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Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Review of Novel Catalysts for Biomass Tar Cracking and Methane Reforming  

SciTech Connect (OSTI)

A review of the literature was conducted to examine the performance of catalysts other than conventional nickel catalysts, and alkaline earth and olivine based catalysts for treating hot raw product gas from a biomass gasifier to convert methane and tars into synthesis gas. Metal catalysts other than Ni included precious metals Rh, Ru, Ir, Pt, and Pd, as well as Cu, Co, and Fe in limited testing. Nickel catalysts promoted with Rh, Zr, Mn, Mo, Ti, Ag, or Sn were also examined, as were Ni catalysts on Ce2O3, TiO2, ZrO2, SiO2, and La2O3. In general, Rh stood out as a consistently superior metal catalyst for methane reforming, tar cracking, and minimizing carbon buildup on the catalyst. Ru and Ir also showed significant improvement over Ni for methane reforming. Ceria stood out as good support material and particularly good promoter material when added in small quantities to another support material such as alumina, zirconia, or olivine. Other promising supports were lanthana, zirconia, and titania.

Gerber, Mark A.

2007-10-10T23:59:59.000Z

2

Gamma prime embrittlement and thermal fatigue cracking of a hydrogen reformer burner end  

SciTech Connect (OSTI)

An investigation into the premature failure of an Alloy 800HT (UNS N08811) oxygen-gas mixer water jacketed end is discussed. Detailed metallurgical analyses showed that gamma prime [Ni{sub 3} (Al, Ti)] embrittlement and thermal fatigue cracking led to eventual leakage. The reduced lif e of the Alloy 800HT (UNS N08811) replacement (problems after only a year) was traced to its higher Al + Ti content (1.1%) compared to Alloy 800H (0.6% Al + Ti) which lasted over two years. While higher aluminum and titanium levels improve high temperature creep and stress rupture properties, both are sigma formers and, at levels > 0.6%, tend to form gamma prime with nickel. The choice of alternative metallurgies requires careful considerations of physical, mechanical and thermal properties as well as an understanding of complex stresses and stress distributions.

Dias, O.C.; Mack, N.C. [Amoco Oil Co., Texas City, TX (United States)

1994-12-31T23:59:59.000Z

3

Catalytic Distillation  

E-Print Network [OSTI]

removing both will occur in the temperature range ne~ded high and low boilers to maintain the tower for reaction. One limitation may be .I the composition profile, exothermic reactions critical point of the system, above w~ich can be easily temperature... with significantly less energy. There are two primary reasons for energy reduction: 1. The heat of reaction for exothermic reactions is fully re covered as useful boilup for fractionation. 2. Fewer attendant distillations are normally required than for a...

Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

1984-01-01T23:59:59.000Z

4

INNOVATION EDUCATION EXCELLENCE DISTILLATIONS  

E-Print Network [OSTI]

INNOVATION · EDUCATION · EXCELLENCE DISTILLATIONS University of Toronto CHEMISTRY ALUMNI MAGAZINE.utoronto.ca / distillations 2012 MessagefromtheChair Our Department of Chemistry has one of the finest collection of peo- ple to a better, more sustain- able future. This issue of Distillations highlights the accomplishments last year

Chan, Hue Sun

5

DUNCAN PRITCHARD Reforming Reformed Epistemology*  

E-Print Network [OSTI]

DUNCAN PRITCHARD Reforming Reformed Epistemology* 0. Introduction There has been a renaissance-called "reformed" defence of the rationality of reli- gious belief. The starting-point for this reformed conception concern here. Instead, I will be outlining one way in which the reformed epistemological stance can

Edinburgh, University of

6

Advanced Distillation Final Report  

SciTech Connect (OSTI)

The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

2010-03-24T23:59:59.000Z

7

Distillation: The Efficient Workhorse  

E-Print Network [OSTI]

DISTILLATION: THE EFFICIENT WORKHORSE Dan Steinmeyer Monsanto Company St. Louis, Missouri Distillation is inherently highly efficient: phase separation is clean it is relatively easy to build a mUltistage countercurrent device equilibrium... of separation to the work pmbedded in the reboiler and condenser thermal flows. The right application is one where the streams ? separated both exceed la' of the feed, relative volatility exceeds 1.2, and separation is complete - i.e. pure products...

Steinmeyer, D.

8

Energy efficient distillation apparatus  

SciTech Connect (OSTI)

An energy efficient distillation method is provided which is particularly adapted for use on a dairy farm, and which comprises a distilland evaporating receptacle, a distillate condensing receptacle, and a conduit interconnecting the evaporating receptacle and the condensing receptacle. A vacuum pump is provided for drawing a partial vacuum within the evaporating receptacle, and a vapor compression refrigeration system is provided which includes condenser coils disposed to heat and vaporize the distilland while it is within the evaporating receptacle, and evaporator coils for cooling and condensing the vaporized distilland in the condensing receptacle. A cooling distribution system is also provided whereby a variable portion of the cooling potential of the refrigeration system may be selectively directed to each of the condensing receptacle, a distillate receiver tank, or to a bulk milk container as utilized on a dairy farm or the like.

Melton, J.D.

1982-08-17T23:59:59.000Z

9

Distillate fuel-oil processing for phosphoric acid fuel-cell power plants  

SciTech Connect (OSTI)

The current efforts to develop distillate oil-steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high-temperature steam reforming (HTSR); autothermal reforming (ATR); autothermal gasification (AG); and ultra desulfurization followed by steam reforming. Sulfur in the feed is a key problem in the process development. A majority of the developers consider sulfur as an unavoidable contaminant of distillate fuel and are aiming to cope with it by making the process sulfur-tolerant. In the HTSR development, the calcium aluminate catalyst developed by Toyo Engineering represents the state of the art. United Technology (UTC), Engelhard, and Jet Propulsion Laboratory (JPL) are also involved in the HTSR research. The ATR of distillate fuel is investigated by UTC and JPL. The autothermal gasification (AG) of distillate fuel is being investigated by Engelhard and Siemens AG. As in the ATR, the fuel is catalytically gasified utilizing the heat generated by in situ partial combustion of feed, however, the goal of the AG is to accomplish the initial breakdown of the feed into light gases and not to achieve complete conversion to CO and H/sub 2/. For the fuel-cell integration, a secondary reforming of the light gases from the AG step is required. Engelhard is currently testing a system in which the effluent from the AG section enters the steam-reforming section, all housed in a single vessel. (WHK)

Ushiba, K. K.

1980-02-01T23:59:59.000Z

10

Attrition resistant fluidizable reforming catalyst  

DOE Patents [OSTI]

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

2011-03-29T23:59:59.000Z

11

Distributed Reforming of Biomass Pyrolysis Oils: Cooperative Research and Development Final Report, CRADA number CRD-06-00192  

SciTech Connect (OSTI)

The objective of this project is for Chevron and NREL to collaborate in determining the effect of bio-oil composition variability on autothermal reforming performance including bio-oil volatilization, homogeneous oxidative cracking, and catalytic reforming.

Czernik, S.

2010-07-01T23:59:59.000Z

12

Reflux for multifeed distillation  

SciTech Connect (OSTI)

Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

Chou, S.M.; Yaws, C.L.

1986-12-01T23:59:59.000Z

13

Low Energy Distillation Schemes  

E-Print Network [OSTI]

an important means of reducing energy consumption in distillation processes. However, its conventional use requires the installation of piping (and pipes carrying vapour streams tend to be of large diameter and are consequently expensive). So, finally we.... However, its conventional use requires the installation of piping (and pipes carrying vapour streams tend to be of large diameter and are consequently expensive). In the late eighties engineers in Germany [e.g. Kaibel, 1987] looked at one way in which...

Polley, G. T.

14

Oil recovery from condensed corn distillers solubles.  

E-Print Network [OSTI]

??Condensed corn distillers solubles (CCDS) contains more oil than dried distillers grains with solubles (DDGS), 20 vs. 12% (dry weight basis). Therefore, significant amount of… (more)

Majoni, Sandra

2009-01-01T23:59:59.000Z

15

Optimal Control of Distillation Systems  

E-Print Network [OSTI]

The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

Chatterjee, N.; Suchdeo, S. R.

1984-01-01T23:59:59.000Z

16

Integrating Gas Turbines with Cracking Heaters - Impact on Emissions and Energy Efficiency  

E-Print Network [OSTI]

Turbine Exhaust Gas (TEG) contains high levels of oxygen, typically 15 vol. percent, due to gas turbine blade material temperature limits. As such it can be used as an oxidant for combustion in cracking furnaces and reformers. Its high temperature...

Platvoet, E.

2011-01-01T23:59:59.000Z

17

Distilling entanglement from arbitrary resources  

E-Print Network [OSTI]

We obtain the general formula for the optimal rate at which singlets can be distilled from any given noisy and arbitrarily correlated entanglement resource, by means of local operations and classical communication (LOCC). Our formula, obtained by employing the quantum information spectrum method, reduces to that derived by Devetak and Winter, in the special case of an i.i.d. resource. The proofs rely on a one-shot version of the so-called "hashing bound," which in turn provides bounds on the one-shot distillable entanglement under general LOCC.

Francesco Buscemi; Nilanjana Datta

2010-10-15T23:59:59.000Z

18

Corrosion inhibition for distillation apparatus  

DOE Patents [OSTI]

Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY); Schweighardt, Frank K. (Upper Macungie, PA)

1985-01-01T23:59:59.000Z

19

Optimal distillation using thermodynamic geometry Bjarne Andresen  

E-Print Network [OSTI]

(temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2Optimal distillation using thermodynamic geometry Bjarne Andresen Ørsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler

Salamon, Peter

20

Momentive Performance Materials Distillation Intercharger  

E-Print Network [OSTI]

Presenter: Nicki (Collins) Boucher Project Team: T. Baisley, C. Beers, R. Cameron, K. Holman, T. Kotkoskie, K. Norris Momentive Performance Materials Inc. Waterford, NY May 23, 2013 Industrial Energy Technology Conference ACC Responsible... Care? Energy Efficiency Program Momentive Performance Materials Distillation Interchanger ESL-IE-13-05-20 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Copyright 2013 Momentive Performance...

Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Fluid catalytic cracking of heavy petroleum fractions  

SciTech Connect (OSTI)

A process is claimed for fluid catalytic cracking of residuum and other heavy oils comprising of gas oil, petroleum residue, reduced and whole crudes and shale oil to produce gasoline and other liquid products which are separated in various streams in a fractionator and associated vapor recovery equipment. The heat from combustion of coke on the coked catalyst is removed by reacting sulfur-containing coke deposits with steam and oxygen in a separate stripper-gasifier to produce a low btu gas stream comprising of sulfur compounds, methane, carbon monoxide, hydrogen, and carbon dioxide at a temperature of from about 1100/sup 0/F. To about 2200/sup 0/F. The partially regenerated catalyst then undergoes complete carbon removal in a regeneration vessel. The regenerated catalyst is recycled for re-use in the cracking of heavy petroleum fractions. The liquid products are gasoline, distillates, heavy fuel oil, and light hydrocarbons.

McHenry, K.W.

1981-06-30T23:59:59.000Z

22

Crack coalescence in granite  

E-Print Network [OSTI]

This thesis experimentally investigates crack coalescence in prismatic Barre Granite specimens with two pre-cut, open flaws under uniaxial compression. Using a high-speed video system, crack initiation, propagation, and ...

Miller, James Thomas, Ph. D. Massachusetts Institute of Technology

2008-01-01T23:59:59.000Z

23

Steam reforming analyzed  

SciTech Connect (OSTI)

This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

1992-07-01T23:59:59.000Z

24

Rank three bipartite entangled states are distillable  

E-Print Network [OSTI]

We prove that the bipartite entangled state of rank three is distillable. So there is no rank three bipartite bound entangled state. By using this fact, We present some families of rank four states that are distillable. We also analyze the relation between the low rank state and the Werner state.

Lin Chen; Yi-Xin Chen

2008-03-07T23:59:59.000Z

25

Locally Accessible Information and Distillation of Entanglement  

E-Print Network [OSTI]

A new type of complementary relation is found between locally accessible information and final average entanglement for given ensemble. It is also shown that in some well known distillation protocol, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

Sibasish Ghosh; Pramod Joag; Guruprasad Kar; Samir Kunkri; Anirban Roy

2004-03-18T23:59:59.000Z

26

Forpeerreview Synthesis of Complex Thermally Coupled Distillation  

E-Print Network [OSTI]

US energy consumption, which is equivalent to 2.87x10 18 J (2.87 million TJ) per year, or to a power; Divided Wall Column; Superstructure optimization; GDP. Introduction Distillation is one of the most limitations. Distillation columns use very large amounts of energy because the evaporation steps involved

Grossmann, Ignacio E.

27

Distillability of entanglement in accelerated frames  

E-Print Network [OSTI]

We study the entanglement distillability of bipartite mixed states of two modes of a free Dirac field as seen by two relatively accelerated parties. It is shown that there are states that will change from distillable into separable for a certain value of acceleration. We exemplify these criteria in the context of Werner states.

Shahpoor Moradi

2012-01-02T23:59:59.000Z

28

New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes  

SciTech Connect (OSTI)

This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

Agrawal, Rakesh

2013-11-21T23:59:59.000Z

29

New Design Methods and Algorithms for Multi-component Distillation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf More...

30

acrobat distiller job: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

31

Immigration reform and California agriculture  

E-Print Network [OSTI]

reform and California agriculture Philip Martin Professor,proposals for California agriculture. Immigration reformCenter. 196 CALIFORNIA AGRICULTURE • VOLUME 67 , NUMBER 4

Martin, Philip

2013-01-01T23:59:59.000Z

32

Distillation: Still towering over other options  

SciTech Connect (OSTI)

Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

Kunesh, J.G. [Fractionation Research, Inc., Stillwater, OK (United States); Kister, H.Z. [Brown and Root, Inc., Alhambra (Canada); Lockett, M.J. [Praxair, Inc., Tonawanda, NY (United States); Fair, J.R. [Univ. of Texas, Austin, TX (United States)

1995-10-01T23:59:59.000Z

33

Development of energy efficient membrane distillation systems  

E-Print Network [OSTI]

Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

Summers, Edward K

2013-01-01T23:59:59.000Z

34

Minimizing corrosion in coal liquid distillation  

DOE Patents [OSTI]

In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

1985-01-01T23:59:59.000Z

35

Absorptive Recycle of Distillation Waste Heat  

E-Print Network [OSTI]

condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

Erickson, D. C.; Lutz, E. J., Jr.

1982-01-01T23:59:59.000Z

36

An improved model for multiple effect distillation  

E-Print Network [OSTI]

Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

Mistry, Karan H.

37

Advancing Biorefining of Distillers Grain and Corn Stover Blends  

Broader source: Energy.gov (indexed) [DOE]

pretreatment process for distiller's grains and corn stover to convert residual starch, cellulose, and hemicellulose to ethanol and high- converting residual starch in order to...

38

Complex Fluid Analysis with the Advanced Distillation Curve Approach  

E-Print Network [OSTI]

of a complex fluid is a graph of boiling temperature versus volume fraction distilled, a procedure embodied for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements) an assessment of the energy content of each distillate fraction; (6) trace chemical analysis of each distillate

39

Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates  

SciTech Connect (OSTI)

High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

1987-04-01T23:59:59.000Z

40

Catalytic reforming methods  

DOE Patents [OSTI]

A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

Tadd, Andrew R; Schwank, Johannes

2013-05-14T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Crack isobutane for isobutylene  

SciTech Connect (OSTI)

This paper describes the coastal isobutane cracking process which cracks isobutane under controlled conditions in the presence of steam utilizing efficient tubular furnaces and produces high propylene and isobutylene yields. The authors list the options to which this process lends itself.

Soudek, M. (Coastal States Management Corp., Houston, TX (US)); Lacatena, J.J. (Foster Wheeler USA Corp., Clinton, NJ (US))

1990-05-01T23:59:59.000Z

42

NETL - Fuel Reforming Facilities  

ScienceCinema (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2014-06-27T23:59:59.000Z

43

NETL - Fuel Reforming Facilities  

SciTech Connect (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2013-06-12T23:59:59.000Z

44

Natural Gas Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen Production Natural Gas Reforming Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon...

45

Elevated temperature crack propagation  

SciTech Connect (OSTI)

This paper is a summary of two NASA contracts on high temperature fatigue crack propagation in metals. The first evaluated the ability of fairly simple nonlinear fracture parameters to correlate crack propagation. Hastelloy-X specimens were tested under isothermal and thermomechanical cycling at temperatures up to 980 degrees C (1800 degrees F). The most successful correlating parameter was the crack tip opening displacement derived from the J-integral. The second evaluated the ability of several path-independent integrals to correlate crack propagation behavior. Inconel 718 specimens were tested under isothermal, thermomechanical, temperature gradient, and creep conditions at temperatures up to 650 degrees C (1200 degrees F). The integrals formulated by Blackburn and by Kishimoto correlated the data reasonably well under all test conditions.

Orange, T.W.

1994-02-01T23:59:59.000Z

46

Plasmatron Fuel Reformer Development and Internal Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications...

47

Distillation sequence for the purification and recovery of hydrocarbons  

DOE Patents [OSTI]

This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

2007-12-25T23:59:59.000Z

48

Sulfur distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale  

E-Print Network [OSTI]

by the thermal cracking process of the El-Lujjan oil shale showed that the yield of oil was around 12 wt of the boiling point for different distillate fractions. Sulfur in Jordanian oil shale was found to be mainly the dominant phases in these fractions. q 2005 Published by Elsevier Ltd. 1. Introduction Oil shale

Shawabkeh, Reyad A.

49

Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) Geographic Area Month Kerosene No. 1 Distillate No. 2...

50

Desalination Using Vapor-Compression Distillation  

E-Print Network [OSTI]

and MSF, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas...

Lubis, Mirna R.

2010-07-14T23:59:59.000Z

51

Complex Distillation Arrangements : Extending the Petlyuk Ideas  

E-Print Network [OSTI]

to distillation columns ac- count for roughly 3 of the total energy consumption in the U.S. (Ognisty 1995 to reduce energy consumption at least two alternative approaches have been proposed both in the literature is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

Skogestad, Sigurd

52

Minimum Energy Diagrams for Multieffect Distillation Arrangements  

E-Print Network [OSTI]

and the energy use from this process accounts for an estimated 3% of the world energy consumption.1 With rising on the overall plant energy consumption. The use of heat integration combined with complex config- urations distillation ar- rangements. An easy form of comparison for energy consumption is the minimum vapor flow rate

Skogestad, Sigurd

53

Naphthenic acid corrosion in crude distillation units  

SciTech Connect (OSTI)

This paper summarizes corrosion experience in crude distillation units processing highly naphthenic California crude oils. Correlations have been developed relating corrosion rates to temperature and total acid number. There is a threshold acid number in the range of 1.5 to 2 mg KOH/g below which corrosion is minimal. High concentrations of hydrogen sulfide may raise this threshold value.

Piehl, R.L.

1988-01-01T23:59:59.000Z

54

Distillation: Present Status and Future Directions  

E-Print Network [OSTI]

-pressure steam as a heat source. The steam has, very likely, been sent through one or more users (turbi ne dri ves) before reaching the distillation reboiler. It seems almost characteristic of large chemical and refining complexes that there is a chronic...

Fair, J. R.; Humphrey, J. L.

1984-01-01T23:59:59.000Z

55

Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves  

SciTech Connect (OSTI)

Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

1996-11-01T23:59:59.000Z

56

Construction and operation of a flash distillation apparatus  

E-Print Network [OSTI]

, Calibration Data of Orifioe ~, i, . ~ ~ ~ . ~ ~ . ~ 13 III. Equilibrium Data of Ethanol-Eater Mixtures . ~ * ~ ~ , 17 IV, . Flash Vaporieation Data of Ethanol Hater hIlxtures& + , 18 VI ~ Hempel Distillation of Oklahoma City Crude ~ . . . Flash... Vaporiration of Oklahoma City Crude ~ . ~ 21 22 VII' Hempel Distillations of Flash Distillates of Oklahoma City Crude . ~ ~ ~ ~ ~ ~ ~ i ~ ~ ~ ~ ~ ~ ~ ~ 24 VIII+ Hompel Distillations of Flash Residuums of Oklahoma City Crude ~ ~ ~ ~ ~ i ~ ~ o...

Knezevich, Milan

2012-06-07T23:59:59.000Z

57

FOOD REFORM MOVEMENTS Nicolas Larchet  

E-Print Network [OSTI]

FOOD REFORM MOVEMENTS Nicolas Larchet Social historians have broadly defined two cycles of American history characterized by an efflorescence of social movements aiming to reform both the individual to the 1920s. The reform impulse thrived wherever there was a perceived vice, abuse or corruption

Boyer, Edmond

58

Reforming the Private Insurance Market  

E-Print Network [OSTI]

SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION he prospects for national health care reform are more promising than at any time since 1994. President Obama and Members of Congress have made health care reform a top priority and legislation

Kammen, Daniel M.

59

Autothermal reforming catalyst and process  

SciTech Connect (OSTI)

High activity steam reforming catalysts are described particularly adapted for use in autothermal reforming processes. A rhodium catalyst on a calcium oxide impregnated alumina substrate allow the autothermal reforming process to take place with substantially no carbon plugging at oxygen to carbon ratios below what had been considered critical for avoiding carbon plugging of the catalyst in the past.

Setzer, H. J.; Karavolis, S.; Lesieur, R. R.; Wnuck, W. G.

1984-09-25T23:59:59.000Z

60

Integrated C3 Feedstock and Aggregated Distillation Model for  

E-Print Network [OSTI]

Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits Distillation Model Relates overhead composition of propane with flowrate of propane feed to the splitter

Grossmann, Ignacio E.

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens,  

E-Print Network [OSTI]

to infinity. We call such protocols asymp- totic and the fraction of distilled Bell states per initial copy#12;#12;Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens, Jeroen: July 13, 2006) We present a new asymptotic bipartite entanglement distillation protocol

62

DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY  

E-Print Network [OSTI]

: 47-7-594080 Figure 1: Typical simple distillation column. zF, yD and xB are mole fractions. tureDYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed

Skogestad, Sigurd

63

Effect of Number of Fractionating Trays on Reactive Distillation Performance  

E-Print Network [OSTI]

Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

Al-Arfaj, Muhammad A.

64

DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY  

E-Print Network [OSTI]

distillation column. z F , yD and xB are mole fractions. ture review, but a few new ideas are also presentedDYNAMICS AND CONTROL OF DISTILLATION COLUMNS ­ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177­217, 1997. Abstract Distillation column dynamics and control has been viewed

Skogestad, Sigurd

65

Model Predictive Control of a Kaibel Distillation Column  

E-Print Network [OSTI]

column with model predictive control (MPC). A Kaibel distillation column has several advantages comparedModel Predictive Control of a Kaibel Distillation Column Martin Kvernland Ivar Halvorsen Sigurd only a single column shell. The distillation process is a multivariable process which leads

Skogestad, Sigurd

66

RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT  

E-Print Network [OSTI]

RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT J. R. Taylor**, 0. Hansen*, C. Jensen*, 0. F. A risk analysis of a batch distillation unit is de- scribed. The analysis has been carried out at several.2. Objectives and organisation 5 1.2.2. Philosophy and approach 6 1.3.1. The distillation unit 8 1

67

CHEM333: Experiment 4: Steam Distillation of Essential Oils;  

E-Print Network [OSTI]

CHEM­333: Experiment 4: Steam Distillation of Essential Oils; Experiments A, C, D and below. Reading: For this experiment read Chapter 10. This week you will get to use steam distillation to isolate may wait until you come to lab to find out which spice you get. Steam distillation is not a common

Taber, Douglass

68

Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction  

SciTech Connect (OSTI)

The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

2007-09-15T23:59:59.000Z

69

Crack propagation in Hastelloy X  

SciTech Connect (OSTI)

The fatigue and creep crack growth rates of Hastelloy X were examined both in air and impure helium. Creep crack growth rate is higher in air and impure helium at 650/sup 0/C. Initial creep crack growth from the original sharp fatigue crack is by an intergranular mode of fracture. As the cracking accelerates at higher stress intensities, growth is by a mixed mode of both intergranular and transgranular fracture. Fatigue crack growth rate increases with increasing temperature and decreasing frequency for the range of stress intensities reported in the literature and is lower in impure helium than in air.

Weerasooriya, T.; Strizak, J.P.

1980-05-01T23:59:59.000Z

70

Dry reforming of hydrocarbon feedstocks  

SciTech Connect (OSTI)

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

71

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1984-03-27T23:59:59.000Z

72

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1985-08-20T23:59:59.000Z

73

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1984-01-01T23:59:59.000Z

74

Contact structure for use in catalytic distillation  

DOE Patents [OSTI]

A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1985-01-01T23:59:59.000Z

75

Reflective Cracking Study: Summary Report  

E-Print Network [OSTI]

Cracking Study: First-level Report on Laboratory ShearStudy: Second-Level Analysis Report. Davis and Berkeley, CA:Cracking Study: First-level Report on HVS Testing on Section

Jones, David; Harvey, John T; Monismith, Carl L.

2008-01-01T23:59:59.000Z

76

Hydrocarbon cracking catalyst  

SciTech Connect (OSTI)

This patent describes a catalyst composition for cracking hydrocarbons to maximize gasoline comprising: rare earth exchanged ''Y'' crystalline faujasite dispersed in a clay containing matrix material; and which has been subsequently further ion exchanged to contain 0.20 to 3.0 wt% yttrium, calculated as the oxide, whereby the yttrium is chemically combined in the catalyst composition.

Lochow, C.F.; Kovacs, D.B.

1988-12-27T23:59:59.000Z

77

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

78

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

79

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

80

Methanol partial oxidation reformer  

DOE Patents [OSTI]

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Apparatus for distilling shale oil from oil shale  

SciTech Connect (OSTI)

An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

Shishido, T.; Sato, Y.

1984-02-14T23:59:59.000Z

82

Steam reformer with catalytic combustor  

DOE Patents [OSTI]

A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Voecks, Gerald E. (La Crescenta, CA)

1990-03-20T23:59:59.000Z

83

What's right SHIP & Healthcare Reform Forum  

E-Print Network [OSTI]

&Health Reform What's right for you SHIP & Healthcare Reform Forum: What's Right for You This session will help you: * demystify the healthcare reform changes * explore your options * learn how

Walker, Matthew P.

84

Energy conservation in distillation: a technology applications manual  

SciTech Connect (OSTI)

Distillation is the most widely practiced technique for separating mixtures of chemical species, but it is an energy intensive process. A 10% reduction in distillation energy consumption would effect a significant savings. On a national basis this would be an annual savings of 200 trillion Btu, or the equivalent of 36.5 million barrels of oil per year. Technology to achieve these savings in distillation energy is available and measures are presented to assist process engineers in technical and economic analysis of the energy conservation measures most suitable for particular distillation applications. The manual catalogs all of the energy conservation options applicable to distillation and the options by the investment required; describes in detail the options having a significant potential to reduce distillation energy requirements economically; provides guidelines that will allow the plant engineer to quickly screen each option for his application; and provides short-cut calculation procedures for use in a preliminary economic analysis of promising options.

Not Available

1980-05-01T23:59:59.000Z

85

Energy Conservation Options in Distillation Processes  

E-Print Network [OSTI]

~itroo.? ':!OD.e~tell.,..ot!.k1 .'k..,.-.ottNltlu'..,. II ""'I'JI ..... ~I_ """-.4008l1"OO I ~.z.,. 1 ,1'1 (-frl-.'....u_~ R.da at AC~Ofllftl\\,J'ftlit...." ? I 5 "'-tlnc&! Tt.,.. ? 21.' \\lip Gilil.In31 j TnyE.'tIc>Mcy .11.1'llo I ~~TI""'.'2.at... I There are many options available to the engi*eer seeking to reduce the energy requirements of a distil lation process. The technology for most of these I, options has been available for many years, but it has only recently become economically...

Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

1980-01-01T23:59:59.000Z

86

Use of computers for multicomponent distillation calculations  

E-Print Network [OSTI]

The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

Sullivan, Samuel Lane

1959-01-01T23:59:59.000Z

87

Advanced Distillation: Programs Proposed to DOE  

E-Print Network [OSTI]

to the foremost practitioner of the Advanced Distillation art, due to a 30 year continuity in Ule area as both a consultant and a university professor. His consulting assignments lu1ve been long-ternl

Woinsky, S. G.

88

advanced distillation control: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Morari California.Eng., Norwegian Institute of Technology (NTH), N-7034 Trondheim, Norway Paper presented at Symposium Distillation Skogestad, Sigurd 14 CONTROL AND ENERGY...

89

azeotropic distillation columns: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT How can we separate ternary mixtures in closed batch...

90

Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

91

Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...  

Gasoline and Diesel Fuel Update (EIA)

Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

92

Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...  

Gasoline and Diesel Fuel Update (EIA)

Marketing Annual 1996 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

93

Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

94

Renewable Liquid Fuels Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Renewable Liquid Fuels Reforming The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used...

95

Novel Reforming Catalysts  

SciTech Connect (OSTI)

Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

Pfefferle, Lisa D; Haller, Gary L

2012-10-16T23:59:59.000Z

96

Negative Valve Overlap Reforming Chemistry in Low-Oxygen Environments  

SciTech Connect (OSTI)

Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) and other forms of advanced combustion. When fuel is injected into O2-deficient NVO conditions, a portion of the fuel can be converted to products containing significant levels of H2 and CO. Additionally, other short chain hydrocarbons are produced by means of thermal cracking, water-gas shift, and partial oxidation reactions. The present study experimentally investigates the fuel reforming chemistry that occurs during NVO. To this end, two very different experimental facilities are utilized and their results are compared. One facility is located at Oak Ridge National Laboratory, which uses a custom research engine cycle developed to isolate the NVO event from main combustion, allowing a steady stream of NVO reformate to be exhausted from the engine and chemically analyzed. The other experimental facility, located at Sandia National Laboratories, uses a dump valve to capture the exhaust from a single NVO event for analysis. Results from the two experiments are in excellent trend-wise agreement and indicate that the reforming process under low-O2 conditions produces substantial concentrations of H2, CO, methane, and other short-chain hydrocarbon species. The concentration of these species is found to be strongly dependent on fuel injection timing and injected fuel type, with weaker dependencies on NVO duration and initial temperature, indicating that NVO reforming is kinetically slow. Further, NVO reforming does not require a large energy input from the engine, meaning that it is not thermodynamically expensive. The implications of these results on HCCI and other forms of combustion are discussed in detail.

Szybist, James P [ORNL] [ORNL; Steeper, Richard R. [Sandia National Laboratories (SNL)] [Sandia National Laboratories (SNL); Splitter, Derek A [ORNL] [ORNL; Kalaskar, Vickey B [ORNL] [ORNL; Pihl, Josh A [ORNL] [ORNL; Daw, C Stuart [ORNL] [ORNL

2014-01-01T23:59:59.000Z

97

Energy Use in Distillation Operation: Nonlinear Economic Effects  

E-Print Network [OSTI]

important. For many distillation columns there is a tradeoff in operation between energy usage and product recovery and setting the proper usage target involves a calculation of the economic tradeoff between these two factors. However, distillation is a non-linear...

White, D. C.

2010-01-01T23:59:59.000Z

98

Saber's heavy oil cracking refinery project  

SciTech Connect (OSTI)

Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

Benefield, C.S.; Glasscock, W.L.

1983-03-01T23:59:59.000Z

99

Multipath Curved Planar Reformation of the Peripheral  

E-Print Network [OSTI]

Multipath Curved Planar Reformation of the Peripheral Arterial Tree in CT Angiography1 Justus that cause artifacts in multipath curved planar reformations (MPCPRs) of the peripheral arterial tree in 10-oblique multiplanar reformations perpendicular to the ves- sel centerline (10), and curved planar reformations

100

Optimization of Multiplanar Reformations from Isotropic  

E-Print Network [OSTI]

Optimization of Multiplanar Reformations from Isotropic Data Sets Acquired with 16­ Detector Row coronal reformations at vari- ous thicknesses were ranked qualitatively by three radiol- ogists. Effective reformations of data acquired in the custom phantom were compared, coronal reformations obtained with the 16

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Toward a Reformalization of QSIM Benjamin Shults  

E-Print Network [OSTI]

Toward a Reformalization of QSIM Benjamin Shults Department of Mathematics University of Texas is to reformalize part of the framework of the Guaranteed Coverage Theorem for QSIM. The intention is not to reformalize every detail of the proof but merely to mention some areas whose reformalization lends deeper

Kuipers, Benjamin

102

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of US Navy jet fuel (JP-5) has been related to the amounts of large n-alkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how the n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30, and 32 ppM in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-01-01T23:59:59.000Z

103

Pyrolysis of shale oil vacuum distillate fractions  

SciTech Connect (OSTI)

The freezing point of U.S. Navy jet fuel (JP-5) has been related to the amounts of large nalkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how th n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30 and 32 ppm in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

Hazlett, R.N.; Beal, E.

1983-02-01T23:59:59.000Z

104

Stress corrosion crack growth in porous sandstones.   

E-Print Network [OSTI]

Stress corrosion crack growth occurs when the chemical weakening of strained crack tip bonds facilitates crack propagation. I have examined the effect of chemical processes on the growth of a creack population by carrying out triaxial compression...

Ojala, Ira O

105

Applications of solar reforming technology  

SciTech Connect (OSTI)

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

1993-11-01T23:59:59.000Z

106

Before the House Oversight and Government Reform Subcommittee...  

Office of Environmental Management (EM)

Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform...

107

Heat Integrated Distillation through Use of Microchannel Technology  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

108

CHEM333: Lab Experiment 3: Distillation and Gas Chromatography  

E-Print Network [OSTI]

. Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wine much about the mathematics of Raoult's Law; you will see it again in physical chemistry. Pay particular

Taber, Douglass

109

Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings  

E-Print Network [OSTI]

The absorption cycle offers one of the most economic and widely applicable technologies for waste heat upgrading. It can use off-the-shelf hardware that is available now, at any required capacity rating. Fractional distillations, as a class...

Erickson, D. C.; Davidson, W. F.

1984-01-01T23:59:59.000Z

110

Membrane augmented distillation to separate solvents from water  

DOE Patents [OSTI]

Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

2012-09-11T23:59:59.000Z

111

An experimental and mathematical investigation of hydrocarbon steam distillation  

E-Print Network [OSTI]

of Committee) Dr. Pau B. Crawford (Member) r. William D. McCain Jr. r. A ber t T. Watson (Member) Dr. i l. iam D. on Gonten ead of Department) December 1984 ABSTRACT An Experimental and Mathematical Investigation of Hydrocarbon Steam Distillation... mechanism associated with steam flooding and in-situ combustion enhanced oil recovery projects. It also takes place in hydrocarbon recovery from deep volatile oil reservoirs. Nethods for predicting the recovery of hydrocarbons by steam distillation have...

Langhoff, John Allan

1984-01-01T23:59:59.000Z

112

Determination of plate efficiencies for conventional distillation columns  

E-Print Network [OSTI]

DETERMINATION OF PLATE EFFICIENCIES FOR CONVENTIONAL DISTILLATION COIUMNS A Thesis By Thomas Raymond Harris Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1962 Ma)or Sub)ect t Chemical Engineering DETERMINATION OF PLATE EFFICIENCIES FOR CONVENTIONAL DISTILLATION COLUMNS A Thesis Thomas Raymond Harris Approred as to style and content bye Chairman of ommittee Head...

Harris, Thomas Raymond

2012-06-07T23:59:59.000Z

113

Single-step distillation protocol with generalized beam splitters  

SciTech Connect (OSTI)

We develop a distillation protocol for multilevel qubits (qudits) using generalized beam splitters like in the proposal of Pan et al. for ordinary qubits. We find an acceleration with respect to the scheme of Bennet et al. when extended to qudits. It is also possible to distill entangled pairs of photons carrying orbital angular momenta states that conserve the total angular momenta as those produced in recent experiments.

Martin-Delgado, M. A.; Navascues, M. [Departamento de Fisica Teorica I, Universidad Complutense, 28040 Madrid, (Spain)

2003-07-01T23:59:59.000Z

114

Integrated Thermal and Hydraulic Analysis of Distillation Columns  

E-Print Network [OSTI]

significant additional insights to help screen the options for distillation column revamps. Column Targeting Aspen Plus Column Targeting tool offers capabilities for thermal and hydraulic analysis of distillation columns. During design or retrofit analysis...). Aspen Plus Column Targeting Tool generates the CGCCs based on the Practical Near-Minimum Thermodynamic Condition (PNMTC) approximation (Dhole and Linnhoff). The enthalpies used in plotting the CGCCs are calculated at a given stage of the column...

Samant, K.; Sinclair, I.; Keady, G.

115

Synthesis and design of optimal thermal membrane distillation networks  

E-Print Network [OSTI]

distillation as a technology that can be driven by thermal energy at low enthalpy, such as geothermal energy, by using a hybrid air gap membrane distillation- fluidized bed crystallization assembly for desalination. Tomaszewska (2000) has studied... of pre-pressurizing of the membrane pores and control of dissolved gas concentrations in the feed and recycled permeate in order to prevent pore penetration and wetting (Agashichev and Sivakov, 1993). Temperature polarization effects have been...

Nyapathi Seshu, Madhav

2006-10-30T23:59:59.000Z

116

Peridynamic model for fatigue cracking.  

SciTech Connect (OSTI)

The peridynamic theory is an extension of traditional solid mechanics in which the field equations can be applied on discontinuities, such as growing cracks. This paper proposes a bond damage model within peridynamics to treat the nucleation and growth of cracks due to cyclic loading. Bond damage occurs according to the evolution of a variable called the %22remaining life%22 of each bond that changes over time according to the cyclic strain in the bond. It is shown that the model reproduces the main features of S-N data for typical materials and also reproduces the Paris law for fatigue crack growth. Extensions of the model account for the effects of loading spectrum, fatigue limit, and variable load ratio. A three-dimensional example illustrates the nucleation and growth of a helical fatigue crack in the torsion of an aluminum alloy rod.

Silling, Stewart A.; Abe Askari (Boeing)

2014-10-01T23:59:59.000Z

117

Key Distillation and the Secret-Bit Fraction  

E-Print Network [OSTI]

We consider distillation of secret bits from partially secret noisy correlations P_ABE, shared between two honest parties and an eavesdropper. The most studied distillation scenario consists of joint operations on a large number of copies of the distribution (P_ABE)^N, assisted with public communication. Here we consider distillation with only one copy of the distribution, and instead of rates, the 'quality' of the distilled secret bits is optimized, where the 'quality' is quantified by the secret-bit fraction of the result. The secret-bit fraction of a binary distribution is the proportion which constitutes a secret bit between Alice and Bob. With local operations and public communication the maximal extractable secret-bit fraction from a distribution P_ABE is found, and is denoted by Lambda[P_ABE]. This quantity is shown to be nonincreasing under local operations and public communication, and nondecreasing under eavesdropper's local operations: it is a secrecy monotone. It is shown that if Lambda[P_ABE]>1/2 then P_ABE is distillable, thus providing a sufficient condition for distillability. A simple expression for Lambda[P_ABE] is found when the eavesdropper is decoupled, and when the honest parties' information is binary and the local operations are reversible. Intriguingly, for general distributions the (optimal) operation requires local degradation of the data.

Nick S. Jones; Lluis Masanes

2008-05-12T23:59:59.000Z

118

Process for removing naphthenic acids from petroleum distillates  

SciTech Connect (OSTI)

A liquid extraction process is described for removing naphthenic acids from naphthenic acid containing petroleum distillates boiling within the range of about 180/sup 0/-600/sup 0/C. and having an acid number of at least about 0.2 which process comprises the steps of: (a) intimately contacting the petroleum distillates with a solvent consisting essentially of methanol, water, and about from 2-20 wt. % ammonia and having a methanol: water ratio in the range of about from 0.2 to 3 parts by weight of methanol per part by weight of water and using an ammonia to petroleum distillate ratio of about 0.1-1 part by weight of ammonia per 100 parts by weight of the petroleum distillate. This selectively extracts the naphthenic acids into the solvent and yielding an immiscible two-phase liquid mixture, one of which is naphthenic acid-rich solvent phase and the other of which is a substantially napthenic acid-free petroleum distillate phase; and (b) separating and respectively recovering the naphtenic acid-rich solvent phase and petroleum distillate phase.

Danzik, M.

1987-01-06T23:59:59.000Z

119

Cracking behavior of cored structures  

SciTech Connect (OSTI)

The effects of compositional gradients, are considered based on a thermodynamic analysis, referred to as the Cahn-Hillard analysis, which describes the degree to which a local surface energy is modified by the presence of a composition gradient. The analysis predicts that both ductile and brittle fracture mechanisms are enhanced by the presence of a composition gradient. Data on stress corrosion cracking and fatigue crack growth in selected FCC alloys are used to illustrate the significance of microsegregation on mechanical properties.

Wahid, A.; Olson, D.L.; Matlock, D.K. (Colorado School of Mines, Golden, CO (United States). Center for Welding and Joining Research); Kelly, T.J. (General Electric Aircraft Engines, Evendale, OH (United States))

1991-01-01T23:59:59.000Z

120

Recover heat from steam reforming  

SciTech Connect (OSTI)

Steam reforming is one of the most important chemical processes--it is used in the manufacture of ammonia, hydrogen, methanol, and many chemicals made from hydrogen and carbon monoxide. Furthermore, many current trends will increase its importance. For example, methanol for addition to gasoline is likely to be produced by steam reforming. Because steam reforming occurs at high temperatures--typically 750 C--900 C--it generates a large amount of waste heat. Clearly, heat recovery is crucial to process economics. A typical 50,000 Nm[sup 3]/h hydrogen plant using natural gas feed has a radiant heat duty of about 50 MW. At a radiant efficiency of 50% and fuel cost of $3/GJ, this means that the reformer fires $9 million worth of fuel per year. Obviously, this amount of fuel justifies a close loot at ways to reduce costs. This article first provides a brief overview of steam reforming. It then outlines the available heat-recovery options and explains how to select the best method.

Fleshman, J.D. (Foster Wheeler USA Corp., Livingston, NJ (United States))

1993-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Method of steam reforming methanol to hydrogen  

DOE Patents [OSTI]

The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA)

1990-01-01T23:59:59.000Z

122

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network [OSTI]

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

123

Crack propagation driven by crystal growth  

SciTech Connect (OSTI)

Crystals that grow in confinement may exert a force on their surroundings and thereby drive crack propagation in rocks and other materials. We describe a model of crystal growth in an idealized crack geometry in which the crystal growth and crack propagation are coupled through the stress in the surrounding bulk solid. Subcritical crack propagation takes place during a transient period, which may be very long, during which the crack velocity is limited by the kinetics of crack propagation. When the crack is sufficiently large, the crack velocity becomes limited by the kinetics of crystal growth. The duration of the subcritical regime is determined by two non-dimensional parameters, which relate the kinetics of crack propagation and crystal growth to the supersaturation of the fluid and the elastic properties of the surrounding material.

A. Royne; Paul Meaking; A. Malthe-Sorenssen; B. Jamtveit; D. K. Dysthe

2011-10-01T23:59:59.000Z

124

Kinetics and thermodynamics of hydrotreating synthetic middle distillates  

SciTech Connect (OSTI)

Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

1987-04-01T23:59:59.000Z

125

Nonlinear structural crack growth monitoring  

DOE Patents [OSTI]

A method and apparatus are provided for the detection, through nonlinear manipulation of data, of an indicator of imminent failure due to crack growth in structural elements. The method is a process of determining energy consumption due to crack growth and correlating the energy consumption with physical phenomena indicative of a failure event. The apparatus includes sensors for sensing physical data factors, processors or the like for computing a relationship between the physical data factors and phenomena indicative of the failure event, and apparatus for providing notification of the characteristics and extent of such phenomena.

Welch, Donald E. (Oak Ridge, TN); Hively, Lee M. (Philadelphia, TN); Holdaway, Ray F. (Clinton, TN)

2002-01-01T23:59:59.000Z

126

Cracking Resistance of Asphalt Rubber Mix Versus  

E-Print Network [OSTI]

. crack length curve for KR #12;Load vs. CMOD 0.0 0.5 1.0 1.5 2.0 Crack mouth opening, mm 0 500 1000 1500 non-linear fracture mechanics ·Compliance approach ·R-Curve approach #12;Conventional Fatigue Testing factor R-Curve approach Resistance to initiation & growth of cracks Evaluates fracture toughness

Mobasher, Barzin

127

Original article Stem cracks in Norway spruce  

E-Print Network [OSTI]

Original article Stem cracks in Norway spruce in southern Scandinavia: causes and consequences Garpenberg, Sweden (Received 1st September 1992; accepted 17 June 1993) Summary — Stem cracks in Norway;INTRODUCTION Background During this century, the widespread crack- ing of Norway spruce (Picea abies L Karst

Boyer, Edmond

128

Plasma-catalyzed fuel reformer  

DOE Patents [OSTI]

A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

2013-06-11T23:59:59.000Z

129

Table A3. Refiner/Reseller Prices of Distillate and Residual...  

Gasoline and Diesel Fuel Update (EIA)

A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

130

Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump  

E-Print Network [OSTI]

(Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

Skogestad, Sigurd

131

ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried  

E-Print Network [OSTI]

. Physical properties . Protein . Twin-screw extruder Introduction As a consequence of changes in energyORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced

132

Rigorous Synthesis and Simulation of Complex Distillation Networks  

E-Print Network [OSTI]

energy-efficient distillation net- works. Complex column networks have substantial potential for energy- thesizing such complex energy-efficient networks. A robust feasibility criterion drives the selection foundations of se st in exploring energy-efficient distillatin exploring energy-efficient distillat ave

Linninger, Andreas A.

133

Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements  

E-Print Network [OSTI]

Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

Skogestad, Sigurd

134

Solar Ethanol Distillation Oara Neumann,1,3  

E-Print Network [OSTI]

requiring no energy input by conventional sources, with the potential to replace, or significantly reduce-harvesting nanoparticles that capture solar energy for direct liquid-vapor conversion, eliminating the energy O-9 Solar Ethanol Distillation Oara Neumann,1,3 Albert D. Neumann,2 Julius Müller,1

135

Steam reforming utilizing high activity catalyst  

SciTech Connect (OSTI)

High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

Setzer, H. J.

1985-03-05T23:59:59.000Z

136

Environmentally assisted cracking of LWR materials  

SciTech Connect (OSTI)

Research on environmentally assisted cracking (EAC) of light water reactor materials has focused on (a) fatigue initiation in pressure vessel and piping steels, (b) crack growth in cast duplex and austenitic stainless steels (SSs), (c) irradiation-assisted stress corrosion cracking (IASCC) of austenitic SSs, and (d) EAC in high- nickel alloys. The effect of strain rate during different portions of the loading cycle on fatigue life of carbon and low-alloy steels in 289{degree}C water was determined. Crack growth studies on wrought and cast SSs have been completed. The effect of dissolved-oxygen concentration in high-purity water on IASCC of irradiated Type 304 SS was investigated and trace elements in the steel that increase susceptibility to intergranular cracking were identified. Preliminary results were obtained on crack growth rates of high-nickel alloys in water that contains a wide range of dissolved oxygen and hydrogen concentrations at 289 and 320{degree}C. The program on Environmentally Assisted Cracking of Light Water Reactor Materials is currently focused on four tasks: fatigue initiation in pressure vessel and piping steels, fatigue and environmentally assisted crack growth in cast duplex and austenitic SS, irradiation-assisted stress corrosion cracking of austenitic SSs, and environmentally assisted crack growth in high-nickel alloys. Measurements of corrosion-fatigue crack growth rates (CGRs) of wrought and cast stainless steels has been essentially completed. Recent progress in these areas is outlined in the following sections.

Chopra, O.K.; Chung, H.M.; Kassner, T.F.; Shack, W.J.

1995-12-01T23:59:59.000Z

137

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

138

Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units  

E-Print Network [OSTI]

, Pennsylvania 15213, United States. Crude-oil assays, Distillation, Fractionation, Swing-cuts, Temperature cut with in the nonlinear optimization. 1. INTRODUCTION Distillation or fractionation models for planning and scheduling1 Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units Brenno

Grossmann, Ignacio E.

139

Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating  

E-Print Network [OSTI]

Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating Vidar the unexpected result that over-fractionating one of the product streams in a Petlyuk distillation column may is optimal in some cases. 1. Introduction The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator

Skogestad, Sigurd

140

Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel  

E-Print Network [OSTI]

into a number of product fractions in a single batch column whereas, in continuous distillation several columnsIntegrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum-boiling azeotropic mixtures, where the extractive agent

Skogestad, Sigurd

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Model predictive control of a pilot-scale distillation column using a programmable automation controller  

E-Print Network [OSTI]

Model predictive control of a pilot-scale distillation column using a programmable automation). The controller is tested on a pilot-scale binary distillation column to track reference temperatures. A majorRIO) to control a pilot-scale binary distillation col- umn. Both the PI-controllers and the supervising online MPC

142

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security Reform  

E-Print Network [OSTI]

Lessons Learned from Prior Attempts at National Security Reform The Project on National Security was their solution effective? 4. What implications for present-day reformers can be drawn from this reform? Lessons learned from each chapter are summarized at the end of each section, and a synthesis of these findings

Lewis, Robert Michael

143

Hydrogen from Biomass by Autothermal Reforming  

Broader source: Energy.gov [DOE]

Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

144

Distributed Bio-Oil Reforming (Presentation)  

SciTech Connect (OSTI)

This presentation by Bob Evans at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's distributed bio-oil reforming efforts.

Evans, R. J.; Czernik, S.; French, R.; Ratcliff, M.; Marda, J.; Dean, A. M.

2007-05-15T23:59:59.000Z

145

Comparative case studies of health reform in England  

E-Print Network [OSTI]

Comparative case studies of health reform in England Report submitted to the Department of Health........................................................................................14 1.1 Presenting the Health System Reform policy agenda...................................14 1 ..........................................................................................64 Demand Side Reform.........................................

Birmingham, University of

146

Apparatus for production of synthesis gas using convective reforming  

SciTech Connect (OSTI)

This patent describes a system for the steam reforming of hydrocarbons into a hydrogen-rich gas. It comprises a convective reformer device having indirect heat exchange means for partially reforming a feed mixture of hydrocarbons and steam; a steam reforming furnace having a radiant section, reforming tubes in the radiant section, and means for producing radiant heat for the further reforming of the partially reformed effluent; an auto-thermal reformer for fully reforming the effluent; conduit means for passing the partially reformed effluent; conduit means for passing the effluent; and conduit means for passing the fully reformed effluent to supply the heat of reaction for the partial reformation of the hydrocarbon-steam feed mixture.

Karafian, M.; Tsang, I.C.

1991-04-09T23:59:59.000Z

147

Solid oxide fuel cell steam reforming power system  

DOE Patents [OSTI]

The present invention is a Solid Oxide Fuel Cell Reforming Power System that utilizes adiabatic reforming of reformate within this system. By utilizing adiabatic reforming of reformate within the system the system operates at a significantly higher efficiency than other Solid Oxide Reforming Power Systems that exist in the prior art. This is because energy is not lost while materials are cooled and reheated, instead the device operates at a higher temperature. This allows efficiencies higher than 65%.

Chick, Lawrence A.; Sprenkle, Vincent L.; Powell, Michael R.; Meinhardt, Kerry D.; Whyatt, Greg A.

2013-03-12T23:59:59.000Z

148

Cascading of fluid cracking catalysts  

SciTech Connect (OSTI)

A process is described for conversion of hydrocarbon feedstocks by cascading a cracking catalyst containing zeolite in an acidic matrix from one hydrocarbon processing unit to another, wherein there are at least three different interconnected hydrocarbon processing units comprising a first unit having a regeneration zone and a riser zone, a second unit having having a regeneration zone and a riser zone, and a third unit having a riser zone and a regeneration zone, each unit having different processing conditions.

Kovach, S.M.; Miller, C.B.

1986-05-27T23:59:59.000Z

149

Stiffness reduction and stress transfer in composite laminates with transverse matrix cracks  

E-Print Network [OSTI]

-staggered cracking. Laminates with staggered cracks showed a greater reduction in effective modulus at lower crack densities. The crack opening displacements at different crack densities were normalized in a way as to compare with the solution for an isolated crack...

Praveen, Grama Narasimhaprasad

2012-06-07T23:59:59.000Z

150

Design, Modeling, and Validation of a Flame Reformer for LNT...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration Design, Modeling, and Validation of a Flame Reformer for LNT External Bypass Regeneration...

151

Regulatory and Financial Reform of Federal Research Policy: Recommenda...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy:...

152

Secretary Moniz to Present Project Management Reforms to the...  

Energy Savers [EERE]

Moniz to Present Project Management Reforms to the National Academy of Public Administration Secretary Moniz to Present Project Management Reforms to the National Academy of Public...

153

Diesel Reforming for Fuel Cell Auxiliary Power Units  

SciTech Connect (OSTI)

This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

2005-01-27T23:59:59.000Z

154

Hydrogen generation from plasmatron reformers and use for diesel...  

Broader source: Energy.gov (indexed) [DOE]

Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003...

155

Comparative Investigation of Benzene Steam Reforming over Spinel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts....

156

Enabling Informed Adaptation of Reformed Instructional Materials  

E-Print Network [OSTI]

Enabling Informed Adaptation of Reformed Instructional Materials Rachel E. Scherr and Andrew Elby 20742 USA Abstract. Instructors inevitably need to adapt even the best reform materials to suit instructors, and video clips of students working on the materials. Our materials thus facilitate their own

Elby, Andy

157

Fuel cell integrated with steam reformer  

DOE Patents [OSTI]

A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

1987-01-01T23:59:59.000Z

158

Reformate Cleanup: The Case for Microchannel Architecture  

E-Print Network [OSTI]

Reformate Cleanup: The Case for Microchannel Architecture DOE Hydrogen and Fuel Cells 2003 Annual for MicrochannelMicrochannel ArchitectureArchitecture DOE Hydrogen and Fuel CellsDOE Hydrogen and Fuel Cells 2003, controls Integrated reformer/fuel cell demonstration at ~2 kWeFY 2002 WGS/PROX catalyst studies

159

Methanol Steam Reformer on a Silicon Wafer  

SciTech Connect (OSTI)

A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

2004-04-15T23:59:59.000Z

160

Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation  

SciTech Connect (OSTI)

A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

Garg, D.

1986-08-19T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Reactive Distillation for Esterification of Bio-based Organic Acids  

SciTech Connect (OSTI)

The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

2008-09-23T23:59:59.000Z

162

Enhanced Separation Efficiency in Olefin/Paraffin Distillation  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

163

"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering  

E-Print Network [OSTI]

distillation · Underwood (1946, 1948a,b), Fractional distillation of multicomponent mixtures · Shiras (1950"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science

Skogestad, Sigurd

164

Combustion in cracks of PBX 9501  

SciTech Connect (OSTI)

Recent experiments involving the combustion of PBX 9501 explosive under confined conditions reveal the importance of crack and flaws in reaction violence. Experiments on room temperature confined disks of pristine and thermally damaged PBX 9501 reveal that crack ignition depends on hot gases entering existing or pressure induced cracks rather than on energy release at the crack tip. PBX 9501 slot combustion experiments show that the reaction propagation rate in the slot does not depend on the external pressure. We have observed 1500 d s in long slots of highly-confined PBX 9501. We present experiments that examine the combustion of mechanically and thermally damaged samples of PBX 9501.

Berghout, H. L. (Henry L.); Son, S. F. (Steven F.); Bolme, C. A. (Cynthia A.); Hill, L. G. (Larry G.); Asay, B. W. (Blaine W.); Dickson, P. M. (Peter M.); Henson, B. F. (Bryan F.); Smilowitz, L. B. (Laura B.)

2002-01-01T23:59:59.000Z

165

Biomaterials 24 (2003) 52095221 Crack blunting, crack bridging and resistance-curve fracture  

E-Print Network [OSTI]

Biomaterials 24 (2003) 5209­5221 Crack blunting, crack bridging and resistance-curve fracture focused on a description of the fracture toughness properties of dentin in terms of resistance-curve (R-curve) behavior, i.e., fracture resistance increasing with crack extension, particularly in light of the relevant

Ritchie, Robert

166

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA  

E-Print Network [OSTI]

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA Jeffrey Sachs ABSTRACT: The paper reviews the experience of Poland and Russia with economic reform, with occasional comparison to China's experience. The author argues that macroeconomic chaos in Poland and Russia preceded reform and was allayed by reform

167

September 25, 2013 AFSCME Continues to Object to Pension Reform;  

E-Print Network [OSTI]

September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

Leistikow, Bruce N.

168

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH  

E-Print Network [OSTI]

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH Cecilia TESTA London School of Economics are a reform and a compensating taxation. The main feature of the reform is that it creates gainers and losers on tax parameters. keywords: reform, lobbying, redistribution, economic welfare. 1 #12;Introduction

Royal Holloway, University of London

169

Diesel Reforming for Solid Oxide Fuel Cell Application  

SciTech Connect (OSTI)

This presentation discusses the development of a diesel reforming catalyst and catalytic system development.

Liu, D-J.; Sheen, S-H.; Krumpelt, M.

2005-01-27T23:59:59.000Z

170

Electricity reform in developing and transition countries: A reappraisal  

E-Print Network [OSTI]

Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

Kammen, Daniel M.

171

Internal reforming fuel cell assembly with simplified fuel feed  

DOE Patents [OSTI]

A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

2001-01-01T23:59:59.000Z

172

Characterization of Fatigue Cracking and Healing of Asphalt Mixtures  

E-Print Network [OSTI]

Fatigue cracking is one of the most common distresses of asphalt pavements, whereas healing is a counter process to cracking which alleviates cracking damage and extends fatigue life of asphalt pavements. Most of existing methods to characterize...

Luo, Xue

2012-07-16T23:59:59.000Z

173

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

174

Development of crack shape: LBB methodology for cracked pipes  

SciTech Connect (OSTI)

For structures like vessels or pipes containing a fluid, the Leak-Before-Break (LBB) assessment requires to demonstrate that it is possible, during the lifetime of the component, to detect a rate of leakage due to a possible defect, the growth of which would result in a leak before-break of the component. This LBB assessment could be an important contribution to the overall structural integrity argument for many components. The aim of this paper is to review some practices used for LBB assessment and to describe how some new R & D results have been used to provide a simplified approach of fracture mechanics analysis and especially the evaluation of crack shape and size during the lifetime of the component.

Moulin, D.; Chapuliot, S.; Drubay, B. [Commissariat a l Energie Atomique, Gif sur Yvette (France)

1997-04-01T23:59:59.000Z

175

Crack shape developments and leak rates for circumferential complex-cracked pipes  

SciTech Connect (OSTI)

A computerized procedure has been developed that predicts the growth of an initial circumferential surface crack through a pipe and further on to failure. The crack growth mechanism can either be fatigue or stress corrosion. Consideration is taken to complex crack shapes and for the through-wall cracks, crack opening areas and leak rates are also calculated. The procedure is based on a large number of three-dimensional finite element calculations of cracked pipes. The results from these calculations are stored in a database from which the PC-program, denoted LBBPIPE, reads all necessary information. In this paper, a sensitivity analysis is presented for cracked pipes subjected to both stress corrosion and vibration fatigue.

Brickstad, B.; Bergman, M. [SAQ Inspection Ltd., Stockholm (Sweden)

1997-04-01T23:59:59.000Z

176

SciTech Connect: CRACK TIP PLASTICITY AND FRACTURE INITIATION...  

Office of Scientific and Technical Information (OSTI)

N50000* --Metals, Ceramics, & Other Materials; CRACKS; FRACTURE PROPERTIES; METALS BUILDING MATERIALSfracture of metal, crack tip plasticity and initiation criteria for;...

177

Life prediction for bridged fatigue cracks  

SciTech Connect (OSTI)

One of the more promising classes of composites touted for high temperature applications, and certainly the most available, is that of relatively brittle matrices, either ceramic or intermetallic, reinforced by strong, aligned, continuous fibers. Under cyclic loading in the fiber direction, these materials develop matrix cracks that often run perpendicular to the fibers, while the fibers remain intact in the crack wake, supplying bridging tractions across the fracture surfaces. The bridging tractions shield the crack tip from the applied load, dramatically reducing the crack velocity from that expected in an unreinforced material subjected to the same value, {Delta}K{sub a}, of the cyclic applied stress intensity factor. An important issue in reliability is the prediction of the growth rates of the bridged cracks. The growth rates of matrix fatigue cracks bridged by sliding fibers are now commonly predicted by models based on the micromechanics of frictional interfaces. However, there exist many reasons, both theoretical and experimental, for suspecting that the most popular micromechanical models are probably wrong in detail in the context of fatigue cracks. Furthermore, a review of crack growth data reveals that the validity of the micromechanics-based predictive model has never been tested and may never be tested. In this paper, two alternative approaches are suggested to the engineering problem of predicting the growth rates of bridged cracks without explicit recourse to micromechanics. Instead, it is shown that the material properties required to analyze bridging effects can be deduced directly from crack growth data. Some experiments are proposed to test the validity of the proposals.

Cox, B.N.

1994-08-01T23:59:59.000Z

178

Heat Recovery in Distillation by Mechanical Vapor Recompression  

E-Print Network [OSTI]

matc~ can be made between low-grade waste energy sourc~s and process uses, thereby improving plant energ~ efficiency. I A relatively high rate of return on invest-JI ment is expected in most cases. The optimum op, erating conditions are dictated...," Chem. Eng. Prog., Vol. 76:7, pp. 44-49, July 1980. I 2. Anon, "Di,stillation Prime Target for Energ~ Conservation," Oil & Gas Journal, Vol. 76:~6, pp. 92-94, April 17, 1978. I 3. W. F. Kenne'y, "Reducing the Energy Demand o~ Separation Processes...

Becker, F. E.; Zakak, A. I.

179

Multiple steady states during reactive distillation of methyl tert-butyl ether  

SciTech Connect (OSTI)

This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

1993-11-01T23:59:59.000Z

180

Electrical Generation Tax Reform Act (Montana)  

Broader source: Energy.gov [DOE]

This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the Montana electric utility industry that allows...

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Electricity reform abroad and US investment  

SciTech Connect (OSTI)

This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

NONE

1997-10-01T23:59:59.000Z

182

Device for cooling and humidifying reformate  

DOE Patents [OSTI]

Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

2008-04-08T23:59:59.000Z

183

E-Print Network 3.0 - assessing welfare reform Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reventionscience.umn.edu Summary: , poverty, welfare reform, school reform, and health- care reform. An emphasis is given to large... , and dissemination of a variety of programs...

184

E-Print Network 3.0 - advanced distillation curve Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

58 (2003) 26712680 www.elsevier.comlocateces Summary: distillation: Advanced simulation and experimental validation. Computers and Chemical Engineering, 22, S371-S......

185

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Gasoline and Diesel Fuel Update (EIA)

Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

186

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Gasoline and Diesel Fuel Update (EIA)

Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

187

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

U.S. Energy Information Administration (EIA) Indexed Site

Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

188

Table A3. Refiner/Reseller Prices of Distillate and Residual...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

189

E-Print Network 3.0 - atmospheric crude distillation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Problems Summary: and atmospheric distillations of crude-oil mixtures from charging tanks. The crude is then processed in order... of resources: crude marine vessels, storage...

190

Development of a Fuzzy Logic Controller for a Distillation Column using Rockwell Software .  

E-Print Network [OSTI]

??In this thesis, an alternative control method based on Fuzzy Inference System (FIS) is proposed to keep the product composition of a distillation column constant.… (more)

Nizami, Muhammad

2011-01-01T23:59:59.000Z

191

Liquid fuel reformer development: Autothermal reforming of Diesel fuel  

SciTech Connect (OSTI)

Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

2000-07-24T23:59:59.000Z

192

Early stages in the development of stress corrosion cracks  

SciTech Connect (OSTI)

Processes in growth of short cracks and stage I of long stress corrosion cracks were identified and evaluated. There is evidence that electrochemical effects can cause short stress corrosion cracks to grow at rates faster or slower than long cracks. Short cracks can grow at faster rates than long cracks for a salt film dissolution growth mechanism or from reduced oxygen inhibition of hydrolytic acidification. An increasing crack growth rate with increasing crack length could result from a process of increasing crack tip concentration of a critical anion, such as Cl{sup {minus}}, with increasing crack length in a system where the crack velocity is dependent on the Cl{sup {minus}} or some other anion concentration. An increasing potential drop between crack tip and mouth would result in an increased anion concentration at the crack tip and hence an increasing crack velocity. Stage I behavior of long cracks is another early development stage in the life of a stress corrosion crack which is poorly understood. This stage can be described by da/dt = AK{sup m} where da/dt is crack velocity, A is a constant, K is stress intensity and m ranges from 2 to 24 for a variety of materials and environments. Only the salt film dissolution model was found to quantitatively describe this stage; however, the model was only tested on one material and its general applicability is unknown.

Jones, R.H.; Simonen, E.P.

1993-12-01T23:59:59.000Z

193

Perspective: The road to reform  

SciTech Connect (OSTI)

The rapid transformation underway in the utility industry provides ample evidence that the reality of the Energy Policy Act of 1992 is sinking in. This law reflected Congress's conclusion that competition in wholesale power generation-at the plant busbar-is a demonstrable reality. It expressed the vision of a fully competitive wholesale generation market, with suppliers linked to markets through a grid that would provide service on a nondiscriminatory basis. But will consumers reap the full benefits of effective competition at the wholesale generation level Or will more disorderly forms of competition emerge, reflecting a hybrid of deregulation and old-fashioned monopoly tactics Along the latter course we run the risk of cost shifts among customer classes, customer defections, diminished utility cooperation, and higher overall costs to society. In short, the vision of a competitive market in wholesale generation will not come about without thoughtful efforts at defining the relevant market, as well as careful attention to the management of a difficult transition away from outmodes mindsets and regulatory models. As a national trade association representing independent power producers (IPPs) and suppliers of goods and services to the competitive wholesale electric generation industry, the Electric Generation Association (EGA) believes that constructive dialogue will yield the best approach to managing this difficult process of transition. In that spirit, the EGA Emerging Operational Issues Committee recently released a while paper, [open quotes]Electrifying Change: Strategies for Structural Reform in the Electric Industry,[close quotes] which forms the basis for this article.

Howe, J.B. (J. Makowski Associates Inc., Boston, MA (United States))

1994-04-01T23:59:59.000Z

194

Hydrogen generation utilizing integrated CO2 removal with steam reforming  

DOE Patents [OSTI]

A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

Duraiswamy, Kandaswamy; Chellappa, Anand S

2013-07-23T23:59:59.000Z

195

Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column  

E-Print Network [OSTI]

Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column how the minimum energy consumption is related to the feed-component distribution for all possible operating points in a two-product distillation column with a multicomponent feed. The classical Underwood

Skogestad, Sigurd

196

Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products and Generalized Petlyuk Arrangements  

E-Print Network [OSTI]

Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products-component feed into M products has been derived. Interestingly, the minimum-energy solution in a complex solution of minimum energy for distillation of a multicomponent feed into multiple products has not been

Skogestad, Sigurd

197

Study of the Distillability of Werner States Using Entanglement Witnesses and Robust Semidefinite Programs  

E-Print Network [OSTI]

We use Robust Semidefinite Programs and Entanglement Witnesses to study the distillability of Werner states. We perform exact numerical calculations which show 2-undistillability in a region of the state space which was previously conjectured to be undistillable. We also introduce bases which yield interesting expressions for the {\\em distillability witnesses} and for a tensor product of Werner states with arbitrary number of copies.

Reinaldo O. Vianna; Andrew C. Doherty

2006-08-11T23:59:59.000Z

198

Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation  

E-Print Network [OSTI]

Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation · The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator (C1) and a main column (C21 and C22) N-7465 Trondheim, Norway Abstract This work shows the unexpected result that over-fractionating one

Skogestad, Sigurd

199

Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)  

E-Print Network [OSTI]

coupling 1. Introduction Separation by distillation is responsible for a large fraction of immense amountDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved indicated that a 15 component aromatic's mixture can be separated very efficiently into four fractions

Skogestad, Sigurd

200

Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**  

E-Print Network [OSTI]

that handle more than 90% of separations and purifications. The capital investment for these distillation.87 million TJ) per year, or to a power consumption of 91 GW, or 54 million tons of crude oil. Distillation conditions to minimize the total investment and operating cost. Continuous decisions are related

Grossmann, Ignacio E.

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Catalytic cracking of residual petroleum fractions  

SciTech Connect (OSTI)

This paper reports on Arabian Light crude oil vacuum bottoms fractionated into five high-boiling fractions by wiped film evaporation, and the fractions subjected to catalytic cracking in a fixed-fluidized bed using a commercial equilibrium cracking catalyst. Density, aromaticity, and heteroatom content generally increased with boiling point, as did metals content except for vanadium and iron which demonstrated possible bimodal distributions. The cracking response of these fractions showed increasing yields of dry gas and coke, with decreasing gasoline yields, as a function of increasing apparent boiling point as would normally be expected. Surprisingly, however, local maxima were observed for wet gas yield and total conversion, with local minima for cycle oil and slurry yields, in the region of the 1200-1263{degrees}F (650-680{degrees}C) middle fraction. All fractions showed significant response to cracking, with coke yields generally being the only negative factor observed.

Moore, H.F.; Mayo, S.L.; Goolsby, T.L. (Research and Development Dept., Ashland Petroleum Co., Ashland, KY (US))

1991-01-01T23:59:59.000Z

202

Parallel interacting edge cracks under pure bending  

E-Print Network [OSTI]

. Once the applicability of the Williams' equations, have been proved or disproved, the power of the singularity represented by the first term of equation 1. 1 and the polynomial expansion can be truncated in order to extract information... of Williams' approach for the case of cracked bodies under pure bending is demonstrated. Four point bending load is applied on specimens with either a vertical or a slant crack giving Mode I or Mixed Mode I ? II respectively. The existence...

Moran, Ivan

1991-01-01T23:59:59.000Z

203

Studies on fruit cracking of tomatoes  

E-Print Network [OSTI]

STUDIES ON FRUIT CRACKING OF TOMATOES A Thesis Sam Don Cotner Submitted to the Graduate College of' ths Texas A&M University in partial fulfillment of the requirements i' or the degree of MASTER OF SCIENCE January~ 1966 Major Subject...: Horticulture STUDlES ON FRUIT CRACKING OF TOMATOES A Thesis Sam Dcn Cotnsr Approved as to style and content by; (Chairman of tes Member (Head o Department) mbsr) January 1966 TABLE OF CONTENTS Chapter I. INTRODUCTION . II. REVIEW OF LITERATURE Page...

Cotner, Sam Don

1966-01-01T23:59:59.000Z

204

Low Cost Autothermal Diesel Reforming Catalyst Development  

SciTech Connect (OSTI)

Catalytic autothermal reforming (ATR) represents an important step of converting fossil fuel to hydrogen rich reformate for use in solid oxide fuel cell (SOFC) stacks. The state-of-the-art reforming catalyst, at present, is a Rh based material which is effective but costly. The objective of our current research is to reduce the catalyst cost by finding an efficient ATR catalyst containing no rhodium. A group of perovskite based catalysts have been synthesized and evaluated under the reforming condition of a diesel surrogate fuel. Hydrogen yield, reforming efficiency, and conversion selectivity to carbon oxides of the catalyst ATR reaction are calculated and compared with the benchmark Rh based material. Several catalyst synthesis improvements were carried out including: 1) selectively doping metals on the A-site and B-site of the perovskite structure, 2) changing the support from perovskite to alumina, 3) altering the method of metal addition, and 4) using transition metals instead of noble metals. It was found that the catalytic activity changed little with modification of the A-site metal, while it displayed considerable dependence on the B-site metal. Perovskite supports performed much better than alumina based supports.

Shihadeh, J.; Liu, D.

2004-01-01T23:59:59.000Z

205

Electricity reform in Chile : lessons for developing countries  

E-Print Network [OSTI]

Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. ...

Pollitt, Michael G.

2004-01-01T23:59:59.000Z

206

The Effect of Welfare Reform on Childbirth, Marriage, and Divorce  

E-Print Network [OSTI]

This dissertation contains two essays on the effect of welfare reform on child- birth, marriage, and divorce. In the first essay, I exploit the cross state variation in welfare reform implementation to identify its effect on birth rates. The results...

Pakdeethai, Pimrak

2010-10-12T23:59:59.000Z

207

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION?  

E-Print Network [OSTI]

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION? David Watts Paulo Atienza to participate. Chile was the pioneer introducing this kind of reforms, through the application of a centralized

Catholic University of Chile (Universidad Católica de Chile)

208

How Did Health Care Reform in Massachusetts Impact Insurance Premiums?  

E-Print Network [OSTI]

It is widely recognized that the 2006 Massachusetts health reforms served as a blueprint for national reform under the 2010 Affordable Care Act (ACA). As such, there is interest in using the Massachusetts experience to ...

Graves, John A.

209

MORE HEALTH CARE REFORM By Victor R. Fuchs  

E-Print Network [OSTI]

MORE HEALTH CARE REFORM By Victor R. Fuchs #12;2 | MORE HEALTH CARE REFORM The Robert Wood Johnson?................................................................................... 8 Government Payment for Health Care -- Causes and Consequences....................................................................................................................................................................................... 16 Health Care Is Different -- That's Why Expenditures Matter

Zalta, Edward N.

210

Pyrochlore catalysts for hydrocarbon fuel reforming  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

2012-08-14T23:59:59.000Z

211

Thermally integrated staged methanol reformer and method  

DOE Patents [OSTI]

A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

2001-01-01T23:59:59.000Z

212

Recent evaluations of crack-opening-area in circumferentially cracked pipes  

SciTech Connect (OSTI)

Leak-before-break (LBB) analyses for circumferentially cracked pipes are currently being conducted in the nuclear industry to justify elimination of pipe whip restraints and jet shields which are present because of the expected dynamic effects from pipe rupture. The application of the LBB methodology frequently requires calculation of leak rates. The leak rates depend on the crack-opening area of the through-wall crack in the pipe. In addition to LBB analyses which assume a hypothetical flaw size, there is also interest in the integrity of actual leaking cracks corresponding to current leakage detection requirements in NRC Regulatory Guide 1.45, or for assessing temporary repair of Class 2 and 3 pipes that have leaks as are being evaluated in ASME Section XI. The objectives of this study were to review, evaluate, and refine current predictive models for performing crack-opening-area analyses of circumferentially cracked pipes. The results from twenty-five full-scale pipe fracture experiments, conducted in the Degraded Piping Program, the International Piping Integrity Research Group Program, and the Short Cracks in Piping and Piping Welds Program, were used to verify the analytical models. Standard statistical analyses were performed to assess used to verify the analytical models. Standard statistical analyses were performed to assess quantitatively the accuracy of the predictive models. The evaluation also involved finite element analyses for determining the crack-opening profile often needed to perform leak-rate calculations.

Rahman, S.; Brust, F.; Ghadiali, N.; Wilkowski, G.; Miura, N.

1997-04-01T23:59:59.000Z

213

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation  

E-Print Network [OSTI]

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation September 2012 1 Ofqual: A Level Reform Consultation Response by the Wellcome Trust September 2012 Key Points National Subject to university. We are therefore pleased to respond to this consultation on reforming A levels. Our comments

Rambaut, Andrew

214

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com  

E-Print Network [OSTI]

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com On March 23, President Obama signed is tracking the myriad other developments of the new health reform law. You can find a wide range of related material, including enacting language, implementing documents, and analysis through the Health Reform

Chapman, Michael S.

215

Preliminary and incomplete A Modest Proposal for International Monetary Reform  

E-Print Network [OSTI]

Preliminary and incomplete A Modest Proposal for International Monetary Reform International Columbia University #12;- 1 - - 1 - #12;- 2 - A Modest Proposal for International Monetary Reform Bruce are fundamental aspects of the present system and that, without reform, they will continue to plague the global

Grishok, Alla

216

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY  

E-Print Network [OSTI]

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY Olivier CARDI Romain RESTOUT December, 2010 REFORMS IN AN OPEN ECONOMY Olivier CARDI Universit´e Panth´eon-Assas ERMES Ecole Polytechnique Romain with traded and non traded goods to in- vestigate the sectoral effects of three tax reforms: i) two revenue

Boyer, Edmond

217

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS?  

E-Print Network [OSTI]

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS? Susie LEE Ingmar SCHUMACHER (in)stability induce financial reforms? Susie Lee1 Ingmar Schumacher2 October 26, 2011 Abstract The article studies whether financial sector (in)stability had an effect on reforms in the fi- nancial sector

Boyer, Edmond

218

the triple aim MEETING THE GOAL OF HEALTH REFORM  

E-Print Network [OSTI]

the triple aim MEETING THE GOAL OF HEALTH REFORM Produced by OHSU Strategic Communications -- emphasizing shared decision-making and coordination between providers -- could influence reform in a big way care. health reform is about getting better health outcomes for our communities, improving access

Chapman, Michael S.

219

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network [OSTI]

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high cases. #12;1 Introduction The naphtha reforming process converts low-octane gasoline blending compo-octane components for use in high-performance gasoline fuels. The reformer also has an important function

Skogestad, Sigurd

220

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect (OSTI)

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

TRANSPORT THROUGH CRACKED CONCRETE: LITERATURE REVIEW  

SciTech Connect (OSTI)

Concrete containment structures and cement-based fills and waste forms are used at the Savannah River Site to enhance the performance of shallow land disposal systems designed for containment of low-level radioactive waste. Understanding and measuring transport through cracked concrete is important for describing the initial condition of radioactive waste containment structures at the Savannah River Site (SRS) and for predicting performance of these structures over time. This report transmits the results of a literature review on transport through cracked concrete which was performed by Professor Jason Weiss, Purdue University per SRR0000678 (RFP-RQ00001029-WY). This review complements the NRC-sponsored literature review and assessment of factors relevant to performance of grouted systems for radioactive waste disposal. This review was performed by The Center for Nuclear Waste Regulatory Analyses, San Antonio, TX, and The University of Aberdeen, Aberdeen Scotland and was focused on tank closure. The objective of the literature review on transport through cracked concrete was to identify information in the open literature which can be applied to SRS transport models for cementitious containment structures, fills, and waste forms. In addition, the literature review was intended to: (1) Provide a framework for describing and classifying cracks in containment structures and cementitious materials used in radioactive waste disposal, (2) Document the state of knowledge and research related to transport through cracks in concrete for various exposure conditions, (3) Provide information or methodology for answering several specific questions related to cracking and transport in concrete, and (4) Provide information that can be used to design experiments on transport through cracked samples and actual structures.

Langton, C.

2012-05-11T23:59:59.000Z

222

E-Print Network 3.0 - axially cracked pressure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Engineering 2 MATERIAL POINT METHOD CALCULATIONS WITH EXPLICIT CRACKS, FRACTURE PARAMETERS, AND CRACK Summary: under axial impact with a crack in the central disk....

223

E-Print Network 3.0 - anomolous fatigue crack Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science ; Engineering 6 Cracking Resistance of Asphalt Rubber Mix Versus Summary: vs. Fracture Mechanics Conventional Fatigue Testing Crack initiation Fracture Mechanics Crack......

224

Fractionation studies on the unidentified growth factor(s) in distillers dried solubles  

E-Print Network [OSTI]

. This was called "methyl aloohol soluble fraction of distillers dried solublesi The residue wss air drie4 and labeled "aetna 1 alcohol insoluble fraotion of distillers drie4 solubles". $. r fo m at nt ist e i o ubl s Five hundred gm of distillexs dried... fraction ox Ms- tillers Cried solubles (pH 1)"L "water soluole fr~ction of distillers dried solubles (PH '/)"L ~ "water soluble fxaction of dis~illers dried solubles (pH 11)". ur h r Pra tionatio f th Sate 8 lub e }raut of 9 still rs ed Soluo es a...

Dannenburg, Warren Nathaniel

1955-01-01T23:59:59.000Z

225

Creep failure of cracking heater at a petrochemical plant  

SciTech Connect (OSTI)

After two and half years of operation, a bend tube in a cracking heater at an ethylene plant failed due to creep cracking. Creep damage occurred as a result of metallurgical instability including coarsening of carbides that caused softening and initiation of voids or wedge-type intergranular cracks. This was accelerated due to increasing inner surface temperature during decoking process. Thermal fatigue contributed to the failure as a result of temperature variations due to several shutdown-startup operations. To minimize such failure in futures, periodic inspection to monitor crack formation was scheduled. Nondestructive tests including dye penetrant test for surface cracking and radiographic test for internal crack were implemented.

El-Batahgy, A. [Welding Research Department, Central, Metallurgical R and D Institute, Cairo (Egypt)]. E-mail: elbatahgy@yahoo.com; Zaghloul, B. [Central Metallurgical R and D Institute, P.O. Box: 87 Helwan, Cairo (Egypt)

2005-03-15T23:59:59.000Z

226

In Njeri Wamukonya, ed., Electricity Reform  

E-Print Network [OSTI]

electricity consumption in industrial countries has caused major air pollution problems. In fact, power plants maintain that governing the electricity industry according to market dynamics, rather than socioIn Njeri Wamukonya, ed., Electricity Reform: Social and Environmental Challenges Roskilde, Denmark

Delaware, University of

227

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

228

Affordable Care Act & Medicaid Reform in Wisconsin  

E-Print Network [OSTI]

Affordable Care Act & Medicaid Reform in Wisconsin Enrollment Trends Chartpack 2013-2014 ACA Open,731 Wisconsinites Living in Poverty Access Health Care Through Medicaid," Press Release, May 19, 2014. http://walker.wi.gov/newsroom/press-release/81731-wisconsinites-living-poverty-access-health-care-through- Medicaid Medicaid & CHIP: April 2014

Sheridan, Jennifer

229

Patent Reform: Aligning Reward and Contribution  

E-Print Network [OSTI]

4 Patent Reform: Aligning Reward and Contribution Carl Shapiro, University of California the current U.S. patent system allows patent holders to capture private rewards that exceed their social with the patent system and discourage in- novation by others. Economic efficiency is promoted if rewards to patent

Sadoulet, Elisabeth

230

Environmentally assisted cracking of LWR materials.  

SciTech Connect (OSTI)

The effect of dissolved oxygen level on fatigue life of austenitic stainless steels is discussed and the results of a detailed study of the effect of the environment on the growth of cracks during fatigue initiation are presented. Initial test results are given for specimens irradiated in the Halden reactor. Impurities introduced by shielded metal arc welding that may affect susceptibility to stress corrosion cracking are described. Results of calculations of residual stresses in core shroud weldments are summarized. Crack growth rates of high-nickel alloys under cyclic loading with R ratios from 0.2-0.95 in water that contains a wide range of dissolved oxygen and hydrogen concentrations at 289 and 320 C are summarized.

Chopra, O. K.; Chung, H. M.; Kassner, T. F.; Park, J. H.; Shack, W. J.; Zhang, J.; Brust, F. W.; Dong, P.

1997-12-05T23:59:59.000Z

231

Crack detection using resonant ultrasound spectroscopy  

DOE Patents [OSTI]

Method and apparatus are provided for detecting crack-like flaws in components. A plurality of exciting frequencies are generated and applied to a component in a dry condition to obtain a first ultrasonic spectrum of the component. The component is then wet with a selected liquid to penetrate any crack-like flaws in the component. The plurality of exciting frequencies are again applied to the component and a second ultrasonic spectrum of the component is obtained. The wet and dry ultrasonic spectra are then analyzed to determine the second harmonic components in each of the ultrasonic resonance spectra and the second harmonic components are compared to ascertain the presence of crack-like flaws in the component. 5 figs.

Migliori, A.; Bell, T.M.; Rhodes, G.W.

1994-10-04T23:59:59.000Z

232

Crack detection using resonant ultrasound spectroscopy  

DOE Patents [OSTI]

Method and apparatus are provided for detecting crack-like flaws in components. A plurality of exciting frequencies are generated and applied to a component in a dry condition to obtain a first ultrasonic spectrum of the component. The component is then wet with a selected liquid to penetrate any crack-like flaws in the component. The plurality of exciting frequencies are again applied to the component and a second ultrasonic spectrum of the component is obtained. The wet and dry ultrasonic spectra are then analyzed to determine the second harmonic components in each of the ultrasonic resonance spectra and the second harmonic components are compared to ascertain the presence of crack-like flaws in the component.

Migliori, Albert (Santa Fe, NM); Bell, Thomas M. (Santa Fe, NM); Rhodes, George W. (Albuquerque, NM)

1994-01-01T23:59:59.000Z

233

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

234

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents [OSTI]

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

235

Solar reforming of methane in a direct absorption catalytic reactor on a parabolic dish  

SciTech Connect (OSTI)

The concept of solar driven chemical reactions in a commercial-scale volumetric receiver/reactor on a parabolic concentrator was successfully demonstrated in the CAtalytically Enhanced Solar Absorption Receiver (CAESAR) test. Solar reforming of methane (CH{sub 4}) with carbon dioxide (CO{sub 2}) was achieved in a 64-cm diameter direct absorption reactor on a parabolic dish capable of 150 kW solar power. The reactor was a catalytic volumetric absorber consisting of a multi-layered, porous alumina foam disk coated with rhodium (Rh) catalyst. The system was operated during both steady-state and solar transient (cloud passage) conditions. The total solar power absorbed reached values up to 97 kW and the maximum methane conversion was 70%. Receiver thermal efficiencies ranged up to 85% and chemical efficiencies peaked at 54%. The absorber performed satisfactorily in promoting the reforming reaction during the tests without carbon formation. However, problems of cracking and degradation of the porous matrix, nonuniform dispersion of the Rh through the absorber, and catalyst deactivation due to sintering and possible encapsulation, must be resolved to achieve long-term operation and eventual commercialization. 17 refs., 11 figs., 1 tab.

Muir, J.F.; Hogan, R.E. Jr.; Skocypec, R.D. (Sandia National Labs., Albuquerque, NM (USA)); Buck, R. (Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Stuttgart (Germany, F.R.). Inst. fuer Technische Thermodynamik)

1990-01-01T23:59:59.000Z

236

Simple rules help select best hydrocarbon distillation scheme  

SciTech Connect (OSTI)

Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del (Inst. Mexicano del Petroleo, Mexico City (Mexico))

1993-12-06T23:59:59.000Z

237

Fast electromigration crack in nanoscale aluminum film  

SciTech Connect (OSTI)

The current-induced breakage of 20?nm thin aluminum layers deposited onto capacitor grade polypropylene (PP) films is experimentally studied. Biexponential current pulses of different amplitude (10–15?A) and duration (0.1–1??s) were applied to the samples. Breakage occurred after fast development of electromigrating ?200?nm-wide cracks with initial propagation velocity of ?1?m/s under a high current density of ?10{sup 12?}A/m{sup 2}. The cracks stopped when their lengths reached 250–450??m. This behavior is explained by the balance of electromigration and stress-induced atomic fluxes.

Emelyanov, O. A., E-mail: oaemel2@gmail.com; Ivanov, I. O. [St. Petersburg State Polytechnical University, Saint-Petersburg (Russian Federation)

2014-08-14T23:59:59.000Z

238

Crack closure effects on fatigue crack growth thresholds and remaining life in an HSLA steel  

SciTech Connect (OSTI)

The effects of crack closure on the near-threshold corrosion fatigue crack growth behavior of Mil S-24645 HSLA steel and its weld metal have been investigated in air, ASTM seawater at the free corrosion potential, and ASTM seawater at {minus}0.8V and {minus}1.0V (SCE) using frequencies of 10, 2, and 0.2 Hz, and a stress ratio, R = 0.1. Remaining life, in the presence and absence of crack closure, has been estimated as a function of applied stress range for a structure containing a 3-mm-deep surface semi-elliptical flaw.

Todd, J.A.; Mostovoy, S. [Illinois Inst. of Tech., Chicago, IL (United States). Dept. of Mechanical, Materials and Aerospace Engineering; Chen, L. [Texas Instruments, Attleboro, MA (United States); Yankov, E.Y. [A. Finkl and Sons, Chicago, IL (United States)

1997-02-01T23:59:59.000Z

239

Water distillation using waste engine heat from an internal combustion engine  

E-Print Network [OSTI]

To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

Mears, Kevin S

2006-01-01T23:59:59.000Z

240

Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle  

E-Print Network [OSTI]

Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle Ethanol, but sorghum grain is commonly either blended with corn before use or used as the sole grain for ethanol

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

242

Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...  

Gasoline and Diesel Fuel Update (EIA)

839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

243

Overview of used antifreeze and industrial glycol recycling by vacuum distillation  

SciTech Connect (OSTI)

A leading method of reclaiming ethylene glycol from both used automotive coolants and waste industrial glycol streams is vacuum distillation. Over 15 million gallons per year of total glycols are recovered by this technology, which are marketed for use in antifreeze and industrial chemicals. It is a robust technology, tolerant of many common feed contaminants, and producing minimum waste. This paper presents an overview of vacuum distillation as one part of a multistep process for recovering glycols from a wide variety of feedstreams. Described are industry practices for laboratory prescreening of feedstreams, process adjustments and pretreatments, distillation technologies and post-distillation polishing methods. In each section, information and data are presented from two independent facilities and for several streams processed at each facility. It is concluded that the facilities participating in this study can reliably produce ethylene glycol suitable for the production of ASTM specification engine coolants.

Frye, D.K. [Filter Recovery Services, Alexandria, VA (United States); Chan, K.; Pourhassanian, C. [DeMenno/Kerdoon, Inc., Compton, CA (United States)

1999-08-01T23:59:59.000Z

244

Grain Boundary Structure Effects on Intergranular Stress Corrosion Cracking of  

E-Print Network [OSTI]

Grain Boundary Structure Effects on Intergranular Stress Corrosion Cracking of Alloy X­750 Y. Pan B­of­freedom) and correlations with intergranular stress corrosion cracking observed in Alloy X­750. Orientation imaging

Olson, Tamara

245

Reflective Cracking Study: HVS Test Section Forensic Investigation  

E-Print Network [OSTI]

the asphalt concrete. Summary of Testing on the Underlyingtesting performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the forensic investigation of the HVS rutting and reflective cracking testing

Jones, David; Steven, B.; Harvey, John T

2008-01-01T23:59:59.000Z

246

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

SciTech Connect (OSTI)

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

247

The Scaleup of Structured Packing from Distillation Pilot Plant Testing to Commercial Application  

E-Print Network [OSTI]

fractionator was performed, it was necessary to inventory the column with feed and, under total reflux conditions, draw off distillate or bottoms product until the proper composition profile was achieved. To investigate various design options, both... stream by a factor of five. In summary, from the customer's point of view, the application of structured packing to the main fractionator in the SFP fractionation train is a cOOluercial success. NEW DISTILLATION DEVELOPMENT PILOT PLANT Since...

Berven, O. J.; Ulowetz, M. A.

248

Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation  

E-Print Network [OSTI]

EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

Jaiswal, Namit

2007-09-17T23:59:59.000Z

249

PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION  

SciTech Connect (OSTI)

Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

Pierce, R. A.; Pak, D. J.

2012-09-11T23:59:59.000Z

250

Environmentally assisted cracking in light water reactors  

SciTech Connect (OSTI)

This report summarizes work performed by Argonne National Laboratory on fatigue and environmentally assisted cracking (EAC) in light water reactors (LWRs) from April 1995 to December 1995. Topics that have been investigated include fatigue of carbon and low-alloy steel used in reactor piping and pressure vessels, EAC of Alloy 600 and 690, and irradiation-assisted stress corrosion cracking (IASCC) of Type 304 SS. Fatigue tests were conducted on ferritic steels in water that contained various concentrations of dissolved oxygen (DO) to determine whether a slow strain rate applied during different portions of a tensile-loading cycle are equally effective in decreasing fatigue life. Crack-growth-rate tests were conducted on compact-tension specimens from several heats of Alloys 600 and 690 in simulated LWR environments. Effects of fluoride-ion contamination on susceptibility to intergranular cracking of high- and commercial- purity Type 304 SS specimens from control-tensile tests at 288 degrees Centigrade. Microchemical changes in the specimens were studied by Auger electron spectroscopy and scanning electron microscopy to determine whether trace impurity elements may contribute to IASCC of these materials.

Chopra, O.K.; Chung, H.M.; Gruber, E.E. [and others

1996-07-01T23:59:59.000Z

251

Digital radiographic systems detect boiler tube cracks  

SciTech Connect (OSTI)

Boiler water wall leaks have been a major cause of steam plant forced outages. But conventional nondestructive evaluation techniques have a poor track record of detecting corrosion fatigue cracking on the inside surface of the cold side of waterwall tubing. EPRI is performing field trials of a prototype direct-digital radiographic system that promises to be a game changer. 8 figs.

Walker, S. [EPRI, Charlotte, NC (United States)

2008-06-15T23:59:59.000Z

252

CRACKING OF PIc NUCLEAR CONTAINMENT STRUCTURES  

E-Print Network [OSTI]

CRACKING OF PIc NUCLEAR CONTAINMENT STRUCTURES By Sami H. Rizkalla,l Sidney H. Simmonds': and James structures for some Canadian nuclear reactors consist of a heavy concrete base, a cylindrical wall, a ring the design accident pressure. This would result in the walls and dome of the containment being stressed

253

NORTHWESTERN UNIVERSITY Autonomous Crack Comparometer Phase II  

E-Print Network [OSTI]

program between the two universities. Thanks are also given to the staff of the Infrastructure Technology Institute and in particular Dan Marron for all his advice and assistance during the project. I would like that daily and weekly weather related crack displacements are greater than those produced by dynamic events

254

Stress corrosion cracking and crack tip characterization of Alloy X-750 in light water reactor environments  

E-Print Network [OSTI]

Stress corrosion cracking (SCC) susceptibility of Inconel Alloy X-750 in the HTH condition has been evaluated in high purity water at 93 and 288°C under Boiling Water Reactor Normal Water Chemistry (NWC) and Hydrogen Water ...

Gibbs, Jonathan Paul

2011-01-01T23:59:59.000Z

255

Stress Corrosion Cracking and Crack Tip Characterization of Alloy X-750 in Light Water Reactor Environments  

E-Print Network [OSTI]

Stress corrosion cracking (SCC) susceptibility of Inconel Alloy X-750 in the HTH condition has been evaluated in high purity water at 93 and 288°C under Boiling Water Reactor Normal Water Chemistry (NWC) and Hydrogen Water ...

Gibbs, Jonathan Paul

256

Enhanced ultrasonic detection of fatigue cracks by laser-induced crack closure  

E-Print Network [OSTI]

, corrosion, etc. . Sec- ond, it is important to distinguish small fatigue cracks as early as possible after threshold in aluminum, aluminum­ lithium, and titanium alloys.1 For example, extensive multiple-site fatigue

Nagy, Peter B.

257

CRACK STATISTIC OF CRYSTALLINE SILICON PHOTOVOLTAIC MODULES M. Kntges1  

E-Print Network [OSTI]

the risk of cracks, as well as for statistical power loss assessment. Keywords: PV module, micro cracks separation, thus resulting in inactive cell parts. For this special case a clear assessment of the power loss this gap and provide a first statistic of cracks in PV modules for future power loss assessment

258

Application of the cracked pipe element to creep crack growth prediction  

SciTech Connect (OSTI)

The modification of a computer code for leak before break analysis is very briefly described. The CASTEM2000 code was developed for ductile fracture assessment of piping systems with postulated circumferential through-wall cracks under static or dynamic loading. The modification extends the capabilities of the cracked pipe element to the determination of fracture parameters under creep conditions (C*, {phi}c and {Delta}c). The model has the advantage of evaluating significant secondary effects, such as those from thermal loading.

Brochard, J.; Charras, T.

1997-04-01T23:59:59.000Z

259

Characterization of cracking restraint at sawcut joints using the German Cracking Frame  

E-Print Network [OSTI]

. . 7 Percentage cracks vs. time aAer placement in bike trail concrete. . . , . . . . . . 8. Development of cracking stress and strength vs. time atter placement of bike trail concrete 9. Equivalent temperature difference (between the slab top... and bottom) vs. time after placement in the bike trail concrete. . . . . . . . . . . . . , , . . . . . . . . 10, Relative humidity at 0. 75 inches below surface vs. time after placement for the bike trail concrete 11. Calculated shrinkage vs. time aAer...

Vepakomma, Shilpa

2002-01-01T23:59:59.000Z

260

Autothermal reforming catalyst having perovskite structure  

DOE Patents [OSTI]

The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

Krumpel, Michael (Naperville, IL); Liu, Di-Jia (Naperville, IL)

2009-03-24T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

To give a better understanding of autothermal reforming (ATR), a process which offers an advantageous alternative to steam reforming for H/sub 2/ production for fuel cells because of the wider range of fuels which can be converted, the conversion of individual fuel components was studied. Attempts have been made to characterize the chemical reactions of light and heavy paraffins and aromatics in ATR. Results of studies to determine the effects of operating parameters on the carbon-forming tendency of each hydrocarbon type are reported. The catalyst used for the ATR process was three-layers of supported nickel catalysts, Norton NC-100 spheres in the top zone, cylindrical G-56B tablets in the bottom one, and either ICI 46-I or ICI 46-4 Raschig rings in the middle zone. A summary of the experimental studies of the ATR of n-hexane, n-tetradecane, benzene, and benzene solutions of naphthalene is presented. (BLM)

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

262

Autothermal hydrodesulfurizing reforming method and catalyst  

DOE Patents [OSTI]

A method for reforming a sulfur-containing carbonaceous fuel in which the sulfur-containing carbonaceous fuel is mixed with H.sub.2 O and an oxidant, forming a fuel/H.sub.2 O/oxidant mixture. The fuel H.sub.2 O/oxidant mixture is brought into contact with a catalyst composition comprising a dehydrogenation portion, an oxidation portion and a hydrodesulfurization portion, resulting in formation of a hydrogen-containing gas stream.

Krumpelt, Michael; Kopasz, John P.; Ahmed, Shabbir; Kao, Richard Li-chih; Randhava, Sarabjit Singh

2005-11-22T23:59:59.000Z

263

Partial oxidation fuel reforming for automotive power systems.  

SciTech Connect (OSTI)

For widespread use of fuel cells to power automobiles in the near future, it is necessary to convert gasoline or other transportation fuels to hydrogen on-board the vehicle. Partial oxidation reforming is particularly suited to this application as it eliminates the need for heat exchange at high temperatures. Such reformers offer rapid start and good dynamic performance. Lowering the temperature of the partial oxidation process, which requires the development of a suitable catalyst, can increase the reforming efficiency. Catalytic partial oxidation (or autothermal) reformers and non-catalytic partial oxidation reformers developed by various organizations are presently undergoing testing and demonstration. This paper summarizes the process chemistries as well as recent test data from several different reformers operating on gasoline, methanol, and other fuels.

Ahmed, S.; Chalk, S.; Krumpelt, M.; Kumar, R.; Milliken, J.

1999-09-07T23:59:59.000Z

264

Why Do Kraft Recovery Boiler Composite Floor Tubes Crack?  

SciTech Connect (OSTI)

Cracks were first reported in 1992 in co-extruded 304L stainless steel/SA210 Gd Al carbon steel floor tubes of North American black liquor recovery boilers. Since then, a considerable amount of information has been collected on the tube environment, crack characteristics, the stress state of the tubes, and the crack initiation and propagation mechanisms. These studies have identified both operating procedures that apparently can greatly lessen the likelihood of crack formation in the stainless steel layer and alternate materials that appear to be much more resistant to cracking than is 304L stainless.

Keiser, J.R.

2001-10-22T23:59:59.000Z

265

Soil cracking modelling using the mesh-free SPH method  

E-Print Network [OSTI]

The presence of desiccation cracks in soils can significantly alter their mechanical and hydrological properties. In many circumstances, desiccation cracking in soils can cause significant damage to earthen or soil supported structures. For example, desiccation cracks can act as the preference path way for water flow, which can facilitate seepage flow causing internal erosion inside earth structures. Desiccation cracks can also trigger slope failures and landslides. Therefore, developing a computational procedure to predict desiccation cracking behaviour in soils is vital for dealing with key issues relevant to a range of applications in geotechnical and geo-environment engineering. In this paper, the smoothed particle hydrodynamics (SPH) method will be extended for the first time to simulate shrinkage-induced soil cracking. The main objective of this work is to examine the performance of the proposed numerical approach in simulating the strong discontinuity in material behaviour and to learn about the crack ...

Bui, H H; Kodikara, J; Sanchez, M

2015-01-01T23:59:59.000Z

266

Distributed Reforming of Renewable Liquids via Water Splitting...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

267

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Production Systems, Sandy Thomas, H2Gen Integrated Short Contact Time Hydrogen Generator, Wei Wei, GE Global Research Distributed Bio-Oil Reforming, Darlene Steward,...

268

Agenda for the Derived Liquids to Hydrogen Distributed Reforming...  

Broader source: Energy.gov (indexed) [DOE]

Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to...

269

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming...

270

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets  

Broader source: Energy.gov [DOE]

Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

271

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Contact Time Hydrogen Generator, Ke Liu, GE Global Research Hydrogen from Biomass by Autothermal Reforming, Lanny D. Schmidt, University of Minnesota Low-Cost Hydrogen from Ethanol...

272

Welfare Impacts of Electricity Generation Sector Reform in the Philippines  

E-Print Network [OSTI]

the Government lost and there was an air pollution cost. The paper concludes that the reform with private sector participation increased social welfare....

Toba, Natsuko

2004-06-16T23:59:59.000Z

273

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Broader source: Energy.gov (indexed) [DOE]

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer Mark Hemingway, Dr. Joachim Kupe, Joseph Bonadies, Mike Seino, Dr. John Kirwan, - Delphi Powertrain DEER, August...

274

Compatibility of selected ceramics with steam-methane reformer environments  

SciTech Connect (OSTI)

Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

1996-04-01T23:59:59.000Z

275

advance hatchery reform: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Private Insurance Market Renewable Energy Websites Summary: SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION...

276

Diesel Reformers for On-board Hydrogen Applications  

Broader source: Energy.gov (indexed) [DOE]

After-treatment Catalyst Clean Exhaust Effective Catalyst Regeneration Emission Reduction Electricity for On-road and Idling Loads SOFC APU Efficiency Boost Reformers for...

277

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon  

E-Print Network [OSTI]

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon Countries, Vickerstaff, S & Loretto, W 2012, 'Reforming State Pension provision in `Liberal' Anglo Saxon Countries: Re University Press. Lain, D., Vickerstaff, S. & Loretto, W. 2012, "Reforming State Pension provision

Millar, Andrew J.

278

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type or Print)  

E-Print Network [OSTI]

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type Care Structural Reform: What's Happening in Albany and Washington? Changing the Social Determinants of Health Reform in the Pharmaceutical Industry Sustaining Community Health Workers Comparative

Brown, Lucy L.

279

Aligning modes of organization with technology: Critical transactions in the reform of infrastructures  

E-Print Network [OSTI]

1 Aligning modes of organization with technology: Critical transactions in the reform of their reform. Since infrastructures are characterized by strong technical complementarities, we explore the alignment between organization and technology and should be taken explicitly into account when reforming

Boyer, Edmond

280

Negotiating Education Reform: Teacher Evaluations and Incentives in Chile (1990-2010)  

E-Print Network [OSTI]

Reforms designed to improve the quality of teaching by reforming personnel practices, such as pay for performance arrangements, usually run into opposition from well-organized teacher unions that can either block reform ...

Mizala, Alejandra

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Electricity Sector Reform in Developing Countries: A Survey of Empirical Evidence on Determinants and Performance  

E-Print Network [OSTI]

This paper reviews the empirical evidence on electricity reform in developing countries. We find that country institutions and sector governance play an important role in success and failure of reform; reforms appear to have increased operating...

Jamasb, Tooraj; Mota, Raffaella L; Newbery, David; Pollitt, Michael G.

2004-07-09T23:59:59.000Z

282

SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS  

SciTech Connect (OSTI)

Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

Klein, J; Jeffrey Holder, J

2007-07-16T23:59:59.000Z

283

Circumferential cracking of steam generator tubes  

SciTech Connect (OSTI)

On April 28, 1995, the U.S. Nuclear Regulatory Commission (NRC) issued Generic Letter (GL) 95-03, {open_quote}Circumferential Cracking of Steam Generator Tubes.{close_quote} GL 95-03 was issued to obtain information needed to verify licensee compliance with existing regulatory requirements regarding the integrity of steam generator tubes in domestic pressurized-water reactors (PWRs). This report briefly describes the design and function of domestic steam generators and summarizes the staff`s assessment of the responses to GL 95-03. The report concludes with several observations related to steam generator operating experience. This report is intended to be representative of significant operating experience pertaining to circumferential cracking of steam generator tubes from April 1995 through December 1996. Operating experience prior to April 1995 is discussed throughout the report, as necessary, for completeness.

Karwoski, K.J.

1997-04-01T23:59:59.000Z

284

Process for magnetic beneficiating petroleum cracking catalyst  

DOE Patents [OSTI]

A process for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded.

Doctor, Richard D. (Lisle, IL)

1993-01-01T23:59:59.000Z

285

Process for magnetic beneficiating petroleum cracking catalyst  

DOE Patents [OSTI]

A process is described for beneficiating a particulate zeolite petroleum cracking catalyst having metal values in excess of 1000 ppm nickel equivalents. The particulate catalyst is passed through a magnetic field in the range of from about 2 Tesla to about 5 Tesla generated by a superconducting quadrupole open-gradient magnetic system for a time sufficient to effect separation of said catalyst into a plurality of zones having different nickel equivalent concentrations. A first zone has nickel equivalents of about 6,000 ppm and greater, a second zone has nickel equivalents in the range of from about 2000 ppm to about 6000 ppm, and a third zone has nickel equivalents of about 2000 ppm and less. The zones of catalyst are separated and the second zone material is recycled to a fluidized bed of zeolite petroleum cracking catalyst. The low nickel equivalent zone is treated while the high nickel equivalent zone is discarded. 1 figures.

Doctor, R.D.

1993-10-05T23:59:59.000Z

286

The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients  

SciTech Connect (OSTI)

As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

1989-07-01T23:59:59.000Z

287

Structures for dense, crack free thin films  

DOE Patents [OSTI]

The process described herein provides a simple and cost effective method for making crack free, high density thin ceramic film. The steps involve depositing a layer of a ceramic material on a porous or dense substrate. The deposited layer is compacted and then the resultant laminate is sintered to achieve a higher density than would have been possible without the pre-firing compaction step.

Jacobson, Craig P. (Lafayette, CA); Visco, Steven J. (Berkeley, CA); De Jonghe, Lutgard C. (Lafayette, CA)

2011-03-08T23:59:59.000Z

288

CDF central preshower and crack detector upgrade  

SciTech Connect (OSTI)

The CDF Central Preshower and Crack Detector Upgrade consist of scintillator tiles with embedded wavelength-shifting fibers, clear-fiber optical cables, and multi-anode photomultiplier readout. A description of the detector design, test results from R&D studies, and construction phase are reported. The upgrade was installed late in 2004, and a large amount of proton-antiproton collider data has been collected since then. Detector studies using those data are also discussed.

Artikov, A.; Boudagov, J.; Chokheli, D.; Drake, G.; Gallinaro, M.; Giunta, M.; Grudzinski, J.; Huston, J.; Iori, M.; Kim, D.; Kim, M.; /Dubna, JINR /Argonne /Rockefeller

2007-02-01T23:59:59.000Z

289

E-Print Network 3.0 - act contracting reform Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

US Pricing Basics and What to Expect from Healthcare Reform By Jack Mycka... health care reform and pricing 12;3 MME LLC 2010 Applied Pharmacoeconomics and Outcomes...

290

Source book for planning nuclear dual-purpose electric/distillation desalination plants  

SciTech Connect (OSTI)

A source book on nuclear dual-purpose electric/distillation desalination plants was prepared to assist government and other planners in preparing broad evaluations of proposed applications of dual-purpose plants. The document is divided into five major sections. Section 1 presents general discussions relating to the benefits of dual-purpose plants, and spectrum for water-to-power ratios. Section 2 presents information on commercial nuclear plants manufactured by US manufacturers. Section 3 gives information on distillation desalting processes and equipment. Section 4 presents a discussion on feedwater pretreatment and scale control. Section 5 deals with methods for coupling the distillation and electrical generating plants to operate in the dual mode.

Reed, S.A.

1981-02-01T23:59:59.000Z

291

Environmental fiscal reform (EFR) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Power Basics (The followingDirectLowDiscussion-4,611,201.00fiscal reform (EFR)

292

Health Care Reform Challenge: Creating a High Performance Healthcare System  

E-Print Network [OSTI]

Health Care Reform Challenge: Creating a High Performance Healthcare System Tom Simmer, MD Chief;The Challenge of Reform: Accountable Care Organizations (ACO) · ACO's are provider organizations health care delivery Organized Systems of Care Population focus for primary care physicians, hospitals

Finley Jr., Russell L.

293

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network [OSTI]

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high process converts low-octane gasoline blending compo- nents to high-octane components for use in high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

Skogestad, Sigurd

294

BREAKING WITH OR BUILDING ON THE PAST? REFORMING IRISH PUBLIC  

E-Print Network [OSTI]

of the application of new public management styles to Ireland. Particular attention is paid to the public serviceBREAKING WITH OR BUILDING ON THE PAST? REFORMING IRISH PUBLIC ADMINISTRATION: 1958-2008 Niamh? REFORMING IRISH PUBLIC ADMINISTRATION: 1958-2008 Niamh Hardiman and Muiris MacCarthaigh Working Papers

295

ISSN 1745-9648 Electricity Sector Reform in Greece  

E-Print Network [OSTI]

ISSN 1745-9648 Electricity Sector Reform in Greece by Ekaterini Iliadou Lawyer - Legal Department of the electricity market reform in Greece which started in 2001 and is still developing slowly. This is related to the persisting dominance of the incumbent company and the specificities of the electricity sector of Greece

Feigon, Brooke

296

Consulting Assistance on Economic Reform II Discussion Papers  

E-Print Network [OSTI]

Consulting Assistance on Economic Reform II Discussion Papers The objectives of the Consulting Assistance on Economic Reform (CAER II) project are to contribute to broad-based and sustainable economic, Bureau for Global Programs, Field Support and Research, Center for Economic Growth and Agricultural

297

Steam reforming of fuel to hydrogen in fuel cells  

DOE Patents [OSTI]

A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

1984-01-01T23:59:59.000Z

298

Steam reforming of fuel to hydrogen in fuel cell  

DOE Patents [OSTI]

A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Young, J.E.; Fraioli, A.V.

1983-07-13T23:59:59.000Z

299

Application of the cracked pipe element to creep crack growth prediction  

SciTech Connect (OSTI)

Modifications to a computer code for ductile fracture assessment of piping systems with postulated circumferential through-wall cracks under static or dynamic loading are very briefly described. The modifications extend the capabilities of the CASTEM2000 code to the determination of fracture parameters under creep conditions. The main advantage of the approach is that thermal loads can be evaluated as secondary stresses. The code is applicable to piping systems for which crack propagation predictions differ significantly depending on whether thermal stresses are considered as primary or secondary stresses.

Brochard, J.; Charras, T. [C.E.A.-C.E.-Saclay DRN/DMT, Gif Sur Yvette (France); Ghoudi, M. [C.E.A.-C.E.-Saclay, Gif Sur Yvette (France)

1997-04-01T23:59:59.000Z

300

The Products of the Destructive Distillation of Keratin in the Form of Leather  

E-Print Network [OSTI]

ure to the air. After this came a white crystal­ line solid, fourth a reddish fciquid, fifth a red­ dish crystalline compound and sixth the black oil spoken of abovd. A volume of the distillate, equaling about a liter was collected and the two... the material the temperature rose to 200° C. and then reduction started and the temperature fell rapidly. The tar or oil constitutes from 3 to 4 per cent of the weight of the leather used. The aqueous portion of the distillate was subjected to a fractional...

Rose, Reed Phillips

1913-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Process for converting heavy oil deposited on coal to distillable oil in a low severity process  

DOE Patents [OSTI]

A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

1994-01-01T23:59:59.000Z

302

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.

2003-05-21T23:59:59.000Z

303

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg

2003-05-01T23:59:59.000Z

304

Method and apparatus for generating a natural crack  

DOE Patents [OSTI]

A method and apparatus for generating a measurable natural crack includes forming a primary notch in the surface of a solid material. A nonsustained single pressure pulse is then generated in the vicinity of the primary notch, reuslting in the formation of a shock wave which travels through the material. The shock wave creates a measurable natural crack within the material which extends from the primary notch. The natural crack formed possesses predictable geometry, location and orientation.

Fulton, F.J.; Honodel, C.A.; Holman, W.R.; Weingart, R.C.

1982-05-06T23:59:59.000Z

305

CYCLIC PLASTICITY OF A CRACKED STRUCTURE SUBJECTED TO MIXED MODE LOADING  

E-Print Network [OSTI]

CYCLIC PLASTICITY OF A CRACKED STRUCTURE SUBJECTED TO MIXED MODE LOADING Sylvie Pommier1, a 1 LMT, mixed mode crack propagation, plasticity, crack deflection. Abstract. Cyclic plasticity in the crack tip stresses in the overload's plastic zone. Moreover, if the overload's ratio is large enough, the crack may

306

P wave anisotropy, stress, and crack distribution at Coso geothermal...  

Open Energy Info (EERE)

Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: P wave anisotropy, stress, and crack distribution at Coso geothermal field, California...

307

High-Resolution Crack Imaging Reveals Degradation Processes in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reveals Degradation Processes in Nuclear Reactor Structural Materials. Abstract: Corrosion and cracking represent critical failure mechanisms for structural materials in many...

308

Physics-Based Stress Corrosion Cracking Component Reliability  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physics-Based Stress Corrosion Cracking Component Reliability Model cast in an R7-Compatible Cumulative Damage Framework Draft Report Supporting Technology Inputs to the Risk-...

309

White-Etching Crack Failure Overview, Tomography Analysis, and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

White-Etching Crack Failure Overview, Tomography Analysis, and Test Development Presented by Aaron Greco of Argonne National Laboratory at the Wind Turbine Tribology Seminar 2014....

310

Investigation of White Etching Crack (WEC) Formation Mechanisms...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigation of White Etching Crack (WEC) Formation Mechanisms Under Non-hydrogen Charged Test Conditions Presented by Alex Richardson, Afton Chemical (representing University of...

311

Tribological Analysis of White Etching Crack (WEC) Failures in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crack (WEC) Failures in Rolling Element Bearings Presented by Arnaud Ruellan, INSA de Lyon at the Wind Turbine Tribology Seminar 2014. 20141030NREL2014ArgonneRuellancomV...

312

Shrinkage - cracking characteristics of structural lightweight concrete  

E-Print Network [OSTI]

'P'D. ) FIGURE 4-14 Cracking as Indi. cat d by Nater Loss PACE IO 5-1 Thermal Expansion Correction by Emtrspolation /7 LZST OP TAELES TAELE Environments 35 Test. ing Program. Statistical Data Direct Tensile Specim n Data 59 4-3 Comparison of Selected.... Cement contents of 5, 0, 6. 0 ind 6. 5 i a~n. , /ci-hie yorri were used. Unrestraineii volume changes wcr liaaoi - . . i o! standard type specimens (3 x 3 x i 1. 25 . in, ) . Craciring i'!ali!ai. cd ns thi! number of ccac!. s occurring on a s, ~ i...

McKeen, Robert Gordon

1969-01-01T23:59:59.000Z

313

Cracking in reinforced concrete bent caps  

E-Print Network [OSTI]

) . . . . . . . . . . . . . . . . 4. 2 Group It2 Response (Specimens 3C, 3D, 4C, 4E, 5D, 5E) . . . 4. 3 Group tt3 Response (Specimens 6F, 6G, 7F, 7H, 8G, 8H) . . . 4. 4 General Response 4. 5 Sununary. . . . . 49 . . . . 58 . . . . 64 70 . . . 75 5. STRUT-AND-TIE MODELING... be expressed as the product of the steel strain (s, ) at that level multiplied by the crack spacing (s, ); 20 w =z*s C S C (2. 6) a linear strain gradient can be used to project the maximum strain occurring at the level of the flexural reinforcement...

Young, Bradley S.

2000-01-01T23:59:59.000Z

314

3:2:1 Crack Spread  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:short version)ecTotal (Data from:2:1 Crack Spread

315

Crack opening area estimates in pressurized through-wall cracked elbows under bending  

SciTech Connect (OSTI)

One of the most important aspects in the leak-before-break approach is the estimation of the crack opening area corresponding to potential through-wall cracks at critical locations during plant operation. In order to provide a reasonable lower bound to the leak area under such loading conditions, numerous experimental and numerical programs have been developed in USA, U.K. and FRG and widely discussed in literature. This paper aims to extend these investigations on a class of pipe elbows characteristic of PWR main coolant piping. The paper is divided in three main parts. First, a new simplified estimation scheme for leakage area is described, based on the reference stress method. This approach mainly developed in U.K. and more recently in France provides a convenient way to account for the non-linear behavior of the material. Second, the method is carried out for circumferential through-wall cracks located in PWR elbows subjected to internal pressure. Finite element crack area results are presented and comparisons are made with our predictions. Finally, in the third part, the discussion is extended to elbows under combined pressure and in plane bending moment.

Franco, C.; Gilles, P.; Pignol, M.

1997-04-01T23:59:59.000Z

316

Efficient use of an intermediate reboiler or condenser in a binary distillation  

SciTech Connect (OSTI)

The impact of an intermediate reboiler or condenser on the distillation of ideal binary mixtures into pure product streams is studied using a simplified model. The advantage of heuristics derived from this study is that they can quickly tell a process engineer if an intermediate reboiler or condenser is going to be effective in improving the efficiency and, of the two options, which one would be more effective. The heuristics simply states that if the actual fraction of liquid in a given feed is less than that with the maximum thermodynamic efficiency for distillation with no intermediate reboiler or condenser, then an intermediate condenser not only substantially improves the thermodynamic efficiency but is also more effective than an intermediate reboiler. An analogous heuristics exists for the intermediate reboiler when the fraction of liquid in the feed is greater than the optimum. Quick identification of cases that can achieve a substantial improvement in efficiency provides an incentive to search for the proper utilities needed for the intermediate reboiler or condenser. When relatively pure feed streams (concentration of either component greater than 90%) are distilled, the extremely low efficiencies of distillation can be remarkably improved by using an intermediate reboiler or condenser.

Agrawal, R.; Herron, D.M. [Air Products and Chemicals, Inc., Allentown, PA (United States)] [Air Products and Chemicals, Inc., Allentown, PA (United States)

1998-06-01T23:59:59.000Z

317

Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation  

E-Print Network [OSTI]

prefer a process where the energy may be supplied at a low temperature and cooling may be supplied law). This leads us to the reversible Petlyuk arrangement. However the total required heat supply). A characteristic of the reversible distillation column is that some of the heat is supplied continuously along

Skogestad, Sigurd

318

Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni  

E-Print Network [OSTI]

A study on middle distillate hydrotreatment zeolite catalysts containing Pt/Pd and/or Ni was performed. The effect of the addition of the corresponding CoMo, CoMoPd, CoMoPtPd and CoMoNi in PdNiPt-zeolite, Pt-zeolite, Ni-zeolite, and Pd...

Marin-Rosas, Celia

2009-05-15T23:59:59.000Z

319

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates*  

E-Print Network [OSTI]

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates samples, such as petroleum and coal, or for man-made samples, such as coal liquids, a major desire- nique for studying coal-liquid samples. 1-4 We demon- strated that the Raman spectra of polycyclic

Asher, Sanford A.

320

Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements  

E-Print Network [OSTI]

1 Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements of this paper is to present a simple graphical method for obtaining the energy usage and to compare the energy of Chemical Engineering, 7491 Trondheim, Norway Abstract The minimum energy requirements of six different heat

Skogestad, Sigurd

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Hybrid magic state distillation for universal fault-tolerant quantum computation  

E-Print Network [OSTI]

A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

2014-12-11T23:59:59.000Z

322

Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance  

SciTech Connect (OSTI)

In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

Eaton, Scott J [ORNL; Bunting, Bruce G [ORNL; Lewis Sr, Samuel Arthur [ORNL; Fairbridge, Craig [National Centre for Upgrading Technology, Canada

2009-01-01T23:59:59.000Z

323

Black-Box Identification for PLC based MPC of a Binary Distillation Column  

E-Print Network [OSTI]

Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

324

HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT  

E-Print Network [OSTI]

321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E hydrogen gas (so- called protium) must be used. It is necessary to avoid transfers of - to impurities imposes strict and critical requirements on the hydrogen gas system supporting the detector. Desirable

Titov, Anatoly

325

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to the Department for Education's reformed GCSE subject content  

E-Print Network [OSTI]

's reformed GCSE subject content consultation - August 2013 Department for Education: Reformed GCSE subject's reformed GCSE subject content consultation. The proposed changes to science qualifications promote reform and have enclosed a copy for information. 1 ` Direct assessment' is based on the direct assessment

Rambaut, Andrew

326

MOVIE "CHICAGO CITY COUNCIL: READY FOR REFORM?" (27 minutes/color)  

E-Print Network [OSTI]

, transportation, and health care. 8. Investigate how many of the reform proposals were in place twenty years afterMOVIE ­ "CHICAGO CITY COUNCIL: READY FOR REFORM?" (27 minutes/color) SYNOPSIS Following the death of Mayor Harold Washington, residents and reformers of Chicago still hoped for continued reform in Chicago

Illinois at Chicago, University of

327

Development of reduced crude cracking catalysts  

SciTech Connect (OSTI)

In 1974 OPEC imposed an embargo on oil to the United States and caused a rapid rise in the price of a barrel of oil. At the time of the embargo, Ashland imported a considerable portion of its oil from the Middle East, thus raising the question of oil availability. As the problem increased in severity, Messrs. George Meyer, Oliver Zandona and Llyod Busch, began to explore alternative ways of squeezing more product from a given barrel of crude. After considering many alternatives, they arrived at the innovative thought that it might be possible to catalytically crack the 1050{degree}F plus fraction of the barrel directly to gasoline which would in effect, give them an additional volume of crude oil. Also, if vacuum fractionation were eliminated and if the entire 650{degree}F plus (reduced crude) portion of the barrel processed, this would further reduce operating costs. With these objectives and some new process innovations in mind, they began reduced crude cracking experimentation in a small 12,000 B/D FCC operating unit at Louisville. It was from these goals, concepts and a small operating unit, that the RCC process was born.

Hettinger, W.P. Jr. (Ashland Petroleum Company, KY (USA))

1987-08-01T23:59:59.000Z

328

E-Print Network 3.0 - applications crack growth Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

that the critical crack-tip opening angle (CTOA) value measured on the specimen... fracture changes a Mode-I type of crack growth to a mixed-mode IIII type of crack growth. It...

329

Evaluation of Partial Oxidation Reformer Emissions  

SciTech Connect (OSTI)

In this study, a gasoline fuel processor and an ethanol fuel processor were operated under conditions simulating both startup and normal operation. Emissions were measured before and after the AGB in order to quantify the effectiveness of the burner catalyst in controlling emissions. The emissions sampling system includes CEM for O2, CO2, CO, NOx, and THC. Also, integrated gas samples are collected in evacuated canisters for hydrocarbon speciation analysis via GC. This analysis yields the concentrations of the hydrocarbon species required for the California NMOG calculation. The PM concentration in the anode burner exhaust was measured through the placement of a filter in the exhaust stream. The emissions from vehicles with fully developed on board reformer systems were estimated.

Unnasch, Stefan; Fable, Scott; Waterland, Larry

2006-01-06T23:59:59.000Z

330

Catalytic autothermal reforming increases fuel cell flexibility  

SciTech Connect (OSTI)

Experimental results are presented for the autothermal reforming (ATR) of n-hexane, n-tetradecane, benzene and benzene solutions of naphthalene. The tests were run at atmospheric pressure and at moderately high reactant preheat temperatures in the 800-900 K range. Carbon formation lines were determined for paraffinic and aromatic liquids. Profiles were determined for axial bed temperature and composition. Space velocity efforts were assessed, and the locations and types of carbon were recorded. Significant reactive differences between hydrocarbons were identified. Carbon formation characteristics were hydrocarbon specific. The differing behavior of paraffinic and aromatic fuels with respect to their carbon formation may be important in explaining the narrow range of carbon-free operating conditions found in the ATR of number two fuel oil.

Flytzani-Stephanopoulos, M.; Voecks, G.E.

1981-12-01T23:59:59.000Z

331

Thermally efficient melting and fuel reforming for glass making  

DOE Patents [OSTI]

An integrated process is described for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling. 2 figures.

Chen, M.S.; Painter, C.F.; Pastore, S.P.; Roth, G.S.; Winchester, D.C.

1991-10-15T23:59:59.000Z

332

Thermally efficient melting and fuel reforming for glass making  

DOE Patents [OSTI]

An integrated process for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling.

Chen, Michael S. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary S. (Trexlertown, PA); Winchester, David C. (Allentown, PA)

1991-01-01T23:59:59.000Z

333

The Influence of Crystallographic Orientation on Crack Tip Displacements of  

E-Print Network [OSTI]

consists of 212 randomly shaped, sized and oriented grains, loaded monotonically in uniaxial tension to a maximum load of 0.9Rp0.2 (240 MPa). The influence that a random grain structure imposes on a Stage I crack will preferably follow the slip plane where the crack tip opening displacement is highest, we show

Cizelj, Leon

334

Fracture mechanics analysis of slow crack growth in polyethylene  

E-Print Network [OSTI]

Slow crack growth in polyethylene is often the limiting factor in long-term service of plastic pipe or other structural applications. A new test method and analysis method was developed to study slow crack growth in polyethylene. Two high density...

Self, Robert Alan

1997-01-01T23:59:59.000Z

335

NORTHWESTERN UNIVERSITY Crack Response to Weather Effects, Blasting, and Construction  

E-Print Network [OSTI]

NORTHWESTERN UNIVERSITY Crack Response to Weather Effects, Blasting, and Construction Vibrations Acknowledgements iii Abstract iv List of Figures v List of Tables xi Chapter 1- Introduction 1 Chapter 2- Blast Vibration Response, Southbury, Connecticut 5 Structural Description Instrumentation Blast Response Crack

336

Crack-based analysis of concrete with brittle reinforcement  

E-Print Network [OSTI]

{ FaberMaunsell Ltd; University of Cambridge Brittle reinforcement (such as fibre-reinforced plastic to the surround- ing concrete, at a crack surface sL=sR s on the left/right side of a crack u increase in unbonded

Burgoyne, Chris

337

Prediction of pure water stress corrosion cracking (PWSCC) in nickel base alloys using crack growth rate models  

SciTech Connect (OSTI)

The Ford/Andresen slip dissolution SCC model, originally developed for stainless steel components in BWR environments, has been applied to Alloy 600 and Alloy X-750 tested in deaerated pure water chemistry. A method is described whereby the crack growth rates measured in compact tension specimens can be used to estimate crack growth in a component. Good agreement was found between model prediction and measured SCC in X-750 threaded fasteners over a wide range of temperatures, stresses, and material condition. Most data support the basic assumption of this model that cracks initiate early in life. The evidence supporting a particular SCC mechanism is mixed. Electrochemical repassivation data and estimates of oxide fracture strain indicate that the slip dissolution model can account for the observed crack growth rates, provided primary rather than secondary creep rates are used. However, approximately 100 cross-sectional TEM foils of SCC cracks including crack tips reveal no evidence of enhanced plasticity or unique dislocation patterns at the crack tip or along the crack to support a classic slip dissolution mechanism. No voids, hydrides, or microcracks are found in the vicinity of the crack tips creating doubt about classic hydrogen related mechanisms. The bulk oxide films exhibit a surface oxide which is often different than the oxides found within a crack. Although bulk chromium concentration affects the rate of SCC, analytical data indicates the mechanism does not result from chromium depletion at the grain boundaries. The overall findings support a corrosion/dissolution mechanism but not one necessarily related to slip at the crack tip.

Thompson, C.D.; Krasodomski, H.T.; Lewis, N.; Makar, G.L.

1995-02-22T23:59:59.000Z

338

Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report  

SciTech Connect (OSTI)

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Not Available

1994-05-01T23:59:59.000Z

339

SciTech Connect: Stress corrosion cracking of alloy 600 using...  

Office of Scientific and Technical Information (OSTI)

Stress corrosion cracking of alloy 600 using the constant strain rate test Citation Details In-Document Search Title: Stress corrosion cracking of alloy 600 using the constant...

340

E-Print Network 3.0 - assisted cracking resistance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

crack... and the time-dependent, environmentally-assisted, crack initiation and subcritical growth in the oxide layer... of exploring these prin- ciples is seen in Figure 5....

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - automated crack inspection Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

through micro cracks in the composite material... system with micro cracking induced damage is carried out. The effective permeability due ... Source: Popov, Peter - Institute of...

342

Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons  

SciTech Connect (OSTI)

An apparatus is described for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising: (a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein; (b) means defining a primary reforming zone within the outer reactor shell and having catalyst-containing reformer tubes positioned therein, the primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occurring therein; (c) means for introducing a fluid hydrocarbon feed stream and steam to the outer reactor shell for passage through the reformer tubes in the primary reforming zone; (d) means defining a secondary reforming zone within the outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to the catalyst bed and a discharge end at the opposite side of the secondary reforming catalyst bed to the feed end; and (e) conduit means positioned entirely within the outer reactor shell and extending through the secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to the catalyst-free reaction space in the secondary reforming zone.

Fuderer, A.

1987-03-17T23:59:59.000Z

343

The stability of coerced economic reform : the case of IPR  

E-Print Network [OSTI]

Theories in international relations posit, and empirical evidence has verified, that unwilling states can be compelled by another state or by an international institution to enact domestic policy reform. However, these ...

Wilcox, Trudy

2005-01-01T23:59:59.000Z

344

Fuel reforming for scramjet thermal management and combustion optimization  

E-Print Network [OSTI]

Fuel reforming for scramjet thermal management and combustion optimization E. DANIAU* , M. BOUCHEZ in a Scramjet combustion chamber. Another critical point is that mixing and combustion should be sufficiently

Paris-Sud XI, Université de

345

Petroleum Refinery Catalytic Reforming -- Cutting High Energy Costs  

E-Print Network [OSTI]

. It is essential that the operation and maintenance of these furnaces be optimized to minimize production costs. This paper describes the performance testing and evaluation of a set of ten refinery furnaces used to thermally drive several reforming reactors...

Viar, W. L.

1979-01-01T23:59:59.000Z

346

Process Reform, Security and Suitability- December 17, 2008  

Broader source: Energy.gov [DOE]

This is to report on the progress made to improve the timeliness and effectiveness of our hiring and clearing decisions and the specific plan to reform the process further, in accordance with our initial proposals made in April ofthis year.

347

Before the House Committee on Oversight and Government Reform...  

Broader source: Energy.gov (indexed) [DOE]

Senior Advisor to the Secretary Before the House Committee on Oversight and Government Reform 2-11-15JohnMacWilliams FT HOGR.pdf More Documents & Publications Testimony Before...

348

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...  

Office of Environmental Management (EM)

Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3...

349

Bio-Derived Liquids to Hydrogen Distributed Reforming Working...  

Broader source: Energy.gov (indexed) [DOE]

X , H 2 2:15 pm Break 2:30 pm 3:45 pm X Arlene Anderson, 4:00 pm Adjourn Distributed Bio-Oil Reforming , National Renewable Energy Lab Investigation of Reaction Networks and...

350

Electricity Reform in Argentina: Lessons for Developing Countries  

E-Print Network [OSTI]

Argentina was one of the first countries in the world to implement a comprehensivereform of its electricity sector in the recent period. Among developing countries onlyChile has had a comparably comprehensive and successful reform. This paper traces...

Pollitt, Michael G.

2006-03-14T23:59:59.000Z

351

Faculty perceptions of presidential leadership in urban school reform  

E-Print Network [OSTI]

The study examined urban university faculty members’ perceptions of their presidents’ leadership role in urban school reform. The population for this study consisted of faculty members from five urban research universities. All of the universities...

McClendon, Rodney Prescott

2009-06-02T23:59:59.000Z

352

Argonne National Laboratory Chemical Engineering Division Catalysts for autothermal reforming  

E-Print Network [OSTI]

,110,861) awarded Oct 2000: CRADA w/H2Fuel to commercialize reformer Aug 2001: Began work on perovskite catalysts Feb 2002: CRADA w/Süd-Chemie to optimize catalyst performance Oct 2002: Demonstrated conversion

353

The Dynamics of Reform of India’s Federal System  

E-Print Network [OSTI]

very different set of policies, India has followed China inIssues in Tax Policy and Reform in India, paper presented atWater Disputes in India: Institutions and Policies,” in

Singh, Nirvikar

2007-01-01T23:59:59.000Z

354

Chemical simulation of hydrogen generation in a plasma fuel reformer  

E-Print Network [OSTI]

A model for a plasma fuel reformer or plasmatron has been developed. The model was based in a series of experiments realized at the Plasma Science and Fusion Center with such a plasmatron. The device is set up to produce ...

Margarit Bel, Nuria, 1977-

2004-01-01T23:59:59.000Z

355

Isle of Eigg : land reform, people, and power   

E-Print Network [OSTI]

An historiographical analysis of the present political debates regarding land reform in Scotland provides the point of departure for a case study of the Isle of Eigg and the 1997 purchase of the island by the Isle ofEigg ...

Morgan, Daniel Rhys

2000-07-20T23:59:59.000Z

356

ISSN 1745-9648 Organisation and Reforms of the  

E-Print Network [OSTI]

of liberalisation of the Slovenian electricity market to a large extent resembles what other EU countries were: electricity reform, restructuring, competition, South East Europe, liberalisation #12;2 Acknowledgements

Feigon, Brooke

357

A cross country analysis of electricity market reforms  

E-Print Network [OSTI]

econometric model based on Poisson regression with cross-section data covering 51 US states, 13 Canada states and 51 other countries. The results show that both the background of the chairperson of electricity market regulatory agency when reforms started...

Erdogdu, Erkan

2012-06-19T23:59:59.000Z

358

High Pressure Ethanol Reforming for Distributed Hydrogen Production  

Broader source: Energy.gov [DOE]

Presentation by S. Ahmed and S.H.D. Lee at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

359

Insights into Stress Corrosion Cracking Mechanisms from High-Resolution Measurements of Crack-Tip Structures and Compositions  

SciTech Connect (OSTI)

The fundamental basis for mechanistic understanding and modeling of SCC remains in question for many systems. Specific mechanisms controlling SCC can vary with changes in alloy characteristics, applied/residual stress or environmental conditions. The local crack electrochemistry, crack-tip mechanics and material metallurgy are the main factors controlling crack growth. These localized properties are difficult or impossible to measure in active cracks. Nevertheless, it is essential to quantitatively interrogate these crack-tip conditions if mechanistic understanding is to be obtained. A major recent advance has been the ability to investigate SCC cracks and crack tips using high-resolution ATEM techniques. ATEM enables the characterization of SCC cracks including trapped tip solution chemistries, corrosion product/film compositions and structures, and elemental composition gradients and defect microstructures along the crack walls and at the crack tip. A wide variety of methods for imaging and analyses at resolutions down to the atomic level can be used to examine the crack and corrosion film characteristics. Surface films and reaction layers have been examined by cross-sectional TEM techniques, but little work had been conducted on environmentally induced internal cracks until that of Lewis and co-workers [1-3] and the current authors [4-17]. This capability combined with modern ATEM techniques has enabled exciting new insights into corrosion processes occurring at buried interfaces and is being used to identify mechanisms controlling IGSCC in boiling water reactor (BWR) and pressurized water reactor (PWR) components. The objective of this paper is to summarize certain results focused on IGSCC of Fe- base and Ni-base stainless alloys in high-temperature water environments. Representative crack-tip examples will be shown to illustrate specific aspects that are characteristic of SCC in the material/environment combinations. Differences and similarities in crack-tip structures- chemistries will be highlighted comparing Fe-base 316/304SS to Ni-base alloy 600/182 and for tests in oxidizing versus hydrogenated water environments.

Bruemmer, Stephen M.; Thomas, Larry E.

2010-04-05T23:59:59.000Z

360

APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE  

SciTech Connect (OSTI)

Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

Pierce, R.; Pak, D.

2011-08-10T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation  

SciTech Connect (OSTI)

Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

Yang, Dali [Los Alamos National Laboratory; Orler, Bruce [Los Alamos National Laboratory; Tornga, Stephanie [Los Alamos National Laboratory; Welch, Cindy [Los Alamos National Laboratory

2011-01-26T23:59:59.000Z

362

Evaluation of reformed methanol as an automotive engine fuel  

E-Print Network [OSTI]

EVALUATION OF REFORMED METHANOL AS AN AUTOMOTIVE ENGINE FUEL A Thesis by DAVID MICHAEL MCCALL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December... 1903 Major Subject: Mechanical Engineering EVALUATION OF REFORMED METHANOL AS AN AUTOMOTIVE ENGINE FUEL A Thesis by DAVID MICHAEL MCCALL Approved as to style and content by: Dr. T. R. Lalk (Chairman o f Committee ) Dr. R. R. Davison (Member...

McCall, David M

1983-01-01T23:59:59.000Z

363

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

SciTech Connect (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

364

Implications of early stages in the growth of stress corrosion cracking on component reliability  

SciTech Connect (OSTI)

Environment-induced crack growth generally progresses through several stages prior to component failure. Crack initiation, short crack growth, and stage 1 growth are early stages in crack development that are summarized in this paper. The implications of these stages on component reliability, derive from the extended time that the crack exists in the early stages because crack velocity is slow. The duration of the early stages provides a greater opportunity for corrective action if cracks can be detected. Several important factors about the value of understanding short crack behavior include: (1) life prediction requires a knowledge of the total life cycle of the crack including the early stages, (2) greater reliability is possible if the transition between short and long crack behavior is known component life after this transition is short and (3) remedial actions are more effective for short than long cracks.

Jones, R.H.; Simonen, E.P.

1995-04-01T23:59:59.000Z

365

Cracking blends of gas oil and residual oil  

SciTech Connect (OSTI)

In a catalytic cracking process unit wherein a gas oil feed is cracked in a cracking zone at an elevated temperature in the presence of a cracking catalyst, the cracking catalyst is regenerated in a regeneration zone by burning coke of the catalyst, and catalyst is circulated between the cracking zone and the regeneration zone. The improvement is described for obtaining a naphtha product of improved octane number comprising introducing sufficient of a nickel and vanadium metals-containing heavy feedstock with the gas oil feed introduced into the cracking zone to deposit nickel and vanadium metals on the catalyst and raise the nickel and metals-content of the catalyst to a level ranging from about 1500 to about 6000 parts per million of the metals expressed as equivalent nickel, based on the weight of the catalyst, and maintaining the nickel and vanadium metals level on the catalyst by withdrawing high nickel and vanadium metals containing catalyst and adding low nickel and vanadium metals-containing catalyst to the regeneration zone.

Myers, G.D.

1988-03-01T23:59:59.000Z

366

Interactive chemical effects and instability of shale derived middle distillate fuels  

SciTech Connect (OSTI)

This paper presents a study of instability of shale-derived fuels. Changes in fuel properties with time have been a continuing problem in the use of middle distillate fuels. The authors define instability as the formation of insoluble sediments and gums as well as the production of peroxides and color bodies. Nitrogen and sulfur heterocycles have long been implicated in fuel degradation, but present knowledge is limited regarding the chemistry of their autoxidation reactions in the complex fuel media. Based on the GC/MS identification of nitrogen heterocyclic constituents in several shale-derived middle distillate fuels, the authors have conducted gravimetric instability tests employing three model nitrogen heterocycles in shale-derived diesel fuels. Model sulfur compound dopant studies on shale-derived jet fuels were conducted by monitoring hydroperoxide formation/decomposition and the decreased quantity of sulfur compound. Potential interactive effects have been defined for these model dopants.

Mushrush, G.W.; Beal, E.J.; Watkins, J.M.; Morris, R.E.; Hardy, D.R. (Fuels Section, Naval Research Lab., Washington, DC (US))

1989-01-01T23:59:59.000Z

367

An evaluation of the potential end uses of a Utah tar sand bitumen. [Tar sand distillate  

SciTech Connect (OSTI)

To date the commercial application of tar sand deposits in the United States has been limited to their use as paving materials for county roads, parking lots, and driveways because the material, as obtained from the quarries, does not meet federal highway specifications. The bitumen in these deposits has also been the subject of upgrading and refining studies to produce transportation fuels, but the results have not been encouraging from an economic standpoint. The conversion of tar sand bitumen to transportation fuels cannot compete with crude oil refining. The purposes of this study were two-fold. The first was to produce vacuum distillation residues and determine if their properties met ASTM asphalt specifications. The second was to determine if the distillates could serve as potential feedstocks for the production of aviation turbine fuels. The bitumen used for this study was the oil produced during an in situ steamflood project at the Northwest Asphalt Ridge (Utah) tar sand deposit. Two distillation residues were produced, one at +316/sup 0/C and one at +399/sup 0/C. However, only the lower boiling residue met ASTM specifications, in this case as an AC-30 asphalt. The original oil sample met specifications as an AC-5 asphalt. These residue samples showed some unique properties in the area of aging; however, these properties need to be investigated further to determine the implications. It was also suggested that the low aging indexes and high flow properties of the asphalts may be beneficial for pavements that require good low-temperature performance. Two distillate samples were produced, one at IBP-316/sup 0/C and one at IBP-399/sup 0/C. The chemical and physical properties of these samples were determined, and it was concluded that both samples appear to be potential feedstocks for the production of aviation turbine fuels. However, hydrogenation studies need to be conducted and the properties of the finished fuels determined to verify the prediction. 14 refs., 12 tabs.

Thomas, K.P.; Harnsberger, P.M.; Guffey, F.D.

1986-09-01T23:59:59.000Z

368

The distribution of n-alkanes in partially frozen middle distillate fuels  

SciTech Connect (OSTI)

This work on partially frozen fuels is one of a continuing series of studies on the effect of composition on the freezing properties of hydrocarbon fuels. The method used for this purpose was reported previously. By means of this method the authors were able to determine the composition of the liquid and solid phases in partially frozen mixtures consisting of liquid and of solid crystals plus entrapped liquid. This paper presents the results of this study on five different middle distillate fuels.

Van Winkle, T.L.; Affens, W.A.; Beal, E.J.; Hazlett, R.N.; Guzman, J.

1986-04-01T23:59:59.000Z

369

Prediction of thermal reflection cracking in west Texas  

E-Print Network [OSTI]

for the stress intensity factor, Ck, following Barenblatt (53) is used. z 'e(')4' C = ? / k n o (3-11) where C is the distance away from crack tip and o (g) is the surface e stress inside the crack tip element, i. e. ? o is the thermal stress at the depth... of the studies being conducted on pavement temp- erature cracking have been mainly concerned with the fracture suscepti- bilityy of asphalt concrete under extremely low temperature (3, 4). Find- ings of these studies could not provide satisfactory...

Chang, Hang-Sun

1975-01-01T23:59:59.000Z

370

Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers  

E-Print Network [OSTI]

The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

Nelson, R. E.

1982-01-01T23:59:59.000Z

371

Magnetocaloric properties of distilled gadolinium: Effects of structural inhomogeneity and hydrogen impurity  

SciTech Connect (OSTI)

High-purity Gd prepared by distillation is a structurally inhomogeneous system consisting of needle-shaped crystals of cross section 0.5–2.5??m with near-c-axis orientation embedded in a matrix of nanosized (30–100?nm) grains. By measuring the magnetocaloric effect (MCE) directly, we find that the MCE values differ markedly for the plate-shaped samples cut out of a distillate along and perpendicular to the crystals. The effect of small controlled amounts of impurity (hydrogen) on the properties of distilled Gd is further studied. We observe opposite trends in the MCE response to hydrogen charging with respect to the crystal's orientation within the samples and discuss mechanisms interrelating the unique structural morphology with the impurity behavior. As an overall assessment, the Curie temperatures of ?-GdH{sub x} solid solutions increase from 291?K up to 294?K when increasing hydrogen concentration x from 0 to 0.15. Hydrogenation is found to broaden the ferromagnetic-to-paramagnetic phase transition. Hydrogen-containing specimens demonstrate reversibility of MCE at these temperatures.

Burkhanov, G. S.; Kolchugina, N. B.; Chzhan, V. B.; Chistyakov, O. D. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); Tereshina, E. A. [Institute of Physics ASCR, 18221 Prague (Czech Republic); Tereshina, I. S. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow (Russian Federation); Politova, G. A. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Badurski, D.; Drulis, H. [Institute of Low Temperature and Structure Research PAS, 50-950 Wroclaw (Poland); Paukov, M.; Havela, L. [Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, 12116 Prague (Czech Republic)

2014-06-16T23:59:59.000Z

372

A novel proportional--integral-derivative control configuration with application to the control of batch distillation  

SciTech Connect (OSTI)

The aim of this paper is to propose a novel proportional-integral-derivative (PID) control configuration based on an observer structure. Batch distillation is used as the base case study where the regulated output is the distillate composition. The proposed PID control law is derived in the framework of robust nonlinear control with modeling error compensation techniques. A reduced-order observer is proposed to estimate both the derivative of the regulated output and the underlying modeling error. These observations are subsequently used in a control loop to feedback variations of distillate composition (derivative feedback) and to counteract the effects of modeling errors. It is shown that, under certain conditions, the resulting control law is equivalent to a classical PID controller with an antireset windup scheme. Moreover, the tuning of the controller is performed very easily in terms of a prescribed closed-loop time constant and an estimation time constant. Numerical results are provided for binary and multicomponent separations. Sampled/delayed measurements and several sources of uncertainties are considered in order to provide a realistic test scenario for the proposed control design procedure.

Alvarez-Ramirez, J.; Monroy-Loperena, R.; Cervantes, I.; Morales, A.

2000-02-01T23:59:59.000Z

373

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg; K. M. Shaber

2003-05-01T23:59:59.000Z

374

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect (OSTI)

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

2003-05-21T23:59:59.000Z

375

Improve syngas production using autothermal reforming  

SciTech Connect (OSTI)

Synthesis gas or syngas, i.e., mixtures of CO and H[sub 2], is a major route from hydrocarbons to many important bulk chemicals ranging from acetic acid to ammonia. Syngas conversion uses hydrocarbon feedstocks, steam, O[sub 2] and CO[sub 2], either separately or in combinations. Autothermal reforming (ATR) is a low-investment process using a simple reactor design. The process is soot-free due to burner design and fixed-bed catalyst. Developed in the late '50s, ATR's main application was for ammonia and methanol syntheses. In ammonia plants, hydrogen production was maximized by operating at high H[sub 2]O/C ratios ranging from 2.5 to 3.5 mole/mole. In methanol units, CO[sub 2] recycle adjusted the syngas composition. ATR is also used to co-produce CO and H[sub 2] as separate streams at H[sub 2]O/C ratios of 1.4 to 2.0 mole/mole. recent developments and optimizations allow cost-effective operation at very low H[sub 2]O/C feed ratios to produce CO-rich syngas. The paper describes the process, including feedstocks and reactor design, the chemical reactions, development and improvements to the process, test results, soot formation, burner design, burner testing, applications, thermodynamic calculations, industrial application, noncatalytic and catalytic partial oxidation, and future uses.

Christensen, T.S.; Primdahl, I.I. (Haldor Topsoe, Copenhagen (Denmark))

1994-03-01T23:59:59.000Z

376

A three-dimensional validation of crack curvature in muscovite mica  

SciTech Connect (OSTI)

Experimental and computational efforts focused on characterizing crack tip curvature in muscovite mica. Wedge-driven cracks were propagated under monochromatic light. Micrographs verified the subtle curvature of the crack front near the free surface. A cohesive approach was employed to model mixed-mode fracture in a three-dimensional framework. Finite element calculations captured the crack curvature observed in experiment.

J. C. Hill; J. W. Foulk III; P. A. Klein; E. P. Chen

2001-01-07T23:59:59.000Z

377

Author's personal copy Effect of fluid salinity on subcritical crack propagation in calcite  

E-Print Network [OSTI]

Author's personal copy Effect of fluid salinity on subcritical crack propagation in calcite Fatma Accepted 22 October 2012 Available online 31 October 2012 Keywords: Subcritical crack growth Calcite Salt Damage The slow propagation of cracks, also called subcritical crack growth, is a mechanism of fracturing

378

Automated crack control analysis for concrete pavement construction  

E-Print Network [OSTI]

The focus of this research is on the control of random cracking in concrete paving by using sawcut notch locations in the early stages of construction. This is a major concern in concrete pavement construction. This research also addresses a...

Jang, Se Hoon

2005-11-01T23:59:59.000Z

379

Field Examples of Axial Cracked Bearings in Wind Turbine Gearboxes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Field Examples of Axial Cracked Bearings in Wind Turbine Gearboxes Presented by Paul John Baker of FrontierPro Services at the Wind Turbine Tribology Seminar 2014. 141030 Axial...

380

Modeling of crack initiation, propagation and coalescence in rocks  

E-Print Network [OSTI]

Natural or artificial fracturing of rock plays a very important role in geologic processes and for engineered structures in and on rock. Fracturing is associated with crack initiation, propagation and coalescence, which ...

Gonçalves da Silva, Bruno Miguel

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Thermal cracking in disc brakes Thomas J. Mackin *,1  

E-Print Network [OSTI]

Thermal cracking in disc brakes Thomas J. Mackin *,1 , Steven C. Noe, K.J. Ball, B.C. Bedell, D, or hub, which is connected to the wheel and axle, and an inboard and outboard braking surface

Salvaggio, Carl

382

PLASMA Approximate Dynamic Programming finally cracks the locomotive optimization problem  

E-Print Network [OSTI]

PLASMA ­ Approximate Dynamic Programming finally cracks the locomotive optimization problem schedules and new operating policies. PLASMA is currently running at Norfolk Southern for strategic of PLASMA: Each locomotive is modeled individually, making it possible to capture both horsepower

Powell, Warren B.

383

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

384

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

SciTech Connect (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

385

The use of advanced steam reforming technology for hydrogen production  

SciTech Connect (OSTI)

The demand for supplementary hydrogen production in refineries is growing significantly world-wide as environmental legislation concerning cleaner gasoline and diesel fuels is introduced. The main manufacturing method is by steam reforming. The process has been developed both to reduce the capital cost and increase efficiency, reliability and ease of operation. ICI Katalco`s Leading Concept Hydrogen or LCH process continues this process of improvement by replacing the conventional fired steam reformer with a type of heat exchange reformer known as the Gas Heated Reformer or GHR. The GHR was first used in the Leading Concept Ammonia process, LCA at ICI`s manufacturing site at Severnside, England and commissioned in 1988 and later in the Leading Concept Methanol (LCM) process for methanol at Melbourne, Australia and commissioned in 1994. The development of the LCH process follows on from both LCA and LCM processes. This paper describes the development and use of the GHR in steam reforming, and shows how the GHR can be used in LCH. A comparison between the LCH process and a conventional hydrogen plant is given, showing the benefits of the LCH process in certain circumstances.

Abbishaw, J.B.; Cromarty, B.J. [ICI Katalco, Billingham (United Kingdom)

1996-12-01T23:59:59.000Z

386

Copolymers useful as additives for lowering the cloud point of middle hydrocarbon distillates, and compositions of middle hydrocarbon distillates comprising them  

SciTech Connect (OSTI)

Products useful as additives for lowering the cloud point of middle distillates have a molecular weight from 1,000 to 50,000, and are obtained by reacting a compound of the formula R-Z((CH/sub 2/) /SUB n/ NH) /SUB m/ H or HO-CH/sub 2/-R'-NH/sub 2/ where R is a monovalent saturated aliphatic radical of 1-30 carbon atoms, Z is -NH- or oxygen, n is 2 to 4, m is zero or 1 to 4 and R' is a saturated divalent aliphatic radical of 1-18 carbon atoms, with a copolymer comprising recurrent units (A) from an alkyl ester of an unsaturated monocarboxylic acid and/or a vinyl ester of a saturated monocarboxylic acid, recurrent units (B) from diisobutylene and recurrent units (C) from an unsaturated a,b-dicarboxylic compound.

Durand, J. P.; Damin, B.; Dawans, F.; Leger, R.

1985-03-05T23:59:59.000Z

387

J-integral values for cracks in conventional fatigue specimens  

SciTech Connect (OSTI)

Comprehensive S-N fatigue data has been developed worldwide using conventional low-cycle fatigue tests. Such tests use smooth unnotched specimens subjected to controlled axial deflection or strain ranges. The tests must be run in the plastic regime in order to achieve the required cycles-to-failure. Recent developments have highlighted the need to understand and interpret the significance of the resulting strain range vs. cycles to failure data in terms of crack initiation and propagation. Since conventional fatigue tests are conducted in the plastic regime, linear elastic fracture mechanics cannot be used to accurately quantify crack growth in such tests. Elastic-plastic J-integral theory, however, has been shown to provide excellent correlations of crack growth in the elastic, elastic-plastic and grossly-plastic regimes for a wide range of geometric and loading conditions. The authors are applying this theory to the low-cycle fatigue specimen crack behavior. As cracks progress in conventional fatigue specimens, bending becomes significant. Since fatigue testing machines are quite stiff relative to the small fatigue specimens, the ends of the specimen are constrained to remain parallel, and this reduces bending in the cracked cross-section. Three-dimensional finite element elastic-plastic analyses are required to include these constraints in the J-integral solutions.

O`Donnell, T.P.; O`Donnell, W.J. [O`Donnell Consulting Engineers, Pittsburgh, PA (United States)

1996-12-01T23:59:59.000Z

388

Assessment of crack opening area for leak rates  

SciTech Connect (OSTI)

This paper outlines the background to recommended crack opening area solutions given in a proposed revision to leak before break guidance for the R6 procedure. Comparisons with experimental and analytical results are given for some selected cases of circumferential cracks in cylinders. It is shown that elastic models can provide satisfactory estimations of crack opening displacement (and area) but they become increasingly conservative for values of L{sub r} greater than approximately 0.4. The Dugdale small scale yielding model gives conservative estimates of crack opening displacement with increasing enhancement for L{sub r} values greater than 0.4. Further validation of the elastic-plastic reference stress method for up to L{sub r} values of about 1.0 is presented by experimental and analytical comparisons. Although a more detailed method, its application gives a best estimate of crack opening displacement which may be substantially greater than small scale plasticity models. It is also shown that the local boundary conditions in pipework need to be carefully considered when evaluating crack opening area for through-wall bending stresses resulting from welding residual stresses or geometry discontinuities.

Sharples, J.K.; Bouchard, P.J.

1997-04-01T23:59:59.000Z

389

ffe1098 FFE March 7, 2007 21:55 Crack tip displacements of microstructurally small cracks in 316L steel  

E-Print Network [OSTI]

steel and their dependence on crystallographic orientations of grains I. SIMONOVSKI1 , KARL orientations on a short Stage I surface crack in a 316L stainless steel. The analysis is based on a plane

Cizelj, Leon

390

Roles of grain boundaries in cleavage cracking and thermal crack arrest experiments in iron-silicon alloy  

E-Print Network [OSTI]

High-angle grain boundaries in steel offer an important resistance to the propagation of cleavage cracks that affects the fracture toughness and can modulate the ductile-to-brittle transition temperature of fracture downward. ...

Qiao, Yu, 1972-

2002-01-01T23:59:59.000Z

391

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Broader source: Energy.gov (indexed) [DOE]

leg) 8 2004 DEER Conference September 2, 2004 Experimental Setup NOx Trap Engine Reformer Diesel Air Power NOx Trap NOx Trap Engine NOx Trap Diesel Diesel Fuel Reformer Setup...

392

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network [OSTI]

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

393

Bargaining in the Chinese Leviathan: An Examination on the Steel Industry after China's SOE Reform  

E-Print Network [OSTI]

This thesis centers on the competitions between enterprises in the steel industry in China after the SOE (state-owned enterprises) reform, which can be viewed as a case for mass economic reforms within Chinese Leviathan. To examine the effect...

Li, Zichao

2010-06-28T23:59:59.000Z

394

The Lessons of Practice: Domestic Policy Reform as a Way to Address...  

Open Energy Info (EERE)

Practice: Domestic Policy Reform as a Way to Address Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Lessons of Practice: Domestic Policy Reform as a...

395

Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

396

A Comparative Study between Co and Rh for Steam Reforming of...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

between Co and Rh for Steam Reforming of Ethanol. A Comparative Study between Co and Rh for Steam Reforming of Ethanol. Abstract: Rh and Co-based catalyst performance was compared...

397

Voluntary Disclosure and Information Asymmetry: Evidence from the 2005 Securities Offering Reform  

E-Print Network [OSTI]

In 2005, the Securities and Exchange Commission enacted the Securities Offering Reform (Reform), which relaxes “gun-jumping” restrictions, thereby allowing firms to more freely disclose information before equity offerings. ...

SHROFF, NEMIT

398

Globalization, Economic Reform, and Structural Price Transmission: SAM Decomposition Techniques with an empirical application to Vietnam  

E-Print Network [OSTI]

of Copenhagen and RDRC ABSTRACT Globalization poses special challenges for economies in transition, particularly1 Globalization, Economic Reform, and Structural Price Transmission: SAM Decomposition Techniques undermine reform and structural adjustments efforts in this important emerging Asian economy. Key words

Kammen, Daniel M.

399

E-Print Network 3.0 - agricultural price reforms Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

T Y J A N U A R Y 1 1 , 2 0 1 0 You Get What You Pay For: The Obama Approach to Health Care Reform 12... fundamental issues in health care reform 12;Coverage is actually quite...

400

From negotiation to auction : Land-Conveyance Reform in China and its institutional and social impacts  

E-Print Network [OSTI]

The land market and the associated land-development-control mechanism in China have been experiencing a series of reforms since the 1990s, of which Land Conveyance Reform (LCR) in 2004 is a very recent and an important ...

Chen, Zhiyu (Zhiyu Jerry)

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Strengthening, Crack Arrest And Multiple Cracking In Brittle Materials Using Residual Stresses.  

DOE Patents [OSTI]

Embodiments include a method for forming a glass which displays visible cracking prior to failure when subjected to predetermined stress level that is greater than a predetermined minimum stress level and less than a failure stress level. The method includes determining a critical flaw size in the glass and introducing a residual stress profile to the glass so that a plurality of visible cracks are formed prior to failure when the glass is subjected to a stress that is greater than the minimum stress level and lower than the critical stress. One method for forming the residual stress profile includes performing a first ion exchange so that a first plurality of ions of a first element in the glass are exchanged with a second plurality of ions of a second element that have a larger volume than the first ions. A second ion exchange is also performed so that a plurality of the second ions in the glass are exchanged back to ions of the first element.

Green, David J. (State College, PA); Sglavo, Vincenzo M. (Roncegno, IT); Tandon, Rajan (Fremont, CA)

2003-02-11T23:59:59.000Z

402

Producing Clean Syngas via Catalytic Reforming for Fuels Production  

SciTech Connect (OSTI)

Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

2012-01-01T23:59:59.000Z

403

Steam methane reforming in molten carbonate salt. Final report  

SciTech Connect (OSTI)

This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

Erickson, D.C.

1996-05-01T23:59:59.000Z

404

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents [OSTI]

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

405

High performance internal reforming unit for high temperature fuel cells  

DOE Patents [OSTI]

A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

2008-10-07T23:59:59.000Z

406

Vacuum Distillation  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uraniumE. GreatVENTURADay)

407

Heat exchanger for fuel cell power plant reformer  

DOE Patents [OSTI]

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

1988-01-01T23:59:59.000Z

408

DOES HOSPITAL COMPETITION SAVE LIVES? EVIDENCE FROM THE ENGLISH NHS PATIENT CHOICE REFORMS*  

E-Print Network [OSTI]

DOES HOSPITAL COMPETITION SAVE LIVES? EVIDENCE FROM THE ENGLISH NHS PATIENT CHOICE REFORMS* Zack Cooper, Stephen Gibbons, Simon Jones and Alistair McGuire Recent substantive reforms to the English with fixed prices. This study investigates whether these reforms led to improvements in hospital quality. We

Mateo, Jill M.

409

Even if it's not Bribery: The Case for Campaign Finance Reform  

E-Print Network [OSTI]

Even if it's not Bribery: The Case for Campaign Finance Reform Brendan Daley Erik Snowberg Duke reform alleviates this phenomenon and improves voter welfare at the expense of politicians. Thus, we expect successful politicians to oppose true campaign finance reform. We also show our model

Jensen, Grant J.

410

Copyright reform on the EU level European Network for Copyright in support of  

E-Print Network [OSTI]

Copyright reform on the EU level European Network for Copyright in support of Education and Budapest Business School #12;Copyright reform on the EU level What can science and education expect from a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR

Kuhlen, Rainer

411

BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA  

E-Print Network [OSTI]

107 BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA OR THE SEARCH FOR A "MODERN" of the country. The dominant role of secularist elites paved the way for the "reform of Islam." This process in the organization and reform of official religious institutions. For example, it interfered in the organization

Boyer, Edmond

412

WELLCOME TRUST CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England  

E-Print Network [OSTI]

WELLCOME TRUST CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England April 2013 1 Department for Education: Reform of the National Curriculum in England CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England April 2013 2

Rambaut, Andrew

413

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge  

E-Print Network [OSTI]

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

Mallinson, Richard

414

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa  

E-Print Network [OSTI]

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa , N. Baillya , M was designed to be operated in pure methane, without reforming or carrier gas. The fuel cell was built up from-CGO catalytic layer. The operation principle is based on Gradual Internal Reforming. After an initiation in H2

Boyer, Edmond

415

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual's GCSE reform consultation -August 2013  

E-Print Network [OSTI]

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual's GCSE reform consultation - August 2013 1 Ofqual: GCSE reform consultation Response by the Wellcome Trust August 2013 Key points and indirect practical assessment in its reform proposals. The total contribution of direct and indirect

Rambaut, Andrew

416

August 15, 2013 Bargaining Update 8: UC stresses fair compensation and reasonable pension reform  

E-Print Network [OSTI]

reform UC stressed with the California Nurses Association on Aug. 6-8, 2013 the need to reach a fair's market. UC's pension reform proposal calls for: · Employees hired before July 1, 2013: UC would in substantive negotiations over responsible and necessary pension reform. CNA has not accepted UC's pension

Leistikow, Bruce N.

417

Inequality and the Politics of Social Policy Implementation: Gender, Age and Chile's 2004 Health Reforms  

E-Print Network [OSTI]

Reforms CHRISTINA EWIG and GASTO´ N A. PALMUCCI * University of Wisconsin-Madison, USA Summary implementation. We examine the 2004 Chilean health reforms that sought to regulate private insurers, and measure their effects on gender and age inequality. We find that reforms intended to decrease these inequalities largely

Wisconsin at Madison, University of

418

Using a CSCL-Driven Shift in Agency to Undertake Educational Reform1  

E-Print Network [OSTI]

1 Using a CSCL-Driven Shift in Agency to Undertake Educational Reform1 Mark Guzdial1, Matthew educational reform efforts, but there are many challenges to face before achieving that vision. Two attempting to use this tool to leverage a particular kind of educational reform goal: Achieving integration

Guzdial, Mark

419

SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR  

E-Print Network [OSTI]

process of a solar reformer of dry methane reforming was proposed to operate in a temperature range of 600SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR Khalid Al-Ali 1 including lower melting point, thermal and chemical stability, acting simultaneously as heat transport

Paris-Sud XI, Université de

420

THE CALIFORNIAN MODEL AS THE PARADIGM FOR SECOND GENERATION REFORMS IN LATINAMERIC  

E-Print Network [OSTI]

THE CALIFORNIAN MODEL AS THE PARADIGM FOR SECOND GENERATION REFORMS IN LATINAMERIC Hugh Rudnick for a second stage of reform, establishing highly flexible mechanisms of decentralised exchanges, and achieving about the validity of this new paradigm for second stage reforms. They question themselves

Catholic University of Chile (Universidad Católica de Chile)

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Method for improving catalyst function in auto-thermal and partial oxidation reformer-based processors  

DOE Patents [OSTI]

The invention provides a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H.D.; Ahluwalia, Rajesh K.

2014-08-26T23:59:59.000Z

422

2007 DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting  

E-Print Network [OSTI]

Biogas reformation Shift reactorShift reactor Selective oxidation of COSelective oxidation of CO Fuel cellFuel cell2007 DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts Hua Song Lingzhi Zhang Umit S

423

Fiscal Sustainability and Retirement Security: A Reform Proposal for the Illinois State Universities  

E-Print Network [OSTI]

situation: health care and retirement. First, Medicaid expenditures, already a substantial share of state1 Fiscal Sustainability and Retirement Security: A Reform Proposal for the Illinois State errors, are those of the authors alone. I.The Urgent Need for Reform Public pension reform is a national

Illinois at Chicago, University of

424

PHS 650 Summer 2011 Page 1 State-Level Health System and Coverage Reform 2011  

E-Print Network [OSTI]

and describe two state-based reforms underway in Wisconsin's health care industry. Topics/Readings The Big Patient Protection and Affordable Care Act Current State-Level Trends and Health Reforms The SyllabusPHS 650 Summer 2011 Page 1 State-Level Health System and Coverage Reform 2011 Course Overview

Sheridan, Jennifer

425

Health Care Reform: What School Mental Health Professionals Need to Know  

E-Print Network [OSTI]

Health Care Reform: What School Mental Health Professionals Need to Know On March 23, 2010, President Obama signed comprehensive health care reform, the Patient Protection and Affordable Care Act (ACA), into law (P.L. 111-148). This major reform to health care certainly has had and will continue to have

Weber, David J.

426

The effect of reformate gas enrichment on extinction limits and NOX formation  

E-Print Network [OSTI]

premixed combustion. When the reformate gas is added, the formation of NO is reduced in a near advantage of the reformate gas enriched lean premixed combustion is that it greatly reduces the formation combustion; Fuel enrichment; NOX; Extinction limit; Reformate gas 1. Introduction Lean premixed combustion

Gülder, �mer L.

427

Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant  

SciTech Connect (OSTI)

When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

Gambert, G.

1996-12-31T23:59:59.000Z

428

,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: EnergyShale ProvedTexas"Brunei (Dollars perReserves (Billion Cubic Feet)"+ LeaseDistillate

429

Method and apparatus for assessing distillate-fuel stability by oxygen overpressure  

SciTech Connect (OSTI)

Reactions leading to insoluble sediments formation in distillate fuel are accelerated by forcing oxygen into solution in the fuel at pressures of between about 90 and 110 psig and then stressing the fuel under conditions of accelerated storage at temperatures of between about 40 C to 100 C. The method then makes use of gravimetric determination of the total insoubles formed. The stability of the fuel over a period of time as well as its comparitive stability to other fuels can then be predicted from the amount of insolubles formed. The method can be carried out by using a specialized pressure vessel.

Hardy, D.R.; Beal, E.J.; Burnett, J.C.

1989-06-27T23:59:59.000Z

430

Determination of crack morphology parameters from service failures for leak-rate analyses  

SciTech Connect (OSTI)

In leak-rate analyses described in the literature, the crack morphology parameters are typically not well agreed upon by different investigators. This paper presents results on a review of crack morphology parameters determined from examination of service induced cracks. Service induced cracks were found to have a much more tortuous flow path than laboratory induced cracks due to crack branching associated with the service induced cracks. Several new parameters such as local and global surface roughnesses, as well as local and global number of turns were identified. The effect of each of these parameters are dependent on the crack-opening displacement. Additionally, the crack path is typically assumed to be straight through the pipe thickness, but the service data show that the flow path can be longer due to the crack following a fusion line, and/or the number of turns, where the number of turns in the past were included as a pressure drop term due to the turns, but not the longer flow path length. These parameters were statistically evaluated for fatigue cracks in air, corrosion-fatigue, IGSCC, and thermal fatigue cracks. A refined version of the SQUIRT leak-rate code was developed to account for these variables. Sample calculations are provided in this paper that show how the crack size can vary for a given leak rate and the statistical variation of the crack morphology parameters.

Wilkowski, G.; Ghadiali, N.; Paul, D. [Battelle Memorial Institute, Columbus, OH (United States)] [and others

1997-04-01T23:59:59.000Z

431

Solar Reforming of Carbon Dioxide to Produce Diesel Fuel  

SciTech Connect (OSTI)

This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

Dennis Schuetzle; Robert Schuetzle

2010-12-31T23:59:59.000Z

432

High-Resolution Characterizations of Stress-Corrosion Cracks in Austenitic Stainless Steel from Crack Growth Tests in BWR-Simulated Environments  

SciTech Connect (OSTI)

Mechanisms controlling environmental degradation and cracking in light-water-reactor (LWR) systems have been investigated by analytical transmission electron microscopy (ATEM) of cracks and crack tips. The current work focuses on intergranular stress corrosion cracking (IGSCC) of 300-series, austenitic stainless steels in high-temperature LWR environments. Comparisons are made between cold-worked 304SS containing stress-corrosion cracks produced in a simulated boiling-water-reactor (BWR) environment during crack-growth tests, and a 304SS core component with cracks produced during 26-year BWR service. Similar corrosion products consisting of duplex-layered spinel oxides were found along the walls of open cracks in the service and laboratory test samples. These oxide films consisted of oriented Cr-rich spinel up to ~30 nm thick along the metal crack walls and large-grained Fe-rich spinel at the crack centers. Cracks in the service sample were generally more filled with oxide, perhaps reflecting the much longer times available for corrosion to occur after the crack passage. Crack tips in the BWR top-guide sample exhibited unique and unexpected structures with oxide-filled cracks <10 nm wide ending in finger-like attack and locally “dealloyed” zones of Fe/Cr-depleted, Ni-rich metal. Alloy compositions measured at numerous crack tips were 40 wt% Fe, 4 wt% Cr and 55 wt% Ni immediately ahead of the degradation front versus approximately 70 wt% Fe, 19 wt% Cr and 9 wt% Ni in the bulk 304SS. Laboratory samples with cracks grown over much shorted times (~1.5 months) did not show the distinctive crack tip structures or strong Ni enrichment in the metal ahead of the crack tips as for the service sample. This suggests that although selective oxidation processes occur during degradation, significant composition differences may only develop after crack propagation has slowed or stopped. Additional nanometer-scale measurements elucidating corrosion processes occurring during crack advance are presented to provide insights into mechanisms controlling IGSCC.

Bruemmer, Stephen M.; Thomas, Larry E.

2005-07-20T23:59:59.000Z

433

ISSN 1745-9648 The Impact of Electricity Market Reform  

E-Print Network [OSTI]

ISSN 1745-9648 The Impact of Electricity Market Reform on Consumers by Catherine Waddams Price ESRC, University of East Anglia CCP Working Paper 08-7 Abstract: We examine the effect of current electricity, where household expenditure surveys and electricity tariffs are available, we analyse the effects

Feigon, Brooke

434

French public management reform: an evaluation Gilles Jeannot, Danile Guillemot  

E-Print Network [OSTI]

shared opposition in principle to certain New Public Management precepts (especially benchmarking1 French public management reform: an evaluation Gilles Jeannot, Danièle Guillemot International journal of public sector management, vol 26, n° 4, 2013, p. 283-297 Comparative research depicts France

Paris-Sud XI, Université de

435

Argonne Electrochemical Technology Program Sulfur removal from reformate  

E-Print Network [OSTI]

Argonne Electrochemical Technology Program Sulfur removal from reformate Xiaoping Wang, Theodore Krause, and Romesh Kumar Chemical Engineering Division Argonne National Laboratory Hydrogen, Fuel Cells, and Infrastructure Technologies 2003 Merit Review Berkeley, CA May 19-22, 2003 #12;Argonne Electrochemical Technology

436

Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming  

E-Print Network [OSTI]

-gas-shift catalytic membrane reactor, and (2) a multi-layer design for bioethanol reforming. A two-dimensional model is developed to describe reaction and diffusion in the catalytic membrane coupled with plug-flow equations in the retentate and permeate volumes using...

Kuncharam, Bhanu Vardhan

2013-11-26T23:59:59.000Z

437

DFMA Cost Estimates of Fuel-Cell/Reformer Systems  

E-Print Network [OSTI]

Page 1 DFMA Cost Estimates of Fuel-Cell/Reformer Systems at Low/Medium/High Production Rates Brian system · Direct hydrogen fuel cell system (with 5kpsi H2 storage) 2. Determine costs for system ·Fuel cell stacks ·Air supply and humidification ·Thermal management ·Water management ·Fuel Supply

438

Steam Reforming of Low-Level Mixed Waste  

SciTech Connect (OSTI)

Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

None

1998-01-01T23:59:59.000Z

439

ISSN 1745-9648 Electricity Reform in Serbia  

E-Print Network [OSTI]

ISSN 1745-9648 Electricity Reform in Serbia by Sandra Jednak Faculty of Organizational Sciences in Serbia have been started, and certain results were achieved. But, the electric power infrastructure decided whether the Serbian Electric Power Industry will be privatised, and if it is privatised which

Feigon, Brooke

440

ISSN 1745-9648 Electricity Reform in Romania  

E-Print Network [OSTI]

ISSN 1745-9648 Electricity Reform in Romania by Oana Diaconu Department of Economics and Management-11 Abstract: Romania is a net exporter of electricity to the SE Europe region. Its performance of this role for international transmission. Romania has committed itself to an electricity restructuring plan that includes

Feigon, Brooke

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

The Clean Development Mechanism and Power Sector Reforms in Developing  

E-Print Network [OSTI]

regions include stimulating private sector financing, increasing operational and managerial efficiencies and lowering electricity tariffs #12;The CDM and renewable energy · Power sector reforms could potentially require higher investments for electricity generation than conventional fuel projects · Can also offer

442

ISSN 1745-9648 Potential Impact of Electricity Reforms on  

E-Print Network [OSTI]

reforming her energy sector in line with EU Energy Acquis since 2001. Introducing a cost reflective tariff Bagdadioglu Department of Public Finance, Hacettepe University & Alparslan Basaran Department of Public for price changes, and consumption information from the 2003 Turkish Household Expenditure Survey. Turkey

Feigon, Brooke

443

Integrated autothermal reactor concepts for oxidative coupling and reforming of  

E-Print Network [OSTI]

#12;Integrated autothermal reactor concepts for oxidative coupling and reforming of methane #12-90-365-2985-3, DOI 10.3990/1.9789036529853 #12;INTEGRATED AUTOTHERMAL REACTOR CONCEPTS FOR OXIDATIVE COUPLING . . . . . . . . . . . . . . . . . . . . 31 2.5 Dual function catalyst particle . . . . . . . . . . . . . . . . . . . . . . 34 2.6 Autothermal

Twente, Universiteit

444

The Role of Informatics in Health Care Reform  

E-Print Network [OSTI]

The Role of Informatics in Health Care Reform Yueyi I. Liu, MD, PhD, Daniel L. Rubin, MD, MS Improving health care quality while simultaneously reducing cost has become a high priority of health care (such as radiation dose tracking) and quality initiatives. Key Words: Informatics; health care. ª

Rubin, Daniel L.

445

Healthcare Reform in Texas: How the Affordable Care Act (ACA)  

E-Print Network [OSTI]

Healthcare Reform in Texas: How the Affordable Care Act (ACA) Will Impact Small Employer Health requirements, the function of health insurance exchanges and the future of employer-sponsored health insurance Shield of Texas Katrina Daniel Associate Commissioner, Life, Accident and Health Section Regulatory

O'Toole, Alice J.

446

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide  

E-Print Network [OSTI]

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su University INTRODUCTION Energy consumption continues to skyrocket worldwide. Biodiesel is a renewable fuel as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel

Collins, Gary S.

447

First Generation Indian External Sector Reforms in Context  

E-Print Network [OSTI]

India's first generation external sector reforms are a fascinating case study of emergence from a post-Independence socialist-style economy to the world’s largest free market democracy. Part I of this article reviews the Indian license Raj system...

Bhala, Raj

2013-01-01T23:59:59.000Z

448

Influence of cracking on the diffusion properties of cement-based materials. Part I: Influence of continuous cracks on the steady-state regime  

SciTech Connect (OSTI)

The influence of traversing cracks on the steady-state diffusion properties of concrete was studied. The effect of both anisotropic and isotropic crack networks was first theoretically assessed using an analytical approach. To simplify the transport equations, cracks were assumed to be of uniform size and evenly distributed on a one- or two-dimensional grid. Results of the theoretical analysis were then compared to experimental data. Both series of results indicate that cracking can markedly alter the diffusion properties of the material and favor the penetration (or the leaching) of drifting species. A simple method to predict the effect of cracking on the concrete diffusivity is proposed. Predictions are made on the basis of two parameters: the crack density and the mean crack aperture. This method can provide a first estimate of the diffusion properties of severely damaged concrete elements.

Gerard, B.; Marchand, J.

2000-01-01T23:59:59.000Z

449

Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry  

E-Print Network [OSTI]

Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

Colin J. Trout; Kenneth R. Brown

2015-01-29T23:59:59.000Z

450

Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry  

E-Print Network [OSTI]

Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

Colin J. Trout; Kenneth R. Brown

2015-01-07T23:59:59.000Z

451

Optimum Requirements for the Synthesis of Biodiesel Using Fatty Acid Distillates  

E-Print Network [OSTI]

The optimum requirements of temperature, retention time, mole ratio of reactants and catalyst for the direct synthesis of biodiesel from fatty acid distillates of palm kernel oil using tetraoxosulphate (VI) acid as catalyst was studied. The following parameters were used for the efficient and economic production of biodiesel: eight (8) moles of methanol per mole of fatty acid, 0.06 mole of tetraoxosulphate (VI) acid per mole of fatty acid, a retention time of sixty (60) minutes and reaction temperature of 65 OC. And this gave a maximum percentage yield of 98.4. Other parameters obtained include: an acid value of 0.1683 mg KOH/g, iodine value of 15.3549, flash point of 209 OC, viscosity of 3.7957 mm2s-1, density of 0.8776 g cm-3, water content of 400.05 mg kg-1, soap content of 2.30 mg/kg, and ester content of 98.804 %. From the obtained parameters, the biodiesel produced from fatty acid distillates of palm kernel oil reaches prescribed international standards for biodiesel production.

Akunna E. Ejele

452

Wellcome Trust SUBMISSION OF EVIDENCE Wellcome Trust response to the NHS Future Forum inquiry into the NHS reforms  

E-Print Network [OSTI]

into the NHS reforms October 2011 1 NHS Future Forum: Inquiry into the NHS reforms Response by the Wellcome focus primarily on the impact of the reforms on health research and innovation, which run throughout the Future Forum's four themes. 3. The reforms of the NHS and public health systems must bring about

Rambaut, Andrew

453

Wellcome Trust SUBMISSION OF EVIDENCE Wellcome Trust response to Department for Education: Reforming Key Stage 4 qualifications  

E-Print Network [OSTI]

: Reforming Key Stage 4 qualifications December 2012 Department for Education: Reforming Key Stage 4 science skills. 2. We are pleased to have the opportunity to respond to the consultation on reforms to Key consultations on the reform to curriculum and assessment at various stages of schooling. There is an opportunity

Rambaut, Andrew

454

Stress-corrosion cracking in BWR and PWR piping  

SciTech Connect (OSTI)

Intergranular stress-corrosion cracking of weld-sensitized wrought stainless steel piping has been an increasingly ubiquitous and expensive problem in boiling-water reactors over the last decade. In recent months, numerous cracks have been found, even in large-diameter lines. A number of potential remedies have been developed. These are directed at providing more resistant materials, reducing weld-induced stresses, or improving the water chemistry. The potential remedies are discussed, along with the capabilities of ultrasonic testing to find and size the cracks and related safety issues. The problem has been much less severe to date in pressurized-water reactors, reflecting the use of different materials and much lower coolant oxygen levels.

Weeks, R.W.

1983-07-01T23:59:59.000Z

455

Hydrocarbon cracking with yttrium exchanged zeolite y catalyst  

SciTech Connect (OSTI)

A process is described for cracking a gas oil boiling range hydrocarbon feedstock comprising the step of contacting the feedstock in a catalytic cracking zone under catalytic cracking conditions to produce convulsion products comprising gasoline with a catalyst composition. The process comprises: a Y crystalline aluminosilicate zeolite, having the structure of faujasite and having uniform pore diameters and a silica to alumina mole ratio of at least about 5; an inorganic oxide matrix; and the zeolite having been ion exchanged with a mixture of rare earths prior to compositing with the matrix; and the zeolite having been subsequently further ion exchanged with yttrium following compositing with the matrix, whereby the catalyst composition contains 0.30 to 3.0 wt% yttrium.

Lochow, C.F.; Kovacs, D.B.

1987-05-12T23:59:59.000Z

456

Protocol development for evaluation of commercial catalytic cracking catalysts  

SciTech Connect (OSTI)

A complete, new set of testing protocols has been developed for qualification of catalysts for Ashland's commercial catalytic cracking units. The objective of this test development is to identify new generations of improved cracking catalysts. Prior test protocols have classically utilized microactivity (MAT) testing of steamed virgin catalysts, while more advanced methods have utilized fixed fluid bed and/or circulating pilot units. Each of these techniques, however, have been limited by their correlation to commercial operations, weaknesses in metallation and preparation of pseudo-equilibrium catalysts, and mechanical constraints on the use of heavy, vacuum bottoms-containing feedstocks. These new protocols have been baselined, compared to commercial Ashland results on known catalytic cracking catalysts, and utilized to evaluate a range of potentially new catalyst samples.

Mitchell, M.M. Jr.; Moore, H.F. (Ashland Petroleum Co., KY (USA))

1988-09-01T23:59:59.000Z

457

Method for fabrication of crack-free ceramic dielectric films  

DOE Patents [OSTI]

The invention provides a process for forming crack-free dielectric films on a substrate. The process comprise the application of a dielectric precursor layer of a thickness from about 0.3 .mu.m to about 1.0 .mu.m to a substrate. The deposition is followed by low temperature heat pretreatment, prepyrolysis, pyrolysis and crystallization step for each layer. The deposition, heat pretreatment, prepyrolysis, pyrolysis and crystallization are repeated until the dielectric film forms an overall thickness of from about 1.5 .mu.m to about 20.0 .mu.m and providing a final crystallization treatment to form a thick dielectric film. Also provided was a thick crack-free dielectric film on a substrate, the dielectric forming a dense thick crack-free dielectric having an overall dielectric thickness of from about 1.5 .mu.m to about 20.0 .mu.m.

Ma, Beihai; Balachandran, Uthamalingam; Chao, Sheng; Liu, Shanshan; Narayanan, Manoj

2014-02-11T23:59:59.000Z

458

Weld solidification cracking in 304 to 204L stainless steel  

SciTech Connect (OSTI)

A series of annulus welds were made between 304 and 304L stainless steel coaxial tubes using both pulsed laser beam welding (LBW) and pulsed gas tungsten arc welding (GTAW). In this application, a change in process from pulsed LBW to pulsed gas tungsten arc welding was proposed to limit the possibility of weld solidification cracking since weldability diagrams developed for GTAW display a greater range of compositions that are not crack susceptible relative to those developed for pulsed LBW. Contrary to the predictions of the GTAW weldability diagram, cracking was found.This result was rationalized in terms of the more rapid solidification rate of the pulsed gas tungsten arc welds. In addition, for the pulsed LBW conditions, the material compositions were predicted to be, by themselves, 'weldable' according to the pulsed LBW weldability diagram. However, the composition range along the tie line connecting the two compositions passed through the crack susceptible range. Microstructurally, the primary solidification mode (PSM) of the material processed with higher power LBW was determined to be austenite (A), while solidification mode of the materials processed with lower power LBW apparently exhibited a dual PSM of both austenite (A) and ferrite-austenite (FA) within the same weld. The materials processed by pulsed GTAW showed mostly primary austenite solidification, with some regions of either primary austenite-second phase ferrite (AF) solidification or primary ferrite-second phase austenite (FA) solidification. This work demonstrates that variations in crack susceptibility may be realized when welding different heats of 'weldable' materials together, and that slight variations in processing can also contribute to crack susceptibility.

Hochanadel, Patrick W [Los Alamos National Laboratory; Lienert, Thomas J [Los Alamos National Laboratory; Martinez, Jesse N [Los Alamos National Laboratory; Johnson, Matthew Q [Los Alamos National Laboratory

2010-09-15T23:59:59.000Z

459

Weld solidification cracking in 304 to 304L stainless steel  

SciTech Connect (OSTI)

A series of annulus welds were made between 304 and 304L stainless steel coaxial tubes using both pulsed laser beam welding (LBW) and pulsed gas tungsten arc welding (GTAW). In this application, a change in process from pulsed LBW to pulsed gas tungsten arc welding was proposed to limit the possibility of weld solidification cracking since weldability diagrams developed for GTAW display a greater range of compositions that are not crack susceptible relative to those developed for pulsed LBW. Contrary to the predictions of the GTAW weldability diagram, cracking was found. This result was rationalized in terms of the more rapid solidification rate of the pulsed gas tungsten arc welds. In addition, for the pulsed LBW conditions, the material compositions were predicted to be, by themselves, 'weldable' according to the pulsed LBW weldability diagram. However, the composition range along the tie line connecting the two compositions passed through the crack susceptible range. Microstructurally, the primary solidification mode (PSM) of the material processed with higher power LBW was determined to be austenite (A), while solidification mode of the materials processed with lower power LBW apparently exhibited a dual PSM of both austenite (A) and ferrite-austenite (FA) within the same weld. The materials processed by pulsed GT A W showed mostly primary austenite solidification, with some regions of either primary austenite-second phase ferrite (AF) solidification or primary ferrite-second phase austenite (FA) solidification. This work demonstrates that variations in crack susceptibility may be realized when welding different heats of 'weldable' materials together, and that slight variations in processing can also contribute to crack susceptibility.

Hochanadel, Patrick W [Los Alamos National Laboratory; Lienert, Thomas J [Los Alamos National Laboratory; Martinez, Jesse N [Los Alamos National Laboratory; Martinez, Raymond J [Los Alamos National Laboratory; Johnson, Matthew Q [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

460

Reflective Cracking Study: First-level Report on HVS Testing on Section 588RF - 90 mm AR4000-DOverlay  

E-Print Network [OSTI]

testing being performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the results of the fourth HVS reflective cracking testingconcrete. It describes the results of the fourth HVS reflective cracking testing

Jones, David; Wu, R; Harvey, John T

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Reflective Cracking Study: First-Level Report on HVS Testing on Section 590RF - 90 mm MB4-G Overlay  

E-Print Network [OSTI]

testing being performed to validate Caltrans overlay strategies for the rehabilitation of cracked asphalt concrete.concrete. It describes the results of the first HVS reflective cracking testingconcrete. It describes the results of the first HVS reflective cracking testing

Jones, David; Tsai, Bor-Wen; Harvey, John T

2008-01-01T23:59:59.000Z

462

HH22 Reformer, Fuel Cell Power Plant,Reformer, Fuel Cell Power Plant, & Vehicle Refueling System& Vehicle Refueling System  

E-Print Network [OSTI]

sufficient hydrogen demand develops. #12;4 Relevant DOE Program Objectives Reduce dependence on foreign oil Promote use of diverse, domestic energy resources ­ Natural gas reformation Develop and demonstrate on test fill tank, CNG/H2 ICE vehicles and H2 Fuel Cell vehicles. Fuel dispensing integrated with City

463

Model of crack propagation in a clay soil  

E-Print Network [OSTI]

of independent variables for maximum R to determine A for crack de th, 2 Number of variables in model (p) R Variables in model 0. 703913 0. 916176 0. 988151 0. 997207 0. 999328 H*CLrH*M~CL H, H*M, H~M*CL H, CL, H*M, H*M*CL H, CL, H"M, H*CL, H...: Agricultural Engineering MODEL OF CRACK PROPAGATION IN A CLAY SOIL A Thesis by PATRICK EDWIDGE CARRIERE Approved as to style and content by: John L. Nieber (Chairman of Committee) Donald L. Reddell (Member) Kirk W, Brown (Member ) Wilbert H...

Carriere, Patrick Edwidge

2012-06-07T23:59:59.000Z

464

Stress relief cracking in creep resisting low alloy ferritic steels.  

E-Print Network [OSTI]

, for their inspiration by example, to Messrs. R.Turkentine, S. Charter, D. Evans, P.Hull and D.Duke, for their guidance and assistfu.ce during all stages of the experi- mental work; also to Professor G.S.Kent, Dr.M.N.Mct1orris, Professor T.P.Hughes, Dr... >eased and inter>granular> cavitation cracking increased. Indeed the mixed upper> and lower> bainite matr>ix pr>oduced by oil quenching, showed ver>y br>ittle behaviOUr> associated with little opening of the intergranular cr>acKs. The implication...

Tait, Robert Andrew

1976-10-26T23:59:59.000Z

465

Stress Corrosion Crack Detection on HU-25 Guardian Aircraft  

SciTech Connect (OSTI)

Several ultrasonic inspection methods were developed at the Federal Aviation Administration's Airworthiness Assurance NDI Validation Center (AANC) to easily and rapidly detect hidden stress corrosion cracks in all vertical windshield posts on the US Coast Guard (USCG) HU-25 Guardian aircraft. The inspection procedure locates cracks as small as 2.0 millimeters emanating from internal fastener holes and determines their length. A test procedure was developed and a baseline assessment of the USCG fleet was conducted. Inspection results on twenty-five aircraft revealed a good correlation with results made during subsequent structural disassembly and visual inspection.

Blackmon, R.; Huffman, J.; Mello, C.W.; Moore, D.G.; Walkington, P.D.

1999-02-17T23:59:59.000Z

466

Energy Efficiency Improvement in the Petroleum Refining Industry  

E-Print Network [OSTI]

i.e. crude distillation, hydrotreating, reforming, vacuumthe severity and in hydrotreating the treated feed may

Worrell, Ernst; Galitsky, Christina

2005-01-01T23:59:59.000Z

467

Monitoring Cracking of a Smectitic Vertisol using Three-dimensional Electrical Resistivity Tomography  

E-Print Network [OSTI]

Upon desiccation, the matrix of Vertisols and other expansive soils shrinks. Matrix shrinkage results in the formation of cracks that can alter the hydrology of the soil. Despite the importance of cracks, many hydrologic models do not account...

Ackerson, Jason Paul

2013-11-20T23:59:59.000Z

468

Evaluation of cracking in steam generator feedwater piping in pressurized water reactor plants  

SciTech Connect (OSTI)

Cracking in feedwater piping was detected near the inlet to steam generators in 15 pressurized water reactor plants. Sections with cracks from nine plants are examined with the objective of identifying the cracking mechanism and assessing various factors that might contribute to this cracking. Using transmission electron microscopy, fatigue striations are observed on replicas of cleaned crack surfaces. Calculations based on the observed striation spacings gave a cyclic stress value of 150 MPa (22 ksi) for one of the major cracks. The direction of crack propagation was invariably related to the piping surface and not to the piping axis. These two factors are consistent with the proposed concept of thermally induced, cyclic, tensile surface stresses and it is concluded that the overriding factor in the cracking problem was the presence of such undocumented cyclic loads.

Goldberg, A.; Streit, R.D.

1981-05-01T23:59:59.000Z

469

Stress Corrosion Cracking and Delayed Increase in Penetration Resistance after Dynamic Compaction of Sand  

E-Print Network [OSTI]

Stress Corrosion Cracking and Delayed Increase in Penetration Resistance after Dynamic Compaction on the process of stress corrosion cracking of the micro-morphological features on the surface of the sand grains

Michalowski, Radoslaw L.

470

E-Print Network 3.0 - assisted crack growth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cal crack growth by stress... for the first time in sapphire for both modes of subcritical cracking. It was found that growth rates were... growth rates could be closely...

471

Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation  

E-Print Network [OSTI]

Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

Plazas Garcia, Joyce Vivia

2002-01-01T23:59:59.000Z

472

E-Print Network 3.0 - amplitude fatigue crack Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with an initial crack. Constant ... Source: Fatemi, Ali - Department of Mechanical, Industrial and Manufacturing Engineering, University of Toledo Collection: Materials...

473

Thin film cracking and ratcheting caused by temperature cycling  

E-Print Network [OSTI]

Thin film cracking and ratcheting caused by temperature cycling M. Huang and Z. Suo Mechanical caused by ratcheting in an adjacent ductile layer. For example, on a silicon die directly attached corners. Aided by cycling temperature, the shear stresses cause ratcheting in the aluminum pads

Suo, Zhigang

474

Cracks and Atoms** By Dominic Holland* and Michael Marder  

E-Print Network [OSTI]

Cracks and Atoms** By Dominic Holland* and Michael Marder 1. Introduction Many materials scientists the atomic scale on the mechanical response of materials. On the one hand, there is a reluctance to believe that the invisible atomic scale is important for macroscopic mechanical deformation. Out of sight, out of mind

Texas at Austin. University of

475

Method of making crack-free zirconium hydride  

DOE Patents [OSTI]

Crack-free hydrides of zirconium and zirconium-uranium alloys are produced by alloying the zirconium or zirconium-uranium alloy with beryllium, or nickel, or beryllium and scandium, or nickel and scandium, or beryllium and nickel, or beryllium, nickel and scandium and thereafter hydriding.

Sullivan, Richard W. (Denver, CO)

1980-01-01T23:59:59.000Z

476

CONTAINED PLASTIC DEFORMATION NEAR CRACKS AND NOTCHES UNDER LONGITUDINAL SHEAR  

E-Print Network [OSTI]

CONTAINED PLASTIC DEFORMATION NEAR CRACKS AND NOTCHES UNDER LONGITUDINAL SHEAR James R. Rice* ABSTRACT An exact linear elastic-perfectly plastic solution is presented for the problem of a sharp notch coordinates corresponding to given stresses, position of the elastic-plastic boundary, and accompanying

477

Crack-resistant siloxane molding compounds. [Patent application  

DOE Patents [OSTI]

The crack resistance of phenyl silicone molding resins containing siliceous fillers is improved by incorporating therein about 0.5 to 5.5% by weight of ..beta..-eucryptite, a lithium aluminum silicate having a negative thermal expansion coefficient. These molding resins are particularly suitable for encapsulating electronic devices such as diodes, coils, resistors, and the like.

McFarland, J.W.; Swearngin, C.B.

1980-11-03T23:59:59.000Z

478

MATHEMATICAL MODEL OF DELAMINATION CRACKS ON IMPERFECT INTERFACES  

E-Print Network [OSTI]

monolith combustors that are being incorporated into new proto-type designs of gas turbines. The 1 #12. In the application in a gas turbine combustor, temperatures of the catalyst layer could vary from ambient conditionsMATHEMATICAL MODEL OF DELAMINATION CRACKS ON IMPERFECT INTERFACES Y. A. Antipov 1 , O. Avila

Bath, University of

479

Stress corrosion cracking under low stress: Continuous or discontinuous Longkui K. Zhu a  

E-Print Network [OSTI]

Stress corrosion cracking under low stress: Continuous or discontinuous cracks? Longkui K. Zhu a , Yu Yan a , Jinxu X. Li a , Lijie J. Qiao a, , Alex A. Volinsky b,a a Corrosion and Protection Center. Stress corrosion C. Anodic dissolution a b s t r a c t Two-dimensional and three-dimensional crack

Volinsky, Alex A.

480

Influence of Impurity Segregation on Temper Embrittlement and on Slow Fatigue Crack  

E-Print Network [OSTI]

of segregated impurity atoms (temper embrittlement) and hydrogen atoms, evolved from crack tip surface reactions with water vapor in the moist air environment (hydrogen embrittlement). The signifi- cance of crack closureInfluence of Impurity Segregation on Temper Embrittlement and on Slow Fatigue Crack Growth

Ritchie, Robert

Note: This page contains sample records for the topic "distillation cracking reforming" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Effects of Matrix Cracks on the Thermal Diffusivity of a Fiber-Reinforced Ceramic Composite  

E-Print Network [OSTI]

Effects of Matrix Cracks on the Thermal Diffusivity of a Fiber-Reinforced Ceramic Composite of Engineering Science, University of Western Ontario, London, Ontario N6A 5B9, Canada Effects of matrix cracks conductances coupled with a unit cell model for a fiber composite containing a periodic array of matrix cracks

Zok, Frank

482

Thermal resistance of bridged cracks in fiber-reinforced ceramic John Dryden  

E-Print Network [OSTI]

-reinforced ceramic composites obtain high toughness is through the de- velopment of multiple matrix cracksThermal resistance of bridged cracks in fiber-reinforced ceramic composites John Dryden Department November 2000; accepted for publication 16 January 2001 The thermal resistance of a bridged matrix crack

Zok, Frank

483

White(etching!matter!in!bearing!steel! Part1:!Controlled(cracking!of!52100!steel!  

E-Print Network [OSTI]

! 1! White(etching!matter!in!bearing!steel! Part1:!Controlled(cracking!of!52100!steel! ! W!phenomena!such!as!the!appearance!of!"white(etching!areas"!or!"white(etching! cracks",!crack!particular!kind!of!microstructural!damage!in!the!form!of!regions!of!the! structure,! which! appear! white! in

Cambridge, University of

484

A creep model for austenitic stainless steels incorporating cavitation and wedge cracking  

E-Print Network [OSTI]

A creep model for austenitic stainless steels incorporating cavitation and wedge cracking S Mahesh evolution in the form of cavitation and wedge- cracking on grain boundary facets is considered. Both: Austenitic stainless steel, creep, grain boundary sliding, cavitation, wedge- cracking. Submitted to

Mahesh, Sivasambu

485

A new approach to the subcritical cracking of ceramic Pierre Ladev`eze,a,1  

E-Print Network [OSTI]

A new approach to the subcritical cracking of ceramic fibers Pierre Ladev`eze,a,1 , Martin Geneta a Cachan Cedex, France Abstract A new modeling approach to subcritical crack propagation (i.e. static fa, the result comes down to the widely-used Paris-like subcritical crack propagation law. For the general case

486

Average crack front velocity during subcritical fracture propagation in a heterogeneous medium  

E-Print Network [OSTI]

Average crack front velocity during subcritical fracture propagation in a heterogeneous medium relaxation tests, exploring subcritical to critical regimes. Transparency of the material (PMMA) allows kinetic crack propagation is usually referred to as sub-critical crack growth or sub- critical regime

Paris-Sud XI, Université de

487

On the physics of moisture-induced cracking in metal-glass ,,copper-silica... interfaces  

E-Print Network [OSTI]

September 2007 Environmentally dependent subcritical crack growth, or stress-corrosion cracking, along on the moisture content in gaseous environments. Water and several organic liquids, namely n-butanol, methanol, additionally, subcritical crack growth17 and cyclically induced fracture18 at or near these interfaces when

Ritchie, Robert

488

Reforming petroleum-based fuels for fuel cell vehicles : composition-performance relationships.  

SciTech Connect (OSTI)

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior. Components which may be beneficial for ICEs for their octane enhancing value were detrimental to reforming. Fuels with high aromatic and naphthenic content were more difficult to reform. Aromatics were also found to have an impact on the kinetics for reforming of paraffins. The effects of sulfur impurities were dependent on the catalyst. Sulfur was detrimental for Ni, Co, and Ru catalysts. Sulfur was beneficial for reforming with Pt catalysts, however, the effect was dependent on the sulfur concentration.

Kopasz, J. P.; Miller, L. E.; Ahmed, S.; Devlin, P. R.; Pacheco, M.

2001-12-04T23:59:59.000Z

489

Theoretical Analysis of an Ideal Noiseless Linear Amplifier for Einstein-Podolsky-Rosen Entanglement Distillation  

E-Print Network [OSTI]

We study the operational regime of a noiseless linear amplifier based on quantum scissors that can nondeterministically amplify the one photon component of a quantum state with weak excitation. It has been shown that an arbitrarily large quantum state can be amplified by first splitting it into weak excitation states using a network of beamsplitters. The output states of the network can then be coherently recombined. In this paper, we analyse the performance of such a device for distilling entanglement after transmission through a lossy quantum channel, and look at two measures to determine the efficacy of the noiseless linear amplifier. The measures used are the amount of entanglement achievable and the final purity of the output amplified entangled state. We study the performances of both a single and a two-element noiseless linear amplifier for amplifying weakly excited states. Practically, we show that it may be advantageous to work with a limited number of stages.

J. Bernu; S. Armstrong; T. Symul; T. C. Ralph; P. K. Lam

2014-11-03T23:59:59.000Z

490

Upgrading of middle distillate fractions of syncrudes from athabasca oil sands  

SciTech Connect (OSTI)

Middle distillate fractions of syncrudes from Athabasca Oil Sands were evaluated for suitability as feedstocks in the catalytic conversion to diesel fuel meeting cetane number specifications. Hydrogenation of aromatic components to napthenes under severe conditions (380 to 400/sup 0/C, 2500 psig) using sulfided CoO/MoO/sub 3/ and NiO/WO/sub 3/ over ..cap alpha.. . Al/sub 2/O/sub 3/ in a previously described catalyst testing system. Reaction products were analyzed for aromatic carbon content using C/sup 13/ NMR spectroscopy and pseudo first order rate constants and activation energies (15.0 and 14.2 kcal 1 g-mole, respectively) were determined by regression analysis. At optimum conditions 97% aromatic conversion was obtained with the Ni-W catalyst. Product diesel fuel cetane number (42) was within specifications. Co-Mo catalyst was significantly less active.

Wilson, M.F.; Kriz, J.F.

1983-03-01T23:59:59.000Z

491

Dynamics and control of a heterogeneous azeotropic distillation column: Conventional control approach  

SciTech Connect (OSTI)

In this work, bifurcation analysis and dynamic simulation were used to investigate the optimum conventional control strategy of an isopropyl alcohol (IPA), cyclohexane (CyH), and water (H{sub 2}O) heterogeneous azeotropic column. Steady-state process analysis shows that the optimal operation point should be located at a critical reflux, a transition point at which the distillation path switches from a route that passes through the IPA + H{sub 2}O azeotrope to one that passes through the IPA + CyH azeotrope. A good control strategy must be able to maintain a steady column temperature profile that shows a plateau near 70 C to ensure passage around the IPA + CyH azeotrope. An inverse double-loop control strategy is proposed based on principal component analysis. This scheme is capable of maintaining the desired column temperature profile given all kinds of feed disturbances, thus keeping the product IPA purity at the desired level.

Chien, I.L. [National Taiwan Univ. of Science and Technology, Taipei (Taiwan, Province of China). Dept. of Chemical Engineering; Wang, C.J.; Wong, D.S.H. [National Tsing Hua Univ., Hsinchu (Taiwan, Province of China). Dept. of Chemical Engineering

1999-02-01T23:59:59.000Z

492

Re-refining of Waste Oil Solvent Is Used in Treatment/Distillation Process  

E-Print Network [OSTI]

INDUSTRIAL APPLICATION. A combination solvent treatment/distillation process has been designed for re-refining industrial waste oil (such as equipment lubricants, metal-working oil, and process oil) and used automotive lubricants (engine oil, hydraulic oil, and gear oil) for reuse. WASTE ENERGY RECOVERY. Recycling of waste oil in the United States has the potential to save the energy equivalent of 7-12 million bbl of crude oil annually.1 WASTE OIL RECOVERY. Prior to 1960, a significant portion of the demand for automotive lubricating oil was met by re-relined used oil. At the time, 150 re-refineries produced 300 million gal of motor oil annually. Since 1960, however, the production of re-refined oil has steadily declined. In 1981, for example, out of about 1.2 billion gal of automobile lubricating oil and 1.6 billion gal of industrial lubricating oils purchased, 25 U.S. rerefineries

unknown authors

493

On local indistinguishability of orthogonal pure states by using a bound on distillable entanglement  

E-Print Network [OSTI]

We show that the four states a|00>+b|11>, b^*|00>-a^*|11>, c|01>+d|10> and d^*|01>-c^*|10> cannot be discriminated with certainty if only local operations and classical communication (LOCC) are allowed and if only a single copy is provided, except in the case when they are simply |00>, |11>, |01> and |10> (in which case they are trivially distinguishable with LOCC). We go on to show that there exists a continuous range of values of a, b, c and d such that even three states among the above four are not locally distinguishable, if only a single copy is provided. The proof follows from the fact that logarithmic negativity is an upper bound of distillable entanglement.

Sibasish Ghosh; Guruprasad Kar; Anirban Roy; Debasis Sarkar; Aditi Sen De; Ujjwal Sen

2001-11-25T23:59:59.000Z

494

Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions  

SciTech Connect (OSTI)

This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

1995-03-01T23:59:59.000Z

495

Assigning a Value to Dried Distillers' Grains as a Protein Supplement in Cattle Consuming Low-Quality Forage  

E-Print Network [OSTI]

Cattle consuming low-quality forage may have decreased forage organic matter intake as a result of decreased nitrogen (N) intake. To date, a value has not been assigned to dried distillers' grains as a protein supplement to cattle consuming low...

Rambo, Zachary Joseph

2011-08-08T23:59:59.000Z

496

Fuel cell system with combustor-heated reformer  

DOE Patents [OSTI]

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Pettit, William Henry (Rochester, NY)

2000-01-01T23:59:59.000Z

497

Voting Systems and Election Reform: What Do Election Officials Think?  

E-Print Network [OSTI]

and systems, local election officials face different constraints and institutional arrangements depending on their state. The Election Reform Information Project?s research found a diverse set of ?power-sharing arrangements ranging from elections run... obscure but powerful group of administrators: election board officials at the state and local level. Second, Florida highlighted the role that existing voting technology plays in shaping the number of votes counted and, in particular, problems...

Gray, Jennifer; Gray, Marshall; Hodges, Joshua; Jewell, Jeff; Larson, Marcia; Mitchell, Ryan; Murello, Erin; Murello, Steve; Reeves, Alice; Siddique, Julie

2005-01-01T23:59:59.000Z

498

National Development and Reform Commission | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3Informationof EnergyNapaInformationand Reform Commission

499

Steam reforming of low-level mixed waste. Final report  

SciTech Connect (OSTI)

ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

NONE

1998-06-01T23:59:59.000Z

500

Thermodynamic evaluation of hydrogen production via bioethanol steam reforming  

SciTech Connect (OSTI)

In this article, a thermodynamic analysis for bioethanol steam reforming for hydrogen production is presented. Bioethanol is a newly proposed renewable energy carrier mainly produced from biomass fermentation. Reforming of bioethanol provides a promising method for hydrogen production from renewable resources. Steam reforming of ethanol (SRE) takes place under the action of a metal catalyst capable of breaking C-C bonds into smaller molecules. A large domain for the water/bioethanol molar ratio as well as the temperature and average pressure has been used in the present work. The interval of investigated temperature was 100-800°C, the pressure was in the range of 1-10 bar and the molar ratio was between 3-25. The variations of gaseous species concentration e.g. H{sub 2}, CO, CO{sub 2}, CH{sub 4} were analyzed. The concentrations of the main products (H{sub 2} and CO) at lower temperature are smaller than the ones at higher temperature due to by-products formation (methane, carbon dioxide, acetylene etc.). The concentration of H2 obtained in the process using high molar ratio (>20) is higher than the one at small molar ratio (near stoichiometric). When the pressure is increased the hydrogen concentration decreases. The results were compared with literature data for validation purposes.

Tasnadi-Asztalos, Zsolt; Cormos, Ana-Maria; Imre-Lucaci, Árpád; Cormos, C?lin C. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)] [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, Arany Janos 11, RO-400028, Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z