National Library of Energy BETA

Sample records for displace cold cathode

  1. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, Gordon E. (Albuquerque, NM)

    1998-01-01

    A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging.

  2. Cold cathode vacuum gauging system

    DOE Patents [OSTI]

    Denny, Edward C. (Knoxville, TN)

    2004-03-09

    A vacuum gauging system of the cold cathode type is provided for measuring the pressure of a plurality of separate vacuum systems, such as in a gas centrifuge cascade. Each casing is fitted with a gauge tube assembly which communicates with the vacuum system in the centrifuge casing. Each gauge tube contains an anode which may be in the form of a slender rod or wire hoop and a cathode which may be formed by the wall of the gauge tube. The tube is provided with an insulated high voltage connector to the anode which has a terminal for external connection outside the vacuum casing. The tube extends from the casing so that a portable magnet assembly may be inserted about the tube to provide a magnetic field in the area between the anode and cathode necessary for pressure measurements in a cold cathode-type vacuum gauge arrangement. The portable magnetic assembly is provided with a connector which engages the external high voltage terminal for providing power to the anode within in the gauge tube. Measurement is made in the same manner as the prior cold cathode gauges in that the current through the anode to the cathode is measured as an indication of the pressure. By providing the portable magnetic assembly, a considerable savings in cost, installation, and maintenance of vacuum gauges for pressure measurement in a gas centrifuge cascade is realizable.

  3. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, G.E.

    1998-04-14

    A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by chemical vapor deposition (CVD) or diamond-like carbon (DLC) deposition are disclosed. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 14 figs.

  4. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, G.E.

    1998-03-10

    A cold cathode vacuum discharge tube, and method for making same, are disclosed with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 15 figs.

  5. High-Current Cold Cathode Employing Diamond and Related Materials

    SciTech Connect (OSTI)

    Hirshfield, Jay L.

    2014-10-22

    The essence of this project was for diamond films to be deposited on cold cathodes to improve their emission properties. Films with varying morphology, composition, and size of the crystals were deposited and the emission properties of the cathodes that utilize such films were studied. The prototype cathodes fabricated by the methods developed during Phase I were tested and evaluated in an actual high-power RF device during Phase II. These high-power tests used the novel active RF pulse compression system and the X-band magnicon test facility at US Naval Research Laboratory. In earlier tests, plasma switches were employed, while tests under this project utilized electron-beam switching. The intense electron beams required in the switches were supplied from cold cathodes embodying diamond films with varying morphology, including uncoated molybdenum cathodes in the preliminary tests. Tests with uncoated molybdenum cathodes produced compressed X-band RF pulses with a peak power of 91 MW, and a maximum power gain of 16.5:1. Tests were also carried out with switches employing diamond coated cathodes. The pulse compressor was based on use of switches employing electron beam triggering to effect mode conversion. In experimental tests, the compressor produced 165 MW in a ~ 20 ns pulse at ~18× power gain and ~ 140 MW at ~ 16× power gain in a 16 ns pulse with a ~ 7 ns flat-top. In these tests, molybdenum blade cathodes with thin diamond coatings demonstrated good reproducible emission uniformity with a 100 kV, 100 ns high voltage pulse. The new compressor does not have the limitations of earlier types of active pulse compressors and can operate at significantly higher electric fields without breakdown.

  6. Stabilization of a cold cathode electron beam glow discharge for surface treatment

    E-Print Network [OSTI]

    Rocca, Jorge J.

    Stabilization of a cold cathode electron beam glow discharge for surface treatment N. Mingolo and C that the reproducibility of electron beam pulses generated by a high power, cold cathode glow discharge is greatly improved cathode high voltage glow discharges can generate powerful electron beams for materials processing.1

  7. Miniature quadrupole mass spectrometer having a cold cathode ionization source

    DOE Patents [OSTI]

    Felter, Thomas E. (Livermore, CA)

    2002-01-01

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  8. Methods for batch fabrication of cold cathode vacuum switch tubes

    DOE Patents [OSTI]

    Walker, Charles A. (Albuquerque, NM); Trowbridge, Frank R. (Albuquerque, NM)

    2011-05-10

    Methods are disclosed for batch fabrication of vacuum switch tubes that reduce manufacturing costs and improve tube to tube uniformity. The disclosed methods comprise creating a stacked assembly of layers containing a plurality of adjacently spaced switch tube sub-assemblies aligned and registered through common layers. The layers include trigger electrode layer, cathode layer including a metallic support/contact with graphite cathode inserts, trigger probe sub-assembly layer, ceramic (e.g. tube body) insulator layer, and metallic anode sub-assembly layer. Braze alloy layers are incorporated into the stacked assembly of layers, and can include active metal braze alloys or direct braze alloys, to eliminate costs associated with traditional metallization of the ceramic insulator layers. The entire stacked assembly is then heated to braze/join/bond the stack-up into a cohesive body, after which individual switch tubes are singulated by methods such as sawing. The inventive methods provide for simultaneously fabricating a plurality of devices as opposed to traditional methods that rely on skilled craftsman to essentially hand build individual devices.

  9. Long-pulse arc-discharge plasma source with cold cathode for diagnostic neutral beam injector

    SciTech Connect (OSTI)

    Deichuli, P. P.; Ivanov, A. A.; Stupishin, N. V.

    2008-02-15

    Long-pulse cold cathode arc-discharge plasma generators have been successfully used as high-quality hydrogen ion sources for plasma diagnostic neutral beams. One of the main advantages of this type of plasma source is a high proton fraction (80%-90%). However, the lifetime of the plasma source is limited due to intensive electrode's erosion, especially at the cathode region. An optimized design of the cathode and the nearest electrodes is found which reduces the erosion and allows us to increase the pulse length. The plasma source produces the extracted ion current up to 3 A at a low angular divergence, and at the pulse duration up to 2 s.

  10. Thermal, thermoelectric, and cathode poisoning effects in cold fusion experiments

    SciTech Connect (OSTI)

    Keesing, R.G.; Greenhow, R.C.; Cohler, M.D. ); McQuillan, A.J. )

    1991-03-01

    This paper reports on an unsuccessful attempt to repeat the observations by Fleischmann and Pons of cold nuclear fusion in deuterium-charged palladium; no excess heat is found, nor is any gamma or neutron activity identified. Peltier heating at the palladium/platinum junction is investigated, but no effects are seen; the possibility remains, however, that a large Peltier coefficient may arise for deuterium concentrations that render the palladium-deuterium semiconducting. Finally, the effects of poisoning the palladium with cyanide were investigated.

  11. Method for analyzing the mass of a sample using a cold cathode ionization source mass filter

    DOE Patents [OSTI]

    Felter, Thomas E.

    2003-10-14

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  12. Development of a cold cathode ion source for a mass spectrometer type vacuum leak detector 

    E-Print Network [OSTI]

    Thomas, Harold Albert

    1947-01-01

    of cathode and ohmic loss of electrolyte significantly increases under reduced temperatures which lead to decreased cell performance and power output. To address the above issues, the efforts in this work are focused on engineering microstructure of cathode...

  13. HIGH-CURRENT COLD CATHODE FIELD EMISSION ARRAY FOR ELECTRON LENS APPLICATION

    SciTech Connect (OSTI)

    Hirshfield, Jay L

    2012-12-28

    During Phase I, the following goals were achieved: (1) design and fabrication of a novel, nano-dimensional CNT field emitter assembly for high current density application, with high durability; (2) fabrication of a ceramic based micro channel plate (MCP) and characterization of its secondary electron emission; and (3) characterizing the CNT/MCP cathode for high field emission and durability. As a result of these achievements, a relatively high current density of ~ 1.2 A/cm2 from a CNT cathode and single channel MCP were measured. The emission current was also extremely stable with a peak-to-peak variation of only 1.8%. The emission current could be further enhanced to meet requirements for electron lens applications by increasing the number of MCP channels. A calculation for maximum possible current density with a 1200 channel/cm2 MCP, placed over a cathode with 1200 uniformly functioning CNTs, would be ~1.46 kA/cm2, neglecting space charge limitations. Clearly this level of emission is far greater than what is needed for the electron lens application, but it does offer a highly comforting margin to account for sub-standard emitters and/or to allow the lesser challenge of building a cathode with fewer channels/cm2. A satisfactory goal for the electron lens application would be a controllable emission of 2-4 mA per channel in an ensemble of 800-1200 uniformly-functioning channels/cm2, and a cathode with overall area of about 1 cm2.

  14. Ion sources with arc-discharge plasma box driven by directly heated LaB{sub 6} electron emitter or cold cathode (invited)

    SciTech Connect (OSTI)

    Ivanov, Alexander A.; Davydenko, Vladimir I.; Deichuli, Petr P.; Shulzhenko, Grigori I.; Stupishin, Nikolay V.

    2008-02-15

    In the Budker Institute, Novosibirsk, an ion source with arc-discharge plasma box has been developed in the recent years for application in thermonuclear devices for plasma diagnostics. Several modifications of the ion source were provided with extracted current ranging from 1 to 7 A and pulse duration of up to 4 s. Initially, the arc-discharge plasma box with cold cathode was used, with which pulse duration is limited to 2 s by the cathode overheating and sputtering in local arc spots. Recently, a directly heated LaB{sub 6} electron emitter was employed instead, which has extended lifetime compared to the cold cathode. In the paper, characteristics of the beam produced with both arrangements of the plasma box are presented.

  15. Cathodic arcs

    E-Print Network [OSTI]

    Anders, Andre

    2003-01-01

    Rectangular vacuum-arc plasma source, Jan. 2, 1996. [40] A.A. Anders, Cathodic Arc Plasma Deposition (in preparation) (from the cathodic arc plasma. In most cases, a magnetic

  16. Vacuum encapsulated hermetically sealed diamond amplified cathode capsule and method for making same

    DOE Patents [OSTI]

    Rao, Triveni; Walsh, John; Gangone, Elizabeth

    2014-12-30

    A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first cold-weld ring disposed between the cathode element and the annular insulating spacer and a second cold-weld ring disposed between the annular insulating spacer and the diamond window element. The cathode capsule is formed by a vacuum cold-weld process such that the first cold-weld ring forms a hermetical seal between the cathode element and the annular insulating spacer and the second cold-weld ring forms a hermetical seal between the annular spacer and the diamond window element whereby a vacuum encapsulated chamber is formed within the capsule.

  17. Phase stabilization of laser beams in a cold atom accelerometer

    E-Print Network [OSTI]

    Byrne, Nicole (Nicole Malenie)

    2014-01-01

    A cold atom accelerometer measures the displacement of a proof mass of laser cooled atoms with respect to an instrument reference frame. The cold atom interferometer's reference frame is defined by a pair of specially ...

  18. Displacer for Stirling engine

    SciTech Connect (OSTI)

    Brown, A. T.

    1985-12-24

    In a Stirling engine and the like, a displacer piston having a plurality of internal baffles and insulation so as to prevent undesired heat transfer across the displacer piston.

  19. Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black

    E-Print Network [OSTI]

    support and functions as a current collector. Poly(tetrafluoroethylene) (PTFE) is normally used cathodes can be made with a PTFE binder by batch18,20 or continuous (rolling) cold-pressing of the AC onto

  20. Hollow-cathode electrode for high-power, high-pressure discharge devices

    DOE Patents [OSTI]

    Chang, J.J.; Alger, T.W.

    1995-08-22

    Several different cold cathode configurations are disclosed for a gas discharge device each having a plurality of grooves of selected spacing, depth and width to improve the emission of electrons in a gas discharge device. Each of the cold cathode configurations can be machined from a single piece of a selected material. Several of the configurations can be assembled with individual elements which is easily seen from the various figures. 8 figs.

  1. Electrorefining cell with parallel electrode/concentric cylinder cathode

    DOE Patents [OSTI]

    Gay, Eddie C. (Park Forest, IL); Miller, William E. (Naperville, IL); Laidler, James J. (Burr Ridge, IL)

    1997-01-01

    A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two.

  2. Electrorefining cell with parallel electrode/concentric cylinder cathode

    DOE Patents [OSTI]

    Gay, E.C.; Miller, W.E.; Laidler, J.J.

    1997-07-22

    A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two. 12 figs.

  3. Cathodes - Technological review

    SciTech Connect (OSTI)

    Cherkouk, Charaf; Nestler, Tina

    2014-06-16

    Lithium cobalt oxide (LiCoO{sub 2}) was already used in the first commercialized Li-ion battery by SONY in 1990. Still, it is the most frequently used cathode material nowadays. However, LiCoO{sub 2} is intrinsically unstable in the charged state, especially at elevated temperatures and in the overcharged state causing volume changes and transport limitation for high power batteries. In this paper, some technological aspects with large impact on cell performance from the cathode material point of view will be reviewed. At first it will be focused on the degradation processes and life-time mechanisms of the cathode material LiCoO{sub 2}. Electrochemical and structural results on commercial Li-ion batteries recorded during the cycling will be discussed. Thereafter, advanced nanomaterials for new cathode materials will be presented.

  4. Precision displacement reference system

    DOE Patents [OSTI]

    Bieg, Lothar F. (Albuquerque, NM); Dubois, Robert R. (Albuquerque, NM); Strother, Jerry D. (Edgewood, NM)

    2000-02-22

    A precision displacement reference system is described, which enables real time accountability over the applied displacement feedback system to precision machine tools, positioning mechanisms, motion devices, and related operations. As independent measurements of tool location is taken by a displacement feedback system, a rotating reference disk compares feedback counts with performed motion. These measurements are compared to characterize and analyze real time mechanical and control performance during operation.

  5. Transient digitizer with displacement current samplers

    DOE Patents [OSTI]

    McEwan, T.E.

    1996-05-21

    A low component count, high speed sample gate, and digitizer architecture using the sample gates is based on use of a signal transmission line, a strobe transmission line and a plurality of sample gates connected to the sample transmission line at a plurality of positions. The sample gates include a strobe pickoff structure near the strobe transmission line which generates a charge displacement current in response to propagation of the strobe signal on the strobe transmission line sufficient to trigger the sample gate. The sample gate comprises a two-diode sampling bridge and is connected to a meandered signal transmission line at one end and to a charge-holding cap at the other. The common cathodes are reverse biased. A voltage step is propagated down the strobe transmission line. As the step propagates past a capacitive pickoff, displacement current i=c(dv/dT), flows into the cathodes, driving the bridge into conduction and thereby charging the charge-holding capacitor to a value related to the signal. A charge amplifier converts the charge on the charge-holding capacitor to an output voltage. The sampler is mounted on a printed circuit board, and the sample transmission line and strobe transmission line comprise coplanar microstrips formed on a surface of the substrate. Also, the strobe pickoff structure may comprise a planar pad adjacent the strobe transmission line on the printed circuit board. 16 figs.

  6. Transient digitizer with displacement current samplers

    DOE Patents [OSTI]

    McEwan, Thomas E. (Livermore, CA)

    1996-01-01

    A low component count, high speed sample gate, and digitizer architecture using the sample gates is based on use of a signal transmission line, a strobe transmission line and a plurality of sample gates connected to the sample transmission line at a plurality of positions. The sample gates include a strobe pickoff structure near the strobe transmission line which generates a charge displacement current in response to propagation of the strobe signal on the strobe transmission line sufficient to trigger the sample gate. The sample gate comprises a two-diode sampling bridge and is connected to a meandered signal transmission line at one end and to a charge-holding cap at the other. The common cathodes are reverse biased. A voltage step is propagated down the strobe transmission line. As the step propagates past a capacitive pickoff, displacement current i=c(dv/dT), flows into the cathodes, driving the bridge into conduction and thereby charging the charge-holding capacitor to a value related to the signal. A charge amplifier converts the charge on the charge-holding capacitor to an output voltage. The sampler is mounted on a printed circuit board, and the sample transmission line and strobe transmission line comprise coplanar microstrips formed on a surface of the substrate. Also, the strobe pickoff structure may comprise a planar pad adjacent the strobe transmission line on the printed circuit board.

  7. Cathode materials review

    SciTech Connect (OSTI)

    Daniel, Claus Mohanty, Debasish Li, Jianlin Wood, David L.

    2014-06-16

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO{sub 2} cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  8. Filtered cathodic arc source

    DOE Patents [OSTI]

    Falabella, S.; Sanders, D.M.

    1994-01-18

    A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge is described. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45[degree] to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles. 3 figures.

  9. Miniaturized cathodic arc plasma source

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA)

    2003-04-15

    A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  10. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2013-07-23

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  11. Cold galaxies

    E-Print Network [OSTI]

    Rowan-Robinson, Michael

    2015-01-01

    We use 350 mu angular diameter estimates from Planck to test the idea that some galaxies contain exceptionally cold (10-13 K) dust, since colder dust implies a lower surface brightness radiation field illuminating the dust, and hence a greater physical extent for a given luminosity. The galaxies identified from their spectral energy distributions as containing cold dust do indeed show the expected larger 350 mu diameters. For a few cold dust galaxies where Herschel data are available we are able to use submillimetre maps or surface brightness profiles to locate the cold dust, which as expected generally lies outside the optical galaxy.

  12. Air cathode structure manufacture

    DOE Patents [OSTI]

    Momyer, William R. (Palo Alto, CA); Littauer, Ernest L. (Los Altos Hills, CA)

    1985-01-01

    An improved air cathode structure for use in primary batteries and the like. The cathode structure includes a matrix active layer, a current collector grid on one face of the matrix active layer, and a porous, nonelectrically conductive separator on the opposite face of the matrix active layer, the collector grid and separator being permanently bonded to the matrix active layer. The separator has a preselected porosity providing low IR losses and high resistance to air flow through the matrix active layer to maintain high bubble pressure during operation of the battery. In the illustrated embodiment, the separator was formed of porous polypropylene. A thin hydrophobic film is provided, in the preferred embodiment, on the current collecting metal grid.

  13. Cathodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels|Programs | DepartmentDepartment of EnergyWyomingNationalCathodes

  14. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

    E-Print Network [OSTI]

    Sansongsiri, Sakon

    2008-01-01

    cathode filtered cathodic arc plasma system. Fig. 2. Filmfiltered cathodic arc plasma deposition Sakon Sansongsiri a,filtered cathodic arc plasma deposition Sakon Sansongsiri a,

  15. Synthesis and Characterization of Cathode Materials | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cathode Materials Synthesis and Characterization of Cathode Materials Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in...

  16. Performance Enhancement of Cathodes with Conductive Polymers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhancement of Cathodes with Conductive Polymers Performance Enhancement of Cathodes with Conductive Polymers Presentation from the U.S. DOE Office of Vehicle Technologies "Mega"...

  17. Hot hollow cathode gun assembly

    DOE Patents [OSTI]

    Zeren, J.D.

    1983-11-22

    A hot hollow cathode deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, the hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  18. A Micromachined Vacuum Triode Using a Carbon Nanotube Cold Cathode

    E-Print Network [OSTI]

    Jin, Sungho

    2002-01-01

    surface using microelectromechanical systems (MEMS) de- signfield emission, microelectromechanical systems (MEMS),

  19. A Micromachined Vacuum Triode Using a Carbon Nanotube Cold Cathode

    E-Print Network [OSTI]

    Jin, Sungho

    2002-01-01

    silicon surface using microelectromechanical systems (MEMS)field emission, microelectromechanical systems (MEMS),

  20. Magnetic-cusp, cathodic-arc source

    DOE Patents [OSTI]

    Falabella, Steven (Livermore, CA)

    1995-01-01

    A magnetic-cusp for a cathodic-arc source wherein the arc is confined to the desired cathode surface, provides a current path for electrons from the cathode to the anode, and utilizes electric and magnetic fields to guide ions from the cathode to a point of use, such as substrates to be coated. The magnetic-cusp insures arc stability by an easy magnetic path from anode to cathode, while the straight-through arrangement leads to high ion transmission.

  1. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01

    Challenges in Future Li-Battery Research. Phil Trans. RoyalBatteries: Overview of Battery Cathodes Marca M. Doeffduring cell discharge. Battery-a device consisting of one or

  2. Operation of thoriated tungsten cathodes

    SciTech Connect (OSTI)

    Polk, J.E. )

    1993-01-20

    The operating temperature of thoriated tungsten cathodes used in electric thrusters depends on the surface coverage of thorium, which is determined by a balance of rate processes which supply and deplete the surface layer. The fundamental processes and rates are first reviewed in detail, then a phenomenological model based on these rate processes is described. The model indicates that the thermionic emission capabilities of thoriated tungsten cathodes decay rapidly because of thorium depletion at temperatures encountered in electric thrusters.

  3. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio...

  4. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    49thackeray2011o.pdf More Documents & Publications Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Layered Cathode Materials...

  5. Cathodic Arc Deposition of Copper Oxide Thin Films

    E-Print Network [OSTI]

    MacGill, R.A.

    2011-01-01

    compatibility. A cathodic arc plasma source with a copperon operating a cathodic arc plasma source with a copperdeposited using a cathodic arc plasma source with a copper

  6. Theory, Investigation and Stability of Cathode Electrocatalytic Activity

    SciTech Connect (OSTI)

    Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

    2012-09-30

    The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar conditions. This was also confirmed by x-ray analyses. For example, soft x-ray XANES data reveal that Co cations displace the Mn cations as being more favored to be reduced. Variations in the Sr-O in the annealed LSCF Fourier-transformed (FT) EXAFS suggest that some Sr segregation is occurring, but is not present in the annealed LSM-infiltrated LSCF cathode materials. Further, a surface enhanced Raman technique was also developed into to probe and map LSM and LSCF phase on underlying YSZ substrate, enabling us to capture important chemical information of cathode surfaces under practical operating conditions. Electrochemical models for the design of test cells and understanding of mechanism have been developed for the exploration of fundamental properties of electrode materials. Novel catalyst coatings through particle depositions (SDC, SSC, and LCC) or continuous thin films (PSM and PSCM) were successfully developed to improve the activity and stability of LSCF cathodes. Finally, we have demonstrated enhanced activity and stability of LSCF cathodes over longer periods of time in homemade and commercially available cells by an optimized LSM infiltration process. Microstructure examination of the tested cells did not show obvious differences between blank and infiltrated cells, suggesting that the infiltrated LSM may form a coherent film on the LSCF cathodes. There was no significant change in the morphology or microstructure of the LSCF cathode due to the structural similarity of LSCF and LSM. Raman analysis of the tested cells indicated small peaks emerging on the blank cells that correspond to trace amounts of secondary phase formation during operation (e.g., CoO{sub x}). The formation of this secondary phase might be attributed to performance degradation. In contrast, there was no such secondary phase observed in the LSM infiltrated cells, indicating that the LSM modification staved off secondary phase formation and thus improved the stability.

  7. cold standby

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About1996HowFOAShowingFuelWeatherize »EvePlantEnergyinspection report isCold

  8. Application of dynamic displacement current for diagnostics of subnanosecond breakdowns in an inhomogeneous electric field

    SciTech Connect (OSTI)

    Shao Tao; Zhang Cheng; Yan Ping [Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Key Laboratory of Power Electronics and Electric Drive, Chinese Academy of Sciences, Beijing 100190 (China); Tarasenko, Victor F.; Burachenko, Alexandr G.; Rybka, Dmitry V.; Kostyrya, Igor' D.; Lomaev, Mikhail I.; Baksht, Evgeni Kh. [Institute of High Current Electronics, Russian Academy of Sciences, Tomsk 634055 (Russian Federation)

    2013-05-15

    The breakdown of different air gaps at high overvoltages in an inhomogeneous electric field was investigated with a time resolution of up to 100 ps. Dynamic displacement current was used for diagnostics of ionization processes between the ionization wave front and a plane anode. It is demonstrated that during the generation of a supershort avalanche electron beam (SAEB) with amplitudes of {approx}10 A and more, conductivity in the air gaps at the breakdown stage is ensured by the ionization wave, whose front propagates from the electrode of small curvature radius, and by the dynamic displacement current between the ionization wave front and the plane electrode. The amplitude of the dynamic displacement current measured by a current shunt is 100 times greater than the SAEB. It is shown that with small gaps and with a large cathode diameter, the amplitude of the dynamic displacement current during a subnanosecond rise time of applied pulse voltage can be higher than 4 kA.

  9. Regenerative rotary displacer Stirling engine

    SciTech Connect (OSTI)

    Isshiki, Naotsugu; Watanabe, Hiroichi; Raggi, L.; Isshiki, Seita; Hirata, Koichi

    1996-12-31

    A few rotary displacer Stirling engines in which the displacer has one gas pocket space at one side and rotates in a main enclosed cylinder, which is heated from one side and cooled from opposite side without any regenerator, have been studied for some time by the authors. The authors tried to improve this engine by equipping it with a regenerator, because without a regenerator, pressure oscillation and efficiency are too small. Here, several types of regenerative rotary displacer piston Stirling engines are proposed. One is the contra-rotating tandem two disc type displacer engine using axial heat conduction through side walls or by heat pipes and another is a single disc type with circulating fluid regenerator or heat pipes. Stirling engines of this new rotary displacer type are thought to attain high speed. Here, experimental results of the original rotary displacer Stirling engine without a regenerator, and one contra-rotating tandem displacer engine with side wall regenerator by axial heat conduction are reported accompanied with a discussion of the results.

  10. Innovative Cathode Coating Enables Faster Battery Charging, Dischargin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative Cathode Coating Enables Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating...

  11. Chopping effect observed at cathodic arc initiation

    E-Print Network [OSTI]

    Anders, Andre

    2000-01-01

    generation by vacuum arc plasma guns,” Rev. Sci. Instrum. ,probe L L SCR C C D I arc plasma source and filter cathode Rto IEEE Trans. Plasma Science Cathodic arcs or “vacuum” arcs

  12. Dual-porosity ribbed fuel cell cathode

    DOE Patents [OSTI]

    Johnsen, Richard; Yuh, Chao-Yi; Alexander, Michael

    2005-05-10

    A fuel cell cathode comprising a cathode body having rib regions and base regions which connect the rib regions, the rib regions being of greater thickness and of less porosity than the base regions.

  13. Literature Review of Displacement Ventilation 

    E-Print Network [OSTI]

    Cho, S.; Im, P.; Haberl, J. S.

    2005-01-01

    Performance Evaluation and Design Guidelines for Displacement Ventilation” by Chen and Clicksman (2003), were used to begin the literature search. Their references include papers, articles, and web sites presenting major contributions to the understanding...

  14. Displacement sensing system and method

    DOE Patents [OSTI]

    VunKannon, Jr., Robert S

    2006-08-08

    A displacement sensing system and method addresses demanding requirements for high precision sensing of displacement of a shaft, for use typically in a linear electro-dynamic machine, having low failure rates over multi-year unattended operation in hostile environments. Applications include outer space travel by spacecraft having high-temperature, sealed environments without opportunity for servicing over many years of operation. The displacement sensing system uses a three coil sensor configuration, including a reference and sense coils, to provide a pair of ratio-metric signals, which are inputted into a synchronous comparison circuit, which is synchronously processed for a resultant displacement determination. The pair of ratio-metric signals are similarly affected by environmental conditions so that the comparison circuit is able to subtract or nullify environmental conditions that would otherwise cause changes in accuracy to occur.

  15. Remote control for anode-cathode adjustment

    DOE Patents [OSTI]

    Roose, Lars D. (Albuquerque, NM)

    1991-01-01

    An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

  16. Thermoelectric Generator (TEG) Fuel Displacement Potential using...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Displacement Potential using Engine-in-the-Loop and Simulation Thermoelectric Generator (TEG) Fuel Displacement Potential using Engine-in-the-Loop and Simulation Assessment...

  17. Clean Cities Regional Support & Petroleum Displacement Awards...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Regional Support & Petroleum Displacement Awards Clean Cities Regional Support & Petroleum Displacement Awards 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual...

  18. Magnetic-cusp, cathodic-arc source

    DOE Patents [OSTI]

    Falabella, S.

    1995-11-21

    A magnetic-cusp for a cathodic-arc source wherein the arc is confined to the desired cathode surface, provides a current path for electrons from the cathode to the anode, and utilizes electric and magnetic fields to guide ions from the cathode to a point of use, such as substrates to be coated. The magnetic-cusp insures arc stability by an easy magnetic path from anode to cathode, while the straight-through arrangement leads to high ion transmission. 3 figs.

  19. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  20. Filters for cathodic arc plasmas

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA); Bilek, Marcela M. M. (Engadine, AU); Brown, Ian G. (Berkeley, CA)

    2002-01-01

    Cathodic arc plasmas are contaminated with macroparticles. A variety of magnetic plasma filters has been used with various success in removing the macroparticles from the plasma. An open-architecture, bent solenoid filter, with additional field coils at the filter entrance and exit, improves macroparticle filtering. In particular, a double-bent filter that is twisted out of plane forms a very compact and efficient filter. The coil turns further have a flat cross-section to promote macroparticle reflection out of the filter volume. An output conditioning system formed of an expander coil, a straightener coil, and a homogenizer, may be used with the magnetic filter for expanding the filtered plasma beam to cover a larger area of the target. A cathodic arc plasma deposition system using this filter can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  1. Nickel-titanium-phosphate cathodes

    DOE Patents [OSTI]

    Belharouak, Ilias (Westmont, IL); Amine, Khalil (Downers Grove, IL)

    2008-12-16

    Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.

  2. Modification of polymer velvet cathode via metallic Mo coating for enhancement of high-current electron emission performances

    SciTech Connect (OSTI)

    Xiong, Ying; Wang, Bing; Yi, Yong; Xia, Liansheng; Zhang, Huang

    2013-09-15

    The effect of surface Mo coating on the high-current electron emission performances for polymer velvet cathode has been investigated in a diode with A-K gap of 11.5 cm by the combination of time-resolved electrical diagnostic and temporal pressure variation. Compared with uncoated polymer velvet cathode under the single-pulsed emission mode, the Mo-coated one shows lower outgassing levels (?0.40 Pa L), slower cathode plasma expansion velocity (?2.30 cm/?s), and higher emission stability as evidences by the change in cathode current, temporal pressure variation, and diode perveance. Moreover, after Mo coating, the emission consistency of the polymer velvet cathode between two adjacent pulses is significantly improved in double-pulsed emission mode with ?500 ns interval between two pulses, which further confirms the effectiveness of Mo coating for enhancement of electron emission performance of polymer velvet cathodes. These results should be of interest to the high-repetitive high-power microwave systems with cold cathodes.

  3. DISPLACEMENT BASED SEISMIC DESIGN METHODS.

    SciTech Connect (OSTI)

    HOFMAYER,C.MILLER,C.WANG,Y.COSTELLO,J.

    2003-07-15

    A research effort was undertaken to determine the need for any changes to USNRC's seismic regulatory practice to reflect the move, in the earthquake engineering community, toward using expected displacement rather than force (or stress) as the basis for assessing design adequacy. The research explored the extent to which displacement based seismic design methods, such as given in FEMA 273, could be useful for reviewing nuclear power stations. Two structures common to nuclear power plants were chosen to compare the results of the analysis models used. The first structure is a four-story frame structure with shear walls providing the primary lateral load system, referred herein as the shear wall model. The second structure is the turbine building of the Diablo Canyon nuclear power plant. The models were analyzed using both displacement based (pushover) analysis and nonlinear dynamic analysis. In addition, for the shear wall model an elastic analysis with ductility factors applied was also performed. The objectives of the work were to compare the results between the analyses, and to develop insights regarding the work that would be needed before the displacement based analysis methodology could be considered applicable to facilities licensed by the NRC. A summary of the research results, which were published in NUREGICR-6719 in July 2001, is presented in this paper.

  4. Free displacer and Ringbom displacer for a Malone refrigerator

    SciTech Connect (OSTI)

    Swift, G.W.; Brown, A.O.

    1994-05-01

    Malone refrigeration uses a liquid near its critical point (instead of the customary gas) as the working fluid in a Stirling, Brayton, or similar regenerative or recuperative cycle. Thus far, we have focused on the Stirling cycle, to avoid the difficult construction of the high-pressure-difference counterflow recuperator required for a Brayton machine. Our first Malone refrigerator used liquid propylene (C{sub 3}H{sub 6}) in a double-acting 4-cylinder Stirling configuration. First measurements with a free displacer used in a liquid working fluid are presented. The displacer was operated both in harmonic mode and in Ringbom mode, in liquid carbon dioxide. The results are in reasonable agreement with expectations.

  5. Arc initiation in cathodic arc plasma sources

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA)

    2002-01-01

    A "triggerless" arc initiation method and apparatus is based on simply switching the arc supply voltage to the electrodes (anode and cathode). Neither a mechanical trigger electrode nor a high voltage flashover from a trigger electrode is required. A conducting path between the anode and cathode is provided, which allows a hot spot to form at a location where the path connects to the cathode. While the conductive path is eroded by the cathode spot action, plasma deposition ensures the ongoing repair of the conducting path. Arc initiation is achieved by simply applying the relatively low voltage of the arc power supply, e.g. 500 V-1 kV, with the insulator between the anode and cathode coated with a conducting layer and the current at the layer-cathode interface concentrated at one or a few contact points. The local power density at these contact points is sufficient for plasma production and thus arc initiation. A conductive surface layer, such as graphite or the material being deposited, is formed on the surface of the insulator which separates the cathode from the anode. The mechanism of plasma production (and arc initiation) is based on explosive destruction of the layer-cathode interface caused by joule heating. The current flow between the thin insulator coating and cathode occurs at only a few contact points so the current density is high.

  6. Filtered cathodic arc deposition with ion-species-selective bias

    E-Print Network [OSTI]

    Anders, Andre; Pasaja, Nitisak; Sansongsiri, Sakon; Lim, Sunnie H.N.

    2006-01-01

    Photograph of a cathodic arc plasma source with two cathodesof ions of cathodic arc plasmas. The selection was made forAbstract A dual-cathode arc plasma source was combined with

  7. Performance Degradation of LSCF Cathodes

    SciTech Connect (OSTI)

    Alinger, Matthew

    2013-09-30

    This final report summarizes the progress made during the October 1, 2008 - September 30, 2013 period under Cooperative Agreement DE-NT0004109 for the U. S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled “Performance Degradation of LSCF Cathodes”. The primary objective of this program is to develop a performance degradation mitigation path for high performing, cost-effective solid oxide fuel cells (SOFCs). Strategies to mitigate performance degradation are developed and implemented. In addition, thermal spray manufacturing of SOFCs is explored. Combined, this work establishes a basis for cost-effective SOFC cells.

  8. Development of high-capacity cathode materials with integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    high-capacity cathode materials with integrated structures Development of high-capacity cathode materials with integrated structures 2009 DOE Hydrogen Program and Vehicle...

  9. Development of High-Capacity Cathode Materials with Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Development of High-Capacity Cathode Materials with Integrated Structures Development of High-Capacity Cathode Materials with Integrated Structures...

  10. Development of High-Capacity Cathode Materials with Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Development of high-capacity cathode materials with integrated structures Development of High-Capacity Cathode Materials with Integrated Structures...

  11. Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading Presented at the Department of Energy Fuel Cell...

  12. Cathodic Arcs: Fractal Voltage and Cohesive Energy Rule

    E-Print Network [OSTI]

    Anders, Andre; Oks, Efim M.; Gera, Yu. Yushkov

    2005-01-01

    Applications of Vacuum-Arc-Produced Plasma, Ion and Electronparameters of cathodic arc plasma, many researches decidedof a coaxial cathodic arc plasma source, and analyzing the

  13. High Energy Materials for PHEVs: Cathodes (New Project) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for PHEVs: Cathodes (New Project) High Energy Materials for PHEVs: Cathodes (New Project) Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit...

  14. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  15. Studies on Lithium Manganese Rich MNC Composite Cathodes | Department...

    Office of Environmental Management (EM)

    Studies on Lithium Manganese Rich MNC Composite Cathodes Studies on Lithium Manganese Rich MNC Composite Cathodes 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies...

  16. Surface modified CFx cathode material for ultrafast discharge...

    Office of Scientific and Technical Information (OSTI)

    Surface modified CFx cathode material for ultrafast discharge and high energy density Citation Details In-Document Search Title: Surface modified CFx cathode material for ultrafast...

  17. Surface modified CFx cathode material for ultrafast discharge...

    Office of Scientific and Technical Information (OSTI)

    Surface modified CFx cathode material for ultrafast discharge and high energy density Prev Next Title: Surface modified CFx cathode material for ultrafast discharge and high...

  18. Water Mist Suppression in Conjunction with Displacement

    E-Print Network [OSTI]

    Hickman, Mark

    Water Mist Suppression in Conjunction with Displacement Ventilation By Benjamin Piers Hume-2758 #12;#12;Displacement Water Mist System Masters of Fire Engineering Thesis 2003 i A man of genius makes Water Mist System Masters of Fire Engineering Thesis 2003 ii #12;Displacement Water Mist System Masters

  19. Cathode for an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

    2001-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  20. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, J.

    1999-04-06

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically. 23 figs.

  1. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, John (M.I.T. Branch P.O. Box 301, Cambridge, MA 02139)

    1995-01-01

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically.

  2. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, J.

    1995-05-30

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically. 29 figs.

  3. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, John (M.I.T. P.O. Box 397301, Cambridge, MA 02139)

    1999-01-01

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically.

  4. Batteries: Overview of Battery Cathodes

    SciTech Connect (OSTI)

    Doeff, Marca M

    2010-07-12

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

  5. How cold is cold dark matter?

    SciTech Connect (OSTI)

    Armendariz-Picon, Cristian; Neelakanta, Jayanth T., E-mail: armen@phy.syr.edu, E-mail: jtneelak@syr.edu [Department of Physics, Syracuse University, Syracuse, NY 13244-1130 (United States)

    2014-03-01

    If cold dark matter consists of particles, these must be non-interacting and non-relativistic by definition. In most cold dark matter models however, dark matter particles inherit a non-vanishing velocity dispersion from interactions in the early universe, a velocity that redshifts with cosmic expansion but certainly remains non-zero. In this article, we place model-independent constraints on the dark matter temperature to mass ratio, whose square root determines the dark matter velocity dispersion. We only assume that dark matter particles decoupled kinetically while non-relativistic, when galactic scales had not entered the horizon yet, and that their momentum distribution has been Maxwellian since that time. Under these assumptions, using cosmic microwave background and matter power spectrum observations, we place upper limits on the temperature to mass ratio of cold dark matter today (away from collapsed structures). These limits imply that the present cold dark matter velocity dispersion has to be smaller than 54 m/s. Cold dark matter has to be quite cold, indeed.

  6. K2CsSb Cathode Development

    SciTech Connect (OSTI)

    Smedley,J.; Rao, T.; Wang, E.

    2008-10-01

    K{sub 2}CsSb is an attractive photocathode for high current applications. With a quantum efficiency of >4% at 532nm and >10% at 355nm, it is the only cathode to have demonstrated an average current of 35mA in an accelerator environment We describe ongoing cathode development work. for the energy recovery linac being constructed at BNL Several cathodes have been created on both copper and stainless steel substrates, and their spatial uniformity and spectral response have been characterized. Preliminary lifetime measurements have been performed at high average current densities (>1 mA/mm{sup 2}).

  7. Cathode for molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Mrazek, Franklin C. (Hickory Hills, IL)

    1990-01-01

    A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

  8. Coated porous carbon cathodes for lithium ion batteries

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Dudney, Nancy J [ORNL; Kiggans, Jim [ORNL; Klett, James William [ORNL

    2008-01-01

    Coated porous carbon cathodes for automotive lithium batteries are being developed with the goal of overcoming the problems with capacity fade and poor thermal management in conventional polymer-bonded cathodes. The active cathode material (lithium iron phosphate nanoparticles) is carbon-bonded to the porous carbon support material. Cathodes have been developed with high specific energy and power and with good cycling behavior.

  9. Software Enabled Virtually Variable Displacement Pumps -Theoretical and Experimental Studies

    E-Print Network [OSTI]

    Li, Perry Y.

    Software Enabled Virtually Variable Displacement Pumps - Theoretical and Experimental Studies the functional equivalent of a variable displacement pump. This approach combines a fixed displacement pump valve control, without many of the shortcomings of commercially available variable displacement pumps

  10. Variable delivery, fixed displacement pump

    DOE Patents [OSTI]

    Sommars, Mark F. (Sparland, IL)

    2001-01-01

    A variable delivery, fixed displacement pump comprises a plurality of pistons reciprocated within corresponding cylinders in a cylinder block. The pistons are reciprocated by rotation of a fixed angle swash plate connected to the pistons. The pistons and cylinders cooperate to define a plurality of fluid compression chambers each have a delivery outlet. A vent port is provided from each fluid compression chamber to vent fluid therefrom during at least a portion of the reciprocal stroke of the piston. Each piston and cylinder combination cooperates to close the associated vent port during another portion of the reciprocal stroke so that fluid is then pumped through the associated delivery outlet. The delivery rate of the pump is varied by adjusting the axial position of the swash plate relative to the cylinder block, which varies the duration of the piston stroke during which the vent port is closed.

  11. High current density cathode for electrorefining in molten electrolyte

    DOE Patents [OSTI]

    Li, Shelly X.

    2010-06-29

    A high current density cathode for electrorefining in a molten electrolyte for the continuous production and collection of loose dendritic or powdery deposits. The high current density cathode eliminates the requirement for mechanical scraping and electrochemical stripping of the deposits from the cathode in an anode/cathode module. The high current density cathode comprises a perforated electrical insulated material coating such that the current density is up to 3 A/cm.sup.2.

  12. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    in High-Power Lithium-Ion Batteries for Use in Hybridas Cathodes for Lithium-Ion Batteries. Chem. Mater. 2011,seen in magnesium or lithium ion batteries would operate at

  13. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    of Vanadium Oxide Aerogels. J. Non. Cryst. Solids (102)of composite V 2 O 5 aerogel electrodes. 26electrolyte and a V 2 O 5 aerogel cathode. There are few

  14. Engineering of High Energy Cathode Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kang Xu ( ARL) * Jun Liu (PNNL) * Toda * BASF * ECPRO Partners 2 Enable the Argonne high energy composite layered cathode xLi 2 MnO 3 *(1-x)LiNiO 2 (LMR- NMC) for 40 miles PHEV...

  15. Cathodic protection of storage field well casings

    SciTech Connect (OSTI)

    Dabkowski, J.

    1986-01-01

    Downhole logging of gas storage field wells to determine cathodic protection (CP) levels is expensive and requires removing the well from service. A technique allowing the prediction of downhole CP levels by modeling combined with limiting field measurements would provide the industry with a cost-effective means of implementing and monitoring casing protection. A computer model has been developed for a cathodically protected well casing.

  16. Displacement of crude oil by carbon dioxide 

    E-Print Network [OSTI]

    Omole, Olusegun

    1980-01-01

    DISPLACEMENT OF CRUDE OIL BY CARBON DIOXIDE A Thesis by OLUSEGUN OMOLE Submitted to the Graduate College of Texas ASM University in part';al fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1980 Major Subject...: Petroleum Engineering DISPLACEMENT OF CRUDE OIL BY CARBON DIOXIDE A Thesis by OLUSEGUN OMOLE Approved as to style and content by: hairman of Committee / (Member (Member (Member (Hea o Depart ent December 1980 ABSTRACT Displacement of Crude Oil...

  17. Final Technical Report- Back-gate Field Emission-based Cathode RF Electron Gun

    SciTech Connect (OSTI)

    McGuire, Gary; Martin, Allen; Noonan, John

    2010-10-30

    The objective was to complete the design of an electron gun which utilizes a radio frequency (RF) power source to apply a voltage to a field emission (FE) cathode, a so called cold cathode, in order to produce an electron beam. The concept of the RF electron gun was originally conceived at Argonne National Laboratory but never reduced to practice. The research allowed the completion of the design based upon the integration of the FE electron source. Compared to other electron guns, the RF gun is very compact, less than one third the size of other comparable guns, and produces a high energy (to several MeV), high quality, high power electron beam with a long focal length with high repetition rates. The resultant electron gun may be used in welding, materials processing, analytical equipment and waste treatment.

  18. The influence of deposits on palladium cathodes in D[sub 2]O electrolysis

    SciTech Connect (OSTI)

    Lihn, C.J.; Wan, C.C.; Wan, C.M.; Perng, T.P. )

    1993-11-01

    Platinum and silicon have been found deposited on the palladium cathode during the electrolysis of a 0.1 M LiOD solution with a platinum anode in a glass cell. Various techniques including surface analysis, cyclic voltammetry, and electrochemical permeation were used to study the surface deposits, electrochemical deuterium-sorption behavior, and permeation rate of deuterium into palladium, respectively. It was shown that palladium cathodes were contaminated by platinum and silicon deposits after a certain period of electrolysis. These deposits could affect the electrochemical processes during electrolysis. The contamination may be a cause of the sporadic results reported in [open quotes]cold fusion[close quotes] research. 18 refs., 15 figs.

  19. Displacing Natural Gas Consumption and Lowering Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Refinery and Chemical Plant Process Heaters ADVANCED MANUFACTURING OFFICE Displacing Natural Gas Consumption and Lowering Emissions By enabling process heaters to utilize...

  20. Plasma processes inside dispenser hollow cathodes

    SciTech Connect (OSTI)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.; Jameson, Kristina K.

    2006-06-15

    A two-dimensional fluid model of the plasma and neutral gas inside dispenser orificed hollow cathodes has been developed to quantify plasma processes that ultimately determine the life of the porous emitters inserted in these devices. The model self-consistently accounts for electron emission from the insert as well as for electron and ion flux losses from the plasma. Two cathodes, which are distinctively different in size and operating conditions, have been simulated numerically. It is found that the larger cathode, with outer tube diameter of 1.5 cm and orifice diameter of 0.3 cm, establishes an effective emission zone that spans approximately the full length of the emitter when operated at a discharge current of 25 A and a flow rate of 5.5 sccm. The net heating of the emitter is caused by ions that are produced by ionization of the neutral gas inside the tube and are then accelerated by the sheath along the emitter. The smaller cathode, with an outer diameter of 0.635 cm and an orifice diameter of 0.1 cm, does not exhibit the same operational characteristics. At a flow rate of 4.25 sccm and discharge current of 12 A, the smaller cathode requires 4.5 times the current density near the orifice and operates with more than 6 times the neutral particle density compared to the large cathode. As a result, the plasma particle density is almost one order of magnitude higher compared to the large cathode. The plasma density in this small cathode is high enough such that the Debye length is sufficiently small to allow 'sheath funneling' into the pores of the emitter. By accessing areas deeper into the insert material, it is postulated that the overall emission of electrons is significantly enhanced. The maximum emission current density is found to be about 1 A/mm{sup 2} in the small cathode, which is about one order of magnitude higher than attained in the large cathode. The effective emission zone in the small cathode extends to about 15% of the emitter length only, and the power deposited at the emitter surface by returning electrons is found to be twice that deposited by ions. A previous study suggested that the computed particle flux and energy of ions to the emitter of the 1.5 cm cathode were not high enough to change the barium evaporation rate compared to thermally induced evaporation. The same suggestion is made here for the 0.635 cm cathode. The peak ion flux to the emitter is found to be 1.2 A/cm{sup 2} (7.6x10{sup 18}/s cm{sup 2}), and the corresponding peak sheath drop is 2.9 V. Consequently, once the emitter operating temperature is known it is possible to determine directly the barium depletion-limited life of these cathodes using existing vacuum-cathode data.

  1. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    SciTech Connect (OSTI)

    Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

    2003-03-31

    This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

  2. Effect of underlayer on coalescence of silver islands grown by filtered cathodic arc deposition

    E-Print Network [OSTI]

    Byon, Eungsun; Anders, Andre

    2003-01-01

    1. A miniature pulsed cathodic arc plasma source 14) with ausing a pulsed cathodic arc plasma source with a Nb cathode.

  3. Improved cathode materials for microbial electrosynthesis

    SciTech Connect (OSTI)

    Zhang, T; Nie, HR; Bain, TS; Lu, HY; Cui, MM; Snoeyenbos-West, OL; Franks, AE; Nevin, KP; Russell, TP; Lovley, DR

    2013-01-01

    Microbial electrosynthesis is a promising strategy for the microbial conversion of carbon dioxide to transportation fuels and other organic commodities, but optimization of this process is required for commercialization. Cathodes which enhance electrode-microbe electron transfer might improve rates of product formation. To evaluate this possibility, biofilms of Sporomusa ovata, which are effective in acetate electrosynthesis, were grown on a range of cathode materials and acetate production was monitored over time. Modifications of carbon cloth that resulted in a positive-charge enhanced microbial electrosynthesis. Functionalization with chitosan or cyanuric chloride increased acetate production rates 6-7 fold and modification with 3-aminopropyltriethoxysilane gave rates 3-fold higher than untreated controls. A 3-fold increase in electrosynthesis over untreated carbon cloth cathodes was also achieved with polyaniline cathodes. However, not all strategies to provide positively charged surfaces were successful, as treatment of carbon cloth with melamine or ammonia gas did not stimulate acetate electrosynthesis. Treating carbon cloth with metal, in particular gold, palladium, or nickel nanoparticles, also promoted electrosynthesis, yielding electrosynthesis rates that were 6-,4.7- or 4.5-fold faster than the untreated control, respectively. Cathodes comprised of cotton or polyester fabric treated with carbon nanotubes yielded cathodes that supported acetate electrosynthesis rates that were similar to 3-fold higher than carbon cloth controls. Recovery of electrons consumed in acetate was similar to 80% for all materials. The results demonstrate that one approach to increase rates of carbon dioxide reduction in microbial electrosynthesis is to modify cathode surfaces to improve microbe-electrode interactions.

  4. 2013 Estorm - Invited Paper - Cathode Materials Review

    SciTech Connect (OSTI)

    Daniel, Claus; Mohanty, Debasish; Li, Jianlin; Wood III, David L

    2014-01-01

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403 431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783 789) demonstrated a high-energy and high-power LiCoO2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  5. Critical speed measurements in the Tevatron cold compressors

    SciTech Connect (OSTI)

    DeGraff, B.; Bossert, R.; Martinez, A.; Soyars, W.M.; /Fermilab

    2006-01-01

    The Fermilab Tevatron cryogenic system utilizes high-speed centrifugal cold compressors, manufactured by Ishikawajima-Harima Heavy Industries Co. Ltd. (IHI), for high energy operations. Nominal operating range for these compressors is 43,000 to 85,000 rpm. Past foil bearing failures prompted investigation to determine if critical speeds for operating compressors fall within operating range. Data acquisition hardware and software settings will be discussed for measuring liftoff, first critical and second critical speeds. Several tests provided comparisons between an optical displacement probe and accelerometer measurements. Vibration data and analysis of the 20 Tevatron ring cold compressors will be presented.

  6. Displacement Hull Catamaran July 26, 2006

    E-Print Network [OSTI]

    Wood, Stephen L.

    Systems for the funds given during the project, as well as Structural Composites Inc. of West Melbourne was to design and build a prototype displacement catamaran vessel to the scale of the existing planing catamaran was to test the displacement catamaran hull and acquire meaningful performance data using multi

  7. Field free, directly heated lanthanum boride cathode

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Moussa, David (San Francisco, CA); Wilde, Stephen B. (Pleasant Hill, CA)

    1991-01-01

    A directly heated cylindrical lanthanum boride cathode assembly is disclosed which minimizes generation of magnetic fields which would interfere with electron emission from the cathode. The cathode assembly comprises a lanthanum boride cylinder in electrical contact at one end with a central support shaft which functions as one electrode to carry current to the lanthanum boride cylinder and in electrical contact, at its opposite end with a second electrode which is coaxially position around the central support shaft so that magnetic fields generated by heater current flowing in one direction through the central support shaft are cancelled by an opposite magnetic field generated by current flowing through the lanthanum boride cylinder and the coaxial electrode in a direction opposite to the current flow in the central shaft.

  8. Filtered cathodic arc deposition apparatus and method

    DOE Patents [OSTI]

    Krauss, Alan R. (24461 W. Blvd. De John, Naperville, IL 60564)

    1999-01-01

    A filtered cathodic arc deposition method and apparatus for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

  9. Field free, directly heated lanthanum boride cathode

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Moussa, D.; Wilde, S.B.

    1987-02-02

    A directly heated cylindrical lanthanum boride cathode assembly is disclosed which minimizes generation of magnetic field which would interfere with electron emission from the cathode. The cathode assembly comprises a lanthanum boride cylinder in electrical contact at one end with a central support shaft which functions as one electrode to carry current to the lanthanum boride cylinder and in electrical contact, at its opposite end with a second electrode which is coaxially position around the central support shaft so that magnetic fields generated by heater current flowing in one direction through the central support shaft are cancelled by an opposite magnetic field generated by current flowing through the lanthanum boride cylinder and the coaxial electrode in a direction opposite to the current flow in the central shaft.

  10. Deuterium concentration and cold fusion; Rate distributions in palladium

    SciTech Connect (OSTI)

    Rogers, V.C.; Sandquist, G.M.; Nielson, K.K. )

    1989-12-01

    Cold fusion reactions and excess heat production have been reported in the electrolysis of heavy water with a palladium metal cathode. Solution of the standard diffusion equation for deuterium without fusion indicates that the deuterium concentration distribution rapidly becomes constant in the palladium lattice. Solution of the nonlinear diffusion equation for deuterium undergoing fusion also gives constant deuterium concentrations, suggesting that any fusion occurs uniformly throughout the palladium lattice. The hypothesis that fusion reactions occur predominantly at the palladium surface is shown to be inconsistent with experimental data.

  11. Synchrotron Investigations of SOFC Cathode Degradation

    SciTech Connect (OSTI)

    Idzerda, Yves

    2013-09-30

    The atomic variations occurring in cathode/electrolyte interface regions of La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3-?} (LSCF) cathodes and other SOFC related materials have been investigated and characterized using soft X-ray Absorption Spectroscopy (XAS) and diffuse soft X-ray Resonant Scattering (XRS). X-ray Absorption Spectroscopy in the soft X-ray region (soft XAS) is shown to be a sensitive technique to quantify the disruption that occurs and can be used to suggest a concrete mechanism for the degradation. For LSC, LSF, and LSCF films, a significant degradation mechanism is shown to be Sr out-diffusion. By using the XAS spectra of hexavalent Cr in SrCrO4 and trivalent Cr in Cr2O3, the driving factor for Sr segregation was identified to be the oxygen vacancy concentration at the anode and cathode side of of symmetric LSCF/GDC/LSCF heterostructures. This is direct evidence of vacancy induced cation diffusion and is shown to be a significant indicator of cathode/electrolyte interfacial degradation. X-ray absorption spectroscopy is used to identify the occupation of the A-sites and B-sites for LSC, LSF, and LSCF cathodes doped with other transition metals, including doping induced migration of Sr to the anti-site for Sr, a significant cathode degradation indicator. By using spatially resolved valence mapping of Co, a complete picture of the surface electrochemistry can be determined. This is especially important in identifying degradation phenomena where the degradation is spatially localized to the extremities of the electrochemistry and not the average. For samples that have electrochemical parameters that are measured to be spatially uniform, the Co valence modifications were correlated to the effects of current density, overpotential, and humidity.

  12. Development of Ultra-low Platinum Alloy Cathode Catalyst for...

    Energy Savers [EERE]

    Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells These slides were presented...

  13. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. esp13thackeray.pdf More Documents & Publications Design and Evaluation of High Capacity Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Design and...

  14. Asymmetric injection of cathodic arc plasma into a macroparticle filter

    E-Print Network [OSTI]

    Anders, Andre; MacGill, Robert A.

    2004-01-01

    setup. The cathodic arc plasma source is flange-mounted andfirewall" twist filter arc plasma source F IG. 1 Current (A)Injection of Cathodic Arc Plasma into a Macroparticle Filter

  15. Cathodic protection of pipelines in discontinuous permafrost

    SciTech Connect (OSTI)

    Mitchell, C.J.; Wright, M.D.; Waslen, D.W.

    1997-08-01

    This paper discusses the challenges in providing cathodic protection for a pipeline located in an area with discontinuous permafrost. Specific challenges included: unknown time for the permafrost to melt out, unpredictable current distribution characteristics and wet, inaccessible terrain. Based on preliminary pipe-to-soil data, it appears that cathodic protection coverage was achieved in discontinuous permafrost regions without the need of local anodes. Future work is required to verify whether this conclusion can be extended over the course of an annual freeze-thaw cycle.

  16. Tubular Membrane Cathodes for Scalable Power Generation in

    E-Print Network [OSTI]

    architecture that provides large surface areas for oxygen reduction at the cathode and bacteria growth, is a promising architecture that is intrinsically scalable for creating larger systems. Further increases and its use is sustainable (13). Exposing one side of the cathode to air (air cathode) has significantly

  17. High Surface Area Stainless Steel Brushes as Cathodes in Microbial

    E-Print Network [OSTI]

    High Surface Area Stainless Steel Brushes as Cathodes in Microbial Electrolysis Cells D O U G L show here that high surface area stainless steel brush cathodes produce hydrogen at rates. Using a stainless steel brush cathode with a specific surface area of 810 m2 /m3 , hydrogen was produced

  18. Scale model studies of displacement ventilation

    E-Print Network [OSTI]

    Okutan, Galip Mehmet

    1995-01-01

    Displacement ventilation is an air conditioning method that provides conditioned air to indoor environments with the goal to improve air quality while reducing energy consumption. This study investigates the performance ...

  19. Management of Internal Displacement in Nigeria

    E-Print Network [OSTI]

    Olagunju, Olajide

    This research examined the management of IDP’s (internally displaced persons) in Nigeria based on the February/May 2000 communal conflict at Kaduna, Northern Nigeria, as an example and a focus for the study. The research ...

  20. Displacement speeds in turbulent premixed flame simulations

    E-Print Network [OSTI]

    Day, Marcus S.; Shepherd, Ian G.; Bell, J.; Grcar, Joseph F.; Lijewski, Michael J.

    2008-01-01

    elds for reaction rate progress and ?uid velocity. Thefor the velocity ?elds and the scalar measure of reactionvelocity and the temperature. To evaluate the displacement speed we de?ne a reaction

  1. Bimetallic Cathode Materials for Lithium Based Batteries

    E-Print Network [OSTI]

    Bimetallic Cathode Materials for Lithium Based Batteries Frontiers in Materials Science Seminar / Chemistryg g g g g y University at Buffalo ­ The State University of New York (SUNY) Abstract Batteries/SVO batteries. A case study highlighting the rich chemistry and electrochemistry of the Li/SVO system providing

  2. Cathodic protection of pipelines in discontinuous permafrost

    SciTech Connect (OSTI)

    Mitchell, C.J.; Wright, M.D.; Waslen, D.W.

    1997-10-01

    There are many unknowns and challenges in providing cathodic protection (CP) for a pipeline located in discontinuous permafrost areas. Preliminary pipe-to-soil data indicates that CP coverage was achieved in these regions without needing local anodes. Work is required to verify whether this conclusion can be extended over the course of an annual freeze-thaw cycle.

  3. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

    2011-03-29

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La.sub.0.8Sr.sub.0.2CoO.sub.3) and lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1).

  4. A STOCHASTIC METHOD FOR MODELING FLUID DISPLACEMENT IN PETROLEUM RESERVOIRS

    E-Print Network [OSTI]

    Anderson, C.

    2011-01-01

    FLUID DISPLACEMENT IN PETROLEUM RESERVOIRS C. Anderson andFLUID DISPLACEMENT IN PETROLEUM RESERVOIRS C. Anderson andachieve optimal recovery of petroleum from a reservoir, it

  5. Carbon-containing cathodes for enhanced electron emission

    DOE Patents [OSTI]

    Cao, Renyu (Cupertino, CA); Pan, Lawrence (Pleasanton, CA); Vergara, German (Madrid, ES); Fox, Ciaran (Los Altos, CA)

    2000-01-01

    A cathode has electropositive atoms directly bonded to a carbon-containing substrate. Preferably, the substrate comprises diamond or diamond-like (sp.sup.3) carbon, and the electropositive atoms are Cs. The cathode displays superior efficiency and durability. In one embodiment, the cathode has a negative electron affinity (NEA). The cathode can be used for field emission, thermionic emission, or photoemission. Upon exposure to air or oxygen, the cathode performance can be restored by annealing or other methods. Applications include detectors, electron multipliers, sensors, imaging systems, and displays, particularly flat panel displays.

  6. Cathode R&D for Future Light Sources

    SciTech Connect (OSTI)

    Dowell, D.H.; Bazarov, I.; Dunham, B.; Harkay, K.; Hernandez-Garcia; Legg, R.; Padmore, H.; Rao, T.; Smedley, J.; Wan, W.

    2010-05-26

    This paper reviews the requirements and current status of cathodes for accelerator applications, and proposes a research and development plan for advancing cathode technology. Accelerator cathodes need to have long operational lifetimes and produce electron beams with a very low emittance. The two principal emission processes to be considered are thermionic and photoemission with the photocathodes being further subdivided into metal and semi-conductors. Field emission cathodes are not included in this analysis. The thermal emittance is derived and the formulas used to compare the various cathode materials. To date, there is no cathode which provides all the requirements needed for the proposed future light sources. Therefore a three part research plan is described to develop cathodes for these future light source applications.

  7. The effect of cathode geometry on barium transport in hollow cathode plasmas

    SciTech Connect (OSTI)

    Polk, James E. Mikellides, Ioannis G.; Katz, Ira; Capece, Angela M.

    2014-05-14

    The effect of barium transport on the operation of dispenser hollow cathodes was investigated in numerical modeling of a cathode with two different orifice sizes. Despite large differences in cathode emitter temperature, emitted electron current density, internal xenon neutral and plasma densities, and size of the plasma-surface interaction region, the barium transport in the two geometries is qualitatively very similar. Barium is produced in the insert and flows to the surface through the porous structure. A buildup of neutral Ba pressure in the plasma over the emitter surface can suppress the reactions supplying the Ba, restricting the net production rate. Neutral Ba flows into the dense Xe plasma and has a high probability of being ionized at the periphery of this zone. The steady state neutral Ba density distribution is determined by a balance between pressure gradient forces and the drag force associated with collisions between neutral Ba and neutral Xe atoms. A small fraction of the neutral Ba is lost upstream. The majority of the neutral Ba is ionized in the high temperature Xe plasma and is pushed back to the emitter surface by the electric field. The steady state Ba{sup +} ion density distribution results from a balance between electrostatic and pressure forces, neutral Xe drag and Xe{sup +} ion drag with the dominant forces dependent on location in the discharge. These results indicate that hollow cathodes are very effective at recycling Ba within the discharge and therefore maintain a high coverage of Ba on the emitter surface, which reduces the work function and sustains high electron emission current densities at moderate temperatures. Barium recycling is more effective in the cathode with the smaller orifice because the Ba is ionized in the dense Xe plasma concentrated just upstream of the orifice and pushed back into the hollow cathode. Despite a lower emitter temperature, the large orifice cathode has a higher Ba loss rate through the orifice because the Xe plasma density peaks further upstream.

  8. Cold spray nozzle design

    DOE Patents [OSTI]

    Haynes, Jeffrey D. (Stuart, FL); Sanders, Stuart A. (Palm Beach Gardens, FL)

    2009-06-09

    A nozzle for use in a cold spray technique is described. The nozzle has a passageway for spraying a powder material, the passageway having a converging section and a diverging section, and at least the diverging section being formed from polybenzimidazole. In one embodiment of the nozzle, the converging section is also formed from polybenzimidazole.

  9. Magnetron cathodes in plasma electrode Pockels cells

    DOE Patents [OSTI]

    Rhodes, M.A.

    1995-04-25

    Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal. 5 figs.

  10. Monitoring cathodic protection of well casings

    SciTech Connect (OSTI)

    Dabkowski, J.

    1980-01-01

    Because conventional downhole logging of gas storage wells to determine cathodic-protection levels is expensive and inconvenient, a program was developed (1) to predict downhole casing-to-soil potentials from wellhead measurements in the presence of interference and (2 )to model the mutual interference effects occurring between the wells and the cathodic-protection systems. In the first phase of this project, a transmission-line model that was developed to represent the well casing electrically adequately predicted the downhole potentials for both ideal and nonideal polarization conditions. By allowing the number of sections used and their parameter values as variables, the model can accommodate different environments and casing configurations. The model's representation of a well casing by a lumped-parameter electrical network will also permit interference studies between mutually coupled wells.

  11. NUMERICAL MODELING OF CATHODE CONTACT MATERIAL DENSIFICATION

    SciTech Connect (OSTI)

    Koeppel, Brian J.; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-11-01

    Numerical modeling was used to simulate the constrained sintering process of the cathode contact layer during assembly of solid oxide fuel cells (SOFCs). A finite element model based on the continuum theory for sintering of porous bodies was developed and used to investigate candidate low-temperature cathode contact materials. Constitutive parameters for various contact materials under investigation were estimated from dilatometry screening tests, and the influence of processing time, processing temperature, initial grain size, and applied compressive stress on the free sintering response was predicted for selected candidate materials. The densification behavior and generated stresses within a 5-cell planar SOFC stack during sintering, high temperature operation, and room temperature shutdown were predicted. Insufficient constrained densification was observed in the stack at the proposed heat treatment, but beneficial effects of reduced grain size, compressive stack preload, and reduced thermal expansion coefficient on the contact layer densification and stresses were observed.

  12. Displacement Echoes: Classical Decay and Quantum Freeze

    E-Print Network [OSTI]

    Cyril Petitjean; Diego V. Bevilaqua; Eric J. Heller; Philippe Jacquod

    2007-04-23

    Motivated by neutron scattering experiments, we investigate the decay of the fidelity with which a wave packet is reconstructed by a perfect time-reversal operation performed after a phase space displacement. In the semiclassical limit, we show that the decay rate is generically given by the Lyapunov exponent of the classical dynamics. For small displacements, we additionally show that, following a short-time Lyapunov decay, the decay freezes well above the ergodic value because of quantum effects. Our analytical results are corroborated by numerical simulations.

  13. Fiber-optic displacement sensor system 

    E-Print Network [OSTI]

    Cava, Norayda Nora

    1990-01-01

    FIBER-OPTIC DISPLACEMENT SENSOR SYSTEM A Thesis by NORAYDA NORA CAVA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1990 Major Subject...: Electrical Engineering FIBER-OPTIC DISPLACEMENT SENSOR SYSTEM A Thesis by NORAYDA NORA CAVA Approved as to style and content by: H nry F. Taylor (Chair of Committee) Brian Y ng (Member) Raghve n ey ( ember) Sohi Rastegar (Member) Jo owze (Head...

  14. Displacement Echoes: Classical Decay and Quantum Freeze

    SciTech Connect (OSTI)

    Petitjean, Cyril [Departement de Physique Theorique, Universite de Geneve, CH-1211 Geneva 4 (Switzerland); Bevilaqua, Diego V. [Department of Physics, Harvard University, Cambridge, Massachusetts 02138 (United States); Heller, Eric J. [Department of Physics, Harvard University, Cambridge, Massachusetts 02138 (United States); Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138 (United States); Jacquod, Philippe [Physics Department, University of Arizona, Tucson, Arizona 85721 (United States)

    2007-04-20

    Motivated by neutron scattering experiments, we investigate the decay of the fidelity with which a wave packet is reconstructed by a perfect time-reversal operation performed after a phase-space displacement. In the semiclassical limit, we show that the decay rate is generically given by the Lyapunov exponent of the classical dynamics. For small displacements, we additionally show that, following a short-time Lyapunov decay, the decay freezes well above the ergodic value because of quantum effects. Our analytical results are corroborated by numerical simulations.

  15. Cathode Ion Bombardment in RF Photoguns

    SciTech Connect (OSTI)

    Pozdeyev,E.; Kayran, D.; Litvinenko, V.

    2008-09-01

    In this paper, we use the method of rapid oscillating field to solve the equation of ion motion in an RF gun. We apply the method to the BNL 1/2-cell SRF photogun and demonstrate that a significant portion of ions produced in the gun can reach the cathode if no special precautions are taken. Also, the paper proposes a simple mitigation recipe that can reduce the rate of ion bombardment.

  16. Experimental investigation of a 1 kA/cm{sup 2} sheet beam plasma cathode electron gun

    SciTech Connect (OSTI)

    Kumar, Niraj Narayan Pal, Udit; Prajesh, Rahul; Prakash, Ram; Kumar Pal, Dharmendra

    2015-01-15

    In this paper, a cold cathode based sheet-beam plasma cathode electron gun is reported with achieved sheet-beam current density ?1 kA/cm{sup 2} from pseudospark based argon plasma for pulse length of ?200 ns in a single shot experiment. For the qualitative assessment of the sheet-beam, an arrangement of three isolated metallic-sheets is proposed. The actual shape and size of the sheet-electron-beam are obtained through a non-conventional method by proposing a dielectric charging technique and scanning electron microscope based imaging. As distinct from the earlier developed sheet beam sources, the generated sheet-beam has been propagated more than 190 mm distance in a drift space region maintaining sheet structure without assistance of any external magnetic field.

  17. Cathode power distribution system and method of using the same for power distribution

    DOE Patents [OSTI]

    Williamson, Mark A; Wiedmeyer, Stanley G; Koehl, Eugene R; Bailey, James L; Willit, James L; Barnes, Laurel A; Blaskovitz, Robert J

    2014-11-11

    Embodiments include a cathode power distribution system and/or method of using the same for power distribution. The cathode power distribution system includes a plurality of cathode assemblies. Each cathode assembly of the plurality of cathode assemblies includes a plurality of cathode rods. The system also includes a plurality of bus bars configured to distribute current to each of the plurality of cathode assemblies. The plurality of bus bars include a first bus bar configured to distribute the current to first ends of the plurality of cathode assemblies and a second bus bar configured to distribute the current to second ends of the plurality of cathode assemblies.

  18. Production of neutrals and their and effects on the ion charge states in cathodic vacuum arc plasmas

    E-Print Network [OSTI]

    Anders, Andre; Oks, Efim M.; Yushkov, Georgy Yu.

    2007-01-01

    states in cathodic vacuum arc plasmas André Anders a , EfimRussia Abstract Cathodic arc plasmas are considered fullybeen known that cathodic arc plasmas go through an initial

  19. Air Emissions and Oil Displacement Benefits

    E-Print Network [OSTI]

    McGaughey, Alan

    and the U.S. costs of oil consumption, including supply disruption risks, increases in world oil prices dueAir Emissions and Oil Displacement Benefits from Plug-in Vehicles The electrification of passenger; and (3) reduce gasoline consumption, helping to diminish dependency on imported oil. Current policy

  20. Wien's Displacement Law in Rindler Space

    E-Print Network [OSTI]

    De, Sanchari; Ghosh, Sutapa; Chakrabarty, Somenath

    2015-01-01

    In this article we have developed a formalism to obtained the modified form of Wien's displacement law when the wall of the enclosure containing a photon gas is expanding adiabatically with a uniform acceleration. We have also studied the gravitational redshift of photons inside the enclosure using the prescription of extended relativistic dynamics with an upper limit of acceleration.

  1. Coreflood experimental study of steam displacement 

    E-Print Network [OSTI]

    Cerutti, Andres Enrique

    1997-01-01

    The main objective of this study was to verify experimentally whether or not a Buckley-Leverett shock front exists when steam displaces oil in a porous medium, as assumed in the Aydelotte-Pope steamflood predictive model. Experiments were conducted...

  2. Scanning optical pyrometer for measuring temperatures in hollow cathodes

    SciTech Connect (OSTI)

    Polk, J. E.; Marrese-Reading, C. M.; Thornber, B.; Dang, L.; Johnson, L. K.; Katz, I.

    2007-09-15

    Life-limiting processes in hollow cathodes are determined largely by the temperature of the electron emitter. To support cathode life assessment, a noncontact temperature measurement technique which employs a stepper motor-driven fiber optic probe was developed. The probe is driven inside the hollow cathode and collects light radiated by the hot interior surface of the emitter. Ratio pyrometry is used to determine the axial temperature profile. Thermocouples on the orifice plate provide measurements of the external temperature during cathode operation and are used to calibrate the pyrometer system in situ with a small oven enclosing the externally heated cathode. The diagnostic method and initial measurements of the temperature distribution in a hollow cathode are discussed.

  3. Molten carbonate fuel cell cathode with mixed oxide coating

    SciTech Connect (OSTI)

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  4. Cold nuclear fusion

    SciTech Connect (OSTI)

    Tsyganov, E. N.

    2012-02-15

    Recent accelerator experiments on fusion of various elements have clearly demonstrated that the effective cross-sections of these reactions depend on what material the target particle is placed in. In these experiments, there was a significant increase in the probability of interaction when target nuclei are imbedded in a conducting crystal or are a part of it. These experiments open a new perspective on the problem of so-called cold nuclear fusion.

  5. Development of High-Capacity Cathode Materials with Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Development of High-Capacity Cathode Materials with Integrated Structures Vehicle Technologies Office Merit Review 2015: Design and Evaluation of High...

  6. Aliovalent Substitution in Mixed Ni-Mn-Co Oxide Cathodes

    E-Print Network [OSTI]

    Kam, Kinson C.

    2012-01-01

    batteries, cathode, transition metal oxides, aliovalent substitution Acknowledgment This work was supported by the Assistant Secretary for Energy Efficiency and Renewable

  7. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    s049thackeray2012p.pdf More Documents & Publications Design and Evaluation of High Capacity Cathodes Vehicle Technologies Office Merit Review 2014: Design and Evaluation of High...

  8. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Lithium Source For High Performance Li-ion Cells Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High Performance Li-ion Cells...

  9. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High Performance Li-ion Cells Lithium Source For...

  10. Multi-cathode metal vapor arc ion source

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); MacGill, Robert A. (645 Kern St., Richmond, CA 94805)

    1988-01-01

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. One embodiment of the appaatus utilizes a multi-cathode arrangement for interaction with the anode.

  11. The fractal nature of vacuum arc cathode spots

    E-Print Network [OSTI]

    Anders, Andre

    2005-01-01

    functions of vacuum arc plasmas," J. Appl. Phys. , vol. 93,macroparticles in vacuum arc plasmas," in preparation, 2005.A. Anders, Cathodic Arc Plasma Deposition: From Fractal

  12. Battery Cathode Developed by Argonne Powers Plug-in Electric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    capacities than conventional cathode materials, resulting in batteries with higher energy density. Because the batteries can store more energy, manufacturers can either use...

  13. Surface Characterization of the LCLS RF Gun Cathode

    SciTech Connect (OSTI)

    Brachmann, Axel; Decker, Franz-Josef; Ding, Yuantao; Dowell, David; Emma, Paul; Frisch, Josef; Gilevich, Sasha; Hays, Gregory; Hering, Philippe; Huang, Zhirong; Iverson, Richard; Loos, Henrik; Miahnahri, Alan; Nordlund, Dennis; Nuhn, Heinz-Dieter; Pianetta, Piero; Turner, James; Welch, James; White, William; Wu, Juhao; Xiang, Dao; /SLAC

    2012-06-25

    The first copper cathode installed in the LCLS RF gun was used during LCLS commissioning for more than a year. However, after high charge operation (> 500 pC), the cathode showed a decline of quantum efficiency within the area of drive laser illumination. They report results of SEM, XPS and XAS studies that were carried out on this cathode after it was removed from the gun. X-ray absorption and X-ray photoelectron spectroscopy reveal surface contamination by various hydrocarbon compounds. In addition they report on the performance of the second installed cathode with emphasis on the spatial distribution of electron emission.

  14. LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles

    E-Print Network [OSTI]

    Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-01-01

    58757 INTRODUCTION For practical SOFC cathodes, the selectedthe high temperatures where SOFC membranes are fabricated.costs, lowering of the SOFC operating temperatures has been

  15. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

    2011-04-05

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of Perovskite AMeO.sub.3, wherein A is at least one of lanthanum and a combination of lanthanum and strontium and Me is one or more of transition metals, lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1) and X-doped LiMeO.sub.2, wherein X is one of Mg, Ca, and Co.

  16. Fidelity Decay for Phase Space Displacements

    E-Print Network [OSTI]

    Diego V. Bevilaqua; Eric J. Heller

    2004-09-03

    In this letter we analyse the behavior of fidelity decay under a very specific kind of perturbation: phase space displacements. Under these perturbations, systems will decay following the Lyapunov regime only. Others universal regimes discussed in the literature are not presented in this case; instead, for small values of the perturbation we observe quantum freeze of the fidelity. We also show that it is possible to connect this result with the incoherent neutron scattering problem

  17. Peregrinations on cold fusion

    SciTech Connect (OSTI)

    Turner, L.

    1989-01-01

    Attention is focused on the possibility of resonance-enhanced deuteron Coulomb barrier penetration. Because of the many-body nature of the interactions of room-temperature deuterons diffusing through a lattice possessing deuterons in many of the interstitial positions, the diffusing deuterons can resonate on the atomic scale in the potential wells bounded by the ascending walls of adjacent Coulomb barriers and thereby penetrate the Coulomb barriers in a fashion vastly underestimated by two-body calculations in which wells for possible resonance are absent. Indeed, perhaps the lack of robust reproducibility in cold fusion originates from the narrowness of such transmission resonances. 4 refs., 1 fig.

  18. Material and Energy Flows in the Production of Cathode and Anode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Title Material and Energy Flows in the Production of Cathode and Anode...

  19. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01

    O 2 Cathode Material in Lithium Ion Batteries. Adv. Energysolvent decomposition in lithium ion batteries: first-Cathode Materials for Lithium-Ion Batteries. Adv. Funct.

  20. Self-contained hot-hollow cathode gun source assembly

    DOE Patents [OSTI]

    Zeren, J.D.

    1984-08-01

    A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

  1. Self-contained hot-hollow cathode gun source assembly

    DOE Patents [OSTI]

    Zeren, Joseph D. (Boulder, CO)

    1986-01-01

    A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

  2. Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode

    E-Print Network [OSTI]

    Sethuraman, Vijay A.

    Hydrogen Peroxide Formation Rates in a PEMFC Anode and Cathode Effect of Humidity and Temperature Hydrogen peroxide H2O2 formation rates in a proton exchange membrane fuel cell PEMFC anode and cathode were, has the capability to be the structural and fundamental unit of an impending hydrogen economy. Two

  3. Nanofiber Scaffold for Cathode of Solid Oxide Fuel Cell

    SciTech Connect (OSTI)

    Mingjia Zhi; Nicholas Mariani; Randall Gemmen; Kirk Gerdes; Nianqiang Wu

    2010-10-01

    A high performance solid oxide fuel cell cathode using the yttria-stabilized zirconia (YSZ) nanofibers scaffold with the infiltrated La1-xSrxMnO3 (LSM) shows an enhanced catalytic activity toward oxygen reduction. Such a cathode offers a continuous path for charge transport and an increased number of triple-phase boundary sites.

  4. Carbon Dioxide Addition to Microbial Fuel Cell Cathodes Maintains

    E-Print Network [OSTI]

    Angenent, Lars T.

    Carbon Dioxide Addition to Microbial Fuel Cell Cathodes Maintains Sustainable Catholyte p losses and, therefore, power losses. Here, we report that adding carbon dioxide (CO2) gas to the cathode and sustainable energy from wastewaters, replace energy intensive wastewater treatment processes, and produce

  5. Focused cathode design to reduce anode heating during vircator operation

    SciTech Connect (OSTI)

    Lynn, Curtis F.; Dickens, James C.; Neuber, Andreas A.

    2013-10-15

    Virtual cathode oscillators, or vircators, are a type of high power microwave device which operates based on the instability of a virtual cathode, or cloud of electrons, which forms when electron current injected into the drift tube exceeds the space charge limited current within the drift tube. Anode heating by the electron beam during vircator operation ultimately limits achievable pulse lengths, repetition rates, and the duration of burst mode operation. This article discusses a novel cathode design that focuses electrons through holes in the anode, thus significantly reducing anode heating by the electrons emitted from the cathode during the first transit through the A-K gap. Reflexing electrons continue to deposit energy on the anode; however, the discussed minimization of anode heating by main beam electrons has the potential to enable higher repetition rates as well as efficiency and longer diode lifetime. A simulation study of this type of cathode design illustrates possible advantages.

  6. Visualization and simulation of immiscible displacement in fractured systems using micromodels: Steam injection

    SciTech Connect (OSTI)

    Yortsos, Y.C.

    1995-07-01

    A study of steam and hot water injection processes in micromodel geometries that mimic a matrix-fracture system was undertaken. The followings were observed: Light components existing in the crude oil generated a very high efficient gas-drive at elevated temperatures. This gas generation in conjunction with natural surfactant existing in the crude oil, lead to the formation of a foam in the fracture and to improved displacement in the matrix. We observed that the steam enters the fracture and the matrix depending on whether the steam rate exceeds or not the critical values. The resulting condensed water also moves preferentially into the matrix or the fracture depending on the corresponding capillary number. Since steam is a non-wetting phase as a vapor, but becomes a wetting phase when condensed in a water-wet system, steam injection involves both drainage and imbibition. It was found that all of the oil trapped by the condensed water can be mobilized and recovered when in contact with steam. We also examined hot-water displacement. In comparison with cold-water experiments at the same capillary number, a higher sweep efficiency for both light and heavy oils was observed. It was found that the loam generated in the fracture during hot-water injection, is more stable than in steamflooding. Nonetheless, hot-water injection resulted into less efficient displacement in its absence.

  7. Two-dimensional modeling of the cathode sheath formation during the streamer-cathode interaction

    SciTech Connect (OSTI)

    Yan, Wen; Sang, Chaofeng; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Liu, Fucheng [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)] [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2014-01-15

    In this paper, a computational simulation of the sheath formation during the streamer-surface interaction at atmospheric pressure is presented. A two-dimensional fluid model of a point-to-plane configuration is applied to investigate the evolution of the discharge in the vicinity of cathode plane. The effects of the surfaces on the properties of streamer have been studied for three cases, i.e., conductive surface with secondary electron emission (SEE), conductive surface without SEE, and dielectric surface. In all cases, we found that the axial propagation velocity of the streamer front decreases as the streamer arrives at the boundary of the cathode sheath. And the simulation results showed that the properties of the surface have a significant effect on the streamer. Besides the influences, the secondary emission coefficient and the relative permittivity on the streamer-surface interactions are also studied.

  8. Superconducting inductive displacement detection of a microcantilever

    SciTech Connect (OSTI)

    Vinante, A., E-mail: anvinante@fbk.eu [Istituto di Fotonica e Nanotecnologie, CNR - Fondazione Bruno Kessler, I-38123 Povo, Trento (Italy)

    2014-07-21

    We demonstrate a superconducting inductive technique to measure the displacement of a micromechanical resonator. In our scheme, a type I superconducting microsphere is attached to the free end of a microcantilever and approached to the loop of a dc Superconducting Quantum Interference Device (SQUID) microsusceptometer. A local magnetic field as low as 100??T, generated by a field coil concentric to the SQUID, enables detection of the cantilever thermomechanical noise at 4.2?K. The magnetomechanical coupling and the magnetic spring are in good agreement with image method calculations assuming pure Meissner effect. These measurements are relevant to recent proposals of quantum magnetomechanics experiments based on levitating superconducting microparticles.

  9. Displacement Transfer Zone | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstrumentsArea (DOE GTP)Displacement Transfer Zone Jump to:

  10. Cold isopressing method

    DOE Patents [OSTI]

    Chen, Jack C. (Getzville, NY); Stawisuck, Valerie M. (North Tonawanda, NY); Prasad, Ravi (East Amherst, NY)

    2003-01-01

    A cold isopressing method in which two or more layers of material are formed within an isopressing mold. One of the layers consists of a tape-cast film. The layers are isopressed within the isopressing mold, thereby to laminate the layers and to compact the tape-cast film. The isopressing mold can be of cylindrical configuration with the layers being coaxial cylindrical layers. The materials used in forming the layers can contain green ceramic materials and the resultant structure can be fired and sintered as necessary and in accordance with known methods to produce a finished composite, ceramic structure. Further, such green ceramic materials can be of the type that are capable of conducting hydrogen or oxygen ions at high temperature with the object of utilizing the finished composite ceramic structure as a ceramic membrane element.

  11. Cathodic Vacuum Arc Plasma of Thallium

    SciTech Connect (OSTI)

    Yushkov, Georgy Yu.; Anders, Andre

    2006-10-02

    Thallium arc plasma was investigated in a vacuum arc ionsource. As expected from previous consideration of cathode materials inthe Periodic Table of the Elements, thallium plasma shows lead-likebehavior. Its mean ion charge state exceeds 2.0 immediately after arctriggering, reaches the predicted 1.60 and 1.45 after about 100 microsecand 150 microsec, respectively. The most likely ion velocity is initially8000 m/s and decays to 6500 m/s and 6200 m/s after 100 microsec and 150microsec, respectively. Both ion charge states and ion velocities decayfurther towards steady state values, which are not reached within the 300microsec pulses used here. It is argued that the exceptionally high vaporpressure and charge exchange reactions are associated with theestablishment of steady state ion values.

  12. Mixed polyanion glass cathodes: Iron phosphate vanadate glasses

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

    2014-01-01

    Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

  13. High Performance Cathodes for Li-Air Batteries

    SciTech Connect (OSTI)

    Xing, Yangchuan

    2013-08-22

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  14. Performance of field emission cathodes in xenon environments

    SciTech Connect (OSTI)

    Marrese, C.M.; Polk, J.E.; Jensen, K.L.; Gallimore, A.D.; Spindt, C.; Fink, R.L.; Tolt, Z.L.; Palmer, W.D.

    1999-07-01

    Field emission (FE) cathodes are currently being considered to supply electrons in electric propulsion systems for propellant ionization and ion beam neutralization. Hollow cathodes with thermionic electron emitters typically used with Hall and ion thrusters require propellant and heaters for operation. Therefore there are lower limits on their size and power. Because FE cathodes do not require propellant or heaters they can be used with small and micropropulsion systems. The primary concern with integrating these two technologies is cathode lifetime. An FE cathode must be capable of operation in a plasma environment where xenon pressures exceed 2 x 10{sup {minus}6} Torr. Experiments were conducted at the Jet Propulsion Laboratory to evaluate the performance of silicon and molybdenum microtip field emission array cathodes, and carbon film cathodes in xenon pressures up to 2 x 10{sup {minus}5} Torr. Experimental and modeling results were used to determine energy thresholds for sputtering silicon and molybdenum by xenon ions. Experiments and theoretical results are presented for performance degradation in xenon environments.

  15. Investigation of cold fusion phenomena in deuterated metals. Final report, Volume 1. Overview, executive summary, chemistry, physics, gas reactions, metallurgy. Technical information series

    SciTech Connect (OSTI)

    Anderson, L.; Barrowes, S.C.; Bergeson, H.E.; Bourgeois, F.; Cedzynska, K.

    1991-06-01

    The March 1989 announcement by Pons and Fleischmann stimulated worldwide interest in the cold fusion phenomenon. In Utah the legislature appropriated $5 million to support cold fusion research and development. As cold fusion inquiries continue worldwide, this interim report has been written to document the scientific and legal work that has been funded by the Utah legislature. Partial contents include these titles of papers: Cold Fusion Studies in a High-Pressure Sealed Cell; Tritium and Neutron Generation in Palladium Cathodes with High Deuterium Loading; Deuterium-Gas Phase Reactions on Palladium; Excess Heat Estimation with the Kalman Filter; Ultrasonic Energy Effects on Palladium Electrodes in Cold Fusion Cells; Nuclear Measurements on Deuterium-Loaded Palladium and Titanium.

  16. The Evolution and Life Cycle of Valley Cold Pools

    E-Print Network [OSTI]

    Wilson, Travis Harold

    2015-01-01

    Pools . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .Pools . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4 Adiabatic Cold Pools . . . . . . . . . . . . . . . . . . .

  17. Characterization of plasma chemistry and ion energy in cathodic arc plasma from Ti-Si cathodes of different compositions

    SciTech Connect (OSTI)

    Eriksson, A. O.; Zhirkov, I.; Dahlqvist, M.; Jensen, J.; Hultman, L.; Rosen, J.

    2013-04-28

    Arc plasma from Ti-Si compound cathodes with up to 25 at. % Si was characterized in a DC arc system with respect to chemistry and charge-state-resolved ion energy. The plasma ion composition showed a lower Si content, diverging up to 12 at. % compared to the cathode composition, yet concurrently deposited films were in accordance with the cathode stoichiometry. Significant contribution to film growth from neutrals is inferred besides ions, since the contribution from macroparticles, estimated by scanning electron microscopy, cannot alone account for the compositional difference between cathode, plasma, and film. The average ion charge states for Ti and Si were higher than reference data for elemental cathodes. This result is likely related to TiSi{sub x} phases of higher cohesive energies in the compound cathodes and higher effective electron temperature in plasma formation. The ion energy distributions extended up to {approx}200 and {approx}130 eV for Ti and Si, respectively, with corresponding average energies of {approx}60 and {approx}30 eV. These averages were, however, not dependent on Si content in the cathode, except for 25 at. % Si where the average energies were increased up to 72 eV for Ti and 47 eV for Si.

  18. Illinois: High-Energy, Concentration-Gradient Cathode Material...

    Office of Environmental Management (EM)

    plug-in hybrid and all-electric vehicles. Unlike existing cathodes used in lithium (Li)-ion batteries on the market, this cell has an outer shell that separates the very reactive...

  19. ENVIRONMENTAL BIOTECHNOLOGY Brewery wastewater treatment using air-cathode

    E-Print Network [OSTI]

    ENVIRONMENTAL BIOTECHNOLOGY Brewery wastewater treatment using air-cathode microbial fuel cells using actual wastewaters. The efficiency of wastewater treatment of a beer brewery wastewater to solution conductivity. These results show that brewery wastewater can be effectively treated using MFCs

  20. Characterization of New Cathode Materials using Synchrotron-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techniques Characterization of New Cathode Materials using Synchrotron-based X-ray Techniques Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008...

  1. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01

    Alloy design for lithium-ion battery anodes. J. Electrochem.advances in lithium ion battery materials. Electrochim. ActaO 2 cathode material for lithium ion battery: Dependence of

  2. Characterization of New Cathode Materials using Synchrotron-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Cathode Materials using Synchrotron-based X-ray Techniques and the Studies of Li-Air Batteries 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review...

  3. Centrifugal deterministic lateral displacement separation system

    E-Print Network [OSTI]

    Mingliang Jiang; Aaron D. Mazzeo; German Drazer

    2015-07-22

    This work investigates the migration of spherical particles of different sizes in a centrifuge-driven deterministic lateral displacement (c-DLD) device. Specifically, we use a scaled-up model to study the motion of suspended particles through a square array of cylindrical posts under the action of centrifugation. Experiments show that separation of particles by size is possible depending on the orientation of the driving acceleration with respect to the array of posts (forcing angle). We focus on the fractionation of binary suspensions and measure the separation resolution at the outlet of the device for different forcing angles. We found excellent resolution at intermediate forcing angles, when large particles are locked to move at small migration angles but smaller particles follow the forcing angle more closely. Finally, we show that reducing the initial concentration (number) of particles, approaching the dilute limit of single particles, leads to increased resolution in the separation.

  4. Centrifugal deterministic lateral displacement separation system

    E-Print Network [OSTI]

    Jiang, Mingliang; Drazer, German

    2015-01-01

    This work investigates the migration of spherical particles of different sizes in a centrifuge-driven deterministic lateral displacement (c-DLD) device. Specifically, we use a scaled-up model to study the motion of suspended particles through a square array of cylindrical posts under the action of centrifugation. Experiments show that separation of particles by size is possible depending on the orientation of the driving acceleration with respect to the array of posts (forcing angle). We focus on the fractionation of binary suspensions and measure the separation resolution at the outlet of the device for different forcing angles. We found excellent resolution at intermediate forcing angles, when large particles are locked to move at small migration angles but smaller particles follow the forcing angle more closely. Finally, we show that reducing the initial concentration (number) of particles, approaching the dilute limit of single particles, leads to increased resolution in the separation.

  5. Optical inverse-square displacement sensor

    DOE Patents [OSTI]

    Howe, R.D.; Kychakoff, G.

    1989-09-12

    This invention comprises an optical displacement sensor that uses the inverse-square attenuation of light reflected from a diffused surface to calculate the distance from the sensor to the reflecting surface. Light emerging from an optical fiber or the like is directed onto the surface whose distance is to be measured. The intensity I of reflected light is angle dependent, but within a sufficiently small solid angle it falls off as the inverse square of the distance from the surface. At least a pair of optical detectors are mounted to detect the reflected light within the small solid angle, their ends being at different distances R and R + [Delta]R from the surface. The distance R can then be found in terms of the ratio of the intensity measurements and the separation length as given in an equation. 10 figs.

  6. Preparation of redox polymer cathodes for thin film rechargeable batteries

    DOE Patents [OSTI]

    Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

    1994-11-08

    The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

  7. Investigations of the deuterium-deuterium fusion reaction in cast, annealed, and cold-rolled palladium

    SciTech Connect (OSTI)

    Ilic, R.; Rant, J.; Sutej, T.; Dobersek, M.; Kristof, E.; Skvarc, J.; Kozelj, M. )

    1990-11-01

    This paper reports on a search conducted for neutrons, protons, tritons, {sup 3}He ions, gamma rays, and ion-induced X-rays from deuterium-deuterium (D-D) fusion in cast (36-g), annealed (4-g), and cold-rolled (16-g) palladium specimens and a palladium hydrogen thermal valve (11 g) electrochemically charged with deuterium. The palladium cathodes were charged in an electrolytic cell (0.1 M LiOD (99.8% deuterium), platinum anode) at a current density of 25 mA/cm{sup 2} from 20 to 140 h.

  8. Low energy properties of the random displacement model

    E-Print Network [OSTI]

    Jeff Baker; Michael Loss; Günter Stolz

    2008-08-05

    We study low-energy properties of the random displacement model, a random Schr\\"odinger operator describing an electron in a randomly deformed lattice. All periodic displacement configurations which minimize the bottom of the spectrum are characterized. While this configuration is essentially unique for dimension greater than one, there are infinitely many different minimizing configurations in the one-dimensional case. The latter leads to unusual low energy asymptotics for the integrated density of states of the one-dimensional random displacement model. For symmetric Bernoulli-distributed displacements it has a $1/\\log^2$-singularity at the bottom of the spectrum. In particular, it is not H\\"older-continuous.

  9. Operator Splitting for Compressible Miscible Displacement in Porous Media

    E-Print Network [OSTI]

    Douglas Jr., Jim

    , relevant for tertiary recovery in petroleum reservoirs, have been related to incompressible ow problems. The numerical approximation of incom- pressible miscible displacement has been carefully investigated

  10. Cathodic Protection of the Yaquina Bay Bridge

    SciTech Connect (OSTI)

    Bullard, Sophie J.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Laylor, H.M.; Cryer, C.B.

    2001-02-01

    The Yaquina Bay Bridge in Newport, Oregon, was designed by Conde B. McCullough and built in 1936. The 3,223-foot (982 m) structure is a combination of concrete arch approach spans and a steel through arch over the shipping channel. Cathodic protection is used to prevent corrosion damage to the concrete arches. The Oregon Department of Transportation (Oregon DOT) installed a carbon anode coating (DAC-85) on two of the north approach spans in 1985. This anode was operated at a current density of 6.6 mA/m2(0.6 mA/ft2). No failure of the conductive anode was observed in 1990, five years after application, or in 2000, 15 years after application. Thermal-sprayed zinc anodes 20 mils (0.5 mm) thick were applied to half the south approach spans beginning in 1990. Thermal-sprayed zinc anodes 15 mils (0.4 mm) thick were applied to the remaining spans in 1996. These anodes were operated at a current density of 2.2 mA/m2(0.2 mA/ft2). In 1999, four zones on the approach spans were included in a two-year field trial of humectants to improve zinc anode performance. The humectants LiNO3 and LiBr were applied to two zones; the two adjacent zones were left untreated as controls. The humectants substantially reduced circuit resistance compared to the controls.

  11. Development and evaluation of carbon and binder loading in low-cost activated carbon cathodes for air-cathode microbial fuel cells{

    E-Print Network [OSTI]

    for air-cathode microbial fuel cells{ Bin Wei,a Justin C. Tokash,a Guang Chen,ab Michael A. Hicknerb fuel cell (MFC) can be used to generate electricity from many different organic and inorganic, and then to 890 ¡ 20 mW m22 after 5 months. Cathode performance was optimized for all cathodes by using the least

  12. NASA Cold Land Processes Field Experiment

    E-Print Network [OSTI]

    NASA Cold Land Processes Field Experiment Overview and Preliminary Results NASA Cold Land Processes Field Experiment Overview and Preliminary Results NASA Cold Land ProcessesNASA Cold Land Processes Field properties using active and passive microwave remote sensing. NASA DC-8 Airborne Laboratory with AIRSAR

  13. Cold War Entanglements of Social ANDY BYFORD

    E-Print Network [OSTI]

    Solovey, Mark

    REVIEW Cold War Entanglements of Social Science ANDY BYFORD MLAC, Durham University, UK Cold War.00. The Cold War era the three decades between the end of the Second World War and the end of the Vietnam War of `America' s Cold War' (Farish, 2010). More speci cally, it focuses on the multiple ambiguous `entanglements

  14. INFLUENCE OF MASS ON DISPLACEMENT THRESHOLD

    SciTech Connect (OSTI)

    Setyawan, Wahyu; Selby, A.; Nandipati, Giridhar; Roche, Kenneth J.; Kurtz, Richard J.; Wirth, Brian D.

    2014-12-30

    Molecular dynamics simulations are performed to investigate the effect of mass on displacement threshold energy in Cr, Mo, Fe and W. For each interatomic potential, the mass of the atoms is varied among those metals for a total of 16 combinations. The average threshold energy over all crystal directions is calculated within the irreducible crystal directions using appropriate weighting factors. The weighting factors account for the different number of equivalent directions among the grid points and the different solid angle coverage of each grid point. The grid points are constructed with a Miller index increment of 1/24 for a total of 325 points. For each direction, 10 simulations each with a different primary-knock-on atom are performed. The results show that for each interatomic potential, the average threshold energy is insensitive to the mass; i.e., the values are the same within the standard error. In the future, the effect of mass on high-energy cascades for a given interatomic potential will be investigated.

  15. Gage for measuring displacements in rock samples

    DOE Patents [OSTI]

    Holcomb, David J. (Albuquerque, NM); McNamee, Michael J. (Albuquerque, NM)

    1986-01-01

    A gage for measuring diametral displacement within a rock sample for use in a rock mechanics laboratory and in the field, comprises a support ring housing a linear variable differential transformer, a mounting screw, and a leaf spring. The mounting screw is adjustable and defines a first point of contact with the rock sample. The leaf spring has opposite ends fixed to the inner periphery of the mounting ring. An intermediate portion of the leaf spring projecting radially inward from the ring is formed with a dimple defining a second point of contact with the sample. The first and second points of contact are diametrically opposed to each other. The LVDT is mounted in the ring with its axis parallel to the line of measurement and its core rod received in the dimple of the leaf spring. Any change in the length of the line between the first and second support points is directly communicated to the LVDT. The leaf spring is rigid to completely support lateral forces so that the LVDT is free of all load for improved precision.

  16. Gage for measuring displacements in rock samples

    DOE Patents [OSTI]

    Holcomb, D.J.; McNamee, M.J.

    1985-07-18

    A gage for measuring diametral displacement within a rock sample for use in a rock mechanics laboratory and in the field, comprises a support ring housing a linear variable differential transformer (LVDT), a mounting screw, and a leaf spring. The mounting screw is adjustable and defines a first point of contact with the rock sample. The leaf spring has opposite ends fixed to the inner periphery of the mounting ring. An intermediate portion of the leaf spring projecting radially inward from the ring is formed with a dimple defining a second point of contact with the sample. The first and second points of contact are diametrically opposed to each other. The LVDT is mounted in the ring with its axis parallel to the line of measurement and its core rod received in the dimple of the leaf spring. Any change in the length of the line between the first and second support points is directly communicated to the LVDT. The leaf spring is rigid to completely support lateral forces so that the LVDT is free of all load for improved precision.

  17. Atomic displacements due to spinspin repulsion in conjugated alternant hydrocarbons

    E-Print Network [OSTI]

    Benzi, Michele

    Atomic displacements due to spin­spin repulsion in conjugated alternant hydrocarbons Ernesto-induced atomic displacements in conjugated alt- ernant hydrocarbons. It appears to be responsible alternant hydrocarbons (CAHs) have played a fun- damental role in the development of theoretical chemistry

  18. Functionally Graded Cathodes for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

    2008-04-30

    The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts would be most effective for LSCF, and how to achieve further enhancement of the performance and stability of SOFC cathodes.

  19. Asymmetric injection of cathodic arc plasma into a macroparticlefilter

    SciTech Connect (OSTI)

    Anders, Andre; MacGill, Robert A.

    2004-02-11

    The cathodic arc plasmas produced by cathode spots usuallyinclude macroparticles, which is undesirable for many applications. Acommon way of removing macroparticles is to use curved solenoid filterswhich guide the plasma from the source to the substrate. In this work, anarc source with relatively small cathode is used, limiting the possiblelocations of plasma production. The relative position of cathodic arcsource and macroparticle filtered was systematically varied and thefiltered plasma current was recorded. It was found that axis-symmetricplasma injection leads to maximum throughput only if an anode aperturewas used, which limited the plasma to near-axis flow by scraping offplasma at larger angles to the axis. When the anode aperture was removed,more plasma could enter the filter. In this case, maximum filtered ioncurrent was achieved when the plasma was injected off-axis, namely offsetin the direction where the filter is curved. Such behavior wasanticipated because the plasma column in the filter is known to beshifted by ExB and centrifugal drift as well as by non-axis-symmetriccomponents of the magnetic field in the filter entrance and exit plane.The data have implications for plasma transport variations caused bydifferent spot locations on cathodes that are not small compared to thefilter cross section.

  20. Improved structural and electrical properties of thin ZnO:Al films by dc filtered cathodic arc deposition

    E-Print Network [OSTI]

    Zhu, Yuankun

    2013-01-01

    scale heating in cathodic arc plasma deposition. Appl. Phys.using filtered cathodic arc plasmas. Vacuum 67 673 (2002).to rid cathodic arc plasma of macro- and nanoparticles: a

  1. Characteristic of a triple-cathode vacuum arc plasma source

    SciTech Connect (OSTI)

    Xiang, W.; Li, M.; Chen, L.

    2012-02-15

    In order to generate a better ion beam, a triple-cathode vacuum arc plasma source has been developed. Three plasma generators in the vacuum arc plasma source are equally located on a circle. Each generator initiated by means of a high-voltage breakdown between the cathode and the anode could be operated separately or simultaneously. The arc plasma expands from the cathode spot region in vacuum. In order to study the behaviors of expanding plasma plume generated in the vacuum arc plasma source, a Langmuir probe array is employed to measure the saturated ion current of the vacuum arc plasma source. The time-dependence profiles of the saturated current density of the triple vacuum arc plasma source operated separately and simultaneously are given. Furthermore, the plasma characteristic of this vacuum arc plasma source is also presented in the paper.

  2. Process system and method for fabricating submicron field emission cathodes

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Hayes, Jeffrey P. (Ripon, CA)

    1998-01-01

    A process method and system for making field emission cathodes exists. The deposition source divergence is controlled to produce field emission cathodes with height-to-base aspect ratios that are uniform over large substrate surface areas while using very short source-to-substrate distances. The rate of hole closure is controlled from the cone source. The substrate surface is coated in well defined increments. The deposition source is apertured to coat pixel areas on the substrate. The entire substrate is coated using a manipulator to incrementally move the whole substrate surface past the deposition source. Either collimated sputtering or evaporative deposition sources can be used. The position of the aperture and its size and shape are used to control the field emission cathode size and shape.

  3. LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles

    SciTech Connect (OSTI)

    Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ.; De Jonghe, Lutgard C.

    2006-01-31

    To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.

  4. Carbonaceous cathode with enhanced wettability for aluminum production

    DOE Patents [OSTI]

    Keller, Rudolf; Gatty, David G.; Barca, Brian J.

    2003-09-09

    A method of preparing carbonaceous blocks or bodies for use in a cathode in an electrolytic cell for producing aluminum wherein the cell contains an electrolyte and has molten aluminum contacting the cathode, the cathode having improved wettability with molten aluminum. The method comprises the steps of providing a carbonaceous block and a boron oxide containing melt. The carbonaceous block is immersed in the melt and pressure is applied to the melt to impregnate the melt into pores in the block. Thereafter, the carbonaceous block is withdrawn from the melt, the block having boron oxide containing melt intruded into pores therein, the boron oxide capable of reacting with a source of titanium or zirconium or like metal to form titanium or zirconium diboride during heatup or operation of said cell.

  5. Cold Spring Harbor Laboratory Cold Spring Harbor Laboratory

    E-Print Network [OSTI]

    and educational institution founded 1890 980 staff members Seven divisions ·Research (cancer, neuroscience, plant, located at Cold Spring Harbor, Plymouth (UK), Tuebingen (Germany) and San Diego. Over 200 books in print ·Finding appropriate authors/editors for new books ·Preparing a proposal for the book ·Outline / Table

  6. Puzzling differences in bismuth and lead plasmas: evidence for the significant role of neutrals in cathodic vacuum arcs

    E-Print Network [OSTI]

    Anders, Andre; Yushkov, Georgy Yu.

    2007-01-01

    for Pb and Bi cathodic arc plasmas revealed unexpectedCathodic vacuum arc plasmas are generally considered to beand (iv) the condensing arc plasma itself, because non-

  7. A comparison of the marginal adaptation of cathode-arc vapor-deposited titanium and cast base metal copings.

    E-Print Network [OSTI]

    Wu, Jean C; Lai, Li-Chung; Sheets, Cherilyn G; Earthman, James; Newcomb, Robert

    2011-01-01

    of Prosthetic Dentistry plasma arc on the cathode surface.arc deposition consists of a titanium cathode material and metal plasma

  8. Mo-containing tetrahedral amorphous carbon deposited by dual filtered cathodic vacuum arc with selective pulsed bias voltage

    E-Print Network [OSTI]

    Pasaja, Nitisak; Sansongsiri, Sakon; Intasiri, Sawate; Vilaithong, Thiraphat; Anders, Andre

    2007-01-01

    filtered cathodic vacuum arc plasma sources with selectivedual filtered cathodic vacuum arc plasma sources operated inrepetitively pulsed vacuum arc plasma sources operating in

  9. SHEAR STRENGTH MEASURING EQUIPMENT EVALUATION AT THE COLD TEST FACILITY

    SciTech Connect (OSTI)

    MEACHAM JE

    2009-09-09

    Retrievals under current criteria require that approximately 2,000,000 gallons of double-shell tank (DST) waste storage space not be used to prevent creating new tanks that might be susceptible to buoyant displacement gas release events (BDGRE). New criteria are being evaluated, based on actual sludge properties, to potentially show that sludge wastes do not exhibit the same BDGRE risk. Implementation of the new criteria requires measurement of in situ waste shear strength. Cone penetrometers were judged the best equipment for measuring in situ shear strength and an A.P. van den berg Hyson 100 kN Light Weight Cone Penetrometer (CPT) was selected for evaluation. The CPT was procured and then evaluated at the Hanford Site Cold Test Facility. Evaluation demonstrated that the equipment with minor modification was suitable for use in Tank Farms.

  10. Activation of a MnO2 cathode by water-stimulated Mg2+ insertion...

    Office of Scientific and Technical Information (OSTI)

    Activation of a MnO2 cathode by water-stimulated Mg2+ insertion for a magnesium ion battery Citation Details In-Document Search Title: Activation of a MnO2 cathode by...

  11. Investigation of non-hydrogenated DLC:Si prepared by cathodic arc

    E-Print Network [OSTI]

    Monteiro, Othon R.; Delplancke-Ogletree, Marie-Paule

    2002-01-01

    source filtered cathodic arc plasma, and the mechanical andpulse. Typical arc current in the plasma sources were 250 Athe cathodic arc source is 1.4 (the plasma stream consists

  12. Cathodic ALD V2O5 thin films for high-rate electrochemical energy...

    Office of Scientific and Technical Information (OSTI)

    Cathodic ALD V2O5 thin films for high-rate electrochemical energy storage Citation Details In-Document Search Title: Cathodic ALD V2O5 thin films for high-rate electrochemical...

  13. Synthesis and characterization of novel fluoride and oxide cathodes for rechargeable batteries

    E-Print Network [OSTI]

    Twu, Nancy (Nancy Hao-Jan)

    2015-01-01

    Developing new cathode materials is key to improving the energy density of rechargeable batteries and enabling new applications of energy storage. In this thesis, two families of materials were explored as candidate cathode ...

  14. Axis-1 diode simulations I: standard 2-inch cathode

    SciTech Connect (OSTI)

    Ekdahl, Carl [Los Alamos National Laboratory

    2011-01-11

    The standard configuration of the DARHT Axis-I diode features a 5.08-cm diameter velvet emitter mounted in the flat surface of the cathode shroud. The surface of the velvet is slightly recessed {approx}2.5 mm. This configuration produces a 1.75 kA beam when a 3.8-MV pulse is applied to the anode-cathode (AK) gap. This note addresses some of the physics of this diode through the use of finite-element simulations.

  15. QE data for Pb/Nb deposited photo cathode samples

    E-Print Network [OSTI]

    Sekutowicz, J

    2010-01-01

    This report outlines progress in the development of photo-cathodes for a hybrid lead/niobium (Pb/Nb) superconducting SRF electron injector. We have coated eight Nb samples with lead to study and determine deposition conditions leading to high quality emitting area. The results show that the oxide layer significantly influences the quantum efficiency (QE) of all measured cathodes. In addition, we learned that although the laser cleaning enhanced the QE substantially, the film morphology was strongly modified. That observation convinced us to make the coatings thicker and therefore more robust.

  16. Cathode preparation method for molten carbonate fuel cell

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Sim, James W. (Evergreen Park, IL); Kucera, Eugenia H. (Downers Grove, IL)

    1988-01-01

    A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

  17. Plutonium recovery from spent reactor fuel by uranium displacement

    DOE Patents [OSTI]

    Ackerman, J.P.

    1992-03-17

    A process is described for separating uranium values and transuranic values from fission products containing rare earth values when the values are contained together in a molten chloride salt electrolyte. A molten chloride salt electrolyte with a first ratio of plutonium chloride to uranium chloride is contacted with both a solid cathode and an anode having values of uranium and fission products including plutonium. A voltage is applied across the anode and cathode electrolytically to transfer uranium and plutonium from the anode to the electrolyte while uranium values in the electrolyte electrolytically deposit as uranium metal on the solid cathode in an amount equal to the uranium and plutonium transferred from the anode causing the electrolyte to have a second ratio of plutonium chloride to uranium chloride. Then the solid cathode with the uranium metal deposited thereon is removed and molten cadmium having uranium dissolved therein is brought into contact with the electrolyte resulting in chemical transfer of plutonium values from the electrolyte to the molten cadmium and transfer of uranium values from the molten cadmium to the electrolyte until the first ratio of plutonium chloride to uranium chloride is reestablished.

  18. Plutonium recovery from spent reactor fuel by uranium displacement

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL)

    1992-01-01

    A process for separating uranium values and transuranic values from fission products containing rare earth values when the values are contained together in a molten chloride salt electrolyte. A molten chloride salt electrolyte with a first ratio of plutonium chloride to uranium chloride is contacted with both a solid cathode and an anode having values of uranium and fission products including plutonium. A voltage is applied across the anode and cathode electrolytically to transfer uranium and plutonium from the anode to the electrolyte while uranium values in the electrolyte electrolytically deposit as uranium metal on the solid cathode in an amount equal to the uranium and plutonium transferred from the anode causing the electrolyte to have a second ratio of plutonium chloride to uranium chloride. Then the solid cathode with the uranium metal deposited thereon is removed and molten cadmium having uranium dissolved therein is brought into contact with the electrolyte resulting in chemical transfer of plutonium values from the electrolyte to the molten cadmium and transfer of uranium values from the molten cadmium to the electrolyte until the first ratio of plutonium chloride to uranium chloride is reestablished.

  19. Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating

    SciTech Connect (OSTI)

    Feng Jin

    2009-01-07

    This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

  20. Studies of Local Degradation Phenomena in Composite Cathodes for Lithium-Ion Batteries

    E-Print Network [OSTI]

    Kerlau, M.; Marcinek, M.; Srinivasan, V.; Kostecki, R.M.

    2008-01-01

    Composite Cathodes for Li-ion Batteries Marie Kerlau, Marekfrom commercial Li-ion batteries and mode cells which

  1. Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries

    E-Print Network [OSTI]

    Kam, Kinson

    2012-01-01

    Cathodes for Lithium-ion Batteries Kinson C. Kam and Marcarechargeable lithium-ion batteries has become an integral

  2. Develop high energy high power Li-ion battery cathode materials : a first principles computational study

    E-Print Network [OSTI]

    Xu, Bo; Xu, Bo

    2012-01-01

    Designing new electrode materials for energy devices byTo1) - a New Cathode Material for Batteries of High- Energy

  3. Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries

    E-Print Network [OSTI]

    Kam, Kinson

    2012-01-01

    Oxides Cathodes for Lithium-ion Batteries Kinson C. Kam andusing rechargeable lithium-ion batteries has become an

  4. Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries

    E-Print Network [OSTI]

    Kam, Kinson

    2012-01-01

    Metal Oxides Cathodes for Lithium-ion Batteries Kinson C.storage using rechargeable lithium-ion batteries has become

  5. Testing a GaAs cathode in SRF gun

    SciTech Connect (OSTI)

    Wang, E.; Kewisch, J.; Ben-Zvi, I.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

    2011-03-28

    RF electron guns with a strained superlattice GaAs cathode are expected to generate polarized electron beams of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface and lower cathode temperature. We plan to install a bulk GaAs:Cs in a SRF gun to evaluate the performance of both the gun and the cathode in this environment. The status of this project is: In our 1.3 GHz 1/2 cell SRF gun, the vacuum can be maintained at nearly 10{sup -12} Torr because of cryo-pumping at 2K. With conventional activation of bulk GaAs, we obtained a QE of 10% at 532 nm, with lifetime of more than 3 days in the preparation chamber and have shown that it can survive in transport from the preparation chamber to the gun. The beam line has been assembled and we are exploring the best conditions for baking the cathode under vacuum. We report here the progress of our test of the GaAs cathode in the SRF gun. Future particle accelerators, such as eRHIC and the ILC require high-brightness, high-current polarized electrons. Strained superlattice GaAs:Cs has been shown to be an efficient cathode for producing polarized electrons. Activation of GaAs with Cs,O(F) lowers the electron affinity and makes it energetically possible for all the electrons, excited into the conduction band that drift or diffuse to the emission surface, to escape into the vacuum. Presently, all operating polarized electron sources, such as the CEBAF, are DC guns. In these devices, the excellent ultra-high vacuum extends the lifetime of the cathode. However, the low field gradient on the photocathode's emission surface of the DC guns limits the beam quality. The higher accelerating gradients, possible in the RF guns, generate a far better beam. Until recently, most RF guns operated at room temperature, limiting the vacuum to {approx}10{sup -9} Torr. This destroys the GaAs's NEA surface. The SRF guns combine the excellent vacuum conditions of DC guns and the high accelerating gradient of the RF guns, potentially offering a long lived cathode with very low emittance. Testing this concept requires preparation of the cathode, transportation to the SRF gun and evaluation of the performance of the cathode and the gun at cryogenic temperatures. In our work at BNL, we successfully activated the bulk GaAs in the preparation chamber. The highest quantum efficient was 10% at 532 nm that fell to 0.5% after 100 hours. We explored three different ways to activate the GaAs. We verified that the GaAs photocathode remains stable for 30 hours in a 10{sup -11} Torr vacuum. Passing the photocathode through the low 10{sup -9} Torr transfer section in several seconds caused the QE to drop to 0.8%. The photocathode with 0.8% QE can be tested for the SRF gun. The gun and beam pipe were prepared and assembled. After baking at 200 C baking, the vacuum of the gun and beam pipe can sustain a low 10{sup -11} Torr at room temperature. The final test to extract electrons from the gun is ongoing. In this paper, we discuss our progress with this SRF gun and the results of the photocathode in preparation chamber and in magnet transfer line.

  6. Cold Air Distribution in Office Buildings: Technology Assessment for California

    E-Print Network [OSTI]

    Bauman, F.S.

    2008-01-01

    Field Evaluation of Cold Air Distribution Systems. EPRIand J.S. Elleson. 1988. Cold Air Distribution Design Guide.Field Evaluation of a Cold Air Distribution System. EPRI

  7. Nano-structured textiles as high-performance aqueous cathodes for microbial Mauro Pasta,bc

    E-Print Network [OSTI]

    Cui, Yi

    Microbial fuel cells (MFCs) can recover energy from waste due to the catalytic activity of microorganismsNano-structured textiles as high-performance aqueous cathodes for microbial fuel cells Xing Xie)­textile­Pt cathode for aqueous-cathode microbial fuel cells (MFCs) was prepared by electrochemically depositing Pt

  8. A reduced temperature solid oxide fuel cell with three-dimensionally ordered macroporous cathode

    SciTech Connect (OSTI)

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-01-01

    Three-dimensionally ordered macroporous cathode was fabricated for a zirconia based micro-tubular solid oxide fuel cells (SOFCs). Three different cathodes (cathode A, no pore former; cathode B, with pore former (1.5 {micro}m in diameter); cathode C, with pore former (0.8 {micro}m in diameter)) were compared to investigate how the microstructure of it affected the cell performance at various operating temperatures. Micro-sized pores were well distributed within cathode B and C. The total porosity of cathode A is 35%, while it respectively reached 42 and 50% for cathodes B and C. At the same time, the specific surface area of them was 28.8 and 52.0% larger than that of the cathode A. As a result, the peak power density of the zirconia based cell, with cathode C, was 0.25 and 0.56 W cm{sup -2} at 550 and 600 C, while the respective value was just 0.11 and 0.30 W cm{sup -2} for the cell with cathode A. Thus, optimizing microstructure of cathode should be one of the best approaches for lowering the operating temperature for SOFCs.

  9. Domain wall displacement by remote spin-current injection

    E-Print Network [OSTI]

    Skirdkov, P. N.

    We demonstrate numerically the ability to displace a magnetic domain wall (DW) by remote spin current injection. We consider a long and narrow magnetic nanostripe with a single DW. The spin-polarized current is injected ...

  10. Constant displacement rate experiments and constitutive modeling of asphalt mixtures 

    E-Print Network [OSTI]

    Hariharakumar, Pradeep

    2006-04-12

    The focus of this dissertation is on constant displacment rate experiments on asphalt concrete and on developing continuum models in a general thermo-mechanical setting which will corroborate with the experimental results. Modeling asphalt concrete...

  11. The Vroman effect: a molecular level description of fibrinogen displacement 

    E-Print Network [OSTI]

    Jung, Seung-Yong

    2005-02-17

    this system. The results demonstrate that the protein's ?C domains play the critical role. When fibrinogen is adsorbed to a hydrophilic surface via these moieties, its displacement rate in the presence of human plasma is approximately 170 times faster...

  12. Adsorption, Desorption, and Displacement Kinetics of H2O and...

    Office of Scientific and Technical Information (OSTI)

    CO2. The onset of CO2 displacement by H2O occurs between 65 and 75 K. Authors: Smith, R. Scott ; Li, Zhenjun ; Dohnalek, Zdenek ; Kay, Bruce D. Publication Date:...

  13. A scale model study of displacement ventilation with chilled ceilings

    E-Print Network [OSTI]

    Holden, Katherine J. A. (Katherine Joan Adrienne)

    1995-01-01

    Displacement ventilation is a form of air-conditioning which provides good air quality and some energy savings. The air quality is better than for a conventional mixed ventilation system. The maximum amount of cooling that ...

  14. Key Factors in Displacement Ventilation Systems for Better IAQ 

    E-Print Network [OSTI]

    Wang, X.; Chen, J.; Li, Y.; Wang, Z.

    2006-01-01

    This paper sets up a mathematical model of three-dimensional steady turbulence heat transfer in an air-conditioned room of multi-polluting heat sources. Numerical simulation helps identify key factors in displacement ventilation systems that affect...

  15. Iraq's housing crisis : upgrading settlements for IDPS (internally displaced persons)

    E-Print Network [OSTI]

    Shaikley, Layla Karim

    2013-01-01

    The most recent war in Iraq has resulted in a large wave of internal and external displacement with increased sectarian violence and ethnic tension. Subsequent conflict has exacerbated conditions within the nation and ...

  16. Recovery of oil from fractured reservoirs by gas displacement 

    E-Print Network [OSTI]

    Unneberg, Arild

    1974-01-01

    RECOVERY OF OIL FROM FRACTURED RESERVOIRS BY GAS DISPLACEMENT A Thesis by ARILD UNNE BE RG Submitted to the Graduate College of Texas AlkM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1974... Major Subject: Petroleum Engineering RECOVERY OF OIL FROM FRACTURED RESERVOIRS BY GAS DISPLACEMENT A Thesis by ARILD UNNEBERG Approved as, to style and content by: . ( y (Chairman of Cornrnittee) (Head of Depar nt) / (Membe r) (Member) M b...

  17. Time Displaced Entanglement and Non-Linear Quantum Evolution

    E-Print Network [OSTI]

    T. C. Ralph

    2005-10-06

    We discuss time displaced entanglement, produced by taking one member of a Bell pair on a round trip at relativistic speeds, thus inducing a time-shift between the pair. We show that decoherence with respect to Bell measurements on the pair is predicted. We then study a teleportation protocol, using time displaced entanglement as its resource, in which a time-like loop is apparently formed. The result is non-unitary, non-linear evolution of the teleported state.

  18. A study of oil displacement by carbonated water 

    E-Print Network [OSTI]

    Partovi-Najafabadi, Roohollah

    1968-01-01

    A STUDY OF OIL DISPLACEMENT BY CARBONATED WATER A Thesis by Roohollah Partovi-N. Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1988... Major Subject: Petroleum Fn ineerin A STUDY OF OIL DISPLACEMENT BY CARBONATED WATER A Thesis by Roohollah Partovi-N. Approved as to style and content by: ( irman of mmittee) M mber) (Head of partment) (Member) January 1968 CP9292...

  19. Individually addressable cathodes with integrated focusing stack or detectors

    DOE Patents [OSTI]

    Thomas, Clarence E.; Baylor, Larry R.; Voelkl, Edgar; Simpson, Michael L.; Paulus, Michael J.; Lowndes, Douglas; Whealton, John; Whitson, John C.; Wilgen, John B.

    2005-07-12

    Systems and method are described for addressable field emission array (AFEA) chips. A plurality of individually addressable cathodes are integrated with an electrostatic focusing stack and/or a plurality of detectors on the addressable field emission array. The systems and methods provide advantages including the avoidance of space-charge blow-up.

  20. Rigid indented cylindrical cathode for x-ray tube

    DOE Patents [OSTI]

    Hudgens, C.R.

    1983-06-03

    A cathode assembly for a vacuum tube includes a wire filament, a straight tubular anode parallel to and surrounding the wire filament, insulating spacers for rigidly fastening the filament with respect to the anode, and with one side of the anode indented or flattened such that only one portion of the anode is heated to emitting temperatures by the filament.

  1. Rigid indented cylindrical cathode for X-ray tube

    DOE Patents [OSTI]

    Hudgens, Claude R. (Dayton, OH)

    1985-01-01

    A cathode assembly for a vacuum tube includes a wire filament, a straight bular anode parallel to and surrounding the wire filament, and insulating spacers for rigidly fastening the filament with respect to the anode, and with one side of the anode indented or flattened such that only one portion of the anode is heated to emitting temperatures by the filament.

  2. INVESTIGATION OF OXYGEN REDUCTION MECHANISMS USING CATHODE MICROELECTRODES, PART II

    E-Print Network [OSTI]

    Yildiz, Bilge

    and alternatives are proposed for further investigation. INTRODUCTION The power of a solid oxide fuel cell (SOFC. Although oxygen re- duction at SOFC cathodes has been studied in the literature, a comprehensive and clear resistances and capacitances in the SOFC behavior. All implications presented in Refs. 2-7 have been based

  3. Engineering analyses of large precision cathode strip chambers for GEM

    SciTech Connect (OSTI)

    Horvath, J.A.; Belser, F.C.; Pratuch, S.M.; Wuest, C.R. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); Mitselmakher, G. [Superconducting Super Collider Lab., Dallas, TX (United States)] [Superconducting Super Collider Lab., Dallas, TX (United States); Gordeev, A. [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation)] [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Johnson, C.V. [Lawrence Livermore National Lab., CA (United States)] [Lawrence Livermore National Lab., CA (United States); [Superconducting Super Collider Lab., Dallas, TX (United States); Polychronakos, V.A. [Brookhaven National Lab., Upton, NY (United States)] [Brookhaven National Lab., Upton, NY (United States); Golutvin, I.A. [Joint Institute for Nuclear Research, Dubna (Russian Federation)] [Joint Institute for Nuclear Research, Dubna (Russian Federation)

    1993-10-21

    Structural analyses of large precision cathode strip chambers performed up to the date of this publication are documented. Mechanical property data for typical chamber materials are included. This information, originally intended to be an appendix to the {open_quotes}CSC Structural Design Bible,{close_quotes} is presented as a guide for future designers of large chambers.

  4. Microbial Fuel Cell Cathodes With Poly(dimethylsiloxane) Diffusion

    E-Print Network [OSTI]

    the performance of the cathode. Two PDMS/ carbon layers achieved the highest maximum power density of 1610 ( 56 m, and their ability to generate high power densities (7-9, 12). Scale-up is an important issue for practical applications of MFCs for wastewater treatment and bioenergy production. The main challenges for commercializing

  5. Vibrational cooling in a cold ion trap: Vibrationally resolved photoelectron spectroscopy of cold C60

    E-Print Network [OSTI]

    Simons, Jack

    Vibrational cooling in a cold ion trap: Vibrationally resolved photoelectron spectroscopy of cold C August 2005 We demonstrate vibrational cooling of anions via collisions with a background gas in an ion cold C60 - anions, produced by electrospray ionization and cooled in the cold ion trap, have been

  6. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-09-05

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  7. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-03-21

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  8. DOE's Office of Science Sets up Program to Aid Scientists Displaced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sets up Program to Aid Scientists Displaced by Hurricane Katrina DOE's Office of Science Sets up Program to Aid Scientists Displaced by Hurricane Katrina September 9, 2005 -...

  9. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01

    a new cathode material for batteries of high energy density.energy sources, are strong drivers for fundamental research in new materials

  10. The reality of cold fusion

    SciTech Connect (OSTI)

    Case, L.C. (Eltron, Inc., Winchester, MA (US))

    1991-12-01

    Despite the unreproducibility, doubt, and controversy involved in the question of the cold fusion of deuterium, enough good data have been published to clearly indicate the reality of some sort of nuclear fusion. Yamaguchi and Niushioka reported a thrice-repeated event in which large amounts of heat and definite bursts of neutrons evolved simultaneously with considerable out-gassing of absorbed deuterium. These results are consistent with nuclear fusion and not with a chemical reaction. In this paper a detailed mechanism is proposed that is consistent with these events and that also generally explains many of the scattered indications of cold fusion that have been reported. There must be an adventitiously large enough presence of tritium to initiate the nuclear reaction. The results of previously successful experiments cannot now be reproduced because currently available D{sub 2}O (and D{sub 2}) is so low in adventitious tritium as to preclude initiation of the nuclear reaction.

  11. Joule heat generation in thermionic cathodes of high-pressure arc discharges

    SciTech Connect (OSTI)

    Benilov, M. S.; Cunha, M. D.

    2013-02-14

    The nonlinear surface heating model of plasma-cathode interaction in high-pressure arcs is extended to take into account the Joule effect inside the cathode body. Calculation results are given for different modes of current transfer to tungsten cathodes of different configurations in argon plasmas of atmospheric or higher pressures. Special attention is paid to analysis of energy balances of the cathode and the near-cathode plasma layer. In all the cases, the variation of potential inside the cathode is much smaller than the near-cathode voltage drop. However, this variation can be comparable to the volt equivalent of the energy flux from the plasma to the cathode and then the Joule effect is essential. Such is the case of the diffuse and mixed modes on rod cathodes at high currents, where the Joule heating causes a dramatic change of thermal and electrical regimes of the cathode. The Joule heating has virtually no effect over characteristics of spots on rod and infinite planar cathodes.

  12. Anode-cathode power distribution systems and methods of using the same for electrochemical reduction

    DOE Patents [OSTI]

    Koehl, Eugene R; Barnes, Laurel A; Wiedmeyer, Stanley G; Williamson, Mark A; Willit, James L

    2014-01-28

    Power distribution systems are useable in electrolytic reduction systems and include several cathode and anode assembly electrical contacts that permit flexible modular assembly numbers and placement in standardized connection configurations. Electrical contacts may be arranged at any position where assembly contact is desired. Electrical power may be provided via power cables attached to seating assemblies of the electrical contacts. Cathode and anode assembly electrical contacts may provide electrical power at any desired levels. Pairs of anode and cathode assembly electrical contacts may provide equal and opposite electrical power; different cathode assembly electrical contacts may provide different levels of electrical power to a same or different modular cathode assembly. Electrical systems may be used with an electrolyte container into which the modular cathode and anode assemblies extend and are supported above, with the modular cathode and anode assemblies mechanically and electrically connecting to the respective contacts in power distribution systems.

  13. Modular cathode assemblies and methods of using the same for electrochemical reduction

    DOE Patents [OSTI]

    Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L

    2014-12-02

    Modular cathode assemblies are useable in electrolytic reduction systems and include a basket through which fluid electrolyte may pass and exchange charge with a material to be reduced in the basket. The basket can be divided into upper and lower sections to provide entry for the material. Example embodiment cathode assemblies may have any shape to permit modular placement at any position in reduction systems. Modular cathode assemblies include a cathode plate in the basket, to which unique and opposite electrical power may be supplied. Example embodiment modular cathode assemblies may have standardized electrical connectors. Modular cathode assemblies may be supported by a top plate of an electrolytic reduction system. Electrolytic oxide reduction systems are operated by positioning modular cathode and anode assemblies at desired positions, placing a material in the basket, and charging the modular assemblies to reduce the metal oxide.

  14. Horizontal displacements contribution to tsunami wave energy balance

    E-Print Network [OSTI]

    Dutykh, Denys; Chubarov, Leonid; Shokin, Yuriy

    2010-01-01

    The main reason for the generation of tsunamis is the deformation of the bottom of the ocean caused by an underwater earthquake. Usually, only the vertical bottom motion is taken into accound while the horizontal displacements are neglected. In the present paper we study both the vertical and the horizontal bottom motion while we propose a novel methodology for reconstructing the bottom coseismic displacements field which is transmitted to the free surface using a new three-dimensional Weakly Nonlinear (WN) approach. We pay a special attention to the evolution of kinetic and potential energies of the resulting wave while the contribution of horizontal displacements into wave energy balance is also quantified. Approaches proposed in this study are illustrated on the July 17, 2006 Java tsunami.

  15. Higher harmonics generation in relativistic electron beam with virtual cathode

    SciTech Connect (OSTI)

    Kurkin, S. A., E-mail: KurkinSA@gmail.com; Badarin, A. A.; Koronovskii, A. A.; Hramov, A. E. [Saratov State Technical University, Politechnicheskaja 77, Saratov 410028, Russia and Saratov State University, Astrakhanskaja 83, Saratov 410012 (Russian Federation)

    2014-09-15

    The study of the microwave generation regimes with intense higher harmonics taking place in a high-power vircator consisting of a relativistic electron beam with a virtual cathode has been made. The characteristics of these regimes, in particular, the typical spectra and their variations with the change of the system parameters (beam current, the induction of external magnetic field) as well as physical processes occurring in the system have been analyzed by means of 3D electromagnetic simulation. It has been shown that the system under study demonstrates the tendency to the sufficient growth of the amplitudes of higher harmonics in the spectrum of current oscillations in the VC region with the increase of beam current. The obtained results allow us to consider virtual cathode oscillators as promising high power mmw-to-THz sources.

  16. Heterogeneous electrocatalysis in porous cathodes of solid oxide fuel cells

    E-Print Network [OSTI]

    Fu, Y; Bertei, A; Qi, C; Mohanram, A; Pietras, J D; Bazant, M Z

    2014-01-01

    A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas dissociative adsorption and surface diffusion of the oxygen intermediate to the triple phase boundary, where charge transfer occurs. The model accurately captures the Gerischer-like frequency dependence and the oxygen partial pressure dependence of the impedance of symmetric cathode cells. Digital image analysis of the microstructure of the cathode functional layer in four different cells directly confirms the predicted connection between geometrical properties and the impedance response. As in classical catalysis, the electrocatalytic activity is controlled by an effective Thiele modulus, which is the ratio of the surface diffusion length (mean distance from an adsorption site to the triple phase boundary) to the surface boundary layer length (square root of surface diffusivity div...

  17. Electroconvection under injection from cathode and heating from above

    SciTech Connect (OSTI)

    Mordvinov, A. N.; Smorodin, B. L.

    2012-05-15

    We study the electroconvection that appears in a nonuniformly heated, poorly conducting liquid in a parallel-plate horizontal capacitor due to the action of an external static electric field on the charge injected from the cathode. It is shown that the heating of the layer from above prevents steady-state convection and that, unlike the isothermal situation, electroconvection can appear in the oscillatory manner as a result of direct Hopf bifurcation. The effect of the heating intensity, the intensity of charge injection from the cathode, and the charge mobility on the thresholds of oscillatory and monotonic electroconvection is analyzed and the characteristic scales and frequencies of critical perturbations are determined. The nonlinear wave and steady-state regimes of the 2D convective structures formed in the poorly conducting liquid under the action of thermogravitational and injection mechanisms of convection are analyzed. The domains of existence of standing, traveling, and modulated waves are determined.

  18. Limitations in using pulsed rectifiers for well casing cathodic protection

    SciTech Connect (OSTI)

    Dabkowski, J. [Electro Sciences, Inc., Crystal Lake, IL (United States)

    1995-11-01

    Due to earth propagation losses the rectifier current pulses suffer considerable waveform deterioration as the penetration depth increases. Hence, cathodic protection benefits attributable to the use of a pulsed rectifier will not be attainable below a certain depth which is a function of the pulse characteristics and the soil resistivity. In this paper a hypothetical 3,000 meter length well casing is modeled as a distributed lossy electrical transmission line. It is shown that below a depth of 300 to 500 meters, the higher frequency content of the pulse is severely attenuated. The cathodic protection process at these and increased depths, therefore, will not differ significantly from that obtained with a non-pulsed dc rectifier.

  19. Apparatus and method for treating a cathode material provided on a thin-film substrate

    DOE Patents [OSTI]

    Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

    2001-01-01

    An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

  20. Apparatus and method for treating a cathode material provided on a thin-film substrate

    DOE Patents [OSTI]

    Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

    2003-01-01

    An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

  1. Formation of metal oxides by cathodic arc deposition

    SciTech Connect (OSTI)

    Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

    1995-03-01

    Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

  2. Additive for iron disulfide cathodes used in thermal batteries

    DOE Patents [OSTI]

    Armijo, James R. (Albuquerque, NM); Searcy, Jimmie Q. (Albuquerque, NM)

    1983-01-01

    The invention comprises thermal batteries employing an FeS.sub.2 depolarizer, i.e. cathode material, and the depolarizer itself. A minor amount of CaSi.sub.2 preferably, 1-3% by weight is provided as an additive in the FeS.sub.2 depolarizer to eliminate the voltage transient (spike) which normally occurs upon activation of batteries of this type. The amount of FeS.sub.2 by weight generally comprises 64-90%.

  3. Negative ion source with hollow cathode discharge plasma

    DOE Patents [OSTI]

    Hershcovitch, A.; Prelec, K.

    1980-12-12

    A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

  4. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  5. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, Eugene (Coram, NY)

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  6. Search for High Energy Density Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 -RobSSL INDepartmentHigh Energy Density Cathode Materials

  7. Non-Platinum Bimetallic Cathode Electrocatalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills and Reduce CarbonEnergy Fuel Effects onPlatinum Bimetallic Cathode

  8. Investigations of Cathode Architecture using Graphite Fibers | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S. Department of(Presentation) |of Energy Cathode

  9. Engineering of High Energy Cathode Material | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographiclighbulbs - high-resolution2 DOEHigh Energy Cathode Material

  10. Engineering of High Energy Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographiclighbulbs - high-resolution2 DOEHigh Energy Cathode Material2

  11. Engineering of High Energy Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographiclighbulbs - high-resolution2 DOEHigh Energy Cathode

  12. Cold Climate Building Enclosure Solutions

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby a contractorEnergy, science,6. Radiative Forcing ofCold

  13. Criteria for displacement by gas versus water in oil reservoirs 

    E-Print Network [OSTI]

    Piper, Larry Dean

    1981-01-01

    the problem. Croes and SchwarzIp stud1ed the eff1c1ency of water flooding and presented results show1ng effic1ency and water cut as a function of total production for a range of v1scosity rat1os between I and 500. They also used the1r results to compare... of the oil in place at various values of the displac1ng fluid-to-oil ratio (DFOR)* was used as the measure of displacement effic1ency. This procedure was used for two reasons. F1rst, economic limits may be established based on DFOR. Recovery at various...

  14. Displacement of oil from porous material with carbonated water 

    E-Print Network [OSTI]

    Yadav, Jagjit Singh

    1967-01-01

    DISPLACEMENT OF OIL FROM POROUS MATERIAL WITH CARBONATED WATER A Thesis By JAGJIT S. YADAV Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1967 Ma/or Sub)act; Petroleum Engineering DISPLACEMENT OF OIL FROM POROUS MATERIAL WITH CARBONATED WATER A Thesis By JAGJIT ST YADAV Approved as to style and content by: ( ai an of Committee) cZ&-& 3~ ~" (Head of Department) (Member) (Member...

  15. Humectant use in the cathodic protection of reinforced concrete

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Russell, James H.; Bullard, Sophie J.; Cramer, Stephen D.; Collins, W.K.; Bennett, J.E.; Laylor, H.M.

    2000-11-01

    Use of humectants to improve the thermal-sprayed zinc anode performance during the cathodic protection (CP) of reinforced concrete was examined. A humectant is a hygroscopic material. It is applied onto the surface of the zinc anode to keep the concrete-anode interface moist and a good conductor. The thermodynamics of humectants are discussed. Laboratory results are presented on the effects of using lithium bromide (LiBr) and lithium nitrate (LiNO{sub 3}) as humectants in galvanic cathodic protection (GCP) and impressed current cathodic protection (ICCP) systems, in high and low relative humidities, and on new and previously electrochemically aged CP systems. LiNO{sub 3} and LiBr promoted more effective CP performance. Both improved the performance of aged slabs, suggesting that application of humectants onto existing CP systems would be of benefit. Microscopy showed that humectant-treated slabs develop the same cement-reaction zone, zinc anode structures as untreated slabs. Microscopy of LiBr-treated slabs revealed that the highest concentration of bromide was in the reaction zone. In GCP tests, LiBr was more effective than LiNO{sub 3}. In accelerated ICCP tests, LiNO{sub 3} was more effective than LiBr. It was surmised that bromide could be oxidized in the high-voltage accelerated ICCP tests. At the lower impressed currents of most installed ICCP systems, LiBr may perform as well as or better than LiNO{sub 3}.

  16. An interchangeable-cathode vacuum arc plasma source

    SciTech Connect (OSTI)

    Olson, David K.; Peterson, Bryan G.; Hart, Grant W.

    2010-01-15

    A simplified vacuum arc design [based on metal vapor vacuum arc (MeVVA) concepts] is employed as a plasma source for a study of a {sup 7}Be non-neutral plasma. The design includes a mechanism for interchanging the cathode source. Testing of the plasma source showed that it is capable of producing on the order of 10{sup 12} charges at confinable energies using a boron-carbide disk as the cathode target. The design is simplified from typical designs for lower energy and lower density applications by using only the trigger spark rather than the full vacuum arc in high current ion beam designs. The interchangeability of the cathode design gives the source the ability to replace only the source sample, simplifying use of radioactive materials in the plasma source. The sample can also be replaced with a completely different conductive material. The design can be easily modified for use in other plasma confinement or full MeVVA applications.

  17. Ion velocities in a micro-cathode arc thruster

    SciTech Connect (OSTI)

    Zhuang Taisen; Shashurin, Alexey; Keidar, Michael; Beilis, Isak

    2012-06-15

    Ion velocities in the plasma jet generated by the micro-cathode arc thruster are studied by means of time-of-flight method using enhanced ion detection system (EIDS). The EIDS triggers perturbations (spikes) on arc current waveform, and the larger current in the spike generates denser plasma bunches propagating along with the mainstream plasma. The EIDS utilizes double electrostatic probes rather than single probes. The average Ti ion velocity is measured to be around 2 Multiplication-Sign 10{sup 4} m/s without a magnetic field. It was found that the application of a magnetic field does not change ion velocities in the interelectrode region while leads to ion acceleration in the free expanding plasma plume by a factor of about 2. Ion velocities of about 3.5 Multiplication-Sign 10{sup 4} m/s were detected for the magnetic field of about 300 mT at distance of about 100-200 mm from the cathode. It is proposed that plasma is accelerated due to Lorentz force. The average thrust is calculated using the ion velocity measurements and the cathode mass consumption rate, and its increase with the magnetic field is demonstrated.

  18. A knife-edge array field emission cathode

    SciTech Connect (OSTI)

    Lee, B.

    1994-08-01

    many cathode applications require a new type of cathode that is able to produce short pulsed electron beams at high emission current. Gated field emitter arrays of micrometer size are recognized as candidates to meet this need and have become the research focus of vacuum microelectronics. Existing fabrication methods produce emitters that are limited either in frequency response or in current emission. One reason is that the structure of these emitters are not sufficiently optimized. In this study, the author investigated the factors that affect the performance of field emitters. An optimum emitter structure, the knife-edge field emitter array, was developed from the analysis. Large field enhancement factor, large effective emission area, and small emitter capacitance are the advantages of the structure. The author next explored various options of fabricating the knife-edge emitter structure. He proposed a unique thin film process procedure and developed the fabrication techniques to build the emitters on (110) silicon wafers. Data from the initial cathode tests showed very low onset voltages and Fowler-Nordheim type emission. Emission simulation based on the fabricated emitter structure indicated that the knife-edge emitter arrays have the potential to produce high performance in modulation frequency and current emission. Several fabrication issues that await further development are discussed and possible solutions are suggested.

  19. Process for Low Cost Domestic Production of LIB Cathode Materials

    SciTech Connect (OSTI)

    Thurston, Anthony

    2012-10-31

    The objective of the research was to determine the best low cost method for the large scale production of the Nickel-Cobalt-Manganese (NCM) layered cathode materials. The research and development focused on scaling up the licensed technology from Argonne National Laboratory in BASF’s battery material pilot plant in Beachwood Ohio. Since BASF did not have experience with the large scale production of the NCM cathode materials there was a significant amount of development that was needed to support BASF’s already existing research program. During the three year period BASF was able to develop and validate production processes for the NCM 111, 523 and 424 materials as well as begin development of the High Energy NCM. BASF also used this time period to provide free cathode material samples to numerous manufactures, OEM’s and research companies in order to validate the ma-terials. The success of the project can be demonstrated by the construction of the production plant in Elyria Ohio and the successful operation of that facility. The benefit of the project to the public will begin to be apparent as soon as material from the production plant is being used in electric vehicles.

  20. International workshop on cold neutron sources

    SciTech Connect (OSTI)

    Russell, G.J.; West, C.D. )

    1991-08-01

    The first meeting devoted to cold neutron sources was held at the Los Alamos National Laboratory on March 5--8, 1990. Cosponsored by Los Alamos and Oak Ridge National Laboratories, the meeting was organized as an International Workshop on Cold Neutron Sources and brought together experts in the field of cold-neutron-source design for reactors and spallation sources. Eighty-four people from seven countries attended. Because the meeting was the first of its kind in over forty years, much time was spent acquainting participants with past and planned activities at reactor and spallation facilities worldwide. As a result, the meeting had more of a conference flavor than one of a workshop. The general topics covered at the workshop included: Criteria for cold source design; neutronic predictions and performance; energy deposition and removal; engineering design, fabrication, and operation; material properties; radiation damage; instrumentation; safety; existing cold sources; and future cold sources.

  1. NANOWIRE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES

    SciTech Connect (OSTI)

    John Olson, PhD

    2004-07-21

    This project involved the synthesis of nanowire ã-MnO2 and characterization as cathode material for high-power lithium-ion batteries for EV and HEV applications. The nanowire synthesis involved the edge site decoration nanowire synthesis developed by Dr. Reginald Penner at UC Irvine (a key collaborator in this project). Figure 1 is an SEM image showing ã-MnO2 nanowires electrodeposited on highly oriented pyrolytic graphite (HOPG) electrodes. This technique is unique to other nanowire template synthesis techniques in that it produces long (>500 um) nanowires which could reduce or eliminate the need for conductive additives due to intertwining of fibers. Nanowire cathode for lithium-ion batteries with surface areas 100 times greater than conventional materials can enable higher power batteries for electric vehicles (EVs) and hybrid electric vehicles (HEVs). The synthesis of the ã-MnO2 nanowires was successfully achieved. However, it was not found possible to co-intercalate lithium directly in the nanowire synthesis. Based on input from proposal reviewers, the scope of the project was altered to attempt the conversion into spinel LiMn2O4 nanowire cathode material by solid state reaction of the ã-MnO2 nanowires with LiNO3 at elevated temperatures. Attempts to perform the conversion on the graphite template were unsuccessful due to degradation of the graphite apparently caused by oxidative attack by LiNO3. Emphasis then shifted to quantitative removal of the nanowires from the graphite, followed by the solid state reaction. Attempts to quantitatively remove the nanowires by several techniques were unsatisfactory due to co-removal of excess graphite or poor harvesting of nanowires. Intercalation of lithium into ã-MnO2 electrodeposited onto graphite was demonstrated, showing a partial demonstration of the ã-MnO2 material as a lithium-ion battery cathode material. Assuming the issues of nanowires removal can be solved, the technique does offer potential for creating high-power lithium-ion battery cathode needed for advanced EV and HEVs. Several technical advancements will still be required to meet this goal, and are likely topics for future SBIR feasibility studies.

  2. Cold vacuum drying facility design requirements

    SciTech Connect (OSTI)

    IRWIN, J.J.

    1999-07-01

    This document provides the detailed design requirements for the Spent Nuclear Fuel Project Cold Vacuum Drying Facility. Process, safety, and quality assurance requirements and interfaces are specified.

  3. Evaporative cooling enhanced cold storage system

    DOE Patents [OSTI]

    Carr, P.

    1991-10-15

    The invention provides an evaporatively enhanced cold storage system wherein a warm air stream is cooled and the cooled air stream is thereafter passed into contact with a cold storage unit. Moisture is added to the cooled air stream prior to or during contact of the cooled air stream with the cold storage unit to effect enhanced cooling of the cold storage unit due to evaporation of all or a portion of the added moisture. Preferably at least a portion of the added moisture comprises water condensed during the cooling of the warm air stream. 3 figures.

  4. Evaporative cooling enhanced cold storage system

    DOE Patents [OSTI]

    Carr, Peter (Cary, NC)

    1991-01-01

    The invention provides an evaporatively enhanced cold storage system wherein a warm air stream is cooled and the cooled air stream is thereafter passed into contact with a cold storage unit. Moisture is added to the cooled air stream prior to or during contact of the cooled air stream with the cold storage unit to effect enhanced cooling of the cold storage unit due to evaporation of all or a portion of the added moisture. Preferably at least a portion of the added moisture comprises water condensed during the cooling of the warm air stream.

  5. Note: Design and development of improved indirectly heated cathode based strip electron gun

    SciTech Connect (OSTI)

    Maiti, Namita; Patil, D. S.; Dasgupta, K.; Bade, Abhijeet; Tembhare, G. U.

    2015-02-15

    An improved design of indirectly heated solid cathode based electron gun (200 kW, 45 kV, 270° bent strip type electron gun) has been presented. The solid cathode is made of thoriated tungsten, which acts as an improved source of electron at lower temperature. So, high power operation is possible without affecting structural integrity of the electron gun. The design issues are addressed based on the uniformity of temperature on the solid cathode and the single long filament based design. The design approach consists of simulation followed by extensive experimentation. In the design, the effort has been put to tailor the non-uniformity of the heat flux from the filament to the solid cathode to obtain better uniformity of temperature on the solid cathode. Trial beam experiments have been carried out and it is seen that the modified design achieves one to one correspondence of the solid cathode length and the electron beam length.

  6. Large area directly heated lanthanum hexaboride cathode structure having predetermined emission profile

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Gordon, K.C.; Kippenhan, D.O.; Purgalis, P.; Moussa, D.; Williams, M.D.; Wilde, S.B.; West, M.W.

    1987-10-16

    A large area directly heated lanthanum hexaboride (LaB/sub 6/) cathode system is disclosed. The system comprises a LaB/sub 6/ cathode element generally circular in shape about a central axis. The cathode element has a head with an upper substantially planar emission surface, and a lower downwardly and an intermediate body portion which diminishes in cross-section from the head towards the base of the cathode element. A central rod is connected to the base of the cathode element and extends along the central axis. Plural upstanding spring fingers are urged against an outer peripheral contact surface of the head end to provide a mechanical and electrical connection to the cathode element. 7 figs

  7. Characterization of Atomic and Electronic Structures of Electrochemically Active SOFC Cathode Surfaces

    SciTech Connect (OSTI)

    Kevin Blinn; Yongman Choi; Meilin Liu

    2009-08-11

    The objective of this project is to gain a fundamental understanding of the oxygen-reduction mechanism on mixed conducting cathode materials by means of quantum-chemical calculations coupled with direct experimental measurements, such as vibrational spectroscopy. We have made progress in the elucidation of the mechanisms of oxygen reduction of perovkite-type cathode materials for SOFCs using these quantum chemical calculations. We established computational framework for predicting properties such as oxygen diffusivity and reaction rate constants for adsorption, incorporation, and TPB reactions, and formulated predictions for LSM- and LSC-based cathode materials. We have also further developed Raman spectroscopy as well as SERS as a characterization tool for SOFC cathode materials. Raman spectroscopy was used to detect chemical changes in the cathode from operation conditions, and SERS was used to probe for pertinent adsorbed species in oxygen reduction. However, much work on the subject of unraveling oxygen reduction for SOFC cathodes remains to be done.

  8. Potential displacement of petroleum imports by solar energy technologies

    SciTech Connect (OSTI)

    DeLeon, P.; Jackson, B.L.; McNown, R.F.; Mahrenholz, G.J.

    1980-05-01

    The United States currently imports close to half of its petroleum requirements. This report delineates the economic, social, and political costs of such a foreign oil dependency. These costs are often intangible, but combined they clearly constitute a greater price for imported petroleum than the strictly economic cost. If we can assume that imported oil imposes significant socioeconomic costs upon the American economy and society, one way to reduce these costs is to develop alternative, domestic energy sources - such as solar energy technologies - which can displace foreign petroleum. The second half of this report estimates that by the year 2000, solar energy technologies can displace 3.6 quads of petroleum. This figure includes solar energy applications in utilities, industrial and agricultural process heat, and transportation. The estimate can be treated as a lower bound; if the United States were to achieve the proposed goal of 20 quads by 2000, the amount of displaced oil probably would be greater. Although all the displaced oil would not be imported, the reduction in imported petroleum would relieve many of the conditions that increase the present cost of foreign oil to the American consumer.

  9. Gamma displacement cross-sections in various materials

    E-Print Network [OSTI]

    Motta, Arthur T.

    Electric (GE) Advanced Boiling Water Reactor (ABWR) indicated that the calculated gamma displacement damage of reactor pressure vessel (RPV) steels in the HFIR reactor (Rehn and Birtcher, 1993; Farrell et al. 1994 there is a large water gap, gamma damage can become comparable to that produced by neutrons, on a straight

  10. Behavior of fullscale concrete segmented pipelines under permanent ground displacements

    E-Print Network [OSTI]

    Michalowski, Radoslaw L.

    Behavior of fullscale concrete segmented pipelines under permanent ground displacements Junhee, Indiana; d Department of Civil Engineering, Merrimack College, MA ABSTRACT Concrete pipelines are one pipelines and eventually lead to joint failures. In order to understand and model the typical failure

  11. Deriving Displacement from a 3 axis Accelerometer Mr. Andrew Blake

    E-Print Network [OSTI]

    Winstanley, Graham

    Deriving Displacement from a 3 axis Accelerometer Mr. Andrew Blake University of Brighton CMIS, Additive 1. Introduction The Nintendo WiiTM, Sony's Playstation 3TM and Microsoft's Xbox 360TM all feature a 1000 seconds is 1,000,000 times greater than that at 1 second. Any small offset errors

  12. Displacement Correction Scheme for MR-Guided Interstitial Laser Therapy

    E-Print Network [OSTI]

    van Vliet, Lucas J.

    Displacement Correction Scheme for MR-Guided Interstitial Laser Therapy S. Suprijanto1 , M.W. Vogel[1,3]. In the absence of motion, MR thermometry based on phase imaging is quite accurate[12 , F.M. Vos1 , H.A. Vrooman2,3 , and A.M. Vossepoel1 1 Pattern Recognition Group, Department

  13. Composite Organic Radical - Inorganic Hybrid Cathode for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Huang, Qian; Cosimbescu, Lelia; Koech, Phillip K.; Choi, Daiwon; Lemmon, John P.

    2013-07-01

    A new organic radical inorganic hybrid cathode comprised of PTMA/LiFePO4 composite system is developed and reported for the first time. The hybrid cathodes demonstrate high pulse power capability resulting in a significant improvement over the pure PTMA or LiFePO4 cathode which is very promising for transportation and other high pulse power applications that require long cycle life and lower cost.

  14. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect (OSTI)

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  15. Oxygen reduction and transportation mechanisms in solid oxide fuel cell cathodes

    SciTech Connect (OSTI)

    Li YH, Gemmen R, Liu XB

    2010-06-01

    In recent years, various models have been developed for describing the reaction mechanisms in solid oxide fuel cell (SOFC) especially for the cathode electrode. However, many fundamental issues regarding the transport of oxygen and electrode kinetics have not been fully understood. This review tried to summarize the present status of the SOFC cathode modeling efforts, and associated experimental approaches on this topic. In addition, unsolved problems and possible future research directions for SOFC cathode kinetics had been discussed

  16. Surface topography of a palladium cathode after electrolysis in heavy water

    SciTech Connect (OSTI)

    Silver, D.S. ); Dash, J.; Keefe, P.S. )

    1993-12-01

    Electrolysis was performed with a palladium cathode and an electrolyte containing both hydrogen and deuterium ions. The cathode bends toward the anode during this process. Examination of both the concave and the convex surfaces with the scanning electron microscope, scanning tunneling microscope, and atomic force microscope shows unusual surface characteristics. Rimmed craters with faceted crystals inside and multitextural surfaces were observed on an electrolyzed palladium cathode but not on palladium that has not been electrolyzed. 9 refs., 9 figs.

  17. Minimizing Mould Growth in Cold Rooms Why does mould growth occur in Cold Rooms?

    E-Print Network [OSTI]

    Chan, Hue Sun

    , textiles, or other porous materials inside the cold room. Styrofoam is okay. Store files in plastic bins

  18. Probing Baryogenesis with Displaced Vertices at the LHC

    E-Print Network [OSTI]

    Yanou Cui; Brian Shuve

    2015-07-08

    The generation of the asymmetric cosmic baryon abundance requires a departure from thermal equilibrium in the early universe. In a large class of baryogenesis models, the baryon asymmetry results from the out-of-equilibrium decay of a new, massive particle. We highlight that in the interesting scenario where this particle has a weak scale mass, this out-of-equilibrium condition requires a proper decay length larger than O(1) mm. Such new fields are within reach of the LHC, at which they can be pair produced leaving a distinctive, displaced-vertex signature. This scenario is realized in the recently proposed mechanism of baryogenesis where the baryon asymmetry is produced through the freeze-out and subsequent decay of a meta-stable weakly interacting massive particle ("WIMP baryogenesis"). In analogy to missing energy searches for WIMP dark matter, the LHC is an excellent probe of these new long-lived particles responsible for baryogenesis via the low-background displaced vertex channel. In our paper, we estimate the limits on simplified models inspired by WIMP baryogenesis from two of the most sensitive collider searches by CMS and ATLAS with 8 TeV LHC data. We also estimate the LHC reach at 13 TeV using current strategies, and demonstrate that O(10) improvements in cross-section limits can be achieved by requiring two displaced vertices while lowering kinematic thresholds. For meta-stable WIMPs produced through electroweak interactions, the high luminosity LHC is sensitive to masses up to 2.5 TeV for lifetimes around 1 cm, while for singlets pair-produced through the off-shell-Higgs portal, the LHC is sensitive to production cross sections of O(50) ab for benchmark masses around 150 GeV. Our analysis and proposals also generally apply to displaced vertex signatures from other new physics such as hidden valley models, twin Higgs models and displaced supersymmetry.

  19. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01

    O 2 Cathode Material in Lithium Ion Batteries. Adv. Energydecomposition in lithium ion batteries: first-principlesMaterials for Lithium-Ion Batteries. Adv. Funct. Mater. 23,

  20. Charge state dependence of cathodic vacuum arc ion energy and velocity distributions

    E-Print Network [OSTI]

    Rosen, Johanna; Schneider, Jochen M.; Anders, Andre

    2006-01-01

    velocity in vacuum arc plasmas by arc current perturbationin aluminum vacuum arc plasma. We show that the conflictingdistinguished. Cathodic vacuum arc plasma is well known to

  1. The evolution of ion charge states in cathodic vacuum arc plasmas: a review

    E-Print Network [OSTI]

    Anders, Andre

    2013-01-01

    in metal vapor vacuum arc plasmas and ion sources," Plasmathe separation of cathodic arc plasma and macroparticles incharge states in vacuum arc plasmas in a magnetic field,"

  2. Simulations of multipacting in the cathode stalk and FPC of 112 MHz superconducting electron gun

    SciTech Connect (OSTI)

    Xin T.; Ben-Zvi, I.; Belomestnykh, S.; Chang, X.; Rao, T.; Skaritka, J.; Wu, Q.; Wang, E.; Liang, X.

    2012-05-20

    A 112 MHz superconducting quarter-wave resonator electron gun will be used as the injector of the Coherent Electron Cooling (CEC) proof-of-principle experiment at BNL. Furthermore, this electron gun can be used for testing of the performance of various high quantum efficiency photocathodes. In a previous paper, we presented the design of the cathode stalks and a Fundamental Power Coupler (FPC). In this paper we present updated designs of the cathode stalk and FPC. Multipacting in the cathode stalk and FPC was simulated using three different codes. All simulation results show no serious multipacting in the cathode stalk and FPC.

  3. Material and Energy Flows in the Production of Cathode and Anode...

    Office of Scientific and Technical Information (OSTI)

    and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the...

  4. Methods and apparatuses for making cathodes for high-temperature, rechargeable batteries

    DOE Patents [OSTI]

    Meinhardt, Kerry D; Sprenkle, Vincent L; Coffey, Gregory W

    2014-05-20

    The approaches for fabricating cathodes can be adapted to improve control over cathode composition and to better accommodate batteries of any shape and their assembly. For example, a first solid having an alkali metal halide, a second solid having a transition metal, and a third solid having an alkali metal aluminum halide are combined into a mixture. The mixture can be heated in a vacuum to a temperature that is greater than or equal to the melting point of the third solid. When the third solid is substantially molten liquid, the mixture is compressed into a desired cathode shape and then cooled to solidify the mixture in the desired cathode shape.

  5. Cathodic disbondment resistance with reactive ethylene terpolymer blends and composite coatings

    E-Print Network [OSTI]

    Love, Corey T.

    2008-01-01

    buried steel pipelines from corrosion, cathodic disbondmentfor the passive corrosion protection of pipelines around thepipelines. The corrosion of steel pipelines in soil is due

  6. Thermal Instability of Olivine-Type LiMnP04 Cathodes

    E-Print Network [OSTI]

    Chen, Guoying

    2010-01-01

    commercialization as a lithium ion battery cathode material.in the presence of a lithium-ion battery electrolyte is also

  7. R-Cold: Order (2013-CE-5354)

    Broader source: Energy.gov [DOE]

    DOE ordered R-Cold, Inc. to pay a $8,000 civil penalty after finding R-Cold had failed to certify that any basic models of walk-in cooler or freezer components comply with the applicable energy conservation standards.

  8. Gauss Sum Factorization with Cold Atoms

    SciTech Connect (OSTI)

    Gilowski, M.; Wendrich, T.; Mueller, T.; Ertmer, W.; Rasel, E. M. [Institut fuer Quantenoptik, Leibniz Universitaet Hannover, Welfengarten 1, D-30167 Hannover (Germany); Jentsch, Ch. [Astrium GmbH-Satellites, 88039 Friedrichshafen (Germany); Schleich, W. P. [Institut fuer Quantenphysik, Universitaet Ulm, Albert-Einstein-Allee 11, D-89081 Ulm (Germany)

    2008-01-25

    We report the first implementation of a Gauss sum factorization algorithm by an internal state Ramsey interferometer using cold atoms. A sequence of appropriately designed light pulses interacts with an ensemble of cold rubidium atoms. The final population in the involved atomic levels determines a Gauss sum. With this technique we factor the number N=263193.

  9. Electrophoretic Deposition for Inexpensive Carbon Nano-Composite Lithium Air Battery Cathodes Vanderbilt Institute of Nanoscale Science and Engineering Research Experience for Undergraduates Summer 2013

    E-Print Network [OSTI]

    materials [4]. In this study we use electropho- retic deposition (EPD) to create car- bon nanotube and nanotube-nanohorn composite cathodes and test batteries using them to compare discharge characteristics Conclusions Functionalized Nanotube Cathodes Unfunctionalized Nanotube Cathodes Electrophoretic Deposition

  10. A novel electron gun with an independently addressable cathode array.

    SciTech Connect (OSTI)

    Rudys, Joseph Matthew; Reed, Kim Warren; Peña, Gary Edward; Schneider, Larry X.

    2006-08-01

    The design of a novel electron gun with an array of independently addressable cathode elements is presented. Issues relating to operation in a 6.5 Tesla axial magnetic field are discussed. Simulations with the TriComp [1] electromagnetic field code that were used to determine the space charge limited tube characteristic and to model focusing of the electron beam in the magnetic field are reviewed. Foil heating and stress calculations are discussed. The results of CYLTRAN [2] simulations yielding the energy spectrum of the electron beam and the current transmitted through the foil window are presented.

  11. Pulsed rectifier limitations for well casing cathodic protection

    SciTech Connect (OSTI)

    Dabkowski, J. [Electro Sciences, Inc., Crystal Lake, IL (United States)

    1995-10-01

    Rectifier current pulses applied to deep well casings suffer considerable waveform deterioration as well depth increases. Cathodic protection (CP) attributed to the use of a pulsed rectifier will not be effective below a certain depth, which is a function of pulse characteristics and soil resistivity. A hypothetical 3,000-m length well casing is modeled as a distributed lossy electrical transmission line. Below 300- to 500-m depths, the higher frequency of the pulse is severely attenuated. Therefore, the CP process results at greater depths will not differ significantly from those obtained with a nonpulsed DC rectifier.

  12. Cathode Coating (IN-09-061) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReportsDeterminatIonFornl ProjectUPFDeterminationCathode Coating

  13. Advanced Cathode Catalysts and Supports for PEM Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A sCOLONY PROJECT under agreement SUBC-B555909,Cathode

  14. Modeling Cold Start in a Polymer-Electrolyte Fuel Cell

    E-Print Network [OSTI]

    Balliet, Ryan

    2010-01-01

    3.2.2.9 3.3 Cold—Start Simulation Transport of ions andperformance during cold start. Transport of water in thetransport overpotentials for the hydrogen electrode are neglected. Table 1.3: Automotive cold-

  15. New analogies between extreme QCD and cold atoms

    SciTech Connect (OSTI)

    Nishida, Yusuke

    2012-08-15

    We discuss two new analogies between extreme QCD and cold atoms. One is the analogue of 'hard probes' in cold atoms. The other is the analogue of 'quark-hadron continuity' in cold atoms.

  16. IDENTITIES OF DISPLACEMENT: WOMEN, HOME, AND TRANSNATIONAL VISUAL CULTURE

    E-Print Network [OSTI]

    Lee, Sohyun

    2010-04-22

    , in particular, the visuality of femininities. Not only do the concepts of home and displacement allow for a consideration of the relationship between the cultural context of globalization and identity formation, but they also provide a critical lens through... cultural theorists to rethink physical realities of home and to take notice of discursive dimensions of home. In her study on the expatriates on the Cayman Islands, anthropologist Karen Fog-Olwig, argues that the islanders “chose not to locate their home...

  17. A consistent formalism for the Thomas-Ehrman Level Displacement

    E-Print Network [OSTI]

    J. J. He; A. St. J. Murphy

    2007-04-26

    Usage of the Thomas-Ehrman Level Displacement formalism has been examined. Mistakes and inconsistencies are found in several papers, being repeated in subsequent works. Here, we present a complete formalism with a consistent set of definitions. Full algorithms are made available, both as a {\\tt FORTRAN} source file and as a user-friendly Visual Basic executable tool, available for download on the World Wide Web.

  18. Theoretical and experimental study on regenerative rotary displacer Stirling engine

    SciTech Connect (OSTI)

    Raggi, L.; Katsuta, Masafumi; Isshiki, Naotsugu; Isshiki, Seita

    1997-12-31

    Recently a quite new type of hot air engine called rotary displacer engine, in which the displacer is a rotating disk enclosed in a cylinder, has been conceived and developed. The working gas, contained in a notch excavated in the disk, is heated and cooled alternately, on account of the heat transferred through the enclosing cylinder that is heated at one side and cooled at the opposite one. The gas temperature oscillations cause the pressure fluctuations that get out mechanical power acting on a power piston. In order to attempt to increase the performances for this kind of engine, the authors propose three different regeneration methods. The first one comprises two coaxial disks that, revolving in opposite ways, cause a temperature gradient on the cylinder wall and a regenerative axial heat conduction through fins shaped on the cylinder inner wall. The other two methods are based on the heat transferred by a proper closed circuit that in one case has a circulating liquid inside and in the other one is formed by several heat pipes working each one for different temperatures. An engine based on the first principle, the Regenerative Tandem Contra-Rotary Displacer Stirling Engine, has been realized and experimented. In this paper experimental results with and without regeneration are reported comparatively with a detailed description of the unity. A basic explanation of the working principle of this engine and a theoretical analysis investigating the main influential parameters for the regenerative effect are done. This new rotating displacer Stirling engines, for their simplicity, are expected to attain high rotational speed especially for applications as demonstration and hobby unities.

  19. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

    SciTech Connect (OSTI)

    Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

    2008-01-20

    Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

  20. Compliant displacement-multiplying apparatus for microelectromechanical systems

    DOE Patents [OSTI]

    Kota, Sridhar (9391 Quail Ridge Run, Brighton, MI 48114); Rodgers, M. Steven (12216 Papaya Ct., NE., Albuquerque, NM 87111); Hetrick, Joel A. (818 S. Gammon, Apartment 4, Madison, WI 53719)

    2001-01-01

    A pivotless compliant structure is disclosed that can be used to increase the geometric advantage or mechanical advantage of a microelectromechanical (MEM) actuator such as an electrostatic comb actuator, a capacitive-plate electrostatic actuator, or a thermal actuator. The compliant structure, based on a combination of interconnected flexible beams and cross-beams formed of one or more layers of polysilicon or silicon nitride, can provide a geometric advantage of from about 5:1 to about 60:1 to multiply a 0.25-3 .mu.m displacement provided by a short-stroke actuator so that such an actuator can be used to generate a displacement stroke of about 10-34 .mu.m to operate a ratchet-driven MEM device or a microengine. The compliant structure has less play than conventional displacement-multiplying devices based on lever arms and pivoting joints, and is expected to be more reliable than such devices. The compliant structure and an associated electrostatic or thermal actuator can be formed on a common substrate (e.g. silicon) using surface micromachining.

  1. Achieving high mobility ZnO:Al at very high growth rates by dc filtered cathodic arc deposition

    E-Print Network [OSTI]

    Mendelsberg, Rueben

    2013-01-01

    scale heating in cathodic arc plasma deposition. Appl. Phys.modest 25-70 A dc. The arc plasma was ?ltered using aenergy of the cathodic arc plasma is utilized for ?lm growth

  2. COD removal characteristics in air-cathode microbial fuel cells Bioresource Technology, Volume 176, 2015, Pages 23-31.

    E-Print Network [OSTI]

    such as activated sludge process require large amount of energy to remove them. Microbial fuel cell (MFC-cathode microbial fuel cells - Renewable Energy Glob.Search... COD removal characteristics in air-cathode microbial fuel cells Bioresource Technology

  3. Cationic fluorinated polymer binders for microbial fuel cell cathodes{ Guang Chen,ab

    E-Print Network [OSTI]

    or carbons) in the cathode is held in contact with the current collector using a polymer binder.12Cationic fluorinated polymer binders for microbial fuel cell cathodes{ Guang Chen,ab Bin Wei.1039/c2ra20705b Fluorinated quaternary ammonium-containing polymers were used as catalyst binders

  4. Doped LiFePO? cathodes for high power density lithium ion batteries

    E-Print Network [OSTI]

    Bloking, Jason T. (Jason Thompson), 1979-

    2003-01-01

    Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

  5. Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy

    E-Print Network [OSTI]

    Subramanian, Venkat

    Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy to study the performance of cathode materials in lithium-ion batteries. The methodology takes into account. Published September 26, 2008. Lithium-ion batteries are state-of-the-art power sources1 for por- table

  6. Geometrical Aspects of a Hollow-Cathode Magnetron (HCM) Zhehui Wang and Samuel A. Cohen

    E-Print Network [OSTI]

    -sputtering-magnetron (PSM) cathode with a hollow-cathode structure (HCS), see FIG. 1. The HCS is a right cylinder characterized by its length L and inner diameter D. A conventional PSM can be regarded as an extreme of a HCM volume is generated within the HCM than in its PSM counterpart. This feature may allow HCM plasmas

  7. High Current Density, Long Life Cathodes for High Power RF Sources

    SciTech Connect (OSTI)

    Ives, Robert Lawrence; Collins, George; Falce, Lou; Schwartzkopf, Steve; Busbaher, Daniel

    2014-01-22

    This program was tasked with improving the quality and expanding applications for Controlled Porosity Reservoir (CPR) cathodes. Calabazas Creek Research, Inc. (CCR) initially developed CPR cathodes on a DOE-funded SBIR program to improve cathodes for magnetron injection guns. Subsequent funding was received from the Defense Advanced Research Projects Agency. The program developed design requirements for implementation of the technology into high current density cathodes for high frequency applications. During Phase I of this program, CCR was awarded the prestigious 2011 R&D100 award for this technology. Subsequently, the technology was presented at numerous technical conferences. A patent was issued for the technology in 2009. These cathodes are now marketed by Semicon Associates, Inc. in Lexington, KY. They are the world’s largest producer of cathodes for vacuum electron devices. During this program, CCR teamed with Semicon Associates, Inc. and Ron Witherspoon, Inc. to improve the fabrication processes and expand applications for the cathodes. Specific fabrications issues included the quality of the wire winding that provides the basic structure and the sintering to bond the wires into a robust, cohesive structure. The program also developed improved techniques for integrating the resulting material into cathodes for electron guns.

  8. Characterization of a Filtered High Current Pulsed Cathodic Vacuum Arc Plasma Source: Plasma Transport Analysis

    SciTech Connect (OSTI)

    Sangines, R.; Tarrant, R. N.; Bilek, M. M. M.; McKenzie, D. R.; Andruczyk, D.

    2008-03-19

    Studies of plasma behavior produced by a filtered high current pulsed cathodic vacuum arc system are reported. Titanium plasma is initiated from the cathode by surface flash over triggering at the centre of the cathode disk. The multiple arc spots move outwards due to their mutual repulsion and the arc current pulse is terminated as the arc spots reach the edge of the cathode disk. The plasma moves into a positively biased quarter-torus magnetic filter and is guided towards the substrate position located 150 mm beyond the filter exit. Electron density and plasma current measurements have been employed to analyze the transport of the plasma associated with different cathode currents, and its dependence on confining magnetic field and bias conditions. For a given cathode current, the optimum plasma transport to the substrate requires the right combination of the strength of the confining magnetic field and the magnetic filter positive bias. The optimum values of these two parameters were found to increase with increasing cathode current. Initially the optimum throughput of plasma increases more strongly than the arc current (roughly 1.5 times the increase in the current); however, at high cathode current regimes (2.4 kA) a significant change of the plasma behavior is seen and transport efficiency is reduced.

  9. On the mechanism of operation of a cathode spot cell in a vacuum arc

    SciTech Connect (OSTI)

    Mesyats, G. A.; Petrov, A. A.; Bochkarev, M. B.; Barengolts, S. A.

    2014-05-05

    The erosive structures formed on a tungsten cathode as a result of the motion of the cathode spot of a vacuum arc over the cathode surface have been examined. It has been found that the average mass of a cathode microprotrusion having the shape of a solidified jet is approximately equal to the mass of ions removed from the cathode within the lifetime of a cathode spot cell carrying a current of several amperes. The time of formation of a new liquid-metal jet under the action of the reactive force of the plasma ejected by the cathode spot is about 10?ns, which is comparable to the lifetime of a cell. The growth rate of a liquid-metal jet is ?10{sup 4}?cm/s. The geometric shape and size of a solidified jet are such that a new explosive emission center (spot cell) can be initiated within several nanoseconds during the interaction of the jet with the dense cathode plasma. This is the underlying mechanism of the self-sustained operation of a vacuum arc.

  10. How to Make Cathodes with a Diffusion Layer for Single-Chamber Microbial Fuel Cells

    E-Print Network [OSTI]

    ) The instructions below describe how to make 12 cm2 circular cathodes with a polytetrafluoroethylene (PTFE wait time. Pt/C Catalyst Layer PTFE Diffusion Layers AIR SIDESOLUTION SIDE Carbon Cloth Carbon Base Layer Figure 1: Exaggerated side-view of a cathode with a four-coating PTFE diffusion layer Materials

  11. Re-generable Field Emission Cathodes Part II: Quenched Emitter Performance Analyses

    E-Print Network [OSTI]

    King, Lyon B.

    Re-generable Field Emission Cathodes Part II: Quenched Emitter Performance Analyses Jason M. Makela emission cathodes have been considered for use as neutralizers on electric propulsion systems. In order to be compatible with EP, the field emission electron sources must be capable of long-life operation and must

  12. Re-generable Field Emission Cathodes Part I: Surface Morphology of Emitter Apex

    E-Print Network [OSTI]

    King, Lyon B.

    Re-generable Field Emission Cathodes Part I: Surface Morphology of Emitter Apex Jason M. Makela This is the first part of a two-part paper that focuses on a field-emission cathode for use in Electric Propulsion was then subjected to electron-extracting potentials stable and long-lived electron emission was observed. The focus

  13. Proton-Induced Dysfunction Mechanism of Cathodes in an Aqueous Lithium Ion Battery

    E-Print Network [OSTI]

    Gong, Xingao

    Proton-Induced Dysfunction Mechanism of Cathodes in an Aqueous Lithium Ion Battery Qiang Shu, Long: The proton-induced dysfunction mechanism of cathodes in aqueous lithium ion batteries is investigated of the Li+ and H+ in the solution. Lithium ion batteries (LIBs) have been proved to be com- mercially

  14. Study of Ionic Conductivity Profiles of the Air Cathode of a PEMFC by AC Impedance Spectroscopy

    E-Print Network [OSTI]

    Study of Ionic Conductivity Profiles of the Air Cathode of a PEMFC by AC Impedance Spectroscopy membrane fuel cell PEMFC cathode by ac impedance measurement at open-circuit potential conditions membrane fuel cell PEMFC .1 The function of a proton-conducting ionomer such as Nafion® is to provide

  15. Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells M.J. Kermani1 J and N2, through the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically) an energy equation, written in a form that has enthalpy as the dependent variable. Keywords: PEM fuel cells

  16. The use and optimization of stainless steel mesh cathodes in microbial electrolysis cells

    E-Print Network [OSTI]

    The use and optimization of stainless steel mesh cathodes in microbial electrolysis cells Yimin September 2010 Keywords: Stainless steel mesh Microbial electrolysis cell Cathode a b s t r a c t Microbial- ramethylphenylporphyrin (CoTMPP & FeCoTMPP) [8], nickel oxide [9], stainless steel (SS) [9e11], and tungsten carbide [12

  17. Increasing power generation for scaling up single-chamber air cathode microbial fuel cells

    E-Print Network [OSTI]

    power density was shown to be a linear function of cathode specific surface area (ratio of cathode is the most critical factor for scaling-up MFCs to obtain high power densities. Ó 2010 Elsevier Ltd. All potential as a tech- nology for sustainable bioenergy production due to their ability to generate

  18. Raman Microscopy of Lithium-Manganese-Rich Cathodes

    SciTech Connect (OSTI)

    Ruther, Rose E [ORNL; Callender, Andrew F. [Tennessee Technological University; Zhou, Hui [ORNL; Martha, Surendra [Indian Institute of Technology, Hyderabad; Nanda, Jagjit [ORNL

    2014-01-01

    Lithium rich, manganese rich composites with general formula xLi2MnO3 (1-x)LiMO2 are promising candidates for high capacity and high voltage cathodes for lithium ion batteries. Lithium rich oxides crystallize as a nanocomposite of layered phases whose structure further evolves with electrochemical cycling. Raman spectroscopy is potentially a powerful tool to monitor the crystal chemistry and correlate phase changes with electrochemical behavior. While several groups have reported Raman spectra of lithium rich oxides, the data show considerable variability in terms of both the vibrational features observed and their interpretation. In this study Raman microscopy is used to investigate lithium-rich manganese-rich cathodes as a function of average charge and electrochemical cycling. LMR-NMC cycled at elevated temperature (60 C) has a modified crystal structure which may account for some of the observed increase in capacity. Contrary to some reports, no growth of a spinel phase is observed. However, analysis of the Raman spectra does indicate the structure of LMR-NMC deviates significantly from an ideal layered phase. The results also highlight the importance of using low laser power and large sample sizes to obtain consistent data sets.

  19. Residential Cold Climate Heat Pump with Variable-Speed Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Cold Climate Heat Pump with Variable-Speed Technology Residential Cold Climate Heat Pump with Variable-Speed Technology Purdue prototype system Purdue prototype system...

  20. Advanced Composite Materials for Cold and Cryogenic Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Composite Materials for Cold and Cryogenic Hydrogen Storage Applications in Fuel Cell Electric Vehicles Workshop Advanced Composite Materials for Cold and Cryogenic Hydrogen...

  1. Linking Legacies: Connecting the Cold War Nuclear Weapons Production...

    Office of Environmental Management (EM)

    Linking Legacies: Connecting the Cold War Nuclear Weapons Production Processes to Their Environmental Consequences Linking Legacies: Connecting the Cold War Nuclear Weapons...

  2. Modification of the Dykstra-Parsons method to incorporate Buckley-Leverett displacement theory for waterfloods 

    E-Print Network [OSTI]

    Gasimov, Rustam Rauf

    2005-11-01

    -water relative permeability for each layer. A new analytical model for layer 1-D oil displacement by water in multilayered reservoir has been developed that incorporates Buckley-Leverett displacement and different oilwater relative permeability and water...

  3. A comparison of the marginal adaptation of cathode-arc vapor-deposited titanium and cast base metal copings.

    E-Print Network [OSTI]

    Wu, Jean C; Lai, Li-Chung; Sheets, Cherilyn G; Earthman, James; Newcomb, Robert

    2011-01-01

    thick, dark titanium oxide layer. The new cathode-arc vaporcolor of the titanium oxide layer resulted in compromised

  4. Vacuum encapsulated, high temperature diamond amplified cathode capsule and method for making same

    DOE Patents [OSTI]

    Rao, Triveni; Walsh, John; Gangone, Elizabeth

    2015-12-29

    A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first high-temperature solder weld disposed between the diamond window element and the annular insulating spacer and a second high-temperature solder weld disposed between the annular insulating spacer and the cathode element. The cathode capsule is formed by a high temperature weld process under vacuum such that the first solder weld forms a hermetical seal between the diamond window element and the annular insulating spacer and the second solder weld forms a hermetical seal between the annular spacer and the cathode element whereby a vacuum encapsulated chamber is formed within the capsule.

  5. Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Franz, Robert; Polcik, Peter; Anders, André

    2015-06-01

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr2+ ions were dominating in Ar and N2 and Cr+ in O2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected tomore »collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.« less

  6. Raman subrecoil spectroscopy of cold cesium atoms

    E-Print Network [OSTI]

    J. Ringot; P. Szriftgiser; J. C. Garreau

    2001-07-28

    We describe and characterize a setup for subrecoil stimulated Raman spectroscopy of cold cesium atoms. We study in particular the performances of a method designed to active control and stabilization of the magnetic fields across a cold-atom cloud inside a small vacuum cell. The performance of the setup is monitored by {\\em copropagative-beam} stimulated Raman spectroscopy of a cold cesium sample. The root mean-square value of the residual magnetic field is 300 $\\mu G$, with a compensation bandwidth of 500 Hz. The shape of the observed spectra is theoretically interpreted and compares very well to numerically generated spectra.

  7. Impacts of Electric Vehicles on Primary Energy Consumption and Petroleum Displacement

    E-Print Network [OSTI]

    Wang, Quanlu; Delucchi, Mark A.

    1991-01-01

    on Primary Energy Consumption and Petroleum Displacementon Primary Energy Consumption and Petroleum Displacementprimary energy savings impacts and petroleum displacement

  8. The Orientation Distributions of Lines, Surfaces, and Interfaces around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    in a multiphase ceramic material. I. Introduction THE active cathode regions of many solid oxide fuel cells (SOFCs in Solid Oxide Fuel Cell Cathodes Shen J. Dillon, Lam Helmick,§,¶ Herbert M. Miller,§ Lane Wilson relevant triple phase boundary lines and surfaces near them in SOFC cathodes made up of a porous mixture

  9. COLD FUSION ONE YEAR AFTER R. Battiston and C. Presilla

    E-Print Network [OSTI]

    Presilla, Carlo

    of deuterium, initially faxed around the world and later published on the Journal of Electroanalytic Chemistry and palladium cathodes, in a solution 0.1 M of LiOD in 99.5% D20+0.S% H20. The Pd cathode was electrolytically preloaded with deuterium. When the equilibrium was reached, the solution temperature was continuously

  10. STS.436 Cold War Science, Spring 2004

    E-Print Network [OSTI]

    Kaiser, David

    This course examines the history and legacy of the Cold War on science, looking predominantly at examples in the United States. It begins by exploring scientists’ new political roles after World War II, ranging from elite ...

  11. It was 1986, during the Cold War...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    was 1986, during the Cold War, and I had finished my session at a large conference focused on topics related to nuclear war. It was lunchtime. I walked into the lunchroom. I...

  12. Cold quark matter in compact stars

    SciTech Connect (OSTI)

    Franzon, B.; Fogaca, D. A.; Navarra, F. S.; Horvath, J. E.

    2013-03-25

    We used an equation of state for the cold quark matter to the study of properties of quark stars. We also discuss the absolute stability of quark matter and compute the mass-radius relation for self-bound stars.

  13. Trapping cold rubidium in a fiber

    E-Print Network [OSTI]

    Brown, David Ross, S.B. Massachusetts Institute of Technology

    2007-01-01

    In this thesis, we demonstrate the novel technique of loading cold ??Rb into a red-detuned optical dipole trap within a hollow core photonic fiber. This confines the atoms to 6 microns in two dimensions. We initially cooled ...

  14. E-Commerce cold chain fulfillment

    E-Print Network [OSTI]

    Yakzan, Mounir

    2015-01-01

    A challenging part of E-Commerce for perishable consumer packaged goods (PCPG) is the fulfillment. Given the fragile nature of the items shipped, they require a low cost, effective cold chain fulfillment method so as to ...

  15. Some Calculations for Cold Fusion Superheavy Elements

    E-Print Network [OSTI]

    Zhong, X H; Ning, P Z

    2004-01-01

    The Q value and optimal exciting energy of the hypothetical superheavy nuclei in cold fusion reaction are calculated with relativistic mean field model and semiemperical shell model mass equation(SSME) and the validity of the two models is tested. The fusion barriers are also calculated with two different models and reasonable results are obtained. The calculations can give useful references for the experiments in the superheavy nuclei synthesized in cold fusion reactions.

  16. Implications of Theoretical Ideas Regarding Cold Fusion

    E-Print Network [OSTI]

    Afsar Abbas

    1995-03-29

    A lot of theoretical ideas have been floated to explain the so called cold fusion phenomenon. I look at a large subset of these and study further physical implications of the concepts involved. I suggest that these can be tested by other independent physical means. Because of the significance of these the experimentalists are urged to look for these signatures. The results in turn will be important for a better understanding and hence control of the cold fusion phenomenon.

  17. Some Calculations for Cold Fusion Superheavy Elements

    E-Print Network [OSTI]

    X. H. Zhong; L. Li; P. Z. Ning

    2004-10-18

    The Q value and optimal exciting energy of the hypothetical superheavy nuclei in cold fusion reaction are calculated with relativistic mean field model and semiemperical shell model mass equation(SSME) and the validity of the two models is tested. The fusion barriers are also calculated with two different models and reasonable results are obtained. The calculations can give useful references for the experiments in the superheavy nuclei synthesized in cold fusion reactions.

  18. Toxicity evaluation and hazard review Cold Smoke

    SciTech Connect (OSTI)

    Archuleta, M.M.; Stocum, W.E.

    1993-12-01

    Cold Smoke is a dense white smoke produced by the reaction of titanium tetrachloride and aqueous ammonia aerosols. Early studies on the toxicity of this nonpyrotechnically generated smoke indicated that the smoke itself is essentially non-toxic (i.e. exhibits to systemic toxicity or organ damage due to exposure) under normal deployment conditions. The purpose of this evaluation was to review and summarize the recent literature data available on the toxicity of Cold Smoke, its chemical constituents, and its starting materials.

  19. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  20. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  1. Energy level displacement of excited np states of kaonic hydrogen

    E-Print Network [OSTI]

    A. N. Ivanov; M. Cargnelli; M. Faber; H. Fuhrmann; V. A. Ivanova; J. Marton; N. I. Troitskaya; J. Zmeskal

    2005-04-09

    We compute the energy level displacement of the excited np states of kaonic hydrogen within the quantum field theoretic and relativistic covariant model of strong low-energy bar-KN interactions suggested in EPJA21, 11 (2004). For the width of the energy level of the excited 2p state of kaonic hydrogen, caused by strong low-energy interactions, we find Gamma_2p = 2 meV. This result is important for the theoretical analysis of the X-ray yields in kaonic hydrogen.

  2. Energy level displacement of excited np state of kaonic hydrogen

    E-Print Network [OSTI]

    Ivanov, A N; Faber, M; Fuhrmann, H; Ivanova, V A; Marton, J; Troitskaya, N I; Zmeskal, J

    2004-01-01

    We have computed the energy level displacement of the excited np state of kaonic hydrogen within the quantum field theoretic and relativistic covariant model of strong low-energy bar-KN interactions suggested in EPJA21, 11 (2004). For the width of the energy level of the excited 2p state of kaonic hydrogen, caused by strong low-energy interactions, we have got Gamma_2p = 2 meV. The obtained result is important for the theoretical analysis of the X-ray yields in kaonic hydrogen.

  3. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M.; Woan, Karran V.; Bell, Nelson Simmons

    2010-11-01

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  4. Analysis of deformed palladium cathodes resulting from heavy water electrolysis

    SciTech Connect (OSTI)

    An, H.K.; Jeong, E.J.; Hong, J.H.; Lee, Y.

    1995-07-01

    Earlier experiments suggested that large differences in heat release between the two sides of a palladium electrode coated with gold on one side and manganese oxide on the other cause observed electrode deformation with high-pressure D{sub 2} gas loading in an electrolysis-like cell. Similar experiments were repeated using heavy water electrolysis. Palladium/titanium coatings on one side and gold coating on the other were made for the preparation of the palladium electrodes. Biaxial bending, partial discoloration, and microcracks of palladium electrodes were observed after 18 days of electrolysis. Analysis of the deformed palladium cathodes was performed. It was discovered that to convert this configuration to a practical energy-producing cell, a coating technique must be found to reduce outward diffusion of deuterium, i.e., to maintain a high D/Pd ratio over longer periods of time. 33 refs., 7 figs., 1 tab.

  5. Cold Air Distribution in Office Buildings: Technology Assessment for California

    E-Print Network [OSTI]

    Bauman, F.S.

    2008-01-01

    energy commission representatives, and other users of cold air distribution technology. The contact list

  6. Analyses of palladium cathodes used for heavy water electrolysis

    SciTech Connect (OSTI)

    Kumar, K.; Dauwalter, C.R.; Stecyk, A. )

    1991-01-01

    This paper reports on the sporadic nature of the excess heat reported from heavy water electrolysis which has attributed to variability among the different palladium cathodes used. Experimental repeatability should, therefore, be enhanced if the microstructure of the palladium can be controlled. Toward this end, palladium rod samples from two heavy water electrolysis experiments were compared to a sample representative of the as-installed condition. The samples examined showed equiaxed grains and significant abnormal grain growth. The rod axes had strong textures, which were attributed to their prior thermomechanical history. The postelectrolysis palladium rods were sampled at two locations that were suspected to have operated at different average current densities. The suspected higher current density regions consisted of single-phase Pd-D{sub 0.7} microstructures. Surface-originated cracks were seen along the grain boundaries in one of two such specimens. Cracks were absent in samples from the suspected lower current density regions, which showed two-phase microstructures with Pd-D{sub 0.7} as the dominant phase. The minor phase, indexed as palladium in the X-ray pattern, was dispersed nonuniformly, mostly in the form of stringers, across the grain boundaries. It is concluded that high current densities resulted in high deuterium loadings in palladium. Smoothing effects from the electrolytic process, resulting in preferential material removal from the grain boundaries, were seen on the cathode surface. A number of high-mass impurities were seen to have deposited on the exposed surface. An initial secondary ion mass spectrometry examination of the specimen interior indicated a significant presence of mass 2 species and considerably lower concentrations of mass 3 and 4 species. Repeat analyses failed to confirm the presence of the mass 3 and 4 species.

  7. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wongchang

    2014-05-13

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  8. IN-SITU XRD OF OPERATING LSFC CATHODES: DEVELOPMENT OF A NEW ANALYTICAL CAPABILITY

    SciTech Connect (OSTI)

    Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

    2012-11-19

    A solid oxide fuel cell (SOFC) research capability has been developed that facilitates measuring the electrochemical performance of an operating SOFC while simultaneously performing x-ray diffraction on its cathode. The evolution of this research tool’s development is discussed together with a description of the instrumentation used for in-situ x-ray diffraction (XRD) measurements of operating SOFC cathodes. The challenges that were overcome in the process of developing this capability, which included seals and cathode current collectors, are described together with the solutions that are presently being applied to mitigate them.

  9. Color-Induced Displacement double stars in SDSS

    E-Print Network [OSTI]

    D. Pourbaix; Z. Ivezic; G. R. Knapp; J. E. Gunn

    2004-03-09

    We report the first successful application of the astrometric color-induced displacement technique (CID, the displacement of the photocenter between different bandpasses due to a varying contribution of differently colored components to the total light), originally proposed by Wielen (1996) for discovering unresolved binary stars. Using the Sloan Digital Sky Survey (SDSS) Data Release 1 with 2.5 million stars brighter than 21m in the u and g bands, we select 419 candidate binary stars with CID greater than 0.5 arcsec. The SDSS colors of the majority of these candidates are consistent with binary systems including a white dwarf and any main sequence star with spectral type later than ~K7. The astrometric CID method discussed here is complementary to the photometric selection of binary stars in SDSS discussed by Smolcic et al. (2004), but there is considerable overlap (15%) between the two samples of selected candidates. This overlap testifies both to the physical soundness of both methods, as well as to the astrometric and photometric quality of SDSS data.

  10. Cold atmospheric plasma in cancer therapy

    SciTech Connect (OSTI)

    Keidar, Michael; Shashurin, Alex; Volotskova, Olga; Ann Stepp, Mary; Srinivasan, Priya; Sandler, Anthony; Trink, Barry

    2013-05-15

    Recent progress in atmospheric plasmas has led to the creation of cold plasmas with ion temperature close to room temperature. This paper outlines recent progress in understanding of cold plasma physics as well as application of cold atmospheric plasma (CAP) in cancer therapy. Varieties of novel plasma diagnostic techniques were developed recently in a quest to understand physics of CAP. It was established that the streamer head charge is about 10{sup 8} electrons, the electrical field in the head vicinity is about 10{sup 7} V/m, and the electron density of the streamer column is about 10{sup 19} m{sup ?3}. Both in-vitro and in-vivo studies of CAP action on cancer were performed. It was shown that the cold plasma application selectively eradicates cancer cells in-vitro without damaging normal cells and significantly reduces tumor size in-vivo. Studies indicate that the mechanism of action of cold plasma on cancer cells is related to generation of reactive oxygen species with possible induction of the apoptosis pathway. It is also shown that the cancer cells are more susceptible to the effects of CAP because a greater percentage of cells are in the S phase of the cell cycle.

  11. Cold versus hot fusion deuterium branching ratios

    SciTech Connect (OSTI)

    Fox, H.; Bass, R.

    1995-12-31

    A major source of misunderstanding of the nature of cold nuclear fusion has been the expectation that the deuterium branching ratios occurring within a palladium lattice would be consistent with the gas-plasma branching ratios. This misunderstanding has led to the concept of the dead graduate student, the 1989`s feverish but fruitless search for neutron emissions from cold fusion reactors, and the follow-on condemnation of the new science of cold fusion. The experimental facts are that in a properly loaded palladium lattice, the deuterium fusion produces neutrons at little above background, a greatly less-than-expected production of tritium (the tritium desert), and substantially more helium-4 than is observed in hot plasma physics. The experimental evidence is now compelling (800 reports of success from 30 countries) that cold nuclear fusion is a reality, that the branching ratios are unexpected, and that a new science is struggling to be recognized. Commercialization of some types of cold fusion devices has already begun.

  12. Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

    E-Print Network [OSTI]

    Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

    2003-01-01

    Cathode for Lithium-Ion Batteries J. Shim a , A. Guerfi b ,material for Li rechargeable batteries because of low-cost,is a part of BATT (Batteries for Advanced Transportation

  13. Nanocrystallization of LiCoO2 Cathodes for Thin Film Batteries Utilizing Pulse Thermal Processing

    SciTech Connect (OSTI)

    2009-04-01

    This factsheet describes a study whose focus is on the nanocrystallization of the LiCoO2 cathode thin films on polyimide substrates and evaluate the microstructural evolution and resistance as a function of PTP processing conditions.

  14. Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries

    E-Print Network [OSTI]

    Davis, Robin M. (Robin Manes)

    2005-01-01

    Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

  15. Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries

    E-Print Network [OSTI]

    Moore, Charles J. (Charles Jacob)

    2012-01-01

    A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

  16. Measurements of the Ion Species of Cathodic Arc Plasma in an Axial Magnetic Field

    E-Print Network [OSTI]

    Oks, Efim

    2011-01-01

    distributions of a vacuum arc plasma," Rev. Sci. Instrum. ,by filtered cathodic arc plasma," physica status solidi (a),in high current vacuum arc plasma in a magnetic field," IEEE

  17. Ultrathin ta-C films on heads depositied by twist-filtered cathodic arc carbon plasmas

    E-Print Network [OSTI]

    Anders, Andre; Ryan, Francis W.

    2000-01-01

    Ion velocities in vacuum arc plasmas. submitted to J. Appl.to rid cathodic arc plasma of macro- and nanoparticles: aBrown, Transport of vacuum arc plasma through straight and

  18. Approaches to rid cathodic arc plasmas of macro- and nanoparticles: A review

    E-Print Network [OSTI]

    Anders, Andre

    2008-01-01

    Sablev, and R. I. Stupka, Plasma arc apparatus for applyingMagnetically filtered cathodic arc plasma apparatus, PatentRectangular vacuum-arc plasma source, Patent 5,480,527, Jan.

  19. Correlation between cathode properties, burning voltage, and plasma parameters of vacuum arcs

    SciTech Connect (OSTI)

    Anders, Andre; Yotsombat, Banchob; Binder, Robert

    2001-06-15

    Burning voltages of vacuum arcs were measured for 54 cathode materials and compared with literature data. As anticipated, a correlation between the arc burning voltage and the plasma temperature was found. However, more importantly, a correlation between the cohesive energy of the cathode material and the arc burning voltage could be demonstrated. This link between a cathode material property, the cohesive energy, and a discharge property, the arc burning voltage, is essential for the operation of the vacuum arc discharge because is determines the plasma temperature. Energy balance considerations show that this {open_quotes}cohesive energy rule{close_quotes} is responsible for several other secondary relationships, such as the correlation between the mean ion charge state and the boiling temperature of the cathode. {copyright} 2001 American Institute of Physics.

  20. Evaluation of plasma-sprayed CoS{sub 2} cathodes for thermal batteries

    SciTech Connect (OSTI)

    Guidotti, R.A.

    1999-12-22

    Conventional electroactive stack components in thermal batteries are constructed from pressed-powder parts. These include the anode, separator, and cathode pellets (discs). Pressing parts that are less than 0.010 inch thick is difficult. The use of plasma spray to deposit thin CoS{sub 2} cathode films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The plasma-sprayed electrodes were tested in single cells under isothermal conditions and constant-current discharge over a temperature range of 400 C to 550 C using standard LiSi anodes and separators based on the LiCl-KCl eutectic. Similar tests were conducted with cells built with conventional pressed-powder cathodes, which were tested under the same conditions for comparative purposes. This paper presents the results of those tests.

  1. Model of calcareous deposit formation on cathodically protected steel in seawater: improvements and extensions 

    E-Print Network [OSTI]

    Blackburne, Patricia Nicole

    1996-01-01

    A mathematical model of calcareous deposits on cathodically protected steel in seawater has been improved for practical applications. The model can be used in industry and as a pedagogical tool. The model extracts useful information from National...

  2. Supply and demand in the material recovery system for cathode ray tube glass

    E-Print Network [OSTI]

    Nadeau, Marie-Claude

    This paper presents an analysis of the material recovery system for leaded glass from cathode ray tubes (CRTs). In particular, the global mass flow of primary and secondary CRT glass and the theoretical capacities for using ...

  3. Advanced Lithium Battery Cathodes Using Dispersed Carbon Fibers as the Current Collector

    SciTech Connect (OSTI)

    Martha, Surendra K; Kiggans, Jim; Nanda, Jagjit; Dudney, Nancy J

    2011-01-01

    To fabricate LiFePO4 battery cathodes, highly conductive carbon fibers of 10-20 m in diameter have been used to replace a conventional aluminum (Al) foil current collector. This disperses the current collector throughout the cathode sheet and increases the contact area with the LiFePO4 (LFP) particles. In addition, the usual organic binder plus carbon-black can be replaced by a high temperature binder of <5 weight % carbonized petroleum pitch (P-pitch). Together these replacements increase the specific energy density and energy per unit area of the electrode. Details of the coating procedure, characterization and approach for maximizing the energy density are discussed. In a side-by-side comparison with conventional cathodes sheets of LFP on Al foil, the carbon fiber composite cathodes have a longer cycle life, higher thermal stability, and high capacity utilization with little sacrifice of the rate performance.

  4. NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-10-01

    Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

  5. Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell

    Broader source: Energy.gov [DOE]

    Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy novel cathode / alloy...

  6. The role of phase transformation in the rate performance limited Lix? V? O? battery cathode

    E-Print Network [OSTI]

    Avery, Kenneth Charles

    2009-01-01

    It has recently been reported that the rate performance of Lix? V?O?, a widely studied candidate Li-ion battery cathode material, can be significantly improved through a variety of particle size reduction techniques, (e.g. ...

  7. Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells IV. On the Ohmic loss in anode supported button cells with LSM or LSCF cathodes

    SciTech Connect (OSTI)

    Lu, Zigui; Zhou, Xiao Dong; Templeton, Jared W.; Stevenson, Jeffry W.

    2010-05-08

    Anode-supported solid oxide fuel cells (SOFC) with a variety of YSZ electrolyte thicknesses were fabricated by tape casting and lamination. The preparation of the YSZ electrolyte tapes with various thicknesses was accomplished by using doctor blades with different gaps between the precision machined, polished blade and the casting surface. The green tape was cut into discs, sintered at 1385°C for 2 h, and subsequently creep-flattened at 1350°C for 2 h. Either LSCF with an SDC interlayer or LSM+YSZ composite was used as the cathode material for the fuel cells. The ohmic resistances of these anode-supported fuel cells were characterized by electrochemical impedance spectroscopy at temperatures from 500°C to 750°C. A linear relationship was found between the ohmic resistance of the fuel cell and the YSZ electrolyte thickness at all the measuring temperatures for both LSCF and LSM+YSZ cathode fuel cells. The ionic conductivities of the YSZ electrolyte, derived for the fuel cells with LSM+YSZ or LSCF cathodes, were independent of the cathode material and cell configuration. The ionic conductivities of the YSZ electrolyte was slightly lower than that of the bulk material, possibly due to Ni-doping into the electrolyte. The fuel cell with a SDC interlayer and LSCF cathode showed larger intercept resistance than the fuel cell with LSM+YSZ cathode, which was possibly due to the imperfect contact between the SDC interlayer and the YSZ electrolyte and the migration of Zr into the SDC interlayer to form an insulating solid solution during cell fabrication. Calculations of the contribution of the YSZ electrolyte to the total ohmic resistance showed that YSZ was still a satisfactory electrolyte at temperatures above 650°C. Explorations should be directed to reduce the intercept resistance to achieve significant improvement in cell performance.

  8. Analytical expression for the electric potential in the plasma sheath near an arc-cathode

    SciTech Connect (OSTI)

    Askari, S.; Minoo, H.

    2008-04-15

    An expression for the spatial dependence of the electric potential in a collisionless plasma sheath near an electron-emitting cathode is presented. The applicability of this expression for an arc cathode is demonstrated. Comparison with the numerical solutions of the model equations indicates that the sheath thickness and potential variation predicted by this expression are accurate in a wide range of the electron-emission yield.

  9. Oxygen transport in the internal xenon plasma of a dispenser hollow cathode

    SciTech Connect (OSTI)

    Capece, Angela M. Shepherd, Joseph E.; Polk, James E.; Mikellides, Ioannis G.

    2014-04-21

    Reactive gases such as oxygen and water vapor modify the surface morphology of BaO dispenser cathodes and degrade the electron emission properties. For vacuum cathodes operating at fixed temperature, the emission current drops rapidly when oxygen adsorbs on top of the low work function surface. Previous experiments have shown that plasma cathodes are more resistant to oxygen poisoning and can operate with O{sub 2} partial pressures one to two orders of magnitude higher than vacuum cathodes before the onset of poisoning occurs. Plasma cathodes used for electric thrusters are typically operated with xenon; however, gas phase barium, oxygen, and tungsten species may be found in small concentrations. The densities of these minor species are small compared with the plasma density, and thus, their presence in the discharge does not significantly alter the xenon plasma parameters. It is important, however, to consider the transport of these minor species as they may deposit on the emitter surface and affect the electron emission properties. In this work, we present the results of a material transport model used to predict oxygen fluxes to the cathode surface by solving the species conservation equations in a cathode with a 2.25?mm diameter orifice operated at a discharge current of 15?A, a Xe flow rate of 3.7 sccm, and 100?ppm of O{sub 2}. The dominant ionization process for O{sub 2} is resonant charge exchange with xenon ions. Ba is effectively recycled in the plasma; however, BaO and O{sub 2} are not. The model shows that the oxygen flux to the surface is not diffusion-limited; therefore, the high resistance to oxygen poisoning observed in plasma cathodes likely results from surface processes not considered here.

  10. Pore Scale Modeling of the Reactive Transport of Chromium in the Cathode of a Solid Oxide Fuel Cell

    SciTech Connect (OSTI)

    Ryan, Emily M.; Tartakovsky, Alexandre M.; Recknagle, Kurtis P.; Khaleel, Mohammad A.; Amon, Cristina

    2011-01-01

    We present a pore scale model of a solid oxide fuel cell (SOFC) cathode. Volatile chromium species are known to migrate from the current collector of the SOFC into the cathode where over time they decrease the voltage output of the fuel cell. A pore scale model is used to investigate the reactive transport of chromium species in the cathode and to study the driving forces of chromium poisoning. A multi-scale modeling approach is proposed which uses a cell level model of the cathode, air channel and current collector to determine the boundary conditions for a pore scale model of a section of the cathode. The pore scale model uses a discrete representation of the cathode to explicitly model the surface reactions of oxygen and chromium with a cathode material. The pore scale model is used to study the reaction mechanisms of chromium by considering the effects of reaction rates, diffusion coefficients, chromium vaporization, and oxygen consumption on chromium’s deposition in the cathode. The study shows that chromium poisoning is most significantly affected by the chromium reaction rates in the cathode and that the reaction rates are a function of the local current density in the cathode.

  11. Hollow cathode theory and experiment. II. A two-dimensional theoretical model of the emitter region

    SciTech Connect (OSTI)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.

    2005-12-01

    Despite their long history and wide range of applicability that includes electric propulsion, detailed understanding of the driving physics inside orificed hollow cathodes remains elusive. The theoretical complexity associated with the multicomponent fluid inside the cathode, and the difficulty of accessing empirically this region, have limited our ability to design cathodes that perform better and last longer. A two-dimensional axisymmetric theoretical model of the multispecies fluid inside an orificed hollow cathode is presented. The level of detail attained by the model is allowed by its extended system of governing equations not solved for in the past within the hollow cathode. Such detail is motivated in part by the need to quantify the effect(s) of the plasma on the emitter life, and by the need to build the foundation for future modeling that will assess erosion of the keeper plate. Results from numerical simulations of a 1.2-cm-diam cathode operating at a discharge current of 25 A and a gas flow rate of 5 SCCM show that approximately 10 A of electron current, and 3.45 A of ion current return back to the emitter surface. The total emitted electron current is 33.8 A and the peak emitter temperature is found to be 1440 K. Comparisons with the measurements suggest that anomalous heating of the plasma is possible near the orifice region. The model predicts heavy species temperatures as high as 2034 K and peak voltage drops near the emitting surface not exceeding 8 V.

  12. Regeneration of strong-base anion-exchange resins by sequential chemical displacement

    SciTech Connect (OSTI)

    Brown, Gilbert M.; Gu, Baohua; Moyer, Bruce A.; Bonnesen, Peter V.

    2002-01-01

    A method for regenerating strong-base anion exchange resins utilizing a sequential chemical displacement technique with new regenerant formulation. The new first regenerant solution is composed of a mixture of ferric chloride, a water-miscible organic solvent, hydrochloric acid, and water in which tetrachloroferrate anion is formed and used to displace the target anions on the resin. The second regenerant is composed of a dilute hydrochloric acid and is used to decompose tetrachloroferrate and elute ferric ions, thereby regenerating the resin. Alternative chemical displacement methods include: (1) displacement of target anions with fluoroborate followed by nitrate or salicylate and (2) displacement of target anions with salicylate followed by dilute hydrochloric acid. The methodology offers an improved regeneration efficiency, recovery, and waste minimization over the conventional displacement technique using sodium chloride (or a brine) or alkali metal hydroxide.

  13. Humectant use in the cathodic protection of reinforced concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, B.S. Jr.; Russell, J.H.; Bullard, S.J.; Cramer, S.D.; Collins, W.K.; Bennett, J.E.; H.M. Laylor

    2000-03-01

    The use of humectants to improve the thermal-sprayed zinc anode performance during the cathodic protection (CP) of reinforced concrete is examined. A humectant is a hygroscopic material. It is applied onto the surface of the zinc anode to keep the concrete-anode interface moist and a good conductor. The thermodynamics of humectants are discussed. Laboratory results are presented on the effects of using LiBr and LiNO{sub 3} as humectants in galvanic (GCP) and impressed current (ICCP) systems, in high and low relative humidities, and on new and previously electrochemically aged CP systems. LiNO{sub 3} and LiBr promoted more effective CP performance. Both improved the performance of aged slabs, suggesting that application of humectants onto existing CP systems would be of benefit. Microscopy showed that humectant-treated slabs develop the same cement-reaction zone-zinc anode structures as untreated slabs. Microscopy of LiBr-treated slabs revealed that the highest concentration of bromide was in the reaction zone. In GCP tests, LiBr was more effective than LiNO{sub 3}. In accelerated ICCP tests, LiNO{sub 3} was more effective than LiBr. It was surmised that bromide could be oxidized in the high-voltage accelerated ICCP tests. At the lower impressed currents of most installed ICCP systems, LiBr may perform as well as or better than LiNO{sub 3}.

  14. Neutral beam dump with cathodic arc titanium gettering

    SciTech Connect (OSTI)

    Smirnov, A.; Korepanov, S. A.; Putvinski, S.; Krivenko, A. S.; Murakhtin, S. V.; Savkin, V. Ya.

    2011-03-15

    An incomplete neutral beam capture can degrade the plasma performance in neutral beam driven plasma machines. The beam dumps mitigating the shine-through beam recycling must entrap and retain large particle loads while maintaining the beam-exposed surfaces clean of the residual impurities. The cathodic arc gettering, which provides high evaporation rate coupled with a fast time response, is a powerful and versatile technique for depositing clean getter films in vacuum. A compact neutral beam dump utilizing the titanium arc gettering was developed for a field-reversed configuration plasma sustained by 1 MW, 20-40 keV neutral hydrogen beams. The titanium evaporator features a new improved design. The beam dump is capable of handling large pulsed gas loads, has a high sorption capacity, and is robust and reliable. With the beam particle flux density of 5 x 10{sup 17} H/(cm{sup 2}s) sustained for 3-10 ms, the beam recycling coefficient, defined as twice the ratio of the hydrogen molecular flux leaving the beam dump to the incident flux of high-energy neutral atoms, is {approx}0.7. The use of the beam dump allows us to significantly reduce the recycling of the shine-through neutral beam as well as to improve the vacuum conditions in the machine.

  15. Excimer emission from pulsed microhollow cathode discharges in xenon

    SciTech Connect (OSTI)

    Lee, B.-J.; Nam, S. H. [Pohang Accelerator Laboratory, Pohang, Kyungbuk 790-784 (Korea, Republic of)] [Pohang Accelerator Laboratory, Pohang, Kyungbuk 790-784 (Korea, Republic of); Rahaman, H. [CSIR–CEERI Pilani, Rajasthan 333031 (India)] [CSIR–CEERI Pilani, Rajasthan 333031 (India); Iberler, M.; Jacoby, J. [Institute of Applied Physics, Goethe University, Max-von-Laue-Str. 1, 60438 Frankfurt am Main (Germany)] [Institute of Applied Physics, Goethe University, Max-von-Laue-Str. 1, 60438 Frankfurt am Main (Germany); Frank, K. [Physics Department 1, University of Erlangen – Nuremberg, 91058 Erlangen (Germany)] [Physics Department 1, University of Erlangen – Nuremberg, 91058 Erlangen (Germany)

    2013-12-15

    Direct current (dc) microhollow cathode discharge (MHCD) is an intense source for excimer radiation in vacuum ultraviolet at a wavelength of 172 nm in a high pressure xenon (Xe) gas. The concentration of precursors for the excimer formation, i.e., excited and ionized gas atoms, increases significantly by applying high voltage pulse onto the dc MHCD over the pulse duration range from 20 to 100 ns. The intensity of the excimer emission for the voltage pulse of 20 ns duration exceeds that of the emission intensity obtained from the same MHCD operated only in the dc mode, by one order of magnitude. In addition, the emission intensity increases by one order of magnitude over the pulse duration range from 20 to 100 ns. It can be assumed that the emission intensity of the MHCD source increases as long as the duration of the high voltage pulse is shorter than the electron relaxation time. For the high voltage pulse of 100 ns duration, the emission intensity has been found to be further enhanced by a factor of three when the gas pressure is increased from 200 to 800 mbar.

  16. Iron-based perovskite cathodes for solid oxide fuel cells

    DOE Patents [OSTI]

    Ralph, James M.; Rossignol, Cecile C.R.; Vaughey, John T.

    2007-01-02

    An A and/or A' site deficient perovskite of general formula of (A.sub.1-xA'.sub.x).sub.1-yFeO.sub.3-.delta. or of general formula A.sub.1-x-yA'.sub.xFeO.sub.3-67, wherein A is La alone or with one or more of the rare earth metals or a rare earth metal other than Ce alone or a combination of rare earth metals and X is in the range of from 0 to about 1; A' is Sr or Ca or mixtures thereof and Y is in the range of from about 0.01 to about 0.3; .delta. represents the amount of compensating oxygen loss. If either A or A' is zero the remaining A or A' is deficient. A fuel cell incorporating the inventive perovskite as a cathode is disclosed as well as an oxygen separation membrane. The inventive perovskite is preferably single phase.

  17. Ignition and extinction phenomena in helium micro hollow cathode discharges

    SciTech Connect (OSTI)

    Kulsreshath, M. K.; Schwaederle, L.; Dufour, T.; Lefaucheux, P.; Dussart, R.; Overzet, L. J.

    2013-12-28

    Micro hollow cathode discharges (MHCD) were produced using 250??m thick dielectric layer of alumina sandwiched between two nickel electrodes of 8??m thickness. A through cavity at the center of the chip was formed by laser drilling technique. MHCD with a diameter of few hundreds of micrometers allowed us to generate direct current discharges in helium at up to atmospheric pressure. A slowly varying ramped voltage generator was used to study the ignition and the extinction periods of the microdischarges. The analysis was performed by using electrical characterisation of the V-I behaviour and the measurement of He*({sup 3}S{sub 1}) metastable atoms density by tunable diode laser spectroscopy. At the ignition of the microdischarges, 2??s long current peak as high as 24?mA was observed, sometimes followed by low amplitude damped oscillations. At helium pressure above 400?Torr, an oscillatory behaviour of the discharge current was observed just before the extinction of the microdischarges. The same type of instability in the extinction period at high pressure also appeared on the density of He*({sup 3}S{sub 1}) metastable atoms, but delayed by a few ?s relative to the current oscillations. Metastable atoms thus cannot be at the origin of the generation of the observed instabilities.

  18. Room air stratification in combined chilled ceiling and displacement ventilation systems.

    E-Print Network [OSTI]

    Schiavon, Stefano; Bauman, Fred; Tully, Brad; Rimmer, Julian

    2012-01-01

    Environments. Proceedings of Indoor Air 2005: 10 thInternational Conference on Indoor Air Quality and Climate,displacement ventilation hybrid air conditioning system-

  19. Vehicle Technologies Office Merit Review 2015: Fuel Displacement Potential of Advanced Technologies under Different Thermal Conditions

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fuel displacement...

  20. Waste Management: Garbage Displacement and the Ethics of Mafia Representation in Matteo Garrone’s Gomorra

    E-Print Network [OSTI]

    Bondavalli, Simona

    2011-01-01

    We are all in the waste management business, but we don’tWaste Management: Garbage Displacement and the Ethics ofhearing the phrase “waste management and organized crime,”

  1. Cold Climates Heat Pump Design Optimization

    SciTech Connect (OSTI)

    Abdelaziz, Omar [ORNL] [ORNL; Shen, Bo [ORNL] [ORNL

    2012-01-01

    Heat pumps provide an efficient heating method; however they suffer from sever capacity and performance degradation at low ambient conditions. This has deterred market penetration in cold climates. There is a continuing effort to find an efficient air source cold climate heat pump that maintains acceptable capacity and performance at low ambient conditions. Systematic optimization techniques provide a reliable approach for the design of such systems. This paper presents a step-by-step approach for the design optimization of cold climate heat pumps. We first start by describing the optimization problem: objective function, constraints, and design space. Then we illustrate how to perform this design optimization using an open source publically available optimization toolbox. The response of the heat pump design was evaluated using a validated component based vapor compression model. This model was treated as a black box model within the optimization framework. Optimum designs for different system configurations are presented. These optimum results were further analyzed to understand the performance tradeoff and selection criteria. The paper ends with a discussion on the use of systematic optimization for the cold climate heat pump design.

  2. Strip edge cracking simulation in cold rolling

    SciTech Connect (OSTI)

    Hubert, C.; Dubar, L.; Dubar, M.; Dubois, A.

    2011-01-17

    This research work focuses on a specific defect which occurs during cold rolling of steel strips: edge-serration. Investigations on the industrial processes have led to the conclusion that this defect is the result of the edge-trimming and cold rolling sequences. The aim of this research work is to analyze the effect of the cutting process and the cold rolling on cracks occurrence, especially on strip edges.This study is performed using an experimental testing stand called Upsetting Rolling Test (URT). It allows to reproduce cold rolling contact parameters such as forward slip, reduction ratio and friction coefficients. Specimens sampled near trimmed industrial strip edges are deformed using the URT stand. Two sets of specimens with different stress states, obtained by annealing, are submitted to two reduction passes with extreme forward slips.Scanning electron microscopy observations added to 3D optical surface profiler topographies show that on one hand, forward slip has a major effect on cracks opening. On the other hand, cracks opening decreases according to high roll strip speed gradient. Concerning the heat-treated specimens, no crack appeared after all reduction passes, showing a large influence of the cutting process and consequently of the local stress state in the vicinity of the burnish and fracture regions.

  3. NUCLEAR WASTE VITRIFICATION EFFICIENCY COLD CAP REACTIONS

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; POKORNY R

    2011-07-29

    The cost and schedule of nuclear waste treatment and immobilization are greatly affected by the rate of glass production. Various factors influence the performance of a waste-glass melter. One of the most significant, and also one of the least understood, is the process of batch melting. Studies are being conducted to gain fundamental understanding of the batch reactions, particularly those that influence the rate of melting, and models are being developed to link batch makeup and melter operation to the melting rate. Batch melting takes place within the cold cap, i.e., a batch layer floating on the surface of molten glass. The conversion of batch to glass consists of various chemical reactions, phase transitions, and diffusion-controlled processes. These include water evaporation (slurry feed contains as high as 60% water), gas evolution, the melting of salts, the formation of borate melt, reactions of borate melt with molten salts and with amorphous oxides (Fe{sub 2}O{sub 3} and Al{sub 2}O{sub 3}), the formation of intermediate crystalline phases, the formation of a continuous glass-forming melt, the growth and collapse of primary foam, and the dissolution of residual solids. To this list we also need to add the formation of secondary foam that originates from molten glass but accumulates on the bottom of the cold cap. This study presents relevant data obtained for a high-level-waste melter feed and introduces a one-dimensional (1D) mathematical model of the cold cap as a step toward an advanced three-dimensional (3D) version for a complete model of the waste glass melter. The 1D model describes the batch-to-glass conversion within the cold cap as it progresses in a vertical direction. With constitutive equations and key parameters based on measured data, and simplified boundary conditions on the cold-cap interfaces with the glass melt and the plenum space of the melter, the model provides sensitivity analysis of the response of the cold cap to the batch makeup and melter conditions. The model demonstrates that batch foaming has a decisive influence on the rate of melting. Understanding the dynamics of the foam layer at the bottom of the cold cap and the heat transfer through it appears crucial for a reliable prediction of the rate of melting as a function of the melter-feed makeup and melter operation parameters. Although the study is focused on a batch for waste vitrification, the authors expect that the outcome will also be relevant for commercial glass melting.

  4. Nuclear waste vitrification efficiency: cold cap reactions

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.; Pokorny, Richard

    2012-12-15

    The cost and schedule of nuclear waste treatment and immobilization are greatly affected by the rate of glass production. Various factors influence the performance of a waste-glass melter. One of the most significant, and also one of the least understood, is the process of batch melting. Studies are being conducted to gain fundamental understanding of the batch reactions, particularly those that influence the rate of melting, and models are being developed to link batch makeup and melter operation to the melting rate. Batch melting takes place within the cold cap, i.e., a batch layer floating on the surface of molten glass. The conversion of batch to glass consists of various chemical reactions, phase transitions, and diffusion-controlled processes. These include water evaporation (slurry feed contains as high as 60% water), gas evolution, the melting of salts, the formation of borate melt, reactions of borate melt with molten salts and with amorphous oxides (Fe2O3 and Al2O3), the formation of intermediate crystalline phases, the formation of a continuous glass-forming melt, the growth and collapse of primary foam, and the dissolution of residual solids. To this list we also need to add the formation of secondary foam that originates from molten glass but accumulates on the bottom of the cold cap. This study presents relevant data obtained for a high-level-waste melter feed and introduces a one-dimensional (1D) mathematical model of the cold cap as a step toward an advanced three-dimensional (3D) version for a complete model of the waste glass melter. The 1D model describes the batch-to-glass conversion within the cold cap as it progresses in a vertical direction. With constitutive equations and key parameters based on measured data, and simplified boundary conditions on the cold-cap interfaces with the glass melt and the plenum space of the melter, the model provides sensitivity analysis of the response of the cold cap to the batch makeup and melter conditions. The model demonstrates that batch foaming has a decisive influence on the rate of melting. Understanding the dynamics of the foam layer at the bottom of the cold cap and the heat transfer through it appears crucial for a reliable prediction of the rate of melting as a function of the melter-feed makeup and melter operation parameters. Although the study is focused on a batch for waste vitrification, the authors expect that the outcome will also be relevant for commercial glass melting.

  5. Influence of projectile neutron number on cross section in cold fusion reactions

    E-Print Network [OSTI]

    Dragojevic, I.

    2008-01-01

    ON CROSS SECTION IN COLD FUSION REACTIONS I. Dragojevi? ,type of reaction has been referred to as “cold fusion. ”The study of cold fusion reactions is an indispensable

  6. T-661: ColdFusion Security Hotfix | APSB11-14, ColdFusion Important...

    Broader source: Energy.gov (indexed) [DOE]

    Console, CSRF protection is disabled. 3. If ColdFusion throws an exception "java.io.FileNotFoundException: ..logsesapiconfig.log" after applying the hot fix, go to...

  7. Charge-state and element-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

    E-Print Network [OSTI]

    Franz, Robert; Anders, André

    2014-01-01

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al$^{+}$ regardless of the background gas species, whereas Cr$^{2+}$ ions were dominating in Ar and N$_2$ and Cr$^{+}$ in O$_2$ atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were mainly thermalised. In addition to the positively charged metal and gas ions, negatively charged oxygen an...

  8. Operation of an ungated diamond field-emission array cathode in a L-band radiofrequency electron source

    SciTech Connect (OSTI)

    Piot, P. [Northern Illinois Center for Accelerator and Detector Development and Department of Physics, Northern Illinois University, DeKalb, Illinois 60115 (United States); Accelerator Physics Center, Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States); Brau, C. A.; Gabella, W. E.; Ivanov, B.; Mendenhall, M. H. [Department of Physics and Astronomy, Vanderbilt University, Nashville, Tennessee 37235 (United States); Choi, B. K. [Department of Electrical Engineering and Computer Science, Vanderbilt University, Nashville, Tennessee 37235 (United States); Vanderbilt Institute of Nanoscale Science and Engineering, Vanderbilt University, Nashville, Tennessee 37235 (United States); Blomberg, B.; Mihalcea, D.; Panuganti, H. [Northern Illinois Center for Accelerator and Detector Development and Department of Physics, Northern Illinois University, DeKalb, Illinois 60115 (United States); Jarvis, J. [Advanced Energy Systems, Inc., Medford, New York 11763 (United States); Prieto, P.; Reid, J. [Accelerator Division, Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States)

    2014-06-30

    We report on the operation of a field-emitter-array cathode in a conventional L-band radio-frequency electron source. The cathode consisted of an array of ?10{sup 6} diamond tips on pyramids. Maximum current on the order of 15?mA was reached and the cathode did not show appreciable signs of fatigue after weeks of operation. The measured Fowler-Nordheim characteristics, transverse beam density, and current stability are discussed.

  9. Lab begins demolition of Cold War-era buildings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demolition begins of cold War-Era buildings Lab begins demolition of Cold War-era buildings More than 165,000 square feet of former research, production, and office buildings will...

  10. Modeling Cold Start in a Polymer-Electrolyte Fuel Cell

    E-Print Network [OSTI]

    Balliet, Ryan

    2010-01-01

    of starting a cold PEFC . . . . . . . . . . . . . 1.2.3 Theand Design Parameters on PEFC Cold Start,” Journal of Powera) Expanded View of a single PEFC. (b) Cells arranged in a

  11. Hot-dark matter, cold dark matter and accelerating universe

    E-Print Network [OSTI]

    Abbas Farmany; Amin Farmany; Mohammad Mahmoodi

    2006-07-07

    The Friedman equation is solved for a universe contains hotdark matter and cold dark matter. In this scenario, hot-dark matter drives an accelerating universe no cold dark matter.

  12. Freeze-In Dark Matter with Displaced Signatures at Colliders

    E-Print Network [OSTI]

    Raymond T. Co; Francesco D'Eramo; Lawrence J. Hall; Duccio Pappadopulo

    2015-06-24

    Dark matter, $X$, may be generated by new physics at the TeV scale during an early matter-dominated (MD) era that ends at temperature $T_R \\ll {\\rm TeV}$. Compared to the conventional radiation-dominated (RD) results, yields from both Freeze-Out and Freeze-In processes are greatly suppressed by dilution from entropy production, making Freeze-Out less plausible while allowing successful Freeze-In with a much larger coupling strength. Freeze-In is typically dominated by the decay of a particle $B$ of the thermal bath, $B \\rightarrow X$. For a large fraction of the relevant cosmological parameter space, the decay rate required to produce the observed dark matter abundance leads to displaced signals at LHC and future colliders, for any $m_X$ in the range ${\\rm keV} < m_X < m_B$ and for values of $m_B$ accessible to these colliders. This result applies whether the early MD era arises after conventional inflation, when $T_R$ is the usual reheat temperature, or is a generic MD era with an alternative origin. In the former case, if $m_X$ is sufficiently large to be measured from kinematics, the reheat temperature $T_R$ can be extracted. Our result is independent of the particular particle physics implementation of $B \\rightarrow X$, and can occur via any operator of dimension less than 8 (4) for a post-inflation (general MD) cosmology. An interesting example is provided by DFS axion theories with TeV-scale supersymmetry and axino dark matter of mass GeV to TeV, which is typically overproduced in a conventional RD cosmology. If $B$ is the higgsino, $\\tilde h$, Higgs, W and Z particles appear at the displaced decays, $\\tilde h \\rightarrow h \\tilde a, Z \\tilde a$ and $\\tilde h^\\pm \\rightarrow W^\\pm \\tilde a$. The scale of axion physics, $f$, is predicted to be in the range $(3\\times10^8 - 10^{12})$ GeV and, over much of this range, can be extracted from the decay length.

  13. Experience at Fermilab with high quantum efficiency photo-cathodes for rf electron guns

    SciTech Connect (OSTI)

    A. Fry, E. Hahn, W. Hartung, M. Kuchnir, P. Michelato and D. Sertore

    1998-10-01

    As part of the A0 Photo-injector collaboration at Fermi-lab [1, 2] and the TeSLA collaboration [3], a high bright-ness, low emittance electron source has been developed. In the process, a system was constructed for coating molybde-num cathodes with a layer of cæsium telluride (Cs2 Te), a photo-emissive material of high quantum efficiency (QE). The use of Cs2 Te was first investigated at CERN [4] and LANL [5]. The development of the systems for the TeSLA Test Facility Linac and the Fermilab Photo-injector was done in Milano [6]. The system at Fermilab incorporates manipulator arms to transfer a cathode from the preparation chamber into a 1.3 GHz photo-electron RF gun while it re-mains in an ultra-high vacuum (UHV) environment, in or-der to avoid the deleterious effects of residual gases on the QE. A first prototype electron gun has been operated with a photo-cathode for several months [1]. This paper describes preliminary results obtained with the first 2 photo-cathodes and the first gun. Some of the desired parameters for the TeSLA Test Fa-cility beam are given in Table 1. The desired characteristics for the photo-cathodes include (i) high QE, (ii) high current density (>500 A/cm{sup 2} ), (iii) long lifetime, and (iv) low field emission. The choice of Cs2 Te is a compromise between long lifetime, rugged metal cathodes with low QE (typi-cally between 10{sup -6} and 10{sup -4} and semiconductor cathodes with high QE (>10%), which generally have a short life-time because of their sensitivity to contamination.

  14. High-current long-duration uniform electron beam generation in a diode with multicapillary carbon-epoxy cathode

    SciTech Connect (OSTI)

    Queller, T.; Gleizer, J. Z.; Krasik, Ya. E. [Physics Department, Technion, Haifa 32000 (Israel)] [Physics Department, Technion, Haifa 32000 (Israel)

    2013-09-28

    The results of reproducibly generating an electron beam with a current density of up to 5 kA/cm{sup 2}, without the cathode-anode gap being shorted by the plasma formed inside the cathode carbon-epoxy capillaries, in a ?350 kV, ?600 ns diode, with and without an external guiding magnetic field, are presented. The cathode sustained hundreds of pulses without degradation of its emission properties. Time- and space-resolved emissions of the plasma and spectroscopy analyses were used to determine the cathode plasma's density, temperature, and expansion velocity.

  15. Mo-containing tetrahedral amorphous carbon deposited by dual filtered cathodic vacuum arc with selective pulsed bias voltage

    E-Print Network [OSTI]

    Pasaja, Nitisak; Sansongsiri, Sakon; Anders, Andre; Vilaithong, Thiraphat; Intasiri, Sawate

    2006-01-01

    filtered cathodic vacuum arc plasma sources with selectiverepetitively pulsed vacuum arc plasma sources operating inthe pulse length from each arc plasma source. They concluded

  16. External Mass Injection to Reduce Energetic Ion Production in the Discharge Plume of High Current Hollow Cathodes

    E-Print Network [OSTI]

    Chu, Emily

    2012-01-01

    half the maximum ion energy (right) plotted against cathodehalf the maximum ion energy (right) plotted against cathodehalf the maximum ion energy (right) plotted against cathode

  17. www.carleton.ca/~kbstorey ADAPTATIONS TO COLD

    E-Print Network [OSTI]

    Storey, Kenneth B.

    12/19/2012 1 www.carleton.ca/~kbstorey ADAPTATIONS TO COLD Below 0°C Freeze Avoidance Freeze Supercool ADAPTATIONS TO COLD Below 0°C Freeze Avoidance Freeze Tolerance Hibernation Invertebrates Some Migrating DOWN #12;12/19/2012 3 Fresh Water Salt water ADAPTATIONS TO COLD Below 0°C Freeze Avoidance Freeze

  18. Radiation trapping in a cold atomic gas Guillaume Labeyrie,1

    E-Print Network [OSTI]

    field of study deals with the transport of near resonant light in such media. Using cold atoms, one can at the end of the 20th century that studies of light transport in optically thick clouds of cold atomsRadiation trapping in a cold atomic gas Guillaume Labeyrie,1 Robin Kaiser,1, and Dominique Delande

  19. Page 1 of 3 Policy: Cold Weather Policy

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Page 1 of 3 Policy: Cold Weather Policy Responsible Party: Director, Safety and Risk Management The Office of Safety and Risk Management (SRM) at Montana State University (MSU) has developed a cold weather and infrastructure resulting from periods of cold and snowy weather. 200.00 TRIGGER POINTS Trigger points have been

  20. DISPLACEMENT CASCADE SIMULATION IN TUNGSTEN AT 1025 K

    SciTech Connect (OSTI)

    Setyawan, Wahyu; Nandipati, Giridhar; Roche, Kenneth J.; Heinisch, Howard L.; Kurtz, Richard J.; Wirth, Brian D.

    2013-09-30

    Molecular dynamics simulation was employed to investigate the irradiation damage properties of bulk tungsten at 1025 K (0.25 melting temperature). A comprehensive data set of primary cascade damage was generated up to primary knock-on atom (PKA) energies 100 keV. The dependence of the number of surviving Frenkel pairs (NFP) on the PKA energy (E) exhibits three different characteristic domains presumably related to the different cascade morphologies that form. The low-energy regime < 0.2 keV is characterized by a hit-or-miss type of Frenkel pair (FP) production near the displacement threshold energy of 128 eV. The middle regime 0.3 – 30 keV exhibits a sublinear dependence of log(NFP) vs log(E) associated with compact cascade morphology with a slope of 0.73. Above 30 keV, the cascade morphology consists of complex branches or interconnected damage regions. In this extended morphology, large interstitial clusters form from superposition of interstitials from nearby damage regions. Strong clustering above 30 keV results in a superlinear dependence of log(NFP) vs log(E) with a slope of 1.365. At 100 keV, an interstitial cluster of size 92 and a vacancy cluster of size 114 were observed.

  1. Freeze-In Dark Matter with Displaced Signatures at Colliders

    E-Print Network [OSTI]

    Co, Raymond T; Hall, Lawrence J; Pappadopulo, Duccio

    2015-01-01

    Dark matter, $X$, may be generated by new physics at the TeV scale during an early matter-dominated (MD) era that ends at temperature $T_R \\ll {\\rm TeV}$. Compared to the conventional radiation-dominated (RD) results, yields from both Freeze-Out and Freeze-In processes are greatly suppressed by dilution from entropy production, making Freeze-Out less plausible while allowing successful Freeze-In with a much larger coupling strength. Freeze-In is typically dominated by the decay of a particle $B$ of the thermal bath, $B \\rightarrow X$. For a large fraction of the relevant cosmological parameter space, the decay rate required to produce the observed dark matter abundance leads to displaced signals at LHC and future colliders, for any $m_X$ in the range ${\\rm keV} < m_X < m_B$ and for values of $m_B$ accessible to these colliders. This result applies whether the early MD era arises after conventional inflation, when $T_R$ is the usual reheat temperature, or is a generic MD era with an alternative origin. I...

  2. Arp 65 interaction debris: massive HI displacement and star formation

    E-Print Network [OSTI]

    Sengupta, Chandreyee; Paudel, Sanjaya; Saikia, D J; Dwarakanath, K S; Sohn, B W

    2015-01-01

    Context: Pre-merger interactions between galaxies can induce significant changes in the morphologies and kinematics of the stellar and ISM components. Large amounts of gas and stars are often found to be disturbed or displaced as tidal debris. This debris then evolves, sometimes forming stars and occasionally tidal dwarf galaxies. Here we present results from our HI study of Arp 65, an interacting pair hosting extended HI tidal debris. Aims: In an effort to understand the evolution of tidal debris produced by interacting pairs of galaxies, including in situ star and tidal dwarf galaxy formation, we are mapping HI in a sample of interacting galaxy pairs. The Arp 65 pair is one of them. Methods: Our resolved HI 21 cm line survey is being carried out using the Giant Metrewave Radio Telescope (GMRT). We used our HI survey data as well as available SDSS optical, Spitzer infra-red and GALEX UV data to study the evolution of the tidal debris and the correlation of HI with the star-forming regions within it. Results:...

  3. Builders Challenge Guide to 40% Whole-House Energy Savings in the Cold and Very Cold Climate – Volume 12

    SciTech Connect (OSTI)

    Pacific Northwest National Laboratory

    2011-02-01

    This document describes measures builders can use to construct homes that have whole-house energy savings of 40% in the cold and very cold climate region of the United States.

  4. In Search of Shelter Mapping the Effects of Climate Change on Human Migration and Displacement

    E-Print Network [OSTI]

    a In Search of Shelter Mapping the Effects of Climate Change on Human Migration and Displacement #12;#12;In Search of Shelter Mapping the Effects of Climate Change on Human Migration and Displacement be addressed to the primary authors Koko Warner (warner@ehs.unu.edu), Charles Ehrhart (ehrhart

  5. In Search of Shelter Mapping the Effects of Climate Change on Human Migration and Displacement

    E-Print Network [OSTI]

    Columbia University

    a In Search of Shelter Mapping the Effects of Climate Change on Human Migration and Displacement of Shelter Mapping the Effects of Climate Change on Human Migration and Displacement Authors: Koko Warner are welcome and should be addressed to the primary authors Koko Warner (warner@ehs.unu.edu), Charles Ehrhart

  6. Morphology, displacement, and slip rates along the North Anatolian Fault, Turkey

    E-Print Network [OSTI]

    Hubert-Ferrari, Aurélia

    Morphology, displacement, and slip rates along the North Anatolian Fault, Turkey Aure´lia Hubert, Ayazaga, Istanbul, Turkey Received 29 January 2001; revised 8 January 2002; accepted 13 January 2002 the central and eastern North Anatolian Fault (NAF) in Turkey. The NAF total displacement is reevaluated using

  7. Collateral damage: Evolution with displacement of fracture distribution and secondary fault strands in fault

    E-Print Network [OSTI]

    Savage, Heather M.

    Collateral damage: Evolution with displacement of fracture distribution and secondary fault strands in fault damage zones Heather M. Savage1,2 and Emily E. Brodsky1 Received 22 April 2010; revised 10 of fracture distributions as a function of displacement to determine whether damage around small and large

  8. Balanced electronic detection of displacement in nanoelectromechanical K. L. Ekinci,a)

    E-Print Network [OSTI]

    Roukes, Michael L.

    - ings. First, detection of the EMF becomes extremely chal- lenging, when Re Rm, i.e., in unmetallizedBalanced electronic detection of displacement in nanoelectromechanical systems K. L. Ekinci,a) Y. T describe a broadband radio frequency balanced bridge technique for electronic detection of displacement

  9. A mulitple cathode gun design for the eRHIC polarized electron source

    SciTech Connect (OSTI)

    Chang, X.; Ben-Zvi, I.; Kewisch, J.; Litvinenko, V.; Pikin, A.; Ptitsyn, V.; Rao, T.; Sheehy, B.; Skaritka, J.; Wang, E.; Wu, Q.; Xin, T.

    2011-03-28

    The future electron-ion collider eRHIC requires a high average current ({approx}50 mA), short bunch ({approx}3 mm), low emittance ({approx}20 {micro}m) polarized electron source. The maximum average current of a polarized electron source so far is more than 1 mA, but much less than 50 mA, from a GaAs:Cs cathode. One possible approach to overcome the average current limit and to achieve the required 50 mA beam for eRHIC, is to combine beamlets from multiple cathodes to one beam. In this paper, we present the feasibility studies of this technique. The future eRHIC project, next upgrade of RHIC, will be the first electron-heavy ion collider in the world. It requires polarized electron source with a high average current ({approx}50 mA), short bunch ({approx}3 mm), emittance of about 20 {micro}m and energy spread of {approx}1% at 10 MeV. The state-of-art polarized electron cathode can generate average current of about more than 1 mA, but much less than 50 mA. The current is limited by the low quantum efficiency, space charge and ultra-high vacuum requirement of the polarized cathode. A possible approach to achieve the 50 mA beam is to employ multiple cathodes, such as 20 cathodes, and funnel the multiple bunched beams from cathodes to the same axis. Fig.1 illustrates schematically the concept of combining the multiple beams. We name it as 'Gatling gun' because it bears functional similarity to a Gatling gun. Laser beams strike the cathodes sequentially with revolution frequency of 700 kHz. Each beam bunch is focused by a solenoid and is bent toward the combiner. The combiner with rotating bending field bends all bunches arriving the combiner with a rotational pattern to the same axis. The energy of each bunch is modified by a bunching cavity (112MHz) and a 3rd harmonic cavity (336MHz). The bunch length is compressed ballistically in the drift space and is frozen after energy has been boosted to 10 MeV by the Booster linac. Each beam bunch contains 3.5 nC charge. The space charge is very strong at energy of 200 keV. A long bunch, {sigma} of 250 ps, is adopted to reduce the space charge on cathode. To compress the beam to final length of 3 mm (10 ps) can be achieved by ballistic compression with a 3rd harmonic cavity.

  10. The Central American cold surge: an observational analysis of the deep southward penetration of North American cold fronts 

    E-Print Network [OSTI]

    Reding, Philip John

    1992-01-01

    THE CENTRAL AMERICAN COLD SURGE: AN OBSERVATIONAL ANALYSIS OF THE DEEP SOUTHWARD PENETRATION OF NORTH AMERICAN COLD FRONTS A Thesis by PHILIP JOHN REDING Submitted to the Office of Graduate Studies of Texas A &M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Meteorology THE CENTRAL AMERICAN COLD SURGE: AN OBSERVATIONAL ANALYSIS OF THE DEEP SOUTHWARD PENETRATION OF NORTH AMERICAN COLD FRONTS A Thesis by PHILIP...

  11. Two types of diffusions at the cathode/electrolyte interface in IT-SOFCs

    SciTech Connect (OSTI)

    Li Zhipeng, E-mail: LI.Zhipeng@nims.go.jp [Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Mori, Toshiyuki [Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Auchterlonie, Graeme John [Centre for Microscopy and Microanalysis, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia); Zou Jin [Centre for Microscopy and Microanalysis, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia); Division of Materials, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia); Drennan, John [Centre for Microscopy and Microanalysis, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia)

    2011-09-15

    Analytical transmission electron microscopy, in particular with the combination of energy dispersive X-ray spectroscopy (EDX) and electron energy-loss spectroscopy (EELS), has been performed to investigate the microstructure and microchemistry of the interfacial region between the cathode (La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3}, LSCF) and the electrolyte (Gd-doped ceria, GDC). Two types of diffusions, mutual diffusion between cathode and electrolyte as well as the diffusion along grain boundaries, have been clarified. These diffusions suggest that the chemical stability of LSCF and GDC are not as good as previously reported. The results are more noteworthy if we take into consideration the fact that such interdiffusions occur even during the sintering process of cell preparation. - Graphical Abstract: Two types of diffusions, the mutual diffusion and the diffusion along grain boundaries, occurred at the cathode/electrolyte interface of intermediate temperature solid state fuel cells, during cell preparation. The mutual diffusion is denoted by black arrows and the diffusion along grain boundaries assigned by pink arrows. Highlights: > All the cations in cathode (LSCF) and electrolyte (GDC) can mutually diffuse into each other. > Diffusing elements will segregate at grain boundaries or triple junctions around the cathode/electrolyte interface. > Two types of diffusions, the mutual diffusion and diffusion along grain boundaries, have been clarified thereafter.

  12. Representation in terms of displaced number states and realization of elementary linear operators based on it

    E-Print Network [OSTI]

    Sergey A. Podoshvedov

    2015-07-23

    We develop a new method of representation of quantum states in terms of the displaced number states. We call it representation, where is an amplitude of the base displaced states. In particular, representation was obtained for set of the displaced number states with different amplitude of the displacement, two-mode squeezed vacuum (TMSV) and superposition of vacuum and single photon. The treatment is employed for building of elementary linear operators, in particular, two-qubit control-sign gate, Hadamard matrix between two two-dimensional Hilbert spaces. Main idea underlying the method is extraction of the displaced number state from initial state. Coherent qubit with large amplitude taken simultaneously two modes shifts two-mode target qubit on phase plane and constructive interference appears after measurement of single photon. The results are exact, any approximations are not exploited. We show implementation of the gates with almost unity fidelity of the output states is possible in realistic scenario.

  13. Ultrasensitive measurement of MEMS cantilever displacement sensitivity below the shot noise limit

    E-Print Network [OSTI]

    Pooser, R C

    2014-01-01

    The displacement of micro-electro-mechanical-systems(MEMs) cantilevers is used to measure a variety of phenomena in devices ranging from force microscopes for single spin detection[1] to biochemical sensors[2] to uncooled thermal imaging systems[3]. The displacement readout is often performed optically with segmented detectors or interference measurements. Until recently, various noise sources have limited the minimum detectable displacement in MEMs systems, but it is now possible to minimize all other sources[4] so that the noise level of the coherent light field, called the shot noise limit(SNL), becomes the dominant source. Light sources dis- playing quantum-enhanced statistics below this limit are available[5, 6], with applications in gravitational wave astronomy[7] and bioimaging[8], but direct displacement measurements of MEMS cantilevers below the SNL have been impossible until now. Here, we demonstrate the first direct measurement of a MEMs cantilever displacement with sub-SNL sensitivity, thus enabli...

  14. Cryogenic target formation using cold gas jets

    DOE Patents [OSTI]

    Hendricks, Charles D. [Livermore, CA

    1980-02-26

    A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member.

  15. Cryogenic target formation using cold gas jets

    DOE Patents [OSTI]

    Hendricks, C.D.

    1980-02-26

    A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets are disclosed. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member. 4 figs.

  16. Cold condensation of dust in the ISM

    E-Print Network [OSTI]

    Rouillé, Gaël; Krasnokutski, Serge A; Krebsz, Melinda; Henning, Thomas

    2015-01-01

    The condensation of complex silicates with pyroxene and olivine composition at conditions prevailing in molecular clouds has been experimentally studied. For this purpose, molecular species comprising refractory elements were forced to accrete on cold substrates representing the cold surfaces of surviving dust grains in the interstellar medium. The efficient formation of amorphous and homogeneous magnesium iron silicates at temperatures of about 12 K has been monitored by IR spectroscopy. The gaseous precursors of such condensation processes in the interstellar medium are formed by erosion of dust grains in supernova shock waves. In the laboratory, we have evaporated glassy silicate dust analogs and embedded the released species in neon ice matrices that have been studied spectroscopically to identify the molecular precursors of the condensing solid silicates. A sound coincidence between the 10 micron band of the interstellar silicates and the 10 micron band of the low-temperature siliceous condensates can be...

  17. Cryogenic target formation using cold gas jets

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA)

    1981-01-01

    A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member.

  18. Palladium metallurgy and cold fusion; Some remarks

    SciTech Connect (OSTI)

    Murr, L.E. )

    1990-04-01

    In this paper the recent confusion surrounding claims for the observation of cold fusion involving palladium electrodes in electrochemical cells containing deuterium might be clarified to some extent if the palladium metallurgy, particularly in the context of fundamental microstructures, are accurately defined. Both the palladium/hydrogen and palladium/deuterium systems have been extensively investigated, and it is asserted more than two decades ago that the palladium/hydrogen system was perhaps the most extensively, experimentally investigated metal/gas system. Ordinary hydrogen absorbed in palladium fused to form helium, while in the 1940's Wilner actually observed the fusion reaction at the center of the current cold fusion controversy: d + d {yields} {sup 3}He + n (where d = {sup 2}H represents a deuteron, and n is a neutron). In the experiment by Wilner, a deuterium-saturated palladium sheet was bombarded with accelerated deuterons. The product neutrons (n) were slowed by paraffin wax and detected by the activation of silver.

  19. Combined cold compressor/ejector helium refrigerator

    DOE Patents [OSTI]

    Brown, D.P.

    1984-06-05

    A refrigeration apparatus having an ejector operatively connected with a cold compressor to form a two-stage pumping system. This pumping system is used to lower the pressure, and thereby the temperature of a bath of boiling refrigerant (helium). The apparatus as thus arranged and operated has substantially improved operating efficiency when compared to other processes or arrangements for achieving a similar low pressure.

  20. Cold worked ferritic alloys and components

    DOE Patents [OSTI]

    Korenko, Michael K. (Wexford, PA)

    1984-01-01

    This invention relates to liquid metal fast breeder reactor and steam generator precipitation hardening fully ferritic alloy components which have a microstructure substantially free of the primary precipitation hardening phase while having cells or arrays of dislocations of varying population densities. It also relates to the process by which these components are produced, which entails solution treating the alloy followed by a final cold working step. In this condition, the first significant precipitation hardening of the component occurs during high temperature use.

  1. Effect of Ti-Al cathode composition on plasma generation and plasma transport in direct current vacuum arc

    SciTech Connect (OSTI)

    Zhirkov, I. Petruhins, A.; Dahlqvist, M.; Ingason, A. S.; Rosen, J.; Eriksson, A. O.

    2014-03-28

    DC arc plasma from Ti, Al, and Ti{sub 1-x}Al{sub x} (x?=?0.16, 0.25, 0.50, and 0.70) compound cathodes was characterized with respect to plasma chemistry and charge-state-resolved ion energy. Scanning electron microscopy, X-ray diffraction, and Energy-dispersive X-ray spectroscopy of the deposited films and the cathode surfaces were used for exploring the correlation between cathode-, plasma-, and film composition. Experimental work was performed at a base pressure of 10{sup ?6}?Torr, to exclude plasma-gas interaction. The plasma ion composition showed a reduction of Al of approximately 5 at. % compared to the cathode composition, while deposited films were in accordance with the cathode stoichiometry. This may be explained by presence of neutrals in the plasma/vapour phase. The average ion charge states (Ti?=?2.2, Al?=?1.65) were consistent with reference data for elemental cathodes, and approximately independent on the cathode composition. On the contrary, the width of the ion energy distributions (IEDs) were drastically reduced when comparing the elemental Ti and Al cathodes with Ti{sub 0.5}Al{sub 0.5}, going from??150 and ?175?eV to ?100 and ?75?eV for Ti and Al ions, respectively. This may be explained by a reduction in electron temperature, commonly associated with the high energy tail of the IED. The average Ti and Al ion energies ranged between ?50 and ?61?eV, and ?30 and ?50?eV, respectively, for different cathode compositions. The attained energy trends were explained by the velocity rule for compound cathodes, which states that the most likely velocities of ions of different mass are equal. Hence, compared to elemental cathodes, the faster Al ions will be decelerated, and the slower Ti ions will be accelerated when originating from compound cathodes. The intensity of the macroparticle generation and thickness of the deposited films were also found to be dependent on the cathode composition. The presented results may be of importance for choice of cathodes for thin film depositions involving compound cathodes.

  2. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wonchang

    2010-05-18

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  3. Structural and Chemical Evolution of Li- and Mn-rich Layered Cathode Material

    SciTech Connect (OSTI)

    Zheng, Jianming; Xu, Pinghong; Gu, Meng; Xiao, Jie; Browning, Nigel D.; Yan, Pengfei; Wang, Chong M.; Zhang, Jiguang

    2015-02-24

    Lithium (Li)- and manganese-rich (LMR) layered-structure materials are very promising cathodes for high energy density lithium-ion batteries. However, their voltage fading mechanism and its relationships with fundamental structural changes are far from being sufficiently understood. Here we report the detailed phase transformation pathway in the LMR cathode (Li[Li0.2Ni0.2Mn0.6]O2) during cycling for the samples prepared by hydro-thermal assistant method. It is found the transformation pathway of LMR cathode is closely correlated to its initial structure and preparation conditions. The results reveal that LMR cathode prepared by HA approach experiences a phase transformation from the layered structure to a LT-LiCoO2 type defect spinel-like structure (Fd-3m space group) and then to a disordered rock-salt structure (Fm-3m space group). The voltage fade can be well correlated with the Li ion insertion into octahedral sites, rather than tetrahedral sites, in both defect spinel-like structure and disordered rock-salt structure. The reversible Li insertion/removal into/from the disordered rock-salt structure is ascribed to the Li excess environment that can satisfy the Li percolating in the disordered rock-salt structure despite the increased kinetic barrier. Meanwhile, because of the presence of a great amount of oxygen vacancies, a significant decrease of Mn valence is detected in the cycled particle, which is below that anticipated for a potentially damaging Jahn-Teller distortion (+3.5). Clarification of the phase transformation pathway, cation redistribution, oxygen vacancy and Mn valence change undoubtedly provides insights into a profound understanding on the voltage fade, and capacity degradation of LMR cathode. The results also inspire us to further enhance the reversibility of LMR cathode via improving its surface structural stability.

  4. Charge-State-Resolved Ion Energy Distribution Functions of Cathodic Vacuum Arcs: A Study Involving the Plasma Potential and Biased Plasmas

    E-Print Network [OSTI]

    Anders, Andre; Oks, Efim

    2006-01-01

    velocity in vacuum arc plasmas by arc current perturbationwith a pulsed cathodic arc plasma source of the “minigun”produced by a cathodic arc plasma source of the “minigun”

  5. Theoretical Study of the Structural Evolution of a Na2FeMn(CN)6 Cathode upon Na Intercalation

    E-Print Network [OSTI]

    Henkelman, Graeme

    Blue analog, NaxFeMn(CN)6, is a potential new cathode material for Na-ion batteries. During Na-sharing tetrahedra. INTRODUCTION Cathode materials for Li and Na batteries have attracted a great deal of interest for renewable energy applications.1-3 They are also of interest scientifically, owing to the rich chemistry

  6. A Hybrid Laser-driven E-beam Injector Using Photo-cathode Electron Gun and superconducting Cavity*

    E-Print Network [OSTI]

    Geng, Rong-Li

    A Hybrid Laser-driven E-beam Injector Using Photo-cathode Electron Gun and superconducting Cavity, Beijing 100871, China * Work supported by NNSF of China Abstract A laser-driven photo-cathode electron gun constructed and tested. As the next step, a hybrid photo-injector, using a DC laser-driven electron gun

  7. Advanced plasma flow simulations of cathodic-arc and ferroelectric plasma sources for neutralized drift compression experiments

    E-Print Network [OSTI]

    Gilson, Erik

    Advanced plasma flow simulations of cathodic-arc and ferroelectric plasma sources for neutralized cathodic-arc plasma source show the coupling efficiency of the plasma flow from the source to the drift drift compression experiments Adam B. Sefkow, Ronald C. Davidson, and Erik P. Gilson Plasma Physics

  8. Effect of surface composition of Pt-Au alloy cathode catalyst on the performance of direct methanol fuel cells

    E-Print Network [OSTI]

    Zhao, Tianshou

    Effect of surface composition of Pt-Au alloy cathode catalyst on the performance of direct methanol 2010 Available online 12 June 2010 Keywords: Fuel cell Direct methanol fuel cell Catalyst Active Site Pt-Au alloy a b s t r a c t A pure Pt cathode catalyst in direct methanol fuel cells is not only

  9. Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio computations

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Novel mixed polyanions lithium-ion battery cathode materials predicted by high-throughput ab initio (>700 Wh/kg) cathode materials for lithium-ion batteries. 1 Introduction The widespread use of lithium compounds. Testing previously known lithium-containing compounds for battery properties can lead

  10. Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz

    E-Print Network [OSTI]

    Gall, Daniel

    Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz as cathode electrodes in proton exchange membrane PEM fuel cells. Deposition on flat substrates yields February 4, 2010. Proton exchange membrane PEM fuel cells are promising for future automotive applications

  11. Condensation in the Cathode of a PEM Fuel Cell M. J. Kermani J. M. Stockie A. G. Gerber

    E-Print Network [OSTI]

    Stockie, John

    Condensation in the Cathode of a PEM Fuel Cell M. J. Kermani J. M. Stockie A. G. Gerber University@unb.ca. ABSTRACT Three species condensing flow in the cathode of a Proton Exchange Membrane (PEM) fuel cell, to compute the amount of moisture gen- erated a multi-phase model is needed. 1 INTRODUCTION A fuel cell

  12. Short communication Effect of electrolyte pH on the rate of the anodic and cathodic reactions in an

    E-Print Network [OSTI]

    at the open-circuit potential (OCP) revealed that the anodic microbial process preferred a neutral p seen as waste, but instead as a valuable energy resource. Today, primarily methane is gained from between the anode and the cathode. Air-cathode MFCs have shown promising power production while

  13. P-129 / J. X. Sun P-129: Highly Efficient Stacked OLED Employing New Anode-Cathode Layer

    E-Print Network [OSTI]

    light emitting diode (OLED) [1], much development has been made to improve this device for applicationsP-129 / J. X. Sun P-129: Highly Efficient Stacked OLED Employing New Anode-Cathode Layer J. X. Sun Highly efficient stacked OLEDs have been fabricated using a new anode-cathode-layer (ACL) that connects

  14. Quantum efficiency temporal response and lifetime of a GaAs cathode in SRF electron gun

    SciTech Connect (OSTI)

    Wang, E.; Ben-Zvi, I.; Kewisch, J.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

    2010-05-23

    RF electron guns with a strained super lattice GaAs cathode can generate polarized electron beam of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface. In a normal conducting RF gun, the extremely high vaccum required by these cathodes can not be met. We report on an experiment with a superconducting SRF gun, which can maintain a vacuum of nearly 10-12 torr because of cryo-pumping at the temperature of 4.2K. With conventional activation, we obtained a QE of 3% at 532 nm, with lifetime of nearly 3 days in the preparation chamber. We plan to use this cathode in a 1.3 GHz 1/2 cell SRF gun to study its performance. In addition, we studied the multipacting at the location of cathode. A new model based on the Forkker-Planck equation which can estimate the bunch length of the electron beam is discussed in this paper. Future particle accelerators such as eRHIC and ILC require high brightness, high current polarized electrons Recently, using a superlattice crystal, the maximum polarization of 95% was reached. Activation with Cs,O lowers the electron affinity and makes it energetically possible for all the electrons excited in to the conduction band and reach the surface to escape into the vacuum. Presently the polarized electron sources are based on DC gun, such as that at the CEBAF at Jlab. In these devices, the life time of the cathode is extended due to the reduced back bombardment in their UHV conditions. However, the low accelerating gradient of the DC guns lead to poor longitudinal emittance. The higher accelerating gradient of the RF gun generates low emittance beams. Superconducting RF guns combine the excellent vacuum conditions of the DC guns with the higher accelerating gradients of the RF guns and provide potentially a long lived cathode with very low transverse and longitudinal emittance. In our work at BNL, we successfully activated the GaAs. The quantum efficient is 3% at 532 nm and is expected to improve further. In addition, we studied the multipacting at the location of cathode. A new model based on the Forkker-Planck equation which can estimate the bunch length of the electron beam is discussed in this paper.

  15. Electron depletion via cathode spot dispersion of dielectric powder into an overhead plasma

    SciTech Connect (OSTI)

    Gillman, Eric D. [Naval Research Laboratory, 4555 Overlook Ave SW, Washington, District of Columbia 20375 (United States)] [Naval Research Laboratory, 4555 Overlook Ave SW, Washington, District of Columbia 20375 (United States); Foster, John E. [Department of Nuclear Engineering and Radiological Sciences (NERS), University of Michigan, 2355 Bonisteel Blvd., Ann Arbor, Michigan 48109 (United States)] [Department of Nuclear Engineering and Radiological Sciences (NERS), University of Michigan, 2355 Bonisteel Blvd., Ann Arbor, Michigan 48109 (United States)

    2013-11-15

    The effectiveness of cathode spot delivered dielectric particles for the purpose of plasma depletion is investigated. Here, cathode spot flows kinetically entrain and accelerate dielectric particles originally at rest into a background plasma. The time variation of the background plasma density is tracked using a cylindrical Langmuir probe biased approximately at electron saturation. As inferred from changes in the electron saturation current, depletion fractions of up to 95% are observed. This method could be exploited as a means of communications blackout mitigation for manned and unmanned reentering spacecraft as well as any high speed vehicle enveloped by a dense plasma layer.

  16. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOE Patents [OSTI]

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  17. Study of the fragmentation of a displacement cascade in subcascades within the Binary Collision Approximation framework

    SciTech Connect (OSTI)

    Luneville, Laurence [CEA, Saclay, France; Simone, David [CEA, Saclay, France; Weber, William J [ORNL

    2011-01-01

    When a material is subjected to irradiation, many primary defects are cre- ated at the atomic level by sequences of ballistic collision events to form highly disordered regions defined as displacement cascades. The long term evolution of materials under irradiation is dictated by the number and the spatial distribution of the surviving defects in the displacement cascade. The peculiar power law shape of collision cross sections is responsible for the frag- mentation of a displacement cascade into smaller subcascades. However, it remains difficult to define a subcascade. Within the fractal geometry frame- work, we demonstrate in this work that the set of atomic trajectories in a displacement cascade exhibit a fractal behavior. From this analysis, we present a new criterion to describe the fragmentation of a displacement cas- cade and to calculate the distribution and the number of defects from this fragmentation. Such an analysis provides the natural framework to estimate the number of defects created in a displacement cascade to integrate with results of MD simulations. From this defiintion of the fragmentation of a displacement cascade, this work gives some new insights to describe both the primary defects produced in a material under irradiation and then to compare different irradiations performed with different particles.

  18. Effect of Body Mass Index on Intrafraction Prostate Displacement Monitored by Real-Time Electromagnetic Tracking

    SciTech Connect (OSTI)

    Butler, Wayne M., E-mail: wbutler@wheelinghospital.org [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States); Wheeling Jesuit University, Wheeling, West Virginia (United States); Morris, Mallory N. [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States)] [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States); Merrick, Gregory S. [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States) [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States); Wheeling Jesuit University, Wheeling, West Virginia (United States); Kurko, Brian S.; Murray, Brian C. [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States)] [Schiffler Cancer Center, Wheeling Hospital, Wheeling, West Virginia (United States)

    2012-10-01

    Purpose: To evaluate, using real-time monitoring of implanted radiofrequency transponders, the intrafraction prostate displacement of patients as a function of body mass index (BMI). Methods and Materials: The motions of Beacon radiofrequency transponders (Calypso Medical Technologies, Seattle, WA) implanted in the prostate glands of 66 men were monitored throughout the course of intensity modulated radiation therapy. Data were acquired at 10 Hz from setup to the end of treatment, but only the 1.7 million data points with a 'beam on' tag were used in the analysis. There were 21 obese patients, with BMI {>=}30 and 45 nonobese patients in the study. Results: Mean displacements were least in the left-right lateral direction (0.56 {+-} 0.24 mm) and approximately twice that magnitude in the superior-inferior and anterior-posterior directions. The net vector displacement was larger still, 1.95 {+-} 0.47 mm. Stratified by BMI cohort, the mean displacements per patient in the 3 Cartesian axes as well as the net vector for patients with BMI {>=}30 were slightly less (<0.2 mm) but not significantly different than the corresponding values for patients with lower BMIs. As a surrogate for the magnitude of oscillatory noise, the standard deviation for displacements in all measured planes showed no significant differences in the prostate positional variability between the lower and higher BMI groups. Histograms of prostate displacements showed a lower frequency of large displacements in obese patients, and there were no significant differences in short-term and long-term velocity distributions. Conclusions: After patients were positioned accurately using implanted radiofrequency transponders, the intrafractional displacements in the lateral, superior-inferior, and anterior-posterior directions as well as the net vector displacements were smaller, but not significantly so, for obese men than for those with lower BMI.

  19. Molecular Dynamics Simulations of Displacement Cascades in Single and Polycrystalline Zirconia

    SciTech Connect (OSTI)

    Du Jincheng

    2009-03-10

    Displacement cascades in zirconia have been studied using classical molecular dynamics simulations. Polycrystalline zirconia with nano-meter grains were created using Voronoi polyhedra construction and studied in comparison with single crystalline zirconia. The results show that displacement cascades with similar kinetic energy generated larger number of displaced atoms in polycrystalline than in the single crystal structure. The fraction of atoms with coordination number change was also higher in polycrystalline zirconia that was explained to be due to the diffusion of oxygen and relaxation at grain boundaries.

  20. Axions as hot and cold dark matter

    SciTech Connect (OSTI)

    Jeong, Kwang Sik; Kawasaki, Masahiro; Takahashi, Fuminobu E-mail: kawasaki@icrr.u-tokyo.ac.jp

    2014-02-01

    The presence of a hot dark matter component has been hinted at 3? by a combination of the results from different cosmological observations. We examine a possibility that pseudo Nambu-Goldstone bosons account for both hot and cold dark matter components. We show that the QCD axions can do the job for the axion decay constant f{sub a}?

  1. Cold neutron scattering in imperfect deuterium crystals

    E-Print Network [OSTI]

    Andrzej Adamczak

    2010-12-10

    The differential cross sections for cold neutron scattering in mosaic deuterium crystals have been calculated for various target temperatures. The theoretical results are compared with the recent experimental data for the neutron wavelengths $\\lambda\\approx$~1--9~\\AA. It is shown that the structures of observed Bragg peaks can be explained by the mosaic spread of about $3^{\\circ}$ and contributions from a~limited number of crystal orientations. Such a~crystal structure should be also taken into account in ultracold neutron upscattering due to the coherent phonon annihilation in solid deuterium.

  2. Direct Detection of Cold Dark Matter

    E-Print Network [OSTI]

    Laura Baudis

    2007-11-25

    We know from cosmological and astrophysical observations that more than 80% of the matter density in the Universe is non-luminous, or dark. This non-baryonic dark matter could be composed of neutral, heavy particles, which were non-relativistic, or 'cold', when they decoupled from ordinary matter. I will review the direct detection methods of these hypothetical particles via their interactions with nuclei in ultra-low background, deep underground experiments. The emphasis is on most recent results and on the status of near future projects.

  3. Cold Vacuum Drying Facility - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAuditsCluster Compatibility Mode Cluster CompatibilityCoalCodeCold Vacuum

  4. High Efficiency Cold Climate Heat Pump

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡ ¢HelpHigh Efficiency Cold Climate

  5. SOFTWARE ENABLED VARIABLE DISPLACEMENT PUMPS -EXPERIMENTAL Michael B. Rannow, Haink C. Tu, Perry Y. Liand Thomas R. Chase

    E-Print Network [OSTI]

    Li, Perry Y.

    SOFTWARE ENABLED VARIABLE DISPLACEMENT PUMPS - EXPERIMENTAL STUDIES Michael B. Rannow, Haink C. Tu of hydraulic systems are controlled using a me- tering valve or the use of variable displacement pumps to throttling losses. Variable displace- ment pumps are far more efficient as the pump only produces

  6. Displacement, politics and governance : access to low-income housing in a Beirut suburb

    E-Print Network [OSTI]

    Bou Akar, Hiba

    2005-01-01

    Lebanon witnessed large-scale phases of internal displacement during and after its civil war (1975-1990). This study analyzes access to low-income housing for a Lebanese Shiites group which has already experienced two ...

  7. Improving Petroleum Displacement Potential of PHEVs Using Enhanced Charging Scenarios: Preprint

    SciTech Connect (OSTI)

    Markel, T.; Smith, K.; Pesaran, A. A.

    2009-05-01

    Describes NREL's R&D on the petroleum displacement potential of plug-in hybrid vehicles; vehicles charged during the day would save about 5% more fuel than those charged at night.

  8. Stabilizing Fluid-Fluid Displacements in Porous Media Through Wettability Alteration

    E-Print Network [OSTI]

    Trojer, Mathias

    We study experimentally how wettability impacts fluid-fluid-displacement patterns in granular media. We inject a low-viscosity fluid (air) into a thin bed of glass beads initially saturated with a more-viscous fluid (a ...

  9. Effects of density on displacement, falls, injuries, and orientation during horse transportation 

    E-Print Network [OSTI]

    Collins, Maranda Nicole

    2000-01-01

    Three groups of horses (totaling 30 mares and 29 geldings) purchased from local auctions, were used to determine density effects on displacement (distance moved during a stop), falls, injuries, and orientation using a ...

  10. The structure and evolution of small-displacement strike-slip faults in porous sandstone 

    E-Print Network [OSTI]

    Schafer, Kirk Wyatt

    2002-01-01

    The early-evolution of fault structure is inferred from analysis of detailed maps of portions of strike-slip faults with uniform displacements ranging from mm to decimeter in porous quartzose sandstone. Emphasis is on ...

  11. Fact #663: February 21, 2011 Clean Cities Program Petroleum Displacement Estimates for 2009

    Broader source: Energy.gov [DOE]

    Each year, estimates are made of the amount of petroleum that is displaced by the efforts of the U.S. Department of Energy's Clean Cities Program. These estimates are based on data provided by...

  12. Experimental examination of wire mesh dampers subjected to large amplitude displacements 

    E-Print Network [OSTI]

    Jones, Adam Matthew

    2009-06-02

    of interest. Next, to verify the results, a second methodology was employed using shaker testing. It was found that both the stiffness and hysteretic damping decrease with increasing displacement. However, they both approached asymptotes around 2 mils...

  13. Ultrasensitive measurement of MEMS cantilever displacement sensitivity below the shot noise limit

    E-Print Network [OSTI]

    R. C. Pooser; B. J. Lawrie

    2015-06-29

    The displacement of micro-electro-mechanical-systems (MEMS) cantilevers is used to measure a broad variety of phenomena in devices ranging from force microscopes to biochemical sensors to thermal imaging systems. We demonstrate the first direct measurement of a MEMS cantilever displacement with a noise floor at 40% of the shot noise limit (SNL). By combining multi-spatial-mode quantum light sources with a simple ?differential measurement, we show that sub-SNL MEMS displacement sensitivity is highly accessible compared to previous efforts that measured the displacement of macroscopic mirrors with very distinct spatial structures crafted with multiple optical parametric amplifiers and locking loops. These results support a new class of quantum MEMS sensor with an ultimate signal to noise ratio determined by quantum correlations, enabling ultra-trace sensing, imaging, and microscopy applications in which signals were previously obscured by shot noise.

  14. Simulation of Oil Displacement from Oil-Wet Cores by Interfacial Tension Reduction and Wettability Alteration

    E-Print Network [OSTI]

    Kalaei, Mohammad Hosein

    2010-01-29

    Waterflooding in oil-wet naturally fractured reservoirs is not successful because the ability of matrix blocks to imbibe the injected water and displace the oil into the fracture system is poor. Chemical enhanced oil recovery methods...

  15. Beyond a Billion: Clean Cities Coaliations Have Displaced More Than a Billion Gallons of Gasoline

    SciTech Connect (OSTI)

    Not Available

    2005-10-01

    In 2004, DOE's Clean Cities achieved a milestone - displacing the equivalent of more than 1 billion gallons of gasoline since 1994. This fact sheet describes how Clean Cities achieved this goal.

  16. Composite force sensing foot utilizing volumetric displacement of a hyperelastic polymer

    E-Print Network [OSTI]

    Chuah, Meng Yee (Meng Yee Michael)

    2012-01-01

    In this thesis, I will describe the fabrication and characterization of a footpad based on an original principle of volumetric displacement sensing. It is intended for use in detecting ground contact forces in a running ...

  17. Design and fabrication of force sensing robotic foot utilizing the volumetric displacement of a hyperelastic polymer

    E-Print Network [OSTI]

    Estrada, Matthew A

    2012-01-01

    This thesis illustrates the fabrication and characterization of a footpad based on an original principle of volumetric displacement sensing. It is intended for use in detecting ground reaction forces in a running quadrupedal ...

  18. Composite force sensing foot utilizing volumetric displacement of a hyperelastic polymer

    E-Print Network [OSTI]

    Chuah, Meng Yee

    This paper illustrates the fabrication and characterization of a footpad based on an original principle of volumetric displacement sensing. It is intended for use in detecting ground contact forces in a running quadrupedal ...

  19. Is it a Cold or the Flu? -Know the Difference Signs & Symptoms Cold Flu

    E-Print Network [OSTI]

    Cantlon, Jessica F.

    Rare Usual; high (100.40 F to 1020 F) is typical; lasts 3-4 days Cough Hacking: mild Dry; can become discomfort Mild to moderate; hacking cough Common Treatment Antihistamines Decongestants Advil® (ibuprofen. Avoid close contact with anyone with a cold. Vaccination. Wash your hands. Cover your cough. Stay

  20. Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial

    E-Print Network [OSTI]

    . Stabilization of excess activated and EBPR sludge in an anaerobic digester results in significant releases of nuElectrochemical struvite precipitation from digestate with a fluidized bed cathode microbial conditions. Soluble phosphorus removal using digester effluent ranged from 70 to 85% with current generation

  1. Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode Particles

    E-Print Network [OSTI]

    Sastry, Ann Marie

    Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode sur- faces in postmortem analysis of batteries.5-7 Stress generation results from lithium-ion, as will be discussed later. Heat transfer analyses of lithium-ion batteries have stemmed from work on full cells.10

  2. Computational Modeling of Electrolyte/Cathode Interfaces in Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Bjørnstad, Ottar Nordal

    Computational Modeling of Electrolyte/Cathode Interfaces in Proton Exchange Membrane Fuel Cells Dr Proton exchange membrane fuel cells (PEMFCs) are alternative energy conversion devices that efficiently. The fundamental relationship between operating conditions and device performance will help to optimize the device

  3. Perturbation of the cathode fall in direct-current glow discharges by particulate contamination

    E-Print Network [OSTI]

    Kushner, Mark

    Perturbation of the cathode fall in direct-current glow discharges by particulate contamination July 1991; accepted for publication 19 September 1991) Particulate (or "dust") contamination of plasma by dust contamination. We find that at constant current densities, the plasma responds to the reduction

  4. Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC

    E-Print Network [OSTI]

    Popov, Branko N.

    The stability of the NiO cathodes in molten carbonate fuel cell (MCFC) has been improved through cell; Microencapsulation; Dissolution 1. Introduction The molten carbonate fuel cell (MCFC), operating Elsevier Science B.V. All rights reserved. Keywords: Cobalt; Electroless plating; Molten carbonate; Fuel

  5. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    SciTech Connect (OSTI)

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  6. High-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature,

    E-Print Network [OSTI]

    Cui, Yi

    capacity of 849 and 610 mAh/g at 2C and 4C, respectively. lithium sulfur battery | energy storage | long energy storage (1­4). To achieve a quantum leap in the batteries specific energy density, new electrodeHigh-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature

  7. Design and performance of a 30 KV electron gun with ten independent cathodes & a magnetic lens.

    SciTech Connect (OSTI)

    Rudys, Joseph Matthew; Reed, Kim Warren

    2006-08-01

    Measurements on a 30 kV electron gun with ten independent cathodes, operating in a 6.5 Tesla (T) magnetic field are presented. An earlier paper covered the design of this electron gun [1]. Experimental results are compared to model predictions. Beam current is compared to theoretical space charge limited flow.

  8. Ion velocities in direct current arc plasma generated from compound cathodes

    SciTech Connect (OSTI)

    Zhirkov, I.; Rosen, J.; Eriksson, A. O.; Oerlikon Balzers Coating AG, Iramali 18, 9496 Balzers

    2013-12-07

    Arc plasma from Ti-C, Ti-Al, and Ti-Si cathodes was characterized with respect to charge-state-resolved ion energy. The evaluated peak velocities of different ion species in plasma generated from a compound cathode were found to be equal and independent on ion mass. Therefore, measured difference in kinetic energies can be inferred from the difference in ion mass, with no dependence on ion charge state. The latter is consistent with previous work. These findings can be explained by plasma quasineutrality, ion acceleration by pressure gradients, and electron-ion coupling. Increasing the C concentration in Ti-C cathodes resulted in increasing average and peak ion energies for all ion species. This effect can be explained by the “cohesive energy rule,” where material and phases of higher cohesive energy generally result in increasing energies (velocities). This is also consistent with the here obtained peak velocities around 1.37, 1.42, and 1.55 (10{sup 4} m/s) for ions from Ti{sub 0.84}Al{sub 0.16}, Ti{sub 0.90}Si{sub 0.10}, and Ti{sub 0.90}C{sub 0.10} cathodes, respectively.

  9. Increased performance of single-chamber microbial fuel cells using an improved cathode structure

    E-Print Network [OSTI]

    performance. We show here that application of successive polytetrafluoroethylene (PTFE) layers (DLs), on a carbon/PTFE base layer, to the air-side of the cath- ode in a single chamber MFC significantly improved reserved. Keywords: Microbial fuel cell; Air cathode; Diffusion layer; PTFE coating; Coulombic efficiency 1

  10. Field emission from strained carbon nanotubes on cathode substrate D. Roy Mahapatra a,

    E-Print Network [OSTI]

    Melnik, Roderick

    Field emission from strained carbon nanotubes on cathode substrate D. Roy Mahapatra a, *, N. Sinha, Waterloo, Ont. N2L3C5, Canada 1. Introduction Field emission from carbon nanotube (CNT) was first reported, the use of CNTs in the field emission devices (e.g., field emission displays, X-ray tube sources, electron

  11. Enhanced water desalination efficiency in an air-cathode stacked microbial electrodeionization cell (SMEDIC)

    E-Print Network [OSTI]

    less electrical energy [2,3]. Microbial desalination cells (MDCs) have recently drawn atten- tion as a low-energy method of water desalination. The simplest MDC is a microbial fuel cell (MFCEnhanced water desalination efficiency in an air-cathode stacked microbial electrodeionization cell

  12. Use of low cost and easily regenerated Prussian Blue cathodes for efficient electrical energy

    E-Print Network [OSTI]

    Cui, Yi

    Cui*bd Microbial fuel cells can directly convert chemical energy into electrical energy, but significant energy losses result from the use of O2 as the cathode. Microbial batteries (MBs) replace of microorganisms, converting the chemical energy of dilute organic matter into electricity.1­5 Microbial fuel cells

  13. Understanding structural defects in lithium-rich layered oxide cathodes Karalee A. Jarvis,a

    E-Print Network [OSTI]

    Ferreira, Paulo J.

    the required amounts of lithium, manganese, and nickel acetates were added to this solution. The molar ratioUnderstanding structural defects in lithium-rich layered oxide cathodes Karalee A. Jarvis, Accepted 31st March 2012 DOI: 10.1039/c2jm30575e Planar defects in lithium-rich layered oxides were

  14. Methanol adsorbates on the DMFC cathode and their effect on the cell performance

    E-Print Network [OSTI]

    Zhao, Tianshou

    Methanol adsorbates on the DMFC cathode and their effect on the cell performance J. Prabhuram, T in the performance of a direct methanol fuel cell (DMFC) occurred after the cell had been operated at a higher temperature with higher methanol concentrations as compared with the polarization data collected under

  15. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    DOE Patents [OSTI]

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  16. A Comparison of Fick and Maxwell-Stefan Diffusion Formulations in PEMFC Cathode Gas

    E-Print Network [OSTI]

    Wetton, Brian

    A Comparison of Fick and Maxwell-Stefan Diffusion Formulations in PEMFC Cathode Gas Diffusion Electrolyte Membrane Fuel Cells (PEMFC) are promising energy pro- ducing electrochemical devices [15]. Thus, models of PEMFC include a description of multi- component gas flow in porous media

  17. Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga

    E-Print Network [OSTI]

    1 Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga.O. Box 451, Princeton, NJ 08543 May 31, 1999 Abstract Energy distributions of N atoms in a hollow, University of Illinois c Varian Associates, Inc. #12;2 atom energy distributions for atomic ions

  18. innovati nNREL Enhances the Performance of a Lithium-Ion Battery Cathode

    E-Print Network [OSTI]

    potential environmental and safety issues. The search for a replacement cathode material has led to lithium, the chemical reaction of the anode with the electrolyte causes electrons to enter the wire, moving throughFePO4 is due to the particular geometry of its electronic struc- ture--in technical terms, it has

  19. Cathode fall model and current-voltage characteristics of field emission driven direct current microplasmas

    SciTech Connect (OSTI)

    Venkattraman, Ayyaswamy

    2013-11-15

    The post-breakdown characteristics of field emission driven microplasma are studied theoretically and numerically. A cathode fall model assuming a linearly varying electric field is used to obtain equations governing the operation of steady state field emission driven microplasmas. The results obtained from the model by solving these equations are compared with particle-in-cell with Monte Carlo collisions simulation results for parameters including the plasma potential, cathode fall thickness, ion number density in the cathode fall, and current density vs voltage curves. The model shows good overall agreement with the simulations but results in slightly overpredicted values for the plasma potential and the cathode fall thickness attributed to the assumed electric field profile. The current density vs voltage curves obtained show an arc region characterized by negative slope as well as an abnormal glow discharge characterized by a positive slope in gaps as small as 10 ?m operating at atmospheric pressure. The model also retrieves the traditional macroscale current vs voltage theory in the absence of field emission.

  20. Phase field modeling of microstructure evolution of electrocatalyst-infiltrated solid oxide fuel cell cathodes

    E-Print Network [OSTI]

    Chen, Long-Qing

    instability and mechanical damage in solid oxide fuel cell anodes J. Appl. Phys. 114, 183519 (2013); 10-phase electrode microstructures in solid oxide fuel cells Appl. Phys. Lett. 101, 033909 (2012); 10.1063/1.4738230 Synthesis and calorimetric studies of oxide multilayer systems: Solid oxide fuel cell cathode