Sample records for disciplines surface chemistry

  1. Protein Patterning with Programmable Surface Chemistry Chips

    E-Print Network [OSTI]

    step with different protein solution on a different heater. The micro-fabrication process consists-isopropylacrylamide, ppNIPAM) onto arrays of micro-fabricated metallic heaters. Activating a single heater causes proteins were used to demonstrate localized immobilization of proteins on the surface of coated micro-heater

  2. Surface Chemistry of 2-Propanol on TiO2(110): Low and High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of 2-Propanol on TiO2(110): Low and High Temperature Dehydration, Isotope Effects, and Influence of Local Surface Chemistry of 2-Propanol on TiO2(110): Low and High...

  3. The Role of Surface Chemistry and Bulk Properties on the Cycling...

    Broader source: Energy.gov (indexed) [DOE]

    before and after cycling using synchrotron X-ray diffraction and transmission X-ray absorption spectroscopy. Correlating surface chemistry and bulk structure information with...

  4. The Role of Surface Chemistry on the Cycling and Rate Capability...

    Broader source: Energy.gov (indexed) [DOE]

    before and after cycling using synchrotron X-ray diffraction and transmission X-ray absorption spectroscopy. Correlating surface chemistry and bulk structure information with...

  5. Surface Electro Radiation and Photo Chemistry PARIS-SUD GENOVA PORTO POZNAN

    E-Print Network [OSTI]

    Surface Electro Radiation and Photo ­ Chemistry SERP-Chem PARIS-SUD GENOVA PORTO POZNAN SERP students 17 000 for European students Two-years master course in Surface, Electro, Radiation, and Photo, Radiation, and Photo Chemistry CONTACT INFORMATION ERASMUS MUNDUS Support of G.Ertl, Nobel price

  6. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01T23:59:59.000Z

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  7. Molecular Surface Chemistry by Metal Single Crystals and Nanoparticles from Vacuum to High Pressure.

    SciTech Connect (OSTI)

    Somorjai, Gabor A.; Park, Jeong Y.

    2008-04-05T23:59:59.000Z

    Model systems for studying molecular surface chemistry have evolved from single crystal surfaces at low pressure to colloidal nanoparticles at high pressure. Low pressure surface structure studies of platinum single crystals using molecular beam surface scattering and low energy electron diffraction techniques probe the unique activity of defects, steps and kinks at the surface for dissociation reactions (H-H, C-H, C-C, O{double_bond}O bonds). High-pressure investigations of platinum single crystals using sum frequency generation vibrational spectroscopy have revealed the presence and the nature of reaction intermediates. High pressure scanning tunneling microscopy of platinum single crystal surfaces showed adsorbate mobility during a catalytic reaction. Nanoparticle systems are used to determine the role of metal-oxide interfaces, site blocking and the role of surface structures in reactive surface chemistry. The size, shape and composition of nanoparticles play important roles in determining reaction activity and selectivity.

  8. Experimental studies of lithium-based surface chemistry for fusion plasma-facing materials applications q

    E-Print Network [OSTI]

    Harilal, S. S.

    - ments of plasma-surface interactions in tokamaks such as NSTX. Results suggest that the lithium bondingExperimental studies of lithium-based surface chemistry for fusion plasma-facing materials.65.y a b s t r a c t Lithium has enhanced the operational performance of fusion devices such as: TFTR

  9. Chem. Rev. 1994, 94, 107-125 107 Optical Second Harmonic Generation as a Probe of Surface Chemistry

    E-Print Network [OSTI]

    Chem. Rev. 1994, 94, 107-125 107 Optical Second Harmonic Generation as a Probe of Surface Chemistry 109 IV. SHG Measurements of Surface Chemistry 109 VI. Acknowledgments 122 V II.References 122 V. Other Surface SHG Experiments and Future 122 Directions I. Introduction Optical second harmonic generation (SHG

  10. Surface chemistry controls crystallinity of ZnSnanoparticles

    SciTech Connect (OSTI)

    Gilbert, Benjamin; Huang, Feng; Lin, Zhang; Goodell, Carmen; Zhang, Hengzhong; Banfield Jillian F.

    2005-12-20T23:59:59.000Z

    Combined small-angle and high energy wide-angle x-ray scattering measurements of nanoparticle size and structure permit interior strain and disorder to be directly observed in the real-space pair distribution function (PDF). PDF analysis showed that samples of ZnS nanoparticle with similar mean diameters (3.2-3.6 nm) but synthesized and treated differently possess a dramatic range of interior disorder. We used Fourier transform infra-red spectroscopy to detect the surface species and the nature of surface chemical interactions. Our results suggest that there is a direct correlation between the strength of surface-ligand interactions and interior crystallinity.

  11. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry

  12. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms AboutRESEARCH CAPABILITIES Thematerials | CenterChemistry

  13. Explorations of Functionalized Gold Nanoparticle Surface Chemistry for Laser Desorption Ionization Mass Spectrometry Applications

    E-Print Network [OSTI]

    Gomez Hernandez, Mario 1980-

    2012-07-11T23:59:59.000Z

    EXPLORATIONS OF FUNCTIONALIZED GOLD NANOPARTICLE SURFACE CHEMISTRY FOR LASER DESORPTION IONIZATION MASS SPECTROMETRY APPLICATIONS A Thesis by MARIO ESTUARDO GOMEZ HERNANDEZ Submitted to the Office... DESORPTION IONIZATION MASS SPECTROMETRY APPLICATIONS A Thesis by MARIO ESTUARDO GOMEZ HERNANDEZ Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree...

  14. LU Surface Chemistry 17 STM of (2222)R45-Ti5O8/Pt(100)

    E-Print Network [OSTI]

    Gilchrist, James F.

    on MgO(100) NO2 adsorption on metals IRAS ITAS #12;LU Surface Chemistry 22 New FTIR ·Measurements Research Scientist, Air Products PLC, Packaged Gases COE, European Technology Group, Crewe, Cheshire CW1 6(-x) Corrosion Etching and Dissolution UPD and Film growth Electrodes for Batteries Fuel cell electrocatalysts

  15. Surface chemistry : a non-negligible parameter in determining optical properties of small colloidal metal nanoparticles.

    SciTech Connect (OSTI)

    Sun, Y.; Gray, S. K.; Peng, S. (Center for Nanoscale Materials)

    2011-01-01T23:59:59.000Z

    Surface chemistry can become pronounced in determining the optical properties of colloidal metal nanoparticles as the nanoparticles become so small (diameters <20 nm) that the surface atoms, which can undergo chemical interactions with the environment, represent a significant fraction of the total number of atoms although this effect is often ignored. For instance, formation of chemical bonds between surface atoms of small metal nanoparticles and capping molecules that help stabilize the nanoparticles can reduce the density of conduction band electrons in the surface layer of metal atoms. This reduced electron density consequently influences the frequency-dependent dielectric constant of the metal atoms in the surface layer and, for sufficiently high surface to volume ratios, the overall surface plasmon resonance (SPR) absorption spectrum. The important role of surface chemistry is highlighted here by carefully analyzing the classical Mie theory and a multi-layer model is presented to produce more accurate predictions by considering the chemically reduced density of conduction band electrons in the outer shell of metal atoms in nanoparticles. Calculated absorption spectra of small Ag nanoparticles quantitatively agree with the experimental results for our monodispersed Ag nanoparticles synthesized via a well-defined chemical reduction process, revealing an exceptional size-dependence of absorption peak positions: the peaks first blue-shift followed by a turnover and a dramatic red-shift as the particle size decreases. A comprehensive understanding of the relationship between surface chemistry and optical properties is beneficial to exploit new applications of small colloidal metal nanoparticles, such as colorimetric sensing, electrochromic devices, and surface enhanced spectroscopies.

  16. Designing a service science discipline with discipline

    E-Print Network [OSTI]

    Glushko, Robert J.

    in what IBM began to call, in late 2004, service science, management and engineering--or simply SSME. 3 in information and computing technol- ogy, industrial engineering, business strategy, eco- nomics, lawDesigning a service science discipline with discipline & R. J. Glushko This paper relates our

  17. Effects of Alloying on the Chemistry of CO and H2S on Fe Surfaces D. E. Jiang

    E-Print Network [OSTI]

    Carter, Emily A.

    Effects of Alloying on the Chemistry of CO and H2S on Fe Surfaces D. E. Jiang Department. Carter* Department of Mechanical and Aerospace Engineering and Program in Applied and Computational with the metal surface. Here we consider whether alloying the steel surface might be able to inhibit

  18. Thermal chemistry of the Cu-KI5 atomic layer deposition precursor on a copper surface

    SciTech Connect (OSTI)

    Ma, Qiang; Zaera, Francisco, E-mail: zaera@ucr.edu [Department of Chemistry, University of California, Riverside, California 92521 (United States)

    2015-01-01T23:59:59.000Z

    The thermal chemistry of a Cu(I) ketoiminate complex, Cu-KI5, resulting from the modification of the known Air Products CupraSelect{sup } copper CVD precursor Cu(hfac)(tmvs) designed to tether the two ligands via an isopropoxide linker, was studied under ultrahigh vacuum on a Cu(110) single-crystal surface by using a combination of temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy. Adsorption at low temperatures was determined to take place via the displacement of the vinyl ligand by the surface. Molecular desorption was seen at 210?K, and the evolution of Cu(II)-KI5{sub 2} was established to take place at 280?K, presumably from a disproportionation reaction that also leads to the deposition of Cu(0). Other sets of desorption products were seen at 150, 250, and 430?K, all containing copper atoms and small organic moieties with molecular masses below 100 amu. The latter TPD peak in particular indicates significant fragmentation of the ligands, likely at the CN bond that holds the vinylsilane-isopropoxide moiety tethered to the ketoimine fragment, and possibly also at the union between the vinylsilane and the alkoxide linker. The 430?K temperature measured for this chemistry may set an upper limit for clean Cu film deposition, but since reactivity on the surface was also found to be inhibited at higher surface coverages, it may be delayed to higher temperatures under atomic layer deposition conditions.

  19. Effects of extreme pressure additive chemistry on rolling element bearing surface durability

    SciTech Connect (OSTI)

    Evans, Ryan D. [Timken Company; Nixon, H. P. [Timken Company; Darragh, Craig V. [Timken Company; Howe, Jane Y [ORNL; Coffey, Dorothy W [ORNL

    2007-01-01T23:59:59.000Z

    Lubricant additives have been known to affect rolling element bearing surface durability for many years. Tapered roller bearings were used in fatigue testing of lubricants formulated with gear oil type additive systems. These systems have sulfur- and phosphoruscontaining compounds used for gear protection as well as bearing lubrication. Several variations of a commercially available base additive formulation were tested having modified sulfur components. The variations represent a range of ''active'' extreme pressure (EP) chemistries. The bearing fatigue test results were compared with respect to EP formulation and test conditions. Inner ring near-surface material in selected test bearings was evaluated on two scales: the micrometer scale using optical metallography and the nanometer scale using transmission electron microscopy (TEM). Focused-ion beam (FIB) techniques were used for TEM specimen preparation. Imaging and chemical analysis of the bearing samples revealed near-surface material and tribofilm characteristics. These results are discussed with respect to the relative fatigue lives.

  20. Administering Workforce Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-10-27T23:59:59.000Z

    To provide requirements and responsibilities for administering workforce discipline that includes disciplinary, adverse, and alternative corrective actions in the Department of Energy (DOE).

  1. Investigation of IAQ-Relevant Surface Chemistry and Emissions on HVAC Filter Materials

    E-Print Network [OSTI]

    Destaillats, Hugo

    2010-01-01T23:59:59.000Z

    VOCs emitted by reactions of HVAC filters with ozone usingChemistry and Emissions on HVAC Filter Materials HugoChemistry and Emissions on HVAC Filter Materials Authors:

  2. CHEMICAL MODELING OF INFRARED DARK CLOUDS: THE ROLE OF SURFACE CHEMISTRY

    SciTech Connect (OSTI)

    Vasyunina, T.; Vasyunin, A. I.; Herbst, Eric [Department of Chemistry, University of Virginia, Charlottesville, VA 22904 (United States); Linz, H. [Max Planck Institute for Astronomy (MPIA), Koenigstuhl 17, D-69117 Heidelberg (Germany)

    2012-06-01T23:59:59.000Z

    We simulate the chemistry of infrared dark clouds (IRDCs) with a model in which the physical conditions are homogeneous and time independent. The chemistry is solved as a function of time with three networks: one purely gas phase, one that includes accretion and desorption, and one, the complete gas-grain network, that includes surface chemistry in addition. We compare our results with observed molecular abundances for two representative IRDCs-IRDC013.90-1 and IRDC321.73-1-using the molecular species N{sub 2}H{sup +}, HC{sub 3}N, HNC, HCO{sup +}, HCN, C{sub 2}H, NH{sub 3}, and CS. IRDC013.90-1 is a cold IRDC, with a temperature below 20 K, while IRDC321.73-1 is somewhat warmer, in the range 20-30 K. We find that the complete gas-grain model fits the data very well, but that the goodness of fit is not sharply peaked at a particular temperature. Surface processes are important for the explanation of the high gas-phase abundance of N{sub 2}H{sup +} in IRDC321.73-1. The general success of the zero-dimensional model in reproducing single-dish observations of our limited sample of eight species shows that it is probably sufficient for an explanation of this type of data. To build and justify more complicated models, including spatial temperature and density structure, contraction, and heating, we require high-resolution interferometric data.

  3. Chemistry of SOFC Cathode Surfaces: Fundamental Investigation and Tailoring of Electronic Behavior

    SciTech Connect (OSTI)

    Yildiz, Bilge; Heski, Clemens

    2013-08-31T23:59:59.000Z

    1) Electron tunneling characteristics on La0.7Sr0.3MnO3 (LSM) thin-film surfaces were studied up to 580oC in 10-3mbar oxygen pressure, using scanning tunneling microscopy/ spectroscopy (STM/STS). A threshold-like drop in the tunneling current was observed at positive bias in STS, which is interpreted as a unique indicator for the activation polarization in cation oxygen bonding on LSM cathodes. Sr-enrichment was found on the surface at high temperature using Auger electron spectroscopy, and was accompanied by a decrease in tunneling conductance in STS. This suggests that Sr-terminated surfaces are less active for electron transfer in oxygen reduction compared to Mn-terminated surfaces on LSM. 2) Effects of strain on the surface cation chemistry and the electronic structure are important to understand and control for attaining fast oxygen reduction kinetics on transition metal oxides. Here, we demonstrate and mechanistically interpret the strain coupling to Sr segregation, oxygen vacancy formation, and electronic structure on the surface of La0.7Sr0.3MnO3 (LSM) thin films as a model system. Our experimental results from x-ray photoelectron spectroscopy and scanning tunneling spectroscopy are discussed in light of our first principles-based calculations. A stronger Sr enrichment tendency and a more facile oxygen vacancy formation prevail for the tensile strained LSM surface. The electronic structure of the tensile strained LSM surface exhibits a larger band gap at room temperature, however, a higher tunneling conductance near the Fermi level than the compressively strained LSM at elevated temperatures in oxygen. Our findings suggest lattice strain as a key parameter to tune the reactivity of perovskite transition metal oxides with oxygen in solid oxide fuel cell cathodes. 3) Cation segregation on perovskite oxide surfaces affects vastly the oxygen reduction activity and stability of solid oxide fuel cell (SOFC) cathodes. A unified theory that explains the physical origins of this phenomenon is therefore needed for designing cathode materials with optimal surface chemistry. We quantitatively assessed the elastic and electrostatic interactions of the dopant with the surrounding lattice as the key driving forces for segregation on model perovskite compounds, LnMnO3 (host cation Ln=La, Sm). Our approach combines surface chemical analysis with X-ray photoelectron and Auger electron spectroscopy on model dense thin films, and computational analysis with density functional theory (DFT) calculations and analytical models. Elastic energy differences were systematically induced in the system by varying the radius of the selected dopants (Ca, Sr, Ba) with respect to the host cations (La, Sm) while retaining the same charge state. Electrostatic energy differences were introduced by varying the distribution of charged oxygen and cation vacancies in our models. Varying the oxygen chemical potential in our experiments induced changes in both the elastic energy and electrostatic interactions. Our results quantitatively demonstrate that the mechanism of dopant segregation on perovskite oxides includes both the elastic and electrostatic energy contributions. A smaller size mismatch between the host and dopant cations and a chemically expanded lattice were found to reduce the segregation level of the dopant and to enable more stable cathode surfaces. Ca-doped LaMnO3 was found to have the most stable surface composition with the least cation segregation among the compositions surveyed. The diffusion kinetics of the larger dopants, Ba and Sr, was found to be slower, and can kinetically trap the segregation at reduced temperatures despite the larger elastic energy driving force. Lastly, scanning probe image-contrast showed that the surface chemical heterogeneities made of dopant oxides upon segregation were electronically insulating. The consistency between the results obtained from experiments, DFT calculations and analytical theory in this work provides a predictive capability to tailor the cathode surface compositions for high-performance SO

  4. fll INTRODUCTION Solid mechanics is a fundamental discipline which, in

    E-Print Network [OSTI]

    generation technologies such as fusion, nuclear and gas turbine power, aerospace and surface trans- nortation, solid mechanics is a central discipline for hydrocarbon resource extraction by drilling, hydraulic

  5. Untangling the Chemical Evolution of Titan's Atmosphere and Surface -- From Homogeneous to Heterogeneous Chemistry

    SciTech Connect (OSTI)

    Kaiser, Ralf I.; Maksyutenko, Pavlo; Ennis, Courtney; Zhang, Fangtong; Gu, Xibin; Krishtal, Sergey P.; Mebel, Alexander M.; Kostko, Oleg; Ahmed, Musahid

    2010-03-16T23:59:59.000Z

    The arrival of the Cassini-Huygens probe at Saturn's moon Titan - the only Solar System body besides Earth and Venus with a solid surface and a thick atmosphere with a pressure of 1.4 atm at surface level - in 2004 opened up a new chapter in the history of Solar System exploration. The mission revealed Titan as a world with striking Earth-like landscapes involving hydrocarbon lakes and seas as well as sand dunes and lava-like features interspersed with craters and icy mountains of hitherto unknown chemical composition. The discovery of a dynamic atmosphere and active weather system illustrates further the similarities between Titan and Earth. The aerosol-based haze layers, which give Titan its orange-brownish color, are not only Titan's most prominent optically visible features, but also play a crucial role in determining Titan's thermal structure and chemistry. These smog-like haze layers are thought to be very similar to those that were present in Earth's atmosphere before life developed more than 3.8 billion years ago, absorbing the destructive ultraviolet radiation from the Sun, thus acting as 'prebiotic ozone' to preserve astrobiologically important molecules on Titan. Compared to Earth, Titan's low surface temperature of 94 K and the absence of liquid water preclude the evolution of biological chemistry as we know it. Exactly because of these low temperatures, Titan provides us with a unique prebiotic 'atmospheric laboratory' yielding vital clues - at the frozen stage - on the likely chemical composition of the atmosphere of the primitive Earth. However, the underlying chemical processes, which initiate the haze formation from simple molecules, have been not understood well to date.

  6. DNA damage response to different surface chemistry of silver nanoparticles in mammalian cells

    SciTech Connect (OSTI)

    Ahamed, Maqusood; Karns, Michael; Goodson, Michael; Rowe, John [Department of Biology, Centre for Tissue Regeneration and Engineering, University of Dayton, Dayton-45469, OH (United States); Hussain, Saber M.; Schlager, John J. [Applied Biotechnology Branch, Human Effectiveness Directorate Air Force Research Laboratory/HEPB, Wright-Patterson Air Force Base-45433, OH (United States); Hong Yiling [Department of Biology, Centre for Tissue Regeneration and Engineering, University of Dayton, Dayton-45469, OH (United States)], E-mail: Yiling.Hong@notes.udayton.edu

    2008-12-15T23:59:59.000Z

    Silver nanoparticles (Ag NPs) have recently received much attention for their possible applications in biotechnology and life sciences. Ag NPs are of interest to defense and engineering programs for new material applications as well as for commercial purposes as an antimicrobial. However, little is known about the genotoxicity of Ag NPs following exposure to mammalian cells. This study was undertaken to examine the DNA damage response to polysaccharide surface functionalized (coated) and non-functionalized (uncoated) Ag NPs in two types of mammalian cells; mouse embryonic stem (mES) cells and mouse embryonic fibroblasts (MEF). Both types of Ag NPs up-regulated the cell cycle checkpoint protein p53 and DNA damage repair proteins Rad51 and phosphorylated-H2AX expression. Furthermore both of them induced cell death as measured by the annexin V protein expression and MTT assay. Our observations also suggested that the different surface chemistry of Ag NPs induce different DNA damage response: coated Ag NPs exhibited more severe damage than uncoated Ag NPs. The results suggest that polysaccharide coated particles are more individually distributed while agglomeration of the uncoated particles limits the surface area availability and access to membrane bound organelles.

  7. A Comprehensive Study of Surface Chemistry for Application to Engine NOx Aftertreatment

    SciTech Connect (OSTI)

    Aceves, S M; Piggot, T; Pitz, W; Mundy, C; Kuo, W; Havstad, M

    2004-02-19T23:59:59.000Z

    This work focuses on developing a scientific understanding of the processes associated with NO{sub x} trap operation. NO{sub x} traps are the most advanced technology for achieving future emissions standards with diesel engines. Successful development of NO{sub x} traps will allow widespread use of diesel engines in light-duty vehicles, reducing oil imports by as much as 60%. Diesel engines have a high efficiency and low maintenance that makes them the ideal choice for transportation applications. Use of diesel engines in all light-duty vehicles would reduce oil consumption in the USA by 30% and oil imports by 60%, considerably improving our energy security. For heavy trucks, there is no viable alternative to diesel engines. Only diesel engines can provide the necessary high efficiency and long life. These benefits are offset by high emission of pollutants. Diesel engines have high emissions of NO{sub x} and particulate matter. Over the last 20 years, EPA has been reducing allowable emissions from diesel engines, and NO{sub x} emissions are scheduled to be cut by a factor of 10 over the next 7 years. The target NO{sub x} emissions for year 2010 is 0.20 g/hp-hr. This value is well below 1 g/hp-hr, which has been identified by one of the authors (Pitz [1]) as the minimum possible NO{sub x} emissions that can be obtained in a diesel engine with satisfactory combustion and without exhaust aftertreatment. An 80% efficient aftertreatment system is therefore necessary for achieving the 2010 NO{sub x} emissions regulation. Achieving this level of diesel aftertreatment efficiency is a daunting task, and one that will require a strong research effort. Manufacturing diesel after treatment systems with 80% efficiency for model year 2010 is an extremely difficult task. Our advanced analysis tools (computational chemistry linked with fluid mechanics and heat transfer) can be used to analyze and optimize NO{sub x} traps, which are the system of choice for diesel engine aftertreatment. NO{sub x} adsorbing catalysts operate by adsorbing the NO{sub x} in the exhaust stream during regular engine operation. After a period of time (1 minute), the catalyst saturates and has to be regenerated. Regeneration is achieved by injecting a reductant (typically fuel, although hydrogen or ammonia can also be used) into the catalyst. The adsorbed NO{sub x} desorbs under rich conditions, and then reacts with the reductant, producing molecular nitrogen, water and carbon dioxide. The regeneration cycle typically lasts about 2 seconds. After the regeneration cycle, the catalyst is ready for a new adsorption cycle. Intermittent regeneration of the catalytic surfaces is a complex process, and much of the basic science behind this process is not understood. Unsolved scientific problems include the development of chemical kinetic mechanisms for surface chemistry; the analysis of sulfur poisoning of the catalyst surfaces and the phenomenon of thermal aging of the catalyst materials. The adsorption and regeneration processes are dependent on gaseous flow rate, surface chemical kinetics and converter geometry. A comprehensive study of this process is of great importance to achieve the desired system efficiency for NO{sub x} reduction. The possibilities and future market opportunities are enormous. This project supports the DOE mission by improving national security through reduced dependence on foreign oil. This work also provides an opportunity for enhancing our surface chemistry analysis capabilities, which have great applicability to missile reentry, fuel cells, and sensors for chemical warfare agents and explosives detection. In addition to this, we will help the US industry remain competitive and will help clean up the environment.

  8. CHEMISTRY 2011 Academic regulations for the Bachelor's degree in Chemistry 2011

    E-Print Network [OSTI]

    CHEMISTRY 2011 Academic regulations for the Bachelor's degree in Chemistry 2011 1. Framework) in Chemistry. Academic line and main subject areas of the degree The Bachelor's degree in Chemistry students a basic introduction to the Chemistry disciplines. In addition, the Bachelor's degree programme

  9. Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1983-03-23T23:59:59.000Z

    The order provides guidance and procedures and states responsibilities for maintaining work force discipline in DOE. Chg 1, dated 3-11-85; Chg 2, dated 1-6-86; Chg 3, dated 3-21-89; Chg 4, dated 8-2-90; Chg 5, dated 3-9-92; Chg 6, dated 8-21-92, cancels Chg 5.

  10. Dissolution rates and surface chemistry of feldspar glass and crystal. Final technical report, June 15, 1995 - August 14, 2001

    SciTech Connect (OSTI)

    Brantley, S.; Pantano, C.

    2002-06-11T23:59:59.000Z

    Final report summarizing the completed work of the project entitled 'Dissolution of Feldspar in the Field and Laboratory.' One of the highly debated questions today in low-temperature geochemical kinetics centers upon the rate and mechanism of dissolution of feldspar, the most common mineral in the crust. In this project, the mechanisms of feldspar dissolution were investigated by emphasizing experiments with feldspar glass and crystal while comparing surface and solution chemistry. Specifically, laboratory work focused on the structure of altered surface layers on feldspars, the rate of dissolution of feldspar crystal and glass, and the presence of porosity and surface coatings on feldspars. In a complementary field project, the use of Sr concentrations and isotopic ratios were used to calculate feldspar dissolution rates.

  11. Research degrees MPhil, PhD in Chemistry

    E-Print Network [OSTI]

    Sussex, University of

    nuclear magnetic resonance spectrometers, with multinuclear capability · high-res mass spectrometers second-class undergraduate honours degree in chemistry or a related discipline English language

  12. Regulation 2: Student Discipline REGULATION 2: STUDENT DISCIPLINE

    E-Print Network [OSTI]

    Sussex, University of

    Regulation 2: Student Discipline 6 REGULATION 2: STUDENT DISCIPLINE 1. Definitions In this Regulation: The University means the University of Sussex. Council means Council of the University. Senate to the regulations of the affiliated institution, and excluding students in attendance at the Brighton and Sussex

  13. 147Chemistry Chemistry (Chem)

    E-Print Network [OSTI]

    Dresden, Gregory

    147Chemistry Chemistry (Chem) Bayly Foundation PROFESSORS FRANCE, PLEVA ASSOCIATE PROFESSORS ALty A student may complete only one of the majors listed in the Department of Chemistry. The major in chemistry leading to a Bachelor of Arts degree requires completion of 44 credits as follows: 1. Chemistry 111, 112

  14. The effect of mineral surface chemistry on the biodegradation of petroleum

    E-Print Network [OSTI]

    Allan, Katherine Ann

    1997-01-01T23:59:59.000Z

    treatments after normalizing based on the amount of available surface area. The high surface area (372 M2) sand treatment degraded faster than the low surface area (186 M2) sand treatment whereas the opposite was true for the Vertisol. The observed...

  15. Measuring the role of surface chemistry in silicon microphotonics Matthew Borselli,a

    E-Print Network [OSTI]

    Painter, Oskar

    can be de- fined as s s/ts, where s is the fractional electric field energy overlap with a surface, California 91125 Received 13 December 2005; accepted 7 March 2006; published online 31 March 2006 Utilizing surface optical loss of s 10-7 , we show that the optical loss within Si microphotonic components can

  16. Examining metal nanoparticle surface chemistry using hollow-core, photonic-crystal, fiber-assisted SERS

    E-Print Network [OSTI]

    the enhancement of the local electromagnetic field of metal NPs due to excitation of localized surface plasmons [1 to monitor minute amounts of sur- face ligands on gold nanoparticles used as an SERS substrate. The SERS--mercaptopoly(ethylene glycol) on the surface of gold nanorods as an exemplary system, we show the feasibility of using HCPCF

  17. Surface chemistry of stainless steel and evaporated titanium layers in tokamaks

    SciTech Connect (OSTI)

    Staib, P.; Dylla, H.F.; Rossenagel, S.M.

    1980-08-01T23:59:59.000Z

    The combined use of x-ray photoelectron spectroscopy and secondary ion mass spectroscopy is shown to be a powerful tool in the investigation of the chemical modifications of a surface in interaction with a plasma. The reported investigations are performed in-situ in the surface analysis station of the PDX tokamak. The evolution of stainless steel surfaces is followed after various treatments such as hydrogen glow discharge conditioning (GDC), exposure to tokamak discharges, and ion sputtering. Iron oxides are shown to be partially reduced by exposure to GDC; the metal-oxide binding is converted to metal-hydroxide binding from which water can be desorbed. The oxygen behavior on evaporated titanium films is substantially different: the oxide layer evolves to higher oxidation states during exposure to GDC. In contrast, the behavior of carbon is identical on both stainless steel and titanium surfaces: carbon is removed during exposure to GDC via the formation of methane which can spontaneously desorb from the surface.

  18. Synthesis and elaboration of polyethylene surfaces modified via anionic grafting chemistry

    E-Print Network [OSTI]

    Bandella, Ashok Krishangopal

    1996-01-01T23:59:59.000Z

    (given by cos 8) decreased on going from a to b to c indicating that the grafted surfaces were more hydrophilic. Variation of Young's water contact angle with pH for poly(acrylic acid) grafted PE films. Measurements were taken aAer allowing a drop... 1). CH3 CH2 H3 CH2 CH, Cr03-H2SO4 COOH COOH C=O OH C=O COOH However, this technique implicitly incorporates chain scission as part of the overall reaction along with some undesired side reactions. The functionalized 'surface...

  19. Effect of flame-retarding additives on surface chemistry in Li-ion batteries

    SciTech Connect (OSTI)

    Nam, N.D.; Park, I.J. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)] [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, J.G., E-mail: kimjg@skku.ac.kr [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, H.S. [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)] [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    This study examined the properties of 1 wt.% vinylene carbonate (VC), vinyl ethylene carbonate (VEC), and diphenyl octyl phosphate (DPOF) additive electrolytes as a promising way of beneficially improving the surface and cell resistance of Li-ion batteries. Surface film formation on the negative and positive electrodes was analyzed by electrochemical impedance spectroscopy (EIS), Fourier transform infrared (FT-IR) spectroscopy, and scanning electron microscopy (SEM). In conclusion, EIS, FT-IR spectroscopy and SEM results confirmed that DPOF is an excellent additive to the electrolyte in the Li-ion batteries due to the improved co-intercalation of the solvent molecules.

  20. Antireflection and SiO2 Surface Passivation by Liquid-Phase Chemistry for Efficient Black Silicon Solar Cells: Preprint

    SciTech Connect (OSTI)

    Yuan, H. C.; Oh, J.; Zhang, Y.; Kuznetsov, O. A.; Flood, D. J.; Branz, H. M.

    2012-06-01T23:59:59.000Z

    We report solar cells with both black Si antireflection and SiO2 surface passivation provided by inexpensive liquid-phase chemistry, rather than by conventional vacuum-based techniques. Preliminary cell efficiency has reached 16.4%. Nanoporous black Si antireflection on crystalline Si by aqueous etching promises low surface reflection for high photon utilization, together with lower manufacturing cost compared to vacuum-based antireflection coating. Ag-nanoparticle-assisted black Si etching and post-etching chemical treatment recently developed at NREL enables excellent control over the pore diameter and pore separation. Performance of black Si solar cells, including open-circuit voltage, short-circuit current density, and blue response, has benefited from these improvements. Prior to this study, our black Si solar cells were all passivated by thermal SiO2 produced in tube furnaces. Although this passivation is effective, it is not yet ideal for ultra-low-cost manufacturing. In this study, we report, for the first time, the integration of black Si with a proprietary liquid-phase deposition (LPD) passivation from Natcore Technology. The Natcore LPD forms a layer of <10-nm SiO2 on top of the black Si surface in a relatively mild chemical bath at room temperature. We demonstrate black Si solar cells with LPD SiO2 with a spectrum-weighted average reflection lower than 5%, similar to the more costly thermally grown SiO2 approach. However, LPD SiO2 provides somewhat better surface-passivation quality according to the lifetime analysis by the photo-conductivity decay measurement. Moreover, black Si solar cells with LPD SiO2 passivation exhibit higher spectral response at short wavelength compared to those passivated by thermally grown SiO2. With further optimization, the combination of aqueous black Si etching and LPD could provide a pathway for low-cost, high-efficiency crystalline Si solar cells.

  1. Surface Water Chemistry in White Oak Creek, North-East Texas: Effect of Land Use

    E-Print Network [OSTI]

    Watson, Eliza

    2012-02-14T23:59:59.000Z

    watersheds soils, leaches readily to surface waters. Manure can contribute a significant amount of phosphorus loading into adjacent streams from livestock agriculture (James et al. 2007). Contributions from dairy cattle in a watershed in southeastern... New York showed that in-stream fecal deposits from pastured cattle represented 10% of watershed phosphorus loadings (James et al. 2007). Additionally, it was found that livestock grazing along streams and riparian zones can also have adverse...

  2. Study of the surface chemistry and morphology of single walled carbon nanotube-magnetite composites

    SciTech Connect (OSTI)

    Marquez-Linares, F. [Institute for Physical Chemical Applied Research, School of Science, University of Turabo, PO Box 3030, Gurabo, PR 00778-3030 (Puerto Rico); Uwakweh, O.N.C. [Engineering Science and Materials Department, College of Engineering, University of Puerto Rico-Mayagueez Campus, Mayaguez, PR 00681-9044 (Puerto Rico); Lopez, N. [Chemical Engineering Department, College of Engineering, University of Puerto Rico-Mayagueez Campus, Mayaguez, PR 00681-9000 (Puerto Rico); Chavez, E. [Physics Department, University of Puerto Rico-Mayagueez Campus, Mayaguez, PR 00681-9000 (Puerto Rico); Polanco, R. [Institute for Physical Chemical Applied Research, School of Science, University of Turabo, PO Box 3030, Gurabo, PR 00778-3030 (Puerto Rico); Morant, C.; Sanz, J.M.; Elizalde, E. [Department of Applied Physics, C-XII, Universidad Autonoma de Madrid, Cantoblanco, 28049-Madrid (Spain); Neira, C.; Nieto, S. [Institute for Physical Chemical Applied Research, School of Science, University of Turabo, PO Box 3030, Gurabo, PR 00778-3030 (Puerto Rico); Roque-Malherbe, R., E-mail: RRoque@suagm.ed [Institute for Physical Chemical Applied Research, School of Science, University of Turabo, PO Box 3030, Gurabo, PR 00778-3030 (Puerto Rico)

    2011-03-15T23:59:59.000Z

    The study of the morphologies of the single walled carbon nanotube (SWCNT), magnetite nanoparticles (MNP), and the composite based on them was carried with combined X-ray diffraction (XRD), Raman spectroscopy (RS), scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopy (HRTEM). These techniques together with thermogravimetric analyses (TGA) and diffuse reflectance infrared transform spectroscopy (DRIFTS) confirmed the production of pure single phases, and that the composite material consisted of MNP attached to the outer surface of the SWCNT. The Moessbauer spectroscopy (MS) research showed the presence of a large quantity of Lewis acid sites in the highly dispersed magnetite particles supported on the SWCNT outer surface. The DRIFTS carbon dioxide adsorption study of the composites revealed significant adsorption of carbon dioxide, fundamentally in the Lewis acid sites. Then, the Lewis acid sites were observed to be catalytically active. Further, the electron exchange between the Lewis acid sites and the basic or amphoteric adsorbed molecules could influence the magnetic properties of the magnetite. Consequently, together with this first ever use of MS in the study of Lewis acid sites, this investigation revealed the potential of the composites for catalytic and sensors applications. -- Graphical abstract: A large amount of Lewis acid sites were found in the highly dispersed magnetite which is supported on the SWCNT outer surface. Display Omitted Research highlights: {yields} The obtained materials were completely characterized with XRD, Raman and SEM-TEM. {yields} DRIFT, TGA and adsorption of the composites allowed understand the material formation. {yields} This is the first report of a study of Lewis sites by Moessbauer spectroscopy.

  3. Preparation, characterization, surface chemistry, and corrosion properties of Ni-TM-P alloys produced by autocatalytic reduction

    SciTech Connect (OSTI)

    Mendoza Gonzalez, O.

    1991-01-01T23:59:59.000Z

    Autocatalytic or electroless deposition of Ni-P film alloys was reviewed and considered as a model for the deposition of ternary alloys such as Ni-TM-P where TM is W-Mo and Cr. This study is a comprehensive analysis of the parameters that influence each one of the steps involved in a successful deposition. It starts in the preparation of the substrate to be plated; special attention is given to the mechanical polishing, degreasing and chemical activation. The degree of cleanliness provides the film's quality of adherence. The bath's chemical composition is explained in terms of the role played by each of the bath components such as Ni and P, complexing agents, buffers, stabilizers and other additives. The characterization of the autocatalytic film was done from the structural, chemical-composition, and surface-chemistry perspectives. Chemical and electrochemical mechanisms of autocatalytic deposition of Ni-TM-P and chemical kinetics were studied. Results show that the deposition of Ni-W-P is mostly a chemical mechanism; deposition of Ni-Mo-P is governed by both chemical and electrochemical mechanisms; and Ni-Cr-P deposition is only possible when the process is controlled by an electrochemical mechanism. Corrosion results show that structure or chemical composition alone are not sufficient to provide excellent corrosion-resistant properties for electroless films.

  4. Analysis Of Post-Wet-Chemistry Heat Treatment Effects On Nb SRF Surface Resistance

    SciTech Connect (OSTI)

    Dhakal, Pashupati; Ciovati, Gianluigi; Kneisel, Peter K.; Myneni, Ganapati Rao

    2014-02-01T23:59:59.000Z

    Most of the current research in superconducting radio frequency (SRF) cavities is focused on ways to reduce the construction and operating cost of SRF-based accelerators as well as on the development of new or improved cavity processing techniques. The increase in quality factors is the result of the reduction of the surface resistance of the materials. A recent test on a 1.5 GHz single cell cavity made from ingot niobium of medium purity and heat treated at 1400 deg C in a ultra-high vacuum induction furnace resulted in a residual resistance of ~ 1n{Omega} and a quality factor at 2.0 K increasing with field up to ~ 510{sup 10} at a peak magnetic field of 90 mT. In this contribution, we present some results on the investigation of the origin of the extended Q{sub 0}-increase, obtained by multiple HF rinses, oxypolishing and heat treatment of ?all Nb? cavities.

  5. Browse by Discipline -- E-print Network Subject Pathways: Chemistry --

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  12. Investigation of IAQ-Relevant Surface Chemistry and Emissions on HVAC Filter Materials

    SciTech Connect (OSTI)

    Destaillats, Hugo; Fisk, William J.

    2010-02-01T23:59:59.000Z

    Chemical reactions involving ozone of outdoor origin and indoor materials are known to be significant sources of formaldehyde and other irritant gas-phase oxidation products in the indoor environment. HVAC filters are exposed to particularly high ozone concentrations--close to outdoor levels. In this study, we investigated chemical processes taking place on the surface of filters that included fiberglass, polyester, cotton/polyester blend and synthetic (e.g., polyolefin) filter media. Ozone reactions were studied on unused filter media, and on filters that were deployed for 3 months in two different locations: at the Lawrence Berkeley National Laboratory and at the Port of Oakland. Specimens from each filter were exposed to ozone under controlled conditions in a laboratory flow tube at a constant flow of dry or humidified air (50percent relative humidity). Ozone was generated with a UV source upstream of the flow tube, and monitored using a photometric detector. Ozone breakthrough curves were recorded for each sample exposed to ~;;150 ppbv O3 for periods of ~;;1000 min, from which we estimated their uptake rate. Most experiments were performed at 1.3 L/min (corresponding to a face velocity of 0.013 m/s), except for a few tests performed at a higher airflow rate, to obtain a face velocity of 0.093 m/s, slightly closer to HVAC operation conditions. Formaldehyde and acetaldehyde, two oxidation byproducts, were collected downstream of the filter and quantified. Emissions of these volatile aldehydes were consistently higher under humidified air than under dry conditions, at which levels were near the limit of detection. Our results confirm that there are significant reactions of ozone as air containing ozone flows through HVAC filters, particularly when the filters are loaded with particles and the air is humidified. The amount of ozone reacted was not clearly related to the types of filter media, e.g., fiberglass versus synthetic. Specific fiberglass filters that were coated with an impaction oil showed significantly higher formaldehyde emissions than most other samples. Those emissions were magnified in the presence of particles (i.e., in used filters), and were observed even in the absence of ozone, which suggests that hydrolysis of filter binder or tackifier additives may be the reason for those high emissions. Mass balance calculations indicate that the emission rates of formaldehyde and acetaldehyde from the filters are generally not large enough to substantially increase indoor formaldehyde or acetaldehyde concentrations.

  13. Are We Closing the School Discipline Gap?

    E-Print Network [OSTI]

    Losen, Daniel; Hodson, Cheri; Keith II, Michael A; Morrison, Katrina; Belway, Shakti

    2015-01-01T23:59:59.000Z

    D.J. , (Ed). Closing the School Discipline Gap: EquitableBooth, E.A. (2011). Breaking schools rules: A statewidestudy of how school discipline relates to students success

  14. 148 Chemistry/Chinese Chemistry 347 (3)--Advanced Organic Chemistry

    E-Print Network [OSTI]

    Dresden, Gregory

    148 Chemistry/Chinese Chemistry 347 (3)--Advanced Organic Chemistry Prerequisite: Chemistry 242,syntheticmethodology,mod- ernsyntheticreactions,protectinggroups,naturalprod- uctssynthesis,andcombinatorialchemistry.France. Spring Chemistry 350 (3)--Advanced Inorganic Chemistry Prerequisites: Chemistry 250, 252, and 262. Anintro

  15. Atmospheric Chemistry

    E-Print Network [OSTI]

    Finlayson-Pitts, B. J

    2010-01-01T23:59:59.000Z

    in our understanding of important chemistry and highlightedin our knowledge. In summary, the chemistry occurring in theBJ, Pitts JN, Jr (2000) Chemistry of the Upper and Lower

  16. CLUSTER CHEMISTRY

    E-Print Network [OSTI]

    Muetterties, Earl L.

    2013-01-01T23:59:59.000Z

    Advanced Inorganic Chemistry, 11 Wiley Huetterties and C. M.Submitted to the Journal of Organometallic ChemistryCLUSTER CHEMISTRY Earl L. Muetterties TWO-WEEK LOAN COPY May

  17. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01T23:59:59.000Z

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  18. Chemistry on the Edge: A Microscopic Analysis of the Intercalation, Exfoliation, Edge Functionalization, and Monolayer Surface Tiling

    E-Print Network [OSTI]

    Chemistry on the Edge: A Microscopic Analysis of the Intercalation, Exfoliation, EdgeVed May 29, 1998 Abstract: The intercalation and exfoliation reactions of R-zirconium phosphate, Zr(HPO4-assembled aperiodic multilayers.3 The exfoliation of clays, alkali transition metal oxides, metal phosphates, graphite

  19. NERSC HPSS Storage by Scientific Discipline

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage by Scientific Discipline Troubleshooting IO Resources for Scientific Applications at NERSC Optimizing IO performance on the Lustre file system IO Formats Science...

  20. The Puzzle of Discipline: An Examination of African American Disproportionality in School Discipline and Student Performance

    E-Print Network [OSTI]

    Butler, Bettie Ray

    2012-07-16T23:59:59.000Z

    The intent of this study was to systematically investigate the relationship between African American disproportionality in school discipline which is the overrepresentation of students for exclusionary discipline practices (i.e., out-of-school...

  1. Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} synthesized using a chelating route for use in IT-SOFC cathodes: Microstructure, surface chemistry and electrical conductivity

    SciTech Connect (OSTI)

    Scurtu, Rares [IlieMurgulescu Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania); Romania National Institute for Research and Development in Microtechnologies(IMT), 023573 Bucharest (Romania); Somacescu, Simona, E-mail: ssimona@icf.ro [IlieMurgulescu Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania); Calderon-Moreno, Jose Maria; Culita, Daniela [IlieMurgulescu Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania); Bulimestru, Ion; Popa, Nelea; Gulea, Aurelian [Faculty of Chemistry and Chemical Technology State University of Moldova 60 Mateevici, Chisinau MD 2009 Republic of Moldova (Moldova, Republic of); Osiceanu, Petre [IlieMurgulescu Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania)

    2014-02-15T23:59:59.000Z

    Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} powders were synthesized by a chelating route using different polyfunctional H{sub x}APC acids (APC=aminopolycarboxylate; x=3, 4, 5). Different homologous aminopolycarboxylic acids, namely nitrilotriacetic (H{sub 3}nta), ethylenediaminetetraacetic (H{sub 4}edta), 1,2-cyclohexanediaminetetracetic (H{sub 4}cdta) and diethylenetriaminepentaacetic (H{sub 5}dtpa) acid, were used as chelating agents to combine Sm, Sr, Co elements into a perovskite structure. The effects of the chelating agents on the crystalline structure, porosity, surface chemistry and electrical properties were investigated. The electrical properties of the perovskite-type materials emphasized that their conductivities in the temperature range of interest (600800 C) depend on the nature of the precursors as well as on the presence of a residual Co oxide phase as shown by XRD and XPS analysis. The surface chemistry and the surface stoichiometries were determined by XPS revealing a complex chemical behavior of Sr that exhibits a peculiar surface phase and bulk phase chemistry within the detected volume (<10 nm). - Graphical abstract: Synthesis of nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} powders by a chelating route and the investigation of the microstructure, surface chemistry and electrical properties. Display Omitted - Highlights: Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} obtained by a chelating synthesis route. Cubic perovskite structures with crystallite sizes ?232 nm. The porous nature revealed by N{sub 2} adsorption/desorption (BET). The surface chemistry and the surface stoichiometries highlighted by XPS. A complex chemical behavior of Sr exhibits a peculiar surface phase and bulk phase chemistry.

  2. Software Engineering, an established Accreditable Engineering Discipline

    E-Print Network [OSTI]

    Szabados, Barna

    Software Engineering, an established Accreditable Engineering Discipline By B.Szabados, P.Eng, Mc of the Canadian Engineering Accreditation Board (CEAB), as well as at a workshop at the NCDEAS meeting in September 1997. 1. INTRODUCTION In the late seventies, the discipline of Computer Engineering has evolved

  3. Environmental Chemistry II (Atmospheric Chemistry)

    E-Print Network [OSTI]

    Dibble, Theodore

    SYLLABUS FOR Environmental Chemistry II (Atmospheric Chemistry) FCH 511 Fall 2013 Theodore S/explaining the trends in J as a function of altitude and solar zenith angle. The second involves analyzing real

  4. Balance of chemistry, topography, and mechanics at the cellbiomaterial interface: Issues and challenges for

    E-Print Network [OSTI]

    of creating surfaces with well-defined chemistry and topography combined with sensitive surface. Keywords: Surface tension; Adhesion; Surface structure, morphology, roughness, and topography; Atomic force- face chemistry, topography, or mechanics of the substrate). The surface scientist is already quite

  5. SYNTHESIS AND SURFACE CHEMISTRY OF ZN3P2 Gregory M. Kimball, Nathan S. Lewis, Harry A. Atwater

    E-Print Network [OSTI]

    Kimball, Gregory

    alternative to traditional materials (e.g. CIGS, CdTe, a-Si) for thin film photovoltaics. Open circuit voltage in Zn3P2 cells has been limited by Fermi-level pinning due to surfaces states and heterojunction promise for solar energy conversion but has not been investigated as thoroughly as other thin film

  6. The influence of simplified peroxy radical chemistry on the interpretation of NO2NOO3 surface exchange

    E-Print Network [OSTI]

    Heal, Mathew R

    2001-01-01T23:59:59.000Z

    Reactions of NO with peroxy radicals XO2 (=HO2+RO2) are shown to be the most important chemical reactions causing flux divergence of NO2 and NO close to the surface, in addition to the "NOxO3 only" reactions of ...

  7. Thermal chemistry of Mn{sub 2}(CO){sub 10} during deposition of thin manganese films on silicon oxide and on copper surfaces

    SciTech Connect (OSTI)

    Qin Xiangdong; Sun Huaxing; Zaera, Francisco [Department of Chemistry, University of California, Riverside, California 92521 (United States)

    2012-01-15T23:59:59.000Z

    The surface chemistry of dimanganese decacarbonyl on the native oxide of Si(100) wafers was characterized with the aid of x-ray photoelectron spectroscopy. Initial experiments in a small stainless-steel reactor identified a narrow range of temperatures, between approximately 445 and 465 K, in which the deposition of manganese could be achieved in a self-limiting fashion, as is desirable for atomic layer deposition. Deposition at higher temperatures leads to multilayer growth, but the extent of this Mn deposition reverses at even higher temperatures (about 625 K), and also ifhydrogen is added to the reaction mixture. Extensive decarbonylation takes place below room temperature, but limited C-O bond dissociation and carbon deposition are still seen after high exposures at 625 K. The films deposited at low ({approx}450 K) temperatures are mostly in the form of MnO, but at 625 K that converts to a manganese silicate, and upon higher doses a manganese silicide forms at the SiO{sub 2}/Si(100) interface as well. No metallic manganese could be deposited with this precursor on either silicon dioxide or copper surfaces.

  8. Organophosphorus chemistry

    E-Print Network [OSTI]

    Hanson, Paul R.

    2014-09-04T23:59:59.000Z

    2087 Organophosphorus chemistry Paul R. Hanson Editorial Open Access Address: Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS 66045-7582, USA Email: Paul R. Hanson - phanson@ku.edu. Keywords: organophosphorus... Beilstein J. Org. Chem. 2014, 10, 20872088. doi:10.3762/bjoc.10.217 Received: 28 July 2014 Accepted: 06 August 2014 Published: 04 September 2014 This article is part of the Thematic Series "Organophosphorus chemistry" Guest Editor: P. R. Hanson 2014...

  9. Physical Chemistry Position Description The chemistry department at the Rochester Institute of Technology invites applications

    E-Print Network [OSTI]

    Zanibbi, Richard

    for application in chemically-based energy generation or energy storage or organic photovoltaics. Disciplines, conductive metal oxides, material degradation and reliability testing, solid state chemistry, physical (NPRL), spanning 10,000 square feet, is equipped with state of the art photovoltaic processing

  10. The effects of surface chemistry of mesoporous silica materials and solution pH on kinetics of molsidomine adsorption

    SciTech Connect (OSTI)

    Dolinina, E.S.; Parfenyuk, E.V., E-mail: terrakott37@mail.ru

    2014-01-15T23:59:59.000Z

    Adsorption kinetics of molsidomine on mesoporous silica material (UMS), the phenyl- (PhMS) and mercaptopropyl-functionalized (MMS) derivatives from solution with different pH and 298 K was studied. The adsorption kinetics was found to follow the pseudo-second-order kinetic model for all studied silica materials and pH. Effects of surface functional groups and pH on adsorption efficiency and kinetic adsorption parameters were investigated. At all studied pH, the highest molsidomine amount is adsorbed on PhMS due to ?? interactions and hydrogen bonding between surface groups of PhMS and molsidomine molecules. An increase of pH results in a decrease of the amounts of adsorbed molsidomine onto the silica materials. Furthermore, the highest adsorption rate kinetically evaluated using a pseudo-second-order model, is observed onto UMS and it strongly depends on pH. The mechanism of the adsorption process was determined from the intraparticle diffusion and Boyd kinetic filmdiffusion models. The results showed that the molsidomine adsorption on the silica materials is controlled by film diffusion. Effect of pH on the diffusion parameters is discussed. - Graphical abstract: The kinetic study showed that the k{sub 2} value, the rate constant of pseudo-second order kinetic model, is the highest for molsidomine adsorption on UMS and strongly depends on pH because it is determined by availability and accessibility of the reaction sites of the adsorbents molsidomine binding. Display Omitted - Highlights: The adsorption capacities of UMS, PhMS and MMS were dependent on the pH. At all studied pH, the highest molsidomine amount is adsorbed on PhMS. The highest adsorption rate, k{sub 2}, is observed onto UMS and strongly depends on pH. Film diffusion was the likely rate-limiting step in the adsorption process.

  11. Reactive Surfaces and Interfaces utilizing 2-Vinyl-4,4-Dimethylazlactone (VDMA): An Example of ??Click?? Chemistry

    SciTech Connect (OSTI)

    Messman, Jamie M [ORNL; Kilbey, II, S Michael [ORNL; Lokitz, Bradley S [ORNL; Hinestrosa Salazar, Juan Pablo [Clemson University; Ankner, John Francis [ORNL

    2009-01-01T23:59:59.000Z

    Creating polymer-modified interfaces decorated with biologically-relevant materials V so-called bio-interfaces V with precise control over the nanoscale structure and properties is of increasing technological importance for a large number of advanced materials applications, including adaptive and/or lubricious biomaterial coatings, electro-actuators (synthetic muscles), biosensors with amplified response, coatings for stealth drug delivery, supports for enzymatic catalysts, protein or antibody arrays, and high affinity separation agents. The ability to design and decorate interfaces with biologically-relevant molecules and understand synthesis-structure-function relationships remains a significant challenge. The overarching objective of this research program is to investigate the polymerization and functionalization of a new class of polymeric materials that are capable of serving as a versatile platform from which bio-interfaces for specific applications can be created and evaluated. Stimuli-responsive (co)polymers containing vinyl dimethyl azlactone (VDMA) have been prepared using free radical polymerization techniques (controlled and conventional). Subsequent immobilization of biomolecules (e.g., dansylcadaverine, N ,N -bis(carboxymethyl)-L-lysine hydrate) on PVDMA-containing surface scaffolds affords bio-interfaces. Reaction of nucleophiles with the azlactone moiety proceeds rapidly, quantitatively, and in the absence of byproducts, which are essential criteria governing the click-type nature of this procedure. The conversion of these materials into polyelectrolytes and bioconjugates can be monitored in real-time using infrared spectroscopy. Additionally, pVDMA polymers prepared using reversible addition fragmentation chain transfer (RAFT) polymerization are the basis for creating polymer brushes by a grafting to approach. We will describe how compositional differences and changes in molecular weight affect the solubility and responsiveness of pVDMA-based polymers and surface layers when functionalized with various biomolecules.

  12. STATE OF THE DISCIPLINE POVERTY, RACE, AND

    E-Print Network [OSTI]

    Shyy, Wei

    STATE OF THE DISCIPLINE POVERTY, RACE, AND ANTIPOVERTY POLICY BEFORE AND AFTER HURRICANE KATRINA1 response toward those affected, it did not lead to a serious discourse about the nature of poverty earnings are lower and poverty rates are higher for African Americans than for Whites, the economic

  13. Behaviors That Result in Employee Discipline

    E-Print Network [OSTI]

    Oliver, Douglas L.

    would much rather you be productive and happy on the job. Most employers have resources to help is not punishment. The goal of discipline is to deter a re- peat of the performance problem (quality of work your concerns confidentially with an employee assistance professional can help. Human resources is also

  14. DISCIPLINE OF RADIATION THERAPY SAFETY DOCUMENT

    E-Print Network [OSTI]

    O'Mahony, Donal E.

    DISCIPLINE OF RADIATION THERAPY SAFETY DOCUMENT Contents Page 1. Health & Safety arrangements 1 Inspection 1.4 Hazard Reporting 1.5 Security in College 1.6 Out of Hours Working 1.7 Management of Work.7 Management of Work-related Stress Those experiencing symptoms of work-related stress should raise this matter

  15. Surfaces

    E-Print Network [OSTI]

    DeMaio, Ernest Vincent, 1964-

    1989-01-01T23:59:59.000Z

    Surfaces is a collection of four individual essays which focus on the characteristics and tactile qualities of surfaces within a variety of perceived landscapes. Each essay concentrates on a unique surface theme and purpose; ...

  16. DISCIPLINE AND TERMINATION POLICY Employees covered by this policy

    E-Print Network [OSTI]

    DISCIPLINE AND TERMINATION POLICY Employees covered by this policy This policy applies to all non to discipline, suspend with or without pay, or terminate employees for just cause. Just cause includes to discipline or termination for just cause, the University reserves the right to demote, suspend or terminate

  17. This journal is The Royal Society of Chemistry [year] [journal], [year], [vol], 0000 | 1 Droplet mobility on lubricant-impregnated surfaces

    E-Print Network [OSTI]

    , the surrounding gas, and the liquid that needs to be shed referred hereafter for simplicity as oil, airThis journal is The Royal Society of Chemistry [year] [journal], [year], [vol], 0000 | 1 Droplet

  18. Position: Assistant Professor of Chemistry, Physical Chemistry

    E-Print Network [OSTI]

    John Grey Position: Assistant Professor of Chemistry, Physical Chemistry Email: jkgrey@unm.edu Phone: 505.277.1658; Fax: 505.277.2609 Office: Clark Hall B70 Homepage: http://chemistry.unm.edu/faculty_web/jgrey Education B.S. in Chemistry, 1999, Michigan Technological University, Houghton, MI Ph.D. in Chemistry

  19. Green Chemistry and Workers

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    J. Warner. 1998. Green Chemistry: Theory and Practice. NewNew Science, Green Chemistry and Environmental Health.abstract.html 5. American Chemistry Council. 2003. Guide to

  20. UCLA CHEMISTRY & BIOCHEMISTRY

    E-Print Network [OSTI]

    Levine, Alex J.

    UCLA CHEMISTRY & BIOCHEMISTRY ORIENTATION HANDBOOK 2012-2013 #12;Table of Contents Introduction .............................................................................................................................................2 Chemistry & Biochemistry Undergraduate Office ..................................................................................................3 Majors in Chemistry

  1. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973 1 IntroductionActinide Chemistry Actinide chemistry

  2. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology and imple- #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  3. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Using Combined Snowpack and

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture, BCMOF 1 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  4. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  5. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS

  6. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note

  7. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Assessing Habitat Quality of

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS

  8. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Relationships between Elevation and Slope

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  9. Chemistry 106X -Fall 2010 General Chemistry

    E-Print Network [OSTI]

    Wagner, Diane

    Chemistry 106X - Fall 2010 General Chemistry Instructor: Christopher Iceman Class: MWF 9 bookstore or elsewhere: Chemistry and Chemical Reactivity 7th Ed. by Kotz, Treichel, and Townsend-0-495-38703-9 Electronic Book - ISBN 978-0-495-68043-7 OWL pin number for Chemistry and Chemical Reactivity 7th Ed. (1

  10. Chemistry 411/611 Inorganic Chemistry (2011)

    E-Print Network [OSTI]

    Mather, Patrick T.

    2011-01-01T23:59:59.000Z

    1 Chemistry 411/611 Inorganic Chemistry (2011) Instructor: Assistant Professor Mathew M. Maye Chemistry", 5th Edition, Freeman Press. Available at SU bookstore. The solution manual is optional. (Suggested for CHE611 Students pursuing Inorganic) Huheey, "Inorganic Chemistry: Principles of Structure

  11. Chemistry 106X -Spring 2011 General Chemistry

    E-Print Network [OSTI]

    Wagner, Diane

    Chemistry 106X - Spring 2011 General Chemistry Instructor: Christopher Iceman Class: MWF 1 and can be purchased in the UAF bookstore or elsewhere: Chemistry and Chemical Reactivity 7th Ed for Chemistry and Chemical Reactivity 7th Ed. (1 or 2 semester) TurningPoint Technologies ResponseCard RF

  12. 2011 Organometallic Chemistry (July 10-15, 2011, Salve Regina University, Newport, RI)

    SciTech Connect (OSTI)

    Dr. Emilio Bunel

    2011-07-15T23:59:59.000Z

    Organometallic chemistry has played and will continue to play a significant role in helping us understand the way bonds are made or broken in the presence of a transition metal complex. Current challenges range from the efficient exploitation of energy resources to the creative use of natural and artificial enzymes. Most of the new advances in the area are due to our extended understanding of processes at a molecular level due to new mechanistic studies, techniques to detect reaction intermediates and theory. The conference will bring the most recent advances in the field including nanocatalysis, surface organometallic chemistry, characterization techniques, new chemical reactivity and theoretical approaches along with applications to organic synthesis and the discovery of new materials. The Conference will bring together a collection of investigators who are at the forefront of their field, and will provide opportunities for junior scientists and graduate students to present their work in poster format and exchange ideas with leaders in the field. Six outstanding posters will be selected for short talks. The collegial atmosphere of this Conference, with programmed discussion sessions as well as opportunities for informal gatherings in the afternoons and evenings, provides an avenue for scientists from different disciplines to brainstorm and promotes cross-disciplinary collaborations in the various research areas represented. Graduate students and postdoctoral fellows should also consider participating in the Gordon Research Seminar on Organometallic Chemistry (July 9-10, same location) which is specially designed to promote interaction and discussion between junior scientists.

  13. DRAFT - DOE O 333.1, Administering Work Force Discipline

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    To provide requirements and responsibilities for administering workforce discipline that includes disciplinary, adverse, and alternative corrective actions in the Department of Energy (DOE).

  14. School of Chemistry CHEM3100: Chemistry at a Molecular Level

    E-Print Network [OSTI]

    Rzepa, Henry S.

    School of Chemistry CHEM3100: Chemistry at a Molecular Level Tutorial Groups 2013/14 Name Programme Tutor Ahmed, Zacher Medicinal Chemistry Arif, Saboor Chemistry Bagnall, Samuel Chemistry Barbara, David Chemistry Beaumont, Nicholas Chemistry Quinn, Michael J Chemistry Bennett, Matthew Chemistry Booth, Natalie

  15. CHEMISTRY CURRICULUM SEMESTER I

    E-Print Network [OSTI]

    Srinivasan, N.

    CHEMISTRY CURRICULUM SEMESTER ­ I Chemistry-I: Physical principles (2:1) Atomic structure-state approximation, Arrhenius equation and collision theory and catalysis. SEMESTER ­ II Chemistry-II: Structure orbital theory: polyatomic molecules - Walsh diagram; Main group chemistry: periodic properties, chemistry

  16. Cycle time variability for a network under two queueing disciplines

    E-Print Network [OSTI]

    Vasquez Pariente, Marta Irene

    1996-01-01T23:59:59.000Z

    A network of three single-server queues is investigated. Performance of two queueing disciplines is compared on the basis of the mean and variance of the network cycle time. The two queueing disciplines are first-in-system first-out (FISFO...

  17. Supramolecular Chemistry DOI: 10.1002/anie.200905460

    E-Print Network [OSTI]

    Angewandte Chemie Supramolecular Chemistry DOI: 10.1002/anie.200905460 Porous Capsules {(M)M5}12FeIII 30 (M = MoVI , WVI ): Sphere Surface Supramolecular Chemistry with 20 Ammonium Ions, Related Solution materials scientific aspects;[1] for general aspects of the chemistry, see referen- ces [13d

  18. Green Chemistry and Workers

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    19. P. Anastas, J. Warner. 1998. Green Chemistry: Theory andto Advance New Science, Green Chemistry and EnvironmentalChronicle Extra: Guide to Green Jobs. Field with a Future.

  19. Chemistry Division: Annual progress report for period ending March 31, 1987

    SciTech Connect (OSTI)

    Not Available

    1987-08-01T23:59:59.000Z

    This report is divided into the following sections: coal chemistry; aqueous chemistry at high temperatures and pressures; geochemistry of crustal processes to high temperatures and pressures; chemistry of advanced inorganic materials; structure and dynamics of advanced polymeric materials; chemistry of transuranium elements and compounds; separations chemistry; reactions and catalysis in molten salts; surface science related to heterogeneous catalysis; electron spectroscopy; chemistry related to nuclear waste disposal; computational modeling of security document printing; and special topics. (DLC)

  20. Department of Chemistry "Supramolecular Chemistry in Polymeric

    E-Print Network [OSTI]

    Mark, James E.

    Department of Chemistry "Supramolecular Chemistry in Polymeric Systems: From Nanoassemblies to Dynamic Materials" Presented by: Professor Stuart J. Rowan Case Western Reserve University Departmental Colloquium Friday, May 15, 2009 3:00 p.m. 502 Rieveschl #12;Supramolecular Chemistry in Polymeric Systems

  1. Chemistry 411/611 Inorganic Chemistry (2010)

    E-Print Network [OSTI]

    Mather, Patrick T.

    2010-01-01T23:59:59.000Z

    -ligand reactivity, and the chemical synthesis of coordination compounds and other "solid" state materials 1 Chemistry 411/611 Inorganic Chemistry (2010) Instructor: Assistant Professor Mathew M. Maye: M-W 4:00-5:00, and by appointment Credits: 3 Text: (Required) Shriver & Atkins, "Inorganic Chemistry

  2. FACULTY POSITION IN INORGANIC CHEMISTRY Department of Chemistry

    E-Print Network [OSTI]

    Doyle, Robert

    FACULTY POSITION IN INORGANIC CHEMISTRY Department of Chemistry Syracuse University The Department of Chemistry at Syracuse University invites applications for a tenure track faculty position at the Assistant Professor level in inorganic chemistry with specialization in materials chemistry (broadly defined

  3. Sem. Chemistry Materials Science Electrical Engineering Miscellaneous CP Introduction to General Chemistry,

    E-Print Network [OSTI]

    Pfeifer, Holger

    Sem. Chemistry Materials Science Electrical Engineering Miscellaneous CP Introduction to General & Inorganic Materials Chemistry (4 CP) Energy Science and Technology I (5 CP) Surfaces/Interfaces/ Heterogen. Catalysis/ Electrocatalysis (5 CP) Materials Science II (5 CP) Energy Science and Technology II ( 5 CP

  4. Electrical Engineering is a diverse discipline encompassing computer and information

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering is a diverse discipline encompassing computer and information environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Processing institute. PROGRAMS AVAILABLE Electrical Engineering

  5. Electrical Engineering is a diverse discipline encompassing computer and information

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering is a diverse discipline encompassing computer and information environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Processing institute. PROGRAMS AVAILABLE Electrical Engineering Bachelor

  6. Why chemistry? Chemistry is fundamental: it is the enabling

    E-Print Network [OSTI]

    Sussex, University of

    Chemistry Why chemistry? Chemistry is fundamental: it is the enabling science that underlies many technology. A chemistry degree gives you the understanding to contribute to our future in very topical areas) in Chemistry BSc (Hons) in Chemistry MChem (Hons) in Chemistry (with an industrial placement year) MChem (Hons

  7. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Using Airphotos to Interpret

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture March 2004 Research Section, Coast Forest Region, BCMOF 1 Research Disciplines: Ecology ~ Geology

  8. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology-748-1331. mdeact@shaw.ca #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  9. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.for.gov.bc.ca/vancouvr/research/research_index.htm #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  10. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.for.gov.bc.ca/vancouvr/research/research_index.htm #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture

  11. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology, BC, V9J 1G4 #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  12. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Rd., Black Creek, BC, V9J 1G4 #12;Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology

  13. IN-PACKAGE CHEMISTRY ABSTRACTION

    SciTech Connect (OSTI)

    E. Thomas

    2005-07-14T23:59:59.000Z

    This report was developed in accordance with the requirements in ''Technical Work Plan for Postclosure Waste Form Modeling'' (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model, which uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model, which is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials, and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed (CDSP) waste packages containing high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor diffusing into the waste package, and (2) seepage water entering the waste package as a liquid from the drift. (1) Vapor-Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H{sub 2}O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Liquid-Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package.

  14. Computational Chemistry Robots

    E-Print Network [OSTI]

    Townsend, Joseph A; Murray-Rust, Peter; Tyrrell, Simon M; Zhang, Yong

    Computational Chemistry Robots ACS Sep 2005 Computational Chemistry Robots J. A. Townsend, P. Murray-Rust, S. M. Tyrrell, Y. Zhang jat45@cam.ac.uk Can high-throughput computation provide a reliable experimental resource for molecular...

  15. Why chemistry? Chemistry is fundamental: it is the enabling science

    E-Print Network [OSTI]

    Sussex, University of

    Chemistry Why chemistry? Chemistry is fundamental: it is the enabling science that underlies many technology. A chemistry degree allows you to understand and to contribute to our future. Chemistry is challenging: understanding the very fabric of matter is both stimulating and rewarding. Studying chemistry

  16. Chemistry Division Department of Biological

    E-Print Network [OSTI]

    Heller, Barbara

    1 Chemistry Division Department of Biological and Chemical Sciences, Illinois Institute-13 Chemistry Division invites nominations for Kilpatrick Fellowship for the academic year 2012's Chemistry Department from 19471960. Mary Kilpatrick was a chemistry faculty member from 1947

  17. Chemistry and Biochemistry Scholarships

    E-Print Network [OSTI]

    Almor, Amit

    Chemistry and Biochemistry Scholarships Complete Scholarship Name Application Deadline Date Contact Endowment Fund To provide support for undergraduate biomedical research in the Department of Chemistry/or the purchase of supplies. Yes w/recommendation s from faculty Call goes out in February to all chemistry

  18. CHEMISTRY DEPARTMENT HANDBOOKFOR STUDENTS

    E-Print Network [OSTI]

    Hardy, Christopher R.

    CHEMISTRY DEPARTMENT HANDBOOKFOR STUDENTS Millersville University Millersville, Pennsylvania in the ChemistryDepartment. It brings together material not collected in other places and is not meant Resources 2 Programs in Chemistry and The General Education Curriculum Record Form 3 The Major Requirements

  19. Chemistry and Biochemistry Scholarships

    E-Print Network [OSTI]

    Almor, Amit

    Chemistry and Biochemistry Scholarships Complete Scholarship Name Application Deadline Date Contact to Chemistry and Biochemistry entering graduate students who have asked for consideration to serve as research@chem.sc.edu Hiram and Lawanda Allen Scholarship for Excellence in Chemistry This award is given to a graduating

  20. Adam Benoit Medicinal Chemistry

    E-Print Network [OSTI]

    Thomas, David D.

    #12;Adam Benoit Medicinal Chemistry Ph.D. Thesis Title: Synthesis and Evaluation of Acridine Country: United States #12;Amit Gangar Medicinal Chemistry Ph.D. Thesis Title: Design and Development Wagner Home Country: India #12;Dan Wang Medicinal Chemistry M.S. Thesis Title: Synthesis and Evaluation

  1. Organic Chemistry 51B -Winter 2013 Organic Chemistry Peer Tutoring Program Chemistry 51B Reactions List

    E-Print Network [OSTI]

    Rose, Michael R.

    Organic Chemistry 51B - Winter 2013 Organic Chemistry Peer Tutoring Program Chemistry 51B Reactions(s). Chapter 7: Nucleophilic Substitution + + NaOH CH3O- #12;Organic Chemistry 51B - Winter 2013 Organic Chemistry Peer Tutoring Program Chapter 8: Elimination Reactions #12;Organic Chemistry 51B - Winter 2013

  2. Sustainable Future Stevens students bridged disciplines to advance

    E-Print Network [OSTI]

    Yang, Eui-Hyeok

    Building a Sustainable Future Stevens students bridged disciplines to advance sustainable living which collects and analyzes data to preserve energy and teach occupants to live more sustainably of our sustainable future. 4stevens.edu/ecohabit (1) Ecohabit was the only competition house that used

  3. Towards a Discipline of Geospatial Distributed Event Based Systems

    E-Print Network [OSTI]

    Heaton, Thomas H.

    Towards a Discipline of Geospatial Distributed Event Based Systems Annie Liu Computer Science, Caltech 1200 E California Blvd Pasadena, CA 91125, USA mani@cms.caltech.edu ABSTRACT A geospatial system is one in which the state space in- cludes one, two or three-dimensional space and time. A geospatial

  4. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Hudson and Axel Anderson KEYWORDS: Water management, Coastal watersheds, hydrological modeling CITATIONPractice. ResearchSection,Coast ForestRegion, BCMOF,Nanaimo, BC. Extension Note EN-022. EN-022 Hydrology March 2006

  5. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology,Tsitika Watershed.Research Section,CoastForest Region,BCMOF, Nanaimo, BC. Extension Note EN-021. EN-021 Hydrology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note EN-021 March 2006 Forest Research

  6. Mechanisms for fluoride-promoted dissolution of bayerite [{beta}-Al(OH){sub 3}(s)] and boehmite [{gamma}-AlOOH]: {sup 19}F-NMR spectroscopy and aqueous surface chemistry

    SciTech Connect (OSTI)

    Nordin, J.P.; Sullivan, D.J.; Phillips, B.L.; Casey, W.H.

    1999-11-01T23:59:59.000Z

    Some reactions that control the dissolution of bayerite [{beta}-Al(OH){sub 3}(s)] and boehmite [{gamma}-AlOOH] were identified by comparing the adsorption chemistry, the dissolution rates, and solid-state {sup 19}F-NMR spectra of the reacting surfaces. The {sup 19}F-NMR spectra of bayerite distinguish two sites for fluoride reaction that vary in relative concentration with the total adsorbate density. One resonance at {minus}131 ppm is assigned to fluoride bridges and the other resonance at {minus}142 ppm is assigned to fluoride at terminal sites. These same resonances are observed on boehmite, in addition to a third resonance at {minus}151 ppm that is tentatively assigned to aqueous AlF{sub n}(H{sub 2}O){sub 6{minus}n}{sup (3{minus}n)+} (aq) complexes in pores. Peak broadening due to dipolar coupling between surface fluorides at high loading indicates that these sites are in close proximity. A consistent picture of dissolution is derived by considering the {sup 19}F-NMR results, the aqueous experiments, and information derived from the studies of aqueous complexes, particularly studies of the dissociation mechanisms of aqueous multimers. Both fluoride and adsorbed proton enhance the dissolution rates via a series of pathways that may be coupled to one another, and there is a profound dependence of the rate on the concentration of adsorbed protons and adsorbed fluorides. Particularly important are fluoride-substituted bridges and sites where aluminum atoms are bonded to several terminal fluorides or hydroxyls. These results illustrate that it is possible to test hypotheses about molecular-scale processes if adsorption studies are coupled to spectroscopy and ligand-promoted dissolution experiments where reaction via different pathways can be distinguished.

  7. TCD-IISc Symposium "Chemistry & Chemical Biology"

    E-Print Network [OSTI]

    O'Mahony, Donal E.

    actinide chemistry, with a focus on coordination and organometallic uranium chemistry. Paula ColavitaTCD-IISc Symposium "Chemistry & Chemical Biology" Trinity College Clive Williams, Dean of Chemistry. Research areas include supramolecular organic and inorganic chemistry and medicinal chemistry

  8. Department of Chemistry and Biochemistry CBF Enrichment Program The Department of Chemistry and Biochemistry student community has enthusiastically participated

    E-Print Network [OSTI]

    Sze, Lawrence

    purchased with CBF funds are: 1: Students using the FT-IR in lab Organic Chemistry · GC-mass spectrometer in the evenings and on weekends. Equipment for Instructional Labs and Undergraduate Research Requests and Analytical Chemistry · Surface tensiometer · Atomic absorption spectrometer · Benchtop FT-NMR · Bomb

  9. CHEM 4170, Medicinal Chemistry University of Missouri

    E-Print Network [OSTI]

    Gates, Kent. S.

    CHEM 4170, Medicinal Chemistry University of Missouri Computer Graphics Visualization of Proteins "pockets" or "clefts" on the surface of their macromolecular targets. A favorable free energy of binding the best way to visualize these structures is using computer graphics. In this assignment, we will use

  10. For immediate release --October 1, 2014 New media practices converge across disciplines

    E-Print Network [OSTI]

    Hossain, Shahadat

    For immediate release -- October 1, 2014 New media practices converge across disciplines Students entering the field of new media might not be aware of all the ways new media tools are being used across disciplines

  11. CHEMISTRY 450 Spring, 2009

    E-Print Network [OSTI]

    Stuart, Steven J.

    CHEMISTRY 450 Spring, 2009 Gautam Bhattacharyya, 363 Hunter Labs, phone: 656-1356 gautamb. This course does NOT have a separate laboratory meeting time. Course Goals CH 450 is the Chemistry Capstone to change. #12;CH 450 Spring, 2009 -2- Course Outline (Tentative) Journal due dates are designated each week

  12. Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Technical Report Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS SUMMARY

  13. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Biology, Ecology, and Management

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS ABSTRACT

  14. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Extension Note EN-007

  15. Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture Systems ~ Wildlife Silvicultural Treatments for Enhancing

    E-Print Network [OSTI]

    Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife CONTENTS EXECUTIVE SUMMARY

  16. Marquette University Department of Chemistry

    E-Print Network [OSTI]

    Reid, Scott A.

    Analysis Inorganic Chemistry Lecture Inorganic Synthesis Lab #12;Our Curriculum Physical Chemistry Lecture.... Directly influence the lives of others? Develop new materials with enhanced flame- retardant properties

  17. CHEMISTRY 1010 CHEMISTRY, HUMANITY AND ENVIRONMENT

    E-Print Network [OSTI]

    Simons, Jack

    day to add classes, select C/NC option or to audit a class is Jan. 23. 3. The last day to withdraw. The University of Utah seeks to provide equal access to its programs, services and activities for people: Chemistry 1010 aims to promote understanding of the basic environmental ingredients, energy, atoms

  18. Surface Chemistry in Tribology Andrew J. Gellman

    E-Print Network [OSTI]

    Gellman, Andrew J.

    in operation under the most extreme of tribological conditions. Understanding boundary lubrication, however higher than under hydrodynamic lubrication conditions. This is the regime of "boundary lubrication by the need for improved lubricants for new machines developed in the first few decades of the century

  19. THE COORDINATION CHEMISTRY OF METAL SURFACES

    E-Print Network [OSTI]

    Muetterties, Earl L.

    2013-01-01T23:59:59.000Z

    of methyl isocyanide, acetonitrile 1 benzene and toluene.desorb from tn1s sur f ace. 11 Acetonitrile forms an orderedNi(.l00) respectively. Acetonitrile thermal desorption from

  20. An extensive analysis of modified nanotube surfaces for next-generation orthopedic implants

    E-Print Network [OSTI]

    Frandsen, Christine Jeanette

    2012-01-01T23:59:59.000Z

    Effects of titanium surface topography on bone integration:influence of surface chemistry and topography on the contactstiffness). Biomaterial surface topographies that have been

  1. Structure, chemistry, and properties of mineral nanoparticles

    SciTech Connect (OSTI)

    Waychunas, G.A.; Zhang, H.; Gilbert, B.

    2008-12-02T23:59:59.000Z

    Nanoparticle properties can depart markedly from their bulk analog materials, including large differences in chemical reactivity, molecular and electronic structure, and mechanical behavior. The greatest changes are expected at the smallest sizes, e.g. 10 nm and below, where surface effects are expected to dominate bonding, shape and energy considerations. The precise chemistry at nanoparticle interfaces can have a profound effect on structure, phase transformations, strain, and reactivity. Certain phases may exist only as nanoparticles, requiring transformations in chemistry, stoichiometry and structure with evolution to larger sizes. In general, mineralogical nanoparticles have been little studied.

  2. National Chemistry Week Theme: "Candy: The Sweet Side of Chemistry"

    E-Print Network [OSTI]

    Stephens, Jacqueline

    National Chemistry Week Theme: "Candy: The Sweet Side of Chemistry" Super Science Saturday Saturday-on chemistry and science demonstrations! All students & families are welcome! Fun & educational for all ages! Sponsored by: American Chemical Society LSU Department of Chemistry LSU Athletic Department Free admission

  3. I. Required core Chemistry Courses (1905 & 1925) Chemistry

    E-Print Network [OSTI]

    Advisor: Advisee: I. Required core Chemistry Courses (1905 & 1925) Chemistry CH 111 PY 211 _____ PY 212 _____ (or PY 242 _____ or PY 252 ______) II. Chemistry Options (one required) 1905 (Concentration in Chemistry) Option A (2 advanced CH courses, 401 or higher, only one may

  4. A DISCIPLINED APPROACH TO ACCIDENT ANALYSIS DEVELOPMENT AND CONTROL SELECTION

    SciTech Connect (OSTI)

    Ortner, T; Mukesh Gupta, M

    2007-04-13T23:59:59.000Z

    The development and use of a Safety Input Review Committee (SIRC) process promotes consistent and disciplined Accident Analysis (AA) development to ensure that it accurately reflects facility design and operation; and that the credited controls are effective and implementable. Lessons learned from past efforts were reviewed and factored into the development of this new process. The implementation of the SIRC process has eliminated many of the problems previously encountered during Safety Basis (SB) document development. This process has been subsequently adopted for use by several Savannah River Site (SRS) facilities with similar results and expanded to support other analysis activities.

  5. Macromolecular Chemistry and Physics

    E-Print Network [OSTI]

    Guo, John Zhanhu

    Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710, USA E-mail: zhanhu.guo@lamar.edu Y. Li, S. Wei Department of Chemistry and Biochemistry, Lamar

  6. Macromolecular Chemistry and Physics

    E-Print Network [OSTI]

    Guo, John Zhanhu

    Engineering, Lamar University, Beaumont, TX 77710, USA E-mail: suying.wei@lamar.edu; zhanhu.guo@lamar.edu Q. He, Prof. S. Wei Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX 77710, USA

  7. Chemistry 455 Chemical Nanotechnology

    E-Print Network [OSTI]

    Rohs, Remo

    Chemistry 455 Chemical Nanotechnology 4 units Prof. Richard Brutchey, Fall 2014 (Lecture = 12:0012:50 pm MWF) CHEM 455 is an upper-division undergraduate course in Chemical Nanotechnology. The intent

  8. Ice chemistry in starless molecular cores

    E-Print Network [OSTI]

    Kalvans, Juris

    2015-01-01T23:59:59.000Z

    Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of five starless cores, with their physical conditions derived from observations. The ice chemistry of oxygen, nitrogen, sulfur, and complex organic molecules (COMs) was analyzed. We found that an ice-depth dimension, measured, e.g., in monolayers, is essential for modeling of chemistry in interstellar ices. Particularly, the H2O:CO:CO2:N2:NH3 ice abundance ratio regulates the production and destruction of minor species. It is suggested that photodesorption during core collapse period is responsible for high abundance of interstellar H2O2 and O2H, and other species synthesized on the surface. The calculated abundances of COMs in ice were compared to observed gas-phase values. Smaller activation barriers for CO and H2CO hydrogenation may help explain the production of a number of...

  9. Chemistry Student Handbook College of Science

    E-Print Network [OSTI]

    Hickman, Mark

    Chemistry Student Handbook College of Science React. Science #12;Contents 2 Welcome to the Department of Chemistry 2 Course Advice 3 What is Chemistry? 4 Career Profiles in Chemistry 5 An Undergraduate Degree in Chemistry 6 Chemistry Streams 13 Chemistry Honours Programme 14 Research

  10. Technical Report TR-014 May 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife just like Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology

  11. Chemistry at the Dirac Point of Graphene

    E-Print Network [OSTI]

    Sarkar, Santanu

    2013-01-01T23:59:59.000Z

    Haddon, R. C. Covalent Chemistry for Graphene Electronics.P. K. ; Yang, J. X. The Chemistry of Graphene. J. Mater.R. C. Organometallic Chemistry of Extended Periodic ?-

  12. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR)...

  13. Chemistry | More Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization ofChemistry and TransportChemistry of

  14. Chemistry | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry OxideChemistry Soft Matter

  15. Chemistry Division annual progress report for period ending April 30, 1993

    SciTech Connect (OSTI)

    Poutsma, M.L.; Ferris, L.M.; Mesmer, R.E.

    1993-08-01T23:59:59.000Z

    The Chemistry Division conducts basic and applied chemical research on projects important to DOE`s missions in sciences, energy technologies, advanced materials, and waste management/environmental restoration; it also conducts complementary research for other sponsors. The research are arranged according to: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, chemistry of advanced inorganic materials, structure and dynamics of advanced polymeric materials, chemistry of transuranium elements and compounds, chemical and structural principles in solvent extraction, surface science related to heterogeneous catalysis, photolytic transformations of hazardous organics, DNA sequencing and mapping, and special topics.

  16. Inorganic Chemistry Solutions to Semiconductor Nanocrystal Problems

    SciTech Connect (OSTI)

    Alvarado, Samuel R. [Ames Laboratory; Guo, Yijun [Ames Laboratory; Ruberu, T. Purnima A. [Ames Laboratory; Tavasoli, Elham [Ames Laboratory; Vela, Javier [Ames Laboratory

    2014-03-15T23:59:59.000Z

    The optoelectronic and chemical properties of semiconductor nanocrystals heavily depend on their composition, size, shape and internal structure, surface functionality, etc. Available strategies to alter these properties through traditional colloidal syntheses and ligand exchange methods place a premium on specific reaction conditions and surfactant combinations. In this invited review, we apply a molecular-level understanding of chemical precursor reactivity to reliably control the morphology, composition and intimate architecture (core/shell vs. alloyed) of semiconductor nanocrystals. We also describe our work aimed at achieving highly selective, low-temperature photochemical methods for the synthesis of semiconductormetal and semiconductormetal oxide photocatalytic nanocomposites. In addition, we describe our work on surface modification of semiconductor nanocrystal quantum dots using new approaches and methods that bypass ligand exchange, retaining the nanocrystal's native ligands and original optical properties, as well as on spectroscopic methods of characterization useful in determining surface ligand organization and chemistry. Using recent examples from our group and collaborators, we demonstrate how these efforts have lead to faster, wider and more systematic application of semiconductor nanocrystal-based materials to biological imaging and tracking, and to photocatalysis of unconventional substrates. We believe techniques and methods borrowed from inorganic chemistry (including coordination, organometallic and solid state chemistry) have much to offer in reaching a better understanding of the synthesis, functionalization and real-life application of such exciting materials as semiconductor nanocrystals (quantum dots, rods, tetrapods, etc.).

  17. Anticorrelation between Surface and Subsurface Point Defects...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    between Surface and Subsurface Point Defects and the Impact on the Redox Chemistry of TiO2(110). Anticorrelation between Surface and Subsurface Point Defects and the...

  18. Recovery Boiler Corrosion Chemistry

    E-Print Network [OSTI]

    Das, Suman

    11/13/2014 1 Recovery Boiler Corrosion Chemistry Sandy Sharp and Honghi Tran Symposium on Corrosion of a recovery boiler each cause their own forms of corrosion and cracking Understanding the origin of the corrosive conditions enables us to operate a boiler so as to minimize corrosion and cracking select

  19. Chemistry Portfolio (Revised August, 2011)

    E-Print Network [OSTI]

    Baltisberger, Jay H.

    at or above the 75th percentile on the American Chemical Society (ACS) Introductory Chemistry Exami- nation

  20. MAC 560 --Tropospheric Chemistry I Spring, 2009

    E-Print Network [OSTI]

    Miami, University of

    chemistry · to learn the atmospheric chemistry behind well-known phenomena such as smog, acid rain.3. Sulfur chemistry and acid rain 5.4. Nitrogen chemistry 5.5. Organic acids 5.6. Ecological and structural

  1. Shooting device for free-surface impact studies

    E-Print Network [OSTI]

    Daigh, Sara L. (Sarah Louise), 1981-

    2004-01-01T23:59:59.000Z

    The hydrodynamics of free-surface impacts are of great interest to scientists across many disciplines including ocean engineering, fluids mechanics, and biology. This thesis focuses on designing a mechanism to shoot small ...

  2. Chemistry Department Colloquium: Spring, 2012

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Chemistry Department Colloquium: Spring, 2012 Friday, March 16; 3:30 Seminar Hall (room 1315 Chemistry) Lost in Translation: How Regulators Use Science and How Scientists Can Help Bridge Gaps Stephanie to combine her Chemistry background with a legal education to improve the use of science in environmental

  3. 6, 1205712120, 2006 Surface tension

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ACPD 6, 1205712120, 2006 Surface tension: measurement, modelling and cloud activation D. O a Creative Commons License. Atmospheric Chemistry and Physics Discussions Surface tensions of multi12120, 2006 Surface tension: measurement, modelling and cloud activation D. O. Topping et al. Title Page

  4. Introduction: Surface Chemistry of Oxides Understanding the surface chemistry of oxide materials

    E-Print Network [OSTI]

    Campbell, Charles T.

    and for pollution cleanup, and for the production and use of fuel cells, solar fuel photocatalysts, batteries. Optimization of our ability to improve or enable the technologies outlined above requires detailed knowledge

  5. Cite this: Lab Chip, 2013, 13, 1457 Unconventional microfluidics: expanding the discipline

    E-Print Network [OSTI]

    Cite this: Lab Chip, 2013, 13, 1457 Unconventional microfluidics: expanding the discipline DOI: 10*a Since its inception, the discipline of microfluidics has been harnessed for innovations-effect of stereotyping microfluidics as a platform for medical diagnostics and miniaturized lab processes

  6. Multi-discipline Waste Acceptance Process at the Nevada National Security Site - 13573

    SciTech Connect (OSTI)

    Carilli, Jhon T. [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States)] [US Department Of Energy, Nevada Site Office, P. O. Box 98518, Las Vegas, Nevada 89193-8518 (United States); Krenzien, Susan K. [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)] [Navarro-Intera, LLC, P. O. Box 98952, Las Vegas, Nevada 89193-8952 (United States)

    2013-07-01T23:59:59.000Z

    The Nevada National Security Site low-level radioactive waste disposal facility acceptance process requires multiple disciplines to ensure the protection of workers, the public, and the environment. These disciplines, which include waste acceptance, nuclear criticality, safety, permitting, operations, and performance assessment, combine into the overall waste acceptance process to assess low-level radioactive waste streams for disposal at the Area 5 Radioactive Waste Management Site. Four waste streams recently highlighted the integration of these disciplines: the Oak Ridge Radioisotope Thermoelectric Generators and Consolidated Edison Uranium Solidification Project material, West Valley Melter, and classified waste. (authors)

  7. Sandia National Laboratories: atmospheric chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric chemistry that is expected to benefit auto and engine manufacturers, oil and gas utilities, and other industries that employ combustion models. A paper...

  8. Sandia National Laboratories: combustion chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric chemistry that is expected to benefit auto and engine manufacturers, oil and gas utilities, and other industries that employ combustion models. A paper...

  9. agricultural chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Chemistry Honors in Chemistry Research Instructions (Seniors only) Materials Science Websites Summary: Department of Chemistry Honors in Chemistry Research Instructions...

  10. Environmental Soil Chemistry Second Edition Environmental Soil Chemistry illustrates fundamental principles of soil

    E-Print Network [OSTI]

    Sparks, Donald L.

    Environmental Soil Chemistry Second Edition Environmental Soil Chemistry illustrates fundamental principles of soil chemistry with respect to environmental reactions between soils and other natural contemporary training in the basics of soil chemistry and applications to real-world environmental concerns

  11. Chemistry Major and Minor At A Glance

    E-Print Network [OSTI]

    Schmitt, William R.

    Chemistry Major and Minor At A Glance Major I Pre-professional (Medicine, Dentistry, Business, Law, Engineering) Major II ACS Certified e.g. Graduate Study or Entry Level Chemistry Employment. Major III Forensic Chemistry Major IV** Biochemistry Option Chemistry Minor General Chemistry I & II

  12. Chemistry and Biochemistry Graduate Student Spring 2012

    E-Print Network [OSTI]

    Chemistry and Biochemistry Graduate Student Tutors Spring 2012 (All arrangements are solely between.axelrod@mail.utexas.edu Organic Chemistry Chris Bates chrismbates@gmail.com General Chemistry Lecture/Lab Organic Chemistry Amy Bonaparte abonaparte@mail.utexas.edu General and Organic Chemistry Shelly Casciato slcasciato

  13. Chemistry UMass Lowell Commonwealth Honors Track

    E-Print Network [OSTI]

    Massachusetts at Lowell, University of

    Chemistry UMass Lowell Commonwealth Honors Track Scholarship Rises. Freshman Year/ Fall Semester Cr) Honors Chemistry I 3 84.136 (H) Honors Chemistry II 3 84.123 (H) Honors Chemistry I Lab 1 84.124 (H) Honors Chemistry II Lab 1 92.131 Calculus I 4 92.132 Honors Calculus II 4 Hon 110 Honors FYSH (AH) 3 Gen

  14. Chemistry and Biochemistry Graduate Student Summer 2012

    E-Print Network [OSTI]

    Chemistry and Biochemistry Graduate Student Tutors Summer 2012 (All arrangements are solely between.axelrod@mail.utexas.edu Organic Chemistry Chris Bates chrismbates@gmail.com General Chemistry Lecture/Lab Organic Chemistry Amy Bonaparte abonaparte@mail.utexas.edu General and Organic Chemistry Shelly Casciato slcasciato

  15. Technical Report TR-014 May 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-014 Tools9T 6E9, 250-751-7001 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  16. Electrical Engineering is a diverse discipline encompassing computer and information systems, controls, lasers,

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering is a diverse discipline encompassing computer and information environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Processing institute. PROGRAMS AVAILABLE Electrical Engineering

  17. Electrical Engineering (EE) is a diverse discipline encompassing computer and information systems, controls,

    E-Print Network [OSTI]

    Rohs, Remo

    70 ELECTRICAL Electrical Engineering (EE) is a diverse discipline encompassing computer, photonics, and quantum information processing. MAJORS & AREAS OF EMPHASIS ElectricalEngineering ComputerEngineering)Algorithmsandcomputationalmeth- odsforefficientsolutionofengineeringproblems. Introductiontoengineeringsoftwaretools. EE 200L Foundations of Electrical Engineer- ing Systems

  18. Why Should I Study Engineering? Georgia Southern offers three engineering disciplines Civil, Electrical and Mechanical.

    E-Print Network [OSTI]

    Hutcheon, James M.

    , Electrical and Mechanical. Engineers plan, design, develop, test and analyze infrastructure components (CivilWhy Should I Study Engineering? Georgia Southern offers three engineering disciplines Civil), electronic systems (Electrical), and systems with moving parts (Mechanical) that affect and improve people

  19. electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer and

    E-Print Network [OSTI]

    Rohs, Remo

    62 electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering. Programs Available Electrical Engineering Bachelor of Science 131 units Computer Engineering

  20. electrical (EE) Electrical Engineering is a diverse discipline encompassing computer and

    E-Print Network [OSTI]

    Rohs, Remo

    66 electrical (EE) Electrical Engineering is a diverse discipline encompassing computer environmental engineering and manufacturing to semiconductors and telecommunica- tions. The Electrical Technology and the Signal and Image Processing institute. Programs Available Electrical Engineering

  1. electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer and

    E-Print Network [OSTI]

    Rohs, Remo

    62 electrical engineering (EE) Electrical Engineering is a diverse discipline encompassing computer environmental engineering and manufacturing to semiconductors and telecommunications. The Electrical Engineering Technology and the Signal and Image Process- ing institute. Programs Available Electrical Engineering

  2. To appear in Topics in Cognitive Science How Can Philosophy be a True Cognitive Science Discipline?

    E-Print Network [OSTI]

    Bechtel, William

    and cognitive neuroscience. Second, analyses of mental representation address both their vehicle in the autonomous disciplines. Indeed, for those discussions that do not afford linkage to the rest of cognitive

  3. Asteroid Surface Geophysics

    E-Print Network [OSTI]

    Murdoch, Naomi; Schwartz, Stephen R; Miyamoto, Hideaki

    2015-01-01T23:59:59.000Z

    The regolith-covered surfaces of asteroids preserve records of geophysical processes that have occurred both at their surfaces and sometimes also in their interiors. As a result of the unique micro-gravity environment that these bodies posses, a complex and varied geophysics has given birth to fascinating features that we are just now beginning to understand. The processes that formed such features were first hypothesised through detailed spacecraft observations and have been further studied using theoretical, numerical and experimental methods that often combine several scientific disciplines. These multiple approaches are now merging towards a further understanding of the geophysical states of the surfaces of asteroids. In this chapter we provide a concise summary of what the scientific community has learned so far about the surfaces of these small planetary bodies and the processes that have shaped them. We also discuss the state of the art in terms of experimental techniques and numerical simulations that...

  4. The relationship of parental consistency in discipline to locus of control in preschoolers

    E-Print Network [OSTI]

    Schmidt, Corliss Theresa

    1979-01-01T23:59:59.000Z

    THE RELATIONSHIP OF PARENTAL CONSISTENCY IN DISCIPLINE TO LOCUS OF CONTROL IN PRESCHOOLERS A Thesis by CORLISS THERESA SCHMIDT Submitted to the Graduate College of Texas AIIM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIEI'ICE August 1979 Major Subject: Psychology THE RELATIONSHIP OF PARENTAL CONSISTENCY IN DISCIPLINE TO LOCUS OF CONTROL IN PRESCHOOLERS A Thesis by CORLISS THERESA SCHMIDT Approved as to style and content by: ( a a of Committee...

  5. BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry

    E-Print Network [OSTI]

    Seamons, Kent E.

    BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry For students entering Chemistry and Biochemistry Department requires the final 10 hours of required chemistry credit to be taken for graduation. Complete the following: Chem 111* Honors Principles of Chemistry Chem 112 Principles of Chemistry

  6. Chemistry -Bachelor of Science (SCHUG) Total Credits Required: 128 Chemistry -ACS Certified

    E-Print Network [OSTI]

    Chemistry - Bachelor of Science (SCHUG) Total Credits Required: 128 Chemistry - ACS Certified Major of the following courses Course Credits Course Credits CH1150 University Chemistry I AND 3 CH4110 Pharmaceutical Chemistry: Drug Action 3 CH1151 University Chemistry Lab 1 AND 1 CH4120 Pharmaceutical Chemistry: Drug

  7. Chemistry -Bachelor of Science (SCH1UG) Total Credits Required: 128 Chemistry/Polymers -ACS Certified

    E-Print Network [OSTI]

    Chemistry - Bachelor of Science (SCH1UG) Total Credits Required: 128 Chemistry/Polymers - ACS credits Course Credits Course Credits CH1150 University Chemistry I AND 3 CH4610 Intro to Polymer Science 3 CH1151 University Chemistry Lab 1 AND 1 CH4620 Polymer Chemistry 3 CH1153 University Chemistry

  8. Course Syllabus: Chemistry 3AL Course Information

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    Course Syllabus: Chemistry 3AL Course Information Course Name Chemistry 3AL Course Instructor are online. Chemistry 3AL Syllabus https://elearning.berkeley.edu/AngelUploads/Content/2013SUC... 1 of 5 5

  9. Technical Report TR-011 March 2000 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-011 Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife #12;Technical ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Page Summary

  10. Chemistry @ Imperial College 2007 Introduction

    E-Print Network [OSTI]

    techniques from a wide variety of disciplines, they are able to directly observe, model or even manipulate and protein biosynthesis, as well as how these events are regulated. By drawing knowledge and experimental-molecule control of protein function and properties, methods for predicting which molecules will display desirable

  11. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Cell Chemistries and Streamlining Optimization of Electrode Screen Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrode 2010 DOE Vehicle Technologies...

  12. Cetane Performance and Chemistry Comparing Conventional Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance and Chemistry Comparing Conventional Fuels and Fuels Derived from Heavy Crude Sources Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels...

  13. Nanostructure, Chemistry and Crystallography of Iron Nitride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanostructure, Chemistry and Crystallography of Iron Nitride Magnetic Materials by Ultra-High-Resolution Electron Microscopy and Related Methods Nanostructure, Chemistry and...

  14. A chemistry tale of two carbons | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A chemistry tale of two carbons A chemistry tale of two carbons Released: September 03, 2012 Comprehensive field study of urban, natural emissions interacting to affect climate...

  15. 2014 CHEMICAL REACTIONS AT SURFACES GORDON RESEARCH CONFERENCE AND GORDON RESEARCH SEMINAR (APRIL 28-MAY 3, 2013 - LES DIABLERETS CONFERENCE CENTER, LES DIABLERETS, SWITZERLAND)

    SciTech Connect (OSTI)

    Stair, Peter C.

    2013-02-03T23:59:59.000Z

    presentations on chemistry at solid and liquid surfaces of relevance to catalysis, synthesis, photochemistry, environmental science, and tribology. Topics include: Fundamental Surface Chemistry; Catalysis; Solid Liquid and Aerosol Interfaces; Surface Photochemistry; Synthesis of Surfaces; Environmental Interfaces; Hot Topics in Surface Chemical Reactions; Tribology; Gas-Surface Scattering and Reactions; Novel Materials and Environments.

  16. Mica Surfaces Stabilize Pentavalent Uranium. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ilton ES, A Haiduc, CL Cahill, and AR Felmy.2005."Mica Surfaces Stabilize Pentavalent Uranium."Inorganic Chemistry 44(9):2986-2988. Authors: ES Ilton A Haiduc CL Cahill AR...

  17. Advanced Chemistry Basins Model

    SciTech Connect (OSTI)

    Blanco, Mario; Cathles, Lawrence; Manhardt, Paul; Meulbroek, Peter; Tang, Yongchun

    2003-02-13T23:59:59.000Z

    The objective of this project is to: (1) Develop a database of additional and better maturity indicators for paleo-heat flow calibration; (2) Develop maturation models capable of predicting the chemical composition of hydrocarbons produced by a specific kerogen as a function of maturity, heating rate, etc.; assemble a compositional kinetic database of representative kerogens; (3) Develop a 4 phase equation of state-flash model that can define the physical properties (viscosity, density, etc.) of the products of kerogen maturation, and phase transitions that occur along secondary migration pathways; (4) Build a conventional basin model and incorporate new maturity indicators and data bases in a user-friendly way; (5) Develop an algorithm which combines the volume change and viscosities of the compositional maturation model to predict the chemistry of the hydrocarbons that will be expelled from the kerogen to the secondary migration pathways; (6) Develop an algorithm that predicts the flow of hydrocarbons along secondary migration pathways, accounts for mixing of miscible hydrocarbon components along the pathway, and calculates the phase fractionation that will occur as the hydrocarbons move upward down the geothermal and fluid pressure gradients in the basin; and (7) Integrate the above components into a functional model implemented on a PC or low cost workstation.

  18. National Nuclear Chemistry Summer School

    Broader source: Energy.gov [DOE]

    The Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding is provided by the US Department of Energy.

  19. National Nuclear Chemistry Summer School

    Broader source: Energy.gov [DOE]

    he Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding...

  20. Antibody binding to p-Si using LANL SAM chemistry

    SciTech Connect (OSTI)

    Anderson, Aaron S [Los Alamos National Laboratory

    2010-12-06T23:59:59.000Z

    This NMSBA-sponsored project involves the attachment of antibodies to polymeric silicon (p-Si) surfaces, with the ultimate goal of attaching antibodies to nanowires for Vista Therapeutics, Inc. (Santa Fe, NM). This presentation describes the functionalization of p-Si surfaces. the activation of terminal carboxylates on these surfaces, the conjugation of antibodies, and the analyses undertaken at each step. The results of this work show that antibody conjugation is possible on p-Si coatings using the well-known EDC/NHS activation chemistry.

  1. 2010 Tetrapyrroles, Chemistry & Biology of Gordon Research Conference

    SciTech Connect (OSTI)

    Angela Wilks

    2010-07-30T23:59:59.000Z

    The objective of the Chemistry & Biology of Tetrapyrroles Gordon Conference is to bring together researchers from diverse disciplines that otherwise would not interact. By bringing biologists, chemists, engineers and clinicians with a common interest in tetrapyrroles the conference provides a forum for cross-disciplinary ideas and collaboration. The perspective provided by biologists, chemists, and clinicians working in fields such as newly discovered defects in human porphyrin metabolism, the myriad of strategies for light harvesting in photosynthetic organisms, novel tetrapyrroles that serve as auxiliary chromophores or enzyme cofactors, synthetic strategies in the design of novel tetrapyrrole scaffolds, and tetrapyrrole based cell signaling and regulatory systems, makes this conference unique in the field. Over the years the growing evidence for the role of tetrapyrroles and their reactive intermediates in cell signaling and regulation has been of increasing importance at this conference. The 2010 conference on Chemistry & Biology of Tetrapyrroles will focus on many of these new frontiers as outlined in the preliminary program listed. Speakers will emphasize unpublished results and new findings in the field. The oral sessions will be followed by the highly interactive afternoon poster sessions. The poster sessions provide all conferees with the opportunity to present their latest research and to exchange ideas in a more informal setting. As in the past, this opportunity will continue during the nightly social gathering that takes place in the poster hall following the evening lectures. All conferees are encouraged to submit and present posters. At the conference the best poster in the areas of biology, chemistry and medicine will be selected by a panel of previous conference chairs.

  2. Heterogeneous Chemistry: Understanding Aerosol/Oxidant Interactions

    SciTech Connect (OSTI)

    Joyce E. Penner

    2005-03-14T23:59:59.000Z

    Global radiative forcing of nitrate and ammonium aerosols has mostly been estimated from aerosol concentrations calculated at thermodynamic equilibrium or using approximate treatments for their uptake by aerosols. In this study, a more accurate hybrid dynamical approach (DYN) was used to simulate the uptake of nitrate and ammonium by aerosols and the interaction with tropospheric reactive nitrogen chemistry in a three-dimensional global aerosol and chemistry model, IMPACT, which also treats sulfate, sea salt and mineral dust aerosol. 43% of the global annual average nitrate aerosol burden, 0.16 TgN, and 92% of the global annual average ammonium aerosol burden, 0.29 TgN, exist in the fine mode (D<1.25 {micro}m) that scatters most efficiently. Results from an equilibrium calculation differ significantly from those of DYN since the fraction of fine-mode nitrate to total nitrate (gas plus aerosol) is 9.8%, compared to 13% in DYN. Our results suggest that the estimates of aerosol forcing from equilibrium concentrations will be underestimated. We also show that two common approaches used to treat nitrate and ammonium in aerosol in global models, including the first-order gas-to-particle approximation based on uptake coefficients (UPTAKE) and a hybrid method that combines the former with an equilibrium model (HYB), significantly overpredict the nitrate uptake by aerosols especially that by coarse particles, resulting in total nitrate aerosol burdens higher than that in DYN by +106% and +47%, respectively. Thus, nitrate aerosol in the coarse mode calculated by HYB is 0.18 Tg N, a factor of 2 more than that in DYN (0.086 Tg N). Excessive formation of the coarse-mode nitrate in HYB leads to near surface nitrate concentrations in the fine mode lower than that in DYN by up to 50% over continents. In addition, near-surface HNO{sub 3} and NO{sub x} concentrations are underpredicted by HYB by up to 90% and 5%, respectively. UPTAKE overpredicts the NO{sub x} burden by 56% and near-surface NO{sub x} concentrations by a factor of 2-5. These results suggest the importance of using the more accurate hybrid dynamical method in the estimates of both aerosol forcing and tropospheric ozone chemistry.

  3. EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused on understanding the

    E-Print Network [OSTI]

    Krylov, Anna I.

    EARTH SCIENCESEARTH SCIENCESEARTH SCIENCES This major includes a spectrum of disciplines focused this understanding to read the record of earth history written in rocks and sediments, and on developing models by humans. Opportunities for Students Sigma Gamma Epsilon: The Omega Chapter of the national honorary earth

  4. 1.14 Note: Actual time to complete varies by discipline and departmental requirements. Dissertation Timeline

    E-Print Network [OSTI]

    Papalambros, Panos

    1.14 Note: Actual time to complete varies by discipline and departmental requirements. Dissertation Timeline STUDENT SERVICES: ACADEMIC RECORDS & DISSERTATIONS 915 E. Washington Street 0120 Rackham://wolverineaccess.umich.edu/ 6 months prior to Group Pre-Defense Review Rackham Format Guidelines http://www.rackham.umich.edu/downloads/oard-dissertation

  5. Electrical Engineering (EE) is a diverse discipline encompassing computer and information systems, controls,

    E-Print Network [OSTI]

    Rohs, Remo

    70 electrical Electrical Engineering (EE) is a diverse discipline encompassing computer information processing. ProgrAmS AVAilAble ElectricalEngineering Bachelor of Science 131 units ComputerEngineeringand Computer Science Bachelor of Science (see page 69) 132 units ElectricalEngineering(Computers) degree

  6. Electrical Engineering (EE) is a diverse discipline encompassing computer and information systems, controls,

    E-Print Network [OSTI]

    Rohs, Remo

    70 electrical Electrical Engineering (EE) is a diverse discipline encompassing computer information processing. mAjorS & AreAS of emPhASiS ElectricalEngineering ComputerEngineering& Computer Science (see page 69) ElectricalEngineering Emphasis in Computers See pages 76-77 for the curriculum

  7. Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Extension Note Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology.Understanding how the hydrologic cycle is affected by climate, trees and plants, soils, geology, topography, springs, or any Figure 1. The hydrologic cycle, or water cycle (courtesy of the US Geological Survey

  8. The NU Transportation Center Icarus Society presents.... "Airline Capacity Discipline: Where and

    E-Print Network [OSTI]

    Bustamante, Fabián E.

    The NU Transportation Center Icarus Society presents.... "Airline Capacity Discipline: Where and to What Extent? Aaron J. Gellman Professor of Transportation Northwestern University Transportation Center and Kellogg School of Management Thursday Nov. 29, 2012 3:00 pm Location: Transportation Center Chambers Hall

  9. Wind power is a rapidly growing and evolving field that crosses traditional academic disciplines and increasingly

    E-Print Network [OSTI]

    Delaware, University of

    ways in which society's understanding and acceptance of renewable energy power generation can impactWind power is a rapidly growing and evolving field that crosses traditional academic disciplines and increasingly requires practitioners who understand the relationships among the various components of wind

  10. 1997 Atmospheric Chemistry Colloquium for Emerging Senior Scientists

    SciTech Connect (OSTI)

    Paul H. Wine

    1998-11-23T23:59:59.000Z

    DOE's Atmospheric Chemistry Program is providing partial funding for the Atmospheric Chemistry Colloquium for Emerging Senior Scientists (ACCESS) and FY 1997 Gordon Research Conference in Atmospheric Chemistry

  11. analytical chemistry organic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Electronic Structure and Laser, Foundation for Research and Technology 25 SYLLABUS for CHEMISTRY 2310 ORGANIC CHEMISTRY 1 Chemistry Websites Summary: Discussion...

  12. applied chemistry organic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Electronic Structure and Laser, Foundation for Research and Technology 18 SYLLABUS for CHEMISTRY 2310 ORGANIC CHEMISTRY 1 Chemistry Websites Summary: Discussion...

  13. Letters to Analytical Chemistry Silver Nanoparticles on a Plastic Platform for

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    Letters to Analytical Chemistry Silver Nanoparticles on a Plastic Platform for Localized Surface on plastics is described. The silver-nanopar- ticles-on-plastic sensor (SNOPS) was fabricated by chemi- cally modifying the surface of a common plastic, polyeth- yleneterephthalate

  14. Chemistry and Materials Science, 1990--1991. [Second annual report

    SciTech Connect (OSTI)

    Sugihara, T.T.; Bruner, J.M.; McElroy, L.A. [eds.

    1991-12-31T23:59:59.000Z

    This 2-year (FY 1990-91) contains 49 technical articles in ten sections: research sampler, metals and alloys, energetic materials, chemistry and physics of advanced materials, bonding and reactions at surfaces and interfaces, superconductivity, energy R and D, waste processing and management, characterization and analysis, and facilities and instrumentation. Two more sections list department personnel, their publications etc., consultants, and summary of department budgets. The articles are processed separately for the data base. (DLC)

  15. Chemistry and Processing of Nanostructured Materials

    SciTech Connect (OSTI)

    Fox, G A; Baumann, T F; Hope-Weeks, L J; Vance, A L

    2002-01-18T23:59:59.000Z

    Nanostructured materials can be formed through the sol-gel polymerization of inorganic or organic monomer systems. For example, a two step polymerization of tetramethoxysilane (TMOS) was developed such that silica aerogels with densities as low as 3 kg/m{sup 3} ({approx} two times the density of air) could be achieved. Organic aerogels based upon resorcinol-formaldehyde and melamine-formaldehyde can also be prepared using the sol-gel process. Materials of this type have received significant attention at LLNL due to their ultrafine cell sizes, continuous porosity, high surface area and low mass density. For both types of aerogels, sol-gel polymerization depends upon the transformation of these monomers into nanometer-sized clusters followed by cross-linking into a 3-dimensional gel network. While sol-gel chemistry provides the opportunity to synthesize new material compositions, it suffers from the inability to separate the process of cluster formation from gelation. This limitation results in structural deficiencies in the gel that impact the physical properties of the aerogel, xerogel or nanocomposite. In order to control the properties of the resultant gel, one should be able to regulate the formation of the clusters and their subsequent cross-linking. Towards this goal, we are utilizing dendrimer chemistry to separate the cluster formation from the gelation so that new nanostructured materials can be produced. Dendrimers are three-dimensional, highly branched macromolecules that are prepared in such a way that their size, shape and surface functionality are readily controlled. The dendrimers will be used as pre-formed clusters of known size that can be cross-linked to form an ordered gel network.

  16. 32.02.02.V1.01 DISCIPLINE AND DISMISSAL Supplements System Policy 32.02 and System Regulation

    E-Print Network [OSTI]

    32.02.02.V1.01 DISCIPLINE AND DISMISSAL Supplements System Policy 32.02 and System Regulation 32) in the administration of the discipline and dismissal policy and regulation. 2.00 APPROVAL PROCEDURE 2.01 A supervisor that is available for review. Following the review, AgriLife Human Resources will, in keeping with System Regulation

  17. Molten fluoride fuel salt chemistry

    SciTech Connect (OSTI)

    Toth, L.M.; Del Cul, G.D.; Dai, S.; Metcalf, D.H. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.

    1994-09-01T23:59:59.000Z

    The chemistry of molten fluorides is traced from their development as fuels in the Molten Salt Reactor Experiment with important factors in their selection being discussed. Key chemical characteristics such as solubility, redox behavior, and chemical activity are explained as they relate to the behavior of molten fluoride fuel systems. Fission product behavior is described along with processing experience. Development requirements for fitting the current state of the chemistry to modern nuclear fuel system are described. It is concluded that while much is known about molten fluoride behavior, processing and recycle of the fuel components is a necessary factor if future systems are to be established.

  18. Carbon Chemistry in interstellar clouds

    E-Print Network [OSTI]

    Maryvonne Gerin; David Fosse; Evelyne Roueff

    2002-12-03T23:59:59.000Z

    We discuss new developments of interstellar chemistry, with particular emphasis on the carbon chemistry. We confirm that carbon chains and cycles are ubiquitous in the ISM and closely chemically related to ea ch other, and to carbon. Investigation of the carbon budget in shielded and UV illuminated gas shows that the inventory of interstellar molecules is not complete and more complex molecules with 4 or more carbon atoms must be present. Finally we discuss the consequences for the evolution of clouds and conclude that the ubiquitous presence of carbon chains and cycles is not a necessary consequence of a very young age for interstellar clouds.

  19. Chemistry, Life, and Earth Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry OxideChemistry Soft

  20. E-Print Network 3.0 - acetate surface modified Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    42 Topic T4 Claudia Hildenbrand 274 EDLC electrodes from cellulose-based carbon aerogels: influence of Summary: -pyrolysis). Thus the carbon material's surface chemistry was...

  1. Thermal chemistry and photochemistry of hexafluoroacetone on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistry and photochemistry of hexafluoroacetone on rutile TiO2(110) . Thermal chemistry and photochemistry of hexafluoroacetone on rutile TiO2(110) . Abstract: The ultraviolet...

  2. Capturing Chemistry in XML/CML

    E-Print Network [OSTI]

    Townsend, Joseph A; Adams, Sam; Goodman, Jonathan M; Murray-Rust, Peter; Waudby, Chris A

    Chemical Markup Language (CML) is an XML-conformant Schema that describes molecules, spectra, reactions, and computational chemistry. It is capable of capturing the chemistry in a variety of current publications and is becoming adopted by many...

  3. User Manual Frick Chemistry Laboratory

    E-Print Network [OSTI]

    Torquato, Salvatore

    the atrium connects the laboratory wing with the administrative offices. This provides a light-filled space to make the new Frick Chemistry Laboratory (and the surrounding natural sciences neighborhood) one technologies that reduce energy demand and con- serve water. The design and construction teams have implemented

  4. Theoretical Chemistry Theory, Computation, and

    E-Print Network [OSTI]

    Gherman, Benjamin F.

    1 23 Theoretical Chemistry Accounts Theory, Computation, and Modeling ISSN 1432-881X Volume 128). In order to explore the origin of this preference, density functional theory (DFT) calculations have been-terminus of nascent eubacterial proteins during protein synthesis [14]. As PDF is essential for bacterial survival

  5. Disciplines Atmosphere

    E-Print Network [OSTI]

    Laurini, Robert

    Ultraviolet X-Rays Gamma-Rays Visible Red Orange Yellow Green Blue Violet 0,7 m 0,4 m Waves #12;Satellites of pollution (air, water, etc.) etc. #12;http://www.sbg.ac.at/geo/idrisi/gis_environmental_modeling/sf_papers/brendan_mackey/mackey_paper.html #12;Contents 1 Data acquisition 2 Environmental data modelling 3 Continuous data 4 XML

  6. Interfacial Chemistry and Engineering Annual Report 2000

    SciTech Connect (OSTI)

    Grate, Jay W.

    2001-08-01T23:59:59.000Z

    This annual report describes the research and staff accomplishments in 2000 for the EMSL Interfacial Chemistry and Engineering Directorate.

  7. Eleventh international symposium on radiopharmaceutical chemistry

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    This document contains abstracts of papers which were presented at the Eleventh International Symposium on Radiopharmaceutical Chemistry. Sessions included: radiopharmaceuticals for the dopaminergic system, strategies for the production and use of labelled reactive small molecules, radiopharmaceuticals for measuring metabolism, radiopharmaceuticals for the serotonin and sigma receptor systems, labelled probes for molecular biology applications, radiopharmaceuticals for receptor systems, radiopharmaceuticals utilizing coordination chemistry, radiolabelled antibodies, radiolabelling methods for small molecules, analytical techniques in radiopharmaceutical chemistry, and analytical techniques in radiopharmaceutical chemistry.

  8. Technetium Chemistry Science Challenges in Environmental Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technetium Chemistry Science Challenges in Environmental Science and Waste Processing Workshop Sponsored by Environmental Molecular Science Laboratory Richland, Washington July...

  9. Chemistry / Biochemistry B.S. Curriculum

    E-Print Network [OSTI]

    Long, Nicholas

    Chemistry / Biochemistry B.S. Curriculum Freshman Chemistry CHE 133/133L, 134/134L; ENG 131, 132, BIO elective Sophomore Chemistry CHE 231/231L, 241/241L, 331/331L, 332/332L; MTH 233, 234; PHY 241 elective Junior Chemistry CHE 337/337L, 338/338L, 452/452L; CSC 101 or 201, ENG 273, Eng. Lit; Core

  10. Materials Chemistry and Performance of Silicone-Based Replicating Compounds.

    SciTech Connect (OSTI)

    Brumbach, Michael T.; Mirabal, Alex James; Kalan, Michael; Trujillo, Ana B; Hale, Kevin

    2014-11-01T23:59:59.000Z

    Replicating compounds are used to cast reproductions of surface features on a variety of materials. Replicas allow for quantitative measurements and recordkeeping on parts that may otherwise be difficult to measure or maintain. In this study, the chemistry and replicating capability of several replicating compounds was investigated. Additionally, the residue remaining on material surfaces upon removal of replicas was quantified. Cleaning practices were tested for several different replicating compounds. For all replicating compounds investigated, a thin silicone residue was left by the replica. For some compounds, additional inorganic species could be identified in the residue. Simple solvent cleaning could remove some residue.

  11. Updated March 2011 Ph.D. Chemistry; Option in Chemistry Education

    E-Print Network [OSTI]

    New Hampshire, University of

    Updated March 2011 Ph.D. Chemistry; Option in Chemistry Education University of New Hampshire below), or candidate can obtain MS at UNH on the way to the PhD with Option in Chemistry Education Cumulative exams are split between education and chemistry cores Professional presentation allowed in place

  12. Roadmap: Chemistry Chemistry -Bachelor of Science [AS-BS-CHEM-CHEM

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Chemistry Chemistry - Bachelor of Science [AS-BS-CHEM-CHEM] College of Arts and Sciences Department of Chemistry and Biochemistry Catalog Year: 2013-2014 Page 1 of 2 | Last Updated: 30-Apr-13/LNHD for certification by the American Chemical Society CHEM 10060 General Chemistry I (4) and CHEM 10062 General

  13. BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry

    E-Print Network [OSTI]

    Olsen Jr., Dan R.

    BA in CHEMISTRY (692827) MAP Sheet Department of Chemistry and Biochemistry For students entering in major courses. --The Chemistry and Biochemistry Department requires the final 10 hours of required chemistry credit to be taken in residence at BYU for this degree program. These hours may also go toward BYU

  14. Minor in Chemistry Handout1.doc (04/30/08) Department of Chemistry

    E-Print Network [OSTI]

    Reed, Christopher A.

    Minor in Chemistry Handout1.doc (04/30/08) Department of Chemistry Undergraduate Student Academic.fleming@ucr.edu Minor in Chemistry Procedure: It is assumed that you have completed the requirements listed in section to Declare a Minor to Chemistry. Include the following: full name, student identification number, and email

  15. CHEMISTRY AND TECHNOLOGY 2011 Academic regulations for the Bachelor's degree in Chemistry and Technology

    E-Print Network [OSTI]

    CHEMISTRY AND TECHNOLOGY 2011 Academic regulations for the Bachelor's degree in Chemistry Bachelor's degree programme provides graduates with the title Bachelor of Science (BSc) in Chemistry and Technology. Academic line and main subject areas of the degree The Bachelor's degree in Chemistry

  16. Roadmap: Chemistry Chemistry -Bachelor of Science [AS-BS-CHEM-CHEM

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Chemistry Chemistry - Bachelor of Science [AS-BS-CHEM-CHEM] College of Arts and Sciences Department of Chemistry and Biochemistry Catalog Year: 20122013 Page 1 of 2 | Last Updated: 17-May-12/LNHD for certification by the American Chemical Society CHEM 10060 General Chemistry I (4) and CHEM 10062 General

  17. Chemistry -Bachelor of Science (SCH5UG) Total Credits Required: 128 Chemistry/Environmental -ACS Certified

    E-Print Network [OSTI]

    Chemistry - Bachelor of Science (SCH5UG) Total Credits Required: 128 Chemistry/Environmental - ACS credits Course Credits Course Credits CH1150 University Chemistry I AND 3 BL1040 Principles of Biology 4 CH1151 University Chemistry Lab 1 AND 1 BL3310 Environmental Microbiology 3 CH1153 University

  18. The School of Chemistry Handbook for Postgraduate

    E-Print Network [OSTI]

    Rzepa, Henry S.

    The School of Chemistry Handbook for Postgraduate Research Students 2013/14 School of Chemistry FACULTY OF MATHS AND PHYSICAL SCIENCES #12;2 Welcome The School of Chemistry welcomes new postgraduate that is relevant for your time spent in the School, including information about facilities to support your research

  19. Chemistry Department Assessment Table of Contents

    E-Print Network [OSTI]

    Bogaerts, Steven

    0 Chemistry Department Assessment May, 2006 Table of Contents Page Executive Summary 1 Prelude 1 Mission Statement and Learning Goals 1 Facilities 2 Staffing 3 Students: Chemistry Majors and Student Taking Service Courses Table: 1997-2005 graduates profile Table: GRE Score for Chemistry Majors, 1993

  20. Chemistry-nuclear chemistry division. Progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Ryan, R.R. (comp.)

    1981-05-01T23:59:59.000Z

    This report presents the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, element migration and fixation, inorganic chemistry, isotope separation and analysis, atomic and molecular collisions, molecular spectroscopy, muonic x rays, nuclear cosmochemistry, nuclear structure and reactions, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  1. Technical Report TR-013 March 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-013 Hydrology March 2001 Roberts Creek Study Forest: Pre-harvest chemical characteristics of three S6 creeks-751-7001 Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

  2. DOE Chair of Excellence in Environmental Disciplines-Final Technical Report

    SciTech Connect (OSTI)

    Kurunganty, Sastry; Lorn, Roberto; Roque-Malherbe, Rolando; Hijazi, Yazan; Nieto, Santander; Gmez, Will A.; Ducong, Jos; Cotto, Mara del C.; Muiz, Carlos; Daz, Francisco J.; Neira, Carlos F.; Mrquez, Francisco; Del Valle, W.; Thommes, M.

    2014-02-19T23:59:59.000Z

    The report Massie Chair of Excellence Program at Universidad del Turabo, contract DE-FG02-95EW12610, during the period of 9/29/1995 to 9/29/2011. The initial program aims included development of academic programs in the Environmental Sciences and Engineering, and Research and Development focused initially on environmentally friendly processes and later revised also include: renewable energy and international cooperation. From 1995 -2005, the Program at UT lead the establishment of the new undergraduate program in electrical engineering at the School of Engineering (SoE), worked on requirements to achieve ABET accreditation of the SoE B.S. Mechanical Engineering and B.S. Electrical Engineering programs, mentored junior faculty, taught undergraduate courses in electrical engineering, and revised the electrical engineering curriculum. Engineering undergraduate laboratories were designed and developed. The following research sub-project was developed: Research and development of new perovskite-alumina hydrogen permeable asymmetrical nanostructured membranes for hydrogen purification, and extremely high specific surface area silica materials for hydrogen storage in the form of ammonia, Dr. Rolando Roque-Malherbe Subproject PI, Dr. Santander Nieto and Mr. Will Gmez Research Assistants. In 2006, the Massie Chair of Excellence Program was transferred to the National Nuclear Security Agency, NNSA and DNN. DoE required a revised proposal aligned with the priorities of the Administration. The revised approved program aims included: (1) Research (2) Student Development: promote the development of minority undergraduate and graduate students through research teams, internships, conferences, new courses; and, (3) Support: (a) Research administration and (b) Dissemination through international conferences, the UT Distinguished Lecturer Series in STEM fields and at the annual Universidad del Turabo (UT) Researchers Conference. Research included: Sub-Project 1: Synthesis and Characterization of low Refractive Index Aerogel Silica for Cherenkov Counters- Dr. Rolando Roque-Malherbe Sub-project PI, Dr. Jose Duconge Sub-project Co-PI, Dr. Santander Nieto Assistant Researcher, Francisco Diaz and Carlos Neira Associate Researchers. The initial aim of this sub-project was changed to the synthesis and characterization of extremely high specific surface area aerogel silica for gas storage. A high specific surface area silica gel that has applications in gas drying, cleaning operation useful in nuclear industry in process was developed. Sub-Project 2: Investigation Study of Magnetic and Electronic Transport Properties at Material Interfaces in Magnetic Multilayer Heterostructure using Gd. Dr. Yazan Hijazi, Sub-project Co-PI. UT developed the capability and infrastructure to produce high quality thin-film magnetic films and magnetic multilayer structures with fine control over film quality and thickness using sputter deposition capability to perform in-house electric and magnetic characterization of these films. The research experimentally quantified the effect of Gd incorporation within the magnetic multilayer structure and produce magnetic media with exchanged decoupled multilevel magnetic anisotropy. From September 2006 to September 2011 the Massie Chair produced nineteen (19) publications, (including 3 books), five (5) presentations and three (3) international conferences abstracts. A total of fourteen (14) undergraduates and (6) graduate students acquired research experience. Two Ph.D. students presented their dissertations on topics related to nuclear energy and graduated as follows: Mara Cotto (May 2009) and Eric Caldern (May 2011). Five of the participating undergraduate students graduated: Ramon Polanco (BSME, May 2009), Jason Prez (BSEE, May 2008), Rafael Coln (BSME, May 2008), Jessenia Marfisi (BS Chemistry, May 2008). Eleven (11) students were sent to National Laboratories (LANL, SNL and LLNL), NNSA and DoE facilities for summer internships. Twenty eight (28) undergraduate students participated in Summer Internships (2010,

  3. Hydrophobicity of protein surfaces: Separating geometry from chemistry

    E-Print Network [OSTI]

    scenarios for events such as protein folding and directed self-assembly are summarized well in ref. 8, in the context of protein folding. The basic feature distinguishing these scenarios is the relationship between; the processes are sequential. Illustrative examples summarized from available protein folding studies (8

  4. Surface and Interface Science Physics 627; Chemistry 542

    E-Print Network [OSTI]

    Glashausser, Charles

    : Insulator; wide or narrow bandgap semiconductor; Superconductor; ferroelectric; multiferroic ; ... Focus+ Bridge and in-plane oxygen (1 x 1) LEED pattern, STM Rumpling and relaxation 3. Role of point defects rings, but some 5-member 4. Range of bond angles around 104 deg 5. Bridging and non-bridging oxygens

  5. Surface Chemistry DOI: 10.1002/anie.201402374

    E-Print Network [OSTI]

    Li, Weixue

    Catalysts in Propylene Oxidation with Molecular Oxygen** Qing Hua, Tian Cao, Xiang-Kui Gu, Jiqing Lu oxidation of propylene with O2 to propylene oxide and acrolein is of great interest and impor- tance. We, and rhombic dodecahedra in catalyzing propylene oxidation with O2: Cu2O octahedra exposing {111} crystal

  6. Surface chemistry control for selective fossil resin flotation

    DOE Patents [OSTI]

    Miller, Jan D. (1886 Atkin Ave., Salt Lake City, UT 84106); Yi, Ye (2875 E. Wander Way, Salt Lake City, UT 84117); Yu, Qiang (224 University Village, Salt Lake City, UT 84108)

    1994-01-01T23:59:59.000Z

    A froth flotation method is disclosed for separating fine particles of fossil resin from by use of frothing reagents which include an aliphatic organic compound having a polar group and containing not more than four carbon atoms. Butanol is an effective frothing reagent in this method.

  7. Correlation between surface chemistry, density and band gap in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of WO3 films. The XPS analyses indicate the formation of stoichiometric WO3 with tungsten existing in fully oxidized valence state (W6+). However, WO3 films grown at high...

  8. American Chemical Society Division of Colloid and Surface Chemistry

    E-Print Network [OSTI]

    Wagner, Oliver

    Crystals M. A. Banares, Organizer Papers 241-245 Synthesis and Structure of Organic and Inorganic Oxide, Organizer Papers 260-265 Synthesis and Structure of Organic and Inorganic Oxide or Sulfide Composites S. Banares, Organizer Papers 5-9 Applications of Porous Materials in Environmental Problems T. J. Bandosz

  9. Surface chemistry control for selective fossil resin flotation

    DOE Patents [OSTI]

    Miller, J.D.; Yi, Y.; Yu, Q.

    1994-06-07T23:59:59.000Z

    A froth flotation method is disclosed for separating fine particles of fossil resin by use of frothing reagents which include an aliphatic organic compound having a polar group and containing not more than four carbon atoms. Butanol is an effective frothing reagent in this method. 12 figs.

  10. Reaction chemistry and ligand exchange at cadmium selenide nanocrystal surfaces

    E-Print Network [OSTI]

    Owen, Jonathan

    2008-01-01T23:59:59.000Z

    E. ; Colvin, V. L. ; Alivisatos, A.P. J. Phys. Chem. 1994,Galli, G. ; Manna, L. ; Alivisatos, A. P. Nano Lett. 2004,L. W. ; Cingolani, R. ; Alivisatos, A. P. J. Phys. Chem. B

  11. Effect of Gold Nanorod Surface Chemistry on Cellular Response

    E-Print Network [OSTI]

    Grabinski, Christin

    Gold nanorods (GNRs) stabilized with cetyltrimethylammonium bromide (CTAB) and GNR functionalized via a ligand exchange method with either thiolated polyethylene glycol (PEG5000) or mercaptohexadecanoic acid (MHDA) were ...

  12. COORDINATION CHEMISTRY OF METAL SURFACES AND METAL COMPLEXES

    E-Print Network [OSTI]

    Muetterties, E.L.

    2013-01-01T23:59:59.000Z

    probable orientation of acetonitrile molecules bound to atwo isomeric molecules, acetonitrile and methyl isocyanide,of methyl isocyanide to acetonitrile within these nickel

  13. Towards a Molecular Scale Understanding of Surface Chemistry...

    Office of Scientific and Technical Information (OSTI)

    and pollution control; energy production (photoelectrochemical and production of hydrogen); and novel materials synthesis. times redirected to final destination ShortURL...

  14. The Novel ''Controlled Intermediate Nuclear Fusion'' and its Possible Industrial Realization as Predicted by Hadronic Mechanics and Chemistry

    E-Print Network [OSTI]

    Santilli, R M

    2006-01-01T23:59:59.000Z

    In this note, we propose, apparently for the first time, a new type of controlled nuclear fusion called "intermediate" because occurring at energies intermediate between those of the ''cold'' and ''hot'' fusions, and propose a specific industrial realization. For this purpose: 1) We show that known limitations of quantum mechanics, quantum chemistry and special relativity cause excessive departures from the conditions occurring for all controlled fusions; 2) We outline the covering hadronic mechanics, hadronic chemistry and isorelativity specifically conceived, constructed and verified during the past two decades for new cleans energies and fuels; 3) We identify seven physical laws predicted by the latter disciplines that have to be verified by all controlled nuclear fusions to occur; 4) We review the industrial research conducted to date in the selection of the most promising engineering realization as well as optimization of said seven laws; and 5) We propose with construction details a specific {\\it hadron...

  15. Orientation-Specific Attachment of Polymeric Microtubes on Cell Surfaces

    E-Print Network [OSTI]

    Gilbert, Jonathan B.

    Tubular particles presenting heterogeneous regions of chemistry on the tube-ends versus the side are fabricated and are shown to control the particle orientation on the surface of live lymphocytes. Controlling the orientation ...

  16. Penn State Multi-Discipline Tribology Group and Energy Institute Studies.

    SciTech Connect (OSTI)

    Perez, Joseph

    2001-08-05T23:59:59.000Z

    This presentation is a summary of the current research activities on fuels and lubricants in the Multi-discipline Tribology group and the engine test group in the Combustion Laboratory of the Pennsylvania State University. The progress areas discussed in this summary include those found in Table 1. Table 1. RESEARCH AREAS: Diesel Engine Emission Reduction; Oxygenated Fuels; Improved Friction Fuels; Vegetable Oil Lubricants; Extended Drain Lubricants; Effect of Chemical Structure on Friction and Wear. The research is of interest either directly or indirectly to the goal of this workshop, diesel engine emissions reduction. The current projects at Penn State in the areas listed above will be discussed.

  17. Chemistry Add-In for Word

    E-Print Network [OSTI]

    Townsend, Joseph A

    2011-07-05T23:59:59.000Z

    The Add-In (.NET) links a semantic chemistry engine (.NUMBO) through a command interface (CID) to a chemistry zone. Chemistry zones are textual or graphic renderings within a Word document (DOCX). All content and relationships are bound to CML... OOXML + CML Data publication difficult and unsupported Insufficient data to fully support research Data preparation integrated into user workflow Open Standards promote Open Semantic Science Domain aware software and semantic data allows...

  18. Surface tension in a reactive binary mixture of incompressible fluids

    E-Print Network [OSTI]

    Struchtrup, Henning

    Surface tension in a reactive binary mixture of incompressible fluids Henning Struchtrup Institute with a distributed form of surface tension. The model describes chemistry, diffusion, viscosity and heat transfer tension at the front. Keywords: Binary mixtures, Surface tension, Irreversible thermodynamics, Hele

  19. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization of SelectiveBrownFirstU.S. DOEChemistry

  20. THE ADVANCED CHEMISTRY BASINS PROJECT

    SciTech Connect (OSTI)

    William Goddard; Peter Meulbroek; Yongchun Tang; Lawrence Cathles III

    2004-04-05T23:59:59.000Z

    In the next decades, oil exploration by majors and independents will increasingly be in remote, inaccessible areas, or in areas where there has been extensive shallow exploration but deeper exploration potential may remain; areas where the collection of data is expensive, difficult, or even impossible, and where the most efficient use of existing data can drive the economics of the target. The ability to read hydrocarbon chemistry in terms of subsurface migration processes by relating it to the evolution of the basin and fluid migration is perhaps the single technological capability that could most improve our ability to explore effectively because it would allow us to use a vast store of existing or easily collected chemical data to determine the major migration pathways in a basin and to determine if there is deep exploration potential. To this end a the DOE funded a joint effort between California Institute of Technology, Cornell University, and GeoGroup Inc. to assemble a representative set of maturity and maturation kinetic models and develop an advanced basin model able to predict the chemistry of hydrocarbons in a basin from this input data. The four year project is now completed and has produced set of public domain maturity indicator and maturation kinetic data set, an oil chemistry and flash calculation tool operable under Excel, and a user friendly, graphically intuitive basin model that uses this data and flash tool, operates on a PC, and simulates hydrocarbon generation and migration and the chemical changes that can occur during migration (such as phase separation and gas washing). The DOE Advanced Chemistry Basin Model includes a number of new methods that represent advances over current technology. The model is built around the concept of handling arbitrarily detailed chemical composition of fluids in a robust finite-element 2-D grid. There are three themes on which the model focuses: chemical kinetic and equilibrium reaction parameters, chemical phase equilibrium, and physical flow through porous media. The chemical kinetic scheme includes thermal indicators including vitrinite, sterane ratios, hopane ratios, and diamonoids; and a user-modifiable reaction network for primary and secondary maturation. Also provided is a database of type-specific kerogen maturation schemes. The phase equilibrium scheme includes modules for primary and secondary migration, multi-phase equilibrium (flash) calculations, and viscosity predictions.

  1. CHEMISTRY AND CHEMICAL ENGINEERING DIVISION

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy FutureDepartmentCAIRSPlanning TimelineChemistry |CHARTERExponent,

  2. Better Enzymes for Biofuels and Green Chemistry

    E-Print Network [OSTI]

    Better Enzymes for Biofuels and Green Chemistry: Solving the Cofactor Imbalance Problem Imbalances for the production of biofuels or other valuable chemicals. Though several research groups have re

  3. 2005 American Conference on Theoretical Chemistry

    SciTech Connect (OSTI)

    Carter, Emily A

    2006-11-19T23:59:59.000Z

    The materials uploaded are meant to serve as final report on the funds provided by DOE-BES to help sponsor the 2005 American Conference on Theoretical Chemistry.

  4. Nanostructure, Chemistry and Crystallography of Iron Nitride...

    Broader source: Energy.gov (indexed) [DOE]

    Nanostructure, Chemistry and Crystallography of Iron Nitride Magnetic Materials by Ultra-High-Resolution Electron Microscopy and Related Methods DOE 2011 Vehicle Technologies...

  5. Chemistry of Organic Electronic Materials 6483-Fall

    E-Print Network [OSTI]

    Sherrill, David

    Chemistry of Organic Electronic Materials 6483- Fall Tuesdays organic materials. The discussion will include aspects of synthesis General introduction to the electronic structure of organic materials with connection

  6. Lithium Insertion Chemistry of Some Iron Vanadates

    E-Print Network [OSTI]

    Patoux, Sebastien; Richardson, Thomas J.

    2008-01-01T23:59:59.000Z

    in A. Nazri, G.Pistoia (Eds. ), Lithium batteries, Science &structure materials in lithium cells, for a lower limitLithium Insertion Chemistry of Some Iron Vanadates Sbastien

  7. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 L ast edited: 2014-06-02 08:56:54...

  8. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    forensics, and consequence management," Journal of Radioanalytical and Nuclear Chemistry, 1-18 (2012). Magen E. Coleman, Evelyn M. Bond, W. Allen Moody, and Lav Tandon,...

  9. Science at the Edge Traditionally distinct scientific disciplines are merging to create new

    E-Print Network [OSTI]

    The Technology Barrier to Advanced Batteries for Energy Storage October 8 - Quantitative Biology/Gene Expression Energy Conversion November 5 - Quantitative Biology/Gene Expression in Development & Disease Seminar Gary, Departments of Chemistry and Materials Science, State University of New York at Binghamton Materials

  10. CHEMISTRY 1 Faculty of Natural Sciences, Department of

    E-Print Network [OSTI]

    CHEMISTRY 1 Faculty of Natural Sciences, Department of --Chemistry This publication refers.imperial.ac.uk/pgprospectus. Chemistry Interests in chemistry at Imperial College cover physical, organic, inorganic, analytical, polymer and biological chemistry and chemical crystallography, as well as intersectional and medical topics

  11. Rev. 3/1/10 NEW.........Minor in Chemistry

    E-Print Network [OSTI]

    Chatterjee, Avik P.

    Rev. 3/1/10 NEW.........Minor in Chemistry The Department of Chemistry offers a minor in chemistry to students who wish to enhance their degrees with a strong concentration in this area. The Chemistry minor and enhances the records of students. The Chemistry minor provides a broad and general exposure

  12. ADVANCED INORGANIC LABORATORY FALL 2008 CHEMISTRY 410 (CRN 11299:), CHEMISTRY 510 (CRN 11315)

    E-Print Network [OSTI]

    Richmond, Geraldine L.

    materials and announcements will be posted on the site. Required Text: "Synthesis and Technique in InorganicADVANCED INORGANIC LABORATORY FALL 2008 CHEMISTRY 410 (CRN 11299:), CHEMISTRY 510 (CRN 11315 to a wide range of conceptual and practical (laboratory) inorganic chemistry. Because of the introductory

  13. Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2

    E-Print Network [OSTI]

    Weber, Rodney

    1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 Problem 1: Nighttime loss of NOx in the lower troposphere proceeds by: 1 Air Pollution Physics and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

  14. Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and

    E-Print Network [OSTI]

    CMR Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) building supports research and experimental activities for plutonium and uranium analytical chemistry and metallurgy. In 1952, the first LANL CMR facility was completed. At that time

  15. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect (OSTI)

    Butler, L.J. [Univ. of Chicago, IL (United States)

    1993-12-01T23:59:59.000Z

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  16. Modeling aluminum etch chemistry in high density plasmas

    SciTech Connect (OSTI)

    Meeks, E. [Sandia National Labs., Livermore, CA (United States); Ho, P.; Buss, R. [Sandia National Labs., Albuquerque, NM (United States)

    1997-08-01T23:59:59.000Z

    The authors have assembled a chemical reaction mechanism that describes the BCl{sub 3}/Cl{sub 2}/Ar plasma etch of Al metallization layers. The reaction set for gas-phase and surface processes was derived either from literature data or estimated from data on related systems. A well-mixed reactor model was used to develop the mechanism and test it against experimental measurements of plasma species and etch-rates in processing reactors. Finally, use of reduced chemistry mechanisms are demonstrated in 2-D simulations for a complex reactor geometry.

  17. Modelling the sulphur chemistry evolution in Orion KL

    E-Print Network [OSTI]

    Esplugues, G B; Goicoechea, J R; Cernicharo, J

    2014-01-01T23:59:59.000Z

    We study the sulphur chemistry evolution in the Orion KL along the gas and grain phases of the cloud. We investigate the processes that dominate the sulphur chemistry and to determine how physical and chemical parameters, such as the final star mass and the initial elemental abundances, influence the evolution of the hot core and of the surrounding outflows and shocked gas (the plateau). We independently modelled the chemistry evolution of both components using the time-dependent gas-grain model UCL_CHEM and considering two different phase calculations. Phase I starts with the collapsing cloud and the depletion of atoms and molecules onto grain surfaces. Phase II starts when a central protostar is formed and the evaporation from grains takes place. We show how the gas density, the gas depletion efficiency, the initial sulphur abundance, the shocked gas temperature and the different chemical paths on the grains leading to different reservoirs of sulphur on the mantles affect sulphur-bearing molecules at differ...

  18. Chemistry -Bachelor of Science (SCH3UG) Total Credits Required: 128 Chemistry/Secondary Education -ACS Certified

    E-Print Network [OSTI]

    Chemistry - Bachelor of Science (SCH3UG) Total Credits Required: 128 Chemistry/Secondary Education - 40 credits Course Credits Course Credits CH1150 University Chemistry I AND 3 CH3020 Laboratory Teaching Internship 2 CH1151 University Chemistry Lab 1 AND 1 CH4810 Design/Oper of High School Chemistry

  19. Study of Heterogeneouse Processes Related to the Chemistry of Tropospheric Oxidants and Aerosols

    SciTech Connect (OSTI)

    Davidovits, Paul; Worsnop, D R; Jayne, J T; Colb, C E

    2013-02-13T23:59:59.000Z

    The objective of the studies was to elucidate the heterogeneous chemistry of tropospheric aerosols. Experiments were designed to measure both specifically needed parameters, and to obtain systematic data required to build a fundamental understanding of the nature of gas-surface physical and chemical interactions

  20. Interactive chemistry in the Laboratoire de Meteorologie Dynamique general circulation model

    E-Print Network [OSTI]

    Hourdin, Chez Frdric

    of soluble species. The global and annual mean methane (7.9 years) and methylchloroform (4.6 years) chemical chemical scheme representative of the background chemistry of the troposphere is considered. We derive rapid interhemispheric exchange times of 1.13 1.38 years and 0.700.82 years, based on surface

  1. Comparison of plasma chemistries for inductively coupled plasma etching of InGaAlP alloys

    SciTech Connect (OSTI)

    Hong, J.; Lee, J.W.; Abernathy, C.R.; Lambers, E.S.; Pearton, S.J. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States)] [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Shul, R.J. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States)] [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Hobson, W.S. [Bell Laboratories, Lucent Technologies, Murray Hill, New Jersey 07974 (United States)] [Bell Laboratories, Lucent Technologies, Murray Hill, New Jersey 07974 (United States)

    1998-05-01T23:59:59.000Z

    Two plasma chemistries, i.e., CH{sub 4}/H{sub 2}/Ar and Cl{sub 2}/Ar, were compared for the etching of InGaP, AlInP, and AlGaP under inductively coupled plasma (ICP) conditions. While the etching with CH{sub 4}/H{sub 2}/Ar discharges appears to be ion driven, Cl{sub 2}/Ar discharges showed an additional strong chemical enhancement. The highest etch rate ({approximately}1 {mu}m/min) for InGaP was achieved at high ICP source power ({ge}750 W) with the Cl{sub 2}/Ar chemistry. Cl{sub 2}/Ar discharges provided very smooth surfaces in all three materials with root-mean-square roughness measured by atomic force microscopy around 2 nm. This result may be due to the efficient ion-assisted product desorption in this chemistry. The etched near-surface region of InGaP ({approximately}100 {Angstrom}) with Cl{sub 2}/Ar maintained almost the same stoichiometry as that of the unetched control. By contrast, the CH{sub 4}/H{sub 2}/Ar plasma chemistry produced somewhat rougher surfaces and depletion of phosphorous (P) from the surface of InGaP. {copyright} {ital 1998 American Vacuum Society.}

  2. Effects of broadleaf woodland cover on streamwater chemistry and risk assessments of streamwater acidification in acid-sensitive catchments in the UK

    E-Print Network [OSTI]

    Gagkas, Zisis

    2007-01-01T23:59:59.000Z

    Acidification of surface waters has been recognised as the major water quality problem in the UK uplands. The adverse effects of conifer afforestation on streamwater chemistry and ecology are well documented in ...

  3. Goal: Understand some of the basic principles of the chemistry of earth science and envi- Knowledge necessary for solving current and emerging problems

    E-Print Network [OSTI]

    Schofield, Jeremy

    Overview Goal: Understand some of the basic principles of the chemistry of earth science and envi; Turbulent due to heat of earth's surface: lots of mixing ! giant chemical reactor #15; Clouds and rain

  4. Chemistry-Nuclear Chemistry Division. Progress report, October 1980-September 1981

    SciTech Connect (OSTI)

    Ryan, R.R. (comp.)

    1982-05-01T23:59:59.000Z

    This report describes major progress in the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory during FY 1981. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, medical radioisotopes research, element migration and fixation, nuclear waste isolation research, inorganic and structural chemistry, isotope separation, analysis and applications, the newly established Nuclear Magnetic Resonance Center, atomic and molecular collisions, molecular spectroscopy, nuclear cosmochemistry, nuclear structure and reactions, pion charge exchange, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  5. Postdoctoral Researcher, Materials Chemistry (2 year contract)

    E-Print Network [OSTI]

    Humphrys, Mark

    Postdoctoral Researcher, Materials Chemistry (2 year contract) Adaptive Sensors Group Dublin City Foundation Ireland through the CLARITY CSET (www.clarity- centre.org), supplemented by significant project partners. The group's research strategy in materials chemistry research is to closely align activity

  6. Analytical Chemistry Division's sample transaction system

    SciTech Connect (OSTI)

    Stanton, J.S.; Tilson, P.A.

    1980-10-01T23:59:59.000Z

    The Analytical Chemistry Division uses the DECsystem-10 computer for a wide range of tasks: sample management, timekeeping, quality assurance, and data calculation. This document describes the features and operating characteristics of many of the computer programs used by the Division. The descriptions are divided into chapters which cover all of the information about one aspect of the Analytical Chemistry Division's computer processing.

  7. Ash Chemistry in MSW Incineration Plants

    E-Print Network [OSTI]

    Ash Chemistry in MSW Incineration Plants: Advanced Characterization and Thermodynamic Introduction to Municipal Solid Waste Incineration 2 Chapter 2 Plants Considered and Samples Collected 5 Chapter 3 Mapping of Ash Chemistry in MSWI Plants 8 Chapter 4 Advanced Characterization Methods 12 4

  8. Richard T. Oakley FRSC, Professor of Chemistry

    E-Print Network [OSTI]

    Le Roy, Robert J.

    Interests: Synthesis and solid state transport properties of open shell inorganic and organic ring systems. Heavy atom radicals as multifunctional molecular conductors and magnetic materials. Academic Background: B.Sc., 1969, Honours Chemistry, University of British Columbia M.Sc., 1970, Inorganic Chemistry

  9. Exploring Chemistry Using SMT Rolf Fagerberg1

    E-Print Network [OSTI]

    Flamm, Christoph

    Exploring Chemistry Using SMT Rolf Fagerberg1 , Christoph Flamm2 , Daniel Merkle1 , Philipp Peters1 power of Satisfiability Modulo Theory (SMT) solvers. We show results for an analysis of the Pentose in the usage of SMT for expressing search problems in chemistry, and in the generality of its resulting

  10. Chemistry 593: Stirling's Formula David Ronis

    E-Print Network [OSTI]

    Ronis, David M.

    Chemistry 593: Stirling's Formula © David Ronis McGill University There is a simple way to obtain) Winter, 2014 #12;Chemistry 593 -2- Stirling's Formula which implies that ln(x!)x ln(x) - x + ln[(2 x)1/2 ]. (4') Clearly, for xO(1023 ), the last logarithm is negligible, and the simple form of Stirling

  11. advanced organic chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 21 SYLLABUS for CHEMISTRY 2310 ORGANIC CHEMISTRY 1 Chemistry Websites Summary: Discussion...

  12. Chemistry -Bachelor of Science (SCH4UG) Total Credits Required: 128 Chemistry/Chemical Physics -ACS Certified

    E-Print Network [OSTI]

    Chemistry I 3 PH4210 Electricity and Magnetism I 3 CH3511 Physical Chemistry Lab I 2 PH4510 Intro to Solid Analysis 5 General Education Requirements - 28 credits CH4310 Inorganic Chemistry I 3 UN1001 Perspectives

  13. NERSC training events: Data Transfer and Archiving; Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications NERSC training events: Data Transfer and Archiving; Chemistry and Material Sciences...

  14. June 26 Training: Using Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 26 Training: Using Chemistry and Material Sciences Applications June 26 Training: Using Chemistry and Material Sciences Applications June 15, 2012 by Francesca Verdier (0...

  15. Materials Science and Materials Chemistry for Large Scale Electrochemi...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid Materials Science and Materials Chemistry for Large Scale...

  16. analytical chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from Analytical Chemistry, 1990, 62. Copyright 0 1990 by the American Chemical Society Ion Source Mark van Straaten,* Akos Vertes,' and Renaat Gijbels Department of Chemistry,...

  17. analytical chemistry division: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from Analytical Chemistry, 1990, 62. Copyright 0 1990 by the American Chemical Society Ion Source Mark van Straaten,* Akos Vertes,' and Renaat Gijbels Department of Chemistry,...

  18. analytical chemistry biochemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from Analytical Chemistry, 1990, 62. Copyright 0 1990 by the American Chemical Society Ion Source Mark van Straaten,* Akos Vertes,' and Renaat Gijbels Department of Chemistry,...

  19. analytical chemistry dac: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from Analytical Chemistry, 1990, 62. Copyright 0 1990 by the American Chemical Society Ion Source Mark van Straaten,* Akos Vertes,' and Renaat Gijbels Department of Chemistry,...

  20. Enriched Stable Isotope Materials and Chemistry | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Chemistry SHARE Enriched Stable Isotope Materials and Chemistry Reductiondistillation of calcium-48 metal valued at over 900,000. An inventory of 2,300 batches of...

  1. Private Company Uses EERE-Supported Chemistry Model to Substantially...

    Office of Environmental Management (EM)

    Private Company Uses EERE-Supported Chemistry Model to Substantially Improve Combustion Engine Simulation Software Private Company Uses EERE-Supported Chemistry Model to...

  2. association chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Gao, Chemistry Don Truhlar, Chemistry February 2007 12;Zn Metalloprotein Force Field Design Zn: unusual coordination, charge distribution at transition states in...

  3. activation chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Gao, Chemistry Don Truhlar, Chemistry February 2007 12;Zn Metalloprotein Force Field Design Zn: unusual coordination, charge distribution at transition states in...

  4. applied chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Gao, Chemistry Don Truhlar, Chemistry February 2007 12;Zn Metalloprotein Force Field Design Zn: unusual coordination, charge distribution at transition states in...

  5. applied edman chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Gao, Chemistry Don Truhlar, Chemistry February 2007 12;Zn Metalloprotein Force Field Design Zn: unusual coordination, charge distribution at transition states in...

  6. ainse radiation chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Gao, Chemistry Don Truhlar, Chemistry February 2007 12;Zn Metalloprotein Force Field Design Zn: unusual coordination, charge distribution at transition states in...

  7. atropisomeric lactam chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Gao, Chemistry Don Truhlar, Chemistry February 2007 12;Zn Metalloprotein Force Field Design Zn: unusual coordination, charge distribution at transition states in...

  8. Distance-dependent radiation chemistry: Oxidation versus hydrogenation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Distance-dependent radiation chemistry: Oxidation versus hydrogenation of CO in electron-irradiated H2OCOH2O ices. Distance-dependent radiation chemistry: Oxidation versus...

  9. High Level Computational Chemistry Approaches to the Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Level Computational Chemistry Approaches to the Prediction of Energetic Properties of Chemical Hydrogen Storage Systems High Level Computational Chemistry Approaches to the...

  10. applied inorganic chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bus.Admin.Public Admin. Chemical Engineering Chem. Eng.Comp. Sci. Chemistry Civil Engineering Heller, Barbara 6 Role of inorganic chemistry on nuclear energy examined...

  11. Molecular Chemistry of Organic Aerosols Through the Application...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Organic Aerosols Through the Application of High Resolution Mass Spectrometry. Molecular Chemistry of Organic Aerosols Through the Application of High Resolution Mass...

  12. analytical chemistry general: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for students who have a prepared background in chemistry Ravikumar, B. 4 General syllabus for third-cycle studies in Technical Analytical Chemistry This syllabus has been...

  13. advanced physical chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    material listed extended material on chemical kinetcs. (The topics covered are in the Syllabus below.) This means that Raina, Ramesh 2 CHEMISTRY 521 GRADUATE PHYSICAL CHEMISTRY...

  14. atmospheric physical chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1999, Michigan Technological University, Houghton, MI Ph.D. in Chemistry 8 Course Syllabus ATMO 613: Advanced Atmospheric Chemistry (Spring 2014) Geosciences Websites Summary:...

  15. Plastic Bags to Batteries: A Green Chemistry Solution | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plastic Bags to Batteries: A Green Chemistry Solution Share Description Plastic bags are the scourge of roadsides, parking lots and landfills. But chemistry comes to the rescue At...

  16. MAY 14, 2008 Chemistry and environmental science professor receives Carroll

    E-Print Network [OSTI]

    Reid, Scott A.

    MAY 14, 2008 Chemistry and environmental science professor receives Carroll College faculty award WAUKESHA, WIS.-- An associate professor of chemistry and environmental science has received an annual

  17. aggregation chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mission Statement The Sawyer Environmental Chemistry Research Laboratory is a multi industry. The Sawyer Environmental Chemistry Research Laboratory employs advanced analytical...

  18. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemistry and Cetane Effects on HCCI Performance, Combustion, and Emissions Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels Derived from Heavy Crude Sources...

  19. applied chemistry division: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their independent research identity and become a chemistry research leader of the future. Funding for the most Oxford, University of 6 DIVISION OF MARINE AND ATMOSPHERIC CHEMISTRY...

  20. Substrate Changes Associated with the Chemistry of Self-Assembled...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Substrate Changes Associated with the Chemistry of Self-Assembled Monolayers on Silicon. Substrate Changes Associated with the Chemistry of Self-Assembled Monolayers on Silicon....

  1. New Mass Spectrometry Techniques for Studying Physical Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mass Spectrometry Techniques for Studying Physical Chemistry of Atmospheric Heterogeneous Processes. New Mass Spectrometry Techniques for Studying Physical Chemistry of Atmospheric...

  2. Redox Chemistry in Thin Layers of Organometallic Complexes Prepared...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft Landing. Redox Chemistry in Thin Layers of Organometallic Complexes Prepared Using Ion Soft...

  3. Chemistry and cooling in metal-free and metal-poor gas

    E-Print Network [OSTI]

    S. C. O. Glover

    2007-09-04T23:59:59.000Z

    I summarize four of the most important areas of uncertainty in the study of the chemistry and cooling of gas with zero or very low metallicity. These are: i) the importance and effects of HD cooling in primordial gas; ii) the importance of metal-line and dust cooling in low metallicity gas; iii) the impact of the large uncertainties that exist in the rate coefficients of several key reactions involved in the formation of H2; and iv) the effectiveness of grain surface chemistry at high redshifts.

  4. Chemistry Division annual progress report for period ending January 31, 1984

    SciTech Connect (OSTI)

    Not Available

    1984-05-01T23:59:59.000Z

    Progress is reported in the following fields: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, high-temperature chemistry and thermodynamics of structural materials, chemistry of transuranium elements and compounds, separations chemistry, elecrochemistry, catalysis, chemical physics, theoretical chemistry, nuclear waste chemistry, chemistry of hazardous chemicals, and thermal energy storage.

  5. Intermediate-energy nuclear chemistry workshop

    SciTech Connect (OSTI)

    Butler, G.W.; Giesler, G.C.; Liu, L.C.; Dropesky, B.J.; Knight, J.D.; Lucero, F.; Orth, C.J.

    1981-05-01T23:59:59.000Z

    This report contains the proceedings of the LAMPF Intermediate-Energy Nuclear Chemistry Workshop held in Los Alamos, New Mexico, June 23-27, 1980. The first two days of the Workshop were devoted to invited review talks highlighting current experimental and theoretical research activities in intermediate-energy nuclear chemistry and physics. Working panels representing major topic areas carried out indepth appraisals of present research and formulated recommendations for future research directions. The major topic areas were Pion-Nucleus Reactions, Nucleon-Nucleus Reactions and Nuclei Far from Stability, Mesonic Atoms, Exotic Interactions, New Theoretical Approaches, and New Experimental Techniques and New Nuclear Chemistry Facilities.

  6. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry OxideChemistry ofChemistry

  7. Institute of Physical Chemistry, Physical Chemistry of Condensed Matter

    E-Print Network [OSTI]

    Weick, Guillaume - IPCMS

    ,anchored` redox molecules: Objectives: Microcalorimetry: - ferrocene modified thiols on Au - viologenes Institute of Technology, Germany -microcalorimetry of electrochemical redox reactions -tunneling.00.50.0-0.5 tunnel voltage (V) -0.20 -0.15 -0.10 -0.05 0.00 dI/dU(a.u.) Redox Reactions at Electrode Surfaces sovent

  8. 4 Chemistry4 Chemistry Spring 2000 Chemists Shed Light on

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    a molecule that gelled the highly pressurized CO2. "Then we had another surprise," said Yale chemist Andrew step, he said, will be to improve the viscos- ity-enhancing properties of the CO2-gelling molecules, we can create small hot spots with temperatures as high as a star surface, pressures as great

  9. Temperature-responsive surface-functionalized polyethylene films

    E-Print Network [OSTI]

    Ponder, Bill C.

    1998-01-01T23:59:59.000Z

    which do not use wet chemistry have been used. Plasma treatment is a commonly used technique in industry. " In plasma modification, the types of functional groups, introduced onto the target surface depend on the plasma gas used. Oxygen plasma... on the surface of the modified surface as a function of plasma exposure time. At treatment times of 0. 5-2. 0 minutes, the atomic concentration of fluorine at the surface decreased and the oxygen concentration increased. However, after 15 minutes of plasma...

  10. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Soil Surface Soil We compare local soil samples with samples collected from northern New Mexico locations that are beyond the range of potential influence from normal...

  11. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M. (Scotia, NY)

    1989-01-01T23:59:59.000Z

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  12. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M. (Scotia, NY)

    1990-01-01T23:59:59.000Z

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  13. Pollution of Natural Waters 1. Redox chemistry

    E-Print Network [OSTI]

    Schofield, Jeremy

    . Eutrophication 4. Water treatment 1. Redox chemistry #15; Principle of equilibration of chemical system R Keq;sh and other aquatic life { Shift to anaerobic metabolic mechanisms #15; Eutrophication: agin

  14. CHEMISTRY OF SILICA IN CERRO PRIETO BRINES

    E-Print Network [OSTI]

    Weres, O.

    2012-01-01T23:59:59.000Z

    chemistry of silica in Cerro Prieto brine may profitably be14 mgl-1 AND SYNTHFTIC CERRO PRIETO BRINES High Ca We112Q.by the CFE Laboratory at Cerro Prieto and kindly provided to

  15. Computational Science and Engineering Certification for Chemistry

    E-Print Network [OSTI]

    Gilbert, Matthew

    Computational Science and Engineering Certification for Chemistry The Computational Science that are distinct from already- required coursework. To receive a certificate in "Computational Science a solid base in problem solving using computation as a major tool for modeling complicated problems

  16. Eugene R. Zubarev Department of Chemistry

    E-Print Network [OSTI]

    Zubarev, Eugene

    , amphiphilic structures. Experimental: organic synthesis, polymerization, synthesis of inorganic nanocrystals-2005 Assistant Professor of Materials Science and Engineering, Iowa State University 2000-2002 Research Associate and supramolecular chemistry, molecular self-assembly, organic-inorganic hybrid structures, nanoparticle catalysts

  17. February 11, 1987 I Inorganic Chemistry

    E-Print Network [OSTI]

    Girolami, Gregory S.

    Volume 26 Number 3 February 11, 1987 I Inorganic Chemistry 0 Copyright 1987 by the American uranium phthalocyanine derivatives have been crystallographically (I) (a) Kasuga, K.; Tsutsui, M. Coord

  18. Graduate Profile Chemistry & PhysiCs

    E-Print Network [OSTI]

    Graduate Profile Chemistry & PhysiCs "...I am helping to develop low-cost solar technology." Ricky to develop low-cost solar technology. The aim of my project is to achieve increased light absorption in thin

  19. Physics and chemistry of gas in discs

    E-Print Network [OSTI]

    Tilling, Ian

    2013-11-28T23:59:59.000Z

    Protoplanetary discs set the initial conditions for planet formation. By combining observations with detailed modelling, it is possible to constrain the physics and chemistry in such discs. I have used the detailed ...

  20. Chemistry in Higher What's available and where is the info?

    E-Print Network [OSTI]

    Anderson, Jim

    Chemistry in Higher Education What's available and where is the info? What does studying chemistry? Where does it lead and what might a chemistry career look like? Dr. David Read, Director of Outreach 2013 #12;310 (294) HE courses with chemistry offered as a single subject hosted at 53 universities 699

  1. Chemistry 100 Fall 2011 Page 1 of 5

    E-Print Network [OSTI]

    Indiana University

    Chemistry 100 Fall 2011 Page 1 of 5 The World of Chemistry Course Syllabus Instructor Kirkwood Hall 212 Texts: Required: Chemistry in Context (CC) Course information is online through OnCourse. Course Objective(s): The primary goal of this course is to teach you about the chemistry that surrounds

  2. MAJOR TO CAREER GUIDE B.A. Chemistry

    E-Print Network [OSTI]

    Walker, Lawrence R.

    MAJOR TO CAREER GUIDE B.A. Chemistry College of Sciences www.unlv.edu/chemistry Mission of the College of Sciences The College of Sciences offers programs in life sciences, chemistry, geoscience: 702-895-2077 Campus Location: MPE-A 130 www.unlv.edu/sciences/advising About the Chemistry Career

  3. MAJOR TO CAREER GUIDE B.S. Chemistry

    E-Print Network [OSTI]

    Walker, Lawrence R.

    MAJOR TO CAREER GUIDE B.S. Chemistry College of Sciences www.unlv.edu/chemistry Mission of the College of Sciences The College of Sciences offers programs in life sciences, chemistry, geoscience: 702-895-2077 Campus Location: MPE-A 130 www.unlv.edu/sciences/advising Chemistry Career Options

  4. Chemistry Major and Minor www.chem.pitt.edu

    E-Print Network [OSTI]

    Jiang, Huiqiang

    Chemistry Major and Minor www.chem.pitt.edu Revised: 10/2012 Chemistry is the most central disease, and processes to provide energy for societal needs. Chemistry plays an ever-increasing role design and ceramics. The bachelor's degree in chemistry consists of core courses in four primary areas

  5. ISSN 1463-9076 Physical Chemistry Chemical Physics

    E-Print Network [OSTI]

    Alavi, Ali

    on structural a London Centre for Nanotechnology and Department of Chemistry, University College London, London

  6. Animal Health Diagnostic Center Test and Fee Schedule Test Name Test Fee Discipline Test Days Lag** Samples Container Coolant Comments

    E-Print Network [OSTI]

    Keinan, Alon

    Animal Health Diagnostic Center Test and Fee Schedule Test Name Test Fee Discipline Test Days Lag** Samples Container Coolant Comments Equine Tests Equine Tests Acid Fast Stain (for bacteria) M-F 1-2 days 1 4 hours for equine. For more information, see Equine Cushing's Tests or AppendixC. For Equine only

  7. FUNDAMENTAL IMPACTS A Study of the Cross-Discipline and Societal Benefits of UK Research in Particle Physics

    E-Print Network [OSTI]

    Crowther, Paul

    a wide variety of other disciplines, particularly those in the medical and life sciences. Despite prodigious advances in our knowledge of fundamental physics, there remain many unanswered questions that will require significant technological innovation to address. This innovation will enable advances to be made

  8. UCF-3.0124 Discipline and Termination for Cause of Non-unit Faculty and A&P Staff Members.

    E-Print Network [OSTI]

    Van Stryland, Eric

    UCF-3.0124 Discipline and Termination for Cause of Non-unit Faculty and A&P Staff Members. (1) Just cause shall be defined as: (a) Incompetence; or (b) Misconduct. (2) Termination and Suspension. (a) The appointment of a non-unit faculty or an A&P staff member may be terminated or suspended during its term

  9. Chemistry -Bachelor of Science (SCH2UG) Total Credits Required: 128 Chemistry/Biochemistry -ACS Certified

    E-Print Network [OSTI]

    of the following courses 3 CH1122 University Chemistry - Studio Lab II 5 BL3300 Introduction to Genomics 3 CH1130

  10. Ramon Eritja Nucleic Acid Chemistry Group

    E-Print Network [OSTI]

    Ritort, Felix

    Ramon Eritja Nucleic Acid Chemistry Group Chemistry and Molecular Pharmacology Dpt. IRB Barcelona nanoparticle assemblies. #12;The DNA can be used as template for the fabrication of silver nanowires between;Preparation of thiol-functionalized arrays N N O NH S-St Bu N N O NH S-St Bu N N O NH S-St BuO DMT-O O P O N

  11. Chemistry 365: Stirling's Formula David Ronis

    E-Print Network [OSTI]

    Ronis, David M.

    Chemistry 365: Stirling's Formula © David Ronis McGill University There is a simple way to obtain;Chemistry 365 -2- Stirling's Formula x!(2 )1/2 xx+1/2 e-x , (4) which implies that ln(x!)x ln(x) - x + ln[(2 of Stirling's formula ln(x!)x[ln(x) - 1], is obtained. With a little extra effort you can work out the next

  12. Exhaust Phosphorous Chemistry | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:RevisedAdvisoryStandardGenerationEducationalChemistry Exhaust Phosphorous Chemistry

  13. Stephen L. Morgan, Department of Chemistry & Biochemistry, University of South Carolina, 2014. 1 Department of Chemistry & Biochemistry

    E-Print Network [OSTI]

    Morgan, Stephen L.

    "that is "similar to gasoline in flammability," said Rick L. Danheiser, professor of chemistry and chairStephen L. Morgan, Department of Chemistry & Biochemistry, University of South Carolina, 2014. 1 Department of Chemistry & Biochemistry The University of South Carolina USC Chemistry & Biochemistry Safety

  14. 2011 Chemical Reactions at Surfaces Gordon Research Conference

    SciTech Connect (OSTI)

    Peter Stair

    2011-02-11T23:59:59.000Z

    The Gordon Research Conference on Chemical Reactions at Surfaces is dedicated to promoting and advancing the fundamental science of interfacial chemistry and physics by providing surface scientists with the foremost venue for presentation and discussion of research occurring at the frontiers of their fields.

  15. Phase chemistry and radionuclide retention from simulated tank sludges

    SciTech Connect (OSTI)

    KRUMHANSL,JAMES L.; LIU,J.; ARTHUR,SARA E.; HUTCHERSON,SHEILA K.; QIAN,MORRIS; ANDERSON,HOWARD L.

    2000-05-19T23:59:59.000Z

    Decommissioning high level nuclear waste tanks will leave small amounts of residual sludge clinging to the walls and floor of the structures. The permissible amount of material left in the tanks depends on the radionuclide release characteristics of the sludge. At present, no systematic process exists for assessing how much of the remaining inventory will migrate, and which radioisotopes will remain relatively fixed. Working with actual sludges is both dangerous and prohibitively expensive. Consequently, methods were developed for preparing sludge simulants and doping them with nonradioactive surrogates for several radionuclides and RCRA metals of concern in actual sludges. The phase chemistry of these mixes was found to be a reasonable match for the main phases in actual sludges. Preliminary surrogate release characteristics for these sludges were assessed by lowering the ionic strength and pH of the sludges in the manner that would occur if normal groundwater gained access to a decommissioned tank. Most of the Se, Cs and Tc in the sludges will be released into the first pulse of groundwater passing through the sludge. A significant fraction of the other surrogates will be retained indefinitely by the sludges. This prolonged sequestration results from a combination coprecipitated and sorbed into or onto relatively insoluble phases such as apatite, hydrous oxides of Fe, Al, Bi and rare earth oxides and phosphates. The coprecipitated fraction cannot be released until the host phase dissolves or recrystallizes. The sorbed fraction can be released by ion exchange processes as the pore fluid chemistry changes. However, these releases can be predicted based on a knowledge of the fluid composition and the surface chemistry of the solids. In this regard, the behavior of the hydrous iron oxide component of most sludges will probably play a dominant role for many cationic radionuclides while the hydrous aluminum oxides may be more important in governing anion releases.

  16. Inorganic water chemistry 71 Chapter 4 -Inorganic Water Chemistry of the Boulder Creek

    E-Print Network [OSTI]

    Inorganic water chemistry 71 Chapter 4 - Inorganic Water Chemistry of the Boulder Creek Watershed Creek Watershed, Colorado were determined on a suite of water samples collected during high and low flow sixteen stream sites, twelve tributaries/inflows, and Saint Vrain Creek. The most upstream site was above

  17. Chemistry Impacts in Gasoline HCCI

    SciTech Connect (OSTI)

    Szybist, James P [ORNL; Bunting, Bruce G [ORNL

    2006-09-01T23:59:59.000Z

    The use of homogeneous charge compression ignition (HCCI) combustion in internal combustion engines is of interest because it has the potential to produce low oxides of nitrogen (NOx) and particulate matter (PM) emissions while providing diesel-like efficiency. In HCCI combustion, a premixed charge of fuel and air auto-ignites at multiple points in the cylinder near top dead center (TDC), resulting in rapid combustion with very little flame propagation. In order to prevent excessive knocking during HCCI combustion, it must take place in a dilute environment, resulting from either operating fuel lean or providing high levels of either internal or external exhaust gas recirculation (EGR). Operating the engine in a dilute environment can substantially reduce the pumping losses, thus providing the main efficiency advantage compared to spark-ignition (SI) engines. Low NOx and PM emissions have been reported by virtually all researchers for operation under HCCI conditions. The precise emissions can vary depending on how well mixed the intake charge is, the fuel used, and the phasing of the HCCI combustion event; but it is common for there to be no measurable PM emissions and NOx emissions <10 ppm. Much of the early HCCI work was done on 2-stroke engines, and in these studies the CO and hydrocarbon emissions were reported to decrease [1]. However, in modern 4-stroke engines, the CO and hydrocarbon emissions from HCCI usually represent a marked increase compared with conventional SI combustion. This literature review does not report on HCCI emissions because the trends mentioned above are well established in the literature. The main focus of this literature review is the auto-ignition performance of gasoline-type fuels. It follows that this discussion relies heavily on the extensive information available about gasoline auto-ignition from studying knock in SI engines. Section 2 discusses hydrocarbon auto-ignition, the octane number scale, the chemistry behind it, its shortcomings, and its relevance to HCCI. Section 3 discusses the effects of fuel volatility on fuel and air mixing and the consequences it has on HCCI. The effects of alcohol fuels on HCCI performance, and specifically the effects that they have on the operable speed/load range, are reviewed in Section 4. Finally, conclusions are drawn in Section 5.

  18. Chemistry of Water Collected From an Unventilated Drift, Yucca Mountain, Nevada

    SciTech Connect (OSTI)

    Marshall, Brian D.; Peterman, Zell E. [WRD/YMPB, U.S. Geological Survey, WRD MS 963, Denver Federal Center, Denver, CO, 80225-0046 (United States); Oliver, Thomas A. [WRD/YMPB, S.M. Stoller Corp., c/o U.S. Geological Survey, WRD MS 963, Denver Federal Center, Denver, CO, 80225-0046 (United States)

    2007-07-01T23:59:59.000Z

    Water samples (referred to as puddle water samples) were collected from the surfaces of a conveyor belt and plastic sheeting in the unventilated portion of the Enhanced Characterization of the Repository Block (ECRB) Cross Drift in 2003 and 2005 at Yucca Mountain, Nevada. The chemistry of these puddle water samples is very different than that of pore water samples from borehole cores in the same region of the Cross Drift or than seepage water samples collected from the Exploratory Studies Facility tunnel in 2005. The origin of the puddle water is condensation on surfaces of introduced materials and its chemistry is dominated by components of the introduced materials. Large CO{sub 2} concentrations may be indicative of localized chemical conditions induced by biologic activity. (authors)

  19. Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles

    E-Print Network [OSTI]

    Burke, Andrew; Miller, Marshall

    2009-01-01T23:59:59.000Z

    Whether any of the lithium battery chemistries can meetgeneral the higher cost lithium battery chemistries have thecosts for various lithium battery chemistries Electrode

  20. Reduction Chemistry of Rare-Earth Metal Complexes: Toward New Reactivity and Properties

    E-Print Network [OSTI]

    Huang, Wenliang

    2013-01-01T23:59:59.000Z

    and Chemistry of Rare Earths; Karl A. Gschneidner, Jr. ,and Chemistry of Rare Earths; Karl A. Gschneidner, Jr. ,and Chemistry of Rare Earths; Gschneidner, K. A. , Bnzli,

  1. DEUTERIUM CHEMISTRY IN PROTOPLANETARY DISKS. II. THE INNER 30 AU

    SciTech Connect (OSTI)

    Willacy, K. [Jet Propulsion Laboratory, California Institute of Technology, MS 169-506, Pasadena, CA 91109 (United States); Woods, P. M., E-mail: Karen.Willacy@jpl.nasa.go, E-mail: Paul.Woods@manchester.ac.u [Jodrell Bank Centre for Astrophysics, Alan Turing Building, School of Physics and Astronomy, University of Manchester, Oxford Road, Manchester, M13 9PL (United Kingdom)

    2009-09-20T23:59:59.000Z

    We present the results of models of the chemistry, including deuterium, in the inner regions of protostellar disks. We find good agreement with recent gas-phase observations of several (non-deuterated) species. We also compare our results with observations of comets and find that in the absence of other processing, e.g., in the accretion shock at the surface of the disk, or by mixing in the disk, the calculated D/H ratios in ices are higher than measured and reflect the D/H ratio set in the molecular cloud phase. Our models give quite different abundances and molecular distributions to other inner disk models because of the differences in physical conditions in the model disk. This emphasizes how changes in the assumptions about the density and temperature distribution can radically affect the results of chemical models.

  2. The chemistry of particulate formation in fluorocarbon plasmas

    SciTech Connect (OSTI)

    Buss, R.J.; Hareland, W.A.

    1993-10-01T23:59:59.000Z

    The production, suspension and transport of fluorocarbon particulates in rf discharges have been studied using in situ laser light scattering and ex situ chemical analysis. The time evolution of the spatial distribution of suspended particles was obtained by 2-D imaging of the scattered light. The chemistry of the discharge was varied by the use of a range of pure fluorocarbon gases and mixtures with argon, oxygen and hydrogen-containing molecules. The addition of hydrogen to a fluorocarbon discharge increases the rate of formation of particles although these powders are found by FTIR to contain negligible hydrogen. Particle formation rates correlate with polymer deposition rates and are independent of apparatus history. It is proposed that this is a clear example of gas-phase rather than surface processes leading to particle nucleation and growth.

  3. Advanced fuel chemistry for advanced engines.

    SciTech Connect (OSTI)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

    2009-09-01T23:59:59.000Z

    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

  4. Chemistry of Low Mass Substellar Objects

    E-Print Network [OSTI]

    Katharina Lodders; Bruce Fegley, Jr

    2006-01-17T23:59:59.000Z

    "Brown dwarfs" is the collective name for objects more massive than giant planets such as Jupiter but less massive than M dwarf stars. This review gives a brief description of the classification and chemistry of low mass dwarfs. The current spectral classification of stars includes L and T dwarfs that encompass the coolest known stars and substellar objects. The relatively low atmospheric temperatures and high total pressures in substellar dwarfs lead to molecular gas and condensate chemistry. The chemistry of elements such as C, N, O, Ti, V, Fe, Cr, and the alkali elements play a dominant role in shaping the optical and infrared spectra of the "failed" stars. Chemical diagnostics for the subclassifications are described.

  5. DOI: 10.1002/adma.200701428 Surface Nanopatterning to Control Cell Growth**

    E-Print Network [OSTI]

    parameters including surface chemistry,[1] elasti- city,[2] topography,[3] and energy.[4] To date, efforts for affecting cellular activity.[9,13,14] Work in this area has been facilitated by recent advances

  6. Near-Field Imaging of Infinite Rough Surfaces in Dielectric Media

    E-Print Network [OSTI]

    Bao, G. and Li, P.

    2014-05-01T23:59:59.000Z

    May 15, 2014 ... of modern science and technology, including surface chemistry, biology, materials science, and ... Research Plan of NSFC (91130004), and a special research grant from Zhejiang University. .... for energy absorption.

  7. Surface Modification of Layered Zirconium Phosphates: A Novel Pathway to Multifunctional Nanomaterials

    E-Print Network [OSTI]

    Mosby, Brian Matthew

    2014-04-08T23:59:59.000Z

    the surface or exterior layers of the material, while leaving the internal layers and structure unchanged. This allows for organic derivatives of layered materials in which the interlayer chemistry is not lost to achieve organic functionalization. The addition...

  8. Publisher's Note: "Ab initio potential energy surfaces for NH,,3 -...-NH,,3 -

    E-Print Network [OSTI]

    Publisher's Note: "Ab initio potential energy surfaces for NH,,3 - ...-NH,,3 - ... with analytical of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland Received 21 December 2009; published

  9. The chemistry of Si{sub 3}N{sub 4} and Si deposition studied using molecular beam techniques

    SciTech Connect (OSTI)

    Buss, R.J.; Ho, P.; Breiland, W.G.

    1992-08-01T23:59:59.000Z

    Molecular beam techniques can be used to obtain valuable kinetic information for the chemistry of high temperature deposition processes. Molecular beam measurements of Si{sub 3}N{sub 4} deposited from SiF{sub 4} and NH{sub 3} have shown that the CVD reactor chemistry is dominated by surface reactions of the starting gases. Using a beam of heated silane, it is shown that the translational and internal energy of the gas does not influence its surface reactivity in silicon CVD. The IRIS (Imaging of Radicals Interacting with Surfaces) technique for measuring the surface reactivity of radicals during deposition is also discussed with examples (SiH, SiO and NH). 5 refs., 4 figs.

  10. The chemistry of Si sub 3 N sub 4 and Si deposition studied using molecular beam techniques

    SciTech Connect (OSTI)

    Buss, R.J.; Ho, P.; Breiland, W.G.

    1992-01-01T23:59:59.000Z

    Molecular beam techniques can be used to obtain valuable kinetic information for the chemistry of high temperature deposition processes. Molecular beam measurements of Si{sub 3}N{sub 4} deposited from SiF{sub 4} and NH{sub 3} have shown that the CVD reactor chemistry is dominated by surface reactions of the starting gases. Using a beam of heated silane, it is shown that the translational and internal energy of the gas does not influence its surface reactivity in silicon CVD. The IRIS (Imaging of Radicals Interacting with Surfaces) technique for measuring the surface reactivity of radicals during deposition is also discussed with examples (SiH, SiO and NH). 5 refs., 4 figs.

  11. Proton Pathways in Green Fluorescence Protein Department of Physical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel

    E-Print Network [OSTI]

    Agmon, Noam

    Proton Pathways in Green Fluorescence Protein Noam Agmon Department of Physical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel ABSTRACT Proton pathways in green fluorescent protein pathway exists from the active site to the protein surface, controlled by a threonine switch. A proton

  12. Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas-phase chemistry

    E-Print Network [OSTI]

    Qiao, Li

    : Coal gasification Carbon gasification Detailed chemistry Heterogeneous surface reactions Radiation Multi-physics numerical modeling a b s t r a c t Fuel synthesis through coal and biomass gasification Fuel synthesis through coal gasification offers a potential solu- tion to the problem of increasing

  13. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization ofChemistry and Transport Chemistry

  14. Chemistry: Theory - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization ofChemistry and TransportChemistryTheory

  15. Chemistry for Measurement and Detection Science publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry Oxide InterfacesChemistry

  16. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry OxideChemistry of

  17. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry OxideChemistry

  18. Tailoring the surface properties of Ti6Al4V by controlled chemical oxidation

    E-Print Network [OSTI]

    activity at the surface of implants, mainly by modifying their topography and physicochemical properties, such as its surface chemistry and energy, roughness, and topography [6]. It is generally accepted that roughTailoring the surface properties of Ti6Al4V by controlled chemical oxidation Fabio Variola a,b , Ji

  19. ASTRONOMY BIOLOGY CHEMISTRY COMPUTER-SCIENCE GEOGRAPHY MATHEMATICS PHYSICS STATISTICS

    E-Print Network [OSTI]

    Bernstein, Phil

    BIOMEDICAL-ENGINEERING ELECTRONIC- ENGINEERING ASTRONOMY BIOLOGY CHEMISTRY COMPUTER-SCIENCE GEOGRAPHY MATHEMATICS PHYSICS STATISTICS HEALTHCARE BIOMEDICAL-ENGINEERING ELECTRONIC-ENGINEERING ASTRONOMY BIOLOGY C H HEALTHCARE BIOMEDICAL-ENGINEERING ELECTRONIC-ENGINEERING ASTRONOMY BIOLOGY CHEMISTRY COMPUTER

  20. 5.301 Chemistry Laboratory Techniques, January IAP 2004

    E-Print Network [OSTI]

    Tabacco, Sarah

    2004-01-01T23:59:59.000Z

    This course is an intensive introduction to the techniques of experimental chemistry and gives first year students an opportunity to learn and master the basic chemistry lab techniques for carrying out experiments. Students ...

  1. Microfluidics for High School Chemistry Students Melissa Hemling,,

    E-Print Network [OSTI]

    Weibel, Douglas B.

    Microfluidics for High School Chemistry Students Melissa Hemling,, John A. Crooks, Piercen M present a laboratory experiment that introduces high school chemistry students to microfluidics while microfluidic systems using nonspecialized equipment that is available in high school classrooms and reagents

  2. Linking local air pollution to global chemistry and climate

    E-Print Network [OSTI]

    Mayer, Monika.; Wang, Chien.; Webster, Mort David.; Prinn, Ronald G.

    We have incorporated a reduced-form urban air chemistry model in MIT's 2D-LO coupled chemistry-climate model. The computationally efficient reduced-form urban model is derived from the California Institute of Technology-Carnegie ...

  3. analytical chemistry laboratory: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: 12;12;A BRIEF HISTORY THE ANALYTICAL CHEMISTRY DIVISION OF OAK RIDGE NATIONAL LABORATORY 1950 hiembers of the Chemistry Division R-on: J. A. Swartout In...

  4. Forrest S. Schultz, PhD Professor of Chemistry

    E-Print Network [OSTI]

    Wu, Mingshen

    to support programs in Nanoscience, Biotechnology, Computer and Electrical Engineering and Plastics with the Chemistry Department to most effectively meet the challenge of a growing demand for chemistry courses

  5. ENVIRONMENTAL CHEMISTRY AND TECHNOLOGY PROGRAM University of Wisconsin-Madison

    E-Print Network [OSTI]

    Sprott, Julien Clinton

    Material damage Ecosystem Impacts Nutrients Toxics Climate Change #12;ENVIRONMENTAL CHEMISTRYENVIRONMENTAL CHEMISTRY AND TECHNOLOGY PROGRAM University of Wisconsin-Madison Optimizing University of Wisconsin-Madison #12;ENVIRONMENTAL CHEMISTRY AND TECHNOLOGY PROGRAM University of Wisconsin

  6. Safety Training Policy Virginia Tech Chemistry Department

    E-Print Network [OSTI]

    Crawford, T. Daniel

    Safety Training Policy Virginia Tech Chemistry Department Approved by the Executive Committee on 06 at specific training sessions or programs is mandatory. Tenure-track faculty members may choose their level research are exempt, as their safety training is incorporated into their laboratory courses. The first step

  7. 1999 Gordon Research Conference on Atmospheric Chemistry

    SciTech Connect (OSTI)

    Storm, C.

    2000-08-01T23:59:59.000Z

    The Gordon Research Conference (GRC) on Atmospheric Chemistry was held at Salve Regina University in Newport, Rhode Island, June 13-18, 1999. The conference was well attended with 151 participants. The attendees represented the spectrum of endeavor in this field coming from academia, industry, and government laboratories, both US and foreign scientists, senior researchers, young investigators, and students.

  8. Chemical Transport Policy Virginia Tech Chemistry Department

    E-Print Network [OSTI]

    Crawford, T. Daniel

    Chemical Transport Policy Virginia Tech Chemistry Department This policy was enacted. The purpose of this policy is to ensure the safety of personnel transporting chemicals and anyone who might be affected by a problem occurring during such transport. The policy also helps to shield stockroom personnel

  9. Spin Contamination in Inorganic Chemistry Calculations

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    R EVISED PAG E PR O O FS ia617 Spin Contamination in Inorganic Chemistry Calculations Jason L . In such cases, 0 is said to be spin contaminated owing to incorporation of higher spin state character of IronSulfur ia618 Clusters). It is important to note that while spin-contaminated and broken

  10. Mathematical Review for Physical Chemistry 1. Integration

    E-Print Network [OSTI]

    Peterson, Kirk A.

    Mathematical Review for Physical Chemistry Outline: 1. Integration (a) Important Integrals (b) Tricks for evaluating integrals 2. Derivatives (a) Important derivatives (b) Tricks 3. Expansions 4 dierentials 6. Properties of Logs 7. Review of Trigonometry 1 Integration: 1.1 Integrals you should know: 1

  11. Environmental Analytical Chemistry (ENERGY, POWER AND ENVIRONMENT)

    E-Print Network [OSTI]

    Sherrill, David

    /or irrational emotions rather than by the sound scientific principles. Since its large-scale introduction half using sound scientific principles. Chemistry occupies central position in discussion of any production sites (movie: Hanford today) 11/2-4 Nuclear Energy production (civilian); Safe reactor designs 11

  12. 128 Department of Chemistry Graduate Catalogue 201415

    E-Print Network [OSTI]

    on nanocapsules, nanocrystals, curcurmin and PAHs for physical and biophysical studies; fluorescence sensing in physical and biophysical chemistry; new methods for depollution of water contaminated by organic pollutants for the degradation of pesticides and chlorinated organic compounds in water; renewable energy, biosensing

  13. Adam D. McFarland Chemistry Department

    E-Print Network [OSTI]

    Janssen, Michel

    Involving Sulfur Compounds@ 2001 M.S., Chemistry, Northwestern University, Evanston, IL 2004 Ph Northwestern University, Department of Materials Science. Present Design and Construction of a low temperature optical ultra-high vacuum scanning tunneling microscope. 1999-2004 Teaching Assistant Northwestern

  14. The Influence of Chemistry, Production and Community

    E-Print Network [OSTI]

    and their interaction on leaf litter chemistry and decomposition in pure stands of aspen (Populus tremuloides) and mixed stands of birch (Betula pa- pyrifera) and aspen at the Aspen Free Air CO2 Enrichment (FACE) experiment in the second year. For aspen litter but not mixed birch-aspen litter, decomposition rates were negatively

  15. Chemistry 180, Section 1 Spring 2014

    E-Print Network [OSTI]

    Nickrent, Daniel L.

    -mail: mmccarroll@chem.siu.edu Text Beer: Tap into the Art and Science of Brewing By Charles Bamforth Oxford 218 Course Description The course covers the science and chemistry of beer and brewing. The history of beer and brewing will be introduced to follow the evolution of beer as a food and beverage, including

  16. Chemistry 181, Section 1 Spring 2014

    E-Print Network [OSTI]

    Nickrent, Daniel L.

    to CHEM 180, The Chemistry of Beer and Brewing. The laboratory will cover various aspects of beer of the various style categories of beer, using the Beer Judge Certificate Program (BJCP) Style Guideline, working in brewing beer from base ingredients using common homebrewing techniques and laboratory scale experiments

  17. Exploring Tuning Strategies for Quantum Chemistry Computations

    E-Print Network [OSTI]

    Sosonkina, Masha

    to an efficient execution. General Atomic and Molecular Electronic Structure (GAMESS), used for ab-initio molecular quantum chemistry calculations, uses NICAN for dynamically making adaptations so as to improve calculations. These calculations include a wide range of Hartree-Fock (HF) wave function (RHF, ROHF, UHF, GVB

  18. Chemistry and Society December 16, 2011

    E-Print Network [OSTI]

    Viola, Ronald

    Chemistry and Society Final Exam December 16, 2011 Answer all multiple choice questions (Part I energy content per gram? A. gasoline B. propane C. hard coal D. hydrogen 3. Which of the following chains 14. A higher octane rating means smoother burning gasoline. Octane rating is increased by: A

  19. 1Fractions and Chemistry Because molecules and

    E-Print Network [OSTI]

    1Fractions and Chemistry Because molecules and atoms come in 'integer' packages, the ratios of gasoline (ethane) are combined with 7 molecules of oxygen you get 4 molecules of carbon dioxide and 6;1 Answer Key Problem 1 - What makes your car go: When 2 molecules of gasoline (ethane) are combined with 7

  20. Dilution physics modeling: Dissolution/precipitation chemistry

    SciTech Connect (OSTI)

    Onishi, Y.; Reid, H.C.; Trent, D.S.

    1995-09-01T23:59:59.000Z

    This report documents progress made to date on integrating dilution/precipitation chemistry and new physical models into the TEMPEST thermal-hydraulics computer code. Implementation of dissolution/precipitation chemistry models is necessary for predicting nonhomogeneous, time-dependent, physical/chemical behavior of tank wastes with and without a variety of possible engineered remediation and mitigation activities. Such behavior includes chemical reactions, gas retention, solids resuspension, solids dissolution and generation, solids settling/rising, and convective motion of physical and chemical species. Thus this model development is important from the standpoint of predicting the consequences of various engineered activities, such as mitigation by dilution, retrieval, or pretreatment, that can affect safe operations. The integration of a dissolution/precipitation chemistry module allows the various phase species concentrations to enter into the physical calculations that affect the TEMPEST hydrodynamic flow calculations. The yield strength model of non-Newtonian sludge correlates yield to a power function of solids concentration. Likewise, shear stress is concentration-dependent, and the dissolution/precipitation chemistry calculations develop the species concentration evolution that produces fluid flow resistance changes. Dilution of waste with pure water, molar concentrations of sodium hydroxide, and other chemical streams can be analyzed for the reactive species changes and hydrodynamic flow characteristics.

  1. UNIVERSITY OF CALIFORNIA, SANTA CRUZ DEPARTMENT OF CHEMISTRY AND BIOCHEMISTRY

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    in Chemistry or a related field and at least one year of additional research training such as postdoctoral

  2. Special Topics in Organic Chemistry Biorenewable Polymers 8833

    E-Print Network [OSTI]

    Sherrill, David

    Biorefinery b. Pretreatment Chemistry Lignocellulosics c. SSF/CBP Conversion of Biomass to BioEthanol d. Third

  3. Department of Chemistry | Center for Catalytic HydrocarbonFunctionali...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Faculty & Research Outreach Programs Graduate Studies Events & Seminars Undergraduate Studies Contact Us Faculty & Research > Research Centers & Programs > Center for...

  4. School of Chemistry FACULTY OF MATHEMATICS AND PHYSICAL SCIENCES

    E-Print Network [OSTI]

    Rzepa, Henry S.

    School of Chemistry FACULTY OF MATHEMATICS AND PHYSICAL SCIENCES CHEMISTRYPOSTGRADUATE MASTERS DEGREES #12;WWW.CHEM.LEEDS.AC.UK 02 School of Chemistry // MASTERS PROGRAMMES contents 03 Welcome 04 Study and Accommodation 19 Visit Us #12;SCHOOLOFCHEMISTRY 03 Welcome to the School of Chemistry The School warmly welcomes

  5. Course Syllabus: Chem W1A General Chemistry Course Information

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    Course Syllabus: Chem W1A General Chemistry Course Information Course Number Chemistry W1A Course) Themed Problems.3. Participation in the discussion forums.4. Chem W1A General Chemistry Syllabus https Syllabus https://elearning.berkeley.edu/AngelUploads/Content/2013SUC... 2 of 10 5/28/13 10:13 AM #12;We

  6. INTERNATIONAL PERCEPTIONS OF THE UK CHEMISTRY RESEARCH BASE

    E-Print Network [OSTI]

    Medical Research Council INTERNATIONAL PERCEPTIONS OF THE UK CHEMISTRY RESEARCH BASE Chemistry advances in many areas. Chemistry research underpins a wide range of activities that benefit society also thank our colleagues from the Medical Research Council (MRC), the Biotechnology and Biological

  7. CHEMISTRY COURSE OFFERINGS, FALL, 2013 (Updated 8/1/13)

    E-Print Network [OSTI]

    Kounaves, Samuel P.

    in Chemistry 61. Techniques in synthesis, spectroscopy, and reactivity studies. Applications of inorganic compounds in synthesis, catalysis, materials sciences, and biology. One laboratory, one lecture, one and chemistry of materials. Three lectures, one laboratory, one recitation. Only one of Chemistry 1, 11, or 16

  8. Chemistry at IIT: Where Can It Take You?

    E-Print Network [OSTI]

    Heller, Barbara

    Chemistry at IIT: Where Can It Take You? CCHEMISTRY CCHEMISTRY To Learn More and How To Apply http://www.iit.edu/csl/pathways/ Undergraduate Admissions: http://www.iit.edu/undergrad_admission/ 800.448.2329 The IIT Legacy in Chemistry opportunities, help you steer your course. The IIT chemistry program is approved by the American Chemical

  9. Chemistry B.S. Fall--First Year

    E-Print Network [OSTI]

    Gering, Jon C.

    Chemistry B.S. Fall--First Year CHEM 130 Chemical Principles I* CHEM 145 Freshman Seminar CHEM 222 Intro to Quant Analysis CHEM 245 Sophomore Seminar CHEM 329 Organic Chemistry I MATH 264 Calculus III LSP coursework Fall--Third Year CHEM 345 Junior Seminar CHEM 323/324 Physical Chemistry

  10. Ris National Laboratory Fuel Cells and Solid State Chemistry Department

    E-Print Network [OSTI]

    Risø National Laboratory Postprint Fuel Cells and Solid State Chemistry Department Year 2007 Paper Højgaard Jensen1, Jørgen B. Bilde-Sørensen3, Mogens Mogensen1 1Fuel Cells and Solid State Chemistry-Sørensen3 , Mogens Mogensen1 1 Fuel Cells and Solid State Chemistry Department, Risø National Laboratory

  11. Interfacial chemistry and structure in ceramic composites

    SciTech Connect (OSTI)

    Jones, R.H.; Saenz, N.T.; Schilling, C.H.

    1990-09-01T23:59:59.000Z

    The interfacial chemistry and structure of ceramic matrix composites (CMCs) play a major role in the properties of these materials. Fiber-matrix interfaces chemistries are vitally important in the fracture strength, fracture toughness, and fracture resistance of ceramic composites because they influence fiber loading and fiber pullout. Elevated-temperature properties are also linked to the interfacial characteristics through the chemical stability of the interface in corrosive environments and the creep/pullout behavior of the interface. Physical properties such as electrical and thermal conductivity are also dependent on the interface. Fiber-matrix interfaces containing a 1-{mu}m-thick multilayered interface with amorphous and graphitic C to a 1-nm-thick SiO{sub 2} layer can result from sintering operations for some composite systems. Fibers coated with C, BN, C/BC/BN, and Si are also used to produce controlled interface chemistries and structures. Growth interfaces within the matrix resulting from processing of CMCs can also be crucial to the behavior of these materials. Evaluation of the interfacial chemistry and structure of CMCs requires the use of a variety of analytical tools, including optical microscopy, scanning electron microscopy, Auger electron spectroscopy, and transmission electron microscopy coupled with energy dispersive x-ray analysis. A review of the interfacial chemistry and structure of SiC whisker- and fiber-reinforced Si{sub 3}N{sub 4} and SiC/SiC materials is presented. Where possible, correlations with fracture properties and high-temperature stability are made. 94 refs., 10 figs.

  12. 1.23 Constraints on Seismic Models from Other Disciplines Implications for Mantle Dynamics and

    E-Print Network [OSTI]

    Long, Bernard

    , and different algorithms for inverting the global seis- mic data. A review of the recent advances in global surface 817 1.23.2.3.5 Boundary conditions at CMB 819 1.23.2.3.6 Determining viscous flow Green functions Response Functions for the Mantle 824 1.23.2.5 Depth Dependence of Mantle Viscosity 825 1.23.3 Modeling

  13. Chemistry Division annual progress report for period ending July 31, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-01-01T23:59:59.000Z

    Research is reported on: chemistry of coal liquefaction, aqueous chemistry at high temperatures, geosciences, high-temperature chemistry and thermodynamics of structural materials, chemistry of TRU elements and compounds, separations chemistry, electrochemistry, nuclear waste chemistry, chemical physics, theoretical chemistry, inorganic chemistry of hydrogen cycles, molten salt systems, and enhanced oil recovery. Separate abstracts were prepared for the sections dealing with coal liquefaction, TRU elements and compounds, separations, nuclear wastes, and enhanced oil recovery. (DLC)

  14. Technical Report TR-012 March 2001 Research Section, Vancouver Forest Region, BCMOF Research Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife

    E-Print Network [OSTI]

    Disciplines: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife TR-012: Ecology ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife #12;Technical Report TR ~ Geology ~ Geomorphology ~ Hydrology ~ Pedology ~ Silviculture ~ Wildlife Page Summary 2 Keywords 2

  15. From the portfolio to the diagram : architectural discourse and the transformation of the discipline of architecture in America, 1918-1943

    E-Print Network [OSTI]

    Pae, Hy?ng-min.

    1993-01-01T23:59:59.000Z

    This dissertation is an historical inquiry into the concomitant transformations of architectural discourse and the discipline of architecture in America. It proceeds on the theoretical assumption that the documents produced ...

  16. Chemistry Division annual progress report for period ending January 31, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-05-01T23:59:59.000Z

    This report has been indexed by 11 separate chapters. The subjects covered are: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, materials chemistry, chemistry of transuranium elements and compounds, separations chemistry, catalysis, electron spectroscopy, nuclear waste chemistry, heuristic modeling, and special topics. (PLG)

  17. Lon A. Porter, Jr., Ph.D. Assistant Professor of Chemistry

    E-Print Network [OSTI]

    Porter Jr., Lon A.

    Nanotechnology, Industrial Inorganic Chemistry, Materials Chemistry, Forensic Chemistry, and Chemistry, Business in the synthesis of exotic new materials and utilization of cutting edge fabrication/characterization methods Fellowship Graduated in August 2003 with a Ph. D. in inorganic chemistry, as related to inorganic chemistry

  18. The Novel ''Controlled Intermediate Nuclear Fusion'' and its Possible Industrial Realization as Predicted by Hadronic Mechanics and Chemistry

    E-Print Network [OSTI]

    Ruggero Maria Santilli

    2006-02-17T23:59:59.000Z

    In this note, we propose, apparently for the first time, a new type of controlled nuclear fusion called "intermediate" because occurring at energies intermediate between those of the ''cold'' and ''hot'' fusions, and propose a specific industrial realization. For this purpose: 1) We show that known limitations of quantum mechanics, quantum chemistry and special relativity cause excessive departures from the conditions occurring for all controlled fusions; 2) We outline the covering hadronic mechanics, hadronic chemistry and isorelativity specifically conceived, constructed and verified during the past two decades for new cleans energies and fuels; 3) We identify seven physical laws predicted by the latter disciplines that have to be verified by all controlled nuclear fusions to occur; 4) We review the industrial research conducted to date in the selection of the most promising engineering realization as well as optimization of said seven laws; and 5) We propose with construction details a specific {\\it hadronic reactor} (patented and international patents pending), consisting of actual equipment specifically intended for the possible industrial production of the clean energy released by representative cases of controlled intermediate fusions for independent scrutiny by interested colleagues.

  19. Negative ion chemistry of SF{sub 4}

    SciTech Connect (OSTI)

    Miller, A.E.; Miller, T.M.; Viggiano, A.A.; Morris, R.A.; VanDoren, J.M.

    1995-06-08T23:59:59.000Z

    Releases of SF6 gas in the earth`s ionosphere have been carried out for three decades. Modeling of the ion chemistry observed taking place following such a release has suggested that SF4 may be produced in successive reactions initiated by the small amount of SF5 formed in electron attachment to SF6. The models show what may be called a plateau in the reaction scheme, beyond which SF4 ion chemistry plays an important role. A similar behavior has been noted by others in studying sparks or glow discharges in SF6, in relation to the use of SF6 vapor in switches and as an insulating gas. The SF4 observed in those cases results from electron-impact fragmentation of SF6 (and aided by metal electrodes which take up fluorine) and from fluoride transfer from SF5 to neutral molecules. SF6 in the earth`s atmosphere is gaining attention as a greenhouse gas. SF6 may have one of the greatest greenhouse warming values (per molecule) of any of the trace greenhouse gases, and despite its many beneficial applications, its use may have to be controlled. The concentration of SF6 in the atmosphere near the earth`s surface is essentially negligible from a greenhouse perspective, but has reportedly increased by 2 orders of magnitude since 1970. Atmospheric models have indicated that the lifetime of an SF6 molecule in the atmosphere may be over 3000 years. Electron interactions may result in a significant reduction in this lifetime.

  20. Chemistry and materials science research report

    SciTech Connect (OSTI)

    Not Available

    1990-05-31T23:59:59.000Z

    The research reported here in summary form was conducted under the auspices of Weapons-Supporting Research (WSR) and Institutional Research and Development (IR D). The period covered is the first half of FY90. The results reported here are for work in progress; thus, they may be preliminary, fragmentary, or incomplete. Research in the following areas are briefly described: energetic materials, tritium, high-Tc superconductors, interfaces, adhesion, bonding, fundamental aspects of metal processing, plutonium, synchrotron-radiation-based materials science, photocatalysis on doped aerogels, laser-induced chemistry, laser-produced molecular plasmas, chemistry of defects, dta equipment development, electronic structure study of the thermodynamic and mechanical properties of Al-Li Alloys, and the structure-property link in sub-nanometer materials.

  1. Simultaneous assessment of phase chemistry, phase abundance and bulk chemistry with statistical electron probe micro-analyses: Application to cement clinkers

    SciTech Connect (OSTI)

    Wilson, William; Krakowiak, Konrad J.; Ulm, Franz-Josef, E-mail: ulm@mit.edu

    2014-01-15T23:59:59.000Z

    According to recent developments in cement clinker engineering, the optimization of chemical substitutions in the main clinker phases offers a promising approach to improve both reactivity and grindability of clinkers. Thus, monitoring the chemistry of the phases may become part of the quality control at the cement plants, along with the usual measurements of the abundance of the mineralogical phases (quantitative X-ray diffraction) and the bulk chemistry (X-ray fluorescence). This paper presents a new method to assess these three complementary quantities with a single experiment. The method is based on electron microprobe spot analyses, performed over a grid located on a representative surface of the sample and interpreted with advanced statistical tools. This paper describes the method and the experimental program performed on industrial clinkers to establish the accuracy in comparison to conventional methods. -- Highlights: A new method of clinker characterization Combination of electron probe technique with cluster analysis Simultaneous assessment of phase abundance, composition and bulk chemistry Experimental validation performed on industrial clinkers.

  2. COSMIC-RAY-MEDIATED FORMATION OF BENZENE ON THE SURFACE OF SATURN'S MOON TITAN

    SciTech Connect (OSTI)

    Zhou Li; Zheng Weijun; Kaiser, Ralf I. [Department of Chemistry, University of Hawaii at Manoa, Honolulu, HI (United States); Landera, Alexander; Mebel, Alexander M. [Department of Chemistry and Biochemistry, Florida International University, Miami, FL (United States); Liang, Mao-Chang [Research Center for Environmental Changes, Academia Sinica, Taipei, Taiwan (China); Yung, Yuk L. [Division of Geological and Planetary Sciences, Caltech, Pasadena, CA (United States)

    2010-08-01T23:59:59.000Z

    The aromatic benzene molecule (C{sub 6}H{sub 6})-a central building block of polycyclic aromatic hydrocarbon molecules-is of crucial importance for the understanding of the organic chemistry of Saturn's largest moon, Titan. Here, we show via laboratory experiments and electronic structure calculations that the benzene molecule can be formed on Titan's surface in situ via non-equilibrium chemistry by cosmic-ray processing of low-temperature acetylene (C{sub 2}H{sub 2}) ices. The actual yield of benzene depends strongly on the surface coverage. We suggest that the cosmic-ray-mediated chemistry on Titan's surface could be the dominant source of benzene, i.e., a factor of at least two orders of magnitude higher compared to previously modeled precipitation rates, in those regions of the surface which have a high surface coverage of acetylene.

  3. International symposium on oilfield chemistry: Proceedings

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    This volume contains 66 papers presented at the symposium related to the following topics in oil field chemistry: waste treatment of produced waters; methods for enhanced recovery of petroleum (mainly surfactants, polymers, and carbon dioxide injection); cement hydration and additives; drilling fluid stability; paraffin deposition in wells and pipelines; scale control and corrosion inhibitors; displacement fluid wettability and environmental transport; fracturing fluids; formation damage; asphaltene removal; and plugging agents. All papers have been processed separately for inclusion on the data base.

  4. The Chemistry of Flammable Gas Generation

    SciTech Connect (OSTI)

    ZACH, J.J.

    2000-10-30T23:59:59.000Z

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  5. CHEMISTRY 3311, Fall 1998 Professor Walba

    E-Print Network [OSTI]

    Walba, David

    Name: -1- CHEMISTRY 3311, Fall 1998 Professor Walba Third Hour Exam November 19, 1998 scores: 1) 2) 3) 4) PLEASE read the questions carefully! This is a closed-book "open model" exam. You may use for scratch. H He Li Be B C N O F Na Mg Al Si P S Ne Cl Ar Br I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

  6. CHEMISTRY 3311, Fall 2000 Professor Walba

    E-Print Network [OSTI]

    Walba, David

    Name: -1- CHEMISTRY 3311, Fall 2000 Professor Walba Third Hour Exam November 16, 2000 scores: 1) 2) 3) 4) PLEASE read the questions carefully! This is a closed-book "open model" exam. You may use for scratch. H He Li Be B C N O F Na Mg Al Si P S Ne Cl Ar Br I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

  7. CHEMISTRY 3311, Fall 2000 Professor Walba

    E-Print Network [OSTI]

    Walba, David

    Name: -1- CHEMISTRY 3311, Fall 2000 Professor Walba Second Hour Exam October 26, 2000 scores: 1) 2) 3) 4) PLEASE read the questions carefully! This is a closed-book "open model" exam. You may use for scratch. H He Li Be B C N O F Na Mg Al Si P S Ne Cl Ar Br I 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

  8. The interfacial chemistry of solidification/stabilization of metals in cement and pozzolanic material systems

    SciTech Connect (OSTI)

    Yousuf, M.; Mollah, A.; Vempati, R.K.; Lin, T.C.; Cocke, D.L. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States)

    1995-11-01T23:59:59.000Z

    The chemistry of cement, its hydration and mechanisms of solidification/stabilization (s/s) of toxic metals by cement-based systems and pozzolanic materials are significantly controlled by surface, near-surface and interfacial phenomena. The adsorption conditions and the selectivity strong affinity of hazardous metals towards clay minerals, certain hydrated metal oxides and oxyhydroxides, and cementitous substances also play an important role in the s/s process for the immobilization of contaminants. Recent works from the authors` laboratory involving metal ions and superplasticizers have elucidated the mechanisms of reactions leading to the retardation of cement hydration and subsequent setting and their interactions with silicate-based systems. This article delineates the current status of interfacial chemistry at the solid-liquid boundary and places it in perspective with present and future s/s processes based on Portland cement and pozzolanic materials. The importance of surface charge, the role of interfacial phenomena on adsorption, and the importance of calcium and other types of anions and cations in s/s are also discussed. A surface charge control reaction model that accounts for the importance of calcium and other cations and anions is outlined and used to discuss the chemical nature and microstructure of the interfacial transition zone.

  9. Quantum Chemistry, and Eclectic Mix: From Silicon Carbide to Size Consistency

    SciTech Connect (OSTI)

    Jamie Marie Rintelman

    2004-12-19T23:59:59.000Z

    Chemistry is a field of great breadth and variety. It is this diversity that makes for both an interesting and challenging field. My interests have spanned three major areas of theoretical chemistry: applications, method development, and method evaluation. The topics presented in this thesis are as follows: (1) a multi-reference study of the geometries and relative energies of four atom silicon carbide clusters in the gas phase; (2) the reaction of acetylene on the Si(100)-(2x1) surface; (3) an improvement to the Effective Fragment Potential (EFP) solvent model to enable the study of reactions in both aqueous and nonaqueous solution; and (4) an evaluation of the size consistency of Multireference Perturbation Theory (MRPT). In the following section, the author briefly discusses two topics central to, and present throughout, this thesis: Multi-reference methods and Quantum Mechanics/Molecular Mechanics (QM/MM) methods.

  10. Evolution of Chemistry and Its Effects on the Corrosion of Engineered Barrier Materials

    SciTech Connect (OSTI)

    Dunn, Darrell [Mechanical and Materials Engineering, Southwest Research Institute, San Antonio, TX, 78238 (United States); Pan, Yi-Ming; He, Xihua; Yang, Lietai; Pabalan, Roberto [Center for Nuclear Waste Regulatory Analyses, San Antonio, TX, 78238 (United States)

    2007-07-01T23:59:59.000Z

    The evolution of environmental conditions within the emplacement drifts of a potential high-level waste repository at Yucca Mountain, Nevada, may be influenced by several factors, including the temperature and relative humidity within the emplacement drifts and the composition of seepage water. The performance of the waste package and the drip shield may be affected by the evolution of the environmental conditions within the emplacement drifts. In this study, tests evaluated the evolution of environmental conditions on the waste package surfaces and in the surrounding host rock. The tests were designed to (i) simulate the conditions expected within the emplacement drifts; (ii) measure the changes in near-field chemistry; and (iii) determine environmental influence on the performance of the engineered barrier materials. Results of tests conducted in this study indicate the composition of salt deposits was consistent with the initial dilute water chemistry. Salts and possibly concentrated calcium chloride brines may be more aggressive than either neutral or alkaline brines. (authors)

  11. Programmable surfaces

    E-Print Network [OSTI]

    Sun, Amy (Amy Teh-Yu)

    2012-01-01T23:59:59.000Z

    Robotic vehicles walk on legs, roll on wheels, are pulled by tracks, pushed by propellers, lifted by wings, and steered by rudders. All of these systems share the common character of momentum transport across their surfaces. ...

  12. Cleaning and passivation of copper surfaces to remove surface radioactivity and prevent oxide formation

    SciTech Connect (OSTI)

    Hoppe, Eric W.; Seifert, Allen; Aalseth, Craig E.; Bachelor, Paula P.; Day, Anthony R.; Edwards, Danny J.; Hossbach, Todd W.; Litke, Kevin E.; McIntyre, Justin I.; Miley, Harry S.; Schulte, Shannon M.; Smart, John E.; Warren, Glen A.

    2007-08-21T23:59:59.000Z

    High-purity copper is an attractive material for constructing ultra-low-background radiation measurement devices. Many low-background experiments using high-purity copper have indicated surface contamination emerges as the dominant background. Radon daughters plate out on exposed surfaces, leaving a residual 210Pb background that is difficult to avoid. Dust is also a problem; even under cleanroom conditions, the amount of U and Th deposited on surfaces can represent the largest remaining background. To control these backgrounds, a copper cleaning chemistry has been developed. Designed to replace an effective, but overly aggressive concentrated nitric acid etch, this peroxide-based solution allows for a more controlled cleaning of surfaces. The acidified hydrogen peroxide solution will generally target the Cu+/Cu2+ species which are the predominant surface participants, leaving the bulk of copper metal intact. This preserves the critical tolerances of parts and eliminates significant waste disposal issues. Accompanying passivation chemistry has also been developed that protects copper surfaces from oxidation. Using a high-activity polonium surface spike, the most difficult-to-remove daughter isotope of radon, the performance of these methods are quantified. 2001 Elsevier Science. All rights reserved

  13. Inductively Coupled Plasma Etching in ICl- and IBr-Based Chemistries: Part II. InP, InSb, InGaP and InGaAs

    SciTech Connect (OSTI)

    Abernathy, C.R.; Cho, H.; Hahn, Y.B.; Hays, D.C.; Hobson, W.S.; Jung, K.B.; Lambers, E.S.; Pearton, S.J.; Shul, R.J.

    1998-11-23T23:59:59.000Z

    A parametric study of Inductively Coupled Plasma etching of InP, InSb, InGaP and InGaAs has been carried out in IC1/Ar and IBr/Ar chemistries. Etch rates in excess of 3.1 prrdmin for InP, 3.6 prnh-nin for InSb, 2.3 pm/min for InGaP and 2.2 ~rrdmin for InGaAs were obtained in IBr/Ar plasmas. The ICP etching of In-based materials showed a general tendency: the etch rates increased substantially with increasing the ICP source power and rf chuck power in both chemistries, while they decreased with increasing chamber pressure. The IBr/Ar chemistry typically showed higher etch rates than IC1/Ar, but the etched surface mophologies were fairly poor for both chemistries.

  14. Overview of actinide chemistry in the WIPP

    SciTech Connect (OSTI)

    Borkowski, Marian [Los Alamos National Laboratory; Lucchini, Jean - Francois [Los Alamos National Laboratory; Richmann, Michael K [Los Alamos National Laboratory; Reed, Donald T [Los Alamos National Laboratory; Khaing, Hnin [Los Alamos National Laboratory; Swanson, Juliet [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    The year 2009 celebrates 10 years of safe operations at the Waste Isolation Pilot Plant (WIPP), the only nuclear waste repository designated to dispose defense-related transuranic (TRU) waste in the United States. Many elements contributed to the success of this one-of-the-kind facility. One of the most important of these is the chemistry of the actinides under WIPP repository conditions. A reliable understanding of the potential release of actinides from the site to the accessible environment is important to the WIPP performance assessment (PA). The environmental chemistry of the major actinides disposed at the WIPP continues to be investigated as part of the ongoing recertification efforts of the WIPP project. This presentation provides an overview of the actinide chemistry for the WIPP repository conditions. The WIPP is a salt-based repository; therefore, the inflow of brine into the repository is minimized, due to the natural tendency of excavated salt to re-seal. Reducing anoxic conditions are expected in WIPP because of microbial activity and metal corrosion processes that consume the oxygen initially present. Should brine be introduced through an intrusion scenario, these same processes will re-establish reducing conditions. In the case of an intrusion scenario involving brine, the solubilization of actinides in brine is considered as a potential source of release to the accessible environment. The following key factors establish the concentrations of dissolved actinides under subsurface conditions: (1) Redox chemistry - The solubility of reduced actinides (III and IV oxidation states) is known to be significantly lower than the oxidized forms (V and/or VI oxidation states). In this context, the reducing conditions in the WIPP and the strong coupling of the chemistry for reduced metals and microbiological processes with actinides are important. (2) Complexation - For the anoxic, reducing and mildly basic brine systems in the WIPP, the most important inorganic complexants are expected to be carbonate/bicarbonate and hydroxide. There are also organic complexants in TRU waste with the potential to strongly influence actinide solubility. (3) Intrinsic and pseudo-actinide colloid formation - Many actinide species in their expected oxidation states tend to form colloids or strongly associate with non actinide colloids present (e.g., microbial, humic and organic). In this context, the relative importance of actinides, based on the TRU waste inventory, with respect to the potential release of actinides from the WIPP, is greater for plutonium and americium, and to less extent for uranium and thorium. The most important oxidation states for WIPP-relevant conditions are III and IV. We will present an update of the literature on WIPP-specific data, and a summary of the ongoing research related to actinide chemistry in the WIPP performed by the Los Alamos National Laboratory (LANL) Actinide Chemistry and Repository Science (ACRSP) team located in Carlsbad, NM [Reed 2007, Lucchini 2007, and Reed 2006].

  15. Magnetic nanoworms Systematic Surface Engineering of Magnetic Nanoworms

    E-Print Network [OSTI]

    Bhatia, Sangeeta

    Magnetic nanoworms Systematic Surface Engineering of Magnetic Nanoworms for in vivo Tumor Targeting and Engineering Program Department of Chemistry and Biochemistry University of California, San Diego 9500 Gilman magnetic materials nanoworms peptides tumor targeting 694 2009 Wiley-VCH Verlag GmbH & Co. KGa

  16. Buffer Layer Assisted Laser Patterning of Metals on Surfaces

    E-Print Network [OSTI]

    Asscher, Micha

    power. In general, absorbed laser power density above 10 MW/cm2 should be avoided, to conserve* Department of Physical Chemistry, The Farkas Center for Light Induced Processes, The Hebrew Uni tool of metallic thin films on surfaces due to their strong binding and the extremely high laser power

  17. Surface Tension Mediated Conversion of Light to Work David Okawa,,

    E-Print Network [OSTI]

    Zettl, Alex

    of intermediates. Considerable effort has been devoted to improving energy collection, storage, and utilization;2Surface Tension Mediated Conversion of Light to Work David Okawa,, Stefan J. Pastine, Alex Zettl,, and Jean M. J. Frechet*,, College of Chemistry and Department of Physics, UniVersity of California

  18. FLAME SURFACE DENSITIES IN PREMIXED COMBUSTION AT MEDIUM TO HIGH

    E-Print Network [OSTI]

    Gülder, ?mer L.

    premixed combustion diagrams. Small-scale transport of heat and species may be more important and chemistryFLAME SURFACE DENSITIES IN PREMIXED COMBUSTION AT MEDIUM TO HIGH TURBULENCE INTENSITIES O¨ MER L in turbulent premixed propane= air flames were determined experimentally. The instantaneous flame fronts were

  19. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our InstagramStructure ofIndustrialSupportingAlbedo at theSurface Soil Surface Soil

  20. Cooperative Research in C1 Chemistry

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2000-10-27T23:59:59.000Z

    C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F-T plant development in the U.S. is in the Alaskan oil fields.

  1. AiR surface: AiR surface 1

    E-Print Network [OSTI]

    Tanaka, Jiro

    AiR surface: 1 PDA AiR surface 1 1: AiR surface () () 2 [1] [2] 3 AiR surface AiR surface surface surface surface 3.1 surface [3]( 3 ) surface 3.2 surface surface AiR surface 4 AiR surface surface AiR surface: Virtual Touch Panel

  2. Environmental Chemistry Division annual report, 1989

    SciTech Connect (OSTI)

    Newman, L.

    1990-01-01T23:59:59.000Z

    The research activities making up the programs in the Environmental Chemistry Division of the Department of Applied Science are presented. Some of the more significant accomplishments during 1989 are described and plans for 1990 are discussed briefly. Publications for the period are listed and abstracts are provided. Research objectives and principal investigators are given for each of the active programs. A list of personnel and collaborators during the past year is presented. The support distribution of FY 1989 is approximately 85% from the Department of Energy (65% Office of Health and Environmental Research), and 15% other agencies (principally from the Electric Power Research Institute).

  3. Radiation Chemistry of Advanced TALSPEAK Flowsheet

    SciTech Connect (OSTI)

    Mincher, Bruce; Peterman, Dean; Mcdowell, Rocklan; Olson, Lonnie; Lumetta, Gregg J.

    2013-08-28T23:59:59.000Z

    This report summarizes the results of initial experiments designed to understand the radiation chemistry of an Advanced TALSPEAK process for separating trivalent lanthanides form the actinides. Biphasic aerated samples were irradiated and then analyzed for post-irradiation constituent concentrations and solvent extraction distribution ratios. The effects of irradiation on the TALSPEAK and Advanced TALSPEAK solvents were similar, with very little degradation of the organic phase extractant. Decomposition products were detected, with a major product in common for both solvents. This product may be responsible for the slight increase in distribution ratios for Eu and Am with absorbed dose, however; separation factors were not greatly affected.

  4. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization ofChemistry and Transport

  5. Chemistry Controls Material's Nanostructure | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry Oxide Interfaces

  6. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of theChemistry Oxide

  7. Chemistry and Materials Science at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms AboutRESEARCH CAPABILITIES Thematerials | CenterChemistry

  8. Exploring Ultrafast Chemistry with Long Pulses: Beyond Pump-Probe...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relevance with respect to electron-driven chemistry and radiation damage in biological systems by low-energy secondary electrons. I will also discuss our very recent experiments...

  9. actinides separation chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for those course guides came largely from Chuck Spuches of the Instructional Development Dibble, Theodore 228 Student Orientation Guide Organic Chemistry Engineering Websites...

  10. actinide chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for those course guides came largely from Chuck Spuches of the Instructional Development Dibble, Theodore 189 Student Orientation Guide Organic Chemistry Engineering Websites...

  11. actinide chemistry progress: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for those course guides came largely from Chuck Spuches of the Instructional Development Dibble, Theodore 210 Student Orientation Guide Organic Chemistry Engineering Websites...

  12. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic...

  13. Boston University's Department of Chemistry Selection of Dissertation Advisory Committee

    E-Print Network [OSTI]

    Boston University's Department of Chemistry Selection of Dissertation Advisory Committee, will select the members of a Dissertation Advisory Committee and submit the list of names to the chair

  14. adaptive chemistry dac: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tool Needs for Faster Mainstream Acceptance of 3D Lim, Sung Kyu 5 Ethical Conduct in Science and Engineering Adapted from Chemistry-Biology Interface Program Ethics Materials...

  15. Variable Charge Soils: Their Mineralogy, Chemistry and Management

    SciTech Connect (OSTI)

    Qafoku, Nik; Van Ranst, Eric; Noble, Andrew; Baert, Geert

    2004-07-01T23:59:59.000Z

    In this article, the mineralogy, chemistry and management of variable charge soils that are spread throughout the world are treated in details.

  16. Rye Patch geothermal development, hydro-chemistry of thermal...

    Open Energy Info (EERE)

    development, hydro-chemistry of thermal water applied to resource definition Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Rye Patch geothermal...

  17. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A. (eds.)

    1984-05-01T23:59:59.000Z

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  18. Chemistry Division annual progress report, February 29, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-07-01T23:59:59.000Z

    Separate abstracts were prepared for 12 of the 13 sections of this report. The remaining section, Chemistry In Support of the Nuclear Fuel Cycles, is very brief. (DLC)

  19. 3.091 Introduction to Solid State Chemistry, Fall 2002

    E-Print Network [OSTI]

    Sadoway, Donald R.

    Basic principles of chemistry and their application to engineering systems. The relationship between electronic structure, chemical bonding, and atomic order. Characterization of atomic arrangements in crystalline and ...

  20. Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry

    E-Print Network [OSTI]

    Gruner, Daniel S.

    Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry Perkin Elmer 560 AA Harvester-Luminometer scintillation counter, CBMG Centrifuges Beckman Coulter Optima XL-I Analytical

  1. Surveys of research in the Chemistry Division, Argonne National Laboratory

    SciTech Connect (OSTI)

    Grazis, B.M. (ed.)

    1992-01-01T23:59:59.000Z

    Research reports are presented on reactive intermediates in condensed phase (radiation chemistry, photochemistry), electron transfer and energy conversion, photosynthesis and solar energy conversion, metal cluster chemistry, chemical dynamics in gas phase, photoionization-photoelectrons, characterization and reactivity of coal and coal macerals, premium coal sample program, chemical separations, heavy elements coordination chemistry, heavy elements photophysics/photochemistry, f-electron interactions, radiation chemistry of high-level wastes (gas generation in waste tanks), ultrafast molecular electronic devices, and nuclear medicine. Separate abstracts have been prepared. Accelerator activites and computer system/network services are also reported.

  2. Surveys of research in the Chemistry Division, Argonne National Laboratory

    SciTech Connect (OSTI)

    Grazis, B.M. [ed.

    1992-11-01T23:59:59.000Z

    Research reports are presented on reactive intermediates in condensed phase (radiation chemistry, photochemistry), electron transfer and energy conversion, photosynthesis and solar energy conversion, metal cluster chemistry, chemical dynamics in gas phase, photoionization-photoelectrons, characterization and reactivity of coal and coal macerals, premium coal sample program, chemical separations, heavy elements coordination chemistry, heavy elements photophysics/photochemistry, f-electron interactions, radiation chemistry of high-level wastes (gas generation in waste tanks), ultrafast molecular electronic devices, and nuclear medicine. Separate abstracts have been prepared. Accelerator activites and computer system/network services are also reported.

  3. Fundamental Studies of Lithium-Sulfur Cell Chemistry

    Broader source: Energy.gov (indexed) [DOE]

    Studies of Lithium-Sulfur Cell Chemistry PI: Nitash Balsara LBNL June 17, 2014 Project ID ESS224 This presentation does not contain any proprietary, confidential, or otherwise...

  4. Sulfurization of carbon surface for vapor phase mercury removal I: Effect of temperature and sulfurization protocol

    E-Print Network [OSTI]

    Borguet, Eric

    with the decomposition of surface functionalities, which creates active sites for sulfur bonding. The presence of H2S2S adsorption, and that surface chemistry played a significant role in the uptake of H2S. Mikhalovsky and Zaitsev [9] showed that H2S adsorption from an inert atmosphere on activated carbons resulted

  5. (Lithium and lead-lithium corrosion and chemistry)

    SciTech Connect (OSTI)

    Tortorelli, P.F.

    1989-10-09T23:59:59.000Z

    Presentations on Mass Transport Processes in Li/Fe-12Cr-1MoVW Steel,'' A Lower Temperature Lithium Purification Process Incorporating Warm Trapping','' and Kinetic Analysis of Corrosion in Pb-17 at. % Li and Comparison to Pure Lithium'' were given by the traveler at the 1989 European Workshop on Lithium and Lead-Lithium Corrosion and Chemistry in Vienna, Austria. The European effort in lead-lithium appeared to be continuing unabated with a future focus on deposition and surface products reactions that can lead to corrosion control. The temperature gain realized from the use of ferritic/martensitic steels instead of austenitic steels in Pb-17 at. % Li appears to be 25--50{degrees}C. The traveler also visited the European Community's Joint Research Centre at Ispra to discuss Fe-Mn-Cr steels. He presented a seminar on Recent ORNL Results on the Development of Fe-Mn-Cr Steels,'' and toured the liquid metal laboratories. Our developmental Fe-Mn-Cr steels, which are compositionally tailored for shallow land burial, would not qualify as low activation'' materials per European standards. Because of both this and the poor sensitization resistance of these steels, our alloy development strategy for reduced activation materials should be critically reviewed.

  6. Chemistry and Materials Science Department annual report, 1988--1989

    SciTech Connect (OSTI)

    Borg, R.J.; Sugihara, T.T.; Cherniak, J.C.; Corey, C.W. [eds.

    1989-12-31T23:59:59.000Z

    This is the first annual report of the Chemistry & Materials Science (C&MS) Department. The principal purpose of this report is to provide a concise summary of our scientific and technical accomplishments for fiscal years 1988 and 1989. The report is also tended to become part of the archival record of the Department`s activities. We plan to publish future editions annually. The activities of the Department can be divided into three broad categories. First, C&MS staff are assigned by the matrix system to work directly in a program. These programmatic assignments typically involve short deadlines and critical time schedules. A second category is longer-term research and development in technologies important to Laboratory programs. The focus and direction of this technology-base work are generally determined by programmatic needs. Finally, the Department manages its own research program, mostly long-range in outlook and basic in orientation. These three categories are not mutually exclusive but form a continuum of technical activities. Representative examples of all three are included in this report. The principal subject matter of this report has been divided into six sections: Innovations in Analysis and Characterization, Advanced Materials, Metallurgical Science and Technology, Surfaces and Interfaces, Energetic Materials and Chemical Synthesis, and Energy-Related Research and Development.

  7. Arsenic chemistry in soils and sediments

    E-Print Network [OSTI]

    Fendorf, S.

    2010-01-01T23:59:59.000Z

    retention mechanisms on goethite. 1. Surface structure.ion adsorbed on synthetic goethite (?-FeOOH). Soil Sci. 35:of arsenic(III) on goethite: spectroscopic evidence for

  8. Turbulence-chemistry interactions in reacting flows

    SciTech Connect (OSTI)

    Barlow, R.S.; Carter, C.D. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01T23:59:59.000Z

    Interactions between turbulence and chemistry in nonpremixed flames are investigated through multiscalar measurements. Simultaneous point measurements of major species, NO, OH, temperature, and mixture fraction are obtained by combining spontaneous Raman scattering, Rayleigh scattering, and laser-induced fluorescence (LIF). NO and OH fluorescence signals are converted to quantitative concentrations by applying shot-to-shot corrections for local variations of the Boltzmann fraction and collisional quenching rate. These measurements of instantaneous thermochemical states in turbulent flames provide insights into the fundamental nature of turbulence-chemistry interactions. The measurements also constitute a unique data base for evaluation and refinement of turbulent combustion models. Experimental work during the past year has focused on three areas: (1) investigation of the effects of differential molecular diffusion in turbulent combustion: (2) experiments on the effects of Halon CF{sub 3}Br, a fire retardant, on the structure of turbulent flames of CH{sub 4} and CO/H{sub 2}/N{sub 2}; and (3) experiments on NO formation in turbulent hydrogen jet flames.

  9. Identification of Adsorbed Phenyl (C6H5) Groups on Metal Surfaces: Electron-Induced Dissociation of Benzene on Au(111)

    E-Print Network [OSTI]

    Ellison, Barney

    of Benzene on Au(111) Denis Syomin, Jooho Kim, and Bruce E. Koel* Department of Chemistry, Uni thermal and electron-induced chemistry of benzene (C6H6) adsorbed on a Au(111) surface. Thermal desorption of benzene occurs in three desorption peaks: monolayer at 239 K, bilayer at 155 K, and multilayer films

  10. Hydrogen transport in nickel ,,111... Department of Physical Chemistry and the Fritz Haber Research Center, The Hebrew University, Jerusalem 91904, Israel

    E-Print Network [OSTI]

    Zeiri, Yehuda

    Hydrogen transport in nickel ,,111... Roi Baer Department of Physical Chemistry and the Fritz Haber Received 13 November 1996; revised manuscript received 21 January 1997 The intricate dynamics of hydrogen of subsurface with surface hydrogen on the nickel host. The analysis is based on the embedded diatomics

  11. Surface treated polypropylene (PP) fibres for reinforced concrete

    SciTech Connect (OSTI)

    Lpez-Buenda, Angel M., E-mail: buendia@uv.es [AIDICO Technological Institute of Construction, Benjamin Franklin 17, 46380 Paterna, Valencia (Spain); Romero-Snchez, Mara Dolores [AIDICO Technological Institute of Construction, Marble Technical Unit, Cam de Castella 4, 03660 Novelda. Alicante (Spain)] [AIDICO Technological Institute of Construction, Marble Technical Unit, Cam de Castella 4, 03660 Novelda. Alicante (Spain); Climent, Vernica [Lafarge Cementos, Polgono Sepes, Isaac Newton s/n, 46500 Sagunto, Valencia (Spain)] [Lafarge Cementos, Polgono Sepes, Isaac Newton s/n, 46500 Sagunto, Valencia (Spain); Guillem, Celia [AIDICO Technological Institute of Construction, Marble Technical Unit, Cam de Castella 4, 03660 Novelda. Alicante (Spain)] [AIDICO Technological Institute of Construction, Marble Technical Unit, Cam de Castella 4, 03660 Novelda. Alicante (Spain)

    2013-12-15T23:59:59.000Z

    Surface treatments on a polypropylene (PP) fibre have contributed to the improvement of fibre/concrete adhesion in fibre-reinforced concrete. The treatments to the PP fibre were characterized by contact angle measurements, ATR-IR and XPS to analyse chemical alterations. The surface topography and fibre/concrete interaction were analysed by several microscopic techniques, namely optical petrographic, and scanning electron microscopy. Treatment modified the surface chemistry and topography of the fibre by introducing sodium moieties and created additional fibre surface roughness. Modifications in the fibre surface led to an increase in the adhesion properties between the treated fibres and concrete and an improvement in the mechanical properties of the fibre-reinforced concrete composite as compared to the concrete containing untreated PP fibres. Compatibility with the concrete and increased roughness and mineral surface was also improved by nucleated portlandite and ettringite mineral association anchored on the alkaline PP fibre surface, which is induced during treatment.

  12. SOLVING VERTICAL TRANSPORT AND CHEMISTRY IN AIR POLLUTION MODELS

    E-Print Network [OSTI]

    Botchev, Mike

    SOLVING VERTICAL TRANSPORT AND CHEMISTRY IN AIR POLLUTION MODELS P.J.F. BERKVENS #3; , M.A. BOTCHEV; transport-chemistry problems from air pollution modelling, standard ODE solvers are not feasible due causing large errors for such species. In the framework of an operational global air pollution model, we

  13. Steven C. Zimmerman Roger Adams Professor of Chemistry

    E-Print Network [OSTI]

    Bashir, Rashid

    and Disciplinary Service Coorganizer, Symposium on Supramolecular Chemistry at the Interface of Materials, Biology, Supramolecular Chemistry Panel of the NSF Macromolecular, Supramolecular and Nanochemistry (MSN) program, Arlington, VA on March 12-13, 2012. National Science Foundation, Macromolecular and Supramolecular Panel 2

  14. A filtered tabulated chemistry model for LES of premixed combustion

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    A filtered tabulated chemistry model for LES of premixed combustion B. Fiorinaa , R. Vicquelina to turbulent combustion regimes by including subgrid scale wrinkling effects in the flame front propagation Simulation, Turbulent premixed combustion, Tabulated chemistry 1. Introduction Flame ignition and extinction

  15. Dissertation Committee Request Form Department of Chemistry and Biochemistry

    E-Print Network [OSTI]

    Taber, Douglass

    Dissertation Committee Request Form Department of Chemistry and Biochemistry Dissertation Candidate)_____________________________________________________ Composition of the Dissertation Committee: (Please refer to Section IVb of Ph.D. Requirements. The above on a dissertation committee in the Chemistry and Biochemistry Department, please submit a brief curriculum vitae

  16. Introduction to Rutgers and the Department of Chemistry

    E-Print Network [OSTI]

    Lawson, Catherine L.

    Modification New Jersey Center for Biomaterials Nucleic Acid Database Protein Data Bank Rutgers Energy and Biophysical Chemistry Molecular Design and Synthesis Nano and Materials Chemistry Energy and EnvironmentAdvisory Board Maxine Ballen New Jersey Technology Council Sol Barer Celgene Anthony Cicatiello - Bio

  17. Midterm Exam: Chemistry 223 McGill University

    E-Print Network [OSTI]

    Ronis, David M.

    Midterm Exam: Chemistry 223 McGill University INSTRUCTIONS 1. No books or notes are permitted. 2;Midterm Exam -2- Chemistry 223 1. (20%) Derive the the expression for ZA,B the number of collisions and to define any sym- bols. 5. (20%) Gasoline is a mixture of various aliphatic hydrocarbons, however, here we

  18. Department of Chemistry University of Wisconsin-Madison

    E-Print Network [OSTI]

    Sheridan, Jennifer

    ://www.chem.wisc.edu/content/safety-information 3) The Chemistry Library Safety page at http://chemistry.library.wisc.edu/resources/#safety The library site contains links to Material Safety Data Sheets (MSDS). You will also need to locate specific, and record its flashpoint, UEL, LEL, Autoignition temperature, flammability classification, extinguishing

  19. Uranium Cluster Chemistry DOI: 10.1002/anie.200906605

    E-Print Network [OSTI]

    Uranium Cluster Chemistry DOI: 10.1002/anie.200906605 Tetranuclear Uranium Clusters by Reductive in the coordination chemistry and small-molecule reactivity of uranium. Among the intriguing reactivity patterns of tetravalent uranium with 3,5-dimethylpyrazolate (Me2Pz ) led to forma- tion of an unprecedented homoleptic

  20. Z .Marine Chemistry 74 2001 1528 www.elsevier.nlrlocatermarchem

    E-Print Network [OSTI]

    Hinch, Scott G.

    Z .Marine Chemistry 74 2001 1528 www.elsevier.nlrlocatermarchem An intercomparison of small a a ( )Department of Marine Chemistry and Geochemistry MS 25 , Woods Hole Oceanographic Institution, Woods Hole, MA that is pro- duced continuously in seawater from its soluble par- Z 9 .ent, uranium-238 t s4.47=10 years