Sample records for distillation coking oil

  1. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15T23:59:59.000Z

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  2. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15T23:59:59.000Z

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  3. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  4. Stocks of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,591 135,428 135,820

  5. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) Geographic Area Month Kerosene No. 1 Distillate No. 2...

  6. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  7. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  8. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1996 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  9. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  10. CHEM333: Experiment 4: Steam Distillation of Essential Oils;

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Experiment 4: Steam Distillation of Essential Oils; Experiments A, C, D and below. Reading: For this experiment read Chapter 10. This week you will get to use steam distillation to isolate may wait until you come to lab to find out which spice you get. Steam distillation is not a common

  11. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01T23:59:59.000Z

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  12. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  13. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01T23:59:59.000Z

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  14. Atmospheric Crude Oil Distillation Operable Capacity

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 OilU.S.5AreOil andMarket Module This

  15. Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division

    SciTech Connect (OSTI)

    Volkov, E.L.

    1981-01-01T23:59:59.000Z

    Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

  16. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  17. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  18. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  19. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  20. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  1. Effects of petroleum distillate on viscosity, density and surface tension of intermediate and heavy crude oils

    E-Print Network [OSTI]

    Abdullayev, Azer

    2009-06-02T23:59:59.000Z

    : San Francisco oil from Columbia with specific gravity of 28o-29o API, Duri oil with gravity of 19o-21o API, Jobo oil with gravity of 8o-9o API and San Ardo oil gravity of 11o-13o API. The additive used in all of the experiments is petroleum distillate...

  2. Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine

    E-Print Network [OSTI]

    Yarbrough, Charles Michael

    1984-01-01T23:59:59.000Z

    J/'CA] volume rate of change [m /'CA) ? apparent rate of heat release [kJ/'CA] fuel air ratio [kg/kg] heat transfer coefficient [kJ/m 'K sec] ratio of specific heats connecting rod length [m] fuel lower heating value [kJ/kg] total mass of combustion gas...OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf...

  3. Re-refining of Waste Oil Solvent Is Used in Treatment/Distillation Process

    E-Print Network [OSTI]

    unknown authors

    INDUSTRIAL APPLICATION. A combination solvent treatment/distillation process has been designed for re-refining industrial waste oil (such as equipment lubricants, metal-working oil, and process oil) and used automotive lubricants (engine oil, hydraulic oil, and gear oil) for reuse. WASTE ENERGY RECOVERY. Recycling of waste oil in the United States has the potential to save the energy equivalent of 7-12 million bbl of crude oil annually.1 WASTE OIL RECOVERY. Prior to 1960, a significant portion of the demand for automotive lubricating oil was met by re-relined used oil. At the time, 150 re-refineries produced 300 million gal of motor oil annually. Since 1960, however, the production of re-refined oil has steadily declined. In 1981, for example, out of about 1.2 billion gal of automobile lubricating oil and 1.6 billion gal of industrial lubricating oils purchased, 25 U.S. rerefineries

  4. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  5. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  6. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A.

    1988-06-01T23:59:59.000Z

    Today's commercially proved technology to recover oil from the Athabasca oil sands, as practiced by Suncor and Syncrude, involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil. Significant amounts of petroleum coke are produced during the bitumen upgrading process. Suncor burns the bulk of its petroleum coke in boilers to fulfill the energy requirements of the entire operation, still meeting government regulations restricting the amount of sulfur dioxide that can be released to the environment. In contrast, Syncrude is able to burn only 20% of its coke production because of high sulphur dioxide emissions from elsewhere in its operations. The boiler ash (Fly ash) which contains appreciable amounts of metals, such as vanadium, nickel, titianium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke fired steam generation plants. There has been relatively little effort made towards the understanding of the chemical or physical nature of these materials. Knowledge of the physico-chemical properties of these materials will be helpful in assessing their beneficiation and potential use as fuel or metallurigcal coke and the feasibility of extracting some metals, especially Ni and V. In this communication the authors report studies of acid demineralization as a means of reducing ash content of these materials for /sup 13/C NMR spectroscopic investigations.

  7. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  8. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  9. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  10. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect (OSTI)

    Eaton, Scott J [ORNL; Bunting, Bruce G [ORNL; Lewis Sr, Samuel Arthur [ORNL; Fairbridge, Craig [National Centre for Upgrading Technology, Canada

    2009-01-01T23:59:59.000Z

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  11. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation 

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  12. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  13. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  14. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10T23:59:59.000Z

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  15. Adjusted Distillate Fuel Oil Sales for Residential Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 Oil ElectricityUsingStephenSpring

  16. Distillate fuel-oil processing for phosphoric acid fuel-cell power plants

    SciTech Connect (OSTI)

    Ushiba, K. K.

    1980-02-01T23:59:59.000Z

    The current efforts to develop distillate oil-steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high-temperature steam reforming (HTSR); autothermal reforming (ATR); autothermal gasification (AG); and ultra desulfurization followed by steam reforming. Sulfur in the feed is a key problem in the process development. A majority of the developers consider sulfur as an unavoidable contaminant of distillate fuel and are aiming to cope with it by making the process sulfur-tolerant. In the HTSR development, the calcium aluminate catalyst developed by Toyo Engineering represents the state of the art. United Technology (UTC), Engelhard, and Jet Propulsion Laboratory (JPL) are also involved in the HTSR research. The ATR of distillate fuel is investigated by UTC and JPL. The autothermal gasification (AG) of distillate fuel is being investigated by Engelhard and Siemens AG. As in the ATR, the fuel is catalytically gasified utilizing the heat generated by in situ partial combustion of feed, however, the goal of the AG is to accomplish the initial breakdown of the feed into light gases and not to achieve complete conversion to CO and H/sub 2/. For the fuel-cell integration, a secondary reforming of the light gases from the AG step is required. Engelhard is currently testing a system in which the effluent from the AG section enters the steam-reforming section, all housed in a single vessel. (WHK)

  17. ,"U.S. Adjusted Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources andPlant Liquids,+ LeasePrice SoldPlantGrossDistillate Fuel Oil by End

  18. Upgrading of middle distillate fractions of syncrudes from athabasca oil sands

    SciTech Connect (OSTI)

    Wilson, M.F.; Kriz, J.F.

    1983-03-01T23:59:59.000Z

    Middle distillate fractions of syncrudes from Athabasca Oil Sands were evaluated for suitability as feedstocks in the catalytic conversion to diesel fuel meeting cetane number specifications. Hydrogenation of aromatic components to napthenes under severe conditions (380 to 400/sup 0/C, 2500 psig) using sulfided CoO/MoO/sub 3/ and NiO/WO/sub 3/ over ..cap alpha.. . Al/sub 2/O/sub 3/ in a previously described catalyst testing system. Reaction products were analyzed for aromatic carbon content using C/sup 13/ NMR spectroscopy and pseudo first order rate constants and activation energies (15.0 and 14.2 kcal 1 g-mole, respectively) were determined by regression analysis. At optimum conditions 97% aromatic conversion was obtained with the Ni-W catalyst. Product diesel fuel cetane number (42) was within specifications. Co-Mo catalyst was significantly less active.

  19. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  20. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06T23:59:59.000Z

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  1. A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which

    E-Print Network [OSTI]

    Galvin, David

    : a distillation tower, which takes in crude oil, up to a maximum of 650,000 barrels per day (bbl/day) and produces that maximizes profit. Note: Taha's Example 2.3-7 has distillation tower capacity 1,500,000 bbl/day, and is otherwise the same. 1 #12;Solution Let x1 be daily input to distillation tower Constraint: 0 x1 650000

  2. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  3. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31T23:59:59.000Z

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  4. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources andPlant Liquids,+ LeasePrice SoldPlantGrossDistillateReserves+

  5. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07T23:59:59.000Z

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  6. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31T23:59:59.000Z

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  7. Catalytic Distillation

    E-Print Network [OSTI]

    Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

    1984-01-01T23:59:59.000Z

    Catalytic Distillation' refers to a chemical process which performs both a catalyzed reaction and primary fractionation of the reaction components simultaneously. A structured catalyst which also is an effective distillation component has been...

  8. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  9. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

    1997-12-31T23:59:59.000Z

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  10. Distill, Distill_roll Distill for CASP10

    E-Print Network [OSTI]

    Pollastri, Gianluca

    Distill, Distill_roll Distill for CASP10 C. Mirabello1, G. Tradigo1,2 , P.Veltri2, and G. Pollastri1 1 ­ UCD Dublin, Ireland, 2 ­ Università di Cosenza, Italy gianluca.pollastri@ucd.ie Distill has to the distance maps of templates rather than to predicted contact maps. The difference between Distill

  11. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01T23:59:59.000Z

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  12. Distillation 29 Chem 355 Jasperse DISTILLATION

    E-Print Network [OSTI]

    Jasperse, Craig P.

    Distillation 29 Chem 355 Jasperse DISTILLATION Background Distillation is a widely used technique for purifying liquids. The basic distillation process involves heating a liquid such that liquid molecules that is condensed and collected must be more pure than the original liquid mix. Distillation can be used to remove

  13. Met coke world summit 2005

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  14. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01T23:59:59.000Z

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  15. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect (OSTI)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  16. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Lab Experiment 3: Distillation and Gas Chromatography: Prelab-Assignment: read Chapters 5 and 6. Distillation is one of the most powerful techniques for purifying volatile organic compounds. Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wine

  17. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31T23:59:59.000Z

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  18. Synthesis and design of optimal thermal membrane distillation networks 

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    of oil. An overview of Direct Contact Membrane Distillation (DCMD) reports the narrow range of applications of membrane distillation in the industry, such as desalination and water purification (Burgoyne and Vahdati, 2000; Cath et al., 2004). Gryta... crystalliser and air gap membrane distillation as a solution to geothermal water desalination. Desalination 152 (1-3), 237-244. Burgoyne, A, Vahdati, M.M. 2000. Direct contact membrane distillation.Separation Science and Technology 35 (8), 1257...

  19. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01T23:59:59.000Z

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  20. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1984-01-01T23:59:59.000Z

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  1. New coke-sorting system at OAO Koks

    SciTech Connect (OSTI)

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  2. Imports of Distillate Fuel Oil

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 3400, U.S.MajorMarketsNov-14 Dec-14Has Hydrocarbon,2014147 128

  3. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Gasoline and Diesel Fuel Update (EIA)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  4. DistillationTheory.fm 2 September 1999 Distillation Theory.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 DistillationTheory.fm 2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway #12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Material Balance on a Distillation Stage

  5. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17T23:59:59.000Z

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  6. INNOVATION EDUCATION EXCELLENCE DISTILLATIONS

    E-Print Network [OSTI]

    Chan, Hue Sun

    INNOVATION · EDUCATION · EXCELLENCE DISTILLATIONS University of Toronto CHEMISTRY ALUMNI MAGAZINE.utoronto.ca / distillations 2012 MessagefromtheChair Our Department of Chemistry has one of the finest collection of peo- ple to a better, more sustain- able future. This issue of Distillations highlights the accomplishments last year

  7. Trends in the automation of coke production

    SciTech Connect (OSTI)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  8. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

  9. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16T23:59:59.000Z

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  10. Forpeerreview Synthesis of Complex Thermally Coupled Distillation

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    consumption of 91 GW, or 54 million tons of crude oil. The distillation research is motivated by its major US energy consumption, which is equivalent to 2.87x10 18 J (2.87 million TJ) per year, or to a power

  11. Method and apparatus for quenching coke

    SciTech Connect (OSTI)

    Calderon, A.

    1980-07-22T23:59:59.000Z

    A method is described for controlling pollutions during the discharge of coke from a coke oven having a pusher side and a coke discharge opening. The method comprises the steps of moving a carriage into alignment with the coke discharge opening, pushing a body of hot coke out of the discharge opening of the oven, guiding the coke pushed from the oven into a chamber supported on said carriage, quenching the coke by directing liquid at coke which is pushed into said chamber for dropping the temperature of the coke, confining steam and vapor generated during the dropping of the temperature of the coke in the chamber for building a positive pressure within the chamber, forcing the steam and vapors generated from the quenching of the coke out of the chamber through a venturi-like opening by means of the positive pressure built up in the chamber, and spraying liquid at the gases forced through said venturi-like opening by the positive pressure in the chamber for cleaning the gases.

  12. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-02-10T23:59:59.000Z

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  13. Distillation: The Efficient Workhorse

    E-Print Network [OSTI]

    Steinmeyer, D.

    DISTILLATION: THE EFFICIENT WORKHORSE Dan Steinmeyer Monsanto Company St. Louis, Missouri Distillation is inherently highly efficient: phase separation is clean it is relatively easy to build a mUltistage countercurrent device equilibrium... is closely approached on each stage Given the right perspective; the right application; and the right design - distillation is difficult to beat from an efficiency standpoint. ? The right perspective is that efficiency is the ratio of the work...

  14. Generalized entanglement distillation

    E-Print Network [OSTI]

    Yu-Bo Sheng; Lan Zhou

    2014-04-14T23:59:59.000Z

    We present a way for the entanglement distillation of genuine mixed state. Different from the conventional mixed state in entanglement purification protocol, each components of the mixed state in our protocol is a less-entangled state, while it is always a maximally entangled state. With the help of the weak cross-Kerr nonlinearity, this entanglement distillation protocol does not require the sophisticated single-photon detectors. Moreover, the distilled high quality entangled state can be retained to perform the further distillation. These properties make it more convenient in practical applications.

  15. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  16. MULTIVESSEL BATCH DISTILLATION EXPERIMENTAL VERIFICATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION ­ EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad 1 The experimental verification of the operation of a multivessel batch distillation column, operated under total vessels, provides a generalization of previously proposed batch distillation schemes. We propose a simple

  17. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01T23:59:59.000Z

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  18. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22T23:59:59.000Z

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  19. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01T23:59:59.000Z

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  20. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    Simulation study has shown oil production is accelerated when propane is used as an additive during steam injection. To better understand this phenomenon, distillation experiments were performed using San Ardo crude oil (12oAPI). For comparison...

  1. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24T23:59:59.000Z

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  2. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31T23:59:59.000Z

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  3. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31T23:59:59.000Z

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  4. Estimating Coke and Pepsi's price and advertising strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

    1999-01-01T23:59:59.000Z

    No. 789 ESTIMATING COKE AND PEPSI’ PRICE S AND ADVERTISINGAdvertising Strategies: Coke and Pepsi) by Amos Golan, LarryMarch 1999 Estimating Coke and Pepsi’s Price and Advertising

  5. Kinetics and thermodynamics of hydrotreating synthetic middle distillates

    SciTech Connect (OSTI)

    Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

    1987-04-01T23:59:59.000Z

    Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

  6. New designs in the reconstruction of coke-sorting systems

    SciTech Connect (OSTI)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  7. Random multiparty entanglement distillation

    E-Print Network [OSTI]

    Ben Fortescue; Hoi-Kwong Lo

    2008-01-15T23:59:59.000Z

    We describe various results related to the random distillation of multiparty entangled states - that is, conversion of such states into entangled states shared between fewer parties, where those parties are not predetermined. In previous work [Phys. Rev. Lett. 98, 260501 (2007)] we showed that certain output states (namely Einstein-Podolsky-Rosen (EPR) pairs) could be reliably acquired from a prescribed initial multipartite state (namely the W state) via random distillation that could not be reliably created between predetermined parties. Here we provide a more rigorous definition of what constitutes ``advantageous'' random distillation. We show that random distillation is always advantageous for W-class three-qubit states (but only sometimes for Greenberger-Horne-Zeilinger (GHZ)-class states). We show that the general class of multiparty states known as symmetric Dicke states can be readily converted to many other states in the class via random distillation. Finally we show that random distillation is provably not advantageous in the limit of multiple copies of pure states.

  8. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E. [British Steel plc, Scunthorpe (United Kingdom). Scunthorpe Works

    1995-12-01T23:59:59.000Z

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  9. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  10. Converting Petroleum Coke to Electricity

    E-Print Network [OSTI]

    Pavone, A.

    Changes in oil refining technology and economics are driving refiners to utilize thermal processes to maximize the conversion of heavy crude oil components to clean products. Since the primary unit operation to accomplish this objective...

  11. An experimental and mathematical investigation of hydrocarbon steam distillation

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01T23:59:59.000Z

    the Holland and Welch method was very good. The agreement between experimental and predicted separation data indicated the Holland and Welch method could be extended to calculate crude oil-water -vapor separations. A practical procedure using the Holland... and Welch method and simulated distillation data was developed to predict crude oil-water-vapor separations. The method was compared to experimental crude oil-water-vapor separation data obtained at saturated steam conditions of 378 F and 456 F...

  12. Energy efficient distillation apparatus

    SciTech Connect (OSTI)

    Melton, J.D.

    1982-08-17T23:59:59.000Z

    An energy efficient distillation method is provided which is particularly adapted for use on a dairy farm, and which comprises a distilland evaporating receptacle, a distillate condensing receptacle, and a conduit interconnecting the evaporating receptacle and the condensing receptacle. A vacuum pump is provided for drawing a partial vacuum within the evaporating receptacle, and a vapor compression refrigeration system is provided which includes condenser coils disposed to heat and vaporize the distilland while it is within the evaporating receptacle, and evaporator coils for cooling and condensing the vaporized distilland in the condensing receptacle. A cooling distribution system is also provided whereby a variable portion of the cooling potential of the refrigeration system may be selectively directed to each of the condensing receptacle, a distillate receiver tank, or to a bulk milk container as utilized on a dairy farm or the like.

  13. Qutrit Magic State Distillation

    E-Print Network [OSTI]

    Anwar, Hussain; Browne, Dan E

    2012-01-01T23:59:59.000Z

    Magic state distillation (MSD) is a purification protocol that plays a central role in fault tolerant quantum computation. Repeated iteration of the steps of a MSD protocol, generates pure single non-stabilizer states, or magic states, from multiple copies of a mixed resource state using stabilizer operations only. Thus mixed resource states promote the stabilizer operations to full universality. Magic state distillation was introduced for qubit-based quantum computation, but little has been known concerning MSD in higher dimensional qudit-based computation. Here, we describe a general approach for studying MSD in higher dimensions. We use it to investigate the features of a qutrit MSD protocol based on the 5-qutrit stabilizer code. We show that this protocol distills non-stabilizer magic states, and identify two types of states, that are attractors of this iteration map. Finally, we show how these states may be converted, via stabilizer circuits alone, into a state suitable for state injected implementation ...

  14. Compositional changes in heavy oil steamflood simulators

    E-Print Network [OSTI]

    Lolley, Christopher Scott

    1995-01-01T23:59:59.000Z

    including distillation, vapor pressure, steam distillation and viscosity measurements, along with a commercial PVT simulator are used to tune equation-of-state (EOS) and viscosity parameters to properly model the PVT properties of the oil. The Peng...

  15. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  16. Topological Quantum Distillation

    E-Print Network [OSTI]

    H. Bombin; M. A. Martin-Delgado

    2007-03-29T23:59:59.000Z

    We construct a class of topological quantum codes to perform quantum entanglement distillation. These codes implement the whole Clifford group of unitary operations in a fully topological manner and without selective addressing of qubits. This allows us to extend their application also to quantum teleportation, dense coding and computation with magic states.

  17. Low Energy Distillation Schemes

    E-Print Network [OSTI]

    Polley, G. T.

    of reducing energy consumption. We look at how the better integrated distillation schemes can be quickly identified. It is found that the design of integrated schemes is quicker than that of non-integrated schemes. We then look at how the use of heat pumps...

  18. New and revised standards for coke production

    SciTech Connect (OSTI)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  19. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15T23:59:59.000Z

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  20. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01T23:59:59.000Z

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  1. Heteroazeotropic Batch Distillation Feasibility and Operation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Heteroazeotropic Batch Distillation Feasibility and Operation by Efstathios Skouras and distillation is the dominating unit operation for such separations. However, the presence of azeotropes and non distillation as the best suited process. Among, various techniques to enhance distillation, heterogeneous

  2. Method for processing coke oven gas

    SciTech Connect (OSTI)

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1980-11-25T23:59:59.000Z

    Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

  3. Oil

    E-Print Network [OSTI]

    unknown authors

    Waste oils offer a tremendous recycling potential. An important, dwindling natural resource of great economic and industrial value, oil products are a cornerstone of our modern industrial society. Petroleum is processed into a wide variety of products: gasoline, fuel oil, diesel oil, synthetic rubber, solvents, pesticides, synthetic fibres, lubricating oil, drugs and many more ' (see Figure 1 1. The boilers of Amercian industries presently consume about 40 % of the used lubricating oils collected. In Ontario, the percentage varies from 20 to 30%. Road oiling is the other major use of collected waste oils. Five to seven million gallons (50-70 % of the waste oil col1ected)is spread on dusty Ontario roads each summer. The practice is both a wasteful use of a dwindling resource and an environmental hazard. The waste oil, with its load of heavy metals, particularly lead, additives including dangerous polynuclear aromatics and PCBs, is carried into the natural environment by runoff and dust to contaminate soils and water courses.2 The largest portion of used oils is never collected, but disappears into sewers, landfill sites and backyards. In Ontario alone, approximately 22 million gallons of potentially recyclable lube oil simply vanish each year. While oil recycling has ad-114 Oil

  4. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  5. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B. [Hoogovens IJmuiden B.V. (Netherlands)

    1995-12-01T23:59:59.000Z

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  6. Renormalising entanglement distillation

    E-Print Network [OSTI]

    Stephan Waeldchen; Janina Gertis; Earl T. Campbell; Jens Eisert

    2015-03-16T23:59:59.000Z

    Entanglement distillation refers to the task of transforming a collection of weakly entangled pairs into fewer highly entangled ones. It is a core ingredient in quantum repeater protocols, needed to transmit entanglement over arbitrary distances in order to realise quantum key distribution schemes. Usually, it is assumed that the initial entangled pairs are i.i.d. distributed and uncorrelated with each other, an assumption that might not be reasonable at all in any entanglement generation process involving memory channels. Here, we introduce a framework that captures entanglement distillation in the presence of natural correlations arising from memory channels. Conceptually, we bring together ideas from condensed-matter physics - that of renormalisation and of matrix-product states and operators - with those of local entanglement manipulation, Markov chain mixing, and quantum error correction. We identify meaningful parameter regions for which we prove convergence to maximally entangled states, arising as the fixed points of a matrix-product operator renormalisation flow.

  7. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15T23:59:59.000Z

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  8. Reflux for multifeed distillation

    SciTech Connect (OSTI)

    Chou, S.M.; Yaws, C.L.

    1986-12-01T23:59:59.000Z

    Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

  9. Intermediate Vapor Expansion Distillation and Nested Enrichment Cascade Distillation

    E-Print Network [OSTI]

    Erickson, D. C.

    INTERMEDIATE VAPOR EXPANSION DISTILLATION AND NESTED ENRICHMENT CASCADE DISTILLATION D.. C. Erickson Energy Concepts Company Annapolis, Maryland ABSTRACT Although it is known that incorporating an intermediate reboiler or reflux... condenser in a distillation ~olumn will improve column efficiency by 15 to 100%, there has been little use of this technique to date." Intermediate vapor compression heat pumping was recently introduced as one practical means of achieving this benefit...

  10. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15T23:59:59.000Z

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  11. Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH

    SciTech Connect (OSTI)

    Boak, S.C.; Prucha, D.G.; Turic, H.L.

    1981-01-01T23:59:59.000Z

    Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

  12. Product Supplied for Distillate Fuel Oil

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousand CubicCubic Feet) Yeara 436 Energy Information3,879

  13. Distillate Fuel Oil Sales for Commercial Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecadeReservesYear21CompanySFoot)YearD e2,850,895

  14. Distillate Fuel Oil Sales for Farm Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecadeReservesYear21CompanySFoot)YearD

  15. Distillate Fuel Oil Sales for Industrial Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecadeReservesYear21CompanySFoot)YearD593,750

  16. Distillate Fuel Oil Sales for Military Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecadeReservesYear21CompanySFoot)YearD593,750270,975

  17. Distillate Fuel Oil Sales for Railroad Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127 1,710,513 1,751,162

  18. Distillate Fuel Oil Sales for Residential Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127 1,710,513 1,751,1625,568,066

  19. Total Adjusted Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear JanYear Jan Feb Mar Apr May(MillionFeet)July

  20. Total Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear JanYear Jan Feb Mar Apr

  1. Distillate Fuel Oil Days of Supply

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline353/06) 2Yonthly Energy : b ra&le.com 1U.S.

  2. Distillate Fuel Oil Sales for Residential Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline353/06) 2Yonthly Energy : b ra&le.comEnd

  3. Atmospheric Crude Oil Distillation Operable Capacity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternativeOperational ManagementDemand Module ThisAt NREL,TheDust

  4. Product Supplied for Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a evie _ =_ In7, 20116,650.0 167,905.6 173,210.44,115

  5. Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE

    E-Print Network [OSTI]

    Karp, Larry S.

    Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

  6. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  7. Water protection in coke-plant design

    SciTech Connect (OSTI)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  8. TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION BERND WITTGENS, RAJAB LITTO, EVA SØRENSEN in this paper provides a generalization of previously proposed batch distillation schemes. A simple feedback been built and the experiments verify the simulations. INTRODUCTION Although batch distillation

  9. Minimum Energy Diagrams for Multieffect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Minimum Energy Diagrams for Multieffect Distillation Arrangements Hilde K. Engelien and Sigurd distillation arrangements for separating a ternary mixture have been considered. The focus is on a heat-integrated complex distillation configuration, called a multieffect prefractionator arrangement. The comparison

  10. Multivessel Batch Distillation Potential Energy Savings

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multivessel Batch Distillation ­ Potential Energy Savings Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT ­ A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  11. Multivessel Batch Distillation -Potential Energy Savings

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multivessel Batch Distillation - Potential Energy Savings Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT - A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  12. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  13. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01T23:59:59.000Z

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  14. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, Raymond P. (Overland Park, KS); Schmalzer, David K. (Englewood, CO); Wright, Charles H. (Overland Park, KS)

    1982-12-21T23:59:59.000Z

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  15. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21T23:59:59.000Z

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  16. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, G.T.; Holshouser, S.K.; Coleman, R.M.; Harless, C.E.; Whinnery, W.N. III

    1982-03-17T23:59:59.000Z

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  17. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, Gus T. (Paducah, KY); Holshouser, Stephen K. (Boaz, KY); Coleman, Richard M. (Paducah, KY); Harless, Charles E. (Smithland, KY); Whinnery, III, Walter N. (Paducah, KY)

    1983-01-01T23:59:59.000Z

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  18. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  19. Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

  20. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  1. Optimal Control of Distillation Systems

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01T23:59:59.000Z

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  2. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  3. EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS Tshepo Sehole David Modise A thesis or in combination, such as distillation, extraction, crystallization, ect. Among these, distillation is by far profiles for the preliminary design of distillation columns. Residue curves and column profile are not only

  4. Momentive Performance Materials Distillation Intercharger

    E-Print Network [OSTI]

    Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

    2013-01-01T23:59:59.000Z

    Care? Energy Efficiency Program Momentive Performance Materials Distillation Interchanger ESL-IE-13-05-20 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Copyright 2013 Momentive Performance... Materials Inc. All rights reserved. CONFIDENTIAL IETC Energy Efficiency Award Winner Distillation Interchanger ? Waterford, NY Agenda ? Momentive Overview ? Waterford, NY Site Overview ? Project Overview ? Project Timeline ? NYSERDA ? Project Team...

  5. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

    2009-11-03T23:59:59.000Z

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  6. Quantum universality by state distillation

    E-Print Network [OSTI]

    Ben W. Reichardt

    2009-07-13T23:59:59.000Z

    Quantum universality can be achieved using classically controlled stabilizer operations and repeated preparation of certain ancilla states. Which ancilla states suffice for universality? This "magic states distillation" question is closely related to quantum fault tolerance. Lower bounds on the noise tolerable on the ancilla help give lower bounds on the tolerable noise rate threshold for fault-tolerant computation. Upper bounds show the limits of threshold upper-bound arguments based on the Gottesman-Knill theorem. We extend the range of single-qubit mixed states that are known to give universality, by using a simple parity-checking operation. For applications to proving threshold lower bounds, certain practical stability characteristics are often required, and we also show a stable distillation procedure. No distillation upper bounds are known beyond those given by the Gottesman-Knill theorem. One might ask whether distillation upper bounds reduce to upper bounds for single-qubit ancilla states. For multi-qubit pure states and previously considered two-qubit ancilla states, the answer is yes. However, we exhibit two-qubit mixed states that are not mixtures of stabilizer states, but for which every postselected stabilizer reduction from two qubits to one outputs a mixture of stabilizer states. Distilling such states would require true multi-qubit state distillation methods.

  7. Marathon Oil Company

    E-Print Network [OSTI]

    unknown authors

    Marine oil shale from the Shenglihe oil shale section in the Qiangtang basin, northern Tibet, China, was dated by the Re-Os technique using Carius Tube digestion, Os distillation, Re extraction by acetone and ICP-MS measure-ment. An isochron was obtained giving an age of 101±24 Ma with an initial

  8. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23T23:59:59.000Z

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

  9. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  10. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  11. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  12. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been...

  13. Countries Distillate Heating Oil (No. 2 Heating Oil and Gasoil...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Countries (U.S. dollars per gallon, excluding taxes) Date Belgium France Germany Italy Netherlands UK US 42715 2.40 2.30 2.43 2.41 2.41 2.11 2.56 42015 2.26 2.21 2.35 2.32 2.31...

  14. Countries Distillate Heating Oil (No. 2 Heating Oil and Gasoil...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    excluding taxes) Date Belgium France Germany Italy Netherlands UK US 42715 2.15 2.32 2.11 2.61 1.49 2.11 NA 42015 2.07 2.26 2.09 2.50 1.46 2.05 NA 41315 1.96 2.15 1.97 2.36...

  15. Countries Distillate Heating Oil (No. 2 Heating Oil and Gasoil...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including taxes) Date Belgium France Germany Italy Netherlands UK US 42715 2.69 3.17 2.81 5.21 4.24 2.88 NA 42015 2.59 3.08 2.79 5.05 4.18 2.81 NA 41315 2.46 2.95 2.64 4.85...

  16. Distillate Fuel Oil Sales for Oil Company Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127 1,710,513 1,751,162 1984-2013

  17. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01T23:59:59.000Z

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  18. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs 

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  19. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  20. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  1. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

    1995-12-01T23:59:59.000Z

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  2. Syncrude coke burned in bubbling fluidized bed

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Syncrude Canada Ltd.'s byproduct coke is high in sulfur (7%) and vanadium (0.2%), and moderate in ash (5.9%). It contains a high proportion of unreactive forms of carbon and is low in volatiles, 6.6%. It is unsuitable for combustion by established technologies, and at present the entire production of over 2000 tons per day is being stockpiled. Experiments with atmospheric fluidized bed combustion (AFBC) are described. The AFBC provides abatement of SO/sub 2/ emissions by means of limestone sorbent fed to the combustor together with the fuel. The pilot plant, combustion efficiency, and sulfur capture are discussed. 3 figures.

  3. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-12-01T23:59:59.000Z

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  4. Entanglement distillation using particle statistics

    E-Print Network [OSTI]

    H. L. Huang; L. H. Cheng; X. X. Yi

    2005-10-25T23:59:59.000Z

    We extend the idea of entanglement concentration for pure states(Phys. Rev. Lett. {\\bf 88}, 187903) to the case of mixed states. The scheme works only with particle statistics and local operations, without the need of any other interactions. We show that the maximally entangled state can be distilled out when the initial state is pure, otherwise the entanglement of the final state is less than one. The distillation efficiency is a product of the diagonal elements of the initial state, it takes the maximum 50%, the same as the case for pure states.

  5. Distilling entanglement from arbitrary resources

    E-Print Network [OSTI]

    Francesco Buscemi; Nilanjana Datta

    2010-10-15T23:59:59.000Z

    We obtain the general formula for the optimal rate at which singlets can be distilled from any given noisy and arbitrarily correlated entanglement resource, by means of local operations and classical communication (LOCC). Our formula, obtained by employing the quantum information spectrum method, reduces to that derived by Devetak and Winter, in the special case of an i.i.d. resource. The proofs rely on a one-shot version of the so-called "hashing bound," which in turn provides bounds on the one-shot distillable entanglement under general LOCC.

  6. The Use of TaBoRR as a Heavy Oil Upgrader

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones

    2009-02-05T23:59:59.000Z

    Preliminary testing has shown that Western Research Institute's (WRI) Tank Bottom Recovery and Remediation (TaBoRR{reg_sign}) technology shows promise for heavy oil upgrading. Approximately 70 to 75 wt% of a Canadian Cold Lake bitumen feed was converted to a partially upgraded overhead product that could be transported directly by pipeline or blended with the parent bitumen to produce transportable crude. TaBoRR{reg_sign} was originally developed to remediate tank bottom wastes by producing a distillate product and solid waste. TaBoRR{reg_sign}'s processing steps include breaking a water-oil emulsion, recovering a light hydrocarbon fraction by distillation in a stripper unit, and pyrolyzing the residua reducing it to additional overhead and a benign coke for disposal. Cold Lake bitumen was tested in WRI's bench-scale equipment to evaluate the potential use of TaBoRR{reg_sign} technology for heavy oil upgrading to produce a stable, partially (or fully) upgraded product that will allow diluent-reduced or diluent-free transportation of bitumen or ultra-heavy crudes to market. Runs were conducted at temperatures of low, intermediate and high severity in the stripper to produce stripper overhead and bottoms. The bottoms from each of these runs were processed further in a 6-inch screw pyrolyzer to produce pyrolyzer overhead for blending with the corresponding stripper overheads. Proceeding in this fashion yielded three partially upgraded crudes. The products from TaBoRR{reg_sign} processing, the parent bitumen, and bitumen blends were subjected to stability and compatibility testing at the National Centre for Upgrading Technology (NCUT). Chemical analyses of the overhead product blends have met pipeline specifications for viscosity and density; however the bromine number does not, which might indicate the need for mild hydrotreating. Storage stability tests showed the blends to be stable. The blends were also soluble and compatible with most other Alberta crudes.

  7. Oil & Chemical Pollution 6 (19'X)} 81-

    E-Print Network [OSTI]

    Canberra, University of

    distribution offuel distillates is evident with only a small contribution from lubricating and heavier oilOil & Chemical Pollution 6 (19'X)} 81- pollution as all oils contain aromatic hydrocarbons while few, if any, biogenic aromatic hydrocarbons

  8. Entanglement distillation by extendible maps

    E-Print Network [OSTI]

    Lukasz Pankowski; Fernando G. S. L. Brandao; Michal Horodecki; Graeme Smith

    2013-08-25T23:59:59.000Z

    It is known that from entangled states that have positive partial transpose it is not possible to distill maximally entangled states by local operations and classical communication (LOCC). A long-standing open question is whether maximally entangled states can be distilled from every state with a non-positive partial transpose. In this paper we study a possible approach to the question consisting of enlarging the class of operations allowed. Namely, instead of LOCC operations we consider k-extendible operations, defined as maps whose Choi-Jamiolkowski state is k-extendible. We find that this class is unexpectedly powerful - e.g. it is capable of distilling EPR pairs even from product states. We also perform numerical studies of distillation of Werner states by those maps, which show that if we raise the extension index k simultaneously with the number of copies of the state, then the class of k-extendible operations is not that powerful anymore and provide a better approximation to the set of LOCC operations.

  9. Corrosion inhibition for distillation apparatus

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY); Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01T23:59:59.000Z

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  10. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01T23:59:59.000Z

    ure to the air. After this came a white crystal­ line solid, fourth a reddish fciquid, fifth a red­ dish crystalline compound and sixth the black oil spoken of abovd. A volume of the distillate, equaling about a liter was collected and the two... the material the temperature rose to 200° C. and then reduction started and the temperature fell rapidly. The tar or oil constitutes from 3 to 4 per cent of the weight of the leather used. The aqueous portion of the distillate was subjected to a fractional...

  11. Process Svstems Enaineerina Instability of Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Process Svstems Enaineerina , Instability of Distillation Columns Elling W. Jacobsen and Sigurd recognized, distillation columns, operating with reflux and boilup as independent inputs, may have The dynamic behavior of distillation columns has been stud- ied quite extensively over the past decades

  12. POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT ­ A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  13. POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT - A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  14. Optimal distillation using thermodynamic geometry Bjarne Andresen

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal distillation using thermodynamic geometry Bjarne Andresen Ørsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler (temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2

  15. Analysis and Control of Heteroazeotropic Batch Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis and Control of Heteroazeotropic Batch Distillation S. Skouras and S. Skogestad Dept.interscience.wiley.com). The separation of close-boiling and azeotropic mixtures by heterogeneous azeotropic distillation is addressed. The results show that heteroazeotropic batch distillation exhibits substantial flexibility. The column profile

  16. Experimental entanglement distillation of mesoscopic quantum states

    E-Print Network [OSTI]

    Loss, Daniel

    LETTERS Experimental entanglement distillation of mesoscopic quantum states RUIFANG DONG1 , MIKAEL, entanglement distillation, a process of extracting a small set of highly entangled states from a large set of less entangled states, can be used4­14 . Here we report on the distillation of deterministically

  17. TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION BERND WITTGENS, RAJAB LITTO, EVA S RENSEN a generalization of previously proposed batch distillation schemes. A simple feedback control strategy for total re verify the simulations. INTRODUCTION Although batch distillation generally is less energy e cient than

  18. New process for coke-oven gas desulfurization

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-10-01T23:59:59.000Z

    With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

  19. Method for removal of furfural coke from metal surfaces

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-27T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  20. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    with distance along the reactor, and therefore the coke distribution should follow a similar pattern. A distribution of coke deposits along the reactor was also observed by Noda er al. (1974) in a study of iso-pentane isomerization. In this case the coke..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

  1. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Hofherr, K. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  2. Estimating Coke and Pepsi's Price and Advertising Strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

    1998-01-01T23:59:59.000Z

    2b: GME-Nash Estimates of Pepsi’s Strategies (First QuarterStrategy Distributions for Pepsi (First Quarter 1977) a)789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISING STRATEGIES

  3. Problem of improving coke oven gas purification systems

    SciTech Connect (OSTI)

    Goldin, I.A.

    1982-01-01T23:59:59.000Z

    A discussion of the problems of improving desulfurization processes of coke oven gas was presented. Of particular interest were control systems and increasing capacity of the coke ovens. Included in the discussion were the vacuum-carbonate and arsenic-soda sulfur removal systems. Problems involved with these systems were the number of treatment operations, the volume of the reagents used, and the operation of equipment for naphthalene and cyanide removal.

  4. Priorities in the design of chemical shops at coke plants

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  5. History of Heating Oil Reserve Releases

    Broader source: Energy.gov [DOE]

    The Northeast Home Heating Oil Reserve (NEHHOR), a one million barrel supply of ultra low sulfur distillate (diesel), was created to build a buffer to allow commercial companies to compensate for...

  6. Distillation of Bell states in open systems

    E-Print Network [OSTI]

    E. Isasi; D. Mundarain

    2009-08-14T23:59:59.000Z

    In this work we review the entire classification of 2x2 distillable states for protocols with a finite numbers of copies. We show a distillation protocol that allows to distill Bell states with non zero probability at any time for an initial singlet in vacuum. It is shown that the same protocol used in non zero thermal baths yields a considerable recovering of entanglement.

  7. Heat Exchanger Technologies for Distillation Columns

    E-Print Network [OSTI]

    Polley, G. T.

    Heat Exchanger Technologies for Distillation Columns G.T.Polley Pinchtechnology.com In this paper we look at the challenges that improvements in energy efficiency of distillation systems presents the heat exchanger designer. We examine... condensate sub-cooling. So, if this condensate subsequently requires re-heating both energy and capital have been wasted. If the condensate forms a feed to another distillation column it results in increased energy consumption if that separation...

  8. Reducing Energy Usage in Extractive Distillation

    E-Print Network [OSTI]

    Saxena, A. C.; Bhandari, V. A.

    , .. ~ REDUCING ENERGY USAGE IN,EXTRACTIVE DISTILLATION A. C. Saxena V. A. Bhandari Polysar Limited Sarnia, Ontario, Canada Abstract Butadiene 1:3 is separated from other C. hydrocarbons by extractive distillation in a sieve plate tower.... To improve the energy efficiency, butadiene recovery and productivity of the extractive distillation process, many process changes have been made. Their rationale, the methodology used to implement the various changes, and how they affected the process...

  9. Entanglement distillation from quasifree Fermions

    E-Print Network [OSTI]

    Zoltan Kadar; Michael Keyl; Dirk Schlingemann

    2011-03-24T23:59:59.000Z

    We develop a scheme to distill entanglement from bipartite Fermionic systems in an arbitrary quasifree state. It can be applied if either one system containing infinite one-copy entanglement is available or if an arbitrary amount of equally prepared systems can be used. We show that the efficiency of the proposed scheme is in general very good and in some cases even optimal. Furthermore we apply it to Fermions hopping on an infinite lattice and demonstrate in this context that an efficient numerical analysis is possible for more then 10^6 lattice sites.

  10. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01T23:59:59.000Z

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  11. Development of the Write Process for Pipeline-Ready Heavy Oil

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones; Frank Guffey

    2009-03-07T23:59:59.000Z

    Work completed under this program advances the goal of demonstrating Western Research Institute's (WRI's) WRITE{trademark} process for upgrading heavy oil at field scale. MEG Energy Corporation (MEG) located in Calgary, Alberta, Canada supported efforts at WRI to develop the WRITE{trademark} process as an oil sands, field-upgrading technology through this Task 51 Jointly Sponsored Research project. The project consisted of 6 tasks: (1) optimization of the distillate recovery unit (DRU), (2) demonstration and design of a continuous coker, (3) conceptual design and cost estimate for a commercial facility, (4) design of a WRITE{trademark} pilot plant, (5) hydrotreating studies, and (6) establish a petroleum analysis laboratory. WRITE{trademark} is a heavy oil and bitumen upgrading process that produces residuum-free, pipeline ready oil from heavy material with undiluted density and viscosity that exceed prevailing pipeline specifications. WRITE{trademark} uses two processing stages to achieve low and high temperature conversion of heavy oil or bitumen. The first stage DRU operates at mild thermal cracking conditions, yielding a light overhead product and a heavy residuum or bottoms material. These bottoms flow to the second stage continuous coker that operates at severe pyrolysis conditions, yielding light pyrolyzate and coke. The combined pyrolyzate and mildly cracked overhead streams form WRITE{trademark}'s synthetic crude oil (SCO) production. The main objectives of this project were to (1) complete testing and analysis at bench scale with the DRU and continuous coker reactors and provide results to MEG for process evaluation and scale-up determinations and (2) complete a technical and economic assessment of WRITE{trademark} technology to determine its viability. The DRU test program was completed and a processing envelope developed. These results were used for process assessment and for scaleup. Tests in the continuous coker were intended to determine the throughput capability of the coker so a scaled design could be developed that maximized feed rate for a given size of reactor. These tests were only partially successful because of equipment problems. A redesigned coker, which addressed the problems, has been build but not operated. A preliminary economic analysis conducted by MEG and an their engineering consultant concluded that the WRITE{trademark} process is a technically feasible method for upgrading bitumen and that it produces SCO that meets pipeline specifications for density. When compared to delayed coking, the industry benchmark for thermal upgrading of bitumen, WRITE{trademark} produced more SCO, less coke, less CO{sub 2} per barrel of bitumen fed, and had lower capital and operating costs. On the other hand, WRITE{trademark}'s lower processing severity yielded crude with higher density and a different product distribution for naphtha, light gas oil and vacuum oil that, taken together, might reduce the value of the SCO. These issues plus the completion of more detailed process evaluation and economics need to be resolved before WRITE{trademark} is deployed as a field-scale pilot.

  12. CLOSED OPERATION OF MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 CLOSED OPERATION OF MULTIVESSEL BATCH DISTILLATION - EXPERIMENTAL VERIFICATION Submitted to AICheÆcient operation, multicomponent distillation, batch distillation, total re ux operation ABSTRACT. The multivessel batch distillation column, as well as conven- tional batch distillation, may be operated in a closed

  13. NATCOR -Xpress case study Margaret Oil produces three products: gasoline, jet fuel, and heating oil. The average

    E-Print Network [OSTI]

    Hall, Julian

    NATCOR - Xpress case study Margaret Oil produces three products: gasoline, jet fuel, and heating oil. To produce these products, Margaret purchases crude oil at a price of £11 per barrel. Each day to produce gasoline or jet fuel. Distilled oil can be used to produce all three products. The octane level

  14. Sulfur distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    by the thermal cracking process of the El-Lujjan oil shale showed that the yield of oil was around 12 wt of the boiling point for different distillate fractions. Sulfur in Jordanian oil shale was found to be mainly the dominant phases in these fractions. q 2005 Published by Elsevier Ltd. 1. Introduction Oil shale

  15. Locally Accessible Information and Distillation of Entanglement

    E-Print Network [OSTI]

    Sibasish Ghosh; Pramod Joag; Guruprasad Kar; Samir Kunkri; Anirban Roy

    2004-03-18T23:59:59.000Z

    A new type of complementary relation is found between locally accessible information and final average entanglement for given ensemble. It is also shown that in some well known distillation protocol, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

  16. Rigorous Synthesis and Simulation of Complex Distillation Networks

    E-Print Network [OSTI]

    Linninger, Andreas A.

    Rigorous Synthesis and Simulation of Complex Distillation Networks Gerardo J. Ruiz, Seon B. Kim energy-efficient distillation net- works. Complex column networks have substantial potential for energy column, networks, temperature collocation, inverse design, Aspen validation Introduction Distillation

  17. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  18. Shell middle distillate hydrogenation process

    SciTech Connect (OSTI)

    Lucien, J.P. [Companie Rhenane de Raffinage Reichstett, Reichstett Vendenheim (France); Berg, J.P. van den; Hooijdonk, H.M.J.H. van; Thielemans, G.L.B. [Shell Internationale Petroleum Mij., The Hague (Netherlands); Germaine, G. [Shell Recherche SA, Grand-Couronne (France); Gjers, M. [Shell Raffinaderi AB, Gothenburg (Sweden)

    1994-12-31T23:59:59.000Z

    The strive towards cleaner environment has lead to low sulfur specifications for middle distillate fuels. In addition compositional specifications are presently debated. Thus, to meet future emissions standards regarding, specifically, particulates emissions, the motor industry calls for improved automotive gasoil quality. Although automotive gasoil quality affects emissions from diesel engines it is considered less influential than engine design and maintenance. Sulfur, density and cetane number are the fuel properties having the greatest influence on diesel engine emissions although also aromatics and endpoint specifications have been defined in environmentally adopted government initiatives. This paper reviews the options which are available to tackle these new requirements. The high severity single stage concept (using conventional mixed sulfides catalysts) will be discussed in its potential to meet more severe product requirements as well as in terms of its limitations, especially at the point of aromatics saturation and cetaine upgrading. Furthermore, it is shown that the option of severe hydrotreating followed by hydrogenation with conventional noble metal catalysts is preferred if deep aromatics saturation is aimed at. However, this conventional two stage concept has limitations with respect to heaviness and sulfur and nitrogen content of feedstocks. The new Shell Middle Distillate Hydrogenation (SMDH) technology, applying a (semi) two stage approach based on the Shell developed hydrogenation catalyst is presented. The SMDH process will be discussed in its potential to break the limitations of the conventional options. The new catalyst is crucial in this process and allows a highly integrated mode of operation. A number of applications of this novel process will be discussed.

  19. atmospheric crude distillation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  20. acrobat distiller job: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  1. advanced distillation curve: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  2. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

    1997-12-31T23:59:59.000Z

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  3. Distillation: Still towering over other options

    SciTech Connect (OSTI)

    Kunesh, J.G. [Fractionation Research, Inc., Stillwater, OK (United States); Kister, H.Z. [Brown and Root, Inc., Alhambra (Canada); Lockett, M.J. [Praxair, Inc., Tonawanda, NY (United States); Fair, J.R. [Univ. of Texas, Austin, TX (United States)

    1995-10-01T23:59:59.000Z

    Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

  4. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect (OSTI)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  5. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  6. Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*

    E-Print Network [OSTI]

    Lansky, Joshua

    Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm theory. We use these methods to estimate the pricing and adver- tising strategies of Coca-Cola and Pepsi

  7. Coke profile and effect on methane/ethylene conversion process 

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

  8. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01T23:59:59.000Z

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  9. Nonlocality Distillation for High-Dimensional System

    E-Print Network [OSTI]

    Pan, Guo-Zhu; Chen, Zheng-Gen; Yang, Ming; Cao, Zhuo-Liang

    2012-01-01T23:59:59.000Z

    The intriguing and powerful capability of nonlocality in communication field ignites the research of the nonlocality distillation. The first protocol presented in Ref[Phys. Rev. Lett. 102, 120401] shows that the nonlocality of bipartite binary-input and binary-output nonsignaling correlated boxes could be amplified by 'wiring' two copies of weaker-nonlocality boxes. Several optimized distillation protocols were presented later for bipartite binary-input and binary-output nonsignaling correlated boxes. In this paper, we focus on the bipartite binary-input and multi-nary-output nonsignaling correlated boxes---high-dimensional boxes, and design comparators-based protocols to achieve the distillation of high-dimensional nonlocality. The results show that the high-dimensional nonlocality can be distilled in different ways, and we find that the efficiencies of the protocols are influenced not only by the wirings but also by the classes the initial nonlocality boxes belongs to. Here, the initial nonlcalities may hav...

  10. Intelligent fuzzy supervisory control for distillation columns

    E-Print Network [OSTI]

    Santhanam, Srinivasan

    1993-01-01T23:59:59.000Z

    problem. Multivariable design techniques are used to control the column. Some of the different multivariable techniques which have been used in the distillation column control include decoupling control, optimal control and internal model control [5...

  11. Advanced Distillation: Programs Proposed to DOE

    E-Print Network [OSTI]

    Woinsky, S. G.

    EPRI has provided proposal preparation assistance and offered cost share funding assistance for two projects proposed in 2000. EPRI is highly interested, since this technology is applicable in all distillation systems, and since it will increase...

  12. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  13. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01T23:59:59.000Z

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  14. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    When the heat source available to a distillation process is at a significantly higher temperature than the reboiler temperature, there is unused availability (ability to perform work) in the heat supplied to the reboiler. Similarly, if the reflux...

  15. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J.

    1988-06-01T23:59:59.000Z

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulfur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader, now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional products, also based on hydrogenation, will use ebullated bed catalyst systems: the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  16. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J. (Chrones Engineering Consultants Inc., 111 Lord Seaton Road, Willowdale, Ontario (CA)); Germain, R.R. (Alberta Oil Sands Technology and Research Authority, Edmonton, AB (Canada))

    1989-01-01T23:59:59.000Z

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulphur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional projects, also based on hydrogenation, will use ebullated bed catalyst systems; the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  17. Complex Fluid Analysis with the Advanced Distillation Curve Approach

    E-Print Network [OSTI]

    Complex Fluid Analysis with the Advanced Distillation Curve Approach Thomas J. Bruno, Lisa S. Ott for measuring distillation curves reveals the physicochemical properties of complex fluids such as fuels distillation curves of complex fluids. The distillation curve provides the only practical avenue to assess

  18. On the Communication Complexity of Correlation and Entanglement Distillation

    E-Print Network [OSTI]

    On the Communication Complexity of Correlation and Entanglement Distillation Ke Yang May 4th, 2004 distillation, entanglement distillation, communication complexity, EPR pairs, quantum key distribution #12) information, and then engage in a protocol to \\distill" the correlation/entanglement via communication. We

  19. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio blog distillation by adding a link analysis phase to the standard retrieval-by-topicality phase, where in blog distillation. 1 Introduction Blog distillation is a subtask of blog search. It is defined

  20. Solar Ethanol Distillation Oara Neumann,1,3

    E-Print Network [OSTI]

    O-9 Solar Ethanol Distillation Oara Neumann,1,3 Albert D. Neumann,2 Julius Müller,1 of separation, particularly distillation. The 40,000 commercial distillation columns in use in the U. S. consume or product purity. Distillation is the critical energy-consuming step accounting for 70-85% of the energy

  1. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA SØRENSEN 3 and RAJAB distillation schemes. A simple feedback control strategy for the total reflux operation of a multivessel column distillation generally is less energy efficient than continuous distillation, it has received increased

  2. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA S RENSEN 3 and RAJAB distillation schemes. A simple feedback control strategy for the total re ux operation of a multivessel column distillation generally is less energy e cient than continuous distillation, it has received increased attention

  3. Multipartite secret key distillation and bound entanglement

    E-Print Network [OSTI]

    Remigiusz Augusiak; Pawel Horodecki

    2009-09-25T23:59:59.000Z

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted GHZ structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with help of the privacy squeezing technique.

  4. Multipartite secret key distillation and bound entanglement

    SciTech Connect (OSTI)

    Augusiak, Remigiusz; Horodecki, Pawel [Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk (Poland) and ICFO-Institute Ciencies Fotoniques, Mediterranean Technology Park, 08860 Castelldefels (Barcelona) (Spain); Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk (Poland)

    2009-10-15T23:59:59.000Z

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted Greenberger-Horne-Zeilinger (GHZ) structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with the help of the privacy squeezing technique.

  5. Absorptive Recycle of Distillation Waste Heat

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    ABSORPTIVE RECYCLE OF DISTILLATION WASTE HEAT Donald C. Erickson and Edward J. Lutz Jr. Energy Concepts Company Annapolis, Maryland ABSTRACT When the heat source available to a distillation process is at a significantly higher temperature... which conserve 60 to 70%. Also, there are ver sions which incorporate separate low tem perature waste heat streams and thereby conserve over 90% of the required dis tillation energy. The main limitations of the R/AHP are the need for sufficient...

  6. Table 16. U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910. Average3.5.6.

  7. Table 21. U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910.9. Average1.

  8. Co-processing of carbonaceous solids and petroleum oil

    DOE Patents [OSTI]

    Gupta, Avinash (Bloomfield, NJ); Greene, Marvin I. (Oradell, NJ)

    1992-01-01T23:59:59.000Z

    In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the thermal liquefaction heater. Coal may be co-processed with petroleum oil by adding pre-hydrogenated oil to the first stage or unhydrogenated oil to the second stage.

  9. Distillate Fuel Oil Sales for All Other Uses

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecadeReservesYear21CompanySFoot)YearD e

  10. Distillate Fuel Oil Sales for Off-Highway Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at

  11. Distillate Fuel Oil Sales for Vessel Bunkering Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127 1,710,513

  12. East Coast (PADD 1) Distillate Fuel Oil Imports

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877SouthwestWisconsinStatement 1 June 7, 2013Nov-14

  13. Gross Input to Atmospheric Crude Oil Distillation Units

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688Electricity UseFoot) YearNetper

  14. Distillate Fuel Oil Assessment for Winter 1995-1996

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline353/06) 2Yonthly Energy : b ra&le.com 1U.S.

  15. Stocks of Distillate Fuel Oil 15 ppm Sulfur and Under

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights ï‚·2008DeutscheState470,603

  16. Stocks of Distillate Fuel Oil Greater Than 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights ï‚·2008DeutscheState470,6036,190

  17. Refiner and Blender Net Production of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a evie _ =_ In7, 20116,650.0 Weekly7a.7.Nov-145,083 5,011

  18. Coke oven gas desulphurization by the Carl Still process

    SciTech Connect (OSTI)

    Knight, R.E.

    1981-01-01T23:59:59.000Z

    The Steubenville East Coke Plant need a desulfurization process that would desulfurize an eventual 95 million standard cubic feet per day of coke oven gas from an inlet of 450 gr/DSCF to an outlet of 45 gr/DSCF of hydrogen sulfide. The Dravo/Still plant process was selected, due to the use of ammonia which was available in the gas, as the absorbing agent. It was also a proven process. Dravo/Still also was capable of building a sulfuric acid plant. The desulfurization efficiency of the plant has consistently provided an average final gas sulfur loading below the guaranteed 45 gr/DSCF. This removal efficiency has enabled production of an average of 4615 tons per day of 66/sup 0/Be acid. Also SO/sub 2/ to SO/sub 3/ conversion has averaged 98%. 3 figures. (DP)

  19. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01T23:59:59.000Z

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  20. Pipeline charging of coke ovens with a preheated charge

    SciTech Connect (OSTI)

    Karpov, A.V.; Khadzhioglo, A.V.; Kuznichenko, V.M.

    1983-01-01T23:59:59.000Z

    Work to test a pipeline charging method was conducted at the Konetsk Coke Works (a PK-2K coke oven system with a single gas main, oven width 407 mm, height 4300 mm, effective column 20.0 cm/sub 3/). This method consists of transporting the heated coal charge to the ovens through a pipe by means of steam. the charge is transported by high pressure chamber groups, and loaded by means of systems equipped with devices for separation, withdrawal and treatment of the spent steam. The principal goal of the present investigation was to test technical advances in the emission-free charging of preheated charges. The problem was, first, to create a reliable technology for separation of the steam from the charge immediately before loading it into the oven and, second, to provide a total elimination of emissions, thereby protecting the environment against toxic substances.

  1. Local purity distillation with bounded classical communication

    E-Print Network [OSTI]

    Hari Krovi; Igor Devetak

    2007-05-28T23:59:59.000Z

    Local pure states are an important resource for quantum computing. The problem of distilling local pure states from mixed ones can be cast in an information theoretic paradigm. The bipartite version of this problem where local purity must be distilled from an arbitrary quantum state shared between two parties, Alice and Bob, is closely related to the problem of separating quantum and classical correlations in the state and in particular, to a measure of classical correlations called the one-way distillable common randomness. In Phys. Rev. A 71, 062303 (2005), the optimal rate of local purity distillation is derived when many copies of a bipartite quantum state are shared between Alice and Bob, and the parties are allowed unlimited use of a unidirectional dephasing channel. In the present paper, we extend this result to the setting in which the use of the channel is bounded. We demonstrate that in the case of a classical-quantum system, the expression for the local purity distilled is efficiently computable and provide examples with their tradeoff curves.

  2. New environmental concepts in the chemical and coke industries

    SciTech Connect (OSTI)

    A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

    2007-05-15T23:59:59.000Z

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  3. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31T23:59:59.000Z

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  4. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21T23:59:59.000Z

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  5. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01T23:59:59.000Z

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  6. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro [Kobe Steel Ltd. (Japan). Kobe Works

    1997-12-31T23:59:59.000Z

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  7. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31T23:59:59.000Z

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  8. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31T23:59:59.000Z

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  9. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01T23:59:59.000Z

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  10. The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties

    SciTech Connect (OSTI)

    Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

    2006-07-01T23:59:59.000Z

    In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

  11. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  12. X-ray evaluation of coke-oven gas line deposits

    SciTech Connect (OSTI)

    Swain, Y.T.

    1983-08-01T23:59:59.000Z

    Control of coke-oven gas pipeline deposits has been facilitated through the use of an X-ray technique that provides quantitative data without disrupting plant operations.

  13. An evaluation of the potential end uses of a Utah tar sand bitumen. [Tar sand distillate

    SciTech Connect (OSTI)

    Thomas, K.P.; Harnsberger, P.M.; Guffey, F.D.

    1986-09-01T23:59:59.000Z

    To date the commercial application of tar sand deposits in the United States has been limited to their use as paving materials for county roads, parking lots, and driveways because the material, as obtained from the quarries, does not meet federal highway specifications. The bitumen in these deposits has also been the subject of upgrading and refining studies to produce transportation fuels, but the results have not been encouraging from an economic standpoint. The conversion of tar sand bitumen to transportation fuels cannot compete with crude oil refining. The purposes of this study were two-fold. The first was to produce vacuum distillation residues and determine if their properties met ASTM asphalt specifications. The second was to determine if the distillates could serve as potential feedstocks for the production of aviation turbine fuels. The bitumen used for this study was the oil produced during an in situ steamflood project at the Northwest Asphalt Ridge (Utah) tar sand deposit. Two distillation residues were produced, one at +316/sup 0/C and one at +399/sup 0/C. However, only the lower boiling residue met ASTM specifications, in this case as an AC-30 asphalt. The original oil sample met specifications as an AC-5 asphalt. These residue samples showed some unique properties in the area of aging; however, these properties need to be investigated further to determine the implications. It was also suggested that the low aging indexes and high flow properties of the asphalts may be beneficial for pavements that require good low-temperature performance. Two distillate samples were produced, one at IBP-316/sup 0/C and one at IBP-399/sup 0/C. The chemical and physical properties of these samples were determined, and it was concluded that both samples appear to be potential feedstocks for the production of aviation turbine fuels. However, hydrogenation studies need to be conducted and the properties of the finished fuels determined to verify the prediction. 14 refs., 12 tabs.

  14. Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates

    SciTech Connect (OSTI)

    Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

    1987-04-01T23:59:59.000Z

    High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

  15. Energy Saving in Distillation Using Structured Packing and Vapor Recompression

    E-Print Network [OSTI]

    Hill, J.H.

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated distillation columns. Larger...

  16. Desalination Using Vapor-Compression Distillation

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    the outgoing salt concentration was 1.5% and 7%, respectively. Distillation was performed at 439 K (331oF) and 722 kPa (105 psia) for both brackish water feed and seawater feed. Water costs of the various conditions were calculated for brackish water...

  17. Distillation: Present Status and Future Directions

    E-Print Network [OSTI]

    Fair, J. R.; Humphrey, J. L.

    1984-01-01T23:59:59.000Z

    -pressure steam as a heat source. The steam has, very likely, been sent through one or more users (turbi ne dri ves) before reaching the distillation reboiler. It seems almost characteristic of large chemical and refining complexes that there is a chronic...

  18. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    to distillation columns ac- count for roughly 3 of the total energy consumption in the U.S. (Ognisty 1995 to reduce energy consumption at least two alternative approaches have been proposed both in the literature is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  19. Energy Conservation Options in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    I ENERGY CONSERVATION OPTIONS IN DISTILLATION PROCESSES G.E. Harris, W.R. Hearn, G.M. Blythe, and J.M. Stuart, Radian Corporation, Austin, Texas I This paper summarizes the results of a survey of energy conservation options applicable...

  20. Distilling one-qubit magic states into Toffoli states

    E-Print Network [OSTI]

    Bryan Eastin

    2013-02-21T23:59:59.000Z

    For certain quantum architectures and algorithms, most of the required resources are consumed during the distillation of one-qubit magic states for use in performing Toffoli gates. I show that the overhead for magic-state distillation can be reduced by merging distillation with the implementation of Toffoli gates. The resulting routine distills 8 one-qubit magic states directly to a Toffoli state, which can be used without further magic to perform a Toffoli gate.

  1. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits Distillation Model Relates overhead composition of propane with flowrate of propane feed to the splitter

  2. Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens,

    E-Print Network [OSTI]

    to infinity. We call such protocols asymp- totic and the fraction of distilled Bell states per initial copy#12;#12;Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens, Jeroen: July 13, 2006) We present a new asymptotic bipartite entanglement distillation protocol

  3. Optimal Control of a Continuous Distillation Process under Probabilistic Constraints

    E-Print Network [OSTI]

    Henrion, René

    Optimal Control of a Continuous Distillation Process under Probabilistic Constraints René Henrion1 Universität Berlin, Germany Abstract A continuous distillation process with random inflow rate is considered model including the dynamics of the distillation process and proba- bilistic constraints under different

  4. Bloggers as Experts Feed Distillation using Expert Retrieval Models

    E-Print Network [OSTI]

    de Rijke, Maarten

    Bloggers as Experts Feed Distillation using Expert Retrieval Models Krisztian Balog kbalog Kruislaan 403, 1098 SJ Amsterdam ABSTRACT We address the task of (blog) feed distillation: to find blogs- ness as feed distillation strategies. The two models capture the idea that a human will often search

  5. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS ­ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177­217, 1997. Abstract Distillation column dynamics and control has been viewed these, the feasibility of using the distillate­bottom structure for control (which was believed

  6. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed, the feasibility of using the distillate-bottomstructure for control which was believed to be impossible

  7. Column Initialization 1 Initializing Distillation Column Models 1

    E-Print Network [OSTI]

    Dundee, University of

    Column Initialization 1 Initializing Distillation Column Models 1 Roger Fletcher \\Lambda with the optimisation of distillation column models by non­ linear programming are considered. The paper presents of the distillation column model. A certain limiting case of the column model is examined, that of infinite reflux

  8. Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b a SINTEF ICT, Applied Keywords: Distillation Minimum energy Energy saving Dividing wall column Petlyuk arrangement Vmin-diagram a b s t r a c t Distillation is responsible for a significant amount of the energy consumption

  9. Many copies may be required for entanglement distillation John Watrous

    E-Print Network [OSTI]

    Watrous, John

    Many copies may be required for entanglement distillation John Watrous Department of Computer state shared between two parties is said to be distillable if, by means of a protocol involving only |+ = (|00 + |11 )/ 2. In this paper it is proved that there exist states that are distillable

  10. Active constraint regions for optimal operation of distillation columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Active constraint regions for optimal operation of distillation columns Magnus G. Jacobsen the control structure of distillation columns, with optimal operation in mind, it is important to know how for distillation columns change with variations in energy cost and feed flow rate. The production of the most

  11. Multiple copy distillation and purification of phase diffused squeezed states

    E-Print Network [OSTI]

    Petr Marek; Jaromir Fiurasek; Boris Hage; Alexander Franzen; James DiGugliemo; Roman Schnabel

    2007-11-16T23:59:59.000Z

    We provide a detailed theoretical analysis of multiple copy purification and distillation protocols for phase diffused squeezed states of light. The standard iterative distillation protocol is generalized to a collective purification of an arbitrary number of N copies. We also derive a semi-analytical expression for the asymptotic limit of the iterative distillation and purification protocol and discuss its properties.

  12. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio report a new approach to blog distillation, defined as the task in which, given a user query, the system of the TREC Blog Track. 1 Introduction Blog distillation is a subtask of the blog search task. It is defined

  13. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA S RENSEN 3 and RAJAB distillation schemes, including the inverted column and the middle vessel column. The total re ux operation of the multivessel batch distillation column was presented recently, and the main contribution of this paper

  14. Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures using Elementary) diagrams like distillation lines and isotherms maps may be used in analysis of the closed (total reflux) multivessel batch distillation column. An indirect level control strategy is implemented that eliminates

  15. Azeotropic Distillation as a Technique for Emulsion Size Reduction

    E-Print Network [OSTI]

    Petta, Jason

    Azeotropic Distillation as a Technique for Emulsion Size Reduction Taylor Emanuelle Sweet 2013 Prism/PCCM #12;Overview -Intro- What is Microfluidics? What is Heterogeneous Azeotropic Distillation microns in size and use Binary Heterogeneous Azeotropic Distillation to shrink droplets to 5-10 microns

  16. Model Predictive Control of a Kaibel Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Model Predictive Control of a Kaibel Distillation Column Martin Kvernland Ivar Halvorsen Sigurd (e-mail: skoge@ntnu.no) Abstract: This is a simulation study on controlling a Kaibel distillation column with model predictive control (MPC). A Kaibel distillation column has several advantages compared

  17. Multiple Steady States in Ideal Two-Product Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multiple Steady States in Ideal Two-Product Distillation Elling W. Jacobsen and Sigurd Skogestad Chemical Engineering Dept., University of Trondheim-NTH, N-7034 Trondheim, Norway Simple distillation and compositions in the column. Introduction Multiple steady states (multiplicity) in distillation columns have

  18. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT ·How can we separate ternary mixtures in closed batch distillation-up period is required, followed by a heteroazeotropic distillation step (Figure 3) Modified: The separation

  19. Effect of Number of Fractionating Trays on Reactive Distillation Performance

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

  20. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA SØRENSEN 3 and RAJAB distillation schemes, including the inverted column and the middle vessel column. The total reflux operation of the multivessel batch distillation column was presented recently, and the main contribution of this paper

  1. RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT

    E-Print Network [OSTI]

    RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT J. R. Taylor**, 0. Hansen*, C. Jensen*, 0. F. A risk analysis of a batch distillation unit is de- scribed. The analysis has been carried out at several.2. Objectives and organisation 5 1.2.2. Philosophy and approach 6 1.3.1. The distillation unit 8 1

  2. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    Solar thermal powered desalination: membrane versus distillation technologies G. Burgess and K Canberra ACT 0200 AUSTRALIA E-mail: greg.burgess@anu.edu.au Multiple Effect Distillation (MED) is generally assisted) desalination has been conducted. Solar thermal driven Multiple Effect Distillation (MED) has been

  3. Human versus Machine in the Topic Distillation Task Mingfang Wu

    E-Print Network [OSTI]

    Wu, Mingfang

    Human versus Machine in the Topic Distillation Task Mingfang Wu 1 , Gheorghe Muresan2 , Alistair Mc. The focus is on comparing humans and machine algorithms in terms of performance in a topic distillation task demonstrated that machines can perform nearly as well as people on the topic distillation task. Given a system

  4. Economically Optimal Control of Kaibel Distillation Column: Fixed boilup rate

    E-Print Network [OSTI]

    Skogestad, Sigurd

    : In this study, a control structure is designed for a 4-product dividing wall (Kaibel) distillation column, basedEconomically Optimal Control of Kaibel Distillation Column: Fixed boilup rate Maryam Ghadrdan distillation column; Vapour split manipulation; Self-optimizing control. 1. INTRODUCTION Thermally coupled

  5. Optimal Synthesis of Complex Distillation ColumnsUsing Rigorous Models

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    a review of recent work for the optimal design of distillation of individual columns using tray review of the area of optimal design and synthesis of distillation columns, emphasizing recentOptimal Synthesis of Complex Distillation ColumnsUsing Rigorous Models Ignacio E. Grossmann1 , Pío

  6. THE DOS AND DONTS OF DISTILLATION COLUMN CONTROL

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DOS AND DON·TS OF DISTILLATION COLUMN CONTROL S. Skogestadà Department of Chemical Engineering distillation column control within the general framework of plant- wide control. In addition, it aims at providing simple recommendations to assist the engineer in designing control systems for distillation

  7. Process for dissolving coke oven deposits comprising atomizing a composition containing N-methyl-2-pyrrolidone into the gas lines

    SciTech Connect (OSTI)

    Stafford, M.L.; Nicholson, G.M.

    1993-07-06T23:59:59.000Z

    A method is described for cleaning gas lines in coke oven batteries comprising atomizing a composition into the gas lines of coke oven batteries, where the composition comprises N-methyl-2-pyrrolidone.

  8. Takahax-Hirohax process for coke oven gas desulfurization

    SciTech Connect (OSTI)

    Gastwirth, H.; Miner, R.; Stengle, W.

    1981-01-01T23:59:59.000Z

    This paper describes the Takahax-Hirohax process to desulfurize coke oven gas and to produce an ammonium sulfate end product. A review is also made of current operating experience and recent technical developments. The Takahax-Hirohax process is extremely useful when the COG contains a suitable ammonia to sulfur ratio and when ammonium sulfate is a desirable end product. No contaminated effluent streams are emitted from the process. The process is simple, reliable, flexible, and responds easily to COG variations. 4 figures, 3 tables. (DP)

  9. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  10. Analytical input-output and supply chain study of China's coke and steel sectors

    E-Print Network [OSTI]

    Li, Yu, 1976-

    2004-01-01T23:59:59.000Z

    I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

  11. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31T23:59:59.000Z

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  12. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  13. Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

  14. Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

  15. Bethlehem Steel announces plans to control coke oven air and water pollution

    SciTech Connect (OSTI)

    Not Available

    1989-08-01T23:59:59.000Z

    Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

  16. Secret key distillation from shielded two-qubit states

    E-Print Network [OSTI]

    Joonwoo Bae

    2010-09-22T23:59:59.000Z

    The quantum states corresponding to a secret key are characterized using the so-called private states, where the key part consisting of a secret key is shielded by the additional systems. Based on the construction, it was shown that a secret key can be distilled from bound entangled states. In this work, I consider the shielded two-qubit states in a key-distillation scenario and derive the conditions under which a secret key can be distilled using the recurrence protocol or the two-way classical distillation, advantage distillation together with one-way postprocessing. From the security conditions, it is shown that a secret key can be distilled from bound entangled states in a much wider range. In addition, I consider the case that in which white noise is added to quantum states and show that the classical distillation protocol still works despite a certain amount of noise although the recurrence protocol does not.

  17. Qutrit Magic State Distillation Tight in Some Directions

    E-Print Network [OSTI]

    Hillary Dawkins; Mark Howard

    2015-04-22T23:59:59.000Z

    Magic state distillation is a crucial component in the leading approaches to implementing universal fault tolerant quantum computation, with existing protocols for both qubit and higher dimensional systems. Early work focused on determining the region of distillable states for qubit protocols, yet comparatively little is known about which states can be distilled and with what distillable region for d>2. Here we focus on d=3 and present new four-qutrit distillation schemes that improve upon the known distillable region, and achieve distillation tight to the boundary of undistillable states for some classes of state. As a consequence of recent results, this implies that there is a family of quantum states that enable universality if and only if they exhibit contextuality with respect to stabilizer measurements. We also identify a new routine whose fixed point is a magic state with maximal sum-negativity i.e., it is maximally non-stabilizer in a specific sense.

  18. Secret key distillation from shielded two-qubit states

    SciTech Connect (OSTI)

    Bae, Joonwoo [School of Computational Sciences, Korea Institute for Advanced Study, Seoul 130-722 (Korea, Republic of)

    2010-05-15T23:59:59.000Z

    The quantum states corresponding to a secret key are characterized using the so-called private states, where the key part consisting of a secret key is shielded by the additional systems. Based on the construction, it was shown that a secret key can be distilled from bound entangled states. In this work, I consider the shielded two-qubit states in a key-distillation scenario and derive the conditions under which a secret key can be distilled using the recurrence protocol or the two-way classical distillation, advantage distillation together with one-way postprocessing. From the security conditions, it is shown that a secret key can be distilled from bound entangled states in a much wider range. In addition, I consider the case that in which white noise is added to quantum states and show that the classical distillation protocol still works despite a certain amount of noise although the recurrence protocol does not.

  19. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27T23:59:59.000Z

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  20. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20T23:59:59.000Z

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  1. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01T23:59:59.000Z

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  2. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01T23:59:59.000Z

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  3. Desulphurization of coke oven gas by the Stretford Process

    SciTech Connect (OSTI)

    Plenderleith, J.

    1981-01-01T23:59:59.000Z

    The Stretford process is probably the most effective means available for removing hydrogen sulphide from gas streams. For streams which do not contain hydrogen cyanide or excessive oxygen it should be nearly ideal. However, the large volume of waste liquor generated by fixation of hydrogen cyanide has prevented its widespread adoption for coke oven gas treatment. Investigations of various proposals for treating the waste liquor indicate that the only practicable way of dealing with it is by reductive incineration. Although attempts to apply the Peabody-Holmes reductive incineration process have been disappointing, significant progress in overcoming some of its deficiencies has been made. The Zimpro wet oxidation process will provide a convenient method of treating the HCN scrubber effluent at No. 1 Plant. However, it will not treat the sodium based liquor from the Stretford plant. Its application to Stretford waste treatment is limited to situations where ammonium liquors and ammonium sulphate recovery facilities are available. Commissioning of this plant has been delayed while a defect in the air compressor supplied for the plant is being remedied. When the problem of liquid effluent disposal has been overcome, and if reagent chemicals continue to be available at reasonable prices, the Stretford process will be a good choice for coke oven gas desulphurization. 8 figures.

  4. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  5. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  6. The attractor mechanism as a distillation procedure

    E-Print Network [OSTI]

    Péter Lévay; Szilárd Szalay

    2010-04-14T23:59:59.000Z

    In a recent paper it has been shown that for double extremal static spherically symmetric BPS black hole solutions in the STU model the well-known process of moduli stabilization at the horizon can be recast in a form of a distillation procedure of a three-qubit entangled state of GHZ-type. By studying the full flow in moduli space in this paper we investigate this distillation procedure in more detail. We introduce a three-qubit state with amplitudes depending on the conserved charges the warp factor, and the moduli. We show that for the recently discovered non-BPS solutions it is possible to see how the distillation procedure unfolds itself as we approach the horizon. For the non-BPS seed solutions at the asymptotically Minkowski region we are starting with a three-qubit state having seven nonequal nonvanishing amplitudes and finally at the horizon we get a GHZ state with merely four nonvanishing ones with equal magnitudes. The magnitude of the surviving nonvanishing amplitudes is proportional to the macroscopic black hole entropy. A systematic study of such attractor states shows that their properties reflect the structure of the fake superpotential. We also demonstrate that when starting with the very special values for the moduli corresponding to flat directions the uniform structure at the horizon deteriorates due to errors generalizing the usual bit flips acting on the qubits of the attractor states.

  7. Chemical Composition and Insecticidal Properties of Thymus numidicus (Poiret) Essential Oil from Algeria

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    were isolated by steam distillation, analysed by gas chromatography coupled with the mass spectrometry toxicity of global oil recovered after one hour of extraction and its fraction F1 recovered after 2 distillation is a very rapid process and the duration of extraction could be limited to15 minutes, since more

  8. OIL AND GREASE: A PROPOSED ANALYTICAL METHOD FOR

    E-Print Network [OSTI]

    because a slight oil residue may carryover into the oil fraction. Blend about 100 parts of Celite (vol) PE, filter and apply suction until reasonably dry. Air dry and store in a jar. Filter paper dispersion: Blend 20 7-cm filter paper disks (Whatman 1 or 40) with distilled water in a blender for 5 - 10

  9. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01T23:59:59.000Z

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  10. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  11. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31T23:59:59.000Z

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  12. Surface code implementation of block code state distillation

    E-Print Network [OSTI]

    Austin G. Fowler; Simon J. Devitt; Cody Jones

    2013-01-29T23:59:59.000Z

    State distillation is the process of taking a number of imperfect copies of a particular quantum state and producing fewer better copies. Until recently, the lowest overhead method of distilling states |A>=(|0>+e^{i\\pi/4}|1>)/\\sqrt{2} produced a single improved |A> state given 15 input copies. New block code state distillation methods can produce k improved |A> states given 3k+8 input copies, potentially significantly reducing the overhead associated with state distillation. We construct an explicit surface code implementation of block code state distillation and quantitatively compare the overhead of this approach to the old. We find that, using the best available techniques, for parameters of practical interest, block code state distillation does not always lead to lower overhead, and, when it does, the overhead reduction is typically less than a factor of three.

  13. Iterative Entanglement Distillation: Approaching full Elimination of Decoherence

    E-Print Network [OSTI]

    Boris Hage; Aiko Samblowski; James DiGuglielmo; Jaromír Fiurášek; Roman Schnabel

    2010-07-09T23:59:59.000Z

    The distribution and processing of quantum entanglement form the basis of quantum communication and quantum computing. The realization of the two is difficult because quantum information inherently has a high susceptibility to decoherence, i.e. to uncontrollable information loss to the environment. For entanglement distribution, a proposed solution to this problem is capable of fully eliminating decoherence; namely iterative entanglement distillation. This approach builds on a large number of distillation steps each of which extracts a number of weakly decohered entangled states from a larger number of strongly decohered states. Here, for the first time, we experimentally demonstrate iterative distillation of entanglement. Already distilled entangled states were further improved in a second distillation step and also made available for subsequent steps.Our experiment displays the realization of the building blocks required for an entanglement distillation scheme that can fully eliminate decoherence.

  14. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  15. Energy efficiency of alternative coke-free metallurgical technologies

    SciTech Connect (OSTI)

    V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

    2009-02-15T23:59:59.000Z

    Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

  16. W-like bound entangled states and secure key distillation

    E-Print Network [OSTI]

    Remigiusz Augusiak; Pawel Horodecki

    2009-09-09T23:59:59.000Z

    We construct multipartite entangled states with underlying W-type structure satisfying positive partial transpose (PPT) condition under any (N-1)|1 partition. Then we show how to distill N-partite secure key form the states using two different methods: direct application of local filtering and novel random key distillation scheme in which we adopt the idea form recent results on entanglement distillation. Open problems and possible implications are also discussed.

  17. Quantum states representing perfectly secure bits are always distillable

    E-Print Network [OSTI]

    Pawel Horodecki; Remigiusz Augusiak

    2007-11-06T23:59:59.000Z

    It is proven that recently introduced states with perfectly secure bits of cryptographic key (private states representing secure bit) [K. Horodecki et al., Phys. Rev. Lett. 94, 160502 (2005)] as well as its multipartite and higher dimension generalizations always represent distillable entanglement. The corresponding lower bounds on distillable entanglement are provided. We also present a simple alternative proof that for any bipartite quantum state entanglement cost is an upper bound on distillable cryptographic key in bipartite scenario.

  18. Fuel oil and kerosene sales 1994

    SciTech Connect (OSTI)

    NONE

    1995-09-27T23:59:59.000Z

    This publication contains the 1994 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the sixth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA)for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1994 edition marks the 11th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Distillate and residual fuel oil sales continued to move in opposite directions during 1994. Distillate sales rose for the third year in a row, due to a growing economy. Residual fuel oil sales, on the other hand, declined for the sixth year in a row, due to competitive natural gas prices, and a warmer heating season than in 1993. Distillate fuel oil sales increased 4.4 percent while residual fuel oil sales declined 1.6 percent. Kerosene sales decreased 1.4 percent in 1994.

  19. Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves

    SciTech Connect (OSTI)

    Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

    1996-11-01T23:59:59.000Z

    Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

  20. Energy Conservation Options in Distillation Processes

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    ~itroo.? ':!OD.e~tell.,..ot!.k1 .'k..,.-.ottNltlu'..,. II ""'I'JI ..... ~I_ """-.4008l1"OO I ~.z.,. 1 ,1'1 (-frl-.'....u_~ R.da at AC~Ofllftl\\,J'ftlit...." ? I 5 "'-tlnc&! Tt.,.. ? 21.' \\lip Gilil.In31 j TnyE.'tIc>Mcy .11.1'llo I ~~TI""'.'2.at... I There are many options available to the engi*eer seeking to reduce the energy requirements of a distil lation process. The technology for most of these I, options has been available for many years, but it has only recently become economically...

  1. Use of computers for multicomponent distillation calculations

    E-Print Network [OSTI]

    Sullivan, Samuel Lane

    1959-01-01T23:59:59.000Z

    The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

  2. New Design Methods and Algorithms for Multi-component Distillation...

    Broader source: Energy.gov (indexed) [DOE]

    CX-100137 Categorical Exclusion Determination ITP Chemicals: Hybripd SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Energy...

  3. Integrated Thermal and Hydraulic Analysis of Distillation Columns

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    . The paper outlines how bringing together the column thermal and hydraulics analysis provides significant additional insights to help screen the options for distillation column revamps....

  4. Local Gaussian operations can enhance continuous-variable entanglement distillation

    E-Print Network [OSTI]

    ShengLi Zhang; Peter van Loock

    2011-03-23T23:59:59.000Z

    Entanglement distillation is a fundamental building block in long-distance quantum communication. Though known to be useless on their own for distilling Gaussian entangled states, local Gaussian operations may still help to improve non-Gaussian entanglement distillation schemes. Here we show that by applying local squeezing operations, both the performance and the efficiency of existing distillation protocols can be enhanced. We derive the optimal enhancement through local Gaussian unitaries, which can be obtained even in the most natural scenario when Gaussian mixed entangled states are shared after their distribution through a lossy-fiber communication channel.

  5. advanced distillation control: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Morari California.Eng., Norwegian Institute of Technology (NTH), N-7034 Trondheim, Norway Paper presented at Symposium Distillation Skogestad, Sigurd 14 CONTROL AND ENERGY...

  6. azeotropic distillation columns: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT How can we separate ternary mixtures in closed batch...

  7. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    on the price of home heating oil may also be obtained byincluding kerosene, home heating oil, range oil, stove oil,to most marketers of home heating oil. Consequently, during

  8. Producing and controlling of the pollutant in the coal`s coking process

    SciTech Connect (OSTI)

    Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

    1997-12-31T23:59:59.000Z

    In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

  9. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  10. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  11. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite 

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    45 Figure 9. Relationship between enhanced coke formation with increasing yields of paraffins and diminishing yields of olefins 46 Figure 10. Gas chromatogram of the concentrated carbon tetrachloride extract of spent catalyst pellets . . . 49...THE NATURE ABD FORMATION OF COKE IB THE REACTIOB OF METHANOL TO HIDROCARBOBS OVER CHABAZITE A Thesis KENNETH WOOT MCLAUGHLLN Submitted to the Graduate College of Texas AAM Univers ty partial. fulfillment nf the req~nt fo~he degree of MASTER...

  12. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  13. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  14. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01T23:59:59.000Z

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  15. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  16. NONLINEAR MPC BASED ON MULTI-MODEL FOR DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Foss, Bjarne A.

    NONLINEAR MPC BASED ON MULTI-MODEL FOR DISTILLATION COLUMNS Bjarne A. Foss1 , Song-Bo Cong established for a petroleum distillation column through first principle analysis, and its parameters have been-estimation and prediction in a MPC scheme. The controller has been applied to quality control of a FCCU fractionator

  17. Optimum Requirements for the Synthesis of Biodiesel Using Fatty Acid Distillates

    E-Print Network [OSTI]

    Akunna E. Ejele

    The optimum requirements of temperature, retention time, mole ratio of reactants and catalyst for the direct synthesis of biodiesel from fatty acid distillates of palm kernel oil using tetraoxosulphate (VI) acid as catalyst was studied. The following parameters were used for the efficient and economic production of biodiesel: eight (8) moles of methanol per mole of fatty acid, 0.06 mole of tetraoxosulphate (VI) acid per mole of fatty acid, a retention time of sixty (60) minutes and reaction temperature of 65 OC. And this gave a maximum percentage yield of 98.4. Other parameters obtained include: an acid value of 0.1683 mg KOH/g, iodine value of 15.3549, flash point of 209 OC, viscosity of 3.7957 mm2s-1, density of 0.8776 g cm-3, water content of 400.05 mg kg-1, soap content of 2.30 mg/kg, and ester content of 98.804 %. From the obtained parameters, the biodiesel produced from fatty acid distillates of palm kernel oil reaches prescribed international standards for biodiesel production.

  18. A Decision Mechanism for the Selective Combination of Evidence in Topic Distillation

    E-Print Network [OSTI]

    Jose, Joemon M.

    A Decision Mechanism for the Selective Combination of Evidence in Topic Distillation Vassilis combination of evidence for Web Information Retrieval and particularly for topic distillation. We introduce. Keywords Web information retrieval, Topic distillation, decision mechanism, selective combination

  19. Temperature Collocation Algorithm for Fast and Robust Distillation Libin Zhang and Andreas A. Linninger*

    E-Print Network [OSTI]

    Linninger, Andreas A.

    Temperature Collocation Algorithm for Fast and Robust Distillation Design Libin Zhang and Andreas A mixtures that exhibit suitable volatility differences.1 Hence, continuous distillation columns, along commodity manufacturing. The common practice for distillation design often involves numerous trial

  20. Non-Gaussian entanglement distillation for continuous variables

    E-Print Network [OSTI]

    Hiroki Takahashi; Jonas S. Neergaard-Nielsen; Makoto Takeuchi; Masahiro Takeoka; Kazuhiro Hayasaka; Akira Furusawa; Masahide Sasaki

    2009-07-13T23:59:59.000Z

    Entanglement distillation is an essential ingredient for long distance quantum communications. In the continuous variable setting, Gaussian states play major roles in quantum teleportation, quantum cloning and quantum cryptography. However, entanglement distillation from Gaussian states has not yet been demonstrated. It is made difficult by the no-go theorem stating that no Gaussian operation can distill Gaussian states. Here we demonstrate the entanglement distillation from Gaussian states by using measurement-induced non-Gaussian operations, circumventing the fundamental restriction of the no-go theorem. We observed a gain of entanglement as a result of conditional local subtraction of a single photon or two photons from a two-mode Gaussian state. Furthermore we confirmed that two-photon subtraction also improves Gaussian-like entanglement as specified by the Einstein-Podolsky-Rosen (EPR) correlation. This distilled entanglement can be further employed to downstream applications such as high fidelity quantum teleportation and a loophole-free Bell test.

  1. Experimental and analytical modeling studies of steam injection with hydrocarbon additives to enhance recovery of San Ardo heavy oil 

    E-Print Network [OSTI]

    Simangunsong, Roly

    2006-10-30T23:59:59.000Z

    Experimental and analytical studies have been carried out to better understand production mechanisms of heavy oil under steam injection with propane and petroleum distillate as steam additives. The studies have been conducted ...

  2. Two-stage hydrotreating of a bitumen-derived middle distillate to produce diesel and jet fuels, and kinetics of aromatics hydrogenation

    SciTech Connect (OSTI)

    Yui, S.M. [Syncrude Canada Ltd., Edmonton, Alberta (Canada)

    1994-12-31T23:59:59.000Z

    The middle distillate from a synthetic crude oil derived from Athabasca bitumen was further hydrotreated in a downflow pilot unit over a typical NiMo catalyst at 330 to 400 C, 7 to 11 MPa and 0.63 to 1.39 h{sup {minus}1} LHSV. Feed and liquid products were characterized for aromatics, cetane index (CI) and other diesel specification items. Aromatics were determined by a supercritical fluid chromatography method, while CI was determined using the correlation developed at Syncrude Canada Ltd. Also feed and selected products were distilled into a jet fuel cut (150/260 C) by spinning band distillation for the determination of smoke point and other jet fuel specification items. A good relationship between aromatics content and CI was obtained. Kinetics of aromatics hydrogenation were investigated, employing a simple-first order reversible reaction model.

  3. Multilevel distillation of magic states for quantum computing

    E-Print Network [OSTI]

    Cody Jones

    2013-03-27T23:59:59.000Z

    We develop a procedure for distilling magic states used in universal quantum computing that requires substantially fewer initial resources than prior schemes. Our distillation circuit is based on a family of concatenated quantum codes that possess a transversal Hadamard operation, enabling each of these codes to distill the eigenstate of the Hadamard operator. A crucial result of this design is that low-fidelity magic states can be consumed to purify other high-fidelity magic states to even higher fidelity, which we call "multilevel distillation." When distilling in the asymptotic regime of infidelity $\\epsilon \\rightarrow 0$ for each input magic state, the number of input magic states consumed on average to yield an output state with infidelity $O(\\epsilon^{2^r})$ approaches $2^r+1$, which comes close to saturating the conjectured bound in [Phys. Rev. A 86, 052329]. We show numerically that there exist multilevel protocols such that the average number of magic states consumed to distill from error rate $\\epsilon_{\\mathrm{in}} = 0.01$ to $\\epsilon_{\\mathrm{out}}$ in the range $10^{-5}$ to $10^{-40}$ is about $14\\log_{10}(1/\\epsilon_{\\mathrm{out}}) - 40$; the efficiency of multilevel distillation dominates all other reported protocols when distilling Hadamard magic states from initial infidelity 0.01 to any final infidelity below $10^{-7}$. These methods are an important advance for magic-state distillation circuits in high-performance quantum computing, and they provide insight into the limitations of nearly resource-optimal quantum error correction.

  4. Distillation and Dehydro Reactors Advanced Process Conrol Freeport Texas PLant

    E-Print Network [OSTI]

    Eisele, D.

    2014-01-01T23:59:59.000Z

    Distillation and Dehydro Reactors Advanced Process Control Freeport Texas Plant ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation...-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC – Control Matrix 6/2/2014 INTERNAL; CONFIDENTIAL 3 ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology...

  5. Construction and operation of a flash distillation apparatus

    E-Print Network [OSTI]

    Knezevich, Milan

    1940-01-01T23:59:59.000Z

    VII HElPEL D1STILLATIONS OF FLASH DISTILLATES OF OKLAHOMA CITY CRUDE Flash Temperature of Distillate XII DoE. F, 260 308 342 392 Volume Distilled per oent Telsp e deE. F. Temp e deE ~ Fs Toslp e doge Fo Tolllp Tolsp e deg. F, doE ~ F..., and they lose much of their kinetio energy to the high boiling molocules ~ Therefore, the solution does not start to vaporise at tho normal boiling point of the low boiling components At low percentages vaporissd flash vaporisation requires a higher vapor...

  6. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  7. Diffusion and Reactivity of Gas Oil in FCC Catalysts SULAIMAN Al-KHATTAF, HUGO I. de LASA*

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    developed in a novel CREC Simulator, is employed to estimate the unconverted gas oil, the gasoline and secondary cracking reactions and the yields of gasoline, coke and light gas yields. Key words: FCC, cracking in FCC units has become more prevalent due to the declining availability and as a result higher prices

  8. The Cylinder: Kinematics of the Nineteenth Century

    E-Print Network [OSTI]

    Müller-Sievers, Helmut

    2012-01-01T23:59:59.000Z

    distillation. The coking of coal as well as the productionin coal mines, in steel and paper mills, in coking plants,

  9. Dale Coke: Coke Farm

    E-Print Network [OSTI]

    Farmer, Ellen

    2010-01-01T23:59:59.000Z

    the right place to get compost, or how you get the beststerilized or pasteurized our compost before we put it out.

  10. LLNL oil shale project review

    SciTech Connect (OSTI)

    Cena, R.J. (ed.)

    1990-04-01T23:59:59.000Z

    Livermore's oil shale project is funded by two budget authorities, two thirds from base technology development and one third from environmental science. Our base technology development combines fundamental chemistry research with operation of pilot retorts and mathematical modeling. We've studied mechanisms for oil coking and cracking and have developed a detailed model of this chemistry. We combine the detailed chemistry and physics into oil shale process models (OSP) to study scale-up of generic second generation Hot-Recycled-Solid (HRS) retorting systems and compare with results from our 4 tonne-per-day continuous-loop HRS pilot retorting facility. Our environmental science program focuses on identification of gas, solid and liquid effluents from oil shale processes and development of abatement strategies where necessary. We've developed on-line instruments to quantitatively measure trace sulfur and nitrogen compounds released during shale pyrolysis and combustion. We've studied shale mineralogy, inorganic and organic reactions which generate and consume environmentally sensitive species. Figures, references, and tables are included with each discussion.

  11. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  12. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  13. Energy Use in Distillation Operation: Nonlinear Economic Effects

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation is obviously very...

  14. Magic-state distillation with the four-qubit code

    E-Print Network [OSTI]

    Meier, Adam M; Knill, Emanuel

    2012-01-01T23:59:59.000Z

    The distillation of magic states is an often-cited technique for enabling universal quantum computing once the error probability for a special subset of gates has been made negligible by other means. We present a routine for magic-state distillation that reduces the required overhead for a range of parameters of practical interest. Each iteration of the routine uses a four-qubit error-detecting code to distill the +1 eigenstate of the Hadamard gate at a cost of ten input states per two improved output states. Use of this routine in combination with the 15-to-1 distillation routine described by Bravyi and Kitaev allows for further improvements in overhead.

  15. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  16. Magic-state distillation with the four-qubit code

    E-Print Network [OSTI]

    Adam M. Meier; Bryan Eastin; Emanuel Knill

    2012-04-18T23:59:59.000Z

    The distillation of magic states is an often-cited technique for enabling universal quantum computing once the error probability for a special subset of gates has been made negligible by other means. We present a routine for magic-state distillation that reduces the required overhead for a range of parameters of practical interest. Each iteration of the routine uses a four-qubit error-detecting code to distill the +1 eigenstate of the Hadamard gate at a cost of ten input states per two improved output states. Use of this routine in combination with the 15-to-1 distillation routine described by Bravyi and Kitaev allows for further improvements in overhead.

  17. Synthesis and design of optimal thermal membrane distillation networks

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    Thermal membrane distillation is one of the novel separation methods in the process industry. It involves the simultaneous heat and mass transfer through a hydrophobic semipermeable membrane through the use of thermal energy to bring about...

  18. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01T23:59:59.000Z

    The absorption cycle offers one of the most economic and widely applicable technologies for waste heat upgrading. It can use off-the-shelf hardware that is available now, at any required capacity rating. Fractional distillations, as a class...

  19. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  20. Energy Use in Distillation Operation: Nonlinear Economic Effects 

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation ...

  1. The extraction of bitumen from western oil sands. Quarterly report, April--June 1993

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1993-07-01T23:59:59.000Z

    Accomplishments are briefly described for the following tasks: environmental impact statement; coupled fluidized bed bitumen recovery and coked sand combustion; water-based recovery of bitumen; rotary kiln process for recovery of bitumen and combustion of coke sand; recovery of bitumen from oil sands using fluidized bed reactors and combustion of spent sands in transport reactors; recovery of bitumen from oil sand and upgrading of bitumen by solvent extraction; catalytic and thermal upgrading of bitumens and bitumen-derived liquids; evaluation of Utah`s major oil sand deposits for the production of asphalt, high energy jet fuels and other specialty products; development of mathematical models for bitumen recovery and processing; completion of the cost examination study of the pilot plant restoration; development studies of equipment for three-product gravity separation of bitumen and sand; determine thickener requirements; and environmental studies of the North Salt Lake pilot plant rehabilitation and eventual operation and those environmental problems associated with eventual commercial products.

  2. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L. [Bethlehem Steel Corp., Burns Harbor, IN (United States); [Bethlehem Steel Corp., PA (United States)

    1997-12-31T23:59:59.000Z

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  3. Reducing WWW Latency and Bandwidth Requirements by RealTime Distillation

    E-Print Network [OSTI]

    California at Berkeley, University of

    Reducing WWW Latency and Bandwidth Requirements by Real­Time Distillation Armando Fox and Eric A Distillation and Refinement Can Help 1. The Concept of Datatype­Specific Distillation 2. Refinement 3. Trading. Optimizing for Rendering on Impoverished Devices 3. An Implemented HTTP Proxy Based on Real­Time Distillation

  4. Control strategies for reactive batch distillation Eva Swensen and Sigurd Skogestad"

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control strategies for reactive batch distillation Eva Swensen and Sigurd Skogestad" Department be combined directly with a distillation column by distilling off the light component product in order a maximum value in order to avoid break-through of an intermediate component in the distillate. This maximum

  5. Dividing wall columns for heterogeneous azeotropic distillation Quang-Khoa Le1

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Dividing wall columns for heterogeneous azeotropic distillation Quang-Khoa Le1 , Ivar J. Halvorsen2 of this work is to implement heterogeneous azeotropic distillation schemes in a dividing wall column (DWC distillation, Petlyuk arrangement, energy saving. 1. Introduction Distillation is one of the most energy

  6. Interferometric distillation and determination of unknown two-qubit entanglement

    E-Print Network [OSTI]

    S. -S. B. Lee; H. -S. Sim

    2010-06-08T23:59:59.000Z

    We propose a scheme for both distilling and quantifying entanglement, applicable to individual copies of an arbitrary unknown two-qubit state. It is realized in a usual two-qubit interferometry with local filtering. Proper filtering operation for the maximal distillation of the state is achieved, by erasing single-qubit interference, and then the concurrence of the state is determined directly from the visibilities of two-qubit interference. We compare the scheme with full state tomography.

  7. Heat Recovery in Distillation by Mechanical Vapor Recompression

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    tower energy requirements can be achieved by mechanical vapor recompression. Three design approaches for heating a distillation tower reboiler by mechanical vapor recompression are presented. The advantages of using a screw compressor are discussed... for lowering energy consumption in the distillation process through various heat recovery techniques. (3-8) One such technique utilizes mechanical vapor recompression. (9-12) The principle of this ap proach involves the use of a compressor to recycle...

  8. Single-step distillation protocol with generalized beam splitters

    SciTech Connect (OSTI)

    Martin-Delgado, M. A.; Navascues, M. [Departamento de Fisica Teorica I, Universidad Complutense, 28040 Madrid, (Spain)

    2003-07-01T23:59:59.000Z

    We develop a distillation protocol for multilevel qubits (qudits) using generalized beam splitters like in the proposal of Pan et al. for ordinary qubits. We find an acceleration with respect to the scheme of Bennet et al. when extended to qudits. It is also possible to distill entangled pairs of photons carrying orbital angular momenta states that conserve the total angular momenta as those produced in recent experiments.

  9. A short and simple explanation of how oil is converted into gasoline and then brought to

    E-Print Network [OSTI]

    it is not usable. It must first be sent to a refinery where it is converted into many dif- ferent products that we or thicker the oil, the more work the refinery must do to distill it into a useful form. The second, the most economical way to transport crude oil from the well to the refinery is through pipelines. While

  10. Key Distillation and the Secret-Bit Fraction

    E-Print Network [OSTI]

    Nick S. Jones; Lluis Masanes

    2008-05-12T23:59:59.000Z

    We consider distillation of secret bits from partially secret noisy correlations P_ABE, shared between two honest parties and an eavesdropper. The most studied distillation scenario consists of joint operations on a large number of copies of the distribution (P_ABE)^N, assisted with public communication. Here we consider distillation with only one copy of the distribution, and instead of rates, the 'quality' of the distilled secret bits is optimized, where the 'quality' is quantified by the secret-bit fraction of the result. The secret-bit fraction of a binary distribution is the proportion which constitutes a secret bit between Alice and Bob. With local operations and public communication the maximal extractable secret-bit fraction from a distribution P_ABE is found, and is denoted by Lambda[P_ABE]. This quantity is shown to be nonincreasing under local operations and public communication, and nondecreasing under eavesdropper's local operations: it is a secrecy monotone. It is shown that if Lambda[P_ABE]>1/2 then P_ABE is distillable, thus providing a sufficient condition for distillability. A simple expression for Lambda[P_ABE] is found when the eavesdropper is decoupled, and when the honest parties' information is binary and the local operations are reversible. Intriguingly, for general distributions the (optimal) operation requires local degradation of the data.

  11. Use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Popov, A.A.; Rezunenko, Yu.I.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution which show that the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be recovered in the form of ethylenethiourea - a marketable byproduct.

  12. Design, construction and start-up of a modern coke plant

    SciTech Connect (OSTI)

    Williams, A.E.

    1983-05-01T23:59:59.000Z

    The planning and design of a 60-oven, 6m replacement coke battery and associated by-products plant for Republic Steel Corp, Chicago, are described together with the constructional methods used and problems experienced through start-up of the facility. Pushing emission control is achieved with a Mitsubishi-type land-based system and changing emission control with a Nippon Steel combination car and land-based system. A Takahax-Hirohax coke-oven gas desulphurization unit is included in the by-product plant. Construction began in March 1979 with the first push in December 1981.

  13. The use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Rezunenko, Y.I.; Popov, A.A.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution showed the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be used in the form of ethylenethiourea - a marketable byproduct.

  14. The Role of the Flexicoking Process in Heavy Oil Processing 

    E-Print Network [OSTI]

    Taylor, R. I.

    1980-01-01T23:59:59.000Z

    a clean product slate composed of low Btu gas, high Btu gas, LPG, naphtha, distillate and gas oil. The low Btu gas falls within the definition of an "Alternate Fuel" under current legislation (PL 95-620). Originally developed for refinery bottoms...

  15. Crude Distillation Unit Heat Recovery Study

    E-Print Network [OSTI]

    John, P.

    1979-01-01T23:59:59.000Z

    to 426?F. There is no preheat of tower bottoms. All heat beyond the prefractionator comes from fired furnaces. But there is steam generation at 25 pounds pressure from hot oil and an approved project to generate ISO-pound steam from flue gas. Pipe Still... Sinks Sources Difference Disposition Sinks 110 (110) (213) Furnace Duty 400/690 430/720 255 152 (103) l50-Pound Steam Production 365/400 395/430 25 44 19 50-Pound Steam Production 300/365 330/395 47 80 33 29 25-Pound Steam...

  16. This Week In Petroleum Distillate Section

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910.9.The

  17. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    and Retail Fuel Oil Market Hi9hly Competitive • . . . • .Describe the heating oil market. Investigate coverage andprices in the heating oil market. on El1el5asis of----rnis-

  18. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    dislocation-of crude oil and products could jeopardize theoil, residual fuel oil and petroleum products and resultantof users of such oil or product." 34 The EPCA also provided

  19. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    1977-1978 HEATING OIL PRICES II-1 II-3 II-3 Wholesale PricesMonthly U.S. Heating Oil Prices, 1970 - 1978 . . A-16 .H-3 .continuous No. 2 heating oil price information from 1970 to

  20. Immobilization of vanadia deposited on catalytic materials during carbo-metallic oil conversion

    SciTech Connect (OSTI)

    Beck, H.W.; Carruthers, J.D.; Cornelius, E.B.; Hettinger, Jr., W.P.; Kovach, S.M.; Palmer, J.L.; Zandona, O.J.

    1988-06-14T23:59:59.000Z

    This patent describes a process for the cracking of a hydrocarbon oil feed having a significant content of at least 0.1 ppm vanadium to lighter oil products. The process consists of contacting the feed under conversion conditions in a conversion zone with a catalyst containing a precipitated metal additive to immobilize vanadium compounds by forming compounds therewith that have melting points above temperatures found in regenerating a coked catalyst; and having catalytic cracking characteristics, coke and vanadium being deposited on the catalyst by the contact; regenerating the coked catalyst in the presence of an oxygen containing gas at a temperature sufficient to remove at least some of the coke, and, recycling the regenerated catalyst to the conversion zone for contact with fresh feed; the metal additive being present on the catalyst in an amount sufficient to immobilize at least a portion of the vanadium compound in the presence of the oxygen containing gas at the catalyst regeneration temperature; wherein the metal additive to immobilize vanadium compounds deposited on the catalyst is selected from the group consisting of Sr, Sc, Y, Nb, and Ta elements, and an element in the actinide series, or a combination of two or more of the elements.

  1. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  2. Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore Torquatob)

    E-Print Network [OSTI]

    Torquato, Salvatore

    Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore of a Brownian particle diffusing among a, digitized lattice-based domain of traps. Following the first, the inverse of the trapping rate, is obtained for a variety of configurations involving digitized spheres

  3. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24T23:59:59.000Z

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  4. Final environmental information volume for the coke oven gas cleaning project at the Bethlehem Steel Corporation Sparrows Point Plant

    SciTech Connect (OSTI)

    Not Available

    1990-04-24T23:59:59.000Z

    Bethelehem Steel Corporation (BSC) is planning to conduct a demonstration project involving an integrated system that can be retrofitted into coke oven gas handling systems to address a variety of environmental and operational factors in a more cost-effective manner. Successful application of this technology to existing US coke plants could: (1) reduce emissions of sulfur dioxide, cyanide, and volatile organic compounds (including benzene) (2) reduce the cost and handling of processing feed chemicals, (3) disposal costs of nuisance by-products and (4) increase reliability and reduce operation/maintenance requirements for coke oven gas desulfurization systems. The proposed system will remove sulfur from the coke oven gas in the form of hydrogen sulfide using the ammonia indigenous to the gas as the primary reactive chemical. Ammonia and hydrogen cyanide are also removed in this process. The hydrogen sulfide removed from the coke oven gas in routed to a modified Claus plant for conversion to a saleable sulfur by-product. Ammonia and hydrogen cyanide will be catalytically converted to hydrogen, nitrogen, carbon dioxide, and carbon monoxide. The tail gas from the sulfur recovery unit is recycled to the coke oven gas stream, upstream of the new gas cleaning system. The proposed demonstration project will be installed at the existing coke oven facilities at BSC's Sparrows Point Plant. This volume describes the proposed actions and the resulting environmental impacts. 21 refs., 19 figs., 9 tabs.

  5. Non-Locality Distillation is Impossible for Isotropic Quantum Systems

    E-Print Network [OSTI]

    Dejan D. Dukaric

    2011-09-20T23:59:59.000Z

    Non-locality is a powerful resource for various communication and information theoretic tasks, e.g., to establish a secret key between two parties, or to reduce the communication complexity of distributed computing. Typically, the more non-local a system is, the more useful it is as a resource for such tasks. We address the issue of non-locality distillation, i.e., whether it is possible to create a strongly non-local system by local operations on several weakly non-local ones. More specifically, we consider a setting where non-local systems can be realized via measurements on underlying shared quantum states. The hardest instances for non-locality distillation are the isotropic quantum systems: if a certain isotropic system can be distilled, then all systems of the same non-locality can be distilled as well. The main result of this paper is that non-locality cannot be distilled from such isotropic quantum systems. Our results are based on the theory of cross norms defined over the tensor product of certain Banach spaces. In particular, we introduce a single-parameter family of cross norms, which is used to construct a hierarchy of convex sets that are closed under local operations. This hierarchy interpolates between the set of local systems and an approximation to the set of quantum systems.

  6. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01T23:59:59.000Z

    growth. For data on world oil consumption and long- term oilOil Production Domestic Oil Consumption a variety of

  7. Table 17. Average Price of U.S. Coke Exports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910. Average3.5.6.7.

  8. Table 22. Average Price of U.S. Coke Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oilAll Tables133,477 133,5910.9. Average1.2.

  9. China Energy Databook -- User Guide and Documentation, Version 7.0

    E-Print Network [OSTI]

    Fridley, Ed., David

    2008-01-01T23:59:59.000Z

    years report coking and oil refining investment in a singleyears report coking and oil refining investment in a singleyears report coking and oil refining investment in a single

  10. A New Protocol of Continuous-Variable Entanglement Distillation

    E-Print Network [OSTI]

    Shi Jin; Xian-Min Jin; Joshua Nunn; Animesh Datta; Ian Walmsley

    2012-10-16T23:59:59.000Z

    We introduce a new protocol in continuous variable entanglement distillation that requires only linear temporal and constant physical or spatial resources.Compared with the existing protocols, our protocol uses atom-photon entanglement to substitute for atom-atom entanglement in existing protol, which will not only save the number of quantum memories, but also has the advantages in operation efficiency and temporal saving. The distillation can be realized by a fixed model of iterations, in which only three quantum memories and photon detectors are required.

  11. Lubricating-oil basestock data and analysis: based on the ASTM-NBS basestock consistency study

    SciTech Connect (OSTI)

    Becker, D.A.; Hsu, S.M.; Weeks, S.

    1983-10-01T23:59:59.000Z

    In this 13-month study, four virgin oil and six re-refined oil companies submitted monthly production samples to National Bureau of Standards (NBS). There, the samples were subdivided, coded, and sent to 14 participating laboratories for analysis of the physical and chemical properties as well as for evaluation in various bench tests. An eleventh control sample was sent monthly for reference. Various re-refining processes included in the study are: acid/clay; clay treatment; short path distillation; pretreat/vacuum distillation/clay finish; pretreat/hydrogenation. The processes for the virgin base oils are mainly solvent extraction/distillation with and without the hydro-finishing step. In this report the data are grouped into six main categories: (1) theology; (2) physical properties; (3) chemical properties; (4) hydrocarbon type analysis; (5) general performance tests; and (6) oxidation and wear bench tests. Within each category, test results are arranged according to the similarity of the tests or test properties.

  12. "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science and Technology (NTNU) Department of Chemical Engineering Working Party on "Distillation, Absorption

  13. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E for manufacturing of ultra pure protium from hydrogen [2]. A principle of hydrogen cryogenic distillation was used

  14. December 13, 2012 The steady state model of a reactive distillation column for ethylene glycol

    E-Print Network [OSTI]

    Neumaier, Arnold

    December 13, 2012 The steady state model of a reactive distillation column for ethylene glycol in an ethylene glycol reactive distillation column. Ind. Eng. Chem. Res., 33:2738­2748, 1994. 3 #12;

  15. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  16. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

  17. Optimal distillation of three-qubit W states

    E-Print Network [OSTI]

    Ali Yildiz

    2010-07-19T23:59:59.000Z

    Some of the asymmetric three qubit $W$ states are used for perfect teleportation, superdense coding and quantum information splitting. We present the protocols for the optimal distillation of the asymmetric as well as the symmetric $W$ states from a single copy of any three qubit $W$ class pure state.

  18. The application of continuation methods in solving steady-state distillation problems

    E-Print Network [OSTI]

    Ellis, Mark Francis

    1985-01-01T23:59:59.000Z

    80 101 105 CHAPTER I INTRODUCTION Distillation is the most common separ ation process in the chemical and petroleum industr ies. A ma]or tool in the design of distillation columns is steady-state distillation simulation. Also, steady-stat. e...'s Equation 98 B BIFURCATION AND TURNING POINTS ON CONTINUATION PATHS 100 C FORMULATION OF MATHEMATICAI MODELS USED IN EXAMPLE PROBLEMS 104 Problem 1 ? A Conventional Distillation Column Separating an Ideal Solution Problem 2 ? A Conventional...

  19. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

    2009-05-15T23:59:59.000Z

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  20. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. (Armco Steel Co., Middletown, OH (United States))

    1993-01-01T23:59:59.000Z

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  1. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  2. Potential use of California lignite and other alternate fuel for enhanced oil recovery. Phase I and II. Final report. [As alternative fuels for steam generation in thermal EOR

    SciTech Connect (OSTI)

    Shelton, R.; Shimizu, A.; Briggs, A.

    1980-02-01T23:59:59.000Z

    The Nation's continued reliance on liquid fossil fuels and decreasing reserves of light oils gives increased impetus to improving the recovery of heavy oil. Thermal enhanced oil recovery EOR techniques, such as steam injection, have generally been the most effective for increasing heavy oil production. However, conventional steam generation consumes a large fraction of the produced oil. The substitution of alternate (solid) fuels would release much of this consumed oil to market. This two-part report focuses on two solid fuels available in California, the site of most thermal EOR - petroleum coke and lignite. Phase I, entitled Economic Analysis, shows detailed cost comparisons between the two candidate fuels and also with Western coal. The analysis includes fuels characterizations, process designs for several combustion systems, and a thorough evaluation of the technical and economic uncertainties. In Phase II, many technical parameters of petroleum coke combustion were measured in a pilot-plant fluidized bed. The results of the study showed that petroleum coke combustion for EOR is feasible and cost effective in a fluidized bed combustor.

  3. Cracking blends of gas oil and residual oil

    SciTech Connect (OSTI)

    Myers, G.D.

    1988-03-01T23:59:59.000Z

    In a catalytic cracking process unit wherein a gas oil feed is cracked in a cracking zone at an elevated temperature in the presence of a cracking catalyst, the cracking catalyst is regenerated in a regeneration zone by burning coke of the catalyst, and catalyst is circulated between the cracking zone and the regeneration zone. The improvement is described for obtaining a naphtha product of improved octane number comprising introducing sufficient of a nickel and vanadium metals-containing heavy feedstock with the gas oil feed introduced into the cracking zone to deposit nickel and vanadium metals on the catalyst and raise the nickel and metals-content of the catalyst to a level ranging from about 1500 to about 6000 parts per million of the metals expressed as equivalent nickel, based on the weight of the catalyst, and maintaining the nickel and vanadium metals level on the catalyst by withdrawing high nickel and vanadium metals containing catalyst and adding low nickel and vanadium metals-containing catalyst to the regeneration zone.

  4. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Distillation Ivar J. Halvorsen1 and Sigurd Skogestad Norwegian University of Science and Technology, Department at the Topical conference on Separations Technology, Session 23 - Distillation Modeling and Processes II. 2001 Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation Ivar J

  5. Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj Department structures for ethyl tert-butyl ether (ETBE) reactive distillation columns are studied. Two process The use of reactive distillation has grown in recent years because it results in less expensive and more

  6. Rejection and fate of trace organic compounds (TrOCs) during membrane distillation

    E-Print Network [OSTI]

    Rejection and fate of trace organic compounds (TrOCs) during membrane distillation Kaushalya COCs) Direct contact membrane distillation (DCMD) Volatility Fate and transport Hydrophobicity/hydrophilicity a b s t r a c t In this study, we examined the feasibility of membrane distillation (MD) for removing

  7. The dos and don'ts of distillation column control Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    The dos and don'ts of distillation column control Sigurd Skogestad* Department of Chemical discusses distillation column control within the general framework of plantwide control. In addition for distillation columns. The standard LV-configuration combined with a fast temperature loop is recommended

  8. Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column distillation columns have been explored in many papers, very few papers have dealt with closed-loop control. Most of these control papers consider reactive distillation columns in which there is only one product

  9. MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA S RENSEN 2

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA S RENSEN 2 and RAJAB LITTO column presented in this paper provides a generalization of previously proposed batch distillation schemes. The economic potential of the multivessel batch distillation under total re ux is demon- strated

  10. Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements-integrated multi-effect and three non-integrated distillation arrangements for separating a ternary mixture have been considered. The focus of the paper is on a heat-integrated complex distillation configuration

  11. Experimental and Theoretical Studies on the Start-Up Operation of a Multivessel Batch Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Experimental and Theoretical Studies on the Start-Up Operation of a Multivessel Batch DistillationVersity of Science and Technology, Trondheim, Norway Multivessel batch distillation is a promising alternative to conventional batch distillation. Earlier studies proved the feasibility of temperature control in a closed

  12. On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal

    E-Print Network [OSTI]

    Skogestad, Sigurd

    On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal Binary Columns distillation processes. By considering the e ect of small changes in the operating parameters, e.g., initial-mail: jacobsen@elixir.e.kth.se 1 #12;1 Introduction Batch distillation has become of increasing importance

  13. Optimization of a Diabatic Distillation Column with Sequential Heat Edward Steven Jimenez and Peter Salamon*

    E-Print Network [OSTI]

    Salamon, Peter

    Optimization of a Diabatic Distillation Column with Sequential Heat Exchangers Edward Steven of Copenhagen, Copenhagen, Denmark Diabatic distillation is a separation process in which heat is transferred is enormous because distillation is the single largest energy degrading unit operation worldwide. Introduction

  14. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial heat integrated distillation column Truls Larsson Sigurd Skogestad ÝDepartment of Chemical. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process QH column

  15. THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES --WITH APPLICATION TO DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES --WITH APPLICATION TO DISTILLATION COLUMNS John Morud that a subsystem is influenced only by its nabor subsystems. An example of such a process is a distillation column in high purity distillation columns; in fact, the magnitude of these time constants may increase

  16. Topic Distillation with Query-Dependent Link Connections and Page Characteristics

    E-Print Network [OSTI]

    Wu, Mingfang

    6 Topic Distillation with Query-Dependent Link Connections and Page Characteristics MINGFANG WU about a topic. Finding such results is called topic distillation. Previous research has shown statistics. This article presents a new approach to improve topic distillation by exploring the use

  17. Use of Two Distillation Columns in Systems with Maximum Temperature Limitations

    E-Print Network [OSTI]

    Gilchrist, James F.

    Use of Two Distillation Columns in Systems with Maximum Temperature Limitations Rebecca H. Masel, Pennsylvania 18015, United States ABSTRACT: Maximum temperature limitations are encountered in distillation of the bottoms product fixes the column base pressure and, hence, the condenser pressure. The distillate

  18. On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal

    E-Print Network [OSTI]

    Skogestad, Sigurd

    On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal Binary Columns sensitivity in batch distillation processes. By considering the effect of small changes in the operating #12; 1 Introduction Batch distillation has become of increasing importance in industry during the last

  19. Know-Center at TREC 2009 Blog Distillation Task: A Notebook Paper

    E-Print Network [OSTI]

    Hammerton, James

    Know-Center at TREC 2009 Blog Distillation Task: A Notebook Paper Elisabeth Lex, Michael Granitzer,mgrani,ajuffinger}@know-center.at Abstract. This paper outlines our experiments carried out at TREC 2009 Blog Distillation Task. Our system, specifically the blog distillation task, exactly this problem is addressed. The goal of the track is to rank

  20. MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad1

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad1 The experimental veri cation of the operation of a multivessel batch distillation column, operated under total re vessels, provides a generalization of previously proposed batch distillation schemes. We propose a simple

  1. Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column Edward Abstract Diabatic distillation is a separation process in which heat is transferred on the trays inside savings is through diabatic distillation. Instead of just one heat source (the reboiler) and one heat sink

  2. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum-boiling azeotropic mixtures, where the extractive agent and a control structure for the batch extractive middle vessel distillation is proposed. In extractive

  3. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimization of Distillation Processes. José A. Caballero* and Ignacio E. Grossmann** *Dept and a single condenser in the entire sequence. We also review the rigorous design of distillation columns, or column sequences. In all the cases we focus on mathematical programming approaches. Keywords Distillation

  4. Enhanced Topic Distillation using Text, Markup Tags, and Hyperlinks Soumen Chakrabarti

    E-Print Network [OSTI]

    Chakrabarti, Soumen

    Enhanced Topic Distillation using Text, Markup Tags, and Hyperlinks Soumen Chakrabarti Mukul Joshi Vivek Tawde IIT Bombay ABSTRACT Topic distillation is the analysis of hyperlink graph structure to authorities). Topic distillation is becoming common in Web search engines, but the best-known algorithms model

  5. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process system for TAME reactive distillation process using extraction column with water as a solvent. The design distillation column which was optimized to recover methanol and recycle water to the extraction column. Other

  6. DISTILLATION DES LIQUIDES SOUS L'INFLUENCE DE L'LECTRICIT STATIQUE; PAR M. D. GERNEZ.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    36I DISTILLATION DES LIQUIDES SOUS L'INFLUENCE DE L'ÉLECTRICITÉ STATIQUE; PAR M. D. GERNEZ. La décharge, la distillation se produit aussitôt en sens in- verse (2). Ce phénomène est extrêmemen t n e sens suivant lequel se produit cette distillation est contraire à celui que sem- bleraient indiquer les

  7. Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami-Beckner inequality

    E-Print Network [OSTI]

    O'Donnell, Ryan

    Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami In this paper we study non-interactive correlation distillation (NICD), a generalization of noise sen- sitivity distillation (NICD), previously considered in [5, 31, 39]. In its most general form the problem involves k

  8. Retrieval and Feedback Models for Blog Distillation Jonathan Elsas, Jaime Arguello, Jamie Callan, Jaime Carbonell

    E-Print Network [OSTI]

    Carbonell, Jaime

    Retrieval and Feedback Models for Blog Distillation Jonathan Elsas, Jaime Arguello, Jamie Callan and results for the Feed Distillation task in the Blog track at TREC 2007. Our experiments focus on two Wikipedia. 1 Introduction Blog distillation (or "feed search") is the task of finding blog feeds

  9. Assured Information Distillation in Social Sensing University of Illinois at Urbana-Champaign

    E-Print Network [OSTI]

    Garibaldi, Skip

    Colloquium Assured Information Distillation in Social Sensing Dong Wang University of Illinois. This opens up unprecedented challenges and opportunities in social sensing, where the goal is to distill, social and physical networks. The talk will also introduce a new information distillation system we built

  10. MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA SRENSEN 2

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA SØRENSEN 2 and RAJAB LITTO column presented in this paper provides a generalization of previously proposed batch distillation schemes. The economic potential of the multivessel batch distillation under total reflux is demon­ strated

  11. Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse

    E-Print Network [OSTI]

    Regev, Oded

    Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami In this paper we study non-interactive correlation distillation (NICD), a generalization of noise sensitivity in this paper is the problem of non-interactive correlation distil- lation (NICD), previously considered in [5

  12. Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating Vidar Trondheim, Norway Keywords: Distillation, Petlyuk, Divided-wall, Minimum energy Abstract This paper shows the unexpected result that over-fractionating one of the product streams in a Petlyuk distillation column may

  13. Sustainable operation of membrane distillation for enhancement of mineral recovery from hypersaline solutions

    E-Print Network [OSTI]

    Sustainable operation of membrane distillation for enhancement of mineral recovery from hypersaline December 2013 Available online 25 December 2013 Keywords: Membrane distillation Desalination Hypersaline brine Scaling Membrane cleaning Evaporation pond a b s t r a c t Membrane distillation (MD

  14. Noisy Processing and the Distillation of Private States Joseph M. Renes1

    E-Print Network [OSTI]

    Noisy Processing and the Distillation of Private States Joseph M. Renes1 and Graeme Smith2 1 general private state is distilled. Besides a more general target state, the usual entanglement distillation tools are employed (in par- ticular, Calderbank-Shor-Steane (CSS)-like codes), with the crucial

  15. THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES WITH APPLICATION TO DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES WITH APPLICATION TO DISTILLATION COLUMNS John Morud that a subsystem is in uenced only by its nabor subsystems. An example of such a process is a distillation column in high purity distillation columns; in fact, the magnitude of these time constants may increase

  16. A globally convergent method for finding all steady-state solutions of distillation columns

    E-Print Network [OSTI]

    Neumaier, Arnold

    A globally convergent method for finding all steady-state solutions of distillation columns Ali distillation column with 7 steady-states show the robustness of the method. No published software known to the steady-state model of distillation columns as it returns the original system as a single large block

  17. Distillation Codes and Applications to DoS Resistant Multicast Authentication

    E-Print Network [OSTI]

    Perrig, Adrian

    Distillation Codes and Applications to DoS Resistant Multicast Authentication Chris Karlof UC We introduce distillation codes, a method for streaming and storing data. Like erasure codes, distillation codes allow information to be decoded from a sufficiently large quorum of symbols. In contrast

  18. Synthesizing Representative I/O Workloads Using Iterative Distillation Zachary Kurmas

    E-Print Network [OSTI]

    Kurmas, Zachary

    Synthesizing Representative I/O Workloads Using Iterative Distillation Zachary Kurmas College proper- ties are "key" for a given workload and storage system. We have developed a tool, the Distiller, that automati- cally identifies the key properties ("attribute-values") of the workload. The Distiller then uses

  19. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum­boiling azeotropic mixtures, where the extractive agent and a control structure for the batch extractive middle vessel distillation is proposed. In extractive

  20. Integrating the Document Object Model with Hyperlinks for Enhanced Topic Distillation and Information Extraction

    E-Print Network [OSTI]

    Chakrabarti, Soumen

    Integrating the Document Object Model with Hyperlinks for Enhanced Topic Distillation://www.cse.iitb.ernet.in/~soumen ABSTRACT Topic distillation is the process of finding authoritative Web pages and comprehensive "hubs distillation has been traditionally applied to a macroscopic Web model where documents are nodes in a directed

  1. SEPARATION OF TERNARY HETEROAZEOTROPIC MIXTURES IN A CLOSED MULTIVESSEL BATCH DISTILLATION-DECANTER HYBRID

    E-Print Network [OSTI]

    Skogestad, Sigurd

    SEPARATION OF TERNARY HETEROAZEOTROPIC MIXTURES IN A CLOSED MULTIVESSEL BATCH DISTILLATION, Trondheim, Norway The feasibility of a novel multivessel batch distillation-decanter hybrid for simultaneous enables us to make direct use of the distillation line (or residue curve) map. Simple rules for predicting

  2. Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio Sebastiani

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio in revised form 10 May 2013 Accepted 30 May 2013 Available online 14 June 2013 Keywords: Blog distillation to blog distillation, defined as the task in which, given a user query, the system ranks the blogs

  3. Complex Distillation Arrangements 23.May 2001 by I.Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Complex Distillation Arrangements 23.May 2001 by I.Halvorsen NTNU Department of Chemical Engineering 1 Minimum Energy Requirements in Complex Distillation Arrangements A thesis submitted for the degree of dr. ing. 23. May 2001 by Ivar J. Halvorsen #12;Complex Distillation Arrangements 23.May 2001

  4. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial heat integrated distillation column Truls Larsson Sigurd Skogestad y Department of Chemical. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process Q H column

  5. Manifold-based starting point generation and its application to distillation

    E-Print Network [OSTI]

    Neumaier, Arnold

    Manifold-based starting point generation and its application to distillation Ali Baharev*, Ferenc-states in homogeneous azeotropic distillation . . . . . . . . . . 11 5.2 Multiple steady-states in ideal two-product distillation . . . . . . . . . . . . . . 11 6 Conclusion 13 A Ordering sparse matrices 14 A.1 Ordering to block

  6. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    structure design. Keywords: Kaibel column, thermally coupled distillation columns, optimal operation 1J.Halvorsen@sintef.no Abstract The objective of this paper is to study the Kaibel distillation column from operability point. Introduction The thermally-coupled Petlyuk 1 distillation column separates the feed into three products

  7. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    is a viable option in present case. Keywords: Distillation, Energy saving, Dividing wall column, Thermal challenge is to design distillation systems that at the same time are sustainable and economically feasibleDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved

  8. Optimal Synthesis of Thermally Coupled Distillation Sequences Using a Novel MILP Approach.

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    . Pittsburgh, PA. USA. Abstract This paper introduces a novel MILP approach for the design of distillation Column; Superstructure optimization; GDP. Introduction Distillation is the most widely used method distillation (TCD), in which heat is directly transferred between columns through two streams (liquid a vapor

  9. Active Constraint Regions for Optimal Operation of Distillation Magnus G. Jacobsen and Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , NTNU, N-7491, Trondheim, Norway ABSTRACT: When designing the control structure of distillation columnsActive Constraint Regions for Optimal Operation of Distillation Columns Magnus G. Jacobsen presented in an earlier paper, to find how the active constraints for distillation columns change

  10. Model predictive control of a pilot-scale distillation column using a programmable automation controller

    E-Print Network [OSTI]

    Model predictive control of a pilot-scale distillation column using a programmable automation). The controller is tested on a pilot-scale binary distillation column to track reference temperatures. A majorRIO) to control a pilot-scale binary distillation col- umn. Both the PI-controllers and the supervising online MPC

  11. Choosing a coke-oven gas desulfurization system: a review of current technology

    SciTech Connect (OSTI)

    Lynch, P.A.

    1982-12-01T23:59:59.000Z

    Installation of coke-oven gas desulphurizing systems is primarily the result of air pollution control regulations. Although not currently profitable, operating costs can be minimized by choosing the technology most suited to the particular application. The Stretford Holmes, Takahax/Hirohax, Koppers Vacuum Carbonate, Sulfiban and Dravo/Still processes are discussed, together with criteria for economic analysis based on technical and by-product market evaluations.

  12. Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method

    SciTech Connect (OSTI)

    Ritter, H.

    1985-05-21T23:59:59.000Z

    An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

  13. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect (OSTI)

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

    1996-02-01T23:59:59.000Z

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  14. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    engaged in the production of crude oil and to ensure thatgas plant production by integrated firms that have crude oilcrude oil and nonproduct costs are allocated to different types of regulated products in the following way: Production

  15. Crude oil and shale oil

    SciTech Connect (OSTI)

    Mehrotra, A.K. [Univ. of Calgary (Canada)

    1995-06-15T23:59:59.000Z

    This year`s review on crude oil and shale oil has been prepared by classifying the references into the following main headings: Hydrocarbon Identification and Characterization, Trace Element Determination, Physical and Thermodynamic Properties, Viscosity, and Miscellaneous Topics. In the two-year review period, the references on shale oils were considerably less in number than those dealing with crude oils. Several new analytical methodologies and applications were reported for hydrocarbon characterization and trace element determination of crude oils and shale oils. Also included in this review are nine U.S., Canadian British and European patents. 12 refs.

  16. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  17. Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks

    SciTech Connect (OSTI)

    S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

  18. Definition of heavy oil and natural bitumen

    SciTech Connect (OSTI)

    Meyer, R.F.

    1988-08-01T23:59:59.000Z

    Definition and categorization of heavy oils and natural bitumens are generally based on physical or chemical attributes or on methods of extraction. Ultimately, the hydrocarbon's chemical composition will govern both its physical state and the extraction technique applicable. These oils and bitumens closely resemble the residuum from wholecrude distillation to about 1,000/degree/F; if the residuum constitutes at least 15% of the crude, it is considered to be heavy. In this material is concentrated most of the trace elements, such as sulfur, oxygen, and nitrogen, and metals, such as nickel and vanadium. A widely used definition separates heavy oil from natural bitumen by viscosity, crude oil being less, and bitumen more viscous than 10,000 cp. Heavy crude then falls in the range 10/degree/-20/degree/ API inclusive and extra-heavy oil less than 10/degree/ API. Most natural bitumen is natural asphalt (tar sands, oil sands) and has been defined as rock containing hydrocarbons more viscous than 10,000 cp or else hydrocarbons that may be extracted from mined or quarried rock. Other natural bitumens are solids, such as gilsonite, grahamite, and ozokerite, which are distinguished by streak, fusibility, and solubility. The upper limit for heavy oil may also be set at 18/degree/ API, the approximate limit for recovery by waterflood.

  19. Distillation and purification of symmetric entangled Gaussian states

    E-Print Network [OSTI]

    Jaromir Fiurasek

    2010-11-03T23:59:59.000Z

    We propose an entanglement distillation and purification scheme for symmetric two-mode entangled Gaussian states that allows to asymptotically extract a pure entangled Gaussian state from any input entangled symmetric Gaussian state. The proposed scheme is a modified and extended version of the entanglement distillation protocol originally developed by [Browne et al., Phys. Rev. A 67, 062320 (2003)]. A key feature of the present protocol is that it utilizes a two-copy de-Gaussification procedure that involves a Mach-Zehnder interferometer with single-mode non-Gaussian filters inserted in its two arms. The required non-Gaussian filtering operations can be implemented by coherently combining two sequences of single-photon addition and subtraction operations.

  20. Distillation of entanglement by projection on permutationally invariant subspaces

    E-Print Network [OSTI]

    Czechlewski, Miko?aj; Horodecki, Micha?; Mozrzymas, Marek; Studzi?ski, Micha?

    2011-01-01T23:59:59.000Z

    We consider distillation of entanglement from two qubit states which are mixtures of three mutually orthogonal states: two pure entangled states and one pure product state. We distill entanglement from such states by projecting n copies of the state on permutationally invariant subspace and then applying one-way hashing protocol. We find analytical expressions for the rate of the protocol. We also generalize this method to higher dimensional systems. To get analytical expression for two qubit case, we faced a mathematical problem of diagonalizing a family of matrices enjoying some symmetries w.r.t. to symmetric group. We have solved this problem in two ways: (i) directly, by use of Schur-Weyl decomposition and Young symmetrizers (ii) showing that the problem is equivalent to a problem of diagonalizing adjacency matrices in a particular instance of a so called algebraic association scheme.

  1. Reducing the quantum computing overhead with complex gate distillation

    E-Print Network [OSTI]

    Guillaume Duclos-Cianci; David Poulin

    2014-03-20T23:59:59.000Z

    In leading fault-tolerant quantum computing schemes, accurate transformation are obtained by a two-stage process. In a first stage, a discrete, universal set of fault-tolerant operations is obtained by error-correcting noisy transformations and distilling resource states. In a second stage, arbitrary transformations are synthesized to desired accuracy by combining elements of this set into a circuit. Here, we present a scheme which merges these two stages into a single one, directly distilling complex transformations. We find that our scheme can reduce the total overhead to realize certain gates by up to a few orders of magnitude. In contrast to other schemes, this efficient gate synthesis does not require computationally intensive compilation algorithms, and a straightforward generalization of our scheme circumvents compilation and synthesis altogether.

  2. Distillation of hydrogen isotopes for polarized HD target

    E-Print Network [OSTI]

    T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouill'; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

    2011-12-12T23:59:59.000Z

    We have developed a cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for a polarized HD target in LEPS experiments at SPring-8. A small amount of ortho-H$_2$ ($\\sim$0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1$\\sim$5% impurities of H$_2$ and D$_2$ in commercially available HD gases, it is inevitable that the HD gas is purified up to $\\sim$99.99%. The distillation system has a cryogenic pot (17$\\sim$21 K) containing many small stainless steel cells called Heli-pack. Commercial HD gas with an amount of 5.2 mol is fed into the pot. We carried out three distillation runs by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed by using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. The HD gas of 1 mol with a purity better than 99.99% has been successfully obtained. The effective NTS (Number of Theoretical Stages), which is an indicator of the distillator performances, is obtained as 37.2$\\pm$0.6. This value is in reasonable agreement with a designed value of 37.9. The HD target is expected to be efficiently polarized under a well-controlled condition by doping an optimal amount of ortho-H$_2$ to the purified HD gas.

  3. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  4. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23T23:59:59.000Z

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  5. Distillation of hydrogen isotopes for polarized HD target

    E-Print Network [OSTI]

    Ohta, T; Didelez, J -P; Fujiwara, M; Fukuda, K; Kohri, H; Kunimatsu, T; Morisaki, C; Ono, S; Rouill', G; Tanaka, M; Ueda, K; Uraki, M; Utsuro, M; Wang, S Y; Yosoi, M

    2011-01-01T23:59:59.000Z

    We have developed a cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for a polarized HD target in LEPS experiments at SPring-8. A small amount of ortho-H$_2$ ($\\sim$0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1$\\sim$5% impurities of H$_2$ and D$_2$ in commercially available HD gases, it is inevitable that the HD gas is purified up to $\\sim$99.99%. The distillation system has a cryogenic pot (17$\\sim$21 K) containing many small stainless steel cells called Heli-pack. Commercial HD gas with an amount of 5.2 mol is fed into the pot. We carried out three distillation runs by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed by using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. The HD gas of 1 mol with a purity better than 99.99% has been successfully obtained. The effective NTS (Number of Theoretical Stages), which is...

  6. Temperature effects on oil-water relative permeabilities for unconsolidated sands

    SciTech Connect (OSTI)

    Sufi, A.H.

    1983-03-01T23:59:59.000Z

    This study presents an experimental investigation of temperature effects on relative permeabilities of oil- water systems in unconsolidated sands. The fluids used in this study were refined mineral oil and distilled water. A rate sensitivity study was done on residual oil saturation and oil and water relative permeabilities. The temperature sensitivity study of relative permeabilities was conducted in 2 parts. The first was to investigate changes in residual oil saturation with temperature where the cores were 100% saturated with oil at the start of the waterflood. The second part continued the floods for a longer time until the water-cut was virtually 100%. Under these conditions, little change in residual oil saturation was observed with temperature. A study on viscous instabilities also was performed. This verified the existence of viscous fingers during waterflooding. It also was observed that tubing volume after the core could cause fingering, resulting in lower apparent breakthrough oil recoveries.

  7. Experience and results of new heating control system of coke oven batteries at Rautaruukki Oy Raahe Steel

    SciTech Connect (OSTI)

    Swanljung, J.; Palmu, P. [Rautaruukki Oy Raahe Steel (Finland)

    1997-12-31T23:59:59.000Z

    The latest development and results of the heating control system at Raahe Steel are presented in this paper. From the beginning of coke production in Rautaruukki Oy Raahe Steel (October 1987) the heating control systems have been developed. During the first stage of development work at the coking plant (from year 1987 to 1992), when only the first coke oven battery consisting of 35 ovens was in production, the main progress was in the field of process monitoring. After commissioning of the second stage of the coking plant (November 1992), the development of the new heating control model was started. Target of the project was to develop a dynamic control system which guides the heating of batteries through the various process conditions. Development work took three years and the heating control system was commissioned in the year 1995. Principle of the second generation system is an energy balance calculation, coke end temperature determination and dynamic oven scheduling system. The control is based on simultaneous feedforward and feedback control. The fuzzy logic components were added after about one year experience.

  8. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

    2009-09-15T23:59:59.000Z

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  9. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    IV. v. Retail Marketers . . Wholesale Marketers Explanationof Supportive Data Wholesale and Retail Fuel Oil MarketPRICES II-1 II-3 II-3 Wholesale Prices to Wholesalers and

  10. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    flow directly from the refinery to wholesaler, to retailer,of No. 2 heating oil for the refinery, wholesale and retailfirst system monitored refinery, wholesale and retail price

  11. Reduction of NO[sub x] emissions coke oven gas combustion process

    SciTech Connect (OSTI)

    Terza, R.R. (USS Clairton Works, PA (United States)); Sardesai, U.V. (Westfield Engineering and Services, Inc., Houston, TX (United States))

    1993-01-01T23:59:59.000Z

    The paper describes by-product processing at Clairton Works which uses a unique cryogenic technology. Modifications to the desulfurization facility, nitrogen oxide formation in combustion processes (both thermal and fuel NO[sub x]), and the boilers plants are described. Boilers were used to study the contribution of fuel NO[sub x] formation during the combustion of coke oven gas. Results are summarized. The modifications made to the desulfurization facility resulted in the overall H[sub 2]S emission being reduced by 2-4 grains/100scf and the NO[sub x] emission being reduced by 21-42% in the boiler stacks.

  12. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J. [Magnitogorsk Integrated Iron and Steel Works, (Russian Federation); Gross, M. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  13. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  14. Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.

    SciTech Connect (OSTI)

    Arora, S.; Wu, M.; Wang, M.; Energy Systems

    2011-02-01T23:59:59.000Z

    Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

  15. Biochemical processing of heavy oils and residuum

    SciTech Connect (OSTI)

    Lin, M.S.; Premuzic, T.; Yablon, J.H.; Zhou, Wei-Min

    1995-05-01T23:59:59.000Z

    During the past several decades, the petroleum industry has adjusted gradually to accommodate the changes in market product demands, government regulations, and the quality and cost of feedstock crude oils. For example, the trends show that the demand for distillate fuels, such as diesel, as compared to gasoline are increasing. Air-quality standards have put additional demand on the processing of heavier and higher sulfur feed stocks. Thus, the 1990 Clean Air Act amendments require the industry to produce greater quantities of oxygenated gasoline, and lower sulfur diesel and reformulated gasoline. Biochemical technology may play an important role in responding to these demands on the petroleum industry.

  16. Bound States for Magic State Distillation in Fault-Tolerant Quantum Computation

    E-Print Network [OSTI]

    Earl T. Campbell; Dan E. Browne

    2010-02-01T23:59:59.000Z

    Magic state distillation is an important primitive in fault-tolerant quantum computation. The magic states are pure non-stabilizer states which can be distilled from certain mixed non-stabilizer states via Clifford group operations alone. Because of the Gottesman-Knill theorem, mixtures of Pauli eigenstates are not expected to be magic state distillable, but it has been an open question whether all mixed states outside this set may be distilled. In this Letter we show that, when resources are finitely limited, non-distillable states exist outside the stabilizer octahedron. In analogy with the bound entangled states, which arise in entanglement theory, we call such states bound states for magic state distillation.

  17. Multiple steady states during reactive distillation of methyl tert-butyl ether

    SciTech Connect (OSTI)

    Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

    1993-11-01T23:59:59.000Z

    This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

  18. An Itegrated Approach to Water Treatment in Oil and Gas Industry via Thermal Membrane Distillation 

    E-Print Network [OSTI]

    Elsayed, Nesreen Ahmed Abdelmoez Mohamed

    2014-10-14T23:59:59.000Z

    an increasing level of interest in the area of high-purity separation especially in water treatment. It is driven primarily by heat which creates a vapor-pressure difference across a porous hydrophobic membrane. Hot produced water and excess low-level heat from...

  19. Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    processes can be found in commercial simulators such as Aspen-Plus and Hysys (Aspen Techology), Petro

  20. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousand CubicCubic Feet) Yeara Oxygenated17,583.7 5,086.5

  1. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousand CubicCubic Feet) Yeara Oxygenated17,583.7

  2. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet) DecadeV49 1553,177.25.6 366.2

  3. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet) DecadeV49 1553,177.25.6 366.23,186.1

  4. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet) DecadeV49 1553,177.25.6

  5. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet) DecadeV49 1553,177.25.6872.2 68,866.5

  6. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet) DecadeV49 1553,177.25.6872.2

  7. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle Fuel Consumption.9.

  8. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle Fuel Consumption.9.048.9

  9. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle Fuel

  10. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle FuelFoot,Effective PADA3.

  11. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle FuelFoot,Effective PADA3.

  12. U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Zandofpoint motional%^ U N C L A SDistillate

  13. U.S. Adjusted Sales of Distillate Fuel Oil by End Use

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Zandofpoint motional%^ U N C L A

  14. U.S. Distillate Fuel Oil and Kerosene Sales by End Use

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Zandofpoint motional%^602SWPA

  15. An Itegrated Approach to Water Treatment in Oil and Gas Industry via Thermal Membrane Distillation

    E-Print Network [OSTI]

    Elsayed, Nesreen Ahmed Abdelmoez Mohamed

    2014-10-14T23:59:59.000Z

    and discharge to conserve water resources and reduce the negative environmental impact associated with discharging wastewater into the environment. Wastewater treatment enables providing water with specifications suitable for either recycle in the same... process or reuse in other ways within the process or outside the process. Therefore, water treatment and recycle/reuse contribute to addressing both of the aforementioned water problems: fresh water sacristy and environmental impact of wastewater...

  16. ,"U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources andPlant Liquids,+ LeasePrice SoldPlantGross

  17. U.S. Sales of Distillate Fuel Oil by End Use

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at Commercial and InstitutionalArea: U.S. East Coast502Propane,Area:

  18. Distillate Fuel Oil Refinery, Bulk Terminal, and Natural Gas Plant Stocks

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline353/06) 2Yonthly Energy : b ra&le.com

  19. Table 10.24 Reasons that Made Distillate Fuel Oil Unswitchable, 2006;

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are nowTotal" (Percent) Type: Sulfur Content API Gravity Period: Monthly AnnualConnecticut"Montana"Oregon"UnitedWyoming" "megawatthours"4 Reasons

  20. Stocks of Distillate Fuel Oil Greater Than 15 ppm to 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Energy I I' a(STEO) Highlights ï‚·2008DeutscheState470,6036,190 5,932