation and high Pco2 pressures was carbon presumably derived from underlying Paleozoic limestones. Phase rule constraints...

  8. Microsoft Word - EPAct_TRS_Greene Co Site_final_20140915.docx

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    ... 6 Figure 4: Structure contour map on a persistent limestone unit within ... 2) plugging and perforation to improve efficiency An Evaluation of Fracture Growth and ...

  9. Mining Industry Profile | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    These mined minerals include coal, metals such as iron, copper, or zinc, and industrial minerals such as potash, limestone, and other crushed rocks. Oil and natural gas extraction ...

  10. Stratigraphic Boundaries | Open Energy Information

    Open Energy Info (EERE)

    Tectonics Mississippian-Pennsylvanian; Pleistocene, 1.6 to 1.25 Ma Limestone-Madera Formation "MIPu"; Rhyolitic tuff-Intracaldera Bandelier Tuff (upper Tshirege "Qbt" and...

  11. Caldera Rim Margins | Open Energy Information

    Open Energy Info (EERE)

    Tectonics Mississippian-Pennsylvanian; Pleistocene, 1.6 to 1.25 Ma Limestone-Madera Formation "MIPu"; Rhyolitic tuff-Intracaldera Bandelier Tuff (upper Tshirege "Qbt" and...

  12. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reservior Technology Research Development and Demonstration ( 2001). Gallup, DL. Ore Geology Reviews(1998) 3 | US DOE Geothermal Office eere.energy.gov Impact of Research: Robust...

  13. Fermi Observations of High-Energy Gamma-Ray Emission from GRB...

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    Cruz ; Axelsson, M. ; Stockholm U., OKC Stockholm U. ; Baldini, L. ; INFN, Pisa ; Ballet, J. ; DAPNIA, Saclay ; Band, D.L. ; NASA, Goddard NASA, Goddard ; Barbiellini,...

  14. Fermi Observations of High-Energy Gamma-Ray Emission From GRB...

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    Cruz ; Axelsson, M. ; Stockholm U. Stockholm U., OKC ; Baldini, L. ; INFN, Pisa ; Ballet, J. ; DAPNIA, Saclay ; Band, D.L. ; NASA, Goddard ; Barbiellini, G. ; INFN, Trieste...

  15. Temperature coefficients for PV modules and arrays: Measurement...

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    methods, difficulties, and results King, D.L.; Kratochvil, J.A.; Boyson, W.E. 14 SOLAR ENERGY; SOLAR CELL ARRAYS; SOLAR CELLS; MEASURING METHODS; TEMPERATURE DEPENDENCE;...

  16. P

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    P - . . - - 4 v - r REQUEST FOR RECORDS Dl To: NATIONAL ARCHIVES and RECORDS ADMINISTRATION (NIR) WASHINGTON, DC 20408 1. FROM (Agency or establishment) NATIONAL ARCHIVES AND ...

  17. Most Viewed Documents for Renewable Energy Sources: September...

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    70 Seventh Edition Fuel Cell Handbook NETL (2004) 67 Temperature coefficients for PV modules and arrays: Measurement methods, difficulties, and results King, D.L.; Kratochvil, ...

  18. June 2015 Most Viewed Documents for Renewable Energy Sources...

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    102 Seventh Edition Fuel Cell Handbook NETL (2004) 97 Temperature coefficients for PV modules and arrays: Measurement methods, difficulties, and results King, D.L.; Kratochvil, ...

  19. Most Viewed Documents for Renewable Energy Sources: December...

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    Engineering cost analysis Higbee, Charles V. (1998) 54 Temperature coefficients for PV modules and arrays: Measurement methods, difficulties, and results King, D.L.; Kratochvil, ...

  20. September 2015 Most Viewed Documents for Renewable Energy Sources...

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    design and simulation Leeper, S.A. (1981) 190 Temperature coefficients for PV modules and arrays: Measurement methods, difficulties, and results King, D.L.; Kratochvil, ...

  1. Microsoft Word - Final Scientific - Technical Report_DE-EE0005390...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of computational platforms that can accomplish the necessary computing to various levels. The system available within Cooper that was used for this project was an HP DL585...

  2. Fuel gas desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Shen, Ming-Shing (Rocky Point, NY)

    1981-01-01

    A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.

  3. Sub-crop geologic map of pre-Tertiary rocks in the Yucca Flat and northern Frenchman Flat areas, Nevada Test Site, southern Nevada

    SciTech Connect (OSTI)

    Cole, J.C.; Harris, A.G.; Wahl, R.R.

    1997-10-02

    This map displays interpreted structural and stratigraphic relations among the Paleozoic and older rocks of the Nevada Test Site region beneath the Miocene volcanic rocks and younger alluvium in the Yucca Flat and northern Frenchman Flat basins. These interpretations are based on a comprehensive examination and review of data for more than 77 drillholes that penetrated part of the pre-Tertiary basement beneath these post-middle Miocene structural basins. Biostratigraphic data from conodont fossils were newly obtained for 31 of these holes, and a thorough review of all prior microfossil paleontologic data is incorporated in the analysis. Subsurface relationships are interpreted in light of a revised regional geologic framework synthesized from detailed geologic mapping in the ranges surrounding Yucca Flat, from comprehensive stratigraphic studies in the region, and from additional detailed field studies on and around the Nevada Test Site. All available data indicate the subsurface geology of Yucca Flat is considerably more complicated than previous interpretations have suggested. The western part of the basin, in particular, is underlain by relics of the eastward-vergent Belted Range thrust system that are folded back toward the west and thrust by local, west-vergent contractional structures of the CP thrust system. Field evidence from the ranges surrounding the north end of Yucca Flat indicate that two significant strike-slip faults track southward beneath the post-middle Miocene basin fill, but their subsurface traces cannot be closely defined from the available evidence. In contrast, the eastern part of the Yucca Flat basin is interpreted to be underlain by a fairly simple north-trending, broad syncline in the pre-Tertiary units. Far fewer data are available for the northern Frenchman Flat basin, but regional analysis indicates the pre-Tertiary structure there should also be relatively simple and not affected by thrusting. This new interpretation has implications for ground water flow through pre-Tertiary rocks beneath the Yucca Flat and northern Frenchman Flat areas, and has consequences for ground water modeling and model validation. Our data indicate that the Mississippian Chainman Shale is not laterally extensive confining unit in the western part of the basin because it is folded back onto itself by the convergent structures of the Belted Range and CP thrust systems. Early and Middle Paleozoic limestone and dolomite are present beneath most of both basins and, regardless of structural complications, are interpreted to form a laterally continuous and extensive carbonate aquifer. Structural culmination that marks the French Peak accommodation zone along the topographic divide between the two basins provides a lateral pathway through highly fractured rock between the volcanic aquifers of Yucca Flat and the regional carbonate aquifer. This pathway may accelerate the migration of ground-water contaminants introduced by underground nuclear testing toward discharge areas beyond the Nevada Test Site boundaries. Predictive three-dimensional models of hydrostratigraphic units and ground-water flow in the pre-Tertiary rocks of subsurface Yucca Flat are likely to be unrealistic due to the extreme structural complexities. The interpretation of hydrologic and geochemical data obtained from monitoring wells will be difficult to extrapolate through the flow system until more is known about the continuity of hydrostratigraphic units. 1 plate

  4. Evaluating the Influence of Pore Architecture and Initial Saturation on Wettability and Relative Permeability in Heterogeneous, Shallow-Shelf Carbonates

    SciTech Connect (OSTI)

    Alan P. Byrnes; Saibal Bhattacharya; John Victorine; Ken Stalder

    2007-09-30

    Thin (3-40 ft thick), heterogeneous, limestone and dolomite reservoirs, deposited in shallow-shelf environments, represent a significant fraction of the reservoirs in the U.S. midcontinent and worldwide. In Kansas, reservoirs of the Arbuckle, Mississippian, and Lansing-Kansas City formations account for over 73% of the 6.3 BBO cumulative oil produced over the last century. For these reservoirs basic petrophysical properties (e.g., porosity, absolute permeability, capillary pressure, residual oil saturation to waterflood, resistivity, and relative permeability) vary significantly horizontally, vertically, and with scale of measurement. Many of these reservoirs produce from structures of less than 30-60 ft, and being located in the capillary pressure transition zone, exhibit vertically variable initial saturations and relative permeability properties. Rather than being simpler to model because of their small size, these reservoirs challenge characterization and simulation methodology and illustrate issues that are less apparent in larger reservoirs where transition zone effects are minor and most of the reservoir is at saturations near S{sub wirr}. These issues are further augmented by the presence of variable moldic porosity and possible intermediate to mixed wettability and the influence of these on capillary pressure and relative permeability. Understanding how capillary-pressure properties change with rock lithology and, in turn, within transition zones, and how relative permeability and residual oil saturation to waterflood change through the transition zone is critical to successful reservoir management and as advanced waterflood and improved and enhanced recovery methods are planned and implemented. Major aspects of the proposed study involve a series of tasks to measure data to reveal the nature of how wettability and drainage and imbibition oil-water relative permeability change with pore architecture and initial water saturation. Focus is placed on carbonate reservoirs of widely varying moldic pore systems that represent the major of reservoirs in Kansas and are important nationally and worldwide. A goal of the project is to measure wettability, using representative oils from Kansas fields, on a wide range of moldic-porosity lithofacies that are representative of Kansas and midcontinent shallow-shelf carbonate reservoirs. This investigation will discern the relative influence of wetting and pore architecture. In the midcontinent, reservoir water saturations are frequently greater than 'irreducible' because many reservoirs are largely in the capillary transition zone. This can change the imbibition oil-water relative permeability relations. Ignoring wettability and transition-zone relative permeabilities in reservoir modeling can lead to over- and under-prediction of oil recovery and recovery rates, and less effective improved recovery management. A goal of this project is to measure drainage and imbibition oil-water relative permeabilities for a large representative range of lithofacies at differ ent initial water saturations to obtain relations that can be applied everywhere in the reservoir. The practical importance of these relative permeability and wettability models will be demonstrated by using reservoir simulation studies on theoretical/generic and actual reservoir architectures. The project further seeks to evaluate how input of these new models affects reservoir simulation results at varying scales. A principal goal is to obtain data that will allow us to create models that will show how to accurately simulate flow in the shallow-structure, complex carbonate reservoirs that lie in the transition zone. Tasks involved to meet the project objectives include collection and consolidation of available data into a publicly accessible relational digital database and collection of oil and rock samples from carbonate fields around the state (Task 1). Basic properties of these rocks and oils will be measured and used in wettability tests. Comparison will be performed between crude and synthetic oil wettability and

  5. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg; Robert K. Svec

    2002-12-20

    This document is the First Annual Report for the U.S. Department of Energy under contract No., a three-year contract entitled: ''Improving CO{sub 2} Efficiency for Recovering Oil in Heterogeneous Reservoirs.'' The research improved our knowledge and understanding of CO{sub 2} flooding and includes work in the areas of injectivity and mobility control. The bulk of this work has been performed by the New Mexico Petroleum Recovery Research Center, a research division of New Mexico Institute of Mining and Technology. This report covers the reporting period of September 28, 2001 and September 27, 2002. Injectivity continues to be a concern to the industry. During this period we have contacted most of the CO{sub 2} operators in the Permian Basin and talked again about their problems in this area. This report has a summary of what we found. It is a given that carbonate mineral dissolution and deposition occur in a formation in geologic time and are expected to some degree in carbon dioxide (CO{sub 2}) floods. Water-alternating-gas (WAG) core flood experiments conducted on limestone and dolomite core plugs confirm that these processes can occur over relatively short time periods (hours to days) and in close proximity to each other. Results from laboratory CO{sub 2}-brine flow experiments performed in rock core were used to calibrate a reactive transport simulator. The calibrated model is being used to estimate in situ effects of a range of possible sequestration options in depleted oil/gas reservoirs. The code applied in this study is a combination of the well known TOUGH2 simulator, for coupled groundwater/brine and heat flow, with the chemistry code TRANS for chemically reactive transport. Variability in response among rock types suggests that CO{sub 2} injection will induce ranges of transient and spatially dependent changes in intrinsic rock permeability and porosity. Determining the effect of matrix changes on CO{sub 2} mobility is crucial in evaluating the efficacy and potential environmental implications of storing CO{sub 2} in the subsurface. Chemical cost reductions are identified that are derived from the synergistic effects of cosurfactant systems using a good foaming agent and a less expensive poor foaming agent. The required good foaming agent is reduced by at least 75%. Also the effect on injectivity is reduced by as much as 50% using the cosurfactant system, compared to a previously used surfactant system. Mobility control of injected CO{sub 2} for improved oil recovery can be achieved with significant reduction in the chemical cost of SAG, improved injectivity of SAG, and improved economics of CO{sub 2} injection project when compared to reported systems. Our past work has identified a number of mobility control agents to use for CO{sub 2}-foam flooding. In particular the combination of the good foaming agent CD 1045 and a sacrificial agent and cosurfactant lignosulfonate. This work scrutinizes the methods that we are using to determine the efficiency of the sacrificial agents and cosurfactant systems. These have required concentration determinations and reusing core samples. Here, we report some of the problems that have been found and some interesting effects that must be considered.

  6. EXPLOITATION AND OPTIMIZATION OF RESERVOIR PERFORMANCE IN HUNTON FORMATION, OKLAHOMA

    SciTech Connect (OSTI)

    Mohan Kelkar

    2003-10-01

    This report presents the work done so far on Hunton Formation in West Carney Field in Lincoln County, Oklahoma. West Carney Field produces oil and gas from the Hunton Formation. The field was developed starting in 1995. Some of the unique characteristics of the field include decreasing water oil ratio over time, decreasing gas-oil ratio at the beginning of production, inability to calculate oil reserves in the field based on log data, and sustained oil rates over long periods of time. To understand the unique characteristics of the field, an integrated evaluation was undertaken. Production data from the field were meticulously collected, and over forty wells were cored and logged to better understand the petrophysical and engineering characteristics. Based on the work done in this budget period so far, some of the preliminary conclusions can be listed as follows: (1) Based on PVT analysis, the field most likely contains volatile oil with bubble point close to initial reservoir pressure of 1,900 psia. (2) The initial oil in place, which is contact with existing wells, can be determined by newly developed material balance technique. The oil in place, which is in communication, is significantly less than determined by volumetric analysis, indicating heterogeneous nature of the reservoir. The oil in place, determined by material balance, is greater than determined by decline curve analysis. This difference may lead to additional locations for in fill wells. (3) The core and log evaluation indicates that the intermediate pores (porosity between 2 and 6 %) are very important in determining production potential of the reservoir. These intermediate size pores contain high oil saturation. (4) The limestone part of the reservoir, although low in porosity (mostly less than 6 %) is much more prolific in terms of oil production than the dolomite portion of the reservoir. The reason for this difference is the higher oil saturation in low porosity region. As the average porosity increases, the remaining oil saturation decreases. This is evident from log and core analysis. (5) Using a compositional simulator, we are able to reproduce the important reservoir characteristics by assuming a two layer model. One layer is high permeability region containing water and the other layer is low permeability region containing mostly oil. The results are further verified by using a dual porosity model. Assuming that most of the volatile oil is contained in the matrix and the water is contained in the fractures, we are able to reproduce important reservoir performance characteristics. (6) Evaluation of secondary mechanisms indicates that CO{sub 2} flooding is potentially a viable option if CO{sub 2} is available at reasonable price. We have conducted detailed simulation studies to verify the effectiveness of CO{sub 2} huff-n-puff process. We are in the process of conducting additional lab tests to verify the efficacy of the same displacement. (7) Another possibility of improving the oil recovery is to inject surfactants to change the near well bore wettability of the rock from oil wet to water wet. By changing the wettability, we may be able to retard the water flow and hence improve the oil recovery as a percentage of total fluid produced. If surfactant is reasonably priced, other possibility is also to use huff-n-puff process using surfactants. Laboratory experiments are promising, and additional investigation continues. (8) Preliminary economic evaluation indicates that vertical wells outperform horizontal wells. Future work in the project would include: (1) Build multi-well numerical model to reproduce overall reservoir performance rather than individual well performance. Special emphasis will be placed on hydrodynamic connectivity between wells. (2) Collect data from adjacent Hunton reservoirs to validate our understanding of what makes it a productive reservoir. (3) Develop statistical methods to rank various reservoirs in Hunton formation. This will allow us to evaluate other Hunton formations based on old well logs, and determine, apriori, if

  7. Identification of an Archean marine oxygen oasis

    SciTech Connect (OSTI)

    Riding, Dr Robert E; Fralick, Dr Philip; Liang, Liyuan

    2014-01-01

    The early Earth was essentially anoxic. A number of indicators suggest the presence of oxygenic photosynthesis 2700 3000 million years (Ma) ago, but direct evidence for molecular oxygen (O2) in seawater has remained elusive. Here we report rare earth element (REE) analyses of 2800 million year old shallowmarine limestones and deep-water iron-rich sediments at Steep Rock Lake, Canada. These show that the seawater from which extensive shallow-water limestones precipitated was oxygenated, whereas the adjacent deeper waters where iron-rich sediments formed were not. We propose that oxygen promoted limestone precipitation by oxidative removal of dissolved ferrous iron species, Fe(II), to insoluble Fe(III) oxyhydroxide, and estimate that at least 10.25 M oxygen concentration in seawater was required to accomplish this at Steep Rock. This agrees with the hypothesis that an ample supply of dissolved Fe(II) in Archean oceans would have hindered limestone formation. There is no direct evidence for the oxygen source at Steep Rock, but organic carbon isotope values and diverse stromatolites in the limestones suggest the presence of cyanobacteria. Our findings support the view that during the Archean significant oxygen levels first developed in protected nutrient-rich shallow marine habitats. They indicate that these environments were spatially restricted, transient, and promoted limestone precipitation. If Archean marine limestones in general reflect localized oxygenic removal of dissolved iron at the margins of otherwise anoxic iron-rich seas, then early oxygen oases are less elusive than has been assumed.

  8. Lead in human blood from children living in Campania, Italy

    SciTech Connect (OSTI)

    Amodio-Cocchieri, R.; Arnese, A.; Prospero, E.; Roncioni, A.

    1996-03-01

    Blood lead (PbB) levels were determined in children living Campania (in Naples and in a rural zone in the district of Caserta). Atmospheric lead (PbA) concentration in these considered areas was monitored for 1 yr (1993-1994). The children tested were questioned about common sources of lead, other than atmospheric relating to their living and dietary habits. The PbB levels in children living in Naples were at the 50th percentile, 18.8 {mu}g/dl in males and 13.7 {mu}g/dl in females; in children living in the rural area the median PbB levels were 8.9{mu}g/dl in males, and 9.9 {mu}g/dl in females. The annual mean values of atmospheres lead were 1.15 {plus_minus} 0.24 {mu}g/dl in Naples and 0.23 {plus_minus} 0.07 {mu}g/dl in the rural area. Significant and congruent mean differences between urban and rural sites were found in children`s blood and concurrent air lead. Considering the PbB level of 10 {mu}g/dl as the maximum level that is not associated any known adverse effect in children, the Neapolitan group can be considered at risk of chronic intoxication by lead. 18 refs., 3 figs., 4 tabs.

  9. Coronal electron confinement by double layers

    SciTech Connect (OSTI)

    Li, T. C.; Drake, J. F.; Swisdak, M.

    2013-12-01

    In observations of flare-heated electrons in the solar corona, a longstanding problem is the unexplained prolonged lifetime of the electrons compared to their transit time across the source. This suggests confinement. Recent particle-in-cell (PIC) simulations, which explored the transport of pre-accelerated hot electrons through ambient cold plasma, showed that the formation of a highly localized electrostatic potential drop, in the form of a double layer (DL), significantly inhibited the transport of hot electrons. The effectiveness of confinement by a DL is linked to the strength of the DL as defined by its potential drop. In this work, we investigate the scaling of the DL strength with the hot electron temperature by PIC simulations and find a linear scaling. We demonstrate that the strength is limited by the formation of parallel shocks. Based on this, we analytically determine the maximum DL strength, and also find a linear scaling with the hot electron temperature. The DL strength obtained from the analytic calculation is comparable to that from the simulations. At the maximum strength, the DL is capable of confining a significant fraction of hot electrons in the source.

  10. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention ? Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term ?globule? refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 ?m range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 ?m or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 ?m (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety

  11. Basic Data Report for Drillhole SNL-3 (C-2949)

    SciTech Connect (OSTI)

    Dennis W. Powers; Washington Regulatory and Environmental Services

    2005-01-20

    SNL-3 (permitted by the New Mexico State Engineer as C-2949) was drilled to provide geological data and hydrological testing of the Culebra Dolomite Member of the Permian Rustler Formation within a dissolution reentrant north of the WIPP site and well east of Livingston Ridge. SNL-3 is located in the southeast quarter of section 34, T21S, R31E, in eastern Eddy County, New Mexico. SNL-3 was drilled to a total depth of 970 ft below ground level (bgl). Below surface dune sand, SNL-3 encountered, in order, the Mescalero caliche, Gatuna, Dewey Lake, Rustler, and upper Salado Formations. Two intervals were cored: (1) from the lower Forty-niner Member through the Magenta Dolomite and into the upper Tamarisk Member; and (2) from the lower Tamarisk Member through the Culebra Dolomite and Los Meda?os Members and into the uppermost Salado.

  12. CX-012445: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation CX(s) Applied: A11Date: 41878 Location(s): IllinoisOffices(s): National Energy Technology Laboratory

  13. Pinch valves fight clogging, leaking and wear in FGD systems

    SciTech Connect (OSTI)

    Schneider, L.

    1982-12-01

    Pinch valves can provide a non-sticking, non-leaking, low maintenance system capable of controlling the flow of abrasive limestone slurries such as are found in flue gas desulphurisation units.

  14. ITP Mining: Energy and Environmental Profile of the U.S. Mining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Chapter 5 - Copper PDF icon Chapter 6 - Lead and Zinc PDF icon Chapter 7 - Gold and Silver PDF icon Chapter 8 - Phosphate PDF icon Chapter 9 - Limestone and Crushed ...

  15. Zeolitic Alteration | Open Energy Information

    Open Energy Info (EERE)

    Caldera Rim Margins Mississippian-Pennsylvanian; Pleistocene, 1.6 to 1.25 Ma Limestone-Madera Formation "MIPu"; Rhyolitic tuff-Intracaldera Bandelier Tuff (upper Tshirege "Qbt" and...

  16. BPA-2011-00611-FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2011 . C1IVEas tip' BPA OIA OFI "E THIS %TE:: 'f 1 Ms. Christina Munro :;L;E D."l s- FOIA Office Bonneville Power Administration ' Routing: DK-7 ,x ; P.O. Box 3621 f,4 ,...

  17. MIT Plasma Science & Fusion Center: research, alcator, publications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Winslow, D.L. - Edge Fluctuation Measurements with a Triple Probe on Alcator C-Mod, FRC, Univ. of TX Elder, J.D. - Univ. of Toronto Poster PDF (4.9MB) Terry, J.L. -...

  18. CamSemi | Open Energy Information

    Open Energy Info (EERE)

    CamSemi Jump to: navigation, search Name: CamSemi Place: Cambridge, United Kingdom Zip: CB4 1DL Product: CamSemi is developing a new generation of highly-intelligent, single chip...

  19. ILDS

    Energy Science and Technology Software Center (OSTI)

    003176IBMPC00 Intelligent Leak Detection System https://www.dropbox.com/sh/aycss2bffzmur10/AAAJvqH8IKmrA93kngsAy45qa?dl=0

  20. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Treatment Using a Single-Column Model and ARM Observations Iacobellis, S.F. (a), Mitchell, D.L. (b), and Somerville, R.C.J. (a), Scripps Institution of Oceanography (a),...

  1. IDENTIFYING FRACTURES AND FLUID TYPES USING FLUID INCLUSION STRATIGRAP...

    Open Energy Info (EERE)

    affects the wall rock at distances of 5 to 10 feet beyond the fracture. Authors Dilley, L.M.; Newman, D.L. ; McCulloch and J.; Published PROCEEDINGS, Thirtieth Workshop on...

  2. Fluid Inclusion Stratigraphy: Interpretation of New Wells in...

    Open Energy Info (EERE)

    to moderate producers, problem producers, injectors, and non producers Authors Dilley, L.M.; Newman, D.L. ; McCulloch, J.; Wiggett and G. Published Geothermal Resource Council...

  3. Newbie here. Is there any software/site which can poll my utility...

    Open Energy Info (EERE)

    Newbie here. Is there any softwaresite which can poll my utility to DL my green data file and email it to me? Home My provider is JEA. They only provide the Green Data download...

  4. December 2015 Most Viewed Documents for Renewable Energy Sources...

    Office of Scientific and Technical Information (OSTI)

    salt content between 5 and 25% Dittman, G.L. (1977) 228 Temperature coefficients for PV modules and arrays: Measurement methods, difficulties, and results King, D.L.; Kratochvil, ...

  5. March 2015 Most Viewed Documents for Renewable Energy Sources...

    Office of Scientific and Technical Information (OSTI)

    ...ZnOAl sub 2 O sub 3 catalyst Al-Adwani, H.A. (1992) 97 Temperature coefficients for PV modules and arrays: Measurement methods, difficulties, and results King, D.L.; Kratochvil, ...

  6. Borehole geophysics evaluation of the Raft River geothermal reservoir...

    Open Energy Info (EERE)

    HYDROTHERMAL SYSTEMS; NORTH AMERICA; PACIFIC NORTHWEST REGION; USA Authors Applegate, J.K.; Donaldson, P.R.; Hinkley, D.L.; Wallace and T.L. Published Journal Geophysics, 21...

  7. Profile for Enrique Ricardo Batista

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol.129, iss.23, p.7224-+, JUN 13 2007. Yang, P * Batista, ER * Tretiak, S * Saxena, A * Martin, RL * Smith, DL, "Effect of...

  8. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Radiative Properties Stackhouse, P.W., Jr. (a), Mitchell, D.L. (b), and Yang, P. (c), NASA Langley Research Center (a), Desert Research Institute (b), NASA Goddard...

  9. Docker File System Isolation By Darrin Schmitz David Huff Destiny...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Docker File System Isolation By Darrin Schmitz David Huff Destiny Velasquez 1 LA-UR-15-25911 Specifications * HP ProLiant DL380p Gen8 servers * Head node has 32 cores and 32 GB RAM...

  10. Household Vehicles Energy Consumption 1994

    U.S. Energy Information Administration (EIA) Indexed Site

    DC, October 1995), Table DL-1B. 5. "Chained dollars" is a measure used to express real prices. Real prices are those that have been adjusted to remove the effect of changes...

  11. HOW TO OBTAIN EIA PRODUCTS AND SERVICES

    U.S. Energy Information Administration (EIA) Indexed Site

    DC, October 1995), Table DL-1B. 5. "Chained dollars" is a measure used to express real prices. Real prices are those that have been adjusted to remove the effect of changes...

  12. Residential

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MacDonald and D.L. White. Oak Ridge National Laboratory. ORNLCON-304.(5-91) InfiltrationVentilation Measurements in RCDP Manufactured Homes. Pacific Northwest Laboratory, D....

  13. The Sloan Digital Sky Survey Monitor Telescope Pipeline (Journal...

    Office of Scientific and Technical Information (OSTI)

    Authors: Tucker, D.L. ; Kent, S. ; Richmond, M.W. ; Annis, J. ; Smith, J.A. ; Allam, S.S. ; Rodgers, C.T. ; Stute, J.L. ; Adelman-McCarthy, Jennifer K. ; Brinkmann, J. ; Doi, M. ;...

  14. ARM Mentor Selection Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research DOE U.S. Department of Energy DQ data quality QA quality assurance QC quality control DL Sisterson, October 2015, DOESC-ARM-TR-171 1 Contents Acronyms and...

  15. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Revised Treatment of Cirrus Microphysics on the Radiation Budget of the Unified Model Edwards, J.M. (a), Mitchell, D.L. (b), Ivanova, D. (b), and Wilson, D.R. (a), Met Office,...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Working Group(s): Cloud Life Cycle Journal Reference: Ma H, S Xie, SA Klein, KD Williams, JS Boyle, S Bony, H Douville, S Fermepin, B Medeiros, S Tyteca, M Watanabe, and DL...

  17. Most Viewed Documents - Materials | OSTI, US Dept of Energy,...

    Office of Scientific and Technical Information (OSTI)

    and Seebeck coefficients of unirradiated and irradiated graphites from 300 to 1000 K Moore, J.P.; Graves, R.S.; McElroy, D.L. (1973) LITERATURE SURVEY ON DILUTE URANIUM ALLOYS ...

  18. Reference Linking at the DOE Office of Scientific and Technical...

    Office of Scientific and Technical Information (OSTI)

    Links Without Reference Links Spin Polarized Electron Probes and Magnetic Nanostructures PDF PDF Identifier Number: 816290 - CreatorAuthor: Mills, D.L. Often, when a DOE R&D...

  19. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieval of Ice Water Path Using Thermal Channels Mitchell, D.L. (a), d'Entremont, R.P. (b), Stackhouse, P.W., Jr. (c), and Heymsfield, A.J. (d), Desert Research Institute (a),...

  20. Laser Wakefield Particle Acceleration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in new capability for rapid data exploration and analysis. Investigators: Cameron Geddes, Jean-Luc Vay, Carl Schroeder, E. Cormier-Michel, E. Esarey, W.P. Leemans (LBNL); D.L....

  1. Climate Action Champions: Dubuque, IA | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dubuque, IA Climate Action Champions: Dubuque, IA The City of Dubuque, Iowa, features a rich history, a diverse arts and cultural scene, and abundant natural beauty, including majestic limestone bluffs along the Mississippi riverfront. Sustainability is among the city’s top priorities for the future. | Photo courtesy of the City of Dubuque. The City of Dubuque, Iowa, features a rich history, a diverse arts and cultural scene, and abundant natural beauty, including majestic limestone bluffs

  2. INDIA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM instruments on top of the ARIES Observatory in Nainital Doppler Lidar (DL) Shortwave Array Spectroradiometers, both Hemispheric and Zenith (SASHE and SASZE) Shortwave Array Spectroradiometers, both Hemispheric and Zenith (SASHE and SASZE) Total Sky Imager (TSI) on the far left, Cimel Sunphotometer (CSPHOT) center, and Sky Radiometers on Stand for Downwelling Radiation (SKYRAD) to the right Sky Radiometers on Stand for Downwelling Radiation (SKYRAD) Total Sky Imager (TSI) Doppler Lidar (DL)

  3. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Mica, biotite, muscovite, diopside, tremolite, ultramafic rock, hematite, Ca-Mg-carbonate, calcite, aragonite, dolomite, crystal nucleation,

  4. Improved oil recovery in Mississippian carbonate reservoirs of Kansas - near term -- Class 2. Quarterly progress report, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    Carr, T.; Green, D.W.; Willhite, G.P.

    1995-11-01

    The objective of this project is to demonstrate incremental reserves from Osagian and Meramecian dolomite reservoirs in western Kansas through application of reservoir characterization to identify areas of unrecovered mobile petroleum. Specific reservoirs targeted are the Schaben Field in Ness County and the Bindley Field in Hodgeman County.

  5. The Bakken - An Unconventional Petroleum and Reservoir System

    SciTech Connect (OSTI)

    Sarg, J.

    2011-12-31

    An integrated geologic and geophysical study of the Bakken Petroleum System, in the Williston basin of North Dakota and Montana indicates that: (1) dolomite is needed for good reservoir performance in the Middle Bakken; (2) regional and local fractures play a significant role in enhancing permeability and well production, and it is important to recognize both because local fractures will dominate in on-structure locations; and (3) the organic-rich Bakken shale serves as both a source and reservoir rock. The Middle Bakken Member of the Bakken Formation is the target for horizontal drilling. The mineralogy across all the Middle Bakken lithofacies is very similar and is dominated by dolomite, calcite, and quartz. This Member is comprised of six lithofacies: (A) muddy lime wackestone, (B) bioturbated, argillaceous, calcareous, very fine-grained siltstone/sandstone, (C) planar to symmetrically ripple to undulose laminated, shaly, very fine-grained siltstone/sandstone, (D) contorted to massive fine-grained sandstone, to low angle, planar cross-laminated sandstone with thin discontinuous shale laminations, (E) finely inter-laminated, bioturbated, dolomitic mudstone and dolomitic siltstone/sandstone to calcitic, whole fossil, dolomitic lime wackestone, and (F) bioturbated, shaly, dolomitic siltstone. Lithofacies B, C, D, and E can all be reservoirs, if quartz and dolomite-rich (facies D) or dolomitized (facies B, C, E). Porosity averages 4-8%, permeability averages 0.001-0.01 mD or less. Dolomitic facies porosity is intercrystalline and tends to be greater than 6%. Permeability may reach values of 0.15 mD or greater. This appears to be a determinant of high productive wells in Elm Coulee, Parshall, and Sanish fields. Lithofacies G is organic-rich, pyritic brown/black mudstone and comprises the Bakken shales. These shales are siliceous, which increases brittleness and enhances fracture potential. Mechanical properties of the Bakken reveal that the shales have similar effective stress as the Middle Bakken suggesting that the shale will not contain induced fractures, and will contribute hydrocarbons from interconnected micro-fractures. Organic-rich shale impedance increases with a reduction in porosity and an increase in kerogen stiffness during the burial maturation process. Maturation can be directly related to impedance, and should be seismically mappable. Fractures enhance permeability and production. Regional fractures form an orthogonal set with a dominant NE-SW trend, and a less prominent NW-SE trend. Many horizontal 1 direction to intersect these fractures. Local structures formed by basement tectonics or salt dissolution generate both hinge parallel and hinge oblique fractures that may overprint and dominate the regional fracture signature. Horizontal microfractures formed by oil expulsion in the Bakken shales, and connected and opened by hydrofracturing provide permeability pathways for oil flow into wells that have been hydro-fractured in the Middle Bakken lithofacies. Results from the lithofacies, mineral, and fracture analyses of this study were used to construct a dual porosity Petrel geo-model for a portion of the Elm Coulee Field. In this field, dolomitization enhances reservoir porosity and permeability. First year cumulative production helps locate areas of high well productivity and in deriving fracture swarm distribution. A fracture model was developed based on high productivity well distribution, and regional fracture distribution, and was combined with favorable matrix properties to build a dual porosity geo-model.

  6. The Bakken-An Unconventional Petroleum and Reservoir System

    SciTech Connect (OSTI)

    Frederick Sarg

    2011-12-31

    An integrated geologic and geophysical study of the Bakken Petroleum System, in the Williston basin of North Dakota and Montana indicates that: (1) dolomite is needed for good reservoir performance in the Middle Bakken; (2) regional and local fractures play a significant role in enhancing permeability and well production, and it is important to recognize both because local fractures will dominate in on-structure locations; and (3) the organic-rich Bakken shale serves as both a source and reservoir rock. The Middle Bakken Member of the Bakken Formation is the target for horizontal drilling. The mineralogy across all the Middle Bakken lithofacies is very similar and is dominated by dolomite, calcite, and quartz. This Member is comprised of six lithofacies: (A) muddy lime wackestone, (B) bioturbated, argillaceous, calcareous, very fine-grained siltstone/sandstone, (C) planar to symmetrically ripple to undulose laminated, shaly, very fine-grained siltstone/sandstone, (D) contorted to massive fine-grained sandstone, to low angle, planar cross-laminated sandstone with thin discontinuous shale laminations, (E) finely inter-laminated, bioturbated, dolomitic mudstone and dolomitic siltstone/sandstone to calcitic, whole fossil, dolomitic lime wackestone, and (F) bioturbated, shaly, dolomitic siltstone. Lithofacies B, C, D, and E can all be reservoirs, if quartz and dolomite-rich (facies D) or dolomitized (facies B, C, E). Porosity averages 4-8%, permeability averages 0.001-0.01 mD or less. Dolomitic facies porosity is intercrystalline and tends to be greater than 6%. Permeability may reach values of 0.15 mD or greater. This appears to be a determinant of high productive wells in Elm Coulee, Parshall, and Sanish fields. Lithofacies G is organic-rich, pyritic brown/black mudstone and comprises the Bakken shales. These shales are siliceous, which increases brittleness and enhances fracture potential. Mechanical properties of the Bakken reveal that the shales have similar effective stress as the Middle Bakken suggesting that the shale will not contain induced fractures, and will contribute hydrocarbons from interconnected micro-fractures. Organic-rich shale impedance increases with a reduction in porosity and an increase in kerogen stiffness during the burial maturation process. Maturation can be directly related to impedance, and should be seismically mappable. Fractures enhance permeability and production. Regional fractures form an orthogonal set with a dominant NE-SW trend parallel to ?1, and a less prominent NW-SE trend. Many horizontal wells are drilled perpendicular to the ?1 direction to intersect these fractures. Local structures formed by basement tectonics or salt dissolution generate both hinge parallel and hinge oblique fractures that may overprint and dominate the regional fracture signature. Horizontal microfractures formed by oil expulsion in the Bakken shales, and connected and opened by hydrofracturing provide permeability pathways for oil flow into wells that have been hydro-fractured in the Middle Bakken lithofacies. Results from the lithofacies, mineral, and fracture analyses of this study were used to construct a dual porosity Petrel geo-model for a portion of the Elm Coulee Field. In this field, dolomitization enhances reservoir porosity and permeability. First year cumulative production helps locate areas of high well productivity and in deriving fracture swarm distribution. A fracture model was developed based on high productivity well distribution, and regional fracture distribution, and was combined with favorable matrix properties to build a dual porosity geo-model.

  7. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, April 1993--June 1993

    SciTech Connect (OSTI)

    Randolph, A.D.; Kwon, T.M.

    1993-12-01

    Precipitation and hydrolysis of the N-S compounds in the waste scrubbing liquor provided by Dravo Lime Co. was investigated. Precipitation of N-S compounds by a metathetical reaction with potassium sulfate was performed in continuous crystallizers. A preliminary operation showed that compared to a typical Mixed-Suspension-Mixed-Product-Removal (MSMPR) crystallizer, the Double-Draw-Off (DDO) crystallizer was superior by increasing the average size of the precipitated crystals of N-S compounds from 173 {mu}m to 218 {mu}m. However, the hydrolysis characteristics of the precipitated crystals were not dependent upon crystallizer type. A brief description of a new process which uses lime/limestone for precipitation of N-S compounds in the scrubbing liquor is presented. Preliminary investigations showed the lime/limestone process is efficient in precipitating N-S compounds and the precipitated crystals were shown to be more easily hydrolyzed than potassium salts of N-S compounds. This lime/limestone process is a novel process which seems better than the K{sub 2}SO{sub 4} process because one does not need to purchase/introduce a new chemical additive to precipitate in the lime/limestone Fe-EDTA wet scrubbing processes. Up to the present, the authors focused on developing the K{sub 2}SO{sub 4} process following their original proposal. However, the new lime/limestone process seems more advantageous in terms of economy and environmental safety. Therefore, it seems desirable changing research phase and putting an emphasis on the development of the lime/limestone process. Future study will include investigation of the DDO crystallizer operation to increase the size of precipitated crystals and thus to enhance their processibility. This study seems to be essential to the new lime/limestone process since the precipitated crystals are relatively small in size and thus poor in filterability.

  8. Elastic properties, sp fraction, and Raman scattering in low and high pressure synthesized diamond-like boron rich carbides

    SciTech Connect (OSTI)

    Zinin, Pavel V.; Burgess, Katherine; Jia, Ruth; Sharma, Shiv; Ming, Li-Chung; Liu, Yongsheng; Ciston, Jim; Hong, Shiming

    2014-10-07

    Dense BC{sub x} phases with high boron concentration are predicted to be metastable, superhard, and conductors or superconductors depending on boron concentration. However, up to this point, diamond-like boron rich carbides BC{sub x} (dl-BC{sub x}) phases have been thought obtainable only through high pressure and high temperature treatment, necessitating small specimen volume. Here, we use electron energy loss spectroscopy combined with transmission electron microscopy, Raman spectroscopy, surface Brillouin scattering, laser ultrasonics (LU) technique, and analysis of elastic properties to demonstrate that low pressure synthesis (chemical vapor deposition) of BC{sub x} phases may also lead to the creation of diamond-like boron rich carbides. The elastic properties of the dl-BC{sub x} phases depend on the carbon spversus sp content, which decreases with increasing boron concentration, while the boron bonds determine the shape of the Raman spectra of the dl-BC{sub x} after high pressure-high temperature treatment. Using the estimation of the density value based on the sp fraction, the shear modulus ? of dl-BC?, containing 10% carbon atoms with sp bonds, and dl-B?C?, containing 38% carbon atoms with sp bonds, were found to be ? = 19.3 GPa and ? = 170 GPa, respectively. The presented experimental data also imply that boron atoms lead to a creation of sp bonds during the deposition processes.

  9. Electric utility engineer`s FGD manual -- Volume 1: FGD process design. Final report

    SciTech Connect (OSTI)

    1996-03-04

    Part 1 of the Electric Utility Engineer`s Flue Gas Desulfurization (FGD) Manual emphasizes the chemical and physical processes that form the basis for design and operation of lime- and limestone-based FGD systems applied to coal- or oil-fired steam electric generating stations. The objectives of Part 1 are: to provide a description of the chemical and physical design basis for lime- and limestone-based wet FGD systems; to identify and discuss the various process design parameters and process options that must be considered in developing a specification for a new FGD system; and to provide utility engineers with process knowledge useful for operating and optimizing a lime- or limestone-based wet FGD system.

  10. Aerosols released during large-scale integral MCCI tests in the ACE Program

    SciTech Connect (OSTI)

    Fink, J.K.; Thompson, D.H.; Spencer, B.W.; Sehgal, B.R.

    1992-04-01

    As part of the internationally sponsored Advanced Containment Experiments (ACE) program, seven large-scale experiments on molten core concrete interactions (MCCIs) have been performed at Argonne National Laboratory. One of the objectives of these experiments is to collect and characterize all the aerosols released from the MCCIs. Aerosols released from experiments using four types of concrete (siliceous, limestone/common sand, serpentine, and limestone/limestone) and a range of metal oxidation for both BWR and PWR reactor core material have been collected and characterized. Release fractions were determined for UO{sup 2}, Zr, the fission-products: BaO, SrO, La{sub 2}O{sub 3}, CeO{sub 2}, MoO{sub 2}, Te, Ru, and control materials: Ag, In, and B{sub 4}C. Release fractions of UO{sub 2} and the fission products other than Te were small in all tests. However, release of control materials was significant.

  11. Aerosols released during large-scale integral MCCI tests in the ACE Program

    SciTech Connect (OSTI)

    Fink, J.K.; Thompson, D.H.; Spencer, B.W. ); Sehgal, B.R. )

    1992-01-01

    As part of the internationally sponsored Advanced Containment Experiments (ACE) program, seven large-scale experiments on molten core concrete interactions (MCCIs) have been performed at Argonne National Laboratory. One of the objectives of these experiments is to collect and characterize all the aerosols released from the MCCIs. Aerosols released from experiments using four types of concrete (siliceous, limestone/common sand, serpentine, and limestone/limestone) and a range of metal oxidation for both BWR and PWR reactor core material have been collected and characterized. Release fractions were determined for UO{sup 2}, Zr, the fission-products: BaO, SrO, La{sub 2}O{sub 3}, CeO{sub 2}, MoO{sub 2}, Te, Ru, and control materials: Ag, In, and B{sub 4}C. Release fractions of UO{sub 2} and the fission products other than Te were small in all tests. However, release of control materials was significant.

  12. Worker lead exposures during renovation of homes with lead-based paint

    SciTech Connect (OSTI)

    Sussell, A.; Gittleman, J.; Singal, M.

    1998-11-01

    The authors evaluated lead exposures among full-time home renovators and part-time volunteers working primarily in pre-1960 homes with lead-based paint. Potentially hazardous lead exposures were measured during two tasks: exterior dry scraping and wet scraping. Maximum exposures were 120 and 63 {micro}g/m{sup 3}, respectively. Exposures during other tasks, including general repair, weatherization, exterior scraping/painting, window replacement, demolition, and plumbing, were low, as were all 13 full-shift personal exposures. Blood lead levels for full-time workers ranged up to 17.5 {micro}g/dl, with a GM of 5.2 {micro}g/dl; the GM for volunteers was 3.2 {micro}g/dl. All of the paint samples collected from work surfaces had detectable amounts of lead, with 65% of the work surfaces tested having an average lead concentration of >0.5%.

  13. ADVANCED CHARACTERIZATION OF FRACTURED RESERVOIRS IN CARBONATE ROCKS: THE MICHIGAN BASIN

    SciTech Connect (OSTI)

    James R. Wood; William B. Harrison

    2002-12-01

    The purpose of the study was to collect and analyze existing data on the Michigan Basin for fracture patterns on scales ranging form thin section to basin. The data acquisition phase has been successfully concluded with the compilation of several large digital databases containing nearly all the existing information on formation tops, lithology and hydrocarbon production over the entire Michigan Basin. These databases represent the cumulative result of over 80 years of drilling and exploration. Plotting and examination of these data show that contrary to most depictions, the Michigan Basin is in fact extensively faulted and fractured, particularly in the central portion of the basin. This is in contrast to most of the existing work on the Michigan Basin, which tends to show relatively simple structure with few or minor faults. It also appears that these fractures and faults control the Paleozoic sediment deposition, the subsequent hydrocarbon traps and very likely the regional dolomitization patterns. Recent work has revealed that a detailed fracture pattern exists in the interior of the Central Michigan Basin, which is related to the mid-continent gravity high. The inference is that early Precambrian, ({approx}1 Ga) rifting events presumed by many to account for the gravity anomaly subsequently controlled Paleozoic sedimentation and later hydrocarbon accumulation. There is a systematic relationship between the faults and a number of gas and oil reservoirs: major hydrocarbon accumulations consistently occur in small anticlines on the upthrown side of the faults. The main tools used in this study to map the fault/fracture patterns are detailed, close-interval (CI = 10 feet) contouring of the formation top picks accompanied by a new way of visualizing the data using a special color spectrum to bring out the third dimension. In addition, recent improvements in visualization and contouring software were instrumental in the study. Dolomitization is common in the Michigan Basin, and it is crucial in developing reservoir quality rocks in some fields. Data on the occurrence of dolomite was extracted from driller's reports for all reported occurrences in Michigan, nearly 50 fields and over 500 wells. A digital database was developed containing the geographic location of all these wells (latitude-longitude) as well as the elevation of the first encounter of dolomite in the field/reservoir. Analysis shows that these dolomite occurrences are largely confined to the center of the basin, but with some exceptions, such as N. Adams Field. Further, some of the dolomite occurrences show a definite relationship to the fracture pattern described above, suggesting a genetic relationship that needs further work. Other accomplishments of this past reporting period include obtaining a complete land grid for the State of Michigan and further processing of the high and medium resolution DEM files. We also have measured new fluid inclusion data on dolomites from several fields that suggest that the dolomitization occurred at temperatures between 100 and 150 C. Finally, we have extracted the lithologic data for about 5000 wells and are in the process of integrating this data into the overall model for the Michigan Basin.

  14. Shell appraising deepwater discovery off Philippines

    SciTech Connect (OSTI)

    Scherer, M. ); Lambers, E.J.T.; Steffens, G.S. )

    1993-05-10

    Shell International Petroleum Co. Ltd. negotiated a farmout in 1990 from Occidental International Exploration and Production Co. for Block SC-38 in the South China Sea off Palawan, Philippines, following Oxy's discovery of gas in 1989 in a Miocene Nido limestone buildup. Under the terms of the farmout agreement, Shell became operator with a 50% share. Following the disappointing well North Iloc 1, Shell was successful in finding oil and gas in Malampaya 1. Water 700-1,000 m deep, remoteness, and adverse weather conditions have imposed major challenges for offshore operations. The paper describes the tectonic setting; the Nido limestone play; the Malampaya discovery; and Shell's appraisal studies.

  15. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  16. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  17. Double layer -- a particle accelerator in the magnetosphere

    SciTech Connect (OSTI)

    Fu, Xiangrong

    2015-07-16

    Slides present the material under the following topics: Introduction (What is a double layer (DL)? Why is it important? Key unsolved problems); Theory -- time-independent solutions of 1D Vlasov--Poisson system; Particle-in-cell simulations (Current-driven DLs); and Electron acceleration by DL (Betatron acceleration). Key problems include the generation mechanism, stability, and electron acceleration. In summary, recent observations by Van Allen Probes show large number of DLs in the outer radiation belt, associated with enhanced flux of relativistic electrons. Simulations show that ion acoustic double layers can be generated by field-aligned currents. Thermal electrons can gain energy via betatron acceleration in a dipole magnetic field.

  18. DISCLAIMER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM-TR-101 Doppler Lidar (DL) Handbook RK Newsom February 2012 Work supported by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research RK Newsom, February 2012, DOE/SC-ARM-TR-101 iii Acronyms and Abbreviations AGL above ground level AMF ARM Mobile Facility AMFDL AMF Doppler Lidar ARM Atmospheric Radiation Measurement DL Doppler Lidar DMF Data Management Facility DOE U.S. Department of Energy DQO Data Quality Office GVAX Ganges Valley Aerosol Experiment

  19. Ms. Maria Galanti Site Coordinator

    Office of Environmental Management (EM)

    ? 5 2011 PPPO-03-1251788-11 Ohio Environmental Protection Agency Southeast District Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: TRANSMITTAL OF Dl CONSTRUCTION COMPLETION REPORT FOR PHASES I AND II OF THE REMOVAL OF THE X-760 CHEMICAL ENGINEERING BUILDING AT THE PORTSMOUTH GASEOUS DIFFUSION PLANT, PIKETON, OHIO (DOE/PPPO/03-0196&Dl) Reference: Letter from M. Galanti to J. Bradbume, "Construction Completion Report for Phases I and II ofthe Removal of the X-760 Chemical

  20. L I NATIONAL' LEAD COMPANY OF OHIO

    Office of Legacy Management (LM)

    L I NATIONAL' LEAD COMPANY OF OHIO tJw HEALTH AND SAFETY DI"ISION - ANALITICIL DEPT. ANALYTICAL DATA SHEET _I . . NATIONAL LEAD COMPANY O F OHIO HEALTH AND SAFETY DIY1SION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET NATIONA-i LEn' D COMPANY OF OHIO HEALTH AND SAFETY Dl"lSlDN - m4ALITICAL DEPT. ANALYTICAL DATA SHEET NO. I DlSTRlBUTlON OF COPIES I I A,w,lytlc.al Loboratorr (RBCORD COPI) 2 Induswlol Hvalen. B Rodhtlon Dept. 3 1 Water Trsotmmt Plant c=.z w&w hnp,., Only, - . _. NATIONAL

  1. Depositional environment of the Yates Formation in Kermit Field, Winkler County, Texas

    SciTech Connect (OSTI)

    Baker, S.G. (Mobil Exploration and Producing, Denver, CO (USA))

    1990-05-01

    The Yates Formation (Permian Guadalupian) is a series of alternating clastic and carbonate units deposited on a shallow marine shelf in repetitive cycles: (1) a mottled, anhydritic dolomite at the base, (2) an overlying oxidized wind-blown very fine-grained sand and silt, (3) a bioturbated, but otherwise massive, sandstone, and (4) an uppermost massive dolomite containing oolites or skeletal material. A typical cycle is 10-20 ft thick. Deposition of the Yates was controlled by fluctuations in sea level governed by glacial activity and local tectonics. During sea level low stands, carbonates were dolomitized and displaced by anhydrite. This was followed by deposition of wind-blown sediments creating planar horizontal laminae and exposure features (desiccation cracks, tepee structures, and adhesion ripples). During sea level high stands, dunes an the platform were deposited as sheet sands. Lastly, a carbonate layer was deposited before sea level dropped and another cycle began. Sands were transported to the Central Basin platform as eolian dunes from the Pedernal highlands of central New Mexico. Wind direction for the Permian is documented as south-southeast based on mapping of sand dunes in the southwestern US. Quartz size in the clastics ranges from 0.03-0.11 mm, averaging 0.07 mm. The sandstones are homogeneous, well sorted, and most quartz grains are frosted. Except for planar wind laminae, these units contain only indistinct primary sedimentary structures, constrained by small grain size and grain size uniformity within beds. The clastics are 52% monocrystalline quartz, 17% feldspar, 4% rock fragments, 5% other minerals, and 22% matrix (dolomite in the carbonates and authigenic clays in the clastics).

  2. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at

  3. Basic Data Report for Drillhole SNL-9 (C-2950)

    SciTech Connect (OSTI)

    Dennis W. Powers; Washington Regulatory and Environmental Services

    2005-01-19

    SNL-9 (permitted by the State Engineer as C-2950) was drilled to provide geological data and hydrological testing of the Culebra Dolomite Member of the Permian Rustler Formation within a proposed re-entrant of the margin of halite dissolved from the upper part of the Salado near Livingston Ridge. SNL-9 is located in the southeast quarter of section 23, T22S, R30E, in eastern Eddy County, New Mexico. SNL-9 was drilled to a total depth of 845 ft below the ground surface. Below surface dune sand and the Berino soil, SNL-9 encountered, in order, the Mescalero caliche, Gatuna, Dewey Lake, Rustler, and uppermost Salado Formations. Two intervals were cored: 1) from the lower Forty-niner Member through the Magenta Dolomite and into the upper Tamarisk Member; and 2) from the lower Tamarisk Member through the Culebra Dolomite and Los Meda?os Members and into the uppermost Salado Formation. Geophysical logs were acquired from the open hole to total depth, and the drillhole was successfully completed with a screened interval open across the Culebra.

  4. Basic Data Report for Drillhole SNL-5 (C-3002)

    SciTech Connect (OSTI)

    Dennis W. Powers; Washington Regulatory and Environmental Services

    2005-01-18

    SNL-5 (permitted by the New Mexico State Engineer as C-3002) was drilled to provide geological data and hydrological testing of the Culebra Dolomite Member of the Permian Rustler Formation in an area north of the Waste Isolation Pilot Plant (WIPP) site where data are sparse and where a pumping or monitoring well for the northern pumping test is needed. SNL-5 is located in the southeast quarter of section 6, T22S, R31E, in eastern Eddy County, New Mexico. SNL-5 was drilled to a total depth of 687 ft below ground level (bgl), based on driller's measurements. Below the caliche pad, SNL-5 encountered the Mescalero caliche, Gatu?a, Dewey Lake, and Rustler Formations. Two intervals of the Rustler were cored: (1) from the lower Forty-niner Member through the Magenta Dolomite and into the upper Tamarisk Member; and (2) from the lower Tamarisk Member through the Culebra Dolomite and into the upper Los Meda?os Members. Geophysical logs were acquired from the open hole to a depth of ~672 ft. No water was observed to flow into the open drillhole until the Culebra was penetrated. includes horizontal beds and laminae near the base, and the uppermost part shows some inclined bedding. The mudstone unit shows mostly reddish brown claystone and siltstone with some gray mottling. Clasts or intraclasts are also included in the unit. The upper Tamarisk sulfate is somewhat brecciated near the base.

  5. Evaporite Caprock Integrity. An experimental study of reactive mineralogy and pore-scale heterogeneity during brine-CO2 exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Sholokhova, Yelena; Hao, Yue; Carroll, Susan A.

    2012-07-25

    Characterization and geochemical data are presented from a core-flooding experiment on a sample from the Three Fingers evaporite unit forming the lower extent of caprock at the Weyburn-Midale reservoir, Canada. This low-permeability sample was characterized in detail using X-ray computed microtomography before and after exposure to CO 2-acidified brine, allowing mineral phase and voidspace distributions to be quantified in three dimensions. Solution chemistry indicated that CO 2-acidified brine preferentially dissolved dolomite until saturation was attained, while anhydrite remained unreactive. Dolomite dissolution contributed to increases in bulk permeability through the formation of a localized channel, guided by microfractures as well asmore » porosity and reactive phase distributions aligned with depositional bedding. An indirect effect of carbonate mineral reactivity with CO 2-acidified solution is voidspace generation through physical transport of anhydrite freed from the rock matrix following dissolution of dolomite. The development of high permeability fast pathways in this experiment highlights the role of carbonate content and potential fracture orientations in evaporite caprock formations considered for both geologic carbon sequestration and CO 2-enhanced oil recovery operations.« less

  6. Maquoketa Shale Caprock Integrity Evaluation

    SciTech Connect (OSTI)

    Leetaru, Hannes

    2014-09-30

    The Knox Project objective is to evaluate the potential of formations within the Cambrian-Ordovician strata above the Mt. Simon Sandstone (St. Peter Sandstone and Potosi Dolomite) as potential targets for carbon dioxide (CO2) sequestration in the Illinois and Michigan Basins. The suitability of the St. Peter Sandstone and Potosi Dolomite to serve as reservoirs for CO2 sequestration is discussed in separate reports. In this report the data gathered from the Knox project, the Illinois Basin Decatur Project (IBDP) and Illinois Industrial Carbon Capture and Sequestration project (IL-ICCS) are used to make some conclusions about the suitability of the Maquoketa shale as a confining layer for CO2 sequestration. These conclusions are then upscaled to basin-wide inferences based on regional knowledge. Data and interpretations (stratigraphic, petrophysical, fractures, geochemical, risk, seismic) applicable to the Maquoketa Shale from the above mentioned projects was inventoried and summarized. Based on the analysis of these data and interpretations, the Maquoketa Shale is considered to be an effective caprock for a CO2 injection project in either the Potosi Dolomite or St. Peter Sandstone because it has a suitable thickness (~200ft. ~61m), advantageous petrophysical properties (low effective porosity and low permeability), favorable geomechanical properties, an absence of observable fractures and is regionally extensive. Because it is unlikely that CO2 would migrate upward through the Maquoketa Shale, CO2, impact to above lying fresh water aquifers is unlikely. Furthermore, the observations indicate that CO2 injected into the St. Peter Sandstone or Potosi Dolomite may never even migrate up into the Maquoketa Shale at a high enough concentrations or pressure to threaten the integrity of the caprock. Site specific conclusions were reached by unifying the data and conclusions from the IBDP, ICCS and the Knox projects. In the Illinois Basin, as one looks further away from these sites, the formation characteristics are expected to vary. The degree of how well this data can be extrapolated throughout the Basins (regionalized) is difficult to quantify because of the limited amount of data collected on the Maquoketa Shale away from IBDP, IL-ICCS and the Knox projects. Data gathered from the IBDP/IL-ICCS/Knox projects were used to make conclusions about the suitability of the Maquoketa shale as a confining layer for CO2 sequestration. This study indicates that the Maquoketa Shale would be a suitable caprock for a CO2 injection program in either the Potosi Dolomite or St. Peter Sandstone.

  7. Geochemistry and sedimentation of organic matter in the Triassic-Liassic carbonate laminated source rocks of the Ragusa basin (Italy)

    SciTech Connect (OSTI)

    Brosse, E.; Loreau, J.P.; Frixa, A.

    1988-08-01

    The Noto and Streppenosa formations of the Ragusa basin (southeastern Sicily) are considered the main source rocks for oil in this area. They display various styles of sedimentation in a generally carbonate context. The organic matter is basically of marine planktonic origin but with some variations, especially in terms of O/C ratio and kinetic behavior. Three main styles of sedimentation occurred within these formations: (1) laminates in a dominantly carbonate rock with thin recurrent interlayers of black shales; (2) alternating layers of marls and limestones, both containing interlayers of black shales and with occasional laminations in the limestones; and (3) silty shales, more or less rich in carbonates (30-70%). The highest petroleum potentials are neither strictly associated with the algal-sedimentary laminites nor with the basinal silty facies but with the black shales interbedded in the different facies or abruptly overlying limestones. In these black shales, oxygen-poor kerogens are dominant. Limestones of the alternated layers are generally organic lean (TOC < 1%), and oxygen-rich kerogens are dominant. The transition from one type of kerogen to the other occurs in the marly layers of the sequence. A tentative integration of both sedimentological and geochemical results is proposed, at the scale of the core, to interpret the respective influence of the depositional pattern and the diagenetic conditions on the content and nature of the kerogen in the source rocks.

  8. Core-in-shell sorbent for hot coal gas desulfurization

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Akiti, Jr., Tetteh T.

    2004-02-10

    A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired physical characteristics to withstand the conditions of use.

  9. Method for the production of cementitious compositions and aggregate derivatives from said compositions, and cementitious compositions and aggregates produced thereby

    DOE Patents [OSTI]

    Minnick, L. John (Box 271, Plymouth Meeting, PA 19462)

    1983-01-01

    The present invention relates to a method for preparing synthetic shaped cementitious compositions having high quality even without the addition of high energy binders, such as portland cement, through the use of the spent residue from a fluidized combustion bed of the type wherein limestone particles are suspended in a fluidized medium and sulfur oxides are captured, and pulverized coal fly ash.

  10. New methods of nozzle attachment to FRP spray headers

    SciTech Connect (OSTI)

    Boucher, E.J.

    1995-06-01

    The traditional method of attaching spray nozzles to FRP spray headers in the absorber tower of a wet limestone system has been through the use of 150 lb. Flanges. This paper will illustrate two additional methods (grooved adapters & adhesive bonded nozzles) and will demonstrate the cost saving associated versus the flanged option, as well as the advantages and disadvantages of each system.

  11. Petrology of Eocene rocks, southeastern Georgia coastal plain

    SciTech Connect (OSTI)

    Thayer, P.A.; Miller, J.A.

    1988-09-01

    Study of cores from a US Geological Survey test well in Wayne County indicates that Eocene strata represent an overall shallowing-upward, clastic-carbonate sequence. The 1397-ft (426-m) Eocene section is divided into three units: unnamed lower Eocene rocks, middle Eocene (Claibornian) Lisbon and Avon Park Formations, and upper Eocene (Jacksonian) Ocala Limestone.

  12. Polaron Coherence Condensation in Layered Colossal Resistive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    when the temperature is close to the Curie point, TC 120 K, for LSMO and the critical point, Tc 83 K, for BiSCCO2212. BiSCCO2212 data from D.L. Feng et al., Science 289, 277...

  13. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Equation (1) (2) (3) (4) (5) Tank Model Recycling Ratio A IF A OF dp dl qV Ag dp q g HD HA T S n T S - + 1 1 V dPW HA HD MFD MFD dPW MFD P E + - dPW A...

  14. Dynamics of double layers, ion acceleration, and heat flux suppression during solar flares

    SciTech Connect (OSTI)

    Li, T. C.; Drake, J. F.; Swisdak, M.

    2014-09-20

    Observations of flare-heated electrons in the corona typically suggest confinement of electrons. The confinement mechanism, however, remains unclear. The transport of coronal hot electrons into ambient plasma was recently investigated by particle-in-cell (PIC) simulations. Electron transport was significantly suppressed by the formation of a highly localized, nonlinear electrostatic potential in the form of a double layer (DL). In this work large-scale PIC simulations are performed to explore the dynamics of DLs in larger systems where, instead of a single DL, multiple DLs are generated. The primary DL accelerates return current electrons, resulting in high velocity electron beams that interact with ambient ions. This forms a Buneman unstable system that spawns more DLs. Trapping of heated return current electrons between multiple DLs strongly suppresses electron transport. DLs also accelerate ambient ions and produce strong ion flows over an extended region. This clarifies the mechanism by which hot electrons in the corona couple to and accelerate ions to form the solar wind. These new dynamics in larger systems reveal a more likely picture of DL development and their impact on the ambient plasma in the solar corona. They are applicable to the preparation for in situ coronal space missions like the Solar Probe Plus.

  15. Atmospheric measurements of carbonyl sulfide, dimethyl sulfide, and carbon disulfide using the electron capture sulfur detector

    SciTech Connect (OSTI)

    Johnson, J.E.; Bates, T.S. [NOAA, Seattle, WA (United States)

    1993-12-01

    Measurements of atmospheric dimethyl sulfide (DMS), carbonyl sulfide (COS), and carbon disulfide (CS2) were conducted over the Atlantic Ocean on board the NASA Electra aircraft during the Chemical Instrumentation Test and Evaluation (CITE 3) project using the electron capture sulfur detector (ECD-S). The system employed cryogenic preconcentration of air samples, gas chromatographic separation, catalytic fluorination, and electron capture detection. Samples collected for DMS analysis were scrubbed of oxidants with NaOH impregnated glass fiber filters to preconcentration. The detection limits (DL) of the system for COS, DMS, and CS2 were 5, 5, and 2 ppt, respectively. COS concentrations ranged from 404 to 603 ppt with a mean of 489 ppt for measurements over the North Atlantic Ocean (31 deg N to 41 deg N), and from 395 to 437 ppt with a mean of 419 ppt for measurements over the Tropical Atlantic Ocean (11 deg S to 2 deg N). DMS concentrations in the lower marine boundary layer, below 600-m altitude, ranged from below DL to 150 ppt from flights over the North Atlantic, and from 9 to 104 ppt over the Tropical Atlantic. CS2 concentrations ranged from below DL to 29 ppt over the North Atlantic. Almost all CS2 measurements over the Tropical Atlantic were below DL.

  16. BPA-2011-00122-FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ry ,Laura M - DK-7 From: richard t k;CELVED BY B1 01A OFFICE Sent: Friday. October22, 2010 12:04 PM 11 To: FOIA DL E DATE: Subject: FOIA Request t The following is a New FOIA...

  17. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J.D. Savee, D.L. Osborn, S.S. Vasu, C.J. Percival, D.E. Shallcross, and C.A. Taatjes, "Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I...

  18. INDIA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Instruments AERI Atmospheric Emitted Radiance Interferometer Measurement Type: Radiometric View Plots AOS Aerosol Observing System Measurement Type: Aerosol View Plots DL Doppler Lidar Measurement Type: Cloud Properties View Plots GNDRAD Ground Radiometers on Stand for Upwelling Radiation Measurement Type: Radiometric View Plots MET Surface Meteorological Instrumentation Measurement Type: Surface Meteorology View Plots MFRSR Multifilter Rotating Shadowband Radiometer Measurement Type:

  19. Technical Basis Agreement Document for UGTA CAU 99 RM/SM

    National Nuclear Security Administration (NNSA)

    D.L. Finnegan, J.L. Thompson, C.M. Miller, P.L. Baca, L.F. Olivas, C.G. Geoffrion, D.K. Smith, W. Goishi, B.K. Esser, J.W. Meadows, N. Namboodiri, J.F. Wild. 2001. Nevada Test Site...

  20. 2004 ORAU/ORISE Bibliography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program At Rocky Flats. 2004. Aldrich, J.M., N.M. Daugherty, D.L. Cragle, E.D. Ellis, R.B. Falk, J. Follmer, F.J. Furman, D.J. Girardi, D. Hilmas, J.P. Watkins, and S.M....

  1. Radioactive Lysine in Protein Metabolism Studies

    DOE R&D Accomplishments [OSTI]

    Miller, L. L.; Bale, W. F.; Yuile, C. L.; Masters, R. E.; Tishkoff, G. H.; Whipple,, G. H.

    1950-01-09

    Studies of incorporation of DL-lysine in various body proteins of the dog; the time course of labeled blood proteins; and apparent rate of disappearance of labeled plasma proteins for comparison of behavior of the plasma albumin and globulin fractions; shows more rapid turn over of globulin fraction.

  2. IAEA-F1-CN69.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NUMBER SCALING, PLASMA FLOW, AND REDUCED TRANSPORT G. Fiksel, 1 A.F. Almagri, 1 J.K. Anderson, 1 T.M. Biewer, 1 D.L. Brower, 2 C-S. Chiang, 1 B.E. Chapman, 1 J.T. Chapman, 1 D.J....

  3. I'

    Office of Legacy Management (LM)

    OF t.W IlB ?BTAL 'IC F'MNKFORD ARS3UL SfiEQL: PTS:DlX:mam (m-31) Please ship from iQA inventory,-& the earliest possible date, approximately 125 feet of 1316 inch uranium rod...

  4. Reduced repair capacity of a DNA clustered damage site comprised of 8-oxo-7,8-dihydro-2'-deoxyguanosine and 2-deoxyribonolactone results in an increased mutagenic potential of these lesions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cunniffe, Siobhan; O’Neill, Peter; Greenberg, Marc M.; Lomax, Martine E.

    2014-04-01

    A signature of ionizing radiation is the induction of DNA clustered damaged sites. Non-double strand break (DSB) clustered damage has been shown to compromise the base excision repair pathway, extending the lifetimes of the lesions within the cluster, compared to isolated lesions. This increases the likelihood the lesions persist to replication and thus increasing the mutagenic potential of the lesions within the cluster. Lesions formed by ionizing radiation include 8-oxo-7,8-dihydro-2'-deoxyguanosine (8-oxodGuo) and 2-deoxyribonolactone (dL). dL poses an additional challenge to the cell as it is not repaired by the short-patch base excision repair pathway. Here we show recalcitrant dL repairmore » is reflected in mutations observed when DNA containing it and a proximal 8-oxodGuo is replicated in Escherichia coli. 8-oxodGuo in close proximity to dL on the opposing DNA strand results in an enhanced frequency of mutation of the lesions within the cluster and a 20 base sequence flanking the clustered damage site in an E. coli based plasmid assay. In vitro repair of a dL lesion is reduced when compared to the repair of an abasic (AP) site and a tetrahydrofuran (THF), and this is due mainly to a reduction in the activity of polymerase β, leading to retarded FEN1 and ligase 1 activities. This study has given insights in to the biological effects of clusters containing dL.« less

  5. Effects of heavy metals on biomarkers for oxidative stress in Griffon vulture (Gyps fulvus)

    SciTech Connect (OSTI)

    Espn, Silvia; Martnez-Lpez, Emma; Jimnez, Pedro; Mara-Mojica, Pedro; Garca-Fernndez, Antonio J.

    2014-02-01

    Metals are involved in the formation of reactive oxygen species (ROS) which may result in metal-related oxidative stress that can lead to oxidative damage to lipids, DNA and proteins. It is necessary to understand the mechanisms of metal toxicity in wild birds, and the concentrations that cause effects on oxidative stress biomarkers. The aim of this study is to assess the concentrations of lead (Pb), cadmium (Cd), mercury (Hg), copper (Cu) and zinc (Zn) with regards to oxidative stress in blood samples of 66 Griffon vultures (Gyps fulvus) from two areas of the Autonomous Community of Valencia (East of Spain). The two study areas (Alcoy n=36 and Cinctorres n=30) were selected as random locations of interest that had not yet been studied, and are feeding stations where supplementary food, mainly of pork origin, is provided for vultures. Given that the two study areas are not considered polluted sites, we expected to find low metal concentrations. However, there are no known threshold concentrations at which metals can affect antioxidant systems, and low metal levels may have an effect on antioxidant biomolecules. In this study, since sampling was done at the beginning of the hunting season, the low Pb levels found in most Griffon vultures from Alcoy and Cinctorres (median=12.37 and 16.26 ?g/dl, respectively) are suggestive of background levels usually found in vultures that feed on pork carcasses all year round. The ingestion of game meat with bullet fragments in carcasses or with Pb shots embedded in the flesh could be the cause of the high blood Pb concentrations found in three vultures from Cinctorres (83, 290 and 362 ?g/dl). Griffon vultures feeding in Cinctorres had enhanced CAT and GST activities and tGSH concentrations, which may be interpreted as protective response against the higher TBARS levels. This study provides threshold concentrations at which metals affect antioxidant system derived from 66 samples of Griffon vulture. Blood Cd concentrations greater than 0.05 ?g/dl produced an induction of 33% in GPx and of 44% in CAT activity in erythrocytes of vultures from Alcoy. Hg concentrations in blood higher than 3 ?g/dl produced an induction of 10% in SOD activity. Concentrations of Pb above 15 g/dl in blood produced an inhibition of 12.5% in GPx and 11.3% in CAT activity, and a TBARS induction of 10.7% in erythrocytes of Griffon vultures. - Highlights: Except for 3 Griffon vultures, lead levels could be considered background levels. Three vultures may be exposed to meat with bullet fragments (blood Pb=83362 ?g/dl). Blood Cd levels?0.05 ?g/dl caused an induction of GPx and CAT activity (33% and 44%). Blood Hg levels?3 ?g/dl caused an induction of 10% in SOD activity. Blood Pb?15 g/dl caused an inhibition of GPx and CAT activity and a TBARS induction.

  6. Application of a selective phase extraction procedure to samples from the Adamello contact aureole (Italy)

    SciTech Connect (OSTI)

    Payne, T.E.; Lumpkin, G.R.; McGlinn, P.J.; Hart, K.P.

    1995-12-31

    Hydrothermal veins, rich in Ti, Zr, rare earth elements (REEs), and actinides, occur in the pure dolomitic marbles of the Adamello contact metamorphic aureole. A selective phase extraction using 9M HCl was applied to samples from within and near these veins to chemically separate acid-soluble phases from residual phases, and to study the associations of U, Th, and REEs with these phases. The samples were from the phlogopite, titanian clinohumite, and forsterite vein zones, and from the country rock. The effects of the extraction were studied by SEM/EDS and by chemical analysis. Isotopes of U and Th were analyzed by alpha-spectrometry. The chemical data and SEM/EDS results indicated that dolomite, calcite, apatite, and much of the pyrrhotite were dissolved by the 9M HCl, whereas spinel, phlogopite, titanite, chalcopyrite, and zirconolite were among the acid-resistant phases. In all vein samples, the REE-patterns of acid-soluble phases were consistent with the dissolution of REE-rich apatite. In samples from the phlogopite zone, the majority of U, Th, and REEs were in residual phases, and the REE pattern of the residue was similar to that of REE-rich titanite. In the titanian clinohumite zone, a substantial proportion of these elements were in acid-soluble phases, and the REE pattern of the residual phases resembled that of zirconolite. Clinohumite was partially dissolved by the HCl treatment. The sample from the forsterite zone contained substantial amounts of REEs in acid-soluble phases, whereas Th and U were mostly in residual phases. The dolomite (country rock) samples contained small amounts of an acid-resistant, uranium-rich phase which, while only comprising about 0.2% of the mass, accounted for 40--60% of the uranium present.

  7. Coal pyrolysis by hot solids from a fluidized-bed combustor. Final technical report, June 1977-June 1982

    SciTech Connect (OSTI)

    Longwell, J.P.; Evans, L.B.; Howard, J.B.; Peters, W.A.; Floess, J.K.; Fong, L.; Chen, C.; Yeboah, J.

    1982-06-01

    The effect of adding calcined dolomite stone to the fluidized-bed pyrolysis of coal and oil shale on product quality and product distribution has been studied. This work has provided information relevant to systems where heat is generated by fluidized-bed combustion in the presence of a sulfur acceptor (dolomite) and where the hot stone from the combustor is used in a second reactor to provide heat for pyrolysis. A scoping economic analysis indicated that, for coal, the pyrolysis gas and liquids produced are lower cost than gas and liquids produced by single-product gasification and liquefaction processes. The presence of calcium oxide during pyrolysis was found to improve gas heating value by CO/sub 2/ removal and to essentially eliminate H/sub 2/S. Gas yield was increased at the expense of liquid yield (20 to 30% reduction). Tar properties were improved by reduction of oxygen content, however, little sulfur or nitrogen removal was observed. Used stone from a fluidized-bed combustor gave results comparable to fresh stone with little reduction of the calcium sulfate present in the used stone. Since Colorado oil shale contains dolomite and calcite, stones from spent-shale combustion might be expected to have similar effects on product yields. CO/sub 2/ and H/sub 2/S removal from the gas were observed. Fortunately, liquid yields were not reduced within the 5% experimental error of this work. It is indicated that CaO tends to remove phenols and polycyclic aromatics which are present in much lower concentration in shale oil than in coal tar.

  8. Basic Data Report for Drillhole SNL-2 (C-2948)

    SciTech Connect (OSTI)

    Dennis W. Powers; Washington Regultory and Environmental Services

    2005-01-19

    SNL-2 was drilled in the northwest quarter of Section 12, T22S, R30E, in eastern Eddy County, New Mexico (Figure 2-1). It is located 574 ft from the north line (fnl) and 859 ft from the west line (fwl) of the section (Figure 2-2). This location places the drillhole east of the Livingston Ridge escarpment among oil wells of the Cabin Lake field. SNL-2 will be used to test hydraulic properties and to monitor ground water levels of the Culebra Dolomite Member of the Permian Rustler Formation. SNL-2 was permitted by the New Mexico State Engineer as C-2948. [Official correspondence regarding permitting and regulatory information must reference this permit number.] In the plan describing the integrated groundwater hydrology program (Sandia National Laboratories, 2003), SNL-2 is also codesignated WTS-1 because the location also satisfies needs for long-term monitoring of water quality and movement in the Culebra Dolomite for RCRA permitting; this program is under the management of Washington TRU Solutions LLC (WTS). In the event that additional wells are established on the SNL-2 drillpad to monitor other hydrological units (e.g., the Magenta Dolomite Member of the Permian Rustler Formation), the current drillhole will likely be referred to as SNL-2C because it is completed in the Culebra. Most drillholes at WIPP have been described after completion to provide an account of the geology, hydrology, or other basic data acquired during drilling and immediate completion of the drillhole. In addition, the basic data report provides an account of the drilling procedures and activities that may be helpful to later interpretations of data or for further work in the drillhole, including test activities and eventual plugging and abandoning activities. The basic data report also provides a convenient means of reporting information about administrative activities necessary to drill the hole.

  9. Habitat of oil in the Lindsborg field, Salina basin, north-central Kansas

    SciTech Connect (OSTI)

    Newell, K.D. )

    1991-03-01

    The Lindsborg field was discovered in 1938, and is now 14 mi in length and 1-2 mi in width. It has a projected ultimate recovery of 16 MMBO. Three pay zones (5-20 ft thick) produce in the field. The Simpson pay zone (Middle Ordovician) is a well-rounded, quartzitic sandstone that is interpreted to be a paralic, high-energy shelf deposit. The Viola pay (Middle Ordovician) appears to be a dolomitic, lime grainstone but no cores are available to confirm this. The uppermost pay zone, the Upper Ordovician Maquoketa, is a finely laminated, vuggy, cherry dolomite interpreted to have been deposited as a subtidal lime mudstone in a restricted lagoon. The Simpson and Viola pays are structurally trapped in culminations along the crest of the Lindsborg anticline. Although the Maquoketa pay is structurally trapped with the other pay zones in the southern half of the field, its locus of production in the north half of the fields extends 100 ft vertically down the western flank of the anticline. The trapping mechanism is unclear due to lack of core control and modern logging suites, but it may be subtle updip diagenetic change from vuggy to nonvuggy dolomite. The Simpson and Maquoketa oils are geochemically distinct. Both may reflect efficient local source-to-reservoir migration from originally rich but marginally mature Ordovician and Devonian shales that contact each pay zone. If oil in the Lindsborg field is locally generated, the prospectivity of the relatively unproductive and underexplored Salina basin may be enhanced.

  10. Hydrological conditions at the 317/319 Area at Argonne National Laboratory

    SciTech Connect (OSTI)

    Patton, T.L.; Pearl, R.H.; Tsai, S.Y.

    1990-08-01

    This study examined the hydrological conditions of the glacial till underlying the 317/319 Area at Argonne National Laboratory (ANL) near Lemont, Illinois. The study's purpose was to review and summarize hydrological data collected by ANL's Environment, Safety, and Health Department and to characterize, based on these data, the groundwater movement and migration of potential contaminants in the area. Recommendations for further study have been made based on the findings of this review. The 317/319 Area is located between Meridian Road and the southern border of ANL. The 317 Area was commissioned in the late 1940s for the temporary storage of radioactive waste. Low- and high-level solid radioactive waste is stored in partially buried concrete vaults. Low-level radioactive waste awaiting shipment for off-site disposal is stored in aboveground steel bins north of the vaults. The 319 Area is an inactive landfill, located east of the 317 Area that was used for the disposal of general refuse, demolition debris, and laboratory equipment. Fluorescent light bulbs, chemical containers, and suspect waste were also placed in the landfill. Liquid chemical wastes were disposed of at each site in gravel-filled trenches called French drains.'' The 317/319 Area is underlain by a silty clay glacial till. Dolomite bedrock underlies the till at an average depth of about 19.5m. Organic contaminants and radionuclides have been detected in groundwater samples from wells completed in the till. Fractures in the clay as well as sand and gravel lenses present in the till could permit these contaminants to migrate downward to the dolomite aquifer. At the time of this report, no chemical quality analyses had been made on groundwater samples from the dolomite. The study found that existing information about subsurface characteristics at the site is inadequate to identify potential pathways for contaminant migration. 14 refs., 13 figs., 6 tabs.

  11. Hydrological conditions at the 800 Area at Argonne National Laboratory

    SciTech Connect (OSTI)

    Patton, T.L.; Pearl, R.H.; Tsai, S.Y.

    1990-08-01

    This study examined the hydrological conditions of the glacial till underlying the 800 Area sanitary landfill at Argonne National Laboratory (ANL) near Lemont, Illinois. The study's purpose was to review and summarize hydrological data collected by ANL's Environment, Safety, and Health Department and to characterize, on the basis of these data, the groundwater movement and migration of potential contaminants in the area. Recommendations for further study have been made based on the findings of this review. The 800 Area landfill is located on the western edge of ANL, just south of Westgate Road. It has been in operation since 1966 and has been used for the disposal of sanitary, general refuse. From 1969 through 1978, however, substantial quantities of liquid organic and inorganic wastes were disposed of in a French drain'' at the northeast corner of the landfill. The 800 Area landfill is underlain by a silty clay glacial till. Dolomite bedrock underlies the till at an average depth of about 45.6 m. Trace levels of organic contaminants and radionuclides have been detected in groundwater samples from wells completed in the till. Fractures in the clay as well as sand and gravel lenses present in the till could permit these contaminants to migrate downward to the dolomite aquifer. When this report was prepared, no chemical quality analysis have been made on groundwater samples from the dolomite. The study found that existing information about subsurface characteristics at the site is inadequate to identify potential pathways for contaminant migration. Recommended actions include installation of five new well clusters and one background well, thorough record-keeping, sample collection and analysis during borehole drilling, slug testing to measure hydraulic conductivity, topographic mapping, continued monitoring of groundwater levels and quality, and monitoring of the unsaturated zone. 17 refs., 13 figs., 4 tabs.

  12. Geological and reservoir characterization of shallow-shelf carbonate fields, Southern Paradox Basin, Utah

    SciTech Connect (OSTI)

    Chidsey, T.C. Jr.; Eby, D.E.

    1996-12-31

    The Paradox basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from carbonate mounds within the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to three wells with primary per field production ranging from 700 MBO to 2 MMBO at a 15-20% recovery rate. Five fields (Anasazi, Mule, Blue Hogan, Heron North, and Runway) within the Navajo Nation of southeastern Utah have been evaluated for CO{sub 2}-flood projects based upon geological characterization and reservoir modeling. Conventional cores from the five fields show that three compositional reservoir types are present: (1) phylloid algal, (2) bioclastic calcarenite, and (3) bryozoan-dominated. Phylloid algal mounds are abundant in four of the five fields, and exhibit the best overall porosity and permeability. This mound type developed where shallow water depths and low energy allowed establishment of calcareous algal colonies possibly on paleohighs. The principal reservoir rock is algal bafflestone composed mostly of the phylloid Ivanovia and occasionally dolomitized. The Heron North field is a bioclastic calcarenite reservoir. It represents high-energy conditions resulting in carbonate beaches developed over foreshore carbonate rubble. The principal reservoir rocks are grainstones and rudstones having grain-selective dissolution and complete dolomitization. Bryozoan-dominated mounds present in Runway field developed in quiet, below wave-base settings that appear to be localized along Mississippian fault blocks trends. The principal reservoir rocks are bindstone and framestone with no dolomitization. The resulting model suggests that CO{sub 2} miscible flooding of these and other small carbonate reservoirs in the Paradox basin could significantly increase ultimate recovery of oil.

  13. Geological and reservoir characterization of shallow-shelf carbonate fields, Southern Paradox Basin, Utah

    SciTech Connect (OSTI)

    Chidsey, T.C. Jr. ); Eby, D.E. )

    1996-01-01

    The Paradox basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from carbonate mounds within the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to three wells with primary per field production ranging from 700 MBO to 2 MMBO at a 15-20% recovery rate. Five fields (Anasazi, Mule, Blue Hogan, Heron North, and Runway) within the Navajo Nation of southeastern Utah have been evaluated for CO[sub 2]-flood projects based upon geological characterization and reservoir modeling. Conventional cores from the five fields show that three compositional reservoir types are present: (1) phylloid algal, (2) bioclastic calcarenite, and (3) bryozoan-dominated. Phylloid algal mounds are abundant in four of the five fields, and exhibit the best overall porosity and permeability. This mound type developed where shallow water depths and low energy allowed establishment of calcareous algal colonies possibly on paleohighs. The principal reservoir rock is algal bafflestone composed mostly of the phylloid Ivanovia and occasionally dolomitized. The Heron North field is a bioclastic calcarenite reservoir. It represents high-energy conditions resulting in carbonate beaches developed over foreshore carbonate rubble. The principal reservoir rocks are grainstones and rudstones having grain-selective dissolution and complete dolomitization. Bryozoan-dominated mounds present in Runway field developed in quiet, below wave-base settings that appear to be localized along Mississippian fault blocks trends. The principal reservoir rocks are bindstone and framestone with no dolomitization. The resulting model suggests that CO[sub 2] miscible flooding of these and other small carbonate reservoirs in the Paradox basin could significantly increase ultimate recovery of oil.

  14. Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

    SciTech Connect (OSTI)

    Li, Q.S.; Chen, J.J.; Li, Y.C.

    2008-02-15

    Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months of plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.

  15. Chemical composition of interstitial waters from the Japan Sea, ODP Leg 128

    SciTech Connect (OSTI)

    Sturz, A. ); Von Breymann, M.; Dunbar, R. )

    1990-06-01

    During ODP Leg 128, interstitial waters were recovered from Oki Ridge (Site 798) and Kita-Yamato Trough (Site 799) sediment, Sea of Japan. Interstitial water chemical composition reflects diagenetic processes. Evidence indicating organic matter degradation processes includes sulfate depletion, high ammonium concentrations, and shallow maxima of dissolved phosphate. Rapid alkalinity increases in the uppermost sections of the sediments are accompanied by decreases in dissolved calcium, reflecting inorganic calcite precipitation. Authigenic dolomitization results in changes in slopes of the Mg/Ca molar ratios with depth. The opal-A/opal-CT transition is documented by the concentration depth profiles of dissolved silica and lithium. Dolomitization precedes the opal-A/opal-CT transition at both sites. Kita-Yamato Trough sediments show an abrupt change in the compositional character of the pore fluids below 435 mbsf, which coincides with the occurrence of low porosity and high bulk density layers composed of dolomite and opal-CT. These layers impede to some extent diffusional communication with the overlying interstitial waters. The interstitial waters in sediments below 435 mbsf have chloride concentrations of 504-515 mM, significantly lower than that of modern day Japan Sea water (540 mM). The presence of low chloride waters within Miocene age sediments may indicate: (1) diagenetic reactions that involve the release of exchangeable and structural bound water from clay minerals and/or opal-A, (2) Miocene connate brackish lake water, (3) phase separation of hydrothermal fluids associated with rifting, (4) potential effects of clay membrane filtration in a high pressure zone.

  16. HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND

    Office of Scientific and Technical Information (OSTI)

    HIGH-PRESSURE AIR INJECTION: APPLICATION IN A FRACTURED AND KARSTED DOLOMITE RESERVOIR Semi-Annual Report Reporting Period Start Date: May 1, 2003 Reporting Period End Date: November 1, 2003 Principal Authors: Robert Loucks (Co-PI), Steve Ruppel (Co-PI), Julia Gale, Jon Holder, Jon Olsen, Deanna Combs, Dhiraj Dembla, and Leonel Gomez Date Report Issued: December 10, 2003 DOE Award Number: DE-FC26-02NT15442 Bureau of Economic Geology The John A. and Katherine G. Jackson School of Geosciences The

  17. Organic binders for iron ore pelletization and steelmaking

    SciTech Connect (OSTI)

    Karkoska, D.; Sankey, E.; Anderson, R.

    1995-12-01

    Historically, bentonite has been used in the agglomeration process in North American iron ore plants. In 1986, Eveleth Mines replaced bentonite with Peridur, a carboxy methyl cellulose organic binder used in conjunction with 1% limestone. Since May of 1993, Allied Colloids` Alcotac FE8 has been used by Eveleth as the replacement for bentonite. This paper discusses the performance benefits obtained when bentonite was replaced with an organic binder. These totally synthetic binders are used in conjunction with limestone. The benefits of organic binders are: improved metallurgical parameters of the fired pellet, especially the reducibility, which results in more efficient use of gases in the blast furnace; reduced silica in the pellet, in the case of Eveleth Mines this was a reduction of 0.5%, a lower silica pellet reduces slag in the blast furnace; increased production in both the agglomeration/induration and steelmaking processes; and a decrease in coke consumption.

  18. MODELING UNDERGROUND STRUCTURE VULNERABILITY IN JOINTED ROCK

    SciTech Connect (OSTI)

    R. SWIFT; D. STEEDMAN

    2001-02-01

    The vulnerability of underground structures and openings in deep jointed rock to ground shock attack is of chief concern to military planning and security. Damage and/or loss of stability to a structure in jointed rock, often manifested as brittle failure and accompanied with block movement, can depend significantly on jointed properties, such as spacing, orientation, strength, and block character. We apply a hybrid Discrete Element Method combined with the Smooth Particle Hydrodynamics approach to simulate the MIGHTY NORTH event, a definitive high-explosive test performed on an aluminum lined cylindrical opening in jointed Salem limestone. Representing limestone with discrete elements having elastic-equivalence and explicit brittle tensile behavior and the liner as an elastic-plastic continuum provides good agreement with the experiment and damage obtained with finite-element simulations. Extending the approach to parameter variations shows damage is substantially altered by differences in joint geometry and liner properties.

  19. Soil stabilization using oil shale solid wastes: Laboratory evaluation of engineering properties

    SciTech Connect (OSTI)

    Turner, J.P.

    1991-01-01

    Oil shale solid wastes were evaluated for possible use as soil stabilizers. A laboratory study was conducted and consisted of the following tests on compacted samples of soil treated with water and spent oil shale: unconfined compressive strength, moisture-density relationships, wet-dry and freeze-thaw durability, and resilient modulus. Significant increases in strength, durability, and resilient modulus were obtained by treating a silty sand with combusted western oil shale. Moderate increases in strength, durability, and resilient modulus were obtained by treating a highly plastic clay with combusted western oil shale. Solid waste from eastern shale can be used for soil stabilization if limestone is added during combustion. Without limestone, eastern oil shale waste exhibits little or no cementation. The testing methods, results, and recommendations for mix design of spent shale-stabilized pavement subgrades are presented. 11 refs., 3 figs., 10 tabs.

  20. Metallic species derived from fluidized bed coal combustion. [59 references

    SciTech Connect (OSTI)

    Natusch, D.F.S.; Taylor, D.R.

    1980-01-01

    Samples of fly ash generated by the combustion of Montana Rosebud coal in an experimental 18 inch fluidized bed combustor were collected. The use of a heated cascade impactor permitted collection of size fractionated material that avoided condensation of volatile gases on the particles. Elemental concentration trends were determined as a function of size and temperature and the results compared to published reports for conventional power plants. The behavior of trace metals appears to be substantially different in the two systems due to lower operating temperatures and the addition of limestone to the fluidized bed. Corrosion of the impactor plates was observed at the highest temperature and lowest limestone feed rate sampled during the study. Data from the elemental concentration and leaching studies suggest that corrosion is most likely due to reactions involving sodium sulfate. However, it is concluded that corrosion is less of a potential problem in fluidized-bed systems than in conventional coal-fired systems.

  1. A double-layer based model of ion confinement in electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Mascali, D. Neri, L.; Celona, L.; Castro, G.; Gammino, S.; Ciavola, G.; Torrisi, G.; Universit Mediterranea di Reggio Calabria, Dipartimento di Ingegneria dellInformazione, delle Infrastrutture e dellEnergia Sostenibile, Via Graziella, I-89100 Reggio Calabria ; Sorbello, G.; Universit degli Studi di Catania, Dipartimento di Ingegneria Elettrica Elettronica ed Informatica, Viale Andrea Doria 6, 95125 Catania

    2014-02-15

    The paper proposes a new model of ion confinement in ECRIS, which can be easily generalized to any magnetic configuration characterized by closed magnetic surfaces. Traditionally, ion confinement in B-min configurations is ascribed to a negative potential dip due to superhot electrons, adiabatically confined by the magneto-static field. However, kinetic simulations including RF heating affected by cavity modes structures indicate that high energy electrons populate just a thin slab overlapping the ECR layer, while their density drops down of more than one order of magnitude outside. Ions, instead, diffuse across the electron layer due to their high collisionality. This is the proper physical condition to establish a double-layer (DL) configuration which self-consistently originates a potential barrier; this barrier confines the ions inside the plasma core surrounded by the ECR surface. The paper will describe a simplified ion confinement model based on plasma density non-homogeneity and DL formation.

  2. DESCRIPTION BARCODE MANUFACTURER MODEL_NO COST SN BLDG ROOM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DESCRIPTION BARCODE MANUFACTURER MODEL_NO COST SN BLDG ROOM CAMCORDER PANASONIC 0000001582 PANASONIC AG-HVX200A $11,002.00 H8TCB00051 922 177 SERVER HP DL380 G7 E 0000002402 HEWLETT PACKARD DL380 $11,318.96 SGH130X5SH 922 116 STEADICAM F24LEHDVLN 0000001560 STEADICAM F24LEHDVLNNS $11,500.00 N/A 922 177 CAMERA EVOLUTION 410 0000000017 EVOLUTION 4100 $11,844.77 JRR24TA-10C 922 177 PRINTER/PLOTTER HP D C4153 HEWLETT PACKARD C6096V $16,088.00 SG18S1401H 922 1W13 APPLIANCE PART #: GS 0000002039

  3. Dynamical consequences of a constraint on the Langevin thermostat in molecular cluster simulation

    SciTech Connect (OSTI)

    Stinson, Jake L.; Kathmann, Shawn M.; Ford, Ian J.

    2014-11-17

    We investigate some unusual behaviour observed while performing molecular dynamics simulations with the DL_POLY_4.03 code. Under the standard Langevin thermostat, atoms appear to be thermalised to different temperatures, depending on their mass and on the total number of particles in the system. We find that an imposed constraint whereby no thermal noise acts on the centre of mass of the system is the cause of the unexpected behaviour. This is demonstrated by solving the stochastic dynamics for the constrained thermostat and comparing the results with simulation data. The effect of the constraint can be considerable for small systems with disparate masses. By removing the constraint the Langevin thermostat may be restored to its intended behaviour and this has been implemented as an option in DL_POLY_4.05. SMK was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  4. Proceedings of the international symposium on engineering in complex rock formations

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This book contains over 100 papers. Some of the titles are: Rheology of rock-salt and its application for radioactive waste disposal purposes; A scale model study on the deformation around the drift in Korean inclined coal seam; Stabilization of a landslide in fractured marls and limestone; Dead Sea underground hydroelectric power station; and Rock mechanics in design of underground power house of lubuge hydropower project.

  5. TRANS4: a computer code calculation of solid fuel penetration of a concrete barrier. [LMFBR; GCFR

    SciTech Connect (OSTI)

    Ono, C. M.; Kumar, R.; Fink, J. K.

    1980-07-01

    The computer code, TRANS4, models the melting and penetration of a solid barrier by a solid disc of fuel following a core disruptive accident. This computer code has been used to model fuel debris penetration of basalt, limestone concrete, basaltic concrete, and magnetite concrete. Sensitivity studies were performed to assess the importance of various properties on the rate of penetration. Comparisons were made with results from the GROWS II code.

  6. News Item

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research may Predict How Carbon is Stored Underground Computer simulations conducted at the Molecular Foundry could help scientists make sense of a recently observed and puzzling wrinkle in one of nature's most important chemical processes. It turns out that calcium carbonate-the ubiquitous compound that is a major component of seashells, limestone, concrete, antacids and myriad other naturally and industrially produced substances-may momentarily exist in liquid form as it crystallizes from

  7. Gasification Systems Project Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project Information Gasifier Optimization Archived Projects Agreement Number Project Title Performer Name Technology Area FE0023497 Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation Alstom Power, Inc Gasification Systems FE0023577 Advanced Gasifier and Water Gas Shift Technologies for Low Cost Coal Conversion to High Hydrogen Syngas Gas Technology Institute Coal & Coal-Biomass to Liquids, Gasification Systems FE0023915 Pilot Scale Operation and

  8. Method of feeding particulate material to a fluidized bed

    DOE Patents [OSTI]

    Borio, Richard W. (Somers, CT); Goodstine, Stephen L. (Windsor, CT)

    1984-01-01

    A centrifugal spreader type feeder that supplies a mixture of particulate limestone and coal to the top of a fluidized bed reactor having a flow of air upward therethrough. Large particles of particulate matter are distributed over the upper surface of the bed to utilize the natural mixing within the bed, while fine particles are adapted to utilize an independent feeder that separates them from the large particles and injects them into the bed.

  9. Fate and Transport of Uranium (VI) in Weathered Saprolite (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Journal Article: Fate and Transport of Uranium (VI) in Weathered Saprolite Citation Details In-Document Search Title: Fate and Transport of Uranium (VI) in Weathered Saprolite Batch and column experiments were conducted to investigate sorption and transport of uranium (U) in the presence of saprolite derived from interbedded shale, limestone, and sandstone sequences. Sorption kinetics were measured at two initial concentrations (C0; 1, 10 mM) and three soil:solution ratios

  10. Page

    Gasoline and Diesel Fuel Update (EIA)

    Page 1 Updated: March 2013 APPENDIX B U.S. PORT CODES District Port Code Code Name 01 PORTLAND, MAINE 01 Portland 02 Bangor (including Brewer) 03 Eastport (including Cutler, Lubec) 04 Jackman 05 Vanceboro 06 Houlton 07 Fort Fairfield 08 Van Buren 09 Madawaska 10 Fort Kent 11 Bath 12 Bar Harbor 15 Calais (including Robbinston) 18 Limestone 21 Rockland 22 Jonesport 27 Bridgewater 31 Portsmouth, NH 32 Belfast (including Bucksport, Sandy Point, Winterport) 52 Searsport 02 ST. ALBANS, VERMONT 01 St.

  11. DE-SC0004118 (Wong & Lindquist). Final Report: Changes of Porosity, Permeability and Mechanical Strength Induced by Carbon Dioxide Sequestration.

    SciTech Connect (OSTI)

    WONG, TENG-FONG; Lindquist, Brent

    2014-09-22

    In the context of CO{sub 2} sequestration, the overall objective of this project is to conduct a systematic investigation of how the flow of the acidic, CO{sub 2} saturated, single phase component of the injected/sequestered fluid changes the microstructure, permeability and strength of sedimentary rocks, specifically limestone and sandstone samples. Hydromechanical experiments, microstructural observations and theoretical modeling on multiple scales were conducted.

  12. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

    2009-01-20

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  13. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, Shou-Heng (Kaohsiung, TW); Liu, Zhao-Rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

    2011-08-30

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  14. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Bejing, CN); Yan, Naiqiang (Burkeley, CA)

    2010-07-13

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  15. Method for producing H.sub.2 using a rotating drum reactor with a pulse jet heat source

    DOE Patents [OSTI]

    Paulson, Leland E. (Morgantown, WV)

    1990-01-01

    A method of producing hydrogen by an endothermic steam-carbon reaction using a rotating drum reactor and a pulse jet combustor. The pulse jet combustor uses coal dust as a fuel to provide reaction temperatures of 1300.degree. to 1400.degree. F. Low-rank coal, water, limestone and catalyst are fed into the drum reactor where they are heated, tumbled and reacted. Part of the reaction product from the rotating drum reactor is hydrogen which can be utilized in suitable devices.

  16. U.S. Environmental Protection Agency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Protection Agency U.S. Environmental Protection Agency The City Hall in Austin, Texas was designed to reflect its natural surroundings. The four-story building incorporates local limestone, a waterfall and nonsymmetrical shapes, meant to reflect the waterways and canyons of the area. The building also includes amphitheater seating shaded by solar photovoltaic panels. An EPA Green Power Partner since September 2006, the City of Austin uses more than 370 million kilowatt-hours of

  17. Microsoft Word - Final_Range74_EA.doc

    National Nuclear Security Administration (NNSA)

    FINAL RANGE 74 TARGET COMPLEXES ENVIRONMENTAL ASSESSMENT NEVADA TEST AND TRAINING RANGE, NEVADA July 2007 FINDING OF NO SIGNIFICANT IMPACT (FONSI) 1. Name of Action. RANGE 74 TARGET COMPLEXES, NEVADA TEST AND TRAINING RANGE, NEVADA 2. Description of Proposed Action and Alternatives The U.S. Air Force (Air Force) proposes to construct and operate three target complexes in mountainous terrain in Range 74 of the Nevada Test and Training Range (NTTR) at Saucer Mesa, Limestone Ridge, and Cliff

  18. STFC PowerPoint template

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Tevatron on Technology and Innovation John Womersley Chief Executive, STFC 11 June 2012 John Womersley CERN: LHC ESO: Alma Array ESA: Top Sat ILL and ESRF JCMT Telescope Research in UK universities, RAL and DL The Science & Technology Facilities Council John Womersley Why do governments support science? Science Understanding of the Universe Technological innovation, skills $ Government Impacts * Can we try to measure the payoff from the investment made in the Tevatron? - At least in the

  19. Draft - DOE G 410.2-1, Nuclear Material Disposition

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    This document provides a roadmap for implementing the requirements for disposition of nuclear material as outlined in the U.S. Department of Energy (DOE) Order 410.2, Management of Nuclear Materials, and DOE Order 474.2, Nuclear Material Control and Accountability. This Guide provides the basic framework for the nuclear material disposition process, includes information related to the Programmatic Value Determination (PVD) process, and identifies Discard Limits (DL) for specific low-equity nuclear materials.

  20. Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sensors and Sensing Technologies Sensors and Sensing Technologies Publications Journal articles on Sensors and Sensing Technologies Contact Institute Director Charles Farrar (505) 663-5330 Email UCSD EI Director Michael Todd (858) 534-5951 Professional Staff Assistant Ellie Vigil (505) 667-2818 Email Administrative Assistant Rebecca Duran (505) 665-8899 Email Journal Articles Stull, C.J., Taylor, S. G., Wren, J., Mascarenas, D.L., Farrar, C. R., "Real-Time Condition Assessment of the Raptor

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Small Ice Crystals on Ice Sedimentation Rates in Cirrus Clouds and GCM Simulations Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Rasch, P., Pacific Northwest National Laboratory Ivanova, D., Embry-Riddle Aeronautical University McFarquhar, G., University of Illinois, Urbana Nousiainen, T. P., University of Helsinki Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Properties Journal Reference: Mitchell, DL, P

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Summertime Radiative Forcing by Shallow Cumuli at the ARM SGP Download a printable PDF Submitter: Berg, L., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Berg LK, EI Kassianov, CN Long, and DL Mills. 2011. "Surface summertime radiative forcing by shallow cumuli at the ARM SGP." Journal of Geophysical Research - Atmospheres, 116, D01202, 10.1029/2010JD014593. Histogram of hourly average shortwave

  3. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Micropulse Lidar Slant Sensing Retrieval of Aerosol Optical Properties Powell, D.M., and Reagan, J.A., University of Arizona; Spinhirne, J.D., National Aeronautics and Space Administration-Goddard Space Flight Center; Campbell, J.R., and Hlavka, D.L., Science Systems and Applications Inc.; Ferrare, R.A., National Aeronautics and Space Administration-Langley Research Center; Turner, D.D., Flynn, C.J., and Mendosa, A., Pacific Northwest National Laboratory Ninth Atmospheric Radiation Measurement

  4. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GCM Parameterization of Bimodal Size Spectra for Mid-Latitude Cirrus Clouds Ivanova, D. (a), Mitchell, D.L. (a), Arnott, P.W. (a), and Poellot, M. (b), Desert Research Institute (a), Dept. of Atmospheric Science, Univ. of North Dakota (b) Eleventh Atmospheric Radiation Measurement (ARM) Science Team Meeting This is a new mid-latitude cirrus parameterization, based on our current analysis of 996 bimodal size distributions(SDs), obtained from 17 flights, representative for 17 case studies during

  5. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieval of Ice Water Path, Ice Particle Size, and Shape Mitchell, D.L., Arnott, W.P., and Ivanova, D.C., Desert Research Institute Twelfth Atmospheric Radiation Measurement (ARM) Science Team Meeting Ground based retrievals of ice water path, particle size and shape are needed for testing and generating improvements in cloud resolving models and GCMs, a long-standing goal of the ARM program. The lidar/radiometer (LIRAD) method developed by Martin Platt has recently been generalized for using

  6. P

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    P - . . - - 4 v - r REQUEST FOR RECORDS Dl To: NATIONAL ARCHIVES and RECORDS ADMINISTRATION (NIR) WASHINGTON, DC 20408 1. FROM (Agency or establishment) NATIONAL ARCHIVES AND RECORDS ADMIN. 2. MAJOR SUBDIVISION OFFICE OF SPECIAL AND REGIONAL ARCHIVES DATE RECEIVED 6-3-7 6 NOTIFICATION TO AGENCY In accordance with the provisions of 44 U. S. C. 3 303 a, the disposition request, including amendments, is approved except for items that may be marked 3. MINOR SUBDIVISION I is not required; is

  7. viennaking.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IMPROVED ACCURACY FOR LOW-COST SOLAR IRRADIANCE SENSORS D.L. King, W.E. Boyson, B.R. Hansen, and W.I. Bower, Sandia National Laboratories Presented at the 2 nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion, 6-10 July 1998, Vienna, Austria Sandia National Laboratories Sandia National Laboratories Photovoltaic Systems Department Post Office Box 5800 Albuquerque, NM 87185-0753 Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company,

  8. ARM - Datastreams - dlcal1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlcal1 Documentation Data Quality Plots Citation DOI: 10.5439/1025183 [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLCAL1 Doppler Lidar - calibration scan 1 Active Dates 2010.10.30 - 2015.07.22 Measurement Categories Aerosols, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered scientifically relevant are

  9. ARM - Datastreams - dlcal2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlcal2 Documentation Data Quality Plots Citation DOI: 10.5439/1025184 [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLCAL2 Doppler Lidar - calibration scan 2 Active Dates 2010.10.21 - 2016.03.11 Measurement Categories Aerosols, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered scientifically relevant are

  10. ARM - Datastreams - dlfpt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlfpt Documentation Data Quality Plots Citation DOI: 10.5439/1025185 [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLFPT Doppler Lidar - Fixed Pointing mode Active Dates 2010.10.21 - 2016.03.12 Measurement Categories Aerosols, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered scientifically relevant are

  11. ARM - Datastreams - dlppi

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlppi Documentation Data Quality Plots Citation DOI: 10.5439/1025186 [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLPPI Doppler Lidar - Plan Position Indicator Active Dates 2010.10.28 - 2016.03.12 Measurement Categories Aerosols, Atmospheric State, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered

  12. ARM - Datastreams - dlrhi

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlrhi Documentation Data Quality Plots Citation DOI: 10.5439/1046188 [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLRHI Doppler LIDAR Range-Height Indicator scan Active Dates 2011.07.21 - 2015.08.24 Measurement Categories Aerosols, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered scientifically relevant

  13. ARM - Datastreams - dlrhi2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlrhi2 Documentation Data Quality Plots Citation DOI: 10.5439/1025188 [ What is this? ] Generate Citation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLRHI2 Doppler Lidar - Patrial Range-Height-Indicator scan Active Dates 2010.10.21 - 2010.11.21 Measurement Categories Aerosols, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered

  14. ARM - Datastreams - dlusr

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Datastreamsdlusr Documentation Data Quality Plots Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Datastream : DLUSR Doppler Lidar -- ? user information ? Active Dates 2012.07.09 - 2013.07.03 Measurement Categories Aerosols, Cloud Properties Originating Instrument Doppler Lidar (DL) Measurements Only measurements considered scientifically relevant are shown below by default. Show all measurements Measurement Units Variable Altitude above mean sea

  15. A Unified Approach for Reporting ARM Measurement Uncertainties Technical Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 A Unified Approach for Reporting ARM Measurement Uncertainties Technical Report E Campos DL Sisterson October 2015 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents

  16. Conditions for diffusion-limited and reaction-limited recombination in nanostructured solar cells

    SciTech Connect (OSTI)

    Ansari-Rad, Mehdi; Department of Physics, University of Shahrood, Shahrood ; Anta, Juan A.; Arzi, Ezatollah

    2014-04-07

    The performance of Dye-sensitized solar cells (DSC) and related devices made of nanostructured semiconductors relies on a good charge separation, which in turn is achieved by favoring charge transport against recombination. Although both processes occur at very different time scales, hence ensuring good charge separation, in certain cases the kinetics of transport and recombination can be connected, either in a direct or an indirect way. In this work, the connection between electron transport and recombination in nanostructured solar cells is studied both theoretically and by Monte Carlo simulation. Calculations using the Multiple-Trapping model and a realistic trap distribution for nanostructured TiO{sub 2} show that for attempt-to-jump frequencies higher than 10{sup 11}10{sup 13} Hz, the system adopts a reaction limited (RL) regime, with a lifetime which is effectively independent from the speed of the electrons in the transport level. For frequencies lower than those, and depending on the concentration of recombination centers in the material, the system enters a diffusion-limited regime (DL), where the lifetime increases if the speed of free electrons decreases. In general, the conditions for RL or DL recombination depend critically on the time scale difference between recombination kinetics and free-electron transport. Hence, if the former is too rapid with respect to the latter, the system is in the DL regime and total thermalization of carriers is not possible. In the opposite situation, a RL regime arises. Numerical data available in the literature, and the behavior of the lifetime with respect to (1) density of recombination centers and (2) probability of recombination at a given center, suggest that a typical DSC in operation stays in the RL regime with complete thermalization, although a transition to the DL regime may occur for electrolytes or hole conductors where recombination is especially rapid or where there is a larger dispersion of energies of electron acceptors.

  17. CONFIGURATION CHANGE PROPOSAL (CCP)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Change Request | Domain Name Server (DNS) Change | | This change request form is to share information on domain name server changes, new requirements, modifications, or enhancements within the DOE Headquarters programmatic and office management areas. This change request should be forwarded to the Domain Management Team (DL-Domain.Management@hq.doe.gov) for validation, review and discussion. Detailed instructions are available at https://powerpedia.energy.gov/wiki/Domain_change_process. |

  18. Ms. Maria Galanti Site Coordinator

    Office of Environmental Management (EM)

    3 0 2015 Ohio Environmental Protection Agency Southeast District Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: PPP0-03-3065331-15 FINAL RECORD OF DECISION FOR THE PROCESS BUILDINGS AND COMPLEX FACILITIES DECONTAMINATION AND DECOMMISSIONING EVALUATION PROJECT AT THE PORTSMOUTH GASEOUS DIFFUSION PLANT, PIKETON, OHIO (DOE/PPP0/03-0425&Dl) References: 1. Letter from W. Murphie to M. Galanti, "Record of Decision for the Process Buildings and Complex Facilities Decontamination

  19. Mr. Carl Schafer Director of Environmental Policy

    Office of Legacy Management (LM)

    Designeuguns and nuclear projectiles. Radioactive material involvement in the operations is unknown. Believed to have assembled bomb compone$s. Identified on 1954 Accountable Station Lists. /,, i: .; ." , !: ' .. 12. 13. ENCLOSURE 2 (Cont'dl DEPARTMENT OF THE DEFENSE INSTALLATIONS/FACILITIES Installation/Facility MED/AEC Activity Naval Research Laboratory (Former Anacostia Naval Air Station) Washington,. DC Nellis Air Force,Base (*I Las Vegas, NV Conducted research and.development

  20. Mr. Carl Schafer Director of Environmental Policy

    Office of Legacy Management (LM)

    Designeoguns and nuclear projectiles. Radioactive material involvement in the operations is unknown. Believed to have assembled bomb compone$s. Identified on 1954 Accountable Station Lists. /,, i: .; ." , !: ' .. 12. 13. ENCLOSURE 2 (Cont'dl DEPARTMENT OF THE DEFENSE INSTALLATIONS/FACILITIES Installation/Facility MED/AEC Activity Naval Research Laboratory (Former Anacostia Naval Air Station) Washington,. DC Nellis Air Force,Base (*I Las Vegas, NV Conducted research and.development

  1. NMMSS News-October/November 2005

    National Nuclear Security Administration (NNSA)

    OCTOBER/NOVEMBER 2005 SPONSORED BY DOE AND NRC PREPARED BY NAC INTERNATIONAL Office of Security and Safety Performance Assurance Reorganized On October 21, 2005, the DOE Office of Security and Safety Performance Assurance (SSA) announced its new Office of Material Control and Accountability (SP-70) with D.L. Whaley as the acting director. The Office of Material Control and Accountability is responsible for all aspects of SSA's material control and accountability (MC&A) and sealed source

  2. Rivesville multicell fluidized bed boiler

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    One objective of the experimental MFB at Rivesville, WV, was the evaluation of alternate feed systems for injecting coal and limestone into a fluidized bed. A continuous, uniform feed flow to the fluid bed is essential in order to maintain stable operations. The feed system originally installed on the MFB was a gravity feed system with an air assist to help overcome the back pressure created by the fluid bed. The system contained belt, vibrating, and rotary feeders which have been proven adequate in other material handling applications. This system, while usable, had several operational and feeding problems during the MFB testing. A major portion of these problems occurred because the coal and limestone feed control points - a belt feeder and rotary feeder, respectively - were pressurized in the air assist system. These control points were not designed for pressurized service. An alternate feed system which could accept feed from the two control points, split the feed into six equal parts and eliminate the problems of the pressurized system was sought. An alternate feed system designed and built by the Fuller Company was installed and tested at the Rivesville facility. Fuller feed systems were installed on the north and south side of C cell at the Rivesville facility. The systems were designed to handle 10,000 lb/hr of coal and limestone apiece. The systems were installed in late 1979 and evaluated from December 1979 to December 1980. During this time period, nearly 1000 h of operating time was accumulated on each system.

  3. Laboratory-scale sodium-carbonate aggregate concrete interactions. [LMFBR

    SciTech Connect (OSTI)

    Westrich, H.R.; Stockman, H.W.; Suo-Anttila, A.

    1983-09-01

    A series of laboratory-scale experiments was made at 600/sup 0/C to identify the important heat-producing chemical reactions between sodium and carbonate aggregate concretes. Reactions between sodium and carbonate aggregate were found to be responsible for the bulk of heat production in sodium-concrete tests. Exothermic reactions were initiated at 580+-30/sup 0/C for limestone and dolostone aggregates as well as for hydrated limestone concrete, and at 540+-10/sup 0/C for dehydrated limestone concrete, but were ill-defined for dolostone concrete. Major reaction products included CaO, MgO, Na/sub 2/CO/sub 3/, Na/sub 2/O, NaOH, and elemental carbon. Sodium hydroxide, which forms when water is released from cement phases, causes slow erosion of the concrete with little heat production. The time-temperature profiles of these experiments have been modeled with a simplified version of the SLAM computer code, which has allowed derivation of chemical reaction rate coefficients.

  4. Geohydrologic study of the Michigan Basin for the applicability of Jack W. McIntyre`s patented process for simultaneous gas recovery and water disposal in production wells

    SciTech Connect (OSTI)

    Maryn, S.

    1994-03-01

    Geraghty & Miller, Inc. of Midland, Texas conducted a geohydrologic study of the Michigan Basin to evaluate the applicability of Jack McIntyre`s patented process for gas recovery and water disposal in production wells. A review of available publications was conducted to identify, (1) natural gas reservoirs which generate large quantities of gas and water, and (2) underground injection zones for produced water. Research efforts were focused on unconventional natural gas formations. The Antrim Shale is a Devonian gas shale which produces gas and large quantities of water. Total 1992 production from 2,626 wells was 74,209,916 Mcf of gas and 25,795,334 bbl of water. The Middle Devonian Dundee Limestone is a major injection zone for produced water. ``Waterless completion`` wells have been completed in the Antrim Shale for gas recovery and in the Dundee Limestone for water disposal. Jack McIntyre`s patented process has potential application for the recovery of gas from the Antrim Shale and simultaneous injection of produced water into the Dundee Limestone.

  5. Dessicant materials screening for backfill in a salt repository

    SciTech Connect (OSTI)

    Simpson, D.R.

    1980-10-01

    Maintaining an anhydrous environment around nuclear waste stored in a salt repository is a concern which can be alleviated by using a desiccant material for backfilling. Such a desiccant should desiccate a brine yet be non deliquescent, the hydrated product should have moderate thermal stability, and the desiccant should have a high capacity and be readily available. From a literature search MgO and CaO were identified for detailed study. These oxides, and an intimate mixture of the two obtained by calcining dolomite, were used in experiments to further determine their suitability. They proved to be excellent desiccants with a high water capacity. The hydrates of both have moderate thermal stability and a high water content. Both MgO and CaO react in an alkaline chloride brine forming oxychloride compounds with different waters of crystallization. Some of these compounds are the Sorel Cements. CaO hydrates to Ca(OH)/sub 2/ which carbonates with CO/sub 2/ in air to form CaCO/sub 3/ and release the hydrated water. Thus the intimate mixture of CaO and MgO from calcined dolomite may serve as a desiccant and remove CO/sub 2/ from the repository atmosphere.

  6. Maquoketa paleotopography key to reservoirs in western Illinois

    SciTech Connect (OSTI)

    Whitaker, S.T.; Ledbetter, J.C.

    1996-08-12

    Shallow Silurian reservoirs in western Illinois have been a primary target for exploration since the late 1950s. It was not until the discovery and development of Buckhorn Consolidated field in the early 1980s, however, that significant drilling efforts for Silurian reservoirs were focused on western Illinois. At Buckhorn, 1.7 million bbl of oil have been produced from a basal Silurian dolomite at about 650 ft. Drawn by inexpensive drilling and available acreage, hundreds of operators flocked to western Illinois to try their luck. By the late 1980s, however, exploration efforts in western Illinois were curtailed due to the failure to locate additional significant reservoirs. Much of this failure was due to the lack of a suitable geologic model that could be used to explain the reason for reservoir development and thereby guide exploration efforts. An article by Whitaker and Howard in 1995 presented a geologic model explaining Silurian reservoir development and stratigraphic entrapment of oil at Buckhorn Consolidated field were formed as Silurian dolomite in-filled a shallow paleovalley cut into the underlying Ordovician Maquoketa shale. Some companies have recently initiated new exploration efforts in the area using this model. This paper discusses the efforts and results of several of these new areas.

  7. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    SciTech Connect (OSTI)

    Zheng, L.; Samper, J.; Montenegro, L.; Major, J.C.

    2008-10-15

    During the construction and operational phases of a high-level radioactive waste (HLW) repository constructed in a clay formation, ventilation of underground drifts will cause desaturation and oxidation of the rock. The Ventilation Experiment (VE) was performed in a 1.3 m diameter unlined horizontal microtunnel on Opalinus clay at Mont Terri underground research laboratory in Switzerland to evaluate the impact of desaturation on rock properties. A multiphase flow and reactive transport model of VE is presented here. The model accounts for liquid, vapor and air flow, evaporation/condensation and multicomponent reactive solute transport with kinetic dissolution of pyrite and siderite and local-equilibrium dissolution/precipitation of calcite, ferrihydrite, dolomite, gypsum and quartz. Model results reproduce measured vapor flow, liquid pressure and hydrochemical data and capture the trends of measured relative humidities, although such data are slightly overestimated near the rock interface due to uncertainties in the turbulence factor. Rock desaturation allows oxygen to diffuse into the rock and triggers pyrite oxidation, dissolution of calcite and siderite, precipitation of ferrihydrite, dolomite and gypsum and cation exchange. pH in the unsaturated rock varies from 7.8 to 8 and is buffered by calcite. Computed changes in the porosity and the permeability of Opalinus clay in the unsaturated zone caused by oxidation and mineral dissolution/precipitation are smaller than 5%. Therefore, rock properties are not expected to be affected significantly by ventilation of underground drifts during construction and operational phases of a HLW repository in clay.

  8. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  9. Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 4, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler`s outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  10. Porosity reduction in Monterey Formation, California

    SciTech Connect (OSTI)

    Compton, J.S.

    1987-05-01

    Porosity and grain density were determined for different lithologies from throughout a 1.2-km thick section of the Monterey and Sisquoc formations in the Santa Maria basin area, California. Porosity reduction by physical and chemical compaction in the predominantly siliceous sediment is controlled largely by the bulk sediment composition and silica phase transformations. Physical compaction of sediment grains from increasing overburden pressure is responsible for most of the gradual porosity reduction with increasing burial depth in opal-A siliceous ooze and diatomite. The porous, incompressible diatom frustule maintains a high porosity relative to clayey and calcareous sediment. Therefore, a positive correlation exists between porosity and biogenic silica (diatom) content of the sediment. During the opal-A to opal-CT silica phase transformation, solution of the porous diatom frustule and precipitation of cryptocrystalline opal-CT results in a porosity reduction that roughly correlates with the biogenic silica content of the sediment. Local porosity reduction occurs in pore-filling dolomite and chert nodules. Dry bulk density as well as porosity reduction tend to increase with sediment depth. Dolomite and organic matter have the most significant influence on the bulk density because of their respective high and low density. The maximum burial depth of the uplifted and eroded section is estimated by overlapping the porosity-depth relation of average deep-sea siliceous ooze.

  11. Basic data report for drilling and hydrologic testing of drillhole DOE-2 at the Waste Isolation Pilot Plant (WIIP) site

    SciTech Connect (OSTI)

    Mercer, J.W.; Beauheim, R.L.; Snyder, R.P.; Fairer, G.M.

    1987-04-01

    Drillhole DOE-2 was drilled to investigate a structural depression marked by the downward displacement of stratigraphic markers in the Salado Formation. Contrary to several hypotheses, halite layers were thicker in the lower part of the Salado, not thinner as a result of any removal of halite. The upper Castile anhydrite in Drillhole DOE-2 is anomalously thick and is strongly deformed relative to the anhydrite in adjacent drillholes. In contrast, the halite was <8 ft thick and significantly thinner than usually encountered. The lower Castile anhydrite appears to be normal. The depression within the correlated marker beds in the Salado Formation in Drillhole DOE-2 is interpreted as a result of gravity-driven deformation of the underlying Castile Formation. Several stratigraphic units were hydrologically tested in Drillhole DOE-2. Testing of the unsaturated lower portion of the Dewey Lake Red Beds was unsuccessful because of exceptionally small rates of fluid intake. Drill-stem tests were conducted in five intervals in the Rustler Formation, over the Marker Bed 138-139 interval in the Salado formation, and over three sandstone members of the Bell Canyon Formation. A pumping test was conducted in the Culebra Dolomite Member of the Rustler Formation. Pressure-pulse tests were conducted over the entire Salado Formation. Fluid samples were collected from the Culebra Dolomite Member and from the Hays Member of the Bell Canyon Formation. 31 refs., 31 figs., 5 tabs.

  12. Sauk structural elements and depositional response in Ohio and northern Kentucky

    SciTech Connect (OSTI)

    Coogan, A.H.; Peng, Shengfeng (Kent State Univ., OH (United States). Dept. of Geology)

    1992-01-01

    Three area structural elements were inherited from Precambrian events--the Rome Trough, Middle Run trough at the Grenville Line, and the Ohio platform on part of the more stable Grenville Province. They strongly influence the type of basal Sauk clastic and non-clastic deposits as documented from hundreds of wells in Ohio and adjacent northern Kentucky. These elements and the topography resulting from erosion during the Lipalian Interval most directly influence sedimentation during the onlap phase of the basal Sauk Sequence. Clastic wedge-base deposits are the Mt. Simon, Rome'', and Eau Claire formations. Deposition of the middle Cambrian Conasauga Shale coincides with the maximum marine onlap and wedge middle position. Upper Sauk Sequence deposition of the Knox Group carbonate rocks (Cooper Ridge Dolomite, Beekmantown Dolomite) and their interbedded clastic units (Steam Corners and Rose Run formations) represents the shallowing upward, pulsating clastic depositional events which anticipate the differential uplift and erosion that occurred later during the Taconic Orogeny and Early Ordovician hiatus. New Taconic structural elements involve the uplift of the central Ohio platform on the western part of the Grenville Province along reactivated, pre-Grenville sutures identified by CoCorp seismic lines. Platform uplift exposes lower Knox rocks to erosion. Younger Knox rocks are preserved east of the fault line zone. The Appalachian Basin's western edge is marked at this time by the trend of the Rose Run and Beekmantown subcrop below the Knox Unconformity surface and by the edge of the high magnetic intensity basement.

  13. Major Oil Plays in Utah and Vicinity

    SciTech Connect (OSTI)

    Thomas C. Chidsey; Craig D. Morgan; Kevin McClure; Douglas A. Sprinkel; Roger L. Bon; Hellmut H. Doelling

    2003-12-31

    Utah oil fields have produced over 1.2 billion barrels (191 million m{sup 3}). However, the 13.7 million barrels (2.2 million m{sup 3}) of production in 2002 was the lowest level in over 40 years and continued the steady decline that began in the mid-1980s. The Utah Geological Survey believes this trend can be reversed by providing play portfolios for the major oil-producing provinces (Paradox Basin, Uinta Basin, and thrust belt) in Utah and adjacent areas in Colorado and Wyoming. Oil plays are geographic areas with petroleum potential caused by favorable combinations of source rock, migration paths, reservoir rock characteristics, and other factors. The play portfolios will include: descriptions and maps of the major oil plays by reservoir; production and reservoir data; case-study field evaluations; locations of major oil pipelines; identification and discussion of land-use constraints; descriptions of reservoir outcrop analogs; and summaries of the state-of-the-art drilling, completion, and secondary/tertiary techniques for each play. This report covers research activities for the sixth quarter of the project (October 1 through December 31, 2003). This work included describing outcrop analogs for the Jurassic Twin Creek Limestone and Mississippian Leadville Limestone, major oil producers in the thrust belt and Paradox Basin, respectively, and analyzing best practices used in the southern Green River Formation play of the Uinta Basin. Production-scale outcrop analogs provide an excellent view of reservoir petrophysics, facies characteristics, and boundaries contributing to the overall heterogeneity of reservoir rocks. They can be used as a ''template'' for evaluation of data from conventional core, geophysical and petrophysical logs, and seismic surveys. In the Utah/Wyoming thrust belt province, the Jurassic Twin Creek Limestone produces from subsidiary closures along major ramp anticlines where the low-porosity limestone beds are extensively fractured and sealed by overlying argillaceous and non-fractured units. The best outcrop analogs for Twin Creek reservoirs are found at Devils Slide and near the town of Peoa, Utah, where fractures in dense, homogeneous non-porous limestone beds are in contact with the basal siltstone units (containing sealed fractures) of the overlying units. The shallow marine, Mississippian Leadville Limestone is a major oil and gas reservoir in the Paradox Basin of Utah and Colorado. Hydrocarbons are produced from basement-involved, northwest-trending structural traps with closure on both anticlines and faults. Excellent outcrops of Leadville-equivalent rocks are found along the south flank of the Uinta Mountains, Utah. For example, like the Leadville, the Mississippian Madison Limestone contains zones of solution breccia, fractures, and facies variations. When combined with subsurface geological and production data, these outcrop analogs can improve (1) development drilling and production strategies such as horizontal drilling, (2) reservoir-simulation models, (3) reserve calculations, and (4) design and implementation of secondary/tertiary oil recovery programs and other best practices used in the oil fields of Utah and vicinity. In the southern Green River Formation play of the Uinta Basin, optimal drilling, development, and production practices consist of: (1) owning drilling rigs and frac holding tanks; (2) perforating sandstone beds with more than 8 percent neutron porosity and stimulate with separate fracture treatments; (3) placing completed wells on primary production using artificial lift; (4) converting wells relatively soon to secondary waterflooding maintaining reservoir pressure above the bubble point to maximize oil recovery; (5) developing waterflood units using an alternating injector--producer pattern on 40-acre (16-ha) spacing; and (6) recompleting producing wells by perforating all beds that are productive in the waterflood unit. As part of technology transfer activities during this quarter, an abstract describing outcrop reservoir analogs was accepted by the American Assoc

  14. Structure and time of deformation in the central Pancake Range, Nye County, Nevada

    SciTech Connect (OSTI)

    Perry, W.J.; Grow, J.A. )

    1993-04-01

    In east-central Nevada, the Portuguese Mountain area of the central Pancake Range directly west of Railroad Valley contains mapped thrust' faults that form part of the basis of the central Nevada thrust-belt oil play. The authors have mapped and field checked the structure of this area to determine if thrust-style hydrocarbon traps are likely. In this region, previously mapped thrusts have been found to be (1) normal faults, dipping more than 60[degree], (2) landslide masses of both Oligocene igneous rocks and Paleozoic carbonate rocks, and (3) low-angle attenuation faults that omit rather than duplicate stratigraphic section. Locally, the first two types (mapped Portuguese Mountain thrust') involve Oligocene igneous rocks and are therefore younger. The third is represented by a low-angle detachment system northeast of Portuguese Mountain that was first differentially eroded and then overlapped by thin limestone-clast conglomerate and red clays (terra rosa) of the Sheep Pass( ) Formation and overlying volcanic rocks. The possible Sheep Pass correlation would imply that the detachment system is Paleogene or older. Farther north, near McClure Spring, a similar terra rosa and subjacent thin limestone-clast conglomerate sequence is underlain paraconformably by gray claystone containing dinosaur bone fragments, similar to the type Newark Canyon Formation (Cretaceous) to the north. Sheep Pass( ) terra rosa of the upper part of this sequence rest with profound unconformity (nearly 90[degree]) on mid-Pennsylvanian limestone of the east limb of the McClure Spring syncline, a major recumbent syncline cored by Permian to Triassic( ) synorogenic conglomerates. These rocks contain outcrop-scale synorogenic angular unconformities of as much as 15[degree] suggesting that folding began in Permian time. These preliminary results suggest that contractional deformation of the McClure Spring syncline may be pre-Sevier and possibly of Permian-Triassic age.

  15. Flash hydropyrolysis of coal. Quarterly report No. 11, October 1-December 31, 1979

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.; Bhatt, B.L.

    1980-02-01

    The following conclusions can be drawn from this work: (1) when the caking bituminous coals are used with diluents, only 20% Pittsburgh No. 8 coal can be added to the diluent swhile 40% Illinois No. 6 could be added due to the higher free swelling index of the Pittsburgh No. 8; (2) When limestone is used as a diluent, considerably more sulfur is retained in the char than when using sand; (3) when the char from an experiment using limestone is recycled as the diluent for another experiment, the char continually retains additional sulfur through at least three recycles; (4) decomposition of the limestone and reduction is indicated by the high concentrations of CO observed at 900/sup 0/C; (5) increasing the coal feed rate by a factor of 4 from 2.4 to 10.7 lb/hr at low H/sub 2//Coal ratios (approx. = 0.6) results in no appreciable change in gaseous HC yields (approx. = 27%) or concentration (approx. = 45%) but higher BTX yields (1.1% vs. 5.4%); (6) although only one experiment was conducted, it appears that hydrogasification of untreated New Mexico sub-bituminous coal at 950/sup 0/C does not give an increase in yield over hydrogasification at 900/sup 0/C; (7) the hydrogasification of Wyodak lignite gives approximately the same gaseous HC yields as that obtained from North Dakota lignite but higher BTX yields particularly at 900/sup 0/C and 1000 psi (9% vs. 2%); (8) treating New Mexico sub-bituminous coal with NaCO/sub 3/ does not increase its hydrogasification qualities between 600/sup 0/C and 900/sup 0/C at 1000 psi but does decrease the BTX yield.

  16. Mild gasification technology development process: Task 3, Bench-scale char upgrading study, February 1988--November 1990

    SciTech Connect (OSTI)

    Carty, R.H.; Onischak, M.; Babu, S.P.; Knight, R.A.; Wootten, J.M.; Duthie, R.G.

    1990-12-01

    The overall objective of this program is to develop mild gasification technology and co-product utilization. The objective of Task 3 was to investigate the necessary steps for upgrading the mild gasification char into potential high-market-value solid products. Recommendations of the Task 1 market survey section formed the basis for selecting three value-added solid products from mild gasification char: form coke, smokeless fuel, and activated adsorbent char. The formation and testing for the form coke co-product involved an evaluation of its briquette strength and reactivity. The measured tensile strength and reactivity of the form coke sample briquettes were in the range of commercial coke, and development tests on a larger scale are recommended. The reaction rate of the form coke carbon with carbon dioxide at 1825{degree}F was measured using a standard procedure. A smokeless fuel briquette with limestone added to control sulfur can be made from mild gasification char in a simple manner. Test results have shown that briquettes with limestone have a heating value comparable to other solid fuels and the limestone can retain up to 88% of the sulfur during combustion in a simple bench-scale combustion test, almost all of it as a stable calcium sulfate. Adsorbent chars were prepared with a standard steam activation procedure and tested for a variety of pertinent property and performance values. Such adsorbents may be better suited for use in some areas, such as the adsorption of low-molecular-weight substances, because of the smaller pore sizes measured in the char. 5 refs., 17 figs., 6 tabs.

  17. Numerical simulations used for a validity check on the laser induced photo-detachment diagnostic method in electronegative plasmas

    SciTech Connect (OSTI)

    Oudini, N.; Taccogna, F.; Aanesland, A.

    2014-06-15

    Laser photo-detachment is used as a method to measure or determine the negative ion density and temperature in electronegative plasmas. In essence, the method consists of producing an electropositive channel (negative ion free region) via pulsed laser photo-detachment within an electronegative plasma bulk. Electrostatic probes placed in this channel measure the change in the electron density. A second pulse might be used to track the negative ion recovery. From this, the negative ion density and temperature can be determined. We study the formation and relaxation of the electropositive channel via a two-dimensional Particle-In-Cell/Mote Carlo collision model. The simulation is mainly carried out in a Hydrogen plasma with an electronegativity of ??=?1, with a parametric study for ? up to 20. The temporal and spatial evolution of the plasma potential and the electron densities shows the formation of a double layer (DL) confining the photo-detached electrons within the electropositive channel. This DL evolves into two fronts that move in the opposite directions inside and outside of the laser spot region. As a consequence, within the laser spot region, the background and photo-detached electron energy distribution function relaxes/thermalizes via collisionless effects such as Fermi acceleration and Landau damping. Moreover, the simulations show that collisional effects and the DL electric field strength might play a non-negligible role in the negative ion recovery within the laser spot region, leading to a two-temperature negative ion distribution. The latter result might have important effects in the determination of the negative ion density and temperature from laser photo detachment diagnostic.

  18. Mineralogical evaluation and industrial applications of the Triassic clay deposits, Southern Tunisia

    SciTech Connect (OSTI)

    Baccour, H. Medhioub, M.; Jamoussi, F.; Mhiri, T.; Daoud, A.

    2008-11-15

    This study deals with the mineralogical and thermal analysis of Triassic clays in the south-Eastern Tunisia (Medenine area) in order to use them in the faience ceramic. That is why the study had recourse to several quantitative and qualitative research instruments: chemical analysis, mineralogical study, thermal analyses and analyses of geotechnical traits. The data collected from these techniques show that illite and kaolinite are the major clay phases. The accessory minerals detected in powdered rock are; quartz, dolomite and hematite. Geotechnical characterization was carried out on the three representative mixtures of Triassic clay samples. Each mixture is fired at three different temperatures 850,900 and 950 deg. C. Firing characteristics (shrinkage, water absorption, and mechanical resistance to the inflection) were measured and the neomineralization processes were investigated principally by X-ray diffraction. At the end of this study, one can affirm that these clays have qualities necessary for the manufacture of faience ceramic and earthenware production.

  19. Petrographic report on clay-rich samples from Permian Unit 4 salt, G. Friemel No. 1 well, Palo Duro Basin, Deaf Smith County, Texas: unanalyzed data

    SciTech Connect (OSTI)

    Fukui, L M

    1983-09-01

    This report presents the results of mineralogic and petrographic analyses performed on five samples of clay-rich rock from salt-bearing Permian strata sampled by drill core from G. Friemel No. 1 Well, Deaf Smith County, Texas. Five samples of clay-rich rock from depths of about 2457, 2458, 2521, 2548, and 2568 feet were analyzed to determine the amounts of soluble phase (halite) and the amounts and mineralogy of the insoluble phases. The amounts of halite found were 59, 79, 47, 40, and 4 weight percent, respectively, for the samples. The insoluble minerals are predominately clay (20 to 60 volume percent) and anhydrite (up to 17 volume percent), with minor (about 1.0%) and trace amounts of quartz, dolomite, muscovite, and gypsum. The clays include illite, chlorite, and interstratified chlorite-smectite. The results presented in this petrographic report are descriptive, uninterpreted data. 2 references, 7 tables.

  20. Loop-bed combustion apparatus

    DOE Patents [OSTI]

    Shang, Jer-Yu (Fairfax, VA); Mei, Joseph S. (Morgantown, WV); Slagle, Frank D. (Kingwood, WV); Notestein, John E. (Morgantown, WV)

    1984-01-01

    The present invention is directed to a combustion apparatus in the configuration of a oblong annulus defining a closed loop. Particulate coal together with a sulfur sorbent such as sulfur or dolomite is introduced into the closed loop, ignited, and propelled at a high rate of speed around the loop. Flue gas is withdrawn from a location in the closed loop in close proximity to an area in the loop where centrifugal force imposed upon the larger particulate material maintains these particulates at a location spaced from the flue gas outlet. Only flue gas and smaller particulates resulting from the combustion and innerparticle grinding are discharged from the combustor. This structural arrangement provides increased combustion efficiency due to the essentially complete combustion of the coal particulates as well as increased sulfur absorption due to the innerparticle grinding of the sorbent which provides greater particle surface area.

  1. Biomass gasification for liquid fuel production

    SciTech Connect (OSTI)

    Najser, Jan E-mail: vaclav.peer@vsb.cz; Peer, Vclav E-mail: vaclav.peer@vsb.cz

    2014-08-06

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they do?t compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  2. Selective flotation of phosphate minerals with hydroxamate collectors

    DOE Patents [OSTI]

    Miller, Jan D.; Wang, Xuming; Li, Minhua

    2002-01-01

    A method is disclosed for separating phosphate minerals from a mineral mixture, particularly from high-dolomite containing phosphate ores. The method involves conditioning the mineral mixture by contacting in an aqueous in environment with a collector in an amount sufficient for promoting flotation of phosphate minerals. The collector is a hydroxamate compound of the formula; ##STR1## wherein R is generally hydrophobic and chosen such that the collector has solubility or dispersion properties it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms. M is a cation, typically hydrogen, an alkali metal or an alkaline earth metal. Preferably, the collector also comprises an alcohol of the formula, R'--OH wherein R' is generally hydrophobic and chosen such that the collector has solubility or dispersion properties so that it can be distributed in the mineral mixture, typically an alkyl, aryl, or alkylaryl group having 6 to 18 carbon atoms.

  3. Completion and workover fluid

    SciTech Connect (OSTI)

    Block, J.

    1985-09-17

    An aqueous completion or workover fluid for oil or gas wells having at least two solid components. One component is a hydroxy containing aluminum compound represented by the formula AlO(OH).xH/sub 2/O. The second component is a fluid loss control agent which can be either a cross-linked polyvinyl alcohol or a cross-linked hydroxyalkyl cellulose reaction product. An acid soluble weighting agent can be added for wells having higher down hole pressures. Examples of the weighting agents include iron carbonates, iron oxides, calcium carbonates, dolomite, sodium or calcium chloride, zinc bromide and calcium bromide. After use, the fluid can be displaced from the well with acid, e.g. 15% HCl, and the cake previously deposited on the bore-hole wall is dissolved by the acid so that no damaging residue remains.

  4. Re-use of drinking water treatment plant (DWTP) sludge: Characterization and technological behaviour of cement mortars with atomized sludge additions

    SciTech Connect (OSTI)

    Husillos Rodriguez, N.; Martinez Ramirez, S.; Blanco Varela, M.T.; Guillem, M.; Puig, J.; Larrotcha, E.; Flores, J.

    2010-05-15

    This paper aims to characterize spray-dried DWTP sludge and evaluate its possible use as an addition for the cement industry. It describes the physical, chemical and micro-structural characterization of the sludge as well as the effect of its addition to Portland cements on the hydration, water demand, setting and mechanical strength of standardized mortars. Spray drying DWTP sludge generates a readily handled powdery material whose particle size is similar to those of Portland cement. The atomized sludge contains 12-14% organic matter (mainly fatty acids), while its main mineral constituents are muscovite, quartz, calcite, dolomite and seraphinite (or clinoclor). Its amorphous material content is 35%. The mortars were made with type CEM I Portland cement mixed with 10 to 30% atomized sludge exhibited lower mechanical strength than the control cement and a decline in slump. Setting was also altered in the blended cements with respect to the control.

  5. Pore scale modeling of reactive transport involved in geologic CO2 sequestration

    SciTech Connect (OSTI)

    Kang, Qinjin; Lichtner, Peter C; Viswanathan, Hari S; Abdel-fattah, Amr I

    2009-01-01

    We apply a multi-component reactive transport lattice Boltzmann model developed in previolls studies to modeling the injection of a C02 saturated brine into various porous media structures at temperature T=25 and 80 C. The porous media are originally consisted of calcite. A chemical system consisting of Na+, Ca2+, Mg2+, H+, CO2(aq), and CI-is considered. The fluid flow, advection and diHusion of aqueous species, homogeneous reactions occurring in the bulk fluid, as weB as the dissolution of calcite and precipitation of dolomite are simulated at the pore scale. The effects of porous media structure on reactive transport are investigated. The results are compared with continuum scale modeling and the agreement and discrepancy are discussed. This work may shed some light on the fundamental physics occurring at the pore scale for reactive transport involved in geologic C02 sequestration.

  6. Basic Data Report for Drillhole SNL-1 (C-2953)

    SciTech Connect (OSTI)

    Dennis W. Powers; Washington Regulatory and Environmental Services

    2005-01-19

    SNL-1 (permitted by the New Mexico State Engineer as C-2953) was drilled to provide geological data and hydrological testing of the Culebra Dolomite Member of the Permian Rustler Formation near the margin of dissolution of halite in the upper Permian Salado Formation in the northeast arm of Nash Draw. SNL-1 is located in the northwest quarter of section 16, T21S, R31E, in eastern Eddy County, New Mexico, and it is adjacent to the tailings pile of Mississippi Potash Incorporated (now Intrepid) East mine to test for the presence of shallow zones that might include brine infiltrated from the tailings pile. SNL-1 was drilled to a total depth of 644 ft below ground level (bgl). Below surface wash, SNL-1 encountered, in order, the Mescalero caliche, Dewey Lake, and Rustler Formations.

  7. Method of production H/sub 2/ using a rotating drum reactor with a pulse jet heat source

    DOE Patents [OSTI]

    Paulson, L.E.

    1988-05-13

    A method of producing hydrogen by an endothermic steam-carbon reaction using a rotating drum reactor and a pulse jet combustor. The pulse jet combustor uses coal dust as a fuel to provide reaction temperatures of 1300/degree/ to 1400/degree/F. Low-rank coal, water, limestone and catalyst are fed into the drum reactor where they are heated, tumbled and reacted. Part of the reaction product from the rotating drum reactor is hydrogen which can be utilized in suitable devices. 1 fig.

  8. Hybrid fluidized bed combuster

    DOE Patents [OSTI]

    Kantesaria, Prabhudas P. (Windsor, CT); Matthews, Francis T. (Poquonock, CT)

    1982-01-01

    A first atmospheric bubbling fluidized bed furnace is combined with a second turbulent, circulating fluidized bed furnace to produce heat efficiently from crushed solid fuel. The bed of the second furnace receives the smaller sizes of crushed solid fuel, unreacted limestone from the first bed, and elutriated solids extracted from the flu gases of the first bed. The two-stage combustion of crushed solid fuel provides a system with an efficiency greater than available with use of a single furnace of a fluidized bed.

  9. Mesoscopic modeling of multi-physicochemical transport phenomena in porous media

    SciTech Connect (OSTI)

    Kang, Qinjin; Wang, Moran; Mukherjee, Partha P; Lichtner, Peter C

    2009-01-01

    We present our recent progress on mesoscopic modeling of multi-physicochemical transport phenomena in porous media based on the lattice Boltzmann method. Simulation examples include injection of CO{sub 2} saturated brine into a limestone rock, two-phase behavior and flooding phenomena in polymer electrolyte fuel cells, and electroosmosis in homogeneously charged porous media. It is shown that the lattice Boltzmann method can account for multiple, coupled physicochemical processes in these systems and can shed some light on the underlying physics occuning at the fundamental scale. Therefore, it can be a potential powerful numerical tool to analyze multi-physicochemical processes in various energy, earth, and environmental systems.

  10. Alabama Profile

    Gasoline and Diesel Fuel Update (EIA)

    Alabama State Energy Profile Alabama Quick Facts In 2013, Alabama ranked 17th in the nation in the number of producing natural gas wells. Mobile, Alabama was the fourth-largest seaport for exporting U.S. coal in 2013. Coking coal used in the steelmaking process accounted for 82% of total exported coal. The three reactors at the Browns Ferry Nuclear Plant in Limestone County, Alabama have a combined generating capacity of 3,310 megawatts, second in capacity only to Arizona's Palo Verde plant.

  11. Trenton strata in western Illinois Basin, Brown and Schuyler Counties, Illinois

    SciTech Connect (OSTI)

    Pochel, R.M.

    1984-12-01

    Trenton strata in the western Illinois basin are very good prospects for oil exploration. Much drilling has been done in the area but, as yet, no producing wells have been completed. Oil stains and some tars have been found in some samples from most wells. The Trenton in the area of Brown and Schuyler Counties is a fine-grained limestone that underlies the Maquoketa Shale at an average depth of 800 ft (244 m). Because of its position near the edge of the Illinois basin, the stratigraphy varies considerably and inconsistencies are present in most samples viewed.

  12. Retrofit costs for SO sub 2 and NOx control options at 200 coal-fired plants

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This 5-volume report gives the results of site-specific cost estimations for retrofitting six control technologies to coal-fired power plants. The six technologies were: lime/limestone flue gas desulfurization, lime spray drying, coal switching and cleaning, furnace and duct sorbent injection, low NOx combustion or natural gas reburning, and selective catalytic reduction. Volume 1 gives the methodology. The other four volumes each cover 5-7 specific states east of the Mississippi River. Maine, Vermont, Rhode Island, and Connecticut are not included.

  13. Performance and economics of a spray-dryer FGD system used with high-sulfur coal

    SciTech Connect (OSTI)

    Livengood, C.D.; Farber, P.S.

    1986-04-01

    Flue-gas desulfurization (FGD) systems based on spray drying to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. Uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. This paper summarizes 4 years, operating and research experience with that system and describes the current research program, which includes an indepth characterization of an industrial scale dry scrubber with 3.5% sulfur coal.

  14. Pumped storage job is a rocky challenge

    SciTech Connect (OSTI)

    Setzer, S.W.

    1994-03-07

    Georgia mountain lives up to its rugged name as excavators fight some unexpected ground conditions. When settlers pushed into the remote valleys of far northwestern Georgia, they had no idea just how apt the name given one odd geologic formation would become to a new generation of pioneers. Rocky Mountain`s 700 ft of diagonally upthrusting limestone, shale and sandstone layers have become the main antagonists in a decade-long struggle to place an 848-Mw pumped storage power project in and around the mountain.

  15. Pueblo of Jemez Geothermal Feasibility Study Fianl Report

    SciTech Connect (OSTI)

    S.A. Kelley; N. Rogers; S. Sandberg; J. Witcher; J. Whittier

    2005-03-31

    This project assessed the feasibility of developing geothermal energy on the Pueblo of Jemez, with particular attention to the Red Rocks area. Geologic mapping of the Red Rocks area was done at a scale of 1:6000 and geophysical surveys identified a potential drilling target at a depth of 420 feet. The most feasible business identified to use geothermal energy on the reservation was a greenhouse growing culinary and medicinal herbs. Space heating and a spa were identified as two other likely uses of geothermal energy at Jemez Pueblo. Further geophysical surveys are needed to identify the depth to the Madera Limestone, the most likely host for a major geothermal reservoir.

  16. Characterizing toxic emissions from a coal-fired power plant demonstrating the AFGD ICCT Project and a plant utilizing a dry scrubber/baghouse system: Bailly Station Units 7 and 8 and AFGD ICCT Project. Final report. Final report

    SciTech Connect (OSTI)

    Dismukes, E.B.

    1994-10-20

    This report describes results of assessment of the risk of emissions of hazardous air pollutants at one of the electric power stations, Bailly Station, which is also the site of a Clean Coal Technology project demonstrating the Pure Air Advanced Flue Gas Desulfurization process (wet limestone). This station represents the configuration of no NO{sub x} reduction, particulate control with electrostatic precipitators, and SO{sub 2} control with a wet scrubber. The test was conducted September 3--6, 1993. Sixteen trace metals were determined along with 5 major metals. Other inorganic substances and organic compounds were also determined.

  17. Boston's McCormack Building Gets Makeover | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Boston's McCormack Building Gets Makeover Boston's McCormack Building Gets Makeover November 4, 2010 - 10:53am Addthis Maya Payne Smart Former Writer for Energy Empowers, EERE Constructed from 1931 to 1933, the U.S. Post Office and Courthouse in Boston created quite a buzz with its Art Deco design. A departure from the Classical Revival style popular among federal buildings of the time, its aluminum windows, unadorned granite and limestone base and stepped parapets illustrated its modernity. But

  18. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2001-07-01

    Mechanically weak formations, such as chalks, high porosity sandstones, and marine sediments, pose significant problems for oil and gas operators. Problems such as compaction, subsidence, and loss of permeability can affect reservoir production operations. For example, the unexpected subsidence of the Ekofisk chalk in the North Sea required over one billion dollars to re-engineer production facilities to account for losses created during that compaction (Sulak 1991). Another problem in weak formations is that of shallow water flows (SWF). Deep water drilling operations sometimes encounter cases where the marine sediments, at shallow depths just below the seafloor, begin to uncontrollably flow up and around the drill pipe. SWF problems created a loss of $150 million for the Ursa development project in the U.S. Gulf Coast SWF (Furlow 1998a,b; 1999a,b). The goal of this project is to provide a database on both the rock mechanical properties and the geophysical properties of weak rocks and sediments. These could be used by oil and gas companies to detect, evaluate, and alleviate potential production and drilling problems. The results will be useful in, for example, pre-drill detection of events such as SWF's by allowing a correlation of seismic data (such as hazard surveys) to rock mechanical properties. The data sets could also be useful for 4-D monitoring of the compaction and subsidence of an existing reservoir and imaging the zones of damage. During the second quarter of the project the research team has: (1) completed acoustic sensor construction, (2) conducted reconnaissance tests to map the deformational behaviors of the various rocks, (3) developed a sample assembly for the measurement of dynamic elastic and poroelastic parameters during triaxial testing, and (4) conducted a detailed review of the scientific literature and compiled a bibliography of that review. During the first quarter of the project the research team acquired several rock types for testing including: (a) Danian chalk, (b) Cordoba Cream limestone, (c) Indiana limestone, (d) Ekofisk chalk, (e) Oil Creek sandstone, (f) unconsolidated Oil Creek sand, and (g) unconsolidated Brazos river sand. During the second quarter experiments were begun on these rock types. A series of reconnaissance experiments have been carried out on all but the Ekofisk (for which there is a preliminary data set already inhouse). A series of triaxial tests have been conducted on the Danian chalk, the Cordoba Cream limestone, the Indiana limestone, and sand samples to make a preliminary determination of the deformational mechanisms present in these samples.

  19. New interpretations of Paleozoic stratigraphy and history in the northern Laramie Range and vicinity, Southeast Wyoming

    SciTech Connect (OSTI)

    Sando, W.J.; Sandberg, C.A.

    1987-01-01

    Biostratigraphic and lithostratigraphic studies of the Paleozoic sequence in Southeast Wyoming indicate the need for revision of the ages and nomenclature of Devonian, Mississippian, and Pennsylvanian formations. The Paleozoic sequence begins with a quartzarenite of Devonian age referred to the newly named Fremont Canyon Sandstone, which is overlain by the Englewood Formation of Late Devonian and Early Mississippian age. The Englewood is succeeded by the Madison Limestone of Early and Late Mississippian age, which is overlain disconformably by the Darwin Sandstone Member (Pennsylvanian) of the Casper and Hartville formations. This sequence represents predominantly marine deposition in near-shore environments marginal to the ancient Transcontinental Arch.

  20. From:

    Office of Environmental Management (EM)

    Energy Development Oversight vs Midwest Farmer Heartache Date: Sunday, September 21, 2014 2:51:40 PM FERC needs to mandate transmission lines are be within existing right of ways such as utility and highway corridors as intended by our legislature in S1462. FERC needs to mandate these lines are to be buried using current technology such as HVDC Light Line, following the best practices in Canada and Europe. In Missouri this is north of the fragile Karst limestone formations or within Highway 36.

  1. S P

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S P 0 s 00 0 t 4 ENVIRONMENTAL PROTECTION DlVMON OF ENVIRONMENTAL PROTECTION Leo M. Drozdofi flE.,Adrninistral b e - protecting the future for generations o + August 2,2006 Ms. Angela P. Colarusso, Acting Federal Project Director Waste Management Project National Nuclear Security Administration Nevada Site Office P.O. Box 9851 8 Las Vegas, NV 891 93-851 8 Re: Regulatory Position Regarding Void Space The Nevada Division of Environmental Protection, Bureau of Federal Facilities (NDEP) has been

  2. Appendix B - Control Points

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B Control Points B.1 Injector Control Points Qty Type Device 2 Magnet Bend magnet - DL1 bend 9 Magnet Quad magnet 10 Magnet X-Y Corrector Pair 2 Magnet Solenoid 2 Magnet Spectrometer 1 RF Gun 2 RF Accelerating Structure 1 RF Transverse RF Structure 1 TIMING Timing/Trigger System 1 Laser Gun Laser 1 Laser Alignment Laser 13 DIAG BPM 4 DIAG Wire Scanner 11 DIAG Profile Monitor 3 DIAG Toroid 1 DIAG Transverse RF BL Monitor 3 DIAG Faraday Cup 1 DIAG Energy Collimator 1 DIAG Tune-up Dump 1 VAC Vacuum

  3. Flight Path 90L - About TPC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Target 4 Flight Path 90L (TPC) Collaborators LANL: F. Tovesson, R. Meharchand, V. Kleinrath, D.L. Duke LLNL: M. Cunningham, M. Heffner, J.Ruz, S. Sangiorgio, B. Seilhan, L. Snyder PNNL: D.M. Asner, S. Stave, G. Tatishvili, L. Wood INL: T. Hill California Polytechnic State University, San Luis Obispo: R.G. Baker, J.L. Klay Colorado School of Mines: U. Greife, J. Bundgaard, U. Hager Idaho State University: E. Burgett, J. Deaven, B. Wendt Ohio University: S. Grimes, N. Kornilov, T.N. Massey Abilene

  4. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  5. Hemoglobin Labeled by Radioactive Lysine

    DOE R&D Accomplishments [OSTI]

    Bale, W. F.; Yuile, C. L.; DeLaVergne, L.; Miller, L. L.; Whipple, G. H.

    1949-12-08

    This paper reports on the utilization of tagged epsilon carbon of DL-lysine by a dog both anemic and hypoproteinemic due to repeated bleeding plus a diet low in protein. The experiment extended over period of 234 days, a time sufficient to indicate an erythrocyte life span of at least 115 days based upon the rate of replacement of labeled red cell proteins. The proteins of broken down red cells seem not to be used with any great preference for the synthesis of new hemoglobin.

  6. Documentation - Laboratory for Laser Energetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 - Laser Drivers Front Matter - Maintenance Index & Schedules (S-OM-P-026) Laser Driver Subsystem Procedures Check for Ground Loops (S-SM-P-002) ACSL IFES Synchronization (S-SM-P-053) 12GHz Agilent DSO91204A Calibration Procedure (SSD/BL) (S-SM-P-397) 12 GHz Keysight Scope Calibration (PHX/DL) (S-SM-P-397) TMPS Contrast Measurement (S-SM-P-426) TMPS Switch Voltage Calibration (S-SM-P-427) PGR/DER HVAC Check (S-SM-P-081) Pulse Shaping Procedures Modulator Calibration (MODCAL) (S-SM-P-004)

  7. ENVIRONMENTAL NOTIFICATION FORM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Document(s) responsive to Item 1 TOC-ENV-NOT-2013-0019 Rev. 0 ENVIRONMENTAL NOTIFICATION FORM Date: 02/15/2013 Notification No.: TOC-ENV-NOT- 2013-0019 Name: D.L. Dyekman Revision No. 0 Section 1. Spills NA M ChemicalName: see section 3 below MSDS No.: n/a Regulated per 40 CFR 302: Yes 0 No 13EPCRA EHS: Yes Z No E3 CAS No.: n/ a Quantity Released: up to 300gal/yr Reportable Quantity (RO):_________ CAS No.: ________Quantity Released: ___________Reportable Quantity (RO):__________ CAS No.:

  8. Lawrence Berkeley Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    e UNIVERSITY OF CALIFORNIA Presented at the International Workhop on Physics and Engineering in Computerized Multidimensional Imaging and Processing, Irvine, CA, April 4, 1986; and to be published in Journal of the SPIE RECENT DEVELOPMENTS IN POSITRON EMISSION TOMOGRAPHY (PET) INSTRUMENTATION S.E. Derenzo and T.F. Budinger April 1986 Prepared for the U.S. Department of Energy under Contract DE-AC03-76SF00098 DlSTRlBUTiON OF THIS DOCUMENT bs UMLtMlTEO LEGAL NOTICE This book was prepared as an

  9. Microsoft Word - Varenna_Paper-11.dot

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interferometry Techniques for Burning Plasmas D.L. Brower, W.X. Ding Department of Physics University of California at Los Angeles Los Angeles, California 90095-1547 USA V.V. Mirnov Department of Physics University of Wisconsin-Madison Madison, Wisconsin 53706 USA M.A. Van Zeeland, T.N. Carlstrom General Atomics San Diego, California 92121-1122 USA Abstract. For future burning plasma experiments, all diagnostics must be re-evaluated in terms of their measurement capabilities and robustness to

  10. Microsoft PowerPoint - 02XEPO-0_Lustre.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lustre File System Lustre File System Customer Documentation and Training Cray XT/XE Systems I/O Support - The compute nodes usually hand off I/O to the SIO or XIO (service I/O) nodes Th li ti l h h dl tdi - The aprun application launcher handles stdin, stdout, and stderr Refer to the Cray XT Programming Environment User's Guide y g g (S-2396), "I/O Support" in the "Catamount Programming Considerations" section 10/18/2010 2 Cray Private Cray I/O Architecture A li ti Login

  11. RESULTS OF RADIOLOGICAL I'IEASUREMENTS HIGHT{AYS 18 AI.ID IO4 IN NIAGARA

    Office of Legacy Management (LM)

    9s' RESULTS OF RADIOLOGICAL I'IEASUREMENTS HIGHT{AYS 18 AI.ID IO4 IN NIAGARA az76 rl//.ry' ORNL/RASA.85/ 40 TAKEN AT JUNCTION FALLS, NEH YORK Accesr to the information in thit rcport ir limiled to tho!' inOllateO on tho dl3tribution li3t and to OePartment ot Encrgy and Oepartmcnt ol Enotgy Gontracton This report was prepared as an account of work sponsored by an agency of the United States Government. Neitherth€ U nited StatesGovernment norany agency thereof, nor any of their employees, makes

  12. A case report of lead paint poisoning during renovation of a Victorian farmhouse

    SciTech Connect (OSTI)

    Marino, P.E.; Landrigan, P.J.; Graef, J.; Nussbaum, A.; Bayan, G.; Boch, K.; Boch, S. )

    1990-10-01

    We describe a series of four cases of childhood lead poisoning and two cases of adult lead toxicity in a professional family exposed to lead dust and fume during renovation of a rural farmhouse. Initial blood lead levels in the children ranged from 2.70 to 4.20 microM/L (56 to 87 microns/dl) and all four required chelation therapy. Lead-based paint poisoning, a well recognized entity among young children in poor, urban neighborhoods, is not confined exclusively to such areas.

  13. Ed Jascevsky Safety Division ChIcago Operations Office MIT CONTFACT INFCE"ATION

    Office of Legacy Management (LM)

    ;/:4,4 (; . 1.; e octo: ' J : 18, 1976 Ed Jascevsky Safety Division ChIcago Operations Office MIT CONTFACT INFCE"ATION During the discussions on October 8, 1976, you iquired about information relative to work done by MIT as background infomation for survey planning. The enclosed information is parephrased frorc an unpublished history of program work carried out by the Process Eevclopncnt Group of the Dl.ti,si.on of Raw Katerids, I believe this work was done under contract nuder AT(30-1)956.

  14. The Honorable Marvin,L. Kay

    Office of Legacy Management (LM)

    .' @partment of Energy, / Washington. DC 20585 : .. , The Honorable Marvin,L. Kay 911 10th Street, City Hall , Golden, Colorado 804dl. . . Dear Mayor Kay: : 'j, . .,a approach to openness in with the public. 'In Secretary of Energy Hazel .O'Leary,has announced a new the Department of Energy (DOE) and its communications 'support of.this, initiative, we,are pleased to,forward the enclosed information related to the former.Coors.Porcelain site in your jurisdiction that performed work'for DOE's

  15. United States Government

    Office of Legacy Management (LM)

    DOE F t325.8 (s8s) Dl? l 36-z EFG (07-90) United States Government m e m o randum Department of Energy DATE: LUG 2 ' 3 1394 ",cl,'," EM-421 (W. A. W illiams, 427-1719) SUBJECT: Elimination of the Sites from the Formerly Utilized Sites Remedial Action Program To' The File In 1990, with the assistance of M r. Doug Tonkay and Ms. M ichelle Landis, I reviewed a number of sites that had formerly provided goods and/or services to the Fernald facility as subcontractors. For 24 of these sites,

  16. z

    Office of Legacy Management (LM)

    ,,:,z !8,!,. i ,OCT 2 8 1981 .., : $... . ,, .., ., ? conversation of October 14,.1981.~sb&ween Dr. My& A. Whitman regarding the collection of samples and infnm , to'verify the results of the decontamination effortc nf '1.. : asreported in their. final radioloalcal PIIIWW N ^- : .' ..' -:'.& dlSCUS& &ring the me&in; it DOE Headq&&~S on-Se$&&'i, lg& ;' . . ,'~ :~ ' with Dr. R. Wmveen. Mr. W. Smfth. and yourself, we concur wfth the'schedile of actfvftfes

  17. CENTRAL NEVADA-16 January

    Office of Legacy Management (LM)

    CENTRAL NEVADA-16 January 1970 UNITED STATES DEPARTMENT OF THE Dl"'TERIOR GEOLOGICAL SURVEY Federal Center. Denver. Colorado 80225 PRELIMINARY REPORT ON TliE GEOLOGIC EFFECTS OF THE FAULTLESS EVENT By ,'. USGS-474-65 F. A. McKeown. D. D. Dickey and W. L. Ellis ABSTRACT The Faultless event. an intermediate-yield nucl~ar explosion, produced fractures as much as thousands of feet in length, most of which are along preevent lineaments. Vertical displacements on the fractures are as much as

  18. F33

    Office of Legacy Management (LM)

    F33 ,> : ' I ,fl*; ,' . * DO EIEV-0005139 ANL=OHS/HP-83401 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE ALBANY METALLURGICAL RESEARCH CENTER UNITED STATES BUREAU OF MINES BIOMASS FACILITY AND THE "BACK FORTY" AREA ALBANY, OREGON *&-c+ +f@ $+-S pJJol ' ( % . BP CP OCCUPATIONAL HEALTH AND SAFETY DlVlSlON Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Operated by THE UNIVERSITY OF CHICAGO for the U. S. DEPARTMENT OF

  19. L

    Office of Legacy Management (LM)

    c. : -* :. : 1 : : ; : s ' ;: ..:, --A,, -... ! : ' Q "3 _, ' ;' ,Z .2 , ., .- -2 ' 1 ' \A ' ., 3 \ * .' >,-' ;;' ;x., -.; t 1 ' .L i ' iq. ) :p 22T*+g~;s~ .r(,, , ~~::---y-~' -' --, ) ,;*; -,:;' L;e.-:.:.: ..,. >,.*L<seT,, :' .5 -1,; JI I,' ' <> ' I. ..; -_ : ,... :,-.;i __. PRODUCTXIN PJZPORT "* *_ ' L T I R(.XJXXG OF TT~C l!ftN D X m X3AZ~IEX INGCt.fS. A T * 2lI,mG~~-LuDL~~~ sTl2zEL coRPoR:!'"I9~~- -_. . _.. ,. .: ii .- _, . :. GN Ofiicial CkuiFcr??bn. d t!+

  20. Lr Lr F

    Office of Legacy Management (LM)

    r* Lr Lr F r F I P I- rr c1 c I' ORAU 89/G-76 0 ogfjj Prepared by Oak Ridge Associated Universities Prepared for Divisiin of Facility and Site Decommissioning U.S. Department of Enwgy RADIOLOGICAL SURVEY AT 4555 WEST ADDISON STREET CHICAGO, ILLINO IS M. FL LAblDlS FINAL REPORT * OCTOBER 1989 I I I + Environmental Survey and Site Assessment Program Energy/Environment Systems Division I _--- a.^-_ -_. ORAU 89/G-76 RADIOLOGICAL SURVEY AT 4555 WEST ADDISON STREET CHICAGO, ILLINOIS Prepared by M.R.

  1. MEMORANDUM TO: FILE DATE

    Office of Legacy Management (LM)

    FROH: ~+dL :fi:k ALTERNATE F~-5~iM-~~IcRe-C~f~-~----NAME: -------.e-- ____ OWNER(S) ------__ past: ~~-~Y~~~~-~~~~~Current: --x+-!!xh)- ___________ l- Owner c:nntacted q yes xno; if yea, date contacted TYPE OF OPERATION -------------____ BR~+earch & Development -a Facility Type @?..Pdtt. r'o UC Ion scale testing 0 Pilot Scale @ Manufacturing 0 Bench Scale Process q University a Theoretical Studies 0 Research Organization 0 Sample & Analysis 0 Government Sponsored Facility 0 Other

  2. Mr. Carl Schafer Director of Environmental Policy

    Office of Legacy Management (LM)

    MP.Y 2 9 1987 -f/j ' I ,DL -3 d Mr. Carl Schafer Director of Environmental Policy Office of the Deputy Assistant Secretary of Defense for Installations Pentagon Washington, D.C. 20301 Dear Mr. Schafer: As you know, the Department of Energy (DOE) is implementing a program to identify sites that may be radiologically contaminated as a result of DOE predecessor operations and to correct any problems associated with this contamination if there is DOE authority to do so. Reviews of historical

  3. Mr. Carl Schafer Director of Environmental Policy

    Office of Legacy Management (LM)

    Cont'dl DEPARTMENT OF THE DEFENSE INSTALLATIONS/FACILITIES Installation/Facility MED/AEC Activity Naval Research Laboratory (Former Anacostia Naval Air Station) Washington,. DC Nellis Air Force,Base (*I Las Vegas, NV Conducted research and.development activi,ties on thermal diffusion. A.pilot plant (S-50 Plant).was built at the former Anacostia Naval ./Y Air Station to separate uranium isotopes by ;,~!,c liquid thermal diffusion. A letter dated 26 Aug 1969 from the Commanding Officer, Lake Mead

  4. NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT.

    Office of Legacy Management (LM)

    NATIONAL LEAD COMPANY OF OHIO HEALTH AND SAFETY DIVISION - ANALYTICAL DEPT. ANALYTICAL DATA SHEET 1. H. NO. INDUSTRIAL HYGIENE AND RADIATION DEPT. ANALYTICAL CHEMISTRY SECT10 AMPLE NOS.: - ROUTE TO1 7 c, U NO:, Oil Bo Cl Beta METHOD OC ANALYSIS: Ro r/fae*3 r4tSAAQ. 5 PH DYI Th TSS COVNTINO DATA1 -BKGD .31=/cr, b EO w% SAMPLE I HOUR SAMPLE DESCRIPTION NO. DlSTRlBUTlON OF COPIES 1 Analytical Loboratory (RECORD COPI) 2 lndurtrlal Hygiene CI, Radlatlon Dept. 2 Water freatmnt Plant (Fw Wehr Samples

  5. PLEAEERUSH ANALYTICAL DA-~-A SHEET

    Office of Legacy Management (LM)

    ' PLEAEERUSH ANALYTICAL DA-~-A SHEET ' ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlON 1956 Industrial Hygiene or Medical Dept. 1. H.#~~Sample Nos. 3 --Date Collected~~by-CESS-.Route to CBS LocationTITANIUM Type of Sample airnalyzed for F Alpham Remarks NIAGARA pALI+S* N.Y. U Beta Bldg. 103 - furnace room - -NO, Ra Oil PH Be Th Sample No. Hour Sample Description I I I--- R ) T 1 Q I I I 7392 1100 GA Induction furnace area duri-nn ----l----- mDeriod;.02; 151 .3 while furnace was charged with UOT_-

  6. PRODUCTIOR"OF TRORI~JW~IETALIWES PROCESS F6R RB)IJCIRO T&Old 2 ':

    Office of Legacy Management (LM)

    PRODUCTIOR"OF TRORI~JW~IETALIWES PROCESS F6R RB)IJCIRO T&Old 2 ': am wm ..,. :I.::. ? ; \: :.:, .,, : ,. / 1. ..ri:,:,.:, :/ I 8yblBOLa PPaJPT i: >. ,,;.;~:,,; ,;.. !,., ,ip; ,,,:. ;., -. , ^ , . . 3 '>) ! .,:<;:,,..,. ; : :..,, ,,.+ -../ ,:,; I,:;?: ..: : ,, ,,: ; !. (' '; ::, Durine,~~~v%eit'to Amae &8Htate~Coliegd on Mar6h 4 and 2 to dl&ni& prinalpally~~asl~~prd~ess~~~1 also r&&&d wltlvDii 8. Wilhelm and Dr. D. Peterson of An~?e Iowa State College

  7. SITES ELIHlNAlED FRCil FUW' ~1WWk'l ffi LY

    Office of Legacy Management (LM)

    SITES ELIHlNAlED FRCil FUW' ~1WWk'l ffi LY Lfcfi0n 31, I?%7 STGTE m rtE!xm ICmFIED cm&B fi re3xf.H ROJECT TIM #% HER M JWDlCTICd Cf M W.&f&t ff NIF, Ml TtE FKILIIY If0 LICWSES TO WRE ffiDliXClIVE tt%iML. IVJ R&w mm IS h-m. STTE S#W MC&TED W P4DlOKTIVIN kmvi t+mi BkcTmam

  8. DOE/OR/07-2247&D1

    Office of Environmental Management (EM)

    f 8}.~11 Ohio Environmental Protection Agency Southeast District Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: PPPO-03-1335655-12 REMOVAL ACTION COMPLETION REPORT FOR THE X-I03 AUXILIARY OFFICE BUILDING AT THE PORTSMOUTH GASEOUS DIFFUSION PLANT, PIKETON, OHIO Enclosed for your review and concurrence, please find the Removal Action Completion Report for the X-J 03 Auxiliary Office Building at the Portsmouth Gaseous Diffusion Plant, Piketon, Ohio (DOE/PPPOI03-0223&Dl). This

  9. DOEIET5-0064

    Office of Environmental Management (EM)

    DOEIET5-0064 uc-z,11 Final Environmental lmpact (Final Statement to ERDA Statement 1545-Dl R(rcky Fhts Phnt slte Goldeh, Jeffetson Gounty, Golorado Ruth C. Clusen Assistant .Secretary for Environrnent U.S. DEPARTMENT OF ENERGY Washington, D,C. 20585 APRIL 1980 Volume 3 of 3 RESPONSES TO PUBLIC GOMMENTS Responsible Official ,// 4-*q, ll;{ru:l-r,. SUMMARY OF CONTENTS VOLUI'{E I Table of Contents List of Tables List of Figures Abbreviations, Symbols and Acronyns Glossary Metric to English

  10. Twenty years of sedimentary change and diagenesis, Qatar Peninsula, Arabian Gulf

    SciTech Connect (OSTI)

    Shinn, E.A.

    1988-02-01

    Re-examination in February 1986 of areas studied by the author in 1966 and 1967 revealed rapid rates of sedimentation and diagenesis along the east coast of the Qatar Peninsula. At Ras Um Sa on the north-east side of Qatar, a series of chenier-like beaches and curved spits is building southward under the influence of longshore currents. Beach and spit growth increasingly protects the shoreline and allows tidal flats to form in their lee. As these spits accrete, they become armored on their lagoonal side by beachrock formation. In the last 20 years a spit approximately 1/2 km long has grown, and beachrock has already armored its recurved lagoonal side. At Umm Said on the southeast side of Qatar, seawardly accreting barchan dunes composed of quartz sand have built a 40-km long, 10-km wide sabkha as thick as 30 m. Aerial and ground photographs show that certain dunes near the seaward edge of the sabkha have migrated into the sea and have contributed to shoreline accretion. The observed rate of dune migration suggests that within approximately 100 years the remaining quartz sands will be depleted and blown into the sea because there is no replenishment of the dune field. Subsequently, the area will revert to one of carbonate deposition. Fine-grained dolomite is presently precipitating in interstitial brines in the landwardmost portions of this unusual sabkha. In the geologic record, such a deposit would be an anomalous, porous and permeable, cross-bedded, linear, 30-m thick, dolomite-cemented sandstone body encased in carbonate sediments. A modern model such as the one at Umm Said can provide useful clues for determining the origin of similar deposits in ancient rocks.

  11. Assessment of hydrologic transport of radionuclides from the Gnome underground nuclear test site, New Mexico

    SciTech Connect (OSTI)

    Earman, S.; Chapman, J.; Pohlmann, K.; Andricevic, R.

    1996-09-01

    The U.S. Department of Energy (DOE) is operating an environmental restoration program to characterize, remediate, and close non-Nevada Test Site locations that were used for nuclear testing. Evaluation of radionuclide transport by groundwater from these sites is an important part of the preliminary site risk analysis. These evaluations are undertaken to allow prioritization of the test areas in terms of risk, provide a quantitative basis for discussions with regulators and the public about future work at the sites, and provide a framework for assessing data needs to be filled by site characterization. The Gnome site in southeastern New Mexico was the location of an underground detonation of a 3.5-kiloton nuclear device in 1961, and a hydrologic tracer test using radionuclides in 1963. The tracer test involved the injection of tritium, {sup 90}Sr, and {sup 137}Cs directly into the Culebra Dolomite, a nine to ten-meter-thick aquifer located approximately 150 in below land surface. The Gnome nuclear test was carried out in the Salado Formation, a thick salt deposit located 200 in below the Culebra. Because salt behaves plastically, the cavity created by the explosion is expected to close, and although there is no evidence that migration has actually occurred, it is assumed that radionuclides from the cavity are released into the overlying Culebra Dolomite during this closure process. Transport calculations were performed using the solute flux method, with input based on the limited data available for the site. Model results suggest that radionuclides may be present in concentrations exceeding drinking water regulations outside the drilling exclusion boundary established by DOE. Calculated mean tritium concentrations peak at values exceeding the U.S. Environmental Protection Agency drinking water standard of 20,000 pCi/L at distances of up to almost eight kilometers west of the nuclear test.

  12. Bridging the Gap between Chemical Flooding and Independent Oil Producers

    SciTech Connect (OSTI)

    Stan McCool; Tony Walton; Paul Whillhite; Mark Ballard; Miguel Rondon; Kaixu Song; Zhijun Liu; Shahab Ahmed; Peter Senior

    2012-03-31

    Ten Kanas oil reservoirs/leases were studied through geological and engineering analysis to assess the potential performance of chemical flooding to recover oil. Reservoirs/leases that have been efficiently waterflooded have the highest performance potential for chemical flooding. Laboratory work to identify efficient chemical systems and to test the oil recovery performance of the systems was the major effort of the project. Efficient chemical systems were identified for crude oils from nine of the reservoirs/leases. Oil recovery performance of the identified chemical systems in Berea sandstone rocks showed 90+ % recoveries of waterflood residual oil for seven crude oils. Oil recoveries increased with the amount of chemical injected. Recoveries were less in Indiana limestone cores. One formulation recovered 80% of the tertiary oil in the limestone rock. Geological studies for nine of the oil reservoirs are presented. Pleasant Prairie, Trembley, Vinland and Stewart Oilfields in Kansas were the most favorable of the studied reservoirs for a pilot chemical flood from geological considerations. Computer simulations of the performance of a laboratory coreflood were used to predict a field application of chemical flooding for the Trembley Oilfield. Estimates of field applications indicated chemical flooding is an economically viable technology for oil recovery.

  13. Manilla Bay 1, 1A, 1A sidetrack; success against all odds

    SciTech Connect (OSTI)

    Durkee, E.F.; Rillera, F.G. )

    1996-01-01

    The discovery of gas in Manila Bay is one of the more significant exploration discoveries in the Western Pacific in recent years. Within the Philippine Archipelago there is no better geographic or economic location to discover gas than at Manila Bay. Geologically, the well has proven that new concepts applied to old areas, in opposition to past beliefs and dogmas is still a valid way to find hydrocarbons. This is especially true re the western margin of the Central Valley of Luzon. New Venture reviewers (more than 100) were generally negative about the possibility of limestone objectives at this setting. The operators eventually drilled the prospect by themselves. The Manila Bay discovery well is on a large basement uplift with more than 2000 feet of vertical closure and 8,000 acres of areal closure at Miocene levels. The geological surprise was that the well drilled through a Pliocene Limestone (700 feet) charged with gas. An estimated in place resource of up to 2 TCF is possible. This is economically very significant for the Philippines as it is only 30 km from downtown Manila, a city of some 10 million people without any indigenous energy supply. Over-pressured fresh water sands induced drilling problems in the initial well MB-1AST and the deeper primary objectives in Middle to Lower Miocene, also predicted to be carbonates, were not reached. A second well to appraise the Pliocene and explore the deep zones will be drilled in early 1996.

  14. Manilla Bay 1, 1A, 1A sidetrack; success against all odds

    SciTech Connect (OSTI)

    Durkee, E.F.; Rillera, F.G.

    1996-12-31

    The discovery of gas in Manila Bay is one of the more significant exploration discoveries in the Western Pacific in recent years. Within the Philippine Archipelago there is no better geographic or economic location to discover gas than at Manila Bay. Geologically, the well has proven that new concepts applied to old areas, in opposition to past beliefs and dogmas is still a valid way to find hydrocarbons. This is especially true re the western margin of the Central Valley of Luzon. New Venture reviewers (more than 100) were generally negative about the possibility of limestone objectives at this setting. The operators eventually drilled the prospect by themselves. The Manila Bay discovery well is on a large basement uplift with more than 2000 feet of vertical closure and 8,000 acres of areal closure at Miocene levels. The geological surprise was that the well drilled through a Pliocene Limestone (700 feet) charged with gas. An estimated in place resource of up to 2 TCF is possible. This is economically very significant for the Philippines as it is only 30 km from downtown Manila, a city of some 10 million people without any indigenous energy supply. Over-pressured fresh water sands induced drilling problems in the initial well MB-1AST and the deeper primary objectives in Middle to Lower Miocene, also predicted to be carbonates, were not reached. A second well to appraise the Pliocene and explore the deep zones will be drilled in early 1996.

  15. Waste tires as auxiliary fuel for cement kilns

    SciTech Connect (OSTI)

    Dodds, J.

    1987-01-01

    The subject I have been asked to speak about is the utilization of scrap tires as an auxiliary fuel for cement kilns. My experience with scrap tires began five years ago when we performed a technical and economic evaluation for tire pyrolysis. I work for the Idaho National Engineering Laboratory which is supported by the Department of Energy. My interest in scrap tires continued; in 1984 the Department of Energy and the Portland Cement Association jointly sponsored a conference on the utilization of scrap tires in cement kilns. Most of my remarks today are based upon that conference along with some current information in the US. Mr. Sladek requested that I speak on the combustion process, the progress to date, and the factors that impede or encourage implementation of using scrap tires in cement kilns. For discussion purposes it would help if we had a common understanding of the cement manufacturing process. Cement is made by heating a mixture of finely ground limestone and silica from clay or sand to about 1450/degree/C in a large rotating kiln. The heat causes the limestone to decarbonate and subsequently react with the silica to form calcium silicates. 5 figs.

  16. Expansion of the commercial output of Estonian oil shale mining and processing

    SciTech Connect (OSTI)

    Fraiman, J.; Kuzmiv, I. [Estonian Oil Shale State Co., Jyhvi (Estonia). Scientific Research Center

    1996-09-01

    Economic and ecological preconditions are considered for the transition from monoproduct oil shale mining to polyproduct Estonian oil shale deposits. Underground water, limestone, and underground heat found in oil shale mines with small reserves can be operated for a long time using chambers left after oil shale extraction. The adjacent fields of the closed mines can be connected to the operations of the mines that are still working. Complex usage of natural resources of Estonian oil shale deposits is made possible owing to the unique features of its geology and technology. Oil shale seam development is carried out at shallow depths (40--70 m) in stable limestones and does not require expensive maintenance. Such natural resources as underground water, carbonate rocks, heat of rock mass, and underground chambers are opened by mining and are ready for utilization. Room-and-pillar mining does not disturb the surface, and worked oil shale and greenery waste heaps do not breach its ecology. Technical decisions and economic evaluation are presented for the complex utilization of natural resources in the boundaries of mine take of the ``Tammiku`` underground mine and the adjacent closed mine N2. Ten countries have already experienced industrial utilization of oil shale in small volumes for many years. Usually oil shale deposits are not notable for complex geology of the strata and are not deeply bedded. Thus complex utilization of quite extensive natural resources of Estonian oil shale deposits is of both scientific and practical interest.

  17. Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivity values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.

  18. Coolside waste management demonstration OCDO grant agreement No. CDO/D-902-9. Final report

    SciTech Connect (OSTI)

    Wu, M.; Winschel, R.A.

    1997-10-01

    The objectives of this project were to evaluate the potential utilization in road construction of wastes produced from the Coolside, LIMB (limestone injection multi-stage burner) and FBC (fluidized-bed combustion) processes, and to specify criteria for landfill disposal of waste from the Coolside process. These three processes are considered to be clean coal technologies. The Coolside process involves injecting an aqueous slurry of hydrated lime into the ductwork downstream of the air preheater in a coal-fired boiler. The hydrated lime captures sulfur dioxide from the flue gas producing anhydrous calcium sulfite and calcium sulfate, which are collected along with the unused hydrated lime and fly ash. The LIMB process involves injection of lime or hydrated lime directly into the furnace to capture sulfur dioxide. The waste consists principally of anhydrous calcium sulfate, lime, and fly ash. Both processes were demonstrated successfully at the Edgewater Station of Ohio Edison in Lorrain, OH, from 1989 to 1992. Circulating fluidized-bed combustion (FBC) is a commercial technology which combines steam generation with SO{sub 2} control by burning coal in a circulating bed of limestone. The waste, chemically similar to LIMB waste, is produced by bleed-off of the bed material and by collection of the flue dust. All three processes produce a dry solid waste, which must either be used or disposed of and managed to ensure environmental compliance and economic feasibility. The project was completed in June 1996.

  19. Flue gas desulfurization: Physicochemical and biotechnological approaches

    SciTech Connect (OSTI)

    Pandey, R.A.; Biswas, R.; Chakrabarti, T.; Devotta, S.

    2005-07-01

    Various flue gas desulfurization processes - physicochemical, biological, and chemobiological - for the reduction of emission of SO{sub 2} with recovery of an economic by-product have been reviewed. The physicochemical processes have been categorized as 'once-through' and 'regenerable.' The prominent once-through technologies include wet and dry scrubbing. The wet scrubbing technologies include wet limestone, lime-inhibited oxidation, limestone forced oxidation, and magnesium-enhanced lime and sodium scrubbing. The dry scrubbing constitutes lime spray drying, furnace sorbent injection, economizer sorbent injection, duct sorbent injection, HYPAS sorbent injection, and circulating fluidized bed treatment process. The regenerable wet and dry processes include the Wellman Lord's process, citrate process, sodium carbonate eutectic process, magnesium oxide process, amine process, aqueous ammonia process, Berglau Forchung's process, and Shell's process. Besides these, the recently developed technologies such as the COBRA process, the OSCAR process, and the emerging biotechnological and chemobiological processes are also discussed. A detailed outline of the chemistry, the advantages and disadvantages, and the future research and development needs for each of these commercially viable processes is also discussed.

  20. Rhythmic bedding patterns for locating structural features, Niobrara Formation, United States western interior

    SciTech Connect (OSTI)

    Laferriere, A.P.; Hattin, D.E.

    1989-05-01

    Milankovitch-type bedding cycles are well developed in the Upper Cretaceous Fort Hays Limestone Member, Niobrara Formation. These time-equivalent cycles can be correlated across much of Colorado, Kansas, and northeastern New Mexico by combining subsurface and outcrop data. Documentation of thickness variations within the regionally persistent Fort Hays bedding sequences furnishes a basis for fine-scale analysis of Late Cretaceous crustal movements within the eastern ramp region of the Western Interior foreland basin. Regional thickness changes in groups of shale-limestone couplets were correlated and mapped in outcrop and in the subsurface to locate structural elements that influenced Fort Hays deposition. In the Denver-Julesburg basin of Colorado and western Kansas, up to 6.1 m (20 ft) of thinning of the section occurs dominantly along northeastwardly trending belts formed during Late Cretaceous reactivation of the Transcontinental arch. Mapping of these small-scale thickness changes in the Fort Hays demonstrates that Cretaceous reactivation of the Transcontinental arch was not restricted to the northern part of the Denver-Julesburg basin. Additional structures may occur as far south as the Colorado-New Mexico border. A northwestwardly thinning trend is also apparent and may have resulted from increased compaction and diagenesis, reduction of sediment input during transgression, or from uplift in the vicinity of the Colorado Front Range. 8 figures.

  1. Making web annotations persistent over time

    SciTech Connect (OSTI)

    Sanderson, Robert; Van De Sompel, Herbert

    2010-01-01

    As Digital Libraries (DL) become more aligned with the web architecture, their functional components need to be fundamentally rethought in terms of URIs and HTTP. Annotation, a core scholarly activity enabled by many DL solutions, exhibits a clearly unacceptable characteristic when existing models are applied to the web: due to the representations of web resources changing over time, an annotation made about a web resource today may no longer be relevant to the representation that is served from that same resource tomorrow. We assume the existence of archived versions of resources, and combine the temporal features of the emerging Open Annotation data model with the capability offered by the Memento framework that allows seamless navigation from the URI of a resource to archived versions of that resource, and arrive at a solution that provides guarantees regarding the persistence of web annotations over time. More specifically, we provide theoretical solutions and proof-of-concept experimental evaluations for two problems: reconstructing an existing annotation so that the correct archived version is displayed for all resources involved in the annotation, and retrieving all annotations that involve a given archived version of a web resource.

  2. INTEGRATED GEOLOGIC-ENGINEERING MODEL FOR REEF AND CARBONATE SHOAL RESERVOIRS ASSOCIATED WITH PALEOHIGHS: UPPER JURASSIC SMACKOVER FORMATION, NORTHEASTERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2004-02-25

    The University of Alabama, in cooperation with Texas A&M University, McGill University, Longleaf Energy Group, Strago Petroleum Corporation, and Paramount Petroleum Company, has undertaken an integrated, interdisciplinary geoscientific and engineering research project. The project is designed to characterize and model reservoir architecture, pore systems and rock-fluid interactions at the pore to field scale in Upper Jurassic Smackover reef and carbonate shoal reservoirs associated with varying degrees of relief on pre-Mesozoic basement paleohighs in the northeastern Gulf of Mexico. The project effort includes the prediction of fluid flow in carbonate reservoirs through reservoir simulation modeling which utilizes geologic reservoir characterization and modeling and the prediction of carbonate reservoir architecture, heterogeneity and quality through seismic imaging. The primary goal of the project is to increase the profitability, producibility and efficiency of recovery of oil from existing and undiscovered Upper Jurassic fields characterized by reef and carbonate shoals associated with pre-Mesozoic basement paleohighs. Geoscientific reservoir property, geophysical seismic attribute, petrophysical property, and engineering property characterization has shown that reef (thrombolite) and shoal reservoir lithofacies developed on the flanks of high-relief crystalline basement paleohighs (Vocation Field example) and on the crest and flanks of low-relief crystalline basement paleohighs (Appleton Field example). The reef thrombolite lithofacies have higher reservoir quality than the shoal lithofacies due to overall higher permeabilities and greater interconnectivity. Thrombolite dolostone flow units, which are dominated by dolomite intercrystalline and vuggy pores, are characterized by a pore system comprised of a higher percentage of large-sized pores and larger pore throats. Rock-fluid interactions (diagenesis) studies have shown that although the primary control on reservoir architecture and geographic distribution of Smackover reservoirs is the fabric and texture of the depositional lithofacies, diagenesis (chiefly dolomitization) is a significant factor that preserves and enhances reservoir quality. The evaporative pumping mechanism is favored to explain the dolomitization of the thrombolite doloboundstone and dolostone reservoir flow units at Appleton and Vocation Fields. Geologic modeling, reservoir simulation, and the testing and applying the resulting integrated geologic-engineering models have shown that little oil remains to be recovered at Appleton Field and a significant amount of oil remains to be recovered at Vocation Field through a strategic infill drilling program. The drive mechanisms for primary production in Appleton and Vocation Fields remain effective; therefore, the initiation of a pressure maintenance program or enhanced recovery project is not required at this time. The integrated geologic-engineering model developed for a low-relief paleohigh (Appleton Field) was tested for three scenarios involving the variables of present-day structural elevation and the presence/absence of potential reef thrombolite lithofacies. In each case, the predictions based upon the model were correct. From this modeling, the characteristics of the ideal prospect in the basement ridge play include a low-relief paleohigh associated with dendroidal/chaotic thrombolite doloboundstone and dolostone that has sufficient present-day structural relief so that these carbonates rest above the oil-water contact. Such a prospect was identified from the modeling, and it is located northwest of well Permit No. 3854B (Appleton Field) and south of well No. Permit No.11030B (Northwest Appleton Field).

  3. Role of mag-enhanced lime scrubbing in the FGD industry

    SciTech Connect (OSTI)

    Babu, M.; College, J.; Smith, K.; Stowe, D.H.

    1997-12-31

    The mag-enhanced lime scrubbing process has been in commercial use in the US since the early 1970`s. At present over 14,000 MW of coal-fired utility plants in the US burning high sulfur coal (2.5--4.0% S) utilize this process with an excellent emission compliance and cost performance record to date. Dravo Lime Company (DLC) being the largest supplier of lime to this industry continues to conduct extensive R and D in this area and provides technical support service to these users. The success of the mag-enhanced lime process is largely attributed to the dual alkali effect of the Mg-Ca ions with a very distinct role for the highly soluble Mg ion in the scrubber liquor. It is well known that the high solubility of the magnesium ions provides alkalinities in the scrubbing liquor far in excess of the limestone systems. As a result of this high alkalinity liquor the mag-lime scrubbers need a much lower liquid to gas ratio, have lower scrubber pressure drop, consume lower parasitic load, are able to handle very high inlet SO{sub 2} concentrations, show little scaling tendency, etc. The scrubbers, recirculation pumps, piping, etc., are much smaller and the systems have lower capital and operating costs over comparable limestone systems. This system typically has a high availability and the process is less severe mechanically on the scrubber, pumps, nozzles, piping than comparable limestone processes. DLC`s patented ThioClear{reg_sign} process is an improvement over the conventional Thiosorbic process in use today. The ThioClear process while providing all of the advantages of the Thiosorbic process uses a nearly clear liquor to scrub and can use an innovative Horizontal Scrubber at gas velocities of up to 7.62--9.14 m/s (25--30 FPS). This process produces an excellent quality gypsum for wall board, cement or other applications and can also produce valuable Mg(OH){sub 2} as by-product. This paper discusses the merits of Thiosorbic/ThioClear processes, innovations with respect to the scrubber design, cost advantages and the freedom to choose a lower cost higher S coal while easily meeting or exceeding the regulatory requirements in the industry.

  4. Vulnerability of Karangkates dams area by means of zero crossing analysis of data magnetic

    SciTech Connect (OSTI)

    Sunaryo, E-mail: sunaryo.geofis.ub@gmail.com; Susilo, Adi

    2015-04-24

    Study with entitled Vulnerability Karangkates Dam Area By Means of Zero Crossing Analysis of Data Magnetic has been done. The study was aimed to obtain information on the vulnerability of two parts area of Karangkates dams, i.e. Lahor dam which was inaugurated in 1977 and Sutami dam inaugurated in 1981. Three important things reasons for this study are: 1). The dam age was 36 years old for Lahor dam and 32 years old for Sutami dam, 2). Geologically, the location of the dams are closed together to the Pohgajih local shear fault, Selorejo local fault, and Selorejo limestone-andesite rocks contact plane, and 3). Karangkates dams is one of the important Hydro Power Plant PLTA with the generating power of about 400 million KWH per year from a total of about 29.373MW installed in Indonesia. Geographically, the magnetic data acquisition was conducted at coordinates (112.4149oE;-8.2028oS) to (112.4839oE;-8.0989oS) by using Proton Precession Magnetometer G-856. Magnetic Data acquisition was conducted in the radial direction from the dams with diameter of about 10 km and the distance between the measurements about 500m. The magnetic data acquisition obtained the distribution of total magnetic field value in the range of 45800 nT to 44450 nT. Residual anomalies obtained by doing some corrections, including diurnal correction, International Geomagnetic Reference Field (IGRF) correction, and reductions so carried out the distribution of the total magnetic field value in the range of -650 nT to 700 nT. Based on the residual anomalies, indicate the presence of 2 zones of closed closures dipole pairs at located in the west of the Sutami dam and the northwest of the Lahor dam from 5 total zones. Overlapping on the local geological map indicated the lineament of zero crossing patterns in the contour of residual anomaly contour with the Pohgajih shear fault where located at about 4 km to the west of the Sutami dam approximately and andesite-limestone rocks contact where located at about 6 km to the west of the Lahor dam approximately. These shown a possible of vulnerability on geohazards at the west zone of the Karangkates (Lahor-Sutami) dams area if there are triggers by the vibration (earthquake) on the Pohgajih shear fault, andesite-limestone contact plane, and instability rocks on two zones of closed closure dipole pairs area. Reality, on the location of the study shown some local landslide at the several locations and the main road that need considering for disaster mitigation.

  5. High-power radio frequency pulse generation and extration based on wakefield excited by an intense charged particle beam in dielectric-loaded waveguides.

    SciTech Connect (OSTI)

    Gao, F.; High Energy Physics; Illinois Inst. of Tech

    2009-07-24

    Power extraction using a dielectric-loaded (DL) waveguide is a way to generate high-power radio frequency (RF) waves for future particle accelerators, especially for two-beam-acceleration. In a two-beam-acceleration scheme, a low-energy, high-current particle beam is passed through a deceleration section of waveguide (decelerator), where the power from the beam is partially transferred to trailing electromagnetic waves (wakefields); then with a properly designed RF output coupler, the power generated in the decelerator is extracted to an output waveguide, where finally the power can be transmitted and used to accelerate another usually high-energy low-current beam. The decelerator, together with the RF output coupler, is called a power extractor. At Argonne Wakefield Accelerator (AWA), we designed a 7.8GHz power extractor with a circular DL waveguide and tested it with single electron bunches and bunch trains. The output RF frequency (7.8GHz) is the sixth harmonic of the operational frequency (1.3GHz) of the electron gun and the linac at AWA. In single bunch excitation, a 1.7ns RF pulse with 30MW of power was generated by a single 66nC electron bunch passing through the decelerator. In subsequent experiments, by employing different splitting-recombining optics for the photoinjector laser, electron bunch trains were generated and thus longer RF pulses could be successfully generated and extracted. In 16-bunch experiments, 10ns and 22ns RF pulses have been generated and extracted; and in 4-bunch experiments, the maximum power generated was 44MW with 40MW extracted. A 26GHz DL power extractor has also been designed to test this technique in the millimeter-wave range. A power level of 148MW is expected to be generated by a bunch train with a bunch spacing of 769ps and bunch charges of 20nC each. The arrangement for the experiment is illustrated in a diagram. Higher-order-mode (HOM) power extraction has also been explored in a dual-frequency design. By using a bunch train with a bunch spacing of 769ps and bunch charges of 50nC each, 90.4MW and 8.68MW of extracted power levels are expected to be reached at 20.8GHz and 35.1GHz, respectively. In order to improve efficiency in HOM power extraction, a novel technique has been proposed to suppress unintended modes.

  6. Mineral-Surfactant Interactions for Minimum Reagents Precipitation and Adsorption for Improved Oil Recovery

    SciTech Connect (OSTI)

    P. Somasundaran

    2008-09-20

    Chemical EOR can be an effective method for increasing oil recovery and reducing the amount of produced water; however, reservoir fluids are chemically complex and may react adversely to the polymers and surfactants injected into the reservoir. While a major goal is to alter rock wettability and interfacial tension between oil and water, rock-fluid and fluid-fluid interactions must be understood and controlled to minimize reagent loss, maximize recovery and mitigate costly failures. The overall objective of this project was to elucidate the mechanisms of interactions between polymers/surfactants and the mineral surfaces responsible for determining the chemical loss due to adsorption and precipitation in EOR processes. The role of dissolved inorganic species that are dependent on the mineralogy is investigated with respect to their effects on adsorption. Adsorption, wettability and interfacial tension are studied with the aim to control chemical losses, the ultimate goal being to devise schemes to develop guidelines for surfactant and polymer selection in EOR. The adsorption behavior of mixed polymer/surfactant and surfactant/surfactant systems on typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) was correlated to their molecular structures, intermolecular interactions and the solution conditions such as pH and/or salinity. Predictive models as well as general guidelines for the use of polymer/surfactant surfactant/surfactant system in EOR have been developed The following tasks have been completed under the scope of the project: (1) Mineral characterization, in terms of SEM, BET, size, surface charge, and point zero charge. (2) Study of the interactions among typical reservoir minerals (quartz, alumina, calcite, dolomite, kaolinite, gypsum, pyrite, etc.) and surfactants and/or polymers in terms of adsorption properties that include both macroscopic (adsorption density, wettability) and microscopic (orientation/conformation of the adsorbed layers), as well as precipitation/abstraction characteristics. (3) Investigation of the role of dissolved species, especially multivalent ions, on interactions between reservoir minerals and surfactants and/or polymers leading to surfactant precipitation or activated adsorption. (4) Solution behavior tests--surface tension, interaction, ultra filtration, and other tests. (5) Surfactant-mineral interactions relative to adsorption, wettability, and electrophoresis. (6) Work on the effects of multivalent ions, pH, temperature, salinity, and mixing ratio on the adsorption. Developments of adsorption models to explain interactions between surfactants/polymers/minerals. (7) General guidelines for the use of certain surfactants, polymers and their mixtures in micelle flooding processes.

  7. Installation restoration program: Hydrologic measurements with an estimated hydrologic budget for the Joliet Army Ammunition Plant, Joliet, Illinois. [Contains maps of monitoring well locations, topography and hydrologic basins

    SciTech Connect (OSTI)

    Diodato, D.M.; Cho, H.E.; Sundell, R.C.

    1991-07-01

    Hydrologic data were gathered from the 36.8-mi{sup 2} Joliet Army Ammunition Plant (JAAP) located in Joliet, Illinois. Surface water levels were measured continuously, and groundwater levels were measured monthly. The resulting information was entered into a database that could be used as part of numerical flow model validation for the site. Deep sandstone aquifers supply much of the water in the JAAP region. These aquifers are successively overlain by confining shales and a dolomite aquifer of Silurian age. This last unit is unconformably overlain by Pleistocene glacial tills and outwash sand and gravel. Groundwater levels in the shallow glacial system fluctuate widely, with one well completed in an upland fluctuating more than 17 ft during the study period. The response to groundwater recharge in the underlying Silurian dolomite is slower. In the upland recharge areas, increased groundwater levels were observed; in the lowland discharge areas, groundwater levels decreased during the study period. The decreases are postulated to be a lag effect related to a 1988 drought. These observations show that fluid at the JAAP is not steady-state, either on a monthly or an annual basis. Hydrologic budgets were estimated for the two principal surface water basins at the JAAP site. These basins account for 70% of the facility's total land area. Meteorological data collected at a nearby dam show that total measured precipitation was 31.45 in. and total calculated evapotranspiration was 23.09 in. for the study period. The change in surface water storage was assumed to be zero for the annual budget for each basin. The change in groundwater storage was calculated to be 0.12 in. for the Grant Creek basin and 0. 26 in. for the Prairie Creek basin. Runoff was 7.02 in. and 7.51 in. for the Grant Creek and Prairie Creek basins, respectively. The underflow to the deep hydrogeologic system in the Grant Creek basin was calculated to be negligible. 12 refs., 17 figs., 15 tabs.

  8. Basic Data Report for Drillholes on the H-19 Hydropad (Waste Isolation Pilot Plant--WIPP)

    SciTech Connect (OSTI)

    Mercer, J.W.; Cole, D.L.; Holt, R.M.

    1998-10-09

    Seven holes were drilled and wells (H-19b0, H-19b2, H-19b3, H-19b4, H-19b5, H-19b6, and H-19b7) were constructed on the H-19 hydropad to conduct field activities in support of the Culebra Transport Program. These wells were drilled and completed on the Waste Isolation Pilot Plant (WIPP) site during February to September 1995. An eighth hole, H-19b1, was drilled but had to be abandoned before the target depth was reached because of adverse hole conditions. The geologic units penetrated at the H-19 location include surficial deposits of Holocene age, rocks from the Dockum Group of Upper Triassic age, the Dewey Lake Redbeds, and Rustler Formation of the Permian age. The Rustler Formation has been further divided into five informal members which include the Forty-niner Member, Magenta Member, Tamarisk Member, Culebra Dolomite Member, and an unnamed lower member. The Rustler Formation, particularly the Culebra Dolomite Member, is considered critical for hydrologic site characterization. The Culebra is the most transmissive saturated unit above the WIPP repository and, as such, is considered to be the most likely pathway for radionuclide transport to the accessible environment in the unlikely event the repository is breached. Seven cores from the Culebra were recovered during drilling activities at the H-19 hydropad and detailed descriptions of these cores were made. On the basis of geologic descriptions, four hydrostratigraphic units were identified in the Culebra cores and were correlated with the mapping units from the WFP air intake shaft. The entire length of H-19b1 was cored and was described in detail. During coring of H-19b1, moisture was encountered in the upper part of the Dewey Lake Redbeds. A 41-ft-thick section of this core was selected for detailed description to qualify the geologic conditions related to perched water in the upper Dewey Lake. In addition to cuttings and core, a suite of geophysical logs run on the drillholes was used to identify and correlate different lithologies among the seven wells.

  9. Comparison of the Wymark CO2 Reservoir with the Midale Beds at the Weyburn CO2 Injection Project

    SciTech Connect (OSTI)

    Ryerson, F; Johnson, J

    2010-11-22

    The Devonian carbonates of the Duperow Formation on the western flank of the Williston Basin in southwest Saskatchewan contain natural accumulations of CO{sub 2}, and may have done so for as long as 50 m.y. in the views of some investigations. These carbonate sediments are characterized by a succession of carbonate cycles capped by anhydrite-rich evaporites that are thought to act as seals to fluid migration. The Weyburn CO{sub 2} injection site lies 400 km to the east in a series of Mississippian carbonates that were deposited in a similar depositional environment. That natural CO{sub 2} can be stored long-term within carbonate strata has motivated the investigation of the Duperow rocks as a potential natural analogue to storage of anthropogenic CO{sub 2} that may ultimately provide additional confidence for CO{sub 2} sequestration in carbonate lithologies. For the Duperow strata to represent a legitimate analog for Midale injection and storage, the similarity in lithofacies, whole rock compositions, mineral compositions and porosity with the Midale Beds must be established. Previous workers have demonstrated the similarity of the lithofacies at both sites. Here we compare the whole rock compositions, mineralogy and mineral compositions. The major mineral phases at both locales are calcite, dolomite and anhydrite. In addition, accessory pyrite, fluorite and celestine are also observed. The distribution of porosity in the Midale Vuggy units is virtually identical to that of the Duperow Formation, but the Marly units of the Midale have significantly higher porosity. The Duperow Formation is topped by the Dinesmore evaporite that is particularly rich in anhydrite, and often contains authigenic K-feldspar. The chemistry of dolomite and calcite from the two localities also overlaps. Silicate minerals are in low abundance within the analyzed Duperow samples, < 3 wt% on a normative basis, with quartz the only phase identifiable in x-ray diffraction patterns. The Midale Beds contain significantly higher silica/silicate concentrations, but the silicate minerals observed, K-feldspar and quartz, are unlikely to participate in carbonate mineral precipitation due to the absence of alkaline earths. Hence, physical and solution trapping are likely to be the primary trapping mechanisms at both sites. Given the similarity of mineral constituents, whole rock and mineral chemistry, reactive transport models developed for the Weyburn site should also be applicable to the Duperow lithologies.

  10. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO42H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~814 ?g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  11. GEOCHEMICAL INVESTIGATIONS OF CO?-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO?), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO? emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO?. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO? without the potential for the release of harmful contaminants liberated by the reaction between CO?-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (91019860 kPa [13201430 psi] and 3242C [90 108F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO? as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO? injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO? and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  12. Novel CO2 Foam Concepts and Injection Schemes for Improving CO2 Sweep Efficiency in Sandstone and Carbonate Hydrocarbon Formations

    SciTech Connect (OSTI)

    Nguyen, Quoc; Hirasaki, George; Johnston, Keith

    2015-02-05

    We explored cationic, nonionic and zwitterionic surfactants to identify candidates that have the potential to satisfy all the key requirements for CO2 foams in EOR. We have examined the formation, texture, rheology and stability of CO2 foams as a function of the surfactant structure and formulation variables including temperature, pressure, water/CO2 ratio, surfactant concentration, salinity and concentration of oil. Furthermore, the partitioning of surfactants between oil and water as well as CO2 and water was examined in conjunction with adsorption measurements on limestone by the Hirasaki lab to develop strategies to optimize the transport of surfactants in reservoirs.

  13. Inversion Breakup in Small Rocky Mountain and Alpine Basins

    SciTech Connect (OSTI)

    Whiteman, Charles D.; Pospichal, Bernhard; Eisenbach, Stefan; Weihs, P.; Clements, Craig B.; Steinacker, Reinhold; Mursch-Radlgruber, Erich; Dorninger, Manfred

    2004-08-01

    Comparisons are made between the post-sunrise breakup of temperature inversions in two similar closed basins in quite different climate settings, one in the eastern Alps and one in the Rocky Mountains. The small, high-altitude, limestone sinkholes have both experienced extreme temperature minima below -50C. On undisturbed clear nights, temperature inversions reach to 120 m heights in both sinkholes, but are much stronger in the drier Rocky Mountain basin (24K versus 13K). Inversion destruction takes place 2.6 to 3 hours after sunrise and is accomplished primarily by subsidence warming associated with the removal of air from the base of the inversion by the upslope flows that develop over the sidewalls. Differences in inversion strengths and post-sunrise heating rates are caused by differences in the surface energy budget, with drier soil and a higher sensible heat flux in the Rocky Mountain sinkhole.

  14. Environmental monitoring for the DOE coolside and LIMB demonstration extension projects. Final report, May--August 1991

    SciTech Connect (OSTI)

    White, T.; Contos, L.; Adams, L.

    1992-03-01

    The purpose of this document is to present environmental monitoring data collected during the US Department of Energy Limestone Injection Multistage Burner (DOE LIMB) Demonstration Project Extension at the Ohio Edison Edgewater Generating Station in Lorain, Ohio. The DOE project is an extension of the US Environmental Protection Agency`s (EPA`s) original LIMB Demonstration. The program is operated nuclear DOE`s Clean Coal Technology Program of ``emerging clean coal technologies`` under the categories of ``in boiler control of oxides of sulfur and nitrogen`` as well as ``post-combustion clean-up.`` The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators (ESPs).

  15. Environmental monitoring for the DOE coolside and LIMB demonstration extension projects

    SciTech Connect (OSTI)

    White, T.; Contos, L.; Adams, L. )

    1992-03-01

    The purpose of this document is to present environmental monitoring data collected during the US Department of Energy Limestone Injection Multistage Burner (DOE LIMB) Demonstration Project Extension at the Ohio Edison Edgewater Generating Station in Lorain, Ohio. The DOE project is an extension of the US Environmental Protection Agency's (EPA's) original LIMB Demonstration. The program is operated nuclear DOE's Clean Coal Technology Program of emerging clean coal technologies'' under the categories of in boiler control of oxides of sulfur and nitrogen'' as well as post-combustion clean-up.'' The objective of the LIMB program is to demonstrate the sulfur dioxide (SO{sub 2}) and nitrogen oxide (NO{sub x}) emission reduction capabilities of the LIMB system. The LIMB system is a retrofit technology to be used for existing coal-fired boilers equipped with electrostatic precipitators (ESPs).

  16. Process for recovery of aluminum from carbonaceous waste products

    SciTech Connect (OSTI)

    Kapolyi, L.

    1984-03-13

    A carbonaceous waste product, preferably containing 30 to 60% mineral substances, 35 to 55% carbonaceous materials, 5 to 20% water, and having a calorific value of 2,000 to 3,500 k cal/kg is fired to produce thermal energy and a combustion residue. The residue is adjusted, if necessary, by addition of mineral containing additives so that it contains 15 to 50% alumina, 15 to 20% silica and 13 to 45% other oxides (mainly iron oxide, manganese oxide and calcium oxide). Sufficient limestone is added to produce a mixture containing 1.8 to 2.2 moles of calcium oxide per mole of silica and 1.1 to 1.3 moles of calcium oxide per mole of alumina. The mixture is then sintered. The total energy requirements of the sintering step are supplied by the energy generated in the firing step. Useful products such as cement and cast stone can be produced from the sintered product.

  17. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, OH)

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  18. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, Deborah A. (Canfield, OH); Farthing, George A. (Washington Township, Stark County, OH)

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  19. Procedures control total mud losses while drilling in deep water

    SciTech Connect (OSTI)

    Dewar, J. ); Halkett, D. )

    1993-11-01

    In the deepwater (830-1,000 m) drilling program offshore Philippines, reefal limestones were encountered in which total mud losses could be expected because of the presence of large fractures. The danger was that a sudden drop in hydrostatic head (resulting from the losses) could allow any natural gas to enter the well bore quickly. The gas could then migrate up the well bore and form hydrates in the blowout preventers (BOPs). Once hydrates form, they are difficult to remove and can make a BOP stack inoperable. To combat this potential problem, containment procedures were developed to cope with these fluid losses. The philosophy behind the procedures was to prevent hydrocarbons from entering the well bore and, if they did enter, to ensure that they did not move up the well bore and into the riser. Additionally, procedures were developed to allow drilling to continue during the losses and the curing of losses.

  20. Pre-Feasibility Analysis of Pellet Manufacturing on the Former Loring Air Force Base Site. A Study Prepared in Partnership with the Environmental Protection Agency for the RE-Powering America's Land Initiative: Siting Renewable Energy on Potentially Contaminated Land and Mine Sites

    SciTech Connect (OSTI)

    Hunsberger, R.; Mosey, G.

    2014-04-01

    The U.S. Environmental Protection Agency (EPA) Office of Solid Waste and Emergency Response, in accordance with the RE-Powering America's Lands initiative, engaged the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) to conduct feasibility studies to assess the viability of developing renewable energy generating facilities on contaminated sites. This site, in Limestone, Maine -- formerly the location of the Loring Air Force Base but now owned by the Aroostook Band of Micmac -- was selected for the potential to produce heating pellets from woody feedstock. Biomass was chosen as the renewable energy resource to evaluate based on abundant woody-biomass resources available in the area. NREL also evaluates potential savings from converting existing Micmac property from oil-fired heating to pellet heating.

  1. Process for generating electricity in a pressurized fluidized-bed combustor system

    DOE Patents [OSTI]

    Kasper, Stanley (Pittsburgh, PA)

    1991-01-01

    A process and apparatus for generating electricity using a gas turbine as part of a pressurized fluidized-bed combustor system wherein coal is fed as a fuel in a slurry in which other constituents, including a sulfur sorbent such as limestone, are added. The coal is combusted with air in a pressurized combustion chamber wherein most of the residual sulfur in the coal is captured by the sulfur sorbent. After particulates are removed from the flue gas, the gas expands in a turbine, thereby generating electric power. The spent flue gas is cooled by heat exchange with system combustion air and/or system liquid streams, and the condensate is returned to the feed slurry.

  2. The EPRI Laboratory experiments at ANL. [Vaporization of core-concrete mixtures

    SciTech Connect (OSTI)

    Roche, M.F.; Settle, J.L.; Leibowitz, L.; Johnson, C.E.; Ritzman, R.L.

    1987-10-28

    The vaporization of core-concrete mixtures is being measured using a transpiration method. Mixtures of stainless steel, concrete (limestone or basaltic) and urania (doped with La/sub 2/O/sub 3/, SrO, BaO, and ZrO/sub 2/) are vaporized at 2150 - 2400 K from a zirconia crucible into flowing He - 6% H/sub 2/ gas. Up to 600 ppM H/sub 2/O is added to the gas to fix the partial molar free energy of oxygen in the range -420 kJ to -550 kJ. The fraction of the sample that is vaporized is determined by weight change and by chemical analyses on the condensates that are collected in an Mo condenser tube. The results are being used to test the thermodynemic data base and the underlying assumptions of computer codes used for prediction of release during the severe accident. 13 refs., 2 tabs.

  3. Soil stabilization using oil-shale solid waste

    SciTech Connect (OSTI)

    Turner, J.P. (Univ. of Wyoming, Laramie, WY (United States). Dept. of Civil and Archeological Engineering)

    1994-04-01

    Oil-shale solid wastes are evaluated for use as soil stabilizers. A laboratory study consisted of the following tests on compacted samples of soil treated with water and spent oil shale: unconfined compressive strength, moisture-density relationships, wet-dry and freeze-thaw durability, and resilient modulus. Significant increases in strength, durability, and resilient modulus were obtained by treating a silty sand with combusted western oil shale. Moderate increases in durability and resilient modulus were obtained by treating a highly plastic clay with combusted western oil shale. Solid waste from eastern oil shale appears to be feasible for soil stabilization only if limestone is added during combustion. Testing methods, results, and recommendations for mix design of spent shale-stabilized pavement subgrades are presented and the mechanisms of spent-shale cementation are discussed.

  4. Utilization of Estonian oil shale at power plants

    SciTech Connect (OSTI)

    Ots, A. [Tallin Technical Univ. (Estonia). Thermal Engineering Department

    1996-12-31

    Estonian oil shale belongs to the carbonate class and is characterized as a solid fuel with very high mineral matter content (60--70% in dry mass), moderate moisture content (9--12%) and low heating value (LHV 8--10 MJ/kg). Estonian oil shale deposits lie in layers interlacing mineral stratas. The main constituent in mineral stratas is limestone. Organic matter is joined with sandy-clay minerals in shale layers. Estonian oil shale at power plants with total capacity of 3060 MW{sub e} is utilized in pulverized form. Oil shale utilization as fuel, with high calcium oxide and alkali metal content, at power plants is connected with intensive fouling, high temperature corrosion and wear of steam boiler`s heat transfer surfaces. Utilization of Estonian oil shale is also associated with ash residue use in national economy and as absorbent for flue gas desulfurization system.

  5. Implications of the Clean Air Act acid rain title on industrial boilers

    SciTech Connect (OSTI)

    Maibodi, M. )

    1991-11-01

    This paper discusses the impacts of the 1990 Clean Air Act Amendments related to acid rain controls, as they apply to industrial boilers. Emphasis is placed on explaining the Title IV provisions of the Amendments that permit nonutility sources to participate in the SO{sub 2} allowance system. The allowance system, as it pertains to industrial boiler operators, is described, and the opportunities for operators to trade and/or sell SO{sub 2} emission credits is discussed. The paper also reviews flue gas desulfurization system technologies available for industrial boiler operators who may choose to participate in the system. Furnace sorbent injection, advanced silicate process, lime spray drying, dry sorbent injection, and limestone scrubbing are described, including statements of their SO{sub 2} removing capability, commercial status, and costs. Capital costs, levelized costs and cost-effectiveness are presented for these technologies.

  6. Integrated Air Pollution Control System (IAPCS), Executable Model and Source Model (version 4. 0) (for microcomputers). Model-Simulation

    SciTech Connect (OSTI)

    Not Available

    1990-10-29

    The Integrated Air Pollution Control System (IAPCS) Cost Model is an IBM PC cost model that can be used to estimate the cost of installing SO2, NOx, and particulate matter control systems at coal-fired utility electric generating facilities. The model integrates various combinations of the following technologies: physical coal cleaning, coal switching, overfire air/low NOx burners, natural gas reburning, LIMB, ADVACATE, electrostatic precipitator, fabric filter, gas conditioning, wet lime or limestone FGD, lime spray drying/duct spray drying, dry sorbent injection, pressurized fluidized bed combustion, integrated gasification combined cycle, and pulverized coal burning boiler. The model generates capital, annualized, and unitized pollutant removal costs in either constant or current dollars for any year.

  7. Integrated Air Pollution Control System (IAPCS), Executable Model (Version 4. 0) (for microcomputers). Model-Simulation

    SciTech Connect (OSTI)

    Not Available

    1990-10-29

    The Integrated Air Pollution Control System (IAPCS) Cost Model is an IBM PC cost model that can be used to estimate the cost of installing SO2, NOx, and particulate matter control systems at coal-fired utility electric generating facilities. The model integrates various combinations of the following technologies: physical coal cleaning, coal switching, overfire air/low NOx burners, natural gas reburning, LIMB, ADVACATE, electrostatic precipitator, fabric filter, gas conditioning, wet lime or limestone FGD, lime spray drying/duct spray drying, dry sorbent injection, pressurized fluidized bed combustion, integrated gasification combined cycle, and pulverized coal burning boiler. The model generates capital, annualized, and unitized pollutant removal costs in either constant or current dollars for any year.

  8. Experimental investigations of long-term interactions of molten UO/sub 2/ with MgO and concrete at Argonne National Laboratory. [LMFBR

    SciTech Connect (OSTI)

    Stein, R.P.; Farhadieh, R.; Pedersen, D.R.; Gunther, W.H.; Purviance, R.T.

    1982-01-01

    Experimental work at Argonne is being performed to investigate the long-term molten-core-debris retention capability of the ex-vessel cavity following a postulated meltdown accident. The eventual objective of the work is to determine if normal structural material (concrete) or a specifically selected sacrificial material (MgO) located in the ex-vessel cavity region can effectively contain molten core debris. The materials under investigation at ANL are various types of concrete (limestone, basalt and magnetite) and commercially-available MgO brick. Results are presented of the status of real material experimental investigation at ANL into (1) molten UO/sub 2/ pool heat transfer, (2) long-term molten UO/sub 2/ penetration into concrete and (3) long-term molten UO/sub 2/ penetration into refractory substrates. The decay heating in the fuel has been simulated by direct electrical heating permitting the study of the long-term interaction.

  9. IDENTIFYING ROOF FALL PREDICTORS USING FUZZY CLASSIFICATION

    SciTech Connect (OSTI)

    Bertoncini, C. A.; Hinders, M. K.

    2010-02-22

    Microseismic monitoring involves placing geophones on the rock surfaces of a mine to record seismic activity. Classification of microseismic mine data can be used to predict seismic events in a mine to mitigate mining hazards, such as roof falls, where properly bolting and bracing the roof is often an insufficient method of preventing weak roofs from destabilizing. In this study, six months of recorded acoustic waveforms from microseismic monitoring in a Pennsylvania limestone mine were analyzed using classification techniques to predict roof falls. Fuzzy classification using features selected for computational ease was applied on the mine data. Both large roof fall events could be predicted using a Roof Fall Index (RFI) metric calculated from the results of the fuzzy classification. RFI was successfully used to resolve the two significant roof fall events and predicted both events by at least 15 hours before visual signs of the roof falls were evident.

  10. (Relative mobilities and transport mechanisms of trace elements during contact metamorphism of carbonate rocks). Progress report

    SciTech Connect (OSTI)

    1980-01-01

    The main objective of this study is to investigate the relative mobilities and transport mechanisms of major, minor, and trace elements during the contact metamorphism of carbonate rocks. The large contrasts in chemical potentials of SiO/sub 2/, Al/sub 2/O/sub 3/, and CaO across a granitic pluton-limestone contact may induce metasomatism. In addition, rare earth and transition metal elements may act as tracers, and their redistribution during metamorphism may record convective cooling processes. The results of this study may have an application toward the problem of radioactive waste disposal and the degree to which radioactive nuclides may be expected to migrate during geologically significant periods of time.

  11. A comparison of {sup 137}Cs radioactivity in localized evergreen and deciduous plant species

    SciTech Connect (OSTI)

    Rangel, R.C.

    1996-05-01

    A vegetation study at the Comanche Peak Steam Electric Station (CPSES) near Glen Rose, Texas was conducted in 1991 and 1992. The CPSES is a commercial nuclear power plant owned and operated by Texas Utilities Electric of Dallas, Texas. The US Nuclear Regulatory Commission (USNRC) requires the CPSES to routinely sample broadleaf vegetation in place of milk samples. Few commercial dairies exist in the vicinity. Broadleaf tree species are scarce because the climate and local limestone geology have produced a dry rolling hill topography. An evergreen juniper is the dominant tree species. Few broadleaves during the winter season have hindered year-round sampling. This study compares the environmental {sup 137}Cs concentrations between broadleaf and evergreen foliage at CPSES. Soil {sup 137}Cs concentrations from each vegetation location were also compared to the foliage {sup 137}Cs concentrations. The study`s objective was to determine if the deciduous and evergreen vegetation {sup 137}Cs concentrations are statistically the same.

  12. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  13. Flue gas desulfurization method and apparatus

    DOE Patents [OSTI]

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  14. ''A ground water resources study of a Pacific Ocean atoll - Tarawa, Gilbert Islands,'' by J. W. Lloyd, J. C. Miles, G. R. Chessmand, and S. F. Bugg

    SciTech Connect (OSTI)

    Wheatcraft, S.W.; Buddemeier, R.W.

    1981-10-01

    Several inherent problems in the methodology employed in the ground water resource study of Tarawa Atoll (Lloyd, et al., 1981) are described. Studies of Enewetak Atoll have provided data that require a significantly different conceptual model of the atoll hydrogeology system. Comparison of well, lagoon, and ocean tidal observations with a mathematical model that assumes horizontal tidal propagation indicates that the observed results are more consistent with a system that is controlled by vertical coupling between the unconsolidated surface aquifer and an underlying aquifer of more permeable limestone. This indicates that most fresh water recharged to the aquifer migrates downward and mixes with the sea water in a deeper aquifer providing easy exchange with the ocean. Lloyd, et al., do not take tidal mixing or vertical transport into account and it therefore seems likely that fresh water inventories are significantly overestimated. Failure to include these significant loss terms in the island water budget may also account for calculated heads above ground level. (JMT)

  15. The Fermilab CMTF cryogenic distribution remote control system

    SciTech Connect (OSTI)

    Pei, L.; Theilacker, J.; Klebaner, A.; Martinez, A.; Bossert, R.

    2014-01-29

    The Cryomodule Test Facility (CMTF) is able to provide the necessary test bed for measuring the performance of Superconducting Radio Frequency (SRF) cavities in a cryomodule (CM). The CMTF have seven 300 KW screw compressors, two liquid helium refrigerators, and two Cryomodule Test Stands (CMTS). CMTS1 is designed for 1.3 GHz cryomodule operating in a pulsed mode (PM) and CMTS2 is for cryomodule operating in Half-Wave (HW) and Continuous Wave (CW) mode. Based on the design requirement, each subsystem has to be far away from each other and be placed in distant locations. Therefore choosing Siemens Process Control System 7-400, DL205 PLC, Synoptic and Fermilab ACNET are the ideal choices for CMTF cryogenic distribution real-time remote control system. This paper presents a method which has been successfully used by many Fermilab distribution cryogenic real-time remote control systems.

  16. Renewables in Alaska Native Villages: Fort Yukon Wood Energy Program - Wood Boiler Deployment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    : B : kC : d P eo A oP : k d : p — nd P p — P : K o ' : P l ' : K kK oa P a K K P d o i : p — S a P p K d : o o : oP P : p — i i : nK — P B P p : — P K o: P o oP d p B B: hP P d oo a a : P p nP p P d K — u p l l P o oP dl o: p dol p P dP l o u Community Community Biomass Biomass Utilization Utilization Program Program Wildfire Mitigation Energy Cost Reduction Habitat Enhancement Rural Economic Development Environmental Improvement Circle Beaver Central Venetie Fort

  17. Center for Inverse Design Highlight: Enabling Practical p-Type Doping in Oxide Spinels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Practical p-Type Doping in Oxide Spinels The Center for Inverse Design has identified a class of metal oxide spinels-typified by Co 2 ZnO 4 -that have no intrinsic hole-killers and hence enable unopposed p-type doping in easily grown materials. Reference: J.D. Perkins, T.R. Paudel, A. Zakutayev, P.F. Ndione, P.A. Parilla, D.L. Young, S. Lany, D.S. Ginley, A. Zunger, N.H. Perry, Y. Tang, M. Grayson, T.O. Mason, J.S. Bettinger, Y. Z. Shi, and M.F. Toney, Phys. Rev. B, 10.1103/PhysRevB.84.205207

  18. Poly(lactide)-block-poly([epsilon]-caprolactone-co-[epsilon]-decalactone)-block-poly(lactide) copolymer elastomers

    SciTech Connect (OSTI)

    Schneiderman, Deborah K.; Hill, Erin M.; Martello, Mark T.; Hillmyer, Marc A.

    2015-08-28

    Batch ring opening transesterification copolymerization of ?-caprolactone and ?-decalactone was used to generate statistical copolymers over a wide range of compositions and molar masses. Reactivity ratios determined for this monomer pair, rCL = 5.9 and rDL = 0.03, reveal ?-caprolactone is added preferentially regardless of the propagating chain end. Relative to poly(?-caprolactone) the crystallinity and melting point of these statistical copolymers were depressed by the addition of ?-decalactone; copolymers containing greater than 31 mol% (46 wt%) ?-decalactone were amorphous. Poly(lactide)-block-poly(?-caprolactone-co-?-decalactone)-block-poly(lactide) triblock polymers were also prepared and used to explore the influence of midblock composition on the temperature dependent Flory-Huggins interaction parameter (?). In addition, uniaxial extension tests were used to determine the effects of midblock composition, poly(lactide) content, and molar mass on the mechanical properties of these new elastomeric triblocks.

  19. Letter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 (2007) L17-L20 doi:10.1088/0029-5515/47/9/L01 LETTER Recent improvements in confinement and beta in the MST reversed-field pinch D.J. Den Hartog 1 , J.-W. Ahn 1 , A.F. Almagri 1 , J.K. Anderson 1 , A.D. Beklemishev 2 , A.P. Blair 1 , F. Bonomo 3 , M.T. Borchardt 1 , D.L. Brower 4 , D.R. Burke 1 , M. Cengher 1 , B.E. Chapman 1 , S. Choi 1 , D.J. Clayton 1 , W.A. Cox 1 , S.K. Combs 5 , D. Craig 1 , H.D. Cummings 1 , V.I. Davydenko 2 , D.R. Demers 6 , B.H. Deng 4 , W.X. Ding 4 , F. Ebrahimi 1 ,

  20. IAEA-CN-94/EX/C4-6

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IAEA-CN-94/EX/C4-6 1 Core Fluctuations and Current Profile Dynamics in the MST Reversed-Field Pinch D.L. Brower 1), W.X. Ding 1), J. Lei 2), J.K. Anderson 3), T.M. Biewer 3), B.E. Chapman 3), K.A. Connor 2), D. Craig 3), D.R. Demers 2), C.B. Forest 3), D. Holly 3), R. O'Connell 3), S.C. Prager 3), J.S. Sarff 3), P.M. Schoch 2), S.D. Terry 1), J.C. Wright 3) 1) Electrical Engineering Department, University of California at Los Angeles, Los Angeles, California USA 2) Electrical, Computer and

  1. INSTITUTE OF PHYSICS PUBLISHING

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 (2005) S276-S282 doi:10.1088/0029-5515/45/10/S23 Overview of results in the MST reversed field pinch experiment S.C. Prager 1 , J. Adney 1 , A. Almagri 1 , J. Anderson 1 , A. Blair 1 , D.L. Brower 2 , M. Cengher 1 , B.E. Chapman 1 , S. Choi 1 , D. Craig 1 , S. Combs 3 , D.R. Demers 4 , D.J. Den Hartog 1 , B. Deng 2 , W.X. Ding 2 , F. Ebrahimi 1 , D. Ennis 1 , G. Fiksel 1 , R. Fitzpatrick 5 , C. Foust 3 , C.B. Forest 1 , P. Franz 6 , L. Frassinetti 6 , J. Goetz 1 , D. Holly 1 , B. Hudson 1 , M.

  2. Stratified-charge glow plug ignition engine experiments. Topical report

    SciTech Connect (OSTI)

    Thring, R.H.; Leet, J.A.

    1991-05-01

    An investigation was conducted to study the feasibility of operating a natural gas two-stroke engine using glow plug ignition with very lean mixtures. The term Stratified-Charge Glow Plus Ignition (SCGI) was coined to describe the engine. A JLO DL 365 single-cylinder, two-stroke, diesel engine was converted first to a natural gas fueled spark-ignited engine for the baseline tests, and then to the SCGI engine. The engine was successfully run, but was found to be sensitive to various conditions such as the glow plug temperature. The engine ran very lean, to an equivalence ratio of 0.33, offering the potential of good fuel economy and low NOx emissions. Numerous photographs, diagrams, and charts are included.

  3. TITLE

    Office of Legacy Management (LM)

    Peccrdei et .... g:~.g-..o*c *ck .*,- &.-. fi+ E C 7 ---.----.- .-.... 3$rS --------- ixx4!30 F A ~ 953 ' 27565' glla 5tcpEe.l. Peeorder Reception N o . - STATE OF COtOPA00 COUFlTY OF GARFIELD MfEREAS, under date of kcember 7 , 1966, an oil and gas l e a s e was entered i n t o between Claude V. Hayward, lessor, snd Rustrat dl1 Ccmpany Incorporated, Lessee, covering, among other l a n d s , t a t 1 1 , being the Northeast Quarter ~b the Southwest Q u a r t e r o f Section 25, f - 7 4 ,

  4. CO.

    Office of Legacy Management (LM)

    \j 7, b 6 - / :!otification of I:eeL i' lr Sor?!c POiYl Of ::cm2diS;L hcticr, - L.J. !hj:ont Pcl~c:x~i?rs and Co., IltZCptKlt~r, >!r:vr Jersey s. bleycrs, NE-90 EV/Efl has detor.nincd 3 portion of t!,e E.I. D~~TXXL~ h\:e:Y?O~ aid CO. f:icil.j.ty at Dccpwatcr, :!ew Jcrscy to k.c co;ltrzi::citnd vi-:.h rx~ionctive -."nc i dl],~ .&.-se*. 3s :I resul", Of ac-Livitics COEAiiCtCJJ .Lcor ti;c Ii:+il~iLt.tn1, i7ll~iricCr ?ii:;trict 251 ,1toilic Lncr:!y Coxl~iissioil. 1';~ consi.?cr thi

  5. V, Ii. Pat-SC&~, Ciructor, Elvision of Techdcal Jkitiseru

    Office of Legacy Management (LM)

    V, Ii. Pat-SC&~, Ciructor, Elvision of Techdcal Jkitiseru I?. J. !%.Ltl2, Jr., chief, 5isC81bleDU3 Cperstions jw;ta, Prodcc' s.on Giviaion S-A-fiCi : PC: 3JS:?dl please '& advised that zrrangezkenta ?a-Je hem mde M.ti All.e~~ny ~~IWZI ta roll a% *Qdr %tcrylLct, 3. Y. plant on tkx3 firsC, xeclr4z.i of ZY&I m .nLh, %I=& shro*sgh June 1352, and -nil& !Sethlehe:a Stotl to roll at +,hai.r T~ckaxinna, 3. Y. plan% on the second n;ze:tznd of tk23 -IFx-xlth. 3: aould suaost, hcesvcr,

  6. Geologic investigation of roof and floor strata: longwall demonstration, Old Ben Mine No. 24. Prediction of coal balls in the Herrin Coal. Final technical report: Part 2. [Mineralized peat balls

    SciTech Connect (OSTI)

    DeMaris, P.J.; Bauer, R.A.; Cahill, R.A.; Damberger, H.H.

    1983-04-01

    Coal-ball areas, large deposits of mineralized peat in the coal seam, obstructed longwall mining in the Herrin Coal at Old Ben Mine No. 24. In-mine mapping located coal balls under transitional roof - areas where the roof lithology alternates between the Energy Shale and the Anna Shale/Brereton Limestone. Specifically, coal balls occur under eroded exposures or windows of the marine Anna Shale/Brereton Limestone in the Energy Shale. Two types of coal-ball areas have been identified, based on stratigraphic position in the coal seam: type I is restricted to the top of the seam, and type II occurs at midseam and below. To predict the distribution of coal balls, as well as explain their formation, a depositional model was developed: First, freshwater sediments buried the Herrin peat. Decomposition of the sealed peat continued, producing high CO/sub 2/ partial pressures; then selective erosion took place as a river removed the cover along sinuous paths, cutting through to the peat in some places. With the seal broken, CO/sub 2/ was released, and freshwaters that contained Ca and Mg ions flushed out organic acids. Later, marine mud buried both the freshwater sediments and the exposed peat, which accounts for the transitional roof over the Herrin Coal and the coal balls under the marine shale windows in the Energy Shale. The depositional model was supported by the first comprehensive set of geochemical data for coal balls. Coal balls generally contained less than 4 percent organic carbon and very low levels of detrital minerals. Although individual sites of concentrated coal balls cannot be predicted, the specific linear roof exposures associated with these coal-ball areas can be identified by mapping. Based on previously mapped areas, the trends of these linear exposures can be projected.

  7. Mineralogical characterization of saprolite at the FRC background site in Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Kim, Young-Jin; Moon, Ji Won; Roh, Yul; Brooks, Scott C

    2008-12-01

    The Field Research Center (FRC) including five contaminated sites and a clean background area was established in Oak Ridge, Tennessee, as a part of the U.S. Department of Energy's Natural and Accelerated Bioremediation Research (NABIR) program. This study investigates the mineralogy and mineralogical pathways of saprolite at the FRC background site to provide a fundamental basis for the remediation strategy for contaminated sites. The background site is underlain interbedded shales, siltstones, and limestones with nearly identical characteristics to the contaminated sites. Bulk samples of saprolite were collected by hand picking approximately at 1 m depth (C horizon) from the soil surface. The soil pH of 4.3 and cation exchange capacity (CEC) of 10.5 cmol/kg measured are in the range of the typical shallow depth saprolite layer in this area. Total Fe by citrate-bicarbonate-dithionate (CBD) and ammonium oxalate extractable (amorphous) were 17.6 and 0.61 g/kg, respectively. Total Mn extracted by NH{sub 2}OH{center_dot}HCl was 0.17 g/kg. X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses indicate that quartz, illite, and microcline (K-feldspar) are the dominant minerals, occupying 95% of mineral composition. The saprolite samples analyzed have shown characteristics of oxic conditions overall, and the degrees of weathering for three sampling locations were various, most for S1 and least for S3, likely influenced either by the flow channels developed through saprolite or by seasonal fluctuation of the groundwater table. The source of the manganese oxide that observed from the site is likely to be Mn-rich muscovite in the shale or Mn-rich biotite in the blackish band in the limestone. The results such as abundant Mn and Fe contents identified encouraging prospects for conducting remediation projects in FRC sites.

  8. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  9. Depositional sequence analysis and sedimentologic modeling for improved prediction of Pennsylvanian reservoirs

    SciTech Connect (OSTI)

    Watney, W.L.

    1994-12-01

    Reservoirs in the Lansing-Kansas City limestone result from complex interactions among paleotopography (deposition, concurrent structural deformation), sea level, and diagenesis. Analysis of reservoirs and surface and near-surface analogs has led to developing a {open_quotes}strandline grainstone model{close_quotes} in which relative sea-level stabilized during regressions, resulting in accumulation of multiple grainstone buildups along depositional strike. Resulting stratigraphy in these carbonate units are generally predictable correlating to inferred topographic elevation along the shelf. This model is a valuable predictive tool for (1) locating favorable reservoirs for exploration, and (2) anticipating internal properties of the reservoir for field development. Reservoirs in the Lansing-Kansas City limestones are developed in both oolitic and bioclastic grainstones, however, re-analysis of oomoldic reservoirs provides the greatest opportunity for developing bypassed oil. A new technique, the {open_quotes}Super{close_quotes} Pickett crossplot (formation resistivity vs. porosity) and its use in an integrated petrophysical characterization, has been developed to evaluate extractable oil remaining in these reservoirs. The manual method in combination with 3-D visualization and modeling can help to target production limiting heterogeneities in these complex reservoirs and moreover compute critical parameters for the field such as bulk volume water. Application of this technique indicates that from 6-9 million barrels of Lansing-Kansas City oil remain behind pipe in the Victory-Northeast Lemon Fields. Petroleum geologists are challenged to quantify inferred processes to aid in developing rationale geologically consistent models of sedimentation so that acceptable levels of prediction can be obtained.

  10. Vacuum pyrolysis of waste tires with basic additives

    SciTech Connect (OSTI)

    Zhang Xinghua; Wang Tiejun Ma Longlong; Chang Jie

    2008-11-15

    Granules of waste tires were pyrolyzed under vacuum (3.5-10 kPa) conditions, and the effects of temperature and basic additives (Na{sub 2}CO{sub 3}, NaOH) on the properties of pyrolysis were thoroughly investigated. It was obvious that with or without basic additives, pyrolysis oil yield increased gradually to a maximum and subsequently decreased with a temperature increase from 450 deg. C to 600 deg. C, irrespective of the addition of basic additives to the reactor. The addition of NaOH facilitated pyrolysis dramatically, as a maximal pyrolysis oil yield of about 48 wt% was achieved at 550 deg. C without the addition of basic additives, while a maximal pyrolysis oil yield of about 50 wt% was achieved at 480 deg. C by adding 3 wt% (w/w, powder/waste tire granules) of NaOH powder. The composition analysis of pyrolytic naphtha (i.b.p. (initial boiling point) {approx}205 deg. C) distilled from pyrolysis oil showed that more dl-limonene was obtained with basic additives and the maximal content of dl-limonene in pyrolysis oil was 12.39 wt%, which is a valuable and widely-used fine chemical. However, no improvement in pyrolysis was observed with Na{sub 2}CO{sub 3} addition. Pyrolysis gas was mainly composed of H{sub 2}, CO, CH{sub 4}, CO{sub 2}, C{sub 2}H{sub 4} and C{sub 2}H{sub 6}. Pyrolytic char had a surface area comparable to commercial carbon black, but its proportion of ash (above 11.5 wt%) was much higher.

  11. Flow and axial dispersion in a sinusoidal-walled tube: Effects of inertial and unsteady flows

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Perkins, William A.; Scheibe, Timothy D.; Lambert, Adam; Wood, Brian D.

    2013-12-01

    Dispersion in porous media flows has been the subject of much experimental, theoretical and numerical study. Here we consider a wavy-walled tube (a three-dimensional tube with sinusoidally-varying diameter) as a simplified conceptualization of flow in porous media, where constrictions represent pore throats and expansions pore bodies. A theoretical model for effective (macroscopic) longitudinal dispersion in this system has been developed by volume averaging the microscale velocity field. Direct numerical simulation using computational fluid dynamics (CFD) methods was used to compute velocity fields by solving the Navier-Stokes equations, and also to numerically solve the volume averaging closure problem, for a range of Reynolds numbers (Re) spanning the low-Re to inertial flow regimes, including one simulation at Re = 449 for which unsteady flow was observed. Dispersion values were computed using both the volume averaging solution and a random walk particle tracking method, and results of the two methods were shown to be consistent. Our results are compared to experimental measurements of dispersion in porous media and to previous theoretical results for the low-Re, Stokes flow regime. In the steady inertial regime we observe an power-law increase in effective longitudinal dispersion (DL) with Re, consistent with previous results. This rapid rate of increase is caused by trapping of solute in expansions due to flow separation (eddies). For the unsteady case (Re = 449), the rate of increase of DL with Re was smaller than that observed at lower Re. Velocity fluctuations in this regime lead to increased rates of solute mass transfer between the core flow and separated flow regions, thus diminishing the amount of tailing caused by solute trapping in eddies and thereby reducing longitudinal dispersion.

  12. Sex-based differences in gene expression in hippocampus following postnatal lead exposure

    SciTech Connect (OSTI)

    Schneider, J.S., E-mail: jay.schneider@jefferson.edu; Anderson, D.W.; Sonnenahalli, H.; Vadigepalli, R.

    2011-10-15

    The influence of sex as an effect modifier of childhood lead poisoning has received little systematic attention. Considering the paucity of information available concerning the interactive effects of lead and sex on the brain, the current study examined the interactive effects of lead and sex on gene expression patterns in the hippocampus, a structure involved in learning and memory. Male or female rats were fed either 1500 ppm lead-containing chow or control chow for 30 days beginning at weaning.Blood lead levels were 26.7 {+-} 2.1 {mu}g/dl and 27.1 {+-} 1.7 {mu}g/dl for females and males, respectively. The expression of 175 unique genes was differentially regulated between control male and female rats. A total of 167 unique genes were differentially expressed in response to lead in either males or females. Lead exposure had a significant effect without a significant difference between male and female responses in 77 of these genes. In another set of 71 genes, there were significant differences in male vs. female response. A third set of 30 genes was differentially expressed in opposite directions in males vs. females, with the majority of genes expressed at a lower level in females than in males. Highly differentially expressed genes in males and females following lead exposure were associated with diverse biological pathways and functions. These results show that a brief exposure to lead produced significant changes in expression of a variety of genes in the hippocampus and that the response of the brain to a given lead exposure may vary depending on sex. - Highlights: > Postnatal lead exposure has a significant effect on hippocampal gene expression patterns. > At least one set of genes was affected in opposite directions in males and females. > Differentially expressed genes were associated with diverse biological pathways.

  13. Does aspartic acid racemization constrain the depth limit of the subsurface biosphere?

    SciTech Connect (OSTI)

    Onstott, T. C.; Aubrey, A.D.; Kieft, T L; Silver, B J; Phelps, Tommy Joe; Van Heerden, E.; Opperman, D. J.; Bada, J L.

    2014-01-01

    Previous studies of the subsurface biosphere have deduced average cellular doubling times of hundreds to thousands of years based upon geochemical models. We have directly constrained the in situ average cellular protein turnover or doubling times for metabolically active micro-organisms based on cellular amino acid abundances, D/L values of cellular aspartic acid, and the in vivo aspartic acid racemization rate. Application of this method to planktonic microbial communities collected from deep fractures in South Africa yielded maximum cellular amino acid turnover times of ~89 years for 1 km depth and 27 C and 1 2 years for 3 km depth and 54 C. The latter turnover times are much shorter than previously estimated cellular turnover times based upon geochemical arguments. The aspartic acid racemization rate at higher temperatures yields cellular protein doubling times that are consistent with the survival times of hyperthermophilic strains and predicts that at temperatures of 85 C, cells must replace proteins every couple of days to maintain enzymatic activity. Such a high maintenance requirement may be the principal limit on the abundance of living micro-organisms in the deep, hot subsurface biosphere, as well as a potential limit on their activity. The measurement of the D/L of aspartic acid in biological samples is a potentially powerful tool for deep, fractured continental and oceanic crustal settings where geochemical models of carbon turnover times are poorly constrained. Experimental observations on the racemization rates of aspartic acid in living thermophiles and hyperthermophiles could test this hypothesis. The development of corrections for cell wall peptides and spores will be required, however, to improve the accuracy of these estimates for environmental samples.

  14. Investigation of the long-term performance of betafite and zirconolite in hydrothermal veins from Adamello, Italy

    SciTech Connect (OSTI)

    Lumpkin, G.R.; Day, R.A.; McGlinn, P.J.; Payne, T.E.; Giere, R.; Williams, C.T.

    1999-07-01

    Betafite and zirconolite occur in Ti-rich hydrothermal veins emplaced within dolomite marble in the contact aureole of the Adamello batholith, northern Italy. Zirconolite contains up to 18 wt% ThO{sub 2} and 24 wt% UO{sub 2}, and exhibits strong compositional zoning. Some zirconolite grains were corroded by the hydrothermal fluid. Betafite, the Ti-rich member of the pyrochlore group, often occurs as overgrowths on zirconolite. The betafite is weakly zoned and contains 29--34 wt% UO{sub 2}. In terms of end-members, betafite contains approximately 50 mole percent CaUTi{sub 2}O{sub 7} and is the closest known natural composition to the pyrochlore phase proposed for use in titanate waste forms. Amorphization and volume expansion of the betafite caused cracks to form in the enclosing silicate mineral grains. Backscattered electron images reveal that betafite was subsequently altered along crystal rims, particularly near the cracks. EPMA data reveal little difference in composition between altered and unaltered areas, except for lower totals, suggesting that alteration is primarily due to hydration. The available evidence demonstrates that both betafite and zirconolite retained actinides for approximately 40 million years after the final stage of vein formation. During this time, betafite and zirconolite accumulated a total alpha-decay dose of 3--4 x 10{sup 16} and 0.2--2 x 10{sup 16} {alpha}/mg, respectively.

  15. Value of Information Analysis Project Gnome Site, New Mexico

    SciTech Connect (OSTI)

    Greg Pohll; Jenny Chapman

    2010-01-01

    The Project Gnome site in southeastern New Mexico was the location of an underground nuclear detonation in 1961 and a hydrologic tracer test using radionuclides in 1963. The tracer test is recognized as having greater radionuclide migration potential than the nuclear test because the tracer test radionuclides (tritium, 90Sr, 131I, and 137Cs) are in direct contact with the Culebra Dolomite aquifer, whereas the nuclear test is within a bedded salt formation. The tracer test is the topic here. Recognizing previous analyses of the fate of the Gnome tracer test contaminants (Pohll and Pohlmann, 1996; Pohlmann and Andricevic, 1994), and the existence of a large body of relevant investigations and analyses associated with the nearby Waste Isolation Pilot Plant (WIPP) site (summarized in US DOE, 2009), the Gnome Site Characterization Work Plan (U.S. DOE, 2002) called for a Data Decision Analysis to determine whether or not additional characterization data are needed prior to evaluating existing subsurface intrusion restrictions and determining long-term monitoring for the tracer test. Specifically, the Work Plan called for the analysis to weigh the potential reduction in uncertainty from additional data collection against the cost of such field efforts.

  16. DENSE MEDIUM CYCLONE OPTIMIZATON

    SciTech Connect (OSTI)

    Gerald H. Luttrell; Chris J. Barbee; Peter J. Bethell; Chris J. Wood

    2005-06-30

    Dense medium cyclones (DMCs) are known to be efficient, high-tonnage devices suitable for upgrading particles in the 50 to 0.5 mm size range. This versatile separator, which uses centrifugal forces to enhance the separation of fine particles that cannot be upgraded in static dense medium separators, can be found in most modern coal plants and in a variety of mineral plants treating iron ore, dolomite, diamonds, potash and lead-zinc ores. Due to the high tonnage, a small increase in DMC efficiency can have a large impact on plant profitability. Unfortunately, the knowledge base required to properly design and operate DMCs has been seriously eroded during the past several decades. In an attempt to correct this problem, a set of engineering tools have been developed to allow producers to improve the efficiency of their DMC circuits. These tools include (1) low-cost density tracers that can be used by plant operators to rapidly assess DMC performance, (2) mathematical process models that can be used to predict the influence of changes in operating and design variables on DMC performance, and (3) an expert advisor system that provides plant operators with a user-friendly interface for evaluating, optimizing and trouble-shooting DMC circuits. The field data required to develop these tools was collected by conducting detailed sampling and evaluation programs at several industrial plant sites. These data were used to demonstrate the technical, economic and environmental benefits that can be realized through the application of these engineering tools.

  17. INNOVATIVE METHODOLOGY FOR DETECTION OF FRACTURE-CONTROLLED SWEET SPOTS IN THE NORTHERN APPALACHIAN BASION

    SciTech Connect (OSTI)

    Rober Jacobi

    2006-05-31

    During this reporting period, Fortuna retrieved the first oriented horizontal core from the Trenton/Black River in the northern Appalachian Basin. The core came from central New York State, the ''hottest'' play in the Appalachian Basin. A complete well log suite was also collected in the horizontal hole, including an FMI log. After reassembling the core sections, and orienting the core, we analyzed the whole core before it was cut for full-diameter core analyses (e.g., permeability) and before the core was split, in order that we did not miss any features that may be lost during cutting. We recognized and mapped along the core 43 stylolites, 99 veins and several large partially filled vugs. Kinematic indicators suggest multiple phases of strike-slip motion. Master-abutting relationships at intersections (primarily determined from which feature ''cuts'' which other feature) show three stages of stylolite growth: sub horizontal, nearly vertical, and steeply dipping. These development stages reflect vertical loading, tectonic horizontal loading, and finally oblique loading. Hydrothermal dolomite veins cut and are cut by all three stages of the stylolites. A set of horizontal veins indicates vertical unloading. Analyses of the core will continue, as well as the well logs.

  18. PLAY ANALYSIS AND DIGITAL PORTFOLIO OF MAJOR OIL RESERVOIRS IN THE PERMIAN BASIN: APPLICATION AND TRANSFER OF ADVANCED GEOLOGICAL AND ENGINEERING TECHNOLOGIES FOR INCREMENTAL PRODUCTION OPPORTUNITIES

    SciTech Connect (OSTI)

    Shirley P. Dutton; Eugene M. Kim; Ronald F. Broadhead; William Raatz; Cari Breton; Stephen C. Ruppel; Charles Kerans; Mark H. Holtz

    2003-04-01

    A play portfolio is being constructed for the Permian Basin in west Texas and southeast New Mexico, the largest petroleum-producing basin in the US. Approximately 1300 reservoirs in the Permian Basin have been identified as having cumulative production greater than 1 MMbbl of oil through 2000. Of these major reservoirs, approximately 1,000 are in Texas and 300 in New Mexico. On a preliminary basis, 32 geologic plays have been defined for Permian Basin oil reservoirs and assignment of each of the 1300 major reservoirs to a play has begun. The reservoirs are being mapped and compiled in a Geographic Information System (GIS) by play. Detailed studies of three reservoirs are in progress: Kelly-Snyder (SACROC unit) in the Pennsylvanian and Lower Permian Horseshoe Atoll Carbonate play, Fullerton in the Leonardian Restricted Platform Carbonate play, and Barnhart (Ellenburger) in the Ellenburger Selectively Dolomitized Ramp Carbonate play. For each of these detailed reservoir studies, technologies for further, economically viable exploitation are being investigated.

  19. Draft Title 40 CFR 191 compliance certification application for the Waste Isolation Pilot Plant. Volume 8: Appendices HYDRO, IRD, LTM, NUTS, PAR, PMR, QAPD, RBP

    SciTech Connect (OSTI)

    1995-03-31

    Geohydrologic data have been collected in the Los Medanos area at the US Department of Energy`s proposed Waste Isolation Pilot Plant (WIPP) site in southeastern New Mexico since 1975 as part of a study evaluating the feasibility of storing defense-associated nuclear wastes within the bedded salt of the Salado Formation of Permian age. Drilling and hydrologic testing have identified three principal water-bearing zones above the Salado Formation and one below that could potentially transport wastes to the biosphere if the proposed facility were breached. The zones above the Salado are the contact between the Rustler and Salado Formations and the Culebra and Magenta Dolomite Members of the Rustler Formation of Permian age. The zone below the Salado Formation consists of channel sandstones in the Bell Canyon Formation of the Permian Delaware Mountain Group. Determinations of hydraulic gradients, directions of flow, and hydraulic properties were hindered because of the negligible permeability of the water-bearing zones. Special techniques in drilling, well completion, and hydraulic testing have been developed to determine the hydrologic characteristics of these water-producing zones.

  20. Chemical stability of melt-cast refractories in K/sub 2/S/sub 2/O/sub 7/-V/sub 2/O/sub 5/ melt

    SciTech Connect (OSTI)

    Abanin, V.I.; Federov, A.A.; Malyavin, A.G.; Ketov, A.N.

    1983-02-20

    Melts based on V/sub 2/O/sub 5/ are promising as catalysts for conversion of sulfur dioxide and thermocatalytic decomposition of spent sulfuric acid. The high chemical activity of such media with respect to metallic materials necessitates development of new materials of construction not based on metals. The purpose of the present work was to study the influence the composition and structure of melt-cast refractories on their chemical stability in K/sub 2/S/sub 2/O/sub 7/-V/sub 2/O/sub 5/ melts. The chemical stability of refractories based on SiO/sub 2/ in K/sub 2/S/sub 2/O/sub 7/-V/sub 2/O/sub 5/ melt is raised by the presence of chain calcium silicates with pyroxene and pyroxenoid chains, and lowered in presence of the oxides of zirconium, zinc, and cobalt in the materials. Fused quartz, cor-93, cast stone of diopside composition, and basalt-dolomite cast stone have high chemical stability in K/sub 2/S/sub 2/O/sub 7/-V/sub 2/O/sub 5/ melt and can be recommended as construction materials for equipment used for thermocatalytic decomposition of spent sulfuric acid.

  1. Hanford Site ground-water monitoring for July through December 1987

    SciTech Connect (OSTI)

    Evans, J.C.; Dennison, D.I.; Bryce, R.W.; Mitchell, P.J.; Sherwood, D.R.; Krupka, K.M.; Hinman, N.W.; Jacobson, E.A.; Freshley, M.D.

    1988-12-01

    The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between July and December 1987 included monitoring ground-water elevations across the Site, monitoring hazardous chemicals and radionuclides in ground water, geochemical evaluations of unconfined ground-water data, and calibration of ground-water flow and transport models. Water levels continued to rise in areas receiving increased recharge (e.g., beneath B Pond) and decline in areas where the release of water to disposal facilities has been terminated (e.g., U Pond). The major areas of ground-water contamination defined by monitoring activities are (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and 200-West Areas; (3) hexavalent chromium contamination in the 100-B, 100-D, 100-F, 100-H, 100-K, and 200-West Areas; (4) chlorinated hydrocarbons in the vicinity of the Central Landfill and 300 Area; (5) uranium in the 100-F, 100-H, 200-West, and 300 Areas; and (6) tritium and nitrate across the Site. The MINTEQ geochemical code was used to identify chemical reactions that may be affecting the concentrations of dissolved hazardous chemicals in the unconfined ground water. Results indicate that many cations are present mainly as dissolved carbonate complexes and that a majority of the ground-water samples are in near equilibrium with carbonate minerals (e.g., calcite, dolomite, otavite).

  2. CRADA opportunities in removal of particulates from hot-gas streams by filtration

    SciTech Connect (OSTI)

    Smith, D.H.

    1995-06-01

    Our analyses of samples and operating data from the Pressurized Fluidized Bed Combustion (PFBC), cyclone, and filtration units of the Tidd Clean Coal demonstration facility show that calcined dolomitic sorbent reacted with SO{sub 2} (and O{sub 2}) to form Sulfates (CaSO{sub 4} and CaMgn [SO{sub 4}]n+1) not only in the PFBC bed, but also in the filtration vessel. Analyses of limited data from the journal literature suggest that the filter-vessel reactions may have produced sulfate {open_quotes}necks,{close_quotes} which bonded the particles together, thus substantially increasing the critical angle of repose and shear tensile strengths of the filtered powders. This proposed mechanism rationalizes the {open_quotes}bridging{close_quotes} and other particle-accumulation problems that caused filter breakage. Engineering services potentially available to resolve these problems include elucidation and modeling of ex-situ and in-situ filter-vessel chemistry, measurement and modeling of particulate materials properties, and measurement and modeling of cleaning back-pulse aerodynamics and cleaning efficiencies.

  3. Surveillance of Site A and Plot M, Report for 2009.

    SciTech Connect (OSTI)

    Golchert, N. W.

    2010-04-21

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for Calendar Year 2009 are presented. Based on the results of the 1976-1978 radiological characterization of the site, a determination was made that a surveillance program be established. The characterization study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current surveillance program began in 1980 and consists of sample collection and analysis of surface and subsurface water. The results of the analyses are used to monitor the migration pathway of hydrogen-3 contaminated water from the burial ground (Plot M) to the hand-pumped picnic wells and monitor for the presence of radioactive materials in the environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Hydrogen-3 continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  4. Surveillance of Site A and Plot M

    SciTech Connect (OSTI)

    Golchert, N.W.

    1991-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for CY 1990 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to determine the migration pathway of water from the burial ground (plot M) to the hand-pumped picnic wells, establish if buries radionuclides other than hydrogen-3 have migrated, and generally characterize the radiological environment of the area. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continues to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site or those living in the vicinity. 20 refs., 7 figs., 15 tabs.

  5. The use of expert elicitation to quantify uncertainty in incomplete sorption data bases for Waste Isolation Pilot Plant performance assessment

    SciTech Connect (OSTI)

    Anderson, D.R.; Trauth, K.M. ); Hora, S.C. )

    1991-01-01

    Iterative, annual performance-assessment calculations are being performed for the Waste Isolation Pilot Plant (WIPP), a planned underground repository in southeastern New Mexico, USA for the disposal of transuranic waste. The performance-assessment calculations estimate the long-term radionuclide releases from the disposal system to the accessible environment. Because direct experimental data in some areas are presently of insufficient quantity to form the basis for the required distributions. Expert judgment was used to estimate the concentrations of specific radionuclides in a brine exiting a repository room or drift as it migrates up an intruding borehole, and also the distribution coefficients that describe the retardation of radionuclides in the overlying Culebra Dolomite. The variables representing these concentrations and coefficients have been shown by 1990 sensitivity analyses to be among the set of parameters making the greatest contribution to the uncertainty in WIPP performance-assessment predictions. Utilizing available information, the experts (one expert panel addressed concentrations and a second panel addressed retardation) developed an understanding of the problem and were formally elicited to obtain probability distributions that characterize the uncertainty in fixed, but unknown, quantities. The probability distributions developed by the experts are being incorporated into the 1991 performance-assessment calculations. 16 refs., 4 tabs.

  6. Hydrogeochemical studies of the Rustler Formation and related rocks in the Waste Isolation Pilot Plant Area, Southeastern New Mexico

    SciTech Connect (OSTI)

    Siegel, M.D.; Lambert, S.J.; Robinson, K.L.

    1991-08-01

    Chemical, mineralogical, isotopic, and hydrological studies of the Culebra dolomite member of the Rustler Formation and related rocks are used to delineate hydrochemical facies and form the basis for a conceptual model for post-Pleistocene groundwater flow and chemical evolution. Modern flow within the Culebra in the Waste Isolation Pilot Plant (WIPP) area appears to be largely north-to-south; however, these flow directions under confined conditions are not consistent with the salinity distribution in the region surrounding the WIPP Site. Isotopic, mineralogical, and hydrological data suggest that vertical recharge to the Culebra in the WIPP area and to the immediate east and south has not occurred for several thousand years. Eastward increasing {sup 234}U/{sup 238}U activity ratios suggest recharge from a near-surface Pleistocene infiltration zone flowing from the west-northwest and imply a change in flow direction in the last 30,000 to 12,000 years. 49 refs., 34 figs., 4 tabs.

  7. Surveillance of Site A and Plot M report for 2010.

    SciTech Connect (OSTI)

    Golchert, N. W.

    2011-05-31

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for Calendar Year 2010 are presented. Based on the results of the 1976-1978 radiological characterization of the site, a determination was made that a surveillance program be established. The characterization study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current surveillance program began in 1980 and consists of sample collection and analysis of surface and subsurface water. The results of the analyses are used to monitor the migration pathway of hydrogen-3 contaminated water from the burial ground (Plot M) to the hand-pumped picnic wells and monitor for the presence of radioactive materials in the environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Hydrogen-3 continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  8. Sedimentological, mineralogical and geochemical definition of oil-shale facies in the lower Parachute Creek Member of Green River Formation, Colorado

    SciTech Connect (OSTI)

    Cole, R.D.

    1984-04-01

    Sedimentological, mineralogical and geochemical studies of two drill cores penetrating the lower Saline zone of the Parachute Creek Member (middle L-4 oil-shale zone through upper R-2 zone) of the Green River Formation in north-central Piceance Creek basin, Colorado, indicate the presence of two distinct oil-shale facies. The most abundant facies has laminated stratification and frequently occurs in the L-4, L-3 and L-2 oil-shale zones. The second, and subordinate facies, has ''streaked and blebby'' stratification and is most abundant in the R-4, R-3 and R-2 zones. Laminated oil shale originated by slow, regular sedimentation during meromictic phases of ancient Lake Uinta, whereas streaked and blebby oil shale was deposited by episodic, non-channelized turbidity currents. Laminated oil shale has higher contents of nahcolite, dawsonite, quartz, K-feldspar and calcite, but less dolomite/ankerite and albite than streaked and blebby oil shale. Ca-Mg-Fe carbonate minerals in laminated oil shale have more variable compositions than those in streaked and blebby shales. Streaked and blebby oil shale has more kerogen and a greater diversity of kerogen particles than laminated oil shale. Such variations may produce different pyrolysis reactions when each shale type is retorted.

  9. Exploration for basal Silurian reservoirs in western Illinois

    SciTech Connect (OSTI)

    Whitaker, S.T.; Howard, R.H.

    1995-07-31

    The discovery of two oil fields, Kellerville and Siloam, in shallow (600--675 ft deep) basal Silurian carbonates in 1958 and 1959 respectively, was the first new production in western Illinois since the discovery of the Devonian Hoing sandstone at Colmar-Plymouth field in 1914. A second, and more major, drilling boom in western Illinois resulted from official recognition in 1982 of a significant oil discovery in basal Silurian rocks at Buckhorn East oil field, later Buckhorn Consolidated. Within a relatively short time, numerous rigs were moving into western Illinois in the hopes of repeating the successes experienced at Buckhorn East. Unfortunately, there was no adequate geologic model that explained the oil accumulations in western Illinois. Basal Silurian reservoirs in western Illinois developed due to dolomitization of carbonate that filled shallow valleys incised in the underlying Maquoketa shale. Exploration for these reservoirs should utilize all of the clues that are presented here. It will be critical to continue gathering data from the area via quality wireline logs, cores, samples, and geophysical studies. It is unlikely that the Buckhorn-Siloam-Kellerville complex is unique in western Illinois.

  10. DOE workshop: Sedimentary systems, aqueous and organic geochemistry

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    A DOE workshop on sedimentary systems, aqueous and organic geochemistry was held July 15-16, 1993 at Lawrence Berkeley Laboratory. Papers were organized into several sections: Fundamental Properties, containing papers on the thermodynamics of brines, minerals and aqueous electrolyte solutions; Geochemical Transport, covering 3-D imaging of drill core samples, hydrothermal geochemistry, chemical interactions in hydrocarbon reservoirs, fluid flow model application, among others; Rock-Water Interactions, with presentations on stable isotope systematics of fluid/rock interaction, fluid flow and petotectonic evolution, grain boundary transport, sulfur incorporation, tracers in geologic reservoirs, geothermal controls on oil-reservoir evolution, and mineral hydrolysis kinetics; Organic Geochemistry covered new methods for constraining time of hydrocarbon migration, kinetic models of petroleum formation, mudstones in burial diagenesis, compound-specific carbon isotope analysis of petroleums, stability of natural gas, sulfur in sedimentary organic matter, organic geochemistry of deep ocean sediments, direct speciation of metal by optical spectroscopies; and lastly, Sedimentary Systems, covering sequence stratigraphy, seismic reflectors and diagenetic changes in carbonates, geochemistry and origin of regional dolomites, and evidence of large comet or asteroid impacts at extinction boundaries.

  11. The use of the scanning electron microscope in the determination of the mineral composition of Ballachulish slate

    SciTech Connect (OSTI)

    Walsh, Joan A.

    2007-11-15

    Slate is a fine-grained, low-grade metamorphic rock derived from argillaceous sediments or occasionally volcanic ash. Although most slates contain mainly quartz, chlorite and white mica, they vary considerably in their durability, some lasting centuries while others fail after a few years of service. A detailed characterisation of their mineralogy is required for the assessment of performance, and to establish the provenance of a used slate. A combination of methods was used to examine Ballachulish slates; XRD analysis to determine the principal minerals present, XRF analysis to determine the total chemical composition, and scanning electron microscopy to determine the chemical composition of individual minerals. It was found that the white mica in Ballachulish slate is phengite and the chlorite is ripidolite. Feldspar is present as albite and carbonate as ferroan dolomite. Several accessory minerals were also identified, including chloritoid, monzonite and zircon. There was considerable variation in the ratio of the principal minerals, making it impossible to identify used slates by this criterion. Instead, chemical composition of the individual minerals, and possibly key accessory minerals, should be used to determine the provenance of slates.

  12. Development of a coal-fired combustion system for industrial process heating applications. Phase 3 final report, November 1992--December 1994

    SciTech Connect (OSTI)

    1995-09-26

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product.

  13. Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1988-01-01

    A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

  14. Alternative Fuel for Portland Cement Processing

    SciTech Connect (OSTI)

    Anton K. Schindler; Steve R. Duke; Thomas E. Burch; Edward W. Davis; Ralph H. Zee; David I. Bransby; Carla Hopkins; Rutherford L. Thompson; Jingran Duan; Vignesh Venkatasubramanian; Stephen Giles.

    2012-06-30

    The production of cement involves a combination of numerous raw materials, strictly monitored system processes, and temperatures on the order of 1500 °C. Immense quantities of fuel are required for the production of cement. Traditionally, energy from fossil fuels was solely relied upon for the production of cement. The overarching project objective is to evaluate the use of alternative fuels to lessen the dependence on non-renewable resources to produce portland cement. The key objective of using alternative fuels is to continue to produce high-quality cement while decreasing the use of non-renewable fuels and minimizing the impact on the environment. Burn characteristics and thermodynamic parameters were evaluated with a laboratory burn simulator under conditions that mimic those in the preheater where the fuels are brought into a cement plant. A drop-tube furnace and visualization method were developed that show potential for evaluating time- and space-resolved temperature distributions for fuel solid particles and liquid droplets undergoing combustion in various combustion atmospheres. Downdraft gasification has been explored as a means to extract chemical energy from poultry litter while limiting the throughput of potentially deleterious components with regards to use in firing a cement kiln. Results have shown that the clinkering is temperature independent, at least within the controllable temperature range. Limestone also had only a slight effect on the fusion when used to coat the pellets. However, limestone addition did display some promise in regards to chlorine capture, as ash analyses showed chlorine concentrations of more than four times greater in the limestone infused ash as compared to raw poultry litter. A reliable and convenient sampling procedure was developed to estimate the combustion quality of broiler litter that is the best compromise between convenience and reliability by means of statistical analysis. Multi-day trial burns were conducted at a full-scale cement plant with alternative fuels to examine their compatibility with the cement production process. Construction and demolition waste, woodchips, and soybean seeds were used as alternative fuels at a full-scale cement production facility. These fuels were co-fired with coal and waste plastics. The alternative fuels used in this trial accounted for 5 to 16 % of the total energy consumed during these burns. The overall performance of the portland cement produced during the various trial burns performed for practical purposes very similar to the cement produced during the control burn. The cement plant was successful in implementing alternative fuels to produce a consistent, high-quality product that increased cement performance while reducing the environmental footprint of the plant. The utilization of construction and demolition waste, woodchips and soybean seeds proved to be viable replacements for traditional fuels. The future use of these fuels depends on local availability, associated costs, and compatibility with a facility??s production process.

  15. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Musharraf Zaman, Ph.D.; Younane Abousleiman, Ph.D.

    2001-04-01

    The oil and gas industry has encountered significant problems in the production of oil and gas from weak rocks (such as chalks and limestones) and from unconsolidated sand formations. Problems include subsidence, compaction, sand production, and catastrophic shallow water sand flows during deep water drilling. Together these cost the petroleum industry hundreds of millions of dollars annually. The goals of this first quarterly report is to document the progress on the project to provide data on the acoustic imaging and mechanical properties of soft rock and marine sediments. The project is intended to determine the geophysical (acoustic velocities) rock properties of weak, poorly cemented rocks and unconsolidated sands. In some cases these weak formations can create problems for reservoir engineers. For example, it cost Phillips Petroleum 1 billion dollars to repair of offshore production facilities damaged during the unexpected subsidence and compaction of the Ekofisk Field in the North Sea (Sulak 1991). Another example is the problem of shallow water flows (SWF) occurring in sands just below the seafloor encountered during deep water drilling operations. In these cases the unconsolidated sands uncontrollably flow up around the annulus of the borehole resulting in loss of the drill casing. The $150 million dollar loss of the Ursa development project in the U.S. Gulf Coast resulted from an uncontrolled SWF (Furlow 1998a,b; 1999a,b). The first three tasks outlined in the work plan are: (1) obtain rock samples, (2) construct new acoustic platens, (3) calibrate and test the equipment. These have been completed as scheduled. Rock Mechanics Institute researchers at the University of Oklahoma have obtained eight different types of samples for the experimental program. These include: (a) Danian Chalk, (b) Cordoba Cream Limestone, (c) Indiana Limestone, (d) Ekofisk Chalk, (e) Oil Creek Sandstone, (f) unconsolidated Oil Creek sand, and (g) unconsolidated Brazos river sand. These weak rocks and sands are intended to represent analogs to the formations that present oil and gas engineers with problems during oil and gas production and drilling operations. A series of new axial acoustic sensors have been constructed (and tested) to allow measurement of compressional and shear wave velocities during high pressure triaxial tests on these weak rock and sand samples. In addition, equipment to be utilized over the next 18 months of the project have tested and calibrated. These include the load frames, triaxial pressure cells, pressure sensors, load cells, extensometers, and oscilloscopes have been calibrated and tested. The multichannel acoustic emission and acoustic pulse transmission systems have also been tested. Graduate research assistant, research faculty, and the laboratory technician have begun Tasks 4 and 5 which involve preparing the sand samples and rock samples for testing. The construction of the lateral acoustic sensors has also been started during this quarter as outlined in the project timeline. With the equipment having been tested and calibrated, and the samples now being prepared, the experiments are on schedule to be started in April, 2001.

  16. Stratigraphy of the PB-1 well, Nopal I uranium deposit, Sierra Pena Blanca, Chihuahua, Mexico

    SciTech Connect (OSTI)

    Dobson, P.; Fayek, M.; Goodell, P.; Ghezzehei, T.; Melchor, F.; Murrell, M.; Oliver, R.; Reyes-Cortes, I.A.; de la Garza, R.; Simmons, A.

    2008-08-01

    The Nopal I site in the Pena Blanca uranium district has a number of geologic and hydrologic similarities to the proposed high-level radioactive waste repository at Yucca Mountain, making it a useful analogue to evaluate process models for radionuclide transport. The PB-1 well was drilled in 2003 at the Nopal I uranium deposit as part of a DOE-sponsored natural analogue study to constrain processes affecting radionuclide transport. The well penetrates through the Tertiary volcanic section down to Cretaceous limestone and intersects the regional aquifer system. The well, drilled along the margin of the Nopal I ore body, was continuously cored to a depth of 250 m, thus providing an opportunity to document the local stratigraphy. Detailed observations of these units were afforded through petrographic description and rock-property measurements of the core, together with geophysical logs of the well. The uppermost unit encountered in the PB-1 well is the Nopal Formation, a densely welded, crystal-rich, rhyolitic ash-flow tuff. This cored section is highly altered and devitrified, with kaolinite, quartz, chlorite, and montmorillonite replacing feldspars and much of the groundmass. Breccia zones within the tuff contain fracture fillings of hematite, limonite, goethite, jarosite, and opal. A zone of intense clay alteration encountered in the depth interval 17.45-22.30 m was interpreted to represent the basal vitrophyre of this unit. Underlying the Nopal Formation is the Coloradas Formation, which consists of a welded lithic-rich rhyolitic ash-flow tuff. The cored section of this unit has undergone devitrification and oxidation, and has a similar alteration mineralogy to that observed in the Nopal tuff. A sharp contact between the Coloradas tuff and the underlying Pozos Formation was observed at a depth of 136.38 m. The Pozos Formation consists of poorly sorted conglomerate containing clasts of subangular to subrounded fragments of volcanic rocks, limestone, and chert. Three thin (2-6 m) intervals of intercalated pumiceous tuffs were observed within this unit. The contact between the Pozos Formation and the underlying Cretaceous limestone basement was observed at a depth of 244.40 m. The water table is located at a depth of {approx}223 m. Several zones with elevated radioactivity in the PB-1 core are located above the current water table. These zones may be associated with changes in redox conditions that could have resulted in the precipitation of uraninite from downward flowing waters transporting U from the overlying Nopal deposit. All of the intersected units have low (typically submillidarcy) matrix permeability, thus fluid flow in this area is dominated by fracture flow. These stratigraphic and rock-property observations can be used to constrain flow and transport models for the Pena Blanca natural analogue.

  17. Leveraging Regional Exploration to Develop Geologic Framework for CO2 Storage in Deep Formations in Midwestern United States

    SciTech Connect (OSTI)

    Neeraj Gupta

    2009-09-30

    Obtaining subsurface data for developing a regional framework for geologic storage of CO{sub 2} can require drilling and characterization in a large number of deep wells, especially in areas with limited pre-existing data. One approach for achieving this objective, without the prohibitive costs of drilling costly standalone test wells, is to collaborate with the oil and gas drilling efforts in a piggyback approach that can provide substantial cost savings and help fill data gaps in areas that may not otherwise get characterized. This leveraging with oil/gas drilling also mitigates some of the risk involved in standalone wells. This collaborative approach has been used for characterizing in a number of locations in the midwestern USA between 2005 and 2009 with funding from U.S. Department of Energy's National Energy Technology Laboratory (DOE award: DE-FC26-05NT42434) and in-kind contributions from a number of oil and gas operators. The results are presented in this final technical report. In addition to data collected under current award, selected data from related projects such as the Midwestern Regional Carbon Sequestration Partnership (MRCSP), the Ohio River Valley CO{sub 2} storage project at and near the Mountaineer Plant, and the drilling of the Ohio Stratigraphic well in Eastern Ohio are discussed and used in the report. Data from this effort are also being incorporated into the MRCSP geologic mapping. The project activities were organized into tracking and evaluation of characterization opportunities; participation in the incremental drilling, basic and advanced logging in selected wells; and data analysis and reporting. Although a large number of opportunities were identified and evaluated, only a small subset was carried into the field stage. Typical selection factors included reaching an acceptable agreement with the operator, drilling and logging risks, and extent of pre-existing data near the candidate wells. The region of study is primarily along the Ohio River Valley corridor in the Appalachian Basin, which underlies large concentrations of CO{sub 2} emission sources. In addition, some wells in the Michigan basin are included. Assessment of the geologic and petrophysical properties of zones of interest has been conducted. Although a large number of formations have been evaluated across the geologic column, the primary focus has been on evaluating the Cambrian sandstones (Mt. Simon, Rose Run, Kerbel) and carbonates layers (Knox Dolomite) as well as on the Silurian-Devonian carbonates (Bass Island, Salina) and sandstones (Clinton, Oriskany, Berea). Factors controlling the development of porosity and permeability, such as the depositional setting have been explored. In northern Michigan the Bass Islands Dolomite appears to have favorable reservoir development. In west central Michigan the St. Peter sandstone exhibits excellent porosity in the Hart and Feuring well and looks promising. In Southeastern Kentucky in the Appalachian Basin, the Batten and Baird well provided valuable data on sequestration potential in organic shales through adsorption. In central and eastern Ohio and western West Virginia, the majority of the wells provided an insight to the complex geologic framework of the relatively little known Precambrian through Silurian potential injection targets. Although valuable data was acquired and a number of critical data gaps were filled through this effort, there are still many challenges ahead and questions that need answered. The lateral extent to which favorable potential injection conditions exist in most reservoirs is still generally uncertain. The prolongation of the characterization of regional geologic framework through partnership would continue to build confidence and greatly benefit the overall CO{sub 2} sequestration effort.

  18. COMPLETION REPORT FOR WELL CLUSTER ER-5-3

    SciTech Connect (OSTI)

    BECHTEL NEVADA

    2005-12-01

    Well Cluster ER-5-3 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. This cluster of 3 wells was drilled in 2000 and 2001 as part of a hydrogeologic investigation program in Frenchman Flat. The first borehole in the cluster, Well ER-5-3, was drilled in February and March 2000. A 47.0-centimeter surface hole was drilled and cased off to the depth of 374.8 meters. The hole diameter was decreased to 31.1 centimeters for drilling to a total depth of 794.3 meters within welded ash-flow tuff. A piezometer string with 1 slotted interval was installed in the annulus of the surface casing, open to the saturated alluvium. A completion string with 2 slotted intervals was installed in the main hole, open to saturated alluvium and to the welded tuff aquifer. A second piezometer string with 1 slotted interval open to the welded-tuff aquifer was installed outside the completion string. Well ER-5-3 No.2 was drilled about 30 meters west of the first borehole in March 2000, and was recompleted in March 2001. A 66.0-centimeter hole was drilled and cased off to the depth of 613.8 meters. The hole diameter was decreased to 44.5 centimeters and the borehole was drilled and cased off to the depth of 849.0 meters. The hole diameter was decreased once more to 31.1 centimeters for drilling to a total depth of 1,732.2 meters in dolomite. A completion string open to the dolomite (lower carbonate aquifer) was installed. Well ER-5-3 No.3 was drilled approximately 30 meters north of the first 2 boreholes in February 2001. A 66.0-centimeter hole was drilled and cased off to the depth of 36.6 meters, then the main 25.1-centimeter-diameter hole was drilled to a total depth of 548.6 meters in alluvium. A slotted stainless-steel tubing string was installed in the saturated alluvium. A preliminary composite, static water level was measured at the depth of 282.6 meters, prior to development and hydrologic testing. Detailed lithologic descriptions and stratigraphic assignments are included in the report. These are based on composite drill cuttings collected every 3 meters, and 120 sidewall samples taken at various depths below 91 meters in Wells ER-5-3 and ER-5-3 No.2, supplemented by geophysical log data. The wells penetrated Quaternary/Tertiary alluvium to the depth of 622.4 meters, and an 8.5-meter-thick basalt flow was encountered within the alluvium. Tertiary tuff was penetrated to the depth of approximately 1,425.9 meters, where the top of the lower carbonate aquifer was tagged in Well ER-5-3 No.2.

  19. An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins

    SciTech Connect (OSTI)

    Leetaru, Hannes

    2014-12-01

    The studies summarized herein were conducted during 20092014 to investigate the utility of the Knox Group and St. Peter Sandstone deeply buried geologic strata for underground storage of carbon dioxide (CO2), a practice called CO2 sequestration (CCS). In the subsurface of the midwestern United States, the Knox and associated strata extend continuously over an area approaching 500,000 sq. km, about three times as large as the State of Illinois. Although parts of this region are underlain by the deeper Mt. Simon Sandstone, which has been proven by other Department of Energy-funded research as a resource for CCS, the Knox strata may be an additional CCS resource for some parts of the Midwest and may be the sole geologic storage (GS) resource for other parts. One group of studies assembles, analyzes, and presents regional-scale and point-scale geologic information that bears on the suitability of the geologic formations of the Knox for a CCS project. New geologic and geo-engineering information was developed through a small-scale test of CO2 injection into a part of the Knox, conducted in western Kentucky. These studies and tests establish the expectation that, at least in some locations, geologic formations within the Knox will (a) accept a commercial-scale flow rate of CO2 injected through a drilled well; (b) hold a commercial-scale mass of CO2 (at least 30 million tons) that is injected over decades; and (c) seal the injected CO2 within the injection formations for hundreds to thousands of years. In CCS literature, these three key CCS-related attributes are called injectivity, capacity, and containment. The regional-scale studies show that reservoir and seal properties adequate for commercial-scale CCS in a Knox reservoir are likely to extend generally throughout the Illinois and Michigan Basins. Information distinguishing less prospective subregions from more prospective fairways is included in this report. Another group of studies report the results of reservoir flow simulations that estimate the progress and outcomes of hypothetical CCS projects carried out within the Knox (particularly within the Potosi Dolomite subunit, which, in places, is highly permeable) and within the overlying St. Peter Sandstone. In these studies, the regional-scale information and a limited amount of detailed data from specific boreholes is used as the basis for modeling the CO2 injection process (dynamic modeling). The simulation studies were conducted progressively, with each successive study designed to refine the conclusions of the preceding one or to answer additional questions. The simulation studies conclude that at Decatur, Illinois or a geologically similar site, the Potosi Dolomite reservoir may provide adequate injectivity and capacity for commercial-scale injection through a single injection well. This conclusion depends on inferences from seismic-data attributes that certain highly permeable horizons observed in the wells represent laterally persistent, porous vuggy zones that are vertically more common than initially evident from wellbore data. Lateral persistence of vuggy zones is supported by isotopic evidence that the conditions that caused vug development (near-surface processes) were of regional rather than local scale. Other studies address aspects of executing and managing a CCS project that targets a Knox reservoir. These studies cover well drilling, public interactions, representation of datasets and conclusions using geographic information system (GIS) platforms, and risk management.

  20. Improved Mobility Control for Carbon Dioxide (CO{sub 2}) Enhanced Oil Recovery Using Silica-Polymer-Initiator (SPI) Gels

    SciTech Connect (OSTI)

    Oglesby, Kenneth

    2014-01-31

    SPI gels are multi-component silicate based gels for improving (areal and vertical) conformance in oilfield enhanced recovery operations, including water-floods and carbon dioxide (CO{sub 2}) floods, as well as other applications. SPI mixtures are like-water when pumped, but form light up to very thick, paste-like gels in contact with CO{sub 2}. When formed they are 3 to 10 times stronger than any gelled polyacrylamide gel now available, however, they are not as strong as cement or epoxy, allowing them to be washed / jetted out of the wellbore without drilling. This DOE funded project allowed 8 SPI field treatments to be performed in 6 wells (5 injection wells and 1 production well) in 2 different fields with different operators, in 2 different basins (Gulf Coast and Permian) and in 2 different rock types (sandstone and dolomite). Field A was in a central Mississippi sandstone that injected CO{sub 2} as an immiscible process. Field B was in the west Texas San Andres dolomite formation with a mature water-alternating-gas miscible CO{sub 2} flood. Field A treatments are now over 1 year old while Field B treatments have only 4 months data available under variable WAG conditions. Both fields had other operational events and well work occurring before/ during / after the treatments making definitive evaluation difficult. Laboratory static beaker and dynamic sand pack tests were performed with Ottawa sand and both fields core material, brines and crude oils to improve SPI chemistry, optimize SPI formulations, ensure SPI mix compatibility with field rocks and fluids, optimize SPI treatment field treatment volumes and methods, and ensure that strong gels set in the reservoir. Field quality control procedures were designed and utilized. Pre-treatment well (surface) injectivities ranged from 0.39 to 7.9 MMCF/psi. The SPI treatment volumes ranged from 20.7 cubic meters (m{sup 3}, 5460 gallons/ 130 bbls) to 691 m{sup 3} (182,658 gallons/ 4349 bbls). Various size and types of chemical/ water buffers before and after the SPI mix ensured that pre-gelled SPI mix got out into the formation before setting into a gel. SPI gels were found to be 3 to 10 times stronger than any commercially available cross-linked polyacrylamide gels based on Penetrometer and Bulk Gel Shear Testing. Because of SPIs unique chemistry with CO{sub 2}, both laboratory and later field tests demonstrated that multiple, smaller volume SPI treatments maybe more effective than one single large SPI treatment. CO{sub 2} injectivities in injection well in both fields were reduced by 33 to 70% indicating that injected CO{sub 2} is now going into new zones. This reduction has lasted 1+ year in Field A. Oil production increased and CO{sub 2} production decreased in 5 Field A production wells, offsets to Well #1 injector, for a total of about 2,250 m{sup 3} (600,000 gallons/ 14,250 bbls) of incremental oil production- a $140 / SPI bbl return. Treated marginal production well, Field A Well #2, immediately began showing increased oil production totaling 238 m{sup 3} (63,000 gallons/ 1500 BBLs) over 1 year and an immediate 81% reduced gas-oil ratio.

  1. Mobilization of Metals from Eau Claire Siltstone and the Impact of Oxygen under Geological Carbon Dioxide Sequestration Conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Kukkadapu, Ravi K.; Krogstad, Eirik J.; Newburn, Matthew K.; Cantrell, Kirk J.

    2014-09-01

    Geologic CO2 sequestration (GCS) has been proposed as a viable strategy to reduce anthropogenic CO2 emission; however, the increased cost that will be incurred by fossil energy production facilities is a deterrent to implementation of this technology. Allowing impurities in the effluent CO2 stream could result in significant financial and energy savings for CO2 capture and separation. However, impurities such as O2 have the potential to influence the redox state and alter the geochemical interactions that occur within GCS reservoirs, which increases the concern for CO2 and brine leakage from the storage reservoir as well as the overlying groundwater contamination. In this work, to investigate the impact of O2 co-injected with CO2 on the geochemical interactions, especially the trace metal mobilization from a GCS reservoir rock, batch studies were conducted with Eau Claire siltstone collected from CO2 sequestration sites. The rock was reacted with synthetic brines in contact with either 100% CO2 or a mixture of 95 mole% CO2-5 mole% O2 at 10.1 MPa and 75 C. Both microscopic and spectroscopic measurements, including 57Fe-Mssbauer spectroscopy, Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry, powder X-ray diffraction, scanning electron microscopy-energy dispersive x-ray spectroscopy, and chemical extraction were combined in this study to investigate reaction mechanisms. The Eau Claire siltstone contains quartz (52 wt%), fluorapatite (40%), and aluminosilicate (5%) as major components, and dolomite (2%), pyrite (1%), and small-particle-/poorly-crystalline Fe-oxides as minor components. With the introduction of CO2 into the reaction vessel containing rock and brine, the leaching of small amounts of fluorapatite, aluminosilicate, and dolomite occurred. Trace metals of environmental concern, including Pb, As, Cd, and Cu were detected in the leachate with concentrations up to 400 ppb in the CO2-brine-rock reaction system within 30 days. In the presence of O2, the mobilization of Pb, Cd, and Cu was significantly enhanced, whereas As concentrations decreased, compared with the reaction system without oxygen. The presence of oxygen resulted in the formation of secondary Fe-oxides which appear to be Fe(II)-substituted P-containing ferrihydrite. Although the rock contained only 1.04 wt% total Fe, oxidative dissolution of pyrite, leaching and oxidation of structural Fe(II) in fluorapatite, and precipitation of Fe-oxides significantly decreased the pH in brine with oxygen(pH 3.3-3.7), compared with the reaction system without oxygen (pH 4.2-4.4). In the CO2-rock-brine system without O2, the majority of As remained in the rock, with about 1.1% of the total As being released from intrinsic Fe-oxides to the aqueous phase. The release behavior of As to solution was consistent with competitive adsorption between phosphate/fluoride and As on Fe-oxide surfaces. In the presence of O2 the mobility of As was reduced due to enhanced adsorption onto both intrinsic and secondary Fe-oxide surfaces.When O2 was present, the dominant species in solution was the less toxic As(V). This work will advance our understanding of the geochemical reaction mechanisms that occur under GCS conditions and help to evaluate the risks associated with geological CO2 sequestration.

  2. A Systems Approach to Identifying Exploration and Development Opportunities in the Illinois Basin: Digital Portifolio of Plays in Underexplored Lower Paleozoic Rocks

    SciTech Connect (OSTI)

    Beverly Seyler; David Harris; Brian Keith; Bryan Huff; Yaghoob Lasemi

    2008-06-30

    This study examined petroleum occurrence in Ordovician, Silurian and Devonian reservoirs in the Illinois Basin. Results from this project show that there is excellent potential for additional discovery of petroleum reservoirs in these formations. Numerous exploration targets and exploration strategies were identified that can be used to increase production from these underexplored strata. Some of the challenges to exploration of deeper strata include the lack of subsurface data, lack of understanding of regional facies changes, lack of understanding the role of diagenetic alteration in developing reservoir porosity and permeability, the shifting of structural closures with depth, overlooking potential producing horizons, and under utilization of 3D seismic techniques. This study has shown many areas are prospective for additional discoveries in lower Paleozoic strata in the Illinois Basin. This project implemented a systematic basin analysis approach that is expected to encourage exploration for petroleum in lower Paleozoic rocks of the Illinois Basin. The study has compiled and presented a broad base of information and knowledge needed by independent oil companies to pursue the development of exploration prospects in overlooked, deeper play horizons in the Illinois Basin. Available geologic data relevant for the exploration and development of petroleum reservoirs in the Illinois Basin was analyzed and assimilated into a coherent, easily accessible digital play portfolio. The primary focus of this project was on case studies of existing reservoirs in Devonian, Silurian, and Ordovician strata and the application of knowledge gained to future exploration and development in these underexplored strata of the Illinois Basin. In addition, a review of published reports and exploration in the New Albany Shale Group, a Devonian black shale source rock, in Illinois was completed due to the recent increased interest in Devonian black shales across the United States. The New Albany Shale is regarded as the source rock for petroleum in Silurian and younger strata in the Illinois Basin and has potential as a petroleum reservoir. Field studies of reservoirs in Devonian strata such as the Geneva Dolomite, Dutch Creek Sandstone and Grassy knob Chert suggest that there is much additional potential for expanding these plays beyond their current limits. These studies also suggest the potential for the discovery of additional plays using stratigraphic concepts to develop a subcrop play on the subkaskaskia unconformity boundary that separates lower Devonian strata from middle Devonian strata in portions of the basin. The lateral transition from Geneva Dolomite to Dutch Creek Sandstone also offers an avenue for developing exploration strategies in middle Devonian strata. Study of lower Devonian strata in the Sesser Oil Field and the region surrounding the field shows opportunities for development of a subcrop play where lower Devonian strata unconformably overlie Silurian strata. Field studies of Silurian reservoirs along the Sangamon Arch show that opportunities exist for overlooked pays in areas where wells do not penetrate deep enough to test all reservoir intervals in Niagaran rocks. Mapping of Silurian reservoirs in the Mt. Auburn trend along the Sangamon Arch shows that porous reservoir rock grades laterally to non-reservoir facies and several reservoir intervals may be encountered in the Silurian with numerous exploration wells testing only the uppermost reservoir intervals. Mapping of the Ordovician Trenton and shallower strata at Centralia Field show that the crest of the anticline shifted through geologic time. This study illustrates that the axes of anticlines may shift with depth and shallow structure maps may not accurately predict structurally favorable reservoir locations at depth.

  3. GEOGRAPHIC INFORMATION SYSTEM APPROACH FOR PLAY PORTFOLIOS TO IMPROVE OIL PRODUCTION IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Beverly Seyler; John Grube

    2004-12-10

    Oil and gas have been commercially produced in Illinois for over 100 years. Existing commercial production is from more than fifty-two named pay horizons in Paleozoic rocks ranging in age from Middle Ordovician to Pennsylvanian. Over 3.2 billion barrels of oil have been produced. Recent calculations indicate that remaining mobile resources in the Illinois Basin may be on the order of several billion barrels. Thus, large quantities of oil, potentially recoverable using current technology, remain in Illinois oil fields despite a century of development. Many opportunities for increased production may have been missed due to complex development histories, multiple stacked pays, and commingled production which makes thorough exploitation of pays and the application of secondary or improved/enhanced recovery strategies difficult. Access to data, and the techniques required to evaluate and manage large amounts of diverse data are major barriers to increased production of critical reserves in the Illinois Basin. These constraints are being alleviated by the development of a database access system using a Geographic Information System (GIS) approach for evaluation and identification of underdeveloped pays. The Illinois State Geological Survey has developed a methodology that is being used by industry to identify underdeveloped areas (UDAs) in and around petroleum reservoirs in Illinois using a GIS approach. This project utilizes a statewide oil and gas Oracle{reg_sign} database to develop a series of Oil and Gas Base Maps with well location symbols that are color-coded by producing horizon. Producing horizons are displayed as layers and can be selected as separate or combined layers that can be turned on and off. Map views can be customized to serve individual needs and page size maps can be printed. A core analysis database with over 168,000 entries has been compiled and assimilated into the ISGS Enterprise Oracle database. Maps of wells with core data have been generated. Data from over 1,700 Illinois waterflood units and waterflood areas have been entered into an Access{reg_sign} database. The waterflood area data has also been assimilated into the ISGS Oracle database for mapping and dissemination on the ArcIMS website. Formation depths for the Beech Creek Limestone, Ste. Genevieve Limestone and New Albany Shale in all of the oil producing region of Illinois have been calculated and entered into a digital database. Digital contoured structure maps have been constructed, edited and added to the ILoil website as map layers. This technology/methodology addresses the long-standing constraints related to information access and data management in Illinois by significantly simplifying the laborious process that industry presently must use to identify underdeveloped pay zones in Illinois.

  4. No corrosion caused by coal chlorine found in AFBC pilot scale tests

    SciTech Connect (OSTI)

    Ho, K.; Pan, W.P.; Riley, J.T.; Liu, K.; Smith, S.

    2000-07-01

    Measurements of deposition and corrosion were made in the freeboard of a 3 m inner diameter pilot scale atmospheric fluidized-bed combustor (AFBC) during seven 1,000-hours tests using coals with chlorine (Cl) contents ranging from 0.026% up to 0.47% and sulfur contents ranging from 0.897{approximately}4.4%. Uncooled coupons of alloys 304, 309, 347 and a cooled tube of A210C medium carbon steel were exposed to the hot flue gases to investigate the effects of different coal compositions on deposition and corrosion behavior, if any. The uncooled coupons were installed at the tope of the freeboard to simulate the superheater tube conditions (1,020--1,100 F surface temperature), while the temperature of the cooled A210C test tube was controlled to match the conditions of the evaporator tubes. Specimens were removed for examination after 250, 500, 750, 1,000 hours of exposure and analyzed for deposit formation and corrosion. No chlorine was found in the corrosion scale or on the metal surfaces after any of the tests. High sulfur contents were found in the outer parts of the deposits, and appeared to be associated with calcium and magnesium suggesting that the fly ash may react further after being deposited on the surface of the metal. It was concluded that the limestone bed in the AFBC not only can capture the sulfur but also can effectively capture chlorine. This effect helps being the Cl in the AFBC flue gas down to a level of <50 ppm which is significantly lower than the 300{approximately}400 ppm expected from combustion of the coal in the absence of limestone. This reduction in chlorine species in the gas phase has possible implications for decreased corrosion problems not only in the freeboard, but also in the cold end of the boiler. No evidence was found in these tests that metal wastage or corrosion was accelerated, either directly or indirectly, by chlorine in the coal.

  5. Extending the radial diffusion model of Falthammar to non-dipole background field

    SciTech Connect (OSTI)

    Cunningham, Gregory Scott

    2015-05-26

    A model for radial diffusion caused by electromagnetic disturbances was published by Falthammar (1965) using a two-parameter model of the disturbance perturbing a background dipole magnetic field. Schulz and Lanzerotti (1974) extended this model by recognizing the two parameter perturbation as the leading (non--dipole) terms of the Mead Williams magnetic field model. They emphasized that the magnetic perturbation in such a model induces an electric ield that can be calculated from the motion of field lines on which the particles are frozen. Roederer and Zhang (2014) describe how the field lines on which the particles are frozen can be calculated by tracing the unperturbed field lines from the minimum-B location to the ionospheric footpoint, and then tracing the perturbed field (which shares the same ionospheric footpoint due to the frozen -in condition) from the ionospheric footpoint back to a perturbed minimum B location. The instantaneous change n Roederer L*, dL*/dt, can then be computed as the product (dL*/dphi)*(dphi/dt). dL*/Dphi is linearly dependent on the perturbation parameters (to first order) and is obtained by computing the drift across L*-labeled perturbed field lines, while dphi/dt is related to the bounce-averaged gradient-curvature drift velocity. The advantage of assuming a dipole background magnetic field, as in these previous studies, is that the instantaneous dL*/dt can be computed analytically (with some approximations), as can the DLL that results from integrating dL*/dt over time and computing the expected value of (dL*)^2. The approach can also be applied to complex background magnetic field models like T89 or TS04, on top of which the small perturbations are added, but an analytical solution is not possible and so a numerical solution must be implemented. In this talk, I discuss our progress in implementing a numerical solution to the calculation of DL*L* using arbitrary background field models with simple electromagnetic perturbations.

  6. Improved characterization of reservoir behavior by integration of reservoir performances data and rock type distributions

    SciTech Connect (OSTI)

    Davies, D.K.; Vessell, R.K.; Doublet, L.E.

    1997-08-01

    An integrated geological/petrophysical and reservoir engineering study was performed for a large, mature waterflood project (>250 wells, {approximately}80% water cut) at the North Robertson (Clear Fork) Unit, Gaines County, Texas. The primary goal of the study was to develop an integrated reservoir description for {open_quotes}targeted{close_quotes} (economic) 10-acre (4-hectare) infill drilling and future recovery operations in a low permeability, carbonate (dolomite) reservoir. Integration of the results from geological/petrophysical studies and reservoir performance analyses provide a rapid and effective method for developing a comprehensive reservoir description. This reservoir description can be used for reservoir flow simulation, performance prediction, infill targeting, waterflood management, and for optimizing well developments (patterns, completions, and stimulations). The following analyses were performed as part of this study: (1) Geological/petrophysical analyses: (core and well log data) - {open_quotes}Rock typing{close_quotes} based on qualitative and quantitative visualization of pore-scale features. Reservoir layering based on {open_quotes}rock typing {close_quotes} and hydraulic flow units. Development of a {open_quotes}core-log{close_quotes} model to estimate permeability using porosity and other properties derived from well logs. The core-log model is based on {open_quotes}rock types.{close_quotes} (2) Engineering analyses: (production and injection history, well tests) Material balance decline type curve analyses to estimate total reservoir volume, formation flow characteristics (flow capacity, skin factor, and fracture half-length), and indications of well/boundary interference. Estimated ultimate recovery analyses to yield movable oil (or injectable water) volumes, as well as indications of well and boundary interference.

  7. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  8. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  9. UIC permitting process for class IID and Class III wells: Protection of drinking water in New York State

    SciTech Connect (OSTI)

    Hillenbrand, C.J.

    1995-09-01

    The U.S. Environmental Protection Agency (EPA) Region II, Underground Injection Control (UIC) Program regulates injection wells in the State of New York to protect drinking water; UIC regulations can be found under Title 40 of the Code of Federal Regulations Parts 124, 144, 146 and 147. Operators of solution mining injection wells (UIC Class IIIG) and produced fluid disposal wells (UIC Class IID) are required to obtain an UIC permit for authorization to inject. The permitting process requires submittal of drinking water, geologic and proposed operational data in order to assure that pressure build-up within the injection zone will not compromise confining layers and allow vertical migration of fluid into Underground Sources of Drinking Water (USDW). Additional data is required within an Area of Review (AOR), defined as an area determined by the intersection of the adjusted potentiometric surface produced by injection and a depth 50 feet below the base of the lowermost USDW, or a radius of 1/4 mile around the injection well, whichever is greater. Locations of all wells in the AOR must be identified, and completion reports and plugging reports must be submitted. Requirements are set for maximum injection pressure and flow rates, monitoring of brine properties of the injection well and monitoring of water supply wells in the AOR for possible contamination. Any noncompliance with permit requirements constitutes a violation of the Safe Drinking Water Act and is grounds for enforcement action, including possible revocation of permit. Presently four Class IID wells are authorized under permit in New York State. The Queenston sandstone, Medina sandstone, Salina B, Akron dolomite and Oriskany sandstone have been used for brine disposal; the lower Ordovician-Cambrian section is currently being considered as an injection zone. Over one hundred Class IIIG wells are authorized under permit in New York State and all have been utilized for solution mining of the Syracuse salt.

  10. Gas reservoir potential of the Lower Ordovician Beekmantown Group, Quebec Lowlands, Canada discussion

    SciTech Connect (OSTI)

    Friedman, G.M.

    1996-10-01

    Dykstra and Longman (1995), in an interesting paper, discussed the gas-reservoir potential of the Lower Ordovician Beekmantown Group of Quebec, Canada. They pointed out that the dolomites of this group provide an important exploration target in both the autochthon and the overlying thrust sheets. They then compare their rocks with those of correlative units in Oklahoma. Nowhere in their paper do they relate their study to the extensive work on these same rocks in the contiguous parts of the same basin in neighboring New York state. The purpose of this discussion is to fill in this lack and provide information on prospective Cambrian-Ordovician reservoirs in New York state, for which the Oil and Gas Investor (Anonymous, 1995a) has predicted counties of western New York are the next frontier for the Cambrian-Ordovician play. Dykstra and Longman (1995) compare their Quebec rocks with those of correlative rocks in faraway Oklahoma and completely overlook those in the same basin in nearby New York. At least one of the boreholes that we have studied in the St. Lawrence Valley is only tens of miles from their boreholes (Harris and Friedman, 1982). During the past 31 yr our team alone has published at least 50 papers and abstracts on the surface and subsurface geology of the Beekmantown Group in New York state. Dykstra and Longman`s (1995) paper provides data identical to those we have obtained for the contiguous New York Beekmantown (for a partial reference list see Friedman, 1993, 1994a, b, 1995). Because no reference to New York state is included in their reference section, I want to quote from an abstract titled {open_quotes}Gas Potential of the Eastern Overthrust...New York{close_quotes}(Friedman, s1992), which compares with their title {open_quotes}Gas Reservoir Potential...of Quebec, Canada{close_quotes} (Dykstra and Longman, 1995).

  11. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  12. Surveillance of Site A and Plot M report for 1997

    SciTech Connect (OSTI)

    Golchert, N.M.

    1998-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for 1997 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976--1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to: (1) monitor the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  13. Surveillance of Site A and Plot M

    SciTech Connect (OSTI)

    Golchert, N.W.

    1993-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for CY 1992 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976--1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) determine the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  14. Surveillance of site A and plot M, report for 2007.

    SciTech Connect (OSTI)

    Golchert, N. W.; ESH /QA Oversight

    2008-03-25

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for Calendar Year 2007 are presented. Based on the results of the 1976-1978 radiological characterization of the site, a determination was made that a surveillance program be established. The characterization study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand pumped picnic wells. The current surveillance program began in 1980 and consists of sample collection and analysis of surface and subsurface water. The results of the analyses are used to: (1) monitor the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if other buried radionuclides have migrated, and (3) monitor the presence of radioactive materials in the environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Hydrogen-3 continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  15. Surveillance of Site A and Plot M. Report for 1992

    SciTech Connect (OSTI)

    Golchert, N.W.

    1993-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for CY 1992 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976--1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) determine the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  16. Surveillance of Site A and Plot M, Report for 2008.

    SciTech Connect (OSTI)

    Golchert, N. W.

    2009-05-07

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for Calendar Year 2008 are presented. Based on the results of the 1976-1978 radiological characterization of the site, a determination was made that a surveillance program be established. The characterization study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand pumped picnic wells. The current surveillance program began in 1980 and consists of sample collection and analysis of surface and subsurface water. The results of the analyses are used to (1) monitor the migration pathway of hydrogen-3 contaminated water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if other buried radionuclides have migrated, and (3) monitor for the presence of radioactive materials in the environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Hydrogen-3 continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  17. Surveillance of Site A and Plot M. Report for 1996

    SciTech Connect (OSTI)

    Golchert, N.W.

    1997-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for 1996 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) monitor the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  18. Surveillance of Site A and Plot M - Report for 2006.

    SciTech Connect (OSTI)

    Golchert, N. W.; ESH /QA Oversight

    2007-05-07

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for Calendar Year 2006 are presented. Based on the results of the 1976-1978 radiological characterization of the site, a determination was made that a surveillance program be established. The characterization study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current surveillance program began in 1980 and consists of sample collection and analysis of surface and subsurface water. The results of the analyses are used to (1) monitor the migration pathway of water from the burial ground (PlotM) to the hand pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) monitor the presence of radioactive and chemically hazardous materials in the environment of the area. Hydrogen-3 in the Red GateWoods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Hydrogen-3 continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  19. Surveillance of Site A and Plot M - report for 1993

    SciTech Connect (OSTI)

    Golchert, N.W.

    1994-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for CY 1993 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) determine the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  20. Surveillance of Site A and Plot M report for 1994

    SciTech Connect (OSTI)

    Golchert, N.W.

    1995-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for 1994 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) monitor the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  1. Surveillance of Site A and Plot M report for 1995

    SciTech Connect (OSTI)

    Golchert, N.W.

    1996-06-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for 1995 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) monitor the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. For many years it was the only radionuclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  2. Surveillance of Site A and Plot M - Report for 2005.

    SciTech Connect (OSTI)

    Golchert, N. W.; ESH /QA Oversight

    2006-04-10

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for Calendar Year 2005 are presented. Based on the results of the 1976-1978 radiological characterization of the site, a determination was made that a surveillance program be established. The characterization study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby handpumped picnic wells. The current surveillance program began in 1980 and consists of sample collection and analysis of surface and subsurface water. The results of the analyses are used to (1) monitor the migration pathway of water from the burial ground (Plot M) to the handpumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) monitor the presence of radioactive and chemically hazardous materials in the environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Hydrogen-3 continues to be detected in a number of wells, boreholes, dolomite holes, and a surface stream. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of boreholes next to Plot M. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site, using the picnic area, or living in the vicinity.

  3. Surveillance of Site A and Plot M report for 1991

    SciTech Connect (OSTI)

    Golchert, N.W.

    1992-05-01

    The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for CY 1991 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976--1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment. The results of the analyses are used to (1) determine the migration pathway of water from the burial ground (Plot M) to the hand-pumped picnic wells, (2) establish if buried radionuclides other than hydrogen-3 have migrated, and (3) generally characterize the radiological environment of the area. Hydrogen-3 in the Red Gate Woods picnic wells was still detected this year, but the average and maximum concentrations were significantly less than found earlier. Tritiated water continues to be detected in a number of wells, boreholes, dolomite holes, and surface stream. For many years it was the only radionclide found to have migrated in measurable quantities. Analyses since 1984 have indicated the presence of low levels of strontium-90 in water from a number of borehole next to Plot M. The available data does not allow a firm conclusion as to whether the presence of this nuclide represents recent migration or movement that may have occurred before Plot M was capped. The results of the surveillance program continue to indicate that the radioactivity remaining at Site A/Plot M does not endanger the health or safety of the public visiting the site or those living in the vicinity.

  4. CO{sub 2} Injectivity, Storage Capacity, Plume Size, and Reservoir and Seal Integrity of the Ordovician St. Peter Sandstone and the Cambrian Potosi Formation in the Illnois Basin

    SciTech Connect (OSTI)

    Hannes Leetaru; Alan Brown; Donald Lee; Ozgur Senel; Marcia Coueslan

    2012-05-01

    The Cambro-Ordovician strata of the Illinois and Michigan Basins underlie most of the states of Illinois, Indiana, Kentucky, and Michigan. This interval also extends through much of the Midwest of the United States and, for some areas, may be the only available target for geological sequestration of CO{sub 2}. We evaluated the Cambro-Ordovician strata above the basal Mt. Simon Sandstone reservoir for sequestration potential. The two targets were the Cambrian carbonate intervals in the Knox and the Ordovician St. Peter Sandstone. The evaluation of these two formations was accomplished using wireline data, core data, pressure data, and seismic data from the USDOE-funded Illinois Basin ?? Decatur Project being conducted by the Midwest Geological Sequestration Consortium in Macon County, Illinois. Interpretations were completed using log analysis software, a reservoir flow simulator, and a finite element solver that determines rock stress and strain changes resulting from the pressure increase associated with CO{sub 2} injection. Results of this research suggest that both the St. Peter Sandstone and the Potosi Dolomite (a formation of the Knox) reservoirs may be capable of storing up to 2 million tonnes of CO{sub 2} per year for a 20-year period. Reservoir simulation results for the St. Peter indicate good injectivity and a relatively small CO{sub 2} plume. While a single St. Peter well is not likely to achieve the targeted injection rate of 2 million tonnes/year, results of this study indicate that development with three or four appropriately spaced wells may be sufficient. Reservoir simulation of the Potosi suggest that much of the CO{sub 2} flows into and through relatively thin, high permeability intervals, resulting in a large plume diameter compared with the St. Peter.

  5. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect (OSTI)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation C. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation C sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  6. Natural-analog studies for partial validation of conceptual models of radionuclide retardation at the Waste Isolation Pilot Plant (WIPP)

    SciTech Connect (OSTI)

    Ward, D.B.; Brookins, D.G. . Dept. of Geology); Siegel, M.D.; Lambert, S.J. )

    1990-01-01

    Transport by groundwater within the Culebra Dolomite, an aquifer above the Waste Isolation Pilot Plant (WIPP), is the most probable mechanism for long-term release of radionuclides to the accessible environment. Radionuclides could be retarded by sorption if the groundwater is exposed to sufficient amounts of fracture-lining clays. In this natural-analog study, distributions of U and trace metals have been examined to constrain the strength of clay/solute interactions within the Culebra. Uranium solid/liquid distribution ratios, calculated from U concentrations of groundwaters and consanguineous fracture-filling clays, range from {approximately}80 to 800 m{ell}/g and imply retardation factors of 60 to 500 using a fracture-flow model. Retardation factors inferred from uranium-series disequilibria and {sup 14}C ages in Culebra groundwaters alone are much lower ({approximately}10), implying that clays may contain a significant unreactive component of U. Such a possibility is corroborated by Rb/Sr ages; these imply long-term stability of the clays,with resetting occurring more than 250 Ma ago. Factor analysis and mass-balance calculations suggest, however, that Mg-rich clays are dissolving in Pleistocene-age groundwaters and/or are converting to Na-rich smectites, and that B and Li are taken up from the water by the clays. Apparently, the solution chemistry reflects gradual equilibration of clays with groundwater, but thus far the bulk of the clays remain structurally intact. Measurements of the distribution of U in the Culebra will be more meaningful if the inert and exchangeable components of the U content of the clays can be quantified. 26 refs., 3 figs., 2 tabs.

  7. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  8. Groundwater geochemical modeling and simulation of a breached high-level radioactive waste repository in the northern Tularosa Basin, New Mexico

    SciTech Connect (OSTI)

    Chappell, R.W.

    1989-01-01

    The northern Tularosa Basin in south-central New Mexico was ranked favorably as a potential location for a high-level radioactive waste repository by a US Geological Survey pilot screening study of the Basin and Range Province. The favorable ranking was based chiefly on hydrogeologic and descriptive geochemical evidence. A goal of this study was to develop a methodology for predicting the performance of this or any other basin as a potential repository site using geochemical methods. The approach involves first characterizing the groundwater geochemistry, both chemically and isotopically, and reconstructing the probable evolutionary history of, and controls on the ground water chemistry through modeling. In the second phase of the approach, a hypothetically breached repository is introduced into the system, and the mobility of the parent radionuclide, uranium, in the groundwater is predicted. Possible retardation of uranium transport in the downgradient flow direction from the repository by adsorption and mineral precipitation is then considered. The Permian Yeso Formation, the primary aquifer in the northern Tularosa Basin, was selected for study, development and testing of the methodology outlined above. The Yeso Formation contains abundant gypsum and related evaporite minerals, which impart a distinctive chemical signature to the ground water. Ground water data and solubility calculations indicate a conceptual model of irreversible gypsum and dolomite dissolution with concomitant calcite precipitation. Recharge areas are apparent from temperature, {delta}{sup 18}O and {delta}{sup 2} H, and {sup 3}H trends in the aquifer. Corrected {sup 14}C ages range between modern and 31,200 years, and suggest an average ground water velocity of 0.83 m/yr.

  9. Surfactant Based Enhanced Oil Recovery and Foam Mobility Control

    SciTech Connect (OSTI)

    George J. Hirasaki; Clarence A. Miller; Gary A. Pope

    2005-07-01

    Surfactant flooding has the potential to significantly increase recovery over that of conventional waterflooding. The availability of a large number of surfactant structures makes it possible to conduct a systematic study of the relation between surfactant structure and its efficacy for oil recovery. A combination of two surfactants was found to be particularly effective for application in carbonate formations at low temperature. A formulation has been designed for a particular field application. The addition of an alkali such as sodium carbonate makes possible in situ generation of surfactant and significant reduction of surfactant adsorption. In addition to reduction of interfacial tension to ultra-low values, surfactants and alkali can be designed to alter wettability to enhance oil recovery. The design of the process to maximize the region of ultra-low IFT is more challenging since the ratio of soap to synthetic surfactant is a parameter in the conditions for optimal salinity. Compositional simulation of the displacement process demonstrates the interdependence of the various components for oil recovery. An alkaline surfactant process is designed to enhance spontaneous imbibition in fractured, oil-wet, carbonate formations. It is able to recover oil from dolomite core samples from which there was no oil recovery when placed in formation brine. Mobility control is essential for surfactant EOR. Foam is evaluated to improve the sweep efficiency of surfactant injected into fractured reservoirs. UTCHEM is a reservoir simulator specially designed for surfactant EOR. It has been modified to represent the effects of a change in wettability. Simulated case studies demonstrate the effects of wettability.

  10. Sedimentology and diagenesis of windward-facing fore-reef calcarenites, Late Pleistocene of Barbados, West Indies

    SciTech Connect (OSTI)

    Humphrey, J.D.; Kimbell, T.N.

    1989-03-01

    Late Pleistocene reef terraces in southeastern Barbardos developed extensive fore-reef sand facies during deposition in response to high-energy windward-facing conditions. Sedimentology and diagenesis of these deposits illustrate significant contrasts with previous studies from the leeward west coast. These calcarenites are dominantly skeletal packstones with less common grainstones and wackestones present. The fore-reef sand facies occurs within progradational reef sequences, being conformably overlain by deep-water head coral facies. Medium-bedded, laterally continuous sand sheets retain original depositional slopes, dipping seaward at 10/degrees/-15/degrees/. These fore-reef deposits, in places, are over 30 m thick (average 20 m) and developed rapidly during late Pleistocene glacio-eustatic sea level highstands. Sedimentation rate ranges from 2 to 5 m/1000 years. Areal extent of fore-reef calcarenites in southeastern Barbados is estimated to be 8-10 km/sup 2/. Lithologically, the packstones are composed of an abundance of coralline red algae and the benthic foraminifer Amphistegina sp. Other volumetrically significant allochems include echinoids, mollusks, rhodoliths, peloids, and micritized grains. Micrite in the wackestone and packstone lithologies is likely derived from intense physical/mechanical abrasion of shoal-water reef facies. Diagenesis of these lithologies reflects a complex interplay of meteoric, mixing zone, and marine environments as a result of glacio-eustasy. Differences in diagenetic character are derived from differences in terrace ages, terrace geometry, a paleotopographic control on meteoric ground-water distribution, and high-energy coastal conditions. Diagenetic fabrics include equant, blocky meteoric phreatic calcite; limpid dolomite of mixing zone origin: and peloidal and isopachous fibrous cements from marine precipitation.

  11. Iridium profile for 10 million years across the Cretaceous-Tertiary boundary at Gubbio (Italy)

    SciTech Connect (OSTI)

    Alvarez, W.; Montanari, A. ); Asaro, F. )

    1990-12-21

    The iridium anomaly at the Cretaceous-Tertiary (KT) boundary was discovered in the pelagic limestone sequence at Gubbio on the basis of 12 samples analyzed by neutron activation analysis (NAA) and was interpreted as indicating impact of a large extraterrestrial object at exactly the time of the KT mass extinction. Continuing controversy over the shape of the Ir profile at the Gubbio KT boundary and its interpretation called for a more detailed follow-up study. Analysis of a 57-meter-thick, 10-million-year-old part of the Gubbio sequence using improved NAA techniques revealed that there is only one Ir anomaly at the KT boundary, but this anomaly shows an intricate fine structure, the origin of which cannot yet be entirely explained. The KT Ir anomaly peaks in a 1-centimeter-thick clay layer, where the average Ir concentration is 3,000 parts per trillion (ppt); this peak is flanked by tails with Ir concentrations of 20 to 80 ppt that rise above a background of 12 to 13 ppt. The fine structure of the tails is probably due in part to lateral reworking, diffusion, burrowing, and perhaps Milankovitch cyclicity.

  12. Bioclastic turbiditic reservoirs: San Giorgio, Santa Maria Mare, Sarago Mare fields (Italy)

    SciTech Connect (OSTI)

    Heritier, F.E.; Soudet, H.; Richert, J.

    1987-05-01

    These three fields and the associated Mormora discovery are located along the coastline of the central Adriatic Sea or on the very proximate shelf south of Ancona. Geologically they belong to the Marches basin. These fields are situated on highly faulted northwest-trending anticlines which are related to a north-south shear zone under the disharmonic cover of late Miocene and early Pliocene shales. Oil and gas are contained in the Scaglia limestone formation of Late Cretaceous to Paleocene age whose reservoirs consist of high-energy bioclastic grainstones interbedded in open marine chalk deposits, and spread and deposited by turbiditic currents. The diagenesis of these bioclastic grainstones is closely related to the thickness and composition of the different beds and is chiefly located at the top and bottom of them. It is also related to the fluid content of the reservoir. Fracturing of these beds under the tectonic stresses is linked to the reservoir's characteristics and to the extension of consolidated facies by diagenesis. This fracturing is responsible for the production behavior of the different wells. Source rocks are the evaporitic shales of upper Miocene age, mature in the deeper part of the Marches basin under the upper Pliocene olistostromes.

  13. Synsedimentary tectonics in Late Cretaceous-Early Tertiary pelagic basin of northern Apennines, Italy

    SciTech Connect (OSTI)

    Montanari, A.; Chan, L.S.; Alvarez, W.

    1987-05-01

    The sequence of Upper Cretaceous-Lower Tertiary pelagic limestones in the Umbria-Marches Apennines of Italy have recorded, with remarkable continuity, the geologic history of an epeiric sea on the eastern continental margin of the Ligurian Ocean during a time of widespread tectonism in the western Tethys domain. Sedimentary facies and paleocurrent analyses indicate that intrabasinal depocenters and structural highs have formed in response to extensional tectonic movements which started to affect the central part of the paleobasin in the early Turonian. The topography of the paleobasin was probably controlled by a complex pattern of buried fault blocks formed during the passive margin phase of the western Tethys and then reactivated in the Turonian after a prolonged time (Aptian to Cenomanian) of tectonic quiescence. Calcareous turbidites essentially made of remobilized pelagic mud were generated on the newly formed intrabasinal slopes and deposited in the adjacent depocenters. Conspicuous sedimentary events such as maxima in turbiditic deposition and soft-sediment slumps in these intrabasinal depocenters are attributed to major syndepositional earthquakes of regional extent. A detailed event-stratigraphy based on these sedimentary features indicates that the level of syndepositional tectonic activity reached a peak in the late Maastrichtian-early Paleocene and rapidly diminished in the Eocene.

  14. Middle Triassic paleokarst surfaces and associated stratigraphic patterns in platform carbonates: Evidence from sedimentology and diagenesis, southern Alps, Italy

    SciTech Connect (OSTI)

    Mutti, M.; Jadoul, F. )

    1991-03-01

    Triassic carbonate platforms are superbly exposed in the Southern Alps. A regional paleokarst surface occurs in the Middle Triassic, at the Ladinian-Carnian stage boundary, and is well recognized throughout the Tethyan region. The authors describe the characteristics of the paleokarst and the stratigraphic patterns of the strata deposited immediately after the formation of the surface in the Brembana Valley. The paleokarst cuts up to tens of meters into the underlying Esino Limestone massive platform facies and forms a lens-shaped depression filled by peritidal cyclic facies intensively deformed in tepees. The origin of this geometry can be explained either as a tectonic-controlled feature or as a karst-processes related incised-valley associated to a major eustatic cycle. Depression-filling peritidal facies are intensively deformed in senile tepees and are periodically interbedded with 'terra rossa' soils and tend to pinchout at the margins of the depression. Several orders of cyclicity are recognized in peritidal carbonates. Diagenetic features are exceptionally complex and record a wide variety of superimposing environments ranging from normal marine to early meteoric and can be related to major cyclic stratigraphic patterns. Syndepositional cements form up to 80% of the present rock.

  15. Pattern of extensional faulting in pelagic carbonates of the Unbria-Marche Apennines of central Italy

    SciTech Connect (OSTI)

    Alvarez, W. )

    1990-05-01

    The Umbria-Marche Apennines provide a new region in which the nature passive-margin extensional faulting can be studied in outcrop. In these dominantly pelagic carbonate rocks of Jurassic and Cretaceous age, horsts acted as shallow, nonvolcani seamounts, while tilted half grabens formed deeper basins. One well-exposed seamount-basin transition agrees in general with the model of listric normal faulting and tilted half grabens, but shows interesting and significant divergences when studied in detail. A small sedimentary wedge at the faulted margin of a horst-block seamount thickens unexpectedly toward the adjacent basin. This wedge developed because of local convex-upward curvature of the shallowest part of a fault which at depth must have concave-up, listric geometry. The local sedimentary wedge resulted from deposition on the hanging wall as it tilted, followed by differential compaction of younger limestones that lapped onto the gentle slope leading from the horst-block seamount toward the basin. The map pattern of listric normal faulting in the Umbria-Marche Apennines suggests that both principal strain axes were extensional, in contrast to the usual pattern of listric faults crossed by transfer faults.

  16. Channelized fluid flow through shear zones during fluid-enhanced dynamic recrystallization, Northern Apennines, Italy

    SciTech Connect (OSTI)

    Carter, K.E.; Dworkin, S.I. )

    1990-08-01

    Geochemical and petrographic studies of the Triassic Portoro limestone of the Tuscan nappe in Liguria, Italy, indicate that fluid flow was channeled through interlayered bedding-parallel shear zones during Miocene shearing and low-grade metamorphism. Carbon, oxygen, and strontium isotopic compositions and trace element concentrations in the Portoro indicate that it was precipitated from normal marine waters. In sheared and unsheared layers these isotopic compositions are indistinguishable, yet sheared layers of microspar contain less than half the amount of strontium preserved in undeformed layers. Wavy grain boundaries and a dimensional preferred orientation of elongated grains indicate that calcite within sheared zones was dynamically recrystallized. On the basis of these observations we suggest that during burial, extraformational fluids were buffered into oxygen isotopic, but not strontium-concentration, equilibrium with the Portoro. These syndeformational fluids were channeled through discrete 1- to 15-cm-thick shear zones in which strontium was expelled from calcite and incorporated into grain-boundary fluids during dynamic recrystallization.

  17. Proximal impact deposits at the Cretaceous-Tertiary boundary in the Gulf of Mexico: A restudy of DSDP Leg 77 Sites 536 and 540

    SciTech Connect (OSTI)

    Alvarez, W.; Asaro, F. ); Smit, J. ); Lowrie, W. ); Asaro, F. ); Margolis, S.V.; Claeys, P. ); Kastner, M. ); Hildebrand, A.R. )

    1992-08-01

    Restudy of Deep Sea Drilling Project Sites 536 and 540 in the southeast Gulf of Mexico gives evidence for a giant wave at Cretaceous-Tertiary boundary time. Five units are recognized: (1) Cenomanian limestone underlies a hiatus in which the five highest Cretaceous stages are missing, possibly because of catastrophic K-T erosion. (2) Pebbly mudstone, 45 m thick, represents a submarine landslide possibly of K-T age. (3) Current-bedded sandstone, more than 2.5 m thick, contains anomalous iridium, tektite glass, and shocked quartz; it is interpreted as ejecta from a nearby impact crater, reworked on the deep-sea floor by the resulting tsunami. (4) A 50-cm interval of calcareous mudstone containing small Cretaceous planktic foraminifera and the Ir peak is interpreted as the silt-size fraction of the Cretaceous material suspended by the impact-generated wave. (5) Calcareous mudstone with basal Tertiary forams and the uppermost tail of the Ir anomaly overlies the disturbed interval, dating the impact and wave event as K-T boundary age. Like Beloc in Haiti and Mimbral in Mexico, Sites 536 and 540 are consistent with a large K-T age impact at the nearby Chicxulub crater.

  18. Folding associated with extensional faulting: Sheep Range detachment, southern Nevada

    SciTech Connect (OSTI)

    Guth, P.L.

    1985-01-01

    The Sheep Range detachment is a major Miocene extensional fault system of the Great Basin. Its major faults have a scoop shape, with straight, N-S traces extending 15-30 km and then abruptly turning to strike E-W. Tertiary deformation involved simultaneous normal faulting, sedimentation, landsliding, and strike-slip faulting. Folds occur in two settings: landslide blocks and drag along major faults. Folds occur in landslide blocks and beneath them. Most folds within landslide blocks are tight anticlines, with limbs dipping 40-60 degrees. Brecciation of the folds and landslide blocks suggests brittle deformation. Near Quijinump Canyon in the Sheep Range, at least three landslide blocks (up to 500 by 1500 m) slid into a small Tertiary basin. Tertiary limestone beneath the Paleozoic blocks was isoclinally folded. Westward dips reveal drag folds along major normal faults, as regional dips are consistently to the east. The Chowderhead anticline is the largest drag fold, along an extensional fault that offsets Ordovician units 8 km. East-dipping Ordovician and Silurian rocks in the Desert Range form the hanging wall. East-dipping Cambrian and Ordovician units in the East Desert Range form the foot wall and east limb of the anticline. Caught along the fault plane, the anticline's west-dipping west limb contains mostly Cambrian units.

  19. Chemical Engineering Division research highlights, 1979

    SciTech Connect (OSTI)

    Burris, L.; Webster, D. S.; Barney, D. L.; Cafasso, F. A.; Steindler, M. J.

    1980-06-01

    In 1979, CEN conducted research and development in the following areas: (1) high-temperature, rechargeable lithium/iron sulfide batteries for electric vehicles and electric utility load leveling; (2) ambient-temperature batteries - improved lead-acid, nickel/zinc, and nickel/iron - for electric vehicles; (3) molten carbonate fuel cells for use by electric utilities; (4) coal technology - mainly fluidized-bed combustion of coal in the presence of SO/sub 2/ sorbent of limestone; (5) heat- and seed- recovery technology for open-cycle magnetohydrodynamic systems; (6) solar energy collectors and thermal energy storage; (7) fast breeder reactor chemistry research - chemical support of reactor safety studies, chemistry of irradiated fuels, and sodium technology; (8) fuel cycle technology - reprocessing of nuclear fuels, management of nuclear wastes, geologic migration studies, and proof-of-breeding studies for the Light Water Breeder Reactor; (9) magnetic fusion research - lithium processing technology and materials research; and (10) basic energy sciences - homogeneous catalysis, thermodynamics of inorganic and organic materials, environmental chemistry, electrochemistry, and physical properties of salt vapors. Separate abstracts were prepared for each of these areas.

  20. Cold-Air-Pool Structure and Evolution in a Mountain Basin: Peter Sinks, Utah

    SciTech Connect (OSTI)

    Clements, Craig B.; Whiteman, Charles D.; Horel, John D.

    2003-06-01

    The evolution of potential temperature and wind structure during the buildup of nocturnal cold-air pools was investigated during clear, dry, September nights in Utah's Peter Sinks basin, a 1-km-diameter limestone sinkhole that holds the Utah minimum temperature record of -56 C. The evolution of cold-pool characteristics depended on the strength of prevailing flows above the basin. On an undisturbed day, a 30 C diurnal temperature range and a strong nocturnal potential temperature inversion (22 K in 100 m) were observed in the basin. Initially, downslope flows formed on the basin sidewalls. As a very strong potential temperature jump (17 K) developed at the top of the cold pool, however, the winds died within the basin and over the sidewalls. A persistent turbulent sublayer formed below the jump. Turbulent sensible heat flux on the basin floor became negligible shortly after sunset while the basin atmosphere continued to cool. Temperatures over the slopes, except for a 1 to 2-m-deep layer, became warmer than over the basin center at the same altitude. Cooling rates for the entire basin near sunset were comparable to the 90 W m-2 rate of loss of net longwave radiation at the basin floor, but these rates decreased to only a few watts per square meter by sunrise. This paper compares the observed cold-pool buildup in basins with inversion buildup in valleys.

  1. Site characterization of the highest-priority geologic formations for CO2 storage in Wyoming

    SciTech Connect (OSTI)

    Surdam, Ronald C.; Bentley, Ramsey; Campbell-Stone, Erin; Dahl, Shanna; Deiss, Allory; Ganshin, Yuri; Jiao, Zunsheng; Kaszuba, John; Mallick, Subhashis; McLaughlin, Fred; Myers, James; Quillinan, Scott

    2013-12-07

    This study, funded by U.S. Department of Energy National Energy Technology Laboratory award DE-FE0002142 along with the state of Wyoming, uses outcrop and core observations, a diverse electric log suite, a VSP survey, in-bore testing (DST, injection tests, and fluid sampling), a variety of rock/fluid analyses, and a wide range of seismic attributes derived from a 3-D seismic survey to thoroughly characterize the highest-potential storage reservoirs and confining layers at the premier CO2 geological storage site in Wyoming. An accurate site characterization was essential to assessing the following critical aspects of the storage site: (1) more accurately estimate the CO2 reservoir storage capacity (Madison Limestone and Weber Sandstone at the Rock Springs Uplift (RSU)), (2) evaluate the distribution, long-term integrity, and permanence of the confining layers, (3) manage CO2 injection pressures by removing formation fluids (brine production/treatment), and (4) evaluate potential utilization of the stored CO2

  2. 3-D description of fracture surfaces and stress-sensitivity analysis for naturally fractured reservoirs

    SciTech Connect (OSTI)

    Zhang, S.Q.; Jioa, D.; Meng, Y.F.; Fan, Y.

    1997-08-01

    Three kinds of reservoir cores (limestone, sandstone, and shale with natural fractures) were used to study the effect of morphology of fracture surfaces on stress sensitivity. The cores, obtained from the reservoirs with depths of 2170 to 2300 m, have fractures which are mated on a large scale, but unmated on a fine scale. A specially designed photoelectric scanner with a computer was used to describe the topography of the fracture surfaces. Then, theoretical analysis of the fracture closure was carried out based on the fracture topography generated. The scanning results show that the asperity has almost normal distributions for all three types of samples. For the tested samples, the fracture closure predicted by the elastic-contact theory is different from the laboratory measurements because plastic deformation of the aspirates plays an important role under the testing range of normal stresses. In this work, the traditionally used elastic-contact theory has been modified to better predict the stress sensitivity of reservoir fractures. Analysis shows that the standard deviation of the probability density function of asperity distribution has a great effect on the fracture closure rate.

  3. Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

    SciTech Connect (OSTI)

    Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

    2003-11-15

    The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

  4. Bahamian Pleistocene model for some Mississippian oolites

    SciTech Connect (OSTI)

    Bain, R.J. (Univ. of Akron, OH (USA))

    1989-08-01

    San Salvador Island, unlike most Bahamian islands, is a narrow isolated platform surrounded by deep ocean. Therefore, sedimentary deposits on San Salvador must be explained in terms of processes and settings on this narrow, isolated shelf. Pleistocene oolite occurs between Illinoian and Wisconsinan paleosols. Dune ridges of up to 120 ft are composed of Pleistocene cross-bedded oolitic grainstone, whereas interdunal deposits are bioclastic packstone and wackestone containing abundant Chione cancellata. In lower dunal deposits, bioclastic content increases and the degree of sorting decreases. A fenestral porosity zone occurs approximately 5 ft above present-day sea level. In several ridges, oolite drapes over older paleosol-capped bioclastic ridges. During the Sangamonian, sea water flooded the platform, however some remnant Aftonian ridges remained above sea level. As cold water from the surrounding deep ocean warmed on the shelf, ooids were generated and were washed onto beaches and blown into dunes. Remnant ridges restricted water movement and acted as nucleii for eolian ooid dunes. As sea level continued to rise, ooids were replaced by lagoonal bioclastic deposits. Ooid production was restricted to the swash zone along beaches resulting in the mixture of ooids and bioclastic sand in later Sangamonian deposits. Numerous Mississippian oolites display features similar to the Pleistocene oolite of San Salvador Island. Possible comparisons include thick lenses of Ste. Genevieve and Bangor limestones, paleosols in the Ste. Genevieve halo-shaped bodies of Greenbrier oolite, and the relationship of nearly all olites with bioclastic facies.

  5. ACOUSTICAL IMAGING AND MECHANICAL PROPERTIES OF SOFT ROCK AND MARINE SEDIMENTS

    SciTech Connect (OSTI)

    Thurman E. Scott, Jr., Ph.D.; Younane Abousleiman, Ph.D.; Musharraf Zaman, Ph.D., P.E.

    2001-01-31

    During this phase of the project the research team concentrated on acquisition of acoustic emission data from the high porosity rock samples. The initial experiments indicated that the acoustic emission activity from high porosity Danian chalk were of a very low amplitude. Even though the sample underwent yielding and significant plastic deformation the sample did not generate significant AE activity. This was somewhat surprising. These initial results call into question the validity of attempting to locate AE activity in this weak rock type. As a result the testing program was slightly altered to include measuring the acoustic emission activity from many of the rock types listed in the research program. The preliminary experimental results indicate that AE activity in the sandstones is much higher than in the carbonate rocks (i.e., the chalks and limestones). This observation may be particularly important for planning microseismic imaging of reservoir rocks in the field environment. The preliminary results suggest that microseismic imaging of reservoir rock from acoustic emission activity generated from matrix deformation (during compaction and subsidence) would be extremely difficult to accomplish.

  6. Sorbent preparation/modification/additives. Final report, September 1, 1992--November 30, 1993

    SciTech Connect (OSTI)

    Prudich, M.E.; Venkataramakrishnan, R.

    1994-02-01

    Sorbent preparation techniques used today have generally been adapted from techniques traditionally used by the lime industry. Traditional dry hydration and slaking processes have been optimized to produce materials intended for use in the building industry. These preparation techniques should be examined with an eye to optimization of properties important to the SO{sub 2} capture process. The study of calcium-based sorbents for sulfur dioxide capture is complicated by two factors: (1) little is known about the chemical mechanisms by which the standard sorbent preparation and enhancement techniques work, and (2) a sorbent preparation technique that produces a calcium-based sorbent that enjoys enhanced calcium utilization in one regime of operation [flame zone (>2400 F), in-furnace (1600--2400 F), economizer (800--1100 F), after air preheater (<350 F)] may not produce a sorbent that enjoys enhanced calcium utilization in the other reaction zones. Again, an in-depth understanding of the mechanism of sorbent enhancement is necessary if a systematic approach to sorbent development is to be used. As a long-term goal, an experimental program is being carried out for the purpose of (1) defining the effects of slaking conditions on the properties of calcium-based sorbents, (2) determining how the parent limestone properties of calcium-based sorbents, and (3) elucidating the mechanism(s) relating to the activity of various dry sorbent additives. An appendix contains a one-dimensional duct injection model with modifications to handle the sodium additives.

  7. Civil defense shelters: A state-of-the-art assessment, 1986

    SciTech Connect (OSTI)

    Chester, C.V.; Zimmerman, G.P.

    1987-02-01

    The literature on the design, construction, testing, and cost of blast and fallout shelters was reviewed, and a bibliography of over 1000 documents was assembled. It was found that nuclear weapon effects and shelter design are well understood. An important barrier to construction of permanent shelters is cost. Single-purpose shelters cost in the high hundreds to low thousands of dollars per occupant (or per space), depending on size, hardness, location, and whether the shelter is part of new construction or retrofit. Multiplied by a risk area population of approximately 160 million, the cost of a blast shelter construction program would rival that of a major strategic weapon system. Options in the mid-range of expense, a few tens to a few hundreds of dollars per space include (1) requiring modified limestone mining practices, where appropriate, to generate usable shelter space near cities; (2) encouraging the construction of earth-sheltered housing and other buildings; and (3) requiring and/or subsidizing the construction of dual-use basement shelter in new construction. A program using this approach would require an annual expenditure of approximately 1% of the annual defense budget for 10 or more years. 950 refs., 68 figs., 9 tabs.

  8. Civil defense shelters: a state-of-the-art assessment - 1986. Final report

    SciTech Connect (OSTI)

    Chester, C.V.; Zimmerman, G.P.

    1986-12-01

    The literature on the design, construction, testing, and cost of blast and fallout shelters was reviewed, and a bibliography of over 1000 documents was assembled. It was found that nuclear weapon effects and shelter design are well understood. The principal technical barrier to construction of permanent shelters is cost. Single-purpose blast shelters cost in the high hundreds to low thousands of dollars per space, depending on size, hardness, location, and whether the shelter is part of new construction or retrofit. The risk area population requiring blast protection is approximately 160 million. The very-low-cost options open to the U.S. Government, with its present civil defense budget, remain: (1) maintain the inventory on fallout shelter and identify space with some blast protection potential; (2) plan for crisis upgrading to improve existing space in a crisis, and (3) plan for construction of expedient shelter in a crisis. Fallout shelters might be mandated in appropriate new construction outside risk areas at little cost to the government. Options in the mid-range of expense, a few tens to a few hundreds of dollars per space include: (1) requiring modified limestone-mining practices, where appropriate, to generate useable shelter space near cities; (2) encouraging the construction of earth-sheltered housing and other buildings, and (3) requiring and/or subsidizing the construction of dual-use basement shelter in new construction.

  9. Co-Firing Oil Shale with Coal and Other Fuels for Improved Efficiency and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Robert A. Carrington; William C. Hecker; Reed Clayson

    2008-06-01

    Oil shale is an abundant, undeveloped natural resource which has natural sorbent properties, and its ash has natural cementitious properties. Oil shale may be blended with coal, biomass, municipal wastes, waste tires, or other waste feedstock materials to provide the joint benefit of adding energy content while adsorbing and removing sulfur, halides, and volatile metal pollutants, and while also reducing nitrogen oxide pollutants. Oil shale depolymerization-pyrolysis-devolatilization and sorption scoping studies indicate oil shale particle sorption rates and sorption capacity can be comparable to limestone sorbents for capture of SO2 and SO3. Additionally, kerogen released from the shale was shown to have the potential to reduce NOx emissions through the well established reburning chemistry similar to natural gas, fuel oil, and micronized coal. Productive mercury adsorption is also possible by the oil shale particles as a result of residual fixed-carbon and other observed mercury capture sorbent properties. Sorption properties were found to be a function particle heating rate, peak particle temperature, residence time, and gas-phase stoichmetry. High surface area sorbents with high calcium reactivity and with some adsorbent fixed/activated carbon can be produced in the corresponding reaction zones that exist in a standard pulverized-coal or in a fluidized-bed combustor.

  10. A feasibility study of oil shale fired pulse combustors with applications to oil shale retorting

    SciTech Connect (OSTI)

    Morris, G.J.; Johnson, E.K.; Zhang, G.Q.; Roach, R.A.

    1992-07-01

    The results of the experimental investigation performed to determine the feasibility of using pulverized Colorado oil shale to fuel a bench scale pulse combustor reveal that oil shale cannot sustain pulsations when used alone as fuel. Trace amounts of propane mixed with the oil shale enabled the pulsations, however. Up to 80% of the organic material in the oil shale was consumed when it was mixed with propane in the combustor. Beyond the feasibility objectives, the operating conditions of the combustor fuel with propane and mixtures of oil shale and propane were characterized with respect to pulsation amplitude and frequency and the internal combustor wall temperature over fuel lean and fuel rich stoichiometries. Maximum pressure excursions of 12.5 kPa were experienced in the combustor. Pulsation frequencies ranged from 50 to nearly 80 Hz. Cycle resolved laser Doppler anemometry velocities were measured at the tail pipe exit plane. Injecting inert mineral matter (limestone) into the pulse combustor while using propane fuel had only a slight effect on the pulsation frequency for the feed rates tested.

  11. A feasibility study of oil shale fired pulse combustors with applications to oil shale retorting. Final report

    SciTech Connect (OSTI)

    Morris, G.J.; Johnson, E.K.; Zhang, G.Q.; Roach, R.A.

    1992-07-01

    The results of the experimental investigation performed to determine the feasibility of using pulverized Colorado oil shale to fuel a bench scale pulse combustor reveal that oil shale cannot sustain pulsations when used alone as fuel. Trace amounts of propane mixed with the oil shale enabled the pulsations, however. Up to 80% of the organic material in the oil shale was consumed when it was mixed with propane in the combustor. Beyond the feasibility objectives, the operating conditions of the combustor fuel with propane and mixtures of oil shale and propane were characterized with respect to pulsation amplitude and frequency and the internal combustor wall temperature over fuel lean and fuel rich stoichiometries. Maximum pressure excursions of 12.5 kPa were experienced in the combustor. Pulsation frequencies ranged from 50 to nearly 80 Hz. Cycle resolved laser Doppler anemometry velocities were measured at the tail pipe exit plane. Injecting inert mineral matter (limestone) into the pulse combustor while using propane fuel had only a slight effect on the pulsation frequency for the feed rates tested.

  12. Physical and mechanical properties of bituminous mixtures containing oil shales

    SciTech Connect (OSTI)

    Katamine, N.M.

    2000-04-01

    Rutting of bituminous surfaces on the Jordanian highways is a recurring problem. Highway authorities are exploring the use of extracted shale oil and oil shale fillers, which are abundant in Jordan. The main objectives of this research are to investigate the rheological properties of shale oil binders (conventional binder with various percentages of shale oil), in comparison with a conventional binder, and to investigate the ability of mixes to resist deformation. The latter is done by considering three wearing course mixes containing three different samples of oil shale fillers--which contained three different oil percentages--together with a standard mixture containing limestone filler. The Marshall design method and the immersion wheel tracking machine were adopted. It was concluded that the shale oil binders displayed inconsistent physical properties and therefore should be treated before being used. The oil shale fillers have provided mixes with higher ability to resist deformation than the standard mix, as measured by the Marshall quotients and the wheel tracking machine. The higher the percentages of oil in the oil shale fillers, the lower the ability of the mixes to resist deformation.

  13. Production and blast-furnace smelting of boron-alloyed iron-ore pellets

    SciTech Connect (OSTI)

    A.A. Akberdin; A.S. Kim

    2008-08-15

    Industrial test data are presented regarding the production (at Sokolovsk-Sarbaisk mining and enrichment enterprise) and blast-furnace smelting (at Magnitogorsk metallurgical works) of boron-alloyed iron-ore pellets (500000 t). It is shown that, thanks to the presence of boron, the compressive strength of the roasted pellets is increased by 18.5%, while the strength in reduction is doubled; the limestone consumption is reduced by 11%, the bentonite consumption is halved, and the dust content of the gases in the last section of the roasting machines is reduced by 20%. In blast-furnace smelting, the yield of low-sulfur (<0.02%) hot metal is increased from 65-70 to 85.1% and the furnace productivity from 2.17-2.20 to 2.27 t/(m{sup 3} day); coke consumption is reduced by 3-8 kg/t of hot metal. The plasticity and stamping properties of 08IO auto-industry steel are improved by microadditions of boron.

  14. Power-plant fly-ash utilization: a chemical processing perspective

    SciTech Connect (OSTI)

    Burnet, G.; Murtha, M.J.

    1981-01-01

    The 1976 Resource Conservation and Recovery Act (RCRA) deals with the management of solid and hazardous wastes, and encourages energy and resource recovery. Recent research has indicated that solid wastes from coal combustion, including fly ash, could be classified as hazardous under present EPA definitions. The seriousness of this possibility has been recognized and new rules for coal ash waste disposal are being considered. Ames Laboratory research on fly ash utilization as an alternative to disposal includes extraction of metals from the ash and discovery of uses for the process residues. Recovery of alumina and iron oxides by physical and chemical processing would permit large scale utilization of fly ash and help reduce dependency on imports. One of the processes investigated uses a lime-soda sinter method to form soluble aluminate compounds from mixtures of fly ash, limestone, and soda ash. The aluminates are extracted, treated to remove silicates, and precipitated: the precipitate is calcined to metallurgical grade alumina. The extract residue shows promise as a raw material for the production of Portland cement. Process economics are presented, and the effects of alumina and silica contents of the fly ash, sintering temperatures and time, and sales credits for by-products are discussed.

  15. EXAFS of heavy metal coordination in acid mine drainage sediments

    SciTech Connect (OSTI)

    Carroll, S.; O`Day, P.; Waychunas, G.; Phillips, B.

    1995-12-01

    We use extended x-ray adsorption fine structure (EXAFS) spectroscopy to examine the chemical environment of zinc (1-2 wt. %), lead (300-600 ppm) and cadmium (50-200 ppm) in complex acid mine drainage sediments from the Tri-State Mining District (KS, MO, OK). The sediments in streams draining tailings piles and open mine shafts are dominated by quartz or amorphous iron hydroxides; accessory minerals include calcite. The bulk water chemistry is buffered by the limestone geology and is undersaturated with respect to pure heavy metal carbonates and hydroxides. EXAFS spectra of the sediment samples were taken at SSRL with a fluorescence detector at low temperature ({approximately}10 K). Heavy metals do not form pure carbonate or hydroxide phases, nor do they appear to sorb to quartz surfaces. In sediments near the mine source, the metals are present primarily as sulfides, the original host mineral. With increasing distance from the source, second-neighbor backscattering from Fe indicates that the metals leached from the sulfides are taken up with amorphous iron hydroxides.

  16. Latest research findings from petite sismique trials

    SciTech Connect (OSTI)

    Belesky, R.M.; Bieniawski, Z.T.; Greenfield, R.J.

    1984-01-01

    Research on a novel in-situ technique known as petite sismique is discussed. This geophysical method is capable of estimating the static deformation modules of a rock mass. The petite-sismique technique utilizes a seismic-refraction survey stressing a correlation between shear-wave frequency and the static deformation modulus. Although the technique was introduced in 1967, petite sismique has not been used extensively due to difficulties in shear-wave generation and detection. Recent developments in geophysical instrumentation provided an opportunity to evaluate better the technique in this study. With the objective of assessing the deformation modulus, field trials were conducted in coal and limestone mines. Despite attempts to develop a reliable shear-wave source, difficulties in frequency determinations persisted due to source characteristics and receiver resonance. A limited number of shear-wave-frequency observations did not confirm the originally documented relationship between shear-wave frequency and the static deformation modulus. The indicated discrepancy is attributed to differences in characteristics of the sources used in the two studies. Arising out of this research are equipment modifications and procedural recommendations which should improve the chances for success in future studies.

  17. Isotopic evidence of enhanced carbonate dissolution at a coal mine drainage site in Allegheny County, Pennsylvania, USA

    SciTech Connect (OSTI)

    Sharma, Shikha; Sack, Andrea; Adams, James P.; Vesper, Dorothy; J Capo, Rosemary C.; Hartsock, Angela; Edenborn, Harry M.

    2013-01-01

    Stable isotopes were used to determine the sources and fate of dissolved inorganic C (DIC) in the circumneutral pH drainage from an abandoned bituminous coal mine in western Pennsylvania. The C isotope signatures of DIC (?{sup 13}C{sub DIC}) were intermediate between local carbonate and organic C sources, but were higher than those of contemporaneous Pennsylvanian age groundwaters in the region. This suggests a significant contribution of C enriched in {sup 13}C due to enhanced carbonate dissolution associated with the release of H{sub 2}SO{sub 4} from pyrite oxidation. The Sr isotopic signature of the drainage was similar to other regional mine waters associated with the same coal seam and reflected contributions from limestone dissolution and cation exchange with clay minerals. The relatively high ?{sup 34}S{sub SO4} and ?{sup 18}O{sub SO4} isotopic signatures of the mine drainage and the presence of presumptive SO{sub 4}-reducing bacteria suggest that SO{sub 4} reduction activity also contributes C depleted in {sup 13}C isotope to the total DIC pool. With distance downstream from the mine portal, C isotope signatures in the drainage increased, accompanied by decreased total DIC concentrations and increased pH. These data are consistent with H{sub 2}SO{sub 4} dissolution of carbonate rocks, enhanced by cation exchange, and C release to the atmosphere via CO{sub 2} outgassing.

  18. Hydrology of the Melton Valley radioactive-waste burial grounds at Oak Ridge National Laboratory, Tennessee

    SciTech Connect (OSTI)

    Webster, D.A.; Bradley, M.W.

    1988-12-31

    Burial grounds 4, 5, and 6 were used sequentially from 1951 to the present for the disposal of solid, low-level radioactive waste by burial in shallow trenches and auger holes. Abundant rainfall, a generally thin unsaturated zone, geologic media of inherently low permeability, and the operational practices employed have contributed to partial saturation of the buried waste, leaching of radionuclides, and transport of dissolved matter from the burial areas. Two primary methods of transport from these sites are by dissolution in circulating ground water, and the overflow of fluids in trenches and subsequent flow across land surface. The waste-disposal areas are underlain by the Conasauga Group (Cambrian age), a complex sequence of mudstone, siltstone, and limestone interbeds grading from one lithotype to the other, both laterally and vertically. Compressional forces that caused regional thrust faulting also caused much internal deformation of the beds. Folds, bedding-plane faults, and joints are widespread. Small solution openings have developed in some areas where the structurally-related openings have provided ingress to ground water.

  19. 4-D High-Resolution Seismic Reflection Monitoring of Miscible CO2 Injected into a Carbonate Reservoir

    SciTech Connect (OSTI)

    Richard D. Miller; Abdelmoneam E. Raef; Alan P. Byrnes; William E. Harrison

    2007-06-30

    The objective of this research project was to acquire, process, and interpret multiple high-resolution 3-D compressional wave and 2-D, 2-C shear wave seismic data in the hopes of observing changes in fluid characteristics in an oil field before, during, and after the miscible carbon dioxide (CO{sub 2}) flood that began around December 1, 2003, as part of the DOE-sponsored Class Revisit Project (DOE No.DE-AC26-00BC15124). Unique and key to this imaging activity is the high-resolution nature of the seismic data, minimal deployment design, and the temporal sampling throughout the flood. The 900-m-deep test reservoir is located in central Kansas oomoldic limestones of the Lansing-Kansas City Group, deposited on a shallow marine shelf in Pennsylvanian time. After 30 months of seismic monitoring, one baseline and eight monitor surveys clearly detected changes that appear consistent with movement of CO{sub 2} as modeled with fluid simulators and observed in production data. Attribute analysis was a very useful tool in enhancing changes in seismic character present, but difficult to interpret on time amplitude slices. Lessons learned from and tools/techniques developed during this project will allow high-resolution seismic imaging to be routinely applied to many CO{sub 2} injection programs in a large percentage of shallow carbonate oil fields in the midcontinent.

  20. A joint research project -- Investigating man-made vitreous fiber (MMVF) insulation removal practices in the power industry, with preliminary results of potential worker exposure to airborne MMVF fibers

    SciTech Connect (OSTI)

    Axten, C.W.; Anoush, F.

    1996-10-01

    Man-made vitreous fibers (MMVFs) are components of a large number of important products manufactured worldwide, and include glass wool, rock and slag wool, and refractory ceramic fibers. These fibers are distinguished from each other by their chemical composition, physical properties and methods of production. Glass wool, or fiber glass as it is more commonly known is a borosilicate compound, produced from molten sand and inorganic materials under highly controlled conditions, Rock and slag wool, sometimes collectively referred to as mineral wool, is comprised of calcium-magnesium-aluminum-silicate glass. Slag wool is produced by melting a mixture of various blast furnace iron ore slags and other raw materials such as clay, sand and limestone in a coke fired cupola. Rock wool is produced using the same process, with a mixture of various natural and synthetic rock sources that yield the desired composition. In both rock and slag wool manufacturing, typically one raw material is the primary component, with other material added to supplement chemical deficiencies. The purpose of this study was to develop a flexible, representative, and valid exposure database for fiber glass and rock and slag wool insulation removal and reinstallation in a cross section of industrial environments with excellent supporting documentation. This information will be used to make more informed decisions to further worker health and safety through recommendation of exposure controls, product modifications, and personal protective equipment use and/or work practice controls.

  1. Final report on process modeling of cupola furnaces

    SciTech Connect (OSTI)

    Not Available

    1990-07-01

    This report describes the first phase of the AFS/DOE program on mathematical modeling of cupola behavior, covering the period May 19, 1989 to July 19, 1990. The objective of the program is to develop a comprehensive mathematical model of the cupola furnace for on-line and off-line process control and optimization. The work is being carried out by five organizations: Massachusetts Institute of Technology with responsibility for heat transfer and fluid flow modeling, and incorporation of the chemical models being developed by the University of Michigan team. Modern Equipment Company has the responsibility of compiling information on needed sensors for monitoring operation and providing materials data to be used for cupola input. General Motors, Central Foundry Division, is investigating the potential to augment the mathematical models with artificial intelligence programs. Lastly, General Motors Research laboratories are charged with providing accurate cupola operational data to test the models being developed. To date, a one-dimensional steady state model has been developed which considers heat transfer, fluid flow and important chemical processes: combustion, iron composition development, limestone calcination and iron oxidation. The model is based on established physico-chemical principles and data available in the literature. Model predictions compare favorably with data obtained in a production sale cupola, operating under carefully controlled, but realistic, conditions. At the present time, the chemical sub-models are being incorporated into the master program, and a complete working cupola model is expected by September 1990. 43 refs.

  2. Verification of simplified procedures for site-specific SO sub 2 and NOx control cost estimates. Final report, March 1988-May 1989

    SciTech Connect (OSTI)

    Emmel, T.E.; Maibodi, M.

    1990-02-01

    The report documents results of an evaluation to verify the accuracy of simplified procedures for estimating sulfur dioxide (SO2) and nitrogen oxides (NOx) retrofit control costs and performance for 200 SO2-emitting coal-fired power plants in the 31-state eastern region. Initially, detailed retrofit studies were conducted for 12 coal-fired plants in Ohio, Kentucky, and the Tennessee Valley Authority system. Because detailed studies are expensive and time-consuming, results from the 12-plant study were used to develop simplified procedures which require less time, data, and preparation effort. The evaluation compared the costs for a number of plants estimated using the simplified procedures to costs estimated using detailed procedures, actual retrofit costs, and more detailed cost estimates provided by utility companies. Based on the evaluation, recommendations for changes to the simplified procedures were developed. Control technologies addressed in the report are conventional lime/limestone flue gas desulfurization, lime spray drying, furnace sorbent injection, duct spray drying, coal switching, physical coal cleaning, and selective catalytic reduction. In general, it was found that the simplified procedures can be used to generate improved cost performance estimates based on generally available information.

  3. Advanced SO/sub 2/ control by-product utilization laboratory evaluation: Final report

    SciTech Connect (OSTI)

    Not Available

    1988-09-01

    This report presents the results of an investigation into the utilization potential of by-products from the following advanced SO/sub 2/ control processes: Atmospheric Fluidized Bed Combustion; Calcium Spray Drying; Limestone Furnace Injection; Sodium Sorbent Injection; and Calcium Sorbent Injection. Utilization applications identified as potentially feasible (from both technical and market perspectives) in the preliminary investigation (EPRI CS-5269) were evaluated through small-scale laboratory testing. The applications considered were primarily low to medium technology process and medium to high volume use applications. The laboratory test results were evaluated in concert with by-product physical, chemical and extract characteristics (developed during EPRI Research Project 2708-1) and a market assessment. Then, an economic evaluation was performed for each utilization application based upon a typical or hypothetical by-product marketing situation in which an advanced SO/sub 2/ control by-product could be substituted for a competing material on a local project or in a local product. Finally, based on the major factors considered in this project (laboratory characterization, technical feasibility evaluation, and economic and market assessments), the utilization potential for each application considered was rated as high, medium or low, and future research needs were identified. The following utilization applications were found to have a high potential for the majority of the calcium-based advanced SO/sub 2/ control by-products: road base, soil and sludge stabilization and grout applications. 76 refs., 18 figs., 70 tabs.

  4. Second survey of dry SO/sub 2/ control systems. Final report Mar-Sep 80

    SciTech Connect (OSTI)

    Kelly, M.E.; Shareef, S.A.

    1981-02-01

    The report is an updated assessment of dry flue gas desulfurization (FGD) systems. Current and recently completed research, development, and commercial activities in the U.S. since October 1979, are reviewed including: (1) spray dryers with a fabric filter or an electrostatic precipitator (ESP), (2) dry injection of alkaline material into flue gas combined with particulate collection in an ESP or fabric filter, and (3) combustion of coal/alkali fuel mixtures. Spray drying remains the only commercially applied dry FGD process. Since the last survey, completed late in 1979, eight utility and two industrial spray drying systems have been sold. Nine of them use lime as the sorbent, and nine use a fabric filter for particulate collection. Removal guarantees for so/sub 2/ range from 62 to 85%, depending on coal sulfur content. Two full-scale industrial spray drying systems are currently operating. The first large utility system is scheduled for startup early in 1981. Several publicly and privately funded pilot-scale programs have been completed in the past year. EPA is currently funding three such programs (two spray drying and one dry injection), as well as development of two combustion modification processes for SO2 control (combustion of coal/limestone pellets and of a pulverized coal/alkali mixture in a low-NOx burner). The DoE and others are studying dry injection on a pilot scale.

  5. Dry FGD (flue-gas desulfurization) at Argonne National Laboratory

    SciTech Connect (OSTI)

    Livengood, C.D.

    1990-01-01

    Flue-gas desulfurization (FGD) systems based on spray drying are a relatively recent addition to the spectrum of sulfur dioxide (SO{sub 2}) control options available to utility and industrial boiler operators. Such systems appear to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. These advantages have promoted rapid acceptance of dry scrubbers for applications using western low-sulfur coal, but uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. At Argonne National Laboratory (ANL) we have had more than eight years of operating experience with an industrial-scale dry scrubber used with a boiler firing high-sulfur (3.5%) midwestern coal. This paper describes our operating experience with that system and summarizes several research programs that have utilized it. 7 refs., 15 figs., 6 tabs.

  6. JV Task 126 - Mercury Control Technologies for Electric Utilities Burning Bituminous Coal

    SciTech Connect (OSTI)

    Jason Laumb; John Kay; Michael Jones; Brandon Pavlish; Nicholas Lentz; Donald McCollor; Kevin Galbreath

    2009-03-29

    The EERC developed an applied research consortium project to test cost-effective mercury (Hg) control technologies for utilities burning bituminous coals. The project goal was to test innovative Hg control technologies that have the potential to reduce Hg emissions from bituminous coal-fired power plants by {ge}90% at costs of one-half to three-quarters of current estimates for activated carbon injection (ACI). Hg control technology evaluations were performed using the EERC's combustion test facility (CTF). The CTF was fired on pulverized bituminous coals at 550,000 Btu/hr (580 MJ/hr). The CTF was configured with the following air pollution control devices (APCDs): selective catalytic reduction (SCR) unit, electrostatic precipitator (ESP), and wet flue gas desulfurization system (WFDS). The Hg control technologies investigated as part of this project included ACI (three Norit Americas, Inc., and eleven Envergex sorbents), elemental mercury (Hg{sup 0}) oxidation catalysts (i.e., the noble metals in Hitachi Zosen, Cormetech, and Hitachi SCR catalysts), sorbent enhancement additives (SEAs) (a proprietary EERC additive, trona, and limestone), and blending with a Powder River Basin (PRB) subbituminous coal. These Hg control technologies were evaluated separately, and many were also tested in combination.

  7. An experimental and theoretical study to relate uncommon rock/fluid properties to oil recovery. Final report

    SciTech Connect (OSTI)

    Watson, R.

    1995-07-01

    Waterflooding is the most commonly used secondary oil recovery technique. One of the requirements for understanding waterflood performance is a good knowledge of the basic properties of the reservoir rocks. This study is aimed at correlating rock-pore characteristics to oil recovery from various reservoir rock types and incorporating these properties into empirical models for Predicting oil recovery. For that reason, this report deals with the analyses and interpretation of experimental data collected from core floods and correlated against measurements of absolute permeability, porosity. wettability index, mercury porosimetry properties and irreducible water saturation. The results of the radial-core the radial-core and linear-core flow investigations and the other associated experimental analyses are presented and incorporated into empirical models to improve the predictions of oil recovery resulting from waterflooding, for sandstone and limestone reservoirs. For the radial-core case, the standardized regression model selected, based on a subset of the variables, predicted oil recovery by waterflooding with a standard deviation of 7%. For the linear-core case, separate models are developed using common, uncommon and combination of both types of rock properties. It was observed that residual oil saturation and oil recovery are better predicted with the inclusion of both common and uncommon rock/fluid properties into the predictive models.

  8. Milliken Clean Coal Technology Demonstration Project. Environmental monitoring report, July--September 1996

    SciTech Connect (OSTI)

    1998-05-01

    New York State Electric and Gas Corporation (NYSEG) has installed and is presently operating a high-efficiency flue gas desulfurization (FGD) system to demonstrate innovative emissions control technology and comply with the Clean Air Act Amendments of 1990. The host facility for this demonstration project is NYSEG`s Milliken Station, in the Town of Lansing, New York. The primary objective of this project is to demonstrate a retrofit of energy-efficient SO{sub 2} and NO{sub x} control systems with minimal impact on overall plant efficiency. The demonstration project has added a forced oxidation, formic acid-enhanced wet limestone FGD system, which is expected to reduce SO{sub 2} emissions by at least 90 percent. NYSEG also made combustion modifications to each boiler and plans to demonstrate selective non-catalytic reduction (SNCR) technology on unit 1, which will reduce NO{sub x} emissions. Goals of the proposed demonstration include up to 98 percent SO{sub 2} removal efficiency while burning high-sulfur coal, 30 percent NO{sub x} reductions through combustion modifications, additional NO{sub x} reductions using SNCR technology, production of marketable commercial-grade gypsum and calcium chloride by-products to minimize solid waste disposal, and zero wastewater discharge.

  9. Integration of geothermal data along the Balcones/Ouachita trend, central Texas. Final report

    SciTech Connect (OSTI)

    Woodruff, C.M. Jr.; Gever, C.; Snyder, Fred R.; Wuerch, David Robert

    1983-01-01

    This report presents data that address possible controls on warm-water resources. Data are presented on a series of maps, and interpretations appear in the brief text accompanying the maps. It is thought that structural controls provided by the Balcones Fault Zone on the west and by the Luling-Mexia-Talco Fault Zone on the east localize the warm waters. The ultimate controlling attribute is the foundered Ouachita structural belt, which, in turn, has controlled the orientation and magnitude of displacement of the superjacent normal fault systems. This thesis is supported by maps (in pocket) showing the following: distribution of thermal waters measured in wells along the Balcones/Ouachita structural trend showing water temperature in /sup 0/F, total depth of the well measured, water salinity in parts per million, and the geologic formation producing the water; structural contours on the base of the Cretaceous System showing the configuration of the Paleozoic Ouachita basement; structural configuration of the Balcones and Luling Fault Zone, Mexia and Talco Fault Zone, and foreland areas adjacent to the Ouachita Orogen using data from the Buda Limestone, Sligo Formation, and Ellenburger Group; Landsat lineaments and Bouguer gravity contours; and geothermal gradient contours of the Balcones/Ouachita trend based on thermal values from Paleozoic and selected Mesozoic formations.

  10. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2004-08-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have continued our work on analyzing well logs and microstructural constraints on seismic signatures. We report results of three studies in this report. The first one deals with fractures and faults that provide the primary control on the underground fluid flow through low permeability massive carbonate rocks. Fault cores often represent lower transmissibility whereas the surrounding damaged rocks and main slip surfaces are high transmissibility elements. We determined the physical properties of fault rocks collected in and around the fault cores of large normal faults in central Italy. After studying the P- and S-wave velocity variation during cycles of confining pressure, we conclude that a rigid pore frame characterizes the fault gouge whereas the fractured limestone comprises pores with a larger aspect ratio. The second study was to characterize the seismic properties of brine as its temperature decreases from 25 C to -21 C. The purpose was to understand how the transmitted wave changes with the onset of freezing. The main practical reason for this experiment was to use partially frozen brine as an analogue for a mixture of methane hydrate and water present in the pore space of a gas hydrate reservoir. In the third study we analyzed variations in dynamic moduli in various carbonate reservoirs. The investigations include log and laboratory data from velocity, porosity, permeability, and attenuation measurements.

  11. Distribution of Mississippian oolites and associated hydrocarbon production in the United States

    SciTech Connect (OSTI)

    Keith, B.D.; Zuppann, C.W. )

    1989-12-01

    Mississippian oolites (oolitic limestones) are widely distributed across the continental US, and are economically important as hydrocarbon reservoirs. Initial understanding of Mississippian oolitic reservoirs comes from an overview of the Mississippian depositional framework and a review of published literature on depositional models for Mississippian oolites and associated facies. The Mississippian was divided into four intervals corresponding approximately to the following stages: Kinderhookian (interval A), early Valmeyeran or Osagian (interval B), late Valmeyeran or Meramercian (interval C), and Chesterian (interval D). These intervals, which are not unique to this study, provide a convenient method of subdividing Mississippian rocks for more detailed regional mapping. Paleogeographic and gross lithofacies maps were prepared for each interval to relate oolite occurrences to their regional settings. Interval A was characterized by two broad, shallow seas separated by the Transcontinental lowlands. Marine deposition was dominantly carbonate toward the west and shale to the east. Areas of extensive oolite deposition were adjacent to either side of the Transcontinental lowlands. Interval B was a time of extensive marine transgression with small land areas isolated in a broad, generally shallow sea. Shale deposition continued in the Michigan, Illinois, and northern Appalachian basin, and cherty carbonates accumulated elsewhere. Oolite deposition was limited to the western US in the Williston basin, and to other areas along the slightly submerged Transcontinental arch. During interval C, land areas became more emergent and the Transcontinental lowlands once again separated the eastern and western seas.

  12. Chemical analyses of rocks, minerals, and detritus, Yucca Mountain--Preliminary report, special report No. 11

    SciTech Connect (OSTI)

    Hill, C.A.; Livingston, D.E.

    1993-09-01

    This chemical analysis study is part of the research program of the Yucca Mountain Project intended to provide the State of Nevada with a detailed assessment of the geology and geochemistry of Yucca Mountain and adjacent regions. This report is preliminary in the sense that more chemical analyses may be needed in the future and also in the sense that these chemical analyses should be considered as a small part of a much larger geological data base. The interpretations discussed herein may be modified as that larger data base is examined and established. All of the chemical analyses performed to date are shown in Table 1. There are three parts to this table: (1) trace element analyses on rocks (limestone and tuff) and minerals (calcite/opal), (2) rare earth analyses on rocks (tuff) and minerals (calcite/opal), and (3) major element analyses + CO{sub 2} on rocks (tuff) and detritus sand. In this report, for each of the three parts of the table, the data and its possible significance will be discussed first, then some overall conclusions will be made, and finally some recommendations for future work will be offered.

  13. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping . E-mail: zzhong@seu.edu.cn; Jin Baosheng; Huang Yaji; Zhou Hongcang; Lan Jixiang

    2006-07-01

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  14. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman

    2003-01-01

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  15. Low-Salinity Waterflooding to Improve Oil Recovery - Historical Field Evidence

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-11-01

    Waterflooding is by far the most widely applied method of improved oil recovery. Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of wa-terfloods. Laboratory water-flood tests and single-well tracer tests have shown that injection of dilute brine can increase oil recovery, but work designed to test the method on a field scale has not yet been undertaken. Historical waterflood records could unintentionally provide some evidence of improved recovery from waterflooding with lower salinity brine. Nu-merous fields in the Powder River basin of Wyoming have been waterflooded using low salinity brine (about 500 ppm) obtained from the Madison limestone or Fox Hills sandstone. Three Minnelusa formation fields in the basin were identified as potential candidates for waterflood comparisons based on the salinity of the connate and injection water. Historical pro-duction and injection data for these fields were obtained from the public record. Field waterflood data were manipulated to be displayed in the same format as laboratory coreflood re-sults. Recovery from fields using lower salinity injection wa-ter was greater than that using higher salinity injection wa-termatching recovery trends for laboratory and single-well tests.

  16. Profiles in garbage glass containers

    SciTech Connect (OSTI)

    Miller, C.

    1997-09-01

    Glass containers are made from sand, limestone, soda ash, cullet (crushed bottles), and various additives, including those used to color brown, green, or blue bottles. Sixty percent of the glass used in the US is clear (flint) and one-fourth is brown (amber). Almost half of the green bottles are imported wind and beer bottles. Other glass products include flat glass such as windows; fiberglass insulation; and glassware. These products use different manufacturing processes and different additives than container glass. This profile covers only container glass. Glass bottles are commonly collected in curb-side programs. Losses due to breakage and the abrasiveness of glass during collection and processing offset their low collection and processing costs. Breakage solutions include installation of interior baffles or nets in the collection trucks, special glass-only truck compartments, and limiting the number of times glass is transferred after collection before final processing. Ten states require deposits on glass bottles for beer and soft drinks and related items.

  17. Wilderness study area, mineral resources of the Sleeping Giant, Lewis and Clark County, Montana

    SciTech Connect (OSTI)

    Tysdal, G.; Reynold, M.W.; Carlson, R.R.; Kleinkopf, M.D.; Rowan, L.C. ); Peters, T.J. )

    1991-01-01

    A Mineral resource survey was conducted in 1987 by the U.S. Geological Survey and the U.S. Bureau of Mines to evaluate mineral resources (known) and mineral resource potential (undiscovered) of the Sleeping Giant Wilderness Study Area (MT-075-111) in Lewis and Clark County, Montana. The only economic resource in the study area is an inferred 1.35-million-ton reserve of decorative stone (slate); a small gold placer resource is subeconomic. A high resource potential for decorative slate exists directly adjacent to the area of identified slate resource and in the northeastern part of the study area. The rest of the study area has a low potential for decorative slate. The westernmost part of the study area has a moderate resource potential for copper and associated silver in state-bound deposits in green beds and limestone; potential is low in the rest of the study are. The study area has a low resource potential for sapphires in placer deposits, gold in placer deposits (exclusive of subeconomic resource mentioned above), phosphate in the Spokane Formation, diatomite in lake deposits, uranium, oil, gas, geothermal energy, and no resource potential for phosphate in the Phosphoria Formation.

  18. Updating about reductions of air and blood lead concentrations in Turin, Italy, following reductions in the lead content of gasoline

    SciTech Connect (OSTI)

    Bono, R.; Pignata, C.; Gilli, G.

    1995-07-01

    Considering its well known toxicity and the chronic human exposure to lead, international lawmakers enforced some directives or laws calling for the reduction of lead content in gasoline. All of these legislative acts aimed to reduce health risks for the general population. The aim of this study was to consider the effectiveness of these laws on air lead levels and consequently on blood lead levels in a randomly selected urban Italian population. In particular, these markers were analyzed over the course of several years, corresponding to the periods just before and after enforcements of the reductions of lead in petrol. Data presented point out some considerations: (1) enforcement of legislative measures concerning the reduction of lead in petrol has reduced atmospheric levels of lead. This result demonstrates a major environmental success in primary prevention efforts. (2) This success is clear especially considering that the actual Pb-B levels can be extended to the urbanized populations. Pb-B levels were consistently higher for drinkers, for older adults and for males. The mean of Pb-B level for the present urbanized population is higher than the U.S. overall population (6.4 vs 3 {mu}g/dl). This difference can be also explained considering the different historical period of enforcement of the restriction laws. 10 refs., 3 figs., 3 tabs.

  19. STOCK: Structure mapper and online coarse-graining kit for molecular simulations

    SciTech Connect (OSTI)

    Bevc, Sta; Junghans, Christoph; Praprotnik, Matej

    2015-03-15

    We present a web toolkit STructure mapper and Online Coarse-graining Kit for setting up coarse-grained molecular simulations. The kit consists of two tools: structure mapping and Boltzmann inversion tools. The aim of the first tool is to define a molecular mapping from high, e.g. all-atom, to low, i.e. coarse-grained, resolution. Using a graphical user interface it generates input files, which are compatible with standard coarse-graining packages, e.g. VOTCA and DL_CGMAP. Our second tool generates effective potentials for coarse-grained simulations preserving the structural properties, e.g. radial distribution functions, of the underlying higher resolution model. The required distribution functions can be provided by any simulation package. Simulations are performed on a local machine and only the distributions are uploaded to the server. The applicability of the toolkit is validated by mapping atomistic pentane and polyalanine molecules to a coarse-grained representation. Effective potentials are derived for systems of TIP3P (transferable intermolecular potential 3 point) water molecules and salt solution. The presented coarse-graining web toolkit is available at http://stock.cmm.ki.si.

  20. A brief overview of Chinese Design Code on Fossil-Fueled Power Plants

    SciTech Connect (OSTI)

    Xu Zhongqing; He Yehong

    1996-10-01

    The Chinese Design Code on Fossil Fueled Power Plants (DL 5000-94) was issued in April 1994 by the Ministry of Electric Power Industry, P.R. China, and the English version has been drafted and will be formally published in the near future. Based on the 1984 version and the nation`s current policies, the 1994 version was formed to meet the challenges of the nation`s speedy development of electric power construction. In general, the code is primarily a directive document guiding the planning and engineering of China`s large- and medium-sized fossil-fueled power plants. The preparation of the 1984 version and the revision of it to the 1994 version were all carried out by the East China Electric Power Design Institute under the direction of Electric Power Planning and Engineering Institute. For small-sized power plants with unit rating of 25 MW and below, there is another national design code titled Code for Design of Small Sized Power Plants (GB 50049-94) issued in November 1994 jointly by the China`s National Technology Supervision Administration and the Ministry of Construction.