National Library of Energy BETA

Sample records for distillate oil residual

  1. "Table A10. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page|Monthly","10/2015","1/15/1981"0. Total Consumption of LPG, Distillate Fuel Oil, and Residual

  2. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  3. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  4. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon...

  5. "Table A2. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page|Monthly","10/2015","1/15/1981"0. Total Consumption of LPG, Distillate Fuel Oil, and6.. Total

  6. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  7. Stocks of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil Prices Brent crudeEnvironment144,415

  8. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  9. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  10. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  11. Catalyst deactivation model for residual oil hydrodesulfurization

    SciTech Connect (OSTI)

    Takatsuka, T.; Higasino, S.; Hirohama, S. [Chiyoda Corporation, Yokohama (Japan)] [and others

    1995-12-31

    Hydrodesulfurization process plays a dominant role in the modern refineries to upgrade residual oil either by removing heterogeneous atoms or by hydrocracking the bottom to distillates products. The practical model is proposed to predict a catalyst life which is the most concern in the process. The catalyst is deactivated in the early stage of the operation by coke deposition on the catalyst active site. The ultimate catalyst life is determined by pore mouth plugging depending on its metal capacity. The phenomena are mathematically described by losses of catalyst surface area and effective diffusivity of feedstock molecules in catalyst pore. The model parameters were collected through the pilot plant tests with different types of catalysts and feedstocks.

  12. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  13. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  14. Arabian crude-oil residues evaluated

    SciTech Connect (OSTI)

    Ali, M.F.; Bukhari, A.; Hasan, M.; Saleem, M.

    1985-08-12

    This article evaluates detailed physical and chemical characteristics for four important Saudi Arabian resids. Petroleum residues are composed of a mixture of large and complex hydrocarbon molecules along with one or more heteroatoms such as sulfur, oxygen, nitrogen, vanadium, and nickel. The amount of residue and its physical and chemical composition depend on the source of the crude oil and methods of processing. Residues from four Saudi Arabian crude oils produced by the Arabian American Oil Co. (Aramco) were evaluated. The crude oils are 38.5 degrees API Arabian Extra Light, 33.8 degrees API Arabian Light, 30.4 degrees Api Arabian Medium, and 28.03 degrees API Arabian Heavy. Results are presented and residue preparation, and physical and chemical characteristics are analyzed.

  15. Production of gasoline and distillate fuels from light cycle oil

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Owens, P.J.; Sarli, M.S.

    1991-01-15

    This patent describes a process for the co-production of high quality gasoline and distillate products from catalytically cracked feedstocks. It comprises: hydrocracking a substantially dealkylated feedstock with a hydrocracking catalyst at a hydrogen partial pressure not greater than 1200 psig and a conversion to gasoline boiling range products not more than 75 wt. percent; separating the products of hydrocracking into a gasoline boiling range fraction, a first distillate range fraction boiling immediately above the gasoline fraction with an end point in the range of 450{degrees} to 500{degrees} F. and a second distillate fraction boiling above the first distillate fraction; recycling at least a portion of the first distillate fraction to the hydrocracking step to effect saturation and partial cracking of aromatics in the recycled fraction to increase the paraffin content of the second distillate fraction; recovering the second distillate fraction.

  16. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

  17. Production of gasoline and distillate fuels from light cycle oil

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Owens, P.J.; Sarli, M.S.

    1991-02-05

    This patent describes a process for the co-production of high quality gasoline and distillate products from catalytically cracked feedstocks. It comprises catalytically cracking a hydrocarbon feedstock to produce a substantially dealkylated cracked product, hydrocracking the substantially dealkylated product with a hydrocracking catalyst at a hydrogen partial pressure not greater than 1200 psig and a conversion to gasoline boiling range products not more than 75 wt. percent; separating the products of hydrocracking into a gasoline boiling range fraction, a first distillate range fraction boiling immediately above the gasoline fraction with an end point in the range of 450{degrees} to 500{degrees} F and a second, higher boiling distillate fraction which is more paraffinic than the first distillate fraction; recycling at least a portion of the first, lower boiling distillate fraction to the catalytic cracking step, recovering the second, higher boiling distillate fraction.

  18. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect (OSTI)

    Eaton, Scott J; Bunting, Bruce G; Lewis Sr, Samuel Arthur; Fairbridge, Craig

    2009-01-01

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  19. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation 

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  20. Stocks of Distillate Fuel Oil 15 ppm Sulfur and Under

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG Oil10:Price27,84320,354

  1. The toxicity of two crude oils and kerosine to cattle 

    E-Print Network [OSTI]

    Rowe, Loyd Douglas

    1972-01-01

    in this study: c (1) a west Texas raw sour crude oil relatively low in gasoline, naphtha, and kerosine and relatively high in gas oil, lubricating distillates, residue, and sulfur; (2) a west Texas raw sweet d crude oil relatively high in gasoline, naphtha... and Kerosine Administered to Cattle* Characteristic Sweet crude Sour crude Kerosine Light gasoline (/) 14. 2 9. 6 Total gasoline plus naphtha (%) 43. 0 31. 6 Kerosine (/) Gas oil Lubricating distillates (%) Residue (%) Distillation loss (%%d) Sulfur...

  2. Viscosity stabilization of SRC residual oil. Final technical report

    SciTech Connect (OSTI)

    Tewari, K.C.

    1984-05-01

    The use of SRC residual oils for No. 6 Fuel Oil substitutes has been proposed. The oils exhibit viscosity characteristics at elevated temperatures that allow this substitution with only minor modifications to the existing fuel oil infrastructure. However, loss of low-boiling materials causes an increase in the viscosity of the residual oils that is greater than expected from concentration changes. A process has been developed that minimizes the loss of volatiles and thus maintains the viscosity of these materials. The use of an additive (water, phenol, or an SRC light oil cut rich in low-boiling phenols in amounts up to 2.0 wt %) accomplishes this and hence stabilizes the pumping and atomizing characteristics for an extended period. During the course of the work, the components of the volatiles lost were identified and the viscosity change due to this loss was quantified. 3 references, 6 figures, 9 tables.

  3. ,"U.S. Total Sales of Residual Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    to Oil Company Consumers (Thousand Gallons)","U.S. Residual Fuel Oil SalesDeliveries to Electric Utility Consumers (Thousand Gallons)","U.S. Residual Fuel Oil SalesDeliveries to...

  4. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  5. A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which

    E-Print Network [OSTI]

    Galvin, David

    A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which takes in crude oil, up to a maximum of 650,000 barrels per day (bbl/day) and produces **" means "**% octane".) Once crude oil enters the system, it goes fully through the process. The refinery

  6. Table 42. Residual Fuel Oil Prices by PAD District and State

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1999 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  7. Table 42. Residual Fuel Oil Prices by PAD District and State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Information AdministrationPetroleum Marketing Annual 1998 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  8. Effects of petroleum distillate on viscosity, density and surface tension of intermediate and heavy crude oils 

    E-Print Network [OSTI]

    Abdullayev, Azer

    2009-06-02

    Experimental and analytical studies have been carried out to better understand the effects of additives on viscosity, density and surface tension of intermediate and heavy crude oils. The studies have been conducted for the following oil samples...

  9. ,"U.S. Adjusted Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

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  10. An Itegrated Approach to Water Treatment in Oil and Gas Industry via Thermal Membrane Distillation 

    E-Print Network [OSTI]

    Elsayed, Nesreen Ahmed Abdelmoez Mohamed

    2014-10-14

    This work is aimed at developing a systematic approach for designing treatment systems for wastewater streams resulting from upstream production and downstream processing of oil and gas systems. The approach will provide an optimum and integrated...

  11. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.22 ConsumptionNonfuel"

  12. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.22 ConsumptionNonfuel" PAD

  13. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  14. Sand pack residual oil saturations as affected by extraction with various solvents 

    E-Print Network [OSTI]

    Murray, Clarence

    1958-01-01

    LIBRARY S 4 M COLLEGE OF TEXAS SAND PACK RESIDUAL OIL SATURATIONS AS AFFECTED BY EXTRACTION WITH VARIOUS SOLVENTS A Thesis CLARENCE MURRAY, JR. Submitted to the Graduate School of The Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE August, I958 Major Subject: Petroleum Engineering SAND PACK RESIDUAL OIL SAT URATIONS AS AFFECTED BY EXTRACTION WITH VARIOUS SOLVENTS A Thesis By CLARENCE MURRAY, JR. Approved...

  15. Stocks of Distillate Fuel Oil Greater Than 15 ppm to 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG Oil10:Price27,84320,3548,679

  16. U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil General Industries and TBD OMB

  17. U.S. Adjusted Sales of Distillate Fuel Oil by End Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil General Industries and TBD OMBArea:

  18. U.S. Distillate Fuel Oil and Kerosene Sales by End Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil Generaldiesel fuel priceArea: U.S.

  19. The investigation of the effects of wettability on residual oil after water flooding 

    E-Print Network [OSTI]

    Burja, Edward Oscar

    1953-01-01

    THE INVESTIGATION OF THE EFFECTS OF WETTABILITY ON RESIDUAL OIL AFTER WATER FLOODING A Thesis BY E. 0, BUR JA Approved as to style and content by: (Cha rman of C mmittee (Head of Department) (Mo th (Year) THE INVESTIGATION OF THE EFFECTS... OF WETTABILITY ON RESIDUAL OIL AFTER WATER FLOODING By E. O. Burja A Thesis Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Major Subject...

  20. Characterization of contaminants in oil shale residuals and the potential for their management to meet environmental quality standards. Final report

    SciTech Connect (OSTI)

    Schmidt-Collerus, J.J.

    1984-02-01

    Some general aspects of various oil shale processes developed for scale-up to commercial size modular units are described. The overall magnitude of an envisioned commercial shale oil operation and the magnitude of resulting potentially polluting residues in particular solid residues from retorting oil shale and associated operations and wastewater from retort streams and other sources are considered. The potential problems ensuing from self-oxidation of stockpiles of oil shale and from residual carbonaceous retorted oil shale disposed above ground and/or from in situ retorting operations are examined. Some methods for managing self-heating processes are suggested. The most plausible method of avoiding potential self-heating for retorted oil shale is to oxidize as much as possible of the organic carbon present by utilizing a process that will produce low carbon or carbon-free retorted oil shale residues. In the case of unretorted oil shale, the dimensions and shapes of the stockpiles should be designed such that heat build-up is eliminated or kept to a minimum.

  1. Synthetic crude oils carcinogenicity screening tests. Progress report, September 15, 1979-March 15, 1980

    SciTech Connect (OSTI)

    Calkins, W.H.; Deye, J.F.; King, C.F.; Hartgrove, R.W.; Krahn, D.F.

    1980-01-01

    Four crude oils (H Coal-Fuel Oil Mode, Occidental in situ Shale Oil, Exxon Donor Solvent Liquid, and SRC II) which were distilled into four fractions (naphtha, mid-distillate, gas oil and residue) for analysis and biological screening testing during the last report period were tested for mutagenicity by the Ames test and for tumor initiating activity by an initiation/promotion (skin painting) test. Substantial agreement exists between Ames and skin painting results. Low boiling naphtha fractions of the 4 crude oils showed little or no mutagenicity or tumor initiating activity by the two tests used. The higher boiling fractions (gas oils and residues) and the crude oils themselves were mutagenic and exhibited tumor initiation activity. The coal derived fractions were more active by both tests than the shale oil fractions.

  2. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    . Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wineCHEM­333: Lab Experiment 3: Distillation and Gas Chromatography: Prelab-Assignment: read Chapters 5 and 6. Distillation is one of the most powerful techniques for purifying volatile organic compounds

  3. Fuel oil and kerosene sales 1994

    SciTech Connect (OSTI)

    NONE

    1995-09-27

    This publication contains the 1994 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the sixth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA)for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1994 edition marks the 11th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Distillate and residual fuel oil sales continued to move in opposite directions during 1994. Distillate sales rose for the third year in a row, due to a growing economy. Residual fuel oil sales, on the other hand, declined for the sixth year in a row, due to competitive natural gas prices, and a warmer heating season than in 1993. Distillate fuel oil sales increased 4.4 percent while residual fuel oil sales declined 1.6 percent. Kerosene sales decreased 1.4 percent in 1994.

  4. PEMEX selects the H-Oil{reg_sign} process for their hydrodesulfurization residue complex at the Miguel Hidalgo Refinery

    SciTech Connect (OSTI)

    Wisdom, L.I.; Colyar, J.J. [Hydrocarbon Research, Inc., Princeton, NJ (United States)

    1995-12-31

    Petroleos Mexicanos (PEMEX) has selected the H-Oil Process for the conversion and upgrading of a blend of Maya and Isthmus vacuum residua at the Miguel Hidalgo Refinery. The 8,450 metric ton/day (50,000 bpsd) H-Oil Plant will produce a low sulfur (0.8 wt%) fuel oil, diesel, naphtha, and LPG. The H-Oil Plant will be a key component of the Hydrodesulfurization Residue (HDR) Complex which will be located at the Miguel Hidalgo Refinery in Tula, State of Hidalgo, Mexico. The project is part of PEMEX`s Ecology Projects currently underway in Mexico. This paper describes the HDR Complex and the design basis of the H-Oil Plant and provides the current status of this project.

  5. Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

    SciTech Connect (OSTI)

    Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

    2014-12-01

    Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

  6. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17

    the synthetic sample and experimental study previously carried out. (e) To correlate steam-propane distillation yields for some crude oils and synthetic hydrocarbons to generate steam-propane distillation data that could be used to develop the input data... there is need to develop a model to predict distillate yield under any set of conditions for any heavy oil, requiring only the simulated distillation (SIMDIS) trace (i.e. percent off vs. normal boiling temperature) of the oil. The expected deliverables from...

  7. Imports of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See full Hydrocarbon7,747 8,021 8,312218

  8. ,"U.S. Adjusted Sales of Residual Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative FuelsMonthly","10/2015"Monthly","10/2015" ,"ReleaseMonthly","10/2015"Net Receipts byDistillate

  9. Hydroprocessing Bio-oil and Products Separation for Coke Production

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.

    2013-04-01

    Fast pyrolysis of biomass can be used to produce a raw bio-oil product, which can be upgraded by catalytic hydroprocessing to hydrocarbon liquid products. In this study the upgraded products were distilled to recover light naphtha and oils and to produce a distillation resid with useful properties for coker processing and production of renewable, low-sulfur electrode carbon. For this hydroprocessing work, phase separation of the bio-oil was applied as a preparatory step to concentrate the heavier, more phenolic components thus generating a more amenable feedstock for resid production. Low residual oxygen content products were produced by continuous-flow, catalytic hydroprocessing of the phase separated bio-oil.

  10. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-02-10

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  11. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-09-08

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  12. Determination of Nickel Species in Stack Emissions from Eight Residual Oil-Fired Utility Steam-Generating Units

    SciTech Connect (OSTI)

    F Huggins; K Galbreath; K Eylands; L Van Loon; J Olson; E Zillioux; S Ward; P Lynch; P Chu

    2011-12-31

    XAFS spectroscopy has been used to determine the Ni species in particulate matter collected on quartz thimble filters in the stacks of eight residual (No. 6 fuel) oil-burning electric utility steam-generating units. Proper speciation of nickel in emitted particulate matter is necessary to correctly anticipate potential health risks. Analysis of the spectroscopic data using least-squares linear combination methods and a newly developed method specific for small quantities of Ni sulfide compounds in such emissions show that potentially carcinogenic Ni sulfide compounds are absent within the detection limits of the method ({le}3% of the total Ni) in the particulate matter samples investigated. In addition to the major nickel sulfate phase (NiSO{sub 4} {center_dot} 6H{sub 2}O), lesser amounts of (Ni,Mg)O and/or NiFe{sub 2}O{sub 4} were also identified in most emission samples. On the basis of the results from these emission characterization studies, the appropriateness of the U.S. Environmental Protection Agency's assumption that the Ni compound mixture emitted from residual oil-fired power plants is 50% as carcinogenic as nickel subsulfide (Ni{sub 3}S{sub 2}) should be re-evaluated.

  13. Evaluation of residual shale oils as feedstocks for valuable carbon materials

    SciTech Connect (OSTI)

    Fei, You Qing; Derbyshire, F. [Univ. of Kentucky, Lexington, KY (United States)

    1995-12-31

    Oil shale represents one of the largest fossil fuel resources in the US and in other pans of the world. Beginning in the 1970s until recently, there was considerable research and development activity directed primarily to technologies for the production of transportation fuels from oil shale. Due to the low cost of petroleum, as with other alternate fuel strategies, oil shale processing is not economically viable at present. However, future scenarios can be envisaged in which non-petroleum resources may be expected to contribute to the demand for hydrocarbon fuels and chemicals, with the expectation that process technologies can be rendered economically attractive. There is potential to improve the economics of oil shale utilization through broadening the spectrum of products that can be derived from this resource, and producing added-value materials that are either unavailable or more difficult to produce from other sources. This concept is by no means original. The history of oil shale development shows that most attempts to commercialize oil shale technology have relied upon the marketing of by-products. Results are presented on carbonization and the potential for generating a pitch that could serve as a precursur material.

  14. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    dislocation-of crude oil and products could jeopardize theoil, residual fuel oil and petroleum products and resultantof users of such oil or product." 34 The EPCA also provided

  15. Simulation of residual oil displacement in a sinusoidal channel with the lattice Boltzmann method

    E-Print Network [OSTI]

    Otomo, Hiroshi; Hazlett, Randy; Li, Yong; Staroselsky, Ilya; Zhang, Raoyang; Chen, Hudong

    2016-01-01

    We simulate oil slug displacement in a sinusoidal channel in order to validate computational models and algorithms for multi-component flow. This case fits in the gap between fully realistic cases characterized by complicated geometry and academic cases with simplistic geometry. Our computational model is based on the lattice Boltzmann method and allows for variation of physical parameters such as wettability and viscosity. The effect of variation of model parameters is analyzed, in particular via comparison with analytical solutions. We discuss the requirements for accurate solution of the oil slug displacement problem.

  16. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  17. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  18. LOW COST BIOHEATING OIL APPLICATION.

    SciTech Connect (OSTI)

    KRISHNA,C.R.

    2003-05-01

    The report describes primarily the results of combustion tests carried out with a soy methyl ester (SME) that can be considered as a biofuel that does not quite meet the ASTM D 6751-02 specifications for biodiesel. The tests were performed in a residential boiler and a commercial boiler. Blends of the SME in distillate fuel (home heating fuel or equivalently, ASTM No.2 fuel oil) were tested in both the boilers. Similar tests had been conducted in a previous project with ASTM biodiesel blends and hence provided a comparison. Blends of the SME in ASTM No.6 oil (residual oil) were also tested in the commercial boiler using a different burner. Physical properties of the blends (in both the petroleum based fuels) were also measured. It was found that the SME blends in the distillate burned, not surprisingly, similarly to biodiesel blends. Reductions in NOx with blending of the SME were the most significant finding as before with biodiesel blends. The blends in No.6 oil also showed reductions in NOx in the commercial boiler combustion tests, though levels with No.6 blends are higher than with No.2 blends as expected. A significant conclusion from the physical property tests was that even the blending of 10% SME with the No.6 oil caused a significant reduction in viscosity, which suggests a potential direction of application of such blends.

  19. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  20. U.S. Adjusted Sales of Residual Fuel Oil by End Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil General Industries and TBDArea: U.S.

  1. Rheology and stability of SRC residual fuel oils - storage evaluation. SRC-1 quarterly technical report, October-December 1982. Supplement

    SciTech Connect (OSTI)

    Tewari, K.C.

    1984-06-01

    In Air Products ongoing study to characterize the rheology and stability of various SRC residual oils, single-phase blends of 50 wt % HSRC and TSL SRC in 1:1 mixtures of 1st- and 2nd-stage process solvents were subjected to storage stability tests at 150/sup 0/F in nitrogen and air atmospheres. Using viscosity as an indicator, it was observed that the blends studied increased in viscosity with storage time in an air atmosphere; the viscosity increase began after a 4-week storage period. The increase in HSRC blend viscosity was significantly greater than that of the TSL SRC blend. A 60-day air-stored blend will require a pumping temperature about 10/sup 0/F higher than that specified for an unaged blend in order to have the same viscosity. The viscosity increase under nitrogen storage was relatively insignificant. Nitrogen blanketing appears to be important in maintaining the specified viscosity characteristics of the blends during storage in the 150/sup 0/F storage condition tested. A loss of volatiles undoubtedly occurs during high-temperature storage under laboratory conditions. Such losses contribute to an increase in the viscosity of the blend. In commercial practice, volatile losses are expected to be significantly lower. Solvent extraction data and analysis of separated fractions suggest that during storage under the above conditions, some oxidative polymerization of pentane-soluble oil components forms higher molecular weight pentane insolubles (asphaltenes and benzene insolubles). Asphaltenes are also involved in the increase in viscosity and do chemically change. 1 reference, 8 figures, 27 tables.

  2. Technology on In-Situ Gas Generation to Recover Residual Oil Reserves

    SciTech Connect (OSTI)

    Sayavur Bakhtiyarov

    2008-02-29

    This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define the sweep efficiency of the in-situ generated CO{sub 2} gas. A set of core flood experiments were conducted to define effect of surfactant on recovery efficiency. The results demonstrated obvious advantages of the foamy system over the brine solution in order to achieve higher sweep efficiency and recovery coefficient. It is shown that a slug injection is not an efficient method for mixing GY and GF solutions and it can't generate considerable gas inside the slim-tube.

  3. Compositional changes in heavy oil steamflood simulators 

    E-Print Network [OSTI]

    Lolley, Christopher Scott

    1995-01-01

    including distillation, vapor pressure, steam distillation and viscosity measurements, along with a commercial PVT simulator are used to tune equation-of-state (EOS) and viscosity parameters to properly model the PVT properties of the oil. The Peng...

  4. New developments in deep hydroconversion of heavy residues with dispersed catalysts

    SciTech Connect (OSTI)

    Del Bianco, A.; Zangirolami, A.; Di Carlo, S. [Enricerche and EURON, Donato (Italy)

    1993-12-31

    Hydrocracking processes utilizing finely dispersed hydrogenation catalysts are particularly suited to upgrade heavy oils and petroleum residues which generally contain high concentrations of heteroatoms, metals and asphaltenes. With this study, the authors observed the effect of the reaction conditions on products yield and quality for hydrocracking experiments performed on a vacuum residue (VR) of Belaym crude (Egypt) in the presence of Mo-naphtenate and within a wide range of severities (410-470{degrees}C, 15-240 minutes). The experimental results demonstrate that the catalyst provides hydrogen in an active form for stabilization of the free radicals produced by thermal cracking so that distillate yields greater than 80% can be obtained with minimum coke production. The data describing the influence of the reaction condition on distillate and gas composition as well as asphaltene conversion are discussed and a preliminary kinetic analysis of the VR conversion reaction is presented.

  5. New coal-derived catalyst for transfer hydrocracking of vacuum residue

    SciTech Connect (OSTI)

    Nakamura, Ikusei; Fujimoto, Kaoru [Univ. of Tokyo (Japan)

    1995-12-31

    Liquid phase hydrocracking of Arabian Heavy vacuum residue conducted in the presence of metal supported active carbon catalyst gave large amount of distillates (70%) with small hydrogen consumption. Especially the Yallourn coal derived active carbon catalyst showed high activity for the cracking of Arabian Heavy vacuum residue. The yield of asphaltene in the product oil was very low, whereas the coke yield was relatively high (about 4 wt%). In the metal-free active carbon system, the coke yield and the content of olefins, sulfur compounds, and asphaltene in the product oil were higher than those of the metal-supported active carbon system. These results suggest that asphaltene in feed oil was adsorbed on the metal supported active carbon catalyst and was decomposed or dehydrogenated on it to form coke and hydrogen atoms. The hydrogen atoms formed migrated on the carbon surface to reach the metal site and transferred to free radicals, olefins, or organo sulfur compounds.

  6. High resolution FT-ICR mass spectral analysis of bio-oil and residual water soluble organics produced by hydrothermal liquefaction of the marine microalga Nannochloropsis salina

    SciTech Connect (OSTI)

    Sudasinghe, Nilusha; Dungan, Barry; Lammers, Peter; Albrecht, Karl O.; Elliott, Douglas C.; Hallen, Richard T.; Schaub, Tanner

    2014-03-01

    We report a detailed compositional characterization of a bio-crude oil and aqueous by-product from hydrothermal liquefaction of Nannochloropsis salina by direct infusion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) in both positive- and negative-ionization modes. The FT-ICR MS instrumentation approach facilitates direct assignment of elemental composition to >7000 resolved mass spectral peaks and three-dimensional mass spectral images for individual heteroatom classes highlight compositional diversity of the two samples and provide a baseline description of these materials. Aromatic nitrogen compounds and free fatty acids are predominant species observed in both the bio-oil and aqueous fraction. Residual organic compounds present in the aqueous fraction show distributions that are slightly lower in both molecular ring and/or double bond value and carbon number relative to those found in the bio-oil, albeit with a high degree of commonality between the two compositions.

  7. Time course of systemic oxidative stress and inflammatory response induced by an acute exposure to Residual Oil Fly Ash

    SciTech Connect (OSTI)

    Marchini, T.; Magnani, N.D.; Paz, M.L.; Vanasco, V.; Tasat, D.; González Maglio, D.H.; and others

    2014-01-15

    It is suggested that systemic oxidative stress and inflammation play a central role in the onset and progression of cardiovascular diseases associated with the exposure to particulate matter (PM). The aim of this work was to evaluate the time changes of systemic markers of oxidative stress and inflammation, after an acute exposure to Residual Oil Fly Ash (ROFA). Female Swiss mice were intranasally instilled with a ROFA suspension (1.0 mg/kg body weight) or saline solution, and plasma levels of oxidative damage markers [thiobarbituric acid reactive substances (TBARSs) and protein carbonyls], antioxidant status [reduced (GSH) and oxidized (GSSG) glutathione, ascorbic acid levels, and superoxide dismutase (SOD) activity], cytokines levels, and intravascular leukocyte activation were evaluated after 1, 3 or 5 h of exposure. Oxidative damage to lipids and decreased GSH/GSSG ratio were observed in ROFA-exposed mice as early as 1 h. Afterwards, increased protein oxidation, decreased ascorbic acid content and SOD activity were found in this group at 3 h. The onset of an adaptive response was observed at 5 h after the ROFA exposure, as indicated by decreased TBARS plasma content and increased SOD activity. The observed increase in oxidative damage to plasma macromolecules, together with systemic antioxidants depletion, may be a consequence of a systemic inflammatory response triggered by the ROFA exposure, since increased TNF-? and IL-6 plasma levels and polymorphonuclear leukocytes activation was found at every evaluated time point. These findings contribute to the understanding of the increase in cardiovascular morbidity and mortality, in association with environmental PM inhalation. - Highlights: • An acute exposure to ROFA triggers the occurrence of systemic oxidative stress. • Changes in plasmatic oxidative stress markers appear as early as 1 h after exposure. • ROFA induces proinflammatory cytokines release and intravascular leukocyte activation. • PMN activation is a relevant source of reactive oxygen species in this model. • These findings may account for previously described cardiopulmonary alterations.

  8. Hydrocracking distillate feedstocks

    SciTech Connect (OSTI)

    Kurganov, V.M.; Gorshtein, A.B.; Shkol'nik, B.L.; Shtein, V.I.

    1987-05-01

    The main shortcoming of single-stage hydrocracking is the very high level of feedstock cracking. The authors discuss the development of multistage technology in which each stage can operate under optimal conditions at a moderate conversion level, better flexibility in process control, and better process indexes. The main feature of the multistage technology is the preliminary hydrogenation of the original feed. The composition of the original feed and the middle distillate cuts obtaining in two-stage hydrocracking of a vacuum distillate from West Siberian crude, using cobalt-molybdenum oxide catalyst in the first stage and a zeolitic catalyst in the second stage is presented. Data is provided on the influence of pressure on the hydrocracking indexes.

  9. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    that handle more than 90% of separations and purifications. The capital investment for these distillation.87 million TJ) per year, or to a power consumption of 91 GW, or 54 million tons of crude oil. Distillation conditions to minimize the total investment and operating cost. Continuous decisions are related

  10. How to convert gradually to oil-refinery hydrocracking

    SciTech Connect (OSTI)

    Basta, N.

    1986-01-06

    Over the past ten years, demand for refined petroleum products has been relatively constant, primarily because of worldwide conservation efforts. In fact, the demand for residual fuels has actually declined, while the market for gasoline has risen just slightly. Only middle distillates, which have seen a moderate increase since 1975, will continue to rise slowly over the next several years, says UOP Inc., a Des Plaines, Illinois, division of Allied-Signal Inc. This rise, coupled with the decline in resid demand, dictates the need for conversion capacity that will be capable of selectively producing distillate products. Traditionally, this need has been filled by hydrocracking gas oils to distillates. However, full conversion to hydrocracking requires high capital investment, which may not be possible in today's competitive refining industry. As a solution to this problem, UOP has developed a staged approach to distillate production, which allows the refiner both to phase in capital costs and to increase production over a number of years, says Mark Reno, manager of hydrocracking process development. The staged approach involves (1) constructing a mild-hydrocracking (MHC) unit that would produce less distillate, but at a lower cost; (2) upgrading to full conversion at a later date. The aldready-installed MHC equipment would be used with only minor modifications. UOP offers its own mild/full hydrocracking technology, called unibon; the firm says it can also convert a customer's existing hydrotreating equipment.

  11. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01

    are treated under the same conditions* Prom our knowledge of the de­ structive distillation of organic substances, the most common of which are coal, wood, bones, peat and lignite, it is reasonable to conclude also that the destructive distillation... the question as to what are the char­ acteristic properties of the two carbon residues 20 obtained from the decomposition of carbonaceous materials, termed coke and charcoal. Some author­ ities use the term coke for the carbon residue from coal and call all...

  12. ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried

    E-Print Network [OSTI]

    ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced amounts of fish meal, fish oil, whole wheat flour, corn gluten meal, and vitamin and mineral premixes

  13. Process for preparing lubricating oil from used waste lubricating oil

    DOE Patents [OSTI]

    Whisman, Marvin L. (Bartlesville, OK); Reynolds, James W. (Bartlesville, OK); Goetzinger, John W. (Bartlesville, OK); Cotton, Faye O. (Bartlesville, OK)

    1978-01-01

    A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

  14. Product Supplied for Distillate Fuel Oil

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1,272 1,192 1981-2015 Gulf Coast (PADD 3) 922 908 771 788 795 783 1981-2015 Rocky Mountain (PADD 4) 201 203 206 184 204 193 1981-2015 West Coast (PADD 5) 501 492 551 495 526...

  15. Atmospheric Crude Oil Distillation Operable Capacity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O DBiomass and BiofuelsPhysicist47 Industrial1 (Barrels per

  16. Distillate Fuel Oil Sales for Commercial Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet)Cubic1992Thousand9)%YearD

  17. Distillate Fuel Oil Sales for Farm Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet)Cubic1992Thousand9)%YearD660,024

  18. Distillate Fuel Oil Sales for Industrial Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic

  19. Distillate Fuel Oil Sales for Military Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242 246,243 142,696 146,356 220,601

  20. Distillate Fuel Oil Sales for Railroad Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242 246,243 142,696

  1. Distillate Fuel Oil Sales for Residential Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242 246,243 142,6964,103,881

  2. Total Adjusted Sales of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8, 2015

  3. Total Sales of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8,Product:

  4. Atmospheric Crude Oil Distillation Operable Capacity

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table 1.101 (Million Short6 Macroeconomic8 (Barrels

  5. Distillate Fuel Oil Days of Supply

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table272/S The National Interim714 b Weekly Download

  6. Distillate Fuel Oil Sales for Residential Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table272/S The National Interim714 b WeeklyEnd Use/

  7. Product Supplied for Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160 OctoberFeet)22,108.15,452.333,646

  8. Data acquisition, distillation,Data acquisition, distillation, and storageand storage

    E-Print Network [OSTI]

    ' to executeDetermines `best time' to execute a program based on weather,a program based on weather, arrayData acquisition, distillation,Data acquisition, distillation, and storageand storage · FASR will produce ~10 Tbyte/day at maturity · "Raw" data products include visibility data, M&C data, calibration

  9. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, Raymond P. (Overland Park, KS); Schmalzer, David K. (Englewood, CO); Wright, Charles H. (Overland Park, KS)

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  10. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  11. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated...

  12. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, Gus T. (Paducah, KY); Holshouser, Stephen K. (Boaz, KY); Coleman, Richard M. (Paducah, KY); Harless, Charles E. (Smithland, KY); Whinnery, III, Walter N. (Paducah, KY)

    1983-01-01

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  13. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, G.T.; Holshouser, S.K.; Coleman, R.M.; Harless, C.E.; Whinnery, W.N. III

    1982-03-17

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  14. Optimal Control of Distillation Systems 

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  15. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

    2009-11-03

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  16. A Study of the Use of Jatropha Oil Blends in Boilers

    SciTech Connect (OSTI)

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic reductions in sulfur dioxide emissions are measured with the blends. Again, consistent with our past experience with biodiesel blends, significant reductions in nitrogen oxide emissions nearing 50% with 100% Jatropha oil, were also measured. This is in contrast with the use of biodiesel in diesel engines, where the NOx has a tendency to increase. In addition to the gaseous emission measurements, particulate emissions were measured using an EPA CTM-39 system to obtain both particulates, of sizes below 2.5 microns, so-called PM2.5, and of sizes larger than 2.5 microns. The results show that the particulate emissions are lower with the blending of Jatropha oil. Overall, one can conclude that the blending of Jatropha oil with residual oil is a feasible approach to using non-edible plant oil to provide a renewable content to residual oil, with significant benefits in the reduction of pollutant emissions such as sulfur dioxide, nitrogen oxides and particulates.

  17. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

  18. ,"U.S. Sales for Resale Refiner Residual Fuel Oil and No. 4 Fuel Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall to $3.43U.S.longecReformulated Gasoline RefinerResidual Fuel

  19. Distillate Fuel Oil Sales for Oil Company Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242 246,243 142,696 146,356760,877

  20. Crude oil and finished fuel storage stability: An annotated review

    SciTech Connect (OSTI)

    Whisman, M.L.; Anderson, R.P.; Woodward, P.W.; Giles, H.N.

    1991-01-01

    A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by all the citations for that category.

  1. Method for reclaiming waste lubricating oils

    DOE Patents [OSTI]

    Whisman, Marvin L. (Bartlesville, OK); Goetzinger, John W. (Bartlesville, OK); Cotton, Faye O. (Bartlesville, OK)

    1978-01-01

    A method for purifying and reclaiming used lubricating oils containing additives such as detergents, antioxidants, corrosion inhibitors, extreme pressure agents and the like and other solid and liquid contaminants by preferably first vacuum distilling the used oil to remove water and low-boiling contaminants, and treating the dried oil with a solvent mixture of butanol, isopropanol and methylethyl ketone which causes the separation of a layer of sludge containing contaminants, unspent additives and oxidation products. After solvent recovery, the desludged oil is then subjected to conventional lubricating oil refining steps such as distillation followed by decolorization and deodorization.

  2. Assisted distillation of quantum coherence

    E-Print Network [OSTI]

    Chitambar, E; Rana, S; Bera, M N; Adesso, G; Lewenstein, M

    2015-01-01

    We introduce and study the task of assisted coherence distillation. This task arises naturally in bipartite systems where both parties work together to generate the maximal possible coherence on one of the subsystems. Only incoherent operations are allowed on the target system while general local quantum operations are permitted on the other, an operational paradigm that we call local quantum-incoherent operations and classical communication (LQICC). We show that the asymptotic rate of assisted coherence distillation for pure states is equal to the coherence of assistance, a direct analog of the entanglement of assistance, whose properties we characterize. Our findings imply a novel interpretation of the von Neumann entropy: it quantifies the maximum amount of extra quantum coherence a system can gain when receiving assistance from a collaborative party. Our results are generalized to coherence localization in a multipartite setting and possible applications are discussed.

  3. Mild hydrocracking: a low cost route to more distillate

    SciTech Connect (OSTI)

    Kalnes, T.N.; Lamb, P.R.; Pegg, D.R.; Tajbl, D.G.

    1984-03-01

    The UOP MHC Unibon process, a relatively new application of distillate hydrocracking technology, combines the features of desulfurization and hydrocracking to provide a useful tool to aid the refiner in meeting future product demand trends. Already commercialized in four locations, the process is particularly attractive to those refiners who do not have residual conversion capacity. Pay backs of less than one year are common. In addition, the process can provide the FCC refiner with added capability for adjusting the product slate to meet seasonal demands.

  4. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated as a manufacturing method for microchannel...

  5. Energy Recovery in Industrial Distillation Processes 

    E-Print Network [OSTI]

    Paul, D. B.

    1983-01-01

    Distillation processes are energy intensive separation processes which present attractive opportunities for energy conservation. Through the use of multistage vapor recompression, heat which is normally unavailable can be ...

  6. NATCOR -Xpress case study Margaret Oil produces three products: gasoline, jet fuel, and heating oil. The average

    E-Print Network [OSTI]

    Hall, Julian

    NATCOR - Xpress case study Margaret Oil produces three products: gasoline, jet fuel, and heating oil. To produce these products, Margaret purchases crude oil at a price of £11 per barrel. Each day to produce gasoline or jet fuel. Distilled oil can be used to produce all three products. The octane level

  7. Sulfur distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale

    E-Print Network [OSTI]

    Shawabkeh, Reyad A.

    by the thermal cracking process of the El-Lujjan oil shale showed that the yield of oil was around 12 wt of the boiling point for different distillate fractions. Sulfur in Jordanian oil shale was found to be mainly the dominant phases in these fractions. q 2005 Published by Elsevier Ltd. 1. Introduction Oil shale

  8. Reactive oxygen species produced by NADPH oxidase and mitochondrial dysfunction in lung after an acute exposure to Residual Oil Fly Ashes

    SciTech Connect (OSTI)

    Magnani, Natalia D.; Marchini, Timoteo; Vanasco, Virginia; Tasat, Deborah R.; Alvarez, Silvia; Evelson, Pablo

    2013-07-01

    Reactive O{sub 2} species production triggered by particulate matter (PM) exposure is able to initiate oxidative damage mechanisms, which are postulated as responsible for increased morbidity along with the aggravation of respiratory diseases. The aim of this work was to quantitatively analyse the major sources of reactive O{sub 2} species involved in lung O{sub 2} metabolism after an acute exposure to Residual Oil Fly Ashes (ROFAs). Mice were intranasally instilled with a ROFA suspension (1.0 mg/kg body weight), and lung samples were analysed 1 h after instillation. Tissue O{sub 2} consumption and NADPH oxidase (Nox) activity were evaluated in tissue homogenates. Mitochondrial respiration, respiratory chain complexes activity, H{sub 2}O{sub 2} and ATP production rates, mitochondrial membrane potential and oxidative damage markers were assessed in isolated mitochondria. ROFA exposure was found to be associated with 61% increased tissue O{sub 2} consumption, a 30% increase in Nox activity, a 33% increased state 3 mitochondrial O{sub 2} consumption and a mitochondrial complex II activity increased by 25%. During mitochondrial active respiration, mitochondrial depolarization and a 53% decreased ATP production rate were observed. Neither changes in H{sub 2}O{sub 2} production rate, nor oxidative damage in isolated mitochondria were observed after the instillation. After an acute ROFA exposure, increased tissue O{sub 2} consumption may account for an augmented Nox activity, causing an increased O{sub 2}{sup ·?} production. The mitochondrial function modifications found may prevent oxidative damage within the organelle. These findings provide new insights to the understanding of the mechanisms involving reactive O{sub 2} species production in the lung triggered by ROFA exposure. - Highlights: • Exposure to ROFA alters the oxidative metabolism in mice lung. • The augmented Nox activity contributes to the high tissue O{sub 2} consumption. • Exposure to ROFA produces alterations in mitochondrial function. • ??{sub m} decrease in state 3 may be responsible for the decreased ATP production. • Mild uncoupling prevents mitochondrial oxidative damage.

  9. Oil biodegradation and bioremediation: A tale of the two worst spills in U.S. history

    E-Print Network [OSTI]

    Atlas, R.M.

    2012-01-01

    L. Biodegradability of dispersed crude oil at two differentBiodegradability of lingering crude oil 19 years after theand weathering of crude oil residues on shorelines 18 years

  10. Analysis and Control of Heteroazeotropic Batch Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , called an entrainer, has to be added to facilitate separation and enhance distillation. When a heavy entrainer is added continuously in the top section of the batch column the process is called extractive batch distillation. When an entrainer is added batchwise to the original mixture we simply call

  11. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01

    condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

  12. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  13. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  14. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  15. Electric Driven Heat Pumps in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.

    1983-01-01

    Radian Corporation, under contract to the Electric Power Research Institute, has recently completed a study of the potential range of application for retrofitting electric driven heat pumps to existing distillation columns. ...

  16. Explaining EIA Crude Oil and Petroleum Product Price Data and Comparing with Other U.S. Government Data Sources, 2001 to 2010

    Reports and Publications (EIA)

    2012-01-01

    This article describes the sampling frames and basic data collection methods for petroleum price data reported by Energy Information Administration (EIA) and other Government agencies. In addition, it compares and contrasts annual average prices reported by EIA with comparable prices from the Bureau of Labor Statistics (BLS) CPI (Consumer Price Indexes) for the retail prices of residential No. 2 distillate, on-highway diesel fuel and motor gasoline (all grades.) Further, it compares refiner wholesale/resale prices for No. 2 fuel oil, No. 2 diesel fuel, motor gasoline (all grades,) kerosene-type jet fuel and residual fuel oil reported by EIA with comparable prices from the BLS PPI (Producer Price Index.) A discussion of the various crude oil prices and spot/futures prices published by EIA and other Government agencies is also included in the article.

  17. POTENTIAL USES OF SPENT SHALE IN THE TREATMENT OF OIL SHALE RETORT WATERS

    E-Print Network [OSTI]

    Fox, J.P.

    2013-01-01

    pore-volume study of retorted oil shale," Lawrence Livermorekinetics between and oil-shale residual carbon. 1. co Effectkinetics between and oil-shale residual carbon. 2. co 2

  18. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio blog distillation by adding a link analysis phase to the standard retrieval-by-topicality phase, where in blog distillation. 1 Introduction Blog distillation is a subtask of blog search. It is defined

  19. Co-processing of carbonaceous solids and petroleum oil

    DOE Patents [OSTI]

    Gupta, Avinash (Bloomfield, NJ); Greene, Marvin I. (Oradell, NJ)

    1992-01-01

    In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the thermal liquefaction heater. Coal may be co-processed with petroleum oil by adding pre-hydrogenated oil to the first stage or unhydrogenated oil to the second stage.

  20. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    185.2 1,221.3 2,194.0 W 2,280.9 May ... 47.5 W 452.2 880.5 143.6 1,024.1 1,476.3 W 1,528.3 June ... 35.4 W...

  1. East Coast (PADD 1) Distillate Fuel Oil Imports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969Central RegionReporting Guidelines VoluntaryStatement 1

  2. Distillate Fuel Oil Sales for All Other Uses

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet)Cubic1992Thousand9)%YearD eDiscussion0

  3. Distillate Fuel Oil Sales for Off-Highway Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242 246,243 142,696 146,356

  4. Distillate Fuel Oil Sales for Vessel Bunkering Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242 246,243 142,6964,103,8811,912,984

  5. Stocks of Distillate Fuel Oil Greater Than 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG

  6. Adjusted Distillate Fuel Oil Sales for Residential Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table 1.10 CoolingNotes &*GinaSpring 2008

  7. Distillate Fuel Oil Assessment for Winter 1995-1996

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table272/S The National Interim714 b

  8. Gross Input to Atmospheric Crude Oil Distillation Units

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See full Genealogy of MajorNationalDay)

  9. Refiner and Blender Net Production of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space5,168 5,228 5,107 4,938

  10. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  11. Entanglement distillation in optomechanics via unsharp measurements

    E-Print Network [OSTI]

    Víctor Montenegro; Alessandro Ferraro; Sougato Bose

    2015-03-15

    Quantum technologies based on optical Gaussian states have proven very promising in terms of scalability. However, their use in quantum networking is hindered by the fact that Gaussian entanglement cannot be distilled via Gaussian operations. We take advantage of hybrid optomechanical systems to address this problem, proposing a scheme to distill optical two-mode squeezed vacua via unsharp measurements. Here, one of the optical modes is injected into a single sided Fabry-P\\'{e}rot cavity and non-linearly coupled to a mechanical oscillator. Afterwards, the position of the oscillator is measured using pulsed optomechanics and homodyne detection. Our results show that this measurement can conditionally increase the initial entanglement under an optimal radiation-pressure interaction strength, which corresponds to an effective unsharp non-Gaussian measurement of the photon number inside the cavity. We show how the resulting entanglement distillation can be verified by using a standard quantum teleportation procedure.

  12. Control Strategies for Abandoned in situ Oil Shale Retorts

    E-Print Network [OSTI]

    Persoff, P.; Fox, J.P.

    1979-01-01

    Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Pollution of Spent Oil Shale Residues, EDB Lea, Salinity

  13. Control Strategies for Abandoned in situ Oil Shale Retorts

    E-Print Network [OSTI]

    Persoff, P.; Fox, J.P.

    1979-01-01

    Presented elt the TUJelfth Oil Shale Synlposittnz, Golden,for Abandoned In Situ Oil Shale Retorts P. Persoll and ]. P.Water Pollution of Spent Oil Shale Residues, EDB Lea,

  14. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Zamarripa, Pablo A. Marchetti, Ignacio E. Grossmann Department of Chemical Engineering Carnegie Mellon Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits

  15. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    homes in the United States use middle distillate as a primary energy source for heating. -homes in the United States use middle distillate as their primary energy source for heating. -

  16. Industrial Utilization of Coal-Oil Mixtures 

    E-Print Network [OSTI]

    Dunn, J. E.; Hawkins, G. T.

    1982-01-01

    Coal-oil mixtures (COM) are receiving increasing interest as economical alternatives to residual fuel oil and natural gas used in heavy industrial and utility applications. Four basic approaches are currently employed in the manufacture of COM...

  17. Refiner/marketer targets production of transportation fuels and distillates

    SciTech Connect (OSTI)

    Thompson, J.E.

    1997-01-01

    Citgo Petroleum Corp., the wholly owned subsidiary of Petroleos de Venezuela, S.A. (PDVSA), the Venezuelan national oil company, owns two gasoline producing refineries, a 305,000-b/d system in Lake Charles, La., and a 130,000-b/d facility in Corpus Christi, Texas. Each is considered a deep conversion facility capable of converting heavy, sour crudes into a high percentage of transportation fuels and distillates. Two smaller refineries, one in Paulsboro, N.J., and one in Savannah, GA., have the capacity to process 40,000 b/d and 28,000 b/d of crude, respectively, for asphalt products. In the past two years, Citgo`s light oils refineries operated safely and reliably with a minimum of unscheduled shutdowns. An ongoing emphasis to increase reliability has resulted in extended run lengths at the refineries. Citgo has invested $314 million at its facilities in 1995, much of this toward environmental and regulatory projects, such as the new waste water treatment unit at the Lake Charles refinery. Over the next few years, Citgo expects to complete $1.5 billion in capital spending for major processing units such as a 60,000-b/d FCC feed hydrotreater unit at the Lake Charles refinery and crude expansion at the Corpus Christi refinery. Product exchanges and expanded transport agreements are allowing Citgo to extend its marketing reach.

  18. Crude Distillation Unit Heat Recovery Study 

    E-Print Network [OSTI]

    John, P.

    1979-01-01

    Baytown's Pipe Still 3 is a 95,000 barrel per day crude distillation unit. A comprehensive heat recovery and energy utilization study was done on Pipe Still 3 after a preliminary cursory study had indicated that an overall look at the total picture...

  19. Intelligent fuzzy supervisory control for distillation columns 

    E-Print Network [OSTI]

    Santhanam, Srinivasan

    1993-01-01

    (disturbance) and the response of the top tray temperature(controlled variable). This thesis will also outline a simulation software to characterize a benzene-toluene binary distillation column and an X-window based Graphical User Interface to run the simulation....

  20. Energy Conservation Options in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01

    of theoretical trays in any re boiled distillation column. Columns in which all of the required heat enters with the feed cannot achieve i I I ....e-.........c..._. I "

  1. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and Technology N--7034 Trondheim Norway Abstract The task of separating a multicomponent mixture into streams shell using dividing walls or vertical partitions. INTRODUCTION Industrial distillation processes is also known as the Petlyuk column, due to a theoretical study of Pet­ lyuk et al. (1965), or as a fully

  2. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and Technology N­7034 Trondheim Norway Abstract The task of separating a multicomponent mixture intostreams shell using dividing walls or vertical partitions. INTRODUCTION Industrial distillation processes is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  3. Advanced Distillation: Programs Proposed to DOE 

    E-Print Network [OSTI]

    Woinsky, S. G.

    2001-01-01

    to the foremost practitioner of the Advanced Distillation art, due to a 30 year continuity in Ule area as both a consultant and a university professor. His consulting assignments lu1ve been long-ternl companies such as M, W, Kellogg... when a plgasoline have lead...

  4. New Design Methods and Algorithms for Multi-component Distillation...

    Broader source: Energy.gov (indexed) [DOE]

    multicomponent.pdf More Documents & Publications CX-100137 Categorical Exclusion Determination ITP Chemicals: Hybripd SeparationsDistillation Technology. Research Opportunities...

  5. POTENTIAL USES OF SPENT SHALE IN THE TREATMENT OF OIL SHALE RETORT WATERS

    E-Print Network [OSTI]

    Fox, J.P.

    2013-01-01

    study of retorted oil shale," Lawrence Livermore Laboratoryb) using columns of spent shale. REFERENCES Burnham, Alankinetics between and oil-shale residual carbon. 1. co Effect

  6. Suppression of sludge formation by two-stage hydrocracking of vacuum residue at high conversion

    SciTech Connect (OSTI)

    Mochida, I.; Zhao, X.; Sakanishi, K. (Inst. of Advanced Material Study, Kyushu Univ., Kasuga, Fukuoka 816 (JP))

    1990-12-01

    This paper reports on hydrocracked products from Arabian light vacuum residue at high conversion into distillate ({gt}50%) that were analyzed in order to reveal how sludge formation was suppressed in the two-stage reaction. Although the asphaltene in the starting residue was highly soluble in the starting maltene in spite of is largest molecular weight, single-stage hydrocracking at a higher temperature of 420{degrees}C increased the aromaticity of the asphaltene through extensive deaklylation and dehydrogenation, leading to sludge formation. In contrast, two-stage hydrocracking at 390{degrees}C--3 h/420{degrees}C--1/h accomplished effective depolymerization of the asphaltene, high conversion being achieved without sludge. The carbon aromaticity (f{sub a}) of the produced asphaltene was maintained rather low, although its amount in the product was much the same regardless of the reaction conditions. The heptane-soluble maltenes in the hydrocracked oils exhibited variable dissolving abilities against the asphaltene according to the content and aromaticity of its aromatic fraction, also influencing sludge formation. Hydrocracking produced paraffins through the hydrogenative deaklylation of long-chain alkylbenzenes, decreasing f{sub a} and the dissolving ability of the hydrocracked maltene.

  7. HOUSEHOLD AND STRUCTURAL INSECTS Mineral Oil and Aliphatic Alcohols: Toxicity and Analysis of Synergistic

    E-Print Network [OSTI]

    O'Brien, Timothy E.

    HOUSEHOLD AND STRUCTURAL INSECTS Mineral Oil and Aliphatic Alcohols: Toxicity and Analysis. Entomol. 104(5): 1680Ð1686 (2011); DOI: http://dx.doi.org/10.1603/EC10440 ABSTRACT Two mineral oils and 12 and some- times repeated applications. Mineral oils, and other petroleum distillates, are often used

  8. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  9. Unifying classical and quantum key distillation

    E-Print Network [OSTI]

    Matthias Christandl; Artur Ekert; Michal Horodecki; Pawel Horodecki; Jonathan Oppenheim; Renato Renner

    2007-02-28

    Assume that two distant parties, Alice and Bob, as well as an adversary, Eve, have access to (quantum) systems prepared jointly according to a tripartite state. In addition, Alice and Bob can use local operations and authenticated public classical communication. Their goal is to establish a key which is unknown to Eve. We initiate the study of this scenario as a unification of two standard scenarios: (i) key distillation (agreement) from classical correlations and (ii) key distillation from pure tripartite quantum states. Firstly, we obtain generalisations of fundamental results related to scenarios (i) and (ii), including upper bounds on the key rate. Moreover, based on an embedding of classical distributions into quantum states, we are able to find new connections between protocols and quantities in the standard scenarios (i) and (ii). Secondly, we study specific properties of key distillation protocols. In particular, we show that every protocol that makes use of pre-shared key can be transformed into an equally efficient protocol which needs no pre-shared key. This result is of practical significance as it applies to quantum key distribution (QKD) protocols, but it also implies that the key rate cannot be locked with information on Eve's side. Finally, we exhibit an arbitrarily large separation between the key rate in the standard setting where Eve is equipped with quantum memory and the key rate in a setting where Eve is only given classical memory. This shows that assumptions on the nature of Eve's memory are important in order to determine the correct security threshold in QKD.

  10. American Distillation Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen5AllEnergyAmeriPower LLC Jump to:Distillation Inc Jump

  11. Increasing Distillate Production at U.S. Refineries

    Reports and Publications (EIA)

    2010-01-01

    Paper explores the potential for U.S. refiners to create more distillate and less gasoline without major additional investments beyond those already planned.

  12. Volatile organic emissions from the distillation and pyrolysis of vegetation

    E-Print Network [OSTI]

    Greenberg, T

    2006-01-01

    emissions from vegetation pyrolysis Comprehensive laboratoryfrom the distillation and pyrolysis of vegetation J. P.J. Anal. and Appl. Pyrolysis, 60, 123–130, 2000. Fall, R. :

  13. The role of convective geothermal systems in the generation, migration, and entrapment of oil

    SciTech Connect (OSTI)

    Hulen, J.B. [Univ. of Utah Research Institute, Salt Lake City, UT (United States)

    1995-06-01

    Modern convective geothermal systems (for example, at Yellowstone National Park) and their fossil equivalents, epithermal mineral deposits (like McLaughlin, California) have traditionally been considered poor petroleum prospects. The concentrated heat which drives these systems is commonly viewed as a negative influence: in other words, any oil initially present in or generated by these systems is quickly degraded to a useless carbonaceous residue. This is true in extreme cases, but numerous examples from the Great Basin, the northern California Coast Ranges, and elsewhere suggest that under certain circumstances, geothermal systems can efficiently generate, transport, and entrap significant quantities of producible petroleum. B.R.T. Simoneit has shown that oil can be hydrothermally generated in an {open_quotes} instant{close_quotes} of geologic time. It follows, then, that away from geothermal systems` high-temperature centers (or in wholly moderate-temperature systems), the encompassing shallow thermal anomalies can distill large volumes of oil from otherwise immature hydrocarbon source rocks. Transport of this newly-generated oil is enhanced by the buoyant upwelling of heated aqueous fluid. Porosity for oil transport and storage is created or increased by hydrothermal dissolution of rock-forming or secondary silicates and carbonates. Finally, geothermal {open_quotes}self-sealing{close_quotes} -- the deposition of secondary minerals (especially silica and clay) at the margins of a system -- can provide a very effective hydrocarbon seal. Lee Allison has noted the coincidence of igneous intrusions and oil reservoirs in Nevada. It is suggested that here and elsewhere, both igneous-related and amagmatic geothermal systems in otherwise favorable settings should be viewed as prime petroleum exploration targets.

  14. A new approach to oil refining with allowance for ecological requirements

    SciTech Connect (OSTI)

    Nasirov, R.K.; Serikov, P.Yu.; Barsukov, O.V. [and others

    1994-12-01

    More stringent quality requirements are being imposed on oil fuels because of the deteriorating ecological situation. At the same time the new ecological constraints have slightly reduced the supplies of light crudes on the world market because the oil-producing countries have been forced to consume more of their best crudes and only heavier and sour crudes are sent to other countries for refining. In view of this, in recent years work has been focused on thorough refining of oil distillates and residues in a medium of hydrogen-containing gas in the presence of catalysts for hydrorefining and hydrocracking. Hydrorefining destroys sulfur-, nitrogen-, and oxygen-containing compounds of the stock, removes organometallic components, improves the ecological characteristics of the products, reduces the corrosion of the refinery equipment, and reduces atmospheric pollution. Hydrorefining units have been built at almost all refineries, with allowance for the above and the fact that the hydroprocesses are highly technologically suitable and controllable and produce almost no waste. A number of problems pertaining to hydroprocesses, interesting scientific results, and developed theoretical approaches to intensify hydrorefining processes are described.

  15. Cost, Conflict and Climate: U.S. Challenges in the World Oil Market

    E-Print Network [OSTI]

    Borenstein, Severin

    2008-01-01

    1.1 and 1.1A Figure 6: Uses of Crude Oil in the UnitedStates Other Residual Fuel Oil (bunker fuel) PetrochemicalDiesel Fuel and Heating Oil Jet Fuel Figure 7: Sources of

  16. Defining a Standard Metric for Electricity Savings

    E-Print Network [OSTI]

    Koomey, Jonathan

    2009-01-01

    delivered to the meter Fuel Existing plants Steam turbineSteam turbineSteam turbine Steam turbine Coal Residual oil Distillate oil

  17. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio report a new approach to blog distillation, defined as the task in which, given a user query, the system ranks the blogs in descending order of relevance to the query topic. Our approach is based on the idea

  18. Phytologia (February 2013) 95(1)10 Chemosystematics of Juniperus: Effects of leaf drying on the essential oil composition of

    E-Print Network [OSTI]

    Adams, Robert P.

    on the essential oil composition of Juniperus pinchotii Robert P. Adams Biology Department, Baylor University, Box. at 22ºC (room temperature, RT). The oils were distilled and analyzed from fresh, 0.5, 1, 2, 4, 8, 16, and 24 mos. storage at RT. The oil yields showed a slight decline initially, but remained fairly constant

  19. Phytologia (May 2013) 95(2)132 Chemosystematics of Juniperus: Effects of leaf drying on the essential oil composition of

    E-Print Network [OSTI]

    Adams, Robert P.

    on the essential oil composition of Juniperus pinchotii, changes during the first 48 hours of drying Robert P-45º C for up to 48 hrs. The oils were distilled and analyzed from fresh leaves and those dried for 4h h of drying (as the leaves became brittle), which explains the previous report of changes in oils

  20. Residual Fuel Oil Sales for Industrial Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011 2012 2013

  1. Residual Fuel Oil Sales for Military Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011 2012 201314,609

  2. Residual Fuel Oil for All Other Uses

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011

  3. Residual Fuel Oil for Commercial Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011415,107 356,343

  4. Total Adjusted Sales of Residual Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8, 2015End Use: TotalEnd

  5. Total Sales of Residual Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8,Product:269,010

  6. Moderate-pressure hydrocracking of heavy vacuum gas oils

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Tracy, W.J.

    1986-03-01

    Market trends toward increased middle distillate have prompted renewed interest in hydrocracking. Moderate pressure hydrocracking (MPHC) is once-through, single stage hydrocracking process which enables partial conversion of 345 C + vacuum gas oils to low sulfur distillates. Advantages over conventional hydrocracking include lower hydrogen partial pressure and, consequently, much lower hydrogen consumption. Lower pressure is also desirable from the point of view of equipment availability since the process may be operated in low pressure equipment not normally used for hydrocracking. An example of commercial application of a MPHC retrofit of a vacuum gas oil desulfurization unit is given. Catalysts and economics are described for the process. 4 references.

  7. Shale Oil Production Performance from a Stimulated Reservoir Volume 

    E-Print Network [OSTI]

    Chaudhary, Anish Singh

    2011-10-21

    RF Recovery factor at 30 years, percent So Oil saturation, fraction Sorg Residual oil saturation at connate gas saturation, fraction Sgc Critical gas saturation, fraction Sw Water saturation, fraction viii SRV Stimulated reservoir volume PVT.................... 24 Table 3: PVT properties of oil used for Eagle Ford oil window well setup .................... 24 Table 4: Relative permeability end points for fracture and matrix.................................. 25...

  8. Microbial enhanced oil recovery and compositions therefor

    DOE Patents [OSTI]

    Bryant, Rebecca S. (Bartlesville, OK)

    1990-01-01

    A method is provided for microbial enhanced oil recovery, wherein a combination of microorganisms is empirically formulated based on survivability under reservoir conditions and oil recovery efficiency, such that injection of the microbial combination may be made, in the presence of essentially only nutrient solution, directly into an injection well of an oil bearing reservoir having oil present at waterflood residual oil saturation concentration. The microbial combination is capable of displacing residual oil from reservoir rock, which oil may be recovered by waterflooding without causing plugging of the reservoir rock. Further, the microorganisms are capable of being transported through the pores of the reservoir rock between said injection well and associated production wells, during waterflooding, which results in a larger area of the reservoir being covered by the oil-mobilizing microorganisms.

  9. Residual Fuel Oil Sales for Oil Company Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011 2012

  10. EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    into one or more high-purity products. Several technologies are feasible for this task, either alone the most widely spread and has a long history in chemical technology. However, until recently, there has in accordance with theoretical predictions of CPM theory. #12;iv Residue curves (RCs) and pinch point curves

  11. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  12. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  13. Synthesis and design of optimal thermal membrane distillation networks 

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30

    Thermal membrane distillation is one of the novel separation methods in the process industry. It involves the simultaneous heat and mass transfer through a hydrophobic semipermeable membrane through the use of thermal energy to bring about...

  14. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  15. Energy Saving in Distillation Using Structured Packing and Vapor Recompression 

    E-Print Network [OSTI]

    Hill, J.H.

    1987-01-01

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated ...

  16. Energy Use in Distillation Operation: Nonlinear Economic Effects 

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation is obviously very...

  17. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  18. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings 

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01

    of applications, embody characteristics that inherently make them economic candidates for absorption cycle heat upgrading. Practical applications to current U.S. distillations could save 30 trillion BTU per year, at payback periods ranging from 1 to 3 years. So...

  19. Integrated Thermal and Hydraulic Analysis of Distillation Columns 

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    2002-01-01

    and Hydraulic Analysis of Distillation Columns Ketan Samant, Aspen Technology Ian Sinclair, Aspen Technology Ginger Keady, Aspen Technology This paper outlines the implementation of column thermal and hydraulic analysis in a simulation environment...

  20. Energy Efficiency in Cryogenic Fractionation Through Distributive Distillation 

    E-Print Network [OSTI]

    Carradine, C. R.; McCue, R. H.

    1992-01-01

    The Advanced Recovery System (ARS) is a patented process that uses the principle of distributed distillation to achieve energy efficiency in the olefins process. This paper describes the concept of ARS and how, by integrating the chill...

  1. Heat Recovery in Distillation by Mechanical Vapor Recompression 

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    1986-01-01

    IN DISTILLATION BY MECHANICAL VAPOR RECOMPRESSION Frederick E. Becker and Alexandra I. Zakak Tecogen, Inc., A Subsidiary of Thermo Electron Corporation Waltham, Massachusetts ABSTRACT A significant reduction in distillation tower energy requirements can..., and then recompressing the low-pressure bottom vapors and injecting them directly into the column bottom. The choice of either scheme is a function of the physical properties of the vapors; i.e., the specific volume of the top or bottom vapors may dictate the most...

  2. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    an overall scheme of crude oil price regulation that met thethe com- putation of crude oil cost increases to refiners.=Average per unit cost of. crude oil pur- chased by the i"'

  3. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    1977-1978 HEATING OIL PRICES II-1 II-3 II-3 Wholesale PricesMonthly U.S. Heating Oil Prices, 1970 - 1978 . . A-16 .H-3 .continuous No. 2 heating oil price information from 1970 to

  4. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    an overall scheme of crude oil price regulation that met thebegan increasing crude oil prices in 1973 but the incomeselling price minus the average costs of crude oil and

  5. This Week In Petroleum Distillate Section

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil Prices

  6. Biomass from Logging Residue and Mill Residue

    E-Print Network [OSTI]

    Biomass from Logging Residue and Mill Residue in East Texas, 2008 by Curtis L. VanderSchaaf, Forest Resource Analyst October 2009 #12;N Introduction The abundance of woody biomass from East Texas forests. This report represents the most current data on the availability of woody biomass in the form of logging

  7. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    growth. For data on world oil consumption and long- term oilOil Production Domestic Oil Consumption a variety of

  8. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  9. Mild hydrocracking for middle distillate production

    SciTech Connect (OSTI)

    Tippett, T.W.; Ward, J.W.

    1985-03-01

    Twenty years ago the first Unicracking plant was installed at Union Oil Company's Los Angeles Refinery. Since that time, 58 Unicracking plants have been installed, converted from other technologies, or are in engineering. The Unicracking process installed at Los Angeles Refinery was pioneering in a number of ways. In particular, it was the first hydrocracking process to use molecular sieve based catalysts. It was also the first hydrocracking process to use integral process technology, namely, the total hydrofined product from the hydrotreater passed without separation into the cracking reactor. The original process was primarily designed to produce high yields of high octane gasoline. Since that time, there have been many changes in the requirements of refinery upgrading units due to changes in and availability of feedstocks, and due to changing product distribution slates. In response to these changing objectives, many modifications have occurred in the Unicracking process and catalysts. Some of the process and catalyst innovations recently implemented are discussed in this paper.

  10. Life-Cycle Assessment of Pyrolysis Bio-Oil Production

    SciTech Connect (OSTI)

    Steele, Philp; Puettmann, Maureen E.; Penmetsa, Venkata Kanthi; Cooper, Jerome E.

    2012-02-01

    As part ofthe Consortium for Research on Renewable Industrial Materials' Phase I life-cycle assessments ofbiofuels, lifecycle inventory burdens from the production of bio-oil were developed and compared with measures for residual fuel oil. Bio-oil feedstock was produced using whole southern pine (Pinus taeda) trees, chipped, and converted into bio-oil by fast pyrolysis. Input parameters and mass and energy balances were derived with Aspen. Mass and energy balances were input to SimaPro to determine the environmental performance of bio-oil compared with residual fuel oil as a heating fuel. Equivalent functional units of 1 MJ were used for demonstrating environmental preference in impact categories, such as fossil fuel use and global warming potential. Results showed near carbon neutrality of the bio-oil. Substituting bio-oil for residual fuel oil, based on the relative carbon emissions of the two fuels, estimated a reduction in CO2 emissions by 0.075 kg CO2 per MJ of fuel combustion or a 70 percent reduction in emission over residual fuel oil. The bio-oil production life-cycle stage consumed 92 percent of the total cradle-to-grave energy requirements, while feedstock collection, preparation, and transportation consumed 4 percent each. This model provides a framework to better understand the major factors affecting greenhouse gas emissions related to bio-oil production and conversion to boiler fuel during fast pyrolysis.

  11. Case Studies of the ROZ CO2 Flood and the Combined ROZ/MPZ CO2 Flood at the Goldsmith Landreth Unit, Ector County, Texas. Using “Next Generation” CO2 EOR Technologies to Optimize the Residual Oil Zone CO2 Flood

    SciTech Connect (OSTI)

    Trentham, Robert C.; Melzer, L. Stephen; Kuuskraa, Vello; Koperna, George

    2015-06-30

    The technology for CO2 Enhanced Oil Recovery (CO2 EOR) has significantly advanced since the earliest floods were implemented in the 1970s. At least for the Permian Basin region of the U.S., the oil recovery has been now been extended into residual oil zones (ROZs) where the mobile fluid phase is water and immobile phase is oil. But the nature of the formation and fluids within the ROZs has brought some challenges that were not present when flooding the MPZs. The Goldsmith-Landreth project in the Permian Basin was intended to first identify the most pressing issues of the ROZs floods and, secondly, begin to address them with new techniques designed to optimize a flood that commingled the MPZ and the ROZ. The early phase of the research conducted considerable reservoir and fluid characterization work and identified both technical and commercial challenges of producing the enormous quantities of water when flooding the ROZs. It also noted the differing water compositions in the ROZ as compared to the overlying MPZs. A new CO2 gas lift system using a capillary string was successfully applied during the project which conveyed the CO2 to the deeper and differing ROZ reservoir conditions at Goldsmith and added a second capillary string that facilitated applying scale inhibitors to mitigate the scaling tendencies of the mixing ROZ and MPZ formation waters. The project also undertook a reservoir modeling effort, using the acquired reservoir characterization data, to history match both the primary and water flood phases of the MPZ and to establish the initial conditions for a modeling effort to forecast response of the ROZ to CO2 EOR. With the advantage of many profile logs acquired from the operator, some concentration on the original pattern area for the ROZ pilot was accomplished to attempt to perfect the history match for that area. Several optional scenarios for producing the ROZ were simulated seeking to find the preferred mode of producing the two intervals. Finally, the project attempted to document for the first time the production performance of commingled MPZ and ROZ CO2 EOR project at the nearby Seminole San Andres Unit. The analysis shows that over 10,000 bopd can be shown to be coming from the ROZ interval, a zone that would have produced no oil under primary or water flood phases. A similar analysis was done for the GLSAU project illustrating that 2000 bopd of incremental EOR oil is currently being produced. The results of the modeling work would suggest that 800 bopd can be attributed to the ROZ alone at GLSAU.

  12. Distillation and Dehydro Reactors Advanced Process Conrol Freeport Texas PLant 

    E-Print Network [OSTI]

    Eisele, D.

    2014-01-01

    Reactors Advanced Process Control Freeport Texas Plant ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC 6/2/2014 INTERNAL... Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC – Control Matrix 6/2/2014 INTERNAL; CONFIDENTIAL 3 ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20...

  13. Process for oil shale retorting

    DOE Patents [OSTI]

    Jones, John B. (300 Enterprise Bldg., Grand Junction, CO 80501); Kunchal, S. Kumar (300 Enterprise Bldg., Grand Junction, CO 80501)

    1981-10-27

    Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

  14. Automated Dispersive Solid Phase Extraction of Pesticide Residues in Botanicals using Triple Quadrupole LC/MS/MS

    E-Print Network [OSTI]

    Heller, Barbara

    /g ·Distilled water (10 mL) was added to the sample and mixed for 1min. ·Samples were then extracted using 10 mAutomated Dispersive Solid Phase Extraction of Pesticide Residues in Botanicals using Triple analysis in food and food products. These methods use acetonitrile extraction followed by salting out

  15. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  16. Experimental Study of Steam Surfactant Flood for Enhancing Heavy Oil Recovery After Waterflooding 

    E-Print Network [OSTI]

    Sunnatov, Dinmukhamed

    2010-07-14

    Steam injection with added surface active chemicals is one of general EOR processes aimed to recover residual oil after primary production processes. It has been demonstrated that, after waterflooding, an oil swept area ...

  17. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    thermal energy (e.g. Koschikowski et al, 2003): #12;Solar thermal powered desalination: reviewSolar thermal powered desalination: membrane versus distillation technologies G. Burgess and K considered to be the desalination technology most suited to integration with concentrating solar thermal

  18. Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b

    E-Print Network [OSTI]

    Skogestad, Sigurd

    savings in energy consumption and reduction of investment cost. In this paper we give an overview of some and calculate energy requirements and provide a basis for detailed design. Reduced CO2 emission is an additional, and to carry out this separation with a minimum cost and energy consumption. Distillation is the most widely

  19. Hydrocracking process with integrated distillate product hydrogenation reactor

    SciTech Connect (OSTI)

    Hoehn, R.K.; Reno, M.E.

    1991-06-25

    This patent describes a hydrocracking process. It comprises passing a feed stream which comprises an admixture of hydrocarbons boiling above 240 degrees Centigrade and hydrogen through a hydrocracking reaction zone maintained at hydrocracking conditions and producing a mixed-phase hydrocracking reaction zone effluent stream; separating the mixed-phase hydrocracking reaction zone effluent stream into a first vapor stream, which comprises hydrogen, light hydrocarbons and distillate hydrocarbons, and a first liquid stream, which comprises distillate hydrocarbons; forming a second vapor stream and a second liquid, stream by partially condensing the first vapor stream, with the second liquid stream comprising distillate hydrocarbons and having a lower average boiling point than the first liquid stream; passing the second liquid stream and added hydrogen through a hydrogenation reaction zone maintained at hydrogenation conditions and producing a hydrogenation zone effluent stream; and, passing distillate hydrocarbons present in the hydrogenation zone effluent stream and the first liquid stream into a fractionation zone, and recovering a hydrocracking zone product stream.

  20. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    . The daily desalinated water output per square metre of solar collector area is estimated for a number suited to integration with concentrating solar thermal concentrating collectors on a medium to largeSolar thermal powered desalination: membrane versus distillation technologies G. Burgess and K

  1. Improved Analysis and Understanding of the Petlyuk Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the energy consumption. When the column is oper­ ated optimally, the infinite staged Petlyuk column always Extended Abstract The Petlyuk (Petlyuk 1965) arrangement for separation of a ternary mixture into three pure product streams has the potential of 20­50% energy savings compared to conventional distillation

  2. Improved Analysis and Understanding of the Petlyuk Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the energy consumption. When the column is oper- ated optimally, the infinite staged Petlyuk column always Extended Abstract The Petlyuk (Petlyuk 1965) arrangement for separation of a ternary mixture into three pure product streams has the potential of 20-50% energy savings compared to conventional distillation

  3. On Boiling of Crude Oil under Elevated Pressure

    E-Print Network [OSTI]

    Pimenova, Anastasiya V

    2015-01-01

    We construct a thermodynamic model for theoretical calculation of the boiling process of multicomponent mixtures of hydrocarbons (e.g., crude oil). The model governs kinetics of the mixture composition in the course of the distillation process along with the boiling temperature increase. The model heavily relies on the theory of dilute solutions of gases in liquids. Importantly, our results are applicable for modelling the process under elevated pressure (while the empiric models for oil cracking are not scalable to the case of extreme pressure), such as in an oil field heated by lava intrusions.

  4. On Boiling of Crude Oil under Elevated Pressure

    E-Print Network [OSTI]

    Anastasiya V. Pimenova; Denis S. Goldobin

    2015-10-08

    We construct a thermodynamic model for theoretical calculation of the boiling process of multicomponent mixtures of hydrocarbons (e.g., crude oil). The model governs kinetics of the mixture composition in the course of the distillation process along with the boiling temperature increase. The model heavily relies on the theory of dilute solutions of gases in liquids. Importantly, our results are applicable for modelling the process under elevated pressure (while the empiric models for oil cracking are not scalable to the case of extreme pressure), such as in an oil field heated by lava intrusions.

  5. Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad Department. It is well known which variables to control in normal distillation columns. But for heat integrated for heat integrated distillation columns. We will use the concept of self­optimizing control (Skogestad et

  6. Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad Department. It is well known which variables to control in normal distillation columns. But for heat integrated for heat integrated distillation columns. We will use the concept of self-optimizing control (Skogestad et

  7. Peanut varieties: potential for fuel oil

    SciTech Connect (OSTI)

    Hammons, R.O.

    1981-01-01

    Research is beginning in farm crushing of peanuts into fuel oil, the high-protein residue being used as livestock feed. Thirty peanut genotypes were investigated for oil and protein yields in field trials in Georgia. For 11 varieties in an irrigated test, mean oil contents (dry base) were in the 49.7-52.7% range, and the level of protein was in the 22.60-26.70% range. Wider variations in oil and protein contents were found in 19 other genotypes selected for possible use as an oil crop. Breeding for high oil yield has not been practiced in US peanut breeding programs. Convergent improvement to attain higher levels of oil content, shell-out percentage, and stable yield will require 6-10 generations of crossing, backcrossing, selection, and testing.

  8. Duality, Residues, Fundamental class

    E-Print Network [OSTI]

    2011-05-22

    May 22, 2011 ... Duality, Residues, Fundamental class. Joseph Lipman. Purdue University. Department of Mathematics lipman@math.purdue.edu. May 22 ...

  9. Integrated process of distillation with side reactors for synthesis of organic acid esters

    DOE Patents [OSTI]

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  10. Energy Information Administration/Petroleum Marketing Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    39 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate...

  11. Biomass from Logging Residue and Mill Residue

    E-Print Network [OSTI]

    as a renewable energy resource or for chemical extraction. This report represents the most current data harvesting or are cut off the central stem of the tree due to a merchantability standard. Limbs refer for energy production or chemical extraction. Table 1 shows the logging residue available in East Texas

  12. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  13. Entanglement cost and distillable entanglement of symmetric states

    E-Print Network [OSTI]

    Keiji Matsumoto

    2007-08-23

    We compute entanglement cost and distillable entanglement of states supported on symmetric subspace. Not only giving general formula, we apply them to the output states of optimal cloning machines. Surprisingly, under some settings, the optimal n to m clone and true m copies are the same in entanglement measures. However, they differ in the error exponent of entanglement dilution. We also presented a general theory of entanglement dilution which is applicable to any non-i.i.d sequence of states.

  14. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  15. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  16. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  17. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  18. New Design Methods and Algorithms for Multi-component Distillation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    isomerization, reforming, and the processing of crude oil, liquefied petroleum gas (LPG), and natural gas liquids (NGL). Project Description The main goal of this research...

  19. Hanford Tank Waste Residuals

    Office of Environmental Management (EM)

    Hanford Tank Waste Residuals DOE HLW Corporate Board November 6, 2008 Chris Kemp, DOE ORP Bill Hewitt, YAHSGS LLC Hanford Tanks & Tank Waste * Single-Shell Tanks (SSTs) - 27...

  20. Process for tertiary oil recovery using tall oil pitch

    DOE Patents [OSTI]

    Radke, Clayton J. (El Cerrito, CA)

    1985-01-01

    Compositions and process employing same for enhancing the recovery of residual acid crudes, particularly heavy crudes, by injecting a composition comprising caustic in an amount sufficient to maintain a pH of at least about 11, preferably at least about 13, and a small but effective amount of a multivalent cation for inhibiting alkaline silica dissolution with the reservoir. Preferably a tall oil pitch soap is included and particularly for the heavy crudes a polymeric mobility control agent.

  1. ORGANOCHLORINE RESIDUES IN FISHES FROM THE NORTHWEST ATLANTIC OCEAN AND GULF OF MEXICO

    E-Print Network [OSTI]

    southeastern United States. Species with lowest oil content «3%)-gag, Mycteroperca microlepis; black grouper, M amounts of chlorinated hydrocarbon residues. Species with higher oil content- king mackerel, Scomberomorus chemical, DDT, became the magic tool of the medical profession, deeply concerned with preventing outbreaks

  2. Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.

    SciTech Connect (OSTI)

    Arora, S.; Wu, M.; Wang, M.; Energy Systems

    2011-02-01

    Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

  3. Azeotropic Distillation as a Technique for Emulsion Size Reduction

    E-Print Network [OSTI]

    Petta, Jason

    : A solvent with HA Boiling point with water Heptane or Hexane Low vapor pressure viscosifying oil Technique for producing uniform picoliter droplets by manipulating two phase fluid flows at low Reynolds such as chloroform, ethanol, and polymers. Microfluidic Generation of Droplets #12;Materials for Emulsions Oil Phase

  4. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    22.7 478.0 - 88.5 22.7 566.5 W 92.0 W 658.5 April ... 24.6 452.2 - 73.8 24.6 525.9 W 102.4 W 628.3 May ... 25.8 733.8 -...

  5. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    1,816.8 W 232.9 W 2,049.7 W 1,434.7 748.3 3,484.5 June ... 452.2 1,645.0 W NA W 1,947.0 W 1,797.0 670.0 3,744.0 July ......

  6. Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    processes can be found in commercial simulators such as Aspen-Plus and Hysys (Aspen Techology), Petro

  7. ,"U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End...

    U.S. Energy Information Administration (EIA) Indexed Site

    worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Residential",4,"Annual",2013,"6301984" ,"Data...

  8. ,"U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative FuelsMonthly","10/2015"Monthly","10/2015" ,"ReleaseMonthly","10/2015"Net Receipts by

  9. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative FuelsMonthly","10/2015"Monthly","10/2015"Imports" ,"Click worksheet name or tab at bottom for

  10. ,,"Distillate Fuel Oil",,,"Alternative Energy Sources(b)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 Relative Standard Errors for Table 5.7;" " Unit:8 Relative

  11. ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 Relative Standard Errors for Table 5.7;" " Unit:8

  12. ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 Relative Standard Errors for Table 5.7;" " Unit:89

  13. ,,,,"Reasons that Made Distillate Fuel Oil Unswitchable"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7 Relative Standard Errors for Table 5.7;" "10.3 Relative534

  14. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.68,502.854.8

  15. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.68,502.854.83,186.1 57,015.7

  16. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.68,502.854.83,186.1

  17. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.68,502.854.83,186.1872.2

  18. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.68,502.854.83,186.1872.2956.0

  19. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.2 10,037.23,846.349.9

  20. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.2 10,037.23,846.349.9048.9 3,882.7

  1. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.2 10,037.23,846.349.9048.9

  2. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubicFracking,MichiganThousand47,959.1 11,050.917,583.7 5,086.5

  3. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubicFracking,MichiganThousand47,959.1 11,050.917,583.7

  4. Table 10.24 Reasons that Made Distillate Fuel Oil Unswitchable, 2006;

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand7,Year Jan995 15

  5. Distillate Fuel Oil Refinery, Bulk Terminal, and Natural Gas Plant Stocks

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table272/S The National Interim714 b Weekly

  6. U.S. Sales of Distillate Fuel Oil by End Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global CrudeWhat'sMay-15 Jun-15Area: U.S. East

  7. Refiner and Blender Net Production of Distillate Fuel Oil 15 ppm Sulfur and

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space5,168 5,228 5,107

  8. Refiner and Blender Net Production of Distillate Fuel Oil > 15 pmm to 500

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space5,168 5,228 5,107ppm

  9. Refiner and Blender Net Production of Distillate Fuel Oil > 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space5,168 5,228 5,107ppm

  10. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  11. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01

    Oil Production . . . . . . . . . . . . . . . . . . . . . . . . . . .Oil Production in Venezuela and Mexico . . . . . . . . . .Oil Production and Productivity in Venezuela and

  12. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01

    the Oil Industry . . . . . . . . . . . . . . . . . . . . . .in the Venezuelan Oil Industry . . . . . . . . . . . . .and Productivity: Evidence from the Oil Industry . .

  13. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  14. Mild hydrocracking of virgin vacuum gas oil, cycle oils and coker gas oil with the T-STAR{reg_sign} process

    SciTech Connect (OSTI)

    Nongbri, G.; Rodarte, A.I. [Texaco Fuels and Lubricants Research Dept., Port Arthur, TX (United States); Falsetti, J.S. [Texaco Inc., White Plains, NY (United States). Alternate Energy Resources Dept.

    1996-12-01

    Texaco Fuels and Lubricants Research recently completed a successful pilot plant program demonstrating the use of the T-STAR{reg_sign} process for mild hydrocracking of blends of low value feedstocks (cycle oils, coker gas oils), virgin distillates and vacuum gas oils to generate high quality diesel and improved quality FCC feed. The T-STAR{reg_sign} Process runs at constant temperature. Catalytic activity is maintained by daily catalyst addition and withdrawal while the unit is on stream. No unit shutdown is needed to replace the catalyst. The possibility of bed plugging or blockage from accumulation of fine solids in the feed is virtually eliminated in this ebullated bed system and the reactor operates with a low and constant pressure drop. The process handles a variety of feedstocks including light and heavy coker gas oils and deasphalted oils. Yields and product properties from a blend of virgin vacuum gas oil, light cycle gas oil and heavy coker gas oil are discussed. A scheme for integrating this process in an existing refinery is also presented.

  15. Behaviour of oil ganglia displaced by a surfactant solution in a porous medium

    E-Print Network [OSTI]

    Boyer, Edmond

    L-97 Behaviour of oil ganglia displaced by a surfactant solution in a porous medium J. C. Moulu'importance relative des forces de viscosité et des forces capillaires. Abstract. 2014 The velocity of oil ganglia residual oil phase by water injection in a porous medium [1, 2]. These studies have demonstrated

  16. Microbial Enhanced Oil Recovery in Fractional-Wet Systems: A Pore-Scale Investigation

    SciTech Connect (OSTI)

    Armstrong, Ryan T.; Wildenschild, Dorthe

    2012-10-24

    Microbial enhanced oil recovery (MEOR) is a technology that could potentially increase the tertiary recovery of oil from mature oil formations. However, the efficacy of this technology in fractional-wet systems is unknown, and the mechanisms involved in oil mobilization therefore need further investigation. Our MEOR strategy consists of the injection of ex situ produced metabolic byproducts produced by Bacillus mojavensis JF-2 (which lower interfacial tension (IFT) via biosurfactant production) into fractional-wet cores containing residual oil. Two different MEOR flooding solutions were tested; one solution contained both microbes and metabolic byproducts while the other contained only the metabolic byproducts. The columns were imaged with X-ray computed microtomography (CMT) after water flooding, and after MEOR, which allowed for the evaluation of the pore-scale processes taking place during MEOR. Results indicate that the larger residual oil blobs and residual oil held under relatively low capillary pressures were the main fractions recovered during MEOR. Residual oil saturation, interfacial curvatures, and oil blob sizes were measured from the CMT images and used to develop a conceptual model for MEOR in fractional-wet systems. Overall, results indicate that MEOR was effective at recovering oil from fractional-wet systems with reported additional oil recovered (AOR) values between 44 and 80%; the highest AOR values were observed in the most oil-wet system.

  17. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    oil and No. 2-D diesel fuel, from price and allocationdiesel fuel, effective October 1, 1977, bad assumed from pricellY controlled prices at No. 2-D diesel fuel to ultimate

  18. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    Frank Zarb to Congress Energy Data Report DOE Regions Sampleare Reported on the Energy Data Report Fuel Oil MarketingAgency: Office of Energy Data/EIA is responsible for

  19. Production and pricing patterns in the international crude oil market

    SciTech Connect (OSTI)

    Fischer, S.C.

    1985-01-01

    This study focuses on measuring the patterns of production and pricing of the major oil-exporting countries over the past decade. It conducts a series of empirical investigations, relying largely on quarterly data, into the determinants of the distribution of oil liftings in the OPEC areas, including the significance of relative crude oil price incentives, the stability of oil prices and market shares, the components of the residual demand for OPEC oil with emphasis on fluctuations in speculative demand for oil inventories, the impact of effective capacity utilization and speculative demand on major price escalations, and the sensitivity of Saudi Arabian price preferences to evolving net demand reaction to higher oil prices and to the share it is able to retain of the OPEC market. The background for this analysis is provided by a review of the historical evolution of oil and energy consumption, production and development patterns during the postwar era, and the reversal of theoretical frameworks for analyzing the international oil market are described, and the rationale for the noncompetitive view of oil prices and production in major exporting countries is detailed. Finally, the transformation of the structure of crude oil marketing over the past decade is analyzed, emphasizing growing competitive trends in the industry mixed with residual oligopolistic tendencies.

  20. Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio Sebastiani

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio in revised form 10 May 2013 Accepted 30 May 2013 Available online 14 June 2013 Keywords: Blog distillation Blog search Link analysis Sentiment analysis a b s t r a c t In this paper we test a new approach

  1. Scaling control during membrane distillation of coal seam gas reverse osmosis brine

    E-Print Network [OSTI]

    Scaling control during membrane distillation of coal seam gas reverse osmosis brine Hung C. Duong during membrane distillation (MD) of brine from reverse osmosis (RO) treatment of coal seam gas (CSG. During CSG production, both gas and water are extracted to the surface. Gas is commonly separated from

  2. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process Q H columnPROMS. AIChE 1999 Annual meeting / 11.03.99 2 NTNU #12; T. Larsson, S. Skogestad Control of a industrial heat

  3. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process QH columnE 1999 Annual meeting / 11.03.99 2 NTNU #12;T. Larsson, S. Skogestad Control of a industrial heat

  4. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Distillation Ivar J. Halvorsen1 and Sigurd Skogestad Norwegian University of Science and Technology, Department Also at SINTEF Electronics and Cybernetics, 7465 Trondheim, Norway Prepared for presentation at the Topical conference on Separations Technology, Session 23 - Distillation Modeling and Processes II. 2001

  5. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  6. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  7. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  8. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    From EIA, “World Production of Crude Oil, NGPL, and Otherfrom EIA, “World Production of Crude Oil, NGPL, and Otherfrom EIA, “World Production of Crude Oil, NGPL, and Other

  9. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  10. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  11. Low capital implementation of distributed distillation in ethylene recovery

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  12. Effects of system densities on distillation column performance

    SciTech Connect (OSTI)

    Fasesan, S.O.; Sanni, S.A.; Taiwo, E.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria). Dept. of Chemical Engineering

    1998-06-01

    Distillation experiments were carried out on three binary systems (ethanol-butanol, ethanol-propan-2-ol, and propan-2-ol-butanol) in a 0.1-m internal diameter glass column packed with 8 mm diameter Raschig rings. The experiments were performed under total reflux conditions and at atmospheric pressure. The data collected on column performance showed that performance declined with increasing average bulk liquid density. The results also lend credence to earlier reports on the behavior of column performance with respect to component concentration in the feed mixtures. The system densities of the three binary systems were measured at four different temperatures, 30, 40, 50, and 60 C. The data were compared with the predicted data of Yen-Woods and Multifluid models. The accuracy of the predictions of the Yen-Woods model was rather poor while that of the Multifluid model was very encouraging.

  13. An experimental and mathematical investigation of hydrocarbon steam distillation 

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01

    I LIJ D D CO D CIC D P1a L), OOLQLI [ [ LQS LQ WP8Q$ ?7) I/I I?I hl m ~ III O I?I I/I O & P) ?I- 0 O nj (Z) 4J Q O E III ID Cl ?I ?I Q ?/ ??: PJ Cl C C I?l ICl E ?J ??I I III 0 az I? I W K Q3 Ctl IQ C) PV... decreases near the end of the run. Th1s occurs when the volume of hydrocarbon 1n the 11quid phase of the distillation cell becomes small and cannot support 1ts vapor pressure. 07 C5 0 III QI 5- I/I QI 5- 0- 5- 0 CL IQ ) 0 CQ Ol O 0 4J Itl...

  14. Investigation and development of alternative methods for shale oil processing and analysis. Final technical report, October 1979--April 1983

    SciTech Connect (OSTI)

    Evans, R.A.

    1998-06-01

    Oil shale, a carbonaceous rock which occurs abundantly in the earth`s crust, has been investigated for many years as an alternate source of fuel oil. The insoluble organic matter contained in such shales is termed {open_quotes}Kerogen{close_quotes} from the Greek meaning oil or oil forming. The kerogen in oil shale breaks down into oil-like products when subjected to conditions simulating destructive distillation. These products have been the subject of extensive investigations by several researchers and many of the constituents of shale oil have been identified. (1) Forsman (2) estimates that the kerogen content of the earth is roughly 3 {times} 10{sup 15} tons as compared to total coal reserves of about 5 {times} 10{sup 12}. Although the current cost per barrel estimate for commercial production of shale oil is higher than that of fossil oil, as our oil reserves continue to dwindle, shale oil technology will become more and more important. When oil shale is heated, kerogen is said to undergo chemical transformation to usable oil in two steps (3): Kerogen (in oil shale) 300-500{degrees}C bitumen. Crude shale oil and other products. The crude shale oil so obtained differs from fossil oil in that: (1) kerogen is thought to have been produced from the aging of plant matter over many years; (2) shale oil has a higher nitrogen content than fossil oil; (3) non-hydrocarbons are present to a much greater extent in shale oil; and (4) the hydrocarbons in shale oil are much more unsaturated than those in fossil oil (petroleum).

  15. A Characterization and Evaluation of Coal Liquefaction Process Streams The Kinetics of Coal Liquefaction Distillation Resid Conversion

    SciTech Connect (OSTI)

    D.Campbell; D.G. Nichols; D.J. Pazuchanics; H.Huang; M.T.Klein; R.A. Winschel; S.D. Brandes; S.Wang; W.H. Calkins

    1998-06-04

    Under subcontract from CONSOL Inc. (DOE Contract N o. DE- AC22- 94PC93054), the University of Delaware studied the mechanism and kinetics of coal liquefaction resid conversion. Th e program at Delaware was conducted be tween August 15, 1994, and April 30, 1997. It consisted of two primary tasks. The first task was to develop an empirical test to measure the reactivit y toward hydrocracking of coal- derived distillation resids. The second task was to formulate a computer model to represent the structure of the resids and a kinetic and mechanistic model of resid reactivity based on the structural representations. An Introduction and Summary of th e project authored by CONSOL and a report of the program findings authored by the University of Delaware researchers are presented here. INTRODUCTION Resid hydrocracking is a key reaction of modern (i. e., distillate- producing) coal liquefactio n processes. Coals are readily converted to resid a nd lighter products in the liquefaction process. The resid is combined with fr esh coal in a ratio often greater than 1: 1, and some vacuum gas oil and is recycled to be further converted. Understanding the chemistry of resids and resi d reactivity is important to improve direct liquefaction process design and to achieve economi c objectives for direct coal liquefaction. Computational models that predict resid conversion from the chemical characteristics of the resids and reaction conditions would be a cost- efficient way to explore process variables. Implementation of such models could aid in the design an d operation of liquefaction facilities.

  16. Full Report.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    g,h Retail Electricity Total Energy g,i Coal Natural Gas a Petroleum Nuclear Fuel Biomass Total g,h,i Distillate Fuel Oil Jet Fuel b LPG c Motor Gasoline d Residual Fuel Oil...

  17. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    oil may indi- thereof -may- participate in these hear- rentrent financial and regulatory situation facing the vast majority of independent fuel oiloil during the cur- evaluation of dB,ta concerill.ng those )PUblished survey data by EIA on rent

  18. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    January 1983 forward; Form EIA-460, "Petroleum Industry Monthly Report for Product Prices," source for backcast estimates prior to January 1983. 36 Energy Information...

  19. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    58.7 46.2 46.3 39.3 49.5 42.9 February ... 54.6 43.7 41.8 35.4 45.2 39.3 March ... 49.3 39.8 37.6 33.9 40.3 35.8 April...

  20. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13 1993

  1. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13 1993

  2. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13 1993

  3. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13 1993

  4. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13 1993

  5. Table 20. U.S. Refiner Residual Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 1993 January

  6. Table 20. U.S. Refiner Residual Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 1993 January

  7. Table 20. U.S. Refiner Residual Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 1993 January

  8. Table 20. U.S. Refiner Residual Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 1993 January

  9. Table 20. U.S. Refiner Residual Fuel Oil Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 1993 January

  10. Residual Fuel Oil Prices, Average - Sales to End Users

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011 2012 2013 2014

  11. Residual Fuel Oil Sales for Vessel Bunkering Use

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic2009 2010 2011 20124,589,049

  12. U.S. Residual Fuel Oil Refiner Sales Volumes

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers inYear Jan FebFeet)YearCrude

  13. U.S. Residual Fuel Oil Prices by Sales Type

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global CrudeWhat'sMay-15 Jun-15Area: U.S. East Coast

  14. Prime Supplier Sales Volumes of Residual Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160 OctoberFeet)22,108.1

  15. Residual Fuel Oil Prices, Average - Sales to End Users

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996 2.003 1990-2016 East Coast (PADD 1)

  16. Residual Fuel Oil Sales to End Users Refiner Sales Volumes

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996 2.003 1990-2016 East Coast (PADD 1)May-15

  17. Residual Fuel Oil Sales to End Users Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearby the(Dollars1.840 2.318 3.1195) Model8)3

  18. Milk is a common ingredient in many fried foods. Allergen cross contact can occur through the use of shared frying oil. Analytical methods are needed to determine the level of protein contamination in re-used oil. This study

    E-Print Network [OSTI]

    Heller, Barbara

    the use of shared frying oil. Analytical methods are needed to determine the level of protein contamination in re-used oil. This study evaluated the performance of four ELISA test kits in comparison with a total protein assay for detection of milk protein residues in spiked oils that have been subjected

  19. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect (OSTI)

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  20. Use of extractive distillation to produce concentrated nitric acid

    SciTech Connect (OSTI)

    Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

    1981-04-01

    Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

  1. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  2. A heat & mass integration approach to reduce capital and operating costs of a distillation configuration

    SciTech Connect (OSTI)

    Madenoor Ramapriya, Gautham; Jiang, Zheyu; Tawarmalani, Mohit; Agrawal, Rakesh

    2015-11-11

    We propose a general method to consolidate distillation columns of a distillation configuration using heat and mass integration. The proposed method encompasses all heat and mass integrations known till date, and includes many more. Each heat and mass integration eliminates a distillation column, a condenser, a reboiler and the heat duty associated with a reboiler. Thus, heat and mass integration can potentially offer significant capital and operating cost benefits. In this talk, we will study the various possible heat and mass integrations in detail, and demonstrate their benefits using case studies. This work will lay out a framework to synthesize an entire new class of useful configurations based on heat and mass integration of distillation columns.

  3. DYNAMIC MODELING AND CONTROL OF REACTIVE DISTILLATION FOR HYDROGENATION OF BENZENE 

    E-Print Network [OSTI]

    Aluko, Obanifemi

    2010-01-16

    This work presents a modeling and control study of a reactive distillation column used for hydrogenation of benzene. A steady state and a dynamic model have been developed to investigate control structures for the column. ...

  4. Water distillation using waste engine heat from an internal combustion engine

    E-Print Network [OSTI]

    Mears, Kevin S

    2006-01-01

    To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

  5. High Performance Trays and Heat Exchangers in Heat Pumped Distillation Columns 

    E-Print Network [OSTI]

    Wisz, M. W.; Antonelli, R.; Ragi, E. G.

    1981-01-01

    exchangers and distillation trays permits additional energy savings by lower reboiler temperature differences, and reduced reflux requirements for a fixed column height, due to closer tray spacings. This paper surveys the heat pump systems currently...

  6. Northeast Home Heating Oil Reserve System Heating Oil, PIA Office...

    Broader source: Energy.gov (indexed) [DOE]

    Northeast Home Heating Oil Reserve System Heating Oil, PIA Office of Fossil Energy Headquaters Northeast Home Heating Oil Reserve System Heating Oil, PIA Office of Fossil Energy...

  7. 5 World Oil Trends WORLD OIL TRENDS

    E-Print Network [OSTI]

    's share of world crude oil production has rebound5 World Oil Trends Chapter 1 WORLD OIL TRENDS INTRODUCTION In considering the outlook for California's petroleum supplies, it is important to give attention to expecta- tions of what the world oil

  8. Characteristics of various methods for solving steady state and unsteady state distillation problems 

    E-Print Network [OSTI]

    Coco, Vincent Joseph

    1965-01-01

    CHARACTERISTICS OF VARIOUS METHODS FOR SOLVING STEADY STATE AND UNSTEADY STATE DISTILLATION PROBLEMS A Thesis By VINCENT JOSEPH COCO Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1965 Major Subject: Chemical Engineering CHARACTERISTICS OF VARIOUS METHODS FOR SOLVING STEADY STATE AND UNSTEADY STATE DISTILLATION PROBLEMS A Thesis By VINCENT JOSEPH COCO Approved as to style and content by...

  9. Comparison between continuous stirred tank reactor extractor and soxhlet extractor for extraction of El-Lajjun oil shale

    SciTech Connect (OSTI)

    Anabtawi, M.Z. [Univ. of Bahrain, Isa Town (Bahrain)

    1996-02-01

    Extraction on El-Lajjun oil shale in a continuous stirred tank reactor extractor (CSTRE) and a Soxhlet extractor was carried out using toluene and chloroform as solvents. Solvents were recovered using two distillation stages, a simple distillation followed by a fractional distillation. Gas chromotography was used to test for the existence of trapped solvent in the yield. It was found that extraction using a CSTRE gave a 12% increase in yield on average compared with the Soxhlet extractor, and an optimum shale size of 1.0mm offered a better yield and solvent recovery for both techniques. It was also found that an optimum ratio of solvent to oil shale of 2:1 gave the best oil yield. The Soxhlet extractor was found to offer an extraction rate of 1 hour to complete extraction compared with 4 hours in a CSTRE. The yield in a CSTRE was found to increase on increase of stirring. When extraction was carried out at the boiling point of the solvents in a CSTRE, the yield was found to increase by 30% on average compared to that of extraction when the solvent was at room temperature. When toluene was used for extraction, the average amount of bitumen extracted was 0.032 g/g of oil shale and 76.4% of the solvent recovered, compared with 0.037 g/g of oil shale and 84.1% of the solvent recovered using a Soxhlet extractor.

  10. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  11. Removal of aqueous rinsable flux residues in a batch spray dishwater

    SciTech Connect (OSTI)

    Slanina, J.T.

    1992-02-01

    An alkaline detergent solution used in an industrial dishwasher was evaluated to remove aqueous rinsable flux residues on printed wiring boards (PWBs) after hot air solder leveling and hot oil solder dip and leveling. The dishwasher, a batch cleaning process, was compared to an existing conveyorized aqueous cleaning process. The aqueous soluble flux residues from both soldering processes were removed with a solution of a mild alkaline detergent dissolved in hot deionized (DI) water.

  12. Materials recovery from shredder residues

    SciTech Connect (OSTI)

    Daniels, E. J.; Jody, B. J.; Pomykala, J., Jr.

    2000-07-24

    Each year, about five (5) million ton of shredder residues are landfilled in the US. Similar quantities are landfilled in Europe and the Pacific Rim. Landfilling of these residues results in a cost to the existing recycling industry and also represents a loss of material resources that are otherwise recyclable. In this paper, the authors outline the resources recoverable from typical shredder residues and describe technology that they have developed to recover these resources.

  13. Mild hydrotreating of heavy oils with modified alumina based catalysts

    SciTech Connect (OSTI)

    Dai, E.P.; Campbell, C.N. [Texaco Research and Development, Port Arthur, TX (United States)

    1994-12-31

    The decreasing demand for heavy fuels oils requires that refiners find ways for converting heavy hydrocarbon feedstocks to higher value mid-distillate products. To increase mid-distillate production, the refiner can choose from several processing options such as hydrocracking, fluid catalytic cracking, and coking. All of these options, however, require heavy capital investments. Because of these high investment costs, refiners are continually searching for conversion processes which may be utilized in existing units. One such process is mild hydrocracking (MHC). The general objective of this work is to identify an MHC catalyst which gives a higher conversion level for heavy hydrocarbon feedstocks, especially that fraction of the feedstock that boils above 1,000 F (538 C), while maintaining the same amount of sediment production. The conventional hydrocracking catalysts that consist of acidic cracking components such as Y zeolite, though exhibiting conversion improvements over alumina based catalysts, were not suitable for processing of heavy oils in the mild hydrocracking mode because of high sediment formation. In contrast, alumina catalysts containing basic oxides (alkali metal and alkaline earth metal) not only improve heavy oil conversion but, also maintain the sediment make at the same level as alumina based catalysts. The sediment make generally decreased with increasing macroporosity.

  14. Residuals, Sludge, and Composting (Maine)

    Broader source: Energy.gov [DOE]

    The Maine Department of Environmental Protection's Residuals, Sludge, and Composting program regulates the land application and post-processing of organic wastes, including sewage sludge, septage,...

  15. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    . Total Fuel Oil Consumption and Expenditures for Non-Mall Buildings, 2003" ,"All Buildings* Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  16. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Total Fuel Oil Consumption and Expenditures for All Buildings, 2003" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  17. Bridging the Gap between Chemical Flooding and Independent Oil Producers

    SciTech Connect (OSTI)

    Stan McCool; Tony Walton; Paul Willhite; Mark Ballard; Miguel Rondon; Kaixu Song; Zhijun Liu; Shahab Ahmend; Peter Senior

    2012-03-31

    Ten Kanas oil reservoirs/leases were studied through geological and engineering analysis to assess the potential performance of chemical flooding to recover oil. Reservoirs/leases that have been efficiently waterflooded have the highest performance potential for chemical flooding. Laboratory work to identify efficient chemical systems and to test the oil recovery performance of the systems was the major effort of the project. Efficient chemical systems were identified for crude oils from nine of the reservoirs/leases. Oil recovery performance of the identified chemical systems in Berea sandstone rocks showed 90+ % recoveries of waterflood residual oil for seven crude oils. Oil recoveries increased with the amount of chemical injected. Recoveries were less in Indiana limestone cores. One formulation recovered 80% of the tertiary oil in the limestone rock. Geological studies for nine of the oil reservoirs are presented. Pleasant Prairie, Trembley, Vinland and Stewart Oilfields in Kansas were the most favorable of the studied reservoirs for a pilot chemical flood from geological considerations. Computer simulations of the performance of a laboratory coreflood were used to predict a field application of chemical flooding for the Trembley Oilfield. Estimates of field applications indicated chemical flooding is an economically viable technology for oil recovery.

  18. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    unfettered access to oil resources including the possibleChina’s search for oil resources around the world. However,a survey of China’s oil resources, while others focus

  19. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    Figure 5. Monthly oil production for Iran, Iraq, and Kuwait,day. Monthly crude oil production Iran Iraq Kuwait Figure 6.and the peak in U.S. oil production account for the broad

  20. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    per day. Monthly crude oil production Iran Iraq KuwaitEIA Table 1.2, “OPEC Crude Oil Production (Excluding Lease2008, from EIA, “Crude Oil Production. ” Figure 16. U.S.

  1. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),the Predictive Accuracy of Crude Oil Futures Prices,” EnergyFigure 3. Price of crude oil contract maturing December of

  2. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),percent change in real oil price. Figure 3. Price of crude023 Understanding Crude Oil Prices James D. Hamilton June

  3. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    and Income on Energy and Oil Demand,” Energy Journal 23(1),the faster its growth in oil demand over the last half ofthe income elasticity of oil demand to fall signi?cantly.

  4. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    current pace of growth in oil demand as staying consistentthis point, China’s demand Oil Demand vs. Domestic Supply inand predictions of oil supply and demand affected foreign

  5. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    Michael T. Klare, Blood and Oil: The Dangers of America’sDowns and Jeffrey A. Bader, “Oil-Hungry China Belongs at BigChina, Africa, and Oil,” (Council on Foreign Relations,

  6. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    Natural Gas, Heating Oil and Gasoline,” NBER Working Paper.2006. “China’s Growing Demand for Oil and Its Impact on U.S.and Income on Energy and Oil Demand,” Energy Journal 23(1),

  7. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    China made an Iranian oil investment valued at $70 billion.across Iran, China’s oil investment may exceed $100 billionthese involving investment in oil and gas, really undermine

  8. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    in U.S. real GDP and oil consumption, 1949-2006. slope =Historical Chinese oil consumption and projection of trend.1991-2006: Chinese oil consumption in millions of barrels

  9. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    2004. “OPEC’s Optimal Crude Oil Price,” Energy Policy 32(2),023 Understanding Crude Oil Prices James D. Hamilton Junedirectly. Understanding Crude Oil Prices* James D. Hamilton

  10. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    geological limits, global production of crude oil next yearGlobal production of crude petroleum. Notes: Bold line: From EIA, “World Production of Crude Oil,

  11. Oil Security Metrics Model

    SciTech Connect (OSTI)

    Greene, David L.; Leiby, Paul N.

    2005-03-06

    A presentation to the IWG GPRA USDOE, March 6, 2005, Washington, DC. OSMM estimates oil security benefits of changes in the U.S. oil market.

  12. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    China’s domestic oil supply will peak, and demand Robertpeak will come around 2020, 24 and that by this point, China’s demand Oil

  13. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    historical data for claiming to be able to predict oil pricehistorical data. The second is to look at the predictions of economic theory as to how oil prices

  14. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect (OSTI)

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  15. DEVELOPMENT AND DEPLOYMENT OF VACUUM SALT DISTILLATION AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.; Edwards, T.

    2010-10-28

    The Savannah River Site has a mission to dissolve fissile materials and disposition them. The primary fissile material is plutonium dioxide (PuO{sub 2}). To support dissolution of these materials, the Savannah River National Laboratory (SRNL) designed and demonstrated a vacuum salt distillation (VSD) apparatus using both representative radioactive samples and non-radioactive simulant materials. Vacuum salt distillation, through the removal of chloride salts, increases the quantity of materials suitable for processing in the site's HB-Line Facility. Small-scale non-radioactive experiments at 900-950 C show that >99.8 wt % of the initial charge of chloride salt distilled from the sample boat with recovery of >99.8 wt % of the ceric oxide (CeO{sub 2}) - the surrogate for PuO{sub 2} - as a non-chloride bearing 'product'. Small-scale radioactive testing in a glovebox demonstrated the removal of sodium chloride (NaCl) and potassium chloride (KCl) from 13 PuO{sub 2} samples. Chloride concentrations were distilled from a starting concentration of 1.8-10.8 wt % to a final concentration <500 mg/kg chloride. Initial testing of a non-radioactive, full-scale production prototype is complete. A designed experiment evaluated the impact of distillation temperature, time at temperature, vacuum, product depth, and presence of a boat cover. Significant effort has been devoted to mechanical considerations to facilitate simplified operation in a glovebox.

  16. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow (Rocky Point, NY)

    1994-01-01

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  17. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  18. Dependence of waterflood remaining oil saturation on relative permeability, capillary pressure, and reservoir parameters in mixed wet, turbidite sands

    SciTech Connect (OSTI)

    Hirasaki, G.J.

    1995-12-31

    The dependence of waterflood oil recovery on relative permeability, capillary pressure, and reservoir parameters was investigated by numerical simulation. The relative permeability and capillary pressure curves were based on laboratory measurements on unconsolidated sands and were evaluated for water-wet and mixed wet states. The reservoir model was a prototype turbidite sand with a range of thickness and permeability values. The economic oil recovery was based on an economic limit water cut of 50%. The remaining oil saturation in the swept region for the water-wet cases was close to the residual oil saturation. The remaining oil saturation of the mixed wet cases ranged from low values near the residual oil saturation to far above the residual oil saturation. It is dependent on the reservoir parameters that govern: (1) the vertical {open_quotes}film surface drainage{close_quotes} of oil by gravity, (2) accumulation of a high oil saturation and thus a high relative permeability under the cap rock, (3) updip migration of the oil that accumulated under the cap rock. The dependence on the reservoir parameters can be summarized by dimensionless groups. There is a dimensionless time for the vertical displacement of oil by gravity. The accumulation of a high oil saturation under the cap rock is dependent on the ratio of the capillary transition zone and the sand thickness. The updip migration is dependent on a combination of the gravity number and the end point mobility ratio.

  19. Investigating the Effect of Oil Saturation on Acid Propagation during Matrix Acidization of Carbonate Rocks 

    E-Print Network [OSTI]

    Kumar, Rahul Pradeep

    2014-01-02

    , and waterflood residual oil using 15 wt% HCl. The viscosity of the crude oil used was 3.8 cP at 200°F. CAT scans were used to characterize wormholes through the cores. The concentrations of the dissolved calcium and magnesium ions were measured using Inductively...

  20. ORIGINAL PAPER Brassicaceae seed oil identified as illuminant in Nilotic shells

    E-Print Network [OSTI]

    Marinova, Elena

    millennium AD Coptic church in Bawit, Egypt Kerlijne Romanus & Wim Van Neer & Elena Marinova & Kristin of Bawit, Egypt, and supposedly used as oil lamps. The residues were subjected to a combination, as analysed by gas chromatography (GC) in the methylated extract, suggest the presence of a vegetal oil

  1. Multiperiod Refinery Planning Optimization

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    ;7 Example 1: 5 crudes, 4 weeks Produce fuel gas, regular gasoline, premium gasoline, distillate, fuel oil gasoline, distillate, fuel oil and treated residu Optimal solution ($1000's) Profit 3641.3 Sales 33790 seconds (94% NLP, 6% MIP) #12;8 Example 2: 8 crudes, 6 weeks Produce fuel gas, regular gasoline, premium

  2. Eco Oil 4

    SciTech Connect (OSTI)

    Brett Earl; Brenda Clark

    2009-10-26

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  3. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Strathclyde, University of

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  4. Systems and methods for reactive distillation with recirculation of light components

    DOE Patents [OSTI]

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  5. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration

    SciTech Connect (OSTI)

    Zuo, Lin; Benson, Sally M.

    2013-01-01

    A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

  6. Utilization of Estonian oil shale at power plants

    SciTech Connect (OSTI)

    Ots, A. [Tallin Technical Univ. (Estonia). Thermal Engineering Department

    1996-12-31

    Estonian oil shale belongs to the carbonate class and is characterized as a solid fuel with very high mineral matter content (60--70% in dry mass), moderate moisture content (9--12%) and low heating value (LHV 8--10 MJ/kg). Estonian oil shale deposits lie in layers interlacing mineral stratas. The main constituent in mineral stratas is limestone. Organic matter is joined with sandy-clay minerals in shale layers. Estonian oil shale at power plants with total capacity of 3060 MW{sub e} is utilized in pulverized form. Oil shale utilization as fuel, with high calcium oxide and alkali metal content, at power plants is connected with intensive fouling, high temperature corrosion and wear of steam boiler`s heat transfer surfaces. Utilization of Estonian oil shale is also associated with ash residue use in national economy and as absorbent for flue gas desulfurization system.

  7. Processes for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil, and apparatuses for treating biomass-derived pyrolysis oil

    DOE Patents [OSTI]

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-11-24

    Processes and apparatuses for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil are provided herein. An exemplary process for washing a spent ion exchange bed employed in purification of biomass-derived pyrolysis oil includes the step of providing a ion-depleted pyrolysis oil stream having an original oxygen content. The ion-depleted pyrolysis oil stream is partially hydrotreated to reduce the oxygen content thereof, thereby producing a partially hydrotreated pyrolysis oil stream having a residual oxygen content that is less than the original oxygen content. At least a portion of the partially hydrotreated pyrolysis oil stream is passed through the spent ion exchange bed. Water is passed through the spent ion exchange bed after passing at least the portion of the partially hydrotreated pyrolysis oil stream therethrough.

  8. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (Btu) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy Intensity (thousand Btu...

  9. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01

    is described below. Data Crude oil production data is fromproductivity measure is crude oil production per worker, andwhich is measured as crude oil production per worker, is

  10. The Politics of Oil Nationalizations

    E-Print Network [OSTI]

    Mahdavi, Paasha

    2015-01-01

    in the oil and gas sectors . . . . . . . . . . . . . .of regime change, using oil and gas income per capita as aregime change, using fitted oil and gas income per capita as

  11. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01

    Venezuelan Oil Industry Total Wells Drilled and InvestmentWells Drilled and Investment in the Venezuelan Oil Industryopenness of the oil sector to foreign investment contributes

  12. Hybrid Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction

    SciTech Connect (OSTI)

    Eldridge, R. Bruce; Seibert, A. Frank; Robinson, Sharon; Rogers, Jo

    2005-04-01

    This report focuses on improving the existing separations systems for the two largest energy-consuming sectors: the chemicals and petroleum refining industries. It identifies the technical challenges and research needs for improving the efficiency of distillation systems. Areas of growth are also highlighted.

  13. Hydrocracking process with improved distillate selectivity with high silica large pore zeolites

    SciTech Connect (OSTI)

    Partridge, R.D.; LaPierre, R.B.

    1989-04-11

    A process is described for increasing the selectivity of the production of higher boiling distillate range product in hydrocracking reactions which can produce gasoline boiling range product and higher boiling distillate range product, which process comprises: contacting a feedstock to be hydrocracked in a hydrocracking, in the presence of hydrogen and under hydrocracking conditions, with a catalyst comprising a hydrogenation component and a zeolite which has a porous lattice structure having pores with a dimension greater than 6 Angstroms and a hydrocarbon sorption capacity for hexane of at least 6 percent and has a framework silica:alumina ratio of at least about 50:1, whereby the selectivity of the process for production of the higher boiling distillate range product is preferentially increased, wherein the distillate selectivity is defined by reference to the amounts of the 165/sup 0/C-343/sup 0/C (330 F-650/sup 0/F) fraction and the total 343/sup 0/C-fraction in the hydrocracker effluent.

  14. Evaluation of Intake Limiting Agents in a Self-fed Dried Distillers' Supplement 

    E-Print Network [OSTI]

    Sugg, Joel D

    2013-08-14

    Response to range supplementation is in part driven by level of supplement consumed and amount of associated variation. In order to evaluate intake limiting agents in a self-fed dried distillers’ grain supplement (DDG), heifers (n=59) in Trial 1...

  15. Hybrid magic state distillation for universal fault-tolerant quantum computation

    E-Print Network [OSTI]

    Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

    2014-12-11

    A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

  16. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E hydrogen gas (so- called protium) must be used. It is necessary to avoid transfers of - to impurities imposes strict and critical requirements on the hydrogen gas system supporting the detector. Desirable

  17. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process, Dhahran, 31261, Saudi Arabia Abstract This paper studies the synthesis and the design of methanol recovery that methanol could be recovered completely from the hydrocarbon when 5 equilibrium trays in the extraction

  18. Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column Edward the column . We have previously shown (Jimenez et al. 2003) that optimaloperation of serial heat exchangers total heat exchanger area in different trays and calculate the optimal allocation of a given heat

  19. Black-Box Identification for PLC based MPC of a Binary Distillation Column

    E-Print Network [OSTI]

    Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

  20. Report to Congress on the feasibility of establishing a heating oil component to the Strategic Petroleum Reserve. Volume 2: Appendices

    SciTech Connect (OSTI)

    1998-06-01

    Nine appendices to the main report are included in this volume. They are: Northeastern US distillate supply systems; New England fuel oil storage capacities and inventories; Characteristics of the northeast natural gas market; Documentation of statistical models and calculation of benefits; Regional product reserve study; Other countries` experience with refined product storage; Global refining supply demand appraisal; Summary of federal authorities relevant to the establishment of petroleum product reserves; Product stability and turnover requirements.

  1. Spot-Oiling Johnsongrass. 

    E-Print Network [OSTI]

    Elliott, Fred C.; Norris, M. J.; Rea, H. E.

    1955-01-01

    -treat Johnsongrass in cotton in 19 54. Power-driven sprayers normally used for in- tect control in row crops were modified for Yose. A spray pressure of 12 pounds re inch was used. Two systems of the grass were tried. In one system the crenr applying the oil... crown-oilings with naphtha, 83 percent in 7 tests by 3 oil- ings, 95 percent in 6 tests by 4 oilings and 98 percent in 4 tests by 5 to 7 oilings. The use of mixtures of 50 percent naphtha and 50 per- cent kerosene or diesel fuel oil reduced...

  2. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  3. The examination of residual plots

    E-Print Network [OSTI]

    Tsai, Chih-Ling; Cai, Zongwu; Wu, Xizhi

    1998-01-01

    , then equations (14) and (18) indicate that the plot of eˆ(i) (or eˆi) versus yˆi might not reveal a nonlinear pattern even though the true mean function includes the nonlinear component, g(Z). Cook’s Example 7.1 (1994) illustrates this point. In practice...), Examples 7.1 and 7.2) has shown that this type of plot may provide misleading information when fitted values are used, we therefore suggest using the linear residual plot (residuals versus explanatory variables case) for the detection of nonlinearity...

  4. China's Global Oil Strategy

    E-Print Network [OSTI]

    Thomas, Bryan G

    2009-01-01

    21, 2008. Ying, Wang. “ China, Venezuela firms to co-developApril 21, “China and Venezuela sign oil agreements. ” Chinaaccessed April 21, “Venezuela and China sign oil deal. ” BBC

  5. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    an alternative investment strategy to buying oil today andinvestments necessary to catch up. This was the view o?ered by oilinvestment strategy. date t) in order to purchase a quantity Q barrels of oil

  6. Report to Congress on the feasibility of establishing a heating oil component to the Strategic Petroleum Reserve. Volume 1

    SciTech Connect (OSTI)

    1998-06-01

    In the Autumn of 1996, consumers and Members of Congress from the Northeast expressed concern about high prices for heating oil and historically low levels of inventories. Some Members of Congress advocated building a Federal inventory of heating oil as part of the Strategic Petroleum Reserve (SPR). Regional reserves are authorized as part of the SPR for import dependent regions by the Energy Policy and Conservation Act. In response, the Department of Energy (DOE) proposed a series of studies related to heating fuels, including a study of the desirability, feasibility, and cost of creating a Federal reserve containing distillate fuel. This report documents that study.

  7. Chemical Methods for Ugnu Viscous Oils

    SciTech Connect (OSTI)

    Kishore Mohanty

    2012-03-31

    The North Slope of Alaska has large (about 20 billion barrels) deposits of viscous oil in Ugnu, West Sak and Shraeder Bluff reservoirs. These shallow reservoirs overlie existing productive reservoirs such as Kuparuk and Milne Point. The viscosity of the Ugnu reservoir on top of Milne Point varies from 200 cp to 10,000 cp and the depth is about 3300 ft. The same reservoir extends to the west on the top of the Kuparuk River Unit and onto the Beaufort Sea. The depth of the reservoir decreases and the viscosity increases towards the west. Currently, the operators are testing cold heavy oil production with sand (CHOPS) in Ugnu, but oil recovery is expected to be low (< 10%). Improved oil recovery techniques must be developed for these reservoirs. The proximity to the permafrost is an issue for thermal methods; thus nonthermal methods must be considered. The objective of this project is to develop chemical methods for the Ugnu reservoir on the top of Milne Point. An alkaline-surfactant-polymer (ASP) formulation was developed for a viscous oil (330 cp) where as an alkaline-surfactant formulation was developed for a heavy oil (10,000 cp). These formulations were tested in one-dimensional and quarter five-spot Ugnu sand packs. Micromodel studies were conducted to determine the mechanisms of high viscosity ratio displacements. Laboratory displacements were modeled and transport parameters (such as relative permeability) were determined that can be used in reservoir simulations. Ugnu oil is suitable for chemical flooding because it is biodegraded and contains some organic acids. The acids react with injected alkali to produce soap. This soap helps in lowering interfacial tension between water and oil which in turn helps in the formation of macro and micro emulsions. A lower amount of synthetic surfactant is needed because of the presence of organic acids in the oil. Tertiary ASP flooding is very effective for the 330 cp viscous oil in 1D sand pack. This chemical formulation includes 1.5% of an alkali, 0.4% of a nonionic surfactant, and 0.48% of a polymer. The secondary waterflood in a 1D sand pack had a cumulative recovery of 0.61 PV in about 3 PV injection. The residual oil saturation to waterflood was 0.26. Injection of tertiary alkaline-surfactant-polymer slug followed by tapered polymer slugs could recover almost 100% of the remaining oil. The tertiary alkali-surfactant-polymer flood of the 330 cp oil is stable in three-dimensions; it was verified by a flood in a transparent 5-spot model. A secondary polymer flood is also effective for the 330 cp viscous oil in 1D sand pack. The secondary polymer flood recovered about 0.78 PV of oil in about 1 PV injection. The remaining oil saturation was 0.09. The pressure drops were reasonable (<2 psi/ft) and depended mainly on the viscosity of the polymer slug injected. For the heavy crude oil (of viscosity 10,000 cp), low viscosity (10-100 cp) oil-in-water emulsions can be obtained at salinity up to 20,000 ppm by using a hydrophilic surfactant along with an alkali at a high water-to-oil ratio of 9:1. Very dilute surfactant concentrations (~0.1 wt%) of the synthetic surfactant are required to generate the emulsions. It is much easier to flow the low viscosity emulsion than the original oil of viscosity 10,000 cp. Decreasing the WOR reverses the type of emulsion to water-in-oil type. For a low salinity of 0 ppm NaCl, the emulsion remained O/W even when the WOR was decreased. Hence a low salinity injection water is preferred if an oil-in-water emulsion is to be formed. Secondary waterflood of the 10,000 cp heavy oil followed by tertiary injection of alkaline-surfactants is very effective. Waterflood has early water breakthrough, but recovers a substantial amount of oil beyond breakthrough. Waterflood recovers 20-37% PV of the oil in 1D sand pack in about 3 PV injection. Tertiary alkali-surfactant injection increases the heavy oil recovery to 50-70% PV in 1D sand packs. As the salinity increased, the oil recovery due to alkaline surfactant flood increased, but water-in-oil emulsion was p

  8. Vegetable oils for tractors

    SciTech Connect (OSTI)

    Moroney, M.

    1981-11-14

    Preliminary tests by the Agricultural Institute, show that tractors can be run on a 50:50 rape oil-diesel mixture or on pure rape oil. In fact, engine power actually increased slightly with the 50:50 blend but decreased fractionally with pure rape oil. Research at the North Dakota State University on using sunflower oil as an alternative to diesel fuel is also noted.

  9. Enhanced Oil Recovery of Viscous Oil by Injection of Water-in-Oil Emulsion Made with Used Engine Oil 

    E-Print Network [OSTI]

    Fu, Xuebing

    2012-08-20

    Solids-stabilized water-in-oil emulsions have been suggested as a drive fluid to recover viscous oil through a piston-like displacement pattern. While crude heavy oil was initially suggested as the base oil, an alternative oil ? used engine oil...

  10. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  11. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  12. Oil Quantity : The histori

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    120 140 160 19 Oil Quantity Con Wel N E A N N ng Results e Bay : The histori Bay over tim : Prudhoe Ba returns plan n in percent m 0% to 300% 968 1973 Oil Productio Productio 5000600 4000500 3000400 2000300 model for Prudhoe Bay. Figure 11: Historical Prudhoe Bay oil production data, modeled economically

  13. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing in organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed.

  14. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  15. Oil spill response resources 

    E-Print Network [OSTI]

    Muthukrishnan, Shankar

    1996-01-01

    source in an effective manner. Oil spills are fast becoming pollution sources that are causing the maximum damage to the environment. This is owing to the compounds that are released and the way oil spreads in both water and land. Preventing the oil spill...

  16. Oil and Gas Exploration

    E-Print Network [OSTI]

    Tingley, Joseph V.

    , oil and gas, and geothermal activities and accomplishments in Nevada: production statistics Products 23. Sloan dolomite quarry 24. Weiser gypsum quarry Oil Fields 1. Blackburn field 2. North WillowMetals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada

  17. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  18. Isolation of levoglucosan from pyrolysis oil derived from cellulose

    DOE Patents [OSTI]

    Moens, L.

    1994-12-06

    High purity levoglucosan is obtained from pyrolysis oil derived from cellulose by: mixing pyrolysis oil with water and a basic metal hydroxide, oxide, or salt in amount sufficient to elevate pH values to a range of from about 12 to about 12.5, and adding an amount of the hydroxide, oxide, or salt in excess of the amount needed to obtain the pH range until colored materials of impurities from the oil are removed and a slurry is formed; drying the slurry azeotropically with methyl isobutyl ketone solvent to form a residue, and further drying the residue by evaporation; reducing the residue into a powder; continuously extracting the powder residue with ethyl acetate to provide a levoglucosan-rich extract; and concentrating the extract by removing ethyl acetate to provide crystalline levoglucosan. Preferably, Ca(OH)[sub 2] is added to adjust the pH to the elevated values, and then Ca(OH)[sub 2] is added in an excess amount needed. 3 figures.

  19. Isolation of levoglucosan from pyrolysis oil derived from cellulose

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    1994-01-01

    High purity levoglucosan is obtained from pyrolysis oil derived from cellulose by: mixing pyrolysis oil with water and a basic metal hydroxide, oxide, or salt in amount sufficient to elevate pH values to a range of from about 12 to about 12.5, and adding an amount of the hydroxide, oxide, or salt in excess of the amount needed to obtain the pH range until colored materials of impurities from the oil are removed and a slurry is formed; drying the slurry azeotropically with methyl isobutyl ketone solvent to form a residue, and further drying the residue by evaporation; reducing the residue into a powder; continuously extracting the powder residue with ethyl acetate to provide a levoglucosan-rich extract; and concentrating the extract by removing ethyl acetate to provide crystalline levoglucosan. Preferably, Ca(OH).sub.2 is added to adjust the pH to the elevated values, and then Ca(OH).sub.2 is added in an excess amount needed.

  20. Evaluation of residue drum storage safety risks

    SciTech Connect (OSTI)

    Conner, W.V.

    1994-06-17

    A study was conducted to determine if any potential safety problems exist in the residue drum backlog at the Rocky Flats Plant. Plutonium residues stored in 55-gallon drums were packaged for short-term storage until the residues could be processed for plutonium recovery. These residues have now been determined by the Department of Energy to be waste materials, and the residues will remain in storage until plans for disposal of the material can be developed. The packaging configurations which were safe for short-term storage may not be safe for long-term storage. Interviews with Rocky Flats personnel involved with packaging the residues reveal that more than one packaging configuration was used for some of the residues. A tabulation of packaging configurations was developed based on the information obtained from the interviews. A number of potential safety problems were identified during this study, including hydrogen generation from some residues and residue packaging materials, contamination containment loss, metal residue packaging container corrosion, and pyrophoric plutonium compound formation. Risk factors were developed for evaluating the risk potential of the various residue categories, and the residues in storage at Rocky Flats were ranked by risk potential. Preliminary drum head space gas sampling studies have demonstrated the potential for formation of flammable hydrogen-oxygen mixtures in some residue drums.

  1. Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers 

    E-Print Network [OSTI]

    Nelson, R. E.

    1982-01-01

    The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

  2. Transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kam??l?, Fatih

    2010-01-01

    Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

  3. Residue management at Rocky Flats

    SciTech Connect (OSTI)

    Olencz, J.

    1995-12-31

    Past plutonium production and manufacturing operations conducted at the Rocky Flats Environmental Technology Site (RFETS) produced a variety of plutonium-contaminated by-product materials. Residues are a category of these materials and were categorized as {open_quotes}materials in-process{close_quotes} to be recovered due to their inherent plutonium concentrations. In 1989 all RFETS plutonium production and manufacturing operations were curtailed. This report describes the management of plutonium bearing liquid and solid wastes.

  4. Vitrification of NAC process residue

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D. [Pacific Northwest Lab., Richland, WA (United States)

    1995-12-31

    Vitrification tests have been performed with simulated waste compositions formulated to represent the residue which would be obtained from the treatment of low-level, nitrate wastes from Hanford and Oak Ridge by the nitrate to ammonia and ceramic (NAC) process. The tests were designed to demonstrate the feasibility of vitrifying NAC residue and to quantify the impact of the NAC process on the volume of vitrified waste. The residue from NAC treatment of low-level nitrate wastes consists primarily of oxides of aluminum and sodium. High alumina glasses were formulated to maximize the waste loading of the NAC product. Transparent glasses with up to 35 wt% alumina, and even higher contents in opaque glasses, were obtained at melting temperatures of 1,200 C to 1,400 C. A modified TCLP leach test showed the high alumina glasses to have good chemical durability, leaching significantly less than either the ARM-1 or the DWPF-EA high-level waste reference glasses. A significant increase in the final waste volume would be a major result of the NAC process on LLW vitrification. For Hanford wastes, NAC-treatment of nitrate wastes followed by vitrification of the residue will increase the final volume of vitrified waste by 50% to 90%; for Melton Valley waste from Oak Ridge, the increase in final glass volume will be 260% to 280%. The increase in volume is relative to direct vitrification of the waste in a 20 wt% Na{sub 2}O glass formulation. The increase in waste volume directly affects not only disposal costs, but also operating and/or capital costs. Larger plant size, longer operating time, and additional energy and additive costs are direct results of increases in waste volume. Such increases may be balanced by beneficial impacts on the vitrification process; however, those effects are outside the scope of this report.

  5. Vitrification of NAC process residue

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D.

    1995-09-01

    Vitrification tests have been performed with simulated waste compositions formulated to represent the residue which would be obtained from the treatment of low-level, nitrate wastes from Hanford and Oak Ridge by the nitrate to ammonia and ceramic (NAC) process. The tests were designed to demonstrate the feasibility of vitrifying NAC residue and to quantify the impact of the NAC process on the volume of vitrified waste. The residue from NAC treatment of low-level nitrate wastes consists primarily of oxides of aluminum and sodium. High alumina glasses were formulated to maximize the waste loading of the NAC product. Transparent glasses with up to 35 wt% alumina, and even higher contents in opaque glasses, were obtained at melting temperatures of 1200{degrees}C to 1400{degrees}C. A modified TCLP leach test showed the high alumina glasses to have good chemical durability, leaching significantly less than either the ARM-1 or the DWPF-EA high-level waste reference glasses. A significant increase in the final waste volume would be a major result of the NAC process on LLW vitrification. For Hanford wastes, NAC-treatment of nitrate wastes followed by vitrification of the residue will increase the final volume of vitrified waste by 50% to 90%; for Melton Valley waste from Oak Ridge, the increase in final glass volume will be 260% to 280%. The increase in volume is relative to direct vitrification of the waste in a 20 wt% Na{sub 2}O glass formulation. The increase in waste volume directly affects not only disposal costs, but also operating and/or capital costs. Larger plant size, longer operating time, and additional energy and additive costs are direct results of increases in waste volume. Such increases may be balanced by beneficial impacts on the vitrification process; however, those effects are outside the scope of this report.

  6. Composition-explicit distillation curves of aviation fuel JP-8 and a coal-based jet fuel

    SciTech Connect (OSTI)

    Beverly L. Smith; Thomas J. Bruno [National Institute of Standards and Technology, Boulder, CO (United States). Physical and Chemical Properties Division

    2007-09-15

    We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications to the classical measurement provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements that are true thermodynamic state points; (3) temperature, volume, and pressure measurements of low uncertainty suitable for an equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; (6) a trace chemical analysis of each distillate fraction; and (7) a corrosivity assessment of each distillate fraction. The most significant modification is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to the measurement of rocket propellant, gasoline, and jet fuels. In this paper, we present the application of the technique to representative batches of the military aviation fuel JP-8, and also to a coal-derived fuel developed as a potential substitute. We present not only the distillation curves but also a chemical characterization of each fraction and discuss the contrasts between the two fluids. 26 refs., 5 figs., 6 tabs.

  7. REVIEW PAPER Biodeterioration of crude oil and oil derived

    E-Print Network [OSTI]

    Appanna, Vasu

    REVIEW PAPER Biodeterioration of crude oil and oil derived products: a review Natalia A. Yemashova January 2007 Ó Springer Science+Business Media B.V. 2007 Abstract Biodeterioration of crude oil and oil of operational problems. Nowadays various test-systems are utilized for microbial monitoring in crude oils

  8. Crude Oil Analysis Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  9. Dependence of waterflood remaining oil saturation on relative permeability, capillary pressure, and reservoir parameters in mixed-wet turbidite sands

    SciTech Connect (OSTI)

    Hirasaki, G.J.

    1996-05-01

    The dependence of waterflood oil recovery on relative permeability, capillary pressure, and reservoir parameters was investigated by numerical simulation. The relative permeability and capillary pressure curves were based on laboratory measurements on unconsolidated sands. The water-wet case is based on the assumption that the system is water-wet and measurements were made with refined oil. The mixed-wet case assumed that the system is mixed-wet and restored-state measurements were made with crude oil. The reservoir model was a prototype turbidite sand with a range of thickness and permeability values. The economic oil recovery was based on an economic limit water cut of 50%. The remaining oil saturation (ROS) in the swept region for the water-wet cases was close to the residual oil saturation. The ROS of the mixed-wet cases ranged from low values near the residual oil saturation to far above the residual oil saturation. It is dependent on the reservoir parameters that govern (1) the vertical film surface drainage of oil by gravity, (2) accumulation of a high oil saturation and thus a high relative permeability under the caprock, and (3) up-dip migration of the oil that accumulated under the caprock. The dependence on the reservoir parameters can be summarized by dimensionless groups. There is a dimensionless time for the vertical displacement of oil by gravity. The accumulation of a high oil saturation under the caprock is dependent on the ratio of the capillary transition zone and the sand thickness. The updip migration is dependent on a combination of the gravity number and the endpoint mobility ratio.

  10. Proposed plant will turn wood residues into synfuel

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    A group of entrepreneurs plan to have a plant operating in Burney, CA. The projected facility will produce an estimated 21,000 gallons of oil per day, converting about 300 tons of raw material. Converting cellulose into synthetic fuel is superior to alcohol production. The process yields approximately 84 gallons of synthetic fuel per ton of raw material. The entire LHG (liquid hydrogen gas) patented facility is self-sufficient and releases only carbon dioxide into the atmosphere. Synfuel production is a three-phase process. First, butyl alcohol (butanol) and acetone are produced from a portion of the raw material. This is facilitated by adding to the raw material a bacteria culture. The planned facility in Burney will have thirty-five 2100 gallon fermentation tanks and will produce 1.25 million gallons of butanol. Next, organic material is blended with water and is pumped into patented LHG catalytic converters, charged with carbon monoxide gas as a catalyst and then heated to 350 degrees C at 2000 to 5000 psi. Here, the organic material is converted to No. 4 oil with bituminous tar as a residue. A patented gasifier system produces the carbon monoxide catalyst plus COH (carbon hydroxide) gas. The COH is used to power a gas turbine driving a 100 kW generator and a central hydraulic pump. The facility, which will be energy self-sufficient, will have approximately 50 kW of excess power to sell to the local utility power grid. Finally, the No. 4 oil, butanol and liquified COH gas are blended to produce any grade fuel oil or a gasoline substitute of very high octane.

  11. World Oil: Market or Mayhem?

    E-Print Network [OSTI]

    Smith, James L.

    2008-01-01

    The world oil market is regarded by many as a puzzle. Why are oil prices so volatile? What is OPEC and what does OPEC do? Where are oil prices headed in the long run? Is “peak oil” a genuine concern? Why did oil prices ...

  12. Preparation of brightness stabilization agent for lignin containing pulp from biomass pyrolysis oils

    DOE Patents [OSTI]

    Agblevor, Foster A. (Blacksburg, VA); Besler-Guran, Serpil (Flemington, NJ)

    2001-01-01

    A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous layer with ethyl acetate, and discarding the ethyl acetate fraction to obtain a brown-colored solution not susceptible to gelling or solidification upon heating; i) heating the solution to distill off water and other light components and concentrating a bottoms fraction comprising hydroxyacetaldehyde and other non-volatile components having high boiling points; and j) decolorizing the stabilized brown solution with activated carbon to obtain a colorless solution.

  13. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    disruptions, and the peak in U.S. oil production account foroil increased 81.1% (logarithmically) between January 1979 and the peak

  14. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 2001 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II (Continued) PAD District...

  15. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 2000 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II (Continued) PAD District...

  16. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II (Continued) PAD District...

  17. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1998 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II (Continued) PAD District...

  18. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 2002 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II (Continued) PAD District...

  19. Thermally-enhanced oil recovery method and apparatus

    DOE Patents [OSTI]

    Stahl, Charles R. (Scotia, NY); Gibson, Michael A. (Houston, TX); Knudsen, Christian W. (Houston, TX)

    1987-01-01

    A thermally-enhanced oil recovery method and apparatus for exploiting deep well reservoirs utilizes electric downhole steam generators to provide supplemental heat to generate high quality steam from hot pressurized water which is heated at the surface. A downhole electric heater placed within a well bore for local heating of the pressurized liquid water into steam is powered by electricity from the above-ground gas turbine-driven electric generators fueled by any clean fuel such as natural gas, distillate or some crude oils, or may come from the field being stimulated. Heat recovered from the turbine exhaust is used to provide the hot pressurized water. Electrical power may be cogenerated and sold to an electric utility to provide immediate cash flow and improved economics. During the cogeneration period (no electrical power to some or all of the downhole units), the oil field can continue to be stimulated by injecting hot pressurized water, which will flash into lower quality steam at reservoir conditions. The heater includes electrical heating elements supplied with three-phase alternating current or direct current. The injection fluid flows through the heater elements to generate high quality steam to exit at the bottom of the heater assembly into the reservoir. The injection tube is closed at the bottom and has radial orifices for expanding the injection fluid to reservoir pressure.

  20. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J. (Chicago, IL); Daniels, Edward J. (Oak Lawn, IL); Bonsignore, Patrick V. (Channahon, IL)

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  1. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Energy Savers [EERE]

    Home Heating Oil Reserve System (Heating Oil) More Documents & Publications PIA - WEB Physical Security Major Application PIA - GovTrip (DOE data) PIA - WEB Unclassified...

  2. Oil Shale and Oil Sands Development Robert Keiter; John Ruple...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Robert Keiter; John Ruple; Heather Tanana; Rebecca Holt 29 ENERGY...

  3. The Politics of Oil Nationalizations

    E-Print Network [OSTI]

    Mahdavi, Paasha

    2015-01-01

    model specifications Oil production in the 1930-1950 period,NOCs by type, 1947-2005 . . Oil production, before and afterThe Political Economy of Oil Production in Latin America. ”

  4. The Politics of Oil Nationalizations

    E-Print Network [OSTI]

    Mahdavi, Paasha

    2015-01-01

    revenues (adjusted for real oil price) before and after es-to the volatility of oil prices – and thus the volatility ofSonin (2011) shows that oil prices and executive constraints

  5. The Politics of Oil Nationalizations

    E-Print Network [OSTI]

    Mahdavi, Paasha

    2015-01-01

    assessment of political and economic factors of oilAssessment of PEMEX’s Performance and Strategy. In Oil andOil Company resembled more of a regulator NOC). I will combine this assessment

  6. The Politics of Oil Nationalizations

    E-Print Network [OSTI]

    Mahdavi, Paasha

    2015-01-01

    Markus Br¨ uckner. 2012. “Oil Rents, Corruption, and Statewithin-country variance in oil rents and their effects onshift in the capture of oil rents – but I show why more work

  7. The Legacy of Oil Spills

    E-Print Network [OSTI]

    Trevors, J. T.; Saier, M. H.

    2010-01-01

    010-0527-5 The Legacy of Oil Spills J. T. Trevors & M. H.workers were killed, and oil has been gushing out everday. It is now June, and oil continues to spew forth into

  8. Determination of oil/water and octanol/water distribution coefficients from aqueous solutions from four fossil fuels. [MS thesis; in oil-water and octanol-water

    SciTech Connect (OSTI)

    Thomas, B.L.

    1984-07-01

    Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.

  9. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  10. RESIDUAL STRESSES IN 3013 CONTAINERS

    SciTech Connect (OSTI)

    Mickalonis, J.; Dunn, K.

    2009-11-10

    The DOE Complex is packaging plutonium-bearing materials for storage and eventual disposition or disposal. The materials are handled according to the DOE-STD-3013 which outlines general requirements for stabilization, packaging and long-term storage. The storage vessels for the plutonium-bearing materials are termed 3013 containers. Stress corrosion cracking has been identified as a potential container degradation mode and this work determined that the residual stresses in the containers are sufficient to support such cracking. Sections of the 3013 outer, inner, and convenience containers, in both the as-fabricated condition and the closure welded condition, were evaluated per ASTM standard G-36. The standard requires exposure to a boiling magnesium chloride solution, which is an aggressive testing solution. Tests in a less aggressive 40% calcium chloride solution were also conducted. These tests were used to reveal the relative stress corrosion cracking susceptibility of the as fabricated 3013 containers. Significant cracking was observed in all containers in areas near welds and transitions in the container diameter. Stress corrosion cracks developed in both the lid and the body of gas tungsten arc welded and laser closure welded containers. The development of stress corrosion cracks in the as-fabricated and in the closure welded container samples demonstrates that the residual stresses in the 3013 containers are sufficient to support stress corrosion cracking if the environmental conditions inside the containers do not preclude the cracking process.

  11. Vacuum Distillation

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of theCubicEstimation ResultsYear JanYearDay) Process: Vacuum

  12. Balancing oil and environment... responsibly.

    SciTech Connect (OSTI)

    Weimer, Walter C.; Teske, Lisa

    2007-01-25

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  13. Oil & Gas Science and Technology

    E-Print Network [OSTI]

    F. DAÏM

    2002-11-12

    update of the mechanical displacement and porosity field. In ... water and oil pressures are equal. ... o or w, denote the cell values of the oil and water phase.

  14. Essays on Macroeconomics and Oil

    E-Print Network [OSTI]

    CAKIR, NIDA

    2013-01-01

    Oil Production in Venezuela and Mexico . . . . . . . . . .and Productivity in Venezuela and Mexico . . . . . . . . OilEllner, ”Organized Labor in Venezuela 1958-1991: Behavior

  15. Synthesis of zeolite from Italian coal fly ash: Differences in crystallization temperature using seawater instead of distilled water

    SciTech Connect (OSTI)

    Belviso, Claudia; Cavalcante, Francesco; Fiore, Saverio

    2010-05-15

    In this study Italian coal fly ash was converted into several types of zeolite in laboratory experiments with temperatures of crystallization ranging from 35 up to 90 deg. C. Distilled and seawater were used during the hydrothermal synthesis process in separate experiments, after a pre-treatment fusion with NaOH. The results indicate that zeolites could be formed from different kind of Italian coal fly ash at low temperature of crystallization using both distilled and seawater. SEM data and the powder patterns of X-ray diffraction analysis show that faujasite, zeolite ZK-5 and sodalite were synthesized when using both distilled and seawater; zeolite A crystallized only using distilled water. In particular the experiments indicate that the synthesis of zeolite X and zeolite ZK-5 takes place at lower temperatures when using seawater (35 and 45 deg. C, respectively). The formation of sodalite is always competitive with zeolite X which shows a metastable behaviour at higher temperatures (70-90 deg. C). The chemical composition of the fly ash source could be responsible of the differences on the starting time of synthesized zeolite with distilled water, in any case our data show that the formation of specific zeolites takes place always at lower temperatures when using seawater.

  16. Heavy oil hydroprocessing

    SciTech Connect (OSTI)

    Pratt, R.E.; Nongbri, G.; Clausen, G.A. [Texaco R& D, Port Arthur, TX (United States)] [and others

    1995-12-31

    Many of the crude oils available worldwide are classified as heavy oils (API gravity less than 20). In addition, many of the heavier crude oils are also high in sulfur content. Both the low gravity and high sulfur content make these crude oils difficult to process in many refineries and additional processing equipment is required. Often, deasphalting of the vacuum residuum is one of the processing routes chosen. However, the deasphalted oil (DAO) is often of poor quality and presents problems in processing in existing refinery units. Fixed bed hydrotreater and hydrocracker catalysts are quickly fouled and fluid catalytic cracking units (FCCU) reach regenerator temperature limits with only small amounts of DAO in the feed. Use of the T-STAR ebullated bed process to hydrocrack and upgrade the DAO is an excellent route for making the DAO more palatable to refinery units.

  17. Org. Synth. 2006, 83, 121-130 121 Published on the Web 9/11/06

    E-Print Network [OSTI]

    Denmark, Scott

    with 14 x 8 Watt low pressure Hg lamps (254 nm). The reaction mixture is heated to reflux with a heating to a single nitrogen source leading to an oil bubbler. The flask is placed in a Rayonet Photoreactor fitted are removed by distillation at atmospheric pressure (Note 3). The residue is distilled to provide 67.6 g (50

  18. Corrosivity Of Pyrolysis Oils

    SciTech Connect (OSTI)

    Keiser, James R; Bestor, Michael A; Lewis Sr, Samuel Arthur; Storey, John Morse

    2011-01-01

    Pyrolysis oils from several sources have been analyzed and used in corrosion studies which have consisted of exposing corrosion coupons and stress corrosion cracking U-bend samples. The chemical analyses have identified the carboxylic acid compounds as well as the other organic components which are primarily aromatic hydrocarbons. The corrosion studies have shown that raw pyrolysis oil is very corrosive to carbon steel and other alloys with relatively low chromium content. Stress corrosion cracking samples of carbon steel and several low alloy steels developed through-wall cracks after a few hundred hours of exposure at 50 C. Thermochemical processing of biomass can produce solid, liquid and/or gaseous products depending on the temperature and exposure time used for processing. The liquid product, known as pyrolysis oil or bio-oil, as produced contains a significant amount of oxygen, primarily as components of water, carboxylic acids, phenols, ketones and aldehydes. As a result of these constituents, these oils are generally quite acidic with a Total Acid Number (TAN) that can be around 100. Because of this acidity, bio-oil is reported to be corrosive to many common structural materials. Despite this corrosive nature, these oils have the potential to replace some imported petroleum. If the more acidic components can be removed from this bio-oil, it is expected that the oil could be blended with crude oil and then processed in existing petroleum refineries. The refinery products could be transported using customary routes - pipelines, barges, tanker trucks and rail cars - without a need for modification of existing hardware or construction of new infrastructure components - a feature not shared by ethanol.

  19. Oil shale ash-layer thickness and char combustion kinetics

    SciTech Connect (OSTI)

    Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

    1992-04-15

    A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

  20. BIOMASS TO BIO-OIL BY LIQUEFACTION

    SciTech Connect (OSTI)

    Wang, Huamin; Wang, Yong

    2013-01-10

    Significant efforts have been devoted to develop processes for the conversion of biomass, an abundant and sustainable source of energy, to liquid fuels and chemicals, in order to replace diminishing fossil fuels and mitigate global warming. Thermochemical and biochemical methods have attracted the most attention. Among the thermochemical processes, pyrolysis and liquefaction are the two major technologies for the direct conversion of biomass to produce a liquid product, often called bio-oil. This chapter focuses on the liquefaction, a medium-temperature and high-pressure thermochemical process for the conversion of biomass to bio-oil. Water has been most commonly used as a solvent and the process is known as hydrothermal liquefaction (HTL). Fundamentals of HTL process, key factors determining HTL behavior, role of catalyst in HTL, properties of produced bio-oil, and the current status of the technology are summarized. The liquefaction of biomass by using organic solvents, a process called solvolysis, is also discussed. A wide range of biomass feedstocks have been tested for liquefaction including wood, crop residues, algae, food processing waste, and animal manure.

  1. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  2. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  3. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01

    htm ENVIRONMENTAL AND SOCIAL IMPACTS OF OIL Dutch Shell andAnalysis ENVIRONMENTAL AND SOCIAL IMPACTS OF OIL Briefs:ENVIRONMENTAL AND SOCIAL IMPACTS OF OIL Oil obviously

  4. An informal description of Standard OIL and Instance OIL

    E-Print Network [OSTI]

    Murawski, Andrzej

    An informal description of Standard OIL and Instance OIL 28 November 2000 Sean Bechhofer (1) Jeen to be specified in some language. This paper introduces the newest version of OIL ­ the ontology inference layer of the DAML language, with working name DAML-OIL, was proposed in a message to the rdf-logic mailing list

  5. European Market Study for BioOil (Pyrolysis Oil)

    E-Print Network [OSTI]

    European Market Study for BioOil (Pyrolysis Oil) Dec 15, 2006 Doug Bradley President Climate Change of Contents Scope Executive Summary 1. Background 2. Pyrolysis Oil-Char Supply and Export Potential 2 Competitiveness 3.1. Substitute Fuels 3.2. Price of Fossil Fuels 3.3. Delivered Costs of Pyrolysis Oil/Char 4

  6. Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles

    SciTech Connect (OSTI)

    Haihua Zhao; Per F. Peterson

    2012-10-01

    Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

  7. FCC Tail Gas olefins conversion to gasoline via catalytic distillation with aromatics

    SciTech Connect (OSTI)

    Partin, E.E. (Brown and Root U.S.A., Inc., Houston, TX (US))

    1988-01-01

    The goal of every refiner is to continually improve profitability by such means as increasing gasoline production, increasing gasoline octane pool and in cases where fuel balance becomes a problem, decreasing refinery fuel gas production. A new refinery process is currently being developed which accomplish these goals. Chemical Research and Licensing Company (CR and L) developed Catalytic Distillation technology in 1978 to produce MTBE. They have since used the Catalytic Distillation technique to produce cumene. CR and L has further developed this technology to convert olefin gases currently consumed as refinery fuel, to high octane gasoline components. The process, known as CATSTILL, alkylates olefin gases such as ethylene, propylene and butylene, present in FCC Tail Gas with light aromatics such as benzene, toluene and xylene, present in reformate, to produce additional quantities of high octane gasoline components. A portable CATSTILL demonstration plant has been constructed by Brown and Root U.S.A., under an agreement with CR and L, for placement in a refinery to further develop data necessary to design commercial plants. This paper presents current data relative to the CATSTILL development.

  8. Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry

    E-Print Network [OSTI]

    Colin J. Trout; Kenneth R. Brown

    2015-01-29

    Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

  9. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  10. Petroleum marketing monthly with data for October 1996

    SciTech Connect (OSTI)

    NONE

    1997-01-01

    This publication presents statistical data on crude oil costs and refined petroleum products sales. Data on petroleum include the domestic first purchase price, landed cost of imported crude oil, and the refiner`s acquisition cost of crude oil. Sales data include motor gasoline, distillates, residuals, aviation fuels, kerosene, and propane.

  11. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro; Passarini, Fabrizio; Vassura, Ivano; Serrano, David; Dufour, Javier

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  12. A Benchmark Study on Casting Residual Stress

    SciTech Connect (OSTI)

    Johnson, Eric M. [John Deere -- Moline Tech Center; Watkins, Thomas R [ORNL; Schmidlin, Joshua E [ORNL; Dutler, S. A. [MAGMA Foundry Technologies, Inc.

    2012-01-01

    Stringent regulatory requirements, such as Tier IV norms, have pushed the cast iron for automotive applications to its limit. The castings need to be designed with closer tolerances by incorporating hitherto unknowns, such as residual stresses arising due to thermal gradients, phase and microstructural changes during solidification phenomenon. Residual stresses were earlier neglected in the casting designs by incorporating large factors of safety. Experimental measurement of residual stress in a casting through neutron or X-ray diffraction, sectioning or hole drilling, magnetic, electric or photoelastic measurements is very difficult and time consuming exercise. A detailed multi-physics model, incorporating thermo-mechanical and phase transformation phenomenon, provides an attractive alternative to assess the residual stresses generated during casting. However, before relying on the simulation methodology, it is important to rigorously validate the prediction capability by comparing it to experimental measurements. In the present work, a benchmark study was undertaken for casting residual stress measurements through neutron diffraction, which was subsequently used to validate the accuracy of simulation prediction. The stress lattice specimen geometry was designed such that subsequent castings would generate adequate residual stresses during solidification and cooling, without any cracks. The residual stresses in the cast specimen were measured using neutron diffraction. Considering the difficulty in accessing the neutron diffraction facility, these measurements can be considered as benchmark for casting simulation validations. Simulations were performed using the identical specimen geometry and casting conditions for predictions of residual stresses. The simulation predictions were found to agree well with the experimentally measured residual stresses. The experimentally validated model can be subsequently used to predict residual stresses in different cast components. This enables incorporation of the residual stresses at the design phase along with external loads for accurate predictions of fatigue and fracture performance of the cast components.

  13. California: Agricultural Residues Produce Renewable Fuel | Department...

    Office of Environmental Management (EM)

    in America to reduce our dependence on imported oil. Addthis Related Articles The Energy Department's Bioenergy Technologies Office engages with the U.S. Department of...

  14. New Products TACKLING OIL SPILLS

    E-Print Network [OSTI]

    Rock, Chris

    New Products TACKLING OIL SPILLS Low-grade nonwoven cotton Texas Tech University researchers its own weight in oil. The results strengthen the use of cotton as a natural sorbent for oil, said Mr Engineering and Environmental Toxicology. "With the 2010 crude oil spill in the Gulf of Mexico. which resulted

  15. Residual Toxicities of Insecticides to Cotton Insects. 

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01

    -ITHION. The residual toxicity of para- rliioti to the tumid spider mite was not affected by ~i1nul;ttetl rain when the spray was applied at a dosage c.cluiv;~lcnt to 0.3 pound of toxicant per acre. Kill5 or the cotton aphid on spray residues of 1),11;1thion were...

  16. Tank 12H residuals sample analysis report

    SciTech Connect (OSTI)

    Oji, L. N.; Shine, E. P.; Diprete, D. P.; Coleman, C. J.; Hay, M. S.

    2015-06-11

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 12H final characterization samples to determine the residual tank inventory prior to grouting. Eleven Tank 12H floor and mound residual material samples and three cooling coil scrape samples were collected and delivered to SRNL between May and August of 2014.

  17. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation 

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30

    Recent experimental and simulation studies -conducted at the Department of Petroleum Engineering at Texas A&M University - confirm oil production is accelerated when propane is used as an additive during steam injection. To better understand...

  18. A techno-economic and environmental assessment of hydroprocessed renewable distillate fuels

    E-Print Network [OSTI]

    Pearlson, Matthew Noah

    2011-01-01

    This thesis presents a model to quantify the economic costs and environmental impacts of producing fuels from hydroprocessed renewable oils (HRO) process. Aspen Plus was used to model bio-refinery operations and supporting ...

  19. Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni 

    E-Print Network [OSTI]

    Marin-Rosas, Celia

    2009-05-15

    dibenzothiophenes (sDBT) and phenanthrene as well as molar-averaged conversion was evaluated in a continuous flow Robinson Mahoney reactor with stationary basket in the hydrodesulfurization and hydrogenation of heavy gas oil which contains sulphur refractory...

  20. Effects of Ruminally Degradable Nitrogen in Diets Containing Wet Distiller’s Grains with Solubles and Steam-flaked Corn on Feedlot Cattle Performance and Carcass Characteristics 

    E-Print Network [OSTI]

    Ponce, Christian

    2010-10-12

    process (67% of total ethanol production). The process involves five general steps: grinding, cooking, liquefaction, saccharification, and fermentation. Endproducts of this process include ethanol, carbon dioxide, residual grain particles, and yeast... to approximately 100?C to generate 4 4 4 4 soluble dextrins and destroy any preexisting microogranims. Liquefaction of this treated mash is accomplished by holding the temperature at 85?C and adding additional alpha- amylase for at least 30 minutes...

  1. Oil shale research in China

    SciTech Connect (OSTI)

    Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

    1989-01-01

    There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

  2. Oil Mill Operators 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    Natural gas and petroleum are non-renewable and scarce energy sources. Although, it is well known that hydrocarbon reserves are depleting through the years, oil and gas remain the principal source of energy upon which our ...

  3. Crude Oil Prices

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    19.11 18.73 18.63 17.97 18.75 18.10 See footnotes at end of table. 21. Domestic Crude Oil First Purchase Prices Energy Information Administration Petroleum Marketing Annual...

  4. Crude Oil Prices

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    20.86 20.67 20.47 20.24 20.32 19.57 See footnotes at end of table. 21. Domestic Crude Oil First Purchase Prices Energy Information Administration Petroleum Marketing Annual...

  5. Using Oils As Pesticides 

    E-Print Network [OSTI]

    Bogran, Carlos E.; Ludwig, Scott; Metz, Bradley

    2006-10-30

    Petroleum and plant-derived spray oils show increasing potential for use as part of Integrated Pest Management systems for control of soft-bodied pests on fruit trees, shade trees, woody ornamentals and household plants. ...

  6. Oil Market Assessment

    Reports and Publications (EIA)

    2001-01-01

    Based on Energy Information Administration (EIA) contacts and trade press reports, overall U.S. and global oil supplies appear to have been minimally impacted by yesterday's terrorist attacks on the World Trade Center and the Pentagon.

  7. Understanding Crude Oil Prices

    E-Print Network [OSTI]

    Hamilton, James Douglas

    2008-01-01

    that the income elasticity of U.S. petroleum demand hasincome growth over the period and 1.11 for 11 oil-exporting countries.. And it is the latter countries where petroleum

  8. Imbibition assisted oil recovery 

    E-Print Network [OSTI]

    Pashayev, Orkhan H.

    2004-11-15

    analyzed in detail to investigate oil recovery during spontaneous imbibition with different types of boundary conditions. The results of these studies have been upscaled to the field dimensions. The validity of the new definition of characteristic length...

  9. Initial Husky BPU H-OIL{reg_sign} unit operations and performance

    SciTech Connect (OSTI)

    Faupel, T.H.; Tasker, K.G. [Hydrocarbon Research, Inc., Princeton, NJ (United States); Bannayan, M.A. [Husky Oil Operations Ltd., Saskatchewan (Canada)

    1995-12-31

    The Husky Bi-Provincial Upgrader (BPU) complex was successfully started up in the fall of 1992. The heart of this heavy oil upgrading plant is the H-Oil{reg_sign} unit, which utilizes ebullated-bed technology to hydrocrack and upgrade heavy atmospheric residue (400{degrees}C{sup +}) to synthetic crude oil. The H-Oil process, jointly licensed by Hydrocarbon Research, Inc. (HRI) and Texaco Development Corp. (TDC), employs daily catalyst additions and withdrawals, thereby maintaining constant catalytic activity. Since its successful start-up, the H-Oil unit, designed to process 5,088 m{sup 3}/sd (32,000 BPSD), has processed in excess of 5,850 m{sup 3}/sd (36,800 BPSD) of atmospheric residue at conversion levels in the 55 to 65 vol% range. The on-stream factor for the first year of operation has been a very respectable 81% for a new unit, which is significantly better than prior residue hydrocracking unit start-ups. The onstream factor for the second full year of operation was over 95% based on unit availability. The process performance and yields from the H-Oil unit have been in close agreement with the design values. The H-Oil unit was accepted by the BPU without a process guarantee test run which was waived. This paper summarizes the initial operations and performance of the H-Oil unit and provides a comparison of process performance and product yields between ebullated-bed laboratory units and the commercial unit.

  10. Catalyst deactivation in residue hydrocracking

    SciTech Connect (OSTI)

    Oballa, M.C.; Wong, C.; Krzywicki, A. [Novacor Research and Technology Corp., Calgary, Alberta (Canada)

    1994-12-31

    The existence of a computer-controlled bench scale hydrocracking units at the authors site has made cheaper the non-stop running of experiments for long periods of time. It was, therefore possible to show, at minimal costs, when three hydrocracking catalysts in service reach their maximum lifetime. Different parameters which are helpful for catalyst life and activity predictions were calculated, e.g., relative catalyst age and the effectiveness factor. Experimental results compared well with model, giving them the minimum and maximum catalyst lifetime, as well as the deactivation profile with regard to sulfur and metals removal. Reaction rate constants for demetallization and desulfurization were also determined. Six commercial catalysts were evaluated at short term runs and the three most active were used for long term runs. Out of three catalysts tested for deactivation at long term runs, it was possible to choose one whose useful life was higher than the others. All runs were carried out in a Robinson-Mahoney continuous flow stirred tank reactor, using 50/50 volumetric mixture of Cold Lake/Lloydminster atmospheric residue and NiMo/Al{sub 2}O{sub 3} catalyst.

  11. Oil/gas collector/separator for underwater oil leaks

    DOE Patents [OSTI]

    Henning, Carl D. (Livermore, CA)

    1993-01-01

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  12. All auto shredding: evaluation of automotive shredder residue generated by shredding only vehicles.

    SciTech Connect (OSTI)

    Duranceau, C. M.; Spangenberger, J. S.

    2011-09-26

    A well developed infrastructure exists for the reuse and recycling of automotive parts and materials. At the end of a vehicle's useful life many parts are removed and sold for reuse and fluids are recovered for recycling or proper disposal. What remains is shredded, along with other metal bearing scrap such as home appliances, demolition debris and process equipment, and the metals are separated out and recycled. The remainder of the vehicle materials is call shredder residue which ends up in the landfill. As energy and natural resources becomes more treasured, increased effort has been afforded to find ways to reduce energy consumption and minimize the use of our limited resources. Many of the materials found in shredder residue could be recovered and help offset the use of energy and material consumption. For example, the energy content of the plastics and rubbers currently landfilled with the shredder residue is equivalent to 16 million barrels of oil per year. However, in the United States, the recovered materials, primarily polymers, cannot be recycled due to current regulatory barriers which preclude the re-introduction into commerce of certain materials because of residual contamination with substances of concern (SOCs) such as polychlorinated biphenyls (PCBs). The source of the PCBs is not well understood. Old transformers, capacitors, white goods and ballasts from lighting fixtures are likely contributing factors. The project was designed to evaluate whether vehicles of varying age and manufacturing origin contribute to the PCB content in shredder residue. Additionally, the project was designed to determine if there are any trends in material composition of the shredder residue from varied age and manufacturing groups. This information would aid in future material recovery facility strategy and design. The test utilized a newly installed shredder plant to shred four categories of automobiles. The categories were defined by vehicle age and the manufacturing company and location. Each category of vehicles was processed individually through the shredder plant and the resulting shredder residue was analyzed for its materials composition and presence of PCBs and leachable metals. The results show that shredder residue from all vehicle categories tested are not significant contributors of PCBs and leachable metals. It was evident that leachable cadmium levels have decreased in newer vehicles. The composition of the shredder residue from each of the four categories is similar to the others. In addition, these compositions are approximately equal to the composition of typical shredder residues, not limited to automotive materials.

  13. Seismic stimulation for enhanced oil recovery

    E-Print Network [OSTI]

    Pride, S.R.

    2008-01-01

    aims to enhance oil production by sending seismic wavesbe expected to enhance oil production. INTRODUCTION The hopethe reservoir can cause oil production to increase. Quite

  14. WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J.P.

    2010-01-01

    H. H. Peters, Shale Oil Waste Water Recovery by Evaporation,treatment of oil shale waste products. Consequently, bothmost difficult and costly oil shale waste stream requiring

  15. Water Heaters (Storage Oil) | Department of Energy

    Energy Savers [EERE]

    Oil) Water Heaters (Storage Oil) Water Heater, Storage Oil - v1.0.xlsx More Documents & Publications Water Heaters (Tankless Electric) Water Heaters (Storage Electric)...

  16. WASTEWATER TREATMENT IN THE OIL SHALE INDUSTRY

    E-Print Network [OSTI]

    Fox, J.P.

    2010-01-01

    during oil shale retorting: retort water and gas condensate.commercial oil shale plant, retort water and gas condensateunique to an oil shale retort water, gas condensate, and

  17. Distillation efficiencies of an industrial-scale i-butane/n-butane fractionator

    SciTech Connect (OSTI)

    Klemola, K.T.; Ilme, J.K.

    1996-12-01

    Rarely published industrial-scale distillation efficiency data are presented. The Murphree tray efficiencies are determined from the i-butane/n-butane fractionator performance data. Point efficiencies, numbers of overall vapor phase transfer units, numbers of vapor and liquid phase transfer units, and liquid phase resistances of mass transfer are backcalculated from the Murphree tray efficiencies. Various efficiency prediction and scale-up methods have been tested against experimental results. A new model for the prediction of the numbers of vapor and liquid phase transfer units has been developed. The model can be applied to hydrocarbon systems at high pressure. The influence of the mass-transfer coefficients, the interfacial area, and the vapor and liquid residence times on mass transfer has been analyzed separately, and as a result the NTU correlations for vapor and liquid phases are obtained. The constants of the model can be obtained by fitting the model to experimental efficiency data from a similar system.

  18. Colorimetric Determination of Nitrite in Foods Principle: The sample is extracted with distilled water and the aqueous extract clarified

    E-Print Network [OSTI]

    Nazarenko, Alexander

    water and the aqueous extract clarified with zinc hydroxide. Sulfanilic acid is diazotisedColorimetric Determination of Nitrite in Foods Principle: The sample is extracted with distilled/50 mL. The absorbance range should extend from 0 to 0.6 approx. E. Extraction Procedure Weigh ca 100g

  19. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE AND CHLORIDE FROM LEGACY FISSILE MATERIALS

    SciTech Connect (OSTI)

    Pierce, R.; Peters, T.

    2011-11-01

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and the Savannah River Site (SRS) HB-Line Facility designed, developed, tested, and successfully deployed a production-scale system for the distillation of sodium chloride (NaCl) and potassium chloride (KCl) from plutonium oxide (PuO{sub 2}). Subsequent efforts adapted the vacuum salt distillation (VSD) technology for the removal of chloride and fluoride from less-volatile halide salts at the same process temperature and vacuum. Calcium chloride (CaCl{sub 2}), calcium fluoride (CaF{sub 2}), and plutonium fluoride (PuF{sub 3}) were of particular concern. To enable the use of the same operating conditions for the distillation process, SRNL employed in situ exchange reactions to convert the less-volatile halide salts to compounds that facilitated the distillation of halide without removal of plutonium. SRNL demonstrated the removal of halide from CaCl{sub 2}, CaF{sub 2} and PuF{sub 3} below 1000 C using VSD technology.

  20. Oil and Gas Investor returns climb as oil

    E-Print Network [OSTI]

    Arizona, University of

    Oil and Gas Investor returns climb as oil and gas drilling ventures succeed. www #12;Eng-Tips Forum Medical News Building/Construction · Engineers Advance Fuel Cell Technology · Micro

  1. Residual stress in nanocrystalline nickel tungsten electrodeposits

    E-Print Network [OSTI]

    Ziebell, Tiffany D. (Tiffany Dawn)

    2011-01-01

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We employ a three-dimensional ...

  2. Harvesting Residuals-Economic Energy Link 

    E-Print Network [OSTI]

    Owens, E. T.; Curtis, D. B.

    1986-01-01

    A description of systems used in integrated harvesting of quality and unmerchantable trees is outlined for three areas in New Brunswick, Canada. The silvicultural benefits and the use of residues as an alternative to ...

  3. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    1995-01-01

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350.degree. and 375.degree. C. to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan.

  4. Isolation of levoglucosan from lignocellulosic pyrolysis oil derived from wood or waste newsprint

    DOE Patents [OSTI]

    Moens, L.

    1995-07-11

    A method is provided for preparing high purity levoglucosan from lignocellulosic pyrolysis oils derived from wood or waste newsprint. The method includes reducing wood or newsprint to fine particle sizes, treating the particles with a hot mineral acid for a predetermined period of time, and filtering off and drying resulting solid wood or newsprint material; pyrolyzing the dried solid wood or newsprint material at temperatures between about 350 and 375 C to produce pyrolysis oils; treating the oils to liquid-liquid extraction with methyl isobutyl ketone to remove heavy tar materials from the oils, and to provide an aqueous fraction mixture of the oils containing primarily levoglucosan; treating the aqueous fraction mixtures with a basic metal salt in an amount sufficient to elevate pH values to a range of about 12 to about 12.5 and adding an amount of the salt in excess of the amount needed to obtain the pH range to remove colored materials of impurities from the oil and form a slurry, and freeze-drying the resulting slurry to produce a dry solid residue; and extracting the levoglucosan from the residue using ethyl acetate solvent to produce a purified crystalline levoglucosan. 2 figs.

  5. FINAL REPORT LGP Discrimination and Residual Risk Analysis on Standardized

    E-Print Network [OSTI]

    Fernandez, Thomas

    FINAL REPORT LGP Discrimination and Residual Risk Analysis on Standardized Test Sites ­ Camp Sibert............................................................................................................... 10 2.1.6 Residual Risk Analysis

  6. Used Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label the container "Waste Oil Only".

    E-Print Network [OSTI]

    Maroncelli, Mark

    the container "Waste Oil Only". Maintain a written log to document all amounts and types of oil addedUsed Oil and Filter Disposal Used Oil: Create a segregated storage area or container. Label to the container. No solvents, oil contaminated with solvents, PCBs, non-petroleum based oils, or any other

  7. Virent is Replacing Crude Oil

    Office of Energy Efficiency and Renewable Energy (EERE)

    Breakout Session 2A—Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Virent is Replacing Crude Oil Randy Cortright, Founder & Chief Technology Officer, Virent

  8. Business cycles in oil economies

    SciTech Connect (OSTI)

    Al-Mutairi, N.H.

    1991-01-01

    This study examines the impact of oil price shocks on output fluctuations of several oil-exporting economies. In most studies of business cycles, the role of oil price is ignored; the few studies that use oil price as one of the variables in the system focus on modeling oil-importing economies. The vector autoregression (VAR) technique is used to consider the cases of Norway, Nigeria, and Mexico. Both atheoretical and structural' VARs are estimated to determine the importance of oil price impulses on output variations. The study reports two types of results: variance decomposition and impulse response functions, with particular emphasis on the issues of stationarity and co-integration among the series. The empirical results suggest that shocks to oil price are important in explaining output variations. In most cases, shocks to oil price are shown to explain more than 20% of the forecast variance of output over a 40-quarter horizon.

  9. Oil | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyApril 2014DepartmentCouncilOffice of the ChiefResearchOil Oil For

  10. Oil and gas outlook

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural GasNatural GasEIARegionalMethodologyNorth093 *Oil andOil and

  11. SOLID PHASE MICROEXTRACTION SAMPLING OF FIRE DEBRIS RESIDUES IN THE PRESENCE OF RADIONUCLIDE SURROGATE METALS

    SciTech Connect (OSTI)

    Duff, M; Keisha Martin, K; S Crump, S

    2007-03-23

    The Federal Bureau of Investigation (FBI) Laboratory currently does not have on site facilities for handling radioactive evidentiary materials and there are no established FBI methods or procedures for decontaminating highly radioactive fire debris (FD) evidence while maintaining evidentiary value. One experimental method for the isolation of FD residue from radionuclide metals involves using solid phase microextraction (SPME) fibers to remove the residues of interest. Due to their high affinity for organics, SPME fibers should have little affinity for most (radioactive) metals. The focus of this research was to develop an examination protocol that was applicable to safe work in facilities where high radiation doses are shielded from the workers (as in radioactive shielded cells or ''hot cells''). We also examined the affinity of stable radionuclide surrogate metals (Co, Ir, Re, Ni, Ba, Cs, Nb, Zr and Nd) for sorption by the SPME fibers. This was done under exposure conditions that favor the uptake of FD residues under conditions that will provide little contact between the SPME and the FD material (such as charred carpet or wood that contains commonly-used accelerants). Our results from mass spectrometric analyses indicate that SPME fibers show promise for use in the room temperature head space uptake of organic FD residue (namely, diesel fuel oil, kerosene, gasoline and paint thinner) with subsequent analysis by gas chromatography (GC) with mass spectrometric (MS) detection. No inorganic forms of ignitable fluids were included in this study.

  12. USE OF POLYMERS TO RECOVER VISCOUS OIL FROM UNCONVENTIONAL RESERVOIRS

    SciTech Connect (OSTI)

    Randall Seright

    2011-09-30

    This final technical progress report summarizes work performed the project, 'Use of Polymers to Recover Viscous Oil from Unconventional Reservoirs.' The objective of this three-year research project was to develop methods using water soluble polymers to recover viscous oil from unconventional reservoirs (i.e., on Alaska's North Slope). The project had three technical tasks. First, limits were re-examined and redefined for where polymer flooding technology can be applied with respect to unfavorable displacements. Second, we tested existing and new polymers for effective polymer flooding of viscous oil, and we tested newly proposed mechanisms for oil displacement by polymer solutions. Third, we examined novel methods of using polymer gels to improve sweep efficiency during recovery of unconventional viscous oil. This report details work performed during the project. First, using fractional flow calculations, we examined the potential of polymer flooding for recovering viscous oils when the polymer is able to reduce the residual oil saturation to a value less than that of a waterflood. Second, we extensively investigated the rheology in porous media for a new hydrophobic associative polymer. Third, using simulation and analytical studies, we compared oil recovery efficiency for polymer flooding versus in-depth profile modification (i.e., 'Bright Water') as a function of (1) permeability contrast, (2) relative zone thickness, (3) oil viscosity, (4) polymer solution viscosity, (5) polymer or blocking-agent bank size, and (6) relative costs for polymer versus blocking agent. Fourth, we experimentally established how much polymer flooding can reduce the residual oil saturation in an oil-wet core that is saturated with viscous North Slope crude. Finally, an experimental study compared mechanical degradation of an associative polymer with that of a partially hydrolyzed polyacrylamide. Detailed results from the first two years of the project may be found in our first and second annual reports. Our latest research results, along with detailed documentation of our past work, can be found on our web site at http://baervan.nmt.edu/randy/. As an overall summary of important findings for the project, polymer flooding has tremendous potential for enhanced recovery of viscous oil. Fear of substantial injectivity reduction was a primary hurdle that limited application of polymer flooding. However, that concern is largely mitigated by (1) use of horizontal wells and (2) judicious injection above the formation parting pressure. Field cases now exist where 200-300-cp polymer solutions are injected without significant reductions in injectivity. Concern about costs associated with injection of viscous polymer solutions was a second major hurdle. However, that concern is reduced substantially by realization that polymer viscosity increases approximately with the square of polymer concentration. Viscosity can be doubled with only a 40% increase in polymer concentration. Up to a readily definable point, increases in viscosity of the injected polymer solution are directly related to increases in sweep efficiency and oil recovery. Previously published simulation results - suggesting that shear-thinning polymer solutions were detrimental to sweep efficiency - were shown to be unfounded (both theoretically and experimentally).

  13. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research

    SciTech Connect (OSTI)

    Speight, J.G.

    1992-01-01

    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  14. Characterization of oil and gas reservoirs and recovery technology deployment on Texas State Lands

    SciTech Connect (OSTI)

    Tyler, R.; Major, R.P.; Holtz, M.H.

    1997-08-01

    Texas State Lands oil and gas resources are estimated at 1.6 BSTB of remaining mobile oil, 2.1 BSTB, or residual oil, and nearly 10 Tcf of remaining gas. An integrated, detailed geologic and engineering characterization of Texas State Lands has created quantitative descriptions of the oil and gas reservoirs, resulting in delineation of untapped, bypassed compartments and zones of remaining oil and gas. On Texas State Lands, the knowledge gained from such interpretative, quantitative reservoir descriptions has been the basis for designing optimized recovery strategies, including well deepening, recompletions, workovers, targeted infill drilling, injection profile modification, and waterflood optimization. The State of Texas Advanced Resource Recovery program is currently evaluating oil and gas fields along the Gulf Coast (South Copano Bay and Umbrella Point fields) and in the Permian Basin (Keystone East, Ozona, Geraldine Ford and Ford West fields). The program is grounded in advanced reservoir characterization techniques that define the residence of unrecovered oil and gas remaining in select State Land reservoirs. Integral to the program is collaboration with operators in order to deploy advanced reservoir exploitation and management plans. These plans are made on the basis of a thorough understanding of internal reservoir architecture and its controls on remaining oil and gas distribution. Continued accurate, detailed Texas State Lands reservoir description and characterization will ensure deployment of the most current and economically viable recovery technologies and strategies available.

  15. Nineteenth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1986-01-01

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  16. Oil Conservation Division Environmental Bureau

    E-Print Network [OSTI]

    Oil Conservation Division Environmental Bureau Brine Well Collapse Evaluation Report June 18, 2009 Prukop of the Energy, Minerals and Natural Resources Department (EMNRD) ordered the Oil Conservation directed OCD to work with the Environmental Protection Agency, other states, technical experts, and oil

  17. Hypocholesterolemic Effects of Marine Oils

    E-Print Network [OSTI]

    Hypocholesterolemic Effects of Marine Oils UNITED STATES DEPART MENT OF THE INTERIOR FISH FISHERIES, H. E. Crowther, Director Hypocholesterolemic Effects of Marine Oils By JAMES J. PEIFER Excerpt from Chapter 23 of the book, "Fish Oils,·· M. E. Stansby, editor Avi Publishing Company, Westport

  18. OIL ANALYSIS LAB TRIVECTOR ANALYSIS

    E-Print Network [OSTI]

    OIL ANALYSIS LAB TRIVECTOR ANALYSIS This test method is a good routine test for the overall condition of the oil, the cleanliness, and can indicate the presence of wear metals that could be coming of magnetic metal particles within the oil. This may represent metals being worn from components (i

  19. Oil shale: Technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-10-01

    This report documents the status of the US Department of Energy's (DOE) Oil Shale Program as of the end of FY 86. The report consists of (1) a status of oil shale development, (2) a description of the DOE Oil Shale Program, (3) an FY 86 oil shale research summary, and (4) a summary of FY 86 accomplishments. Discoveries were made in FY 86 about the physical and chemical properties and behavior of oil shales, process chemistry and kinetics, in situ retorting, advanced processes, and the environmental behavior and fate of wastes. The DOE Oil Shale Program shows an increasing emphasis on eastern US oil shales and in the development of advanced oil shale processing concepts. With the award to Foster Wheeler for the design of oil shale conceptual plants, the first step in the development of a systems analysis capability for the complete oil shale process has been taken. Unocal's Parachute Creek project, the only commercial oil shale plant operating in the United States, is operating at about 4000 bbl/day. The shale oil is upgraded at Parachute Creek for input to a conventional refinery. 67 refs., 21 figs., 3 tabs.

  20. The Politics of Oil Nationalizations

    E-Print Network [OSTI]

    Mahdavi, Paasha

    2015-01-01

    s ability to use oil wealth to finance its expenditures.Finance Bribes paid to SOCAR officials Bribes through agents to Sonangol, Iraqi oilFinance Act, and in the United States the effective tax rate is 16.7% for shallow-water oil

  1. The Use of TaBoRR as a Heavy Oil Upgrader

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones

    2009-02-05

    Preliminary testing has shown that Western Research Institute's (WRI) Tank Bottom Recovery and Remediation (TaBoRR{reg_sign}) technology shows promise for heavy oil upgrading. Approximately 70 to 75 wt% of a Canadian Cold Lake bitumen feed was converted to a partially upgraded overhead product that could be transported directly by pipeline or blended with the parent bitumen to produce transportable crude. TaBoRR{reg_sign} was originally developed to remediate tank bottom wastes by producing a distillate product and solid waste. TaBoRR{reg_sign}'s processing steps include breaking a water-oil emulsion, recovering a light hydrocarbon fraction by distillation in a stripper unit, and pyrolyzing the residua reducing it to additional overhead and a benign coke for disposal. Cold Lake bitumen was tested in WRI's bench-scale equipment to evaluate the potential use of TaBoRR{reg_sign} technology for heavy oil upgrading to produce a stable, partially (or fully) upgraded product that will allow diluent-reduced or diluent-free transportation of bitumen or ultra-heavy crudes to market. Runs were conducted at temperatures of low, intermediate and high severity in the stripper to produce stripper overhead and bottoms. The bottoms from each of these runs were processed further in a 6-inch screw pyrolyzer to produce pyrolyzer overhead for blending with the corresponding stripper overheads. Proceeding in this fashion yielded three partially upgraded crudes. The products from TaBoRR{reg_sign} processing, the parent bitumen, and bitumen blends were subjected to stability and compatibility testing at the National Centre for Upgrading Technology (NCUT). Chemical analyses of the overhead product blends have met pipeline specifications for viscosity and density; however the bromine number does not, which might indicate the need for mild hydrotreating. Storage stability tests showed the blends to be stable. The blends were also soluble and compatible with most other Alberta crudes.

  2. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  3. African oil plays

    SciTech Connect (OSTI)

    Clifford, A.J. )

    1989-09-01

    The vast continent of Africa hosts over eight sedimentary basins, covering approximately half its total area. Of these basins, only 82% have entered a mature exploration phase, 9% have had little or no exploration at all. Since oil was first discovered in Africa during the mid-1950s, old play concepts continue to bear fruit, for example in Egypt and Nigeria, while new play concepts promise to become more important, such as in Algeria, Angola, Chad, Egypt, Gabon, and Sudan. The most exciting developments of recent years in African oil exploration are: (1) the Gamba/Dentale play, onshore Gabon; (2) the Pinda play, offshore Angola; (3) the Lucula/Toca play, offshore Cabinda; (4) the Metlaoui play, offshore Libya/Tunisia; (5) the mid-Cretaceous sand play, Chad/Sudan; and (6) the TAG-I/F6 play, onshore Algeria. Examples of these plays are illustrated along with some of the more traditional oil plays. Where are the future oil plays likely to develop No doubt, the Saharan basins of Algeria and Libya will feature strongly, also the presalt of Equatorial West Africa, the Central African Rift System and, more speculatively, offshore Ethiopia and Namibia, and onshore Madagascar, Mozambique, and Tanzania.

  4. Production of Shale Oil 

    E-Print Network [OSTI]

    Loper, R. D.

    1982-01-01

    part of 40% share up to a maximum of $1.1 billion. North of these two projects are the two prot Federal lease projects in Colorado -- the we most operated by the Rio Blanco Shale Oil Co a limited partnership between Amoco and Gulf Their early...

  5. Dying for oil

    SciTech Connect (OSTI)

    Sachs, A.

    1996-05-01

    This article discusses the fight and execution of Ken Saro-Wiwa, the Ogoni leader who defended his people`s land on the Niger delta against oil development encouraged by the government and persued by the Royal/Dutch Shell Co. Political reprocussions and heightened vigilance of environmental activists are discussed at length.

  6. World Oil Transit Chokepoints

    Reports and Publications (EIA)

    2012-01-01

    Chokepoints are narrow channels along widely used global sea routes, some so narrow that restrictions are placed on the size of vessel that can navigate through them. They are a critical part of global energy security due to the high volume of oil traded through their narrow straits.

  7. Structural Oil Pan With Integrated Oil Filtration And Cooling System

    DOE Patents [OSTI]

    Freese, V, Charles Edwin (Westland, MI)

    2000-05-09

    An oil pan for an internal combustion engine includes a body defining a reservoir for collecting engine coolant. The reservoir has a bottom and side walls extending upwardly from the bottom to present a flanged lip through which the oil pan may be mounted to the engine. An oil cooler assembly is housed within the body of the oil pan for cooling lubricant received from the engine. The body includes an oil inlet passage formed integrally therewith for receiving lubricant from the engine and delivering lubricant to the oil cooler. In addition, the body also includes an oil pick up passage formed integrally therewith for providing fluid communication between the reservoir and the engine through the flanged lip.

  8. Energy Policy 34 (2006) 515531 Have we run out of oil yet? Oil peaking analysis from

    E-Print Network [OSTI]

    2006-01-01

    of conventional oil production from an optimist's perspective. Is the oil peak imminent? What is the range oil production, geological constraints on the rates at which oil can be produced are not represented. Unconventional oil is chosen because production from Venezuela's heavy-oil fields and Canada's Athabascan oil

  9. Phase Behavior, Solid Organic Precipitation, and Mobility Characterization Studies in Support of Enhanced Heavy Oil Recovery on the Alaska North Slope

    SciTech Connect (OSTI)

    Shirish Patil; Abhijit Dandekar; Santanu Khataniar

    2008-12-31

    The medium-heavy oil (viscous oil) resources in the Alaska North Slope are estimated at 20 to 25 billion barrels. These oils are viscous, flow sluggishly in the formations, and are difficult to recover. Recovery of this viscous oil requires carefully designed enhanced oil recovery processes. Success of these recovery processes is critically dependent on accurate knowledge of the phase behavior and fluid properties, especially viscosity, of these oils under variety of pressure and temperature conditions. This project focused on predicting phase behavior and viscosity of viscous oils using equations of state and semi-empirical correlations. An experimental study was conducted to quantify the phase behavior and physical properties of viscous oils from the Alaska North Slope oil field. The oil samples were compositionally characterized by the simulated distillation technique. Constant composition expansion and differential liberation tests were conducted on viscous oil samples. Experiment results for phase behavior and reservoir fluid properties were used to tune the Peng-Robinson equation of state and predict the phase behavior accurately. A comprehensive literature search was carried out to compile available compositional viscosity models and their modifications, for application to heavy or viscous oils. With the help of meticulously amassed new medium-heavy oil viscosity data from experiments, a comparative study was conducted to evaluate the potential of various models. The widely used corresponding state viscosity model predictions deteriorate when applied to heavy oil systems. Hence, a semi-empirical approach (the Lindeloff model) was adopted for modeling the viscosity behavior. Based on the analysis, appropriate adjustments have been suggested: the major one is the division of the pressure-viscosity profile into three distinct regions. New modifications have improved the overall fit, including the saturated viscosities at low pressures. However, with the limited amount of geographically diverse data, it is not possible to develop a comprehensive predictive model. Based on the comprehensive phase behavior analysis of Alaska North Slope crude oil, a reservoir simulation study was carried out to evaluate the performance of a gas injection enhanced oil recovery technique for the West Sak reservoir. It was found that a definite increase in viscous oil production can be obtained by selecting the proper injectant gas and by optimizing reservoir operating parameters. A comparative analysis is provided, which helps in the decision-making process.

  10. Entanglement distillation for continuous-variables under a thermal environment: Effectiveness of a non-Gaussian operation

    E-Print Network [OSTI]

    Jaehak Lee; Hyunchul Nha

    2013-03-31

    We study the task of distilling entanglement by a coherent superposition operation $t\\hat{a}+r\\hat{a}^\\dagger$ applied to a continuous-variable state under a thermal noise. In particular, we compare the performances of two different strategies, i.e., the non-Gaussian operation $t\\hat{a}+r\\hat{a}^\\dagger$ is applied before or after the noisy Gaussian channel. This is closely related to a fundamental problem of whether Gaussian or non-Gaussian entanglement can be more robust under a noisy channel and also provides a useful insight into the practical implementation of entanglement distribution for a long-distance quantum communication. We specifically look into two entanglement characteristics, the logarithmic negativity as a measure of entanglement and the teleportation fidelity as a usefulness of entanglement, for each distilled state. We find that the non-Gaussian operation after (before) the thermal noise becomes more effective in the low (high) temperature regime.

  11. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S. . Rocky Flats Plant); Rivera, M.A. )

    1993-01-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  12. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S.; Rivera, M.A.

    1993-03-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  13. SUPRI Heavy Oil Research Program, SUPRI TR 85

    SciTech Connect (OSTI)

    Brigham, W.E.; Ramey, H.J. Jr.; Castanier, L.M.

    1992-05-01

    This report concerns progress made during the 1990--1991 fiscal year. Information is given an the following projects: (1) A Study of End Effects in Displacement Experiments; (2) Kinetics of In-Situ Combustion; (3) In-Situ Combustion with Metallic Additives; (4) Steam-Foam Studies in the Presence of Residual Oil; (5) Characterization of Surfactants in the Presence of Oil for Steam-Foam Applications; (6) CT Imaging of Steam and Steam Foam Laboratory Experiments; (7) Microvisualization of Foam Flow in Porous Media; (8) Transient Foam Flow in Porous Media with Cat Scanner; (9) Study of Matrix/Fracture Transfer During Steam Injections; (10) Transient Behavior of Gravity Drainage Wells; (11) Multivariate Optimization of Production Systems; (12) Ultrasonic Flowmeter. (VC)

  14. Simultaneous demetalization and hydrocracking of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Belinko, K.; Packwood, R.H.; Patmore, D.J.; Ranganathan, R.

    1983-03-15

    A process is described for the simultaneous demetalization and hydrocracking of heavy hydrocarbon oils. The process permits the recovery of metals such as vanadium and nickel in an economic manner by passing a slurry of a heavy hydrocarbon oil and carbonaceous additive particles, such as coal, in the presence of hydrogen through a confined vertical hydrocracking zone at high temperatures and pressures. A mixed effluent containing a gaseous phase and a liquid phase is removed from the top of a hydrocracking zone, while there is removed from the bottom of the hydrocracking zone a portion of the hydrocracking zone contents containing carbonaceous remains of the additive particles to which is adsorbed the metal residues from the feedstock. The effluent removed from the top of the hydrocracking zone can be subsequently fed directly to a catalytic hydrocracking unit.

  15. Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

    SciTech Connect (OSTI)

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

  16. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01

    bution of the impacts of oil production and consumption. Theof harmful effects from oil production and use. A criticaland procedural impacts of oil production and consumption

  17. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01

    of the impacts of oil production and consumption. The reviewimpacts of oil production and consumption conclude theincreased oil production and consumption. But how well do

  18. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01

    AND SOCIAL IMPACTS OF OIL product, product that does notthe quantity of oil products that escapes from pipelines. ”transport of crude oil and petroleum products accounted for

  19. Just oil? The distribution of environmental and social impacts of oil production and consumption

    E-Print Network [OSTI]

    O'Rourke, D; Connolly, S

    2003-01-01

    VII. IMPACTS OF OIL CONSUMPTION . . . . . . .and the location of oil consumption necessitates that crudere?neries. VII. IMPACTS OF OIL CONSUMPTION The combustion of

  20. Assigning a Value to Dried Distillers' Grains as a Protein Supplement in Cattle Consuming Low-Quality Forage 

    E-Print Network [OSTI]

    Rambo, Zachary Joseph

    2011-08-08

    - product. Operations using dry grind attempt to maximize ethanol production per unit of energy. Basic steps in the dry grinding process include; grinding, cooking, liquefaction, simultaneous saccharification, fermentation, and distillation. 3... Grinding is accomplished through the use of hammermills or roller mills which reduce particle size and facilitate water penetration. Fines resulting from grinding are mixed with water to create a slurry which is cooked after liquefaction and the addition...