Sample records for distillation cracking reforming

  1. Gamma prime embrittlement and thermal fatigue cracking of a hydrogen reformer burner end

    SciTech Connect (OSTI)

    Dias, O.C.; Mack, N.C. [Amoco Oil Co., Texas City, TX (United States)

    1994-12-31T23:59:59.000Z

    An investigation into the premature failure of an Alloy 800HT (UNS N08811) oxygen-gas mixer water jacketed end is discussed. Detailed metallurgical analyses showed that gamma prime [Ni{sub 3} (Al, Ti)] embrittlement and thermal fatigue cracking led to eventual leakage. The reduced lif e of the Alloy 800HT (UNS N08811) replacement (problems after only a year) was traced to its higher Al + Ti content (1.1%) compared to Alloy 800H (0.6% Al + Ti) which lasted over two years. While higher aluminum and titanium levels improve high temperature creep and stress rupture properties, both are sigma formers and, at levels > 0.6%, tend to form gamma prime with nickel. The choice of alternative metallurgies requires careful considerations of physical, mechanical and thermal properties as well as an understanding of complex stresses and stress distributions.

  2. Catalytic Distillation

    E-Print Network [OSTI]

    Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

    1984-01-01T23:59:59.000Z

    Catalytic Distillation' refers to a chemical process which performs both a catalyzed reaction and primary fractionation of the reaction components simultaneously. A structured catalyst which also is an effective distillation component has been...

  3. Distill, Distill_roll Distill for CASP10

    E-Print Network [OSTI]

    Pollastri, Gianluca

    Distill, Distill_roll Distill for CASP10 C. Mirabello1, G. Tradigo1,2 , P.Veltri2, and G. Pollastri1 1 ­ UCD Dublin, Ireland, 2 ­ Università di Cosenza, Italy gianluca.pollastri@ucd.ie Distill has to the distance maps of templates rather than to predicted contact maps. The difference between Distill

  4. Distillation 29 Chem 355 Jasperse DISTILLATION

    E-Print Network [OSTI]

    Jasperse, Craig P.

    Distillation 29 Chem 355 Jasperse DISTILLATION Background Distillation is a widely used technique for purifying liquids. The basic distillation process involves heating a liquid such that liquid molecules that is condensed and collected must be more pure than the original liquid mix. Distillation can be used to remove

  5. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1984-01-01T23:59:59.000Z

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  6. DistillationTheory.fm 2 September 1999 Distillation Theory.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 DistillationTheory.fm 2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway #12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Material Balance on a Distillation Stage

  7. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17T23:59:59.000Z

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  8. INNOVATION EDUCATION EXCELLENCE DISTILLATIONS

    E-Print Network [OSTI]

    Chan, Hue Sun

    INNOVATION · EDUCATION · EXCELLENCE DISTILLATIONS University of Toronto CHEMISTRY ALUMNI MAGAZINE.utoronto.ca / distillations 2012 MessagefromtheChair Our Department of Chemistry has one of the finest collection of peo- ple to a better, more sustain- able future. This issue of Distillations highlights the accomplishments last year

  9. DUNCAN PRITCHARD Reforming Reformed Epistemology*

    E-Print Network [OSTI]

    Edinburgh, University of

    DUNCAN PRITCHARD Reforming Reformed Epistemology* 0. Introduction There has been a renaissance-called "reformed" defence of the rationality of reli- gious belief. The starting-point for this reformed conception concern here. Instead, I will be outlining one way in which the reformed epistemological stance can

  10. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-02-10T23:59:59.000Z

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  11. Distillation: The Efficient Workhorse

    E-Print Network [OSTI]

    Steinmeyer, D.

    DISTILLATION: THE EFFICIENT WORKHORSE Dan Steinmeyer Monsanto Company St. Louis, Missouri Distillation is inherently highly efficient: phase separation is clean it is relatively easy to build a mUltistage countercurrent device equilibrium... is closely approached on each stage Given the right perspective; the right application; and the right design - distillation is difficult to beat from an efficiency standpoint. ? The right perspective is that efficiency is the ratio of the work...

  12. Generalized entanglement distillation

    E-Print Network [OSTI]

    Yu-Bo Sheng; Lan Zhou

    2014-04-14T23:59:59.000Z

    We present a way for the entanglement distillation of genuine mixed state. Different from the conventional mixed state in entanglement purification protocol, each components of the mixed state in our protocol is a less-entangled state, while it is always a maximally entangled state. With the help of the weak cross-Kerr nonlinearity, this entanglement distillation protocol does not require the sophisticated single-photon detectors. Moreover, the distilled high quality entangled state can be retained to perform the further distillation. These properties make it more convenient in practical applications.

  13. MULTIVESSEL BATCH DISTILLATION EXPERIMENTAL VERIFICATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION ­ EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad 1 The experimental verification of the operation of a multivessel batch distillation column, operated under total vessels, provides a generalization of previously proposed batch distillation schemes. We propose a simple

  14. Reforming process

    SciTech Connect (OSTI)

    Buss, W.C.

    1987-02-24T23:59:59.000Z

    A reforming process is described comprising: (a) contacting a hydrocarbon feed with a first reforming catalyst at conditions which favor reforming to form a product stream. The first reforming catalyst is bifunctional and comprises a metallic oxide support which contains acidic sites having disposed therein a Group VIII metal; and (b) contacting the product stream with a second reforming catalyst at conditions which favor reforming. The second reforming catalyst is a monofunctional, non-acidic catalyst comprising a large-pore zeolite containing at least one Group VIII metal.

  15. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01T23:59:59.000Z

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  16. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22T23:59:59.000Z

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  17. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24T23:59:59.000Z

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  18. Random multiparty entanglement distillation

    E-Print Network [OSTI]

    Ben Fortescue; Hoi-Kwong Lo

    2008-01-15T23:59:59.000Z

    We describe various results related to the random distillation of multiparty entangled states - that is, conversion of such states into entangled states shared between fewer parties, where those parties are not predetermined. In previous work [Phys. Rev. Lett. 98, 260501 (2007)] we showed that certain output states (namely Einstein-Podolsky-Rosen (EPR) pairs) could be reliably acquired from a prescribed initial multipartite state (namely the W state) via random distillation that could not be reliably created between predetermined parties. Here we provide a more rigorous definition of what constitutes ``advantageous'' random distillation. We show that random distillation is always advantageous for W-class three-qubit states (but only sometimes for Greenberger-Horne-Zeilinger (GHZ)-class states). We show that the general class of multiparty states known as symmetric Dicke states can be readily converted to many other states in the class via random distillation. Finally we show that random distillation is provably not advantageous in the limit of multiple copies of pure states.

  19. Energy efficient distillation apparatus

    SciTech Connect (OSTI)

    Melton, J.D.

    1982-08-17T23:59:59.000Z

    An energy efficient distillation method is provided which is particularly adapted for use on a dairy farm, and which comprises a distilland evaporating receptacle, a distillate condensing receptacle, and a conduit interconnecting the evaporating receptacle and the condensing receptacle. A vacuum pump is provided for drawing a partial vacuum within the evaporating receptacle, and a vapor compression refrigeration system is provided which includes condenser coils disposed to heat and vaporize the distilland while it is within the evaporating receptacle, and evaporator coils for cooling and condensing the vaporized distilland in the condensing receptacle. A cooling distribution system is also provided whereby a variable portion of the cooling potential of the refrigeration system may be selectively directed to each of the condensing receptacle, a distillate receiver tank, or to a bulk milk container as utilized on a dairy farm or the like.

  20. Qutrit Magic State Distillation

    E-Print Network [OSTI]

    Anwar, Hussain; Browne, Dan E

    2012-01-01T23:59:59.000Z

    Magic state distillation (MSD) is a purification protocol that plays a central role in fault tolerant quantum computation. Repeated iteration of the steps of a MSD protocol, generates pure single non-stabilizer states, or magic states, from multiple copies of a mixed resource state using stabilizer operations only. Thus mixed resource states promote the stabilizer operations to full universality. Magic state distillation was introduced for qubit-based quantum computation, but little has been known concerning MSD in higher dimensional qudit-based computation. Here, we describe a general approach for studying MSD in higher dimensions. We use it to investigate the features of a qutrit MSD protocol based on the 5-qutrit stabilizer code. We show that this protocol distills non-stabilizer magic states, and identify two types of states, that are attractors of this iteration map. Finally, we show how these states may be converted, via stabilizer circuits alone, into a state suitable for state injected implementation ...

  1. Distillate fuel-oil processing for phosphoric acid fuel-cell power plants

    SciTech Connect (OSTI)

    Ushiba, K. K.

    1980-02-01T23:59:59.000Z

    The current efforts to develop distillate oil-steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high-temperature steam reforming (HTSR); autothermal reforming (ATR); autothermal gasification (AG); and ultra desulfurization followed by steam reforming. Sulfur in the feed is a key problem in the process development. A majority of the developers consider sulfur as an unavoidable contaminant of distillate fuel and are aiming to cope with it by making the process sulfur-tolerant. In the HTSR development, the calcium aluminate catalyst developed by Toyo Engineering represents the state of the art. United Technology (UTC), Engelhard, and Jet Propulsion Laboratory (JPL) are also involved in the HTSR research. The ATR of distillate fuel is investigated by UTC and JPL. The autothermal gasification (AG) of distillate fuel is being investigated by Engelhard and Siemens AG. As in the ATR, the fuel is catalytically gasified utilizing the heat generated by in situ partial combustion of feed, however, the goal of the AG is to accomplish the initial breakdown of the feed into light gases and not to achieve complete conversion to CO and H/sub 2/. For the fuel-cell integration, a secondary reforming of the light gases from the AG step is required. Engelhard is currently testing a system in which the effluent from the AG section enters the steam-reforming section, all housed in a single vessel. (WHK)

  2. Topological Quantum Distillation

    E-Print Network [OSTI]

    H. Bombin; M. A. Martin-Delgado

    2007-03-29T23:59:59.000Z

    We construct a class of topological quantum codes to perform quantum entanglement distillation. These codes implement the whole Clifford group of unitary operations in a fully topological manner and without selective addressing of qubits. This allows us to extend their application also to quantum teleportation, dense coding and computation with magic states.

  3. Low Energy Distillation Schemes

    E-Print Network [OSTI]

    Polley, G. T.

    of reducing energy consumption. We look at how the better integrated distillation schemes can be quickly identified. It is found that the design of integrated schemes is quicker than that of non-integrated schemes. We then look at how the use of heat pumps...

  4. Heteroazeotropic Batch Distillation Feasibility and Operation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Heteroazeotropic Batch Distillation Feasibility and Operation by Efstathios Skouras and distillation is the dominating unit operation for such separations. However, the presence of azeotropes and non distillation as the best suited process. Among, various techniques to enhance distillation, heterogeneous

  5. Attrition resistant fluidizable reforming catalyst

    DOE Patents [OSTI]

    Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

    2011-03-29T23:59:59.000Z

    A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

  6. Distributed Reforming of Biomass Pyrolysis Oils: Cooperative Research and Development Final Report, CRADA number CRD-06-00192

    SciTech Connect (OSTI)

    Czernik, S.

    2010-07-01T23:59:59.000Z

    The objective of this project is for Chevron and NREL to collaborate in determining the effect of bio-oil composition variability on autothermal reforming performance including bio-oil volatilization, homogeneous oxidative cracking, and catalytic reforming.

  7. Renormalising entanglement distillation

    E-Print Network [OSTI]

    Stephan Waeldchen; Janina Gertis; Earl T. Campbell; Jens Eisert

    2015-03-16T23:59:59.000Z

    Entanglement distillation refers to the task of transforming a collection of weakly entangled pairs into fewer highly entangled ones. It is a core ingredient in quantum repeater protocols, needed to transmit entanglement over arbitrary distances in order to realise quantum key distribution schemes. Usually, it is assumed that the initial entangled pairs are i.i.d. distributed and uncorrelated with each other, an assumption that might not be reasonable at all in any entanglement generation process involving memory channels. Here, we introduce a framework that captures entanglement distillation in the presence of natural correlations arising from memory channels. Conceptually, we bring together ideas from condensed-matter physics - that of renormalisation and of matrix-product states and operators - with those of local entanglement manipulation, Markov chain mixing, and quantum error correction. We identify meaningful parameter regions for which we prove convergence to maximally entangled states, arising as the fixed points of a matrix-product operator renormalisation flow.

  8. Reflux for multifeed distillation

    SciTech Connect (OSTI)

    Chou, S.M.; Yaws, C.L.

    1986-12-01T23:59:59.000Z

    Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

  9. Intermediate Vapor Expansion Distillation and Nested Enrichment Cascade Distillation

    E-Print Network [OSTI]

    Erickson, D. C.

    INTERMEDIATE VAPOR EXPANSION DISTILLATION AND NESTED ENRICHMENT CASCADE DISTILLATION D.. C. Erickson Energy Concepts Company Annapolis, Maryland ABSTRACT Although it is known that incorporating an intermediate reboiler or reflux... condenser in a distillation ~olumn will improve column efficiency by 15 to 100%, there has been little use of this technique to date." Intermediate vapor compression heat pumping was recently introduced as one practical means of achieving this benefit...

  10. Acquisition Reform

    E-Print Network [OSTI]

    Sapolsky, Harvey

    This report reviews the six most recent major acquisition reform reports, starting in 1949 with the Hoover Commissions and including McNamara's Total Package Procurement, Fitzhugh Commission, the Commission on Government ...

  11. TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION BERND WITTGENS, RAJAB LITTO, EVA SØRENSEN in this paper provides a generalization of previously proposed batch distillation schemes. A simple feedback been built and the experiments verify the simulations. INTRODUCTION Although batch distillation

  12. Minimum Energy Diagrams for Multieffect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Minimum Energy Diagrams for Multieffect Distillation Arrangements Hilde K. Engelien and Sigurd distillation arrangements for separating a ternary mixture have been considered. The focus is on a heat-integrated complex distillation configuration, called a multieffect prefractionator arrangement. The comparison

  13. Multivessel Batch Distillation Potential Energy Savings

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multivessel Batch Distillation ­ Potential Energy Savings Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT ­ A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  14. Multivessel Batch Distillation -Potential Energy Savings

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multivessel Batch Distillation - Potential Energy Savings Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT - A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  15. Slab reformer

    DOE Patents [OSTI]

    Spurrier, Francis R. (Whitehall, PA); DeZubay, Egon A. (Mt. Lebanon, PA); Murray, Alexander P. (Murrysville, PA); Vidt, Edward J. (Churchill, PA)

    1985-03-12T23:59:59.000Z

    Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot combustion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

  16. Slab reformer

    DOE Patents [OSTI]

    Spurrier, Francis R. (Whitehall, PA); DeZubay, Egon A. (Mt. Lebanon, PA); Murray, Alexander P. (Murrysville, PA); Vidt, Edward J. (Churchill, PA)

    1984-02-07T23:59:59.000Z

    Slab-shaped high efficiency catalytic reformer configurations particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot comubstion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant.

  17. Slab reformer

    DOE Patents [OSTI]

    Spurrier, F.R.; DeZubay, E.A.; Murray, A.P.; Vidt, E.J.

    1984-02-07T23:59:59.000Z

    Slab-shaped high efficiency catalytic reformer configurations are disclosed particularly useful for generation of fuels to be used in fuel cell based generation systems. A plurality of structures forming a generally rectangular peripheral envelope are spaced about one another to form annular regions, an interior annular region containing a catalytic bed and being regeneratively heated on one side by a hot combustion gas and on the other side by the gaseous products of the reformation. An integrally mounted combustor is cooled by impingement of incoming oxidant. 14 figs.

  18. Optimal Control of Distillation Systems

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01T23:59:59.000Z

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  19. EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS Tshepo Sehole David Modise A thesis or in combination, such as distillation, extraction, crystallization, ect. Among these, distillation is by far profiles for the preliminary design of distillation columns. Residue curves and column profile are not only

  20. Momentive Performance Materials Distillation Intercharger

    E-Print Network [OSTI]

    Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

    2013-01-01T23:59:59.000Z

    Care? Energy Efficiency Program Momentive Performance Materials Distillation Interchanger ESL-IE-13-05-20 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Copyright 2013 Momentive Performance... Materials Inc. All rights reserved. CONFIDENTIAL IETC Energy Efficiency Award Winner Distillation Interchanger ? Waterford, NY Agenda ? Momentive Overview ? Waterford, NY Site Overview ? Project Overview ? Project Timeline ? NYSERDA ? Project Team...

  1. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

    2009-11-03T23:59:59.000Z

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  2. Quantum universality by state distillation

    E-Print Network [OSTI]

    Ben W. Reichardt

    2009-07-13T23:59:59.000Z

    Quantum universality can be achieved using classically controlled stabilizer operations and repeated preparation of certain ancilla states. Which ancilla states suffice for universality? This "magic states distillation" question is closely related to quantum fault tolerance. Lower bounds on the noise tolerable on the ancilla help give lower bounds on the tolerable noise rate threshold for fault-tolerant computation. Upper bounds show the limits of threshold upper-bound arguments based on the Gottesman-Knill theorem. We extend the range of single-qubit mixed states that are known to give universality, by using a simple parity-checking operation. For applications to proving threshold lower bounds, certain practical stability characteristics are often required, and we also show a stable distillation procedure. No distillation upper bounds are known beyond those given by the Gottesman-Knill theorem. One might ask whether distillation upper bounds reduce to upper bounds for single-qubit ancilla states. For multi-qubit pure states and previously considered two-qubit ancilla states, the answer is yes. However, we exhibit two-qubit mixed states that are not mixtures of stabilizer states, but for which every postselected stabilizer reduction from two qubits to one outputs a mixture of stabilizer states. Distilling such states would require true multi-qubit state distillation methods.

  3. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23T23:59:59.000Z

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

  4. Integrating Gas Turbines with Cracking Heaters - Impact on Emissions and Energy Efficiency

    E-Print Network [OSTI]

    Platvoet, E.

    2011-01-01T23:59:59.000Z

    Turbine Exhaust Gas (TEG) contains high levels of oxygen, typically 15 vol. percent, due to gas turbine blade material temperature limits. As such it can be used as an oxidant for combustion in cracking furnaces and reformers. Its high temperature...

  5. Entanglement distillation using particle statistics

    E-Print Network [OSTI]

    H. L. Huang; L. H. Cheng; X. X. Yi

    2005-10-25T23:59:59.000Z

    We extend the idea of entanglement concentration for pure states(Phys. Rev. Lett. {\\bf 88}, 187903) to the case of mixed states. The scheme works only with particle statistics and local operations, without the need of any other interactions. We show that the maximally entangled state can be distilled out when the initial state is pure, otherwise the entanglement of the final state is less than one. The distillation efficiency is a product of the diagonal elements of the initial state, it takes the maximum 50%, the same as the case for pure states.

  6. Distilling entanglement from arbitrary resources

    E-Print Network [OSTI]

    Francesco Buscemi; Nilanjana Datta

    2010-10-15T23:59:59.000Z

    We obtain the general formula for the optimal rate at which singlets can be distilled from any given noisy and arbitrarily correlated entanglement resource, by means of local operations and classical communication (LOCC). Our formula, obtained by employing the quantum information spectrum method, reduces to that derived by Devetak and Winter, in the special case of an i.i.d. resource. The proofs rely on a one-shot version of the so-called "hashing bound," which in turn provides bounds on the one-shot distillable entanglement under general LOCC.

  7. Entanglement distillation by extendible maps

    E-Print Network [OSTI]

    Lukasz Pankowski; Fernando G. S. L. Brandao; Michal Horodecki; Graeme Smith

    2013-08-25T23:59:59.000Z

    It is known that from entangled states that have positive partial transpose it is not possible to distill maximally entangled states by local operations and classical communication (LOCC). A long-standing open question is whether maximally entangled states can be distilled from every state with a non-positive partial transpose. In this paper we study a possible approach to the question consisting of enlarging the class of operations allowed. Namely, instead of LOCC operations we consider k-extendible operations, defined as maps whose Choi-Jamiolkowski state is k-extendible. We find that this class is unexpectedly powerful - e.g. it is capable of distilling EPR pairs even from product states. We also perform numerical studies of distillation of Werner states by those maps, which show that if we raise the extension index k simultaneously with the number of copies of the state, then the class of k-extendible operations is not that powerful anymore and provide a better approximation to the set of LOCC operations.

  8. Corrosion inhibition for distillation apparatus

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY); Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01T23:59:59.000Z

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  9. Process Svstems Enaineerina Instability of Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Process Svstems Enaineerina , Instability of Distillation Columns Elling W. Jacobsen and Sigurd recognized, distillation columns, operating with reflux and boilup as independent inputs, may have The dynamic behavior of distillation columns has been stud- ied quite extensively over the past decades

  10. POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT ­ A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  11. POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT - A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  12. Optimal distillation using thermodynamic geometry Bjarne Andresen

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal distillation using thermodynamic geometry Bjarne Andresen Ørsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler (temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2

  13. Analysis and Control of Heteroazeotropic Batch Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis and Control of Heteroazeotropic Batch Distillation S. Skouras and S. Skogestad Dept.interscience.wiley.com). The separation of close-boiling and azeotropic mixtures by heterogeneous azeotropic distillation is addressed. The results show that heteroazeotropic batch distillation exhibits substantial flexibility. The column profile

  14. Experimental entanglement distillation of mesoscopic quantum states

    E-Print Network [OSTI]

    Loss, Daniel

    LETTERS Experimental entanglement distillation of mesoscopic quantum states RUIFANG DONG1 , MIKAEL, entanglement distillation, a process of extracting a small set of highly entangled states from a large set of less entangled states, can be used4­14 . Here we report on the distillation of deterministically

  15. TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION BERND WITTGENS, RAJAB LITTO, EVA S RENSEN a generalization of previously proposed batch distillation schemes. A simple feedback control strategy for total re verify the simulations. INTRODUCTION Although batch distillation generally is less energy e cient than

  16. Fuel reforming for scramjet thermal management and combustion optimization

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and the composition of the cracked fuel entering the combustor, an accurate predictive model of the thermalFuel reforming for scramjet thermal management and combustion optimization E. DANIAU* , M. BOUCHEZ of the main issues of hypersonic flight is the thermal management of the overall vehicle and more specifically

  17. Californians and Immigration Reform

    E-Print Network [OSTI]

    Sekhon, Jasjeet S.

    June 2013 Californians and Immigration Reform Alternatives Jack Citrin Morris Levy Gabriel Lenz, include: · Even when alternative reforms are included in the ques- tion, most respondents support some about immigration reform remains a com- plex subject," said IGS Director Jack Citrin, who led the re

  18. Distillation of Bell states in open systems

    E-Print Network [OSTI]

    E. Isasi; D. Mundarain

    2009-08-14T23:59:59.000Z

    In this work we review the entire classification of 2x2 distillable states for protocols with a finite numbers of copies. We show a distillation protocol that allows to distill Bell states with non zero probability at any time for an initial singlet in vacuum. It is shown that the same protocol used in non zero thermal baths yields a considerable recovering of entanglement.

  19. Heat Exchanger Technologies for Distillation Columns

    E-Print Network [OSTI]

    Polley, G. T.

    Heat Exchanger Technologies for Distillation Columns G.T.Polley Pinchtechnology.com In this paper we look at the challenges that improvements in energy efficiency of distillation systems presents the heat exchanger designer. We examine... condensate sub-cooling. So, if this condensate subsequently requires re-heating both energy and capital have been wasted. If the condensate forms a feed to another distillation column it results in increased energy consumption if that separation...

  20. Reducing Energy Usage in Extractive Distillation

    E-Print Network [OSTI]

    Saxena, A. C.; Bhandari, V. A.

    , .. ~ REDUCING ENERGY USAGE IN,EXTRACTIVE DISTILLATION A. C. Saxena V. A. Bhandari Polysar Limited Sarnia, Ontario, Canada Abstract Butadiene 1:3 is separated from other C. hydrocarbons by extractive distillation in a sieve plate tower.... To improve the energy efficiency, butadiene recovery and productivity of the extractive distillation process, many process changes have been made. Their rationale, the methodology used to implement the various changes, and how they affected the process...

  1. Entanglement distillation from quasifree Fermions

    E-Print Network [OSTI]

    Zoltan Kadar; Michael Keyl; Dirk Schlingemann

    2011-03-24T23:59:59.000Z

    We develop a scheme to distill entanglement from bipartite Fermionic systems in an arbitrary quasifree state. It can be applied if either one system containing infinite one-copy entanglement is available or if an arbitrary amount of equally prepared systems can be used. We show that the efficiency of the proposed scheme is in general very good and in some cases even optimal. Furthermore we apply it to Fermions hopping on an infinite lattice and demonstrate in this context that an efficient numerical analysis is possible for more then 10^6 lattice sites.

  2. CLOSED OPERATION OF MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 CLOSED OPERATION OF MULTIVESSEL BATCH DISTILLATION - EXPERIMENTAL VERIFICATION Submitted to AICheÆcient operation, multicomponent distillation, batch distillation, total re ux operation ABSTRACT. The multivessel batch distillation column, as well as conven- tional batch distillation, may be operated in a closed

  3. Crack coalescence in granite

    E-Print Network [OSTI]

    Miller, James Thomas, Ph. D. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    This thesis experimentally investigates crack coalescence in prismatic Barre Granite specimens with two pre-cut, open flaws under uniaxial compression. Using a high-speed video system, crack initiation, propagation, and ...

  4. Steam reforming analyzed

    SciTech Connect (OSTI)

    Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

    1992-07-01T23:59:59.000Z

    This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

  5. Locally Accessible Information and Distillation of Entanglement

    E-Print Network [OSTI]

    Sibasish Ghosh; Pramod Joag; Guruprasad Kar; Samir Kunkri; Anirban Roy

    2004-03-18T23:59:59.000Z

    A new type of complementary relation is found between locally accessible information and final average entanglement for given ensemble. It is also shown that in some well known distillation protocol, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

  6. Rigorous Synthesis and Simulation of Complex Distillation Networks

    E-Print Network [OSTI]

    Linninger, Andreas A.

    Rigorous Synthesis and Simulation of Complex Distillation Networks Gerardo J. Ruiz, Seon B. Kim energy-efficient distillation net- works. Complex column networks have substantial potential for energy column, networks, temperature collocation, inverse design, Aspen validation Introduction Distillation

  7. Shell middle distillate hydrogenation process

    SciTech Connect (OSTI)

    Lucien, J.P. [Companie Rhenane de Raffinage Reichstett, Reichstett Vendenheim (France); Berg, J.P. van den; Hooijdonk, H.M.J.H. van; Thielemans, G.L.B. [Shell Internationale Petroleum Mij., The Hague (Netherlands); Germaine, G. [Shell Recherche SA, Grand-Couronne (France); Gjers, M. [Shell Raffinaderi AB, Gothenburg (Sweden)

    1994-12-31T23:59:59.000Z

    The strive towards cleaner environment has lead to low sulfur specifications for middle distillate fuels. In addition compositional specifications are presently debated. Thus, to meet future emissions standards regarding, specifically, particulates emissions, the motor industry calls for improved automotive gasoil quality. Although automotive gasoil quality affects emissions from diesel engines it is considered less influential than engine design and maintenance. Sulfur, density and cetane number are the fuel properties having the greatest influence on diesel engine emissions although also aromatics and endpoint specifications have been defined in environmentally adopted government initiatives. This paper reviews the options which are available to tackle these new requirements. The high severity single stage concept (using conventional mixed sulfides catalysts) will be discussed in its potential to meet more severe product requirements as well as in terms of its limitations, especially at the point of aromatics saturation and cetaine upgrading. Furthermore, it is shown that the option of severe hydrotreating followed by hydrogenation with conventional noble metal catalysts is preferred if deep aromatics saturation is aimed at. However, this conventional two stage concept has limitations with respect to heaviness and sulfur and nitrogen content of feedstocks. The new Shell Middle Distillate Hydrogenation (SMDH) technology, applying a (semi) two stage approach based on the Shell developed hydrogenation catalyst is presented. The SMDH process will be discussed in its potential to break the limitations of the conventional options. The new catalyst is crucial in this process and allows a highly integrated mode of operation. A number of applications of this novel process will be discussed.

  8. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21T23:59:59.000Z

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  9. atmospheric crude distillation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  10. acrobat distiller job: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  11. advanced distillation curve: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  12. Distillation: Still towering over other options

    SciTech Connect (OSTI)

    Kunesh, J.G. [Fractionation Research, Inc., Stillwater, OK (United States); Kister, H.Z. [Brown and Root, Inc., Alhambra (Canada); Lockett, M.J. [Praxair, Inc., Tonawanda, NY (United States); Fair, J.R. [Univ. of Texas, Austin, TX (United States)

    1995-10-01T23:59:59.000Z

    Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

  13. Immigration reform and California agriculture

    E-Print Network [OSTI]

    Martin, Philip

    2013-01-01T23:59:59.000Z

    reform and California agriculture Philip Martin Professor,proposals for California agriculture. Immigration reformCenter. 196 CALIFORNIA AGRICULTURE • VOLUME 67 , NUMBER 4

  14. Crack healing as a function of pOH- and fracture morphology

    E-Print Network [OSTI]

    Fallon, Jessica Anne

    2005-02-17T23:59:59.000Z

    Crack healing in quartz has been investigated by optical microscopy and interferometry of rhombohedral ( 1) cracks in polished Brazilian quartz prisms that were annealed hydrothermally at temperatures of 250?C and 400?C for 2.4 to 240 hours, fluid... pressure Pf = Pc = 41 MPa, and varying pOH- (from 5.4 to 1.2 at 250?C for fluids consisting of distilled water and NaOH solutions with molalities up to 1). Crack morphologies before and after annealing were recorded for each sample in plane light...

  15. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01T23:59:59.000Z

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  16. Nonlocality Distillation for High-Dimensional System

    E-Print Network [OSTI]

    Pan, Guo-Zhu; Chen, Zheng-Gen; Yang, Ming; Cao, Zhuo-Liang

    2012-01-01T23:59:59.000Z

    The intriguing and powerful capability of nonlocality in communication field ignites the research of the nonlocality distillation. The first protocol presented in Ref[Phys. Rev. Lett. 102, 120401] shows that the nonlocality of bipartite binary-input and binary-output nonsignaling correlated boxes could be amplified by 'wiring' two copies of weaker-nonlocality boxes. Several optimized distillation protocols were presented later for bipartite binary-input and binary-output nonsignaling correlated boxes. In this paper, we focus on the bipartite binary-input and multi-nary-output nonsignaling correlated boxes---high-dimensional boxes, and design comparators-based protocols to achieve the distillation of high-dimensional nonlocality. The results show that the high-dimensional nonlocality can be distilled in different ways, and we find that the efficiencies of the protocols are influenced not only by the wirings but also by the classes the initial nonlocality boxes belongs to. Here, the initial nonlcalities may hav...

  17. Intelligent fuzzy supervisory control for distillation columns

    E-Print Network [OSTI]

    Santhanam, Srinivasan

    1993-01-01T23:59:59.000Z

    problem. Multivariable design techniques are used to control the column. Some of the different multivariable techniques which have been used in the distillation column control include decoupling control, optimal control and internal model control [5...

  18. Advanced Distillation: Programs Proposed to DOE

    E-Print Network [OSTI]

    Woinsky, S. G.

    EPRI has provided proposal preparation assistance and offered cost share funding assistance for two projects proposed in 2000. EPRI is highly interested, since this technology is applicable in all distillation systems, and since it will increase...

  19. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  20. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01T23:59:59.000Z

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  1. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    When the heat source available to a distillation process is at a significantly higher temperature than the reboiler temperature, there is unused availability (ability to perform work) in the heat supplied to the reboiler. Similarly, if the reflux...

  2. Complex Fluid Analysis with the Advanced Distillation Curve Approach

    E-Print Network [OSTI]

    Complex Fluid Analysis with the Advanced Distillation Curve Approach Thomas J. Bruno, Lisa S. Ott for measuring distillation curves reveals the physicochemical properties of complex fluids such as fuels distillation curves of complex fluids. The distillation curve provides the only practical avenue to assess

  3. On the Communication Complexity of Correlation and Entanglement Distillation

    E-Print Network [OSTI]

    On the Communication Complexity of Correlation and Entanglement Distillation Ke Yang May 4th, 2004 distillation, entanglement distillation, communication complexity, EPR pairs, quantum key distribution #12) information, and then engage in a protocol to \\distill" the correlation/entanglement via communication. We

  4. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio blog distillation by adding a link analysis phase to the standard retrieval-by-topicality phase, where in blog distillation. 1 Introduction Blog distillation is a subtask of blog search. It is defined

  5. Solar Ethanol Distillation Oara Neumann,1,3

    E-Print Network [OSTI]

    O-9 Solar Ethanol Distillation Oara Neumann,1,3 Albert D. Neumann,2 Julius Müller,1 of separation, particularly distillation. The 40,000 commercial distillation columns in use in the U. S. consume or product purity. Distillation is the critical energy-consuming step accounting for 70-85% of the energy

  6. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA SØRENSEN 3 and RAJAB distillation schemes. A simple feedback control strategy for the total reflux operation of a multivessel column distillation generally is less energy efficient than continuous distillation, it has received increased

  7. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA S RENSEN 3 and RAJAB distillation schemes. A simple feedback control strategy for the total re ux operation of a multivessel column distillation generally is less energy e cient than continuous distillation, it has received increased attention

  8. Multipartite secret key distillation and bound entanglement

    E-Print Network [OSTI]

    Remigiusz Augusiak; Pawel Horodecki

    2009-09-25T23:59:59.000Z

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted GHZ structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with help of the privacy squeezing technique.

  9. Multipartite secret key distillation and bound entanglement

    SciTech Connect (OSTI)

    Augusiak, Remigiusz; Horodecki, Pawel [Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk (Poland) and ICFO-Institute Ciencies Fotoniques, Mediterranean Technology Park, 08860 Castelldefels (Barcelona) (Spain); Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk (Poland)

    2009-10-15T23:59:59.000Z

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted Greenberger-Horne-Zeilinger (GHZ) structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with the help of the privacy squeezing technique.

  10. Absorptive Recycle of Distillation Waste Heat

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    ABSORPTIVE RECYCLE OF DISTILLATION WASTE HEAT Donald C. Erickson and Edward J. Lutz Jr. Energy Concepts Company Annapolis, Maryland ABSTRACT When the heat source available to a distillation process is at a significantly higher temperature... which conserve 60 to 70%. Also, there are ver sions which incorporate separate low tem perature waste heat streams and thereby conserve over 90% of the required dis tillation energy. The main limitations of the R/AHP are the need for sufficient...

  11. Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates

    SciTech Connect (OSTI)

    Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

    1987-04-01T23:59:59.000Z

    High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

  12. Reforming the Private Insurance Market

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Reforming the Private Insurance Market: Lessons from California for National Health Reform Janet M and Community Medicine, University of California, San Francisco ADVANCING NATIONAL HEALTH REFORM POLICY BRIEF Security |Reforming the Private Insurance Market: Lessons from California ACKNOWLEDGMENTS I would like

  13. Reforming Undergraduate Education at UNLV

    E-Print Network [OSTI]

    Hemmers, Oliver

    Reforming Undergraduate Education at UNLV #12;Reforms Passed by Faculty Senate In 2011 the Faculty Senate Passed Two Reforms: 1. University Undergraduate Learning Outcomes (UULOs) ­ The skills Reform · Improving quality of our undergraduate education · Greater Coherence of Gen Ed and Undergraduate

  14. Catalytic reforming methods

    DOE Patents [OSTI]

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14T23:59:59.000Z

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  15. NETL - Fuel Reforming Facilities

    SciTech Connect (OSTI)

    None

    2013-06-12T23:59:59.000Z

    Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

  16. NETL - Fuel Reforming Facilities

    ScienceCinema (OSTI)

    None

    2014-06-27T23:59:59.000Z

    Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

  17. Natural Gas Reforming | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Production Natural Gas Reforming Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon...

  18. Local purity distillation with bounded classical communication

    E-Print Network [OSTI]

    Hari Krovi; Igor Devetak

    2007-05-28T23:59:59.000Z

    Local pure states are an important resource for quantum computing. The problem of distilling local pure states from mixed ones can be cast in an information theoretic paradigm. The bipartite version of this problem where local purity must be distilled from an arbitrary quantum state shared between two parties, Alice and Bob, is closely related to the problem of separating quantum and classical correlations in the state and in particular, to a measure of classical correlations called the one-way distillable common randomness. In Phys. Rev. A 71, 062303 (2005), the optimal rate of local purity distillation is derived when many copies of a bipartite quantum state are shared between Alice and Bob, and the parties are allowed unlimited use of a unidirectional dephasing channel. In the present paper, we extend this result to the setting in which the use of the channel is bounded. We demonstrate that in the case of a classical-quantum system, the expression for the local purity distilled is efficiently computable and provide examples with their tradeoff curves.

  19. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25T23:59:59.000Z

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  20. Sulfur distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    by the thermal cracking process of the El-Lujjan oil shale showed that the yield of oil was around 12 wt of the boiling point for different distillate fractions. Sulfur in Jordanian oil shale was found to be mainly the dominant phases in these fractions. q 2005 Published by Elsevier Ltd. 1. Introduction Oil shale

  1. Energy Saving in Distillation Using Structured Packing and Vapor Recompression

    E-Print Network [OSTI]

    Hill, J.H.

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated distillation columns. Larger...

  2. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) Geographic Area Month Kerosene No. 1 Distillate No. 2...

  3. Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves

    SciTech Connect (OSTI)

    Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

    1996-11-01T23:59:59.000Z

    Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

  4. Automated pavement crack detection

    E-Print Network [OSTI]

    Rao, Ashok Madhava

    1991-01-01T23:59:59.000Z

    : Electrical Engineering AUTOMATED PAVEMENT CRACK DETECTION A Thesis by ASHOK MADHAVA RAO Approved as to style and content by . c Norman C. Grisw d (Chair of Committ ) Nasser Kehtarnavaz (Member) g, J~, Karan Watson Robert L. Lytt (Member) Jo W.... Howze (Head of Department) December 1991 111 ABSTRACT Automated Pavement Crack Detection. (December 1991) Ashok Madhava, Rao, B. E. , Mysore University Chair of Advisory Committee: Norman. C. Griswold Due to load, environmental and structural...

  5. Desalination Using Vapor-Compression Distillation

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    the outgoing salt concentration was 1.5% and 7%, respectively. Distillation was performed at 439 K (331oF) and 722 kPa (105 psia) for both brackish water feed and seawater feed. Water costs of the various conditions were calculated for brackish water...

  6. Distillation: Present Status and Future Directions

    E-Print Network [OSTI]

    Fair, J. R.; Humphrey, J. L.

    1984-01-01T23:59:59.000Z

    -pressure steam as a heat source. The steam has, very likely, been sent through one or more users (turbi ne dri ves) before reaching the distillation reboiler. It seems almost characteristic of large chemical and refining complexes that there is a chronic...

  7. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    to distillation columns ac- count for roughly 3 of the total energy consumption in the U.S. (Ognisty 1995 to reduce energy consumption at least two alternative approaches have been proposed both in the literature is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  8. Forpeerreview Synthesis of Complex Thermally Coupled Distillation

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    consumption of 91 GW, or 54 million tons of crude oil. The distillation research is motivated by its major US energy consumption, which is equivalent to 2.87x10 18 J (2.87 million TJ) per year, or to a power

  9. Energy Conservation Options in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    I ENERGY CONSERVATION OPTIONS IN DISTILLATION PROCESSES G.E. Harris, W.R. Hearn, G.M. Blythe, and J.M. Stuart, Radian Corporation, Austin, Texas I This paper summarizes the results of a survey of energy conservation options applicable...

  10. Synthesis and design of optimal thermal membrane distillation networks 

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    of oil. An overview of Direct Contact Membrane Distillation (DCMD) reports the narrow range of applications of membrane distillation in the industry, such as desalination and water purification (Burgoyne and Vahdati, 2000; Cath et al., 2004). Gryta... crystalliser and air gap membrane distillation as a solution to geothermal water desalination. Desalination 152 (1-3), 237-244. Burgoyne, A, Vahdati, M.M. 2000. Direct contact membrane distillation.Separation Science and Technology 35 (8), 1257...

  11. Distilling one-qubit magic states into Toffoli states

    E-Print Network [OSTI]

    Bryan Eastin

    2013-02-21T23:59:59.000Z

    For certain quantum architectures and algorithms, most of the required resources are consumed during the distillation of one-qubit magic states for use in performing Toffoli gates. I show that the overhead for magic-state distillation can be reduced by merging distillation with the implementation of Toffoli gates. The resulting routine distills 8 one-qubit magic states directly to a Toffoli state, which can be used without further magic to perform a Toffoli gate.

  12. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits Distillation Model Relates overhead composition of propane with flowrate of propane feed to the splitter

  13. Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens,

    E-Print Network [OSTI]

    to infinity. We call such protocols asymp- totic and the fraction of distilled Bell states per initial copy#12;#12;Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens, Jeroen: July 13, 2006) We present a new asymptotic bipartite entanglement distillation protocol

  14. Optimal Control of a Continuous Distillation Process under Probabilistic Constraints

    E-Print Network [OSTI]

    Henrion, René

    Optimal Control of a Continuous Distillation Process under Probabilistic Constraints René Henrion1 Universität Berlin, Germany Abstract A continuous distillation process with random inflow rate is considered model including the dynamics of the distillation process and proba- bilistic constraints under different

  15. Bloggers as Experts Feed Distillation using Expert Retrieval Models

    E-Print Network [OSTI]

    de Rijke, Maarten

    Bloggers as Experts Feed Distillation using Expert Retrieval Models Krisztian Balog kbalog Kruislaan 403, 1098 SJ Amsterdam ABSTRACT We address the task of (blog) feed distillation: to find blogs- ness as feed distillation strategies. The two models capture the idea that a human will often search

  16. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS ­ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177­217, 1997. Abstract Distillation column dynamics and control has been viewed these, the feasibility of using the distillate­bottom structure for control (which was believed

  17. CHEM333: Experiment 4: Steam Distillation of Essential Oils;

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Experiment 4: Steam Distillation of Essential Oils; Experiments A, C, D and below. Reading: For this experiment read Chapter 10. This week you will get to use steam distillation to isolate may wait until you come to lab to find out which spice you get. Steam distillation is not a common

  18. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed, the feasibility of using the distillate-bottomstructure for control which was believed to be impossible

  19. Column Initialization 1 Initializing Distillation Column Models 1

    E-Print Network [OSTI]

    Dundee, University of

    Column Initialization 1 Initializing Distillation Column Models 1 Roger Fletcher \\Lambda with the optimisation of distillation column models by non­ linear programming are considered. The paper presents of the distillation column model. A certain limiting case of the column model is examined, that of infinite reflux

  20. Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b a SINTEF ICT, Applied Keywords: Distillation Minimum energy Energy saving Dividing wall column Petlyuk arrangement Vmin-diagram a b s t r a c t Distillation is responsible for a significant amount of the energy consumption

  1. Many copies may be required for entanglement distillation John Watrous

    E-Print Network [OSTI]

    Watrous, John

    Many copies may be required for entanglement distillation John Watrous Department of Computer state shared between two parties is said to be distillable if, by means of a protocol involving only |+ = (|00 + |11 )/ 2. In this paper it is proved that there exist states that are distillable

  2. Active constraint regions for optimal operation of distillation columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Active constraint regions for optimal operation of distillation columns Magnus G. Jacobsen the control structure of distillation columns, with optimal operation in mind, it is important to know how for distillation columns change with variations in energy cost and feed flow rate. The production of the most

  3. Multiple copy distillation and purification of phase diffused squeezed states

    E-Print Network [OSTI]

    Petr Marek; Jaromir Fiurasek; Boris Hage; Alexander Franzen; James DiGugliemo; Roman Schnabel

    2007-11-16T23:59:59.000Z

    We provide a detailed theoretical analysis of multiple copy purification and distillation protocols for phase diffused squeezed states of light. The standard iterative distillation protocol is generalized to a collective purification of an arbitrary number of N copies. We also derive a semi-analytical expression for the asymptotic limit of the iterative distillation and purification protocol and discuss its properties.

  4. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Lab Experiment 3: Distillation and Gas Chromatography: Prelab-Assignment: read Chapters 5 and 6. Distillation is one of the most powerful techniques for purifying volatile organic compounds. Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wine

  5. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio report a new approach to blog distillation, defined as the task in which, given a user query, the system of the TREC Blog Track. 1 Introduction Blog distillation is a subtask of the blog search task. It is defined

  6. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA S RENSEN 3 and RAJAB distillation schemes, including the inverted column and the middle vessel column. The total re ux operation of the multivessel batch distillation column was presented recently, and the main contribution of this paper

  7. Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures using Elementary) diagrams like distillation lines and isotherms maps may be used in analysis of the closed (total reflux) multivessel batch distillation column. An indirect level control strategy is implemented that eliminates

  8. Azeotropic Distillation as a Technique for Emulsion Size Reduction

    E-Print Network [OSTI]

    Petta, Jason

    Azeotropic Distillation as a Technique for Emulsion Size Reduction Taylor Emanuelle Sweet 2013 Prism/PCCM #12;Overview -Intro- What is Microfluidics? What is Heterogeneous Azeotropic Distillation microns in size and use Binary Heterogeneous Azeotropic Distillation to shrink droplets to 5-10 microns

  9. Model Predictive Control of a Kaibel Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Model Predictive Control of a Kaibel Distillation Column Martin Kvernland Ivar Halvorsen Sigurd (e-mail: skoge@ntnu.no) Abstract: This is a simulation study on controlling a Kaibel distillation column with model predictive control (MPC). A Kaibel distillation column has several advantages compared

  10. Multiple Steady States in Ideal Two-Product Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multiple Steady States in Ideal Two-Product Distillation Elling W. Jacobsen and Sigurd Skogestad Chemical Engineering Dept., University of Trondheim-NTH, N-7034 Trondheim, Norway Simple distillation and compositions in the column. Introduction Multiple steady states (multiplicity) in distillation columns have

  11. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT ·How can we separate ternary mixtures in closed batch distillation-up period is required, followed by a heteroazeotropic distillation step (Figure 3) Modified: The separation

  12. Effect of Number of Fractionating Trays on Reactive Distillation Performance

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

  13. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA SØRENSEN 3 and RAJAB distillation schemes, including the inverted column and the middle vessel column. The total reflux operation of the multivessel batch distillation column was presented recently, and the main contribution of this paper

  14. RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT

    E-Print Network [OSTI]

    RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT J. R. Taylor**, 0. Hansen*, C. Jensen*, 0. F. A risk analysis of a batch distillation unit is de- scribed. The analysis has been carried out at several.2. Objectives and organisation 5 1.2.2. Philosophy and approach 6 1.3.1. The distillation unit 8 1

  15. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    Solar thermal powered desalination: membrane versus distillation technologies G. Burgess and K Canberra ACT 0200 AUSTRALIA E-mail: greg.burgess@anu.edu.au Multiple Effect Distillation (MED) is generally assisted) desalination has been conducted. Solar thermal driven Multiple Effect Distillation (MED) has been

  16. Human versus Machine in the Topic Distillation Task Mingfang Wu

    E-Print Network [OSTI]

    Wu, Mingfang

    Human versus Machine in the Topic Distillation Task Mingfang Wu 1 , Gheorghe Muresan2 , Alistair Mc. The focus is on comparing humans and machine algorithms in terms of performance in a topic distillation task demonstrated that machines can perform nearly as well as people on the topic distillation task. Given a system

  17. Economically Optimal Control of Kaibel Distillation Column: Fixed boilup rate

    E-Print Network [OSTI]

    Skogestad, Sigurd

    : In this study, a control structure is designed for a 4-product dividing wall (Kaibel) distillation column, basedEconomically Optimal Control of Kaibel Distillation Column: Fixed boilup rate Maryam Ghadrdan distillation column; Vapour split manipulation; Self-optimizing control. 1. INTRODUCTION Thermally coupled

  18. Optimal Synthesis of Complex Distillation ColumnsUsing Rigorous Models

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    a review of recent work for the optimal design of distillation of individual columns using tray review of the area of optimal design and synthesis of distillation columns, emphasizing recentOptimal Synthesis of Complex Distillation ColumnsUsing Rigorous Models Ignacio E. Grossmann1 , Pío

  19. THE DOS AND DONTS OF DISTILLATION COLUMN CONTROL

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DOS AND DON·TS OF DISTILLATION COLUMN CONTROL S. Skogestadà Department of Chemical Engineering distillation column control within the general framework of plant- wide control. In addition, it aims at providing simple recommendations to assist the engineer in designing control systems for distillation

  20. FOOD REFORM MOVEMENTS Nicolas Larchet

    E-Print Network [OSTI]

    Boyer, Edmond

    FOOD REFORM MOVEMENTS Nicolas Larchet Social historians have broadly defined two cycles of American history characterized by an efflorescence of social movements aiming to reform both the individual to the 1920s. The reform impulse thrived wherever there was a perceived vice, abuse or corruption

  1. Autothermal reforming catalyst and process

    SciTech Connect (OSTI)

    Setzer, H. J.; Karavolis, S.; Lesieur, R. R.; Wnuck, W. G.

    1984-09-25T23:59:59.000Z

    High activity steam reforming catalysts are described particularly adapted for use in autothermal reforming processes. A rhodium catalyst on a calcium oxide impregnated alumina substrate allow the autothermal reforming process to take place with substantially no carbon plugging at oxygen to carbon ratios below what had been considered critical for avoiding carbon plugging of the catalyst in the past.

  2. Secret key distillation from shielded two-qubit states

    E-Print Network [OSTI]

    Joonwoo Bae

    2010-09-22T23:59:59.000Z

    The quantum states corresponding to a secret key are characterized using the so-called private states, where the key part consisting of a secret key is shielded by the additional systems. Based on the construction, it was shown that a secret key can be distilled from bound entangled states. In this work, I consider the shielded two-qubit states in a key-distillation scenario and derive the conditions under which a secret key can be distilled using the recurrence protocol or the two-way classical distillation, advantage distillation together with one-way postprocessing. From the security conditions, it is shown that a secret key can be distilled from bound entangled states in a much wider range. In addition, I consider the case that in which white noise is added to quantum states and show that the classical distillation protocol still works despite a certain amount of noise although the recurrence protocol does not.

  3. Qutrit Magic State Distillation Tight in Some Directions

    E-Print Network [OSTI]

    Hillary Dawkins; Mark Howard

    2015-04-22T23:59:59.000Z

    Magic state distillation is a crucial component in the leading approaches to implementing universal fault tolerant quantum computation, with existing protocols for both qubit and higher dimensional systems. Early work focused on determining the region of distillable states for qubit protocols, yet comparatively little is known about which states can be distilled and with what distillable region for d>2. Here we focus on d=3 and present new four-qutrit distillation schemes that improve upon the known distillable region, and achieve distillation tight to the boundary of undistillable states for some classes of state. As a consequence of recent results, this implies that there is a family of quantum states that enable universality if and only if they exhibit contextuality with respect to stabilizer measurements. We also identify a new routine whose fixed point is a magic state with maximal sum-negativity i.e., it is maximally non-stabilizer in a specific sense.

  4. Secret key distillation from shielded two-qubit states

    SciTech Connect (OSTI)

    Bae, Joonwoo [School of Computational Sciences, Korea Institute for Advanced Study, Seoul 130-722 (Korea, Republic of)

    2010-05-15T23:59:59.000Z

    The quantum states corresponding to a secret key are characterized using the so-called private states, where the key part consisting of a secret key is shielded by the additional systems. Based on the construction, it was shown that a secret key can be distilled from bound entangled states. In this work, I consider the shielded two-qubit states in a key-distillation scenario and derive the conditions under which a secret key can be distilled using the recurrence protocol or the two-way classical distillation, advantage distillation together with one-way postprocessing. From the security conditions, it is shown that a secret key can be distilled from bound entangled states in a much wider range. In addition, I consider the case that in which white noise is added to quantum states and show that the classical distillation protocol still works despite a certain amount of noise although the recurrence protocol does not.

  5. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27T23:59:59.000Z

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  6. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20T23:59:59.000Z

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  7. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01T23:59:59.000Z

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  8. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01T23:59:59.000Z

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  9. The attractor mechanism as a distillation procedure

    E-Print Network [OSTI]

    Péter Lévay; Szilárd Szalay

    2010-04-14T23:59:59.000Z

    In a recent paper it has been shown that for double extremal static spherically symmetric BPS black hole solutions in the STU model the well-known process of moduli stabilization at the horizon can be recast in a form of a distillation procedure of a three-qubit entangled state of GHZ-type. By studying the full flow in moduli space in this paper we investigate this distillation procedure in more detail. We introduce a three-qubit state with amplitudes depending on the conserved charges the warp factor, and the moduli. We show that for the recently discovered non-BPS solutions it is possible to see how the distillation procedure unfolds itself as we approach the horizon. For the non-BPS seed solutions at the asymptotically Minkowski region we are starting with a three-qubit state having seven nonequal nonvanishing amplitudes and finally at the horizon we get a GHZ state with merely four nonvanishing ones with equal magnitudes. The magnitude of the surviving nonvanishing amplitudes is proportional to the macroscopic black hole entropy. A systematic study of such attractor states shows that their properties reflect the structure of the fake superpotential. We also demonstrate that when starting with the very special values for the moduli corresponding to flat directions the uniform structure at the horizon deteriorates due to errors generalizing the usual bit flips acting on the qubits of the attractor states.

  10. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  11. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  12. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  13. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  14. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  15. Catalytic reforming catalyst

    SciTech Connect (OSTI)

    Buss, W.C.; Kluksdahl, H.E.

    1980-12-09T23:59:59.000Z

    An improved catalyst, having a reduced fouling rate when used in a catalytic reforming process, said catalyst comprising platinum disposed on an alumina support wherein the alumina support is obtained by removing water from aluminum hydroxide produced as a by-product from a ziegler higher alcohol synthesis reaction, and wherein the alumina is calcined at a temperature of 1100-1400/sup 0/F so as to have a surface area of 165 to 215 square meters per gram.

  16. Hydrocarbon cracking catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1988-12-27T23:59:59.000Z

    This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

  17. Surface code implementation of block code state distillation

    E-Print Network [OSTI]

    Austin G. Fowler; Simon J. Devitt; Cody Jones

    2013-01-29T23:59:59.000Z

    State distillation is the process of taking a number of imperfect copies of a particular quantum state and producing fewer better copies. Until recently, the lowest overhead method of distilling states |A>=(|0>+e^{i\\pi/4}|1>)/\\sqrt{2} produced a single improved |A> state given 15 input copies. New block code state distillation methods can produce k improved |A> states given 3k+8 input copies, potentially significantly reducing the overhead associated with state distillation. We construct an explicit surface code implementation of block code state distillation and quantitatively compare the overhead of this approach to the old. We find that, using the best available techniques, for parameters of practical interest, block code state distillation does not always lead to lower overhead, and, when it does, the overhead reduction is typically less than a factor of three.

  18. Iterative Entanglement Distillation: Approaching full Elimination of Decoherence

    E-Print Network [OSTI]

    Boris Hage; Aiko Samblowski; James DiGuglielmo; Jaromír Fiurášek; Roman Schnabel

    2010-07-09T23:59:59.000Z

    The distribution and processing of quantum entanglement form the basis of quantum communication and quantum computing. The realization of the two is difficult because quantum information inherently has a high susceptibility to decoherence, i.e. to uncontrollable information loss to the environment. For entanglement distribution, a proposed solution to this problem is capable of fully eliminating decoherence; namely iterative entanglement distillation. This approach builds on a large number of distillation steps each of which extracts a number of weakly decohered entangled states from a larger number of strongly decohered states. Here, for the first time, we experimentally demonstrate iterative distillation of entanglement. Already distilled entangled states were further improved in a second distillation step and also made available for subsequent steps.Our experiment displays the realization of the building blocks required for an entanglement distillation scheme that can fully eliminate decoherence.

  19. Steam reformer with catalytic combustor

    DOE Patents [OSTI]

    Voecks, Gerald E. (La Crescenta, CA)

    1990-03-20T23:59:59.000Z

    A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

  20. AEDP & Healthcare Reform Dipti Patel, FSA, MAAA

    E-Print Network [OSTI]

    Hong, Don

    Cigna AEDP & Healthcare Reform Dipti Patel, FSA, MAAA March 19, 2012 #12; Introductions Introducing... Cigna An overview of the AEDP Healthcare Reform Questions and Answers Overview #12 Branding ­ "GO YOU" · Things are changing ­ Health Care Reform · Young, energetic, executive leadership

  1. What's right SHIP & Healthcare Reform Forum

    E-Print Network [OSTI]

    Walker, Matthew P.

    &Health Reform What's right for you SHIP & Healthcare Reform Forum: What's Right for You This session will help you: * demystify the healthcare reform changes * explore your options * learn how

  2. W-like bound entangled states and secure key distillation

    E-Print Network [OSTI]

    Remigiusz Augusiak; Pawel Horodecki

    2009-09-09T23:59:59.000Z

    We construct multipartite entangled states with underlying W-type structure satisfying positive partial transpose (PPT) condition under any (N-1)|1 partition. Then we show how to distill N-partite secure key form the states using two different methods: direct application of local filtering and novel random key distillation scheme in which we adopt the idea form recent results on entanglement distillation. Open problems and possible implications are also discussed.

  3. Quantum states representing perfectly secure bits are always distillable

    E-Print Network [OSTI]

    Pawel Horodecki; Remigiusz Augusiak

    2007-11-06T23:59:59.000Z

    It is proven that recently introduced states with perfectly secure bits of cryptographic key (private states representing secure bit) [K. Horodecki et al., Phys. Rev. Lett. 94, 160502 (2005)] as well as its multipartite and higher dimension generalizations always represent distillable entanglement. The corresponding lower bounds on distillable entanglement are provided. We also present a simple alternative proof that for any bipartite quantum state entanglement cost is an upper bound on distillable cryptographic key in bipartite scenario.

  4. Energy Conservation Options in Distillation Processes

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    ~itroo.? ':!OD.e~tell.,..ot!.k1 .'k..,.-.ottNltlu'..,. II ""'I'JI ..... ~I_ """-.4008l1"OO I ~.z.,. 1 ,1'1 (-frl-.'....u_~ R.da at AC~Ofllftl\\,J'ftlit...." ? I 5 "'-tlnc&! Tt.,.. ? 21.' \\lip Gilil.In31 j TnyE.'tIc>Mcy .11.1'llo I ~~TI""'.'2.at... I There are many options available to the engi*eer seeking to reduce the energy requirements of a distil lation process. The technology for most of these I, options has been available for many years, but it has only recently become economically...

  5. Use of computers for multicomponent distillation calculations

    E-Print Network [OSTI]

    Sullivan, Samuel Lane

    1959-01-01T23:59:59.000Z

    The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

  6. New Design Methods and Algorithms for Multi-component Distillation...

    Broader source: Energy.gov (indexed) [DOE]

    CX-100137 Categorical Exclusion Determination ITP Chemicals: Hybripd SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Energy...

  7. Integrated Thermal and Hydraulic Analysis of Distillation Columns

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    . The paper outlines how bringing together the column thermal and hydraulics analysis provides significant additional insights to help screen the options for distillation column revamps....

  8. Local Gaussian operations can enhance continuous-variable entanglement distillation

    E-Print Network [OSTI]

    ShengLi Zhang; Peter van Loock

    2011-03-23T23:59:59.000Z

    Entanglement distillation is a fundamental building block in long-distance quantum communication. Though known to be useless on their own for distilling Gaussian entangled states, local Gaussian operations may still help to improve non-Gaussian entanglement distillation schemes. Here we show that by applying local squeezing operations, both the performance and the efficiency of existing distillation protocols can be enhanced. We derive the optimal enhancement through local Gaussian unitaries, which can be obtained even in the most natural scenario when Gaussian mixed entangled states are shared after their distribution through a lossy-fiber communication channel.

  9. advanced distillation control: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Morari California.Eng., Norwegian Institute of Technology (NTH), N-7034 Trondheim, Norway Paper presented at Symposium Distillation Skogestad, Sigurd 14 CONTROL AND ENERGY...

  10. azeotropic distillation columns: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT How can we separate ternary mixtures in closed batch...

  11. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  12. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  13. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1996 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  14. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  15. Understanding Educational Reforms: Physics Education Research

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    Understanding Educational Reforms: Impacts of Physics Education Research Steven Pollock Physics Science Education Scientifically Theoretical frames Student concepts and engagement Curricular reforms

  16. Negative Valve Overlap Reforming Chemistry in Low-Oxygen Environments

    SciTech Connect (OSTI)

    Szybist, James P [ORNL] [ORNL; Steeper, Richard R. [Sandia National Laboratories (SNL)] [Sandia National Laboratories (SNL); Splitter, Derek A [ORNL] [ORNL; Kalaskar, Vickey B [ORNL] [ORNL; Pihl, Josh A [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) and other forms of advanced combustion. When fuel is injected into O2-deficient NVO conditions, a portion of the fuel can be converted to products containing significant levels of H2 and CO. Additionally, other short chain hydrocarbons are produced by means of thermal cracking, water-gas shift, and partial oxidation reactions. The present study experimentally investigates the fuel reforming chemistry that occurs during NVO. To this end, two very different experimental facilities are utilized and their results are compared. One facility is located at Oak Ridge National Laboratory, which uses a custom research engine cycle developed to isolate the NVO event from main combustion, allowing a steady stream of NVO reformate to be exhausted from the engine and chemically analyzed. The other experimental facility, located at Sandia National Laboratories, uses a dump valve to capture the exhaust from a single NVO event for analysis. Results from the two experiments are in excellent trend-wise agreement and indicate that the reforming process under low-O2 conditions produces substantial concentrations of H2, CO, methane, and other short-chain hydrocarbon species. The concentration of these species is found to be strongly dependent on fuel injection timing and injected fuel type, with weaker dependencies on NVO duration and initial temperature, indicating that NVO reforming is kinetically slow. Further, NVO reforming does not require a large energy input from the engine, meaning that it is not thermodynamically expensive. The implications of these results on HCCI and other forms of combustion are discussed in detail.

  17. NONLINEAR MPC BASED ON MULTI-MODEL FOR DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Foss, Bjarne A.

    NONLINEAR MPC BASED ON MULTI-MODEL FOR DISTILLATION COLUMNS Bjarne A. Foss1 , Song-Bo Cong established for a petroleum distillation column through first principle analysis, and its parameters have been-estimation and prediction in a MPC scheme. The controller has been applied to quality control of a FCCU fractionator

  18. A Decision Mechanism for the Selective Combination of Evidence in Topic Distillation

    E-Print Network [OSTI]

    Jose, Joemon M.

    A Decision Mechanism for the Selective Combination of Evidence in Topic Distillation Vassilis combination of evidence for Web Information Retrieval and particularly for topic distillation. We introduce. Keywords Web information retrieval, Topic distillation, decision mechanism, selective combination

  19. Temperature Collocation Algorithm for Fast and Robust Distillation Libin Zhang and Andreas A. Linninger*

    E-Print Network [OSTI]

    Linninger, Andreas A.

    Temperature Collocation Algorithm for Fast and Robust Distillation Design Libin Zhang and Andreas A mixtures that exhibit suitable volatility differences.1 Hence, continuous distillation columns, along commodity manufacturing. The common practice for distillation design often involves numerous trial

  20. Non-Gaussian entanglement distillation for continuous variables

    E-Print Network [OSTI]

    Hiroki Takahashi; Jonas S. Neergaard-Nielsen; Makoto Takeuchi; Masahiro Takeoka; Kazuhiro Hayasaka; Akira Furusawa; Masahide Sasaki

    2009-07-13T23:59:59.000Z

    Entanglement distillation is an essential ingredient for long distance quantum communications. In the continuous variable setting, Gaussian states play major roles in quantum teleportation, quantum cloning and quantum cryptography. However, entanglement distillation from Gaussian states has not yet been demonstrated. It is made difficult by the no-go theorem stating that no Gaussian operation can distill Gaussian states. Here we demonstrate the entanglement distillation from Gaussian states by using measurement-induced non-Gaussian operations, circumventing the fundamental restriction of the no-go theorem. We observed a gain of entanglement as a result of conditional local subtraction of a single photon or two photons from a two-mode Gaussian state. Furthermore we confirmed that two-photon subtraction also improves Gaussian-like entanglement as specified by the Einstein-Podolsky-Rosen (EPR) correlation. This distilled entanglement can be further employed to downstream applications such as high fidelity quantum teleportation and a loophole-free Bell test.

  1. The Mathematician and the Mathematics Education Reform

    E-Print Network [OSTI]

    Wu, Hung-Hsi

    The Mathematician and the Mathematics Education Reform H. Wu Department of Mathematics #3840 of [education] reform?" ([EW], p.671) With the current mathematics education reform movement in place for al- most a decade, Moore's words of a century ago become all the more relevant now. The "reform" referred

  2. Multipath Curved Planar Reformation of the Peripheral

    E-Print Network [OSTI]

    Multipath Curved Planar Reformation of the Peripheral Arterial Tree in CT Angiography1 Justus that cause artifacts in multipath curved planar reformations (MPCPRs) of the peripheral arterial tree in 10-oblique multiplanar reformations perpendicular to the ves- sel centerline (10), and curved planar reformations

  3. Optimization of Multiplanar Reformations from Isotropic

    E-Print Network [OSTI]

    Optimization of Multiplanar Reformations from Isotropic Data Sets Acquired with 16­ Detector Row coronal reformations at vari- ous thicknesses were ranked qualitatively by three radiol- ogists. Effective reformations of data acquired in the custom phantom were compared, coronal reformations obtained with the 16

  4. Toward a Reformalization of QSIM Benjamin Shults

    E-Print Network [OSTI]

    Kuipers, Benjamin

    Toward a Reformalization of QSIM Benjamin Shults Department of Mathematics University of Texas is to reformalize part of the framework of the Guaranteed Coverage Theorem for QSIM. The intention is not to reformalize every detail of the proof but merely to mention some areas whose reformalization lends deeper

  5. Crack Path Selection Fatigue crack path imaged via SEM

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Crack path selects secondary phases and interface Conclusions ·Nb-Si Alloys tested exhibited toughness phases fail in a brittle manner Fatigue Crack Growth ABSTRACT Advanced aerospace materials continue at high temperatures. An important property of any high temperature aerospace engineering material is its

  6. Saber's heavy oil cracking refinery project

    SciTech Connect (OSTI)

    Benefield, C.S.; Glasscock, W.L.

    1983-03-01T23:59:59.000Z

    Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

  7. Stress corrosion crack growth in porous sandstones. 

    E-Print Network [OSTI]

    Ojala, Ira O

    Stress corrosion crack growth occurs when the chemical weakening of strained crack tip bonds facilitates crack propagation. I have examined the effect of chemical processes on the growth of a creack population by carrying out triaxial compression...

  8. Multilevel distillation of magic states for quantum computing

    E-Print Network [OSTI]

    Cody Jones

    2013-03-27T23:59:59.000Z

    We develop a procedure for distilling magic states used in universal quantum computing that requires substantially fewer initial resources than prior schemes. Our distillation circuit is based on a family of concatenated quantum codes that possess a transversal Hadamard operation, enabling each of these codes to distill the eigenstate of the Hadamard operator. A crucial result of this design is that low-fidelity magic states can be consumed to purify other high-fidelity magic states to even higher fidelity, which we call "multilevel distillation." When distilling in the asymptotic regime of infidelity $\\epsilon \\rightarrow 0$ for each input magic state, the number of input magic states consumed on average to yield an output state with infidelity $O(\\epsilon^{2^r})$ approaches $2^r+1$, which comes close to saturating the conjectured bound in [Phys. Rev. A 86, 052329]. We show numerically that there exist multilevel protocols such that the average number of magic states consumed to distill from error rate $\\epsilon_{\\mathrm{in}} = 0.01$ to $\\epsilon_{\\mathrm{out}}$ in the range $10^{-5}$ to $10^{-40}$ is about $14\\log_{10}(1/\\epsilon_{\\mathrm{out}}) - 40$; the efficiency of multilevel distillation dominates all other reported protocols when distilling Hadamard magic states from initial infidelity 0.01 to any final infidelity below $10^{-7}$. These methods are an important advance for magic-state distillation circuits in high-performance quantum computing, and they provide insight into the limitations of nearly resource-optimal quantum error correction.

  9. Before the House Oversight and Government Reform Subcommittee...

    Office of Environmental Management (EM)

    Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform...

  10. Distillation and Dehydro Reactors Advanced Process Conrol Freeport Texas PLant

    E-Print Network [OSTI]

    Eisele, D.

    2014-01-01T23:59:59.000Z

    Distillation and Dehydro Reactors Advanced Process Control Freeport Texas Plant ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation...-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC – Control Matrix 6/2/2014 INTERNAL; CONFIDENTIAL 3 ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology...

  11. Construction and operation of a flash distillation apparatus

    E-Print Network [OSTI]

    Knezevich, Milan

    1940-01-01T23:59:59.000Z

    VII HElPEL D1STILLATIONS OF FLASH DISTILLATES OF OKLAHOMA CITY CRUDE Flash Temperature of Distillate XII DoE. F, 260 308 342 392 Volume Distilled per oent Telsp e deE. F. Temp e deE ~ Fs Toslp e doge Fo Tolllp Tolsp e deg. F, doE ~ F..., and they lose much of their kinetio energy to the high boiling molocules ~ Therefore, the solution does not start to vaporise at tho normal boiling point of the low boiling components At low percentages vaporissd flash vaporisation requires a higher vapor...

  12. Energy Use in Distillation Operation: Nonlinear Economic Effects

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation is obviously very...

  13. Magic-state distillation with the four-qubit code

    E-Print Network [OSTI]

    Meier, Adam M; Knill, Emanuel

    2012-01-01T23:59:59.000Z

    The distillation of magic states is an often-cited technique for enabling universal quantum computing once the error probability for a special subset of gates has been made negligible by other means. We present a routine for magic-state distillation that reduces the required overhead for a range of parameters of practical interest. Each iteration of the routine uses a four-qubit error-detecting code to distill the +1 eigenstate of the Hadamard gate at a cost of ten input states per two improved output states. Use of this routine in combination with the 15-to-1 distillation routine described by Bravyi and Kitaev allows for further improvements in overhead.

  14. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  15. Magic-state distillation with the four-qubit code

    E-Print Network [OSTI]

    Adam M. Meier; Bryan Eastin; Emanuel Knill

    2012-04-18T23:59:59.000Z

    The distillation of magic states is an often-cited technique for enabling universal quantum computing once the error probability for a special subset of gates has been made negligible by other means. We present a routine for magic-state distillation that reduces the required overhead for a range of parameters of practical interest. Each iteration of the routine uses a four-qubit error-detecting code to distill the +1 eigenstate of the Hadamard gate at a cost of ten input states per two improved output states. Use of this routine in combination with the 15-to-1 distillation routine described by Bravyi and Kitaev allows for further improvements in overhead.

  16. Synthesis and design of optimal thermal membrane distillation networks

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    Thermal membrane distillation is one of the novel separation methods in the process industry. It involves the simultaneous heat and mass transfer through a hydrophobic semipermeable membrane through the use of thermal energy to bring about...

  17. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01T23:59:59.000Z

    The absorption cycle offers one of the most economic and widely applicable technologies for waste heat upgrading. It can use off-the-shelf hardware that is available now, at any required capacity rating. Fractional distillations, as a class...

  18. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  19. Energy Use in Distillation Operation: Nonlinear Economic Effects 

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation ...

  20. Reducing WWW Latency and Bandwidth Requirements by RealTime Distillation

    E-Print Network [OSTI]

    California at Berkeley, University of

    Reducing WWW Latency and Bandwidth Requirements by Real­Time Distillation Armando Fox and Eric A Distillation and Refinement Can Help 1. The Concept of Datatype­Specific Distillation 2. Refinement 3. Trading. Optimizing for Rendering on Impoverished Devices 3. An Implemented HTTP Proxy Based on Real­Time Distillation

  1. Control strategies for reactive batch distillation Eva Swensen and Sigurd Skogestad"

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control strategies for reactive batch distillation Eva Swensen and Sigurd Skogestad" Department be combined directly with a distillation column by distilling off the light component product in order a maximum value in order to avoid break-through of an intermediate component in the distillate. This maximum

  2. Dividing wall columns for heterogeneous azeotropic distillation Quang-Khoa Le1

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Dividing wall columns for heterogeneous azeotropic distillation Quang-Khoa Le1 , Ivar J. Halvorsen2 of this work is to implement heterogeneous azeotropic distillation schemes in a dividing wall column (DWC distillation, Petlyuk arrangement, energy saving. 1. Introduction Distillation is one of the most energy

  3. Interferometric distillation and determination of unknown two-qubit entanglement

    E-Print Network [OSTI]

    S. -S. B. Lee; H. -S. Sim

    2010-06-08T23:59:59.000Z

    We propose a scheme for both distilling and quantifying entanglement, applicable to individual copies of an arbitrary unknown two-qubit state. It is realized in a usual two-qubit interferometry with local filtering. Proper filtering operation for the maximal distillation of the state is achieved, by erasing single-qubit interference, and then the concurrence of the state is determined directly from the visibilities of two-qubit interference. We compare the scheme with full state tomography.

  4. Heat Recovery in Distillation by Mechanical Vapor Recompression

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    tower energy requirements can be achieved by mechanical vapor recompression. Three design approaches for heating a distillation tower reboiler by mechanical vapor recompression are presented. The advantages of using a screw compressor are discussed... for lowering energy consumption in the distillation process through various heat recovery techniques. (3-8) One such technique utilizes mechanical vapor recompression. (9-12) The principle of this ap proach involves the use of a compressor to recycle...

  5. Single-step distillation protocol with generalized beam splitters

    SciTech Connect (OSTI)

    Martin-Delgado, M. A.; Navascues, M. [Departamento de Fisica Teorica I, Universidad Complutense, 28040 Madrid, (Spain)

    2003-07-01T23:59:59.000Z

    We develop a distillation protocol for multilevel qubits (qudits) using generalized beam splitters like in the proposal of Pan et al. for ordinary qubits. We find an acceleration with respect to the scheme of Bennet et al. when extended to qudits. It is also possible to distill entangled pairs of photons carrying orbital angular momenta states that conserve the total angular momenta as those produced in recent experiments.

  6. Key Distillation and the Secret-Bit Fraction

    E-Print Network [OSTI]

    Nick S. Jones; Lluis Masanes

    2008-05-12T23:59:59.000Z

    We consider distillation of secret bits from partially secret noisy correlations P_ABE, shared between two honest parties and an eavesdropper. The most studied distillation scenario consists of joint operations on a large number of copies of the distribution (P_ABE)^N, assisted with public communication. Here we consider distillation with only one copy of the distribution, and instead of rates, the 'quality' of the distilled secret bits is optimized, where the 'quality' is quantified by the secret-bit fraction of the result. The secret-bit fraction of a binary distribution is the proportion which constitutes a secret bit between Alice and Bob. With local operations and public communication the maximal extractable secret-bit fraction from a distribution P_ABE is found, and is denoted by Lambda[P_ABE]. This quantity is shown to be nonincreasing under local operations and public communication, and nondecreasing under eavesdropper's local operations: it is a secrecy monotone. It is shown that if Lambda[P_ABE]>1/2 then P_ABE is distillable, thus providing a sufficient condition for distillability. A simple expression for Lambda[P_ABE] is found when the eavesdropper is decoupled, and when the honest parties' information is binary and the local operations are reversible. Intriguingly, for general distributions the (optimal) operation requires local degradation of the data.

  7. Peridynamic model for fatigue cracking.

    SciTech Connect (OSTI)

    Silling, Stewart A.; Abe Askari (Boeing)

    2014-10-01T23:59:59.000Z

    The peridynamic theory is an extension of traditional solid mechanics in which the field equations can be applied on discontinuities, such as growing cracks. This paper proposes a bond damage model within peridynamics to treat the nucleation and growth of cracks due to cyclic loading. Bond damage occurs according to the evolution of a variable called the %22remaining life%22 of each bond that changes over time according to the cyclic strain in the bond. It is shown that the model reproduces the main features of S-N data for typical materials and also reproduces the Paris law for fatigue crack growth. Extensions of the model account for the effects of loading spectrum, fatigue limit, and variable load ratio. A three-dimensional example illustrates the nucleation and growth of a helical fatigue crack in the torsion of an aluminum alloy rod.

  8. The Need for Language Repair The Reformation Algorithm Discussion Reformation: A Domain-Independent Algorithm

    E-Print Network [OSTI]

    St Andrews, University of

    The Need for Language Repair The Reformation Algorithm Discussion Reformation: A Domain of Edinburgh University of St Andrews, 27th November 2013 #12;The Need for Language Repair The Reformation Algorithm Discussion Outline 1 The Need for Language Repair 2 The Reformation Algorithm 3 Discussion #12;The

  9. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01T23:59:59.000Z

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  10. Social scientists prompt educational reforms 2

    E-Print Network [OSTI]

    Shahriar, Selim

    Social scientists prompt educational reforms 2 Museum exhibit project 3 On the BookShelf 3 of the 1998 national curricula reforms. For Takehiko Kariya, a professor at the University of Tokyo's Graduate School of Education and one of the reforms' most vocal critics, this shift confirmed what his and other

  11. Patent Reform: Aligning Reward and Contribution

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    4 Patent Reform: Aligning Reward and Contribution Carl Shapiro, University of California major reforms to the patent system designed to spur innovation by better aligning the rewards, and strengthening the procedures by which patents are reexamined after they are issued. Three ad- ditional reforms

  12. Distributional Effects of WTO Agricultural Reforms

    E-Print Network [OSTI]

    Distributional Effects of WTO Agricultural Reforms in Rich and Poor Countries Roman Keeney Purdue Poverty Decrease (000s) Doha Poverty Decrease (000s) Full Reform #12;Farm Income changes for each scenario of Full Reforms -30 -25 -20 -15 -10 -5 0 Top 10% Median Bottom 10% Land Wealth Change Farm Net Worth

  13. Reformation May 30-June 15, 2013

    E-Print Network [OSTI]

    Peak, Derek

    Women of the Reformation Study Tour May 30-June 15, 2013 For more information, please contact Rev registrar.lts@usask.ca by January 29, 2013 We invite you to come and explore the Reformations with us! We hear a lot about the great reformers of the sixteenth century, people like Martin Luther, Phillip

  14. PER-Based Reform at a Multicultural

    E-Print Network [OSTI]

    Steinberg, Richard N.

    PER-Based Reform at a Multicultural Institution Some Lessons from Physics Education Research that the most suc- cessful reform strategies require significant interactions among students, and between students and instructor. It is therefore reasonable to wonder about the extent to which PER-based reform

  15. INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING

    E-Print Network [OSTI]

    INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

  16. Non-Locality Distillation is Impossible for Isotropic Quantum Systems

    E-Print Network [OSTI]

    Dejan D. Dukaric

    2011-09-20T23:59:59.000Z

    Non-locality is a powerful resource for various communication and information theoretic tasks, e.g., to establish a secret key between two parties, or to reduce the communication complexity of distributed computing. Typically, the more non-local a system is, the more useful it is as a resource for such tasks. We address the issue of non-locality distillation, i.e., whether it is possible to create a strongly non-local system by local operations on several weakly non-local ones. More specifically, we consider a setting where non-local systems can be realized via measurements on underlying shared quantum states. The hardest instances for non-locality distillation are the isotropic quantum systems: if a certain isotropic system can be distilled, then all systems of the same non-locality can be distilled as well. The main result of this paper is that non-locality cannot be distilled from such isotropic quantum systems. Our results are based on the theory of cross norms defined over the tensor product of certain Banach spaces. In particular, we introduce a single-parameter family of cross norms, which is used to construct a hierarchy of convex sets that are closed under local operations. This hierarchy interpolates between the set of local systems and an approximation to the set of quantum systems.

  17. Kinetics and thermodynamics of hydrotreating synthetic middle distillates

    SciTech Connect (OSTI)

    Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

    1987-04-01T23:59:59.000Z

    Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

  18. Integrated reformer and shift reactor

    DOE Patents [OSTI]

    Bentley, Jeffrey M.; Clawson, Lawrence G.; Mitchell, William L.; Dorson, Matthew H.

    2006-06-27T23:59:59.000Z

    A hydrocarbon fuel reformer for producing diatomic hydrogen gas is disclosed. The reformer includes a first reaction vessel, a shift reactor vessel annularly disposed about the first reaction vessel, including a first shift reactor zone, and a first helical tube disposed within the first shift reactor zone having an inlet end communicating with a water supply source. The water supply source is preferably adapted to supply liquid-phase water to the first helical tube at flow conditions sufficient to ensure discharge of liquid-phase and steam-phase water from an outlet end of the first helical tube. The reformer may further include a first catalyst bed disposed in the first shift reactor zone, having a low-temperature shift catalyst in contact with the first helical tube. The catalyst bed includes a plurality of coil sections disposed in coaxial relation to other coil sections and to the central longitudinal axis of the reformer, each coil section extending between the first and second ends, and each coil section being in direct fluid communication with at least one other coil section.

  19. The Effect of Reformate on PEM Fuel Cell Performance Mahesh Murthy

    E-Print Network [OSTI]

    Van Zee, John W.

    ). For the reforming process, a steam reforming of methanol and autothermal reforming of natural gas or gasoline

  20. Parallel interacting edge cracks under pure bending

    E-Print Network [OSTI]

    Moran, Ivan

    1991-01-01T23:59:59.000Z

    specimens. . . 66 Table 6. 4 a SIFs for interactive cracks. Position 14. . 73 Table 6. 4 b SIFs for interactive cracks. Position 24 . . 79 Table 6. 4 c SIFs for interactive cracks. Position 13. . 83 Table 6. 5 a K~ff for position 14 Table 6. 5 b K... Table 5. 3 Models Dimensions SPECIMEN MODEL 1 MODEL 2 Length L (inches) Dimension m (in) 6. 50 6. 50 1. 25 1. 25 Spec. Width H (in) 1. 100 1. 276 Thickness t (in) 0. 238 0. 238 Crack Angle p (o) 90 54 Crack Width c (in) Crack Length a (in) 0...

  1. A New Protocol of Continuous-Variable Entanglement Distillation

    E-Print Network [OSTI]

    Shi Jin; Xian-Min Jin; Joshua Nunn; Animesh Datta; Ian Walmsley

    2012-10-16T23:59:59.000Z

    We introduce a new protocol in continuous variable entanglement distillation that requires only linear temporal and constant physical or spatial resources.Compared with the existing protocols, our protocol uses atom-photon entanglement to substitute for atom-atom entanglement in existing protol, which will not only save the number of quantum memories, but also has the advantages in operation efficiency and temporal saving. The distillation can be realized by a fixed model of iterations, in which only three quantum memories and photon detectors are required.

  2. Nonlinear structural crack growth monitoring

    DOE Patents [OSTI]

    Welch, Donald E. (Oak Ridge, TN); Hively, Lee M. (Philadelphia, TN); Holdaway, Ray F. (Clinton, TN)

    2002-01-01T23:59:59.000Z

    A method and apparatus are provided for the detection, through nonlinear manipulation of data, of an indicator of imminent failure due to crack growth in structural elements. The method is a process of determining energy consumption due to crack growth and correlating the energy consumption with physical phenomena indicative of a failure event. The apparatus includes sensors for sensing physical data factors, processors or the like for computing a relationship between the physical data factors and phenomena indicative of the failure event, and apparatus for providing notification of the characteristics and extent of such phenomena.

  3. "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science and Technology (NTNU) Department of Chemical Engineering Working Party on "Distillation, Absorption

  4. CrackTree: Automatic crack detection from pavement images Qin Zou a,b,c,

    E-Print Network [OSTI]

    Wang, Song

    CrackTree: Automatic crack detection from pavement images Qin Zou a,b,c, , Yu Cao c , Qingquan Li b t Pavement cracks are important information for evaluating the road condition and conducting the neces- sary pavement images. In practice, crack detection is a very challenging problem because of (1) low con- trast

  5. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E for manufacturing of ultra pure protium from hydrogen [2]. A principle of hydrogen cryogenic distillation was used

  6. December 13, 2012 The steady state model of a reactive distillation column for ethylene glycol

    E-Print Network [OSTI]

    Neumaier, Arnold

    December 13, 2012 The steady state model of a reactive distillation column for ethylene glycol in an ethylene glycol reactive distillation column. Ind. Eng. Chem. Res., 33:2738­2748, 1994. 3 #12;

  7. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  8. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Gasoline and Diesel Fuel Update (EIA)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  9. Original article Stem cracks in Norway spruce

    E-Print Network [OSTI]

    Boyer, Edmond

    Original article Stem cracks in Norway spruce in southern Scandinavia: causes and consequences Garpenberg, Sweden (Received 1st September 1992; accepted 17 June 1993) Summary — Stem cracks in Norway;INTRODUCTION Background During this century, the widespread crack- ing of Norway spruce (Picea abies L Karst

  10. Cracking Resistance of Asphalt Rubber Mix Versus

    E-Print Network [OSTI]

    Mobasher, Barzin

    . crack length curve for KR #12;Load vs. CMOD 0.0 0.5 1.0 1.5 2.0 Crack mouth opening, mm 0 500 1000 1500 non-linear fracture mechanics ·Compliance approach ·R-Curve approach #12;Conventional Fatigue Testing factor R-Curve approach Resistance to initiation & growth of cracks Evaluates fracture toughness

  11. Plasma-catalyzed fuel reformer

    DOE Patents [OSTI]

    Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

    2013-06-11T23:59:59.000Z

    A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

  12. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

  13. Optimal distillation of three-qubit W states

    E-Print Network [OSTI]

    Ali Yildiz

    2010-07-19T23:59:59.000Z

    Some of the asymmetric three qubit $W$ states are used for perfect teleportation, superdense coding and quantum information splitting. We present the protocols for the optimal distillation of the asymmetric as well as the symmetric $W$ states from a single copy of any three qubit $W$ class pure state.

  14. The application of continuation methods in solving steady-state distillation problems

    E-Print Network [OSTI]

    Ellis, Mark Francis

    1985-01-01T23:59:59.000Z

    80 101 105 CHAPTER I INTRODUCTION Distillation is the most common separ ation process in the chemical and petroleum industr ies. A ma]or tool in the design of distillation columns is steady-state distillation simulation. Also, steady-stat. e...'s Equation 98 B BIFURCATION AND TURNING POINTS ON CONTINUATION PATHS 100 C FORMULATION OF MATHEMATICAI MODELS USED IN EXAMPLE PROBLEMS 104 Problem 1 ? A Conventional Distillation Column Separating an Ideal Solution Problem 2 ? A Conventional...

  15. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Distillation Ivar J. Halvorsen1 and Sigurd Skogestad Norwegian University of Science and Technology, Department at the Topical conference on Separations Technology, Session 23 - Distillation Modeling and Processes II. 2001 Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation Ivar J

  16. Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj Department structures for ethyl tert-butyl ether (ETBE) reactive distillation columns are studied. Two process The use of reactive distillation has grown in recent years because it results in less expensive and more

  17. Rejection and fate of trace organic compounds (TrOCs) during membrane distillation

    E-Print Network [OSTI]

    Rejection and fate of trace organic compounds (TrOCs) during membrane distillation Kaushalya COCs) Direct contact membrane distillation (DCMD) Volatility Fate and transport Hydrophobicity/hydrophilicity a b s t r a c t In this study, we examined the feasibility of membrane distillation (MD) for removing

  18. The dos and don'ts of distillation column control Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    The dos and don'ts of distillation column control Sigurd Skogestad* Department of Chemical discusses distillation column control within the general framework of plantwide control. In addition for distillation columns. The standard LV-configuration combined with a fast temperature loop is recommended

  19. Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column distillation columns have been explored in many papers, very few papers have dealt with closed-loop control. Most of these control papers consider reactive distillation columns in which there is only one product

  20. MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA S RENSEN 2

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA S RENSEN 2 and RAJAB LITTO column presented in this paper provides a generalization of previously proposed batch distillation schemes. The economic potential of the multivessel batch distillation under total re ux is demon- strated

  1. Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements-integrated multi-effect and three non-integrated distillation arrangements for separating a ternary mixture have been considered. The focus of the paper is on a heat-integrated complex distillation configuration

  2. Experimental and Theoretical Studies on the Start-Up Operation of a Multivessel Batch Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Experimental and Theoretical Studies on the Start-Up Operation of a Multivessel Batch DistillationVersity of Science and Technology, Trondheim, Norway Multivessel batch distillation is a promising alternative to conventional batch distillation. Earlier studies proved the feasibility of temperature control in a closed

  3. On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal

    E-Print Network [OSTI]

    Skogestad, Sigurd

    On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal Binary Columns distillation processes. By considering the e ect of small changes in the operating parameters, e.g., initial-mail: jacobsen@elixir.e.kth.se 1 #12;1 Introduction Batch distillation has become of increasing importance

  4. Optimization of a Diabatic Distillation Column with Sequential Heat Edward Steven Jimenez and Peter Salamon*

    E-Print Network [OSTI]

    Salamon, Peter

    Optimization of a Diabatic Distillation Column with Sequential Heat Exchangers Edward Steven of Copenhagen, Copenhagen, Denmark Diabatic distillation is a separation process in which heat is transferred is enormous because distillation is the single largest energy degrading unit operation worldwide. Introduction

  5. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial heat integrated distillation column Truls Larsson Sigurd Skogestad ÝDepartment of Chemical. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process QH column

  6. THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES --WITH APPLICATION TO DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES --WITH APPLICATION TO DISTILLATION COLUMNS John Morud that a subsystem is influenced only by its nabor subsystems. An example of such a process is a distillation column in high purity distillation columns; in fact, the magnitude of these time constants may increase

  7. Topic Distillation with Query-Dependent Link Connections and Page Characteristics

    E-Print Network [OSTI]

    Wu, Mingfang

    6 Topic Distillation with Query-Dependent Link Connections and Page Characteristics MINGFANG WU about a topic. Finding such results is called topic distillation. Previous research has shown statistics. This article presents a new approach to improve topic distillation by exploring the use

  8. Use of Two Distillation Columns in Systems with Maximum Temperature Limitations

    E-Print Network [OSTI]

    Gilchrist, James F.

    Use of Two Distillation Columns in Systems with Maximum Temperature Limitations Rebecca H. Masel, Pennsylvania 18015, United States ABSTRACT: Maximum temperature limitations are encountered in distillation of the bottoms product fixes the column base pressure and, hence, the condenser pressure. The distillate

  9. On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal

    E-Print Network [OSTI]

    Skogestad, Sigurd

    On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal Binary Columns sensitivity in batch distillation processes. By considering the effect of small changes in the operating #12; 1 Introduction Batch distillation has become of increasing importance in industry during the last

  10. Know-Center at TREC 2009 Blog Distillation Task: A Notebook Paper

    E-Print Network [OSTI]

    Hammerton, James

    Know-Center at TREC 2009 Blog Distillation Task: A Notebook Paper Elisabeth Lex, Michael Granitzer,mgrani,ajuffinger}@know-center.at Abstract. This paper outlines our experiments carried out at TREC 2009 Blog Distillation Task. Our system, specifically the blog distillation task, exactly this problem is addressed. The goal of the track is to rank

  11. MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad1

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad1 The experimental veri cation of the operation of a multivessel batch distillation column, operated under total re vessels, provides a generalization of previously proposed batch distillation schemes. We propose a simple

  12. Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column Edward Abstract Diabatic distillation is a separation process in which heat is transferred on the trays inside savings is through diabatic distillation. Instead of just one heat source (the reboiler) and one heat sink

  13. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum-boiling azeotropic mixtures, where the extractive agent and a control structure for the batch extractive middle vessel distillation is proposed. In extractive

  14. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimization of Distillation Processes. José A. Caballero* and Ignacio E. Grossmann** *Dept and a single condenser in the entire sequence. We also review the rigorous design of distillation columns, or column sequences. In all the cases we focus on mathematical programming approaches. Keywords Distillation

  15. Enhanced Topic Distillation using Text, Markup Tags, and Hyperlinks Soumen Chakrabarti

    E-Print Network [OSTI]

    Chakrabarti, Soumen

    Enhanced Topic Distillation using Text, Markup Tags, and Hyperlinks Soumen Chakrabarti Mukul Joshi Vivek Tawde IIT Bombay ABSTRACT Topic distillation is the analysis of hyperlink graph structure to authorities). Topic distillation is becoming common in Web search engines, but the best-known algorithms model

  16. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process system for TAME reactive distillation process using extraction column with water as a solvent. The design distillation column which was optimized to recover methanol and recycle water to the extraction column. Other

  17. DISTILLATION DES LIQUIDES SOUS L'INFLUENCE DE L'LECTRICIT STATIQUE; PAR M. D. GERNEZ.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    36I DISTILLATION DES LIQUIDES SOUS L'INFLUENCE DE L'ÉLECTRICITÉ STATIQUE; PAR M. D. GERNEZ. La décharge, la distillation se produit aussitôt en sens in- verse (2). Ce phénomène est extrêmemen t n e sens suivant lequel se produit cette distillation est contraire à celui que sem- bleraient indiquer les

  18. Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami-Beckner inequality

    E-Print Network [OSTI]

    O'Donnell, Ryan

    Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami In this paper we study non-interactive correlation distillation (NICD), a generalization of noise sen- sitivity distillation (NICD), previously considered in [5, 31, 39]. In its most general form the problem involves k

  19. Retrieval and Feedback Models for Blog Distillation Jonathan Elsas, Jaime Arguello, Jamie Callan, Jaime Carbonell

    E-Print Network [OSTI]

    Carbonell, Jaime

    Retrieval and Feedback Models for Blog Distillation Jonathan Elsas, Jaime Arguello, Jamie Callan and results for the Feed Distillation task in the Blog track at TREC 2007. Our experiments focus on two Wikipedia. 1 Introduction Blog distillation (or "feed search") is the task of finding blog feeds

  20. Assured Information Distillation in Social Sensing University of Illinois at Urbana-Champaign

    E-Print Network [OSTI]

    Garibaldi, Skip

    Colloquium Assured Information Distillation in Social Sensing Dong Wang University of Illinois. This opens up unprecedented challenges and opportunities in social sensing, where the goal is to distill, social and physical networks. The talk will also introduce a new information distillation system we built

  1. MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA SRENSEN 2

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA SØRENSEN 2 and RAJAB LITTO column presented in this paper provides a generalization of previously proposed batch distillation schemes. The economic potential of the multivessel batch distillation under total reflux is demon­ strated

  2. Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse

    E-Print Network [OSTI]

    Regev, Oded

    Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami In this paper we study non-interactive correlation distillation (NICD), a generalization of noise sensitivity in this paper is the problem of non-interactive correlation distil- lation (NICD), previously considered in [5

  3. Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating Vidar Trondheim, Norway Keywords: Distillation, Petlyuk, Divided-wall, Minimum energy Abstract This paper shows the unexpected result that over-fractionating one of the product streams in a Petlyuk distillation column may

  4. Sustainable operation of membrane distillation for enhancement of mineral recovery from hypersaline solutions

    E-Print Network [OSTI]

    Sustainable operation of membrane distillation for enhancement of mineral recovery from hypersaline December 2013 Available online 25 December 2013 Keywords: Membrane distillation Desalination Hypersaline brine Scaling Membrane cleaning Evaporation pond a b s t r a c t Membrane distillation (MD

  5. Noisy Processing and the Distillation of Private States Joseph M. Renes1

    E-Print Network [OSTI]

    Noisy Processing and the Distillation of Private States Joseph M. Renes1 and Graeme Smith2 1 general private state is distilled. Besides a more general target state, the usual entanglement distillation tools are employed (in par- ticular, Calderbank-Shor-Steane (CSS)-like codes), with the crucial

  6. THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES WITH APPLICATION TO DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES WITH APPLICATION TO DISTILLATION COLUMNS John Morud that a subsystem is in uenced only by its nabor subsystems. An example of such a process is a distillation column in high purity distillation columns; in fact, the magnitude of these time constants may increase

  7. A globally convergent method for finding all steady-state solutions of distillation columns

    E-Print Network [OSTI]

    Neumaier, Arnold

    A globally convergent method for finding all steady-state solutions of distillation columns Ali distillation column with 7 steady-states show the robustness of the method. No published software known to the steady-state model of distillation columns as it returns the original system as a single large block

  8. Distillation Codes and Applications to DoS Resistant Multicast Authentication

    E-Print Network [OSTI]

    Perrig, Adrian

    Distillation Codes and Applications to DoS Resistant Multicast Authentication Chris Karlof UC We introduce distillation codes, a method for streaming and storing data. Like erasure codes, distillation codes allow information to be decoded from a sufficiently large quorum of symbols. In contrast

  9. Synthesizing Representative I/O Workloads Using Iterative Distillation Zachary Kurmas

    E-Print Network [OSTI]

    Kurmas, Zachary

    Synthesizing Representative I/O Workloads Using Iterative Distillation Zachary Kurmas College proper- ties are "key" for a given workload and storage system. We have developed a tool, the Distiller, that automati- cally identifies the key properties ("attribute-values") of the workload. The Distiller then uses

  10. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum­boiling azeotropic mixtures, where the extractive agent and a control structure for the batch extractive middle vessel distillation is proposed. In extractive

  11. Integrating the Document Object Model with Hyperlinks for Enhanced Topic Distillation and Information Extraction

    E-Print Network [OSTI]

    Chakrabarti, Soumen

    Integrating the Document Object Model with Hyperlinks for Enhanced Topic Distillation://www.cse.iitb.ernet.in/~soumen ABSTRACT Topic distillation is the process of finding authoritative Web pages and comprehensive "hubs distillation has been traditionally applied to a macroscopic Web model where documents are nodes in a directed

  12. SEPARATION OF TERNARY HETEROAZEOTROPIC MIXTURES IN A CLOSED MULTIVESSEL BATCH DISTILLATION-DECANTER HYBRID

    E-Print Network [OSTI]

    Skogestad, Sigurd

    SEPARATION OF TERNARY HETEROAZEOTROPIC MIXTURES IN A CLOSED MULTIVESSEL BATCH DISTILLATION, Trondheim, Norway The feasibility of a novel multivessel batch distillation-decanter hybrid for simultaneous enables us to make direct use of the distillation line (or residue curve) map. Simple rules for predicting

  13. Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio Sebastiani

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio in revised form 10 May 2013 Accepted 30 May 2013 Available online 14 June 2013 Keywords: Blog distillation to blog distillation, defined as the task in which, given a user query, the system ranks the blogs

  14. Complex Distillation Arrangements 23.May 2001 by I.Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Complex Distillation Arrangements 23.May 2001 by I.Halvorsen NTNU Department of Chemical Engineering 1 Minimum Energy Requirements in Complex Distillation Arrangements A thesis submitted for the degree of dr. ing. 23. May 2001 by Ivar J. Halvorsen #12;Complex Distillation Arrangements 23.May 2001

  15. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial heat integrated distillation column Truls Larsson Sigurd Skogestad y Department of Chemical. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process Q H column

  16. Manifold-based starting point generation and its application to distillation

    E-Print Network [OSTI]

    Neumaier, Arnold

    Manifold-based starting point generation and its application to distillation Ali Baharev*, Ferenc-states in homogeneous azeotropic distillation . . . . . . . . . . 11 5.2 Multiple steady-states in ideal two-product distillation . . . . . . . . . . . . . . 11 6 Conclusion 13 A Ordering sparse matrices 14 A.1 Ordering to block

  17. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    structure design. Keywords: Kaibel column, thermally coupled distillation columns, optimal operation 1J.Halvorsen@sintef.no Abstract The objective of this paper is to study the Kaibel distillation column from operability point. Introduction The thermally-coupled Petlyuk 1 distillation column separates the feed into three products

  18. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    is a viable option in present case. Keywords: Distillation, Energy saving, Dividing wall column, Thermal challenge is to design distillation systems that at the same time are sustainable and economically feasibleDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved

  19. Optimal Synthesis of Thermally Coupled Distillation Sequences Using a Novel MILP Approach.

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    . Pittsburgh, PA. USA. Abstract This paper introduces a novel MILP approach for the design of distillation Column; Superstructure optimization; GDP. Introduction Distillation is the most widely used method distillation (TCD), in which heat is directly transferred between columns through two streams (liquid a vapor

  20. Active Constraint Regions for Optimal Operation of Distillation Magnus G. Jacobsen and Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , NTNU, N-7491, Trondheim, Norway ABSTRACT: When designing the control structure of distillation columnsActive Constraint Regions for Optimal Operation of Distillation Columns Magnus G. Jacobsen presented in an earlier paper, to find how the active constraints for distillation columns change

  1. Model predictive control of a pilot-scale distillation column using a programmable automation controller

    E-Print Network [OSTI]

    Model predictive control of a pilot-scale distillation column using a programmable automation). The controller is tested on a pilot-scale binary distillation column to track reference temperatures. A majorRIO) to control a pilot-scale binary distillation col- umn. Both the PI-controllers and the supervising online MPC

  2. Steam reforming utilizing high activity catalyst

    SciTech Connect (OSTI)

    Setzer, H. J.

    1985-03-05T23:59:59.000Z

    High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

  3. Plasmatron Fuel Reformer Development and Internal Combustion...

    Broader source: Energy.gov (indexed) [DOE]

    Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications* L. Bromberg MIT Plasma Science and Fusion Center Cambridge MA 02139 * Work supported by US...

  4. Hydrogen from Biomass by Autothermal Reforming

    Broader source: Energy.gov [DOE]

    Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  5. Distributed Bio-Oil Reforming (Presentation)

    SciTech Connect (OSTI)

    Evans, R. J.; Czernik, S.; French, R.; Ratcliff, M.; Marda, J.; Dean, A. M.

    2007-05-15T23:59:59.000Z

    This presentation by Bob Evans at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's distributed bio-oil reforming efforts.

  6. Plasmatron Fuel Reformer Development and Internal Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment Onboard Plasmatron Generation of Hydrogen rich Gas for...

  7. Lessons Learned from Prior Attempts at National Security Reform The Project on National Security Reform

    E-Print Network [OSTI]

    Lewis, Robert Michael

    Lessons Learned from Prior Attempts at National Security Reform The Project on National Security Reform Overarching Issues Working Group Drew Cramer & Grant Mullins Thomas Jefferson Program in Public battles that ensue when attempting to change the national security apparatus can hinder effective reform

  8. Environmentally assisted cracking of LWR materials

    SciTech Connect (OSTI)

    Chopra, O.K.; Chung, H.M.; Kassner, T.F.; Shack, W.J.

    1995-12-01T23:59:59.000Z

    Research on environmentally assisted cracking (EAC) of light water reactor materials has focused on (a) fatigue initiation in pressure vessel and piping steels, (b) crack growth in cast duplex and austenitic stainless steels (SSs), (c) irradiation-assisted stress corrosion cracking (IASCC) of austenitic SSs, and (d) EAC in high- nickel alloys. The effect of strain rate during different portions of the loading cycle on fatigue life of carbon and low-alloy steels in 289{degree}C water was determined. Crack growth studies on wrought and cast SSs have been completed. The effect of dissolved-oxygen concentration in high-purity water on IASCC of irradiated Type 304 SS was investigated and trace elements in the steel that increase susceptibility to intergranular cracking were identified. Preliminary results were obtained on crack growth rates of high-nickel alloys in water that contains a wide range of dissolved oxygen and hydrogen concentrations at 289 and 320{degree}C. The program on Environmentally Assisted Cracking of Light Water Reactor Materials is currently focused on four tasks: fatigue initiation in pressure vessel and piping steels, fatigue and environmentally assisted crack growth in cast duplex and austenitic SS, irradiation-assisted stress corrosion cracking of austenitic SSs, and environmentally assisted crack growth in high-nickel alloys. Measurements of corrosion-fatigue crack growth rates (CGRs) of wrought and cast stainless steels has been essentially completed. Recent progress in these areas is outlined in the following sections.

  9. Inquiry-Based Learning: An Educational Reform Based

    E-Print Network [OSTI]

    McLoughlin, Padraig

    -Based Learning: An Educational Reform Based Upon Content-Centred Teaching. 1046-Centred Educational Reform 3 III Inquiry-Based Learning Pedagogy is Content 27 #12; ii Abstract Inquiry-Based Learning: An Educational Reform

  10. A Reformed Mathematics Education at Chalmers Stig Larsson

    E-Print Network [OSTI]

    Larsson, Stig

    A Reformed Mathematics Education at Chalmers Stig to reform to effectively use t* *he new tools offered by computers. We present a program for a reformed engineering mathematics * *education. The full program covering the basic mathematics

  11. Comparative case studies of health reform in England

    E-Print Network [OSTI]

    Birmingham, University of

    Comparative case studies of health reform in England Report submitted to the Department of Health........................................................................................14 1.1 Presenting the Health System Reform policy agenda...................................14 1 ..........................................................................................64 Demand Side Reform.........................................

  12. Apparatus for production of synthesis gas using convective reforming

    SciTech Connect (OSTI)

    Karafian, M.; Tsang, I.C.

    1991-04-09T23:59:59.000Z

    This patent describes a system for the steam reforming of hydrocarbons into a hydrogen-rich gas. It comprises a convective reformer device having indirect heat exchange means for partially reforming a feed mixture of hydrocarbons and steam; a steam reforming furnace having a radiant section, reforming tubes in the radiant section, and means for producing radiant heat for the further reforming of the partially reformed effluent; an auto-thermal reformer for fully reforming the effluent; conduit means for passing the partially reformed effluent; conduit means for passing the effluent; and conduit means for passing the fully reformed effluent to supply the heat of reaction for the partial reformation of the hydrocarbon-steam feed mixture.

  13. Solid oxide fuel cell steam reforming power system

    DOE Patents [OSTI]

    Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

    2013-03-12T23:59:59.000Z

    The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

  14. Cascading of fluid cracking catalysts

    SciTech Connect (OSTI)

    Kovach, S.M.; Miller, C.B.

    1986-05-27T23:59:59.000Z

    A process is described for conversion of hydrocarbon feedstocks by cascading a cracking catalyst containing zeolite in an acidic matrix from one hydrocarbon processing unit to another, wherein there are at least three different interconnected hydrocarbon processing units comprising a first unit having a regeneration zone and a riser zone, a second unit having having a regeneration zone and a riser zone, and a third unit having a riser zone and a regeneration zone, each unit having different processing conditions.

  15. Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements...

  16. Research and Development of a PEM Fuel Cell, Hydrogen Reformer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of a PEM Fuel Cell, Hydrogen Reformer, and Vehicle Refueling Facility Research and Development of a PEM Fuel Cell, Hydrogen Reformer, and Vehicle Refueling Facility Technical paper...

  17. STEM education reform A public research university imperative!

    E-Print Network [OSTI]

    Sin, Peter

    STEM education reform A public research university imperative! University of Florida A significant education reform initiative for introductory courses. Will these -- and a growing number of other national

  18. Design, Modeling, and Validation of a Flame Reformer for LNT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration...

  19. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reforming, Darlene Steward, National Renewable Energy Laboratory High-Pressure Steam Ethanol Reforming, Romesh Kumar, Argonne National Laboratory Investigation of Bio-Ethanol...

  20. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Presented at the 2007...

  1. Before the House Committee on Oversight and Government Reform...

    Energy Savers [EERE]

    Oversight and Government Reform Subcommittee on the Interior Before the House Committee on Oversight and Government Reform Subcommittee on the Interior Testimony of John Kotek,...

  2. Regulatory and Financial Reform of Federal Research Policy: Recommenda...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy:...

  3. Secretary Moniz to Present Project Management Reforms to the...

    Energy Savers [EERE]

    Moniz to Present Project Management Reforms to the National Academy of Public Administration Secretary Moniz to Present Project Management Reforms to the National Academy of Public...

  4. Diesel Reforming for Fuel Cell Auxiliary Power Units

    SciTech Connect (OSTI)

    Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

    2005-01-27T23:59:59.000Z

    This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

  5. Hydrogen generation from plasmatron reformers and use for diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003 DEER...

  6. Comparative Investigation of Benzene Steam Reforming over Spinel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts....

  7. Distillation and purification of symmetric entangled Gaussian states

    E-Print Network [OSTI]

    Jaromir Fiurasek

    2010-11-03T23:59:59.000Z

    We propose an entanglement distillation and purification scheme for symmetric two-mode entangled Gaussian states that allows to asymptotically extract a pure entangled Gaussian state from any input entangled symmetric Gaussian state. The proposed scheme is a modified and extended version of the entanglement distillation protocol originally developed by [Browne et al., Phys. Rev. A 67, 062320 (2003)]. A key feature of the present protocol is that it utilizes a two-copy de-Gaussification procedure that involves a Mach-Zehnder interferometer with single-mode non-Gaussian filters inserted in its two arms. The required non-Gaussian filtering operations can be implemented by coherently combining two sequences of single-photon addition and subtraction operations.

  8. Distillation of entanglement by projection on permutationally invariant subspaces

    E-Print Network [OSTI]

    Czechlewski, Miko?aj; Horodecki, Micha?; Mozrzymas, Marek; Studzi?ski, Micha?

    2011-01-01T23:59:59.000Z

    We consider distillation of entanglement from two qubit states which are mixtures of three mutually orthogonal states: two pure entangled states and one pure product state. We distill entanglement from such states by projecting n copies of the state on permutationally invariant subspace and then applying one-way hashing protocol. We find analytical expressions for the rate of the protocol. We also generalize this method to higher dimensional systems. To get analytical expression for two qubit case, we faced a mathematical problem of diagonalizing a family of matrices enjoying some symmetries w.r.t. to symmetric group. We have solved this problem in two ways: (i) directly, by use of Schur-Weyl decomposition and Young symmetrizers (ii) showing that the problem is equivalent to a problem of diagonalizing adjacency matrices in a particular instance of a so called algebraic association scheme.

  9. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  10. Reducing the quantum computing overhead with complex gate distillation

    E-Print Network [OSTI]

    Guillaume Duclos-Cianci; David Poulin

    2014-03-20T23:59:59.000Z

    In leading fault-tolerant quantum computing schemes, accurate transformation are obtained by a two-stage process. In a first stage, a discrete, universal set of fault-tolerant operations is obtained by error-correcting noisy transformations and distilling resource states. In a second stage, arbitrary transformations are synthesized to desired accuracy by combining elements of this set into a circuit. Here, we present a scheme which merges these two stages into a single one, directly distilling complex transformations. We find that our scheme can reduce the total overhead to realize certain gates by up to a few orders of magnitude. In contrast to other schemes, this efficient gate synthesis does not require computationally intensive compilation algorithms, and a straightforward generalization of our scheme circumvents compilation and synthesis altogether.

  11. Methanol Steam Reformer on a Silicon Wafer

    SciTech Connect (OSTI)

    Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

    2004-04-15T23:59:59.000Z

    A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

  12. Enabling Informed Adaptation of Reformed Instructional Materials

    E-Print Network [OSTI]

    Elby, Andy

    Enabling Informed Adaptation of Reformed Instructional Materials Rachel E. Scherr and Andrew Elby 20742 USA Abstract. Instructors inevitably need to adapt even the best reform materials to suit instructors, and video clips of students working on the materials. Our materials thus facilitate their own

  13. Fuel cell integrated with steam reformer

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

    1987-01-01T23:59:59.000Z

    A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

  14. Distillation of hydrogen isotopes for polarized HD target

    E-Print Network [OSTI]

    T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouill'; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

    2011-12-12T23:59:59.000Z

    We have developed a cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for a polarized HD target in LEPS experiments at SPring-8. A small amount of ortho-H$_2$ ($\\sim$0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1$\\sim$5% impurities of H$_2$ and D$_2$ in commercially available HD gases, it is inevitable that the HD gas is purified up to $\\sim$99.99%. The distillation system has a cryogenic pot (17$\\sim$21 K) containing many small stainless steel cells called Heli-pack. Commercial HD gas with an amount of 5.2 mol is fed into the pot. We carried out three distillation runs by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed by using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. The HD gas of 1 mol with a purity better than 99.99% has been successfully obtained. The effective NTS (Number of Theoretical Stages), which is an indicator of the distillator performances, is obtained as 37.2$\\pm$0.6. This value is in reasonable agreement with a designed value of 37.9. The HD target is expected to be efficiently polarized under a well-controlled condition by doping an optimal amount of ortho-H$_2$ to the purified HD gas.

  15. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  16. An experimental and mathematical investigation of hydrocarbon steam distillation

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01T23:59:59.000Z

    the Holland and Welch method was very good. The agreement between experimental and predicted separation data indicated the Holland and Welch method could be extended to calculate crude oil-water -vapor separations. A practical procedure using the Holland... and Welch method and simulated distillation data was developed to predict crude oil-water-vapor separations. The method was compared to experimental crude oil-water-vapor separation data obtained at saturated steam conditions of 378 F and 456 F...

  17. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23T23:59:59.000Z

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  18. Distillation of hydrogen isotopes for polarized HD target

    E-Print Network [OSTI]

    Ohta, T; Didelez, J -P; Fujiwara, M; Fukuda, K; Kohri, H; Kunimatsu, T; Morisaki, C; Ono, S; Rouill', G; Tanaka, M; Ueda, K; Uraki, M; Utsuro, M; Wang, S Y; Yosoi, M

    2011-01-01T23:59:59.000Z

    We have developed a cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for a polarized HD target in LEPS experiments at SPring-8. A small amount of ortho-H$_2$ ($\\sim$0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1$\\sim$5% impurities of H$_2$ and D$_2$ in commercially available HD gases, it is inevitable that the HD gas is purified up to $\\sim$99.99%. The distillation system has a cryogenic pot (17$\\sim$21 K) containing many small stainless steel cells called Heli-pack. Commercial HD gas with an amount of 5.2 mol is fed into the pot. We carried out three distillation runs by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed by using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. The HD gas of 1 mol with a purity better than 99.99% has been successfully obtained. The effective NTS (Number of Theoretical Stages), which is...

  19. Characterization of cracking restraint at sawcut joints using the German Cracking Frame

    E-Print Network [OSTI]

    Vepakomma, Shilpa

    2002-01-01T23:59:59.000Z

    Cracking of concrete slabs at sawcut notches is a major concern in the early stages of construction. Several factors affecting crack initiation are material strength parameters, method and quality of curing, slab/subbase stiffness, and concrete...

  20. Characterization of geothermal reservoir crack patterns using...

    Open Energy Info (EERE)

    reservoir crack patterns using shear-wave splitting Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Characterization of geothermal reservoir...

  1. Slow crack growth in polycarbonate films

    E-Print Network [OSTI]

    Cortet, Pierre-Philippe; Vanel, Loic; Ciliberto, Sergio

    2005-01-01T23:59:59.000Z

    We study experimentally the slow growth of a single crack in polycarbonate films submitted to uniaxial and constant imposed stress. The specificity of fracture in polycarbonate films is the appearance of flame shaped macroscopic process zones at the tips of the crack. Supported by an experimental study of the mechanical properties of polycarbonate films, an analysis of the stress dependence of the mean ratio between the process zone and crack lengths, during the crack growth, show a quantitative agreement with the Dugdale-Barenblatt model of the plastic process zone. We find that the fracture growth curves obey strong scaling properties that lead to a well defined growth master curve.

  2. White Etching Cracks | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Etching Cracks Presented by Walter Holweger of Schaeffler at the Wind Turbine Tribology Seminar 2014. NREL Chicago291014Holweger26nosec...

  3. 7. Low temperature cracking in HMA Pavement Cracking Al-Qadi, Scarpas & Loizos (eds)

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    7. Low temperature cracking in HMA 367 #12;#12;Pavement Cracking ­ Al-Qadi, Scarpas & Loizos (eds, Storrs, Connecticut, USA ABSTRACT: Low temperature cracking remains one of the major pavement distresses in asphalt concrete pavements in cold regions. An integrated laboratory testing, field performance data

  4. Integrated hydrocarbon reforming system and controls

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Thijssen, Johannes; Davis, Robert; Papile, Christopher; Rumsey, Jennifer W.; Longo, Nathan; Cross, III, James C.; Rizzo, Vincent; Kleeburg, Gunther; Rindone, Michael; Block, Stephen G.; Sun, Maria; Morriseau, Brian D.; Hagan, Mark R.; Bowers, Brian

    2003-11-04T23:59:59.000Z

    A hydrocarbon reformer system including a first reactor configured to generate hydrogen-rich reformate by carrying out at least one of a non-catalytic thermal partial oxidation, a catalytic partial oxidation, a steam reforming, and any combinations thereof, a second reactor in fluid communication with the first reactor to receive the hydrogen-rich reformate, and having a catalyst for promoting a water gas shift reaction in the hydrogen-rich reformate, and a heat exchanger having a first mass of two-phase water therein and configured to exchange heat between the two-phase water and the hydrogen-rich reformate in the second reactor, the heat exchanger being in fluid communication with the first reactor so as to supply steam to the first reactor as a reactant is disclosed. The disclosed reformer includes an auxiliary reactor configured to generate heated water/steam and being in fluid communication with the heat exchanger of the second reactor to supply the heated water/steam to the heat exchanger.

  5. AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA

    E-Print Network [OSTI]

    AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA Jeffrey Sachs ABSTRACT: The paper reviews the experience of Poland and Russia with economic reform, with occasional comparison to China's experience. The author argues that macroeconomic chaos in Poland and Russia preceded reform and was allayed by reform

  6. Electricity reform in developing and transition countries: A reappraisal

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

  7. September 25, 2013 AFSCME Continues to Object to Pension Reform;

    E-Print Network [OSTI]

    Leistikow, Bruce N.

    September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

  8. REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH

    E-Print Network [OSTI]

    Royal Holloway, University of London

    REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH Cecilia TESTA London School of Economics are a reform and a compensating taxation. The main feature of the reform is that it creates gainers and losers on tax parameters. keywords: reform, lobbying, redistribution, economic welfare. 1 #12;Introduction

  9. Autothermal Cyclic Reforming Based H2 Generating & Dispensing System

    E-Print Network [OSTI]

    Pressure Reforming Comp- ressor 100 psig 100 psig Reformer H2 PSA SyngasNatural Gas Low Pressure Reforming CMP Syngas 5 psig5 psig Reformer CMP 100 psig H2 PSA Natural Gas Syngas CMP HX CMP HX Thermal Reliability (Eliminates Syngas Compressor) Advantages 70-80%70-80%Thermal Efficiency (Excludes Electricity

  10. Internal reforming fuel cell assembly with simplified fuel feed

    DOE Patents [OSTI]

    Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

    2001-01-01T23:59:59.000Z

    A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

  11. Steam reforming utilizing iron oxide catalyst

    SciTech Connect (OSTI)

    Setzer, H. T.; Bett, J. A. S.

    1985-06-11T23:59:59.000Z

    High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

  12. Bound States for Magic State Distillation in Fault-Tolerant Quantum Computation

    E-Print Network [OSTI]

    Earl T. Campbell; Dan E. Browne

    2010-02-01T23:59:59.000Z

    Magic state distillation is an important primitive in fault-tolerant quantum computation. The magic states are pure non-stabilizer states which can be distilled from certain mixed non-stabilizer states via Clifford group operations alone. Because of the Gottesman-Knill theorem, mixtures of Pauli eigenstates are not expected to be magic state distillable, but it has been an open question whether all mixed states outside this set may be distilled. In this Letter we show that, when resources are finitely limited, non-distillable states exist outside the stabilizer octahedron. In analogy with the bound entangled states, which arise in entanglement theory, we call such states bound states for magic state distillation.

  13. 082714-416430-Water-Resources-Reform Page 1 of 12 Water Resources Reform and Development Act of 2014

    E-Print Network [OSTI]

    US Army Corps of Engineers

    082714-416430-Water-Resources-Reform Page 1 of 12 Water Resources Reform and Development Act to the Water Resources Reform and Development Act 2014 Listening Session. My name is Jan Rasgus. I'm a senior of you know, President Obama signed the Water Resources Reform and Development Act, WRRDA, of 2014

  14. Multiple steady states during reactive distillation of methyl tert-butyl ether

    SciTech Connect (OSTI)

    Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

    1993-11-01T23:59:59.000Z

    This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

  15. Crack shape developments and leak rates for circumferential complex-cracked pipes

    SciTech Connect (OSTI)

    Brickstad, B.; Bergman, M. [SAQ Inspection Ltd., Stockholm (Sweden)

    1997-04-01T23:59:59.000Z

    A computerized procedure has been developed that predicts the growth of an initial circumferential surface crack through a pipe and further on to failure. The crack growth mechanism can either be fatigue or stress corrosion. Consideration is taken to complex crack shapes and for the through-wall cracks, crack opening areas and leak rates are also calculated. The procedure is based on a large number of three-dimensional finite element calculations of cracked pipes. The results from these calculations are stored in a database from which the PC-program, denoted LBBPIPE, reads all necessary information. In this paper, a sensitivity analysis is presented for cracked pipes subjected to both stress corrosion and vibration fatigue.

  16. Development of crack shape: LBB methodology for cracked pipes

    SciTech Connect (OSTI)

    Moulin, D.; Chapuliot, S.; Drubay, B. [Commissariat a l Energie Atomique, Gif sur Yvette (France)

    1997-04-01T23:59:59.000Z

    For structures like vessels or pipes containing a fluid, the Leak-Before-Break (LBB) assessment requires to demonstrate that it is possible, during the lifetime of the component, to detect a rate of leakage due to a possible defect, the growth of which would result in a leak before-break of the component. This LBB assessment could be an important contribution to the overall structural integrity argument for many components. The aim of this paper is to review some practices used for LBB assessment and to describe how some new R & D results have been used to provide a simplified approach of fracture mechanics analysis and especially the evaluation of crack shape and size during the lifetime of the component.

  17. SciTech Connect: CRACK TIP PLASTICITY AND FRACTURE INITIATION...

    Office of Scientific and Technical Information (OSTI)

    N50000* --Metals, Ceramics, & Other Materials; CRACKS; FRACTURE PROPERTIES; METALS BUILDING MATERIALSfracture of metal, crack tip plasticity and initiation criteria for;...

  18. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  19. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  20. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  1. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  2. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

  3. Copyright Law Reform: Some Achievable Goals 

    E-Print Network [OSTI]

    MacQueen, Hector L

    2007-01-01T23:59:59.000Z

    Copyright law reform in the European Union. The chapter discusses possible actions in light of new and amended EU Directives and whether these balances rights' holders and users' interests....

  4. Electricity reform abroad and US investment

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

  5. Device for cooling and humidifying reformate

    DOE Patents [OSTI]

    Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

    2008-04-08T23:59:59.000Z

    Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

  6. Electrical Generation Tax Reform Act (Montana)

    Broader source: Energy.gov [DOE]

    This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the Montana electric utility industry that allows...

  7. March 9, 2001 REPORT TO THE INTERNATIONAL ENERGY AGENCY

    E-Print Network [OSTI]

    . Steam methane reforming B. Partial oxidation C. Auto-thermal reforming D. Methanol reforming E oxidation, autothermal reforming, methanol reforming, ammonia cracking and catalytic cracking of methane

  8. Life prediction for bridged fatigue cracks

    SciTech Connect (OSTI)

    Cox, B.N.

    1994-08-01T23:59:59.000Z

    One of the more promising classes of composites touted for high temperature applications, and certainly the most available, is that of relatively brittle matrices, either ceramic or intermetallic, reinforced by strong, aligned, continuous fibers. Under cyclic loading in the fiber direction, these materials develop matrix cracks that often run perpendicular to the fibers, while the fibers remain intact in the crack wake, supplying bridging tractions across the fracture surfaces. The bridging tractions shield the crack tip from the applied load, dramatically reducing the crack velocity from that expected in an unreinforced material subjected to the same value, {Delta}K{sub a}, of the cyclic applied stress intensity factor. An important issue in reliability is the prediction of the growth rates of the bridged cracks. The growth rates of matrix fatigue cracks bridged by sliding fibers are now commonly predicted by models based on the micromechanics of frictional interfaces. However, there exist many reasons, both theoretical and experimental, for suspecting that the most popular micromechanical models are probably wrong in detail in the context of fatigue cracks. Furthermore, a review of crack growth data reveals that the validity of the micromechanics-based predictive model has never been tested and may never be tested. In this paper, two alternative approaches are suggested to the engineering problem of predicting the growth rates of bridged cracks without explicit recourse to micromechanics. Instead, it is shown that the material properties required to analyze bridging effects can be deduced directly from crack growth data. Some experiments are proposed to test the validity of the proposals.

  9. School Reform for Students of Color and English Learners: Leaving Pedagogy Behind

    E-Print Network [OSTI]

    Trujillo, Tina

    2011-01-01T23:59:59.000Z

    education. Public school reformers have responded to theseto study how California’s reformers can influence not justhow influence California’s reformers can influen ce not just

  10. Recipe for Reform: The Food Economy Movement in Britain During the First World War

    E-Print Network [OSTI]

    Buckley, Michael Dennis

    2009-01-01T23:59:59.000Z

    series. However, one food reformer had not plagiarized fromBefore the war, food reformers addressed endemic hungerback on the prewar reformers' program of "food economy."

  11. Liquid fuel reformer development: Autothermal reforming of Diesel fuel

    SciTech Connect (OSTI)

    Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

    2000-07-24T23:59:59.000Z

    Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

  12. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, R.E.

    1988-03-08T23:59:59.000Z

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream 1 and spent fuel stream 2. Spent fuel stream 1 is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream 1 and exhaust stream 2, and exhaust stream 1 is vented. Exhaust stream 2 is mixed with spent fuel stream 2 to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells. 1 fig.

  13. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, Ralph E. (Finleyville, PA)

    1988-01-01T23:59:59.000Z

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  14. Early stages in the development of stress corrosion cracks

    SciTech Connect (OSTI)

    Jones, R.H.; Simonen, E.P.

    1993-12-01T23:59:59.000Z

    Processes in growth of short cracks and stage I of long stress corrosion cracks were identified and evaluated. There is evidence that electrochemical effects can cause short stress corrosion cracks to grow at rates faster or slower than long cracks. Short cracks can grow at faster rates than long cracks for a salt film dissolution growth mechanism or from reduced oxygen inhibition of hydrolytic acidification. An increasing crack growth rate with increasing crack length could result from a process of increasing crack tip concentration of a critical anion, such as Cl{sup {minus}}, with increasing crack length in a system where the crack velocity is dependent on the Cl{sup {minus}} or some other anion concentration. An increasing potential drop between crack tip and mouth would result in an increased anion concentration at the crack tip and hence an increasing crack velocity. Stage I behavior of long cracks is another early development stage in the life of a stress corrosion crack which is poorly understood. This stage can be described by da/dt = AK{sup m} where da/dt is crack velocity, A is a constant, K is stress intensity and m ranges from 2 to 24 for a variety of materials and environments. Only the salt film dissolution model was found to quantitatively describe this stage; however, the model was only tested on one material and its general applicability is unknown.

  15. Perspective: The road to reform

    SciTech Connect (OSTI)

    Howe, J.B. (J. Makowski Associates Inc., Boston, MA (United States))

    1994-04-01T23:59:59.000Z

    The rapid transformation underway in the utility industry provides ample evidence that the reality of the Energy Policy Act of 1992 is sinking in. This law reflected Congress's conclusion that competition in wholesale power generation-at the plant busbar-is a demonstrable reality. It expressed the vision of a fully competitive wholesale generation market, with suppliers linked to markets through a grid that would provide service on a nondiscriminatory basis. But will consumers reap the full benefits of effective competition at the wholesale generation level Or will more disorderly forms of competition emerge, reflecting a hybrid of deregulation and old-fashioned monopoly tactics Along the latter course we run the risk of cost shifts among customer classes, customer defections, diminished utility cooperation, and higher overall costs to society. In short, the vision of a competitive market in wholesale generation will not come about without thoughtful efforts at defining the relevant market, as well as careful attention to the management of a difficult transition away from outmodes mindsets and regulatory models. As a national trade association representing independent power producers (IPPs) and suppliers of goods and services to the competitive wholesale electric generation industry, the Electric Generation Association (EGA) believes that constructive dialogue will yield the best approach to managing this difficult process of transition. In that spirit, the EGA Emerging Operational Issues Committee recently released a while paper, [open quotes]Electrifying Change: Strategies for Structural Reform in the Electric Industry,[close quotes] which forms the basis for this article.

  16. Studies on fruit cracking of tomatoes

    E-Print Network [OSTI]

    Cotner, Sam Don

    1966-01-01T23:59:59.000Z

    calcium , 33 Means for naturally occurring cracks as influenced by foliar calcium applications 33 Analysis of variance for tomato fruit cracking as influended by foliar applications of CaC12 36 LIST QF TABLES CONTINUED 17. Analysis of variance...on of the cell contents oi' tomato fruits late in the season have been reported (10). Whatley (37) states that there is a 20 percent increase in osmot1c pressure from mature green to the red ripe stags. Radial cracking may be due to an increase...

  17. Effects of Ruminally Degradable Nitrogen in Diets Containing Wet Distiller’s Grains with Solubles and Steam-flaked Corn on Feedlot Cattle Performance and Carcass Characteristics

    E-Print Network [OSTI]

    Ponce, Christian

    2010-10-12T23:59:59.000Z

    plants, certain deviations of methods due to technologies employed at specific plants might explain some of the variation in nutritive value of the co-products. Holt and Pritchard (2004) determined nutrient variations of wet distiller?s grains... disappearance was 3.9%/h, and 47% of the CP present was ruminal escape protein. Crude protein values of up to 37.6% have been determined on samples collected directly from 4 plants (Holt and Pritchard, 2004). One nutritional limitation of WDGS...

  18. Hydrogen generation utilizing integrated CO2 removal with steam reforming

    DOE Patents [OSTI]

    Duraiswamy, Kandaswamy; Chellappa, Anand S

    2013-07-23T23:59:59.000Z

    A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

  19. Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation · The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator (C1) and a main column (C21 and C22) N-7465 Trondheim, Norway Abstract This work shows the unexpected result that over-fractionating one

  20. Study of the Distillability of Werner States Using Entanglement Witnesses and Robust Semidefinite Programs

    E-Print Network [OSTI]

    Reinaldo O. Vianna; Andrew C. Doherty

    2006-08-11T23:59:59.000Z

    We use Robust Semidefinite Programs and Entanglement Witnesses to study the distillability of Werner states. We perform exact numerical calculations which show 2-undistillability in a region of the state space which was previously conjectured to be undistillable. We also introduce bases which yield interesting expressions for the {\\em distillability witnesses} and for a tensor product of Werner states with arbitrary number of copies.

  1. Use of Short-cut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Use of Short-cut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns Ivar J: Petlyuk distillation column, dividing wall column, optimizing control, minimum energy 1. INTRODUCTION- ments for the level of automatic control and to the design of number of stages in each column section. 2

  2. Use of Shortcut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Use of Short­cut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns Ivar J: Petlyuk distillation column, dividing wall column, optimizing control, minimum energy 1. INTRODUCTION­ ments for the level of automatic control and to the design of number of stages in each column section. 2

  3. CRACK SPACING IN STRAINED FILMS B.B. Guzina1

    E-Print Network [OSTI]

    Guzina, Bojan

    , similar transverse cracking patterns are a feature of asphalt concrete pavements systems in cold climates

  4. Quantum distillation: Dynamical generation of low-entropy states of strongly correlated fermions in an optical lattice

    E-Print Network [OSTI]

    Tennessee, University of

    Quantum distillation: Dynamical generation of low-entropy states of strongly correlated fermions of double occupancies. We promote the notion of quantum distillation: during the expansion and in the case

  5. Coding the cracks | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . October 3, 2014 Printer-friendly version Researchers use Mira to study stress-corrosion cracking in silicates Encased in the rocks that comprise much of Earth's crust and...

  6. Catalytic cracking of residual petroleum fractions

    SciTech Connect (OSTI)

    Moore, H.F.; Mayo, S.L.; Goolsby, T.L. (Research and Development Dept., Ashland Petroleum Co., Ashland, KY (US))

    1991-01-01T23:59:59.000Z

    This paper reports on Arabian Light crude oil vacuum bottoms fractionated into five high-boiling fractions by wiped film evaporation, and the fractions subjected to catalytic cracking in a fixed-fluidized bed using a commercial equilibrium cracking catalyst. Density, aromaticity, and heteroatom content generally increased with boiling point, as did metals content except for vanadium and iron which demonstrated possible bimodal distributions. The cracking response of these fractions showed increasing yields of dry gas and coke, with decreasing gasoline yields, as a function of increasing apparent boiling point as would normally be expected. Surprisingly, however, local maxima were observed for wet gas yield and total conversion, with local minima for cycle oil and slurry yields, in the region of the 1200-1263{degrees}F (650-680{degrees}C) middle fraction. All fractions showed significant response to cracking, with coke yields generally being the only negative factor observed.

  7. Cracking in reinforced concrete bent caps 

    E-Print Network [OSTI]

    Young, Bradley S.

    2000-01-01T23:59:59.000Z

    by studying the relationship between stresses in the longitudinal tension reinforcement, reinforcement detailing, shear resistance, and cracking of the bent cap during service loading through to failure. As a part of this investigation, sixteen full...

  8. Low Cost Autothermal Diesel Reforming Catalyst Development

    SciTech Connect (OSTI)

    Shihadeh, J.; Liu, D.

    2004-01-01T23:59:59.000Z

    Catalytic autothermal reforming (ATR) represents an important step of converting fossil fuel to hydrogen rich reformate for use in solid oxide fuel cell (SOFC) stacks. The state-of-the-art reforming catalyst, at present, is a Rh based material which is effective but costly. The objective of our current research is to reduce the catalyst cost by finding an efficient ATR catalyst containing no rhodium. A group of perovskite based catalysts have been synthesized and evaluated under the reforming condition of a diesel surrogate fuel. Hydrogen yield, reforming efficiency, and conversion selectivity to carbon oxides of the catalyst ATR reaction are calculated and compared with the benchmark Rh based material. Several catalyst synthesis improvements were carried out including: 1) selectively doping metals on the A-site and B-site of the perovskite structure, 2) changing the support from perovskite to alumina, 3) altering the method of metal addition, and 4) using transition metals instead of noble metals. It was found that the catalytic activity changed little with modification of the A-site metal, while it displayed considerable dependence on the B-site metal. Perovskite supports performed much better than alumina based supports.

  9. Low capital implementation of distributed distillation in ethylene recovery

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31T23:59:59.000Z

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  10. Comparison of advanced distillation control methods. Third annual report

    SciTech Connect (OSTI)

    Riggs, J.B.

    1997-07-01T23:59:59.000Z

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls, feedforward from a feed composition analyzer, and decouplers. Auto Tune Variation (ATV) identification with on-line detuning for setpoint changes was used for tuning the diagonal proportional integral (PI) composition controls. In addition, robustness tests were conducted by inducting reboiler duty upsets. For single composition control, the (L, V) configuration was found to be best. For dual composition control, the optimum configuration changes from one column to another. Moreover, the use of analysis tools, such as RGA, appears to be of little value in identifying the optimum configuration for dual composition control. Using feedforward from a feed composition analyzer and using decouplers are shown to offer significant advantages for certain specific cases.

  11. Effects of system densities on distillation column performance

    SciTech Connect (OSTI)

    Fasesan, S.O.; Sanni, S.A.; Taiwo, E.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria). Dept. of Chemical Engineering

    1998-06-01T23:59:59.000Z

    Distillation experiments were carried out on three binary systems (ethanol-butanol, ethanol-propan-2-ol, and propan-2-ol-butanol) in a 0.1-m internal diameter glass column packed with 8 mm diameter Raschig rings. The experiments were performed under total reflux conditions and at atmospheric pressure. The data collected on column performance showed that performance declined with increasing average bulk liquid density. The results also lend credence to earlier reports on the behavior of column performance with respect to component concentration in the feed mixtures. The system densities of the three binary systems were measured at four different temperatures, 30, 40, 50, and 60 C. The data were compared with the predicted data of Yen-Woods and Multifluid models. The accuracy of the predictions of the Yen-Woods model was rather poor while that of the Multifluid model was very encouraging.

  12. Shrinkage - cracking characteristics of structural lightweight concrete

    E-Print Network [OSTI]

    McKeen, Robert Gordon

    1969-01-01T23:59:59.000Z

    1969 ABSTRACT Shrinkage-Cracking Characteristics of Structural Lightweight Concrete (August 1969) B. S. C. E. , Texas AERY University Directed by: if. B. Ledbetter Tests were conducted to det. trains the effect of coarse. s -gre- gate type...'csults indicated that both unrestrained shrinkage and concret. c water loss relate to restrained shrinkage stress. Unrestrained shrinks e did not indicate. cracking ter. dency while we+ er loss provided an indi cati on of cr cking tendency. ACRRO!Jr. ROOD. i...

  13. INDIVIDUAL REFORM ELEMENTS .63Average course exam score

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    INDIVIDUAL REFORM ELEMENTS .63Average course exam score .11In class clicker score .02Lecture: · Correlations with effort/curricular elements are positive but not high, indicating no individual course reform

  14. Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells Presented at the DOE-DOD Shipboard APU Workshop on...

  15. Electricity reform in Chile : lessons for developing countries

    E-Print Network [OSTI]

    Pollitt, Michael G.

    2004-01-01T23:59:59.000Z

    Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. ...

  16. MORE HEALTH CARE REFORM By Victor R. Fuchs

    E-Print Network [OSTI]

    Zalta, Edward N.

    MORE HEALTH CARE REFORM By Victor R. Fuchs #12;2 | MORE HEALTH CARE REFORM The Robert Wood Johnson?................................................................................... 8 Government Payment for Health Care -- Causes and Consequences....................................................................................................................................................................................... 16 Health Care Is Different -- That's Why Expenditures Matter

  17. How Did Health Care Reform in Massachusetts Impact Insurance Premiums?

    E-Print Network [OSTI]

    Graves, John A.

    It is widely recognized that the 2006 Massachusetts health reforms served as a blueprint for national reform under the 2010 Affordable Care Act (ACA). As such, there is interest in using the Massachusetts experience to ...

  18. adiabatic reformer processes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CELL of consequences, the most important of which are the possibility to partially reform the raw fuel in the fuel cell and energy balance, different types of fuel reforming...

  19. Thermally integrated staged methanol reformer and method

    DOE Patents [OSTI]

    Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

    2001-01-01T23:59:59.000Z

    A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

  20. Pyrochlore catalysts for hydrocarbon fuel reforming

    DOE Patents [OSTI]

    Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

    2012-08-14T23:59:59.000Z

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

  1. Auxiliary reactor for a hydrocarbon reforming system

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Bentley, Jeffrey M.; Davis, Robert; Rumsey, Jennifer W.

    2006-01-17T23:59:59.000Z

    An auxiliary reactor for use with a reformer reactor having at least one reaction zone, and including a burner for burning fuel and creating a heated auxiliary reactor gas stream, and heat exchanger for transferring heat from auxiliary reactor gas stream and heat transfer medium, preferably two-phase water, to reformer reaction zone. Auxiliary reactor may include first cylindrical wall defining a chamber for burning fuel and creating a heated auxiliary reactor gas stream, the chamber having an inlet end, an outlet end, a second cylindrical wall surrounding first wall and a second annular chamber there between. The reactor being configured so heated auxiliary reactor gas flows out the outlet end and into and through second annular chamber and conduit which is disposed in second annular chamber, the conduit adapted to carry heat transfer medium and being connectable to reformer reaction zone for additional heat exchange.

  2. Ind. Eng. Chem. Res. 1996,34, 4395-4405 4396 Multiple Steady States and Instability in Distillation. Implications

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Ind. Eng. Chem. Res. 1996,34, 4395-4405 4396 Multiple Steady States and Instability in Distillation-7034 Trondheim, Norway The fact that distillation columns, even in the ideal binary case, may display addresses some implications of these phenomena for the operation and control of distillation columns. Under

  3. Design of Hybrid Distillation-Vapor Membrane Separation Systems. Jose A. Caballero*; Ignacio E. Grossmann **; Majid Keyvani+

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Design of Hybrid Distillation-Vapor Membrane Separation Systems. Jose A. Caballero*; Ignacio E (ethane, propane) on a commercial scale is performed almost exclusively by cryogenic distillation to optimize and retrofit a hybrid separation system consisting of a distillation column and a parallel

  4. LA DISTILLATION a t introduite en Occident avec l'alchimie au cours du XIIe sicle. Par convention, on

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    LA DISTILLATION a été introduite en Occident avec l'alchimie au cours du XIIe siècle. Par Pseudo-Geber, distingue plusieurs façons de distiller et propose même une classi- fication de ces distillat (per descensum). La distillation par élévation des vapeurs, ou per ascensum, nécessite l

  5. MODELING, IDENTIFICATION AND CONTROL, 2000, VOL. 21, NO. 2, 83103 Evaluation of Dynamic Models of Distillation Columns with Emphasis

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of Distillation Columns with Emphasis on the Initial Response BERND WITTGENS and SIGURD SKOGESTAD* Keywords: Distillation dynamics, tray hydraulics, experimental response The flow dynamics (tray hydraulics) are of key importance for the initial dynamic response of distillation columns. The most important parameters

  6. JMLR: Workshop and Conference Proceedings 29:116, 2014 ACML 2014 Sample Distillation for Object Detection and Image

    E-Print Network [OSTI]

    Fleuret, François

    JMLR: Workshop and Conference Proceedings 29:1­16, 2014 ACML 2014 Sample Distillation for Object different computer vision problems. First, we show that distillation can be used to improve the traditional bootstrap- ping approach to object detection. Second, we apply distillation to a classification problem

  7. Can the Operating Leaves of a Distillation Column Really Be Tshepo S. Modise, Michaela Tapp, Diane Hildebrandt,* and David Glasser

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Can the Operating Leaves of a Distillation Column Really Be Expanded? Tshepo S. Modise, Michaela to determine the operation leaves and hence the feasible region for distillation columns operating at a specific distillate and bottoms composition for all possible constant reflux and reboil ratios

  8. Measurement Reconciliation and Interpretation in Packed Distillation Column Operation Teck C. Lee and Colin S. Howat, Ph.D.

    E-Print Network [OSTI]

    Howat, Colin S. "Chip"

    . To overcome this limitation, a pilot plant scale, packed distillation column was designed, built, and tested plant scale, packed distillation column was designed, built, and tested. This column can be operatedMeasurement Reconciliation and Interpretation in Packed Distillation Column Operation Teck C. Lee

  9. Cost Analysis of Bio-Derived Liquids Reforming

    E-Print Network [OSTI]

    Ethanol Reforming Options Gas Phase Liquid Phase Virent Steam Partial Oxidation Reforming GE (SCPO) decomposition C2H5OH Æ CH4 + CO + H2 steam reforming CH4 + 2H2O Æ 4H2 + CO2 3) C2H5OH dehydrogenation to acetaldehyde (C2H4O) dehydrogenation C2H5OH Æ C2H4O + H2 decarbonylation C2H4O Æ CH4 + CO steam reforming CH4

  10. Diesel reforming for SOFC auxiliary power units

    SciTech Connect (OSTI)

    Borup, R. L. (Rodney L.); Parkinson, W. J. (William Jerry),; Inbody, M. A. (Michael A.); Tafoya, J. I. (Jose I.); Guidry, D. R. (Dennis Ray)

    2004-01-01T23:59:59.000Z

    The use of a solid-oxide fuel cell (SOFC) to provide auxiliary power for heavy duty trucks can increase fuel efficiency and reduce emissions by reducing engine idling time. The logical fuel of choice for a truck SOFC APU is diesel fuel, as diesel is the fuel of choice for these vehicles. SOFC's that directly oxidize hydrocarbon fuels have lower power densities than do SOFC's that operate from hydrocarbon reformate, and since the SOFC is a costly component, maximizing the fuel cell power density provides benefits in reducing the overall APU system cost. Thus current SOFC APU systems require the reformation of higher hydrocarbons for the most efficient and cost effect fuel cell system. The objective of this research is to develop the technology to enable diesel reforming for SOFC truck APU applications. Diesel fuel can be reformed into a H{sub 2} and CO-rich fuel feed stream for a SOFC by autothermal reforming (ATR), a combination of catalytic partial oxidation (CPOx), and steam reforming (SR). The typical autothermal reformer is an adiabatic, heterogeneous catalytic reactor and the challenges in its design, operation and durability on diesel fuel are manifold. These challenges begin with the vaporization and mixing of diesel fuel with air and steam where fuel pyrolysis can occur and improper mixing leads to hot and cold spots, which contribute to carbon formation and incomplete fuel conversion. The exotherm of the partial oxidation reaction can generate temperatures in excess of 800 C, a temperature at which catalysts rapidly sinter, thus reducing their lifetime. The temperature rise can be reduced by the steam reforming endotherm, but this requires the addition of water along with proper design to balance the kinetic rates. Carbon formation during operation and startup can lead to catalyst deactivation and fouling of downstream components, thus reducing durability of the fuel processor. Water addition helps to reduce carbon formation, but a key issue is the source of the water onboard a vehicle. Additionally, changes in diesel fuel composition, such as seasonal changes affect the reactor operation and design considerations. Our research addresses these issues through an experimental and modeling examination of the fundamentals of these processes.

  11. APPROACHING THE LIMIT: EARLY NATIONAL LESSONS FROM WELFARE REFORM

    E-Print Network [OSTI]

    Shyy, Wei

    APPROACHING THE LIMIT: EARLY NATIONAL LESSONS FROM WELFARE REFORM Sheldon Danziger University of Welfare Reform. Kalamazoo, MI: Upjohn Institute for Employment Research, 2001. Sheldon Danziger is Henry J, and Bruce Weber, helpful comments on a previous draft. #12;2 Welfare reform has been one of the most

  12. REFORM OF EUROPEAN MERGER POLICY Bruce R Lyons

    E-Print Network [OSTI]

    Feigon, Brooke

    REFORM OF EUROPEAN MERGER POLICY by Bruce R Lyons CCR Working Paper CCR 03-5 Abstract This article highlights the main drivers for merger policy reform in the EU, including the consequences of the recent appeal court reverses. It discusses some of the substantive and procedural issues that the reform package

  13. DFMA Cost Estimates of Fuel-Cell/Reformer Systems

    E-Print Network [OSTI]

    Page 1 DFMA Cost Estimates of Fuel-Cell/Reformer Systems at Low/Medium/High Production Rates Brian estimates of complete fuel cell- reformer systems at low/medium/high manufacturing rates to assess of Boothroyd Dewhurst Inc. #12;Page 4 Scope of Project Reformer System Fuel Cell System Fuel Storage What

  14. Tax Reform in the 21st Alan J. Auerbach*

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    Tax Reform in the 21st Century Alan J. Auerbach* University of California, Berkeley, and NBER May 6 for a conference, "Is it Time for Fundamental Tax Reform?" held at the James A. Baker III Institute at Rice a major reform to make its tax system simpler, fairer and more efficient? In addressing this question, I

  15. The Future of Democracy in Europe Trends, Analyses and Reforms

    E-Print Network [OSTI]

    Franz, Sven Oliver

    1 The Future of Democracy in Europe Trends, Analyses and Reforms A Green Paper for the Council-level accountability Mechanisms for direct citizen consultation Part III. Recommendations for reform Introduction Guidelines Our "wish list" of recommended reforms 1. Universal citizenship 2. Discretionary voting 3

  16. SANITARY REFORM The Montreal Witness, April 27, 1859

    E-Print Network [OSTI]

    Genest, Christian

    SANITARY REFORM The Montreal Witness, April 27, 1859 A lecture was delivered on this singularly was thoroughly acquainted with his sub- ject, having been for a number of years actively engaged in this reform in England, part of the time as Secretary of an eminent sanitary reformer, and his facts and figures were

  17. ISSN 1745-9648 The Impact of Electricity Market Reform

    E-Print Network [OSTI]

    Feigon, Brooke

    ISSN 1745-9648 The Impact of Electricity Market Reform on Consumers by Catherine Waddams Price ESRC market reform on residential consumers, using a sequence of hypothetical scenarios which are likely to be prompted by reform. These include raising tariffs to cost-reflective levels and introducing a standing

  18. Data reconciliation and optimal operation of a catalytic naphtha reformer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Data reconciliation and optimal operation of a catalytic naphtha reformer Tore Lid Statoil Mongstad-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

  19. AAPT Philadelphia 1/02 Gender, Educational Reform,

    E-Print Network [OSTI]

    Wu, Mingshen

    AAPT Philadelphia 1/02 Gender, Educational Reform, and Instructional Assessment: Part I Laura Mc/02 Why study this issue? One goal of PER is to improve physics education for all Current reform effort is strong; reforms serving subpopulations? Is this gender gap showing at the college level in physics? #12

  20. A Reformed Mathematics Education at Chalmers Stig Larsson

    E-Print Network [OSTI]

    Larsson, Stig

    A Reformed Mathematics Education at Chalmers Stig Larsson Department of Mathematics Chalmers@math.chalmers.se Kvalitetskonferensen, Norrk¨oping, September 25­27, 2001 Abstract Engineering education faces the challenge to reform to effectively use the new tools offered by computers. We present a program for a reformed engineering

  1. Data reconciliation and optimal operation of a catalytic naphtha reformer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Data reconciliation and optimal operation of a catalytic naphtha reformer Tore Lid Statoil Mongstad-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high-octane components for use in high-performance gasoline fuels. The reformer also has an important function

  2. Land Reform and Exclusion of Poor Jagat Basnet

    E-Print Network [OSTI]

    Richner, Heinz

    141 CHAPTER 6 Land Reform and Exclusion of Poor People Jagat Basnet 6.1 Land Questions Firstly, by land reform, it is widely understood to be a process of confiscating someone's land and award Planning Commission (NPC). Land reform is an important factor for improving the economic status

  3. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21T23:59:59.000Z

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  4. health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com

    E-Print Network [OSTI]

    Chapman, Michael S.

    health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com On March 23, President Obama signed is tracking the myriad other developments of the new health reform law. You can find a wide range of related material, including enacting language, implementing documents, and analysis through the Health Reform

  5. Preliminary and incomplete A Modest Proposal for International Monetary Reform

    E-Print Network [OSTI]

    Grishok, Alla

    Preliminary and incomplete A Modest Proposal for International Monetary Reform International Columbia University #12;- 1 - - 1 - #12;- 2 - A Modest Proposal for International Monetary Reform Bruce are fundamental aspects of the present system and that, without reform, they will continue to plague the global

  6. SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY

    E-Print Network [OSTI]

    Boyer, Edmond

    SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY Olivier CARDI Romain RESTOUT December, 2010 REFORMS IN AN OPEN ECONOMY Olivier CARDI Universit´e Panth´eon-Assas ERMES Ecole Polytechnique Romain with traded and non traded goods to in- vestigate the sectoral effects of three tax reforms: i) two revenue

  7. WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS?

    E-Print Network [OSTI]

    Boyer, Edmond

    WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS? Susie LEE Ingmar SCHUMACHER (in)stability induce financial reforms? Susie Lee1 Ingmar Schumacher2 October 26, 2011 Abstract The article studies whether financial sector (in)stability had an effect on reforms in the fi- nancial sector

  8. the triple aim MEETING THE GOAL OF HEALTH REFORM

    E-Print Network [OSTI]

    Chapman, Michael S.

    the triple aim MEETING THE GOAL OF HEALTH REFORM Produced by OHSU Strategic Communications -- emphasizing shared decision-making and coordination between providers -- could influence reform in a big way care. health reform is about getting better health outcomes for our communities, improving access

  9. Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation

    E-Print Network [OSTI]

    Rambaut, Andrew

    Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation September 2012 1 Ofqual: A Level Reform Consultation Response by the Wellcome Trust September 2012 Key Points National Subject to university. We are therefore pleased to respond to this consultation on reforming A levels. Our comments

  10. Topology of desiccation crack patterns in clay and invariance of crack interface area with thickness

    E-Print Network [OSTI]

    Tajkera Khatun; Tapati Dutta; Sujata Tarafdar

    2014-12-09T23:59:59.000Z

    We study the crack patterns developed on desiccating films of an aqueous colloidal suspension of bentonite on a glass substrate. Varying the thickness of the layer $h$ gives the following new and interesting results: (i)We identify a critical thickness $h_{c}$, above which isolated cracks join each other to form a fully connected network. A topological analysis of the crack network shows that the Euler number falls to a minimum at $h_{c}$. (ii) We find further, that the total vertical surface area of the clay $A_v$, which has opened up due to cracking, is a constant independent of the layer thickness for $h \\geq h_c$. (iii) The total area of the glass substrate $A_s$, exposed by the hierarchical sequence of cracks is also a constant for $h \\geq h_c$. These results are shown to be consistent with a simple energy conservation argument, neglecting dissipative losses. (iv) Finally we show that if the crack pattern is viewed at successively finer resolution, the total cumulative area of cracks visible at a certain resolution, scales with the layer thickness. A suspension of Laponite in methanol is found to exhibit similar salient features (i)-(iv), though in this case the crack initiation process for very thin layers is quite different.

  11. Contstraint effects of shallow cracks in structures containing fillet weld toe cracks

    E-Print Network [OSTI]

    Neligon, Melinda T

    1995-01-01T23:59:59.000Z

    for structures containing a/W--O.l and a/W--O.5 fillet weld toe cracks. The Anderson-Dodds scaling model is applied to quantify the effects of finite size on J contour integral values for structures containing a/W=O.l and a/W=0.5 fillet weld toe cracks loaded...

  12. Contstraint effects of shallow cracks in structures containing fillet weld toe cracks 

    E-Print Network [OSTI]

    Neligon, Melinda T

    1995-01-01T23:59:59.000Z

    for structures containing a/W--O.l and a/W--O.5 fillet weld toe cracks. The Anderson-Dodds scaling model is applied to quantify the effects of finite size on J contour integral values for structures containing a/W=O.l and a/W=0.5 fillet weld toe cracks loaded...

  13. Recent evaluations of crack-opening-area in circumferentially cracked pipes

    SciTech Connect (OSTI)

    Rahman, S.; Brust, F.; Ghadiali, N.; Wilkowski, G.; Miura, N.

    1997-04-01T23:59:59.000Z

    Leak-before-break (LBB) analyses for circumferentially cracked pipes are currently being conducted in the nuclear industry to justify elimination of pipe whip restraints and jet shields which are present because of the expected dynamic effects from pipe rupture. The application of the LBB methodology frequently requires calculation of leak rates. The leak rates depend on the crack-opening area of the through-wall crack in the pipe. In addition to LBB analyses which assume a hypothetical flaw size, there is also interest in the integrity of actual leaking cracks corresponding to current leakage detection requirements in NRC Regulatory Guide 1.45, or for assessing temporary repair of Class 2 and 3 pipes that have leaks as are being evaluated in ASME Section XI. The objectives of this study were to review, evaluate, and refine current predictive models for performing crack-opening-area analyses of circumferentially cracked pipes. The results from twenty-five full-scale pipe fracture experiments, conducted in the Degraded Piping Program, the International Piping Integrity Research Group Program, and the Short Cracks in Piping and Piping Welds Program, were used to verify the analytical models. Standard statistical analyses were performed to assess used to verify the analytical models. Standard statistical analyses were performed to assess quantitatively the accuracy of the predictive models. The evaluation also involved finite element analyses for determining the crack-opening profile often needed to perform leak-rate calculations.

  14. TRANSPORT THROUGH CRACKED CONCRETE: LITERATURE REVIEW

    SciTech Connect (OSTI)

    Langton, C.

    2012-05-11T23:59:59.000Z

    Concrete containment structures and cement-based fills and waste forms are used at the Savannah River Site to enhance the performance of shallow land disposal systems designed for containment of low-level radioactive waste. Understanding and measuring transport through cracked concrete is important for describing the initial condition of radioactive waste containment structures at the Savannah River Site (SRS) and for predicting performance of these structures over time. This report transmits the results of a literature review on transport through cracked concrete which was performed by Professor Jason Weiss, Purdue University per SRR0000678 (RFP-RQ00001029-WY). This review complements the NRC-sponsored literature review and assessment of factors relevant to performance of grouted systems for radioactive waste disposal. This review was performed by The Center for Nuclear Waste Regulatory Analyses, San Antonio, TX, and The University of Aberdeen, Aberdeen Scotland and was focused on tank closure. The objective of the literature review on transport through cracked concrete was to identify information in the open literature which can be applied to SRS transport models for cementitious containment structures, fills, and waste forms. In addition, the literature review was intended to: (1) Provide a framework for describing and classifying cracks in containment structures and cementitious materials used in radioactive waste disposal, (2) Document the state of knowledge and research related to transport through cracks in concrete for various exposure conditions, (3) Provide information or methodology for answering several specific questions related to cracking and transport in concrete, and (4) Provide information that can be used to design experiments on transport through cracked samples and actual structures.

  15. An Adaptive Entanglement Distillation Scheme Using Quantum Low Density Parity Check Codes

    E-Print Network [OSTI]

    K. H. Ho; H. F. Chau

    2008-07-14T23:59:59.000Z

    Quantum low density parity check (QLDPC) codes are useful primitives for quantum information processing because they can be encoded and decoded efficiently. Besides, the error correcting capability of a few QLDPC codes exceeds the quantum Gilbert-Varshamov bound. Here, we report a numerical performance analysis of an adaptive entanglement distillation scheme using QLDPC codes. In particular, we find that the expected yield of our adaptive distillation scheme to combat depolarization errors exceed that of Leung and Shor whenever the error probability is less than about 0.07 or greater than about 0.28. This finding illustrates the effectiveness of using QLDPC codes in entanglement distillation.

  16. Lower Bound of Concurrence and Distillation for Arbitrary Dimensional Bipartite Quantum States

    E-Print Network [OSTI]

    Zhao, Ming-Jing; Fei, Shao-Ming; Li-Jost, Xianqing; 10.1103/PhysRevA.84.062322

    2011-01-01T23:59:59.000Z

    We present a lower bound of concurrence for arbitrary dimensional bipartite quantum states. This lower bound may be used to improve all the known lower bounds of concurrence. Moreover, the lower bound gives rise to an operational sufficient criterion of distillability of quantum entanglement. The significance of our result is illustrated by quantitative evaluation of entanglement for entangled states that fail to be identified by the usual concurrence estimation method, and by showing the distillability of mixed states that can not be recognized by other distillability criteria.

  17. On the distillation and purification of phase-diffused squeezed states

    E-Print Network [OSTI]

    B. Hage; A. Franzen; J. DiGuglielmo; P. Marek; J. Fiurášek; R. Schnabel

    2007-07-17T23:59:59.000Z

    Recently it was discovered that non-Gaussian decoherence processes, such as phase-diffusion, can be counteracted by purification and distillation protocols that are solely built on Gaussian operations. Here, we make use of this experimentally highly accessible regime, and provide a detailed experimental and theoretical analysis of several strategies for purification/distillation protocols on phase-diffused squeezed states. Our results provide valuable information for the optimization of such protocols with respect to the choice of the trigger quadrature, the trigger threshold value and the probability of generating a distilled state.

  18. Lower Bound of Concurrence and Distillation for Arbitrary Dimensional Bipartite Quantum States

    E-Print Network [OSTI]

    Ming-Jing Zhao; Xue-Na Zhu; Shao-Ming Fei; Xianqing Li-Jost

    2011-12-23T23:59:59.000Z

    We present a lower bound of concurrence for arbitrary dimensional bipartite quantum states. This lower bound may be used to improve all the known lower bounds of concurrence. Moreover, the lower bound gives rise to an operational sufficient criterion of distillability of quantum entanglement. The significance of our result is illustrated by quantitative evaluation of entanglement for entangled states that fail to be identified by the usual concurrence estimation method, and by showing the distillability of mixed states that can not be recognized by other distillability criteria.

  19. Quantum repeaters and quantum key distribution: the impact of entanglement distillation on the secret key rate

    E-Print Network [OSTI]

    Sylvia Bratzik; Silvestre Abruzzo; Hermann Kampermann; Dagmar Bruß

    2013-03-14T23:59:59.000Z

    We investigate quantum repeaters in the context of quantum key distribution. We optimize the secret key rate per memory per second with respect to different distillation protocols and distillation strategies. For this purpose, we also derive an analytical expression for the average number of entangled pairs created by the quantum repeater, including classical communication times for entanglement swapping and entanglement distillation. We investigate the impact of this classical communication time on the secret key rate. We finally study the effect of the detector efficiency on the secret key rate.

  20. In Njeri Wamukonya, ed., Electricity Reform

    E-Print Network [OSTI]

    Delaware, University of

    electricity consumption in industrial countries has caused major air pollution problems. In fact, power plants maintain that governing the electricity industry according to market dynamics, rather than socioIn Njeri Wamukonya, ed., Electricity Reform: Social and Environmental Challenges Roskilde, Denmark

  1. Alternative technologies to steam-methane reforming

    SciTech Connect (OSTI)

    Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

    1995-11-01T23:59:59.000Z

    Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

  2. STRESS CORROSION CRACKING IN TEAR DROP SPECIMENS

    SciTech Connect (OSTI)

    Lam, P; Philip Zapp, P; Jonathan Duffey, J; Kerry Dunn, K

    2009-05-01T23:59:59.000Z

    Laboratory tests were conducted to investigate the stress corrosion cracking (SCC) of 304L stainless steel used to construct the containment vessels for the storage of plutonium-bearing materials. The tear drop corrosion specimens each with an autogenous weld in the center were placed in contact with moist plutonium oxide and chloride salt mixtures. Cracking was found in two of the specimens in the heat affected zone (HAZ) at the apex area. Finite element analysis was performed to simulate the specimen fabrication for determining the internal stress which caused SCC to occur. It was found that the tensile stress at the crack initiation site was about 30% lower than the highest stress which had been shifted to the shoulders of the specimen due to the specimen fabrication process. This finding appears to indicate that the SCC initiation took place in favor of the possibly weaker weld/base metal interface at a sufficiently high level of background stress. The base material, even subject to a higher tensile stress, was not cracked. The relieving of tensile stress due to SCC initiation and growth in the HAZ and the weld might have foreclosed the potential for cracking at the specimen shoulders where higher stress was found.

  3. Crack detection using pulsed eddy current stimulated thermography

    SciTech Connect (OSTI)

    Kostson, E.; Weekes, B.; Almond, D. P. [RCNDE, Department of Mechanical Engineering, University of Bath (United Kingdom); Wilson, J.; Tian, G. Y. [School of Electrical, Electronic and Computer Engineering, Newcastle University (United Kingdom)

    2011-06-23T23:59:59.000Z

    This contribution presents results from studies investigating factors that influence the detection of surface breaking cracks using pulsed eddy current thermography. The influences of the current strength and crack orientation in both ferromagnetic and non-ferromagnetic metals have been investigated. It has been found that crack detection is far more sensitive to crack orientation in non-ferromagnetic metals than in ferromagnetic metals. The effects of crack size on detectability are presented for a large number of steel, nickel alloy and titanium samples. Results of studies comparing crack images obtained prior and after coating a nickel alloy sample with a thermal barrier coating are presented.

  4. Hydrocarbon reforming catalyst material and configuration of the same

    DOE Patents [OSTI]

    Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

    1996-06-18T23:59:59.000Z

    A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

  5. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls. ATV identification with on-line detuning was used for tuning the diagonal PI composition controllers. Each configuration was evaluated with respect to steady-state RGA values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity), were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  6. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect (OSTI)

    Riggs, J.B.

    1996-11-01T23:59:59.000Z

    Detailed dynamic simulations of two industrial distillation columns (a propylene/propane splitter and a xylene/toluene column) have been used to study the issue of configuration selection for diagonal PI dual composition controls. Auto Tune Variation (ATV) identification with on-line detuning was used for tuning the diagonal proportional integral (PI) composition controls. Each configuration was evaluated with respect to steady-state relative gain array (RGA) values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity) were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  7. Environmentally assisted cracking of LWR materials.

    SciTech Connect (OSTI)

    Chopra, O. K.; Chung, H. M.; Kassner, T. F.; Park, J. H.; Shack, W. J.; Zhang, J.; Brust, F. W.; Dong, P.

    1997-12-05T23:59:59.000Z

    The effect of dissolved oxygen level on fatigue life of austenitic stainless steels is discussed and the results of a detailed study of the effect of the environment on the growth of cracks during fatigue initiation are presented. Initial test results are given for specimens irradiated in the Halden reactor. Impurities introduced by shielded metal arc welding that may affect susceptibility to stress corrosion cracking are described. Results of calculations of residual stresses in core shroud weldments are summarized. Crack growth rates of high-nickel alloys under cyclic loading with R ratios from 0.2-0.95 in water that contains a wide range of dissolved oxygen and hydrogen concentrations at 289 and 320 C are summarized.

  8. Crack detection using resonant ultrasound spectroscopy

    DOE Patents [OSTI]

    Migliori, Albert (Santa Fe, NM); Bell, Thomas M. (Santa Fe, NM); Rhodes, George W. (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    Method and apparatus are provided for detecting crack-like flaws in components. A plurality of exciting frequencies are generated and applied to a component in a dry condition to obtain a first ultrasonic spectrum of the component. The component is then wet with a selected liquid to penetrate any crack-like flaws in the component. The plurality of exciting frequencies are again applied to the component and a second ultrasonic spectrum of the component is obtained. The wet and dry ultrasonic spectra are then analyzed to determine the second harmonic components in each of the ultrasonic resonance spectra and the second harmonic components are compared to ascertain the presence of crack-like flaws in the component.

  9. Crack detection using resonant ultrasound spectroscopy

    DOE Patents [OSTI]

    Migliori, A.; Bell, T.M.; Rhodes, G.W.

    1994-10-04T23:59:59.000Z

    Method and apparatus are provided for detecting crack-like flaws in components. A plurality of exciting frequencies are generated and applied to a component in a dry condition to obtain a first ultrasonic spectrum of the component. The component is then wet with a selected liquid to penetrate any crack-like flaws in the component. The plurality of exciting frequencies are again applied to the component and a second ultrasonic spectrum of the component is obtained. The wet and dry ultrasonic spectra are then analyzed to determine the second harmonic components in each of the ultrasonic resonance spectra and the second harmonic components are compared to ascertain the presence of crack-like flaws in the component. 5 figs.

  10. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    Simulation study has shown oil production is accelerated when propane is used as an additive during steam injection. To better understand this phenomenon, distillation experiments were performed using San Ardo crude oil (12oAPI). For comparison...

  11. Water distillation using waste engine heat from an internal combustion engine

    E-Print Network [OSTI]

    Mears, Kevin S

    2006-01-01T23:59:59.000Z

    To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

  12. Multipartite continuous-variable entanglement distillation using local squeezing and only one photon-subtraction operation

    E-Print Network [OSTI]

    Song Yang; XuBo Zou; ShengLi Zhang; Bao-Sen Shi; Peter van Loock; GuangCan Guo

    2011-06-08T23:59:59.000Z

    In this paper, we study entanglement distillation of multipartite continuous-variable Gaussian entangled states. Following Opatrn\\'{y} \\emph{et al.}'s photon subtraction (PS) scheme, the probability of successful distillation decreases exponentially with the number of parties $N$. However, here, we shall propose an entanglement distillation scheme whose success probability scales as a constant with $N$. Our protocol employs several local squeezers, but it requires only a single PS operation. Using the logarithmic negativity as a measure of entanglement, we find that both the success probability and the distilled entanglement can be improved at the same time. Moreover, an $N$-mode transfer theorem (transferring states from phase space to Hilbert space) is presented.

  13. Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle

    E-Print Network [OSTI]

    Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle Ethanol, but sorghum grain is commonly either blended with corn before use or used as the sole grain for ethanol

  14. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  15. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  16. DYNAMIC MODELING AND CONTROL OF REACTIVE DISTILLATION FOR HYDROGENATION OF BENZENE 

    E-Print Network [OSTI]

    Aluko, Obanifemi

    2010-01-16T23:59:59.000Z

    This work presents a modeling and control study of a reactive distillation column used for hydrogenation of benzene. A steady state and a dynamic model have been developed to investigate control structures for the column. The most important aspects...

  17. Distillation: Energy Savings and Other Benefits From the Use of High Efficiency Packings

    E-Print Network [OSTI]

    Bravo, J. L.; Fair, J. R.; Humphrey, J. L.

    DISTILLATION: ENERGY SAVINGS AND OTHER BENEFITS. FROM THE USE OF HIGH-EFFICIENCY PACKINGS -. Jose L. Bravo, James R. Fair, and Jimmy L. Humpnrey The University of Texas at Austin Austin, Texas ABSTRACT A great deal of attention has been... focused lately on the use of high-efficiency packings for distillation applications. This paper discusses benefits that can be derived from the use of these devices. In parti~ular, the reduction in energy requirements for a given separation...

  18. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

  19. Utilization of Structured Packing for Energy Savings in Distillation and Absorption Columns

    E-Print Network [OSTI]

    Berven, O. J.; Howard, W. E.

    "UTILIZATION OF STRUCTURED PACKING FOR ENERGY SAVINGS IN DISTILLATION AND ABSORPTION COLUMNS" O. Jeffrey Berven and Wendell E. Howard Koch Engineering Company, Inc. Wi chita, Kansas As the need to reduce production costs causes... manufacturers to re-evaluate process ing schemes, hi gh efficiency structured packings are increasingly recognized as an effective alternative for reducing energy consumption in heat and mass transfer operations. In distillation, the high efficiency and low...

  20. The Scaleup of Structured Packing from Distillation Pilot Plant Testing to Commercial Application

    E-Print Network [OSTI]

    Berven, O. J.; Ulowetz, M. A.

    The Scaleup of Structured Packing From Distillation Pilot Plant Testing to Commercial Application O. Jeffrey'Berven and Michael A. Ulowetz Koch Engineering Company, Inc. Wichita, Kansas Structured packing is being utilized more and more... in the process industry for increased efficiency, greater capacity, and energy savings in distillation columns. Pilot plant testing of the actual chemical system using commercially available structured packing is invaluable, but years of experience in pilot...

  1. Fast electromigration crack in nanoscale aluminum film

    SciTech Connect (OSTI)

    Emelyanov, O. A., E-mail: oaemel2@gmail.com; Ivanov, I. O. [St. Petersburg State Polytechnical University, Saint-Petersburg (Russian Federation)

    2014-08-14T23:59:59.000Z

    The current-induced breakage of 20?nm thin aluminum layers deposited onto capacitor grade polypropylene (PP) films is experimentally studied. Biexponential current pulses of different amplitude (10–15?A) and duration (0.1–1??s) were applied to the samples. Breakage occurred after fast development of electromigrating ?200?nm-wide cracks with initial propagation velocity of ?1?m/s under a high current density of ?10{sup 12?}A/m{sup 2}. The cracks stopped when their lengths reached 250–450??m. This behavior is explained by the balance of electromigration and stress-induced atomic fluxes.

  2. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26T23:59:59.000Z

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  3. Crack closure effects on fatigue crack growth thresholds and remaining life in an HSLA steel

    SciTech Connect (OSTI)

    Todd, J.A.; Mostovoy, S. [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Mechanical, Materials and Aerospace Engineering; Chen, L. [Texas Instruments, Attleboro, MA (United States); Yankov, E.Y. [A. Finkl and Sons, Chicago, IL (United States)

    1997-02-01T23:59:59.000Z

    The effects of crack closure on the near-threshold corrosion fatigue crack growth behavior of Mil S-24645 HSLA steel and its weld metal have been investigated in air, ASTM seawater at the free corrosion potential, and ASTM seawater at {minus}0.8V and {minus}1.0V (SCE) using frequencies of 10, 2, and 0.2 Hz, and a stress ratio, R = 0.1. Remaining life, in the presence and absence of crack closure, has been estimated as a function of applied stress range for a structure containing a 3-mm-deep surface semi-elliptical flaw.

  4. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11T23:59:59.000Z

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  5. Reflective Cracking Study: HVS Test Section Forensic Investigation

    E-Print Network [OSTI]

    Jones, David; Steven, B.; Harvey, John T

    2008-01-01T23:59:59.000Z

    the asphalt concrete. Summary of Testing on the Underlyingtesting performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the forensic investigation of the HVS rutting and reflective cracking testing

  6. Characterization of Fatigue Cracking and Healing of Asphalt Mixtures

    E-Print Network [OSTI]

    Luo, Xue

    2012-07-16T23:59:59.000Z

    mixtures using an energy-based mechanistic approach. A controlled-strain repeated direct tension (RDT) test is selected to generate both fatigue cracking and permanent deformation in an asphalt mixture specimen. Fatigue cracking is separated from...

  7. Grain Boundary Structure Effects on Intergranular Stress Corrosion Cracking of

    E-Print Network [OSTI]

    Olson, Tamara

    Grain Boundary Structure Effects on Intergranular Stress Corrosion Cracking of Alloy X­750 Y. Pan B­of­freedom) and correlations with intergranular stress corrosion cracking observed in Alloy X­750. Orientation imaging

  8. A dynamical law for slow crack growth in polycarbonate films

    E-Print Network [OSTI]

    Cortet, Pierre-Philippe; Ciliberto, Sergio

    2007-01-01T23:59:59.000Z

    We study experimentally the slow growth of a single crack in polycarbonate films submitted to uniaxial and constant imposed stress. For this visco-plastic material, we uncover a dynamical law that describes the dependence of the instantaneous crack velocity with experimental parameters. The law involves a Dugdale-Barenblatt static description of crack tip plastic zones associated to an Eyring's law and an empirical dependence with the crack length that may come from a residual elastic field.

  9. Prediction of thermal crack spacing D.H. Timm a

    E-Print Network [OSTI]

    Guzina, Bojan

    understanding of thin film coatings but an understanding of how so-called thermal cracks, a feature of cold

  10. autogenous shrinkage cracking: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Restrained Shrinkage Cracking of Concrete Materials," 15th International Glass Fibre Reinforced Concrete Association Engineering Websites Summary: . The experiments...

  11. Straddler-based Gender Reform in Saudi Arabia: The Case of Jeddah Chamber of Commerce and Industry

    E-Print Network [OSTI]

    Hamilton, Katherine

    2010-01-01T23:59:59.000Z

    of pioneering feminist reformers in the country and theof the JCCI illustrates how reformers were able to utilize aconservatives and liberal reformers. These competing social

  12. From the Frontlines to the Bottom Line: Medical Marijuana, the War on Drugs, and the Drug Policy Reform Movement

    E-Print Network [OSTI]

    Heddleston, Thomas Reed

    2012-01-01T23:59:59.000Z

    how drug policy reformers used the ballot initiative processand future directions for reformers. Bock’s (2000) work isto analyze how drug policy reformers frame their actions and

  13. Comparison of Advanced Distillation Control Methods, Final Technical Report

    SciTech Connect (OSTI)

    Dr. James B. Riggs

    2000-11-30T23:59:59.000Z

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to evaluate configuration selections for single-ended and dual-composition control, as well as to compare conventional and advanced control approaches. In addition, a simulator of a main fractionator was used to compare the control performance of conventional and advanced control. For each case considered, the controllers were tuned by using setpoint changes and tested using feed composition upsets. Proportional Integral (PI) control performance was used to evaluate the configuration selection problem. For single ended control, the energy balance configuration was found to yield the best performance. For dual composition control, nine configurations were considered. It was determined that the use of dynamic simulations is required in order to identify the optimum configuration from among the nine possible choices. The optimum configurations were used to evaluate the relative control performance of conventional PI controllers, MPC (Model Predictive Control), PMBC (Process Model-Based Control), and ANN (Artificial Neural Networks) control. It was determined that MPC works best when one product is much more important than the other, while PI was superior when both products were equally important. PMBC and ANN were not found to offer significant advantages over PI and MPC. MPC was found to outperform conventional PI control for the main fractionator. MPC was applied to three industrial columns: one at Phillips Petroleum and two at Union Carbide. In each case, MPC was found to significantly outperform PI controls. The major advantage of the MPC controller is its ability to effectively handle a complex set of constraints and control objectives.

  14. CRACK STATISTIC OF CRYSTALLINE SILICON PHOTOVOLTAIC MODULES M. Kntges1

    E-Print Network [OSTI]

    the risk of cracks, as well as for statistical power loss assessment. Keywords: PV module, micro cracks separation, thus resulting in inactive cell parts. For this special case a clear assessment of the power loss this gap and provide a first statistic of cracks in PV modules for future power loss assessment

  15. RESEARCH Open Access Pavement crack characteristic detection based

    E-Print Network [OSTI]

    Joensuu, University of

    RESEARCH Open Access Pavement crack characteristic detection based on sparse representation Xiaoming Sun1 , Jianping Huang1 , Wanyu Liu1* and Mantao Xu2 Abstract Pavement crack detection plays an important role in pavement maintaining and management. The three- dimensional (3D) pavement crack detection

  16. Enhanced ultrasonic detection of fatigue cracks by laser-induced crack closure

    E-Print Network [OSTI]

    Nagy, Peter B.

    , corrosion, etc. . Sec- ond, it is important to distinguish small fatigue cracks as early as possible after threshold in aluminum, aluminum­ lithium, and titanium alloys.1 For example, extensive multiple-site fatigue

  17. Stress corrosion cracking and crack tip characterization of Alloy X-750 in light water reactor environments

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    2011-01-01T23:59:59.000Z

    Stress corrosion cracking (SCC) susceptibility of Inconel Alloy X-750 in the HTH condition has been evaluated in high purity water at 93 and 288°C under Boiling Water Reactor Normal Water Chemistry (NWC) and Hydrogen Water ...

  18. Stress Corrosion Cracking and Crack Tip Characterization of Alloy X-750 in Light Water Reactor Environments

    E-Print Network [OSTI]

    Gibbs, Jonathan Paul

    Stress corrosion cracking (SCC) susceptibility of Inconel Alloy X-750 in the HTH condition has been evaluated in high purity water at 93 and 288°C under Boiling Water Reactor Normal Water Chemistry (NWC) and Hydrogen Water ...

  19. The true toughness of human cortical bone measured with realistically short cracks

    E-Print Network [OSTI]

    Ritchie, Robert

    crack-resistance curves. We find that after only 500 µm of cracking, the driving force for crack. However, the toughness in the longitudinal orientation, where cracks tend to follow the cement lines mechanisms, which act primarily in the crack wake to `shield' the crack from the applied driving force

  20. Digital radiographic systems detect boiler tube cracks

    SciTech Connect (OSTI)

    Walker, S. [EPRI, Charlotte, NC (United States)

    2008-06-15T23:59:59.000Z

    Boiler water wall leaks have been a major cause of steam plant forced outages. But conventional nondestructive evaluation techniques have a poor track record of detecting corrosion fatigue cracking on the inside surface of the cold side of waterwall tubing. EPRI is performing field trials of a prototype direct-digital radiographic system that promises to be a game changer. 8 figs.

  1. Environmentally assisted cracking in light water reactors

    SciTech Connect (OSTI)

    Chopra, O.K.; Chung, H.M.; Gruber, E.E. [and others

    1996-07-01T23:59:59.000Z

    This report summarizes work performed by Argonne National Laboratory on fatigue and environmentally assisted cracking (EAC) in light water reactors (LWRs) from April 1995 to December 1995. Topics that have been investigated include fatigue of carbon and low-alloy steel used in reactor piping and pressure vessels, EAC of Alloy 600 and 690, and irradiation-assisted stress corrosion cracking (IASCC) of Type 304 SS. Fatigue tests were conducted on ferritic steels in water that contained various concentrations of dissolved oxygen (DO) to determine whether a slow strain rate applied during different portions of a tensile-loading cycle are equally effective in decreasing fatigue life. Crack-growth-rate tests were conducted on compact-tension specimens from several heats of Alloys 600 and 690 in simulated LWR environments. Effects of fluoride-ion contamination on susceptibility to intergranular cracking of high- and commercial- purity Type 304 SS specimens from control-tensile tests at 288 degrees Centigrade. Microchemical changes in the specimens were studied by Auger electron spectroscopy and scanning electron microscopy to determine whether trace impurity elements may contribute to IASCC of these materials.

  2. Autothermal reforming catalyst having perovskite structure

    DOE Patents [OSTI]

    Krumpel, Michael (Naperville, IL); Liu, Di-Jia (Naperville, IL)

    2009-03-24T23:59:59.000Z

    The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

  3. Catalytic autothermal reforming increases fuel cell flexibility

    SciTech Connect (OSTI)

    Flytzani-Stephanopoulos, M.; Voecks, G.E.

    1981-12-01T23:59:59.000Z

    To give a better understanding of autothermal reforming (ATR), a process which offers an advantageous alternative to steam reforming for H/sub 2/ production for fuel cells because of the wider range of fuels which can be converted, the conversion of individual fuel components was studied. Attempts have been made to characterize the chemical reactions of light and heavy paraffins and aromatics in ATR. Results of studies to determine the effects of operating parameters on the carbon-forming tendency of each hydrocarbon type are reported. The catalyst used for the ATR process was three-layers of supported nickel catalysts, Norton NC-100 spheres in the top zone, cylindrical G-56B tablets in the bottom one, and either ICI 46-I or ICI 46-4 Raschig rings in the middle zone. A summary of the experimental studies of the ATR of n-hexane, n-tetradecane, benzene, and benzene solutions of naphthalene is presented. (BLM)

  4. The mathematics education reform: What is it and why should you care?

    E-Print Network [OSTI]

    Wu, Hung-Hsi

    The mathematics education reform: What is it and why should you care? H. Wu Department. Introduction §2. Special features of the reform §3. A little background §4. The manifesto of the reform the current math- ematics education reform movement. As used here, "reform" refers to both the K-12

  5. Application of the cracked pipe element to creep crack growth prediction

    SciTech Connect (OSTI)

    Brochard, J.; Charras, T.

    1997-04-01T23:59:59.000Z

    The modification of a computer code for leak before break analysis is very briefly described. The CASTEM2000 code was developed for ductile fracture assessment of piping systems with postulated circumferential through-wall cracks under static or dynamic loading. The modification extends the capabilities of the cracked pipe element to the determination of fracture parameters under creep conditions (C*, {phi}c and {Delta}c). The model has the advantage of evaluating significant secondary effects, such as those from thermal loading.

  6. Autothermal hydrodesulfurizing reforming method and catalyst

    SciTech Connect (OSTI)

    Krumpelt, Michael; Kopasz, John P.; Ahmed, Shabbir; Kao, Richard Li-chih; Randhava, Sarabjit Singh

    2005-11-22T23:59:59.000Z

    A method for reforming a sulfur-containing carbonaceous fuel in which the sulfur-containing carbonaceous fuel is mixed with H.sub.2 O and an oxidant, forming a fuel/H.sub.2 O/oxidant mixture. The fuel H.sub.2 O/oxidant mixture is brought into contact with a catalyst composition comprising a dehydrogenation portion, an oxidation portion and a hydrodesulfurization portion, resulting in formation of a hydrogen-containing gas stream.

  7. Partial oxidation fuel reforming for automotive power systems.

    SciTech Connect (OSTI)

    Ahmed, S.; Chalk, S.; Krumpelt, M.; Kumar, R.; Milliken, J.

    1999-09-07T23:59:59.000Z

    For widespread use of fuel cells to power automobiles in the near future, it is necessary to convert gasoline or other transportation fuels to hydrogen on-board the vehicle. Partial oxidation reforming is particularly suited to this application as it eliminates the need for heat exchange at high temperatures. Such reformers offer rapid start and good dynamic performance. Lowering the temperature of the partial oxidation process, which requires the development of a suitable catalyst, can increase the reforming efficiency. Catalytic partial oxidation (or autothermal) reformers and non-catalytic partial oxidation reformers developed by various organizations are presently undergoing testing and demonstration. This paper summarizes the process chemistries as well as recent test data from several different reformers operating on gasoline, methanol, and other fuels.

  8. Model of crack propagation in a clay soil

    E-Print Network [OSTI]

    Carriere, Patrick Edwidge

    1985-01-01T23:59:59.000Z

    in elevation of the soil surface were recorded over time of drying for each of the treatments. A logarithmic model to predict the crack depth, the crack width, and the drop in elevation of the soil surface expressed by the equation y = A + C*logt, was found... 2 MEANS procedure results for crack depth. 3 ANOVA results for crack depth. 19 29 30 4 Values of A and C obtained from linear regression analysis for crack depth. 35 5 Selection of combinations of independent variables for maximum R...

  9. Why Do Kraft Recovery Boiler Composite Floor Tubes Crack?

    SciTech Connect (OSTI)

    Keiser, J.R.

    2001-10-22T23:59:59.000Z

    Cracks were first reported in 1992 in co-extruded 304L stainless steel/SA210 Gd Al carbon steel floor tubes of North American black liquor recovery boilers. Since then, a considerable amount of information has been collected on the tube environment, crack characteristics, the stress state of the tubes, and the crack initiation and propagation mechanisms. These studies have identified both operating procedures that apparently can greatly lessen the likelihood of crack formation in the stainless steel layer and alternate materials that appear to be much more resistant to cracking than is 304L stainless.

  10. Soil cracking modelling using the mesh-free SPH method

    E-Print Network [OSTI]

    Bui, H H; Kodikara, J; Sanchez, M

    2015-01-01T23:59:59.000Z

    The presence of desiccation cracks in soils can significantly alter their mechanical and hydrological properties. In many circumstances, desiccation cracking in soils can cause significant damage to earthen or soil supported structures. For example, desiccation cracks can act as the preference path way for water flow, which can facilitate seepage flow causing internal erosion inside earth structures. Desiccation cracks can also trigger slope failures and landslides. Therefore, developing a computational procedure to predict desiccation cracking behaviour in soils is vital for dealing with key issues relevant to a range of applications in geotechnical and geo-environment engineering. In this paper, the smoothed particle hydrodynamics (SPH) method will be extended for the first time to simulate shrinkage-induced soil cracking. The main objective of this work is to examine the performance of the proposed numerical approach in simulating the strong discontinuity in material behaviour and to learn about the crack ...

  11. Improved System Performance and Reduced Cost of a Fuel Reformer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System Performance and Reduced Cost of a Fuel Reformer, LNT, and SCR Aftertreatment System Meeting Emissions Useful Life Requirement Improved System Performance and Reduced Cost of...

  12. Compatibility of selected ceramics with steam-methane reformer environments

    SciTech Connect (OSTI)

    Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

    1996-04-01T23:59:59.000Z

    Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

  13. On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer

    Broader source: Energy.gov (indexed) [DOE]

    On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Mark Hemingway, Dr. Joachim Kupe, Joseph Bonadies, Mike Seino, Dr. John Kirwan, - Delphi Powertrain DEER, August...

  14. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming...

  15. Agenda for the Derived Liquids to Hydrogen Distributed Reforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to Hydrogen Distributed...

  16. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Laboratory Investigation of Reaction Networks and Active Sites in Bio-Ethanol Steam Reforming over Cobalt Based Catalysts, Umit Ozkan, Ohio State University Hydrogen...

  17. Distributed Reforming of Renewable Liquids via Water Splitting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

  18. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets

    Broader source: Energy.gov [DOE]

    Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  19. actinide reformer concept: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Private Insurance Market Renewable Energy Websites Summary: SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION...

  20. advance hatchery reform: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Private Insurance Market Renewable Energy Websites Summary: SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION...

  1. agricultural price reforms: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    co-payments as well as to sizable decreases in overall producer revenues and health care expenditures. The reform induced consumers to substitute away from branded drugs for...

  2. autothermal steam reforming: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Private Insurance Market Renewable Energy Websites Summary: SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION...

  3. abortion law reform: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to reform Massachusetts law Materials Science Websites Summary: , and access to health care. The course benefitted from the continued dedication of an exceptional teachingAdvocacy...

  4. Diesel Reformers for On-board Hydrogen Applications

    Broader source: Energy.gov (indexed) [DOE]

    After-treatment Catalyst Clean Exhaust Effective Catalyst Regeneration Emission Reduction Electricity for On-road and Idling Loads SOFC APU Efficiency Boost Reformers for...

  5. Moving Toward a Vision of Family Independence: Local Managers' Views of Michigan's Welfare Reforms

    E-Print Network [OSTI]

    Shyy, Wei

    Reforms Kristin S. Seefeldt Jodi Sandfort Sandra K. Danziger February, 1998 This project is supported? .................................................................................39 SECTION IV: MANAGERS' VIEW OF WELFARE REFORM AND IMPLEMENTATION ISSUES......................................................................44 Support for Reform Initiatives

  6. Globalization, Economic Reform, and Structural Price Transmission: SAM Decomposition Techniques with an empirical application to Vietnam

    E-Print Network [OSTI]

    Kammen, Daniel M.

    1 Globalization, Economic Reform, and Structural Price Transmission: SAM Decomposition Techniques those which have been slow to reform systems of administered prices. Such allocation mechanisms now undermine reform and structural adjustments efforts in this important emerging Asian economy. Key words

  7. Reforming the EU: The Future of European Law and Policy IV CONFERENCE PROGRAMME

    E-Print Network [OSTI]

    Birmingham, University of

    Reforming the EU: The Future of European Law and Policy IV CONFERENCE session "Reforming the EU" Chair: Dr Luca Rubini, Deputy Director Institute Rubini Reforming European competition law: should the European Commission have

  8. Negotiating Education Reform: Teacher Evaluations and Incentives in Chile (1990-2010)

    E-Print Network [OSTI]

    Mizala, Alejandra

    Reforms designed to improve the quality of teaching by reforming personnel practices, such as pay for performance arrangements, usually run into opposition from well-organized teacher unions that can either block reform ...

  9. Electricity Sector Reform in Developing Countries: A Survey of Empirical Evidence on Determinants and Performance

    E-Print Network [OSTI]

    Jamasb, Tooraj; Mota, Raffaella L; Newbery, David; Pollitt, Michael G.

    2004-07-09T23:59:59.000Z

    This paper reviews the empirical evidence on electricity reform in developing countries. We find that country institutions and sector governance play an important role in success and failure of reform; reforms appear to have increased operating...

  10. Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon

    E-Print Network [OSTI]

    Millar, Andrew J.

    Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon Countries, Vickerstaff, S & Loretto, W 2012, 'Reforming State Pension provision in `Liberal' Anglo Saxon Countries: Re University Press. Lain, D., Vickerstaff, S. & Loretto, W. 2012, "Reforming State Pension provision

  11. Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type or Print)

    E-Print Network [OSTI]

    Brown, Lucy L.

    Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type Care Structural Reform: What's Happening in Albany and Washington? Changing the Social Determinants of Health Reform in the Pharmaceutical Industry Sustaining Community Health Workers Comparative

  12. Aligning modes of organization with technology: Critical transactions in the reform of infrastructures

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Aligning modes of organization with technology: Critical transactions in the reform of their reform. Since infrastructures are characterized by strong technical complementarities, we explore the alignment between organization and technology and should be taken explicitly into account when reforming

  13. DEVELOPMENT AND DEPLOYMENT OF VACUUM SALT DISTILLATION AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.; Edwards, T.

    2010-10-28T23:59:59.000Z

    The Savannah River Site has a mission to dissolve fissile materials and disposition them. The primary fissile material is plutonium dioxide (PuO{sub 2}). To support dissolution of these materials, the Savannah River National Laboratory (SRNL) designed and demonstrated a vacuum salt distillation (VSD) apparatus using both representative radioactive samples and non-radioactive simulant materials. Vacuum salt distillation, through the removal of chloride salts, increases the quantity of materials suitable for processing in the site's HB-Line Facility. Small-scale non-radioactive experiments at 900-950 C show that >99.8 wt % of the initial charge of chloride salt distilled from the sample boat with recovery of >99.8 wt % of the ceric oxide (CeO{sub 2}) - the surrogate for PuO{sub 2} - as a non-chloride bearing 'product'. Small-scale radioactive testing in a glovebox demonstrated the removal of sodium chloride (NaCl) and potassium chloride (KCl) from 13 PuO{sub 2} samples. Chloride concentrations were distilled from a starting concentration of 1.8-10.8 wt % to a final concentration <500 mg/kg chloride. Initial testing of a non-radioactive, full-scale production prototype is complete. A designed experiment evaluated the impact of distillation temperature, time at temperature, vacuum, product depth, and presence of a boat cover. Significant effort has been devoted to mechanical considerations to facilitate simplified operation in a glovebox.

  14. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect (OSTI)

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01T23:59:59.000Z

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  15. Sustaining School Reform: Lessons from Georgia Education Policy and Evaluation Center, College of Education, University of Georgia

    E-Print Network [OSTI]

    Scott, Robert A.

    Sustaining School Reform: Lessons from Georgia Education Policy and Evaluation Center, College addressing lessons learned from two years of evaluation of Comprehensive School Reform (CSR) grant recipients implementing reform initiatives, in general. Background The Comprehensive School Reform (CSR) Program began

  16. Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof

    SciTech Connect (OSTI)

    Oswald, A.A.; Bhatia, R.N.; Mozeleski, E.J.; Glivicky, A.P.; Brueggeman, B.G.; Hooten, J.R.; Smith, C.M.; Hsu, C.S.

    1991-07-09T23:59:59.000Z

    This patent describes a hydroformylation-hydrogenation process comprising reacting an olefinic cracked petroleum distillate feed, produced from petroleum residue by high temperature thermal cracking, and containing C{sub 5} to C{sub 35}-1-n-alkyl olefins as the major type of olefin components, and organic sulfur compounds in concentrations exceeding 0.1% sulfur. It comprises at first with carbon monoxide and hydrogen at temperatures between about 50 and 250{degrees} C and pressures in the range of 50 to 6000 psi; in the presence of a Group VIII transition metal carbonyl complex catalyst in effective amounts to produce aldehydes of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule.

  17. SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS

    SciTech Connect (OSTI)

    Klein, J; Jeffrey Holder, J

    2007-07-16T23:59:59.000Z

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

  18. Screening tests for improved methane cracking materials

    SciTech Connect (OSTI)

    Klein, J. E.; Hoelder, J. S. [Savannah River National Laboratory, Aiken, SC 29808 (United States)

    2008-07-15T23:59:59.000Z

    Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{sup R} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 deg.C, 101.3 kPa (760 torr) with a 10 seem feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAESr getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas. (authors)

  19. Process for magnetic beneficiating petroleum cracking catalyst

    DOE Patents [OSTI]

    Doctor, R.D.

    1993-10-05T23:59:59.000Z

    A process is described for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded. 1 figures.

  20. Process for magnetic beneficiating petroleum cracking catalyst

    DOE Patents [OSTI]

    Doctor, Richard D. (Lisle, IL)

    1993-01-01T23:59:59.000Z

    A process for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded.